Sample records for high-voltage solid polymer

  1. High-Voltage Solid Polymer Batteries for Electric Drive Vehicles...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Voltage Solid Polymer Batteries for Electric Drive Vehicles High-Voltage Solid Polymer Batteries for Electric Drive Vehicles 2012 DOE Hydrogen and Fuel Cells Program and...

  2. Vehicle Technologies Office Merit Review 2014: High-Voltage Solid Polymer Batteries for Electric Drive Vehicles

    Broader source: Energy.gov [DOE]

    Presentation given by Seeo, Inc. at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high-voltage solid polymer...

  3. Compact high voltage solid state switch

    DOE Patents [OSTI]

    Glidden, Steven C.

    2003-09-23T23:59:59.000Z

    A compact, solid state, high voltage switch capable of high conduction current with a high rate of current risetime (high di/dt) that can be used to replace thyratrons in existing and new applications. The switch has multiple thyristors packaged in a single enclosure. Each thyristor has its own gate drive circuit that circuit obtains its energy from the energy that is being switched in the main circuit. The gate drives are triggered with a low voltage, low current pulse isolated by a small inexpensive transformer. The gate circuits can also be triggered with an optical signal, eliminating the trigger transformer altogether. This approach makes it easier to connect many thyristors in series to obtain the hold off voltages of greater than 80 kV.

  4. High-Voltage Solid Polymer Batteries for Electric Drive Vehicles

    Broader source: Energy.gov (indexed) [DOE]

    - Contractor share: 2.1M * Funding received in FY13: 2.1M * Funding for FY14: 1.3M * Hydro-Qubec (IREQ): - Li anode development - For baseline, interim & final deliverable...

  5. High-Voltage Solid Polymer Batteries for Electric Drive Vehicles

    Broader source: Energy.gov (indexed) [DOE]

    - Contractor share: 2.1M * Funding received in FY11: 0K * Funding for FY12: 1.3M * Hydro-Qubec (IREQ): - Li anode development - For baseline, interim & final deliverable...

  6. High-Voltage Solid Polymer Batteries for Electric Drive Vehicles

    Broader source: Energy.gov (indexed) [DOE]

    - Contractor share: 2.1M * Funding received in FY12: 1.2M * Funding for FY13: 2.0M * Hydro-Qubec (IREQ): - Li anode development - For baseline, interim & final deliverable...

  7. High-Voltage Solid Polymer Batteries for Electric Drive Vehicles

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  8. High-Voltage Solid Polymer Batteries for Electric Drive Vehicles |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGridHYDROGEND D e e p p a a rDepartment

  9. Solid polymer electrolytes

    DOE Patents [OSTI]

    Abraham, Kuzhikalail M. (Needham, MA); Alamgir, Mohamed (Dedham, MA); Choe, Hyoun S. (Waltham, MA)

    1995-01-01T23:59:59.000Z

    This invention relates to Li ion (Li.sup.+) conductive solid polymer electrolytes composed of poly(vinyl sulfone) and lithium salts, and their use in all-solid-state rechargeable lithium ion batteries. The lithium salts comprise low lattice energy lithium salts such as LiN(CF.sub.3 SO.sub.2).sub.2, LiAsF.sub.6, and LiClO.sub.4.

  10. Solid polymer electrolytes

    DOE Patents [OSTI]

    Abraham, K.M.; Alamgir, M.; Choe, H.S.

    1995-12-12T23:59:59.000Z

    This invention relates to Li ion (Li{sup +}) conductive solid polymer electrolytes composed of poly(vinyl sulfone) and lithium salts, and their use in all-solid-state rechargeable lithium ion batteries. The lithium salts comprise low lattice energy lithium salts such as LiN(CF{sub 3}SO{sub 2}){sub 2}, LiAsF{sub 6}, and LiClO{sub 4}. 2 figs.

  11. Temperature controlled high voltage regulator

    DOE Patents [OSTI]

    Chiaro, Jr., Peter J. (Clinton, TN); Schulze, Gerald K. (Knoxville, TN)

    2004-04-20T23:59:59.000Z

    A temperature controlled high voltage regulator for automatically adjusting the high voltage applied to a radiation detector is described. The regulator is a solid state device that is independent of the attached radiation detector, enabling the regulator to be used by various models of radiation detectors, such as gas flow proportional radiation detectors.

  12. Solid polymer electrolyte compositions

    DOE Patents [OSTI]

    Garbe, James E. (Stillwater, MN); Atanasoski, Radoslav (Edina, MN); Hamrock, Steven J. (St. Paul, MN); Le, Dinh Ba (St. Paul, MN)

    2001-01-01T23:59:59.000Z

    An electrolyte composition is featured that includes a solid, ionically conductive polymer, organically modified oxide particles that include organic groups covalently bonded to the oxide particles, and an alkali metal salt. The electrolyte composition is free of lithiated zeolite. The invention also features cells that incorporate the electrolyte composition.

  13. Solid polymer electrolyte lithium batteries

    DOE Patents [OSTI]

    Alamgir, M.; Abraham, K.M.

    1993-10-12T23:59:59.000Z

    This invention pertains to Lithium batteries using Li ion (Li[sup +]) conductive solid polymer electrolytes composed of solvates of Li salts immobilized in a solid organic polymer matrix. In particular, this invention relates to Li batteries using solid polymer electrolytes derived by immobilizing solvates formed between a Li salt and an aprotic organic solvent (or mixture of such solvents) in poly(vinyl chloride). 3 figures.

  14. Solid polymer electrolyte lithium batteries

    DOE Patents [OSTI]

    Alamgir, Mohamed (Dedham, MA); Abraham, Kuzhikalail M. (Needham, MA)

    1993-01-01T23:59:59.000Z

    This invention pertains to Lithium batteries using Li ion (Li.sup.+) conductive solid polymer electrolytes composed of solvates of Li salts immobilized in a solid organic polymer matrix. In particular, this invention relates to Li batteries using solid polymer electrolytes derived by immobilizing solvates formed between a Li salt and an aprotic organic solvent (or mixture of such solvents) in poly(vinyl chloride).

  15. High Voltage Safety Act

    Broader source: Energy.gov [DOE]

    The purpose of the High Voltage Safety Act is to prevent injury to persons and property and interruptions of utility service resulting from accidental or inadvertent contact with high-voltage...

  16. High-Voltage Solid Polymer Batteries for Electric Drive Vehicles | SciTech

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC) EnvironmentalGyroSolé(tm) Harmonicbet WhenHiggsmiddlewareHigh-PressureOffice

  17. DE-EE0005449 High-Voltage Solid Polymer Batteries fo r Electric Drive Vehicles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power Administration would likeConstitution4Customer-Comments Sign8SeeBottomMechanical Testing

  18. Long cycle life solid-state solid polymer electrolyte cells

    SciTech Connect (OSTI)

    Sammells, A.F.

    1988-02-02T23:59:59.000Z

    This patent describes a rechargeable solid-state lithium conducting solid polymer electrolyte electrochemical cell comprising: a lithium intercalation compound negative electrode selected from the group consisting of: MoO/sub 2/; RuO/sub 2/; WO; OsO/sub 2/; IrO/sub 2/; and Mo1/2V1/2O/sub 2/; a lithium ion conducting solid polymer electrolyte comprising a lithium ion conducting supporting electrolyte complexed with a solid polymer contacting the negative electrode on one side; and a lithium intercalation compound positive electrode contacting the opposite side of the solid polymer electrolyte.

  19. High voltage pulse conditioning

    DOE Patents [OSTI]

    Springfield, Ray M. (Sante Fe, NM); Wheat, Jr., Robert M. (Los Alamos, NM)

    1990-01-01T23:59:59.000Z

    Apparatus for conditioning high voltage pulses from particle accelerators in order to shorten the rise times of the pulses. Flashover switches in the cathode stalk of the transmission line hold off conduction for a determinable period of time, reflecting the early portion of the pulses. Diodes upstream of the switches divert energy into the magnetic and electrostatic storage of the capacitance and inductance inherent to the transmission line until the switches close.

  20. ABBGroup-1-High voltage lab

    E-Print Network [OSTI]

    Basse, Nils Plesner

    oscillations are due to travelling waves in the heating volume. #12;©ABBGroup-9- 3-Sep-07 2. High voltage phase interrupts the injected current, it is stressed by the transient recovery voltage (TRV) oscillating©ABBGroup-1- 3-Sep-07 High voltage lab Research on high voltage gas circuit breakers Nils P. Basse

  1. Solid polymer electrolytes for rechargeable batteries

    SciTech Connect (OSTI)

    Narang, S.C.; Macdonald, D.D.

    1990-11-01T23:59:59.000Z

    SRI International has synthesized novel solid polymer electrolytes for high energy density, rechargeable lithium batteries. We have systematically replaced the oxygens in PEO with sulfur to reduce the strong hard-acid hard-base interaction, while retaining the favorable helical conformation of the polymer backbone. The best polymer electrolyte produced so far is suitable for a medium power battery. In another effort, we have synthesized single ion conducting polymer electrolytes based on polyethyleneimine, polyphosphazene, and polysiloxane backbones. The single ion conducting polymer electrolytes will allow greater depth of charge and discharge by preventing dc polarization. The best conductivity so far with single ion conductors is 1.0 {times} 10{sup {minus}3} Scm{sup {minus}1} at room temperature. Further optimization of electrical and mechanical properties will allow the use of these polymer electrolytes in the fabrication of rechargeable lithium batteries. 8 tabs.

  2. Solid polymer MEMS-based fuel cells

    DOE Patents [OSTI]

    Jankowski, Alan F. (Livermore, CA); Morse, Jeffrey D. (Pleasant Hill, CA)

    2008-04-22T23:59:59.000Z

    A micro-electro-mechanical systems (MEMS) based thin-film fuel cells for electrical power applications. The MEMS-based fuel cell may be of a solid oxide type (SOFC), a solid polymer type (SPFC), or a proton exchange membrane type (PEMFC), and each fuel cell basically consists of an anode and a cathode separated by an electrolyte layer. The electrolyte layer can consist of either a solid oxide or solid polymer material, or proton exchange membrane electrolyte materials may be used. Additionally catalyst layers can also separate the electrodes (cathode and anode) from the electrolyte. Gas manifolds are utilized to transport the fuel and oxidant to each cell and provide a path for exhaust gases. The electrical current generated from each cell is drawn away with an interconnect and support structure integrated with the gas manifold. The fuel cells utilize integrated resistive heaters for efficient heating of the materials. By combining MEMS technology with thin-film deposition technology, thin-film fuel cells having microflow channels and full-integrated circuitry can be produced that will lower the operating temperature an will yield an order of magnitude greater power density than the currently known fuel cells.

  3. Solid polymer electrolyte from phosphorylated chitosan

    SciTech Connect (OSTI)

    Fauzi, Iqbal, E-mail: arcana@chem.itb.ac.id; Arcana, I Made, E-mail: arcana@chem.itb.ac.id [Inorganic and Physical Chemistry Research Groups, Faculty of Mathematics and Natural Sciences, Institut Teknologi Bandung, Jl. Ganesha 10, Bandung 40132 (Indonesia)

    2014-03-24T23:59:59.000Z

    Recently, the need of secondary battery application continues to increase. The secondary battery which using a liquid electrolyte was indicated had some weakness. A solid polymer electrolyte is an alternative electrolytes membrane which developed in order to replace the liquid electrolyte type. In the present study, the effect of phosphorylation on to polymer electrolyte membrane which synthesized from chitosan and lithium perchlorate salts was investigated. The effect of the component’s composition respectively on the properties of polymer electrolyte, was carried out by analyzed of it’s characterization such as functional groups, ion conductivity, and thermal properties. The mechanical properties i.e tensile resistance and the morphology structure of membrane surface were determined. The phosphorylation processing of polymer electrolyte membrane of chitosan and lithium perchlorate was conducted by immersing with phosphoric acid for 2 hours, and then irradiated on a microwave for 60 seconds. The degree of deacetylation of chitosan derived from shrimp shells was obtained around 75.4%. Relative molecular mass of chitosan was obtained by viscometry method is 796,792 g/mol. The ionic conductivity of chitosan membrane was increase from 6.33 × 10{sup ?6} S/cm up to 6.01 × 10{sup ?4} S/cm after adding by 15 % solution of lithium perchlorate. After phosphorylation, the ionic conductivity of phosphorylated lithium chitosan membrane was observed 1.37 × 10{sup ?3} S/cm, while the tensile resistance of 40.2 MPa with a better thermal resistance. On the strength of electrolyte membrane properties, this polymer electrolyte membrane was suggested had one potential used for polymer electrolyte in field of lithium battery applications.

  4. High voltage photovoltaic power converter

    DOE Patents [OSTI]

    Haigh, Ronald E. (Arvada, CO); Wojtczuk, Steve (Cambridge, MA); Jacobson, Gerard F. (Livermore, CA); Hagans, Karla G. (Livermore, CA)

    2001-01-01T23:59:59.000Z

    An array of independently connected photovoltaic cells on a semi-insulating substrate contains reflective coatings between the cells to enhance efficiency. A uniform, flat top laser beam profile is illuminated upon the array to produce electrical current having high voltage. An essentially wireless system includes a laser energy source being fed through optic fiber and cast upon the photovoltaic cell array to prevent stray electrical signals prior to use of the current from the array. Direct bandgap, single crystal semiconductor materials, such as GaAs, are commonly used in the array. Useful applications of the system include locations where high voltages are provided to confined spaces such as in explosive detonation, accelerators, photo cathodes and medical appliances.

  5. Solid-particle erosion of bismaleimide polymers

    SciTech Connect (OSTI)

    Brandstaedter, A.; Goretta, K.C.; Routbort, J.L. [Argonne National Lab., IL (United States)] [Argonne National Lab., IL (United States); Groppi, D.P.; Karasek, K.R. [Allied-Signal Inc., Des Plaines, IL (United States)] [Allied-Signal Inc., Des Plaines, IL (United States)

    1991-12-31T23:59:59.000Z

    Solid-particle erosion of bismaleimide (BMI) polymers of various compositions was studied and compared with measured mechanical properties. For angular aluminum oxide erodents of mean diameter 42, 63, 143 or 390 {mu}m impacting normal to the surface at 60 m s{sup {minus}1}, the erosion rate was found to be a strong function of the size of the impacting particle. Material removal occurred primarily by a process of brittle-fracture-induced damage. However, the results suggest that for the BMI specimens, degradation and plasticity occurred in addition to fracture, and that the occurrence of these phenomena reduced the erosion rates.

  6. Solid polymer electrolyte composite membrane comprising laser micromachined porous support

    DOE Patents [OSTI]

    Liu, Han (Waltham, MA); LaConti, Anthony B. (Lynnfield, MA); Mittelsteadt, Cortney K. (Natick, MA); McCallum, Thomas J. (Ashland, MA)

    2011-01-11T23:59:59.000Z

    A solid polymer electrolyte composite membrane and method of manufacturing the same. According to one embodiment, the composite membrane comprises a rigid, non-electrically-conducting support, the support preferably being a sheet of polyimide having a thickness of about 7.5 to 15 microns. The support has a plurality of cylindrical pores extending perpendicularly between opposing top and bottom surfaces of the support. The pores, which preferably have a diameter of about 5 microns, are made by laser micromachining and preferably are arranged in a defined pattern, for example, with fewer pores located in areas of high membrane stress and more pores located in areas of low membrane stress. The pores are filled with a first solid polymer electrolyte, such as a perfluorosulfonic acid (PFSA) polymer. A second solid polymer electrolyte, which may be the same as or different than the first solid polymer electrolyte, may be deposited over the top and/or bottom of the first solid polymer electrolyte.

  7. Passivation-free solid state battery

    DOE Patents [OSTI]

    Abraham, K.M.; Peramunage, D.

    1998-06-16T23:59:59.000Z

    This invention pertains to passivation-free solid-state rechargeable batteries composed of Li{sub 4}Ti{sub 5}O{sub 12} anode, a solid polymer electrolyte and a high voltage cathode. The solid polymer electrolyte comprises a polymer host, such as polyacrylonitrile, poly(vinyl chloride), poly(vinyl sulfone), and poly(vinylidene fluoride), plasticized by a solution of a Li salt in an organic solvent. The high voltage cathode includes LiMn{sub 2}O{sub 4}, LiCoO{sub 2}, LiNiO{sub 2} and LiV{sub 2}O{sub 5} and their derivatives. 5 figs.

  8. Method of synthesizing polymers from a solid electrolyte

    DOE Patents [OSTI]

    Skotheim, T.A.

    1984-10-19T23:59:59.000Z

    A method of synthesizing electrically conductive polymers from a solvent-free solid polymer electrolyte is disclosed. An assembly of a substrate having an electrode thereon, a thin coating of solid electrolyte including a solution of PEO complexed with an alkali salt, and a thin transparent noble metal electrode are disposed in an evacuated chamber into which a selected monomer vapor is introduced while an electric potential is applied across the solid electrolyte to hold the thin transparent electrode at a positive potential relative to the electrode on the substrate, whereby a highly conductive polymer film is grown on the transparent electrode between it and the solid electrolyte.

  9. Solid-polymer-electrolyte fuel cells

    SciTech Connect (OSTI)

    Fuller, T.F.

    1992-07-01T23:59:59.000Z

    A transport model for polymer electrolytes is presented, based on concentrated solution theory and irreversible thermodynamics. Thermodynamic driving forces are developed, transport properties are identified and experiments devised. Transport number of water in Nafion 117 membrane is determined using a concentration cell. It is 1.4 for a membrane equilibrated with saturated water vapor at 25{degrees}C, decreases slowly as the membrane is dehydrated, and falls sharply toward zero as the water content approaches zero. The relation between transference number, transport number, and electroosmotic drag coefficient is presented, and their relevance to water-management is discussed. A mathematical model of transport in a solid-polymer-electrolyte fuel cell is presented. A two-dimensional membrane-electrode assembly is considered. Water management, thermal management, and utilization of fuel are examined in detail. The membrane separators of these fuel cells require sorbed water to maintain conductivity; therefore it is necessary to manage the water content in membranes to ensure efficient operation. Water and thermal management are interrelated. Rate of heat removal is shown to be a critical parameter in the operation of these fuel cells. Current-voltage curves are presented for operation on air and reformed methanol. Equations for convective diffusion to a rotating disk are solved numerically for a consolute point between the bulk concentration and the surface. A singular-perturbation expansion is presented for the condition where the bulk concentration is nearly equal to the consolute-point composition. Results are compared to Levich's solution and analysis.

  10. High voltage DC power supply

    DOE Patents [OSTI]

    Droege, Thomas F. (Batavia, IL)

    1989-01-01T23:59:59.000Z

    A high voltage DC power supply having a first series resistor at the output for limiting current in the event of a short-circuited output, a second series resistor for sensing the magnitude of output current, and a voltage divider circuit for providing a source of feedback voltage for use in voltage regulation is disclosed. The voltage divider circuit is coupled to the second series resistor so as to compensate the feedback voltage for a voltage drop across the first series resistor. The power supply also includes a pulse-width modulated control circuit, having dual clock signals, which is responsive to both the feedback voltage and a command voltage, and also includes voltage and current measuring circuits responsive to the feedback voltage and the voltage developed across the second series resistor respectively.

  11. High voltage DC power supply

    DOE Patents [OSTI]

    Droege, T.F.

    1989-12-19T23:59:59.000Z

    A high voltage DC power supply having a first series resistor at the output for limiting current in the event of a short-circuited output, a second series resistor for sensing the magnitude of output current, and a voltage divider circuit for providing a source of feedback voltage for use in voltage regulation is disclosed. The voltage divider circuit is coupled to the second series resistor so as to compensate the feedback voltage for a voltage drop across the first series resistor. The power supply also includes a pulse-width modulated control circuit, having dual clock signals, which is responsive to both the feedback voltage and a command voltage, and also includes voltage and current measuring circuits responsive to the feedback voltage and the voltage developed across the second series resistor respectively. 7 figs.

  12. Solid-polymer-electrolyte fuel cells

    SciTech Connect (OSTI)

    Fuller, T.F.

    1992-07-01T23:59:59.000Z

    A transport model for polymer electrolytes is presented, based on concentrated solution theory and irreversible thermodynamics. Thermodynamic driving forces are developed, transport properties are identified and experiments devised. Transport number of water in Nafion 117 membrane is determined using a concentration cell. It is 1.4 for a membrane equilibrated with saturated water vapor at 25{degrees}C, decreases slowly as the membrane is dehydrated, and falls sharply toward zero as the water content approaches zero. The relation between transference number, transport number, and electroosmotic drag coefficient is presented, and their relevance to water-management is discussed. A mathematical model of transport in a solid-polymer-electrolyte fuel cell is presented. A two-dimensional membrane-electrode assembly is considered. Water management, thermal management, and utilization of fuel are examined in detail. The membrane separators of these fuel cells require sorbed water to maintain conductivity; therefore it is necessary to manage the water content in membranes to ensure efficient operation. Water and thermal management are interrelated. Rate of heat removal is shown to be a critical parameter in the operation of these fuel cells. Current-voltage curves are presented for operation on air and reformed methanol. Equations for convective diffusion to a rotating disk are solved numerically for a consolute point between the bulk concentration and the surface. A singular-perturbation expansion is presented for the condition where the bulk concentration is nearly equal to the consolute-point composition. Results are compared to Levich`s solution and analysis.

  13. Solid electrolyte material manufacturable by polymer processing methods

    DOE Patents [OSTI]

    Singh, Mohit; Gur, Ilan; Eitouni, Hany Basam; Balsara, Nitash Pervez

    2012-09-18T23:59:59.000Z

    The present invention relates generally to electrolyte materials. According to an embodiment, the present invention provides for a solid polymer electrolyte material that is ionically conductive, mechanically robust, and can be formed into desirable shapes using conventional polymer processing methods. An exemplary polymer electrolyte material has an elastic modulus in excess of 1.times.10.sup.6 Pa at 90 degrees C. and is characterized by an ionic conductivity of at least 1.times.10.sup.-5 Scm-1 at 90 degrees C. An exemplary material can be characterized by a two domain or three domain material system. An exemplary material can include material components made of diblock polymers or triblock polymers. Many uses are contemplated for the solid polymer electrolyte materials. For example, the present invention can be applied to improve Li-based batteries by means of enabling higher energy density, better thermal and environmental stability, lower rates of self-discharge, enhanced safety, lower manufacturing costs, and novel form factors.

  14. Solid polymer electrolyte composite membrane comprising plasma etched porous support

    DOE Patents [OSTI]

    Liu, Han (Waltham, MA); LaConti, Anthony B. (Lynnfield, MA)

    2010-10-05T23:59:59.000Z

    A solid polymer electrolyte composite membrane and method of manufacturing the same. According to one embodiment, the composite membrane comprises a rigid, non-electrically-conducting support, the support preferably being a sheet of polyimide having a thickness of about 7.5 to 15 microns. The support has a plurality of cylindrical pores extending perpendicularly between opposing top and bottom surfaces of the support. The pores, which preferably have a diameter of about 0.1 to 5 microns, are made by plasma etching and preferably are arranged in a defined pattern, for example, with fewer pores located in areas of high membrane stress and more pores located in areas of low membrane stress. The pores are filled with a first solid polymer electrolyte, such as a perfluorosulfonic acid (PFSA) polymer. A second solid polymer electrolyte, which may be the same as or different than the first solid polymer electrolyte, may be deposited over the top and/or bottom of the first solid polymer electrolyte.

  15. Low power, scalable multichannel high voltage controller

    DOE Patents [OSTI]

    Stamps, James Frederick (Livermore, CA); Crocker, Robert Ward (Fremont, CA); Yee, Daniel Dadwa (Dublin, CA); Dils, David Wright (Fort Worth, TX)

    2008-03-25T23:59:59.000Z

    A low voltage control circuit is provided for individually controlling high voltage power provided over bus lines to a multitude of interconnected loads. An example of a load is a drive for capillary channels in a microfluidic system. Control is distributed from a central high voltage circuit, rather than using a number of large expensive central high voltage circuits to enable reducing circuit size and cost. Voltage is distributed to each individual load and controlled using a number of high voltage controller channel switches connected to high voltage bus lines. The channel switches each include complementary pull up and pull down photo isolator relays with photo isolator switching controlled from the central high voltage circuit to provide a desired bus line voltage. Switching of the photo isolator relays is further controlled in each channel switch using feedback from a resistor divider circuit to maintain the bus voltage swing within desired limits. Current sensing is provided using a switched resistive load in each channel switch, with switching of the resistive loads controlled from the central high voltage circuit.

  16. Low power, scalable multichannel high voltage controller

    DOE Patents [OSTI]

    Stamps, James Frederick (Livermore, CA); Crocker, Robert Ward (Fremont, CA); Yee, Daniel Dadwa (Dublin, CA); Dils, David Wright (Fort Worth, TX)

    2006-03-14T23:59:59.000Z

    A low voltage control circuit is provided for individually controlling high voltage power provided over bus lines to a multitude of interconnected loads. An example of a load is a drive for capillary channels in a microfluidic system. Control is distributed from a central high voltage circuit, rather than using a number of large expensive central high voltage circuits to enable reducing circuit size and cost. Voltage is distributed to each individual load and controlled using a number of high voltage controller channel switches connected to high voltage bus lines. The channel switches each include complementary pull up and pull down photo isolator relays with photo isolator switching controlled from the central high voltage circuit to provide a desired bus line voltage. Switching of the photo isolator relays is further controlled in each channel switch using feedback from a resistor divider circuit to maintain the bus voltage swing within desired limits. Current sensing is provided using a switched resistive load in each channel switch, with switching of the resistive loads controlled from the central high voltage circuit.

  17. Optically triggered high voltage switch network and method for switching a high voltage

    DOE Patents [OSTI]

    El-Sharkawi, Mohamed A. (Renton, WA); Andexler, George (Everett, WA); Silberkleit, Lee I. (Mountlake Terrace, WA)

    1993-01-19T23:59:59.000Z

    An optically triggered solid state switch and method for switching a high voltage electrical current. A plurality of solid state switches (350) are connected in series for controlling electrical current flow between a compensation capacitor (112) and ground in a reactive power compensator (50, 50') that monitors the voltage and current flowing through each of three distribution lines (52a, 52b and 52c), which are supplying three-phase power to one or more inductive loads. An optical transmitter (100) controlled by the reactive power compensation system produces light pulses that are conveyed over optical fibers (102) to a switch driver (110') that includes a plurality of series connected optical triger circuits (288). Each of the optical trigger circuits controls a pair of the solid state switches and includes a plurality of series connected resistors (294, 326, 330, and 334) that equalize or balance the potential across the plurality of trigger circuits. The trigger circuits are connected to one of the distribution lines through a trigger capacitor (340). In each switch driver, the light signals activate a phototransistor (300) so that an electrical current flows from one of the energy reservoir capacitors through a pulse transformer (306) in the trigger circuit, producing gate signals that turn on the pair of serially connected solid state switches (350).

  18. High Voltage Electrolyte for Lithium Batteries

    Broader source: Energy.gov (indexed) [DOE]

    Argonne's Fluorinated Compounds as High Voltage Electrolytes (HVEs) O O O O O O EC EMC O O O CF CF 3 CF 3 O O O CF 3 F 2 HC C F 2 O F 2 C CF 2 H 6 Code Name Chemical...

  19. Design, construction and operational results of the IGBT controlled solid state modulator high voltage power supply used in the high power RF systems of the Low Energy Demonstration Accelerator of the accelerator production of tritium (APT) project

    SciTech Connect (OSTI)

    Bradley, J.T. III; Rees, D.; Przeklasa, R.S. [Los Alamos National Lab., NM (United States); Scott, M.C. [Continental Electronics Corp., Dallas, TX (United States)

    1998-12-31T23:59:59.000Z

    The 1700 MeV, 100 mA Accelerator Production of Tritium (APT) Proton Linac will require 244 1 MW, continuous wave RF systems. 1 MW continuous wave klystrons are used as the RF source and each klystron requires 95 kV, 17 A of beam voltage and current. The cost of the DC power supplies is the single largest percentage of the total RF system cost. Power supply reliability is crucial to overall RF system availability and AC to DC conversion efficiency affects the operating cost. The Low Energy Demonstration Accelerator (LEDA) being constructed at Los Alamos National Laboratory (LANL) will serve as the prototype and test bed for APT. The design of the RF systems used in LEDA is driven by the need to field test high efficiency systems with extremely high reliability before APT is built. The authors present a detailed description and test results of one type of advanced high voltage power supply system using Insulated Gate Bipolar Transistors (IGBTs) that has been used with the LEDA High Power RF systems. The authors also present some of the distinctive features offered by this power supply topology, including crowbarless tube protection and modular construction which allows graceful degradation of power supply operation.

  20. Production of high voltage by ion bombardment

    E-Print Network [OSTI]

    Phinney, Lucas Carter

    2003-01-01T23:59:59.000Z

    . . . 35 FIGIJRE Page 19 I-V curve for the ammeter setup . . 35 20 Diagram of the leakage current test setup . . . . . . 37 21 Voltmeter readings at each high voltage interval . . . . . , 38 CHAPTER I INTRODUCTION Direct energy conversion... streaming into the source There is also a moveable shutter that can stop the beam &om entering the beam line. A Varian VHS-6 diffusion pump is connected at the bottom of the glass cross. Its function is to maintain a vacuum in this part of the accelerator...

  1. Structural Optimization of High Voltage Transmission Line Towers considering

    E-Print Network [OSTI]

    Colominas, Ignasi

    Structural Optimization of High Voltage Transmission Line Towers considering Continuum and Discrete/or to common designs largely repeated (e.g. automotive compo- nents), and high voltage transmission towers can than conventional designs of high voltage transmission line towers. The optimization model proposed

  2. Chapter 17. High-Voltage Systems and Dielectric Materials High-Voltage Systems and Dielectric Materials

    E-Print Network [OSTI]

    -Voltage Systems and Dielectric Materials 17-2 RLE Progress Report 152 provides very useful insight into pre-breakdown in high voltage conduction and breakdown phenomena. 1. Mechanisms Behind Positive Streamers and Their Distinct Propagation Modes in Transformer Oil Sponsors This work was supported by ABB Corporate Research

  3. Electro-optic high voltage sensor

    DOE Patents [OSTI]

    Davidson, James R.; Seifert, Gary D.

    2003-09-16T23:59:59.000Z

    A small sized electro-optic voltage sensor capable of accurate measurement of high voltages without contact with a conductor or voltage source is provided. When placed in the presence of an electric field, the sensor receives an input beam of electromagnetic radiation. A polarization beam displacer separates the input beam into two beams with orthogonal linear polarizations and causes one linearly polarized beam to impinge a crystal at a desired angle independent of temperature. The Pockels effect elliptically polarizes the beam as it travels through the crystal. A reflector redirects the beam back through the crystal and the beam displacer. On the return path, the polarization beam displacer separates the elliptically polarized beam into two output beams of orthogonal linear polarization. The system may include a detector for converting the output beams into electrical signals and a signal processor for determining the voltage based on an analysis of the output beams.

  4. Millisecond switching in solid state electrochromic polymer devices fabricated from ionic self-assembled multilayers

    E-Print Network [OSTI]

    Heflin, Randy

    Millisecond switching in solid state electrochromic polymer devices fabricated from ionic self The electrochromic switching times of solid state conducting polymer devices fabricated by the ionic self shown to decrease with the active area of the electrochromic device suggesting that even faster

  5. Modular high voltage power supply for chemical analysis

    DOE Patents [OSTI]

    Stamps, James F. (Livermore, CA); Yee, Daniel D. (Dublin, CA)

    2010-05-04T23:59:59.000Z

    A high voltage power supply for use in a system such as a microfluidics system, uses a DC-DC converter in parallel with a voltage-controlled resistor. A feedback circuit provides a control signal for the DC-DC converter and voltage-controlled resistor so as to regulate the output voltage of the high voltage power supply, as well as, to sink or source current from the high voltage supply.

  6. Modular high voltage power supply for chemical analysis

    SciTech Connect (OSTI)

    Stamps, James F. (Livermore, CA); Yee, Daniel D. (Dublin, CA)

    2007-01-09T23:59:59.000Z

    A high voltage power supply for use in a system such as a microfluidics system, uses a DC--DC converter in parallel with a voltage-controlled resistor. A feedback circuit provides a control signal for the DC--DC converter and voltage-controlled resistor so as to regulate the output voltage of the high voltage power supply, as well as, to sink or source current from the high voltage supply.

  7. Modular high voltage power supply for chemical analysis

    SciTech Connect (OSTI)

    Stamps, James F. (Livermore, CA); Yee, Daniel D. (Dublin, CA)

    2008-07-15T23:59:59.000Z

    A high voltage power supply for use in a system such as a microfluidics system, uses a DC-DC converter in parallel with a voltage-controlled resistor. A feedback circuit provides a control signal for the DC-DC converter and voltage-controlled resistor so as to regulate the output voltage of the high voltage power supply, as well as, to sink or source current from the high voltage supply.

  8. Nanoscale Morphological and Chemical Changes of High Voltage...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanoscale Morphological and Chemical Changes of High Voltage Lithium-Manganese Rich NMC Composite Cathodes with Cycling Friday, August 29, 2014 Renewable energy is critical for the...

  9. Measurement of high voltage using Rutherford backscattering spectrometry

    E-Print Network [OSTI]

    Abrego, Celestino Pete

    2007-04-25T23:59:59.000Z

    A novel variation of Rutherford Backscattering Spectrometry (RBS) has been utilized to measure a high voltage collected on an aluminum target by Direct Energy Conversion. The maximum high voltage on the target was measured to be 97.5 kV +/- 2 k...

  10. Stimuli-Tailored Dispersion State of Aqueous Carbon Nanotube Suspensions and Solid Polymer Nanocomposites 

    E-Print Network [OSTI]

    Etika, Krishna

    2012-02-14T23:59:59.000Z

    state. The ability to tailor nanoparticle dispersion state in liquid and solid media can ultimately provide a powerful method for tailoring the properties of solution processed nanoparticle-filled polymer composites. This dissertation reports the use...

  11. High-voltage air-core pulse transformers

    SciTech Connect (OSTI)

    Rohwein, G. J.

    1981-01-01T23:59:59.000Z

    General types of air core pulse transformers designed for high voltage pulse generation and energy transfer applications are discussed with special emphasis on pulse charging systems which operate up to the multi-megavolt range. The design, operation, dielectric materials, and performance are described. It is concluded that high voltage air core pulse transformers are best suited to applications outside the normal ranges of conventional magnetic core transformers. In general these include charge transfer at high power levels and fast pulse generation with comparatively low energy. When properly designed and constructed, they are capable of delivering high energy transfer efficiency and have demonstrated superior high voltage endurance. The principal disadvantage of high voltage air core transformers is that they are not generally available from commercial sources. Consequently, the potential user must become thoroughly familiar with all aspects of design, fabrication and system application before he can produce a high performance transformer system. (LCL)

  12. Unravelling the Performance Degradation Mechanisms in High-voltage...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Unravelling the Performance Degradation Mechanisms in High-voltage Lithium-ion Battery Composite Oxide Electrodes Apr 11 2014 02:00 PM - 03:00 PM Debasish Mohanty, ORNL, Oak Ridge...

  13. active polymer solids: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stem-flower'' polymer conformation, and the related mechanism of zipping'' during the adsorption process are shown to lead to a Fokker-Planck equation with reflecting boundary...

  14. E-beam high voltage switching power supply

    DOE Patents [OSTI]

    Shimer, Daniel W. (Danville, CA); Lange, Arnold C. (Livermore, CA)

    1997-01-01T23:59:59.000Z

    A high power, solid state power supply is described for producing a controllable, constant high voltage output under varying and arcing loads suitable for powering an electron beam gun or other ion source. The present power supply is most useful for outputs in a range of about 100-400 kW or more. The power supply is comprised of a plurality of discrete switching type dc-dc converter modules, each comprising a voltage regulator, an inductor, an inverter for producing a high frequency square wave current of alternating polarity, an improved inverter voltage clamping circuit, a step up transformer, and an output rectifier for producing a dc voltage at the output of each module. The inputs to the converter modules are fed from a common dc rectifier/filter and are linked together in parallel through decoupling networks to suppress high frequency input interactions. The outputs of the converter modules are linked together in series and connected to the input of the transmission line to the load through a decoupling and line matching network. The dc-dc converter modules are phase activated such that for n modules, each module is activated equally 360.degree./n out of phase with respect to a successive module. The phased activation of the converter modules, combined with the square current waveforms out of the step up transformers, allows the power supply to operate with greatly reduced output capacitance values which minimizes the stored energy available for discharge into an electron beam gun or the like during arcing. The present power supply also provides dynamic response to varying loads by controlling the voltage regulator duty cycle using simulated voltage feedback signals and voltage feedback loops. Circuitry is also provided for sensing incipient arc currents reflected at the output of the power supply and for simultaneously decoupling the power supply circuitry from the arcing load.

  15. E-beam high voltage switching power supply

    DOE Patents [OSTI]

    Shimer, D.W.; Lange, A.C.

    1997-03-11T23:59:59.000Z

    A high power, solid state power supply is described for producing a controllable, constant high voltage output under varying and arcing loads suitable for powering an electron beam gun or other ion source. The present power supply is most useful for outputs in a range of about 100-400 kW or more. The power supply is comprised of a plurality of discrete switching type dc-dc converter modules, each comprising a voltage regulator, an inductor, an inverter for producing a high frequency square wave current of alternating polarity, an improved inverter voltage clamping circuit, a step up transformer, and an output rectifier for producing a dc voltage at the output of each module. The inputs to the converter modules are fed from a common dc rectifier/filter and are linked together in parallel through decoupling networks to suppress high frequency input interactions. The outputs of the converter modules are linked together in series and connected to the input of the transmission line to the load through a decoupling and line matching network. The dc-dc converter modules are phase activated such that for n modules, each module is activated equally 360{degree}/n out of phase with respect to a successive module. The phased activation of the converter modules, combined with the square current waveforms out of the step up transformers, allows the power supply to operate with greatly reduced output capacitance values which minimizes the stored energy available for discharge into an electron beam gun or the like during arcing. The present power supply also provides dynamic response to varying loads by controlling the voltage regulator duty cycle using simulated voltage feedback signals and voltage feedback loops. Circuitry is also provided for sensing incipient arc currents reflected at the output of the power supply and for simultaneously decoupling the power supply circuitry from the arcing load. 7 figs.

  16. Design and development of a cooling device for solid polymer electrolyte fuel cells

    E-Print Network [OSTI]

    Nandi, Asis

    1991-01-01T23:59:59.000Z

    DESIGN AND DEVEI OPMENT OF A COOLING DEVICE FOR SOLID POLYMER ELECTROLYTE FUEL CELLS A Thesis by- ASIS NANDI Submitted to the Office of Graduate Studies of Texas ALA'I Ifniversity in partial fulfillment of the requirements I' or the degree ot...' MASTER OF SCIENCE December 1991 Major Subject: Mechanical Engineering DESIGN AND DEVELOPMENT OF A COOLING DEVICE FOR SOLID POLYMER ELECTROLYTE FUEL CELLS A Thesis ASIS lVAiVDI Approved as to style and content by: q. v, 4~. V. K. Anand (' Chair...

  17. High voltage switch triggered by a laser-photocathode subsystem

    DOE Patents [OSTI]

    Chen, Ping; Lundquist, Martin L.; Yu, David U. L.

    2013-01-08T23:59:59.000Z

    A spark gap switch for controlling the output of a high voltage pulse from a high voltage source, for example, a capacitor bank or a pulse forming network, to an external load such as a high gradient electron gun, laser, pulsed power accelerator or wide band radar. The combination of a UV laser and a high vacuum quartz cell, in which a photocathode and an anode are installed, is utilized as triggering devices to switch the spark gap from a non-conducting state to a conducting state with low delay and low jitter.

  18. Current isolating epitaxial buffer layers for high voltage photodiode array

    DOE Patents [OSTI]

    Morse, Jeffrey D. (Martinez, CA); Cooper, Gregory A. (Pleasant Hill, CA)

    2002-01-01T23:59:59.000Z

    An array of photodiodes in series on a common semi-insulating substrate has a non-conductive buffer layer between the photodiodes and the semi-insulating substrate. The buffer layer reduces current injection leakage between the photodiodes of the array and allows optical energy to be converted to high voltage electrical energy.

  19. Ultra-compact Marx-type high-voltage generator

    DOE Patents [OSTI]

    Goerz, David A. (Brentwood, CA); Wilson, Michael J. (Modesto, CA)

    2000-01-01T23:59:59.000Z

    An ultra-compact Marx-type high-voltage generator includes individual high-performance components that are closely coupled and integrated into an extremely compact assembly. In one embodiment, a repetitively-switched, ultra-compact Marx generator includes low-profile, annular-shaped, high-voltage, ceramic capacitors with contoured edges and coplanar extended electrodes used for primary energy storage; low-profile, low-inductance, high-voltage, pressurized gas switches with compact gas envelopes suitably designed to be integrated with the annular capacitors; feed-forward, high-voltage, ceramic capacitors attached across successive switch-capacitor-switch stages to couple the necessary energy forward to sufficiently overvoltage the spark gap of the next in-line switch; optimally shaped electrodes and insulator surfaces to reduce electric field stresses in the weakest regions where dissimilar materials meet, and to spread the fields more evenly throughout the dielectric materials, allowing them to operate closer to their intrinsic breakdown levels; and uses manufacturing and assembly methods to integrate the capacitors and switches into stages that can be arranged into a low-profile Marx generator.

  20. Field Optimization of Three Dimensional High Voltage C. Trinitis

    E-Print Network [OSTI]

    Stamatakis, Alexandros

    Field Optimization of Three Dimensional High Voltage Equipment C. Trinitis Lehrstuhl f The goal of finding an optimal electric field strength distribution for arbitrary three di­ mensional­ cal optimization algorithm. The package ob­ tained from these three components is then able

  1. High Voltage DC Transmission 1.0 Introduction

    E-Print Network [OSTI]

    McCalley, James D.

    1 High Voltage DC Transmission 1.0 Introduction HVDC has been applied in electric power systems for many years now. Figure 1 illustrates worldwide many of the HVDC applications [1]. Fig. 1 ABB provides a webpage which summarizes HVDC projects by type and capacity or by commissioning year [2]. Wikipedia [3

  2. High Voltage DC Transmission 2 1.0 Introduction

    E-Print Network [OSTI]

    McCalley, James D.

    1 High Voltage DC Transmission 2 1.0 Introduction Interconnecting HVDC within an AC system requires on use of switching devices collectively referred to in the HVDC community as valves. Valves may be non. Fig. 1 There have been three types of devices for implementing HVDC converter circuits: mercury

  3. Low-profile high-voltage compact gas switch

    SciTech Connect (OSTI)

    Goerz, D.A.; Wilson, M.J.; Speer, R.D.

    1997-06-30T23:59:59.000Z

    This paper discusses the development and testing of a low-profile, high-voltage, spark-gap switch designed to be closely coupled with other components into an integrated high-energy pulsed-power source. The switch is designed to operate at 100 kV using SF6 gas pressurized to less than 0.7 MPa. The volume of the switch cavity region is less than 1.5 cm3, and the field stress along the gas-dielectric interface is as high as 130 kV/cm. The dielectric switch body has a low profile that is only I -cm tall at its greatest extent and nominally 2-mm thick over most of its area. This design achieves a very low inductance of less than 5 nH, but results in field stresses exceeding 500 kV/cm in the dielectric material. Field modeling was done to determine the appropriate shape for the highly stressed insulator and electrodes, and special manufacturing techniques were employed to mitigate the usual mechanisms that induce breakdown and failure in solid dielectrics. Static breakdown tests verified that the switch operates satisfactorily at 100 kV levels. The unit has been characterized with different shaped electrodes having nominal gap spacings of 2.0, 2.5, and 3.0 mm. The relationship between self-break voltage and operating pressure agrees well with published data on gas properties, accounting for the field enhancements of the electrode shapes being used. Capacitor discharge tests in a low inductance test fixture exhibited peak currents up to 25 kA with characteristic frequencies of the ringdown circuit ranging from 10 to 20 MHz. The ringdown waveforms and scaling of measured parameters agree well with circuit modeling of the switch and test fixture. Repetitive operation has been demonstrated at moderate rep-rates up to 15 Hz, limited by the power supply being used. Preliminary tests to evaluate lifetime of the compact switch assembly have been encouraging. In one case, after more than 7,000 high-current ringdown tests with approximately 30 C of total charge transferred, the switch continued to operate satisfactorily with no apparent tracking or deterioration of the insulator.

  4. Radio-Frequency Interference (RFI) From Extra-High-Voltage (EHV) Transmission Lines

    E-Print Network [OSTI]

    Ellingson, Steven W.

    -current (HVAC) transmission lines; high-voltage direct-current (HVDC) transmission lines will be addressed

  5. Quantification of the solid-state charge mobility in a model radical polymer

    SciTech Connect (OSTI)

    Baradwaj, Aditya G.; Rostro, Lizbeth; Boudouris, Bryan W., E-mail: boudouris@purdue.edu [School of Chemical Engineering, Purdue University, 480 Stadium Mall Drive, West Lafayette, Indiana 47907 (United States); Alam, Muhammad A. [School of Electrical and Computer Engineering, Purdue University, 475 Northwestern Avenue, West Lafayette, Indiana 47907 (United States)

    2014-05-26T23:59:59.000Z

    We establish that an oft-used radical polymer, poly(2,2,6,6-tetramethylpiperidinyloxy methacrylate) (PTMA), has a solid-state hole mobility value on the order of 10{sup ?4} cm{sup 2} V{sup ?1} s{sup ?1} in a space charge-limited device geometry. Despite being completely amorphous and lacking any ?-conjugation, these results demonstrate that the hole mobility of PTMA is comparable to many well-studied conjugated polymers [e.g., poly(3-hexylthiophene)]. Furthermore, we show that the space charge-limited charge carrier mobility of these macromolecules is only a weak function of temperature, in contrast to many thermally-activated models of charge transport in polymeric materials. This key result demonstrates that the charge transport in radical polymers is inherently different than that in semicrystalline, conjugated polymers. These results establish the mechanism of solid-state charge transport in radical polymers and provide macromolecular design principles for this emerging class of organic electronic materials.

  6. Planar LTCC transformers for high voltage flyback converters: Part II.

    SciTech Connect (OSTI)

    Schofield, Daryl (NASCENTechnology, Inc., Watertown, SD); Schare, Joshua M., Ph.D.; Slama, George (NASCENTechnology, Inc., Watertown, SD); Abel, David (NASCENTechnology, Inc., Watertown, SD)

    2009-02-01T23:59:59.000Z

    This paper is a continuation of the work presented in SAND2007-2591 'Planar LTCC Transformers for High Voltage Flyback Converters'. The designs in that SAND report were all based on a ferrite tape/dielectric paste system originally developed by NASCENTechnoloy, Inc, who collaborated in the design and manufacturing of the planar LTCC flyback converters. The output/volume requirements were targeted to DoD application for hard target/mini fuzing at around 1500 V for reasonable primary peak currents. High voltages could be obtained but with considerable higher current. Work had begun on higher voltage systems and is where this report begins. Limits in material properties and processing capabilities show that the state-of-the-art has limited our practical output voltage from such a small part volume. In other words, the technology is currently limited within the allowable funding and interest.

  7. High voltage stability performance of a gamma ray detection device

    SciTech Connect (OSTI)

    Abdullah, Nor Arymaswati; Lombigit, Lojius; Rahman, Nur Aira Abd [Technical Support Division, Malaysian Nuclear Agency, 43000 Kajang, Selangor (Malaysia)

    2014-02-12T23:59:59.000Z

    An industrial grade digital radiation survey meter device is currently being developed at Malaysian Nuclear Agency. This device used a cylindrical type Geiger Mueller (GM) which acts as a detector. GM detector operates at relatively high direct current voltages depend on the type of GM tube. This thin/thick walled cylindrical type of GM tube operates at 450-650 volts range. Proper value and stability performance of high voltage are important parameters to ensure that this device give a reliable radiation dose measurement. This paper will present an assessment of the stability and performance of the high voltage supply for radiation detector. The assessment is performed using System Identification tools box in MATLAB and mathematical statistics.

  8. Design & Fabrication of a High-Voltage Photovoltaic Cell

    SciTech Connect (OSTI)

    Felder, Jennifer; /North Carolina State U. /SLAC

    2012-09-05T23:59:59.000Z

    Silicon photovoltaic (PV) cells are alternative energy sources that are important in sustainable power generation. Currently, applications of PV cells are limited by the low output voltage and somewhat low efficiency of such devices. In light of this fact, this project investigates the possibility of fabricating high-voltage PV cells on float-zone silicon wafers having output voltages ranging from 50 V to 2000 V. Three designs with different geometries of diffusion layers were simulated and compared in terms of metal coverage, recombination, built-in potential, and conduction current density. One design was then chosen and optimized to be implemented in the final device design. The results of the simulation serve as a feasibility test for the design concept and provide supportive evidence of the effectiveness of silicon PV cells as high-voltage power supplies.

  9. Electronic high voltage generator with a high temperature superconducting coil

    SciTech Connect (OSTI)

    Jin, J.X.; Liu, H.K.; Dou, S.X. [Univ. of Wollongong (Australia)] [and others

    1996-12-31T23:59:59.000Z

    A novel method for generating high voltages from a low voltage DC source, by using a capacitor and inductor in a R, L, C resonant circuit has been developed with the consideration of using a high temperature superconducting (HTS) coil. To generate high voltages the polarity of a low voltage battery source is reversed each half resonant cycle, the control being achieved by an electronic switch. Resistance in the circuit limits the voltages that can be built up. By replacing a copper winding inductor with another inductor which has a HTS winding, the magnitude of achievable voltages is substantially increased. A (Bi,Pb){sub 2}Sr{sub 2}Ca{sub 2}Cu{sub 3}O{sub 10+x} multifilament HTS wire is considered in this work to make the superconducting inductor. The high voltages generated are not capable of supplying low impedance loads, however, possible applications of the generator include electrical partial discharge testing and insulation resistance testing. It could also be used as a testing method for the HTS itself with respect to the critical current and AC loss measurement.

  10. POLYMER PROGRAM SEMINAR "Polymer Nanofibers: Electrospinning, Structure, and Properties"

    E-Print Network [OSTI]

    Alpay, S. Pamir

    POLYMER PROGRAM SEMINAR "Polymer Nanofibers: Electrospinning, Structure, and Properties" Dr. Masaya been widely employed as a technique to produce sub-micron and nanometer scale polymer fibers. The technique utilizes electrical forces induced by a high voltage to draw charged polymer solution jet

  11. Induction of nuclear fission by high-voltage application

    E-Print Network [OSTI]

    Hirokazu Maruyama

    2007-11-20T23:59:59.000Z

    In nuclear power generation, fissile materials are mainly used. For example, $U^{235}$ is fissile and therefore quite essential for use of nuclear energy. However, the material $U^{235}$ has very small natural abundance less than 1 %. We should seek possibility of utilizing fissionable materials such as $U^{238}$ because natural abundance of such fissionable materials is generally much larger than fissile ones. In this paper, we show that thermal neutrons with vanishing kinetic energy can induce nuclear fission when high voltage is applied to fissionable materials. To obtain this result, we use the liquid-drop model for nuclei. Finally, we propose how fissionable materials can be utilized.

  12. Worldwide reliability surveys of high voltage circuit breakers

    SciTech Connect (OSTI)

    Heising, C.R.

    1995-05-01T23:59:59.000Z

    This article reports on the results of two CIGRE 13.06 Working Group worldwide surveys of the reliability of high voltage circuit breakers, 63 kV and above. The first inquiry included 78,000 breaker-years of ``in service data`` from 102 utilities in 22 countries during the years 1974--1977 and included all interrupting technologies. The second inquiry included 70,708 breaker-years from 132 utilities in 22 countries for the years 1988--1991 and only included single-pressure SF6 breakers, because this is what most utilities are now buying. Thirty-one US utilities submitted data.

  13. Self-monitoring high voltage transmission line suspension insulator

    DOE Patents [OSTI]

    Stemler, Gary E. (Vancouver, WA); Scott, Donald N. (Vancouver, WA)

    1981-01-01T23:59:59.000Z

    A high voltage transmission line suspension insulator (18 or 22) which monitors its own dielectric integrity. A dielectric rod (10) has one larger diameter end fitting attachable to a transmission line and another larger diameter end fitting attachable to a support tower. The rod is enclosed in a dielectric tube (14) which is hermetically sealed to the rod's end fittings such that a liquidtight space (20) is formed between the rod and the tube. A pressurized dielectric liquid is placed within that space. A discoloring dye placed within this space is used to detect the loss of the pressurized liquid.

  14. An earth-isolated optically coupled wideband high voltage probe powered by ambient light

    E-Print Network [OSTI]

    Bellan, Paul M.

    An earth-isolated optically coupled wideband high voltage probe powered by ambient light Xiang Zhai) An earth-isolated optically coupled wideband high voltage probe powered by ambient light Xiang Zhaia online 9 October 2012) An earth-isolated optically-coupled wideband high voltage probe has been developed

  15. Use of nafion as a solid polymer electrolyte for the electroreduction of tungsten (VI) fluoride

    SciTech Connect (OSTI)

    Bettelheim, A.; Raven, A.; Polak, M.; Ozer, D. (Nuclear Research Center, Beer-Sheva 84190 (IL))

    1992-01-01T23:59:59.000Z

    In this paper a new method is described in which WF{sub 6} is electroreduced in a solid-state cell configuration with a Nafion membrane serving as a solid polymer electrolyte. Cyclic voltammetry indicates a behavior similar to that of metallic tungsten for coatings obtained at dry conditions and similar to that of tungsten oxide species when water vapor is not totally expelled. Surface analysis using Auger electroscope and x-ray photoelectron spectroscopy shows that solid-state electro-reduction of WF{sub 6} in dry conditions yields coatings free of fluorine, which contain much less oxygen than electrodeposits obtained from aqueous solutions. However, due to possible oxidation and reduction reactions occurring before and during the surface-analysis process, it is not possible at this state to determine the exact content of metallic and oxide species in the deposits obtained by the present method.

  16. An accurate continuous calibration system for high voltage current transformer

    SciTech Connect (OSTI)

    Tong Yue; Li Binhong [College of Electrical and Electronic Engineering, Huazhong University of Science and Technology, Wuhan 430074, Hubei Province (China)

    2011-02-15T23:59:59.000Z

    A continuous calibration system for high voltage current transformers is presented in this paper. The sensor of this system is based on a kind of electronic instrument current transformer, which is a clamp-shape air core coil. This system uses an optical fiber transmission system for its signal transmission and power supply. Finally the digital integrator and fourth-order convolution window algorithm as error calculation methods are realized by the virtual instrument with a personal computer. It is found that this system can calibrate a high voltage current transformer while energized, which means avoiding a long calibrating period in the power system and the loss of power metering expense. At the same time, it has a wide dynamic range and frequency band, and it can achieve a high accuracy measurement in a complex electromagnetic field environment. The experimental results and the on-site operation results presented in the last part of the paper, prove that it can reach the 0.05 accuracy class and is easy to operate on site.

  17. ESS 2012 Peer Review - Low Cost, Manufacturable High Voltage...

    Broader source: Energy.gov (indexed) [DOE]

    Transformer Solid State Transformer 2 Other Targeted Applications Solid State Transformers * Replace passive transformers with power electronic converters to reduce size *...

  18. Laser Transferable Polymer-Ionic Liquid Separator/Electrolytes for Solid-State Rechargeable Lithium-Ion Microbatteries

    E-Print Network [OSTI]

    Arnold, Craig B.

    Laser Transferable Polymer-Ionic Liquid Separator/Electrolytes for Solid-State Rechargeable Lithium-Ion characterized by ac-impedance spectroscopy and in lithium- ion microbatteries. Size and weight percent effects be laser transferred onto a substrate to form a solid separator/electrolyte layer for a lithium ion power

  19. Polymer sphere lithography for solid oxide fuel cells: a route to functional, well-defined electrode structures

    E-Print Network [OSTI]

    Polymer sphere lithography for solid oxide fuel cells: a route to functional, well. Introduction Dramatic breakthroughs in the materials, particularly electrode materials, for solid oxide fuel cells (SOFCs) have been reported in recent years.1­3 Fundamental understanding of the electro- catalytic

  20. Effect of low energy oxygen ion beam irradiation on ionic conductivity of solid polymer electrolyte

    SciTech Connect (OSTI)

    Manjunatha, H., E-mail: gnk-swamy@blr.amrita.edu; Kumaraswamy, G. N., E-mail: gnk-swamy@blr.amrita.edu [Department of Physics, Amrita Vishwa Vidyapeetham, Bengaluru-560035 (India); Damle, R. [Department of Physics, Bangalore University, Bengaluru-560056 (India)

    2014-04-24T23:59:59.000Z

    Over the past three decades, solid polymer electrolytes (SPEs) have drawn significant attention of researchers due to their prospective commercial applications in high energy-density batteries, electrochemical sensors and super-capacitors. The optimum conductivity required for such applications is about 10{sup ?2} – 10{sup ?4} S/cm, which is hard to achieve in these systems. It is known that the increase in the concentration of salt in the host polymer results in a continuous increase in the ionic conductivity. However, there is a critical concentration of the salt beyond which the conductivity decreases due to formation of ion pairs with no net charge. In the present study, an attempt is made to identify the concentration at which ion pair formation occurs in PEO: RbBr. We have attempted to modify microstructure of the host polymer matrix by low energy ion (Oxygen ion, O{sup +1} with energy 100 keV) irradiation. Ionic conductivity measurements in these systems were carried out using Impedance Spectroscopy before and after irradiation to different fluencies of the oxygen ion. It is observed that the conductivity increases by one order in magnitude. The increase in ionic conductivity may be attributed to the enhanced segmental motion of the polymer chains. The study reveals the importance of ion irradiation as an effective tool to enhance conductivity in SPEs.

  1. Understanding and Improving High Voltage Vacuum Insulators for Microsecond Pulses

    SciTech Connect (OSTI)

    Javedani, J B; Goerz, D A; Houck, T L; Lauer, E J; Speer, R D; Tully, L K; Vogtlin, G E; White, A D

    2007-03-05T23:59:59.000Z

    High voltage insulation is one of the main areas of pulsed power research and development, and dielectric breakdown is usually the limiting factor in attaining the highest possible performance in pulsed power devices. For many applications the delivery of pulsed power into a vacuum region is the most critical aspect of operation. The surface of an insulator exposed to vacuum can fail electrically at an applied field more than an order or magnitude below the bulk dielectric strength of the insulator. This mode of breakdown, called surface flashover, imposes serious limitations on the power flow into a vacuum region. This is especially troublesome for applications where high voltage conditioning of the insulator and electrodes is not practical and for applications where relatively long pulses, on the order of several microseconds, are required. The goal of this project is to establish a sound fundamental understanding of the mechanisms that lead to surface flashover, and then evaluate the most promising techniques to improve vacuum insulators and enable high voltage operation at stress levels near the intrinsic bulk breakdown limits of the material. The approach we proposed and followed was to develop this understanding through a combination of theoretical and computation methods coupled with experiments to validate and quantify expected behaviors. In this report we summarize our modeling and simulation efforts, theoretical studies, and experimental investigations. The computational work began by exploring the limits of commercially available codes and demonstrating methods to examine field enhancements and defect mechanisms at microscopic levels. Plasma simulations with particle codes used in conjunction with circuit models of the experimental apparatus enabled comparisons with experimental measurements. The large scale plasma (LSP) particle-in-cell (PIC) code was run on multiprocessor platforms and used to simulate expanding plasma conditions in vacuum gap regions. Algorithms were incorporated into LSP to handle secondary electron emission from dielectric materials to enable detailed simulations of flashover phenomenon. Theoretical studies were focused on explaining a possible mechanism for anode initiated surface flashover that involves an electron avalanche process starting near the anode, not a mechanism involving bulk dielectric breakdown. Experiments were performed in Engineering's Pulsed Power Lab using an available 100-kV, 10-{micro}s pulse generator and vacuum chamber. The initial experiments were done with polyethylene insulator material in the shape of a truncated cone cut at +45{sup o} angle between flat electrodes with a gap of 1.0 cm. The insulator was sized so there were no flashovers or breakdowns under nominal operating conditions. Insulator flashover or gap closure was induced by introducing a plasma source, a tuft of velvet, in proximity to the insulator or electrode.

  2. A high voltage pulsed power supply for capillary discharge waveguide applications

    SciTech Connect (OSTI)

    Abuazoum, S.; Wiggins, S. M.; Issac, R. C.; Welsh, G. H.; Vieux, G.; Jaroszynski, D. A. [Department of Physics, Scottish Universities Physics Alliance, University of Strathclyde, Glasgow G4 0NG (United Kingdom); Ganciu, M. [Low Temperature Plasma Department, National Institute of Lasers, Plasma and Radiation Physics, 077125, Magurele, Bucharest (Romania)

    2011-06-15T23:59:59.000Z

    We present an all solid-state, high voltage pulsed power supply for inducing stable plasma formation (density {approx}10{sup 18} cm{sup -3}) in gas-filled capillary discharge waveguides. The pulser (pulse duration of 1 {mu}s) is based on transistor switching and wound transmission line transformer technology. For a capillary of length 40 mm and diameter 265 {mu}m and gas backing pressure of 100 mbar, a fast voltage pulse risetime of 95 ns initiates breakdown at 13 kV along the capillary. A peak current of {approx}280 A indicates near complete ionization, and the r.m.s. temporal jitter in the current pulse is only 4 ns. Temporally stable plasma formation is crucial for deploying capillary waveguides as plasma channels in laser-plasma interaction experiments, such as the laser wakefield accelerator.

  3. (Insulating materials and large high voltage electric systems)

    SciTech Connect (OSTI)

    Dale, S.J.

    1990-09-18T23:59:59.000Z

    The traveler attended the 33rd Session of CIGRE (The International Conference on Large High Voltage Electric Systems in Paris, France) as a US technical expert advisor the Study Committee 15, Insulating Materials. Over 200 papers were discussed, contributed from over 45 countries at the conference on all aspects of electric power generation and transmission. Of special interest was a panel session on superconducting technology for electric power systems and the participation on a new task force on the electrical insulation at cryogenic temperatures. Significant insight was gained into the development of superconducting power technologies in Europe and Japan. CIGRE has set up a committee to follow the development in research on the biological effects of electric and magnetic fields. The traveler also visited the Centre for Electric Power Engineering at the University of Strathclyde, Glasgow, Scotland and discussed research on degradation of polymeric cable insulation and gas insulated equipment. 5 refs.

  4. DIII-D ICRF high voltage power supply regulator upgrade

    SciTech Connect (OSTI)

    Cary, W.P.; Burley, B.L.; Grosnickle, W.H.

    1997-11-01T23:59:59.000Z

    For reliable operation and component protection, of the 2 MW 30--120 MHz ICRF Amplifier System on DIII-D, it is desirable for the amplifier to respond to high VSWR conditions as rapidly as possible. This requires a rapid change in power which also means a rapid change in the high voltage power supply current demands. An analysis of the power supply`s regulator dynamics was needed to verify its expected operation during such conditions. Based on this information it was found that a new regulator with a larger dynamic range and some anticipation capability would be required. This paper will discuss the system requirements, the as-delivered regulator performance, and the improved performance after installation of the new regulator system. It will also be shown how this improvement has made the amplifier perform at higher power levels more reliably.

  5. Planar LTCC transformers for high voltage flyback converters.

    SciTech Connect (OSTI)

    Schofield, Daryl (NASCENT Technology Inc. , Watertown, SD); Schare, Joshua M.; Glass, Sarah Jill; Roesler, Alexander William; Ewsuk, Kevin Gregory; Slama, George (NASCENT Technology Inc. , Watertown, SD); Abel, Dave (NASCENT Technology Inc. , Watertown, SD)

    2007-06-01T23:59:59.000Z

    This paper discusses the design and use of low-temperature (850 C to 950 C) co-fired ceramic (LTCC) planar magnetic flyback transformers for applications that require conversion of a low voltage to high voltage (> 100V) with significant volumetric constraints. Measured performance and modeling results for multiple designs showed that the LTCC flyback transformer design and construction imposes serious limitations on the achievable coupling and significantly impacts the transformer performance and output voltage. This paper discusses the impact of various design factors that can provide improved performance by increasing transformer coupling and output voltage. The experiments performed on prototype units demonstrated LTCC transformer designs capable of greater than 2 kV output. Finally, the work investigated the effect of the LTCC microstructure on transformer insulation. Although this paper focuses on generating voltages in the kV range, the experimental characterization and discussion presented in this work applies to designs requiring lower voltage.

  6. Effect of high-voltage nanosecond pulses on complex plasmas

    SciTech Connect (OSTI)

    Pustylnik, M. Y.; Ivlev, A. V.; Thomas, H. M.; Morfill, G. E. [Max-Planck-Institut fuer Extraterrestrische Physik, Giessenbachstrasse, 85741 Garching (Germany); Vasilyak, L. M.; Vetchinin, S. P.; Polyakov, D. N.; Fortov, V. E. [Joint Institute for High Temperatures, Russian Academy of Sciences, Izhorskaya 13/19, 125412 Moscow (Russian Federation)

    2009-11-15T23:59:59.000Z

    Influence of high-voltage (1-11 kV) pulses of nanosecond (20 ns) duration on microparticles levitating in a rf plasma is studied. It is shown that the pulses produce significant influence on the plasma, causing perturbations with the relaxation time of the order of 10{sup -4} s. This time is sufficient for the microparticle to acquire significant kinetic energy. Application of repetitive pulses leads to the vertical oscillations of the microparticles. Clusters, consisting of small number of microparticles, exhibit parametric instabilities of horizontal modes under the effect of repetitive pulses. It was shown that the parametric instability is caused by the vertical oscillations of the microparticles in the nonuniform environment of the sheath.

  7. E-beam high voltage switching power supply

    DOE Patents [OSTI]

    Shimer, D.W.; Lange, A.C.

    1996-10-15T23:59:59.000Z

    A high-power power supply produces a controllable, constant high voltage output under varying and arcing loads. The power supply includes a voltage regulator, an inductor, an inverter for producing a high frequency square wave current of alternating polarity, an improved inverter voltage clamping circuit, a step up transformer, an output rectifier for producing a dc voltage at the output of each module, and a current sensor for sensing output current. The power supply also provides dynamic response to varying loads by controlling the voltage regulator duty cycle and circuitry is provided for sensing incipient arc currents at the output of the power supply to simultaneously decouple the power supply circuitry from the arcing load. The power supply includes a plurality of discrete switching type dc--dc converter modules. 5 figs.

  8. E-beam high voltage switching power supply

    DOE Patents [OSTI]

    Shimer, Daniel W. (Danville, CA); Lange, Arnold C. (Livermore, CA)

    1996-01-01T23:59:59.000Z

    A high-power power supply produces a controllable, constant high voltage put under varying and arcing loads. The power supply includes a voltage regulator, an inductor, an inverter for producing a high frequency square wave current of alternating polarity, an improved inverter voltage clamping circuit, a step up transformer, an output rectifier for producing a dc voltage at the output of each module, and a current sensor for sensing output current. The power supply also provides dynamic response to varying loads by controlling the voltage regulator duty cycle and circuitry is provided for sensing incipient arc currents at the output of the power supply to simultaneously decouple the power supply circuitry from the arcing load. The power supply includes a plurality of discrete switching type dc--dc converter modules.

  9. Summary of multiterminal high-voltage direct current transmission technology

    SciTech Connect (OSTI)

    Biggs, R.B.; Jewell, W.T.

    1984-05-01T23:59:59.000Z

    This report summarizes the present state of multiterminal (MT) high-voltage direct current (HVDC) power transmission. The purpose is to reassess the need for HVDC circuit breakers and to identify needed research for MT HVDC. The fundamentals of this technology are presented, and previous research and development is reviewed. Although no MT HVDC systems have yet been built, many concepts have been proposed. Some require a dc breaker, and others do not. Both options have advantages and disadvantages for various applications, so the selection will depend on the proposed application. Research is needed to define operating characteristics of various MT HVDC systems. In some applications, dc breakers will be useful, so research into HVDC interruption should continue. Also, dc fault detection and control algorithms for MT systems should be studied.

  10. Long-cycle-life solid-state solid-polymer electrolyte cells. Final report. Report on Phase 1

    SciTech Connect (OSTI)

    Sammells, A.F.; Semkow, K.W.; Cook, R.L.

    1986-07-01T23:59:59.000Z

    Experimental work was directed toward determining the viability of two complementary solid-state electrochemical cells incorporating Na/sup +/ and Li/sup +/ conducting solid polymer electrolytes (SPE). SPEs used included those based upon poly(ethylene oxide), poly(ethylene oxide)/poly(ethylene glycol) mixtures, and polyphosphazenes. For Li/sup +/ conducting SPEs, LixWO/sub 2/ was used for the negative and TiS/sub 2/ for the positive electrode. In cells utilizing Na+ conducting SPEs, homogeneous matrix electrodes based upon transition-metal-doped B'-alumina were used for the positive and negative electrodes. Here transition metals were incorporated into immobile A1/sup 3 +/ lattice sites within the B'-alumina structure, where changed in electrochemical potential upon cell charge/discharge cycling occurred via redox electrochemistry involving the doped immobile transition-metal species. Secondary cells were found to have respective open-circuit potentials of 2.2 and 1.5V, high electrochemical reversibility, and theoretical energy densities of 175 and 178 Wh/kg.

  11. Anion exchange polymer electrolytes

    DOE Patents [OSTI]

    Kim, Yu Seung; Kim, Dae Sik

    2013-09-10T23:59:59.000Z

    Solid anion exchange polymer electrolytes include chemical compounds comprising a polymer backbone with side chains that include guanidinium cations.

  12. High voltage electrical amplifier having a short rise time

    DOE Patents [OSTI]

    Christie, David J. (Pleasanton, CA); Dallum, Gregory E. (Livermore, CA)

    1991-01-01T23:59:59.000Z

    A circuit, comprising an amplifier and a transformer is disclosed that produces a high power pulse having a fast response time, and that responds to a digital control signal applied through a digital-to-analog converter. The present invention is suitable for driving a component such as an electro-optic modulator with a voltage in the kilovolt range. The circuit is stable at high frequencies and during pulse transients, and its impedance matching circuit matches the load impedance with the output impedance. The preferred embodiment comprises an input stage compatible with high-speed semiconductor components for amplifying the voltage of the input control signal, a buffer for isolating the input stage from the output stage; and a plurality of current amplifiers connected to the buffer. Each current amplifier is connected to a field effect transistor (FET), which switches a high voltage power supply to a transformer which then provides an output terminal for driving a load. The transformer comprises a plurality of transmission lines connected to the FETs and the load. The transformer changes the impedance and voltage of the output. The preferred embodiment also comprises a low voltage power supply for biasing the FETs at or near an operational voltage.

  13. Fiber optic current monitor for high-voltage applications

    DOE Patents [OSTI]

    Renda, G.F.

    1992-04-21T23:59:59.000Z

    A current monitor which derives its power from the conductor being measured for bidirectionally measuring the magnitude of current (from DC to above 50 khz) flowing through a conductor across which a relatively high level DC voltage is applied, includes a pair of identical transmitter modules connected in opposite polarity to one another in series with the conductor being monitored, for producing from one module a first light signal having an intensity directly proportional to the magnitude of current flowing in one direction through the conductor during one period of time, and from the other module a second light signal having an intensity directly proportional to the magnitude of current flowing in the opposite direction through the conductor during another period of time, and a receiver located in a safe area remote from the high voltage area for receiving the first and second light signals, and converting the same to first and second voltage signals having levels indicative of the magnitude of current being measured at a given time. 6 figs.

  14. Advanced Gate Drive for the SNS High Voltage Converter Modulator

    SciTech Connect (OSTI)

    Nguyen, M.N.; Burkhart, C.; Kemp, M.A.; /SLAC; Anderson, D.E.; /Oak Ridge

    2009-05-07T23:59:59.000Z

    SLAC National Accelerator Laboratory is developing a next generation H-bridge switch plate [1], a critical component of the SNS High Voltage Converter Modulator [2]. As part of that effort, a new IGBT gate driver has been developed. The drivers are an integral part of the switch plate, which are essential to ensuring fault-tolerant, high-performance operation of the modulator. The redesigned driver improves upon the existing gate drive in several ways. The new gate driver has improved fault detection and suppression capabilities; suppression of shoot-through and over-voltage conditions, monitoring of dI/dt and Vce(sat) for fast over-current detection and suppression, and redundant power isolation are some of the added features. In addition, triggering insertion delay is reduced by a factor of four compared to the existing driver. This paper details the design and performance of the new IGBT gate driver. A simplified schematic and description of the construction are included. The operation of the fast over-current detection circuits, active IGBT over-voltage protection circuit, shoot-through prevention circuitry, and control power isolation breakdown detection circuit are discussed.

  15. High voltage power supply with modular series resonant inverters

    DOE Patents [OSTI]

    Dreifuerst, G.R.; Merritt, B.T.

    1995-07-18T23:59:59.000Z

    A relatively small and compact high voltage, high current power supply for a laser utilizes a plurality of modules containing series resonant half bridge inverters. A pair of reverse conducting thyristors are incorporated in each series resonant inverter module such that the series resonant inverter modules are sequentially activated in phases 360{degree}/n apart, where n=number of modules for n>2. Selective activation of the modules allows precise output control reducing ripple and improving efficiency. Each series resonant half bridge inverter module includes a transformer which has a cooling manifold for actively circulating a coolant such as water, to cool the transformer core as well as selected circuit elements. Conductors connecting and forming various circuit components comprise hollow, electrically conductive tubes such as copper. Coolant circulates through the tubes to remove heat. The conductive tubes act as electrically conductive lines for connecting various components of the power supply. Where it is desired to make electrical isolation breaks, tubes comprised of insulating material such as nylon are used to provide insulation and continue the fluid circuit. 11 figs.

  16. High voltage power supply with modular series resonant inverters

    DOE Patents [OSTI]

    Dreifuerst, Gary R. (Livermore, CA); Merritt, Bernard T. (Livermore, CA)

    1995-01-01T23:59:59.000Z

    A relatively small and compact high voltage, high current power supply for a laser utilizes a plurality of modules containing series resonant half bridge inverters. A pair of reverse conducting thyristors are incorporated in each series resonant inverter module such that the series resonant inverter modules are sequentially activated in phases 360.degree./n apart, where n=number of modules for n>2. Selective activation of the modules allows precise output control reducing ripple and improving efficiency. Each series resonant half bridge inverter module includes a transformer which has a cooling manifold for actively circulating a coolant such as water, to cool the transformer core as well as selected circuit elements. Conductors connecting and forming various circuit components comprise hollow, electrically conductive tubes such as copper. Coolant circulates through the tubes to remove heat. The conductive tubes act as electrically conductive lines for connecting various components of the power supply. Where it is desired to make electrical isolation breaks, tubes comprised of insulating material such as nylon are used to provide insulation and continue the fluid circuit.

  17. activated si-gaas high-voltage: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: ??This thesis is concerned with developing a new approach to high voltage transformers condition monitoring, which involve partial discharge (PD) measurement and...

  18. Solvent-washable polymer templated synthesis of mesoporous materials and solid-acid nanocatalysts in one-potw

    E-Print Network [OSTI]

    Schiff, Eric A.

    Solvent-washable polymer templated synthesis of mesoporous materials and solid-acid nanocatalysts the inorganic material, surfactant template, and synthetic conditions employed, mesoporous materials with widely mesoporous material.3 The synthesis of well-ordered mesoporous structures requires an extraction step

  19. Electrode assembly for use in a solid polymer electrolyte fuel cell

    DOE Patents [OSTI]

    Raistrick, Ian D. (Los Alamos, NM)

    1989-01-01T23:59:59.000Z

    A gas reaction fuel cell may be provided with a solid polymer electrolyte membrane. Porous gas diffusion electrodes are formed of carbon particles supporting a catalyst which is effective to enhance the gas reactions. The carbon particles define interstitial spaces exposing the catalyst on a large surface area of the carbon particles. A proton conducting material, such as a perfluorocarbon copolymer or ruthenium dioxide contacts the surface areas of the carbon particles adjacent the interstitial spaces. The proton conducting material enables protons produced by the gas reactions adjacent the supported catalyst to have a conductive path with the electrolyte membrane. The carbon particles provide a conductive path for electrons. A suitable electrode may be formed by dispersing a solution containing a proton conducting material over the surface of the electrode in a manner effective to coat carbon surfaces adjacent the interstitial spaces without impeding gas flow into the interstitial spaces.

  20. Solid polymer electrolyte electrochemical storage cell containing a redox shuttle additive for overcharge protection

    DOE Patents [OSTI]

    Richardson, Thomas J. (Oakland, CA); Ross, Philip N. (Moraga, CA)

    1999-01-01T23:59:59.000Z

    A class of organic redox shuttle additives is described, preferably comprising nitrogen-containing aromatics compounds, which can be used in a high temperature (85.degree. C. or higher) electrochemical storage cell comprising a positive electrode, a negative electrode, and a solid polymer electrolyte to provide overcharge protection to the cell. The organic redox additives or shuttles are characterized by a high diffusion coefficient of at least 2.1.times.10.sup.-8 cm.sup.2 /second and a high onset potential of 2.5 volts or higher. Examples of such organic redox shuttle additives include an alkali metal salt of 1,2,4-triazole, an alkali metal salt of imidazole, 2,3,5,6-tetramethylpyrazine, 1,3,5-tricyanobenzene, and a dialkali metal salt of 3-4-dihydroxy-3-cyclobutene-1,2-dione.

  1. Chapter 19. High Voltage Insulation, Diagnostics and Energetic Electron and Photon Beam Interactions

    E-Print Network [OSTI]

    Chapter 19. High Voltage Insulation, Diagnostics and Energetic Electron and Photon Beam Interactions 19-1 High Voltage Insulation, Diagnostics and Energetic Electron and Photon Beam Interactions 1. DC Properties of Modern Filled Epoxy Insulation Academic and Research Staff Dr. Chathan Cooke Sponsor

  2. High voltage transformers. (Latest citations from the Inspec database). NewSearch

    SciTech Connect (OSTI)

    Not Available

    1994-11-01T23:59:59.000Z

    The bibliography contains citations concerning materials and performance of insulators used for high voltage transformers. Topics examine use of mica-fibers, gases, mica filled epoxies, and ceramics. Effects of insulation aging are reviewed, and acceptance testing of high voltage power transformers and apparatus is also examined. (Contains a minimum of 104 citations and includes a subject term index and title list.)

  3. High voltage transformers. (Latest citations from the US Patent bibliographic file with exemplary claims). Published Search

    SciTech Connect (OSTI)

    NONE

    1996-08-01T23:59:59.000Z

    The bibliography contains citations of selected patents concerning high voltage transformers. Included are hybrid, video, rectifier, x-ray diagnostic generator, temperature control system, and printed circuit wound high voltage transformers. The fabrication, assembly, and testing of these transformers are also presented. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  4. High voltage transformers. (Latest citations from the US Patent bibliographic file with exemplary claims). Published Search

    SciTech Connect (OSTI)

    NONE

    1995-07-01T23:59:59.000Z

    The bibliography contains citations of selected patents concerning high voltage transformers. Included are hybrid, video, rectifier, x-ray diagnostic generator, temperature control system, and printed circuit wound high voltage transformers. The fabrication, assembly, and testing of these transformers are also presented. (Contains 50-250 citations and includes a subject term index and title list.)

  5. Distributed Voltage and Current Control of Multi-Terminal High-Voltage Direct

    E-Print Network [OSTI]

    Dimarogonas, Dimos

    }@kth.se.) Abstract: High-voltage direct current (HVDC) is a commonly used technology for long-distance power for multi-terminal HVDC (MTDC) systems is proposed. Under certain conditions on the controller gains factor behind long-distance power transmission. High-voltage direct current (HVDC) is a commonly used

  6. Understanding the grafting of telechelic polymers on a solid substrate to form loops

    SciTech Connect (OSTI)

    Huang, Zhenyu [University of Tennessee, Knoxville (UTK); Ji, Haining [ORNL; Mays, Jimmy [ORNL; Dadmun, Mark D [ORNL

    2008-01-01T23:59:59.000Z

    Recent experimental and theoretical studies have demonstrated that relative to singly tethered chains, the presence of polymer loops at interfaces significantly improves interfacial properties such as adhesion, friction, and wettability. In the present study, a simple system was studied to examine the formation of polymeric loops on a solid surface, where the grafting of carboxylic acid terminated telechelic polystyrene from the melt to an epoxy functionalized silicon is chosen. The impact of telechelic molecular weight, grafting temperature, and surface functionality on the telechelic attachment process is studied. It was found that grafting of the telechelic to the surface at both ends to form loops is the primary product of this grafting process. Moreover, examination of the kinetics of the grafting process indicates that it is reaction controlled. Fluorescence tagging of the dangling ends of singly bound chains provides a mechanism to monitor their time evolution during grafting, and these results indicate that the grafting process is accurately described by recent Monte Carlo simulation work. The results also provide a method to control the extent of loop formation at interfaces and therefore provide an opportunity to further understand the role of the loops in the interfacial properties in multicomponent polymer systems.

  7. Preparation and characterization of plasticized palm-based polyurethane solid polymer electrolyte

    SciTech Connect (OSTI)

    Daud, Farah Nadia; Ahmad, Azizan; Badri, Khairiah Haji [School of Chemical Science and Food Technology, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 UKM Bangi, Selangor Darul Ehsan (Malaysia)

    2013-11-27T23:59:59.000Z

    Palm-based polyurethane solid polymer electrolyte was prepared via prepolymerization method between palm kernel oil based polyols (PKO-p) and 2,4’-diphenylmethane diisocyanate (2,4’-MDI) in acetone at room temperature with the vary amount of lithium trifuoromethanesulfonate (LiCF{sub 3}SO{sub 3}) salt and polyethylene glycol (PEG). The film was analyzed using attenuated total reflection infrared (ATR-IR) spectroscopy, electrochemical impedance spectroscopy (EIS) and X-ray diffractometry (XRD). EIS result indicated ionic conductivity obtained with 30 wt% LiCF3SO3 increased to 6.55 × 10{sup ?6} S cm{sup ?1} when 10 wt.% of plasticizer was added into the system. FTIR analysis showed the interaction between lithium ions and amine (-N-H) at 3600–3100 cm{sup ?1}, carbonyl (-C=O) at 1750–1650 cm{sup ?1} and ether (-C-O-C-) at 1150–1000 cm{sup ?1} of the polyurethane forming polymer-salt complexes. The XRD result confirmed that LiCF{sub 3}SO{sub 3} salt completely dissociated within the polyurethane film with the absence of crystalline peaks of LiCF{sub 3}SO{sub 3}.

  8. Radio-frequency powered glow discharge device and method with high voltage interface

    DOE Patents [OSTI]

    Duckworth, Douglas C. (Knoxville, TN); Marcus, R. Kenneth (Clemson, SC); Donohue, David L. (Vienna, AT); Lewis, Trousdale A. (Oak Ridge, TN)

    1994-01-01T23:59:59.000Z

    A high voltage accelerating potential, which is supplied by a high voltage direct current power supply, is applied to the electrically conducting interior wall of an RF powered glow discharge cell. The RF power supply desirably is electrically grounded, and the conductor carrying the RF power to the sample held by the probe is desirably shielded completely excepting only the conductor's terminal point of contact with the sample. The high voltage DC accelerating potential is not supplied to the sample. A high voltage capacitance is electrically connected in series between the sample on the one hand and the RF power supply and an impedance matching network on the other hand. The high voltage capacitance isolates the high DC voltage from the RF electronics, while the RF potential is passed across the high voltage capacitance to the plasma. An inductor protects at least the RF power supply, and desirably the impedance matching network as well, from a short that might occur across the high voltage capacitance. The discharge cell and the probe which holds the sample are configured and disposed to prevent the probe's components, which are maintained at ground potential, from bridging between the relatively low vacuum region in communication with the glow discharge maintained within the cell on the one hand, and the relatively high vacuum region surrounding the probe and cell on the other hand. The probe and cell also are configured and disposed to prevent the probe's components from electrically shorting the cell's components.

  9. Radio-frequency powered glow discharge device and method with high voltage interface

    DOE Patents [OSTI]

    Duckworth, D.C.; Marcus, R.K.; Donohue, D.L.; Lewis, T.A.

    1994-06-28T23:59:59.000Z

    A high voltage accelerating potential, which is supplied by a high voltage direct current power supply, is applied to the electrically conducting interior wall of an RF powered glow discharge cell. The RF power supply desirably is electrically grounded, and the conductor carrying the RF power to the sample held by the probe is desirably shielded completely excepting only the conductor's terminal point of contact with the sample. The high voltage DC accelerating potential is not supplied to the sample. A high voltage capacitance is electrically connected in series between the sample on the one hand and the RF power supply and an impedance matching network on the other hand. The high voltage capacitance isolates the high DC voltage from the RF electronics, while the RF potential is passed across the high voltage capacitance to the plasma. An inductor protects at least the RF power supply, and desirably the impedance matching network as well, from a short that might occur across the high voltage capacitance. The discharge cell and the probe which holds the sample are configured and disposed to prevent the probe's components, which are maintained at ground potential, from bridging between the relatively low vacuum region in communication with the glow discharge maintained within the cell on the one hand, and the relatively high vacuum region surrounding the probe and cell on the other hand. The probe and cell also are configured and disposed to prevent the probe's components from electrically shorting the cell's components. 11 figures.

  10. High Power, High Voltage FETs in Linear Applications: A User's Perspective

    SciTech Connect (OSTI)

    N. Greenough, E. Fredd, S. DePasquale

    2009-09-21T23:59:59.000Z

    The specifications of the current crop of highpower, high-voltage field-effect transistors (FETs) can lure a designer into employing them in high-voltage DC equipment. Devices with extremely low on-resistance and very high power ratings are available from several manufacturers. However, our experience shows that high-voltage, linear operation of these devices at near-continuous duty can present difficult reliability challenges at stress levels well-below their published specifications. This paper chronicles the design evolution of a 600 volt, 8 ampere shunt regulator for use with megawatt-class radio transmitters, and presents a final design that has met its reliability criteria.

  11. High-voltage crowbar protection for the large CDF axial drift chamber

    SciTech Connect (OSTI)

    Binkley, M.; Mukherjee, A.; Stuermer, W.; Wagner, R.L.; /Fermilab

    2004-01-01T23:59:59.000Z

    The Central Outer Tracker (COT) is a big cylindrical drift chamber that provides charged particle tracking for the Collider Detector at Fermilab experiment. To protect the COT, the large stored energy in the high voltage system needs to be removed quickly when a problem is sensed. For the high voltage switch, a special-order silicon-controlled-rectifier was chosen over more readily available integrated gate bipolar transistors because of layout and reliability questions. The considerations concerning the high voltage switch, the prototype performance, and the experience of more than two years of running are described.

  12. An Annotated Bibliography of High-Voltage Direct-Current Transmission and Flexible AC Transmission (FACTS) Devices, 1991-1993.

    SciTech Connect (OSTI)

    Litzenberger, Wayne; Lava, Val

    1994-08-01T23:59:59.000Z

    References are contained for HVDC systems, converter stations and components, overhead transmission lines, cable transmission, system design and operations, simulation of high voltage direct current systems, high-voltage direct current installations, and flexible AC transmission system (FACTS).

  13. Vehicle Technologies Office Merit Review 2015: High-Voltage, High-Capacity Polyanion Cathodes

    Broader source: Energy.gov [DOE]

    Presentation given by U of Texas at Austin at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high-voltage, high...

  14. High voltage repetitive pulsed nanosecond discharges as a selective source of reactive species

    E-Print Network [OSTI]

    Guerra García, Carmen

    2011-01-01T23:59:59.000Z

    High voltage nanosecond duration discharges can be used in a repetitive manner to create a sustained pool of short lived excited species and ions and long-lived radicals in a gas. Although the suitability of the Repetitive ...

  15. 130kV 130A High Voltage Switching Mode Power Supply for Neutral Injections – Control Issues and Algorithms

    E-Print Network [OSTI]

    130kV 130A High Voltage Switching Mode Power Supply for Neutral Injections – Control Issues and Algorithms

  16. Princeton Power Systems (TRL 5 6 Component)- Marine High-Voltage Power Conditioning and Transmission System with Integrated Energy Storage

    Broader source: Energy.gov [DOE]

    Princeton Power Systems (TRL 5 6 Component) - Marine High-Voltage Power Conditioning and Transmission System with Integrated Energy Storage

  17. High voltage transformers. (Latest citations from the INSPEC database). Published Search

    SciTech Connect (OSTI)

    NONE

    1996-02-01T23:59:59.000Z

    The bibliography contains citations concerning materials and performance of insulators used for high voltage transformers. Topics examine use of mica-fibers, gases, mica filled epoxies, and ceramics. Effects of insulation aging are reviewed, and acceptance testing of high voltage power transformers and apparatus is also examined. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  18. High voltage transformers. (Latest citations from the INSPEC database). Published Search

    SciTech Connect (OSTI)

    NONE

    1997-05-01T23:59:59.000Z

    The bibliography contains citations concerning materials and performance of insulators used for high voltage transformers. Topics examine use of mica-fibers, gases, mica filled epoxies, and ceramics. Effects of insulation aging are reviewed, and acceptance testing of high voltage power transformers and apparatus is also examined.(Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  19. Cermet insert high voltage holdoff improvement for ceramic/metal vacuum devices

    DOE Patents [OSTI]

    Ierna, W.F.

    1986-03-11T23:59:59.000Z

    An improved metal-to-ceramic seal is provided wherein the ceramic body of the seal contains an integral region of cermet material in electrical contact with the metallic member, e.g., an electrode, of the seal. The seal is useful in high voltage vacuum devices, e.g., vacuum switches, and increases the high-voltage holdoff capabilities of such devices. A method of fabricating such seals is also provided.

  20. Cermet insert high voltage holdoff for ceramic/metal vacuum devices

    DOE Patents [OSTI]

    Ierna, William F. (Seminole, FL)

    1987-01-01T23:59:59.000Z

    An improved metal-to-ceramic seal is provided wherein the ceramic body of the seal contains an integral region of cermet material in electrical contact with the metallic member, e.g., an electrode, of the seal. The seal is useful in high voltage vacuum devices, e.g., vacuum switches, and increases the high-voltage holdoff capabilities of such devices. A method of fabricating such seals is also provided.

  1. High-temperature steam-treatment of PBI, PEEK, and PEKK polymers with H2O and D2O: A solid-state NMR study

    E-Print Network [OSTI]

    Bluemel, Janet

    High-temperature steam-treatment of PBI, PEEK, and PEKK polymers with H2O and D2O: A solid 2014 Keywords: Steam-treatment of PBI, PEEK, PEKK Solid-state NMR Water and D2O uptake polymers a b with D2O steam at temperatures of 150 and 315 C. All samples are studied by TGA, IR, 13 C CP/MAS, 1 H

  2. Decoupling Ionic Conductivity from Structural Relaxation: A Way to Solid Polymer Electrolytes?

    SciTech Connect (OSTI)

    Agapov, Alexander L [ORNL; Sokolov, Alexei P [ORNL

    2011-01-01T23:59:59.000Z

    Using broadband dielectric spectroscopy, we studied the temperature dependence of ionic conductivity and structural relaxation in a number of polymers. We demonstrate that temperature dependence of ionic conductivity can be decoupled from structural relaxation in a material specific way. We show that the strength of the decoupling correlates with the steepness of the temperature dependence of structural relaxation in the polymer, i.e., with its fragility. We ascribe the observed result to stronger frustration in chain packing characteristic for more fragile polymers. We speculate that employment of more fragile polymers might lead to design of polymers with higher ionic conductivity.

  3. TiN coated aluminum electrodes for DC high voltage electron guns

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mamun, Md Abdullah A.; Elmustafa, Abdelmageed A.; Taus, Rhys; Forman, Eric; Poelker, Matthew

    2015-05-01T23:59:59.000Z

    Preparing electrodes made of metals like stainless steel, for use inside DC high voltage electron guns, is a labor-intensive and time-consuming process. In this paper, the authors report the exceptional high voltage performance of aluminum electrodes coated with hard titanium nitride (TiN). The aluminum electrodes were comparatively easy to manufacture and required only hours of mechanical polishing using silicon carbide paper, prior to coating with TiN by a commercial vendor. The high voltage performance of three TiN-coated aluminum electrodes, before and after gas conditioning with helium, was compared to that of bare aluminum electrodes, and electrodes manufactured from titanium alloymore »(Ti-6Al-4V). Following gas conditioning, each TiN-coated aluminum electrode reached ?225?kV bias voltage while generating less than 100?pA of field emission (« less

  4. Packaging of solid state devices

    DOE Patents [OSTI]

    Glidden, Steven C.; Sanders, Howard D.

    2006-01-03T23:59:59.000Z

    A package for one or more solid state devices in a single module that allows for operation at high voltage, high current, or both high voltage and high current. Low thermal resistance between the solid state devices and an exterior of the package and matched coefficient of thermal expansion between the solid state devices and the materials used in packaging enables high power operation. The solid state devices are soldered between two layers of ceramic with metal traces that interconnect the devices and external contacts. This approach provides a simple method for assembling and encapsulating high power solid state devices.

  5. Method and apparatus for connecting high voltage leads to a high temperature super-conducting transformer

    SciTech Connect (OSTI)

    Golner, Thomas M.; Mehta, Shirish P.

    2005-07-26T23:59:59.000Z

    A method and apparatus for connecting high voltage leads to a super-conducting transformer is provided that includes a first super-conducting coil set, a second super-conducting coil set, and a third super-conducting coil set. The first, second and third super-conducting coil sets are connected via an insulated interconnect system that includes insulated conductors and insulated connectors that are utilized to connect the first, second, and third super-conducting coil sets to the high voltage leads.

  6. Design and development of a cooling device for solid polymer electrolyte fuel cells 

    E-Print Network [OSTI]

    Nandi, Asis

    1991-01-01T23:59:59.000Z

    cell (PAFC), (iv) molten carbonate I'uel cell (AICFC j, and (vj solid oxide fuel cell (SOFC). One of the most promising, in respect to achieving the high energy efficiencies and the high power densities. uses a, solid polyiner electrolyte. The solid...

  7. Effects of electrode compression on the performance of a solid polymer electrolyte fuel cell

    E-Print Network [OSTI]

    Del Campo, Christopher Scott

    1997-01-01T23:59:59.000Z

    The effects of electrode compression on the performance of a polymer electrolyte fuel cell (PEFC) were investigated. Preliminary testing showed that considerable compression of the carbon cloth electrodes was provided by the PEFC structure. Further...

  8. Realizing high-voltage thin film lateral bipolar transistors on SOI with a collector-tub

    E-Print Network [OSTI]

    Kumar, M. Jagadesh

    Realizing high-voltage thin film lateral bipolar transistors on SOI with a collector-tub Sukhendu-dimensional device simulation to examine the effect of a collector tub on the collector breakdown of the SOI based BJTs. This method involves creating a collector tub by etching the buried oxide followed by an n

  9. STRUCTURAL HEALTH MONITORING OF HIGH VOLTAGE ELECTRICAL SWITCH CERAMIC INSULATORS IN SEISMIC AREAS

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    STRUCTURAL HEALTH MONITORING OF HIGH VOLTAGE ELECTRICAL SWITCH CERAMIC INSULATORS IN SEISMIC AREAS damage. 7th European Workshop on Structural Health Monitoring July 8-11, 2014. La Cité, Nantes, France European Workshop on Structural Health Monitoring (2014)" #12;(a) (b) Figure 1 : a) Elect

  10. Public Opinions of Building Additional High-Voltage Electric Power Lines

    E-Print Network [OSTI]

    Tesfatsion, Leigh

    Public Opinions of Building Additional High-Voltage Electric Power Lines A Report to the National-Voltage Electric Power Lines: A Report to the National Science Foundation and the Electric Power Research Center to build new power lines. Residents living in counties with planned routes for new transmission lines

  11. The powerful high-voltage glow discharge electron gun and power unit on its base

    SciTech Connect (OSTI)

    Chernov, V.A. [All-Russian Electrotechnical Institute, Moscow (Russian Federation)

    1994-12-31T23:59:59.000Z

    The technical and operational characteristics and features of powerful electron gun with cold cathodes on the basis of high-voltage glow discharge (HGD) are submitted. The systems, ensuring their work are described. Some results of operation and applications of these non-traditional electron guns are presented.

  12. A Charge Pump that Generates Negative High Voltage with Variable Voltage , Eugene Ivanova,

    E-Print Network [OSTI]

    Ayers, Joseph

    A Charge Pump that Generates Negative High Voltage with Variable Voltage Gain Jun Zhaob, , Eugene, Massachusetts 02115, U.S.A. Abstract A cross-coupled structure based charge pump that generates negative high. The proposed negative charge pump is designed to deliver 40 uA with a wide supply range from 2.5V to 5.5V using

  13. High sensitivity bulk electro-optic modulator field sensor for high voltage environments

    E-Print Network [OSTI]

    Shy,Jow-Tsong

    High sensitivity bulk electro-optic modulator field sensor for high voltage environments Mao December 2004) An optical electric field sensor is an effective instrument for surveying the electric attacked by unexpected electrical shocks through the metal cable of the sensor. Sensing by optical sensors

  14. High voltage bus and auxiliary heater control system for an electric or hybrid vehicle

    DOE Patents [OSTI]

    Murty, Balarama Vempaty (West Bloomfield, MI)

    2000-01-01T23:59:59.000Z

    A control system for an electric or hybrid electric vehicle includes a vehicle system controller and a control circuit having an electric immersion heater. The heater is electrically connected to the vehicle's high voltage bus and is thermally coupled to a coolant loop containing a heater core for the vehicle's climate control system. The system controller responds to cabin heat requests from the climate control system by generating a pulse width modulated signal that is used by the control circuit to operate the heater at a duty cycle appropriate for the amount of cabin heating requested. The control system also uses the heater to dissipate excess energy produced by an auxiliary power unit and to provide electric braking when regenerative braking is not desirable and manual braking is not necessary. The control system further utilizes the heater to provide a safe discharge of a bank of energy storage capacitors following disconnection of the battery or one of the high voltage connectors used to transmit high voltage operating power to the various vehicle systems. The control circuit includes a high voltage clamping circuit that monitors the voltage on the bus and operates the heater to clamp down the bus voltage when it exceeds a pre-selected maximum voltage. The control system can also be used to phase in operation of the heater when the bus voltage exceeds a lower threshold voltage and can be used to phase out the auxiliary power unit charging and regenerative braking when the battery becomes fully charged.

  15. CONTROL SYSTEM FOR THE ORNL MULTICHARGED ION RESEARCH FACILITY HIGH-VOLTAGE PLATFORM

    E-Print Network [OSTI]

    CONTROL SYSTEM FOR THE ORNL MULTICHARGED ION RESEARCH FACILITY HIGH-VOLTAGE PLATFORM M. E for the 250-kV platform and beamlines for accelerating and transporting ions produced by an all- permanent of the electrical potentials of the installation, that is at the source, platform, and ground potentials, are inter

  16. Using Dielectric Losses to De-Ice Power Transmission Lines with 100 kHz High-Voltage

    E-Print Network [OSTI]

    Using Dielectric Losses to De-Ice Power Transmission Lines with 100 kHz High-Voltage Excitation J DIELECTRIC LOSSES TO DE-ICE POWER TRANSMISSION LINES . . . 1 Using Dielectric Losses to De-Ice Power Transmission Lines with 100 kHz High-Voltage Excitation Joshua D. McCurdy, Charles R. Sullivan and Victor F

  17. Development of the Fast Scintillation Detector with Programmable High Voltage Adjustment Suitable for Moessbauer Spectroscopy

    SciTech Connect (OSTI)

    Prochazka, R.; Frydrych, J. [Center for Nanomaterial Research, Faculty of Science Palacky University, Slechtitelu 11, 783 71 Olomouc (Czech Republic); Pechousek, J. [Center for Nanomaterial Research, Faculty of Science Palacky University, Slechtitelu 11, 783 71 Olomouc (Czech Republic); Department of Experimental Physics, Faculty of Science, 17. listopadu 1192/12, 771 46 Olomouc (Czech Republic)

    2010-07-13T23:59:59.000Z

    This work is focused on a development of a compact fast scintillation detector suitable for Moessbauer spectroscopy (low energy X-ray/{gamma}-ray detection) where high counting rates are inevitable. Optimization of this part was necessary for a reliable function, better time resolution and to avoid a detector pulses pile-up effect. The pile-up effect decreases the measurement performance, significantly depends on the source activity and also on the pulse duration. Our new detection unit includes a fast scintillation crystal YAP:Ce, an R6095 photomultiplier tube, a high voltage power supply socket C9028-01 assembly, an AD5252 digital potentiometer with an I2C interface and an AD8000 ultra fast operation preamplifier. The main advantages of this solution lie in a short pulse duration (less than 200 ns), stable operation for high activities, programmable gain of the high voltage supply and compact design in the aluminum housing.

  18. Switch contact device for interrupting high current, high voltage, AC and DC circuits

    DOE Patents [OSTI]

    Via, Lester C.; Witherspoon, F. Douglas; Ryan, John M.

    2005-01-04T23:59:59.000Z

    A high voltage switch contact structure capable of interrupting high voltage, high current AC and DC circuits. The contact structure confines the arc created when contacts open to the thin area between two insulating surfaces in intimate contact. This forces the arc into the shape of a thin sheet which loses heat energy far more rapidly than an arc column having a circular cross-section. These high heat losses require a dramatic increase in the voltage required to maintain the arc, thus extinguishing it when the required voltage exceeds the available voltage. The arc extinguishing process with this invention is not dependent on the occurrence of a current zero crossing and, consequently, is capable of rapidly interrupting both AC and DC circuits. The contact structure achieves its high performance without the use of sulfur hexafluoride.

  19. High-Voltage Terminal Test of Test Stand for 1-MV Electrostatic Accelerator

    E-Print Network [OSTI]

    Park, Sae-Hoon

    2015-01-01T23:59:59.000Z

    The Korea Multipurpose Accelerator Complex (KOMAC) has been developing a 300-kV test stand for a 1-MV electrostatic accelerator ion source. The ion source and accelerating tube will be installed in a high-pressure vessel. The ion source in the high-pressure vessel is required to have a high reliability. The test stand has been proposed and developed to confirm the stable operating conditions of the ion source. The ion source will be tested at the test stand to verify the long-time operating conditions. The test stand comprises a 300-kV high-voltage terminal, a battery for the ion-source power, a 60-Hz inverter, 200-MHz RF power, a 5-kV extraction power supply, a 300-kV accelerating tube, and a vacuum system. The results of the 300-kV high-voltage terminal tests are presented in this paper.

  20. Static reactive power compensators for high-voltage power systems. Final report

    SciTech Connect (OSTI)

    Not Available

    1981-04-01T23:59:59.000Z

    A study conducted to summarize the role of static reactive power compensators for high voltage power system applications is described. This information should be useful to the utility system planning engineer in applying static var systems (SVS) to high voltage as (HVAC) systems. The static var system is defined as a form of reactive power compensator. The general need for reactive power compensation in HVAC systems is discussed, and the static var system is compared to other devices utilized to provide reactive power compensation. Examples are presented of applying SVS for specific functions, such as the prevention of voltage collapse. The operating principles of commercially available SVS's are discussed in detail. The perormance and active power loss characteristics of SVS types are compared.

  1. Design and validation of a high-voltage levitation circuit for electrostatic accelerometers

    SciTech Connect (OSTI)

    Li, G.; Wu, S. C.; Zhou, Z. B.; Bai, Y. Z.; Hu, M.; Luo, J. [MOE Key Laboratory of Fundamental Physical Quantities Measurements, School of Physics, Huazhong University of Science and Technology, Wuhan, Hubei 430074 (China)] [MOE Key Laboratory of Fundamental Physical Quantities Measurements, School of Physics, Huazhong University of Science and Technology, Wuhan, Hubei 430074 (China)

    2013-12-15T23:59:59.000Z

    A simple high-voltage circuit with a voltage range of 0 to 900 V and an open-loop bandwidth of 11 kHz is realized by using an operational amplifier and a MOSFET combination. The circuit is used for the levitation of a test mass of 71 g, suspended below the top-electrodes with a gap distance of 57 ?m, so that the performance of an electrostatic accelerometer can be tested on the ground. The translation noise of the accelerometer, limited by seismic noise, is about 4 × 10{sup ?8} m/s{sup 2}/Hz{sup 1/2} at 0.1 Hz, while the high-voltage coupling noise is one-order of magnitude lower.

  2. Tests of industrial ethylene-propylene rubber high voltage cable for cryogenic use

    E-Print Network [OSTI]

    Balhan, B; Goddard, B; Muratori, G; Otwinowski, S; Rieubland, Jean Michel; Wang, H; CERN. Geneva. SPS and LEP Division

    1999-01-01T23:59:59.000Z

    At the beginning of 1999 UCLA has received a prototype High Voltage Cryogenic Cable supplied fee of charge by Pirelli. The cable is intended for more than ten years of service at 100 kV D.C. and liquid argon temperature. Thecable uses an all welded construction, whichi is axially tight and free of ionizable voids. The cable was submitted to a number of mechanical and electrical tests as described below.

  3. Round-robin artificial contamination test on high voltage dc insulators

    SciTech Connect (OSTI)

    Naito, K.; Schneider, H.M.

    1995-07-01T23:59:59.000Z

    This paper summarizes the results of a worldwide round-robin test of high voltage dc (HVDC) insulators, which was carried out in six laboratories aiming at standardization of the method for artificial contamination tests on HVDC insulators. Flashover characteristics of three kinds of specimens were evaluated by the clean fog and the salt fog procedures. Sufficient information is now available to allow the preparation of provisional international specifications for artificial contamination testing of HVDC insulators.

  4. CRYOGENIC LIFETIME TESTS ON A COMMERCIAL EPOXY RESIN HIGH VOLTAGE BUSHING

    SciTech Connect (OSTI)

    Schwenterly, S W [ORNL; Pleva, Ed [Waukesha Electric Systems, Waukesha, WI; Ha, Tam T [ORNL

    2012-01-01T23:59:59.000Z

    High-temperature superconducting (HTS) power devices operating in liquid nitrogen frequently require high-voltage bushings to carry the current leads from the superconducting windings to the room temperature grid connections. Oak Ridge National Laboratory is collaborating with Waukesha Electric Systems, SuperPower, and Southern California Edison to develop and demonstrate an HTS utility power transformer. Previous dielectric high voltage tests in support of this program have been carried out in test cryostats with commercial epoxy resin bushings from Electro Composites Inc. (ECI). Though the bushings performed well in these short-term tests, their long-term operation at high voltage in liquid nitrogen needs to be verified for use on the utility grid. Long-term tests are being carried out on a sample 28-kV-class ECI bushing. The bushing has a monolithic cast, cycloaliphatic resin body and is fire- and shatter-resistant. The test cryostat is located in an interlocked cage and is energized at 25 kVac around the clock. Liquid nitrogen (LN) is automatically refilled every 9.5 hours. Partial discharge, capacitance, and leakage resistance tests are periodically performed to check for deviations from factory values. At present, over 2400 hours have been accumulated with no changes in these parameters. The tests are scheduled to run for four to six months.

  5. Design, conditioning, and performance of a high voltage, high brightness dc photoelectron gun with variable gap

    SciTech Connect (OSTI)

    Maxson, Jared; Bazarov, Ivan; Dunham, Bruce; Dobbins, John; Liu, Xianghong; Smolenski, Karl [Cornell Laboratory for Accelerator-Based Sciences and Education, Cornell University, Ithaca, New York 14853 (United States)

    2014-09-15T23:59:59.000Z

    A new high voltage photoemission gun has been constructed at Cornell University which features a segmented insulator and a movable anode, allowing the cathode-anode gap to be adjusted. In this work, we describe the gun's overall mechanical and high voltage design, the surface preparation of components, as well as the clean construction methods. We present high voltage conditioning data using a 50 mm cathode-anode gap, in which the conditioning voltage exceeds 500 kV, as well as at smaller gaps. Finally, we present simulated emittance results obtained from a genetic optimization scheme using voltage values based on the conditioning data. These results indicate that for charges up to 100 pC, a 30 mm gap at 400 kV has equal or smaller 100% emittance than a 50 mm gap at 450 kV, and also a smaller core emittance, when placed as the source for the Cornell energy recovery linac photoinjector with bunch length constrained to be <3 ps rms. For 100 pC up to 0.5 nC charges, the 50 mm gap has larger core emittance than the 30 mm gap, but conversely smaller 100% emittance.

  6. Polymers 2014, 6, 311-326; doi:10.3390/polym6020311 ISSN 2073-4360

    E-Print Network [OSTI]

    Takada, Shoji

    #12;Polymers 2014, 6, 311-326; doi:10.3390/polym6020311 polymers ISSN 2073-4360 www.mdpi.com/journal/polymers copolymers, star polymers, and concentrated polymer brushes on solid surfaces were prepared using living catalysts; block copolymers; triblock copolymers; star polymers; polymer brushes OPEN ACCESS #12;Polymers

  7. A Neutron Reflectivity Study of Polymer-Modified Phospholipid Monolayers at the Solid-Solution Interface: Polyethylene Glycol-Lipids on

    E-Print Network [OSTI]

    Wong, Joyce

    A Neutron Reflectivity Study of Polymer-Modified Phospholipid Monolayers at the Solid,# S. Steinberg,# D. E. Leckband,§ J. N. Israelachvili,# and G. S. Smith* *Manuel Lujan, Jr. Neutron Scattering Center, Los Alamos National Laboratory, Los Alamos, New Mexico 87545; # Department of Chemical

  8. Fabrication and characterization of face-centered-cubic void dots photonic crystals in a solid polymer material

    SciTech Connect (OSTI)

    Zhou Guangyong; Ventura, Michael James; Vanner, Michael Ross; Gu Min [Centre for Micro-Photonics and CUDOS, Faculty of Engineering and Industrial Sciences, Swinburne University of Technology, P.O. Box 218, Hawthorn, Victoria 3122 (Australia)

    2005-01-03T23:59:59.000Z

    Spherical void dots with a diameter of 1.2-1.8 {mu}m have been generated in a solid polymer material by use of the ultrafast laser driven micro-explosion method. Micron-sized structures with a face-centered cubic lattice stacked in the [100] and [111] directions have been fabricated. Confocal microscopic images show the high uniformity of the fabricated structures. Photonic stopgaps with a suppression rate of approximately 70% as well as the second-order stopgaps have been observed in both directions. It is shown that the dependence of the stopgaps on the illumination angle in the [100] direction is significantly different from that in the [111] direction.

  9. Studying the Breaking Mechanism of Polymer-Based In-Situ Gelled Acids using Solid Breaker

    E-Print Network [OSTI]

    Tian, Zhida

    2012-10-19T23:59:59.000Z

    of this study is to examine the working mechanisms of the solid breaker and the factors that affect the breaking time. The flowback of the spent acid and the core damage induced by it will also be assessed in detail. Viscosity and rheological experimental...

  10. A Fusing Switch for Fault Suppression in the SNS High Voltage Converter Modulators

    SciTech Connect (OSTI)

    Kemp, Mark A.; Burkhart, Craig; Nguyen, Minh N.; /SLAC; Anderson, David E.; /Oak Ridge

    2009-08-03T23:59:59.000Z

    The High Voltage Converter Modulators (HVCMs) at the Spallation Neutron Source (SNS) have operated in excess of a combined 250,000 hours. Performance and reliability improvements to the HVCM are ongoing to increase modulator availability as accelerator system demands increase. There is a relatively large amount of energy storage in the HVCMs, {approx}180 kJ. This energy has the potential to dump into unsuppressed faults, cause damage, and increase the time to repair. The 'fusing switch' concept involves isolation of this stored energy from the location of the most common faults. This paper introduces this concept and its application to the HVCMs.

  11. High voltage ignition of high pressure microwave powered UV light sources

    SciTech Connect (OSTI)

    Frank, J.D.; Cekic, M.; Wood, C.H. [Fusion U.V. Curing Systems Corp., Gaithersburg, MD (United States)

    1997-12-31T23:59:59.000Z

    Industrial microwave powered (electrodeless) light sources have been limited to quiescent pressures of {approximately}300 Torr of buffer gas and metal-halide fills. The predominant reason for such restrictions has been the inability to microwave ignite the plasma due to the collisionality of higher pressure fills and/or the electronegativity of halide bulb chemistries. Commercially interesting bulb fills require electric fields for ionization that are often large multiples of the breakdown voltage for air. Many auxiliary ignition methods are evaluated for efficiency and practicality before the choice of a high-voltage system with a retractable external electrode. The scheme utilizes a high voltage pulse power supply and a novel field emission source. Acting together they create localized condition of pressure reduction and high free electron density. This allows the normal microwave fields to drive this small region into avalanche, ignite the bulb, and heat the plasma to its operating point (T{sub e} {approx} 0.5 eV). This process is currently being used in a new generation of lamps, which are using multi-atmospheric excimer laser chemistries and pressure and constituent enhanced metal-halide systems. At the present time, production prototypes produce over 900 W of radiation in a 30 nm band, centered at 308 nm. Similarly, these prototypes when loaded with metal-halide bulb fills produce over 1 kW of radiation in 30 nm wide bands, centered about the wavelength of interest.

  12. Stabilization of turbulent lifted jet flames assisted by pulsed high voltage discharge

    SciTech Connect (OSTI)

    Criner, K.; Cessou, A.; Louiche, J.; Vervisch, P. [CORIA UMR 6614 CNRS-Universite et INSA de Rouen, University of Rouen, 76801 Saint Etienne du Rouvray (France)

    2006-01-01T23:59:59.000Z

    To reduce fuel consumption or the pollutant emissions of combustion (furnaces, aircraft engines, turbo-reactors, etc.), attempts are made to obtain lean mixture combustion regimes. These lead to poor stability of the flame. Thus, it is particularly interesting to find new systems providing more flexibility in aiding flame stabilization than the usual processes (bluff-body, stabilizer, quarl, swirl, etc.). The objective is to enlarge the stability domain of flames while offering flexibility at a low energy cost. Evidence is presented that the stabilization of a turbulent partially premixed flame of more than 10 kW can be enhanced by pulsed high-voltage discharges with power consumption less than 0.1% of the power of the flame. The originality of this work is to demonstrate that very effective stabilization of turbulent flames is obtained when high-voltage pulses with very short rise times are used (a decrease by 300% in terms of liftoff height for a given exit jet velocity can be reached) and to provide measurements of minimum liftoff height obtained with discharge over a large range of the stability domain of the lifted jet flame.

  13. The commercial development of water repellent coatings for high voltage transmission lines

    SciTech Connect (OSTI)

    Hunter, Scott Robert [ORNL

    2013-10-01T23:59:59.000Z

    The purpose of the Cooperative Research and Development Agreement (CRADA) between UT-Battelle, LLC and Southwire Company was to jointly develop a low cost, commercially viable, water-repellant anti-icing coating system for high voltage transmission lines. Icing of power lines and other structures caused by freezing rain events occurs annually in the United States, and leads to severe and prolonged power outages. These outages cause untold economic and personal distress for many American families and businesses. Researchers at the Department of Energy s Oak Ridge National Laboratory (ORNL) in Oak Ridge, Tennessee have previously developed a set of superhydrophobic coatings with remarkable anti-icing properties that could potentially be sprayed or painted onto high-tension power lines and pylons. These coatings drastically reduce ice accumulation on these structures during freezing rain events. The project involved obtaining technical input, supplies and test high voltage cables from Southwire, along with the joint development of anti-icing coating techniques, which would result in a commercial license agreement between Southwire and ORNL, and potentially other companies requiring water repellent anti-icing coatings.

  14. The commercial development of water repellent coatings for high voltage transmission lines

    SciTech Connect (OSTI)

    Hunter, S. R. [ORNL] [ORNL; Daniel, A. [Southwire Company] [Southwire Company

    2013-10-31T23:59:59.000Z

    The purpose of the Cooperative Research and Development Agreement (CRADA) between UT-Battelle, LLC and Southwire Company was to jointly develop a low cost, commercially viable, water-repellant anti-icing coating system for high voltage transmission lines. Icing of power lines and other structures caused by freezing rain events occurs annually in the United States, and leads to severe and prolonged power outages. These outages cause untold economic and personal distress for many American families and businesses. Researchers at the Department of Energy?s Oak Ridge National Laboratory (ORNL) in Oak Ridge, Tennessee have previously developed a set of superhydrophobic coatings with remarkable anti-icing properties that could potentially be sprayed or painted onto high-tension power lines and pylons. These coatings drastically reduce ice accumulation on these structures during freezing rain events. The project involved obtaining technical input, supplies and test high voltage cables from Southwire, along with the joint development of anti-icing coating techniques, which would result in a commercial license agreement between Southwire and ORNL, and potentially other companies requiring water repellent anti-icing coatings.

  15. Ultraviolet stimulation of hydrogen peroxide production using aminoindazole, diaminopyridine, and phenylenediamine solid polymer complexes of Zn(II)

    SciTech Connect (OSTI)

    Hayes, Jennifer A.; Schubert, David M.; Amonette, James E.; Nachimuthu, Ponnusamy; Disselkamp, Robert S.

    2008-06-25T23:59:59.000Z

    Hydrogen peroxide is a valuable chemical commodity whose production relies on expensive methods. If an efficient, sustainable, and inexpensive solar-mediated production method could be developed from the reaction between dioxygen and water then its use as a fuel may be possible and gain acceptance. Hydrogen peroxide at greater than 10 M possesses a high specific energy, is environmentally clean, and is easily stored. However, the current method of manufacturing H2O2 via the anthraquinone process is environmentally unfriendly making the unexplored nature of its photochemical production from solar irradiation of interest. Here the concentration and quantum yield of hydrogen peroxide produced in an ultraviolet (UV-B) irradiated environment using aromatic and nitrogen-heterocyclic ring complexes of zinc(II) as solid substrates was studied. The amino-substituted isomers of the substrates indazole, pyridine, and phenylenediamine solid polymer complexes are examined. Samples exposed to the ambient atmosphere (e.g., aerated) were irradiated with a low power lamp with emission from 280-360 nm. Irradiation of various zinc complexes revealed Zn-5-aminoindazole to have the greatest first-day production of 63 mM/day with a 37% quantum yield. Para-phenylenediamine (PPAM) showed the greatest long-term stability and thus suggests H2O2 is produced photocatalytically. Isomeric forms of the catalyst’s organic components (e.g., amino groups) did have an effect on the production. Irradiation of diaminopyridine isomers indicated 2,3-diamino and 3,4-diamino structures were the most productive, each generating 32 mM/day hydrogen peroxide. However, the 2,5-diamino isomer showed no peroxide production. A significant decrease in hydrogen peroxide production in all but PPAM was noticed in the samples, suggesting the possibility of a catalyst poisoning mechanism. The samples ability to produce H2O2 is rationalized by proposing a reaction mechanism and examining the stability of the resonance structures of the different isomers.

  16. Integrated feature scale modeling of plasma processing of porous and solid SiO2 . II. Residual fluorocarbon polymer stripping

    E-Print Network [OSTI]

    Kushner, Mark

    fluorocarbon polymer stripping and barrier layer deposition Arvind Sankarana) Department of Chemical from trenches following etching using fluorocarbon plasmas and the deposition of a continuous barrier these issues, reactions mechanisms for plasma stripping of fluorocarbon polymer using oxygen containing plasmas

  17. High-Temperature Steam-Treatment of PBI, PEEK, and PEKK Polymers with H2O and D2O: A Solid-State NMR Study

    E-Print Network [OSTI]

    Bluemel, Janet

    1 High-Temperature Steam-Treatment of PBI, PEEK, and PEKK Polymers with H2O and D2O: A Solid Supplementary Information Figure S1. TGA of melt-molded PBI after stirring in H2O at RT and steam-treatment with H2O at 150 °C and 315 °C. Figure S2. TGA of melt-molded PEEK after stirring in D2O at RT and steam

  18. The design, construction, and operation of long-distance high-voltage electricity transmission technologies.

    SciTech Connect (OSTI)

    Molburg, J. C.; Kavicky, J. A.; Picel, K. C.

    2008-03-03T23:59:59.000Z

    This report focuses on transmission lines, which operate at voltages of 115 kV and higher. Currently, the highest voltage lines comprising the North American power grid are at 765 kV. The grid is the network of transmission lines that interconnect most large power plants on the North American continent. One transmission line at this high voltage was built near Chicago as part of the interconnection for three large nuclear power plants southwest of the city. Lines at this voltage also serve markets in New York and New England, also very high demand regions. The large power transfers along the West Coast are generally at 230 or 500 kV. Just as there are practical limits to centralization of power production, there are practical limits to increasing line voltage. As voltage increases, the height of the supporting towers, the size of the insulators, the distance between conductors on a tower, and even the width of the right-of-way (ROW) required increase. These design features safely isolate the electric power, which has an increasing tendency to arc to ground as the voltage (or electrical potential) increases. In addition, very high voltages (345 kV and above) are subject to corona losses. These losses are a result of ionization of the atmosphere, and can amount to several megawatts of wasted power. Furthermore, they are a local nuisance to radio transmission and can produce a noticeable hum. Centralized power production has advantages of economies of scale and special resource availability (for instance, hydro resources), but centralized power requires long-distance transfers of power both to reach customers and to provide interconnections for reliability. Long distances are most economically served at high voltages, which require large-scale equipment and impose a substantial footprint on the corridors through which power passes. The most visible components of the transmission system are the conductors that provide paths for the power and the towers that keep these conductors at a safe distance from each other and from the ground and the natural and built environment. Common elements that are generally less visible (or at least more easily overlooked) include the maintained ROW along the path of the towers, access roads needed for maintenance, and staging areas used for initial construction that may be restored after construction is complete. Also visible but less common elements along the corridor may include switching stations or substations, where lines of similar or different voltages meet to transfer power.

  19. Health-hazard evaluation report HETA 81-415-1385, High Voltage Maintenance Corporation, Mentor, Ohio

    SciTech Connect (OSTI)

    Kominsky, J.R.; Lipscomb, J.

    1983-10-01T23:59:59.000Z

    In September 1981 the National Institute for Occupational Safety and Health (NIOSH) was requested to evaluate exposures to polychlorinated biphenyls (PCBs) and to chlorinated benzenes and ethanes for electricians at High Voltage Maintenance (HVM) Corp., Mentor, Ohio. The HVM Corp. services electrical power transformers and capacitors on a contract basis with the work performed both in the field and at the Mentor facilities. On the basis of the data collected, NIOSH concludes that workers were exposed to potentially toxic concentrations of airborne 1,1,1-trichloroethane and PCBs. Significant PCB contamination of work surfaces demonstrate a potential for continued exposure to PCBs via skin contact and ingestion. PCB blood levels also indicate excessive absorption of PCBs. Recommendations for decontamination of the buildings and exposure controls are offered in Section VIII of this report.

  20. Droop Compensation with soft Switching for High Voltage Converter Modulator (HVCM)

    SciTech Connect (OSTI)

    Bland, Michael [University of Nottingham; Scheinker, Alexander [Los Alamos National Laboratory; Clare, Jon [University of Nottingham; Watson, Alan [University of Nottingham; Ji, Chao [University of Nottingham; Reass, William [Los Alamos National Laboratory

    2012-06-04T23:59:59.000Z

    High Voltage Converter Modulators (HVCM) offer significant performance advantages over conventional modulator technologies for long pulse applications. One of the key advantages of HVCM technology is the ability to compensate for capacitor bank voltage droop. Achieving droop compensation without incurring significant additional switching loss has not been possible in existing designs. This paper presents an analysis of the 'Y-point' variant of the HVCM topology using the Combined Phase and Frequency Modulation (CPFM) technique. This, combined with the addition of a 'lossless' snubber circuit, enables droop compensation while achieving soft switching over the entire pulse duration. The rise time and overshoot of the output voltage pulse is optimized using an iterative extreme seeking algorithm. The optimization reduces the rise time from 100 {micro}s to 50 {micro}s with no overshoot. This will lead to an increase in overall accelerator efficiency.

  1. Process for measuring degradation of sulfur hexafluoride in high voltage systems

    DOE Patents [OSTI]

    Sauers, I.

    1985-04-23T23:59:59.000Z

    This invention is a method of detecting the presence of toxic and corrosive by-products in high voltage systems produced by electrically induced degradation of SF/sub 6/ insulating gas in the presence of certain impurities. It is an improvement over previous methods because it is extremely sensitive, detecting by-products present in parts per billion concentrations, and because the device employed is of a simple design and takes advantage of the by-products natural affinity for fluoride ions. The method employs an ion-molecule reaction cell in which negative ions of the by-products are produced by fluorine attachment. These ions are admitted to a negative ion mass spectrometer and identified by their spectra. This spectrometry technique is an improvement over conventional techniques because the negative ion peaks are strong and not obscured by a major ion spectra of the SF/sub 6/ component as is the case in positive ion mass spectrometry.

  2. Process for measuring degradation of sulfur hexafluoride in high voltage systems

    DOE Patents [OSTI]

    Sauers, Isidor (Knoxville, TN)

    1986-01-01T23:59:59.000Z

    This invention is a method of detecting the presence of toxic and corrosive by-products in high voltage systems produced by electrically induced degradation of SF.sub.6 insulating gas in the presence of certain impurities. It is an improvement over previous methods because it is extremely sensitive, detecting by-products present in parts per billion concentrations, and because the device employed is of a simple design and takes advantage of the by-products natural affinity for fluoride ions. The method employs an ion-molecule reaction cell in which negative ions of the by-products are produced by fluorine attachment. These ions are admitted to a negative ion mass spectrometer and identified by their spectra. This spectrometry technique is an improvement over conventional techniques because the negative ion peaks are strong and not obscured by a major ion spectra of the SF.sub.6 component as is the case in positive ion mass spectrometry.

  3. Electric power high-voltage transmission lines: Design options, cost, and electric and magnetic field levels

    SciTech Connect (OSTI)

    Stoffel, J.B.; Pentecost, E.D.; Roman, R.D.; Traczyk, P.A.

    1994-11-01T23:59:59.000Z

    This report provides background information about (1) the electric and magnetic fields (EMFs) of high-voltage transmission lines at typical voltages and line configurations and (2) typical transmission line costs to assist on alternatives in environmental documents. EMF strengths at 0 {+-} 200 ft from centerline were calculated for ac overhead lines, and for 345 and 230-kV ac underground line and for a {+-}450-kV dc overhead line. Compacting and height sensitivity factors were computed for the variation in EMFs when line conductors are moved closer or raised. Estimated costs for the lines are presented and discussed so that the impact of using alternative strategies for reducing EMF strengths and the implications of implementing the strategies can be better appreciated.

  4. Partial discharge measurements on a high voltage direct current mass impregnated paper cable

    SciTech Connect (OSTI)

    Jeroense, M.J.P. [NKF KABEL B.V., Delft (Netherlands); Kreuger, F.H. [Delft Univ. of Technology (Netherlands)

    1996-12-31T23:59:59.000Z

    Partial discharge measurement has been a good tool for the quality assurance of cables under alternating voltage. With the growing interest in High Voltage Direct Current cables it seems therefore logical to extend this technique for use at direct voltage. The paper describes this technique as used on a HVDC cable with mass impregnated paper. The different phases of operation (no load, full load, cooling phase, etc.) are characterized by a different discharge behavior. Special attention is given to the dangerous cooling phase. Models have been developed which can explain the discharge patterns that were measured. This paper gives an insight in the electrical behavior of a HVDC cable with mass impregnated paper insulation.

  5. Evaluation of electropolished stainless steel electrodes for use in DC high voltage photoelectron guns

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    BastaniNejad, Mahzad; Elmustafa, Abdelmageed A.; Forman, Eric; Covert, Steven; Hansknecht, John; Hernandez-Garcia, Carlos; Poelker, Matthew; Das, Lopa; Kelley, Michael; Williams, Phillip

    2015-07-01T23:59:59.000Z

    DC high voltage photoelectron guns are used to produce polarized electron beams for accelerator-based nuclear and high-energy physics research. Low-level field emission (~nA) from the cathode electrode degrades the vacuum within the photogun and reduces the photoelectron yield of the delicate GaAs-based photocathode used to produce the electron beams. High-level field emission (>?A) can cause significant damage the photogun. To minimize field emission, stainless steel electrodes are typically diamond-paste polished, a labor-intensive process often yielding field emission performance with a high degree of variability, sample to sample. As an alternative approach and as comparative study, the performance of electrodes electropolishedmore »by conventional commercially available methods is presented. Our observations indicate the electropolished electrodes exhibited less field emission upon the initial application of high voltage, but showed less improvement with gas conditioning compared to the diamond-paste polished electrodes. In contrast, the diamond-paste polished electrodes responded favorably to gas conditioning, and ultimately reached higher voltages and field strengths without field emission, compared to electrodes that were only electropolished. The best performing electrode was one that was both diamond-paste polished and electropolished, reaching a field strength of 18.7 MV/m while generating less than 100 pA of field emission. The speculate that the combined processes were the most effective at reducing both large and small scale topography. However, surface science evaluation indicates topography cannot be the only relevant parameter when it comes to predicting field emission performance.« less

  6. DC BUFFERING AND FLOATING CURRENT FOR A HIGH VOLTAGE IMB APPLICATION

    SciTech Connect (OSTI)

    J.L. Morrison

    2014-08-01T23:59:59.000Z

    An interface technique for the latest generation of the Impedance Measurement Box (IMB) has been conceived to enable measurement of impedance spectra for battery modules up to 300V. A 300V capable or higher IMB is an enabling technology for in-situ diagnostics within electric vehicle charging stations or battery back-ups within power distribution sub-stations. It is possible that the existing IMB can be adapted via a 300V interface module to a test battery with voltage significantly greater than 50V. Recently a new concept was conceived for the calibration, algorithm and electronics of the IMB. That algorithm and calibration for that concept have been physically validated. The principal feature of the new electronics is the floating current source excitation of the battery under test. The single ended current excitation of the battery under test, used in the 50V IMB, requires that the negative terminal of the test battery must be the analog ground for the IMB. The new floating current technique allows the test battery to be fully high impedance isolated for a measurement. That isolation will improve IMB noise immunity and enable interrogation of cells internal to a battery module. All these techniques still use the same rapid concept for impedance measurement with the IMB. The purpose of this disclosure is to provide an overview of the analytical validation for three concepts to interface the floating current excitation to a high voltage battery. Recursive simulation models were used in different test scenarios to validate the various new concepts. The analysis will show that it is possible to interface the floating signal current to obtain an impedance measurement on a high voltage test battery. Additionally, the analysis will investigate stress seen by electronics while testing a 300V battery.

  7. Novel Nonflammable Electrolytes for Secondary Magnesium Batteries and High Voltage Electrolytes for Electrochemcial Supercapacitors

    SciTech Connect (OSTI)

    Dr. Brian Dixon

    2008-12-30T23:59:59.000Z

    Magnesium has been used successfully in primary batteries, but its use in rechargeable cells has been stymied by the lack of suitable non-aqueous electrolyte that can conduct Mg+2 species, combined with poor stripping and plating properties. The development of a suitable cathode material for rechargeable magnesium batteries has also been a roadblock, but a nonflammable electrolyte is key. Likewise, the development of safe high voltage electrochemical supercapaitors has been stymied by the use of flammable solvents in the liquid electrolyte; to wit, acetonitrile. The purpose of the research conducted in this effort was to identify useful compositions of magnesium salts and polyphosphate solvents that would enable magnesium ions to be cycled within a secondary battery design. The polyphosphate solvents would provide the solvent for the magnesium salts while preventing the electrolyte from being flammable. This would enable these novel electrolytes to be considered as an alternative to THF-based electrolytes. In addition, we explored several of these solvents together with lithium slats for use as high voltage electrolytes for carbon-based electrochemical supercapacitors. The research was successful in that: 1) Magnesium imide dissolved in a phosphate ester solvent that contains a halogented phosphate ester appears to be the preferred electrolyte for a rechargeable Mg cell. 2) A combination of B-doped CNTs and vanadium phosphate appear to be the cathode of choice for a rechargeable Mg cell by virtue of higher voltage and better reversibility. 3) Magnesium alloys appear to perform better than pure magnesium when used in combination with the novel polyphosphate electrolytes. Also, this effort has established that Phoenix Innovationâ??s family of phosphonate/phosphate electrolytes together with specific lithium slats can be used in supercapacitor systems at voltages of greater than 10V.

  8. Solid State Nuclear Magnetic Resonance Investigation of Polymer Backbone Dynamics in Poly(Ethylene Oxide) Based Lithium and Sodium Polyether-ester-sulfonate Ionomers

    SciTech Connect (OSTI)

    Roach, David J. [Penn State Univ., State College, PA (United States). Dept. of Chemistry; Dou, Shichen [Penn State Univ., State College, PA (United States). Dept. of Materials Science and Engineering; Colby, Ralph H. [Penn State Univ., State College, PA (United States). Dept. of Materials Science and Engineering; Mueller, Karl T. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Penn State Univ., State College, PA (United States). Dept. of Chemistry

    2013-05-21T23:59:59.000Z

    Polymer backbone dynamics of single ion conducting poly(ethylene oxide) (PEO)-based ionomer samples with low glass transition temperatures (Tg) have been investigated using solid-state nuclear magnetic resonance (NMR). Experiments detecting 13C with 1H decoupling under magic angle spinning (MAS) conditions identified the different components of the polymer backbone (PEO spacer and isophthalate groups) and their relative mobilities for a suite of lithium- and sodium-containing ionomer samples with varying cation contents. Variable temperature (203-373 K) 1H-13C cross-polarization MAS (CP-MAS) experiments also provided qualitative assessment of the differences in the motions of the polymer backbone components as a function of cation content and identity. Each of the main backbone components exhibit distinct motions, following the trends expected for motional characteristics based on earlier Quasi Elastic Neutron Scattering and 1H spin-lattice relaxation rate measurements. Previous 1H and 7Li spin-lattice relaxation measurements focused on both the polymer backbone and cation motion on the nanosecond timescale. The studies presented here assess the slower timescale motion of the polymer backbone allowing for a more comprehensive understanding of the polymer dynamics. The temperature dependences of 13C linewidths were used to both qualitatively and quantitatively examine the effects of cation content and identity on PEO spacer mobility. Variable contact time 1H-13C CP-MAS experiments were used to further assess the motions of the polymer backbone on the microsecond timescale. The motion of the PEO spacer, reported via the rate of magnetization transfer from 1H to 13C nuclei, becomes similar for T ? 1.1 Tg in all ionic samples, indicating that at similar elevated reduced temperatures the motions of the polymer backbones on the microsecond timescale become insensitive to ion interactions. These results present an improved picture, beyond those of previous findings, for the dependence of backbone dynamics on cation density (and here, cation identity as well) in these amorphous PEO-based ionomer systems.

  9. Redesign of the H-Bridge Switch Plate of the SNS High Voltage Converter Modulator

    SciTech Connect (OSTI)

    Kemp, M.A.; Burkhart, C.; Nguyen, M.N.; /SLAC; Anderson, D.E.; /Oak Ridge

    2009-05-07T23:59:59.000Z

    The 1-MW High Voltage Converter Modulators [1] have operated in excess of 250,000 hours at the Spallation Neutron Source. Increased demands on the accelerator performance require increased modulator reliability. An effort is underway at SLAC National Accelerator Laboratory to redesign the modulator H-bridge switch plate with the goals of increasing reliability and performance [2]. The major difference between the SLAC design and the existing design is the use of press-pack IGBTs. Compared to other packaging options, these IGBTs have been shown to have increased performance in pulsed-power applications, have increased cooling capability, and do not fragment and disassemble during a fault event. An overview of the SLAC switch plate redesign is presented. Design steps including electrical modeling of the modulator and H-bridge, development of an integrated IGBT clamping mechanism, and fault tests are discussed. Experimental results will be presented comparing electrical performance of the SLAC switch plate to the existing switchplate under normal and fault conditions.

  10. Atmospheric pressure plasma jet with high-voltage power supply based on piezoelectric transformer

    SciTech Connect (OSTI)

    Babij, Micha?; Kowalski, Zbigniew W., E-mail: zbigniew.w.kowalski@pwr.wroc.pl; Nitsch, Karol; Gotszalk, Teodor [Wroc?aw University of Technology, Wybrze?e Wyspia?skiego 27, 50-370 Wroc?aw (Poland)] [Wroc?aw University of Technology, Wybrze?e Wyspia?skiego 27, 50-370 Wroc?aw (Poland); Silberring, Jerzy [AGH University of Science and Technology, Al. A. Mickiewicza 30, 30-059 Kraków (Poland)] [AGH University of Science and Technology, Al. A. Mickiewicza 30, 30-059 Kraków (Poland)

    2014-05-15T23:59:59.000Z

    The dielectric barrier discharge plasma jet, an example of the nonthermal atmospheric pressure plasma jet (APPJ), generates low-temperature plasmas that are suitable for the atomization of volatile species and can also be served as an ionization source for ambient mass and ion mobility spectrometry. A new design of APPJ for mass spectrometry has been built in our group. In these plasma sources magnetic transformers (MTs) and inductors are typically used in power supplies but they present several drawbacks that are even more evident when dealing with high-voltage normally used in APPJs. To overcome these disadvantages, high frequency generators with the absence of MT are proposed in the literature. However, in the case of miniaturized APPJs these conventional power converters, built of ferromagnetic cores and inductors or by means of LC resonant tank circuits, are not so useful as piezoelectric transformer (PT) based power converters due to bulky components and small efficiency. We made and examined a novel atmospheric pressure plasma jet with PT supplier served as ionization source for ambient mass spectrometry, and especially mobile spectrometry where miniaturization, integration of components, and clean plasma are required. The objective of this paper is to describe the concept, design, and implementation of this miniaturized piezoelectric transformer-based atmospheric pressure plasma jet.

  11. High voltage power supply systems for electron beam and plasma technologies. Its new element base

    SciTech Connect (OSTI)

    Dermengi, P.G.; Kureghan, A.S.; Pokrovsky, S.V.; Tchvanov, V.A.

    1994-12-31T23:59:59.000Z

    Transforming technique and high voltage technique supplementing each other more and more unite in indivisible constructions of modern apparatuses and systems and applicated in modern technologies providing its high efficiency. Specially worked out, ecologically clean, inertial, inflammable perfluororganic liquid is used in elements and electronic apparatuses simultaneously as insulating and cooling media. This liquid is highly fluid, fills tiny cavities in construction elements and in the places of high concentration of losses, where maximum local overheating of active parts or apparatus constructions takes place, it transforms to boiling state with highly intensive taking off of heat energy from cooled surface point. For instance, being cooled by mentioned perfluororganic liquid, copper wire can conduct current to 50 A/mm{sup 2} density, but in ordinary conditions of transformers, reactors and busses, current density can reach only few Amperes. Possibility of considerable increasing of current density, that is reached by means of intensive cooling, provided by worked out liquid, and taking into account its incredibly high insulating features (liquid has electric strength to 50 KV/mm) allows to provide optimum heat regime of active parts of transformers. reactors, condenser, semiconductor devices, resistors, construction elements and electrotechnical apparatus in general. Particularly high effect of decreasing of weight and dimensions characteristics of elements and electrotechnical apparatus in general can be reached under working out of special constructions of each element and apparatus details, adapted to use of mentioned liquid as insulating and cooling media.

  12. Assessment of research directions for high-voltage direct-current power systems. Final report

    SciTech Connect (OSTI)

    Long, W F

    1982-09-01T23:59:59.000Z

    High voltage direct current (HVDC) power transmission continues to be an emerging technology nearly thirty years after its introduction into modern power systems. To date its use has been restricted to either specialized applications having identifiable economic advantages (e.g., breakeven distance) or, rarely, applications where decoupling is needed. Only recently have the operational advantages (e.g., power modulation) of HVDC been realized on operating systems. A research project whose objective was to identify hardware developments and, where appropriate, system applications which can exemplify cost and operational advantages of integrated ac/dc power systems is discussed. The three principal tasks undertaken were: assessment of equipment developments; quantification of operational advantages; and interaction with system planners. Interest in HVDC power transmission has increased markedly over the past several years, and many new systems are now being investigated. The dissemination of information about HVDC, including specifically the symposium undertaken for Task 3, is a critical factor in fostering an understanding of this important adjunct to ac power transmission.

  13. An Ultra-Compact Marx-Type High-Voltage Generator

    SciTech Connect (OSTI)

    Goerz, D; Ferriera, T; Nelson, D; Speer, R; Wilson, M

    2001-06-15T23:59:59.000Z

    This paper discusses the design of an ultra-compact, Marx-type, high-voltage generator. This system incorporates high-performance components that are closely coupled and integrated into an extremely compact assembly. Low profile, custom ceramic capacitors with coplanar extended electrodes provide primary energy storage. Low-inductance, spark-gap switches incorporate miniature gas cavities imbedded within the central region of the annular shaped capacitors, with very thin dielectric sections separating the energy storage capacitors. Carefully shaped electrodes and insulator surfaces are used throughout to minimize field enhancements, reduce fields at triple-point regions, and enable operation at stress levels closer to the intrinsic breakdown limits of the dielectric materials. Specially shaped resistors and inductors are used for charging and isolation during operation. Forward-coupling ceramic capacitors are connected across successive switch-capacitor-switch stages to assist in switching. Pressurized SF, gas is used for electrical insulation in the spark-gap switches and throughout the unit. The pressure housing is constructed entirely of dielectric materials, with segments that interlock with the low-profile switch bodies to provide an integrated support structure for all of the components. This ultra-compact Marx generator employs a modular design that can be sized as needed for a particular application. Units have been assembled with 4, 10, and 30 stages and operated at levels up to 100 kV per stage.

  14. Degradation of Photovoltaic Modules Under High Voltage Stress in the Field: Preprint

    SciTech Connect (OSTI)

    del Cueto, J. A.; Rummel, S. R.

    2010-08-01T23:59:59.000Z

    The degradation in performance for eight photovoltaic (PV) modules stressed at high voltage (HV) is presented. Four types of modules--tandem-junction and triple-junction amorphous thin-film silicon, plus crystalline and polycrystalline silicon modules--were tested, with a pair of each biased at opposite polarities. They were deployed outdoors between 2001 and 2009 with their respective HV leakage currents through the module encapsulation continuously monitored with a data acquisition system, along with air temperature and relative humidity. For the first 5 years, all modules were biased continuously at fixed 600 VDC, day and night. In the last 2 years, the modules were step-bias stressed cyclically up and down in voltage between 10 and 600 VDC, in steps of tens to hundreds of volts. This allowed characterization of leakage current versus voltage under a large range of temperature and moisture conditions, facilitating determination of leakage paths. An analysis of the degradation is presented, along with integrated leakage charge. In HV operation: the bulk silicon modules degraded either insignificantly or at rates of 0.1%/yr higher than modules not biased at HV; for the thin-film silicon modules, the added loss rates are insignificant for one type, or 0.2%/yr-0.6%/yr larger for the other type.

  15. Mechanisms of deflagration-to-detonation transition under initiation by high-voltage nanosecond discharges

    SciTech Connect (OSTI)

    Rakitin, Aleksandr E.; Starikovskii, Andrei Yu. [Physics of Nonequilibrium Systems Lab, Moscow Institute of Physics and Technology, 9 Institutski Lane, Dolgoprudny 141700 (Russian Federation)

    2008-10-15T23:59:59.000Z

    An experimental study of detonation initiation in a stoichiometric propane-oxygen mixture by a high-voltage nanosecond gas discharge was performed in a detonation tube with a single-cell discharge chamber. The discharge study performed in this geometry showed that three modes of discharge development were realized under the experimental conditions: a spark mode with high-temperature channel formation, a streamer mode with nonuniform gas excitation, and a transient mode. Under spark and transient initiation, simultaneous ignition inside the discharge channel occurred, forming a shock wave and leading to a conventional deflagration-to-detonation transition (DDT) via an adiabatic explosion. The DDT length and time at 1 bar of initial pressure in the square smooth tube with a 20-mm transverse size amounted to 50 mm and 50{mu}s, respectively. The streamer mode of discharge development at an initial pressure of 1 bar resulted in nonuniform mixture excitation and a successful DDT via a gradient mechanism, which was confirmed by high-speed time resolved ICCD imaging. The gradient mechanism implied a longer DDT time of 150{mu}s, a DDT run-up distance of 50 mm, and an initiation energy of 1 J, which is two orders of magnitude less than the direct initiation energy for a planar detonation under these conditions. (author)

  16. Marine High Voltage Power Conditioning and Transmission System with Integrated Storage DE-EE0003640 Final Report

    SciTech Connect (OSTI)

    Frank Hoffmann, PhD; Aspinall, Rik

    2012-12-10T23:59:59.000Z

    Design, Development, and test of the three-port power converter for marine hydrokinetic power transmission. Converter provides ports for AC/DC conversion of hydrokinetic power, battery storage, and a low voltage to high voltage DC port for HVDC transmission to shore. The report covers the design, development, implementation, and testing of a prototype built by PPS.

  17. LINUDANS -Research and development of high voltage towers. Reykjavik University is working in Collaboration with Linudans, research based company specialized

    E-Print Network [OSTI]

    Karlsson, Brynjar

    LINUDANS - Research and development of high voltage towers. Reykjavik University is working problems regarding the growing energy transport. All products of Linudans are green and environmentally voltage towers is the main focus of Linudans. The company has developed an innovative concept which serves

  18. A simple high-voltage high current spark gap with subnanosecond jitter triggered by femtosecond laser filamentation

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 A simple high-voltage high current spark gap with subnanosecond jitter triggered by femtosecond and able to switch currents in excess of 10 kA with sub-nanosecond jitter. The spark gap is remotely with a nanosecond jitter time2-7 . The jitter could be reduced to hundred of picoseconds with a SF6 filled cell8

  19. A three-level buck converter to regulate a high-voltage DC-to-AC inverter

    E-Print Network [OSTI]

    Schrock, Kenneth C

    2008-01-01T23:59:59.000Z

    A three-level buck converter is designed and analyzed, and shown to be suitable as a high-voltage down converter as a pre-regulation stage for a 600 watt DC-to-AC power inverter. Topology selection for the inverter is ...

  20. Solid electrolytes

    DOE Patents [OSTI]

    Abraham, Kuzhikalail M. (Needham, MA); Alamgir, Mohamed (Dedham, MA)

    1993-06-15T23:59:59.000Z

    This invention pertains to Li ion (Li.sup.+) conductive solid polymer electrolytes composed of solvates of Li salts immobilized (encapsulated) in a solid organic polymer matrix. In particular, this invention relates to solid polymer electrolytes derived by immobilizing complexes (solvates) formed between a Li salt such as LiAsF.sub.6, LiCF.sub.3 SO.sub.3 or LiClO.sub.4 and a mixture of aprotic organic solvents having high dielectric constants such as ethylene carbonate (EC) (dielectric constant=89.6) and propylene carbonate (PC) (dielectric constant=64.4) in a polymer matrix such as polyacrylonitrile, poly(tetraethylene glycol diacrylate), or poly(vinyl pyrrolidinone).

  1. Multinuclear Solid-State NMR Studies of Polymers and Immobilized Sonogashira Catalysts for Cross-Coupling Reactions

    E-Print Network [OSTI]

    Pope, Jacqueline Christine

    2014-08-28T23:59:59.000Z

    to metals, and their superior corrosion resistance under demanding conditions, e.g. off-shore drilling or fracking operations. Blends of PAEK polymers, such as polyetheretherketones 2 (PEEK) and polyetherketoneketones (PEKK), with polybenzimidazole...

  2. Impact of high-power stress on dynamic ON-resistance of high-voltage GaN HEMTs Donghyun Jin

    E-Print Network [OSTI]

    del Alamo, Jesús A.

    Impact of high-power stress on dynamic ON-resistance of high-voltage GaN HEMTs Donghyun Jin-resistance (RON) in high- voltage GaN High-Electron-Mobility Transistors (HEMTs). We use a newly proposed dynamic. All rights reserved. 1. Introduction In the last decade, GaN Field-Effect Transistors have emerged

  3. Tritium containing polymers having a polymer backbone substantially void of tritium

    DOE Patents [OSTI]

    Jensen, G.A.; Nelson, D.A.; Molton, P.M.

    1992-03-31T23:59:59.000Z

    A radioluminescent light source comprises a solid mixture of a phosphorescent substance and a tritiated polymer. The solid mixture forms a solid mass having length, width, and thickness dimensions, and is capable of self-support. In one aspect of the invention, the phosphorescent substance comprises solid phosphor particles supported or surrounded within a solid matrix by a tritium containing polymer. The tritium containing polymer comprises a polymer backbone which is essentially void of tritium. 2 figs.

  4. Tritium containing polymers having a polymer backbone substantially void of tritium

    DOE Patents [OSTI]

    Jensen, George A. (Richland, WA); Nelson, David A. (Richland, WA); Molton, Peter M. (Richland, WA)

    1992-01-01T23:59:59.000Z

    A radioluminescent light source comprises a solid mixture of a phosphorescent substance and a tritiated polymer. The solid mixture forms a solid mass having length, width, and thickness dimensions, and is capable of self-support. In one aspect of the invention, the phosphorescent substance comprises solid phosphor particles supported or surrounded within a solid matrix by a tritium containing polymer. The tritium containing polymer comprises a polymer backbone which is essentially void of tritium.

  5. Calculation and measurement of a neutral air flow velocity impacting a high voltage capacitor with asymmetrical electrodes

    SciTech Connect (OSTI)

    Malík, M., E-mail: michal.malik@tul.cz; Primas, J.; Kopecký, V.; Svoboda, M. [Faculty of Mechatronics, Informatics and Interdisciplinary Studies, Technical University of Liberec, Liberec, 461 17 (Czech Republic)] [Faculty of Mechatronics, Informatics and Interdisciplinary Studies, Technical University of Liberec, Liberec, 461 17 (Czech Republic)

    2014-01-15T23:59:59.000Z

    This paper deals with the effects surrounding phenomenon of a mechanical force generated on a high voltage asymmetrical capacitor (the so called Biefeld-Brown effect). A method to measure this force is described and a formula to calculate its value is also given. Based on this the authors derive a formula characterising the neutral air flow velocity impacting an asymmetrical capacitor connected to high voltage. This air flow under normal circumstances lessens the generated force. In the following part this velocity is measured using Particle Image Velocimetry measuring technique and the results of the theoretically calculated velocity and the experimentally measured value are compared. The authors found a good agreement between the results of both approaches.

  6. Connecting Renewables Directly to the Grid: Resilient Multi-Terminal HVDC Networks with High-Voltage High-Frequency Electronics

    SciTech Connect (OSTI)

    None

    2012-01-23T23:59:59.000Z

    GENI Project: GE is developing electricity transmission hardware that could connect distributed renewable energy sources, like wind farms, directly to the grid—eliminating the need to feed the energy generated through intermediate power conversion stations before they enter the grid. GE is using the advanced semiconductor material silicon carbide (SiC) to conduct electricity through its transmission hardware because SiC can operate at higher voltage levels than semiconductors made out of other materials. This high-voltage capability is important because electricity must be converted to high-voltage levels before it can be sent along the grid’s network of transmission lines. Power companies do this because less electricity is lost along the lines when the voltage is high.

  7. High voltage power supply. (Latest citations from the US Patent bibliographic file with exemplary claims). Published Search

    SciTech Connect (OSTI)

    NONE

    1996-03-01T23:59:59.000Z

    The bibliography contains citations of selected patents concerning high voltage power supply systems and devices. References describe direct and high current power supplies, microprocessor controlled and programmable systems, amplifiers, power supply stabilization, power circuit protection, feedback control, and pulse modulation. Applications cover laser systems, x-ray tubes, electrophoresis, video apparatus, radar and electronic warfare systems, helmet mounted display, and electrosurgery. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  8. High voltage power supply. (Latest citations from the US Patent bibliographic file with exemplary claims). Published Search

    SciTech Connect (OSTI)

    NONE

    1997-06-01T23:59:59.000Z

    The bibliography contains citations of selected patents concerning high voltage power supply systems and devices. References describe direct and high current power supplies, microprocessor controlled and programmable systems, amplifiers, power supply stabilization, power circuit protection, feedback control, and pulse modulation. Applications cover laser systems, x-ray tubes, electrophoresis, video apparatus, radar and electronic warfare systems, helmet mounted display, and electrosurgery. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  9. Electrochromic window based on poly(aniline-N-butylsulfonate)s with a radiation-cured solid polymer electrolyte film

    SciTech Connect (OSTI)

    Kim, E.; Lee, K.; Rhee, S.B. [Korea Research Inst. of Chemical Technology, Yusung, Taejeon (Korea, Republic of). Advanced Polymer Division

    1997-01-01T23:59:59.000Z

    Electrochromic properties of poly(aniline N-butylsulfonate)s (PANBUS) coatings on indium-tin oxide (ITO) glasses exposed to an ion conducting polymer films were investigated. The ion conducting polymer films were prepared via photocross-linking reactions of methoxy polyethylene glycol-mono methacrylate with tri(propylene glycol) diacrylate in the presence of a photoinitiator and LiClO{sub 4}. Mechanical properties of the electrolyte film were enhanced by introducing styrene or butylmethacrylate into the polymer network. Color contrast and optical response of the PANBUS-based window were improved by adding Nafion into the electrolyte. The electrochromic (EC) window assembled with PANBUS, Nafion containing polymer electrolyte film, and tungsten trioxide coated ITO glass (type 2) required less energy for operation ({+-}1.5 V) compared to the EC window without tungsten trioxide film (type 1, {+-}2.0 V). By applying {+-}1.5 V, optical density of the type 2 window changed from zero to maximum of 1.2, corresponding transmission change of higher than 95%. Lifetime tests show that the type 2 window could support more than 2.3 {times} 10{sup 3} cycles, of 60 s duration.

  10. Preprint submitted to International Journal of Solids and Structures 1 PREDICTING THERMAL SHAPE MEMORY OF CROSSLINKED POLYMER NETWORKS FROM LINEAR

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    . ABSTRACT: The viscoelastic behavior of an amorphous shape-memory polymer network and its dependence on time was evaluated by comparison with experimental shape memory thermomechanical torsion data in a large deformation regimen. The simulations showed excellent agreement with experimental shape memory thermomechanical cycle

  11. Process to produce lithium-polymer batteries

    DOE Patents [OSTI]

    MacFadden, Kenneth Orville (Highland, MD)

    1998-01-01T23:59:59.000Z

    A polymer bonded sheet product suitable for use as an electrode in a non-aqueous battery system. A porous electrode sheet is impregnated with a solid polymer electrolyte, so as to diffuse into the pores of the electrode. The composite is allowed to cool, and the electrolyte is entrapped in the porous electrode. The sheet products composed have the solid polymer electrolyte composition diffused into the active electrode material by melt-application of the solid polymer electrolyte composition into the porous electrode material sheet. The solid polymer electrolyte is maintained at a temperature that allows for rapid diffusion into the pores of the electrode. The composite electrolyte-electrode sheets are formed on current collectors and can be coated with solid polymer electrolyte prior to battery assembly. The interface between the solid polymer electrolyte composite electrodes and the solid polymer electrolyte coating has low resistance.

  12. Process to produce lithium-polymer batteries

    DOE Patents [OSTI]

    MacFadden, K.O.

    1998-06-30T23:59:59.000Z

    A polymer bonded sheet product is described suitable for use as an electrode in a non-aqueous battery system. A porous electrode sheet is impregnated with a solid polymer electrolyte, so as to diffuse into the pores of the electrode. The composite is allowed to cool, and the electrolyte is entrapped in the porous electrode. The sheet products composed have the solid polymer electrolyte composition diffused into the active electrode material by melt-application of the solid polymer electrolyte composition into the porous electrode material sheet. The solid polymer electrolyte is maintained at a temperature that allows for rapid diffusion into the pores of the electrode. The composite electrolyte-electrode sheets are formed on current collectors and can be coated with solid polymer electrolyte prior to battery assembly. The interface between the solid polymer electrolyte composite electrodes and the solid polymer electrolyte coating has low resistance. 1 fig.

  13. Measurement of low radioactivity background in a high voltage cable by high resolution inductively coupled plasma mass spectrometry

    SciTech Connect (OSTI)

    Vacri, M. L. di; Nisi, S.; Balata, M. [Gran Sasso National Laboratory, Chemistry Service, SS 17bis km 18.910, 67100 Assergi (Aq) (Italy)] [Gran Sasso National Laboratory, Chemistry Service, SS 17bis km 18.910, 67100 Assergi (Aq) (Italy)

    2013-08-08T23:59:59.000Z

    The measurement of naturally occurring low level radioactivity background in a high voltage (HV) cable by high resolution inductively coupled plasma mass spectrometry (HR ICP MS) is presented in this work. The measurements were performed at the Chemistry Service of the Gran Sasso National Laboratory. The contributions to the radioactive background coming from the different components of the heterogeneous material were separated. Based on the mass fraction of the cable, the whole contamination was calculated. The HR ICP MS results were cross-checked by gamma ray spectroscopy analysis that was performed at the low background facility STELLA (Sub Terranean Low Level Assay) of the LNGS underground lab using HPGe detectors.

  14. Study of static reactive power compensators for high-voltage power systems. Final report, May 12, 1981

    SciTech Connect (OSTI)

    Byerly, R.T.; Bennon, R.J.; Taylor, E.R. Jr.; Poznaniak, D.T.

    1981-05-12T23:59:59.000Z

    A general study of the application of static VAR compensators (SVC's) to high-voltage transmission systems has been performed. Considerable emphasis has been placed on improvements to synchronous stability, and it is shown that SVC's can provide significant benefits in terms of damping for unstable modes of oscillation and increases in transient stability limits. This report includes descriptions of static VAR compensators, technical and economic comparisons of different compensators, compensator models for system studies, comprehensive study procedures, study results for two small-scale systems, and guidelines for SVC application.

  15. Recommended practice for fire protection for electric generating plants and high voltage direct current converter stations. 2005 ed.

    SciTech Connect (OSTI)

    NONE

    2005-07-01T23:59:59.000Z

    The standard outlines fire safety recommendations for gas, oil, coal, and alternative fuel electric generating plants including high voltage direct current converter stations and combustion turbine units greater than 7500 hp used for electric generation. Provisions apply to both new and existing plants. The document provides fire prevention and fire protection recommendations for the: safety of construction and operating personnel; physical integrity of plant components; and continuity of plant operations. The 2005 edition includes revisions and new art that clarify existing provisions. 5 annexes.

  16. Analysis of system wide distortion in an integrated power system utilizing a high voltage DC bus and silicon carbide power devices

    E-Print Network [OSTI]

    Fallier, William F. (William Frederick)

    2007-01-01T23:59:59.000Z

    This research investigates the distortion on the electrical distribution system for a high voltage DC Integrated Power System (IPS). The analysis was concentrated on the power supplied to a propulsion motor driven by an ...

  17. An accurate online calibration system based on combined clamp-shape coil for high voltage electronic current transformers

    SciTech Connect (OSTI)

    Li, Zhen-hua; Li, Hong-bin; Zhang, Zhi [CEEE of Huazhong University of Science and Technology, Wuhan 430074 (China) [CEEE of Huazhong University of Science and Technology, Wuhan 430074 (China); State Key Laboratory of Advanced Electromagnetic Engineering and Technology, Wuhan 430074 (China)

    2013-07-15T23:59:59.000Z

    Electronic transformers are widely used in power systems because of their wide bandwidth and good transient performance. However, as an emerging technology, the failure rate of electronic transformers is higher than that of traditional transformers. As a result, the calibration period needs to be shortened. Traditional calibration methods require the power of transmission line be cut off, which results in complicated operation and power off loss. This paper proposes an online calibration system which can calibrate electronic current transformers without power off. In this work, the high accuracy standard current transformer and online operation method are the key techniques. Based on the clamp-shape iron-core coil and clamp-shape air-core coil, a combined clamp-shape coil is designed as the standard current transformer. By analyzing the output characteristics of the two coils, the combined clamp-shape coil can achieve verification of the accuracy. So the accuracy of the online calibration system can be guaranteed. Moreover, by employing the earth potential working method and using two insulating rods to connect the combined clamp-shape coil to the high voltage bus, the operation becomes simple and safe. Tests in China National Center for High Voltage Measurement and field experiments show that the proposed system has a high accuracy of up to 0.05 class.

  18. Charge and fluence lifetime measurements of a dc high voltage GaAs photogun at high average current

    SciTech Connect (OSTI)

    J. Grames, R. Suleiman, P.A. Adderley, J. Clark, J. Hansknecht, D. Machie, M. Poelker, M.L. Stutzman

    2011-04-01T23:59:59.000Z

    GaAs-based dc high voltage photoguns used at accelerators with extensive user programs must exhibit long photocathode operating lifetime. Achieving this goal represents a significant challenge for proposed high average current facilities that must operate at tens of milliamperes or more. This paper describes techniques to maintain good vacuum while delivering beam, and techniques that minimize the ill effects of ion bombardment, the dominant mechanism that reduces photocathode yield of a GaAs-based dc high voltage photogun. Experimental results presented here demonstrate enhanced lifetime at high beam currents by: (a) operating with the drive laser beam positioned away from the electrostatic center of the photocathode, (b) limiting the photocathode active area to eliminate photoemission from regions of the photocathode that do not support efficient beam delivery, (c) using a large drive laser beam to distribute ion damage over a larger area, and (d) by applying a relatively low bias voltage to the anode to repel ions created within the downstream beam line. A combination of these techniques provided the best total charge extracted lifetimes in excess of 1000 C at dc beam currents up to 9.5 mA, using green light illumination of bulk GaAs inside a 100 kV photogun.

  19. Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity

    DOE Patents [OSTI]

    Skotheim, Terje (East Patchogue, NY)

    1986-01-01T23:59:59.000Z

    There is disclosed a polymer blend of a highly conductive polymer and a solid polymer electrolyte that is designed to achieve better charge transfer across the conductive film/polymer electrolyte interface of the electrochemical photovoltaic cell. The highly conductive polymer is preferably polypyrrole or poly-N-p-nitrophenylpyrrole and the solid polymer electrolyte is preferably polyethylene oxide or polypropylene oxide.

  20. Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity

    DOE Patents [OSTI]

    Skotheim, T.

    1984-09-28T23:59:59.000Z

    There is disclosed a polymer blend of a highly conductive polymer and a solid polymer electrolyte that is designed to achieve better charge transfer across the conductive film/polymer electrolyte interface of the electrochemical photovoltaic cell. The highly conductive polymer is preferably polypyrrole or poly-N-p-nitrophenylpyrrole and the solid polymer electrolyte is preferably polyethylene oxide or polypropylene oxide.

  1. High voltage dc--dc converter with dynamic voltage regulation and decoupling during load-generated arcs

    DOE Patents [OSTI]

    Shimer, D.W.; Lange, A.C.

    1995-05-23T23:59:59.000Z

    A high-power power supply produces a controllable, constant high voltage output under varying and arcing loads. The power supply includes a voltage regulator, an inductor, an inverter for producing a high frequency square wave current of alternating polarity, an improved inverter voltage clamping circuit, a step up transformer, an output rectifier for producing a dc voltage at the output of each module, and a current sensor for sensing output current. The power supply also provides dynamic response to varying loads by controlling the voltage regulator duty cycle and circuitry is provided for sensing incipient arc currents at the output of the power supply to simultaneously decouple the power supply circuitry from the arcing load. The power supply includes a plurality of discrete switching type dc--dc converter modules. 5 Figs.

  2. High voltage dc-dc converter with dynamic voltage regulation and decoupling during load-generated arcs

    DOE Patents [OSTI]

    Shimer, Daniel W. (Danville, CA); Lange, Arnold C. (Livermore, CA)

    1995-01-01T23:59:59.000Z

    A high-power power supply produces a controllable, constant high voltage output under varying and arcing loads. The power supply includes a voltage regulator, an inductor, an inverter for producing a high frequency square wave current of alternating polarity, an improved inverter voltage clamping circuit, a step up transformer, an output rectifier for producing a dc voltage at the output of each module, and a current sensor for sensing output current. The power supply also provides dynamic response to varying loads by controlling the voltage regulator duty cycle and circuitry is provided for sensing incipient arc currents at the output of the power supply to simultaneously decouple the power supply circuitry from the arcing load. The power supply includes a plurality of discrete switching type dc--dc converter modules.

  3. Nanosecond pulsed electric fields (nsPEFs) low cost generator design using power MOSFET and Cockcroft-Walton multiplier circuit as high voltage DC source

    SciTech Connect (OSTI)

    Sulaeman, M. Y.; Widita, R. [Department of Physics, Nuclear Physics and Biophysics Research Division, Faculty of Mathematics and Natural Science, Institut Teknologi Bandung, Bandung (Indonesia)

    2014-09-30T23:59:59.000Z

    Purpose: Non-ionizing radiation therapy for cancer using pulsed electric field with high intensity field has become an interesting field new research topic. A new method using nanosecond pulsed electric fields (nsPEFs) offers a novel means to treat cancer. Not like the conventional electroporation, nsPEFs able to create nanopores in all membranes of the cell, including membrane in cell organelles, like mitochondria and nucleus. NsPEFs will promote cell death in several cell types, including cancer cell by apoptosis mechanism. NsPEFs will use pulse with intensity of electric field higher than conventional electroporation, between 20–100 kV/cm and with shorter duration of pulse than conventional electroporation. NsPEFs requires a generator to produce high voltage pulse and to achieve high intensity electric field with proper pulse width. However, manufacturing cost for creating generator that generates a high voltage with short duration for nsPEFs purposes is highly expensive. Hence, the aim of this research is to obtain the low cost generator design that is able to produce a high voltage pulse with nanosecond width and will be used for nsPEFs purposes. Method: Cockcroft-Walton multiplier circuit will boost the input of 220 volt AC into high voltage DC around 1500 volt and it will be combined by a series of power MOSFET as a fast switch to obtain a high voltage with nanosecond pulse width. The motivation using Cockcroft-Walton multiplier is to acquire a low-cost high voltage DC generator; it will use capacitors and diodes arranged like a step. Power MOSFET connected in series is used as voltage divider to share the high voltage in order not to damage them. Results: This design is expected to acquire a low-cost generator that can achieve the high voltage pulse in amount of ?1.5 kV with falltime 3 ns and risetime 15 ns into a 50? load that will be used for nsPEFs purposes. Further detailed on the circuit design will be explained at presentation.

  4. Polymer blends for use in photoelectrochemical cells for conversion of solar energy to electricity and methods for manufacturing such blends

    DOE Patents [OSTI]

    Skotheim, Terje (East Patchogue, NY)

    1984-01-01T23:59:59.000Z

    There is disclosed a polymer blend of a highly conductive polymer and a solid polymer electrolyte that is designed to achieve better charge transfer across the conductive film/polymer electrolyte interface of the electrochemical photovoltaic cell. The highly conductive polymer is preferably polypyrrole or poly-N-p-nitrophenylpyrrole and the solid polymer electrolyte is preferably polyethylene oxide or polypropylene oxide.

  5. Characterization of the Li(Si)/CoS(2) couple for a high-voltage, high-power thermal battery

    SciTech Connect (OSTI)

    GUIDOTTI,RONALD A.; REINHARDT,FREDERICK W.

    2000-02-01T23:59:59.000Z

    In order to determined the capabilities of a thermal battery with high-voltage and high-power requirements, a detailed characterization of the candidate LiSi/LiCl-LiBr-LiF/CoS{sub 2} electrochemical couple was conducted. The rate capability of this system was investigated using 0.75 inch-dia. and 1.25 inch-dia. single and multiple cells under isothermal conditions, where the cells were regularly pulsed at increasingly higher currents. Limitations of the electronic loads and power supplies necessitated using batteries to obtain the desired maximum current densities possible for this system. Both 1.25 inch-dia. and 3 inch-dia. stacks were used with the number of cells ranging from 5 to 20. Initial tests involved 1.25 inch-dia. cells, where current densities in excess of 15 A/cm{sup 2} (>200 W/cm{sup 2}) were attained with 20-cell batteries during 1-s pulses. In subsequent follow-up tests with 3 inch-dia., 10-cell batteries, ten 400-A 1-s pulses were delivered over an operating period often minutes. These tests formed the foundation for subsequent full-sized battery tests with 125 cells with this chemistry.

  6. C-H surface diamond field effect transistors for high temperature (400?°C) and high voltage (500?V) operation

    SciTech Connect (OSTI)

    Kawarada, H., E-mail: kawarada@waseda.jp [Faculty of Science and Engineering, Waseda University, Shinjuku, Tokyo 169-8555 (Japan); Institute of Nano-Science and Nano-Engineering, Waseda University, Shinjuku, Tokyo 169-8555 (Japan); Kagami Memorial Laboratory for Material Science and Technology, Waseda University, Shinjuku, Tokyo 169-0051 (Japan); Tsuboi, H.; Naruo, T.; Yamada, T.; Xu, D.; Daicho, A.; Saito, T. [Faculty of Science and Engineering, Waseda University, Shinjuku, Tokyo 169-8555 (Japan); Hiraiwa, A. [Institute of Nano-Science and Nano-Engineering, Waseda University, Shinjuku, Tokyo 169-8555 (Japan)

    2014-07-07T23:59:59.000Z

    By forming a highly stable Al{sub 2}O{sub 3} gate oxide on a C-H bonded channel of diamond, high-temperature, and high-voltage metal-oxide-semiconductor field-effect transistor (MOSFET) has been realized. From room temperature to 400?°C (673?K), the variation of maximum drain-current is within 30% at a given gate bias. The maximum breakdown voltage (V{sub B}) of the MOSFET without a field plate is 600?V at a gate-drain distance (L{sub GD}) of 7 ?m. We fabricated some MOSFETs for which V{sub B}/L{sub GD}?>?100?V/?m. These values are comparable to those of lateral SiC or GaN FETs. The Al{sub 2}O{sub 3} was deposited on the C-H surface by atomic layer deposition (ALD) at 450?°C using H{sub 2}O as an oxidant. The ALD at relatively high temperature results in stable p-type conduction and FET operation at 400?°C in vacuum. The drain current density and transconductance normalized by the gate width are almost constant from room temperature to 400?°C in vacuum and are about 10 times higher than those of boron-doped diamond FETs.

  7. Epidemiologic study of Holstein dairy cow performance and reproduction near a high-voltage direct - current powerline

    SciTech Connect (OSTI)

    Martin, F.B.; Bender, A.; Steuernagel, G.; Robinson, R.A.; Revsbech, R.; Sorensen, D.K.; Williamson, N.; Williams, A.

    1986-01-01T23:59:59.000Z

    The development and operation of a high-voltage direct-current (HVDC) transmission line in rural Minnesota generated public concern over potential adverse effects to nearby residents and their livestock. Electrical parameters near an HVDC line decline rapidly with distance, but effects on ambient space charge have been detected out to 1 mile. To identify potential adverse effects of HVDC line operation on livestock, case-control and cohort study methods were used to examine various indices of Holstein performance in relation to distance from the line and the onset of line operation. It was believed that these indices would reflect changes in physiologic function or overt health effects that might arise from the HVDC environment. High-quality performance data from existing Dairy Herd Improvement Association (DHIA) records were obtained for 97% of qualifying herds located within 10 miles of the line. The large number of animals and years of observation provided high statistical power to detect even small systematic changes in performance. No significant differences in milk production or reproductive capacity were associated with presumed exposure to the HVDC environment. The absence of measurable effects in a large sentinel animal population may have implications for the assessment of human health risks related to HVDC transmission lines.

  8. Effect of High-Voltage Heterojunction Bipolar Transistor Collector Design on f(T) and f(MAX)

    SciTech Connect (OSTI)

    Ashby, C.I.H.; Baca, A.G.; Chang, P.C.; Hietala, V.M.

    1999-03-02T23:59:59.000Z

    High-speed InGaP/GaAs heterojunction bipolar transistors (HBTs) for high-voltage circuit applications have been investigated. In order to obtain ideal IV characteristics, a lightly doped (N{sub DC} = 7.5 x 10{sup 15} cm{sup {minus}3}) thick (W{sub C} = 3.5 {micro}m) layer of GaAs was used as the collector layer. The devices fabricated have shown breakdown voltage exceeding 65 V. Device operated at up to a 60V bias, which is the highest operating voltage reported up to date for single heterojunction HBTs. Peak {line_integral}{sub T} and {line_integral}{sub MAX} values of 18 GHz and 29 GHz, respectively, have been achieved on a device with emitter area of 4x 12.5 {micro}m{sup 2}. Both {line_integral}{sub T} and {line_integral}{sub Max} degrades with higher bias, which is related to the elongation of the collector depletion width.

  9. Graphene-oxide-coated LiNi0.5Mn1.5O4 as high voltage cathode for lithium ion batteries with high energy

    E-Print Network [OSTI]

    Zhou, Chongwu

    Graphene-oxide-coated LiNi0.5Mn1.5O4 as high voltage cathode for lithium ion batteries with high Since Sony rst commercialized lithium ion batteries in the early 1990s, the market for lithium ion of the great success of lithium ion battery technology developed for portable electronic devices, higher

  10. Method and system for making integrated solid-state fire-sets and detonators

    DOE Patents [OSTI]

    O`Brien, D.W.; Druce, R.L.; Johnson, G.W.; Vogtlin, G.E.; Barbee, T.W. Jr.; Lee, R.S.

    1998-03-24T23:59:59.000Z

    A slapper detonator comprises a solid-state high-voltage capacitor, a low-jitter dielectric breakdown switch and trigger circuitry, a detonator transmission line, an exploding foil bridge, and a flier material. All these components are fabricated in a single solid-state device using thin film deposition techniques. 13 figs.

  11. Method and system for making integrated solid-state fire-sets and detonators

    DOE Patents [OSTI]

    O'Brien, Dennis W. (Livermore, CA); Druce, Robert L. (Union City, CA); Johnson, Gary W. (Livermore, CA); Vogtlin, George E. (Fremont, CA); Barbee, Jr., Troy W. (Palo Alto, CA); Lee, Ronald S. (Livermore, CA)

    1998-01-01T23:59:59.000Z

    A slapper detonator comprises a solid-state high-voltage capacitor, a low-jitter dielectric breakdown switch and trigger circuitry, a detonator transmission line, an exploding foil bridge, and a flier material. All these components are fabricated in a single solid-state device using thin film deposition techniques.

  12. Polymer films

    DOE Patents [OSTI]

    Granick, Steve (Champaign, IL); Sukhishvili, Svetlana A. (Maplewood, NJ)

    2008-12-30T23:59:59.000Z

    A film contains a first polymer having a plurality of hydrogen bond donating moieties, and a second polymer having a plurality of hydrogen bond accepting moieties. The second polymer is hydrogen bonded to the first polymer.

  13. Conductive Polymers

    SciTech Connect (OSTI)

    Bohnert, G.W.

    2002-11-22T23:59:59.000Z

    Electroluminescent devices such as light-emitting diodes (LED) and high-energy density batteries. These new polymers offer cost savings, weight reduction, ease of processing, and inherent rugged design compared to conventional semiconductor materials. The photovoltaic industry has grown more than 30% during the past three years. Lightweight, flexible solar modules are being used by the U.S. Army and Marine Corps for field power units. LEDs historically used for indicator lights are now being investigated for general lighting to replace fluorescent and incandescent lights. These so-called solid-state lights are becoming more prevalent across the country since they produce efficient lighting with little heat generation. Conductive polymers are being sought for battery development as well. Considerable weight savings over conventional cathode materials used in secondary storage batteries make portable devices easier to carry and electric cars more efficient and nimble. Secondary battery sales represent an $8 billion industry annually. The purpose of the project was to synthesize and characterize conductive polymers. TRACE Photonics Inc. has researched critical issues which affect conductivity. Much of their work has focused on production of substituted poly(phenylenevinylene) compounds. These compounds exhibit greater solubility over the parent polyphenylenevinylene, making them easier to process. Alkoxy substituted groups evaluated during this study included: methoxy, propoxy, and heptyloxy. Synthesis routes for production of alkoxy-substituted poly phenylenevinylene were developed. Considerable emphasis was placed on final product yield and purity.

  14. Statistical analysis of the dynamics of secondary electrons in the flare of a high-voltage beam-type discharge

    SciTech Connect (OSTI)

    Demkin, V. P.; Mel'nichuk, S. V. [National Research Tomsk State University, 36, Lenin Ave., 634050 Tomsk (Russian Federation)

    2014-09-15T23:59:59.000Z

    In the present work, results of investigations into the dynamics of secondary electrons with helium atoms in the presence of the reverse electric field arising in the flare of a high-voltage pulsed beam-type discharge and leading to degradation of the primary electron beam are presented. The electric field in the discharge of this type at moderate pressures can reach several hundred V/cm and leads to considerable changes in the kinetics of secondary electrons created in the process of propagation of the electron beam generated in the accelerating gap with a grid anode. Moving in the accelerating electric field toward the anode, secondary electrons create the so-called compensating current to the anode. The character of electron motion and the compensating current itself are determined by the ratio of the field strength to the concentration of atoms (E/n). The energy and angular spectra of secondary electrons are calculated by the Monte Carlo method for different ratios E/n of the electric field strength to the helium atom concentration. The motion of secondary electrons with threshold energy is studied for inelastic collisions of helium atoms and differential analysis is carried out of the collisional processes causing energy losses of electrons in helium for different E/n values. The mechanism of creation and accumulation of slow electrons as a result of inelastic collisions of secondary electrons with helium atoms and selective population of metastable states of helium atoms is considered. It is demonstrated that in a wide range of E/n values the motion of secondary electrons in the beam-type discharge flare has the character of drift. At E/n values characteristic for the discharge of the given type, the drift velocity of these electrons is calculated and compared with the available experimental data.

  15. Radioluminescent light sources, tritium containing polymers, and methods for producing the same

    DOE Patents [OSTI]

    Jensen, G.A.; Nelson, D.A.; Molton, P.M.

    1989-12-26T23:59:59.000Z

    A radioluminescent light source comprises a solid mixture of a phosphorescent substance and a tritiated polymer. The solid mixture forms a solid mass having length, width, and thickness dimensions, and is capable of self-support. In one aspect of the invention, the phosphorescent substance comprises solid phosphor particles supported or surrounded within a solid matrix by a tritium containing polymer. The tritium containing polymer comprises a polymer backbone which is essentially void of tritium. 2 figs.

  16. Radioluminescent light sources, tritium containing polymers, and methods for producing the same

    DOE Patents [OSTI]

    Jensen, George A. (Richland, WA); Nelson, David A. (Richland, WA); Molton, Peter M. (Richland, WA)

    1989-01-01T23:59:59.000Z

    A radioluminescent light source comprises a solid mixture of a phosphorescent substance and a tritiated polymer. The solid mixture forms a solid mass having length, width, and thickness dimensions, and is capable of self-support. In one aspect of the invention, the phosphorescent substance comprises solid phosphor particles supported or surrounded within a solid matix by a tritium containing polymer. The tritium containing polymer comprises a polymer backbone which is essentially void of tritium.

  17. HIGH VOLTAGE TERMINAL IN COSY ELECTRON COOLER V.A. Chekavinskiy, E.A. Bekhtenev, I.A. Gusev, M.N. Kondaurov, V.R. Kozak, E.A. Kuper, V.R.

    E-Print Network [OSTI]

    Kozak, Victor R.

    HIGH VOLTAGE TERMINAL IN COSY ELECTRON COOLER V.A. Chekavinskiy, E.A. Bekhtenev, I.A. Gusev, M acceleration system ­ high voltage terminal. All power and control electronics were placed in a single isolated Voltage Terminal (HVT) in electron cooler is intended for generating of electron cooling beam

  18. AlGaN/GaN High-Electron-Mobility Transistor Employing an Additional Gate for High-Voltage Switching Applications

    E-Print Network [OSTI]

    Seo, Kwang Seok

    AlGaN/GaN High-Electron-Mobility Transistor Employing an Additional Gate for High-Voltage Switching 16, 2004; accepted May 10, 2005; published September 8, 2005) We have proposed and fabricated an AlGaN/GaN: GaN, AlGaN, HEMT, switch 1. Introduction GaN has attracted attention for high-power and high

  19. Solid polymeric electrolytes for lithium batteries

    DOE Patents [OSTI]

    Angell, Charles A.; Xu, Wu; Sun, Xiaoguang

    2006-03-14T23:59:59.000Z

    Novel conductive polyanionic polymers and methods for their preparion are provided. The polyanionic polymers comprise repeating units of weakly-coordinating anionic groups chemically linked to polymer chains. The polymer chains in turn comprise repeating spacer groups. Spacer groups can be chosen to be of length and structure to impart desired electrochemical and physical properties to the polymers. Preferred embodiments are prepared from precursor polymers comprising the Lewis acid borate tri-coordinated to a selected ligand and repeating spacer groups to form repeating polymer chain units. These precursor polymers are reacted with a chosen Lewis base to form a polyanionic polymer comprising weakly coordinating anionic groups spaced at chosen intervals along the polymer chain. The polyanionic polymers exhibit high conductivity and physical properties which make them suitable as solid polymeric electrolytes in lithium batteries, especially secondary lithium batteries.

  20. Preparation of redox polymer cathodes for thin film rechargeable batteries

    DOE Patents [OSTI]

    Skotheim, T.A.; Lee, H.S.; Okamoto, Yoshiyuki.

    1994-11-08T23:59:59.000Z

    The present invention relates to the manufacture of thin film solid state electrochemical devices using composite cathodes comprising a redox polymer capable of undergoing oxidation and reduction, a polymer solid electrolyte and conducting carbon. The polymeric cathode material is formed as a composite of radiation crosslinked polymer electrolytes and radiation crosslinked redox polymers based on polysiloxane backbones with attached organosulfur side groups capable of forming sulfur-sulfur bonds during electrochemical oxidation.

  1. CIGRE WG 13.06 studies on the reliability of single pressure SF6-gas high-voltage circuit-breakers

    SciTech Connect (OSTI)

    Janssen, A.L.J. [KEMA, Arnhem (Netherlands)] [KEMA, Arnhem (Netherlands); Brunke, J.H.; Heising, C.R.; Lanz, W.

    1996-01-01T23:59:59.000Z

    The final results of the CIGRE second international inquiry on the reliability of high voltage circuit-breakers in service are presented. In the seventies the first international inquiry, that covered all technology circuit-breakers, was conducted. The second international inquiry was limited to single pressure SF6 gas circuit-breakers, thus showing the improvements due to this technology. The main conclusion is that the reliability concerning Major Failures has increased considerably and that the maintainability of modern SF6 circuit-breakers is much better than the older technology circuit-breakers. Also the conclusions from several other studies, based on the results of the inquiries, are presented.

  2. Solid-state radioluminescent compositions

    DOE Patents [OSTI]

    Clough, Roger L. (Albuquerque, NM); Gill, John T. (Miamisburg, OH); Hawkins, Daniel B. (Fairbanks, AK); Renschler, Clifford L. (Tijeras, NM); Shepodd, Timothy J. (Livermore, CA); Smith, Henry M. (Overland Park, KS)

    1991-01-01T23:59:59.000Z

    A solid state radioluminescent composition for light source comprises an optically clear polymer organic matrix containing tritiated organic materials and dyes capable of "red" shifting primary scintillation emissions from the polymer matrix. The tritiated organic materials are made by reducing, with tritium, an unsaturated organic compound that prior to reduction contains olefinic or alkynylic bonds.

  3. Continuous process to produce lithium-polymer batteries

    DOE Patents [OSTI]

    Chern, Terry Song-Hsing (Midlothian, VA); Keller, David Gerard (Baltimore, MD); MacFadden, Kenneth Orville (Highland, MD)

    1998-01-01T23:59:59.000Z

    Solid polymer electrolytes are extruded with active electrode material in a continuous, one-step process to form composite electrolyte-electrodes ready for assembly into battery cells. The composite electrolyte-electrode sheets are extruded onto current collectors to form electrodes. The composite electrodes, as extruded, are electronically and ionically conductive. The composite electrodes can be overcoated with a solid polymer electrolyte, which acts as a separator upon battery assembly. The interface between the solid polymer electrolyte composite electrodes and the solid polymer electrolyte separator has low resistance.

  4. Continuous process to produce lithium-polymer batteries

    DOE Patents [OSTI]

    Chern, T.S.H.; Keller, D.G.; MacFadden, K.O.

    1998-05-12T23:59:59.000Z

    Solid polymer electrolytes are extruded with active electrode material in a continuous, one-step process to form composite electrolyte-electrodes ready for assembly into battery cells. The composite electrolyte electrode sheets are extruded onto current collectors to form electrodes. The composite electrodes, as extruded, are electronically and ionically conductive. The composite electrodes can be over coated with a solid polymer electrolyte, which acts as a separator upon battery assembly. The interface between the solid polymer electrolyte composite electrodes and the solid polymer electrolyte separator has low resistance. 1 fig.

  5. Improving the performance of stainless-steel DC high voltage photoelectron gun cathode electrodes via gas conditioning with helium or krypton

    SciTech Connect (OSTI)

    Bastaninejad, Mahzad [ODU; Elmustafa, Abdelmageed [ODU; Forman, Eric I. [JLAB; Clark, James [JLAB; Covert, Steven R. [JLAB; Grames, Joseph M. [JLAB; Hansknecht, John C. [JLAB; Hernandez-Garcia, Carlos [JLAB; Poelker, Bernard [JLAB; Suleiman, Riad S. [JLAB

    2014-10-01T23:59:59.000Z

    Gas conditioning was shown to eliminate field emission from cathode electrodes used inside DC high voltage photoelectron guns, thus providing a reliable means to operate photoguns at higher voltages and field strengths. Measurements and simulation results indicate that gas conditioning eliminates field emission from cathode electrodes via two mechanisms: sputtering and implantation, with the benefits of implantation reversed by heating the electrode. We have studied five stainless steel electrodes (304L and 316LN) that were polished to approximately 20 nm surface roughness using diamond grit, and evaluated inside a high voltage apparatus to determine the onset of field emission as a function of voltage and field strength. The field emission characteristics of each electrode varied significantly upon the initial application of voltage but improved to nearly the same level after gas conditioning using either helium or krypton, exhibiting less than 10 pA field emission at ?225 kV bias voltage with a 50 mm cathode/anode gap, corresponding to a field strength of ~13 MV/m. Field emission could be reduced with either gas, but there were conditions related to gas choice, voltage and field strength that were more favorable than others.

  6. Method of forming a foamed thermoplastic polymer

    DOE Patents [OSTI]

    Duchane, D.V.; Cash, D.L.

    1984-11-21T23:59:59.000Z

    A solid thermoplastic polymer is immersed in an immersant solution comprising a compatible carrier solvent and an infusant solution containing an incompatible liquid blowing agent for a time sufficient for the immersant solution to infuse into the polymer. The carrier solvent is then selectively extracted, preferably by a solvent exchange process in which the immersant solution is gradually diluted with and replaced by the infusant solution, so as to selectively leave behind the infustant solution permanently entrapped in the polymer. The polymer is then heated to volatilize the blowing agent and expand the polymer into a foamed state.

  7. High cation transport polymer electrolyte

    DOE Patents [OSTI]

    Gerald, II, Rex E. (Brookfield, IL); Rathke, Jerome W. (Homer Glen, IL); Klingler, Robert J. (Westmont, IL)

    2007-06-05T23:59:59.000Z

    A solid state ion conducting electrolyte and a battery incorporating same. The electrolyte includes a polymer matrix with an alkali metal salt dissolved therein, the salt having an anion with a long or branched chain having not less than 5 carbon or silicon atoms therein. The polymer is preferably a polyether and the salt anion is preferably an alkyl or silyl moiety of from 5 to about 150 carbon/silicon atoms.

  8. Charging a Battery-Powered Device with a Fiber-Optically Connected Photonic Power System for Achieving High-Voltage Isolation

    SciTech Connect (OSTI)

    Lizon, David C [Los Alamos National Laboratory; Gioria, Jack G [Los Alamos National Laboratory; Dale, Gregory E [Los Alamos National Laboratory; Snyder, Hans R [Los Alamos National Laboratory

    2008-01-01T23:59:59.000Z

    This paper describes the development and testing of a system to provide isolated power to the cathode-subsystem electronics of an x-ray tube. These components are located at the cathode potential of several hundred kilovolts, requiring a supply of power isolated from this high voltage. In this design a fiber-optically connected photonic power system (PPS) is used to recharge a lithium-ion battery pack, which will subsequently supply power to the cathode-subsystem electronics. The suitability of the commercially available JDSU PPS for this application is evaluated. The output of the ppe converter is characterized. The technical aspects of its use for charging a variety of Li-Ion batteries are discussed. Battery charge protection requirements and safety concerns are also addressed.

  9. High elastic modulus polymer electrolytes

    DOE Patents [OSTI]

    Balsara, Nitash Pervez; Singh, Mohit; Eitouni, Hany Basam; Gomez, Enrique Daniel

    2013-10-22T23:59:59.000Z

    A polymer that combines high ionic conductivity with the structural properties required for Li electrode stability is useful as a solid phase electrolyte for high energy density, high cycle life batteries that do not suffer from failures due to side reactions and dendrite growth on the Li electrodes, and other potential applications. The polymer electrolyte includes a linear block copolymer having a conductive linear polymer block with a molecular weight of at least 5000 Daltons, a structural linear polymer block with an elastic modulus in excess of 1.times.10.sup.7 Pa and an ionic conductivity of at least 1.times.10.sup.-5 Scm.sup.-1. The electrolyte is made under dry conditions to achieve the noted characteristics.

  10. ABBGroup-1-High voltage lab

    E-Print Network [OSTI]

    Basse, Nils Plesner

    . GENERATION System voltage: 12-24 kV Rated current: 6000-24000 A Max. short-circuit current: 50-500 kA TRANSMISSION System voltage: 72-800 kV Rated current: 2500-4000 A Max. short-circuit current: 25-63 k. It is designed to protect an electrical circuit from damage caused by overload or short-circuit. A circuit

  11. High voltage MOSFET switching circuit

    DOE Patents [OSTI]

    McEwan, T.E.

    1994-07-26T23:59:59.000Z

    The problem of source lead inductance in a MOSFET switching circuit is compensated for by adding an inductor to the gate circuit. The gate circuit inductor produces an inductive spike which counters the source lead inductive drop to produce a rectangular drive voltage waveform at the internal gate-source terminals of the MOSFET. 2 figs.

  12. High voltage MOSFET switching circuit

    DOE Patents [OSTI]

    McEwan, Thomas E. (Livermore, CA)

    1994-01-01T23:59:59.000Z

    The problem of source lead inductance in a MOSFET switching circuit is compensated for by adding an inductor to the gate circuit. The gate circuit inductor produces an inductive spike which counters the source lead inductive drop to produce a rectangular drive voltage waveform at the internal gate-source terminals of the MOSFET.

  13. Inner surface flash-over of insulator of low-inductance high-voltage self-breakdown gas switch and its application

    SciTech Connect (OSTI)

    Zhang, Hong-bo, E-mail: walkman67@163.com; Liu, Jin-liang [College of Opto-electronic Science and Engineering, National University of Defense Technology, Changsha, Hunan 410073 (China)] [College of Opto-electronic Science and Engineering, National University of Defense Technology, Changsha, Hunan 410073 (China)

    2014-04-15T23:59:59.000Z

    In this paper, the inner surface flash-over of high-voltage self-breakdown switch, which is used as a main switch of pulse modulator, is analyzed in theory by employing the method of distributed element equivalent circuit. Moreover, the field distortion of the switch is simulated by using software. The results of theoretical analysis and simulation by software show that the inner surface flash-over usually starts at the junction points among the stainless steel, insulator, and insulation gas in the switch. A switch with improved structure is designed and fabricated according to the theoretical analysis and simulation results. Several methods to avoid inner surface flash-over are used to improve the structure of switch. In experiment, the inductance of the switch is no more than 100 nH, the working voltage of the switch is about 600 kV, and the output voltage and current of the accelerator is about 500 kV and 50 kA, respectively. And the zero-to-peak rise time of output voltage at matched load is less than 30 ns due to the small inductance of switch. The original switch was broken-down after dozens of experiments, and the improved switch has been worked more than 200 times stably.

  14. Effect of the change in the load resistance on the high voltage pulse transformer of the intense electron-beam accelerators

    SciTech Connect (OSTI)

    Cheng Xinbing; Liu Jinliang; Qian Baoliang; Zhang Yu; Zhang Hongbo [College of Photoelectrical Science and Engineering, National University of Defense Technology, Hunan 410073 (China)

    2009-11-15T23:59:59.000Z

    A high voltage pulse transformer (HVPT) is usually used as a charging device for the pulse forming line (PFL) of intense electron-beam accelerators (IEBAs). Insulation of the HVPT is one of the important factors that restrict the development of the HVPT. Until now, considerable effort has been focused on minimizing high field regions to avoid insulation breakdown between windings. Characteristics of the HVPT have been widely discussed to achieve these goals, but the effects of the PFL and load resistance on HVPT are usually neglected. In this paper, a HVPT is used as a charging device for the PFL of an IEBA and the effect of the change in the load resistance on the HVPT of the IEBA is presented. When the load resistance does not match the wave impedance of the PFL, a high-frequency bipolar oscillating voltage will occur, and the amplitude of the oscillating voltage will increase with the decrease in the load resistance. The load resistance approximates to zero and the amplitude of the oscillating voltage is much higher. This makes it easier for surface flashover along the insulation materials to form and decrease the lifetime of the HVPT.

  15. Investigation of the spatiotemporal characteristics of the electric field in the Ne-H{sub 2} plasma of a beam-type high-voltage pulsed discharge

    SciTech Connect (OSTI)

    Demkin, V. P.; Mel'nichuk, S. V.; Borisov, A. V.; Bardin, S. S. [National Research Tomsk State University, 36, Lenin Ave., 634050 Tomsk (Russian Federation)] [National Research Tomsk State University, 36, Lenin Ave., 634050 Tomsk (Russian Federation)

    2013-12-15T23:59:59.000Z

    In the present work, the spatiotemporal dynamics of the electric field E(x, t) of plasma produced by a beam-type high-voltage pulsed discharge is investigated. The electric field strength E(x, t) in an accelerating gap and in a plasma flare was determined from the measured Stark splitting of the H{sub ?} hydrogen line. The obtained dependence E(x, t) was used to calculate the electron distribution function and the spectral line intensities in the accelerating gap and in the plasma flare by the method of statistical modeling. The calculated population of He atomic states excited by electron impact and their comparison with the measured spectral line intensities I(?, x, t) demonstrate that a reverse electric field retarding the electron motion and leading to electron beam degradation must be present in the plasma flare near the grid. Measurement of the field strength from the Stark splitting of the H{sub ?} line demonstrates that it can reach considerable values.

  16. Total current collapse in High-Voltage GaN MIS-HEMTs induced by Zener trapping D. Jin, J. Joh*, S. Krishnan*, N. Tipirneni*, S. Pendharkar* and J. A. del Alamo

    E-Print Network [OSTI]

    del Alamo, Jesús A.

    Total current collapse in High-Voltage GaN MIS-HEMTs induced by Zener trapping D. Jin, J. Joh*, S collapse in GaN MIS-HEMTs for >600 V operation. Extreme trapping leading to total current collapse has been trapping ("Zener trapping") inside the AlGaN barrier or the GaN channel layers. The trapping takes place

  17. Electronically conductive polymer composites and microstructures

    SciTech Connect (OSTI)

    Van Dyke, L.S.

    1993-01-01T23:59:59.000Z

    Composites of electronically conductive polymers with insulating host materials are investigated. A template synthesis method was developed for the production of electronically conductive polymer microstructures. In template synthesis the pores of a porous host membrane act as templates for the polymerization of a conductive polymer. The template synthetic method can be used to form either solid microfibrils or hollow microtubules. The electrochemical properties of conductive polymers produced via the template synthesis method are superior to those of conventionally synthesized conductive polymers. Electronically conductive polymers are used to impart conductivity to non-conductive materials. Two different approaches are used. First, thin film composites of conductive polymers with fluoropolymers are made by the polymerization of conductive polymers onto fluoropolymer films. Modification of the fluoropolymer surface prior to conductive polymer polymerization is necessary to obtain good adhesion between the two materials. The difference in adhesion of the conductive polymer to the modified and unmodified fluoropolymer surfaces can be used to pattern the conductive polymer coating. Patterning of the conductive polymer coating can alternatively be done via UV laser ablation of the conductive polymer. The second method by which conductive polymers were used to impart conductivity to an insulating polymer was via the formation of a graft copolymer. In this approach, heterocyclic monomers grafted to an insulating polyphosphazene backbone were polymerized to yield semiconductive materials. Finally the measurement of electrolyte concentration in polypyrrole and the effects of hydroxide anion on the electrochemical and electrical properties of polypyrrole are described. It is shown that treatment of polypyrrole with hydroxide anion increases the potential window over which polypyrrole is a good electronic conductor.

  18. Dielectric Actuation of Polymers

    E-Print Network [OSTI]

    Niu, Xiaofan

    2013-01-01T23:59:59.000Z

    S. Stanford, Interpenetrating polymer networks for high-based on interpenetrating polymer networks, Proceeding ofX. Niu, Q. Pei, Interpenetrating polymer networks based on

  19. Branched Polymers

    E-Print Network [OSTI]

    Richard Kenyon; Peter Winkler

    2007-09-14T23:59:59.000Z

    Building on and from the work of Brydges and Imbrie, we give an elementary calculation of the volume of the space of branched polymers of order $n$ in the plane and in 3-space. Our development reveals some more general identities, and allows exact random sampling. In particular we show that a random 3-dimensional branched polymer of order $n$ has diameter of order $\\sqrt{n}$.

  20. Dielectric-wall linear accelerator with a high voltage fast rise time switch that includes a pair of electrodes between which are laminated alternating layers of isolated conductors and insulators

    DOE Patents [OSTI]

    Caporaso, G.J.; Sampayan, S.E.; Kirbie, H.C.

    1998-10-13T23:59:59.000Z

    A dielectric-wall linear accelerator is improved by a high-voltage, fast rise-time switch that includes a pair of electrodes between which are laminated alternating layers of isolated conductors and insulators. A high voltage is placed between the electrodes sufficient to stress the voltage breakdown of the insulator on command. A light trigger, such as a laser, is focused along at least one line along the edge surface of the laminated alternating layers of isolated conductors and insulators extending between the electrodes. The laser is energized to initiate a surface breakdown by a fluence of photons, thus causing the electrical switch to close very promptly. Such insulators and lasers are incorporated in a dielectric wall linear accelerator with Blumlein modules, and phasing is controlled by adjusting the length of fiber optic cables that carry the laser light to the insulator surface. 12 figs.

  1. Insight into the Atomic Structure of High-Voltage Spinel LiNi0.5Mn1.5O4 Cathode Material in the First Cycle

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Huang, Xuejie; Yu, Xiqian; Lin, Mingxiang; Ben, Liubin; Sun, Yang; Wang, Hao; Yang, Zhenzhong; Gu, Lin; Yang, Xiao -Qing; Zhao, Haofei; et al

    2015-01-13T23:59:59.000Z

    Application of high-voltage spinel LiNi0.5Mn1.5O4 cathode material is the closest and the most realistic approach to meeting the midterm goal of lithium-ion batteries for electric vehicles (EVs) and plug-in hybrid electric vehicles (HEVs). However, this application has been hampered by long-standing issues, such as capacity degradation and poor first-cycle Coulombic efficiency of LiNi0.5Mn1.5O4 cathode material. Although it is well-known that the structure of LiNi0.5Mn1.5O4 into which Li ions are reversibly intercalated plays a critical role in the above issues, performance degradation related to structural changes, particularly in the first cycle, are not fully understood. Here, we report detailed investigations ofmore »local atomic-level and average structure of LiNi0.5Mn1.5O4 during first cycle (3.5–4.9 V) at room temperature. We observed two types of local atomic-level migration of transition metals (TM) ions in the cathode of a well-prepared LiNi0.5Mn1.5O4//Li half-cell during first charge via an aberration-corrected scanning transmission electron microscopy (STEM). Surface regions (~2 nm) of the cycled LiNi0.5Mn1.5O4 particles show migration of TM ions into tetrahedral Li sites to form a Mn3O4-like structure. However, subsurface regions of the cycled particles exhibit migration of TM ions into empty octahedral sites to form a rocksalt-like structure. The migration of these TM ions are closely related to dissolution of Ni/Mn ions and building-up of charge transfer impedance, which contribute significantly to the capacity degradation and the poor first-cycle Coulombic efficiency of spinel LiNi0.5Mn1.5O4 cathode material. Accordingly, we provide suggestions of effective stabilization of LiNi0.5Mn1.5O4 structure to obtain better electrochemical performance.« less

  2. Insight into the Atomic Structure of High-Voltage Spinel LiNi0.5Mn1.5O4 Cathode Material in the First Cycle

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Huang, Xuejie [Chinese Academy of Sciences, Beijing (China); Yu, Xiqian [Brookhaven National Laboratory (BNL), Upton, NY (United States); Lin, Mingxiang [Chinese Academy of Sciences, Beijing (China); Ben, Liubin [Chinese Academy of Sciences, Beijing (China); Sun, Yang [Chinese Academy of Sciences, Beijing (China); Wang, Hao [Chinese Academy of Sciences, Beijing (China); Yang, Zhenzhong [Chinese Academy of Sciences, Beijing (China); Gu, Lin [Chinese Academy of Sciences, Beijing (China); Yang, Xiao -Qing [Brookhaven National Laboratory (BNL), Upton, NY (United States); Zhao, Haofei [Chinese Academy of Sciences, Beijing (China); Yu, Richeng [Chinese Academy of Sciences, Beijing (China); Armand, Michel [CIC Energigune, Alava (Spain)

    2015-01-13T23:59:59.000Z

    Application of high-voltage spinel LiNi0.5Mn1.5O4 cathode material is the closest and the most realistic approach to meeting the midterm goal of lithium-ion batteries for electric vehicles (EVs) and plug-in hybrid electric vehicles (HEVs). However, this application has been hampered by long-standing issues, such as capacity degradation and poor first-cycle Coulombic efficiency of LiNi0.5Mn1.5O4 cathode material. Although it is well-known that the structure of LiNi0.5Mn1.5O4 into which Li ions are reversibly intercalated plays a critical role in the above issues, performance degradation related to structural changes, particularly in the first cycle, are not fully understood. Here, we report detailed investigations of local atomic-level and average structure of LiNi0.5Mn1.5O4 during first cycle (3.5–4.9 V) at room temperature. We observed two types of local atomic-level migration of transition metals (TM) ions in the cathode of a well-prepared LiNi0.5Mn1.5O4//Li half-cell during first charge via an aberration-corrected scanning transmission electron microscopy (STEM). Surface regions (~2 nm) of the cycled LiNi0.5Mn1.5O4 particles show migration of TM ions into tetrahedral Li sites to form a Mn3O4-like structure. However, subsurface regions of the cycled particles exhibit migration of TM ions into empty octahedral sites to form a rocksalt-like structure. The migration of these TM ions are closely related to dissolution of Ni/Mn ions and building-up of charge transfer impedance, which contribute significantly to the capacity degradation and the poor first-cycle Coulombic efficiency of spinel LiNi0.5Mn1.5O4 cathode material. Accordingly, we provide suggestions of effective stabilization of LiNi0.5Mn1.5O4 structure to obtain better electrochemical performance.

  3. Antimicrobial Polymer

    DOE Patents [OSTI]

    McDonald, William F. (Utica, OH); Wright, Stacy C. (Flint, MI); Taylor, Andrew C. (Ann Arbor, MI)

    2004-09-28T23:59:59.000Z

    A polymeric composition having antimicrobial properties and a process for rendering the surface of a substrate antimicrobial are disclosed. The polymeric composition comprises a crosslinked chemical combination of (i) a polymer having amino group-containing side chains along a backbone forming the polymer, (ii) an antimicrobial agent selected from metals, metal alloys, metal salts, metal complexes and mixtures thereof, and (iii) a crosslinking agent containing functional groups capable of reacting with the amino groups. In one example embodiment, the polymer is a polyamide formed from a maleic anhydride or maleic acid ester monomer and alkylamines thereby producing a polyamide having amino substituted alkyl chains on one side of the polyamide backbone; the crosslinking agent is a phosphine having the general formula (A).sub.3 P wherein A is hydroxyalkyl; and the metallic antimicrobial agent is selected from chelated silver ions, silver metal, chelated copper ions, copper metal, chelated zinc ions, zinc metal and mixtures thereof.

  4. Antimocrobial Polymer

    DOE Patents [OSTI]

    McDonald, William F. (Utica, OH); Huang, Zhi-Heng (Walnut Creek, CA); Wright, Stacy C. (Columbus, GA)

    2005-09-06T23:59:59.000Z

    A polymeric composition having antimicrobial properties and a process for rendering the surface of a substrate antimicrobial are disclosed. The composition comprises a crosslinked chemical combination of (i) a polymer having amino group-containing side chains along a backbone forming the polymer, (ii) an antimicrobial agent selected from quaternary ammonium compounds, gentian violet compounds, substituted or unsubstituted phenols, biguanide compounds, iodine compounds, and mixtures thereof, and (iii) a crosslinking agent containing functional groups capable of reacting with the amino groups. In one embodiment, the polymer is a polyamide formed from a maleic anhydride or maleic acid ester monomer and alkylamines thereby producing a polyamide having amino substituted alkyl chains on one side of the polyamide backbone; the crosslinking agent is a phosphine having the general formula (A)3P wherein A is hydroxyalkyl; and the antimicrobial agent is chlorhexidine, dimethylchlorophenol, cetyl pyridinium chloride, gentian violet, triclosan, thymol, iodine, and mixtures thereof.

  5. Polymer inflation

    E-Print Network [OSTI]

    Syed Moeez Hassan; Viqar Husain; Sanjeev S. Seahra

    2015-03-05T23:59:59.000Z

    We consider the semi-classical dynamics of a free massive scalar field in a homogeneous and isotropic cosmological spacetime. The scalar field is quantized using the polymer quantization method assuming that it is described by a gaussian coherent state. For quadratic potentials, the semi-classical equations of motion yield a universe that has an early "polymer inflation" phase which is generic and almost exactly de Sitter, followed by a epoch of slow-roll inflation. We compute polymer corrections to the slow roll formalism, and discuss the probability of inflation in this model using a physical Hamiltonian arising from time gauge fixing. We also show how in this model, it is possible to obtain a significant amount of slow-roll inflation from sub-Planckain initial data, hence circumventing some of the criticisms of standard scenarios. These results show the extent to which a quantum gravity motivated quantization method affects early universe dynamics.

  6. Polymers Pushing Polymers: Polymer Mixtures in Thermodynamic Equilibrium with a Pore

    E-Print Network [OSTI]

    Podgornik, Rudolf

    Polymers Pushing Polymers: Polymer Mixtures in Thermodynamic Equilibrium with a Pore R. Podgornik, 1000 Ljubljana, Slovenia Polymer Science and Engineering Department, University of Massachusetts, Amherst, Massachusetts 01003, United States ABSTRACT: We investigate polymer partitioning from polymer

  7. POLYMER PROGRAM SEMINAR "Nanomanufacturing with Polymers"

    E-Print Network [OSTI]

    Alpay, S. Pamir

    POLYMER PROGRAM SEMINAR "Nanomanufacturing with Polymers" Prof. Joey Mead University Lowell has developed a suite of processes to enable the nanomanufacturing of polymer based products of properties (e.g. biocompatibility, polarity, and modulus). Polymer materials can be used as substrates

  8. HELIUM, SOLID 1 Helium, Solid

    E-Print Network [OSTI]

    Glyde, Henry R.

    HELIUM, SOLID 1 Helium, Solid Henry R. Glyde Introduction Helium was first solidified at the famous focused on the melting curve, the specific heat, and the thermal conductivity of solid helium as a test criterion of melting does not hold in solid helium. This pioneering work up to 1957 is elegantly

  9. Fabricating solid carbon porous electrodes from powders

    DOE Patents [OSTI]

    Kaschmitter, James L. (Pleasanton, CA); Tran, Tri D. (Livermore, CA); Feikert, John H. (Livermore, CA); Mayer, Steven T. (San Leandro, CA)

    1997-01-01T23:59:59.000Z

    Fabrication of conductive solid porous carbon electrodes for use in batteries, double layer capacitors, fuel cells, capacitive dionization, and waste treatment. Electrodes fabricated from low surface area (<50 m.sup.2 /gm) graphite and cokes exhibit excellent reversible lithium intercalation characteristics, making them ideal for use as anodes in high voltage lithium insertion (lithium-ion) batteries. Electrodes having a higher surface area, fabricated from powdered carbon blacks, such as carbon aerogel powder, carbon aerogel microspheres, activated carbons, etc. yield high conductivity carbon compositives with excellent double layer capacity, and can be used in double layer capacitors, or for capacitive deionization and/or waste treatment of liquid streams. By adding metallic catalysts to be high surface area carbons, fuel cell electrodes can be produced.

  10. Fabricating solid carbon porous electrodes from powders

    DOE Patents [OSTI]

    Kaschmitter, J.L.; Tran, T.D.; Feikert, J.H.; Mayer, S.T.

    1997-06-10T23:59:59.000Z

    Fabrication is described for conductive solid porous carbon electrodes for use in batteries, double layer capacitors, fuel cells, capacitive deionization, and waste treatment. Electrodes fabricated from low surface area (<50 m{sup 2}/gm) graphite and cokes exhibit excellent reversible lithium intercalation characteristics, making them ideal for use as anodes in high voltage lithium insertion (lithium-ion) batteries. Electrodes having a higher surface area, fabricated from powdered carbon blacks, such as carbon aerogel powder, carbon aerogel microspheres, activated carbons, etc. yield high conductivity carbon composites with excellent double layer capacity, and can be used in double layer capacitors, or for capacitive deionization and/or waste treatment of liquid streams. By adding metallic catalysts to high surface area carbons, fuel cell electrodes can be produced. 1 fig.

  11. Dielectric Actuation of Polymers

    E-Print Network [OSTI]

    Niu, Xiaofan

    2013-01-01T23:59:59.000Z

    strain in dielectric elastomers, Journal of Polymer SciencePart B: Polymer Physics. 49 (2011) 504–515. [25] X. Zhao, Z.Electroactive nanostructured polymers as tunable actuators,

  12. Dielectric Actuation of Polymers

    E-Print Network [OSTI]

    Niu, Xiaofan

    2013-01-01T23:59:59.000Z

    AgNW) polymer composite material that is conductive enoughAgNW/polymer composite was nominated as a highly conductive,

  13. Borrowing Nature's Polymers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Borrowing Nature's Polymers 1663 Los Alamos science and technology magazine Latest Issue:January 2015 All Issues submit Borrowing Nature's Polymers Los Alamos scientists are...

  14. "Rapid Pattern Based Powder Sintering With Room Temperature Polymer Infiltration," Z. He, Y. Kim, M. Kokkengada and J. G. Zhou, Proceedings of the Tenth Solid Freeform Fabrication Symposium, Austin, Texas,

    E-Print Network [OSTI]

    Zhou, Jack

    of polymer materials, several kinds of infiltration materials were selected, and their main mechanical and infiltration. After a green mold or part, having desired cavity/geometry, is made through laser scanning (such should have a lower melting temperature than that of the powder material, so that the melted alloy can

  15. Polymers for Chemical Sensors Using Hydrosilylation Chemistry

    SciTech Connect (OSTI)

    Grate, Jay W.; Kaganove, Steven N.; Nelson, David A.

    2001-06-28T23:59:59.000Z

    Sorbent and functionalized polymers play a key role in a diverse set of fields, including chemical sensors, separation membranes, solid phase extraction techniques, and chromatography. Sorbent polymers are critical to a number of sensor array or "electronic nose" systems. The responses of the sensors in the array give rise to patterns that can be used to distinguish one compound from another, provided that a sufficiently diverse set of sensing materials is present in the array. Figure 1 illustrates the concept of several sensors, each with a different sensor coating, giving rise to variable responses to an analyte that appear as a pattern in bar graph format. Using hydrosilylation as the bond-forming reaction, we have developed a versatile and efficient approach to developing sorbent polymers with diverse interactive properties for sensor applications. Both the chemical and physical properties of these polymers are predictable and tunable by design.

  16. Cycling of Geotube® Solids from Dairy Lagoons Through Turfgrass Sod

    E-Print Network [OSTI]

    Schnell, R.; Tahboub, M.; Vietor, D.; Munster, C.; Provin, T.; Mukhtar, S.

    or socks made of synthetic fibers. Alum (aluminum sulfate) and polymers are injected into wastewater during pumping from lagoons into the socks to facilitate particle flocculation as water drains out of the tube through pores in the fabric. Solids... of alum and polymers during effluent treatment raises questions about the sustainability of Geotube ? solids application to agricultural or urban soils within or outside watersheds on which dairies are located (Sims et al. 2005). Sustainable systems...

  17. Velocity dependence of friction of confined polymers

    E-Print Network [OSTI]

    I. M. Sivebaek; V. N. Samoilov; B. N. J. Persson

    2009-11-18T23:59:59.000Z

    We present molecular dynamics friction calculations for confined hydrocarbon solids with molecular lengths from 20 to 1400 carbon atoms. Two cases are considered: (a) polymer sliding against a hard substrate, and (b) polymer sliding on polymer. We discuss the velocity dependence of the frictional shear stress for both cases. In our simulations, the polymer films are very thin (approx. 3 nm), and the solid walls are connected to a thermostat at a short distance from the polymer slab. Under these circumstances we find that frictional heating effects are not important, and the effective temperature in the polymer film is always close to the thermostat temperature. In the first setup (a), for hydrocarbons with molecular lengths from 60 to 1400 carbon atoms, the shear stresses are nearly independent of molecular length, but for the shortest hydrocarbon C20H42 the frictional shear stress is lower. In all cases the frictional shear stress increases monotonically with the sliding velocity. For polymer sliding on polymer [case (b)] the friction is much larger, and the velocity dependence is more complex. For hydrocarbons with molecular lengths from 60 to 140 C-atoms, the number of monolayers of lubricant increases (abruptly) with increasing sliding velocity (from 6 to 7 layers), leading to a decrease of the friction. Before and after the layering transition, the frictional shear stresses are nearly proportional to the logarithm of sliding velocity. For the longest hydrocarbon (1400 C-atoms) the friction shows no dependence on the sliding velocity, and for the shortest hydrocarbon (20 C-atoms) the frictional shear stress increases nearly linearly with the sliding velocity.

  18. Solid state safety jumper cables

    DOE Patents [OSTI]

    Kronberg, James W. (353 Church Rd., Beech Island, SC 29841)

    1993-01-01T23:59:59.000Z

    Solid state jumper cables for connecting two batteries in parallel, having two bridge rectifiers for developing a reference voltage, a four-input decoder for determining which terminals are to be connected based on a comparison of the voltage at each of the four terminals to the reference voltage, and a pair of relays for effecting the correct connection depending on the determination of the decoder. No connection will be made unless only one terminal of each battery has a higher voltage than the reference voltage, indicating "positive" terminals, and one has a lower voltage than the reference voltage, indicating "negative" terminals, and that, therefore, the two high voltage terminals may be connected and the two lower voltage terminals may be connected. Current flows once the appropriate relay device is closed. The relay device is preferably a MOSFET (metal oxide semiconductor field effect transistor) combined with a series array of photodiodes that develop MOSFET gate-closing potential when the decoder output causes an LED to light.

  19. Solid state safety jumper cables

    DOE Patents [OSTI]

    Kronberg, J.W.

    1993-02-23T23:59:59.000Z

    Solid state jumper cables for connecting two batteries in parallel, having two bridge rectifiers for developing a reference voltage, a four-input decoder for determining which terminals are to be connected based on a comparison of the voltage at each of the four terminals to the reference voltage, and a pair of relays for effecting the correct connection depending on the determination of the decoder. No connection will be made unless only one terminal of each battery has a higher voltage than the reference voltage, indicating positive'' terminals, and one has a lower voltage than the reference voltage, indicating negative'' terminals, and that, therefore, the two high voltage terminals may be connected and the two lower voltage terminals may be connected. Current flows once the appropriate relay device is closed. The relay device is preferably a MOSFET (metal oxide semiconductor field effect transistor) combined with a series array of photodiodes that develop MOSFET gate-closing potential when the decoder output causes an LED to light.

  20. Polymers with increased order

    DOE Patents [OSTI]

    Sawan, Samuel P. (Tyngsborough, MA); Talhi, Abdelhafid (Rochester, MI); Taylor, Craig M. (Jemez Springs, NM)

    1998-08-25T23:59:59.000Z

    The invention features polymers with increased order, and methods of making them featuring a dense gas.

  1. Examination of the fundamental relation between ionic transport and segmental relaxation in polymer electrolytes

    SciTech Connect (OSTI)

    Wang, Yangyang [ORNL; Fan, Fei [ORNL; Agapov, Alexander L [ORNL; Saito, Tomonori [ORNL; Yang, Jun [ORNL; Yu, Xiang [ORNL; Hong, Kunlun [ORNL; Mays, Jimmy [University of Tennessee, Knoxville (UTK); Sokolov, Alexei P [ORNL

    2014-01-01T23:59:59.000Z

    Replacing traditional liquid electrolytes by polymers will significantly improve electrical energy storage technologies. Despite significant advantages for applications in electrochemical devices, the use of solid polymer electrolytes is strongly limited by their poor ionic conductivity. The classical theory predicts that the ionic transport is dictated by the segmental motion of the polymer matrix. As a result, the low mobility of polymer segments is often regarded as the limiting factor for development of polymers with sufficiently high ionic conductivity. Here, we show that the ionic conductivity in many polymers can be strongly decoupled from their segmental dynamics, in terms of both temperature dependence and relative transport rate. Based on this principle, we developed several polymers with superionic conductivity. The observed fast ion transport suggests a fundamental difference between the ionic transport mechanisms in polymers and small molecules and provides a new paradigm for design of highly conductive polymer electrolytes.

  2. Solid friction in gel electrophoresis S. F. Burlatskya)

    E-Print Network [OSTI]

    Deutch, John

    Solid friction in gel electrophoresis S. F. Burlatskya) and John M. Deutch Department of Chemistry 1995 We study the influence of solid frictional forces acting on polymer chains moving in a random environment. We show that the total reduction in the chain tension resulting from the small friction between

  3. Process and material that encapsulates solid hazardous waste

    DOE Patents [OSTI]

    O'Brien, Michael H. (Idaho Falls, ID); Erickson, Arnold W. (Idaho Falls, ID)

    1999-01-01T23:59:59.000Z

    A method of encapsulating mixed waste in which a thermoplastic polymer having a melting temperature less than about 150.degree. C. and sulfur and mixed waste are mixed at an elevated temperature not greater than about 200.degree. C. and mixed for a time sufficient to intimately mix the constituents, and then cooled to a solid. The resulting solid is also disclosed.

  4. Improved FGD dewatering process cuts solid wastes

    SciTech Connect (OSTI)

    Moer, C.; Fernandez, J.; Carraro, B. [Duke Energy (United States)

    2009-08-15T23:59:59.000Z

    In 2007, Duke Energy's W.H. Zimmer Station set out to advance the overall performance of its flue gas desulfurization (FGD) dewatering process. The plant implemented a variety of measures, including upgrading water-solids separation, improving polymer program effectiveness and reliability, optimizing treatment costs, reducing solid waste sent to the landfill, decreasing labor requirements, and maintaining septic-free conditions in clarifiers. The changes succeeded in greatly reducing solid waste generation and achieving total annual savings of over half a million dollars per year. 8 figs., 1 tab.

  5. Synchrotron Radiation in Polymer Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synchrotron Radiation in Polymer Science Synchrotron Radiation in Polymer Science March 30-April 2, 2012; San Francisco...

  6. Stiff Quantum Polymers

    E-Print Network [OSTI]

    H. Kleinert

    2007-05-01T23:59:59.000Z

    At ultralow temperatures, polymers exhibit quantum behavior, which is calculated here for the moments and of the end-to-end distribution in the large-stiffness regime. The result should be measurable for polymers in wide optical traps.

  7. Surface effects in the crystallization process of elastic flexible polymers

    E-Print Network [OSTI]

    Stefan Schnabel; Thomas Vogel; Michael Bachmann; Wolfhard Janke

    2010-02-10T23:59:59.000Z

    Investigating thermodynamic properties of liquid-solid transitions of flexible homopolymers with elastic bonds by means of multicanonical Monte Carlo simulations, we find crystalline conformations that resemble ground-state structures of Lennard-Jones clusters. This allows us to set up a structural classification scheme for finite-length flexible polymers and their freezing mechanism in analogy to atomic cluster formation. Crystals of polymers with "magic length" turn out to be perfectly icosahedral.

  8. Solid-state electrochromic devices based on poly ,,phenylene vinylene... A. L. Holt, J. M. Leger, and S. A. Cartera

    E-Print Network [OSTI]

    Carter, Sue

    Solid-state electrochromic devices based on poly ,,phenylene vinylene... polymers A. L. Holt, J. M state electrochromic device based on poly phenylene vinylene light-emitting polymers and explore device-of-the-art conducting polymer electrochromic devices. © 2005 American Institute of Physics. DOI: 10

  9. Insulating polymer concrete

    DOE Patents [OSTI]

    Schorr, H. Peter (Douglaston, NY); Fontana, Jack J. (Shirley, NY); Steinberg, Meyer (Melville, NY)

    1987-01-01T23:59:59.000Z

    A lightweight insulating polymer concrete formed from a lightweight closed cell aggregate and a water resistance polymeric binder.

  10. Method for polymer synthesis in a reaction well

    DOE Patents [OSTI]

    Brennan, Thomas M. (San Francisco, CA)

    1998-01-01T23:59:59.000Z

    A method of synthesis for building a polymer chain, oligonucleotides in particular, by sequentially adding monomer units to at least one solid support for growing and immobilizing a polymer chain thereon in a liquid reagent solution. The method includes the step of: A) depositing a liquid reagent in a reaction well (26) in contact with at least one solid support and at least one monomer unit of the polymer chain affixed to the solid support. The well (26) includes at least one orifice (74) extending into the well (26), and is of a size and dimension to form a capillary liquid seal to retain the reagent solution in the well (26) to enable polymer chain growth on the solid support. The method further includes the step of B) expelling the reagent solution from the well (26), while retaining the polymer chain therein. This is accomplished by applying a first gas pressure to the reaction well such that a pressure differential between the first gas pressure and a second gas pressure exerted on an exit (80) of the orifice (74) exceeds a predetermined amount sufficient to overcome the capillary liquid seal and expel the reagent solution from the well (26) through the orifice exit (80).

  11. Method for polymer synthesis in a reaction well

    DOE Patents [OSTI]

    Brennan, T.M.

    1998-09-29T23:59:59.000Z

    A method of synthesis is described for building a polymer chain, oligonucleotides in particular, by sequentially adding monomer units to at least one solid support for growing and immobilizing a polymer chain thereon in a liquid reagent solution. The method includes the step of: (A) depositing a liquid reagent in a reaction well in contact with at least one solid support and at least one monomer unit of the polymer chain affixed to the solid support. The well includes at least one orifice extending into the well, and is of a size and dimension to form a capillary liquid seal to retain the reagent solution in the well to enable polymer chain growth on the solid support. The method further includes the step of (B) expelling the reagent solution from the well, while retaining the polymer chain therein. This is accomplished by applying a first gas pressure to the reaction well such that a pressure differential between the first gas pressure and a second gas pressure exerted on an exit of the orifice exceeds a predetermined amount sufficient to overcome the capillary liquid seal and expel the reagent solution from the well through the orifice exit. 9 figs.

  12. Nanoporous polymer electrolyte

    DOE Patents [OSTI]

    Elliott, Brian (Wheat Ridge, CO); Nguyen, Vinh (Wheat Ridge, CO)

    2012-04-24T23:59:59.000Z

    A nanoporous polymer electrolyte and methods for making the polymer electrolyte are disclosed. The polymer electrolyte comprises a crosslinked self-assembly of a polymerizable salt surfactant, wherein the crosslinked self-assembly includes nanopores and wherein the crosslinked self-assembly has a conductivity of at least 1.0.times.10.sup.-6 S/cm at 25.degree. C. The method of making a polymer electrolyte comprises providing a polymerizable salt surfactant. The method further comprises crosslinking the polymerizable salt surfactant to form a nanoporous polymer electrolyte.

  13. The Design of Organic Polymers and Small Molecules to Improve the Efficiency of Excitonic Solar Cells

    E-Print Network [OSTI]

    Armstrong, Paul Barber

    2010-01-01T23:59:59.000Z

    of solid-state dye sensitized cells have previously beenon organic polymer and dye-sensitized cells. The detailedof a Typical Dye-Sensitized Cell……12 Design of Dyes for Dye-

  14. A thermodynamical framework for the solidification of molten polymers and its application to fiber extrusion

    E-Print Network [OSTI]

    Kannan, Krishna

    2006-04-12T23:59:59.000Z

    A thermodynamical framework is presented that describes the solidification of molten polymers to an amorphous as well as to a semicrystalline solid-like state. This framework fits into a general structure developed for materials undergoing a large...

  15. Molecular thermodynamics of polymer melts at interfaces

    SciTech Connect (OSTI)

    Theodorou, D.N.

    1988-09-01T23:59:59.000Z

    A lattice model is developed for the prediction of structure and thermodynamic properties at free polymer melt surfaces and polymer melt/solid interfaces. Density variations in the interfacial region are taken into account by introducing voids in the lattice, in the spirit of the equation of state theory of Sanchez and Lacombe. Intramolecular energy (chain stiffness) effects are explicitly incorporated. The model is derived through a rigorous statistical mechanical and thermodynamic analysis, which is based on the concept of availability. Two cases are considered: ''full equilibrium,'' whereby the interfacial polymer is taken as free to exchange heat, work and mass with a bulk polymer phase at given temperature and pressure; and ''restricted equilibrium,'' whereby a thin polymer film is allowed to equilibrate locally in response to ambient temperature and pressure, but in which chains do not necessarily have the same chemical potential as in the unconstrained bulk. Techniques are developed for calculating surface tension, adhesion tension, density profiles, chain shape, bond orientation, as well as the distribution of segments of various orders in the interfacial region. 28 refs., 6 figs.

  16. Polymer-Graphite Nanocomposites: Effective Dispersion and Major Property Enhancement via

    E-Print Network [OSTI]

    Polymer-Graphite Nanocomposites: Effective Dispersion and Major Property Enhancement via SolidVed NoVember 2, 2007 Introduction. Polymer nanocomposites are of scientific and commercial interest-hybridized carbon layers termed "graphene sheets" are isolated or in "paper" form.20-23 Chemi- cally similar

  17. Electrical system architecture having high voltage bus

    DOE Patents [OSTI]

    Hoff, Brian Douglas (East Peoria, IL); Akasam, Sivaprasad (Peoria, IL)

    2011-03-22T23:59:59.000Z

    An electrical system architecture is disclosed. The architecture has a power source configured to generate a first power, and a first bus configured to receive the first power from the power source. The architecture also has a converter configured to receive the first power from the first bus and convert the first power to a second power, wherein a voltage of the second power is greater than a voltage of the first power, and a second bus configured to receive the second power from the converter. The architecture further has a power storage device configured to receive the second power from the second bus and deliver the second power to the second bus, a propulsion motor configured to receive the second power from the second bus, and an accessory motor configured to receive the second power from the second bus.

  18. Optically initiated silicon carbide high voltage switch

    DOE Patents [OSTI]

    Caporaso, George J. (Livermore, CA); Sampayan, Stephen E. (Manteca, CA); Sullivan, James S. (Livermore, CA); Sanders; David M. (Livermore, CA)

    2011-02-22T23:59:59.000Z

    An improved photoconductive switch having a SiC or other wide band gap substrate material, such as GaAs and field-grading liners composed of preferably SiN formed on the substrate adjacent the electrode perimeters or adjacent the substrate perimeters for grading the electric fields.

  19. Gaseous insulators for high voltage electrical equipment

    DOE Patents [OSTI]

    Christophorou, Loucas G. (Oak Ridge, TN); James, David R. (Knoxville, TN); Pace, Marshall O. (Knoxville, TN); Pai, Robert Y. (Concord, TN)

    1981-01-01T23:59:59.000Z

    Gaseous insulators comprise compounds having high attachment cross sections for electrons having energies in the 0-1.3 electron volt range. Multi-component gaseous insulators comprise compounds and mixtures having overall high electron attachment cross sections in the 0-1.3 electron volt range and moderating gases having high cross sections for inelastic interactions with electrons of energies 1-4 electron volts. Suitable electron attachment components include hexafluorobutyne, perfluorobutene-2, perfluorocyclobutane, perfluorodimethylcyclobutane, perfluorocyclohexene, perfluoromethylcyclohexane, hexafluorobutadiene, perfluoroheptene-1 and hexafluoroazomethane. Suitable moderating gases include N.sub.2, CO, CO.sub.2 and H.sub.2. The gaseous insulating mixture can also contain SF.sub.6, perfluoropropane and perfluorobenzene.

  20. Lookout device for high voltage circuit breaker

    SciTech Connect (OSTI)

    Kozlowski, L.J.; Shirey, L.A.

    1991-12-31T23:59:59.000Z

    An improved lockout assembly is provided for a circuit breaker to lock the switch handle into a selected switch position. The lockout assembly includes two main elements, each having a respective foot for engaging a portion of the upper housing wall of the circuit breaker. The first foot is inserted into a groove in the upper housing wall, and the second foot is inserted into an adjacent aperture (e.g., a slot) in the upper housing wall. The first foot is slid under and into engagement with a first portion, and the second foot is slid under and into engagement with a second portion of the upper housing wall. At the same time the respective two feet are placed in engagement with the respective portions of the upper housing wall, two holes, one on each of the respective two main elements of the assembly, are placed in registration; and a locking device, such as a special scissors equipped with a padlock, is installed through the registered holes to secure the lockout assembly on the circuit breaker. When the lockout assembly of the invention is secured on the circuit breaker, the switch handle of the circuit breaker is locked into the selected switch position and prevented from being switched to another switch position.

  1. Lockout device for high voltage circuit breaker

    DOE Patents [OSTI]

    Kozlowski, L.J.; Shirey, L.A.

    1993-01-26T23:59:59.000Z

    An improved lockout assembly is provided for a circuit breaker to lock the switch handle into a selected switch position. The lockout assembly includes two main elements, each having a respective foot for engaging a portion of the upper housing wall of the circuit breaker. The first foot is inserted into a groove in the upper housing wall, and the second foot is inserted into an adjacent aperture (e.g., a slot) in the upper housing wall. The first foot is slid under and into engagement with a first portion, and the second foot is slid under and into engagement with a second portion of the upper housing wall. At the same time the respective two feet are placed in engagement with the respective portions of the upper housing wall, two holes, one on each of the respective two main elements of the assembly, are placed in registration; and a locking device, such as a special scissors equipped with a padlock, is installed through the registered holes to secure the lockout assembly on the circuit breaker. When the lockout assembly of the invention is secured on the circuit breaker, the switch handle of the circuit breaker is locked into the selected switch position and prevented from being switched to another switch position.

  2. Lockout device for high voltage circuit breaker

    SciTech Connect (OSTI)

    Kozlowski, Lawrence J. (New Kensington, PA); Shirey, Lawrence A. (North Huntingdon, PA)

    1993-01-01T23:59:59.000Z

    An improved lockout assembly is provided for a circuit breaker to lock the switch handle into a selected switch position. The lockout assembly includes two main elements, each having a respective foot for engaging a portion of the upper housing wall of the circuit breaker. The first foot is inserted into a groove in the upper housing wall, and the second foot is inserted into an adjacent aperture (e.g., a slot) in the upper housing wall. The first foot is slid under and into engagement with a first portion, and the second foot is slid under and into engagement with a second portion of the upper housing wall. At the same time the repsective two feet are placed in engagement with the respective portions of the upper housing wall, two holes, one on each of the respective two main elements of the assembly, are placed in registration; and a locking device, such as a special scissors equipped with a padlock, is installed through the registered holes to secure the lockout assembly on the circuit breaker. When the lockout assembly of the invention is secured on the circuit breaker, the switch handle of the circuit breaker is locked into the selected switch position and prevented from being switched to another switch position.

  3. Polymerizable Additive for Passivating High Voltage Cathodes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In this research project, we are studying the use of organic monomers as electrolyte additives that will oxidize and polymerize to form stable passivation films on the surface of...

  4. Electro-optic high voltage sensor

    DOE Patents [OSTI]

    Davidson, James R. (Idaho Falls, ID); Seifert, Gary D. (Idaho Falls, ID)

    2002-01-01T23:59:59.000Z

    A small sized electro-optic voltage sensor capable of accurate measurement of high levels of voltages without contact with a conductor or voltage source is provided. When placed in the presence of an electric field, the sensor receives an input beam of electromagnetic radiation into the sensor. A polarization beam displacer serves as a filter to separate the input beam into two beams with orthogonal linear polarizations. The beam displacer is oriented in such a way as to rotate the linearly polarized beams such that they enter a Pockels crystal having at a preferred angle of 45 degrees. The beam displacer is therefore capable of causing a linearly polarized beam to impinge a crystal at a desired angle independent of temperature. The Pockels electro-optic effect induces a differential phase shift on the major and minor axes of the input beam as it travels through the Pockels crystal, which causes the input beam to be elliptically polarized. A reflecting prism redirects the beam back through the crystal and the beam displacer. On the return path, the polarization beam displacer separates the elliptically polarized beam into two output beams of orthogonal linear polarization representing the major and minor axes. The system may include a detector for converting the output beams into electrical signals, and a signal processor for determining the voltage based on an analysis of the output beams. The output beams are amplitude modulated by the frequency of the electric field and the amplitude of the output beams is proportional to the magnitude of the electric field, which is related to the voltage being measured.

  5. High Voltage Electrolyte for Lithium Batteries

    Broader source: Energy.gov (indexed) [DOE]

    5.0E-04 1.0E-03 2 2.2 2.4 2.6 2.8 Voltage (V) dQdV (AhV) 1 st Charge 1.2M LiPF 6 ECEMC 37 1 st Charge 1.0M LiPF 6 TMS1NM3 55 with 2% and 4% VC 1 st Charge 1.0M LiPF 6 TMS...

  6. High voltage photo switch package module

    DOE Patents [OSTI]

    Sullivan, James S; Sanders, David M; Hawkins, Steven A; Sampayan, Stephen E

    2014-02-18T23:59:59.000Z

    A photo-conductive switch package module having a photo-conductive substrate or wafer with opposing electrode-interface surfaces, and at least one light-input surface. First metallic layers are formed on the electrode-interface surfaces, and one or more optical waveguides having input and output ends are bonded to the substrate so that the output end of each waveguide is bonded to a corresponding one of the light-input surfaces of the photo-conductive substrate. This forms a waveguide-substrate interface for coupling light into the photo-conductive wafer. A dielectric material such as epoxy is then used to encapsulate the photo-conductive substrate and optical waveguide so that only the metallic layers and the input end of the optical waveguide are exposed. Second metallic layers are then formed on the first metallic layers so that the waveguide-substrate interface is positioned under the second metallic layers.

  7. Mechanics of amorphous polymers and polymer gels

    E-Print Network [OSTI]

    Chester, Shawn Alexander

    2011-01-01T23:59:59.000Z

    Many applications of amorphous polymers require a thermo-mechanically coupled large-deformation elasto-viscoplasticity theory which models the strain rate and temperature dependent response of amorphous polymeric materials ...

  8. Michael Scholl, mss4@wustl.edu (A paper written under the guidance of Prof. Raj Jain) Download High availability is one of the major goals of smart grid systems. This paper examines the availability of wind turbines, a high voltage DC (HVDC)

    E-Print Network [OSTI]

    Jain, Raj

    the availability of wind turbines, a high voltage DC (HVDC) transmission system, and a supervisory control and data of a Wind Turbine 3.2 Availability Data 3.3 Sensitivity Analysis 4. HVDC Transmission System 4.1 Parts of a HVDC Transmission System 4.2 Availability Data 4.3 Sensitivity Analysis 5. Control System 5.1 Parts

  9. Tunneling of Polymer Particles

    E-Print Network [OSTI]

    A. Martín-Ruiz; E. Chan-López; A. Carbajal-Domínguez; J. Bernal

    2014-08-28T23:59:59.000Z

    In this paper we study the tunneling using a background independent (polymer) quantization scheme. We show that at low energies, for the tunneling through a single potential barrier, the polymer transmission coefficient and the polymer tunneling time converge to its quantum-mechanical counterparts in a clear fashion. As the energy approaches the maximum these polymer quantities abruptly decrease to zero. We use the transfer matrix method to study the tunneling through a series of identical potential barriers. We obtain that the transmission coefficients (polymer and quantum-mechanical) behave qualitatively in a similar manner, as expected. Finally we show that the polymer tunneling time exhibits anomalous peaks compared with the standard result. Numerical results are also presented.

  10. A two-photoelectrode solid-state photoelectrochemical cell

    SciTech Connect (OSTI)

    Sammells, A.F.; Schmidt, S.K.

    1985-02-01T23:59:59.000Z

    This article describes a two photoelectrode solid-state photoelectrochemical cell which is able to produce photopotentials in excess of one voltage and possesses some inherent storage capacity. The storage capacity is presently limited by the low concentration and thin solid polymer electrolyte (SPE) redox layers used between the photoelectrode and the SPE membrane. The use of solid-electrolyte based photoelectrochemical cells provides a unique approach for the photoelectrochemical conversion and storage of selected redox species incorporated within the proximity of the semiconductor/solid electrolyte interface. It is expected that the described cell will be of potential value as not only a specialized storage device, but for specific detector applications.

  11. Percolation in a nanotube-polymer system and its lumped-circuit modeling

    SciTech Connect (OSTI)

    Tuncer, Enis [ORNL; Vaia, Richard A [ORNL; Arlen, Michael Jeffrey [ORNL

    2010-01-01T23:59:59.000Z

    Electrical properties of composites composed of polyurethane polymer and multi-walled nanotubes are reported. Samples with different nanotube volume fractions are prepared, and an impedance spectroscopy technique in the frequency range from 10 mHz to 10 MHz is used to characterize the properties of the samples. It is observed that the resistivity of the mixture can be varied widely, from {approx}10 M{Omega}m to {approx}1 {Omega}m, just by slightly altering the volume fraction of nanotubes. A lumped-circuit model illustrated that the micro-scale morphology between nanotube-clusters influences the resistive relaxation in the composite system. The investigations show that the presented binary mixture has a potential to be utilized in conductive electrical components (flexible electrodes), electromagnetic shielding, and electrostatic and field grading materials for electronic and high voltage insulation technologies.

  12. Effects of backbone rigidity on the local structure and dynamics in polymer melts and glasses

    SciTech Connect (OSTI)

    Kumar, Rajeev [ORNL; Goswami, Monojoy [ORNL; Sumpter, Bobby G [ORNL; Novikov, Vladimir [ORNL; Sokolov, Alexei P [ORNL

    2013-01-01T23:59:59.000Z

    Frustration in chain packing has been proposed to play an important role in thermodynamic and dynamic properties of polymeric melts and glasses. Based on a quantitative analysis using Voronoi tessellations and large scale molecular dynamics simulations of flexible and semi-flexible polymers, we demonstrate that the rigid polymer chains have higher averaged Voronoi polyhedral volumes and significantly wider distribution of the volume due to frustration in the chain packing. Using these results, we discuss the advantage of the rigid polymers for possible enhancement of transport properties, e.g. for enhancing ionic conductivity in solid polymer electrolytes.

  13. Melons are branched polymers

    E-Print Network [OSTI]

    Razvan Gurau; James P. Ryan

    2013-02-18T23:59:59.000Z

    Melonic graphs constitute the family of graphs arising at leading order in the 1/N expansion of tensor models. They were shown to lead to a continuum phase, reminiscent of branched polymers. We show here that they are in fact precisely branched polymers, that is, they possess Hausdorff dimension 2 and spectral dimension 4/3.

  14. Stiff quantum polymers

    E-Print Network [OSTI]

    H. Kleinert

    2009-10-19T23:59:59.000Z

    At ultralow temperatures, polymers exhibit quantum behavior, which is calculated here for the second and fourth moments of the end-to-end distribution in the large-stiffness regime. The result should be measurable for polymers in wide optical traps.

  15. Porous polymer media

    DOE Patents [OSTI]

    Shepodd, Timothy J. (Livermore, CA)

    2002-01-01T23:59:59.000Z

    Highly crosslinked monolithic porous polymer materials for chromatographic applications. By using solvent compositions that provide not only for polymerization of acrylate monomers in such a fashion that a porous polymer network is formed prior to phase separation but also for exchanging the polymerization solvent for a running buffer using electroosmotic flow, the need for high pressure purging is eliminated. The polymer materials have been shown to be an effective capillary electrochromatographic separations medium at lower field strengths than conventional polymer media. Further, because of their highly crosslinked nature these polymer materials are structurally stable in a wide range of organic and aqueous solvents and over a pH range of 2-12.

  16. Polymer-Metal Nanocomposites via Polymer Thin Film

    E-Print Network [OSTI]

    Shyamasundar, R.K.

    Polymer-Metal Nanocomposites via Polymer Thin Film T. P. Radhakrishnan School of Chemistry, University of Hyderabad Polymer-metal nanocomposite thin films are versatile materials that not only Chemistry Inside a Polymer Thin Film P. Radhakrishnan School of Chemistry, University of Hyderabad metal

  17. Anion exchange polymer electrolytes

    DOE Patents [OSTI]

    Kim, Yu Seung; Kim, Dae Sik; Lee, Kwan-Soo

    2013-07-23T23:59:59.000Z

    Solid anion exchange polymer electrolytes and compositions comprising chemical compounds comprising a polymeric core, a spacer A, and a guanidine base, wherein said chemical compound is uniformly dispersed in a suitable solvent and has the structure: ##STR00001## wherein: i) A is a spacer having the structure O, S, SO.sub.2, --NH--, --N(CH.sub.2).sub.n, wherein n=1-10, --(CH.sub.2).sub.n--CH.sub.3--, wherein n=1-10, SO.sub.2-Ph, CO-Ph, ##STR00002## wherein R.sub.5, R.sub.6, R.sub.7 and R.sub.8 each are independently --H, --NH.sub.2, F, Cl, Br, CN, or a C.sub.1-C.sub.6 alkyl group, or any combination of thereof; ii) R.sub.9, R.sub.10, R.sub.11, R.sub.12, or R.sub.13 each independently are --H, --CH.sub.3, --NH.sub.2, --NO, --CH.sub.nCH.sub.3 where n=1-6, HC.dbd.O--, NH.sub.2C.dbd.O--, --CH.sub.nCOOH where n=1-6, --(CH.sub.2).sub.n--C(NH.sub.2)--COOH where n=1-6, --CH--(COOH)--CH.sub.2--COOH, --CH.sub.2--CH(O--CH.sub.2CH.sub.3).sub.2, --(C.dbd.S)--NH.sub.2, --(C.dbd.NH)--N--(CH.sub.2).sub.nCH.sub.3, where n=0-6, --NH--(C.dbd.S)--SH, --CH.sub.2--(C.dbd.O)--O--C(CH.sub.3).sub.3, --O--(CH.sub.2).sub.n--CH--(NH.sub.2)--COOH, where n=1-6, --(CH.sub.2).sub.n--CH.dbd.CH wherein n=1-6, --(CH.sub.2).sub.n--CH--CN wherein n=1-6, an aromatic group such as a phenyl, benzyl, phenoxy, methylbenzyl, nitrogen-substituted benzyl or phenyl groups, a halide, or halide-substituted methyl groups; and iii) wherein the composition is suitable for use in a membrane electrode assembly.

  18. Silvered polymer reflectors

    SciTech Connect (OSTI)

    Schissel, P.; Neidlinger, H.H.; Czanderna, A.W.

    1985-03-01T23:59:59.000Z

    One of the principal objectives of the Solar Thermal Research Program is to develop silvered polymer films for constructing durable, low-cost, lightweight concentrating collectors for high temperature solar thermal systems. The mirrors are characterized for their solar-weighted (air mass 1.5) reflectance and exposed to environmental degradation. Photodegradation of polymers has also been studied using Fourier transform infrared spectroscopy supplemented with surface analysis characterization. Results are discussed for extruded films, ultraviolet effects, metallization, and the effects of polymer additives. (LEW)

  19. Preparation of metallic cation conducting polymers based on sterically hindered phenols containing polymeric systems

    DOE Patents [OSTI]

    Skotheim, Terje A. (Shoreham, NY); Okamoto, Yoshiyuki (Fort Lee, NJ); Lee, Hung S. (Woodside, NY)

    1989-01-01T23:59:59.000Z

    The present invention relates to ion-conducting solvent-free polymeric systems characterized as being cationic single ion conductors. The solvent-free polymer electrolytes comprise a flexible polymer backbone to which is attached a metal salt, such as a lithium, sodium or potassium salt, of a sterically hindered phenol. The solid polymer electrolyte may be prepared either by (1) attaching the hindered phenol directly to a flexible polymeric backbone, followed by neutralization of the phenolic OH's or (2) reacting the hindered phenol with a polymer precursor which is then polymerized to form a flexible polymer having phenolic OH's which are subsequently neutralized. Preferably the hindered phenol-modified polymeric backbone contains a polyether segment. The ionic conductivity of these solvent-free polymer electrolytes has been measured to be in the range of 10.sup.-4 to 10.sup.-7 S cm.sup.-1 at room temperature.

  20. Preparation of metallic cation conducting polymers based on sterically hindered phenols containing polymeric systems

    DOE Patents [OSTI]

    Skotheim, T.A.; Okamoto, Yoshiyuki; Lee, H.S.

    1989-11-21T23:59:59.000Z

    The present invention relates to ion-conducting solvent-free polymeric systems characterized as being cationic single ion conductors. The solvent-free polymer electrolytes comprise a flexible polymer backbone to which is attached a metal salt, such as a lithium, sodium or potassium salt, of a sterically hindered phenol. The solid polymer electrolyte may be prepared either by (1) attaching the hindered phenol directly to a flexible polymeric backbone, followed by neutralization of the phenolic OH's or (2) reacting the hindered phenol with a polymer precursor which is then polymerized to form a flexible polymer having phenolic OH's which are subsequently neutralized. Preferably the hindered phenol-modified polymeric backbone contains a polyether segment. The ionic conductivity of these solvent-free polymer electrolytes has been measured to be in the range of 10[sup [minus]4] to 10[sup [minus]7] S cm[sup [minus]1] at room temperature.

  1. Solid oxide MEMS-based fuel cells

    DOE Patents [OSTI]

    Jankowksi, Alan F.; Morse, Jeffrey D.

    2007-03-13T23:59:59.000Z

    A micro-electro-mechanical systems (MEMS) based thin-film fuel cells for electrical power applications. The MEMS-based fuel cell may be of a solid oxide type (SOFC), a solid polymer type (SPFC), or a proton exchange membrane type (PEMFC), and each fuel cell basically consists of an anode and a cathode separated by an electrolyte layer. The electrolyte layer can consist of either a solid oxide or solid polymer material, or proton exchange membrane electrolyte materials may be used. Additionally catalyst layers can also separate the electrodes (cathode and anode) from the electrolyte. Gas manifolds are utilized to transport the fuel and oxidant to each cell and provide a path for exhaust gases. The electrical current generated from each cell is drawn away with an interconnect and support structure integrated with the gas manifold. The fuel cells utilize integrated resistive heaters for efficient heating of the materials. By combining MEMS technology with thin-film deposition technology, thin-film fuel cells having microflow channels and full-integrated circuitry can be produced that will lower the operating temperature an will yield an order of magnitude greater power density than the currently known fuel cells.

  2. Sulfonated polyphenylene polymers

    DOE Patents [OSTI]

    Cornelius, Christopher J. (Albuquerque, NM); Fujimoto, Cy H. (Albuquerque, NM); Hickner, Michael A. (Albuquerque, NM)

    2007-11-27T23:59:59.000Z

    Improved sulfonated polyphenylene compositions, improved polymer electrolyte membranes and nanocomposites formed there from for use in fuel cells are described herein. The improved compositions, membranes and nanocomposites formed there from overcome limitations of Nafion.RTM. membranes.

  3. Polymer quantization and Symmetries

    E-Print Network [OSTI]

    Ghanashyam Date; Nirmalya Kajuri

    2013-02-24T23:59:59.000Z

    Polymer quantization was discovered during the construction of Loop Quantum Cosmology. For the simplest quantum theory of one degree of freedom, the implications for dynamics were studied for the harmonic oscillator as well as some other potentials. For more degrees of freedom, the possibility of continuous, kinematic symmetries arises. While these are realised on the Hilbert space of polymer quantum mechanics, their infinitesimal versions are not supported. For an invariant Hamiltonian, these symmetry realizations imply infinite degeneracy suggesting that the symmetry should be spontaneously or explicitly broken. The estimation of symmetry violations in some cases have been analysed before. Here we explore the alternative of shifting the arena to the distributional states. We discuss both the polymer quantum mechanics case as well as polymer quantized scalar field.

  4. Heavily fluorinated electronic polymers

    E-Print Network [OSTI]

    Lim, Jeewoo

    2011-01-01T23:59:59.000Z

    Building blocks, containing majority fluorine content by weight, for PPEs and PPVs have been synthesized. Some of the monomers were shown to give exclusively fluorous-phase soluble polymers, the syntheses of which were ...

  5. Conducting polymer nanostructures for biological applications

    E-Print Network [OSTI]

    Berdichevsky, Yevgeny

    2006-01-01T23:59:59.000Z

    of Electronically Conductive Polymer Nanostructures,” Acc.et al. , “Conjugated-Polymer Micro- and Milliactuators for3. Y. Berdichevsky, Y. -H. Lo, “Polymer Microvalve Based on

  6. Polymers in disordered environments

    E-Print Network [OSTI]

    V. Blavatska; N. Fricke; W. Janke

    2014-11-18T23:59:59.000Z

    A brief review of our recent studies aiming at a better understanding of the scaling behaviour of polymers in disordered environments is given. The main emphasis is on a simple generic model where the polymers are represented by (interacting) self-avoiding walks and the disordered environment by critical percolation clusters. The scaling behaviour of the number of conformations and their average spatial extent as a function of the number of monomers and the associated critical exponents $\\gamma$ and $\

  7. Solid-state ultracapacitors for electric vehicles and consumer electronics. Final report

    SciTech Connect (OSTI)

    Dr. Brian G. Dixon

    1999-06-01T23:59:59.000Z

    Advanced ultracapacitors are described that are based upon conducting polymer technology. Both Type I and Type II capacitors were constructed in single cell and stacked arrays that had superior electrochemical properties. More specifically nanophase clay electrode supports were fabricated and the conducting polymers solvent deposited upon them. Both liquid phase and solid polymer electrolytes were evaluated as well. Both single cell and multiple cell capacitors were prepared that exceeded the 15Wh/kg, 1500W/kg goals set by the United States Department of Energy. In addition, it was shown that different conducting polymer electrode configurations could be constructed that showed promise.

  8. Interfacial thermal conductance in spun-cast polymer films and polymer brushes

    E-Print Network [OSTI]

    Braun, Paul

    Interfacial thermal conductance in spun-cast polymer films and polymer brushes Mark D. Losego inorganic materials and anharmonic polymers have potentially intriguing thermal transport behavior. The low thermal conductivity of amorphous polymers limits significant interfacial effects to polymer film

  9. Solid Waste (New Mexico)

    Broader source: Energy.gov [DOE]

    The New Mexico Environment Department's Solid Waste Bureau manages solid waste in the state. The Bureau implements and enforces the rules established by the Environmental Improvement Board.

  10. Danish Polymer Centre Annual Report 2002

    E-Print Network [OSTI]

    Danish Polymer Centre Annual Report 2002 #12;2 The Danish Polymer Centre, DTU and Risř Annual.1 Polymer based solar cells (photovoltaics) ................................ 5 2.2 Structuring Plastic ........................................................................ 17 2.7 Biodegradable polymer composites .......................................... 19 2

  11. Self-extinguishing Polymer/Organoclay Nanocomposites

    SciTech Connect (OSTI)

    Si,M.; Zaitsev, V.; Goldman, M.; Frenkel, A.; Peiffer, D.; Weil, E.; Sokolov, J.; Rafailovich, M.

    2006-01-01T23:59:59.000Z

    We demonstrated that self-extinguishing polymer nanocomposites, which can pass the stringent UL 94 V0 standard, can be successfully prepared by combining modified organoclays with traditional flame retardant (FR) agents. Using secondary ion mass spectrometry (SIMS) and transmission electron microscopy (TEM), we determined that the addition of modified clays, which can intercalate or exfoliate in the matrix, also improved the dispersion of the FR agents. Dynamic mechanical analysis (DMA) indicated that the clays increased the modulus of the polymer above T{sub g}, which prevented dripping during burning. Cone calorimetry test showed that the nanocomposites with both FR and organoclay, had a lower peak heat release rate (PHRR) and average mass loss rate (MLR) than those with only clay or the FR agents. Extended X-ray absorption fine structure (EXAFS) data confirmed that no FR/clay interactions occurred in the solid phase, and that the synergistic effects were due to gas phase reactions. Since this mechanism is not specific, it opens the possibility of formulating self-extinguishing materials from a large class of polymers.

  12. Imaging Hydrated Microbial Extracellular Polymers: Comparative...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrated Microbial Extracellular Polymers: Comparative Analysis by Electron Microscopy . Imaging Hydrated Microbial Extracellular Polymers: Comparative Analysis by Electron...

  13. The Polymer Bouncer

    E-Print Network [OSTI]

    A. Martin-Ruiz; A. Frank; L. F. Urrutia

    2015-05-31T23:59:59.000Z

    Polymer Quantization (PQ) is a background independent quantization scheme that is deployed in Loop Quantum Gravity. This framework leads to a new short-distance (discretized) structure characterized by a fundamental length. In this paper we use PQ to analyze the problem of a particle bouncing on a perfectly reflecting surface under the influence of Earth's gravitational field, what we have called "\\textit{The Polymer Bouncer}". In this scenario, deviations from the usual quantum effects are induced by the spatial discreteness, but not by a new short-range gravitational interaction. We solve the polymer Schr\\"odinger equation in an analytical fashion, and we evaluate numerically the corresponding energy levels. We find that the polymer energy spectrum exhibits a negative shift compared to the obtained for the quantum bouncer. The comparison of our results with those obtained in the GRANIT experiment leads to an upper bound for the fundamental length scale, namely $\\lambda \\ll 0.6 \\buildrel _{\\circ} \\over {\\mathrm{A}}$. We find polymer corrections to the probability of transitions between levels, induced by small vibrations, together with the probability of spontaneous emission in the quadrupole approximation.

  14. Solid Polymer Fuel Cell Research Group | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-f < RAPID‎SolarCity Corp Jump to:Solibro AB Jump to: navigation,

  15. Solids fluidizer-injector

    DOE Patents [OSTI]

    Bulicz, Tytus R. (Hickory Hills, IL)

    1990-01-01T23:59:59.000Z

    An apparatus and process for fluidizing solid particles by causing rotary motion of the solid particles in a fluidizing chamber by a plurality of rotating projections extending from a rotatable cylinder end wall interacting with a plurality of fixed projections extending from an opposite fixed end wall and passing the solid particles through a radial feed orifice open to the solids fluidizing chamber on one side and a solid particle utilization device on the other side. The apparatus and process are particularly suited for obtaining intermittent feeding with continual solids supply to the fluidizing chamber. The apparatus and process are suitable for injecting solid particles, such as coal, to an internal combustion engine.

  16. Branched Polymers and Hyperplane Arrangements

    E-Print Network [OSTI]

    Postnikov, Alexander

    We generalize the construction of connected branched polymers and the notion of the volume of the space of connected branched polymers studied by Brydges and Imbrie (Ann Math, 158:1019–1039, 2003), and Kenyon and Winkler ...

  17. Fluctuations of ring polymers

    E-Print Network [OSTI]

    Medalion, Shlomi; Meirovitch, Hagai; Barkai, Eli; Kessler, David A

    2015-01-01T23:59:59.000Z

    We present an exact solution for the distribution of sample averaged monomer to monomer distance of ring polymers. For non-interacting and weakly-interacting models these distributions correspond to the distribution of the area under the reflected Bessel bridge and the Bessel excursion respectively, and are shown to be identical in dimension d greater or equal 2. A symmetry of the problem reveals that dimension d and 4 minus d are equivalent, thus the celebrated Airy distribution describing the areal distribution of the one dimensional Brownian excursion describes also a polymer in three dimensions. For a self-avoiding polymer in dimension d we find numerically that the fluctuations of the scaled averaged distance are nearly identical in dimensions 2 and 3, and are well described to a first approximation by the non-interacting excursion model in dimension 5.

  18. Antithrombogenic Polymer Coating.

    DOE Patents [OSTI]

    Huang, Zhi Heng (San Ramon, CA); McDonald, William F. (Utica, OH); Wright, Stacy C. (Flint, MI); Taylor, Andrew C. (Ann Arbor, MI)

    2003-01-21T23:59:59.000Z

    An article having a non-thrombogenic surface and a process for making the article are disclosed. The article is formed by (i) coating a polymeric substrate with a crosslinked chemical combination of a polymer having at least two amino substituted side chains, a crosslinking agent containing at least two crosslinking functional groups which react with amino groups on the polymer, and a linking agent containing a first functional group which reacts with a third functional group of the crosslinking agent, and (ii) contacting the coating on the substrate with an antithrombogenic agent which covalently bonds to a second functional group of the linking agent. In one example embodiment, the polymer is a polyamide having amino substituted alkyl chains on one side of the polyamide backbone, the crosslinking agent is a phosphine having the general formula (A).sub.3 P wherein A is hydroxyalkyl, the linking agent is a polyhydrazide and the antithrombogenic agent is heparin.

  19. Shape memory polymer medical device

    DOE Patents [OSTI]

    Maitland, Duncan (Pleasant Hill, CA); Benett, William J. (Livermore, CA); Bearinger, Jane P. (Livermore, CA); Wilson, Thomas S. (San Leandro, CA); Small, IV, Ward (Livermore, CA); Schumann, Daniel L. (Concord, CA); Jensen, Wayne A. (Livermore, CA); Ortega, Jason M. (Pacifica, CA); Marion, III, John E. (Livermore, CA); Loge, Jeffrey M. (Stockton, CA)

    2010-06-29T23:59:59.000Z

    A system for removing matter from a conduit. The system includes the steps of passing a transport vehicle and a shape memory polymer material through the conduit, transmitting energy to the shape memory polymer material for moving the shape memory polymer material from a first shape to a second and different shape, and withdrawing the transport vehicle and the shape memory polymer material through the conduit carrying the matter.

  20. BRANCHED POLYMERS AND HYPERPLANE ARRANGEMENTS

    E-Print Network [OSTI]

    Postnikov, Alexander

    BRANCHED POLYMERS AND HYPERPLANE ARRANGEMENTS KAROLA M´ESZ´AROS ALEXANDER POSTNIKOV Abstract. We of connected branched polymers studied by Brydges and Imbrie [BI], and Kenyon and Winkler [KW] to any hyperplane arrangement A. The volume of the resulting configuration space of connected branched polymers

  1. Continuous equal channel angular extrusion of glassy polymers

    E-Print Network [OSTI]

    Dilan, Hector

    1997-01-01T23:59:59.000Z

    by multiplying the square of the sound speed across the material by the material density. The effective elastic moduli are calculated by using the wave velocity measured in three orthogonal directions of propagation. Three propagating velocities are measured... Discussion Conclusions Figure 1. Proposed approach. CONTINUOUS EQUAL C~L ANGULAR EXTRUSION OF POLYMERS Hydraulic Cylinder Exlruder Cooling Jackets Solid State Liquid State Temperature Controlled Zones ~tI- Multi- // // / /' //// ~%PE//l~/ //r...

  2. Gel polymer electrolytes for batteries

    DOE Patents [OSTI]

    Balsara, Nitash Pervez; Eitouni, Hany Basam; Gur, Ilan; Singh, Mohit; Hudson, William

    2014-11-18T23:59:59.000Z

    Nanostructured gel polymer electrolytes that have both high ionic conductivity and high mechanical strength are disclosed. The electrolytes have at least two domains--one domain contains an ionically-conductive gel polymer and the other domain contains a rigid polymer that provides structure for the electrolyte. The domains are formed by block copolymers. The first block provides a polymer matrix that may or may not be conductive on by itself, but that can soak up a liquid electrolyte, thereby making a gel. An exemplary nanostructured gel polymer electrolyte has an ionic conductivity of at least 1.times.10.sup.-4 S cm.sup.-1 at 25.degree. C.

  3. Durable metallized polymer mirror

    DOE Patents [OSTI]

    Schissel, Paul O. (Golden, CO); Kennedy, Cheryl E. (Lafayette, CO); Jorgensen, Gary J. (Pine, CO); Shinton, Yvonne D. (Northglenn, CO); Goggin, Rita M. (Englewood, CO)

    1994-01-01T23:59:59.000Z

    A metallized polymer mirror construction having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate.

  4. POLYMER ELECTROLYTE FUEL CELLS

    E-Print Network [OSTI]

    Petta, Jason

    POLYMER ELECTROLYTE FUEL CELLS: The Gas Diffusion Layer Johannah Itescu Princeton University PRISM REU #12;PEM FUEL CELLS: A little background information I. What do fuel cells do? Generate electricity through chemical reaction #12;PEM FUEL CELLS: A little background information -+ + eHH 442 2 0244 22 He

  5. High temperature polymer concrete

    DOE Patents [OSTI]

    Fontana, J.J.; Reams, W.

    1984-05-29T23:59:59.000Z

    This invention is concerned with a polymer concrete composition, which is a two-component composition useful with many bases including metal. Component A, the aggregate composition, is broadly composed of silica, silica flour, portland cement, and acrylamide, whereas Component B, which is primarily vinyl and acrylyl reactive monomers, is a liquid system.

  6. Durable metallized polymer mirror

    DOE Patents [OSTI]

    Schissel, P.O.; Kennedy, C.E.; Jorgensen, G.J.; Shinton, Y.D.; Goggin, R.M.

    1994-11-01T23:59:59.000Z

    A metallized polymer mirror construction is disclosed having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate. 6 figs.

  7. Primordial polymer perturbations

    E-Print Network [OSTI]

    Sanjeev S. Seahra; Iain A. Brown; Golam Mortuza Hossain; Viqar Husain

    2012-09-25T23:59:59.000Z

    We study the generation of primordial fluctuations in pure de Sitter inflation where the quantum scalar field dynamics are governed by polymer (not Schrodinger) quantization. This quantization scheme is related to, but distinct from, the structures employed in Loop Quantum Gravity; and it modifies standard results above a polymer energy scale $M_{\\star}$. We recover the scale invariant Harrison Zel'dovich spectrum for modes that have wavelengths bigger than $M_{\\star}^{-1}$ at the start of inflation. The primordial spectrum for modes with initial wavelengths smaller than $M_{\\star}^{-1}$ exhibits oscillations superimposed on the standard result. The amplitude of these oscillations is proportional to the ratio of the inflationary Hubble parameter $H$ to the polymer energy scale. For reasonable choices of $M_{\\star}$, we find that polymer effects are likely unobservable in CMB angular power spectra due to cosmic variance uncertainty, but future probes of baryon acoustic oscillations may be able to directly constrain the ratio $H/M_{\\star}$.

  8. In-plane and out-of-plane band-gap properties of a two-dimensional triangular polymer-based void channel photonic crystal

    E-Print Network [OSTI]

    photonic crystals fabricated by femtosecond laser drilling in a solid polymer material were characterized is based on the generation of submicron-size void channels using tightly focused femtosecond-pulsed laser

  9. Solid composite electrolytes for lithium batteries

    DOE Patents [OSTI]

    Kumar, Binod (Dayton, OH); Scanlon, Jr., Lawrence G. (Fairborn, OH)

    2001-01-01T23:59:59.000Z

    Solid composite electrolytes are provided for use in lithium batteries which exhibit moderate to high ionic conductivity at ambient temperatures and low activation energies. In one embodiment, a polymer-ceramic composite electrolyte containing poly(ethylene oxide), lithium tetrafluoroborate and titanium dioxide is provided in the form of an annealed film having a room temperature conductivity of from 10.sup.-5 S cm.sup.-1 to 10.sup.-3 S cm.sup.-1 and an activation energy of about 0.5 eV.

  10. Laser cooling of solids

    SciTech Connect (OSTI)

    Epstein, Richard I [Los Alamos National Laboratory; Sheik-bahae, Mansoor [UNM

    2008-01-01T23:59:59.000Z

    We present an overview of solid-state optical refrigeration also known as laser cooling in solids by fluorescence upconversion. The idea of cooling a solid-state optical material by simply shining a laser beam onto it may sound counter intuitive but is rapidly becoming a promising technology for future cryocooler. We chart the evolution of this science in rare-earth doped solids and semiconductors.

  11. Journal of the Mechanics and Physics of Solids 56 (2008) 17791793 A theory of coupled diffusion and large deformation in

    E-Print Network [OSTI]

    Zhao, Xuanhe

    2008-01-01T23:59:59.000Z

    in elastic solids date at least back to Gibbs (1878), who formulated a thermodynamic theory of largeJournal of the Mechanics and Physics of Solids 56 (2008) 1779­1793 A theory of coupled diffusion and mixing the network with the small molecules. Both the small molecules and the long polymers are taken

  12. Colloids and Surfaces A: Physicochem. Eng. Aspects 263 (2005) 336340 Phenomenology of bubble nucleation in the solid-state

    E-Print Network [OSTI]

    Kumar, Vipin

    nucleation in the solid-state nitrogen­polystyrene microcellular foams Vipin Kumar Department of Mechanical that the classical theory may not be applicable to nucleation in thermoplastic polymers near the glass transition. © 2005 Elsevier B.V. All rights reserved. Keywords: Microcellular foams; Solid-state foams; Bubble

  13. Tetraphenylborate Solids Stability Tests

    SciTech Connect (OSTI)

    Walker, D.D. [Westinghouse Savannah River Company, AIKEN, SC (United States); Edwards, T.B.

    1997-12-19T23:59:59.000Z

    Tetraphenylborate solids provide a potentially large source of benzene in the slurries produced in the In-Tank Precipitation process. The stability of the solids is an important consideration in the safety analysis of the process and we desire an understanding of the factors that influence the rate of conversion of the solids to benzene.

  14. Solid State Division

    SciTech Connect (OSTI)

    Green, P.H.; Watson, D.M. (eds.)

    1989-08-01T23:59:59.000Z

    This report contains brief discussions on work done in the Solid State Division of Oak Ridge National Laboratory. The topics covered are: Theoretical Solid State Physics; Neutron scattering; Physical properties of materials; The synthesis and characterization of materials; Ion beam and laser processing; and Structure of solids and surfaces. (LSP)

  15. Mesoporous carbons and polymers

    DOE Patents [OSTI]

    Bell, William; Dietz, Steven

    2004-05-18T23:59:59.000Z

    A polymer is prepared by polymerizing a polymerizable component from a mixture containing the polymerizable component and a surfactant, the surfactant and the polymerizable component being present in the mixture in a molar ratio of at least 0.2:1, having an average pore size greater than 4 nm and a density greater than 0.1 g/cc. The polymerizable component can comprise a resorcinol/formaldehyde system and the mixture can comprise an aqueous solution or the polymerizable component can comprise a divinylbenzene/styrene system and the mixture can comprise an organic solution. Alternatively, the polymerizable component can comprise vinylidene chloride or a vinylidene chloride/divinylbenzene system. The polymer may be monolithic, have a BET surface area of at least about 50 m.sup.2 /g., include a quantity of at least one metal powder, or have an electrical conductivity greater than 10 Scm.sup.-1.

  16. Low band gap polymers Organic Photovoltaics

    E-Print Network [OSTI]

    Low band gap polymers for Organic Photovoltaics Eva Bundgaard Ph.D. Dissertation Risř National Bundgaard Title: Low band gap polymers for Organic photovoltaics Department: The polymer department Report the area of organic photovoltaics are focusing on low band gap polymers, a type of polymer which absorbs

  17. Polymer Stretching by Turbulence

    SciTech Connect (OSTI)

    Chertkov, Michael

    2000-05-15T23:59:59.000Z

    The stretching of a polymer chain by a large-scale chaotic flow is considered. The steady state which emerges as a balance of the turbulent stretching and anharmonic resistance of the chain is quantitatively described, i.e., the dependency on the flow parameters (Lyapunov exponent statistics) and the chain characteristics (the number of beads and the interbead elastic potential) is made explicit. (c) 2000 The American Physical Society.

  18. Polymer Crowding and Shape Distributions in Polymer-Nanoparticle Mixtures

    E-Print Network [OSTI]

    Wei Kang Lim; Alan R. Denton

    2014-10-24T23:59:59.000Z

    Macromolecular crowding can influence polymer shapes, which is important for understanding the thermodynamic stability of polymer solutions and the structure and function of biopolymers (proteins, RNA, DNA) under confinement. We explore the influence of nanoparticle crowding on polymer shapes via Monte Carlo simulations and free-volume theory of a coarse-grained model of polymer-nanoparticle mixtures. Exploiting the geometry of random walks, we model polymer coils as effective penetrable ellipsoids, whose shapes fluctuate according to the probability distributions of the eigenvalues of the gyration tensor. Accounting for the entropic cost of a nanoparticle penetrating a larger polymer coil, we compute the crowding-induced shift in the shape distributions, radius of gyration, and asphericity of ideal polymers in a theta solvent. With increased nanoparticle crowding, we find that polymers become more compact (smaller, more spherical), in agreement with predictions of free-volume theory. Our approach can be easily extended to nonideal polymers in good solvents and used to model conformations of biopolymers in crowded environments.

  19. Solid Waste Management Written Program

    E-Print Network [OSTI]

    Pawlowski, Wojtek

    Solid Waste Management Program Written Program Cornell University 8/28/2012 #12;Solid Waste.................................................................... 4 4.2.1 Compost Solid Waste Treatment Facility.................................................................... 4 4.2.2 Pathological Solid Waste Treatment Facility

  20. Solids fluidizer-injector

    DOE Patents [OSTI]

    Bulicz, T.R.

    1990-04-17T23:59:59.000Z

    An apparatus and process are described for fluidizing solid particles by causing rotary motion of the solid particles in a fluidizing chamber by a plurality of rotating projections extending from a rotatable cylinder end wall interacting with a plurality of fixed projections extending from an opposite fixed end wall and passing the solid particles through a radial feed orifice open to the solids fluidizing chamber on one side and a solid particle utilization device on the other side. The apparatus and process are particularly suited for obtaining intermittent feeding with continual solids supply to the fluidizing chamber. The apparatus and process are suitable for injecting solid particles, such as coal, to an internal combustion engine. 3 figs.

  1. Electrochromic device with a polymer ionic conductor

    SciTech Connect (OSTI)

    Zhou, Y.; Gu, P.; Tang, J. [Zhejiang Univ., Hangzhou (China). Dept. of Optical Engineering

    1993-12-31T23:59:59.000Z

    An electrochromic material is one which can undergo a reversible color change on the exertion of an external electric field. This can be used for large-area glazings of future buildings, automobiles, aircrafts, etc. Transmittance control of the smart windows can be useful to reduce lighting, heating and cooling energy loads. The optical and electrochromic properties of tungsten oxide films deposited by e-beam evaporation were investigated. A laminated structure device was prepared. The as-deposited tungsten oxide film was used as the electrochromic film. A solid polymer electrolyte PPG-PMMA-LiClO{sub 4} was used as an ionic conductor. Spectrophotometric measurements show that the luminous transmittance of the device can be modulated between about 60% and 15%.

  2. Incorporation of additives into polymers

    DOE Patents [OSTI]

    McCleskey, T. Mark; Yates, Matthew Z.

    2003-07-29T23:59:59.000Z

    There has been invented a method for incorporating additives into polymers comprising: (a) forming an aqueous or alcohol-based colloidal system of the polymer; (b) emulsifying the colloidal system with a compressed fluid; and (c) contacting the colloidal polymer with the additive in the presence of the compressed fluid. The colloidal polymer can be contacted with the additive by having the additive in the compressed fluid used for emulsification or by adding the additive to the colloidal system before or after emulsification with the compressed fluid. The invention process can be carried out either as a batch process or as a continuous on-line process.

  3. Stretched Polymers in Random Environment

    E-Print Network [OSTI]

    Dmitry Ioffe; Yvan Velenik

    2011-03-01T23:59:59.000Z

    We survey recent results and open questions on the ballistic phase of stretched polymers in both annealed and quenched random environments.

  4. Solid-Liquid Separation of Animal Manure and Wastewater

    E-Print Network [OSTI]

    Mukhtar, Saqib; Sweeten, John M.; Auvermann, Brent W.

    1999-10-19T23:59:59.000Z

    such as ferric chloride (FeCL 3 ), alum (Al 2 (SO 4 ) 3 ) and lime (Ca(OH) 2 ). These chemical treatments may work well for manure with fine particles, such as poultry and swine manure. Laboratory studies have found that ferric chloride and alum are effective... coagulants that help manure solids to gravity settle by sedimentation. A polymer used with ferric chloride or alum produces dense flocs and helps remove solids by the process of screening. Performance and economics of separators Each kind of separator works...

  5. Thin film-coated polymer webs

    DOE Patents [OSTI]

    Wenz, Robert P. (Cottage Grove, MN); Weber, Michael F. (Shoreview, MN); Arudi, Ravindra L. (Woodbury, MN)

    1992-02-04T23:59:59.000Z

    The present invention relates to thin film-coated polymer webs, and more particularly to thin film electronic devices supported upon a polymer web, wherein the polymer web is treated with a purifying amount of electron beam radiation.

  6. Photopatterned conjugated polymer electrochromic nanofibers Arvind Kumara

    E-Print Network [OSTI]

    Otero, Toribio Fernández

    Photopatterned conjugated polymer electrochromic nanofibers on paper Arvind Kumara , Chris Asemotaa. Electrochromic nanofibers of conducting polymer (terthiophene) have been deposited over a conventional paper in electrochromic characters. SEM images of the conducting polymer nanofibers together with the cellulose fibers

  7. Nitinol-reinforced shape-memory polymers

    E-Print Network [OSTI]

    Di Leo, Claudio V

    2010-01-01T23:59:59.000Z

    Reinforced shape-memory polymers have been developed from an acrylate based thermoset shape-memory polymer and nitinol wires. A rectangular shape-memory polymer measuring approximately 1 by 2 by 0.1 inches has a ten fold ...

  8. Nanostructure Control of Biologically Inspired Polymers

    E-Print Network [OSTI]

    Rosales, Adrianne

    2013-01-01T23:59:59.000Z

    E. B. ; Wagener, K. B. Polymer 2008, 49, 2985-2995. Boz,T. ; Matyjaszewski, K. Polymer 2008, 49, 1567-1578. Kim,Flory, P. J. ; Jackson, J. B. Polymer 1963, 4, (2), 221-236.

  9. Highly efficient carbon dioxide capture with a porous organic polymer impregnated with

    E-Print Network [OSTI]

    Paik Suh, Myunghyun

    Highly efficient carbon dioxide capture with a porous organic polymer impregnated environmental crises such as global warming and ocean acidication, efficient carbon dioxide (CO2) capture As CO2 capture mate- rials, numerous solid adsorbents such as silica5 and carbon materials,6 metal

  10. authors demonstrate that the new polymer is highly soluble in common organic solvents,

    E-Print Network [OSTI]

    Nicchitta, Chris

    . & Thelakkat, M. Appl.Phys.Lett. 92, 093302/1 (2008). 10. Cantatore, E. etal. IEEEJ.SolidStateCircuits 42, 84authors demonstrate that the new polymer is highly soluble in common organic solvents stabil- ity. The new material will undoubtedly inspire further work to synthesize other donor­accep- tor

  11. Journal Title: Journal of polymer science. Part B, Polymer physics

    E-Print Network [OSTI]

    Fleming, Paul D. "Dan"

    composites. rigid rod polymer. mo- lecular modeling. poly (azomethine) · epoxy. glass/epoxy composite. Such composites would find * To whom correspondence should be addressed. Journal of Polymer Science: Part B molecular composite. Since heat conduction oc- curs more efficiently intramolecularly (through bonds) than

  12. Influence of confinement on polymer-electrolyte relaxational dynamics.

    SciTech Connect (OSTI)

    Zanotti, J.-M.; Smith, L. J.; Price, D. L.; Saboungi, M.-L.; Intense Pulsed Neutron Source; Lab. Leon Brillouin (CEA-CRNS); Clark Univ.; CRMHT (CNRS); CRMD (CNRS)

    2004-01-01T23:59:59.000Z

    Conception and industrial production of viable high specific energy/power batteries is a central issue for the development of non-polluting vehicles. In terms of stored energy and safety, solid-state devices using polymer electrolytes are highly desirable. One of the most studied systems is PEO (polyethylene oxide) complexed by Li salts. Polymer segmental motions and ionic conductivity are closely related. Bulk PEO is actually a biphasic system where an amorphous and a crystalline state (Tm 335 K) coexist. To improve ionic conduction in those systems requires a significant increase of the amorphous phase fraction where lithium conduction is known to mainly take place. Confinement strongly affects properties of condensed matter and in particular the collective phenomena inducing crystallization. Confinement of the polymer matrix is therefore a possible alternative route to the unpractical use of high temperature. Results of a quasi-elastic incoherent neutron scattering study of the influence of confinement on polyethylene oxide (PEO) and (PEO)8Li+[(CF3SO2)2N]- (or (POE)8LiTFSI) dynamics are presented. The nano-confining media is Vycor, a silica based hydrophilic porous glass (characteristic size of the 3D pore network 50 {angstrom}). As expected, the presence of Li salt slows down the bulk polymer dynamics. The confinement also affects dramatically the apparent mean-square displacement of the polymer. Local relaxational PEO dynamics is described KWW model. We also present an alternate model and show how the detailed polymer dynamics (correlation times and local geometry of the motions) can be described without the use of such stretched exponentials so as to access a rheology-related meaningful physical quantity: the monomeric friction coefficient.

  13. Biomass Biorefinery for the production of Polymers and Fuels

    SciTech Connect (OSTI)

    Dr. Oliver P. Peoples

    2008-05-05T23:59:59.000Z

    The conversion of biomass crops to fuel is receiving considerable attention as a means to reduce our dependence on foreign oil imports and to meet future energy needs. Besides their use for fuel, biomass crops are an attractive vehicle for producing value added products such as biopolymers. Metabolix, Inc. of Cambridge proposes to develop methods for producing biodegradable polymers polyhydroxyalkanoates (PHAs) in green tissue plants as well as utilizating residual plant biomass after polymer extraction for fuel generation to offset the energy required for polymer extraction. The primary plant target is switchgrass, and backup targets are alfalfa and tobacco. The combined polymer and fuel production from the transgenic biomass crops establishes a biorefinery that has the potential to reduce the nation’s dependence on foreign oil imports for both the feedstocks and energy needed for plastic production. Concerns about the widespread use of transgenic crops and the grower’s ability to prevent the contamination of the surrounding environment with foreign genes will be addressed by incorporating and expanding on some of the latest plant biotechnology developed by the project partners of this proposal. This proposal also addresses extraction of PHAs from biomass, modification of PHAs so that they have suitable properties for large volume polymer applications, processing of the PHAs using conversion processes now practiced at large scale (e.g., to film, fiber, and molded parts), conversion of PHA polymers to chemical building blocks, and demonstration of the usefulness of PHAs in large volume applications. The biodegradability of PHAs can also help to reduce solid waste in our landfills. If successful, this program will reduce U.S. dependence on imported oil, as well as contribute jobs and revenue to the agricultural economy and reduce the overall emissions of carbon to the atmosphere.

  14. Singular Limits in Polymer Stabilized Liquid Crystals

    E-Print Network [OSTI]

    1910-31-00T23:59:59.000Z

    We investigate equilibrium configurations for a polymer stabilized liquid crys- tal material ... eling the cross section of the liquid crystal-polymer fiber composite.

  15. Partially fluorinated cyclic ionic polymers and membranes

    DOE Patents [OSTI]

    Yang, Zhen-Yu

    2013-04-09T23:59:59.000Z

    Ionic polymers are made from selected partially fluorinated dienes, in which the repeat units are cycloaliphatic. The polymers are formed into membranes.

  16. Using Theory to Model Polymer Properties There are two general themes to this research: (1) polymer degradation that occurs when

    E-Print Network [OSTI]

    the polymer with nanoinclusions of carbon nanotubes and graphene sheets and other structures. Polymer

  17. Polymers in a vacuum

    E-Print Network [OSTI]

    J. M. Deutsch

    2007-06-13T23:59:59.000Z

    In a variety of situations, isolated polymer molecules are found in a vacuum and here we examine their properties. Angular momentum conservation is shown to significantly alter the average size of a chain and its conservation is only broken slowly by thermal radiation. The time autocorrelation for monomer position oscillates with a characteristic time proportional to chain length. The oscillations and damping are analyzed in detail. Short range repulsive interactions suppress oscillations and speed up relaxation but stretched chains still show damped oscillatory time correlations.

  18. Vacuum flash evaporated polymer composites

    DOE Patents [OSTI]

    Affinito, John D. (Kennewick, WA); Gross, Mark E. (Pasco, WA)

    1997-01-01T23:59:59.000Z

    A method for fabrication of polymer composite layers in a vacuum is disclosed. More specifically, the method of dissolving salts in a monomer solution, vacuum flash evaporating the solution, condensing the flash evaporated solution as a liquid film, and forming the condensed liquid film into a polymer composite layer on a substrate is disclosed.

  19. Vacuum flash evaporated polymer composites

    DOE Patents [OSTI]

    Affinito, J.D.; Gross, M.E.

    1997-10-28T23:59:59.000Z

    A method for fabrication of polymer composite layers in a vacuum is disclosed. More specifically, the method of dissolving salts in a monomer solution, vacuum flash evaporating the solution, condensing the flash evaporated solution as a liquid film, and forming the condensed liquid film into a polymer composite layer on a substrate is disclosed.

  20. High elastic modulus polymer electrolytes suitable for preventing thermal runaway in lithium batteries

    DOE Patents [OSTI]

    Mullin, Scott; Panday, Ashoutosh; Balsara, Nitash Pervez; Singh, Mohit; Eitouni, Hany Basam; Gomez, Enrique Daniel

    2014-04-22T23:59:59.000Z

    A polymer that combines high ionic conductivity with the structural properties required for Li electrode stability is useful as a solid phase electrolyte for high energy density, high cycle life batteries that do not suffer from failures due to side reactions and dendrite growth on the Li electrodes, and other potential applications. The polymer electrolyte includes a linear block copolymer having a conductive linear polymer block with a molecular weight of at least 5000 Daltons, a structural linear polymer block with an elastic modulus in excess of 1.times.10.sup.7 Pa and an ionic conductivity of at least 1.times.10.sup.-5 Scm.sup.-1. The electrolyte is made under dry conditions to achieve the noted characteristics. In another aspect, the electrolyte exhibits a conductivity drop when the temperature of electrolyte increases over a threshold temperature, thereby providing a shutoff mechanism for preventing thermal runaway in lithium battery cells.

  1. Mixed oxide solid solutions

    DOE Patents [OSTI]

    Magno, Scott (Dublin, CA); Wang, Ruiping (Fremont, CA); Derouane, Eric (Liverpool, GB)

    2003-01-01T23:59:59.000Z

    The present invention is a mixed oxide solid solution containing a tetravalent and a pentavalent cation that can be used as a support for a metal combustion catalyst. The invention is furthermore a combustion catalyst containing the mixed oxide solid solution and a method of making the mixed oxide solid solution. The tetravalent cation is zirconium(+4), hafnium(+4) or thorium(+4). In one embodiment, the pentavalent cation is tantalum(+5), niobium(+5) or bismuth(+5). Mixed oxide solid solutions of the present invention exhibit enhanced thermal stability, maintaining relatively high surface areas at high temperatures in the presence of water vapor.

  2. Solid Waste Management (Connecticut)

    Broader source: Energy.gov [DOE]

    Solid waste facilities operating in Connecticut must abide by these regulations, which describe requirements and procedures for issuing construction and operating permits; environmental...

  3. Solid Waste Permits (Louisiana)

    Broader source: Energy.gov [DOE]

    The Louisiana Department of Environmental Quality administers the rules and regulations governing the storage, collection, processing, recovery, and reuse of solid waste protect the air,...

  4. Solid Waste Management (Indiana)

    Broader source: Energy.gov [DOE]

    The state supports the implementation of source reduction, recycling, and other alternative solid waste management practices over incineration and land disposal. The Indiana Department of...

  5. Solid Waste Management (Michigan)

    Broader source: Energy.gov [DOE]

    This Act encourages the Department of Environmental Quality and Health Department representatives to develop and encourage methods for disposing solid waste that are environmentally sound, that...

  6. Nanowires and Nanostructures That Grow Like Polymer Molecules

    SciTech Connect (OSTI)

    Shaw, Santosh [Iowa State University; Cademartiri, Ludovico [Ames Laboratory

    2013-09-20T23:59:59.000Z

    Unique properties (e.g., rubber elasticity, viscoelasticity, folding, reptation) determine the utility of polymer molecules and derive from their morphology (i.e., one-dimensional connectivity and large aspect ratios) and flexibility. Crystals do not display similar properties because they have smaller aspect ratios, they are rigid, and they are often too large and heavy to be colloidally stable. We argue, with the support of recent experimental studies, that these limitations are not fundamental and that they might be overcome by growth processes that mimic polymerization. Furthermore, we (i) discuss the similarities between crystallization and polymerization, (ii) critically review the existing experimental evidence of polymer-like growth kinetic and behavior in crystals and nanostructures, and (iii) propose heuristic guidelines for the synthesis of “polymer-like” crystals and assemblies. Understanding these anisotropic materials at the boundary between molecules and solids will determine whether we can confer the unique properties of polymer molecules to crystals, expanding them with topology, dynamics, and information and not just tuning them with size.

  7. Accelerated Characterization of Polymer Properties

    SciTech Connect (OSTI)

    R. Wroczynski; l. Brewer; D. Buckley; M. Burrell; R. Potyrailo

    2003-07-30T23:59:59.000Z

    This report describes the efforts to develop a suite of microanalysis techniques that can rapidly measure a variety of polymer properties of industrial importance, including thermal, photo-oxidative, and color stability; as well as ductility, viscosity, and mechanical and antistatic properties. Additional goals of the project were to direct the development of these techniques toward simultaneous measurements of multiple polymer samples of small size in real time using non-destructive and/or parallel or rapid sequential measurements, to develop microcompounding techniques for preparing polymers with additives, and to demonstrate that samples prepared in the microcompounder could be analyzed directly or used in rapid off-line measurements. These enabling technologies are the crucial precursors to the development of high-throughput screening (HTS) methodologies for the polymer additives industry whereby the rate of development of new additives and polymer formulations can be greatly accelerated.

  8. Rotational dynamics of entangled polymers

    E-Print Network [OSTI]

    Jean-Charles Walter; Michiel Laleman; Marco Baiesi; Enrico Carlon

    2014-09-01T23:59:59.000Z

    Some recent results on the rotational dynamics of polymers are reviewed and extended. We focus here on the relaxation of a polymer, either flexible or semiflexible, initially wrapped around a rigid rod. We also study the steady polymer rotation generated by a constant torque on the rod. The interplay of frictional and entropic forces leads to a complex dynamical behavior characterized by non-trivial universal exponents. The results are based on extensive simulations of polymers undergoing Rouse dynamics and on an analytical approach using force balance and scaling arguments. The analytical results are in general in good agreement with the simulations, showing how a simplified approach can correctly capture the complex dynamical behavior of rotating polymers.

  9. Oilfield flooding polymer

    DOE Patents [OSTI]

    Martin, Fred D. (Socorro, NM); Hatch, Melvin J. (Socorro, NM); Shepitka, Joel S. (Socorro, NM); Donaruma, Lorraine G. (Syosset, NY)

    1986-01-01T23:59:59.000Z

    A monomer, polymers containing the monomer, and the use of the polymer in oilfield flooding is disclosed. The subject monomer is represented by the general formula: ##STR1## wherein: n is an integer from 0 to about 4; m is an integer from 0 to about 6; a is an integer equal to at least 1 except where m is equal to 0, a must equal 0 and where m is equal to 1, a must equal 0 or 1; p is an integer from 2 to about 10; b is an integer equal to at least 1 and is of sufficient magnitude that the ratio b/p is at least 0.2; and q is an integer from 0 to 2. The number of hydroxy groups in the monomer is believed to be critical, and therefore the sum of (a+b) divided by the sum (m+p) should be at least 0.2. The moieties linked to the acrylic nitrogen can be joined to provide a ringed structure.

  10. Polymer solutions: from hard monomers to soft polymers

    E-Print Network [OSTI]

    J. -P. Hansen; C. I. Addison; A. A. Louis

    2005-07-15T23:59:59.000Z

    A coarse-graining strategy for dilute and semi-dilute solutions of interacting polymers, and of colloid polymer mixtures is briefly described. Monomer degrees of freedom are traced out to derive an effective, state dependent pair potential between the polymer centres of mass. The cross-over between good and poor solvent conditions is discussed within a scaling analysis. The method is extended to block copolymers represented as "necklaces" of soft "blobs", and its success is illustrated here in the case of a symmetric diblock copolymer which exhibits microphase separation.

  11. High solids fermentation reactor

    DOE Patents [OSTI]

    Wyman, Charles E.; Grohmann, Karel; Himmel, Michael E.; Richard, Christopher J.

    1993-03-02T23:59:59.000Z

    A fermentation reactor and method for fermentation of materials having greater than about 10% solids. The reactor includes a rotatable shaft along the central axis, the shaft including rods extending outwardly to mix the materials. The reactor and method are useful for anaerobic digestion of municipal solid wastes to produce methane, for production of commodity chemicals from organic materials, and for microbial fermentation processes.

  12. High solids fermentation reactor

    DOE Patents [OSTI]

    Wyman, Charles E. (Lakewood, CO); Grohmann, Karel (Littleton, CO); Himmel, Michael E. (Littleton, CO); Richard, Christopher J. (Lakewood, CO)

    1993-01-01T23:59:59.000Z

    A fermentation reactor and method for fermentation of materials having greater than about 10% solids. The reactor includes a rotatable shaft along the central axis, the shaft including rods extending outwardly to mix the materials. The reactor and method are useful for anaerobic digestion of municipal solid wastes to produce methane, for production of commodity chemicals from organic materials, and for microbial fermentation processes.

  13. Solid Flame: Fundamentals and

    E-Print Network [OSTI]

    Mukasyan, Alexander

    ;Self-propagating High-temperature Synthesis (SHS) Or Combustion Synthesis TECHNOLOGY FOR MATERIAL (solid) ignition front propagation cooling The Phenomenon of Wave Localization for Solid State Self-propagating) 1.0000 Temperature (K) 2744 Gas products amount (mol) 6.00E-15 Products heat capacity (J/K) 74

  14. Regenerable solid imine sorbents

    DOE Patents [OSTI]

    Gray, McMahan; Champagne, Kenneth J.; Fauth, Daniel; Beckman, Eric

    2013-09-10T23:59:59.000Z

    Two new classes of amine-based sorbents are disclosed. The first class comprises new polymer-immobilized tertiary amine sorbents; the second class new polymer-bound amine sorbents. Both classes are tailored to facilitate removal of acid anhydrides, especially carbon dioxide (CO.sub.2), from effluent gases. The amines adsorb acid anhydrides in a 1:1 molar ratio. Both classes of amine sorbents adsorb in the temperature range from about 20.degree. C. upwards to 90.degree. C. and can be regenerated by heating upwards to 100.degree. C.

  15. Polymer Thermodynamics and Chain Structure Polymers display some similarities and some differences with nano-aggregates.

    E-Print Network [OSTI]

    Beaucage, Gregory

    Polymer Thermodynamics and Chain Structure Polymers display some similarities and some differences with nano-aggregates. Both materials are composed of basic units, Kuhn units for polymers which are rod an aggregate in nanomaterials and a polymer coil in Polymer Science. The mass-fractal or minimum dimension

  16. Polymer adsorption near the surface of a polymer solution : a universal behaviour

    E-Print Network [OSTI]

    Boyer, Edmond

    699 Polymer adsorption near the surface of a polymer solution : a universal behaviour J. des5 , pour 0 03B5 1. Abstract.2014 A universal property of good solutions of long polymers near. Introduction. The free surface of a polymer solution may attract the polymer which forms an adsorbed layer

  17. ENG BE/ME/MS 504: Polymers and Soft Materials GRS PY 744: Polymer Physics.

    E-Print Network [OSTI]

    Vajda, Sandor

    ENG BE/ME/MS 504: Polymers and Soft Materials GRS PY 744: Polymer Physics. Prof. Rama Bansil Class will be assumed. The course will not emphasize synthetic polymer chemistry. Practical applications of polymers of classes TEXT BOOKS Main Text Book: Required: Polymer Chemistry, 2nd Edition, Hiemenz and Lodge, CRC Press

  18. Carbon nanotube-polymer composite actuators

    DOE Patents [OSTI]

    Gennett, Thomas (Denver, CO); Raffaelle, Ryne P. (Honeoye Falls, NY); Landi, Brian J. (Rochester, NY); Heben, Michael J. (Denver, CO)

    2008-04-22T23:59:59.000Z

    The present invention discloses a carbon nanotube (SWNT)-polymer composite actuator and method to make such actuator. A series of uniform composites was prepared by dispersing purified single wall nanotubes with varying weight percents into a polymer matrix, followed by solution casting. The resulting nanotube-polymer composite was then successfully used to form a nanotube polymer actuator.

  19. Kac polymers Paolo Butt`a

    E-Print Network [OSTI]

    Procacci, Aldo

    Kac polymers Paolo Butt`a Aldo Procacci Benedetto Scoppola Abstract We show how a polymer in two- sidered on the appropriate scale. Key words: Polymers, Kac potentials, phase transition. Running title: Kac polymers Dedicated to a Marzio Cassandro's birthday. 1 Introduction In the last two decades

  20. Non-strinking siloxane polymers

    DOE Patents [OSTI]

    Loy, Douglas A. (Albuquerque, NM); Rahimian, Kamyar (Albuquerque, NM)

    2001-01-01T23:59:59.000Z

    Cross-linked polymers formed by ring-opening polymerization of a precursor monomer of the general formula R[CH.sub.2 CH(Si(CH.sub.3).sub.2).sub.2 O].sub.2, where R is a phenyl group or an alkyl group having at least two carbon atoms. A cross-linked polymer is synthesized by mixing the monomer with a co-monomer of the general formula CH.sub.2 CHR.sup.2 (SiMe.sub.2).sub.2 O in the presence of an anionic base to form a cross-linked polymer of recurring units of the general formula R(Me.sub.2 SiOCH.sub.2 CHSiMe.sub.2).sub.2 [CH.sub.2 CHR.sup.2 (SiMe.sub.2).sub.2 O].sub.n, where R.sup.2 is hydrogen, phenyl, ethyl, propyl or butyl. If the precursor monomer is a liquid, the polymer can be directly synthesized in the presence of an anionic base to a cross-linked polymer containing recurring units of the general formula R(Me.sub.2 SiOCH.sub.2 CHSiMe.sub.2).sub.2. The polymers have approximately less than 1% porosity and are thermally stable at temperatures up to approximately 500.degree. C. The conversion to the cross-linked polymer occurs by ring opening polymerization and results in shrinkage of less than approximately 5% by volume.

  1. Thermodynamics of tubelike flexible polymers

    E-Print Network [OSTI]

    Thomas Vogel; Thomas Neuhaus; Michael Bachmann; Wolfhard Janke

    2009-07-17T23:59:59.000Z

    In this work we present the general phase behavior of short tubelike flexible polymers. The geometric thickness constraint is implemented through the concept of the global radius of curvature. We use sophisticated Monte Carlo sampling methods to simulate small bead-stick polymer models with Lennard-Jones interaction among non-bonded monomers. We analyze energetic fluctuations and structural quantities to classify conformational pseudophases. We find that the tube thickness influences the thermodynamic behavior of simple tubelike polymers significantly, i.e., for given temperature, the formation of secondary structures strongly depends on the tube thickness.

  2. Management of Solid Waste (Oklahoma)

    Broader source: Energy.gov [DOE]

    The Solid Waste Management Division of the Department of Environmental Quality regulates solid waste disposal or any person who generates, collects, transports, processes, and/or disposes of solid...

  3. Adsorption of comb copolymers on weakly attractive solid surfaces A. Strioloa

    E-Print Network [OSTI]

    Jayaraman, Arthi

    Adsorption of comb copolymers on weakly attractive solid surfaces A. Strioloa Department In this work continuum and lattice Monte Carlo simulation methods are used to study the adsorption of linear. At infinite dilution the presence of short side chains promotes the adsorption of polymers favoring both

  4. Solid-State NMR Study of Intercalated Species in Poly( -caprolactone)/Clay Nanocomposites

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Solid-State NMR Study of Intercalated Species in Poly( - caprolactone)/Clay Nanocomposites J of surfactant and polymer chains in intercalated poly( - caprolactone)/clay nanocomposites are characterized by 31 P magic-angle spinning (MAS) and 13 C cross-polarization MAS NMR techniques. To obtain hybrid

  5. Structure of All-Polymer Solar Cells Impedes Efficiency

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengthening a solid ... Strengthening aStructure of All-Polymer Solar Cells

  6. Characterization of macro-length conducting polymers and the development of a conducting polymer rotary motor

    E-Print Network [OSTI]

    Schmid, Bryan D. (Bryan David), 1981-

    2005-01-01T23:59:59.000Z

    Conducting polymers are a subset of materials within the electroactive polymer class that exhibit active mechanical deformations. These deformations induce stresses and strains that allow for conducting polymers to be used ...

  7. Polymer electronic devices and materials.

    SciTech Connect (OSTI)

    Schubert, William Kent; Baca, Paul Martin; Dirk, Shawn M.; Anderson, G. Ronald; Wheeler, David Roger

    2006-01-01T23:59:59.000Z

    Polymer electronic devices and materials have vast potential for future microsystems and could have many advantages over conventional inorganic semiconductor based systems, including ease of manufacturing, cost, weight, flexibility, and the ability to integrate a wide variety of functions on a single platform. Starting materials and substrates are relatively inexpensive and amenable to mass manufacturing methods. This project attempted to plant the seeds for a new core competency in polymer electronics at Sandia National Laboratories. As part of this effort a wide variety of polymer components and devices, ranging from simple resistors to infrared sensitive devices, were fabricated and characterized. Ink jet printing capabilities were established. In addition to promising results on prototype devices the project highlighted the directions where future investments must be made to establish a viable polymer electronics competency.

  8. Continuous production of conducting polymer

    E-Print Network [OSTI]

    Gaige, Terry A. (Terry Alden), 1981-

    2004-01-01T23:59:59.000Z

    A device to continuously produce polypyrrole was designed, manufactured, and tested. Polypyrrole is a conducting polymer which has potential artificial muscle applications. The objective of continuous production was to ...

  9. Constitutive modeling of active polymers

    E-Print Network [OSTI]

    Therkelsen, Scott V. (Scott Vincent), 1980-

    2005-01-01T23:59:59.000Z

    This thesis develops a three-dimensional constitutive model of active polymeric materials, including changes in material volume and properties due to actuation. Active polymers reversibly change shape, volume and/or material ...

  10. A conjugated polymer plastic gel

    E-Print Network [OSTI]

    Alcazar Jorba, Daniel

    2008-01-01T23:59:59.000Z

    We present a gel route to process highly oriented conjugated polymer films and fibers. The incorporation of hexafluoroisopropanol, a strong and stable dipolar group, to the polythiophene backbone enhances the solubility ...

  11. Conductive polymer-based material

    DOE Patents [OSTI]

    McDonald, William F. (Utica, OH); Koren, Amy B. (Lansing, MI); Dourado, Sunil K. (Ann Arbor, MI); Dulebohn, Joel I. (Lansing, MI); Hanchar, Robert J. (Charlotte, MI)

    2007-04-17T23:59:59.000Z

    Disclosed are polymer-based coatings and materials comprising (i) a polymeric composition including a polymer having side chains along a backbone forming the polymer, at least two of the side chains being substituted with a heteroatom selected from oxygen, nitrogen, sulfur, and phosphorus and combinations thereof; and (ii) a plurality of metal species distributed within the polymer. At least a portion of the heteroatoms may form part of a chelation complex with some or all of the metal species. In many embodiments, the metal species are present in a sufficient concentration to provide a conductive material, e.g., as a conductive coating on a substrate. The conductive materials may be useful as the thin film conducting or semi-conducting layers in organic electronic devices such as organic electroluminescent devices and organic thin film transistors.

  12. Polyphosphazine-based polymer materials

    DOE Patents [OSTI]

    Fox, Robert V.; Avci, Recep; Groenewold, Gary S.

    2010-05-25T23:59:59.000Z

    Methods of removing contaminant matter from porous materials include applying a polymer material to a contaminated surface, irradiating the contaminated surface to cause redistribution of contaminant matter, and removing at least a portion of the polymer material from the surface. Systems for decontaminating a contaminated structure comprising porous material include a radiation device configured to emit electromagnetic radiation toward a surface of a structure, and at least one spray device configured to apply a capture material onto the surface of the structure. Polymer materials that can be used in such methods and systems include polyphosphazine-based polymer materials having polyphosphazine backbone segments and side chain groups that include selected functional groups. The selected functional groups may include iminos, oximes, carboxylates, sulfonates, .beta.-diketones, phosphine sulfides, phosphates, phosphites, phosphonates, phosphinates, phosphine oxides, monothio phosphinic acids, and dithio phosphinic acids.

  13. Polymer Bose--Einstein Condensates

    E-Print Network [OSTI]

    E. Castellanos; G. Chacon-Acosta

    2013-01-22T23:59:59.000Z

    In this work we analyze a non--interacting one dimensional polymer Bose--Einstein condensate in an harmonic trap within the semiclassical approximation. We use an effective Hamiltonian coming from the polymer quantization that arises in loop quantum gravity. We calculate the number of particles in order to obtain the critical temperature. The Bose--Einstein functions are replaced by series, whose high order terms are related to powers of the polymer length. It is shown that the condensation temperature presents a shift respect to the standard case, for small values of the polymer scale. In typical experimental conditions, it is possible to establish a bound for $\\lambda^{2}$ up to $ \\lesssim 10 ^{-16}$m$^2$. To improve this bound we should decrease the frequency of the trap and also decrease the number of particles.

  14. Layered plasma polymer composite membranes

    DOE Patents [OSTI]

    Babcock, W.C.

    1994-10-11T23:59:59.000Z

    Layered plasma polymer composite fluid separation membranes are disclosed, which comprise alternating selective and permeable layers for a total of at least 2n layers, where n is [>=]2 and is the number of selective layers. 2 figs.

  15. Solid Waste Management Act (Oklahoma)

    Broader source: Energy.gov [DOE]

    This Act establishes rules for the permitting, posting of security, construction, operation, closure, maintenance and remediation of solid waste disposal sites; disposal of solid waste in ways that...

  16. Solid Waste Rules (New Hampshire)

    Broader source: Energy.gov [DOE]

    The solid waste statute applies to construction and demolition debris, appliances, recyclables, and the facilities that collect, process, and dispose of solid waste. DES oversees the management of...

  17. Solid Waste Management (North Carolina)

    Broader source: Energy.gov [DOE]

    The Solid Waste Program regulates safe management of solid waste through guidance, technical assistance, regulations, permitting, environmental monitoring, compliance evaluation and enforcement....

  18. Hydrogen-Bond Acidic Polymers for Chemical Vapor Sensing. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Acidic Polymers for Chemical Vapor Sensing. Hydrogen-Bond Acidic Polymers for Chemical Vapor Sensing. Abstract: A review with 171 references. Hydrogen-bond acidic polymers for...

  19. Exploring Polymer and Liposomal Carriers for Optimized Drug Delivery

    E-Print Network [OSTI]

    Ferguson, Heidi M

    2012-01-01T23:59:59.000Z

    1459–1467. Fox, M. E. Dendritic polymers for the delivery ofiii Chapter 1: Introduction to Polymer and Liposome Drugbioavailability. Conclusions Polymers and liposomes can be

  20. Polymer-Ceramic MEMS Bimorphs as Thermal Infrared Sensors

    E-Print Network [OSTI]

    Warren, Clinton Gregory

    2010-01-01T23:59:59.000Z

    Recent Developments in Polymer MEMS. Advanced Materials,using thin silicon/polymer bimorph membranes. Sensors andof cantilever arrays reveal polymer film expansion and

  1. Vadose Zone Soil Moisture Wicking Using Super Absorbent Polymers...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Vadose Zone Soil Moisture Wicking Using Super Absorbent Polymers. Vadose Zone Soil Moisture Wicking Using Super Absorbent Polymers. Abstract: Super-absorbent polymers (SAPs) have...

  2. a-1 polymer chemistry: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    walk in random Sepplinen, Timo 16 Polymer-Metal Nanocomposites via Polymer Thin Film Computer Technologies and Information Sciences Websites Summary: Polymer-Metal...

  3. Coordination polymers and building blocks based on ditopic heteroscorpionate ligands

    E-Print Network [OSTI]

    Santillan, Guillermo A.

    2009-01-01T23:59:59.000Z

    of Silver (I) Coordination Polymers formed through hydrogenBlocks for Coordination Polymers” Inorg. Chem. *One of theof Silver(I) Coordination Polymers Formed through Hydrogen

  4. Characterization of the molecular structure and mechanical properties of polymer surfaces and protein/polymer interfaces by sum frequency generation vibrational spectroscopy and atomic force microscopy

    SciTech Connect (OSTI)

    Koffas, Telly Stelianos

    2004-05-15T23:59:59.000Z

    Sum frequency generation (SFG) vibrational spectroscopy, atomic force microscopy (AFM), and other complementary surface-sensitive techniques have been used to study the surface molecular structure and surface mechanical behavior of biologically-relevant polymer systems. SFG and AFM have emerged as powerful analytical tools to deduce structure/property relationships, in situ, for polymers at air, liquid and solid interfaces. The experiments described in this dissertation have been performed to understand how polymer surface properties are linked to polymer bulk composition, substrate hydrophobicity, changes in the ambient environment (e.g., humidity and temperature), or the adsorption of macromolecules. The correlation of spectroscopic and mechanical data by SFG and AFM can become a powerful methodology to study and engineer materials with tailored surface properties. The overarching theme of this research is the interrogation of systems of increasing structural complexity, which allows us to extend conclusions made on simpler model systems. We begin by systematically describing the surface molecular composition and mechanical properties of polymers, copolymers, and blends having simple linear architectures. Subsequent chapters focus on networked hydrogel materials used as soft contact lenses and the adsorption of protein and surfactant at the polymer/liquid interface. The power of SFG is immediately demonstrated in experiments which identify the chemical parameters that influence the molecular composition and ordering of a polymer chain's side groups at the polymer/air and polymer/liquid interfaces. In general, side groups with increasingly greater hydrophobic character will be more surface active in air. Larger side groups impose steric restrictions, thus they will tend to be more randomly ordered than smaller hydrophobic groups. If exposed to a hydrophilic environment, such as water, the polymer chain will attempt to orient more of its hydrophilic groups to the surface in order to minimize the total surface energy. With an understanding of the structural and environmental parameters which govern polymer surface structure, SFG is then used to explore the effects of surface hydrophobicity and solvent polarity on the orientation and ordering of amphiphilic neutral polymers adsorbed at the solid/liquid interface. SFG spectra show that poly(propylene glycol) (PPG) and poly(ethylene glycol) (PEG) adsorb with their hydrophobic moieties preferentially oriented toward hydrophobic polystyrene surfaces. These same moieties, however, disorder when adsorbed onto a hydrophilic silica/water interface. Water is identified as a critical factor for mediating the orientation and ordering of hydrophobic moieties in polymers adsorbed at hydrophobic interfaces. The role of bulk water content and water vapor, as they influence hydrogel surface structure and mechanics, continues to be explored in the next series of experiments. A method was developed to probe the surface viscoelastic properties of hydroxylethyl methacrylate (HEMA) based contact lens materials by analyzing AFM force-distance curves. AFM analysis indicates that the interfacial region is dehydrated, relative to the bulk. Experiments performed on poly(HEMA+MA) (MA = methacrylic acid), a more hydrophilic copolymer with greater bulk water content, show even greater water depletion at the surface. SFG spectra, as well as surface energy arguments, suggest that the more hydrophilic polymer component (such as MA) is not favored at the air interface; this may explain anomalies in water retention at the hydrogel surface. Adsorption of lysozyme onto poly(HEMA+MA) was found to further reduce near-surface viscous behavior, suggesting lower surface water content. Lastly, protein adsorption is studied using a model polymer system of polystyrene covalently bound with a monolayer of bovine serum albumin. SFG results indicate that some amino acid residues in proteins adopt preferred orientations. SFG spectra also show that the phenyl rings of the bare polystyrene substrate in contact with air or

  5. Solids Accumulation Scouting Studies

    SciTech Connect (OSTI)

    Duignan, M. R.; Steeper, T. J.; Steimke, J. L.

    2012-09-26T23:59:59.000Z

    The objective of Solids Accumulation activities was to perform scaled testing to understand the behavior of remaining solids in a Double Shell Tank (DST), specifically AW-105, at Hanford during multiple fill, mix, and transfer operations. It is important to know if fissionable materials can concentrate when waste is transferred from staging tanks prior to feeding waste treatment plants. Specifically, there is a concern that large, dense particles containing plutonium could accumulate in poorly mixed regions of a blend tank heel for tanks that employ mixing jet pumps. At the request of the DOE Hanford Tank Operations Contractor, Washington River Protection Solutions, the Engineering Development Laboratory of the Savannah River National Laboratory performed a scouting study in a 1/22-scale model of a waste staging tank to investigate this concern and to develop measurement techniques that could be applied in a more extensive study at a larger scale. Simulated waste tank solids: Gibbsite, Zirconia, Sand, and Stainless Steel, with stainless steel particles representing the heavier particles, e.g., plutonium, and supernatant were charged to the test tank and rotating liquid jets were used to mix most of the solids while the simulant was pumped out. Subsequently, the volume and shape of the mounds of residual solids and the spatial concentration profiles for the surrogate for heavier particles were measured. Several techniques were developed and equipment designed to accomplish the measurements needed and they included: 1. Magnetic particle separator to remove simulant stainless steel solids. A device was designed and built to capture these solids, which represent the heavier solids during a waste transfer from a staging tank. 2. Photographic equipment to determine the volume of the solids mounds. The mounds were photographed as they were exposed at different tank waste levels to develop a composite of topographical areas. 3. Laser rangefinders to determine the volume of the solids mounds. The mounds were scanned after tank supernatant was removed. 4. Core sampler to determine the stainless steel solids distribution within the solids mounds. This sampler was designed and built to remove small sections of the mounds to evaluate concentrations of the stainless steel solids at different special locations. 5. Computer driven positioner that placed the laser rangefinders and the core sampler in appropriate locations over solids mounds that accumulated on the bottom of a scaled staging tank where mixing is poor. These devices and techniques were effective to estimate the movement, location, and concentrations of the solids representing heavier particles and could perform well at a larger scale The experiment contained two campaigns with each comprised of ten cycles to fill and empty the scaled staging tank. The tank was filled without mixing, but emptied, while mixing, in seven batches; the first six were of equal volumes of 13.1 gallons each to represent the planned fullscale batches of 145,000 gallons, and the last, partial, batch of 6.9 gallons represented a full-scale partial batch of 76,000 gallons that will leave a 72-inch heel in the staging tank for the next cycle. The sole difference between the two campaigns was the energy to mix the scaled staging tank, i.e., the nozzle velocity and jet rotational speed of the two jet pumps. Campaign 1 used 22.9 ft/s, at 1.54 rpm based on past testing and Campaign 2 used 23.9 ft/s at 1.75 rpm, based on visual observation of minimum velocity that allowed fast settling solids, i.e., sand and stainless steel, to accumulate on the scaled tank bottom.

  6. Solid Waste Management (Kansas)

    Broader source: Energy.gov [DOE]

    This act aims to establish and maintain a cooperative state and local program of planning and technical and financial assistance for comprehensive solid waste management. No person shall construct,...

  7. Novel solid state proton-conductors based on polymeric non-oxy acids. Final report

    SciTech Connect (OSTI)

    Appleby, A.J.; Srinivasan, S.; Parthasarathy, A.; Gonzalez, E.R. [Texas A and M Univ., College Station, TX (United States). Center for Electrochemical Systems and Hydrogen Research; DesMarteau, D.; Gillette, M.S.; Ghosh, J.K. [Clemson Univ., SC (United States). Dept. of Chemistry; Jalan, V.; Desai, M. [ElectroChem, Inc., Woburn, MA (United States)

    1992-01-01T23:59:59.000Z

    Objectives of this project were to prepare and characterize novel solid state proton-conductors and to evaluate these compounds as fuel cell electrolytes. The thrust was on the synthesis of new proton-conducting ``model`` and ``polymeric`` compounds, based on acid functions of the type (R{sub f}SO{sub 2}){sub 2}NH and (R{sub f}SO{sub 2}){sub 2}CH{sub 2} in appropriate fluorinated carbon structures, their physics-chemical characterization (Infra-red, Nuclear Magnetic Resonance, Differential Scanning Calorimetry, and X-ray Diffraction), and is pro. evaluation as candidate fuel cell electrolytes for use at elevated temperatures. This project consisted of four tasks (i) Synthesis of Proton-Conducting Polymer Electrolytes; (ii) Physical and Chemical Characterization of Proton-Conducting Polymer Electrolytes; (iii) Electrochemical Characterization of Proton-Conducting Polymer Electrolytes; and (iv) Evaluation of Proton-Conducting Polymer Electrolytes for Fuel Cells.

  8. Solid model design simplification

    SciTech Connect (OSTI)

    Ames, A.L.; Rivera, J.J.; Webb, A.J.; Hensinger, D.M.

    1997-12-01T23:59:59.000Z

    This paper documents an investigation of approaches to improving the quality of Pro/Engineer-created solid model data for use by downstream applications. The investigation identified a number of sources of problems caused by deficiencies in Pro/Engineer`s geometric engine, and developed prototype software capable of detecting many of these problems and guiding users towards simplified, useable models. The prototype software was tested using Sandia production solid models, and provided significant leverage in attacking the simplification problem.

  9. Nanostructured polymer membranes for proton conduction

    DOE Patents [OSTI]

    Balsara, Nitash Pervez; Park, Moon Jeong

    2013-06-18T23:59:59.000Z

    Polymers having an improved ability to entrain water are characterized, in some embodiments, by unusual humidity-induced phase transitions. The described polymers (e.g., hydrophilically functionalized block copolymers) have a disordered state and one or more ordered states (e.g., a lamellar state, a gyroid state, etc.). In one aspect, the polymers are capable of undergoing a disorder-to-order transition while the polymer is exposed to an increasing temperature at a constant relative humidity. In some aspects the polymer includes a plurality of portions, wherein a first portion forms proton-conductive channels within the membrane and wherein the channels have a width of less than about 6 nm. The described polymers are capable of entraining and preserving water at high temperature and low humidity. Surprisingly, in some embodiments, the polymers are capable of entraining greater amounts of water with the increase of temperature. The polymers can be used in Polymer Electrolyte Membranes in fuel cells.

  10. Polymer Parametrised Field Theory

    E-Print Network [OSTI]

    Alok Laddha; Madhavan Varadarajan

    2008-05-02T23:59:59.000Z

    Free scalar field theory on 2 dimensional flat spacetime, cast in diffeomorphism invariant guise by treating the inertial coordinates of the spacetime as dynamical variables, is quantized using LQG type `polymer' representations for the matter field and the inertial variables. The quantum constraints are solved via group averaging techniques and, analogous to the case of spatial geometry in LQG, the smooth (flat) spacetime geometry is replaced by a discrete quantum structure. An overcomplete set of Dirac observables, consisting of (a) (exponentials of) the standard free scalar field creation- annihilation modes and (b) canonical transformations corresponding to conformal isometries, are represented as operators on the physical Hilbert space. None of these constructions suffer from any of the `triangulation' dependent choices which arise in treatments of LQG. In contrast to the standard Fock quantization, the non- Fock nature of the representation ensures that the algebra of conformal isometries as well as that of spacetime diffeomorphisms are represented in an anomaly free manner. Semiclassical states can be analysed at the gauge invariant level. It is shown that `physical weaves' necessarily underly such states and that such states display semiclassicality with respect to, at most, a countable subset of the (uncountably large) set of observables of type (a). The model thus offers a fertile testing ground for proposed definitions of quantum dynamics as well as semiclassical states in LQG.

  11. SUPER HARD SURFACED POLYMERS

    SciTech Connect (OSTI)

    Mansur, Louis K [ORNL] [ORNL; Bhattacharya, R [UES, Incorporated, Dayton, OH] [UES, Incorporated, Dayton, OH; Blau, Peter Julian [ORNL] [ORNL; Clemons, Art [ORNL] [ORNL; Eberle, Cliff [ORNL] [ORNL; Evans, H B [UES, Incorporated, Dayton, OH] [UES, Incorporated, Dayton, OH; Janke, Christopher James [ORNL] [ORNL; Jolly, Brian C [ORNL] [ORNL; Lee, E H [Consultant, Milpitas, CA] [Consultant, Milpitas, CA; Leonard, Keith J [ORNL] [ORNL; Trejo, Rosa M [ORNL] [ORNL; Rivard, John D [ORNL] [ORNL

    2010-01-01T23:59:59.000Z

    High energy ion beam surface treatments were applied to a selected group of polymers. Of the six materials in the present study, four were thermoplastics (polycarbonate, polyethylene, polyethylene terephthalate, and polystyrene) and two were thermosets (epoxy and polyimide). The particular epoxy evaluated in this work is one of the resins used in formulating fiber reinforced composites for military helicopter blades. Measures of mechanical properties of the near surface regions were obtained by nanoindentation hardness and pin on disk wear. Attempts were also made to measure erosion resistance by particle impact. All materials were hardness tested. Pristine materials were very soft, having values in the range of approximately 0.1 to 0.5 GPa. Ion beam treatment increased hardness by up to 50 times compared to untreated materials. For reference, all materials were hardened to values higher than those typical of stainless steels. Wear tests were carried out on three of the materials, PET, PI and epoxy. On the ion beam treated epoxy no wear could be detected, whereas the untreated material showed significant wear.

  12. Development of shape memory polymer (SMP) blend for biomedical and clinical applications Shape memory polymers (SMP) are a class of responsive stimuli materials that are able to respond to external stimulus

    E-Print Network [OSTI]

    Development of shape memory polymer (SMP) blend for biomedical and clinical applications Shape properties of this shape memory biopolymers and blends. The bio-compatible SMP blend will be fabricated by melt-blending and gas foaming. The various shape memory and mechanical properties of the foam and solid

  13. Propagation of polymer slugs through porous media

    SciTech Connect (OSTI)

    Lecourtier, J.; Chauveteau, G.

    1984-09-01T23:59:59.000Z

    This paper describes an experimental and theoretical study of the mechanisms governing polymer slug propagation through porous media. An analytical model taking into account the macromolecule exclusion from pore walls is proposed to predict rodlike polymer velocity in porous media and thus the spreading out of polydispersed polymer slugs. Under conditions where this wall exclusion is maximum, i.e. at low shear rates and polymer concentrations, the experiments show that xanthan propagation is effectively predicted by this model. At higher flow rates and polymer concentrations, the effects of hydrodynamic dispersion and viscous fingering are analyzed. A new fractionation method for determining molecular weight distribution of polymers used in EOR is proposed.

  14. Solid Target Options S. Childress

    E-Print Network [OSTI]

    McDonald, Kirk

    power is higher than for existing solid target designs - but not by a large factor. · NuMI graphite beam power) · High beam power solid targets frequently use higher z materials for increased yield plusSolid Target Options NuFACT'00 S. Childress Solid Target Options · The choice of a primary beam

  15. Micro-collimator fabricated by alpha-particle irradiation of polyallyldiglycol carbonate polymer film and subsequent chemical etching

    E-Print Network [OSTI]

    Yu, K.N.

    Micro-collimator fabricated by alpha-particle irradiation of polyallyldiglycol carbonate polymer 25 October 2009 Keywords: Solid-state nuclear track detector SSNTD Alpha particle PADC Collimator a b are discussed. & 2009 Elsevier B.V. All rights reserved. 1. Introduction Alpha-particle radiobiological

  16. Polymer Welding: Strength Through Entanglements

    E-Print Network [OSTI]

    Ting Ge; Flint Pierce; Dvora Perahia; Gary S. Grest; Mark O. Robbins

    2012-11-29T23:59:59.000Z

    Large-scale simulations of thermal welding of polymers are performed to investigate the rise of mechanical strength at the polymer-polymer interface with the welding time. The welding process is in the core of integrating polymeric elements into devices as well as in thermal induced healing of polymers; processes that require development of interfacial strength equal to that of the bulk. Our simulations show that the interfacial strength saturates at the bulk shear strength much before polymers diffuse by their radius of gyration. Along with the strength increase, the dominant failure mode changes from chain pullout at the interface to chain scission as in the bulk. Formation of sufficient entanglements across the interface, which we track using a Primitive Path Analysis is required to arrest catastrophic chain pullout at the interface. The bulk response is not fully recovered until the density of entanglements at the interface reaches the bulk value. Moreover, the increase of interfacial strength before saturation is proportional to the number of interfacial entanglements between chains from opposite sides.

  17. Development of A Self Biased High Efficiency Solid-State Neutron Detector for MPACT Applications

    SciTech Connect (OSTI)

    Danon, Yaron; Bhat, Ishwara; Jian-Qiang Lu, James

    2013-09-03T23:59:59.000Z

    Neutron detection is an important aspect of materials protection, accounting, and control for transmutation (MPACT). Currently He-3 filled thermal neutron detectors are utilized in many applications; these detectors require high-voltage bias for operation, which complicates the system when multiple detectors are used. In addition, due to recent increase in homeland security activity and the nuclear renaissance, there is a shortage of He-3, and these detectors become more expensive. Instead, cheap solid-state detectors that can be mass produced like any other computer chips will be developed. The new detector does not require a bias for operation, has low gamma sensitivity, and a fast response. The detection system is based on a honeycomb-like silicon device, which is filled with B-10 as the neutron converter; while a silicon p-n diode (i.e., solar cell type device) formed on the thin silicon wall of the honeycomb structure detects the energetic charged particles emitted from the B-10 conversion layer. Such a detector has ~40% calculated thermal neutron detection efficiency with an overall detector thickness of about 200 ?m. Stacking of these devices allows over 90% thermal neutron detection efficiency. The goal of the proposed research is to develop a high-efficiency, low-noise, self-powered solid-state neutron detector system based on the promising results of the existing research program. A prototype of this solid-state neutron detector system with sufficient detector size (up to 8-inch diam., but still portable and inexpensive) and integrated with interface electronics (e.g., preamplifier) will be designed, fabricated, and tested as a coincidence counter for MPACT applications. All fabrications proposed are based on silicon-compatible processing; thus, an extremely cheap detector system could be massively produced like any other silicon chips. Such detectors will revolutionize current neutron detection systems by providing a solid-state alternative to traditional gas-based neutron detectors.

  18. Dual design resistor for high voltage conditioning and transmission lines

    DOE Patents [OSTI]

    Siggins, Timothy Lynn (Newport News, VA); Murray, Charles W. (Hayes, VA); Walker, Richard L. (Norfolk, VA)

    2007-01-23T23:59:59.000Z

    A dual resistor for eliminating the requirement for two different value resistors. The dual resistor includes a conditioning resistor at a high resistance value and a run resistor at a low resistance value. The run resistor can travel inside the conditioning resistor. The run resistor is capable of being advanced by a drive assembly until an electrical path is completed through the run resistor thereby shorting out the conditioning resistor and allowing the lower resistance run resistor to take over as the current carrier.

  19. Optically-initiated silicon carbide high voltage switch

    DOE Patents [OSTI]

    Caporaso, George J. (Livermore, CA); Sampayan, Stephen E. (Manteca, CA); Sullivan, James S. (Livermore, CA); Sanders, David M. (Livermore, CA)

    2012-02-28T23:59:59.000Z

    An improved photoconductive switch having a SIC or other wide band gap substrate material, such as GaAs and field-grading liners composed of preferably SiN formed on the substrate adjacent the electrode perimeters or adjacent the substrate perimeters for grading the electric fields.

  20. Modal analysis of multiterminal high voltage direct current transmission

    SciTech Connect (OSTI)

    Dagle, J.E.

    1993-12-01T23:59:59.000Z

    This report describes a first phase of effort in providing the Bonneville Power Administration (BPA) with comprehensive tools for model-based analysis of interactions between the Pacific HVDC Intertie (PDCI) and the alternating current (ac) system containing it. The work builds upon the transient stability model coded by Control Technologies, Inc. (CTI) for use in the Electric Power Research Institute (EPRI) Extended Transient-Midterm Stability Package (ETMSP). The general thrust of the effort is that CM`s model be interfaced to and tested against all tools provided by EPRI`s Power System Analysis Package (PSAPAC), and that these tools be used to investigate options for PDCI use in testing and control of western system dynamics. This will require refinements to the tools, the model, and western system case data. The PSAPAC tool for eigenanalysis is the Small Signal Stability Package (SSSP), useful for performing modal analysis of the multiterminal HVDC (MTDC) system. Such analyses are necessary to design and test an expanded role of the PDCI for power system control. This study focused on testing the application of the MTDC with SSSP. Modifications were made to enable SSSP to read the MTDC model. The PSAPAC and SSSP tools and the MTDC model were evaluated for accuracy and consistency using several modal analysis techniques, including Prony analysis on ETMSP-generated data. Although SSSP appears to be useful in analyzing the PDCI modes, inconsistencies limit the overall usefulness of that approach. The modal frequencies and damping identified by SSSP are inconsistent, indicating SSSP has difficulty analyzing the MTDC representation of the dc systems. The differences between the new and existing models can be used to identify the particular modeling issues associated with SSSP which are presently resulting in inconsistent results.

  1. The Appraisal Journal, Price Effects of High Voltage Transmission...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    data was sufficient to derive precise market price equations via multiple linear regression analysis for both Portland and Seattle. In addition, due to where the rights of way...

  2. Light-weight DC to very high voltage DC converter

    DOE Patents [OSTI]

    Druce, Robert L. (Union City, CA); Kirbie, Hugh C. (Dublin, CA); Newton, Mark A. (Livermore, CA)

    1998-01-01T23:59:59.000Z

    A DC-DC converter capable of generating outputs of 100 KV without a transformer comprises a silicon opening switch (SOS) diode connected to allow a charging current from a capacitor to flow into an inductor. When a specified amount of charge has flowed through the SOS diode, it opens up abruptly; and the consequential collapsing field of the inductor causes a voltage and current reversal that is steered into a load capacitor by an output diode. A switch across the series combination of the capacitor, inductor, and SOS diode closes to periodically reset the SOS diode by inducing a forward-biased current.

  3. Light-weight DC to very high voltage DC converter

    DOE Patents [OSTI]

    Druce, R.L.; Kirbie, H.C.; Newton, M.A.

    1998-06-30T23:59:59.000Z

    A DC-DC converter capable of generating outputs of 100 KV without a transformer comprises a silicon opening switch (SOS) diode connected to allow a charging current from a capacitor to flow into an inductor. When a specified amount of charge has flowed through the SOS diode, it opens up abruptly; and the consequential collapsing field of the inductor causes a voltage and current reversal that is steered into a load capacitor by an output diode. A switch across the series combination of the capacitor, inductor, and SOS diode closes to periodically reset the SOS diode by inducing a forward-biased current. 1 fig.

  4. The BABAR LST Detector High Voltage System: Design and Implementation

    E-Print Network [OSTI]

    Honscheid, Klaus

    in the BaBar experiment to replace the ageing Resistive Plate Chambers (RPCs) as active detectors for the BABAR Instrumented Flux Return (IFR) muon system. Each streamer tube of the new detector consists of 8 were chosen to replace the rapidly ageing Resistive Plate Chambers (RPCs) in the Instrumened Flux

  5. Easily disassembled electrical connector for high voltage, high frequency connections

    DOE Patents [OSTI]

    Milner, J.R.

    1994-05-10T23:59:59.000Z

    An easily accessible electrical connector capable of rapid assembly and disassembly is described wherein a wide metal conductor sheet may be evenly contacted over the entire width of the conductor sheet by opposing surfaces on the connector which provide an even clamping pressure against opposite surfaces of the metal conductor sheet using a single threaded actuating screw. 13 figures.

  6. Experiment Hazard Class 13.0 - High Voltage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    APS Electrical Safety Committee is available for consultation. Training - ESH 114 Lockout-Tagout ESH 371 General Electrical Safety ESH 375 NFPA 70 E Following the guidance...

  7. High-voltage atmospheric breakdown across intervening rutile dielectrics.

    SciTech Connect (OSTI)

    Williamson, Kenneth Martin; Simpson, Sean; Coats, Rebecca Sue; Jorgenson, Roy Eberhardt; Hjalmarson, Harold Paul; Pasik, Michael Francis

    2013-09-01T23:59:59.000Z

    This report documents work conducted in FY13 on electrical discharge experiments performed to develop predictive computational models of the fundamental processes of surface breakdown in the vicinity of high-permittivity material interfaces. Further, experiments were conducted to determine if free carrier electrons could be excited into the conduction band thus lowering the effective breakdown voltage when UV photons (4.66 eV) from a high energy pulsed laser were incident on the rutile sample. This report documents the numerical approach, the experimental setup, and summarizes the data and simulations. Lastly, it describes the path forward and challenges that must be overcome in order to improve future experiments for characterizing the breakdown behavior for rutile.

  8. Studies on High Voltage Lithium Rich MNC Composite Cathodes

    Broader source: Energy.gov (indexed) [DOE]

    the U.S. Department of Energy Improve the current state-of-the art Li-ion cathode materials to achieve overall USABC EV energy density of 300 WhL (long-term ) at C3 and...

  9. Experimental validation of a high voltage pulse measurement method.

    SciTech Connect (OSTI)

    Cular, Stefan; Patel, Nishant Bhupendra; Branch, Darren W.

    2013-09-01T23:59:59.000Z

    This report describes X-cut lithium niobate's (LiNbO3) utilization for voltage sensing by monitoring the acoustic wave propagation changes through LiNbO3 resulting from applied voltage. Direct current (DC), alternating current (AC) and pulsed voltage signals were applied to the crystal. Voltage induced shift in acoustic wave propagation time scaled quadratically for DC and AC voltages and linearly for pulsed voltages. The measured values ranged from 10 - 273 ps and 189 ps - 2 ns for DC and non-DC voltages, respectively. Data suggests LiNbO3 has a frequency sensitive response to voltage. If voltage source error is eliminated through physical modeling from the uncertainty budget, the sensor's U95 estimated combined uncertainty could decrease to ~0.025% for DC, AC, and pulsed voltage measurements.

  10. Highline Pacific Northwests High-Voltage Transmission System

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    made substantial contributions to BPA, including the innovation of vibration dampers on transmission towers, which help reduce wind noise. It was the first color film produced by...

  11. Electrolytes and Separators for High Voltage Li Ion Cells

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  12. High voltage design structure for high temperature superconducting device

    DOE Patents [OSTI]

    Tekletsadik, Kasegn D. (Rexford, NY)

    2008-05-20T23:59:59.000Z

    In accordance with the present invention, modular corona shields are employed in a HTS device to reduce the electric field surrounding the HTS device. In a exemplary embodiment a fault current limiter module in the insulation region of a cryogenic cooling system has at least one fault current limiter set which employs a first corona shield disposed along the top portion of the fault current limiter set and is electrically coupled to the fault current limiter set. A second corona shield is disposed along the bottom portion of the fault current limiter set and is electrically coupled to the fault current limiter set. An insulation barrier is disposed within the insulation region along at least one side of the fault current limiter set. The first corona shield and the second corona shield act together to reduce the electric field surrounding the fault limiter set when voltage is applied to the fault limiter set.

  13. High Temperature, High Voltage Fully Integrated Gate Driver Circuit...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    09 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. ape03marlino...

  14. High Temperature, High Voltage Fully Integrated Gate Driver Circuit...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    10 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. ape003tolbert2010p...

  15. High voltage fault current limiter having immersed phase coils

    DOE Patents [OSTI]

    Darmann, Francis Anthony

    2014-04-22T23:59:59.000Z

    A fault current limiter including: a ferromagnetic circuit formed from a ferromagnetic material and including at least a first limb, and a second limb; a saturation mechanism surrounding a limb for magnetically saturating the ferromagnetic material; a phase coil wound around a second limb; a dielectric fluid surrounding the phase coil; a gaseous atmosphere surrounding the saturation mechanism.

  16. High Voltage Electrolytes for Li-ion Batteries

    Broader source: Energy.gov (indexed) [DOE]

    Program 3 3.5 4 4.5 5 0 0.5 1 1.5 CapacitymAh 80th 1st 50th 1.0 m LiPF 6 in ECEMC (30:70) with 1% ARL-3 on LiNi 0.5 Mn 1.5 O 4 3 3.5 4 4.5 5 0 0.5 1 1.5 CapacitymAh...

  17. High Voltage Electrolytes for Li-ion Batteries

    Broader source: Energy.gov (indexed) [DOE]

    long cycling 3 3.5 4 4.5 5 0 0.5 1 1.5 CapacitymAh 80th 1st 50th 1.0 m LiPF 6 in ECEMC (30:70) with 1% ARL-3 on LiNi 0.5 Mn 1.5 O 4 3 3.5 4 4.5 5 0 0.5 1 1.5 CapacitymAh...

  18. High Voltage Electrolytes for Li-ion Batteries

    Broader source: Energy.gov (indexed) [DOE]

    0.992 0.994 0.996 0.998 1 0 100 200 300 400 500 600 700 Baseline: 1.2 M LiPF 6 in ECEMC (30:70) Baseline + 5 mM PFBP Baseline + 10 mM AFAC Cycle Number ANL LMNOGR Full Cells...

  19. High-voltage direct current handbook: First edition

    SciTech Connect (OSTI)

    Piwko, R.J.; Leonard, D.J.; Nolan, J.J.; Thorpe, J.B. [eds.] [GE Industrial and Power Systems, Schenectady, NY (United States)

    1994-12-31T23:59:59.000Z

    HVDC systems offer opportunities for power transfer between asynchronous systems, improved performance of the ac system in which the dc link is integrated, and possibly increased power transfer across existing lines if converted to HVDC. This handbook is intended to help planners and engineers understand the intricacies of HVDC systems.

  20. High Voltage Electrolytes for Li-ion Batteries

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  1. Measurements for validation of high voltage underground cable modelling

    E-Print Network [OSTI]

    Bak, Claus Leth

    in part by the Danish TSO, Energinet.dk. U.S.G. is a PhD student at the Institute of Energy Technology.L.B. is with the Institute of Energy Technology, Aalborg University, 9220 Aalborg, Denmark (clb@iet.aau.dk). W

  2. Unravelling the Performance Degradation Mechanisms in High-voltage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengthening aTurbulence mayUndergraduateAbout Us / OurPastin situ

  3. Nanoscale Morphological and Chemical Changes of High Voltage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's Possible for Renewable Energy: GridTruckNanostructued Glass-Ceramic WasteLithium-Manganese Rich

  4. High-Voltage Insulators and Components - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh School football High School footballHigh-Pressure

  5. Highline Pacific Northwests High-Voltage Transmission System

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh School football High SchoolBundles to Living

  6. HIGH-VOLTAGE SPINEL AND POLYANION CATHODES | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGrid Integration0-1HAWAI'I CLEANDepartmentDOEHIGH-VOLTAGE

  7. High Temperature, High Voltage Fully Integrated Gate Driver Circuit |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGridHYDROGEND D e e p p a a r r t t m m e e nDepartment of

  8. High Temperature, High Voltage Fully Integrated Gate Driver Circuit |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGridHYDROGEND D e e p p a a r r t t m m e e nDepartment

  9. High Voltage Electrolyte for Lithium Batteries | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGridHYDROGEND D e e p p a a r r t t m m e

  10. High Voltage Electrolyte for Lithium Batteries | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGridHYDROGEND D e e p p a a r r t t m m e1 DOE Hydrogen and

  11. Elastic and Viscoelastic Properties of Non-bulk Polymer Interphases in Nanotube-reinforced Polymers

    E-Print Network [OSTI]

    Fisher, Frank

    Elastic and Viscoelastic Properties of Non-bulk Polymer Interphases in Nanotube-reinforced Polymers polymer composite materials with outstanding mechanical, electrical, and thermal properties. A hurdle to nanoscale interactions between the embedded NTs and adjacent polymer chains. This interphase region

  12. ENG BE/ME/MS 504: Polymers and Soft Materials GRS PY 744: Polymer Physics.

    E-Print Network [OSTI]

    Vajda, Sandor

    ENG BE/ME/MS 504: Polymers and Soft Materials GRS PY 744: Polymer Physics. Prof. Rama Bansil Class: Blackboard.bu.edu ME/MS/BE 504 PY 744 A1 POLYMERS AND SOFT MATERIALS (FALL 2012) (12FALLENGME504_A1) E with thermodynamics and statistical mechanics will be assumed. Practical applications of polymers will be discussed

  13. Some Rigorous Results on Semiflexible Polymers I. Free and confined polymers

    E-Print Network [OSTI]

    Velenik, Yvan

    Some Rigorous Results on Semiflexible Polymers I. Free and confined polymers O. Hryniva , Y 4, Switzerland Abstract We introduce a class of models of semiflexible polymers. The latter, called the persistence length, being of the same order as the polymer length. We determine

  14. Polymers: Molecular Structure [A polymer is a very large molecule comprising hundreds or thousands of atoms,

    E-Print Network [OSTI]

    Hall, Christopher

    1 Polymers: Molecular Structure [A polymer is a very large molecule comprising hundreds into chain or network structures|The concept of the polymer is one of the great ideas of twentieth century with the name of Hermann Staudinger who received the Nobel Prize in 1953. The influence of the polymer (or

  15. Confining multiple polymers between sticky walls: a directed walk model of two polymers

    E-Print Network [OSTI]

    Rechnitzer, Andrew

    Confining multiple polymers between sticky walls: a directed walk model of two polymers Thomas Wong 30, 2014 Abstract We study a model of two polymers confined to a slit with sticky walls. More on the square lattice. We compare the infinite slit limit, in which the length of the polymer (thermodynamic

  16. The challenges of organic polymer solar cells

    E-Print Network [OSTI]

    Saif Addin, Burhan K. (Burhan Khalid)

    2011-01-01T23:59:59.000Z

    The technical and commercial prospects of polymer solar cells were evaluated. Polymer solar cells are an attractive approach to fabricate and deploy roll-to-roll processed solar cells that are reasonably efficient (total ...

  17. Modeling and Optimization of Interpenetrating Polymer

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Modeling and Optimization of Interpenetrating Polymer Network Process Weijie Lin, Lorenz T. Biegler. Crosslinking Features Complex diffusion; single component reaction Complex composite networking reaction · Initiator feeding rate · Initial polymer · Monomer concentration · Initiator concentration · Holding

  18. Transports of Polymer Nanomedicine in the Environment

    E-Print Network [OSTI]

    Zhang, Ming

    2013-11-14T23:59:59.000Z

    With increasing production and commercial use of polymer nanomedicine and a lack of regulation to govern their disposal, polymer nanomedicine may enter into soils and ultimately into ground water system. In this dissertation, adsorption of polymeric...

  19. Highly cross-linked nanoporous polymers

    DOE Patents [OSTI]

    Steckle, Jr., Warren P. (Los Alamos, NM); Apen, Paul G. (Los Alamos, NM); Mitchell, Michael A. (Los Alamos, NM)

    1998-01-01T23:59:59.000Z

    Condensation polymerization followed by a supercritical extraction step can be used to obtain highly cross-linked nanoporous polymers with high surface area, controlled pore sizes and rigid structural integrity. The invention polymers are useful for applications requiring separation membranes.

  20. Dynamics of Polymers in Flowing Colloidal Suspensions

    E-Print Network [OSTI]

    Chen, Hsieh

    Using hydrodynamic simulations we examine the behavior of single polymers in a confined colloidal suspension under flow. We study the conformations of both, collapsed and noncollapsed polymers. Our results show that the ...

  1. Highly cross-linked nanoporous polymers

    DOE Patents [OSTI]

    Steckle, Jr., Warren P. (Los Alamos, NM); Apen, Paul G. (Los Alamos, NM); Mitchell, Michael A. (Los Alamos, NM)

    1997-01-01T23:59:59.000Z

    Condensation polymerization followed by a supercritical extraction step can be used to obtain highly cross-linked nanoporous polymers with high surface area, controlled pore sizes and rigid structural integrity. The invention polymers are useful for applications requiring separation membranes.

  2. Modelling Viscoelastic Behaviour of Polymer by A Mixed Velocity, Displacement Formulation - Numerical and Experimental Results

    SciTech Connect (OSTI)

    Pham, VT.; Silva, L.; Digonnet, H.; Combeaud, C.; Billon, N.; Coupez, T. [Centre for Material Forming (CEMEF), MINES ParisTech, Rue Claude Daunesse, Sophia Antipolis cedex (France)

    2011-05-04T23:59:59.000Z

    The objective of this work is to model the viscoelastic behaviour of polymer from the solid state to the liquid state. With this objective, we perform experimental tensile tests and compare with simulation results. The chosen polymer is a PMMA whose behaviour depends on its temperature. The computation simulation is based on Navier-Stokes equations where we propose a mixed finite element method with an interpolation P1+/P1 using displacement (or velocity) and pressure as principal variables. The implemented technique uses a mesh composed of triangles (2D) or tetrahedra (3D). The goal of this approach is to model the viscoelastic behaviour of polymers through a fluid-structure coupling technique with a multiphase approach.

  3. Solid state switch

    DOE Patents [OSTI]

    Merritt, B.T.; Dreifuerst, G.R.

    1994-07-19T23:59:59.000Z

    A solid state switch, with reverse conducting thyristors, is designed to operate at 20 kV hold-off voltage, 1,500 A peak, 1.0 [mu]s pulsewidth, and 4,500 pps, to replace thyratrons. The solid state switch is more reliable, more economical, and more easily repaired. The switch includes a stack of circuit card assemblies, a magnetic assist and a trigger chassis. Each circuit card assembly contains a reverse conducting thyristor, a resistor capacitor network, and triggering circuitry. 6 figs.

  4. Polymers as advanced materials for desiccant applications

    SciTech Connect (OSTI)

    Czanderna, A.W.

    1990-12-01T23:59:59.000Z

    This research is concerned with solid materials used as desiccants for desiccant cooling systems (DCSs) that process water vapor in an atmosphere to produce cooling. Background information includes an introduction to DCSs and the role of the desiccant as a system component. The water vapor sorption performance criteria used for screening the modified polymers prepared include the water sorption capacity from 5% to 80% relative humidity (R.H.), isotherm shape, and rate of adsorption and desorption. Measurements are presented for the sorption performance of modified polymeric advanced desiccant materials with the quartz crystal microbalance. Isotherms of polystyrene sulfonic acid (PSSA) taken over a 5-month period show that the material has a dramatic loss in capacity and that the isotherm shape is time dependent. The adsorption and desorption kinetics for PSSA and all the ionic salts of it studied are easily fast enough for commercial DCS applications with a wheel rotation speed of 6 min per revolution. Future activities for the project are addressed, and a 5-year summary of the project is included as Appendix A. 34 refs., 20 figs., 3 tabs.

  5. Laser Processing of Metals and Polymers

    SciTech Connect (OSTI)

    Senthilraja Singaravelu

    2012-05-31T23:59:59.000Z

    A laser offers a unique set of opportunities for precise delivery of high quality coherent energy. This energy can be tailored to alter the properties of material allowing a very flexible adjustment of the interaction that can lead to melting, vaporization, or just surface modification. Nowadays laser systems can be found in nearly all branches of research and industry for numerous applications. Sufficient evidence exists in the literature to suggest that further advancements in the field of laser material processing will rely significantly on the development of new process schemes. As a result they can be applied in various applications starting from fundamental research on systems, materials and processes performed on a scientific and technical basis for the industrial needs. The interaction of intense laser radiation with solid surfaces has extensively been studied for many years, in part, for development of possible applications. In this thesis, I present several applications of laser processing of metals and polymers including polishing niobium surface, producing a superconducting phase niobium nitride and depositing thin films of niobium nitride and organic material (cyclic olefin copolymer). The treated materials were examined by scanning electron microscopy (SEM), electron probe microanalysis (EPMA), atomic force microscopy (AFM), high resolution optical microscopy, surface profilometry, Fourier transform infrared spectroscopy (FTIR) and x-ray diffraction (XRD). Power spectral density (PSD) spectra computed from AFM data gives further insight into the effect of laser melting on the topography of the treated niobium.

  6. Post polymerization cure shape memory polymers

    SciTech Connect (OSTI)

    Wilson, Thomas S; Hearon, Michael Keith; Bearinger, Jane P

    2014-11-11T23:59:59.000Z

    This invention relates to chemical polymer compositions, methods of synthesis, and fabrication methods for devices regarding polymers capable of displaying shape memory behavior (SMPs) and which can first be polymerized to a linear or branched polymeric structure, having thermoplastic properties, subsequently processed into a device through processes typical of polymer melts, solutions, and dispersions and then crossed linked to a shape memory thermoset polymer retaining the processed shape.

  7. Adsorption of polymers at nanowires

    E-Print Network [OSTI]

    Thomas Vogel; Michael Bachmann

    2011-03-09T23:59:59.000Z

    Low-energy structures of a hybrid system consisting of a polymer and an attractive nanowire substrate as well as the thermodynamics of the adsorption transition are studied by means of Monte Carlo computer simulations. Depending on structural and energetic properties of the substrate, we find different adsorbed polymer conformations, amongst which are spherical droplets attached to the wire and monolayer tubes surrounding it. We identify adsorption temperatures and the type of the transition between adsorbed and desorbed structures depending on the substrate attraction strength.

  8. Modeling and Optimization for Interpenetrating polymer

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Modeling and Optimization for Interpenetrating polymer network process 1 Weijie Lin, Lorenz T #12;Project Overview · IPN Interpenetrating polymer network ­ A combination of two polymers in a network form Fig. 2 An IPN process example · Typical Sequential Type of Process Fig. 1 IPN network

  9. Novel polyoxazolines polymer drug delivery platform

    E-Print Network [OSTI]

    performed with 4 different polymers in multi- drug resistant (MCF7/ADR) human adenocarcinoma cells, non-resistant (MCF7) human adenocarcinoma cells and Madin-Darby canine kidney (MDCK) cells. All polymers were found lines. 2. To investigate the effect of the addition of drugs to the polymers on cell toxicity, micelles

  10. Organosiloxane-grafted natural polymer coatings

    DOE Patents [OSTI]

    Sugama, Toshifumi (Wading River, NY)

    1998-01-01T23:59:59.000Z

    A new family of polysaccharide graft polymers are provided as corrosion resistant coatings having antimicrobial properties which are useful on light metals such as aluminum, magnesium, zinc, steel and their alloys. Methods of making the polysaccharide graft polymers are also included. The methods of making the polysaccharide graft polymers involve reacting a polysaccharide source with an antimicrobial agent under conditions of hydrolysis-condensation.

  11. Polymer microcantilevers fabricated via multiphoton absorption polymerization

    E-Print Network [OSTI]

    Teich, Malvin C.

    Polymer microcantilevers fabricated via multiphoton absorption polymerization Z. Bayindir, Y. Sun polymer cantilevers. Atomic force microscopy has been used to characterize the mechanical properties orders of magnitude smaller than would be predicted from the properties of the bulk polymer.6 If correct

  12. Nordic Polymer Days 2006 Copenhagen, Denmark

    E-Print Network [OSTI]

    Abstract Nordic Polymer Days 2006 Copenhagen, Denmark Polyacrylamide nanosensor embedded Scharff-Poulsen, c Hong Gu, d Wolf B. Fromme, b Iver Jakobsen, a Kristoffer Almdal a The Danish Polymer-linked polymer in nanometer scale, have several advantages over direct loading of cells with fluorescent probes

  13. Polymers in a Vacuum J. M. Deutsch

    E-Print Network [OSTI]

    Deutsch, Josh

    Polymers in a Vacuum J. M. Deutsch Department of Physics, University of California, Santa Cruz polymer molecules are found in a vacuum, and here we examine their properties. Angular momentum The properties of polymer chains have been investigated extensively over the past 50 years [1], but the vast

  14. North Dakota State University Postoc Biobased Polymers

    E-Print Network [OSTI]

    Alpay, S. Pamir

    North Dakota State University Postoc ­ Biobased Polymers A postdoctoral position is available in the area of synthesis and characterization of novel biobased thermosetting polymer systems for coatings will include the synthesis of monomers and polymers, preparation of coatings, thermosets, etc., preparation

  15. Selfattractive random polymers Remco van der Hofstad

    E-Print Network [OSTI]

    Klenke, Achim

    Self­attractive random polymers Remco van der Hofstad Stieltjes Institute of Mathematics Delft polymer of finite length in Zd . Its law is that of a finite simple random walk path in Zd receiving that for > the attraction dominates the repulsion, i.e., with high probability the polymer is contained in a finite box

  16. Luminescent organosilicon polymers and sol-gel synthesis of nano-structured silica

    E-Print Network [OSTI]

    Martinez, H. Paul

    2011-01-01T23:59:59.000Z

    Photoluminescent   Polymers   Containing   Metalloles.  Metallole-­? Containing  Polymers.   Journal  of  Forensic  S.   J. ;   Trogler,   W.   C. ,   Polymer   sensors   for  

  17. Stretching of polymers in a turbulent environment

    E-Print Network [OSTI]

    Bruno Eckhardt; Jochen Kronjaeger; Joerg Schumacher

    2002-01-20T23:59:59.000Z

    The interaction of polymers with small-scale velocity gradients can trigger a coil-stretch transition in the polymers. We analyze this transition within a direct numerical simulation of shear turbulence with an Oldroyd-B model for the polymer. In the coiled state the lengths of polymers are distributed algebraically with an exponent alpha=2 gamma-1/De, where gamma is a characteristic stretching rate of the flow and De the Deborah number. In the stretched state we demonstrate that the length distribution of the polymers is limited by the feedback to the flow.

  18. Friction between Ring Polymer Brushes

    E-Print Network [OSTI]

    A. Erbas; J. Paturej

    2015-01-07T23:59:59.000Z

    Friction between ring-polymer brushes at melt densities sliding past each other are studied using extensive course-grained molecular dynamics simulations and scaling arguments, and the results are compared to the friction between linear-polymer brushes. We show that for a velocity range spanning over three decades, the frictional forces measured for ring-polymer brushes are half the corresponding friction in case of linear brushes. In the linear-force regime, the weak inter-digitation of two ring brushes compared to linear brushes also leads to a lower number of binary collisions between the monomers of opposing brushes. At high velocities, where the thickness of the inter-digitation layer between two opposing brushes is on the order monomer size regardless of brush topology, stretched segments of ring polymers take a double-stranded conformation. As a result, monomers of the double-stranded segments collide less with the monomers of the opposing ring brush even though a similar number of monomers occupies the inter-digitation layer for ring and linear-brush bilayers. The numerical data obtained from our simulations is consistent with the proposed scaling analysis. Conformation-dependent frictional reduction observed in ring brushes can have important consequences in non-equilibrium bulk systems.

  19. Enhanced photophysics of conjugated polymers

    DOE Patents [OSTI]

    Chen, Liaohai (Darien, IL)

    2007-06-12T23:59:59.000Z

    A particulate fluorescent conjugated polymer surfactant complex and method of making and using same. The particles are between about 15 and about 50 nm and when formed from a lipsome surfactant have a charge density similar to DNA and are strongly absorbed by cancer cells.

  20. Polymer representations and geometric quantization

    E-Print Network [OSTI]

    Miguel Campiglia

    2011-11-02T23:59:59.000Z

    Polymer representations of the Weyl algebra of linear systems provide the simplest analogues of the representation used in loop quantum gravity. The construction of these representations is algebraic, based on the Gelfand-Naimark-Segal construction. Is it possible to understand these representations from a Geometric Quantization point of view? We address this question for the case of a two dimensional phase space.

  1. Water-soluble conductive polymers

    DOE Patents [OSTI]

    Aldissi, M.

    1988-02-12T23:59:59.000Z

    Polymers which are soluble in water and are electrically conductive. The monomer repeat unit is a thiophene or pyrrole molecule having an alkyl group substituted for the hydrogen atom located in the beta position of the thiophene or pyrrole ring and having a surfactant molecule at the end of the alkyl chain. Polymers of this class having 8 or more carbon atoms in the alkyl chain exhibit liquid crystalline behavior, resulting in high electrical anisotropy. The monomer-to-monomer bonds are located between the carbon atoms which are adjacent to the sulfur or nitrogen atoms. The number of carbon atoms in the alkyl group may vary from 1 to 20 carbon atoms. The surfactant molecule consists of a sulfonate group, or a sulfate group, or a carboxylate group, and hydrogen or an alkali metal. Negative ions from a supporting electrolyte which may be used in the electrochemical synthesis of a polymer may be incorporated into the polymer during the synthesis and serve as a dopant to increase the conductivity.

  2. Water-soluble conductive polymers

    DOE Patents [OSTI]

    Aldissi, Mahmoud (Sante Fe, NM)

    1989-01-01T23:59:59.000Z

    Polymers which are soluble in water and are electrically conductive. The monomer repeat unit is a thiophene or pyrrole molecule having an alkyl group substituted for the hydrogen atom located in the beta position of the thiophene or pyrrole ring and having a surfactant molecule at the end of the alkyl chain. Polymers of this class having 8 or more carbon atoms in the alkyl chain exhibit liquid crystalline behavior, resulting in high electrical anisotropy. The monomer-to-monomer bonds are located between the carbon atoms which are adjacent to the sulfur or nitrogen atoms. The number of carbon atoms in the alkyl group may vary from 1 to 20 carbon atoms. The surfactant molecule consists of a sulfonate group, or a sulfate group, or a carboxylate group, and hydrogen or an alkali metal. Negative ions from a supporting electrolyte which may be used in the electrochemical synthesis of a polymer may be incorporated into the polymer during the synthesis and serve as a dopant to increase the conductivity.

  3. Water-soluble conductive polymers

    DOE Patents [OSTI]

    Aldissi, Mahmoud (Sante Fe, NM)

    1990-01-01T23:59:59.000Z

    Polymers which are soluble in water and are electrically conductive. The monomer repeat unit is a thiophene or pyrrole molecule having an alkyl group substituted for the hydrogen atom located in the beta position of the thiophene or pyrrole ring and having a surfactant molecule at the end of the alkyl chain. Polymers of this class having 8 or more carbon atoms in the alkyl chain exhibit liquid crystalline behavior, resulting in high electrical anisotropy. The monomer-to-monomer bonds are located between the carbon atoms which are adjacent to the sulfur or nitrogen atoms. The number of carbon atoms in the alkyl group may vary from 1 to 20 carbon atoms. The surfactant molecule consists of a sulfonate group, or a sulfate group, or a carboxylate group, and hydrogen or an alkali metal. Negative ions from a supporting electrolyte which may be used in the electrochemical synthesis of a polymer may be incorporated into the polymer during the synthesis and serve as a dopant to increase the conductivity.

  4. EFFECTS OF TRITIUM GAS EXPOSURE ON ELECTRICALLY CONDUCTING POLYMERS

    SciTech Connect (OSTI)

    Kane, M.; Clark, E.; Lascola, R.

    2009-12-16T23:59:59.000Z

    Effects of beta (tritium) and gamma irradiation on the surface electrical conductivity of two types of conducting polymer films are documented to determine their potential use as a sensing and surveillance device for the tritium facility. It was shown that surface conductivity was significantly reduced by irradiation with both gamma and tritium gas. In order to compare the results from the two radiation sources, an approximate dose equivalence was calculated. The materials were also sensitive to small radiation doses (<10{sup 5} rad), showing that there is a measurable response to relatively small total doses of tritium gas. Spectroscopy was also used to confirm the mechanism by which this sensing device would operate in order to calibrate this sensor for potential use. It was determined that one material (polyaniline) was very sensitive to oxidation while the other material (PEDOT-PSS) was not. However, polyaniline provided the best response as a sensing material, and it is suggested that an oxygen-impermeable, radiation-transparent coating be applied to this material for future device prototype fabrication. A great deal of interest has developed in recent years in the area of conducting polymers due to the high levels of conductivity that can be achieved, some comparable to that of metals [Gerard 2002]. Additionally, the desirable physical and chemical properties of a polymer are retained and can be exploited for various applications, including light emitting diodes (LED), anti-static packaging, electronic coatings, and sensors. The electron transfer mechanism is generally accepted as one of electron 'hopping' through delocalized electrons in the conjugated backbone, although other mechanisms have been proposed based on the type of polymer and dopant [Inzelt 2000, Gerard 2002]. The conducting polymer polyaniline (PANi) is of particular interest because there are extensive studies on the modulation of the conductivity by changing either the oxidation state of the main backbone chain, or by protonation of the imine groups [de Acevedo, 1999]. There are several types of radiation sensors commercially available, including ionization chambers, geiger counters, proportional counters, scintillators and solid state detectors. Each type has advantages, although many of these sensors require expensive electronics for signal amplification, are large and bulky, have limited battery life or require expensive materials for fabrication. A radiation sensor constructed of a polymeric material could be flexible, light, and the geometry designed to suit the application. Very simple and inexpensive electronics would be necessary to measure the change in conductivity with exposure to radiation and provide an alarm system when a set change of conductivity occurs in the sensor that corresponds to a predetermined radiation dose having been absorbed by the polymer. The advantages of using a polymeric sensor of this type rather than those currently in use are the flexibility of sensor geometry and relatively low cost. It is anticipated that these sensors can be made small enough for glovebox applications or have the ability to monitor the air tritium levels in places where a traditional monitor cannot be placed. There have been a few studies on the changes in conductivity of polyaniline specifically for radiation detection [de Acevedo, 1999; Lima Pacheco, 2003], but there have been no reports on the effects of tritium (beta radiation) on conducting polymers, such as polyaniline or polythiophene. The direct implementation of conducting polymers as radiation sensor materials has not yet been commercialized due to differing responses with total dose, dose rate, etc. Some have reported a large increase in the surface conductivity with radiation dose while others report a marked decrease in conductive properties; these differing observations may reflect the competing mechanisms of chain scission and cross-linking. However, it is clear that the radiation dose effects on conducting polymers must be fully understood before these materials can be used

  5. Solid Waste Act (New Mexico)

    Broader source: Energy.gov [DOE]

    The main purpose of the Solid Waste Act is to authorize and direct the establishment of a comprehensive solid waste management program. The act states details about specific waste management...

  6. Solid Waste Management Program (Missouri)

    Broader source: Energy.gov [DOE]

    The Solid Waste Management Program in the Department of Natural Resources regulates the management of solid waste in the state of Missouri. A permit is required prior to the construction or...

  7. Delaware Solid Waste Authority (Delaware)

    Broader source: Energy.gov [DOE]

    The Delaware Solid Waste Authority (DSWA) runs three landfills, all of which recover methane and generate electricity with a total capacity of 24 MWs. The DSWA Solid Waste Plan includes goals,...

  8. Solid Waste Disposal Act (Texas)

    Broader source: Energy.gov [DOE]

    The Texas Commission on Environmental Quality is responsible for the regulation and management of municipal solid waste and hazardous waste. A fee is applied to all solid waste disposed in the...

  9. TRANSPORT NUMBER GRADIENTS AND SOLID ELECTROLYTE DEGRADATION

    E-Print Network [OSTI]

    De Jonghe, Lutgard C.

    2012-01-01T23:59:59.000Z

    AND SOLID ELECTROLYTE DEGRADATION Lutgard C. De Jonghe TWO-AND SOLID ELECTROLYTE DEGRADATION Lutgard C. De JongheAND SOLID ELECTROLYTE DEGRADATION Lutgard C. De Jonghe

  10. Active Polymers Confer Fast Reorganization Kinetics

    E-Print Network [OSTI]

    Douglas Swanson; Ned S. Wingreen

    2011-10-02T23:59:59.000Z

    Many cytoskeletal biopolymers are "active," consuming energy in large quantities. In this Letter, we identify a fundamental difference between active polymers and passive, equilibrium polymers: for equal mean lengths, active polymers can reorganize faster than equilibrium polymers. We show that equilibrium polymers are intrinsically limited to linear scaling between mean lifetime and mean length, MFPT ~ , by analogy to 1-d Potts models. By contrast, we present a simple active-polymer model that improves upon this scaling, such that MFPT ~ ^{1/2}. Since to be biologically useful, structural biopolymers must typically be many monomers long, yet respond dynamically to the needs of the cell, the difference in reorganization kinetics may help to justify active polymers' greater energy cost. PACS numbers: 87.10.Ed, 87.16.ad, 87.16.Ln

  11. Solid state electrochemical current source

    DOE Patents [OSTI]

    Potanin, Alexander Arkadyevich (Sarov, RU); Vedeneev, Nikolai Ivanovich (Sarov, RU)

    2002-04-30T23:59:59.000Z

    A cathode and a solid state electrochemical cell comprising said cathode, a solid anode and solid fluoride ion conducting electrolyte. The cathode comprises a metal oxide and a compound fluoride containing at least two metals with different valences. Representative compound fluorides include solid solutions of bismuth fluoride and potassium fluoride; and lead fluoride and potassium fluoride. Representative metal oxides include copper oxide, lead oxide, manganese oxide, vanadium oxide and silver oxide.

  12. Heat Recovery From Solid Waste

    E-Print Network [OSTI]

    Underwood, O. W.

    1981-01-01T23:59:59.000Z

    areas of evaluation, including the cost of fuel, cost of solid waste disposal, plant energy requirements, available technology, etc....

  13. Crowding of Polymer Coils and Demixing in Nanoparticle-Polymer Mixtures

    E-Print Network [OSTI]

    Ben Lu; Alan R. Denton

    2011-06-24T23:59:59.000Z

    The Asakura-Oosawa-Vrij (AOV) model of colloid-polymer mixtures idealizes nonadsorbing polymers as effective spheres that are fixed in size and impenetrable to hard particles. Real polymer coils, however, are intrinsically polydisperse in size (radius of gyration) and may be penetrated by smaller particles. Crowding by nanoparticles can affect the size distribution of polymer coils, thereby modifying effective depletion interactions and thermodynamic stability. To analyse the influence of crowding on polymer conformations and demixing phase behaviour, we adapt the AOV model to mixtures of nanoparticles and ideal, penetrable polymer coils that can vary in size. We perform Gibbs ensemble Monte Carlo simulations, including trial nanoparticle-polymer overlaps and variations in radius of gyration. Results are compared with predictions of free-volume theory. Simulation and theory consistently predict that ideal polymers are compressed by nanoparticles and that compressibility and penetrability stabilise nanoparticle-polymer mixtures.

  14. Polymer compositions, polymer films and methods and precursors for forming same

    DOE Patents [OSTI]

    Klaehn, John R; Peterson, Eric S; Orme, Christopher J

    2013-09-24T23:59:59.000Z

    Stable, high performance polymer compositions including polybenzimidazole (PBI) and a melamine-formaldehyde polymer, such as methylated, poly(melamine-co-formaldehyde), for forming structures such as films, fibers and bulky structures. The polymer compositions may be formed by combining polybenzimidazole with the melamine-formaldehyde polymer to form a precursor. The polybenzimidazole may be reacted and/or intertwined with the melamine-formaldehyde polymer to form the polymer composition. For example, a stable, free-standing film having a thickness of, for example, between about 5 .mu.m and about 30 .mu.m may be formed from the polymer composition. Such films may be used as gas separation membranes and may be submerged into water for extended periods without crazing and cracking. The polymer composition may also be used as a coating on substrates, such as metal and ceramics, or may be used for spinning fibers. Precursors for forming such polymer compositions are also disclosed.

  15. Z .Thin Solid Films 315 1998 912 Patterning of a polysiloxane precursor to silicate glasses by microcontact

    E-Print Network [OSTI]

    Tien, Joe

    Z .Thin Solid Films 315 1998 9­12 Letter Patterning of a polysiloxane precursor to silicate glasses. Introduction This paper describes a new method to generate mm-scale patterns of silicate glass on flat and non to silica. After removing the unreacted polymer and curing, a silicate glass pattern is produced. Z

  16. High contrast solid state electrochromic devices based on Ruthenium Purple nanocomposites fabricated by layer-by-layer assemblyw

    E-Print Network [OSTI]

    Heflin, Randy

    High contrast solid state electrochromic devices based on Ruthenium Purple nanocomposites: 10.1039/b803915a Electrochromic Ruthenium Purple­polymer nanocomposite films, fabricated by multilayer assembly, were found to exhibit sub-second switching speed and the highest electrochromic con

  17. Epoxidised Natural Rubber Based Composite Polymer Electrolyte Systems For Use In Electrochemical Device Applications

    SciTech Connect (OSTI)

    Idris, Razali; Tasnim, Anis; Mahbor, Kamisah Mohamad [Advanced Materials Research Centre, Lot 34 Kulim Hi-Tech Park, 09000 Kulim, Kedah (Malaysia); Hakim, Mas Rosemal [School of Chemical Sciences, University Sciences of Malaysia, 11800 USM, Minden, P. Pinang (Malaysia); Mohd, Dahlan Hj.; Ghazali, Zulkafli [Radiation Processing Technology Division, Malaysian Nuclear Agency, Dengkil, 43000 Kajang, Selangor (Malaysia)

    2009-09-14T23:59:59.000Z

    Composite polymer electrolyte (CPE) comprising epoxy-fimctionalized rubber (ENR), HDDA monomer, mixed plasticizer-propylene carbonate/ethylene carbonate, silica filler and lithium bis(trifluoromethanesulfonylimide), Li[(CF{sub 3}SO{sub 2}){sub 2}N]have been prepared using photo-induced polymerization by UV irradiation technique. The irradiated samples of filled and non-filled silica of composites electrolytes have formed dry solid-flexible and transparent films in the self-constructed Teflon mould. Thermal behaviors, FTIR, morphology and ionic conductivity were performed on such ENR based PE polymer composites having varied compositions. The thermal stability has improved slightly in the temperature range 120-200 deg. C with optimized composition. FTIR measurements data revealed that the interaction of lithium with the epoxy groups of the un-bonded electrons within polymer occurred. The results suggest that the variation of conductivity with temperature indicates that the silica filled composite has achieved optimal ionic conductivity 10{sup -4} S cm{sup -1} and retained high percent of plasticizer. The ionic conductivity behavior of the silica-filled ENR based composite polymer electrolyte is consistent at elevated temperature compared to non-filled CPE system. This finding opens a new pathway for further investigation to diffusion of ions in the complex polymer electrolyte systems.

  18. Combinatorial synthesis and screening of non-biological polymers

    DOE Patents [OSTI]

    Schultz, Peter G.; Xiang, Xiao-Dong; Goldwasser, Isy; Briceno, Gabriel; Sun, Xiao-Dong; Wang, Kai-An

    2006-04-25T23:59:59.000Z

    Methods and apparatus for the preparation and use of a substrate having an array of diverse materials in predefined regions thereon. A substrate having an array of diverse materials thereon is generally prepared by delivering components of materials to predefined regions on a substrate, and simultaneously reacting the components to form at least two materials. Materials which can be prepared using the methods and apparatus of the present invention include, for example, covalent network solids, ionic solids and molecular solids. More particularly, materials which can be prepared using the methods and apparatus of the present invention include, for example, inorganic materials, intermetallic materials, metal alloys, ceramic materials, organic materials, organometallic materials, non-biological organic polymers, composite materials (e.g., inorganic composites, organic composites, or combinations thereof), etc. Once prepared, these materials can be screened for useful properties including, for example, electrical, thermal, mechanical, morphological, optical, magnetic, chemical, or other properties. Thus, the present invention provides methods for the parallel synthesis and analysis of novel materials having useful properties.

  19. Polymer arrays from the combinatorial synthesis of novel materials

    DOE Patents [OSTI]

    Schultz, Peter G.; Xiang, Xiao-Dong; Goldwasser, Isy; Briceno, Gabriel; Sun, Xiao-Dong

    2004-09-21T23:59:59.000Z

    Methods and apparatus for the preparation and use of a substrate having an array of diverse materials in predefined regions thereon. A substrate having an array of diverse materials thereon is generally prepared by delivering components of materials to predefined regions on a substrate, and simultaneously reacting the components to form at least two materials. Materials which can be prepared using the methods and apparatus of the present invention include, for example, covalent network solids, ionic solids and molecular solids. More particularly, materials which can be prepared using the methods and apparatus of the present invention include, for example, inorganic materials, intermetallic materials, metal alloys, ceramic materials, organic materials, organometallic materials, non-biological organic polymers, composite materials (e.g., inorganic composites, organic composites, or combinations thereof), etc. Once prepared, these materials can be screened for useful properties including, for example, electrical, thermal, mechanical, morphological, optical, magnetic, chemical, or other properties. Thus, the present invention provides methods for the parallel synthesis and analysis of novel materials having useful properties.

  20. A blurred interface formulation of The Reference Map Technique for Fluid-Solid Interactions and Fluid-Solid-Solid Interactions

    E-Print Network [OSTI]

    Valkov, Boris Ivanov

    2014-01-01T23:59:59.000Z

    In this work we present a blurred interface method for Fluid-Solid Interactions (FSI) and multiple solids immersed in a fluid or FSSI (Fluid-Solid-Solid Interactions) based on the reference map technique as presented by ...