Sample records for high-temperature syngas cleanup

  1. EA-1867: Scale-up of High-Temperature Syngas Cleanup Technology, Polk County, Florida

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of a proposal to provide cost-shared funding to RTI International (RTI) for its proposed project to demonstrate the precommercial scale-up of RTI’s high-temperature syngas cleanup and carbon capture and sequestration technologies.

  2. DOE-Sponsored Syngas Cleanup Demonstration Project Reaches Development...

    Energy Savers [EERE]

    DOE-Sponsored Syngas Cleanup Demonstration Project Reaches Development Milestone DOE-Sponsored Syngas Cleanup Demonstration Project Reaches Development Milestone February 19, 2015...

  3. Progress toward Biomass and Coal-Derived Syngas Warm Cleanup...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Progress toward Biomass and Coal-Derived Syngas Warm Cleanup: Proof-of-Concept Process Demonstration of Multicontaminant Removal Progress toward Biomass and Coal-Derived Syngas...

  4. High temperature electrolysis for syngas production

    DOE Patents [OSTI]

    Stoots, Carl M. (Idaho Falls, ID); O'Brien, James E. (Idaho Falls, ID); Herring, James Stephen (Idaho Falls, ID); Lessing, Paul A. (Idaho Falls, ID); Hawkes, Grant L. (Sugar City, ID); Hartvigsen, Joseph J. (Kaysville, UT)

    2011-05-31T23:59:59.000Z

    Syngas components hydrogen and carbon monoxide may be formed by the decomposition of carbon dioxide and water or steam by a solid-oxide electrolysis cell to form carbon monoxide and hydrogen, a portion of which may be reacted with carbon dioxide to form carbon monoxide. One or more of the components for the process, such as steam, energy, or electricity, may be provided using a nuclear power source.

  5. THE PRODUCTION OF SYNGAS VIA HIGH TEMPERATURE ELECTROLYSIS AND BIO-MASS GASIFICATION

    SciTech Connect (OSTI)

    M. G. McKellar; G. L. Hawkes; J. E. O'Brien

    2008-11-01T23:59:59.000Z

    A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to improve the hydrogen production efficiency of the steam electrolysis process. Hydrogen from electrolysis allows a high utilization of the biomass carbon for syngas production. Based on the gasifier temperature, 94% to 95% of the carbon in the biomass becomes carbon monoxide in the syngas (carbon dioxide and hydrogen). Assuming the thermal efficiency of the power cycle for electricity generation is 50%, (as expected from GEN IV nuclear reactors), the syngas production efficiency ranges from 70% to 73% as the gasifier temperature decreases from 1900 K to 1500 K.

  6. Direct Utilization of Coal Syngas in High Temperature Fuel Cells

    SciTech Connect (OSTI)

    Celik, Ismail B.

    2014-10-30T23:59:59.000Z

    This EPSCoR project had two primary goals: (i) to build infrastructure and work force at WVU to support long-term research in the area of fuel cells and related sciences; (ii) study effects of various impurities found in coal-syngas on performance of Solid Oxide Fuel Cells (SOFC). As detailed in this report the WVU research team has made significant accomplishments in both of these areas. What follows is a brief summary of these accomplishments: State-of-the-art test facilities and diagnostic tools have been built and put into use. These include cell manufacturing, half-cell and full-cell test benches, XPS, XRD, TEM, Raman, EDAX, SEM, EIS, and ESEM equipment, unique in-situ measurement techniques and test benches (Environmental EM, Transient Mass-Spectrometer-MS, and IR Optical Temperature measurements). In addition, computational capabilities have been developed culminating in a multi-scale multi-physics fuel cell simulation code, DREAM-SOFC, as well as a Beowulf cluster with 64 CPU units. We have trained 16 graduate students, 10 postdoctoral fellows, and recruited 4 new young faculty members who have actively participated in the EPSCoR project. All four of these faculty members have already been promoted to the tenured associate professor level. With the help of these faculty and students, we were able to secure 14 research awards/contracts amounting to a total of circa $5.0 Million external funding in closely related areas of research. Using the facilities mentioned above, the effects of PH3, HCl, Cl2, and H2S on cell performance have been studied in detail, mechanisms have been identified, and also remedies have been proposed and demonstrated in the laboratory. For example, it has been determined that PH3 reacts rapidly with Ni to from secondary compounds which may become softer or even melt at high temperature and then induce Ni migration to the surface of the cell changing the material and micro-structural properties of the cell drastically. It is found that the extent of steam and current load accelerate the degradation caused by PH3. A unique filtering technique has been proposed to reduce the effect of PH3. In addition, various cell materials have been proposed to reduce the rate of degradation caused by H2S. Furthermore, a three-dimensional, transient multi-physics model has been formulated to describe primary transport processes and electro-chemical reactions occurring within the cell. This model has been validated using data gathered from accelerated tests. The validated model then has been used to study the degradation rates under a range of operating conditions and impurity levels. This has resulted in a procedure that uses both experiments and simulations to predict the life-time of a cell operating with syngas with known concentration of trace impurities. Finally all the experience and knowledge gained has been disseminated via 39 journal papers and 43 presentations/posters/conference papers.

  7. Catalytic Tar Reforming for Cleanup and Conditioning of Biomass-derived Syngas

    SciTech Connect (OSTI)

    Dayton, D. C.; Bain, R. L.; Phillips, S. D.; Magrini-Bair, K.; Feik, C. J.

    2006-01-01T23:59:59.000Z

    Biomass gasification is being investigated to produce clean syngas from biomass or biorefinery residues as an intermediate that can be used directly as a fuel for integrated heat and power production or further refined and upgraded by various processing technologies. Conditioning of biomass-derived syngas, with an emphasis on tar reforming, to make it a suitable feed for high temperature, pressurized liquid fuels synthesis is the goal of current research efforts.

  8. PROCESS MODEL FOR THE PRODUCTION OF SYNGAS VIA HIGH TEMPERATURE CO-ELECTROLYSIS

    SciTech Connect (OSTI)

    M. G. McKellar; J. E. O'Brien; C. M. Stoots; G. L. Hawkes

    2007-11-01T23:59:59.000Z

    A process model has been developed to evaluate the potential performance of a large-scale high-temperature coelectrolysis plant for the production of syngas from steam and carbon dioxide. The coelectrolysis process allows for direct electrochemical reduction of the steam – carbon dioxide gas mixture, yielding hydrogen and carbon monoxide, or syngas. The process model has been developed using the HYSYS systems analysis code. Using this code, a detailed process flowsheet has been defined that includes all the components that would be present in an actual plant such as pumps, compressors, heat exchangers, turbines, and the electrolyzer. Since the electrolyzer is not a standard HYSYS component, a custom one-dimensional coelectrolysis model was developed for incorporation into the overall HYSYS process flowsheet. The 1-D coelectrolysis model assumes local chemical equilibrium among the four process-gas species via the shift reaction. The electrolyzer model allows for the determination of coelectrolysis outlet temperature, composition (anode and cathode sides), mean Nernst potential, operating voltage and electrolyzer power based on specified inlet gas flow rates, heat loss or gain, current density, and cell area-specific resistance. The one-dimensional electrolyzer model was validated by comparison with results obtained from a fully 3-D computational fluid dynamics model developed using FLUENT, and by comparison to experimental data. This paper provides representative results obtained from the HYSYS flowsheet model for a 300 MW coelectrolysis plant, coupled to a high-temperature gas-cooled nuclear reactor. The coelectrolysis process, coupled to a nuclear reactor, provides a means of recycling carbon dioxide back into a useful liquid fuel. If the carbon dioxide source is based on biomass, the entire process would be climate neutral.

  9. Parametric Study Of Large-Scale Production Of Syngas Via High Temperature Co-Electrolysis

    SciTech Connect (OSTI)

    J. E. O'Brien; M. G. McKellar; C. M. Stoots; J. S. Herring; G. L. Hawkes

    2007-11-01T23:59:59.000Z

    A process model has been developed to evaluate the potential performance of a largescale high-temperature co-electrolysis plant for the production of syngas from steam and carbon dioxide. The co-electrolysis process allows for direct electrochemical reduction of the steam – carbon dioxide gas mixture, yielding hydrogen and carbon monoxide, or syngas. The process model has been developed using the Honeywell UniSim systems analysis code. Using this code, a detailed process flow sheet has been defined that includes all the components that would be present in an actual plant such as pumps, compressors, heat exchangers, turbines, and the electrolyzer. Since the electrolyzer is not a standard UniSim component, a custom one-dimensional co-electrolysis model was developed for incorporation into the overall UniSim process flow sheet. The one dimensional co-electrolysis model assumes local chemical equilibrium among the four process-gas species via the gas shift reaction. The electrolyzer model allows for the determination of co-electrolysis outlet temperature, composition (anode and cathode sides); mean Nernst potential, operating voltage and electrolyzer power based on specified inlet gas flow rates, heat loss or gain, current density, and cell area-specific resistance. The one-dimensional electrolyzer model was validated by comparison with results obtained from a fully three dimensional computational fluid dynamics model developed using FLUENT, and by comparison to experimental data. This paper provides representative results obtained from the UniSim flow sheet model for a 300 MW co-electrolysis plant, coupled to a high-temperature gas-cooled nuclear reactor. The coelectrolysis process, coupled to a nuclear reactor, provides a means of recycling carbon dioxide back into a useful liquid fuel. If the carbon dioxide source is based on biomass, the overall process, from production through utilization, would be climate neutral.

  10. Idaho National Laboratory Experimental Research In High Temperature Electrolysis For Hydrogen And Syngas Production

    SciTech Connect (OSTI)

    Carl M. Stoots; James E. O'Brien; J. Stephen Herring; Joseph J. Hartvigsen

    2008-09-01T23:59:59.000Z

    The Idaho National Laboratory (Idaho Falls, Idaho, USA), in collaboration with Ceramatec, Inc. (Salt Lake City, Utah, USA), is actively researching the application of solid oxide fuel cell technology as electrolyzers for large scale hydrogen and syngas production. This technology relies upon electricity and high temperature heat to chemically reduce a steam or steam / CO2 feedstock. Single button cell tests, multi-cell stack, as well as multi-stack testing has been conducted. Stack testing used 10 x 10 cm cells (8 x 8 cm active area) supplied by Ceramatec and ranged from 10 cell short stacks to 240 cell modules. Tests were conducted either in a bench-scale test apparatus or in a newly developed 5 kW Integrated Laboratory Scale (ILS) test facility. Gas composition, operating voltage, and operating temperature were varied during testing. The tests were heavily instrumented, and outlet gas compositions were monitored with a gas chromatograph. The ILS facility is currently being expanded to ~15 kW testing capacity (H2 production rate based upon lower heating value).

  11. HIGH-TEMPERATURE ELECTROLYSIS FOR LARGE-SCALE HYDROGEN AND SYNGAS PRODUCTION FROM NUCLEAR ENERGY – SYSTEM SIMULATION AND ECONOMICS

    SciTech Connect (OSTI)

    J. E. O'Brien; M. G. McKellar; E. A. Harvego; C. M. Stoots

    2009-05-01T23:59:59.000Z

    A research and development program is under way at the Idaho National Laboratory (INL) to assess the technological and scale-up issues associated with the implementation of solid-oxide electrolysis cell technology for efficient high-temperature hydrogen production from steam. This work is supported by the US Department of Energy, Office of Nuclear Energy, under the Nuclear Hydrogen Initiative. This paper will provide an overview of large-scale system modeling results and economic analyses that have been completed to date. System analysis results have been obtained using the commercial code UniSim, augmented with a custom high-temperature electrolyzer module. Economic analysis results were based on the DOE H2A analysis methodology. The process flow diagrams for the system simulations include an advanced nuclear reactor as a source of high-temperature process heat, a power cycle and a coupled steam electrolysis loop. Several reactor types and power cycles have been considered, over a range of reactor outlet temperatures. Pure steam electrolysis for hydrogen production as well as coelectrolysis for syngas production from steam/carbon dioxide mixtures have both been considered. In addition, the feasibility of coupling the high-temperature electrolysis process to biomass and coal-based synthetic fuels production has been considered. These simulations demonstrate that the addition of supplementary nuclear hydrogen to synthetic fuels production from any carbon source minimizes emissions of carbon dioxide during the production process.

  12. Manganese and Ceria Sorbents for High Temperature Sulfur Removal from Biomass-Derived Syngas -- The Impact of Steam on Capacity and Sorption Mode

    SciTech Connect (OSTI)

    Cheah, S.; Parent, Y. O.; Jablonski, W. S.; Vinzant, T.; Olstad, J. L.

    2012-07-01T23:59:59.000Z

    Syngas derived from biomass and coal gasification for fuel synthesis or electricity generation contains sulfur species that are detrimental to downstream catalysts or turbine operation. Sulfur removal in high temperature, high steam conditions has been known to be challenging, but experimental reports on methods to tackle the problem are not often reported. We have developed sorbents that can remove hydrogen sulfide from syngas at high temperature (700 C), both in dry and high steam conditions. The syngas composition chosen for our experiments is derived from statistical analysis of the gasification products of wood under a large variety of conditions. The two sorbents, Cu-ceria and manganese-based, were tested in a variety of conditions. In syngas containing steam, the capacity of the sorbents is much lower, and the impact of the sorbent in lowering H{sub 2}S levels is only evident in low space velocities. Spectroscopic characterization and thermodynamic consideration of the experimental results suggest that in syngas containing 45% steam, the removal of H{sub 2}S is primarily via surface chemisorptions. For the Cu-ceria sorbent, analysis of the amount of H{sub 2}S retained by the sorbent in dry syngas suggests both copper and ceria play a role in H{sub 2}S removal. For the manganese-based sorbent, in dry conditions, there is a solid state transformation of the sorbent, primarily into the sulfide form.

  13. Task 3.3: Warm Syngas Cleanup and Catalytic Processes for Syngas Conversion to Fuels Subtask 3: Advanced Syngas Conversion to Fuels

    SciTech Connect (OSTI)

    Lebarbier Dagel, Vanessa M.; Li, J.; Taylor, Charles E.; Wang, Yong; Dagle, Robert A.; Deshmane, Chinmay A.; Bao, Xinhe

    2014-03-31T23:59:59.000Z

    This collaborative joint research project is in the area of advanced gasification and conversion, within the Chinese Academy of Sciences (CAS)-National Energy Technology Laboratory (NETL)-Pacific Northwest National Laboratory (PNNL) Memorandum of Understanding. The goal for this subtask is the development of advanced syngas conversion technologies. Two areas of investigation were evaluated: Sorption-Enhanced Synthetic Natural Gas Production from Syngas The conversion of synthetic gas (syngas) to synthetic natural gas (SNG) is typically catalyzed by nickel catalysts performed at moderate temperatures (275 to 325°C). The reaction is highly exothermic and substantial heat is liberated, which can lead to process thermal imbalance and destruction of the catalyst. As a result, conversion per pass is typically limited, and substantial syngas recycle is employed. Commercial methanation catalysts and processes have been developed by Haldor Topsoe, and in some reports, they have indicated that there is a need and opportunity for thermally more robust methanation catalysts to allow for higher per-pass conversion in methanation units. SNG process requires the syngas feed with a higher H2/CO ratio than typically produced from gasification processes. Therefore, the water-gas shift reaction (WGS) will be required to tailor the H2/CO ratio. Integration with CO2 separation could potentially eliminate the need for a separate WGS unit, thereby integrating WGS, methanation, and CO2 capture into one single unit operation and, consequently, leading to improved process efficiency. The SNG process also has the benefit of producing a product stream with high CO2 concentrations, which makes CO2 separation more readily achievable. The use of either adsorbents or membranes that selectively separate the CO2 from the H2 and CO would shift the methanation reaction (by driving WGS for hydrogen production) and greatly improve the overall efficiency and economics of the process. The scope of this activity was to develop methods and enabling materials for syngas conversion to SNG with readily CO2 separation. Suitable methanation catalyst and CO2 sorbent materials were developed. Successful proof-of-concept for the combined reaction-sorption process was demonstrated, which culminated in a research publication. With successful demonstration, a decision was made to switch focus to an area of fuels research of more interest to all three research institutions (CAS-NETL-PNNL). Syngas-to-Hydrocarbon Fuels through Higher Alcohol Intermediates There are two types of processes in syngas conversion to fuels that are attracting R&D interest: 1) syngas conversion to mixed alcohols; and 2) syngas conversion to gasoline via the methanol-to-gasoline process developed by Exxon-Mobil in the 1970s. The focus of this task was to develop a one-step conversion technology by effectively incorporating both processes, which is expected to reduce the capital and operational cost associated with the conversion of coal-derived syngas to liquid fuels. It should be noted that this work did not further study the classic Fischer-Tropsch reaction pathway. Rather, we focused on the studies for unique catalyst pathways that involve the direct liquid fuel synthesis enabled by oxygenated intermediates. Recent advances made in the area of higher alcohol synthesis including the novel catalytic composite materials recently developed by CAS using base metal catalysts were used.

  14. Technical and economic evaluation of ten high temperature, high pressure particulate cleanup systems for pressurized fluidized bed combustion

    SciTech Connect (OSTI)

    Rubow, L.N.; Borden, M.; Buchanan, T.L.; Cramp, J.A.C.; Fischer, W.H.; Klett, M.G.; Maruvada, S.M.; Nelson, E.T.; Weinstein, R.E.; Zaharchuk, R.

    1984-07-01T23:59:59.000Z

    The objective of this analysis was to provide a technical and economic evaluation of the ten high temperature, high pressure (HTHP) systems for the purpose of prioritizing them according to performance, cost, and general viability of achieving commercial status. The scope primarily included reviewing/normalizing test experience to date, normalizing commercial designs, developing normalized capital and operating costs for each system, performing trade-off studies, and performing an evaluation utilizing in-house and outside inputs. The HTHP particulate cleanup system must be capable of the same stringent operating requirements as a conventional system, except it must do so at HTHP conditions. Utilities will demand nearly the same reliability as found in conventional equipment. Regarding particulate cleanup, the system must meet NSPS requirements at the stack, and also meet turbine inlet requirements. The ten devices evaluated were: Electrostatic Precipitator - Cottrell Environmental Sciences (CES); Ceramic Felt Filter - Acurex Corporation; Ceramic Cross Flow Filter - Westinghouse; Shallow Static Granular Bed Filter - Ducon/Westinghouse; Electrostatic Granular Bed Filter - General Electric (GE); Moving Granular Bed Filter - Combustion Power Company (CPC); Dry Plate Scrubber - Air Pollution Technology (APT); Magnetic Granular Bed Filter - Exxon; Electrocyclone - General Electric; and Acoustic Agglomerator - Aerojet/Pennsylvania State University (PSU). The test data for the ten devices were normalized to standard conditions with a reference inlet particle loading and size distribution. The purpose of system design normalization is to provide, for each of the HTHP concepts, a scaled-up commercial design which reflects a consistent design approach. 104 figures, 136 tables.

  15. Integrated Warm Gas Multicontaminant Cleanup Technologies for Coal-Derived Syngas

    SciTech Connect (OSTI)

    Turk, Brian; Gupta, Raghubir; Sharma, Pradeepkumar; Albritton, Johnny; Jamal, Aqil

    2010-09-30T23:59:59.000Z

    One of the key obstacles for the introduction of commercial gasification technology for the production of power with Integrated Gasification Combined Cycle (IGCC) plants or the production of value added chemicals, transportation fuels, and hydrogen has been the cost of these systems. This situation is particularly challenging because the United States has ample coal resources available as raw materials and effective use of these raw materials could help us meet our energy and transportation fuel needs while significantly reducing our need to import oil. One component of the cost of these systems that faces strong challenges for continuous improvement is removing the undesirable components present in the syngas. The need to limit the increase in cost of electricity to < 35% for new coal-based power plants which include CO{sub 2} capture and sequestration addresses both the growing social concern for global climate change resulting from the emission of greenhouse gas and in particular CO{sub 2} and the need to control cost increases to power production necessary to meet this social objective. Similar improvements to technologies for trace contaminants are getting similar pressure to reduce environmental emissions and reduce production costs for the syngas to enable production of chemicals from coal that is cost competitive with oil and natural gas. RTI, with DOE/NETL support, has been developing sorbent technologies that enable capture of trace contaminants and CO{sub 2} at temperatures above 400 °F that achieve better capture performance, lower costs and higher thermal efficiency. This report describes the specific work of sorbent development for mercury (Hg), arsenic (As), selenium (Se), cadmium (Cd), and phosphorous (P) and CO{sub 2} removal. Because the typical concentrations of Hg, As, Se, Cd, and P are less than 10 ppmv, the focus has been on single-use sorbents with sufficient capacity to ensure replacement costs are cost effective. The research in this report describes the development efforts which expand this sorbent development effort to include Se, Cd, and P as well as Hg and As. Additional research has focused on improving removal performance with the goal of achieving effluent concentrations that are suitable for chemical production applications. By contrast, sorbent development for CO{sub 2} capture has focused on regenerable sorbents that capture the CO{sub 2} byproduct at higher CO{sub 2} pressures. Previous research on CO{sub 2} sorbents has demonstrated that the most challenging aspect of developing CO{sub 2} sorbents is regeneration. The research documented in this report investigates options to improve regeneration of the CO{sub 2} capture sorbents. This research includes effort on addressing existing regeneration limitations for sorbents previously developed and new approaches that focus initially on the regeneration performance of the sorbent.

  16. Development of ceramic membrane reactors for high temperature gas cleanup. Final report

    SciTech Connect (OSTI)

    Roberts, D.L.; Abraham, I.C.; Blum, Y.; Gottschlich, D.E.; Hirschon, A.; Way, J.D.; Collins, J.

    1993-06-01T23:59:59.000Z

    The objective of this project was to develop high temperature, high pressure catalytic ceramic membrane reactors and to demonstrate the feasibility of using these membrane reactors to control gaseous contaminants (hydrogen sulfide and ammonia) in integrated gasification combined cycle (IGCC) systems. Our strategy was to first develop catalysts and membranes suitable for the IGCC application and then combine these two components as a complete membrane reactor system. We also developed a computer model of the membrane reactor and used it, along with experimental data, to perform an economic analysis of the IGCC application. Our results have demonstrated the concept of using a membrane reactor to remove trace contaminants from an IGCC process. Experiments showed that NH{sub 3} decomposition efficiencies of 95% can be achieved. Our economic evaluation predicts ammonia decomposition costs of less than 1% of the total cost of electricity; improved membranes would give even higher conversions and lower costs.

  17. Progress toward Biomass and Coal-Derived Syngas Warm Cleanup: Proof-of-Concept Process Demonstration of Multicontaminant Removal for Biomass Application

    SciTech Connect (OSTI)

    Howard, Christopher J.; Dagle, Robert A.; Lebarbier, Vanessa MC; Rainbolt, James E.; Li, Liyu; King, David L.

    2013-06-19T23:59:59.000Z

    Systems comprising of multiple sorbent and catalytic beds have been developed for the warm syngas cleanup of coal- and biomass-derived syngas. Tailored specifically for biomass application the process described here consists of six primary unit operations: 1) Na2CO3 bed for HCl removal, 2) two regenerable ZnO beds for bulk H2S removal, 3) ZnO bed for H2S polishing, 4) NiCu/SBA-16 sorbent for trace metal (e.g. AsH3) removal, 5) steam reforming catalyst bed for tars and light hydrocarbons reformation and NH3 decomposition, and a 6) Cu-based LT-WGS catalyst bed. Simulated biomass-derived syngas containing a multitude of inorganic contaminants (H2S, AsH3, HCl, and NH3) and hydrocarbon additives (methane, ethylene, benzene, and naphthalene) was used to demonstrate process effectiveness. The efficiency of the process was demonstrated for a period of 175 hours, during which no signs of deactivation were observed. Post-run analysis revealed small levels of sulfur slipped through the sorbent bed train to the two downstream catalytic beds. Future improvements could be made to the trace metal polishing sorbent to ensure complete inorganic contaminant removal (to low ppb level) prior to the catalytic steps. However, dual, regenerating ZnO beds were effective for continuous removal for the vast majority of the sulfur present in the feed gas. The process was effective for complete AsH3 and HCl removal. The steam reforming catalyst completely reformed all the hydrocarbons present in the feed (methane, ethylene, benzene, and naphthalene) to additional syngas. However, post-run evaluation, under kinetically-controlled conditions, indicates deactivation of the steam reforming catalyst. Spent material characterization suggests this is attributed, in part, to coke formation, likely due to the presence of benzene and/or naphthalene in the feed. Future adaptation of this technology may require dual, regenerable steam reformers. The process and materials described in this report hold promise for a warm cleanup of a variety of contaminant species within warm syngas.

  18. US Department of Energy`s high-temperature and high-pressure particulate cleanup for advanced coal-based power systems

    SciTech Connect (OSTI)

    Dennis, R.A.

    1997-05-01T23:59:59.000Z

    The availability of reliable, low-cost electricity is a cornerstone for the United States` ability to compete in the world market. The Department of Energy (DOE) projects the total consumption of electricity in the US to rise from 2.7 trillion kilowatt-hours in 1990 to 3.5 trillion in 2010. Although energy sources are diversifying, fossil fuel still produces 90 percent of the nation`s energy. Coal is our most abundant fossil fuel resource and the source of 56 percent of our electricity. It has been the fuel of choice because of its availability and low cost. A new generation of high-efficiency power systems has made it possible to continue the use of coal while still protecting the environment. Such power systems greatly reduce the pollutants associated with cola-fired plants built before the 1970s. To realize this high efficiency and superior environmental performance, advanced coal-based power systems will require gas stream cleanup under high-temperature and high-pressure (HTHP) process conditions. Presented in this paper are the HTHP particulate capture requirements for the Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized-Bed Combustion (PFBC) power systems, the HTHP particulate cleanup systems being implemented in the PFBC and IGCC Clean Coal Technology (CCT) Projects, and the currently available particulate capture performance results.

  19. High-Temperature Co-electrolysis of Steam and Carbon Dioxide for Direct Production of Syngas; Equilibrium Model and Single-Cell Tests

    SciTech Connect (OSTI)

    O'Brien, J. E.; Stoots, C. M.; Herring, J. S.; Hartvigsen, J. J.

    2007-07-01T23:59:59.000Z

    An experimental study has been completed to assess the performance of single solid-oxide electrolysis cells operating over a temperature range of 800 to 850şC in the coelectrolysis mode, simultaneously electrolyzing steam and carbon dioxide for the direct production of syngas. The experiments were performed over a range of inlet flow rates of steam, carbon dioxide, hydrogen and nitrogen and over a range of current densities (-0.1 to 0.25 A/cm2) using single electrolyte-supported button electrolysis cells. Steam and carbon dioxide consumption rates associated with electrolysis were measured directly using inlet and outlet dewpoint instrumentation and a gas chromatograph, respectively. Cell operating potentials and cell current were varied using a programmable power supply. Measured values of open-cell potential and outlet gas composition are compared to predictions obtained from a chemical equilibrium coelectrolysis model. Model predictions of outlet gas composition based on an effective equilibrium temperature are shown to agree well with measurements. Cell area-specific resistance values were similar for steam electrolysis and coelectrolysis.

  20. High-Temperature Co-electrolysis of Carbon Dioxide and Steam for the Production of Syngas; Equilibrium Model and Single-Cell Tests

    SciTech Connect (OSTI)

    J. E. O'Brien; C. M. Stoots; G. L. Hawkes; J. S. Herring; J. J. Hartvigsen

    2007-06-01T23:59:59.000Z

    An experimental study has been completed to assess the performance of single solid-oxide electrolysis cells operating over a temperature range of 800 to 850şC in the coelectrolysis mode, simultaneously electrolyzing steam and carbon dioxide for the direct production of syngas. The experiments were performed over a range of inlet flow rates of steam, carbon dioxide, hydrogen and nitrogen and over a range of current densities (-0.1 to 0.25 A/cm2) using single electrolyte-supported button electrolysis cells. Steam and carbon dioxide consumption rates associated with electrolysis were measured directly using inlet and outlet dewpoint instrumentation and a gas chromatograph, respectively. Cell operating potentials and cell current were varied using a programmable power supply. Measured values of open-cell potential and outlet gas composition are compared to predictions obtained from a chemical equilibrium coelectrolysis model. Model predictions of outlet gas composition based on an effective equilibrium temperature are shown to agree well with measurements. Area-specific resistance values were similar for steam electrolysis and coelectrolysis.

  1. The Development of Warm Gas Cleanup Technologies for the Removal of Sulfur Containing Species from Steam Hydrogasification

    E-Print Network [OSTI]

    Luo, Qian

    2012-01-01T23:59:59.000Z

    for biomas-derived syngas. National Renewable EnergyM. Lesemann. RTI/Eastman warm syngas clean-up technology:v the composition of syngas from steam hydrogasification

  2. Integrated High Temperature Coal-to-Hydrogen System with CO2 Separation

    SciTech Connect (OSTI)

    James A. Ruud; Anthony Ku; Vidya Ramaswamy; Wei Wei; Patrick Willson

    2007-05-31T23:59:59.000Z

    A significant barrier to the commercialization of coal-to-hydrogen technologies is high capital cost. The purity requirements for H{sub 2} fuels are generally met by using a series of unit clean-up operations for residual CO removal, sulfur removal, CO{sub 2} removal and final gas polishing to achieve pure H{sub 2}. A substantial reduction in cost can be attained by reducing the number of process operations for H{sub 2} cleanup, and process efficiency can be increased by conducting syngas cleanup at higher temperatures. The objective of this program was to develop the scientific basis for a single high-temperature syngas-cleanup module to produce a pure stream of H{sub 2} from a coal-based system. The approach was to evaluate the feasibility of a 'one box' process that combines a shift reactor with a high-temperature CO{sub 2}-selective membrane to convert CO to CO{sub 2}, remove sulfur compounds, and remove CO{sub 2} in a simple, compact, fully integrated system. A system-level design was produced for a shift reactor that incorporates a high-temperature membrane. The membrane performance targets were determined. System level benefits were evaluated for a coal-to-hydrogen system that would incorporate membranes with properties that would meet the performance targets. The scientific basis for high temperature CO{sub 2}-selective membranes was evaluated by developing and validating a model for high temperature surface flow membranes. Synthesis approaches were pursued for producing membranes that integrated control of pore size with materials adsorption properties. Room temperature reverse-selectivity for CO{sub 2} was observed and performance at higher temperatures was evaluated. Implications for future membrane development are discussed.

  3. Equipment Design and Cost Estimation for Small Modular Biomass Systems, Synthesis Gas Cleanup, and Oxygen Separation Equipment; Task 2: Gas Cleanup Design and Cost Estimates -- Black Liquor Gasification

    SciTech Connect (OSTI)

    Nexant Inc.

    2006-05-01T23:59:59.000Z

    As part of Task 2, Gas Cleanup and Cost Estimates, Nexant investigated the appropriate process scheme for removal of acid gases from black liquor-derived syngas for use in both power and liquid fuels synthesis. Two 3,200 metric tonne per day gasification schemes, both low-temperature/low-pressure (1100 deg F, 40 psi) and high-temperature/high-pressure (1800 deg F, 500 psi) were used for syngas production. Initial syngas conditions from each of the gasifiers was provided to the team by the National Renewable Energy Laboratory and Princeton University. Nexant was the prime contractor and principal investigator during this task; technical assistance was provided by both GTI and Emery Energy.

  4. Development of an Integrated Multi-Contaminant Removal Process Applied to Warm Syngas Cleanup for Coal-Based Advanced Gasification Systems

    SciTech Connect (OSTI)

    Howard Meyer

    2010-11-30T23:59:59.000Z

    This project met the objective to further the development of an integrated multi-contaminant removal process in which H2S, NH3, HCl and heavy metals including Hg, As, Se and Cd present in the coal-derived syngas can be removed to specified levels in a single/integrated process step. The process supports the mission and goals of the Department of Energyâ??s Gasification Technologies Program, namely to enhance the performance of gasification systems, thus enabling U.S. industry to improve the competitiveness of gasification-based processes. The gasification program will reduce equipment costs, improve process environmental performance, and increase process reliability and flexibility. Two sulfur conversion concepts were tested in the laboratory under this project, i.e., the solventbased, high-pressure University of California Sulfur Recovery Process â?? High Pressure (UCSRP-HP) and the catalytic-based, direct oxidation (DO) section of the CrystaSulf-DO process. Each process required a polishing unit to meet the ultra-clean sulfur content goals of <50 ppbv (parts per billion by volume) as may be necessary for fuel cells or chemical production applications. UCSRP-HP was also tested for the removal of trace, non-sulfur contaminants, including ammonia, hydrogen chloride, and heavy metals. A bench-scale unit was commissioned and limited testing was performed with simulated syngas. Aspen-Plus®-based computer simulation models were prepared and the economics of the UCSRP-HP and CrystaSulf-DO processes were evaluated for a nominal 500 MWe, coal-based, IGCC power plant with carbon capture. This report covers the progress on the UCSRP-HP technology development and the CrystaSulf-DO technology.

  5. Simulation and optimization of hot syngas separation processes in integrated gasification combined cycle

    E-Print Network [OSTI]

    Prakash, Kshitij

    2009-01-01T23:59:59.000Z

    IGCC with CO2 capture offers an exciting approach for cleanly using abundant coal reserves of the world to generate electricity. The present state-of-the-art synthesis gas (syngas) cleanup technologies in IGCC involve ...

  6. Liquid Fuel Production from Biomass via High Temperature Steam Electrolysis

    SciTech Connect (OSTI)

    Grant L. Hawkes; Michael G. McKellar

    2009-11-01T23:59:59.000Z

    A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to heat steam for the hydrogen production via the high temperature steam electrolysis process. Hydrogen from electrolysis allows a high utilization of the biomass carbon for syngas production. Oxygen produced form the electrolysis process is used to control the oxidation rate in the oxygen-fed biomass gasifier. Based on the gasifier temperature, 94% to 95% of the carbon in the biomass becomes carbon monoxide in the syngas (carbon monoxide and hydrogen). Assuming the thermal efficiency of the power cycle for electricity generation is 50%, (as expected from GEN IV nuclear reactors), the syngas production efficiency ranges from 70% to 73% as the gasifier temperature decreases from 1900 K to 1500 K. Parametric studies of system pressure, biomass moisture content and low temperature alkaline electrolysis are also presented.

  7. Integrated High Temperature Coal to Hydrogen System with CO2 Separation: Semi-Annual Progress Report 1

    SciTech Connect (OSTI)

    Ruud, J A; Ku, A; Ramaswamy, V; Wei, W

    2005-12-21T23:59:59.000Z

    This is the first semi-annual progress report for the program "Integrated High Temperature Coal to Hydrogen System with CO2 Separation." The objective of the program is to develop a detailed design for a single high-temperature syngas-cleanup module to produce a pure stream of H2 from a coal-based system and to develop the new high-temperature membrane materials at the core of that design. The novel one-box process combines a shift reactor with a high-temperature CO2-selective membrane to convert CO to CO2, remove sulfur compounds, and remove CO2 in a simple, compact, fully integrated system. In the first six months of the program, a conceptual design for the one-box system was developed in Task 1 and the performance targets for the system and the membrane were evaluated. In Task 2.1 processes were developed for creating pore architectures in ceramics that are applicable to membrane structures. In Task 2.2, candidate materials were identified that have the potential for separation of CO2 and H2S at high temperatures.

  8. High Temperatures & Electricity Demand

    E-Print Network [OSTI]

    High Temperatures & Electricity Demand An Assessment of Supply Adequacy in California Trends.......................................................................................................1 HIGH TEMPERATURES AND ELECTRICITY DEMAND.....................................................................................................................7 SECTION I: HIGH TEMPERATURES AND ELECTRICITY DEMAND ..........................9 BACKGROUND

  9. High temperature ceramic membrane for CO? reuse and syngas production

    E-Print Network [OSTI]

    Chang, Le, S.M. Massachusetts Institute of Technology

    2013-01-01T23:59:59.000Z

    In recent years, membrane based technologies have attracted much attention thanks to their simplicity in reactor design. The concept proposed is to use mixed ionic-electronic conducting membrane (MIEC) in CO2 reuse and ...

  10. Assessment of the SRI Gasification Process for Syngas Generation with HTGR Integration -- White Paper

    SciTech Connect (OSTI)

    A.M. Gandrik

    2012-04-01T23:59:59.000Z

    This white paper is intended to compare the technical and economic feasibility of syngas generation using the SRI gasification process coupled to several high-temperature gas-cooled reactors (HTGRs) with more traditional HTGR-integrated syngas generation techniques, including: (1) Gasification with high-temperature steam electrolysis (HTSE); (2) Steam methane reforming (SMR); and (3) Gasification with SMR with and without CO2 sequestration.

  11. Produce syngas for methanol

    SciTech Connect (OSTI)

    Farina, G.L. (Foster Wheeler International Corp., Milan (IT))

    1992-03-01T23:59:59.000Z

    Combined reforming, in which an oxygen reforming reactor is added downstream from a conventional tubular reactor to produce syngas for methanol, achieves a substantial reduction in energy consumption with the least impact on the environment. This paper reports that the advantages of this process scheme are as follows: 8% to 10% reduction in the consumption of natural gas per ton of methanol, The size of the primary reformer is reduced, Reduction of syngas compression requirement due to increased syngas pressure, Reduced steam consumption, Production of syngas with the stoichiometric composition required by methanol synthesis. Synthesis gases for the production of methanol and synfuels are basically mixtures of hydrogen and carbon oxides. They have been produced from natural gas by steam reforming, autothermal reforming and noncatalytic partial oxidation.

  12. SYSTEM ANALYSIS OF NUCLEAR-ASSISTED SYNGAS PRODUCTION FROM COAL

    SciTech Connect (OSTI)

    E. A. Harvego; M. G. McKellar; J. E. O'Brien

    2008-09-01T23:59:59.000Z

    A system analysis has been performed to assess the efficiency and carbon utilization of a nuclear-assisted coal gasification process. The nuclear reactor is a high-temperature helium-cooled reactor that is used primarily to provide power for hydrogen production via high-temperature electrolysis. The supplemental hydrogen is mixed with the outlet stream from an oxygen-blown coal gasifier to produce a hydrogen-rich gas mixture, allowing most of the carbon dioxide to be converted into carbon monoxide, with enough excess hydrogen to produce a syngas product stream with a hydrogen/carbon monoxide molar ratio of about 2:1. Oxygen for the gasifier is also provided by the high-temperature electrolysis process. Results of the analysis predict 90.5% carbon utilization with a syngas production efficiency (defined as the ratio of the heating value of the produced syngas to the sum of the heating value of the coal plus the high-temperature reactor heat input) of 66.1% at a gasifier temperature of 1866 K for the high-moisture-content lignite coal considered. Usage of lower moisture coals such as bituminous can yield carbon utilization approaching 100% and 70% syngas production efficiency.

  13. Method for high temperature mercury capture from gas streams

    DOE Patents [OSTI]

    Granite, E.J.; Pennline, H.W.

    2006-04-25T23:59:59.000Z

    A process to facilitate mercury extraction from high temperature flue/fuel gas via the use of metal sorbents which capture mercury at ambient and high temperatures. The spent sorbents can be regenerated after exposure to mercury. The metal sorbents can be used as pure metals (or combinations of metals) or dispersed on an inert support to increase surface area per gram of metal sorbent. Iridium and ruthenium are effective for mercury removal from flue and smelter gases. Palladium and platinum are effective for mercury removal from fuel gas (syngas). An iridium-platinum alloy is suitable for metal capture in many industrial effluent gas streams including highly corrosive gas streams.

  14. High-Temperature Superconductivity

    ScienceCinema (OSTI)

    Peter Johnson

    2010-01-08T23:59:59.000Z

    Like astronomers tweaking images to gain a more detailed glimpse of distant stars, physicists at Brookhaven National Laboratory have found ways to sharpen images of the energy spectra in high-temperature superconductors ? materials that carry electrical c

  15. High temperature pressure gauge

    DOE Patents [OSTI]

    Echtler, J. Paul (Pittsburgh, PA); Scandrol, Roy O. (Library, PA)

    1981-01-01T23:59:59.000Z

    A high temperature pressure gauge comprising a pressure gauge positioned in fluid communication with one end of a conduit which has a diaphragm mounted in its other end. The conduit is filled with a low melting metal alloy above the diaphragm for a portion of its length with a high temperature fluid being positioned in the remaining length of the conduit and in the pressure gauge.

  16. DOE-Sponsored Syngas Cleanup Demonstration Project Reaches Development

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny:Revised Finding of No Significant6-2002 October5-99 FebruaryThreeCO2

  17. Microsoft PowerPoint - DFT Syngas Cleanup_3

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated Codes |IsLove Your HomeOverview andSinatraMicroBooNEThis page DOE*the

  18. Gas stream cleanup

    SciTech Connect (OSTI)

    Bossart, S.J.; Cicero, D.C.; Zeh, C.M.; Bedick, R.C.

    1990-08-01T23:59:59.000Z

    This report describes the current status and recent accomplishments of gas stream cleanup (GSCU) projects sponsored by the Morgantown Energy Technology Center (METC) of the US Department of Energy (DOE). The primary goal of the Gas Stream Cleanup Program is to develop contaminant control strategies that meet environmental regulations and protect equipment in advanced coal conversion systems. Contaminant control systems are being developed for integration into seven advanced coal conversion processes: Pressurized fludized-bed combustion (PFBC), Direct coal-fueled turbine (DCFT), Intergrated gasification combined-cycle (IGCC), Gasification/molten carbonate fuel cell (MCFC), Gasification/solid oxide fuel cell (SOFC), Coal-fueled diesel (CFD), and Mild gasification (MG). These advanced coal conversion systems present a significant challenge for development of contaminant control systems because they generate multi-contaminant gas streams at high-pressures and high temperatures. Each of the seven advanced coal conversion systems incorporates distinct contaminant control strategies because each has different contaminant tolerance limits and operating conditions. 59 refs., 17 figs., 5 tabs.

  19. Bioenergy Technologies Office Conversion R&D Pathway: Syngas...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Syngas Upgrading to Hydrocarbon Fuels Bioenergy Technologies Office Conversion R&D Pathway: Syngas Upgrading to Hydrocarbon Fuels Syngas upgrading to hydrocarbon fuels is one of...

  20. High-temperature Pump Monitoring - High-temperature ESP Monitoring...

    Broader source: Energy.gov (indexed) [DOE]

    7 4.4.4 High-temperature Pump Monitoring - High-temperature ESP Monitoring Presentation Number: 018 Investigator: Dhruva, Brindesh (Schlumberger Technology Corp.) Objectives: To...

  1. 3D CFD Model of High Temperature H2O/CO2 Co-electrolysis

    SciTech Connect (OSTI)

    Grant Hawkes; James O'Brien; Carl Stoots; Stephen Herring; Joe Hartvigsen

    2007-06-01T23:59:59.000Z

    3D CFD Model of High Temperature H2O/CO2 Co-Electrolysis Grant Hawkes1, James O’Brien1, Carl Stoots1, Stephen Herring1 Joe Hartvigsen2 1 Idaho National Laboratory, Idaho Falls, Idaho, grant.hawkes@inl.gov 2 Ceramatec Inc, Salt Lake City, Utah INTRODUCTION A three-dimensional computational fluid dynamics (CFD) model has been created to model high temperature co-electrolysis of steam and carbon dioxide in a planar solid oxide electrolyzer (SOE) using solid oxide fuel cell technology. A research program is under way at the Idaho National Laboratory (INL) to simultaneously address the research and scale-up issues associated with the implementation of planar solid-oxide electrolysis cell technology for syn-gas production from CO2 and steam. Various runs have been performed under different run conditions to help assess the performance of the SOE. This paper presents CFD results of this model compared with experimental results. The Idaho National Laboratory (INL), in conjunction with Ceramatec Inc. (Salt Lake City, USA) has been researching for several years the use of solid-oxide fuel cell technology to electrolyze steam for large-scale nuclear-powered hydrogen production. Now, an experimental research project is underway at the INL to produce syngas by simultaneously electrolyzing at high-temperature steam and carbon dioxide (CO2) using solid oxide fuel cell technology. A strong interest exists in the large-scale production of syn-gas from CO2 and steam to be reformed into a usable transportation fuel. If biomass is used as the carbon source, the overall process is climate neutral. Consequently, there is a high level of interest in production of syn-gas from CO2 and steam electrolysis. With the price of oil currently around $60 / barrel, synthetically-derived hydrocarbon fuels (synfuels) have become economical. Synfuels are typically produced from syngas – hydrogen (H2) and carbon monoxide (CO) -- using the Fischer-Tropsch process, discovered by Germany before World War II. High-temperature nuclear reactors have the potential for substantially increasing the efficiency of syn-gas production from CO2 and water, with no consumption of fossil fuels, and no production of greenhouse gases. Thermal CO2-splitting and water splitting for syn-gas production can be accomplished via high-temperature electrolysis, using high-temperature nuclear process heat and electricity. A high-temperature advanced nuclear reactor coupled with a high-efficiency high-temperature electrolyzer could achieve a competitive thermal-to-syn-gas conversion efficiency of 45 to 55%.

  2. High temperature storage battery

    SciTech Connect (OSTI)

    Sammells, A.F.

    1988-06-07T23:59:59.000Z

    A high temperature electrochemical cell is described comprising: a solid-state divalent cation conducting electrolyte; a positive electrode in contact with the electrolyte; a solid-state negative electrode contacting a divalent cation conducting molten salt mediating agent providing ionic mediation between the solid-state negative electrode and the solid-state electrolyte.

  3. High Temperature Capacitor Development

    SciTech Connect (OSTI)

    John Kosek

    2009-06-30T23:59:59.000Z

    The absence of high-temperature electronics is an obstacle to the development of untapped energy resources (deep oil, gas and geothermal). US natural gas consumption is projected to grow from 22 trillion cubic feet per year (tcf) in 1999 to 34 tcf in 2020. Cumulatively this is 607 tcf of consumption by 2020, while recoverable reserves using current technology are 177 tcf. A significant portion of this shortfall may be met by tapping deep gas reservoirs. Tapping these reservoirs represents a significant technical challenge. At these depths, temperatures and pressures are very high and may require penetrating very hard rock. Logistics of supporting 6.1 km (20,000 ft) drill strings and the drilling processes are complex and expensive. At these depths up to 50% of the total drilling cost may be in the last 10% of the well depth. Thus, as wells go deeper it is increasingly important that drillers are able to monitor conditions down-hole such as temperature, pressure, heading, etc. Commercial off-the-shelf electronics are not specified to meet these operating conditions. This is due to problems associated with all aspects of the electronics including the resistors and capacitors. With respect to capacitors, increasing temperature often significantly changes capacitance because of the strong temperature dependence of the dielectric constant. Higher temperatures also affect the equivalent series resistance (ESR). High-temperature capacitors usually have low capacitance values because of these dielectric effects and because packages are kept small to prevent mechanical breakage caused by thermal stresses. Electrolytic capacitors do not operate at temperatures above 150oC due to dielectric breakdown. The development of high-temperature capacitors to be used in a high-pressure high-temperature (HPHT) drilling environment was investigated. These capacitors were based on a previously developed high-voltage hybridized capacitor developed at Giner, Inc. in conjunction with a unique high-temperature electrolyte developed during the course of the program. During this program the feasibility of operating a high voltage hybridized capacitor at 230oC was demonstrated. Capacitor specifications were established in conjunction with potential capacitor users. A method to allow for capacitor operation at both ambient and elevated temperatures was demonstrated. The program was terminated prior to moving into Phase II due to a lack of cost-sharing funds.

  4. High Temperature Membrane Working Group

    Broader source: Energy.gov [DOE]

    This presentation provides an overview of the High Temperature Membrane Working Group Meeting in May 2007.

  5. High temperature thermometric phosphors

    DOE Patents [OSTI]

    Allison, Stephen W. (Knoxville, TN); Cates, Michael R. (Oak Ridge, TN); Boatner, Lynn A. (Oak Ridge, TN); Gillies, George T. (Earlysville, VA)

    1999-03-23T23:59:59.000Z

    A high temperature phosphor consists essentially of a material having the general formula LuPO.sub.4 :Dy.sub.(x),Eu.sub.y) wherein: 0.1 wt %.ltoreq.x.ltoreq.20 wt % and 0.1 wt %.ltoreq.y.ltoreq.20 wt %. The high temperature phosphor is in contact with an article whose temperature is to be determined. The article having the phosphor in contact with it is placed in the environment for which the temperature of the article is to be determined. The phosphor is excited by a laser causing the phosphor to fluoresce. The emission from the phosphor is optically focused into a beam-splitting mirror which separates the emission into two separate emissions, the emission caused by the dysprosium dopant and the emission caused by the europium dopent. The separated emissions are optically filtered and the intensities of the emission are detected and measured. The ratio of the intensity of each emission is determined and the temperature of the article is calculated from the ratio of the intensities of the separate emissions.

  6. High temperature thermometric phosphors

    DOE Patents [OSTI]

    Allison, S.W.; Cates, M.R.; Boatner, L.A.; Gillies, G.T.

    1999-03-23T23:59:59.000Z

    A high temperature phosphor consists essentially of a material having the general formula LuPO{sub 4}:Dy{sub x},Eu{sub y} wherein: 0.1 wt % {<=} x {<=} 20 wt % and 0.1 wt % {<=} y {<=} 20 wt %. The high temperature phosphor is in contact with an article whose temperature is to be determined. The article having the phosphor in contact with it is placed in the environment for which the temperature of the article is to be determined. The phosphor is excited by a laser causing the phosphor to fluoresce. The emission from the phosphor is optically focused into a beam-splitting mirror which separates the emission into two separate emissions, the emission caused by the dysprosium dopant and the emission caused by the europium dopant. The separated emissions are optically filtered and the intensities of the emission are detected and measured. The ratio of the intensity of each emission is determined and the temperature of the article is calculated from the ratio of the intensities of the separate emissions. 2 figs.

  7. High temperature adsorption measurements

    SciTech Connect (OSTI)

    Bertani, R.; Parisi, L.; Perini, R.; Tarquini, B.

    1996-01-24T23:59:59.000Z

    Adsorption phenomena are a rich and rather new field of study in geothermal research, in particular at very high temperature. ENEL is interested in the exploitation of geothermal regions with superheated steam, and it is important to understand the behavior of water-rock interaction. We have analyzed in the 170-200 °C temperature range four samples of Monteverdi cuttings; the next experimental effort will be at 220 °C and over in 1996. The first results of the 1995 runs are collected in this paper. We can highlight four main items: 1. At relative pressures over 0.6 the capillarity forces are very important. 2. There is no significant temperature effect. 3. Adsorbed water can be present, and it is able to multiply by a factor of 15 the estimated reserve of super-heated steam only. 4. Pores smaller than 15 Ĺ do not contribute to the adsorbed mass.

  8. Environmental Cleanup Stories

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stories community-environmentassetsimagesicon-environment.jpg Environmental Cleanup Stories Our environmental stewardship commitment: clean up the past, minimize environmental...

  9. High temperature interfacial superconductivity

    DOE Patents [OSTI]

    Bozovic, Ivan (Mount Sinai, NY); Logvenov, Gennady (Port Jefferson Station, NY); Gozar, Adrian Mihai (Port Jefferson, NY)

    2012-06-19T23:59:59.000Z

    High-temperature superconductivity confined to nanometer-scale interfaces has been a long standing goal because of potential applications in electronic devices. The spontaneous formation of a superconducting interface in bilayers consisting of an insulator (La.sub.2CuO.sub.4) and a metal (La.sub.1-xSr.sub.xCuO.sub.4), neither of which is superconducting per se, is described. Depending upon the layering sequence of the bilayers, T.sub.c may be either .about.15 K or .about.30 K. This highly robust phenomenon is confined to within 2-3 nm around the interface. After exposing the bilayer to ozone, T.sub.c exceeds 50 K and this enhanced superconductivity is also shown to originate from a 1 to 2 unit cell thick interfacial layer. The results demonstrate that engineering artificial heterostructures provides a novel, unconventional way to fabricate stable, quasi two-dimensional high T.sub.c phases and to significantly enhance superconducting properties in other superconductors. The superconducting interface may be implemented, for example, in SIS tunnel junctions or a SuFET.

  10. RECHARGEABLE HIGH-TEMPERATURE BATTERIES

    E-Print Network [OSTI]

    Cairns, Elton J.

    2014-01-01T23:59:59.000Z

    F. Eshman, High-Performance Batteries for Electric-VehicleS. Sudar, High Performance Batteries for Electric-VehicleHIGH-TEMPERATURE BATTERIES Elton J. Cairns January 1981 TWO-

  11. Hotline IV ?High Temperature ESP

    Broader source: Energy.gov (indexed) [DOE]

    Hotline IV - High Temperature ESP Brindesh Dhruva (principal Inv.) Michael Dowling (presenter) Schlumberger Track Name May 18, 2010 This presentation does not contain any...

  12. Process for producing ethanol from syngas

    DOE Patents [OSTI]

    Krause, Theodore R; Rathke, Jerome W; Chen, Michael J

    2013-05-14T23:59:59.000Z

    The invention provides a method for producing ethanol, the method comprising establishing an atmosphere containing methanol forming catalyst and ethanol forming catalyst; injecting syngas into the atmosphere at a temperature and for a time sufficient to produce methanol; and contacting the produced methanol with additional syngas at a temperature and for a time sufficient to produce ethanol. The invention also provides an integrated system for producing methanol and ethanol from syngas, the system comprising an atmosphere isolated from the ambient environment; a first catalyst to produce methanol from syngas wherein the first catalyst resides in the atmosphere; a second catalyst to product ethanol from methanol and syngas, wherein the second catalyst resides in the atmosphere; a conduit for introducing syngas to the atmosphere; and a device for removing ethanol from the atmosphere. The exothermicity of the method and system obviates the need for input of additional heat from outside the atmosphere.

  13. syngas optimization | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    as feedstock for production of synthetic fuels such as gasoline, use as feedstock for methanol synthesis, and use as feedstock for production of hydrogen. Desirable Syngas...

  14. syngas composition | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The figure of gasification reactions and transformations illustrated the concept of coal gasification, and noted resulting composition of syngas. This can vary significantly...

  15. Syngas Upgrading to Hydrocarbon Fuels Technology Pathway

    SciTech Connect (OSTI)

    Talmadge, M.; Biddy, M.; Dutta, A.; Jones, S.; Meyer, A.

    2013-03-01T23:59:59.000Z

    This technology pathway case investigates the upgrading of woody biomass derived synthesis gas (syngas) to hydrocarbon biofuels. While this specific discussion focuses on the conversion of syngas via a methanol intermediate to hydrocarbon blendstocks, there are a number of alternative conversion routes for production of hydrocarbons through a wide array of intermediates from syngas. Future work will also consider the variations to this pathway to determine the most economically viable and lowest risk conversion route. Technical barriers and key research needs have been identified that should be pursued for the syngas-to-hydrocarbon pathway to be competitive with petroleum-derived gasoline-, diesel- and jet-range hydrocarbon blendstocks.

  16. Syngas Generator Use for Retrofit DPF Active Regeneration on...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Generator Use for Retrofit DPF Active Regeneration on a Medium Duty Truck Syngas Generator Use for Retrofit DPF Active Regeneration on a Medium Duty Truck Syngas enables low...

  17. Performance of solid oxide fuel cells operated with coal syngas...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Performance of solid oxide fuel cells operated with coal syngas provided directly from a gasification process. Performance of solid oxide fuel cells operated with coal syngas...

  18. Overview of Contaminant Removal From Coal-Derived Syngas

    SciTech Connect (OSTI)

    Layne, A.W.; Alvin, M.A.; Granite, E.; Pennline, H.W.; Siriwardane, R.V.; Keairns, D.; Newby, R.A.

    2007-11-01T23:59:59.000Z

    Gasification is an important strategy for increasing the utilization of abundant domestic coal reserves. DOE envisions increased use of gasification in the United States during the next 20 years. As such, the DOE Gasification Technologies Program, including the FutureGen initiative, will strive to approach a near-zero emissions goal, with respect to multiple pollutants, such as sulfur, mercury, and nitrogen oxides. Since nearly one-third of anthropogenic carbon dioxide emissions are produced by coal-powered generation facilities, conventional coal-burning power plants, and advanced power generation plants, such as IGCC, present opportunities in which carbon can be removed and then permanently stored.
    Gas cleaning systems for IGCC power generation facilities have been effectively demonstrated and used in commercial operations for many years. These systems can reduce sulfur, mercury, and other contaminants in synthesis gas produced by gasifiers to the lowest level achievable in coal-based energy systems. Currently, DOE Fossil Energy's goals set for 2010 direct completion of R&D for advanced gasification combined cycle technology to produce electricity from coal at 45–50% plant efficiency. By 2012, completion of R&D to integrate this technology with carbon dioxide separation, capture, and sequestration into a zero-emissions configuration is targeted with a goal to provide electricity with less than a 10% increase in cost of electricity. By 2020, goals are set to develop zero-emissions plants that are fuel-flexible and capable of multi-product output and thermal efficiencies of over 60% with coal. These objectives dictate that it is essential to not only reduce contaminant emissions into the generated synthesis gas, but also to increase the process or system operating temperature to that of humid gas cleaning criteria conditions (150 to 370 °C), thus reducing the energy penalties that currently exist as a result of lowering process temperatures (?40 to 38 °C) with subsequent reheat to the required higher temperatures.
    From a historical perspective, the evolution of advanced syngas cleaning systems applied in IGCC and chemical and fuel synthesis plants has followed a path of configuring a series of individual cleaning steps, one for each syngas contaminant, each step controlled to its individual temperature and sorbent and catalyst needs. As the number of syngas contaminants of interest has increased (particulates, hydrogen sulfide, carbonyl sulfide, halides such as hydrogen chloride, ammonia, hydrogen cyanide, alkali metals, metal carbonyls, mercury, arsenic, selenium, and cadmium) and the degree of syngas cleaning has become more severe, the potential feasibility of advanced humid gas cleaning has diminished. A focus on multi-contaminant syngas cleaning is needed to enhance the potential cost savings, and performance of humid gas cleaning will focus on multi-contaminant syngas cleaning. Groups of several syngas contaminants to be removed simultaneously need to be considered, resulting in significant gas cleaning system intensification. Intensified, multi-contaminant cleaning processes need to be devised and their potential performance characteristics understood through small-scale testing, conceptual design evaluation, and scale-up assessment with integration into the power generation system. Results of a 1-year study undertaken by DOE/NETL are presented to define improved power plant configurations and technology for advanced multi-contaminant cleanup options.

  19. Bio-Fuel Production Assisted with High Temperature Steam Electrolysis

    SciTech Connect (OSTI)

    Grant Hawkes; James O'Brien; Michael McKellar

    2012-06-01T23:59:59.000Z

    Two hybrid energy processes that enable production of synthetic liquid fuels that are compatible with the existing conventional liquid transportation fuels infrastructure are presented. Using biomass as a renewable carbon source, and supplemental hydrogen from high-temperature steam electrolysis (HTSE), these two hybrid energy processes have the potential to provide a significant alternative petroleum source that could reduce dependence on imported oil. The first process discusses a hydropyrolysis unit with hydrogen addition from HTSE. Non-food biomass is pyrolyzed and converted to pyrolysis oil. The pyrolysis oil is upgraded with hydrogen addition from HTSE. This addition of hydrogen deoxygenates the pyrolysis oil and increases the pH to a tolerable level for transportation. The final product is synthetic crude that could then be transported to a refinery and input into the already used transportation fuel infrastructure. The second process discusses a process named Bio-Syntrolysis. The Bio-Syntrolysis process combines hydrogen from HTSE with CO from an oxygen-blown biomass gasifier that yields syngas to be used as a feedstock for synthesis of liquid synthetic crude. Conversion of syngas to liquid synthetic crude, using a biomass-based carbon source, expands the application of renewable energy beyond the grid to include transportation fuels. It can also contribute to grid stability associated with non-dispatchable power generation. The use of supplemental hydrogen from HTSE enables greater than 90% utilization of the biomass carbon content which is about 2.5 times higher than carbon utilization associated with traditional cellulosic ethanol production. If the electrical power source needed for HTSE is based on nuclear or renewable energy, the process is carbon neutral. INL has demonstrated improved biomass processing prior to gasification. Recyclable biomass in the form of crop residue or energy crops would serve as the feedstock for this process. A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to heat steam for the hydrogen production via the high temperature steam electrolysis process. Oxygen produced form the electrolysis process is used to control the oxidation rate in the oxygen-blown biomass gasifier.

  20. Background and Motivation Biomass derived syngas contains

    E-Print Network [OSTI]

    Das, Suman

    Background and Motivation · Biomass derived syngas contains: CO, H2, small hydrocarbons, H2S shown to be effective for syngas conditioning 0.0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 0 1 2 3 Co2+(molm-2

  1. Philosophy 26 High Temperature Superconductivity

    E-Print Network [OSTI]

    Callender, Craig

    Philosophy 26 High Temperature Superconductivity By Ohm's Law, resistance will dim. Low temperature superconductivity was discovered in 1911 by Heike was explained by BCS theory. BCS theory explains superconductivity microscopically

  2. High-temperature ceramic receivers

    SciTech Connect (OSTI)

    Jarvinen, P. O.

    1980-01-01T23:59:59.000Z

    An advanced ceramic dome cavity receiver is discussed which heats pressurized gas to temperatures above 1800/sup 0/F (1000/sup 0/C) for use in solar Brayton power systems of the dispersed receiver/dish or central receiver type. Optical, heat transfer, structural, and ceramic material design aspects of the receiver are reported and the development and experimental demonstration of a high-temperature seal between the pressurized gas and the high-temperature silicon carbide dome material is described.

  3. Fischer-Tropsch Database Calculations Conversions: CO, H2, and Syngas

    E-Print Network [OSTI]

    Kentucky, University of

    Fischer-Tropsch Database Calculations Conversions: CO, H2, and Syngas f in out in n n n = - 100 n contraction (%) #12;Syngas ratio (H2:CO): sr H in CO in n n = 2 _ _ n: (mols per hour) sr: Syngas ratio Rates active metal (g) r: Rate (mols / hr / g metal) #12;Rate Syngas: syngas H COr r r= +2 r syngas: Syngas

  4. Coal-Derived Warm Syngas Purification and CO2 Capture-Assisted Methane Production

    SciTech Connect (OSTI)

    Dagle, Robert A.; King, David L.; Li, Xiaohong S.; Xing, Rong; Spies, Kurt A.; Zhu, Yunhua; Rainbolt, James E.; Li, Liyu; Braunberger, B.

    2014-10-31T23:59:59.000Z

    Gasifier-derived syngas from coal has many applications in the area of catalytic transformation to fuels and chemicals. Raw syngas must be treated to remove a number of impurities that would otherwise poison the synthesis catalysts. Inorganic impurities include alkali salts, chloride, sulfur compounds, heavy metals, ammonia, and various P, As, Sb, and Se- containing compounds. Systems comprising multiple sorbent and catalytic beds have been developed for the removal of impurities from gasified coal using a warm cleanup approach. This approach has the potential to be more economic than the currently available acid gas removal (AGR) approaches and improves upon currently available processes that do not provide the level of impurity removal that is required for catalytic synthesis application. Gasification also lends itself much more readily to the capture of CO2, important in the regulation and control of greenhouse gas emissions. CO2 capture material was developed and in this study was demonstrated to assist in methane production from the purified syngas. Simultaneous CO2 sorption enhances the CO methanation reaction through relaxation of thermodynamic constraint, thus providing economic benefit rather than simply consisting of an add-on cost for carbon capture and release. Molten and pre-molten LiNaKCO3 can promote MgO and MgO-based double salts to capture CO2 with high cycling capacity. A stable cycling CO2 capacity up to 13 mmol/g was demonstrated. This capture material was specifically developed in this study to operate in the same temperature range and therefore integrate effectively with warm gas cleanup and methane synthesis. By combining syngas methanation, water-gas-shift, and CO2 sorption in a single reactor, single pass yield to methane of 99% was demonstrated at 10 bar and 330oC when using a 20 wt% Ni/MgAl2O4 catalyst and a molten-phase promoted MgO-based sorbent. Under model feed conditions both the sorbent and catalyst exhibited favorable stability after multiple test cycles. The cleanup for warm gas cleanup of inorganics was broken down into three major steps: chloride removal, sulfur removal, and the removal for a multitude of trace metal contaminants. Na2CO3 was found to optimally remove chlorides at an operating temperature of 450şC. For sulfur removal two regenerable ZnO beds are used for bulk H2S removal at 450şC (<5 ppm S) and a non-regenerable ZnO bed for H2S polishing at 300şC (<40 ppb S). It was also found that sulfur from COS could be adsorbed (to levels below our detection limit of 40 ppb) in the presence of water that leads to no detectable slip of H2S. Finally, a sorbent material comprising of Cu and Ni was found to be effective in removing trace metal impurities such as AsH3 and PH3 when operating at 300şC. Proof-of-concept of the integrated cleanup process was demonstrated with gasifier-generated syngas produced at the Western Research Institute using Wyoming Decker Coal. When operating with a ~1 SLPM feed, multiple inorganic contaminant removal sorbents and a tar-reforming bed was able to remove the vast majority of contaminants from the raw syngas. A tar-reforming catalyst was employed due to the production of tars generated from the gasifier used in this particular study. It is envisioned that in a real application a commercial scale gasifier operating at a higher temperature would produce lesser amount of tar. Continuous operation of a poison-sensitive copper-based WGS catalyst located downstream from the cleanup steps resulted in successful demonstration. ?

  5. Thermodynamic analysis of interactions between Ni-based solid oxide fuel cells (SOFC) anodes and trace species in a survey of coal syngas

    SciTech Connect (OSTI)

    Andrew Martinez; Kirk Gerdes; Randall Gemmen; James Postona

    2010-03-20T23:59:59.000Z

    A thermodynamic analysis was conducted to characterize the effects of trace contaminants in syngas derived from coal gasification on solid oxide fuel cell (SOFC) anode material. The effluents from 15 different gasification facilities were considered to assess the impact of fuel composition on anode susceptibility to contamination. For each syngas case, the study considers the magnitude of contaminant exposure resulting from operation of a warm gas cleanup unit at two different temperatures and operation of a nickel-based SOFC at three different temperatures. Contaminant elements arsenic (As), phosphorous (P), and antimony (Sb) are predicted to be present in warm gas cleanup effluent and will interact with the nickel (Ni) components of a SOFC anode. Phosphorous is the trace element found in the largest concentration of the three contaminants and is potentially the most detrimental. Poisoning was found to depend on the composition of the syngas as well as system operating conditions. Results for all trace elements tended to show invariance with cleanup operating temperature, but results were sensitive to syngas bulk composition. Synthesis gas with high steam content tended to resist poisoning.

  6. Carbon Neutral Production Of Syngas Via High Temperature Electrolytic Reduction Of Steam And CO2

    SciTech Connect (OSTI)

    C. Stoots; J. O'Brien; J. Hartvigsen

    2007-11-01T23:59:59.000Z

    This paper presents the most recent results of experiments conducted at the Idaho National Laboratory (INL) studying coelectrolysis of steam and carbon dioxide in solid-oxide electrolysis stacks. Two 10-cell planar stacks were tested under various gas compositions, operating voltages, and operating temperatures. The tests were heavily instrumented, and outlet gas compositions were monitored with a gas chromatograph. Measured outlet compositions, open cell potentials, and coelectrolysis thermal neutral voltages compared reasonably well with a coelectrolysis computer model developed at the INL. Stack ASRs did not change significantly when switching from electrolysis to coelectrolysis operation.

  7. Recent Progress At The Idaho National Laboratory In High Temperature Electrolysis For Hydrogen And Syngas Production

    SciTech Connect (OSTI)

    C. Stoots; J. O'Brien; J. Herring; J. Hartvigsen

    2008-11-01T23:59:59.000Z

    This paper presents the most recent results of experiments conducted at the Idaho National Laboratory (INL) studying electrolysis of steam and coelectrolysis of steam / carbon dioxide in solid-oxide electrolysis stacks. Single button cell tests as well as multi-cell stack testing have been conducted. Multi-cell stack testing used 10 x 10 cm cells (8 x 8 cm active area) supplied by Ceramatec, Inc (Salt Lake City, Utah, USA) and ranged from 10 cell short stacks to 240 cell modules. Tests were conducted either in a bench-scale test apparatus or in a newly developed 5 kW Integrated Laboratory Scale (ILS) test facility. Gas composition, operating voltage, and operating temperature were varied during testing. The tests were heavily instrumented, and outlet gas compositions were monitored with a gas chromatograph. The ILS facility is currently being expanded to 15 kW testing capacity (H2 production rate based upon lower heating value).

  8. High temperature Seebeck coefficient metrology

    SciTech Connect (OSTI)

    Martin, J. [Materials Science and Engineering Laboratory, National Institute of Standards and Technology, Gaithersburg, Maryland 20899 (United States); Tritt, T. [Department of Physics and Astronomy, Clemson University, Clemson, South Carolina 29634 (United States); Uher, C. [Department of Physics, University of Michigan, Ann Arbor, Michigan 48109 (United States)

    2010-12-15T23:59:59.000Z

    We present an overview of the challenges and practices of thermoelectric metrology on bulk materials at high temperature (300 to 1300 K). The Seebeck coefficient, when combined with thermal and electrical conductivity, is an essential property measurement for evaluating the potential performance of novel thermoelectric materials. However, there is some question as to which measurement technique(s) provides the most accurate determination of the Seebeck coefficient at high temperature. This has led to the implementation of nonideal practices that have further complicated the confirmation of reported high ZT materials. To ensure meaningful interlaboratory comparison of data, thermoelectric measurements must be reliable, accurate, and consistent. This article will summarize and compare the relevant measurement techniques and apparatus designs required to effectively manage uncertainty, while also providing a reference resource of previous advances in high temperature thermoelectric metrology.

  9. High temperature Seebeck coefficient metrology

    SciTech Connect (OSTI)

    Martin, J.; Tritt, T.; Uher, Ctirad

    2010-01-01T23:59:59.000Z

    We present an overview of the challenges and practices of thermoelectric metrology on bulk materials at high temperature (300 to 1300 K). The Seebeck coefficient, when combined with thermal and electrical conductivity, is an essential propertymeasurement for evaluating the potential performance of novel thermoelectricmaterials. However, there is some question as to which measurement technique(s) provides the most accurate determination of the Seebeck coefficient at high temperature. This has led to the implementation of nonideal practices that have further complicated the confirmation of reported high ZT materials. To ensure meaningful interlaboratory comparison of data, thermoelectricmeasurements must be reliable, accurate, and consistent. This article will summarize and compare the relevant measurement techniques and apparatus designs required to effectively manage uncertainty, while also providing a reference resource of previous advances in high temperature thermoelectric metrology.

  10. High temperature superconductor current leads

    DOE Patents [OSTI]

    Hull, John R. (Hinsdale, IL); Poeppel, Roger B. (Glen Ellyn, IL)

    1995-01-01T23:59:59.000Z

    An electrical lead having one end for connection to an apparatus in a cryogenic environment and the other end for connection to an apparatus outside the cryogenic environment. The electrical lead includes a high temperature superconductor wire and an electrically conductive material distributed therein, where the conductive material is present at the one end of the lead at a concentration in the range of from 0 to about 3% by volume, and at the other end of the lead at a concentration of less than about 20% by volume. Various embodiments are shown for groups of high temperature superconductor wires and sheaths.

  11. High temperature superconductor current leads

    DOE Patents [OSTI]

    Hull, J.R.; Poeppel, R.B.

    1995-06-20T23:59:59.000Z

    An electrical lead is disclosed having one end for connection to an apparatus in a cryogenic environment and the other end for connection to an apparatus outside the cryogenic environment. The electrical lead includes a high temperature superconductor wire and an electrically conductive material distributed therein, where the conductive material is present at the one end of the lead at a concentration in the range of from 0 to about 3% by volume, and at the other end of the lead at a concentration of less than about 20% by volume. Various embodiments are shown for groups of high temperature superconductor wires and sheaths. 9 figs.

  12. Particulate hot gas stream cleanup technical issues

    SciTech Connect (OSTI)

    Pontius, D.H.; Snyder, T.R.

    1999-09-30T23:59:59.000Z

    The analyses of hot gas stream cleanup particulate samples and descriptions of filter performance studied under this contract were designed to address problems with filter operation that have been linked to characteristics of the collected particulate matter. One objective of this work was to generate an interactive, computerized data bank of the key physical and chemical characteristics of ash and char collected from operating advanced particle filters and to relate these characteristics to the operation and performance of these filters. The interactive data bank summarizes analyses of over 160 ash and char samples from fifteen pressurized fluidized-bed combustion and gasification facilities utilizing high-temperature, high pressure barrier filters.

  13. HIGH TEMPERATURE GEOTHERMAL RESERVOIR ENGINEERING

    E-Print Network [OSTI]

    Schroeder, R.C.

    2009-01-01T23:59:59.000Z

    on the Cerro P r i e t o Geothermal F i e l d , Mexicali,e C e r r o P r i e t o Geothermal F i e l d , Baja C a l i1979 HIGH TEMPERATURE GEOTHERMAL RESERVOIR ENGINEERING R.

  14. High temperature lightweight foamed cements

    DOE Patents [OSTI]

    Sugama, Toshifumi (Mastic Beach, NY)

    1989-01-01T23:59:59.000Z

    Cement slurries are disclosed which are suitable for use in geothermal wells since they can withstand high temperatures and high pressures. The formulation consists of cement, silica flour, water, a retarder, a foaming agent, a foam stabilizer, and a reinforcing agent. A process for producing these cements is also disclosed.

  15. High temperature lightweight foamed cements

    DOE Patents [OSTI]

    Sugama, Toshifumi.

    1989-10-03T23:59:59.000Z

    Cement slurries are disclosed which are suitable for use in geothermal wells since they can withstand high temperatures and high pressures. The formulation consists of cement, silica flour, water, a retarder, a foaming agent, a foam stabilizer, and a reinforcing agent. A process for producing these cements is also disclosed. 3 figs.

  16. Geothermal high temperature instrumentation applications

    SciTech Connect (OSTI)

    Normann, R.A. [Sandia National Labs., Albuquerque, NM (United States); Livesay, B.J. [Livesay Consultants (United States)

    1998-06-11T23:59:59.000Z

    A quick look at the geothermal industry shows a small industry producing about $1 billion in electric sales annually. The industry is becoming older and in need of new innovative solutions to instrumentation problems. A quick look at problem areas is given along with basic instrumentation requirements. The focus of instrumentation is on high temperature electronics.

  17. Development of the Ultra-Clean Dry Cleanup Process for Coal-Based Syngases

    SciTech Connect (OSTI)

    Newby, R.A.; Slimane, R.B.; Lau, F.S.; Jain, S.C.

    2002-09-20T23:59:59.000Z

    The Siemens Westinghouse Power Corporation (SWPC) has proposed a novel scheme for polishing sulfur species, halides, and particulate from syngas to meet stringent cleaning requirements, the ''Ultra-Clean syngas polishing process.'' The overall development objective for this syngas polishing process is to economically achieve the most stringent cleanup requirements for sulfur species, halide species and particulate expected for chemical and fuel synthesis applications (total sulfur species < 60 ppbv, halides < 10 ppbv, and particulate < 0.1 ppmw). A Base Program was conducted to produce ground-work, laboratory test data and process evaluations for a conceptual feasibility assessment of this novel syngas cleaning process. Laboratory testing focused on the identification of suitable sulfur and halide sorbents and operating temperatures for the process. This small-scale laboratory testing was also performed to provide evidence of the capability of the process to reach its stringent syngas cleaning goals. Process evaluations were performed in the Base Program to identify process alternatives, to devise process flow schemes, and to estimate process material & energy balances, process performance, and process costs. While the work has focused on sulfur, halide, and particulate control, considerations of ammonia, and mercury control have also been included.

  18. Acid Doped Membranes for High Temperature PEMFC

    Broader source: Energy.gov [DOE]

    Presentation on Acid Doped Membranes for High Temperature PEMFC to the High Temperature Membrane Working Group, May 25, 2004 in Philadelphia, PA.

  19. High-Temperature Thermoelectric Materials Characterization for...

    Broader source: Energy.gov (indexed) [DOE]

    High-Temperature Thermoelectric Materials Characterization for Automotive Waste Heat Recovery: Success Stories from the High Temperature Materials Laboratory (HTML) User Program...

  20. High Temperature Thermoelectric Materials Characterization for...

    Broader source: Energy.gov (indexed) [DOE]

    High Temperature Thermoelectric Materials Characterization for Automotive Waste Heat Recovery: Success Stories from the High Temperature Materials Laboratory (HTML) User Program...

  1. Nanostructured High Temperature Bulk Thermoelectric Energy Conversion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Temperature Bulk Thermoelectric Energy Conversion for Efficient Waste Heat Recovery Nanostructured High Temperature Bulk Thermoelectric Energy Conversion for Efficient Waste...

  2. Manufacturing Barriers to High Temperature PEM Commercialization...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Barriers to High Temperature PEM Commercialization Manufacturing Barriers to High Temperature PEM Commercialization Presented at the NREL Hydrogen and Fuel Cell Manufacturing R&D...

  3. Sequential high temperature reduction, low temperature hydrolysis...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    high temperature reduction, low temperature hydrolysis for the regeneration of sulfated NOx trap catalysts. Sequential high temperature reduction, low temperature hydrolysis for...

  4. Idaho Cleanup Project Congressional Nuclear Cleanup Caucus

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742Energy ChinaofSchaefer To:Department ofOralGovernmentStandards forand OpportunitiesIanCleanup

  5. Reactor water cleanup system

    DOE Patents [OSTI]

    Gluntz, D.M.; Taft, W.E.

    1994-12-20T23:59:59.000Z

    A reactor water cleanup system includes a reactor pressure vessel containing a reactor core submerged in reactor water. First and second parallel cleanup trains are provided for extracting portions of the reactor water from the pressure vessel, cleaning the extracted water, and returning the cleaned water to the pressure vessel. Each of the cleanup trains includes a heat exchanger for cooling the reactor water, and a cleaner for cleaning the cooled reactor water. A return line is disposed between the cleaner and the pressure vessel for channeling the cleaned water thereto in a first mode of operation. A portion of the cooled water is bypassed around the cleaner during a second mode of operation and returned through the pressure vessel for shutdown cooling. 1 figure.

  6. High temperature structural insulating material

    DOE Patents [OSTI]

    Chen, W.Y.

    1984-07-27T23:59:59.000Z

    A high temperature structural insulating material useful as a liner for cylinders of high temperature engines through the favorable combination of high service temperature (above about 800/sup 0/C), low thermal conductivity (below about 0.2 W/m/sup 0/C), and high compressive strength (above about 250 psi). The insulating material is produced by selecting hollow ceramic beads with a softening temperature above about 800/sup 0/C, a diameter within the range of 20-200 ..mu..m, and a wall thickness in the range of about 2 to 4 ..mu..m; compacting the beads and a compatible silicate binder composition under pressure and sintering conditions to provide the desired structural form with the structure having a closed-cell, compact array of bonded beads.

  7. High temperature structural insulating material

    DOE Patents [OSTI]

    Chen, Wayne Y. (Munster, IN)

    1987-01-01T23:59:59.000Z

    A high temperature structural insulating material useful as a liner for cylinders of high temperature engines through the favorable combination of high service temperature (above about 800.degree. C.), low thermal conductivity (below about 0.2 W/m.degree. C.), and high compressive strength (above about 250 psi). The insulating material is produced by selecting hollow ceramic beads with a softening temperature above about 800.degree. C., a diameter within the range of 20-200 .mu.m, and a wall thickness in the range of about 2-4 .mu.m; compacting the beads and a compatible silicate binder composition under pressure and sintering conditions to provide the desired structural form with the structure having a closed-cell, compact array of bonded beads.

  8. High Temperature Heat Exchanger Project

    SciTech Connect (OSTI)

    Anthony E. Hechanova, Ph.D.

    2008-09-30T23:59:59.000Z

    The UNLV Research Foundation assembled a research consortium for high temperature heat exchanger design and materials compatibility and performance comprised of university and private industry partners under the auspices of the US DOE-NE Nuclear Hydrogen Initiative in October 2003. The objectives of the consortium were to conduct investigations of candidate materials for high temperature heat exchanger componets in hydrogen production processes and design and perform prototypical testing of heat exchangers. The initial research of the consortium focused on the intermediate heat exchanger (located between the nuclear reactor and hydrogen production plan) and the components for the hydrogen iodine decomposition process and sulfuric acid decomposition process. These heat exchanger components were deemed the most challenging from a materials performance and compatibility perspective

  9. High temperature turbine engine structure

    DOE Patents [OSTI]

    Carruthers, William D. (Mesa, AZ); Boyd, Gary L. (Tempe, AZ)

    1994-01-01T23:59:59.000Z

    A high temperature ceramic/metallic turbine engine includes a metallic housing which journals a rotor member of the turbine engine. A ceramic disk-like shroud portion of the engine is supported on the metallic housing portion and maintains a close running clearance with the rotor member. A ceramic spacer assembly maintains the close running clearance of the shroud portion and rotor member despite differential thermal movements between the shroud portion and metallic housing portion.

  10. High temperature turbine engine structure

    DOE Patents [OSTI]

    Carruthers, William D. (Mesa, AZ); Boyd, Gary L. (Tempe, AZ)

    1993-01-01T23:59:59.000Z

    A high temperature ceramic/metallic turbine engine includes a metallic housing which journals a rotor member of the turbine engine. A ceramic disk-like shroud portion of the engine is supported on the metallic housing portion and maintains a close running clearance with the rotor member. A ceramic spacer assembly maintains the close running clearance of the shroud portion and rotor member despite differential thermal movements between the shroud portion and metallic housing portion.

  11. High temperature turbine engine structure

    DOE Patents [OSTI]

    Carruthers, William D. (Mesa, AZ); Boyd, Gary L. (Tempe, AZ)

    1992-01-01T23:59:59.000Z

    A high temperature ceramic/metallic turbine engine includes a metallic housing which journals a rotor member of the turbine engine. A ceramic disk-like shroud portion of the engine is supported on the metallic housing portion and maintains a close running clearance with the rotor member. A ceramic spacer assembly maintains the close running clearance of the shroud portion and rotor member despite differential thermal movements between the shroud portion and metallic housing portion.

  12. Hydrogen production by high-temperature steam gasification of biomass and coal

    SciTech Connect (OSTI)

    Kriengsak, S.N.; Buczynski, R.; Gmurczyk, J.; Gupta, A.K. [University of Maryland, College Park, MD (United States). Dept. of Mechanical Engineering

    2009-04-15T23:59:59.000Z

    High-temperature steam gasification of paper, yellow pine woodchips, and Pittsburgh bituminous coal was investigated in a batch-type flow reactor at temperatures in the range of 700 to 1,200{sup o}C at two different ratios of steam to feedstock molar ratios. Hydrogen yield of 54.7% for paper, 60.2% for woodchips, and 57.8% for coal was achieved on a dry basis, with a steam flow rate of 6.3 g/min at steam temperature of 1,200{sup o}C. Yield of both the hydrogen and carbon monoxide increased while carbon dioxide and methane decreased with the increase in gasification temperature. A 10-fold reduction in tar residue was obtained at high-temperature steam gasification, compared to low temperatures. Steam and gasification temperature affects the composition of the syngas produced. Higher steam-to-feedstock molar ratio had negligible effect on the amount of hydrogen produced in the syngas in the fixed-batch type of reactor. Gasification temperature can be used to control the amounts of hydrogen or methane produced from the gasification process. This also provides mean to control the ratio of hydrogen to CO in the syngas, which can then be processed to produce liquid hydrocarbon fuel since the liquid fuel production requires an optimum ratio between hydrogen and CO. The syngas produced can be further processed to produce pure hydrogen. Biomass fuels are good source of renewable fuels to produce hydrogen or liquid fuels using controlled steam gasification.

  13. LIQUID BIO-FUEL PRODUCTION FROM NON-FOOD BIOMASS VIA HIGH TEMPERATURE STEAM ELECTROLYSIS

    SciTech Connect (OSTI)

    G. L. Hawkes; J. E. O'Brien; M. G. McKellar

    2011-11-01T23:59:59.000Z

    Bio-Syntrolysis is a hybrid energy process that enables production of synthetic liquid fuels that are compatible with the existing conventional liquid transportation fuels infrastructure. Using biomass as a renewable carbon source, and supplemental hydrogen from high-temperature steam electrolysis (HTSE), bio-syntrolysis has the potential to provide a significant alternative petroleum source that could reduce US dependence on imported oil. Combining hydrogen from HTSE with CO from an oxygen-blown biomass gasifier yields syngas to be used as a feedstock for synthesis of liquid transportation fuels via a Fischer-Tropsch process. Conversion of syngas to liquid hydrocarbon fuels, using a biomass-based carbon source, expands the application of renewable energy beyond the grid to include transportation fuels. It can also contribute to grid stability associated with non-dispatchable power generation. The use of supplemental hydrogen from HTSE enables greater than 90% utilization of the biomass carbon content which is about 2.5 times higher than carbon utilization associated with traditional cellulosic ethanol production. If the electrical power source needed for HTSE is based on nuclear or renewable energy, the process is carbon neutral. INL has demonstrated improved biomass processing prior to gasification. Recyclable biomass in the form of crop residue or energy crops would serve as the feedstock for this process. A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to heat steam for the hydrogen production via the high temperature steam electrolysis process. Oxygen produced form the electrolysis process is used to control the oxidation rate in the oxygen-blown biomass gasifier. Based on the gasifier temperature, 94% to 95% of the carbon in the biomass becomes carbon monoxide in the syngas (carbon monoxide and hydrogen). Assuming the thermal efficiency of the power cycle for electricity generation is 50%, (as expected from GEN IV nuclear reactors), the syngas production efficiency ranges from 70% to 73% as the gasifier temperature decreases from 1900 K to 1500 K. Parametric studies of system pressure, biomass moisture content and low temperature alkaline electrolysis are also presented.

  14. Cyclone Performance for Reducing Biochar Concentrations in Syngas

    E-Print Network [OSTI]

    Saucier, David Shane

    2013-05-28T23:59:59.000Z

    % synthesis gas (syngas) and 20% biochar. The concentration of biochar in the syngas needs to be reduced prior to the direct fueling of an internal combustion engine driving a generator for electricity production. It was estimated that direct fueling...

  15. Theoretical study of syngas hydrogenation to methanol on the...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    study of syngas hydrogenation to methanol on the polar Zn-terminated ZnO(0001) surface. Theoretical study of syngas hydrogenation to methanol on the polar Zn-terminated ZnO(0001)...

  16. NSTX High Temperature Sensor Systems

    SciTech Connect (OSTI)

    B.McCormack; H.W. Kugel; P. Goranson; R. Kaita; et al

    1999-11-01T23:59:59.000Z

    The design of the more than 300 in-vessel sensor systems for the National Spherical Torus Experiment (NSTX) has encountered several challenging fusion reactor diagnostic issues involving high temperatures and space constraints. This has resulted in unique miniature, high temperature in-vessel sensor systems mounted in small spaces behind plasma facing armor tiles, and they are prototypical of possible high power reactor first-wall applications. In the Center Stack, Divertor, Passive Plate, and vessel wall regions, the small magnetic sensors, large magnetic sensors, flux loops, Rogowski Coils, thermocouples, and Langmuir Probes are qualified for 600 degrees C operation. This rating will accommodate both peak rear-face graphite tile temperatures during operations and the 350 degrees C bake-out conditions. Similar sensor systems including flux loops, on other vacuum vessel regions are qualified for 350 degrees C operation. Cabling from the sensors embedded in the graphite tiles follows narrow routes to exit the vessel. The detailed sensor design and installation methods of these diagnostic systems developed for high-powered ST operation are discussed.

  17. Syngas Chemistry DOI: 10.1002/anie.201100735

    E-Print Network [OSTI]

    Li, Weixue

    Syngas Chemistry DOI: 10.1002/anie.201100735 Carbon Chain Growth by Formyl Insertion on Rhodium and Cobalt Catalysts in Syngas Conversion** Yong-Hui Zhao, Keju Sun, Xiufang Ma, Jinxun Liu, Dapeng Sun, Hai-Yan Su, and Wei-Xue Li* Syngas (CO/H2) produced from coal, natural gas, or biomass has attracted much

  18. BURNER DEVELOPMENT AND OPERABILITY ISSUES ASSOCIATED WITH STEADY FLOWING SYNGAS

    E-Print Network [OSTI]

    Lieuwen, Timothy C.

    BURNER DEVELOPMENT AND OPERABILITY ISSUES ASSOCIATED WITH STEADY FLOWING SYNGAS FIRED COMBUSTORS-Mu¨nchen, Garching, Germany This article addresses the impact of syngas fuel composition on combustor blowout, flash flashback mechanisms are present in swirling flows, and the key thermophysical properties of a syngas

  19. Syngas into Fuel: Optofluidic Solar Concentrators

    SciTech Connect (OSTI)

    None

    2010-10-01T23:59:59.000Z

    Broad Funding Opportunity Announcement Project: Ohio State has developed an iron-based material and process for converting syngas—a synthetic gas mixture—into electricity, H2, and/or liquid fuel with zero CO2 emissions. Traditional carbon capture methods use chemical solvents or special membranes to separate CO2 from the gas exhaust from coal-fired power plants. Ohio State’s technology uses an iron-based oxygen carrier to generate CO2 and H2 from syngas in separate, pure product streams by means of a circulating bed reactor configuration. The end products of the system are H2, electricity, and/or liquid fuel, all of which are useful sources of power that can come from coal or syngas derived from biomass. Ohio State is developing a high-pressure pilot-scale unit to demonstrate this process at the National Carbon Capture Center.

  20. Mixed conducting membranes for syngas production

    DOE Patents [OSTI]

    Dyer, Paul Nigel (Allentown, PA); Carolan, Michael Francis (Allentown, PA); Butt, Darryl (Gainesville, FL); Van Doorn, Rene Hendrick Elias (Neckarsulm, DE); Cutler, Raymond Ashton (Bountiful, UT)

    2002-01-01T23:59:59.000Z

    This invention presents a new class of multicomponent metallic oxides which are particularly suited toward use in fabricating components used in processes for producing syngas. The non-stoichiometric, A-site rich compositions of the present invention are represented by the formula (Ln.sub.x Ca.sub.1-x).sub.y FeO.sub.3-.delta. wherein Ln is La or a mixture of lanthanides comprising La, and wherein 1.0>x>0.5, 1.1.gtoreq.y>1.0 and .delta. is a number which renders the composition of matter charge neutral. Solid-state membranes formed from these compositions provide a favorable balance of oxygen permeance and resistance to degradation when employed in processes for producing syngas. This invention also presents a process for making syngas which utilizes such membranes.

  1. Faraday imaging at high temperatures

    DOE Patents [OSTI]

    Hackel, L.A.; Reichert, P.

    1997-03-18T23:59:59.000Z

    A Faraday filter rejects background light from self-luminous thermal objects, but transmits laser light at the passband wavelength, thus providing an ultra-narrow optical bandpass filter. The filter preserves images so a camera looking through a Faraday filter at a hot target illuminated by a laser will not see the thermal radiation but will see the laser radiation. Faraday filters are useful for monitoring or inspecting the uranium separator chamber in an atomic vapor laser isotope separation process. Other uses include viewing welds, furnaces, plasma jets, combustion chambers, and other high temperature objects. These filters are can be produced at many discrete wavelengths. A Faraday filter consists of a pair of crossed polarizers on either side of a heated vapor cell mounted inside a solenoid. 3 figs.

  2. Faraday imaging at high temperatures

    DOE Patents [OSTI]

    Hackel, Lloyd A. (Livermore, CA); Reichert, Patrick (Hayward, CA)

    1997-01-01T23:59:59.000Z

    A Faraday filter rejects background light from self-luminous thermal objects, but transmits laser light at the passband wavelength, thus providing an ultra-narrow optical bandpass filter. The filter preserves images so a camera looking through a Faraday filter at a hot target illuminated by a laser will not see the thermal radiation but will see the laser radiation. Faraday filters are useful for monitoring or inspecting the uranium separator chamber in an atomic vapor laser isotope separation process. Other uses include viewing welds, furnaces, plasma jets, combustion chambers, and other high temperature objects. These filters are can be produced at many discrete wavelengths. A Faraday filter consists of a pair of crossed polarizers on either side of a heated vapor cell mounted inside a solenoid.

  3. High-temperature thermocouples and related methods

    DOE Patents [OSTI]

    Rempe, Joy L. (Idaho Falls, ID); Knudson, Darrell L. (Firth, ID); Condie, Keith G. (Idaho Falls, ID); Wilkins, S. Curt (Idaho Falls, ID)

    2011-01-18T23:59:59.000Z

    A high-temperature thermocouple and methods for fabricating a thermocouple capable of long-term operation in high-temperature, hostile environments without significant signal degradation or shortened thermocouple lifetime due to heat induced brittleness.

  4. Materials Characterization Capabilities at the High Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lightweighting Materials Materials Characterization Capabilities at the High Temperature Materials Laboratory: Focus Lightweighting Materials 2011 DOE Hydrogen and Fuel Cells...

  5. Agenda: High Temperature Membrane Working Group Meeting

    Broader source: Energy.gov [DOE]

    Agenda for the High Temperature Membrane Working Group (HTMWG) meeting on May 18, 2009, in Arlington, Virginia

  6. Removal of H{sub 2}S using molten carbonate at high temperature

    SciTech Connect (OSTI)

    Kawase, Makoto, E-mail: kawase@criepi.denken.or.jp; Otaka, Maromu

    2013-12-15T23:59:59.000Z

    Highlights: • The performance of molten carbonate for the removal of H{sub 2}S improves at higher temperatures. • The degree of H{sub 2}S removal is significantly affected by the CO{sub 2} concentration in syngas. • Addition of carbon elements, such as char and tar, decrease the negative effects of CO{sub 2}. • Continuous addition of carbon elements into molten carbonate enables continuous desulfurization. • Desulfurization using molten carbonate is suitable for gasification gas. - Abstract: Gasification is considered to be an effective process for energy conversion from various sources such as coal, biomass, and waste. Cleanup of the hot syngas produced by such a process may improve the thermal efficiency of the overall gasification system. Therefore, the cleanup of hot syngas from biomass gasification using molten carbonate is investigated in bench-scale tests. Molten carbonate acts as an absorbent during desulfurization and dechlorination and as a thermal catalyst for tar cracking. In this study, the performance of molten carbonate for removing H{sub 2}S was evaluated. The temperature of the molten carbonate was set within the range from 800 to 1000 °C. It is found that the removal of H{sub 2}S is significantly affected by the concentration of CO{sub 2} in the syngas. When only a small percentage of CO{sub 2} is present, desulfurization using molten carbonate is inadequate. However, when carbon elements, such as char and tar, are continuously supplied, H{sub 2}S removal can be maintained at a high level. To confirm the performance of the molten carbonate gas-cleaning system, purified biogas was used as a fuel in power generation tests with a molten carbonate fuel cell (MCFC). The fuel cell is a high-performance sensor for detecting gaseous impurities. When purified gas from a gas-cleaning reactor was continuously supplied to the fuel cell, the cell voltage remained stable. Thus, the molten carbonate gas-cleaning reactor was found to afford good gas-cleaning performance.

  7. Improve syngas production using autothermal reforming

    SciTech Connect (OSTI)

    Christensen, T.S.; Primdahl, I.I. (Haldor Topsoe, Copenhagen (Denmark))

    1994-03-01T23:59:59.000Z

    Synthesis gas or syngas, i.e., mixtures of CO and H[sub 2], is a major route from hydrocarbons to many important bulk chemicals ranging from acetic acid to ammonia. Syngas conversion uses hydrocarbon feedstocks, steam, O[sub 2] and CO[sub 2], either separately or in combinations. Autothermal reforming (ATR) is a low-investment process using a simple reactor design. The process is soot-free due to burner design and fixed-bed catalyst. Developed in the late '50s, ATR's main application was for ammonia and methanol syntheses. In ammonia plants, hydrogen production was maximized by operating at high H[sub 2]O/C ratios ranging from 2.5 to 3.5 mole/mole. In methanol units, CO[sub 2] recycle adjusted the syngas composition. ATR is also used to co-produce CO and H[sub 2] as separate streams at H[sub 2]O/C ratios of 1.4 to 2.0 mole/mole. recent developments and optimizations allow cost-effective operation at very low H[sub 2]O/C feed ratios to produce CO-rich syngas. The paper describes the process, including feedstocks and reactor design, the chemical reactions, development and improvements to the process, test results, soot formation, burner design, burner testing, applications, thermodynamic calculations, industrial application, noncatalytic and catalytic partial oxidation, and future uses.

  8. Syngas Upgrading to Hydrocarbon Fuels Technology Pathway

    SciTech Connect (OSTI)

    Talmadge, M.; Biddy, Mary J.; Dutta, Abhijit; Jones, Susanne B.; Meyer, Pimphan A.

    2013-03-31T23:59:59.000Z

    In support of the Bioenergy Technologies Office, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) are undertaking studies of biomass conversion technologies to hydrocarbon fuels to identify barriers and target research toward reducing conversion costs. Process designs and preliminary economic estimates for each of these pathway cases were developed using rigorous modeling tools (Aspen Plus and Chemcad). These analyses incorporated the best information available at the time of development, including data from recent pilot and bench-scale demonstrations, collaborative industrial and academic partners, and published literature and patents. This pathway case investigates the upgrading of biomass derived synthesis gas (‘syngas’) to hydrocarbon biofuels. While this specific discussion focuses on the conversion of syngas via a methanol intermediate to hydrocarbon blendstocks, there are a number of alternative conversion routes for production of hydrocarbons through a wide array of intermediates from syngas. Future work will also consider the variations to this pathway to determine the most economically viable and risk adverse conversion route. Technical barriers and key research needs have been identified that should be pursued for the syngas to hydrocarbon pathway to be competitive with petroleum-derived gasoline, diesel and jet range blendstocks.

  9. High Temperature Superconducting Underground Cable

    SciTech Connect (OSTI)

    Farrell, Roger, A.

    2010-02-28T23:59:59.000Z

    The purpose of this Project was to design, build, install and demonstrate the technical feasibility of an underground high temperature superconducting (HTS) power cable installed between two utility substations. In the first phase two HTS cables, 320 m and 30 m in length, were constructed using 1st generation BSCCO wire. The two 34.5 kV, 800 Arms, 48 MVA sections were connected together using a superconducting joint in an underground vault. In the second phase the 30 m BSCCO cable was replaced by one constructed with 2nd generation YBCO wire. 2nd generation wire is needed for commercialization because of inherent cost and performance benefits. Primary objectives of the Project were to build and operate an HTS cable system which demonstrates significant progress towards commercial progress and addresses real world utility concerns such as installation, maintenance, reliability and compatibility with the existing grid. Four key technical areas addressed were the HTS cable and terminations (where the cable connects to the grid), cryogenic refrigeration system, underground cable-to-cable joint (needed for replacement of cable sections) and cost-effective 2nd generation HTS wire. This was the world’s first installation and operation of an HTS cable underground, between two utility substations as well as the first to demonstrate a cable-to-cable joint, remote monitoring system and 2nd generation HTS.

  10. Upper Los Alamos Canyon Cleanup

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Upper Los Alamos Canyon Cleanup The Upper Los Alamos Canyon Project involves cleaning up hazardous materials left over from some of the Laboratory's earliest activities. Contact...

  11. Biomass-derived Syngas Utilization for Fuels and Chemicals - Final Report

    SciTech Connect (OSTI)

    David C. Dayton

    2010-03-24T23:59:59.000Z

    Executive Summary The growing gap between petroleum production and demand, mounting environmental concerns, and increasing fuel prices have stimulated intense interest in research and development (R&D) of alternative fuels, both synthetic and bio-derived. Currently, the most technically defined thermochemical route for producing alternative fuels from lignocellulosic biomass involves gasification/reforming of biomass to produce syngas (carbon monoxide [CO] + hydrogen [H2]), followed by syngas cleaning, Fischer-Tropsch synthesis (FTS) or mixed alcohol synthesis, and some product upgrading via hydroprocessing or separation. A detailed techno-economic analysis of this type of process has recently been published [1] and it highlights the need for technical breakthroughs and technology demonstration for gas cleanup and fuel synthesis. The latter two technical barrier areas contribute 40% of the total thermochemical ethanol cost and 70% of the production cost, if feedstock costs are factored out. Developing and validating technologies that reduce the capital and operating costs of these unit operations will greatly reduce the risk for commercializing integrated biomass gasification/fuel synthesis processes for biofuel production. The objective of this project is to develop and demonstrate new catalysts and catalytic processes that can efficiently convert biomass-derived syngas into diesel fuel and C2-C4 alcohols. The goal is to improve the economics of the processes by improving the catalytic activity and product selectivity, which could lead to commercialization. The project was divided into 4 tasks: Task 1: Reactor Systems: Construction of three reactor systems was a project milestone. Construction of a fixed-bed microreactor (FBR), a continuous stirred tank reactor (CSTR), and a slurry bubble column reactor (SBCR) were completed to meet this milestone. Task 2: Iron Fischer-Tropsch (FT) Catalyst: An attrition resistant iron FT catalyst will be developed and tested. Task 3: Chemical Synthesis: Promising process routes will be identified for synthesis of selected chemicals from biomass-derived syngas. A project milestone was to select promising mixed alcohol catalysts and screen productivity and performance in a fixed bed micro-reactor using bottled syngas. This milestone was successfully completed in collaboration withour catalyst development partner. Task 4: Modeling, Engineering Evaluation, and Commercial Assessment: Mass and energy balances of conceptual commercial embodiment for FT and chemical synthesis were completed.

  12. ISOBUTANOL FROM SYNGAS IN A THREE PHASE SYSTEM

    SciTech Connect (OSTI)

    Peter Tijrn

    2002-12-29T23:59:59.000Z

    With growing interest in oxygenates as octane booster for automotive fuels, various synthesis routes for these chemicals are being investigated. Among others, alternative routes to isobutene, the C4-components in MTBE-synthesis are under investigation. A promising path to isobutene is the heterogeneously catalyzed CO-hydrogenation to isobutanol with following dehydration (Fig. 1). As shown by thermodynamical studies, the heterogeneously catalyzed CO-hydrogenation to isobutanol is not expected to experience any thermodynamic constraints. However, heterogeneous hydrogenation of CO is a very exothermic process, a problem which can only be partly solved when being conducted in a plug flow reactor. When carried out in reaction vessels with moving catalyst bed (e.g. three phase stirred tank), heat transfer problems can be resolved, along with additional benefits connected with this reactor type. Several heterogeneous catalytic systems have been under investigation for their capability of isobutanol synthesis from syngas. Most promising catalysts for an active and selective isobutanol synthesis from CO are modified high temperature methanol catalysts.

  13. New Contract Helps Portsmouth GDP Cleanup

    Broader source: Energy.gov [DOE]

    To accelerate the Portsmouth GDP cleanup efforts left over from the Cold War, the Department of Energy made a huge step forward in our nuclear environmental cleanup efforts.

  14. Promising Science for Plutonium Cleanup | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Promising Science for Plutonium Cleanup Promising Science for Plutonium Cleanup Released: July 06, 2011 New finding shows a research area to expand in EMSL Radiochemistry Annex...

  15. Deep Trek High Temperature Electronics Project

    SciTech Connect (OSTI)

    Bruce Ohme

    2007-07-31T23:59:59.000Z

    This report summarizes technical progress achieved during the cooperative research agreement between Honeywell and U.S. Department of Energy to develop high-temperature electronics. Objects of this development included Silicon-on-Insulator (SOI) wafer process development for high temperature, supporting design tools and libraries, and high temperature integrated circuit component development including FPGA, EEPROM, high-resolution A-to-D converter, and a precision amplifier.

  16. Materials Characterization Capabilities at the High Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2010 -- Washington D.C. lm028laracurzio2010o.pdf More Documents & Publications Materials Characterization Capabilities at the High Temperature Materials Laboratory and HTML...

  17. Materials Characterization Capabilities at the High Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Review and Peer Evaluation lm028laracurzio2011o.pdf More Documents & Publications Materials Characterization Capabilities at the High Temperature Materials Laboratory and HTML...

  18. Materials Characterization Capabilities at the High Temperature...

    Broader source: Energy.gov (indexed) [DOE]

    and Peer Evaluation Meeting lm028laracurzio2012o.pdf More Documents & Publications Materials Characterization Capabilities at the High Temperature Materials Laboratory and HTML...

  19. Materials Characterization Capabilities at the High Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    May 18-22, 2009 -- Washington D.C. lm01laracurzio.pdf More Documents & Publications Materials Characterization Capabilities at the High Temperature Materials Laboratory and HTML...

  20. Materials Characterization Capabilities at the High Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Laboratory: Focus on Carbon Fiber and Composites Materials Characterization Capabilities at the High Temperature Materials Laboratory: Focus on Carbon Fiber and Composites 2011 DOE...

  1. Materials Characterization Capabilities at the High Temperature...

    Broader source: Energy.gov (indexed) [DOE]

    Characterization Capabilities at the High Temperature Materials Laboratory: Focus on Carbon Fiber and Composites Project ID: LM027 DOE 2011 Vehicle Technologies Annual Merit...

  2. Intertwined Orders in High Temperature Superconductors

    E-Print Network [OSTI]

    Ostoja-Starzewski, Martin

    Intertwined Orders in High Temperature Superconductors ! Eduardo Fradkin University of Illinois · Electronic liquid crystal phases have also been seen heavy fermions and iron superconductors 7 #12

  3. Quantitative Modeling of High Temperature Magnetization Dynamics

    SciTech Connect (OSTI)

    Zhang, Shufeng

    2009-03-01T23:59:59.000Z

    Final Technical Report Project title: Quantitative Modeling of High Temperature Magnetization Dynamics DOE/Office of Science Program Manager Contact: Dr. James Davenport

  4. Photonic crystals for high temperature applications

    E-Print Network [OSTI]

    Yeng, Yi Xiang

    2014-01-01T23:59:59.000Z

    This thesis focuses on the design, optimization, fabrication, and experimental realization of metallic photonic crystals (MPhCs) for high temperature applications, for instance thermophotovoltaic (TPV) energy conversion ...

  5. Syngas Enhanced High Efficiency Low Temperature Combustion for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Enhanced High Efficiency Low Temperature Combustion for Clean Diesel Engines Syngas Enhanced High Efficiency Low Temperature Combustion for Clean Diesel Engines A significant...

  6. High-Temperature-High-Volume Lifting for Enhanced Geothermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Temperature-High-Volume Lifting for Enhanced Geothermal Systems High-Temperature-High-Volume Lifting for Enhanced Geothermal Systems High-Temperature-High-Volume Lifting for...

  7. High Temperature, High Pressure Devices for Zonal Isolation in...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells High Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells High Temperature,...

  8. High Temperature Gas Reactors The Next Generation ?

    E-Print Network [OSTI]

    -Proof Advanced Reactor and Gas Turbine #12;Flow through Power Conversion Vessel 8 #12;9 TRISO Fuel Particle1 High Temperature Gas Reactors The Next Generation ? Professor Andrew C Kadak Massachusetts of Brayton vs. Rankine Cycle · High Temperature Helium Gas (900 C) · Direct or Indirect Cycle · Originally

  9. High temperature superconducting fault current limiter

    DOE Patents [OSTI]

    Hull, J.R.

    1997-02-04T23:59:59.000Z

    A fault current limiter for an electrical circuit is disclosed. The fault current limiter includes a high temperature superconductor in the electrical circuit. The high temperature superconductor is cooled below its critical temperature to maintain the superconducting electrical properties during operation as the fault current limiter. 15 figs.

  10. High temperature superconducting fault current limiter

    DOE Patents [OSTI]

    Hull, John R. (Hinsdale, IL)

    1997-01-01T23:59:59.000Z

    A fault current limiter (10) for an electrical circuit (14). The fault current limiter (10) includes a high temperature superconductor (12) in the electrical circuit (14). The high temperature superconductor (12) is cooled below its critical temperature to maintain the superconducting electrical properties during operation as the fault current limiter (10).

  11. The Morgantown Energy Technology Center`s particulate cleanup program

    SciTech Connect (OSTI)

    Dennis, R.A.

    1995-12-01T23:59:59.000Z

    The development of integrated gasification combined cycle (IGCC) and pressurized fluidized-bed combustion (PFBC) power systems has made it possible to use coal while still protecting the environment. Such power systems significantly reduce the pollutants associated with coal-fired plants built before the 1970s. This superior environmental performance and related high system efficiency is possible, in part, because particulate gas-stream cleanup is conducted at high-temperature and high-pressure process conditions. A main objective of the Particulate Cleanup Program at the Morgantown Energy Technology Center (METC) is to ensure the success of the CCT demonstration projects. METC`s Particulate Cleanup Program supports research, development, and demonstration in three areas: (1) filter-system development, (2) barrier-filter component development, and (3) ash and char characterization. The support is through contracted research, cooperative agreements, Cooperative Research And Development Agreements (CRADAs), and METC`s own in-house research. This paper describes METC`s Particulate Cleanup Program.

  12. Environmental Management (EM) Cleanup Projects

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2008-09-24T23:59:59.000Z

    The guide supports DOE O 413.3A, Program and Project Management for the Acquisition of Capital Assets, and provides guidance on environmental management cleanup projects. Canceled by DOE N 251.105.

  13. Superfund Cleanups and Infant Health

    E-Print Network [OSTI]

    Currie, Janet

    2011-02-23T23:59:59.000Z

    We are the first to examine the effect of Superfund cleanups on infant health rather than focusing on proximity to a site. We study singleton births to mothers residing within 5km of a Superfund site between 1989 and 2003 ...

  14. Synthesis of Methanol and Dimethyl Ether from Syngas over Pd...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Methanol and Dimethyl Ether from Syngas over PdZnOAl2O3 Catalysts. Synthesis of Methanol and Dimethyl Ether from Syngas over PdZnOAl2O3 Catalysts. Abstract: A PdZnOAl2O3...

  15. Amorphous Alloy Membranes for High Temperature Hydrogen Separation

    SciTech Connect (OSTI)

    Coulter, K

    2013-09-30T23:59:59.000Z

    At the beginning of this project, thin film amorphous alloy membranes were considered a nascent but promising new technology for industrial-scale hydrogen gas separations from coal- derived syngas. This project used a combination of theoretical modeling, advanced physical vapor deposition fabricating, and laboratory and gasifier testing to develop amorphous alloy membranes that had the potential to meet Department of Energy (DOE) targets in the testing strategies outlined in the NETL Membrane Test Protocol. The project is complete with Southwest Research Institute® (SwRI®), Georgia Institute of Technology (GT), and Western Research Institute (WRI) having all operated independently and concurrently. GT studied the hydrogen transport properties of several amorphous alloys and found that ZrCu and ZrCuTi were the most promising candidates. GT also evaluated the hydrogen transport properties of V, Nb and Ta membranes coated with different transition-metal carbides (TMCs) (TM = Ti, Hf, Zr) catalytic layers by employing first-principles calculations together with statistical mechanics methods and determined that TiC was the most promising material to provide catalytic hydrogen dissociation. SwRI developed magnetron coating techniques to deposit a range of amorphous alloys onto both porous discs and tubular substrates. Unfortunately none of the amorphous alloys could be deposited without pinhole defects that undermined the selectivity of the membranes. WRI tested the thermal properties of the ZrCu and ZrNi alloys and found that under reducing environments the upper temperature limit of operation without recrystallization is ~250 °C. There were four publications generated from this project with two additional manuscripts in progress and six presentations were made at national and international technical conferences. The combination of the pinhole defects and the lack of high temperature stability make the theoretically identified most promising candidate amorphous alloys unsuitable for application as hydrogen separation membranes in coal fire systems.

  16. Polk power station syngas cooling system

    SciTech Connect (OSTI)

    Jenkins, S.D.

    1995-01-01T23:59:59.000Z

    Tampa Electric Company (TEC) is in the site development and construction phase of the new Polk Power Station Unit No. 1. This will be the first unit at a new site and will use Integrated Gasification Combined Cycle (IGCC) Technology. The unit will utilize Texaco`s oxygen-blown, entrained-flow coal gasification, along with combined cycle power generation, to produce nominal 260MW. Integral to the gasification process is the syngas cooling system. The design, integration, fabrication, transportation, and erection of this equipment have provided and continue to provide major challenges for this project.

  17. SUSY and symmetry nonrestoration at high temperature

    SciTech Connect (OSTI)

    Bajc, Borut [J. Stefan Institute, 1001 Ljubljana (Slovenia)

    1999-07-15T23:59:59.000Z

    The status of internal symmetry breaking at high temperature in super-symmetric models is shortly reviewed. This possibility could solve some well known cosmological problems, such as the domain wall, monopole and false vacuum problems.

  18. Accelerating cleanup: Paths to closure

    SciTech Connect (OSTI)

    NONE

    1998-06-01T23:59:59.000Z

    This report describes the status of Environmental Management`s (EM`s) cleanup program and a direction forward to complete achievement of the 2006 vision. Achieving the 2006 vision results in significant benefits related to accomplishing EM program objectives. As DOE sites accelerate cleanup activities, risks to public health, the environment, and worker safety and health are all reduced. Finding more efficient ways to conduct work can result in making compliance with applicable environmental requirements easier to achieve. Finally, as cleanup activities at sites are completed, the EM program can focus attention and resources on the small number of sites with more complex cleanup challenges. Chapter 1 describes the process by which this report has been developed and what it hopes to accomplish, its relationship to the EM decision-making process, and a general background of the EM mission and program. Chapter 2 describes how the site-by-site projections were constructed, and summarizes, for each of DOE`s 11 Operations/Field Offices, the projected costs and schedules for completing the cleanup mission. Chapter 3 presents summaries of the detailed cleanup projections from three of the 11 Operations/Field Offices: Rocky Flats (Colorado), Richland (Washington), and Savannah River (South Carolina). The remaining eight Operations/Field Office summaries are in Appendix E. Chapter 4 reviews the cost drivers, budgetary constraints, and performance enhancements underlying the detailed analysis of the 353 projects that comprise EM`s accelerated cleanup and closure effort. Chapter 5 describes a management system to support the EM program. Chapter 6 provides responses to the general comments received on the February draft of this document.

  19. Investigations into High Temperature Components and Packaging

    SciTech Connect (OSTI)

    Marlino, L.D.; Seiber, L.E.; Scudiere, M.B.; M.S. Chinthavali, M.S.; McCluskey, F.P.

    2007-12-31T23:59:59.000Z

    The purpose of this report is to document the work that was performed at the Oak Ridge National Laboratory (ORNL) in support of the development of high temperature power electronics and components with monies remaining from the Semikron High Temperature Inverter Project managed by the National Energy Technology Laboratory (NETL). High temperature electronic components are needed to allow inverters to operate in more extreme operating conditions as required in advanced traction drive applications. The trend to try to eliminate secondary cooling loops and utilize the internal combustion (IC) cooling system, which operates with approximately 105 C water/ethylene glycol coolant at the output of the radiator, is necessary to further reduce vehicle costs and weight. The activity documented in this report includes development and testing of high temperature components, activities in support of high temperature testing, an assessment of several component packaging methods, and how elevated operating temperatures would impact their reliability. This report is organized with testing of new high temperature capacitors in Section 2 and testing of new 150 C junction temperature trench insulated gate bipolar transistor (IGBTs) in Section 3. Section 4 addresses some operational OPAL-GT information, which was necessary for developing module level tests. Section 5 summarizes calibration of equipment needed for the high temperature testing. Section 6 details some additional work that was funded on silicon carbide (SiC) device testing for high temperature use, and Section 7 is the complete text of a report funded from this effort summarizing packaging methods and their reliability issues for use in high temperature power electronics. Components were tested to evaluate the performance characteristics of the component at different operating temperatures. The temperature of the component is determined by the ambient temperature (i.e., temperature surrounding the device) plus the temperature increase inside the device due the internal heat that is generated due to conduction and switching losses. Capacitors and high current switches that are reliable and meet performance specifications over an increased temperature range are necessary to realize electronics needed for hybrid-electric vehicles (HEVs), fuel cell (FC) and plug-in HEVs (PHEVs). In addition to individual component level testing, it is necessary to evaluate and perform long term module level testing to ascertain the effects of high temperature operation on power electronics.

  20. DOE outlines complex cleanup options

    SciTech Connect (OSTI)

    Lobsenz, G.

    1994-02-25T23:59:59.000Z

    The Energy Department said last week it will consider four different strategies for cleanup of its nuclear weapons complex in a draft programmatic environmental impact statement due for release this summer. In an implementation plan released for public comment February 17, DOE also said the EIS would look at centralized, decentralized and regional approaches to management of six types of radioactive and hazardous wastes. Other issues to be addressed in the EIS are development of innovative cleanup technology, budgeting and prioritization, job cutbacks and worker retraining, waste minimization and community involvement in cleanup decisions. However, DOE said it had decided not to address spent nuclear fuel storage in the EIS, as had been previously planned. Instead, spent fuel storage options will be reviewed in another environmental study being done under court order for DOE's Idaho National Engineering Laboratory. Findings from the INEL study will be incorporated in the department-wide EIS for environmental restoration and waste management.

  1. Nuclear fuels for very high temperature applications

    SciTech Connect (OSTI)

    Lundberg, L.B.; Hobbins, R.R.

    1992-08-01T23:59:59.000Z

    The success of the development of nuclear thermal propulsion devices and thermionic space nuclear power generation systems depends on the successful utilization of nuclear fuel materials at temperatures in the range 2000 to 3500 K. Problems associated with the utilization of uranium bearing fuel materials at these very high temperatures while maintaining them in the solid state for the required operating times are addressed. The critical issues addressed include evaporation, melting, reactor neutron spectrum, high temperature chemical stability, fabrication, fission induced swelling, fission product release, high temperature creep, thermal shock resistance, and fuel density, both mass and fissile atom. Candidate fuel materials for this temperature range are based on UO{sub 2} or uranium carbides. Evaporation suppression, such as a sealed cladding, is required for either fuel base. Nuclear performance data needed for design are sparse for all candidate fuel forms in this temperature range, especially at the higher temperatures.

  2. Nuclear fuels for very high temperature applications

    SciTech Connect (OSTI)

    Lundberg, L.B.; Hobbins, R.R.

    1992-01-01T23:59:59.000Z

    The success of the development of nuclear thermal propulsion devices and thermionic space nuclear power generation systems depends on the successful utilization of nuclear fuel materials at temperatures in the range 2000 to 3500 K. Problems associated with the utilization of uranium bearing fuel materials at these very high temperatures while maintaining them in the solid state for the required operating times are addressed. The critical issues addressed include evaporation, melting, reactor neutron spectrum, high temperature chemical stability, fabrication, fission induced swelling, fission product release, high temperature creep, thermal shock resistance, and fuel density, both mass and fissile atom. Candidate fuel materials for this temperature range are based on UO{sub 2} or uranium carbides. Evaporation suppression, such as a sealed cladding, is required for either fuel base. Nuclear performance data needed for design are sparse for all candidate fuel forms in this temperature range, especially at the higher temperatures.

  3. High temperature crystalline superconductors from crystallized glasses

    DOE Patents [OSTI]

    Shi, Donglu (Downers Grove, IL)

    1992-01-01T23:59:59.000Z

    A method of preparing a high temperature superconductor from an amorphous phase. The method involves preparing a starting material of a composition of Bi.sub.2 Sr.sub.2 Ca.sub.3 Cu.sub.4 Ox or Bi.sub.2 Sr.sub.2 Ca.sub.4 Cu.sub.5 Ox, forming an amorphous phase of the composition and heat treating the amorphous phase for particular time and temperature ranges to achieve a single phase high temperature superconductor.

  4. Methods and systems for producing syngas

    DOE Patents [OSTI]

    Hawkes, Grant L; O'Brien, James E; Stoots, Carl M; Herring, J. Stephen; McKellar, Michael G; Wood, Richard A; Carrington, Robert A; Boardman, Richard D

    2013-02-05T23:59:59.000Z

    Methods and systems are provided for producing syngas utilizing heat from thermochemical conversion of a carbonaceous fuel to support decomposition of at least one of water and carbon dioxide using one or more solid-oxide electrolysis cells. Simultaneous decomposition of carbon dioxide and water or steam by one or more solid-oxide electrolysis cells may be employed to produce hydrogen and carbon monoxide. A portion of oxygen produced from at least one of water and carbon dioxide using one or more solid-oxide electrolysis cells is fed at a controlled flow rate in a gasifier or combustor to oxidize the carbonaceous fuel to control the carbon dioxide to carbon monoxide ratio produced.

  5. Celebrating DOE'sCleanup

    E-Print Network [OSTI]

    .S. Department of Energy (DOE) and Brookhaven National Laboratory management (the Lab) will celebrate a momentousCelebrating DOE'sCleanup Accomplishments then,now,andtomorrow U.S. Department of Energy Brookhaven-by-shovel, system-by-system, and project-by-project, incremental but progressive achievements were made

  6. Superfund Cleanups and Infant Health

    E-Print Network [OSTI]

    Currie, Janet

    We are the first to examine the effect of Superfund cleanups on infant health rather than focusing on proximity to a site. We study singleton births to mothers residing within 5km of a Superfund site between 1989-2003 in ...

  7. High temperature storage loop : final design report.

    SciTech Connect (OSTI)

    Gill, David Dennis; Kolb, William J.

    2013-07-01T23:59:59.000Z

    A three year plan for thermal energy storage (TES) research was created at Sandia National Laboratories in the spring of 2012. This plan included a strategic goal of providing test capability for Sandia and for the nation in which to evaluate high temperature storage (>650%C2%B0C) technology. The plan was to scope, design, and build a flow loop that would be compatible with a multitude of high temperature heat transfer/storage fluids. The High Temperature Storage Loop (HTSL) would be reconfigurable so that it was useful for not only storage testing, but also for high temperature receiver testing and high efficiency power cycle testing as well. In that way, HTSL was part of a much larger strategy for Sandia to provide a research and testing platform that would be integral for the evaluation of individual technologies funded under the SunShot program. DOE's SunShot program seeks to reduce the price of solar technologies to 6/kWhr to be cost competitive with carbon-based fuels. The HTSL project sought to provide evaluation capability for these SunShot supported technologies. This report includes the scoping, design, and budgetary costing aspects of this effort

  8. Thermal disconnect for high-temperature batteries

    DOE Patents [OSTI]

    Jungst, Rudolph George (Albuquerque, NM); Armijo, James Rudolph (Albuquerque, NM); Frear, Darrel Richard (Austin, TX)

    2000-01-01T23:59:59.000Z

    A new type of high temperature thermal disconnect has been developed to protect electrical and mechanical equipment from damage caused by operation at extreme temperatures. These thermal disconnects allow continuous operation at temperatures ranging from 250.degree. C. to 450.degree. C., while rapidly terminating operation at temperatures 50.degree. C. to 150.degree. C. higher than the continuous operating temperature.

  9. HYDROGEN SULFIDE -HIGH TEMPERATURE DRILLING CONTINGENCY PLAN

    E-Print Network [OSTI]

    HYDROGEN SULFIDE - HIGH TEMPERATURE DRILLING CONTINGENCY PLAN OCEAN DRILLING PROGRAM TEXAS A&M UNIVERSITY Technical Note 16 Steven P. Howard Ocean Drilling Program Texas A&M University 1000 Discovery Drive College Station, TX 77845-9547 Daniel H. Reudelhuber Ocean Drilling Program Texas A&M University

  10. High temperature hot water systems: A primer

    SciTech Connect (OSTI)

    Govan, F.A. [NMD and Associates, Cincinnati, OH (United States)

    1998-01-01T23:59:59.000Z

    The fundamental principles of high temperature water (HTW) system technology and its advantages for thermal energy distribution are presented. Misconceptions of this technology are also addressed. The paper describes design principles, applications, HTW properties, HTW system advantages, selecting the engineer, load diversification, design temperatures, system pressurization, pump considerations, constant vs. VS pumps, HTW generator types, and burners and controls.

  11. High Temperature Gas Reactors Briefing to

    E-Print Network [OSTI]

    Meltdown-Proof Advanced Reactor and Gas Turbine #12;TRISO Fuel Particle -- "Microsphere" · 0.9mm diameter · Utilizes gas turbine technology · Lower Power Density · Less Complicated Design (No ECCS) #12;AdvantagesHigh Temperature Gas Reactors Briefing to by Andrew C. Kadak, Ph.D. Professor of the Practice

  12. QED3 Theory of High Temperature Superconductors

    E-Print Network [OSTI]

    Tesanovic, Zlatko

    QED3 Theory of High Temperature Superconductors Zlatko Tesanovi´c The Johns Hopkins University-wave Superconductor to Antiferromagnet via Strange Metal #12;This talk is based on: M. Franz and ZT, Phys. Rev. Lett is The Problem in high Tc superconductors? · Superconducting state appears dx2-y2 "BCS-like". Low energy

  13. Advanced Converter Systems for High Temperature Environments

    Broader source: Energy.gov (indexed) [DOE]

    500 1000 1500 2000 2500 Voltage (Volts) Current (nA) . 4.0 Resistance (mOhms) 3.5 3.0 2.5 2.0 1.5 0 20 40 60 80 100 Current (Amps) High temperature package voltage breakdown and...

  14. High Temperature Materials Interim Data Qualification Report

    SciTech Connect (OSTI)

    Nancy Lybeck

    2010-08-01T23:59:59.000Z

    ABSTRACT Projects for the very high temperature reactor (VHTR) Technology Development Office provide data in support of Nuclear Regulatory Commission licensing of the VHTR. Fuel and materials to be used in the reactor are tested and characterized to quantify performance in high temperature and high fluence environments. The VHTR program has established the NGNP Data Management and Analysis System (NDMAS) to ensure that VHTR data are qualified for use, stored in a readily accessible electronic form, and analyzed to extract useful results. This document focuses on the first NDMAS objective. It describes the High Temperature Materials characterization data stream, the processing of these data within NDMAS, and reports the interim FY2010 qualification status of the data. Data qualification activities within NDMAS for specific types of data are determined by the data qualification category assigned by the data generator. The High Temperature Materials data are being collected under NQA-1 guidelines, and will be qualified data. For NQA-1 qualified data, the qualification activities include: (1) capture testing, to confirm that the data stored within NDMAS are identical to the raw data supplied, (2) accuracy testing to confirm that the data are an accurate representation of the system or object being measured, and (3) documenting that the data were collected under an NQA-1 or equivalent Quality Assurance program. Currently, data from two test series within the High Temperature Materials data stream have been entered into the NDMAS vault: 1. Tensile Tests for Sm (i.e., Allowable Stress) Confirmatory Testing – 1,403,994 records have been inserted into the NDMAS database. Capture testing is in process. 2. Creep-Fatigue Testing to Support Determination of Creep-Fatigue Interaction Diagram – 918,854 records have been processed and inserted into the NDMAS database. Capture testing is in process.

  15. Hydrogen and Syngas Production from Biodiesel Derived Crude Glycerol

    E-Print Network [OSTI]

    Silvey, Luke

    2012-05-31T23:59:59.000Z

    Hydrogen and Syngas Production from Biodiesel Derived Crude Glycerol By Copyright 2011 Luke Grantham Silvey Submitted to the graduate degree program in the Chemical and Petroleum Program, School of Engineering and the Graduate Faculty...D ________________________________ Christopher Depcik , PhD Date Defended: December 15, 2011 ii The Thesis Committee for Luke Grantham Silvey certifies that this is the approved version of the following thesis: Hydrogen and Syngas Production from Biodiesel Derived Crude...

  16. High Temperature Fuel Cells in the European Union

    Broader source: Energy.gov [DOE]

    Presentation on High Temperature Fuel Cells in the European Union to the High Temperature Membrane Working Group, May 25, 2004 in Philadelphia, PA.

  17. High-Temperature Water Splitting | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Temperature Water Splitting High-Temperature Water Splitting High-temperature water splitting (a "thermochemical" process) is a long-term technology in the early stages of...

  18. Possible Origin of Improved High Temperature Performance of Hydrotherm...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Origin of Improved High Temperature Performance of Hydrothermally Aged CuBeta Zeolite Catalysts. Possible Origin of Improved High Temperature Performance of Hydrothermally Aged...

  19. Institute of Chemical Engineering and High Temperature Chemical...

    Open Energy Info (EERE)

    Institute of Chemical Engineering and High Temperature Chemical Processes ICEHT Jump to: navigation, search Name: Institute of Chemical Engineering and High Temperature Chemical...

  20. A High Temperature Direct Vehicle Exhaust Flowmeter for Heavy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A High Temperature Direct Vehicle Exhaust Flowmeter for Heavy Duty Diesel Emission Measurements. A High Temperature Direct Vehicle Exhaust Flowmeter for Heavy Duty Diesel Emission...

  1. High-Temperature, Air-Cooled Traction Drive Inverter Packaging...

    Broader source: Energy.gov (indexed) [DOE]

    High-Temperature, Air-Cooled Traction Drive Inverter Packaging High-Temperature, Air-Cooled Traction Drive Inverter Packaging 2010 DOE Vehicle Technologies and Hydrogen Programs...

  2. Vehicle Technologies Office Merit Review 2014: High-Temperature...

    Broader source: Energy.gov (indexed) [DOE]

    High-Temperature Air-Cooled Power Electronics Thermal Design Vehicle Technologies Office Merit Review 2014: High-Temperature Air-Cooled Power Electronics Thermal Design...

  3. Development of a 500 Watt High Temperature Thermoelectric Generator

    Broader source: Energy.gov (indexed) [DOE]

    * TEG thermal and electrical interfaces modified to withstand high temperature environment 8 5 August, 2009 Deer 2009 9 100 Watt High Temperature TEG 100 Watt High...

  4. Development of a 100-Watt High Temperature Thermoelectric Generator

    Broader source: Energy.gov (indexed) [DOE]

    performance TEG thermal and electrical interfaces modified to withstand high temperature environment Development of a 100 watt High Temperature TE Generator DEER 2008 11 Prototype...

  5. Nanostructured High-Temperature Bulk Thermoelectric Energy Conversion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Temperature Bulk Thermoelectric Energy Conversion for Efficient Automotive Waste Heat Recovery Nanostructured High-Temperature Bulk Thermoelectric Energy Conversion for...

  6. Low and high Temperature Dual Thermoelectric Generation Waste...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and high Temperature Dual Thermoelectric Generation Waste Heat Recovery System for Light-Duty Vehicles Low and high Temperature Dual Thermoelectric Generation Waste Heat Recovery...

  7. Rotational Rehybridization and the High Temperature Phase of...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rotational Rehybridization and the High Temperature Phase of UC2. Rotational Rehybridization and the High Temperature Phase of UC2. Abstract: The screened hybrid approximation...

  8. High Temperature Thin Film Polymer Dielectric Based Capacitors...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Temperature Thin Film Polymer Dielectric Based Capacitors for HEV Power Electronic Systems High Temperature Thin Film Polymer Dielectric Based Capacitors for HEV Power...

  9. Development of Advanced High Temperature Fuel Cell Membranes

    Broader source: Energy.gov [DOE]

    Presentation on Development of Advanced High Temperature Fuel Cell Membranes to the High Temperature Membrane Working Group Meeting held in Arlington, Virginia, May 26,2005.

  10. High Temperature Polymer Membrane Development at Argonne National Laboratory

    Broader source: Energy.gov [DOE]

    Summary of ANL’s high temperature polymer membrane work presented to the High Temperature Membrane Working Group Meeting, Orlando FL, October 17, 2003

  11. High Temperature Thermal Array for Next Generation Solar Thermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Temperature Thermal Array for Next Generation Solar Thermal Power Production High Temperature Thermal Array for Next Generation Solar Thermal Power Production This...

  12. Cooling Strategies for Vane Leading Edges in a Syngas Environment Including Effects of Deposition and Turbulence

    SciTech Connect (OSTI)

    Ames, Forrest; Bons, Jeffrey

    2014-09-30T23:59:59.000Z

    The Department of Energy has goals to move land based gas turbine systems to alternate fuels including coal derived synthetic gas and hydrogen. Coal is the most abundant energy resource in the US and in the world and it is economically advantageous to develop power systems which can use coal. Integrated gasification combined cycles are (IGCC) expected to allow the clean use of coal derived fuels while improving the ability to capture and sequester carbon dioxide. These cycles will need to maintain or increase turbine entry temperatures to develop competitive efficiencies. The use of coal derived syngas introduces a range of potential contaminants into the hot section of the gas turbine including sulfur, iron, calcium, and various alkali metals. Depending on the effectiveness of the gas clean up processes, there exists significant likelihood that the remaining materials will become molten in the combustion process and potentially deposit on downstream turbine surfaces. Past evidence suggests that deposition will be a strong function of increasing temperature. Currently, even with the best gas cleanup processes a small level of particulate matter in the syngas is expected. Consequently, particulate deposition is expected to be an important consideration in the design of turbine components. The leading edge region of first stage vanes most often have higher deposition rates than other areas due to strong fluid acceleration and streamline curvature in the vicinity of the surface. This region remains one of the most difficult areas in a turbine nozzle to cool due to high inlet temperatures and only a small pressure ratio for cooling. The leading edge of a vane often has relatively high heat transfer coefficients and is often cooled using showerhead film cooling arrays. The throat of the first stage nozzle is another area where deposition potentially has a strongly adverse effect on turbine performance as this region meters the turbine inlet flow. Based on roughness levels found on in service vanes (Bons, et al., 2001, up to 300 microns) flow blockage in first stage turbine nozzles can easily reach 1 to 2 percent in conventional turbines. Deposition levels in syngas fueled gas turbines are expected to be even more problematic. The likelihood of significant deposition to the leading edge of vanes in a syngas environment indicates the need to examine this effect on the leading edge cooling problem. It is critical to understand the influence of leading edge geometry and turbulence on deposition rates for both internally and showerhead cooled leading edge regions. The expected level of deposition in a vane stagnation region not only significantly changes the heat transfer problem but also suggests that cooling arrays may clog. Addressing the cooling issue suggests a need to better understand stagnation region heat transfer with realistic roughness as well as the other variables affecting transport near the leading edge. Also, the question of whether leading edge regions can be cooled internally with modern cooling approaches should also be raised, thus avoiding the clogging issue. Addressing deposition in the pressure side throat region of the nozzle is another critical issue for this environment. Issues such as examining the protective effect of slot and full coverage discrete-hole film cooling on limiting deposition as well as the influence of roughness and turbulence on effectiveness should be raised. The objective of this present study is to address these technical challenges to help enable the development of high efficiency syngas tolerant gas turbine engines.

  13. Corrosion Resistant Coatings for High Temperature Applications

    SciTech Connect (OSTI)

    Besman, T.M.; Cooley, K.M.; Haynes, J.A.; Lee, W.Y.; Vaubert, V.M.

    1998-12-01T23:59:59.000Z

    Efforts to increase efficiency of energy conversion devices have required their operation at ever higher temperatures. This will force the substitution of higher-temperature structural ceramics for lower temperature materials, largely metals. Yet, many of these ceramics will require protection from high temperature corrosion caused by combustion gases, atmospheric contaminants, or the operating medium. This paper discusses examples of the initial development of such coatings and materials for potential application in combustion, aluminum smelting, and other harsh environments.

  14. Thermal fuse for high-temperature batteries

    DOE Patents [OSTI]

    Jungst, Rudolph G. (Albuquerque, NM); Armijo, James R. (Albuquerque, NM); Frear, Darrel R. (Austin, TX)

    2000-01-01T23:59:59.000Z

    A thermal fuse, preferably for a high-temperature battery, comprising leads and a body therebetween having a melting point between approximately 400.degree. C. and 500.degree. C. The body is preferably an alloy of Ag--Mg, Ag--Sb, Al--Ge, Au--In, Bi--Te, Cd--Sb, Cu--Mg, In--Sb, Mg--Pb, Pb--Pd, Sb--Zn, Sn--Te, or Mg--Al.

  15. High temperature hot water distribution system study

    SciTech Connect (OSTI)

    NONE

    1996-12-01T23:59:59.000Z

    The existing High Temperature Hot Water (HTHW) Distribution System has been plagued with design and construction deficiencies since startup of the HTHW system, in October 1988. In October 1989, after one year of service, these deficiencies were outlined in a technical evaluation. The deficiencies included flooded manholes, sump pumps not hooked up, leaking valves, contaminated HTHW water, and no cathodic protection system. This feasibility study of the High Temperature Hot Water (HTHW) Distribution System was performed under Contract No. DACA0l-94-D-0033, Delivery Order 0013, Modification 1, issued to EMC Engineers, Inc. (EMC), by the Norfolk District Corps of Engineers, on 25 April 1996. The purpose of this study was to determine the existing conditions of the High Temperature Hot Water Distribution System, manholes, and areas of containment system degradation. The study focused on two areas of concern, as follows: * Determine existing conditions and areas of containment system degradation (leaks) in the underground carrier pipes and protective conduit. * Document the condition of underground steel and concrete manholes. To document the leaks, a site survey was performed, using state-of-the-art infrared leak detection equipment and tracer gas leak detection equipment. To document the condition of the manholes, color photographs were taken of the insides of 125 manholes, and notes were made on the condition of these manholes.

  16. Cleanup Sites | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE: Alternative FuelsNovember 13, 2014 BuildingEnergy Efficiency and Renewable Energy |Sites Cleanup

  17. A HIGH TEMPERATURE GAS RECEIVER UTILIZING SMALL PARTICLES

    E-Print Network [OSTI]

    Hunt, Arlon

    2012-01-01T23:59:59.000Z

    field of high temperature solar process heat. The ultimateof solar applications including industrial process heat and

  18. Ethanol synthesis from syngas over Rh-based/SiO2 catalysts: A...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    synthesis from syngas over Rh-basedSiO2 catalysts: A combined experimental and theoretical modeling study. Ethanol synthesis from syngas over Rh-basedSiO2 catalysts: A combined...

  19. The Role of Ir in Ternary Rh-Based Catalysts for Syngas Conversion...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Role of Ir in Ternary Rh-Based Catalysts for Syngas Conversion to C2+ Oxygenates. The Role of Ir in Ternary Rh-Based Catalysts for Syngas Conversion to C2+ Oxygenates....

  20. MODELING AND ANALYSIS OF CHEMILUMINESCENCE SENSING FOR SYNGAS, METHANE AND JET-A COMBUSTION

    E-Print Network [OSTI]

    Seitzman, Jerry M.

    MODELING AND ANALYSIS OF CHEMILUMINESCENCE SENSING FOR SYNGAS, METHANE AND JET-A COMBUSTION of Technology August 2008 #12;MODELING AND ANALYSIS OF CHEMILUMINESCENCE SENSING FOR SYNGAS, METHANE AND JET

  1. Syngas Conversion to Gasoline-Range Hydrocarbons over Pd/ZnO...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Syngas Conversion to Gasoline-Range Hydrocarbons over PdZnOAl2O3 and ZSM-5 Composite Catalyst System. Syngas Conversion to Gasoline-Range Hydrocarbons over PdZnOAl2O3 and ZSM-5...

  2. PERSPECTIVES OF HIGH TEMPERATURE ELECTROLYSIS USING S. H. JENSEN and M. MOGENSEN

    E-Print Network [OSTI]

    dioxide results in a mixture of hydrogen and carbon monoxide (syngas). A number of other carbon energy carriers may be produced from syngas. The two simplest are methanol and methane, but also gasoline may of hydrogen and carbon monoxide called syngas. By catalytic reactions a number of other energy carriers may

  3. Synthesis of Methanol and Dimethyl Ether from Syngas over Pd/ZnO/Al2O3 Catalysts

    SciTech Connect (OSTI)

    Lebarbier, Vanessa MC; Dagle, Robert A.; Kovarik, Libor; Lizarazo Adarme, Jair A.; King, David L.; Palo, Daniel R.

    2012-10-01T23:59:59.000Z

    A Pd/ZnO/Al2O3 catalyst was developed for the synthesis of methanol and dimethyl ether (DME) from syngas. Studied were temperatures of operation ranging from 250°C to 380°C. High temperatures (e.g. 380°C) are necessary when combining methanol and DME synthesis with a methanol to gasoline (MTG) process in a single reactor bed. A commercial Cu/ZnO/Al2O3 catalyst, utilized industrially for the synthesis of methanol at 220-280°C, suffers from a rapid deactivation when the reaction is conducted at high temperature (>320°C). On the contrary, a Pd/ZnO/Al2O3 catalyst was found to be highly stable for methanol and DME synthesis at 380°C. The Pd/ZnO/Al2O3 catalyst was thus further investigated for methanol and DME synthesis at P=34-69 bars, T= 250-380°C, GHSV= 5 000-18 000 h-1, and molar feeds H2/CO= 1, 2, and 3. Selectivity to DME increased with decreasing operating temperature, and increasing operating pressure. Increased GHSV’s and H2/CO syngas feed ratios also enhanced DME selectivity. Undesirable CH4 formation was observed, however, can be minimized through choice of process conditions and by catalyst design. By studying the effect of the Pd loading and the Pd:Zn molar ratio the formulation of the Pd/ZnO/Al2O3 catalyst was optimized. A catalyst with 5% Pd and a Pd:Zn molar ratio of 0.25:1 has been identified as the preferred catalyst. Results indicate that PdZn particles are more active than Pdş particles for the synthesis of methanol and less active for CH4 formation. A correlation between DME selectivity and the concentration of acid sites of the catalysts has been established. Hence, two types of sites are required for the direct conversion of syngas to DME: 1) PdZn particles are active for the synthesis of methanol from syngas, and 2) acid sites which are active for the conversion of methanol to DME. Additionally, CO2 formation was problematic as PdZn was found to be active for the water-gas-shift (WGS) reaction, under all the conditions evaluated.

  4. High temperature regenerable hydrogen sulfide removal agents

    DOE Patents [OSTI]

    Copeland, Robert J. (Wheat Ridge, CO)

    1993-01-01T23:59:59.000Z

    A system for high temperature desulfurization of coal-derived gases using regenerable sorbents. One sorbent is stannic oxide (tin oxide, SnO.sub.2), the other sorbent is a metal oxide or mixed metal oxide such as zinc ferrite (ZnFe.sub.2 O.sub.4). Certain otherwise undesirable by-products, including hydrogen sulfide (H.sub.2 S) and sulfur dioxide (SO.sub.2) are reused by the system, and elemental sulfur is produced in the regeneration reaction. A system for refabricating the sorbent pellets is also described.

  5. High Temperature Materials Laboratory third annual report

    SciTech Connect (OSTI)

    Tennery, V.J.; Foust, F.M.

    1990-12-01T23:59:59.000Z

    The High Temperature Materials Laboratory has completed its third year of operation as a designated DOE User Facility at the Oak Ridge National Laboratory. Growth of the user program is evidenced by the number of outside institutions who have executed user agreements since the facility began operation in 1987. A total of 88 nonproprietary agreements (40 university and 48 industry) and 20 proprietary agreements (1 university, 19 industry) are now in effect. Sixty-eight nonproprietary research proposals (39 from university, 28 from industry, and 1 other government facility) and 8 proprietary proposals were considered during this reporting period. Research projects active in FY 1990 are summarized.

  6. Modeling forces in high-temperature superconductors

    SciTech Connect (OSTI)

    Turner, L. R.; Foster, M. W.

    1997-11-18T23:59:59.000Z

    We have developed a simple model that uses computed shielding currents to determine the forces acting on a high-temperature superconductor (HTS). The model has been applied to measurements of the force between HTS and permanent magnets (PM). Results show the expected hysteretic variation of force as the HTS moves first toward and then away from a permanent magnet, including the reversal of the sign of the force. Optimization of the shielding currents is carried out through a simulated annealing algorithm in a C++ program that repeatedly calls a commercial electromagnetic software code. Agreement with measured forces is encouraging.

  7. High-temperature directional drilling turbodrill

    SciTech Connect (OSTI)

    Neudecker, J.W.; Rowley, J.C.

    1982-02-01T23:59:59.000Z

    The development of a high-temperature turbodrill for directional drilling of geothermal wells in hard formations is summarized. The turbodrill may be used for straight-hole drilling but was especially designed for directional drilling. The turbodrill was tested on a dynamometer stand, evaluated in laboratory drilling into ambient temperature granite blocks, and used in the field to directionally drill a 12-1/4-in.-diam geothermal well in hot 200/sup 0/C (400/sup 0/F) granite at depths to 10,5000 ft.

  8. German engineers study UMTRA cleanup programs

    SciTech Connect (OSTI)

    Not Available

    1994-01-01T23:59:59.000Z

    Two environmental engineers from Germany's WISMUT, the organization responsible for uranium tailings cleanup in that country, recently completed extensive training as part of a technology transfer program at the US DOE. For six weeks the two engineers studied the practices employed in the cleanup of the DOE's UMTRA (Uranium Mill Tailings Remedial Action) sites, hoping to gain insight into how Germany's own cleanup program should proceed.

  9. HANFORD SITE CENTRAL PLATEAU CLEANUP COMPLETION STRATEGY

    SciTech Connect (OSTI)

    BERGMAN TB

    2011-01-14T23:59:59.000Z

    Cleanup of the Hanford Site is a complex and challenging undertaking. The U.S. Department of Energy (DOE) has developed a comprehensive vision for completing Hanford's cleanup mission including transition to post-cleanup activities. This vision includes 3 principle components of cleanup: the {approx}200 square miles ofland adjacent to the Columbia River, known as the River Corridor; the 75 square miles of land in the center of the Hanford Site, where the majority of the reprocessing and waste management activities have occurred, known as the Central Plateau; and the stored reprocessing wastes in the Central Plateau, the Tank Wastes. Cleanup of the River Corridor is well underway and is progressing towards completion of most cleanup actions by 2015. Tank waste cleanup is progressing on a longer schedule due to the complexity of the mission, with construction of the largest nuclear construction project in the United States, the Waste Treatment Plant, over 50% complete. With the progress on the River Corridor and Tank Waste, it is time to place increased emphasis on moving forward with cleanup of the Central Plateau. Cleanup of the Hanford Site has been proceeding under a framework defmed in the Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement). In early 2009, the DOE, the State of Washington Department of Ecology, and the U.S. Environmental Protection Agency signed an Agreement in Principle in which the parties recognized the need to develop a more comprehensive strategy for cleanup of the Central Plateau. DOE agreed to develop a Central Plateau Cleanup Completion Strategy as a starting point for discussions. This DOE Strategy was the basis for negotiations between the Parties, discussions with the State of Oregon, the Hanford Advisory Board, and other Stakeholder groups (including open public meetings), and consultation with the Tribal Nations. The change packages to incorporate the Central Plateau Cleanup Completion Strategy were signed by the Parties on October 26,2010, and are now in the process of being implemented.

  10. Hot-gas cleanup system model development. Volume I. Final report

    SciTech Connect (OSTI)

    Ushimaru, K.; Bennett, A.; Bekowies, P.J.

    1982-11-01T23:59:59.000Z

    This two-volume report summarizes the state of the art in performance modeling of advanced high-temperature, high-pressure (HTHP) gas cleanup devices. Volume I contains the culmination of the research effort carried over the past 12 months and is a summary of research achievements. Volume II is the user's manual for the computer programs developed under the present research project. In this volume, Section 2 presents background information on pressurized, fluidized-bed combustion concepts, a description of the role of the advanced gas cleanup systems, and a list of advanced gas cleanup systems that are currently in development under DOE sponsorship. Section 3 describes the methodology for the software architecture that forms the basis of the well-disciplined and structured computer programs developed under the present project. Section 4 reviews the fundamental theories that are important in analyzing the cleanup performance of HTHP gas filters. Section 5 discusses the effect of alkali agents in HTHP gas cleanup. Section 6 evaluates the advanced HTHP gas cleanup models based on their mathematical integrity, availability of supporting data, and the likelihood of commercialization. As a result of the evaluation procedure detailed in Section 6, five performance models were chosen to be incorporated into the overall system simulation code, ASPEN. These five models (the electrocyclone, ceramic bag filter, moving granular bed filter, electrostatic granular bed filter, and electrostatic precipitator) are described in Section 7. The method of cost projection for these five models is discussed in Section 8. The supporting data and validation of the computer codes are presented in Section 9, and finally the conclusions and recommendations for the HTHP gas cleanup system model development are given in Section 10. 72 references, 19 figures, 25 tables.

  11. NOx emission characteristics of counterflow syngas diffusion flames with airstream dilution

    E-Print Network [OSTI]

    Aggarwal, Suresh K.

    NOx emission characteristics of counterflow syngas diffusion flames with airstream dilution Daniel Abstract Syngas is produced through a gasification process using variety of fossil fuels, including coal. Due to its wide flexibility in fuel sources and superior pollutants characteristics, the syngas

  12. A numerical and experimental study of counterflow syngas flames at different pressures

    E-Print Network [OSTI]

    Aggarwal, Suresh K.

    A numerical and experimental study of counterflow syngas flames at different pressures S. Som, A Synthesis gas or ``Syngas'' is being recognized as a viable energy source worldwide, particularly. There are, however, gaps in the fundamental understanding of syngas combustion and emissions characteristics

  13. ITM Syngas and ITM H2: Engineering Development of Ceramic Membrane Reactor Systems for

    E-Print Network [OSTI]

    ITM Syngas and ITM H2: Engineering Development of Ceramic Membrane Reactor Systems for Converting (U.S. DOE) and other members of the ITM Syngas/ITM H2 Team, is developing Ion Transport Membrane (ITM-scale centralized hydrogen production facilities with CO2 capture. The major goals of the ITM Syngas and ITM H2

  14. Syngas Production from Propane using Atmospheric Non-Thermal Plasma F. Ouni, A. Khacef*

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Syngas Production from Propane using Atmospheric Non-Thermal Plasma F. Ouni, A. Khacef* and J. M applications (1, 2) . Synthesis gas or syngas (mixture of hydrogen and carbon monoxide) are used as a major. The conventional reformers allowing syngas production are based on steam reforming of hydrocarbons (3) following

  15. Ab initio screening of metal sorbents for elemental mercury capture in syngas streams

    E-Print Network [OSTI]

    Ceder, Gerbrand

    Ab initio screening of metal sorbents for elemental mercury capture in syngas streams Anubhav Jain to produce a combustible syngas, a mixture of carbon monoxide and hydrogen gas. Power plants incorporating prior to combustion, i.e. in the pre-combustion syngas mixture rather than the flue gas; as such

  16. Bayesian methods for the quantification of uncertainties in syngas chemistry models

    E-Print Network [OSTI]

    Raman, Venkat

    Bayesian methods for the quantification of uncertainties in syngas chemistry models Kalen Braman, Todd Oliver and Venkat Raman, The University of Texas, Austin, Texas, 78712 Syngas chemistry modeling is an integral step toward the development of safe and ef- ficient syngas combustors. Although substantial effort

  17. Sandia National Laboratories: radiation waste cleanup

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    waste cleanup ECIS and UOP (a Honewell Company): CSTs Clean Radioactive Waste in Fukushima and Worldwide On February 14, 2013, in Energy, Materials Science, Nuclear Energy,...

  18. Sandia National Laboratories: radioactive waste solution cleanup

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    solution cleanup ECIS and UOP (a Honewell Company): CSTs Clean Radioactive Waste in Fukushima and Worldwide On February 14, 2013, in Energy, Materials Science, Nuclear Energy,...

  19. High temperature intermetallic binders for HVOF carbides

    SciTech Connect (OSTI)

    Shaw, K.G. [Xform, Inc., Cohoes, NY (United States); Gruninger, M.F.; Jarosinski, W.J. [Praxair Specialty Powders, Indianapolis, IN (United States)

    1994-12-31T23:59:59.000Z

    Gas turbines technology has a long history of employing the desirable high temperature physical attributes of ceramic-metallic (cermet) materials. The most commonly used coatings incorporate combinations of WC-Co and Cr{sub 3}C{sub 2}-NiCr, which have also been successfully utilized in other non-turbine coating applications. Increased turbine operating temperatures and other high temperature service conditions have made apparent the attractive notion of increasing the temperature capability and corrosion resistance of these coatings. In this study the intermetallic binder NiAl has been used to replace the cobalt and NiCr constituents of conventional WC and Cr{sub 3}C{sub 2} cermet powders. The composite carbide thermal spray powders were fabricated for use in the HVOF coating process. The structure of HVOF deposited NiAl-carbide coatings are compared directly to the more familiar WC-Co and Cr{sub 3}C{sub 2}-NiCr coatings using X-ray diffraction, back-scattered electron imaging (BEI) and electron dispersive spectroscopy (EDS). Hardness variations with temperature are reported and compared between the NiAl and Co/NiCr binders.

  20. Method for regeneration and activity improvement of syngas conversion catalyst

    DOE Patents [OSTI]

    Lucki, Stanley J. (Runnemede, NJ); Brennan, James A. (Cherry Hill, NJ)

    1980-01-01T23:59:59.000Z

    A method is disclosed for the treatment of single particle iron-containing syngas (synthes.s gas) conversion catalysts comprising iron, a crystalline acidic aluminosilicate zeolite having a silica to alumina ratio of at least 12, a pore size greater than about 5 Angstrom units and a constraint index of about 1-12 and a matrix. The catalyst does not contain promoters and the treatment is applicable to either the regeneration of said spent single particle iron-containing catalyst or for the initial activation of fresh catalyst. The treatment involves air oxidation, hydrogen reduction, followed by a second air oxidation and contact of the iron-containing single particle catalyst with syngas prior to its use for the catalytic conversion of said syngas. The single particle iron-containing catalysts are prepared from a water insoluble organic iron compound.

  1. Site Cleanup | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO Overview OCHCO OverviewRepositoryManagement | Department of EnergyShaneShawnCleanup

  2. AOI [3] High-Temperature Nano-Derived Micro-H2 and - H2S Sensors

    SciTech Connect (OSTI)

    Perepezko, John; Lu-Steffes, Otto

    2014-08-31T23:59:59.000Z

    The emissions from coal-fired power plants remain a significant concern for air quality. This environmental challenge must be overcome by controlling the emission of sulfur dioxide (SO2) and hydrogen sulfide (H2S) throughout the entire coal combustion process. One of the processes which could specifically benefit from robust, low cost, and high temperature compatible gas sensors is the coal gasification process which converts coal and/or biomass into syngas. Hydrogen (H2), carbon monoxide (CO) and sulfur compounds make up 33%, 43% and 2% of syngas, respectively. Therefore, development of a high temperature (>500°C) chemical sensor for in-situ monitoring of H2, H2S and SO2 levels during coal gasification is strongly desired. The selective detection of SO2/H2S in the presence of H2, is a formidable task for a sensor designer. In order to ensure effective operation of these chemical sensors, the sensor system must inexpensively function within harsh temperature and chemical environment. Currently available sensing approaches, which are based on gas chromatography, electrochemistry, and IR-spectroscopy, do not satisfy the required cost and performance targets. This work focused on the development microsensors that can be applied to this application. In order to develop the high- temperature compatible microsensor, this work addressed various issues related to sensor stability, selectivity, and miniaturization. In the research project entitled “High-Temperature Nano-Derived Micro-H2 and -H2S Sensors”, the team worked to develop micro-scale, chemical sensors and sensor arrays composed of nano-derived, metal-oxide composite materials to detect gases like H2, SO2, and H2S within high-temperature environments (>500?C). The research was completed in collaboration with NexTech Materials, Ltd. (Lewis Center, Ohio). NexTech assisted in the testing of the sensors in syngas with contaminate levels of H2S. The idea of including nanomaterials as the sensing material within resistive-type chemical sensor platforms was to increase the sensitivity (as shown for room temperature applications). Unfortunately, nanomaterials are not stable at high temperatures due to sintering and coarsening processes that are driven by their high surface to volume ratio. Therefore, new hydrogen and sulfur selective nanomaterial systems with high selectivity and stability properties in the proposed harsh environment were investigated. Different nano-morphologies of zirconate, molybdate, and tungstate compounds were investigated. The fabrication of the microsensors consisted of the deposition of the selective nanomaterial systems over metal based interconnects on an inert substrate. This work utilized the chemi-resistive (resistive- type) microsensor architecture where the chemically and structurally stable, high temperature compatible electrodes were sputtered onto a ceramic substrate. The nanomaterial sensing systems were deposited over the electrodes using a lost mold method patterned by conventional optical lithography. The microsensor configuration with optimized nanomaterial system was tested and compared to a millimeter-size sensor e outcomes of this research will contribute to the economical application of sensor arrays for simultaneous sensing of H2, H2S, and SO2.

  3. Reducing PM Concentrations in Simulated High Temperature Gas Streams

    E-Print Network [OSTI]

    Luehrs, Daniel R

    2014-08-07T23:59:59.000Z

    the reaction temperatures and capture the energy in the biomass. CGT has an approximant 16,300 kJ/kg (7,000 Btu/lb) of energy. The resulting synthetic gas (syngas) can have an energy content as high as 7,450 kJ/m^(3) (200 Btu/dscf) and can be fed directly...

  4. High temperature coatings for gas turbines

    DOE Patents [OSTI]

    Zheng, Xiaoci Maggie

    2003-10-21T23:59:59.000Z

    Coating for high temperature gas turbine components that include a MCrAlX phase, and an aluminum-rich phase, significantly increase oxidation and cracking resistance of the components, thereby increasing their useful life and reducing operating costs. The aluminum-rich phase includes aluminum at a higher concentration than aluminum concentration in the MCrAlX alloy, and an aluminum diffusion-retarding composition, which may include cobalt, nickel, yttrium, zirconium, niobium, molybdenum, rhodium, cadmium, indium, cerium, iron, chromium, tantalum, silicon, boron, carbon, titanium, tungsten, rhenium, platinum, and combinations thereof, and particularly nickel and/or rhenium. The aluminum-rich phase may be derived from a particulate aluminum composite that has a core comprising aluminum and a shell comprising the aluminum diffusion-retarding composition.

  5. Thermochemistry of high-temperature corrosion

    SciTech Connect (OSTI)

    Natesan, K.

    1980-01-01T23:59:59.000Z

    Multicomponent gas environments are prevalent in a number of energy systems, especially in those that utilize fossil fuels. The gas environments in these processes contain sulfur-bearing components in addition to oxidants. These complex environments, coupled with the elevated temperatures present in these systems, generally cause significant corrosion of engineering materials. Thermodynamic aspects of high-temperature corrosion processes occuring in complex gas mixtures are discussed, with emphasis on the role of thermochemical diagrams. The interrelationships between the corrosion behavior of materials and gas composition, alloy chemistry, and temperatures are examined. A number of examples from studies on materials behavior in coal-gasification environments are used to elucidate the role of thermochemistry in the understanding of corrosion processes that occur in complex gas mixtures. 11 figures.

  6. Turbine vane with high temperature capable skins

    DOE Patents [OSTI]

    Morrison, Jay A. (Oviedo, FL)

    2012-07-10T23:59:59.000Z

    A turbine vane assembly includes an airfoil extending between an inner shroud and an outer shroud. The airfoil can include a substructure having an outer peripheral surface. At least a portion of the outer peripheral surface is covered by an external skin. The external skin can be made of a high temperature capable material, such as oxide dispersion strengthened alloys, intermetallic alloys, ceramic matrix composites or refractory alloys. The external skin can be formed, and the airfoil can be subsequently bi-cast around or onto the skin. The skin and the substructure can be attached by a plurality of attachment members extending between the skin and the substructure. The skin can be spaced from the outer peripheral surface of the substructure such that a cavity is formed therebetween. Coolant can be supplied to the cavity. Skins can also be applied to the gas path faces of the inner and outer shrouds.

  7. High temperature low friction surface coating

    DOE Patents [OSTI]

    Bhushan, Bharat (Watervliet, NY)

    1980-01-01T23:59:59.000Z

    A high temperature, low friction, flexible coating for metal surfaces which are subject to rubbing contact includes a mixture of three parts graphite and one part cadmium oxide, ball milled in water for four hours, then mixed with thirty percent by weight of sodium silicate in water solution and a few drops of wetting agent. The mixture is sprayed 12-15 microns thick onto an electro-etched metal surface and air dried for thirty minutes, then baked for two hours at 65.degree. C. to remove the water and wetting agent, and baked for an additional eight hours at about 150.degree. C. to produce the optimum bond with the metal surface. The coating is afterwards burnished to a thickness of about 7-10 microns.

  8. High Temperature Battery for Drilling Applications

    SciTech Connect (OSTI)

    Josip Caja

    2009-12-31T23:59:59.000Z

    In this project rechargeable cells based on the high temperature electrochemical system Na/beta''-alumina/S(IV) in AlCl3/NaCl were developed for application as an autonomous power source in oil/gas deep drilling wells. The cells operate in the temperature range from 150 C to 250 C. A prototype DD size cell was designed and built based on the results of finite element analysis and vibration testing. The cell consisted of stainless steel case serving as anode compartment with cathode compartment installed in it and a seal closing the cell. Critical element in cell design and fabrication was hermetically sealing the cell. The seal had to be leak tight, thermally and vibration stable and compatible with electrode materials. Cathode compartment was built of beta''-alumina tube which served as an electrolyte, separator and cathode compartment.

  9. High temperature insulation for ceramic matrix composites

    SciTech Connect (OSTI)

    Merrill, Gary B. (Monroeville, PA); Morrison, Jay Alan (Orlando, FL)

    2000-01-01T23:59:59.000Z

    A ceramic composition is provided to insulate ceramic matrix composites under high temperature, high heat flux environments. The composite comprises a plurality of hollow oxide-based spheres of varios dimentions, a phosphate binder, and at least one oxide filler powder, whereby the phosphate binder partially fills gaps between the spheres and the filler powders. The spheres are situated in the phosphate binder and the filler powders such that each sphere is in contact with at least one other sphere. The spheres may be any combination of Mullite spheres, Alumina spheres, or stabilized Zirconia spheres. The filler powder may be any combination of Alumina, Mullite, Ceria, or Hafnia. Preferably, the phosphate binder is Aluminum Ortho-Phosphate. A method of manufacturing the ceramic insulating composition and its application to CMC substates are also provided.

  10. High temperature insulation for ceramic matrix composites

    DOE Patents [OSTI]

    Merrill, Gary B.; Morrison, Jay Alan

    2004-01-13T23:59:59.000Z

    A ceramic composition is provided to insulate ceramic matrix composites under high temperature, high heat flux environments. The composition comprises a plurality of hollow oxide-based spheres of various dimensions, a phosphate binder, and at least one oxide filler powder, whereby the phosphate binder partially fills gaps between the spheres and the filler powders. The spheres are situated in the phosphate binder and the filler powders such that each sphere is in contact with at least one other sphere. The spheres may be any combination of Mullite spheres, Alumina spheres, or stabilized Zirconia spheres. The filler powder may be any combination of Alumina, Mullite, Ceria, or Hafnia. Preferably, the phosphate binder is Aluminum Ortho-Phosphate. A method of manufacturing the ceramic insulating composition and its application to CMC substrates are also provided.

  11. High temperature insulation for ceramic matrix composites

    SciTech Connect (OSTI)

    Merrill, Gary B. (Monroeville, PA); Morrison, Jay Alan (Orlando, FL)

    2001-01-01T23:59:59.000Z

    A ceramic composition is provided to insulate ceramic matrix composites under high temperature, high heat flux environments. The composition comprises a plurality of hollow oxide-based spheres of various dimensions, a phosphate binder, and at least one oxide filler powder, whereby the phosphate binder partially fills gaps between the spheres and the filler powders. The spheres are situated in the phosphate binder and the filler powders such that each sphere is in contact with at least one other sphere. The spheres may be any combination of Mullite spheres, Alumina spheres, or stabilized Zirconia spheres. The filler powder may be any combination of Alumina, Mullite, Ceria, or Hafnia. Preferably, the phosphate binder is Aluminum Ortho-Phosphate. A method of manufacturing the ceramic insulating composition and its application to CMC substrates are also provided.

  12. Multilayer ultra-high-temperature ceramic coatings

    DOE Patents [OSTI]

    Loehman, Ronald E. (Albuquerque, NM); Corral, Erica L. (Tucson, AZ)

    2012-03-20T23:59:59.000Z

    A coated carbon-carbon composite material with multiple ceramic layers to provide oxidation protection from ultra-high-temperatures, where if the carbon-carbon composite material is uninhibited with B.sub.4C particles, then the first layer on the composite material is selected from ZrB.sub.2 and HfB.sub.2, onto which is coated a layer of SiC coated and if the carbon-carbon composite material is inhibited with B.sub.4C particles, then protection can be achieved with a layer of SiC and a layer of either ZrB.sub.2 and HfB.sub.2 in any order.

  13. Novel polymer membrane process for pre-combustion CO{sub 2} capture from coal-fired syngas

    SciTech Connect (OSTI)

    Merkel, Tim [MTR Inc., Menlo Park, CA (United States)

    2011-09-14T23:59:59.000Z

    This final report describes work conducted for the Department of Energy (DOE NETL) on development of a novel polymer membrane process for pre-combustion CO{sub 2} capture from coalfired syngas (award number DE-FE0001124). The work was conducted by Membrane Technology and Research, Inc. (MTR) from September 15, 2009, through December 14, 2011. Tetramer Technologies, LLC (Tetramer) was our subcontract partner on this project. The National Carbon Capture Center (NCCC) at Wilsonville, AL, provided access to syngas gasifier test facilities. The main objective of this project was to develop a cost-effective membrane process that could be used in the relatively near-term to capture CO{sub 2} from shifted syngas generated by a coal-fired Integrated Gasification Combined Cycle (IGCC) power plant. In this project, novel polymeric membranes (designated as Proteus™ membranes) with separation properties superior to conventional polymeric membranes were developed. Hydrogen permeance of up to 800 gpu and H{sub 2}/CO{sub 2} selectivity of >12 was achieved using a simulated syngas mixture at 150°C and 50 psig, which exceeds the original project targets of 200 gpu for hydrogen permeance and 10 for H{sub 2}/CO{sub 2} selectivity. Lab-scale Proteus membrane modules (with a membrane area of 0.13 m{sup 2}) were also developed using scaled-up Proteus membranes and high temperature stable module components identified during this project. A mixed-gas hydrogen permeance of about 160 gpu and H{sub 2}/CO{sub 2} selectivity of >12 was achieved using a simulated syngas mixture at 150°C and 100 psig. We believe that a significant improvement in the membrane and module performance is likely with additional development work. Both Proteus membranes and lab-scale Proteus membrane modules were further evaluated using coal-derived syngas streams at the National Carbon Capture Center (NCCC). The results indicate that all module components, including the Proteus membrane, were stable under the field conditions (feed pressures: 150-175 psig and feed temperatures: 120-135°C) for over 600 hours. The field performance of both Proteus membrane stamps and Proteus membrane modules is consistent with the results obtained in the lab, suggesting that the presence of sulfur-containing compounds (up to 780 ppm hydrogen sulfide), saturated water vapor, carbon monoxide and heavy hydrocarbons in the syngas feed stream has no adverse effect on the Proteus membrane or module performance. We also performed an economic analysis for a number of membrane process designs developed in this project (using hydrogen-selective membranes, alone or in the combination with CO{sub 2}- selective membranes). The current field performance for Proteus membranes was used in the design analysis. The study showed the current best design has the potential to reduce the increase in Levelized Cost of Electricity (LCOE) caused by 90% CO{sub 2} capture to about 15% if co-sequestration of H{sub 2}S is viable. This value is still higher than the DOE target for increase in LCOE (10%); however, compared to the base-case Selexol process that gives a 30% increase in LCOE at 90% CO2 capture, the membrane-based process appears promising. We believe future improvements in membrane performance have the potential to reach the DOE target.

  14. Catalytic conversion of syngas into C2 oxygenates over Rh-based catalysts--Effect of carbon supports

    E-Print Network [OSTI]

    Bao, Xinhe

    Catalytic conversion of syngas into C2 oxygenates over Rh-based catalysts--Effect of carbon synthesis other than grain fermentation, e.g. from syngas, because syngas can be conveniently manufactured we first undertake a brief overview of the catalyst development for syngas conversion to C2

  15. High-Temperature Solar Selective Coating Development for Power...

    Broader source: Energy.gov (indexed) [DOE]

    High-Temperature Solar Selective Coating Development for Power Tower Receivers - FY13 Q1 High-Temperature Solar Selective Coating Development for Power Tower Receivers - FY13 Q1...

  16. High-Temperature Solar Selective Coating Development for Power...

    Broader source: Energy.gov (indexed) [DOE]

    High-Temperature Solar Selective Coating Development for Power Tower Receivers - FY13 Q2 High-Temperature Solar Selective Coating Development for Power Tower Receivers - FY13 Q2...

  17. Development of a High-Temperature Diagnostics-While-Drilling...

    Energy Savers [EERE]

    Development of a High-Temperature Diagnostics-While-Drilling Tool Development of a High-Temperature Diagnostics-While-Drilling Tool This report documents work performed in the...

  18. Corrosion Studies in High-Temperature Molten Salt Systems for...

    Broader source: Energy.gov (indexed) [DOE]

    Corrosion Studies in High-Temperature Molten Salt Systems for CSP Applications - FY13 Q1 Corrosion Studies in High-Temperature Molten Salt Systems for CSP Applications - FY13 Q1...

  19. Fundamental Corrosion Studies in High-Temperature Molten Salt...

    Broader source: Energy.gov (indexed) [DOE]

    Fundamental Corrosion Studies in High-Temperature Molten Salt Systems for Next-Generation CSP Systems - FY13 Q2 Fundamental Corrosion Studies in High-Temperature Molten Salt...

  20. Zero Emissions Coal Syngas Oxygen Turbo Machinery

    SciTech Connect (OSTI)

    Dennis Horazak

    2010-12-31T23:59:59.000Z

    Siemens Energy, Inc. (formerly Siemens Westinghouse Power Corporation) worked with Clean Energy Systems and Florida Turbine Technologies to demonstrate the commercial feasibility of advanced turbines for oxy-fuel based power systems that discharge negligible CO{sub 2} into the atmosphere. The approach builds upon ultra supercritical steam turbine and advanced gas turbine technology with the goal of attaining plant efficiencies above 50% in the 2015 timeframe. Conceptual designs were developed for baseline, near term, and long term oxy-fuel turbine cycles, representing commercial introductions of increasingly advanced thermal conditions and increasing exposure to steam-CO{sub 2} mixtures. An economic analysis and market demand study was performed by Science Applications International Corp. (SAIC), and indicated that long-term oxy-fuel turbine cycles start to look attractive in 2025 when the CO{sub 2} tax is assumed to reach $40/ ton, and by 2030 it has a clear advantage over both IGCC with sequestration and pulverized coal with sequestration. A separate risk analysis of the oxy-fuel combustor, HP turbine, re-heater, and IP turbine of the long-term cycle identified and categorized risks and proposed mitigation measures. In 2007 the program began to focus on a potential oxy-fuel turbine power generation demonstration project in the 2012 -13 time period while still maintaining a link to the requirements of the long-term oxy-syngas cycle. The SGT-900 turbine was identified as the best fit for modification into an intermediate pressure turbine (IPT) for this application. The base metals, bond coats, thermal barrier coatings (TBCs), and rotor materials used in the SGT-900 were tested for their ability to operate in the steam- CO{sub 2} environment of the oxy-fuel OFT-900. Test results indicated that these same materials would operate satisfactorily, and the plan, is to use SGT-900materials for the OFT-900. Follow-on programs for corrosion testing and evaluation of crack growth rates in oxy-fuel environments have been proposed to build on these results and provide quantifiable assessments of the effects of oxy-fuel environments on the service lives of turbine components.

  1. High Temperature Membrane Working Group Meeting, May 14, 2007

    Broader source: Energy.gov [DOE]

    This agenda provides information about the High Temperature Membrane Working Group Meeting on May 14, 2007 in Arlington, Va.

  2. Agenda for the High Temperature Membrane Working Group Meeting

    Broader source: Energy.gov [DOE]

    This agenda provides information about the Agenda for the High Temperature Membrane Working Group Meeting on September 14, 2006.

  3. Development of EPA radiation site cleanup regulations

    SciTech Connect (OSTI)

    Burnett, J.

    1994-12-31T23:59:59.000Z

    This paper summarizes the EPA program to develop radiation site cleanup and identifies many of the issues related to that effort. The material is drawn from portions of the Agency`s Issues Paper on Radiation Site Cleanup Regulations (EPA 402-R-93-084). The site cleanup regulations will be designed to protect human health and the environment and to facilitate the cleanup of sites. EPA believes that developing specific cleanup standards for radionuclides will ensure consistent, protective, and cost-effective site remediation. They will apply to all Federal facilities such as those operated by the US Department of Energy (DOE), the US Department of Defense (DoD), and sites licensed by the US Nuclear Regulatory Commission (NRC) and its Agreement States.

  4. Environmental Remediation program to perform slope-side cleanup...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Perform slope-side cleanup Environmental Remediation program to perform slope-side cleanup near Smith's Marketplace Los Alamos National Laboratory is performing a high-angle...

  5. High Temperature Integrated Thermoelectric Ststem and Materials

    SciTech Connect (OSTI)

    Mike S. H. Chu

    2011-06-06T23:59:59.000Z

    The final goal of this project is to produce, by the end of Phase II, an all ceramic high temperature thermoelectric module. Such a module design integrates oxide ceramic n-type, oxide ceramic p-type materials as thermoelectric legs and oxide ceramic conductive material as metalizing connection between n-type and p-type legs. The benefits of this all ceramic module are that it can function at higher temperatures (> 700 C), it is mechanically and functionally more reliable and it can be scaled up to production at lower cost. With this all ceramic module, millions of dollars in savings or in new opportunities recovering waste heat from high temperature processes could be made available. A very attractive application will be to convert exhaust heat from a vehicle to reusable electric energy by a thermoelectric generator (TEG). Phase I activities were focused on evaluating potential n-type and p-type oxide compositions as the thermoelectric legs. More than 40 oxide ceramic powder compositions were made and studied in the laboratory. The compositions were divided into 6 groups representing different material systems. Basic ceramic properties and thermoelectric properties of discs sintered from these powders were measured. Powders with different particles sizes were made to evaluate the effects of particle size reduction on thermoelectric properties. Several powders were submitted to a leading thermoelectric company for complete thermoelectric evaluation. Initial evaluation showed that when samples were sintered by conventional method, they had reasonable values of Seebeck coefficient but very low values of electrical conductivity. Therefore, their power factors (PF) and figure of merits (ZT) were too low to be useful for high temperature thermoelectric applications. An unconventional sintering method, Spark Plasma Sintering (SPS) was determined to produce better thermoelectric properties. Particle size reduction of powders also was found to have some positive benefits. Two composition systems, specifically 1.0 SrO - 0.8 x 1.03 TiO2 - 0.2 x 1.03 NbO2.5 and 0.97 TiO2 - 0.03 NbO2.5, have been identified as good base line compositions for n-type thermoelectric compositions in future module design. Tests of these materials at an outside company were promising using that company's processing and material expertise. There was no unique p-type thermoelectric compositions identified in phase I work other than several current cobaltite materials. Ca3Co4O9 will be the primary p-type material for the future module design until alternative materials are developed. BaTiO3 and rare earth titanate based dielectric compositions show both p-type and n-type behavior even though their electrical conductivities were very low. Further research and development of these materials for thermoelectric applications is planned in the future. A preliminary modeling and optimization of a thermoelectric generator (TEG) that uses the n-type 1.0 SrO - 1.03 x 0.8 TiO2 - 1.03 x 0.2 NbO2.5 was performed. Future work will combine development of ceramic powders and manufacturing expertise at TAM, development of SPS at TAM or a partner organization, and thermoelectric material/module testing, modeling, optimization, production at several partner organizations.

  6. Use of High Temperature Electrochemical Cells for Co-Generation of Chemicals and Electricity

    SciTech Connect (OSTI)

    Scott Barnett

    2007-09-30T23:59:59.000Z

    In this project, two key issues were addressed to show the feasibility of electrochemical partial oxidation (EPOx) in a SOFC. First, it was demonstrated that SOFCs can reliably operate directly with natural gas. These results are relevant to both direct-natural-gas SOFCs, where the aim is solely electrical power generation, and to EPOx. Second, it must be shown that SOFCs can work effectively as partial oxidation reactors, i.e, that they can provide high conversion efficiency of natural gas to syngas. The results of this study in both these areas look extremely promising. The main results are summarized briefly: (1) Stability and coke-free direct-methane SOFC operation is promoted by the addition of a thin porous inert barrier layer to the anode and the addition of small amounts of CO{sub 2} or air to the fuel stream; (2) Modeling results readily explained these improvements by a change in the gas composition at the Ni-YSZ anode to a non-coking condition; (3) The operation range for coke-free operation is greatly increased by using a cell geometry with a thin Ni-YSZ anode active layer on an inert porous ceramic support, i.e., (Sr,La)TiO{sub 3} or partially-stabilized zirconia (in segmented-in-series arrays); (4) Ethane and propane components in natural gas greatly increase coking both on the SOFC anode and on gas-feed tubes, but this can be mitigated by preferentially oxidizing these components prior to introduction into the fuel cell, the addition of a small amount of air to the fuel, and/or the use of ceramic-supported SOFC; (5) While a minimum SOFC current density was generally required to prevent coking, current interruptions of up to 8 minutes yielded only slight anode coking that caused no permanent damage and was completely reversible when the cell current was resumed; (6) Stable direct-methane SOFC operation was demonstrated under EPOx conditions in a 350 h test; (7) EPOx operation was demonstrated at 750 C that yielded 0.9 W/cm{sup 2} and a syngas production rate of 30 sccm/cm{sup 2}, and the reaction product composition was close to the equilibrium prediction during the early stages of cell testing; (8) The methane conversion to syngas continuously decreased during the first 100 h of cell testing, even though the cell electrical characteristics did not change, due to a steady decrease in the reforming activity of Ni-YSZ anodes; (9) The stability of methane conversion was substantially improved via the addition of a more stable reforming catalyst to the SOFC anode; (10) Modeling results indicated that a SOFC with anode barrier provides similar non-coking performance as an internal reforming SOFC, and provides a simpler approach with no need for a high-temperature exhaust-gas recycle pump; (11) Since there is little or no heat produced in the EPOx reaction, overall efficiency of the SOFC operated in this mode can, in theory, approach 100%; and (12) The combined value of the electricity and syngas produced allows the EPOx generator to be economically viable at a >2x higher cost/kW than a conventional SOFC.

  7. HANFORD SITE RIVER CORRIDOR CLEANUP

    SciTech Connect (OSTI)

    BAZZELL, K.D.

    2006-02-01T23:59:59.000Z

    In 2005, the US Department of Energy (DOE) launched the third generation of closure contracts, including the River Corridor Closure (RCC) Contract at Hanford. Over the past decade, significant progress has been made on cleaning up the river shore that bordes Hanford. However, the most important cleanup challenges lie ahead. In March 2005, DOE awarded the Hanford River Corridor Closure Contract to Washington Closure Hanford (WCH), a limited liability company owned by Washington Group International, Bechtel National and CH2M HILL. It is a single-purpose company whose goal is to safely and efficiently accelerate cleanup in the 544 km{sup 2} Hanford river corridor and reduce or eliminate future obligations to DOE for maintaining long-term stewardship over the site. The RCC Contract is a cost-plus-incentive-fee closure contract, which incentivizes the contractor to reduce cost and accelerate the schedule. At $1.9 billion and seven years, WCH has accelerated cleaning up Hanford's river corridor significantly compared to the $3.2 billion and 10 years originally estimated by the US Army Corps of Engineers. Predictable funding is one of the key features of the new contract, with funding set by contract at $183 million in fiscal year (FY) 2006 and peaking at $387 million in FY2012. Another feature of the contract allows for Washington Closure to perform up to 40% of the value of the contract and subcontract the balance. One of the major challenges in the next few years will be to identify and qualify sufficient subcontractors to meet the goal.

  8. Sorption-Enhanced Synthetic Natural Gas (SNG) Production from Syngas: A Novel Process Combining CO Methanation, Water-Gas Shift, and CO2 Capture

    SciTech Connect (OSTI)

    Lebarbier, Vanessa MC; Dagle, Robert A.; Kovarik, Libor; Albrecht, Karl O.; Li, Xiaohong S.; Li, Liyu; Taylor, Charles E.; Bao, Xinhe; Wang, Yong

    2014-01-01T23:59:59.000Z

    Synthetic natural gas (SNG) production from syngas is under investigation again due to the desire for less dependency from imports and the opportunity for increasing coal utilization and reducing green house gas emission. CO methanation is highly exothermic and substantial heat is liberated which can lead to process thermal imbalance and deactivation of the catalyst. As a result, conversion per pass is limited and substantial syngas recycle is employed in conventional processes. Furthermore, the conversion of syngas to SNG is typically performed at moderate temperatures (275 to 325°C) to ensure high CH4 yields since this reaction is thermodynamically limited. In this study, the effectiveness of a novel integrated process for the SNG production from syngas at high temperature (i.e. 600?C) was investigated. This integrated process consists of combining a CO methanation nickel-based catalyst with a high temperature CO2 capture sorbent in a single reactor. Integration with CO2 separation eliminates the reverse-water-gas shift and the requirement for a separate water-gas shift (WGS) unit. Easing of thermodynamic constraint offers the opportunity of enhancing yield to CH4 at higher operating temperature (500-700şC) which also favors methanation kinetics and improves the overall process efficiency due to exploitation of reaction heat at higher temperatures. Furthermore, simultaneous CO2 capture eliminates green house gas emission. In this work, sorption-enhanced CO methanation was demonstrated using a mixture of a 68% CaO/32% MgAl2O4 sorbent and a CO methanation catalyst (Ni/Al2O3, Ni/MgAl2O4, or Ni/SiC) utilizing a syngas ratio (H2/CO) of 1, gas-hour-space velocity (GHSV) of 22 000 hr-1, pressure of 1 bar and a temperature of 600oC. These conditions resulted in ~90% yield to methane, which was maintained until the sorbent became saturated with CO2. By contrast, without the use of sorbent, equilibrium yield to methane is only 22%. Cyclic stability of the methanation catalyst and durability of the sorbent were also studied in the multiple carbonation-decarbonation cycle studies proving the potential of this integrated process in a practical application.

  9. High Temperature Interactions of Antimony with Nickel

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.

    2012-07-01T23:59:59.000Z

    In this chapter, the surface and bulk interactions of antimony with the Ni-based anodes in solid oxide fuel cells (SOFC) will be discussed. High fuel flexibility is a significant advantage of SOFCs, allowing the direct use of fossil and bio fuels without a hydrogen separation unit. Synthesis gas derived from coal and biomass consists of a mixture of hydrogen, carbon monoxide, carbon dioxide, and steam, but finite amounts of tars and trace impurities such as S, Se, P, As, Sb, Cd, Pb, Cl, etc, are also always present. While synthesis gas is commonly treated with a series of chemical processes and scrubbers to remove the impurities, complete purification is not economical. Antimony is widely distributed in coals. During coal gasification antimony is volatilized, such that contact with the SOFC anodes and other SOFC parts, e.g., interconnect, current collecting wires, fuel gas supplying tubing, is most likely. This chapter addresses the following topics: high temperature Ni - Sb interactions; alteration phase, Ni3Sb, Ni5Sb2, NiSb, formation; thermochemical modeling; impact of Sb on the electrocatalytic activity of Ni toward the fuel oxidation and the presence of other impurities (sulfur, in particular); converted anode structural instability during long-term SOFC operation; comparison with nickel heterogeneous catalysts.

  10. Secondary calcium solid electrolyte high temperature battery

    SciTech Connect (OSTI)

    Sammells, A.F.; Schumacher, B.

    1986-01-01T23:59:59.000Z

    The authors report on recent work directed towards determining the viability of polycrystalline Ca/sup 2 +/ conducting ..beta..''-alumina solid electrolytes as the basis for a new type of high temperature battery. In this battery system the negative electrode consisted of a calcium-silicon alloy whose redox electro-chemistry was mediated to the calcium conducting solid electrolyte via the use of the molten salt eutectic CaCl/sub 2/ (51.4/sup M//0), CaI/sub 2/ (mp 550/sup 0/C). Both the molten salt and the calcium-alloy negative active material were separated from the positive active material via the Ca/sup 2 +/ conducting polycrystalline solid electrolyte. The positive electrode consisted of a solid-state matrix having a somewhat related crystallographic structure to Ca/sup 2 +/ ..beta..''-alumina, but where a significant fraction of the A1/sup 3 +/ sites located within this solid electrolyte's spinel block were replaced by immobile transition metal species. These species were available for participating in solid-state redox electrochemistry upon electrochemical cell cycling.

  11. Development of Strengthened Bundle High Temperature Superconductors

    SciTech Connect (OSTI)

    Lue, J.W.; Lubell, M.S. [Oak Ridge National Lab., TN (United States); Demko, J.A. [Oak Ridge Inst. for Science and Education, TN (United States); Tomsic, M. [Plastronic, Inc., Troy, OH (United States); Sinha, U. [Southwire Company, Carollton, GA (United States)

    1997-12-31T23:59:59.000Z

    In the process of developing high temperature superconducting (HTS) transmission cables, it was found that mechanical strength of the superconducting tape is the most crucial property that needs to be improved. It is also desirable to increase the current carrying capacity of the conductor so that fewer layers are needed to make the kilo-amp class cables required for electric utility usage. A process has been developed by encapsulating a stack of Bi-2223/Ag tapes with a silver or non-silver sheath to form a strengthened bundle superconductor. This process was applied to HTS tapes made by the Continuous Tube Forming and Filling (CTFF) technique pursued by Plastronic Inc. and HTS tapes obtained from other manufacturers. Conductors with a bundle of 2 to 6 HTS tapes have been made. The bundled conductor is greatly strengthened by the non-silver sheath. No superconductor degradation as compared to the sum of the original critical currents of the individual tapes was seen on the finished conductors.

  12. Integrated low emission cleanup system for direct coal-fueled turbines (electrostatic agglomeration)

    SciTech Connect (OSTI)

    Quimby, J.M.; Kumar, K.S.

    1992-01-01T23:59:59.000Z

    The objective of this contract was to investigate the removal of SO[sub x] and particulate matter from direct coal fired combustion gas streams at high temperature and high pressure conditions. This investigation was to be accomplished through a bench scale testing and evaluation program for SO[sub x] removal and the innovative particulate collection concept of particulate growth through electrostatic agglomeration followed by high efficiency mechanical collection. The process goal was to achieve control better than that required by 1979 New Source Performance Standards. During Phase I, the designs of the combustor and gas cleanup apparatus were successfully completed. Hot gas cleanup was designed to be accomplished at temperature levels between 1800[degrees] and 2500[degrees]F at pressures up to 15 atmospheres. The combustor gas flow rate could be varied between 0.2--0.5 pounds per second. The electrostatic agglomerator residence time could be varied between 0.25 to 3 seconds. In Phase II, all components were fabricated, and erected successfully. Test data from shakedown testing was obtained. Unpredictable difficulties in pilot plant erection and shakedown consumed more budget resources than was estimated and as a consequence DOE, METC, decided ft was best to complete the contract at the end of Phase II. Parameters studied in shakedown testing revealed that high-temperature high pressure electrostatics offers an alternative to barrier filtration in hot gas cleanup but more research is needed in successful system integration between the combustor and electrostatic agglomerator.

  13. Geochemistry of Aluminum in High Temperature Brines

    SciTech Connect (OSTI)

    Benezeth, P.; Palmer, D.A.; Wesolowski, D.J.

    1999-05-18T23:59:59.000Z

    The objective ofthis research is to provide quantitative data on the equilibrium and thermodynamic properties of aluminum minerals required to model changes in permeability and brine chemistry associated with fluid/rock interactions in the recharge, reservoir, and discharge zones of active geothermal systems. This requires a precise knowledge of the thermodynamics and speciation of aluminum in aqueous brines, spanning the temperature and fluid composition rangesencountered in active systems. The empirical and semi-empirical treatments of the solubility/hydrolysis experimental results on single aluminum mineral phases form the basis for the ultimate investigation of the behavior of complex aluminosilicate minerals. The principal objective in FY 1998 was to complete the solubility measurements on boehmite (AIOOH) inNaC1 media( 1 .O and 5.0 molal ionic strength, IOO-250°C). However, additional measurements were also made on boehmite solubility in pure NaOH solutions in order to bolster the database for fitting in-house isopiestic data on this system. Preliminary kinetic Measurements of the dissolution/precipitation of boehmite was also carried out, although these were also not planned in the earlier objective. The 1999 objectives are to incorporate these treatments into existing codes used by the geothermal industry to predict the chemistry ofthe reservoirs; these calculations will be tested for reliability against our laboratory results and field observations. Moreover, based on the success of the experimental methods developed in this program, we intend to use our unique high temperature pH easurement capabilities to make kinetic and equilibrium studies of pH-dependent aluminosilicate transformation reactions and other pH-dependent heterogeneous reactions.

  14. First high-temperature electronics products survey 2005.

    SciTech Connect (OSTI)

    Normann, Randy Allen

    2006-04-01T23:59:59.000Z

    On April 4-5, 2005, a High-Temperature Electronics Products Workshop was held. This workshop engaged a number of governmental and private industry organizations sharing a common interest in the development of commercially available, high-temperature electronics. One of the outcomes of this meeting was an agreement to conduct an industry survey of high-temperature applications. This report covers the basic results of this survey.

  15. Coprocessing of Highvale coal with Athabasca bitumen in syngas mixtures

    SciTech Connect (OSTI)

    Parker, R.J.; Clark, P.D.; Ignasiak, B.L.; Lee, T.; Ohuchi, T.

    1986-04-01T23:59:59.000Z

    Coprocessing of Alberta subbituminous coal with bitumen is currently under investigation at the Alberta Research Council. The high oxygen content of the coal results in high hydrogen consumption. The present study compares the effectiveness of syngas/water mixtures catalyzed by potassium carbonate for coprocessing Highvale coal with Athabasca bitumen. Single-stage (solubilization) experiments were performed with syngas (5.1 MPa) at 390/sup 0/C in a stirred autoclave. In simulated two-stage experiments, the second (upgrading) stage employed hydrogen (8.5 MPa) at 440/sup 0/C with a potassium molybdate/dimethyl disulphide catalyst. Coal conversion improved from 47 to 78% systematically when the carbon monoxide: hydrogen ratio was varied from 1:3 to 7:1. The additional yield was confined to pyridine extractable material. In simulated two-stage experiments similar coal conversions were observed when using carbon monoxide/water (91%) or hydrogen (88%) in the first stage.

  16. Overview of Fraunhofer IPM Activities in High Temperature Bulk...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Workshop including an overview about Fraunhofer IPM, new funding situation in Germany, high temperature material and modules, energy-autarkic sensors, and thermoelectric...

  17. Detecting Fractures Using Technology at High Temperatures and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Detecting Fractures Using Technology at High Temperatures and Depths - Geothermal Ultrasonic Fracture Imager (GUFI); 2010 Geothermal Technology Program Peer Review Report Detecting...

  18. Microchannel High-Temperature Recuperator for Fuel Cell Systems...

    Broader source: Energy.gov (indexed) [DOE]

    developed an efficient, microchannel-based waste heat recuperator for a high-temperature fuel cell system. This technology increases the efficiency of fuel cells and improves...

  19. Detecting Fractures Using Technology at High Temperatures and...

    Broader source: Energy.gov (indexed) [DOE]

    7 4.4.1 Detecting Fractures Using Technology at High Temperatures and Depths - Geothermal Ultrasonic Fracture Imager (GUFI) Presentation Number: 015 Investigator: Patterson, Doug...

  20. High-Temperature-High-Volume Lifting for Enhanced Geothermal...

    Broader source: Energy.gov (indexed) [DOE]

    Turnquist GE Global Research High Temperature Tools and Sensors, Down-hole Pumps and Drilling May 19, 2010 This presentation does not contain any proprietary confidential, or...

  1. Project Profile: Fundamental Corrosion Studies in High-Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Studies in High-Temperature Molten Salt Systems for Next-Generation CSP Systems Savannah River National Laboratory logo The Savannah River National Laboratory (SRNL), under the...

  2. High-Temperature-High-Volume Lifting For Enhanced Geothermal...

    Open Energy Info (EERE)

    include high-temperature drive system materials, journal and thrust bearings, and corrosion and erosion-resistant lifting pump components. Finally, in Phase 3, the overall...

  3. Nanostructured High-Temperature Bulk Thermoelectric Energy Conversion...

    Broader source: Energy.gov (indexed) [DOE]

    Nanostructured High-Temperature Bulk Thermoelectric Energy Conversion for Efficient Automotive Waste Heat Recovery Vehicle Technologies Office Merit Review 2014: Nanostructured...

  4. Feasibility and Design Studies for a High Temperature Downhole Tool

    Broader source: Energy.gov [DOE]

    Project objective: Perform feasibility and design studies for a high temperature downhole tool; which uses nuclear techniques for characterization purposes; using measurements and modeling/simulation.

  5. Enhanced High Temperature Performance of NOx Storage/Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program Annual Merit Review and Peer Evaluation ace026peden2011o.pdf More Documents & Publications Enhanced High Temperature Performance of NOx StorageReduction (NSR) Materials...

  6. Enhanced High Temperature Performance of NOx Storage/Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Meeting ace026peden2012o.pdf More Documents & Publications Enhanced High Temperature Performance of NOx StorageReduction (NSR) Materials Enhanced High and Low...

  7. Combining Raman Microprobe and XPS to Study High Temperature...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    spectroscopy. Citation: Windisch CF, Jr, CH Henager, MH Engelhard, and WD Bennett.2011."Combining Raman Microprobe and XPS to Study High Temperature Oxidation of...

  8. Development of a 500 Watt High Temperature Thermoelectric Generator...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Publications Development of a 100-Watt High Temperature Thermoelectric Generator Automotive Waste Heat Conversion to Power Program Automotive Waste Heat Conversion to Power Program...

  9. A Review of Materials for Gas Turbines Firing Syngas Fuels

    SciTech Connect (OSTI)

    Gibbons, Thomas [ORNL; Wright, Ian G [ORNL

    2009-05-01T23:59:59.000Z

    Following the extensive development work carried out in the 1990's, gas turbine combined-cycle (GTCC) systems burning natural gas represent a reliable and efficient power generation technology widely used in many parts of the world. A critical factor was that, in order to operate at the high turbine entry temperatures required for high efficiency operation, aero-engine technology, i.e., single-crystal blades, thermal barrier coatings, and sophisticated cooling techniques had to be rapidly scaled up and introduced into these large gas turbines. The problems with reliability that resulted have been largely overcome, so that the high-efficiency GTCC power generation system is now a mature technology, capable of achieving high levels of availability. The high price of natural gas and concern about emission of greenhouse gases has focused attention on the desirability of replacing natural gas with gas derived from coal (syngas) in these gas turbine systems, since typical systems analyses indicate that IGCC plants have some potential to fulfil the requirement for a zero-emissions power generation system. In this review, the current status of materials for the critical hot gas path parts in large gas turbines is briefly considered in the context of the need to burn syngas. A critical factor is that the syngas is a low-Btu fuel, and the higher mass flow compared to natural gas will tend to increase the power output of the engine. However, modifications to the turbine and to the combustion system also will be necessary. It will be shown that many of the materials used in current engines will also be applicable to units burning syngas but, since the combustion environment will contain a greater level of impurities (especially sulfur, water vapor, and particulates), the durability of some components may be prejudiced. Consequently, some effort will be needed to develop improved coatings to resist attack by sulfur-containing compounds, and also erosion.

  10. A Hybrid Gas Cleaning Process for Production of Ultraclean Syngas

    SciTech Connect (OSTI)

    Merkel, T.C.; Turk, B.S.; Gupta, R.P.; Cicero, D.C.; Jain, S.C.

    2002-09-20T23:59:59.000Z

    The overall objective of this project is to develop technologies for cleaning/conditioning IGCC generated syngas to meet contaminant tolerance limits for fuel cell and chemical production applications. The specific goals are to develop processes for (1) removal of reduced sulfur species to sub-ppm levels using a hybrid process consisting of a polymer membrane and a regenerable ZnO-coated monolith or a mixed metal oxide sorbent; (2) removal of hydrogen chloride vapors to sub-ppm levels using an inexpensive, high-surface-area material; and (3) removal of NH3 with acidic adsorbents followed by conversion of this NH3 into nitrogen and water. Existing gasification technologies can effectively and efficiently convert a wide variety of carbonaceous feedstocks (coal, petcoke, resids, biomass, etc.) into syngas, which predominantly contains carbon monoxide and hydrogen. Unfortunately, the impurities present in these carbonaceous feedstocks are converted to gaseous contaminants such as H2S, COS, HCl, NH3, alkali macromolecules and heavy metal compounds (such as Hg) during the gasification process. Removal of these contaminants using conventional processes is thermally inefficient and capital intensive. This research and development effort is focused on investigation of modular processes for removal of sulfur, chlorine, nitrogen and mercury compounds from syngas at elevated temperature and pressures at significantly lower costs than conventional technologies.

  11. Scaling Studies for High Temperature Test Facility and Modular High Temperature Gas-Cooled Reactor

    SciTech Connect (OSTI)

    Richard R. Schult; Paul D. Bayless; Richard W. Johnson; James R. Wolf; Brian Woods

    2012-02-01T23:59:59.000Z

    The Oregon State University (OSU) High Temperature Test Facility (HTTF) is an integral experimental facility that will be constructed on the OSU campus in Corvallis, Oregon. The HTTF project was initiated, by the U.S. Nuclear Regulatory Commission (NRC), on September 5, 2008 as Task 4 of the 5-year High Temperature Gas Reactor Cooperative Agreement via NRC Contract 04-08-138. Until August, 2010, when a DOE contract was initiated to fund additional capabilities for the HTTF project, all of the funding support for the HTTF was provided by the NRC via their cooperative agreement. The U.S. Department of Energy (DOE) began their involvement with the HTTF project in late 2009 via the Next Generation Nuclear Plant (NGNP) project. Because the NRC's interests in HTTF experiments were only centered on the depressurized conduction cooldown (DCC) scenario, NGNP involvement focused on expanding the experimental envelope of the HTTF to include steady-state operations and also the pressurized conduction cooldown (PCC).

  12. Integrated Operation of INL HYTEST System and High-Temperature Steam Electrolysis for Synthetic Natural Gas Production

    SciTech Connect (OSTI)

    Carl Marcel Stoots; Lee Shunn; James O'Brien

    2010-06-01T23:59:59.000Z

    The primary feedstock for synthetic fuel production is syngas, a mixture of carbon monoxide and hydrogen. Current hydrogen production technologies rely upon fossil fuels and produce significant quantities of greenhouse gases as a byproduct. This is not a sustainable means of satisfying future hydrogen demands, given the current projections for conventional world oil production and future targets for carbon emissions. For the past six years, the Idaho National Laboratory has been investigating the use of high-temperature steam electrolysis (HTSE) to produce the hydrogen feedstock required for synthetic fuel production. High-temperature electrolysis water-splitting technology, combined with non-carbon-emitting energy sources, can provide a sustainable, environmentally-friendly means of large-scale hydrogen production. Additionally, laboratory facilities are being developed at the INL for testing hybrid energy systems composed of several tightly-coupled chemical processes (HYTEST program). The first such test involved the coupling of HTSE, CO2 separation membrane, reverse shift reaction, and methanation reaction to demonstrate synthetic natural gas production from a feedstock of water and either CO or a simulated flue gas containing CO2. This paper will introduce the initial HTSE and HYTEST testing facilities, overall coupling of the technologies, testing results, and future plans.

  13. To Crack or Not to Crack: Strain in High Temperature Superconductors

    E-Print Network [OSTI]

    Godeke, Arno

    2008-01-01T23:59:59.000Z

    in High Temperature Superconductors Arno Godeke August 22,in High Temperature Superconductors Motivation Magneticin High Temperature Superconductors How do Nb 3 Sn magnets

  14. ANALYSIS OF A HIGH TEMPERATURE GAS-COOLED REACTOR POWERED HIGH TEMPERATURE ELECTROLYSIS HYDROGEN PLANT

    SciTech Connect (OSTI)

    M. G. McKellar; E. A. Harvego; A. M. Gandrik

    2010-11-01T23:59:59.000Z

    An updated reference design for a commercial-scale high-temperature electrolysis (HTE) plant for hydrogen production has been developed. The HTE plant is powered by a high-temperature gas-cooled reactor (HTGR) whose configuration and operating conditions are based on the latest design parameters planned for the Next Generation Nuclear Plant (NGNP). The current HTGR reference design specifies a reactor power of 600 MWt, with a primary system pressure of 7.0 MPa, and reactor inlet and outlet fluid temperatures of 322°C and 750°C, respectively. The reactor heat is used to produce heat and electric power to the HTE plant. A Rankine steam cycle with a power conversion efficiency of 44.4% was used to provide the electric power. The electrolysis unit used to produce hydrogen includes 1.1 million cells with a per-cell active area of 225 cm2. The reference hydrogen production plant operates at a system pressure of 5.0 MPa, and utilizes a steam-sweep system to remove the excess oxygen that is evolved on the anode (oxygen) side of the electrolyzer. The overall system thermal-to-hydrogen production efficiency (based on the higher heating value of the produced hydrogen) is 42.8% at a hydrogen production rate of 1.85 kg/s (66 million SCFD) and an oxygen production rate of 14.6 kg/s (33 million SCFD). An economic analysis of this plant was performed with realistic financial and cost estimating The results of the economic analysis demonstrated that the HTE hydrogen production plant driven by a high-temperature helium-cooled nuclear power plant can deliver hydrogen at a competitive cost. A cost of $3.03/kg of hydrogen was calculated assuming an internal rate of return of 10% and a debt to equity ratio of 80%/20% for a reactor cost of $2000/kWt and $2.41/kg of hydrogen for a reactor cost of $1400/kWt.

  15. Calcite Mineral Scaling Potentials of High-Temperature Geothermal Wells

    E-Print Network [OSTI]

    Karlsson, Brynjar

    #12;i Calcite Mineral Scaling Potentials of High-Temperature Geothermal Wells Alvin I. Remoroza-Temperature Geothermal Wells Alvin I. Remoroza 60 ECTS thesis submitted in partial fulfillment of a Magister Scientiarum #12;iv Calcite Mineral Scaling Potentials of High-Temperature Geothermal Wells 60 ECTS thesis

  16. High Temperature Evaluation of Tantalum Capacitors - Test 1

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Cieslewski, Grzegorz

    Tantalum capacitors can provide much higher capacitance at high-temperatures than the ceramic capacitors. This study evaluates selected tantalum capacitors at high temperatures to determine their suitability for you in geothermal field. This data set contains results of the first test where three different types of capacitors were evaluated at 260C.

  17. High Temperature Evaluation of Tantalum Capacitors - Test 1

    SciTech Connect (OSTI)

    Cieslewski, Grzegorz

    2014-09-28T23:59:59.000Z

    Tantalum capacitors can provide much higher capacitance at high-temperatures than the ceramic capacitors. This study evaluates selected tantalum capacitors at high temperatures to determine their suitability for you in geothermal field. This data set contains results of the first test where three different types of capacitors were evaluated at 260C.

  18. High-temperature piezoresponse force microscopy B. Bhatia,1

    E-Print Network [OSTI]

    King, William P.

    High-temperature piezoresponse force microscopy B. Bhatia,1 J. Karthik,2 D. G. Cahill,1,2 L. W September 2011; published online 24 October 2011) We report high temperature piezoresponse force microscopy resistive heater allows local temperature control up to 1000 C with minimal electrostatic interactions

  19. Quark number susceptibility of high temperature and finite density QCD

    E-Print Network [OSTI]

    Ari Hietanen; Kari Rummukainen

    2007-10-26T23:59:59.000Z

    We utilize lattice simulations of the dimensionally reduced effective field theory (EQCD) to determine the quark number susceptibility of QCD at high temperature ($T>2T_c$). We also use analytic continuation to obtain results at finite density. The results extrapolate well from known perturbative expansion (accurate in extremely high temperatures) to 4d lower temperature lattice data

  20. Calculated Phonon Spectra of Plutonium at High Temperatures

    E-Print Network [OSTI]

    Savrasov, Sergej Y.

    Calculated Phonon Spectra of Plutonium at High Temperatures X. Dai,1 S. Y. Savrasov,2 * G. Kotliar dynamical proper- ties of plutonium using an electronic structure method, which incorporates correlation anharmonic and can be stabilized at high temperatures by its phonon entropy. Plutonium (Pu) is a material

  1. High Temperature Electrolysis of Steam and Carbon Dioxide

    E-Print Network [OSTI]

    High Temperature Electrolysis of Steam and Carbon Dioxide Søren Højgaard Jensen+,#, Jens V. T. Høgh + O2 #12;Electrolysis of steam at high temperature Interesting because · Improved thermodynamic of electrolysis of steam Picture taken from E. Erdle, J. Gross, V. Meyringer, "Solar thermal central receiver

  2. Technical and economic assessment of producing hydrogen by reforming syngas from the Battelle indirectly heated biomass gasifier

    SciTech Connect (OSTI)

    Mann, M.K. [National Renewable Energy Lab., Golden, CO (United States). Industrial Technologies Div.

    1995-08-01T23:59:59.000Z

    The technical and economic feasibility of producing hydrogen from biomass by means of indirectly heated gasification and steam reforming was studied. A detailed process model was developed in ASPEN Plus{trademark} to perform material and energy balances. The results of this simulation were used to size and cost major pieces of equipment from which the determination of the necessary selling price of hydrogen was made. A sensitivity analysis was conducted on the process to study hydrogen price as a function of biomass feedstock cost and hydrogen production efficiency. The gasification system used for this study was the Battelle Columbus Laboratory (BCL) indirectly heated gasifier. The heat necessary for the endothermic gasification reactions is supplied by circulating sand from a char combustor to the gasification vessel. Hydrogen production was accomplished by steam reforming the product synthesis gas (syngas) in a process based on that used for natural gas reforming. Three process configurations were studied. Scheme 1 is the full reforming process, with a primary reformer similar to a process furnace, followed by a high temperature shift reactor and a low temperature shift reactor. Scheme 2 uses only the primary reformer, and Scheme 3 uses the primary reformer and the high temperature shift reactor. A pressure swing adsorption (PSA) system is used in all three schemes to produce a hydrogen product pure enough to be used in fuel cells. Steam is produced through detailed heat integration and is intended to be sold as a by-product.

  3. Money crunch looms for Federal cleanup effort

    SciTech Connect (OSTI)

    Lobsenz, G.

    1992-12-03T23:59:59.000Z

    In an unprecedented acknowledgement that federal facility cleanup activities face a money crunch, a federal-state advisory panel is preparing a new strategy to avert enforcement showdowns when funding cuts prevent federal agencies from meeting legally required cleanup schedules set by states. In a draft report the panel said states must recognize that some cleanup [open quotes]milestones[close quotes] will have to be delayed due to budget pressures - a concession that will be politically difficult in some states. At the same time, the panel said federal agencies must be more forthcoming in working with states and local groups to determine how increasingly scarce resources will be distributed. As a general rule, the report recommended that federal agencies and state environmental officials agree on a [open quotes]fair share[close quotes] allocation method under which the pain of a budget cutback would be spread equally among all cleanup sites within an affected federal agency. That fair share approach would be altered only if the federal agency reached agreement with states that a funding cutback could be absorbed at selected sites without affecting any cleanup milestone.

  4. Upton bill offers clean-up incentives

    SciTech Connect (OSTI)

    Black, B. [Weinberg & Green, Baltimore, MD (United States)

    1994-07-01T23:59:59.000Z

    Like castor oil, the Superfund law can be difficult medicine to swallow, and no one wants to volunteer for a dose. Indeed, the law`s harsh and unbending liability scheme sometimes hinders the cleanup of contaminated property. Confronted with the choice of redeveloping an old {open_quotes}brownfield{close_quotes} urban industrial site or building at a pristine new {open_quotes}greenfield{close_quotes} location, most companies opt for the latter. The brownfield problem is especially troubling because the law often prevents voluntary cleanups at relatively low priority sites that usually don`t get caught up in the Superfund program. This paper describes the Upton Bill which would require the US EPA to establish cleanup standards for hazrdous substances, allow for public comment on a proposed response plan, and require a voluntary party to submit detailed annual reports and maintain records.

  5. Issues paper on radiation site cleanup regulations

    SciTech Connect (OSTI)

    Not Available

    1993-09-01T23:59:59.000Z

    EPA prepared the document to present issues, approaches, and preliminary analyses related to its development of radiation site cleanup regulations. It focuses exclusively on issues and approaches related to developing cleanup regulations; it does not address issues specific to waste management regulations, which will be addressed in a separate document. The first three chapters discuss Significant Issues, Regulatory Approaches, and Summary and Next Steps. Appendix A presents background information on radioactive waste and provides additional details of EPA coordination of its rulemaking effort. Appendix B discusses statutory authorities upon which EPA may base its cleanup regulations. Appendix C is a copy of the EPA/NRC MOU. Appendix D discusses the issues raised in NRC's Enhanced Participatory Rulemaking on Radiological Criteria for Decommissioning, in which EPA participated. Appendix E is a list of acronyms, and Appendix F is a glossary of terms used throughout the document.

  6. Single-Step Syngas-to-Distillates (S2D) Synthesis via Methanol and Dimethyl Ether Intermediates: Final Report

    SciTech Connect (OSTI)

    Dagle, Robert A.; Lebarbier, Vanessa MC; Lizarazo Adarme, Jair A.; King, David L.; Zhu, Yunhua; Gray, Michel J.; Jones, Susanne B.; Biddy, Mary J.; Hallen, Richard T.; Wang, Yong; White, James F.; Holladay, Johnathan E.; Palo, Daniel R.

    2013-11-26T23:59:59.000Z

    The objective of the work was to enhance price-competitive, synthesis gas (syngas)-based production of transportation fuels that are directly compatible with the existing vehicle fleet (i.e., vehicles fueled by gasoline, diesel, jet fuel, etc.). To accomplish this, modifications to the traditional methanol-to-gasoline (MTG) process were investigated. In this study, we investigated direct conversion of syngas to distillates using methanol and dimethyl ether intermediates. For this application, a Pd/ZnO/Al2O3 (PdZnAl) catalyst previously developed for methanol steam reforming was evaluated. The PdZnAl catalyst was shown to be far superior to a conventional copper-based methanol catalyst when operated at relatively high temperatures (i.e., >300°C), which is necessary for MTG-type applications. Catalytic performance was evaluated through parametric studies. Process conditions such as temperature, pressure, gas-hour-space velocity, and syngas feed ratio (i.e., hydrogen:carbon monoxide) were investigated. PdZnAl catalyst formulation also was optimized to maximize conversion and selectivity to methanol and dimethyl ether while suppressing methane formation. Thus, a PdZn/Al2O3 catalyst optimized for methanol and dimethyl ether formation was developed through combined catalytic material and process parameter exploration. However, even after compositional optimization, a significant amount of undesirable carbon dioxide was produced (formed via the water-gas-shift reaction), and some degree of methane formation could not be completely avoided. Pd/ZnO/Al2O3 used in combination with ZSM-5 was investigated for direct syngas-to-distillates conversion. High conversion was achieved as thermodynamic constraints are alleviated when methanol and dimethyl are intermediates for hydrocarbon formation. When methanol and/or dimethyl ether are products formed separately, equilibrium restrictions occur. Thermodynamic relaxation also enables the use of lower operating pressures than what would be allowed for methanol synthesis alone. Aromatic-rich hydrocarbon liquid (C5+), containing a significant amount of methylated benzenes, was produced under these conditions. However, selectivity control to liquid hydrocarbons was difficult to achieve. Carbon dioxide and methane formation was problematic. Furthermore, saturation of the olefinic intermediates formed in the zeolite, and necessary for gasoline production, occurred over PdZnAl. Thus, yield to desirable hydrocarbon liquid product was limited. Evaluation of other oxygenate-producing catalysts could possibly lead to future advances. Potential exists with discovery of other types of catalysts that suppress carbon dioxide and light hydrocarbon formation. Comparative techno-economics for a single-step syngas-to-distillates process and a more conventional MTG-type process were investigated. Results suggest operating and capital cost savings could only modestly be achieved, given future improvements to catalyst performance. Sensitivity analysis indicated that increased single-pass yield to hydrocarbon liquid is a primary need for this process to achieve cost competiveness.

  7. An experimental and kinetic study of syngas/air combustion at elevated temperatures and the effect of water addition

    E-Print Network [OSTI]

    Qiao, Li

    An experimental and kinetic study of syngas/air combustion at elevated temperatures and the effect 20 December 2011 Keywords: Syngas combustion Elevated temperatures Water addition Laminar flame speed a b s t r a c t Laminar flame speeds of premixed syngas/air mixtures were measured at various fuel

  8. Syngas Segregation Induced by Confinement in Carbon Nanotubes: A Combined First-Principles and Monte Carlo Study

    E-Print Network [OSTI]

    Bao, Xinhe

    Syngas Segregation Induced by Confinement in Carbon Nanotubes: A Combined First of the concave and convex surfaces of CNTs formed by graphene layers. As a result, syngas molecules are enriched of CO/H2 inside CNTs increases with respect to the composition of syngas in the exterior gas phase

  9. Method for synthesizing extremely high-temperature melting materials

    DOE Patents [OSTI]

    Saboungi, Marie-Louise (Chicago, IL); Glorieux, Benoit (Perpignan, FR)

    2007-11-06T23:59:59.000Z

    The invention relates to a method of synthesizing high-temperature melting materials. More specifically the invention relates to a containerless method of synthesizing very high temperature melting materials such as carbides and transition-metal, lanthanide and actinide oxides, using an aerodynamic levitator and a laser. The object of the invention is to provide a method for synthesizing extremely high-temperature melting materials that are otherwise difficult to produce, without the use of containers, allowing the manipulation of the phase (amorphous/crystalline/metastable) and permitting changes of the environment such as different gaseous compositions.

  10. Method For Synthesizing Extremely High-Temperature Melting Materials

    DOE Patents [OSTI]

    Saboungi, Marie-Louise (Chicago, IL); Glorieux, Benoit (Perpignan, FR)

    2005-11-22T23:59:59.000Z

    The invention relates to a method of synthesizing high-temperature melting materials. More specifically the invention relates to a containerless method of synthesizing very high temperature melting materials such as borides, carbides and transition-metal, lanthanide and actinide oxides, using an Aerodynamic Levitator and a laser. The object of the invention is to provide a method for synthesizing extremely high-temperature melting materials that are otherwise difficult to produce, without the use of containers, allowing the manipulation of the phase (amorphous/crystalline/metastable) and permitting changes of the environment such as different gaseous compositions.

  11. A summary of high-temperature electronics research and development

    SciTech Connect (OSTI)

    Thome, F.V.; King, D.B.

    1991-10-18T23:59:59.000Z

    Current and future needs in automative, aircraft, space, military, and well logging industries require operation of electronics at higher temperatures than today's accepted limit of 395 K. Without the availability of high-temperature electronics, many systems must operate under derated conditions or must accept severe mass penalties required by coolant systems to maintain electronic temperatures below critical levels. This paper presents ongoing research and development in the electronics community to bring high-temperature electronics to commercial realization. Much of this work was recently reviewed at the First International High-Temperature Electronics Conference held 16--20 June 1991 in Albuquerque, New Mexico. 4 refs., 1 tab.

  12. Method for Synthesizing Extremeley High Temperature Melting Materials

    DOE Patents [OSTI]

    Saboungi, Marie-Louise and Glorieux, Benoit

    2005-11-22T23:59:59.000Z

    The invention relates to a method of synthesizing high-temperature melting materials. More specifically the invention relates to a containerless method of synthesizing very high temperature melting materials such as borides, carbides and transition-metal, lanthanide and actinide oxides, using an Aerodynamic Levitator and a laser. The object of the invention is to provide a method for synthesizing extremely high-temperature melting materials that are otherwise difficult to produce, without the use of containers, allowing the manipulation of the phase (amorphous/crystalline/metastable) and permitting changes of the environment such as different gaseous compositions.

  13. Imperium/Lanzatech Syngas Fermentation Project - Biomass Gasification and Syngas Conditioning for Fermentation Evaluation: Cooperative Research and Development Final Report, CRADA Number CRD-12-474

    SciTech Connect (OSTI)

    Wilcox, E.

    2014-09-01T23:59:59.000Z

    LanzaTech and NREL will investigate the integration between biomass gasification and LanzaTech's proprietary gas fermentation process to produce ethanol and 2,3-butanediol. Using three feed materials (woody biomass, agricultural residue and herbaceous grass) NREL will produce syngas via steam indirect gasification and syngas conditioning over a range of process relevant operating conditions. The gasification temperature, steam-to-biomass ratio of the biomass feed into the gasifier, and several levels of syngas conditioning (based on temperature) will be varied to produce multiple syngas streams that will be fed directly to 10 liter seed fermenters operating with the Lanzatech organism. The NREL gasification system will then be integrated with LanzaTech's laboratory pilot unit to produce large-scale samples of ethanol and 2,3-butanediol for conversion to fuels and chemicals.

  14. Determination of the Effect of Coal/Biomass-Derived Syngas Contaminants on the Performance of Fischer-Tropsch and Water-Gas-Shift Catalysts

    SciTech Connect (OSTI)

    Trembly, Jason; Cooper, Matthew; Farmer, Justin; Turk, Brian; Gupta, Raghubir

    2010-12-31T23:59:59.000Z

    Today, nearly all liquid fuels and commodity chemicals are produced from non-renewable resources such as crude oil and natural gas. Because of increasing scrutiny of carbon dioxide (CO{sub 2}) emissions produced using traditional fossil-fuel resources, the utilization of alternative feedstocks for the production of power, hydrogen, value-added chemicals, and high-quality hydrocarbon fuels such as diesel and substitute natural gas (SNG) is critical to meeting the rapidly growing energy needs of modern society. Coal and biomass are particularly attractive as alternative feedstocks because of the abundant reserves of these resources worldwide. The strategy of co-gasification of coal/biomass (CB) mixtures to produce syngas for synthesis of Fischer-Tropsch (FT) fuels offers distinct advantages over gasification of either coal or biomass alone. Co-feeding coal with biomass offers the opportunity to exploit economies of scale that are difficult to achieve in biomass gasification, while the addition of biomass to the coal gasifier feed leverages proven coal gasification technology and allows CO{sub 2} credit benefits. Syngas generated from CB mixtures will have a unique contaminant composition because coal and biomass possess different concentrations and types of contaminants, and the final syngas composition is also strongly influenced by the gasification technology used. Syngas cleanup for gasification of CB mixtures will need to address this unique contaminant composition to support downstream processing and equipment. To investigate the impact of CB gasification on the production of transportation fuels by FT synthesis, RTI International conducted thermodynamic studies to identify trace contaminants that will react with water-gas-shift and FT catalysts and built several automated microreactor systems to investigate the effect of single components and the synergistic effects of multiple contaminants on water-gas-shift and FT catalyst performance. The contaminants investigated were sodium chloride (NaCl), potassium chloride (KCl), hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), ammonia (NH{sub 3}), and combinations thereof. This report details the thermodynamic studies and the individual and multi-contaminant results from this testing program.

  15. Effects of Combustion-Induced Vortex Breakdown on Flashback Limits of Syngas-Fueled Gas Turbine Combustors

    SciTech Connect (OSTI)

    Ahsan Choudhuri

    2011-03-31T23:59:59.000Z

    Turbine combustors of advanced power systems have goals to achieve very low pollutants emissions, fuel variability, and fuel flexibility. Future generation gas turbine combustors should tolerate fuel compositions ranging from natural gas to a broad range of syngas without sacrificing operational advantages and low emission characteristics. Additionally, current designs of advanced turbine combustors use various degrees of swirl and lean premixing for stabilizing flames and controlling high temperature NOx formation zones. However, issues of fuel variability and NOx control through premixing also bring a number of concerns, especially combustor flashback and flame blowout. Flashback is a combustion condition at which the flame propagates upstream against the gas stream into the burner tube. Flashback is a critical issue for premixed combustor designs, because it not only causes serious hardware damages but also increases pollutant emissions. In swirl stabilized lean premixed turbine combustors onset of flashback may occur due to (i) boundary layer flame propagation (critical velocity gradient), (ii) turbulent flame propagation in core flow, (iii) combustion instabilities, and (iv) upstream flame propagation induced by combustion induced vortex breakdown (CIVB). Flashback due to first two foregoing mechanisms is a topic of classical interest and has been studied extensively. Generally, analytical theories and experimental determinations of laminar and turbulent burning velocities model these mechanisms with sufficient precision for design usages. However, the swirling flow complicates the flashback processes in premixed combustions and the first two mechanisms inadequately describe the flashback propensity of most practical combustor designs. The presence of hydrogen in syngas significantly increases the potential for flashback. Due to high laminar burning velocity and low lean flammability limit, hydrogen tends to shift the combustor operating conditions towards flashback regime. Even a small amount of hydrogen in a fuel blend triggers the onset of flashback by altering the kinetics and thermophysical characteristics of the mixture. Additionally, the presence of hydrogen in the fuel mixture modifies the response of the flame to the global effects of stretch and preferential diffusion. Despite its immense importance in fuel flexible combustor design, little is known about the magnitude of fuel effects on CIVB induced flashback mechanism. Hence, this project investigates the effects of syngas compositions on flashback resulting from combustion induced vortex breakdown. The project uses controlled experiments and parametric modeling to understand the velocity field and flame interaction leading to CIVB driven flashback.

  16. Recovery Act funds advance cleanup efforts at Cold War site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cleanup efforts at Cold War site Recovery Act funds advance cleanup efforts at Cold War site A local small business, ARSEC Environmental, LLC, of White Rock, NM, won a 2 million...

  17. High Temperature Irradiation Resistant Thermocouple (HTIR-TC)

    ScienceCinema (OSTI)

    None

    2013-05-28T23:59:59.000Z

    INL researchers have created a new thermocouple that can resist high temperature and radiation. This device will improve safety and reduce costs associated with unit failures. Learn more about INL research at http://www.facebook.com/idahonationallaboratory

  18. Enabling high-temperature nanophotonics for energy applications

    E-Print Network [OSTI]

    Yeng, YiXiang

    The nascent field of high-temperature nanophotonics could potentially enable many important solid-state energy conversion applications, such as thermophotovoltaic energy generation, selective solar absorption, and selective ...

  19. Electronic properties of doped Mott insulators and high temperature superconductors

    E-Print Network [OSTI]

    Ribeiro, Tiago Castro

    2005-01-01T23:59:59.000Z

    High-temperature superconducting cuprates, which are the quintessential example of a strongly correlated system and the most extensively studied materials after semiconductors, spurred the development in the fields of ...

  20. Copper Aluminate as a potential material for high temperature...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Copper Aluminate as a potential material for high temperature thermoelectric power generation Home Author: D. T. Morelli, E. D. Case, B. D. Hall, S. Wang Year: 2008 Abstract: URL:...

  1. High-Temperature Thermal Array for Next Generation Solar Thermal...

    Broader source: Energy.gov (indexed) [DOE]

    3 Q1 High-Temperature Thermal Array for Next Generation Solar Thermal Power Production - FY13 Q1 This document summarizes the progress of this Los Alamos National Laboratory...

  2. Expansion Joint Concepts for High Temperature Insulation Systems

    E-Print Network [OSTI]

    Harrison, M. R.

    1980-01-01T23:59:59.000Z

    As high temperature steam and process piping expands with heat, joints begin to open between the insulation sections, resulting in increased energy loss and possible unsafe surface temperatures. Many different expansion joint designs are presently...

  3. Fabrication and Characterization of Uranium-based High Temperature...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fabrication and Characterization of Uranium-based High Temperature Reactor Fuel June 01, 2013 The Uranium Fuel Development Laboratory is a modern R&D scale lab for the fabrication...

  4. Stability and quench protection of high-temperature superconductors

    E-Print Network [OSTI]

    Ang, Ing Chea

    2006-01-01T23:59:59.000Z

    In the design and operation of a superconducting magnet, stability and protection are two key issues that determine the magnet's reliability and safe operation. Although the high-temperature superconductor (HTS) is considered ...

  5. High Temperature Fuel Cell (Phosphoric Acid) Manufacturing R...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Cell (Phosphoric Acid) Manufacturing R&D High Temperature Fuel Cell (Phosphoric Acid) Manufacturing R&D Presented at the NREL Hydrogen and Fuel Cell Manufacturing R&D Workshop...

  6. Assessment of Moderate- and High-Temperature Geothermal Resources...

    Open Energy Info (EERE)

    Moderate- and High-Temperature Geothermal Resources of the United States Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Assessment of Moderate- and...

  7. Voluntary Protection Program Onsite Review, Idaho Cleanup Project- October 2010

    Broader source: Energy.gov [DOE]

    Evaluation to determine whether Idaho Cleanup Project is continuing to perform at a level deserving DOE-VPP Star recognition.

  8. Design of high temperature high speed electromagnetic axial thrust bearing

    E-Print Network [OSTI]

    Mohiuddin, Mohammad Waqar

    2002-01-01T23:59:59.000Z

    DESIGN OF HIGH TEMPERATURE HIGH SPEED ELECTROMAGNETIC AXIAL THRUST BEARING A Thesis by MOHAMMAD WAQAR MOHIUDDIN Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE December 2002 Major Subject: Mechanical Engineering DESIGN OF HIGH TEMPERATURE HIGH SPEED ELECTROMAGNETIC AXIAL THRUST BEARING A Thesis by MOHAMMAD WAQAR MOHIUDDIN Submitted to Texas A&M University in partial fulfillment...

  9. Low GWP Working Fluid for High Temperature Heat Pumps

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    Low GWP Working Fluid for High Temperature Heat Pumps: DR-2 Chemical Stability at High Temperatures Temp Heat Pumps: DR-2 Very Low GWP AND Non-Flammable HFC-245fa DR-2 Chemical Formula CF3CH2CHF2 HFO 171.3 Pcr [MPa] 3.65 2.9 Kontomaris-DuPont; European Heat Pump Summit, Nuremberg, October 15th, 2013

  10. Partial oxidation of methane to syngas in different reactor types

    SciTech Connect (OSTI)

    Lapszewicz, J.A.; Campbell, I.; Charlton, B.G.; Foulds, G.A. [CSIRO Division of Coal and Energy Technology, Menai (Australia)

    1995-12-01T23:59:59.000Z

    The performance of Rh/ZnO/{gamma}-Al{sub 2}O{sub 3} catalyst for partial oxidation of methane to syngas was compared in fixed and fluidised bed reactors. Catalyst activity was found not to be a limiting factor under any experimental conditions and complete oxygen conversions were observed in all tests. In the fixed bed reactor both methane conversion and syngas selectivity were increasing with space velocity as the result of an autothermal effect. Satisfactory control of the catalyst temperature at high space velocities could only be achieved with addition of inert diluent or steam to the feed. Different conversion and selectivity patterns were observed in fluidised bed reactor. Methane conversion and carbon monoxide selectivity were decreasing with increasing gas flow. By contrast, hydrogen selectivity showed distinct maximum at medium space velocities. These results are interpreted in terms of catalyst backmixing and its effect on primary and secondary reactions. Improved temperature control was also achieved in fluidised bed reactor. Several experiments using fluidised bed reactor were carried out at elevated pressures. To eliminate the occurrence of non-catalytic gas phase reactions between methane and oxygen very short feed mixing times (< 1 ms) were employed. Despite these measures the reactor could not be successfully operated at pressures above 0.7 MPa. The implications of these findings for process development are discussed.

  11. Integrated low emission cleanup system for direct coal-fueled turbines (electrostatic agglomeration). Draft final technical report

    SciTech Connect (OSTI)

    Quimby, J.M.; Kumar, K.S.

    1992-12-31T23:59:59.000Z

    The objective of this contract was to investigate the removal of SO{sub x} and particulate matter from direct coal fired combustion gas streams at high temperature and high pressure conditions. This investigation was to be accomplished through a bench scale testing and evaluation program for SO{sub x} removal and the innovative particulate collection concept of particulate growth through electrostatic agglomeration followed by high efficiency mechanical collection. The process goal was to achieve control better than that required by 1979 New Source Performance Standards. During Phase I, the designs of the combustor and gas cleanup apparatus were successfully completed. Hot gas cleanup was designed to be accomplished at temperature levels between 1800{degrees} and 2500{degrees}F at pressures up to 15 atmospheres. The combustor gas flow rate could be varied between 0.2--0.5 pounds per second. The electrostatic agglomerator residence time could be varied between 0.25 to 3 seconds. In Phase II, all components were fabricated, and erected successfully. Test data from shakedown testing was obtained. Unpredictable difficulties in pilot plant erection and shakedown consumed more budget resources than was estimated and as a consequence DOE, METC, decided ft was best to complete the contract at the end of Phase II. Parameters studied in shakedown testing revealed that high-temperature high pressure electrostatics offers an alternative to barrier filtration in hot gas cleanup but more research is needed in successful system integration between the combustor and electrostatic agglomerator.

  12. FEEDSTOCK-FLEXIBLE REFORMER SYSTEM (FFRS) FOR SOLID OXIDE FUEL CELL (SOFC)- QUALITY SYNGAS

    SciTech Connect (OSTI)

    Kelly Jezierski; Andrew Tadd; Johannes Schwank; Roland Kibler; David McLean; Mahesh Samineni; Ryan Smith; Sameer Parvathikar; Joe Mayne; Tom Westrich; Jerry Mader; F. Michael Faubert

    2010-07-30T23:59:59.000Z

    The U.S. Department of Energy National Energy Technology Laboratory funded this research collaboration effort between NextEnergy and the University of Michigan, who successfully designed, built, and tested a reformer system, which produced highquality syngas for use in SOFC and other applications, and a novel reactor system, which allowed for facile illumination of photocatalysts. Carbon and raw biomass gasification, sulfur tolerance of non-Platinum Group Metals (PGM) based (Ni/CeZrO2) reforming catalysts, photocatalysis reactions based on TiO2, and mild pyrolysis of biomass in ionic liquids (ILs) were investigated at low and medium temperatures (primarily 450 to 850 C) in an attempt to retain some structural value of the starting biomass. Despite a wide range of processes and feedstock composition, a literature survey showed that, gasifier products had narrow variation in composition, a restriction used to develop operating schemes for syngas cleanup. Three distinct reaction conditions were investigated: equilibrium, autothermal reforming of hydrocarbons, and the addition of O2 and steam to match the final (C/H/O) composition. Initial results showed rapid and significant deactivation of Ni/CeZrO2 catalysts upon introduction of thiophene, but both stable and unstable performance in the presence of sulfur were obtained. The key linkage appeared to be the hydrodesulfurization activity of the Ni reforming catalysts. For feed stoichiometries where high H2 production was thermodynamically favored, stable, albeit lower, H2 and CO production were obtained; but lower thermodynamic H2 concentrations resulted in continued catalyst deactivation and eventual poisoning. High H2 levels resulted in thiophene converting to H2S and S surface desorption, leading to stable performance; low H2 levels resulted in unconverted S and loss in H2 and CO production, as well as loss in thiophene conversion. Bimetallic catalysts did not outperform Ni-only catalysts, and small Ni particles were found to have lower activities under S-free conditions, but did show less effect of S on performance, in this study. Imidazolium-based ILs, choline chloride compounds and low-melting eutectics of metal nitrates were evaluated, and it was found that, ILs have some capacity to dissolve cellulose and show thermal stability to temperatures where pyrolysis begins, have no vapor pressure, (simplifying product recoveries), and can dissolve ionic metal salts, allowing for the potential of catalytic reactions on breakdown intermediates. Clear evidence of photoactive commercial TiO2 was obtained, but in-house synthesis of photoactive TiO2 proved difficult, as did fixed-bed gasification, primarily due to the challenge of removing the condensable products from the reaction zone quickly enough to prevent additional reaction. Further investigation into additional non-PGM catalysts and ILs is recommended as a follow-up to this work.

  13. Application of high temperature air heaters to advanced power generation cycles

    SciTech Connect (OSTI)

    Thompson, T R [Tennessee Valley Authority, Chattanooga, TN (United States)] [Tennessee Valley Authority, Chattanooga, TN (United States); Boss, W H; Chapman, J N [Tennessee Univ., Tullahoma, TN (United States). Space Inst.] [Tennessee Univ., Tullahoma, TN (United States). Space Inst.

    1992-03-01T23:59:59.000Z

    Recent developments in ceramic composite materials open up the possibility of recuperative air heaters heating air to temperatures well above the feasible with metal tubes. A high temperature air heater (HTAH) has long been recognized as a requirement for the most efficient MHD plants in order to reach high combustor flame temperatures. The application of gas turbines in coal-fired plants of all types has been impeded because of the problems in cleaning exhaust gas sufficiently to avoid damage to the turbine. With a possibility of a HTAH, such plants may become feasible on the basis of air turbine cycles, in which air is compressed and heated in the HTAH before being applied to turbine. The heat exchanger eliminates the need for the hot gas cleanup system. The performance improvement potential of advanced cycles with HTAH application including the air turbine cycle in several variations such as the DOE program on ``Coal-Fired Air Furnace Combined Cycle...,`` variations originated by the authors, and the MHD combined cycle are presented. The status of development of ceramic air heater technology is included.

  14. Particulate removal from high-temperature, high-pressure combustion gases

    SciTech Connect (OSTI)

    Henry, R.F.; Saxena, S.C.; Podolski, W.F.

    1983-10-01T23:59:59.000Z

    The adoption by utilities of coal-fired pressurized fluidized-bed/combined cycle combustion systems for electric power generation depends to a large extent on the development of an efficient and economic cleanup system for the high-temperature, high-pressure combustion gases. For adequate turbine protection, these gases must be sufficiently cleaned to bring particulate erosion and alkali vapor corrosion to a level acceptable to gas turbine manufacturers. At the same time, the total particulate content of the flue gas must be reduced to the limit set by the Environmental Protection Agency. To accomplish particulate removal from a dust-laden gas stream, a number of separation devices have been developed. These include conventional and augmented cyclones; porous metal, fiber, fabric, and ceramic filters, as well as fixed, moving, and fluidized-bed granular filters; and electrostatic precipitators. Several other novel separation devices have been proposed and developed to different degrees such as: contactors using molten salt, metal, or glass, dry scrubbers, acoustic agglomerators, as well as cyclones and granular-bed filters with external electrostatic or magnetic fields. Some of these separation devices in various combinations have been tested in process development units or in hot gas simulators by ANL, CPC, CURL, C-W, Exxon, GE, Westinghouse, etc. The results are discussed and evaluated for PFBC applications.

  15. Development of OTM Syngas Process and Testing of Syngas Derived Ultra-clean Fuels in Diesel Engines and Fuel Cells

    SciTech Connect (OSTI)

    E.T. Robinson; John Sirman; Prasad Apte; Xingun Gui; Tytus R. Bulicz; Dan Corgard; John Hemmings

    2005-05-01T23:59:59.000Z

    This final report summarizes work accomplished in the Program from January 1, 2001 through December 31, 2004. Most of the key technical objectives for this program were achieved. A breakthrough material system has lead to the development of an OTM (oxygen transport membrane) compact planar reactor design capable of producing either syngas or hydrogen. The planar reactor shows significant advantages in thermal efficiency and a step change reduction in costs compared to either autothermal reforming or steam methane reforming with CO{sub 2} recovery. Syngas derived ultra-clean transportation fuels were tested in the Nuvera fuel cell modular pressurized reactor and in International Truck and Engine single cylinder test engines. The studies compared emission and engine performance of conventional base fuels to various formulations of ultra-clean gasoline or diesel fuels. A proprietary BP oxygenate showed significant advantage in both applications for reducing emissions with minimal impact on performance. In addition, a study to evaluate new fuel formulations for an HCCI engine was completed.

  16. Visbreaking-enhanced thermal recovery method utilizing high temperature steam

    SciTech Connect (OSTI)

    Shu, W.R.

    1984-06-26T23:59:59.000Z

    The displacement efficiency of a steam drive process is improved and steam override reduced by rapidly injecting a predetermined amount of high temperature steam via an injection well into the formation to visbreak a portion of the oil in the formation prior to a steam drive wherein steam is injected into the formation via the injection well to displace oil to a spaced-apart production well through which oil is recovered. The visbroken oil provides a more favorable transition of mobility ratio between the phases in the formation thereby reducing viscous fingering and increasing the displacement efficiency of the steam drive. In addition, after a predetermined amount of high temperature steam has been injected into the formation, the formation may be allowed to undergo a soak period prior to the steam drive. The high temperature steam injection and soaking steps may be sequentially repeated for a plurality of cycles.

  17. High-temperature corrosion control of lagged piping system components

    SciTech Connect (OSTI)

    Parks, R. (Dept. of the Navy, Naval Sea Systems Command, Code 05M11, Washington, DC (US)); Kogler, R.A. (Advanced Technology Inc., Arlington, VA (US))

    1990-07-01T23:59:59.000Z

    Over the past several years, the U.S. Navy has stepped up efforts to eliminate corrosion aboard its ships. One of the most effective techniques the Navy has employed is the application of sprayed aluminum for high-temperature corrosion protection. This sacrificial coating has performed well in the corrosion protection of high-temperature lagged steam valves and associated piping systems. Because of the superiority of the sprayed aluminum system over the conventional methods of protection for these piping systems, the Navy has realized considerable cost savings. These savings are the direct result of major reductions in routine maintenance associated with the application of sprayed aluminum coatings for corrosion protection purposes. This article discusses specific U.S. Navy experience with the use of sprayed aluminum coatings for high-temperature applications as well as current Navy practice regarding the use of this corrosion control coating.

  18. HIGH TEMPERATURE HIGH PRESSURE THERMODYNAMIC MEASUREMENTS FOR COAL MODEL COMPOUNDS

    SciTech Connect (OSTI)

    Vinayak N. Kabadi

    1999-02-20T23:59:59.000Z

    It is well known that the fluid phase equilibria can be represented by a number of {gamma}-models , but unfortunately most of them do not function well under high temperature. In this calculation, we mainly investigate the performance of UNIQUAC and NRTL models under high temperature, using temperature dependent parameters rather than using the original formulas. the other feature of this calculation is that we try to relate the excess Gibbs energy G{sup E}and enthalpy of mixing H{sup E}simultaneously. In other words, we will use the high temperature and pressure G{sup E} and H{sup E}data to regress the temperature dependant parameters to find out which model and what kind of temperature dependant parameters should be used.

  19. Thermocouples For High Temperature In-Pile Testing

    SciTech Connect (OSTI)

    J. L. Rempe

    2005-11-01T23:59:59.000Z

    Many advanced nuclear reactor designs require new fuel, cladding and structural materials. Data are needed to characeterize the performance of these new materials in high temperature, oxidizing and radiation conditions. To obtain this data, robust instrumentation is needed htat can survive proposed test conditions. Traditional methods for measuring temperature in-pile degrade at temperatures above 1080 degrees C. Hence, a project was intiated to develop specialized thermocouples for high temperature in-pile applications (see Rempe and Wilkins, 2005). This paper summarizes efforts to develop, fabricate and evaluate these specialized thermocouples.

  20. Measurement of thermodynamic temperature of high temperature fixed points

    SciTech Connect (OSTI)

    Gavrilov, V. R.; Khlevnoy, B. B.; Otryaskin, D. A.; Grigorieva, I. A.; Samoylov, M. L.; Sapritsky, V. I. [All-Russian Research Institute for Optical and Physical Measurements (VNIIOFI), 46 Ozernaya St., Moscow 119361 (Russian Federation)] [All-Russian Research Institute for Optical and Physical Measurements (VNIIOFI), 46 Ozernaya St., Moscow 119361 (Russian Federation)

    2013-09-11T23:59:59.000Z

    The paper is devoted to VNIIOFI's measurements of thermodynamic temperature of the high temperature fixed points Co-C, Pt-C and Re-C within the scope of the international project coordinated by the Consultative Committee for Thermometry working group 5 'Radiation Thermometry'. The melting temperatures of the fixed points were measured by a radiance mode radiation thermometer calibrated against a filter radiometer with known irradiance spectral responsivity via a high temperature black body. This paper describes the facility used for the measurements, the results and estimated uncertainties.

  1. Which Chiral Symmetry is Restored in High Temperature QCD?

    E-Print Network [OSTI]

    Claude Bernard; Tom Blum; Carleton DeTar; Steven Gottlieb; Urs M. Heller; James E. Hetrick; K. Rummukainen; R. Sugar; D. Toussaint; Matthew Wingate

    1996-11-27T23:59:59.000Z

    Sigma models for the high temperature phase transition in quantum chromodynamics (QCD) suggest that at high temperature the SU(N_f) x SU(N_f) chiral symmetry becomes exact, but the anomalous axial U(1) symmetry need not be restored. In numerical lattice simulations, traditional methods for detecting symmetry restoration have sought multiplets in the screening mass spectrum. However, these methods were imprecise and the results, so far, incomplete. With improved statistics and methodology, we are now able to offer evidence for a restoration of the SU(2) x SU(2) chiral symmetry just above the crossover, but not of the axial U(1) chiral symmetry.

  2. Margins in high temperature leak-before-break assessments

    SciTech Connect (OSTI)

    Budden, P.J.; Hooton, D.G.

    1997-04-01T23:59:59.000Z

    Developments in the defect assessment procedure R6 to include high-temperature mechanisms in Leak-before-Break arguments are described. In particular, the effect of creep on the time available to detect a leak and on the crack opening area, and hence leak rate, is discussed. The competing influence of these two effects is emphasized by an example. The application to Leak-before-Break of the time-dependent failure assessment diagram approach for high temperature defect assessment is then outlined. The approach is shown to be of use in assessing the erosion of margins by creep.

  3. Optimum high temperature strength of two-dimensional nanocomposites

    SciTech Connect (OSTI)

    Monclús, M. A.; Molina-Aldareguía, J. M., E-mail: jon.molina@imdea.org [IMDEA Materials Institute, C/Eric Kandel 2, 28906 Getafe, Madrid (Spain); Zheng, S. J.; Mayeur, J. R.; Beyerlein, I. J.; Mara, N. A. [Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Polcar, T. [Czech Technical University in Prague, Technická 2, Prague 6 (Czech Republic); Llorca, J. [IMDEA Materials Institute, C/Eric Kandel 2, 28906 Getafe, Madrid (Spain); Department of Materials Science, Polytechnic University of Madrid, E. T. S. de Ingenieros de Caminos, 28040 Madrid (Spain)

    2013-11-01T23:59:59.000Z

    High-temperature nanoindentation was used to reveal nano-layer size effects on the hardness of two-dimensional metallic nanocomposites. We report the existence of a critical layer thickness at which strength achieves optimal thermal stability. Transmission electron microscopy and theoretical bicrystal calculations show that this optimum arises due to a transition from thermally activated glide within the layers to dislocation transmission across the layers. We demonstrate experimentally that the atomic-scale properties of the interfaces profoundly affect this critical transition. The strong implications are that interfaces can be tuned to achieve an optimum in high temperature strength in layered nanocomposite structures.

  4. SYNTHESIS OF METHACRYLATES FROM COAL-DERIVED SYNGAS

    SciTech Connect (OSTI)

    Jang, B.W.L.; Spivey, J.J.; Gogate, M.R.; Zoeller, J.R.; Colberg, R.D.; Choi, G.N.

    1999-12-01T23:59:59.000Z

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel have developed a novel process for synthesis of methyl methacrylate (MMA) from coal-derived syngas, under a contract from the US Department of Energy/Fossil Energy Technology Center (DOE/FETC). This project has resulted in five US patents (four already published and one pending publication). It has served as the basis for the technical and economic assessment of the production of this high-volume intermediate from coal-derived synthesis gas. The three-step process consists of the synthesis of a propionate from ethylene carbonylation using coal-derived CO, condensation of the propionate with formaldehyde to form methacrylic acid (MAA); and esterification of MAA with methanol to yield MMA. The first two steps, propionate synthesis and condensation catalysis, are the key technical challenges and the focus of the research presented here.

  5. NREL Patents a Catalyst that Removes Syngas Tar, Boosting the Economics of Biofuels (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2013-08-01T23:59:59.000Z

    NREL has patented a catalyst that reforms tar into syngas, a breakthrough that can accelerate the process of getting biomass ready for fuel synthesis and use as a drop-in fuel.

  6. PSO project: 4760 High Temperature PEM Fuel Cell

    E-Print Network [OSTI]

    PSO project: 4760 High Temperature PEM Fuel Cell Final report - Public part - #12;Project, Technical University of Denmark Partners: IRD Fuel Cells A/S Danish Power Systems Aps DONG Energy Authors, and a steady reduction of production cost is also desired (as in general for fuel cells). However, during

  7. High-temperature pressure-coupled ultrasonic waveguide

    DOE Patents [OSTI]

    Caines, M.J.

    1981-02-11T23:59:59.000Z

    A pressure coupled ultrasonic waveguide is provided to which one end may be attached a transducer and at the other end a high temperature material for continuous ultrasonic testing of the material. The ultrasonic signal is coupled from the waveguide into the material through a thin, dry copper foil.

  8. A high temperature furnace The Sample Environment Group

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    ). It is designed to accommodate large samples, and use low quality cooling water. The furnace uses a tantalum heat also minimizing mass at the furnace centre. Tantalum and alumina were specified for these items723 A high temperature furnace The Sample Environment Group Neutron Division, Rutherford Appleton

  9. Electrostatic Interchange Instabilities of a Rotating, High-Temperature Plasma

    E-Print Network [OSTI]

    Mauel, Michael E.

    Electrostatic Interchange Instabilities of a Rotating, High-Temperature Plasma Confined by a Dipole #2 Mach Probe #1 Mach Probe #2 High-field, 0.2 MA-turn Water-cooled Magnet #12;Interchange Modes-sized/global... Fast hot electron interchange instability: drift-resonant transport; Gryokinetics; phase-space holes

  10. High Temperature Gas Reactors Andrew C. Kadak, Ph.D.

    E-Print Network [OSTI]

    ­ fewer problems in accident · Utilizes gas turbine technology · Lower Power Density ­ no meltdownHigh Temperature Gas Reactors Andrew C. Kadak, Ph.D. Professor of the Practice Massachusetts Institute of Technology #12;#12;#12;#12;Presentation Overview · Introduction to Gas Reactors · Pebble Bed

  11. Optical Fiber High Temperature Sensor Instrumentation for Energy Intensive Industries

    SciTech Connect (OSTI)

    Cooper, Kristie L.; Wang, Anbo; Pickrell, Gary R.

    2006-11-14T23:59:59.000Z

    This report summarizes technical progress during the program “Optical Fiber High Temperature Sensor Instrumentation for Energy Intensive Industries”, performed by the Center for Photonics Technology of the Bradley Department of Electrical and Computer Engineering at Virginia Tech. The objective of this program was to use technology recently invented at Virginia Tech to develop and demonstrate the application of self-calibrating optical fiber temperature and pressure sensors to several key energy-intensive industries where conventional, commercially available sensors exhibit greatly abbreviated lifetimes due primarily to environmental degradation. A number of significant technologies were developed under this program, including • a laser bonded silica high temperature fiber sensor with a high temperature capability up to 700°C and a frequency response up to 150 kHz, • the world’s smallest fiber Fabry-Perot high temperature pressure sensor (125 x 20 ?m) with 700°C capability, • UV-induced intrinsic Fabry-Perot interferometric sensors for distributed measurement, • a single crystal sapphire fiber-based sensor with a temperature capability up to 1600°C. These technologies have been well demonstrated and laboratory tested. Our work plan included conducting major field tests of these technologies at EPRI, Corning, Pratt & Whitney, and Global Energy; field validation of the technology is critical to ensuring its usefulness to U.S. industries. Unfortunately, due to budget cuts, DOE was unable to follow through with its funding commitment to support Energy Efficiency Science Initiative projects and this final phase was eliminated.

  12. Vibrational Raman Spectroscopy of High-temperature Superconductors

    E-Print Network [OSTI]

    Nabben, Reinhard

    Vibrational Raman Spectroscopy of High-temperature Superconductors C. Thomsen and G. Kaczmarczyk-temperature Superconductors C. Thomsen and G. Kaczmarczyk Technical University of Berlin, Berlin, Germany 1 INTRODUCTION Raman after the discovery of high- critical-temperature Tc superconductors:2 while reports on Raman scattering

  13. Free energy of Lorentz-violating QED at high temperature

    E-Print Network [OSTI]

    M. Gomes; T. Mariz; J. R. Nascimento; A. Yu. Petrov; A. F. Santos; A. J. da Silva

    2010-02-25T23:59:59.000Z

    In this paper we study the one- and two-loop contribution to the free energy in QED with the Lorentz symmetry breaking introduced via constant CPT-even Lorentz-breaking parameters at the high temperature limit. We find the impact of the Lorentz-violating term for the free energy and carry out a numerical estimation for the Lorentz-breaking parameter.

  14. ANALYSIS OF FUTURE PRICES AND MARKETS FOR HIGH TEMPERATURE SUPERCONDUCTORS

    E-Print Network [OSTI]

    1 ANALYSIS OF FUTURE PRICES AND MARKETS FOR HIGH TEMPERATURE SUPERCONDUCTORS BY JOSEPH MULHOLLAND temperature superconductors (HTS) may impact the national electrical system over the next 25 years dollars. However, the savings from superconductivity are offset somewhat by the high cost of manufacturing

  15. Electronically conductive ceramics for high temperature oxidizing environments

    DOE Patents [OSTI]

    Kucera, G.H.; Smith, J.L.; Sim, J.W.

    1983-11-10T23:59:59.000Z

    This invention pertains to a high temperature, ceramic composition having electronic conductivity as measured by resistivity below about 500 ohm-cm, chemical stability particularly with respect to cathode conditions in a molten carbonate fuel cell, and composed of an alkali metal, transition metal oxide containing a dopant metal in the crystalline structure to replace a portion of the alkali metal or transition metal.

  16. Synthesis of Aliphatic-Aromatic Copolyesters by a High Temperature

    E-Print Network [OSTI]

    Khan, Saad A.

    -aromatic polyesters. #12;Full Paper: Reverse-selective polymer membranes exhibiting high CO2 affinity can be used for purification of H2 in industrial gasification processes. In this work, the phy- sical properties of CO2Synthesis of Aliphatic-Aromatic Copolyesters by a High Temperature Bulk Reaction Between Poly

  17. High-temperature quenching of electrical resistance in graphene interconnects

    E-Print Network [OSTI]

    assuming a current density j=3.9 MA/cm2 and a resistivity =2.2 cm. The self- heating problem is aggravated scale structures.3,4 One of the approaches to mitigate the self-heating prob- lem is to incorporateHigh-temperature quenching of electrical resistance in graphene interconnects Q. Shao, G. Liu, D

  18. POWER-TO-GAS PROCESS WITH HIGH TEMPERATURE ELECTROLYSIS

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    · Transportation of energy from production areas to consumption areas Substitute Natural Gas (methane) Myriam DeP · Use of existing natural gas network · Mid or long term storage · Transportation · Production. Energy background 2. Power-to-Substitute Natural Gas process with high temperature steam electrolysis

  19. High Temperature coatings based on {beta}-NiAI

    SciTech Connect (OSTI)

    Severs, Kevin

    2012-07-10T23:59:59.000Z

    High temperature alloys are reviewed, focusing on current superalloys and their coatings. The synthesis, characerization, and oxidation performance of a NiAl–TiB{sub 2} composite are explained. A novel coating process for Mo–Ni–Al alloys for improved oxidation performance is examined. The cyclic oxidation performance of coated and uncoated Mo–Ni–Al alloys is discussed.

  20. Author's Accepted Manuscript High-temperature-oxidation-induced ordered struc-

    E-Print Network [OSTI]

    Laughlin, David E.

    and turbine power generation system, turbine alloys are exposed to high temperature and an atmosphere comprised of steam, CO2 and O2. While surface and internal oxidation of the alloy takes place-fuel combustion turbine power generation systems are being developed, materials performance of candidate

  1. High Temperature Materials Interim Data Qualification Report FY 2011

    SciTech Connect (OSTI)

    Nancy Lybeck

    2011-08-01T23:59:59.000Z

    Projects for the very high temperature reactor (VHTR) Technology Development Office provide data in support of Nuclear Regulatory Commission licensing of the VHTR. Fuel and materials to be used in the reactor are tested and characterized to quantify performance in high temperature and high fluence environments. The VHTR program has established the Next Generation Nuclear Plant (NGNP) Data Management and Analysis System (NDMAS) to ensure that VHTR data are qualified for use, stored in a readily accessible electronic form, and analyzed to extract useful results. This document focuses on the first NDMAS objective. It describes the High Temperature Materials characterization data stream, the processing of these data within NDMAS, and reports the interim fiscal year (FY) 2011 qualification status of the data. Data qualification activities within NDMAS for specific types of data are determined by the data qualification category assigned by the data generator. The High Temperature Materials data are being collected under the Nuclear Quality Assurance (NQA)-1 guidelines and will be qualified data. For NQA-1 qualified data, the qualification activities include: (1) capture testing to confirm that the data stored within NDMAS are identical to the raw data supplied, (2) accuracy testing to confirm that the data are an accurate representation of the system or object being measured, and (3) documenting that the data were collected under an NQA-1 or equivalent Quality Assurance program. Currently, data from seven test series within the High Temperature Materials data stream have been entered into the NDMAS vault, including tensile tests, creep tests, and cyclic tests. Of the 5,603,682 records currently in the vault, 4,480,444 have been capture passed, and capture testing is in process for the remaining 1,123,238.

  2. Modeling of the reburning process using sewage sludge-derived syngas

    SciTech Connect (OSTI)

    Werle, Sebastian, E-mail: sebastian.werle@polsl.pl [Institute of Thermal Technology, Silesian University of Technology at Gliwice, 44-100 Gliwice, Konarskiego 22 (Poland)

    2012-04-15T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer Gasification provides an attractive method for sewage sludges treatment. Black-Right-Pointing-Pointer Gasification generates a fuel gas (syngas) which can be used as a reburning fuel. Black-Right-Pointing-Pointer Reburning potential of sewage sludge gasification gases was defined. Black-Right-Pointing-Pointer Numerical simulation of co-combustion of syngases in coal fired boiler has been done. Black-Right-Pointing-Pointer Calculation shows that analysed syngases can provide higher than 80% reduction of NO{sub x}. - Abstract: Gasification of sewage sludge can provide clean and effective reburning fuel for combustion applications. The motivation of this work was to define the reburning potential of the sewage sludge gasification gas (syngas). A numerical simulation of the co-combustion process of syngas in a hard coal-fired boiler was done. All calculations were performed using the Chemkin programme and a plug-flow reactor model was used. The calculations were modelled using the GRI-Mech 2.11 mechanism. The highest conversions for nitric oxide (NO) were obtained at temperatures of approximately 1000-1200 K. The combustion of hard coal with sewage sludge-derived syngas reduces NO emissions. The highest reduction efficiency (>90%) was achieved when the molar flow ratio of the syngas was 15%. Calculations show that the analysed syngas can provide better results than advanced reburning (connected with ammonia injection), which is more complicated process.

  3. Evaluation of dust cake filtration at high temperature with effluence from an atmospheric fluidized-bed combustor

    SciTech Connect (OSTI)

    Dennis, R.A.

    1990-08-01T23:59:59.000Z

    In the spring of 1989, two separate test series were simultaneously conducted at the US Department of Energy's (DOE's) Morgantown Energy Technology Center (METC) to examine applied and fundamental behavior of dust cake filtration under high temperature and high pressure (HTHP) conditions. The purpose was to provide information on dust-cake filtration properties to gas stream cleanup researchers associated with the Tidd 70 megawatt (MW) pressurized fluidized-bed combustor (PFBC). The two test facilities included (1) a high-pressure natural-gas combustor with injected particulate, which was fed to two full-size candle filters; and (2) an atmospheric fluidized-bed combustor (AFBC) with coal and limestone sorbent to generate a particulate-laden combustion exhaust gas, which was sent to a single full-size candle filter and a small-scale disc filter. Several major conclusions from these studies are noted below. On average reducing the mean particulate size by 33% and the associated loading carried in the filtrate will increase the dust cake specific flow resistance (K{sub 2}) by 498%. High-temperature and high-pressure filtration can be successfully performed with ceramic candle filters at moderate filtration face velocities and reasonable system pressure drops. Off-line filter cleaning can produce a filter system with a higher apparent permeability than that produced from on-line filter cleaning at the same face velocity. 19 refs., 89 figs., 13 tabs.

  4. Universal Membrane Classification Scheme: Maximizing the Return on High Temperature PEM Membrane Research

    Broader source: Energy.gov [DOE]

    This presentation on maximizing the return of high temperature PEM membrane research was given at the High Temperature Membrane Working Group Meeting in May 2007.

  5. CARISMA: A Networking Project for High Temperature PEMFC MEA Activities in Europe

    Broader source: Energy.gov [DOE]

    This presentation on high temperature proton exchange membrane fuel cells was given at the High Temperature Membrane Working Group Meeting in May 2007.

  6. High-Temperature Thermoelectric Characterization of III–V Semiconductor Thin Films by Oxide Bonding

    E-Print Network [OSTI]

    2010-01-01T23:59:59.000Z

    High-Temperature Thermoelectric Characterization of III–Vfor high-temperature thermoelectric charac- terization ofdiffusion barrier. A thermoelectric material, thin-?lm ErAs:

  7. High-Temperature Zirconia Oxygen Sensor with Sealed Metal/Metal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference...

  8. High-Temperature Components for Rankine-Cycle-Based Waste Heat...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Temperature Components for Rankine-Cycle-Based Waste Heat Recovery Systems on Combustion Engines High-Temperature Components for Rankine-Cycle-Based Waste Heat Recovery...

  9. A Discussion of Conductivity Testing in High Temperature Membranes (lessons learned in assessing transport)

    Broader source: Energy.gov [DOE]

    Presentation on conductivity testing in high temperature membranes given by Jim Boncella of Los Alamos National Laboratory at the High Temperature Membrane Working Group meeting in October 2005.

  10. Thermal Conductivity Enhancement of High Temperature Phase Change Materials for Concentrating Solar Power Plant Applications

    E-Print Network [OSTI]

    Roshandell, Melina

    2013-01-01T23:59:59.000Z

    that can operate with Stirling engines at 42% efficiency andfor high temperature Stirling engines which operates at 42%turbines such as Stirling engines, while high-temperature (>

  11. Nevada National Security Site Cleanup Information Is Just a Click...

    Office of Environmental Management (EM)

    National Security Site Cleanup Information Is Just a Click Away with Computer Map, Database - New Interactive Map Makes NNSS Data More Accessible to the Public Nevada National...

  12. accelerated cleanup risk: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    California at Berkeley, University of 20 Guidelines for Investigation and Cleanup of MTBE and Other Ether-Based Oxygenates Overview CiteSeer Summary: (Sher-- Chapter 812,...

  13. Site Transition Process upon Completion of the Cleanup Mission...

    Office of Environmental Management (EM)

    218: Develop a Fact Sheet on Site Transition at On-going Mission Sites Site Transition Summary: Cleanup Completion to Long-Term Stewardship at Department of Energy...

  14. Paducah Cleanup Milestones | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO2:Introduction toManagementOPAM5 Accretion-of-DutiesPROPERTY3-0127 - In-Cleanup Milestones

  15. Cleanup Progress Report - 2010 | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO OverviewAttachments4 Chairs Meeting - AprilEvents Clean EnergyofDepartment of0 Cleanup

  16. Cleanup Progress Report - 2012 | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO OverviewAttachments4 Chairs Meeting - AprilEvents Clean EnergyofDepartment of02 Cleanup

  17. Cleanup Progress Report - 2013 | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO OverviewAttachments4 Chairs Meeting - AprilEvents Clean EnergyofDepartment of02 Cleanup3

  18. Cleanup Progress Report - 2014 | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO OverviewAttachments4 Chairs Meeting - AprilEvents Clean EnergyofDepartment of02 Cleanup34

  19. Los Alamos National Laboratory names cleanup subcontractors

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated Codes |Is YourAwards Pollution Prevention AwardeesEnvironmentalCleanup

  20. High temperature solar thermal technology: The North Africa Market

    SciTech Connect (OSTI)

    Not Available

    1990-12-01T23:59:59.000Z

    High temperature solar thermal (HTST) technology offers an attractive option for both industrialized and non-industrialized countries to generate electricity and industrial process steam. The purpose of this report is to assess the potential market for solar thermal applications in the North African countries of Algeria, Egypt, Morocco and Tunisia. North Africa was selected because of its outstanding solar resource base and the variety of applications to be found there. Diminishing oil and gas resources, coupled with expanding energy needs, opens a large potential market for the US industry. The US high temperature solar trough industry has little competition globally and could build a large market in these areas. The US is already familiar with certain solar markets in North Africa due to the supplying of substantial quantities of US-manufactured flat plate collectors to this region.

  1. RF properties of high temperature superconductors: Cavity methods

    SciTech Connect (OSTI)

    Portis, A.M. (California Univ., Berkeley, CA (USA)); Cooke, D.W.; Gray, E.R. (Los Alamos National Lab., NM (USA))

    1990-01-01T23:59:59.000Z

    A description of cavities used in the study of the microwave properties of the high-temperature superconductors is followed by a lumped-circuit analysis of the coupling of transmission lines and resonators. The frequency dependence of the reflected and transmitted microwave power and the character of transient cavity response are analyzed. Techniques are discussed for the introduction of samples of the high-temperature superconductors into microwave cavities. Following a discussion of sample surface impedance and sample geometry factor, the connection between surface resistance and cavity Q is examined as well as the connection between cavity frequency shift and surface reactance. Measurement techniques that utilize reflected or transmitted power or transient response are described. 35 refs., 1 fig.

  2. Sealed glass coating of high temperature ceramic superconductors

    DOE Patents [OSTI]

    Wu, Weite (Tainan, TW); Chu, Cha Y. (Garnerville, NY); Goretta, Kenneth C. (Downers Grove, IL); Routbort, Jules L. (Darien, IL)

    1995-01-01T23:59:59.000Z

    A method and article of manufacture of a lead oxide based glass coating on a high temperature superconductor. The method includes preparing a dispersion of glass powders in a solution, applying the dispersion to the superconductor, drying the dispersion before applying another coating and heating the glass powder dispersion at temperatures below oxygen diffusion onset and above the glass melting point to form a continuous glass coating on the superconductor to establish compressive stresses which enhance the fracture strength of the superconductor.

  3. Design of a high temperature hot water central heating system

    SciTech Connect (OSTI)

    Beaumont, E.L.; Johnson, R.C.; Weaver, J.M.

    1981-11-01T23:59:59.000Z

    The paper reviews the conceptual design of a central heating system at Los Alamos Scientific Laboratory. The resource considered for this heating system design was hot dry rock geothermal energy. Design criteria were developed to ensure reliability of energy supply, to provide flexibility for adaptation to multiple energy resources, to make optimum use of existing equipment and to minimize reinvestment cost. A variable temperature peaking high temperature water system was selected for this purpose.

  4. Design manual for high temperature hot water and steam systems

    SciTech Connect (OSTI)

    Cofield, R.E. Jr.

    1984-01-01T23:59:59.000Z

    The author presents aspects of high temperature hot water and steam generating systems. It covers all the calculations that must be made for sizing and then selecting the equipment that will make up an energy system. The author provides essential information on loan analysis, types of fuel, storage requirements, handling facilities, waste disposal, HVAC needs, and back-up systems. Also included are the calculations needed for determining the size of compressors, air pollution devices, fans, filters, and other supplementary equipment.

  5. Furnace Controls Using High Temperature Preheated Combustion Air

    E-Print Network [OSTI]

    Gonzales, J. M.; Rebello, W. J.

    1981-01-01T23:59:59.000Z

    FURNACE CONTROLS USING HIGH TEMPERATURE PREHEATED COMBUSTION AIR Jeffrey M. Gonzalez Wilfred J. Rebello GTE Products Corporation PAR Enterprises, Inc. Towanda, Pennsylvania Fairfax, Virginia ABSTRACT GTE Products Corporation (Towanda... available ratio control apparatus. Various control sys (I) was the development of a different way of looking at combustion. As preheated combustion air temperatures increase, excess air Industrial furnaces generally utilize air as the basic source...

  6. Protective interlayer for high temperature solid electrolyte electrochemical cells

    DOE Patents [OSTI]

    Isenberg, Arnold O. (Forest Hills Boro, PA); Ruka, Roswell J. (Churchill Boro, PA)

    1986-01-01T23:59:59.000Z

    A high temperature, solid electrolyte electrochemical cell is made, having a first and second electrode with solid electrolyte between them, where the electrolyte is formed by hot chemical vapor deposition, where a solid, interlayer material, which is electrically conductive, oxygen permeable, and protective of electrode material from hot metal halide vapor attack, is placed between the first electrode and the electrolyte, to protect the first electrode from the hot metal halide vapors during vapor deposition.

  7. Protective interlayer for high temperature solid electrolyte electrochemical cells

    DOE Patents [OSTI]

    Isenberg, Arnold O. (Forest Hills Boro, PA); Ruka, Roswell J. (Churchill Boro, PA); Zymboly, Gregory E. (Penn Hills Township, Allegheny County, PA)

    1985-01-01T23:59:59.000Z

    A high temperature, solid electrolyte electrochemical cell is made, having a first and second electrode with solid electrolyte between them, where the electrolyte is formed by hot chemical vapor deposition, where a solid, interlayer material, which is electrically conductive, oxygen permeable, and protective of electrode material from hot metal halide vapor attack, is placed between the first electrode and the electrolyte, to protect the first electrode from the hot metal halide vapors during vapor deposition.

  8. Protective interlayer for high temperature solid electrolyte electrochemical cells

    DOE Patents [OSTI]

    Isenberg, Arnold O. (Forest Hills Boro, PA); Ruka, Roswell J. (Churchill Boro, PA)

    1987-01-01T23:59:59.000Z

    A high temperature, solid electrolyte electrochemical cell is made, having a first and second electrode with solid electrolyte between them, where the electrolyte is formed by hot chemical vapor deposition, where a solid, interlayer material, which is electrically conductive, oxygen permeable, and protective of electrode material from hot metal halide vapor attack, is placed between the first electrode and the electrolyte, to protect the first electrode from the hot metal halide vapors during vapor deposition.

  9. Cryocooler applications for high-temperature superconductor magnetic bearings.

    SciTech Connect (OSTI)

    Niemann, R. C.

    1998-05-22T23:59:59.000Z

    The efficiency and stability of rotational magnetic suspension systems are enhanced by the use of high-temperature superconductor (HTS) magnetic bearings. Fundamental aspects of the HTS magnetic bearings and rotational magnetic suspension are presented. HTS cooling can be by liquid cryogen bath immersion or by direct conduction, and thus there are various applications and integration issues for cryocoolers. Among the numerous cryocooler aspects to be considered are installation; operating temperature; losses; and vacuum pumping.

  10. Evolution of sputtered tungsten coatings at high temperature

    SciTech Connect (OSTI)

    Stelmakh, Veronika; Rinnerbauer, Veronika; Joannopoulos, John D.; Solja?i?, Marin; Celanovic, Ivan; Senkevich, Jay J. [Institute for Soldier Nanotechnologies, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)] [Institute for Soldier Nanotechnologies, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States); Tucker, Charles; Ives, Thomas; Shrader, Ronney [Materion Corporation, Buellton, California 93427 (United States)] [Materion Corporation, Buellton, California 93427 (United States)

    2013-11-15T23:59:59.000Z

    Sputtered tungsten (W) coatings were investigated as potential high temperature nanophotonic material to replace bulk refractory metal substrates. Of particular interest are materials and coatings for thermophotovoltaic high-temperature energy conversion applications. For such applications, high reflectance of the substrate in the infrared wavelength range is critical in order to reduce losses due to waste heat. Therefore, the reflectance of the sputtered W coatings was characterized and compared at different temperatures. In addition, the microstructural evolution of sputtered W coatings (1 and 5 ?m thick) was investigated as a function of anneal temperature from room temperature to 1000 °C. Using in situ x-ray diffraction analysis, the microstrain in the two samples was quantified, ranging from 0.33% to 0.18% for the 1 ?m sample and 0.26% to 0.20% for the 5 ?m sample, decreasing as the temperature increased. The grain growth could not be as clearly quantified due to the dominating presence of microstrain in both samples but was in the order of 20 to 80 nm for the 1 ?m sample and 50 to 100 nm for the 5 ?m sample, as deposited. Finally, the 5 ?m thick layer was found to be rougher than the 1 ?m thick layer, with a lower reflectance at all wavelengths. However, after annealing the 5 ?m sample at 900 °C for 1 h, its reflectance exceeded that of the 1 ?m sample and approached that of bulk W found in literature. Overall, the results of this study suggest that thick coatings are a promising alternative to bulk substrates as a low cost, easily integrated platform for nanostructured devices for high-temperature applications, if the problem of delamination at high temperature can be overcome.

  11. High temperature superconductivity in metallic region near Mott transition

    E-Print Network [OSTI]

    Tian De Cao

    2009-09-11T23:59:59.000Z

    The spin-singlet superconductivity without phonons is examined in consideration of correlations on an extended Hubbard model. It is shown that the superconductivity requires not only the total correlation should be strong enough but also the density of state around Fermi energy should be large enough, which shows that the high temperature superconductivity could only be found in the metallic region near the Mott metal insulator transition (MIT). Other properties of superconductors are also discussed on these conclusions.

  12. Deposition method for producing silicon carbide high-temperature semiconductors

    DOE Patents [OSTI]

    Hsu, George C. (La Crescenta, CA); Rohatgi, Naresh K. (W. Corine, CA)

    1987-01-01T23:59:59.000Z

    An improved deposition method for producing silicon carbide high-temperature semiconductor material comprising placing a semiconductor substrate composed of silicon carbide in a fluidized bed silicon carbide deposition reactor, fluidizing the bed particles by hydrogen gas in a mildly bubbling mode through a gas distributor and heating the substrate at temperatures around 1200.degree.-1500.degree. C. thereby depositing a layer of silicon carbide on the semiconductor substrate.

  13. High Temperature Heat Recovery Systems Using Ceramic Recuperators

    E-Print Network [OSTI]

    Young, S. B.; Bjerklie, J. W.; York, W. A.

    1980-01-01T23:59:59.000Z

    HIGH TEMPERATURE HEAT RECOVERY SYSTEMS USING CERAMIC RECUPERATORS S. B. Young, J. W. Bjerklie, W. A. York Hague International South Portland, Maine ABSTRACT i Ceramic shell and tube recuperators capable of providing up to 1800 0 F (980... !HAGUE INTERNATIONAL ? 3 ADAMS STREET , SOUTH PORTLAND, MAINE 04106 2011111-1510 2011199-1341 FIGURE 1 ..__ .._.~_._---_._~ -- _._.- ._-----_._--_._-----_.__.._--- _._--~~~-~~~-~--_._._---~---~-~ .".;,,":;' ESL-IE-80-04-50 Proceedings from...

  14. Biomass Gas Cleanup Using a Therminator

    SciTech Connect (OSTI)

    David C. Dayton; Atish Kataria; Rabhubir Gupta

    2012-03-06T23:59:59.000Z

    The objective of the project is to develop and demonstrate a novel fluidized-bed process module called a �¢����Therminator�¢��� to simultaneously destroy and/or remove tar, NH3 and H2S from raw syngas produced by a fluidized-bed biomass gasifier. The raw syngas contains as much as 10 g/m3 of tar, 4,000 ppmv of NH3 and 100 ppmv of H2S. The goal of the Therminator module would be to use promising regenerable catalysts developed for removing tar, ammonia, and H2S down to low levels (around 10 ppm). Tars are cracked to a non-condensable gas and coke that would deposit on the acid catalyst. We will deposit coke, much like a fluid catalytic cracker (FCC) in a petroleum refinery. The deposited coke fouls the catalyst, much like FCC, but the coke would be burned off in the regenerator and the regenerated catalyst would be returned to the cracker. The rapid circulation between the cracker and regenerator would ensure the availability of the required amount of regenerated catalyst to accomplish our goal. Also, by removing sulfur down to less than 10 ppmv, NH3 decomposition would also be possible in the cracker at 600-700���°C. In the cracker, tar decomposes and lays down coke on the acid sites of the catalyst, NH3 is decomposed using a small amount of metal (e.g., nickel or iron) catalyst incorporated into the catalyst matrix, and H2S is removed by a small amount of a metal oxide (e.g. zinc oxide or zinc titanate) by the H2S-metal oxide reaction to form metal sulfide. After a tolerable decline in activity for these reactions, the catalyst particles (and additives) are transported to the regenerator where they are exposed to air to remove the coke and to regenerate the metal sulfide back to metal oxide. Sulfate formation is avoided by running the regeneration with slightly sub-stoichiometric quantity of oxygen. Following regeneration, the catalyst is transported back to the cracker and the cycling continues. Analogous to an FCC reactor system, rapid cycling will allow the use of very active cracking catalysts that lose activity due to coking within the order of several seconds.

  15. Computational and Experimental Development of Novel High Temperature Alloys

    SciTech Connect (OSTI)

    Kramer, M.J.; Ray, P.K.; and Akinc, M.

    2010-06-29T23:59:59.000Z

    The work done in this paper is based on our earlier work on developing an extended Miedema model and then using it to downselect potential alloy systems. Our approach is to closely couple the semi-empirical methodologies to more accurate ab initio methods to dentify the best candidates for ternary alloying additions. The architectural framework for our material's design is a refractory base metal with a high temperature intermetallic which provides both high temperature creep strength and a source of oxidatively stable elements. Potential refractory base metals are groups IIIA, IVA and VA. For Fossil applications, Ni-Al appears to be the best choice to provide the source of oxidatively stable elements but this system requires a 'boost' in melting temperatures to be a viable candidate in the ultra-high temperature regime (> 1200C). Some late transition metals and noble elements are known to increase the melting temperature of Ni-Al phases. Such an approach suggested that a Mo-Ni-Al system would be a good base alloy system that could be further improved upon by dding Platinum group metals (PGMs). In this paper, we demonstrate the variety of microstructures that can be synthesized for the base alloy system, its oxidation behavior as well as the oxidation behavior of the PGM substituted oxidation resistant B2 NiAl phase.

  16. High Temperature Mechanical Properties of Molybdenum Solid Solution Alloys

    SciTech Connect (OSTI)

    Charit, I.; Murty, K.L. [College of Engineering, North Carolina State University, Raleigh, NC 27695, (United States)

    2006-07-01T23:59:59.000Z

    Demanding material requirements for space nuclear power systems have called for the use of refractory alloys. Molybdenum alloys are such candidate materials because of their good mechanical properties at fairly high temperatures, low neutron capture cross-section, and superior resistance to the attack of liquid metals. However, conventional Mo alloys have low ductility at lower temperatures. Hence, there have been several attempts to improve their viability. One of those approaches has been to alloy Mo with various alloying additions in solid solution, most notably with rhenium (Re). In this study the high temperature deformation behavior of various Mo-X (X Re, W, Nb, Hf) alloys is reviewed. High temperature deformation data for these solid solution alloys are analyzed in the light of existing deformation theories. Alloys with both Class-M and -A type behavior are identified and thus, various mechanisms are found to operate. Sometimes data interpretation becomes difficult due to the presence of second phase particles. Results are compared with unalloyed Mo to bring out the importance of solid solution alloying. (authors)

  17. High temperature gas-cooled reactor: gas turbine application study

    SciTech Connect (OSTI)

    Not Available

    1980-12-01T23:59:59.000Z

    The high-temperature capability of the High-Temperature Gas-Cooled Reactor (HTGR) is a distinguishing characteristic which has long been recognized as significant both within the US and within foreign nuclear energy programs. This high-temperature capability of the HTGR concept leads to increased efficiency in conventional applications and, in addition, makes possible a number of unique applications in both electrical generation and industrial process heat. In particular, coupling the HTGR nuclear heat source to the Brayton (gas turbine) Cycle offers significant potential benefits to operating utilities. This HTGR-GT Application Study documents the effort to evaluate the appropriateness of the HTGR-GT as an HTGR Lead Project. The scope of this effort included evaluation of the HTGR-GT technology, evaluation of potential HTGR-GT markets, assessment of the economics of commercial HTGR-GT plants, and evaluation of the program and expenditures necessary to establish HTGR-GT technology through the completion of the Lead Project.

  18. Sourcebook on high-temperature electronics and instrumentation

    SciTech Connect (OSTI)

    Veneruso, A.F. (ed.)

    1981-10-01T23:59:59.000Z

    This sourcebook summarizes the high-temperature characteristics of a number of commercially available electronic components and materials required in geothermal well-logging instruments that must operate to 275/sup 0/C. The sourcebook is written to provide a starting place for instrument designers, who need to know the high-temperature electronic products that are available and the design and performance limitations of these products. The electronic component information given includes the standard repertoire of passive devices such as resistors, capacitors, and magnetics; the active devices and integrated circuits sections emphasize silicon semiconductor JFETs and CMOS circuits; and, to complete the electronics, interconnections and packaging of hybrid microelectronics are described. Thermal insulation and refrigeration alternatives are also presented in the sourcebook. Finally, instrument housing materials and high-temperature cables and cablehead connectors are listed. This information was compiled as part of the Geothermal Logging Instrumentation Development Program that Sandia National Laboratories conducted for the US Department of Energy's Divison of Geothermal Energy from 1976 to 1981.

  19. Note: Zeeman splitting measurements in a high-temperature plasma

    SciTech Connect (OSTI)

    Golingo, R. P.; Shumlak, U.; Den Hartog, D. J. [Aerospace and Energetics Research Program, University of Washington, Seattle, Washington 98195-2250 (United States)

    2010-12-15T23:59:59.000Z

    The Zeeman effect has been used for measurement of magnetic fields in low-temperature plasma, but the diagnostic technique is difficult to implement in a high-temperature plasma. This paper describes new instrumentation and methodology for simultaneous measurement of the entire Doppler-broadened left and right circularly polarized Zeeman spectra in high-temperature plasmas. Measurements are made using spectra emitted parallel to the magnetic field by carbon impurities in high-temperature plasma. The Doppler-broadened width is much larger than the magnitude of the Zeeman splitting, thus simultaneous recording of the two circularly polarized Zeeman line profiles is key to accurate measurement of the magnetic field in the ZaP Z-pinch plasma device. Spectral data are collected along multiple chords on both sides of the symmetry axis of the plasma. This enables determination of the location of the current axis of the Z-pinch and of lower-bound estimates of the local magnetic field at specific radial locations in the plasma.

  20. Development of High Temperature Capacitor Technology and Manufacturing Capability

    SciTech Connect (OSTI)

    None

    2011-05-15T23:59:59.000Z

    The goal of the Development of High Temperature Capacitor Technology and Manufacturing Capability program was to mature a production-ready supply chain for reliable 250°C FPE (fluorinated polyester) film capacitors by 2011. These high-temperature film capacitors enable both the down hole drilling and aerospace industries by enabling a variety of benefits including: ? Deeper oil exploration in higher temperature and pressure environments ? Enabling power electronic and control equipment to operate in higher temperature environments ? Enabling reduced cooling requirements of electronics ? Increasing reliability and life of capacitors operating below rated temperature ? Enabling capacitors to handle higher electrical losses without overheating. The key challenges to bringing the FPE film capacitors to market have been manufacturing challenges including: ? FPE Film is difficult to handle and wind, resulting in poor yields ? Voltage breakdown strength decreases when the film is wound into capacitors (~70% decrease) ? Encapsulation technologies must be improved to enable higher temperature operation ? Manufacturing and test cycle time is very long As a direct result of this program most of the manufacturing challenges have been met. The FPE film production metalization and winding yield has increased to over 82% from 70%, and the voltage breakdown strength of the wound capacitors has increased 270% to 189 V/?m. The high temperature packaging concepts are showing significant progress including promising results for lead attachments and hermetic packages at 200°C and non-hermetic packages at 250°C. Manufacturing and test cycle time will decrease as the market for FPE capacitors develops.

  1. High Temperature Fuel Cell Performance High Temperature Fuel Cell Performance of of Sulfonated Sulfonated Poly(phenylene Poly(phenylene) Proton) Proton Conducting Conducting Polymers

    Broader source: Energy.gov [DOE]

    Presentation by Sandia National Laboratories to the High Temperature Membrane Working Group Meeting held in Honolulu, Hawaii October 8, 2004.

  2. Flue gas cleanup with hydroxyl radical reactions

    SciTech Connect (OSTI)

    Lee, Y.J.; Pennline, H.W.; Markussen, J.M.

    1990-02-01T23:59:59.000Z

    Electric discharge processes have been intensively tested for application to flue gas cleanup. Among the several means of OH- radical generation grouped as electric discharge, E-Beam irradiation is the one that has been most thoroughly studied. Corona glow discharge, especially pulsed corona glow discharge, on the other hand, has attracted attention recently, and several active research projects are being conducted in the United States, Japan, West Germany, and Italy. Other promising approaches for generating OH radicals efficiently are based on thermal or catalytic decomposition of OH-radical precursors. If mixing problems can be overcome to achieve homogeneous distribution of OH radicals in the flue gas stream, these methods may be applicable to flue gas cleanup. Because of their high OH-radical generation rates and potentially low capital costs, the following three approaches are recommended to be tested for their potential capability to remove SO{sub 2}/NO{sub x}: (1) H{sub 2}/O{sub 2} combustion in a hydrogen torch, (2) thermal decomposition of H{sub 2}O{sub 2}, and (3) catalytic decomposition of H{sub 2}O. Ideally, the OH radicals will convert SO{sub 2} and NO{sub x} to sulfuric acid and nitric acid. These acids or acid precursors would easily be removed from the flue gas by conventional technology, such as spray drying and wet limestone scrubbing. 67 refs., 2 tabs.

  3. Sorption Mechanisms for Mercury Capture in Warm Post-Gasification Gas Clean-Up Systems

    SciTech Connect (OSTI)

    Jost Wendt; Sung Jun Lee; Paul Blowers

    2008-09-30T23:59:59.000Z

    The research was directed towards a sorbent injection/particle removal process where a sorbent may be injected upstream of the warm gas cleanup system to scavenge Hg and other trace metals, and removed (with the metals) within the warm gas cleanup process. The specific objectives of this project were to understand and quantify, through fundamentally based models, mechanisms of interaction between mercury vapor compounds and novel paper waste derived (kaolinite + calcium based) sorbents (currently marketed under the trade name MinPlus). The portion of the research described first is the experimental portion, in which sorbent effectiveness to scavenge metallic mercury (Hg{sup 0}) at high temperatures (>600 C) is determined as a function of temperature, sorbent loading, gas composition, and other important parameters. Levels of Hg{sup 0} investigated were in an industrially relevant range ({approx} 25 {micro}g/m{sup 3}) although contaminants were contained in synthetic gases and not in actual flue gases. A later section of this report contains the results of the complementary computational results.

  4. Enhancements to High Temperature In-Pile Thermocouple Performance

    SciTech Connect (OSTI)

    J.C. Crepeau; J.L. Rempe; J.E. Daw; D.L. Knudson: K.G. Condie; S.C. Wilkins

    2008-03-31T23:59:59.000Z

    A joint University of Idaho (UI) and Idaho National Laboratory (INL) University Nuclear Research Initiative (UNERI) was to initiated to extend initial INL efforts to develop doped molybdenum/niobium alloy High Temperature Irradiation Resistant Thermocouples (HTIR-TCs). The overall objective of this UNERI was to develop recommendations for an optimized thermocouple design for high temperature, long duration, in-pile testing by expanding upon results from initial INL efforts. Tasks to quantify the impact of candidate enhancements, such as alternate alloys, alternate geometries, and alternate thermocouple fabrication techniques, on thermocouple performance were completed at INL's High Temperature Test Laboratory (HTTL), a state of the art facility equipped with specialized equipment and trained staff in the area of high temperature instrumentation development and evaluation. Key results of these evaluations, which are documented in this report, are as follows. The doped molybdenum and Nb-1%Zr, which were proposed in the initial INL HTIR-TC design, were found to retain ductility better than the developmental molybdenum-low niobium alloys and the niobium-low molybdenum alloys evaluated. Hence, the performance and lower cost of the commercially available KW-Mo makes a thermocouple containing KW-Mo and Nb-1%Zr the best option at this time. HTIR-TCs containing larger diameter wires offer the potential to increase HTIR-TC stability and reliability at higher temperatures. HTIR-TC heat treatment temperatures and times should be limited to not more than 100 C above the proposed operating temperatures and to durations of at least 4 to 5 hours. Preliminary investigations suggest that the performance of swaged and loose assembly HTIR-TC designs is similar. However, the swaged designs are less expensive and easier to construct. In addition to optimizing HTIR-TC performance, This UNERI project provided unique opportunities to several University of Idaho students, allowing them to become familiar with the techniques and equipment used for specialized high temperature instrumentation fabrication and evaluation and to author/coauthor several key conference papers and journal articles.

  5. Enhancements to High Temperature In-Pile Thermocouple Performance

    SciTech Connect (OSTI)

    J. C. Crepeau; J. L. Rempe; J. E. Daw; D. L. Knudson; K. G. Condie; S. C. Wilkins

    2008-03-01T23:59:59.000Z

    A joint University of Idaho (UI) and Idaho National Laboratory (INL) University Nuclear Research Initiative (UNERI) was to initiated to extend initial INL efforts to develop doped lybdenum/niobium alloy High Temperature Irradiation Resistant Thermocouples (HTIR-TCs). The overall objective of this UNERI was to develop recommendations for an optimized thermocouple design for high temperature, long duration, in-pile testing by expanding upon results from initial INL efforts. Tasks to quantify the impact of candidate enhancements, such as alternate alloys, alternate geometries, and alternate thermocouple fabrication techniques, on thermocouple performance were completed at INL's High Temperature Test Laboratory (HTTL), a state of the art facility equipped with specialized equipment and trained staff in the area of high temperature instrumentation development and evaluation. Key results of these evaluations, which are documented in this report, are as follows. The doped molybdenum and Nb-1%Zr, which were proposed in the initial INL HTIR-TC design, were found to retain ductility better than the developmental molybdenum-low niobium alloys and the niobium-low molybdenum alloys evaluated. Hence, the performance and lower cost of the commercially available KW-Mo makes a thermocouple containing KW-Mo and Nb-1%Zr the best option at this time. HTIR-TCs containing larger diameter wires offer the potential to increase HTIR-TC stability and reliability at higher temperatures. HTIR-TC heat treatment temperatures and times should be limited to not more than 100 °C above the proposed operating temperatures and to durations of at least 4 to 5 hours. Preliminary investigations suggest that the performance of swaged and loose assembly HTIR-TC designs is similar. However, the swaged designs are less expensive and easier to construct. In addition to optimizing HTIR-TC performance, This UNERI project provided unique opportunities to several University of Idaho students, allowing them to become familiar with the techniques and equipment used for specialized high temperature instrumentation fabrication and evaluation and to author/coauthor several key conference papers and journal articles.

  6. Sensitivity of Fischer-Tropsch Synthesis and Water-Gas Shift Catalysts to Poisons from High-Temperature High-Pressure Entrained-Flow (EF) Oxygen-Blown Gasifier Gasification of Coal/Biomass Mixtures

    SciTech Connect (OSTI)

    Burton Davis; Gary Jacobs; Wenping Ma; Dennis Sparks; Khalid Azzam; Janet Chakkamadathil Mohandas; Wilson Shafer; Venkat Ramana Rao Pendyala

    2011-09-30T23:59:59.000Z

    There has been a recent shift in interest in converting not only natural gas and coal derived syngas to Fischer-Tropsch synthesis products, but also converting biomass-derived syngas, as well as syngas derived from coal and biomass mixtures. As such, conventional catalysts based on iron and cobalt may not be suitable without proper development. This is because, while ash, sulfur compounds, traces of metals, halide compounds, and nitrogen-containing chemicals will likely be lower in concentration in syngas derived from mixtures of coal and biomass (i.e., using entrained-flow oxygen-blown gasifier gasification gasification) than solely from coal, other compounds may actually be increased. Of particular concern are compounds containing alkali chemicals like the chlorides of sodium and potassium. In the first year, University of Kentucky Center for Applied Energy Research (UK-CAER) researchers completed a number of tasks aimed at evaluating the sensitivity of cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts and a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to alkali halides. This included the preparation of large batches of 0.5%Pt-25%Co/Al{sub 2}O{sub 3} and 100Fe: 5.1Si: 3.0K: 2.0Cu (high alpha) catalysts that were split up among the four different entities participating in the overall project; the testing of the catalysts under clean FT and WGS conditions; the testing of the Fe-Cr WGS catalyst under conditions of co-feeding NaCl and KCl; and the construction and start-up of the continuously stirred tank reactors (CSTRs) for poisoning investigations. In the second and third years, researchers from the University of Kentucky Center for Applied Energy Research (UK-CAER) continued the project by evaluating the sensitivity of a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to a number of different compounds, including KHCO{sub 3}, NaHCO{sub 3}, HCl, HBr, HF, H{sub 2}S, NH{sub 3}, and a combination of H{sub 2}S and NH{sub 3}. Cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts were also subjected to a number of the same compounds in order to evaluate their sensitivities at different concentration levels of added contaminant.

  7. Minutes of the October 2008 Meeting of the High Temperature Membrane Working Group

    Broader source: Energy.gov [DOE]

    Meeting minutes of the High Temperature Membrane Working Group from October 16, 2008, in Honolulu, Hawaii.

  8. 11th Topical conference high-temperature plasma diagnostics. Book of abstracts

    SciTech Connect (OSTI)

    NONE

    1996-06-01T23:59:59.000Z

    This report contains abstracts from the 11th topical conference on high-temperature plasma diagnostics.

  9. Numerical Analysis of Non-Uniformities and Anisotropy in High-Temperature Superconducting Coils

    E-Print Network [OSTI]

    Hu, Di; Ainslie, Mark D.; Zou, Jin; Cardwell, David A.

    2014-12-12T23:59:59.000Z

    , critical current density (superconductivity), high-temperature superconductors, numerical analysis, superconducting coils, transport ac loss....

  10. IDAHO OPERATIONS OFFICE NAMES NEW IDAHO CLEANUP PROJECT MANAGER

    Broader source: Energy.gov [DOE]

    Idaho Falls, ID – The Department of Energy Idaho Operations Office today announced that James Cooper has been named deputy manager of its highly-successful Idaho Cleanup Project, which oversees the environmental cleanup and waste management mission at DOE’s Idaho site.

  11. Architecture synthesis basis for the Hanford Cleanup system: First issue

    SciTech Connect (OSTI)

    Holmes, J.J. [comp.

    1994-06-01T23:59:59.000Z

    This document describes a set of candidate alternatives proposed to accomplish the Hanford Cleanup system functions defined in a previous work. Development of alternatives is part of a sequence of system engineering activities which lead to definition of all the products which, when completed, accomplish the cleanup mission. The alternative set is developed to functional level four or higher depending on need.

  12. Advanced High-Temperature, High-Pressure Transport Reactor Gasification

    SciTech Connect (OSTI)

    Michael Swanson; Daniel Laudal

    2008-03-31T23:59:59.000Z

    The U.S. Department of Energy (DOE) National Energy Technology Laboratory Office of Coal and Environmental Systems has as its mission to develop advanced gasification-based technologies for affordable, efficient, zero-emission power generation. These advanced power systems, which are expected to produce near-zero pollutants, are an integral part of DOE's Vision 21 Program. DOE has also been developing advanced gasification systems that lower the capital and operating costs of producing syngas for chemical production. A transport reactor has shown potential to be a low-cost syngas producer compared to other gasification systems since its high-throughput-per-unit cross-sectional area reduces capital costs. This work directly supports the Power Systems Development Facility utilizing the KBR transport reactor located at the Southern Company Services Wilsonville, Alabama, site. Over 2800 hours of operation on 11 different coals ranging from bituminous to lignite along with a petroleum coke has been completed to date in the pilot-scale transport reactor development unit (TRDU) at the Energy & Environmental Research Center (EERC). The EERC has established an extensive database on the operation of these various fuels in both air-blown and oxygen-blown modes utilizing a pilot-scale transport reactor gasifier. This database has been useful in determining the effectiveness of design changes on an advanced transport reactor gasifier and for determining the performance of various feedstocks in a transport reactor. The effects of different fuel types on both gasifier performance and the operation of the hot-gas filter system have been determined. It has been demonstrated that corrected fuel gas heating values ranging from 90 to 130 Btu/scf have been achieved in air-blown mode, while heating values up to 230 Btu/scf on a dry basis have been achieved in oxygen-blown mode. Carbon conversions up to 95% have also been obtained and are highly dependent on the oxygen-coal ratio. Higher-reactivity (low-rank) coals appear to perform better in a transport reactor than the less reactive bituminous coals. Factors that affect TRDU product gas quality appear to be coal type, temperature, and air/coal ratios. Testing with a higher-ash, high-moisture, low-rank coal from the Red Hills Mine of the Mississippi Lignite Mining Company has recently been completed. Testing with the lignite coal generated a fuel gas with acceptable heating value and a high carbon conversion, although some drying of the high-moisture lignite was required before coal-feeding problems were resolved. No ash deposition or bed material agglomeration issues were encountered with this fuel. In order to better understand the coal devolatilization and cracking chemistry occurring in the riser of the transport reactor, gas and solid sampling directly from the riser and the filter outlet has been accomplished. This was done using a baseline Powder River Basin subbituminous coal from the Peabody Energy North Antelope Rochelle Mine near Gillette, Wyoming.

  13. Development of a New Flame Speed Vessel to Measure the Effect of Steam Dilution on Laminar Flame Speeds of Syngas Fuel Blends at Elevated Pressures and Temperatures

    E-Print Network [OSTI]

    Krejci, Michael

    2012-07-16T23:59:59.000Z

    Synthetic gas, syngas, is a popular alternative fuel for the gas turbine industry, but the composition of syngas can contain different types and amounts of contaminants, such as carbon dioxide, methane, moisture, and nitrogen, depending...

  14. Performance of solid oxide fuel cells operaated with coal syngas provided directly from a gasification process

    SciTech Connect (OSTI)

    Hackett, G.; Gerdes, K.; Song, X.; Chen, Y.; Shutthanandan, V.; Englehard, M.; Zhu, Z.; Thevuthasan, S.; Gemmen, R.

    2012-01-01T23:59:59.000Z

    Solid oxide fuel cells (SOFCs) are being developed for integrated gasification power plants that generate electricity from coal at 50% efficiency. The interaction of trace metals in coal syngas with Ni-based SOFC anodes is being investigated through thermodynamic analyses and in laboratory experiments, but test data from direct coal syngas exposure are sparsely available. This effort evaluates the significance of performance losses associated with exposure to direct coal syngas. Specimen are operated in a unique mobile test skid that is deployed to the research gasifier at NCCC in Wilsonville, AL. The test skid interfaces with a gasifier slipstream to deliver hot syngas to a parallel array of twelve SOFCs. During the 500 h test period, all twelve cells are monitored for performance at four current densities. Degradation is attributed to syngas exposure and trace material attack on the anode structure that is accelerated at increasing current densities. Cells that are operated at 0 and 125 mA cm{sup 2} degrade at 9.1 and 10.7% per 1000 h, respectively, while cells operated at 250 and 375 mA cm{sup 2} degrade at 18.9 and 16.2% per 1000 h, respectively. Spectroscopic analysis of the anodes showed carbon, sulfur, and phosphorus deposits; no secondary Ni-metal phases were found.

  15. Dual Phase Membrane for High Temperature CO2 Separation

    SciTech Connect (OSTI)

    Jerry Y.S. Lin; Matthew Anderson

    2006-09-29T23:59:59.000Z

    Dual-phase membranes consisting of stainless steel supports infiltrated with molten carbonate have been shown to be selective to CO{sub 2} at high temperatures (400-650 C). However, over time at high temperatures, the formation of iron oxides on the surface of the stainless steel supports render the membranes ineffective. This report details synthesis and characteristics of dual-phase carbonate membrane with an oxidation resistant perovskite type ceramic (lanthanum-strontium-cobaltite-iron; LSCF) support. Porous LSCF supports were prepared from its powder synthesized by the citrate method. Both steady state permeation and mercury porosimetry confirmed that the LSCF membrane sintered at 900 C has pores large enough to absorb molten carbonate, yet small enough to retain the molten carbonate under high pressure conditions. Results of XRD analysis have shown that LSCF and the molten carbonate mixture do not react with each other at temperatures below 700 C. Four-point method conductivity tests indicate that the support material has sufficiently high electronic conductivity for this application. Li-Na-K carbonate was coated to the porous LSCF support by a liquid infiltration method. Helium permeance of the support before and after infiltration of molten carbonate are on the order of 10{sup -6} and 10{sup -10} moles/m{sup 2} {center_dot} Pa {center_dot} s respectively, indicating that the molten carbonate is able to sufficiently infiltrate the membrane. Preliminary high temperature permeation experiments indicate that the membrane does separate CO{sub 2} in the presence of O{sub 2}, with a maximum flux of 0.623 ml/cm{sup 2} {center_dot} min obtained at 850 C.

  16. Thermal Hydraulics of the Very High Temperature Gas Cooled Reactor

    SciTech Connect (OSTI)

    Chang Oh; Eung Kim; Richard Schultz; Mike Patterson; Davie Petti

    2009-10-01T23:59:59.000Z

    The U.S Department of Energy (DOE) is conducting research on the Very High Temperature Reactor (VHTR) design concept for the Next Generation Nuclear Plant (NGNP) Project. The reactor design will be a graphite moderated, thermal neutron spectrum reactor that will produce electricity and hydrogen in a highly efficient manner. The NGNP reactor core will be either a prismatic graphite block type core or a pebble bed core. The NGNP will use very high-burnup, low-enriched uranium, TRISO-coated fuel, and have a projected plant design service life of 60 years. The VHTR concept is considered to be the nearest-term reactor design that has the capability to efficiently produce hydrogen. The plant size, reactor thermal power, and core configuration will ensure passive decay heat removal without fuel damage or radioactive material releases during reactor core-accidents. The objectives of the NGNP Project are to: Demonstrate a full-scale prototype VHTR that is commercially licensed by the U.S. Nuclear Regulatory Commission, and Demonstrate safe and economical nuclear-assisted production of hydrogen and electricity. The DOE laboratories, led by the INL, perform research and development (R&D) that will be critical to the success of the NGNP, primarily in the areas of: • High temperature gas reactor fuels behavior • High temperature materials qualification • Design methods development and validation • Hydrogen production technologies • Energy conversion. This paper presents current R&D work that addresses fundamental thermal hydraulics issues that are relevant to a variety of possible NGNP designs.

  17. Conductor requirements for high-temperature superconducting utility power transformers

    SciTech Connect (OSTI)

    Pleva, E. F. [Waukesha Electric Systems, Waukesha, WI; Mehrotra, V. [Waukesha Electric Systems, Waukesha, WI; Schwenterly, S W [ORNL

    2010-01-01T23:59:59.000Z

    High-temperature superconducting (HTS) coated conductors in utility power transformers must satisfy a set of operating requirements that are driven by two major considerations-HTS transformers must be economically competitive with conventional units, and the conductor must be robust enough to be used in a commercial manufacturing environment. The transformer design and manufacturing process will be described in order to highlight the various requirements that it imposes on the HTS conductor. Spreadsheet estimates of HTS transformer costs allow estimates of the conductor cost required for an HTS transformer to be competitive with a similarly performing conventional unit.

  18. Oxygen Handling and Cooling Options in High Temperature Electrolysis Plants

    SciTech Connect (OSTI)

    Manohar S. Sohal; J. Stephen Herring

    2008-07-01T23:59:59.000Z

    Idaho National Laboratory is working on a project to generate hydrogen by high temperature electrolysis (HTE). In such an HTE system, safety precautions need to be taken to handle high temperature oxygen at ~830°C. This report is aimed at addressing oxygen handling in a HTE plant.. Though oxygen itself is not flammable, most engineering material, including many gases and liquids, will burn in the presence of oxygen under some favorable physicochemical conditions. At present, an absolute set of rules does not exist that can cover all aspects of oxygen system design, material selection, and operating practices to avoid subtle hazards related to oxygen. Because most materials, including metals, will burn in an oxygen-enriched environment, hazards are always present when using oxygen. Most materials will ignite in an oxygen-enriched environment at a temperature lower than that in air, and once ignited, combustion rates are greater in the oxygen-enriched environment. Even many metals, if ignited, burn violently in an oxygen-enriched environment. However, these hazards do not preclude the operations and systems involving oxygen. Oxygen can be safely handled and used if all the materials in a system are not flammable in the end-use environment or if ignition sources are identified and controlled. In fact, the incidence of oxygen system fires is reported to be low with a probability of about one in a million. This report is a practical guideline and tutorial for the safe operation and handling of gaseous oxygen in high temperature electrolysis system. The intent is to provide safe, practical guidance that permits the accomplishment of experimental operations at INL, while being restrictive enough to prevent personnel endangerment and to provide reasonable facility protection. Adequate guidelines are provided to govern various aspects of oxygen handling associated with high temperature electrolysis system to generate hydrogen. The intent here is to present acceptable oxygen standards and practices for minimum safety requirements. A summary of operational hazards, along with oxygen safety and emergency procedures, are provided.

  19. Langevin dynamics and decoherence of heavy quarks at high temperatures

    E-Print Network [OSTI]

    Akamatsu, Yukinao

    2015-01-01T23:59:59.000Z

    Langevin equation of heavy quarks in high-temperature quark-gluon plasma is derived. The dynamics of heavy quark color is coupled with the phase space dynamics and causes a macroscopic superposition state of heavy quark momentum. Decoherence of the superposition state allows us classical description. The time scale of decoherence gives an appropriate discretization time scale $\\Delta t \\sim \\sqrt{M/\\gamma}$ for the classical Langevin equation, where $M$ is heavy quark mass and $\\gamma$ is heavy quark momentum diffusion constant.

  20. Nearly Perfect Fluidity in a High Temperature Superconductor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rameau, J. D. [Brookhaven National Laboratory (BNL), Upton, NY (United States); Reber, T. J. [Brookhaven National Laboratory (BNL), Upton, NY (United States); Yang, H. -B. [Brookhaven National Laboratory (BNL), Upton, NY (United States); Akhanjee, S. [Brookhaven National Laboratory (BNL), Upton, NY (United States); Gu, G. D. [Brookhaven National Laboratory (BNL), Upton, NY (United States); Johnson, P. D. [Brookhaven National Laboratory (BNL), Upton, NY (United States); Campbell, S. [Iowa State University, Ames, IA (United States)

    2014-10-01T23:59:59.000Z

    Perfect fluids are characterized as having the smallest ratio of shear viscosity to entropy density, ?/s, consistent with quantum uncertainty and causality. So far, nearly perfect fluids have only been observed in the quark-gluon plasma and in unitary atomic Fermi gases, exotic systems that are amongst the hottest and coldest objects in the known universe, respectively. We use angle resolved photoemission spectroscopy to measure the temperature dependence of an electronic analog of ?/s in an optimally doped cuprate high-temperature superconductor, finding it too is a nearly perfect fluid around, and above, its superconducting transition temperature Tc.

  1. Narrowband high temperature superconducting receiver for low frequency radio waves

    DOE Patents [OSTI]

    Reagor, David W. (Los Alamos, NM)

    2001-01-01T23:59:59.000Z

    An underground communicating device has a low-noise SQUID using high temperature superconductor components connected to detect a modulated external magnetic flux for outputting a voltage signal spectrum that is related to the varying magnetic flux. A narrow bandwidth filter may be used to select a portion of the voltage signal spectrum that is relatively free of power line noise to output a relatively low noise output signal when operating in a portion of the electromagnetic spectra where such power line noise exists. A demodulator outputs a communication signal, which may be an FM signal, indicative of a modulation on the modulated external magnetic flux.

  2. Spectroscopy and kinetics of combustion gases at high temperatures

    SciTech Connect (OSTI)

    Hanson, R.K.; Bowman, C.T. [Stanford Univ., CA (United States)

    1993-12-01T23:59:59.000Z

    This program involves two complementary activities: (1) development and application of cw ring dye laser absorption methods for sensitive detection of radical species and measurement of fundamental spectroscopic parameters at high temperatures; and (2) shock tube studies of reaction kinetics relevant to combustion. Species currently under investigation in the spectroscopic portion of the research include NO and CH{sub 3}; this has necessitated the continued operated at wavelengths in the range 210-230 nm. Shock tube studies of reaction kinetics currently are focussed on reactions involving CH{sub 3} radicals.

  3. Design manual. [High temperature heat pump for heat recovery system

    SciTech Connect (OSTI)

    Burch, T.E.; Chancellor, P.D.; Dyer, D.F.; Maples, G.

    1980-01-01T23:59:59.000Z

    The design and performance of a waste heat recovery system which utilizes a high temperature heat pump and which is intended for use in those industries incorporating indirect drying processes are described. It is estimated that use of this heat recovery system in the paper, pulp, and textile industries in the US could save 3.9 x 10/sup 14/ Btu/yr. Information is included on over all and component design for the heat pump system, comparison of prime movers for powering the compressor, control equipment, and system economics. (LCL)

  4. Development of twisted high-temperature superconductor composite conductors

    SciTech Connect (OSTI)

    Christopherson, C.J.; Riley, G.N. Jr. [American Superconductor Corporation, Westborough, Massachusetts 01581 (United States)] [American Superconductor Corporation, Westborough, Massachusetts 01581 (United States)

    1995-04-24T23:59:59.000Z

    Multifilamentary high-temperature superconductor (HTS) composite conductors have been developed for alternating current (ac) applications. A twisted HTS conductor containing the Bi-2223 phase fabricated using a modified powder-in-tube technique is reported. Transport critical current densities of 13 800 and 10 900 A/cm {sup 2} (77 K, self-field, 1 {mu}V/cm) have been achieved for twisted tape and wire conductors with twist pitches of 3.7 and 3.6 mm, respectively. These conductors are strongly linked and are thus suitable for use in ac applications.

  5. High temperature performance of scrap tire rubber modified asphalt concrete

    SciTech Connect (OSTI)

    Coomarasamy, A. [Ministry of Transportation, Downsview, Ontario (Canada); Manolis, S.; Hesp, S. [Queen`s Univ., Kingston, Ontario (Canada)

    1996-12-31T23:59:59.000Z

    Wheel track rutting tests on mixes modified with 30 mesh, 80 mesh, and very fine colloidal crumb rubber particles show that a very significant improvement in performance occurs with a reduction in the rubber particle size. The SHRP binder test for rutting, which was originally developed for homogeneous systems only, does not predict the performance improvement for smaller rubber particles. If these new scrap rubber binder systems are to be used in pavements then rutting tests on the asphalt-aggregate mixture should be conducted in order to accurately predict high temperature performance.

  6. Sealed glass coating of high temperature ceramic superconductors

    DOE Patents [OSTI]

    Wu, W.; Chu, C.Y.; Goretta, K.C.; Routbort, J.L.

    1995-05-02T23:59:59.000Z

    A method and article of manufacture of a lead oxide based glass coating on a high temperature superconductor is disclosed. The method includes preparing a dispersion of glass powders in a solution, applying the dispersion to the superconductor, drying the dispersion before applying another coating and heating the glass powder dispersion at temperatures below oxygen diffusion onset and above the glass melting point to form a continuous glass coating on the superconductor to establish compressive stresses which enhance the fracture strength of the superconductor. 8 figs.

  7. Risk management: Reducing brownfield cleanup costs

    SciTech Connect (OSTI)

    Graves, N.

    1997-08-01T23:59:59.000Z

    Balancing environmental protection with economic vitality is crucial to maintaining competitiveness in world markets. One key initiative that has been identified as important to both environmental protection and the economy is the redevelopment of brownfields. Brownfield redevelopment can stimulate local economies that have been devastated by lost jobs and can recycle industrial land use, thereby preserving undeveloped lands. Many existing brownfield sites appear on the US Environmental Protection Agency`s (EPA) National Priority List (NPL), which designates over 1200 sites and is expected to grow to more than 2000 by the end of the decade. EPA estimates the cost of remediating the sites on the current list will approach $30 billion, with the average cost of remediating a site close to $25 million. Thousands of additional brownfield sites that do not appear on the NPL are listed under state cleanup programs.

  8. Syngas production by plasma treatments of alcohols, bio-oils and wood This article has been downloaded from IOPscience. Please scroll down to see the full text article.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Syngas production by plasma treatments of alcohols, bio-oils and wood This article has been Contact us My IOPscience #12;Syngas production by plasma treatments of alcohols, bio-oils and wood K to recover energy from biomass. The Syngas produced from biomass can be used to power internal combustion

  9. Experimental and theoretical study of exhaust gas fuel reforming of Diesel fuel by a non-thermal arc discharge for syngas production

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    -thermal arc discharge for syngas production A. Lebouvier1,2 , F. Fresnet2 , F. Fabry1 , V. Boch2 , V. Rohani1% and a conversion rate of 95% have been reached which correspond to a syngas dry molar fraction of 25%. For the most and promote H2O and CO2 production. Keywords: Plasma reformer, syngas, diesel fuel reforming, NOx trap. 1

  10. Mn Monolayer Modified Rh for Syngas-to-Ethanol Conversion: A First-Principles Study

    SciTech Connect (OSTI)

    Li, Fengyu [University of Puerto Rico; Jiang, Deen [ORNL; Zeng, X.C. [University of Nebraska, Lincoln; Chen, Zhongfang [University of Puerto Rico

    2012-01-01T23:59:59.000Z

    Rh is unique in its ability to convert syngas to ethanol with the help of promoters. We performed systematic first-principles computations to examine the catalytic performance of pure and Mn modified Rh(100) surfaces for ethanol formation from syngas. CO dissociation on the surface as well as CO insertion between the chemisorbed CH{sub 3} and the surface are the two key steps. The CO dissociation barrier on the Mn monolayer modified Rh(100) surface is remarkably lowered by {approx}1.5 eV compared to that on Rh(100). Moreover, the reaction barrier of CO insertion into the chemisorbed CH{sub 3} group on the Mn monolayer modified Rh(100) surface is 0.34 eV lower than that of methane formation. Thus the present work provides new mechanistic insight into the role of Mn promoters in improving Rh's selectivity to convert syngas to ethanol.

  11. Synthesis of acrylates and Methacrylates from Coal-Derived Syngas

    SciTech Connect (OSTI)

    NONE

    1997-05-12T23:59:59.000Z

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel collectively are developing a novel process for the synthesis of methyl methacrylate (MMA) from coal-derived syngas, under a contract from the U.S. Department of Energy, Federal Energy Technology Center. This three-step process consists of synthesis of a propionate, its condensation with formaldehyde, and esterification of resulting methacrylic acid (MAA) with methanol to produce MMA. Eastman has focused on the propionate synthesis step. The resultant Mo catalysts work efficiently at much less severe conditions (170{degrees}C and 30 atm) than the conventional Ni catalysts (270{degrees} C and 180 atm). Bechtel has performed an extensive cost analysis which shows that Eastman`s propionate synthesis step is competitive with other technologies to produce the anhydride. Eastman and Bechtel have also compared the RTI- Eastman-Bechtel three-step methanol route to five other process routes to MMA. The results show that the product MMA can be produced at 520/lb, for a 250 Mlb/year MMA plant, and this product cost is competitive to all other process routes to MMA, except propyne carbonylation. In the second step, RTI and Eastman have developed active and stable V-SI-P tertiary metal oxide catalysts, Nb/Si0{sub 2}, and Ta/Si0{sub 2} catalysts for condensation of propionic anhydride or propionic acid with formaldehyde. RTI has demonstrated a novel correlation among the catalyst acid-base properties, condensation reaction yield, and long-term catalyst performance. Eastman and Bechtel have used the RTI experimental results of a 20 percent Nb/Si0{sub 2} catalyst, in terms of reactant conversions, MAA selectivities, and MAA yield, for their economic analysis. Recent research focuses on enhancing the condensation reaction yields, a better understanding of the acid-base property correlation and enhancing the catalyst lifetime.

  12. Airfoil Heat Transfer Characteristics in Syngas and Hydrogen Turbines

    SciTech Connect (OSTI)

    Mazzotta, D.W. (Univ. of Pittsburgh); Chyu, M.K. (Univ. of Pittsburgh); Alvin, M.A.

    2007-05-01T23:59:59.000Z

    Hydrogen or coal-derivative syngas turbines promise increased efficiency with exceptionally low NOx emissions compared to the natural gas based turbines. To reach this goal, turbine inlet temperature (TIT) will need to be elevated to a level exceeding 1700°C [1, 2]. The thermal load induced by such a temperature increase alone will lead to immense challenges in maintaining material integrity of turbine components. In addition, as working fluid in the gas path will primarily be steam, possibly mixed with carbon oxides, the aero-thermal characteristic in a hydrogen turbine is expected to be far different from that of air/nitrogen enriched gas stream in a gas turbine. For instance, steam has distinctly higher density and specific heat in comparison to a mixture of air and combustion gases as they are expanded in a conventional gas turbine. Even if the temperature limits remain about the same, the expansion in a hydrogen turbine will have to proceed with a greater enthalpy drop and therefore requires a larger number of stages. This also implies that the flow areas may need to be expanded and blade span to be enlarged. Meanwhile, a greater number of stages and hot surfaces need to be protected. This also suggests that current cooling technology available for modern day gas turbines has to be significantly improved. The ultimate goal of the present study is to systematically investigate critical issues concerning cooling technology as it is applicable to oxy-fuel and hydrogen turbine systems, and the main scope is to develop viable means to estimate the thermal load on the turbine “gas side”, that is eventually to be removed from the “coolant side”, and to comparatively quantify the implication of external heat load and potential thermal barrier coating (TBC) degradation on the component durability and lifing. The analysis is based on two well-tested commercial codes, FLUENT and ANSYS.

  13. High Temperature Irradiation-Resistant Thermocouple Performance Improvements

    SciTech Connect (OSTI)

    Joshua Daw; Joy Rempe; Darrell Knudson; John Crepeau; S. Curtis Wilkins

    2009-04-01T23:59:59.000Z

    Traditional methods for measuring temperature in-pile degrade at temperatures above 1100 şC. To address this instrumentation need, the Idaho National Laboratory (INL) developed and evaluated the performance of a high temperature irradiation-resistant thermocouple (HTIR-TC) that contains alloys of molybdenum and niobium. Data from high temperature (up to 1500 şC) long duration (up to 4000 hours) tests and on-going irradiations at INL’s Advanced Test Reactor demonstrate the superiority of these sensors to commercially-available thermocouples. However, several options have been identified that could further enhance their reliability, reduce their production costs, and allow their use in a wider range of operating conditions. This paper presents results from on-going Idaho National Laboratory (INL)/University of Idaho (UI) efforts to investigate options to improve HTIR-TC ductility, reliability, and resolution by investigating specially-formulated alloys of molybdenum and niobium and alternate diameter thermoelements (wires). In addition, on-going efforts to evaluate alternate fabrication approaches, such as drawn and loose assembly techniques will be discussed. Efforts to reduce HTIR-TC fabrication costs, such as the use of less expensive extension cable will also be presented. Finally, customized HTIR-TC designs developed for specific customer needs will be summarized to emphasize the varied conditions under which these sensors may be used.

  14. Corrosion of ceramics in high temperature steam environments

    SciTech Connect (OSTI)

    Keiser, J.R.; Howell, M. [Oak Ridge National Lab., TN (United States); Gondolfe, J.M.; Arnold, D.T. [Stone & Webster Engineering Corp., Houston, TX (United States)

    1997-02-01T23:59:59.000Z

    Ethylene is one of the principal building blocks in the petrochemical industry, and world-wide production and consumption have been steadily increasing. Production of ethylene is accomplished primarily by the pyrolytic stripping of hydrogen from ethane or a higher molecular weight hydrocarbon. This cracking process, sometimes referred to as steam cracking, is currently accomplished in metallic tubes in high temperature furnaces with a conversion efficiency, for ethane of 60-65%. Operation at significantly higher temperature could increase the efficiency as much as 20%, but materials with better high temperature strength would be required. To help identify suitable materials, tests have been conducted to determine the behavior of selected ceramic materials in environments similar to those anticipated for a high-efficiency, advanced steam cracking system. The effects of exposure on weight change, mechanical strength, and microstructure have been determined in a series of 100 hour tests. In addition, 500 hour tests have been conducted to determine the effect of time on material behavior. From these tests, several strong candidates have been identified.

  15. Microstructure, Processing, Performance Relationships for High Temperature Coatings

    SciTech Connect (OSTI)

    Thomas M. Lillo

    2011-04-01T23:59:59.000Z

    This work evaluates the suitability of iron aluminide coatings for use in high temperature fossil fuel combustion environments, such as boiler applications. The coatings are applied using High Velocity Oxy-Fuel (HVOF) thermal spray techniques. Iron aluminide coatings, with the nominal composition of Fe3Al, were applied to various high temperature structural materials (316 Stainless Steel, 9Cr-1Mo steel and Inconel 600) that typically lack inherent resistance to environmental degradation found in fossil fuel combustion atmospheres. Coating/substrate combinations were subjected to thermal cycling to evaluate the effect of HVOF parameters, coating thickness, substrate material and substrate surface roughness on the resistance to coating delamination and cracking. It was found that substrate surface roughness had a profound influence on the performance of a given substrate/coating system and that surface preparation techniques will need to be tailored to the specific substrate material. Also, higher particle velocity during HVOF thermal spray deposition of the iron aluminide coatings tended to result in better-performing coating/substrate systems with less delamination at the coating/substrate interface. Some combinations of HVOF parameters, coating thickness and substrate materials were found to perform extremely well even at temperatures up to 900oC. However, in some cases, substantial reactions at the interface were observed.

  16. High temperature thermometric phosphors for use in a temperature sensor

    DOE Patents [OSTI]

    Allison, Stephen W. (Knoxville, TN); Cates, Michael R. (Oak Ridge, TN); Boatner, Lynn A. (Oak Ridge, TN); Gillies, George T. (Earlysville, VA)

    1998-01-01T23:59:59.000Z

    A high temperature phosphor consists essentially of a material having the general formula LuPO.sub.4 :Dy.sub.(x),Eu.sub.(y), wherein: 0.1 wt %.ltoreq.x.ltoreq.20 wt % and 0.1 wt %.ltoreq.y.ltoreq.20 wt %. The high temperature phosphor is in contact with an article whose temperature is to be determined. The article having the phosphor in contact with it is placed in the environment for which the temperature of the article is to be determined. The phosphor is excited by a laser causing the phosphor to fluoresce. The emission from the phosphor is optically focused into a beam-splitting mirror which separates the emission into two separate emissions, the emission caused by the dysprosium dopant and the emission caused by the europium dopent. The separated emissions are optically filtered and the intensities of the emission are detected and measured. The ratio of the intensity of each emission is determined and the temperature of the article is calculated from the ratio of the intensities of the separate emissions.

  17. High temperature thermometric phosphors for use in a temperature sensor

    DOE Patents [OSTI]

    Allison, S.W.; Cates, M.R.; Boatner, L.A.; Gillies, G.T.

    1998-03-24T23:59:59.000Z

    A high temperature phosphor consists essentially of a material having the general formula LuPO{sub 4}:Dy{sub (x)},Eu{sub (y)}, wherein: 0.1 wt %{<=}x{<=}20 wt % and 0.1 wt %{<=}y{<=}20 wt %. The high temperature phosphor is in contact with an article whose temperature is to be determined. The article having the phosphor in contact with it is placed in the environment for which the temperature of the article is to be determined. The phosphor is excited by a laser causing the phosphor to fluoresce. The emission from the phosphor is optically focused into a beam-splitting mirror which separates the emission into two separate emissions, the emission caused by the dysprosium dopant and the emission caused by the europium dopant. The separated emissions are optically filtered and the intensities of the emission are detected and measured. The ratio of the intensity of each emission is determined and the temperature of the article is calculated from the ratio of the intensities of the separate emissions. 2 figs.

  18. Baseline Concept Description of a Small Modular High Temperature Reactor

    SciTech Connect (OSTI)

    Hans Gougar

    2014-05-01T23:59:59.000Z

    The objective of this report is to provide a description of generic small modular high temperature reactors (herein denoted as an smHTR), summarize their distinguishing attributes, and lay out the research and development (R&D) required for commercialization. The generic concepts rely heavily on the modular high temperature gas-cooled reactor designs developed in the 1980s which were never built but for which pre-licensing or certification activities were conducted. The concept matured more recently under the Next Generation Nuclear Plant (NGNP) project, specifically in the areas of fuel and material qualification, methods development, and licensing. As all vendor-specific designs proposed under NGNP were all both ‘small’ or medium-sized and ‘modular’ by International Atomic Energy Agency (IAEA) and Department of Energy (DOE) standards, the technical attributes, challenges, and R&D needs identified, addressed, and documented under NGNP are valid and appropriate in the context of Small Modular Reactor (SMR) applications. Although the term High Temperature Reactor (HTR) is commonly used to denote graphite-moderated, thermal spectrum reactors with coolant temperatures in excess of 650oC at the core outlet, in this report the historical term High Temperature Gas-Cooled Reactor (HTGR) will be used to distinguish the gas-cooled technology described herein from its liquid salt-cooled cousin. Moreover, in this report it is to be understood that the outlet temperature of the helium in an HTGR has an upper limit of 950 degrees C which corresponds to the temperature to which certain alloys are currently being qualified under DOE’s ARC program. Although similar to the HTGR in just about every respect, the Very High Temperature Reactor (VHTR) may have an outlet temperature in excess of 950 degrees C and is therefore farther from commercialization because of the challenges posed to materials exposed to these temperatures. The VHTR is the focus of R&D under the Generation IV program and its specific R&D needs will be included in this report when appropriate for comparison. The distinguishing features of the HTGR are the refractory (TRISO) coated particle fuel, the low-power density, graphite-moderated core, and the high outlet temperature of the inert helium coolant. The low power density and fuel form effectively eliminate the possibility of core melt, even upon a complete loss of coolant pressure and flow. The graphite, which constitutes the bulk of the core volume and mass, provides a large thermal buffer that absorbs fission heat such that thermal transients occur over a timespan of hours or even days. As chemically-inert helium is already a gas, there is no coolant temperature or void feedback on the neutronics and no phase change or corrosion product that could degrade heat transfer. Furthermore, the particle coatings and interstitial graphite retain fission products such that the source terms at the plant boundary remain well below actionable levels under all anticipated nominal and off-normal operating conditions. These attributes enable the reactor to supply process heat to a collocated industrial plant with negligible risk of contamination and minimal dynamic coupling of the facilities (Figure 1). The exceptional retentive properties of coated particle fuel in a graphite matrix were first demonstrated in the DRAGON reactor, a European research facility that began operation in 1964.

  19. SIMULTANEOUS PRODUCTION OF HIGH-PURITY HYDROGEN AND SEQUESTRATION-READY CO2 FROM SYNGAS

    SciTech Connect (OSTI)

    Linda Denton; Hana Lorethova; Tomasz Wiltowski; Court Moorefield; Parag Kulkarni; Vladimir Zamansky; Ravi Kumar

    2003-12-01T23:59:59.000Z

    This final report summarizes the progress made on the program ''Simultaneous Production of High-Purity Hydrogen and Sequestration-Ready CO{sub 2} from Syngas (contract number DE-FG26-99FT40682)'', during October 2000 through September of 2003. GE Energy and Environmental Research (GE-EER) and Southern Illinois University (SIU) at Carbondale conducted the research work for this program. This program addresses improved methods to efficiently produce simultaneous streams of high-purity hydrogen and separated carbon dioxide from synthesis gas (syngas). The syngas may be produced through either gasification of coal or reforming of natural gas. The process of production of H{sub 2} and separated CO{sub 2} utilizes a dual-bed reactor and regenerator system. The reactor produces hydrogen and the regenerator produces separated CO{sub 2}. The dual-bed system can be operated under either a circulating fluidized-bed configuration or a cyclic fixed-bed configuration. Both configurations were evaluated in this project. The experimental effort was divided into lab-scale work at SIU and bench-scale work at GE-EER. Tests in a lab-scale fluidized bed system demonstrated the process for the conversion of syngas to high purity H{sub 2} and separated CO{sub 2}. The lab-scale system generated up to 95% H{sub 2} (on a dry basis). Extensive thermodynamic analysis of chemical reactions between the syngas and the fluidized solids determined an optimum range of temperature and pressure operation, where the extent of the undesirable reactions is minimum. The cycling of the process between hydrogen generation and oxygen regeneration has been demonstrated. The fluidized solids did not regenerate completely and the hydrogen purity in the reuse cycle dropped to 70% from 95% (on a dry basis). Changes in morphology and particle size may be the most dominant factor affecting the efficiency of the repeated cycling between hydrogen production and oxygen regeneration. The concept of simultaneous production of hydrogen and separated stream of CO{sub 2} was proved using a fixed bed 2 reactor system at GE-EER. This bench-scale cyclic fixed-bed reactor system designed to reform natural gas to syngas has been fabricated in another coordinated DOE project. This system was modified to reform natural gas to syngas and then convert syngas to H{sub 2} and separated CO{sub 2}. The system produced 85% hydrogen (dry basis).

  20. Tritium research laboratory cleanup and transition project final report

    SciTech Connect (OSTI)

    Johnson, A.J.

    1997-02-01T23:59:59.000Z

    This Tritium Research Laboratory Cleanup and Transition Project Final Report provides a high-level summary of this project`s multidimensional accomplishments. Throughout this report references are provided for in-depth information concerning the various topical areas. Project related records also offer solutions to many of the technical and or administrative challenges that such a cleanup effort requires. These documents and the experience obtained during this effort are valuable resources to the DOE, which has more than 1200 other process contaminated facilities awaiting cleanup and reapplication or demolition.

  1. Update of lessons learned from cleanup projects at Oak Ridge

    SciTech Connect (OSTI)

    Sleeman, R.C. [USDOE Oak Ridge Operations, TN (United States)

    1993-12-31T23:59:59.000Z

    The Oak Ridge Operations (ORO) of the US Department of Energy (DOE) has been actively pursuing environmental cleanup of chemically and radioactively contaminated sites for about 7 years. These cleanup projects are carried out under the regulatory requirements of the US Environmental Protection Agency and the various states in which the remedial sites are located. This paper updates and re-examines some of the successes and failures of Oak Ridge cleanup activities, with the intent of encouraging improvements in the areas of safety, project planning, quality assurance, training, and regulatory interactions in future remedial projects.

  2. Central Plateau Cleanup at DOE's Hanford Site - 12504

    SciTech Connect (OSTI)

    Dowell, Jonathan [US DOE (United States)

    2012-07-01T23:59:59.000Z

    The discussion of Hanford's Central Plateau includes significant work in and around the center of the Hanford Site - located about 7 miles from the Columbia River. The Central Plateau is the area to which operations will be shrunk in 2015 when River Corridor cleanup is complete. This work includes retrieval and disposal of buried waste from miles of trenches; the cleanup and closure of massive processing canyons; the clean-out and demolition to 'slab on grade' of the high-hazard Plutonium Finishing Plant; installation of key groundwater treatment facilities to contain and shrink plumes of contaminated groundwater; demolition of all other unneeded facilities; and the completion of decisions about remaining Central Plateau waste sites. A stated goal of EM has been to shrink the footprint of active cleanup to less than 10 square miles by 2020. By the end of FY2011, Hanford will have reduced the active footprint of cleanup by 64 percent exceeding the goal of 49 percent. By 2015, Hanford will reduce the active footprint of cleanup by more than 90 percent. The remaining footprint reduction will occur between 2015 and 2020. The Central Plateau is a 75-square-mile region near the center of the Hanford Site including the area designated in the Hanford Comprehensive Land Use Plan Environmental Impact Statement (DOE 1999) and Record of Decision (64 FR 61615) as the Industrial-Exclusive Area, a rectangular area of about 20 square miles in the center of the Central Plateau. The Industrial-Exclusive Area contains the 200 East and 200 West Areas that have been used primarily for Hanford's nuclear fuel processing and waste management and disposal activities. The Central Plateau also encompasses the 200 Area CERCLA National Priorities List site. The Central Plateau has a large physical inventory of chemical processing and support facilities, tank systems, liquid and solid waste disposal and storage facilities, utility systems, administrative facilities, and groundwater monitoring wells. As a companion to the Hanford Site Cleanup Completion Framework document, DOE issued its draft Central Plateau Cleanup Completion Strategy in September 2009 to provide an outline of DOE's vision for completion of cleanup activities across the Central Plateau. As major elements of the Hanford cleanup along the Columbia River Corridor near completion, DOE believed it appropriate to articulate the agency vision for the remainder of the cleanup mission. The Central Plateau Cleanup Completion Strategy and the Hanford Site Cleanup Completion Framework were provided to the regulatory community, the Tribal Nations, political leaders, the public, and Hanford stakeholders to promote dialogue on Hanford's future. The Central Plateau Cleanup Completion Strategy describes DOE's vision for completion of Central Plateau cleanup and outlines the decisions needed to achieve the vision. The Central Plateau strategy involves steps to: (1) contain and remediate contaminated groundwater, (2) implement a geographic cleanup approach that guides remedy selection from a plateau-wide perspective, (3) evaluate and deploy viable treatment methods for deep vadose contamination to provide long-term protection of the groundwater, and (4) conduct essential waste management operations in coordination with cleanup actions. The strategy will also help optimize Central Plateau readiness to use funding when it is available upon completion of River Corridor cleanup projects. One aspect of the Central Plateau strategy is to put in place the process to identify the final footprint for permanent waste management and containment of residual contamination within the 20-square-mile Industrial-Exclusive Area. The final footprint identified for permanent waste management and containment of residual contamination should be as small as practical and remain under federal ownership and control for as long as a potential hazard exists. Outside the final footprint, the remainder of the Central Plateau will be available for other uses consistent with the Hanford Comprehensive Land-Use Plan (DOE 1999), while

  3. High performance internal reforming unit for high temperature fuel cells

    DOE Patents [OSTI]

    Ma, Zhiwen (Sandy Hook, CT); Venkataraman, Ramakrishnan (New Milford, CT); Novacco, Lawrence J. (Brookfield, CT)

    2008-10-07T23:59:59.000Z

    A fuel reformer having an enclosure with first and second opposing surfaces, a sidewall connecting the first and second opposing surfaces and an inlet port and an outlet port in the sidewall. A plate assembly supporting a catalyst and baffles are also disposed in the enclosure. A main baffle extends into the enclosure from a point of the sidewall between the inlet and outlet ports. The main baffle cooperates with the enclosure and the plate assembly to establish a path for the flow of fuel gas through the reformer from the inlet port to the outlet port. At least a first directing baffle extends in the enclosure from one of the sidewall and the main baffle and cooperates with the plate assembly and the enclosure to alter the gas flow path. Desired graded catalyst loading pattern has been defined for optimized thermal management for the internal reforming high temperature fuel cells so as to achieve high cell performance.

  4. Theory of intertwined orders in high temperature superconductors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fradkin, Eduardo; Tranquada, John M.; Kivelson, Steven A.

    2015-05-01T23:59:59.000Z

    The electronic phase diagrams of many highly correlated systems, and in particular the cuprate high temperature superconductors, are complex, with many different phases appearing with similar—sometimes identical—ordering temperatures even as material properties, such as a dopant concentration, are varied over wide ranges. This complexity is sometimes referred to as “competing orders.” However, since the relation is intimate, and can even lead to the existence of new phases of matter such as the putative “pair-density-wave,” the general relation is better thought of in terms of “intertwined orders.” We selectively analyze some of the experiments in the cuprates which suggest that essentialmore »aspects of the physics are reflected in the intertwining of multiple orders—not just in the nature of each order by itself. We also summarize and critique several theoretical ideas concerning the origin and implications of this complexity.« less

  5. High Temperature Thermocouples For In-pile Applications

    SciTech Connect (OSTI)

    J. L. Rempe; S. C. Wilkins

    2005-10-01T23:59:59.000Z

    Traditional methods for measuring temperature in-pile degrade at temperatures above 1080 degrees C. Hence, a project has been initiated to explore the use of specialized thermocouples that are composed of materials that are able to withstand higher temperature, in-pile test conditions. Results from efforts to develop, fabricate and evaluate the performance of these specialized thermocouples are reported in this paper. Candidate materials were evaluated for their ability to withstand irradiation, to resit material interactions and to remain ductile at high temperatures. In addition, candidate thermocouples were evaluated based on their resolution over the temperature ranges of interest. Results from these evaluations are reported, and additional on-going development activities are summarized.

  6. Materials for the scavanging of hydrogen at high temperatures

    DOE Patents [OSTI]

    Shepodd, Timothy J. (Livermore, CA); Phillip, Bradley L. (Shaker Heights, OH)

    1997-01-01T23:59:59.000Z

    A hydrogen getter composition comprising a double or triple bonded hydrocarbon with a high melting point useful for removing hydrogen gas, to partial pressures below 0.01 torr, from enclosed spaces and particularly from vessels used for transporting or containing fluids at elevated temperatures. The hydrogen getter compositions disclosed herein and their reaction products will neither melt nor char at temperatures in excess of 100.degree. C. They possess significant advantages over conventional hydrogen getters, namely low risk of fire or explosion, no requirement for high temperature activation or operation, the ability to absorb hydrogen even in the presence of contaminants such as water, water vapor, common atmospheric gases and oil mists and are designed to be disposed within the confines of the apparatus. These getter materials can be mixed with binders, such as fluropolymers, which permit the getter material to be fabricated into useful shapes and/or impart desirable properties such as water repellency or impermeability to various gases.

  7. Materials for the scavanging of hydrogen at high temperatures

    DOE Patents [OSTI]

    Shepodd, Timothy J. (330 Thrasher Ave., Livermore, Alameda County, CA 94550); Phillip, Bradley L. (20976 Fairmount Blvd., Shaker Heights, Cuyahoga County, OH 44120)

    1997-01-01T23:59:59.000Z

    A hydrogen getter composition comprising a double or triple bonded hydrocarbon with a high melting point useful for removing hydrogen gas, to partial pressures below 0.01 torr, from enclosed spaces and particularly from vessels used for transporting or containing fluids at elevated temperatures. The hydrogen getter compostions disclosed herein and their reaction products will neither melt nor char at temperatures in excess of 100C. They possess significant advantages over conventional hydrogen getters, namely low risk of fire or explosion, no requirement for high temperature activation or operation, the ability to absorb hydrogen even in the presence of contaminants such as water, water vapor, common atmospheric gases and oil mists and are designed to be disposed within the confines of the apparatus. These getter materials can be mixed with binders, such as fluropolymers, which permit the getter material to be fabricated into useful shapes and/or impart desirable properties such as water repellency or impermeability to various gases.

  8. Flexible high-temperature pH probe

    DOE Patents [OSTI]

    Bielawski, John C. (Scotia, NY); Outwater, John O. (Cambridge, MA); Halbfinger, George P. (Schenectady, NY)

    2003-04-22T23:59:59.000Z

    A flexible pH probe device is provided for use in hot water and other high temperature environments up to about 590.degree. F. The pH probe includes a flexible, inert tubular probe member, an oxygen anion conducting, solid state electrolyte plug located at the distal end of the tubular member, oxide powder disposed at the distal end of the tubular member; a metal wire extending along the tubular member and having a distal end in contact with the oxide powder so as to form therewith an internal reference electrode; and a compression fitting forming a pressure boundary seal around a portion of the tubular member remote from the distal end thereof. Preferably, the tubular member is made of polytetrafluoroethylene, and the solid state electrolyte plug is made of stabilized zirconia. The flexibility of the probe member enables placement of the electrode into the area of interest, including around corners, into confined areas and the like.

  9. High-Temperature Quantum Coherence from Dissipative Environments

    E-Print Network [OSTI]

    George E. Cragg

    2014-11-14T23:59:59.000Z

    The Feynman-Vernon path integral formalism is used to derive the density matrix of a quantum oscillator that is linearly coupled to an environmental reservoir. Although low-temperature reservoirs thermalize the oscillator to the usual Boltzmann distribution, reservoirs at intermediate temperatures reduce this distribution to a single, coherent ground state. Associated with this state is an imaginary frequency indicating an environment which absorbs energy from the oscillator through the suppression of all excited modes. Further increase of the environmental temperature results again in the thermalization of the quantum oscillator to the expected Boltzmann distribution. Qualitatively, this result could account for high-temperature quantum effects including the superconducting properties of graphite grains as well as the quantum coherence observed in photosynthetic systems.

  10. 9 Cr-- 1 Mo steel material for high temperature application

    DOE Patents [OSTI]

    Jablonski, Paul D; Alman, David; Dogan, Omer; Holcomb, Gordon; Cowen, Christopher

    2012-11-27T23:59:59.000Z

    One or more embodiments relates to a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650.degree. C. The 9 Cr-1 Mo steel has a tempered martensite microstructure and is comprised of both large (0.5-3 .mu.m) primary titanium carbides and small (5-50 nm) secondary titanium carbides in a ratio of. from about 1:1.5 to about 1.5:1. The 9 Cr-1 Mo steel may be fabricated using exemplary austenizing, rapid cooling, and tempering steps without subsequent hot working requirements. The 9 Cr-1 Mo steel exhibits improvements in total mass gain, yield strength, and time-to-rupture over ASTM P91 and ASTM P92 at the temperature and time conditions examined.

  11. Remote high-temperature insulatorless heat-flux gauge

    DOE Patents [OSTI]

    Noel, B.W.

    1993-12-28T23:59:59.000Z

    A remote optical heat-flux gauge for use in extremely high temperature environments is described. This application is possible because of the use of thermographic phosphors as the sensing media, and the omission of the need for an intervening layer of insulator between phosphor layers. The gauge has no electrical leads, but is interrogated with ultraviolet or laser light. The luminescence emitted by the two phosphor layers, which is indicative of the temperature of the layers, is collected and analyzed in order to determine the heat flux incident on the surface being investigated. The two layers of thermographic phosphor must be of different materials to assure that the spectral lines collected will be distinguishable. Spatial heat-flux measurements can be made by scanning the light across the surface of the gauge. 3 figures.

  12. Remote high-temperature insulatorless heat-flux gauge

    DOE Patents [OSTI]

    Noel, Bruce W. (Espanola, NM)

    1993-01-01T23:59:59.000Z

    A remote optical heat-flux gauge for use in extremely high temperature environments is described. This application is possible because of the use of thermographic phosphors as the sensing media, and the omission of the need for an intervening layer of insulator between phosphor layers. The gauge has no electrical leads, but is interrogated with ultraviolet or laser light. The luminescence emitted by the two phosphor layers, which is indicative of the temperature of the layers, is collected and analyzed in order to determine the heat flux incident on the surface being investigated. The two layers of thermographic phosphor must be of different materials to assure that the spectral lines collected will be distinguishable. Spatial heat-flux measurements can be made by scanning the light across the surface of the gauge.

  13. Overview of High-Temperature Electrolysis for Hydrogen Production

    SciTech Connect (OSTI)

    Herring, J. S.; O'Brien, J. E.; Stoots, C. M.; Hartvigsen, J. J.; Petri, M. C.; Carter, J. D.; Bischoff, B. L.

    2007-06-01T23:59:59.000Z

    Over the last five years there has been a growing interest in the use of hydrogen as an energy carrier, particularly to augment transportation fuels and thus reduce our dependence on imported petroleum. Hydrogen is now produced primarily via steam reforming of methane. However, in the long term, methane reforming is not a viable process for the large-scale hydrogen production since such fossil fuel conversion processes consume non-renewable resources and emit greenhouse gases. Nuclear energy can be used to produce hydrogen without consuming fossil fuels and without emitting greenhouse gases through the splitting of water into hydrogen and oxygen. The Nuclear Hydrogen Initiative of the DOE Office of Nuclear Energy is developing three general categories of high temperature processes for hydrogen production: thermochemical, electrolytic and hybrid thermo-electrolytic. This paper introduces the work being done in the development of high temperature electrolysis of steam. High Temperature Electrolysis (HTE) is built on the technology of solid oxide fuel cells (SOFCs), which were invented over a century ago, but which have been most vigorously developed during the last twenty years. SOFCs consume hydrogen and oxygen and produce steam and electricity. Solid Oxide Electrolytic Cells (SOECs) consume electricity and steam and produce hydrogen and oxygen. The purpose of the HTE research is to solve those problems unique to the electrolytic mode of operation, while building further on continuing fuel cell development. ORGANIZATION Experiments have been conducted for the last three years at the Idaho National Laboratory and at Ceramatec, Inc. on the operation of button cells and of progressively larger stacks of planar cells. In addition, the INL has been performing analyses of the cell-scale fluid dynamics and plant-scale flowsheets in order to determine optimum operating conditions and plant configurations. Argonne National Laboratory has been performing experiments for the development of new electrode materials, as well as modeling of the fluid dynamics and flowsheets for comparison with the work being done at the INL. ANL has also been performing diagnostic measures on components form long-duration tests at the INL and Ceramatec to determine the causes for the slow degradation in cell performance. Oak Ridge National Laboratory has been developing high temperature porous membranes for the separation of hydrogen from the residual steam, thus avoiding the need to condense and reheat the steam. The University of Nevada at Las Vegas has been collaborating with ANL on the development of electrode and electrolyte materials and will soon begin to investigate the causes of cell degradation. HTE research also includes NERI projects at the Virginia Polytechnic Institute on the development of toughened SOEC composite seals and at the Georgia Institute of Technology on the microstructural design of SOEC materials. EXPERIMENTAL RESULTS The most recent large-scale test of HTE was performed from June 28 through Sept 22, 2006 at the Ceramatec plant in Salt Lake City. The test apparatus consists of two stacks of 60 cells each in a configuration that will be used in the Integrated Laboratory Scale (ILS) experiment during FY-07. The ILS will contain three modules of four stacks each. The “Half-Module” initially produced 1.2 normal m3of H2/hour and 0.65 Nm3/hr at the end of the 2040-hour continuous test.

  14. Design of High Field Solenoids made of High Temperature Superconductors

    SciTech Connect (OSTI)

    Bartalesi, Antonio; /Pisa U.

    2010-12-01T23:59:59.000Z

    This thesis starts from the analytical mechanical analysis of a superconducting solenoid, loaded by self generated Lorentz forces. Also, a finite element model is proposed and verified with the analytical results. To study the anisotropic behavior of a coil made by layers of superconductor and insulation, a finite element meso-mechanic model is proposed and designed. The resulting material properties are then used in the main solenoid analysis. In parallel, design work is performed as well: an existing Insert Test Facility (ITF) is adapted and structurally verified to support a coil made of YBa{sub 2}Cu{sub 3}O{sub 7}, a High Temperature Superconductor (HTS). Finally, a technological winding process was proposed and the required tooling is designed.

  15. Apparatus and method for high temperature viscosity and temperature measurements

    DOE Patents [OSTI]

    Balasubramaniam, Krishnan (Mississippi State, MS); Shah, Vimal (Houston, TX); Costley, R. Daniel (Mississippi State, MS); Singh, Jagdish P. (Mississippi State, MS)

    2001-01-01T23:59:59.000Z

    A probe for measuring the viscosity and/or temperature of high temperature liquids, such as molten metals, glass and similar materials comprises a rod which is an acoustical waveguide through which a transducer emits an ultrasonic signal through one end of the probe, and which is reflected from (a) a notch or slit or an interface between two materials of the probe and (b) from the other end of the probe which is in contact with the hot liquid or hot melt, and is detected by the same transducer at the signal emission end. To avoid the harmful effects of introducing a thermally conductive heat sink into the melt, the probe is made of relatively thermally insulative (non-heat-conductive) refractory material. The time between signal emission and reflection, and the amplitude of reflections, are compared against calibration curves to obtain temperature and viscosity values.

  16. Theory of intertwined orders in high temperature superconductors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fradkin, Eduardo [Univ. of Illinois at Urbana-Champaign, Urbana, IL (United States); Tranquada, John M. [Brookhaven National Lab. (BNL), Upton, NY (United States); Kivelson, Steven A. [Stanford Univ., Stanford, CA (United States)

    2015-05-01T23:59:59.000Z

    The electronic phase diagrams of many highly correlated systems, and in particular the cuprate high temperature superconductors, are complex, with many different phases appearing with similar—sometimes identical—ordering temperatures even as material properties, such as a dopant concentration, are varied over wide ranges. This complexity is sometimes referred to as “competing orders.” However, since the relation is intimate, and can even lead to the existence of new phases of matter such as the putative “pair-density-wave,” the general relation is better thought of in terms of “intertwined orders.” We selectively analyze some of the experiments in the cuprates which suggest that essential aspects of the physics are reflected in the intertwining of multiple orders—not just in the nature of each order by itself. We also summarize and critique several theoretical ideas concerning the origin and implications of this complexity.

  17. Shock-induced synthesis of high temperature superconducting materials

    DOE Patents [OSTI]

    Ginley, D.S.; Graham, R.A.; Morosin, B.; Venturini, E.L.

    1987-06-18T23:59:59.000Z

    It has now been determined that the unique features of the high pressure shock method, especially the shock-induced chemical synthesis technique, are fully applicable to high temperature superconducting materials. Extraordinarily high yields are achievable in accordance with this invention, e.g., generally in the range from about 20% to about 99%, often in the range from about 50% to about 90%, lower and higher yields, of course, also being possible. The method of this invention involves the application of a controlled high pressure shock compression pulse which can be produced in any conventional manner, e.g., by detonation of a high explosive material, the impact of a high speed projectile or the effect of intense pulsed radiation sources such as lasers or electron beams. Examples and a discussion are presented.

  18. Medium-size high-temperature gas-cooled reactor

    SciTech Connect (OSTI)

    Peinado, C.O.; Koutz, S.L.

    1980-08-01T23:59:59.000Z

    This report summarizes high-temperature gas-cooled reactor (HTGR) experience for the 40-MW(e) Peach Bottom Nuclear Generating Station of Philadelphia Electric Company and the 330-MW(e) Fort St. Vrain Nuclear Generating Station of the Public Service Company of Colorado. Both reactors are graphite moderated and helium cooled, operating at approx. 760/sup 0/C (1400/sup 0/F) and using the uranium/thorium fuel cycle. The plants have demonstrated the inherent safety characteristics, the low activation of components, and the high efficiency associated with the HTGR concept. This experience has been translated into the conceptual design of a medium-sized 1170-MW(t) HTGR for generation of 450 MW of electric power. The concept incorporates inherent HTGR safety characteristics (a multiply redundant prestressed concrete reactor vessel (PCRV), a graphite core, and an inert single-phase coolant) and engineered safety features (core auxiliary cooling, relief valve, and steam generator dump systems).

  19. Damping in high-temperature superconducting levitation systems

    DOE Patents [OSTI]

    Hull, John R. (Sammamish, WA)

    2009-12-15T23:59:59.000Z

    Methods and apparatuses for improved damping in high-temperature superconducting levitation systems are disclosed. A superconducting element (e.g., a stator) generating a magnetic field and a magnet (e.g. a rotor) supported by the magnetic field are provided such that the superconducting element is supported relative to a ground state with damped motion substantially perpendicular to the support of the magnetic field on the magnet. Applying this, a cryostat housing the superconducting bearing may be coupled to the ground state with high damping but low radial stiffness, such that its resonant frequency is less than that of the superconducting bearing. The damping of the cryostat may be substantially transferred to the levitated magnetic rotor, thus, providing damping without affecting the rotational loss, as can be derived applying coupled harmonic oscillator theory in rotor dynamics. Thus, damping can be provided to a levitated object, without substantially affecting the rotational loss.

  20. High temperature concrete composites containing organosiloxane crosslinked copolymers

    DOE Patents [OSTI]

    Zeldin, Arkady (Rego Park, NY); Carciello, Neal (Patchogue, NY); Kukacka, Lawrence (Port Jefferson, NY); Fontana, Jack (Shoreham, NY)

    1980-01-01T23:59:59.000Z

    This invention relates to high temperature polymer concrete composites comprising about 10-30% by weight of a liquid monomer mixture consisting essentially of an organosiloxane polymer crosslinked with an olefinically unsaturated monomer selected from the group consisting of styrene, methyl methacrylate, trimethylolpropane trimethacrylate, triallyl cyanurate, n-phenylmalimide, divinyl benzene and mixtures theroef; and about 70-90% by weight of an inert inorganic filler system containing silica sand and preferably a member selected from the group consisting of portland cement, Fe.sub.2 O.sub.3, carbon black and mixtures thereof; and optionally a free radical initiator such as di-tert-butyl peroxide, azobisisobutyronitrile, benzoyl peroxide, lauryl peroxide and other organic peroxides to initiate crosspolymerization of the monomer mixture in the presence of the inorganic filler.

  1. Assessment of microelectronics packaging for high temperature, high reliability applications

    SciTech Connect (OSTI)

    Uribe, F.

    1997-04-01T23:59:59.000Z

    This report details characterization and development activities in electronic packaging for high temperature applications. This project was conducted through a Department of Energy sponsored Cooperative Research and Development Agreement between Sandia National Laboratories and General Motors. Even though the target application of this collaborative effort is an automotive electronic throttle control system which would be located in the engine compartment, results of this work are directly applicable to Sandia`s national security mission. The component count associated with the throttle control dictates the use of high density packaging not offered by conventional surface mount. An enabling packaging technology was selected and thermal models defined which characterized the thermal and mechanical response of the throttle control module. These models were used to optimize thick film multichip module design, characterize the thermal signatures of the electronic components inside the module, and to determine the temperature field and resulting thermal stresses under conditions that may be encountered during the operational life of the throttle control module. Because the need to use unpackaged devices limits the level of testing that can be performed either at the wafer level or as individual dice, an approach to assure a high level of reliability of the unpackaged components was formulated. Component assembly and interconnect technologies were also evaluated and characterized for high temperature applications. Electrical, mechanical and chemical characterizations of enabling die and component attach technologies were performed. Additionally, studies were conducted to assess the performance and reliability of gold and aluminum wire bonding to thick film conductor inks. Kinetic models were developed and validated to estimate wire bond reliability.

  2. Single-Step Syngas-to-Distillates (S2D) Process Based on Biomass-Derived Syngas – A Techno-Economic Analysis

    SciTech Connect (OSTI)

    Zhu, Yunhua; Jones, Susanne B.; Biddy, Mary J.; Dagle, Robert A.; Palo, Daniel R.

    2012-08-01T23:59:59.000Z

    This study reports the comparison of biomass gasification based syngas-to-distillate (S2D) systems using techno-economic analysis (TEA). Three cases, state of technology (SOT) case, goal case, and conventional case, were compared in terms of performance and cost. The SOT case and goal case represent technology being developed at Pacific Northwest National Laboratory for a process starting with syngas using a single-step dual-catalyst reactor for distillate generation (S2D process). The conventional case mirrors the two-step S2D process previously utilized and reported by Mobil using natural gas feedstock and consisting of separate syngas-to-methanol and methanol-to-gasoline (MTG) processes. Analysis of the three cases revealed that the goal case could indeed reduce fuel production cost over the conventional case, but that the SOT was still more expensive than the conventional. The SOT case suffers from low one-pass yield and high selectivity to light hydrocarbons, both of which drive up production cost. Sensitivity analysis indicated that light hydrocarbon yield, single pass conversion efficiency, and reactor space velocity are the key factors driving the high cost for the SOT case.

  3. Single-Step Syngas-to-Distillates (S2D) Process Based on Biomass-Derived Syngas - A Techno-Economic Analysis

    SciTech Connect (OSTI)

    Zhu, Y.; Jones, S. B.; Biddy, M. J.; Dagle, R. A.; Palo, D. R.

    2012-08-01T23:59:59.000Z

    This study compared biomass gasification based syngas-to-distillate (S2D) systems using techno-economic analysis (TEA). Three cases, state of technology (SOT), goal, and conventional, were compared in terms of performance and cost. The SOT case represented the best available experimental results for a process starting with syngas using a single-step dual-catalyst reactor for distillate generation. The conventional case mirrored a conventional two-step S2D process consisting of separate syngas-to-methanol and methanol-to-gasoline (MTG) processes. The goal case assumed the same performance as the conventional, but with a single-step S2D technology. TEA results revealed that the SOT was more expensive than the conventional and goal cases. The SOT case suffers from low one-pass yield and high selectivity to light hydrocarbons, both of which drive up production cost. Sensitivity analysis indicated that light hydrocarbon yield and single pass conversion efficiency were the key factors driving the high cost for the SOT case.

  4. SYNTHESIS OF METHYL METHACRYLATE FROM COAL-DERIVED SYNGAS

    SciTech Connect (OSTI)

    Makarand R. Gogate; James J. Spivey; Joseph R. Zoeller; Richard D. Colberg; Gerald N. Choi

    1999-07-19T23:59:59.000Z

    Research Triangle Institute (RTI), Eastman Chemical Company, and Bechtel collectively are developing a novel three-step process for the synthesis of methyl methacrylate (MMA) from coal-derived syngas that consists of the steps of synthesis of a propionate, its condensation with formaldehyde to form methacrylic acid (MAA), and esterification of MAA with methanol to produce MMA. The research team has completed the research on the three-step methanol-based route to MMA. Under an extension to the original contract, we are currently evaluating a new DME-based process for MMA. The key research need for DME route is to develop catalysts for DME partial oxidation reactions and DME condensation reactions. During the April-June quarter(04-06/99) the first in-situ formaldehyde generation from DME and condensation with methyl propionate is demonstrated and the results are summarized. The supported niobium catalyst shows better condensation activity, but supported tungsten catalyst has higher formaldehyde selectivity. The project team has also completed a 200-hour long term test of PA-HCHO condensation over 30% Nb{sub 2}O{sub 5}/SiO{sub 2}. Three activity cycles and two regeneration cycles were carried out. 30% Nb{sub 2}O{sub 5}/SiO{sub 2} showed similar MAA yields as 10% Nb{sub 2}O{sub 5}/SiO{sub 2} at 300 C. However, the deactivation appears to be slower with 30% Nb{sub 2}O{sub 5}/SiO{sub 2} than 10% Nb{sub 2}O{sub 5}/SiO{sub 2}. An detailed economic analysis of PA-HCHO condensation process for a 250 million lb/yr MMA plant is currently studied by Bechtel. Using the Amoco data-based azeotropic distillation model as the basis, an ASPEN flow sheet model was constructed to simulate the formaldehyde and propionic acid condensation processing section based on RTI's design data. The RTI MAA effluent azeotropic distillation column was found to be much more difficult to converge. The presence of non-condensible gases along with the byproduct DEK (both of which were not presented in Amoco's data) appear to the culprits.

  5. High Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Presentation. Project objectives: Design, demonstrate, and qualify high-temperature high pressure zonal isolation devices compatible with the high temperature downhole Enhanced Geothermal Systems (EGS) environment.

  6. Corrosion in Very High-Temperature Molten Salt for Next Generation...

    Broader source: Energy.gov (indexed) [DOE]

    Corrosion in Very High-Temperature Molten Salt for Next Generation CSP Systems Corrosion in Very High-Temperature Molten Salt for Next Generation CSP Systems This presentation was...

  7. Lithium Diffusion in Li4Ti5O12 at High Temperatures. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithium Diffusion in Li4Ti5O12 at High Temperatures. Lithium Diffusion in Li4Ti5O12 at High Temperatures. Abstract: Synthesis of the spinel lithium titanate Li4Ti5O12 by an...

  8. New Polymeric Proton Conductors for Water-free and High-temperature...

    Broader source: Energy.gov (indexed) [DOE]

    New Polymeric Proton Conductors for Water-free and High-temperature Fuel Cells New Polymeric Proton Conductors for Water-free and High-temperature Fuel Cells Presentation on New...

  9. Development of high-temperature ferromagnetism in SnO2 and paramagneti...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    high-temperature ferromagnetism in SnO2 and paramagnetism in SnO by Fe doping. Development of high-temperature ferromagnetism in SnO2 and paramagnetism in SnO by Fe doping....

  10. Enhanced high temperature performance of MgAl2O4-supported Pt...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    high temperature performance of MgAl2O4-supported Pt-BaO lean NOx trap catalysts. Enhanced high temperature performance of MgAl2O4-supported Pt-BaO lean NOx trap catalysts....

  11. Development of High-Temperature Ferromagnetism in SnO and Paramagnetis...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High-Temperature Ferromagnetism in SnO and Paramagnetism in SnO by Fe Doping. Development of High-Temperature Ferromagnetism in SnO and Paramagnetism in SnO by Fe Doping. Abstract:...

  12. CF8C PLus: A New Cast Stainless Steel for High-Temperature Diesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CF8C PLus: A New Cast Stainless Steel for High-Temperature Diesel Exhaust Components CF8C PLus: A New Cast Stainless Steel for High-Temperature Diesel Exhaust Components...

  13. High Temperature/Low Humidity Polymer Electrolytes Derived from Ionic Liquids

    Broader source: Energy.gov [DOE]

    Presentation on High Temperature/Low Humidity Polymer Electrolytes Derived from Ionic Liquids to the High Temperature Membrane Working Group Meeting held in Arlington, Virginia, May 26,2005.

  14. SUPERCONDUCTIVITY PROGRAM RESEARCH AND DEVELOPMENT High Temperature Superconductivity (HTS) is a technology with the potential

    E-Print Network [OSTI]

    #12;SUPERCONDUCTIVITY PROGRAM RESEARCH AND DEVELOPMENT High Temperature Superconductivity (HTS-of-way. The Department of Energy's efforts to advance High Temperature Superconductivity combine major national strengths: the Superconductivity Partnership Initiative (SPI), the 2nd Generation Wire Initiative

  15. New Polymeric Proton Conductors for Water-free and High-temperature Fuel Cells

    Broader source: Energy.gov [DOE]

    Presentation on New Polymeric Proton Conductors for Water-free and High-temperature Fuel Cells to the High Temperature Membrane Working Group Meeting held in Arlington, Virginia, May 26,2005.

  16. Recovery Act Workers Accomplish Cleanup of Second Cold War Coal...

    Office of Environmental Management (EM)

    June 21, 2011 Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Basin AIKEN, S.C. - American Recovery and Reinvestment Act workers re- cently cleaned up a second...

  17. PPPL's Earth Week features Colloquium on NYC green plan, cleanup...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PPPL's Earth Week features Colloquium on NYC green plan, cleanup and awards By Jeanne Jackson DeVoe April 28, 2014 Tweet Widget Google Plus One Share on Facebook Volunteers clean...

  18. Idaho Site Advances Recovery Act Cleanup after Inventing Effective Treatment

    Broader source: Energy.gov [DOE]

    For the first time in history, workers at the Idaho site achieved success in the initial cleanup of potentially dangerous sodium in a decommissioned nuclear reactor using an innovative treatment...

  19. Radiation site cleanup regulation: An interim progress report

    SciTech Connect (OSTI)

    Not Available

    1994-02-01T23:59:59.000Z

    On October 18 and 19, 1993, the 13 members of the National Advisory Council on Environmental Policy and Technology (NACEPT) Subcommittee on Radiation Site Cleanup Regulations met in Washington D.C. at the invitation of EPA. The Subcommittee discussed a variety of topics relevant to the cleanup of sites contaminated with radiation, and to the regulations which EPA will promulgate to establish cleanup levels for radioactive sites. This Interim Progress Report: condenses and summarizes the major themes, issues, and concerns brought up during the NACEPT Subcommittee meeting in October; Provides a brief description of current Agency thinking regarding each of the major topic areas discussed by the NACEPT Subcommittee; and Serves as a discussion guide for NACEPT Subcommittee members. Four major topics were discussed by the NACEPT Subcommittee members during their first meeting in October 1993: Common Themes; Risk (or Cleanup Levels and Risk Levels); Future Land Use and Local Statutes; and Site-Specific Public Involvement.

  20. NREL Particle Receiver Will Enable High-Temperature CSP (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-08-01T23:59:59.000Z

    Near-blackbody enclosed particle receiver can support high-temperature thermal energy storage and high-efficiency power cycles.

  1. High-Temperature Circuit Boards for Use in Geothermal Well Monitoring Applications

    Broader source: Energy.gov [DOE]

    Project objective: Develop and demonstrate high-temperature; multilayer electronic circuits capable of sustained operation at 300? C.

  2. Performance and Reliability of Bonded Interfaces for High-Temperature Packaging (Presentation)

    SciTech Connect (OSTI)

    Devoto, D.

    2014-06-01T23:59:59.000Z

    This presentation reviews the status of the performance and reliability of bonded interfaces for high-temperature packaging.

  3. Membrane Development for Medium and High Temperature PEMFC in Europe (Presentation)

    Broader source: Energy.gov [DOE]

    Presented at the High Temperature Membrane Working Group Meeting (HTMWG) held October 10, 2007 in Washington, D.C.

  4. High-Temperature Air-Cooled Power Electronics Thermal Design (Presentation)

    SciTech Connect (OSTI)

    Waye, S.

    2014-06-01T23:59:59.000Z

    This presentation discusses the status of research at NREL on high temperature air-cooled power electronics thermal design.

  5. Cleanup Verification Package for the118-F-2 Burial Ground

    SciTech Connect (OSTI)

    J. M. Capron and K. A. Anselm

    2008-02-21T23:59:59.000Z

    This cleanup verification package documents completion of remedial action, sampling activities, and compliance with cleanup criteria for the 118-F-2 Burial Ground. This burial ground, formerly called Solid Waste Burial Ground No. 1, was the original solid waste disposal site for the 100-F Area. Eight trenches contained miscellaneous solid waste from the 105-F Reactor and one trench contained solid waste from the biology facilities.

  6. Composite filter aids for cleanup of additives

    SciTech Connect (OSTI)

    Rudenko, L.I.; Sklyar, V.Y.

    1984-03-01T23:59:59.000Z

    This article examines the properties of composite filter aids in additive cleanup using two- and three-component filter aid composites based on perlite, kieselguhr, diatomite, asbestos, and wood flour. Filtration tests were run on naphtha solutions of the additive zinc dialkyldithiophosphate. The laboratory studies indicate that composites of perlite and kieselguhr with fibrous materials (wood flour or asbestos) show great promise for the removal of solid contaminants from the zinc disalkydithiophosphate additive. The advantages of the filter aid composite based on perlite, kieselguhr, and wood flour in comparison with the two-component composites are the higher filtration rate (by 26%) and the smaller losses of additive (by a factor of 2.1) and isobutyl alcohol (by a factor of 1.6). It is demonstrated that the filtration rate with the three components is 50-60% higher than with the composite of perlite with kieselguhr. The filtration of the zinc dialkyldithiophosphate additive using the composite filter aid based on perlite, kieselguhr, and wood flour, has been adopted at the Volgograd Petroleum Refinery. Includes 2 tables.

  7. HIGH TEMPERATURE IRRADIATION RESISTANT THERMOCOUPLES – A LOW COST SENSOR FOR IN-PILE TESTING AT HIGH TEMPERATURES

    SciTech Connect (OSTI)

    Joy L. Rempe; Darrell L. Knudson; Keith G. Condie; S. Curtis Wilkins; Joshua E. Daw

    2008-06-01T23:59:59.000Z

    Several options have been identified to improve recently-developed Idaho National Laboratory (INL) High Temperature Irradiation Resistant ThermoCouples (HTIR-TCs) for in-pile testing. These options have the potential to reduce fabrication costs and allow HTIR-TC use in higher temperature applications (up to at least 1800 °C). The INL and the University of Idaho (UI) investigated these options with the ultimate objective of providing recommendations for alternate thermocouple designs that are optimized for various applications. This paper summarizes results from these INL/UI investigations. Specifically, results are reported about several options found to enhance HTIR-TC performance, such as improved heat treatments, alternate geometries, alternate fabrication techniques, and the use of copper/nickel alloys as soft extension cable.

  8. Heterogeneous catalytic process for alcohol fuels from syngas. Final technical report

    SciTech Connect (OSTI)

    Dombek, B.D.

    1996-03-01T23:59:59.000Z

    The primary objective of this project has been the pursuit of a catalyst system which would allow the selective production from syngas of methanol and isobutanol. It is desirable to develop a process in which the methanol to isobutanol weight ratio could be varied from 70/30 to 30/70. The 70/30 mixture could be used directly as a fuel additive, while, with the appropriate downstream processing, the 30/70 mixture could be utilized for methyl tertiary-butyl ether (MTBE) synthesis. The indirect manufacture of MTBE from a coal derived syngas to methanol and isobutanol process would appear to be a viable solution to MTBE feedstock limitations. To become economically attractive, a process fro producing oxygenates from coal-derived syngas must form these products with high selectivity and good rates, and must be capable of operating with a low-hydrogen-content syngas. This was to be accomplished through extensions of known catalyst systems and by the rational design of novel catalyst systems.

  9. Computer Control of a Syngas Complex at LaPorte, Texas

    E-Print Network [OSTI]

    Chatterjee, N.

    1981-01-01T23:59:59.000Z

    Air Products and Chemicals has successfully implemented a mini-computer monitoring and control system at its LaPorte Syngas Complex as an integral part of its energy management strategy. The production complex consists of two separate plants at La...

  10. Economic analysis and assessment of syngas production using a modeling approach

    SciTech Connect (OSTI)

    Kim, Hakkwan; Parajuli, Prem B.; Yu, Fei; Columbus, Eugene P.

    2011-08-10T23:59:59.000Z

    Economic analysis and modeling are essential and important issues for the development of current feedstock and process technology for bio-gasification. The objective of this study was to develop an economic model and apply to predict the unit cost of syngas production from a micro-scale bio-gasification facility. An economic model was programmed in C++ computer programming language and developed using a parametric cost approach, which included processes to calculate the total capital costs and the total operating costs. The model used measured economic data from the bio-gasification facility at Mississippi State University. The modeling results showed that the unit cost of syngas production was $1.217 for a 60 Nm-3 h-1 capacity bio-gasifier. The operating cost was the major part of the total production cost. The equipment purchase cost and the labor cost were the largest part of the total capital cost and the total operating cost, respectively. Sensitivity analysis indicated that labor costs rank the top as followed by equipment cost, loan life, feedstock cost, interest rate, utility cost, and waste treatment cost. The unit cost of syngas production increased with the increase of all parameters with exception of loan life. The annual cost regarding equipment, labor, feedstock, waste treatment, and utility cost showed a linear relationship with percent changes, while loan life and annual interest rate showed a non-linear relationship. This study provides the useful information for economic analysis and assessment of the syngas production using a modeling approach.

  11. Characterization of Composite Cores for High Temperature-Low Sag (HTLS)

    E-Print Network [OSTI]

    Characterization of Composite Cores for High Temperature-Low Sag (HTLS) Conductors Final Project project T-33 titled "Characterization of Composite Cores for High Temperature-Low Sag (HTLS) Conductors/University Cooperative Research Center since 1996 PSERC #12;Characterization of Composite Cores for High Temperature-Low

  12. Method of manufacturing a high temperature superconductor with improved transport properties

    DOE Patents [OSTI]

    Balachandran, Uthamalingam (Hinsdale, IL); Siegel, Richard W. (Hinsdale, IL); Askew, Thomas R. (Kalamazoo, MI)

    2001-01-01T23:59:59.000Z

    A method of preparing a high temperature superconductor. A method of preparing a superconductor includes providing a powdered high temperature superconductor and a nanophase paramagnetic material. These components are combined to form a solid compacted mass with the paramagnetic material disposed on the grain boundaries of the polycrystaline high temperature superconductor.

  13. Burning Velocities in Catalytically Assisted Self-Propagating High-Temperature Combustion Synthesis Systems

    E-Print Network [OSTI]

    Wooldridge, Margaret S.

    Burning Velocities in Catalytically Assisted Self-Propagating High-Temperature Combustion Synthesis of catalytically assisted self-propagating high-temperature synthesis (SHS) of the tantalum/carbon material system. © 2001 by The Combustion Institute INTRODUCTION Self-propagating high-temperature combustion synthesis

  14. Dual Phase Membrane for High Temperature CO2 Separation

    SciTech Connect (OSTI)

    Jerry Lin

    2007-06-30T23:59:59.000Z

    This project aimed at synthesis of a new inorganic dual-phase carbonate membrane for high temperature CO{sub 2} separation. Metal-carbonate dual-phase membranes were prepared by the direct infiltration method and the synthesis conditions were optimized. Permeation tests for CO{sub 2} and N{sub 2} from 450-750 C showed very low permeances of those two gases through the dual-phase membrane, which was expected due to the lack of ionization of those two particular gases. Permeance of the CO{sub 2} and O{sub 2} mixture was much higher, indicating that the gases do form an ionic species, CO{sub 3}{sup 2-}, enhancing transport through the membrane. However, at temperatures in excess of 650 C, the permeance of CO{sub 3}{sup 2-} decreased rapidly, while predictions showed that permeance should have continued to increase with temperature. XRD data obtained from used membrane indicated that lithium iron oxides formed on the support surface. This lithium iron oxide layer has a very low conductivity, which drastically reduces the flow of electrons to the CO{sub 2}/O{sub 2} gas mixture; thus limiting the formation of the ionic species required for transport through the membrane. These results indicated that the use of stainless steel supports in a high temperature oxidative environment can lead to decreased performance of the membranes. This revelation created the need for an oxidation resistant support, which could be gained by the use of a ceramic-type membrane. Work was extended to synthesize a new inorganic dual-phase carbonate membrane for high temperature CO{sub 2} separation. Helium permeance of the support before and after infiltration of molten carbonate are on the order of 10{sup -6} and 10{sup -10} moles/m{sup 2} {center_dot} Pa {center_dot} s respectively, indicating that the molten carbonate is able to sufficiently infiltrate the membrane. It was found that La{sub 0.6}Sr{sub 0.4}Co{sub 0.8}Fe{sub 0.2}O{sub 3-{delta}} (LSCF) was a suitable candidate for the support material. This support material proved to separate CO{sub 2} when combined with O{sub 2} at a flux of 0.194 ml/min {center_dot} cm{sup 2} at 850 C. It was also observed that, because LSCF is a mixed conductor (conductor of both electrons and oxygen ions), the support was able to provide its own oxygen to facilitate separation of CO{sub 2}. Without feeding O{sub 2}, the LSCF dual phase membrane produced a maximum CO{sub 2} flux of 0.246 ml/min {center_dot} cm{sup 2} at 900 C.

  15. Advancement of High Temperature Black Liquor Gasification Technology

    SciTech Connect (OSTI)

    Craig Brown; Ingvar Landalv; Ragnar Stare; Jerry Yuan; Nikolai DeMartini; Nasser Ashgriz

    2008-03-31T23:59:59.000Z

    Weyerhaeuser operates the world's only commercial high-temperature black liquor gasifier at its pulp mill in New Bern, NC. The unit was started-up in December 1996 and currently processes about 15% of the mill's black liquor. Weyerhaeuser, Chemrec AB (the gasifier technology developer), and the U.S. Department of Energy recognized that the long-term, continuous operation of the New Bern gasifier offered a unique opportunity to advance the state of high temperature black liquor gasification toward the commercial-scale pressurized O2-blown gasification technology needed as a foundation for the Forest Products Bio-Refinery of the future. Weyerhaeuser along with its subcontracting partners submitted a proposal in response to the 2004 joint USDOE and USDA solicitation - 'Biomass Research and Development Initiative'. The Weyerhaeuser project 'Advancement of High Temperature Black Liquor Gasification' was awarded USDOE Cooperative Agreement DE-FC26-04NT42259 in November 2004. The overall goal of the DOE sponsored project was to utilize the Chemrec{trademark} black liquor gasification facility at New Bern as a test bed for advancing the development status of molten phase black liquor gasification. In particular, project tasks were directed at improvements to process performance and reliability. The effort featured the development and validation of advanced CFD modeling tools and the application of these tools to direct burner technology modifications. The project also focused on gaining a fundamental understanding and developing practical solutions to address condensate and green liquor scaling issues, and process integration issues related to gasifier dregs and product gas scrubbing. The Project was conducted in two phases with a review point between the phases. Weyerhaeuser pulled together a team of collaborators to undertake these tasks. Chemrec AB, the technology supplier, was intimately involved in most tasks, and focused primarily on the design, specification and procurement of facility upgrades. Chemrec AB is also operating a pressurized, O2-blown gasifier pilot facility in Piteaa, Sweden. There was an exchange of knowledge with the pressurized projects including utilization of the experimental results from facilities in Piteaa, Sweden. Resources at the Georgia Tech Research Corporation (GTRC, a.k.a., the Institute of Paper Science and Technology) were employed primarily to conduct the fundamental investigations on scaling and plugging mechanisms and characterization of green liquor dregs. The project also tapped GTRC expertise in the development of the critical underlying black liquor gasification rate subroutines employed in the CFD code. The actual CFD code development and application was undertaken by Process Simulation, Ltd (PSL) and Simulent, Ltd. PSL focused on the overall integrated gasifier CFD code, while Simulent focused on modeling the black liquor nozzle and description of the black liquor spray. For nozzle development and testing Chemrec collaborated with ETC (Energy Technology Centre) in Piteae utilizing their test facility for nozzle spray investigation. GTI (Gas Technology Institute), Des Plains, IL supported the team with advanced gas analysis equipment during the gasifier test period in June 2005.

  16. DEGRADATION ISSUES IN SOLID OXIDE CELLS DURING HIGH TEMPERATURE ELECTROLYSIS

    SciTech Connect (OSTI)

    J. E. O'Brien; C. M. Stoots; V. I. Sharma; B. Yildiz; A. V. Virkar

    2010-06-01T23:59:59.000Z

    Idaho National Laboratory (INL) is performing high-temperature electrolysis research to generate hydrogen using solid oxide electrolysis cells (SOECs). The project goals are to address the technical and degradation issues associated with the SOECs. This paper provides a summary of various ongoing INL and INL sponsored activities aimed at addressing SOEC degradation. These activities include stack testing, post-test examination, degradation modeling, and a list of issues that need to be addressed in future. Major degradation issues relating to solid oxide fuel cells (SOFC) are relatively better understood than those for SOECs. Some of the degradation mechanisms in SOFCs include contact problems between adjacent cell components, microstructural deterioration (coarsening) of the porous electrodes, and blocking of the reaction sites within the electrodes. Contact problems include delamination of an electrode from the electrolyte, growth of a poorly (electronically) conducting oxide layer between the metallic interconnect plates and the electrodes, and lack of contact between the interconnect and the electrode. INL’s test results on high temperature electrolysis (HTE) using solid oxide cells do not provide a clear evidence whether different events lead to similar or drastically different electrochemical degradation mechanisms. Post-test examination of the solid oxide electrolysis cells showed that the hydrogen electrode and interconnect get partially oxidized and become non-conductive. This is most likely caused by the hydrogen stream composition and flow rate during cool down. The oxygen electrode side of the stacks seemed to be responsible for the observed degradation due to large areas of electrode delamination. Based on the oxygen electrode appearance, the degradation of these stacks was largely controlled by the oxygen electrode delamination rate. University of Utah (Virkar) has developed a SOEC model based on concepts in local thermodynamic equilibrium in systems otherwise in global thermodynamic non-equilibrium. This model is under continued development. It shows that electronic conduction through the electrolyte, however small, must be taken into account for determining local oxygen chemical potential, within the electrolyte. The chemical potential within the electrolyte may lie out of bounds in relation to values at the electrodes in the electrolyzer mode. Under certain conditions, high pressures can develop in the electrolyte just under the oxygen electrode (anode)/electrolyte interface, leading to electrode delamination. This theory is being further refined and tested by introducing some electronic conduction in the electrolyte.

  17. High Temperature Calcination - MACT Upgrade Equipment Pilot Plant Test

    SciTech Connect (OSTI)

    Richard D. Boardman; B. H. O'Brien; N. R. Soelberg; S. O. Bates; R. A. Wood; C. St. Michel

    2004-02-01T23:59:59.000Z

    About one million gallons of acidic, hazardous, and radioactive sodium-bearing waste are stored in stainless steel tanks at the Idaho Nuclear Technology and Engineering Center (INTEC), which is a major operating facility of the Idaho National Engineering and Environmental Laboratory. Calcination at high-temperature conditions (600 C, with alumina nitrate and calcium nitrate chemical addition to the feed) is one of four options currently being considered by the Department of Energy for treatment of the remaining tank wastes. If calcination is selected for future processing of the sodium-bearing waste, it will be necessary to install new off-gas control equipment in the New Waste Calcining Facility (NWCF) to comply with the Maximum Achievable Control Technology (MACT) standards for hazardous waste combustors and incinerators. This will require, as a minimum, installing a carbon bed to reduce mercury emissions from their current level of up to 7,500 to <45 {micro}g/dscm, and a staged combustor to reduce unburned kerosene fuel in the off-gas discharge to <100 ppm CO and <10 ppm hydrocarbons. The staged combustor will also reduce NOx concentrations of about 35,000 ppm by 90-95%. A pilot-plant calcination test was completed in a newly constructed 15-cm diameter calciner vessel. The pilot-plant facility was equipped with a prototype MACT off-gas control system, including a highly efficient cyclone separator and off-gas quench/venturi scrubber for particulate removal, a staged combustor for unburned hydrocarbon and NOx destruction, and a packed activated carbon bed for mercury removal and residual chloride capture. Pilot-plant testing was performed during a 50-hour system operability test January 14-16, followed by a 100-hour high-temperature calcination pilot-plant calcination run January 19-23. Two flowsheet blends were tested: a 50-hour test with an aluminum-to-alkali metal molar ratio (AAR) of 2.25, and a 50-hour test with an AAR of 1.75. Results of the testing indicate that sodium-bearing waste can be successfully calcined at 600 C with an AAR of 1.75. Unburned hydrocarbons are reduced to less than 10 ppm (7% O2, dry basis), with >90% reduction of NOx emissions. Mercury removal by the carbon bed reached 99.99%, surpassing the control efficiency needed to meet MACT emissions standards. No deleterious impacts on the carbon bed were observed during the tests. The test results imply that upgrading the NWCF calciner with a more efficient cyclone separator and the proposed MACT equipment can process the remaining tanks wastes in 3 years or less, and comply with the MACT standards.

  18. Optimum catalytic process for alcohol fuels from syngas: Second quarterly technical progress report

    SciTech Connect (OSTI)

    Not Available

    1987-07-30T23:59:59.000Z

    A base case process for economic studies of making fuel alcohols from syngas has been developed. It uses existing technologies which have been demonstrated to be feasible or have already been commercialized. The process consists of the following steps: coal or natural gas (reforming or partial oxidation) to syngas; syngas to methanol by ICI technology; methanol to light olefins by proprietary UCC technology using molecular sieves; olefins to alcohols by hydroformylation (with a homogeneous rhodium catalyst) followed by hydrogenation. Process economics for the two natural gas-based routes have been developed. With insights gained from this, an optimized and integrated multi-step process has been conceptualized which allows estimation of the lowest cost at which fuel alcohols can be produced. A 60% methanol and 40% higher alcohol mix was assumed to be a suitable fuel alcohol blend for gasoline. At a natural gas price of $2/MMBTU, the cost of producing this, by either partial oxidation or reforming, is $1.12/gal. An integrated process with autothermal reforming at 750 psia and methanol synthesis at 700 psia allows incorporation of the best features of reforming and partial oxidation as well as elimination of syngas compression. The production cost of fuel alcohols by this process is estimated to be $0.90/gal. This is, therefore, the lowest cost at which fuel alcohols can be produced by an integrated, multi-step process. An ''ideal'' process has also been conceptualized which establishes a target production cost that new technology should strive for to be competitive. This process incorporates autothermal reforming for producing syngas followed by conversion to fuel alcohols using emerging technologies. The target production cost is estimated to be $0.65/gal. 16 figs., 10 tabs.

  19. Performance of solid oxide fuel cells operated with coal syngas provided directly from a gasification process

    SciTech Connect (OSTI)

    Hackett, Gregory A.; Gerdes, Kirk R.; Song, Xueyan; Chen, Yun; Shutthanandan, V.; Engelhard, Mark H.; Zhu, Zihua; Thevuthasan, Suntharampillai; Gemmen, Randall

    2012-09-15T23:59:59.000Z

    Solid oxide fuel cells (SOFCs) are presently being developed for gasification integrated power plants that generate electricity from coal at 50+% efficiency. The interaction of trace metals in coal syngas with the Ni-based SOFC anodes is being investigated through thermodynamic analyses and in laboratory experiments, but direct test data from coal syngas exposure are sparsely available. This research effort evaluates the significance of SOFC performance losses associated with exposure of a SOFC anode to direct coal syngas. SOFC specimen of industrially relevant composition are operated in a unique mobile test skid that was deployed to the research gasifier at the National Carbon Capture Center (NCCC) in Wilsonville, AL. The mobile test skid interfaces with a gasifier slipstream to deliver hot syngas (up to 300°C) directly to a parallel array of 12 button cell specimen, each of which possesses an active area of approximately 2 cm2. During the 500 hour test period, all twelve cells were monitored for performance at four discrete operating current densities, and all cells maintained contact with a data acquisition system. Of these twelve, nine demonstrated good performance throughout the test, while three of the cells were partially compromised. Degradation associated with the properly functioning cells was attributed to syngas exposure and trace material attack on the anode structure that was accelerated at increasing current densities. Cells that were operated at 0 and 125 mA/cm˛ degraded at 9.1 and 10.7% per 1000 hours, respectively, while cells operated at 250 and 375 mA/cm˛ degraded at 18.9 and 16.2% per 1000 hours, respectively. Post-trial spectroscopic analysis of the anodes showed carbon, sulfur, and phosphorus deposits; no secondary Ni-metal phases were found.

  20. High temperature superconducting composite conductor and method for manufacturing the same

    DOE Patents [OSTI]

    Holesinger, Terry G. (Los Alamos, NM); Bingert, John F. (Jemez Springs, NM)

    2002-01-01T23:59:59.000Z

    A high temperature superconducting composite conductor is provided including a high temperature superconducting material surrounded by a noble metal layer, the high temperature superconducting composite conductor characterized as having a fill factor of greater than about 40. Additionally, the conductor can be further characterized as containing multiple cores of high temperature superconducting material surrounded by a noble metal layer, said multiple cores characterized as having substantially uniform geometry in the cross-sectional dimensions. Processes of forming such a high temperature superconducting composite conductor are also provided.

  1. Polymer nanocomposites for high-temperature composite repair

    SciTech Connect (OSTI)

    Sheng, Xia

    2008-12-01T23:59:59.000Z

    A novel repair agent for resin-injection repair of advanced high temperature composites was developed and characterized. The repair agent was based on bisphenol E cyanate ester (BECy) and reinforced with alumina nanoparticles. To ensure good dispersion and compatibility with the BECy matrix in nanocomposites, the alumina nanoparticles were functionalized with silanes. The BECy nanocomposites, containing bare and functionalized alumina nanoparticles, were prepared and evaluated for their thermal, mechanical, rheological, and viscoelastic properties. The monomer of BECy has an extremely low viscosity at ambient temperature, which is good for processability. The cured BECy polymer is a highly cross-linked network with excellent thermal mechanical properties, with a high glass transition temperature (T{sub g}) of 270 C and decomposition temperature above 350 C. The incorporation of alumina nanoparticles enhances the mechanical and rheological properties of the BECy nanocomposites. Additionally, the alumina nanoparticles are shown to catalyze the cure of BECy. Characterization of the nanocomposites included dynamic mechanical analysis, differential scanning calorimetry, thermogravimetric analysis, rheological and rheokinetic evaluation, and transmission electron microscopy. The experimental results show that the BECy nanocomposite is a good candidate as repair agent for resin-injection repair applications.

  2. High temperature QCD with three flavors of improved staggered quarks

    E-Print Network [OSTI]

    The MILC Collaboration; C. Bernard; T. Burch; C. E. DeTar; Steven Gottlieb; Eric Gregory; U. M. Heller; J. Osborn; R. L. Sugar; D. Toussaint

    2002-09-05T23:59:59.000Z

    We present an update of our study of high temperature QCD with three flavors of quarks, using a Symanzik improved gauge action and the Asqtad staggered quark action. Simulations are being carried out on lattices with Nt=4, 6 and 8 for the case of three degenerate quarks with masses less than or equal to the strange quark mass, $m_s$, and on lattices with Nt=6 and 8 for degenerate up and down quarks with masses in the range 0.2 m_s \\leq m_{u,d} \\leq 0.6 m_s, and the strange quark fixed near its physical value. We also report on first computations of quark number susceptibilities with the Asqtad action. These susceptibilities are of interest because they can be related to event-by-event fluctuations in heavy ion collision experiments. Use of the improved quark action leads to a substantial reduction in lattice artifacts. This can be seen already for free fermions and carries over into our results for QCD.

  3. High temperature QCD with three flavors of improved staggered quarks

    E-Print Network [OSTI]

    Bernard, C; DeTar, C E; Gottlieb, S; Gregory, E; Heller, U M; Osborn, J; Sugar, R L; Toussaint, D; Gottlieb, Steven; Gregory, Eric

    2002-01-01T23:59:59.000Z

    We present an update of our study of high temperature QCD with three flavors of quarks, using a Symanzik improved gauge action and the Asqtad staggered quark action. Simulations are being carried out on lattices with Nt=4, 6 and 8 for the case of three degenerate quarks with masses less than or equal to the strange quark mass, $m_s$, and on lattices with Nt=6 and 8 for degenerate up and down quarks with masses in the range 0.2 m_s \\leq m_{u,d} \\leq 0.6 m_s, and the strange quark fixed near its physical value. We also report on first computations of quark number susceptibilities with the Asqtad action. These susceptibilities are of interest because they can be related to event-by-event fluctuations in heavy ion collision experiments. Use of the improved quark action leads to a substantial reduction in lattice artifacts. This can be seen already for free fermions and carries over into our results for QCD.

  4. High-temperature superconducting transformer performance, cost, and market evaluation

    SciTech Connect (OSTI)

    Dirks, J.A.; Dagle, J.E.; DeSteese, J.G.; Huber, H.D.; Smith, S.A.; Currie, J.W. [Pacific Northwest Lab., Richland, WA (United States); Merrick, S.B. [Westinghouse Hanford Co., Richland, WA (United States); Williams, T.A. [National Renewable Energy Lab., Golden, CO (United States)

    1993-09-01T23:59:59.000Z

    Recent laboratory breakthroughs in high-temperature superconducting (HTS) materials have stimulated both the scientific community and general public with questions regarding how these materials can be used in practical applications. While there are obvious benefits from using HTS materials (most notably the potential for reduced energy losses in the conductors), a number of issues (such as overall system energy losses, cost, and reliability) may limit applications of HTS equipment, even if the well known materials problems are solved. This study examined the future application potential of HTS materials to power transformers. This study effort was part of a US Department of Energy (DOE) Office of Energy Storage and Distribution (OESD) research program, Superconductivity Technology for Electric Power Systems (STEPS). The study took a systems perspective to gain insights to help guide DOE in managing research designed to realize the vision of HTS applications. Specific objectives of the study were as follows: to develop an understanding of the fundamental HTS transformer design issues that can provide guidance for developing practical devices of interest to the electric utility industry; to identify electric utility requirements for HTS transformers and to evaluate the potential for developing a commercial market; to evaluate the market potential and national benefits for HTS transformers that could be achieved by a successful HTS development program; to develop an integrated systems analysis framework, which can be used to support R&D planning by DOE, by identifying how various HTS materials characteristics impact the performance, cost, and national benefits of the HTS application.

  5. Corrosion assessment of refractory materials for high temperature waste vitrification

    SciTech Connect (OSTI)

    Marra, J.C.; Congdon, J.W.; Kielpinski, A.L. [and others

    1995-11-01T23:59:59.000Z

    A variety of vitrification technologies are being evaluated to immobilize radioactive and hazardous wastes following years of nuclear materials production throughout the Department of Energy (DOE) complex. The compositions and physical forms of these wastes are diverse ranging from inorganic sludges to organic liquids to heterogeneous debris. Melt and off-gas products can be very corrosive at the high temperatures required to melt many of these waste streams. Ensuring material durability is required to develop viable treatment processes. Corrosion testing of materials in some of the anticipated severe environments is an important aspect of the materials identification and selection process. Corrosion coupon tests on typical materials used in Joule heated melters were completed using glass compositions with high salt contents. The presence of chloride in the melts caused the most severe attack. In the metal alloys, oxidation was the predominant corrosion mechanism, while in the tested refractory material enhanced dissolution of the refractory into the glass was observed. Corrosion testing of numerous different refractory materials was performed in a plasma vitrification system using a surrogate heterogeneous debris waste. Extensive corrosion was observed in all tested materials.

  6. Ultra high temperature diffusion apparatus and operating procedures

    SciTech Connect (OSTI)

    Wyrick, S.B.

    1985-11-15T23:59:59.000Z

    It is the purpose of this paper to present an experimental apparatus which is capable of measuring diffusion coefficients of interdiffusing gases in the temperature range 300K to 2500K. Because of the high temperatures which will be encountered, a special alloy of tantalum (T-111) is used to house the diffusion process. This T-111 diffusion cell is heated via radiation heat from a tungsten heating element powered by a Saban saturable reactor power supply. The diffusion cell heating element are encased in a nickel-plated copper cooling can. This entire assembly is enclosed in an Ultek vacuum chamber to prevent oxidation of the diffusion cell. This report covers the construction and calibration of the diffusion cell, details of the gas loading and sampling system, and complete information on the components required to operate the vacuum furnace. Thus far, several experiments have been run in the temperature range 600K to 800K and the resulting diffusion coefficients agree fairly well with previously published values. 21 refs., 9 figs., 4 tabs.

  7. Materials for the scavenging of hydrogen at high temperatures

    DOE Patents [OSTI]

    Shepodd, T.J.; Phillip, B.L.

    1997-12-30T23:59:59.000Z

    A hydrogen getter composition is described comprising a double or triple bonded hydrocarbon with a high melting point useful for removing hydrogen gas, to partial pressures below 0.01 torr, from enclosed spaces and particularly from vessels used for transporting or containing fluids at elevated temperatures. The hydrogen getter compositions disclosed herein and their reaction products will neither melt nor char at temperatures in excess of 100 C. They possess significant advantages over conventional hydrogen getters, namely low risk of fire or explosion, no requirement for high temperature activation or operation, the ability to absorb hydrogen even in the presence of contaminants such as water, water vapor, common atmospheric gases and oil mists and are designed to be disposed within the confines of the apparatus. These getter materials can be mixed with binders, such as fluoropolymers, which permit the getter material to be fabricated into useful shapes and/or impart desirable properties such as water repellency or impermeability to various gases. 7 figs.

  8. Materials for the scavenging of hydrogen at high temperatures

    DOE Patents [OSTI]

    Shepodd, T.J.; Phillip, B.L.

    1997-04-29T23:59:59.000Z

    A hydrogen getter composition is described comprising a double or triple bonded hydrocarbon with a high melting point useful for removing hydrogen gas, to partial pressures below 0.01 torr, from enclosed spaces and particularly from vessels used for transporting or containing fluids at elevated temperatures. The hydrogen getter compositions disclosed herein and their reaction products will neither melt nor char at temperatures in excess of 100C. They possess significant advantages over conventional hydrogen getters, namely low risk of fire or explosion, no requirement for high temperature activation or operation, the ability to absorb hydrogen even in the presence of contaminants such as water, water vapor, common atmospheric gases and oil mists and are designed to be disposed within the confines of the apparatus. These getter materials can be mixed with binders, such as fluoropolymers, which permit the getter material to be fabricated into useful shapes and/or impart desirable properties such as water repellency or impermeability to various gases. 7 figs.

  9. Segmented lasing tube for high temperature laser assembly

    DOE Patents [OSTI]

    Sawicki, Richard H. (Danville, CA); Alger, Terry W. (Tracy, CA); Finucane, Raymond G. (Pleasanton, CA); Hall, Jerome P. (Livermore, CA)

    1996-01-01T23:59:59.000Z

    A high temperature laser assembly capable of withstanding operating temperatures in excess of 1500.degree. C. is described comprising a segmented cylindrical ceramic lasing tube having a plurality of cylindrical ceramic lasing tube segments of the same inner and outer diameters non-rigidly joined together in axial alignment; insulation of uniform thickness surround the walls of the ceramic lasing tube; a ceramic casing, preferably of quartz, surrounding the insulation; and a fluid cooled metal jacket surrounds the ceramic casing. In a preferred embodiment, the inner surface of each of the ceramic lasing tube segments are provided with a pair of oppositely spaced grooves in the wall thereof parallel to the center axis of the segmented cylindrical ceramic lasing tube, and both of the grooves and the center axis of the segmented cylindrical ceramic lasing tube lie in a common plane, with the grooves in each ceramic lasing tube segment in circumferential alignment with the grooves in the adjoining ceramic lasing tube segments; and one or more ceramic plates, all lying in a common plane to one another and with the central axis of the segmented ceramic lasing tube, are received in the grooves to provide additional wall area in the segmented ceramic lasing tube for collision and return to ground state of metastable metal atoms within the segmented ceramic lasing tube.

  10. A High Temperature Liquid Plasma Model of the Sun

    E-Print Network [OSTI]

    Pierre-Marie Robitaille

    2004-10-04T23:59:59.000Z

    In this work, a liquid model of the Sun is presented wherein the entire solar mass is viewed as a high density/high energy plasma. This model challenges our current understanding of the densities associated with the internal layers of the Sun, advocating a relatively constant density, almost independent of radial position. The incompressible nature of liquids is advanced to prevent solar collapse from gravitational forces. The liquid plasma model of the Sun is a non-equilibrium approach, where nuclear reactions are free to occur throughout the solar mass. The primary means of addressing internal heat transfer are convection and conduction. As a result of the convective processes on the solar surface, the liquid model brings into question the established temperature of the solar photosphere by highlighting a violation of Kirchhoff's law of thermal emission. Along these lines, the model emphasizes that radiative emission is a surface phenomenon. Strong evidence is provided that the Sun is a high density/high energy liquid plasma. This evidence is based on our knowledge of Planckian thermal emission and condensed matter, including the existence of pressure ionization and liquid metallic hydrogen at high temperatures and pressures. The equations of magnetohydrodynamics are invoked as the proper vehicle for the understanding od stellar convection and structure. Prior to introducing the liquid plasma model, the historic and scientific justifications for the gaseous model of the Sun are reviewed and the gaseous equations of state are also discussed.

  11. Screening study on high temperature energy transport systems

    SciTech Connect (OSTI)

    Graves, R.L.

    1980-10-01T23:59:59.000Z

    The purpose of the study described in this document is to identify the options for transporting thermal energy over long distances. The study deals specifically and exclusively with high temperature (> 400/sup 0/C(752/sup 0/F)) energy for industrial use. Energy transport is seen as a potential solution to: high unit cost of small coal and nuclear steam generators, and opposition to siting of coal or nuclear plants near populated areas. The study is of a preliminary nature but covers many options including steam, molten salts, organics, and chemical heat pipes. The development status and potential problems of these and other energy transport methods are discussed. Energy transport concepts are compared on a fundamental level based on physical properties and also are subjected to an economic study. The economic study indicated that the chemical heat pipe, under a specific set of circumstances, appeared to be the least expensive for distances greater than about 32 km (20 miles). However, if the temperature of the energy was lowered, the heat transfer salt (sodium nitrate/nitrite) system would apparently be a better economic choice for less than about 80 km (50 miles). None of the options studied appear to be more attractive than small coal-fired boilers when the transport distance is over about 64 km (40 miles). Several recommendations are made for refining the analysis.

  12. Power efficiency for very high temperature solar thermal cavity receivers

    DOE Patents [OSTI]

    McDougal, Allan R. (LaCanada-Flintridge, CA); Hale, Robert R. (Upland, CA)

    1984-01-01T23:59:59.000Z

    This invention is an improved solar energy cavity receiver for exposing materials and components to high temperatures. The receiver includes a housing having an internal reflective surface defining a cavity and having an inlet for admitting solar radiation thereto. A photothermal absorber is positioned in the cavity to receive radiation from the inlet. A reflective baffle is positioned between the absorber and the inlet to severely restrict the re-radiation of energy through the inlet. The front surface of the baffle defines a narrow annulus with the internal reflective surface of the housing. The front surface of the baffle is contoured to reflect incoming radiation onto the internal surface of the housing, from which it is reflected through the annulus and onto the front surface of the absorber. The back surface of the baffle intercepts infrared radiation from the front of the absorber. With this arrangement, a high percentage of the solar power input is retained in the cavity; thus, high internal temperatures are attained.

  13. Systems Engineering Provides Successful High Temperature Steam Electrolysis Project

    SciTech Connect (OSTI)

    Charles V. Park; Emmanuel Ohene Opare, Jr.

    2011-06-01T23:59:59.000Z

    This paper describes two Systems Engineering Studies completed at the Idaho National Laboratory (INL) to support development of the High Temperature Stream Electrolysis (HTSE) process. HTSE produces hydrogen from water using nuclear power and was selected by the Department of Energy (DOE) for integration with the Next Generation Nuclear Plant (NGNP). The first study was a reliability, availability and maintainability (RAM) analysis to identify critical areas for technology development based on available information regarding expected component performance. An HTSE process baseline flowsheet at commercial scale was used as a basis. The NGNP project also established a process and capability to perform future RAM analyses. The analysis identified which components had the greatest impact on HTSE process availability and indicated that the HTSE process could achieve over 90% availability. The second study developed a series of life-cycle cost estimates for the various scale-ups required to demonstrate the HTSE process. Both studies were useful in identifying near- and long-term efforts necessary for successful HTSE process deployment. The size of demonstrations to support scale-up was refined, which is essential to estimate near- and long-term cost and schedule. The life-cycle funding profile, with high-level allocations, was identified as the program transitions from experiment scale R&D to engineering scale demonstration.

  14. Cryogenic System for a High Temperature Superconducting Power Transmission Cable

    SciTech Connect (OSTI)

    Demko, J.A.; Gouge, M.J.; Hughey, R.L.; Lue, J.W.; Martin, R.; Sinha, U.; Stovall, J.P.

    1999-07-12T23:59:59.000Z

    High-temperature superconducting (HTS) cable systems for power transmission are under development that will use pressurized liquid nitrogen to provide cooling of the cable and termination hardware. Southwire Company and Oak Ridge National Laboratory have been operating a prototype HTS cable system that contains many of the typical components needed for a commercial power transmission application. It is being used to conduct research in the development of components and systems for eventual commercial deployment. The cryogenic system was built by Air Products and Chemicals, Allentown, Pennsylvania, and can circulate up to 0.35 kg/s of liquid nitrogen at temperatures as low as 67 K at pressures of 1 to 10 bars. Sufficient cooling is provided for testing a 5-m-long HTS transmission cable system that includes the terminations required for room temperature electrical connections. Testing of the 5-m HTS transmission cable has been conducted at the design ac conditions of 1250 A and 7.5 kV line to ground. This paper contains a description of the essential features of the HTS cable cryogenic system and performance results obtained during operation of the system. The salient features of the operation that are important in large commercial HTS cable applications will be discussed.

  15. Electronic high voltage generator with a high temperature superconducting coil

    SciTech Connect (OSTI)

    Jin, J.X.; Liu, H.K.; Dou, S.X. [Univ. of Wollongong (Australia)] [and others

    1996-12-31T23:59:59.000Z

    A novel method for generating high voltages from a low voltage DC source, by using a capacitor and inductor in a R, L, C resonant circuit has been developed with the consideration of using a high temperature superconducting (HTS) coil. To generate high voltages the polarity of a low voltage battery source is reversed each half resonant cycle, the control being achieved by an electronic switch. Resistance in the circuit limits the voltages that can be built up. By replacing a copper winding inductor with another inductor which has a HTS winding, the magnitude of achievable voltages is substantially increased. A (Bi,Pb){sub 2}Sr{sub 2}Ca{sub 2}Cu{sub 3}O{sub 10+x} multifilament HTS wire is considered in this work to make the superconducting inductor. The high voltages generated are not capable of supplying low impedance loads, however, possible applications of the generator include electrical partial discharge testing and insulation resistance testing. It could also be used as a testing method for the HTS itself with respect to the critical current and AC loss measurement.

  16. Development of high temperature superconductors for magnetic field applications

    SciTech Connect (OSTI)

    Larbalestier, D.C.

    1991-12-31T23:59:59.000Z

    The key requirement for magnetic field applications of high temperature superconductor (HTS) materials is to have conductors with high transport critical current density available for magnet builders. After 3 or 4 years of being without any such object, conductor makers have had recent success in producing simple conductor prototypes. These have permitted the construction of simple HTS magnets having self fields exceeding 1 tesla at 4K. Thus the scientific feasibility of making powerful HTS magnets has been demonstrated. Attention to the technological aspects of making HTS conductors for magnets with strong flux pinning and reduced superconducting granularity is now sensible and attractive. However, extrinsic defects such as filament sausaging, cracking, misaligned grains and other perturbation to long range current flow must be controlled at a low level if the benefit of intrinsic improvements to the critical current density is to be maintained in the conductor form. Due to the great complexity of the HTS materials, there is sometimes confusion as to whether a given sample has an intrinsically or extrinsically limited critical current density. Systematic microstructure variation experiments and resistive transition analysis are shown to be particularly helpful in this phase of conductor development.

  17. Gallium phosphide high-temperature bipolar junction transistor

    SciTech Connect (OSTI)

    Zipperian, T.E.; Dawson, L.R.; Caffin, R.J.

    1981-03-01T23:59:59.000Z

    Preliminary results are reported on the development of a high-temperature (> 350/sup 0/C) gallium phosphide bipolar junction transistor (BJT) for goethermal and other energy applications. This four-layer p/sup +/n/sup -/pp/sup +/ structure was fromed by liquid phase epitaxy using a supercooling technique to insure uniform nucleation of the thin layers. Magnesium was used as the p-type dopant to avoid excessive out-diffusion into the lightly doped base. By appropriate choice of electrodes, the device may also be driven as an n-channel junction field-effect transistor. The gallium phosphide BJT is observed to have a common-emitter current gain peaking in the range of 6 to 10 (for temperatures from 20/sup 0/C to 400/sup 0/C) and a room-temperature, punchthrough-limited, collector-emitter breakdown voltage of approximately -6V. Other parameters of interest include an f/sub/ = 400 KHz (at 20/sup 0/C) and a collector base leakage current = 200 ..mu..A (at 350/sup 0/C).

  18. Rotational viscometer for high-pressure high-temperature fluids

    DOE Patents [OSTI]

    Carr, Kenneth R. (Knoxville, TN)

    1985-01-01T23:59:59.000Z

    The invention is a novel rotational viscometer which is well adapted for use with fluids at high temperatures and/or pressures. In one embodiment, the viscometer includes a substantially non-magnetic tube having a closed end and having an open end in communication with a fluid whose viscosity is to be determined. An annular drive magnet is mounted for rotation about the tube. The tube encompasses and supports a rotatable shaft assembly which carries a rotor, or bob, for insertion in the fluid. Affixed to the shaft are (a) a second magnet which is magnetically coupled to the drive magnet and (b) a third magnet. In a typical operation, the drive magnet is rotated to turn the shaft assembly while the shaft rotor is immersed in the fluid. The viscous drag on the rotor causes the shaft assembly to lag the rotation of the drive magnet by an amount which is a function of the amount of viscous drag. A first magnetic pickup generates a waveform whose phase is a function of the angular position of the drive magnet. A second magnetic pickup generates a waveform whose phase is a function of the angular position of the third magnet. An output is generated indicative of the phase difference between the two waveforms.

  19. Pressure Resistance Welding of High Temperature Metallic Materials

    SciTech Connect (OSTI)

    N. Jerred; L. Zirker; I. Charit; J. Cole; M. Frary; D. Butt; M. Meyer; K. L. Murty

    2010-10-01T23:59:59.000Z

    Pressure Resistance Welding (PRW) is a solid state joining process used for various high temperature metallic materials (Oxide dispersion strengthened alloys of MA957, MA754; martensitic alloy HT-9, tungsten etc.) for advanced nuclear reactor applications. A new PRW machine has been installed at the Center for Advanced Energy Studies (CAES) in Idaho Falls for conducting joining research for nuclear applications. The key emphasis has been on understanding processing-microstructure-property relationships. Initial studies have shown that sound joints can be made between dissimilar materials such as MA957 alloy cladding tubes and HT-9 end plugs, and MA754 and HT-9 coupons. Limited burst testing of MA957/HT-9 joints carried out at various pressures up to 400oC has shown encouraging results in that the joint regions do not develop any cracking. Similar joint strength observations have also been made by performing simple bend tests. Detailed microstructural studies using SEM/EBSD tools and fatigue crack growth studies of MA754/HT-9 joints are ongoing.

  20. High Temperature Tolerant Ceramic Composites Having Porous Interphases

    DOE Patents [OSTI]

    Kriven, Waltraud M. (Champaign, IL); Lee, Sang-Jin (Chonnam, KR)

    2005-05-03T23:59:59.000Z

    In general, this invention relates to a ceramic composite exhibiting enhanced toughness and decreased brittleness, and to a process of preparing the ceramic composite. The ceramic composite comprises a first matrix that includes a first ceramic material, preferably selected from the group including alumina (Al2O3), mullite (3Al2O3.2SiO2), yttrium aluminate garnet (YAG), yttria stabilized zirconia (YSZ), celsian (BaAl2Si2O8) and nickel aluminate (NiAl2O4). The ceramic composite also includes a porous interphase region that includes a substantially non-sinterable material. The non-sinterable material can be selected to include, for example, alumina platelets. The platelets lie in random 3-D orientation and provide a debonding mechanism, which is independent of temperature in chemically compatible matrices. The non-sinterable material induces constrained sintering of a ceramic powder resulting in permanent porosity in the interphase region. For high temperature properties, addition of a sinterable ceramic powder to the non-sinterable material provides sufficiently weak debonding interphases. The ceramic composite can be provided in a variety of forms including a laminate, a fibrous monolith, and a fiber-reinforced ceramic matrix. In the laminated systems, intimate mixing of strong versus tough microstructures were tailored by alternating various matrix-to-interphase thickness ratios to provide the bimodal laminate.

  1. Optical Fiber Chemical Sensor with Sol-Gel Derived Refractive Material as Transducer for High Temperature Gas Sensing in Clean Coal Technology

    SciTech Connect (OSTI)

    Shiquan Tao

    2006-12-31T23:59:59.000Z

    The chemistry of sol-gel derived silica and refractive metal oxide has been systematically studied. Sol-gel processes have been developed for preparing porous silica and semiconductor metal oxide materials. Micelle/reversed micelle techniques have been developed for preparing nanometer sized semiconductor metal oxides and noble metal particles. Techniques for doping metal ions, metal oxides and nanosized metal particles into porous sol-gel material have also been developed. Optical properties of sol-gel derived materials in ambient and high temperature gases have been studied by using fiber optic spectroscopic techniques, such as fiber optic ultraviolet/visible absorption spectrometry, fiber optic near infrared absorption spectrometry and fiber optic fluorescence spectrometry. Fiber optic spectrometric techniques have been developed for investigating the optical properties of these sol-gel derived materials prepared as porous optical fibers or as coatings on the surface of silica optical fibers. Optical and electron microscopic techniques have been used to observe the microstructure, such as pore size, pore shape, sensing agent distribution, of sol-gel derived material, as well as the size and morphology of nanometer metal particle doped in sol-gel derived porous silica, the nature of coating of sol-gel derived materials on silica optical fiber surface. In addition, the chemical reactions of metal ion, nanostructured semiconductor metal oxides and nanometer sized metal particles with gas components at room temperature and high temperatures have also been investigated with fiber optic spectrometric methods. Three classes of fiber optic sensors have been developed based on the thorough investigation of sol-gel chemistry and sol-gel derived materials. The first group of fiber optic sensors uses porous silica optical fibers doped with metal ions or metal oxide as transducers for sensing trace NH{sub 3} and H{sub 2}S in high temperature gas samples. The second group of fiber optic sensors uses sol-gel derived porous silica materials doped with nanometer particles of noble metals in the form of fiber or coating for sensing trace H{sub 2}, NH{sub 3} and HCl in gas samples at for applications ambient temperature. The third classes of fiber optic sensors use sol-gel derived semiconductor metal oxide coating on the surface of silica optical fiber as transducers for selectively sensing H{sub 2}, CH{sub 4} and CO at high temperature. In addition, optical fiber temperature sensors use the fluorescence signal of rare-earth metal ions doped porous silica optical fiber or the optical absorption signal of thermochromic metal oxide materials coated on the surface of silica optical fibers have also been developed for monitoring gas temperature of corrosive gas. Based on the results obtained from this project, the principle of fiber optic sensor techniques for monitoring matrix gas components as well as trace components of coal gasification derived syngas has been established. Prototype sensors for sensing trace ammonia and hydrogen sulfide in gasification derived syngas have been built up in our laboratory and have been tested using gas samples with matrix gas composition similar to that of gasification derived fuel gas. Test results illustrated the feasibility of these sensors for applications in IGCC processes.

  2. Near-zero emissions combustor system for syngas and biofuels

    SciTech Connect (OSTI)

    Yongho, Kim [Los Alamos National Laboratory; Rosocha, Louis [Los Alamos National Laboratory

    2010-01-01T23:59:59.000Z

    A multi-institutional plasma combustion team was awarded a research project from the DOE/NNSA GIPP (Global Initiative for Prolifereation Prevention) office. The Institute of High Current Electronics (Tomsk, Russia); Leonardo Technologies, Inc. (an American-based industrial partner), in conjunction with the Los Alamos National Laboratory are participating in the project to develop novel plasma assisted combustion technologies. The purpose of this project is to develop prototypes of marketable systems for more stable and cleaner combustion of syngas/biofuels and to demonstrate that this technology can be used for a variety of combustion applications - with a major focus on contemporary gas turbines. In this paper, an overview of the project, along with descriptions of the plasma-based combustors and associated power supplies will be presented. Worldwide, it is recognized that a variety of combustion fuels will be required to meet the needs for supplying gas-turbine engines (electricity generation, propulsion), internal combustion engines (propulsion, transportation), and burners (heat and electricity generation) in the 21st Century. Biofuels and biofuel blends have already been applied to these needs, but experience difficulties in modifications to combustion processes and combustor design and the need for flame stabilization techniques to address current and future environmental and energy-efficiency challenges. In addition, municipal solid waste (MSW) has shown promise as a feedstock for heat and/or electricity-generating plants. However, current combustion techniques that use such fuels have problems with achieving environmentally-acceptable air/exhaust emissions and can also benefit from increased combustion efficiency. This project involves a novel technology (a form of plasma-assisted combustion) that can address the above issues. Plasma-assisted combustion (PAC) is a growing field that is receiving worldwide attention at present. The project is focused on research necessary to develop a novel, high-efficiency, low-emissions (near-zero, or as low as reasonably achievable), advanced combustion technology for electricity and heat production from biofuels and fuels derived from MSW. For any type of combustion technology, including the advanced technology of this project, two problems of special interest must be addressed: developing and optimizing the combustion chambers and the systems for igniting and sustaining the fuel-burning process. For MSW in particular, there are new challenges over gaseous or liquid fuels because solid fuels must be ground into fine particulates ({approx} 10 {micro}m diameter), fed into the advanced combustor, and combusted under plasma-assisted conditions that are quite different than gaseous or liquid fuels. The principal idea of the combustion chamber design is to use so-called reverse vortex gas flow, which allows efficient cooling of the chamber wall and flame stabilization in the central area of the combustor (Tornado chamber). Considerable progress has been made in design ing an advanced, reverse vortex flow combustion chamber for biofuels, although it was not tested on biofuels and a system that could be fully commercialized has never been completed.

  3. Novel High Temperature Materials for In-Situ Sensing Devices

    SciTech Connect (OSTI)

    Florian Solzbacher; Anil Virkar; Loren Rieth; Srinivasan Kannan; Xiaoxin Chen; Hannwelm Steinebach

    2009-12-31T23:59:59.000Z

    The overriding goal of this project was to develop gas sensor materials and systems compatible with operation at temperatures from 500 to 700 C. Gas sensors operating at these temperatures would be compatible with placement in fossil-energy exhaust streams close to the combustion chamber, and therefore have advantages for process regulation, and feedback for emissions controls. The three thrusts of our work included investigating thin film gas sensor materials based on metal oxide materials and electroceramic materials, and also development of microhotplate devices to support the gas sensing films. The metal oxide materials NiO, In{sub 2}O{sub 3}, and Ga{sub 2}O{sub 3} were investigated for their sensitivity to H{sub 2}, NO{sub x}, and CO{sub 2}, respectively, at high temperatures (T > 500 C), where the sensing properties of these materials have received little attention. New ground was broken in achieving excellent gas sensor responses (>10) for temperatures up to 600 C for NiO and In{sub 2}O{sub 3} materials. The gas sensitivity of these materials was decreasing as temperatures increased above 500 C, which indicates that achieving strong sensitivities with these materials at very high temperatures (T {ge} 650 C) will be a further challenge. The sensitivity, selectivity, stability, and reliability of these materials were investigated across a wide range of deposition conditions, temperatures, film thickness, as using surface active promoter materials. We also proposed to study the electroceramic materials BaZr{sub (1-x)}Y{sub x}O{sub (3-x/2)} and BaCe{sub (2-x)}Ca{sub x}S{sub (4-x/2)} for their ability to detect H{sub 2}O and H{sub 2}S, respectively. This report focuses on the properties and gas sensing characteristics of BaZr{sub (1-x)}Y{sub x}O{sub (3-x/2)} (Y-doped BaZrO{sub 3}), as significant difficulties were encounter in generating BaCe{sub (2-x)}Ca{sub x}S{sub (4-x/2)} sensors. Significant new results were achieved for Y-doped BaZrO{sub 3}, including sensitivities of more than 60 atm{sup -1} for H{sub 2}O vapor at 400 C. These results were achieved despite significant difficulties with a strong Ba deficiency in the deposited films, and difficulties with stress in the targets and films. Ultimately, these films achieved good sensitivity, selectivity, and reliability in our gas sensing tests. The final thrust of our project was to develop microhotpates. We proposed the use of SiC thin films for the heater of the microhotplate, but despite extensive efforts we were not able to secure a reliable source of SiC. An alternative microhotplate architecture using SiO{sub 2} and Si{sub 3}N{sub 4} suspended membrane structures, and a polysilicon heater were developed, which could be fabricate at commercial MEMs foundries. These microhotplates were fabricated at Microtechnology Services Frankfurt (MSF) in Germany. The fabricated heaters were able to achieve temperatures > 600 C using {approx} 0.25 W, and when combined with In{sub 2}O{sub 3} films demonstrated sensor systems with sensor responses up to 50 for 25 ppm NO{sub x}, and time constants of less than 10 s.

  4. Final Scientific Report - "Novel Steels for High Temperature Carburizing"

    SciTech Connect (OSTI)

    McKimpson, Marvin G.; Liu, Tianjun; Maniruzzaman, Md

    2012-07-27T23:59:59.000Z

    This program was undertaken to develop a microalloy-modified grade of standard carburizing steel that can successfully exploit the high temperature carburizing capabilities of current commercial low pressure (i.e. 'vacuum') carburizing systems. Such steels can lower the amount of energy required for commercial carburizing operations by reducing the time required for deep-case carburizing operations. The specific technical objective of the work was to demonstrate a carburizing steel composition capable of maintaining a prior austenite grain size no larger than ASTM grain size number 5 after exposure to simulated carburizing conditions of 1050 C for 8 hr. Such thermal exposure should be adequate for producing carburized case depths up to about 2 mm. Such carburizing steels are expected to be attractive for use across a wide range of industries, including the petroleum, chemical, forest products, automotive, mining and industrial equipment industries. They have potential for reducing energy usage during low pressure carburizing by more than 25%, as well as reducing cycle times and process costs substantially. They also have potential for reducing greenhouse gas emissions from existing low pressure carburizing furnaces by more than 25%. High temperature carburizing can be done in most modern low pressure carburizing systems with no additional capital investment. Accordingly, implementing this technology on carburizing furnaces will provide a return on investment significantly greater than 10%. If disseminated throughout the domestic carburizing community, the technology has potential for saving on the order of 23 to 34 trillion BTU/year in industrial energy usage. Under the program, two compositions of microalloyed, coarsening-resistant low alloy carburizing steels were developed, produced and evaluated. After vacuum annealing at 1050oC for 8 hrs and high pressure gas quenching, both steels exhibited a prior austenite ASTM grain size number of 5.0 or finer. For comparison, a control alloy of similar composition but without the microalloy additions exhibited a duplex prior austenite grain size with grains ranging from ASTM grain size 3 down to ASTM grain size 1 after similar processing and thermal exposure. These results confirm the potential for using microalloy additions of Ti, B, Nb, Al, rare earths and/or N for austenite grain size control in Cr-Mo (i.e. 4000-series) low alloy carburizing steels. They also demonstrate that these microalloy additions will not compromise the processability of the steel; all three materials produced under the program could be hot worked readily using normal steel processing protocols. To fully realize the technical and commercial potential of these steels, there is a need to continue development work using larger-scale heats. These larger-scale heats are needed to provide adequate material for fatigue testing of quenched and tempered alloys, to conduct more complete investigations of potential alloy chemistries and to provide additional material for processing studies. It will also be beneficial to carefully review intellectual property issues associated with this family of steels, since existing Japanese patent literature suggests that significant microstructural and/or process characterization work may be needed on new materials to confirm that these materials fall outside existing patent claims.

  5. High-temperature corrosion in advanced combustion systems

    SciTech Connect (OSTI)

    Natesan, K.; Yanez-Herrero, M.; Fornasieri, C.

    1993-11-01T23:59:59.000Z

    Conceptual designs of advanced combustion systems that utilize coal as a feedstock require high temperature furnaces and heat transfer surfaces capable of operation at much elevated temperatures than those prevalent in current coal-fired power plants. The combination of elevated temperatures and hostile combustion environments necessitate development/application of advanced ceramic materials in these designs. The present paper characterizes the chemistry of coal-fired combustion environments over a wide temperature range of interest in these systems and discusses preliminary experimental results on several materials with potential for application in these systems. An experimental program has been initiated to evaluate materials for advanced combustion systems. Several candidate materials have been identified for evaluation. The candidates included advanced metallic alloys, monolithic ceramics, ceramic particulate/ceramic matrix composites, ceramic fiber/ceramic matrix composites, and ceramic whisker/ceramic matrix composites. The materials examined so far included nickel-base superalloys, alumina, stabilized zirconia, different types of silicon carbide, and silicon nitride. Coupon specimens of several of the materials have been tested in an air environment at 1000, 1200, and 1400{degree}C for 168 h. In addition, specimens were exposed to sodium-sulfate-containing salts at temperatures of 1000 and 1200{degree}C for 168 h. Extensive microstructural analyses were conducted on the exposed specimens to evaluate the corrosion performance of the materials for service in air and fireside environments of advanced coal-fired boilers. Additional tests are underway with several of the materials to evaluate their corrosion performance as a function of salt chemistry, alkali vapor concentration, gas chemistry, exposure temperature, and exposure time.

  6. High Temperature Gas Reactors: Assessment of Applicable Codes and Standards

    SciTech Connect (OSTI)

    McDowell, Bruce K.; Nickolaus, James R.; Mitchell, Mark R.; Swearingen, Gary L.; Pugh, Ray

    2011-10-31T23:59:59.000Z

    Current interest expressed by industry in HTGR plants, particularly modular plants with power up to about 600 MW(e) per unit, has prompted NRC to task PNNL with assessing the currently available literature related to codes and standards applicable to HTGR plants, the operating history of past and present HTGR plants, and with evaluating the proposed designs of RPV and associated piping for future plants. Considering these topics in the order they are arranged in the text, first the operational histories of five shut-down and two currently operating HTGR plants are reviewed, leading the authors to conclude that while small, simple prototype HTGR plants operated reliably, some of the larger plants, particularly Fort St. Vrain, had poor availability. Safety and radiological performance of these plants has been considerably better than LWR plants. Petroleum processing plants provide some applicable experience with materials similar to those proposed for HTGR piping and vessels. At least one currently operating plant - HTR-10 - has performed and documented a leak before break analysis that appears to be applicable to proposed future US HTGR designs. Current codes and standards cover some HTGR materials, but not all materials are covered to the high temperatures envisioned for HTGR use. Codes and standards, particularly ASME Codes, are under development for proposed future US HTGR designs. A 'roadmap' document has been prepared for ASME Code development; a new subsection to section III of the ASME Code, ASME BPVC III-5, is scheduled to be published in October 2011. The question of terminology for the cross-duct structure between the RPV and power conversion vessel is discussed, considering the differences in regulatory requirements that apply depending on whether this structure is designated as a 'vessel' or as a 'pipe'. We conclude that designing this component as a 'pipe' is the more appropriate choice, but that the ASME BPVC allows the owner of the facility to select the preferred designation, and that either designation can be acceptable.

  7. Air Cooling for High Temperature Power Electronics (Presentation)

    SciTech Connect (OSTI)

    Waye, S.; Musselman, M.; King, C.

    2014-09-01T23:59:59.000Z

    Current emphasis on developing high-temperature power electronics, including wide-bandgap materials such as silicon carbide and gallium nitride, increases the opportunity for a completely air-cooled inverter at higher powers. This removes the liquid cooling system for the inverter, saving weight and volume on the liquid-to-air heat exchanger, coolant lines, pumps, and coolant, replacing them with just a fan and air supply ducting. We investigate the potential for an air-cooled heat exchanger from a component and systems-level approach to meet specific power and power density targets. A proposed baseline air-cooled heat exchanger design that does not meet those targets was optimized using a parametric computational fluid dynamics analysis, examining the effects of heat exchanger geometry and device location, fixing the device heat dissipation and maximum junction temperature. The CFD results were extrapolated to a full inverter, including casing, capacitor, bus bar, gate driver, and control board component weights and volumes. Surrogate ducting was tested to understand the pressure drop and subsequent system parasitic load. Geometries that met targets with acceptable loads on the system were down-selected for experimentation. Nine baseline configuration modules dissipated the target heat dissipation, but fell below specific power and power density targets. Six optimized configuration modules dissipated the target heat load, exceeding the specific power and power density targets. By maintaining the same 175 degrees C maximum junction temperature, an optimized heat exchanger design and higher device heat fluxes allowed a reduction in the number of modules required, increasing specific power and power density while still maintaining the inverter power.

  8. Multiyear Program Plan for the High Temperature Materials Laboratory

    SciTech Connect (OSTI)

    Arvid E. Pasto

    2000-03-17T23:59:59.000Z

    Recently, the U.S. Department of Energy's (DOE) Office of Heavy Vehicle Technologies (OHVT) prepared a Technology Roadmap describing the challenges facing development of higher fuel efficiency, less polluting sport utility vehicles, vans, and commercial trucks. Based on this roadmap, a multiyear program plan (MYPP) was also developed, in which approaches to solving the numerous challenges are enumerated. Additional planning has been performed by DOE and national laboratory staff, on approaches to solving the numerous challenges faced by heavy vehicle system improvements. Workshops and planning documents have been developed concerning advanced aerodynamics, frictional and other parasitic losses, and thermal management. Similarly, the Heavy Vehicle Propulsion Materials Program has developed its own multiyear program plan. The High Temperature Materials Laboratory, a major user facility sponsored by OHVT, has now developed its program plan, described herein. Information was gathered via participation in the development of OHVT's overall Technology Roadmap and MYPP, through personal contacts within the materials-user community, and from attendance at conferences and expositions. Major materials issues for the heavy vehicle industry currently center on trying to increase efficiency of (diesel) engines while at the same time reducing emissions (particularly NO{sub x} and particulates). These requirements dictate the use of increasingly stronger, higher-temperature capable and more corrosion-resistant materials of construction, as well as advanced catalysts, particulate traps, and other pollution-control devices. Exhaust gas recirculation (EGR) is a technique which will certainly be applied to diesel engines in the near future, and its use represents a formidable challenge, as will be described later. Energy-efficient, low cost materials processing methods and surface treatments to improve wear, fracture, and corrosion resistance are also required.

  9. NOvel Refractory Materials for High Alkali, High Temperature Environments

    SciTech Connect (OSTI)

    Hemrick, J.G.; Griffin, R. (MINTEQ International, Inc.)

    2011-08-30T23:59:59.000Z

    Refractory materials can be limited in their application by many factors including chemical reactions between the service environment and the refractory material, mechanical degradation of the refractory material by the service environment, temperature limitations on the use of a particular refractory material, and the inability to install or repair the refractory material in a cost effective manner or while the vessel was in service. The objective of this project was to address the need for new innovative refractory compositions by developing a family of novel MgO-Al2O3 spinel or other similar magnesia/alumina containing unshaped refractory composition (castables, gunnables, shotcretes, etc) utilizing new aggregate materials, bond systems, protective coatings, and phase formation techniques (in-situ phase formation, altered conversion temperatures, accelerated reactions, etc). This family of refractory compositions would then be tailored for use in high-temperature, highalkaline industrial environments like those found in the aluminum, chemical, forest products, glass, and steel industries. A research team was formed to carry out the proposed work led by Oak Ridge National Laboratory (ORNL) and was comprised of the academic institution Missouri University of Science and Technology (MS&T), and the industrial company MINTEQ International, Inc. (MINTEQ), along with representatives from the aluminum, chemical, glass, and forest products industries. The two goals of this project were to produce novel refractory compositions which will allow for improved energy efficiency and to develop new refractory application techniques which would improve the speed of installation. Also methods of hot installation were sought which would allow for hot repairs and on-line maintenance leading to reduced process downtimes and eliminating the need to cool and reheat process vessels.

  10. Preventing fuel failure for a beyond design basis accident in a fluoride salt cooled high temperature reactor

    E-Print Network [OSTI]

    Minck, Matthew J. (Matthew Joseph)

    2013-01-01T23:59:59.000Z

    The fluoride salt-cooled high-temperature reactor (FHR) combines high-temperature coated-particle fuel with a high-temperature salt coolant for a reactor with unique market and safety characteristics. This combination can ...

  11. ENGINEERING A NEW MATERIAL FOR HOT GAS CLEANUP

    SciTech Connect (OSTI)

    T.D. Wheelock; L.K. Doraiswamy; K.P. Constant

    2003-09-01T23:59:59.000Z

    The overall purpose of this project was to develop a superior, regenerable, calcium-based sorbent for desulfurizing hot coal gas with the sorbent being in the form of small pellets made with a layered structure such that each pellet consists of a highly reactive lime core enclosed within a porous protective shell of strong but relatively inert material. The sorbent can be very useful for hot gas cleanup in advanced power generation systems where problems have been encountered with presently available materials. An economical method of preparing the desired material was demonstrated with a laboratory-scale revolving drum pelletizer. Core-in-shell pellets were produced by first pelletizing powdered limestone or other calcium-bearing material to make the pellet cores, and then the cores were coated with a mixture of powdered alumina and limestone to make the shells. The core-in-shell pellets were subsequently calcined at 1373 K (1100 C) to sinter the shell material and convert CaCO{sub 3} to CaO. The resulting product was shown to be highly reactive and a very good sorbent for H{sub 2}S at temperatures in the range of 1113 to 1193 K (840 to 920 C) which corresponds well with the outlet temperatures of some coal gasifiers. The product was also shown to be both strong and attrition resistant, and that it can be regenerated by a cyclic oxidation and reduction process. A preliminary evaluation of the material showed that while it was capable of withstanding repeated sulfidation and regeneration, the reactivity of the sorbent tended to decline with usage due to CaO sintering. Also it was found that the compressive strength of the shell material depends on the relative proportions of alumina and limestone as well as their particle size distributions. Therefore, an extensive study of formulation and preparation conditions was conducted to improve the performance of both the core and shell materials. It was subsequently determined that MgO tends to stabilize the high-temperature reactivity of CaO. Therefore, a sorbent prepared from dolomite withstands the effects of repeated sulfidation and regeneration better than one prepared from limestone. It was also determined that both the compressive strength and attrition resistance of core-in-shell pellets depend on shell thickness and that the compressive strength can be improved by reducing both the particle size and amount of limestone in the shell preparation mixture. A semiempirical model was also found which seems to adequately represent the absorption process. This model can be used for analyzing and predicting sorbent performance, and, therefore, it can provide guidance for any additional development which may be required. In conclusion, the overall objective of developing an economical, reusable, and practical material was largely achieved. The material appears suitable for removing CO{sub 2} from fuel combustion products as well as for desulfurizing hot coal gas.

  12. Dual Phase Membrane for High temperature CO2 Separation

    SciTech Connect (OSTI)

    Jerry Y.S. Lin; Matthew Anderson

    2005-12-01T23:59:59.000Z

    Research in the previous years in this project found that stainless steel supports are oxidized during high temperature, dual phase membrane separation of carbon dioxide (with oxygen). Consequently, a new material has been sought to alleviate the problems with oxidation. Lanthanum cobaltite oxide is a suitable candidate for the support material in the dual phase membrane due to its oxidation resistance and electronic conductivity. Porous lanthanum cobaltite membranes were prepared via the citrate method, using nitrate metal precursors as the source of La, Sr, Co and Fe. The material was prepared and ground into a powder, which was subsequently pressed into disks for sintering at 900 C. Conductivity measurements were evaluated using the four-probe DC method. Support pore size was determined by helium permeation. Conductivity of the lanthanum cobaltite material was found to be at a maximum of 0.1856 S/cm at 550 C. The helium permeance of the lanthanum cobaltite membranes for this research was on the order of 10{sup -6} moles/m{sup 2} {center_dot} Pa {center_dot} s, proving that the membranes are porous after sintering at 900 C. The average pore size based on steady state helium permeance measurements was found to be between 0.37 and 0.57 {micro}m. The lanthanum cobaltite membranes have shown to have desired porosity, pore size and electric conductivity as the support for the dual-phase membranes. Molten carbonate was infiltrated to the pores of lanthanum cobaltite membranes support. After infiltration with molten carbonate, the helium permeance of the membranes decreased by three orders of magnitude to 10{sup -9} moles/m{sup 2} {center_dot} Pa {center_dot} s. This number, however, is one order of magnitude larger than the room temperate permeance of the stainless steel supports after infiltration with molten carbonate. Optimization of the dip coating process with molten carbonate will be evaluated to determine if lower permeance values can be obtained with the lanthanum cobaltite membrane supports.

  13. DUAL PHASE MEMBRANE FOR HIGH TEMPERATURE CO2 SEPARATION

    SciTech Connect (OSTI)

    Jerry Y.S. Lin; Seungjoon Chung; Matthew Anderson

    2005-12-01T23:59:59.000Z

    This project is intended to expand upon the previous year's research en route to the development of a sustainable dual phase membrane for CO{sub 2} separation. It was found that the pores within the supports had to be less than 9 {micro}m in order to maintain the stability of the dual phase membrane. Pores larger than 9 {micro}m would be unable to hold the molten carbonate phase in place, rendering the membrane ineffective. Calculations show that 80% of the pore volume of the 0.5 media grade metal support was filled with the molten carbonate. Information obtained from EDS and SEM confirmed that the molten carbonate completely infiltrated the pores on both the contact and non-contact size of the metal support. Permeation tests for CO{sub 2} and N{sub 2} at 450-750 C show very low permeance of those two gases through the dual phase membrane, which was expected due to the lack of ionization of those two gases. Permeance of the CO{sub 2} and O{sub 2} mixture was much higher, indicating that the gases do form an ionic species, CO{sub 3}{sup 2-}, enhancing transport through the membrane. However, at temperatures in excess of 650 C, the permeance of CO{sub 3}{sup 2-} decreased quite rapidly, while predictions showed that permeance should have continued to increase. XRD data obtained form the surface of the membrane indicated the formation of lithium iron oxides on the support. This layer has a very low conductivity, which drastically reduces the flow of electrons to the CO{sub 2}/O{sub 2} gas mixture, limiting the formation of the ionic species. These results indicate that the use of stainless steel supports in a high temperature oxidative environment can lead to decreased performance of the membranes. This revelation has created the need for an oxidation resistant support, which can be gained by the use of a ceramic-type membrane. Future research efforts will be directed towards preparation of a new ceramic-carbonate dual phase membrane. The membrane will based on an oxide ceramic support that has an oxidation resistance better than the metal support and high electronic conductivity (1200-1500 S/cm) in the interested temperature range (400-600 C).

  14. Deterministic Modeling of the High Temperature Test Reactor

    SciTech Connect (OSTI)

    Ortensi, J.; Cogliati, J. J.; Pope, M. A.; Ferrer, R. M.; Ougouag, A. M.

    2010-06-01T23:59:59.000Z

    Idaho National Laboratory (INL) is tasked with the development of reactor physics analysis capability of the Next Generation Nuclear Power (NGNP) project. In order to examine INL’s current prismatic reactor deterministic analysis tools, the project is conducting a benchmark exercise based on modeling the High Temperature Test Reactor (HTTR). This exercise entails the development of a model for the initial criticality, a 19 column thin annular core, and the fully loaded core critical condition with 30 columns. Special emphasis is devoted to the annular core modeling, which shares more characteristics with the NGNP base design. The DRAGON code is used in this study because it offers significant ease and versatility in modeling prismatic designs. Despite some geometric limitations, the code performs quite well compared to other lattice physics codes. DRAGON can generate transport solutions via collision probability (CP), method of characteristics (MOC), and discrete ordinates (Sn). A fine group cross section library based on the SHEM 281 energy structure is used in the DRAGON calculations. HEXPEDITE is the hexagonal z full core solver used in this study and is based on the Green’s Function solution of the transverse integrated equations. In addition, two Monte Carlo (MC) based codes, MCNP5 and PSG2/SERPENT, provide benchmarking capability for the DRAGON and the nodal diffusion solver codes. The results from this study show a consistent bias of 2–3% for the core multiplication factor. This systematic error has also been observed in other HTTR benchmark efforts and is well documented in the literature. The ENDF/B VII graphite and U235 cross sections appear to be the main source of the error. The isothermal temperature coefficients calculated with the fully loaded core configuration agree well with other benchmark participants but are 40% higher than the experimental values. This discrepancy with the measurement stems from the fact that during the experiments the control rods were adjusted to maintain criticality, whereas in the model, the rod positions were fixed. In addition, this work includes a brief study of a cross section generation approach that seeks to decouple the domain in order to account for neighbor effects. This spectral interpenetration is a dominant effect in annular HTR physics. This analysis methodology should be further explored in order to reduce the error that is systematically propagated in the traditional generation of cross sections.

  15. Deriving cleanup guidelines for radionuclides at Brookhaven National Laboratory

    SciTech Connect (OSTI)

    Meinhold, A.F.; Morris, S.C.; Dionne, B.; Moskowitz, P.D.

    1997-01-01T23:59:59.000Z

    Past activities at Brookhaven National Laboratory (BNL) resulted in soil and groundwater contamination. As a result, BNL was designated a Superfund site under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA). BNL`s Office of Environmental Restoration (OER) is overseeing environmental restoration activities at the Laboratory. With the exception of radium, there are no regulations or guidelines to establish cleanup guidelines for radionuclides in soils at BNL. BNL must derive radionuclide soil cleanup guidelines for a number of Operable Units (OUs) and Areas of Concern (AOCs). These guidelines are required by DOE under a proposed regulation for radiation protection of public health and the environment as well as to satisfy the requirements of CERCLA. The objective of this report is to propose a standard approach to deriving risk-based cleanup guidelines for radionuclides in soil at BNL. Implementation of the approach is briefly discussed.

  16. Development of OTM Syngas Process and Testing of Syngas Derived Ultra-clean Fuels in Diesel Engines and Fuel Cells

    SciTech Connect (OSTI)

    E.T. (Skip) Robinson; James P. Meagher; Prasad Apte; Xingun Gui; Tytus R. Bulicz; Siv Aasland; Charles Besecker; Jack Chen Bart A. van Hassel; Olga Polevaya; Rafey Khan; Piyush Pilaniwalla

    2002-12-31T23:59:59.000Z

    This topical report summarizes work accomplished for the Program from November 1, 2001 to December 31, 2002 in the following task areas: Task 1: Materials Development; Task 2: Composite Development; Task 4: Reactor Design and Process Optimization; Task 8: Fuels and Engine Testing; 8.1 International Diesel Engine Program; 8.2 Nuvera Fuel Cell Program; and Task 10: Program Management. Major progress has been made towards developing high temperature, high performance, robust, oxygen transport elements. In addition, a novel reactor design has been proposed that co-produces hydrogen, lowers cost and improves system operability. Fuel and engine testing is progressing well, but was delayed somewhat due to the hiatus in program funding in 2002. The Nuvera fuel cell portion of the program was completed on schedule and delivered promising results regarding low emission fuels for transportation fuel cells. The evaluation of ultra-clean diesel fuels continues in single cylinder (SCTE) and multiple cylinder (MCTE) test rigs at International Truck and Engine. FT diesel and a BP oxygenate showed significant emissions reductions in comparison to baseline petroleum diesel fuels. Overall through the end of 2002 the program remains under budget, but behind schedule in some areas.

  17. Needs for Risk Informing Environmental Cleanup Decision Making - 13613

    SciTech Connect (OSTI)

    Zhu, Ming; Moorer, Richard [U.S. Department of Energy, Washington, DC 20585 (United States)] [U.S. Department of Energy, Washington, DC 20585 (United States)

    2013-07-01T23:59:59.000Z

    This paper discusses the needs for risk informing decision making by the U.S. Department of Energy (DOE) Office of Environmental Management (EM). The mission of the DOE EM is to complete the safe cleanup of the environmental legacy brought about from the nation's five decades of nuclear weapons development and production and nuclear energy research. This work represents some of the most technically challenging and complex cleanup efforts in the world and is projected to require the investment of billions of dollars and several decades to complete. Quantitative assessments of health and environmental risks play an important role in work prioritization and cleanup decisions of these challenging environmental cleanup and closure projects. The risk assessments often involve evaluation of performance of integrated engineered barriers and natural systems over a period of hundreds to thousands of years, when subject to complex geo-environmental transformation processes resulting from remediation and disposal actions. The requirement of resource investments for the cleanup efforts and the associated technical challenges have subjected the EM program to continuous scrutiny by oversight entities. Recent DOE reviews recommended application of a risk-informed approach throughout the EM complex for improved targeting of resources. The idea behind this recommendation is that by using risk-informed approaches to prioritize work scope, the available resources can be best utilized to reduce environmental and health risks across the EM complex, while maintaining the momentum of the overall EM cleanup program at a sustainable level. In response to these recommendations, EM is re-examining its work portfolio and key decision making with risk insights for the major sites. This paper summarizes the review findings and recommendations from the DOE internal reviews, discusses the needs for risk informing the EM portfolio and makes an attempt to identify topics for R and D in integrated risk assessment that could assist in the EM prioritization efforts. (authors)

  18. Clean-up standards and pathways analysis methods

    SciTech Connect (OSTI)

    Devgun, J.S. [Argonne National Lab., IL (United States). Office of Waste Management Programs

    1993-12-31T23:59:59.000Z

    Remediation of a radioactively contaminated site requires that certain regulatory criteria be met before the site can be released for unrestricted future use. Since the ultimate objective of remediation is to protect the public health and safety, residual radioactivity levels remaining at a site after cleanup must be below certain preset limits or meet acceptable dose or risk criteria. This paper discusses cleanup standards for radioactively contaminated soils and describes the use of pathways analysis methods for deriving site-specific residual radioactivity guidelines. An example is provided in which a pathways analysis code (RESRAD) was used to establish such guidelines.

  19. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, John E. (Woodridge, IL); Jalan, Vinod M. (Concord, MA)

    1984-01-01T23:59:59.000Z

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  20. New Membranes for High Temperature Proton Exchange Membrane Fuel Cells Based on Heteropoly Acids

    Broader source: Energy.gov [DOE]

    "Summary of Colorado School of Mines heteropolyacid research presented to the High Temperature Membrane Working Group Meeting, Orlando FL, October 17, 2003 "