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1

Solid oxide steam electrolysis for high temperature hydrogen production .  

E-Print Network [OSTI]

??This study has focused on solid oxide electrolyser cells for high temperature steam electrolysis. Solid oxide electrolysis is the reverse operation of solid oxide fuel (more)

Eccleston, Kelcey L.

2007-01-01T23:59:59.000Z

2

DEGRADATION ISSUES IN SOLID OXIDE CELLS DURING HIGH TEMPERATURE ELECTROLYSIS  

SciTech Connect (OSTI)

Idaho National Laboratory (INL) is performing high-temperature electrolysis research to generate hydrogen using solid oxide electrolysis cells (SOECs). The project goals are to address the technical and degradation issues associated with the SOECs. This paper provides a summary of various ongoing INL and INL sponsored activities aimed at addressing SOEC degradation. These activities include stack testing, post-test examination, degradation modeling, and a list of issues that need to be addressed in future. Major degradation issues relating to solid oxide fuel cells (SOFC) are relatively better understood than those for SOECs. Some of the degradation mechanisms in SOFCs include contact problems between adjacent cell components, microstructural deterioration (coarsening) of the porous electrodes, and blocking of the reaction sites within the electrodes. Contact problems include delamination of an electrode from the electrolyte, growth of a poorly (electronically) conducting oxide layer between the metallic interconnect plates and the electrodes, and lack of contact between the interconnect and the electrode. INLs test results on high temperature electrolysis (HTE) using solid oxide cells do not provide a clear evidence whether different events lead to similar or drastically different electrochemical degradation mechanisms. Post-test examination of the solid oxide electrolysis cells showed that the hydrogen electrode and interconnect get partially oxidized and become non-conductive. This is most likely caused by the hydrogen stream composition and flow rate during cool down. The oxygen electrode side of the stacks seemed to be responsible for the observed degradation due to large areas of electrode delamination. Based on the oxygen electrode appearance, the degradation of these stacks was largely controlled by the oxygen electrode delamination rate. University of Utah (Virkar) has developed a SOEC model based on concepts in local thermodynamic equilibrium in systems otherwise in global thermodynamic non-equilibrium. This model is under continued development. It shows that electronic conduction through the electrolyte, however small, must be taken into account for determining local oxygen chemical potential, within the electrolyte. The chemical potential within the electrolyte may lie out of bounds in relation to values at the electrodes in the electrolyzer mode. Under certain conditions, high pressures can develop in the electrolyte just under the oxygen electrode (anode)/electrolyte interface, leading to electrode delamination. This theory is being further refined and tested by introducing some electronic conduction in the electrolyte.

J. E. O'Brien; C. M. Stoots; V. I. Sharma; B. Yildiz; A. V. Virkar

2010-06-01T23:59:59.000Z

3

DEGRADATION ISSUES IN SOLID OXIDE CELLS DURING HIGH TEMPERATURE ELECTROLYSIS  

SciTech Connect (OSTI)

Idaho National Laboratory (INL) is performing high-temperature electrolysis research to generate hydrogen using solid oxide electrolysis cells (SOECs). The project goals are to address the technical and degradation issues associated with the SOECs. This paper provides a summary of various ongoing INL and INL sponsored activities aimed at addressing SOEC degradation. These activities include stack testing, post-test examination, degradation modeling, and a list of issues that need to be addressed in future. Major degradation issues relating to solid oxide fuel cells (SOFC) are relatively better understood than those for SOECs. Some of the degradation mechanisms in SOFCs include contact problems between adjacent cell components, microstructural deterioration (coarsening) of the porous electrodes, and blocking of the reaction sites within the electrodes. Contact problems include delamination of an electrode from the electrolyte, growth of a poorly (electronically) conducting oxide layer between the metallic interconnect plates and the electrodes, and lack of contact between the interconnect and the electrode. INL's test results on high temperature electrolysis (HTE) using solid oxide cells do not provide a clear evidence whether different events lead to similar or drastically different electrochemical degradation mechanisms. Post-test examination of the solid oxide electrolysis cells showed that the hydrogen electrode and interconnect get partially oxidized and become non-conductive. This is most likely caused by the hydrogen stream composition and flow rate during cool down. The oxygen electrode side of the stacks seemed to be responsible for the observed degradation due to large areas of electrode delamination. Based on the oxygen electrode appearance, the degradation of these stacks was largely controlled by the oxygen electrode delamination rate. University of Utah (Virkar) has developed a SOEC model based on concepts in local thermodynamic equilibrium in systems otherwise in global thermodynamic non-equilibrium. This model is under continued development. It shows that electronic conduction through the electrolyte, however small, must be taken into account for determining local oxygen chemical potential, within the electrolyte. The chemical potential within the electrolyte may lie out of bounds in relation to values at the electrodes in the electrolyzer mode. Under certain conditions, high pressures can develop in the electrolyte just under the oxygen electrode (anode)/electrolyte interface, leading to electrode delamination. This theory is being further refined and tested by introducing some electronic conduction in the electrolyte.

M. S. Sohal; J. E. O'Brien; C. M. Stoots; V. I. Sharma; B. Yildiz; A. Virkar

2012-02-01T23:59:59.000Z

4

EA-0510: High-Temperature Solid Oxide Fuel Cell (Sofc) Generator  

Broader source: Energy.gov (indexed) [DOE]

510: High-Temperature Solid Oxide Fuel Cell (Sofc) Generator 510: High-Temperature Solid Oxide Fuel Cell (Sofc) Generator Development Project (METC), Churchill, Pennsylvania EA-0510: High-Temperature Solid Oxide Fuel Cell (Sofc) Generator Development Project (METC), Churchill, Pennsylvania SUMMARY This EA evaluates the environmental impacts of a proposal to enter into a 5-year cooperative agreement with the Westinghouse Electric Corporation for the development of high-temperature solid oxide fuel cell generators near Pittsburgh, Pennsylvania. PUBLIC COMMENT OPPORTUNITIES None available at this time. DOCUMENTS AVAILABLE FOR DOWNLOAD August 1, 1991 EA-0510: Final Environmental Assessment High-Temperature Solid Oxide Fuel Cell (Sofc) Generator Development Project (METC) August 1, 1991 EA-0510: Finding of No Significant Impact

5

CHALLENGES IN GENERATING HYDROGEN BY HIGH TEMPERATURE ELECTROLYSIS USING SOLID OXIDE CELLS  

SciTech Connect (OSTI)

Idaho National Laboratorys (INL) high temperature electrolysis research to generate hydrogen using solid oxide electrolysis cells is presented in this paper. The research results reported here have been obtained in a laboratory-scale apparatus. These results and common scale-up issues also indicate that for the technology to be successful in a large industrial setting, several technical, economical, and manufacturing issues have to be resolved. Some of the issues related to solid oxide cells are stack design and performance optimization, identification and evaluation of cell performance degradation parameters and processes, integrity and reliability of the solid oxide electrolysis (SOEC) stacks, life-time prediction and extension of the SOEC stack, and cost reduction and economic manufacturing of the SOEC stacks. Besides the solid oxide cells, balance of the hydrogen generating plant also needs significant development. These issues are process and ohmic heat source needed for maintaining the reaction temperature (~830C), high temperature heat exchangers and recuperators, equal distribution of the reactants into each cell, system analysis of hydrogen and associated energy generating plant, and cost optimization. An economic analysis of this plant was performed using the standardized H2A Analysis Methodology developed by the Department of Energy (DOE) Hydrogen Program, and using realistic financial and cost estimating assumptions. The results of the economic analysis demonstrated that the HTE hydrogen production plant driven by a high-temperature helium-cooled nuclear power plant can deliver hydrogen at a cost of $3.23/kg of hydrogen assuming an internal rate of return of 10%. These issues need interdisciplinary research effort of federal laboratories, solid oxide cell manufacturers, hydrogen consumers, and other such stakeholders. This paper discusses research and development accomplished by INL on such issues and highlights associated challenges that need to be addressed for hydrogen to become an economical and viable option.

M. S. Sohal; J. E. O'Brien; C. M. Stoots; M. G. McKellar; J. S. Herring; E. A. Harvego

2008-03-01T23:59:59.000Z

6

2500-Hour High Temperature Solid-Oxide Electrolyzer Long Duration Test  

SciTech Connect (OSTI)

The Idaho National Laboratory (INL) has been developing the concept of using solid oxide fuel cells as electrolyzers for large-scale, high-temperature (efficient), hydrogen production. This program is sponsored by the U.S. Department of Energy under the Nuclear Hydrogen Initiative. Utilizing a fuel cell as an electrolyzer introduces some inherent differences in cell operating conditions. In particular, the performance of fuel cells operated as electrolyzers degrades with time faster. This issue of electrolyzer cell and stack performance degradation over time has been identified as a major barrier to technology development. Consequently, the INL has been working together with Ceramatec, Inc. (Salt Lake City, Utah) to improve the long-term performance of high temperature electrolyzers. As part of this research partnership, the INL conducted a 2500 hour test of a Ceramatec designed and produced stack operated in the electrolysis mode. This report will provide a summary of experimental results for this long duration test.

C. M. Stoots; J. E. O'Brien; K. G. Condie; L. Moore-McAteer; J. J. Hartvigsen; D. Larsen

2009-11-01T23:59:59.000Z

7

High Temperature Solid-Oxide Electrolyzer 2500 Hour Test Results At The Idaho National Laboratory  

SciTech Connect (OSTI)

The Idaho National Laboratory (INL) has been developing the concept of using solid oxide fuel cells as electrolyzers for large-scale, high-temperature (efficient), hydrogen production. This program is sponsored by the U.S. Department of Energy under the Nuclear Hydrogen Initiative. Utilizing a fuel cell as an electrolyzer introduces some inherent differences in cell operating conditions. In particular, the performance of fuel cells operated as electrolyzers degrades with time faster. This issue of electrolyzer cell and stack performance degradation over time has been identified as a major barrier to technology development. Consequently, the INL has been working together with Ceramatec, Inc. (Salt Lake City, Utah) to improve the long-term performance of high temperature electrolyzers. As part of this research partnership, the INL conducted a 2500 hour test of a Ceramatec designed and produced stack operated in the electrolysis mode. This paper will provide a summary of experimental results to date for this ongoing test.

Carl Stoots; James O'Brien; Stephen Herring; Keith Condie; Lisa Moore-McAteer; Joseph J. Hartvigsen; Dennis Larsen

2009-11-01T23:59:59.000Z

8

Low cost stable air electrode material for high temperature solid oxide electrolyte electrochemical cells  

DOE Patents [OSTI]

A low cost, lanthanide-substituted, dimensionally and thermally stable, gas permeable, electrically conductive, porous ceramic air electrode composition of lanthanide-substituted doped lanthanum manganite is provided which is used as the cathode in high temperature, solid oxide electrolyte fuel cells and generators. The air electrode composition of this invention has a much lower fabrication cost as a result of using a lower cost lanthanide mixture, either a natural mixture or an unfinished lanthanide concentrate obtained from a natural mixture subjected to incomplete purification, as the raw material in place of part or all of the higher cost individual lanthanum. The mixed lanthanide primarily contains a mixture of at least La, Ce, Pr, and Nd, or at least La, Ce, Pr, Nd and Sm in its lanthanide content, but can also include minor amounts of other lanthanides and trace impurities. The use of lanthanides in place of some or all of the lanthanum also increases the dimensional stability of the air electrode. This low cost air electrode can be fabricated as a cathode for use in high temperature, solid oxide fuel cells and generators.

Kuo, Lewis J. H. (Monroeville, PA); Singh, Prabhakar (Export, PA); Ruka, Roswell J. (Churchill Boro, PA); Vasilow, Theodore R. (Penn Township, PA); Bratton, Raymond J. (Delmont, PA)

1997-01-01T23:59:59.000Z

9

Low cost stable air electrode material for high temperature solid oxide electrolyte electrochemical cells  

DOE Patents [OSTI]

A low cost, lanthanide-substituted, dimensionally and thermally stable, gas permeable, electrically conductive, porous ceramic air electrode composition of lanthanide-substituted doped lanthanum manganite is provided which is used as the cathode in high temperature, solid oxide electrolyte fuel cells and generators. The air electrode composition of this invention has a much lower fabrication cost as a result of using a lower cost lanthanide mixture, either a natural mixture or an unfinished lanthanide concentrate obtained from a natural mixture subjected to incomplete purification, as the raw material in place of part or all of the higher cost individual lanthanum. The mixed lanthanide primarily contains a mixture of at least La, Ce, Pr, and Nd, or at least La, Ce, Pr, Nd and Sm in its lanthanide content, but can also include minor amounts of other lanthanides and trace impurities. The use of lanthanides in place of some or all of the lanthanum also increases the dimensional stability of the air electrode. This low cost air electrode can be fabricated as a cathode for use in high temperature, solid oxide fuel cells and generators. 4 figs.

Kuo, L.J.H.; Singh, P.; Ruka, R.J.; Vasilow, T.R.; Bratton, R.J.

1997-11-11T23:59:59.000Z

10

Mechanical properties of solid oxide fuel cell glass-ceramic seal at high temperatures  

SciTech Connect (OSTI)

Mechanical properties of solid oxide fuel cell glass-ceramic seal material, G18, are studied at high temperatures. Samples of G18 are aged for either 4h or 100h, resulting in samples with different crystallinity. Reduced modulus, hardness, and time-dependent behavior are measured by nanoindentation. The nanoindentation is performed at room temperature, 550, 650, and 750C, using loading rates of 5 mN/s and 25 mN/s. Results show a decrease in reduced modulus with increasing temperature, with significant decrease above the glass transition temperature (Tg). Hardness generally decreases with increasing temperature, with a slight increase before Tg for the 4h aged sample. Dwell tests show that creep increases with increasing temperature, but decrease with further aging.

Milhans, Jacqueline; Li, Dongsheng; Khaleel, Mohammad A.; Sun, Xin; Al-Haik, Marwan; Harris, Adrian; Garmestani, Hamid

2011-04-20T23:59:59.000Z

11

Mechanistic Studies of Water Electrolysis and Hydrogen Electro-Oxidation on High Temperature Ceria-Based Solid Oxide  

E-Print Network [OSTI]

conversion devices with multicomponent materials (e.g., solid oxide fuel cells, electrolyzers-Based Solid Oxide Electrochemical Cells Chunjuan Zhang,,# Yi Yu,,# Michael E. Grass,,# Catherine Dejoie spectroscopy (APXPS) and a single-sided solid oxide electrochemical cell (SOC), we have studied the mechanism

Li, Weixue

12

Effect of pre-oxidation and environmental aging on the seal strength of a novel high-temperature solid oxide fuel cell (SOFC) sealing glass with metallic interconnect  

SciTech Connect (OSTI)

A novel high-temperature alkaline-earth silicate sealing glass was developed for solid oxide fuel cell (SOFC) applications. The glass was used to join two ferritic stainless steel coupons for strength evaluation. The steel coupons were pre-oxidized at elevated temperatures to promote thick oxide layers to simulate long-term exposure conditions. In addition, seals to as-received metal coupons were also tested after aging in oxidizing or reducing environments to simulate the actual SOFC environment. Room temperature tensile testing showed strength degradation when using pre-oxidized coupons, and more extensive degradation after aging in air. Fracture surface and microstructural analysis confirmed that the cause of degradation was formation of SrCrO4 at the outer sealing edges exposed to air.

Chou, Y. S.; Stevenson, Jeffry W.; Singh, Prabhakar

2008-09-15T23:59:59.000Z

13

SYNGAS PRODUCTION VIA HIGH-TEMPERATURE CO-ELECTROLYSIS OF STEAM AND CARBON DIOXIDE IN A SOLID-OXIDE STACK  

SciTech Connect (OSTI)

This paper presents results of recent experiments conducted at the INL studying coelectrolysis of steam and carbon dioxide in a 10-cell high-temperature solid-oxide electrolysis stack. Coelectrolysis is complicated by the fact that the reverse shift reaction occurs concurrently with the electrolytic reduction reactions. All reactions must be properly accounted for when evaluating results. Electrochemical performance of the stack was evaluated over a range of temperatures, compositions, and flow rates. The apparatus used for these tests is heavily instrumented, with precision mass-flow controllers, on-line dewpoint and CO2 sensors, and numerous pressure and temperature measurement stations. It also includes a gas chromatograph for analyzing outlet gas compositions. Comparisons of measured compositions to predictions obtained from a chemical equilibrium co-electrolysis model are presented, along with corresponding polarization curves. Results indicate excellent agreement between predicted and measured outlet compositions. Coelectrolysis significantly increases the yield of syngas over the reverse water gas shift reaction equilibrium composition. The process appears to be a promising technique for large-scale syngas production.

Carl M. Stoots; James E. O'Brien; Joseph J. Hartvigsen

2007-06-01T23:59:59.000Z

14

The High-Temperature Oxidation of Propane  

Science Journals Connector (OSTI)

...research-article The High-Temperature Oxidation of Propane J. W. Falconer J. H. Knox Above 400 degrees C propane is oxidized by a two-stage degenerately...of propylene becomes important. While propane still in the main reacts to form propylene...

1959-01-01T23:59:59.000Z

15

High temperature phase stabilities and electrochemical properties of InBaCo4-xZnxO7 cathodes for intermediate temperature solid oxide fuel cells  

SciTech Connect (OSTI)

InBaCo4-xZnxO7 oxides have been synthesized and characterized as cathode materials for intermediate temperature solid oxide fuel cells (IT-SOFC). The effect of Zn substitution for Co on the structure, phase stability, thermal expansion, and electrochemical properties of the InBaCo4-xZnxO7 has been investigated. The increase in the Zn content from x = 1 to 1.5 improves the high temperature phase stability at 600 oC and 700 oC for 100 h, and chemical stability against a Gd0.2Ce0.8O1.9 (GDC) electrolyte. Thermal expansion coefficient (TEC) values of the InBaCo4-xZnxO7 (x = 1, 1.5, 2) specimens were determined to be 8.6 10-6 9.6 10-6 /oC in the range of 80 900 oC, which provides good thermal expansion compatibility with the standard SOFC electrolyte materials. The InBaCo4-xZnxO7 + GDC (50:50 wt. %) composite cathodes exhibit improved cathode performances compared to those obtained from the simple InBaCo4-xZnxO7 cathodes due to the extended triple-phase boundary (TPB) and enhanced oxide-ion conductivity through the GDC portion in the composites.

Kim, Jung-Hyun [ORNL; Young Nam, Kim [University of Texas, Austin; Bi, Zhonghe [ORNL; Manthiram, Arumugam [University of Texas, Austin; Paranthaman, Mariappan Parans [ORNL; Huq, Ashfia [ORNL

2011-01-01T23:59:59.000Z

16

Effect of aluminizing of Cr-containing ferritic alloys on the seal strength of a novel high-temperature solid oxide fuel cell sealing glass  

SciTech Connect (OSTI)

A novel high-temperature alkaline-earth silicate sealing glass was developed for solid oxide fuel cell (SOFC) applications. The glass was used to join two metallic coupons of Cr-containing ferritic stainless steel for seal strength evaluation. In previous work, SrCrO4 was found to form along the glass/steel interface, which led to severe strength degradation. In the present study, aluminization of the steel surface was investigated as a remedy to minimize or prevent the strontium chromate formation. Three different processes for aluminization were evaluated with Crofer22APU stainless steel: pack cementation, vapor phase deposition, and aerosol spraying. It was found that pack cementation resulted in a rough surface with occasional cracks in the Al-diffused region. Vapor phase deposition yielded a smoother surface, but the resulting high Al content increased the coefficient of thermal expansion (CTE), resulting in failure of joined coupons. Aerosol spraying of an Al-containing salt resulted in formation of a thin aluminum oxide layer without any surface damage. The room temperature seal strength was evaluated in the as-fired state and in environmentally aged conditions. In contrast to earlier results with uncoated Crofer22APU, the aluminized samples showed no strength degradation even for samples aged in air. Interfacial and chemical compatibility was also investigated. The results showed aluminization to be a viable candidate approach to minimize undesirable chromate formation between alkaline earth silicate sealing glass and Cr-containing interconnect alloys for SOFC applications.

Chou, Y. S.; Stevenson, Jeffry W.; Singh, Prabhakar

2008-12-01T23:59:59.000Z

17

(Y0.5In0.5)Ba(Co,Zn)4O7 cathodes with superior high-temperature phase stability for solid oxide fuel cells  

SciTech Connect (OSTI)

(Y0.5In0.5)BaCo4-xZnxO7 (1.0 x 2.0) oxides crystallizing in a trigonal P31c structure have been synthesized and explored as cathode materials for solid oxide fuel cells (SOFC). At a given Zn content, the (Y0.5In0.5)BaCo4-xZnxO7 sample with 50 % Y and 50 % In exhibits much improved phase stability at intermediate temperatures (600 - 800 oC) compared to the samples with 100 % Y or In. However, the substitution of Zn for Co in (Y0.5In0.5)Ba(Co4-xZnx)O7 (1.0 x 2.0) decreases the amount of oxygen loss on heating, total electrical conductivity, and cathode performance in SOFC while providing good long-term phase stability at high temperatures. Among the various chemical compositions investigated in the (Y0.5In0.5)Ba(Co4-xZnx)O7 system, the (Y0.5In0.5)BaCo3ZnO7 sample offers a combination of good electrochemical performance and low thermal expansion coefficient (TEC) while maintaining superior phase stability at 600 800 oC for 100 h. Fuel cell performances of the (Y0.5In0.5)Ba(Co3Zn)O7 + Ce0.8Gd0.2O1.9 (GDC) (50 : 50 wt. %) composite cathodes collected with anode-supported single cell reveal a maximum power density value of 521 mW cm-2 at 700 oC.

Young Nam, Kim [University of Texas, Austin; Kim, Jung-Hyun [ORNL; Paranthaman, Mariappan Parans [ORNL; Manthiram, Arumugam [University of Texas, Austin; Huq, Ashfia [ORNL

2012-01-01T23:59:59.000Z

18

Protective interlayer for high temperature solid electrolyte electrochemical cells  

DOE Patents [OSTI]

The invention is comprised of an electrically conducting doped or admixed cerium oxide composition with niobium oxide and/or tantalum oxide for electrochemical devices, characterized by the general formula: Nb{sub x}Ta{sub y}Ce{sub 1{minus}x{minus}y}O{sub 2} where x is about 0.0 to 0.05, y is about 0.0 to 0.05, and x+y is about 0.02 to 0.05, and where x is preferably about 0.02 to 0.05 and y is 0, and a method of making the same is also described. This novel composition is particularly applicable in forming a protective interlayer of a high temperature, solid electrolyte electrochemical cell, characterized by a first electrode; an electrically conductive interlayer of niobium and/or tantalum doped cerium oxide deposited over at least a first portion of the first electrode; an interconnect deposited over the interlayer; a solid electrolyte deposited over a second portion of the first electrode, the first portion being discontinuous from the second portion; and, a second electrode deposited over the solid electrolyte. The interlayer is characterized as being porous and selected from the group consisting of niobium doped cerium oxide, tantalum doped cerium oxide, and niobium and tantalum doped cerium oxide or admixtures of the same. The first electrode, an air electrode, is a porous layer of doped lanthanum manganite, the solid electrolyte layer is a dense yttria stabilized zirconium oxide, the interconnect layer is a dense, doped lanthanum chromite, and the second electrode, a fuel electrode, is a porous layer of nickel-zirconium oxide cermet. The electrochemical cell can take on a plurality of shapes such as annular, planar, etc. and can be connected to a plurality of electrochemical cells in series and/or in parallel to generate electrical energy. 5 figs.

Singh, P.; Vasilow, T.R.; Richards, V.L.

1996-05-14T23:59:59.000Z

19

Protective interlayer for high temperature solid electrolyte electrochemical cells  

DOE Patents [OSTI]

The invention comprises of an electrically conducting doped or admixed cerium oxide composition with niobium oxide and/or tantalum oxide for electrochemical devices, characterized by the general formula: Nb.sub.x Ta.sub.y Ce.sub.1-x-y O.sub.2 where x is about 0.0 to 0.05, y is about 0.0 to 0.05, and x+y is about 0.02 to 0.05, and where x is preferably about 0.02 to 0.05 and y is 0, and a method of making the same. This novel composition is particularly applicable in forming a protective interlayer of a high temperature, solid electrolyte electrochemical cell (10), characterized by a first electrode (12); an electrically conductive interlayer (14) of niobium and/or tantalum doped cerium oxide deposited over at least a first portion (R) of the first electrode; an interconnect (16) deposited over the interlayer; a solid electrolyte (18) deposited over a second portion of the first electrode, the first portion being discontinuous from the second portion; and, a second electrode (20) deposited over the solid electrolyte. The interlayer (14) is characterized as being porous and selected from the group consisting of niobium doped cerium oxide, tantalum doped cerium oxide, and niobium and tantalum doped cerium oxide or admixtures of the same. The first electrode (12), an air electrode, is a porous layer of doped lanthanum manganite, the solid electrolyte layer (18) is a dense yttria stabilized zirconium oxide, the interconnect layer (16) is a dense, doped lanthanum chromite, and the second electrode (20), a fuel electrode, is a porous layer of nickel-zirconium oxide cermet. The electrochemical cell (10) can take on a plurality of shapes such as annular, planar, etc. and can be connected to a plurality of electrochemical cells in series and/or in parallel to generate electrical energy.

Singh, Prabhakar (Export, PA); Vasilow, Theodore R. (Manor, PA); Richards, Von L. (Angola, IN)

1996-01-01T23:59:59.000Z

20

BaZn{sub 2}Si{sub 2}O{sub 7} and the solid solution series BaZn{sub 2?x}Co{sub x}Si{sub 2}O{sub 7} (0high temperature seals for solid oxide fuel cells studied by high-temperature X-ray diffraction and dilatometry  

SciTech Connect (OSTI)

For sealing of solid oxide fuel cells, glasses from which crystalline phases with high coefficient of thermal expansion (CTE) can be crystallized are required. In this paper, a new solid solution series BaZn{sub 2?x}Co{sub x}Si{sub 2}O{sub 7} (0high-temperature X-ray diffraction (BaZn{sub 2}Si{sub 2}O{sub 7}). Sintered specimens were characterized by dilatometry. The introduction of Co{sup 2+} does not lead to a change in the space group. All compounds show a transition of a low to a high temperature modification. The attributed temperature increases from 300 C for BaZn{sub 2}Si{sub 2}O{sub 7} to 850 C for BaCo{sub 2}Si{sub 2}O{sub 7}. The volume expansion which runs parallel to the phase transition decreases with increasing cobalt concentration. The phase BaZn{sub 2}Si{sub 2}O{sub 7} shows the largest CTE and a steep volume effect during phase transition. For the compound BaZn{sub 0.25}Co{sub 1.75}Si{sub 2}O{sub 7} the CTE is minimum (8.610{sup ?6} K{sup ?1} (50900 C)) and increases again until for the compound BaCo{sub 2}Si{sub 2}O{sub 7} a CTE of 16.610{sup ?6} K{sup ?1} (50900 C) is reached. In the cobalt rich composition range, the CTEs are in the right range for high temperature fuel cells and can be adjusted by the composition. - Graphical abstract: The composition of the solid solution BaZn{sub 2?x}Co{sub x}Si{sub 2}O{sub 7} strongly affects the thermal expansion. Display Omitted - Highlights: We examined the thermal expansion of solid solutions BaZn{sub 2?x}Co{sub x}Si{sub 2}O{sub 7} (0solid solutions should be suitable for solid oxide fuel cells.

Kerstan, Marita; Thieme, Christian; Grosch, Matthias; Mller, Matthias; Rssel, Christian, E-mail: ccr@rz.uni-jena.de

2013-11-15T23:59:59.000Z

Note: This page contains sample records for the topic "high-temperature solid oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

High temperature solid electrolyte fuel cell configurations and interconnections  

DOE Patents [OSTI]

High temperature fuel cell configurations and interconnections are made including annular cells having a solid electrolyte sandwiched between thin film electrodes. The cells are electrically interconnected along an elongated axial outer surface.

Isenberg, Arnold O. (Forest Hills, PA)

1984-01-01T23:59:59.000Z

22

High Temperature Oxidation Performance of Aluminide Coatings  

SciTech Connect (OSTI)

Aluminide coatings are of interest for many high temperature applications because of the possibility of improving the oxidation resistance of structural alloys by forming a protective external alumina scale. Steam and exhaust gas environments are of particular interest because alumina is less susceptible to the accelerated attack due to hydroxide formation observed for chromia- and silica-forming alloys and ceramics. For water vapor testing, one ferritic (Fe-9Cr-1Mo) and one austenitic alloy (304L) have been selected as substrate materials and CVD coatings have been used in order to have a well-controlled, high purity coating. It is anticipated that similar aluminide coatings could be made by a higher-volume, commercial process such as pack cementation. Previous work on this program has examined as-deposited coatings made by high and low Al activity CVD processes and the short-term performance of these coatings. The current work is focusing on the long term behavior in both diffusion tests16 and oxidation tests of the thicker, high Al activity coatings. For long-term coating durability, one area of concern has been the coefficient of thermal expansion (CTE) mismatch between coating and substrate. This difference could cause cracking or deformation that could reduce coating life. Corrosion testing using thermal cycling is of particular interest because of this potential problem and results are presented where a short exposure cycle (1h) severely degraded aluminide coatings on both types of substrates. To further study the potential role of aluminide coatings in fossil energy applications, several high creep strength Ni-base alloys were coated by CVD for testing in a high pressure (20atm) steam-CO{sub 2} environment for the ZEST (zero-emission steam turbine) program. Such alloys would be needed as structural and turbine materials in this concept. For Ni-base alloys, CVD produces a {approx}50{mu}m {beta}-NiAl outer layer with an underlying interdiffusion zone. Specimens of HR160, alloy 601 and alloy 230 were tested with and without coatings at 900 C and preliminary post-test characterization is reported.

Pint, Bruce A [ORNL; Zhang, Ying [Tennessee Technological University; Haynes, James A [ORNL; Wright, Ian G [ORNL

2004-01-01T23:59:59.000Z

23

Protective interlayer for high temperature solid electrolyte electrochemical cells  

DOE Patents [OSTI]

A high temperature, solid electrolyte electrochemical cell is made, having a first and second electrode with solid electrolyte between them, where the electrolyte is formed by hot chemical vapor deposition, where a solid, interlayer material, which is electrically conductive, oxygen permeable, and protective of electrode material from hot metal halide vapor attack, is placed between the first electrode and the electrolyte, to protect the first electrode from the hot metal halide vapors during vapor deposition.

Isenberg, Arnold O. (Forest Hills Boro, PA); Ruka, Roswell J. (Churchill Boro, PA)

1986-01-01T23:59:59.000Z

24

Protective interlayer for high temperature solid electrolyte electrochemical cells  

DOE Patents [OSTI]

A high temperature, solid electrolyte electrochemical cell is made, having a first and second electrode with solid electrolyte between them, where the electrolyte is formed by hot chemical vapor deposition, where a solid, interlayer material, which is electrically conductive, oxygen permeable, and protective of electrode material from hot metal halide vapor attack, is placed between the first electrode and the electrolyte, to protect the first electrode from the hot metal halide vapors during vapor deposition.

Isenberg, Arnold O. (Forest Hills Boro, PA); Ruka, Roswell J. (Churchill Boro, PA); Zymboly, Gregory E. (Penn Hills Township, Allegheny County, PA)

1985-01-01T23:59:59.000Z

25

Protective interlayer for high temperature solid electrolyte electrochemical cells  

DOE Patents [OSTI]

A high temperature, solid electrolyte electrochemical cell is made, having a first and second electrode with solid electrolyte between them, where the electrolyte is formed by hot chemical vapor deposition, where a solid, interlayer material, which is electrically conductive, oxygen permeable, and protective of electrode material from hot metal halide vapor attack, is placed between the first electrode and the electrolyte, to protect the first electrode from the hot metal halide vapors during vapor deposition.

Isenberg, Arnold O. (Forest Hills Boro, PA); Ruka, Roswell J. (Churchill Boro, PA)

1987-01-01T23:59:59.000Z

26

Dense high temperature ceramic oxide superconductors  

DOE Patents [OSTI]

Dense superconducting ceramic oxide articles of manufacture and methods for producing these articles are described. Generally these articles are produced by first processing these superconducting oxides by ceramic processing techniques to optimize materials properties, followed by reestablishing the superconducting state in a desired portion of the ceramic oxide composite.

Landingham, Richard L. (Livermore, CA)

1993-01-01T23:59:59.000Z

27

High Temperature Oxidation Resistance and Surface Electrical...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

plates with oxidation resistant coatings. Candidate coatings must exhibit chemical and thermal-mechanical stability and high electrical conductivity during long-term...

28

High Temperature Oxidation of Iron-Chromium Alloys  

E-Print Network [OSTI]

and Peter H. Larsen for many good discussions during the work. #12;3 Abstract The high temperature oxidation: References: Abstract (max. 2000 char.): See page 3 Information Service Department Risø National Laboratory P of Southern Denmark. The majority of the work is based on studies performed at the SOFC group at the Materials

29

Single crystal oxide and oxide/oxide eutectic fibres for high temperature composites  

Science Journals Connector (OSTI)

The utilisation of fibre-reinforced metal, intermetallic and ceramic matrix composites (CMCs) in gas turbine engines offers the potential of improved fuel efficiency, higher operating temperature and greater thrust to weight ratio. The development of ceramic fibres with high strength, excellent strength retention at elevated temperatures and good creep resistance is essential to the successful implementation of composites in various high temperature components. Several single crystal oxide and oxide/oxide eutectic fibres have been developed to meet the demanding performance requirements. Recent progress made on developing these fibers will be discussed.

J.-M. Yang

2001-01-01T23:59:59.000Z

30

Solid Oxide Fuel Cells  

Science Journals Connector (OSTI)

A Solid Oxide Fuel Cell (SOFC) is typically composed of two porous electrodes, interposed between an electrolyte made of a particular solid oxide ceramic material. The system originates from the work of Nernst...

Nigel M. Sammes; Roberto Bove; Jakub Pusz

2006-01-01T23:59:59.000Z

31

In situ reduction and oxidation of nickel from solid oxide fuel cells in a Titan ETEM  

E-Print Network [OSTI]

In situ reduction and oxidation of nickel from solid oxide fuel cells in a Titan ETEM A. Faes1. C. Singhal, K. Kendall, High Temperature Solid Oxide Fuel Cell - Fundamentals, Design, Denmark antonin.faes@epfl.ch Keywords: In situ ETEM, nickel oxide, reduction, RedOx, SOFC Solid Oxide Fuel

Dunin-Borkowski, Rafal E.

32

Numerical Simulation of Electrolyte-Supported Planar Button Solid Oxide Fuel Cell.  

E-Print Network [OSTI]

??Solid Oxide Fuel Cells are fuel cells that operate at high temperatures usually in the range of 600 C to 1000 C and employ solid (more)

Aman, Amjad

2012-01-01T23:59:59.000Z

33

A method for carbon oxide concentration evaluation in high-temperature combustion processes  

Science Journals Connector (OSTI)

A method for evaluating carbon oxide concentration in high-temperature combustion processes is presented. The paper offers an optimizing control problem for fuel combustion process using a stabilizing regulatory controller, which affects the fuel/air ...

K. E. Arystanbaev, A. T. Apsemetov

2014-04-01T23:59:59.000Z

34

A method for carbon oxide concentration evaluation in high-temperature combustion processes  

Science Journals Connector (OSTI)

A method for evaluating carbon oxide concentration in high-temperature combustion processes is presented. The paper offers an optimizing control problem for fuel combustion process using a stabilizing regulatory ...

K. E. Arystanbaev; A. T. Apsemetov

2014-04-01T23:59:59.000Z

35

Solid State Joining of High Temperature Alloy Tubes for USC and Heat-Exchanger Systems  

SciTech Connect (OSTI)

The principal objective of this project was to develop materials enabling joining technologies for use in forward looking heat-exchanger fabrication in Brayton cycle HIPPS, IGCC, FutureGen concepts capable of operating at temperatures in excess of 1000{degree}C as well as conventional technology upgrades via Ultra Super-Critical (USC) Rankine-cycle boilers capable of operating at 760{degree}C (1400F)/38.5MPa (5500psi) steam, while still using coal as the principal fossil fuel. The underlying mission in Rankine, Brayton or Brayton-Rankine, or IGCC combined cycle heat engine is a steady quest to improving operating efficiency while mitigating global environmental concerns. There has been a progressive move to higher overall cycle efficiencies, and in the case of fossil fuels this has accelerated recently in part because of concerns about greenhouse gas emissions, notably CO{sub 2}. For a heat engine, the overall efficiency is closely related to the difference between the highest temperature in the cycle and the lowest temperature. In most cases, efficiency gains are prompted by an increase in the high temperature, and this in turn has led to increasing demands on the materials of construction used in the high temperature end of the systems. Our migration to new advanced Ni-base and Oxide Dispersion Strengthened (ODS) alloys poses significant fabrication challenges, as these materials are not readily weldable or the weld performs poorly in the high temperature creep regime. Thus the joining challenge is two-fold to a) devise appropriate joining methodologies for similar/dissimilar Ni-base and ODS alloys while b) preserving the near baseline creep performance in the welded region. Our program focus is on solid state joining of similar and dissimilar metals/alloys for heat exchanger components currently under consideration for the USC, HIPPS and IGCC power systems. The emphasis is to manipulate the joining methods and variables available to optimize joint creep performance compared to the base material creep performance. Similar and dissimilar butt joints were fabricated of MA956, IN740 alloys and using inertia welding techniques. We evaluated joining process details and heat treatments and its overall effect on creep response. Fixed and incrementally accelerated temperature creep tests were performed for similar and dissimilar joints and such incremental creep life data is compiled and reported. Long term MA956-MA556 joint tests indicate a firm 2Ksi creep stress threshold performance at 850{degree}C with a maximum exposure of over 9725 hours recorded in the current program. A Larsen Miller Parameter (LMP) of 48.50 for a 2Ksi test at 850{degree}C was further corroborated with tests at 2Ksi stress at 900{degree}C yielding a LMP=48.80. Despite this threshold the joints exhibit immense temperature sensitivity and fail promptly when test temperature raised above 900{degree}C. In comparison the performance of dissimilar joints was inferior, perhaps dictated by the creep characteristics of the mating nickel-base alloys. We describe a parametric window of joint development, and post weld heat treatment (PWHT) in dissimilar joints with solid solution (IN601, IN617) and precipitate strengthened (IN740) materials. Some concerns are evident regarding the diffusion of aluminum in dissimilar joints during high temperature recrystallization treatments. It is noted that aggressive treatments rapidly deplete the corrosion protecting aluminum reservoir in the vicinity of the joint interface. Subsequently, the impact of varying PWHT has been evaluated in the context on ensuing creep performance.

Bimal Kad

2011-12-31T23:59:59.000Z

36

Production of Carbon from Carbon Dioxide with Iron Oxides and High-Temperature Solar Energy  

Science Journals Connector (OSTI)

Production of Carbon from Carbon Dioxide with Iron Oxides and High-Temperature Solar Energy ... 2 Since it is the major oxidation product from all hydrocarbon combustion processes, its presence permeates nearly every sector of the world economy. ... Thus, CO2 recycling and utilization seems to be a fundamental task from both an ecological and economical point of view. ...

K. Ehrensberger; R. Palumbo; C. Larson; A. Steinfeld

1997-03-03T23:59:59.000Z

37

"Ceramics and high-temperature composites, silicides" Oxidation of Stainless Steel Powder  

E-Print Network [OSTI]

: Powder, stainless steel, oxidation INTRODUCTION Ceramic matrix composites dispersed with metal particles"Ceramics and high-temperature composites, silicides" CHTC9 Oxidation of Stainless Steel Powder. To understand the corrosion behavior of a model 304L(p)-ZrO2(s) composite, a 304L stainless steel powder has

Paris-Sud XI, Université de

38

Oxidation of carbon fiber surfaces for use as reinforcement in high-temperature cementitious material systems  

DOE Patents [OSTI]

The interfacial bond characteristics between carbon fiber and a cement matrix, in high temperature fiber-reinforced cementitious composite systems, can be improved by the oxidative treatment of the fiber surfaces. Compositions and the process for producing the compositions are disclosed. 2 figs.

Sugama, Toshifumi.

1990-05-22T23:59:59.000Z

39

Oxidation of carbon fiber surfaces for use as reinforcement in high-temperature cementitious material systems  

DOE Patents [OSTI]

The interfacial bond characteristics between carbon fiber and a cement matrix, in high temperature fiber-reinforced cementitious composite systems, can be improved by the oxidative treatment of the fiber surfaces. Compositions and the process for producing the compositions are disclosed.

Sugama, Toshifumi (Mastic Beach, NY)

1990-01-01T23:59:59.000Z

40

SOLID OXIDE PLANAR AND TUBULAR SOLID OXIDE FUEL  

E-Print Network [OSTI]

SOLID OXIDE PLANAR AND TUBULAR SOLID OXIDE FUEL CELLS Dynamic Simulation Approach Modular Approach · Parallel planes: PSOFC · Other: combustor, reformer Solid Oxide Fuel Cell Electrochemistry Cell Reactions · Slow pressure transients #12;Fuel Cell Assumptions · H2 electrochemically oxidized only · CO consumed

Mease, Kenneth D.

Note: This page contains sample records for the topic "high-temperature solid oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

High temperature solid lubricant materials for heavy duty and advanced heat engines  

SciTech Connect (OSTI)

Advanced engine designs incorporate higher mechanical and thermal loading to achieve efficiency improvements. This approach often leads to higher operating temperatures of critical sliding elements (e.g. piston ring/cylinder wall contacts and valve guides) which compromise the use of conventional and even advanced synthetic liquid lubricants. For these applications solid lubricants must be considered. Several novel solid lubricant composites and coatings designated PS/PM200 have been employed to dry and marginally oil lubricated contacts in advanced heat engines. These applications include cylinder kits of heavy duty diesels, and high temperature sterling engines, sidewall seals of rotary engines and various exhaust valve and exhaust component applications. The following paper describes the tribological and thermophysical properties of these tribomaterials and reviews the results of applying them to engine applications. Other potential tribological materials and applications are also discussed with particular emphasis to heavy duty and advanced heat engines.

DellaCorte, C.; Wood, J.C.

1994-10-01T23:59:59.000Z

42

High Temperature Solid Oxide Fuel Cell Generator Development  

SciTech Connect (OSTI)

Work performed during the period February 21, 2006 through August 21, 2006 is summarized herein. During this period, efforts were focused on 5 kWe bundle testing, development of on-cell reformation, the conceptual design of an advanced module, and the development of a manufacturing roadmap for cells and bundles. A 5 kWe SOFC system was built and delivered to the Pennsylvania State University; fabrication of a second 5 kWe SOFC for delivery to Montana State University was initiated. Cell testing and microstructural analysis in support of these efforts was also conducted.

Joseph F. Pierre

2006-08-21T23:59:59.000Z

43

High Temperature Solid Oxide Fuel Cell Generator Development  

SciTech Connect (OSTI)

This report describes the results of the tubular SOFC development program from August 22, 1997 to September 30, 2007 under the Siemens/U.S. Department of Energy Cooperative Agreement. The technical areas discussed include cell manufacturing development, cell power enhancement, SOFC module and system cost reduction and technology advancement, and our field unit test program. Whereas significant progress has been made toward commercialization, significant effort remains to achieve our cost, performance and reliability targets for successful commercialization.

Joseph Pierre

2007-09-30T23:59:59.000Z

44

Mechanism of oxygen reduction reaction on transition metal oxide catalysts for high temperature fuel cells  

E-Print Network [OSTI]

The solid oxide fuel cell (SOFC) with its high energy conversion efficiency, low emissions, silent operation and its ability to utilize commercial fuels has the potential to create a large impact on the energy landscape. ...

La O', Gerardo Jose Cordova

2008-01-01T23:59:59.000Z

45

Solid Oxide Fuel Cell and PowerSolid Oxide Fuel Cell and Power S t D l t t PNNLS t D l t t PNNLSystem Development at PNNLSystem Development at PNNL  

E-Print Network [OSTI]

Solid Oxide Fuel Cell and PowerSolid Oxide Fuel Cell and Power S t D l t t PNNLS t D l;Solid Oxide Fuel Cell CharacteristicsSolid Oxide Fuel Cell Characteristics High temperature (~700 ­ 800 of SOFCDevelopment of SOFC TTechnologyechnology Fuel Reforming and System DesignFuel Reforming and System Design

46

High Temperature Thermal Stability and Oxidation Resistance of Magnetron-sputtered Homogeneous CrAlON Coatings on 430 Steel  

SciTech Connect (OSTI)

The requirements of low cost and high-temperature corrosion resistance for bipolar interconnect plates in solid oxide fuel cell stacks has directed attention to the use of metal plates with oxidation resistant coatings. We have investigated the performance of steel plates with homogenous coatings of CrAlON (oxynitrides). The coatings were deposited using RF magnetron sputtering, with Ar as a sputtering gas. Oxygen in these coatings was not intentionally added. Oxygen might have come through contaminated nitrogen gas bottle, leak in the chamber or from the partial pressure of water vapors. Nitrogen was added during the growth process to get oxynitride coating. The Cr/Al composition ratio in the coatings was varied in a combinatorial approach. The coatings were subsequently annealed in air for up to 25 hours at 800 deg. C. The composition of the coated plates and the rate of oxidation were characterized using Rutherford backscattering (RBS) and nuclear reaction analysis (NRA). From our results, we conclude that Al rich coatings are more susceptible to oxidation than Cr rich coatings.

Kayani, A.; Wickey, K. J.; Nandasiri, M. I.; Moore, A.; Garratt, E.; AlFaify, S.; Gao, X. [Western Michigan University-Kalamazoo, MI 49008 (United States); Smith, R. J.; Buchanan, T. L.; Priyantha, W.; Kopczyk, M.; Gannon, P. E. [Montana State University-Bozeman, MT 59717 (United States); Gorokhovsky, V. I. [Arcomac Surface Engineering, LLC-Bozeman, MT 59715 (United States)

2009-03-10T23:59:59.000Z

47

Methyl Chloride from Direct Methane Partial Oxidation: A High-Temperature Shilov-Like Catalytic System  

SciTech Connect (OSTI)

The intention of this study is to demonstrate and evaluate the scientific and economic feasibility of using special solvents to improve the thermal stability of Pt-catalyst in the Shilov system, such that a high reaction temperature could be achieved. The higher conversion rate (near 100%) of methyl chloride from partial oxidation of methane under the high temperature ({approx} 200 C) without significant Pt0 precipitation has been achieved. High concentration of the Cl- ion has been identified as the key for the stabilization of the Pt-catalysts. H/D exchange measurements indicated that the over oxidation will occur at the elevated temperature, developments of the effective product separation processes will be necessary in order to rationalize the industry-visible CH4 to CH3Cl conversion.

Yongchun Tang; John (Qisheng) Ma

2012-03-23T23:59:59.000Z

48

Solid oxide fuel cell with monolithic core  

DOE Patents [OSTI]

A solid oxide fuel cell in which fuel and oxidant gases undergo an electrochemical reaction to produce an electrical output includes a monolithic core comprised of a corrugated conductive sheet disposed between upper and lower generally flat sheets. The corrugated sheet includes a plurality of spaced, parallel, elongated slots which form a series of closed, linear, first upper and second lower gas flow channels with the upper and lower sheets within which a fuel gas and an oxidant gas respectively flow. Facing ends of the fuel cell are generally V-shaped and provide for fuel and oxidant gas inlet and outlet flow, respectively, and include inlet and outlet gas flow channels which are continuous with the aforementioned upper fuel gas and lower oxidant gas flow channels. The upper and lower flat sheets and the intermediate corrugated sheet are preferably comprised of ceramic materials and are securely coupled together such as by assembly in the green state and sintering together during firing at high temperatures. A potential difference across the fuel cell, or across a stacked array of similar fuel cells, is generated when an oxidant gas such as air and a fuel such as hydrogen gas is directed through the fuel cell at high temperatures, e.g., between 700 C and 1,100 C. 8 figs.

McPheeters, C.C.; Mrazek, F.C.

1988-08-02T23:59:59.000Z

49

Solid oxide fuel cell with monolithic core  

DOE Patents [OSTI]

A solid oxide fuel cell in which fuel and oxidant gases undergo an electrochemical reaction to produce an electrical output includes a monolithic core comprised of a corrugated conductive sheet disposed between upper and lower generally flat sheets. The corrugated sheet includes a plurality of spaced, parallel, elongated slots which form a series of closed, linear, first upper and second lower gas flow channels with the upper and lower sheets within which a fuel gas and an oxidant gas respectively flow. Facing ends of the fuel cell are generally V-shaped and provide for fuel and oxidant gas inlet and outlet flow, respectively, and include inlet and outlet gas flow channels which are continuous with the aforementioned upper fuel gas and lower oxidant gas flow channels. The upper and lower flat sheets and the intermediate corrugated sheet are preferably comprised of ceramic materials and are securely coupled together such as by assembly in the green state and sintering together during firing at high temperatures. A potential difference across the fuel cell, or across a stacked array of similar fuel cells, is generated when an oxidant gas such as air and a fuel such as hydrogen gas is directed through the fuel cell at high temperatures, e.g., between 700.degree. C. and 1100.degree. C.

McPheeters, Charles C. (Plainfield, IL); Mrazek, Franklin C. (Hickory Hills, IL)

1988-01-01T23:59:59.000Z

50

Nanostructured Solid Oxide Fuel Cell Electrodes  

E-Print Network [OSTI]

post-Doping of Solid Oxide Fuel Cell Cathodes,? P.h.D.and V. I. Birss, in Solid Oxide Fuel Cells (SOFC IX), S. C.Nanostructured Solid Oxide Fuel Cell Electrodes By Tal Zvi

Sholklapper, Tal Zvi

2007-01-01T23:59:59.000Z

51

Reaction of metal sulfates with molybdenum oxide, a high temperature reaction step for thermochemical cycles  

SciTech Connect (OSTI)

The reaction of sulfates with molybdenum oxide at high temperature was studied to determine the feasibility of using these reactions in a thermochemical process for making hydrogen. The experiments were performed by heating the blended powders to temperatures of 1075 K and higher and analyzing the evolved gas for acid content. It was found that the reaction rate over the first few minutes increased with both temperature and MoO/sub 3/. The fraction of sulfate reacting in the first 5 minutes varies with cation used. At 1125 K and for a molar ratio of sulfate ion/MoO/sub 3/ of 0.5, the fraction reacted was 0.29 for BaSO/sub 4/, 0.32 for CaSO/sub 4/ and 0.82 for La/sub 2/(SO/sub 4/)/sub 3/. These results are encouraging and indicate that an alternative means to sulfuric acid drying and decomposition is feasible using a mixed sulfate/oxide system to lower the effective decomposition temperature of the insoluble sulfate.

Hollabaugh, C.M.; Wallace, T.C.; Bowman, M.G.; Jones, W.M.

1980-01-01T23:59:59.000Z

52

Post-test analysis of electrode-supported solid oxide electrolyser cells  

Science Journals Connector (OSTI)

High temperature electrolysis (HTE) of steam is a very efficient power-to-gas process as long as waste heat is...1], the opposite direction of energy conversion than solid oxide fuel cells (SOFCs) do. In the last...

M. Al Daroukh; F. Tietz; D. Sebold; H. P. Buchkremer

2014-10-01T23:59:59.000Z

53

Architectures for individual and stacked micro single chamber solid oxide fuel cells  

E-Print Network [OSTI]

Solid oxide fuel cells (SOFCs) are electrochemical conversion devices that convert various fuel sources directly into electrical energy at temperatures ranging from 600C to 1000C. These high temperatures could potentially ...

Crumlin, Ethan J

2007-01-01T23:59:59.000Z

54

Fundamental studies of stress distributions and stress relaxation in oxide scales on high temperature alloys. [Final progress report  

SciTech Connect (OSTI)

This report summarizes a three-year study of stresses arising in the oxide scale and underlying metal during high temperature oxidation and of scale cracking. In-situ XRD was developed to measure strains during oxidation over 1000{degrees}C on pure metals. Acoustic emission was used to observe scale fracture during isothermal oxidation and cooling, and statistical analysis was used to infer mechanical aspects of cracking. A microscratch technique was used to measure the fracture toughness of scale/metal interface. A theoretical model was evaluated for the development and relaxation of stresses in scale and metal substrate during oxidation.

Shores, D.A.; Stout, J.H.; Gerberich, W.W.

1993-06-01T23:59:59.000Z

55

DOE Hydrogen Analysis Repository: High Temperature Electrolysis (HTE)  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

High Temperature Electrolysis (HTE) High Temperature Electrolysis (HTE) Project Summary Full Title: High Temperature Electrolysis (HTE) Project ID: 159 Principal Investigator: Steve Herring Brief Description: A three-dimensional computational fluid dynamics (CFD) model was created to model high-temperature steam electrolysis in a planar solid oxide electrolysis cell (SOEC). A solid-oxide fuel cell model adds the electrochemical reactions and loss mechanisms and computation of the electric field throughout the cell. Keywords: Solid oxide fuel cell; solid oxide elctrolysis cell; nuclear; model Purpose Assess the performance of solid-oxide cells operating in the steam electrolysis mode for hydrogen production over a temperature range of 800 to 900ºC. Performer Principal Investigator: Steve Herring

56

Carbon dioxide adsorbents containing magnesium oxide suitable for use at high temperatures  

DOE Patents [OSTI]

Adsorption of carbon dioxide from gas streams at temperatures in the range of 300 to 500.degree. C. is carried out with a solid adsorbent containing magnesium oxide, preferably promoted with an alkali metal carbonate or bicarbonate so that the atomic ratio of alkali metal to magnesium is in the range of 0.006 to 2.60. Preferred adsorbents are made from the precipitate formed on addition of alkali metal and carbonate ions to an aqueous solution of a magnesium salt. Atomic ratios of alkali metal to magnesium can be adjusted by washing the precipitate with water. Low surface area adsorbents can be made by dehydration and CO.sub.2 removal of magnesium hydroxycarbonate, with or without alkali metal promotion. The process is especially valuable in pressure swing adsorption operations.

Mayorga, Steven Gerard (Allentown, PA); Weigel, Scott Jeffrey (Allentown, PA); Gaffney, Thomas Richard (Allentown, PA); Brzozowski, Jeffrey Richard (Macungie, PA)

2001-01-01T23:59:59.000Z

57

Solid oxide electrochemical reactor science.  

SciTech Connect (OSTI)

Solid-oxide electrochemical cells are an exciting new technology. Development of solid-oxide cells (SOCs) has advanced considerable in recent years and continues to progress rapidly. This thesis studies several aspects of SOCs and contributes useful information to their continued development. This LDRD involved a collaboration between Sandia and the Colorado School of Mines (CSM) ins solid-oxide electrochemical reactors targeted at solid oxide electrolyzer cells (SOEC), which are the reverse of solid-oxide fuel cells (SOFC). SOECs complement Sandia's efforts in thermochemical production of alternative fuels. An SOEC technology would co-electrolyze carbon dioxide (CO{sub 2}) with steam at temperatures around 800 C to form synthesis gas (H{sub 2} and CO), which forms the building blocks for a petrochemical substitutes that can be used to power vehicles or in distributed energy platforms. The effort described here concentrates on research concerning catalytic chemistry, charge-transfer chemistry, and optimal cell-architecture. technical scope included computational modeling, materials development, and experimental evaluation. The project engaged the Colorado Fuel Cell Center at CSM through the support of a graduate student (Connor Moyer) at CSM and his advisors (Profs. Robert Kee and Neal Sullivan) in collaboration with Sandia.

Sullivan, Neal P. (Colorado School of Mines, Golden, CO); Stechel, Ellen Beth; Moyer, Connor J. (Colorado School of Mines, Golden, CO); Ambrosini, Andrea; Key, Robert J. (Colorado School of Mines, Golden, CO)

2010-09-01T23:59:59.000Z

58

REVERSIBLE SOLID OXIDE CELLS Mogens Mogensen1  

E-Print Network [OSTI]

The reversibility of solid oxide fuel cells (SOFC), i.e. that they could also work in the solid oxide electrolyser1 REVERSIBLE SOLID OXIDE CELLS Mogens Mogensen1 , Søren Højgaard Jensen1,2 , Anne Hauch1,3 , Ib Chorkendorff2 and Torben Jacobsen3 1 Fuel Cell and Solid State Chemistry Department Risø National Laboratory

59

Solid Oxide Electrolysis Cells Performance and Durability  

E-Print Network [OSTI]

Title: Solid Oxide Electrolysis Cells ­ Performance and Durability Department: Fuel Cells and SolidSolid Oxide Electrolysis Cells ­ Performance and Durability Anne Hauch Risø-PhD-37(EN) Risø : Images from transmission electron microscopy investigation of the H2 electrode for the solid oxide cell

60

A radiant flow reactor for high?temperature reactivity studies of pulverized solids  

Science Journals Connector (OSTI)

Our radiant two?phase flow reactor presents several new possibilities for high?temperature reactivity studies. Most importantly the thermal histories of the suspension and entrainment gas can be independently regulated over wide ranges. At low suspension loadings outlet temperatures can differ by hundreds of degrees and gas temperatures are low enough to inhibit hydrocarbon cracking chemistry so primary products are quenched as soon as they are expelled. With coal suspensions tars were generated with the highest H/C ratio and lowest proton aromaticity ever reported. Alternatively particles and gas can be heated at similar rates to promote secondary chemistry by increasing particle loading. Simply by regulating the furnace temperature arbitrary extents of conversion of coal tar into soot were observed for fixed total mass loss. Under both circumstances heat fluxes are comparable to those in large furnaces so relevant heating rates and reaction times are accessible. Suspensions remain optically thin even for the highest loadings of technological interest because they are only 1 cm wide. Consequently the macroscopic behavior remains firmly connected to single?particle phenomena. Mass and elemental closures are rarely breached by more than 5% in individual runs so interpretations are not subject to inordinate scatter in the data. The reactor is also well suited for combustion studies as demonstrated by extents of carbon and nitrogen burnout from 50% to 100% for various gas?stream oxygen levels.

John C. Chen; Stephen Niksa

1992-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "high-temperature solid oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Solid oxide fuel cell generator  

DOE Patents [OSTI]

A solid oxide fuel cell generator has a plenum containing at least two rows of spaced apart, annular, axially elongated fuel cells. An electrical conductor extending between adjacent rows of fuel cells connects the fuel cells of one row in parallel with each other and in series with the fuel cells of the adjacent row. 5 figures.

Di Croce, A.M.; Draper, R.

1993-11-02T23:59:59.000Z

62

Use of high-temperature gas-tight electrochemical cells to measure electronic transport and thermodynamics in metal oxides  

SciTech Connect (OSTI)

By using a gas-tight electrochemical cell, the authors can perform high-temperature coulometric titration and measure electronic transport properties to determine the electronic defect structure of metal oxides. This technique reduces the time and expense required for conventional thermogravimetric measurements. The components of the gas-tight coulometric titration cell are an oxygen sensor, Pt/yttria stabilized zirconia (YSZ)/Pt, and an encapsulated metal oxide sample. Based on cell design, both transport and thermodynamic measurements can be performed over a wide range of oxygen partial pressures (pO{sub 2} = 10{sup {minus}35} to 1 atm). This paper describes the high-temperature gas-tight electrochemical cells used to determine electronic defect structures and transport properties for pure and doped-oxide systems, such as YSZ, doped and pure ceria (Ca-CeO{sub 2} and CeO{sub 2}), copper oxides, and copper-oxide-based ceramic superconductors, transition metal oxides, SrFeCo{sub 0.5}O{sub x}, and BaTiO{sub 3}.

Park, J.H.; Ma, B.; Park, E.T. [Argonne National Lab., IL (United States). Energy Technology Div.

1997-10-01T23:59:59.000Z

63

High temperature thermoelectric characterization of III-V semiconductor thin films by oxide bonding  

E-Print Network [OSTI]

energy conversion, and other high temperature applications.[1-5] Since the efficiency of those energy conversion applications relies heavily on the carrier transport properties of the materials used, it is very by Molecular Beam Epitaxy (MBE) has demonstrated its usefulness in thermoelectric energy conversion

Bowers, John

64

High-Temperature Thermoelectric Characterization of IIIV Semiconductor Thin Films by Oxide Bonding  

E-Print Network [OSTI]

energy conversion, and other high-temperature applications.1­4 Since the efficiency of these energy conversion applications relies heavily on the carrier transport properties of the materials used, it is very by molecular beam epitaxy (MBE) has demonstrated its useful- ness in thermoelectric energy conversion

65

Fabrication of solid oxide fuel cell by electrochemical vapor deposition  

DOE Patents [OSTI]

In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (approximately 1100.degree.-1300.degree. C.) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20-50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

Brian, Riley (Willimantic, CT); Szreders, Bernard E. (Oakdale, CT)

1989-01-01T23:59:59.000Z

66

Fabrication of solid oxide fuel cell by electrochemical vapor deposition  

DOE Patents [OSTI]

In a high temperature solid oxide fuel cell (SOFC), the deposition of an impervious high density thin layer of electrically conductive interconnector material, such as magnesium doped lanthanum chromite, and of an electrolyte material, such as yttria stabilized zirconia, onto a porous support/air electrode substrate surface is carried out at high temperatures (/approximately/1100/degree/ /minus/ 1300/degree/C) by a process of electrochemical vapor deposition. In this process, the mixed chlorides of the specific metals involved react in the gaseous state with water vapor resulting in the deposit of an impervious thin oxide layer on the support tube/air electrode substrate of between 20--50 microns in thickness. An internal heater, such as a heat pipe, is placed within the support tube/air electrode substrate and induces a uniform temperature profile therein so as to afford precise and uniform oxide deposition kinetics in an arrangement which is particularly adapted for large scale, commercial fabrication of SOFCs.

Riley, B.; Szreders, B.E.

1988-04-26T23:59:59.000Z

67

Solid oxide fuel cell generator  

DOE Patents [OSTI]

A solid oxide fuel cell generator has a pair of spaced apart tubesheets in a housing. At least two intermediate barrier walls are between the tubesheets and define a generator chamber between two intermediate buffer chambers. An array of fuel cells have tubes with open ends engaging the tubesheets. Tubular, axially elongated electrochemical cells are supported on the tubes in the generator chamber. Fuel gas and oxidant gas are preheated in the intermediate chambers by the gases flowing on the other side of the tubes. Gas leakage around the tubes through the tubesheets is permitted. The buffer chambers reentrain the leaked fuel gas for reintroduction to the generator chamber.

Draper, Robert (Churchill Boro, PA); George, Raymond A. (Pittsburgh, PA); Shockling, Larry A. (Plum Borough, PA)

1993-01-01T23:59:59.000Z

68

A High Temperature Electrochemical Energy Storage System Based on Sodium Beta-Alumina Solid Electrolyte (Base)  

SciTech Connect (OSTI)

This report summarizes the work done during the period September 1, 2005 and March 31, 2008. Work was conducted in the following areas: (1) Fabrication of sodium beta{double_prime} alumina solid electrolyte (BASE) using a vapor phase process. (2) Mechanistic studies on the conversion of {alpha}-alumina + zirconia into beta{double_prime}-alumina + zirconia by the vapor phase process. (3) Characterization of BASE by X-ray diffraction, SEM, and conductivity measurements. (4) Design, construction and electrochemical testing of a symmetric cell containing BASE as the electrolyte and NaCl + ZnCl{sub 2} as the electrodes. (5) Design, construction, and electrochemical evaluation of Na/BASE/ZnCl{sub 2} electrochemical cells. (6) Stability studies in ZnCl{sub 2}, SnCl{sub 2}, and SnI{sub 4} (7) Design, assembly and testing of planar stacks. (8) Investigation of the effect of porous surface layers on BASE on cell resistance. The conventional process for the fabrication of sodium ion conducting beta{double_prime}-alumina involves calcination of {alpha}-alumina + Na{sub 2}CO{sub 3} + LiNO{sub 3} at 1250 C, followed by sintering powder compacts in sealed containers (platinum or MgO) at {approx}1600 C. The novel vapor phase process involves first sintering a mixture of {alpha}-alumina + yttria-stabilized zirconia (YSZ) into a dense ceramic followed by exposure to soda vapor at {approx}1450 C to convert {alpha}-alumina into beta{double_prime}-alumina. The vapor phase process leads to a high strength BASE, which is also resistant to moisture attack, unlike BASE made by the conventional process. The PI is the lead inventor of the process. Discs and tubes of BASE were fabricated in the present work. In the conventional process, sintering of BASE is accomplished by a transient liquid phase mechanism wherein the liquid phase contains NaAlO{sub 2}. Some NaAlO{sub 2} continues to remain at grain boundaries; and is the root cause of its water sensitivity. In the vapor phase process, NaAlO{sub 2} is never formed. Conversion occurs by a coupled transport of Na{sup +} through BASE formed and of O{sup 2-} through YSZ to the reaction front. Transport to the reaction front is described in terms of a chemical diffusion coefficient of Na{sub 2}O. The conversion kinetics as a function of microstructure is under investigation. The mechanism of conversion is described in this report. A number of discs and tubes of BASE have been fabricated by the vapor phase process. The material was investigated by X-ray diffraction (XRD), optical microscopy and scanning electron microscopy (SEM), before and after conversion. Conductivity (which is almost exclusively due to sodium ion transport at the temperatures of interest) was measured. Conductivity was measured using sodium-sodium tests as well as by impedance spectroscopy. Various types of both planar and tubular electrochemical cells were assembled and tested. In some cases the objective was to determine if there was any interaction between the salt and BASE. The interaction of interest was mainly ion exchange (possible replacement of sodium ion by the salt cation). It was noted that Zn{sup 2+} did not replace Na+ over the conditions of interest. For this reason much of the work was conducted with ZnCl{sub 2} as the cathode salt. In the case of Sn-based, Sn{sup 2+} did ion exchange, but Sn{sup 4+} did not. This suggests that Sn{sup 4+} salts are viable candidates. These results and implications are discussed in the report. Cells made with Na as the anode and ZnCl{sub 2} as the cathode were successfully charged/discharged numerous times. The key advantages of the batteries under investigation here over the Na-S batteries are: (1) Steel wool can be used in the cathode compartment unlike Na-S batteries which require expensive graphite. (2) Planar cells can be constructed in addition to tubular, allowing for greater design flexibility and integration with other devices such as planar SOFC. (3) Comparable or higher open circuit voltage (OCV) than the Na-S battery. (4) Wider operating temperature range and higher temper

Anil Virkar

2008-03-31T23:59:59.000Z

69

The oxidation of aluminum at high temperature studied by Thermogravimetric Analysis and Differential Scanning Calorimetry.  

SciTech Connect (OSTI)

The oxidation in air of high-purity Al foil was studied as a function of temperature using Thermogravimetric Analysis with Differential Scanning Calorimetry (TGA/DSC). The rate and/or extent of oxidation was found to be a non-linear function of the temperature. Between 650 and 750 %C2%B0C very little oxidation took place; at 850 %C2%B0C oxidation occurred after an induction period, while at 950 %C2%B0C oxidation occurred without an induction period. At oxidation temperatures between 1050 and 1150 %C2%B0C rapid passivation of the surface of the aluminum foil occurred, while at 1250 %C2%B0C and above, an initial rapid mass increase was observed, followed by a more gradual increase in mass. The initial rapid increase was accompanied by a significant exotherm. Cross-sections of oxidized specimens were characterized by scanning electron microscopy (SEM); the observed alumina skin thicknesses correlated qualitatively with the observed mass increases.

Coker, Eric Nicholas

2013-10-01T23:59:59.000Z

70

ReaxFF Reactive Force Field for Solid Oxide Fuel Cell Systems with Application to Oxygen Ion Transport in Yttria-Stabilized Zirconia  

E-Print Network [OSTI]

ReaxFF Reactive Force Field for Solid Oxide Fuel Cell Systems with Application to Oxygen Ion through yttria-stabilized zirconia (YSZ) solid oxide fuel cell (SOFC) membranes. All parameters for Reax temperature, leading to applications as oxygen sensors and as membranes for high temperature solid oxide fuel

Goddard III, William A.

71

High-temperature oxidation of an alumina-coated Ni-base alloy  

SciTech Connect (OSTI)

Alumina coatings were applied to Ni-20Cr (wt%) using combustion chemical vapor deposition (combustion CVD). Combustion CVD is an open air deposition technique performed in a flame. The oxidation kinetics of coated and uncoated specimens were measured by isothermal oxidation tests carried out in pure flowing air at temperatures of 800, 900, 1,000 and 1,100 C. The alumina coatings reduced the oxidation kinetics at all temperatures. The morphologies and compositions of the alumina coatings were characterized by transmission and scanning electron microscopy, energy dispersive x-ray spectroscopy and x-ray photoelectron spectroscopy.

Hendrick, M.R.; Hampikian, J.M.; Carter, W.B.

1996-06-01T23:59:59.000Z

72

Fundamental studies of heterostructured oxide thin film electrocatalysts for oxygen reduction at high temperatures  

E-Print Network [OSTI]

Searching for active and cost-effective catalysts for oxygen electrocatalysis is essential for the development of efficient clean electrochemical energy technologies. Perovskite oxides are active for surface oxygen exchange ...

Crumlin, Ethan J

2012-01-01T23:59:59.000Z

73

Hydrogen Ingress in Steels During High-Temperature Oxidation in Water Vapor  

SciTech Connect (OSTI)

It is well established that hydrogen derived from water vapour can penetrate oxidizing alloys with detrimental effect. However, the complexities of tracking hydrogen in these materials have prevented the direct profiling of hydrogen ingress needed to understand these phenomena. Here we report hydrogen profiles in industrially-relevant alumina- and chromia- forming steels correlated with the local oxide-metal nano/microstructure by use of SIMS D2O tracer studies and experimental protocols to optimize D retention. The D profiles unexpectedly varied markedly among the alloys examined, which indicates mechanistic complexity but also the potential to mitigate detrimental water vapour effects by manipulation of alloy chemistry.

Brady, Michael P [ORNL; Fayek, Mostafa [ORNL; Keiser, James R [ORNL; Meyer III, Harry M [ORNL; More, Karren Leslie [ORNL; Anovitz, Lawrence {Larry} M [ORNL; Wesolowski, David J [ORNL; Cole, David R [ORNL

2011-01-01T23:59:59.000Z

74

High emissivity coatings on titanium alloy prepared by micro-arc oxidation for high temperature application  

Science Journals Connector (OSTI)

Micro-arc oxidation coatings were prepared on Ti6Al4V alloy in...3PO4-based electrolyte with different additives such as FeSO4, Co(CH3COO)2, Ni(CH3COO)2, and K2ZrF6. The composition, structure, surface morphology...

H. Tang; Q. Sun; C. G. Yi; Z. H. Jiang; F. P. Wang

2012-03-01T23:59:59.000Z

75

Mid-infrared response of reduced graphene oxide and its high-temperature coefficient of resistance  

SciTech Connect (OSTI)

Much effort has been made to study the formation mechanisms of photocurrents in graphene and reduced graphene oxide films under visible and near-infrared light irradiation. A built-in field and photo-thermal electrons have been applied to explain the experiments. However, much less attention has been paid to clarifying the mid-infrared response of reduced graphene oxide films at room temperature. Thus, mid-infrared photoresponse and annealing temperature-dependent resistance experiments were carried out on reduced graphene oxide films. A maximum photocurrent of 75 ?A was observed at room temperature, which was dominated by the bolometer effect, where the resistance of the films decreased as the temperature increased after they had absorbed light. The electrons localized in the defect states and the residual oxygen groups were thermally excited into the conduction band, forming a photocurrent. In addition, a temperature increase of 2 C for the films after light irradiation for 2 minutes was observed using absorption power calculations. This work details a way to use reduced graphene oxide films that contain appropriate defects and residual oxygen groups as bolometer-sensitive materials in the mid-infrared range.

Liang, Haifeng, E-mail: hfliang2004@gmail.com [Key Laboratory of Optical Measurement and Thin Film of Shaanxi Province, Xian Technological University, Xian 710032 (China)

2014-10-15T23:59:59.000Z

76

Solid-oxide fuel cell electrolyte  

DOE Patents [OSTI]

A solid-oxide electrolyte operable at between 600.degree. C. and 800.degree. C. and a method of producing the solid-oxide electrolyte are provided. The solid-oxide electrolyte comprises a combination of a compound having weak metal-oxygen interactions with a compound having stronger metal-oxygen interactions whereby the resulting combination has both strong and weak metal-oxygen interaction properties.

Bloom, Ira D. (Bolingbrook, IL); Hash, Mark C. (Joliet, IL); Krumpelt, Michael (Naperville, IL)

1993-01-01T23:59:59.000Z

77

NETL: Solid Oxide Fuel Cells Publications  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Solid Oxide Fuel Cells Publications Operating Principles AEC Development Atmospheric Pressure Systems Pressurized Systems Program Plan Project Portfolio Project Information Systems...

78

Microstructure and High Temperature Oxidation Behavior of Cr-W Alloys  

SciTech Connect (OSTI)

Cr alloys containing 0-30%W by weight were investigated for use in elevated temperature applications. The alloys were melted in a water-cooled, copper-hearth arc furnace. Microstructure of the alloys was characterized using x-ray diffraction, scanning electron microscopy, and light microscopy. A pseudocyclic oxidation test was employed to study scale formation at 1000C in dry air. The scale was predominantly chromia and spalled upon cooling. Alloying with aluminum up to 8 weight percent reduced the spalling drastically. Furthermore, aluminizing the surface of the Cr-W alloys completely stopped the spalling.

Dogan, O.N.

2007-02-01T23:59:59.000Z

79

Durability Evaluation of Reversible Solid Oxide Cells  

SciTech Connect (OSTI)

An experimental investigation on the performance and durability of single solid oxide cells (SOCs) is under way at the Idaho National Laboratory. Reversible operation of SOCs includes electricity generation in the fuel cell mode and hydrogen generation in the electrolysis mode. Degradation is a more significant issue when operating SOCs in the electrolysis mode. In order to understand and mitigate the degradation issues in high temperature electrolysis, single SOCs with different configurations from several manufacturers have been evaluated for initial performance and long-term durability. A new test apparatus for single cell and small stack tests has been developed for this purpose. Cells were obtained from four industrial partners. Cells from Ceramatec Inc. and Materials and Systems Research Inc. (MSRI) showed improved durability in electrolysis mode compared to previous stack tests. Cells from Saint Gobain Advanced Materials Inc. (St. Gobain) and SOFCPower Inc. demonstrated stable performance in the fuel cell mode, but rapid degradation in the electrolysis mode, especially at high current density. Electrolyte-electrode delamination was found to have a significant impact on degradation in some cases. Enhanced bonding between electrolyte and electrode and modification of the electrode microstructure helped to mitigate degradation. Polarization scans and AC impedance measurements were performed during the tests to characterize cell performance and degradation.

Xiaoyu Zhang; James E. O'Brien; Robert C. O'Brien; Gregory K. Housley

2013-11-01T23:59:59.000Z

80

High-temperature corrosion of metallic alloys in an oxidizing atmosphere containing NaCl  

SciTech Connect (OSTI)

A particular heat-exchanger application involved metallic alloys exposed to flue gases of an aluminum remelt furnace. Because the flue gases might contain NaCl and other halides, the corrosion behavior of the alloys was to be investigated. Planned direct exposure of candidate alloys to the flue gases, however, was not conducted because of premature termination of the project. Complementary laboratory testing was conducted on seven commercially available alloys and two nickel aluminides. These materials were exposed to an oxidizing atmosphere containing 0.06 wt % NaCl for 1100 h at 1000/degree/C. Most of the alloy exhibited grain-boundary attack, which resulted in complete oxidation of enveloped grains. The alloys Incoloy MA-956, Incoloy 800, Inconel 625, Inconel 601, Hastelloy X, Haynes 188, and nickel aluminide IC-50 were substantially more corroded than Alloy 214 and nickel aluminide IC-221. The latter two alloys, therefore, would probably be superior to the others in application involving flue gases containing NaCl. Strength fabricability, and weldability, which are briefly discussed, would also affect selection of materials. 8 refs., 12 figs., 5 tabs.

Federer, J.I.

1989-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "high-temperature solid oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Oxidation and Volatilization from Tungsten Brush High Heat Flux Armor During High Temperature Steam Exposure  

SciTech Connect (OSTI)

Tungsten brush accommodates thermal stresses and high heat flux in fusion reactor components such as plasma facing surfaces or armor. However, inherently higher surface areas are introduced with the brush design. We have tested a specific design of tungsten brush in steam between 500 and 1100C. Hydrogen generation and tungsten volatilization rates were determined to address fusion safety issues. The brush prepared from 3.2-mm diameter welding rods had a packing density of 85 percent. We found that both hydrogen generation and tungsten volatilization from brush, fixtured to represent a unit within a larger component, were less than projections based upon the total integrated surface area (TSA). Steam access and the escape of hydrogen and volatile oxide from void spaces within the brush are restricted compared to specimens with more direct diffusion pathways to the test environment. Hydrogen generation rates from restrained specimens based on normal surface area (NSA) remain about five times higher than rates based on total surface areas from specimens with direct steam access. Volatilization rates from restrained specimens based upon normal surface area (NSA) were only 50 percent higher than our historic cumulative maximum flux plot (CMFP) for tungsten. This study has shown that hydrogen generation and tungsten volatilization from brush do not scale according to predictions with previously determined rates, but in fact, with higher packing density could approach those from flat surfaces.

Smolik, Galen Richard; Pawelko, Robert James; Anderl, Robert Andrew; Petti, David Andrew

2000-05-01T23:59:59.000Z

82

Electrical contact structures for solid oxide electrolyte fuel cell  

DOE Patents [OSTI]

An improved electrical output connection means is provided for a high temperature solid oxide electrolyte type fuel cell generator. The electrical connection of the fuel cell electrodes to the electrical output bus, which is brought through the generator housing to be connected to an electrical load line maintains a highly uniform temperature distribution. The electrical connection means includes an electrode bus which is spaced parallel to the output bus with a plurality of symmetrically spaced transversely extending conductors extending between the electrode bus and the output bus, with thermal insulation means provided about the transverse conductors between the spaced apart buses. Single or plural stages of the insulated transversely extending conductors can be provided within the high temperatures regions of the fuel cell generator to provide highly homogeneous temperature distribution over the contacting surfaces.

Isenberg, Arnold O. (Forest Hills, PA)

1984-01-01T23:59:59.000Z

83

High-temperature desulfurization of gasifier effluents with rare earth and rare earth/transition metal oxides  

SciTech Connect (OSTI)

We have improved the application of mixed rare-earth oxides (REOs) as hot gas desulfurization adsorbents by impregnating them on stable high surface area supports and by the inclusion of certain transition metal oxides. We report comparative desulfurization experiments at high temperature (900 K) using a synthetic biomass gasifier effluent containing 0.1 vol % H{sub 2}S, along with H{sub 2}, CO{sub 2}, and water. More complex REO sorbents outperform the simpler CeO{sub 2}/La{sub 2}O{sub 3} mixtures, in some cases significantly. Supporting REOs on Al{sub 2}O{sub 3} (?20 wt % REO) or ZrO{sub 2} actually increased the sulfur capacities found after several cycles on a total weight basis. Another major increase in sulfur capacity took place when MnO{sub x} or FeO{sub x} is incorporated. Apparently most of the Mn or Fe is dispersed on or near the surface of the mixed REOs because the capacities with REOs greatly exceeded those of Al{sub 2}O{sub 3}-supported MnO{sub x} or FeO{sub x} alone at these conditions. In contrast, incorporating Cu has little effect on sulfur adsorption capacities. Both the REO and transition metal/REO adsorbents could be regenerated completely using air for at least five repetitive cycles.

Dooley, Kerry M.; Kalakota, Vikram; Adusumilli, Sumana

2011-01-01T23:59:59.000Z

84

Robust control strategies for hybrid solid oxide fuel cell systems.  

E-Print Network [OSTI]

??Solid Oxide Fuel Cell (SOFC) systems are electrochemical energy conversion devices characterized by the use of solid oxide as the electrolyte. They operate at high (more)

Mathew, Anju Ann

2010-01-01T23:59:59.000Z

85

Solid Oxide Membrane (SOM) Electrolysis of Magnesium: Scale-Up...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Solid Oxide Membrane (SOM) Electrolysis of Magnesium: Scale-Up Research and Engineering for Light-Weight Vehicles Solid Oxide Membrane (SOM) Electrolysis of Magnesium: Scale-Up...

86

Interactions of nickel/zirconia solid oxide fuel cell anodes...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Interactions of nickelzirconia solid oxide fuel cell anodes with coal gas containing arsenic. Interactions of nickelzirconia solid oxide fuel cell anodes with coal gas containing...

87

Low Temperature Constrained Sintering of Cerium Gadolinium Oxide Films for Solid Oxide Fuel Cell Applications  

E-Print Network [OSTI]

Temperature Solid Oxide Fuel Cells, In: S.C. Singhal and M.solidoxide.html, Tubular Solid Oxide Fuel Cell Technology,Oxide Films for Solid Oxide Fuel Cell Applications by Jason

Nicholas, Jason.D.

2007-01-01T23:59:59.000Z

88

The development and operational testing of an experimental reactor for gas-liquid-solid reaction systems at high temperatures and pressures  

E-Print Network [OSTI]

shaft. With the impeller in place and rotating, gas was drawn into the top port and ejected at the impeller mount. The reactor pressure was monitored via the transducer port. The transducer was a Viatran Pressure Transducer, model 103. The liquid...THE DEVELOPMENT AND OPERATIONAL TESTING OF AN EXPERIMENTAL REACTOR FOR GAS-LIQUID-SOLID REACTION SYSTEMS AT HIGH TEMPERATURES AND PRESSURES A Thesis by RICHARD KENNETH HESS Submitted to the Graduate College of Texas A&M University in partial...

Hess, Richard Kenneth

2012-06-07T23:59:59.000Z

89

Metallic Materials in Solid Oxide Fuel Cells  

Science Journals Connector (OSTI)

Fe-Cr alloys with variations in chromium content and additions of different elements were studied for potential application in intermediate temperature Solid Oxide Fuel Cell (SOFC). Recently, a new type of FeC...

V. Shemet; J. Piron-Abellan; W.J. Quadakkers

2005-01-01T23:59:59.000Z

90

Modeling of solid oxide fuel cells  

E-Print Network [OSTI]

A comprehensive membrane-electrode assembly (MEA) model of Solid Oxide Fuel Cell (SOFC)s is developed to investigate the effect of various design and operating conditions on the cell performance and to examine the underlying ...

Lee, Won Yong, S.M. Massachusetts Institute of Technology

2006-01-01T23:59:59.000Z

91

Interfacial material for solid oxide fuel cell  

DOE Patents [OSTI]

Solid oxide fuel cells having improved low-temperature operation are disclosed. In one embodiment, an interfacial layer of terbia-stabilized zirconia is located between the air electrode and electrolyte of the solid oxide fuel cell. The interfacial layer provides a barrier which controls interaction between the air electrode and electrolyte. The interfacial layer also reduces polarization loss through the reduction of the air electrode/electrolyte interfacial electrical resistance. In another embodiment, the solid oxide fuel cell comprises a scandia-stabilized zirconia electrolyte having high electrical conductivity. The scandia-stabilized zirconia electrolyte may be provided as a very thin layer in order to reduce resistance. The scandia-stabilized electrolyte is preferably used in combination with the terbia-stabilized interfacial layer. The solid oxide fuel cells are operable over wider temperature ranges and wider temperature gradients in comparison with conventional fuel cells.

Baozhen, Li (Essex Junction, VT); Ruka, Roswell J. (Pittsburgh, PA); Singhal, Subhash C. (Murrysville, PA)

1999-01-01T23:59:59.000Z

92

High Temperature Superconductors  

Science Journals Connector (OSTI)

Abstract A brief review of the phenomenology of superconductivity, the distinction between type I and type II superconductors, and the application of type II superconductors is followed by a history of the theory of conventional superconductivity. Unconventional high-temperature superconductivity in the copper oxides is reviewed as a phenomenon occurring in narrow two-dimensional bands where the time for an electron transfer between like atoms is comparable to the period of an optical-mode lattice vibration. A family of iron pnictides containing layers of iron atoms may not require an alternative explanation of its high-temperature superconductivity.

J.B. Goodenough

2013-01-01T23:59:59.000Z

93

Integrating catalytic coal gasifiers with solid oxide fuel cells  

SciTech Connect (OSTI)

A review was conducted for coal gasification technologies that integrate with solid oxide fuel cells (SOFC) to achieve system efficiencies near 60% while capturing and sequestering >90% of the carbon dioxide [1-2]. The overall system efficiency can reach 60% when a) the coal gasifier produces a syngas with a methane composition of roughly 25% on a dry volume basis, b) the carbon dioxide is separated from the methane-rich synthesis gas, c) the methane-rich syngas is sent to a SOFC, and d) the off-gases from the SOFC are recycled back to coal gasifier. The thermodynamics of this process will be reviewed and compared to conventional processes in order to highlight where available work (i.e. exergy) is lost in entrained-flow, high-temperature gasification, and where exergy is lost in hydrogen oxidation within the SOFC. The main advantage of steam gasification of coal to methane and carbon dioxide is that the amount of exergy consumed in the gasifier is small compared to conventional, high temperature, oxygen-blown gasifiers. However, the goal of limiting the amount of exergy destruction in the gasifier has the effect of limiting the rates of chemical reactions. Thus, one of the main advantages of steam gasification leads to one of its main problems: slow reaction kinetics. While conventional entrained-flow, high-temperature gasifiers consume a sizable portion of the available work in the coal oxidation, the consumed exergy speeds up the rates of reactions. And while the rates of steam gasification reactions can be increased through the use of catalysts, only a few catalysts can meet cost requirements because there is often significant deactivation due to chemical reactions between the inorganic species in the coal and the catalyst. Previous research into increasing the kinetics of steam gasification will be reviewed. The goal of this paper is to highlight both the challenges and advantages of integrating catalytic coal gasifiers with SOFCs.

Siefert, N.; Shamsi, A.; Shekhawat, D.; Berry, D.

2010-01-01T23:59:59.000Z

94

Effect of Substrate Thickness on Oxide Scale Spallation for Solid Oxide Fuel Cells  

SciTech Connect (OSTI)

In this paper, the effect of the ferritic substrate's thickness on the delamination/spallation of the oxide scale was investigated experimentally and numerically. At the high-temperature oxidation environment of solid oxide fuel cells (SOFCs), a combination of growth stress with thermal stresses may lead to scale delamination/buckling and eventual spallation during SOFC stack cooling, even leading to serious degradation of cell performance. The growth stress is induced by the growth of the oxide scale on the scale/substrate interface, and thermal stress is induced by a mismatch of the coefficient of thermal expansion between the oxide scale and the substrate. The numerical results show that the interfacial shear stresses, which are the driving force of scale delamination between the oxide scale and the ferritic substrate, increase with the growth of the oxide scale and also with the thickness of the ferritic substrate; i.e., the thick ferritic substrate can easily lead to scale delamination and spallation. Experimental observation confirmed the predicted results of the delamination and spallation of the oxide scale on the ferritic substrate.

Liu, Wenning N.; Sun, Xin; Stephens, Elizabeth V.; Khaleel, Mohammad A.

2011-07-01T23:59:59.000Z

95

Biogas fuel reforming for solid oxide fuel cells  

Science Journals Connector (OSTI)

In this paper strategies for biogas reforming and their ensuing effects on solid oxide fuel cell(SOFC) performance are explored. Synthesized biogas (65% CH4?+?35% CO2) fuel streams are reformed over a rhodium catalyst supported on a porous ?-alumina foam. Reforming approaches include steam reforming and catalytic partial oxidation (CPOX) utilizing either air or pure oxygen as the oxidant. A computational model is developed and utilized to guide the specification of reforming conditions that maximize both CH4 and CO2 conversions. Model predictions are validated with experimental measurements over a wide range of biogas-reforming conditions. Higher reforming temperatures are shown to activate the biogas-borne CO2 to enable significant methane dry-reforming chemistry. Dry reforming minimizes the oxidant-addition needs for effective biogas conversion potentially decreasing the thermal requirements for reactant heating and improving system efficiency. Such high-temperature reforming conditions are prevalent during CPOX with a pure-O2 oxidant. While CPOX-with-O2 reforming is highly exothermic the endothermicity of dry-reforming chemistry can be exploited to ensure that catalyst temperatures do not reach levels which cause catalyst sintering and degradation. SOFCelectrochemical performance under biogas reformate is shown to vary substantially with reforming approach. Cell operation under CPOX-with-O2 reformate is found to be comparable to that under humidified hydrogen.

Danielle M. Murphy; Amy E. Richards; Andrew Colclasure; Wade A. Rosensteel; Neal P. Sullivan

2012-01-01T23:59:59.000Z

96

TECHNOLOGY DATA FOR HIGH TEMPERATURE SOLID OXIDE ELECTROLYSER CELLS, ALKALI AND PEM ELECTROLYSERS  

E-Print Network [OSTI]

. Introduction One of the challenges in a future 100 % sustainable energy system is how to realise sustainable the integration of electrolysers in energy systems in combination with other power plants. Values Mathiesen Iva Ridjan David Connolly Department of Energy Technology Mads Pagh Nielsen Technical University

Nielsen, Mads Pagh

97

High temperature water electrolysis using metal supported solid oxide electrolyser cells (SOEC)  

Science Journals Connector (OSTI)

The use of renewable energy has attained increasing interest over the past years. For a wider utilisation of renewable energy sources such as wind, photovoltaic, solar thermal power and others chemical energy car...

G. Schiller; A. Ansar; M. Lang; O. Patz

2009-02-01T23:59:59.000Z

98

High Temperatures & Electricity Demand  

E-Print Network [OSTI]

High Temperatures & Electricity Demand An Assessment of Supply Adequacy in California Trends.......................................................................................................1 HIGH TEMPERATURES AND ELECTRICITY DEMAND.....................................................................................................................7 SECTION I: HIGH TEMPERATURES AND ELECTRICITY DEMAND ..........................9 BACKGROUND

99

Solid Oxide Fuel Cells | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Solid Oxide Fuel Cells Solid Oxide Fuel Cells Solid Oxide Fuel Cells FE researchers at NETL have developed a unique test platform, called the multi-cell array (MCA), to rapidly test multiple fuel cells and determine how they degrade when contaminants exist in the fuel stream, such as might occur when using syngas from a coal gasifier. FE researchers at NETL have developed a unique test platform, called the multi-cell array (MCA), to rapidly test multiple fuel cells and determine how they degrade when contaminants exist in the fuel stream, such as might occur when using syngas from a coal gasifier. Fuel cells are an energy user's dream: an efficient, combustion-less, virtually pollution-free power source, capable of being sited in downtown urban areas or in remote regions that runs almost silently and has few

100

P0301-Mogensen Performance of Reversible Solid Oxide Cells  

E-Print Network [OSTI]

that solid oxide fuel cells (SOFC) could also work in the solid oxide electrolyser cell (SOEC) mode1 P0301-Mogensen Performance of Reversible Solid Oxide Cells: A Review Mogens Mogensen1 , Søren Højgaard Jensen1,2 , Anne Hauch1,3 , Ib Chorkendorff2 and Torben Jacobsen3 1 Fuel Cell and Solid State

Note: This page contains sample records for the topic "high-temperature solid oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Compatibility of refractory metal boride/oxide composites at ultra-high temperatures. Final report, Sep 87-Mar 90  

SciTech Connect (OSTI)

The compatibility of the HfO2/HfSi2/HfB2 phases has been investigated in an argon atmosphere at 1800 deg, 1700 deg and 1600 deg C. At the three temperatures investigated, HfB 2 was determined to be relatively inert to either the oxide or silicide phases when examined with the scanning electron microscope and optical microscope. At 1800 deg C, a reactive product was found between the hafnia and hafnium dislicide phases with a wavy interface moving, parabolically with respect to time. The microstructural analysis of the interface suggests that liquid contributes to the interfacial reactions. In addition, two-solid phases (Hf 2 Si and HfSi) were formed at temperature along with silicide and silicate liquids located between HfSi2 and HfO2. At 1600 deg C for annealing times from 4 to 50 hours, the HfSi 2 /HfO 2 interface does not react as inferred from the acquired constant thickness of the silicide layer.

Bronson, A.; Ma, Y.T.; Mutso, R.R.

1990-12-01T23:59:59.000Z

102

Effect of Coal Gas Contaminants on Solid Oxide Fuel Cell Operation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Coal Gas Contaminants on Solid Oxide Fuel Cell Operation. Effect of Coal Gas Contaminants on Solid Oxide Fuel Cell Operation. Abstract: The operation of solid oxide fuel cells...

103

Formation of thin walled ceramic solid oxide fuel cells  

DOE Patents [OSTI]

To reduce thermal stress and improve bonding in a high temperature monolithic solid oxide fuel cell (SOFC), intermediate layers are provided between the SOFC's electrodes and electrolyte which are of different compositions. The intermediate layers are comprised of a blend of some of the materials used in the electrode and electrolyte compositions. Particle size is controlled to reduce problems involving differential shrinkage rates of the various layers when the entire structure is fired at a single temperature, while pore formers are provided in the electrolyte layers to be removed during firing for the formation of desired pores in the electrode layers. Each layer includes a binder in the form of a thermosetting acrylic which during initial processing is cured to provide a self-supporting structure with the ceramic components in the green state. A self-supporting corrugated structure is thus formed prior to firing, which the organic components of the binder and plasticizer removed during firing to provide a high strength, high temperature resistant ceramic structure of low weight and density.

Claar, Terry D. (Tisle, IL); Busch, Donald E. (Hinsdale, IL); Picciolo, John J. (Lockport, IL)

1989-01-01T23:59:59.000Z

104

Effects of Ce, Y and Mo Addition on the Stress Accelerated Oxidation of Austenitic Stainless Steel in Oxygenated High Temperature Water  

SciTech Connect (OSTI)

Based upon the recent progress in mechanistic understanding of intergranular stress corrosion cracking (IGSCC) of austenitic stainless steels in high temperature water in light water reactor (LWR), the effects of Ce, Y, and Mo addition on oxidation kinetics under a tensile stress condition was investigated. Minor impurity of P was also studied. A kind of circumferentially notched tensile specimen was prepared to simulate the crack tip stress field. The notched specimens of different materials studied were applied with an almost constant load in simulated boiling water reactor (BWR) water. The oxidation was examined by the specimen cross section. It was shown that these elements have quite clear effects on the metal oxidation and alloying element distribution in the oxide layer. (authors)

Shengchun Wang; Nobuaki Kawaguchi; Tetsuo Shoji [Fracture Research Institute, Graduate School of Engineering, Tohoku University, Aramaki Aoba 01, Aoba-ku, Sendai 980-8579 (Japan)

2004-07-01T23:59:59.000Z

105

National Energy Technology Laboratory Publishes Solid Oxide Fuel Cell  

Broader source: Energy.gov (indexed) [DOE]

National Energy Technology Laboratory Publishes Solid Oxide Fuel National Energy Technology Laboratory Publishes Solid Oxide Fuel Cell Studies National Energy Technology Laboratory Publishes Solid Oxide Fuel Cell Studies July 23, 2013 - 1:07pm Addthis National Energy Technology Laboratory Publishes Solid Oxide Fuel Cell Studies What does this project do? For more information on DOE's efforts to make solid oxide fuel cells an efficient and economically compelling option, please visit: The NETL Solid Oxide Fuel Cells Program Webpage Solid oxide fuel cells are among the cleanest, most efficient power-generating technologies now being developed. They provide excellent electrical efficiencies and are capable of operating on a wide variety of fuels, from coal and natural gas to landfill waste and hydrogen. And with continued advancements, solid oxide fuel cells can provide clean

106

Reversible Poisoning of the Nickel/Zirconia Solid Oxide Fuel...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Poisoning of the NickelZirconia Solid Oxide Fuel Cell Anodes by Hydrogen Chloride in Coal Gas. Reversible Poisoning of the NickelZirconia Solid Oxide Fuel Cell Anodes by Hydrogen...

107

Breakout Group 5: Solid Oxide Fuel Cells | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Breakout Group 5: Solid Oxide Fuel Cells Breakout Group 5: Solid Oxide Fuel Cells Report from Breakout Group 5 of the Fuel Cell Pre-Solicitation Workshop, January 23-24, 2008...

108

Electron-Phonon Coupling in High-Temperature Cuprate Superconductors as Revealed by Angle-resolved Photoemisson Spectroscopy  

E-Print Network [OSTI]

Cuprate oxide high-temperature superconductors are dopedsuperconductivity. High temperature superconductors arein understanding high-temperature superconductors, such as

Zhou, X.J.; Hussain, Z.; Shen, Z.-X.

2005-01-01T23:59:59.000Z

109

A high-pressure and high-temperature gas-loading system for the study of conventional to real industrial sized samples in catalysed gas/solid and liquid/solid reactions  

Science Journals Connector (OSTI)

A high-pressure-high-temperature gas-loading system has been developed for combined in situ high-energy X-ray diffraction and mass spectrometry investigations during catalysed gas/solid or liquid/solid reactions. The benefits of such a system are the combination of different gases, the flexibility of the cell design, the rotation of the cell, and the temperature, pressure and gas-flow ranges accessible. This opens up new opportunities for studying catalysts or compounds not just from a fundamental point of view but also for industrial applications, in both cases in operando conditions.

Andrieux, J.

2014-01-18T23:59:59.000Z

110

High-temperature series expansions to fourth order with a multiple-exchange Hamiltonian for both bcc and hcp phases of solid He3  

Science Journals Connector (OSTI)

The high-temperature series expansions with a multiple-exchange Hamiltonian including the most important two, three, and four-particle exchange processes for the bcc and hcp phases of solid He3 are calculated up to fourth order in ?=1/kBT, with arbitrary magnetic field. The series for the susceptibility are derived and compared to the experimental results. For bcc He3 an excellent agreement is obtained with the third- and fourth-order Pad approximants, using the phenomenological parameters formerly published. For hcp He3, we show that the Curie-Weiss temperature ? has been underestimated for the largest molar volumes and propose more accurate fits in better agreement with earlier nuclear-magnetic-resonance estimates.

M. Roger; E. Suaudeau; M. E. R. Bernier

1987-02-01T23:59:59.000Z

111

COMPUTATIONAL FLUID DYNAMICS MODELING OF SOLID OXIDE FUEL CELLS  

E-Print Network [OSTI]

COMPUTATIONAL FLUID DYNAMICS MODELING OF SOLID OXIDE FUEL CELLS Ugur Pasaogullari and Chao-dimensional model has been developed to simulate solid oxide fuel cells (SOFC). The model fully couples current density operation. INTRODUCTION Solid oxide fuel cells (SOFC) are among possible candidates

112

A New Instrument For Characterizing Solid Oxide Fuel Cell Catalysts  

E-Print Network [OSTI]

RESEARCH HIGHLIGHTS A New Instrument For Characterizing Solid Oxide Fuel Cell Catalysts From fuels to renewable energy sources. Solid oxide fuel cells (SOFCs) have enormous potential in this area A New Instrument For Characterizing Solid Oxide Fuel Cell Catalysts Rob Usiskin In partnership

113

Nitric oxide emissions from the high-temperature viscous boundary layers of hypersonic aircraft within the stratosphere  

SciTech Connect (OSTI)

The authors study the nitric oxide emission characteristics of supersonic aircraft resulting from heating of viscous boundary layers along the skin of the aircraft. Previous study has concentrated on nitric oxide emissions coming from combustion products from the scramjet engines. This work shows that above mach 8, emissions from viscous heating become a significant factor in total emission of nitric oxide. Above mach 16 it becomes the dominant source of emission.

Brooks, S.B.; Lewis, M.J.; Dickerson, R.R. [Univ. of Maryland, College Park, MD (United States)

1993-09-20T23:59:59.000Z

114

Sintered electrode for solid oxide fuel cells  

DOE Patents [OSTI]

A solid oxide fuel cell fuel electrode is produced by a sintering process. An underlayer is applied to the electrolyte of a solid oxide fuel cell in the form of a slurry, which is then dried. An overlayer is applied to the underlayer and then dried. The dried underlayer and overlayer are then sintered to form a fuel electrode. Both the underlayer and the overlayer comprise a combination of electrode metal such as nickel, and stabilized zirconia such as yttria-stabilized zirconia, with the overlayer comprising a greater percentage of electrode metal. The use of more stabilized zirconia in the underlayer provides good adhesion to the electrolyte of the fuel cell, while the use of more electrode metal in the overlayer provides good electrical conductivity. The sintered fuel electrode is less expensive to produce compared with conventional electrodes made by electrochemical vapor deposition processes. The sintered electrodes exhibit favorable performance characteristics, including good porosity, adhesion, electrical conductivity and freedom from degradation.

Ruka, Roswell J. (Pittsburgh, PA); Warner, Kathryn A. (Bryan, TX)

1999-01-01T23:59:59.000Z

115

Generator configuration for solid oxide fuel cells  

DOE Patents [OSTI]

Disclosed are improvements in a solid oxide fuel cell generator 1 having a multiplicity of electrically connected solid oxide fuel cells 2, where a fuel gas is passed over one side of said cells and an oxygen-containing gas is passed over the other side of said cells resulting in the generation of heat and electricity. The improvements comprise arranging the cells in the configuration of a circle, a spiral, or folded rows within a cylindrical generator, and modifying the flow rate, oxygen concentration, and/or temperature of the oxygen-containing gases that flow to those cells that are at the periphery of the generator relative to those cells that are at the center of the generator. In these ways, a more uniform temperature is obtained throughout the generator.

Reichner, Philip (Plum Boro, PA)

1989-01-01T23:59:59.000Z

116

Synthesis and Stability of a Nanoparticle-Infiltrated Solid Oxide Fuel Cell Electrode  

E-Print Network [OSTI]

Nanoparticle-Infiltrated Solid Oxide Fuel Cell Electrode Talinfiltrated into SOFC (Solid Oxide Fuel Cell) electrodes can

Sholklapper, Tal Z.; Radmilovic, Velimir; Jacobson, Craig P.; Visco, Steven J.; De Jonghe, Lutgard C.

2006-01-01T23:59:59.000Z

117

Computer Simulation and Experimental Validation on the Oxidation and Sulfate Corrosion Resistance of Novel Chromium-Based High-temperature Alloys  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Computer Simulation and Experimental Computer Simulation and Experimental Validation on the Oxidation and Sulfate Corrosion Resistance of Novel Chromium-Based High-temperature Alloys Background Advanced coal power generation is a critical component of the U.S. energy portfolio. The U.S. Department of Energy (DOE) is committed to supporting research that will increase the efficiency and decrease the environmental impact of coal-fired plants, thus enabling the long term use of a low cost domestic fuel source. One key factor to

118

Wear Behavior of Plasma-Sprayed Carbon Nanotube-Reinforced Aluminum Oxide Coating in Marine and High-Temperature Environments  

Science Journals Connector (OSTI)

Plasma-sprayed aluminum oxide (Al2O3) coatings offer excellent wear resistance, corrosion resistance, heat, and thermal...1-6...). These coatings have to operate under severe conditions, such as high load, high s...

Anup Kumar Keshri; Arvind Agarwal

2011-12-01T23:59:59.000Z

119

Thermodynamics and Transport Phenomena in High Temperature Steam Electrolysis Cells  

SciTech Connect (OSTI)

Hydrogen can be produced from water splitting with relatively high efficiency using high temperature electrolysis. This technology makes use of solid-oxide cells, running in the electrolysis mode to produce hydrogen from steam, while consuming electricity and high temperature process heat. The overall thermal-to-hydrogen efficiency for high temperature electrolysis can be as high as 50%, which is about double the overall efficiency of conventional low-temperature electrolysis. Current large-scale hydrogen production is based almost exclusively on steam reforming of methane, a method that consumes a precious fossil fuel while emitting carbon dioxide to the atmosphere. An overview of high temperature electrolysis technology will be presented, including basic thermodynamics, experimental methods, heat and mass transfer phenomena, and computational fluid dynamics modeling.

James E. O'Brien

2012-03-01T23:59:59.000Z

120

High Temperature Oxidation Behavior of gamma-Ni+gamma'-Ni3Al Alloys and Coatings Modified with Pt and Reactive Elements  

SciTech Connect (OSTI)

Materials for high-pressure turbine blades must be able to operate in the high-temperature gases (above 1000 C) emerging from the combustion chamber. Accordingly, the development of nickel-based superalloys has been constantly motivated by the need to have improved engine efficiency, reliability and service lifetime under the harsh conditions imposed by the turbine environment. However, the melting point of nickel (1455 C) provides a natural ceiling for the temperature capability of nickel-based superalloys. Thus, surface-engineered turbine components with modified diffusion coatings and overlay coatings are used. Theses coatings are capable of forming a compact and adherent oxide scale, which greatly impedes the further transport of reactants between the high-temperature gases and the underlying metal and thus reducing attack by the atmosphere. Typically, these coatings contain {beta}-NiAl as a principal constituent phase in order to have sufficient aluminum content to form an Al{sub 2}O{sub 3} scale at elevated temperatures. The drawbacks to the currently-used {beta}-based coatings, such as phase instabilities, associated stresses induced by such phase instabilities, and extensive coating/substrate interdiffusion, are major motivations in this study to seek next-generation coatings. The high-temperature oxidation resistance of novel Pt + Hf-modified {gamma}-Ni + {gamma}-Ni{sub 3}Al-based alloys and coatings were investigated in this study. Both early-stage and 4-days isothermal oxidation behavior of single-phase {gamma}-Ni and {gamma}{prime}-Ni{sub 3}Al alloys were assessed by examining the weight changes, oxide-scale structures, and elemental concentration profiles through the scales and subsurface alloy regions. It was found that Pt promotes Al{sub 2}O{sub 3} formation by suppressing the NiO growth on both {gamma}-Ni and {gamma}{prime}Ni{sub 3}Al single-phase alloys. This effect increases with increasing Pt content. Moreover, Pt exhibits this effect even at lower temperatures ({approx}970 C) in the very early stage of oxidation. It was also inferred that Pt enhances the diffusive flux of aluminum from the substrate to the scale/alloy interface. Relatively low levels of hafnium addition to Pt-free {gamma}{prime}-Ni{sub 3}Al increased the extent of external NiO formation due to non-protective HfO{sub 2} formation. Accordingly, this effect intensified with increasing Hf content from 0.2 to 0.5 at.%.

Nan Mu

2007-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "high-temperature solid oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Mechanical Engineering Manufacturing Solid Oxide Fuel Cells for Improved Electro-  

E-Print Network [OSTI]

Uday Pal Mechanical Engineering Manufacturing Solid Oxide Fuel Cells for Improved Electro- chemical for the commercialization of solid oxide fuel cells (SOFCs) are its high manufacturing and material costs expressed in terms at 800oC with humidified hydrogen (3% H2O) as the fuel and air as the oxidant. The cells were also tested

Lin, Xi

122

Tubular solid oxide fuel cell current collector  

DOE Patents [OSTI]

An internal current collector for use inside a tubular solid oxide fuel cell (TSOFC) electrode comprises a tubular coil spring disposed concentrically within a TSOFC electrode and in firm uniform tangential electrical contact with the electrode inner surface. The current collector maximizes the contact area between the current collector and the electrode. The current collector is made of a metal that is electrically conductive and able to survive under the operational conditions of the fuel cell, i.e., the cathode in air, and the anode in fuel such as hydrogen, CO, CO.sub.2, H.sub.2O or H.sub.2S.

Bischoff, Brian L. (Knoxville, TN); Sutton, Theodore G. (Kingston, TN); Armstrong, Timothy R. (Clinton, TN)

2010-07-20T23:59:59.000Z

123

High-temperature stability, structure and thermoelectric properties of CaMn1xNbxO3 phases  

E-Print Network [OSTI]

technologies such as solid oxide fuel cells, thermoelectric (TE) modules and high-temperature superconductorsHigh-temperature stability, structure and thermoelectric properties of CaMn1?xNbxO3 phases Laura diffraction and electron diffraction data. Thermogravi- metric heating/cooling studies showed a reversible

124

Solid oxide fuel cell having monolithic core  

DOE Patents [OSTI]

A solid oxide fuel cell is described for electrochemically combining fuel and oxidant for generating galvanic output, wherein the cell core has an array of electrolyte and interconnect walls that are substantially devoid of any composite inert materials for support. Instead, the core is monolithic, where each electrolyte wall consists of thin layers of cathode and anode materials sandwiching a thin layer of electrolyte material therebetween. The electrolyte walls are arranged and backfolded between adjacent interconnect walls operable to define a plurality of core passageways alternately arranged where the inside faces thereof have only the anode material or only the cathode material exposed. Means direct the fuel to the anode-exposed core passageways and means direct the oxidant to the anode-exposed core passageways and means direct the oxidant to the cathode-exposed core passageway; and means also direct the galvanic output to an exterior circuit. Each layer of the electrolyte and interconnect materials is of the order of 0.002 to 0.01 cm thick; and each layer of the cathode and anode materials is of the order of 0.002 to 0.05 cm thick.

Ackerman, J.P.; Young, J.E.

1983-10-12T23:59:59.000Z

125

Oxidation studies of CrAlON nanolayered coatings on steel plates...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

cost and high-temperature corrosion resistance for bipolar interconnect plates in solid oxide fuel cell stacks have directed attention to the use of metal plates with oxidation...

126

High-temperature X-ray diffraction study of crystallization and phase segregation on spinel-type lithium manganese oxides  

SciTech Connect (OSTI)

To study crystallization process of spinel-type Li{sub 1+x}Mn{sub 2-x}O{sub 4}, in-situ high-temperature X-ray diffraction technique (HT-XRD) was utilized for the mixture consisting of Li{sub 2}CO{sub 3} and Mn{sub 2}O{sub 3} as starting material in the temperature range of 25-700 deg. C. In-situ HT-XRD analysis directly revealed that crystallization process of Li{sub 1+x}Mn{sub 2-x}O{sub 4} was significantly affected by the difference in the Li/Mn molar ratio in the precursor. Single phase of stoichiometric LiMn{sub 2}O{sub 4} formed at 700 deg. C. The formation of single phase of spinel was achieved at the lower temperature than the stoichiometric sample as Li/Mn molar ratio in the precursor increased. Lattice parameter of the stoichiometric LiMn{sub 2}O{sub 4} at 25 deg. C was 8.24 A and expanded to 8.31 A at 700 deg. C, which corresponds to the approximately 3% expansion in the unit cell volume. From the slope of the lattice parameter change as a function of temperatures, linear thermal expansion coefficient of the stoichiometric LiMn{sub 2}O{sub 4} was calculated to be 1.2x10{sup -5} deg. C{sup -1} in this temperature range. When the Li/Mn molar ratio in Li{sub 1+x}Mn{sub 2-x}O{sub 4} increased (x > 0.1), the spinel phase segregated into the Li{sub 1+y}Mn{sub 2-y}O{sub 4} (x > y) and Li{sub 2}MnO{sub 3} during heating, which involved the oxygen loss from the materials. During the cooling process from 700 deg. C, and the segregated phase merged into Li{sub 1+x}Mn{sub 2-x}O{sub 4} with oxygen incorporation. Such trend directly observed by in-situ HT-XRD was supported by thermal gravimetric analysis as reversible weight (oxygen) loss/gain at higher temperature (500-700 deg. C). - Graphical abstract: Non-linear variation of lattice parameters of the Li excess LiMn{sub 2}O{sub 4} spinels was observed during cooling process from 700 to 25 deg. C.

Komaba, Shinichi, E-mail: komaba@rs.kagu.tus.ac.j [Department of Applied Chemistry, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku, Tokyo 162-8601 (Japan); Yabuuchi, Naoaki; Ikemoto, Sachi [Department of Applied Chemistry, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku, Tokyo 162-8601 (Japan)

2010-01-15T23:59:59.000Z

127

Sintered electrode for solid oxide fuel cells  

DOE Patents [OSTI]

A solid oxide fuel cell fuel electrode is produced by a sintering process. An underlayer is applied to the electrolyte of a solid oxide fuel cell in the form of a slurry, which is then dried. An overlayer is applied to the underlayer and then dried. The dried underlayer and overlayer are then sintered to form a fuel electrode. Both the underlayer and the overlayer comprise a combination of electrode metal such as nickel, and stabilized zirconia such as yttria-stabilized zirconia, with the overlayer comprising a greater percentage of electrode metal. The use of more stabilized zirconia in the underlayer provides good adhesion to the electrolyte of the fuel cell, while the use of more electrode metal in the overlayer provides good electrical conductivity. The sintered fuel electrode is less expensive to produce compared with conventional electrodes made by electrochemical vapor deposition processes. The sintered electrodes exhibit favorable performance characteristics, including good porosity, adhesion, electrical conductivity and freedom from degradation. 4 figs.

Ruka, R.J.; Warner, K.A.

1999-06-01T23:59:59.000Z

128

Corrosion behavior of an HVOF-sprayed Fe3Al coating in a high-temperature oxidizing/sulfidizing environment  

SciTech Connect (OSTI)

An iron aluminide (Fe3Al) intermetallic coating was deposited onto a F22 (2.25Cr-1Mo) steel substrate using a JP-5000 high velocity oxy-fuel (HVOF) thermal spray system. The as-sprayed coating was examined by electron microscopy and X-ray diffraction and was characterized in terms of oxidation and adhesion. Fe3Al-coated steel specimens were exposed to a mixed oxidizing/sulfidizing environment at 500, 600, 700, and 800DGC for approximately seven days. The gaseous environment consisted of N2-10%CO-5%CO2-2%H2O-0.12%H2S (by volume). All specimens gained mass after exposure to the environment and the mass gains were found to be inversely proportional to temperature increases. Representative specimens exposed at each temperature were cross-sectioned and subjected to examination under a scanning electron microscope (SEM) and X-ray mapping. Results are presented in terms of corrosion weight gain and corrosion product formation. The purpose of the research presented here was to evaluate the effectiveness of an HVOF-sprayed Fe3Al coating in protecting a steel substrate exposed to a fossil energy environment.

Covino, Bernard S., Jr.; Bullard, Sophie J.; Cramer, Stephen D.; Holcomb, Gordon R.; Ziomek-Moroz, Margaret; Shrestha, S. (TWI Ltd.); Harvey, D. (TWI Ltd.)

2005-01-01T23:59:59.000Z

129

One dimensional modeling of planar solid oxide fuel cell.  

E-Print Network [OSTI]

??Using modeling and simulation, the present work offers parametric study for Planar Solid Oxide Fuel Cell (PSOFC) as a function of fuel gas composition. The (more)

Ghosh, Ujjal

2005-01-01T23:59:59.000Z

130

Mathematical Analysis of Planar Solid Oxide Fuel Cells.  

E-Print Network [OSTI]

??The mathematical analysis has been developed by using finite volume method, experimental data from literatures, and solving numerically to predict solid oxide fuel cell performances (more)

Pramuanjaroenkij, Anchasa

2009-01-01T23:59:59.000Z

131

Development of Solid Oxide Fuel Cells Utilizing Alternative Fuels.  

E-Print Network [OSTI]

??This dissertation is a summary of four solid oxide fuel cell (SOFC) research projects which addressed a number of SOFC technologies to use alternative fuels (more)

Labarbera, Mark

2012-01-01T23:59:59.000Z

132

Ageing of integrated-planar solid Oxide Fuel Cells.  

E-Print Network [OSTI]

??The ageing of Solid Oxide Fuel Cells (SOFCs) is a key problem because of the requirement of 50,000 hours to their lifetime in many applications. (more)

Almutairi, Ghzzai

2013-01-01T23:59:59.000Z

133

FY 2014 Solid Oxide Fuel Cell Project Selections | Department...  

Office of Environmental Management (EM)

Effects and Degradation in Solid Oxide Fuel Cells: Understanding Transport and Thermodynamics." The goals of this project are to: 1) understand the detailed mechanisms of...

134

SULFUR-TOLERANT CATALYST FOR THE SOLID OXIDE FUEL CELL.  

E-Print Network [OSTI]

??JP-8 fuel is easily accessible, transportable, and has hydrogen content essential to solid oxide fuel cell (SOFC) operation. However, this syngas has sulfur content which (more)

Bozeman, Joe Frank, III

2010-01-01T23:59:59.000Z

135

Development of efficiency-enhanced cogeneration system utilizing high-temperature exhaust-gas from a regenerative thermal oxidizer for waste volatile-organic-compound gases  

Science Journals Connector (OSTI)

We have developed a gas-turbine cogeneration system that makes effective use of the calorific value of the volatile organic compound (VOC) gases exhausted during production processes at a manufacturing plant. The system utilizes the high-temperature exhaust-gas from the regenerative thermal oxidizer (RTO) which is used for incinerating VOC gases. The high-temperature exhaust gas is employed to resuperheat the steam injected into the gasturbine. The steam-injection temperature raised in this way increases the heat input, resulting in the improved efficiency of the gas-turbine. Based on the actual operation of the system, we obtained the following results: Operation with the steam-injection temperature at 300C (45C resuperheated from 255C) increased the efficiency of the gasturbine by 0.7%. The system can enhance the efficiency by 1.3% when the steam-injection temperature is elevated to 340C (85C resuperheated). In this case, up to 6.6 million yen of the total energy cost and 400 tons of carbon dioxide (CO2) emissions can be reduced annually. A gas-turbine cogeneration and RTO system can reduce energy consumption by 23% and CO2 emission by 30.1% at the plant.

Masaaki Bannai; Akira Houkabe; Masahiko Furukawa; Takao Kashiwagi; Atsushi Akisawa; Takuya Yoshida; Hiroyuki Yamada

2006-01-01T23:59:59.000Z

136

Solid Oxide Fuel Cell System Utilizing Syngas from Coal Gasifiers  

Science Journals Connector (OSTI)

Solid Oxide Fuel Cell System Utilizing Syngas from Coal Gasifiers ... The oxidizer is expected to be similar in design to a HRSG duct firing burner (at the inlet of a HRSG). ...

Hossein Ghezel-Ayagh; Stephen Jolly; Dilip Patel; David Stauffer

2013-01-10T23:59:59.000Z

137

Reactive magnetron sputtering of hard Si-B-C-N films with a high-temperature oxidation resistance  

SciTech Connect (OSTI)

Based on the results obtained for C-N and Si-C-N films, a systematic investigation of reactive magnetron sputtering of hard quaternary Si-B-C-N materials has been carried out. The Si-B-C-N films were deposited on p-type Si(100) substrates by dc magnetron co-sputtering using a single C-Si-B target (at a fixed 20% boron fraction in the target erosion area) in nitrogen-argon gas mixtures. Elemental compositions of the films, their surface bonding structure and mechanical properties, together with their oxidation resistance in air, were controlled by the Si fraction (5-75%) in the magnetron target erosion area, the Ar fraction (0-75%) in the gas mixture, the rf induced negative substrate bias voltage (from a floating potential to -500 V) and the substrate temperature (180-350 deg. C). The total pressure and the discharge current on the magnetron target were held constant at 0.5 Pa and 1 A, respectively. The energy and flux of ions bombarding the growing films were determined on the basis of the discharge characteristics measured for the rf discharge dominating in the deposition zone. Mass spectroscopy was used to show composition of the total ion fluxes onto the substrate and to explain differences between sputtering of carbon, silicon and boron from a composed target in nitrogen-argon discharges. The films, typically 1.0-2.4 {mu}m thick, possessing a density around 2.4 g cm{sup -3}, were found to be amorphous in nanostructure with a very smooth surface (R{sub a}{<=}0.8 nm) and good adhesion to substrates at a low compressive stress (1.0-1.6 GPa). They exhibited high hardness (up to 47 GPa) and elastic recovery (up to 88%), and extremely high oxidation resistance in air at elevated temperatures (up to a 1350 deg.C substrate limit)

Vlcek, Jaroslav; Potocky, Stepan; Cizek, Jiri; Houska, Jiri; Kormunda, Martin; Zeman, Petr; Perina, Vratislav; Zemek, Josef; Setsuhara, Yuichi; Konuma, Seiji [Department of Physics, University of West Bohemia, Univerzitni 22, 306 14 Plzen (Czech Republic); Nuclear Physics Institute, Academy of Sciences of the Czech Republic, 250 68 Rez near Prague (Czech Republic); Institute of Physics, Academy of Sciences of the Czech Republic, Cukrovarnicka 10, 162 53 Prague 6 (Czech Republic); Joining and Welding Research Institute, Osaka University, 11-1 Mihogaoka, Ibaraki, Osaka 567-0047 (Japan); Kanagawa High-Technology Foundation, Kanagawa Science Park, 3-2-1 Sakado, Takatsu-ku, Kawasaki, Kanagawa 213-0012 (Japan)

2005-11-15T23:59:59.000Z

138

Mechanism-Based Testing Methodology for Improving the Oxidation, Hot Corrosion and Impact Resistance of High-Temperature Coatings for Advanced Gas Turbines  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Pittsburgh Pittsburgh University of Pittsburgh PIs: F. S. Pettit, G. H. Meier Subcontractor: J. L. Beuth SCIES Project 02- 01- SR101 DOE COOPERATIVE AGREEMENT DE-FC26-02NT41431 Tom J. George, Program Manager, DOE/NETL Richard Wenglarz, Manager of Research, SCIES Project Awarded (05/01/02, 36 Month Duration + 6 mo No-Cost Extension) $ 458,420 Total Contract Value ($ 412,695 DOE) Mechanism-Based Testing Methodology For Improving the Oxidation, Hot Corrosion and Impact Resistance of High- Temperature Coatings for Advanced Gas Turbines University of Pittsburgh - Carnegie Mellon University University of Pittsburgh University of Pittsburgh In the next generation gas turbine, resistance to thermal cycling damage may be as important as resistance to long isothermal exposures. Moreover, metallic coatings and Thermal Barrier

139

Deformation behavior of laser welds in high temperature oxidation resistant FeCrAl alloys for fuel cladding applications  

Science Journals Connector (OSTI)

Abstract Ferritic-structured FeCrAl alloys are being developed and show promise as oxidation resistant accident tolerant light water reactor fuel cladding. This study focuses on investigating the weldability and post-weld mechanical behavior of three model alloys in a range of Fe(1317.5)Cr(34.4)Al (wt.%) with a minor addition of yttrium using modern laser-welding techniques. A detailed study on the mechanical performance of bead-on-plate welds using sub-sized, flat dog-bone tensile specimens and digital image correlation (DIC) has been carried out to determine the performance of welds as a function of alloy composition. Results indicated a reduction in the yield strength within the fusion zone compared to the base metal. Yield strength reduction was found to be primarily constrained to the fusion zone due to grain coarsening with a less severe reduction in the heat affected zone. For all proposed alloys, laser welding resulted in a defect free weld devoid of cracking or inclusions.

Kevin G. Field; Maxim N. Gussev; Yukinori Yamamoto; Lance L. Snead

2014-01-01T23:59:59.000Z

140

Solid oxide fuel cell process and apparatus  

DOE Patents [OSTI]

Conveying gas containing sulfur through a sulfur tolerant planar solid oxide fuel cell (PSOFC) stack for sulfur scrubbing, followed by conveying the gas through a non-sulfur tolerant PSOFC stack. The sulfur tolerant PSOFC stack utilizes anode materials, such as LSV, that selectively convert H.sub.2S present in the fuel stream to other non-poisoning sulfur compounds. The remaining balance of gases remaining in the completely or near H.sub.2S-free exhaust fuel stream is then used as the fuel for the conventional PSOFC stack that is downstream of the sulfur-tolerant PSOFC. A broad range of fuels such as gasified coal, natural gas and reformed hydrocarbons are used to produce electricity.

Cooper, Matthew Ellis (Morgantown, WV); Bayless, David J. (Athens, OH); Trembly, Jason P. (Durham, NC)

2011-11-15T23:59:59.000Z

Note: This page contains sample records for the topic "high-temperature solid oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Interconnection of bundled solid oxide fuel cells  

DOE Patents [OSTI]

A system and method for electrically interconnecting a plurality of fuel cells to provide dense packing of the fuel cells. Each one of the plurality of fuel cells has a plurality of discrete electrical connection points along an outer surface. Electrical connections are made directly between the discrete electrical connection points of adjacent fuel cells so that the fuel cells can be packed more densely. Fuel cells have at least one outer electrode and at least one discrete interconnection to an inner electrode, wherein the outer electrode is one of a cathode and and anode and wherein the inner electrode is the other of the cathode and the anode. In tubular solid oxide fuel cells the discrete electrical connection points are spaced along the length of the fuel cell.

Brown, Michael; Bessette, II, Norman F; Litka, Anthony F; Schmidt, Douglas S

2014-01-14T23:59:59.000Z

142

Solid oxide fuel cell matrix and modules  

DOE Patents [OSTI]

Porous refractory ceramic blocks arranged in an abutting, stacked configuration and forming a three dimensional array provide a support structure and coupling means for a plurality of solid oxide fuel cells (SOFCs). The stack of ceramic blocks is self-supporting, with a plurality of such stacked arrays forming a matrix enclosed in an insulating refractory brick structure having an outer steel layer. The necessary connections for air, fuel, burnt gas, and anode and cathode connections are provided through the brick and steel outer shell. The ceramic blocks are so designed with respect to the strings of modules that by simple and logical design the strings could be replaced by hot reloading if one should fail. The hot reloading concept has not been included in any previous designs. 11 figs.

Riley, B.

1988-04-22T23:59:59.000Z

143

Creep Behavior of Glass/Ceramic Sealant Used in Solid Oxide Fuel Cells  

SciTech Connect (OSTI)

High operating temperature of solid oxide fuel cells require that sealant must function at high temperature between 600o and 900oC and in the oxidizing and reducing environments of fuel and air. It should be noted that creep deformation becomes relevant for a material when the operating temperature is near or exceeds half of its melting temperature (in degrees of Kelvin). The operating temperatures for most of the solid oxide fuel cells (SOFC) under development in the SECA program are around 800oC, which exceeds the glass transition temperature Tg for most glass ceramic materials. The goal of the study is to develop a creep model to capture the creep behavior of glass ceramic materials at high temperature and to investigate the effect of creep of glass ceramic sealant materials on stresses in glass seal and on the various interfaces of glass seal with other layers. The self-consistent creep models were incorporated into SOFC-MP and Mentat FC, and finite element analyses were performed to quantify the stresses in various parts. The stress in glass seals were released due to its creep behavior during the operating environments.

Liu, Wenning N.; Sun, Xin; Koeppel, Brian J.; Khaleel, Mohammad A.

2010-01-02T23:59:59.000Z

144

Promises and problems with metallic interconnects for reduced temperature solid oxide fuel cells  

E-Print Network [OSTI]

Symposium on Solid Oxide Fuel Cells (SOFC-VI) ed. S. C.FOR REDUCED TEMPERATURE SOLID OXIDE FUEL CELLS Peggy Y. Hou,for low temperature solid oxide fuel cell is discussed in

Hou, Peggy Y.; Huang, Keqin; Bakker, Wate T.

1999-01-01T23:59:59.000Z

145

Solid State Electrochemical Sensors for Nitrogen Oxide (NOx) Detection in Lean Exhaust Gases  

E-Print Network [OSTI]

for Application in Solid Oxide Fuel Cells", (DoctoralImpedance of Solid Oxide Fuel Cell LSM/YSZ CompositeCathode materials of solid oxide fuel cells: a review, J

Rheaume, Jonathan Michael

2010-01-01T23:59:59.000Z

146

Rapid thermal cycling of metal-supported solid oxide fuel cell membranes  

E-Print Network [OSTI]

effect of pressure on solid oxide fuel cell performance," inand flat plate solid oxide fuel cells," in Proceedings ofSymposium on Solid Oxide Fuel Cells. Electrochem. Soc. 1993,

Matus, Yuriy B.; De Jonghe, Lutgard C.; Jacobson, Craig P.; Visco, Steven J.

2004-01-01T23:59:59.000Z

147

Method of electrode fabrication for solid oxide electrochemical cells  

DOE Patents [OSTI]

A process for fabricating cermet electrodes for solid oxide electrochemical cells by sintering is disclosed. First, a porous metal electrode is fabricated on a solid oxide cell, such as a fuel cell by, for example, sintering, and is then infiltrated with a high volume fraction stabilized zirconia suspension. A second sintering step is used to sinter the infiltrated zirconia to a high density in order to more securely attach the electrode to the solid oxide electrolyte of the cell. High performance fuel electrodes can be obtained with this process. Further electrode performance enhancement may be achieved if stabilized zirconia doped with cerium oxide, chromium oxide, titanium oxide, and/or praseodymium oxide for electronic conduction is used.

Jensen, Russell R. (Murrysville, PA)

1990-01-01T23:59:59.000Z

148

Method of electrode fabrication for solid oxide electrochemical cells  

DOE Patents [OSTI]

A process for fabricating cermet electrodes for solid oxide electrochemical cells by sintering is disclosed. First, a porous metal electrode is fabricated on a solid oxide cell, such as a fuel cell by, for example, sintering, and is then infiltrated with a high volume fraction stabilized zirconia suspension. A second sintering step is used to sinter the infiltrated zirconia to a high density in order to more securely attach the electrode to the solid oxide electrolyte of the cell. High performance fuel electrodes can be obtained with this process. Further electrode performance enhancement may be achieved if stabilized zirconia doped with cerium oxide, chromium oxide, titanium oxide, and/or praseodymium oxide for electronic conduction is used. 5 figs.

Jensen, R.R.

1990-11-20T23:59:59.000Z

149

High-Temperature Zirconia Oxygen Sensor with Sealed Metal/Metal...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference...

150

Creep analysis of solid oxide fuel cell with bonded compliant seal design  

Science Journals Connector (OSTI)

Abstract Solid oxide fuel cell (SOFC) requires good sealant because it works in harsh conditions (high temperature, thermal cycle, oxidative and reducing gas environments). Bonded compliant seal (BCS) is a new sealing method for planar SOFC. It uses a thin foil metal to bond the window frame and cell, achieving the seal between window frame and cell. At high temperature, a comprehensive evaluation of its creep strength is essential for the adoption of BCS design. In order to characterize the creep behavior, the creep induced by thermal stresses in SOFC with BCS design is simulated by finite element method. The results show that the foil is compressed and large thermal stresses are generated. The initial peak thermal stress is located in the thin foil because the foil acts as a spring stores the thermal stresses by elastic and plastic deformation in itself. Serving at high temperature, initial thermal displacement is partially recovered because of the creep relaxation, which becomes a new discovered advantage for BCS design. It predicts that the failures are likely to happen in the middle of the cell edge and BNi-2 filler metal, because the maximum residual displacement and creep strain are located.

Wenchun Jiang; Yucai Zhang; Yun Luo; J.M. Gong; S.T. Tu

2013-01-01T23:59:59.000Z

151

HIGH TEMPERATURE ELECTROLYZER MATERIALS PROJECT GOAL  

E-Print Network [OSTI]

with compatible electrodes to develop reversible solid oxide fuel cells for low-cost, high efficient power and solid oxide fuel cells. Notable reversible fuel cell achievements have been demonstrated by Proton of traditional oxide ion conductor-based solid oxide fuel cell (SOFC) materials. [2 ,3 ,4 ] Significantly

Mease, Kenneth D.

152

FUEL CELLS SOLID OXIDE FUEL CELLS | Systems  

Science Journals Connector (OSTI)

In this article, some basic arrangements of solid oxide fuel cell (SOFC) systems are described, starting with atmospheric systems using a catalytic burner or a thermal burner and anode gas recycling. For illustrating the potential electrical efficiency of SOFC systems, their combination with a gas turbine and also with a steam turbine (ST) are described. To be able to evaluate the potential of the different systems, first the essential efficiencies relevant to fuel cell systems are defined and then the basics of calculating energy balance are illustrated. Equations are given to describe, for example, the effect of fuel recycling on system fuel utilization and of internal reforming on the necessary air flow for cooling the stack. It is obvious that electrical efficiency depends strongly on cell voltage and fuel utilization. In the case of cells that operate with a high fuel utilization at cell voltages of 800mV, a net electrical efficiency above 55% can be achieved. The combination in a pressurized system with a gas turbine enables efficiencies of up to 70% and combining this system with an additional ST allows efficiencies of up to 75%. However, an investigation into the size of these \\{STs\\} shows that such combined systems make sense only above a gas input of 10MW.

L. Blum; E. Riensche

2009-01-01T23:59:59.000Z

153

Solid oxide fuel cell matrix and modules  

DOE Patents [OSTI]

Porous refractory ceramic blocks arranged in an abutting, stacked configuration and forming a three dimensional array provide a support structure and coupling means for a plurality of solid oxide fuel cells (SOFCs). Each of the blocks includes a square center channel which forms a vertical shaft when the blocks are arranged in a stacked array. Positioned within the channel is a SOFC unit cell such that a plurality of such SOFC units disposed within a vertical shaft form a string of SOFC units coupled in series. A first pair of facing inner walls of each of the blocks each include an interconnecting channel hole cut horizontally and vertically into the block walls to form gas exit channels. A second pair of facing lateral walls of each block further include a pair of inner half circular grooves which form sleeves to accommodate anode fuel and cathode air tubes. The stack of ceramic blocks is self-supporting, with a plurality of such stacked arrays forming a matrix enclosed in an insulating refractory brick structure having an outer steel layer. The necessary connections for air, fuel, burnt gas, and anode and cathode connections are provided through the brick and steel outer shell. The ceramic blocks are so designed with respect to the strings of modules that by simple and logical design the strings could be replaced by hot reloading if one should fail. The hot reloading concept has not been included in any previous designs.

Riley, Brian (Willimantic, CT)

1990-01-01T23:59:59.000Z

154

Nanostructured Solid Oxide Fuel Cell Electrodes  

SciTech Connect (OSTI)

The ability of Solid Oxide Fuel Cells (SOFC) to directly and efficiently convert the chemical energy in hydrocarbon fuels to electricity places the technology in a unique and exciting position to play a significant role in the clean energy revolution. In order to make SOFC technology cost competitive with existing technologies, the operating temperatures have been decreased to the range where costly ceramic components may be substituted with inexpensive metal components within the cell and stack design. However, a number of issues have arisen due to this decrease in temperature: decreased electrolyte ionic conductivity, cathode reaction rate limitations, and a decrease in anode contaminant tolerance. While the decrease in electrolyte ionic conductivities has been countered by decreasing the electrolyte thickness, the electrode limitations have remained a more difficult problem. Nanostructuring SOFC electrodes addresses the major electrode issues. The infiltration method used in this dissertation to produce nanostructure SOFC electrodes creates a connected network of nanoparticles; since the method allows for the incorporation of the nanoparticles after electrode backbone formation, previously incompatible advanced electrocatalysts can be infiltrated providing electronic conductivity and electrocatalysis within well-formed electrolyte backbones. Furthermore, the method is used to significantly enhance the conventional electrode design by adding secondary electrocatalysts. Performance enhancement and improved anode contamination tolerance are demonstrated in each of the electrodes. Additionally, cell processing and the infiltration method developed in conjunction with this dissertation are reviewed.

Sholklapper, Tal Zvi

2007-12-15T23:59:59.000Z

155

Aerosol Jet Printing of LSCF-CGO Cathode for Solid Oxide Fuel Cells.  

E-Print Network [OSTI]

??Solid oxide fuel cell (SOFC) technology has attracted great attention due to advantages such as low emissions and high efficiency. In this work, solid oxide (more)

Gardner, Paul

2011-01-01T23:59:59.000Z

156

Solid Oxide Fuel Cell Balance of Plant and Stack Component Integration...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Solid Oxide Fuel Cell Balance of Plant and Stack Component Integration Solid Oxide Fuel Cell Balance of Plant and Stack Component Integration Presentation by Acumentrics...

157

The Oxidation of Ferritic Stainless Steels in Simulated Solid-Oxide Fuel-Cell Atmospheres  

Science Journals Connector (OSTI)

The cyclic oxidation of a variety of chromia-forming ferritic stainless steels has been studied in the temperature range 700900C in atmospheres relevant to solid-oxide fuel-cell operation. The most detriment...

J. E. Hammer; S. J. Laney; R. W. Jackson; K. Coyne; F. S. Pettit

2007-02-01T23:59:59.000Z

158

Sandia National Laboratories: High-Pressure and High-Temperature...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ClimateECClimateCarbon CaptureHigh-Pressure and High-Temperature Neutron Reflectometry Cell for Solid-Fluid Interface Studies High-Pressure and High-Temperature Neutron...

159

Intermediate Temperature Solid Oxide Fuel Cell Development  

SciTech Connect (OSTI)

Solid oxide fuel cells (SOFCs) are high efficiency energy conversion devices. Present materials set, using yttria stabilized zirconia (YSZ) electrolyte, limit the cell operating temperatures to 800 C or higher. It has become increasingly evident however that lowering the operating temperature would provide a more expeditious route to commercialization. The advantages of intermediate temperature (600 to 800 C) operation are related to both economic and materials issues. Lower operating temperature allows the use of low cost materials for the balance of plant and limits degradation arising from materials interactions. When the SOFC operating temperature is in the range of 600 to 700 C, it is also possible to partially reform hydrocarbon fuels within the stack providing additional system cost savings by reducing the air preheat heat-exchanger and blower size. The promise of Sr and Mg doped lanthanum gallate (LSGM) electrolyte materials, based on their high ionic conductivity and oxygen transference number at the intermediate temperature is well recognized. The focus of the present project was two-fold: (a) Identify a cell fabrication technique to achieve the benefits of lanthanum gallate material, and (b) Investigate alternative cathode materials that demonstrate low cathode polarization losses at the intermediate temperature. A porous matrix supported, thin film cell configuration was fabricated. The electrode material precursor was infiltrated into the porous matrix and the counter electrode was screen printed. Both anode and cathode infiltration produced high performance cells. Comparison of the two approaches showed that an infiltrated cathode cells may have advantages in high fuel utilization operations. Two new cathode materials were evaluated. Northwestern University investigated LSGM-ceria composite cathode while Caltech evaluated Ba-Sr-Co-Fe (BSCF) based pervoskite cathode. Both cathode materials showed lower polarization losses at temperatures as low as 600 C than conventional manganite or cobaltite cathodes.

S. Elangovan; Scott Barnett; Sossina Haile

2008-06-30T23:59:59.000Z

160

FY 2014 Solid Oxide Fuel Cell Project Selections  

Broader source: Energy.gov [DOE]

In FY 2014, nine research projects focused on advancing the reliability, robustness, and endurance of solid oxide fuel cells (SOFC) have been selected for funding by Office of Fossil Energys...

Note: This page contains sample records for the topic "high-temperature solid oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Perspectives on the metallic interconnects for solid oxide fuel cells  

Science Journals Connector (OSTI)

The various stages and progress in the development of interconnect materials for solid oxide fuel cells (SOFCs) over the last two decades are reviewed. The criteria for the application of materials as intercon...

Wei-zhong Zhu; Mi Yan

2004-12-01T23:59:59.000Z

162

Multi-scale solid oxide fuel cell materials modeling  

Science Journals Connector (OSTI)

Performance and degradation of fuel cell components are discussed in a multi-scale ... paper. Electrochemical reactions in a solid oxide fuel cell occur simultaneously as charge and gas pass ... and cathode to pr...

Ji Hoon Kim; Wing Kam Liu; Christopher Lee

2009-10-01T23:59:59.000Z

163

Mathematical modeling of solid oxide fuel cells using hydrocarbon fuels  

E-Print Network [OSTI]

Solid oxide fuel cells (SOFCs) are high efficiency conversion devices that use hydrogen or light hydrocarbon (HC) fuels in stationary applications to produce quiet and clean power. While successful, HC-fueled SOFCs face ...

Lee, Won Yong, Ph. D. Massachusetts Institute of Technology

2012-01-01T23:59:59.000Z

164

Solid Oxide Fuel Cell and Power System Development at PNNL |...  

Broader source: Energy.gov (indexed) [DOE]

and Power System Development at PNNL Solid Oxide Fuel Cell and Power System Development at PNNL Presented at the DOE-DOD Shipboard APU Workshop on March 29, 2011....

165

Nanostructured thin films for solid oxide fuel cells  

E-Print Network [OSTI]

The goals of this work were to synthesize high performance perovskite based thin film solid oxide fuel cell (TF-SOFC) cathodes by pulsed laser deposition (PLD), to study the structural, electrical and electrochemical properties of these cathodes...

Yoon, Jongsik

2009-05-15T23:59:59.000Z

166

High temperature pressure gauge  

DOE Patents [OSTI]

A high temperature pressure gauge comprising a pressure gauge positioned in fluid communication with one end of a conduit which has a diaphragm mounted in its other end. The conduit is filled with a low melting metal alloy above the diaphragm for a portion of its length with a high temperature fluid being positioned in the remaining length of the conduit and in the pressure gauge.

Echtler, J. Paul (Pittsburgh, PA); Scandrol, Roy O. (Library, PA)

1981-01-01T23:59:59.000Z

167

Delivery system for molten salt oxidation of solid waste  

DOE Patents [OSTI]

The present invention is a delivery system for safety injecting solid waste particles, including mixed wastes, into a molten salt bath for destruction by the process of molten salt oxidation. The delivery system includes a feeder system and an injector that allow the solid waste stream to be accurately metered, evenly dispersed in the oxidant gas, and maintained at a temperature below incineration temperature while entering the molten salt reactor.

Brummond, William A. (Livermore, CA); Squire, Dwight V. (Livermore, CA); Robinson, Jeffrey A. (Manteca, CA); House, Palmer A. (Walnut Creek, CA)

2002-01-01T23:59:59.000Z

168

Low Temperature Constrained Sintering of Cerium Gadolinium OxideFilms for Solid Oxide Fuel Cell Applications  

SciTech Connect (OSTI)

Cerium gadolinium oxide (CGO) has been identified as an acceptable solid oxide fuel cell (SOFC) electrolyte at temperatures (500-700 C) where cheap, rigid, stainless steel interconnect substrates can be used. Unfortunately, both the high sintering temperature of pure CGO, >1200 C, and the fact that constraint during sintering often results in cracked, low density ceramic films, have complicated development of metal supported CGO SOFCs. The aim of this work was to find new sintering aids for Ce{sub 0.9}Gd{sub 0.1}O{sub 1.95}, and to evaluate whether they could be used to produce dense, constrained Ce{sub 0.9}Gd{sub 0.1}O{sub 1.95} films at temperatures below 1000 C. To find the optimal sintering aid, Ce{sub 0.9}Gd{sub 0.1}O{sub 1.95} was doped with a variety of elements, of which lithium was found to be the most effective. Dilatometric studies indicated that by doping CGO with 3mol% lithium nitrate, it was possible to sinter pellets to a relative density of 98.5% at 800 C--a full one hundred degrees below the previous low temperature sintering record for CGO. Further, it was also found that a sintering aid's effectiveness could be explained in terms of its size, charge and high temperature mobility. A closer examination of lithium doped Ce0.9Gd0.1O1.95 indicated that lithium affects sintering by producing a Li{sub 2}O-Gd{sub 2}O{sub 3}-CeO{sub 2} liquid at the CGO grain boundaries. Due to this liquid phase sintering, it was possible to produce dense, crack-free constrained films of CGO at the record low temperature of 950 C using cheap, colloidal spray deposition processes. This is the first time dense constrained CGO films have been produced below 1000 C and could help commercialize metal supported ceria based solid oxide fuel cells.

Nicholas, Jason.D.

2007-06-30T23:59:59.000Z

169

Integrating Multiple Solid Oxide Fuel Cell Modules* Burak Ozpineci1  

E-Print Network [OSTI]

than traditional generators even though they still have an important level of greenhouse gas (CO2 for more than a century. Today, as conventional fossil energy supplies, such as oil, coal and natural gas of Energy's Solid-State Energy Conversion Alliance (SECA) program [3] is targeting solid oxide fuel cell

Tolbert, Leon M.

170

3D CFD Model of a Tubular Porous-Metal Supported Solid Oxide Electrolysis Cell  

SciTech Connect (OSTI)

Currently there is strong interest in the large-scale production of hydrogen as an energy carrier for the non-electrical market [1, 2, and 3]. High-temperature nuclear reactors have the potential for substantially increasing the efficiency of hydrogen production from water splitting, with no consumption of fossil fuels, no production of greenhouse gases, and no other forms of air pollution. A high-temperature advanced nuclear reactor coupled with a high-efficiency high-temperature electrolyzer could achieve a competitive thermal-to-hydrogen conversion efficiency of 45 to 55%. A research program is under way at the INL to simultaneously address the research and scale-up issues associated with the implementation of solid-oxide electrolysis cell technology for hydrogen production from steam. The future SOEC market includes the 1200MW GEN4 reactor which has projected 40-50% efficiency, 400 tones H2 production per day (at 5kg H2/car/300 mile day this corresponds to 80,000 cars/day). DOE is planning for 26GW of nuclear hydrogen production by 2025.

G.L. Hawkes; B.D. Hawkes; M.S. Sohal; P.T. Torgerson; T. Armstrong; M.C. Williams

2007-10-01T23:59:59.000Z

171

Effect of Acid Treatment on the High-Temperature Surface Oxidation Behavior of FeCrAlloy Foil Used for Methane Combustion Catalyst Support  

Science Journals Connector (OSTI)

The catalytic flameless combustion of low alkans improves the efficiency of energy production and reduces NOx emission. ... (3-5) Fe?Cr?Al alloy (FeCrAlloy) has superior stability to other iron-based alloys at high temperatures and has been used in the fabrication of gas burners, industrial heaters, and other high-temperature devices. ... The heating rate was 10 C/min. ...

Dong Zhang; Lihong Zhang; Bin Liang; Yongdan Li

2009-04-24T23:59:59.000Z

172

Breakout Group 5: Solid Oxide Fuel Cells  

Broader source: Energy.gov (indexed) [DOE]

Oxide Fuel Cells PARTICIPANTS Name Organization Robert Ploessl Corning, Inc. Tim Armstrong Oak Ridge National Laboratory Barbara Heydorn SRI International Suresh Baskaran...

173

Chemistry at High Temperatures  

Science Journals Connector (OSTI)

...347 the condensed phase. Both cases are...show the opposite behavior. These predictions...vapors. Condensed phase B203 B + B203 02...complex silicates and hydrates in high-temperature...characterized by phase diagrams (derived...doubt that thou-sands of new chemical materials...

John L. Margrave

1962-02-02T23:59:59.000Z

174

The Development of Nano-Composite Electrodes for Solid Oxide Electrolyzers  

SciTech Connect (OSTI)

Solid oxide fuel cells (SOFC) and electrolyzers (SOE) offer an attractive means for converting between electrical and chemical energy. Because they operate at high temperatures and are usually based on electrolytes that are oxygen-ion conducting ceramics, such as yttria-stabilized zirconia (YSZ), they are equally capable of converting between CO and CO2 as between H2 and H2O. When operated in the SOFC mode, they are able to operate on hydrocarbon fuels so long as there are no materials within the anode that can catalyze carbon formation. Compared to other types of electrolyzers, SOE can exhibit the highest efficiencies because the theoretical Nernst potential is lower at high temperatures and because the electrode overpotentials in SOE tend to be much lower. Finally, pure H2 can be produced without an external electrical source by electrolysis of steam at one electrode and oxidation of any fuel at the other electrode through a process known as Natural-Gas Assisted Steam Electrolysis. This final report describes results from studies of novel electrodes for SOE and SOFC prepared by infiltration methods.

Gorte, Raymond J.; Vohs, John M.

2014-03-26T23:59:59.000Z

175

Author's personal copy Crystal structure and compressibility of a high-pressure Ti-rich oxide,  

E-Print Network [OSTI]

promising candidate for the development of electrolytes in solid oxide fuel cells. & 2009 Elsevier Ltd. All for solid-oxide-fuel-cell electrolytes, owing to its excellent stability at high temperature, good, solid electrolytes in high-temperature fuel cells, thermal barrier coatings in engines, and high

Downs, Robert T.

176

Materials Degradation Studies for High Temperature Steam Electrolysis Systems  

SciTech Connect (OSTI)

Experiments are currently in progress to assess the high temperature degradation behavior of materials in solid oxide electrolysis systems. This research includes the investigation of various electrolysis cell components and balance of plant materials under both anodic and cathodic gas atmospheres at temperatures up to 850C. Current results include corrosion data for a high temperature nickel alloy used for the air-side flow field in electrolysis cells and a commercial ferritic stainless steel used as the metallic interconnect. Three different corrosion inhibiting coatings were also tested on the steel material. The samples were tested at 850C for 500 h in both air and H2O/H2 atmospheres. The results of this research will be used to identify degradation mechanisms and demonstrate the suitability of candidate materials for long-term operation in electrolysis cells.

Paul Demkowicz; Pavel Medvedev; Kevin DeWall; Paul Lessing

2007-06-01T23:59:59.000Z

177

Microstructural coarsening effects on redox instability and mechanical damage in solid oxide fuel cell anodes  

Science Journals Connector (OSTI)

In state-of-the-art high temperature solid oxide fuel cells (SOFCs) a porous composite of nickel and yttria stabilized zirconia (Ni/YSZ) is employed as the anode. The rapid oxidation of Ni into NiO is regarded as the main cause of the so-called reduction-oxidation (redox) instability in Ni/YSZ anodes due to the presence of extensive bulk volume changes associated with this reaction. As a consequence the development of internal stresses can lead to performance degradation and/or structural failure. In this study we employ a recently developed continuum formalism to quantify the mechanical deformation behavior and evolution of internal stresses in Ni/YSZ porous anodes due to re-oxidation. In our approach a local failure criterion is coupled to the continuum framework in order to account for the heterogeneous damage accumulation in the YSZ phase. The hallmark of our approach is the ability to track the spatial evolution of mechanical damage and capture the interaction of YSZ damaged regions with the local microstructure. Simulation results highlight the importance of the microstructure characterized by Ni to YSZ particle size ratio on the redox behavior and damage accumulation in as-synthesized SOFC anode systems. Moreover a redox-strain-to-failure criterion is developed to quantify the degree by which coarsened anode microstructures become more susceptible to mechanical damage during re-oxidation.

F. Abdeljawad; M. Haataja

2013-01-01T23:59:59.000Z

178

High temperature corrosion of boiler waterwalls induced by chlorides and bromides. Part 1: Occurrence of the corrosive ash forming elements in a fluidised bed boiler co-firing solid recovered fuel  

Science Journals Connector (OSTI)

In waste fired boilers high temperature corrosion has often been attributed to zinc and lead chlorides. In addition, bromine induced high temperature corrosion has been earlier observed in a bubbling fluidised bed (BFB) boiler co-firing solid recovered fuel (SRF) with bark and wastewater sludge. In Part 1 of this work a measurement campaign was undertaken to determine the occurrence of Cl, Br, Zn and Pb in the fuel, in the combustion gases as well as in the deposits on the boiler waterwalls. It was observed that Cl, Br, Zn and Pb originate to a large extent from the SRF, they are vaporised in the furnace, and may form waterwall deposits. This, complemented by fluctuations between oxidising and reducing atmosphere resulted in rapid corrosion of the waterwall tubes. Concentrations of Cl, Br, Zn and Pb in the fuel, in the furnace vapours and in the deposits are reported in this work. As there is lack of published data on the bromine induced high temperature corrosion, laboratory scale corrosion tests were carried out to determine the relative corrosiveness of chlorine and bromine and these results will be reported in Part 2 of this work. Furthermore, the forms of Cl, Br, Zn and Pb in the combustion gases as well as in the waterwall deposits were estimated by means of thermodynamic equilibrium modelling and these results will also be discussed in Part 2.

P. Vainikka; D. Bankiewicz; A. Frantsi; J. Silvennoinen; J. Hannula; P. Yrjas; M. Hupa

2011-01-01T23:59:59.000Z

179

3D CFD Model of High Temperature H2O/CO2 Co-electrolysis  

SciTech Connect (OSTI)

3D CFD Model of High Temperature H2O/CO2 Co-Electrolysis Grant Hawkes1, James OBrien1, Carl Stoots1, Stephen Herring1 Joe Hartvigsen2 1 Idaho National Laboratory, Idaho Falls, Idaho, grant.hawkes@inl.gov 2 Ceramatec Inc, Salt Lake City, Utah INTRODUCTION A three-dimensional computational fluid dynamics (CFD) model has been created to model high temperature co-electrolysis of steam and carbon dioxide in a planar solid oxide electrolyzer (SOE) using solid oxide fuel cell technology. A research program is under way at the Idaho National Laboratory (INL) to simultaneously address the research and scale-up issues associated with the implementation of planar solid-oxide electrolysis cell technology for syn-gas production from CO2 and steam. Various runs have been performed under different run conditions to help assess the performance of the SOE. This paper presents CFD results of this model compared with experimental results. The Idaho National Laboratory (INL), in conjunction with Ceramatec Inc. (Salt Lake City, USA) has been researching for several years the use of solid-oxide fuel cell technology to electrolyze steam for large-scale nuclear-powered hydrogen production. Now, an experimental research project is underway at the INL to produce syngas by simultaneously electrolyzing at high-temperature steam and carbon dioxide (CO2) using solid oxide fuel cell technology. A strong interest exists in the large-scale production of syn-gas from CO2 and steam to be reformed into a usable transportation fuel. If biomass is used as the carbon source, the overall process is climate neutral. Consequently, there is a high level of interest in production of syn-gas from CO2 and steam electrolysis. With the price of oil currently around $60 / barrel, synthetically-derived hydrocarbon fuels (synfuels) have become economical. Synfuels are typically produced from syngas hydrogen (H2) and carbon monoxide (CO) -- using the Fischer-Tropsch process, discovered by Germany before World War II. High-temperature nuclear reactors have the potential for substantially increasing the efficiency of syn-gas production from CO2 and water, with no consumption of fossil fuels, and no production of greenhouse gases. Thermal CO2-splitting and water splitting for syn-gas production can be accomplished via high-temperature electrolysis, using high-temperature nuclear process heat and electricity. A high-temperature advanced nuclear reactor coupled with a high-efficiency high-temperature electrolyzer could achieve a competitive thermal-to-syn-gas conversion efficiency of 45 to 55%.

Grant Hawkes; James O'Brien; Carl Stoots; Stephen Herring; Joe Hartvigsen

2007-06-01T23:59:59.000Z

180

High Temperature Membrane Working Group  

Broader source: Energy.gov [DOE]

The High Temperature Membrane Working Group consists of government, industry, and university researchers interested in developing high temperature membranes for fuel cells.

Note: This page contains sample records for the topic "high-temperature solid oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

High temperature probe  

DOE Patents [OSTI]

A high temperature probe for sampling, for example, smokestack fumes, and is able to withstand temperatures of 3000.degree. F. The probe is constructed so as to prevent leakage via the seal by placing the seal inside the water jacket whereby the seal is not exposed to high temperature, which destroys the seal. The sample inlet of the probe is also provided with cooling fins about the area of the seal to provide additional cooling to prevent the seal from being destroyed. Also, a heated jacket is provided for maintaining the temperature of the gas being tested as it passes through the probe. The probe includes pressure sensing means for determining the flow velocity of an efficient being sampled. In addition, thermocouples are located in various places on the probe to monitor the temperature of the gas passing there through.

Swan, Raymond A. (Fremont, CA)

1994-01-01T23:59:59.000Z

182

Stack configurations for tubular solid oxide fuel cells  

DOE Patents [OSTI]

A fuel cell unit includes an array of solid oxide fuel cell tubes having porous metallic exterior surfaces, interior fuel cell layers, and interior surfaces, each of the tubes having at least one open end; and, at least one header in operable communication with the array of solid oxide fuel cell tubes for directing a first reactive gas into contact with the porous metallic exterior surfaces and for directing a second reactive gas into contact with the interior surfaces, the header further including at least one busbar disposed in electrical contact with at least one surface selected from the group consisting of the porous metallic exterior surfaces and the interior surfaces.

Armstrong, Timothy R. (Clinton, TN); Trammell, Michael P. (Clinton, TN); Marasco, Joseph A. (Kingston, TN)

2010-08-31T23:59:59.000Z

183

Effect of Water Vapor on the Oxidation Mechanisms of a Commercial Stainless Steel for Interconnect Application in High Temperature Water Vapor Electrolysis  

Science Journals Connector (OSTI)

High temperature water vapor electrolysis is one of the most promising methods...25%H2O) and cathode atmospheres (10%H290%H2O). In cathode atmosphere, ageing tests performed up to 1,000h revealed the format...

Maria Rosa Ardigo; Ioana Popa; Sbastien Chevalier; Sylvain Weber

2013-06-01T23:59:59.000Z

184

NORTHWESTERN UNIVERSITY A Study of Oxides for Solid Oxide Cells  

E-Print Network [OSTI]

owing to issues of cost, durability, and performance. In this thesis, three dierent aspects of solid;4 Then, degradation taking place when the cell is run in electrolysis mode is discussed. A high current allows for a high production rate of hydrogen gas. However, this can also lead to oxygen bubble

Shkel, Andrei M.

185

High Temperature Membrane Working Group  

Broader source: Energy.gov [DOE]

This presentation provides an overview of the High Temperature Membrane Working Group Meeting in May 2007.

186

Multi-Component and Multi-Dimensional Mathematical Modeling of Solid Oxide Fuel Cells.  

E-Print Network [OSTI]

??Solid oxide fuel cells (SOFCs) are solid-state ceramic cells, typically operating between 1073 K and 1273 K. Because of high operating temperature, SOFCs are mostly (more)

Hussain, Mohammed Mujtaba

2008-01-01T23:59:59.000Z

187

Molten Metal Anodes for Direct Carbon-Solid Oxide Fuel Cells.  

E-Print Network [OSTI]

??The aim of this thesis was to enable the direct utilization of solid carbonaceous fuels like coal and biomass, in solid oxide fuel cells (SOFC). (more)

Jayakumar, Abhimanyu

2012-01-01T23:59:59.000Z

188

High temperature detonator  

DOE Patents [OSTI]

A detonator assembly is provided which is usable at high temperatures about 300.degree. C. A detonator body is provided with an internal volume defining an anvil surface. A first acceptor explosive is disposed on the anvil surface. A donor assembly having an ignition element, an explosive material, and a flying plate, are placed in the body effective to accelerate the flying plate to impact the first acceptor explosive on the anvil for detonating the first acceptor explosive. A second acceptor explosive is eccentrically located in detonation relationship with the first acceptor explosive to thereafter effect detonation of a main charge.

Johnson, James O. (Los Alamos, NM); Dinegar, Robert H. (Los Alamos, NM)

1988-01-01T23:59:59.000Z

189

Modified cermet fuel electrodes for solid oxide electrochemical cells  

DOE Patents [OSTI]

An exterior porous electrode (10), bonded to a solid oxygen ion conducting electrolyte (13) which is in contact with an interior electrode (14), contains coarse metal particles (12) of nickel and/or cobalt, having diameters from 3 micrometers to 35 micrometers, where the coarse particles are coated with a separate, porous, multiphase layer (17) containing fine metal particles of nickel and/or cobalt (18), having diameters from 0.05 micrometers to 1.75 micrometers and conductive oxide (19) selected from cerium oxide, doped cerium oxide, strontium titanate, doped strontium titanate and mixtures thereof.

Ruka, Roswell J. (Churchill Boro, PA); Spengler, Charles J. (Murrysville, PA)

1991-01-01T23:59:59.000Z

190

Direct oxidation of hydrocarbons in a solid oxide fuel cell. I. Methane oxidation  

SciTech Connect (OSTI)

The performance of Cu cermets as anodes for the direct oxidation of CH{sub 4} in solid oxide fuel cells was examined. Mixtures of Cu and yttria-stabilized zirconia (YAZ) were found to give similar performance to Ni-YSZ cermets when H{sub 2} was used as the fuel, but did not deactivate in dry CH{sub 4}. While Cu-YSZ was essentially inert to methane, the addition of ceria to the anode gave rise to reasonable power densities and stable operation over a period of at least 3 days. Proof of direct oxidation of CH{sub 4} came from chemical analysis of the products leaving the cell. The major carbon-containing product was CO{sub 2}, with only traces of CO observed, and there was excellent agreement between the actual cell current and that predicted by the methane conversion. These results demonstrate that direct, electrocatalytic oxidation of dry methane is possible, with reasonable performance.

Park, S.; Craciun, R.; Vohs, J.M.; Gorte, R.J.

1999-10-01T23:59:59.000Z

191

Validation of a solid oxide fuel cell model  

Science Journals Connector (OSTI)

The need to study the performance of solid oxide fuel cells (SOFCs) has made mathematical modeling an essential tool for their design. Electrochemical modeling evaluates ohmic activation and concentration overpotentials that affect SOFC operation. A detailed cell model is developed for an SOFC and is validated with experimental data from the open literature.

Christina Charalampidou; Ioannis K. Kookos

2012-01-01T23:59:59.000Z

192

Nanofiber Scaffold for Cathode of Solid Oxide Fuel Cell  

SciTech Connect (OSTI)

A high performance solid oxide fuel cell cathode using the yttria-stabilized zirconia (YSZ) nanofibers scaffold with the infiltrated La1-xSrxMnO3 (LSM) shows an enhanced catalytic activity toward oxygen reduction. Such a cathode offers a continuous path for charge transport and an increased number of triple-phase boundary sites.

Mingjia Zhi; Nicholas Mariani; Randall Gemmen; Kirk Gerdes; Nianqiang Wu

2010-10-01T23:59:59.000Z

193

Method of fabricating a monolithic solid oxide fuel cell  

DOE Patents [OSTI]

In a two-step densifying process of making a monolithic solid oxide fuel cell, a limited number of anode-electrolyte-cathode cells separated by an interconnect layer are formed and partially densified. Subsequently, the partially densified cells are stacked and further densified to form a monolithic array.

Minh, Nguyen Q. (Fountain Valley, CA); Horne, Craig R. (Redondo Beach, CA)

1994-01-01T23:59:59.000Z

194

Review article Components manufacturing for solid oxide fuel cells  

E-Print Network [OSTI]

-stabilized zirconia, YSZ) and the electrocatalyst (lanthanum manganite for the cathode and nickel metal for the anode are stressed. Especially for planar cell designs, the chromium contamination of the cathode and interfacial; Processing; Interconnect materials 1. Introduction Worldwide, several developers of solid oxide fuel cell

Gleixner, Stacy

195

Nonprecious Metal Catalysts for Low Temperature Solid Oxide Fuel Cells  

Science Journals Connector (OSTI)

Nonprecious Metal Catalysts for Low Temperature Solid Oxide Fuel Cells ... Initial and final state geometries are found with standard geometry optimization, then a number of intermediate states are generated by interpolation of atomic positions. ... A special "metric" and a special "preconditioning" optimized for a plane-wave basis set will be introduced. ...

Timothy P. Holme; Fritz B. Prinz

2011-05-24T23:59:59.000Z

196

New Chemical Systems for Solid Oxide Fuel Cells  

Science Journals Connector (OSTI)

New Chemical Systems for Solid Oxide Fuel Cells ... (238) This, however, represented a significant improvement over earlier work with the use of Pt electrodes, suggesting that further improvements can be made through electrode optimization and, hence, identifying the need for more work in optimizing electrodes for use with apatite electrolytes. ... cond., the optimized compn. ...

A. Orera; P. R. Slater

2009-11-05T23:59:59.000Z

197

Joint Institute for High Temperatures  

National Nuclear Security Administration (NNSA)

Joint Institute for High Temperatures of Russian Academy of Sciences Moscow Institute of Physics and Technology Extended title Extended title Excited state of warm dense matter or Exotic state of warm dense matter or Novel form of warm dense matter or New form of plasma Three sources of generation similarity: solid state density, two temperatures: electron temperature about tens eV, cold ions keep original crystallographic positions, but electron band structure and phonon dispersion are changed, transient but steady (quasi-stationary for a short time) state of non-equilibrium, uniform plasmas (no reference to non-ideality, both strongly and weakly coupled plasmas can be formed) spectral line spectra are emitted by ion cores embedded in plasma environment which influences the spectra strongly,

198

High temperature thermometric phosphors  

DOE Patents [OSTI]

A high temperature phosphor consists essentially of a material having the general formula LuPO.sub.4 :Dy.sub.(x),Eu.sub.y) wherein: 0.1 wt %.ltoreq.x.ltoreq.20 wt % and 0.1 wt %.ltoreq.y.ltoreq.20 wt %. The high temperature phosphor is in contact with an article whose temperature is to be determined. The article having the phosphor in contact with it is placed in the environment for which the temperature of the article is to be determined. The phosphor is excited by a laser causing the phosphor to fluoresce. The emission from the phosphor is optically focused into a beam-splitting mirror which separates the emission into two separate emissions, the emission caused by the dysprosium dopant and the emission caused by the europium dopent. The separated emissions are optically filtered and the intensities of the emission are detected and measured. The ratio of the intensity of each emission is determined and the temperature of the article is calculated from the ratio of the intensities of the separate emissions.

Allison, Stephen W. (Knoxville, TN); Cates, Michael R. (Oak Ridge, TN); Boatner, Lynn A. (Oak Ridge, TN); Gillies, George T. (Earlysville, VA)

1999-03-23T23:59:59.000Z

199

Thermal Stress Analysis of LCA-based Solid Oxide Fuel Cells.  

E-Print Network [OSTI]

??This research characterizes the thermal stress resulting from temperature gradients in hybrid solid oxide fuel cells that are processed using a novel oxide powder slurry (more)

LeMasters, Jason Augustine

2004-01-01T23:59:59.000Z

200

Three-Dimensional Computational Fluid Dynamics Modeling of Solid Oxide Electrolysis Cells and Stacks  

SciTech Connect (OSTI)

A three-dimensional computational fluid dynamics (CFD) electrochemical model has been created for detailed analysis of a high-temperature electrolysis stack (solid oxide fuel cells operated as electrolyzers). Inlet and outlet plenum flow distributions are discussed. Maldistribution of plena flow show deviations in per-cell operating conditions due to non-uniformity of species concentrations. Models have also been created to simulate experimental conditions and for code validation. Comparisons between model predictions and experimental results are discussed. Mass, momentum, energy, and species conservation and transport are provided via the core features of the commercial CFD code FLUENT. A solid-oxide fuel cell (SOFC) model adds the electrochemical reactions and loss mechanisms and computation of the electric field throughout the cell. The FLUENT SOFC user-defined subroutine was modified for this work to allow for operation in the electrolysis mode. Model results provide detailed profiles of temperature, Nernst potential, operating potential, activation over-potential, anode-side gas composition, cathode-side gas composition, current density and hydrogen production over a range of stack operating conditions. Variations in flow distribution, and species concentration are discussed. End effects of flow and per-cell voltage are also considered. Predicted mean outlet hydrogen and steam concentrations vary linearly with current density, as expected. Contour plots of local electrolyte temperature, current density, and Nernst potential indicate the effects of heat transfer, reaction cooling/heating, and change in local gas composition.

Grant Hawkes; James O'Brien; Carl Stoots; Stephen Herring

2008-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "high-temperature solid oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Simulation of creep and damage in the bonded compliant seal of planar solid oxide fuel cell  

Science Journals Connector (OSTI)

Abstract Planar solid oxide fuel cell (SOFC) operates at high temperature and requires a good creep strength to ensure the structure integrity. This paper presents a creep and damage analysis of a bonded compliant seal (BCS) structure of a planar SOFC considering the effect of as-bonded residual stress and thermal stress, as well as the effect of filler metal and foil thickness. A modified continuum creep-damage model is used in the finite element simulation. It demonstrates that the BCS structure meets the requirement of the long-term operation at the high temperature of 600C with an appropriate braze bonding process. The results show that the failure location is not in the region of maximum creep deformation due to the effect of high level multi-axial stress which drastically decreases the multi-axial ductility. Reasonably reducing the thickness of filler metal and foil can decrease the damage of the BCS structure. Based on the consideration of creep and damage, it is proposed that the thickness of filler metal and foil should not exceed 0.1 and 0.05mm, respectively.

Yu-Cai Zhang; Wenchun Jiang; Shan-Tung Tu; Jian-Feng Wen

2014-01-01T23:59:59.000Z

202

Solid oxide fuel cell with single material for electrodes and interconnect  

DOE Patents [OSTI]

A solid oxide fuel cell having a plurality of individual cells. A solid oxide fuel cell has an anode and a cathode with electrolyte disposed therebetween, and the anode, cathode and interconnect elements are comprised of substantially one material.

McPheeters, Charles C. (Naperville, IL); Nelson, Paul A. (Wheaton, IL); Dees, Dennis W. (Downers Grove, IL)

1994-01-01T23:59:59.000Z

203

Solid Oxide Fuel Cell System (SOFC) Technology R&D Needs (Presentation...  

Broader source: Energy.gov (indexed) [DOE]

Solid Oxide Fuel Cell System (SOFC) Technology R&D Needs (Presentation) Solid Oxide Fuel Cell System (SOFC) Technology R&D Needs (Presentation) Presented at the DOE Fuel Cell...

204

Solid Oxide Fuel Cell Balance of Plant and Stack Component Integration  

Broader source: Energy.gov [DOE]

Presentation by Acumentrics Corporation for Solid Oxide Fuel Cell Balance of Plant and Stack Component Integration March 16, 2010

205

Evolution of microstructures inside the Ni-YSZ anode of a solid oxide fuel cell  

E-Print Network [OSTI]

Evolution of microstructures inside the Ni-YSZ anode of a solid oxide fuel cell Jeff Lillibridge Department of Mechanical & Aerospace Engineering Advisor: Mikko Haataja #12;What is a solid oxide fuel cell microstructuralcoarsening processes to electrochemical performancein solid oxide fuel cells: An integrated modeling approach

Petta, Jason

206

Oxygen diffusion in solid oxide fuel cell cathode and electrolyte materials: mechanistic insights from atomistic simulations  

E-Print Network [OSTI]

Oxygen diffusion in solid oxide fuel cell cathode and electrolyte materials: mechanistic insights to drive fast ionic transport. 1. Introduction The interest in Solid Oxide Fuel Cell (SOFC) technology. Current targets of cost and durability necessitate solid oxide fuel cells to operate in the intermediate

Yildiz, Bilge

207

JOURNAL OF MATERIALS SCIENCE 29 (1994) 4135-4151 Bismuth oxide-based solid electrolytes for  

E-Print Network [OSTI]

of investigations has been reported pertaining to the science and technology of solid oxide fuel cells (SOFCs) based as the electrolyte and are accordingly known as the molten carbonate fuel cells (MCFCs) and the solid oxide fuelJOURNAL OF MATERIALS SCIENCE 29 (1994) 4135-4151 Review Bismuth oxide-based solid electrolytes

Azad, Abdul-Majeed

208

Original Research Article Influence of anodic gas recirculation on solid oxide fuel cells in a micro  

E-Print Network [OSTI]

Original Research Article Influence of anodic gas recirculation on solid oxide fuel cells utilization in the cell-stack should be reduced. ? 2014 Published by Elsevier Ltd. Introduction Solid-oxide Anode off-gas recycle a b s t r a c t The recycle of anode depleted gas has been employed in solid oxide

Nielsen, Mads Pagh

209

High-Temperature Water Splitting  

Broader source: Energy.gov [DOE]

High-temperature water splitting (a "thermochemical" process) is a long-term technology in the early stages of development.

210

High-Temperature Thermoelectric Properties of the SolidSolution Zintl Phase Eu11Cd6Sb12xAsx (x < 3)  

SciTech Connect (OSTI)

Zintl phases are compounds that have shown promise for thermoelectric applications. The title solidsolution Zintl compounds were prepared from the elements as single crystals using a tin flux for compositions x = 0, 1, 2, and 3. Eu11Cd6Sb12xAsx (x < 3) crystallize isostructurally in the centrosymmetric monoclinic space group C2/m (no. 12, Z = 2) as the Sr11Cd6Sb12 structure type (Pearson symbol mC58). Efforts to make the As compositions for x exceeding ?3 resulted in structures other than the Sr11Cd6Sb12 structure type. Single-crystal X-ray diffraction indicates that As does not randomly substitute for Sb in the structure but is site specific for each composition. The amount of As determined by structural refinement was verified by electron microprobe analysis. Electronic structures and energies calculated for various model structures of Eu11Cd6Sb10As2 (x = 2) indicated that the preferred As substitution pattern involves a mixture of three of the six pnicogen sites in the asymmetric unit. In addition, As substitution at the Pn4 site opens an energy gap at the Fermi level, whereas substitution at the other five pnicogen sites remains semimetallic with a pseudo gap. Thermoelectric properties of these compounds were measured on hot-pressed, fully densified pellets. Samples show exceptionally low lattice thermal conductivities from room temperature to 775 K: 0.780.49 W/mK for x = 0; 0.720.53 W/mK for x = 1; and 0.700.56 W/mK for x = 2. Eu11Cd6Sb12 shows a high p-type Seebeck coefficient (from +118 to 153 ? V/K) but also high electrical resistivity (6.8 to 12.8 m?cm). The value of zT reaches 0.23 at 774 K. The properties of Eu11Cd6Sb12xAsx are interpreted in discussion with the As site substitution.

Kazem, Nasrin; Xie, Weiwei; Ohno, Saneyuki; Zevalkink, Alexandra; Miller, Gordon J.; Snyder, G. Jeffrey; Kauzlarich, Susan M.

2014-02-11T23:59:59.000Z

211

SOLID OXIDE FUEL CELL HYBRID SYSTEM FOR DISTRIBUTED POWER GENERATION  

SciTech Connect (OSTI)

This report summarizes the work performed by Honeywell during the July 2001 to September 2001 reporting period under Cooperative Agreement DE-FC26-01NT40779 for the U. S. Department of Energy, National Energy Technology Laboratory (DOE/NETL) entitled ''Solid Oxide Fuel Cell Hybrid System for Distributed Power Generation''. The main objective of this project is to develop and demonstrate the feasibility of a highly efficient hybrid system integrating a planar Solid Oxide Fuel Cell (SOFC) and a turbogenerator. An internal program kickoff was held at Honeywell in Torrance, CA. The program structure was outlined and the overall technical approach for the program was presented to the team members. Detail program schedules were developed and detailed objectives were defined. Initial work has begun on the system design and pressurized SOFC operation.

Unknown

2002-03-01T23:59:59.000Z

212

Solid Oxide Fuel Cell Hybrid System for Distributed Power Generation  

SciTech Connect (OSTI)

This report summarizes the work performed by Honeywell during the January 2002 to March 2002 reporting period under Cooperative Agreement DE-FC26-01NT40779 for the U. S. Department of Energy, National Energy Technology Laboratory (DOE/NETL) entitled ''Solid Oxide Fuel Cell Hybrid System for Distributed Power Generation''. The main objective of this project is to develop and demonstrate the feasibility of a highly efficient hybrid system integrating a planar Solid Oxide Fuel Cell (SOFC) and a turbogenerator. For this reporting period the following activities have been carried out: {lg_bullet} Conceptual system design trade studies were performed {lg_bullet} System-level performance model was created {lg_bullet} Dynamic control models are being developed {lg_bullet} Mechanical properties of candidate heat exchanger materials were investigated {lg_bullet} SOFC performance mapping as a function of flow rate and pressure was completed

Nguyen Minh

2002-03-31T23:59:59.000Z

213

Thermo Physical Properties of Materials for Solid Oxide Fuel Cells  

Science Journals Connector (OSTI)

Solid oxide fuel cells (SOFCs) are energy conversion devices that convert chemical energy to electrical energy with high efficiency and have the added advantage of least production of pollutants during their operation. SOFCs comprise of a number of components such as the anode the electrolyte the cathode and the interconnect. Each of these components is made of a different material with different thermophysical and electrical properties. Thermal expansion coefficient is one of the most important properties of these compounds. Various components should have matching thermal expansion behaviour to avoid cracking during thermal cycling and for long term operation of SOFCs. In this article the thermophysical properties of materials for solid oxide fuel cells will be discussed with special emphasize on their thermal expansion behaviour.

S. R. Bharadwaj

2010-01-01T23:59:59.000Z

214

Solid Oxide Fuel Cell Hybrid System for Distributed Power Generation  

SciTech Connect (OSTI)

This report summarizes the work performed by Hybrid Power Generation Systems, LLC (HPGS) during the July 2003 to December 2003 reporting period under Cooperative Agreement DE-FC26-01NT40779 for the U. S. Department of Energy, National Energy Technology Laboratory (DOE/NETL) entitled ''Solid Oxide Fuel Cell Hybrid System for Distributed Power Generation''. The main objective of this project is to develop and demonstrate the feasibility of a highly efficient hybrid system integrating a planar Solid Oxide Fuel Cell (SOFC) and a micro-turbine. In addition, an activity included in this program focuses on the development of an integrated coal gasification fuel cell system concept based on planar SOFC technology. Also, another activity included in this program focuses on the development of SOFC scale up strategies.

Faress Rahman; Nguyen Minh

2004-01-04T23:59:59.000Z

215

Neutron Sciences - Electrode Material for Solid-oxide Fuel Cells  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Theory meets experiment: structure-property relationships in an electrode Theory meets experiment: structure-property relationships in an electrode material for solid-oxide fuel cells Research Contact: Ana B. Munoz-Garcia December 2012, Written by Agatha Bardoel Fuel cell technology is one potentially very efficient and environmentally friendly way to convert the chemical energy of fuels into electricity. Solid-oxide fuel cells (SOFCs) can convert a wide variety of fuels with simpler, cheaper designs than those used in liquid electrolyte cells. Using the Powder Diffractometer at the Spallation Neutron Source, researchers experimentally characterized the promising new SOFC electrode material strontium iron molybdenum oxide─Sr2Fe1.5Mo0.5O6-δ (SFMO). Combining the experimental results with insights from theory showed that the crystal structure is distorted from the ideal cubic simple perovskite

216

Modeling Tools for Solid Oxide Fuel Cell Analysis  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tools for Solid Oxide Fuel Tools for Solid Oxide Fuel Cell Design and Analysis Moe A Khaleel BJ Koeppel, W Liu, K Lai, KP Recknagle, EM Ryan, EV Stephens, X Sun Pacific Northwest National Laboratory Richland, WA 99352 11 th Annual SECA Workshop Pittsburgh, PA July 27-29, 2009 1 PNNL SOFC Modeling Tools SOFC-MP Stack level model for fast analysis of co/counter-flow SOFC stack performance Detailed electrochemistry model Cell level model for the investigation of secondary reactions (degradation/contamination) mechanisms within the tri-layer Component-based design and performance modeling Contact material Interconnect Glass seal 2 SOFC-MP Stack Simulation Code Recent Accomplishments Major memory improvements of 3D model to accommodate 50-cell stacks on LINUX platform. Previously, developed a 2D (or stacked

217

Co-Optimization of Wrought Alumina-Forming Austenitic Stainless Steel Composition Ranges for High-Temperature Creep and Oxidation/Corrosion Resistance  

SciTech Connect (OSTI)

A seriesofcandidatealumina-formingaustenitic(AFA)stainlesssteelsdesignedtoevaluatetheeffectsof variationinAl,C,Cr,Mn,Nb,andNicontentonhigh-temperaturetensileproperties,creep,and oxidation/corrosionresistancewerestudied.ThecompositionsassessedwerebasedonmediumNi (20 25 wt%)andlowNi(12wt%)AFAvariationsstrengthenedprimarilybyMCand/orM23C6 carbide precipitates,andahighNi(32wt%)AFAsuperalloyvariationstrengthenedprimarilyby -Ni3Al intermetallic precipitates.Tensileandcreeppropertiesweremeasuredat650and750/760 1C, oxidation resistance from650to900 1C inairwithwatervaporandsteamenvironments,andsulfidation oxidation resistance inAr 20%H2 20%H2O 5% H2S at550and650 1C. Optimizedcompositionrangesfordifferent use temperaturesrangesbasedontheseevaluationsarepresented.

Brady, Michael P [ORNL] [ORNL; Magee, John H [Carpenter Technology Corporation] [Carpenter Technology Corporation; Yamamoto, Yukinori [ORNL] [ORNL; Helmick, David [Carpenter Technology Corporation] [Carpenter Technology Corporation; Wang, Lu [University of Tennessee, Knoxville (UTK)] [University of Tennessee, Knoxville (UTK)

2014-01-01T23:59:59.000Z

218

Grain boundary depletion and migration during selective oxidation of Cr in a Ni-5Cr binary alloy exposed to high-temperature hydrogenated water  

SciTech Connect (OSTI)

High-resolution microscopy of a high-purity Ni-5Cr alloy exposed to 360C hydrogenated water reveals intergranular selective oxidation of Cr accompanied by local Cr depletion and diffusion-induced grain boundary migration (DIGM). The corrosion-product oxide consists of a porous, interconnected network of Cr2O3 platelets with no further O ingress into the metal ahead. Extensive grain boundary depletion of Cr (to <0.05at.%) is observed typically 20100 nm wide as a result of DIGM and reaching depths of many micrometers beyond the oxidation front.

Schreiber, Daniel K.; Olszta, Matthew J.; Bruemmer, Stephen M.

2014-10-15T23:59:59.000Z

219

Corrosion and Protection of Metallic Interconnects in Solid Oxide Fuel Cells  

SciTech Connect (OSTI)

Energy security and increased concern over environmental protection have spurred a dramatic world-wide growth in research and development of fuel cells, which electrochemically convert incoming fuel into electricity with no or low pollution. Fuel cell technology has become increasingly attractive to a number of sectors, including utility, automotive, and defense industries. Among the various types of fuel cells, solid oxide fuel cells (SOFCs) operate at high temperature (typically 650-1,000 C) and have advantages in terms of high conversion efficiency and the flexibility of using hydrocarbon fuels, in addition to hydrogen. The high temperature operation, however, can lead to increased mass transport and interactions between the surrounding environment and components that are required to be stable during a lifetime of thousands of hours and up to hundreds of thermal cycles. For stacks with relatively low operating temperatures (<800 C), the interconnects that are used to electrically connect a number of cells in series are typically made from cost-effective metals or alloys. The metallic interconnects must demonstrate excellent stability in a very challenging environment during SOFC operation, as they are simultaneously exposed to both an oxidizing (air) environment on the cathode side and a reducing environment (hydrogen or a reformed hydrocarbon fuel) on the anode side. Other challenges include the fact that water vapor is likely to be present in both of these environments, and the fuel is likely to contain impurities, such as sulfides. Since the fuel is usually a reformed hydrocarbon fuel, such as natural gas, coal gas, biogas, gasoline, etc., the interconnect is exposed to a wet carbonaceous environment at the anode side. Finally, the interconnect must be stable towards any adjacent components, such as electrodes, seals and electrical contact materials, with which it is in physical contact.

Yang, Z Gary; Stevenson, Jeffry W.; Singh, Prabhakar

2007-12-09T23:59:59.000Z

220

Method and apparatus for assembling solid oxide fuel cells  

DOE Patents [OSTI]

This invention relates generally to solid oxide fuel power generators and is particularly directed to improvements in the assembly and coupling of solid oxide fuel cell modules. A plurality of jet air tubes are supported and maintained in a spaced matrix array by a positioning/insertion assembly for insertion in respective tubes of a solid oxide fuel cell (SOFC) in the assembly of an SOFC module. The positioning/insertion assembly includes a plurality of generally planar, elongated, linear vanes which are pivotally mounted at each end thereof to a support frame. A rectangular compression assembly of adjustable size is adapted to receive and squeeze a matrix of SOFC tubes so as to compress the inter-tube nickel felt conductive pads which provide series/parallel electrical connection between adjacent SOFCs, with a series of increasingly larger retainer frames used to maintain larger matrices of SOFC tubes in position. Expansion of the SOFC module housing at the high operating temperatures of the SOFC is accommodated by conductive, flexible, resilient expansion, connector bars which provide support and electrical coupling at the top and bottom of the SOFC module housing. 17 figs.

Szreders, B.E.; Campanella, N.

1988-05-11T23:59:59.000Z

Note: This page contains sample records for the topic "high-temperature solid oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Depth profile of oxide volume fractions of Zircaloy-2 in high-temperature steam: An in-situ synchrotron radiation study  

Science Journals Connector (OSTI)

Abstract To study the steam oxidation behavior of Zircaloy-2, a high-energy synchrotron X-ray diffraction technique was applied to perform an in-situ oxidation measurement. The depth profiles of oxide volume fractions were obtained at both 600 and 800C. Multiple layers, including ZrO2 scale, (?+?) Zr matrix with ZrO2 incursions, and (?+?) Zr matrix, were mapped according to the volume fraction of each phase. The volume fractions of these phases were observed to change gradually with different distances to the surface, without a sharp edge distinguishing each of the layers. The ZrO2 consisted of tetragonal and monoclinic crystal structures, which were observed to coexist with different ratios of volume fractions in depth. The higher amount of tetragonal ZrO2 observed in the very inner region of the oxidizing Zircaloy sample indicates that the tetragonal crystal structure is the ab initio phase type, in which new oxide molecules form at the metaloxide interface.

Walid Mohamed; Di Yun; Kun Mo; Michael J. Pellin; Michael C. Billone; Jonathan Almer; Abdellatif M. Yacout

2014-01-01T23:59:59.000Z

222

In Situ Studies of Fuel Oxidation in Solid Oxide Fuel Cells  

Science Journals Connector (OSTI)

In Situ Studies of Fuel Oxidation in Solid Oxide Fuel Cells ... Re-optimization of the Raman signal shows two broad, strong features in the OCV spectrum indicating large amounts of disordered graphite as evidenced by a broad D band (at 1350 cm-1) accompanying the G band (at 1585 cm-1) (Figure 2, right panel). ... intensities from a nonresonant, bond polarizability model optimized for sp2 carbon are also in qual. ...

Michael B. Pomfret; Jeffrey C. Owrutsky; Robert A. Walker

2007-02-13T23:59:59.000Z

223

Solid oxide fuel cell having a glass composite seal  

DOE Patents [OSTI]

A solid oxide fuel cell stack having a plurality of cassettes and a glass composite seal disposed between the sealing surfaces of adjacent cassettes, thereby joining the cassettes and providing a hermetic seal therebetween. The glass composite seal includes an alkaline earth aluminosilicate (AEAS) glass disposed about a viscous glass such that the AEAS glass retains the viscous glass in a predetermined position between the first and second sealing surfaces. The AEAS glass provides geometric stability to the glass composite seal to maintain the proper distance between the adjacent cassettes while the viscous glass provides for a compliant and self-healing seal. The glass composite seal may include fibers, powders, and/or beads of zirconium oxide, aluminum oxide, yttria-stabilized zirconia (YSZ), or mixtures thereof, to enhance the desirable properties of the glass composite seal.

De Rose, Anthony J.; Mukerjee, Subhasish; Haltiner, Jr., Karl Jacob

2013-04-16T23:59:59.000Z

224

Serially connected solid oxide fuel cells having monolithic cores  

DOE Patents [OSTI]

A solid oxide fuel cell for electrochemically combining fuel and oxidant for generating galvanic output, wherein the cell core has an array of cell segments electrically serially connected in the flow direction, each segment consisting of electrolyte walls and interconnect that are substantially devoid of any composite inert materials for support. Instead, the core is monolithic, where each electrolyte wall consists of thin layers of cathode and anode materials sandwiching a thin layer of electrolyte material therebetween. Means direct the fuel to the anode-exposed core passageways and means direct the oxidant to the cathode-exposed core passageways; and means also direct the galvanic output to an exterior circuit. Each layer of the electrolyte composite materials is of the order of 0.002-0.01 cm thick; and each layer of the cathode and anode materials is of the order of 0.002-0.05 cm thick. Between 2 and 50 cell segments may be connected in series.

Herceg, Joseph E. (Naperville, IL)

1987-01-01T23:59:59.000Z

225

High-temperature Pump Monitoring - High-temperature ESP Monitoring...  

Broader source: Energy.gov (indexed) [DOE]

Report Detecting Fractures Using Technology at High Temperatures and Depths - Geothermal Ultrasonic Fracture Imager (GUFI); 2010 Geothermal Technology Program Peer Review Report...

226

Topological analysis of hydrogen oxidation reaction kinetics at Ni/YSZ anode of the solid oxide fuel cell.  

E-Print Network [OSTI]

??The understanding of the mechanisms and kinetics of reactions that occur on the electrodes hold the key to further advances in solid oxide fuel cell (more)

Dar, Yasir Rasool

2011-01-01T23:59:59.000Z

227

Structural and electrochemical characterization of two proton conducting oxide thin films for a microfabricated solid oxide fuel cell  

E-Print Network [OSTI]

The use of proton conducting oxide materials as an electrolyte offers the potential to reduce the operating temperature of a solid oxide fuel cell (SOFC), leading to improved thermal management and material compatibility. ...

Capozzoli, Peter M

2006-01-01T23:59:59.000Z

228

THE IMPACT OF VARIOUS OXIDIZERS ON THE OVERALL PERFORMACE OF A DIRECT FLAME SOLID OXIDE FUEL CELL.  

E-Print Network [OSTI]

??The power output of a direct-flame solid oxide fuel cell (SOFC) was studied using hydrogen (H2) as the fuel for the flame and various oxidizers, (more)

Donadio, Nicholas

2010-01-01T23:59:59.000Z

229

Results Of Recent High Temperature Co-Electrolysis Studies At The Idaho National Laboratory  

SciTech Connect (OSTI)

For the past several years, the Idaho National Laboratory and Ceramatec, Inc. have been studying the feasibility of high temperature solid oxide electrolysis for large-scale, nuclear-powered hydrogen production. Parallel to this effort, the INL and Ceramatec have been researching high temperature solid oxide co-electrolysis of steam/CO2 mixtures to produce syngas, the raw material for synthetic fuels production. When powered by nuclear energy, high temperature co-electrolysis offers a carbon-neutral means of syngas production while consuming CO2. The INL has been conducting experiments to characterize the electrochemical performance of co-electrolysis, as well as validate INL-developed computer models. An inline methanation reactor has also been tested to study direct methane production from co-electrolysis products. Testing to date indicate that high temperature steam electrolysis cells perform equally well under co-electrolysis conditions. Process model predictions compare well with measurements for outlet product compositions. The process appears to be a promising technique for large-scale syngas production.

C. M. Stoots; James E. O'Brien; Joseph J. Hartvigsen

2007-11-01T23:59:59.000Z

230

Combined Theoretical and Experimental Investigation and Design of H2S Tolerant Anode for Solid Oxide Fuel Cells  

SciTech Connect (OSTI)

A solid oxide fuel cell (SOFC) is a high temperature fuel cell and it normally operates in the range of 850 to 1000 C. Coal syngas has been considered for use in SOFC systems to produce electric power, due to its high temperature and high hydrogen and carbon monoxide content. However, coal syngas also has contaminants like carbon dioxide (CO{sub 2}) and hydrogen sulfide (H{sub 2}S). Among these contaminants, H{sub 2}S is detrimental to electrode material in SOFC. Commonly used anode material in SOFC system is nickel-yttria stabilized zirconia (Ni-YSZ). The presence of H{sub 2}S in the hydrogen stream will damage the Ni anode and hinder the performance of SOFC. In the present study, an attempt was made to understand the mechanism of anode (Ni-YSZ) deterioration by H{sub 2}S. The study used computation methods such as quantum chemistry calculations and molecular dynamics to predict the model for anode destruction by H{sub 2}S. This was done using binding energies to predict the thermodynamics and Raman spectroscopy to predict molecular vibrations and surface interactions. On the experimental side, a test stand has been built with the ability to analyze button cells at high temperature under syngas conditions.

Gerardine G. Botte; Damilola Daramola; Madhivanan Muthuvel

2009-01-07T23:59:59.000Z

231

High Temperature Processing Symposium 2014  

E-Print Network [OSTI]

} High temperature recycling operations } Materials sustainability } New furnace technology (including solar) We look forward to seeing you in February 2014. Dr M Akbar Rhamdhani (Chairman HTPS 2014) Prof

Liley, David

232

High temperature corrosion research at the Albany Research Center  

SciTech Connect (OSTI)

The Severe Environment Corrosion and Erosion Research Facility (SECERF) at the Albany Research Center is operational. SECERF consists of 6 modules that share the availability of up to 10 different gases to produce environments for high temperature corrosion and erosion research. Projects to be conducted in the modules include: corrosion sensors for fossil energy systems, thermal gradient effects on high temperature corrosion, the development of sulfidation resistant alloys, determination of the effects of ash on the corrosion of metals and alloys in coal and waste combustion and coal gasification environments, high temperature erosion-corrosion of metals, and molten slag effects on refractories. Results from two areas, the effect of ash deposits on alloy corrosion and thermal gradient effects on the corrosion of metals, will be highlighted. Ash produced in coal gasifiers, coal combustors, and waste combustors, when deposited on metal surfaces, provides sites for corrosion attack and contributes chemical species that participate in the corrosion reaction. Results are presented for the corrosion of 304L stainless steel, that was either uncoated or coated with ash or with ash containing NaCl or Na2SO4, in air-water vapor mixtures at 600 C. The presence of high heat fluxes and temperature gradients in many fossil energy systems creates the need for an understanding of their effects on corrosion and oxidation. Such information would be useful for both improved alloy design and for better translation of isothermal laboratory results to field use. Temperature gradients in a solid oxide result in two changes that modify diffusion within the oxide. The first is when a gradient in point defect concentration is created within the oxide, for example, where more vacancies are expected at a higher temperature. The second change is when the presence of a temperature gradient biases the diffusion jump of an atom. Results of tests are presented for cobalt with metal surface temperatures of approximately 920-950 C in N2 plus 1-10 vol% O2 environments with a heat flux of about 40 kW/m2. Non-equilibrium thermodynamics were used to develop oxidation rate equations in temperature gradients that were combined with point defect information of CoO to predict oxidation rates.

Covino, Bernard S., Jr.; Holcomb, Gordon R.; Russell, James H.; Cramer, Stephen D.; Bullard, Sophie J.; Ziomek-Moroz, Margaret; Matthes, Steven A.; Chinn, R.E.

2002-01-01T23:59:59.000Z

233

Microstructural Degradation of Ni-YSZ Anodes for Solid Oxide Fuel  

E-Print Network [OSTI]

Microstructural Degradation of Ni- YSZ Anodes for Solid Oxide Fuel Cells Karl Thydén Risø-PhD-32(EN 2008 #12;Author: Karl Thydén Title: Microstructural Degradation of Ni-YSZ Anodes for Solid Oxide Fuel Cells Department: Fuel Cells and Solid State Chemistry Department Risø-PhD-32(EN) March 2008 This thesis

234

3D CFD ELECTROCHEMICAL AND HEAT TRANSFER MODEL OF AN INTERNALLY MANIFOLDED SOLID OXIDE ELECTROLYSIS CELL  

SciTech Connect (OSTI)

A three-dimensional computational fluid dynamics (CFD) electrochemical model has been created to model high-temperature electrolysis cell performance and steam electrolysis in an internally manifolded planar solid oxide electrolysis cell (SOEC) stack. This design is being evaluated at the Idaho National Laboratory for hydrogen production from nuclear power and process heat. Mass, momentum, energy, and species conservation and transport are provided via the core features of the commercial CFD code FLUENT. A solid-oxide fuel cell (SOFC) model adds the electrochemical reactions and loss mechanisms and computation of the electric field throughout the cell. The FLUENT SOFC user-defined subroutine was modified for this work to allow for operation in the SOEC mode. Model results provide detailed profiles of temperature, operating potential, steam-electrode gas composition, oxygen-electrode gas composition, current density and hydrogen production over a range of stack operating conditions. Single-cell and five-cell results will be presented. Flow distribution through both models is discussed. Flow enters from the bottom, distributes through the inlet plenum, flows across the cells, gathers in the outlet plenum and flows downward making an upside-down ''U'' shaped flow pattern. Flow and concentration variations exist downstream of the inlet holes. Predicted mean outlet hydrogen and steam concentrations vary linearly with current density, as expected. Effects of variations in operating temperature, gas flow rate, oxygen-electrode and steam-electrode current density, and contact resistance from the base case are presented. Contour plots of local electrolyte temperature, current density, and Nernst potential indicate the effects of heat transfer, reaction cooling/heating, and change in local gas composition. Results are discussed for using this design in the electrolysis mode. Discussion of thermal neutral voltage, enthalpy of reaction, hydrogen production, cell thermal efficiency, cell electrical efficiency, and Gibbs free energy are discussed and reported herein.

Grant L. Hawkes; James E. O'Brien; Greg Tao

2011-11-01T23:59:59.000Z

235

Advantages of Microwave Sintering in Manufacturing of Anode Support Solid Oxide Fuel Cell  

E-Print Network [OSTI]

and facile method in the manufacturing of anode support solid oxide fuel cell(1). Two anode support SOFCsPage 5-211 Advantages of Microwave Sintering in Manufacturing of Anode Support Solid Oxide Fuel oxide fuel cell (SOFC, hereafter) has been identified as an attractive technique in the recent few

Kasagi, Nobuhide

236

Study on Degradation of Solid Oxide Fuel Cell With Pure Ni Anode Zhenjun Jiaoa  

E-Print Network [OSTI]

Study on Degradation of Solid Oxide Fuel Cell With Pure Ni Anode Zhenjun Jiaoa , Naoki Shikazonoa Solid oxide fuel cell (SOFC) has attracted more and more attentions in the last few decades hydrogen as a fuel and pure oxygen as an oxidant. Anode-reference static current method, with a current

Kasagi, Nobuhide

237

Nickel Phase Wettability and YSZ Redox Fracture Percolation in Solid Oxide Fuel Cell Anodes  

E-Print Network [OSTI]

Nickel Phase Wettability and YSZ Redox Fracture Percolation in Solid Oxide Fuel Cell Anodes Alex and Aerospace Engineering Background Solid oxide fuel cells lose mechanical stability and functionality when oxidize (redox reaction) instead of the hydrogen fuel [2]. This conversion to NiO exerts a volumetric

Petta, Jason

238

FUEL CELLS SOLID OXIDE FUEL CELLS | Internal and External Reformation  

Science Journals Connector (OSTI)

Three basic concepts of solid oxide fuel cell (SOFC) systems operating on hydrocarbon fuels, with external, internal, and partial prereforming, respectively, are presented and discussed. Internal reforming of methane is advantageously used for additional cooling of the SOFC stack, thus increasing system efficiency. Basic thermodynamics, catalysis, and kinetics of the methane steam reforming process are presented. Examples of SOFC stacks operating on internal reforming of methane and simulated partial prereforming of mine gas and natural gas are discussed. The latter is used to illustrate the effect of internal methane reforming on heat management in SOFC stacks.

L.G.J. de Haart; R. Peters

2009-01-01T23:59:59.000Z

239

Corner heating in rectangular solid oxide electrochemical cell generators  

DOE Patents [OSTI]

Disclosed is an improvement in a solid oxide electrochemical cell generator 1 having a rectangular design with four sides that meet at corners, and containing multiplicity of electrically connected fuel cells 11, where a fuel gas is passed over one side of said cells and an oxygen containing gas is passed into said cells, and said fuel is burned to form heat, electricity, and an exhaust gas. The improvement comprises passing the exhaust gases over the multiplicity of cells 11 in such a way that more of the heat in said exhaust gases flows at the corners of the generator, such as through channels 19.

Reichner, Philip (Plum Boro, PA)

1989-01-01T23:59:59.000Z

240

ELECTRODE DEVELOPMENT FOR REVERSIBLE SOLID OXIDE FUEL CELLS  

SciTech Connect (OSTI)

The reversibility of the electrodes for a solid oxide fuel cell with an yttria-stabilized zirconia (YSZ) electrolyte was examined using electrochemical impedance spectroscopy and current interrupt methods. The fuel electrodes were nickel/zirconia cermet and lanthanum-doped strontium titanate/doped ceria composites. The air electrodes were lanthanum strontium ferrite (LSF) and lanthanum strontium copper ferrite (LSCuF). Under the experimental conditions studied all four electrodes were able to operate in both the fuel cell and electrolyzer modes. The titanate/ceria fuel electrode performed substantially better in the electrolyzer mode than state-of-art Ni-YSZ. Moreover, it showed slightly higher activity for water electrolysis as compared to hydrogen oxidation. Air electrodes were less active in the electrolyzer than fuel cell modes. LSF typically provided higher overpotential losses in both modes than copper-substituted LSF. Changes in the defect chemistry of electrode materials under cathodic and anodic polarization are discussed.

Marina, Olga A.; Coffey, Greg W.; Pederson, Larry R.; Rieke, Peter C.; Thomsen, Ed C.; Williams, Mark C.

2004-08-06T23:59:59.000Z

Note: This page contains sample records for the topic "high-temperature solid oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Sintering behavior of lanthanide-containing glass-ceramic sealants for solid oxide fuel cells  

SciTech Connect (OSTI)

This article reports on the influence of different lanthanides (La, Nd, Gd and Yb) on sintering behavior of alkaline-earth aluminosilicate glass-ceramics sealants for their application in solid oxide fuel cells (SOFC). All the glasses have been prepared by melt-quench technique. The in situ follow up of sintering behavior of glass powders has been done by high temperature - environmental scanning electron microscope (HT-ESEM) and hot-stage microscope (HSM) while the crystalline phase evolution and assemblage has been analyzed by x-ray diffraction (XRD) and scanning electron microscopy (SEM). All the glass compositions exhibit a glass-in-glass phase separation followed by two stage sintering resulting in well sintered glass powder compacts after heat treatment at 850 C for 1 h. Diopside (CaMgSi{sub 2}O{sub 6}) based phases constituted the major crystalline part in glass-ceramics followed by some minor phases. The increase in lanthanide content in glasses suppressed their tendency towards devitrification, thus, resulting in glass-ceramics with high amount of residual glassy phase (50-96 wt.%) which is expected to facilitate their self-healing behavior during SOFC operation. The electrical conductivity of the investigated glass-ceramics varied between (1.19 and 7.33) x 10{sup -7} S cm{sup -1} (750-800 C), and depended on the ionic field strength of lanthanide cations. Further experimentation with respect to the long term thermal and chemical stability of residual glassy phase under SOFC operation conditions along with high temperature viscosity measurements will be required in order to elucidate the potential of these glass-ceramics as self-healing sealants.

Goel, Ashutosh; Reddy, Allu Amarnath; Pascual, Maria J.; Gremillard, Laurent; Malchere, Annie; Ferreira, Jose M.

2012-05-01T23:59:59.000Z

242

High Temperature | Open Energy Information  

Open Energy Info (EERE)

Temperature Temperature Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Print PDF Sanyal Temperature Classification: High Temperature Dictionary.png High Temperature: No definition has been provided for this term. Add a Definition Sanyal Temp Classification This temperature scheme was developed by Sanyal in 2005 at the request of DOE and GEA, as reported in Classification of Geothermal Systems: A Possible Scheme. Extremely Low Temperature Very Low Temperature Low Temperature Moderate Temperature High Temperature Ultra High Temperature Steam Field Reservoir fluid between 230°C and 300°C is considered by Sanyal to be "high temperature." "Above a temperature level of 230°C, the reservoir would be expected to become two-phase at some point during exploitation. The next higher

243

Solid State Energy Conversion Alliance (SECA) Solid Oxide Fuel Cell Program  

SciTech Connect (OSTI)

This report summarizes the work performed for Phase I (October 2001 - August 2006) under Cooperative Agreement DE-FC26-01NT41245 for the U. S. Department of Energy, National Energy Technology Laboratory (DOE/NETL) entitled 'Solid State Energy Conversion Alliance (SECA) Solid Oxide Fuel Cell Program'. The program focuses on the development of a low-cost, high-performance 3-to-10-kW solid oxide fuel cell (SOFC) system suitable for a broad spectrum of power-generation applications. During Phase I of the program significant progress has been made in the area of SOFC technology. A high-efficiency low-cost system was designed and supporting technology developed such as fuel processing, controls, thermal management, and power electronics. Phase I culminated in the successful demonstration of a prototype system that achieved a peak efficiency of 41%, a high-volume cost of $724/kW, a peak power of 5.4 kW, and a degradation rate of 1.8% per 500 hours. . An improved prototype system was designed, assembled, and delivered to DOE/NETL at the end of the program. This prototype achieved an extraordinary peak efficiency of 49.6%.

Nguyen Minh

2006-07-31T23:59:59.000Z

244

Santa Clara County Planar Solid Oxide Fuel Cell Demonstration Project  

SciTech Connect (OSTI)

The Santa Clara County Planar Solid Oxide Fuel Cell (PSOFC) project demonstrated the technical viability of pre-commercial PSOFC technology at the County 911 Communications headquarters, as well as the input fuel flexibility of the PSOFC. PSOFC operation was demonstrated on natural gas and denatured ethanol. The Santa Clara County Planar Solid Oxide Fuel Cell (PSOFC) project goals were to acquire, site, and demonstrate the technical viability of a pre-commercial PSOFC technology at the County 911 Communications headquarters. Additional goals included educating local permit approval authorities, and other governmental entities about PSOFC technology, existing fuel cell standards and specific code requirements. The project demonstrated the Bloom Energy (BE) PSOFC technology in grid parallel mode, delivering a minimum 15 kW over 8760 operational hours. The PSOFC system demonstrated greater than 81% electricity availability and 41% electrical efficiency (LHV net AC), providing reliable, stable power to a critical, sensitive 911 communications system that serves geographical boundaries of the entire Santa Clara County. The project also demonstrated input fuel flexibility. BE developed and demonstrated the capability to run its prototype PSOFC system on ethanol. BE designed the hardware necessary to deliver ethanol into its existing PSOFC system. Operational parameters were determined for running the system on ethanol, natural gas (NG), and a combination of both. Required modeling was performed to determine viable operational regimes and regimes where coking could occur.

Fred Mitlitsky; Sara Mulhauser; David Chien; Deepak Shukla; David Weingaertner

2009-11-14T23:59:59.000Z

245

LG Solid Oxide Fuel Cell (SOFC) Model Development  

SciTech Connect (OSTI)

This report presents a summary of the work performed by LG Fuel Cell Systems Inc. during the project LG Solid Oxide Fuel Cell (SOFC) Model Development (DOE Award Number: DE-FE0000773) which commenced on October 1, 2009 and was completed on March 31, 2013. The aim of this project is for LG Fuel Cell Systems Inc. (formerly known as Rolls-Royce Fuel Cell Systems (US) Inc.) (?LGFCS?) to develop a multi-physics solid oxide fuel cell (SOFC) computer code (MPC) for performance calculations of the LGFCS fuel cell structure to support fuel cell product design and development. A summary of the initial stages of the project is provided which describes the MPC requirements that were developed and the selection of a candidate code, STAR-CCM+ (CD-adapco). This is followed by a detailed description of the subsequent work program including code enhancement and model verification and validation activities. Details of the code enhancements that were implemented to facilitate MPC SOFC simulations are provided along with a description of the models that were built using the MPC and validated against experimental data. The modeling work described in this report represents a level of calculation detail that has not been previously available within LGFCS.

Haberman, Ben; Martinez-Baca, Carlos; Rush, Greg

2013-03-31T23:59:59.000Z

246

Innovative Self-Healing Seals for Solid Oxide Fuel Cells (SOFCs) University of Cincinnati  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Innovative Self-Healing Seals for Solid Innovative Self-Healing Seals for Solid Oxide Fuel Cells (SOFCs)-University of Cincinnati Background The mission of the U.S. Department of Energy (DOE) National Energy Technology Laboratory (NETL) is to advance energy options to fuel our economy, strengthen our security, and improve our environment. With the Solid State Energy Conversion Alliance (SECA), NETL is leading the research, development, and demonstration of solid oxide

247

The Performance of Planar Solid Oxide Fuel Cells using Hydrogen-depleted Coal Syngas.  

E-Print Network [OSTI]

??Since solid oxide fuel cells can operate on fuel containing both hydrogen and carbon monoxide, it may prove possible to remove hydrogen from syngas streams (more)

Burnette, David D.

2007-01-01T23:59:59.000Z

248

Model-based Interpretation of the Performance and Degradation of Reformate Fueled Solid Oxide Fuel Cells.  

E-Print Network [OSTI]

??Solid oxide fuel cells offer great prospects for the sustainable, clean and safe conversion of various fuels into electrical energy. In this thesis, the performance-determining (more)

Kromp, Alexander

2013-01-01T23:59:59.000Z

249

Mechanochemically synthesized nanomaterials for intermediate temperature solid oxide fuel cell membranes.  

E-Print Network [OSTI]

??[Truncated abstract] In this dissertation an investigation into the utility of mechanochemically synthesized nanopowders for intermediate temperature solid oxide fuel cell components is reported. The (more)

Hos, James Pieter

2005-01-01T23:59:59.000Z

250

Microstructure-based solid oxide fuel cell seal design using statistical mechanics.  

E-Print Network [OSTI]

??Solid oxide fuel cells (SOFC) in a flat-plate configuration require a hermetic seal between the fuel and air sides of the electrodes, and this seal (more)

Milhans, Jacqueline Linda

2010-01-01T23:59:59.000Z

251

E-Print Network 3.0 - anode solid oxide Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

solid oxide fuel cells (SOFCs) exhibit a number of attractive features... of anode and cathode materials for propane oxidation was tested in both flow- through and half... but not...

252

Cryogenic deformation of high temperature superconductive composite structures  

DOE Patents [OSTI]

An improvement in a process of preparing a composite high temperature oxide superconductive wire is provided and involves conducting at least one cross-sectional reduction step in the processing preparation of the wire at sub-ambient temperatures.

Roberts, Peter R. (Groton, MA); Michels, William (Brookline, MA); Bingert, John F. (Jemez Springs, NM)

2001-01-01T23:59:59.000Z

253

Three Dimensional CFD Model of a Planar Solid Oxide Electrolysis Cell for Co-Electrolysis of Steam and Carbon-Dioxide  

SciTech Connect (OSTI)

A three-dimensional computational fluid dynamics (CFD) model has been created to model high temperature co-electrolysis of steam and carbon dioxide in a planar solid oxide electrolyzer (SOE). A research program is under way at the Idaho National Laboratory (INL) to simultaneously address the research and scale-up issues associated with the implementation of planar solid-oxide electrolysis cell technology for syn-gas production from CO2 and steam. Various runs have been performed under different run conditions to help assess the performance of the SOE. An experimental study is also being performed at the INL to assess the SOE. Model results provide detailed profiles of temperature, Nernst potential, operating potential, anode-side gas composition, cathode-side gas composition, current density and syn-gas production over a range of stack operating conditions. Typical results of current density versus cell potential, cell current versus H2 and CO production, temperature, and voltage potential are all presented within this paper. Plots of mole fraction of CO2, CO, H2, H2O, O2, are presented. Currently there is strong interest in the large-scale production of syn-gas from CO2 and steam to be reformed into a usable transportation fuel. This process takes the carbon-neutral approach where the amount of CO2 in the atmosphere does not increase. Consequently, there is a high level of interest in production of syn-gas from CO2 and steam electrolysis. Worldwide, the demand for light hydrocarbon fuels like gasoline and diesel oil is increasing. To satisfy this demand, oil companies have begun to utilize oil deposits of lower hydrogen. In the mean time, with the price of oil currently over $70 / barrel, synthetically-derived hydrocarbon fuels (synfuels) have become economical. Synfuels are typically produced from syngas hydrogen (H2) and carbon monoxide (CO) -- using the Fischer-Tropsch process, discovered by Germany before World War II. South Africa has used synfuels to power a significant number of their buses, trucks, and taxicabs. The Idaho National Laboratory (INL), in conjunction with Ceramatec Inc. (Salt Lake City, USA) has been researching for several years the use of solid-oxide fuel cell technology to electrolyze steam for large-scale nuclear-powered hydrogen production. Now, an experimental research project is underway at the INL to investigate the feasibility of producing syngas by simultaneously electrolyzing at high-temperature steam and carbon dioxide (CO2) using solid oxide fuel cell technology. High-temperature nuclear reactors have the potential for substantially increasing the efficiency of syn-gas production from CO2 and water, with no consumption of fossil fuels, and no production of greenhouse gases. Thermal CO2-splitting and water splitting for syn-gas production can be accomplished via high-temperature electrolysis or thermochemical processes, using high-temperature nuclear process heat. In order to achieve competitive efficiencies, both processes require high-temperature operation (~850C). High-temperature electrolytic CO2 and water splitting supported by nuclear process heat and electricity has the potential to produce syn-gas with an overall system efficiency near those of the thermochemical processes. Specifically, a high-temperature advanced nuclear reactor coupled with a high-efficiency high-temperature electrolyzer could achieve a competitive thermal-to-syn-gas conversion efficiency of 45 to

G. Hawkes; J. O'Brien; C. Stoots; S. Herring; R. Jones

2006-11-01T23:59:59.000Z

254

Serially connected solid oxide fuel cells having monolithic cores  

DOE Patents [OSTI]

Disclosed is a solid oxide fuel cell for electrochemically combining fuel and oxidant for generating galvanic output. The cell core has an array of cell segments electrically serially connected in the flow direction, each segment consisting of electrolyte walls and interconnect that are substantially devoid of any composite inert materials for support. Instead, the core is monolithic, where each electrolyte wall consists of thin layers of cathode and anode materials sandwiching a thin layer of electrolyte material therebetween. Means direct the fuel to the anode-exposed core passageways and means direct the oxidant to the cathode-exposed core passageways; and means also direct the galvanic output to an exterior circuit. Each layer of the electrolyte composite materials is of the order of 0.002 to 0.01 cm thick; and each layer of the cathode and anode materials is of the order of 0.002 to 0.05 cm thick. Between 2 and 50 cell segments may be connected in series.

Herceg, J.E.

1985-05-20T23:59:59.000Z

255

High Temperature coatings based on {beta}-NiAI  

SciTech Connect (OSTI)

High temperature alloys are reviewed, focusing on current superalloys and their coatings. The synthesis, characerization, and oxidation performance of a NiAlTiB{sub 2} composite are explained. A novel coating process for MoNiAl alloys for improved oxidation performance is examined. The cyclic oxidation performance of coated and uncoated MoNiAl alloys is discussed.

Severs, Kevin

2012-07-10T23:59:59.000Z

256

Philosophy 26 High Temperature Superconductivity  

E-Print Network [OSTI]

is the ratio of voltage to current. The resistance of a material tells us how a low resistance, and they are therefore good conductors; other materials, likePhilosophy 26 High Temperature Superconductivity By Ohm's Law, resistance

Callender, Craig

257

High temperature chemistry of advanced heavy water reactor fuel  

Science Journals Connector (OSTI)

The Department of Atomic Energy envisages the use of thoria based fuel in the third phase of nuclear power generation. The fuel will consist of solid solution of thorium-uranium and thorium-plutonium in the form of their oxides. The former will contain 2.5 mole % UO2 while the latter about 4 mole % PuO2. Since no other country in the world has used such fuel, no data is available on its behavior under long-term irradiation. The high temperature chemistry of fuel can however provide some insight into the behavior of such fuel during irradiation and could be of considerable help in the assessment of its long-term integrity. The high temperature chemistry of the fuel essentially involves the measurement of thermodynamic properties of the compounds formed in the multi-component systems comprising the fuel matrix, the fission products and the clad. The physical integrity of the fuel under long-term irradiation can be predicted with the help of basic thermodynamic data such as the Gibbs energy of formation of various compounds and their thermophysical properties such as thermal conductivity and coefficient of thermal expansion derived from experimental measurements. The paper highlights the measurements made on some typical systems relevant to the prediction of thoria based fuel behaviour during long-term irradiation. The experimental problems faced in such measurements are also discussed.

S.R. Dharwadkar

2002-01-01T23:59:59.000Z

258

Degradation mechanisms in La?.?Sr?.?CoO? as oxygen electrode bond layer in solid oxide electrolytic cells (SOECs)  

E-Print Network [OSTI]

High temperature steam electrolysis is an efficient process and a promising technology to convert electricity and steam or a mixture of steam and CO?, into H? or syn-gas (H?2 + CO) respectively. It is carried out in Solid ...

Sharma, Vivek Inder

2009-01-01T23:59:59.000Z

259

Proton diffusion pathways and rates in Y-doped BaZrO3 solid oxide electrolyte from quantum mechanics  

E-Print Network [OSTI]

solid oxide fuel cells based on yttria-stabilized zirconia. In addition, doped perovskite oxides oftenProton diffusion pathways and rates in Y-doped BaZrO3 solid oxide electrolyte from quantum solid oxide proton conductors the principal fea- tures of the proton transport mechanism are generally

Goddard III, William A.

260

Thermodynamic Modeling and Optimum Design Strategy of a Generic Solid Oxide Fuel Cell-Based Hybrid System  

Science Journals Connector (OSTI)

(5, 17, 18) Here, we consider an indirectly combined system of a SOFC and a generic heat engine cycle, which is different from the coupling of high temperature fuel cells with Carnot heat engines, indirectly coupled solid oxide fuel cell/gas turbine hybrid power plants, or integration of a SOFC with a Stirling engine,(19-23) because it can be used to expound the general performance characteristics of a SOFC-based hybrid system, investigate the key irreversible losses of the hybrid system, and obtain the optimum criteria of the main performance parameters. ... The integration of a Stirling engine instead of the microturbine is a second possibility and the object of an ongoing study. ...

Xiuqin Zhang; Juncheng Guo; Jincan Chen

2012-07-09T23:59:59.000Z

Note: This page contains sample records for the topic "high-temperature solid oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Durability Prediction of Solid Oxide Fuel Cell Anode Material under Thermo-Mechanical and Fuel Gas Contaminants Effects  

SciTech Connect (OSTI)

Solid Oxide Fuel Cells (SOFCs) operate under harsh environments, which cause deterioration of anode material properties and service life. In addition to electrochemical performance, structural integrity of the SOFC anode is essential for successful long-term operation. The SOFC anode is subjected to stresses at high temperature, thermal/redox cycles, and fuel gas contaminants effects during long-term operation. These mechanisms can alter the anode microstructure and affect its electrochemical and structural properties. In this research, anode material degradation mechanisms are briefly reviewed and an anode material durability model is developed and implemented in finite element analysis. The model takes into account thermo-mechanical and fuel gas contaminants degradation mechanisms for prediction of long-term structural integrity of the SOFC anode. The proposed model is validated experimentally using a NexTech ProbostatTM SOFC button cell test apparatus integrated with a Sagnac optical setup for simultaneously measuring electrochemical performance and in-situ anode surface deformation.

Iqbal, Gulfam; Guo, Hua; Kang , Bruce S.; Marina, Olga A.

2011-01-10T23:59:59.000Z

262

Heterogeneous electrocatalysis in porous cathodes of solid oxide fuel cells  

E-Print Network [OSTI]

A general physics-based model is developed for heterogeneous electrocatalysis in porous electrodes and used to predict and interpret the impedance of solid oxide fuel cells. This model describes the coupled processes of oxygen gas dissociative adsorption and surface diffusion of the oxygen intermediate to the triple phase boundary, where charge transfer occurs. The model accurately captures the Gerischer-like frequency dependence and the oxygen partial pressure dependence of the impedance of symmetric cathode cells. Digital image analysis of the microstructure of the cathode functional layer in four different cells directly confirms the predicted connection between geometrical properties and the impedance response. As in classical catalysis, the electrocatalytic activity is controlled by an effective Thiele modulus, which is the ratio of the surface diffusion length (mean distance from an adsorption site to the triple phase boundary) to the surface boundary layer length (square root of surface diffusivity div...

Fu, Y; Bertei, A; Qi, C; Mohanram, A; Pietras, J D; Bazant, M Z

2014-01-01T23:59:59.000Z

263

FUEL CELLS SOLID OXIDE FUEL CELLS | Gas Distribution  

Science Journals Connector (OSTI)

A uniform distribution of the reactants over the total available electrode surfaces in solid oxide fuel cells (SOFCs) is a prerequisite for the proper operation of the fuel cell. The gas distribution plays a dominant role not only in the current density distribution but also in the temperature distribution over the cell areas and in the stack and modules. Several transport mechanisms for mass transport occurring in the SOFC are introduced and discussed. General flow configurations and structures for the gas distribution at three different levels, i.e., stack/module, cell/tube, and electrode/electrolyte, are discussed for both tubular and planar type cells and illustrated with examples of concentration and temperature profiles.

L.G.J. de Haart; M. Spiller

2009-01-01T23:59:59.000Z

264

Innovative Self-Healing Seals for Solid Oxide Fuel Cells (SOFC)  

SciTech Connect (OSTI)

Solid oxide fuel cell (SOFC) technology is critical to several national initiatives. Solid State Energy Conversion Alliance (SECA) addresses the technology needs through its comprehensive programs on SOFC. A reliable and cost-effective seal that works at high temperatures is essential to the long-term performance of the SOFC for 40,000 hours at 800°C. Consequently, seals remain an area of highest priority for the SECA program and its industry teams. An innovative concept based on self-healing glasses was advanced and successfully demonstrated through seal tests for 3000 hours and 300 thermal cycles to minimize internal stresses under both steady state and thermal transients for making reliable seals for the SECA program. The self-healing concept requires glasses with low viscosity at the SOFC operating temperature of 800°C but this requirement may lead to excessive flow of the glass in areas forming the seal. To address this challenge, a modification to glass properties by addition of particulate fillers is pursued in the project. The underlying idea is that a non-reactive ceramic particulate filler is expected to form glass-ceramic composite and increase the seal viscosity thereby increasing the creep resistance of the glass-composite seals under load. The objectives of the program are to select appropriate filler materials for making glass-composite, fabricate glass-composites, measure thermal expansion behaviors, and determine stability of the glass-composites in air and fuel environments of a SOFC. Self-healing glass-YSZ composites are further developed and tested over a longer time periods under conditions typical of the SOFCs to validate the long-term stability up to 2000 hours. The new concepts of glass-composite seals, developed and nurtured in this program, are expected to be cost-effective as these are based on conventional processing approaches and use of the inexpensive materials.

Raj Singh

2012-06-30T23:59:59.000Z

265

RECENT ADVANCES IN HIGH TEMPERATURE ELECTROLYSIS AT IDAHO NATIONAL LABORATORY: STACK TESTS  

SciTech Connect (OSTI)

High temperature steam electrolysis is a promising technology for efficient sustainable large-scale hydrogen production. Solid oxide electrolysis cells (SOECs) are able to utilize high temperature heat and electric power from advanced high-temperature nuclear reactors or renewable sources to generate carbon-free hydrogen at large scale. However, long term durability of SOECs needs to be improved significantly before commercialization of this technology. A degradation rate of 1%/khr or lower is proposed as a threshold value for commercialization of this technology. Solid oxide electrolysis stack tests have been conducted at Idaho National Laboratory to demonstrate recent improvements in long-term durability of SOECs. Electrolytesupported and electrode-supported SOEC stacks were provided by Ceramatec Inc., Materials and Systems Research Inc. (MSRI), and Saint Gobain Advanced Materials (St. Gobain), respectively for these tests. Long-term durability tests were generally operated for a duration of 1000 hours or more. Stack tests based on technology developed at Ceramatec and MSRI have shown significant improvement in durability in the electrolysis mode. Long-term degradation rates of 3.2%/khr and 4.6%/khr were observed for MSRI and Ceramatec stacks, respectively. One recent Ceramatec stack even showed negative degradation (performance improvement) over 1900 hours of operation. A three-cell short stack provided by St. Gobain, however, showed rapid degradation in the electrolysis mode. Improvements on electrode materials, interconnect coatings, and electrolyteelectrode interface microstructures contribute to better durability of SOEC stacks.

X, Zhang; J. E. O'Brien; R. C. O'Brien; J. J. Hartvigsen; G. Tao; N. Petigny

2012-07-01T23:59:59.000Z

266

Hydrogen Oxidation Reaction at the Ni/YSZ Anode of Solid Oxide Fuel Cells from First Principles  

Science Journals Connector (OSTI)

By means of abinitio simulations we here provide a comprehensive scenario for hydrogen oxidation reactions at the Ni/zirconia anode of solid oxide fuel cells. The simulations have also revealed that in the presence of water chemisorbed at the oxide surface, the active region for H oxidation actually extends beyond the metal/zirconia interface unraveling the role of water partial pressure in the decrease of the polarization resistance observed experimentally.

Clotilde S. Cucinotta; Marco Bernasconi; Michele Parrinello

2011-11-08T23:59:59.000Z

267

Solid-Oxide Fuel Cell Stack System Identification and Control A Systematic Recipe  

E-Print Network [OSTI]

Solid-Oxide Fuel Cell Stack System Identification and Control A Systematic Recipe Borhan M of Engineering Colorado School of Mines, Golden, CO 80401 USA Solid-Oxide Fuel Cell (MIMO) Systems Are... fuel. Sanandaji, Tyrone L. Vincent, Andrew Colclasure, and Robert J. Kee Colorado Fuel Cell Center (CFCC) Division

Sanandaji, Borhan M.

268

Atomistic simulations of surface segregation of defects in solid oxide electrolytes  

E-Print Network [OSTI]

) are widely used electrolyte materials for solid oxide fuel cells (SOFCs) due to their high ionic conductivAtomistic simulations of surface segregation of defects in solid oxide electrolytes Hark B. Lee is important in fuel cell applications because it can affect the near-surface chemical reactions and ionic

Cai, Wei

269

Advanced Materials for Reversible Solid Oxide Fuel Cell (RSOFC), Dual Mode Operation with Low  

E-Print Network [OSTI]

Advanced Materials for Reversible Solid Oxide Fuel Cell (RSOFC), Dual Mode Operation with Low, Director Product Development & Federal Programs #12;Project Background f Reversible Solid Oxide Fuel Cells:Water The VPS Storage f Wind Fuel Cell / f Solar Electrolyzer Continuous SOFC Intermittent Power Power

270

Solid Oxide Fuel Cell Auxiliary Power Units for Long-Haul Trucks  

E-Print Network [OSTI]

Solid Oxide Fuel Cell Auxiliary Power Units for Long-Haul Trucks Modeling and Control Mohammad and maintenance of the truck engine. While still in the research phase, Solid Oxide Fuel Cell (SOFC) based APUs are used to provide this power, rather than idling the engine, because they use less fuel and reduce wear

271

Anode supported single chamber solid oxide fuel cells operating in exhaust gases of thermal engine  

E-Print Network [OSTI]

Anode supported single chamber solid oxide fuel cells operating in exhaust gases of thermal engine fuel cells are usually described as devices able to convert chemical energy into electrical energy. Conventional solid oxide fuel cells are separated into two compartments containing each electrode split

Boyer, Edmond

272

NETL: News Release - Solid Oxide Fuel Cell Reaches One Year of Operations  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

January 31, 2000 January 31, 2000 Solid Oxide Fuel Cell Reaches One Year of Operations Netherlands Test Boosts Confidence for Commercial Introduction by 2004 An experimental all solid-state fuel cell - the possible prototype for a future "combustion-less" power plant - has passed a key milestone in a joint public-private development effort. Schematic Diagram of Tubular Solid Oxide Fuel Cell The Siemens Westinghouse solid oxide fuel cell is a tubular arrangement of concentric ceramic electrodes and a solid-state electrolyte. Siemens-Westinghouse Power Corp., headquartered in Orlando, FL, announced this week that its 100-kilowatt solid oxide fuel cell power system, the world's largest, has completed one year of total operating time, the longest any fuel cell of this type and size has run. The milestone marked

273

Vortices in high-temperature superconductors  

Science Journals Connector (OSTI)

With the high-temperature superconductors a qualitatively new regime in the phenomenology of type-II superconductivity can be accessed. The key elements governing the statistical mechanics and the dynamics of the vortex system are (dynamic) thermal and quantum fluctuations and (static) quenched disorder. The importance of these three sources of disorder can be quantified by the Ginzburg number Gi=(TcHc2??3)22, the quantum resistance Qu=(e2?)(?n??), and the critical current-density ratio jcjo, with jc and jo denoting the depinning and depairing current densities, respectively (?n is the normal-state resistivity and ?2=mMsuperconductors, leading to interesting effects such as the melting of the vortex lattice, the creation of new vortex-liquid phases, and the appearance of macroscopic quantum phenomena. Introducing quenched disorder into the system turns the Abrikosov lattice into a vortex glass, whereas the vortex liquid remains a liquid. The terms "glass" and "liquid" are defined in a dynamic sense, with a sublinear response ?=?E?j|j?0 characterizing the truly superconducting vortex glass and a finite resistivity ?(j?0)>0 being the signature of the liquid phase. The smallness of jcjo allows one to discuss the influence of quenched disorder in terms of the weak collective pinning theory. Supplementing the traditional theory of weak collective pinning to take into account thermal and quantum fluctuations, as well as the new scaling concepts for elastic media subject to a random potential, this modern version of the weak collective pinning theory consistently accounts for a large number of novel phenomena, such as the broad resistive transition, thermally assisted flux flow, giant and quantum creep, and the glassiness of the solid state. The strong layering of the oxides introduces additional new features into the thermodynamic phase diagram, such as a layer decoupling transition, and modifies the mechanism of pinning and creep in various ways. The presence of strong (correlated) disorder in the form of twin boundaries or columnar defects not only is technologically relevant but also provides the framework for the physical realization of novel thermodynamic phases such as the Bose glass. On a macroscopic scale the vortex system exhibits self-organized criticality, with both the spatial and the temporal scale accessible to experimental investigations.

G. Blatter; M. V. Feigel'man; V. B. Geshkenbein; A. I. Larkin; V. M. Vinokur

1994-10-01T23:59:59.000Z

274

Selective Aerobic Oxidation of 5-Hydroxymethylfurfural in Water Over Solid Ruthenium Hydroxide Catalysts with Magnesium-Based Supports  

Science Journals Connector (OSTI)

Solid catalyst systems comprised of ruthenium hydroxide supported on magnesium-based carrier materials (spinel, magnesium oxide and hydrotalcite) were investigated for the selective, aqueous aerobic oxidation of ...

Yury Y. Gorbanev; Sren Kegns; Anders Riisager

2011-12-01T23:59:59.000Z

275

High temperature methods for forming oxidizer fuel  

DOE Patents [OSTI]

A method of treating a formation fluid includes providing formation fluid from a subsurface in situ heat treatment process. The formation fluid is separated to produce a liquid stream and a first gas stream. The first gas stream includes carbon dioxide, hydrogen sulfide, hydrocarbons, hydrogen or mixtures thereof. Molecular oxygen is separated from air to form a molecular oxygen stream comprising molecular oxygen. The first gas stream is combined with the molecular oxygen stream to form a combined stream comprising molecular oxygen and the first gas stream. The combined stream is provided to one or more downhole burners.

Bravo, Jose Luis (Houston, TX)

2011-01-11T23:59:59.000Z

276

High Temperature Optical Gas Sensing  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Optical Gas Sensing Optical Gas Sensing Opportunity Research is active on optical sensors integrated with advanced sensing materials for high temperature embedded gas sensing applications. Patent applications have been filed for two inventions in this area and several other methods are currently under development. These technologies are available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory (NETL). Organizations or individuals with capabilities in optical sensor packaging for harsh environment and high temperature applications are encouraged to contact NETL to explore potential collaborative opportunities. Overview Contact NETL Technology Transfer Group techtransfer@netl.doe.gov

277

High temperature superconductor current leads  

DOE Patents [OSTI]

An electrical lead is disclosed having one end for connection to an apparatus in a cryogenic environment and the other end for connection to an apparatus outside the cryogenic environment. The electrical lead includes a high temperature superconductor wire and an electrically conductive material distributed therein, where the conductive material is present at the one end of the lead at a concentration in the range of from 0 to about 3% by volume, and at the other end of the lead at a concentration of less than about 20% by volume. Various embodiments are shown for groups of high temperature superconductor wires and sheaths. 9 figs.

Hull, J.R.; Poeppel, R.B.

1995-06-20T23:59:59.000Z

278

Metallic Interconnects for Solid Oxide Fuel Cell: Performance of Reactive Element Oxide Coating During 10, 20 and 30Months Exposure  

Science Journals Connector (OSTI)

One of challenges in improving the performance and cost-effectiveness of SOFCs (Solid Oxide Fuel Cells) is the development of suitable interconnect materials. Chromia-forming alloys and especially ferritic sta...

S. Fontana; S. Chevalier; G. Caboche

2012-12-01T23:59:59.000Z

279

Composite cathode based on yttria stabilized bismuth oxide for low-temperature solid oxide fuel cells  

Science Journals Connector (OSTI)

Composites consisting of silver and yttria stabilized bismuth oxide (YSB) have been investigated as cathodes for low-temperature honeycomb solid oxide fuel cells with stabilized zirconia as electrolytes. At 600? C the interfacial polarization resistances of a porous YSBAg cathode is about 0.3??? cm 2 more than one order of magnitude smaller than those of other reported cathodes on stabilized zirconia. For example the interfacial resistances of a traditional YSZlanthanum maganites composite cathode is about 11.4??? cm 2 at 600? C . Impedance analysis indicated that the performance of an YSBAg composite cathode fired at 850? C for 2 h is severely limited by gas transport due to insufficient porosity. The high performance of the YSBAg cathodes is very encouraging for developing honeycomb fuel cells to be operated at temperatures below 600? C .

Changrong Xia; Yuelan Zhang; Meilin Liu

2003-01-01T23:59:59.000Z

280

High temperature lightweight foamed cements  

DOE Patents [OSTI]

Cement slurries are disclosed which are suitable for use in geothermal wells since they can withstand high temperatures and high pressures. The formulation consists of cement, silica flour, water, a retarder, a foaming agent, a foam stabilizer, and a reinforcing agent. A process for producing these cements is also disclosed. 3 figs.

Sugama, Toshifumi.

1989-10-03T23:59:59.000Z

Note: This page contains sample records for the topic "high-temperature solid oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

High temperature turbine engine structure  

DOE Patents [OSTI]

A high temperature turbine engine includes a rotor portion having axially stacked adjacent ceramic rotor parts. A ceramic/ceramic joint structure transmits torque between the rotor parts while maintaining coaxial alignment and axially spaced mutually parallel relation thereof despite thermal and centrifugal cycling.

Boyd, Gary L. (Tempe, AZ)

1991-01-01T23:59:59.000Z

282

Conditioning effects on La1-xSrxMnO3-Yttria stabilized Zirconia electrodes for thin-film solid oxide fuel cells  

E-Print Network [OSTI]

for Thin-Film Solid Oxide Fuel Cells You-Kee Lee a, *, Jung-performance of a solid oxide fuel cell (SOFC). LSM surfacethe development of solid oxide fuel cells (SOFCs) capable of

2002-01-01T23:59:59.000Z

283

Materials System for Intermediate Temperature Solid Oxide Fuel Cell  

SciTech Connect (OSTI)

The objective of this work was to obtain a stable materials system for intermediate temperature solid oxide fuel cell (SOFC) capable of operating between 600-800 C with a power density greater than 0.2 W/cm{sup 2}. The solid electrolyte chosen for this system was La{sub 0.9}Sr{sub 0.1}Ga{sub 0.8}Mg{sub 0.2}O{sub 3}, (LSGM). To select the right electrode materials from a group of possible candidate materials, AC complex impedance spectroscopy studies were conducted between 600-800 C on symmetrical cells that employed the LSGM electrolyte. Based on the results of the investigation, LSGM electrolyte supported SOFCs were fabricated with La{sub 0.6}Sr{sub 0.4}Co{sub 0.8}Fe{sub 0.2}O{sub 3}-La{sub 0.9}Sr{sub 0.1}Ga{sub 0.8}Mg{sub 0.2}O{sub 3} (LSCF-LSGM) composite cathode and Nickel-Ce{sub 0.6}La{sub 0.4}O{sub 3} (Ni-LDC) composite anode having a barrier layer of Ce{sub 0.6}La{sub 0.4}O{sub 3} (LDC) between the LSGM electrolyte and the Ni-LDC anode. Electrical performance and stability of these cells were determined and the electrode polarization behavior as a function of cell current was modeled between 600-800 C. The electrical performance of the anode-supported SOFC was simulated assuming an electrode polarization behavior identical to the LSGM-electrolyte-supported SOFC. The simulated electrical performance indicated that the selected material system would provide a stable cell capable of operating between 600-800 C with a power density between 0.2 to 1 W/cm{sup 2}.

Uday B. Pal; Srikanth Gopalan

2006-01-12T23:59:59.000Z

284

Conformation of Poly(ethylene oxide)-Hydroxybenzene Molecular Complexes Studied by Solid-State NMR  

E-Print Network [OSTI]

Conformation of Poly(ethylene oxide)-Hydroxybenzene Molecular Complexes Studied by Solid-State NMR February 16, 2000 ABSTRACT: The conformation of poly(ethylene oxide), PEO, in molecular complexes. Introduction Poly(ethylene oxide), PEO, is a relatively nonpolar polymer but contains ether oxygens

Hong, Mei

285

NETL: Mercury Emissions Control Technologies - Enhanced High Temperature  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Enhanced High Temperature Mercury Oxidation and Enhanced High Temperature Mercury Oxidation and In-Situ Active Carbon Generation for Low Cost Mercury Capture Mercury oxidation phenomenon and the studies of this phenomenon have generally focused on lower temperatures, typically below 650°F. This has been based on the mercury vapor equilibrium speciation curve. The baseline extents of mercury oxidation as reported in the ICR dataset and observed during subsequent tests has shown a tremendous amount of scatter. The objective of this project is to examine, establish and demonstrate the effect of higher temperature kinetics on mercury oxidation rates. Further, it is the objective of this project to demonstrate how the inherent mercury oxidation kinetics can be influenced to dramatically increase the mercury oxidation.

286

Titanium dioxide based high temperature carbon monoxide selective sensor  

E-Print Network [OSTI]

Titanium dioxide based high temperature carbon monoxide selective sensor Nancy O. Savagea , Sheikh as a trap for the oxidation products of CO and CH4. Upon oxidation of CO on ALC, carbonate species were detected, whereas the reaction of CH4 produced negligible carbonate species. The insensitivity of the ALC

Dutta, Prabir K.

287

High Temperature Steam Electrolysis: Demonstration of Improved Long-Term Performance  

SciTech Connect (OSTI)

Long-term performance is an ongoing issue for hydrogen production based on high-temperature steam electrolysis (HTSE). For commercial deployment, solid-oxide electrolysis stacks must achieve high performance with long-term degradation rates of {approx}0.5%/1000 hours or lower. Significant progress has been achieved toward this goal over the past few years. This paper will provide details of progress achieved under the Idaho National Laboratory high temperature electrolysis research program. Recent long-term stack tests have achieved high initial performance with degradation rates less than 5%/khr. These tests utilize internally manifolded stacks with electrode-supported cells. The cell material sets are optimized for the electrolysis mode of operation. Details of the cells and stacks will be provided along with details of the test apparatus, procedures, and results.

J. E. O'Brien; X. Zhang; R. C. O'Brien; G. Tao

2011-11-01T23:59:59.000Z

288

Proceedings of the Lucerne Fuel Cell Forum 2006 European Solid Oxide Fuel Cell Forum, 3-7 July 2006  

E-Print Network [OSTI]

Proceedings of the Lucerne Fuel Cell Forum 2006 7th European Solid Oxide Fuel Cell Forum, 3-7 July Uncertainties in our understanding of the oxygen reduction mechanism (ORR) at solid oxide fuel cell (SOFC studies have shown that cathodic or anodic dc polarization of the solid oxide fuel cell oxygen electrodes

Yildiz, Bilge

289

Three-Dimensional Analysis of Solid Oxide Fuel Cell Ni-YSZ Anode Interconnectivity James R. Wilson,a  

E-Print Network [OSTI]

1 Three-Dimensional Analysis of Solid Oxide Fuel Cell Ni-YSZ Anode Interconnectivity James R of interconnectivity of solid-oxide fuel cell (SOFC) electrode phases. The method was applied to the three, and hence was not electrochemically active. #12;2 1. Introduction Attempts to understand solid oxide fuel

Kalies, William D.

290

Nickel-and Ruthenium-Doped Lanthanum Chromite Anodes: Effects of Nanoscale Metal Precipitation on Solid Oxide  

E-Print Network [OSTI]

on Solid Oxide Fuel Cell Performance W. Kobsiriphat,* B. D. Madsen, Y. Wang, M. Shah, L. D. Marks, and S. A characterization and electrochemical measurements in solid oxide fuel cells SOFCs . Transmission electron. Nanometer-scale electrode structures in solid oxide fuel cells SOFCs have the potential to yield improved

Marks, Laurence D.

291

CONTROL-ORIENTED MODELING OF A SOLID-OXIDE FUEL CELL STACK USING AN LPV MODEL STRUCTURE  

E-Print Network [OSTI]

CONTROL-ORIENTED MODELING OF A SOLID-OXIDE FUEL CELL STACK USING AN LPV MODEL STRUCTURE Borhan M dynamic model of a solid oxide fuel cell stack. Using a detailed physical model as a starting point, we (usually air) on the cathode side. Solid-oxide fuel cells (SOFCs) utilize a ceramic oxygen-ion conducting

Sanandaji, Borhan M.

292

IEEE TRANSACTIONS ON POWER ELECTRONICS, VOL. 19, NO. 5, SEPTEMBER 2004 1263 Solid-Oxide-Fuel-Cell Performance and Durability  

E-Print Network [OSTI]

IEEE TRANSACTIONS ON POWER ELECTRONICS, VOL. 19, NO. 5, SEPTEMBER 2004 1263 Solid-Oxide-Fuel-Cell of solid-oxide-fuel-cell (SOFC) power-conditioning system (PCS) at the subsystem/component and system Terms--Power-conditioning system (PCS), power-elec- tronics subsystem (PES), solid-oxide-fuel-cell (SOFC

Mazumder, Sudip K.

293

Journal of Power Sources 135 (2004) 184191 A solid oxide fuel cell system fed with hydrogen sulfide  

E-Print Network [OSTI]

Journal of Power Sources 135 (2004) 184­191 A solid oxide fuel cell system fed with hydrogen for a solid oxide fuel cell (SOFC). This paper presents an examination of a simple hydrogen sulfide and natural gas-fed solid oxide fuel cell system. The possibility of utilization of hydrogen sulfide

294

New Sealing Concept for Planar Solid Oxide Fuel Cells  

SciTech Connect (OSTI)

A key element in developing high performance planar solid oxide fuel cell stacks is the hermetic seal between the metal and ceramic components. There are two methods of sealing that are commonly employed: (1) rigid joining or (2) compressive sealing. Each method has its own set of advantages and design constraints. An alternative approach is currently under development that appears to combine some of the advantages of the other two techiques, including hermeticity, mechanical integrity, and minimization of interfacial stresses in either of the joint substrate materials, particulary the ceramic. The new sealing concept relies on a plastically deformable metal seal; one that offers a quasi-dynamic mechanical response in that it is adherent to both sealing surfaces, i.e. non-sliding, but readily yields or deforms under thermally generated stresses, thereby mitigating the development of stresses in the adjacent ceramic and metal components even when a significant difference in thermal expansion exists between the two materials. The pre-experimental design of the seal, initial proof-of-principle results on small test specimens, and finite element analyses aimed at scaling the seal to prototypical sizes and geometries are described herein.

Weil, K. Scott; Hardy, John S.; Koeppel, Brian J.

2006-08-01T23:59:59.000Z

295

Electrode Performance in Reversible Solid Oxide Fuel Cells  

SciTech Connect (OSTI)

The performance of several negative (fuel) and positive (air) electrode compositions for use in reversible solid oxide fuel cells (SOFC) that are capable of operating both as a fuel cell and as an electrolyzer was investigated in half-cell and full-cell tests. Negative electrode compositions studied were a nickel/zirconia cermet (Ni/YSZ) and lanthanum-substituted strontium titanate/ceria composite, whereas positive electrode compositions examined included mixed ion and electron-conducting lanthanum strontium ferrite (LSF), lanthanum strontium copper ferrite (LSCuF), lanthanum strontium cobalt ferrite (LSCoF), and lanthanum strontium manganite (LSM). While titanate/ceria and Ni/YSZ electrodes performed similarly in the fuel cell mode in half-cell tests, losses associated with electrolysis were lower for the titanate/ceria electrode. Positive electrodes all gave higher losses in the electrolysis mode when compared to the fuel cell mode. This behavior was most apparent for mixed-conducting LSF, LSCuF, and LSCoF electrodes, and discernible but smaller for LSM; observations are consistent with expected trends in the interfacial oxygen vacancy concentration under anodic and cathodic polarization. Full-cell tests conducted for cells with a thin electrolyte (7 um YSZ) similarly showed higher polarization losses in the electrolysis than fuel cell direction.

Marina, Olga A.; Pederson, Larry R.; Williams, Mark C.; Coffey, Greg W.; Meinhardt, Kerry D.; Nguyen, Carolyn D.; Thomsen, Ed C.

2007-03-22T23:59:59.000Z

296

PRESSURIZED SOLID OXIDE FUEL CELL/GAS TURBINE POWER SYSTEM  

SciTech Connect (OSTI)

Power systems based on the simplest direct integration of a pressurized solid oxide fuel cell (SOFC) generator and a gas turbine (GT) are capable of converting natural gas fuel energy to electric power with efficiencies of approximately 60% (net AC/LHV), and more complex SOFC and gas turbine arrangements can be devised for achieving even higher efficiencies. The results of a project are discussed that focused on the development of a conceptual design for a pressurized SOFC/GT power system that was intended to generate 20 MWe with at least 70% efficiency. The power system operates baseloaded in a distributed-generation application. To achieve high efficiency, the system integrates an intercooled, recuperated, reheated gas turbine with two SOFC generator stages--one operating at high pressure, and generating power, as well as providing all heat needed by the high-pressure turbine, while the second SOFC generator operates at a lower pressure, generates power, and provides all heat for the low-pressure reheat turbine. The system cycle is described, major system components are sized, the system installed-cost is estimated, and the physical arrangement of system components is discussed. Estimates of system power output, efficiency, and emissions at the design point are also presented, and the system cost of electricity estimate is developed.

W.L. Lundberg; G.A. Israelson; R.R. Moritz (Rolls-Royce Allison); S.E. Veyo; R.A. Holmes; P.R. Zafred; J.E. King; R.E. Kothmann (Consultant)

2000-02-01T23:59:59.000Z

297

Performance Analysis and Development Strategies for Solid Oxide Fuel Cells  

Science Journals Connector (OSTI)

Solid oxide fuel cells (SOFC) are of great interest for a diverse range of applications. Within the past 10 years, an increase in power density by one order of magnitude, a lowering of the operating temperature by 200 K, and degradation rates lowered by a factor of 10 have been achieved on the cell and stack level. However, there is still room for further enhancement of the overall performance by suitably tailoring the cell components on a micro- and nanostructural level. The efficiency of the electrochemically active single cell is characterized by the linear ohmic losses within the electrolyte and by nonlinear polarization losses at the electrode-electrolyte interfaces. Both depend on material composition and operation conditions (temperature and time, fuel utilisation and gas composition). The area-specific resistance (ASR) is considered as the figure of merit for overall performance. ASR values of anode supported cells (ASC) were determined by means of impedance spectroscopy and subsequently separated into ohmic losses (mainly electrolyte) and nonlinear polarisation losses resulting from gas diffusion and activation polarization in the cathode and anode. The efficiencies of ASCs will be discussed for various material combinations in the temperature range of technological interest (between 550 C and 850 C).

E Ivers-Tiffe; A Leonide; A Weber

2011-01-01T23:59:59.000Z

298

Method of manufacturing a high temperature superconductor with improved transport properties  

SciTech Connect (OSTI)

A method of preparing a high temperature superconductor. A method of preparing a superconductor includes providing a powdered high temperature superconductor and a nanophase paramagnetic material. These components are combined to form a solid compacted mass with the paramagnetic material disposed on the grain boundaries of the polycrystaline high temperature superconductor.

Balachandran, Uthamalingam (Hinsdale, IL); Siegel, Richard W. (Hinsdale, IL); Askew, Thomas R. (Kalamazoo, MI)

2001-01-01T23:59:59.000Z

299

Acid Doped Membranes for High Temperature PEMFC  

Broader source: Energy.gov [DOE]

Presentation on Acid Doped Membranes for High Temperature PEMFC to the High Temperature Membrane Working Group, May 25, 2004 in Philadelphia, PA.

300

Experiment Hazard Class 3 - High Temperatures  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Operation * APS Base Low Temperatures * Cryogenic Systems High Temperatures * Electric Furnace * Optical Furnace * Other High Temperature Lasers * Laser, Class 2 * Laser,...

Note: This page contains sample records for the topic "high-temperature solid oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Method for Synthesizing Extremeley High Temperature Melting Materials  

DOE Patents [OSTI]

The invention relates to a method of synthesizing high-temperature melting materials. More specifically the invention relates to a containerless method of synthesizing very high temperature melting materials such as borides, carbides and transition-metal, lanthanide and actinide oxides, using an Aerodynamic Levitator and a laser. The object of the invention is to provide a method for synthesizing extremely high-temperature melting materials that are otherwise difficult to produce, without the use of containers, allowing the manipulation of the phase (amorphous/crystalline/metastable) and permitting changes of the environment such as different gaseous compositions.

Saboungi, Marie-Louise and Glorieux, Benoit

2005-11-22T23:59:59.000Z

302

Method For Synthesizing Extremely High-Temperature Melting Materials  

DOE Patents [OSTI]

The invention relates to a method of synthesizing high-temperature melting materials. More specifically the invention relates to a containerless method of synthesizing very high temperature melting materials such as borides, carbides and transition-metal, lanthanide and actinide oxides, using an Aerodynamic Levitator and a laser. The object of the invention is to provide a method for synthesizing extremely high-temperature melting materials that are otherwise difficult to produce, without the use of containers, allowing the manipulation of the phase (amorphous/crystalline/metastable) and permitting changes of the environment such as different gaseous compositions.

Saboungi, Marie-Louise (Chicago, IL); Glorieux, Benoit (Perpignan, FR)

2005-11-22T23:59:59.000Z

303

Method for synthesizing extremely high-temperature melting materials  

SciTech Connect (OSTI)

The invention relates to a method of synthesizing high-temperature melting materials. More specifically the invention relates to a containerless method of synthesizing very high temperature melting materials such as carbides and transition-metal, lanthanide and actinide oxides, using an aerodynamic levitator and a laser. The object of the invention is to provide a method for synthesizing extremely high-temperature melting materials that are otherwise difficult to produce, without the use of containers, allowing the manipulation of the phase (amorphous/crystalline/metastable) and permitting changes of the environment such as different gaseous compositions.

Saboungi, Marie-Louise (Chicago, IL); Glorieux, Benoit (Perpignan, FR)

2007-11-06T23:59:59.000Z

304

High temperature turbine engine structure  

DOE Patents [OSTI]

A high temperature ceramic/metallic turbine engine includes a metallic housing which journals a rotor member of the turbine engine. A ceramic disk-like shroud portion of the engine is supported on the metallic housing portion and maintains a close running clearance with the rotor member. A ceramic spacer assembly maintains the close running clearance of the shroud portion and rotor member despite differential thermal movements between the shroud portion and metallic housing portion.

Carruthers, William D. (Mesa, AZ); Boyd, Gary L. (Tempe, AZ)

1994-01-01T23:59:59.000Z

305

High temperature turbine engine structure  

DOE Patents [OSTI]

A high temperature ceramic/metallic turbine engine includes a metallic housing which journals a rotor member of the turbine engine. A ceramic disk-like shroud portion of the engine is supported on the metallic housing portion and maintains a close running clearance with the rotor member. A ceramic spacer assembly maintains the close running clearance of the shroud portion and rotor member despite differential thermal movements between the shroud portion and metallic housing portion.

Carruthers, William D. (Mesa, AZ); Boyd, Gary L. (Tempe, AZ)

1993-01-01T23:59:59.000Z

306

High temperature turbine engine structure  

DOE Patents [OSTI]

A high temperature ceramic/metallic turbine engine includes a metallic housing which journals a rotor member of the turbine engine. A ceramic disk-like shroud portion of the engine is supported on the metallic housing portion and maintains a close running clearance with the rotor member. A ceramic spacer assembly maintains the close running clearance of the shroud portion and rotor member despite differential thermal movements between the shroud portion and metallic housing portion.

Carruthers, William D. (Mesa, AZ); Boyd, Gary L. (Tempe, AZ)

1992-01-01T23:59:59.000Z

307

Development of Brazing Technology for Use in High- Temperature Gas Separation Equipment  

SciTech Connect (OSTI)

The development of high-temperature electrochemical devices such as oxygen and hydrogen separators, fuel gas reformers, solid oxide fuel cells, and chemical sensors is part of a rapidly expanding segment of the solid state technology market. These devices employ an ionic conducting ceramic as the active membrane that establishes the electrochemical potential of the device, either under voltage (i.e. to carry out gas separation) or under chemical gradient (to develop an electrical potential and thereby generate electrical power). Because the device operates under an ionic gradient that develops across the electrolyte, hermiticity across this layer is paramount. That is, not only must this thin ceramic membrane be dense with no interconnected porosity, but it must be connected to the rest of the device, typically constructed from a heat resistant alloy, with a high-temperature, gas-tight seal. A significant engineering challenge in fabricating these devices is how to effectively join the thin electrochemically active membrane to the metallic body of the device such that the resulting seal is hermetic, rugged, and stable during continuous high temperature operation. Active metal brazing is the typical method of joining ceramic and metal engineering components. It employs a braze alloy that contains one or more reactive elements, often titanium, which will chemically reduce the ceramic faying surface and greatly improve its wetting behavior and adherence with the braze. However, recent studies of these brazes for potential use in fabricating high-temperature electrochemical devices revealed problems with interfacial oxidation and subsequent joint failure [1,2]. Specifically, it was found that the introduction of the ceramic electrolyte and/or heat resistant metal substrate dramatically affects the inherent oxidation behavior of the braze, often in a deleterious manner. These conclusions pointed to the need for an oxidation resistant, high-temperature ceramic-to-metal braze and consequently lead to the development of the novel reactive air brazing (RAB) concept. The goal in RAB is to reactively modify one or both oxide faying surfaces with an oxide compound dissolved in a molten noble metal alloy such that the newly formed surface is readily wetted by the remaining liquid filler material. In many respects, this concept is similar to active metal brazing, except that joining can be conducted in air and the final joint will be resistant to oxidation at high temperature. Potentially, there are a number of metal oxide-noble metal systems that can be considered for RAB, including Ag-CuO, Ag-V2O5, and Pt-Nb2O5. Our current interest is in determining whether the Ag-CuO system is suitable for air brazing functional ceramic-to-metal joints such as those needed in practical electrochemical devices. In a series of studies, the wetting behavior of the Ag-CuO braze was investigated with respect to a number of potential hydrogen separation, oxygen separation, and fuel cell electrolyte membrane materials and heat resistant metal systems, including: alumina, (La0.6Sr0.4)(Co0.2Fe0.8)O3, (La0.8Sr0.2)FeO3, YSZ, fecralloy, and Crofer-22APU. Selected findings from these studies as well as from our work on joint strength and durability during high-temperature exposure testing will be discussed.

Weil, K.S.; Hardy, J.S.; Kim, J.Y.

2003-04-23T23:59:59.000Z

308

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures  

DOE Patents [OSTI]

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, John E. (Woodridge, IL); Jalan, Vinod M. (Concord, MA)

1984-01-01T23:59:59.000Z

309

High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures  

DOE Patents [OSTI]

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, J.E.; Jalan, V.M.

1982-07-07T23:59:59.000Z

310

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures  

DOE Patents [OSTI]

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, J.E.; Jalan, V.M.

1984-06-19T23:59:59.000Z

311

Overview of High-Temperature Electrolysis for Hydrogen Production  

SciTech Connect (OSTI)

Over the last five years there has been a growing interest in the use of hydrogen as an energy carrier, particularly to augment transportation fuels and thus reduce our dependence on imported petroleum. Hydrogen is now produced primarily via steam reforming of methane. However, in the long term, methane reforming is not a viable process for the large-scale hydrogen production since such fossil fuel conversion processes consume non-renewable resources and emit greenhouse gases. Nuclear energy can be used to produce hydrogen without consuming fossil fuels and without emitting greenhouse gases through the splitting of water into hydrogen and oxygen. The Nuclear Hydrogen Initiative of the DOE Office of Nuclear Energy is developing three general categories of high temperature processes for hydrogen production: thermochemical, electrolytic and hybrid thermo-electrolytic. This paper introduces the work being done in the development of high temperature electrolysis of steam. High Temperature Electrolysis (HTE) is built on the technology of solid oxide fuel cells (SOFCs), which were invented over a century ago, but which have been most vigorously developed during the last twenty years. SOFCs consume hydrogen and oxygen and produce steam and electricity. Solid Oxide Electrolytic Cells (SOECs) consume electricity and steam and produce hydrogen and oxygen. The purpose of the HTE research is to solve those problems unique to the electrolytic mode of operation, while building further on continuing fuel cell development. ORGANIZATION Experiments have been conducted for the last three years at the Idaho National Laboratory and at Ceramatec, Inc. on the operation of button cells and of progressively larger stacks of planar cells. In addition, the INL has been performing analyses of the cell-scale fluid dynamics and plant-scale flowsheets in order to determine optimum operating conditions and plant configurations. Argonne National Laboratory has been performing experiments for the development of new electrode materials, as well as modeling of the fluid dynamics and flowsheets for comparison with the work being done at the INL. ANL has also been performing diagnostic measures on components form long-duration tests at the INL and Ceramatec to determine the causes for the slow degradation in cell performance. Oak Ridge National Laboratory has been developing high temperature porous membranes for the separation of hydrogen from the residual steam, thus avoiding the need to condense and reheat the steam. The University of Nevada at Las Vegas has been collaborating with ANL on the development of electrode and electrolyte materials and will soon begin to investigate the causes of cell degradation. HTE research also includes NERI projects at the Virginia Polytechnic Institute on the development of toughened SOEC composite seals and at the Georgia Institute of Technology on the microstructural design of SOEC materials. EXPERIMENTAL RESULTS The most recent large-scale test of HTE was performed from June 28 through Sept 22, 2006 at the Ceramatec plant in Salt Lake City. The test apparatus consists of two stacks of 60 cells each in a configuration that will be used in the Integrated Laboratory Scale (ILS) experiment during FY-07. The ILS will contain three modules of four stacks each. The Half-Module initially produced 1.2 normal m3of H2/hour and 0.65 Nm3/hr at the end of the 2040-hour continuous test.

Herring, J. S.; O'Brien, J. E.; Stoots, C. M.; Hartvigsen, J. J.; Petri, M. C.; Carter, J. D.; Bischoff, B. L.

2007-06-01T23:59:59.000Z

312

Functionally Graded Cathodes for Solid Oxide Fuel Cells  

SciTech Connect (OSTI)

One primary suspected cause of long-term performance degradation of solid oxide fuels (SOFCs) is the accumulation of chromium (Cr) species at or near the cathode/electrolyte interface due to reactive Cr molecules originating from Cr-containing components (such as the interconnect) in fuel cell stacks. To date, considerable efforts have been devoted to the characterization of cathodes exposed to Cr sources; however, little progress has been made because a detailed understanding of the chemistry and electrochemistry relevant to the Cr-poisoning processes is still lacking. This project applied multiple characterization methods - including various Raman spectroscopic techniques and various electrochemical performance measurement techniques - to elucidate and quantify the effect of Cr-related electrochemical degradation at the cathode/electrolyte interface. Using Raman microspectroscopy the identity and location of Cr contaminants (SrCrO{sub 4}, (Mn/Cr){sub 3}O{sub 4} spinel) have been observed in situ on an LSM cathode. These Cr contaminants were shown to form chemically (in the absence of current flowing through the cell) at temperatures as low as 625 C. While SrCrO{sub 4} and (Mn/Cr){sub 3}O{sub 4} spinel must preferentially form on LSM, since the LSM supplies the Sr and Mn cations necessary for these compounds, LSM was also shown to be an active site for the deposition of Ag{sub 2}CrO{sub 4} for samples that also contained silver. In contrast, Pt and YSZ do not appear to be active for formation of Cr-containing phases. The work presented here supports the theory that Cr contamination is predominantly chemically-driven and that in order to minimize the effect, cathode materials should be chosen that are free of cations/elements that could preferentially react with chromium, including silver, strontium, and manganese.

Harry Abernathy; Meilin Liu

2006-12-31T23:59:59.000Z

313

Solid Oxide Fuel Cell Successfully Powers Truck Cab and Sleeper in  

Broader source: Energy.gov (indexed) [DOE]

Solid Oxide Fuel Cell Successfully Powers Truck Cab and Sleeper in Solid Oxide Fuel Cell Successfully Powers Truck Cab and Sleeper in DOE-Sponsored Test Solid Oxide Fuel Cell Successfully Powers Truck Cab and Sleeper in DOE-Sponsored Test March 19, 2009 - 1:00pm Addthis Washington, DC --In a test sponsored by the U.S. Department of Energy (DOE), a Delphi auxiliary power unit employing a solid oxide fuel cell (SOFC) successfully operated the electrical system and air conditioning of a Peterbilt Model 386 truck under conditions simulating idling conditions for 10 hours. The device provides an alternative to running a truck's main diesel engine, or using a truck's batteries, to power auxiliary electrical loads during rest periods, thereby lowering emissions, reducing noise, and saving fuel. In testing at Peterbilt Motors Company Texas head-quarters, a Delphi

314

Electrical Generation for More-Electric Aircraft using Solid Oxide Fuel Cells  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

XXXXX XXXXX Prepared for the U.S. Department of Energy under Contract DE-AC05-76RL01830 Electrical Generation for More-Electric Aircraft using Solid Oxide Fuel Cells GA Whyatt LA Chick April 2012 PNNL-XXXXX Electrical Generation for More- Electric Aircraft using Solid Oxide Fuel Cells GA Whyatt LA Chick April 2012 Prepared for the U.S. Department of Energy under Contract DE-AC05-76RL01830 Pacific Northwest National Laboratory Richland, Washington 99352 iii Summary This report examines the potential for Solid-Oxide Fuel Cells (SOFC) to provide electrical generation on-board commercial aircraft. Unlike a turbine-based auxiliary power unit (APU) a solid oxide fuel cell power unit (SOFCPU) would be more efficient than using the main engine generators to generate

315

Methods of reducing emissions of nitrogen oxides at thermal power plants burning solid domestic waste  

Science Journals Connector (OSTI)

Essentially all the major methods of reducing the emissions of nitrogen oxides from flue gases employed in power generation have been tested on plants in Moscow which burn solid domestic waste for production of h...

A. N. Tugov; V. F. Moskvichev

2009-01-01T23:59:59.000Z

316

Development of metallic substrate supported planar solid oxide fuel cells fabricated by atmospheric plasma spraying  

Science Journals Connector (OSTI)

A planar solid oxide fuel cell (SOFC) consisting of a cell supported with a porous metallic substrate and a metallic separator has been developed. In the fabrication of the cell, anodes and electrolytes were form...

Shunji Takenoiri; Naruaki Kadokawa; Kazuo Koseki

2000-09-01T23:59:59.000Z

317

Comparative Life-Cycle Assessment of Residential Heating Systems, Focused on Solid Oxide Fuel Cells  

Science Journals Connector (OSTI)

This study aims to analyze a Solid Oxide Fuel Cell (SOFC) for residential heating applications by...producer, the user as an individual and the user...intended as the heating demand of a building, applied by defa...

Alba Cnovas; Rainer Zah; Santiago Gass

2013-01-01T23:59:59.000Z

318

Design improvements of micro-tubular solid oxide fuel cells for unmanned aircraft applications.  

E-Print Network [OSTI]

??This work contributes to the development of a micro-tubular solid oxide fuel cell (mSOFC) stack for use in a small unmanned aerial vehicle. Fuel cells (more)

Howe, Katie Sarah

2014-01-01T23:59:59.000Z

319

Solid-State NMR Spectroscopic Study of Phosphate Sorption Mechanisms on Aluminum (Hydr)oxides  

E-Print Network [OSTI]

Solid-State NMR Spectroscopic Study of Phosphate Sorption Mechanisms on Aluminum (Hydr)oxides Wei the mechanism of phosphate sorption on aluminum hydroxides under different environ- mental conditions, including

Sparks, Donald L.

320

Seven Projects That Will Advance Solid Oxide Fuel Cell Research Selected by  

Broader source: Energy.gov (indexed) [DOE]

That Will Advance Solid Oxide Fuel Cell Research That Will Advance Solid Oxide Fuel Cell Research Selected by DOE for Further Development Seven Projects That Will Advance Solid Oxide Fuel Cell Research Selected by DOE for Further Development July 27, 2012 - 1:00pm Addthis Washington, D.C. - Seven projects that will help develop low-cost solid oxide fuel cell (SOFC) technology for environmentally responsible central power generation from the Nation's abundant fossil energy resources have been selected for further research by the Department of Energy (DOE). The projects, managed by the Office of Fossil Energy's National Energy Technology Laboratory (NETL), are valued at a total of $4,391,570, with DOE contributing $3,499,250 and the remaining cost provided by the recipients. Four of the selected projects will pursue advances in cathode performance,

Note: This page contains sample records for the topic "high-temperature solid oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Bipolar plating of metal contacts onto oxide interconnection for solid oxide electrochemical cell  

DOE Patents [OSTI]

Disclosed is a method of forming an adherent metal deposit on a conducting layer of a tube sealed at one end. The tube is immersed with the sealed end down into an aqueous solution containing ions of the metal to be deposited. An ionically conducting aqueous fluid is placed inside the tube and a direct current is passed from a cathode inside the tube to an anode outside the tube. Also disclosed is a multi-layered solid oxide fuel cell tube which consists of an inner porous ceramic support tube, a porous air electrode covering the support tube, a non-porous electrolyte covering a portion of the air electrode, a non-porous conducting interconnection covering the remaining portion of the electrode, and a metal deposit on the interconnection.

Isenberg, Arnold O. (Forest Hills Boro, PA)

1987-01-01T23:59:59.000Z

322

Creep Behavior of Glass/Ceramic Sealant and its Effect on Long-term Performance of Solid Oxide Fuel Cells  

SciTech Connect (OSTI)

The creep behavior of glass or glass-ceramic sealant materials used in solid oxide fuel cells (SOFCs) becomes relevant under SOFC operating temperatures. In this paper, the creep of glass-ceramic sealants was experimentally examined, and a standard linear solid model was applied to capture the creep behavior of glass ceramic sealant materials developed for planar SOFCs at high temperatures. The parameters of this model were determined based on the creep test results. Furthermore, the creep model was incorporated into finite-element software programs SOFC-MP and Mentat-FC developed at Pacific Northwest National Laboratory for multi-physics simulation of SOFCs. The effect of creep of glass ceramic sealant materials on the long-term performance of SOFC stacks was investigated by studying the stability of the flow channels and the stress redistribution in the glass seal and on the various interfaces of the glass seal with other layers. Finite element analyses were performed to quantify the stresses in various parts. The stresses in glass seals were released because of creep behavior during operations.

Liu, Wenning N.; Sun, Xin; Koeppel, Brian J.; Stephens, Elizabeth V.; Khaleel, Mohammad A.

2009-10-14T23:59:59.000Z

323

Effects of anode microstructures on durability of microtubular solid oxide fuel cells during internal steam reforming of methane  

Science Journals Connector (OSTI)

Abstract When hydrocarbons are used as a fuel in solid oxide fuel cells (SOFCs), internal steam reforming increases the energy conversion efficiency and simplifies the system, including the balance-of-plant. However, conventional nickelyttria stabilized zirconia (NiYSZ) anodes are prone to deterioration at high temperatures and high humidity. This paper focuses on effects in anode microstructure on performance and durability of microtubular SOFCs. The evaluations were conducted under high steam content and internal methane reforming conditions using NiYSZ anodes using acrylic resin and graphite pore formers. The initial cell performance was almost identical to that of \\{SOFCs\\} with anodes using acrylic resin and graphite pore formers in 40% H23% H2O at 700C. However, the anode using acrylic resin deteriorated rapidly in 40% H230% H2O over a period of 28h. Furthermore, it generated almost no electric power by internal steam reforming of methane. The local oxidation of nickel particles was observed at the interface between the electrolyte and the deteriorated anodes. The anode using graphite pore former provided stable power generation in 40% H230% H2O, and was able to generate power in 10% CH430% H2O. The pore formers strongly affect fuel diffusivity in the SOFC anodes, which is an important factor in stable internal steam reforming of methane.

Hirofumi Sumi; Toshiaki Yamaguchi; Toshio Suzuki; Hiroyuki Shimada; Koichi Hamamoto; Yoshinobu Fujishiro

2014-01-01T23:59:59.000Z

324

Cathode and electrolyte materials for solid oxide fuel cells and ion transport membranes  

DOE Patents [OSTI]

Novel cathode, electrolyte and oxygen separation materials are disclosed that operate at intermediate temperatures for use in solid oxide fuel cells and ion transport membranes based on oxides with perovskite related structures and an ordered arrangement of A site cations. The materials have significantly faster oxygen kinetics than in corresponding disordered perovskites.

Jacobson, Allan J; Wang, Shuangyan; Kim, Gun Tae

2014-01-28T23:59:59.000Z

325

Functionally Graded Cathodes for Solid Oxide Fuel Cells  

SciTech Connect (OSTI)

This DOE SECA project focused on both experimental and theoretical understanding of oxygen reduction processes in a porous mixed-conducting cathode in a solid oxide fuel cell (SOFC). Elucidation of the detailed oxygen reduction mechanism, especially the rate-limiting step(s), is critical to the development of low-temperature SOFCs (400 C to 700 C) and to cost reduction since much less expensive materials may be used for cell components. However, cell performance at low temperatures is limited primarily by the interfacial polarization resistances, specifically by those associated with oxygen reduction at the cathode, including transport of oxygen gas through the porous cathode, the adsorption of oxygen onto the cathode surface, the reduction and dissociation of the oxygen molecule (O{sub 2}) into the oxygen ion (O{sup 2-}), and the incorporation of the oxygen ion into the electrolyte. In order to most effectively enhance the performance of the cathode at low temperatures, we must understand the mechanism and kinetics of the elementary processes at the interfaces. Under the support of this DOE SECA project, our accomplishments included: (1) Experimental determination of the rate-limiting step in the oxygen reduction mechanism at the cathode using in situ FTIR and Raman spectroscopy, including surface- and tip-enhanced Raman spectroscopy (SERS and TERS). (2) Fabrication and testing of micro-patterned cathodes to compare the relative activity of the TPB to the rest of the cathode surface. (3) Construction of a mathematical model to predict cathode performance based on different geometries and microstructures and analyze the kinetics of oxygen-reduction reactions occurring at charged mixed ionic-electronic conductors (MIECs) using two-dimensional finite volume models with ab initio calculations. (4) Fabrication of cathodes that are graded in composition and microstructure to generate large amounts of active surface area near the cathode/electrolyte interface using a novel combustion chemical vapor deposition (CCVD) technique. (5) Application of advanced quantum chemical calculations to interpret measured spectroscopic information, as well as to guide design of high efficient cathode materials.

YongMan Choi; Meilin Liu

2006-09-30T23:59:59.000Z

326

Cover and startup gas supply system for solid oxide fuel cell generator  

DOE Patents [OSTI]

A cover and startup gas supply system for a solid oxide fuel cell power generator is disclosed. Hydrocarbon fuel, such as natural gas or diesel fuel, and oxygen-containing gas are supplied to a burner. Combustion gas exiting the burner is cooled prior to delivery to the solid oxide fuel cell. The system mixes the combusted hydrocarbon fuel constituents with hydrogen which is preferably stored in solid form to obtain a non-explosive gas mixture. The system may be used to provide both non-explosive cover gas and hydrogen-rich startup gas to the fuel cell.

Singh, Prabhakar (Export, PA); George, Raymond A. (Pittsburgh, PA)

1999-01-01T23:59:59.000Z

327

Cover and startup gas supply system for solid oxide fuel cell generator  

DOE Patents [OSTI]

A cover and startup gas supply system for a solid oxide fuel cell power generator is disclosed. Hydrocarbon fuel, such as natural gas or diesel fuel, and oxygen-containing gas are supplied to a burner. Combustion gas exiting the burner is cooled prior to delivery to the solid oxide fuel cell. The system mixes the combusted hydrocarbon fuel constituents with hydrogen which is preferably stored in solid form to obtain a non-explosive gas mixture. The system may be used to provide both non-explosive cover gas and hydrogen-rich startup gas to the fuel cell. 4 figs.

Singh, P.; George, R.A.

1999-07-27T23:59:59.000Z

328

Multilayer ultra-high-temperature ceramic coatings  

DOE Patents [OSTI]

A coated carbon-carbon composite material with multiple ceramic layers to provide oxidation protection from ultra-high-temperatures, where if the carbon-carbon composite material is uninhibited with B.sub.4C particles, then the first layer on the composite material is selected from ZrB.sub.2 and HfB.sub.2, onto which is coated a layer of SiC coated and if the carbon-carbon composite material is inhibited with B.sub.4C particles, then protection can be achieved with a layer of SiC and a layer of either ZrB.sub.2 and HfB.sub.2 in any order.

Loehman, Ronald E. (Albuquerque, NM); Corral, Erica L. (Tucson, AZ)

2012-03-20T23:59:59.000Z

329

Turbine vane with high temperature capable skins  

DOE Patents [OSTI]

A turbine vane assembly includes an airfoil extending between an inner shroud and an outer shroud. The airfoil can include a substructure having an outer peripheral surface. At least a portion of the outer peripheral surface is covered by an external skin. The external skin can be made of a high temperature capable material, such as oxide dispersion strengthened alloys, intermetallic alloys, ceramic matrix composites or refractory alloys. The external skin can be formed, and the airfoil can be subsequently bi-cast around or onto the skin. The skin and the substructure can be attached by a plurality of attachment members extending between the skin and the substructure. The skin can be spaced from the outer peripheral surface of the substructure such that a cavity is formed therebetween. Coolant can be supplied to the cavity. Skins can also be applied to the gas path faces of the inner and outer shrouds.

Morrison, Jay A. (Oviedo, FL)

2012-07-10T23:59:59.000Z

330

High temperature low friction surface coating  

DOE Patents [OSTI]

A high temperature, low friction, flexible coating for metal surfaces which are subject to rubbing contact includes a mixture of three parts graphite and one part cadmium oxide, ball milled in water for four hours, then mixed with thirty percent by weight of sodium silicate in water solution and a few drops of wetting agent. The mixture is sprayed 12-15 microns thick onto an electro-etched metal surface and air dried for thirty minutes, then baked for two hours at 65.degree. C. to remove the water and wetting agent, and baked for an additional eight hours at about 150.degree. C. to produce the optimum bond with the metal surface. The coating is afterwards burnished to a thickness of about 7-10 microns.

Bhushan, Bharat (Watervliet, NY)

1980-01-01T23:59:59.000Z

331

The Orientation Distributions of Lines, Surfaces, and Interfaces around Three-Phase Boundaries in Solid Oxide Fuel Cell Cathodes  

E-Print Network [OSTI]

in Solid Oxide Fuel Cell Cathodes Shen J. Dillon, Lam Helmick,§,¶ Herbert M. Miller,§ Lane Wilson in a multiphase ceramic material. I. Introduction THE active cathode regions of many solid oxide fuel cells (SOFCs of yttria-stabilized zirconia and lanthanum strontium manganese oxide, both before and after mild

Rohrer, Gregory S.

332

In situ reduction and reoxidation of a solid oxide fuel cell anode in an environmental Q. Jeangros1  

E-Print Network [OSTI]

In situ reduction and reoxidation of a solid oxide fuel cell anode in an environmental TEM Q, Denmark Solid oxide fuel cells (SOFC) are efficient devices for the electrochemical conversion of a large, high fuel utilization or a shut down without protection gas. The important expansion during oxidation

Dunin-Borkowski, Rafal E.

333

High temperature electrolysis for syngas production  

DOE Patents [OSTI]

Syngas components hydrogen and carbon monoxide may be formed by the decomposition of carbon dioxide and water or steam by a solid-oxide electrolysis cell to form carbon monoxide and hydrogen, a portion of which may be reacted with carbon dioxide to form carbon monoxide. One or more of the components for the process, such as steam, energy, or electricity, may be provided using a nuclear power source.

Stoots, Carl M. (Idaho Falls, ID); O'Brien, James E. (Idaho Falls, ID); Herring, James Stephen (Idaho Falls, ID); Lessing, Paul A. (Idaho Falls, ID); Hawkes, Grant L. (Sugar City, ID); Hartvigsen, Joseph J. (Kaysville, UT)

2011-05-31T23:59:59.000Z

334

Mechanisms of Oxide Scale Formation on Ferritic Interconnect Steel in Simulated Low and High pO2 Service Environments of Solid Oxide Fuel Cells  

Science Journals Connector (OSTI)

The Laves phase strengthened ferritic steel Crofer 22 H has recently been proposed as construction material for interconnects in solid oxide fuel cells (SOFCs). In the present study, the oxidation kinetics of ...

L. Niewolak; D. J. Young; H. Hattendorf; L. Singheiser

2014-08-01T23:59:59.000Z

335

High Temperature Mechanical Properties as Design Parameters  

Science Journals Connector (OSTI)

...corrosion resistance or high proof strength...development of more efficient power plant, process...Figure 2 shows a high temperature bolt...S.O.) of a Boiler Code (I968...power plant for high temperature pipework, boiler headers, valve...

1976-01-01T23:59:59.000Z

336

High-temperature thermocouples and related methods  

DOE Patents [OSTI]

A high-temperature thermocouple and methods for fabricating a thermocouple capable of long-term operation in high-temperature, hostile environments without significant signal degradation or shortened thermocouple lifetime due to heat induced brittleness.

Rempe, Joy L. (Idaho Falls, ID); Knudson, Darrell L. (Firth, ID); Condie, Keith G. (Idaho Falls, ID); Wilkins, S. Curt (Idaho Falls, ID)

2011-01-18T23:59:59.000Z

337

High Temperature Integrated Thermoelectric Ststem and Materials  

SciTech Connect (OSTI)

The final goal of this project is to produce, by the end of Phase II, an all ceramic high temperature thermoelectric module. Such a module design integrates oxide ceramic n-type, oxide ceramic p-type materials as thermoelectric legs and oxide ceramic conductive material as metalizing connection between n-type and p-type legs. The benefits of this all ceramic module are that it can function at higher temperatures (> 700 C), it is mechanically and functionally more reliable and it can be scaled up to production at lower cost. With this all ceramic module, millions of dollars in savings or in new opportunities recovering waste heat from high temperature processes could be made available. A very attractive application will be to convert exhaust heat from a vehicle to reusable electric energy by a thermoelectric generator (TEG). Phase I activities were focused on evaluating potential n-type and p-type oxide compositions as the thermoelectric legs. More than 40 oxide ceramic powder compositions were made and studied in the laboratory. The compositions were divided into 6 groups representing different material systems. Basic ceramic properties and thermoelectric properties of discs sintered from these powders were measured. Powders with different particles sizes were made to evaluate the effects of particle size reduction on thermoelectric properties. Several powders were submitted to a leading thermoelectric company for complete thermoelectric evaluation. Initial evaluation showed that when samples were sintered by conventional method, they had reasonable values of Seebeck coefficient but very low values of electrical conductivity. Therefore, their power factors (PF) and figure of merits (ZT) were too low to be useful for high temperature thermoelectric applications. An unconventional sintering method, Spark Plasma Sintering (SPS) was determined to produce better thermoelectric properties. Particle size reduction of powders also was found to have some positive benefits. Two composition systems, specifically 1.0 SrO - 0.8 x 1.03 TiO2 - 0.2 x 1.03 NbO2.5 and 0.97 TiO2 - 0.03 NbO2.5, have been identified as good base line compositions for n-type thermoelectric compositions in future module design. Tests of these materials at an outside company were promising using that company's processing and material expertise. There was no unique p-type thermoelectric compositions identified in phase I work other than several current cobaltite materials. Ca3Co4O9 will be the primary p-type material for the future module design until alternative materials are developed. BaTiO3 and rare earth titanate based dielectric compositions show both p-type and n-type behavior even though their electrical conductivities were very low. Further research and development of these materials for thermoelectric applications is planned in the future. A preliminary modeling and optimization of a thermoelectric generator (TEG) that uses the n-type 1.0 SrO - 1.03 x 0.8 TiO2 - 1.03 x 0.2 NbO2.5 was performed. Future work will combine development of ceramic powders and manufacturing expertise at TAM, development of SPS at TAM or a partner organization, and thermoelectric material/module testing, modeling, optimization, production at several partner organizations.

Mike S. H. Chu

2011-06-06T23:59:59.000Z

338

Impurity effects on electronmode coupling in high-temperature superconductors  

E-Print Network [OSTI]

LETTERS Impurity effects on electron­mode coupling in high-temperature superconductors K. TERASHIMA espite years of intensive research on copper oxide superconductors with high transition temperatures (Tc in the high-Tc superconductors. The interaction of electrons with bosonic excitations (phonons or spin

Loss, Daniel

339

Materials Characterization Capabilities at the High Temperature...  

Broader source: Energy.gov (indexed) [DOE]

Characterization Capabilities at the High Temperature Materials Laboratory: Focus on Carbon Fiber and Composites Materials Characterization Capabilities at the High...

340

Reciprocity theorem in high-temperature superconductors  

E-Print Network [OSTI]

This article is devoted to the problem of the validity of the reciprocity theorem in high-temperature

Ivan Jane?ek

2002-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "high-temperature solid oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Scaling in high-temperature superconductors by  

E-Print Network [OSTI]

A Hartree approximation is used to study the interplay of two kinds of scaling which arise in high-temperature

Ian D Lawrie

1994-01-01T23:59:59.000Z

342

Agenda: High Temperature Membrane Working Group Meeting  

Broader source: Energy.gov [DOE]

Agenda for the High Temperature Membrane Working Group (HTMWG) meeting on May 18, 2009, in Arlington, Virginia

343

A Reversible Planar Solid Oxide Fuel-Fed Electrolysis Cell and Solid Oxide Fuel Cell for Hydrogen and Electricity Production Operating on Natural Gas/Biomass Fuels  

SciTech Connect (OSTI)

A solid oxide fuel-assisted electrolysis technique was developed to co-generate hydrogen and electricity directly from a fuel at a reduced cost of electricity. Solid oxide fuel-assisted electrolysis cells (SOFECs), which were comprised of 8YSZ electrolytes sandwiched between thick anode supports and thin cathodes, were constructed and experimentally evaluated at various operation conditions on lab-level button cells with 2 cm2 per-cell active areas as well as on bench-scale stacks with 30 cm2 and 100 cm2 per-cell active areas. To reduce the concentration overpotentials, pore former systems were developed and engineered to optimize the microstructure and morphology of the Ni+8YSZ-based anodes. Chemically stable cathode materials, which possess good electronic and ionic conductivity and exhibit good electrocatalytic properties in both oxidizing and reducing gas atmospheres, were developed and materials properties were investigated. In order to increase the specific hydrogen production rate and thereby reduce the system volume and capital cost for commercial applications, a hybrid system that integrates the technologies of the SOFEC and the solid-oxide fuel cell (SOFC), was developed and successfully demonstrated at a 1kW scale, co-generating hydrogen and electricity directly from chemical fuels.

Tao, Greg, G.

2007-03-31T23:59:59.000Z

344

Microstructure, residual stress, and mechanical properties of thin film materials for a microfabricated solid oxide fuel cell  

E-Print Network [OSTI]

The microstructure and residual stress of sputter-deposited films for use in microfabricated solid oxide fuel cells are presented. Much of the work focuses on the characterization of a candidate solid electrolyte: Yttria ...

Quinn, David John, Sc. D. Massachusetts Institute of Technology

2006-01-01T23:59:59.000Z

345

High Temperature Superconducting Underground Cable  

SciTech Connect (OSTI)

The purpose of this Project was to design, build, install and demonstrate the technical feasibility of an underground high temperature superconducting (HTS) power cable installed between two utility substations. In the first phase two HTS cables, 320 m and 30 m in length, were constructed using 1st generation BSCCO wire. The two 34.5 kV, 800 Arms, 48 MVA sections were connected together using a superconducting joint in an underground vault. In the second phase the 30 m BSCCO cable was replaced by one constructed with 2nd generation YBCO wire. 2nd generation wire is needed for commercialization because of inherent cost and performance benefits. Primary objectives of the Project were to build and operate an HTS cable system which demonstrates significant progress towards commercial progress and addresses real world utility concerns such as installation, maintenance, reliability and compatibility with the existing grid. Four key technical areas addressed were the HTS cable and terminations (where the cable connects to the grid), cryogenic refrigeration system, underground cable-to-cable joint (needed for replacement of cable sections) and cost-effective 2nd generation HTS wire. This was the worlds first installation and operation of an HTS cable underground, between two utility substations as well as the first to demonstrate a cable-to-cable joint, remote monitoring system and 2nd generation HTS.

Farrell, Roger, A.

2010-02-28T23:59:59.000Z

346

Zero Emission Power Plants Using Solid Oxide Fuel Cells and Oxygen Transport Membranes  

SciTech Connect (OSTI)

Siemens Westinghouse Power Corp. (SWPC) is engaged in the development of Solid Oxide Fuel Cell stationary power systems. SWPC has combined DOE Developmental funds with commercial customer funding to establish a record of successful SOFC field demonstration power systems of increasing size. SWPC will soon deploy the first unit of a newly developed 250 kWe Combined Heat Power System. It will generate electrical power at greater than 45% electrical efficiency. The SWPC SOFC power systems are equipped to operate on lower number hydrocarbon fuels such as pipeline natural gas, which is desulfurized within the SOFC power system. Because the system operates with a relatively high electrical efficiency, the CO2 emissions, {approx}1.0 lb CO2/ kW-hr, are low. Within the SOFC module the desulfurized fuel is utilized electrochemically and oxidized below the temperature for NOx generation. Therefore the NOx and SOx emissions for the SOFC power generation system are near negligible. The byproducts of the power generation from hydrocarbon fuels that are released into the environment are CO2 and water vapor. This forward looking DOE sponsored Vision 21 program is supporting the development of methods to capture and sequester the CO2, resulting in a Zero Emission power generation system. To accomplish this, SWPC is developing a SOFC module design, to be demonstrated in operating hardware, that will maintain separation of the fuel cell anode gas, consisting of H2, CO, H2O and CO2, from the vitiated air. That anode gas, the depleted fuel stream, containing less than 18% (H2 + CO), will be directed to an Oxygen Transport Membrane (OTM) Afterburner that is being developed by Praxair, Inc.. The OTM is supplied air and the depleted fuel. The OTM will selectively transport oxygen across the membrane to oxidize the remaining H2 and CO. The water vapor is then condensed from the totally 1.5.DOC oxidized fuel stream exiting the afterburner, leaving only the CO2 in gaseous form. That CO2 can then be compressed and sequestered, resulting in a Zero Emission power generation system operating on hydrocarbon fuel that adds only water vapor to the environment. Praxair has been developing oxygen separation systems based on dense walled, mixed electronic, oxygen ion conducting ceramics for a number of years. The oxygen separation membranes find applications in syngas production, high purity oxygen production and gas purification. In the SOFC afterburner application the chemical potential difference between the high temperature SOFC depleted fuel gas and the supplied air provides the driving force for oxygen transport. This permeated oxygen subsequently combusts the residual fuel in the SOFC exhaust. A number of experiments have been carried out in which simulated SOFC depleted fuel gas compositions and air have been supplied to either side of single OTM tubes in laboratory-scale reactors. The ceramic tubes are sealed into high temperature metallic housings which precludes mixing of the simulated SOFC depleted fuel and air streams. In early tests, although complete oxidation of the residual CO and H2 in the simulated SOFC depleted fuel was achieved, membrane performance degraded over time. The source of degradation was found to be contaminants in the simulated SOFC depleted fuel stream. Following removal of the contaminants, stable membrane performance has subsequently been demonstrated. In an ongoing test, the dried afterburner exhaust composition has been found to be stable at 99.2% CO2, 0.4% N2 and 0.6%O2 after 350 hours online. Discussion of these results is presented. A test of a longer, commercial demonstration size tube was performed in the SWPC test facility. A similar contamination of the simulated SOFC depleted fuel stream occurred and the performance degraded over time. A second test is being prepared. Siemens Westinghouse and Praxair are collaborating on the preliminary design of an OTM equipped Afterburner demonstration unit. The intent is to test the afterburner in conjunction with a reduced size SOFC test module that has the anode gas separati

Shockling, Larry A.; Huang, Keqin; Gilboy, Thomas E. (Siemens Westinghouse Power Corporation); Christie, G. Maxwell; Raybold, Troy M. (Praxair, Inc.)

2001-11-06T23:59:59.000Z

347

High temperature liquid level sensor  

DOE Patents [OSTI]

A length of metal sheathed metal oxide cable is perforated to permit liquid access to the insulation about a pair of conductors spaced close to one another. Changes in resistance across the conductors will be a function of liquid level, since the wetted insulation will have greater electrical conductivity than that of the dry insulation above the liquid elevation.

Tokarz, Richard D. (West Richland, WA)

1983-01-01T23:59:59.000Z

348

Modeling of Solid Oxide Fuel Cell functionally graded electrodes and a feasibility study of fabrication techniques for functionally graded electrodes.  

E-Print Network [OSTI]

??Currently, Solid Oxide Fuel Cell (SOFC) electrodes have not been explored for optimization of graded electrodes and nonlinear functional grading. In this work, a complete (more)

Flesner, Reuben

2009-01-01T23:59:59.000Z

349

Grain-size effects in nanoscaled electrolyte and cathode thin films for solid oxide fuel cells (SOFC).  

E-Print Network [OSTI]

??Due to their high energy conversion efficiencies and low emissions, Solid Oxide Fuel Cells (SOFCs) show promise as a replacement for combustion-based electrical generators at (more)

Peters, Christoph

2009-01-01T23:59:59.000Z

350

Steady state thermal stress analyses of two-dimensional and three-dimensional solid oxide fuel cells.  

E-Print Network [OSTI]

??Fuel cells are electrochemical devices which convert fuels directly into electrical energy without combustion. The Solid Oxide Fuel Cell (SOFC) is the most promising energy (more)

Valluru, Srividya.

2005-01-01T23:59:59.000Z

351

New materials for intermediate-temperature solid oxide fuel cells to be powered by carbon- and sulfur-containing fuels.  

E-Print Network [OSTI]

??Unlike polymer electrolyte fuel cells, solid-oxide fuel cells (SOFCs) have the potential to use a wide variety of fuels, including hydrocarbons and gasified coal or (more)

Yang, Lei

2011-01-01T23:59:59.000Z

352

NETL: News Release - Solid Oxide Fuel Cell Successfully Powers Truck Cab  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

9, 2009 9, 2009 Solid Oxide Fuel Cell Successfully Powers Truck Cab and Sleeper in DOE-Sponsored Test DOE, Delphi, Peterbilt Join to Test Auxiliary Power Unit for Commercial Trucks Washington, DC -In a test sponsored by the U.S. Department of Energy (DOE), a Delphi auxiliary power unit employing a solid oxide fuel cell (SOFC) successfully operated the electrical system and air conditioning of a Peterbilt Model 386 truck under conditions simulating idling conditions for 10 hours. The device provides an alternative to running a truck's main diesel engine, or using a truck's batteries, to power auxiliary electrical loads during rest periods, thereby lowering emissions, reducing noise, and saving fuel. Solid Oxide Fuel Cell Successfully Powers Truck Cab and Sleeper in DOE-Sponsored Test

353

Proton Conductor based Solid Oxide Fuel Cells Ceramatec, Inc., Salt Lake City, UT 84119  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

based Solid Oxide Fuel Cells based Solid Oxide Fuel Cells Ceramatec, Inc., Salt Lake City, UT 84119 S. (Elango) Elangovan, Joseph Hartvigsen, Insoo Bay, and Feng Zhao High efficiency operation is one of the primary attractions to use solid oxide fuel cells as the energy conversion device. High efficiency requires maximizing of the product of operating voltage and fuel utilization. The maximum possible operating voltage however is limited by the Nernst potential near the fuel exhaust. In oxygen conducting electrolyte based fuel cells (O-SOFC) as the fuel utilization increases, the Nernst potential continues to decrease with the dilution of fuel by the reaction products. In contrast, in a proton conducting electrolyte based fuel cell (P-SOFC) the reaction product is formed on the cathode side allowing for high operating voltage at high fuel

354

Ultra High Temperature | Open Energy Information  

Open Energy Info (EERE)

Ultra High Temperature Ultra High Temperature Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Print PDF Sanyal Temperature Classification: Ultra High Temperature Dictionary.png Ultra High Temperature: No definition has been provided for this term. Add a Definition Sanyal Temp Classification This temperature scheme was developed by Sanyal in 2005 at the request of DOE and GEA, as reported in Classification of Geothermal Systems: A Possible Scheme. Extremely Low Temperature Very Low Temperature Low Temperature Moderate Temperature High Temperature Ultra High Temperature Steam Field Reservoir fluid greater than 300°C is considered by Sanyal to be "ultra high temperature". "Such reservoirs are characterized by rapid development of steam saturation in the reservoir and steam fraction in the mobile fluid phase upon

355

High temperature alkali corrosion of ceramics in coal gas  

SciTech Connect (OSTI)

The high temperature alkali corrosion kinetics of SiC have been systematically investigated from 950 to 1100[degrees]C at 0.63 vol % alkali vapor concentration. The corrosion rate in the presence of alkaliis approximately 10[sup 4] to 10[sup 5] times faster than the oxidation rate of SiC in air. The activation energy associated with the alkali corrosion is 406 kJ/mol, indicating a highly temperature-dependent reaction rate. The rate-controlling step of the overall reaction is likely to be the dissolution of silica in the sodium silicate liquid, based on the oxygen diffusivity data.

Pickrell, G.R.; Sun, T.; Brown, J.J.

1992-02-24T23:59:59.000Z

356

Compliant alkali silicate sealing glass for solid oxide fuel cell applications: thermal cycle stability and chemical compatibility  

SciTech Connect (OSTI)

An alkali silicate glass (SCN-1) is currently being evaluated as a candidate sealing glass for solid oxide fuel (SOFC) applications. The glass containing ~17 mole% alkalis (K2O and Na2O) remains vitreous and compliant during SOFC operation, unlike conventional SOFC sealing glasses, which experience substantial devitrification after the sealing process. The non-crystallizing compliant sealing glass has lower glass transition and softening temperatures since the microstructure remains glassy without significant crystallite formation, and hence can relieve or reduce residual stresses and also has the potential for crack healing. Sealing approaches based on compliant glass will also need to satisfy all the mechanical, thermal, chemical, physical, and electrical requirements for SOFC applications, not only in bulk properties but also at sealing interfaces. In this first of a series of papers we will report the thermal cycle stability of the glass when sealed between two SOFC components, i.e., a NiO/YSZ anode supported YSZ bilayer and a coated ferritic stainless steel interconnect material. High temperature leak rates were monitored versus thermal cycles between 700-850oC using back pressures ranging from 0.2 psi to 1.0 psi. Isothermal stability was also evaluated in a dual environment consisting of flowing dilute H2 fuel versus ambient air. In addition, chemical compatibility at the alumina and YSZ interfaces was examined with scanning electron microscopy and energy dispersive spectroscopy. The results shed new light on the topic of SOFC glass seal development.

Chou, Y. S.; Thomsen, Edwin C.; Williams, Riley T.; Choi, Jung-Pyung; Canfield, Nathan L.; Bonnett, Jeff F.; Stevenson, Jeffry W.; Shyam, Amit; Lara-Curzio, E.

2011-03-01T23:59:59.000Z

357

Electrochemical investigations of various high-temperature superconductor phases  

Science Journals Connector (OSTI)

Electrochemical investigations of various high-temperature superconductor phases ... Electrochemistry of High-Temperature Superconductors ...

David R. Riley; A. Manthiram; John T. McDevitt

1992-11-01T23:59:59.000Z

358

High temperature solar selective coatings  

DOE Patents [OSTI]

Improved solar collectors (40) comprising glass tubing (42) attached to bellows (44) by airtight seals (56) enclose solar absorber tubes (50) inside an annular evacuated space (54. The exterior surfaces of the solar absorber tubes (50) are coated with improved solar selective coatings {48} which provide higher absorbance, lower emittance and resistance to atmospheric oxidation at elevated temperatures. The coatings are multilayered structures comprising solar absorbent layers (26) applied to the meta surface of the absorber tubes (50), typically stainless steel, topped with antireflective Savers (28) comprising at least two layers 30, 32) of refractory metal or metalloid oxides (such as titania and silica) with substantially differing indices of refraction in adjacent layers. Optionally, at least one layer of a noble metal such as platinum can be included between some of the layers. The absorbent layers cars include cermet materials comprising particles of metal compounds is a matrix, which can contain oxides of refractory metals or metalloids such as silicon. Reflective layers within the coating layers can comprise refractory metal silicides and related compounds characterized by the formulas TiSi. Ti.sub.3SiC.sub.2, TiAlSi, TiAN and similar compounds for Zr and Hf. The titania can be characterized by the formulas TiO.sub.2, Ti.sub.3O.sub.5. TiOx or TiO.sub.xN.sub.1-x with x 0 to 1. The silica can be at least one of SiO.sub.2, SiO.sub.2x or SiO.sub.2xN.sub.1-x with x=0 to 1.

Kennedy, Cheryl E

2014-11-25T23:59:59.000Z

359

Inhibition of plasmonically enhanced interdot energy transfer in quantum dot solids via photo-oxidation  

SciTech Connect (OSTI)

We studied the impact of photophysical and photochemical processes on the interdot Forster energy transfer in monodisperse CdSe/ZnS quantum dot solids. For this, we investigated emission spectra of CdSe/ZnS quantum dot solids in the vicinity of gold metallic nanoparticles coated with chromium oxide. The metallic nanoparticles were used to enhance the rate of the energy transfer between the quantum dots, while the chromium oxide coating led to significant increase of their photo-oxidation rates. Our results showed that irradiation of such solids with a laser beam can lead to unique spectral changes, including narrowing and blue shift. We investigate these effects in terms of inhibition of the plasmonically enhanced interdot energy transfer between quantum dots via the chromium-oxide accelerated photo-oxidation process. We demonstrate this considering energy-dependent rate of the interdot energy transfer process, plasmonic effects, and the way photo-oxidation enhances non-radiative decay rates of quantum dots with different sizes.

Sadeghi, S. M. [Department of Physics, University of Alabama in Huntsville, Huntsville, Alabama 35899 (United States); Nano and Micro Device Center, University of Alabama in Huntsville, Huntsville, Alabama 35899 (United States); Nejat, A.; West, R. G. [Department of Physics, University of Alabama in Huntsville, Huntsville, Alabama 35899 (United States)

2012-11-15T23:59:59.000Z

360

TEST RESULTS OF HIGH TEMPERATURE STEAM/CO2 CO-ELECTROLYSIS IN A 10-CELL STACK  

SciTech Connect (OSTI)

High temperature coelectrolysis experiments with CO2 / H2O mixtures were performed in a 10-cell planar solid oxide stack. Results indicated that stack apparent ASR values were shown not to vary significantly between pure steam electrolysis and steam / CO2 coelectrolysis values. Product gas compositions measured via an online micro gas chromatograph (GC) showed excellent agreement to predictions obtained from a chemical equilibrium coelectrolysis model developed for this study. Experimentally determined open cell potentials and thermal neutral voltages for coelectrolysis compared favorably to predictions obtained from a chemical equilibrium coelectrolysis and energy balance model, also developed for this study.

James E. O'Brien; Joseph J. Hartvigsen

2007-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "high-temperature solid oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

High Performance Ceramic Interconnect Material for Solid Oxide Fuel Cells (SOFCs): Ca- and Transition Metal-doped Yttrium Chromite  

SciTech Connect (OSTI)

The effect of transition metal substitution on thermal and electrical properties of Ca-doped yttrium chromite was investigated in relation to use as a ceramic interconnect in high temperature solid oxide fuel cells (SOFCs). 10 at% Co, 4 at% Ni, and 1 at% Cu substitution on B-site of 20 at% Ca-doped yttrium chromite led to a close match of thermal expansion coefficient (TEC) with that of 8 mol% yttria-stabilized zirconia (YSZ), and a single phase Y0.8Ca0.2Cr0.85Co0.1Ni0.04Cu0.01O3 remained stable between 25 and 1100 degree C over a wide oxygen partial pressure range. Doping with Cu significantly facilitated densification of yttrium chromite. Ni dopant improved both electrical conductivity and dimensional stability in reducing environments, likely through diminishing the oxygen vacancy formation. Substitution with Co substantially enhanced electrical conductivity in oxidizing atmosphere, which was attributed to an increase in charge carrier density and hopping mobility. Electrical conductivity of Y0.8Ca0.2Cr0.85Co0.1Ni0.04Cu0.01O3 at 900 degree C is 57 S/cm in air and 11 S/cm in fuel (pO2=510^-17 atm) environments. Chemical compatibility of doped yttrium chromite with other cell components was verified at the processing temperatures. Based on the chemical and dimensional stability, sinterability, and thermal and electrical properties, Y0.8Ca0.2Cr0.85Co0.1Ni0.04Cu0.01O3 is suggested as a promising SOFC ceramic interconnect to potentially overcome technical limitations of conventional acceptor-doped lanthanum chromites.

Yoon, Kyung J.; Stevenson, Jeffry W.; Marina, Olga A.

2011-10-15T23:59:59.000Z

362

HIGH-TEMPERATURE ELECTROLYSIS FOR LARGE-SCALE HYDROGEN AND SYNGAS PRODUCTION FROM NUCLEAR ENERGY SYSTEM SIMULATION AND ECONOMICS  

SciTech Connect (OSTI)

A research and development program is under way at the Idaho National Laboratory (INL) to assess the technological and scale-up issues associated with the implementation of solid-oxide electrolysis cell technology for efficient high-temperature hydrogen production from steam. This work is supported by the US Department of Energy, Office of Nuclear Energy, under the Nuclear Hydrogen Initiative. This paper will provide an overview of large-scale system modeling results and economic analyses that have been completed to date. System analysis results have been obtained using the commercial code UniSim, augmented with a custom high-temperature electrolyzer module. Economic analysis results were based on the DOE H2A analysis methodology. The process flow diagrams for the system simulations include an advanced nuclear reactor as a source of high-temperature process heat, a power cycle and a coupled steam electrolysis loop. Several reactor types and power cycles have been considered, over a range of reactor outlet temperatures. Pure steam electrolysis for hydrogen production as well as coelectrolysis for syngas production from steam/carbon dioxide mixtures have both been considered. In addition, the feasibility of coupling the high-temperature electrolysis process to biomass and coal-based synthetic fuels production has been considered. These simulations demonstrate that the addition of supplementary nuclear hydrogen to synthetic fuels production from any carbon source minimizes emissions of carbon dioxide during the production process.

J. E. O'Brien; M. G. McKellar; E. A. Harvego; C. M. Stoots

2009-05-01T23:59:59.000Z

363

Apparatus tube configuration and mounting for solid oxide fuel cells  

DOE Patents [OSTI]

A generator apparatus (10) is made containing long, hollow, tubular, fuel cells containing an inner air electrode (64), an outer fuel electrode (56), and solid electrolyte (54) therebetween, placed between a fuel distribution board (29) and a board (32) which separates the combustion chamber (16) from the generating chamber (14), where each fuel cell has an insertable open end and in insertable, plugged, closed end (44), the plugged end being inserted into the fuel distribution board (29) and the open end being inserted through the separator board (32) where the plug (60) is completely within the fuel distribution board (29).

Zymboly, Gregory E. (Murrysville, PA)

1993-01-01T23:59:59.000Z

364

Nanostructured High Temperature Bulk Thermoelectric Energy Conversion...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Efficient Automotive Waste Heat Recovery Multi-physics modeling of thermoelectric generators for waste heat recovery applications Nanostructured High-Temperature Bulk...

365

High Temperature Thermoelectric Materials Characterization for...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

2009 -- Washington D.C. lmp06wang.pdf More Documents & Publications High-Temperature Thermoelectric Materials Characterization for Automotive Waste Heat Recovery: Success...

366

Materials Characterization Capabilities at the High Temperature...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Laboratory and HTML User Program Success Stories Materials Characterization Capabilities at the High Temperature Materials Laboratory: Focus on Carbon Fiber and Composites...

367

High Temperature Materials Laboratory (HTML) - PSD Directorate  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

filler A National Resource for Collaborative Materials Research The High Temperature Materials Laboratory (HTML) User Program is on hiatus due to federal budget reductions....

368

A Planar Anode -Supported Solid Oxide Fuel Cell Model with Internal Reforming of Natural Gas  

E-Print Network [OSTI]

1 A Planar Anode - Supported Solid Oxide Fuel Cell Model with Internal Reforming of Natural Gas of natural gas has been developed. The model simultaneously solves mass, energy transport equations emission level, and multiple fuel utilization. SOFC can operate with various kinds of fuels such as natural

Boyer, Edmond

369

Bipolar Plate-Supported Solid Oxide Fuel Cell J. D. Carter, T. Cruse, J. Ralph,  

E-Print Network [OSTI]

Bipolar Plate-Supported Solid Oxide Fuel Cell "TuffCell" J. D. Carter, T. Cruse, J. Ralph, R. Kumar, and D. Myers Argonne National Laboratory Argonne, IL 2003 Annual Review DOE Fuel Cells Program May 19;Metallic Bipolar-Plate-Supported SOFC Design (TuffCell) Fuel flow field (metal) Air flow field (metal

370

Influence of NaCl on cathode performance of solid oxide fuel cells  

Science Journals Connector (OSTI)

Degradation induced by sodium chloride in air was...0.8Sr0.2)0.98MnO3(LSM) and La0.6Sr0.4Co0.2Fe0.8O3(LSCF) cathodes in solid oxide fuel cells(SOFC). Cell performance was measured by volatilizing NaCl to...2...fo...

Run-ru Liu; De-jun Wang; Jing Leng

2013-08-01T23:59:59.000Z

371

Solid oxide fuel cell systems with hot zones having improved reactant distribution  

DOE Patents [OSTI]

A Solid Oxide Fuel Cell (SOFC) system having a hot zone with a center cathode air feed tube for improved reactant distribution, a CPOX reactor attached at the anode feed end of the hot zone with a tail gas combustor at the opposing end for more uniform heat distribution, and a counter-flow heat exchanger for efficient heat retention.

Poshusta, Joseph C.; Booten, Charles W.; Martin, Jerry L.

2012-11-06T23:59:59.000Z

372

Application of Atomic Layer Deposition of Platinum to Solid Oxide Fuel Cells  

Science Journals Connector (OSTI)

Application of Atomic Layer Deposition of Platinum to Solid Oxide Fuel Cells ... (4, 5, 8-10) Therefore, the electrode material requires particular attention in the development and optimization of low-temperature SOFCs. ... Enormous Plasmonic Enhancement and Suppressed Quenching of Luminescence from Nanoscale ZnO Films by Uniformly Dispersed Atomic-Layer-Deposited Platinum with Optimized Spacer Thickness ...

Xirong Jiang; Hong Huang; Friedrich B. Prinz; Stacey F. Bent

2008-05-23T23:59:59.000Z

373

Assessment of the Distributed Generation Market Potential for Solid Oxide Fuel Cells  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the Distributed the Distributed Generation Market Potential for Solid Oxide Fuel Cells September 29, 2013 DOE/NETL- 342/093013 NETL Contact: Katrina Krulla Analysis Team: Arun Iyengar, Dale Keairns, Dick Newby Contributors: Walter Shelton, Travish Shulltz, Shailesh Vora OFFICE OF FOSSIL ENERGY Table of Contents Executive Summary .........................................................................................................................1 1 Introduction ...................................................................................................................................2 2 DG Market Opportunity ................................................................................................................3 3 SOFC Technology Development Plan ..........................................................................................6

374

Efficient reversible electrodes for solid oxide electrolyzer cells  

DOE Patents [OSTI]

An electrolyzer cell is disclosed which includes a cathode to reduce an oxygen-containing molecule, such as H2O, CO2, or a combination thereof, to produce an oxygen ion and a fuel molecule, such as H2, CO, or a combination thereof. An electrolyte is coupled to the cathode to transport the oxygen ion to an anode. The anode is coupled to the electrolyte to receive the oxygen ion and produce oxygen gas therewith. In one embodiment, the anode may be fabricated to include an electron-conducting phase having a perovskite crystalline structure or structure similar thereto. This perovskite may have a chemical formula of substantially (Pr(1-x)Lax)(z-y)A'yBO(3-.differential.), wherein 0.ltoreq.x.ltoreq.0.5, 0.ltoreq.y.ltoreq.0.5, and 0.8.ltoreq.z.ltoreq.1.1. In another embodiment, the cathode includes an electron-conducting phase that contains nickel oxide intermixed with magnesium oxide.

Elangovan, Singaravelu (South Jordan, UT); Hartvigsen, Joseph J. (Kaysville, UT)

2011-07-12T23:59:59.000Z

375

Hybrid deposition of thin film solid oxide fuel cells and electrolyzers  

DOE Patents [OSTI]

The use of vapor deposition techniques enables synthesis of the basic components of a solid oxide fuel cell (SOFC); namely, the electrolyte layer, the two electrodes, and the electrolyte-electrode interfaces. Such vapor deposition techniques provide solutions to each of the three critical steps of material synthesis to produce a thin film solid oxide fuel cell (TFSOFC). The electrolyte is formed by reactive deposition of essentially any ion conducting oxide, such as defect free, yttria stabilized zirconia (YSZ) by planar magnetron sputtering. The electrodes are formed from ceramic powders sputter coated with an appropriate metal and sintered to a porous compact. The electrolyte-electrode interface is formed by chemical vapor deposition of zirconia compounds onto the porous electrodes to provide a dense, smooth surface on which to continue the growth of the defect-free electrolyte, whereby a single fuel cell or multiple cells may be fabricated. 8 figs.

Jankowski, A.F.; Makowiecki, D.M.; Rambach, G.D.; Randich, E.

1998-05-19T23:59:59.000Z

376

Hybrid deposition of thin film solid oxide fuel cells and electrolyzers  

DOE Patents [OSTI]

The use of vapor deposition techniques enables synthesis of the basic components of a solid oxide fuel cell (SOFC); namely, the electrolyte layer, the two electrodes, and the electrolyte-electrode interfaces. Such vapor deposition techniques provide solutions to each of the three critical steps of material synthesis to produce a thin film solid oxide fuel cell (TFSOFC). The electrolyte is formed by reactive deposition of essentially any ion conducting oxide, such as defect free, yttria stabilized zirconia (YSZ) by planar magnetron sputtering. The electrodes are formed from ceramic powders sputter coated with an appropriate metal and sintered to a porous compact. The electrolyte-electrode interface is formed by chemical vapor deposition of zirconia compounds onto the porous electrodes to provide a dense, smooth surface on which to continue the growth of the defect-free electrolyte, whereby a single fuel cell or multiple cells may be fabricated.

Jankowski, Alan F. (Livermore, CA); Makowiecki, Daniel M. (Livermore, CA); Rambach, Glenn D. (Livermore, CA); Randich, Erik (Endinboro, PA)

1998-01-01T23:59:59.000Z

377

Hybrid deposition of thin film solid oxide fuel cells and electrolyzers  

DOE Patents [OSTI]

The use of vapor deposition techniques enables synthesis of the basic components of a solid oxide fuel cell (SOFC); namely, the electrolyte layer, the two electrodes, and the electrolyte-electrode interfaces. Such vapor deposition techniques provide solutions to each of the three critical steps of material synthesis to produce a thin film solid oxide fuel cell (TFSOFC). The electrolyte is formed by reactive deposition of essentially any ion conducting oxide, such as defect free, yttria stabilized zirconia (YSZ) by planar magnetron sputtering. The electrodes are formed from ceramic powders sputter coated with an appropriate metal and sintered to a porous compact. The electrolyte-electrode interface is formed by chemical vapor deposition of zirconia compounds onto the porous electrodes to provide a dense, smooth surface on which to continue the growth of the defect-free electrolyte, whereby a single fuel cell or multiple cells may be fabricated.

Jankowski, Alan F. (Livermore, CA); Makowiecki, Daniel M. (Livermore, CA); Rambach, Glenn D. (Livermore, CA); Randich, Erik (Endinboro, PA)

1999-01-01T23:59:59.000Z

378

Thermomechanical Cyclic Response of TiNiPd High-Temperature Shape Memory Alloys  

E-Print Network [OSTI]

TiNiPd high-temperature shape memory alloys (HTSMAs) have attracted considerable attention as potential solid-state actuators capable of operating at temperatures up to 500 C, exhibiting excellent corrosion resistance, adequate ductility levels...

Atli, Kadri

2012-10-19T23:59:59.000Z

379

Recent developments in high-temperature photonic crystals for energy conversion  

E-Print Network [OSTI]

After decades of intense studies focused on cryogenic and room temperature nanophotonics, scientific interest is also growing in high-temperature nanophotonics aimed at solid-state energy conversion. These latest extensive ...

Rinnerbauer, Veronika

380

High Temperature Solar Splitting of Methane  

E-Print Network [OSTI]

-term commercialization opportunities #12;Why Use Solar Energy?Why Use Solar Energy? · High concentrations possible (>1000High Temperature Solar Splitting of Methane to Hydrogen and Carbon High Temperature Solar Splitting and worldwide) ­ Sufficient to power the world (if we choose to) · Advantages tradeoff against collection area

Note: This page contains sample records for the topic "high-temperature solid oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

QED3 Theory of High Temperature Superconductors  

E-Print Network [OSTI]

QED3 Theory of High Temperature Superconductors Zlatko Tesanovi´c The Johns Hopkins University is The Problem in high Tc superconductors? · Superconducting state appears dx2-y2 "BCS-like". Low energy: · Today, everything seems to be a high temperature superconduc- tor (cuprates, C60's, MgB2

Tesanovic, Zlatko

382

TESTING AND PERFORMANCE ANALYSIS OF NASA 5 CM BY 5 CM BI-SUPPORTED SOLID OXIDE ELECTROLYSIS CELLS OPERATED IN BOTH FUEL CELL AND STEAM ELECTROLYSIS MODES  

SciTech Connect (OSTI)

A series of 5 cm by 5 cm bi-supported Solid Oxide Electrolysis Cells (SOEC) were produced by NASA for the Idaho National Laboratory (INL) and tested under the INL High Temperature Steam Electrolysis program. The results from the experimental demonstration of cell operation for both hydrogen production and operation as fuel cells is presented. An overview of the cell technology, test apparatus and performance analysis is also provided. The INL High Temperature Steam Electrolysis laboratory has developed significant test infrastructure in support of single cell and stack performance analyses. An overview of the single cell test apparatus is presented. The test data presented in this paper is representative of a first batch of NASA's prototypic 5 cm by 5 cm SOEC single cells. Clearly a significant relationship between the operational current density and cell degradation rate is evident. While the performance of these cells was lower than anticipated, in-house testing at NASA Glenn has yielded significantly higher performance and lower degradation rates with subsequent production batches of cells. Current post-test microstructure analyses of the cells tested at INL will be published in a future paper. Modification to cell compositions and cell reduction techniques will be altered in the next series of cells to be delivered to INL with the aim to decrease the cell degradation rate while allowing for higher operational current densities to be sustained. Results from the testing of new batches of single cells will be presented in a future paper.

R. C. O'Brien; J. E. O'Brien; C. M. Stoots; X. Zhang; S. C. Farmer; T. L. Cable; J. A. Setlock

2011-11-01T23:59:59.000Z

383

Candidate alloys for cost-effective, high-efficiency, high-temperature compact/foil heat-exchangers  

SciTech Connect (OSTI)

Solid oxide fuel cell (SOFC) and molten carbonate fuel cell (MCFC) systems operate at high temperatures (up to 1000 C and 650 C, respectively), which makes them especially attractive sources for combined heat and power (CHP) cogeneration. However, improvements in the efficiency of heat exchange in these fuel cells require both development and careful processing of advanced cost-effective alloys for use in such high-temperature service conditions. The high-temperature properties of both sheet and foil forms of several alloys being considered for use in compact heat-exchangers (recuperators) have been characterized. Mechanical and creep-rupture testing, oxidation studies, and microstructural studies have been performed on commercially available sheet and foil forms of alloy 347, alloys 625, HR230, HR120, and the new AL20-25+Nb. These studies have led to a mechanistic understanding of the responses of these alloys to anticipated service conditions, and suggest that these alloys developed for gas- and micro-turbine recuperator applications are also suitable for use in fuel cell heat-exchangers. Additional work is still required to achieve foil forms with creep life comparable to thicker-section wrought product forms of the same alloys.

Evans, Neal D [ORNL; Maziasz, Philip J [ORNL; Shingledecker, John P [ORNL; Pint, Bruce A [ORNL; Yamamoto, Yukinori [ORNL

2007-01-01T23:59:59.000Z

384

Thin-film heterostructure solid oxide fuel cells  

Science Journals Connector (OSTI)

A micro thin-filmsolid oxide fuel cell (TFSOFC) has been designed based on thin-filmdeposition and microlithographic processes. The TFSOFC is composed of a thin-filmelectrolyte grown on a nickel foil substrate and a thin-filmcathodedeposited on the electrolyte. The Ni foil substrate is then processed into a porous anode by photolithographic patterning and etching to develop pores for gas transport into the fuel cell. A La 0.5 Sr 0.5 CoO 3 (LSCO) thin-filmcathode is then deposited on the electrolyte and a porous NiOYSZ cermet layer is added to the anode to improve the electrode performance. The TFSOFC has stably operated in a temperature ranges as low as 480570?C significantly lower than bulk SOFCs and has yielded a maximum output power density of ?110? mW/cm 2 in that temperature range.

X. Chen; N. J. Wu; L. Smith; A. Ignatiev

2004-01-01T23:59:59.000Z

385

Sealed glass coating of high temperature ceramic superconductors  

DOE Patents [OSTI]

A method and article of manufacture of a lead oxide based glass coating on a high temperature superconductor. The method includes preparing a dispersion of glass powders in a solution, applying the dispersion to the superconductor, drying the dispersion before applying another coating and heating the glass powder dispersion at temperatures below oxygen diffusion onset and above the glass melting point to form a continuous glass coating on the superconductor to establish compressive stresses which enhance the fracture strength of the superconductor.

Wu, Weite (Tainan, TW); Chu, Cha Y. (Garnerville, NY); Goretta, Kenneth C. (Downers Grove, IL); Routbort, Jules L. (Darien, IL)

1995-01-01T23:59:59.000Z

386

Hole doping in high temperature superconductors using the XANES technique  

E-Print Network [OSTI]

Hole doping in high temperature superconductors using the1994 Thallium-Based High Temperature Superconductors ed A M1994 Thallium-Based High Temperature Superconductors ed A M

Hamdan, Nasser

2012-01-01T23:59:59.000Z

387

Welding of dissimilar alloys for high temperature heat exchangers for SOFC  

SciTech Connect (OSTI)

Reduction in the cost of balance of plant applications is one of the top priority focus areas for the successful implementation of solid oxide fuel cell technology. High temperature heat exchangers are employed to heat cathode air utilizing either hot gases coming from the anode side of the stack or other hot gases generated by external processes. In order to reduce the cost of heat exchangers, it may be necessary to apply several different materials, each in a different temperature zone, for the construction of the heat exchanger. This technique would require the joining of dissimilar materials in the construction. In this work, welding of commercial candidate dissimilar materials is explored. Filler materials were identified using equilibrium phase diagrams and thermodynamic simulation software. Autogenous welding was performed and the welding defects were characterized. Finally, experimental weld microstructures were compared to phases predicted by the simulations.

Wilson, R.D.; Hatem, J.; Dogan, O.N.; King, P.E.

2006-10-01T23:59:59.000Z

388

Journal of Power Sources 153 (2006) 6875 Numerical study of a flat-tube high power density solid oxide fuel cell  

E-Print Network [OSTI]

power density (HPD) solid oxide fuel cell (SOFC) is a geometry based on a tubular type SOFC: Flat-tube; High power density (HPD); Solid oxide fuel cell (SOFC); Simulation; Performance; Optimization 1. Introduction A solid oxide fuel cell (SOFC), like any other fuel cell, produces electrical

389

Transient thermal behaviour of a solid oxide fuel cell Moussa Chnani, Marie-Ccile Pra, Raynal Glises, Jean Marie Kauffmann and  

E-Print Network [OSTI]

Transient thermal behaviour of a solid oxide fuel cell Moussa Chnani, Marie-Cécile Péra, Raynal provided by HTceramix. Keywords: Solid oxide fuel cell; Transient thermal modelling; Fluidic and Electrochemical modelling. 1- Introduction The solid oxide fuel cell (SOFC) is a promising technology

Paris-Sud XI, Université de

390

A thermally self-sustained micro-power plant with integrated micro-solid oxide fuel cells, micro-reformer and functional  

E-Print Network [OSTI]

A thermally self-sustained micro-power plant with integrated micro-solid oxide fuel cells, micro Micro-solid oxide fuel cell Thin films Butane reformation Chemical micro-reactors Thermally independent 2014 Accepted 8 February 2014 Available online xxx a b s t r a c t Low temperature micro-solid oxide

Daraio, Chiara

391

Symposium on high temperature and materials chemistry  

SciTech Connect (OSTI)

This volume contains the written proceedings of the Symposium on High Temperature and Materials Chemistry held in Berkeley, California on October 24--25, 1989. The Symposium was sponsored by the Materials and Chemical Sciences Division of Lawrence Berkeley Laboratory and by the College of Chemistry of the University of California at Berkeley to discuss directions, trends, and accomplishments in the field of high temperature and materials chemistry. Its purpose was to provide a snapshot of high temperature and materials chemistry and, in so doing, to define status and directions.

Not Available

1989-10-01T23:59:59.000Z

392

Redox instability, mechanical deformation, and heterogeneous damage accumulation in solid oxide fuel cell anodes  

Science Journals Connector (OSTI)

Mechanical integrity and damage tolerance represent two key challenges in the design of solid oxide fuel cells(SOFCs). In particular reduction and oxidation(redox) cycles and the associated large transformation strains have a notable impact on the mechanical stability and failure mode of SOFCanodes. In this study the deformation behavior under redox cycling is investigated computationally with an approach that provides a detailed microstructurally based view of heterogeneous damage accumulation behavior within an experimentally obtained nickel/yttria stabilized zirconia SOFCanode microstructure. Simulation results underscore the critical role that the microstructure plays in the mechanical deformation behavior of and failure within such materials.

F. Abdeljawad; G. J. Nelson; W. K. S. Chiu; M. Haataja

2012-01-01T23:59:59.000Z

393

Fuel electrode containing pre-sintered nickel/zirconia for a solid oxide fuel cell  

DOE Patents [OSTI]

A fuel cell structure (2) is provided, having a pre-sintered nickel-zirconia fuel electrode (6) and an air electrode (4), with a ceramic electrolyte (5) disposed between the electrodes, where the pre-sintered fuel electrode (6) contains particles selected from the group consisting of nickel oxide, cobalt and cerium dioxide particles and mixtures thereof, and titanium dioxide particles, within a matrix of yttria-stabilized zirconia and spaced-apart filamentary nickel strings having a chain structure, and where the fuel electrode can be sintered to provide an active solid oxide fuel cell.

Ruka, Roswell J. (Pittsburgh, PA); Vora, Shailesh D. (Monroeville, PA)

2001-01-01T23:59:59.000Z

394

Neptunium(V) Partitioning to Uranium(VI) Oxide and Peroxide Solids  

Science Journals Connector (OSTI)

Secondary uranium (U) solids are expected to be the long-term solubility limiting phases in cases of subsurface U contamination (1) and at geological repository sites for the disposal of U-based spent nuclear fuel (SNF) (2). ... Under the moist, oxidizing environment expected at Yucca Mountain, the proposed repository site in the United States, a paragenetic sequence of hexavalent U oxides and silicates is expected to form (4). ... Primary funding for this work was provided by the U.S. Department of Energy's (DOE) Office of Science Basic Energy Sciences program under contract DE-FG02-01ER15138. ...

Matthew Douglas; Sue B. Clark; Judah I. Friese; Bruce W. Arey; Edgar C. Buck; Brady D. Hanson

2005-05-04T23:59:59.000Z

395

Microsoft PowerPoint - High Temperature Thermoelectric_Ohuchi  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Thermoelectric Oxides Engineered Thermoelectric Oxides Engineered at Multiple Length Scales for Energy Harvesting Program Manager: Patricia Rawls Fumio S. Ohuchi (PI) and Rajendra K. Bordia(Co-PI) Department of Materials Science and Engineering University of Washington Box 352120 Seattle, WA 98195 Grant No. DE-FE0007272 (June 1, 2012-May 31, 2013) Graduate Students: Christopher Dandeneau and YiHsun Yang June 10, 2013 The UCR Contractors Review Conference Introduction/Motivation for Research * Thermoelectric (TE) oxides for waste heat recovery  Good high-temperature stability  Stable in hostile environments  Low cost/toxicity * Oxides with complex structure:  Low thermal conductivity,   Tailor stoichiometry to maximize S

396

An internal winding high temperature heater  

Science Journals Connector (OSTI)

An internal winding high temperature heater ... General principles are outlined for the construction of compact heaters that are suitable for heating small containers or reaction vessels at constant temperature and up to about 1000 C. ...

A. J. Delbouille; E. G. Derouane

1973-01-01T23:59:59.000Z

397

Noise Absorbing High-Temperature Insulation  

Science Journals Connector (OSTI)

Until recently simple heat shields on the engine, in the engine space or on the subframe of a vehicle had given protection against radiant heat from hot components. Today, complex high-temperature insulation syst...

Peter Cappellucci

2013-07-01T23:59:59.000Z

398

Thermodynamics of high-temperature nuclear fuel  

Science Journals Connector (OSTI)

A method for performing a thermodynamic analysis of the high-temperature nuclear fuel using the ASTA computer program is substantiated. Calculations of the chemical composition and pressure of the gas phase of...

I. A. Belov; A. S. Ivanov

399

Enhanced Power Stability for Proton Conducting Solid Oxides Fuel Cells  

SciTech Connect (OSTI)

In order to provide the basis for a rational approach to improving the performance of Y-doped BaZrO{sub 3} electrolytes for proton conducting ceramic fuel cells, we carried out a series of coupled computational and experimental studies to arrive at a consensus view of the characteristics affecting the proton conductivity of these systems. The computational part of the project developed a practical first principles approach to predicting the proton mobility as a function of temperature and doping for polycrystalline systems. This is a significant breakthrough representing the first time that first principles methods have been used to study diffusion across grain boundaries in such systems. The basis for this breakthrough was the development of the ReaxFF reactive force field that accurately describes the structure and energetics of Y-doped BaZrO{sub 3} as the proton hops from site to site. The ReaxFF parameters are all derived from an extensive set of quantum mechanics calculations on various clusters, two dimensionally infinite slabs, and three dimensionally infinite periodic systems for combinations of metals, metal alloys, metal oxides, pure and Y-doped BaZrO{sub 3}, including chemical reaction pathways and proton transport pathways, structures. The ReaxFF force field enables molecular dynamics simulations to be carried out quickly for systems with {approx} 10,000 atoms rather than the {approx}100 or so practical for QM. The first 2.5 years were spent on developing and validating the ReaxFF and we have only had an opportunity to apply these methods to only a few test cases. However these simulations lead to transport properties (diffusion coefficients and activation energy) for multi-granular systems in good agreement with current experimental results. Now that we have validated the ReaxFF for diffusion across grain boundaries, we are in the position of being able to use computation to explore strategies to improve the diffusion of protons across grain boundaries, which both theory and experiment agree is the cause of the low conductivity of multi-granular systems. Our plan for a future project is to use the theory to optimize the additives and processing conditions and following this with experiment on the most promising systems. The experimental part of this project focused on improving the synthetic techniques for controlling the grain size and making measurements on the properties of these systems as a function of doping of impurities and of process conditions. A significant attention was paid to screening potential cathode materials (transition metal perovskites) and anode electrocatalysts (metals) for reactivity with Y-doped BaZrO{sub 3}, fabrication compatibility, and chemical stability in fuel cell environment. A robust method for fabricating crack-free thin membranes, as well as methods for sealing anode and cathode chambers, have been successfully developed. Our Pt|BYZ|Pt fuel cell, with a 100 {micro}m thick Y-doped BaZrO{sub 3} electrolyte layer, demonstrates the peak power density and short circuit current density of 28 mW/cm{sup 2} and 130mA/cm{sup 2}, respectively. These are the highest values of this type of fuel cell. All of these provide the basis for a future project in which theory and computation are combined to develop modified ceramic electrolytes capable of both high proton conductivity and excellent mechanical and chemical stability.

Boris Merinov; William A. Goddard III; Sossina Haile; Adri van Duin; Peter Babilo; Sang Soo Han

2005-12-29T23:59:59.000Z

400

U.S. DEPARTMENT OF ENERGY SOLID OXIDE FUEL CELLS PROGRAM | 2013 PROJECT PORTFOLIO  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

DEPARTMENT OF ENERGY DEPARTMENT OF ENERGY SOLID OXIDE FUEL CELLS PROGRAM | 2013 PROJECT PORTFOLIO 2 THIS PAGE INTENTIONALLY LEFT BLANK OFFICE OF FOSSIL ENERGY SOLID OXIDE FUEL CELLS PROGRAM | 2013 PROJECT PORTFOLIO 3 Disclaimer DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference therein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not neces-

Note: This page contains sample records for the topic "high-temperature solid oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Short time proton dynamics in bulk ice and in porous anode solid oxide fuel cell materials  

SciTech Connect (OSTI)

Oxygen reduction and incorporation into solid electrolytes and the reverse reaction of oxygen evolution play a cru-cial role in Solid Oxide Fuel Cell (SOFC) applications. However a detailed un derstanding of the kinetics of the cor-responding reactions, i.e. on reaction mechanisms, rate limiting steps, reaction paths, electrocatalytic role of materials, is still missing. These include a thorough characterization of the binding potentials experienced by protons in the lattice. We report results of Inelastic Neutron Scattering (INS) measurements of the vibrational state of the protons in Ni- YSZ highly porous composites (75% to 90% ), a ceramic-metal material showing a high electrical conductivity and ther mal stability, which is known to be most effectively used as anodes for solid ox ide fuel cells. The results are compared with INS and Deep Inelastic Neutron Scattering (DINS) experiments on the proton binding states in bulk ice.

Basoli, Francesco [Universit degli Studi di Roma Tor Vergata, Italy] [Universit degli Studi di Roma Tor Vergata, Italy; Senesi, Roberto [ORNL] [ORNL; Kolesnikov, Alexander I [ORNL] [ORNL; Licoccia, Silvia [NAST Center, University of Roma "Tor Vergata"] [NAST Center, University of Roma "Tor Vergata"

2014-01-01T23:59:59.000Z

402

HIGH-TEMPERATURE CO-ELECTROLYSIS OF H2O AND CO2 FOR SYNGAS PRODUCTION  

SciTech Connect (OSTI)

Worldwide, the demand for light hydrocarbon fuels like gasoline and diesel oil is increasing. To satisfy this demand, oil companies have begun to utilize oil deposits of lower hydrogen content (an example is the Athabasca Oil Sands). Additionally, the higher contents of sulfur and nitrogen of these resources requires processes such as hydrotreating to meet environmental requirements. In the mean time, with the price of oil currently over $50 / barrel, synthetically-derived hydrocarbon fuels (synfuels) have become economical. Synfuels are typically produced from syngas hydrogen (H2) and carbon monoxide (CO) -- using the Fischer-Tropsch process, discovered by Germany before World War II. South Africa has used synfuels to power a significant number of their buses, trucks, and taxicabs. The Idaho National Laboratory (INL), in conjunction with Ceramatec Inc. (Salt Lake City, USA) has been researching for several years the use of solid-oxide fuel cell technology to electrolyze steam for large-scale nuclear-powered hydrogen production. Now, an experimental research project is underway at the INL to investigate the feasibility of producing syngas by simultaneously electrolyzing at high-temperature steam and carbon dioxide (CO2) using solid oxide fuel cell technology. The syngas can then be used for synthetic fuel production. This program is a combination of experimental and computational activities. Since the solid oxide electrolyte material is a conductor of oxygen ions, CO can be produced by electrolyzing CO2 sequestered from some greenhouse gas-emitting process. Under certain conditions, however, CO can further electrolyze to produce carbon, which can then deposit on cell surfaces and reduce cell performance. The understanding of the co-electrolysis of steam and CO2 is also complicated by the competing water-gas shift reaction. Results of experiments and calculations to date of CO2 and CO2/H2O electrolysis will be presented and discussed. These will include electrolysis performance at various temperatures, gas mixtures, and electrical settings. Product gas compositions, as measured via a gas analyser, and their relationship to conversion efficiencies will be presented. These measurements will be compared to predictions obtained from chemical equilibrium computer codes. Better understanding of the feasibility of producing syngas using high-temperature electrolysis will initiate the systematic investigation of nuclear-powered synfuel production as a bridge to the future hydrogen economy and ultimate independence from foreign energy resources.

Stoots, C.M.

2006-11-01T23:59:59.000Z

403

Roughening of a Si(100) surface induced by the adsorption of oxygen near the solid-oxide nucleation threshold  

Science Journals Connector (OSTI)

An investigation of the processes on a Si(100) surface interacting with oxygen near the solid-oxide nucleation threshold using x-ray photoelectron spectroscopy and atomic-force microscopy is described. The nuclea...

V. D. Borman; Yu. Yu. Lebedinskii

1998-07-01T23:59:59.000Z

404

Characterization of YSZ solid oxide fuel cells electrolyte deposited by atmospheric plasma spraying and low pressure plasma spraying  

Science Journals Connector (OSTI)

Yttria doped zirconia has been widely used as electrolyte materials for solid oxide fuel cells (SOFC). Plasma spraying is a cost-effective process to...2O3 stabilized ZrO2...(YSZ) layer was deposited by low press...

C. Zhang; H. L. Liao; W. Y. Li; G. Zhang; C. Coddet

2006-12-01T23:59:59.000Z

405

Structure degradation and redistribution of alloying elements in austenitic steel of current collectors of solid oxide fuel cells in service  

Science Journals Connector (OSTI)

The degradation of the 10Kh23N18 steel structure with and ... as a switchgear material of a solid oxide fuel cell. Structural studies have shown no significant differences...

M. V. Degtyarev; V. F. Chukharev

2013-01-01T23:59:59.000Z

406

The development of control strategy for solid oxide fuel cell and micro gas turbine hybrid power system in ship application  

Science Journals Connector (OSTI)

A solid oxide fuel cell (SOFC) and micro gas turbine (MGT) hybrid power system is a newly developed and promising power technology for ship power systems. Compared to conventional power plants on commercial sh...

Jiqing He; Peilin Zhou; David Clelland

2014-12-01T23:59:59.000Z

407

Characterization of Solid Oxide Fuel Cell Sealant Material G18 by Microindentation Alexandra Woldman, Cornell University, 2009 SURF Fellow  

E-Print Network [OSTI]

Milhans Introduction Solid oxide fuel cells (SOFC) require a hermetic seal between the fuel and air side of the electrodes in order to function properly. The cracking or leaking of an SOFC seal is the end of the useful

Li, Mo

408

MECHANICAL PROPERTIES OF Sc???Ce????Zr????O? ELECTROLYTE MATERIAL FOR INTERMEDIATE TEMPERATURE SOLID OXIDE FUEL CELLS  

E-Print Network [OSTI]

Scandia doped zirconia has been considered a candidate for electrolyte material in intermediate temperature Solid Oxide Fuel Cells (SOFCs) due to its high ionic conductivity, chemical stability and good electrochemical performance. The aim...

Lim, Wendy

2011-02-22T23:59:59.000Z

409

Two Phase Transitions Make a High-Temperature Superconductor  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Two Phase Transitions Make a High-Temperature Superconductor Print Two Phase Transitions Make a High-Temperature Superconductor Print Superconductivity-conceptually remarkable and practically revolutionary-is a quantum phenomenon in which bound electron pairs flow through a material in perfect synchrony, without friction. Conventional superconducting materials reach this state via a single thermal phase transition at a critical temperature (Tc). It was generally believed that such a picture also applied to the copper oxide (cuprate) superconductors-first discovered 25 years ago and the current record holders for highest Tc. However, three groups of researchers who performed measurements on the same cuprate material recently joined forces to prove that this view is inaccurate. Their work showed that another phase transition actually exists at a higher temperature in the cuprate phase diagram, below which electrons, instead of pairing up, organize themselves in a drastically different way.

410

Two Phase Transitions Make a High-Temperature Superconductor  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Two Phase Transitions Make a High-Temperature Superconductor Print Two Phase Transitions Make a High-Temperature Superconductor Print Superconductivity-conceptually remarkable and practically revolutionary-is a quantum phenomenon in which bound electron pairs flow through a material in perfect synchrony, without friction. Conventional superconducting materials reach this state via a single thermal phase transition at a critical temperature (Tc). It was generally believed that such a picture also applied to the copper oxide (cuprate) superconductors-first discovered 25 years ago and the current record holders for highest Tc. However, three groups of researchers who performed measurements on the same cuprate material recently joined forces to prove that this view is inaccurate. Their work showed that another phase transition actually exists at a higher temperature in the cuprate phase diagram, below which electrons, instead of pairing up, organize themselves in a drastically different way.

411

Two Phase Transitions Make a High-Temperature Superconductor  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Two Phase Transitions Make a High-Temperature Superconductor Print Two Phase Transitions Make a High-Temperature Superconductor Print Superconductivity-conceptually remarkable and practically revolutionary-is a quantum phenomenon in which bound electron pairs flow through a material in perfect synchrony, without friction. Conventional superconducting materials reach this state via a single thermal phase transition at a critical temperature (Tc). It was generally believed that such a picture also applied to the copper oxide (cuprate) superconductors-first discovered 25 years ago and the current record holders for highest Tc. However, three groups of researchers who performed measurements on the same cuprate material recently joined forces to prove that this view is inaccurate. Their work showed that another phase transition actually exists at a higher temperature in the cuprate phase diagram, below which electrons, instead of pairing up, organize themselves in a drastically different way.

412

Two Phase Transitions Make a High-Temperature Superconductor  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Two Phase Transitions Make a High-Temperature Superconductor Print Two Phase Transitions Make a High-Temperature Superconductor Print Superconductivity-conceptually remarkable and practically revolutionary-is a quantum phenomenon in which bound electron pairs flow through a material in perfect synchrony, without friction. Conventional superconducting materials reach this state via a single thermal phase transition at a critical temperature (Tc). It was generally believed that such a picture also applied to the copper oxide (cuprate) superconductors-first discovered 25 years ago and the current record holders for highest Tc. However, three groups of researchers who performed measurements on the same cuprate material recently joined forces to prove that this view is inaccurate. Their work showed that another phase transition actually exists at a higher temperature in the cuprate phase diagram, below which electrons, instead of pairing up, organize themselves in a drastically different way.

413

Liquid Fuel Production from Biomass via High Temperature Steam Electrolysis  

SciTech Connect (OSTI)

A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to heat steam for the hydrogen production via the high temperature steam electrolysis process. Hydrogen from electrolysis allows a high utilization of the biomass carbon for syngas production. Oxygen produced form the electrolysis process is used to control the oxidation rate in the oxygen-fed biomass gasifier. Based on the gasifier temperature, 94% to 95% of the carbon in the biomass becomes carbon monoxide in the syngas (carbon monoxide and hydrogen). Assuming the thermal efficiency of the power cycle for electricity generation is 50%, (as expected from GEN IV nuclear reactors), the syngas production efficiency ranges from 70% to 73% as the gasifier temperature decreases from 1900 K to 1500 K. Parametric studies of system pressure, biomass moisture content and low temperature alkaline electrolysis are also presented.

Grant L. Hawkes; Michael G. McKellar

2009-11-01T23:59:59.000Z

414

JOURNAL OF MATERIALS SCIENCE 36 (2001) 1087 1091 Materials for high-temperature oxygen reduction  

E-Print Network [OSTI]

in solid oxide fuel cells A. J. MCEVOY Laboratory for Photonics and Interfaces, Department of Chemistry temperature fuel cell is advantageously an all- solid device, part of their system being an iron oxide cathode. In that selection they confronted the require- ments which necessarily define a suitable solid oxide fuel cell

Gleixner, Stacy

415

Solid oxide fuel cell with transitioned cross-section for improved anode gas management at the open end  

DOE Patents [OSTI]

A solid oxide fuel cell (400) is made having a tubular, elongated, hollow, active section (445) which has a cross-section containing an air electrode (452) a fuel electrode (454) and solid oxide electrolyte (456) between them, where the fuel cell transitions into at least one inactive section (460) with a flattened parallel sided cross-section (462, 468) each cross-section having channels (472, 474, 476) in them which smoothly communicate with each other at an interface section (458).

Zafred, Paolo R. (Murrysville, PA); Draper, Robert (Pittsburgh, PA)

2012-01-17T23:59:59.000Z

416

The effect of Mn on the oxidation behavior and electrical conductivity of Fe17Cr alloys in solid oxide fuel cell cathode atmosphere  

Science Journals Connector (OSTI)

Four Fe17Cr alloys with various Mn contents between 0.0 and 3.0wt.% are prepared for investigation of the effect of Mn content on the oxidation behavior and electrical conductivity of the FeCr alloys for the application of metallic interconnects in solid oxide fuel cells (SOFCs). During the initial oxidation stage (within 1min) at 750C in air, Cr is preferentially oxidized to form a layer of Cr2O3 type oxide in all the alloys, regardless the Mn content, with similar oxidation rate and oxide morphology. The subsequent oxidation of the Mn containing alloys is accelerated caused by the fast outward diffusion of Mn ions across the Cr2O3 type oxide layer to form Mn-rich (Mn, Cr)3O4 and Mn2O3 oxides on the top. After 700h oxidation a multi-layered oxide scale is observed in the Mn containing alloys, which corresponds to a multi-stage oxidation kinetics in the alloys containing 0.5 and 1.0wt.% of Mn. The oxidation rate and ASR of the oxide scale increase with the Mn content in the alloy changes from 0.0 to 3.0wt.%. For the application of metallic interconnects in SOFCs, Mn-free Fe17Cr alloy with conducting Cr free spinel coatings is preferred.

Bin Hua; Yonghong Kong; Wenying Zhang; Jian Pu; Bo Chi; Li Jian

2011-01-01T23:59:59.000Z

417

Structural, chemical, and electrochemical characteristics of LaSr2Fe2CrO9--based solid oxide fuel cell anodes  

E-Print Network [OSTI]

Available online 5 March 2012 Keywords: Solid oxide fuel cell Perovskite Oxide anode Redox Sulfur tolerance Solid oxide fuel cells with LaSr2Fe2CrO9-­Gd0.1Ce0.9O2- composite anodes were tested in H2, H2S-of-the-art solid oxide fuel cell (SOFC) anode is Ni-8-mole% yttria stabilized zirconia (YSZ), which performs very

Poeppelmeier, Kenneth R.

418

A novel clean and effective syngas production system based on partial oxidation of methane assisted solid oxide co-electrolysis process  

Science Journals Connector (OSTI)

Abstract Development of the syngas production from solid oxide H2O/CO2 co-electrolysis is limited by the intensive energy input and low efficiency. Here, we present a new concept to efficiently generate syngas in both sides of the solid oxide electrolyzer by synergistically combining co-electrolysis with partial oxidation of methane (POM). Thermodynamic calculation and electrochemical measurements for the POM assisted solid oxide co-electrolysis processes on the SFM-SDC/LSGM/SFM-SDC cells exhibited an reduced electric input, increased energy conversion efficiency and decreased cathodic co-electrolysis polarization resistance in comparison with the conventional co-electrolysis. This method will be crucial to establish a clean and effective energy conversion system to meet global sustainable energy needs.

Yao Wang; Tong Liu; Shumin Fang; Guoliang Xiao; Huanting Wang; Fanglin Chen

2015-01-01T23:59:59.000Z

419

High Temperature Cements | Open Energy Information  

Open Energy Info (EERE)

High Temperature Cements High Temperature Cements Jump to: navigation, search Geothermal ARRA Funded Projects for High Temperature Cements Loading map... {"format":"googlemaps3","type":"ROADMAP","types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"limit":200,"offset":0,"link":"all","sort":[""],"order":[],"headers":"show","mainlabel":"","intro":"","outro":"","searchlabel":"\u2026 further results","default":"","geoservice":"google","zoom":false,"width":"600px","height":"350px","centre":false,"layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","icon":"","visitedicon":"","forceshow":true,"showtitle":true,"hidenamespace":false,"template":false,"title":"","label":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"locations":[{"text":"

420

High Temperature Membrane & Advanced Cathode Catalyst Development  

SciTech Connect (OSTI)

Current project consisted of three main phases and eighteen milestones. Short description of each phase is given below. Table 1 lists program milestones. Phase 1--High Temperature Membrane and Advanced Catalyst Development. New polymers and advanced cathode catalysts were synthesized. The membranes and the catalysts were characterized and compared against specifications that are based on DOE program requirements. The best-in-class membranes and catalysts were downselected for phase 2. Phase 2--Catalyst Coated Membrane (CCM) Fabrication and Testing. Laboratory scale catalyst coated membranes (CCMs) were fabricated and tested using the down-selected membranes and catalysts. The catalysts and high temperature membrane CCMs were tested and optimized. Phase 3--Multi-cell stack fabrication. Full-size CCMs with the down-selected and optimized high temperature membrane and catalyst were fabricated. The catalyst membrane assemblies were tested in full size cells and multi-cell stack.

Protsailo, Lesia

2006-04-20T23:59:59.000Z

Note: This page contains sample records for the topic "high-temperature solid oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Selection of materials for high temperature sensible energy storage  

Science Journals Connector (OSTI)

Abstract Availability of thermal energy storage systems (TES) is a key to ensuring continuous power supply from solar thermal power plants. The application of sensible heat storage (SHS) in solid media is an attractive economic option, but is dependent on identifying suitable SHS media. Given the growing number of new materials available today, finding a suitable material is a time-consuming and difficult process. This paper demonstrates the use of a materials selection software package and identifies suitable SHS materials for high temperature (>500C) TES systems. The environmental performance of some selected materials was also evaluated using the package. Common materials such as alumina, silicon carbide, high temperature concrete, graphite, cast iron and steel were found to be highly suitable for SHS for the duty considered (500750C). For cost comparison, a simple heat exchanger, consisting of a packed bed of the materials (in brick or block form) heated by an inert gas, was considered. On the basis of equivalent gas phase heat transfer, high alumina cement concrete blocks had the lowest cost, followed by a common refractory brick at High temperature concretes, such as the high alumina cement-based materials and aluminasilicate geoploymers, were identified as having potential for SHS media as they are cheap composite materials. Their thermophysical properties could be optimised for SHS by a suitable choice of aggregates, binders and additives.

S. Khare; M. Dell'Amico; C. Knight; S. McGarry

2013-01-01T23:59:59.000Z

422

High temperature crystalline superconductors from crystallized glasses  

DOE Patents [OSTI]

A method of preparing a high temperature superconductor from an amorphous phase. The method involves preparing a starting material of a composition of Bi.sub.2 Sr.sub.2 Ca.sub.3 Cu.sub.4 Ox or Bi.sub.2 Sr.sub.2 Ca.sub.4 Cu.sub.5 Ox, forming an amorphous phase of the composition and heat treating the amorphous phase for particular time and temperature ranges to achieve a single phase high temperature superconductor.

Shi, Donglu (Downers Grove, IL)

1992-01-01T23:59:59.000Z

423

Frustrated phase separation and high temperature superconductivity  

SciTech Connect (OSTI)

A dilute system of neutral holes in an antiferromagnet separates into a hole-rich and a hole-poor phase. The phase separation is frustrated by long-range Coulomb interactions but, provided the dielectric constant is sufficiently large, there remain large-amplitude low-energy fluctuations in the hole density at intermediate length scales. The extensive experimental evidence showing that this behavior giver, a reasonable picture of high temperature superconductors is surveyed. Further, it is shown that the scattering of mobile holes from the local density fluctuations may account for the anomalous normal-state properties of high temperature superconductors and also provide the mechanism of pairing.

Emery, V.J. [Brookhaven National Lab., Upton, NY (United States); Kivelson, S.A. [California Univ., Los Angeles, CA (United States). Dept. of Physics

1992-09-01T23:59:59.000Z

424

Frustrated phase separation and high temperature superconductivity  

SciTech Connect (OSTI)

A dilute system of neutral holes in an antiferromagnet separates into a hole-rich and a hole-poor phase. The phase separation is frustrated by long-range Coulomb interactions but, provided the dielectric constant is sufficiently large, there remain large-amplitude low-energy fluctuations in the hole density at intermediate length scales. The extensive experimental evidence showing that this behavior giver, a reasonable picture of high temperature superconductors is surveyed. Further, it is shown that the scattering of mobile holes from the local density fluctuations may account for the anomalous normal-state properties of high temperature superconductors and also provide the mechanism of pairing.

Emery, V.J. (Brookhaven National Lab., Upton, NY (United States)); Kivelson, S.A. (California Univ., Los Angeles, CA (United States). Dept. of Physics)

1992-01-01T23:59:59.000Z

425

Pore-Scale Investigation of Mass Transport and Electrochemistry in a Solid Oxide Fuel Cell Anode  

SciTech Connect (OSTI)

The development and validation of a model for the study of pore-scale transport phenomena and electrochemistry in a Solid Oxide Fuel Cell (SOFC) anode are presented in this work. This model couples mass transport processes with a detailed reaction mechanism, which is used to model the electrochemical oxidation kinetics. Detailed electrochemical oxidation reaction kinetics, which is known to occur in the vicinity of the three-phase boundary (TPB) interfaces, is discretely considered in this work. The TPB regions connect percolating regions of electronic and ionic conducting phases of the anode, nickel (Ni) and yttria-stabilized zirconia (YSZ), respectively; with porous regions supporting mass transport of the fuel and product. A two-dimensional (2D), multi-species lattice Boltzmann method (LBM) is used to describe the diffusion process in complex pore structures that are representative of the SOFC anode. This diffusion model is discretely coupled to a kinetic electrochemical oxidation mechanism using localized flux boundary conditions. The details of the oxidation kinetics are prescribed as a function of applied activation overpotential and the localized hydrogen and water mole fractions. This development effort is aimed at understanding the effects of the anode microstructure within TPB regions. This work describes the methods used so that future studies can consider the details of SOFC anode microstructure.

Grew, K. N.; Joshi, A. S.; Peracchio, A. A.; Chiu, W. K. S.

2010-01-01T23:59:59.000Z

426

Sealed glass coating of high temperature ceramic superconductors  

DOE Patents [OSTI]

A method and article of manufacture of a lead oxide based glass coating on a high temperature superconductor is disclosed. The method includes preparing a dispersion of glass powders in a solution, applying the dispersion to the superconductor, drying the dispersion before applying another coating and heating the glass powder dispersion at temperatures below oxygen diffusion onset and above the glass melting point to form a continuous glass coating on the superconductor to establish compressive stresses which enhance the fracture strength of the superconductor. 8 figs.

Wu, W.; Chu, C.Y.; Goretta, K.C.; Routbort, J.L.

1995-05-02T23:59:59.000Z

427

Solid-state lithium battery  

DOE Patents [OSTI]

The present invention is directed to a higher power, thin film lithium-ion electrolyte on a metallic substrate, enabling mass-produced solid-state lithium batteries. High-temperature thermodynamic equilibrium processing enables co-firing of oxides and base metals, providing a means to integrate the crystalline, lithium-stable, fast lithium-ion conductor lanthanum lithium tantalate (La.sub.1/3-xLi.sub.3xTaO.sub.3) directly with a thin metal foil current collector appropriate for a lithium-free solid-state battery.

Ihlefeld, Jon; Clem, Paul G; Edney, Cynthia; Ingersoll, David; Nagasubramanian, Ganesan; Fenton, Kyle Ross

2014-11-04T23:59:59.000Z

428

Potential applications of high temperature helium  

SciTech Connect (OSTI)

This paper discusses the DOE MHTGR-SC program`s recent activity to improve the economics of the MHTGR without sacrificing safety performance and two potential applications of high temperature helium, the MHTGR gas turbine plant and a process heat application for methanol production from coal.

Schleicher, R.W. Jr.; Kennedy, A.J.

1992-09-01T23:59:59.000Z

429

Potential applications of high temperature helium  

SciTech Connect (OSTI)

This paper discusses the DOE MHTGR-SC program's recent activity to improve the economics of the MHTGR without sacrificing safety performance and two potential applications of high temperature helium, the MHTGR gas turbine plant and a process heat application for methanol production from coal.

Schleicher, R.W. Jr.; Kennedy, A.J.

1992-09-01T23:59:59.000Z

430

High temperature storage loop : final design report.  

SciTech Connect (OSTI)

A three year plan for thermal energy storage (TES) research was created at Sandia National Laboratories in the spring of 2012. This plan included a strategic goal of providing test capability for Sandia and for the nation in which to evaluate high temperature storage (>650%C2%B0C) technology. The plan was to scope, design, and build a flow loop that would be compatible with a multitude of high temperature heat transfer/storage fluids. The High Temperature Storage Loop (HTSL) would be reconfigurable so that it was useful for not only storage testing, but also for high temperature receiver testing and high efficiency power cycle testing as well. In that way, HTSL was part of a much larger strategy for Sandia to provide a research and testing platform that would be integral for the evaluation of individual technologies funded under the SunShot program. DOE's SunShot program seeks to reduce the price of solar technologies to 6/kWhr to be cost competitive with carbon-based fuels. The HTSL project sought to provide evaluation capability for these SunShot supported technologies. This report includes the scoping, design, and budgetary costing aspects of this effort

Gill, David Dennis; Kolb, William J.

2013-07-01T23:59:59.000Z

431

High Temperature, Permanent Magnet Biased Magnetic Bearings  

E-Print Network [OSTI]

performance, high speed and high temperature applications like space vehicles, jet engines and deep sea equipment. The bearing system had a target design to carry a load equal to 500 lb-f (2225N). Another objective was to design and build a test rig fixture...

Gandhi, Varun R.

2010-07-14T23:59:59.000Z

432

Metallic Hydrogen: A High-Temperature Superconductor?  

Science Journals Connector (OSTI)

Application of the BCS theory to the proposed metallic modification of hydrogen suggests that it will be a high-temperature superconductor. This prediction has interesting astrophysical consequences, as well as implications for the possible development of a superconductor for use at elevated temperatures.

N. W. Ashcroft

1968-12-23T23:59:59.000Z

433

Assessment of Planar Solid Oxide Fuel Cell Technology Arthur D. Little, Inc.  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Planar Solid Planar Solid Oxide Fuel Cell Technology Arthur D. Little, Inc. Acorn Park Cambridge, Massachusetts 02140-2390 Reference 39463-02 Report to: DOE FETC October 1999 EC39463 SOFC 1015 R3 2 Table of Contents 3 Background 4 Planar SOFC Technology Assessment 5 1 Project Objectives "Low Temperature" Planar SOFC Cost Analysis 2 Executive Summary EC39463 SOFC 1015 R3 3 3 Background 4 Planar SOFC Technology Assessment 5 1 Project Objectives "Low Temperature" Planar SOFC Cost Analysis 2 Executive Summary EC39463 SOFC 1015 R3 4 Project Objectives DOE FETC Fuel Cell Program In support of the 21st Century Fuel Cell Concept Team, we have assessed planar architectures for SOFC technology. Tasks Tasks Tasks * Literature Review of Planar SOFC Programs * Interviews with Major Developers

434

Higher ionic conductive ceria-based electrolytes for solid oxide fuel cells  

Science Journals Connector (OSTI)

Codoping is used to enhance the ionic conductivity of ceria-based electrolytes. Sm 3 + and Nd 3 + were selected as codopants to promote low migration energy paths for oxygen vacancydiffusion thereby increasing the ionic conductivity. Moreover the use of codopants also increases the pre-exponential factor in the Arrhenius relationship thus further improving the ionic conductivity. The ionic conductivity of Sm x Nd x Ce 1 ? 2 x O 2 ? ? solid solutions is measured using electrochemical impedance spectroscopy. It was observed that for Sm 0.075 Nd 0.075 Ce 0.85 O 2 ? ? the grain ionic conductivity was 14.0 10 ? 3 S cm ? 1 at 550 C which makes it one of the most promising ceria-based electrolytes for intermediate temperature solid oxide fuel cells.

Shobit Omar; Eric D. Wachsman; Juan C. Nino

2007-01-01T23:59:59.000Z

435

DEVELOPMENT OF LOW-COST MANUFACTURING PROCESSES FOR PLANAR, MULTILAYER SOLID OXIDE FUEL CELL ELEMENTS  

SciTech Connect (OSTI)

This report summarizes the results of a four-year project, entitled, ''Low-Cost Manufacturing Of Multilayer Ceramic Fuel Cells'', jointly funded by the U.S. Department of Energy, the State of Ohio, and by project participants. The project was led by NexTech Materials, Ltd., with subcontracting support provided by University of Missouri-Rolla, Michael A. Cobb & Co., Advanced Materials Technologies, Inc., Edison Materials Technology Center, Gas Technology Institute, Northwestern University, and The Ohio State University. Oak Ridge National Laboratory, though not formally a subcontractor on the program, supported the effort with separate DOE funding. The objective of the program was to develop advanced manufacturing technologies for making solid oxide fuel cell components that are more economical and reliable for a variety of applications. The program was carried out in three phases. In the Phase I effort, several manufacturing approaches were considered and subjected to detailed assessments of manufacturability and development risk. Estimated manufacturing costs for 5-kW stacks were in the range of $139/kW to $179/kW. The risk assessment identified a number of technical issues that would need to be considered during development. Phase II development work focused on development of planar solid oxide fuel cell elements, using a number of ceramic manufacturing methods, including tape casting, colloidal-spray deposition, screen printing, spin-coating, and sintering. Several processes were successfully established for fabrication of anode-supported, thin-film electrolyte cells, with performance levels at or near the state-of-the-art. The work in Phase III involved scale-up of cell manufacturing methods, development of non-destructive evaluation methods, and comprehensive electrical and electrochemical testing of solid oxide fuel cell materials and components.

Scott Swartz; Matthew Seabaugh; William Dawson; Harlan Anderson; Tim Armstrong; Michael Cobb; Kirby Meacham; James Stephan; Russell Bennett; Bob Remick; Chuck Sishtla; Scott Barnett; John Lannutti

2004-06-12T23:59:59.000Z

436

Journal of Power Sources 140 (2005) 331339 Numerical study of a flat-tube high power density solid oxide fuel cell  

E-Print Network [OSTI]

) solid oxide fuel cell (SOFC) is a new design developed by Siemens Westinghouse, based on their formerly.V. All rights reserved. Keywords: Flat-tube; High power density; Solid oxide fuel cell; Simulation; Heat oxide fuel cell Part I. Heat/mass transfer and fluid flow Yixin Lu1, Laura Schaefer, Peiwen Li2

437

Silicon Based Solid Oxide Fuel Cell Chip for Portable Consumer Electronics -- Final Technical Report  

SciTech Connect (OSTI)

LSIs fuel cell uses efficient Solid Oxide Fuel Cell (SOFC) technology, is manufactured using Micro Electrical Mechanical System (MEMS) fabrication methods, and runs on high energy fuels, such as butane and ethanol. The companys Fuel Cell on a Chip technology enables a form-factor battery replacement for portable electronic devices that has the potential to provide an order-of-magnitude run-time improvement over current batteries. Further, the technology is clean and environmentally-friendly. This Department of Energy funded project focused on accelerating the commercialization and market introduction of this technology through improvements in fuel cell chip power output, lifetime, and manufacturability.

Alan Ludwiszewski

2009-06-29T23:59:59.000Z

438

Phase and strain distributions associated with reactive contaminants inside of a solid oxide fuel cell  

Science Journals Connector (OSTI)

A microfocused synchrotron x-ray diffraction method was used to reveal the quantitative distributions of phase fractions internal strains and their interdependences at different layer depths inside of a planar solid oxide fuel cell which was deactivated by chromium contamination through direct contact with the metallic interconnect under typical operating conditions. These observations provide insight into the mechanism of Cr poisoning. The method can serve as a versatile tool for studying the electrochemical devices with thin-layered construction such as batteries and fuel cells under static or in situ conditions.

Di-Jia Liu; Jonathan Almer

2009-01-01T23:59:59.000Z

439

Microstructure and properties of barium cerate based electrolytes for solid oxide fuel cells  

SciTech Connect (OSTI)

Barium cerate based ceramics have been widely reported to have high ionic conductivity and hold promise as electrolyte materials for intermediate-temperature solid oxide fuel cells (SOFC`s). Samples of niobium-doped barium cerate have been produced with a variety of microstructures. Many parameters affecting the final microstructure of the electrolyte materials have been systematically investigated. The conductivity of the electrolyte materials produced have been studied using impedance spectroscopy to understand the effect of microstructure on the desired properties of barium cerate based electrolytes.

Rauch, W.L.; Liu, M. [Georgia Institute of Technology, Atlanta, GA (United States)

1996-12-31T23:59:59.000Z

440

Control of Oxygen Delamination in Solid Oxide Electrolyzer Cells via Modifying Operational Regime  

SciTech Connect (OSTI)

Possible modifications of operational regimes for solid oxide fuel cell (SOEC) devices for hydrogen production are discussed. It is shown that applying alternating current (AC) voltage pulses at a certain frequency range to SOECs could reduce oxygen delamination degradation in these devices and significantly increase their lifetime. This operational scheme provides wide possibilities to increase longevity of SOEC devices required for their use in commercial hydrogen production processes, without any significant modification of used materials and/or cell design. Developed simulation method possesses a broad generality and be employed in a number of other industrial processes.

Sergey N. Rashkeev; Michael V. Glazoff

2011-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "high-temperature solid oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

A Quasi-Two-Dimensional Electrochemistry Modeling Tool for Planar Solid Oxide Fuel Cell Stacks  

SciTech Connect (OSTI)

A two-dimensional numerical model is presented for the efficient computation of the steady-state current density, species concentration, and temperature distributions in planar solid oxide fuel cell stacks. The model reduction techniques, engineering approximations, and numerical procedures used to simulate the stack physics while maintaining adequate computational speed are discussed. The results of the model for benchmark cases with and without on-cell methane reformation are presented with comparisons to results from other research described in the literature. The capabilities, performance, and scalability of the model for the study of large multi-cell stacks are then demonstrated.

Lai, Canhai; Koeppel, Brian J.; Choi, Kyoo Sil; Recknagle, Kurtis P.; Sun, Xin; Chick, Lawrence A.; Korolev, Vladimir N.; Khaleel, Mohammad A.

2011-03-15T23:59:59.000Z

442

Solid oxide fuel cells having porous cathodes infiltrated with oxygen-reducing catalysts  

DOE Patents [OSTI]

Solid-oxide fuel cells include an electrolyte and an anode electrically coupled to a first surface of the electrolyte. A cathode is provided, which is electrically coupled to a second surface of the electrolyte. The cathode includes a porous backbone having a porosity in a range from about 20% to about 70%. The porous backbone contains a mixed ionic-electronic conductor (MIEC) of a first material infiltrated with an oxygen-reducing catalyst of a second material different from the first material.

Liu, Meilin; Liu, Ze; Liu, Mingfei; Nie, Lifang; Mebane, David Spencer; Wilson, Lane Curtis; Surdoval, Wayne

2014-08-12T23:59:59.000Z

443

Mixed Fuel Strategy for Carbon Deposition Mitigation in Solid Oxide Fuel Cells at Intermediate Temperatures  

Science Journals Connector (OSTI)

Mixed Fuel Strategy for Carbon Deposition Mitigation in Solid Oxide Fuel Cells at Intermediate Temperatures ... (1-4) Although the concept of SOFCs was first reported more than one century ago,(5) major technological advances in cell materials, reactor configuration, operation mode, and balance of plant system integration and optimization were realized in the last 2030 years only. ... The hybrid start-up process is optimized with respect to a specific setup as an example, but is of general nature and utility to similar systems. ...

Chao Su; Yubo Chen; Wei Wang; Ran Ran; Zongping Shao; Joo C. Diniz da Costa; Shaomin Liu

2014-05-23T23:59:59.000Z

444

Anode protection system for shutdown of solid oxide fuel cell system  

SciTech Connect (OSTI)

An Anode Protection Systems for a SOFC system, having a Reductant Supply and safety subsystem, a SOFC anode protection subsystem, and a Post Combustion and slip stream control subsystem. The Reductant Supply and safety subsystem includes means for generating a reducing gas or vapor to prevent re-oxidation of the Ni in the anode layer during the course of shut down of the SOFC stack. The underlying ammonia or hydrogen based material used to generate a reducing gas or vapor to prevent the re-oxidation of the Ni can be in either a solid or liquid stored inside a portable container. The SOFC anode protection subsystem provides an internal pressure of 0.2 to 10 kPa to prevent air from entering into the SOFC system. The Post Combustion and slip stream control subsystem provides a catalyst converter configured to treat any residual reducing gas in the slip stream gas exiting from SOFC stack.

Li, Bob X; Grieves, Malcolm J; Kelly, Sean M

2014-12-30T23:59:59.000Z

445

Activity and structure of perovskites as diesel reforming catalysts for solid oxide fuel cells.  

SciTech Connect (OSTI)

Recent progress in developing perovskite materials as more cost-effective catalysts in autothermal reforming (ATR) of diesel fuel to hydrogen-rich reformate for solid oxide fuel cell (SOFC) application is reported. Perovskite-type metal oxides with B sites partially exchanged by ruthenium were prepared and evaluated under ATR reaction conditions. The hydrogen yield, reforming efficiency, and CO{sub x} selectivity of these catalysts were investigated using diesel surrogate fuel with 50 ppm sulfur. The catalyst performances have approached or exceeded a benchmark, high-cost rhodium-based material. In parallel with the reactivity study, we also investigated the physical properties of B-site doped perovskites and their impact on the reforming performance using various characterization techniques such as BET, X-ray powder diffraction, temperature programmable reduction, scanning electron microscopy, and synchrotron X-ray absorption spectroscopy. We found that ruthenium is highly dispersed into perovskite lattice and its redox behavior is directly associated with reforming activity.

Liu, D.-J.; Krumpelt, M.; Chemical Engineering

2005-01-01T23:59:59.000Z

446

Energy and exergy analysis of an ethanol reforming process for solid oxide fuel cell applications  

Science Journals Connector (OSTI)

Abstract The fuel processor in which hydrogen is produced from fuels is an important unit in a fuel cell system. The aim of this study is to apply a thermodynamic concept to identify a suitable reforming process for an ethanol-fueled solid oxide fuel cell (SOFC). Three different reforming technologies, i.e., steam reforming, partial oxidation and autothermal reforming, are considered. The first and second laws of thermodynamics are employed to determine an energy demand and to describe how efficiently the energy is supplied to the reforming process. Effect of key operating parameters on the distribution of reforming products, such as H2, CO, CO2 and CH4, and the possibility of carbon formation in different ethanol reformings are examined as a function of steam-to-ethanol ratio, oxygen-to-ethanol ratio and temperatures at atmospheric pressure. Energy and exergy analysis are performed to identify the best ethanol reforming process for SOFC applications.

Phanicha Tippawan; Amornchai Arpornwichanop

2014-01-01T23:59:59.000Z

447

Polyelectrolyte Materials for High Temperature Fuel Cells  

Broader source: Energy.gov (indexed) [DOE]

* Prepare solid electrolytes where only the proton moves. - Measure conductivity, mechanicalthermal properties of Nafion and other polyelectrolytes doped with imidazoles....

448

Energy balance in solid-oxide fuel assisted electrolyzer cell modules.  

E-Print Network [OSTI]

??High temperature electrolysis of water is a well-known method of extracting hydrogen, and has reduced electrical potential requirements when compared to low temperature electrolysis. The (more)

Butler, Bruce Jacob

2010-01-01T23:59:59.000Z

449

Developing TiAIN Coatings for Intermediate Temperature-Solid Oxide Fuel Cell Interconnect Applications  

SciTech Connect (OSTI)

TiN-type coatings have potential to be used as SOFC interconnect coatings SOFC because of their low resistance and high temperature stability. In this research, various (Ti,Al)N coatings were deposited on stainless steels by filtered-arc method. ASR and XRD tests were conducted on these coatings, and SEM/EDAX analysis were conducted after ASR and XRD tests. SEM/EDAX analyses show that (Ti,Al)N remains stable at temperature up to 700C. It is also indicated that Al has beneficial effect on the stability of TiN type coatings. At 900C, (Ti-30Al)N is fully oxidized and some of (Ti-50Al)N coating still remains as nitride. The analyses on cross-sectional samples show that these coatings are effective barrier to the Cr migration. In summary, (Ti.Al)N coatings are good candidates for the SOFC interconnect applications at 700C. The future directions of this research are to improve the stability of these coatings by alloy-doping and to develop multi-layer coatings.

Liu, X. (West Virginia University); Johnson, C.D.; Li, C. (West Virginia University); Xu, J. (West Virginia University); Cross, C.

2007-02-01T23:59:59.000Z

450

Vehicle Technologies Office: ORNL's High Temperature Materials Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ORNL's High Temperature ORNL's High Temperature Materials Laboratory Assists NASCAR Teams to someone by E-mail Share Vehicle Technologies Office: ORNL's High Temperature Materials Laboratory Assists NASCAR Teams on Facebook Tweet about Vehicle Technologies Office: ORNL's High Temperature Materials Laboratory Assists NASCAR Teams on Twitter Bookmark Vehicle Technologies Office: ORNL's High Temperature Materials Laboratory Assists NASCAR Teams on Google Bookmark Vehicle Technologies Office: ORNL's High Temperature Materials Laboratory Assists NASCAR Teams on Delicious Rank Vehicle Technologies Office: ORNL's High Temperature Materials Laboratory Assists NASCAR Teams on Digg Find More places to share Vehicle Technologies Office: ORNL's High Temperature Materials Laboratory Assists NASCAR Teams on AddThis.com...

451

Vehicle Technologies Office Merit Review 2014: High-Temperature...  

Broader source: Energy.gov (indexed) [DOE]

High-Temperature Air-Cooled Power Electronics Thermal Design Vehicle Technologies Office Merit Review 2014: High-Temperature Air-Cooled Power Electronics Thermal Design...

452

High Temperature Polymer Membrane Development at Argonne National...  

Broader source: Energy.gov (indexed) [DOE]

Polymer Membrane Development at Argonne National Laboratory High Temperature Polymer Membrane Development at Argonne National Laboratory Summary of ANL's high temperature polymer...

453

High Temperature Fuel Cells in the European Union  

Broader source: Energy.gov [DOE]

Presentation on High Temperature Fuel Cells in the European Union to the High Temperature Membrane Working Group, May 25, 2004 in Philadelphia, PA.

454

Low and high Temperature Dual Thermoelectric Generation Waste...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Low and high Temperature Dual Thermoelectric Generation Waste Heat Recovery System for Light-Duty Vehicles Low and high Temperature Dual Thermoelectric Generation Waste Heat...

455

High temperature membranes for DMFC (and PEFC) applications  

Broader source: Energy.gov [DOE]

Presentation on High temperature membranes for DMFCs (and PEFCs) to the High Temperature Membrane Working Group, May 25, 2004 in Philadelphia, PA.

456

Development of Advanced High Temperature Fuel Cell Membranes  

Broader source: Energy.gov [DOE]

Presentation on Development of Advanced High Temperature Fuel Cell Membranes to the High Temperature Membrane Working Group Meeting held in Arlington, Virginia, May 26,2005.

457

Development of a 100-Watt High Temperature Thermoelectric Generator...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Generator Development of a 100-Watt High Temperature Thermoelectric Generator Test results for low and high temperature thermoelectric generators (TEG) those for a...

458

A Discussion of Conductivity Testing in High Temperature Membranes...  

Broader source: Energy.gov (indexed) [DOE]

A Discussion of Conductivity Testing in High Temperature Membranes (lessons learned in assessing transport) A Discussion of Conductivity Testing in High Temperature Membranes...

459

High Temperature Polymer Membrane Development at Argonne National Laboratory  

Broader source: Energy.gov [DOE]

Summary of ANLs high temperature polymer membrane work presented to the High Temperature Membrane Working Group Meeting, Orlando FL, October 17, 2003

460

Nanostructured High-Temperature Bulk Thermoelectric Energy Conversion...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Nanostructured High-Temperature Bulk Thermoelectric Energy Conversion for Efficient Automotive Waste Heat Recovery Nanostructured High-Temperature Bulk Thermoelectric Energy...

Note: This page contains sample records for the topic "high-temperature solid oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Microchannel High-Temperature Recuperator for Fuel Cell Systems...  

Office of Environmental Management (EM)

Microchannel High-Temperature Recuperator for Fuel Cell Systems - Fact Sheet, 2014 Microchannel High-Temperature Recuperator for Fuel Cell Systems - Fact Sheet, 2014 FuelCell...

462

Polyelectrolyte Materials for High Temperature Fuel Cells | Department...  

Broader source: Energy.gov (indexed) [DOE]

Polyelectrolyte Materials for High Temperature Fuel Cells Polyelectrolyte Materials for High Temperature Fuel Cells This presentation, which focuses on polyelectrolyte materials...

463

High Reliability, High TemperatureThermoelectric Power Generation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Reliability, High TemperatureThermoelectric Power Generation Materials and Technologies High Reliability, High TemperatureThermoelectric Power Generation Materials and Technologies...

464

Applications of high-temperature superconductors in power technology  

Science Journals Connector (OSTI)

Since the discovery of the first high-temperature superconductors (HTSs) in the late 1980s, many materials and families of materials have been discovered that exhibit superconductivity at temperatures well above 20?K. Of these, several families of HTSs have been developed for use in electrical power applications. Demonstration of devices such as motors, generators, transmission lines, transformers, fault-current limiters, and flywheels in which HTSs and bulk HTSs have been used has proceeded to ever larger scales. First-generation wire, made from bismuth-based copper oxides, was used in many demonstrations. The rapid development of second-generation wire, made by depositing thin films of yttrium-based copper oxide on metallic substrates, is expected to further accelerate commercial applications. Bulk HTSs, in which large single-grain crystals are used as basic magnetic components, have also been developed and have potential for electrical power applications.

John R Hull

2003-01-01T23:59:59.000Z

465

Improved Martensitic Steel for High Temperature Applications  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Improved Martensitic Steel Improved Martensitic Steel for High Temperature Applications Opportunity Research is active on the patented technology, titled "Heat-Treated 9 Cr-1 Mo Steel for High Temperature Application." This technology is available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory (NETL). Overview The operating efficiency of coal-fired power plants is directly related to combustion system temperature and pressure. Incorporation of ultra- supercritical (USC) steam conditions into new or existing power plants can achieve increased efficiency and reduce coal consumption, while reducing carbon dioxide emissions as well as other pollutants. Traditionally used materials do not possess the optimal characteristics for operation

466

Manufacturing Barriers to High Temperature PEM Commercialization  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

9/2011 9/2011 1 BASF Fuel Cell, Inc. Manufacturing Barriers to high temperature PEM commercialization 39 Veronica Ave Somerset , NJ 08873 Tel : (732) 545-5100 9/9/2011 2 Background on BASF Fuel Cell  BASF Fuel Cell was established in 2007, formerly PEMEAS Fuel Cells (including E-TEK)  Product line is high temperature MEAs (Celtec ® P made from PBI-phosphoric acid)  Dedicated a new advanced pilot manufacturing facility in Somerset NJ May 2009. Ribbon-cutting hosted by Dr. Kreimeyer (BASF BoD, right) and attended by various US pubic officials including former NJ Governor Jon Corzine (left) 9/9/2011 3 Multi-layer product of membrane (polybenzimidazole and phosphoric acid), gas diffusion material and catalysts Unique characteristics:  High operating temperature

467

Compilation of CFD Models of Various Solid Oxide Electrolyzers Analyzed at the Idaho National Laboratory  

SciTech Connect (OSTI)

Various three dimensional computational fluid dynamics (CFD) models of solid oxide electrolyzers have been created and analyzed at the Idaho National Laboratory since the inception of the Nuclear Hydrogen Initiative in 2004. Three models presented herein include: a 60 cell planar cross flow with inlet and outlet plenums, 10 cell integrated planar cross flow, and internally manifolded five cell planar cross flow. Mass, momentum, energy, and species conservation and transport are provided via the core features of the commercial CFD code FLUENT. A solid-oxide fuel cell (SOFC) module adds the electrochemical reactions and loss mechanisms and computation of the electric field throughout the cell. The FLUENT SOFC user-defined subroutine was modified for this work to allow for operation in the SOEC mode. Model results provide detailed profiles of temperature, Nernst potential, operating potential, activation over-potential, anode-side gas composition, cathode-side gas composition, current density and hydrogen production over a range of stack operating conditions. Predicted mean outlet hydrogen and steam concentrations vary linearly with current density, as expected. Contour plots of local electrolyte temperature, current density, and Nernst potential indicated the effects of heat transfer, endothermic reaction, Ohmic heating, and change in local gas composition. Results are discussed for using these models in the electrolysis mode. Discussion of thermal neutral voltage, enthalpy of reaction, hydrogen production is reported herein. Contour plots and discussion show areas of likely cell degradation, flow distribution in inlet plenum, and flow distribution across and along the flow channels of the current collectors

Grant Hawkes; James O'Brien

2012-06-01T23:59:59.000Z

468

Solid oxide fuel cell with multi-unit construction and prismatic design  

DOE Patents [OSTI]

A single cell unit of a solid oxide fuel cell is described that is individually fabricated and sintered prior to being connected to adjacent cells to form a solid oxide fuel cell. The single cell unit is comprised of a shaped anode sheet positioned between a flat anode sheet and an anode-electrolyte-cathode (A/E/C) sheet, and a shaped cathode sheet positioned between the A/E/C sheet and a cathode-interconnect-anode (C/I/A) sheet. An alternate embodiment comprises a shaped cathode sheet positioned between an A/E/C sheet and a C/I/A sheet. The shaped sheets form channels for conducting reactant gases. Each single cell unit is individually sintered to form a finished sub-assembly. The finished sub-assemblies are connected in electrical series by interposing connective material between the end surfaces of adjacent cells, whereby individual cells may be inspected for defects and interchanged with non-defective single cell units. 7 figs.

McPheeters, C.C.; Dees, D.W.; Myles, K.M.

1999-03-16T23:59:59.000Z

469

Solid oxide fuel cell with multi-unit construction and prismatic design  

DOE Patents [OSTI]

A single cell unit of a solid oxide fuel cell that is individually fabricated and sintered prior to being connected to adjacent cells to form a solid oxide fuel cell. The single cell unit is comprised of a shaped anode sheet positioned between a flat anode sheet and an anode-electrolyte-cathode (A/E/C) sheet, and a shaped cathode sheet positioned between the A/E/C sheet and a cathode-interconnect-anode (C/I/A) sheet. An alternate embodiment comprises a shaped cathode sheet positioned between an A/E/C sheet and a C/I/A sheet. The shaped sheets form channels for conducting reactant gases. Each single cell unit is individually sintered to form a finished sub-assembly. The finished sub-assemblies are connected in electrical series by interposing connective material between the end surfaces of adjacent cells, whereby individual cells may be inspected for defects and interchanged with non-defective single cell units.

McPheeters, Charles C. (Naperville, IL); Dees, Dennis W. (Downers Grove, IL); Myles, Kevin M. (Downers Grove, IL)

1999-01-01T23:59:59.000Z

470

CFD Model Of A Planar Solid Oxide Electrolysis Cell For Hydrogen Production From Nuclear Energy  

SciTech Connect (OSTI)

A three-dimensional computational fluid dynamics (CFD) model has been created to model hightemperature steam electrolysis in a planar solid oxide electrolysis cell (SOEC). The model represents a single cell as it would exist in an electrolysis stack. Details of the model geometry are specific to a stack that was fabricated by Ceramatec2, Inc. and tested at the Idaho National Laboratory. Mass, momentum, energy, and species conservation and transport are provided via the core features of the commercial CFD code FLUENT2. A solid-oxide fuel cell (SOFC) model adds the electrochemical reactions and loss mechanisms and computation of the electric field throughout the cell. The FLUENT SOFC user-defined subroutine was modified for this work to allow for operation in the SOEC mode. Model results provide detailed profiles of temperature, Nernst potential, operating potential, anode-side gas composition, cathode-side gas composition, current density and hydrogen production over a range of stack operating conditions. Mean model results are shown to compare favorably with experimental results obtained from an actual ten-cell stack tested at INL.

Grant L. Hawkes; James E. O'Brien; Carl M. Stoots; J. Stephen Herring

2005-10-01T23:59:59.000Z

471

TAPE CALENDERING MANUFACTURING PROCESS FOR MULTILAYER THIN-FILM SOLID OXIDE FUEL CELLS  

SciTech Connect (OSTI)

This report summarizes the work performed by Hybrid Power Generation Systems, LLC during the Phases I and II under Contract DE-AC26-00NT40705 for the U. S. Department of Energy, National Energy Technology Laboratory (DOE/NETL) entitled ''Tape Calendering Manufacturing Process For Multilayer Thin-Film Solid Oxide Fuel Cells''. The main objective of this project was to develop the manufacturing process based on tape calendering for multilayer solid oxide fuel cells (SOFC's) using the unitized cell design concept and to demonstrate cell performance under specified operating conditions. Summarized in this report is the development and improvements to multilayer SOFC cells and the unitized cell design. Improvements to the multilayer SOFC cell were made in electrochemical performance, in both the anode and cathode, with cells demonstrating power densities of nearly 0.9 W/cm{sup 2} for 650 C operation and other cell configurations showing greater than 1.0 W/cm{sup 2} at 75% fuel utilization and 800 C. The unitized cell design was matured through design, analysis and development testing to a point that cell operation at greater than 70% fuel utilization was demonstrated at 800 C. The manufacturing process for both the multilayer cell and unitized cell design were assessed and refined, process maps were developed, forming approaches explored, and nondestructive evaluation (NDE) techniques examined.

Nguyen Minh; Kurt Montgomery

2004-10-01T23:59:59.000Z

472

Thermal fuse for high-temperature batteries  

DOE Patents [OSTI]

A thermal fuse, preferably for a high-temperature battery, comprising leads and a body therebetween having a melting point between approximately 400.degree. C. and 500.degree. C. The body is preferably an alloy of Ag--Mg, Ag--Sb, Al--Ge, Au--In, Bi--Te, Cd--Sb, Cu--Mg, In--Sb, Mg--Pb, Pb--Pd, Sb--Zn, Sn--Te, or Mg--Al.

Jungst, Rudolph G. (Albuquerque, NM); Armijo, James R. (Albuquerque, NM); Frear, Darrel R. (Austin, TX)

2000-01-01T23:59:59.000Z

473

Magnetism in Iron at High Temperatures  

Science Journals Connector (OSTI)

Magnetism in iron at high temperature is investigated by calculating the total electronic band-structure energy for four types of spin arrangements. A slow smooth spatial variation of spin direction costs relatively little energy and the atomic moment m is reduced only ? 10%. More rapid variations have considerably higher energy, which may explain the high degree of short-range order and small ?m observed at T?TC. Other aspects are also discussed.

M. V. You; V. Heine; A. J. Holden; P. J. Lin-Chung

1980-05-12T23:59:59.000Z

474

Establishment of Harrop, High-Temperature Viscometer  

SciTech Connect (OSTI)

This report explains how the Harrop, High-Temperature Viscometer was installed, calibrated, and operated. This report includes assembly and alignment of the furnace, viscometer, and spindle, and explains the operation of the Brookfield Viscometer, the Harrop furnace, and the UDC furnace controller. Calibration data and the development of the spindle constant from NIST standard reference glasses is presented. A simple operational procedure is included.

Schumacher, R.F.

1999-11-05T23:59:59.000Z

475

Charged Vortices in High Temperature Superconductors  

Science Journals Connector (OSTI)

It is argued that in the mixed state of a type II superconductor, because of the difference of the chemical potential in a superconducting versus normal state, the vortex cores may become charged. The extra electron density is estimated. The extra charge contributes to the dynamics of the vortices; in particular, it can explain in certain cases the change of the sign of the Hall coefficient below Tc frequently observed in the high temperature superconductors.

D. I. Khomskii and A. Freimuth

1995-08-14T23:59:59.000Z

476

High Temperature Materials for Aerospace Applications  

E-Print Network [OSTI]

below 430 ?C for exposure times up to 20 minutes. Transition-metal carbides were initially synthesized by carbothermal reduction of transition-metal halides and polymer precursor mixtures, at temperatures that range from 900 to 1500 ?C in an argon... ........................................ 20 2.3 Present/Future Aerospace Applications ......................................... 24 2.4 Ultra-High Temperature Materials ................................................. 27 2.4.1 Transition-Metal Carbides...

Adamczak, Andrea Diane

2011-08-08T23:59:59.000Z

477

Application of LaSr2Fe2CrO9-in Solid Oxide Fuel Cell Jacob M. Haag,a  

E-Print Network [OSTI]

Application of LaSr2Fe2CrO9- in Solid Oxide Fuel Cell Anodes Jacob M. Haag,a Brian D. Madsen composition LaSr2Fe2CrO9- was tested for application as an anode material for solid oxide fuel cells. Despite 28, 2008. Ni­yttria stabilized zirconia YSZ cermets are commonly used in solid oxide fuel cell SOFC

Poeppelmeier, Kenneth R.

478

Thermoeconomic Modeling and Parametric Study of Hybrid Solid Oxide Fuel Cell Gas Turbine Steam Turbine Power Plants Ranging from 1.5 MWe to 10 MWe.  

E-Print Network [OSTI]

??Detailed thermodynamic, kinetic, geometric, and cost models are developed, implemented, and validated for the synthesis/design and operational analysis of hybrid solid oxide fuel cell (SOFC) (more)

Arsalis, Alexandros

2007-01-01T23:59:59.000Z

479

Promoting Effect of Pt on Self-activation over NiOMgO Solid Solution in Oxidative Steam Reforming of Methane  

Science Journals Connector (OSTI)

The addition of Pt on NiOMgO solid solution enhanced the performance of oxidative steam reforming of methane, especially, the catalyst can be activated during the oxidative reforming of methane at low reaction t...

Mohammad Nurunnabi; Baitao Li; Kimio Kunimori; Kimihito Suzuki

2005-10-01T23:59:59.000Z

480

Extended Durability Testing of an External Fuel Processor for a Solid Oxide Fuel Cell (SOFC)  

SciTech Connect (OSTI)

Durability testing was performed on an external fuel processor (EFP) for a solid oxide fuel cell (SOFC) power plant. The EFP enables the SOFC to reach high system efficiency (electrical efficiency up to 60%) using pipeline natural gas and eliminates the need for large quantities of bottled gases. LG Fuel Cell Systems Inc. (formerly known as Rolls-Royce Fuel Cell Systems (US) Inc.) (LGFCS) is developing natural gas-fired SOFC power plants for stationary power applications. These power plants will greatly benefit the public by reducing the cost of electricity while reducing the amount of gaseous emissions of carbon dioxide, sulfur oxides, and nitrogen oxides compared to conventional power plants. The EFP uses pipeline natural gas and air to provide all the gas streams required by the SOFC power plant; specifically those needed for start-up, normal operation, and shutdown. It includes a natural gas desulfurizer, a synthesis-gas generator and a start-gas generator. The research in this project demonstrated that the EFP could meet its performance and durability targets. The data generated helped assess the impact of long-term operation on system performance and system hardware. The research also showed the negative impact of ambient weather (both hot and cold conditions) on system operation and performance.

Mark Perna; Anant Upadhyayula; Mark Scotto

2012-11-05T23:59:59.000Z

Note: This page contains sample records for the topic "high-temperature solid oxide" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


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