National Library of Energy BETA

Sample records for high-temperature reservoir evidence

  1. HIGH TEMPERATURE GEOTHERMAL RESERVOIR ENGINEERING

    E-Print Network [OSTI]

    Schroeder, R.C.

    2009-01-01

    on the Cerro P r i e t o Geothermal F i e l d , Mexicali,e C e r r o P r i e t o Geothermal F i e l d , Baja C a l i1979 HIGH TEMPERATURE GEOTHERMAL RESERVOIR ENGINEERING R.

  2. The Northwest Geysers High-Temperature Reservoir- Evidence For...

    Open Energy Info (EERE)

    the HTR is magmatic, and add new constraints to genetic models of the system and its evolution. The intensity of the magmatic signal is inconsistent with deep boiling of connate...

  3. The Northwest Geysers High-Temperature Reservoir- Evidence For Active

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EISTJ AutomationTexas/Wind ResourcesProgram Jump

  4. DSC Evidence for Microstructure and Phase Transitions in Polyethylene Melts at High Temperatures

    E-Print Network [OSTI]

    Hussein, Ibnelwaleed A.

    DSC Evidence for Microstructure and Phase Transitions in Polyethylene Melts at High Temperatures polyethylenes of types HDPE, LDPE, and LLDPE. DSC data were obtained for a range of heating and cooling rates previous rheology findings of order and high-temperature transitions in polyethylene melts. Introduction

  5. Enhanced Oil Recovery in High Salinity High Temperature Reservoir by Chemical Flooding 

    E-Print Network [OSTI]

    Bataweel, Mohammed Abdullah

    2012-02-14

    that contain high concentrations of divalent cations without the need to recondition the reservoir by flooding it with less saline/ less hardness brines. This strategy was found ineffective in preparing the reservoir for chemical flooding. Surfactants used...

  6. Simulation Study for Improving Seawater Polymer Flood Performance in Stratified High Temperature Reservoirs 

    E-Print Network [OSTI]

    Niu, Geng

    2014-12-10

    Polymer flood has achieved technical and commercial success, especially for its large-scale application in the Daqing oilfield in China. However, previous field tests indicated polymer flood was not economically successful for high temperature...

  7. Technological problems associated with subsea development of high pressure and high temperature hydrocarbon reservoirs

    SciTech Connect (OSTI)

    Grillo, P.; Natarajan, S.

    1996-12-31

    The paper analyzes the implications in design of subsea completion for exploitation of HP/HT hydrocarbon reservoirs. The paper characterizes limitations associated with current subsea technology for HP/HT applications and outlines the engineering and technological development considered necessary to demonstrate the viability of subsea production technology for the exploitation of HP/HT reservoirs.

  8. The development of a correlation for determining oil density in high temperature reservoirs 

    E-Print Network [OSTI]

    Witte, Thurman William

    1987-01-01

    -hydrocarbon components. The correlations were developed using non- linear regression methods on laboratory data from 1310 reservoir fluid samples. DEDICATION This thesis is dedicated to the following people who have been very important in my life: My daughter... OF LITERATURE IDEAL SOLUTION THEORY DATA BASE DEVELOPMENT ANALYSIS OF DATA AND DEVELOPMENT QF EQUATIONS CORRECTION TO DENSITY DUE TO THERMAL EXPANSION CALCULATION OF PSEUDOLIQUID DENSITY FROM COMPOSITION Page 1V V1 V11 Xii 12 15 15 25 NON...

  9. High Temperatures & Electricity Demand

    E-Print Network [OSTI]

    High Temperatures & Electricity Demand An Assessment of Supply Adequacy in California Trends.......................................................................................................1 HIGH TEMPERATURES AND ELECTRICITY DEMAND.....................................................................................................................7 SECTION I: HIGH TEMPERATURES AND ELECTRICITY DEMAND ..........................9 BACKGROUND

  10. High-Temperature Superconductivity

    ScienceCinema (OSTI)

    Peter Johnson

    2010-01-08

    Like astronomers tweaking images to gain a more detailed glimpse of distant stars, physicists at Brookhaven National Laboratory have found ways to sharpen images of the energy spectra in high-temperature superconductors ? materials that carry electrical c

  11. High-temperature sensor

    DOE Patents [OSTI]

    Not Available

    1981-01-29

    A high temperature sensor is described which includes a pair of electrical conductors separated by a mass of electrical insulating material. The insulating material has a measurable resistivity within the sensor that changes in relation to the temperature of the insulating material within a high temperature range (1000 to 2000/sup 0/K). When required, the sensor can be encased within a ceramic protective coating.

  12. High temperature pressure gauge

    DOE Patents [OSTI]

    Echtler, J. Paul (Pittsburgh, PA); Scandrol, Roy O. (Library, PA)

    1981-01-01

    A high temperature pressure gauge comprising a pressure gauge positioned in fluid communication with one end of a conduit which has a diaphragm mounted in its other end. The conduit is filled with a low melting metal alloy above the diaphragm for a portion of its length with a high temperature fluid being positioned in the remaining length of the conduit and in the pressure gauge.

  13. PROCEEDINGS, Twenty-Seventh Workshop on Geothermal Reservoir Engineering Stanford University, Stanford, California, January 28-30, 2002

    E-Print Network [OSTI]

    Boyer, Edmond

    and with magmatic CO2 emanations (minimum CO2 partial pressure estimated to 1 bar). Relative to a diluted sea water laterally from NW to SE at relatively low depths. No major evidence of a high temperature geothermal, 1984 and 1985 showed no major shallow evidences of the occurrence of an high temperature reservoir

  14. High temperature storage battery

    SciTech Connect (OSTI)

    Sammells, A.F.

    1988-06-07

    A high temperature electrochemical cell is described comprising: a solid-state divalent cation conducting electrolyte; a positive electrode in contact with the electrolyte; a solid-state negative electrode contacting a divalent cation conducting molten salt mediating agent providing ionic mediation between the solid-state negative electrode and the solid-state electrolyte.

  15. High Temperature ESP Monitoring

    Broader source: Energy.gov [DOE]

    The purpose of the High Temperature ESP Monitoring project is to develop a down-hole monitoring system to be used in wells with bottom hole temperature up to 300 °C for measuring motor temperature; pump discharge pressure; and formation temperature and pressure.

  16. High Temperature ESP Monitoring

    SciTech Connect (OSTI)

    Jack Booker; Brindesh Dhruva

    2011-06-20

    The objective of the High Temperature ESP Monitoring project was to develop a downhole monitoring system to be used in wells with bottom hole well temperatures up to 300°C for measuring motor temperature, formation pressure, and formation temperature. These measurements are used to monitor the health of the ESP motor, to track the downhole operating conditions, and to optimize the pump operation. A 220 ºC based High Temperature ESP Monitoring system was commercially released for sale with Schlumberger ESP motors April of 2011 and a 250 ºC system with will be commercially released at the end of Q2 2011. The measurement system is now fully qualified, except for the sensor, at 300 °C.

  17. High Temperature Membrane Working Group

    Broader source: Energy.gov [DOE]

    This presentation provides an overview of the High Temperature Membrane Working Group Meeting in May 2007.

  18. High temperature thermometric phosphors

    DOE Patents [OSTI]

    Allison, Stephen W. (Knoxville, TN); Cates, Michael R. (Oak Ridge, TN); Boatner, Lynn A. (Oak Ridge, TN); Gillies, George T. (Earlysville, VA)

    1999-03-23

    A high temperature phosphor consists essentially of a material having the general formula LuPO.sub.4 :Dy.sub.(x),Eu.sub.y) wherein: 0.1 wt %.ltoreq.x.ltoreq.20 wt % and 0.1 wt %.ltoreq.y.ltoreq.20 wt %. The high temperature phosphor is in contact with an article whose temperature is to be determined. The article having the phosphor in contact with it is placed in the environment for which the temperature of the article is to be determined. The phosphor is excited by a laser causing the phosphor to fluoresce. The emission from the phosphor is optically focused into a beam-splitting mirror which separates the emission into two separate emissions, the emission caused by the dysprosium dopant and the emission caused by the europium dopent. The separated emissions are optically filtered and the intensities of the emission are detected and measured. The ratio of the intensity of each emission is determined and the temperature of the article is calculated from the ratio of the intensities of the separate emissions.

  19. High temperature thermometric phosphors

    DOE Patents [OSTI]

    Allison, S.W.; Cates, M.R.; Boatner, L.A.; Gillies, G.T.

    1999-03-23

    A high temperature phosphor consists essentially of a material having the general formula LuPO{sub 4}:Dy{sub x},Eu{sub y} wherein: 0.1 wt % {<=} x {<=} 20 wt % and 0.1 wt % {<=} y {<=} 20 wt %. The high temperature phosphor is in contact with an article whose temperature is to be determined. The article having the phosphor in contact with it is placed in the environment for which the temperature of the article is to be determined. The phosphor is excited by a laser causing the phosphor to fluoresce. The emission from the phosphor is optically focused into a beam-splitting mirror which separates the emission into two separate emissions, the emission caused by the dysprosium dopant and the emission caused by the europium dopant. The separated emissions are optically filtered and the intensities of the emission are detected and measured. The ratio of the intensity of each emission is determined and the temperature of the article is calculated from the ratio of the intensities of the separate emissions. 2 figs.

  20. High temperature interfacial superconductivity

    DOE Patents [OSTI]

    Bozovic, Ivan (Mount Sinai, NY); Logvenov, Gennady (Port Jefferson Station, NY); Gozar, Adrian Mihai (Port Jefferson, NY)

    2012-06-19

    High-temperature superconductivity confined to nanometer-scale interfaces has been a long standing goal because of potential applications in electronic devices. The spontaneous formation of a superconducting interface in bilayers consisting of an insulator (La.sub.2CuO.sub.4) and a metal (La.sub.1-xSr.sub.xCuO.sub.4), neither of which is superconducting per se, is described. Depending upon the layering sequence of the bilayers, T.sub.c may be either .about.15 K or .about.30 K. This highly robust phenomenon is confined to within 2-3 nm around the interface. After exposing the bilayer to ozone, T.sub.c exceeds 50 K and this enhanced superconductivity is also shown to originate from a 1 to 2 unit cell thick interfacial layer. The results demonstrate that engineering artificial heterostructures provides a novel, unconventional way to fabricate stable, quasi two-dimensional high T.sub.c phases and to significantly enhance superconducting properties in other superconductors. The superconducting interface may be implemented, for example, in SIS tunnel junctions or a SuFET.

  1. RECHARGEABLE HIGH-TEMPERATURE BATTERIES

    E-Print Network [OSTI]

    Cairns, Elton J.

    2014-01-01

    F. Eshman, High-Performance Batteries for Electric-VehicleS. Sudar, High Performance Batteries for Electric-VehicleHIGH-TEMPERATURE BATTERIES Elton J. Cairns January 1981 TWO-

  2. Acidizing High-Temperature Carbonate Formations Using Methanesulfonic Acid 

    E-Print Network [OSTI]

    Ortega, Alexis

    2015-03-25

    Hydrochloric acid (HCl) is the most commonly used stimulation fluid for high-temperature wells drilled in carbonate reservoirs due to its high dissolving power and low cost. However, the high corrosion rate of HCl on well tubulars could make its use...

  3. Encapsulation of High Temperature Thermoelectric Modules | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Encapsulation of High Temperature Thermoelectric Modules Encapsulation of High Temperature Thermoelectric Modules Presents concept for hermetic encapsulation of TE modules...

  4. Philosophy 26 High Temperature Superconductivity

    E-Print Network [OSTI]

    Callender, Craig

    Philosophy 26 High Temperature Superconductivity By Ohm's Law, resistance will dim. Low temperature superconductivity was discovered in 1911 by Heike was explained by BCS theory. BCS theory explains superconductivity microscopically

  5. Microlaminated high temperature intermetallic composites

    SciTech Connect (OSTI)

    Rowe, R.G.; Skelly, D.W.; Larsen, M. (GE Corporate Research and Development, Schenectady, NY (United States)); Heathcote, J.; Odette, G.R.; Lucas, G.E. (Univ. of California, Santa Barbara, CA (United States). Materials Dept.)

    1994-12-01

    The thrust to weight ratio of aircraft engines is limited by the density and elevated temperature capability of high temperature turbine materials. Single crystal superalloys, which are the current state-of-the-art in high temperature turbine blade materials, have limited potential for further increases in temperature capability. High temperature intermetallics offer the advantage of higher specific strength and higher temperature capability, but lack ductility and fracture toughness below 1,000 C. By compositing these very high temperature intermetallics with ductile metals, toughening may be improved to the point where the composites have applicability in aircraft engine turbine sections. Lamination of ductile metals with continuous intermetallic layers offers one means of producing such composites. Small lamellae thicknesses may have advantages related to intrinsic defect sizes and the effectiveness of ductile reinforcements in load-controlled applications where strength is important. Intermetallic composites will require a refractory metal for toughening because of the need for metal strength at temperatures above 1,100 C. Niobium-base alloys were selected as the toughening layer in this study because of experience with oxidation-resistant niobium alloys with low densities compared to superalloys and the existence of metal-intermetallic systems in equilibrium at high temperatures. Two microlaminated composite systems, Nb[sub 3]Al-Nb and Cr[sub 2]Nb(Cr) were chosen for microstructural and mechanical property evaluation. The choice of systems was partially based upon knowledge of phase relations between the metal and the intermetallic compositions.

  6. High temperature superconductor current leads

    DOE Patents [OSTI]

    Hull, John R. (Hinsdale, IL); Poeppel, Roger B. (Glen Ellyn, IL)

    1995-01-01

    An electrical lead having one end for connection to an apparatus in a cryogenic environment and the other end for connection to an apparatus outside the cryogenic environment. The electrical lead includes a high temperature superconductor wire and an electrically conductive material distributed therein, where the conductive material is present at the one end of the lead at a concentration in the range of from 0 to about 3% by volume, and at the other end of the lead at a concentration of less than about 20% by volume. Various embodiments are shown for groups of high temperature superconductor wires and sheaths.

  7. High temperature lightweight foamed cements

    DOE Patents [OSTI]

    Sugama, Toshifumi (Mastic Beach, NY)

    1989-01-01

    Cement slurries are disclosed which are suitable for use in geothermal wells since they can withstand high temperatures and high pressures. The formulation consists of cement, silica flour, water, a retarder, a foaming agent, a foam stabilizer, and a reinforcing agent. A process for producing these cements is also disclosed.

  8. High temperature lightweight foamed cements

    DOE Patents [OSTI]

    Sugama, Toshifumi.

    1989-10-03

    Cement slurries are disclosed which are suitable for use in geothermal wells since they can withstand high temperatures and high pressures. The formulation consists of cement, silica flour, water, a retarder, a foaming agent, a foam stabilizer, and a reinforcing agent. A process for producing these cements is also disclosed. 3 figs.

  9. High temperature turbine engine structure

    DOE Patents [OSTI]

    Boyd, Gary L. (Tempe, AZ)

    1990-01-01

    A high temperature turbine engine includes a hybrid ceramic/metallic rotor member having ceramic/metal joint structure. The disclosed joint is able to endure higher temperatures than previously possible, and aids in controlling heat transfer in the rotor member.

  10. High temperature turbine engine structure

    DOE Patents [OSTI]

    Boyd, Gary L. (Tempe, AZ)

    1991-01-01

    A high temperature turbine engine includes a rotor portion having axially stacked adjacent ceramic rotor parts. A ceramic/ceramic joint structure transmits torque between the rotor parts while maintaining coaxial alignment and axially spaced mutually parallel relation thereof despite thermal and centrifugal cycling.

  11. HYDROGEN SULFIDE -HIGH TEMPERATURE DRILLING CONTINGENCY PLAN

    E-Print Network [OSTI]

    HYDROGEN SULFIDE - HIGH TEMPERATURE DRILLING CONTINGENCY PLAN OCEAN DRILLING PROGRAM TEXAS A Foundation. ii #12;HYDROGEN SULFIDE-HIGH TEMPERATURE DRILLING CONTINGENCY PLAN OCEAN DRILLING PROGRAM LEG 139

  12. Acid Doped Membranes for High Temperature PEMFC

    Broader source: Energy.gov [DOE]

    Presentation on Acid Doped Membranes for High Temperature PEMFC to the High Temperature Membrane Working Group, May 25, 2004 in Philadelphia, PA.

  13. High-Temperature Thermoelectric Materials Characterization for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Temperature Thermoelectric Materials Characterization for Automotive Waste Heat Recovery: Success Stories from the High Temperature Materials Laboratory (HTML) User Program...

  14. High Temperature Thermoelectric Materials Characterization for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Temperature Thermoelectric Materials Characterization for Automotive Waste Heat Recovery: Success Stories from the High Temperature Materials Laboratory (HTML) User Program...

  15. Manufacturing Barriers to High Temperature PEM Commercialization...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Barriers to High Temperature PEM Commercialization Manufacturing Barriers to High Temperature PEM Commercialization Presented at the NREL Hydrogen and Fuel Cell Manufacturing R&D...

  16. High temperature turbine engine structure

    DOE Patents [OSTI]

    Carruthers, William D. (Mesa, AZ); Boyd, Gary L. (Tempe, AZ)

    1993-01-01

    A high temperature ceramic/metallic turbine engine includes a metallic housing which journals a rotor member of the turbine engine. A ceramic disk-like shroud portion of the engine is supported on the metallic housing portion and maintains a close running clearance with the rotor member. A ceramic spacer assembly maintains the close running clearance of the shroud portion and rotor member despite differential thermal movements between the shroud portion and metallic housing portion.

  17. High temperature turbine engine structure

    DOE Patents [OSTI]

    Carruthers, William D. (Mesa, AZ); Boyd, Gary L. (Tempe, AZ)

    1994-01-01

    A high temperature ceramic/metallic turbine engine includes a metallic housing which journals a rotor member of the turbine engine. A ceramic disk-like shroud portion of the engine is supported on the metallic housing portion and maintains a close running clearance with the rotor member. A ceramic spacer assembly maintains the close running clearance of the shroud portion and rotor member despite differential thermal movements between the shroud portion and metallic housing portion.

  18. High temperature turbine engine structure

    DOE Patents [OSTI]

    Carruthers, William D. (Mesa, AZ); Boyd, Gary L. (Tempe, AZ)

    1992-01-01

    A high temperature ceramic/metallic turbine engine includes a metallic housing which journals a rotor member of the turbine engine. A ceramic disk-like shroud portion of the engine is supported on the metallic housing portion and maintains a close running clearance with the rotor member. A ceramic spacer assembly maintains the close running clearance of the shroud portion and rotor member despite differential thermal movements between the shroud portion and metallic housing portion.

  19. High Temperature 300°C Directional Drilling System

    SciTech Connect (OSTI)

    Chatterjee, Kamalesh; Aaron, Dick; Macpherson, John

    2015-07-31

    Many countries around the world, including the USA, have untapped geothermal energy potential. Enhanced Geothermal Systems (EGS) technology is needed to economically utilize this resource. Temperatures in some EGS reservoirs can exceed 300°C. To effectively utilize EGS resources, an array of injector and production wells must be accurately placed in the formation fracture network. This requires a high temperature directional drilling system. Most commercial services for directional drilling systems are rated for 175°C while geothermal wells require operation at much higher temperatures. Two U.S. Department of Energy (DOE) Geothermal Technologies Program (GTP) projects have been initiated to develop a 300°C capable directional drilling system, the first developing a drill bit, directional motor, and drilling fluid, and the second adding navigation and telemetry systems. This report is for the first project, “High Temperature 300°C Directional Drilling System, including drill bit, directional motor and drilling fluid, for enhanced geothermal systems,” award number DE-EE0002782. The drilling system consists of a drill bit, a directional motor, and drilling fluid. The DOE deliverables are three prototype drilling systems. We have developed three drilling motors; we have developed four roller-cone and five Kymera® bits; and finally, we have developed a 300°C stable drilling fluid, along with a lubricant additive for the metal-to-metal motor. Metal-to-metal directional motors require coatings to the rotor and stator for wear and corrosion resistance, and this coating research has been a significant part of the project. The drill bits performed well in the drill bit simulator test, and the complete drilling system has been tested drilling granite at Baker Hughes’ Experimental Test Facility in Oklahoma. The metal-to-metal motor was additionally subjected to a flow loop test in Baker Hughes’ Celle Technology Center in Germany, where it ran for more than 100 hours.

  20. Pressure Testing of a High Temperature Naturally Fractured Reservoir...

    Office of Scientific and Technical Information (OSTI)

    m). The formation is a naturally fractured granite at temperatures of about 250 C. The matrix porosity is < 1%and permeability is on the order of 1 nD (10 msup 2). Hence most of...

  1. Well Productivity Enhancement of High Temperature Heterogeneous Carbonate Reservoirs 

    E-Print Network [OSTI]

    Wang, Guanqun

    2014-05-08

    . Uneven acid distribution always results in productivity enhancement under expectation. When such a well is drilled, the temperature of the well could be too high to keep the acid reaction under control. The acid used in the treatment fluid, most commonly...

  2. Pressure Testing of a High Temperature Naturally Fractured Reservoir

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTech ConnectSpeeding accessusers'(x≤2) surface:SciTech ConnectTransition.to

  3. Pressure Testing of a High Temperature Naturally Fractured Reservoir

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTech ConnectSpeeding accessusers'(x≤2) surface:SciTech

  4. High-Temperature Quantum Coherence from Dissipative Environments

    E-Print Network [OSTI]

    George E. Cragg

    2014-11-14

    The Feynman-Vernon path integral formalism is used to derive the density matrix of a quantum oscillator that is linearly coupled to an environmental reservoir. Although low-temperature reservoirs thermalize the oscillator to the usual Boltzmann distribution, reservoirs at intermediate temperatures reduce this distribution to a single, coherent ground state. Associated with this state is an imaginary frequency indicating an environment which absorbs energy from the oscillator through the suppression of all excited modes. Further increase of the environmental temperature results again in the thermalization of the quantum oscillator to the expected Boltzmann distribution. Qualitatively, this result could account for high-temperature quantum effects including the superconducting properties of graphite grains as well as the quantum coherence observed in photosynthetic systems.

  5. High-temperature-measuring device

    DOE Patents [OSTI]

    Not Available

    1981-01-27

    A temperature measuring device for very high design temperatures (to 2000/sup 0/C) is described. The device comprises a homogenous base structure preferably in the form of a sphere or cylinder. The base structure contains a large number of individual walled cells. The base structure has a decreasing coefficient of elasticity within the temperature range being monitored. A predetermined quantity of inert gas is confined within each cell. The cells are dimensonally stable at the normal working temperature of the device. Increases in gaseous pressure within the cells will permanently deform the cell walls at temperatures within the high temperature range to be measured. Such deformation can be correlated to temperature by calibrating similarly constructed devices under known time and temperature conditions.

  6. Faraday imaging at high temperatures

    DOE Patents [OSTI]

    Hackel, L.A.; Reichert, P.

    1997-03-18

    A Faraday filter rejects background light from self-luminous thermal objects, but transmits laser light at the passband wavelength, thus providing an ultra-narrow optical bandpass filter. The filter preserves images so a camera looking through a Faraday filter at a hot target illuminated by a laser will not see the thermal radiation but will see the laser radiation. Faraday filters are useful for monitoring or inspecting the uranium separator chamber in an atomic vapor laser isotope separation process. Other uses include viewing welds, furnaces, plasma jets, combustion chambers, and other high temperature objects. These filters are can be produced at many discrete wavelengths. A Faraday filter consists of a pair of crossed polarizers on either side of a heated vapor cell mounted inside a solenoid. 3 figs.

  7. Faraday imaging at high temperatures

    DOE Patents [OSTI]

    Hackel, Lloyd A. (Livermore, CA); Reichert, Patrick (Hayward, CA)

    1997-01-01

    A Faraday filter rejects background light from self-luminous thermal objects, but transmits laser light at the passband wavelength, thus providing an ultra-narrow optical bandpass filter. The filter preserves images so a camera looking through a Faraday filter at a hot target illuminated by a laser will not see the thermal radiation but will see the laser radiation. Faraday filters are useful for monitoring or inspecting the uranium separator chamber in an atomic vapor laser isotope separation process. Other uses include viewing welds, furnaces, plasma jets, combustion chambers, and other high temperature objects. These filters are can be produced at many discrete wavelengths. A Faraday filter consists of a pair of crossed polarizers on either side of a heated vapor cell mounted inside a solenoid.

  8. High temperature control rod assembly

    DOE Patents [OSTI]

    Vollman, Russell E. (Solana Beach, CA)

    1991-01-01

    A high temperature nuclear control rod assembly comprises a plurality of substantially cylindrical segments flexibly joined together in succession by ball joints. The segments are made of a high temperature graphite or carbon-carbon composite. The segment includes a hollow cylindrical sleeve which has an opening for receiving neutron-absorbing material in the form of pellets or compacted rings. The sleeve has a threaded sleeve bore and outer threaded surface. A cylindrical support post has a threaded shaft at one end which is threadably engaged with the sleeve bore to rigidly couple the support post to the sleeve. The other end of the post is formed with a ball portion. A hollow cylindrical collar has an inner threaded surface engageable with the outer threaded surface of the sleeve to rigidly couple the collar to the sleeve. the collar also has a socket portion which cooperates with the ball portion to flexibly connect segments together to form a ball and socket-type joint. In another embodiment, the segment comprises a support member which has a threaded shaft portion and a ball surface portion. The threaded shaft portion is engageable with an inner threaded surface of a ring for rigidly coupling the support member to the ring. The ring in turn has an outer surface at one end which is threadably engageably with a hollow cylindrical sleeve. The other end of the sleeve is formed with a socket portion for engagement with a ball portion of the support member. In yet another embodiment, a secondary rod is slidably inserted in a hollow channel through the center of the segment to provide additional strength. A method for controlling a nuclear reactor utilizing the control rod assembly is also included.

  9. Recent Developments in High Temperature Superconductivity 

    E-Print Network [OSTI]

    Hor, P. H.

    1988-01-01

    New material systems and the experimental progress of high temperature superconductivity are briefly reviewed. We examine both oxides and non-oxides which exhibit stable and/or unstable superconductivity at high temperatures....

  10. Agenda: High Temperature Membrane Working Group Meeting

    Broader source: Energy.gov [DOE]

    Agenda for the High Temperature Membrane Working Group (HTMWG) meeting on May 18, 2009, in Arlington, Virginia

  11. High Temperature Superconducting Underground Cable

    SciTech Connect (OSTI)

    Farrell, Roger, A.

    2010-02-28

    The purpose of this Project was to design, build, install and demonstrate the technical feasibility of an underground high temperature superconducting (HTS) power cable installed between two utility substations. In the first phase two HTS cables, 320 m and 30 m in length, were constructed using 1st generation BSCCO wire. The two 34.5 kV, 800 Arms, 48 MVA sections were connected together using a superconducting joint in an underground vault. In the second phase the 30 m BSCCO cable was replaced by one constructed with 2nd generation YBCO wire. 2nd generation wire is needed for commercialization because of inherent cost and performance benefits. Primary objectives of the Project were to build and operate an HTS cable system which demonstrates significant progress towards commercial progress and addresses real world utility concerns such as installation, maintenance, reliability and compatibility with the existing grid. Four key technical areas addressed were the HTS cable and terminations (where the cable connects to the grid), cryogenic refrigeration system, underground cable-to-cable joint (needed for replacement of cable sections) and cost-effective 2nd generation HTS wire. This was the world’s first installation and operation of an HTS cable underground, between two utility substations as well as the first to demonstrate a cable-to-cable joint, remote monitoring system and 2nd generation HTS.

  12. Which Chiral Symmetry is Restored in High Temperature QCD?

    E-Print Network [OSTI]

    Claude Bernard; Tom Blum; Carleton DeTar; Steven Gottlieb; Urs M. Heller; James E. Hetrick; K. Rummukainen; R. Sugar; D. Toussaint; Matthew Wingate

    1996-11-27

    Sigma models for the high temperature phase transition in quantum chromodynamics (QCD) suggest that at high temperature the SU(N_f) x SU(N_f) chiral symmetry becomes exact, but the anomalous axial U(1) symmetry need not be restored. In numerical lattice simulations, traditional methods for detecting symmetry restoration have sought multiplets in the screening mass spectrum. However, these methods were imprecise and the results, so far, incomplete. With improved statistics and methodology, we are now able to offer evidence for a restoration of the SU(2) x SU(2) chiral symmetry just above the crossover, but not of the axial U(1) chiral symmetry.

  13. Materials Characterization Capabilities at the High Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Laboratory and HTML User Program Success Stories Materials Characterization Capabilities at the High Temperature Materials Laboratory and HTML User Program Success Stories 2012 DOE...

  14. Materials Characterization Capabilities at the High Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    on Carbon Fiber and Composites Materials Characterization Capabilities at the High Temperature Materials Laboratory: Focus on Carbon Fiber and Composites 2011 DOE Hydrogen and Fuel...

  15. Materials Characterization Capabilities at the High Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    May 18-22, 2009 -- Washington D.C. lm01laracurzio.pdf More Documents & Publications Materials Characterization Capabilities at the High Temperature Materials Laboratory and HTML...

  16. Materials Characterization Capabilities at the High Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2010 -- Washington D.C. lm028laracurzio2010o.pdf More Documents & Publications Materials Characterization Capabilities at the High Temperature Materials Laboratory and HTML...

  17. Materials Characterization Capabilities at the High Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Review and Peer Evaluation lm028laracurzio2011o.pdf More Documents & Publications Materials Characterization Capabilities at the High Temperature Materials Laboratory and HTML...

  18. High-temperature brazed ceramic joints

    DOE Patents [OSTI]

    Jarvinen, Philip O. (Amherst, NH)

    1986-01-01

    High-temperature joints formed from metallized ceramics are disclosed wherein the metal coatings on the ceramics are vacuum sputtered thereon.

  19. Materials Characterization Capabilities at the High Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    at the High Temperature Materials Laboratory and HTML User Program Success Stories Low-Cost Magnesium Sheet Production using the Twin Roll Casting Process and Asymmetric Rolling...

  20. Quantitative Modeling of High Temperature Magnetization Dynamics

    SciTech Connect (OSTI)

    Zhang, Shufeng

    2009-03-01

    Final Technical Report Project title: Quantitative Modeling of High Temperature Magnetization Dynamics DOE/Office of Science Program Manager Contact: Dr. James Davenport

  1. BARNSTEAD|THERMOLYNE CORPORATION High Temperature

    E-Print Network [OSTI]

    Walker, D. Greg

    1 BARNSTEAD|THERMOLYNE CORPORATION High Temperature Muffle Furnace OPERATION MANUAL AND PARTS LIST ....................................................................................................................................................13 Furnace Connection: .........................................................................................................................13 General Operation of Furnace

  2. Photonic crystals for high temperature applications

    E-Print Network [OSTI]

    Yeng, Yi Xiang

    2014-01-01

    This thesis focuses on the design, optimization, fabrication, and experimental realization of metallic photonic crystals (MPhCs) for high temperature applications, for instance thermophotovoltaic (TPV) energy conversion ...

  3. Nanostructured High Temperature Bulk Thermoelectric Energy Conversion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    stage expected to show a 5% fuel efficiency improvement in vehicle platform under US06 drive cycle caylor.pdf More Documents & Publications Nanostructured High-Temperature Bulk...

  4. High Temperature Electrochemistry Center - HiTEC

    SciTech Connect (OSTI)

    McVay, G.; Williams, M.

    2005-01-27

    This presentation discusses the High Temperature Electrochemistry Center (HiTEC). The mission of HiTEC is to advance the solid oxide technology, such as solid oxide, high temperature electrolysers, reversible fuel cells, energy storage devices, proton conductors, etc., for use in DG and FutureGen applications, and to conduct fundamental research that aids the general development of all solid oxide technology.

  5. High temperature superconducting fault current limiter

    DOE Patents [OSTI]

    Hull, J.R.

    1997-02-04

    A fault current limiter for an electrical circuit is disclosed. The fault current limiter includes a high temperature superconductor in the electrical circuit. The high temperature superconductor is cooled below its critical temperature to maintain the superconducting electrical properties during operation as the fault current limiter. 15 figs.

  6. High temperature superconducting fault current limiter

    DOE Patents [OSTI]

    Hull, John R. (Hinsdale, IL)

    1997-01-01

    A fault current limiter (10) for an electrical circuit (14). The fault current limiter (10) includes a high temperature superconductor (12) in the electrical circuit (14). The high temperature superconductor (12) is cooled below its critical temperature to maintain the superconducting electrical properties during operation as the fault current limiter (10).

  7. Development of a 100-Watt High Temperature Thermoelectric Generator...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a 100-Watt High Temperature Thermoelectric Generator Development of a 100-Watt High Temperature Thermoelectric Generator Test results for low and high temperature thermoelectric...

  8. High-Temperature-High-Volume Lifting for Enhanced Geothermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Temperature-High-Volume Lifting for Enhanced Geothermal Systems High-Temperature-High-Volume Lifting for Enhanced Geothermal Systems High-Temperature-High-Volume Lifting for...

  9. High-temperature geochronology constraints on the tectonic history and architecture of the ultrahigh-pressure

    E-Print Network [OSTI]

    Hacker, Bradley R.

    High-temperature geochronology constraints on the tectonic history and architecture, but at present, there is no geochronological evidence in the Dabie- Sulu area to support this. The subduction (2006), High-temperature geochronology constraints on the tectonic history and architecture

  10. Nonlinear high-temperature superconducting terahertz metamaterials

    E-Print Network [OSTI]

    Grady, Nathaniel K.

    We report the observation of a nonlinear terahertz response of split-ring resonator arrays made of high-temperature superconducting films. Intensity-dependent transmission measurements indicate that the resonance strength ...

  11. Investigations into High Temperature Components and Packaging

    SciTech Connect (OSTI)

    Marlino, L.D.; Seiber, L.E.; Scudiere, M.B.; M.S. Chinthavali, M.S.; McCluskey, F.P.

    2007-12-31

    The purpose of this report is to document the work that was performed at the Oak Ridge National Laboratory (ORNL) in support of the development of high temperature power electronics and components with monies remaining from the Semikron High Temperature Inverter Project managed by the National Energy Technology Laboratory (NETL). High temperature electronic components are needed to allow inverters to operate in more extreme operating conditions as required in advanced traction drive applications. The trend to try to eliminate secondary cooling loops and utilize the internal combustion (IC) cooling system, which operates with approximately 105 C water/ethylene glycol coolant at the output of the radiator, is necessary to further reduce vehicle costs and weight. The activity documented in this report includes development and testing of high temperature components, activities in support of high temperature testing, an assessment of several component packaging methods, and how elevated operating temperatures would impact their reliability. This report is organized with testing of new high temperature capacitors in Section 2 and testing of new 150 C junction temperature trench insulated gate bipolar transistor (IGBTs) in Section 3. Section 4 addresses some operational OPAL-GT information, which was necessary for developing module level tests. Section 5 summarizes calibration of equipment needed for the high temperature testing. Section 6 details some additional work that was funded on silicon carbide (SiC) device testing for high temperature use, and Section 7 is the complete text of a report funded from this effort summarizing packaging methods and their reliability issues for use in high temperature power electronics. Components were tested to evaluate the performance characteristics of the component at different operating temperatures. The temperature of the component is determined by the ambient temperature (i.e., temperature surrounding the device) plus the temperature increase inside the device due the internal heat that is generated due to conduction and switching losses. Capacitors and high current switches that are reliable and meet performance specifications over an increased temperature range are necessary to realize electronics needed for hybrid-electric vehicles (HEVs), fuel cell (FC) and plug-in HEVs (PHEVs). In addition to individual component level testing, it is necessary to evaluate and perform long term module level testing to ascertain the effects of high temperature operation on power electronics.

  12. Nuclear fuels for very high temperature applications

    SciTech Connect (OSTI)

    Lundberg, L.B.; Hobbins, R.R.

    1992-08-01

    The success of the development of nuclear thermal propulsion devices and thermionic space nuclear power generation systems depends on the successful utilization of nuclear fuel materials at temperatures in the range 2000 to 3500 K. Problems associated with the utilization of uranium bearing fuel materials at these very high temperatures while maintaining them in the solid state for the required operating times are addressed. The critical issues addressed include evaporation, melting, reactor neutron spectrum, high temperature chemical stability, fabrication, fission induced swelling, fission product release, high temperature creep, thermal shock resistance, and fuel density, both mass and fissile atom. Candidate fuel materials for this temperature range are based on UO{sub 2} or uranium carbides. Evaporation suppression, such as a sealed cladding, is required for either fuel base. Nuclear performance data needed for design are sparse for all candidate fuel forms in this temperature range, especially at the higher temperatures.

  13. Nuclear fuels for very high temperature applications

    SciTech Connect (OSTI)

    Lundberg, L.B.; Hobbins, R.R.

    1992-01-01

    The success of the development of nuclear thermal propulsion devices and thermionic space nuclear power generation systems depends on the successful utilization of nuclear fuel materials at temperatures in the range 2000 to 3500 K. Problems associated with the utilization of uranium bearing fuel materials at these very high temperatures while maintaining them in the solid state for the required operating times are addressed. The critical issues addressed include evaporation, melting, reactor neutron spectrum, high temperature chemical stability, fabrication, fission induced swelling, fission product release, high temperature creep, thermal shock resistance, and fuel density, both mass and fissile atom. Candidate fuel materials for this temperature range are based on UO{sub 2} or uranium carbides. Evaporation suppression, such as a sealed cladding, is required for either fuel base. Nuclear performance data needed for design are sparse for all candidate fuel forms in this temperature range, especially at the higher temperatures.

  14. Application of High Temperature Superconductors to Accelerators

    E-Print Network [OSTI]

    Ballarino, A

    2000-01-01

    Since the discovery of high temperature superconductivity, a large effort has been made by the scientific community to investigate this field towards a possible application of the new oxide superconductors to different devices like SMES, magnetic bearings, flywheels energy storage, magnetic shielding, transmission cables, fault current limiters, etc. However, all present day large scale applications using superconductivity in accelerator technology are based on conventional materials operating at liquid helium temperatures. Poor mechanical properties, low critical current density and sensitivity to the magnetic field at high temperature are the key parameters whose improvement is essential for a large scale application of high temperature superconductors to such devices. Current leads, used for transferring currents from the power converters, working at room temperature, into the liquid helium environment, where the magnets are operating, represent an immediate application of the emerging technology of high t...

  15. Thermal disconnect for high-temperature batteries

    DOE Patents [OSTI]

    Jungst, Rudolph George (Albuquerque, NM); Armijo, James Rudolph (Albuquerque, NM); Frear, Darrel Richard (Austin, TX)

    2000-01-01

    A new type of high temperature thermal disconnect has been developed to protect electrical and mechanical equipment from damage caused by operation at extreme temperatures. These thermal disconnects allow continuous operation at temperatures ranging from 250.degree. C. to 450.degree. C., while rapidly terminating operation at temperatures 50.degree. C. to 150.degree. C. higher than the continuous operating temperature.

  16. Safety Issues for High Temperature Gas Reactors

    E-Print Network [OSTI]

    . · Behavior of fuel, fission product release behavior in reactor building and structures under accidentSafety Issues for High Temperature Gas Reactors Andrew C. Kadak Professor of the Practice #12;Major Consequences AOO AC SPC Challenges DESIGN BASIS * Severe challenge to the Fission Products Confinement Function

  17. High Temperature, Permanent Magnet Biased Magnetic Bearings 

    E-Print Network [OSTI]

    Gandhi, Varun R.

    2010-07-14

    performance, high speed and high temperature applications like space vehicles, jet engines and deep sea equipment. The bearing system had a target design to carry a load equal to 500 lb-f (2225N). Another objective was to design and build a test rig fixture...

  18. ELECTRONIC CERAMICS IN HIGH TEMPERATURE ENVIRONMENTS

    E-Print Network [OSTI]

    Searcy, A.W.

    2010-01-01

    o n on E l e c t r o n i c Ceramics i n Severe Environments,d i n t h e B u l l e t i n o f the American Ceramic S o c ie t y ELECTRONIC CERAMICS IN HIGH TEMPERATURE ENVIRONMENTS

  19. High temperature ceramic/metal joint structure

    DOE Patents [OSTI]

    Boyd, Gary L. (Tempe, AZ)

    1991-01-01

    A high temperature turbine engine includes a hybrid ceramic/metallic rotor member having ceramic/metal joint structure. The disclosed joint is able to endure higher temperatures than previously possible, and aids in controlling heat transfer in the rotor member.

  20. High Temperature Materials Interim Data Qualification Report

    SciTech Connect (OSTI)

    Nancy Lybeck

    2010-08-01

    ABSTRACT Projects for the very high temperature reactor (VHTR) Technology Development Office provide data in support of Nuclear Regulatory Commission licensing of the VHTR. Fuel and materials to be used in the reactor are tested and characterized to quantify performance in high temperature and high fluence environments. The VHTR program has established the NGNP Data Management and Analysis System (NDMAS) to ensure that VHTR data are qualified for use, stored in a readily accessible electronic form, and analyzed to extract useful results. This document focuses on the first NDMAS objective. It describes the High Temperature Materials characterization data stream, the processing of these data within NDMAS, and reports the interim FY2010 qualification status of the data. Data qualification activities within NDMAS for specific types of data are determined by the data qualification category assigned by the data generator. The High Temperature Materials data are being collected under NQA-1 guidelines, and will be qualified data. For NQA-1 qualified data, the qualification activities include: (1) capture testing, to confirm that the data stored within NDMAS are identical to the raw data supplied, (2) accuracy testing to confirm that the data are an accurate representation of the system or object being measured, and (3) documenting that the data were collected under an NQA-1 or equivalent Quality Assurance program. Currently, data from two test series within the High Temperature Materials data stream have been entered into the NDMAS vault: 1. Tensile Tests for Sm (i.e., Allowable Stress) Confirmatory Testing – 1,403,994 records have been inserted into the NDMAS database. Capture testing is in process. 2. Creep-Fatigue Testing to Support Determination of Creep-Fatigue Interaction Diagram – 918,854 records have been processed and inserted into the NDMAS database. Capture testing is in process.

  1. Project Profile: Fundamental Corrosion Studies in High-Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fundamental Corrosion Studies in High-Temperature Molten Salt Systems for Next-Generation CSP Systems Project Profile: Fundamental Corrosion Studies in High-Temperature Molten Salt...

  2. High Temperature Fuel Cells in the European Union

    Broader source: Energy.gov [DOE]

    Presentation on High Temperature Fuel Cells in the European Union to the High Temperature Membrane Working Group, May 25, 2004 in Philadelphia, PA.

  3. Institute of Chemical Engineering and High Temperature Chemical...

    Open Energy Info (EERE)

    Institute of Chemical Engineering and High Temperature Chemical Processes ICEHT Jump to: navigation, search Name: Institute of Chemical Engineering and High Temperature Chemical...

  4. A High Temperature Direct Vehicle Exhaust Flowmeter for Heavy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A High Temperature Direct Vehicle Exhaust Flowmeter for Heavy Duty Diesel Emission Measurements. A High Temperature Direct Vehicle Exhaust Flowmeter for Heavy Duty Diesel Emission...

  5. High Temperature Thermal Array for Next Generation Solar Thermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Temperature Thermal Array for Next Generation Solar Thermal Power Production High Temperature Thermal Array for Next Generation Solar Thermal Power Production This...

  6. Development of Advanced High Temperature Fuel Cell Membranes

    Broader source: Energy.gov [DOE]

    Presentation on Development of Advanced High Temperature Fuel Cell Membranes to the High Temperature Membrane Working Group Meeting held in Arlington, Virginia, May 26,2005.

  7. Low Cost, High Temperature, High Ripple Current DC Bus Capacitors...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Cost, High Temperature, High Ripple Current DC Bus Capacitors Low Cost, High Temperature, High Ripple Current DC Bus Capacitors 2010 DOE Vehicle Technologies and Hydrogen...

  8. Development of a 500 Watt High Temperature Thermoelectric Generator...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a 500 Watt High Temperature Thermoelectric Generator Development of a 500 Watt High Temperature Thermoelectric Generator A low temperature TEG has been built and tested providing...

  9. Materials and Process Design for High-Temperature Carburizing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials and Process Design for High-Temperature Carburizing Materials and Process Design for High-Temperature Carburizing New Class of High-Performance Carburized Steels Saves...

  10. Nanostructured High-Temperature Bulk Thermoelectric Energy Conversion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Temperature Bulk Thermoelectric Energy Conversion for Efficient Automotive Waste Heat Recovery Nanostructured High-Temperature Bulk Thermoelectric Energy Conversion for...

  11. Low and high Temperature Dual Thermoelectric Generation Waste...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and high Temperature Dual Thermoelectric Generation Waste Heat Recovery System for Light-Duty Vehicles Low and high Temperature Dual Thermoelectric Generation Waste Heat Recovery...

  12. High Temperature Polymer Membrane Development at Argonne National Laboratory

    Broader source: Energy.gov [DOE]

    Summary of ANL’s high temperature polymer membrane work presented to the High Temperature Membrane Working Group Meeting, Orlando FL, October 17, 2003

  13. Thermal fuse for high-temperature batteries

    DOE Patents [OSTI]

    Jungst, Rudolph G. (Albuquerque, NM); Armijo, James R. (Albuquerque, NM); Frear, Darrel R. (Austin, TX)

    2000-01-01

    A thermal fuse, preferably for a high-temperature battery, comprising leads and a body therebetween having a melting point between approximately 400.degree. C. and 500.degree. C. The body is preferably an alloy of Ag--Mg, Ag--Sb, Al--Ge, Au--In, Bi--Te, Cd--Sb, Cu--Mg, In--Sb, Mg--Pb, Pb--Pd, Sb--Zn, Sn--Te, or Mg--Al.

  14. High Temperature Materials for Aerospace Applications 

    E-Print Network [OSTI]

    Adamczak, Andrea Diane

    2011-08-08

    ), bismaleimide (b), cyanate ester (c), and imide (d). ....................................................................................... 11 2.4 Use temperatures for common resin matrix composite materials. ............. 12 2.5 PMR-15 chemistry... properties.1-2 Additionally, fiber-reinforced high temperature polymer matrix composites are particularly attractive for aerospace structures because of their low density,2-3 high mechanical strength,2,4-10 high modulus,2,5,7-9 thermo-oxidative stability...

  15. Electronic Applications of High Temperature Superconductors 

    E-Print Network [OSTI]

    Kroger, H.; Miracky, R. F.

    1988-01-01

    of the high temperature superconductors in advanced radar systems. The low loss microwave properties of superconductors have already been exploited by Lincoln Laboratory in demonstrating signal processing systems whose capabilities greatly exceed any... from estimates of its surface im pedance for naturally occurring low-frequency electromagnetic waves. Low-frequen y (10. 3 to let Hz) fluctuations in the earth's magnetic field induce eddy currents at its surface; the size of the induced voltage...

  16. Ultra High Temperature | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-EnhancingEt Al.,Turin, New York: EnergyU.S. EPAEnergyUltra High Temperature Jump to:

  17. Sandia Energy - High-Temperature Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation of Fe(II)Geothermal Energy & Drilling TechnologyHeavyHigh-Temperature Materials

  18. High temperature lined conduits, elbows and tees

    DOE Patents [OSTI]

    De Feo, Angelo (Passaic, NJ); Drewniany, Edward (Bergen, NJ)

    1982-01-01

    A high temperature lined conduit comprising, a liner, a flexible insulating refractory blanket around and in contact with the liner, a pipe member around the blanket and spaced therefrom, and castable rigid refractory material between the pipe member and the blanket. Anchors are connected to the inside diameter of the pipe and extend into the castable material. The liner includes male and female slip joint ends for permitting thermal expansion of the liner with respect to the castable material and the pipe member. Elbows and tees of the lined conduit comprise an elbow liner wrapped with insulating refractory blanket material around which is disposed a spaced elbow pipe member with castable refractory material between the blanket material and the elbow pipe member. A reinforcing band is connected to the elbow liner at an intermediate location thereon from which extend a plurality of hollow tubes or pins which extend into the castable material to anchor the lined elbow and permit thermal expansion. A method of fabricating the high temperature lined conduit, elbows and tees is also disclosed which utilizes a polyethylene layer over the refractory blanket after it has been compressed to maintain the refractory blanket in a compressed condition until the castable material is in place. Hot gases are then directed through the interior of the liner for evaporating the polyethylene and setting the castable material which permits the compressed blanket to come into close contact with the castable material.

  19. Conformal Properties in High Temperature QCD

    E-Print Network [OSTI]

    Ishikawa, K -I; Nakayama, Yu; Yoshie, T

    2015-01-01

    We investigate the properties of quarks and gluons above the chiral phase transition temperature $T_c,$ using the RG improved gauge action and the Wilson quark action with two degenerate quarks mainly on a $32^3\\times 16$ lattice. In the one-loop perturbation theory, the thermal ensemble is dominated by the gauge configurations with effectively $Z(3)$ center twisted boundary conditions, making the thermal expectation value of the spatial Polyakov loop take a non-trivial $Z(3)$ center. This is in agreement with our lattice simulation of high temperature QCD. We further observe that the temporal propagator of massless quarks at extremely high temperature $\\beta=100.0 \\, (T \\simeq10^{58} T_c)$ remarkably agrees with the temporal propagator of free quarks with the $Z(3)$ twisted boundary condition for $t/L_t \\geq 0.2$, but differs from that with the $Z(3)$ trivial boundary condition. As we increase the mass of quarks $m_q$, we find that the thermal ensemble continues to be dominated by the $Z(3)$ twisted gauge fi...

  20. Compliant high temperature seals for dissimilar materials

    DOE Patents [OSTI]

    Rynders, Steven Walton (Fogelsville, PA); Minford, Eric (Laurys Station, PA); Tressler, Richard Ernest (Boalsburg, PA); Taylor, Dale M. (Salt Lake City, UT)

    2001-01-01

    A high temperature, gas-tight seal is formed by utilizing one or more compliant metallic toroidal ring sealing elements, where the applied pressure serves to activate the seal, thus improving the quality of the seal. The compliant nature of the sealing element compensates for differences in thermal expansion between the materials to be sealed, and is particularly useful in sealing a metallic member and a ceramic tube art elevated temperatures. The performance of the seal may be improved by coating the sealing element with a soft or flowable coating such as silver or gold and/or by backing the sealing element with a bed of fine powder. The material of the sealing element is chosen such that the element responds to stress elastically, even at elevated temperatures, permitting the seal to operate through multiple thermal cycles.

  1. Multilayer ultra-high-temperature ceramic coatings

    DOE Patents [OSTI]

    Loehman, Ronald E. (Albuquerque, NM); Corral, Erica L. (Tucson, AZ)

    2012-03-20

    A coated carbon-carbon composite material with multiple ceramic layers to provide oxidation protection from ultra-high-temperatures, where if the carbon-carbon composite material is uninhibited with B.sub.4C particles, then the first layer on the composite material is selected from ZrB.sub.2 and HfB.sub.2, onto which is coated a layer of SiC coated and if the carbon-carbon composite material is inhibited with B.sub.4C particles, then protection can be achieved with a layer of SiC and a layer of either ZrB.sub.2 and HfB.sub.2 in any order.

  2. High temperature coatings for gas turbines

    DOE Patents [OSTI]

    Zheng, Xiaoci Maggie

    2003-10-21

    Coating for high temperature gas turbine components that include a MCrAlX phase, and an aluminum-rich phase, significantly increase oxidation and cracking resistance of the components, thereby increasing their useful life and reducing operating costs. The aluminum-rich phase includes aluminum at a higher concentration than aluminum concentration in the MCrAlX alloy, and an aluminum diffusion-retarding composition, which may include cobalt, nickel, yttrium, zirconium, niobium, molybdenum, rhodium, cadmium, indium, cerium, iron, chromium, tantalum, silicon, boron, carbon, titanium, tungsten, rhenium, platinum, and combinations thereof, and particularly nickel and/or rhenium. The aluminum-rich phase may be derived from a particulate aluminum composite that has a core comprising aluminum and a shell comprising the aluminum diffusion-retarding composition.

  3. Turbine vane with high temperature capable skins

    DOE Patents [OSTI]

    Morrison, Jay A. (Oviedo, FL)

    2012-07-10

    A turbine vane assembly includes an airfoil extending between an inner shroud and an outer shroud. The airfoil can include a substructure having an outer peripheral surface. At least a portion of the outer peripheral surface is covered by an external skin. The external skin can be made of a high temperature capable material, such as oxide dispersion strengthened alloys, intermetallic alloys, ceramic matrix composites or refractory alloys. The external skin can be formed, and the airfoil can be subsequently bi-cast around or onto the skin. The skin and the substructure can be attached by a plurality of attachment members extending between the skin and the substructure. The skin can be spaced from the outer peripheral surface of the substructure such that a cavity is formed therebetween. Coolant can be supplied to the cavity. Skins can also be applied to the gas path faces of the inner and outer shrouds.

  4. High pressure and high temperature apparatus

    DOE Patents [OSTI]

    Voronov, Oleg A.

    2005-09-13

    A design for high pressure/high temperature apparatus and reaction cell to achieve .about.30 GPa pressure in .about.1 cm volume and .about.100 GPa pressure in .about.1 mm volumes and 20-5000.degree. C. temperatures in a static regime. The device includes profiled anvils (28) action on a reaction cell (14, 16) containing the material (26) to be processed. The reaction cell includes a heater (18) surrounded by insulating layers and screens. Surrounding the anvils are cylindrical inserts and supporting rings (30-48) whose hardness increases towards the reaction cell. These volumes may be increased considerably if applications require it, making use of presses that have larger loading force capability, larger frames and using larger anvils.

  5. High temperature insulation for ceramic matrix composites

    DOE Patents [OSTI]

    Merrill, Gary B. (Monroeville, PA); Morrison, Jay Alan (Orlando, FL)

    2001-01-01

    A ceramic composition is provided to insulate ceramic matrix composites under high temperature, high heat flux environments. The composition comprises a plurality of hollow oxide-based spheres of various dimensions, a phosphate binder, and at least one oxide filler powder, whereby the phosphate binder partially fills gaps between the spheres and the filler powders. The spheres are situated in the phosphate binder and the filler powders such that each sphere is in contact with at least one other sphere. The spheres may be any combination of Mullite spheres, Alumina spheres, or stabilized Zirconia spheres. The filler powder may be any combination of Alumina, Mullite, Ceria, or Hafnia. Preferably, the phosphate binder is Aluminum Ortho-Phosphate. A method of manufacturing the ceramic insulating composition and its application to CMC substrates are also provided.

  6. High temperature insulation for ceramic matrix composites

    DOE Patents [OSTI]

    Merrill, Gary B.; Morrison, Jay Alan

    2004-01-13

    A ceramic composition is provided to insulate ceramic matrix composites under high temperature, high heat flux environments. The composition comprises a plurality of hollow oxide-based spheres of various dimensions, a phosphate binder, and at least one oxide filler powder, whereby the phosphate binder partially fills gaps between the spheres and the filler powders. The spheres are situated in the phosphate binder and the filler powders such that each sphere is in contact with at least one other sphere. The spheres may be any combination of Mullite spheres, Alumina spheres, or stabilized Zirconia spheres. The filler powder may be any combination of Alumina, Mullite, Ceria, or Hafnia. Preferably, the phosphate binder is Aluminum Ortho-Phosphate. A method of manufacturing the ceramic insulating composition and its application to CMC substrates are also provided.

  7. High temperature insulation for ceramic matrix composites

    DOE Patents [OSTI]

    Merrill, Gary B. (Monroeville, PA); Morrison, Jay Alan (Orlando, FL)

    2000-01-01

    A ceramic composition is provided to insulate ceramic matrix composites under high temperature, high heat flux environments. The composite comprises a plurality of hollow oxide-based spheres of varios dimentions, a phosphate binder, and at least one oxide filler powder, whereby the phosphate binder partially fills gaps between the spheres and the filler powders. The spheres are situated in the phosphate binder and the filler powders such that each sphere is in contact with at least one other sphere. The spheres may be any combination of Mullite spheres, Alumina spheres, or stabilized Zirconia spheres. The filler powder may be any combination of Alumina, Mullite, Ceria, or Hafnia. Preferably, the phosphate binder is Aluminum Ortho-Phosphate. A method of manufacturing the ceramic insulating composition and its application to CMC substates are also provided.

  8. Heterogeneous metasurface for high temperature selective emission

    SciTech Connect (OSTI)

    Woolf, D., E-mail: dwoolf@psicorp.com; Hensley, J. [Physical Sciences, Inc., 20 New England Business Center, Andover, Massachusetts 01810 (United States); Cederberg, J. G.; Bethke, D. T.; Grine, A. D.; Shaner, E. A. [Sandia National Laboratories, P.O. Box 5800, Albuquerque, New Mexico 87185 (United States)

    2014-08-25

    We demonstrate selective emission from a heterogeneous metasurface that can survive repeated temperature cycling at 1300?K. Simulations, fabrication, and characterization were performed for a cross-over-a-backplane metasurface consisting of platinum and alumina layers on a sapphire substrate. The structure was stabilized for high temperature operation by an encapsulating alumina layer. The geometry was optimized for integration into a thermophotovoltaic (TPV) system, and was designed to have its emissivity matched to the external quantum efficiency spectrum of 0.6?eV InGaAs TPV material. We present spectral measurements of the metasurface that result in a predicted 22% optical-to-electrical power conversion efficiency in a simplified model at 1300?K. Furthermore, this broadly adaptable selective emitter design can be easily integrated into full-scale TPV systems.

  9. Acidizing of Sandstone Reservoirs Using HF and Organic Acids 

    E-Print Network [OSTI]

    Yang, Fei

    2012-10-19

    Mud acid, which is composed of HCl and HF, is commonly used to remove the formation damage in sandstone reservoirs. However, many problems are associated with HCl, especially at high temperatures. Formic-HF acids have served as an alternative...

  10. Development of a 100-Watt High Temperature Thermoelectric Generator

    Broader source: Energy.gov [DOE]

    Test results for low and high temperature thermoelectric generators (TEG) those for a 530-watt BiTe TEG; design and construction of a 100-watt high temperature TEG currently in fabrication.

  11. Development of a High-Temperature Diagnostics-While-Drilling...

    Office of Environmental Management (EM)

    Development of a High-Temperature Diagnostics-While-Drilling Tool Development of a High-Temperature Diagnostics-While-Drilling Tool This report documents work performed in the...

  12. Agenda for the High Temperature Membrane Working Group Meeting

    Broader source: Energy.gov [DOE]

    This agenda provides information about the Agenda for the High Temperature Membrane Working Group Meeting on September 14, 2006.

  13. High Temperature Membrane Working Group Meeting, May 14, 2007

    Broader source: Energy.gov [DOE]

    This agenda provides information about the High Temperature Membrane Working Group Meeting on May 14, 2007 in Arlington, Va.

  14. High Temperature Integrated Thermoelectric Ststem and Materials

    SciTech Connect (OSTI)

    Mike S. H. Chu

    2011-06-06

    The final goal of this project is to produce, by the end of Phase II, an all ceramic high temperature thermoelectric module. Such a module design integrates oxide ceramic n-type, oxide ceramic p-type materials as thermoelectric legs and oxide ceramic conductive material as metalizing connection between n-type and p-type legs. The benefits of this all ceramic module are that it can function at higher temperatures (> 700 C), it is mechanically and functionally more reliable and it can be scaled up to production at lower cost. With this all ceramic module, millions of dollars in savings or in new opportunities recovering waste heat from high temperature processes could be made available. A very attractive application will be to convert exhaust heat from a vehicle to reusable electric energy by a thermoelectric generator (TEG). Phase I activities were focused on evaluating potential n-type and p-type oxide compositions as the thermoelectric legs. More than 40 oxide ceramic powder compositions were made and studied in the laboratory. The compositions were divided into 6 groups representing different material systems. Basic ceramic properties and thermoelectric properties of discs sintered from these powders were measured. Powders with different particles sizes were made to evaluate the effects of particle size reduction on thermoelectric properties. Several powders were submitted to a leading thermoelectric company for complete thermoelectric evaluation. Initial evaluation showed that when samples were sintered by conventional method, they had reasonable values of Seebeck coefficient but very low values of electrical conductivity. Therefore, their power factors (PF) and figure of merits (ZT) were too low to be useful for high temperature thermoelectric applications. An unconventional sintering method, Spark Plasma Sintering (SPS) was determined to produce better thermoelectric properties. Particle size reduction of powders also was found to have some positive benefits. Two composition systems, specifically 1.0 SrO - 0.8 x 1.03 TiO2 - 0.2 x 1.03 NbO2.5 and 0.97 TiO2 - 0.03 NbO2.5, have been identified as good base line compositions for n-type thermoelectric compositions in future module design. Tests of these materials at an outside company were promising using that company's processing and material expertise. There was no unique p-type thermoelectric compositions identified in phase I work other than several current cobaltite materials. Ca3Co4O9 will be the primary p-type material for the future module design until alternative materials are developed. BaTiO3 and rare earth titanate based dielectric compositions show both p-type and n-type behavior even though their electrical conductivities were very low. Further research and development of these materials for thermoelectric applications is planned in the future. A preliminary modeling and optimization of a thermoelectric generator (TEG) that uses the n-type 1.0 SrO - 1.03 x 0.8 TiO2 - 1.03 x 0.2 NbO2.5 was performed. Future work will combine development of ceramic powders and manufacturing expertise at TAM, development of SPS at TAM or a partner organization, and thermoelectric material/module testing, modeling, optimization, production at several partner organizations.

  15. Secondary calcium solid electrolyte high temperature battery

    SciTech Connect (OSTI)

    Sammells, A.F.; Schumacher, B.

    1986-01-01

    The authors report on recent work directed towards determining the viability of polycrystalline Ca/sup 2 +/ conducting ..beta..''-alumina solid electrolytes as the basis for a new type of high temperature battery. In this battery system the negative electrode consisted of a calcium-silicon alloy whose redox electro-chemistry was mediated to the calcium conducting solid electrolyte via the use of the molten salt eutectic CaCl/sub 2/ (51.4/sup M//0), CaI/sub 2/ (mp 550/sup 0/C). Both the molten salt and the calcium-alloy negative active material were separated from the positive active material via the Ca/sup 2 +/ conducting polycrystalline solid electrolyte. The positive electrode consisted of a solid-state matrix having a somewhat related crystallographic structure to Ca/sup 2 +/ ..beta..''-alumina, but where a significant fraction of the A1/sup 3 +/ sites located within this solid electrolyte's spinel block were replaced by immobile transition metal species. These species were available for participating in solid-state redox electrochemistry upon electrochemical cell cycling.

  16. High temperature behavior of zirconium germanates

    SciTech Connect (OSTI)

    Utkin, A.V., E-mail: utkinalex@hotmail.com [Institute of Solid State Chemistry and Mechanochemistry SB RAS, 18 Kutateladze st., Novosibirsk 630128 (Russian Federation); Baklanova, N.I. [Institute of Solid State Chemistry and Mechanochemistry SB RAS, 18 Kutateladze st., Novosibirsk 630128 (Russian Federation); Vasilyeva, I.G. [Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Acad. Lavrentiev ave, Novosibirsk 630090 (Russian Federation)

    2013-05-01

    The high temperature behavior of zirconium germanates ZrGeO? and Zr?GeO? up to 2300 °C has been studied using the original photoemission thermal analysis technique with the comprehensive physicochemical study of solid and gaseous intermediate and final products. The two-stage process of incongruent sublimation of GeO? was established and the phase boundary of the homogeneity range for ZrGeO? and Zr?GeO? were deduced from the thermal analysis, X-ray diffraction and Raman spectroscopy studies. A high tendency to sintering of the final ZrO? product is discussed. - Graphical abstract: The decomposition of zirconium germanates leads to the formation of gaseous GeO? and solid sintered ZrO? and occurs via two stages with the formation of intermediate ZrO?-rich solid solution. Highlights: •Thermal behavior of ZrGeO? and Zr?GeO? was studied using the original thermal analysis technique in wide temperature range. •The decomposition occurs via two stages with the formation of intermediate ZrO?-rich solid solution. •The decomposition of zirconium germanates leads to the formation of gaseous GeO? and solid sintered ZrO?. •The temperature of decomposition is strongly depended on the total gas pressure.

  17. High Temperature Interactions of Antimony with Nickel

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.

    2012-07-01

    In this chapter, the surface and bulk interactions of antimony with the Ni-based anodes in solid oxide fuel cells (SOFC) will be discussed. High fuel flexibility is a significant advantage of SOFCs, allowing the direct use of fossil and bio fuels without a hydrogen separation unit. Synthesis gas derived from coal and biomass consists of a mixture of hydrogen, carbon monoxide, carbon dioxide, and steam, but finite amounts of tars and trace impurities such as S, Se, P, As, Sb, Cd, Pb, Cl, etc, are also always present. While synthesis gas is commonly treated with a series of chemical processes and scrubbers to remove the impurities, complete purification is not economical. Antimony is widely distributed in coals. During coal gasification antimony is volatilized, such that contact with the SOFC anodes and other SOFC parts, e.g., interconnect, current collecting wires, fuel gas supplying tubing, is most likely. This chapter addresses the following topics: high temperature Ni - Sb interactions; alteration phase, Ni3Sb, Ni5Sb2, NiSb, formation; thermochemical modeling; impact of Sb on the electrocatalytic activity of Ni toward the fuel oxidation and the presence of other impurities (sulfur, in particular); converted anode structural instability during long-term SOFC operation; comparison with nickel heterogeneous catalysts.

  18. Austenitic stainless steel for high temperature applications

    DOE Patents [OSTI]

    Johnson, Gerald D. (Kennewick, WA); Powell, Roger W. (Pasco, WA)

    1985-01-01

    This invention describes a composition for an austenitic stainless steel which has been found to exhibit improved high temperature stress rupture properties. The composition of this alloy is about (in wt. %): 12.5 to 14.5 Cr; 14.5 to 16.5 Ni; 1.5 to 2.5 Mo; 1.5 to 2.5 Mn; 0.1 to 0.4 Ti; 0.02 to 0.08 C; 0.5 to 1.0 Si; 0.01 maximum, N; 0.02 to 0.08 P; 0.002 to 0.008 B; 0.004-0.010 S; 0.02-0.05 Nb; 0.01-0.05 V; 0.005-0.02 Ta; 0.02-0.05 Al; 0.01-0.04 Cu; 0.02-0.05 Co; 0.03 maximum, As; 0.01 maximum, O; 0.01 maximum, Zr; and with the balance of the alloy being essentially iron. The carbon content of the alloy is adjusted such that wt. % Ti/(wt. % C+wt. % N) is between 4 and 6, and most preferably about 5. In addition the sum of the wt. % P+wt. % B+wt. % S is at least 0.03 wt. %. This alloy is believed to be particularly well suited for use as fast breeder reactor fuel element cladding.

  19. Refractory thermowell for continuous high temperature measurement of molten metal

    DOE Patents [OSTI]

    Thiesen, Todd J. (Idaho Falls, ID)

    1992-01-01

    An apparatus for the continuous high temperature measurement of materials in vessels lined with rammed or cast refractory materials. A refractory housing member is integral with the refractory lining of the vessel and contains a plurality of high temperature sensing means, such as thermocouples. A face of the housing is flush with the refractory lining and contacts the high temperature material contained in the vessel. Continuous temperature measurement is achieved by a means which is coupled to the thermocouples for indicating the temperature.

  20. Carbon Capture Turned Upside Down: High-Temperature Adsorption...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon Capture Turned Upside Down: High-Temperature Adsorption & Low-Temperature Desorption (HALD) Previous Next List Joos, Lennart; Lejaeghere, Kurt; Huck, Johanna M.; Van...

  1. Detecting Fractures Using Technology at High Temperatures and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Detecting Fractures Using Technology at High Temperatures and Depths - Geothermal Ultrasonic Fracture Imager (GUFI); 2010 Geothermal Technology Program Peer Review Report Detecting...

  2. A potential Rosetta Stone of high temperature superconductivity...

    Office of Science (SC) Website

    for the high temperature superconductivity. Summary Superconductivity enables the flow of electricity without any loss of energy, but this extremely-low temperature...

  3. High-Temperature, Air-Cooled Traction Drive Inverter Packaging...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Temperature, Air-Cooled Traction Drive Inverter Packaging High-Temperature, Air-Cooled Traction Drive Inverter Packaging 2010 DOE Vehicle Technologies and Hydrogen Programs Annual...

  4. Enhanced High Temperature Performance of NOx Storage/Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program Annual Merit Review and Peer Evaluation ace026peden2011o.pdf More Documents & Publications Enhanced High Temperature Performance of NOx StorageReduction (NSR) Materials...

  5. Enhanced High Temperature Performance of NOx Storage/Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CLEERS Aftertreatment Modeling and Analysis Enhanced High Temperature Performance of NOx StorageReduction (NSR) Materials Enhanced High and Low Temperature Performance of NOx...

  6. Novel Refractory Materials for High-Temperature, High-Alkaline...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications Can be used in high-temperature, high-alkaline furnaces and process vessels found in aluminum, chemical, forest products, glass, and steel industries....

  7. Microchannel High-Temperature Recuperator for Fuel Cell Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    heat recuperator for a high-temperature fuel cell system. This technology increases the efficiency of fuel cells and improves their performance in distributed energy...

  8. High Temperature Thin Film Polymer Dielectric Based Capacitors...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Temperature Thin Film Polymer Dielectric Based Capacitors for HEV Power Electronic Systems High Temperature Thin Film Polymer Dielectric Based Capacitors for HEV Power Electronic...

  9. Aerogel-Based Insulation for High-Temperature Industrial Processes...

    Office of Scientific and Technical Information (OSTI)

    Aerogel-Based Insulation for High-Temperature Industrial Processes Dr. Owen Evans 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; COMPETITION; ENERGY CONSUMPTION; MARKET;...

  10. Microchannel High-Temperature Recuperator for Fuel Cell Systems

    SciTech Connect (OSTI)

    2010-02-01

    This factsheet describes a research project whose goal is to build an efficient, microchannel-based waste heat recuperator for a high-temperature fuel cell system.

  11. Microchannel High-Temperature Recuperator for Fuel Cell Systems...

    Broader source: Energy.gov (indexed) [DOE]

    developed an efficient, microchannel-based waste heat recuperator for a high-temperature fuel cell system. This technology increases the efficiency of fuel cells and improves...

  12. Feasibility and Design Studies for a High Temperature Downhole Tool

    Office of Energy Efficiency and Renewable Energy (EERE)

    Project objective: Perform feasibility and design studies for a high temperature downhole tool; which uses nuclear techniques for characterization purposes; using measurements and modeling/simulation.

  13. High Temperature BOP and Fuel Processing | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    11-12, 2011. High Temperature BOP and Fuel Processing More Documents & Publications Biogas Impurities and Cleanup for Fuel Cells Fuel Quality Issues in Stationary Fuel Cell...

  14. Project Profile: High-Temperature Solar Selective Coating Development...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solar Selective Coating Development for Power Tower Receivers Project Profile: High-Temperature Solar Selective Coating Development for Power Tower Receivers Sandia National...

  15. Exploration Guides For Active High-Temperature Geothermal Systems...

    Open Energy Info (EERE)

    V. Bouchot,A. Genter. 2009. Exploration Guides For Active High-Temperature Geothermal Systems As Modern Analogs For Epithermal Paleosystems. In: () ; () ; () . () : GRC; p....

  16. High Temperature Materials Overview Richard Wright Idaho National...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    final action Fossil Energy Ultra- supercritical Materials research in US and Europe Partners in Generation IV International Forum ASME High Temperature Materials Code...

  17. Scaling Studies for High Temperature Test Facility and Modular High Temperature Gas-Cooled Reactor

    SciTech Connect (OSTI)

    Richard R. Schult; Paul D. Bayless; Richard W. Johnson; James R. Wolf; Brian Woods

    2012-02-01

    The Oregon State University (OSU) High Temperature Test Facility (HTTF) is an integral experimental facility that will be constructed on the OSU campus in Corvallis, Oregon. The HTTF project was initiated, by the U.S. Nuclear Regulatory Commission (NRC), on September 5, 2008 as Task 4 of the 5-year High Temperature Gas Reactor Cooperative Agreement via NRC Contract 04-08-138. Until August, 2010, when a DOE contract was initiated to fund additional capabilities for the HTTF project, all of the funding support for the HTTF was provided by the NRC via their cooperative agreement. The U.S. Department of Energy (DOE) began their involvement with the HTTF project in late 2009 via the Next Generation Nuclear Plant (NGNP) project. Because the NRC's interests in HTTF experiments were only centered on the depressurized conduction cooldown (DCC) scenario, NGNP involvement focused on expanding the experimental envelope of the HTTF to include steady-state operations and also the pressurized conduction cooldown (PCC).

  18. High Temperature Evaluation of Tantalum Capacitors - Test 1

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Cieslewski, Grzegorz

    2014-09-28

    Tantalum capacitors can provide much higher capacitance at high-temperatures than the ceramic capacitors. This study evaluates selected tantalum capacitors at high temperatures to determine their suitability for you in geothermal field. This data set contains results of the first test where three different types of capacitors were evaluated at 260C.

  19. Calcite Mineral Scaling Potentials of High-Temperature Geothermal Wells

    E-Print Network [OSTI]

    Karlsson, Brynjar

    #12;i Calcite Mineral Scaling Potentials of High-Temperature Geothermal Wells Alvin I. Remoroza-Temperature Geothermal Wells Alvin I. Remoroza 60 ECTS thesis submitted in partial fulfillment of a Magister Scientiarum #12;iv Calcite Mineral Scaling Potentials of High-Temperature Geothermal Wells 60 ECTS thesis

  20. High Temperature Evaluation of Tantalum Capacitors - Test 1

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Cieslewski, Grzegorz

    Tantalum capacitors can provide much higher capacitance at high-temperatures than the ceramic capacitors. This study evaluates selected tantalum capacitors at high temperatures to determine their suitability for you in geothermal field. This data set contains results of the first test where three different types of capacitors were evaluated at 260C.

  1. Calculated Phonon Spectra of Plutonium at High Temperatures

    E-Print Network [OSTI]

    Savrasov, Sergej Y.

    Calculated Phonon Spectra of Plutonium at High Temperatures X. Dai,1 S. Y. Savrasov,2 * G. Kotliar dynamical proper- ties of plutonium using an electronic structure method, which incorporates correlation anharmonic and can be stabilized at high temperatures by its phonon entropy. Plutonium (Pu) is a material

  2. To Crack or Not to Crack: Strain in High Temperature Superconductors

    E-Print Network [OSTI]

    Godeke, Arno

    2008-01-01

    in High Temperature Superconductors Arno Godeke August 22,in High Temperature Superconductors Motivation Magneticin High Temperature Superconductors How do Nb 3 Sn magnets

  3. DEGRADATION ISSUES IN SOLID OXIDE CELLS DURING HIGH TEMPERATURE ELECTROLYSIS

    SciTech Connect (OSTI)

    M. S. Sohal; J. E. O'Brien; C. M. Stoots; V. I. Sharma; B. Yildiz; A. Virkar

    2012-02-01

    Idaho National Laboratory (INL) is performing high-temperature electrolysis research to generate hydrogen using solid oxide electrolysis cells (SOECs). The project goals are to address the technical and degradation issues associated with the SOECs. This paper provides a summary of various ongoing INL and INL sponsored activities aimed at addressing SOEC degradation. These activities include stack testing, post-test examination, degradation modeling, and a list of issues that need to be addressed in future. Major degradation issues relating to solid oxide fuel cells (SOFC) are relatively better understood than those for SOECs. Some of the degradation mechanisms in SOFCs include contact problems between adjacent cell components, microstructural deterioration (coarsening) of the porous electrodes, and blocking of the reaction sites within the electrodes. Contact problems include delamination of an electrode from the electrolyte, growth of a poorly (electronically) conducting oxide layer between the metallic interconnect plates and the electrodes, and lack of contact between the interconnect and the electrode. INL's test results on high temperature electrolysis (HTE) using solid oxide cells do not provide a clear evidence whether different events lead to similar or drastically different electrochemical degradation mechanisms. Post-test examination of the solid oxide electrolysis cells showed that the hydrogen electrode and interconnect get partially oxidized and become non-conductive. This is most likely caused by the hydrogen stream composition and flow rate during cool down. The oxygen electrode side of the stacks seemed to be responsible for the observed degradation due to large areas of electrode delamination. Based on the oxygen electrode appearance, the degradation of these stacks was largely controlled by the oxygen electrode delamination rate. University of Utah (Virkar) has developed a SOEC model based on concepts in local thermodynamic equilibrium in systems otherwise in global thermodynamic non-equilibrium. This model is under continued development. It shows that electronic conduction through the electrolyte, however small, must be taken into account for determining local oxygen chemical potential, within the electrolyte. The chemical potential within the electrolyte may lie out of bounds in relation to values at the electrodes in the electrolyzer mode. Under certain conditions, high pressures can develop in the electrolyte just under the oxygen electrode (anode)/electrolyte interface, leading to electrode delamination. This theory is being further refined and tested by introducing some electronic conduction in the electrolyte.

  4. Advancing the technology base for high-temperature membranes

    SciTech Connect (OSTI)

    Dye, R.C.; Birdsell, S.A.; Snow, R.C. [and others

    1997-10-01

    This is the final report of a two-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). This project addresses the major issues confronting the implementation of high-temperature membranes for separations and catalysis. We are pursuing high-temperature membrane systems that can have a large impact for DOE and be industrially relevant. A major obstacle for increased use of membranes is that most applications require the membrane material to withstand temperatures above those acceptable for polymer-based systems. Advances made by this project have helped industry and DOE move toward high-temperature membrane applications to improve overall energy efficiency.

  5. Method for Synthesizing Extremeley High Temperature Melting Materials

    DOE Patents [OSTI]

    Saboungi, Marie-Louise and Glorieux, Benoit

    2005-11-22

    The invention relates to a method of synthesizing high-temperature melting materials. More specifically the invention relates to a containerless method of synthesizing very high temperature melting materials such as borides, carbides and transition-metal, lanthanide and actinide oxides, using an Aerodynamic Levitator and a laser. The object of the invention is to provide a method for synthesizing extremely high-temperature melting materials that are otherwise difficult to produce, without the use of containers, allowing the manipulation of the phase (amorphous/crystalline/metastable) and permitting changes of the environment such as different gaseous compositions.

  6. Method for synthesizing extremely high-temperature melting materials

    DOE Patents [OSTI]

    Saboungi, Marie-Louise (Chicago, IL); Glorieux, Benoit (Perpignan, FR)

    2007-11-06

    The invention relates to a method of synthesizing high-temperature melting materials. More specifically the invention relates to a containerless method of synthesizing very high temperature melting materials such as carbides and transition-metal, lanthanide and actinide oxides, using an aerodynamic levitator and a laser. The object of the invention is to provide a method for synthesizing extremely high-temperature melting materials that are otherwise difficult to produce, without the use of containers, allowing the manipulation of the phase (amorphous/crystalline/metastable) and permitting changes of the environment such as different gaseous compositions.

  7. Method For Synthesizing Extremely High-Temperature Melting Materials

    DOE Patents [OSTI]

    Saboungi, Marie-Louise (Chicago, IL); Glorieux, Benoit (Perpignan, FR)

    2005-11-22

    The invention relates to a method of synthesizing high-temperature melting materials. More specifically the invention relates to a containerless method of synthesizing very high temperature melting materials such as borides, carbides and transition-metal, lanthanide and actinide oxides, using an Aerodynamic Levitator and a laser. The object of the invention is to provide a method for synthesizing extremely high-temperature melting materials that are otherwise difficult to produce, without the use of containers, allowing the manipulation of the phase (amorphous/crystalline/metastable) and permitting changes of the environment such as different gaseous compositions.

  8. Assessment of Moderate- and High-Temperature Geothermal Resources...

    Open Energy Info (EERE)

    Assessment of Moderate- and High-Temperature Geothermal Resources of the United States Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Assessment of...

  9. Mold, flow, and economic considerations in high temperature precision casting

    E-Print Network [OSTI]

    Humbert, Matthew S

    2013-01-01

    Casting high temperature alloys that solidify through a noticeable two phase region, specifically platinum-ruthenium alloys, is a particularly challenging task due to their high melting temperature and this necessitates ...

  10. Energy Savings with High Temperature Water Generation Systems 

    E-Print Network [OSTI]

    Manicke, A. C.

    1982-01-01

    rapidly. This paper will present and evaluate the use of a high temperature water (HTW) system and a conventional steam system. Solid, liquid and gaseous fuel applications will be presented along with the application of HTW to Cogeneration Systems. Life...

  11. Enabling high-temperature nanophotonics for energy applications

    E-Print Network [OSTI]

    suppressed by 50% at 75° compared to nor- mal incidence. Finally, a precise high-temperature measurement applications, especially high-efficiency energy conversion systems encompassing hydrocarbon and radio- isotope

  12. Expansion Joint Concepts for High Temperature Insulation Systems 

    E-Print Network [OSTI]

    Harrison, M. R.

    1980-01-01

    As high temperature steam and process piping expands with heat, joints begin to open between the insulation sections, resulting in increased energy loss and possible unsafe surface temperatures. Many different expansion joint designs are presently...

  13. Enabling high-temperature nanophotonics for energy applications

    E-Print Network [OSTI]

    Yeng, YiXiang

    The nascent field of high-temperature nanophotonics could potentially enable many important solid-state energy conversion applications, such as thermophotovoltaic energy generation, selective solar absorption, and selective ...

  14. High Temperature Irradiation Resistant Thermocouple (HTIR-TC)

    ScienceCinema (OSTI)

    None

    2013-05-28

    INL researchers have created a new thermocouple that can resist high temperature and radiation. This device will improve safety and reduce costs associated with unit failures. Learn more about INL research at http://www.facebook.com/idahonationallaboratory

  15. The equation of state at high temperatures from lattice QCD

    E-Print Network [OSTI]

    G. Endrodi; Z. Fodor; S. D. Katz; K. K. Szabo

    2007-10-23

    We present results for the equation of state upto previously unreachable, high temperatures. Since the temperature range is quite large, a comparison with perturbation theory can be done directly.

  16. Study of Catcher Bearings for High Temperature Magnetic Bearing Application 

    E-Print Network [OSTI]

    Narayanaswamy, Ashwanth

    2011-08-08

    temperature permanent magnet based magnetic bearings. The magnetic bearings are made of high temperature resistant permanent magnets (up to 1000 degrees F). A test rig has been developed to test these magnetic bearings. The test rig mainly consists of two...

  17. Stability and quench protection of high-temperature superconductors

    E-Print Network [OSTI]

    Ang, Ing Chea

    2006-01-01

    In the design and operation of a superconducting magnet, stability and protection are two key issues that determine the magnet's reliability and safe operation. Although the high-temperature superconductor (HTS) is considered ...

  18. Project Profile: High-Temperature Thermochemical Storage with...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    fluidized bed to provide high-temperature heat exchange above the storage temperature to drive high-efficiency power cycles, such as super-critical CO2. Approach The research...

  19. Energy Recovery for Medium- and High-Temperature Industrial Furnaces 

    E-Print Network [OSTI]

    Krumm, E. D.

    1981-01-01

    The application of metallic heat exchangers on medium- and high-temperature industrial furnaces is examined. A thorough technical understanding of all furnace operating conditions and the duties imposed upon heat exchangers is identified as a key...

  20. Reducing PM Concentrations in Simulated High Temperature Gas Streams 

    E-Print Network [OSTI]

    Luehrs, Daniel R

    2014-08-07

    F). These high temperatures impact the cyclone inlet velocities as a consequence of the reduced gas densities. Changes in gas densities will influence the cyclone design. It was hypothesized that changes in cyclone performances as a consequence lower gas...

  1. Copper Aluminate as a potential material for high temperature...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Copper Aluminate as a potential material for high temperature thermoelectric power generation Home Author: D. T. Morelli, E. D. Case, B. D. Hall, S. Wang Year: 2008 Abstract: URL:...

  2. Transport and spectral functions in high-temperature QCD

    E-Print Network [OSTI]

    Gert Aarts

    2007-10-03

    The current status of transport coefficients in relativistic field theories at high temperature is reviewed. I contrast weak coupling results obtained using kinetic theory/diagrammatic techniques with strong coupling results obtained using gauge/gravity duality, and describe the recent developments in extracting transport coefficients and spectral functions from lattice QCD simulations. The fate of quarkonium at high temperature as seen from the lattice is briefly mentioned as well.

  3. Low GWP Working Fluid for High Temperature Heat Pumps

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    Low GWP Working Fluid for High Temperature Heat Pumps: DR-2 Chemical Stability at High Temperatures Temp Heat Pumps: DR-2 Very Low GWP AND Non-Flammable HFC-245fa DR-2 Chemical Formula CF3CH2CHF2 HFO 171.3 Pcr [MPa] 3.65 2.9 Kontomaris-DuPont; European Heat Pump Summit, Nuremberg, October 15th, 2013

  4. Non-graphite crucible for high temperature applications

    DOE Patents [OSTI]

    Holcombe, Cressie E. (Knoxville, TN); Pfeiler, William A. (Norris, TN)

    1996-01-01

    A multi-piece crucible for high temperature applications comprises a tubular side wall member having a lip on the inside surface and a bottom member or members forming a container for containing a melt of a material during a high temperature melt-casting operations. The multi-piece design prevents cracking of the crucible or leakage of the melt from the crucible during the melt-casting operation. The lip of the tubular member supports the bottom member. The contacting surfaces where the lip of the tubular side wall member contacts the bottom member of the multi-piece crucible contains a ceramic sealing material. The ceramic sealing material forms a seal sufficient to prevent the melt of the material from leaking out of the multi-piece crucible during the melt-casting process. The multi-piece crucible is made of a material which is chemically inert to the melt and has structural integrity at the melting point temperature of the melt, or of a material coated with such a material. The multi-piece crucible is contained in a thermal can assembly of a high temperature induction furnace during a high temperature melt-casting operation. One embodiment of the multi-piece crucible comprises a tubular member having a vertical slot filled with a ceramic sealing material to provide expansion of the tubular member without cracking during the high temperature melt-casting operation.

  5. Non-graphite crucible for high temperature applications

    DOE Patents [OSTI]

    Holcombe, C.E.; Pfeiler, W.A.

    1996-01-09

    A multi-piece crucible for high temperature applications comprises a tubular side wall member having a lip on the inside surface and a bottom member or members forming a container for containing a melt of a material during a high temperature melt-casting operations. The multi-piece design prevents cracking of the crucible or leakage of the melt from the crucible during the melt-casting operation. The lip of the tubular member supports the bottom member. The contacting surfaces where the lip of the tubular side wall member contacts the bottom member of the multi-piece crucible contains a ceramic sealing material. The ceramic sealing material forms a seal sufficient to prevent the melt of the material from leaking out of the multi-piece crucible during the melt-casting process. The multi-piece crucible is made of a material which is chemically inert to the melt and has structural integrity at the melting point temperature of the melt, or of a material coated with such a material. The multi-piece crucible is contained in a thermal can assembly of a high temperature induction furnace during a high temperature melt-casting operation. One embodiment of the multi-piece crucible comprises a tubular member having a vertical slot filled with a ceramic sealing material to provide expansion of the tubular member without cracking during the high temperature melt-casting operation. 9 figs.

  6. High-temperature corrosion control of lagged piping system components

    SciTech Connect (OSTI)

    Parks, R. (Dept. of the Navy, Naval Sea Systems Command, Code 05M11, Washington, DC (US)); Kogler, R.A. (Advanced Technology Inc., Arlington, VA (US))

    1990-07-01

    Over the past several years, the U.S. Navy has stepped up efforts to eliminate corrosion aboard its ships. One of the most effective techniques the Navy has employed is the application of sprayed aluminum for high-temperature corrosion protection. This sacrificial coating has performed well in the corrosion protection of high-temperature lagged steam valves and associated piping systems. Because of the superiority of the sprayed aluminum system over the conventional methods of protection for these piping systems, the Navy has realized considerable cost savings. These savings are the direct result of major reductions in routine maintenance associated with the application of sprayed aluminum coatings for corrosion protection purposes. This article discusses specific U.S. Navy experience with the use of sprayed aluminum coatings for high-temperature applications as well as current Navy practice regarding the use of this corrosion control coating.

  7. Measurement of thermodynamic temperature of high temperature fixed points

    SciTech Connect (OSTI)

    Gavrilov, V. R.; Khlevnoy, B. B.; Otryaskin, D. A.; Grigorieva, I. A.; Samoylov, M. L.; Sapritsky, V. I.

    2013-09-11

    The paper is devoted to VNIIOFI's measurements of thermodynamic temperature of the high temperature fixed points Co-C, Pt-C and Re-C within the scope of the international project coordinated by the Consultative Committee for Thermometry working group 5 'Radiation Thermometry'. The melting temperatures of the fixed points were measured by a radiance mode radiation thermometer calibrated against a filter radiometer with known irradiance spectral responsivity via a high temperature black body. This paper describes the facility used for the measurements, the results and estimated uncertainties.

  8. Quantum tunneling, quantum computing, and high temperature superconductivity 

    E-Print Network [OSTI]

    Wang, Qian

    2005-02-17

    -1 QUANTUM TUNNELING, QUANTUM COMPUTING, AND HIGH TEMPERATURE SUPERCONDUCTIVITY A Dissertation by QIAN WANG Submitted to the O?ce of Graduate Studies of Texas A&M University in partial ful?llment of the requirements for the degree of DOCTOR OF PHILOSOPHY... December 2003 Major Subject: Physics QUANTUM TUNNELING, QUANTUM COMPUTING, AND HIGH TEMPERATURE SUPERCONDUCTIVITY A Dissertation by QIAN WANG Submitted to Texas A&M University in partial ful?llment of the requirements for the degree of DOCTOR OF PHILOSOPHY...

  9. Method for high temperature mercury capture from gas streams

    DOE Patents [OSTI]

    Granite, E.J.; Pennline, H.W.

    2006-04-25

    A process to facilitate mercury extraction from high temperature flue/fuel gas via the use of metal sorbents which capture mercury at ambient and high temperatures. The spent sorbents can be regenerated after exposure to mercury. The metal sorbents can be used as pure metals (or combinations of metals) or dispersed on an inert support to increase surface area per gram of metal sorbent. Iridium and ruthenium are effective for mercury removal from flue and smelter gases. Palladium and platinum are effective for mercury removal from fuel gas (syngas). An iridium-platinum alloy is suitable for metal capture in many industrial effluent gas streams including highly corrosive gas streams.

  10. Toward Oxide Scale Behavior Management At High Temperature

    SciTech Connect (OSTI)

    Deltombe, R.; Dubar, M.; Dubois, A.; Dubar, L.

    2011-01-17

    Oxide scales grow freely on bare metallic surface under environmental conditions such as high temperature and oxygen. These act as thermal and mechanical shields, especially during high hot forming processes (>1000 deg. C). But product quality can be impacted by these oxide scales due to scale remaining on product or sticking on tools. Thus the TEMPO laboratory has created an original methodology in order to characterize oxide scale under high temperature, pressure and strain gradients. An experimental device has been developed. The final purpose of this work is to understand the scale behavior as a function of temperature, reduction ratio and steel composition.

  11. Vibration Combined High Temperature Cycle Tests for Capacitive MEMS Accelerometers

    E-Print Network [OSTI]

    Z. Szucs; G. Nagy; S. Hodossy; M. Rencz; A. Poppe

    2008-01-07

    In this paper vibration combined high temperature cycle tests for packaged capacitive SOI-MEMS accelerometers are presented. The aim of these tests is to provide useful Design for Reliability information for MEMS designers. A high temperature test chamber and a chopper-stabilized read-out circuitry were designed and realized at BME - DED. Twenty thermal cycles of combined Temperature Cycle Test and Fatigue Vibration Test has been carried out on 5 samples. Statistical evaluation of the test results showed that degradation has started in 3 out of the 5 samples.

  12. Viscosities of natural gases at high pressures and high temperatures 

    E-Print Network [OSTI]

    Viswanathan, Anup

    2007-09-17

    Estimation of viscosities of naturally occurring petroleum gases provides the information needed to accurately work out reservoir-engineering problems. Existing models for viscosity prediction are limited by data, especially at high pressures...

  13. Optical Fiber High Temperature Sensor Instrumentation for Energy Intensive Industries

    SciTech Connect (OSTI)

    Cooper, Kristie L.; Wang, Anbo; Pickrell, Gary R.

    2006-11-14

    This report summarizes technical progress during the program “Optical Fiber High Temperature Sensor Instrumentation for Energy Intensive Industries”, performed by the Center for Photonics Technology of the Bradley Department of Electrical and Computer Engineering at Virginia Tech. The objective of this program was to use technology recently invented at Virginia Tech to develop and demonstrate the application of self-calibrating optical fiber temperature and pressure sensors to several key energy-intensive industries where conventional, commercially available sensors exhibit greatly abbreviated lifetimes due primarily to environmental degradation. A number of significant technologies were developed under this program, including • a laser bonded silica high temperature fiber sensor with a high temperature capability up to 700°C and a frequency response up to 150 kHz, • the world’s smallest fiber Fabry-Perot high temperature pressure sensor (125 x 20 ?m) with 700°C capability, • UV-induced intrinsic Fabry-Perot interferometric sensors for distributed measurement, • a single crystal sapphire fiber-based sensor with a temperature capability up to 1600°C. These technologies have been well demonstrated and laboratory tested. Our work plan included conducting major field tests of these technologies at EPRI, Corning, Pratt & Whitney, and Global Energy; field validation of the technology is critical to ensuring its usefulness to U.S. industries. Unfortunately, due to budget cuts, DOE was unable to follow through with its funding commitment to support Energy Efficiency Science Initiative projects and this final phase was eliminated.

  14. Electronically conductive ceramics for high temperature oxidizing environments

    DOE Patents [OSTI]

    Kucera, Gene H. (Downers Grove, IL); Smith, James L. (Lemont, IL); Sim, James W. (Evergreen Park, IL)

    1986-01-01

    A high temperature, ceramic composition having electronic conductivity as measured by resistivity below about 500 ohm-cm, chemical stability particularly with respect to cathode conditions in a molten carbonate fuel cell, and composed of an alkali metal, transition metal oxide containing a dopant metal in the crystalline structure to replace a portion of the alkali metal or transition metal.

  15. Electronically conductive ceramics for high temperature oxidizing environments

    DOE Patents [OSTI]

    Kucera, G.H.; Smith, J.L.; Sim, J.W.

    1983-11-10

    This invention pertains to a high temperature, ceramic composition having electronic conductivity as measured by resistivity below about 500 ohm-cm, chemical stability particularly with respect to cathode conditions in a molten carbonate fuel cell, and composed of an alkali metal, transition metal oxide containing a dopant metal in the crystalline structure to replace a portion of the alkali metal or transition metal.

  16. Author's Accepted Manuscript High-temperature-oxidation-induced ordered struc-

    E-Print Network [OSTI]

    Laughlin, David E.

    and turbine power generation system, turbine alloys are exposed to high temperature and an atmosphere comprised of steam, CO2 and O2. While surface and internal oxidation of the alloy takes place-fuel combustion turbine power generation systems are being developed, materials performance of candidate

  17. PSO project: 4760 High Temperature PEM Fuel Cell

    E-Print Network [OSTI]

    PSO project: 4760 High Temperature PEM Fuel Cell Final report - Public part - #12;Project, Technical University of Denmark Partners: IRD Fuel Cells A/S Danish Power Systems Aps DONG Energy Authors, and a steady reduction of production cost is also desired (as in general for fuel cells). However, during

  18. ANALYSIS OF FUTURE PRICES AND MARKETS FOR HIGH TEMPERATURE SUPERCONDUCTORS

    E-Print Network [OSTI]

    1 ANALYSIS OF FUTURE PRICES AND MARKETS FOR HIGH TEMPERATURE SUPERCONDUCTORS BY JOSEPH MULHOLLAND temperature superconductors (HTS) may impact the national electrical system over the next 25 years dollars. However, the savings from superconductivity are offset somewhat by the high cost of manufacturing

  19. LALP-06-043 MATERIALSSCIENCEANDTECHNOLOGYDIVISIONRESEARCHHIGHLIGHTMATERIALSSCIENCEANDTECHNOLOGYDIVISIONRESEARCHHIGHLIGHT High temperature separation membranes

    E-Print Network [OSTI]

    membrane in a synthesis gas separation requires a membrane that is thermally, chemically, and mechanically MATERIALSSCIENCEANDTECHNOLOGYDIVISIONRESEARCHHIGHLIGHTMATERIALSSCIENCEANDTECHNOLOGYDIVISIONRESEARCHHIGHLIGHT High temperature separation membranes for hydrogen purification and carbon capture K.A. Berchtold, polymer-based membrane separations are less energy intensive, requiring no phase change in the process

  20. POWER-TO-GAS PROCESS WITH HIGH TEMPERATURE ELECTROLYSIS

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    · Transportation of energy from production areas to consumption areas Substitute Natural Gas (methane) Myriam DeP · Use of existing natural gas network · Mid or long term storage · Transportation · Production. Energy background 2. Power-to-Substitute Natural Gas process with high temperature steam electrolysis

  1. Control of High-Temperature Supersonic Impinging Jets Using Microjets

    E-Print Network [OSTI]

    Control of High-Temperature Supersonic Impinging Jets Using Microjets Rajan Kumar, Sladana Lazic.2514/1.39061 The flowfield associated with supersonic impinging jets has been of interest to both engineers and researchers fluid dynamic point of view. An example of supersonic impinging jets occurs in short takeoff

  2. Free energy of Lorentz-violating QED at high temperature

    E-Print Network [OSTI]

    M. Gomes; T. Mariz; J. R. Nascimento; A. Yu. Petrov; A. F. Santos; A. J. da Silva

    2010-02-25

    In this paper we study the one- and two-loop contribution to the free energy in QED with the Lorentz symmetry breaking introduced via constant CPT-even Lorentz-breaking parameters at the high temperature limit. We find the impact of the Lorentz-violating term for the free energy and carry out a numerical estimation for the Lorentz-breaking parameter.

  3. High Temperature coatings based on {beta}-NiAI

    SciTech Connect (OSTI)

    Severs, Kevin

    2012-07-10

    High temperature alloys are reviewed, focusing on current superalloys and their coatings. The synthesis, characerization, and oxidation performance of a NiAl–TiB{sub 2} composite are explained. A novel coating process for Mo–Ni–Al alloys for improved oxidation performance is examined. The cyclic oxidation performance of coated and uncoated Mo–Ni–Al alloys is discussed.

  4. THE HIGH TEMPERATURE CHEMICAL REACTIVITY OF LI2O

    SciTech Connect (OSTI)

    Kessinger, G.; Missimer, D.

    2009-11-13

    The ultimate purpose of this study was to investigate the use of a Li-Ca mixture for direct reduction of actinide oxides to actinide metals at temperatures below 1500 C. For such a process to be successful, the products of the reduction reaction, actinide metals, Li{sub 2}O, and CaO, must all be liquid at the reaction temperature so the resulting actinide metal can coalesce and be recovered as a monolith. Since the established melting temperature of Li{sub 2}O is in the range 1427-1700 C and the melting temperature of CaO is 2654 C, the Li{sub 2}O-CaO (lithium oxidecalcium oxide) pseudo-binary system was investigated in an attempt to identify the presence of low-melting eutectic compositions. The results of our investigation indicate that there is no evidence of ternary Li-Ca-O phases or solutions melting below 1200 C. In the 1200-1500 C range utilizing MgO crucibles, there is some evidence for the formation of a ternary phase; however, it was not possible to determine the phase composition. The results of experiments performed with ZrO{sub 2} crucibles in the same temperature range did not show the formation of the possible ternary phase seen in the earlier experiment involving MgO crucibles, so it was not possible to confirm the possibility that a ternary Li-Ca-O or Li-Mg-O phase was formed. It appears that the Li{sub 2}O-CaO materials reacted, to some extent, with all of the container materials, alumina (Al{sub 2}O{sub 3}), magnesia (MgO), zirconia (ZrO{sub 2}), and 95% Pt-5% Au; however, to clarify the situation additional experiments are required. In addition to the primary purpose of this study, the results of this investigation led to the conclusions that: (1) The melting temperature of Li{sub 2}O may be as low as 1250 C, which is considerably lower than the previously published values in the range 1427-1700 C; (2) Lithium oxide (Li{sub 2}O) vaporizes congruently; (3) Lithium carbonate and Li2O react with 95% Pt-5% Au, and also reacts with pure Pt; and (4) It is likely that some or all of the past high temperature phase behavior and vaporization experiments involving Li{sub 2}O(s) at temperatures above 1250 C have actually involved Li{sub 2}O(l). If these past measurements were actually measurements performed on Li{sub 2}O(l) instead of the solid, the thermochemical data for phases and species in the Li-O system will require reevaluation.

  5. High Temperature Materials Interim Data Qualification Report FY 2011

    SciTech Connect (OSTI)

    Nancy Lybeck

    2011-08-01

    Projects for the very high temperature reactor (VHTR) Technology Development Office provide data in support of Nuclear Regulatory Commission licensing of the VHTR. Fuel and materials to be used in the reactor are tested and characterized to quantify performance in high temperature and high fluence environments. The VHTR program has established the Next Generation Nuclear Plant (NGNP) Data Management and Analysis System (NDMAS) to ensure that VHTR data are qualified for use, stored in a readily accessible electronic form, and analyzed to extract useful results. This document focuses on the first NDMAS objective. It describes the High Temperature Materials characterization data stream, the processing of these data within NDMAS, and reports the interim fiscal year (FY) 2011 qualification status of the data. Data qualification activities within NDMAS for specific types of data are determined by the data qualification category assigned by the data generator. The High Temperature Materials data are being collected under the Nuclear Quality Assurance (NQA)-1 guidelines and will be qualified data. For NQA-1 qualified data, the qualification activities include: (1) capture testing to confirm that the data stored within NDMAS are identical to the raw data supplied, (2) accuracy testing to confirm that the data are an accurate representation of the system or object being measured, and (3) documenting that the data were collected under an NQA-1 or equivalent Quality Assurance program. Currently, data from seven test series within the High Temperature Materials data stream have been entered into the NDMAS vault, including tensile tests, creep tests, and cyclic tests. Of the 5,603,682 records currently in the vault, 4,480,444 have been capture passed, and capture testing is in process for the remaining 1,123,238.

  6. Support for Cost Analyses on Solar-Driven High Temperature Thermochemi...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Support for Cost Analyses on Solar-Driven High Temperature Thermochemical Water-Splitting Cycles Support for Cost Analyses on Solar-Driven High Temperature Thermochemical...

  7. A Discussion of Conductivity Testing in High Temperature Membranes (lessons learned in assessing transport)

    Broader source: Energy.gov [DOE]

    Presentation on conductivity testing in high temperature membranes given by Jim Boncella of Los Alamos National Laboratory at the High Temperature Membrane Working Group meeting in October 2005.

  8. CARISMA: A Networking Project for High Temperature PEMFC MEA Activities in Europe

    Office of Energy Efficiency and Renewable Energy (EERE)

    This presentation on high temperature proton exchange membrane fuel cells was given at the High Temperature Membrane Working Group Meeting in May 2007.

  9. Thermal Conductivity Enhancement of High Temperature Phase Change Materials for Concentrating Solar Power Plant Applications

    E-Print Network [OSTI]

    Roshandell, Melina

    2013-01-01

    that can operate with Stirling engines at 42% efficiency andfor high temperature Stirling engines which operates at 42%turbines such as Stirling engines, while high-temperature (>

  10. High-Temperature Zirconia Oxygen Sensor with Sealed Metal/Metal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference...

  11. Universal Membrane Classification Scheme: Maximizing the Return on High Temperature PEM Membrane Research

    Broader source: Energy.gov [DOE]

    This presentation on maximizing the return of high temperature PEM membrane research was given at the High Temperature Membrane Working Group Meeting in May 2007.

  12. High-Temperature Thermoelectric Characterization of III–V Semiconductor Thin Films by Oxide Bonding

    E-Print Network [OSTI]

    2010-01-01

    High-Temperature Thermoelectric Characterization of III–Vfor high-temperature thermoelectric charac- terization ofdiffusion barrier. A thermoelectric material, thin-?lm ErAs:

  13. High temperature solar thermal technology: The North Africa Market

    SciTech Connect (OSTI)

    Not Available

    1990-12-01

    High temperature solar thermal (HTST) technology offers an attractive option for both industrialized and non-industrialized countries to generate electricity and industrial process steam. The purpose of this report is to assess the potential market for solar thermal applications in the North African countries of Algeria, Egypt, Morocco and Tunisia. North Africa was selected because of its outstanding solar resource base and the variety of applications to be found there. Diminishing oil and gas resources, coupled with expanding energy needs, opens a large potential market for the US industry. The US high temperature solar trough industry has little competition globally and could build a large market in these areas. The US is already familiar with certain solar markets in North Africa due to the supplying of substantial quantities of US-manufactured flat plate collectors to this region.

  14. Liquid Fuel Production from Biomass via High Temperature Steam Electrolysis

    SciTech Connect (OSTI)

    Grant L. Hawkes; Michael G. McKellar

    2009-11-01

    A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to heat steam for the hydrogen production via the high temperature steam electrolysis process. Hydrogen from electrolysis allows a high utilization of the biomass carbon for syngas production. Oxygen produced form the electrolysis process is used to control the oxidation rate in the oxygen-fed biomass gasifier. Based on the gasifier temperature, 94% to 95% of the carbon in the biomass becomes carbon monoxide in the syngas (carbon monoxide and hydrogen). Assuming the thermal efficiency of the power cycle for electricity generation is 50%, (as expected from GEN IV nuclear reactors), the syngas production efficiency ranges from 70% to 73% as the gasifier temperature decreases from 1900 K to 1500 K. Parametric studies of system pressure, biomass moisture content and low temperature alkaline electrolysis are also presented.

  15. High temperature superconductivity in metallic region near Mott transition

    E-Print Network [OSTI]

    Tian De Cao

    2009-09-11

    The spin-singlet superconductivity without phonons is examined in consideration of correlations on an extended Hubbard model. It is shown that the superconductivity requires not only the total correlation should be strong enough but also the density of state around Fermi energy should be large enough, which shows that the high temperature superconductivity could only be found in the metallic region near the Mott metal insulator transition (MIT). Other properties of superconductors are also discussed on these conclusions.

  16. Furnace Controls Using High Temperature Preheated Combustion Air 

    E-Print Network [OSTI]

    Gonzales, J. M.; Rebello, W. J.

    1981-01-01

    FURNACE CONTROLS USING HIGH TEMPERATURE PREHEATED COMBUSTION AIR Jeffrey M. Gonzalez Wilfred J. Rebello GTE Products Corporation PAR Enterprises, Inc. Towanda, Pennsylvania Fairfax, Virginia ABSTRACT GTE Products Corporation (Towanda... available ratio control apparatus. Various control sys (I) was the development of a different way of looking at combustion. As preheated combustion air temperatures increase, excess air Industrial furnaces generally utilize air as the basic source...

  17. Deposition method for producing silicon carbide high-temperature semiconductors

    DOE Patents [OSTI]

    Hsu, George C. (La Crescenta, CA); Rohatgi, Naresh K. (W. Corine, CA)

    1987-01-01

    An improved deposition method for producing silicon carbide high-temperature semiconductor material comprising placing a semiconductor substrate composed of silicon carbide in a fluidized bed silicon carbide deposition reactor, fluidizing the bed particles by hydrogen gas in a mildly bubbling mode through a gas distributor and heating the substrate at temperatures around 1200.degree.-1500.degree. C. thereby depositing a layer of silicon carbide on the semiconductor substrate.

  18. Cryocooler applications for high-temperature superconductor magnetic bearings.

    SciTech Connect (OSTI)

    Niemann, R. C.

    1998-05-22

    The efficiency and stability of rotational magnetic suspension systems are enhanced by the use of high-temperature superconductor (HTS) magnetic bearings. Fundamental aspects of the HTS magnetic bearings and rotational magnetic suspension are presented. HTS cooling can be by liquid cryogen bath immersion or by direct conduction, and thus there are various applications and integration issues for cryocoolers. Among the numerous cryocooler aspects to be considered are installation; operating temperature; losses; and vacuum pumping.

  19. Sealed glass coating of high temperature ceramic superconductors

    DOE Patents [OSTI]

    Wu, Weite (Tainan, TW); Chu, Cha Y. (Garnerville, NY); Goretta, Kenneth C. (Downers Grove, IL); Routbort, Jules L. (Darien, IL)

    1995-01-01

    A method and article of manufacture of a lead oxide based glass coating on a high temperature superconductor. The method includes preparing a dispersion of glass powders in a solution, applying the dispersion to the superconductor, drying the dispersion before applying another coating and heating the glass powder dispersion at temperatures below oxygen diffusion onset and above the glass melting point to form a continuous glass coating on the superconductor to establish compressive stresses which enhance the fracture strength of the superconductor.

  20. High-Temperature Downhole Tools | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas: Energy Resources Jump to:Hershey,High-Temperature Downhole Tools Jump to:

  1. High power densities from high-temperature material interactions

    SciTech Connect (OSTI)

    Morris, J.F.

    1981-01-01

    Thermionic energy conversion (TEC) and metallic-fluid heat pipes (MFHPs) offer important and unique advantages in terrestrial and space energy processing. And they are well suited to serve together synergistically. TEC and MFHPs operate through working-fluid vaporization, condensation cycles that accept great thermal power densities at high temperatures. TEC and MFHPs have apparently simple, isolated performance mechanisms that are somewhat similar. And they also have obviously difficult, complected material problems that again are somewhat similar. Intensive investigation reveals that aspects of their operating cycles and material problems tend to merge: high-temperature material effects determine the level and lifetime of performance. Simplified equations verify the preceding statement for TEC and MFHPs. Material properties and interactions exert primary influences on operational effectiveness. And thermophysicochemical stabilities dictate operating temperatures which regulate the thermoemissive currents of TEC and the vaporization flow rates of MFHPs. Major high-temperature material problems of TEC and MFHPs have been solved. These solutions lead to productive, cost-effective applications of current TEC and MFHPs - and point to significant improvements with anticipated technological gains.

  2. Improved Durability of SOEC Stacks for High Temperature Electrolysis

    SciTech Connect (OSTI)

    James E. O'Brien; Robert C. O'Brien; Xiaoyu Zhang; Joseph J. Hartvigsen; Greg Tao

    2013-01-01

    High temperature steam electrolysis is a promising technology for efficient and sustainable large-scale hydrogen production. Solid oxide electrolysis cells (SOECs) are able to utilize high temperature heat and electric power from advanced high-temperature nuclear reactors or renewable sources to generate carbon-free hydrogen at large scale. However, long term durability of SOECs needs to be improved significantly before commercialization of this technology can be realized. A degradation rate of 1%/khr or lower is proposed as a threshold value for commercialization of this technology. Solid oxide electrolysis stack tests have been conducted at Idaho National Laboratory to demonstrate recent improvements in long-term durability of SOECs. Electrolyte-supported and electrode-supported SOEC stacks were provided by Ceramatec Inc. and Materials and Systems Research Inc. (MSRI), respectively, for these tests. Long-term durability tests were generally operated for a duration of 1000 hours or more. Stack tests based on technologies developed at Ceramatec and MSRI have shown significant improvement in durability in the electrolysis mode. Long-term degradation rates of 3.2%/khr and 4.6%/khr were observed for MSRI and Ceramatec stacks, espectively. One recent Ceramatec stack even showed negative degradation (performance improvement) over 1900 hours of operation. Optimization of electrode materials, interconnect coatings, and electrolyte-electrode interface microstructures contribute to better durability of SOEC stacks.

  3. Predicting reservoir sedimentation 

    E-Print Network [OSTI]

    Wooten, Stephanie

    1997-01-01

    Sediments accumulate in reservoirs and significantly decrease storage capacity. Predicting sedimentation is an important consideration in the design of new reservoir projects and in the management of existing reservoirs. Sedimentation rates may vary...

  4. High Temperature Fuel Cell Performance High Temperature Fuel Cell Performance of of Sulfonated Sulfonated Poly(phenylene Poly(phenylene) Proton) Proton Conducting Conducting Polymers

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation by Sandia National Laboratories to the High Temperature Membrane Working Group Meeting held in Honolulu, Hawaii October 8, 2004.

  5. Enhancements to High Temperature In-Pile Thermocouple Performance

    SciTech Connect (OSTI)

    J.C. Crepeau; J.L. Rempe; J.E. Daw; D.L. Knudson: K.G. Condie; S.C. Wilkins

    2008-03-31

    A joint University of Idaho (UI) and Idaho National Laboratory (INL) University Nuclear Research Initiative (UNERI) was to initiated to extend initial INL efforts to develop doped molybdenum/niobium alloy High Temperature Irradiation Resistant Thermocouples (HTIR-TCs). The overall objective of this UNERI was to develop recommendations for an optimized thermocouple design for high temperature, long duration, in-pile testing by expanding upon results from initial INL efforts. Tasks to quantify the impact of candidate enhancements, such as alternate alloys, alternate geometries, and alternate thermocouple fabrication techniques, on thermocouple performance were completed at INL's High Temperature Test Laboratory (HTTL), a state of the art facility equipped with specialized equipment and trained staff in the area of high temperature instrumentation development and evaluation. Key results of these evaluations, which are documented in this report, are as follows. The doped molybdenum and Nb-1%Zr, which were proposed in the initial INL HTIR-TC design, were found to retain ductility better than the developmental molybdenum-low niobium alloys and the niobium-low molybdenum alloys evaluated. Hence, the performance and lower cost of the commercially available KW-Mo makes a thermocouple containing KW-Mo and Nb-1%Zr the best option at this time. HTIR-TCs containing larger diameter wires offer the potential to increase HTIR-TC stability and reliability at higher temperatures. HTIR-TC heat treatment temperatures and times should be limited to not more than 100 C above the proposed operating temperatures and to durations of at least 4 to 5 hours. Preliminary investigations suggest that the performance of swaged and loose assembly HTIR-TC designs is similar. However, the swaged designs are less expensive and easier to construct. In addition to optimizing HTIR-TC performance, This UNERI project provided unique opportunities to several University of Idaho students, allowing them to become familiar with the techniques and equipment used for specialized high temperature instrumentation fabrication and evaluation and to author/coauthor several key conference papers and journal articles.

  6. Enhancements to High Temperature In-Pile Thermocouple Performance

    SciTech Connect (OSTI)

    J. C. Crepeau; J. L. Rempe; J. E. Daw; D. L. Knudson; K. G. Condie; S. C. Wilkins

    2008-03-01

    A joint University of Idaho (UI) and Idaho National Laboratory (INL) University Nuclear Research Initiative (UNERI) was to initiated to extend initial INL efforts to develop doped lybdenum/niobium alloy High Temperature Irradiation Resistant Thermocouples (HTIR-TCs). The overall objective of this UNERI was to develop recommendations for an optimized thermocouple design for high temperature, long duration, in-pile testing by expanding upon results from initial INL efforts. Tasks to quantify the impact of candidate enhancements, such as alternate alloys, alternate geometries, and alternate thermocouple fabrication techniques, on thermocouple performance were completed at INL's High Temperature Test Laboratory (HTTL), a state of the art facility equipped with specialized equipment and trained staff in the area of high temperature instrumentation development and evaluation. Key results of these evaluations, which are documented in this report, are as follows. The doped molybdenum and Nb-1%Zr, which were proposed in the initial INL HTIR-TC design, were found to retain ductility better than the developmental molybdenum-low niobium alloys and the niobium-low molybdenum alloys evaluated. Hence, the performance and lower cost of the commercially available KW-Mo makes a thermocouple containing KW-Mo and Nb-1%Zr the best option at this time. HTIR-TCs containing larger diameter wires offer the potential to increase HTIR-TC stability and reliability at higher temperatures. HTIR-TC heat treatment temperatures and times should be limited to not more than 100 °C above the proposed operating temperatures and to durations of at least 4 to 5 hours. Preliminary investigations suggest that the performance of swaged and loose assembly HTIR-TC designs is similar. However, the swaged designs are less expensive and easier to construct. In addition to optimizing HTIR-TC performance, This UNERI project provided unique opportunities to several University of Idaho students, allowing them to become familiar with the techniques and equipment used for specialized high temperature instrumentation fabrication and evaluation and to author/coauthor several key conference papers and journal articles.

  7. Discrete Fracture Reservoir Simulation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Discrete Fracture Reservoir Simulation Shale Gas Flow Simulation Shale Gas Flow Simulation FRACGENNFFLOW, fractured reservoir modeling software developed by NETL's Geological and...

  8. 11th Topical conference high-temperature plasma diagnostics. Book of abstracts

    SciTech Connect (OSTI)

    1996-06-01

    This report contains abstracts from the 11th topical conference on high-temperature plasma diagnostics.

  9. Minutes of the October 2008 Meeting of the High Temperature Membrane Working Group

    Broader source: Energy.gov [DOE]

    Meeting minutes of the High Temperature Membrane Working Group from October 16, 2008, in Honolulu, Hawaii.

  10. Spectroscopy and kinetics of combustion gases at high temperatures

    SciTech Connect (OSTI)

    Hanson, R.K.; Bowman, C.T. [Stanford Univ., CA (United States)

    1993-12-01

    This program involves two complementary activities: (1) development and application of cw ring dye laser absorption methods for sensitive detection of radical species and measurement of fundamental spectroscopic parameters at high temperatures; and (2) shock tube studies of reaction kinetics relevant to combustion. Species currently under investigation in the spectroscopic portion of the research include NO and CH{sub 3}; this has necessitated the continued operated at wavelengths in the range 210-230 nm. Shock tube studies of reaction kinetics currently are focussed on reactions involving CH{sub 3} radicals.

  11. Narrowband high temperature superconducting receiver for low frequency radio waves

    DOE Patents [OSTI]

    Reagor, David W. (Los Alamos, NM)

    2001-01-01

    An underground communicating device has a low-noise SQUID using high temperature superconductor components connected to detect a modulated external magnetic flux for outputting a voltage signal spectrum that is related to the varying magnetic flux. A narrow bandwidth filter may be used to select a portion of the voltage signal spectrum that is relatively free of power line noise to output a relatively low noise output signal when operating in a portion of the electromagnetic spectra where such power line noise exists. A demodulator outputs a communication signal, which may be an FM signal, indicative of a modulation on the modulated external magnetic flux.

  12. Evaluation of permanent magnets for high temperature operations 

    E-Print Network [OSTI]

    Van Hees, Elizabeth

    1985-01-01

    as 3H F = x. m. H- &x where x = the magnetic susceptibility, which is the magnetic moment, M, divided by H, the field strength. The partial differential, 3H/ax, is the field gradient of the magnet, and m is the mass of the sample. This equation... is to inves- tigate the relevent magnetic properties of commercially availalbe magnetic materials for prolonged use in a high temperature environment (200'C to 450'C). Such materials can be utilized in geothermal and petroleum well logging. A device...

  13. Oxygen Handling and Cooling Options in High Temperature Electrolysis Plants

    SciTech Connect (OSTI)

    Manohar S. Sohal; J. Stephen Herring

    2008-07-01

    Idaho National Laboratory is working on a project to generate hydrogen by high temperature electrolysis (HTE). In such an HTE system, safety precautions need to be taken to handle high temperature oxygen at ~830°C. This report is aimed at addressing oxygen handling in a HTE plant.. Though oxygen itself is not flammable, most engineering material, including many gases and liquids, will burn in the presence of oxygen under some favorable physicochemical conditions. At present, an absolute set of rules does not exist that can cover all aspects of oxygen system design, material selection, and operating practices to avoid subtle hazards related to oxygen. Because most materials, including metals, will burn in an oxygen-enriched environment, hazards are always present when using oxygen. Most materials will ignite in an oxygen-enriched environment at a temperature lower than that in air, and once ignited, combustion rates are greater in the oxygen-enriched environment. Even many metals, if ignited, burn violently in an oxygen-enriched environment. However, these hazards do not preclude the operations and systems involving oxygen. Oxygen can be safely handled and used if all the materials in a system are not flammable in the end-use environment or if ignition sources are identified and controlled. In fact, the incidence of oxygen system fires is reported to be low with a probability of about one in a million. This report is a practical guideline and tutorial for the safe operation and handling of gaseous oxygen in high temperature electrolysis system. The intent is to provide safe, practical guidance that permits the accomplishment of experimental operations at INL, while being restrictive enough to prevent personnel endangerment and to provide reasonable facility protection. Adequate guidelines are provided to govern various aspects of oxygen handling associated with high temperature electrolysis system to generate hydrogen. The intent here is to present acceptable oxygen standards and practices for minimum safety requirements. A summary of operational hazards, along with oxygen safety and emergency procedures, are provided.

  14. Nearly Perfect Fluidity in a High Temperature Superconductor

    SciTech Connect (OSTI)

    Rameau, J. D.; Reber, T. J.; Yang, H. -B.; Akhanjee, S.; Gu, G. D.; Johnson, P. D.; Campbell, S.

    2014-10-13

    Perfect fluids are characterized as having the smallest ratio of shear viscosity to entropy density, ?/s, consistent with quantum uncertainty and causality. So far, nearly perfect fluids have only been observed in the quark-gluon plasma and in unitary atomic Fermi gases, exotic systems that are amongst the hottest and coldest objects in the known universe, respectively. We use angle resolved photoemission spectroscopy to measure the temperature dependence of an electronic analog of ?/s in an optimally doped cuprate high-temperature superconductor, finding it too is a nearly perfect fluid around, and above, its superconducting transition temperature Tc.

  15. Conductor requirements for high-temperature superconducting utility power transformers

    SciTech Connect (OSTI)

    Pleva, E. F. [Waukesha Electric Systems, Waukesha, WI; Mehrotra, V. [Waukesha Electric Systems, Waukesha, WI; Schwenterly, S W [ORNL

    2010-01-01

    High-temperature superconducting (HTS) coated conductors in utility power transformers must satisfy a set of operating requirements that are driven by two major considerations-HTS transformers must be economically competitive with conventional units, and the conductor must be robust enough to be used in a commercial manufacturing environment. The transformer design and manufacturing process will be described in order to highlight the various requirements that it imposes on the HTS conductor. Spreadsheet estimates of HTS transformer costs allow estimates of the conductor cost required for an HTS transformer to be competitive with a similarly performing conventional unit.

  16. Control for monitoring thickness of high temperature refractory

    DOE Patents [OSTI]

    Caines, M.J.

    1982-11-23

    This invention teaches an improved monitoring device for detecting the changes in thickness of high-temperature refractory, the device consists of a probe having at least two electrically conductive generally parallel elements separated by a dielectric material. The probe is implanted or embedded directly in the refractory and is elongated to extend in line with the refractory thickness to be measured. Electrical inputs to the conductive elements provide that either or both the electrical conductance or capacitance can be found, so that charges over lapsed time periods can be compared in order to detect changes in the thickness of the refractory.

  17. Silver-bearing, high-temperature, superconducting (HTS) paint

    SciTech Connect (OSTI)

    Ferrando, W.A.

    1990-02-15

    A substantial set of device applications awaits development of a workable, durable, high-temperature superconducting (HTS) paint. Such a paint should be truly superconducting with its critical temperature T sub c>77K. For most of these applications, a high critical current (J sub c) is not required, although probably desirable. A process is described which can be used to produce silver-bearing HTS paint coatings on many engineering materials. Preliminary tests have shown good adherence to several ceramics and the ability to meet the superconducting criteria. Moreover, the coatings withstand multiple thermal cycling and stability under laboratory ambient storage conditions for periods of at least several months.

  18. Sealed glass coating of high temperature ceramic superconductors

    DOE Patents [OSTI]

    Wu, W.; Chu, C.Y.; Goretta, K.C.; Routbort, J.L.

    1995-05-02

    A method and article of manufacture of a lead oxide based glass coating on a high temperature superconductor is disclosed. The method includes preparing a dispersion of glass powders in a solution, applying the dispersion to the superconductor, drying the dispersion before applying another coating and heating the glass powder dispersion at temperatures below oxygen diffusion onset and above the glass melting point to form a continuous glass coating on the superconductor to establish compressive stresses which enhance the fracture strength of the superconductor. 8 figs.

  19. Nearly Perfect Fluidity in a High Temperature Superconductor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rameau, J. D.; Reber, T. J.; Yang, H. -B.; Akhanjee, S.; Gu, G. D.; Johnson, P. D.; Campbell, S.

    2014-10-13

    Perfect fluids are characterized as having the smallest ratio of shear viscosity to entropy density, ?/s, consistent with quantum uncertainty and causality. So far, nearly perfect fluids have only been observed in the quark-gluon plasma and in unitary atomic Fermi gases, exotic systems that are amongst the hottest and coldest objects in the known universe, respectively. We use angle resolved photoemission spectroscopy to measure the temperature dependence of an electronic analog of ?/s in an optimally doped cuprate high-temperature superconductor, finding it too is a nearly perfect fluid around, and above, its superconducting transition temperature Tc.

  20. High-Temperature-High-Volume Lifting For Enhanced Geothermal Systems

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas: Energy Resources Jump to:Hershey,High-Temperature Downhole Tools Jump to:Geothermal

  1. Non-graphite crucible for high temperature applications

    DOE Patents [OSTI]

    Holcombe, Cressie E. (Knoxville, TN); Pfeiler, William A. (Norris, TN)

    1994-01-01

    A multi-piece crucible for high temperature applications comprises a tubular side wall member having a lip on the inside surface and a bottom member or members forming a container for containing a melt of a material during a high temperature melt-casting operations. The multi-piece design prevents cracking of the crucible or leakage of the melt from the crucible during the melt-casting operation. The lip of the tubular member supports the bottom member. The contacting surfaces where the lip of the tubular side wall member contacts the bottom member of the multi-piece crucible contains a ceramic sealing material. The ceramic sealing material forms a seal sufficient to prevent the melt of the material from leaking out of the multi-piece crucible during the melt-casting process. The multi-piece crucible is made of a material which is chemically inert to the melt and has structural integrity at the melting point temperature of the melt, or of a material coated with such a material.

  2. High temperature thermometric phosphors for use in a temperature sensor

    DOE Patents [OSTI]

    Allison, Stephen W. (Knoxville, TN); Cates, Michael R. (Oak Ridge, TN); Boatner, Lynn A. (Oak Ridge, TN); Gillies, George T. (Earlysville, VA)

    1998-01-01

    A high temperature phosphor consists essentially of a material having the general formula LuPO.sub.4 :Dy.sub.(x),Eu.sub.(y), wherein: 0.1 wt %.ltoreq.x.ltoreq.20 wt % and 0.1 wt %.ltoreq.y.ltoreq.20 wt %. The high temperature phosphor is in contact with an article whose temperature is to be determined. The article having the phosphor in contact with it is placed in the environment for which the temperature of the article is to be determined. The phosphor is excited by a laser causing the phosphor to fluoresce. The emission from the phosphor is optically focused into a beam-splitting mirror which separates the emission into two separate emissions, the emission caused by the dysprosium dopant and the emission caused by the europium dopent. The separated emissions are optically filtered and the intensities of the emission are detected and measured. The ratio of the intensity of each emission is determined and the temperature of the article is calculated from the ratio of the intensities of the separate emissions.

  3. Non-graphite crucible for high temperature applications

    DOE Patents [OSTI]

    Holcombe, C.E.; Pfeiler, W.A.

    1994-08-02

    A multi-piece crucible for high temperature applications comprises a tubular side wall member having a lip on the inside surface and a bottom member or members forming a container for containing a melt of a material during a high temperature melt-casting operations. The multi-piece design prevents cracking of the crucible or leakage of the melt from the crucible during the melt-casting operation. The lip of the tubular member supports the bottom member. The contacting surfaces where the lip of the tubular side wall member contacts the bottom member of the multi-piece crucible contains a ceramic sealing material. The ceramic sealing material forms a seal sufficient to prevent the melt of the material from leaking out of the multi-piece crucible during the melt-casting process. The multi-piece crucible is made of a material which is chemically inert to the melt and has structural integrity at the melting point temperature of the melt, or of a material coated with such a material. 6 figs.

  4. Microstructure, Processing, Performance Relationships for High Temperature Coatings

    SciTech Connect (OSTI)

    Thomas M. Lillo

    2011-04-01

    This work evaluates the suitability of iron aluminide coatings for use in high temperature fossil fuel combustion environments, such as boiler applications. The coatings are applied using High Velocity Oxy-Fuel (HVOF) thermal spray techniques. Iron aluminide coatings, with the nominal composition of Fe3Al, were applied to various high temperature structural materials (316 Stainless Steel, 9Cr-1Mo steel and Inconel 600) that typically lack inherent resistance to environmental degradation found in fossil fuel combustion atmospheres. Coating/substrate combinations were subjected to thermal cycling to evaluate the effect of HVOF parameters, coating thickness, substrate material and substrate surface roughness on the resistance to coating delamination and cracking. It was found that substrate surface roughness had a profound influence on the performance of a given substrate/coating system and that surface preparation techniques will need to be tailored to the specific substrate material. Also, higher particle velocity during HVOF thermal spray deposition of the iron aluminide coatings tended to result in better-performing coating/substrate systems with less delamination at the coating/substrate interface. Some combinations of HVOF parameters, coating thickness and substrate materials were found to perform extremely well even at temperatures up to 900oC. However, in some cases, substantial reactions at the interface were observed.

  5. High temperature thermometric phosphors for use in a temperature sensor

    DOE Patents [OSTI]

    Allison, S.W.; Cates, M.R.; Boatner, L.A.; Gillies, G.T.

    1998-03-24

    A high temperature phosphor consists essentially of a material having the general formula LuPO{sub 4}:Dy{sub (x)},Eu{sub (y)}, wherein: 0.1 wt %{<=}x{<=}20 wt % and 0.1 wt %{<=}y{<=}20 wt %. The high temperature phosphor is in contact with an article whose temperature is to be determined. The article having the phosphor in contact with it is placed in the environment for which the temperature of the article is to be determined. The phosphor is excited by a laser causing the phosphor to fluoresce. The emission from the phosphor is optically focused into a beam-splitting mirror which separates the emission into two separate emissions, the emission caused by the dysprosium dopant and the emission caused by the europium dopant. The separated emissions are optically filtered and the intensities of the emission are detected and measured. The ratio of the intensity of each emission is determined and the temperature of the article is calculated from the ratio of the intensities of the separate emissions. 2 figs.

  6. Rotational Rehybridization and the High Temperature Phase of UC2

    SciTech Connect (OSTI)

    Wen, Xiaodong; Rudin, Sven P.; Batista, Enrique R.; Clark, David L.; Scuseria, Gustavo E.; Martin, Richard L.

    2012-12-03

    The screened hybrid approximation (HSE) of density functional theory (DFT) is used to examine the structural, optical, and electronic properties of the high temperature phase, cubic UC(2). This phase contains C(2) units with a computed C-C distance of 1.443 Å which is in the range of a CC double bond; U is formally 4+, C(2) 4-. The closed shell paramagnetic state (NM) was found to lie lowest. Cubic UC(2) is found to be a semiconductor with a narrow gap, 0.4 eV. Interestingly, the C(2) units connecting two uranium sites can rotate freely up to an angle of 30°, indicating a hindered rotational solid. Ab-initio molecular dynamic simulations (HSE) show that the rotation of C(2) units in the low temperature phase (tetragonal UC(2)) occurs above 2000 K, in good agreement with experiment. The computed energy barrier for the phase transition from tetragonal UC(2) to cubic UC(2) is around 1.30 eV per UC(2). What is fascinating about this system is that at high temperature, the phase transformation to the cubic phase is associated with a rehybridization of the C atoms from sp to sp(3).

  7. Baseline Concept Description of a Small Modular High Temperature Reactor

    SciTech Connect (OSTI)

    Hans Gougar

    2014-05-01

    The objective of this report is to provide a description of generic small modular high temperature reactors (herein denoted as an smHTR), summarize their distinguishing attributes, and lay out the research and development (R&D) required for commercialization. The generic concepts rely heavily on the modular high temperature gas-cooled reactor designs developed in the 1980s which were never built but for which pre-licensing or certification activities were conducted. The concept matured more recently under the Next Generation Nuclear Plant (NGNP) project, specifically in the areas of fuel and material qualification, methods development, and licensing. As all vendor-specific designs proposed under NGNP were all both ‘small’ or medium-sized and ‘modular’ by International Atomic Energy Agency (IAEA) and Department of Energy (DOE) standards, the technical attributes, challenges, and R&D needs identified, addressed, and documented under NGNP are valid and appropriate in the context of Small Modular Reactor (SMR) applications. Although the term High Temperature Reactor (HTR) is commonly used to denote graphite-moderated, thermal spectrum reactors with coolant temperatures in excess of 650oC at the core outlet, in this report the historical term High Temperature Gas-Cooled Reactor (HTGR) will be used to distinguish the gas-cooled technology described herein from its liquid salt-cooled cousin. Moreover, in this report it is to be understood that the outlet temperature of the helium in an HTGR has an upper limit of 950 degrees C which corresponds to the temperature to which certain alloys are currently being qualified under DOE’s ARC program. Although similar to the HTGR in just about every respect, the Very High Temperature Reactor (VHTR) may have an outlet temperature in excess of 950 degrees C and is therefore farther from commercialization because of the challenges posed to materials exposed to these temperatures. The VHTR is the focus of R&D under the Generation IV program and its specific R&D needs will be included in this report when appropriate for comparison. The distinguishing features of the HTGR are the refractory (TRISO) coated particle fuel, the low-power density, graphite-moderated core, and the high outlet temperature of the inert helium coolant. The low power density and fuel form effectively eliminate the possibility of core melt, even upon a complete loss of coolant pressure and flow. The graphite, which constitutes the bulk of the core volume and mass, provides a large thermal buffer that absorbs fission heat such that thermal transients occur over a timespan of hours or even days. As chemically-inert helium is already a gas, there is no coolant temperature or void feedback on the neutronics and no phase change or corrosion product that could degrade heat transfer. Furthermore, the particle coatings and interstitial graphite retain fission products such that the source terms at the plant boundary remain well below actionable levels under all anticipated nominal and off-normal operating conditions. These attributes enable the reactor to supply process heat to a collocated industrial plant with negligible risk of contamination and minimal dynamic coupling of the facilities (Figure 1). The exceptional retentive properties of coated particle fuel in a graphite matrix were first demonstrated in the DRAGON reactor, a European research facility that began operation in 1964.

  8. Baseline Concept Description of a Small Modular High Temperature Reactor

    SciTech Connect (OSTI)

    Gougar, Hans D.

    2014-10-01

    The objective of this report is to provide a description of generic small modular high temperature reactors (herein denoted as an smHTR), summarize their distinguishing attributes, and lay out the research and development (R&D) required for commercialization. The generic concepts rely heavily on the modular high temperature gas-cooled reactor designs developed in the 1980s which were never built but for which pre-licensing or certification activities were conducted. The concept matured more recently under the Next Generation Nuclear Plant (NGNP) project, specifically in the areas of fuel and material qualification, methods development, and licensing. As all vendor-specific designs proposed under NGNP were all both ‘small’ or medium-sized and ‘modular’ by International Atomic Energy Agency (IAEA) and Department of Energy (DOE) standards, the technical attributes, challenges, and R&D needs identified, addressed, and documented under NGNP are valid and appropriate in the context of Small Modular Reactor (SMR) applications. Although the term High Temperature Reactor (HTR) is commonly used to denote graphite-moderated, thermal spectrum reactors with coolant temperatures in excess of 650oC at the core outlet, in this report the historical term High Temperature Gas-Cooled Reactor (HTGR) will be used to distinguish the gas-cooled technology described herein from its liquid salt-cooled cousin. Moreover, in this report it is to be understood that the outlet temperature of the helium in an HTGR has an upper limit of 950 degrees C which corresponds to the temperature to which certain alloys are currently being qualified under DOE’s ARC program. Although similar to the HTGR in just about every respect, the Very High Temperature Reactor (VHTR) may have an outlet temperature in excess of 950 degrees C and is therefore farther from commercialization because of the challenges posed to materials exposed to these temperatures. The VHTR is the focus of R&D under the Generation IV program and its specific R&D needs will be included in this report when appropriate for comparison. The distinguishing features of the HTGR are the refractory (TRISO) coated particle fuel, the low-power density, graphite-moderated core, and the high outlet temperature of the inert helium coolant. The low power density and fuel form effectively eliminate the possibility of core melt, even upon a complete loss of coolant pressure and flow. The graphite, which constitutes the bulk of the core volume and mass, provides a large thermal buffer that absorbs fission heat such that thermal transients occur over a timespan of hours or even days. As chemically-inert helium is already a gas, there is no coolant temperature or void feedback on the neutronics and no phase change or corrosion product that could degrade heat transfer. Furthermore, the particle coatings and interstitial graphite retain fission products such that the source terms at the plant boundary remain well below actionable levels under all anticipated nominal and off-normal operating conditions. These attributes enable the reactor to supply process heat to a collocated industrial plant with negligible risk of contamination and minimal dynamic coupling of the facilities (Figure 1). The exceptional retentive properties of coated particle fuel in a graphite matrix were first demonstrated in the DRAGON reactor, a European research facility that began operation in 1964.

  9. Bio-Fuel Production Assisted with High Temperature Steam Electrolysis

    SciTech Connect (OSTI)

    Grant Hawkes; James O'Brien; Michael McKellar

    2012-06-01

    Two hybrid energy processes that enable production of synthetic liquid fuels that are compatible with the existing conventional liquid transportation fuels infrastructure are presented. Using biomass as a renewable carbon source, and supplemental hydrogen from high-temperature steam electrolysis (HTSE), these two hybrid energy processes have the potential to provide a significant alternative petroleum source that could reduce dependence on imported oil. The first process discusses a hydropyrolysis unit with hydrogen addition from HTSE. Non-food biomass is pyrolyzed and converted to pyrolysis oil. The pyrolysis oil is upgraded with hydrogen addition from HTSE. This addition of hydrogen deoxygenates the pyrolysis oil and increases the pH to a tolerable level for transportation. The final product is synthetic crude that could then be transported to a refinery and input into the already used transportation fuel infrastructure. The second process discusses a process named Bio-Syntrolysis. The Bio-Syntrolysis process combines hydrogen from HTSE with CO from an oxygen-blown biomass gasifier that yields syngas to be used as a feedstock for synthesis of liquid synthetic crude. Conversion of syngas to liquid synthetic crude, using a biomass-based carbon source, expands the application of renewable energy beyond the grid to include transportation fuels. It can also contribute to grid stability associated with non-dispatchable power generation. The use of supplemental hydrogen from HTSE enables greater than 90% utilization of the biomass carbon content which is about 2.5 times higher than carbon utilization associated with traditional cellulosic ethanol production. If the electrical power source needed for HTSE is based on nuclear or renewable energy, the process is carbon neutral. INL has demonstrated improved biomass processing prior to gasification. Recyclable biomass in the form of crop residue or energy crops would serve as the feedstock for this process. A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to heat steam for the hydrogen production via the high temperature steam electrolysis process. Oxygen produced form the electrolysis process is used to control the oxidation rate in the oxygen-blown biomass gasifier.

  10. Enhanced High Temperature Performance of NOx Reduction Catalyst Materials

    SciTech Connect (OSTI)

    Gao, Feng; Kim, Do Heui; Luo, Jinyong; Muntean, George G.; Peden, Charles HF; Howden, Ken; Currier, Neal; Kamasamudram, Krishna; Kumar, Ashok; Li, Junhui; Stafford, Randy; Yezerets, Aleksey; Castagnola, Mario; Chen, Hai Ying; Hess, Howard ..

    2012-12-31

    Two primary NOx after-treatment technologies have been recognized as the most promising approaches for meeting stringent NOx emission standards for diesel vehicles within the Environmental Protection Agency’s (EPA’s) 2007/2010 mandated limits, NOx Storage Reduction (NSR) and NH3 selective catalytic reduction (SCR); both are, in fact being commercialized for this application. However, in looking forward to 2015 and beyond with expected more stringent regulations, the continued viability of the NSR technology for controlling NOx emissions from lean-burn engines such as diesels will require at least two specific, significant and inter-related improvements. First, it is important to reduce system costs by, for example, minimizing the precious metal content while maintaining, even improving, performance and long-term stability. A second critical need for future NSR systems, as well as for NH3 SCR, will be significantly improved higher and lower temperature performance and stability. Furthermore, these critically needed improvements will contribute significantly to minimizing the impacts to fuel economy of incorporating these after-treatment technologies on lean-burn vehicles. To meet these objectives will require, at a minimum an improved scientific understanding of the following things: i) the various roles for the precious and coinage metals used in these catalysts; ii) the mechanisms for these various roles; iii) the effects of high temperatures on the active metal performance in their various roles; iv) mechanisms for higher temperature NOx storage performance for modified and/or alternative storage materials; v) the interactions between the precious metals and the storage materials in both optimum NOx storage performance and long term stability; vi) the sulfur adsorption and regeneration mechanisms for NOx reduction materials; vii) materials degradation mechanisms in CHA-based NH3 SCR catalysts. The objective of this CRADA project between PNNL and Cummins, Inc. is to develop a fundamental understanding of the above-listed issues. Model catalysts that are based on literature formulations are the focus of the work being carried out at PNNL. In addition, the performance and stability of more realistic high temperature NSR catalysts, supplied by JM, are being studied in order to provide baseline data for the model catalysts that are, again, based on formulations described in the open literature. For this short summary, we will primarily highlight representative results from our recent studies of the stability of candidate high temperature NSR materials.

  11. A SYSTEMATIC SURVEY OF HIGH-TEMPERATURE EMISSION IN SOLAR ACTIVE REGIONS

    SciTech Connect (OSTI)

    Warren, Harry P. [Space Science Division, Naval Research Laboratory, Washington, DC 20375 (United States); Winebarger, Amy R. [NASA Marshall Space Flight Center, VP 62, Huntsville, AL 35812 (United States); Brooks, David H. [College of Science, George Mason University, 4400 University Drive, Fairfax, VA 22030 (United States)

    2012-11-10

    The recent analysis of observations taken with the EUV Imaging Spectrometer and X-Ray Telescope instruments on Hinode suggests that well-constrained measurements of the temperature distribution in solar active regions can finally be made. Such measurements are critical for constraining theories of coronal heating. Past analysis, however, has suffered from limited sample sizes and large uncertainties at temperatures between 5 and 10 MK. Here we present a systematic study of the differential emission measure distribution in 15 active region cores. We focus on measurements in the 'inter-moss' region, that is, the region between the loop footpoints, where the observations are easier to interpret. To reduce the uncertainties at the highest temperatures we present a new method for isolating the Fe XVIII emission in the AIA/SDO 94 A channel. The resulting differential emission measure distributions confirm our previous analysis showing that the temperature distribution in an active region core is often strongly peaked near 4 MK. We characterize the properties of the emission distribution as a function of the total unsigned magnetic flux. We find that the amount of high-temperature emission in the active region core is correlated with the total unsigned magnetic flux, while the emission at lower temperatures, in contrast, is inversely related. These results provide compelling evidence that high-temperature active region emission is often close to equilibrium, although weaker active regions may be dominated by evolving million degree loops in the core.

  12. Possible Origin of Improved High Temperature Performance of Hydrothermally Aged Cu/Beta Zeolite Catalysts

    SciTech Connect (OSTI)

    Peden, Charles HF; Kwak, Ja Hun; Burton, Sarah D.; Tonkyn, Russell G.; Kim, Do Heui; Lee, Jong H.; Jen, H. W.; Cavattaio, Giovanni; Cheng, Yisun; Lambert, Christine

    2012-04-30

    The hydrothermal stability of Cu/beta NH3 SCR catalysts are explored here. In particular, this paper focuses on the interesting ability of this catalyst to maintain and even enhance high-temperature performance for the "standard" SCR reaction after modest (900 °C, 2 hours) hydrothermal aging. Characterization of the fresh and aged catalysts was performed with an aim to identify possible catalytic phases responsible for the enhanced high temperature performance. XRD, TEM and 27Al NMR all showed that the hydrothermally aging conditions used here resulted in almost complete loss of the beta zeolite structure between 1 and 2 hours aging. While the 27Al NMR spectra of 2 and 10 hour hydrothermally-aged catalysts showed significant loss of a peak associated with tetrahedrally-coordinated Al species, no new spectral features were evident. Two model catalysts, suggested by these characterization data as possible mimics of the catalytic phase formed during hydrothermal aging of Cu/beta, were prepared and tested for their performance in the "standard" SCR and NH3 oxidation reactions. The similarity in their reactivity compared to the 2 hour hydrothermally-aged Cu/beta catalyst suggests possible routes for preparing multi-component catalysts that may have wider temperature windows for optimum performance than those provided by current Cu/zeolite catalysts.

  13. Damping in high-temperature superconducting levitation systems

    DOE Patents [OSTI]

    Hull, John R.

    2009-12-15

    Methods and apparatuses for improved damping in high-temperature superconducting levitation systems are disclosed. A superconducting element (e.g., a stator) generating a magnetic field and a magnet (e.g. a rotor) supported by the magnetic field are provided such that the superconducting element is supported relative to a ground state with damped motion substantially perpendicular to the support of the magnetic field on the magnet. Applying this, a cryostat housing the superconducting bearing may be coupled to the ground state with high damping but low radial stiffness, such that its resonant frequency is less than that of the superconducting bearing. The damping of the cryostat may be substantially transferred to the levitated magnetic rotor, thus, providing damping without affecting the rotational loss, as can be derived applying coupled harmonic oscillator theory in rotor dynamics. Thus, damping can be provided to a levitated object, without substantially affecting the rotational loss.

  14. 9 Cr-- 1 Mo steel material for high temperature application

    DOE Patents [OSTI]

    Jablonski, Paul D; Alman, David; Dogan, Omer; Holcomb, Gordon; Cowen, Christopher

    2012-11-27

    One or more embodiments relates to a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650.degree. C. The 9 Cr-1 Mo steel has a tempered martensite microstructure and is comprised of both large (0.5-3 .mu.m) primary titanium carbides and small (5-50 nm) secondary titanium carbides in a ratio of. from about 1:1.5 to about 1.5:1. The 9 Cr-1 Mo steel may be fabricated using exemplary austenizing, rapid cooling, and tempering steps without subsequent hot working requirements. The 9 Cr-1 Mo steel exhibits improvements in total mass gain, yield strength, and time-to-rupture over ASTM P91 and ASTM P92 at the temperature and time conditions examined.

  15. Design of High Field Solenoids made of High Temperature Superconductors

    SciTech Connect (OSTI)

    Bartalesi, Antonio; /Pisa U.

    2010-12-01

    This thesis starts from the analytical mechanical analysis of a superconducting solenoid, loaded by self generated Lorentz forces. Also, a finite element model is proposed and verified with the analytical results. To study the anisotropic behavior of a coil made by layers of superconductor and insulation, a finite element meso-mechanic model is proposed and designed. The resulting material properties are then used in the main solenoid analysis. In parallel, design work is performed as well: an existing Insert Test Facility (ITF) is adapted and structurally verified to support a coil made of YBa{sub 2}Cu{sub 3}O{sub 7}, a High Temperature Superconductor (HTS). Finally, a technological winding process was proposed and the required tooling is designed.

  16. Cobalt doped lanthanum chromite material suitable for high temperature use

    DOE Patents [OSTI]

    Ruka, R.J.

    1986-12-23

    A high temperature, solid electrolyte electrochemical cell, subject to thermal cycling temperatures of between about 25 C and about 1,200 C, capable of electronic interconnection to at least one other electrochemical cell and capable of operating in an environment containing oxygen and a fuel, is made; where the cell has a first and second electrode with solid electrolyte between them, where an improved interconnect material is applied along a portion of a supporting electrode; where the interconnect is made of a chemically modified lanthanum chromite, containing cobalt as the important additive, which interconnect allows for adjustment of the thermal expansion of the interconnect material to more nearly match that of other cell components, such as zirconia electrolyte, and is stable in oxygen containing atmospheres such as air and in fuel environments. 2 figs.

  17. High temperature concrete composites containing organosiloxane crosslinked copolymers

    DOE Patents [OSTI]

    Zeldin, Arkady (Rego Park, NY); Carciello, Neal (Patchogue, NY); Kukacka, Lawrence (Port Jefferson, NY); Fontana, Jack (Shoreham, NY)

    1980-01-01

    This invention relates to high temperature polymer concrete composites comprising about 10-30% by weight of a liquid monomer mixture consisting essentially of an organosiloxane polymer crosslinked with an olefinically unsaturated monomer selected from the group consisting of styrene, methyl methacrylate, trimethylolpropane trimethacrylate, triallyl cyanurate, n-phenylmalimide, divinyl benzene and mixtures theroef; and about 70-90% by weight of an inert inorganic filler system containing silica sand and preferably a member selected from the group consisting of portland cement, Fe.sub.2 O.sub.3, carbon black and mixtures thereof; and optionally a free radical initiator such as di-tert-butyl peroxide, azobisisobutyronitrile, benzoyl peroxide, lauryl peroxide and other organic peroxides to initiate crosspolymerization of the monomer mixture in the presence of the inorganic filler.

  18. High Temperature Chemical Kinetic Combustion Modeling of Lightly Methylated Alkanes

    SciTech Connect (OSTI)

    Sarathy, S M; Westbrook, C K; Pitz, W J; Mehl, M

    2011-03-01

    Conventional petroleum jet and diesel fuels, as well as alternative Fischer-Tropsch (FT) fuels and hydrotreated renewable jet (HRJ) fuels, contain high molecular weight lightly branched alkanes (i.e., methylalkanes) and straight chain alkanes (n-alkanes). Improving the combustion of these fuels in practical applications requires a fundamental understanding of large hydrocarbon combustion chemistry. This research project presents a detailed high temperature chemical kinetic mechanism for n-octane and three lightly branched isomers octane (i.e., 2-methylheptane, 3-methylheptane, and 2,5-dimethylhexane). The model is validated against experimental data from a variety of fundamental combustion devices. This new model is used to show how the location and number of methyl branches affects fuel reactivity including laminar flame speed and species formation.

  19. Materials for the scavanging of hydrogen at high temperatures

    DOE Patents [OSTI]

    Shepodd, Timothy J. (330 Thrasher Ave., Livermore, Alameda County, CA 94550); Phillip, Bradley L. (20976 Fairmount Blvd., Shaker Heights, Cuyahoga County, OH 44120)

    1997-01-01

    A hydrogen getter composition comprising a double or triple bonded hydrocarbon with a high melting point useful for removing hydrogen gas, to partial pressures below 0.01 torr, from enclosed spaces and particularly from vessels used for transporting or containing fluids at elevated temperatures. The hydrogen getter compostions disclosed herein and their reaction products will neither melt nor char at temperatures in excess of 100C. They possess significant advantages over conventional hydrogen getters, namely low risk of fire or explosion, no requirement for high temperature activation or operation, the ability to absorb hydrogen even in the presence of contaminants such as water, water vapor, common atmospheric gases and oil mists and are designed to be disposed within the confines of the apparatus. These getter materials can be mixed with binders, such as fluropolymers, which permit the getter material to be fabricated into useful shapes and/or impart desirable properties such as water repellency or impermeability to various gases.

  20. Materials for the scavanging of hydrogen at high temperatures

    DOE Patents [OSTI]

    Shepodd, Timothy J. (Livermore, CA); Phillip, Bradley L. (Shaker Heights, OH)

    1997-01-01

    A hydrogen getter composition comprising a double or triple bonded hydrocarbon with a high melting point useful for removing hydrogen gas, to partial pressures below 0.01 torr, from enclosed spaces and particularly from vessels used for transporting or containing fluids at elevated temperatures. The hydrogen getter compositions disclosed herein and their reaction products will neither melt nor char at temperatures in excess of 100.degree. C. They possess significant advantages over conventional hydrogen getters, namely low risk of fire or explosion, no requirement for high temperature activation or operation, the ability to absorb hydrogen even in the presence of contaminants such as water, water vapor, common atmospheric gases and oil mists and are designed to be disposed within the confines of the apparatus. These getter materials can be mixed with binders, such as fluropolymers, which permit the getter material to be fabricated into useful shapes and/or impart desirable properties such as water repellency or impermeability to various gases.

  1. Controlled Chemistry Helium High Temperature Materials Test Loop

    SciTech Connect (OSTI)

    Richard N. WRight

    2005-08-01

    A system to test aging and environmental effects in flowing helium with impurity content representative of the Next Generation Nuclear Plant (NGNP) has been designed and assembled. The system will be used to expose microstructure analysis coupons and mechanical test specimens for up to 5,000 hours in helium containing potentially oxidizing or carburizing impurities controlled to parts per million levels. Impurity levels in the flowing helium are controlled through a feedback mechanism based on gas chromatography measurements of the gas chemistry at the inlet and exit from a high temperature retort containing the test materials. Initial testing will focus on determining the nature and extent of combined aging and environmental effects on microstructure and elevated temperature mechanical properties of alloys proposed for structural applications in the NGNP, including Inconel 617 and Haynes 230.

  2. Theory of intertwined orders in high temperature superconductors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fradkin, Eduardo; Tranquada, John M.; Kivelson, Steven A.

    2015-03-26

    The electronic phase diagrams of many highly correlated systems, and in particular the cuprate high temperature superconductors, are complex, with many different phases appearing with similar—sometimes identical—ordering temperatures even as material properties, such as a dopant concentration, are varied over wide ranges. This complexity is sometimes referred to as “competing orders.” However, since the relation is intimate, and can even lead to the existence of new phases of matter such as the putative “pair-density-wave,” the general relation is better thought of in terms of “intertwined orders.” We selectively analyze some of the experiments in the cuprates which suggest that essentialmore »aspects of the physics are reflected in the intertwining of multiple orders—not just in the nature of each order by itself. We also summarize and critique several theoretical ideas concerning the origin and implications of this complexity.« less

  3. Theory of intertwined orders in high temperature superconductors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fradkin, Eduardo [Univ. of Illinois at Urbana-Champaign, Urbana, IL (United States); Tranquada, John M. [Brookhaven National Lab. (BNL), Upton, NY (United States); Kivelson, Steven A. [Stanford Univ., Stanford, CA (United States)

    2015-05-01

    The electronic phase diagrams of many highly correlated systems, and in particular the cuprate high temperature superconductors, are complex, with many different phases appearing with similar—sometimes identical—ordering temperatures even as material properties, such as a dopant concentration, are varied over wide ranges. This complexity is sometimes referred to as “competing orders.” However, since the relation is intimate, and can even lead to the existence of new phases of matter such as the putative “pair-density-wave,” the general relation is better thought of in terms of “intertwined orders.” We selectively analyze some of the experiments in the cuprates which suggest that essential aspects of the physics are reflected in the intertwining of multiple orders—not just in the nature of each order by itself. We also summarize and critique several theoretical ideas concerning the origin and implications of this complexity.

  4. High performance internal reforming unit for high temperature fuel cells

    DOE Patents [OSTI]

    Ma, Zhiwen (Sandy Hook, CT); Venkataraman, Ramakrishnan (New Milford, CT); Novacco, Lawrence J. (Brookfield, CT)

    2008-10-07

    A fuel reformer having an enclosure with first and second opposing surfaces, a sidewall connecting the first and second opposing surfaces and an inlet port and an outlet port in the sidewall. A plate assembly supporting a catalyst and baffles are also disposed in the enclosure. A main baffle extends into the enclosure from a point of the sidewall between the inlet and outlet ports. The main baffle cooperates with the enclosure and the plate assembly to establish a path for the flow of fuel gas through the reformer from the inlet port to the outlet port. At least a first directing baffle extends in the enclosure from one of the sidewall and the main baffle and cooperates with the plate assembly and the enclosure to alter the gas flow path. Desired graded catalyst loading pattern has been defined for optimized thermal management for the internal reforming high temperature fuel cells so as to achieve high cell performance.

  5. Shock-induced synthesis of high temperature superconducting materials

    DOE Patents [OSTI]

    Ginley, D.S.; Graham, R.A.; Morosin, B.; Venturini, E.L.

    1987-06-18

    It has now been determined that the unique features of the high pressure shock method, especially the shock-induced chemical synthesis technique, are fully applicable to high temperature superconducting materials. Extraordinarily high yields are achievable in accordance with this invention, e.g., generally in the range from about 20% to about 99%, often in the range from about 50% to about 90%, lower and higher yields, of course, also being possible. The method of this invention involves the application of a controlled high pressure shock compression pulse which can be produced in any conventional manner, e.g., by detonation of a high explosive material, the impact of a high speed projectile or the effect of intense pulsed radiation sources such as lasers or electron beams. Examples and a discussion are presented.

  6. Remote high-temperature insulatorless heat-flux gauge

    DOE Patents [OSTI]

    Noel, Bruce W. (Espanola, NM)

    1993-01-01

    A remote optical heat-flux gauge for use in extremely high temperature environments is described. This application is possible because of the use of thermographic phosphors as the sensing media, and the omission of the need for an intervening layer of insulator between phosphor layers. The gauge has no electrical leads, but is interrogated with ultraviolet or laser light. The luminescence emitted by the two phosphor layers, which is indicative of the temperature of the layers, is collected and analyzed in order to determine the heat flux incident on the surface being investigated. The two layers of thermographic phosphor must be of different materials to assure that the spectral lines collected will be distinguishable. Spatial heat-flux measurements can be made by scanning the light across the surface of the gauge.

  7. Remote high-temperature insulatorless heat-flux gauge

    DOE Patents [OSTI]

    Noel, B.W.

    1993-12-28

    A remote optical heat-flux gauge for use in extremely high temperature environments is described. This application is possible because of the use of thermographic phosphors as the sensing media, and the omission of the need for an intervening layer of insulator between phosphor layers. The gauge has no electrical leads, but is interrogated with ultraviolet or laser light. The luminescence emitted by the two phosphor layers, which is indicative of the temperature of the layers, is collected and analyzed in order to determine the heat flux incident on the surface being investigated. The two layers of thermographic phosphor must be of different materials to assure that the spectral lines collected will be distinguishable. Spatial heat-flux measurements can be made by scanning the light across the surface of the gauge. 3 figures.

  8. Apparatus and method for high temperature viscosity and temperature measurements

    DOE Patents [OSTI]

    Balasubramaniam, Krishnan (Mississippi State, MS); Shah, Vimal (Houston, TX); Costley, R. Daniel (Mississippi State, MS); Singh, Jagdish P. (Mississippi State, MS)

    2001-01-01

    A probe for measuring the viscosity and/or temperature of high temperature liquids, such as molten metals, glass and similar materials comprises a rod which is an acoustical waveguide through which a transducer emits an ultrasonic signal through one end of the probe, and which is reflected from (a) a notch or slit or an interface between two materials of the probe and (b) from the other end of the probe which is in contact with the hot liquid or hot melt, and is detected by the same transducer at the signal emission end. To avoid the harmful effects of introducing a thermally conductive heat sink into the melt, the probe is made of relatively thermally insulative (non-heat-conductive) refractory material. The time between signal emission and reflection, and the amplitude of reflections, are compared against calibration curves to obtain temperature and viscosity values.

  9. Cobalt doped lanthanum chromite material suitable for high temperature use

    DOE Patents [OSTI]

    Ruka, Roswell J. (Churchill, PA)

    1986-01-01

    A high temperature, solid electrolyte electrochemical cell, subject to thermal cycling temperatures of between about 25.degree. C. and about 1200.degree. C., capable of electronic interconnection to at least one other electrochemical cell and capable of operating in an environment containing oxygen and a fuel, is made; where the cell has a first and second electrode with solid electrolyte between them, where an improved interconnect material is applied along a portion of a supporting electrode; where the interconnect is made of a chemically modified lanthanum chromite, containing cobalt as the important additive, which interconnect allows for adjustment of the thermal expansion of the interconnect material to more nearly match that of other cell components, such as zirconia electrolyte, and is stable in oxygen containing atmospheres such as air and in fuel environments.

  10. Flexible high-temperature pH probe

    DOE Patents [OSTI]

    Bielawski, John C. (Scotia, NY); Outwater, John O. (Cambridge, MA); Halbfinger, George P. (Schenectady, NY)

    2003-04-22

    A flexible pH probe device is provided for use in hot water and other high temperature environments up to about 590.degree. F. The pH probe includes a flexible, inert tubular probe member, an oxygen anion conducting, solid state electrolyte plug located at the distal end of the tubular member, oxide powder disposed at the distal end of the tubular member; a metal wire extending along the tubular member and having a distal end in contact with the oxide powder so as to form therewith an internal reference electrode; and a compression fitting forming a pressure boundary seal around a portion of the tubular member remote from the distal end thereof. Preferably, the tubular member is made of polytetrafluoroethylene, and the solid state electrolyte plug is made of stabilized zirconia. The flexibility of the probe member enables placement of the electrode into the area of interest, including around corners, into confined areas and the like.

  11. High temperature seal for joining ceramics and metal alloys

    DOE Patents [OSTI]

    Maiya, P. Subraya (Darien, IL); Picciolo, John J. (Lockport, IL); Emerson, James E. (Plainfield, IL); Dusek, Joseph T. (Lombard, IL); Balachandran, Uthamalingam (Hinsdale, IL)

    1998-01-01

    For a combination of a membrane of SrFeCo.sub.0.5 O.sub.x and an Inconel alloy, a high-temperature seal is formed between the membrane and the alloy. The seal is interposed between the alloy and the membrane, and is a fritted compound of Sr oxide and boric oxide and a fritted compound of Sr, Fe and Co oxides. The fritted compound of SrFeCo.sub.0.50 O.sub.x is present in the range of from about 30 to 70 percent by weight of the total sealant material and the fritted compound of Sr oxide and boric oxide has a mole ratio of 2 moles of the Sr oxide for each mole of boric oxide. A method of sealing a ceramic to an Inconel metal alloy is also disclosed.

  12. High-temperature Hydrogen Permeation in Nickel Alloys

    SciTech Connect (OSTI)

    P. Calderoni; M. Ebner; R. Pawelko

    2010-10-01

    In gas cooled Very High Temperature Reactor concepts, tritium is produced as a tertiary fission product and by activation of graphite core contaminants, such as lithium; of the helium isotope, He-3, that is naturally present in the He gas coolant; and the boron in the B4C burnable poison. Because of its high mobility at the reactor outlet temperatures, tritium poses a risk of permeating through the walls of the intermediate heat exchanger (IHX) or steam generator (SG) systems, potentially contaminating the environment and in particular the hydrogen product when the reactor heat is utilized in connection with a hydrogen generation plant. An experiment to measure tritium permeation in structural materials at temperatures up to 1000 C has been constructed at the Idaho National Laboratory Safety and Tritium Applied Research (STAR) facility within the Next Generation Nuclear Plant program. The design is based on two counter flowing helium loops to represent heat exchanger conditions and was optimized to allow control of the materials surface condition and the investigation of the effects of thermal fatigue. In the ongoing campaign three nickel alloys are being considered because of their high-temperature creep properties, alloy 617, 800H and 230. This paper introduces the general issues related to tritium in the on-going assessment of gas cooled VHTR systems fission product transport and outlines the planned research activities in this area; outlines the features and capabilities of the experimental facility being operated at INL; presents and discusses the initial results of hydrogen permeability measurements in two of the selected alloys and compares them with the available database from previous studies.

  13. PROCEEDINGS, Thirty-Sixth Workshop on Geothermal Reservoir Engineering Stanford University, Stanford, California, January 31 -February 2, 2011

    E-Print Network [OSTI]

    Stanford University

    reservoirs are characterized by high temperatures and saline formation waters. Figure 1: Regions of potential1 PROCEEDINGS, Thirty-Sixth Workshop on Geothermal Reservoir Engineering Stanford University and to characterize the various fluid- material surface interactions in an EGS. These interactions were described

  14. Status of Norris Reservoir

    SciTech Connect (OSTI)

    Not Available

    1990-09-01

    This is one in a series of reports prepared by the Tennessee Valley Authority (TVA) for those interested in the conditions of TVA reservoirs. This overview of Norris Reservoir summarizes reservoir and watershed characteristics, reservoir uses, conditions that impair reservoir uses, water quality and aquatic biological conditions, and activities of reservoir management agencies. This information was extracted from the most up-to-date publications and data available, and from interviews with water resource professionals in various federal, state, and local agencies, and in public and private water supply and wastewater treatment facilities. 14 refs., 3 figs.

  15. Cryogenic Heat Pipe for Cooling High Temperature Superconductors with Application to

    E-Print Network [OSTI]

    Cryogenic Heat Pipe for Cooling High Temperature Superconductors with Application;#12;Cryogenic Heat Pipe for Cooling High Temperature Superconductors with Application to Electromagnetic Superconductors with Application to Electromagnetic Formation Flight Satellites by Daniel W. Kwon Submitted

  16. Experimental investigation of sand consolidation using high-temperature alkaline solution 

    E-Print Network [OSTI]

    Moreno Romero, Fidel Enrique

    2000-01-01

    An experimental study was conducted to better understand the sand consolidation process under high-temperature alkaline solution. Wilmington Tar sand samples were successfully consolidated in the laboratory using high-temperature (250-260?C...

  17. High Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Presentation. Project objectives: Design, demonstrate, and qualify high-temperature high pressure zonal isolation devices compatible with the high temperature downhole Enhanced Geothermal Systems (EGS) environment.

  18. New Polymeric Proton Conductors for Water-free and High-temperature Fuel Cells

    Broader source: Energy.gov [DOE]

    Presentation on New Polymeric Proton Conductors for Water-free and High-temperature Fuel Cells to the High Temperature Membrane Working Group Meeting held in Arlington, Virginia, May 26,2005.

  19. CF8C PLus: A New Cast Stainless Steel for High-Temperature Diesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CF8C PLus: A New Cast Stainless Steel for High-Temperature Diesel Exhaust Components CF8C PLus: A New Cast Stainless Steel for High-Temperature Diesel Exhaust Components...

  20. High Temperature/Low Humidity Polymer Electrolytes Derived from Ionic Liquids

    Broader source: Energy.gov [DOE]

    Presentation on High Temperature/Low Humidity Polymer Electrolytes Derived from Ionic Liquids to the High Temperature Membrane Working Group Meeting held in Arlington, Virginia, May 26,2005.

  1. Membrane Development for Medium and High Temperature PEMFC in Europe (Presentation)

    Broader source: Energy.gov [DOE]

    Presented at the High Temperature Membrane Working Group Meeting (HTMWG) held October 10, 2007 in Washington, D.C.

  2. Performance and Reliability of Bonded Interfaces for High-Temperature Packaging (Presentation)

    SciTech Connect (OSTI)

    Devoto, D.

    2014-06-01

    This presentation reviews the status of the performance and reliability of bonded interfaces for high-temperature packaging.

  3. Anomalous deformation twinning in fcc metals at high temperatures Tanushree Sinha and Yashashree Kulkarnia)

    E-Print Network [OSTI]

    Kulkarni, Yashashree

    of nanotwinned metals, especially at high temperatures. Recent studies by Shute et al.18 and Saldana et al.19

  4. NREL Particle Receiver Will Enable High-Temperature CSP (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-08-01

    Near-blackbody enclosed particle receiver can support high-temperature thermal energy storage and high-efficiency power cycles.

  5. High-Temperature Air-Cooled Power Electronics Thermal Design (Presentation)

    SciTech Connect (OSTI)

    Waye, S.

    2014-06-01

    This presentation discusses the status of research at NREL on high temperature air-cooled power electronics thermal design.

  6. High-Temperature Circuit Boards for Use in Geothermal Well Monitoring Applications

    Broader source: Energy.gov [DOE]

    Project objective: Develop and demonstrate high-temperature; multilayer electronic circuits capable of sustained operation at 300? C.

  7. Low and high Temperature Dual Thermoelectric Generation Waste Heat Recovery System for Light-Duty Vehicles

    Broader source: Energy.gov [DOE]

    Developing a low and high temperature dual thermoelectric generation waste heat recovery system for light-duty vehicles.

  8. Advancement of High Temperature Black Liquor Gasification Technology

    SciTech Connect (OSTI)

    Craig Brown; Ingvar Landalv; Ragnar Stare; Jerry Yuan; Nikolai DeMartini; Nasser Ashgriz

    2008-03-31

    Weyerhaeuser operates the world's only commercial high-temperature black liquor gasifier at its pulp mill in New Bern, NC. The unit was started-up in December 1996 and currently processes about 15% of the mill's black liquor. Weyerhaeuser, Chemrec AB (the gasifier technology developer), and the U.S. Department of Energy recognized that the long-term, continuous operation of the New Bern gasifier offered a unique opportunity to advance the state of high temperature black liquor gasification toward the commercial-scale pressurized O2-blown gasification technology needed as a foundation for the Forest Products Bio-Refinery of the future. Weyerhaeuser along with its subcontracting partners submitted a proposal in response to the 2004 joint USDOE and USDA solicitation - 'Biomass Research and Development Initiative'. The Weyerhaeuser project 'Advancement of High Temperature Black Liquor Gasification' was awarded USDOE Cooperative Agreement DE-FC26-04NT42259 in November 2004. The overall goal of the DOE sponsored project was to utilize the Chemrec{trademark} black liquor gasification facility at New Bern as a test bed for advancing the development status of molten phase black liquor gasification. In particular, project tasks were directed at improvements to process performance and reliability. The effort featured the development and validation of advanced CFD modeling tools and the application of these tools to direct burner technology modifications. The project also focused on gaining a fundamental understanding and developing practical solutions to address condensate and green liquor scaling issues, and process integration issues related to gasifier dregs and product gas scrubbing. The Project was conducted in two phases with a review point between the phases. Weyerhaeuser pulled together a team of collaborators to undertake these tasks. Chemrec AB, the technology supplier, was intimately involved in most tasks, and focused primarily on the design, specification and procurement of facility upgrades. Chemrec AB is also operating a pressurized, O2-blown gasifier pilot facility in Piteaa, Sweden. There was an exchange of knowledge with the pressurized projects including utilization of the experimental results from facilities in Piteaa, Sweden. Resources at the Georgia Tech Research Corporation (GTRC, a.k.a., the Institute of Paper Science and Technology) were employed primarily to conduct the fundamental investigations on scaling and plugging mechanisms and characterization of green liquor dregs. The project also tapped GTRC expertise in the development of the critical underlying black liquor gasification rate subroutines employed in the CFD code. The actual CFD code development and application was undertaken by Process Simulation, Ltd (PSL) and Simulent, Ltd. PSL focused on the overall integrated gasifier CFD code, while Simulent focused on modeling the black liquor nozzle and description of the black liquor spray. For nozzle development and testing Chemrec collaborated with ETC (Energy Technology Centre) in Piteae utilizing their test facility for nozzle spray investigation. GTI (Gas Technology Institute), Des Plains, IL supported the team with advanced gas analysis equipment during the gasifier test period in June 2005.

  9. Characterization of Composite Cores for High Temperature-Low Sag (HTLS)

    E-Print Network [OSTI]

    Characterization of Composite Cores for High Temperature-Low Sag (HTLS) Conductors Final Project/University Cooperative Research Center since 1996 PSERC #12;Characterization of Composite Cores for High Temperature project T-33 titled "Characterization of Composite Cores for High Temperature-Low Sag (HTLS) Conductors

  10. Test-Theory Correlation Study for an Ultra High Temperature Thrust Magnetic Bearing 

    E-Print Network [OSTI]

    Desireddy, Vijesh R.

    2010-01-14

    1000 lb-f of axial thrust load, when rotating at high speed, in a high temperature environment of 1000 0F. This high temperature magnetic bearing system would be used in high performance, high speed and high temperature applications like space vehicles...

  11. Method of manufacturing a high temperature superconductor with improved transport properties

    DOE Patents [OSTI]

    Balachandran, Uthamalingam (Hinsdale, IL); Siegel, Richard W. (Hinsdale, IL); Askew, Thomas R. (Kalamazoo, MI)

    2001-01-01

    A method of preparing a high temperature superconductor. A method of preparing a superconductor includes providing a powdered high temperature superconductor and a nanophase paramagnetic material. These components are combined to form a solid compacted mass with the paramagnetic material disposed on the grain boundaries of the polycrystaline high temperature superconductor.

  12. SiC Field-Effect Devices Operating at High Temperature RUBY N. GHOSH13

    E-Print Network [OSTI]

    Ghosh, Ruby N.

    by monitoring the adhesion of the metal gates during high-temperature thermal cycling. A schematic of ourSiC Field-Effect Devices Operating at High Temperature RUBY N. GHOSH1­3 and PETER TOBIAS2 1 250°C. The MOS device operation in chemically corrosive, high-temperature environments places

  13. High Temperature Calcination - MACT Upgrade Equipment Pilot Plant Test

    SciTech Connect (OSTI)

    Richard D. Boardman; B. H. O'Brien; N. R. Soelberg; S. O. Bates; R. A. Wood; C. St. Michel

    2004-02-01

    About one million gallons of acidic, hazardous, and radioactive sodium-bearing waste are stored in stainless steel tanks at the Idaho Nuclear Technology and Engineering Center (INTEC), which is a major operating facility of the Idaho National Engineering and Environmental Laboratory. Calcination at high-temperature conditions (600 C, with alumina nitrate and calcium nitrate chemical addition to the feed) is one of four options currently being considered by the Department of Energy for treatment of the remaining tank wastes. If calcination is selected for future processing of the sodium-bearing waste, it will be necessary to install new off-gas control equipment in the New Waste Calcining Facility (NWCF) to comply with the Maximum Achievable Control Technology (MACT) standards for hazardous waste combustors and incinerators. This will require, as a minimum, installing a carbon bed to reduce mercury emissions from their current level of up to 7,500 to <45 {micro}g/dscm, and a staged combustor to reduce unburned kerosene fuel in the off-gas discharge to <100 ppm CO and <10 ppm hydrocarbons. The staged combustor will also reduce NOx concentrations of about 35,000 ppm by 90-95%. A pilot-plant calcination test was completed in a newly constructed 15-cm diameter calciner vessel. The pilot-plant facility was equipped with a prototype MACT off-gas control system, including a highly efficient cyclone separator and off-gas quench/venturi scrubber for particulate removal, a staged combustor for unburned hydrocarbon and NOx destruction, and a packed activated carbon bed for mercury removal and residual chloride capture. Pilot-plant testing was performed during a 50-hour system operability test January 14-16, followed by a 100-hour high-temperature calcination pilot-plant calcination run January 19-23. Two flowsheet blends were tested: a 50-hour test with an aluminum-to-alkali metal molar ratio (AAR) of 2.25, and a 50-hour test with an AAR of 1.75. Results of the testing indicate that sodium-bearing waste can be successfully calcined at 600 C with an AAR of 1.75. Unburned hydrocarbons are reduced to less than 10 ppm (7% O2, dry basis), with >90% reduction of NOx emissions. Mercury removal by the carbon bed reached 99.99%, surpassing the control efficiency needed to meet MACT emissions standards. No deleterious impacts on the carbon bed were observed during the tests. The test results imply that upgrading the NWCF calciner with a more efficient cyclone separator and the proposed MACT equipment can process the remaining tanks wastes in 3 years or less, and comply with the MACT standards.

  14. High Temperature Variable Conductance Heat Pipes for Radioisotope Stirling Systems

    SciTech Connect (OSTI)

    Tarau, Calin; Walker, Kara L.; Anderson, William G.

    2009-03-16

    In a Stirling radioisotope system, heat must continually be removed from the GPHS modules, to maintain the GPHS modules and surrounding insulation at acceptable temperatures. Normally, the Stirling converter provides this cooling. If the Stirling engine stops in the current system, the insulation is designed to spoil, preventing damage to the GPHS, but also ending the mission. An alkali-metal Variable Conductance Heat Pipe (VCHP) is under development to allow multiple stops and restarts of the Stirling engine. The status of the ongoing effort in developing this technology is presented in this paper. An earlier, preliminary design had a radiator outside the Advanced Stirling Radioisotope Generator (ASRG) casing, used NaK as the working fluid, and had the reservoir located on the cold side adapter flange. The revised design has an internal radiator inside the casing, with the reservoir embedded inside the insulation. A large set of advantages are offered by this new design. In addition to reducing the overall size and mass of the VCHP, simplicity, compactness and easiness in assembling the VCHP with the ASRG are significantly enhanced. Also, the permanently elevated temperatures of the entire VCHP allows the change of the working fluid from a binary compound (NaK) to single compound (Na). The latter, by its properties, allows higher performance and further mass reduction of the system. Preliminary design and analysis shows an acceptable peak temperature of the ASRG case of 140 deg. C while the heat losses caused by the addition of the VCHP are 1.8 W.

  15. Survival of charged rho condensation at high temperature and density

    E-Print Network [OSTI]

    Liu, Hao; Huang, Mei

    2015-01-01

    The charged vector $\\rho$ mesons in the presence of external magnetic fields at finite temperature $T$ and chemical potential $\\mu$ have been investigated in the framework of the Nambu--Jona-Lasinio model. We compute the masses of charged $\\rho$ mesons numerically as a function of the magnetic field for different values of temperature and chemical potential. The self-energy of the $\\rho$ meson contains the quark-loop contribution, i.e. the leading order contribution in $1/N_c$ expansion. The charged $\\rho$ meson mass decreases with the magnetic field and drops to zero at a critical magnetic field $eB_c$, which means that the charged vector meson condensation, i.e. the electromagnetic superconductor can be induced above the critical magnetic field. Surprisingly, it is found that the charged $\\rho$ condensation can even survive at high temperature and density. At zero temperature, the critical magnetic field just increases slightly with the chemical potential, which indicates that the charged $\\rho$ condensatio...

  16. Pressure Resistance Welding of High Temperature Metallic Materials

    SciTech Connect (OSTI)

    N. Jerred; L. Zirker; I. Charit; J. Cole; M. Frary; D. Butt; M. Meyer; K. L. Murty

    2010-10-01

    Pressure Resistance Welding (PRW) is a solid state joining process used for various high temperature metallic materials (Oxide dispersion strengthened alloys of MA957, MA754; martensitic alloy HT-9, tungsten etc.) for advanced nuclear reactor applications. A new PRW machine has been installed at the Center for Advanced Energy Studies (CAES) in Idaho Falls for conducting joining research for nuclear applications. The key emphasis has been on understanding processing-microstructure-property relationships. Initial studies have shown that sound joints can be made between dissimilar materials such as MA957 alloy cladding tubes and HT-9 end plugs, and MA754 and HT-9 coupons. Limited burst testing of MA957/HT-9 joints carried out at various pressures up to 400oC has shown encouraging results in that the joint regions do not develop any cracking. Similar joint strength observations have also been made by performing simple bend tests. Detailed microstructural studies using SEM/EBSD tools and fatigue crack growth studies of MA754/HT-9 joints are ongoing.

  17. Power efficiency for very high temperature solar thermal cavity receivers

    DOE Patents [OSTI]

    McDougal, Allan R. (LaCanada-Flintridge, CA); Hale, Robert R. (Upland, CA)

    1984-01-01

    This invention is an improved solar energy cavity receiver for exposing materials and components to high temperatures. The receiver includes a housing having an internal reflective surface defining a cavity and having an inlet for admitting solar radiation thereto. A photothermal absorber is positioned in the cavity to receive radiation from the inlet. A reflective baffle is positioned between the absorber and the inlet to severely restrict the re-radiation of energy through the inlet. The front surface of the baffle defines a narrow annulus with the internal reflective surface of the housing. The front surface of the baffle is contoured to reflect incoming radiation onto the internal surface of the housing, from which it is reflected through the annulus and onto the front surface of the absorber. The back surface of the baffle intercepts infrared radiation from the front of the absorber. With this arrangement, a high percentage of the solar power input is retained in the cavity; thus, high internal temperatures are attained.

  18. Materials for the scavenging of hydrogen at high temperatures

    DOE Patents [OSTI]

    Shepodd, T.J.; Phillip, B.L.

    1997-04-29

    A hydrogen getter composition is described comprising a double or triple bonded hydrocarbon with a high melting point useful for removing hydrogen gas, to partial pressures below 0.01 torr, from enclosed spaces and particularly from vessels used for transporting or containing fluids at elevated temperatures. The hydrogen getter compositions disclosed herein and their reaction products will neither melt nor char at temperatures in excess of 100C. They possess significant advantages over conventional hydrogen getters, namely low risk of fire or explosion, no requirement for high temperature activation or operation, the ability to absorb hydrogen even in the presence of contaminants such as water, water vapor, common atmospheric gases and oil mists and are designed to be disposed within the confines of the apparatus. These getter materials can be mixed with binders, such as fluoropolymers, which permit the getter material to be fabricated into useful shapes and/or impart desirable properties such as water repellency or impermeability to various gases. 7 figs.

  19. Materials for the scavenging of hydrogen at high temperatures

    DOE Patents [OSTI]

    Shepodd, T.J.; Phillip, B.L.

    1997-12-30

    A hydrogen getter composition is described comprising a double or triple bonded hydrocarbon with a high melting point useful for removing hydrogen gas, to partial pressures below 0.01 torr, from enclosed spaces and particularly from vessels used for transporting or containing fluids at elevated temperatures. The hydrogen getter compositions disclosed herein and their reaction products will neither melt nor char at temperatures in excess of 100 C. They possess significant advantages over conventional hydrogen getters, namely low risk of fire or explosion, no requirement for high temperature activation or operation, the ability to absorb hydrogen even in the presence of contaminants such as water, water vapor, common atmospheric gases and oil mists and are designed to be disposed within the confines of the apparatus. These getter materials can be mixed with binders, such as fluoropolymers, which permit the getter material to be fabricated into useful shapes and/or impart desirable properties such as water repellency or impermeability to various gases. 7 figs.

  20. Advancing the Technology Base for High Temperature Hydrogen Membranes

    SciTech Connect (OSTI)

    Dye, Robert C.; Moss, Thomas S.

    1997-12-31

    High purity hydrogen is a critical component for at least two major industrial processes: 1) the refining of conventional steels and raw pig iron into low carbon steels and high purity iron used for high performance magnets in motors, generators, alternators, transformers, and etc.; and 2) refining metallurgical grade silicon to the high- purity, polycrystalline silicon used in fabricating single crystal silicon wafers for semiconductor manufacturing. In the process of producing low carbon iron products, CO and CO2 impurities prevent efficient removal of the carbon already in the raw iron. In the refining of metallurgical grade silicon, the presence of any impurity above the part-per- million level prevents the ultimate fabrication of the large scale single crystals that are essential to the semiconductor device. In a lesser magnitude role, high quality hydrogen is used in a variety of other processes, including specialty metals refining (e.g., iridium, osmium, palladium, platinum, and ruthenium) and R{ampersand}D in areas such as organic synthesis and development of certain types of fuel cells. In all of these applications, a high-temperature hydrogen membrane can provide a method for achieving a very high purity level of hydrogen in a manner that is more economical and/or more rugged than existing techniques.

  1. Ultra high temperature ceramics for hypersonic vehicle applications.

    SciTech Connect (OSTI)

    Tandon, Rajan; Dumm, Hans Peter; Corral, Erica L.; Loehman, Ronald E.; Kotula, Paul Gabriel

    2006-01-01

    HfB{sub 2} and ZrB{sub 2} are of interest for thermal protection materials because of favorable thermal stability, mechanical properties, and oxidation resistance. We have made dense diboride ceramics with 2 to 20 % SiC by hot pressing at 2000 C and 5000 psi. High-resolution transmission electron microscopy (TEM) shows very thin grain boundary phases that suggest liquid phase sintering. Fracture toughness measurements give RT values of 4 to 6 MPam{sup 1/2}. Four-pt flexure strengths measured in air up to 1450 C were as high as 450-500 MPa. Thermal diffusivities were measured to 2000 C for ZrB{sub 2} and HfB{sub 2} ceramics with SiC contents from 2 to 20%. Thermal conductivities were calculated from thermal diffusivities and measured heat capacities. Thermal diffusivities were modeled using different two-phase composite models. These materials exhibit excellent high temperature properties and are attractive for further development for thermal protection systems.

  2. Polymer nanocomposites for high-temperature composite repair

    SciTech Connect (OSTI)

    Sheng, Xia

    2008-12-01

    A novel repair agent for resin-injection repair of advanced high temperature composites was developed and characterized. The repair agent was based on bisphenol E cyanate ester (BECy) and reinforced with alumina nanoparticles. To ensure good dispersion and compatibility with the BECy matrix in nanocomposites, the alumina nanoparticles were functionalized with silanes. The BECy nanocomposites, containing bare and functionalized alumina nanoparticles, were prepared and evaluated for their thermal, mechanical, rheological, and viscoelastic properties. The monomer of BECy has an extremely low viscosity at ambient temperature, which is good for processability. The cured BECy polymer is a highly cross-linked network with excellent thermal mechanical properties, with a high glass transition temperature (T{sub g}) of 270 C and decomposition temperature above 350 C. The incorporation of alumina nanoparticles enhances the mechanical and rheological properties of the BECy nanocomposites. Additionally, the alumina nanoparticles are shown to catalyze the cure of BECy. Characterization of the nanocomposites included dynamic mechanical analysis, differential scanning calorimetry, thermogravimetric analysis, rheological and rheokinetic evaluation, and transmission electron microscopy. The experimental results show that the BECy nanocomposite is a good candidate as repair agent for resin-injection repair applications.

  3. Novel Gas Sensors for High-Temperature Fossil Fuel Applications

    SciTech Connect (OSTI)

    Palitha Jayaweera; Francis Tanzella

    2005-03-01

    SRI International (SRI) is developing ceramic-based microsensors to detect exhaust gases such as NO, NO{sub 2}, and CO in advanced combustion and gasification systems under this DOE NETL-sponsored research project. The sensors detect the electrochemical activity of the exhaust gas species on catalytic electrodes attached to a solid state electrolyte and are designed to operate at the high temperatures, elevated pressures, and corrosive environments typical of large power generation exhausts. The sensors can be easily integrated into online monitoring systems for active emission control. The ultimate objective is to develop sensors for multiple gas detection in a single package, along with data acquisition and control software and hardware, so that the information can be used for closed-loop control in novel advanced power generation systems. This report details the Phase I Proof-of-Concept, research activities performed from October 2003 to March 2005. SRI's research work includes synthesis of catalytic materials, sensor design and fabrication, software development, and demonstration of pulse voltammetric analysis of NO, NO{sub 2}, and CO gases on catalytic electrodes.

  4. High Temperature Tolerant Ceramic Composites Having Porous Interphases

    DOE Patents [OSTI]

    Kriven, Waltraud M. (Champaign, IL); Lee, Sang-Jin (Chonnam, KR)

    2005-05-03

    In general, this invention relates to a ceramic composite exhibiting enhanced toughness and decreased brittleness, and to a process of preparing the ceramic composite. The ceramic composite comprises a first matrix that includes a first ceramic material, preferably selected from the group including alumina (Al2O3), mullite (3Al2O3.2SiO2), yttrium aluminate garnet (YAG), yttria stabilized zirconia (YSZ), celsian (BaAl2Si2O8) and nickel aluminate (NiAl2O4). The ceramic composite also includes a porous interphase region that includes a substantially non-sinterable material. The non-sinterable material can be selected to include, for example, alumina platelets. The platelets lie in random 3-D orientation and provide a debonding mechanism, which is independent of temperature in chemically compatible matrices. The non-sinterable material induces constrained sintering of a ceramic powder resulting in permanent porosity in the interphase region. For high temperature properties, addition of a sinterable ceramic powder to the non-sinterable material provides sufficiently weak debonding interphases. The ceramic composite can be provided in a variety of forms including a laminate, a fibrous monolith, and a fiber-reinforced ceramic matrix. In the laminated systems, intimate mixing of strong versus tough microstructures were tailored by alternating various matrix-to-interphase thickness ratios to provide the bimodal laminate.

  5. Metal Hydrides for High-Temperature Power Generation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ronnebro, Ewa; Whyatt, Greg A.; Powell, Michael R.; Westman, Matthew P.; Zheng, Feng; Fang, Zhigang Zak

    2015-08-10

    Metal hydrides can be utilized for hydrogen storage and for thermal energy storage (TES) applications. By using TES with solar technologies, heat can be stored from sun energy to be used later which enables continuous power generation. We are developing a TES technology based on a dual-bed metal hydride system, which has a high-temperature (HT) metal hydride operating reversibly at 600-800°C to generate heat as well as a low-temperature (LT) hydride near room temperature that is used for hydrogen storage during sun hours until there is a need to produce electricity, such as during night time, a cloudy day, ormore »during peak hours. We proceeded from selecting a high-energy density, low-cost HT-hydride based on performance characterization on gram size samples, to scale-up to kilogram quantities and design, fabrication and testing of a 1.5kWh, 200kWh/m3 bench-scale TES prototype based on a HT-bed of titanium hydride and a hydrogen gas storage instead of a LT-hydride. COMSOL Multiphysics was used to make performance predictions for cylindrical hydride beds with varying diameters and thermal conductivities. Based on experimental and modeling results, a bench-scale prototype was designed and fabricated and we successfully showed feasibility to meet or exceed all performance targets.« less

  6. Reservoir Characterization Research Laboratory

    E-Print Network [OSTI]

    Texas at Austin, University of

    Reservoir Characterization Research Laboratory for Carbonate Studies Executive Summary for 2014 Outcrop and Subsurface Characterization of Carbonate Reservoirs for Improved Recovery of Remaining/Al 0.00 0.02 0.04 Eagle Ford Fm #12;#12; Reservoir Characterization Research Laboratory Research Plans

  7. Novel High Temperature Materials for In-Situ Sensing Devices

    SciTech Connect (OSTI)

    Florian Solzbacher; Anil Virkar; Loren Rieth; Srinivasan Kannan; Xiaoxin Chen; Hannwelm Steinebach

    2009-12-31

    The overriding goal of this project was to develop gas sensor materials and systems compatible with operation at temperatures from 500 to 700 C. Gas sensors operating at these temperatures would be compatible with placement in fossil-energy exhaust streams close to the combustion chamber, and therefore have advantages for process regulation, and feedback for emissions controls. The three thrusts of our work included investigating thin film gas sensor materials based on metal oxide materials and electroceramic materials, and also development of microhotplate devices to support the gas sensing films. The metal oxide materials NiO, In{sub 2}O{sub 3}, and Ga{sub 2}O{sub 3} were investigated for their sensitivity to H{sub 2}, NO{sub x}, and CO{sub 2}, respectively, at high temperatures (T > 500 C), where the sensing properties of these materials have received little attention. New ground was broken in achieving excellent gas sensor responses (>10) for temperatures up to 600 C for NiO and In{sub 2}O{sub 3} materials. The gas sensitivity of these materials was decreasing as temperatures increased above 500 C, which indicates that achieving strong sensitivities with these materials at very high temperatures (T {ge} 650 C) will be a further challenge. The sensitivity, selectivity, stability, and reliability of these materials were investigated across a wide range of deposition conditions, temperatures, film thickness, as using surface active promoter materials. We also proposed to study the electroceramic materials BaZr{sub (1-x)}Y{sub x}O{sub (3-x/2)} and BaCe{sub (2-x)}Ca{sub x}S{sub (4-x/2)} for their ability to detect H{sub 2}O and H{sub 2}S, respectively. This report focuses on the properties and gas sensing characteristics of BaZr{sub (1-x)}Y{sub x}O{sub (3-x/2)} (Y-doped BaZrO{sub 3}), as significant difficulties were encounter in generating BaCe{sub (2-x)}Ca{sub x}S{sub (4-x/2)} sensors. Significant new results were achieved for Y-doped BaZrO{sub 3}, including sensitivities of more than 60 atm{sup -1} for H{sub 2}O vapor at 400 C. These results were achieved despite significant difficulties with a strong Ba deficiency in the deposited films, and difficulties with stress in the targets and films. Ultimately, these films achieved good sensitivity, selectivity, and reliability in our gas sensing tests. The final thrust of our project was to develop microhotpates. We proposed the use of SiC thin films for the heater of the microhotplate, but despite extensive efforts we were not able to secure a reliable source of SiC. An alternative microhotplate architecture using SiO{sub 2} and Si{sub 3}N{sub 4} suspended membrane structures, and a polysilicon heater were developed, which could be fabricate at commercial MEMs foundries. These microhotplates were fabricated at Microtechnology Services Frankfurt (MSF) in Germany. The fabricated heaters were able to achieve temperatures > 600 C using {approx} 0.25 W, and when combined with In{sub 2}O{sub 3} films demonstrated sensor systems with sensor responses up to 50 for 25 ppm NO{sub x}, and time constants of less than 10 s.

  8. Final Scientific Report - "Novel Steels for High Temperature Carburizing"

    SciTech Connect (OSTI)

    McKimpson, Marvin G.; Liu, Tianjun; Maniruzzaman, Md

    2012-07-27

    This program was undertaken to develop a microalloy-modified grade of standard carburizing steel that can successfully exploit the high temperature carburizing capabilities of current commercial low pressure (i.e. 'vacuum') carburizing systems. Such steels can lower the amount of energy required for commercial carburizing operations by reducing the time required for deep-case carburizing operations. The specific technical objective of the work was to demonstrate a carburizing steel composition capable of maintaining a prior austenite grain size no larger than ASTM grain size number 5 after exposure to simulated carburizing conditions of 1050 C for 8 hr. Such thermal exposure should be adequate for producing carburized case depths up to about 2 mm. Such carburizing steels are expected to be attractive for use across a wide range of industries, including the petroleum, chemical, forest products, automotive, mining and industrial equipment industries. They have potential for reducing energy usage during low pressure carburizing by more than 25%, as well as reducing cycle times and process costs substantially. They also have potential for reducing greenhouse gas emissions from existing low pressure carburizing furnaces by more than 25%. High temperature carburizing can be done in most modern low pressure carburizing systems with no additional capital investment. Accordingly, implementing this technology on carburizing furnaces will provide a return on investment significantly greater than 10%. If disseminated throughout the domestic carburizing community, the technology has potential for saving on the order of 23 to 34 trillion BTU/year in industrial energy usage. Under the program, two compositions of microalloyed, coarsening-resistant low alloy carburizing steels were developed, produced and evaluated. After vacuum annealing at 1050oC for 8 hrs and high pressure gas quenching, both steels exhibited a prior austenite ASTM grain size number of 5.0 or finer. For comparison, a control alloy of similar composition but without the microalloy additions exhibited a duplex prior austenite grain size with grains ranging from ASTM grain size 3 down to ASTM grain size 1 after similar processing and thermal exposure. These results confirm the potential for using microalloy additions of Ti, B, Nb, Al, rare earths and/or N for austenite grain size control in Cr-Mo (i.e. 4000-series) low alloy carburizing steels. They also demonstrate that these microalloy additions will not compromise the processability of the steel; all three materials produced under the program could be hot worked readily using normal steel processing protocols. To fully realize the technical and commercial potential of these steels, there is a need to continue development work using larger-scale heats. These larger-scale heats are needed to provide adequate material for fatigue testing of quenched and tempered alloys, to conduct more complete investigations of potential alloy chemistries and to provide additional material for processing studies. It will also be beneficial to carefully review intellectual property issues associated with this family of steels, since existing Japanese patent literature suggests that significant microstructural and/or process characterization work may be needed on new materials to confirm that these materials fall outside existing patent claims.

  9. Status of Wheeler Reservoir

    SciTech Connect (OSTI)

    Not Available

    1990-09-01

    This is one in a series of status reports prepared by the Tennessee Valley Authority (TVA) for those interested in the conditions of TVA reservoirs. This overview of Wheeler Reservoir summarizes reservoir purposes and operation, reservoir and watershed characteristics, reservoir uses and use impairments, and water quality and aquatic biological conditions. The information presented here is from the most recent reports, publications, and original data available. If no recent data were available, historical data were summarized. If data were completely lacking, environmental professionals with special knowledge of the resource were interviewed. 12 refs., 2 figs.

  10. Status of Cherokee Reservoir

    SciTech Connect (OSTI)

    Not Available

    1990-08-01

    This is the first in a series of reports prepared by Tennessee Valley Authority (TVA) for those interested in the conditions of TVA reservoirs. This overviews of Cherokee Reservoir summarizes reservoir and watershed characteristics, reservoir uses and use impairments, water quality and aquatic biological conditions, and activities of reservoir management agencies. This information was extracted from the most current reports, publications, and data available, and interviews with water resource professionals in various Federal, state, and local agencies and in public and private water supply and wastewater treatment facilities. 11 refs., 4 figs., 1 tab.

  11. Amorphous Alloy Membranes for High Temperature Hydrogen Separation

    SciTech Connect (OSTI)

    Coulter, K

    2013-09-30

    At the beginning of this project, thin film amorphous alloy membranes were considered a nascent but promising new technology for industrial-scale hydrogen gas separations from coal- derived syngas. This project used a combination of theoretical modeling, advanced physical vapor deposition fabricating, and laboratory and gasifier testing to develop amorphous alloy membranes that had the potential to meet Department of Energy (DOE) targets in the testing strategies outlined in the NETL Membrane Test Protocol. The project is complete with Southwest Research Institute® (SwRI®), Georgia Institute of Technology (GT), and Western Research Institute (WRI) having all operated independently and concurrently. GT studied the hydrogen transport properties of several amorphous alloys and found that ZrCu and ZrCuTi were the most promising candidates. GT also evaluated the hydrogen transport properties of V, Nb and Ta membranes coated with different transition-metal carbides (TMCs) (TM = Ti, Hf, Zr) catalytic layers by employing first-principles calculations together with statistical mechanics methods and determined that TiC was the most promising material to provide catalytic hydrogen dissociation. SwRI developed magnetron coating techniques to deposit a range of amorphous alloys onto both porous discs and tubular substrates. Unfortunately none of the amorphous alloys could be deposited without pinhole defects that undermined the selectivity of the membranes. WRI tested the thermal properties of the ZrCu and ZrNi alloys and found that under reducing environments the upper temperature limit of operation without recrystallization is ~250 °C. There were four publications generated from this project with two additional manuscripts in progress and six presentations were made at national and international technical conferences. The combination of the pinhole defects and the lack of high temperature stability make the theoretically identified most promising candidate amorphous alloys unsuitable for application as hydrogen separation membranes in coal fire systems.

  12. Multiyear Program Plan for the High Temperature Materials Laboratory

    SciTech Connect (OSTI)

    Arvid E. Pasto

    2000-03-17

    Recently, the U.S. Department of Energy's (DOE) Office of Heavy Vehicle Technologies (OHVT) prepared a Technology Roadmap describing the challenges facing development of higher fuel efficiency, less polluting sport utility vehicles, vans, and commercial trucks. Based on this roadmap, a multiyear program plan (MYPP) was also developed, in which approaches to solving the numerous challenges are enumerated. Additional planning has been performed by DOE and national laboratory staff, on approaches to solving the numerous challenges faced by heavy vehicle system improvements. Workshops and planning documents have been developed concerning advanced aerodynamics, frictional and other parasitic losses, and thermal management. Similarly, the Heavy Vehicle Propulsion Materials Program has developed its own multiyear program plan. The High Temperature Materials Laboratory, a major user facility sponsored by OHVT, has now developed its program plan, described herein. Information was gathered via participation in the development of OHVT's overall Technology Roadmap and MYPP, through personal contacts within the materials-user community, and from attendance at conferences and expositions. Major materials issues for the heavy vehicle industry currently center on trying to increase efficiency of (diesel) engines while at the same time reducing emissions (particularly NO{sub x} and particulates). These requirements dictate the use of increasingly stronger, higher-temperature capable and more corrosion-resistant materials of construction, as well as advanced catalysts, particulate traps, and other pollution-control devices. Exhaust gas recirculation (EGR) is a technique which will certainly be applied to diesel engines in the near future, and its use represents a formidable challenge, as will be described later. Energy-efficient, low cost materials processing methods and surface treatments to improve wear, fracture, and corrosion resistance are also required.

  13. A High Temperature Hermetic Primer and a Variable Spring Tester

    SciTech Connect (OSTI)

    Begeal, D.R.

    1994-05-01

    Percussion primers are used at Sandia to ignite energetic components such as pyrotechnic actuators and thermal batteries. This report describes a High Temperature Hermetic Primer (HTHP) that was developed to replace a previous G16 Percussion Primer Subassembly (Gl6PPS). The ignition mix in these primers is the same as in the discontinued Remington 44G16 (KC1O{sub 3}, SbS{sub 3}, and Ca{sub 2}Si). The HTHP has nearly the same sensitivity as the 44G16 and a significantly lower sensitivity than the G16PPS. In parallel with the HTHP development, we also designed a Variable Spring Tester (VST) to determine percussion primer ignition sensitivity with firing pins that have the same mass as those used in field applications. The tester is capable of accelerating firing pins over a velocity range of 100 to 600 inches per second for pins weighing up to 6 grams. The desired impulse can be preselected with an accuracy of better than {plus_minus}1%. The actual impulse is measured on every shot. The VST was characterized using the WW42Cl primer, as well as with the G16PPS and the HTHP. Compared to data from conventional ball drop testers, we found that ignition sensitivities were lower and there was less scatter in the sensitivity data. Our experiments indicate that ignition sensitivity is not strictly energy dependent, but also depends on the rate of deposition, or firing pin velocity in this case. Development results for the HTHP and Variable Spring Tester are discussed and design details are shown.

  14. Holographic Calculation for Large Interval Rényi Entropy at High Temperature

    E-Print Network [OSTI]

    Bin Chen; Jie-qiang Wu

    2015-06-10

    In this paper, we study the holographic R\\'enyi entropy of a large interval on a circle at high temperature for the two-dimensional CFT dual to pure AdS$_3$ gravity. In the field theory, the R\\'enyi entropy is encoded in the CFT partition function on $n$-sheeted torus connected with each other by a large branch cut. As proposed in 1412.0763, the effective way to read the entropy in the large interval limit is to insert a complete set of state bases of the twist sector at the branch cut. Then the calculation transforms into an expansion of four-point functions in the twist sector with respect to $e^{-\\frac{2\\pi TR}{n}}$. By using the operator product expansion of the twist operators at the branch points, we read the first few terms of the R\\'enyi entropy, including the leading and next-leading contributions in the large central charge limit. Moreover, we show that the leading contribution is actually captured by the twist vacuum module. In this case by the Ward identity the four-point functions can be derived from the correlation function of four twist operators, which is related to double interval entanglement entropy. Holographically, we apply the recipe in 1303.7221 and 1306.4682 to compute the classical R\\'enyi entropy and its 1-loop quantum correction, after imposing a new set of monodromy conditions. The holographic classical result matches exactly with the leading contribution in the field theory up to $e^{-4\\pi TR}$ and $l^6$, while the holographical 1-loop contribution is in exact agreement with next-leading results in field theory up to $e^{-\\frac{6\\pi TR}{n}}$ and $l^4$ as well.

  15. Air Cooling for High Temperature Power Electronics (Presentation)

    SciTech Connect (OSTI)

    Waye, S.; Musselman, M.; King, C.

    2014-09-01

    Current emphasis on developing high-temperature power electronics, including wide-bandgap materials such as silicon carbide and gallium nitride, increases the opportunity for a completely air-cooled inverter at higher powers. This removes the liquid cooling system for the inverter, saving weight and volume on the liquid-to-air heat exchanger, coolant lines, pumps, and coolant, replacing them with just a fan and air supply ducting. We investigate the potential for an air-cooled heat exchanger from a component and systems-level approach to meet specific power and power density targets. A proposed baseline air-cooled heat exchanger design that does not meet those targets was optimized using a parametric computational fluid dynamics analysis, examining the effects of heat exchanger geometry and device location, fixing the device heat dissipation and maximum junction temperature. The CFD results were extrapolated to a full inverter, including casing, capacitor, bus bar, gate driver, and control board component weights and volumes. Surrogate ducting was tested to understand the pressure drop and subsequent system parasitic load. Geometries that met targets with acceptable loads on the system were down-selected for experimentation. Nine baseline configuration modules dissipated the target heat dissipation, but fell below specific power and power density targets. Six optimized configuration modules dissipated the target heat load, exceeding the specific power and power density targets. By maintaining the same 175 degrees C maximum junction temperature, an optimized heat exchanger design and higher device heat fluxes allowed a reduction in the number of modules required, increasing specific power and power density while still maintaining the inverter power.

  16. NOvel Refractory Materials for High Alkali, High Temperature Environments

    SciTech Connect (OSTI)

    Hemrick, J.G.; Griffin, R.

    2011-08-30

    Refractory materials can be limited in their application by many factors including chemical reactions between the service environment and the refractory material, mechanical degradation of the refractory material by the service environment, temperature limitations on the use of a particular refractory material, and the inability to install or repair the refractory material in a cost effective manner or while the vessel was in service. The objective of this project was to address the need for new innovative refractory compositions by developing a family of novel MgO-Al2O3 spinel or other similar magnesia/alumina containing unshaped refractory composition (castables, gunnables, shotcretes, etc) utilizing new aggregate materials, bond systems, protective coatings, and phase formation techniques (in-situ phase formation, altered conversion temperatures, accelerated reactions, etc). This family of refractory compositions would then be tailored for use in high-temperature, highalkaline industrial environments like those found in the aluminum, chemical, forest products, glass, and steel industries. A research team was formed to carry out the proposed work led by Oak Ridge National Laboratory (ORNL) and was comprised of the academic institution Missouri University of Science and Technology (MS&T), and the industrial company MINTEQ International, Inc. (MINTEQ), along with representatives from the aluminum, chemical, glass, and forest products industries. The two goals of this project were to produce novel refractory compositions which will allow for improved energy efficiency and to develop new refractory application techniques which would improve the speed of installation. Also methods of hot installation were sought which would allow for hot repairs and on-line maintenance leading to reduced process downtimes and eliminating the need to cool and reheat process vessels.

  17. Protective interlayer for high temperature solid electrolyte electrochemical cells

    DOE Patents [OSTI]

    Singh, Prabhakar (Export, PA); Vasilow, Theodore R. (Manor, PA); Richards, Von L. (Angola, IN)

    1996-01-01

    The invention comprises of an electrically conducting doped or admixed cerium oxide composition with niobium oxide and/or tantalum oxide for electrochemical devices, characterized by the general formula: Nb.sub.x Ta.sub.y Ce.sub.1-x-y O.sub.2 where x is about 0.0 to 0.05, y is about 0.0 to 0.05, and x+y is about 0.02 to 0.05, and where x is preferably about 0.02 to 0.05 and y is 0, and a method of making the same. This novel composition is particularly applicable in forming a protective interlayer of a high temperature, solid electrolyte electrochemical cell (10), characterized by a first electrode (12); an electrically conductive interlayer (14) of niobium and/or tantalum doped cerium oxide deposited over at least a first portion (R) of the first electrode; an interconnect (16) deposited over the interlayer; a solid electrolyte (18) deposited over a second portion of the first electrode, the first portion being discontinuous from the second portion; and, a second electrode (20) deposited over the solid electrolyte. The interlayer (14) is characterized as being porous and selected from the group consisting of niobium doped cerium oxide, tantalum doped cerium oxide, and niobium and tantalum doped cerium oxide or admixtures of the same. The first electrode (12), an air electrode, is a porous layer of doped lanthanum manganite, the solid electrolyte layer (18) is a dense yttria stabilized zirconium oxide, the interconnect layer (16) is a dense, doped lanthanum chromite, and the second electrode (20), a fuel electrode, is a porous layer of nickel-zirconium oxide cermet. The electrochemical cell (10) can take on a plurality of shapes such as annular, planar, etc. and can be connected to a plurality of electrochemical cells in series and/or in parallel to generate electrical energy.

  18. Development of high temperature superconductors for electric power applications

    SciTech Connect (OSTI)

    Schiff, N. [American Superconductor Corp., Westborough, MA (United States)

    1995-09-01

    The Nobel Prize-winning discovery in 1986 of a new family of superconductors that exhibited the property of no resistance at temperatures more than ten times greater than the traditional low temperature superconductors (LTS) currently used in MRI and high field magnets, made it possible to foresee a new era for the production, transmission and distribution of electrical power. Smaller, more efficient motors, generators, power cables, transformers, inductors, and superconducting magnetic energy storage (SMES) for power quality were applications immediately envisioned for these high temperature superconductors (HTS), promising enhanced capabilities and lower costs. Work also began on new product concepts, such as more effective fault current limiters for both transmission and distribution systems that could protect expensive hardware and avoid the cost of upgrading circuit breakers as system capacity is increased. The interest of industry and utilities has been increased by successful demonstrations of small-scale prototypes. Recent demonstrations include a one meter conductor for an underground transmission cable produced by American Superconductor which carried over 4,200 amps, a 5 hp synchronous motor produced by Reliance Electric Company, magnet systems which generated over 2 Tesla at temperatures over 20 Kelvin (K) by both American Superconductor Corporation (ASC) and Sumitomo Electric Industries. The Department of Energy, under the Superconductivity Partnership Initiative Program (SPI), recently funded four application development projects: a 100 hp HTS motor demonstration, design of a generator rotor, a fault current limiter for distribution systems, and a 30 meter HTS power transmission cable. This paper will review the progress in application development of HTS products. The specific benefits and costs associated with this technology in power applications will be examined.

  19. High Temperature Gas Reactors: Assessment of Applicable Codes and Standards

    SciTech Connect (OSTI)

    McDowell, Bruce K.; Nickolaus, James R.; Mitchell, Mark R.; Swearingen, Gary L.; Pugh, Ray

    2011-10-31

    Current interest expressed by industry in HTGR plants, particularly modular plants with power up to about 600 MW(e) per unit, has prompted NRC to task PNNL with assessing the currently available literature related to codes and standards applicable to HTGR plants, the operating history of past and present HTGR plants, and with evaluating the proposed designs of RPV and associated piping for future plants. Considering these topics in the order they are arranged in the text, first the operational histories of five shut-down and two currently operating HTGR plants are reviewed, leading the authors to conclude that while small, simple prototype HTGR plants operated reliably, some of the larger plants, particularly Fort St. Vrain, had poor availability. Safety and radiological performance of these plants has been considerably better than LWR plants. Petroleum processing plants provide some applicable experience with materials similar to those proposed for HTGR piping and vessels. At least one currently operating plant - HTR-10 - has performed and documented a leak before break analysis that appears to be applicable to proposed future US HTGR designs. Current codes and standards cover some HTGR materials, but not all materials are covered to the high temperatures envisioned for HTGR use. Codes and standards, particularly ASME Codes, are under development for proposed future US HTGR designs. A 'roadmap' document has been prepared for ASME Code development; a new subsection to section III of the ASME Code, ASME BPVC III-5, is scheduled to be published in October 2011. The question of terminology for the cross-duct structure between the RPV and power conversion vessel is discussed, considering the differences in regulatory requirements that apply depending on whether this structure is designated as a 'vessel' or as a 'pipe'. We conclude that designing this component as a 'pipe' is the more appropriate choice, but that the ASME BPVC allows the owner of the facility to select the preferred designation, and that either designation can be acceptable.

  20. Barriers to the Application of High-Temperature Coolants in Hybrid Electric Vehicles

    SciTech Connect (OSTI)

    Staunton, Robert H; Hsu, John S; Starke, Michael R

    2006-09-01

    This study was performed by the Oak Ridge National Laboratory (ORNL) to identify practical approaches, technical barriers, and cost impacts to achieving high-temperature coolant operation for certain traction drive subassemblies and components of hybrid electric vehicles (HEV). HEVs are unique in their need for the cooling of certain dedicated-traction drive subassemblies/components that include the electric motor(s), generators(s), inverter, dc converter (where applicable), and dc-link capacitors. The new coolant system under study would abandon the dedicated 65 C coolant loop, such as used in the Prius, and instead rely on the 105 C engine cooling loop. This assessment is important because automotive manufacturers are interested in utilizing the existing water/glycol engine cooling loop to cool the HEV subassemblies in order to eliminate an additional coolant loop with its associated reliability, space, and cost requirements. In addition, the cooling of power electronic devices, traction motors, and generators is critical in meeting the U.S. Department of Energy (DOE) FreedomCAR and Vehicle Technology (FCVT) goals for power rating, volume, weight, efficiency, reliability, and cost. All of these have been addressed in this study. Because there is high interest by the original equipment manufacturers (OEMs) in reducing manufacturing cost to enhance their competitive standing, the approach taken in this analysis was designed to be a positive 'can-do' approach that would be most successful in demonstrating the potential or opportunity of relying entirely on a high-temperature coolant system. Nevertheless, it proved to be clearly evident that a few formidable technical and cost barriers exist and no effective approach for mitigating the barriers was evident in the near term. Based on comprehensive thermal tests of the Prius reported by ORNL in 2005 [1], the continuous ratings at base speed (1200 rpm) with different coolant temperatures were projected from test data at 900 rpm. They are approximately 15 kW with 103 C coolant and 20 kW with 50 C coolant. To avoid this 25% drop1 in continuous power, design changes for improved heat dissipation and carefully managed changes in allowable thermal limits would be required in the hybrid subsystems. This study is designed to identify the technical barriers that potentially exist in moving to a high-temperature cooling loop prior to addressing the actual detailed design. For operation at a significantly higher coolant temperature, there were component-level issues that had to be addressed in this study. These issues generally pertained to the cost and reliability of existing or near-term components that would be suitable for use with the 105 C coolant. The assessed components include power electronic devices/modules such as diodes and insulated-gate bipolar transistors (IGBTs), inverter-grade high-temperature capacitors, permanent magnets (PM), and motor-grade wire insulation. The need for potentially modifying/resizing subassemblies such as inverters, motors, and heat exchangers was also addressed in the study. In order to obtain pertinent information to assist ORNL researchers address the thermal issues at the component, module, subassembly, and system levels, pre-existing laboratory test data conducted at varying temperatures was analyzed in conjunction with information obtained from technical literature searches and industry sources.

  1. Barriers to the Application of High-Temperature Coolants in Hybrid Electric Vehicles

    SciTech Connect (OSTI)

    Hsu, J.S.; Staunton, M.R.; Starke, M.R.

    2006-09-30

    This study was performed by the Oak Ridge National Laboratory (ORNL) to identify practical approaches, technical barriers, and cost impacts to achieving high-temperature coolant operation for certain traction drive subassemblies and components of hybrid electric vehicles (HEV). HEVs are unique in their need for the cooling of certain dedicated-traction drive subassemblies/components that include the electric motor(s), generators(s), inverter, dc converter (where applicable), and dc-link capacitors. The new coolant system under study would abandon the dedicated 65 C coolant loop, such as used in the Prius, and instead rely on the 105 C engine cooling loop. This assessment is important because automotive manufacturers are interested in utilizing the existing water/glycol engine cooling loop to cool the HEV subassemblies in order to eliminate an additional coolant loop with its associated reliability, space, and cost requirements. In addition, the cooling of power electronic devices, traction motors, and generators is critical in meeting the U.S. Department of Energy (DOE) FreedomCAR and Vehicle Technology (FCVT) goals for power rating, volume, weight, efficiency, reliability, and cost. All of these have been addressed in this study. Because there is high interest by the original equipment manufacturers (OEMs) in reducing manufacturing cost to enhance their competitive standing, the approach taken in this analysis was designed to be a positive 'can-do' approach that would be most successful in demonstrating the potential or opportunity of relying entirely on a high-temperature coolant system. Nevertheless, it proved to be clearly evident that a few formidable technical and cost barriers exist and no effective approach for mitigating the barriers was evident in the near term. Based on comprehensive thermal tests of the Prius reported by ORNL in 2005 [1], the continuous ratings at base speed (1200 rpm) with different coolant temperatures were projected from test data at 900 rpm. They are approximately 15 kW with 103 C coolant and 20 kW with 50 C coolant. To avoid this 25% drop1 in continuous power, design changes for improved heat dissipation and carefully managed changes in allowable thermal limits would be required in the hybrid subsystems. This study is designed to identify the technical barriers that potentially exist in moving to a high-temperature cooling loop prior to addressing the actual detailed design. For operation at a significantly higher coolant temperature, there were component-level issues that had to be addressed in this study. These issues generally pertained to the cost and reliability of existing or near term components that would be suitable for use with the 105 C coolant. The assessed components include power electronic devices/modules such as diodes and insulated-gate bipolar transistors (IGBTs), inverter-grade high-temperature capacitors, permanent magnets (PM), and motor-grade wire insulation. The need for potentially modifying/resizing subassemblies such as inverters, motors, and heat exchangers was also addressed in the study. In order to obtain pertinent information to assist ORNL researchers address the thermal issues at the component, module, subassembly, and system levels, pre-existing laboratory test data conducted at varying temperatures was analyzed in conjunction with information obtained from technical literature searches and industry sources.

  2. Preventing fuel failure for a beyond design basis accident in a fluoride salt cooled high temperature reactor

    E-Print Network [OSTI]

    Minck, Matthew J. (Matthew Joseph)

    2013-01-01

    The fluoride salt-cooled high-temperature reactor (FHR) combines high-temperature coated-particle fuel with a high-temperature salt coolant for a reactor with unique market and safety characteristics. This combination can ...

  3. Direct Utilization of Coal Syngas in High Temperature Fuel Cells

    SciTech Connect (OSTI)

    Celik, Ismail B.

    2014-10-30

    This EPSCoR project had two primary goals: (i) to build infrastructure and work force at WVU to support long-term research in the area of fuel cells and related sciences; (ii) study effects of various impurities found in coal-syngas on performance of Solid Oxide Fuel Cells (SOFC). As detailed in this report the WVU research team has made significant accomplishments in both of these areas. What follows is a brief summary of these accomplishments: State-of-the-art test facilities and diagnostic tools have been built and put into use. These include cell manufacturing, half-cell and full-cell test benches, XPS, XRD, TEM, Raman, EDAX, SEM, EIS, and ESEM equipment, unique in-situ measurement techniques and test benches (Environmental EM, Transient Mass-Spectrometer-MS, and IR Optical Temperature measurements). In addition, computational capabilities have been developed culminating in a multi-scale multi-physics fuel cell simulation code, DREAM-SOFC, as well as a Beowulf cluster with 64 CPU units. We have trained 16 graduate students, 10 postdoctoral fellows, and recruited 4 new young faculty members who have actively participated in the EPSCoR project. All four of these faculty members have already been promoted to the tenured associate professor level. With the help of these faculty and students, we were able to secure 14 research awards/contracts amounting to a total of circa $5.0 Million external funding in closely related areas of research. Using the facilities mentioned above, the effects of PH3, HCl, Cl2, and H2S on cell performance have been studied in detail, mechanisms have been identified, and also remedies have been proposed and demonstrated in the laboratory. For example, it has been determined that PH3 reacts rapidly with Ni to from secondary compounds which may become softer or even melt at high temperature and then induce Ni migration to the surface of the cell changing the material and micro-structural properties of the cell drastically. It is found that the extent of steam and current load accelerate the degradation caused by PH3. A unique filtering technique has been proposed to reduce the effect of PH3. In addition, various cell materials have been proposed to reduce the rate of degradation caused by H2S. Furthermore, a three-dimensional, transient multi-physics model has been formulated to describe primary transport processes and electro-chemical reactions occurring within the cell. This model has been validated using data gathered from accelerated tests. The validated model then has been used to study the degradation rates under a range of operating conditions and impurity levels. This has resulted in a procedure that uses both experiments and simulations to predict the life-time of a cell operating with syngas with known concentration of trace impurities. Finally all the experience and knowledge gained has been disseminated via 39 journal papers and 43 presentations/posters/conference papers.

  4. Nanofluid-based receivers for high-temperature, high-flux direct solar collectors

    E-Print Network [OSTI]

    Lenert, Andrej

    2010-01-01

    Solar power plants with surface receivers have low overall energy conversion efficiencies due to large emissive losses at high temperatures. Alternatively, volumetric receivers promise increased performance because solar ...

  5. Sandia Energy - High-Pressure and High-Temperature Neutron Reflectomet...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High-Temperature Neutron Reflectometry Cell for Solid-Fluid Interface Studies Home Carbon Capture & Storage Climate News News & Events Carbon Capture Carbon Storage High-Pressure...

  6. Project Profile: A Novel Storage Method for CSP Plants Allowing Operation at High Temperature

    Broader source: Energy.gov [DOE]

    City College of New York (CCNY), under the Thermal Storage FOA, is developing and testing a novel thermal storage method that allows operation at very high temperatures.

  7. High Temperature Membrane Working Group, Minutes of Meeting on September 14, 2006

    Broader source: Energy.gov [DOE]

    These meeting minutes provide information about the High Temperature Membrane Working Group meeting on September 14, 2006 in San Francisco, Ca.

  8. A High-Temperature Fuel Cell to Provide On-Site Process Reducing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    nitrogen gas often provides a reducing atmosphere for these processes. High-temperature fuel cells directly convert the chemical energy in its fuel to electricity, with water,...

  9. High-Temperature Motor Windings for Downhole Pumps Used in Geothermal Energy Production

    Broader source: Energy.gov [DOE]

    Project objective: Develop and demonstrate high-temperature ESP motor windings for use in Enhanced Geothermal Systems and operation at 300?C.

  10. Investigation of Opportunities for High-Temperature Solar Energy in the Aluminum Industry

    SciTech Connect (OSTI)

    Murray, J.

    2006-05-01

    This report gives the conclusions drawn from a study of the potential application of high-temperature solar process heat for production of aluminum.

  11. A Discussion of Testing Protocols and LANL's Contribution to High Temperature Membranes

    Broader source: Energy.gov [DOE]

    Summary of LANL?s testing protocol work presented to the High Temperature Membrane Working Group Meeting, Orlando FL, October 17, 2003

  12. New Membranes for High Temperature Proton Exchange Membrane Fuel Cells Based on Heteropoly Acids

    Broader source: Energy.gov [DOE]

    "Summary of Colorado School of Mines heteropolyacid research presented to the High Temperature Membrane Working Group Meeting, Orlando FL, October 17, 2003 "

  13. Thermal-stress modeling of an optical microphone at high temperature...

    Office of Scientific and Technical Information (OSTI)

    Thermal-stress modeling of an optical microphone at high temperature. Citation Details In-Document Search Title: Thermal-stress modeling of an optical microphone at high...

  14. High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1984-06-19

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  15. High-Temperature Components for Rankine-Cycle-Based Waste Heat...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Components for Rankine-Cycle-Based Waste Heat Recovery Systems on Combustion Engines High-Temperature Components for Rankine-Cycle-Based Waste Heat Recovery Systems on Combustion...

  16. Concept of a thermonuclear reactor based on gravity retention of high-temperature plasma

    E-Print Network [OSTI]

    S. I. Fisenko; I. S. Fisenko

    2007-05-27

    In the present paper the realization of the obtained results in relation to the dense high- temperature plasma of multivalent ions including experimental data interpretation is discussed.

  17. High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures

    DOE Patents [OSTI]

    Young, J.E.; Jalan, V.M.

    1982-07-07

    A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

  18. Screening in (2+1)D pure gauge theory at high temperatures

    E-Print Network [OSTI]

    E. Laermann; C. Legeland; B. Petersson

    1995-01-23

    We compute heavy quark potentials in pure gauge $SU(3)$ at high temperatures in $2+1$ dimensions and confront them with expectations emerging from perturbative calculations.

  19. Reservoir CharacterizationReservoir Characterization Research LaboratoryResearch Laboratory

    E-Print Network [OSTI]

    Texas at Austin, University of

    Reservoir CharacterizationReservoir Characterization Research LaboratoryResearch Laboratory at Austin Austin, Texas 78713Austin, Texas 78713--89248924 #12;Reservoir Characterization Research Laboratory for Carbonate Studies Research Plans for 2012 Outcrop and Subsurface Characterization of Carbonate

  20. Hydraulic Fracture Stimulation and Acid Treatment of Well Baca 20; Geothermal Reservoir Well Stimulation Program

    SciTech Connect (OSTI)

    None

    1983-07-01

    The U.S. Department of Energy-sponsored Geothermal Reservoir Well Stimulation Program was initiated in February 1979 to pursue industry interest in geothermal well stimulation work and to develop technical expertise in areas directly related to geothermal well stimulation activities. This report provides an overview of the two experiments conducted in the high-temperature reservoir in Baca, New Mexico. The report discusses resource and reservoir properties, and provides a description of the stimulation experiment, a description of the treatment evaluation, and a summary of the experiment costs. (DJE-2005)

  1. 1 6 High-Temperature-High-Pressure Diffractometry R. J. Angel*

    E-Print Network [OSTI]

    Downs, Robert T.

    1 6 High- Temperature-High-Pressure Diffractometry R. J. Angel* Bayerisches Geoinstitut 20015 *Present address: Department ofGeological Sciences, Virginia Tech, Blacksburg, VA 24061 INTRODUCTION Effective techniques for conducting high-pressure and high-temperature single-crystal X

  2. Diamond anvil cell for spectroscopic investigation of materials at high temperature, high pressure and shear

    DOE Patents [OSTI]

    Westerfield, Curtis L. (Espanola, NM); Morris, John S. (Los Alamos, NM); Agnew, Stephen F. (Los Alamos, NM)

    1997-01-01

    Diamond anvil cell for spectroscopic investigation of materials at high temperature, high pressure and shear. A cell is described which, in combination with Fourier transform IR spectroscopy, permits the spectroscopic investigation of boundary layers under conditions of high temperature, high pressure and shear.

  3. Diamond anvil cell for spectroscopic investigation of materials at high temperature, high pressure and shear

    DOE Patents [OSTI]

    Westerfield, C.L.; Morris, J.S.; Agnew, S.F.

    1997-01-14

    Diamond anvil cell is described for spectroscopic investigation of materials at high temperature, high pressure and shear. A cell is described which, in combination with Fourier transform IR spectroscopy, permits the spectroscopic investigation of boundary layers under conditions of high temperature, high pressure and shear. 4 figs.

  4. technology offer SandTES -High Temperature Sand Thermal Energy Storage

    E-Print Network [OSTI]

    Szmolyan, Peter

    technology offer SandTES - High Temperature Sand Thermal Energy Storage key words: High Temperature Energy Storage | Fluidized Bed | Sand | The invention consists of a fluidized bed with internal heat together with Dr. Eisl of ENRAG GmbH. Background Thermal energy storage (TES) systems are essential

  5. Aalborg Universitet Design and Control of High Temperature PEM Fuel Cell Systems using Methanol

    E-Print Network [OSTI]

    Berning, Torsten

    Aalborg Universitet Design and Control of High Temperature PEM Fuel Cell Systems using Methanol, S. L., & Justesen, K. K. (2013). Design and Control of High Temperature PEM Fuel Cell Systems using FDFC 2013 Proceedings: Fundamentals & Development of Fuel Cells. European Institute for Energy Research

  6. Aalborg Universitet Development of a 400 W High Temperature PEM Fuel Cell Power Pack -Modelling and

    E-Print Network [OSTI]

    Berning, Torsten

    Aalborg Universitet Development of a 400 W High Temperature PEM Fuel Cell Power Pack - Modelling., Korsgaard, A., Nielsen, M. P., & Kær, S. K. (2006). Development of a 400 W High Temperature PEM Fuel Cell Power Pack - Modelling and System Control. Poster session presented at Fuel Cell Seminar 2006 Conference

  7. Aalborg Universitet Performance and endurance of a high temperature PEM fuel cell operated on methanol

    E-Print Network [OSTI]

    Berning, Torsten

    Aalborg Universitet Performance and endurance of a high temperature PEM fuel cell operated temperature PEM fuel cell operated on methanol reformate. International Journal of Hydrogen Energy, 39 from vbn.aau.dk on: juli 05, 2015 #12;Performance and endurance of a high temperature PEM fuel cell

  8. Infrared emission spectroscopy of CO2 at high temperature. Part I: Experimental setup and source

    E-Print Network [OSTI]

    Boyer, Edmond

    Infrared emission spectroscopy of CO2 at high temperature. Part I: Experimental setup and source measurement, tube effects, CO2 infrared radiation 1. Introduction The knowledge of very high temperature for instance that the IR emission of the CO2 molecule remains predominant at temperatures as high as 4000 K [1

  9. Effects of high-temperature anneals and 60 Co gamma-ray irradiation

    E-Print Network [OSTI]

    Schroder, Dieter K.

    Effects of high-temperature anneals and 60 Co gamma-ray irradiation on strained silicon on insulator was exposed to high-temperature annealing and high-dose 60 Co gamma -ray irradiation to study at a rate of approximately 5 105 °C/s for millisecond duration anneals. For the irradiation experiments

  10. Intermediate coating layer for high temperature rubbing seals for rotary regenerators

    DOE Patents [OSTI]

    Schienle, James L. (Phoenix, AZ); Strangman, Thomas E. (Phoenix, AZ)

    1995-01-01

    A metallic regenerator seal is provided having multi-layer coating comprising a NiCrAlY bond layer, a yttria stabilized zirconia (YSZ) intermediate layer, and a ceramic high temperature solid lubricant surface layer comprising zinc oxide, calcium fluoride, and tin oxide. Because of the YSZ intermediate layer, the coating is thermodynamically stable and resists swelling at high temperatures.

  11. A High Temperature Liquid Plasma Model of the Sun

    E-Print Network [OSTI]

    Robitaille, P M

    2004-01-01

    In this work, a liquid model of the Sun is presented wherein the entire solar mass is viewed as a high density/high energy plasma. This model challenges our current understanding of the densities associated with the internal layers of the Sun, advocating a relatively constant density, almost independent of radial position. The incompressible nature of liquids is advanced to prevent solar collapse from gravitational forces. The liquid plasma model of the Sun is a non-equilibrium approach, where nuclear reactions are free to occur throughout the solar mass. The primary means of addressing internal heat transfer are convection and conduction. As a result of the convective prodesses on the solar surface, the liquid model brings into question the established temperature of the solar photosphere by highlighting a violation of Kirchhoff's law of thermal emission. Along these lines, the model emphasizes that radiative emission is a surface phenomenon. Strong evidence is provided that the Sun is a high density/high en...

  12. Studies of nonlinear electrodynamics of high-temperature superconductors

    SciTech Connect (OSTI)

    Lam, Quan-Chiu H.

    1991-08-01

    Nonlinear electrodynamics of high-{Tc} superconductors are studied both theoretically and experimentally. For powdered samples, a novel model is presented in which the metallographically observed superconducting grains in the powder are modeled as superconducting current loops of various areas with weak links. Surprising harmonic generation behavior in an arc field, H{sub 1} cos({omega}t), is predicted by the model; the power at high harmonics show sharp dips almost periodic in a superposing dc magnetic field, revealing flux quantization in the prototype loops in the model. Such oscillation of the harmonic power in dc magnetic field P{sub nf}(H{sub dc}), is indeed experimentally observed in powdered YBa{sub 2}Cu{sub 3}O{sub 7}. Other experimental aspects also agree with model predictions. For bulk sintered cylindrical samples, a generalized critical state model is presented. In this model, the nonlinear electrodynamics are due to flux-pinning, somewhat similar to low-temperature type-II superconductors, but with a more generalized critical current densities' dependence on magnetic field -- J{sub c}(H){approximately}H{sub local}{sup -{beta}}, with {beta} being an adjustable parameter. Experiments in ac and dc magnetic fields on a sintered cylindrical rod of YBa{sub 2}Cu{sub 3}O{sub 7} yield unambiguous evidence of independent inter- and intragranular contributions to the complex harmonic permeability {tilde {mu}}{sub n} = {mu}{prime}{sub n} -i{mu}{double prime}{sub n}. Temperature- dependence measurements reveal that, while the intragranular supercurrents disappear at {Tc}{ge}91.2 K, the intergranular supercurrents disappear at T{ge}86.6 K. This result is, to our knowledge, the first clear measurement of the phase-locking temperature of the 3-D matrix formed by YBa{sub 2}Cu{sub 3}O{sub 7} grains, which are in electrical contact with one another through weak links.

  13. Studies of nonlinear electrodynamics of high-temperature superconductors

    SciTech Connect (OSTI)

    Lam, Quan-Chiu H.

    1991-08-01

    Nonlinear electrodynamics of high-{Tc} superconductors are studied both theoretically and experimentally. For powdered samples, a novel model is presented in which the metallographically observed superconducting grains in the powder are modeled as superconducting current loops of various areas with weak links. Surprising harmonic generation behavior in an arc field, H{sub 1} cos({omega}t), is predicted by the model; the power at high harmonics show sharp dips almost periodic in a superposing dc magnetic field, revealing flux quantization in the prototype loops in the model. Such oscillation of the harmonic power in dc magnetic field P{sub nf}(H{sub dc}), is indeed experimentally observed in powdered YBa{sub 2}Cu{sub 3}O{sub 7}. Other experimental aspects also agree with model predictions. For bulk sintered cylindrical samples, a generalized critical state model is presented. In this model, the nonlinear electrodynamics are due to flux-pinning, somewhat similar to low-temperature type-II superconductors, but with a more generalized critical current densities` dependence on magnetic field -- J{sub c}(H){approximately}H{sub local}{sup -{beta}}, with {beta} being an adjustable parameter. Experiments in ac and dc magnetic fields on a sintered cylindrical rod of YBa{sub 2}Cu{sub 3}O{sub 7} yield unambiguous evidence of independent inter- and intragranular contributions to the complex harmonic permeability {tilde {mu}}{sub n} = {mu}{prime}{sub n} -i{mu}{double_prime}{sub n}. Temperature- dependence measurements reveal that, while the intragranular supercurrents disappear at {Tc}{ge}91.2 K, the intergranular supercurrents disappear at T{ge}86.6 K. This result is, to our knowledge, the first clear measurement of the phase-locking temperature of the 3-D matrix formed by YBa{sub 2}Cu{sub 3}O{sub 7} grains, which are in electrical contact with one another through weak links.

  14. Two-phase chromium-niobium alloys exhibiting improved mechanical properties at high temperatures

    DOE Patents [OSTI]

    Liu, C.T.; Takeyama, Masao.

    1994-02-01

    The specification discloses chromium-niobium alloys which exhibit improved mechanical properties at high temperatures in the range of 1250 C and improved room temperature ductility. The alloys contain a Cr[sub 2]Nb-rich intermetallic phase and a Cr-rich phase with an overall niobium concentration in the range of from about 5 to about 18 at. %. The high temperature strength is substantially greater than that of state of the art nickel-based superalloys for enhanced high temperature service. Further improvements in the properties of the compositions are obtained by alloying with rhenium and aluminum; and additional rare-earth and other elements. 14 figures.

  15. Two-phase chromium-niobium alloys exhibiting improved mechanical properties at high temperatures

    DOE Patents [OSTI]

    Liu, Chain T. (Oak Ridge, TN); Takeyama, Masao (Tokyo, JP)

    1994-01-01

    The specification discloses chromium-niobium alloys which exhibit improved mechanical properties at high temperatures in the range of 1250.degree. C. and improved room temperature ductility. The alloys contain a Cr.sub.2 Nb-rich intermetallic phase and a Cr-rich phase with an overall niobium concentration in the range of from about 5 to about 18 at. %. The high temperature strength is substantially greater than that of state of the art nickel-based superalloys for enhanced high temperature service. Further improvements in the properties of the compositions are obtained by alloying with rhenium and aluminum; and additional rare-earth and other elements.

  16. High Temperature Gas-cooled Reactor Projected Markets and Scoping Economics

    SciTech Connect (OSTI)

    Larry Demick

    2010-08-01

    The NGNP Project has the objective of developing the high temperature gas-cooled reactor (HTGR) technology to supply high temperature process heat to industrial processes as a substitute for burning of fossil fuels, such as natural gas. Applications of the HTGR technology that have been evaluated by the NGNP Project for supply of process heat include supply of electricity, steam and high-temperature gas to a wide range of industrial processes, and production of hydrogen and oxygen for use in petrochemical, refining, coal to liquid fuels, chemical, and fertilizer plants.

  17. Ionic liquids and ionic liquid acids with high temperature stability for fuel cell and other high temperature applications, method of making and cell employing same

    DOE Patents [OSTI]

    Angell, C. Austen (Mesa, AZ); Xu, Wu (Broadview Heights, OH); Belieres, Jean-Philippe (Chandler, AZ); Yoshizawa, Masahiro (Tokyo, JP)

    2011-01-11

    Disclosed are developments in high temperature fuel cells including ionic liquids with high temperature stability and the storage of inorganic acids as di-anion salts of low volatility. The formation of ionically conducting liquids of this type having conductivities of unprecedented magnitude for non-aqueous systems is described. The stability of the di-anion configuration is shown to play a role in the high performance of the non-corrosive proton-transfer ionic liquids as high temperature fuel cell electrolytes. Performance of simple H.sub.2(g) electrolyte/O.sub.2(g) fuel cells with the new electrolytes is described. Superior performance both at ambient temperature and temperatures up to and above 200.degree. C. are achieved. Both neutral proton transfer salts and the acid salts with HSO.sup.-.sub.4 anions, give good results, the bisulphate case being particularly good at low temperatures and very high temperatures. The performance of all electrolytes is improved by the addition of a small amount of involatile base of pK.sub.a value intermediate between those of the acid and base that make the bulk electrolyte. The preferred case is the imidazole-doped ethylammonium hydrogensulfate which yields behavior superior in all respects to that of the industry standard phosphoric acid electrolyte.

  18. High-temperature Chemical Compatibility of As-fabricated TRIGA Fuel and Type 304 Stainless Steel Cladding

    SciTech Connect (OSTI)

    Dennis D. Keiser, Jr.; Jan-Fong Jue; Eric Woolstenhulme; Kurt Terrani; Glenn A. Moore

    2012-09-01

    Chemical interaction between TRIGA fuel and Type-304 stainless steel cladding at relatively high temperatures is of interest from the point of view of understanding fuel behavior during different TRIGA reactor transient scenarios. Since TRIGA fuel comes into close contact with the cladding during irradiation, there is an opportunity for interdiffusion between the U in the fuel and the Fe in the cladding to form an interaction zone that contains U-Fe phases. Based on the equilibrium U-Fe phase diagram, a eutectic can develop at a composition between the U6Fe and UFe2 phases. This eutectic composition can become a liquid at around 725°C. From the standpoint of safe operation of TRIGA fuel, it is of interest to develop better understanding of how a phase with this composition may develop in irradiated TRIGA fuel at relatively high temperatures. One technique for investigating the development of a eutectic phase at the fuel/cladding interface is to perform out-of-pile diffusion-couple experiments at relatively high temperatures. This information is most relevant for lightly irradiated fuel that just starts to touch the cladding due to fuel swelling. Similar testing using fuel irradiated to different fission densities should be tested in a similar fashion to generate data more relevant to more heavily irradiated fuel. This report describes the results for TRIGA fuel/Type-304 stainless steel diffusion couples that were annealed for one hour at 730 and 800°C. Scanning electron microscopy with energy- and wavelength-dispersive spectroscopy was employed to characterize the fuel/cladding interface for each diffusion couple to look for evidence of any chemical interaction. Overall, negligible fuel/cladding interaction was observed for each diffusion couple.

  19. Reservoir Operation in Texas 

    E-Print Network [OSTI]

    Wurbs, Ralph A.

    1985-01-01

    to store and to release or withdraw for flood control and various conservation purposes. The report is intended to provide a comprehensive, indepth description of how reservoirs are operated in Texas...

  20. Project Profile: High-Temperature Thermal Array for Next-Generation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    the heat transfer fluid (HTF) system used in concentrating solar power (CSP) systems. The technology, called the high-temperature thermal array, aims to achieve the SunShot...

  1. Computational Study of Chain Transfer to Monomer Reactions in High-Temperature Polymerization of Alkyl Acrylates

    E-Print Network [OSTI]

    Rappe, Andrew M.

    paint and coatings, adhesives, and functional additives.1-5 The basic nature of acrylic resins limits on allowable volatile organic contents (VOCs) of resins.6-8 High temperature (>100 °C

  2. Development and Analysis of Advanced High-Temperature Technology for Nuclear Heat Transport and Power Conversion

    SciTech Connect (OSTI)

    Per F. Peterson

    2010-03-01

    This project by the Thermal Hydraulics Research Laboratory at U.C. Berkeley Studied advanced high-temperature heat transport and power conversion technology, in support of the Nuclear Hydrogen Initiative and Generation IV.

  3. An integrated performance model for high temperature gas cooled reactor coated particle fuel

    E-Print Network [OSTI]

    Wang, Jing, 1976-

    2004-01-01

    The performance of coated fuel particles is essential for the development and deployment of High Temperature Gas Reactor (HTGR) systems for future power generation. Fuel performance modeling is indispensable for understanding ...

  4. High Temperature Materials Laboratory User Program: 19th Annual Report, October 1, 2005 - September 30, 2006

    SciTech Connect (OSTI)

    Pasto, Arvid

    2007-08-01

    Annual Report contains overview of the High Temperature Materials Laboratory User Program and includes selected highlights of user activities for FY2006. Report is submitted to individuals within sponsoring DOE agency and to other interested individuals.

  5. A simple way to the high-temperature expansion of relativistic Fermi-Dirac integrals

    E-Print Network [OSTI]

    Khvorostukhin, A S

    2015-01-01

    The pressure of an ideal relativistic Fermi gas is computed as an infinite series for high temperatures. Expansion of the particle number density, the scalar density, and the entropy density as first derivatives of the pressure is also found.

  6. Recent developments in high-temperature photonic crystals for energy conversion

    E-Print Network [OSTI]

    Rinnerbauer, Veronika

    After decades of intense studies focused on cryogenic and room temperature nanophotonics, scientific interest is also growing in high-temperature nanophotonics aimed at solid-state energy conversion. These latest extensive ...

  7. Development of a High Temperature Gas-Cooled Reactor TRISO-coated particle fuel chemistry model

    E-Print Network [OSTI]

    Diecker, Jane T

    2005-01-01

    The first portion of this work is a comprehensive analysis of the chemical environment in a High Temperature Gas-Cooled Reactor TRISO fuel particle. Fission product inventory versus burnup is calculated. Based on those ...

  8. Synthesis and Characterization of High Temperature Cement-Based Hydroceramic Materials 

    E-Print Network [OSTI]

    Kyritsis, Konstantinos

    2009-01-01

    Cement-based materials are of importance in the construction of geothermal wells and high-temperature oil and gas wells. These materials fill the annulus between the well casing and the rock forming a protective layer, ...

  9. Test Results From The Idaho National Laboratory 15kW High Temperature Electrolysis Test Facility

    SciTech Connect (OSTI)

    Carl M. Stoots; Keith G. Condie; James E. O'Brien; J. Stephen Herring; Joseph J. Hartvigsen

    2009-07-01

    A 15kW high temperature electrolysis test facility has been developed at the Idaho National Laboratory under the United States Department of Energy Nuclear Hydrogen Initiative. This facility is intended to study the technology readiness of using high temperature solid oxide cells for large scale nuclear powered hydrogen production. It is designed to address larger-scale issues such as thermal management (feed-stock heating, high temperature gas handling, heat recuperation), multiple-stack hot zone design, multiple-stack electrical configurations, etc. Heat recuperation and hydrogen recycle are incorporated into the design. The facility was operated for 1080 hours and successfully demonstrated the largest scale high temperature solid-oxide-based production of hydrogen to date.

  10. Project Profile: A Small-Particle Solar Receiver for High-Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    high-temperature solar receiver in the multi-megawatt range that can drive a gas turbine to generate low-cost electricity. The goals of this project are to:...

  11. Microsoft Word - NETL-TRS-5-2014_High-Temperature, High-Pressure...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    values at 533 K (gray dashed line). Suggested Citation: Gamwo, I. K.; Tapriyal, D.; Enick, R. M.; McHugh, M. A.; Morreale, B. D. High Temperature, High Pressure Equation of...

  12. Low emissivity high-temperature tantalum thin film coatings for silicon devices

    E-Print Network [OSTI]

    Rinnerbauer, Veronika

    The authors study the use of thin ( ? 230?nm) tantalum (Ta) layers on silicon (Si) as a low emissivity (high reflectivity) coating for high-temperature Si devices. Such coatings are critical to reduce parasitic radiation ...

  13. Technical and economic feasibility of a high-temperature self-assembling battery

    E-Print Network [OSTI]

    Bradwell, David (David Johnathon)

    2006-01-01

    A conceptual high-temperature battery system for large-scale grid power applications was proposed, described, and evaluated. Unlike conventional battery technologies whose maximum current rate is constrained by at least ...

  14. A review of high-temperature geothermal developments in the Northern...

    Open Energy Info (EERE)

    A review of high-temperature geothermal developments in the Northern Basin and Range Province Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: A review of...

  15. A Review of High-Temperature Geothermal Developments in the Northern...

    Open Energy Info (EERE)

    A Review of High-Temperature Geothermal Developments in the Northern Basin and Range Province Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: A...

  16. Iron-niobium-aluminum alloy having high-temperature corrosion resistance

    DOE Patents [OSTI]

    Hsu, Huey S.

    1988-04-14

    An alloy for use in high temperature sulfur and oxygen containing environments, having aluminum for oxygen resistance, niobium for sulfur resistance and the balance iron, is discussed. 4 figs., 2 tabs.

  17. Numerical Analysis of Non-Uniformities and Anisotropy in High-Temperature Superconducting Coils

    E-Print Network [OSTI]

    Hu, Di; Ainslie, Mark D.; Zou, Jin; Cardwell, David A.

    2014-12-12

    High-temperature superconducting (HTS) coils play an important role in a number of large-scale engineering applications, such as electric machines employing HTS coated conductors. Non-uniformities and anisotropy in the properties of the coated...

  18. High Temperature Fuel Cell Tri-Generation of Power, Heat & H2...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heat & H2 from Biogas High Temperature Fuel Cell Tri-Generation of Power, Heat & H2 from Biogas Success story about using waste water treatment gas for hydrogen production at UC...

  19. EA-0510: High-Temperature Solid Oxide Fuel Cell (Sofc) Generator Development Project (METC), Churchill, Pennsylvania

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of a proposal to enter into a 5-year cooperative agreement with the Westinghouse Electric Corporation for the development of high-temperature solid oxide...

  20. Improved germination of pansy seed at high temperatures by priming with salt solutions 

    E-Print Network [OSTI]

    Yoon, Beyoung-Han

    1995-01-01

    various salt solutions at defined osmotic potentials as effective priming treatment for improving germination and emergence of pansy seed at high temperatures. the second objectives was to compare respiration rates during germination for primed...

  1. Transport coefficients in high temperature gauge theories: (I) Leading-log results

    E-Print Network [OSTI]

    Peter Arnold; Guy D. Moore; Laurence G. Yaffe

    2000-10-16

    Leading-log results are derived for the shear viscosity, electrical conductivity, and flavor diffusion constants in both Abelian and non-Abelian high temperature gauge theories with various matter field content.

  2. Large Field Erected and Packaged High Temperature Water (HTW) Generators for Coal Firing 

    E-Print Network [OSTI]

    Boushell, C. C.

    1980-01-01

    The purpose of the paper is to disseminate information on the energy savings possible with High Temperature Water (HTW) for heating and industrial process application and to provide information on coal fired HTW generator ...

  3. Full-length high-temperature severe fuel damage test No. 2. Final safety analysis

    SciTech Connect (OSTI)

    Hesson, G.M.; Lombardo, N.J.; Pilger, J.P.; Rausch, W.N.; King, L.L.; Hurley, D.E.; Parchen, L.J.; Panisko, F.E.

    1993-09-01

    Hazardous conditions associated with performing the Full-Length High- Temperature (FLHT). Severe Fuel Damage Test No. 2 experiment have been analyzed. Major hazards that could cause harm or damage are (1) radioactive fission products, (2) radiation fields, (3) reactivity changes, (4) hydrogen generation, (5) materials at high temperature, (6) steam explosion, and (7) steam pressure pulse. As a result of this analysis, it is concluded that with proper precautions the FLHT- 2 test can be safely conducted.

  4. Oil recovery from naturally fractured reservoirs by steam injection methods. Final report

    SciTech Connect (OSTI)

    Reis, J.C.; Miller, M.A.

    1995-05-01

    Oil recovery by steam injection is a proven, successful technology for nonfractured reservoirs, but has received only limited study for fractured reservoirs. Preliminary studies suggest recovery efficiencies in fractured reservoirs may be increased by as much as 50% with the application of steam relative to that of low temperature processes. The key mechanisms enhancing oil production at high temperature are the differential thermal expansion between oil and the pore volume, and the generation of gases within matrix blocks. Other mechanisms may also contribute to increased production. These mechanisms are relatively independent of oil gravity, making steam injection into naturally fractured reservoirs equally attractive to light and heavy oil deposits. The objectives of this research program are to quantify the amount of oil expelled by these recovery mechanisms and to develop a numerical model for predicting oil recovery in naturally fractured reservoirs during steam injection. The experimental study consists of constructing and operating several apparatuses to isolate each of these mechanisms. The first measures thermal expansion and capillary imbibition rates at relatively low temperature, but for various lithologies and matrix block shapes. The second apparatus measures the same parameters, but at high temperatures and for only one shape. A third experimental apparatus measures the maximum gas saturations that could build up within a matrix block. A fourth apparatus measures thermal conductivity and diffusivity of porous media. The numerical study consists of developing transfer functions for oil expulsion from matrix blocks to fractures at high temperatures and incorporating them, along with the energy equation, into a dual porosity thermal reservoir simulator. This simulator can be utilized to make predictions for steam injection processes in naturally-fractured reservoirs. Analytical models for capillary imbibition have also been developed.

  5. GEOTHERMAL RESERVOIR SIMULATIONS WITH SHAFT79

    E-Print Network [OSTI]

    Pruess, Karsten

    2012-01-01

    that well blocks must geothermal reservoir s·tudies, paperof Califomia. LBL-10066 GEOTHERMAL RESERVOIR SIMULATIONSbe presented at the Fifth Geothermal Reservoir Engineering

  6. Journal of the European Ceramic Society 25 (2005) 13131324 High temperature elasticity measurements on oxides by Brillouin

    E-Print Network [OSTI]

    Jackson, Jennifer M.

    2005-01-01

    for determining the elastic moduli at high temperatures, using both electric resistive heating (to 1800 K) and CO2 by Elsevier Ltd. Keywords: Spectroscopy; Mechanical properties; High-temperature elasticity measurements by Brillouin scattering 1. Introduction Knowledge of the high-temperature elastic properties is fundamental

  7. A reservoir management strategy for multilayered reservoirs in eastern Venezuela 

    E-Print Network [OSTI]

    Espinel Diaz, Arnaldo Leopoldo

    1998-01-01

    A reservoir management strategy has been developed for a field located in eastern Venezuela. The field contains deep, high pressure, multilayer reservoirs. A thorough formation evaluation was accomplished using the log data, core data, PVT data...

  8. Alternative Passive Decay-Heat Systems for the Advanced High-Temperature Reactor

    SciTech Connect (OSTI)

    Forsberg, Charles W.

    2006-07-01

    The Advanced High-Temperature Reactor (AHTR) is a low-pressure, liquid-salt-cooled high-temperature reactor for the production of electricity and hydrogen. The high-temperature (950 deg C) variant is defined as the liquid-salt-cooled very high-temperature reactor (LS-VHTR). The AHTR has the same safety goals and uses the same graphite-matrix coated particle fuel as do modular high-temperature gas-cooled reactors. However, the large AHTR power output [2400 to 4000 MW(t)] implies the need for a different type of passive decay-heat removal system. Because the AHTR is a low-pressure, liquid-cooled reactor like sodium-cooled reactors, similar types of decay-heat-removal systems can be used. Three classes of passive decay heat removal systems have been identified: the reactor vessel auxiliary cooling system which is similar to that proposed for the General Electric S-PRISM sodium-cooled fast reactor; the direct reactor auxiliary cooling system, which is similar to that used in the Experimental Breeder Reactor-II; and a new pool reactor auxiliary cooling system. These options are described and compared. (author)

  9. Facility Configuration Study of the High Temperature Gas-Cooled Reactor Component Test Facility

    SciTech Connect (OSTI)

    S. L. Austad; L. E. Guillen; D. S. Ferguson; B. L. Blakely; D. M. Pace; D. Lopez; J. D. Zolynski; B. L. Cowley; V. J. Balls; E.A. Harvego, P.E.; C.W. McKnight, P.E.; R.S. Stewart; B.D. Christensen

    2008-04-01

    A test facility, referred to as the High Temperature Gas-Cooled Reactor Component Test Facility or CTF, will be sited at Idaho National Laboratory for the purposes of supporting development of high temperature gas thermal-hydraulic technologies (helium, helium-Nitrogen, CO2, etc.) as applied in heat transport and heat transfer applications in High Temperature Gas-Cooled Reactors. Such applications include, but are not limited to: primary coolant; secondary coolant; intermediate, secondary, and tertiary heat transfer; and demonstration of processes requiring high temperatures such as hydrogen production. The facility will initially support completion of the Next Generation Nuclear Plant. It will secondarily be open for use by the full range of suppliers, end-users, facilitators, government laboratories, and others in the domestic and international community supporting the development and application of High Temperature Gas-Cooled Reactor technology. This pre-conceptual facility configuration study, which forms the basis for a cost estimate to support CTF scoping and planning, accomplishes the following objectives: • Identifies pre-conceptual design requirements • Develops test loop equipment schematics and layout • Identifies space allocations for each of the facility functions, as required • Develops a pre-conceptual site layout including transportation, parking and support structures, and railway systems • Identifies pre-conceptual utility and support system needs • Establishes pre-conceptual electrical one-line drawings and schedule for development of power needs.

  10. Hydrocarbon Reservoir Parameter Estimation Using

    E-Print Network [OSTI]

    van Vliet, Lucas J.

    Hydrocarbon Reservoir Parameter Estimation Using Production Data and Time-Lapse Seismic #12;#12;Hydrocarbon Reservoir Parameter Estimation Using Production Data and Time-Lapse Seismic PROEFSCHRIFT ter . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1.2 Recovery process . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1.3 Field

  11. Integrated Process Configuration for High-Temperature Sulfur Mitigation during Biomass Conversion via Indirect Gasification

    SciTech Connect (OSTI)

    Dutta. A.; Cheah, S.; Bain, R.; Feik, C.; Magrini-Bair, K.; Phillips, S.

    2012-06-20

    Sulfur present in biomass often causes catalyst deactivation during downstream operations after gasification. Early removal of sulfur from the syngas stream post-gasification is possible via process rearrangements and can be beneficial for maintaining a low-sulfur environment for all downstream operations. High-temperature sulfur sorbents have superior performance and capacity under drier syngas conditions. The reconfigured process discussed in this paper is comprised of indirect biomass gasification using dry recycled gas from downstream operations, which produces a drier syngas stream and, consequently, more-efficient sulfur removal at high temperatures using regenerable sorbents. A combination of experimental results from NREL's fluidizable Ni-based reforming catalyst, fluidizable Mn-based sulfur sorbent, and process modeling information show that using a coupled process of dry gasification with high-temperature sulfur removal can improve the performance of Ni-based reforming catalysts significantly.

  12. Vacuum encapsulated, high temperature diamond amplified cathode capsule and method for making same

    DOE Patents [OSTI]

    Rao, Triveni; Walsh, John; Gangone, Elizabeth

    2015-12-29

    A vacuum encapsulated, hermetically sealed cathode capsule for generating an electron beam of secondary electrons, which generally includes a cathode element having a primary emission surface adapted to emit primary electrons, an annular insulating spacer, a diamond window element comprising a diamond material and having a secondary emission surface adapted to emit secondary electrons in response to primary electrons impinging on the diamond window element, a first high-temperature solder weld disposed between the diamond window element and the annular insulating spacer and a second high-temperature solder weld disposed between the annular insulating spacer and the cathode element. The cathode capsule is formed by a high temperature weld process under vacuum such that the first solder weld forms a hermetical seal between the diamond window element and the annular insulating spacer and the second solder weld forms a hermetical seal between the annular spacer and the cathode element whereby a vacuum encapsulated chamber is formed within the capsule.

  13. High-temperature fiber optic cubic-zirconia pressure sensor - article no. 124402

    SciTech Connect (OSTI)

    Peng, W.; Pickrell, G.R.; Wang, A.B.

    2005-12-15

    There is a critical need for pressure sensors that can operate reliably at high temperatures in many industrial segments such as in the combustion section of gas turbine engines for both transportation and power generation, coal gasifiers, coal fired boilers, etc. Optical-based sensors are particularly attractive for the measurement of a wide variety of physical and chemical parameters in high-temperature and high-pressure industrial environments due to their small size and immunity to electromagnetic interference. A fiber optic pressure sensor utilizing single-crystal cubic zirconia as the sensing element is reported. The pressure response of this sensor has been measured at temperatures up to 1000{sup o}C. Additional experimental results show that cubic zirconia could be used for pressure sensing at temperatures over 1000{sup o}C. This study demonstrates the feasibility of using a novel cubic-zirconia sensor for pressure measurement at high temperatures.

  14. High-Temperature Nuclear Reactors for In-Situ Recovery of Oil from Oil Shale

    SciTech Connect (OSTI)

    Forsberg, Charles W.

    2006-07-01

    The world is exhausting its supply of crude oil for the production of liquid fuels (gasoline, jet fuel, and diesel). However, the United States has sufficient oil shale deposits to meet our current oil demands for {approx}100 years. Shell Oil Corporation is developing a new potentially cost-effective in-situ process for oil recovery that involves drilling wells into oil shale, using electric heaters to raise the bulk temperature of the oil shale deposit to {approx}370 deg C to initiate chemical reactions that produce light crude oil, and then pumping the oil to the surface. The primary production cost is the cost of high-temperature electrical heating. Because of the low thermal conductivity of oil shale, high-temperature heat is required at the heater wells to obtain the required medium temperatures in the bulk oil shale within an economically practical two to three years. It is proposed to use high-temperature nuclear reactors to provide high-temperature heat to replace the electricity and avoid the factor-of-2 loss in converting high-temperature heat to electricity that is then used to heat oil shale. Nuclear heat is potentially viable because many oil shale deposits are thick (200 to 700 m) and can yield up to 2.5 million barrels of oil per acre, or about 125 million dollars/acre of oil at $50/barrel. The concentrated characteristics of oil-shale deposits make it practical to transfer high-temperature heat over limited distances from a reactor to the oil shale deposits. (author)

  15. Understanding Fundamental Material Degradation Processes in High Temperature Aggressive Chemomechanical Environments

    SciTech Connect (OSTI)

    Stubbins, James; Gewirth, Andrew; Sehitoglu, Huseyin; Sofronis, Petros; Robertson, Ian

    2014-01-16

    The objective of this project is to develop a fundamental understanding of the mechanisms that limit materials durability for very high-temperature applications. Current design limitations are based on material strength and corrosion resistance. This project will characterize the interactions of high-temperature creep, fatigue, and environmental attack in structural metallic alloys of interest for the very high-temperature gas-cooled reactor (VHTR) or Next–Generation Nuclear Plant (NGNP) and for the associated thermo-chemical processing systems for hydrogen generation. Each of these degradation processes presents a major materials design challenge on its own, but in combination, they can act synergistically to rapidly degrade materials and limit component lives. This research and development effort will provide experimental results to characterize creep-fatigue-environment interactions and develop predictive models to define operation limits for high-temperature structural material applications. Researchers will study individually and in combination creep-fatigue-environmental attack processes in Alloys 617, 230, and 800H, as well as in an advanced Ni-Cr oxide dispersion strengthened steel (ODS) system. For comparison, the study will also examine basic degradation processes in nichrome (Ni-20Cr), which is a basis for most high-temperature structural materials, as well as many of the superalloys. These materials are selected to represent primary candidate alloys, one advanced developmental alloy that may have superior high-temperature durability, and one model system on which basic performance and modeling efforts can be based. The research program is presented in four parts, which all complement each other. The first three are primarily experimental in nature, and the last will tie the work together in a coordinated modeling effort. The sections are (1) dynamic creep-fatigue-environment process, (2) subcritical crack processes, (3) dynamic corrosion – crack initiation processes, and (4) modeling.

  16. LARGE-SCALE HYDROGEN PRODUCTION FROM NUCLEAR ENERGY USING HIGH TEMPERATURE ELECTROLYSIS

    SciTech Connect (OSTI)

    James E. O'Brien

    2010-08-01

    Hydrogen can be produced from water splitting with relatively high efficiency using high-temperature electrolysis. This technology makes use of solid-oxide cells, running in the electrolysis mode to produce hydrogen from steam, while consuming electricity and high-temperature process heat. When coupled to an advanced high temperature nuclear reactor, the overall thermal-to-hydrogen efficiency for high-temperature electrolysis can be as high as 50%, which is about double the overall efficiency of conventional low-temperature electrolysis. Current large-scale hydrogen production is based almost exclusively on steam reforming of methane, a method that consumes a precious fossil fuel while emitting carbon dioxide to the atmosphere. Demand for hydrogen is increasing rapidly for refining of increasingly low-grade petroleum resources, such as the Athabasca oil sands and for ammonia-based fertilizer production. Large quantities of hydrogen are also required for carbon-efficient conversion of biomass to liquid fuels. With supplemental nuclear hydrogen, almost all of the carbon in the biomass can be converted to liquid fuels in a nearly carbon-neutral fashion. Ultimately, hydrogen may be employed as a direct transportation fuel in a “hydrogen economy.” The large quantity of hydrogen that would be required for this concept should be produced without consuming fossil fuels or emitting greenhouse gases. An overview of the high-temperature electrolysis technology will be presented, including basic theory, modeling, and experimental activities. Modeling activities include both computational fluid dynamics and large-scale systems analysis. We have also demonstrated high-temperature electrolysis in our laboratory at the 15 kW scale, achieving a hydrogen production rate in excess of 5500 L/hr.

  17. A Process Model for the Production of Hydrogen Using High Temperature Electrolysis

    SciTech Connect (OSTI)

    M. G. Mc Kellar; E. A. Harvego; M. Richards; A. Shenoy

    2006-07-01

    High temperature electrolysis (HTE) involves the splitting of stream into hydrogen and oxygen at high temperatures. The primary advantage of HTE over conventional low temperature electrolysis is that considerably higher hydrogen production efficiencies can be achieved. Performing the electrolysis process at high temperatures results in more favorable thermodynamics for electrolysis, more efficient production of electricity, and allows direct use of process heat to generate steam. This paper presents the results of process analyses performed to evaluate the hydrogen production efficiencies of an HTE plant coupled to a 600 MWt Modular Helium Reactor (MHR) that supplies both the electricity and process heat needed to drive the process. The MHR operates with a coolant outlet temperature of 950 C. Approximately 87% of the high-temperature heat is used to generate electricity at high efficiency using a direct, Brayton-cycle power conversion system. The remaining high-temperature heat is used to generate a superheated steam / hydrogen mixture that is supplied to the electrolyzers. The analyses were performed using the HYSYS process modeling software. The model used to perform the analyses consisted of three loops; a primary high temperature helium loop, a secondary helium loop and the HTE process loop. The detailed model included realistic representations of all major components in the system, including pumps, compressors, heat exchange equipment, and the electrolysis stack. The design of the hydrogen production process loop also included a steam-sweep gas system to remove oxygen from the electrolysis stack so that it can be recovered and used for other applications. Results of the process analyses showed that hydrogen production efficiencies in the range of 45% to 50% are achievable with this system.

  18. To the Non-Local Theory of the High Temperature Superconductivity

    E-Print Network [OSTI]

    Boris V. Alexeev

    2012-01-30

    The possibility of the non local physics application in the theory of superconductivity is investigated. It is shown that by the superconducting conditions the relay ("estafette") motion of the soliton' system ("attice ion - electron") is realizing by the absence of chemical bonds. From the position of the quantum hydrodynamics the problem of creation of the high temperature superconductors leads to finding of materials which lattices could realize the soliton' motion without destruction. These materials should be created using the technology of quantum dots. Key words: Foundations of the theory of transport processes; The theory of solitons; Generalized hydrodynamic equations; Foundations of quantum mechanics; high temperature superconductivity.

  19. Modeling Coupled THM Processes and Brine Migration in Salt at High Temperatures

    SciTech Connect (OSTI)

    Rutqvist, Jonny; Blanco-Martin, Laura; Molins, Sergi; Trebotich, David; Birkholzer, Jens

    2015-09-01

    In this report, we present FY2015 progress by Lawrence Berkeley National Laboratory (LBNL) related to modeling of coupled thermal-hydrological-mechanical-chemical (THMC) processes in salt and their effect on brine migration at high temperatures. This is a combined milestone report related to milestone Salt R&D Milestone “Modeling Coupled THM Processes and Brine Migration in Salt at High Temperatures” (M3FT-15LB0818012) and the Salt Field Testing Milestone (M3FT-15LB0819022) to support the overall objectives of the salt field test planning.

  20. Secondary heat exchanger design and comparison for advanced high temperature reactor

    SciTech Connect (OSTI)

    Sabharwall, P.; Kim, E. S.; Siahpush, A.; McKellar, M.; Patterson, M.

    2012-07-01

    Next generation nuclear reactors such as the advanced high temperature reactor (AHTR) are designed to increase energy efficiency in the production of electricity and provide high temperature heat for industrial processes. The efficient transfer of energy for industrial applications depends on the ability to incorporate effective heat exchangers between the nuclear heat transport system and the industrial process heat transport system. This study considers two different types of heat exchangers - helical coiled heat exchanger and printed circuit heat exchanger - as possible options for the AHTR secondary heat exchangers with distributed load analysis and comparison. Comparison is provided for all different cases along with challenges and recommendations. (authors)

  1. Process for introducing electrical conductivity into high-temperature polymeric materials

    DOE Patents [OSTI]

    Liepins, R.; Jorgensen, B.S.; Liepins, L.Z.

    1993-12-21

    High-temperature electrically conducting polymers are described. The in situ reactions: AgNO[sub 3] + RCHO [yields] Ag + RCOOH and R[sub 3]M [yields] M + 3R, where M=Au or Pt have been found to introduce either substantial bulk or surface conductivity in high-temperature polymers. The reactions involving the R[sub 3]M were caused to proceed thermally suggesting the possibility of using laser means for initiating such reactions in selected areas or volumes of the polymeric materials. The polymers successfully investigated to date are polyphenylquinoxaline, polytolylquinoxaline, polyquinoline, polythiazole, and pyrone.

  2. Process for introducing electrical conductivity into high-temperature polymeric materials

    DOE Patents [OSTI]

    Liepins, R.; Jorgensen, B.S.; Liepins, L.Z.

    1987-08-27

    High-temperature electrically conducting polymers. The in situ reactions: AgNO/sub 3/ + RCHO ..-->.. Ag/sup 0/ + RCOOH and R/sub 3/M ..-->.. M/sup 0/ + 3R, where M = Au or Pt have been found to introduce either substantial bulk or surface conductivity in high- temperature polymers. The reactions involving the R/sub 3/M were caused to proceed thermally suggesting the possibility of using laser means for initiating such reactions in selected areas or volumes of the polymeric materials. The polymers successfully investigated to date are polyphenylquinoxaline, polytolylquinoxaline, polyquinoline, polythiazole, and pyrrone. 3 tabs.

  3. 3D CFD Model of High Temperature H2O/CO2 Co-electrolysis

    SciTech Connect (OSTI)

    Grant Hawkes; James O'Brien; Carl Stoots; Stephen Herring; Joe Hartvigsen

    2007-06-01

    3D CFD Model of High Temperature H2O/CO2 Co-Electrolysis Grant Hawkes1, James O’Brien1, Carl Stoots1, Stephen Herring1 Joe Hartvigsen2 1 Idaho National Laboratory, Idaho Falls, Idaho, grant.hawkes@inl.gov 2 Ceramatec Inc, Salt Lake City, Utah INTRODUCTION A three-dimensional computational fluid dynamics (CFD) model has been created to model high temperature co-electrolysis of steam and carbon dioxide in a planar solid oxide electrolyzer (SOE) using solid oxide fuel cell technology. A research program is under way at the Idaho National Laboratory (INL) to simultaneously address the research and scale-up issues associated with the implementation of planar solid-oxide electrolysis cell technology for syn-gas production from CO2 and steam. Various runs have been performed under different run conditions to help assess the performance of the SOE. This paper presents CFD results of this model compared with experimental results. The Idaho National Laboratory (INL), in conjunction with Ceramatec Inc. (Salt Lake City, USA) has been researching for several years the use of solid-oxide fuel cell technology to electrolyze steam for large-scale nuclear-powered hydrogen production. Now, an experimental research project is underway at the INL to produce syngas by simultaneously electrolyzing at high-temperature steam and carbon dioxide (CO2) using solid oxide fuel cell technology. A strong interest exists in the large-scale production of syn-gas from CO2 and steam to be reformed into a usable transportation fuel. If biomass is used as the carbon source, the overall process is climate neutral. Consequently, there is a high level of interest in production of syn-gas from CO2 and steam electrolysis. With the price of oil currently around $60 / barrel, synthetically-derived hydrocarbon fuels (synfuels) have become economical. Synfuels are typically produced from syngas – hydrogen (H2) and carbon monoxide (CO) -- using the Fischer-Tropsch process, discovered by Germany before World War II. High-temperature nuclear reactors have the potential for substantially increasing the efficiency of syn-gas production from CO2 and water, with no consumption of fossil fuels, and no production of greenhouse gases. Thermal CO2-splitting and water splitting for syn-gas production can be accomplished via high-temperature electrolysis, using high-temperature nuclear process heat and electricity. A high-temperature advanced nuclear reactor coupled with a high-efficiency high-temperature electrolyzer could achieve a competitive thermal-to-syn-gas conversion efficiency of 45 to 55%.

  4. The high-temperature behavior for the directed polymer in dimension 1+2

    E-Print Network [OSTI]

    Quentin Berger; Hubert Lacoin

    2015-06-30

    We investigate the high-temperature behavior of the directed polymer model in dimension $1+2$. More precisely we study the difference $\\Delta \\mathtt{F}(\\beta)$ between the quenched and annealed free energies for small values of the inverse temperature $\\beta$. This quantity is associated to localization properties of the polymer trajectories, and is related to the overlap fraction of two replicas. Adapting recent techniques developed by the authors in the context of the disordered pinning model (Berger and Lacoin, arXiv:1503.07315 [math-ph]), we identify the sharp asymptotic high temperature behavior \\[\\lim_{\\beta\\to 0} \\, \\beta^2 \\log \\Delta \\mathtt{F}(\\beta) = -\\pi \\, .\\

  5. Applying reservoir characterization technology

    SciTech Connect (OSTI)

    Lake, L.W.

    1994-12-31

    While reservoir characterization is an old discipline, only within the last 10 years have engineers and scientists been able to make quantitative descriptions, due mostly to improvements in high-resolution computational power, sophisticated graphics, and geostatistics. This paper summarizes what has been learned during the past decade by using these technologies.

  6. Reinjection into geothermal reservoirs

    SciTech Connect (OSTI)

    Bodvarsson, G.S.; Stefansson, V.

    1987-08-01

    Reinjection of geothermal wastewater is practiced as a means of disposal and for reservoir pressure support. Various aspects of reinjection are discussed, both in terms of theoretical studies as well as specific field examples. The discussion focuses on the major effects of reinjection, including pressure maintenance and chemical and thermal effects. (ACR)

  7. Formation of Ge nanoclusters on Si(1 1 1)-7 7 surface at high temperature

    E-Print Network [OSTI]

    Gao, Hongjun

    Formation of Ge nanoclusters on Si(1 1 1)-7 · 7 surface at high temperature H.M. Guo, Y.L. Wang, H for publication 17 May 2004 Available online 5 June 2004 Abstract We report on Ge nanocluster formation on Si(1 1 of the Ge clusters are more uniform than those obtained at room temperature due to an increase

  8. Proceedings HTR2006: International Topical Meeting on High Temperature Reactor Technology

    E-Print Network [OSTI]

    Proceedings HTR2006: 3rd International Topical Meeting on High Temperature Reactor Technology Massachusetts Institute of Technology Andrew C. Kadak Department of Nuclear Engineering Massachusetts Institute of Technology Abstract MIT has been benchmarking Japanese and German NACOK air ingress tests using the FLUENT

  9. Standard Practice for Surveillance Testing of High-Temperature Nuclear Component Materials

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    1976-01-01

    1.1 This practice covers procedures for specimen testing to establish changes occurring in the mechanical properties due to irradiation and thermal effects of nuclear component metallic materials where these materials are used for high temperature applications above 370°C (700°F).

  10. Graphene, a material for high temperature devices intrinsic carrier density, carrier

    E-Print Network [OSTI]

    Wang, Wei Hua

    Graphene, a material for high temperature devices ­ intrinsic carrier density, carrier drift 3.87 3 106 cm22 K22 ?T2 ), carrier drift velocity, and G mode phonon energy of graphene devices and their temperature dependencies up to 2400 K. Our results show intrinsic carrier density of graphene is an order

  11. Promoting isothermal martensite formation by high temperature heat treatments in a precipitation hardening austenitic stainless steel

    E-Print Network [OSTI]

    Cambridge, University of

    Promoting isothermal martensite formation by high temperature heat treatments in a precipitation hardening austenitic stainless steel David San Martín* and Carlos García-Mateo MATERALIA Group, Dept mechanical properties, the steel investigated (12Cr-9Ni-4Mo-2Cu-1Ti) is solution treated and cooled down

  12. Low emissivity high-temperature tantalum thin film coatings for silicon Veronika Rinnerbauer,a)

    E-Print Network [OSTI]

    Low emissivity high-temperature tantalum thin film coatings for silicon devices Veronika) The authors study the use of thin ($230 nm) tantalum (Ta) layers on silicon (Si) as a low emissivity (high to achieve such a coating are low emissivity in the near infrared and superior thermal stability at high

  13. Welding: insights from high-temperature analogue experiments Steven L. Quane, J.K. Russell*

    E-Print Network [OSTI]

    Russell, Kelly

    Welding: insights from high-temperature analogue experiments Steven L. Quane, J.K. Russell* Igneous of pyroclastic deposits during welding is incompletely understood and is based on a surprisingly small number roles of emplacement temperature, load and glass transition temperature in welding of pyroclastic

  14. High-temperature gas-cooled reactors: preliminary safety and environmental information document. Volume IV

    SciTech Connect (OSTI)

    Not Available

    1980-01-01

    Information is presented concerning medium-enriched uranium/thorium once-through fuel cycle; medium-enrichment uranium-233/thorium recycle fuel; high-enrichment uranium-235/thorium recycle (spiked) fuel cycle; high-enrichment uranium-233/thorium recycle (spiked) fuel cycle; and gas-turbine high-temperature gas-cooled reactor.

  15. Oxidation of carbon fiber surfaces for use as reinforcement in high-temperature cementitious material systems

    DOE Patents [OSTI]

    Sugama, Toshifumi (Mastic Beach, NY)

    1990-01-01

    The interfacial bond characteristics between carbon fiber and a cement matrix, in high temperature fiber-reinforced cementitious composite systems, can be improved by the oxidative treatment of the fiber surfaces. Compositions and the process for producing the compositions are disclosed.

  16. High-temperature deformation in the Neoproterozoic transpressional Ribeira belt, southeast Brazil

    E-Print Network [OSTI]

    Bascou, Jérôme

    High-temperature deformation in the Neoproterozoic transpressional Ribeira belt, southeast Brazil; accepted 12 December 2001 Abstract The Neoproterozoic Ribeira belt is subdivided in two domains of anastomosing transcurrent shear zones parallel to the belt. This contrast is interpreted as reflecting

  17. High-temperature alkali vapor cells with antirelaxation surface coatings S. J. Seltzera

    E-Print Network [OSTI]

    Romalis, Mike

    High-temperature alkali vapor cells with antirelaxation surface coatings S. J. Seltzera and M. V 2009; accepted 31 August 2009; published online 2 December 2009 Antirelaxation surface coatings allow coatings were previously unavailable for operation at temperatures above 80 °C. We demonstrate

  18. Dislocation reactions, plastic anisotropy and forest strengthening in MgO at high temperature

    E-Print Network [OSTI]

    Devincre, Benoit

    Dislocation reactions, plastic anisotropy and forest strengthening in MgO at high temperature J 2013 Available online 18 January 2014 Keywords: MgO Plasticity Dislocation Dynamics simulation Forest by forest reactions. Impor- tant parameters for dislocation density based modeling of MgO plasticity

  19. Irradiated cubic single crystal SiC as a high temperature sensor Alex A. Volinsky

    E-Print Network [OSTI]

    Volinsky, Alex A.

    Irradiated cubic single crystal SiC as a high temperature sensor Alex A. Volinsky University the temperature of irradiation. Based on this effect the original technology of maximum temperature measurement on the phenomenon of SiC crystal lattice expansion as a result of irradiation [3] and consequently relieving

  20. High-temperature hydroxylation of alumina crystalline surfaces Ramesh Chandrasekharan a

    E-Print Network [OSTI]

    High-temperature hydroxylation of alumina crystalline surfaces Ramesh Chandrasekharan a , Luning- talline surfaces (a, c and r) and subsequent hydroxylation. Samples heat-treated at a higher temperature spectra showed clearer spectral features of hydroxylation and higher degree of hydroxylation for heat

  1. A reactor for high-temperature pyrolysis and oxygen isotopic analysis of cellulose via induction heating

    E-Print Network [OSTI]

    Evans, Michael N.

    A reactor for high-temperature pyrolysis and oxygen isotopic analysis of cellulose via induction and theory to recommend pyrolysis at temperatures above 14508C to minimize memory and fractionation effects of producing pyrolysis conditions for the analysis of oxygen and deuterium isotopic compositions of organic

  2. Aalborg Universitet Comparative study of the break in process of post doped and solgel high temperature

    E-Print Network [OSTI]

    Berning, Torsten

    - brane (HTPEM) fuel cells based on phosphoric acid (PA) doped polybenzimidazole (PBI) is advantageous temperature proton exchange membrane fuel cells Vang, Jakob Rabjerg; Andreasen, Søren Juhl; Araya, Samuel in process of post doped and sol­gel high temperature proton exchange membrane fuel cells. International

  3. Recent developments in high-temperature photonic crystals for energy Veronika Rinnerbauer,*a

    E-Print Network [OSTI]

    -to- electrical energy conversion schemes including thermophotovoltaics (TPV), solar­ thermophotovoltaics, solar­thermal. These latest extensive research efforts are spurred by a renewed interest in high temperature thermal, and solar­thermochemical energy conversion systems. This field is profiting tremendously from

  4. Electrical conductivity of wadsleyite at high temperatures and high pressures Lidong Dai a,b

    E-Print Network [OSTI]

    Electrical conductivity of wadsleyite at high temperatures and high pressures Lidong Dai a,b , Shun 2009 Editor: L. Stixrude Keywords: electrical conductivity wadsleyite oxygen fugacity frequency water The electrical conductivity of wadsleyite aggregates has been determined under the broad range of thermodynamic

  5. Integration of High-Temperature Gas-Cooled Reactors into Industrial Process Applications

    SciTech Connect (OSTI)

    Lee Nelson

    2011-09-01

    This report is a summary of analyses performed by the NGNP project to determine whether it is technically and economically feasible to integrate high temperature gas cooled reactor (HTGR) technology into industrial processes. To avoid an overly optimistic environmental and economic baseline for comparing nuclear integrated and conventional processes, a conservative approach was used for the assumptions and calculations.

  6. Transmission electron energy-loss spectroscopy study of carbon nanotubes upon high temperature treatment

    E-Print Network [OSTI]

    Bertsch George F.

    Transmission electron energy-loss spectroscopy study of carbon nanotubes upon high temperature subject to AIP license or copyright; see http://apl.aip.org/about/rights_and_permissions #12;Transmission of carbon nanotube materials, grown with a pulsed-laser deposition technique but purified and heat treated

  7. Tailored Macroporous SiCN and SiC Structures for High-Temperature Fuel Reforming**

    E-Print Network [OSTI]

    Kenis, Paul J. A.

    Tailored Macroporous SiCN and SiC Structures for High-Temperature Fuel Reforming** By In-Kyung Sung such as the reforming of hydrocarbon fuels (e.g., die- sel or JP-8) into hydrogen for use in portable power sources. Performing heterogeneous catalytic reactions in porous struc- tures at the microscale has certain advantages

  8. Design and Evaluation of a High Temperature Burner Duct Recuperator System 

    E-Print Network [OSTI]

    Parks, W. P.; DeBellis, C. L.; Kneidel, K.

    1988-01-01

    "The Babcock & Wilcox Company (B&W) has completed a program to design, construct, install, and field test a ceramic-based high-temperature burner-duct-recuperator (HTBDR) in an industrial setting. The unit was capable of operating in corrosive, high...

  9. Effect of high temperature on mechanical and physical properties of lightweight cement

    E-Print Network [OSTI]

    North Texas, University of

    ­800uC in terms of compressive strength loss. Most of the original strength is lost between 600 and 800u, loading conditions and moisture regime.10­34 Within the factors affecting the high temperature resistance during their formation and production process. Since such aggregates have low a values and more thermal

  10. High-Temperature Infrared Measurements in the Region of the Bending Fundamental of H12

    E-Print Network [OSTI]

    Quapp, Wolfgang

    High-Temperature Infrared Measurements in the Region of the Bending Fundamental of H12 C14 N, H12 C allowed us to measure the bending vibrational levels up to the 0 1111 0 state, at more than 7900 cm 1 in this paper and in a recent paper on deuterated isotopomers. © 2000 Academic Press Key Words: HCN; bond

  11. Assembling gas-phase reaction mechanisms for high temperature inorganic systems based on quantum chemistry calculations

    E-Print Network [OSTI]

    Swihart, Mark T.

    materials synthesis to propulsion to waste incineration, could in principle be modeled with equal or greater materials synthesis to propulsion to waste incineration, could in principle be modeled with equal or greaterAssembling gas-phase reaction mechanisms for high temperature inorganic systems based on quantum

  12. STUDY OF WORKING FLUID MIXTURES AND HIGH TEMPERATURE WORKING FLUIDS FOR COMPRESSOR DRIVEN SYSTEMS

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    Discussion 17 Heat transfer in condensation 19 References 20 3. SYSTEM ASPECTS OF HEAT PUMPS WITH NONAZEOTROPIC MIXTURES 23 Conclusions 32 4. RECENT DEVELOPMENTS IN THE FIELD OF HIGH TEMPERATURE HEAT PUMPS 33 study with finite heat exchanger areas and realistic compressor efficiencies 50 Industrial case 51 Space

  13. Simulation of the high temperature impression of thermal barrier coatings with columnar microstructure

    E-Print Network [OSTI]

    Hutchinson, John W.

    Thermal barrier systems used in gas turbines utilize various ternary oxides as the outermost insulatingSimulation of the high temperature impression of thermal barrier coatings with columnar of Engineering and Applied Sciences, Harvard University, 29 Oxford Street, Cambridge, MA 02138, USA c Materials

  14. EA-1867: Scale-up of High-Temperature Syngas Cleanup Technology, Polk County, Florida

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of a proposal to provide cost-shared funding to RTI International (RTI) for its proposed project to demonstrate the precommercial scale-up of RTI’s high-temperature syngas cleanup and carbon capture and sequestration technologies.

  15. Modeling ofHybrid (Heat Radiation and Microwave) High Temperature Processing ofLimestone

    E-Print Network [OSTI]

    Yakovlev, Vadim

    Modeling ofHybrid (Heat Radiation and Microwave) High Temperature Processing ofLimestone Shawn M (electromagnetic and thermal) modeling to cover practically valuable scenarios of hybrid (heat radiation is applied to the process of hybrid heating of cylindrical samples of limestone in Ceralink's MAT TM kiln

  16. Aalborg Universitet Modelling of a High Temperature PEM Fuel Cell Stack using Electrochemical

    E-Print Network [OSTI]

    Andreasen, Søren Juhl

    and High Temperature Polymer Electrolyte Fuel Cells, La Grande Motte, Montpellier, France. General rights freely distribute the URL identifying the publication in the public portal ? Take down policy If you.aau.dk on: juli 06, 2015 #12;*sja@iet.aau.dkwww.iet.aau.dk AALBORG UNIVERSITY Department of ENERGY

  17. A Modular High Temperature Measurement Set-Up for Semiconductor Device Characterization

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    such as combustion engines, car brake systems, turbines or well drilling. Therefore, the high temperature to the exposure to the oxygen in the surrounding air. Apart from measuring device terminal characteristics chambers has several ports for electrical feedthroughs as well as a feedthrough for the cooling liquid

  18. Oxidation of carbon fiber surfaces for use as reinforcement in high-temperature cementitious material systems

    DOE Patents [OSTI]

    Sugama, Toshifumi.

    1990-05-22

    The interfacial bond characteristics between carbon fiber and a cement matrix, in high temperature fiber-reinforced cementitious composite systems, can be improved by the oxidative treatment of the fiber surfaces. Compositions and the process for producing the compositions are disclosed. 2 figs.

  19. Scanning electron microscopy study of carbon nanotubes heated at high temperatures in air

    E-Print Network [OSTI]

    . INTRODUCTION Because of their remarkable physical and electronic properties, carbon nanotubes are promising nanotubes in air,3,4 in an oxygen stream,5 or under a flow of carbon dioxide gas.6 Thinning of nanotubesScanning electron microscopy study of carbon nanotubes heated at high temperatures in air Xuekun Lu

  20. High temperature interfacial tension measurements of PA6/PP interfaces compatibilized with copolymers

    E-Print Network [OSTI]

    Joseph, Daniel D.

    ) are generally desired when manufacturing a polymer blend3. The effect of concentration of the copolymer%17-22. In a strict analogy to water-surfactant systems the critical micelle concentration (cmc) is an importantHigh temperature interfacial tension measurements of PA6/PP interfaces compatibilized

  1. High temperature furnaces for small and large angle neutron scattering of disordered materials

    E-Print Network [OSTI]

    Boyer, Edmond

    725 High temperature furnaces for small and large angle neutron scattering of disordered materials and small angle neutron scattering (SANS) experiments respectively. They are vacuum furnaces with a thin maintained in a tantalum box. In a neutron beam, the furnaces produce a very low scattering level (without

  2. Thermally Stable Nanocatalyst for High Temperature Reactions: Pt-Mesoporous Silica Core-Shell Nanoparticles

    SciTech Connect (OSTI)

    Joo, Sang Hoon; Park, J.Y.; Tsung, C.-K.; Yamada, Y.; Yang, P.; Somorjai, G.A.

    2008-10-25

    Recent advances in colloidal synthesis enabled the precise control of size, shape and composition of catalytic metal nanoparticles, allowing their use as model catalysts for systematic investigations of the atomic-scale properties affecting catalytic activity and selectivity. The organic capping agents stabilizing colloidal nanoparticles, however, often limit their application in high-temperature catalytic reactions. Here we report the design of a high-temperature stable model catalytic system that consists of Pt metal core coated with a mesoporous silica shell (Pt{at}mSiO{sub 2}). While inorganic silica shells encaged the Pt cores up to 750 C in air, the mesopores directly accessible to Pt cores made the Pt{at}mSiO{sub 2} nanoparticles as catalytically active as bare Pt metal for ethylene hydrogenation and CO oxidation. The high thermal stability of Pt{at}mSiO{sub 2} nanoparticles permitted high-temperature CO oxidation studies, including ignition behavior, which was not possible for bare Pt nanoparticles because of their deformation or aggregation. The results suggest that the Pt{at}mSiO{sub 2} nanoparticles are excellent nanocatalytic systems for high-temperature catalytic reactions or surface chemical processes, and the design concept employed in the Pt{at}mSiO{sub 2} core-shell catalyst can be extended to other metal-metal oxide compositions.

  3. Copper modified austenitic stainless steel alloys with improved high temperature creep resistance

    DOE Patents [OSTI]

    Swindeman, R.W.; Maziasz, P.J.

    1987-04-28

    An improved austenitic stainless steel that incorporates copper into a base Fe-Ni-Cr alloy having minor alloying substituents of Mo, Mn, Si, T, Nb, V, C, N, P, B which exhibits significant improvement in high temperature creep resistance over previous steels. 3 figs.

  4. High strength porous support tubes for high temperature solid electrolyte electrochemical cells

    DOE Patents [OSTI]

    Rossing, Barry R. (Churchill, PA); Zymboly, Gregory E. (Penn Hills, PA)

    1986-01-01

    A high temperature, solid electrolyte electrochemical cell is made, having an electrode and a solid electrolyte disposed on a porous, sintered support material containing thermally stabilized zirconia powder particles and from about 3 wt. % to about 45 wt. % of thermally stable oxide fibers.

  5. Silicoboroncarbonitride ceramics: A class of high-temperature, dopable electronic materials

    E-Print Network [OSTI]

    Balzar, Davor

    Silicoboron­carbonitride ceramics: A class of high-temperature, dopable electronic materials P. A-derived silicoboron­carbonitride ceramics are reported. Structural analysis using radial . The conductivity variation with temperature for both SiCN and SiBCN ceramics shows Mott's variable range hopping

  6. Materials and Process Design for High-Temperature Carburizing: Integrating Processing and Performance

    SciTech Connect (OSTI)

    D. Apelian

    2007-07-23

    The objective of the project is to develop an integrated process for fast, high-temperature carburizing. The new process results in an order of magnitude reduction in cycle time compared to conventional carburizing and represents significant energy savings in addition to a corresponding reduction of scrap associated with distortion free carburizing steels.

  7. Black oxide nanoparticles as durable solar absorbing material for high-temperature concentrating solar power system

    E-Print Network [OSTI]

    California at San Diego, University of

    Available online 8 January 2015 Keywords: Concentrating solar power Solar absorber Cobalt oxide Light trapping High temperature a b s t r a c t Concentrating solar power is becoming an increasingly important an increasingly urgent need for human society [1,2]. Concentrating solar power (CSP) systems (or solar thermal sys

  8. Point defects and high temperature creep of NiO single crystals (*) J. Cabrera-Cano

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    durations between 1 h and 18 h have been used, depending on temperature creep test, with no influence on mL-119 Point defects and high temperature creep of NiO single crystals (*) J. Cabrera MPa-150 MPa. Oxygen partial pressures were varied between 10-5 atm. and air. The steady state creep

  9. "Ceramics and high-temperature composites, silicides" Oxidation of Stainless Steel Powder

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    "Ceramics and high-temperature composites, silicides" CHTC9 Oxidation of Stainless Steel Powder. To understand the corrosion behavior of a model 304L(p)-ZrO2(s) composite, a 304L stainless steel powder has stainless steel particles. In this domain a mechanism is proposed and the kp value is calculated both due

  10. An Experimental Test Facility to Support Development of the Fluoride Salt Cooled High Temperature Reactor

    SciTech Connect (OSTI)

    Yoder Jr, Graydon L; Aaron, Adam M; Cunningham, Richard Burns; Fugate, David L; Holcomb, David Eugene; Kisner, Roger A; Peretz, Fred J; Robb, Kevin R; Wilgen, John B; Wilson, Dane F

    2014-01-01

    The need for high-temperature (greater than 600 C) energy exchange and delivery systems is significantly increasing as the world strives to improve energy efficiency and develop alternatives to petroleum-based fuels. Liquid fluoride salts are one of the few energy transport fluids that have the capability of operating at high temperatures in combination with low system pressures. The Fluoride Salt-Cooled High-Temperature Reactor design uses fluoride salt to remove core heat and interface with a power conversion system. Although a significant amount of experimentation has been performed with these salts, specific aspects of this reactor concept will require experimental confirmation during the development process. The experimental facility described here has been constructed to support the development of the Fluoride Salt Cooled High Temperature Reactor concept. The facility is capable of operating at up to 700 C and incorporates a centrifugal pump to circulate FLiNaK salt through a removable test section. A unique inductive heating technique is used to apply heat to the test section, allowing heat transfer testing to be performed. An air-cooled heat exchanger removes added heat. Supporting loop infrastructure includes a pressure control system; trace heating system; and a complement of instrumentation to measure salt flow, temperatures, and pressures around the loop. The initial experiment is aimed at measuring fluoride salt heat transfer inside a heated pebble bed similar to that used for the core of the pebble bed advanced high-temperature reactor. This document describes the details of the loop design, auxiliary systems used to support the facility, the inductive heating system, and facility capabilities.

  11. Hydraulic fracture stimulation treatment of Well Baca 23. Geothermal Reservoir Well-Stimulation Program

    SciTech Connect (OSTI)

    Not Available

    1981-06-01

    Well Stimulation Experiment No. 5 of the Geothermal Reservoir Well Stimulation Program (GRWSP) was performed on March 22, 1981 in Baca 23, located in Union's Redondo Creek Project Area in Sandoval County, New Mexico. The treatment selected was a large hydraulic fracture job designed specifically for, and utilizing frac materials chosen for, the high temperature geothermal environment. The well selection, fracture treatment, experiment evaluation, and summary of the job costs are presented herein.

  12. Reservoir Outflow (RESOUT) Model 

    E-Print Network [OSTI]

    Purvis, Stuart Travis

    1988-01-01

    rating tables for a comprehensive range of outlet structure types and configurations, simulating a dam breach, routing a hydrograph through the reservoir, and performing drawdown analyses. The thesis describes the basic equations and computational... of Rating Curves Rating Curves for Uncontrolled Ogee Spillways Rating Curves for Uncontrolled Broad-crested Spillways Rating Curves for Spillway Gates Rating Curves for Drop Inlet Spillways Rating Curves for Outlet Works Breach Simulation Storage...

  13. Summary of Research through Phase II/Year 2 of Initially Approved 3 Phase/3 Year Project - Establishing the Relationship between Fracture-Related Dolomite and Primary Rock Fabric on the Distribution of Reservoirs in the Michigan Basin

    SciTech Connect (OSTI)

    G. Grammer

    2007-09-30

    This final scientific/technical report covers the first 2 years (Phases I and II of an originally planned 3 Year/3 Phase program). The project was focused on evaluating the relationship between fracture-related dolomite and dolomite constrained by primary rock fabric in the 3 most prolific reservoir intervals in the Michigan Basin. The characterization of select dolomite reservoirs was the major focus of our efforts in Phases I and II of the project. Structural mapping and log analysis in the Dundee (Devonian) and Trenton/Black River (Ordovician) suggest a close spatial relationship among gross dolomite distribution and regional-scale, wrench fault-related NW-SE and NE-SW structural trends. A high temperature origin for much of the dolomite in these 2 studied intervals (based upon fluid inclusion homogenization temperatures and stable isotopic analyses,) coupled with persistent association of this dolomite in reservoirs coincident with wrench fault-related features, is strong evidence for these reservoirs being influenced by hydrothermal dolomitization. In the Niagaran (Silurian), there is a general trend of increasing dolomitization shelfward, with limestone predominant in more basinward positions. A major finding is that facies types, when analyzed at a detailed level, are directly related to reservoir porosity and permeability in these dolomites which increases the predictability of reservoir quality in these units. This pattern is consistent with our original hypothesis of primary facies control on dolomitization and resulting reservoir quality at some level. The identification of distinct and predictable vertical stacking patterns within a hierarchical sequence and cycle framework provides a high degree of confidence at this point that the results should be exportable throughout the basin. Much of the data synthesis and modeling for the project was scheduled to be part of Year 3/Phase III, but the discontinuation of funding after Year 2 precluded those efforts. Therefore, the results presented in this document are not final, and in many cases represent a report of 'progress to date' as numerous tasks were scheduled to extend into Year 3.

  14. PERFORMANCE ANALYSIS OF A WINDOWED HIGH TEMPERATURE GAS RECEIVER USING A SUSPENSION OF ULTRAFINE CARBON PARTICLES AS THE SOLAR ABSORBER

    E-Print Network [OSTI]

    Fisk, William J.

    2012-01-01

    incident solar intensity on receiver efficiency and receiverA,J,, "The Efficiency of High Temperature Solar ReceiversThe efficiency increases with incident solar intensity but

  15. Development of Designer Diamond Technology for High-Pressure-High Temperature Experiments in Support of the Stockpile Stewardship

    SciTech Connect (OSTI)

    Vohra, Yogesh, K.

    2003-08-27

    OAK B127 Development of Designer Diamond Technology for High-Pressure-High Temperature Experiments in Support of the Stockpile Stewardship

  16. Optimization of ferrous burden high temperature properties to meet blast furnace requirements in British Steel

    SciTech Connect (OSTI)

    Bergstrand, R.

    1996-12-31

    The high temperature properties of ferrous burden materials have long been an important consideration in the operation of British Steel blast furnaces. Previous research presented at this conference has shown that the behavior of materials in the lower stack and bosh can have a significant effect on furnace permeability and stability of operation. However, with increasing levels of hydrocarbon injection via the tuyeres, the reduction conditions inside British Steel blast furnaces have significantly altered over recent years. This paper focuses on the further work that has been undertaken to study the effect on ferrous burden high temperatures properties of the widely differing reduction regimes which can be experienced in today`s blast furnaces. The implications of the findings, and how they have been used in optimizing blast furnace operation and burden quality, are discussed.

  17. Super-High Temperature Alloys and Composites from NbW-Cr Systems

    SciTech Connect (OSTI)

    Shailendra Varma

    2008-12-31

    Nickel base superalloys must be replaced if the demand for the materials continues to rise for applications beyond 1000{sup o}C which is the upper limit for such alloys at this time. There are non-metallic materials available for such high temperature applications but they all present processing difficulties because of the lack of ductility. Metallic systems can present a chance to find materials with adequate room temperature ductility. Obviously the system must contain elements with high melting points. Nb has been chosen by many investigators which has a potential of being considered as a candidate if alloyed properly. This research is exploring the Nb-W-Cr system for the possible choice of alloys to be used as a high temperature material.

  18. Development of high temperature solid lubricant coatings. Final report, 15 August 1997--14 August 1998

    SciTech Connect (OSTI)

    Bhattacharya, R.S.; Keller, S.

    1999-01-29

    The primary research objective of this work was to develop a solid lubricant coating that can function over a broad temperature range. The approach investigated consisted of developing adaptive lubricant coating from materials that undergo chemical change with increasing temperature by reacting together and with the environment. To test this approach, UES and Cleveland State University have conducted experiments to form cesium oxythiotungstate, a high temperature lubricant, on Inconel 718 surface from composite coatings of cesium tungstate and tungsten sulfide. The coatings were deposited by RF sputtering and characterized by X-ray Photoelectron Spectroscopy (XPS). The results indicate that sulfur escapes from the composite coating upon exposure to temperature above 5000C in air. Thus, the desired adaptive lubricant phase, cesium oxythiotungstate could not be formed. However, cesium oxythiotungstate phase has been found to form upon annealing at high temperature in vacuum. The friction coefficients of sputtered cesium oxythiotungstate and cesium tungstate coatings have been measured.

  19. Heat treated 9 Cr-1 Mo steel material for high temperature application

    DOE Patents [OSTI]

    Jablonski, Paul D.; Alman, David; Dogan, Omer; Holcomb, Gordon; Cowen, Christopher

    2012-08-21

    The invention relates to a composition and heat treatment for a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650.degree. C. The novel combination of composition and heat treatment produces a heat treated material containing both large primary titanium carbides and small secondary titanium carbides. The primary titanium carbides contribute to creep strength while the secondary titanium carbides act to maintain a higher level of chromium in the finished steel for increased oxidation resistance, and strengthen the steel by impeding the movement of dislocations through the crystal structure. The heat treated material provides improved performance at comparable cost to commonly used high-temperature steels such as ASTM P91 and ASTM P92, and requires heat treatment consisting solely of austenization, rapid cooling, tempering, and final cooling, avoiding the need for any hot-working in the austenite temperature range.

  20. Development of high temperature transport technology for LiCl-KCl eutectic salt in pyroprocessing

    SciTech Connect (OSTI)

    Lee, Sung Ho; Lee, Hansoo; Kim, In Tae; Kim, Jeong-Guk

    2013-07-01

    The development of high-temperature transport technologies for molten salt is a prerequisite and a key issue in the industrialization of pyro-reprocessing for advanced fuel cycle scenarios. The solution of a molten salt centrifugal pump was discarded because of the high corrosion power of a high temperature molten salt, so the suction pump solution was selected. An apparatus for salt transport experiments by suction was designed and tested using LiC-KCl eutectic salt. The experimental results of lab-scale molten salt transport by suction showed a 99.5% transport rate (ratio of transported salt to total salt) under a vacuum range of 100 mtorr - 10 torr at 500 Celsius degrees. The suction system has been integrated to the PRIDE (pyroprocessing integrated inactive demonstration) facility that is a demonstrator using non-irradiated materials (natural uranium and surrogate materials). The performance of the suction pump for the transport of molten salts has been confirmed.

  1. Apparatus and method for removing particulate deposits from high temperature filters

    DOE Patents [OSTI]

    Nakaishi, Curtis V. (Morgantown, WV); Holcombe, Norman T. (McMurray, PA); Micheli, Paul L. (Morgantown, WV)

    1992-01-01

    A combustion of a fuel-air mixture is used to provide a high-temperature and high-pressure pulse of gaseous combustion products for the back-flush cleaning of ceramic filter elements contained in a barrier filter system and utilized to separate particulates from particulate-laden process gases at high temperature and high pressure. The volume of gaseous combustion products provided by the combustion of the fuel-air mixture is preferably divided into a plurality of streams each passing through a sonic orifice and conveyed to the open end of each filter element as a high pressure pulse which passes through the filter elements and dislodges dust cake supported on a surface of the filter element.

  2. High Temperature Gas-Cooled Reactor Projected Markets and Preliminary Economics

    SciTech Connect (OSTI)

    Larry Demick

    2011-08-01

    This paper summarizes the potential market for process heat produced by a high temperature gas-cooled reactor (HTGR), the environmental benefits reduced CO2 emissions will have on these markets, and the typical economics of projects using these applications. It gives examples of HTGR technological applications to industrial processes in the typical co-generation supply of process heat and electricity, the conversion of coal to transportation fuels and chemical process feedstock, and the production of ammonia as a feedstock for the production of ammonia derivatives, including fertilizer. It also demonstrates how uncertainties in capital costs and financial factors affect the economics of HTGR technology by analyzing the use of HTGR technology in the application of HTGR and high temperature steam electrolysis processes to produce hydrogen.

  3. SCALE Code Validation for Prismatic High-Temperature Gas-Cooled Reactors

    SciTech Connect (OSTI)

    Ilas, Dan [ORNL

    2013-01-01

    Using experimental data published in the International Handbook of Evaluated Reactor Physics Benchmark Experiments for the fresh cold core of the High Temperature Engineering Test Reactor, a comprehensive validation study has been carried out to assess the performance of the SCALE code system for analysis of high-temperature gas-cooled reactor configurations. This paper describes part of the results of that effort. The studies performed included criticality evaluations for the full core and for the annular cores realized during the fuel loading, as well as calculations and comparisons for excess reactivity, shutdown margin, control rod worths, temperature coefficient of reactivity, and reaction rate distributions. Comparisons of the SCALE results with both experimental values and MCNP-calculated values are presented. The comparisons show that the SCALE calculated results, obtained with both multigroup and continuous energy cross sections, are in reasonable agreement with the experimental data and the MCNP predictions.

  4. SCALE Code Validation for Prismatic High-Temperature Gas-Cooled Reactors

    SciTech Connect (OSTI)

    Ilas, Dan [ORNL] [ORNL

    2012-01-01

    Using experimental data published in the International Handbook of Evaluated Reactor Physics Benchmark Experiments for the fresh cold core of the High Temperature Engineering Test Reactor, a comprehensive validation study has been carried out to assess the performance of the SCALE code system for analysis of High Temperature Gas-Cooled Reactor (HTGR) configurations. This paper describes part of the results of this effort. The studies performed included criticality evaluations for the full core and for the annular cores realized during the fuel loading, as well as calculations and comparisons for excess reactivity, shutdown margin, control rod worths, temperature coefficient of reactivity, and reaction rate distributions. Comparisons of the SCALE results with both the experimental values and MCNP-calculated values are presented. The comparisons show that the SCALE calculated results, obtained with both multigroup and continuous energy cross sections, are in reasonable agreement with the experimental data. The agreement with the MCNP predictions is, in general, very good.

  5. Novel Carbon Nanotube-Based Nanostructures for High-Temperature Gas Sensing

    SciTech Connect (OSTI)

    Zhi Chen; Kozo Saito

    2008-08-31

    The primary objective of this research is to examine the feasibility of using vertically aligned multi-wall carbon nanotubes (MWCNTs) as a high temperature sensor material for fossil energy systems where reducing atmospheres are present. In the initial period of research, we fabricated capacitive sensors for hydrogen sensing using vertically aligned MWCNTs. We found that CNT itself is not sensitive to hydrogen. Moreover, with the help of Pd electrodes, hydrogen sensors based on CNTs are very sensitive and fast responsive. However, the Pd-based sensors can not withstand high temperature (T<200 C). In the last year, we successfully fabricated a hydrogen sensor based on an ultra-thin nanoporous titanium oxide (TiO{sub 2}) film supported by an AAO substrate, which can operate at 500 C with hydrogen concentrations in a range from 50 to 500 ppm.

  6. Using high temperature baghouses to enhance desulfurization following economizer sorbent injection

    SciTech Connect (OSTI)

    Li, G.; Keener, T.C.

    1995-12-31

    In order to explore the potential of using high temperature baghouses to enhance SO{sub 2} removal following upstream sorbent injection, an integrated two-stage reactor system has been built. It consists of an injection stage and a filtration stage. Distinct from one-stage fixed-bed reactors, sorbent particles in this system are initially converted under controlled injection conditions before entering the filtration reactor chamber. By the aid of the system, several unique features regarding the gas-solid reactions in the baghouse after economizer zone sorbent injection have been revealed. Results have shown that the appropriate usage of a high temperature baghouse may substantially enhance the performance of the process. The further SO{sub 2} removal in the baghouse is comprehensively affected by both the conditions in the injection zone and those in the baghouse.

  7. High Temperature Steam Electrolysis: Demonstration of Improved Long-Term Performance

    SciTech Connect (OSTI)

    J. E. O'Brien; X. Zhang; R. C. O'Brien; G. Tao

    2011-11-01

    Long-term performance is an ongoing issue for hydrogen production based on high-temperature steam electrolysis (HTSE). For commercial deployment, solid-oxide electrolysis stacks must achieve high performance with long-term degradation rates of {approx}0.5%/1000 hours or lower. Significant progress has been achieved toward this goal over the past few years. This paper will provide details of progress achieved under the Idaho National Laboratory high temperature electrolysis research program. Recent long-term stack tests have achieved high initial performance with degradation rates less than 5%/khr. These tests utilize internally manifolded stacks with electrode-supported cells. The cell material sets are optimized for the electrolysis mode of operation. Details of the cells and stacks will be provided along with details of the test apparatus, procedures, and results.

  8. Enhanced oil recovery through water imbibition in fractured reservoirs using Nuclear Magnetic Resonance 

    E-Print Network [OSTI]

    Hervas Ordonez, Rafael Alejandro

    1994-01-01

    Conventional waterflooding methods of oil recovery are difficult to apply when reservoirs show evidence of natural fractures, because injected water advances through paths of high permeability, and oil trapped in the rock matrix system...

  9. INTEGRATION OF HIGH TEMPERATURE GAS REACTORS WITH IN SITU OIL SHALE RETORTING

    SciTech Connect (OSTI)

    Eric P. Robertson; Michael G. McKellar; Lee O. Nelson

    2011-05-01

    This paper evaluates the integration of a high-temperature gas-cooled reactor (HTGR) to an in situ oil shale retort operation producing 7950 m3/D (50,000 bbl/day). The large amount of heat required to pyrolyze the oil shale and produce oil would typically be provided by combustion of fossil fuels, but can also be delivered by an HTGR. Two cases were considered: a base case which includes no nuclear integration, and an HTGR-integrated case.

  10. High-temperature phase transition in a plasma and the mechanism of powerful solar flares

    E-Print Network [OSTI]

    Fedor V. Prigara

    2006-05-04

    It is shown that the high- temperature phase transition in a plasma gives the mechanism of transition from the highly conductive state to the highly resistive state of a plasma in the `electric circuit' model of solar flares which was first introduced by H.Alfven and P.Carlqvist in 1967. With this addendum, the modern version of the electric circuit model can explain both the fast dissipation of energy and the acceleration of particles in a solar flare.

  11. Hybrid sulfur cycle operation for high-temperature gas-cooled reactors

    DOE Patents [OSTI]

    Gorensek, Maximilian B

    2015-02-17

    A hybrid sulfur (HyS) cycle process for the production of hydrogen is provided. The process uses a proton exchange membrane (PEM) SO.sub.2-depolarized electrolyzer (SDE) for the low-temperature, electrochemical reaction step and a bayonet reactor for the high-temperature decomposition step The process can be operated at lower temperature and pressure ranges while still providing an overall energy efficient cycle process.

  12. Method of and apparatus for removing silicon from a high temperature sodium coolant

    DOE Patents [OSTI]

    Yunker, W.H.; Christiansen, D.W.

    1983-11-25

    This patent discloses a method of and system for removing silicon from a high temperature liquid sodium coolant system for a nuclear reactor. The sodium is cooled to a temperature below the silicon saturation temperature and retained at such reduced temperature while inducing high turbulence into the sodium flow for promoting precipitation of silicon compounds and ultimate separation of silicon compound particles from the liquid sodium.

  13. Fabrication and Design Aspects of High-Temperature Compact Diffusion Bonded Heat Exchangers

    SciTech Connect (OSTI)

    Mylavarapu, Sai K.; Sun, Xiaodong; Christensen, Richard N.; Glosup, Richard E.; Unocic, Raymond R

    2012-01-01

    The very high temperature reactor (VHTR), using gas-cooled reactor technology, is one of the six reactor concepts selected by the Generation IV International Forum and is anticipated to be the reactor type for the next generation nuclear plant (NGNP). In this type of reactor with an indirect power cycle system, a high-temperature and high integrity intermediate heat exchanger (IHX) with high effectiveness is required to efficiently transfer the core thermal output to secondary fluid for electricity production, process heat, or hydrogen cogeneration. The current Technology Readiness Level status issued by NGNP to all components associated with the IHX for reactor core outlet temperatures of 750-800oC is 3 on a scale of 1 to 10 with 10 being the most ready. At present, there is no proven high-temperature IHX concept for VHTRs. Amongst the various potential IHX concepts available, diffusion bonded heat exchangers (henceforth called printed circuit heat exchangers, or PCHEs) appear promising for NGNP applications. The design and fabrication of this key component of NGNP is the primary focus of this paper. In the current study, two PCHEs were fabricated using Alloy 617 plates and will be experimentally investigated for their thermal-hydraulic performance in a high-temperature helium test facility (HTHF). The HTHF was primarily designed and constructed to test the thermal-hydraulic performance of PCHEs The test facility is primarily of Alloy 800H construction and is designed to facilitate experiments at temperatures and pressures up to 800oC and 3 MPa, respectively. The PCHE fabrication related processes, i.e., photochemical machining and diffusion bonding are briefly discussed for Alloy 617 plates. Diffusion bonding of Alloy 617 plates with and without a Ni interlayer is discussed. Furthermore, preliminary microstructural and mechanical characterization studies of representative diffusion bonded Alloy 617 specimens are presented.

  14. NGNP: High Temperature Gas-Cooled Reactor Key Definitions, Plant Capabilities, and Assumptions

    SciTech Connect (OSTI)

    Wayne Moe

    2013-05-01

    This document provides key definitions, plant capabilities, and inputs and assumptions related to the Next Generation Nuclear Plant to be used in ongoing efforts related to the licensing and deployment of a high temperature gas-cooled reactor. These definitions, capabilities, and assumptions were extracted from a number of NGNP Project sources such as licensing related white papers, previously issued requirement documents, and preapplication interactions with the Nuclear Regulatory Commission (NRC).

  15. Small-Particle Solar Receiver for High-Temperature Brayton Power Cycles

    Broader source: Energy.gov [DOE]

    This fact sheet describes a scattering solar thermal concentrators project awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. The team, led by San Diego State University, is working to validate, through on-sun testing, the viability of the Small Particle Heat Exchange Receiver concept. If successful, this project team would build the first large-scale, pressurized, high-temperature, gas-cooled solar receiver capable of being deployed commercially.

  16. HTGR (High Temperature Gas-Cooled Reactor) ingress analysis using MINET

    SciTech Connect (OSTI)

    Van Tuyle, G.J.; Yang, J.W.; Kroeger, P.G.; Mallen, A.N.; Aronson, A.L.

    1989-04-01

    Modeling of water/steam ingress into the primary (helium) cooling circuit of a High Temperature Gas-Cooled Reactor (HTGR) is described. This modeling was implemented in the MINET Code, which is a program for analyzing transients in intricate fluid flow and heat transfer networks. Results from the simulation of a water ingress event postulated for the Modular HTGR are discussed. 27 refs., 6 figs., 6 tabs.

  17. High-temperature instability of a Cr{sub 2}Nb-Nb(Cr) microlaminate composite

    SciTech Connect (OSTI)

    Larsen, M.; Rowe, R.G.; Skelly, D.W. [General Electric Corporate Research and Development, Schenectady, NY (United States)

    1996-12-31

    Microlaminate composites consisting of alternating layers of a high temperature intermetallic compound for elevated temperature strength and a ductile refractory metal for toughening may have uses in aircraft engine turbines. Microstructural stability at elevated temperatures is a crucial requirement for these composites. A microlaminate composite consisting of alternating layers of Cr{sub 2}Nb and Nb(Cr) was produced by vapor phase deposition. The stability of the layers at elevated temperatures was investigated by cross-sectional TEM.

  18. Development of High Temperature/High Sensitivity Novel Chemical Resistive Sensor

    SciTech Connect (OSTI)

    Chen, Chonglin; Nash, Patrick; Ma, Chunrui; Enriquez, Erik; Wang, Haibing; Xu, Xing; Bao, Shangyong; Collins, Gregory

    2013-08-13

    The research has been focused to design, fabricate, and develop high temperature/high sensitivity novel multifunctional chemical sensors for the selective detection of fossil energy gases used in power and fuel systems. By systematically studying the physical properties of the LnBaCo{sub 2}O{sub 5+d} (LBCO) [Ln=Pr or La] thin?films, a new concept chemical sensor based high temperature chemical resistant change has been developed for the application for the next generation highly efficient and near zero emission power generation technologies. We also discovered that the superfast chemical dynamic behavior and an ultrafast surface exchange kinetics in the highly epitaxial LBCO thin films. Furthermore, our research indicates that hydrogen can superfast diffuse in the ordered oxygen vacancy structures in the highly epitaxial LBCO thin films, which suggest that the LBCO thin film not only can be an excellent candidate for the fabrication of high temperature ultra sensitive chemical sensors and control systems for power and fuel monitoring systems, but also can be an excellent candidate for the low temperature solid oxide fuel cell anode and cathode materials.

  19. ULTRA-HIGH TEMPERATURE SENSORS BASED ON OPTICAL PROPERTY MODULATION AND VIBRATION-TOLERANT INTERFEROMETRY

    SciTech Connect (OSTI)

    Nabeel A. Riza

    2005-07-22

    The goals of the first six months of this project were to begin laying the foundations for both the SiC front-end optical chip fabrication techniques for high pressure gas species sensing as well as the design, assembly, and test of a portable high pressure high temperature calibration test cell chamber for introducing gas species. This calibration cell will be used in the remaining months for proposed first stage high pressure high temperature gas species sensor experimentation and data processing. All these goals have been achieved and are described in detail in the report. Both design process and diagrams for the mechanical elements as well as the optical systems are provided. Photographs of the fabricated calibration test chamber cell, the optical sensor setup with the calibration cell, the SiC sample chip holder, and relevant signal processing mathematics are provided. Initial experimental data from both the optical sensor and fabricated test gas species SiC chips is provided. The design and experimentation results are summarized to give positive conclusions on the proposed novel high temperature high pressure gas species detection optical sensor technology.

  20. Comparison of diesel spray combustion in different high-temperature, high-pressure facilities.

    SciTech Connect (OSTI)

    Christiansen, Caspar; Hermant, Laurent; Malbec, Louis-Marie; Bruneaux, Gilles; Genzale, Caroline L.; Pickett, Lyle M.; Schramm, Jesper

    2010-05-01

    Diesel spray experiments at controlled high-temperature and high-pressure conditions offer the potential for an improved understanding of diesel combustion, and for the development of more accurate CFD models that will ultimately be used to improve engine design. Several spray chamber facilities capable of high-temperature, high-pressure conditions typical of engine combustion have been developed, but uncertainties about their operation exist because of the uniqueness of each facility. For the IMEM meeting, we describe results from comparative studies using constant-volume vessels at Sandia National Laboratories and IFP. Targeting the same ambient gas conditions (900 K, 60 bar, 22.8 kg/m{sup 3}, 15% oxygen) and sharing the same injector (common rail, 1500 bar, KS1.5/86 nozzle, 0.090 mm orifice diameter, n-dodecane, 363 K), we describe detailed measurements of the temperature and pressure boundary conditions at each facility, followed by observations of spray penetration, ignition, and combustion using high-speed imaging. Performing experiments at the same high-temperature, high-pressure operating conditions is an objective of the Engine Combustion Network (http://www.ca.sandia.gov/ECN/), which seeks to leverage the research capabilities and advanced diagnostics of all participants in the ECN. We expect that this effort will generate a high-quality dataset to be used for advanced computational model development at engine conditions.

  1. Rules for design of Alloy 617 nuclear components to very high temperatures

    SciTech Connect (OSTI)

    Corum, J.M.; Blass, J.J.

    1991-01-01

    Very-high-temperature gas-cooled reactors provide attractive options for electric power generation using a direct gas-turbine cycle and for process-heat applications. For the latter, temperatures of at least 950{degree}C (1742{degree}F) are desirable. As a first step to providing rules for the design of nuclear components operating at very high temperatures, a draft ASME Boiler and Pressure Vessel Code Case has been prepared by an ad hoc Code task force. The Case, which is patterned after the high-temperature nuclear Code Case N-47, covers Ni-Cr-Co-Mo Alloy 617 for temperatures to 982{degree}C (1800{degree}F). The purpose of this paper is to provide a synopsis of the draft Case and the significant differences between it and Case N-47. Particular emphasis is placed on the material behavior and allowables. The paper also recommends some materials and structures development activities that are needed to place the design methodology on a sound and defensible footing. 4 refs., 9 figs., 1 tab.

  2. Thermal degradation mechanisms in GaAs solar cells with high-temperature contacts

    SciTech Connect (OSTI)

    Tobin, S.P.; Bajgar, C.; Vernon, S.M.; Keavney, C.J.; Chung, M.A.; Ruby, D.S.

    1988-01-01

    This objective of this work was to characterize the thermal stability of GaAs solar cells with high-temperature contacts. High-temperature stability is important for threat environments in space, for compatibility with high-temperature assembly techniques, and for enhanced reliability of cells. Our contact system, described previously, relies on a Pt solid-phase ohmic contact, a TiN barrier layer, and an Au conductor, with contact to a heavily doped p-GaAs contact layer. The behavior of both flat-plate and concentrator cells has been characterized as a function of temperature (400-600/degree/C) and time (5-15 minutes) of the anneal. We find that GaAs cells experience minimal electrical degradation up to 550/degree/C for 5 minutes, or to 490/degree/C for 15 minutes. Increases in the 2kT perimeter dark current are responsible for small decreases in Voc and FF up to these temperatures. At higher temperatures a drastic decrease in efficiency is caused by metallurgical reactions at isolated regions along the grid lines. The reaction, which appears to involve Au-Ga, is initiated at the edges of the grid lines. Away from edges, the contacts are metallurgically stable to at least 600/degree/C. 4 refs., 8 figs., 4 tabs.

  3. Considerations of Alloy N for Fluoride Salt-Cooled High-Temperature Reactor Applications

    SciTech Connect (OSTI)

    Ren, Weiju [ORNL; Muralidharan, Govindarajan [ORNL; Wilson, Dane F [ORNL; Holcomb, David Eugene [ORNL

    2011-01-01

    Fluoride Salt-Cooled High-Temperature Reactors (FHRs) are a promising new class of thermal-spectrum nuclear reactors. The reactor structural materials must possess high-temperature strength and chemical compatibility with the liquid fluoride salt as well as with a power cycle fluid such as supercritical water while remaining resistant to residual air within the containment. Alloy N was developed for use with liquid fluoride salts and it possesses adequate strength and chemical compatibility up to about 700 C. A distinctive property of FHRs is that their maximum allowable coolant temperature is restricted by their structural alloy maximum service temperature. As the reactor thermal efficiency directly increases with the maximum coolant temperature, higher temperature resistant alloys are strongly desired. This paper reviews the current status of Alloy N and its relevance to FHRs including its design principles, development history, high temperature strength, environmental resistance, metallurgical stability, component manufacturability, ASME codification status, and reactor service requirements. The review will identify issues and provide guidance for improving the alloy properties or implementing engineering solutions.

  4. Isothermal oxidation behavior of ternary Zr-Nb-Y alloys at high temperature

    SciTech Connect (OSTI)

    Prajitno, Djoko Hadi, E-mail: djokohp@batan.go.id [Research Center for Nuclear Materials and Radiometry, Jl. Tamansari 71, Bandung 40132 (Indonesia); Soepriyanto, Syoni; Basuki, Eddy Agus [Metallurgy Engineering, Institute Technology Bandung, Jl. Ganesha 10, Bandung 40132 (Indonesia); Wiryolukito, Slameto [Materials Engineering, Institute Technology Bandung, Jl. Ganesha 10, Bandung 40132 (Indonesia)

    2014-03-24

    The effect of yttrium content on isothermal oxidation behavior of Zr-2,5%Nb-0,5%Y, Zr-2,5%Nb-1%Y Zr-2,5%Nb-1,5%Y alloy at high temperature has been studied. High temperature oxidation carried out at tube furnace in air at 600,700 and 800°C for 1 hour. Optical microscope is used for microstructure characterization of the alloy. Oxidized and un oxidized specimen was characterized by x-ray diffraction. In this study, kinetic oxidation of Zr-2,5%Nb with different Y content at high temperature has also been studied. Characterization by optical microscope showed that microstructure of Zr-Nb-Y alloys relatively unchanged and showed equiaxed microstructure. X-ray diffraction of the alloys depicted that the oxide scale formed during oxidation of zirconium alloys is monoclinic ZrO2 while unoxidised alloy showed two phase ? and ? phase. SEM-EDS examination shows that depletion of Zr composition took place under the oxide layer. Kinetic rate of oxidation of zirconium alloy showed that increasing oxidation temperature will increase oxidation rate but increasing yttrium content in the alloys will decrease oxidation rate.

  5. High Temperature Strength of YSZ Joints Brazed with Palladium Silver Copper Oxide Filler Metals

    SciTech Connect (OSTI)

    Darsell, Jens T.; Weil, K. Scott

    2010-06-09

    The Ag-CuOx system is being investigated as potential filler metals for use in air brazing high-temperature electrochemical devices such as solid oxide fuel cells and gas concentrators. The current study examines the effects of palladium addition on the high temperature joint strength of specimens prepared from yttria stabilized zirconia (YSZ) bars brazed with the binary Ag-CuOx, and 15Pd-Ag-CuO. It was found that while the binary Ag-CuOx system exhibits stronger room temperature strength than the 15Pd system the strength is reduced to values equivalent of the 15Pd system at 800°C. The 15Pd system exhibits a lower ambient temperature strength that is retained at 800°C. In both systems the failure mechanism at high temperature appears to be peeling of the noble metal component from the oxide phases and tearing through the noble metal phase whereas sufficient adhesion is retained at lower temperatures to cause fracture of the YSZ substrate.

  6. Concept of an inherently-safe high temperature gas-cooled reactor

    SciTech Connect (OSTI)

    Ohashi, Hirofumi; Sato, Hiroyuki; Tachibana, Yukio; Kunitomi, Kazuhiko; Ogawa, Masuro

    2012-06-06

    As the challenge to ensure no harmful release of radioactive materials at the accidents by deterministic approach instead to satisfy acceptance criteria or safety goal for risk by probabilistic approach, new concept of advanced reactor, an inherently-safe high temperature gas-cooled reactor, is proposed based on the experience of the operation of the actual High Temperature Gas-cooled Reactor (HTGR) in Japan, High Temperature Engineering Test Reactor (HTTR), and the design of the commercial plant (GTHTR300), utilizing the inherent safety features of the HTGR (i.e., safety features based on physical phenomena). The safety design philosophy of the inherently-safe HTGR for the safety analysis of the radiological consequences is determined as the confinement of radioactive materials is assured by only inherent safety features without engineered safety features, AC power or prompt actions by plant personnel if the design extension conditions occur. Inherent safety features to prevent the loss or degradation of the confinement function are identified. It is proposed not to apply the probabilistic approach for the evaluation of the radiological consequences of the accidents in the safety analysis because no inherent safety features fail for the mitigation of the consequences of the accidents. Consequently, there are no event sequences to harmful release of radioactive materials if the design extension conditions occur in the inherently-safe HTGR concept. The concept and future R and D items for the inherently-safe HTGR are described in this paper.

  7. All-optical Reservoir Computing

    E-Print Network [OSTI]

    Duport, François; Smerieri, Anteo; Haelterman, Marc; Massar, Serge

    2012-01-01

    Reservoir Computing is a novel computing paradigm which uses a nonlinear recurrent dynamical system to carry out information processing. Recent electronic and optoelectronic Reservoir Computers based on an architecture with a single nonlinear node and a delay loop have shown performance on standardized tasks comparable to state-of-the-art digital implementations. Here we report an all-optical implementation of a Reservoir Computer, made of off-the-shelf components for optical telecommunications. It uses the saturation of a semiconductor optical amplifier as nonlinearity. The present work shows that, within the Reservoir Computing paradigm, all-optical computing with state-of-the-art performance is possible.

  8. Discrete Fracture Reservoir Simulation

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalentLaboratory | National NuclearDiscoveringDiscrete Fracture Reservoir

  9. Studies Related to the Oregon State University High Temperature Test Facility: Scaling, the Validation Matrix, and Similarities to the Modular High Temperature Gas-Cooled Reactor

    SciTech Connect (OSTI)

    Richard R. Schultz; Paul D. Bayless; Richard W. Johnson; William T. Taitano; James R. Wolf; Glenn E. McCreery

    2010-09-01

    The Oregon State University (OSU) High Temperature Test Facility (HTTF) is an integral experimental facility that will be constructed on the OSU campus in Corvallis, Oregon. The HTTF project was initiated, by the U.S. Nuclear Regulatory Commission (NRC), on September 5, 2008 as Task 4 of the 5 year High Temperature Gas Reactor Cooperative Agreement via NRC Contract 04-08-138. Until August, 2010, when a DOE contract was initiated to fund additional capabilities for the HTTF project, all of the funding support for the HTTF was provided by the NRC via their cooperative agreement. The U.S. Department of Energy (DOE) began their involvement with the HTTF project in late 2009 via the Next Generation Nuclear Plant project. Because the NRC interests in HTTF experiments were only centered on the depressurized conduction cooldown (DCC) scenario, NGNP involvement focused on expanding the experimental envelope of the HTTF to include steady-state operations and also the pressurized conduction cooldown (PCC). Since DOE has incorporated the HTTF as an ingredient in the NGNP thermal-fluids validation program, several important outcomes should be noted: 1. The reference prismatic reactor design, that serves as the basis for scaling the HTTF, became the modular high temperature gas-cooled reactor (MHTGR). The MHTGR has also been chosen as the reference design for all of the other NGNP thermal-fluid experiments. 2. The NGNP validation matrix is being planned using the same scaling strategy that has been implemented to design the HTTF, i.e., the hierarchical two-tiered scaling methodology developed by Zuber in 1991. Using this approach a preliminary validation matrix has been designed that integrates the HTTF experiments with the other experiments planned for the NGNP thermal-fluids verification and validation project. 3. Initial analyses showed that the inherent power capability of the OSU infrastructure, which only allowed a total operational facility power capability of 0.6 MW, is inadequate to permit steady-state operation at reasonable conditions. 4. To enable the HTTF to operate at a more representative steady-state conditions, DOE recently allocated funding via a DOE subcontract to HTTF to permit an OSU infrastructure upgrade such that 2.2 MW will become available for HTTF experiments. 5. Analyses have been performed to study the relationship between HTTF and MHTGR via the hierarchical two-tiered scaling methodology which has been used successfully in the past, e.g., APEX facility scaling to the Westinghouse AP600 plant. These analyses have focused on the relationship between key variables that will be measured in the HTTF to the counterpart variables in the MHTGR with a focus on natural circulation, using nitrogen as a working fluid, and core heat transfer. 6. Both RELAP5-3D and computational fluid dynamics (CD-Adapco’s STAR-CCM+) numerical models of the MHTGR and the HTTF have been constructed and analyses are underway to study the relationship between the reference reactor and the HTTF. The HTTF is presently being designed. It has ¼-scaling relationship to the MHTGR in both the height and the diameter. Decisions have been made to design the reactor cavity cooling system (RCCS) simulation as a boundary condition for the HTTF to ensure that (a) the boundary condition is well defined and (b) the boundary condition can be modified easily to achieve the desired heat transfer sink for HTTF experimental operations.

  10. Stopping of directed energetic electrons in high-temperature hydrogenic plasmas C. K. Li and R. D. Petrasso

    E-Print Network [OSTI]

    Stopping of directed energetic electrons in high-temperature hydrogenic plasmas C. K. Li and R. D, the interaction of directed energetic electrons with a high-temperature hydro- genic plasma is analytically modeled. The randomizing effect of scattering off both plasma ions and electrons is treated from a unified

  11. A New Experimental Approach for In-situ Damage Assessment in Fibrous Ceramic Matrix Composites at High Temperature

    E-Print Network [OSTI]

    Daly, Samantha

    A New Experimental Approach for In-situ Damage Assessment in Fibrous Ceramic Matrix Composites). Abstract High temperature applications of ceramic matrix composites (CMCs) necessitate a rigorous next generation of high-temperature ceramic composites for aerospace applications will experience more

  12. HIGH-TEMPERATURE FRACTURE AND FATIGUE RESISTANCE OF A DUCTILE b-TiNb REINFORCED g-TiAl

    E-Print Network [OSTI]

    Ritchie, Robert

    are in part aimed at improving their low room-temperature ten- sile ductility and fracture toughness, bothHIGH-TEMPERATURE FRACTURE AND FATIGUE RESISTANCE OF A DUCTILE b-TiNb REINFORCED g the fracture toughness of g-TiAl, even at high temperatures, from about 12 to H40 MPa m1/2 , although

  13. Mise-a-la-masse mapping of the HGP-A geothermal reservoir, Hawaii

    SciTech Connect (OSTI)

    Kauahikaua, J.; Mattice, M.; Jackson, D.

    1980-09-01

    The HGP-A well casing was used as an electrode in a mise-a-la-masse experiment to define the boundaries of the geothermal reservoir. Electric potentials were measured to distances of 2 km from the drill hole. Although cased or lined the full 1967 m, only the top 670 m of the HGP-A casing are electrically continuous; the electrode did not extend into the high-temperature part of the reservoir. Nevertheless, the data did define a compartment of dike-impounded freshwater of higher resistivity than the surrounding saltwater-saturated rock. This dike-impounded water is warm and apparently overlies the actual reservoir; however, the lateral boundaries impounding this water probably confine geothermal fluids at depth.

  14. 120 GRC BULLETIN Reservoir Engineering

    E-Print Network [OSTI]

    Foulger, G. R.

    of The Geysers geothermal area. The production area is shaded grey. Red dots: seismometers with vertical sensors120 GRC BULLETIN Reservoir Engineering nergy production at geothermal areas causes physical changes Tool Use of Time-Dependent MEQ Tomography for Monitoring Producing Geothermal Reservoirs G. R. Foulger

  15. Water resources review: Ocoee reservoirs, 1990

    SciTech Connect (OSTI)

    Cox, J.P.

    1990-08-01

    Tennessee Valley Authority (TVA) is preparing a series of reports to make technical information on individual TVA reservoirs readily accessible. These reports provide a summary of reservoir purpose and operation; physical characteristics of the reservoir and watershed; water quality conditions; aquatic biological conditions; and designated, actual and potential uses of the reservoir and impairments of those use. This reservoir status report addressed the three Ocoee Reservoirs in Polk County, Tennessee.

  16. ANALYSIS OF PRODUCTION DECLINE IN GEOTHERMAL RESERVOIRS

    E-Print Network [OSTI]

    Zais, E.J.; Bodvarsson, G.

    2008-01-01

    Petroleum Reservoirs. Geothermal Reservoirs IV. DATA1970, Superheating of Geothermal Steam, Proc. of the U.N.the Development & Utilization of Geothermal Resources, Pisa.

  17. Modeling of Geothermal Reservoirs: Fundamental Processes, Computer...

    Open Energy Info (EERE)

    Abstract This article attempts to critically evaluate the present state of the art of geothermal reservoir simulation. Methodological aspects of geothermal reservoir...

  18. Secondary Heat Exchanger Design and Comparison for Advanced High Temperature Reactor

    SciTech Connect (OSTI)

    Piyush Sabharwall; Ali Siahpush; Michael McKellar; Michael Patterson; Eung Soo Kim

    2012-06-01

    The goals of next generation nuclear reactors, such as the high temperature gas-cooled reactor and advance high temperature reactor (AHTR), are to increase energy efficiency in the production of electricity and provide high temperature heat for industrial processes. The efficient transfer of energy for industrial applications depends on the ability to incorporate effective heat exchangers between the nuclear heat transport system and the industrial process heat transport system. The need for efficiency, compactness, and safety challenge the boundaries of existing heat exchanger technology, giving rise to the following study. Various studies have been performed in attempts to update the secondary heat exchanger that is downstream of the primary heat exchanger, mostly because its performance is strongly tied to the ability to employ more efficient conversion cycles, such as the Rankine super critical and subcritical cycles. This study considers two different types of heat exchangers—helical coiled heat exchanger and printed circuit heat exchanger—as possible options for the AHTR secondary heat exchangers with the following three different options: (1) A single heat exchanger transfers all the heat (3,400 MW(t)) from the intermediate heat transfer loop to the power conversion system or process plants; (2) Two heat exchangers share heat to transfer total heat of 3,400 MW(t) from the intermediate heat transfer loop to the power conversion system or process plants, each exchanger transfers 1,700 MW(t) with a parallel configuration; and (3) Three heat exchangers share heat to transfer total heat of 3,400 MW(t) from the intermediate heat transfer loop to the power conversion system or process plants. Each heat exchanger transfers 1,130 MW(t) with a parallel configuration. A preliminary cost comparison will be provided for all different cases along with challenges and recommendations.

  19. Intelligent Monitoring System with High Temperature Distributed Fiberoptic Sensor for Power Plant Combustion Processes

    SciTech Connect (OSTI)

    Kwang Y. Lee; Stuart S. Yin; Andre Boehman

    2006-09-26

    The objective of the proposed work is to develop an intelligent distributed fiber optical sensor system for real-time monitoring of high temperature in a boiler furnace in power plants. Of particular interest is the estimation of spatial and temporal distributions of high temperatures within a boiler furnace, which will be essential in assessing and controlling the mechanisms that form and remove pollutants at the source, such as NOx. The basic approach in developing the proposed sensor system is three fold: (1) development of high temperature distributed fiber optical sensor capable of measuring temperatures greater than 2000 C degree with spatial resolution of less than 1 cm; (2) development of distributed parameter system (DPS) models to map the three-dimensional (3D) temperature distribution for the furnace; and (3) development of an intelligent monitoring system for real-time monitoring of the 3D boiler temperature distribution. Under Task 1, we have set up a dedicated high power, ultrafast laser system for fabricating in-fiber gratings in harsh environment optical fibers, successfully fabricated gratings in single crystal sapphire fibers by the high power laser system, and developed highly sensitive long period gratings (lpg) by electric arc. Under Task 2, relevant mathematical modeling studies of NOx formation in practical combustors have been completed. Studies show that in boiler systems with no swirl, the distributed temperature sensor may provide information sufficient to predict trends of NOx at the boiler exit. Under Task 3, we have investigated a mathematical approach to extrapolation of the temperature distribution within a power plant boiler facility, using a combination of a modified neural network architecture and semigroup theory. Given a set of empirical data with no analytic expression, we first developed an analytic description and then extended that model along a single axis.

  20. Intelligent Monitoring System With High Temperature Distributed Fiberoptic Sensor For Power Plant Combustion Processes

    SciTech Connect (OSTI)

    Kwang Y. Lee; Stuart S. Yin; Andre Boheman

    2005-12-26

    The objective of the proposed work is to develop an intelligent distributed fiber optical sensor system for real-time monitoring of high temperature in a boiler furnace in power plants. Of particular interest is the estimation of spatial and temporal distributions of high temperatures within a boiler furnace, which will be essential in assessing and controlling the mechanisms that form and remove pollutants at the source, such as NOx. The basic approach in developing the proposed sensor system is three fold: (1) development of high temperature distributed fiber optical sensor capable of measuring temperatures greater than 2000 C degree with spatial resolution of less than 1 cm; (2) development of distributed parameter system (DPS) models to map the three-dimensional (3D) temperature distribution for the furnace; and (3) development of an intelligent monitoring system for real-time monitoring of the 3D boiler temperature distribution. Under Task 1, we set up a dedicated high power, ultrafast laser system for fabricating in-fiber gratings in harsh environment optical fibers, successfully fabricated gratings in single crystal sapphire fibers by the high power laser system, and developed highly sensitive long period gratings (lpg) by electric arc. Under Task 2, relevant mathematical modeling studies of NOx formation in practical combustors. Studies show that in boiler systems with no swirl, the distributed temperature sensor may provide information sufficient to predict trends of NOx at the boiler exit. Under Task 3, we investigate a mathematical approach to extrapolation of the temperature distribution within a power plant boiler facility, using a combination of a modified neural network architecture and semigroup theory. The 3D temperature data is furnished by the Penn State Energy Institute using FLUENT. Given a set of empirical data with no analytic expression, we first develop an analytic description and then extend that model along a single axis. Extrapolation capability was demonstrated for estimating enthalpy in a power plant.

  1. System Evaluation and Economic Analysis of a HTGR Powered High-Temperature Electrolysis Hydrogen Production Plant

    SciTech Connect (OSTI)

    Michael G. McKellar; Edwin A. Harvego; Anastasia A. Gandrik

    2010-10-01

    A design for a commercial-scale high-temperature electrolysis (HTE) plant for hydrogen production has been developed. The HTE plant is powered by a high-temperature gas-cooled reactor (HTGR) whose configuration and operating conditions are based on the latest design parameters planned for the Next Generation Nuclear Plant (NGNP). The current HTGR reference design specifies a reactor power of 600 MWt, with a primary system pressure of 7.0 MPa, and reactor inlet and outlet fluid temperatures of 322°C and 750°C, respectively. The power conversion unit will be a Rankine steam cycle with a power conversion efficiency of 40%. The reference hydrogen production plant operates at a system pressure of 5.0 MPa, and utilizes a steam-sweep system to remove the excess oxygen that is evolved on the anode (oxygen) side of the electrolyzer. The overall system thermal-to-hydrogen production efficiency (based on the higher heating value of the produced hydrogen) is 40.4% at a hydrogen production rate of 1.75 kg/s and an oxygen production rate of 13.8 kg/s. An economic analysis of this plant was performed with realistic financial and cost estimating assumptions. The results of the economic analysis demonstrated that the HTE hydrogen production plant driven by a high-temperature helium-cooled nuclear power plant can deliver hydrogen at a cost of $3.67/kg of hydrogen assuming an internal rate of return, IRR, of 12% and a debt to equity ratio of 80%/20%. A second analysis shows that if the power cycle efficiency increases to 44.4%, the hydrogen production efficiency increases to 42.8% and the hydrogen and oxygen production rates are 1.85 kg/s and 14.6 kg/s respectively. At the higher power cycle efficiency and an IRR of 12% the cost of hydrogen production is $3.50/kg.

  2. Method For Manufacturing Articles For High Temperature Use, And Articles Made Therewith

    DOE Patents [OSTI]

    Wang, Hongyu (Hockessin, DE); Mitchell, David Joseph (Niskayuna, NY); Lau, Yuk-Chiu (Ballston Lake, NY); Henry, Arnold Thomas (Gloversville, NY)

    2006-02-28

    A method for manufacturing an article for use in a high-temperature environment, and an article for use in such an environment, are presented. The method comprises providing a substrate; selecting a desired vertical crack density for a protective coating to be deposited on the substrate; providing a powder, wherein the powder has a size range selected to provide a coating having the desired vertical crack density; and applying a thermal-sprayed coating to the substrate, the coating having the desired vertical crack density, wherein the powder is used as a raw material for the coating.

  3. Method For Manufacturing Articles For High Temperature Use, And Articles Made Therewith

    DOE Patents [OSTI]

    Wang, Hongyu (Hockessin, DE); Mitchell, David Joseph (Niskayuna, NY); Lau, Yuk-Chiu (Ballston Lake, NY); Henry, Arnold Thomas (Gloversville, NY)

    2005-03-15

    A method for manufacturing an article for use in a high-temperature environment, and an article for use in such an environment, are presented. The method comprises providing a substrate; selecting a desired vertical crack density for a protective coating to be deposited on the substrate; providing a powder, wherein the powder has a size range selected to provide a coating having the desired vertical crack density; and applying a thermal-sprayed coating to the substrate, the coating having the desired vertical crack density, wherein the powder is used as a raw material for the coating.

  4. Determination of thermodynamic and kinetic properties of grain boundaries using high temperature calorimetry

    SciTech Connect (OSTI)

    Terwilliger, C.D.; Chiang, Y.M. (Massachusetts Inst. of Tech., Cambridge, MA (USA)); Eastman, J.A.; Liao, Y. (Argonne National Lab., IL (USA))

    1991-06-01

    This work explores the use of high temperature differential scanning calorimetry as a novel way in which to measure thermodynamic and kinetic properties of grain boundaries in ceramics. A calorimetric study of grain growth has become practical only recently, with the development of processing methods for nanocrystalline materials (10--50 nm grain size) that have enough grain boundary area and thus grain boundary excess properties to be detected by commercial calorimeters. Here we report results from experiments on nanocrystalline silicon and titanium dioxide. 14 refs., 6 figs.

  5. DESIGN OF A COMPACT HEAT EXCHANGER FOR HEAT RECUPERATION FROM A HIGH TEMPERATURE ELECTROLYSIS SYSTEM

    SciTech Connect (OSTI)

    G. K. Housley; J.E. O'Brien; G.L. Hawkes

    2008-11-01

    Design details of a compact heat exchanger and supporting hardware for heat recuperation in a high-temperature electrolysis application are presented. The recuperative heat exchanger uses a vacuum-brazed plate-fin design and operates between 300 and 800°C. It includes corrugated inserts for enhancement of heat transfer coefficients and extended heat transfer surface area. Two recuperative heat exchangers are required per each four-stack electrolysis module. The heat exchangers are mated to a base manifold unit that distributes the inlet and outlet flows to and from the four electrolysis stacks. Results of heat exchanger design calculations and assembly details are also presented.

  6. Enhanced High Temperature Performance of NOx Storage/Reduction (NSR) Materials

    SciTech Connect (OSTI)

    Kim, Do Heui; Muntean, George G.; Peden, Charles HF; Howden, Ken; Currier, Neal; Li, Junhui; Stafford, Randy; Yezerets, Aleksey; Chen, Hai Ying; Hess, Howard .

    2012-02-08

    This annual report describes progress on a CRADA project aimed at developing a fundamental understanding of candidate next generation NSR materials for NOx after-treatment for light-duty lean-burn (including diesel) engines. Model catalysts that are based on literature formulations are the focus of the work being carried out at PNNL. In addition, the performance and stability of a realistic high temperature NSR catalyst, supplied by JM, is being studied in order to provide baseline data for the model catalysts that are, again, based on formulations described in the open literature.

  7. The Development and Field Testing of a High Temperature Ceramic Recuperator 

    E-Print Network [OSTI]

    Childs, F. W.; Sohal, M. S.

    1986-01-01

    AND FIELD TESTING OF A HIGH TEMPERATURE CERAMIC RECUPERATOR* F. W. Childs and M. S. Sohal EG&G Idaho, Inc., Idaho Falls, Idaho ABSTRACT Under cost-shared funding with the U.S. Department of Energy and the Gas Research Institute, Ai... RECUPERATOR --(!)--- /' X H A GAS METALLICFLUE U RECUPERATOR 5 T FAN COMBUSTION AIR BLOWER TO BURNER +---..J 2.ooo o F / DILUTIOIIiI AIR COIIiITROL FOR: e'IOO?F METALLIC RECUpeRATOR LIMIT ezooo?F BURIIiIER LIMIT Figure 1. Hybrid...

  8. Residence time distribution studies in a multiphase reactor under high temperature and pressure conditions

    SciTech Connect (OSTI)

    Nalitham, R.V.; Davies, O.L.

    1987-06-01

    The residence time distribution of the slurry phase in a coal liquefaction reactor is determined experimentally under high temperature and pressure conditions using native radioactive tracers. The experimental data are fitted to several exit age distribution models, and a model is selected based on the best fit. The effect of process conditions such as recycle gas rate, coal feed rate, reactor temperature, and solvent-to-coal ratio on the degree of backmixing and mean residence time is studied. Gas holdup is estimated from the experimental mean residence time, the nominal residence time, and the total reactor holdup. The effect of gas superficial velocity on gas holdup is studied.

  9. Corrosion resistant positive electrode for high-temperature, secondary electrochemical cell

    DOE Patents [OSTI]

    Otto, N.C.; Warner, B.T.; Smaga, J.A.; Battles, J.E.

    1982-07-07

    The corrosion rate of low carbon steel within a positive electrode of a high-temperature, secondary electrochemical cell that includes FeS as active material is substantially reduced by incorporating therein finely divided iron powder in stoichiometric excess to the amount required to form FeS in the fully charged electrode. The cell typically includes an alkali metal or alkaline earth metal as negative electrode active material and a molten metal halide salt as electrolyte. The excess iron permits use of inexpensive carbon steel alloys that are substantially free of the costly corrosion resistant elements chromium, nickel and molybdenum while avoiding shorten cell life resulting from high corrosion rates.

  10. Possible Routes to Frictionless Transport of Electronic Fluids in High-Temperature Superconductors

    E-Print Network [OSTI]

    Zotin K-H Chu

    2009-12-23

    Electric-field-driven transport of electronic fluids in metallic glasses as well as three-dimensional amorphous superconductors are investigated by using the verified approach which has been successfully adopted to study the critical transport of glassy solid helium in very low temperature environment. The critical temperatures related to the nearly frictionless transport of electronic fluids were found to be directly relevant to the superconducting temperature of amorphous superconductors after selecting specific activation energies. Our results imply that optimal shear-thinning is an effective way to reach high-temperature charged superfluidity or superconductivity.

  11. On the Free Energy of Noncommutative Quantum Electrodynamics at High Temperature

    E-Print Network [OSTI]

    F. T. Brandt; J. Frenkel; C. M. Muramoto

    2006-09-28

    We compute higher order contributions to the free energy of noncommutative quantum electrodynamics at a nonzero temperature $T$. Our calculation includes up to three-loop contributions (fourth order in the coupling constant $e$). In the high temperature limit we sum all the {\\it ring diagrams} and obtain a result which has a peculiar dependence on the coupling constant. For large values of $e\\theta T^2$ ($\\theta$ is the magnitude of the noncommutative parameters) this non-perturbative contribution exhibits a non-analytic behavior proportional to $e^3$. We show that above a certain critical temperature, there occurs a thermodynamic instability which may indicate a phase transition.

  12. High temperature support apparatus and method of use for casting materials

    DOE Patents [OSTI]

    Clark, Roger F; Cliber, James A; Stoddard, Nathan G; Gerber, Jesse I; Roberts, Raymond J; Wilmerton, Mark A

    2015-02-10

    This invention relates to a system and a method of use for large ceramic member support and manipulation at elevated temperatures in non-oxidizing atmospheres, such as using carbon-carbon composite materials for producing high purity silicon in the manufacture of solar modules. The high temperature apparatus of this invention includes one or more support ribs, one or more cross braces in combination with the one or more support ribs, and a shaped support liner positionable upon the one or more support ribs and the one or more cross braces.

  13. Fragile charge order in the non-superconducting ground state of the underdoped high temperature superconductors

    E-Print Network [OSTI]

    Tan, B. S.; Harrison, N.; Zhu, Z.; Balakirev, F. F.; Ramshaw, B. J.; Srivastava, A.; Sabok, S. A.; Dabrowski, B.; Lonzarich, G. G.; Sebastian, Suchitra E.

    2015-05-28

    Fragile charge order in the non-superconducting ground state of the underdoped high temperature superconductors B. S. Tan1, N. Harrison2, Z. Zhu2, F. F. Balakirev2, B. J. Ramshaw2, A. Srivastava1, S. A. Sabok3, B. Dabrowski3, G. G. Lonzarich1... (Dated: April 2, 2015) The normal state in the hole underdoped copper oxide superconductors has proven to be a source of mystery for decades. The measurement of a small Fermi surface by quantum oscillations on suppression of superconductivity by high...

  14. Assessment of selected conservation measures for high-temperature process industries

    SciTech Connect (OSTI)

    Kusik, C L; Parameswaran, K; Nadkarni, R; O'Neill, J K; Malhotra, S; Hyde, R; Kinneberg, D; Fox, L; Rossetti, M

    1981-01-01

    Energy conservation projects involving high-temperature processes in various stages of development are assessed to quantify their energy conservation potential; to determine their present status of development; to identify their research and development needs and estimate the associated costs; and to determine the most effective role for the Federal government in developing these technologies. The program analyzed 25 energy conserving processes in the iron and steel, aluminium, copper, magnesium, cement, and glassmaking industries. A preliminary list of other potential energy conservation projects in these industries is also presented in the appendix. (MCW)

  15. Materials for high-temperature hydrogen fluorine environments. Final report, June 1976-December 1978

    SciTech Connect (OSTI)

    Holcombe, C.E. Jr.; Kovach, L.

    1981-03-01

    A determination has been made of the stability of 35 materials under high-temperature, fluorine rich, hydrogen fluoride torch testing. Refractory materials tested included 4 borides, 3 carbides, 3 nitrides, 12 oxides, 1 oxynitride, 1 sulfide, 10 metals, and carbon (10 types). Three materials distinctly performed better than nickel: lanthanum hexaboride, calcium hexaboride, and lanthanum silicon oxynitride. Of these, lanthanum hexaboride is the best candidate tested since it has an estimated upper use temperature > 1726 K, which is above the melting point and more than 300 K above the upper use temperature of nickel.

  16. Ab-initio study of high temperature lattice dynamics of BCC zirconium (?-Zr) and uranium (?-U)

    SciTech Connect (OSTI)

    Ghosh, Partha S., E-mail: parthasarathi13@gmail.com; Arya, A., E-mail: parthasarathi13@gmail.com; Dey, G. K., E-mail: parthasarathi13@gmail.com [Materials Science Division, Bhabha Atomic Research Centre, Mumbai-400085 (India)

    2014-04-24

    Using self consistent ab-initio lattice dynamics calculations, we show that bcc structures of Zr and U phases become stable at high temperature by phonon-phonon interactions. The calculated temperature dependent phonon dispersion curve (PDC) of ?-Zr match excellently with experimental PDC. But the calculated PDC for ?-U shows negative phonon frequencies even at solid to liquid transition temperature. We show that this discrepancy is due to an overestimation of instability depth of bcc U phase which is removed by incorporation of spin-orbit coupling in the electronic structure calculations.

  17. Mechanisms Governing the Creep Behavior of High Temperature Alloys for Generation IV Nuclear Energy Systems

    SciTech Connect (OSTI)

    Vasudevan, Vijay; Carroll, Laura; Sham, Sam

    2015-04-06

    This research project, which includes collaborators from INL and ORNL, focuses on the study of alloy 617 and alloy 800H that are candidates for applications as intermediate heat exchangers in GEN IV nuclear reactors, with an emphasis on the effects of grain size, grain boundaries and second phases on the creep properties; the mechanisms of dislocation creep, diffusional creep and cavitation; the onset of tertiary creep; and theoretical modeling for long-term predictions of materials behavior and for high temperature alloy design.

  18. High temperature materials technology for industrial energy systems and processes. Final report, April 1984-May 1986

    SciTech Connect (OSTI)

    Bortz, S.A.

    1986-06-01

    GRI is pursuing new technologies that will improve the performance of natural gas in industrial processes and enable natural gas to be competitive in the industrial sector with other energy alternatives. The program focused on three areas of interest that require establishing a ceramic materials data base for technical input to GRI's RandD planning efforts. These areas are: Ceramics for Heat-Exchanger Applications in High-Temperature Corrosive Flue Streams; Advanced Material and Component Technology for Gas-Fueled Prime Movers; and Gas-Fired Indirect Heating and Melting Systems.

  19. Examination of charge transfer in Au/YSZ for high-temperature optical gas sensing

    SciTech Connect (OSTI)

    Baltrus, John P.; Ohodnicki, Paul R.

    2014-01-01

    Au-nanoparticle incorporated oxide thin film materials demonstrate significant promise as functionalsensor materials for high temperature optical gas sensing in severe environments relevant for fossil andnuclear based power generation. The Au/yttria-stabilized zirconia (YSZ) system has been extensivelystudied in the literature and serves as a model system for fundamental investigations that seek to betterunderstand the mechanistic origin of the plasmonic gas sensing response. In this work, X-ray photoelec-tron spectroscopy techniques are applied to Au/YSZ films in an attempt to provide further experimentalevidence for a proposed sensing mechanism involving a change in free carrier density of Au nanoparticles due to charge transfer.

  20. General information for operation of the high-temperature electromagnetic containerless vacuum induction furnace

    SciTech Connect (OSTI)

    Hahs, C.A.; Fox, R.J.

    1994-06-01

    The High-Temperature Electromagnetic Containerless Vacuum Induction Furnace was developed at Oak Ridge National Laboratory for the National Aeronautics and Space Administration (NASA), Marshall Space Flight Center, Alabama. The high-efficiency radio-frequency system developed for the conceptual design of the Modular Electromagnetic Levitator was created to evaluate this hardware on the KC135 microgravity airplane operated by NASA. Near-future KC135 flights are being planned to levitate, melt, and undercool 5-mm samples of niobium. General information on the operation of this hardware is included.