Sample records for high-pressure steam produced

  1. BILIWG Meeting: High Pressure Steam Reforming of Bio-Derived...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Pressure Steam Reforming of Bio-Derived Liquids (Presentation) BILIWG Meeting: High Pressure Steam Reforming of Bio-Derived Liquids (Presentation) Presented at the 2007...

  2. Steam Oxidation at High Pressure

    SciTech Connect (OSTI)

    Holcomb, Gordon R. [NETL; Carney, Casey [URS

    2013-07-19T23:59:59.000Z

    A first high pressure test was completed: 293 hr at 267 bar and 670{degrees}C; A parallel 1 bar test was done for comparison; Mass gains were higher for all alloys at 267 bar than at 1 bar; Longer term exposures, over a range of temperatures and pressures, are planned to provide information as to the commercial implications of pressure effects; The planned tests are at a higher combination of temperatures and pressures than in the existing literature. A comparison was made with longer-term literature data: The short term exposures are largely consistent with the longer-term corrosion literature; Ferritic steels--no consistent pressure effect; Austenitic steels--fine grain alloys less able to maintain protective chromia scale as pressure increases; Ni-base alloys--more mass gains above 105 bar than below. Not based on many data points.

  3. Apparatus and methods of reheating gas turbine cooling steam and high pressure steam turbine exhaust in a combined cycle power generating system

    DOE Patents [OSTI]

    Tomlinson, Leroy Omar (Niskayuna, NY); Smith, Raub Warfield (Ballston Lake, NY)

    2002-01-01T23:59:59.000Z

    In a combined cycle system having a multi-pressure heat recovery steam generator, a gas turbine and steam turbine, steam for cooling gas turbine components is supplied from the intermediate pressure section of the heat recovery steam generator supplemented by a portion of the steam exhausting from the HP section of the steam turbine, steam from the gas turbine cooling cycle and the exhaust from the HP section of the steam turbine are combined for flow through a reheat section of the HRSG. The reheated steam is supplied to the IP section inlet of the steam turbine. Thus, where gas turbine cooling steam temperature is lower than optimum, a net improvement in performance is achieved by flowing the cooling steam exhausting from the gas turbine and the exhaust steam from the high pressure section of the steam turbine in series through the reheater of the HRSG for applying steam at optimum temperature to the IP section of the steam turbine.

  4. Split stream boilers for high-temperature/high-pressure topping steam turbine combined cycles

    SciTech Connect (OSTI)

    Rice, I.G. [Rice (I.G.), Spring, TX (United States)

    1997-04-01T23:59:59.000Z

    Research and development work on high-temperature and high-pressure (up to 1,500 F TIT and 4,500 psia) topping steam turbines and associated steam generators for steam power plants as well as combined cycle plants is being carried forward by DOE, EPRI, and independent companies. Aeroderivative gas turbines and heavy-duty gas turbines both will require exhaust gas supplementary firing to achieve high throttle temperatures. This paper presents an analysis and examples of a split stream boiler arrangement for high-temperature and high-pressure topping steam turbine combined cycles. A portion of the gas turbine exhaust flow is run in parallel with a conventional heat recovery steam generator (HRSG). This side stream is supplementary fired opposed to the current practice of full exhaust flow firing. Chemical fuel gas recuperation can be incorporated in the side stream as an option. A significant combined cycle efficiency gain of 2 to 4 percentage points can be realized using this split stream approach. Calculations and graphs show how the DOE goal of 60 percent combined cycle efficiency burning natural gas fuel can be exceeded. The boiler concept is equally applicable to the integrated coal gas fuel combined cycle (IGCC).

  5. Enrichment of HFSE in chlorite-harzburgite produced by high-pressure dehydration of antigorite-serpentinite

    E-Print Network [OSTI]

    Demouchy, Sylvie

    Enrichment of HFSE in chlorite-harzburgite produced by high-pressure dehydration of antigorite of antigorite-serpentinite produces chlorite- harzburgite relatively enriched in HFSE due to the stabilization. Godard (2005), Enrichment of HFSE in chlorite-harzburgite produced by high-pressure dehydration

  6. High- and low-temperature-stable thermite composition for producing high-pressure, high-velocity gases

    DOE Patents [OSTI]

    Halcomb, Danny L. (Camden, OH); Mohler, Jonathan H. (Spring Valley, OH)

    1990-10-16T23:59:59.000Z

    A high- and low-temperature-stable thermite composition for producing high-pressure and high-velocity gases comprises an oxidizable metal, an oxidizing reagent, and a high-temperature-stable gas-producing additive selected from the group consisting of metal carbides and metal nitrides.

  7. High pressure melt ejection

    SciTech Connect (OSTI)

    Tarbell, W.W.; Brockmann, J.E.; Pilch, M.

    1983-01-01T23:59:59.000Z

    Recent probabilistic risk assessments have identified the potential for reactor pressure vessel failure while the reactor coolant system is at elevated pressure. The analyses postulate that the blowdown of steam and hydrogen into the reactor cavity will cause the core material to be swept from the cavity region into the containment building. The High Pressure Melt Streaming (HIPS) program is an experimental study of the high pressure ejection of molten material and subsequent interactions within a concrete cavity. The program focuses on using prototypic system conditions and scaled models of reactor geometries to accurately simulate the ex-vessel processes during high-pressure accident sequences. Scaling analyses of the experiment show that the criteria established for core debris removal from the cavity are met or exceeded. Tests are performed at two scales, representing 1/10th and 1/20th linear reproductions of the Zion reactor plant. Results of the 1/20th scale tests are presented.

  8. Oil shale retorting with steam and produced gas

    SciTech Connect (OSTI)

    Merrill, L.S. Jr.; Wheaton, L.D.

    1991-08-20T23:59:59.000Z

    This patent describes a process for retorting oil shale in a vertical retort. It comprises introducing particles of oil shale into the retort, the particles of oil shale having a minimum size such that the particles are retained on a screen having openings 1/4 inch in size; contacting the particles of oil shale with hot gas to heat the particles of oil shale to a state of pyrolysis, thereby producing retort off-gas; removing the off-gas from the retort; cooling the off-gas; removing oil from the cooled off-gas; separating recycle gas from the off-gas, the recycle gas comprising steam and produced gas, the steam being present in amount, by volume, of at least 50% of the recycle gas so as to increase the yield of sand oil; and heating the recycle gas to form the hot gas.

  9. Energy Comparison Vacuum Producing Equipment - Mechanical Vacuum Pumps vs. Steam Ejectors

    E-Print Network [OSTI]

    Foisy, E. C.; Munkittrick, M. T.

    1982-01-01T23:59:59.000Z

    increasing cost of fuel to produce steam, it has become apparent that considerable savings in operating costs and reduction in thermal or water pollution can be achieved by replacing steam ejectors with mechanical vacuum pumps. The liquid ring (sometimes...

  10. A shortened version of this paper appeared in IEEE Computer, October 1994. 1 HighPressure Steam Engines and Computer Software \\Lambda

    E-Print Network [OSTI]

    Leveson, Nancy

    A shortened version of this paper appeared in IEEE Computer, October 1994. 1 High­Pressure Steam the same mistakes. In particular, parallels exist between the early develop­ ment of high­pressure steam A History of the Growth of the Steam Engine (1883) Hero of Alexandria, who lived around 60 AD, con­ ducted

  11. Electrokinetically pumped high pressure sprays

    DOE Patents [OSTI]

    Schoeniger, Joseph S. (Oakland, CA); Paul, Phillip H. (Livermore, CA); Schoeniger, Luke (Pittsford, NY)

    2002-01-01T23:59:59.000Z

    An electrokinetic pump capable of producing high pressure is combined with a nozzle having a submicron orifice to provide a high pressure spray device. Because of its small size, the device can be contained within medical devices such as an endoscope for delivering biological materials such as DNA, chemo therapeutic agents, or vaccines to tissues and cells.

  12. Apparatus and method for enhanced chemical processing in high pressure and atmospheric plasmas produced by high frequency electromagnetic waves

    DOE Patents [OSTI]

    Efthimion, Philip C. (Bedminister, NJ); Helfritch, Dennis J. (Flemington, NJ)

    1989-11-28T23:59:59.000Z

    An apparatus and method for creating high temperature plasmas for enhanced chemical processing of gaseous fluids, toxic chemicals, and the like, at a wide range of pressures, especially at atmospheric and high pressures includes an electro-magnetic resonator cavity, preferably a reentrant cavity, and a wave guiding structure which connects an electro-magnetic source to the cavity. The cavity includes an intake port and an exhaust port, each having apertures in the conductive walls of the cavity sufficient for the intake of the gaseous fluids and for the discharge of the processed gaseous fluids. The apertures are sufficiently small to prevent the leakage of the electro-magnetic radiation from the cavity. Gaseous fluid flowing from the direction of the electro-magnetic source through the guiding wave structure and into the cavity acts on the plasma to push it away from the guiding wave structure and the electro-magnetic source. The gaseous fluid flow confines the high temperature plasma inside the cavity and allows complete chemical processing of the gaseous fluids at a wide range of pressures.

  13. High pressure counterflow CHF.

    E-Print Network [OSTI]

    Walkush, Joseph Patrick

    1975-01-01T23:59:59.000Z

    This is a report of the experimental results of a program in countercurrent flow critical heat flux. These experiments were performed with Freon 113 at 200 psia in order to model a high pressure water system. An internally ...

  14. EFFECT OF H2 PRODUCED THROUGH STEAM-METHANE REFORMING ON CHP PLANT EFFICIENCY

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 EFFECT OF H2 PRODUCED THROUGH STEAM-METHANE REFORMING ON CHP PLANT EFFICIENCY O. Le Corre1 , C for a CHP plant based on spark ignition engine running under lean conditions. An overall auto-fire or knock occurred. Keywords: Hydrogen, CHP, natural gas, power, efficiency, environmental impact. 1

  15. Flash Steam Recovery Project

    E-Print Network [OSTI]

    Bronhold, C. J.

    organic compounds, was targeted for improvement. This unit uses a portion of the high-pressure steam available from the plant's cogeneration facility. Continuous expansions within the unit had exceeded the optimum design capacity of the unit's steam...

  16. Steam System Optimization

    E-Print Network [OSTI]

    Aegerter, R.

    2004-01-01T23:59:59.000Z

    opportunities. Often flanges, control valves, steam turbines, man ways, sections of piping, heads on vessels, etc. are bare and can significantly increase the steam demand. An insulation survey should be conducted of the steam, condensate... is being let down. Some projects are independent of the steam balance, such as eliminating high-pressure (HP) steam leaks, insulating HP steam piping, optimizing the boiler operation, and improving the performance of condensing turbines...

  17. High pressure furnace

    DOE Patents [OSTI]

    Morris, D.E.

    1993-09-14T23:59:59.000Z

    A high temperature high pressure furnace has a hybrid partially externally heated construction. A metallic vessel fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum)). The disclosed alloy is fabricated into 11/4 or 2 inch, 32 mm or 50 mm bar stock and has a length of about 22 inches, 56 cm. This bar stock has an aperture formed therein to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the vessel is provided with a small blind aperture into which a thermocouple can be inserted. The closed end of the vessel is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 19 figures.

  18. High pressure oxygen furnace

    DOE Patents [OSTI]

    Morris, Donald E. (Kensington, CA)

    1992-01-01T23:59:59.000Z

    A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

  19. High pressure oxygen furnace

    DOE Patents [OSTI]

    Morris, D.E.

    1992-07-14T23:59:59.000Z

    A high temperature high pressure oxygen furnace having a hybrid partially externally heated construction is disclosed. A metallic bar fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized, the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 inch bar stock and has a length of about 17 inches. This bar stock is gun drilled for over 16 inches of its length with 0.400 inch aperture to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the bar is provided with a small support aperture into which both a support and a thermocouple can be inserted. The closed end of the gun drilled bar is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior. 5 figs.

  20. High pressure furnace

    DOE Patents [OSTI]

    Morris, Donald E. (Kensington, CA)

    1993-01-01T23:59:59.000Z

    A high temperature high pressure furnace has a hybrid partially externally heated construction. A metallic vessel fabricated from an alloy having a composition of at least 45% nickel, 15% chrome, and 10% tungsten is utilized (the preferred alloy including 55% nickel, 22% chrome, 14% tungsten, 2% molybdenum, 3% iron (maximum) and 5% cobalt (maximum). The disclosed alloy is fabricated into 11/4 or 2 inch, 32 mm or 50 mm bar stock and has a length of about 22 inches, 56 cm. This bar stock has an aperture formed therein to define a closed high temperature, high pressure oxygen chamber. The opposite and closed end of the vessel is provided with a small blind aperture into which a thermocouple can be inserted. The closed end of the vessel is inserted into an oven, preferably heated by standard nickel chrome electrical elements and having a heavily insulated exterior.

  1. Nitrogen at very high pressure

    SciTech Connect (OSTI)

    Nellis, W.J.

    1987-07-01T23:59:59.000Z

    High-pressure results for nitrogen are reviewed and discussed in terms of phenomena that occur at extreme conditions.

  2. Experimental studies of steam and steam-propane injection using a novel smart horizontal producer to enhance oil production in the San Ardo field

    E-Print Network [OSTI]

    Rivero Diaz, Jose Antonio

    2007-09-17T23:59:59.000Z

    is the use of propane as a steam additive with the purpose of increasing recovery and accelerating oil production. The second process involves the use of a novel production configuration that makes use of a vertical injector and a smart horizontal producer...

  3. A simulation study of steam and steam-propane injection using a novel smart horizontal producer to enhance oil production

    E-Print Network [OSTI]

    Sandoval Munoz, Jorge Eduardo

    2004-11-15T23:59:59.000Z

    A 3D 8-component thermal compositional simulation study has been performed to evaluate the merits of steam-propane injection and a novel vertical-smart horizontal well system for the Lombardi reservoir in the San Ardo field, California. The novel...

  4. A simulation study of steam and steam-propane injection using a novel smart horizontal producer to enhance oil production

    E-Print Network [OSTI]

    Sandoval Munoz, Jorge Eduardo

    2004-11-15T23:59:59.000Z

    , under steam injection, oil recovery is significantly higher with the novel vertical-smart horizontal well system (45.5-58.7% OOIP at 150-300 BPDCWE) compared to the vertical well system (33.6-32.2% OOIP at 150-300 BPDCWE). Second, oil recovery increases...

  5. Use Steam Jet Ejectors or Thermocompressors to Reduce Venting...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to Recover Low-Pressure Waste Steam Flash High-Pressure Condensate to Regenerate Low-Pressure Steam Consider Installing High-Pressure Boilers with Backpressure Turbine-Generators...

  6. Energy Comparison Vacuum Producing Equipment - Mechanical Vacuum Pumps vs. Steam Ejectors

    E-Print Network [OSTI]

    Foisy, E. C.; Munkittrick, M. T.

    1982-01-01T23:59:59.000Z

    vacuum on condensers, process reactors, or equipment and processes requiring subatmospheric conditions, has been to utilize steam ejectors. Due to the inherent operating inefficiency and wastefulness of the steam ejector, coupled with the rapidly...

  7. Steam Turbine Cogeneration

    E-Print Network [OSTI]

    Quach, K.; Robb, A. G.

    2008-01-01T23:59:59.000Z

    Steam turbines are widely used in most industrial facilities because steam is readily available and steam turbine is easy to operate and maintain. If designed properly, a steam turbine co-generation (producing heat and power simultaneously) system...

  8. Steam Turbine Cogeneration

    E-Print Network [OSTI]

    Quach, K.; Robb, A. G.

    2008-01-01T23:59:59.000Z

    Steam turbines are widely used in most industrial facilities because steam is readily available and steam turbine is easy to operate and maintain. If designed properly, a steam turbine co-generation (producing heat and power simultaneously) system...

  9. High-pressure neutron diffraction

    SciTech Connect (OSTI)

    Xu, Hongwu [Los Alamos National Laboratory

    2011-01-10T23:59:59.000Z

    This lecture will cover progress and prospect of applications of high-pressure neutron diffraction techniques to Earth and materials sciences. I will first introduce general high-pressure research topics and available in-situ high-pressure techniques. Then I'll talk about high-pressure neutron diffraction techniques using two types of pressure cells: fluid-driven and anvil-type cells. Lastly, I will give several case studies using these techniques, particularly, those on hydrogen-bearing materials and magnetic transitions.

  10. Reduction of Film Coolant in High Pressure Turbines

    E-Print Network [OSTI]

    Wirsum Institute of Power Plant Technology, Steam and Gas Turbines, RWTH Aachen Prof. Dr.-Ing. Ingo RhleReduction of Film Coolant in High Pressure Turbines Bachelor Thesis in Computational Engineering Institute of Propulsion Technology, German Aerospace Center #12;Abstract Gas turbine development has been

  11. HP Steam Trap Monitoring

    E-Print Network [OSTI]

    Pascone, S.

    2011-01-01T23:59:59.000Z

    STEAM MONITORING HP Steam Trap Monitoring HP Steam Trap Monitoring ? 12-18 months payback! ? 3-5% permanent reduction in consumption ? LEED Pt.? Innovation in Operations EB O&M ? Saved clients over $1,000,000 Annual consumption... Steam Trap Monitoring ? Real-time monitoring for high-pressure critical traps (>15 PSIG) ? Average total system cost $25K - $50K ? Web-Based or Modbus/BMS Integration Basic Installation Wireless Signal Transmitter Receiver Repeater...

  12. Consider Installing High-Pressure Boilers with Backpressure Turbine-Generators

    SciTech Connect (OSTI)

    Not Available

    2006-01-01T23:59:59.000Z

    This revised ITP tip sheet on installing high-pressure boilers provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  13. High pressure liquid level monitor

    DOE Patents [OSTI]

    Bean, Vern E. (Frederick, MD); Long, Frederick G. (Ijamsville, MD)

    1984-01-01T23:59:59.000Z

    A liquid level monitor for tracking the level of a coal slurry in a high-pressure vessel including a toroidal-shaped float with magnetically permeable bands thereon disposed within the vessel, two pairs of magnetic field generators and detectors disposed outside the vessel adjacent the top and bottom thereof and magnetically coupled to the magnetically permeable bands on the float, and signal processing circuitry for combining signals from the top and bottom detectors for generating a monotonically increasing analog control signal which is a function of liquid level. The control signal may be utilized to operate high-pressure control valves associated with processes in which the high-pressure vessel is used.

  14. Electrokinetic high pressure hydraulic system

    DOE Patents [OSTI]

    Paul, Phillip H.; Rakestraw, David J.; Arnold, Don W.; Hencken, Kenneth R.; Schoeniger, Joseph S.; Neyer, David W.

    2003-06-03T23:59:59.000Z

    An electrokinetic high pressure hydraulic pump for manipulating fluids in capillary-based system. The pump uses electro-osmotic flow to provide a high pressure hydraulic system, having no moving mechanical parts, for pumping and/or compressing fluids, for providing valve means and means for opening and closing valves, for controlling fluid flow rate, and manipulating fluid flow generally and in capillary-based systems (microsystems), in particular. The compact nature of the inventive high pressure hydraulic pump provides the ability to construct a micro-scale or capillary-based HPLC system that fulfills the desire for small sample quantity, low solvent consumption, improved efficiency, the ability to run samples in parallel, and field portability. Control of pressure and solvent flow rate is achieved by controlling the voltage applied to an electrokinetic pump.

  15. Electrokinetic high pressure hydraulic system

    DOE Patents [OSTI]

    Paul, Phillip H. (Livermore, CA); Rakestraw, David J. (Fremont, CA); Arnold, Don W. (Livermore, CA); Hencken, Kenneth R. (Pleasanton, CA); Schoeniger, Joseph S. (Oakland, CA); Neyer, David W. (Castro Valley, CA)

    2001-01-01T23:59:59.000Z

    An electrokinetic high pressure hydraulic pump for manipulating fluids in capillary-based systems. The pump uses electro-osmotic flow to provide a high pressure hydraulic system, having no moving mechanical parts, for pumping and/or compressing fluids, for providing valve means and means for opening and closing valves, for controlling fluid flow rate, and manipulating fluid flow generally and in capillary-based systems (Microsystems), in particular. The compact nature of the inventive high pressure hydraulic pump provides the ability to construct a micro-scale or capillary-based HPLC system that fulfills the desire for small sample quantity, low solvent consumption, improved efficiency, the ability to run samples in parallel, and field portability. Control of pressure and solvent flow rate is achieved by controlling the voltage applied to an electrokinetic pump.

  16. Electrokinetic high pressure hydraulic system

    DOE Patents [OSTI]

    Paul, Phillip H. (Livermore, CA); Rakestraw, David J. (Fremont, CA)

    2000-01-01T23:59:59.000Z

    A compact high pressure hydraulic pump having no moving mechanical parts for converting electric potential to hydraulic force. The electrokinetic pump, which can generate hydraulic pressures greater than 2500 psi, can be employed to compress a fluid, either liquid or gas, and manipulate fluid flow. The pump is particularly useful for capillary-base systems. By combining the electrokinetic pump with a housing having chambers separated by a flexible member, fluid flow, including high pressure fluids, is controlled by the application of an electric potential, that can vary with time.

  17. High pressure neon arc lamp

    DOE Patents [OSTI]

    Sze, Robert C.; Bigio, Irving J.

    2003-07-15T23:59:59.000Z

    A high pressure neon arc lamp and method of using the same for photodynamic therapies is provided. The high pressure neon arc lamp includes a housing that encloses a quantity of neon gas pressurized to about 500 Torr to about 22,000 Torr. At each end of the housing the lamp is connected by electrodes and wires to a pulse generator. The pulse generator generates an initial pulse voltage to breakdown the impedance of the neon gas. Then the pulse generator delivers a current through the neon gas to create an electrical arc that emits light having wavelengths from about 620 nanometers to about 645 nanometers. A method for activating a photosensitizer is provided. Initially, a photosensitizer is administered to a patient and allowed time to be absorbed into target cells. Then the high pressure neon arc lamp is used to illuminate the target cells with red light having wavelengths from about 620 nanometers to about 645 nanometers. The red light activates the photosensitizers to start a chain reaction that may involve oxygen free radicals to destroy the target cells. In this manner, a high pressure neon arc lamp that is inexpensive and efficiently generates red light useful in photodynamic therapy is provided.

  18. Combined Heat and Power Plant Steam Turbine

    E-Print Network [OSTI]

    Rose, Michael R.

    Combined Heat and Power Plant Steam Turbine Steam Turbine Chiller Campus Heat Load Steam (recovered waste heat) Gas Turbine University Substation High Pressure Natural Gas Campus Electric Load Southern Generator Heat Recovery Alternative Uses: 1. Campus heating load 2. Steam turbine chiller to campus cooling

  19. Computer Optimization of Steam Production

    E-Print Network [OSTI]

    Todd, C. H.

    1982-01-01T23:59:59.000Z

    As fuel costs continued to rise sharply during the 1970' s, the staff at Exxon's Benicia Refinery realized there was a growing economic incentive to optimize the production of high pressure steam. A significant percentage of the Refinery's total...

  20. Effect of Acid, Alkali, and Steam Explosion Pretreatments on Characteristics of Bio-Oil Produced from Pinewood

    SciTech Connect (OSTI)

    Wang, Hui; Srinivasan, Radhakrishnan; Yu, Fei; Steele, Philip; Li, Qi; Mitchell, Brian

    2011-06-21T23:59:59.000Z

    Bio-oil produced from pinewood by fast pyrolysis has the potential to be a valuable substitute for fossil fuels. Pretreatment prior to the fast pyrolysis process has been shown to alter the structure and chemical composition of biomass. To determine the influence of biomass pretreatments on bio-oil produced during fast pyrolysis, we tested three pretreatment methods: dilute acid, dilute alkali, and steam explosion. Bio-oils were produced from untreated and pretreated pinewood feedstocks in an auger reactor at 450 C. The bio-oils?¢???? physical properties including pH, water content, acid value, density, viscosity, and heating value were measured. Chemical characteristics of the bio-oils were determined by gas chromatographymass spectrometry. Results showed that bio-oil yield and composition were influenced by biomass pretreatment. Of the three pretreatment methods, 1%H2SO4 pretreatment resulted in the highest bio-oil yield and best bio-oil quality.

  1. Electokinetic high pressure hydraulic system

    DOE Patents [OSTI]

    Paul, Phillip H. (Livermore, CA); Rakestraw, David J. (Fremont, CA)

    2000-01-01T23:59:59.000Z

    A compact high pressure hydraulic system having no moving parts for converting electric potential to hydraulic force and for manipulating fluids. Electro-osmotic flow is used to provide a valve and means to compress a fluid or gas in a capillary-based system. By electro-osmotically moving an electrolyte between a first position opening communication between a fluid inlet and outlet and a second position closing communication between the fluid inlet and outlet the system can be configured as a valve. The system can also be used to generate forces as large as 2500 psi that can be used to compress a fluid, either a liquid or a gas.

  2. Experimental studies of steam and steam-propane injection using a novel smart horizontal producer to enhance oil production in the San Ardo field

    E-Print Network [OSTI]

    Rivero Diaz, Jose Antonio

    2007-09-17T23:59:59.000Z

    in an attempt to mitigate the effects of steam override. The experimental model was scaled using the conditions in the San Ardo field in California and crude oil from the same field was used for the tests. Superheated steam at 190 â?? 200?ºC was injected...

  3. HIGH PRESSURE COAL COMBUSTON KINETICS PROJECT

    SciTech Connect (OSTI)

    Stefano Orsino

    2005-03-30T23:59:59.000Z

    As part of the U.S. Department of Energy (DoE) initiative to improve the efficiency of coal-fired power plants and reduce the pollution generated by these facilities, DOE has funded the High-Pressure Coal Combustion Kinetics (HPCCK) Projects. A series of laboratory experiments were conducted on selected pulverized coals at elevated pressures with the specific goals to provide new data for pressurized coal combustion that will help extend to high pressure and validate models for burnout, pollutant formation, and generate samples of solid combustion products for analyses to fill crucial gaps in knowledge of char morphology and fly ash formation. Two series of high-pressure coal combustion experiments were performed using SRI's pressurized radiant coal flow reactor. The first series of tests characterized the near burner flame zone (NBFZ). Three coals were tested, two high volatile bituminous (Pittsburgh No.8 and Illinois No.6), and one sub-bituminous (Powder River Basin), at pressures of 1, 2, and 3 MPa (10, 20, and 30 atm). The second series of experiments, which covered high-pressure burnout (HPBO) conditions, utilized a range of substantially longer combustion residence times to produce char burnout levels from 50% to 100%. The same three coals were tested at 1, 2, and 3 MPa, as well as at 0.2 MPa. Tests were also conducted on Pittsburgh No.8 coal in CO2 entrainment gas at 0.2, 1, and 2 MPa to begin establishing a database of experiments relevant to carbon sequestration techniques. The HPBO test series included use of an impactor-type particle sampler to measure the particle size distribution of fly ash produced under complete burnout conditions. The collected data have been interpreted with the help of CFD and detailed kinetics simulation to extend and validate devolatilization, char combustion and pollutant model at elevated pressure. A global NOX production sub-model has been proposed. The submodel reproduces the performance of the detailed chemical reaction mechanism for the NBFZ tests.

  4. High pressure xenon ionization detector

    DOE Patents [OSTI]

    Markey, John K. (New Haven, CT)

    1989-01-01T23:59:59.000Z

    A method is provided for detecting ionization comprising allowing particles that cause ionization to contact high pressure xenon maintained at or near its critical point and measuring the amount of ionization. An apparatus is provided for detecting ionization, the apparatus comprising a vessel containing a ionizable medium, the vessel having an inlet to allow high pressure ionizable medium to enter the vessel, a means to permit particles that cause ionization of the medium to enter the vessel, an anode, a cathode, a grid and a plurality of annular field shaping rings, the field shaping rings being electrically isolated from one another, the anode, cathode, grid and field shaping rings being electrically isolated from one another in order to form an electric field between the cathode and the anode, the electric field originating at the anode and terminating at the cathode, the grid being disposed between the cathode and the anode, the field shaping rings being disposed between the cathode and the grid, the improvement comprising the medium being xenon and the vessel being maintained at a pressure of 50 to 70 atmospheres and a temperature of 0.degree. to 30.degree. C.

  5. High Pressure Hydrogen Materials Compatibility of Piezoelectric...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pressure Hydrogen Materials Compatibility of Piezoelectric Films. High Pressure Hydrogen Materials Compatibility of Piezoelectric Films. Abstract: Abstract: Hydrogen is being...

  6. Economics of high performance steam systems (HPSS) cogeneration: A handbook

    SciTech Connect (OSTI)

    Not Available

    1992-06-01T23:59:59.000Z

    This guidebook aims to farther industry's knowledge of HPSS and their potential benefits. It is also intended to provide industrial end-users with a basis for judging the merits of HPSS under various site-specific conditions by outlining the economics of HPSS and conventional cogeneration systems compared to boilers under representative sets of industrial process conditions. Electric utility companies have experimented with steam pressures in the range of 5,000 psig and temperatures up to 1,200[degrees]F, but generally have remained with more conservative throttle conditions of 2,400 psig, 1,000[degrees]F to improve reliability. Most industrial applications have used steam throttle conditions below 900 psig and 900[degrees]F. Yet thermodynamic analysis shows that in a steam turbine generator, the amount of electricity generated per pound of steam increases as the inlet steam temperature and pressure are increased. Furthermore, the incremental electricity that is generated by raising the steam temperature and pressure is produced in a highly efficient manner. Efforts in this direction explain why, recently, some industrial projects have been built with steam turbine inlet turbine conditions of 1,500 psig and above. The HPSS concept goes one step further: It is based on a high-temperature steam generator capable of producing 1,500[degrees]F superheated steam and a high-speed steam turbine-generator. By utilizing the HPSS system as a topping'' system, high-pressure steam can be expanded from 1,500[degrees]F to the traditional temperatures used by industry.

  7. Economics of high performance steam systems (HPSS) cogeneration: A handbook

    SciTech Connect (OSTI)

    Not Available

    1992-06-01T23:59:59.000Z

    This guidebook aims to farther industry`s knowledge of HPSS and their potential benefits. It is also intended to provide industrial end-users with a basis for judging the merits of HPSS under various site-specific conditions by outlining the economics of HPSS and conventional cogeneration systems compared to boilers under representative sets of industrial process conditions. Electric utility companies have experimented with steam pressures in the range of 5,000 psig and temperatures up to 1,200{degrees}F, but generally have remained with more conservative throttle conditions of 2,400 psig, 1,000{degrees}F to improve reliability. Most industrial applications have used steam throttle conditions below 900 psig and 900{degrees}F. Yet thermodynamic analysis shows that in a steam turbine generator, the amount of electricity generated per pound of steam increases as the inlet steam temperature and pressure are increased. Furthermore, the incremental electricity that is generated by raising the steam temperature and pressure is produced in a highly efficient manner. Efforts in this direction explain why, recently, some industrial projects have been built with steam turbine inlet turbine conditions of 1,500 psig and above. The HPSS concept goes one step further: It is based on a high-temperature steam generator capable of producing 1,500{degrees}F superheated steam and a high-speed steam turbine-generator. By utilizing the HPSS system as a ``topping`` system, high-pressure steam can be expanded from 1,500{degrees}F to the traditional temperatures used by industry.

  8. Steam System Improvements at a Manufacturing Plant

    E-Print Network [OSTI]

    Compher, J.; Morcom, B.

    BWX Technologies, Naval Nuclear Fuel Division (NNFD) is a manufacturing company with a steam system consisting of two Babcock & Wilcox boilers and approximately 350 steam traps. The steam system is used to produce and distribute steam for space...

  9. Zirconate pyrochlores under high pressure. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    phase transformation. Citation: Xiao HY, FX Zhang, F Gao, M Lang, RC Ewing, and WJ Weber.2010."Zirconate pyrochlores under high pressure."Physical Chemistry Chemical Physics....

  10. NETL- High-Pressure Combustion Research Facility

    ScienceCinema (OSTI)

    None

    2014-06-26T23:59:59.000Z

    NETL's High-Pressure Combustion Facility is a unique resource within the National Laboratories system. It provides the test capabilities needed to evaluate new combustion concepts for high-pressure, high-temperature hydrogen and natural gas turbines. These concepts will be critical for the next generation of ultra clean, ultra efficient power systems.

  11. NETL- High-Pressure Combustion Research Facility

    SciTech Connect (OSTI)

    None

    2013-07-08T23:59:59.000Z

    NETL's High-Pressure Combustion Facility is a unique resource within the National Laboratories system. It provides the test capabilities needed to evaluate new combustion concepts for high-pressure, high-temperature hydrogen and natural gas turbines. These concepts will be critical for the next generation of ultra clean, ultra efficient power systems.

  12. Extraction Steam Controls at EPLA-W

    E-Print Network [OSTI]

    Brinker, J. L.

    2004-01-01T23:59:59.000Z

    ExxonMobil's Baton Rouge site encompasses a world-scale refinery, chemical plant and third party power station. Historically, inflexible and unreliable control systems on two high-pressure, extracting/condensing steam turbines prevented the site...

  13. Steam System Optimization

    E-Print Network [OSTI]

    Aegerter, R.

    2004-01-01T23:59:59.000Z

    Refinery and chemical plant steam systems are complex and the fuel required to produce the steam represents a major expense. The incremental cost for generating a 1,000 lb./hr. of steam is typically $45,000 - $60,000/year. Most plants have...

  14. High-pressure studies of ammonia hydrates

    E-Print Network [OSTI]

    Wilson, Craig W.

    2014-06-28T23:59:59.000Z

    Ammonia and water are major components of many planetary bodies, from comets and icy moons such as Saturn's Titan to the interiors of the planets Neptune and Uranus. Under a range of high pressures and/or low temperatures known ...

  15. High-pressure synthesis of electronic materials

    E-Print Network [OSTI]

    Penny, George B. S.

    2010-01-01T23:59:59.000Z

    High-pressure techniques have become increasingly important in the synthesis of ceramic and metallic solids allowing the discovery of new materials with interesting properties. In this research dense solid oxides have ...

  16. Soot particle aerosol dynamics at high pressure

    SciTech Connect (OSTI)

    Harris, S.J. (General Motors Research Labs., Warren, MI (USA). Physics Dept.); Kennedy, I.M. (California Univ., Davis, CA (USA). Dept. of Mechanical Engineering)

    1989-12-01T23:59:59.000Z

    The authors have used detailed calculations to analyze the coagulation dynamics of a soot aerosol at high pressures (20 and 50 atm). They find that the soot size distribution is altered compared to lower-pressure conditions because the mean free path at high pressures is reduced to the point that the particles are similar in size to the mean free path. At lower pressures the form of the size distribution becomes constant (self-preserving) in time, allowing optical measurements to be easily interpreted. However, the authors find that at pressures above about 5 atm the shape of the size distribution continually changes. As a result, proper and accurate interpretation of optical data at high pressures is more difficult than at lower pressures.

  17. High pressure water jet mining machine

    DOE Patents [OSTI]

    Barker, Clark R. (Rolla, MO)

    1981-05-05T23:59:59.000Z

    A high pressure water jet mining machine for the longwall mining of coal is described. The machine is generally in the shape of a plowshare and is advanced in the direction in which the coal is cut. The machine has mounted thereon a plurality of nozzle modules each containing a high pressure water jet nozzle disposed to oscillate in a particular plane. The nozzle modules are oriented to cut in vertical and horizontal planes on the leading edge of the machine and the coal so cut is cleaved off by the wedge-shaped body.

  18. Automated High-Pressure Titration System with In Situ Infrared...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High-Pressure Titration System with In Situ Infrared Spectroscopic Detection. Automated High-Pressure Titration System with In Situ Infrared Spectroscopic Detection. Abstract: A...

  19. A University Consortium on High Pressure, Lean Combustion for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Pressure, Lean Combustion for Efficient and Clean IC Engines (UM - lead, MIT, UCB) A University Consortium on High Pressure, Lean Combustion for Efficient and Clean IC Engines...

  20. High Temperature, High Pressure Devices for Zonal Isolation in...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells High Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells High Temperature,...

  1. Consider Installing High-Pressure Boilers with BackpressureTurbine...

    Broader source: Energy.gov (indexed) [DOE]

    High-Pressure Boilers with Backpressure Turbine-Generators Consider Installing High-Pressure Boilers with Backpressure Turbine-Generators This tip sheet outlines the benefits of...

  2. Intermittently-fed high-pressure gasifier process

    DOE Patents [OSTI]

    Bailey, J.M.; Zadoks, A.L.

    1993-11-30T23:59:59.000Z

    An improved gasifier is described which is adapted for gasifying a predetermined charge of non-gaseous fuel into fuel gas. Each charge of non-gaseous fuel, which may have optional conditioning materials added to it, is intermittently fed to a gasifier chamber where each charge is partially burned with high-pressure air supplied thereto. High-pressure and temperature fuel gas is produced which is cleansed prior to passing out of the gasifier chamber. After gasification of the charge of fuel is ended, the gasifier chamber is vented. The residue of the burned charge in the gasifier chamber is removed, along with the contaminated or reacted conditioning materials, and replaced by a fresh charge. The subject invention provides a feasible way of continuously fueling an internal combustion engine with gasified fuel and is compact enough to be practical for even mobile applications. 3 figures.

  3. Guest disorder and high pressure behavior of argon hydrates

    SciTech Connect (OSTI)

    Yang, L.; Tulk, C.A.; Klug, D.D.; Chakoumakos, B.C.; Ehm, L.; Molaison, J.J.; Parise, J.B.; Simonson, J.M. (NRCC); (SBU); (ORNL)

    2010-03-29T23:59:59.000Z

    The structure of argon hydrate was studied at ambient pressure and low temperature, and between 1.7 and 4.2 GPa at 295 K. This analysis produced a single Ar guest atom, positionally disordered off-center in the large cages of sII. Above 1.7 GPa Ar clathrate transformed to a mixture of a body-centered orthorhombic filled-ice phase, which can be viewed as a polytype of ice-Ih, and high pressure forms of pure ice. The guest disorder is further substantiated by analysis of the guest to host ratio in this high pressure filled-ice structure. The bulk modulus of Ar filled-ice found to be 11.7 {+-} 0.4 GPa.

  4. Intermittently-fed high-pressure gasifier process

    DOE Patents [OSTI]

    Bailey, John M. (Dunlap, IL); Zadoks, Abraham L. (Peoria, IL)

    1993-11-30T23:59:59.000Z

    An improved gasifier adapted for gasifying a predetermined charge of non-gaseous fuel into fuel gas. Each charge of non-gaseous fuel, which may have optional conditioning materials added to it, is intermittently fed to a gasifier chamber where each charge is partially burned with high-pressure air supplied thereto. High-pressure and temperature fuel gas is produced which is cleansed prior to passing out of the gasifier chamber. After gasification of the charge of fuel is is ended, the gasifier chamber is vented. The residue of the burned charge in the gasifier chamber is removed, along with the contaminated or reacted conditioning materials, and replaced by a fresh charge. The subject invention provides a feasible way of continuously fueling an internal combustion engine with gasified fuel and is compact enough to be practical for even mobile applications.

  5. Advanced Diagnostics for High Pressure Spray Combustion.

    SciTech Connect (OSTI)

    Skeen, Scott A.; Manin, Julien Luc; Pickett, Lyle M.

    2014-06-01T23:59:59.000Z

    The development of accurate predictive engine simulations requires experimental data to both inform and validate the models, but very limited information is presently available about the chemical structure of high pressure spray flames under engine- relevant conditions. Probing such flames for chemical information using non- intrusive optical methods or intrusive sampling techniques, however, is challenging because of the physical and optical harshness of the environment. This work details two new diagnostics that have been developed and deployed to obtain quantitative species concentrations and soot volume fractions from a high-pressure combusting spray. A high-speed, high-pressure sampling system was developed to extract gaseous species (including soot precursor species) from within the flame for offline analysis by time-of-flight mass spectrometry. A high-speed multi-wavelength optical extinction diagnostic was also developed to quantify transient and quasi-steady soot processes. High-pressure sampling and offline characterization of gas-phase species formed following the pre-burn event was accomplished as well as characterization of gas-phase species present in the lift-off region of a high-pressure n-dodecane spray flame. For the initial samples discussed in this work several species were identified, including polycyclic aromatic hydrocarbons (PAH); however, quantitative mole fractions were not determined. Nevertheless, the diagnostic developed here does have this capability. Quantitative, time-resolved measurements of soot extinction were also accomplished and the novel use of multiple incident wavelengths proved valuable toward characterizing changes in soot optical properties within different regions of the spray flame.

  6. Catalytic steam gasification reactivity of HyperCoals produced from different rank of coals at 600-775{degree}C

    SciTech Connect (OSTI)

    Atul Sharma; Ikuo Saito; Toshimasa Takanohashi [National Institute of Advanced Industrial Science and Technology, Ibaraki (Japan). Advanced Fuel Group, Energy Technology Research Institute

    2008-11-15T23:59:59.000Z

    HyperCoal is a clean coal with ash content <0.05 wt %. HyperCoals were prepared from a brown coal, a sub-bituminous coal, and a bituminous raw coal by solvent extraction method. Catalytic steam gasification of these HyperCoals was carried out with K{sub 2}CO{sub 3} at 775, 700, 650, and 600 {degree}C, and their rates were compared. HyperCoals produced from low-rank coals were more reactive than those produced from the high-rank coals. XRD measurements were carried out to understand the difference in gasification reactivity of HyperCoals. Arrhenius plot of ln (k) vs 1/T in the temperature range 600-825{degree}C was a curve rather than a straight line. The point of change was observed at 700{degree}C for HyperCoals from low-rank coals and at 775{degree}C for HyperCoals from high-rank coals. Using HyperCoal produced from low-rank coals as feedstock, steam gasification of coal may be possible at temperatures less than 650{degree}C. 22 refs., 6 figs., 2 tabs.

  7. High-pressure liquid chromatographic gradient mixer

    DOE Patents [OSTI]

    Daughton, C.G.; Sakaji, R.H.

    1982-09-08T23:59:59.000Z

    A gradient mixer effects the continuous mixing of any two miscible solvents without excessive decay or dispersion of the resultant isocratic effluent or of a linear or exponential gradient. The two solvents are fed under low or high pressure by means of two high performance liquid chromatographic pumps. The mixer comprises a series of ultra-low dead volume stainless steel tubes and low dead volume chambers. The two solvent streams impinge head-on at high fluxes. This initial nonhomogeneous mixture is then passed through a chamber packed with spirally-wound wires which cause turbulent mixing thereby homogenizing the mixture with minimum band-broadening.

  8. High pressure liquid chromatographic gradient mixer

    DOE Patents [OSTI]

    Daughton, Christian G. (San Pablo, CA); Sakaji, Richard H. (El Cerrito, CA)

    1985-01-01T23:59:59.000Z

    A gradient mixer which effects the continuous mixing of any two miscible solvents without excessive decay or dispersion of the resultant isocratic effluent or of a linear or exponential gradient. The two solvents are fed under low or high pressure by means of two high performance liquid chromatographic pumps. The mixer comprises a series of ultra-low dead volume stainless steel tubes and low dead volume chambers. The two solvent streams impinge head-on at high fluxes. This initial nonhomogeneous mixture is then passed through a chamber packed with spirally-wound wires which cause turbulent mixing thereby homogenizing the mixture with minimum "band-broadening".

  9. High-Pressure Melt Streaming (HIPS) program plan

    SciTech Connect (OSTI)

    Tarbell, W.; Brockmann, J.; Pilch, M.

    1984-08-01T23:59:59.000Z

    The Zion Probabilistic Safety Study (ZPSS) envisions accident sequences that could lead to failure of the reactor vessel while the primary system is pressurized. The resulting ejection of molten core material into the reactor cavity followed by the blowdown of steam and hydrogen is shown to cause the debris to enter into the containment region. The High Pressure Melt Streaming (HIPS) program has been developed to provide an experimental and analytical investigation of the scenario described above. One-tenth linear scale models of the Zion cavity region will be used to investigate the debris dispersal phenomena. Smaller-scale experiments (SPIT-tests) are also used to study high-velocity jets, jet-water interactions, and 1/20th scale cavity geometries. Both matrices are developed using a factorial design approach. The document describes certain aspects of the ZPSS ex-vessel phenomena, the experimental matrices, test equipment, and instrumentation, and the program's analytical efforts. Preliminary data from SPIT testing are included.

  10. Apparatus and methods for supplying auxiliary steam in a combined cycle system

    DOE Patents [OSTI]

    Gorman, William G. (Ballston Spa, NY); Carberg, William George (Ballston Spa, NY); Jones, Charles Michael (Ballston Lake, NY)

    2002-01-01T23:59:59.000Z

    To provide auxiliary steam, a low pressure valve is opened in a combined cycle system to divert low pressure steam from the heat recovery steam generator to a header for supplying steam to a second combined cycle's steam turbine seals, sparging devices and cooling steam for the steam turbine if the steam turbine and gas turbine lie on a common shaft with the generator. Cooling steam is supplied the gas turbine in the combined cycle system from the high pressure steam turbine. Spent gas turbine cooling steam may augment the low pressure steam supplied to the header by opening a high pressure valve whereby high and low pressure steam flows are combined. An attemperator is used to reduce the temperature of the combined steam in response to auxiliary steam flows above a predetermined flow and a steam header temperature above a predetermined temperature. The auxiliary steam may be used to start additional combined cycle units or to provide a host unit with steam turbine cooling and sealing steam during full-speed no-load operation after a load rejection.

  11. Steam reforming analyzed

    SciTech Connect (OSTI)

    Wagner, E.S. (KTI Corp., San Dimas, CA (US)); Froment, G.F. (Ghent Rijksuniversiteit (Belgium))

    1992-07-01T23:59:59.000Z

    This paper reports that maximum steam reformer operation without excessive coking reactions requires careful control of thermodynamic and kinetic conditions. Regardless of the syngas-based feedstock composition, carbon formation problems can be avoided while increasing reformer CO or H{sub 2} production. Steam reforming technology is best understood via: Primary steam reformer developments, Kinetics of methane steam reforming, Simulation of an industrial steam/CO{sub 2} reformer, Example conditions (steam/CO{sub 2} reforming), Thermodynamic approach (minimum to steam ratio). Hydrogen and carbon monoxide are two of the most important building blocks in the chemical industry. Hydrogen is mainly used in ammonia and methanol synthesis and petroleum refining. Carbon monoxide is used to produce pains, plastics, foams, pesticides and insecticides, to name a few. Production of H{sub 2} and CO is usually carried out by the following processes: Steam reforming (primary and secondary) of hydrocarbons, Partial oxidation of hydrocarbons, Coal gasification. Coal gasification and partial oxidation do not use catalysts and depend on partial combustion of the feedstock to internally supply reaction heat. Secondary (autothermal) reforming is a type of steam reforming that also uses the heat of partial combustion but afterwards uses a catalyst of promote the production of hydrogen and CO.

  12. Low energy high pressure miniature screw valve

    DOE Patents [OSTI]

    Fischer, Gary J. (Sandia Park, NM); Spletzer, Barry L. (Albuquerque, NM)

    2006-12-12T23:59:59.000Z

    A low energy high pressure screw valve having a valve body having an upper portion and a lower portion, said lower portion of said valve body defining an inlet flow passage and an outlet flow passage traversing said valve body to a valve seat, said upper portion of said valve body defining a cavity at said valve seat, a diaphragm restricting flow between said upper portion of said valve body and said lower portion, said diaphragm capable of engaging said valve seat to restrict fluid communication between said inlet passage and said outlet passage, a plunger within said cavity supporting said diaphragm, said plunger being capable of engaging said diaphragm with said valve seat at said inlet and outlet fluid passages, said plunger being in point contact with a drive screw having threads engaged with opposing threads within said upper portion of said valve body such engagement allowing motion of said drive screw within said valve body.

  13. Polymerization of Formic Acid under High Pressure

    SciTech Connect (OSTI)

    Goncharov, A F; Manaa, M R; Zaug, J M; Fried, L E; Montgomery, W B

    2004-08-23T23:59:59.000Z

    We report combined Raman, infrared (IR) and x-ray diffraction (XRD) measurements, along with ab initio calculations on formic acid under pressure up to 50 GPa. Contrary to the report of Allan and Clark (PRL 82, 3464 (1999)), we find an infinite chain low-temperature Pna2{sub 1} structure consisting of trans molecules to be a high-pressure phase at room temperature. Our data indicate the symmetrization and a partially covalent character of the intra-chain hydrogen bonds above approximately 20 GPa. Raman spectra and XRD patterns indicate a loss of the long-range order at pressures above 40 GPa with a large hysteresis at decompression. We attribute this behavior to a three-dimensional polymerization of formic acid.

  14. High-pressure coal fuel processor development

    SciTech Connect (OSTI)

    Greenhalgh, M.L. (Caterpillar, Inc., Peoria, IL (United States))

    1992-12-01T23:59:59.000Z

    Caterpillar shares DOE/METC interest in demonstrating the technology required to displace petroleum-based engine fuels with various forms of low cost coal. Current DOE/METC programs on mild gasification and coal-water-slurries are addressing two approaches to this end. Engine and fuel processor system concept studies by Caterpillar have identified a third, potentially promising, option. This option includes high-pressure fuel processing of run-of-the-mine coal and direct injection of the resulting low-Btu gas stream into an ignition assisted, high compression ratio diesel engine. The compactness and predicted efficiency of the system make it suitable for application to line-haul railroad locomotives. Two overall conclusions resulted from Task 1. First direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risk associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept. The significant conclusions from Task 2 were: An engine concept, derived from a Caterpillar 3600 series engine, and a fuel processor concept, based on scaling up a removable-canister configuration from the test rig, appear feasible; and although the results of this concept study are encouraging, further, full-scale component research and development are required before attempting a full-scale integrated system demonstration effort.

  15. Fundamentals of High Pressure Combustion Chapter in High Pressure Processes in Chemical Engineering, Edited by Maximillian Lackner,

    E-Print Network [OSTI]

    Miller, Richard S.

    [2]. Furthermore, gas turbine combustion pres- sures have been increasing at a near linear rateFundamentals of High Pressure Combustion Chapter in High Pressure Processes in Chemical Engineering of the following chapter is to present an overview of the fundamentals of combustion processes in high pressure

  16. Steam Plant Conversion Eliminating Campus Coal Use

    E-Print Network [OSTI]

    Dai, Pengcheng

    Steam Plant Conversion Eliminating Campus Coal Use at the Steam Plant #12; Flagship campus region produce 14% of US coal (TN only 0.2%) Knoxville and the TN Valley #12; UT is one of about 70 U.S. colleges and universities w/ steam plant that burns coal Constructed in 1964, provides steam for

  17. A Computer Program for Simulating Transient Behavior in Steam Turbine Stage Pressure of AHWR

    SciTech Connect (OSTI)

    Dutta, Anu; Thangamani, I.; Chakraborty, G.; Ghosh, A.K.; Kushwaha, H.S. [Bhabha Atomic Research Centre, Trombay, Mumbai - 400 085 (India)

    2006-07-01T23:59:59.000Z

    It is proposed to couple the Advanced Heavy water reactor (AHWR), which is being developed by Bhabha Atomic Research Centre, India, with a desalination plant. The objective of this coupling is to produce system make-up and domestic water. The proposed desalination plant needs about 1.9 kg/sec of steam and the minimum pressure requirement is 3 bars. The desalination plant can be fed with bled steam extracted from a suitable stage in low pressure turbine. As the turbine stage pressure changes with the load, it is essential to know the availability of bled steam at aforesaid pressure for various load condition. The objective of the present study is to identify a suitable extraction point so as to ensure availability of steam at desired condition for desalination plant, even at part load conditions. In order to fulfill the above objective a steam and feed system analysis code was developed which incorporates the mathematical formulation of different components of the steam and feed system such as, high pressure (HP) and low pressure (LP) turbines, re-heater, feed heaters etc. The dynamic equations are solved simultaneously to obtain the stage pressure at various load conditions. Based on the results obtained, the suitable extraction stage in LP turbine was selected. This enables to determine the lowest possible part load operation up to which availability of desalination plant could be ensured. (authors)

  18. Steam Quality

    E-Print Network [OSTI]

    Johnston, W.

    between the water level and the steam in a boiler, some water vapor will always tend to pass through the system with the steam. Hence, a continuing problem. If steam does carry water vapor past the separators it will tend to coalesce as a liquid...

  19. High Pressure Fuel Storage Cylinders Periodic Inspection and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    from Practical Field Experience with High Pressure Gaseous Fuels Natural Gas Vehicle Cylinder Safety, Training and Inspection Project The Compelling Case for Natural Gas Vehicles...

  20. High-pressure Magic Angle Spinning Nuclear Magnetic Resonance...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    advantage of ceramic cylinders for withstanding very high-pressure utilized, but also plastic bushings can be glued tightly in place so that other plastic sealing mechanisms...

  1. Sandia National Laboratories: structural material at high pressure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    structural material at high pressure ECIS-I2CNER: Hydrogen Infrastructure Research Aids Energy Independence Goal On February 14, 2013, in CRF, Energy, Livermore Valley Open Campus...

  2. accessing high pressure: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    place, rem... Liva, Gianluigi; Chiani, Marco 2010-01-01 102 Selection of High Strength Encapsulant for MEMS Devices Undergoing High Pressure Packaging CERN Preprints Summary:...

  3. advanced high pressure: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    interference with increased pressure. We Lee, Tonghun 87 Selection of High Strength Encapsulant for MEMS Devices Undergoing High Pressure Packaging CERN Preprints Summary:...

  4. Energy Systems High Pressure Test Laboratory (Fact Sheet), NREL...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National laboratories Contact Us If you are interested in working with NREL's Energy Systems High Pressure Test Laboratory, please contact: ESIF Manager Carolyn Elam...

  5. Rotating diffuser for pressure recovery in a steam cooling circuit of a gas turbine

    DOE Patents [OSTI]

    Eldrid, Sacheverel Q. (Saratoga Springs, NY); Salamah, Samir A. (Niskayuna, NY); DeStefano, Thomas Daniel (Ballston Lake, NY)

    2002-01-01T23:59:59.000Z

    The buckets of a gas turbine are steam-cooled via a bore tube assembly having concentric supply and spent cooling steam return passages rotating with the rotor. A diffuser is provided in the return passage to reduce the pressure drop. In a combined cycle system, the spent return cooling steam with reduced pressure drop is combined with reheat steam from a heat recovery steam generator for flow to the intermediate pressure turbine. The exhaust steam from the high pressure turbine of the combined cycle unit supplies cooling steam to the supply conduit of the gas turbine.

  6. Humidification Steam vs. Water-Spray

    E-Print Network [OSTI]

    Gidwani, B. N.; Weston, R. F.

    1984-01-01T23:59:59.000Z

    Currently the HVAC systems which require winter humidification at Goddard Space Flight Center (GSFC) utilize an economizer cycle with steam as the source for humidification. Due to the continuously increasing cost of producing steam, a feasibility...

  7. Competition between vitrification and crystallization of methanol at high pressure

    E-Print Network [OSTI]

    Vos, Willem L.

    Competition between vitrification and crystallization of methanol at high pressure Marco J. P methanol at high pressure up to 33 GPa at room temperature with x-ray diffraction, optical polarization and vitrification is observed when methanol is superpressed beyond the freezing pressure of 3.5 GPa: between 5

  8. Structure of crystalline methanol at high pressure David R. Allan

    E-Print Network [OSTI]

    Vos, Willem L.

    Structure of crystalline methanol at high pressure David R. Allan Department of Physics structure, including all atomic positions, of methanol at high pressure and room temperature pressure of methanol is 3.5 GPa. In practice however, it is very easy to superpress the liquid phase

  9. Hydrous silicate melt at high pressure Mainak Mookherjee1

    E-Print Network [OSTI]

    Stixrude, Lars

    LETTERS Hydrous silicate melt at high pressure Mainak Mookherjee1 , Lars Stixrude2 & Bijaya Karki3 The structure and physical properties of hydrous silicate melts and the solubility of water in melts over most in structure to our finding that the water­silicate system becomes increasingly ideal at high pressure: we find

  10. High pressure low heat rate phosphoric acid fuel cell stack

    SciTech Connect (OSTI)

    Wertheim, R.J.

    1987-07-07T23:59:59.000Z

    A high pressure phosphoric acid fuel cell stack assembly is described comprising: (a) a stack of fuel cells for producing electricity, the stack including cathode means, anode means, and heat exchange means; (b) means for delivering pressurized air to the cathode means; (c) means for delivering a hydrogen rich fuel gas to the anode means for electrochemically reacting with oxygen in the pressurized air to produce electricity and water; (d) first conduit means connected to the cathode means for exhausting a mixture of oxygen-depleted air and reaction water from the cathode means; (e) second conduit means connected to the first conduit means for delivering a water fog to the first conduit means for entrainment in the mixture of oxygen-depleted air and reaction water to form a two phase coolant having a gaseous air phase and an entrained water droplet phase; (f) means for circulating the coolant to the heat exchange means to cool the stack solely through vaporization of the water droplet phase in the heat exchange means whereby a mixed gas exhaust of air and water vapor is exhausted from the heat exchange means; and (g) means for heating the mixed gas exhaust and delivering the heated mixed gas exhaust at reformer reaction temperatures to an autothermal reformer in the stack assembly for autothermal reaction with a raw fuel to form the hydrogen rich fuel.

  11. Steam Pricing

    E-Print Network [OSTI]

    Jones, K. C.

    . But he uses it to drive a steam turbine which in turn drives a pump. The turbine expands the steam to a lower pressure where it is then condensed and the condensate returned to the boiler house. Let's find out what the steam is worth to this user. His... while the 15 psig condensing turbine is a good candidate to be replaced with an electric motor. But, whatever the case is, the cost of the steam has nothing to do with its value. The point of the above is that this paper is about COST...

  12. Optical wet steam monitor

    DOE Patents [OSTI]

    Maxey, L.C.; Simpson, M.L.

    1995-01-17T23:59:59.000Z

    A wet steam monitor determines steam particle size by using laser doppler velocimeter (LDV) device to produce backscatter light. The backscatter light signal is processed with a spectrum analyzer to produce a visibility waveform in the frequency domain. The visibility waveform includes a primary peak and a plurality of sidebands. The bandwidth of at least the primary frequency peak is correlated to particle size by either visually comparing the bandwidth to those of known particle sizes, or by digitizing the waveform and comparing the waveforms electronically. 4 figures.

  13. Optical wet steam monitor

    DOE Patents [OSTI]

    Maxey, Lonnie C. (Powell, TN); Simpson, Marc L. (Knoxville, TN)

    1995-01-01T23:59:59.000Z

    A wet steam monitor determines steam particle size by using laser doppler velocimeter (LDV) device to produce backscatter light. The backscatter light signal is processed with a spectrum analyzer to produce a visibility waveform in the frequency domain. The visibility waveform includes a primary peak and a plurality of sidebands. The bandwidth of at least the primary frequency peak is correlated to particle size by either visually comparing the bandwidth to those of known particle sizes, or by digitizing the waveform and comparing the waveforms electronically.

  14. Diffraction studies of order?disorder at high pressures and temperatures

    SciTech Connect (OSTI)

    Parise, John B.; Antao, Sytle M.; Martin, Charles D.; Crichton, Wilson (SBU); (ESRF)

    2008-06-18T23:59:59.000Z

    Recent developments at synchrotron X-ray beamlines now allow collection of data suitable for structure determination and Rietveld structure refinement at high pressures and temperatures on challenging materials. These include materials, such as dolomite (CaMg(CO{sub 3}){sub 2}) that tends to calcine at high temperatures, and Fe-containing materials, such as the spinel MgFe{sub 2}O{sub 4}, which tend to undergo changes in oxidation state. Careful consideration of encapsulation along with the use of radial collimation produced powder diffraction patterns virtually free of parasitic scattering from the cell in the case of large volume high-pressure experiments. These features have been used to study a number of phase transitions, especially those where superior signal-to-noise discrimination is required to distinguish weak ordering reflections. The structures adopted by dolomite, and CaSO4, anhydrite, were determined from 298 to 1466 K at high pressures. Using laser-heated diamond-anvil cells to achieve simultaneous high pressure and temperature conditions, we have observed CaSO{sub 4} undergo phase transitions to the monazite type and at highest pressure and temperature to crystallize in the barite-type structure. On cooling, the barite structure distorts, from an orthorhombic to a monoclinic lattice, to produce the AgMnO{sub 4}-type structure.

  15. Thomas Reddinger Director, Steam

    E-Print Network [OSTI]

    Raina, Ramesh

    Thomas Reddinger Director, Steam Operations Steven Richards Assistant Manager of Maintenance (Distribution) Deborah Moorhead Office Coordinator III Martin Bower Steam Plant Operator Richard Redfield Steam Plant Operator Bohdan Sawa Steam Plant Operator Robert Tedesco Steam Plant Operator James Bradley

  16. Thomas Reddinger Director, Steam

    E-Print Network [OSTI]

    Mather, Patrick T.

    Thomas Reddinger Director, Steam Operations Steven Richards Assistant Manager of Maintenance Bourdon Steam Plant Operator Vincent Massara Steam Plant Operator Cliff Lescenski Steam Plant Operator Robert Tedesco Steam Plant Operator James Bradley Equipment Maintenance Robert Earle Equipment

  17. Viscosities of natural gases at high pressures and high temperatures

    E-Print Network [OSTI]

    Viswanathan, Anup

    2007-09-17T23:59:59.000Z

    Estimation of viscosities of naturally occurring petroleum gases provides the information needed to accurately work out reservoir-engineering problems. Existing models for viscosity prediction are limited by data, especially at high pressures...

  18. DOE Hydrogen Delivery High-Pressure Tanks and Analysis Project...

    Broader source: Energy.gov (indexed) [DOE]

    the DOE Hydrogen Delivery High-Pressure Tanks and Analysis Project Review Meeting at Argonne National Laboratory. The purpose of the meeting was to review the progress and plans...

  19. High pressure water jet cutting of sugar cane

    E-Print Network [OSTI]

    Valco, Thomas Donald

    1977-01-01T23:59:59.000Z

    HIGH PRESSURE WATER JET CUTTING OF SUGAR CANE A Thesis by THOMAS DONALD VALCO Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE May 1977 Major Subject...: Agricultural Engineering HIGH PRESSURE WATER JET CUTTING OF SUGAR CANE A Thesis by THOMAS DONALD VALCO Approved as to style and content by: Dr. Charlie G. Coble (Chairman of Committee) Dr. Edward A. Haler (Head of Department) Mr. William H. Aldred...

  20. High pressure discharges in cavities formed by microfabrication techniques

    SciTech Connect (OSTI)

    Khan, B.A.; Cammack, D.A.; Pinker, R.D.; Racz, J. [Philips Electronics North America Corporation, Philips Research, Briarcliff Manor, New York 10510 (United States)] [Philips Electronics North America Corporation, Philips Research, Briarcliff Manor, New York 10510 (United States)

    1997-07-01T23:59:59.000Z

    High pressure discharges are the basis of small high intensity light sources. In this work, we demonstrate the formation of high pressure discharges, in cavities formed by applying micromachining and integrated circuit techniques to quartz substrates. Cavities containing varying amounts of mercury and argon were fabricated to obtain high pressure discharges. A high pressure mercury discharge was formed in the electrodeless cavities by exciting them with a microwave source, operating at 2.45 GHz and in the electroded cavities by applying a dc voltage. The contraction of the discharge into a high pressure arc was observed. A broad emission spectrum due to self-absorption and collisions between excited atoms and normal atoms, typical of high pressure mercury discharges, was measured. The light output and efficacy increased with increasing pressure. The measured voltage was used to estimate the pressure within the electroded cavities, which is as high as 127 atm for one of the two cavities discussed in this work. Efficacies over 40 lumens per watt were obtained for the electrodeless cavities and over 50 scr(l)m/W for the electroded cavities. {copyright} {ital 1997 American Institute of Physics.}

  1. High pressure melt ejection and direct containment heating in ice condenser containments

    SciTech Connect (OSTI)

    Pilch, M.; Tarbell, W.W.; Carroll, D.E.; Tills, J.L.

    1986-01-01T23:59:59.000Z

    A response of a typical ice condenser containment to a high pressure melt dispersal accident has been studied. While ice beds may be effective in reducing the potential loading caused by direct heating of the containment atmosphere, analyses suggest two other modes of containment failure that have not been previously identified. Calculations with the CONTAIN code indicate that ejected core debris may interact with steam from the primary system, generating sufficient hydrogen to threaten containment integrity. Further, if the debris ejected into the cavity promptly fails the seal table, the dispersed material could enter the in-core instrument room and attack the containment liner. The timing of the failure of the seal table is highly dependent on the characteristics of the debris-to-steel energy transfer.

  2. Energy Systems High Pressure Test Laboratory (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2011-10-01T23:59:59.000Z

    This fact sheet describes the purpose, lab specifications, applications scenarios, and information on how to partner with NREL's Energy Systems High Pressure Test Laboratory at the Energy Systems Integration Facility. The purpose of the Energy Systems High Pressure Test Laboratory at NREL's Energy Systems Integration Facility (ESIF) is to provide space where high pressure hydrogen components can be safely tested. High pressure hydrogen storage is an integral part of energy storage technology for use in fuel cell and in other distributed energy scenarios designed to effectively utilize the variability inherent with renewable energy sources. The high pressure storage laboratory is co-located with energy storage activities such as ultra-capacitors, super conducting magnetic flywheel and mechanical energy storage systems laboratories for an integrated approach to system development and demonstration. Hazards associated with hydrogen storage at pressures up to 10,000 psi include oxygen displacement, combustion, explosion, and pressurization of room air due to fast release and physical hazards associated with burst failure modes. A critical understanding of component failure modes is essential in developing reliable, robust designs that will minimize failure risk beyond the end of service life. Development of test protocol for accelerated life testing to accurately scale to real world operating conditions is essential for developing regulations, codes and standards required for safe operation. NREL works closely with industry partners in providing support of advanced hydrogen technologies. Innovative approaches to product design will accelerate commercialization into new markets. NREL works with all phases of the product design life cycle from early prototype development to final certification testing. High pressure tests are performed on hydrogen components, primarily for the validation of developing new codes and standards for high pressure hydrogen applications. The following types of tests can be performed: Performance, Component and system level efficiency, Strength of materials and hydrogen compatibility, Safety demonstration, Model validation, and Life cycle reliability.

  3. Steam Path Audits on Industrial Steam Turbines

    E-Print Network [OSTI]

    Mitchell, D. R.

    in sellable power output as a result of improved turbine efficiency. The Lyondell facility is a combined cycle power plant where a gas turbine: heat recovery system supplies steam to the steam turbine. Since this steam is a bypropuct of the gas turbine...steam Path Audits on Industrial steam Turbines DOUGLAS R. MITCHELL. ENGINEER. ENCOTECH, INC., SCHENECTADY, NEW YORK ABSTRACT The electric utility industry has benefitted from steam path audits on steam turbines for several years. Benefits...

  4. Flash High-Pressure Condensate to Regenerate Low-Pressure Steam |

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO2: FinalOffers New Training on Energy6

  5. BILIWG Meeting: High Pressure Steam Reforming of Bio-Derived Liquids

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: The FutureComments fromof Energy

  6. Design of Hybrid Steam-In Situ Combustion Bitumen Recovery Processes

    SciTech Connect (OSTI)

    Yang Xiaomeng; Gates, Ian D. [University of Calgary, Department of Chemical and Petroleum Engineering (Canada)], E-mail: ian.gates@ucalgary.ca

    2009-09-15T23:59:59.000Z

    Given enormous capital costs, operating expenses, flue gas emissions, water treatment and handling costs of thermal in situ bitumen recovery processes, improving the overall efficiency by lowering energy requirements, environmental impact, and costs of these production techniques is a priority. Steam-assisted gravity drainage (SAGD) is the most widely used in situ recovery technique in Athabasca reservoirs. Steam generation is done on surface and consequently, because of heat losses, the energy efficiency of SAGD can never be ideal with respect to the energy delivered to the sandface. An alternative to surface steam generation is in situ combustion (ISC) where heat is generated within the formation through injection of oxygen at a sufficiently high pressure to initiate combustion of bitumen. In this manner, the heat from the combustion reactions can be used directly to mobilize the bitumen. As an alternative, the heat can be used to generate steam within the formation which then is the agent to move heat in the reservoir. In this research, alternative hybrid techniques with simultaneous and sequential steam-oxygen injection processes are examined to maximize the thermal efficiency of the recovery process. These hybrid processes have the advantage that during ISC, steam is generated within the reservoir from injected and formation water and as a product of oxidation. This implies that ex situ steam generation requirements are reduced and if there is in situ storage of combustion gases, that overall gas emissions are reduced. In this research, detailed reservoir simulations are done to examine the dynamics of hybrid processes to enable design of these processes. The results reveal that hybrid processes can lower emitted carbon dioxide-to-oil ratio by about 46%, decrease the consumed natural gas-to-oil ratio by about 73%, reduce the cumulative energy-to-oil ratio by between 40% and 70% compared to conventional SAGD, and drop water consumption per unit oil produced. However, oil recovery is between 25% and 40% below that of SAGD. Design of successful hybrid steam-oxygen processes must take into account the balance between injected steam and amount of injected oxygen and combustion gas products that dilute injected and in situ-generated steam in the depletion chamber by lowering its partial pressure, and thus its saturation temperature which in turn impacts production rates and recovery.

  7. Confinement of hydrogen at high pressure in carbon nanotubes

    DOE Patents [OSTI]

    Lassila, David H. (Aptos, CA); Bonner, Brian P. (Livermore, CA)

    2011-12-13T23:59:59.000Z

    A high pressure hydrogen confinement apparatus according to one embodiment includes carbon nanotubes capped at one or both ends thereof with a hydrogen-permeable membrane to enable the high pressure confinement of hydrogen and release of the hydrogen therethrough. A hydrogen confinement apparatus according to another embodiment includes an array of multi-walled carbon nanotubes each having first and second ends, the second ends being capped with palladium (Pd) to enable the high pressure confinement of hydrogen and release of the hydrogen therethrough as a function of palladium temperature, wherein the array of carbon nanotubes is capable of storing hydrogen gas at a pressure of at least 1 GPa for greater than 24 hours. Additional apparatuses and methods are also presented.

  8. Evidence of Tetragonal Nanodomains in the high pressure polymorph

    SciTech Connect (OSTI)

    Ehm, L.; Borkowski, L.A.; Parise J.B.; Ghose, S.; Chen, Z.

    2010-12-17T23:59:59.000Z

    The pressure induced P4mm {yields} Pm{bar 3}m phase transition in BaTiO{sub 3} perovskite was investigated by x-ray total scattering. The evolution of the structure was analyzed by fitting pair distribution functions over a pressure range from ambient pressure up to 6.85(7) GPa. Evidence for the existence of tetragonal ferroelectric nanodomains at high pressure was found. The average size of the nanodomains in the high-pressure phase decreases with increasing pressure. Extrapolation of the domain size to pressures higher than studied experimentally suggests a disappearance of the ferroelectric domains at about 9.3(5) GPa and a cubic symmetry of BaTiO{sub 3} high-pressure phase.

  9. High Pressure Hydrogen Materials Compatibility of Piezoelectric Films

    SciTech Connect (OSTI)

    Alvine, Kyle J.; Shutthanandan, V.; Bennett, Wendy D.; Bonham, Charles C.; Skorski, Daniel C.; Pitman, Stan G.; Dahl, Michael E.; Henager, Charles H.

    2010-12-02T23:59:59.000Z

    Abstract: Hydrogen is being considered as a next-generation clean burning fuel. However, hydrogen has well known materials issues, including blistering and embrittlement in metals. Piezoelectric materials are used as actuators in hydrogen fuel technology. We present studies of materials compatibility of piezoelectric films in a high pressure hydrogen environment. Absorption of high pressure hydrogen was studied with Elastic Recoil Detection Analysis (ERDA) and Rutherford Back Scattering (RBS) in lead zirconate titanate (PZT) and barium titanate (BTO) thin films. Hydrogen surface degradation in the form of blistering and Pb mixing was also observed.

  10. Capillary toroid cavity detector for high pressure NMR

    DOE Patents [OSTI]

    Gerald, II, Rex E. (Brookfield, IL); Chen, Michael J. (Downers Grove, IL); Klingler, Robert J. (Glenview, IL); Rathke, Jerome W. (Honer Glen, IL); ter Horst, Marc (Chapel Hill, NC)

    2007-09-11T23:59:59.000Z

    A Toroid Cavity Detector (TCD) is provided for implementing nuclear magnetic resonance (NMR) studies of chemical reactions under conditions of high pressures and temperatures. A toroid cavity contains an elongated central conductor extending within the toroid cavity. The toroid cavity and central conductor generate an RF magnetic field for NMR analysis. A flow-through capillary sample container is located within the toroid cavity adjacent to the central conductor to subject a sample material flowing through the capillary to a static magnetic field and to enable NMR spectra to be recorded of the material in the capillary under a temperature and high pressure environment.

  11. accompanying high-pressure phase: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    pressure cryocooling Abstract High-pressure methods for solving Gruner, Sol M. 58 High-pressure studies of ammonia hydrates Edinburgh, University of - Research Archive Summary:...

  12. Steam Basics: Use Available Data to Lower Steam System Cost

    E-Print Network [OSTI]

    Risko, J. R.

    2011-01-01T23:59:59.000Z

    of the 2011 Industrial Energy Technology Conference New Orleans, Louisiana, May 17-19, 2011 13. Is there never enough time or resource to periodically blow down strainers / drip pockets? 14. Is there a ?one size fits all? approach towards steam trap... selection; using the same model for all drip and tracer applications? 15. Does the site remove strainer screens from steam traps to prevent blockage? 16. Is at least the same amount of steam produced today as 4 years ago? 17. In the past 3 years, has...

  13. Ultra-high pressure water jet: Baseline report

    SciTech Connect (OSTI)

    NONE

    1997-07-31T23:59:59.000Z

    The ultra-high pressure waterjet technology was being evaluated at Florida International University (FIU) as a baseline technology. In conjunction with FIU`s evaluation of efficiency and cost, this report covers the evaluation conducted for safety and health issues. It is a commercially available technology and has been used for various projects at locations throughout the country. The ultra-high pressure waterjet technology acts as a cutting tool for the removal of surface substrates. The Husky{trademark} pump feeds water to a lance that directs the high pressure water at the surface to be removed. The safety and health evaluation during the testing demonstration focused on two main areas of exposure. These were dust and noise. The dust exposure was found to be minimal, which would be expected due to the wet environment inherent in the technology, but noise exposure was at a significant level. Further testing for noise is recommended because of the outdoor environment where the testing demonstration took place. In addition, other areas of concern found were arm-hand vibration, ergonomics, heat stress, tripping hazards, electrical hazards, lockout/tagout, fall hazards, slipping hazards, hazards associated with the high pressure water, and hazards associated with air pressure systems.

  14. Neutron scattering at high pressure D. B. McWhan

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    715 Neutron scattering at high pressure D. B. McWhan Room 1D-234, Murray Hill, New Jersey 07974, U scattering at steady-state and pulsed sources are reviewed. The pressure cells available at most neutron 10 GPa have been made. For elastic scattering, a comparison is made between neutron scattering and X

  15. High Pressure Research Questionnaire National High Magnetic Field Laboratory

    E-Print Network [OSTI]

    Weston, Ken

    this mounting wax, the sample will be exposed to temperature between 150 and 200 C for a period of 3-10 minutes, and steam) ___Toluene (GE varnish solvent) ___N,N-Dimethyacetamide (used to dissolve conductive epoxy

  16. Advanced High-Temperature, High-Pressure Transport Reactor Gasification

    SciTech Connect (OSTI)

    Michael L. Swanson

    2005-08-30T23:59:59.000Z

    The transport reactor development unit (TRDU) was modified to accommodate oxygen-blown operation in support of a Vision 21-type energy plex that could produce power, chemicals, and fuel. These modifications consisted of changing the loop seal design from a J-leg to an L-valve configuration, thereby increasing the mixing zone length and residence time. In addition, the standpipe, dipleg, and L-valve diameters were increased to reduce slugging caused by bubble formation in the lightly fluidized sections of the solid return legs. A seal pot was added to the bottom of the dipleg so that the level of solids in the standpipe could be operated independently of the dipleg return leg. A separate coal feed nozzle was added that could inject the coal upward into the outlet of the mixing zone, thereby precluding any chance of the fresh coal feed back-mixing into the oxidizing zone of the mixing zone; however, difficulties with this coal feed configuration led to a switch back to the original downward configuration. Instrumentation to measure and control the flow of oxygen and steam to the burner and mix zone ports was added to allow the TRDU to be operated under full oxygen-blown conditions. In total, ten test campaigns have been conducted under enriched-air or full oxygen-blown conditions. During these tests, 1515 hours of coal feed with 660 hours of air-blown gasification and 720 hours of enriched-air or oxygen-blown coal gasification were completed under this particular contract. During these tests, approximately 366 hours of operation with Wyodak, 123 hours with Navajo sub-bituminous coal, 143 hours with Illinois No. 6, 106 hours with SUFCo, 110 hours with Prater Creek, 48 hours with Calumet, and 134 hours with a Pittsburgh No. 8 bituminous coal were completed. In addition, 331 hours of operation on low-rank coals such as North Dakota lignite, Australian brown coal, and a 90:10 wt% mixture of lignite and wood waste were completed. Also included in these test campaigns was 50 hours of gasification on a petroleum coke from the Hunt Oil Refinery and an additional 73 hours of operation on a high-ash coal from India. Data from these tests indicate that while acceptable fuel gas heating value was achieved with these fuels, the transport gasifier performs better on the lower-rank feedstocks because of their higher char reactivity. Comparable carbon conversions have been achieved at similar oxygen/coal ratios for both air-blown and oxygen-blown operation for each fuel; however, carbon conversion was lower for the less reactive feedstocks. While separation of fines from the feed coals is not needed with this technology, some testing has suggested that feedstocks with higher levels of fines have resulted in reduced carbon conversion, presumably due to the inability of the finer carbon particles to be captured by the cyclones. These data show that these low-rank feedstocks provided similar fuel gas heating values; however, even among the high-reactivity low-rank coals, the carbon conversion did appear to be lower for the fuels (brown coal in particular) that contained a significant amount of fines. The fuel gas under oxygen-blown operation has been higher in hydrogen and carbon dioxide concentration since the higher steam injection rate promotes the water-gas shift reaction to produce more CO{sub 2} and H{sub 2} at the expense of the CO and water vapor. However, the high water and CO{sub 2} partial pressures have also significantly reduced the reaction of (Abstract truncated)

  17. High pressure argon ionization chamber systems for the measurement of environmental radiation exposure rates

    E-Print Network [OSTI]

    DeCampo, J A; Raft, P D

    1972-01-01T23:59:59.000Z

    High pressure argon ionization chamber systems for the measurement of environmental radiation exposure rates

  18. Proposal for high pressure RF cavity test in the MTA

    SciTech Connect (OSTI)

    Yonehara, K.; /Fermilab

    2010-09-01T23:59:59.000Z

    In order to demonstrate the feasibility of high pressure hydrogen gas filled RF (HPRF) cavities for muon ionization cooling, an HPRF cavity must be tested with a high intensity charged beam. When an HPRF cavity is irradiated with an intense beam each incident particle generates about 1000 electrons and ions per cubic centimeter in a high pressure cavity via ionization. These ionization electrons are influenced by the RF field and the RF quality factor goes down. This Q factor reduction will be a problem with a multi bunch beam, e.g., a muon beam for a muon collider consists of a 12 to 20 bunch train beam with 5 ns timing gap. Thus, the RF field must recover in few nano seconds. We propose to use a 400 MeV proton beam in the MTA and measure a beam loading effect in the HPRF cavity and study the recovery mechanism of the RF field.

  19. Aging study of boiling water reactor high pressure injection systems

    SciTech Connect (OSTI)

    Conley, D.A.; Edson, J.L.; Fineman, C.F. [Lockheed Idaho Technologies Co., Idaho Falls, ID (United States)

    1995-03-01T23:59:59.000Z

    The purpose of high pressure injection systems is to maintain an adequate coolant level in reactor pressure vessels, so that the fuel cladding temperature does not exceed 1,200{degrees}C (2,200{degrees}F), and to permit plant shutdown during a variety of design basis loss-of-coolant accidents. This report presents the results of a study on aging performed for high pressure injection systems of boiling water reactor plants in the United States. The purpose of the study was to identify and evaluate the effects of aging and the effectiveness of testing and maintenance in detecting and mitigating aging degradation. Guidelines from the United States Nuclear Regulatory Commission`s Nuclear Plant Aging Research Program were used in performing the aging study. Review and analysis of the failures reported in databases such as Nuclear Power Experience, Licensee Event Reports, and the Nuclear Plant Reliability Data System, along with plant-specific maintenance records databases, are included in this report to provide the information required to identify aging stressors, failure modes, and failure causes. Several probabilistic risk assessments were reviewed to identify risk-significant components in high pressure injection systems. Testing, maintenance, specific safety issues, and codes and standards are also discussed.

  20. Reinvestigation of high pressure polymorphism in hafnium metal

    SciTech Connect (OSTI)

    Pandey, K. K., E-mail: kkpandey@barc.gov.in; Sharma, Surinder M. [High Pressure and Synchrotron Radiation Physics Division, Bhabha Atomic Research Centre, Mumbai-400 085 (India); Gyanchandani, Jyoti; Dey, G. K. [Materials Science Division, Bhabha Atomic Research Centre, Mumbai-400 085 (India); Somayazulu, M. [Geophysical Laboratory, Carnegie Institution of Washington, Washington, D.C. 20015 (United States); Sikka, S. K. [Indian National Science Academy, New Delhi-110 002 (India)

    2014-06-21T23:59:59.000Z

    There has been a recent controversy about the high pressure polymorphism of Hafnium (Hf). Unlike, the earlier known ??? structural transition at 38??8?GPa, at ambient temperature, Hrubiak et al. [J. Appl. Phys. 111, 112612 (2012)] did not observe it till 51?GPa. They observed this transition only at elevated temperatures. We have reinvestigated the room temperature phase diagram of Hf, employing x-ray diffraction (XRD) and DFT based first principles calculations. Experimental investigations have been carried out on several pure and impure Hf samples and also with different pressure transmitting media. Besides demonstrating the significant role of impurity levels on the high pressure phase diagram of Hf, our studies re-establish room temperature ??? transition at high pressures, even in quasi-hydrostatic environment. We observed this transition in pure Hf with equilibrium transition pressure P{sub o}?=?44.5?GPa; however, with large hysteresis. The structural sequence, transition pressures, the lattice parameters, the c/a ratio and its variation with compression for the ? and ? phases as predicted by our ab-initio scalar relativistic (SR) calculations are found to be in good agreement with our experimental results of pure Hf.

  1. Dislocation density evolution during high pressure torsion of a nanocrystalline Ni-Fe alloy

    SciTech Connect (OSTI)

    Li, Hongqi [Los Alamos National Laboratory; Wang, Y B [NON LANL; Ho, J C [NON LANL; Cao, Y [NON LANL; Liao, X Z [NON LANL; Ringer, S P [NON LANL; Zhu, Y T [NON LANL; Zhao, Y H [NON LANL; Lavernia, E J [NON LANL

    2009-01-01T23:59:59.000Z

    High-pressure torsion (HPT) induced dislocation density evolution in a nanocrystalline Ni-20wt.%Fe alloy was investigated using X-ray diffraction and transmission electron microscopy. Results suggest that the dislocation density evolution is different from that in coarse-grained materials. An HPT process first reduces the dislocation density within nanocrystalline grains and produces a large number of dislocations located at small-angle sub grain boundaries that are formed via grain rotation and coalescence. Continuing the deformation process eliminates the sub grain boundaries but significantly increases the dislocation density in grains. This phenomenon provides an explanation of the mechanical behavior of some nanostructured materials.

  2. Thomas Reddinger Director, Steam

    E-Print Network [OSTI]

    McConnell, Terry

    Thomas Reddinger Director, Steam Operations Steven Richards Assistant Manager of Maintenance Supervisor (Distribution) Deborah Moorhead Office Coordinator III Martin Bower Steam Plant Operator Richard Redfield Steam Plant Operator SU Steam Station/Chilled Water Plant Bohdan Sawa Steam Plant Operator Robert

  3. Water cooled steam jet

    DOE Patents [OSTI]

    Wagner, Jr., Edward P. (Idaho Falls, ID)

    1999-01-01T23:59:59.000Z

    A water cooled steam jet for transferring fluid and preventing vapor lock, or vaporization of the fluid being transferred, has a venturi nozzle and a cooling jacket. The venturi nozzle produces a high velocity flow which creates a vacuum to draw fluid from a source of fluid. The venturi nozzle has a converging section connected to a source of steam, a diffuser section attached to an outlet and a throat portion disposed therebetween. The cooling jacket surrounds the venturi nozzle and a suction tube through which the fluid is being drawn into the venturi nozzle. Coolant flows through the cooling jacket. The cooling jacket dissipates heat generated by the venturi nozzle to prevent vapor lock.

  4. Steam catalysis in CaO carbonation under low steam partial pressure

    SciTech Connect (OSTI)

    Yang, S.J.; Xiao, Y.H. [Chinese Academy of Science, Beijing (China)

    2008-06-15T23:59:59.000Z

    CaO was widely used to capture CO{sub 2} in direct hydrogen production process, where steam always existed simultaneously. The effect of steam on CaO carbonation performance under low steam partial pressure was investigated using a pressurized thermogravimetric apparatus. The experimental results revealed that steam improved CaO carbonation performance significantly no matter whether Ca(OH){sub 2} was produced or not. At 823 K and 0.5 MPa of steam partial pressure, effect of steam on CaO carbonation performance could not be attributed mainly to production of Ca(OH){sub 2} because the hydration rate of CaO was very slow. The main reason was steam catalysis in CaO carbonation. Enhancement of steam on CaO carbonation performance without Ca(OH){sub 2} production could not be attributed to improvement of steam on the physical property, but to catalytic effect of steam. Effects of CaO precursors, CO{sub 2} partial pressure, steam partial pressure, and temperature with steam addition on CaO carbonation performance were also investigated.

  5. Practical features of illumination with high pressure sodium lamps

    SciTech Connect (OSTI)

    Corth, R.

    1983-06-01T23:59:59.000Z

    A number of concerns raised about the health effects of high pressure sodium lamps (HPS) are discussed. The notion of a ''natural'' human photic environment based on sunlight is disputed. Humans are better adapted to the ''greenish'' spectral composition of forest light than to direct sunlight. It is ironic that the artificial light source which has received the most disapproval, cool white flourescent lamp, has a spectral composition similar to that of forest light. HPS is also available in a full range of colors. Some successful examples of HPS--from North Division High School, in Milwaukee, Wisconsin, to museum exhibits at National Geographic in Washington--are listed.

  6. Surface roughening of superalloys by high pressure pure waterjet

    SciTech Connect (OSTI)

    Taylor, T.A. [Praxair Surface Technologies Inc., Indianapolis, IN (United States)

    1995-12-31T23:59:59.000Z

    A high pressure waterjet has been used to study the surface roughening of superalloys as preparation for thermal spraying. Designed experiments for Mar-M 509 and Rene 80 were carried out for the effects of jet pressure and mass of water delivered per unit area. Comparisons were made of several superalloys in terms of erosion, surface roughness and topology. The mechanism of jet erosion of Rene 80 was studied in relation to its metallurgical microstructure. An MCrAlY coating by shrouded plasma spray was made over a waterjet prepared surface with excellent bonding and having an ideally clean interface.

  7. System Study: High-Pressure Coolant Injection 1998-2012

    SciTech Connect (OSTI)

    T. E. Wierman

    2013-10-01T23:59:59.000Z

    This report presents an unreliability evaluation of the high-pressure coolant injection system (HPCI) at 69 U.S. commercial nuclear power plants. Demand, run hours, and failure data from fiscal year 1998 through 2012 for selected components were obtained from the Equipment Performance and Information Exchange (EPIX). The unreliability results are trended for the most recent 10 year period while yearly estimates for system unreliability are provided for the entire active period. No statistically significant increasing or decreasing trends were identified in the HPCI results.

  8. System Study: High-Pressure Core Spray 19982012

    SciTech Connect (OSTI)

    T. E. Wierman

    2013-10-01T23:59:59.000Z

    This report presents an unreliability evaluation of the high-pressure core spray (HPCS) at 8 U.S. commercial boiling water reactors. Demand, run hours, and failure data from fiscal year 1998 through 2012 for selected components were obtained from the Equipment Performance and Information Exchange (EPIX). The unreliability results are trended for the most recent 10 year period while yearly estimates for system unreliability are provided for the entire active period. No statistically significant increasing or decreasing trends were identified in the HPCS results.

  9. System Study: High-Pressure Safety Injection 19982012

    SciTech Connect (OSTI)

    T. E. Wierman

    2013-10-01T23:59:59.000Z

    This report presents an unreliability evaluation of the high-pressure safety injection system (HPSI) at 69 U.S. commercial nuclear power plants. Demand, run hours, and failure data from fiscal year 1998 through 2012 for selected components were obtained from the Equipment Performance and Information Exchange (EPIX). The unreliability results are trended for the most recent 10 year period while yearly estimates for system unreliability are provided for the entire active period. No statistically significant increasing or decreasing trends were identified in the HPSI results.

  10. High-Pressure MOF Research Yields Structural Insights

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC) EnvironmentalGyroSolé(tm) Harmonicbet WhenHiggsmiddlewareHigh-Pressure MOF

  11. High-Pressure MOF Research Yields Structural Insights

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh School football High School football FancyDepartment ofHigh-Pressure

  12. High-Pressure MOF Research Yields Structural Insights

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh School football High School football FancyDepartmentHigh-Pressure MOF

  13. High-Pressure MOF Research Yields Structural Insights

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh School football High School football FancyDepartmentHigh-Pressure

  14. High-Pressure MOF Research Yields Structural Insights

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh School football High School footballHigh-Pressure MOF Research Yields

  15. Working with SRNL - Our Facilities- High Pressure Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron SpinPrincetonUsingWhat is abigpresentedMetal HydrideHigh Pressure

  16. Steam and Condensate Systems

    E-Print Network [OSTI]

    Yates, W.

    1979-01-01T23:59:59.000Z

    efficiency and profit. Some important factors to consider in steam and condensate systems are: 1) Proper steam pressure 2) Adequate sized steam lines 3) Adequate sized condensate return lines 4) Utilization of flash steam 5) Properly sized... ! can cause system inefficiency. i Adequate sized steam lines assure the process will be furnished with sufficiertt i quantities of steam at the proper pressure. Adequate sized condensate return lines are essential to overall efficiency. lhese...

  17. Steam System Optimization

    E-Print Network [OSTI]

    Aegerter, R. A.

    flanges, control valves, steam turbines, manways, sections of piping, heads on vessels, etc. are uninsulated. If steam is in demand at the steam pressure level of the uninsulated piping and equipment, then the piping and equipment should be insulated... been developed, it is an excellent tool to identify the steam sources. Areas to first look for possible waste are steam turbines and steam let down stations. 161 ESL-IE-98-04-26 Proceedings from the Twentieth National Industrial Energy Technology...

  18. Steam Path Audits on Industrial Steam Turbines

    E-Print Network [OSTI]

    Mitchell, D. R.

    1992-01-01T23:59:59.000Z

    The electric utility industry has benefitted from steam path audits on steam turbines for several years. Benefits include the ability to identify areas of performance degradation during a turbine outage. Repair priorities can then be set...

  19. Acceptance test procedure for High Pressure Water Jet System

    SciTech Connect (OSTI)

    Crystal, J.B.

    1995-05-30T23:59:59.000Z

    The overall objective of the acceptance test is to demonstrate a combined system. This includes associated tools and equipment necessary to perform cleaning in the 105 K East Basin (KE) for achieving optimum reduction in the level of contamination/dose rate on canisters prior to removal from the KE Basin and subsequent packaging for disposal. Acceptance tests shall include necessary hardware to achieve acceptance of the cleaning phase of canisters. This acceptance test procedure will define the acceptance testing criteria of the high pressure water jet cleaning fixture. The focus of this procedure will be to provide guidelines and instructions to control, evaluate and document the acceptance testing for cleaning effectiveness and method(s) of removing the contaminated surface layer from the canister presently identified in KE Basin. Additionally, the desired result of the acceptance test will be to deliver to K Basins a thoroughly tested and proven system for underwater decontamination and dose reduction. This report discusses the acceptance test procedure for the High Pressure Water Jet.

  20. Microhole High-Pressure Jet Drill for Coiled Tubing

    SciTech Connect (OSTI)

    Ken Theimer; Jack Kolle

    2007-06-30T23:59:59.000Z

    Tempress Small Mechanically-Assisted High-Pressure Waterjet Drilling Tool project centered on the development of a downhole intensifier (DHI) to boost the hydraulic pressure available from conventional coiled tubing to the level required for high-pressure jet erosion of rock. We reviewed two techniques for implementing this technology (1) pure high-pressure jet drilling and (2) mechanically-assisted jet drilling. Due to the difficulties associated with modifying a downhole motor for mechanically-assisted jet drilling, it was determined that the pure high-pressure jet drilling tool was the best candidate for development and commercialization. It was also determined that this tool needs to run on commingled nitrogen and water to provide adequate downhole differential pressure and to facilitate controlled pressure drilling and descaling applications in low pressure wells. The resulting Microhole jet drilling bottomhole assembly (BHA) drills a 3.625-inch diameter hole with 2-inch coil tubing. The BHA consists of a self-rotating multi-nozzle drilling head, a high-pressure rotary seal/bearing section, an intensifier and a gas separator. Commingled nitrogen and water are separated into two streams in the gas separator. The water stream is pressurized to 3 times the inlet pressure by the downhole intensifier and discharged through nozzles in the drilling head. The energy in the gas-rich stream is used to power the intensifier. Gas-rich exhaust from the intensifier is conducted to the nozzle head where it is used to shroud the jets, increasing their effective range. The prototype BHA was tested at operational pressures and flows in a test chamber and on the end of conventional coiled tubing in a test well. During instrumented runs at downhole conditions, the BHA developed downhole differential pressures of 74 MPa (11,000 psi, median) and 90 MPa (13,000 psi, peaks). The median output differential pressure was nearly 3 times the input differential pressure available from the coiled tubing. In a chamber test, the BHA delivered up to 50 kW (67 hhp) hydraulic power. The tool drilled uncertified class-G cement samples cast into casing at a rate of 0.04 to 0.17 m/min (8 to 33 ft/hr), within the range projected for this tool but slower than a conventional PDM. While the tool met most of the performance goals, reliability requires further improvement. It will be difficult for this tool, as currently configured, to compete with conventional positive displacement downhole motors for most coil tubing drill applications. Mechanical cutters on the rotating nozzle head would improve cutting. This tool can be easily adapted for well descaling operations. A variant of the Microhole jet drilling gas separator was further developed for use with positive displacement downhole motors (PDM) operating on commingled nitrogen and water. A fit-for-purpose motor gas separator was designed and yard tested within the Microhole program. Four commercial units of that design are currently involved in a 10-well field demonstration with Baker Oil Tools in Wyoming. Initial results indicate that the motor gas separators provide significant benefit.

  1. SteamMaster: Steam System Analysis Software

    E-Print Network [OSTI]

    Wheeler, G.

    2003-01-01T23:59:59.000Z

    recommendations to increase steam system effic iency. Steam System Opportunities ]n nearly 400 industrial assessments, we have recommended 210 steam system improvements, excluding heat recovery, that would save $1.5 million/year with a O.4-year payback. 75...

  2. High Pressure Scanning Tunneling Microscopy and High Pressure X-ray Photoemission Spectroscopy Studies of Adsorbate Structure, Composition and Mobility during Catalytic Reactions on A Model Single Crystal

    E-Print Network [OSTI]

    Montano, M.O.

    2006-01-01T23:59:59.000Z

    Guntherodt, H. -J. , Eds. Scanning Tunneling Microscopy III;157. Chapter 7 : High-Pressure Scanning Tunneling Microscopypressure high-temperature scanning tunneling microscope and

  3. Beam Profile Measurement in MTA Beam Line for High Pressure RF Cavity Beam Test

    SciTech Connect (OSTI)

    Jana, M.R.; Bross, A.; Chung, M.; Greer, S.; Johnstone, C.; Kobilarcik, T.; Koizumi, G.; Leonova, M.; Moretti, A.; Popovic, M.; Schwartz, T.; /Fermilab /IIT, Chicago /PDT, Torino

    2012-05-15T23:59:59.000Z

    Recent High Pressure RF (HPRF) cavity experiment at MuCool Test Area (MTA) has used 400 MeV Linac proton beam to study the beam loading effect. When the energetic proton beam passes through the cavity, it ionizes the inside gas and produces the electrons. These electrons consume RF power inside the cavity. Number of electrons produced per cm inside the cavity (at 950 psi Hydrogen gas) per incident proton is {approx} 1200. The measurement of beam position and profile are necessary. MTA is flammable gas (Hydrogen) hazard zone so we have developed a passive beam diagnostic instrument using Chromox-6 scintillation screen and CCD camera. This paper presents quantitative information about beam position and beam profile. Neutral density filter was used to avoid saturation of CCD camera. Image data is filtered and fitted with Gaussian function to compute the beam size. The beam profile obtained from scintillation screen shall be compared with multi-wire beam profile.

  4. Devices and process for high-pressure magic angle spinning nuclear magnetic resonance

    DOE Patents [OSTI]

    Hoyt, David W; Sears, Jr., Jesse A; Turcu, Romulus V.F.; Rosso, Kevin M; Hu, Jian Zhi

    2014-04-08T23:59:59.000Z

    A high-pressure magic angle spinning (MAS) rotor is detailed that includes a high-pressure sample cell that maintains high pressures exceeding 150 bar. The sample cell design minimizes pressure losses due to penetration over an extended period of time.

  5. Engine having a high pressure hydraulic system and low pressure lubricating system

    DOE Patents [OSTI]

    Bartley, Bradley E. (Manito, IL); Blass, James R. (Bloomington, IL); Gibson, Dennis H. (Chillicothe, IL)

    2000-01-01T23:59:59.000Z

    An engine includes a high pressure hydraulic system having a high pressure pump and at least one hydraulically-actuated device attached to an engine housing. A low pressure engine lubricating system is attached to the engine housing and includes a circulation conduit fluidly connected to an outlet from the high pressure pump.

  6. The value of steam turbine upgrades

    SciTech Connect (OSTI)

    Potter, K.; Olear, D.; [General Physics Corp. (United States)

    2005-11-01T23:59:59.000Z

    Technological advances in mechanical and aerodynamic design of the turbine steam path are resulting in higher reliability and efficiency. A recent study conducted on a 390 MW pulverized coal-fired unit revealed just how much these new technological advancements can improve efficiency and output. The empirical study showed that the turbine upgrade raised high pressure (HP) turbine efficiency by 5%, intermediate pressure (IP) turbine efficiency by 4%, and low pressure (LP) turbine efficiency by 2.5%. In addition, the unit's highest achievable gross generation increased from 360 MW to 371 MW. 3 figs.

  7. LX-17 Deflagration at High Pressures and Temperatures

    SciTech Connect (OSTI)

    Koerner, J; Maienschein, J; Black, K; DeHaven, M; Wardell, J

    2006-10-23T23:59:59.000Z

    We measure the laminar deflagration rate of LX-17 (92.5 wt% TATB, 7.5 wt% Kel-F 800) at high pressure and temperature in a strand burner, thereby obtaining reaction rate data for prediction of thermal explosion violence. Simultaneous measurements of flame front time-of-arrival and temporal pressure history allow for the direct calculation of deflagration rate as a function of pressure. Additionally, deflagrating surface areas are calculated in order to provide quantitative insight into the dynamic surface structure during deflagration and its relationship to explosion violence. Deflagration rate data show that LX-17 burns in a smooth fashion at ambient temperature and is represented by the burn rate equation B = 0.2P{sup 0.9}. At 225 C, deflagration is more rapid and erratic. Dynamic deflagrating surface area calculations show that ambient temperature LX-17 deflagrating surface areas remain near unity over the pressure range studied.

  8. High-pressure lubricity at the meso- and nanoscale

    E-Print Network [OSTI]

    A. Vanossi; A. Benassi; N. Varini; E. Tosatti

    2013-01-11T23:59:59.000Z

    The increase of sliding friction upon increasing load is a classic in the macroscopic world. Here we discuss the possibility that friction rise might sometimes turn into a drop when, at the mesoscale and nanoscale, a confined lubricant film separating crystalline sliders undergoes strong layering and solidification. Under pressure, transitions from N to N-1 layers may imply a change of lateral periodicity of the crystallized lubricant sufficient to alter the matching of crystal structures, influencing the ensuing friction jump. A pressure-induced friction drop may occur as the shear gradient maximum switches from the lubricant middle, marked by strong stick-slip with or without shear melting, to the crystalline slider-lubricant interface, characterized by smooth superlubric sliding. We present high pressure sliding simulations to display examples of frictional drops, suggesting their possible relevance to the local behavior in boundary lubrication.

  9. Ultra-high pressure water jet: Baseline report; Summary

    SciTech Connect (OSTI)

    NONE

    1997-07-31T23:59:59.000Z

    The Husky{trademark} is an ultra high pressure waterjet cutting tool system. The pump is mounted on a steel tube frame which includes slots for transport by a forklift. The Husky{trademark} features an automatic shutdown for several conditions such as low oil pressure and high oil temperature. Placement of the Husky{trademark} must allow for a three foot clearance on all sides for operation and service access. At maximum continuous operation, the output volume is 7.2 gallons per minute with an output pressure of 40,000 psi. A diesel engine provides power for the system. The safety and health evaluation during the human factors assessment focused on two main areas: noise and dust.

  10. High pressure generation by hot electrons driven ablation

    SciTech Connect (OSTI)

    Piriz, A. R. [E.T.S.I. Industriales, CYTEMA, and Instituto de Investigaciones Energticas, Universidad de Castilla-La Mancha, 13071 Ciudad Real (Spain)] [E.T.S.I. Industriales, CYTEMA, and Instituto de Investigaciones Energticas, Universidad de Castilla-La Mancha, 13071 Ciudad Real (Spain); Piriz, S. A. [Facultad de Ciencias Fsicas, Universidad Complutense de Madrid, 28040 Madrid (Spain)] [Facultad de Ciencias Fsicas, Universidad Complutense de Madrid, 28040 Madrid (Spain); Tahir, N. A. [GSI Helmholtzzentrum fr Schwerionenforschung, Planckstrasse 1, 64291 Darmstadt (Germany)] [GSI Helmholtzzentrum fr Schwerionenforschung, Planckstrasse 1, 64291 Darmstadt (Germany)

    2013-11-15T23:59:59.000Z

    A previous model [Piriz et al. Phys. Plasmas 19, 122705 (2012)] for the ablation driven by the hot electrons generated in collisionless laser-plasma interactions in the framework of shock ignition is revisited. The impact of recent results indicating that for a laser wavelength ? = 0.35 ?m the hot electron temperature ?{sub H} would be independent of the laser intensity I, on the resulting ablation pressure is considered. In comparison with the case when the scaling law ?{sub H}?(I?{sup 2}){sup 1/3} is assumed, the generation of the high pressures needed for driving the ignitor shock may be more demanding. Intensities above 10{sup 17} W/cm{sup 2} would be required for ?{sub H}=25?30 keV.

  11. High pressure, high current, low inductance, high reliability sealed terminals

    DOE Patents [OSTI]

    Hsu, John S. (Oak Ridge, TN) [Oak Ridge, TN; McKeever, John W. (Oak Ridge, TN) [Oak Ridge, TN

    2010-03-23T23:59:59.000Z

    The invention is a terminal assembly having a casing with at least one delivery tapered-cone conductor and at least one return tapered-cone conductor routed there-through. The delivery and return tapered-cone conductors are electrically isolated from each other and positioned in the annuluses of ordered concentric cones at an off-normal angle. The tapered cone conductor service can be AC phase conductors and DC link conductors. The center core has at least one service conduit of gate signal leads, diagnostic signal wires, and refrigerant tubing routed there-through. A seal material is in direct contact with the casing inner surface, the tapered-cone conductors, and the service conduits thereby hermetically filling the interstitial space in the casing interior core and center core. The assembly provides simultaneous high-current, high-pressure, low-inductance, and high-reliability service.

  12. High pressure behavior of otavite (CdCo3)

    SciTech Connect (OSTI)

    Minch, R.; Ehm, L.; Seoung, D.H.; Winkler, B.; Knorr, K.; Peters, L.; Borkowski, L.A.; Parise, J.B.; Lee, Y.; Dubrovinsky, L.; Depmeier, W.

    2010-08-24T23:59:59.000Z

    The high-pressure, room temperature behavior of otavite (CdCO{sub 3}) was investigated by angle-dispersive synchrotron radiation powder diffraction up to 40 GPa, Raman spectroscopy up to 23 GPa and quantum mechanical calculations based on density functional theory. The calcite-type structure of CdCO{sub 3} is stable up to at least {approx}19 GPa as shown by Raman spectroscopy. The compression mechanism was obtained from structure refinements against the diffraction data. The quantum mechanical calculations propose a calcite-aragonite phase transition to occur at about 30 GPa. The existence of a pressure-induced phase transition is supported by the Raman and diffraction experiments. Evidence for the transformation is given by broadening of X-ray reflections and external Raman bands starting from about 19 GPa in both experiments.

  13. Vacuum surface flashover and high pressure gas streamers

    SciTech Connect (OSTI)

    Elizondo, J.M.; Krogh, M.L.; Smith, D.; Stolz, D.; Wright, S.N. [Allied-Signal Aerospace Co., Kansas City, MO (United States). Kansas City Div.; Sampayan, S.E.; Caporaso, G.J.; Vitello, P.; Tishchenko, N. [Lawrence Livermore National Lab., CA (United States)

    1997-07-01T23:59:59.000Z

    Pre-breakdown current traces obtained during high pressure gas breakdown and vacuum surface flashover show similar signatures. The initial pre-breakdown current spike, a flat constant current phase, and the breakdown phase with voltage collapse and current surge differ mostly in magnitude. Given these similarities, a model, consisting of the initial current spike corresponding to a fast precursor streamer (ionization wave led by a photoionizing front), the flat current stage as the heating or glow phase, and the terminal avalanche and gap closure, is applied to vacuum surface flashover. A simple analytical approximation based on the resistivity changes induced in the vacuum and dielectric surface is presented. The approximation yields an excellent fit to pre-breakdown time delay vs applied field for previously published experimental data. A detailed kinetics model that includes surface and gas contributions is being developed based in the initial approximation.

  14. Modified approaches for high pressure filtration of fine clean coal

    SciTech Connect (OSTI)

    Yang, J.; Groppo, J.G.; Parekh, B.K. [Center for Applied Energy Research, Lexington, KY (United States)

    1995-12-31T23:59:59.000Z

    Removal of moisture from fine (minus 28 mesh) clean coal to 20% or lower level is difficult using the conventional vacuum dewatering technique. High pressure filtration technique provides an avenue for obtaining low moisture in fine clean coal. This paper describes a couple of novel approaches for dewatering of fine clean coal using pressure filtration which provides much lower moisture in fine clean coal than that obtained using conventional pressure filter. The approaches involve (a) split stream dewatering and (b) addition of paper pulp to the coal slurry. For Pittsburgh No. 8 coal slurry, split stream dewatering at 400 mesh provided filter cake containing 12.9% moisture compared to 24.9% obtained on the feed material. The addition of paper pulp to the slurry provided filter cake containing about 17% moisture.

  15. High-pressure coal fuel processor development. Final report

    SciTech Connect (OSTI)

    Greenhalgh, M.L. [Caterpillar, Inc., Peoria, IL (United States)

    1992-12-01T23:59:59.000Z

    Caterpillar shares DOE/METC interest in demonstrating the technology required to displace petroleum-based engine fuels with various forms of low cost coal. Current DOE/METC programs on mild gasification and coal-water-slurries are addressing two approaches to this end. Engine and fuel processor system concept studies by Caterpillar have identified a third, potentially promising, option. This option includes high-pressure fuel processing of run-of-the-mine coal and direct injection of the resulting low-Btu gas stream into an ignition assisted, high compression ratio diesel engine. The compactness and predicted efficiency of the system make it suitable for application to line-haul railroad locomotives. Two overall conclusions resulted from Task 1. First direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risk associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept. The significant conclusions from Task 2 were: An engine concept, derived from a Caterpillar 3600 series engine, and a fuel processor concept, based on scaling up a removable-canister configuration from the test rig, appear feasible; and although the results of this concept study are encouraging, further, full-scale component research and development are required before attempting a full-scale integrated system demonstration effort.

  16. Steam Production from Waste Stack Gases in a Carbon Black Plant

    E-Print Network [OSTI]

    Istre, R. I.

    1981-01-01T23:59:59.000Z

    gases to produce steam has two very important rewards - energy conservation and pollution abatement. Energy conservation is achieved by using waste gases in place of fuel oil to produce the steam required by the various plants. Pollution abatement is due...

  17. Electrical Cost Reduction Via Steam Turbine Cogeneration

    E-Print Network [OSTI]

    Ewing, T. S.; Di Tullio, L. B.

    1991-01-01T23:59:59.000Z

    years. The availability of this equipment in a packaged system form makes it feasible to replace pressure reducing valves with turbine generator sets in applications with flows as low as 4000 pounds of steam per hour. These systems produce electricity...

  18. Evaluating Steam Trap Performance

    E-Print Network [OSTI]

    Fuller, N. Y.

    EVALUATING STEAM TRAP PERFORMANCE Noel Y Fuller, P.E. Holston Defense Corporation Kingsport, Tennessee ABSTRACT Laboratory tests were conducted on several types of steam traps at Holston Defense Corporation in Kingsport, Tennessee. Data... that live steam loss is the heaviest contributor to the annual operating cost of any steam trap and that maintenance frequency and repair cost are also more important than a trap's first cost. INTRODUCTION Steam traps used on distribution line drip...

  19. Recovery of bitumen from oil sand by steam with chemicals

    SciTech Connect (OSTI)

    Yamazaki, T.

    1988-01-01T23:59:59.000Z

    Recently, oil sand bitumen has become the center of attention as a possible oil energy substitute for the future. Until now, the development of oil sand has been performed by surface miing and conventional steam injection, these methods are limited in respect to resource recovery. A more effective method needs to be developed utilizing in situ recovery. In this study, a new attempt is made for the purpose of enhancing the recovery of bitumen from oil sand by adopting the method of injecting high pressure steam and chemicals such as solvents, surfactants, and others.

  20. Bench-Scale Development of a Hot Carbonate Absorption Process with Crystallization-Enabled High Pressure Stripping for Post-Combustion CO{sub 2} Capture

    SciTech Connect (OSTI)

    Lu, Yongqi

    2014-02-01T23:59:59.000Z

    This report summarizes the methodology and preliminary results of a techno-economic analysis on a hot carbonate absorption process (Hot-CAP) with crystallization-enabled high pressure stripping for post-combustion CO{sub 2} capture (PCC). This analysis was based on the Hot-CAP that is fully integrated with a sub-critical steam cycle, pulverized coal-fired power plant adopted in Case 10 of the DOE/NETLs Cost and Performance Baseline for Fossil Energy Plants. The techno-economic analysis addressed several important aspects of the Hot-CAP for PCC application, including process design and simulation, equipment sizing, technical risk and mitigation strategy, performance evaluation, and cost analysis. Results show that the net power produced in the subcritical power plant equipped with Hot-CAP is 611 MWe, greater than that with Econoamine (550 MWe). The total capital cost for the Hot-CAP, including CO{sub 2} compression, is $399 million, less than that for the Econoamine PCC ($493 million). O&M costs for the power plant with Hot-CAP is $175 million annually, less than that with Econoamine ($178 million). The 20-year levelized cost of electricity (LCOE) for the power plant with Hot-CAP, including CO2 transportation and storage, is 119.4 mills/kWh, a 59% increase over that for the plant without CO2 capture. The LCOE increase caused by CO{sub 2} capture for the Hot-CAP is 31% lower than that for its Econoamine counterpart.

  1. Staged, High-Pressure Oxy-Combustion Technology: Development and Scale-Up

    SciTech Connect (OSTI)

    Axelbaum, Richard; Xia, Fei; Gopan, Akshay; Kumfer, Benjamin

    2014-09-30T23:59:59.000Z

    Washington University in St. Louis and its project partners are developing a unique pressurized oxy-combustion process that aims to improve efficiency and costs by reducing the recycling of flue gas to near zero. Normally, in the absence of recycled flue gas or another inert gas, combustion of fuel and oxygen results in a dramatic increase in temperature of the combustion products and radiant energy, as compared to combustion in air. High heat flux to the boiler tubes may result in a tube surface temperatures that exceed safe operating limits. In the Staged Pressurized Oxy-Combustion (SPOC) process, this problem is addressed by staging the delivery of fuel and by novel combustion design that allows control of heat flux. In addition, the main mode of heat transfer to the steam cycle is by radiation, as opposed to convection. Therefore, the requirement for recycling large amounts of flue gas, for temperature control or to improve convective heat transfer, is eliminated, resulting in a reduction in auxiliary loads. The following report contains a detailed summary of scientific findings and accomplishments for the period of Oct. 1, 2013 to Sept 30, 2014. Results of ASPEN process and CFD modelling activities aimed at improving the SPOC process and boiler design are presented. The effects of combustion pressure and fuel moisture on the plant efficiency are discussed. Combustor pressure is found to have only a minor impact beyond 16 bar. For fuels with moisture content greater than approx 30%, e.g. coal/water slurries, the amount of latent heat of condensation exceeds that which can be utilized in the steam cycle and plant efficiency is reduced significantly. An improved boiler design is presented that achieves a more uniform heat flux profile. In addition, a fundamental study of radiation in high-temperature, high-pressure, particle-laden flows is summarized which provides a more complete understanding of heat transfer in these unusual conditions and to allow for optimization. The results reveal that for the SPOC design, absorption and emission due to particles is the dominant factor for determining the wall heat flux. The mechanism of radiative trapping of energy within the high-temperature flame region and the approach to utilizing this mechanism to control wall heat flux are described. This control arises, by design, from the highly non-uniform (non-premixed) combustion characteristics within the SPOC boiler, and the resulting gradients in temperature and particle concentration. Finally, a simple method for estimating the wall heat flux in pressurized combustion systems is presented.

  2. Steam Oxidation of Advanced Steam Turbine Alloys

    SciTech Connect (OSTI)

    Holcomb, Gordon R.

    2008-01-01T23:59:59.000Z

    Power generation from coal using ultra supercritical steam results in improved fuel efficiency and decreased greenhouse gas emissions. Results of ongoing research into the oxidation of candidate nickel-base alloys for ultra supercritical steam turbines are presented. Exposure conditions range from moist air at atmospheric pressure (650C to 800C) to steam at 34.5 MPa (650C to 760C). Parabolic scale growth coupled with internal oxidation and reactive evaporation of chromia are the primary corrosion mechanisms.

  3. Steam atmosphere drying exhaust steam recompression system

    DOE Patents [OSTI]

    Becker, F.E.; Smolensky, L.A.; Doyle, E.F.; DiBella, F.A.

    1994-03-08T23:59:59.000Z

    This invention relates to a heated steam atmosphere drying system comprising dryer in combination with an exhaust recompression system which is extremely energy efficient and eliminates dangers known to air dryers. The system uses superheated steam as the drying medium, which recirculates through the system where its heat of evaporation and heat of compression is recovered, thereby providing a constant source of heat to the drying chamber. The dryer has inlets whereby feedstock and superheated steam are fed therein. High heat transfer and drying rates are achieved by intimate contact of the superheated steam with the particles being dried. The dryer comprises a vessel which enables the feedstock and steam to enter and recirculate together. When the feedstock becomes dry it will exit the dryer with the steam and become separated from the steam through the use of a curvilinear louver separator (CLS). The CLS enables removal of fine and ultrafine particles from the dryer. Water vapor separated from the particles in the CLS as superheated steam, may then be recovered and recirculated as steam through the use of a compressor to either directly or indirectly heat the dryer, and a heat exchanger or a heater to directly provide heat to the dryer. This system not only provides a very efficient heat transfer system but results in a minimum carry-over of ultrafine particles thereby eliminating any explosive hazard. 17 figures.

  4. Steam atmosphere drying exhaust steam recompression system

    DOE Patents [OSTI]

    Becker, Frederick E. (Reading, MA); Smolensky, Leo A. (Concord, MA); Doyle, Edward F. (Dedham, MA); DiBella, Francis A. (Roslindale, MA)

    1994-01-01T23:59:59.000Z

    This invention relates to a heated steam atmosphere drying system comprising dryer in combination with an exhaust recompression system which is extremely energy efficient and eliminates dangers known to air dryers. The system uses superheated steam as the drying medium, which recirculated through the system where its heat of evaporation and heat of compression is recovered, thereby providing a constant source of heat to the drying chamber. The dryer has inlets whereby feedstock and superheated steam are fed therein. High heat transfer and drying rates are achieved by intimate contact of the superheated steam with the particles being dried The dryer comprises a vessel which enables the feedstock and steam to enter recirculate together. When the feedstock becomes dry it will exit the dryer with the steam and become separated from the steam through the use of a curvilinear louver separator (CLS). The CLS enables removal of fine and ultrafine particles from the dryer. Water vapor separated from the particles in the CLS as superheated steam, may then be recovered and recirculated as steam through the use of a compressor to either directly or indirectly heat the dryer, and a heat exchanger or a heater to directly provide heat to the dryer. This system not only provides a very efficient heat transfer system but results in a minimum carry-over of ultrafine particles thereby eliminating any explosive hazard.

  5. Dislocations and Plasticity in bcc Transition Metals at High Pressure

    SciTech Connect (OSTI)

    Yang, L H; Tang, M; Moriarty, J A

    2009-01-23T23:59:59.000Z

    Using first-principles electronic structure calculations, quantum-based atomistic simulations and atomistically informed dislocation dynamics (DD) simulations, we have studied individual dislocation behavior and the multiscale modeling of single-crystal plasticity in the prototype bcc transition metals Ta, Mo and V under both ambient and high pressure conditions. The primary focus in this work is on the pressure-dependent structure, mobility and interaction of a/2<111> screw dislocations, which dominate the plastic deformation properties of these materials. At the electronic scale, first-principles calculations of elasticity, ideal strength and generalized stacking fault energy surfaces have been used to validate quantum-based multi-ion interatomic potentials. At the atomistic scale, these potentials have been used in flexible Green's function boundary condition simulations to study the core structure, Peierls stress {tau}{sub P}, thermally activated kink-pair formation and mobility below {tau}{sub P}, and phonon-drag mobility above {tau}{sub P}. These results have then been distilled into analytic velocity laws and used directly in predictive microscale DD simulations of flow stress and resolved yield stress over wide ranges of pressure, temperature and strain rate.

  6. Pulsed laser kinetic studies of liquids under high pressure

    SciTech Connect (OSTI)

    Eyring, E.M.

    1993-06-21T23:59:59.000Z

    Experiments have been developed for measuring the rates of chemical reactions liquids and in supercritical Co[sub 2]. A pulsed (Q-switch) Nd:YAG laser at 355 nm was the pump beam for laser flash photolysis studies of molybdenum and tungsten hexacarbonyls undergoing ligand displacement reactions by bidentate chelating agents such as 2,2[prime]-bipyridine in toluene. Experiments were carried out at 0.1 to 150 MPa. In the case of molybdenum complexes, the reaction mechanism for thermal ring closure is found from activation volumes to change from associative interchange to dissociative interchange as substituents on the 2,2[prime]-bipyridine ligands become bulkier. In a similar study of more rigid, substituted phenanthroline bidentate ligands it was found that substituent bulkiness had little effect on the thermal ring closure mechanism. Similar high pressure flash photolysis experiments with tungsten hexacarbonyl have also been completed. The concentration dependence of the fluorescence and nonradiative decay quantum yields for cresyl violet in several solvent have been reported as well as stability constants for the complexation of lithium ion by four different crown ethers dissolved in a room temperature molten salt.

  7. TENSILE TESTING OF CARBON STEEL IN HIGH PRESSURE HYDROGEN

    SciTech Connect (OSTI)

    Duncan, A; Thad Adams, T; Ps Lam, P

    2007-05-02T23:59:59.000Z

    An infrastructure of new and existing pipelines and systems will be required to carry and to deliver hydrogen as an alternative energy source under the hydrogen economy. Carbon and low alloy steels of moderate strength are currently used in hydrogen delivery systems as well as in the existing natural gas systems. It is critical to understand the material response of these standard pipeline materials when they are subjected to pressurized hydrogen environments. The methods and results from a testing program to quantify hydrogen effects on mechanical properties of carbon steel pipeline and pipeline weld materials are provided. Tensile properties of one type of steel (A106 Grade B) in base metal, welded and heat affected zone conditions were tested at room temperature in air and high pressure (10.34 MPa or 1500 psig) hydrogen. A general reduction in the materials ability to plastically deform was noted in this material when specimens were tested in hydrogen. Furthermore, the primary mode of fracture was changed from ductile rupture in air to cleavage with secondary tearing in hydrogen. The mechanical test results will be applied in future analyses to evaluate service life of the pipelines. The results are also envisioned to be part of the bases for construction codes and structural integrity demonstrations for hydrogen service pipeline and vessels.

  8. Chemical tailoring of steam to remediate underground mixed waste contaminents

    DOE Patents [OSTI]

    Aines, Roger D. (Livermore, CA); Udell, Kent S. (Berkeley, CA); Bruton, Carol J. (Livermore, CA); Carrigan, Charles R. (Tracy, CA)

    1999-01-01T23:59:59.000Z

    A method to simultaneously remediate mixed-waste underground contamination, such as organic liquids, metals, and radionuclides involves chemical tailoring of steam for underground injection. Gases or chemicals are injected into a high pressure steam flow being injected via one or more injection wells to contaminated soil located beyond a depth where excavation is possible. The injection of the steam with gases or chemicals mobilizes contaminants, such as metals and organics, as the steam pushes the waste through the ground toward an extraction well having subatmospheric pressure (vacuum). The steam and mobilized contaminants are drawn in a substantially horizontal direction to the extraction well and withdrawn to a treatment point above ground. The heat and boiling action of the front of the steam flow enhance the mobilizing effects of the chemical or gas additives. The method may also be utilized for immobilization of metals by using an additive in the steam which causes precipitation of the metals into clusters large enough to limit their future migration, while removing any organic contaminants.

  9. Steam vacuum cleaning. Innovative technology summary report

    SciTech Connect (OSTI)

    NONE

    1999-05-01T23:59:59.000Z

    The US Department of Energy (DOE) continually seeks safer and more cost-effective remediation technologies for use in the decontamination and decommissioning (D and D) of nuclear facilities. The baseline technology currently used for washing debris is a high-pressure water cleaning (HPWC) system. The system used at the FEMP is the Hotsy{reg_sign} Model 550B HPWC. Although the HPWC technology has functioned satisfactorily, improvements are being sought in areas related to reduced liquid waste volume, increased productivity, increased washing effectiveness, and decreased airborne contamination. An innovative technology that offers potential improvements in these areas is a steam vacuum cleaning (SVC) system that integrates high-pressure steam cleaning with a vacuum recovery sub-system that simultaneously collects dislodged contaminants thereby reducing airborne contamination. The SVC system selected for demonstration at the FEMP was the Kelly{trademark} Decontamination System shown. This report provides comparative performance and cost analyses between the Hotsy HPWC system and the Kelly Decontamination System. Both technologies were demonstrated at the FEMP site located at Fernald, Ohio from July 29, 1996 through August 15, 1996. The demonstrations were conducted at the FEMP Plant 1 as part of the LSTD project sponsored by the Deactivation and Decommissioning Focus Area (DDFA) of the US DOE`s Office of Science and Technology.

  10. Flash Steam Recovery Project

    E-Print Network [OSTI]

    Bronhold, C. J.

    2000-01-01T23:59:59.000Z

    /condensate recovery system, resulting in condensate flash steam losses to the atmosphere. Using computer simulation models and pinch analysis techniques, the Operational Excellence Group (Six Sigma) was able to identify a project to recover the flash steam losses as a...

  11. Downhole steam quality measurement

    DOE Patents [OSTI]

    Lee, D.O.; Montoya, P.C.; Muir, J.F.; Wayland, J.R. Jr.

    1985-06-19T23:59:59.000Z

    The present invention relates to an empirical electrical method for remote sensing of steam quality utilizing flow-through grids which allow measurement of the electrical properties of a flowing two-phase mixture. The measurement of steam quality in the oil field is important to the efficient application of steam assisted recovery of oil. Because of the increased energy content in higher quality steam it is important to maintain the highest possible steam quality at the injection sandface. The effectiveness of a steaming operation without a measure of steam quality downhole close to the point of injection would be difficult to determine. Therefore, a need exists for the remote sensing of steam quality.

  12. Steam Digest 2001

    SciTech Connect (OSTI)

    Not Available

    2002-01-01T23:59:59.000Z

    Steam Digest 2001 chronicles BestPractices Program's contributions to the industrial trade press for 2001, and presents articles that cover technical, financial and managerial aspects of steam optimization.

  13. Downhole steam quality measurement

    DOE Patents [OSTI]

    Lee, David O. (Albuquerque, NM); Montoya, Paul C. (Albuquerque, NM); Muir, James F. (Albuquerque, NM); Wayland, Jr., J. Robert (Albuquerque, NM)

    1987-01-01T23:59:59.000Z

    An empirical method for the remote sensing of steam quality that can be easily adapted to downhole steam quality measurements by measuring the electrical properties of two-phase flow across electrode grids at low frequencies.

  14. Moessbauer studies of iron hydride at high pressure

    SciTech Connect (OSTI)

    Choe, I.; Ingalls, R. (Department of Physics, FM-15, University of Washington, Seattle, Washington 98195 (USA)); Brown, J.M.; Sato-Sorensen, Y. (Geophysics Program, AK-50, University of Washington, Seattle, Washington 98195 (USA)); Mills, R. (Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (USA))

    1991-07-01T23:59:59.000Z

    We have measured {ital in} {ital situ} Moessbauer spectra of iron hydride made in a diamond anvil cell at high pressure and room temperature. The spectra show a sudden change at 3.5{plus minus}0.5 GPa from a single hyperfine pattern to a superposition of three. The former pattern results from normal {alpha}-iron with negligible hydrogen content, and the latter from residual {alpha}-iron plus newly formed iron hydride. Between 3.5 and 10.4 GPa, the extra hydride pattern have hyperfine fields for one ranging from 276 to 263 kOe, and the other, from 317 to 309 kOe. Both have isomer shifts of about 0.4 mm/sec, and negligible quadrupole splittings. X-ray studies on quenched samples have shown that iron hydride is of double hexagonal close-packed structure, whose two nonequivalent iron sites may account for the observation of two different patterns. Even allowing for the effect of volume expansion, the observed isomer shifts for the hydride are considerably more positive than those of other metallic phases of iron. At the same time, the hyperfine fields are slightly smaller than that of {alpha}-iron. As a possible explanation, one may expect a bonding of hydrogen with iron, which would result in a small reduction of 4{ital s} electrons, possibly accompanied by a small increase of 3{ital d} electrons compared with the neutral atom in metallic iron. The difference between the hyperfine fields in the two spectra are presumably due to the different symmetry at the two iron sites.

  15. SteamMaster: Steam System Analysis Software

    E-Print Network [OSTI]

    Wheeler, G.

    tool to facilitate the process. SteamMaster is based on an Excel spreadsheet with a Visual Basic interface to simplify system modeling and analysis. SteamMaster has many features and capabilities, including energy and cost savings calculations for five...

  16. Steam Trap Management

    E-Print Network [OSTI]

    Murphy, J. J.; Hirtner, H. H.

    problemA of water hammer and high back pressure. ? Exorbitantly hi~h percentage of cold trapA. ? External steam leaks within the steam trap stations, bypasA valves and/or strainer blowdown valvefl open, blowin~ steam. ! I ? Dirt nssociated... Trapping 2 Trap Installed Backwards 1 Misapplication of Technology 1 Strainer Blowdown Connections Capped 285 (*b) Test Tee Connections Capped 11 Trap Inlet Connected to Steam Line Strainer Blowdown Connection 3 Water Logged Coils (Vacuum Present) 7...

  17. Exergy Analysis of the Steam Network in Tehran Oil Refinery and Evaluation with New Scenario

    E-Print Network [OSTI]

    Khodaei, H.; Taheri, R.; Arghandeh, R.

    oil refinery, Exergy Analysis, Steam Network, Retrofit, Optimization 1. INTRODUCTION Refinery steam network is considered as a unit that consumes energy greatly. The main objective of the network is to produce the steam, which is required...) Using heat recovery steam generating systems and gas turbines instead of old boilers and so on. Figure 1 shows the opportunities of optimization in steam networks. in this paper, we complete the lost works such as optimization and estimation...

  18. anomalous high-pressure behavior: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    than recently predicted. McMahon, Jeffrey M 2011-01-01 105 Selection of High Strength Encapsulant for MEMS Devices Undergoing High Pressure Packaging CERN Preprints Summary:...

  19. Improved Steam Assisted Gravity Drainage (SAGD) Performance with Solvent as Steam Additive

    E-Print Network [OSTI]

    Li, Weiqiang

    2011-02-22T23:59:59.000Z

    Steam Assisted Gravity Drainage (SAGD) is used widely as a thermal recovery technique in Canada to produce a very viscous bitumen formation. The main research objectives of this simulation and experimental study are to investigate oil recovery...

  20. Electrical Cost Reduction Via Steam Turbine Cogeneration

    E-Print Network [OSTI]

    Ewing, T. S.; Di Tullio, L. B.

    ELECTRICAL COST REDUCTION VIA STEAM TURBINE COGENERATION LYNN B. DI TULLIO, P.E. Project Engineer Ewing Power Systems, Inc. South Deerfield, Mass. ABSTRACT Steam turbine cogeneration is a well established technology which is widely used... to replace pressure reducing valves with turbine generator sets in applications with flows as low as 4000 pounds of steam per hour. These systems produce electricity for $0.01 to $.02 per kWh (based on current costs of gas and oil); system cost is between...

  1. Designing an ultrasupercritical steam turbine

    SciTech Connect (OSTI)

    Klotz, H.; Davis, K.; Pickering, E. [Alstom (Germany)

    2009-07-15T23:59:59.000Z

    Carbon emissions produced by the combustion of coal may be collected and stored in the future, but a better approach is to reduce the carbon produced through efficient combustion technologies. Increasing the efficiency of new plants using ultrasupercritical (USC) technology will net less carbon released per megawatt-hour using the world's abundant coal reserves while producing electricity at the lowest possible cost. The article shows how increasing the steam turbine operating conditions for a new USC project in the USA and quantify the potential CO{sub 2} reduction this advanced design makes possible. 7 figs., 3 tabs.

  2. Downhole steam generator having a downhole oxidant compressor

    DOE Patents [OSTI]

    Fox, Ronald L. (Albuquerque, NM)

    1983-01-01T23:59:59.000Z

    Apparatus and method for generation of steam in a borehole for penetration into an earth formation wherein a downhole oxidant compressor is used to compress relatively low pressure (atmospheric) oxidant, such as air, to a relatively high pressure prior to mixing with fuel for combustion. The multi-stage compressor receives motive power through a shaft driven by a gas turbine powered by the hot expanding combustion gases. The main flow of compressed oxidant passes through a velocity increasing nozzle formed by a reduced central section of the compressor housing. An oxidant bypass feedpipe leading to peripheral oxidant injection nozzles of the combustion chamber are also provided. The downhole compressor allows effective steam generation in deep wells without need for high pressure surface compressors. Feedback preheater means are provided for preheating fuel in a preheat chamber. Preheating of the water occurs in both a water feed line running from aboveground and in a countercurrent water flow channel surrounding the combustor assembly. The countercurrent water flow channels advantageously serve to cool the combustion chamber wall. The water is injected through slotted inlets along the combustion chamber wall to provide an unstable boundary layer and stripping of the water from the wall for efficient steam generation. Pressure responsive doors are provided at the steam outlet for closing and sealing the combustion chamber from entry of reservoir fluids in the event of a flameout.

  3. High Pressure Burn Rate Measurements on an Ammonium Perchlorate Propellant

    SciTech Connect (OSTI)

    Glascoe, E A; Tan, N

    2010-04-21T23:59:59.000Z

    High pressure deflagration rate measurements of a unique ammonium perchlorate (AP) based propellant are required to design the base burn motor for a Raytheon weapon system. The results of these deflagration rate measurements will be key in assessing safety and performance of the system. In particular, the system may experience transient pressures on the order of 100's of MPa (10's kPSI). Previous studies on similar AP based materials demonstrate that low pressure (e.g. P < 10 MPa or 1500 PSI) burn rates can be quite different than the elevated pressure deflagration rate measurements (see References and HPP results discussed herein), hence elevated pressure measurements are necessary in order understand the deflagration behavior under relevant conditions. Previous work on explosives have shown that at 100's of MPa some explosives will transition from a laminar burn mechanism to a convective burn mechanism in a process termed deconsolidative burning. The resulting burn rates that are orders-of-magnitude faster than the laminar burn rates. Materials that transition to the deconsolidative-convective burn mechanism at elevated pressures have been shown to be considerably more violent in confined heating experiments (i.e. cook-off scenarios). The mechanisms of propellant and explosive deflagration are extremely complex and include both chemical, and mechanical processes, hence predicting the behavior and rate of a novel material or formulation is difficult if not impossible. In this work, the AP/HTPB based material, TAL-1503 (B-2049), was burned in a constant volume apparatus in argon up to 300 MPa (ca. 44 kPSI). The burn rate and pressure were measured in-situ and used to calculate a pressure dependent burn rate. In general, the material appears to burn in a laminar fashion at these elevated pressures. The experiment was reproduced multiple times and the burn rate law using the best data is B = (0.6 {+-} 0.1) x P{sup (1.05{+-}0.02)} where B is the burn rate in mm/s and P is the pressure in units of MPa. Details of the experimental method, results and data analysis are discussed herein and briefly compared to other AP based materials that have been measured in this apparatus.

  4. Materials for High-Pressure Fuel Injection Systems

    SciTech Connect (OSTI)

    Blau, P.; Shyam, A.; Hubbard, C.; Howe, J.; Trejo, R.; Yang, N. (Caterpillar, Inc. Technical Center) [Caterpillar, Inc. Technical Center; Pollard, M. (Caterpillar, Inc. Technical Center) [Caterpillar, Inc. Technical Center

    2011-09-30T23:59:59.000Z

    The high-level goal of this multi-year effort was to facilitate the Advanced Combustion Engine goal of 20% improvement (compared to 2009 baseline) of commercial engine efficiency by 2015. A sub-goal is to increase the reliability of diesel fuel injectors by investigating modelbased scenarios that cannot be achieved by empirical, trial and error methodologies alone. During this three-year project, ORNL developed the methodology to evaluate origins and to record the initiation and propagation of fatigue cracks emanating from holes that were electrodischarge machined (EDM), the method used to form spray holes in fuel injector tips. Both x-ray and neutron-based methods for measuring residual stress at four different research facilities were evaluated to determine which, if any, was most applicable to the fuel injector tip geometry. Owing to the shape and small volumes of material involved in the sack area, residual stress data could only be obtained in the walls of the nozzle a few millimeters back from the tip, and there was a hint of only a small compressive stress. This result was consistent with prior studies by Caterpillar. Residual stress studies were suspended after the second year, reserving the possibility of pursuing this in the future, if and when methodology suitable for injector sacks becomes available. The smooth specimen fatigue behavior of current fuel injector steel materials was evaluated and displayed a dual mode initiation behavior. At high stresses, cracks started at machining flaws in the surface; however, below a critical threshold stress of approximately 800 MPa, cracks initiated in the bulk microstructure, below the surface. This suggests that for the next generation for high-pressure fuel injector nozzles, it becomes increasingly important to control the machining and finishing processes, especially if the stress in the tip approaches or exceeds that threshold level. Fatigue tests were also conducted using EDM notches in the gage sections. Compared to the smooth specimens, EDM notching led to a severe reduction in total fatigue life. A reduction in fatigue life of nearly four orders of magnitude can occur at an EDM notch the approximate size of fuel injector spray holes. Consequently, the initiation and propagation behavior of cracks from small spray holes is relevant for generation of design quality data for the next generation diesel fuel injection devices. This is especially true since the current design methodologies usually rely on the less conservative smooth specimen fatigue testing results, and since different materials can have varying levels of notch fatigue resistance.

  5. Steam System Optimization

    E-Print Network [OSTI]

    Aegerter, R. A.

    1998-01-01T23:59:59.000Z

    been developed, it is an excellent tool to identify the steam sources. Areas to first look for possible waste are steam turbines and steam let down stations. 161 ESL-IE-98-04-26 Proceedings from the Twentieth National Industrial Energy Technology... Conference, Houston, TX, April 22-23, 1998 The easiest solution to eliminating excess steam is to shut down steam turbines that exhaust into the header and start up the motor driven spare equipment. Often times this step will be enough to eliminate...

  6. Steam trap monitor

    DOE Patents [OSTI]

    Ryan, M.J.

    1987-05-04T23:59:59.000Z

    A steam trap monitor positioned downstream of a steam trap in a closed steam system includes a first sensor (a hot finger) for measuring the energy of condensate and a second sensor (a cold finger) for measuring the total energy of condensate and steam in the line. The hot finger includes one or more thermocouples for detecting condensate level and energy, while the cold finger contains a liquid with a lower boiling temperature than that of water. Vapor pressure from the liquid is used to do work such as displacing a piston or bellow in providing an indication of total energy (steam + condensate) of the system. Processing means coupled to and responsive to outputs from the hot and cold fingers subtracts the former from the latter to provide an indication of the presence of steam downstream from the trap indicating that the steam trap is malfunctioning. 2 figs.

  7. Materials Performance in USC Steam

    SciTech Connect (OSTI)

    G. R. Holcomb, P. Wang, P. D. Jablonski, and J. A. Hawk

    2010-05-01T23:59:59.000Z

    The proposed steam inlet temperature in the Advanced Ultra Supercritical (A-USC) steam turbine is high enough (760 C) that traditional turbine casing and valve body materials such as ferritic/martensitic steels will not suffice due to temperature limitations of this class of materials. Cast versions of several traditionally wrought Ni-based superalloys were evaluated for use as casing or valve components for the next generation of industrial steam turbines. The full size castings are substantial: 2-5,000 kg each half and on the order of 100 cm thick. Experimental castings were quite a bit smaller, but section size was retained and cooling rate controlled to produce equivalent microstructures. A multi-step homogenization heat treatment was developed to better deploy the alloy constituents. The most successful of these cast alloys in terms of creep strength (Haynes 263, Haynes 282, and Nimonic 105) were subsequently evaluated by characterizing their microstructure as well as their steam oxidation resistance (at 760 and 800 C).

  8. High pressure apparatus for transport properties study in high magnetic field

    SciTech Connect (OSTI)

    Alsmadi, A. M. (Abdel M.); Nakotte, H. (Heinrich); Honda, F.; Sechovsky, V. (Vladimir); Mikulina, O. (Olga); Kamarad, J.; Lacerda, A. H. (Alex H.)

    2002-01-01T23:59:59.000Z

    We have designed a high pressure apparatus for measuring electrical-transport properties at low temperatures, high magnetic field and hydrostatic pressure up to 10 kbar. Details of the high-pressure cell and an exemplary study on UNiAI are described and discussed briefly.

  9. Phase stability of carbon clathrates at high pressure Jian-Tao Wang,1,a

    E-Print Network [OSTI]

    Wang, Wei Hua

    Phase stability of carbon clathrates at high pressure Jian-Tao Wang,1,a Changfeng Chen,2 Ding, Institute of Physics, Chinese Academy of Sciences, Beijing 100080, China 2 Department of Physics and Hi an ab initio study on the structural stability of carbon clathrates at high pressure and identify fcc

  10. Engine with hydraulic fuel injection and ABS circuit using a single high pressure pump

    DOE Patents [OSTI]

    Bartley, Bradley E. (Manito, IL); Blass, James R. (Bloomington, IL); Gibson, Dennis H. (Chillicothe, IL)

    2001-01-01T23:59:59.000Z

    An engine system comprises a hydraulically actuated fuel injection system and an ABS circuit connected via a fluid flow passage that provides hydraulic fluid to both the fuel injection system and to the ABS circuit. The hydraulically actuated system includes a high pressure pump. The fluid control passage is in fluid communication with an outlet from the high pressure pump.

  11. Diamond anvil cell for spectroscopic investigation of materials at high temperature, high pressure and shear

    DOE Patents [OSTI]

    Westerfield, C.L.; Morris, J.S.; Agnew, S.F.

    1997-01-14T23:59:59.000Z

    Diamond anvil cell is described for spectroscopic investigation of materials at high temperature, high pressure and shear. A cell is described which, in combination with Fourier transform IR spectroscopy, permits the spectroscopic investigation of boundary layers under conditions of high temperature, high pressure and shear. 4 figs.

  12. Diamond anvil cell for spectroscopic investigation of materials at high temperature, high pressure and shear

    DOE Patents [OSTI]

    Westerfield, Curtis L. (Espanola, NM); Morris, John S. (Los Alamos, NM); Agnew, Stephen F. (Los Alamos, NM)

    1997-01-01T23:59:59.000Z

    Diamond anvil cell for spectroscopic investigation of materials at high temperature, high pressure and shear. A cell is described which, in combination with Fourier transform IR spectroscopy, permits the spectroscopic investigation of boundary layers under conditions of high temperature, high pressure and shear.

  13. Generating Electricity with your Steam System: Keys to Long Term Savings

    E-Print Network [OSTI]

    Bullock, B.; Downing, A.

    2010-01-01T23:59:59.000Z

    The application of combined heat and power principals to existing plant steam systems can help produce electricity at more than twice efficiency of grid generated electricity. In this way, steam plant managers can realize substantial savings...

  14. Superalloys for ultra supercritical steam turbines--oxidation behavior

    SciTech Connect (OSTI)

    Holcomb, G.R.

    2008-09-01T23:59:59.000Z

    Goals of the U.S. Department of Energys Advanced Power Systems Initiatives include power generation from coal at 60% efficiency, which requires steam conditions of up to 760 C and 340 atm, so called ultra-supercritical (USC) steam conditions. One of the important materials performance considerations is steam-side oxidation resistance. Evaporation of protective chromia scales is expected to be a primary corrosion mechanism under USC conditions. A methodology to calculate Cr evaporation rates from chromia scales with cylindrical geometries was developed that allows for the effects of CrO2(OH)2 saturation within the gas phase. This approach was combined with Cr diffusion calculations within the alloy (with a constant flux of Cr leaving the alloy from evaporation) to predict Cr concentration profiles as a function of exposure time and to predict the time until the alloy surface concentration of Cr reaches zero. This time is a rough prediction of the time until breakaway oxidation. A hypothetical superheater tube, steam pipe, and high pressure turbine steam path was examined. At the highest temperatures and pressures, the time until breakaway oxidation was predicted to be quite short for the turbine blade, and of concern within the steam pipe and the higher temperature portions of the superheater tube. The predicted time until breakaway oxidation increases dramatically with decreases in temperature and total pressure. Possible mitigation techniques were discussed, including those used in solid oxide fuel cell metallic interconnects (lowering the activity of Cr in the oxide scale by adding Mn to the alloy), and thermal barrier coating use on high pressure turbine blades for both erosion and chromia evaporation protection.

  15. An in situ tensile test apparatus for polymers in high pressure hydrogen

    SciTech Connect (OSTI)

    Alvine, K. J., E-mail: kyle.alvine@pnnl.gov; Kafentzis, T. A.; Pitman, S. G.; Johnson, K. I.; Skorski, D.; Tucker, J. C.; Roosendaal, T. J.; Dahl, M. E. [Energy and Environment Directorate, Pacific Northwest National Laboratory, Richland, Washington 99354 (United States)

    2014-10-15T23:59:59.000Z

    Degradation of material properties by high-pressure hydrogen is an important factor in determining the safety and reliability of materials used in high-pressure hydrogen storage and delivery. Hydrogen damage mechanisms have a time dependence that is linked to hydrogen outgassing after exposure to the hydrogen atmosphere that makes ex situ measurements of mechanical properties problematic. Designing in situ measurement instruments for high-pressure hydrogen is challenging due to known hydrogen incompatibility with many metals and standard high-power motor materials such as Nd. Here we detail the design and operation of a solenoid based in situ tensile tester under high-pressure hydrogen environments up to 42 MPa (6000 psi). Modulus data from high-density polyethylene samples tested under high-pressure hydrogen at 35 MPa (5000 psi) are also reported as compared to baseline measurements taken in air.

  16. An In-situ Tensile Test Apparatus for Polymers in High Pressure Hydrogen

    SciTech Connect (OSTI)

    Alvine, Kyle J.; Kafentzis, Tyler A.; Pitman, Stan G.; Johnson, Kenneth I.; Skorski, Daniel C.; Tucker, Joseph C.; Roosendaal, Timothy J.; Dahl, Michael E.

    2014-10-10T23:59:59.000Z

    Degradation of material properties by high-pressure hydrogen is an important factor in determining the safety and reliability of materials used in high-pressure hydrogen storage and delivery. Hydrogen damage mechanisms have a time dependence that is linked to hydrogen outgassing after exposure to the hydrogen atmosphere that makes ex-situ measurements of mechanical properties problematic. Designing in-situ measurement instruments for high-pressure hydrogen is challenging due to known hydrogen incompatibility with many metals and standard high-power motor materials like Nd. Here we detail the design and operation of a solenoid based in-situ tensile tester under high-pressure hydrogen environments up to 5,000 psi. Modulus data from high-density polyethylene (HDPE) samples tested under high-pressure hydrogen are also reported as compared to baseline measurements taken in air.

  17. An improved measurement of electron-ion recombination in high-pressure xenon gas

    E-Print Network [OSTI]

    NEXT Collaboration; L. Serra; M. Sorel; V. lvarez; F. I. G. Borges; M. Camargo; S. Crcel; S. Cebrin; A. Cervera; C. A. N. Conde; T. Dafni; J. Daz; R. Esteve; L. M. P. Fernandes; P. Ferrario; A. L. Ferreira; E. D. C. Freitas; V. M. Gehman; A. Goldschmidt; J. J. Gmez-Cadenas; D. Gonzlez-Daz; R. M. Gutirrez; J. Hauptman; J. A. Hernando Morata; D. C. Herrera; I. G. Irastorza; L. Labarga; A. Laing; I. Liubarsky; N. Lopez-March; D. Lorca; M. Losada; G. Luzn; A. Mar; J. Martn-Albo; G. Martnez-Lema; A. Martnez; T. Miller; F. Monrabal; M. Monserrate; C. M. B. Monteiro; F. J. Mora; L. M. Moutinho; J. Muoz Vidal; M. Nebot-Guinot; D. Nygren; C. A. B. Oliveira; J. Prez; J. L. Prez Aparicio; M. Querol; J. Renner; L. Ripoll; A. Rodrguez; J. Rodrguez; F. P. Santos; J. M. F. dos Santos; D. Shuman; A. Simn; C. Sofka; J. F. Toledo; J. Torrent; Z. Tsamalaidze; J. F. C. A. Veloso; J. A. Villar; R. Webb; J. T. White; N. Yahlali

    2015-02-03T23:59:59.000Z

    We report on results obtained with the NEXT-DEMO prototype of the NEXT-100 high-pressure xenon gas time projection chamber (TPC), exposed to an alpha decay calibration source. Compared to our previous measurements with alpha particles, an upgraded detector and improved analysis techniques have been used. We measure event-by-event correlated fluctuations between ionization and scintillation due to electron-ion recombination in the gas, with correlation coeffcients between -0.80 and -0.56 depending on the drift field conditions. By combining the two signals, we obtain a 2.8 % FWHM energy resolution for 5.49 MeV alpha particles and a measurement of the optical gain of the electroluminescent TPC. The improved energy resolution also allows us to measure the specific activity of the radon in the gas due to natural impurities. Finally, we measure the average ratio of excited to ionized atoms produced in the xenon gas by alpha particles to be $0.561\\pm 0.045$, translating into an average energy to produce a primary scintillation photon of $W_{\\rm ex}=(39.2\\pm 3.2)$ eV.

  18. Steam Champions in Manufacturing

    E-Print Network [OSTI]

    Russell, C.

    2001-01-01T23:59:59.000Z

    Steanl Flow ? Analyze pressure reduction options: none, use boiler controls or PRVs, Through PRVs use backpressure turbines Recover & Utilize ? Maximize volume of condensate recovered and utilized Available Condensate Use High Pressure ? Maximize...

  19. Steam generator support system

    DOE Patents [OSTI]

    Moldenhauer, J.E.

    1987-08-25T23:59:59.000Z

    A support system for connection to an outer surface of a J-shaped steam generator for use with a nuclear reactor or other liquid metal cooled power source is disclosed. The J-shaped steam generator is mounted with the bent portion at the bottom. An arrangement of elongated rod members provides both horizontal and vertical support for the steam generator. The rod members are interconnected to the steam generator assembly and a support structure in a manner which provides for thermal distortion of the steam generator without the transfer of bending moments to the support structure and in a like manner substantially minimizes forces being transferred between the support structure and the steam generator as a result of seismic disturbances. 4 figs.

  20. Steam generator support system

    DOE Patents [OSTI]

    Moldenhauer, James E. (Simi Valley, CA)

    1987-01-01T23:59:59.000Z

    A support system for connection to an outer surface of a J-shaped steam generator for use with a nuclear reactor or other liquid metal cooled power source. The J-shaped steam generator is mounted with the bent portion at the bottom. An arrangement of elongated rod members provides both horizontal and vertical support for the steam generator. The rod members are interconnected to the steam generator assembly and a support structure in a manner which provides for thermal distortion of the steam generator without the transfer of bending moments to the support structure and in a like manner substantially minimizes forces being transferred between the support structure and the steam generator as a result of seismic disturbances.

  1. Predicting Steam Turbine Performance

    E-Print Network [OSTI]

    Harriz, J. T.

    ," PREDICTING STEAM TURBINE PERFORMANCE James T. Harriz, EIT Waterland, Viar & Associates, Inc. Wilmington, Delaware ABSTRACT Tracking the performance of extraction, back pressure and condensing steam turbines is a crucial part... energy) and test data are presented. Techniques for deriving efficiency curves from each source are described. These techniques can be applied directly to any steam turbine reliability study effort. INTRODUCTION As the cost of energy resources...

  2. Steam System Data Management

    E-Print Network [OSTI]

    Roberts, D.

    2013-01-01T23:59:59.000Z

    Steam System Data Management What Does It Include Safety In Motion Wal?Tech?Valve,?Inc. 251?438?2203 The Real Genius Behind Technology Is People ESL-IE-13-05-35 Proceedings of the Thrity-Fifth Industrial Energy Technology Conference New... ? Fabrication Training (Six Year Training) ? Welding Certifications ?Retired From Chevron After 25 Years ? Established A Steam System Program ? Planner For Routine Maintenance Work ? Planner For Steam System Improvements ? Wal-Tech Valve, Inc. ? Purchased...

  3. Downhole steam injector

    DOE Patents [OSTI]

    Donaldson, A. Burl (Albuquerque, NM); Hoke, Donald E. (Albuquerque, NM)

    1983-01-01T23:59:59.000Z

    An improved downhole steam injector has an angled water orifice to swirl the water through the device for improved heat transfer before it is converted to steam. The injector also has a sloped diameter reduction in the steam chamber to throw water that collects along the side of the chamber during slant drilling into the flame for conversion to steam. In addition, the output of the flame chamber is beveled to reduce hot spots and increase efficiency, and the fuel-oxidant inputs are arranged to minimize coking.

  4. Low-Cost High-Pressure Hydrogen Generator

    SciTech Connect (OSTI)

    Cropley, Cecelia C.; Norman, Timothy J.

    2008-04-02T23:59:59.000Z

    Electrolysis of water, particularly in conjunction with renewable energy sources, is potentially a cost-effective and environmentally friendly method of producing hydrogen at dispersed forecourt sites, such as automotive fueling stations. The primary feedstock for an electrolyzer is electricity, which could be produced by renewable sources such as wind or solar that do not produce carbon dioxide or other greenhouse gas emissions. However, state-of-the-art electrolyzer systems are not economically competitive for forecourt hydrogen production due to their high capital and operating costs, particularly the cost of the electricity used by the electrolyzer stack. In this project, Giner Electrochemical Systems, LLC (GES) developed a low cost, high efficiency proton-exchange membrane (PEM) electrolysis system for hydrogen production at moderate pressure (300 to 400 psig). The electrolyzer stack operates at differential pressure, with hydrogen produced at moderate pressure while oxygen is evolved at near-atmospheric pressure, reducing the cost of the water feed and oxygen handling subsystems. The project included basic research on catalysts and membranes to improve the efficiency of the electrolysis reaction as well as development of advanced materials and component fabrication methods to reduce the capital cost of the electrolyzer stack and system. The project culminated in delivery of a prototype electrolyzer module to the National Renewable Energy Laboratory for testing at the National Wind Technology Center. Electrolysis cell efficiency of 72% (based on the lower heating value of hydrogen) was demonstrated using an advanced high-strength membrane developed in this project. This membrane would enable the electrolyzer system to exceed the DOE 2012 efficiency target of 69%. GES significantly reduced the capital cost of a PEM electrolyzer stack through development of low cost components and fabrication methods, including a 60% reduction in stack parts count. Economic analysis indicates that hydrogen could be produced for $3.79 per gge at an electricity cost of $0.05/kWh by the lower-cost PEM electrolyzer developed in this project, assuming high-volume production of large-scale electrolyzer systems.

  5. Options for Generating Steam Efficiently

    E-Print Network [OSTI]

    Ganapathy, V.

    This paper describes how plant engineers can efficiently generate steam when there are steam generators and Heat Recovery Steam Generators in their plant. The process consists of understanding the performance characteristics of the various equipment...

  6. High Pressure Shock Tube Studies of Fuel Combustion Engineering The high-pressure single-pulse shock tube is shown in Figure 8 (rated at 5 to 1000 atm,

    E-Print Network [OSTI]

    Ben-Arie, Jezekiel

    High Pressure Shock Tube Studies of Fuel Combustion Engineering The high-pressure single and oxidative degradation of various components in order to identify the products as guides to the combustion

  7. High Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Presentation. Project objectives: Design, demonstrate, and qualify high-temperature high pressure zonal isolation devices compatible with the high temperature downhole Enhanced Geothermal Systems (EGS) environment.

  8. Experimental Investigation on High-pressure, High-temperature Viscosity of Gas Mixtures

    E-Print Network [OSTI]

    Davani, Ehsan

    2012-02-14T23:59:59.000Z

    Modeling the performance of high-pressure, high-temperature (HPHT) natural gas reservoirs requires the understanding of gas behavior at such conditions. In particular, gas viscosity is an important fluid property that directly affects fluid flow...

  9. Numerical Modeling of Cased-hole Instability in High Pressure and High Temperature Wells

    E-Print Network [OSTI]

    Shen, Zheng 1983-

    2012-11-12T23:59:59.000Z

    of cemented sections in High Pressure High Temperature (HPHT) wells. The existing analysis shows that, in the perforation zones, casing/cement is subject to instability, particularly in the presence of cavities. This dissertation focuses on the instability...

  10. FLOW OF A FLUID THROUGH A POROUS SOLID DUE TO HIGH PRESSURE GRADIENTS

    E-Print Network [OSTI]

    Bonito, Andrea

    or carbon diox- ide sequestration where very high pressure differentials are involved. Another important and geotechnical engineering, for example problems such as enhanced oil recovery and carbon di-oxide sequestration

  11. Radiochemical Transformation of High Pressure Methane under Gamma, Electron, and Neutron Irradiation

    E-Print Network [OSTI]

    Clemens, Jeffrey Tyler

    2014-05-01T23:59:59.000Z

    The chemical effects of irradiation on high pressure methane and noble gas mixtures were investigated using gamma, electron beam, and neutron irradiation sources. The gamma source used was the La-140 source from the Nuclear Science Center (NSC...

  12. ORIGINAL PAPER Titanium-and water-rich metamorphic olivine in high-pressure

    E-Print Network [OSTI]

    Jung, Haemyeong

    ORIGINAL PAPER Titanium- and water-rich metamorphic olivine in high-pressure serpentinites from 2013 Springer-Verlag Berlin Heidelberg 2014 Abstract Titanium- and water-rich metamorphic olivine (Fo

  13. Instrumentation development for magneto-transport and neutron scattering measurements at high pressure and low temperature

    E-Print Network [OSTI]

    Wang, Weiwei

    2013-07-01T23:59:59.000Z

    High pressure, high magnetic field and low temperature techniques are required to investigate magnetic transitions and quantum critical behaviour in different ferromagnetic materials to elucidate how novel forms of ...

  14. Synthesis, structure and properties of high pressure and ambient pressure ternary vanadium oxides

    E-Print Network [OSTI]

    Markkula, Mikael

    2013-11-28T23:59:59.000Z

    Transition metal oxides have been extensively studied during past decades. The purpose of this research was to synthesize new or little characterised transition metal oxides using high-pressure/high-temperature (HPHT) ...

  15. Vehicle having hydraulic and power steering systems using a single high pressure pump

    DOE Patents [OSTI]

    Bartley, Bradley E. (Manito, IL); Blass, James R. (Bloomington, IL); Gibson, Dennis H. (Chillicothe, IL)

    2001-06-22T23:59:59.000Z

    A vehicle comprises a plurality of wheels attached to a vehicle housing. Also attached to the vehicle housing is a power steering system, including a fluid flow circuit, which is operably coupled to a number of the wheels. An internal combustion engine attached to the vehicle housing is connected to a hydraulically actuated system that includes a high pressure pump. An outlet of the high pressure pump is in fluid communication with the fluid flow circuit.

  16. Investigation of a high pressure implosive technique for metal powder compaction

    E-Print Network [OSTI]

    Garrett, Donald Richard

    1970-01-01T23:59:59.000Z

    INVESTIGATION OF A HIGH PRESSURE IMPLOSIVE TECHNIQUE FOR METAL POWDER COMPACTION A Thesis DONALD RICHARD GARRETT Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER... OF SCIENCE August 1970 Ma)or Subject: Mechanical Engineering INVESTIGATION OF A HIGH PRESSURE IMPLOSIVE TECHNIQUE FOR METAL POWDER COMPACTION A Thesis by DONALD RICHARD GARRETT Approved as to style and content by: J@l, (Chairman of Committee) (Head...

  17. Advanced High-Temperature, High-Pressure Transport Reactor Gasification

    SciTech Connect (OSTI)

    Michael Swanson; Daniel Laudal

    2008-03-31T23:59:59.000Z

    The U.S. Department of Energy (DOE) National Energy Technology Laboratory Office of Coal and Environmental Systems has as its mission to develop advanced gasification-based technologies for affordable, efficient, zero-emission power generation. These advanced power systems, which are expected to produce near-zero pollutants, are an integral part of DOE's Vision 21 Program. DOE has also been developing advanced gasification systems that lower the capital and operating costs of producing syngas for chemical production. A transport reactor has shown potential to be a low-cost syngas producer compared to other gasification systems since its high-throughput-per-unit cross-sectional area reduces capital costs. This work directly supports the Power Systems Development Facility utilizing the KBR transport reactor located at the Southern Company Services Wilsonville, Alabama, site. Over 2800 hours of operation on 11 different coals ranging from bituminous to lignite along with a petroleum coke has been completed to date in the pilot-scale transport reactor development unit (TRDU) at the Energy & Environmental Research Center (EERC). The EERC has established an extensive database on the operation of these various fuels in both air-blown and oxygen-blown modes utilizing a pilot-scale transport reactor gasifier. This database has been useful in determining the effectiveness of design changes on an advanced transport reactor gasifier and for determining the performance of various feedstocks in a transport reactor. The effects of different fuel types on both gasifier performance and the operation of the hot-gas filter system have been determined. It has been demonstrated that corrected fuel gas heating values ranging from 90 to 130 Btu/scf have been achieved in air-blown mode, while heating values up to 230 Btu/scf on a dry basis have been achieved in oxygen-blown mode. Carbon conversions up to 95% have also been obtained and are highly dependent on the oxygen-coal ratio. Higher-reactivity (low-rank) coals appear to perform better in a transport reactor than the less reactive bituminous coals. Factors that affect TRDU product gas quality appear to be coal type, temperature, and air/coal ratios. Testing with a higher-ash, high-moisture, low-rank coal from the Red Hills Mine of the Mississippi Lignite Mining Company has recently been completed. Testing with the lignite coal generated a fuel gas with acceptable heating value and a high carbon conversion, although some drying of the high-moisture lignite was required before coal-feeding problems were resolved. No ash deposition or bed material agglomeration issues were encountered with this fuel. In order to better understand the coal devolatilization and cracking chemistry occurring in the riser of the transport reactor, gas and solid sampling directly from the riser and the filter outlet has been accomplished. This was done using a baseline Powder River Basin subbituminous coal from the Peabody Energy North Antelope Rochelle Mine near Gillette, Wyoming.

  18. TRAVELING WAVES IN A FINITE CONDENSATION RATE MODEL FOR STEAM INJECTION

    E-Print Network [OSTI]

    Eindhoven, Technische Universiteit

    TRAVELING WAVES IN A FINITE CONDENSATION RATE MODEL FOR STEAM INJECTION J. BRUINING AND C.J. VAN DUIJN Abstract. Steam drive recovery of oil is an economical way of producing oil even in times of low oil prices and is used world wide. This paper focuses on the one-dimensional setting, where steam

  19. Understanding the Mechanism of Highly Efficient Nanoparticle-Mediated Conversion of Light to Steam

    E-Print Network [OSTI]

    Conversion of Light to Steam Nathaniel J. Hogan,1 Alexander Urban,2 Alberto Pimpinelli,3 Ciceron Ayala in the application of light-harvesting nanoparticles as efficient producers of solar steam. With broad the mechanism whereby such particles convert light into usable steam is a crucial step. Much debate has centered

  20. Method and apparatus for improving the performance of a steam driven power system by steam mixing

    DOE Patents [OSTI]

    Tsiklauri, Georgi V. (Richland, WA); Durst, Bruce M. (Kennewick, WA); Prichard, Andrew W. (Richland, WA); Reid, Bruce D. (Pasco, WA); Burritt, James (Virginia Beach, VA)

    1998-01-01T23:59:59.000Z

    A method and apparatus for improving the efficiency and performance of a steam driven power plant wherein addition of steam handling equipment to an existing plant results in a surprising increase in plant performance. For Example, a gas turbine electrical generation system with heat recovery boiler may be installed along with a micro-jet high pressure and a low pressure mixer superheater. Depending upon plant characteristics, the existing moisture separator reheater (MSR) can be either augmented or done away with. The instant invention enables a reduction in T.sub.hot without a derating of the reactor unit, and improves efficiency of the plant's electrical conversion cycle. Coupled with this advantage is a possible extension of the plant's fuel cycle length due to an increased electrical conversion efficiency. The reduction in T.sub.hot further allows for a surprising extension of steam generator life. An additional advantage is the reduction in erosion/corrosion of secondary system components including turbine blades and diaphragms. The gas turbine generator used in the instant invention can also replace or augment existing peak or emergency power needs. Another benefit of the instant invention is the extension of plant life and the reduction of downtime due to refueling.

  1. Simulation of a main steam line break with steam generator tube rupture using trace

    SciTech Connect (OSTI)

    Gallardo, S.; Querol, A.; Verdu, G. [Departamento de Ingenieria Quimica Y Nuclear, Universitat Politecnica de Valencia, Camino de Vera s/n, 46022, Valencia (Spain)

    2012-07-01T23:59:59.000Z

    A simulation of the OECD/NEA ROSA-2 Project Test 5 was made with the thermal-hydraulic code TRACE5. Test 5 performed in the Large Scale Test Facility (LSTF) reproduced a Main Steam Line Break (MSLB) with a Steam Generator Tube Rupture (SGTR) in a Pressurized Water Reactor (PWR). The result of these simultaneous breaks is a depressurization in the secondary and primary system in loop B because both systems are connected through the SGTR. Good approximation was obtained between TRACE5 results and experimental data. TRACE5 reproduces qualitatively the phenomena that occur in this transient: primary pressure falls after the break, stagnation of the pressure after the opening of the relief valve of the intact steam generator, the pressure falls after the two openings of the PORV and the recovery of the liquid level in the pressurizer after each closure of the PORV. Furthermore, a sensitivity analysis has been performed to know the effect of varying the High Pressure Injection (HPI) flow rate in both loops on the system pressures evolution. (authors)

  2. Streams of Steam The Steam Boiler Specification Case Study

    E-Print Network [OSTI]

    Streams of Steam ­ The Steam Boiler Specification Case Study Manfred Broy, Franz Regensburger-tuned con- cepts of FOCUS by its application of the requirements specification of a steam boiler, see [Abr96-studies. In this context, applying FOCUS to the steam boiler case study ([Abr96]) led us to a couple of questions re- #12

  3. Ukraine Steam Partnership

    SciTech Connect (OSTI)

    Gurvinder Singh

    2000-02-15T23:59:59.000Z

    The Ukraine Steam Partnership program is designed to implement energy efficiency improvements in industrial steam systems. These improvements are to be made by the private plants and local government departments responsible for generation and delivery of energy to end-users. One of the activities planned under this program was to provide a two-day training workshop on industrial steam systems focusing on energy efficiency issues related to the generation, distribution, and consumption of steam. The workshop was geared towards plant managers, who are not only technically oriented, but are also key decision makers in their respective companies. The Agency for Rational Energy Use and Ecology (ARENA-ECO), a non-governmental, not-for-profit organization founded to promote energy efficiency and environmental protection in Ukraine, in conjunction with the Alliance staff in Kiev sent out invitations to potential participants in all the regions of Ukraine. The purpose of this report is the describe the proceedings from the workshop and provide recommendations from the workshop's roundtable discussion. The workshop was broken down into two main areas: (1) Energy efficient boiler house steam generation; and Energy efficient steam distribution and consumption. The workshop also covered the following topics: (1) Ukrainian boilers; (2) Water treatment systems; (3) A profile of UKRESCO (Ukrainian Energy Services Company); (4) Turbine expanders and electricity generation; (5) Enterprise energy audit basics; and (6) Experience of steam use in Donetsk oblast.

  4. Steam trap monitor

    DOE Patents [OSTI]

    Ryan, Michael J. (Plainfield, IL)

    1988-01-01T23:59:59.000Z

    A steam trap monitor positioned downstream of a steam trap in a closed steam system includes a first sensor (the combination of a hot finger and thermocouple well) for measuring the energy of condensate and a second sensor (a cold finger) for measuring the total energy of condensate and steam in the line. The hot finger includes one or more thermocouples for detecting condensate level and energy, while the cold finger contains a liquid with a lower boiling temperature than that of water. Vapor pressure from the liquid is used to do work such as displacing a piston or bellows in providing an indication of total energy (steam+condensate) of the system. Processing means coupled to and responsive to outputs from the thermocouple well hot and cold fingers subtracts the condensate energy as measured by the hot finger and thermocouple well from the total energy as measured by the cold finger to provide an indication of the presence of steam downstream from the trap indicating that the steam trap is malfunctioning.

  5. Steam generator tube failures

    SciTech Connect (OSTI)

    MacDonald, P.E.; Shah, V.N.; Ward, L.W.; Ellison, P.G.

    1996-04-01T23:59:59.000Z

    A review and summary of the available information on steam generator tubing failures and the impact of these failures on plant safety is presented. The following topics are covered: pressurized water reactor (PWR), Canadian deuterium uranium (CANDU) reactor, and Russian water moderated, water cooled energy reactor (VVER) steam generator degradation, PWR steam generator tube ruptures, the thermal-hydraulic response of a PWR plant with a faulted steam generator, the risk significance of steam generator tube rupture accidents, tubing inspection requirements and fitness-for-service criteria in various countries, and defect detection reliability and sizing accuracy. A significant number of steam generator tubes are defective and are removed from service or repaired each year. This wide spread damage has been caused by many diverse degradation mechanisms, some of which are difficult to detect and predict. In addition, spontaneous tube ruptures have occurred at the rate of about one every 2 years over the last 20 years, and incipient tube ruptures (tube failures usually identified with leak detection monitors just before rupture) have been occurring at the rate of about one per year. These ruptures have caused complex plant transients which have not always been easy for the reactor operators to control. Our analysis shows that if more than 15 tubes rupture during a main steam line break, the system response could lead to core melting. Although spontaneous and induced steam generator tube ruptures are small contributors to the total core damage frequency calculated in probabilistic risk assessments, they are risk significant because the radionuclides are likely to bypass the reactor containment building. The frequency of steam generator tube ruptures can be significantly reduced through appropriate and timely inspections and repairs or removal from service.

  6. Materials Performance in USC Steam

    SciTech Connect (OSTI)

    G. R. Holcomb; J. Tylczak; G. H. Meier; N. M. Yanar

    2011-09-07T23:59:59.000Z

    Materials Performance in USC Steam: (1) pressure effects on steam oxidation - unique capability coming on-line; (2) hydrogen evolution - hydrogen permeability apparatus to determine where hydrogen goes during steam oxidation; and (3) NETL materials development - steam oxidation resource for NETL developed materials.

  7. Project DEEP STEAM: third meeting of the technical advisory panel, Bakersfield, CA, March 1980

    SciTech Connect (OSTI)

    Fox, R. L.; Johnson, D. R.; Donaldson, A. B.; Mulac, A. J.; Krueger, D. A.

    1981-04-01T23:59:59.000Z

    The third meeting of the technical advisory panel for the Deep Steam project was held in March 1980 in Bakersfield, California. The following seven papers were presented: Materials Studies; Insulation/Packer Simulation Test; Enhanced Recovery Packer; High Pressure Downhole Steam Generator; Lower Pressure Downhole Steam Generator; Physical Simulations; and Field Testing. The panel made many recommendations, some of which are: shell calcium silicate insulation should be included in the injection string modification program; for metal packer, consider age hardening alloys, testing with thermal cycling, intentionally flawed casing, and operational temperatures effect on differential expansion, plus long term tests under temperature and corrosive environment; for minimum stress packer, consider testing environment carefully as some elastomers are especially susceptible to oil, oxygen, and combustion gases; for downhole steam generator, quality of water required with new low pressure combustion design needs to be investigated; in field testing, materials coupons, for corrosion monitoring, should be an integral part of field test operations.

  8. LNG Vehicle High-Pressure Fuel System and ''Cold Energy'' Utilization

    SciTech Connect (OSTI)

    powers,Charles A.; Derbidge, T. Craig

    2001-03-27T23:59:59.000Z

    A high-pressure fuel system for LNG vehicles with direct-injection natural gas engines has been developed and demonstrated on a heavy-duty truck. A new concept for utilizing the ''cold energy'' associated with LNG vehicles to generate mechanical power to drive auxiliary equipment (such as high-pressure fuel pumps) has also been developed and demonstrated in the laboratory. The high-pressure LNG fuel system development included the design and testing of a new type of cryogenic pump utilizes multiple chambers and other features to condense moderate quantities of sucked vapor and discharge supercritical LNG at 3,000 to 4,000 psi. The pump was demonstrated on a Class 8 truck with a Westport high-pressure direct-injection Cummins ISX engine. A concept that utilizes LNG's ''cold energy'' to drive a high-pressure fuel pump without engine attachments or power consumption was developed. Ethylene is boiled and superheated by the engine coolant, and it is cooled and condensed by rejecting h eat to the LNG. Power is extracted in a full-admission blowdown process, and part of this power is applied to pump the ethylene liquid to the boiler pressure. Tests demonstrated a net power output of 1.1. hp at 1.9 Lbm/min of LNG flow, which is adequate to isentropically pump the LNG to approximately 3,400 psi..

  9. Email To Friend Steam Electricity Generator

    E-Print Network [OSTI]

    . keymanengravables.com Steam Turbine Generator Info, Pictures And Deals For Steam turbine generator ediscountshoppingBack One Email To Friend Steam Electricity Generator Need Steam Electricity Generator? See Steam Electricity Generator. greenshieldsindustrial.com Steam Generators Deals on Steam Generators Find what you

  10. Development of a High Pressure/High Temperature Down-hole Turbine Generator

    SciTech Connect (OSTI)

    Ben Plamp

    2008-06-30T23:59:59.000Z

    As oil & natural gas deposits become more difficult to obtain by conventional means, wells must extend to deeper more heat-intensive environments. The technology of the drilling equipment required to reach these depths has exceeded the availability of electrical power sources needed to operate these tools. Historically, logging while drilling (LWD) and measure while drilling (MWD) devices utilized a wireline to supply power and communication from the operator to the tool. Lithium ion batteries were used in scenarios where a wireline was not an option, as it complicated operations. In current downhole applications, lithium ion battery (LIB) packs are the primary source for electrical power. LIB technology has been proven to supply reliable downhole power at temperatures up to 175 C. Many of the deeper well s reach ambient temperatures above 200 C, creating an environment too harsh for current LIB technology. Other downfalls of LIB technology are cost, limitations on charge cycles, disposal issues and possible safety hazards including explosions and fires. Downhole power generation can also be achieved by utilizing drilling fluid flow and converting it to rotational motion. This rotational motion can be harnessed to spin magnets around a series of windings to produce power proportional to the rpm experienced by the driven assembly. These generators are, in most instances, driven by turbine blades or moyno-based drilling fluid pumps. To date, no commercially available downhole power generators are capable of operating at ambient temperatures of 250 C. A downhole power g enerator capable of operation in a 250 C and 20,000 psi ambient environment will be an absolute necessity in the future. Dexter Magnetic Technologies High-Pressure High-Temperature (HPHT) Downhole Turbine Generator is capable of operating at 250 C and 20, 000 psi, but has not been tested in an actual drilling application. The technology exists, but to date no company has been willing to test the tool.

  11. Autoignition of toluene reference fuels at high pressures modeled with detailed chemical kinetics

    SciTech Connect (OSTI)

    Andrae, J.C.G. [Department of Chemical Engineering and Technology, Royal Institute of Technology, SE-100 44 Stockholm (Sweden); Shell Global Solutions, P.O. Box 1, Chester CH1 3SH (United Kingdom); Bjoernbom, P. [Department of Chemical Engineering and Technology, Royal Institute of Technology, SE-100 44 Stockholm (Sweden); Cracknell, R.F.; Kalghatgi, G.T. [Shell Global Solutions, P.O. Box 1, Chester CH1 3SH (United Kingdom)

    2007-04-15T23:59:59.000Z

    A detailed chemical kinetic model for the autoignition of toluene reference fuels (TRF) is presented. The toluene submechanism added to the Lawrence Livermore Primary Reference Fuel (PRF) mechanism was developed using recent shock tube autoignition delay time data under conditions relevant to HCCI combustion. For two-component fuels the model was validated against recent high-pressure shock tube autoignition delay time data for a mixture consisting of 35% n-heptane and 65% toluene by liquid volume. Important features of the autoignition of the mixture proved to be cross-acceleration effects, where hydroperoxy radicals produced during n-heptane oxidation dramatically increased the oxidation rate of toluene compared to the case when toluene alone was oxidized. Rate constants for the reaction of benzyl and hydroperoxyl radicals previously used in the modeling of the oxidation of toluene alone were untenably high for modeling of the mixture. To model both systems it was found necessary to use a lower rate and introduce an additional branching route in the reaction between benzyl radicals and O{sub 2}. Good agreement between experiments and predictions was found when the model was validated against shock tube autoignition delay data for gasoline surrogate fuels consisting of mixtures of 63-69% isooctane, 14-20% toluene, and 17% n-heptane by liquid volume. Cross reactions such as hydrogen abstractions between toluene and alkyl and alkylperoxy radicals and between the PRF were introduced for completion of chemical description. They were only of small importance for modeling autoignition delays from shock tube experiments, even at low temperatures. A single-zone engine model was used to evaluate how well the validated mechanism could capture autoignition behavior of toluene reference fuels in a homogeneous charge compression ignition (HCCI) engine. The model could qualitatively predict the experiments, except in the case with boosted intake pressure, where the initial temperature had to be increased significantly in order to predict the point of autoignition. (author)

  12. Predicting Steam Turbine Performance

    E-Print Network [OSTI]

    Harriz, J. T.

    1985-01-01T23:59:59.000Z

    Tracking the performance of extraction, back-pressure and condensing steam turbines is a crucial part of minimising energy and maintenance costs for large process industries. A thorough understanding of key equipment performance characteristics...

  13. Steam System Losses

    E-Print Network [OSTI]

    Buchanan, M. G.; Sneary, M. L.

    energy into the air. You might say that many of us are increasing the relative humidity of our respective cities. Before a conventional pump package can handle steam condensate, that fluid must be cooled to somewhere below 180 0 ? This cooling... are increasing the relative humidity of our respective cities. Before a conventional pump package can handle steam condensate, that fluid must be cooled to somewhere below 180 0 . This cooling is accomplished by venting the receiver to the atmosphere...

  14. Molecular Surface Chemistry by Metal Single Crystals and Nanoparticles from Vacuum to High Pressure.

    SciTech Connect (OSTI)

    Somorjai, Gabor A.; Park, Jeong Y.

    2008-04-05T23:59:59.000Z

    Model systems for studying molecular surface chemistry have evolved from single crystal surfaces at low pressure to colloidal nanoparticles at high pressure. Low pressure surface structure studies of platinum single crystals using molecular beam surface scattering and low energy electron diffraction techniques probe the unique activity of defects, steps and kinks at the surface for dissociation reactions (H-H, C-H, C-C, O{double_bond}O bonds). High-pressure investigations of platinum single crystals using sum frequency generation vibrational spectroscopy have revealed the presence and the nature of reaction intermediates. High pressure scanning tunneling microscopy of platinum single crystal surfaces showed adsorbate mobility during a catalytic reaction. Nanoparticle systems are used to determine the role of metal-oxide interfaces, site blocking and the role of surface structures in reactive surface chemistry. The size, shape and composition of nanoparticles play important roles in determining reaction activity and selectivity.

  15. Numerical investigation of high-pressure combustion in rocket engines using Flamelet/Progress-variable models

    E-Print Network [OSTI]

    Coclite, A; De Palma, P; Pascazio, G

    2015-01-01T23:59:59.000Z

    The present paper deals with the numerical study of high pressure LOx/H2 or LOx/hydrocarbon combustion for propulsion systems. The present research effort is driven by the continued interest in achieving low cost, reliable access to space and more recently, by the renewed interest in hypersonic transportation systems capable of reducing time-to-destination. Moreover, combustion at high pressure has been assumed as a key issue to achieve better propulsive performance and lower environmental impact, as long as the replacement of hydrogen with a hydrocarbon, to reduce the costs related to ground operations and increase flexibility. The current work provides a model for the numerical simulation of high- pressure turbulent combustion employing detailed chemistry description, embedded in a RANS equations solver with a Low Reynolds number k-omega turbulence model. The model used to study such a combustion phenomenon is an extension of the standard flamelet-progress-variable (FPV) turbulent combustion model combined ...

  16. An RF-only ion-funnel for extraction from high-pressure gases

    E-Print Network [OSTI]

    Thomas Brunner; Daniel Fudenberg; Victor Varentsov; Amanda Sabourov; Giorgio Gratta; Jens Dilling; Ralph DeVoe; David Sinclair; William Fairbank Jr.; Joshua B Albert; David J Auty; Phil S Barbeau; Douglas Beck; Cesar Benitez-Medina; Martin Breidenbach; Guofu F Cao; Christopher Chambers; Bruce Cleveland; Matthew Coon; Adam Craycraft; Timothy Daniels; Sean J Daugherty; Tamar Didberidze; Michelle J Dolinski; Matthew Dunford; Lorenzo Fabris; Jacques Farine; Wolfhart Feldmeier; Peter Fierlinger; Razvan Gornea; Kevin Graham; Mike Heffner; Mitchell Hughes; Michael Jewell; Xiaoshan S Jiang; Tessa N Johnson; Sereres Johnston; Alexander Karelin; Lisa J Kaufman; Ryan Killick; Thomas Koffas; Scott Kravitz; Reiner Kruecken; Alexey Kuchenkov; Krishna S Kumar; Douglas S Leonard; Francois Leonard; Caio Licciardi; Yi-Hsuan H Lin; Jiajie Ling; Ryan MacLellan; Michael G Marino; Brian Mong; David Moore; Allen Odian; Igor Ostrovskiy; Christian Ouellet; Andreas Piepke; Andrea Pocar; Fabrice Retiere; Peter C Rowson; Maria P Rozo; Alexis Schubert; Erica Smith; Victor Stekhanov; Michal Tarka; Tamer Tolba; Delia Tosi; Karl Twelker; Jean-Luc L Vuilleumier; Josiah Walton; Timothy Walton; Manuel Weber; Liangjian J Wen; Ubi Wichoski; Liang Yang; Yung-Ruey Yen

    2014-12-03T23:59:59.000Z

    An RF ion-funnel technique has been developed to extract ions from a high-pressure (10 bar) noble-gas environment into vacuum ($10^{-6}$ mbar). Detailed simulations have been performed and a prototype has been developed for the purpose of extracting $^{136}$Ba ions from Xe gas with high efficiency. With this prototype, ions have been extracted for the first time from high-pressure xenon gas and argon gas. Systematic studies have been carried out and compared to the simulations. This demonstration of extraction of ions with mass comparable to that of the gas generating the high-pressure into vacuum has applications to Ba tagging from a Xe-gas time-projection chamber (TPC) for double beta decay as well as to the general problem of recovering trace amounts of an ionized element in a heavy (m$>40$ u) carrier gas.

  17. Automated high pressure cell for pressure jump x-ray diffraction

    SciTech Connect (OSTI)

    Brooks, Nicholas J.; Gauthe, Beatrice L. L. E.; Templer, Richard H.; Ces, Oscar; Seddon, John M. [Department of Chemistry, Imperial College London, South Kensington Campus, London SW7 2AZ (United Kingdom); Terrill, Nick J. [Diamond Light Source, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0DE (United Kingdom); Rogers, Sarah E. [ISIS, Rutherford Appleton Laboratory, Harwell Science and Innovation Campus, Didcot, Oxfordshire OX11 0QX (United Kingdom)

    2010-06-15T23:59:59.000Z

    A high pressure cell for small and wide-angle x-ray diffraction measurements of soft condensed matter samples has been developed, incorporating a fully automated pressure generating network. The system allows both static and pressure jump measurements in the range of 0.1-500 MPa. Pressure jumps can be performed as quickly as 5 ms, both with increasing and decreasing pressures. Pressure is generated by a motorized high pressure pump, and the system is controlled remotely via a graphical user interface to allow operation by a broad user base, many of whom may have little previous experience of high pressure technology. Samples are loaded through a dedicated port allowing the x-ray windows to remain in place throughout an experiment; this facilitates accurate subtraction of background scattering. The system has been designed specifically for use at beamline I22 at the Diamond Light Source, United Kingdom, and has been fully integrated with the I22 beamline control systems.

  18. Steam System Tool Suite Introduction Guide

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    Steam System Tool Suite Introduction Guide Alternate Text Narratives and Graphic.............................................................................................................................6 Modules Steam System Scoping Tool (SSST)........................................................................................8 Steam System Assessment Tool (SSAT

  19. DOE's BestPractices Steam End User Training Steam End User Training

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    DOE's BestPractices Steam End User Training Steam End User Training Steam Distribution Losses Module 1 June 29, 2010 Steam EndUser Training Steam Distribution System Losses Module Slide 1 pressure. #12;DOE's BestPractices Steam End User Training Steam End User Training Steam Distribution

  20. Improved x-ray collimation system for diamond-anvil high-pressure cells

    SciTech Connect (OSTI)

    Schiferl, D.; Olinger, B.; Livingston, R.

    1983-09-01T23:59:59.000Z

    An improved x-ray collimation system for diamond-anvil high-pressure cells is described. The usual practice of mounting the collimator directly in the diamond-anvil cell is not followed. Instead, the collimator is mounted and aligned in a fixture which can be removed from the diamong-anvil cell. The end of the collimator furthest from the sample can be fitted with a set of removable plugs, each with a different aperture. This collimation system is easily aligned, can be removed from the high-pressure cell with no loss of alignment, and is inexpensive to construct.

  1. Effect of steam partial pressure on gasification rate and gas composition of product gas from catalytic steam gasification of HyperCoal

    SciTech Connect (OSTI)

    Atul Sharma; Ikuo Saito; Toshimasa Takanohashi [National Institute of Advanced Industrial Science and Technology, Ibaraki (Japan). Advanced Fuel Group

    2009-09-15T23:59:59.000Z

    HyperCoal was produced from coal by a solvent extraction method. The effect of the partial pressure of steam on the gasification rate and gas composition at temperatures of 600, 650, 700, and 750{sup o}C was examined. The gasification rate decreased with decreasing steam partial pressure. The reaction order with respect to steam partial pressure was between 0.2 and 0.5. The activation energy for the K{sub 2}CO{sub 3}-catalyzed HyperCoal gasification was independent of the steam partial pressure and was about 108 kJ/mol. The gas composition changed with steam partial pressure and H{sub 2} and CO{sub 2} decreased and CO increased with decreasing steam partial pressure. By changing the partial pressure of the steam, the H{sub 2}/CO ratio of the synthesis gas can be controlled. 18 refs., 7 figs., 2 tabs.

  2. Fractal characterisation of high-pressure and hydrogen-enriched CH4air turbulent premixed flames

    E-Print Network [OSTI]

    Gülder, ?mer L.

    Fractal characterisation of high-pressure and hydrogen-enriched CH4­air turbulent premixed flames measurements were performed to obtain the flame front images, which were further analyzed for fractal of the flame front curvature as a function of the pressure. Fractal dimension showed a strong dependence

  3. Microdischarge-assisted ignition of dielectric-barrier high-pressure glow discharges

    E-Print Network [OSTI]

    Raja, Laxminarayan L.

    of an array of microdischarges integrated with one of the DB-HPG electrodes, a substantial reduction of DB1000 Torr.1,2 Due to high pd pressure-distance val- ues at high pressures, relatively high breakdown of four microdischarges on the bottom electrode-dielectric assembly surface. The up- per electrode

  4. Hydrogen incorporation in stishovite at high pressure and symmetric hydrogen bonding in N-AlOOH

    E-Print Network [OSTI]

    Stixrude, Lars

    Hydrogen incorporation in stishovite at high pressure and symmetric hydrogen bonding in N significant amounts of hydrogen in stishovite under lower-mantle conditions. The enthalpy of solution pressure and temperature. We predict asymmetric hydrogen bonding in the stishovite^N-AlOOH solid solution

  5. Dynamics of Low-Pressure and High-Pressure Fuel Cell Air Supply System1

    E-Print Network [OSTI]

    Peng, Huei

    comparing the low pressure system with the high- pressure system equipped with a high-speed compressor pressure of the FC that is defined as the pressure at which the reactant hydrogen and oxygen (air) are delivered to the FC stack flow fields. In the case of stored compressed hydrogen the pressure of the cathode

  6. SmNd disequilibrium in high-pressure, low-temperature Himalayan and Alpine rocks

    E-Print Network [OSTI]

    Nicolas, Chamot-Rooke

    disequilibrium in high-pressure, low-temperature rocks, SmNd isotopic analyses were carried out on minerals from contamination processes. In the case of a magmatic protolith, contamination can be achieved through crustal sedimentary protolith contains components from an old contaminant crust. In the Himalayan samples, the inverse

  7. OPTIMAL DESIGN OF A HIGH PRESSURE ORGANOMETALLIC CHEMICAL VAPOR DEPOSITION REACTOR

    E-Print Network [OSTI]

    OPTIMAL DESIGN OF A HIGH PRESSURE ORGANOMETALLIC CHEMICAL VAPOR DEPOSITION REACTOR K.J. BACHMANN vapor deposition (HPOMCVD) reactor for use in thin film crystal growth. The advantages of such a reactor decomposition pressures and increased control over local stoichiometry and defect formation. While we focus here

  8. High pressure studies on uranium and thorium silicide compounds: Experiment S. Yagoubi a,b,c,

    E-Print Network [OSTI]

    Svane, Axel Torstein

    High pressure studies on uranium and thorium silicide compounds: Experiment and theory S. Yagoubi a, USi3, as well as some non-stoichiometric phases presented in Table 1. Among the thoriumB-type) that a ferromagnetic ordering is reported, with TC = 127 K and a saturated moment of 0.1 lB [3]. Concerning the thorium

  9. Stability of very-high pressure arc discharges against perturbations of the electron temperature

    SciTech Connect (OSTI)

    Benilov, M. S. [Departamento de Fisica, Ciencias Exactas e Engenharia, Universidade da Madeira, Largo do Municipio, Funchal 9000 (Portugal); Hechtfischer, U. [Philips Lighting, BU Automotive Lamps, Technology, Philipsstrasse 8, Aachen 52068 (Germany)

    2012-04-01T23:59:59.000Z

    We study the stability of the energy balance of the electron gas in very high-pressure plasmas against longitudinal perturbations, using a local dispersion analysis. After deriving a dispersion equation, we apply the model to a very high-pressure (100 bar) xenon plasma and find instability for electron temperatures, T{sub e}, in a window between 2400 K and 5500-7000 K x 10{sup 3} K, depending on the current density (10{sup 6}-10{sup 8} A/m{sup 2}). The instability can be traced back to the Joule heating of the electron gas being a growing function of T{sub e}, which is due to a rising dependence of the electron-atom collision frequency on T{sub e}. We then analyze the T{sub e} range occurring in very high-pressure xenon lamps and conclude that only the near-anode region exhibits T{sub e} sufficiently low for this instability to occur. Indeed, previous experiments have revealed that such lamps develop, under certain conditions, voltage oscillations accompanied by electromagnetic interference, and this instability has been pinned down to the plasma-anode interaction. A relation between the mechanisms of the considered instability and multiple anodic attachments of high-pressure arcs is discussed.

  10. Aragonite pseudomorphs in high-pressure marbles of Syros, Greece John B. Bradya,*, Michelle J. Markleyb

    E-Print Network [OSTI]

    Brady, John B.

    Aragonite pseudomorphs in high-pressure marbles of Syros, Greece John B. Bradya,*, Michelle J in the blueschist to eclogite facies marbles of Syros, Greece. The rods show a shape-preferred orientation is unusually low (Carlson and Rosenfeld, 1981). Although marbles on the island of Syros (Cyclades, Greece

  11. Dynamic behavior of an aggregate material at simultaneous high pressure and strain rate: SHPB triaxial tests

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    1 Dynamic behavior of an aggregate material at simultaneous high pressure and strain rate: SHPB Low velocity impacts on energetic materials induce plastic deformations and sliding friction which can pressure and high strain rate). Thus, a technique based on the Split Hopkinson Pressure Bars system

  12. Journal of Applied Physics 104,093504 (2008) Picosecond laser structuration under high pressures

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    2008-01-01T23:59:59.000Z

    A research on ultra-short laser modification of materials has been a subject of numerous studies last two. The main effect is specific to the ambient gas and laser pulse duration in the ablation regime: whenJournal of Applied Physics 104,093504 (2008) Picosecond laser structuration under high pressures

  13. High-pressure phases of CaCO3: Crystal structure prediction and experiment

    E-Print Network [OSTI]

    Oganov, Artem R.

    High-pressure phases of CaCO3: Crystal structure prediction and experiment Artem R. Oganov a October 2005 Available online 18 November 2005 Editor: G.D. Price Abstract Post-aragonite phase of CaCO3 transformation in CaCO3 at 40 GPa, Am. Mineral. 90 (2005) 667671], is believed to be a major carbon- containing

  14. Revisit of the relationship between the elastic properties and sound velocities at high pressures

    SciTech Connect (OSTI)

    Wang, Chenju; Yan, Xiaozhen [National Key Laboratory of Shock Wave and Detonation Physics, Institute of Fluid Physics, PO Box 919-102, Mianyang, Sichuan 621900 (China); Institute of Atomic and Molecular Sciences, Sichuan University, Chengdu 610065 (China); Xiang, Shikai, E-mail: skxiang@caep.ac.cn; Chen, Haiyan [National Key Laboratory of Shock Wave and Detonation Physics, Institute of Fluid Physics, PO Box 919-102, Mianyang, Sichuan 621900 (China); Gu, Jianbing; Yu, Yin [National Key Laboratory of Shock Wave and Detonation Physics, Institute of Fluid Physics, PO Box 919-102, Mianyang, Sichuan 621900 (China); College of Physical Science and Technology, Sichuan University, Chengdu 610064 (China); Kuang, Xiaoyu [Institute of Atomic and Molecular Sciences, Sichuan University, Chengdu 610065 (China); International Centre for Materials Physics, Academia Sinica, Shenyang 110016 (China)

    2014-09-14T23:59:59.000Z

    The second-order elastic constants and stress-strain coefficients are defined, respectively, as the second derivatives of the total energy and the first derivative of the stress with respect to strain. Since the Lagrangian and infinitesimal strain are commonly used in the two definitions above, the second-order elastic constants and stress-strain coefficients are separated into two categories, respectively. In general, any of the four physical quantities is employed to characterize the elastic properties of materials without differentiation. Nevertheless, differences may exist among them at non-zero pressures, especially high pressures. Having explored the confusing issue systemically in the present work, we find that the four quantities are indeed different from each other at high pressures and these differences depend on the initial stress applied on materials. Moreover, the various relations between the four quantities depicting elastic properties of materials and high-pressure sound velocities are also derived from the elastic wave equations. As examples, we calculated the high-pressure sound velocities of cubic tantalum and hexagonal rhenium using these nexus. The excellent agreement of our results with available experimental data suggests the general applicability of the relations.

  15. High-pressure phases of FeTiO3 from first principles N. C. Wilson

    E-Print Network [OSTI]

    2005; published 19 July 2005 The structural, elastic, and electronic properties of the high-pressure Fe and their interaction with the structural degrees of freedom. Ilmenite, the mineral form of FeTiO3, is commonly found of diamond deposits.2 In addition to ilmenite, two other polymorphs of FeTiO3 are known,3 namely, the lithium

  16. Ultrafast high-pressure AC electro-osmotic pumps for portable biomedical microfluidics

    E-Print Network [OSTI]

    Bazant, Martin Z.

    Ultrafast high-pressure AC electro-osmotic pumps for portable biomedical microfluidics Chien details the development of an integrated AC electro-osmotic (ACEO) microfluidic pump for dilute (100 mM) biological solutions in separate microfluidic devices, with potential applications in portable

  17. Properties of nanostructured diamond-silicon carbide composites sintered by high pressure infiltration technique

    E-Print Network [OSTI]

    Gubicza, Jen

    peak profiles using Fourier coefficients of ab initio theoretical size and strain profiles Materials Research Society 2703 #12;electric power dissipated in the apparatus. Obtained power temperature and loadpressure plots were used as the calibration curves for subsequent high-pressure, high- temperature

  18. FRICTION FACTOR IN HIGH PRESSURE NATURAL GAS PIPELINES FROM ROUGHNESS MEASUREMENTS

    E-Print Network [OSTI]

    Gudmundsson, Jon Steinar

    FRICTION FACTOR IN HIGH PRESSURE NATURAL GAS PIPELINES FROM ROUGHNESS MEASUREMENTS DETERMINATION DU and Technology, Norway ABSTRACT Pressure drop experiments on natural gas flow at 80 to 120 bar pressure and high of natural gas at typical operating pressures (100-180 bar). At such Reynolds numbers the classical Colebrook

  19. Studies of Charge Exchange in a High?Pressure Pulsed Electron Impact Source

    E-Print Network [OSTI]

    Sharma, D. K. Sen; Hierl, Peter M.; Franklin, J. L.

    1972-01-01T23:59:59.000Z

    A high pressure pulsed ion source has been used in a time?of?flight mass spectrometer in order to study the charge exchangereactions in ArH2 and ArD2 systems using the ion source in the ?ermk mode of operation. As the source was used in a pulsed...

  20. Acceptance test report for high pressure water jet system feed pump

    SciTech Connect (OSTI)

    Crystal, J.B.

    1996-03-12T23:59:59.000Z

    This document summarizes results of WHC-SD-SNF-ATP-016, Rev. 0 ``Acceptance Test Procedure High Pressure Water Jet System``, conducted on December 20, 1995 and December 22, 1995. This jet supplies water at 15,000 psi @ 15 gpm to nozzles to clean surfaces of empty fuel storage canisters.

  1. Steam generator tube rupture study

    E-Print Network [OSTI]

    Free, Scott Thomas

    1986-01-01T23:59:59.000Z

    This report describes our investigation of steam generator behavior during a postulated tube rupture accident. Our study was performed using the steam generator, thermal-hydraulic analysis code THERMIT-UTSG. The purpose ...

  2. Deaerators in Industrial Steam Systems

    SciTech Connect (OSTI)

    Not Available

    2006-01-01T23:59:59.000Z

    This revised ITP tip sheet on deaerators in industrial steam systems provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  3. Reduction in Unit Steam Production

    E-Print Network [OSTI]

    Gombos, R.

    2004-01-01T23:59:59.000Z

    In 2001 the company's Arch-Brandenburg facility faced increased steam costs due to high natural gas prices and decreased production due to shutdown of a process. The facility was challenged to reduce unit steam consumption to minimize the effects...

  4. Belgrade Lot Steam Plant Lot

    E-Print Network [OSTI]

    Thomas, Andrew

    2 2A 2A Belgrade Lot Steam Plant Lot Alfond Lot Satellite Lot North Gym Lot Corbett Lot Dunn Lot Chadbourne Merrill Aubert Hannibal Hamlin Steam Plant Crosby Machine Tool Lab Children's Center Rogers N

  5. Belgrade Lot Steam Plant Lot

    E-Print Network [OSTI]

    Thomas, Andrew

    2 2A 2A Belgrade Lot Steam Plant Lot Alfond Lot Satellite Lot North Gym Lot Corbett Lot Dunn Lot Hamlin Steam Plant Crosby Machine Tool Lab Children's Center Rogers N S Estabrooke Memorial Gym Stevens

  6. Economics of Steam Pressure Reduction

    E-Print Network [OSTI]

    Sylva, D. M.

    Economics of Steam Pressure Reduction is a technical paper that addresses the operating and economic advantages associated with the program to lower the steam operating pressure. Evaluation of a testing program will be discussed. The paper...

  7. Inspect and Repair Steam Traps

    SciTech Connect (OSTI)

    Not Available

    2006-01-01T23:59:59.000Z

    This revised ITP tip sheet on inspecting and repairing steam traps provide how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  8. Belgrade Lot Steam Plant Lot

    E-Print Network [OSTI]

    Thomas, Andrew

    2 2A 2A Belgrade Lot Steam Plant Lot Alfond Lot Satellite Lot North Gym Lot Gym Lot Corbett Lot Greenhouse Patch Oceanographic Operations 1 2 8 5 3 4 7 6 AMC Chadbourne Merrill Aubert Hannibal Hamlin Steam

  9. Belgrade Lot Steam Plant Lot

    E-Print Network [OSTI]

    Thomas, Andrew

    2 2A 2A Belgrade Lot Steam Plant Lot Alfond Lot Satellite Lot North Gym Lot Corbett Lot Dunn Lot Oceanographic Operations 1 2 8 5 3 4 7 6 AMC Chadbourne Merrill Aubert Hannibal Hamlin Steam Plant Crosby

  10. Steam Condensation Induced Waterhammer

    E-Print Network [OSTI]

    Kirsner, W.

    ,200 foot steam line to begin wanning it up. He'd been energizing the G-line for 3 weeks now at the end ofthe asbestos worker's shift and had never had the system warm up this quickly. It usually took from 30 to 45 minutes. When the handwheel spun... at Fort Wainwright, Alaska, the G and H Lines ran underground in narrow utilidors 2 filled with pipe. Originally, the contractor had tried to abate the steam main with the lines energized. This proved to be near impossible for the workers. Utilidor...

  11. DOE's BestPractices Steam End User Training Steam End User Training

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    DOE's BestPractices Steam End User Training Steam End User Training Steam Generation Efficiency Module Shell Losses - 1 8/27/2010 Steam End-User Training Steam Generation Efficiency Module Shell Losses-Section: Shell Losses] Banner: DOE's BestPractices Steam End User Training Steam Generation Efficiency Efficiency

  12. Automated High-Pressure Titration System with In Situ Infrared Spectroscopic Detection

    SciTech Connect (OSTI)

    Thompson, Christopher J.; Martin, Paul F.; Chen, Jeffrey; Benezeth, Pascale; Schaef, Herbert T.; Rosso, Kevin M.; Felmy, Andrew R.; Loring, John S.

    2014-04-17T23:59:59.000Z

    A fully automated titration system with infrared detection was developed for investigating interfacial chemistry at high pressures. The apparatus consists of a high-pressure fluid generation and delivery system coupled to a high-pressure cell with infrared optics. A manifold of electronically actuated valves is used to direct pressurized fluids into the cell. Precise reagent additions to the pressurized cell are made with calibrated tubing loops that are filled with reagent and placed in-line with the cell and a syringe pump. The cells infrared optics facilitate both transmission and attenuated total reflection (ATR) measurements to monitor bulk-fluid composition and solid-surface phenomena such as adsorption, desorption, complexation, dissolution, and precipitation. Switching between the two measurement modes is accomplished with moveable mirrors that direct radiation from a Fourier transform infrared spectrometer into the cell along transmission or ATR light paths. The versatility of the high-pressure IR titration system is demonstrated with three case studies. First, we titrated water into supercritical CO2 (scCO2) to generate an infrared calibration curve and determine the solubility of water in CO2 at 50 C and 90 bar. Next, we characterized the partitioning of water between a montmorillonite clay and scCO2 at 50 C and 90 bar. Transmission-mode spectra were used to quantify changes in the clays sorbed water concentration as a function of scCO2 hydration, and ATR measurements provided insights into competitive residency of water and CO2 on the clay surface and in the interlayer. Finally, we demonstrated how time-dependent studies can be conducted with the system by monitoring the carbonation reaction of forsterite (Mg2SiO4) in water-bearing scCO2 at 50 C and 90 bar. Immediately after water dissolved in the scCO2, a thin film of adsorbed water formed on the mineral surface, and the film thickness increased with time as the forsterite began to dissolve. However, after approximately 2.5 hours, the trend reversed, and a carbonate precipitate began to form on the forsterite surface, exposing dramatic chemical changes in the thin-water film. Collectively, these applications illustrate how the high-pressure IR titration system can provide molecular-level information about the interactions between variably wet scCO2 and minerals relevant to underground storage of CO2 (geologic carbon sequestration). The apparatus could also be utilized to study high-pressure interfacial chemistry in other areas such as catalysis, polymerization, food processing, and oil and gas recovery.

  13. Automated high-pressure titration system with in situ infrared spectroscopic detection

    SciTech Connect (OSTI)

    Thompson, Christopher J., E-mail: chris.thompson@pnnl.gov; Martin, Paul F.; Chen, Jeffrey; Schaef, Herbert T.; Rosso, Kevin M.; Felmy, Andrew R.; Loring, John S. [Pacific Northwest National Laboratory, Richland, Washington 99352 (United States)] [Pacific Northwest National Laboratory, Richland, Washington 99352 (United States); Benezeth, Pascale [Gosciences Environnement Toulouse (GET), CNRS-Universit de Toulouse, 31400 Toulouse (France)] [Gosciences Environnement Toulouse (GET), CNRS-Universit de Toulouse, 31400 Toulouse (France)

    2014-04-15T23:59:59.000Z

    A fully automated titration system with infrared detection was developed for investigating interfacial chemistry at high pressures. The apparatus consists of a high-pressure fluid generation and delivery system coupled to a high-pressure cell with infrared optics. A manifold of electronically actuated valves is used to direct pressurized fluids into the cell. Precise reagent additions to the pressurized cell are made with calibrated tubing loops that are filled with reagent and placed in-line with the cell and a syringe pump. The cell's infrared optics facilitate both transmission and attenuated total reflection (ATR) measurements to monitor bulk-fluid composition and solid-surface phenomena such as adsorption, desorption, complexation, dissolution, and precipitation. Switching between the two measurement modes is accomplished with moveable mirrors that direct the light path of a Fourier transform infrared spectrometer into the cell along transmission or ATR light paths. The versatility of the high-pressure IR titration system was demonstrated with three case studies. First, we titrated water into supercritical CO{sub 2} (scCO{sub 2}) to generate an infrared calibration curve and determine the solubility of water in CO{sub 2} at 50?C and 90 bar. Next, we characterized the partitioning of water between a montmorillonite clay and scCO{sub 2} at 50?C and 90 bar. Transmission-mode spectra were used to quantify changes in the clay's sorbed water concentration as a function of scCO{sub 2} hydration, and ATR measurements provided insights into competitive residency of water and CO{sub 2} on the clay surface and in the interlayer. Finally, we demonstrated how time-dependent studies can be conducted with the system by monitoring the carbonation reaction of forsterite (Mg{sub 2}SiO{sub 4}) in water-bearing scCO{sub 2} at 50?C and 90 bar. Immediately after water dissolved in the scCO{sub 2}, a thin film of adsorbed water formed on the mineral surface, and the film thickness increased with time as the forsterite began to dissolve. However, after approximately 2.5 h, the trend reversed, and a carbonate precipitate began to form on the forsterite surface, exposing dramatic chemical changes in the thin-water film. Collectively, these applications illustrate how the high-pressure IR titration system can provide molecular-level information about the interactions between variably wet scCO{sub 2} and minerals relevant to underground storage of CO{sub 2} (geologic carbon sequestration). The apparatus could also be utilized to study high-pressure interfacial chemistry in other areas such as catalysis, polymerization, food processing, and oil and gas recovery.

  14. Steam Plant, 6% Irrigation,

    E-Print Network [OSTI]

    Zhou, Pei

    Steam Plant, 6% School of Medicine, 17% Irrigation, 3% Hospital, 22% Athletics, 2% Housing, 5 Rainwater Cisterns Reducing the number of once through cooling systems in labs Expediting the connection for Irrigation ~15 million gallons Percent of Water Used for Irrigation that is Non-Potable ~10-15% Number

  15. Line broadening studies on highly defective TiO/sub 2/ produced by high pressure shock loading

    SciTech Connect (OSTI)

    Morosin, B.; Graeber, E.J.; Graham, R.A.

    1983-01-01T23:59:59.000Z

    Enhanced solid state reactivity of materials both during and after shock compression has been attributed to the introduction of large numbers of defects into the crystalline lattices and to reduction in the particle and crystalline size of powders. In particular, orders of magnitude increases in the catalytic activity has been observed in shock-modified TiO/sub 2/. Line broadening of x-ray diffraction profiles provides a means to determine the coherent crystallite size and the residual lattice strain resulting from defect concentrations. The present study on shock-loaded rutile is a detailed investigation of the influence of shock loading on residual lattice strain and coherent crystallite size. Annealing of shock-modified rutile powders is also studied.

  16. Propellant actuated nuclear reactor steam depressurization valve

    DOE Patents [OSTI]

    Ehrke, Alan C. (San Jose, CA); Knepp, John B. (San Jose, CA); Skoda, George I. (Santa Clara, CA)

    1992-01-01T23:59:59.000Z

    A nuclear fission reactor combined with a propellant actuated depressurization and/or water injection valve is disclosed. The depressurization valve releases pressure from a water cooled, steam producing nuclear reactor when required to insure the safety of the reactor. Depressurization of the reactor pressure vessel enables gravity feeding of supplementary coolant water through the water injection valve to the reactor pressure vessel to prevent damage to the fuel core.

  17. Phase transition and metallization of FeO at high pressures and temperatures

    SciTech Connect (OSTI)

    Fischer, Rebecca A.; Campbell, Andrew J.; Lord, Oliver T.; Shofner, Gregory A.; Dera, Przemyslaw; Prakapenka, Vitali B. (Maryland); (UC); (UCL)

    2012-05-10T23:59:59.000Z

    Wuestite, Fe{sub 1-x}O, is an important component in the mineralogy of Earth's lower mantle and may also be a component of the core. Therefore its high pressure-temperature behavior, including its electronic structure, is essential to understanding the nature and evolution of Earth's deep interior. We performed X-ray diffraction and radiometric measurements on wuestite in a laser-heated diamond anvil cell, finding an insulator-metal transition at high pressures and temperatures. Our data show a negative slope for this apparently isostructural phase boundary, which is characterized by a volume decrease and emissivity increase. The metallic phase of FeO is stable at conditions of the lower mantle and core, which has implications for the high P-T character of Fe-O bonds, magnetic field propagation, and lower mantle conductivity.

  18. Systematic prediction of high-pressure melting curves of transition metals

    SciTech Connect (OSTI)

    Hieu, Ho Khac, E-mail: hieuhk@duytan.edu.vn [Institute of Research and Development, Duy Tan University, K7/25 Quang Trung, Danang (Viet Nam)

    2014-10-28T23:59:59.000Z

    The pressure effects on melting temperatures of transition metals have been studied based on the combination of the modified Lindemann criterion with statistical moment method in quantum statistical mechanics. Numerical calculations have been performed for five transition metals including Cu, Pd, Pt, Ni, and Mn up to pressure 100?GPa. Our results are in good and reasonable agreements with available experimental data. This approach gives us a relatively simple method for qualitatively calculating high-pressure melting temperature. Moreover, it can be used to verify future experimental and theoretical works. This research proposes the potential of the combination of statistical moment method and the modified Lindemann criterion on predicting high-pressure melting of materials.

  19. The NEXT experiment: A high pressure xenon gas TPC for neutrinoless double beta decay searches

    E-Print Network [OSTI]

    D. Lorca; J. Martn-Albo; F. Monrabal; for the NEXT Collaboration

    2012-10-15T23:59:59.000Z

    Neutrinoless double beta decay is a hypothetical, very slow nuclear transition in which two neutrons undergo beta decay simultaneously and without the emission of neutrinos. The importance of this process goes beyond its intrinsic interest: an unambiguous observation would establish a Majorana nature for the neutrino and prove the violation of lepton number. NEXT is a new experiment to search for neutrinoless double beta decay using a radiopure high-pressure xenon gas TPC, filled with 100 kg of Xe enriched in Xe-136. NEXT will be the first large high-pressure gas TPC to use electroluminescence readout with SOFT (Separated, Optimized FuncTions) technology. The design consists in asymmetric TPC, with photomultipliers behind a transparent cathode and position-sensitive light pixels behind the anode. The experiment is approved to start data taking at the Laboratorio Subterr\\'aneo de Canfranc (LSC), Spain, in 2014.

  20. Natural gas-assisted steam electrolyzer

    DOE Patents [OSTI]

    Pham, Ai-Quoc (San Jose, CA); Wallman, P. Henrik (Berkeley, CA); Glass, Robert S. (Livermore, CA)

    2000-01-01T23:59:59.000Z

    An efficient method of producing hydrogen by high temperature steam electrolysis that will lower the electricity consumption to an estimated 65 percent lower than has been achievable with previous steam electrolyzer systems. This is accomplished with a natural gas-assisted steam electrolyzer, which significantly reduces the electricity consumption. Since this natural gas-assisted steam electrolyzer replaces one unit of electrical energy by one unit of energy content in natural gas at one-quarter the cost, the hydrogen production cost will be significantly reduced. Also, it is possible to vary the ratio between the electricity and the natural gas supplied to the system in response to fluctuations in relative prices for these two energy sources. In one approach an appropriate catalyst on the anode side of the electrolyzer will promote the partial oxidation of natural gas to CO and hydrogen, called Syn-Gas, and the CO can also be shifted to CO.sub.2 to give additional hydrogen. In another approach the natural gas is used in the anode side of the electrolyzer to burn out the oxygen resulting from electrolysis, thus reducing or eliminating the potential difference across the electrolyzer membrane.

  1. Gas turbine row #1 steam cooled vane

    DOE Patents [OSTI]

    Cunha, Frank J. (Longwood, FL)

    2000-01-01T23:59:59.000Z

    A design for a vane segment having a closed-loop steam cooling system is provided. The vane segment comprises an outer shroud, an inner shroud and an airfoil, each component having a target surface on the inside surface of its walls. A plurality of rectangular waffle structures are provided on the target surface to enhance heat transfer between each component and cooling steam. Channel systems are provided in the shrouds to improve the flow of steam through the shrouds. Insert legs located in cavities in the airfoil are also provided. Each insert leg comprises outer channels located on a perimeter of the leg, each outer channel having an outer wall and impingement holes on the outer wall for producing impingement jets of cooling steam to contact the airfoil's target surface. Each insert leg further comprises a plurality of substantially rectangular-shaped ribs located on the outer wall and a plurality of openings located between outer channels of the leg to minimize cross flow degradation.

  2. Task 1Steam Oxidation (NETL-US)

    SciTech Connect (OSTI)

    G. R. Holcomb

    2010-05-01T23:59:59.000Z

    The proposed steam in let temperature in the Advanced Ultra Supercritical (AUSC) steam turbine is high enough (760C) Ihat traditional turbine casing and valve body materials such as ferr;tic/manensitic steels will not suffice due to temperature lim itations of this class of materials. Cast versions of three traditionally wrought Ni-based superalloys (Haynes 263. Haynes 282, and Nimonic 105) were evaluated for use as casing or valve components for the next generation of industrial steam turbines. The full size castings are substantia l: 2-5,000 kg each half and on the order of 100 nun thick. Experimental castings were quite a bit smaller, but section size was retained and cooling rate controlled to produce equi valem microslruclUre . A multi_step homogenization heat treatment was d~ve loped to better disperse the al loy constituents. These castings were subsequently evaluated by characterizing their microstructure as well as their steam oxidation resistance (al 760 and 800 "C).

  3. Transition in the deformation mode of nanocrystalline tantalum processed by high-pressure torsion

    SciTech Connect (OSTI)

    Ligda, J.P.; Schuster, B.E.; Wei, Q. (UNC)

    2012-10-11T23:59:59.000Z

    We present quasi-static room temperature compression and nanoindentation data for nanocrystalline and ultrafine grained tantalum processed by high-pressure torsion. Because bulk samples possess an inherent gradient in properties, microstructures were characterized using site-specific transmission electron microscopy and synchrotron X-ray diffraction. Nanocrystalline Ta shows appreciable homogeneous plastic deformation in compression; however, specimens with the smallest grain sizes exhibit localized plastic deformation via shear bands. Microstructural changes associated with this transition in deformation mode are discussed.

  4. Pb nanowire formation on Al/lead zirconate titanate surfaces in high-pressure hydrogen

    SciTech Connect (OSTI)

    Alvine, Kyle J.; Shutthanandan, V.; Arey, Bruce W.; Wang, Chong M.; Bennett, Wendy D.; Pitman, Stan G.

    2012-07-12T23:59:59.000Z

    Thin films of Al on lead zirconate titanate (PZT) annealed in high-pressure hydrogen at 100C exhibit surface Pb nanowire growth. Wire diameter is approximately 80 nm and length can exceed 100 microns. Based on microstructural analysis using electron microscopy and ion scattering, a vapor-solid scheme with hydrogen as a carrier gas was proposed as a growth mechanism. We expect that these observations may lead to controlled Pb nanowires growth through pattering of the Al film.

  5. Rotor Design for High Pressure Magic Angle Spinning Nuclear Magnetic Resonance

    SciTech Connect (OSTI)

    Turcu, Romulus V.F.; Hoyt, David W.; Rosso, Kevin M.; Sears, Jesse A.; Loring, John S.; Felmy, Andrew R.; Hu, Jian Z.

    2013-01-01T23:59:59.000Z

    High pressure magic angle spinning (MAS) nuclear magnetic resonance (NMR) with a sample spinning rate exceeding 2.1 kHz and pressure greater than 165 bar has never been realized. In this work, a new sample cell design is reported, suitable for constructing cells of different sizes. Using a 7.5 mm high pressure MAS rotor as an example, internal pressure as high as 200 bar at a sample spinning rate of 6 kHz is achieved. The new high pressure MAS rotor is re-usable and compatible with most commercial NMR set-ups, exhibiting low 1H and 13C NMR background and offering maximal NMR sensitivity. As an example of its many possible applications, this new capability is applied to determine reaction products associated with the carbonation reaction of a natural mineral, antigorite ((Mg,Fe2+)3Si2O5(OH)4), in contact with liquid water in water-saturated supercritical CO2 (scCO2) at 150 bar and 50 deg C. This mineral is relevant to the deep geologic disposal of CO2, but its iron content results in too many sample spinning sidebands at low spinning rate. Hence, this chemical system is a good case study to demonstrate the utility of the higher sample spinning rates that can be achieved by our new rotor design. We expect this new capability will be useful for exploring solid-state, including interfacial, chemistry at new levels of high-pressure in a wide variety of fields.

  6. Engine having hydraulic and fan drive systems using a single high pressure pump

    DOE Patents [OSTI]

    Bartley, Bradley E. (Manito, IL); Blass, James R. (Bloomington, IL); Gibson, Dennis H. (Chillicothe, IL)

    2000-01-01T23:59:59.000Z

    An engine comprises a hydraulic system attached to an engine housing that includes a high pressure pump and a hydraulic fluid flowing through at least one passageway. A fan drive system is also attached to the engine housing and includes a hydraulic motor and a fan which can move air over the engine. The hydraulic motor includes an inlet fluidly connected to the at least one passageway.

  7. Pressure Relief Devices for High-Pressure Gaseous Storage Systems: Applicability to Hydrogen Technology

    SciTech Connect (OSTI)

    Kostival, A.; Rivkin, C.; Buttner, W.; Burgess, R.

    2013-11-01T23:59:59.000Z

    Pressure relief devices (PRDs) are viewed as essential safety measures for high-pressure gas storage and distribution systems. These devices are used to prevent the over-pressurization of gas storage vessels and distribution equipment, except in the application of certain toxic gases. PRDs play a critical role in the implementation of most high-pressure gas storage systems and anyone working with these devices should understand their function so they can be designed, installed, and maintained properly to prevent any potentially dangerous or fatal incidents. As such, the intention of this report is to introduce the reader to the function of the common types of PRDs currently used in industry. Since high-pressure hydrogen gas storage systems are being developed to support the growing hydrogen energy infrastructure, several recent failure incidents, specifically involving hydrogen, will be examined to demonstrate the results and possible mechanisms of a device failure. The applicable codes and standards, developed to minimize the risk of failure for PRDs, will also be reviewed. Finally, because PRDs are a critical component for the development of a successful hydrogen energy infrastructure, important considerations for pressure relief devices applied in a hydrogen gas environment will be explored.

  8. Effect of high pressure homogenization on aqueous phase solvent extraction of lipids from Nannochloris Oculata microalgae

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Samarasinghe, Nalin; Fernando, Sandun; Faulkner, William B.

    2012-01-01T23:59:59.000Z

    The ability to extract lipids from high-moisture Nannochloris Oculata algal biomass disrupted with high pressure homogenization was investigated. During the first phase, the effect of high pressure homogenization (system pressure and number of passes) on disrupting aqueous algae (of different concentrations and degree of stress) was investigated. Secondly, the effect of degree of cell wall disruption on the amount of lipids extracted with three solvents, namely: hexane, dichloromethane and chloroform, were compared. Studies reveled that high pressure homogenization is effective on cell disruption while the amount of system pressure being the most significant factor affecting the degree of cell breakage.moreAlthough the number of passes had some impact, the level of disruption seemed to level-off after a certain number of passes. The study revealed that slightly polar solvents (such as chloroform and dichloromethane) performed better in aqueous-phase lipid extractions as compared to hexane. Also, it was revealed that it was not necessary to disrupt the algal cells completely to achieve appreciable levels of lipid yields. In fact, conditions that exerted only 20% of the cells to completely disrupt, allowed sufficient damage to liberate most of the lipids contained in the remainder of the cells.less

  9. Comparison of diesel spray combustion in different high-temperature, high-pressure facilities.

    SciTech Connect (OSTI)

    Christiansen, Caspar (Technical University of Denmark); Hermant, Laurent (IFP); Malbec, Louis-Marie (IFP); Bruneaux, Gilles (IFP); Genzale, Caroline L.; Pickett, Lyle M.; Schramm, Jesper (Technical University of Denmark)

    2010-05-01T23:59:59.000Z

    Diesel spray experiments at controlled high-temperature and high-pressure conditions offer the potential for an improved understanding of diesel combustion, and for the development of more accurate CFD models that will ultimately be used to improve engine design. Several spray chamber facilities capable of high-temperature, high-pressure conditions typical of engine combustion have been developed, but uncertainties about their operation exist because of the uniqueness of each facility. For the IMEM meeting, we describe results from comparative studies using constant-volume vessels at Sandia National Laboratories and IFP. Targeting the same ambient gas conditions (900 K, 60 bar, 22.8 kg/m{sup 3}, 15% oxygen) and sharing the same injector (common rail, 1500 bar, KS1.5/86 nozzle, 0.090 mm orifice diameter, n-dodecane, 363 K), we describe detailed measurements of the temperature and pressure boundary conditions at each facility, followed by observations of spray penetration, ignition, and combustion using high-speed imaging. Performing experiments at the same high-temperature, high-pressure operating conditions is an objective of the Engine Combustion Network (http://www.ca.sandia.gov/ECN/), which seeks to leverage the research capabilities and advanced diagnostics of all participants in the ECN. We expect that this effort will generate a high-quality dataset to be used for advanced computational model development at engine conditions.

  10. Effect of high pressure homogenization on aqueous phase solvent extraction of lipids from Nannochloris Oculata microalgae

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Samarasinghe, Nalin [Texas A & M Univ., College Station, TX (United States). Dept. of Biological and Agricultural Engineering; Fernando, Sandun [Texas A & M Univ., College Station, TX (United States). Dept. of Biological and Agricultural Engineering; Faulkner, William B. [Texas A & M Univ., College Station, TX (United States). Dept. of Biological and Agricultural Engineering

    2012-01-01T23:59:59.000Z

    The ability to extract lipids from high-moisture Nannochloris Oculata algal biomass disrupted with high pressure homogenization was investigated. During the first phase, the effect of high pressure homogenization (system pressure and number of passes) on disrupting aqueous algae (of different concentrations and degree of stress) was investigated. Secondly, the effect of degree of cell wall disruption on the amount of lipids extracted with three solvents, namely: hexane, dichloromethane and chloroform, were compared. Studies reveled that high pressure homogenization is effective on cell disruption while the amount of system pressure being the most significant factor affecting the degree of cell breakage. Although the number of passes had some impact, the level of disruption seemed to level-off after a certain number of passes. The study revealed that slightly polar solvents (such as chloroform and dichloromethane) performed better in aqueous-phase lipid extractions as compared to hexane. Also, it was revealed that it was not necessary to disrupt the algal cells completely to achieve appreciable levels of lipid yields. In fact, conditions that exerted only 20% of the cells to completely disrupt, allowed sufficient damage to liberate most of the lipids contained in the remainder of the cells.

  11. Equations of state of ice VI and ice VII at high pressure and high temperature

    SciTech Connect (OSTI)

    Bezacier, Lucile; Hanfland, Michael [European Synchrotron Radiation Facility, 6 rue Jules Horowitz, 38000 Grenoble (France); Journaux, Baptiste; Perrillat, Jean-Philippe; Cardon, Herv; Daniel, Isabelle [Laboratoire de Gologie de Lyon, UMR 5276 CNRS, Ecole Normale Suprieure de Lyon Universit Claude Bernard Lyon 1, 2 rue Raphael Dubois, 69622 Villeurbanne Cedex (France)

    2014-09-14T23:59:59.000Z

    High-pressure H{sub 2}O polymorphs among which ice VI and ice VII are abundant in the interiors of large icy satellites and exo-planets. Knowledge of the elastic properties of these pure H{sub 2}O ices at high-temperature and high-pressure is thus crucial to decipher the internal structure of icy bodies. In this study we assess for the first time the pressure-volume-temperature (PVT) relations of both polycrystalline pure ice VI and ice VII at high pressures and temperatures from 1 to 9 GPa and 300 to 450 K, respectively, by using in situ synchrotron X-ray diffraction. The PVT data are adjusted to a second-order Birch-Murnaghan equation of state and give V{sub 0} = 14.17(2) cm{sup 3}?mol{sup ?1}, K{sub 0} = 14.05(23) GPa, and ?{sub 0} = 14.6(14) 10{sup ?5} K{sup ?1} for ice VI and V{sub 0} = 12.49(1) cm{sup 3}?mol{sup ?1}, K{sub 0} = 20.15(16) GPa, and ?{sub 0} = 11.6(5) 10{sup ?5} K{sup ?1} for ice VII.

  12. High-pressure powder x-ray diffraction study of EuVO4

    E-Print Network [OSTI]

    Garg, Alka B

    2015-01-01T23:59:59.000Z

    The high-pressure structural behavior of europium orthovanadate has been studied using in-situ, synchrotron based, high-pressure x-ray powder diffraction technique. Angle-dispersive x-ray diffraction measurements were carried out at room temperature up to 34.7 GPa using a diamond-anvil cell, extending the pressure range reported in previous experiments. We confirmed the occurrence of zircon-scheelite phase transition at 6.8 GPa and the coexistence of low- and high-pressure phases up to 10.1 GPa. In addition, clear evidence of a scheelite-fregusonite transition is found at 23.4 GPa. The fergusonite structure remains stable up to 34.7 GPa, the highest pressure reached in the present measurements. A partial decomposition of EuVO4 was also observed from 8.1 to 12.8 GPa, however, this fact did not preclude the identification of the different crystal structures of EuVO4. The crystal structures of the different phases have been Rietveld refined and their equations of state (EOS) have been determined. The results are...

  13. Development of Designer Diamond Technology for High Pressure High Temperature Experiments in Support of Stockpile Stewardship Program

    SciTech Connect (OSTI)

    Vohra, Yogesh, K.

    2009-10-28T23:59:59.000Z

    The role of nitrogen in the fabrication of designer diamond was systematically investigated by adding controlled amount of nitrogen in hydrogen/methane/oxygen plasma. This has led to a successful recipe for reproducible fabrication of designer diamond anvils for high-pressure high-temperature research in support of stockpile stewardship program. In the three-year support period, several designer diamonds fabricated with this new growth chemistry were utilized in high-pressure experiments at UAB and Lawrence Livermore National Laboratory. The designer diamond anvils were utilized in high-pressure studies on heavy rare earth metals, high pressure melting studies on metals, and electrical resistance measurements on iron-based layered superconductors under high pressures. The growth chemistry developed under NNSA support can be adapted for commercial production of designer diamonds.

  14. Produce syngas for methanol

    SciTech Connect (OSTI)

    Farina, G.L. (Foster Wheeler International Corp., Milan (IT))

    1992-03-01T23:59:59.000Z

    Combined reforming, in which an oxygen reforming reactor is added downstream from a conventional tubular reactor to produce syngas for methanol, achieves a substantial reduction in energy consumption with the least impact on the environment. This paper reports that the advantages of this process scheme are as follows: 8% to 10% reduction in the consumption of natural gas per ton of methanol, The size of the primary reformer is reduced, Reduction of syngas compression requirement due to increased syngas pressure, Reduced steam consumption, Production of syngas with the stoichiometric composition required by methanol synthesis. Synthesis gases for the production of methanol and synfuels are basically mixtures of hydrogen and carbon oxides. They have been produced from natural gas by steam reforming, autothermal reforming and noncatalytic partial oxidation.

  15. X-ray-induced dissociation of H.sub.2O and formation of an O.sub.2-H.sub.2 alloy at high pressure

    DOE Patents [OSTI]

    Mao, Ho-kwang (Washington, DC); Mao, Wendy L. (Washington, DC)

    2011-11-29T23:59:59.000Z

    A novel molecular alloy of O.sub.2 and H.sub.2 and a method of producing such a molecular alloy are provided. When subjected to high pressure and extensive x-radiation, H.sub.2O molecules cleaved, forming O--O and H--H bonds. In the method of the present invention, the O and H framework in ice VII was converted into a molecular alloy of O.sub.2 and H.sub.2. X-ray diffraction, x-ray Raman scattering, and optical Raman spectroscopy demonstrate that this crystalline solid differs from previously known phases.

  16. Steam separator latch assembly

    DOE Patents [OSTI]

    Challberg, R.C.; Kobsa, I.R.

    1994-02-01T23:59:59.000Z

    A latch assembly removably joins a steam separator assembly to a support flange disposed at a top end of a tubular shroud in a nuclear reactor pressure vessel. The assembly includes an annular head having a central portion for supporting the steam separator assembly thereon, and an annular head flange extending around a perimeter thereof for supporting the head to the support flange. A plurality of latches are circumferentially spaced apart around the head flange with each latch having a top end, a latch hook at a bottom end thereof, and a pivot support disposed at an intermediate portion therebetween and pivotally joined to the head flange. The latches are pivoted about the pivot supports for selectively engaging and disengaging the latch hooks with the support flange for fixedly joining the head to the shroud or for allowing removal thereof. 12 figures.

  17. Steam separator latch assembly

    DOE Patents [OSTI]

    Challberg, Roy C. (Livermore, CA); Kobsa, Irvin R. (San Jose, CA)

    1994-01-01T23:59:59.000Z

    A latch assembly removably joins a steam separator assembly to a support flange disposed at a top end of a tubular shroud in a nuclear reactor pressure vessel. The assembly includes an annular head having a central portion for supporting the steam separator assembly thereon, and an annular head flange extending around a perimeter thereof for supporting the head to the support flange. A plurality of latches are circumferentially spaced apart around the head flange with each latch having a top end, a latch hook at a bottom end thereof, and a pivot support disposed at an intermediate portion therebetween and pivotally joined to the head flange. The latches are pivoted about the pivot supports for selectively engaging and disengaging the latch hooks with the support flange for fixedly joining the head to the shroud or for allowing removal thereof.

  18. Steam Trap Application

    E-Print Network [OSTI]

    Murphy, J. J.

    1982-01-01T23:59:59.000Z

    Equipment Collecting leg, same size as equip ment connection but not less than Install a Yarway Process Trap below be drained. Install a Provide vacuum strainer with a blow down valve. Use and Yarway Aldrain valves full ported stop valves, (gate... and Corrosion Problems Like any critical control device the steam trap should be protected from dirt and scale if optimum operation and adequate service life are to be attained. Strainers should be equipped with blowdown valves to provide an effective...

  19. Steam Power Partnership: Improving Steam System Efficiency Through Marketplace Partnerships

    E-Print Network [OSTI]

    Jones, T.

    1997-01-01T23:59:59.000Z

    been great advances in boiler control technology as older pneumatic and analog electronic control systems have given way to digital, computer-based distributed control systems. These systems are more reliable and can extend boiler life. Modem... Several software tools are now available for individual steam technologies, such as steam traps, insulation, and boiler controls. The Partnership should investigate linking these software tools together and incorporating other steam "modules" (i...

  20. Chemical Processing in High-Pressure Aqueous Environments. 7. Process Development for Catalytic Gasification of Wet Biomass Feedstocks

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.; Butner, Scott S.; Zacher, Alan H.; Engelhard, Mark H.; Young, James S.; McCready, David E.

    2004-07-01T23:59:59.000Z

    Through the use of a metal catalyst, gasification of wet biomass can be accomplished with high levels of carbon conversion to gas at relatively low temperature (350 C). In the pressurized-water environment (20 MPa) near-total conversion of the organic structure of biomass to gases has been accomplished in the presence of a ruthenium metal catalyst. The process is essentially steam reforming as there is no added oxidizer or reagent other than water. In addition, the gas produced is a medium-heating value gas due to the synthesis of high-levels of methane, as dictated by thermodynamic equilibrium. Biomass trace components cause processing difficulties using the fixed catalyst bed tubular reactor system. Results are described for both bench-scale and scaled-up reactor systems.

  1. Steam Pressure Reduction: Opportunities and Issues; A BestPractices Steam Technical Brief

    SciTech Connect (OSTI)

    Not Available

    2005-11-01T23:59:59.000Z

    A BestPractices Technical Brief describing industrial steam generation systems and opportunities for reducing steam system operating pressure.

  2. Constant-Pressure Measurement of Steam-

    E-Print Network [OSTI]

    Stanford University

    SGP-TR-169 Constant-Pressure Measurement of Steam- Water Relative Permeability Peter A. O by measuring in-situ steam saturation more directly. Mobile steam mass fraction was established by separate steam and water inlets or by correlating with previous results. The measured steam-water relative

  3. Steam condensate leakage

    SciTech Connect (OSTI)

    Midlock, E.B.; Thuot, J.R.

    1996-07-01T23:59:59.000Z

    Argonne National Laboratory (ANL) is a multi-program research and development center owned by the United States Department of Energy and operated by the University of Chicago. The majority of the buildings on site use steam for heating and other purposes. Steam is generated from liquid water at the site`s central boiler house and distributed around the site by means of large pipes both above and below the ground. Steam comes into each building where it is converted to liquid condensate, giving off heat which can be used by the building. The condensate is then pumped back to the boiler house where it will be reheated to steam again. The process is continual but is not perfectly efficient. A substantial amount of condensate is being lost somewhere on site. The lost condensate has both economic and environmental significance. To compensate for lost condensate, makeup water must be added to the returned condensate at the boiler house. The water cost itself will become significant in the future when ANL begins purchasing Lake Michigan water. In addition to the water cost, there is also the cost of chemically treating the water to remove impurities, and there is the cost of energy required to heat the water, as it enters the boiler house 1000 F colder than the condensate return. It has been estimated that only approximately 60% of ANL`s steam is being returned as condensate, thus 40% is being wasted. This is quite costly to ANL and will become significantly more costly in the future when ANL begins purchasing water from Lake Michigan. This study locates where condensate loss is occurring and shows how much money would be saved by repairing the areas of loss. Shortly after completion of the study, one of the major areas of loss was repaired. This paper discusses the basis for the study, the areas where losses are occurring, the potential savings of repairing the losses, and a hypothesis as to where the unaccounted for loss is occurring.

  4. Flash High-Pressure Condensate to Regenerate Low-Pressure Steam, Energy Tips: STEAM, Steam Tip Sheet #12 (Fact Sheet), Advanced Manufacturing Office (AMO), Energy Efficiency & Renewable Energy (EERE)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport inEnergy June 6-7, 2013 MeetingEA #FebruaryFisker, Tesla,FixedFlash 2011-592

  5. Process for purifying geothermal steam

    DOE Patents [OSTI]

    Li, Charles T. (Richland, WA)

    1980-01-01T23:59:59.000Z

    Steam containing hydrogen sulfide is purified and sulfur recovered by passing the steam through a reactor packed with activated carbon in the presence of a stoichiometric amount of oxygen which oxidizes the hydrogen sulfide to elemental sulfur which is adsorbed on the bed. The carbon can be recycled after the sulfur has been recovered by vacuum distillation, inert gas entrainment or solvent extraction. The process is suitable for the purification of steam from geothermal sources which may also contain other noncondensable gases.

  6. DOE's BestPractices Steam End User Training Steam End User Training

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    DOE's BestPractices Steam End User Training Steam End User Training Steam Generation Efficiency Module Efficiency Definition - 1 8/30/2010 Steam End-User Training Steam Generation Efficiency Module will be discussed. [Slide Visual Contents of Module Sections] Banner: DOE's BestPractices Steam End User Training

  7. DOE's BestPractices Steam End-User Training Steam End User Training

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    DOE's BestPractices Steam End-User Training Steam End User Training Steam Generation Module Stack Losses 1 June 28, 2010 Steam EndUser Training Steam Generation Efficiency Module Stack Losses loss is almost always the largest boiler loss. [Slide Visual ­ Stack Loss Title Page] Steam

  8. Plasma etching of cavities into diamond anvils for experiments at high pressures and high temperatures

    SciTech Connect (OSTI)

    Weir, S.T.; Cynn, H.; Falabella, S.; Evans, W.J.; Aracne-Ruddle, C.; Farber, D.; Vohra, Y.K. (LLNL); (UAB)

    2012-10-23T23:59:59.000Z

    We describe a method for precisely etching small cavities into the culets of diamond anvils for the purpose of providing thermal insulation for samples in experiments at high pressures and high temperatures. The cavities were fabricated using highly directional oxygen plasma to reactively etch into the diamond surface. The lateral extent of the etch was precisely controlled to micron accuracy by etching the diamond through a lithographically fabricated tungsten mask. The performance of the etched cavities in high-temperature experiments in which the samples were either laser heated or electrically heated is discussed.

  9. A field-deployable gamma-ray spectrometer utilizing xenon at high pressure

    SciTech Connect (OSTI)

    Smith, G.C.; Mahler, G.J.; Yu, B.; Salwen, C.; Kane, W.R.; Lemley, J.R.

    1996-10-01T23:59:59.000Z

    Prototype gamma-ray spectrometers utilizing xenon gas at high pressure, suitable for applications in the nuclear safeguards, arms control, and nonproliferation communities, have been developed at Brookhaven National Laboratory (BNL). These spectrometers function as ambient-temperature ionization chambers detecting gamma rays with good efficiency in the energy range 50 keV - 2 MeV, with an energy resolution intermediate between semiconductor (Ge) and scintillation (NaI) spectrometers. They are capable of prolonged, low-power operation without a requirement for cryogenic fluids or other cooling mechanisms, and with the addition of small quantities of {sup 3}He gas, can function simultaneously as efficient thermal neutron detectors.

  10. Stability analysis and testing of a train of centrifugal compressors for high pressure gas injection

    SciTech Connect (OSTI)

    Memmott, E.A. [Dresser-Rand Co., Olean, NY (United States)

    1999-07-01T23:59:59.000Z

    This paper describes the rotor dynamic stability analysis and the PTC-10 Class 1 test of a three body centrifugal compressor train for high pressure natural gas injection services. This train had a full load full pressure string test on hydrocarbon gases to a final discharge pressure of 500 BAR (7250 PSIA). Each compressor is of the back to back configuration, and is equipped with tilting pad seals, damper bearings, and a honeycomb labyrinth at the division wall with shunt holes. The driver is a gas turbine.

  11. Energy distribution and computer modeled nozzle design in high pressure water jet coating removal

    SciTech Connect (OSTI)

    Blades, B. [Hobart Tafa Technologies Inc., Concord, NH (United States)

    1994-12-31T23:59:59.000Z

    Wider acceptance of water jet coating removal as an industrial process has created a demand to better understand the physical phenomena occurring during coating removal. This demand stems from both technical and process control concerns. Research on behavior of coating removal nozzles and high pressure jets in general provide the basis for the development of a mathematical model of rotating nozzle. The model finds uses in both process development and new equipment design. Data confirming the validity of the model has been generated and the need for further refinement of the model has been noted.

  12. High Pressure X-ray Diffraction Study on Icosahedral Boron Arsenide (B12As2)

    SciTech Connect (OSTI)

    J Wu; H Zhu; D Hou; C Ji; C Whiteley; J Edgar; Y Ma

    2011-12-31T23:59:59.000Z

    The high pressure properties of icosahedral boron arsenide (B12As2) were studied by in situ X-ray diffraction measurements at pressures up to 25.5 GPa at room temperature. B12As2 retains its rhombohedral structure; no phase transition was observed in the pressure range. The bulk modulus was determined to be 216 GPa with the pressure derivative 2.2. Anisotropy was observed in the compressibility of B12As2-c-axis was 16.2% more compressible than a-axis. The boron icosahedron plays a dominant role in the compressibility of boron-rich compounds.

  13. Structural changes in nano-crystalline mackinawite (FeS) at high - pressure.

    SciTech Connect (OSTI)

    Ehm, L.; Michael, F. M.; Antao, S. M.; Martin, C. D.; Lee, P. L.; Shastri, S. D.; Chupas, P. J.; Parise, J. B.; Stony Brook Univ.

    2009-02-01T23:59:59.000Z

    The high-pressure behavior of nanocrystalline mackinawite (FeS) with particle sizes of 6, 7 and 8 nm has been investigated by high-energy X-ray total scattering and pair distribution function analysis. An irreversible first-order structural phase transition from tetragonal mackinawite to orthorhombic FeS-II was observed at about 3 GPa. The transition is induced by the closure of the van der Waals gap in the layered mackinawite structure. A grain size effect on the transition pressure and the compressibility was observed.

  14. Innovative high pressure gas MEM's based neutron detector for ICF and active SNM detection.

    SciTech Connect (OSTI)

    Martin, Shawn Bryan; Derzon, Mark Steven; Renzi, Ronald F.; Chandler, Gordon Andrew

    2007-12-01T23:59:59.000Z

    An innovative helium3 high pressure gas detection system, made possible by utilizing Sandia's expertise in Micro-electrical Mechanical fluidic systems, is proposed which appears to have many beneficial performance characteristics with regards to making these neutron measurements in the high bremsstrahlung and electrical noise environments found in High Energy Density Physics experiments and especially on the very high noise environment generated on the fast pulsed power experiments performed here at Sandia. This same system may dramatically improve active WMD and contraband detection as well when employed with ultrafast (10-50 ns) pulsed neutron sources.

  15. Inside Ice Under High Pressure | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurTheBrookhaven National LaboratoryJeffrey L80'sInside Ice Under High Pressure

  16. Steam System Improvement: A Case Study

    E-Print Network [OSTI]

    Venkatesan, V. V.; Leigh, N.

    . For industries, this will result in the reduction of production cost. In industry where steam is utilized, the steam production and distribution system consumes a significant portion of energy. Therefore, optimization of steam system is among the biggest energy...

  17. Why Condensing Steam Turbines are More Efficient than Gas Turbines

    E-Print Network [OSTI]

    Nelson, K. E.

    statement. however, is relevant to value. GAS TURBINE CYCLE Figure :> shows the enthalpy analysis for a gas turbine cycle employing a heat recovery unit for steam generation. Air enters the compressor where it's boosted to about 190 psi and mixed... of preheaters. boilers and superheaters. [n this example. three levels of steam are produced. Exhaust gases vent up the stack. :1 l.:l MMBtu/hr of electricity is produced. with 70.4"'0 of the heat going to the heat recovery unit. Notice that 22...

  18. High performance steam development. Final report, Phase No. 3: 1500{degree}F steam plant for industrial cogeneration prototype development tests

    SciTech Connect (OSTI)

    Duffy, T.; Schneider, P.

    1996-01-01T23:59:59.000Z

    As a key part of DOE`s and industry`s R&D efforts to improve the efficiency, cost, and emissions of power generation, a prototype High Performance Steam System (HPSS) has been designed, built, and demonstrated. The world`s highest temperature ASME Section I coded power plant successfully completed over 100 hours of development tests at 1500{degrees}F and 1500 psig on a 56,000 pound per hour steam generator, control valve and topping turbine at an output power of 5500 hp. This development advances the HPSS to 400{degrees}F higher steam temperature than the current best technology being installed around the world. Higher cycle temperatures produce higher conversion efficiencies and since steam is used to produce the large majority of the world`s power, the authors expect HPSS developments will have a major impact on electric power production and cogeneration in the twenty-first century. Coal fueled steam plants now produce the majority of the United States electric power. Cogeneration and reduced costs and availability of natural gas have now made gas turbines using Heat Recovery Steam Generators (HRSG`s) and combined cycles for cogeneration and power generation the lowest cost producer of electric power in the United States. These gas fueled combined cycles also have major benefits in reducing emissions while reducing the cost of electricity. Development of HPSS technology can significantly improve the efficiency of cogeneration, steam plants, and combined cycles. Figure 2 is a TS diagram that shows the HPSS has twice the energy available from each pound of steam when expanding from 1500{degrees}F and 1500 psia to 165 psia (150 psig, a common cogeneration process steam pressure). This report describes the prototype component and system design, and results of the 100-hour laboratory tests. The next phase of the program consists of building up the steam turbine into a generator set, and installing the power plant at an industrial site for extended operation.

  19. Steam System Survey Guide

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOriginEducationVideo »UsageSecretaryVideosSpringoutAPBF-DEC NOxBestPractices SteamOffice of1/263

  20. Stages of destruction and elastic compression of granular nanoporous carbon medium at high pressures

    E-Print Network [OSTI]

    I. M. Neklyudov; O. P. Ledenyov; N. B. Bobrova; A. A. Chupikov

    2015-05-14T23:59:59.000Z

    The granular nanoporous carbon medium, made of the cylindrical coal granules of the adsorbent of SKT 3, at an influence by the high pressures from 1MPa to 3GPa has been researched. The eight consecutive stages of the materials specific volume change, which is characterized by a certain dependence of the volume change on the pressure change, have been registered. It is shown that there is a linear dependence on the double log log plot of the materials specific volume change on the pressure for an every stage of considered process. The two stages are clearly distinguished such as a stage of materials mechanical destruction, and a stage of elastic compression of material without the disintegration of structure at a nanscale. The hysteresis dependence of the materials specific volume change on the pressure change at the pressure decrease is observed. The small disperse coal dust particles jettisoning between the high pressure cell and the base plate was observed, resulting in the elastic stress reduction in relation to the small disperse coal dust particles volume. The obtained research data can be used to improve the designs of air filters for the radioactive chemical elements absorption at the NPP with the aims to protect the environment.

  1. Dark Matter Directionality Revisited with a High Pressure Xenon Gas Detector

    E-Print Network [OSTI]

    Gopolang Mohlabeng; Kyoungchul Kong; Jin Li; Adam Para; Jonghee Yoo

    2015-03-13T23:59:59.000Z

    An observation of the anisotropy of dark matter interactions in a direction-sensitive detector would provide decisive evidence for the discovery of galactic dark matter. Directional information would also provide a crucial input to understanding its distribution in the local Universe. Most of the existing directional dark matter detectors utilize particle tracking methods in a low-pressure gas time projection chamber. These low pressure detectors require excessively large volumes in order to be competitive in the search for physics beyond the current limit. In order to avoid these volume limitations, we consider a novel proposal, which exploits a columnar recombination effect in a high-pressure gas time projection chamber. The ratio of scintillation to ionization signals observed in the detector carries the angular information of the particle interactions. In this paper, we investigate the sensitivity of a future directional detector focused on the proposed high-pressure Xenon gas time projection chamber. We study the prospect of detecting an anisotropy in the dark matter velocity distribution. We find that tens of events are needed to exclude an isotropic distribution of dark matter interactions at 95% confidence level in the most optimistic case with head-to-tail information. However, one needs at least 10-20 times more events without head-to-tail information for light dark matter below 50 GeV or one between 200 GeV and 400 GeV. For an intermediate mass range, we find it challenging to observe anisotropy of dark matter distribution.

  2. Measurement and interpretation of threshold stress intensity factors for steels in high-pressure hydrogen gas.

    SciTech Connect (OSTI)

    Dadfarnia, Mohsen (University of Illinois at Urbana-Champaign, Urbana, IL); Nibur, Kevin A.; San Marchi, Christopher W.; Sofronis, Petros (University of Illinois at Urbana-Champaign, Urbana, IL); Somerday, Brian P.; Foulk, James W., III; Hayden, Gary A. (CP Industries, McKeesport, PA)

    2010-07-01T23:59:59.000Z

    Threshold stress intensity factors were measured in high-pressure hydrogen gas for a variety of low alloy ferritic steels using both constant crack opening displacement and rising crack opening displacement procedures. The sustained load cracking procedures are generally consistent with those in ASME Article KD-10 of Section VIII Division 3 of the Boiler and Pressure Vessel Code, which was recently published to guide design of high-pressure hydrogen vessels. Three definitions of threshold were established for the two test methods: K{sub THi}* is the maximum applied stress intensity factor for which no crack extension was observed under constant displacement; K{sub THa} is the stress intensity factor at the arrest position for a crack that extended under constant displacement; and K{sub JH} is the stress intensity factor at the onset of crack extension under rising displacement. The apparent crack initiation threshold under constant displacement, K{sub THi}*, and the crack arrest threshold, K{sub THa}, were both found to be non-conservative due to the hydrogen exposure and crack-tip deformation histories associated with typical procedures for sustained-load cracking tests under constant displacement. In contrast, K{sub JH}, which is measured under concurrent rising displacement and hydrogen gas exposure, provides a more conservative hydrogen-assisted fracture threshold that is relevant to structural components in which sub-critical crack extension is driven by internal hydrogen gas pressure.

  3. ORNL provided a feasibility evaluation of EPA's plans to route purchased steam

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    engines, microturbines, steam turbines, fuel cells CHP waste-heat-activated technologies -- generation3/23/09 ORNL provided a feasibility evaluation of EPA's plans to route purchased steam to produce projects. The team's expertise covers: CHP power generation technologies -- turbines, internal combustion

  4. ORNL provided a feasibility evaluation of EPA's plans to route purchased steam

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    engines, microturbines, steam turbines, fuel cells CHP waste-heat-activated technologies -- generation3/20/09 ORNL provided a feasibility evaluation of EPA's plans to route purchased steam to produce projects. The team's expertise covers: CHP power generation technologies -- turbines, internal combustion

  5. Steam Oxidation of Fossil Power Plant Materials: Collaborative Research to Enable Advanced Steam Power Cycles

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    A. T. Fry; I. G Wright; N. J Simms; B. McGhee; G. R. Holcomb

    2013-11-19T23:59:59.000Z

    Research into improved materials systems and associated manufacturing and reliability issues is a major part of initiatives to produce cleaner and cheaper energy systems in the UK and the USA. Under the auspices of a Memorandum of Understanding on Energy R&D, a work programme concerned with steam oxidation has been conducted. The focus was on the generation of definitive information regarding the oxidation behaviour in steam of current and developmental ferritic steels, austenitic steels, and nickelbased alloys required to enable advanced steam power cycles. The results were intended to provide a basis for quantifying the rate of metal loss expected under advanced steam cycle conditions, as well as understanding of the evolution of oxide scale morphologies with time and temperature to identify features that could influence scale exfoliation characteristics. This understanding and acquired data were used to develop and validate models of oxide growth and loss by exfoliation. This paper provides an overview of the activity and highlights a selection of the results coming from the programme.

  6. Energy savings with solid-state ballasted high-pressure sodium lamps

    SciTech Connect (OSTI)

    Verderber, R.R.; Morse, O.

    1981-04-01T23:59:59.000Z

    The performance of three types of solid-state ballasts used to operate high-pressure sodium lamps is discussed. Each type of solid-state ballast has been designed to operate an HPS lamp of a different wattage (150, 200, and 400 watts). The performance of these ballasts compared to standard core-coil ballasts operating the same HPS lamps shows that system efficiency improves as much as 17%. The solid-state ballasted HPS system also demonstrates excellent regulation with respect to input voltage and output power. These new ballasts can dim the HPS lamps and reduce flicker from more than 60% to less than 3%. Refitting street lighting with these new HPS systims provides an attractive return on initial capital investment.

  7. Properties of molecular solids and fluids at high pressure and temperatures

    SciTech Connect (OSTI)

    Etters, R.D.

    1992-03-01T23:59:59.000Z

    This renewal request for DOE grant DE-FG02-86ER45238, is dedicated to providing a complete thermodynamic profile of solids fluids, and fluid mixtures, over a wide range of temperatures and pressures. We are partially motivated by technological interest in detonation, combustion, superhard high pressure materials, and high temperature superconductors, which are important components of interest of various DOE laboratories. Our work on fluids and solids, composed of simple molecules, involves the determination of structures, phase transitions, pressure-volume relations, phonon, vibron, and libron modes of excitation, sound velocities, specific heats, thermal expansion, virial coefficients, sublimation energies, and orientational translational, and magnetic correlations. We hope that the study of these systems under extreme thermodynamic conditions will lead to exotic new materials of value, as well as enhanced fundamental understanding.

  8. Development of a High-Pressure/High-Temperature Downhole Turbine Generator

    SciTech Connect (OSTI)

    Timothy F. Price

    2007-02-01T23:59:59.000Z

    The objective of this project as originally outlined has been to achieve a viable downhole direct current (DC) power source for extreme high pressure, high temperature (HPHT) environments of >25,000 psi and >250 C. The Phase I investigation posed and answered specific questions about the power requirements, mode of delivery and form factor the industry would like to see for downhole turbine generator tool for the HPHT environment, and noted specific components, materials and design features of that commercial system that will require upgrading to meet the HPHT project goals. During the course of Phase I investigation the scope of the project was HPHT downhole DC power. Phase I also investigated the viability of modifying a commercial expanded, without additional cost expected to the project, to include the addition of HT batteries to the power supply platform.

  9. Dynamics of multiple double layers in high pressure glow discharge in a simple torus

    SciTech Connect (OSTI)

    Kumar Paul, Manash, E-mail: manashkr@gmail.com [Department of Physics, National Institute of Technology Agartala, Tripura799 046 (India); Sharma, P. K.; Thakur, A.; Kulkarni, S. V.; Bora, D. [Institute for Plasma Research, Bhat, Gandhinagar, Gujarat382 428 (India)

    2014-06-15T23:59:59.000Z

    Parametric characterization of multiple double layers is done during high pressure glow discharge in a toroidal vessel of small aspect ratio. Although glow discharge (without magnetic field) is known to be independent of device geometry, but the toroidal boundary conditions are conducive to plasma growth and eventually the plasma occupy the toroidal volume partially. At higher anode potential, the visibly glowing spots on the body of spatially extended anode transform into multiple intensely luminous spherical plasma blob structures attached to the tip of the positive electrode. Dynamics of multiple double layers are observed in argon glow discharge plasma in presence of toroidal magnetic field. The radial profiles of plasma parameters measured at various toroidal locations show signatures of double layer formation in our system. Parametric dependence of double layer dynamics in presence of toroidal magnetic field is presented here.

  10. A cryogenic high pressure cell for inelastic neutron scattering measurements of quantum fluids and solids

    SciTech Connect (OSTI)

    Carmichael, Justin R [ORNL; Omar Diallo, Souleymane [ORNL

    2013-01-01T23:59:59.000Z

    We present our new development of a high pressure cell for inelastic neutron scattering measurements of helium at ultra-low temperatures. The cell has a large sample volume of ~140 cm3, and a working pressure of ~70 bar, with a relatively thin wall-thickness (1.1 mm) - thanks to the high yield strength aluminum used in the design. Two variants of this cell have been developed; one with permanently joined components using electron-beam welding and explosion welding, methods that have little or no impact on the global heat treatment of the cell, and another with modular and interchangeable components, which include a capacitance pressure gauge, that can be sealed using traditional indium wire technique. The performance of the cell has been tested in recent measurements on superfluid liquid helium near the solidification line.

  11. Fiber-optic, anti-cycling, high pressure sodium street light control. Final technical progress report

    SciTech Connect (OSTI)

    NONE

    1995-05-01T23:59:59.000Z

    This is the Final Technical Progress Report on a project to develop and market a Fiber-Optic Anti-Cycling High Pressure Sodium Street Light Control. The field test units are now being made with a single vertical PC board design and contains a computer-on-a-chip or PROM IC to take the place of the majority of the components previously contained on the upper logic board. This will reduce the final costs of the unit when it is in production and increase the control`s flexibility. The authors have finished the soft tooling and have made the 400 plastic cases for the field test units. The new configuration of the cases entails a simplified design of the control shell which will have the lenses cast in place. The shell and base plastics are now finished and in final assembly awaiting the completion of the PC boards.

  12. Integrated-fin gasket for palm cubic-anvil high pressure apparatus

    SciTech Connect (OSTI)

    Cheng, J.-G. [Institute for Solid State Physics, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581 (Japan); Beijing National Laboratory for Condensed Matter Physics and Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Matsubayashi, K.; Nagasaki, S.; Hisada, A.; Hirayama, T.; Uwatoko, Y. [Institute for Solid State Physics, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581 (Japan); Hedo, M. [Faculty of Science, University of Ryukyus, Senbaru, Nishihara, Okinawa 903-0213 (Japan); Kagi, H. [Graduate School of Science, University of Tokyo, 7-3-1, Hongo Bunkyo-Ku, Tokyo 113-0033 (Japan)

    2014-09-15T23:59:59.000Z

    We described an integrated-fin gasket technique for the palm cubic-anvil apparatus specialized for the high-pressure and low-temperature measurements. By using such a gasket made from the semi-sintered MgO ceramics and the tungsten-carbide anvils of 2.5 mm square top, we successfully generate pressures over 16 GPa at both room and cryogenic temperatures down to 0.5 K. We observed a pressure self-increment for this specific configuration and further characterized the thermally induced pressure variation by monitoring the antiferromagnetic transition temperature of chromium up to 12 GPa. In addition to enlarge the pressure capacity, such a modified gasket also improves greatly the surviving rate of electrical leads hanging the sample inside a Teflon capsule filled with the liquid pressure-transmitting medium. These improvements should be attributed to the reduced extrusion of gasket materials during the initial compression.

  13. Ground state properties and high pressure behavior of plutonium dioxide: Systematic density functional calculations

    E-Print Network [OSTI]

    Zhang, Ping; Zhao, Xian-Geng

    2010-01-01T23:59:59.000Z

    Plutonium dioxide is of high technological importance in nuclear fuel cycle and is particularly crucial in long-term storage of Pu-based radioactive waste. Using first-principles density-functional theory, in this paper we systematically study the structural, electronic, mechanical, thermodynamic properties, and pressure induced structural transition of PuO$_{2}$. To properly describe the strong correlation in the Pu $5f$ electrons, the local density approximation$+U$ and the generalized gradient approximation$+U$ theoretical formalisms have been employed. We optimize the $U$ parameter in calculating the total energy, lattice parameters, and bulk modulus at the nonmagnetic, ferromagnetic, and antiferromagnetic configurations for both ground state fluorite structure and high pressure cotunnite structure. The best agreement with experiments is obtained by tuning the effective Hubbard parameter $U$ at around 4 eV within the LDA$+U$ approach. After carefully testing the validity of the ground state, we further in...

  14. High-pressure behavior of amorphous selenium from ultrasonic measurements and Raman spectroscopy

    SciTech Connect (OSTI)

    He, Z.; Liu, X. R.; Hong, S. M., E-mail: hpswjtu@gmail.com, E-mail: smhong@home.swjtu.edu.cn [Laboratory of High Pressure Physics, Southwest Jiaotong University, Key Laboratory of Advanced Technologies of Materials, Ministry of Education of China, Chengdu 610031 (China); Wang, Z. G. [National Key Laboratory for Shock Wave and Detonation Physics Research, Institute of Fluid Physics, Chinese Academy of Engineering Physics, Mianyang 621900 (China); Zhu, H. Y. [State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012 (China); Peng, J. P. [School of Physical Science and Technology, Southwest Jiaotong University, Chengdu 610031 (China)

    2014-07-07T23:59:59.000Z

    The high-pressure behavior of melt-quenched amorphous selenium (a-Se) has been investigated via ultrasonic measurements and Raman scattering at room temperature. The ultrasonic measurements were conducted on a-Se in a multi-anvil apparatus with two different sample assemblies at pressures of up to 4.5 and 4.8?GPa. We discovered that similar kinks occur in the slopes of the pressure dependence characteristics of the travel time and the sound velocity in both shear and longitudinal waves in the 2.02.5?GPa range. These kinks are independent of the sample assemblies, indicating an intrinsic transformation of the a-Se. Additionally, we deduced the pressure-volume relationship of a-Se from the sound velocity characteristics using the BirchMurnaghan equation of state, and the results agreed well with those of previous reports. In situ high-pressure Raman scattering measurements of a-Se were conducted in a diamond anvil cell with an 830?nm excitation line up to a pressure of 4.3?GPa. We found that the characteristic band of a-Se at ?250?cm{sup ?1} experienced a smooth shift to a lower frequency with pressure, but a sharp slope change in the band intensity versus pressure occurred near 2.5?GPa. The results of X-ray diffraction and differential scanning calorimetry measurements indicate that the samples remain in their amorphous states after decompression. Thus, we proposed that the abnormal compression behavior of a-Se in the 2.02.5?GPa range can be attributed to pressure-induced local atomic reconfiguration, implying an amorphous-amorphous transition of the elementary selenium.

  15. High Pressure Sensing and Dynamics Using High Speed Fiber Bragg Grating Interrogation Systems

    SciTech Connect (OSTI)

    Rodriguez, G. [LANL; Sandberg, R. L. [LANL; Lalone, B. M. [NSTec; Marshall, B. R. [NSTec; Grover, M. [NSTec; Stevens, G. D. [NSTec; Udd, E. [Columbia Gorge Research

    2014-06-01T23:59:59.000Z

    Fiber Bragg gratings (FBGs) are developing into useful sensing tools for measuring high pressure dynamics in extreme environments under shock loading conditions. Approaches using traditional diode array coupled FBG interrogation systems are often limited to readout speeds in the sub-MHz range. For shock wave physics, required detection speeds approaching 100 MHz are desired. We explore the use of two types of FBG sensing systems that are aimed at applying this technology as embedded high pressure probes for transient shock events. Both approaches measure time resolved spectral shifts in the return light from short (few mm long) uniform FBGs at 1550 nm. In the first approach, we use a fiber coupled spectrometer to demultiplex spectral channels into an array (up to 12) of single element InGaAs photoreceivers. By monitoring the detectors during a shock impact event with high speed recording, we are able to track the pressure induced spectral shifting in FBG down to a time resolution of 20 ns. In the second approach, developed at the Special Technologies Lab, a coherent mode-locked fiber laser is used to illuminate the FBG sensor. After the sensor, wavelength-to-time mapping is accomplished with a chromatic dispersive element, and entire spectra are sampled using a single detector at the modelocked laser repetition rate of 50 MHz. By sampling with a 12 GHz InGaAs detector, direct wavelength mapping in time is recorded, and the pressure induced FBG spectral shift is sampled at 50 MHz. Here, the sensing systems are used to monitor the spectral shifts of FBGs that are immersed into liquid water and shock compressed using explosives. In this configuration, the gratings survive to pressures approaching 50 kbar. We describe both approaches and present the measured spectral shifts from the shock experiments.

  16. Dark Matter Directionality Revisited with a High Pressure Xenon Gas Detector

    E-Print Network [OSTI]

    Gopolang Mohlabeng; Kyoungchul Kong; Jin Li; Adam Para; Jonghee Yoo

    2015-04-29T23:59:59.000Z

    An observation of the anisotropy of dark matter interactions in a direction-sensitive detector would provide decisive evidence for the discovery of galactic dark matter. Directional information would also provide a crucial input to understanding its distribution in the local Universe. Most of the existing directional dark matter detectors utilize particle tracking methods in a low-pressure gas time projection chamber. These low pressure detectors require excessively large volumes in order to be competitive in the search for physics beyond the current limit. In order to avoid these volume limitations, we consider a novel proposal, which exploits a columnar recombination effect in a high-pressure gas time projection chamber. The ratio of scintillation to ionization signals observed in the detector carries the angular information of the particle interactions. In this paper, we investigate the sensitivity of a future directional detector focused on the proposed high-pressure Xenon gas time projection chamber. We study the prospect of detecting an anisotropy in the dark matter velocity distribution. We find that tens of events are needed to exclude an isotropic distribution of dark matter interactions at 95% confidence level in the most optimistic case with head-to-tail information. However, one needs at least 10-20 times more events without head-to-tail information for light dark matter below 50 GeV. For an intermediate mass range, we find it challenging to observe an anisotropy of the dark matter distribution. Our results also show that the directional information significantly improves precision measurements of dark matter mass and the elastic scattering cross section for a heavy dark matter.

  17. High-pressure structural and elastic properties of Tl{sub 2}O{sub 3}

    SciTech Connect (OSTI)

    Gomis, O., E-mail: osgohi@fis.upv.es; Vilaplana, R. [Centro de Tecnologas Fsicas, MALTA Consolider Team, Universitat Politcnica de Valncia, 46022 Valncia (Spain); Santamara-Prez, D. [Departamento de Fsica Aplicada-ICMUV, MALTA Consolider Team, Universidad de Valencia, Edificio de Investigacin, C/Dr. Moliner 50, 46100 Burjassot (Spain); Earth Sciences Department, University College London, Gower Street, WC1E 6BT London (United Kingdom); Ruiz-Fuertes, J. [Departamento de Fsica Aplicada-ICMUV, MALTA Consolider Team, Universidad de Valencia, Edificio de Investigacin, C/Dr. Moliner 50, 46100 Burjassot (Spain); Geowissenschaften, Goethe-Universitt, Altenhferallee 1, 60438 Frankfurt am Main (Germany); Sans, J. A.; Manjn, F. J.; Mollar, M. [Instituto de Diseo para la Fabricacin y Produccin Automatizada, MALTA Consolider Team, Universitat Politcnica de Valncia, 46022 Valncia (Spain); and others

    2014-10-07T23:59:59.000Z

    The structural properties of Thallium (III) oxide (Tl{sub 2}O{sub 3}) have been studied both experimentally and theoretically under compression at room temperature. X-ray powder diffraction measurements up to 37.7?GPa have been complemented with ab initio total-energy calculations. The equation of state of Tl{sub 2}O{sub 3} has been determined and compared to related compounds. It has been found experimentally that Tl{sub 2}O{sub 3} remains in its initial cubic bixbyite-type structure up to 22.0?GPa. At this pressure, the onset of amorphization is observed, being the sample fully amorphous at 25.2?GPa. The sample retains the amorphous state after pressure release. To understand the pressure-induced amorphization process, we have studied theoretically the possible high-pressure phases of Tl{sub 2}O{sub 3}. Although a phase transition is theoretically predicted at 5.8?GPa to the orthorhombic Rh{sub 2}O{sub 3}-II-type structure and at 24.2?GPa to the orthorhombic ?-Gd{sub 2}S{sub 3}-type structure, neither of these phases were observed experimentally, probably due to the hindrance of the pressure-driven phase transitions at room temperature. The theoretical study of the elastic behavior of the cubic bixbyite-type structure at high-pressure shows that amorphization above 22?GPa at room temperature might be caused by the mechanical instability of the cubic bixbyite-type structure which is theoretically predicted above 23.5?GPa.

  18. Engineering development of a lightweight high-pressure scarifier for tank waste retrieval

    SciTech Connect (OSTI)

    Hatchell, B.K.

    1997-09-01T23:59:59.000Z

    The Retrieval Process Development and Enhancements Program (RPD&E) is sponsored by the U.S. Department of Energy Tanks Focus Area to investigate existing and emerging retrieval processes suitable for the retrieval of high-level radioactive waste inside underground storage tanks. This program, represented by industry, national laboratories, and academia, seeks to provide a technical and cost basis to support site-remediation decisions. Part of this program has involved the development of a high-pressure waterjet dislodging system and pneumatic conveyance integrated as a scarifier. Industry has used high-pressure waterjet technology for many years to mine, cut, clean, and scarify materials with a broad range of properties. The scarifier was developed as an alternate means of retrieving waste inside Hanford single-shell tanks, particularly hard, stubborn waste. Testing of the scarifier has verified its ability to retrieve a wide range of tank waste ranging from extremely hard waste that is resistant to other dislodging means to soft sludge and even supernatant fluid. Since the scarifier expends water at a low rate and recovers most of the water as it is used, the scarifier is well suited for retrieval of tanks that leak and cannot be safely sluiced or applications where significant waste dilution is not acceptable. Although the original scarifier was effective, it became evident that a lighter, more compact version that would be compatible with light weight deployment systems under development, such as the Light Duty Utility Arm, was needed. At the end of FY 95, the Light Weight Scarifier (LWS) was designed to incorporate the features of the original scarifier in a smaller, lighter end effector. During FY 96, the detailed design of the LWS was completed and two prototypes were fabricated.

  19. Steam Load Reduction Guidance Emergency Management Program

    E-Print Network [OSTI]

    Pawlowski, Wojtek

    Steam Load Reduction Guidance Emergency Management Program v October 2014 Steam_Load_Reduction_Guidance_DSRDSR 1.0 PurposeandScope Utilities provides steam to the campus community for space heating, hot water in the steam distribution system or the Central Energy Plant, the preservation of building infrastructure

  20. DOE's BestPractices Steam End User Training Steam End User Training

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    DOE's BestPractices Steam End User Training Steam End User Training Welcome Module - 1 8/27/2010 Steam End User Training Welcome Module Slide 1 Steam End User Training Welcome to the Department of Energy's Industrial Technologies Program BestPractices Steam End-User Training. The Department of Energy

  1. DOE's BestPractices Steam End User Training Steam End User Training

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    Condensate recovery o Fuel unit cost o Total fuel consumption o Steam production Slide 6 Boiler o PRV steam flows o o Steam consumers Turbine efficiencies Electrical unit cost o o CondensateDOE's BestPractices Steam End User Training Steam End User Training Conclusion Module 1 June 28

  2. Steam Power Partnership: Improving Steam System Efficiency Through Marketplace Partnerships

    E-Print Network [OSTI]

    Jones, T.

    The Alliance to Save Energy, a national nonprofit organization based in Washington DC, and the U.S. Department of Energy are working with energy efficiency suppliers to promote the comprehensive upgrade of industrial steam systems. Like EPA's Green...

  3. Steam reformer with catalytic combustor

    DOE Patents [OSTI]

    Voecks, Gerald E. (La Crescenta, CA)

    1990-03-20T23:59:59.000Z

    A steam reformer is disclosed having an annular steam reforming catalyst bed formed by concentric cylinders and having a catalytic combustor located at the center of the innermost cylinder. Fuel is fed into the interior of the catalytic combustor and air is directed at the top of the combustor, creating a catalytic reaction which provides sufficient heat so as to maintain the catalytic reaction in the steam reforming catalyst bed. Alternatively, air is fed into the interior of the catalytic combustor and a fuel mixture is directed at the top. The catalytic combustor provides enhanced radiant and convective heat transfer to the reformer catalyst bed.

  4. Steam Cracker Furnace Energy Improvements

    E-Print Network [OSTI]

    Gandler, T.

    & challenges in steam cracking ? Energy efficiency improvements Overview Baytown Olefins Plant Page 3 Baytown Complex ?One of world?s largest integrated, most technologically advanced petroleum/petrochemical complexes ?~3,400 acres along Houston Ship... wall temperatures Furnace tube hydrocarbon + steam 0 0.2 0.4 0.6 0.8 1 1.2 1 2 time C o k e l a y e r Page 8 Steam Cracker Furnace Energy Efficiency ? Overall energy efficiency of furnace depends on ? Run length or % of time...

  5. High pressure ejection of melt from a reactor pressure vessel. The discharge phase. Revision 7

    SciTech Connect (OSTI)

    Pilch, M.; Tarbell, W.M.

    1985-09-01T23:59:59.000Z

    Recent probabilistic risk-assessment studies identified potential accident sequences in which reactor vessel failure occurs while the primary system is at elevated pressure. The phenomenology of the discharge phase is reviewed here. We propose an improved model for hole ablation following vessel failure, and we compare the model with experiment data. Gas blowthrough is identified as a mechanism that allows steam to escape through the vessel breach before melt ejection is complete. Gas blowthrough leads to pneumatic atomization of the remaining melt before significant depressurization of the primary system occurs.

  6. Wet-steam erosion of steam turbine disks and shafts

    SciTech Connect (OSTI)

    Averkina, N. V. [JSC 'NPO TsKTI' (Russian Federation); Zheleznyak, I. V. [Leningradskaya AES branch of JSC 'Kontsern Rosenergoatom' (Russian Federation); Kachuriner, Yu. Ya.; Nosovitskii, I. A.; Orlik, V. G., E-mail: orlikvg@mail.ru [JSC 'NPO TsKTI' (Russian Federation); Shishkin, V. I. [Leningradskaya AES branch of JSC 'Kontsern Rosenergoatom' (Russian Federation)

    2011-01-15T23:59:59.000Z

    A study of wet-steam erosion of the disks and the rotor bosses or housings of turbines in thermal and nuclear power plants shows that the rate of wear does not depend on the diagrammed degree of moisture, but is determined by moisture condensing on the surfaces of the diaphragms and steam inlet components. Renovating the diaphragm seals as an assembly with condensate removal provides a manifold reduction in the erosion.

  7. Computational heterogeneous catalysis applied to steam methane reforming over nickel and nickel/silver catalysts

    E-Print Network [OSTI]

    Blaylock, Donnie Wayne

    2011-01-01T23:59:59.000Z

    The steam methane reforming (SMR) reaction is the primary industrial means for producing hydrogen gas. As such, it is a critical support process for applications including petrochemical processing and ammonia synthesis. ...

  8. REMOVAL OF H2S AND SO2 BY CaCO3-BASED SORBENTS AT HIGH PRESSURES

    SciTech Connect (OSTI)

    Prof. Stratis V. Sotirchos

    2000-09-01T23:59:59.000Z

    The mechanism of the removal of SO{sub 2} and H{sub 2}S by CaCO{sub 3}-based sorbents in pressurized fluidized-bed coal combustors (PFBC) and high pressure gasifiers was investigated in this project. Reactivity evolution experiments were carried out in thermogravimetric apparatuses both under simulated high pressure conditions and at high pressures. Experiments at high pressure were conducted in a high pressure thermogravimetric arrangement that was set up and developed under this project. Two calcitic solids of high calcium carbonate content (over 97%) were employed in the experiments: a fine-grained distributed by Greer Limestone Co. (Greer Limestone) and a solid supplied in the form of large calcitic crystals (Iceland Spar). The decision to work with these solids was mainly based on the fact that they have been employed in several past studies of sulfation, sulfidation, and calcination in our laboratory, and therefore, a large volume of data on their performance under different conditions was available for comparison purposes. In addition to the experimental studies, work was also done on the development of rigorous mathematical models for the description of the occurrence of simultaneous processes (e.g., calcination and sulfation and carbonation and sulfation) in the interior of porous solids and for the simulation of the evolution of the pore structure of porous solids that undergo chemical transformation in their interior.

  9. Foam Cleaning of Steam Turbines

    E-Print Network [OSTI]

    Foster, C.; Curtis, G.; Horvath, J. W.

    2000-01-01T23:59:59.000Z

    The efficiency and power output of a steam turbine can be dramatically reduced when deposits form on the turbine blades. Disassembly and mechanical cleaning of the turbine is very time consuming and costly. Deposits can be removed from the turbine...

  10. Foam Cleaning of Steam Turbines

    E-Print Network [OSTI]

    Foster, C.; Curtis, G.; Horvath, J. W.

    The efficiency and power output of a steam turbine can be dramatically reduced when deposits form on the turbine blades. Disassembly and mechanical cleaning of the turbine is very time consuming and costly. Deposits can be removed from the turbine...

  11. Steam Coal Import Costs - EIA

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    Steam Coal Import Costs for Selected Countries U.S. Dollars per Metric Ton1 (Average Unit Value, CIF2) Country 2001 2002 2003 2004 2005 2006 2007 2008 2009 Belgium 46.96 39.34...

  12. Steam System Forecasting and Management

    E-Print Network [OSTI]

    Mongrue, D. M.; Wittke, D. O.

    1982-01-01T23:59:59.000Z

    '. This and the complex and integrated nature of the plants energy balance makes steam system forecasting and management essential for optimum use of the plant's energy. This paper discusses the method used by Union carbide to accomplish effective forecasting...

  13. Method to prevent/mitigate steam explosions in casting pits

    DOE Patents [OSTI]

    Taleyarkhan, Rusi P. (Knoxville, TN)

    1996-01-01T23:59:59.000Z

    Steam explosions can be prevented or mitigated during a metal casting process by the placement of a perforated flooring system in the casting pit. An upward flow of compressed gas through this perforated flooring system is introduced during the casting process to produce a buffer layer between any spilled molten metal and the cooling water in the reservoir. This buffer layer provides a hydrodynamic layer which acts to prevent or mitigate steam explosions resulting from hot, molten metal being spilled into or onto the cooling water.

  14. Photoluminescence studies of Y{sub 2}O{sub 3}:Eu{sup 3+} under high pressure

    SciTech Connect (OSTI)

    Zhang, Jian; Cui, Hang; Ma, Chunli; Wu, Xiaoxin; Cui, Qiliang [State Key Laboratory of Superhard Materials, Jilin University, Changchun, Jilin 130012 (China); Zhu, Peifen [Department of Electrical and Computer Engineering, Lehigh University, Bethlehem, Pennsylvania 18015 (United States); Zhu, Hongyang, E-mail: hongyangzhu@jlu.edu.cn [State Key Laboratory of Superhard Materials, Jilin University, Changchun, Jilin 130012 (China); College of Materials Science and Engineering, Jilin University, Changchun, Jilin 130012 (China); Ma, Yanzhang [Department of Mechanical Engineering, Texas Tech University, Lubbock, Texas 79409 (United States)

    2014-01-14T23:59:59.000Z

    The Eu-doped yttria (Y{sub 2}O{sub 3}:Eu{sup 3+}) has been investigated by the in situ high-pressure angle dispersive synchrotron X-ray diffraction (XRD) and the photoluminescence (PL) spectroscopy. The red shift and intensity ratio variation of emissions with increasing pressure were observed and elucidated. It was found that the red shift of emissions is related to the expansion of the f orbit of the Eu{sup 3+} and the intensity ratio variation of emissions is ascribed to the change of the crystal field under high pressure. The pressure-induced changes in spectrum are related to the phase transition, which was confirmed by XRD pattern. The two high pressure phases were identified as the monoclinic (C2/m) phase and hexagonal (P-3m1) phase by the Rietveld refinement.

  15. Chemical Processing in High-Pressure Aqueous Environments. 9. Process Development for Catalytic Gasification of Algae Feedstocks

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Hart, Todd R.; Neuenschwander, Gary G.; Rotness, Leslie J.; Olarte, Mariefel V.; Zacher, Alan H.

    2012-07-26T23:59:59.000Z

    Through the use of a metal catalyst, gasification of wet algae slurries can be accomplished with high levels of carbon conversion to gas at relatively low temperature (350 C). In a pressurized-water environment (20 MPa), near-total conversion of the organic structure of the algae to gases has been achieved in the presence of a supported ruthenium metal catalyst. The process is essentially steam reforming, as there is no added oxidizer or reagent other than water. In addition, the gas produced is a medium-heating value gas due to the synthesis of high levels of methane, as dictated by thermodynamic equilibrium. As opposed to earlier work, biomass trace components were removed by processing steps so that they did not cause processing difficulties in the fixed catalyst bed tubular reactor system. As a result, the algae feedstocks, even those with high ash contents, were much more reliably processed. High conversions were obtained even with high slurry concentrations. Consistent catalyst operation in these short-term tests suggested good stability and minimal poisoning effects. High methane content in the product gas was noted with significant carbon dioxide captured in the aqueous byproduct in combination with alkali constituents and the ammonia byproduct derived from proteins in the algae. High conversion of algae to gas products was found with low levels of byproduct water contamination and low to moderate loss of carbon in the mineral separation step.

  16. Synthesis, structural characterization and high pressure phase transitions of monolithium hydronium sulfate

    SciTech Connect (OSTI)

    Banerjee, Debasis, E-mail: debasis.banerjee@stonybrook.edu [Department of Chemistry, Stony Brook University, Stony Brook 11794-3400 (United States); Plonka, Anna M. [Department of Geosciences, Stony Brook University, Stony Brook 11794-2100 (United States); Kim, Sun Jin [Nano-Materials Research Center, Korea Institute of Science and Technology, P.O. Box 131, Cheongryang, Seoul 130-650 (Korea, Republic of); Xu Wenqian [Department of Geosciences, Stony Brook University, Stony Brook 11794-2100 (United States); Parise, John B. [Department of Chemistry, Stony Brook University, Stony Brook 11794-3400 (United States); Mineral Physics Institute, Stony Brook University, Stony Brook, NY 11790-2100 (United States)

    2013-01-15T23:59:59.000Z

    A three dimensional lithium hydronium sulfate LiSO{sub 4}{center_dot}H{sub 3}O [1], [space group Pna2{sub 1}a=8.7785(12) A, b=9.1297(12) A, c=5.2799(7) A, V=423.16(10) A{sup 3}] was synthesized via solvothermal methods using 1,5-naphthalenedisulfonic acid (1,5-NSA) as the source of sulfate ions. The structure of [1], determined by single crystal X-ray diffraction techniques, consists of corner sharing LiO{sub 4} and SO{sub 4} tetrahedra, forming an anionic 3-D open framework that is charge balanced by hydronium ions positioned within channels running along [001] and forming strong H-bonding with the framework oxygen atoms. Compound [1] undergoes two reversible phase transitions, involving reorientation of SO{sub 4}{sup 2-} ions at pressures of approximately 2.5 and 5 GPa at room temperature, as evident from characteristic discontinuous frequency drops in the {nu}{sub 1} mode of the Raman spectra. Additionally, compound [1] forms dense {beta}-lithium sulfate at 300 Degree-Sign C, as evident from temperature dependent powder XRD and combined reversible TGA-DSC experiments. - Graphical abstract: Left: View of corner-shared LiO{sub 4} and SO{sub 4} tetrahedra along [001] direction with hydronium ions situated in the channels. Right: (a) Photograph of the loaded DAC (b) Ambient pressure Raman spectrum of compound [1] (c) Evolution of the {nu}{sub 1} mode with the increasing and decreasing pressure indicating transitions to high-pressure phases at {approx}2.5 (red curves) and {approx}5 GPa (blue curves) and at {approx}3.5 GPa upon decompression. Highlights: Black-Right-Pointing-Pointer A 3-D lithium hydronium sulfate is synthesized by solvothermal methods. Black-Right-Pointing-Pointer Two high pressure phase transition occurs due to rotation of sulfate groups. Black-Right-Pointing-Pointer The framework undergoes a high temperature structural transformation, to form {beta}-Li{sub 2}SO{sub 4} phase.

  17. The effect of high-pressure injection of gas on the reservoir volume factor of a crude oil

    E-Print Network [OSTI]

    Honeycutt, Baxter Bewitt

    1957-01-01T23:59:59.000Z

    THE EFFECT OF HIGH-PRESSURE INJECTION OF GAS ON THE RESERVOIR VOLUME FACTOR OF A CRUDE OIL A Thesis By+ BAXTER DS'kONEYCUTT o Submitted to the Graduate School of the Agricultural and Mechanical College of Texas in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE August, i957 Major Subject: Petroleum Engineering THE EFFECT OF HIGH-PRESSURE INJECTION OF GAS ON THE RESERVOIR VOLUME FACTOR OF A CRUDE OIL A Thesis By BAXTER D. HONEYCUTT Appro d as to style...

  18. Hydrogen production by high-temperature steam gasification of biomass and coal

    SciTech Connect (OSTI)

    Kriengsak, S.N.; Buczynski, R.; Gmurczyk, J.; Gupta, A.K. [University of Maryland, College Park, MD (United States). Dept. of Mechanical Engineering

    2009-04-15T23:59:59.000Z

    High-temperature steam gasification of paper, yellow pine woodchips, and Pittsburgh bituminous coal was investigated in a batch-type flow reactor at temperatures in the range of 700 to 1,200{sup o}C at two different ratios of steam to feedstock molar ratios. Hydrogen yield of 54.7% for paper, 60.2% for woodchips, and 57.8% for coal was achieved on a dry basis, with a steam flow rate of 6.3 g/min at steam temperature of 1,200{sup o}C. Yield of both the hydrogen and carbon monoxide increased while carbon dioxide and methane decreased with the increase in gasification temperature. A 10-fold reduction in tar residue was obtained at high-temperature steam gasification, compared to low temperatures. Steam and gasification temperature affects the composition of the syngas produced. Higher steam-to-feedstock molar ratio had negligible effect on the amount of hydrogen produced in the syngas in the fixed-batch type of reactor. Gasification temperature can be used to control the amounts of hydrogen or methane produced from the gasification process. This also provides mean to control the ratio of hydrogen to CO in the syngas, which can then be processed to produce liquid hydrocarbon fuel since the liquid fuel production requires an optimum ratio between hydrogen and CO. The syngas produced can be further processed to produce pure hydrogen. Biomass fuels are good source of renewable fuels to produce hydrogen or liquid fuels using controlled steam gasification.

  19. Use Steam Jet Ejectors or Thermocompressors to Reduce Venting of Low-Pressure Steam

    SciTech Connect (OSTI)

    Not Available

    2005-09-01T23:59:59.000Z

    Industrial Technologies Program's BestPractices tip sheet on improving efficiency of industrial steam systems by recovery latent heat from low-pressure steam.

  20. Diamond-anvil high-pressure cell with improved X-ray collimation system

    DOE Patents [OSTI]

    Schiferl, David (Los Alamos, NM); Olinger, Barton W. (Santa Fe, NM); Livingston, Robert W. (Los Alamos, NM)

    1986-01-01T23:59:59.000Z

    An adjustable X-ray collimation system for a diamond-anvil high-pressure cell of the type including a cooperable piston and cylinder and a pair of opposing diamonds located between the head of the piston and the head of the cylinder. The X-ray collimation system includes a tubular insert which contains an X-ray collimator. The insert is engageable in the bore of the piston. The collimator is mounted within the insert by means of an elastomeric O-ring at the end closest the opposed diamonds, and by means of a set of adjustable set screws at the opposite end. By adjustment of the set screws the collimator can be pivoted about the O-ring and brought into alignment with the opposed diamonds and the sample contained therein. In the preferred embodiment there is further provided a set of plugs which are insertable in the bore of the collimator. The plugs have bores of different diameters. By successively inserting plugs of progressively smaller bore diameters and adjusting the alignment of the collimator with each plug, the collimator can be quickly brought into accurate alignment with the diamonds. The collimation system allows alignment of the collimator either before or after the cell has been loaded and pressurized.

  1. Diamond-anvil high-pressure cell with improved x-ray collimation system

    DOE Patents [OSTI]

    Schiferl, D.; Olinger, B.W.; Livingston, R.W.

    1984-03-30T23:59:59.000Z

    An adjustable x-ray collimation system for a diamond-anvil high-pressure cell of the type including a cooperable piston and cylinder and a pair of opposing diamonds located between the head of the piston and the head of the cylinder. The x-ray collimation system includes a tubular insert which contains an x-ray collimator. The insert is engageable in the bore of the piston. The collimator is mounted within the insert by means of an elastomeric o-ring at the end closest the opposed diamonds, and by means of a set of adjustable set screws at the opposite end. By adjustment of the set screws the collimator can be pivoted about the o-ring and brought into alignment with the opposed diamonds and the sample contained therein. In the preferred embodiment there is further provided a set of plugs which are insertable in the bore of the collimator. The plugs have bores of different diameters. By successively inserting plugs of progressively smaller bore diameters and adjusting the alignment of the collimator with each plug, the collimator can be quickly brought into accurate alignment with the diamonds. The collimation system allows alignment of the collimator either before or after the cell has been loaded and pressurized.

  2. Diamond-anvil high-pressure cell with improved x-ray collimation system

    SciTech Connect (OSTI)

    Schiferl, D.; Olinger, B.W.; Livingston, R.W.

    1986-07-22T23:59:59.000Z

    This patent describes a diamond-anvil high-pressure cell having a tubular piston and a cylinder in which the piston is slidable to effect compression of a pair of opposed diamonds located between the piston and the cylinder. The piston includes a central bore opening on one end, an adjustable X-ray collimation system comprising a tubular insert engageable in the bore of the piston, the insert including a central bore and having first and second ends, with the first end of the insert being closest to the opposed diamonds and the second end of the insert extending out of the open end of the piston, a collimator insertable in the bore of the tubular insert. The collimator has a central bore and having first and second ends corresponding respectively with the first and second ends of the insert, elastomeric pivot means mounted in the bore of the insert at the first end of the insert for flexibly retaining the first end of the collimator while allowing the collimator to pivot within the pivot means, and adjustable locking means located at the second end of the insert for adjusting and securing the second end of the collimator so as to be in alignment with the opposed diamonds.

  3. An Innovative High-Temperature High-Pressure Measurement While Drilling (MWD) Tool

    SciTech Connect (OSTI)

    Brian Boling

    2007-06-01T23:59:59.000Z

    Measurement while drilling (MWD) tools specified to 150 C (302 F) that provide wellbore surveys, real-time inclination, and natural gamma ray detection are a commodity item in the oilfield services industry. MWD tools specified to 175 C (347 F) that routinely demonstrate highly reliable operation are available from only a few service companies. Commercial MWD tools that reliably operate to 200 C (392 F) for extended periods of time and offer features like real-time gamma ray, retrievability, and reseatability are nonexistent. Need for these higher temperature tools will increase as wells become hotter in the search for new oil and gas resources. The goal of this project was to design a retrievable and reseatable high-pressure/high-temperature MWD tool with real-time continuous inclination, vibration detection, annular pressure, and gamma ray detection. This report describes the development of such a tool from concept, through feasibility, and into field testing and preliminary development planning. It describes the challenges encountered in the design of the tool, along with testing results and decisions about the commercial viability of the tool in the configuration in which it was developed. The decision was made not to commercialize the tool developed under this project because of a combination of battery technology problems and modulation power consumption at the required depths.

  4. High-pressure shock behavior of WC and Ta2O5 powders.

    SciTech Connect (OSTI)

    Knudson, Marcus D. (Sandia National Laboratories, Albuquerque, NM); Reinhart, William Dodd (Sandia National Laboratories, Albuquerque, NM); Vogler, Tracy John; Root, Seth (Sandia National Laboratories, Albuquerque, NM)

    2011-10-01T23:59:59.000Z

    Planar shock experiments were conducted on granular tungsten carbide (WC) and tantalum oxide (Ta{sub 2}O{sub 5}) using the Z machine and a 2-stage gas gun. Additional shock experiments were also conducted on a nearly fully dense form of Ta{sub 2}O{sub 5}. The experiments on WC yield some of the highest pressure results for granular materials obtained to date. Because of the high distention of Ta{sub 2}O{sub 5}, the pressures obtained were significantly lower, but the very high temperatures generated led to large contributions of thermal energy to the material response. These experiments demonstrate that the Z machine can be used to obtain accurate shock data on granular materials. The data on Ta{sub 2}O{sub 5} were utilized in making improvements to the P-{lambda} model for high pressures; the model is found to capture the results not only of the Z and gas gun experiments but also those from laser experiments on low density aerogels. The results are also used to illustrate an approach for generating an equation of state using only the limited data coming from nanoindentation. Although the EOS generated in this manner is rather simplistic, for this material it gives reasonably good results.

  5. Dielectric Spectroscopy and Ultrasonic Study of Propylene Carbonate under Ultra-high Pressures

    E-Print Network [OSTI]

    M. V. Kondrin; E. L. Gromnitskaya; A. A. Pronin; A. G. Lyapin; V. V. Brazhkin; A. A. Volkov

    2013-05-16T23:59:59.000Z

    We present the high pressure dielectric spectroscopy (up to 4.2 GPa) and ultrasonic study (up to 1.7 GPa) of liquid and glassy propylene carbonate (PC). Both of the methods provide complementary pictures of the glass transition in PC under pressure. No other relaxation processes except $\\alpha$-relaxation have been found in the studied pressure interval. The propylene carbonate liquid is a glassformer where simple relaxation and the absence of $\\beta$-relaxation are registered in the record-breaking ranges of pressures and densities. The equation of state of liquid PC was extended up to 1 GPa from ultrasonic measurements of bulk modulus and is in good accordance with the previous equations developed from volumetric data. We measured the bulk and shear moduli and Poisson's ratio of glassy PC up to 1.7 GPa. Many relaxation and elastic properties of PC can be qualitatively described by the soft-sphere or Lennard-Jones model. However, for the quantitative description of entire set of the experimental data, these models are insufficient. Moreover, the Poisson coefficient value for glassy PC indicates a significant contribution of non-central forces to the intermolecular potential. The well-known correlation between Poisson's ratio and fragility index (obtained from dielectric relaxation) is confirmed for PC at ambient pressure, but it is violated with pressure increase. This indicates that different features of the potential energy landscape are responsible for the evolution of dielectric response and elasticity with pressure increase.

  6. Direct containment heating and aerosol generation during high-pressure-melt expulsion experiments

    SciTech Connect (OSTI)

    Tarbell, W.W.; Brockmann, J.E.; Washington, K.E.; Pilch, M.; Marx, K.D.

    1988-01-01T23:59:59.000Z

    Severe nuclear plant accidents can involve the degradation of the reactor core while the primary coolant system remains pressurized. Molten fuel reaching the lower head of the reactor pressure vessel (RPV) may attack and fail the instrument guide tube penetrations, allowing the tube to be expelled from the vessel. The resulting aperture allows the molten fuel to be ejected into the cavity, followed by the blowdown of the contents of the primary system (high-pressure-melt ejection). Entrainment of the core debris in the cavity by the blowdown gases may cause high-temperature fuel particles to be carried into the containment building. Energy exchange between the particles and the atmosphere may cause heating and pressurizing of the containment (direct containment heating (DCH)). The complex phenomena associated with direct containment heating accident sequences are not well understood. This work describes a series of four experiments that have been performed to study and quantify the processes involved. The data from the experiments are used to guide the development of computer models to describe the response of containments under accident conditions.

  7. A primary high-pressure air flow measurement standard in Taiwan

    SciTech Connect (OSTI)

    Jiunn-Haur Shaw; Fong-Ruey Yang; Yao-Fu Chen [Industrial Technology Research Inst., Hsinchu (Taiwan, Province of China)

    1995-12-31T23:59:59.000Z

    A high-pressure air-flow national measurement standard is constructed in Taiwan with a capacity of 8400 Nm{sup 3}/h and a projected measurement uncertainty of {plus_minus}0.2% in the pressure range of 1 {approximately} 84 bars. it is a blow-down type facility, and its main purpose is to serve as the primary standard of a larger-flowrate natural gas flow measurement facility to be built in the future by Chinese Petroleum Company (CPC). The system has a gyroscopic weighing platform suitable for high precision gravimetric measurements and several sonic nozzles with different throat diameters situated in a chamber to be the reference flow meters. A set of two turbine meters, 50mm and 100mm, are sued as the transfer standard. The facility has two test sections separated by the nozzle chamber and four different calibration modes could be arranged. To make calibration, the storage tank, the temperature control loop, and two sets of pressure regulating valve establish a pressurized air flow with stable temperature and pressure in the test section. The control of the air-flow diversion, connect-disconnect mechanism, sonic nozzle array is made through a hydraulic power unit operating at 200 bars. Real time measurements of temperature, pressure, flow signal, and time are collected through a Honeywell 9000-series PLC and a FIX DMAC data acquisition/control software. This paper describes the key components of the test facility and presents the preliminary results of performance assessment.

  8. Particulate removal from high-temperature, high-pressure combustion gases

    SciTech Connect (OSTI)

    Henry, R.F.; Saxena, S.C.; Podolski, W.F.

    1983-10-01T23:59:59.000Z

    The adoption by utilities of coal-fired pressurized fluidized-bed/combined cycle combustion systems for electric power generation depends to a large extent on the development of an efficient and economic cleanup system for the high-temperature, high-pressure combustion gases. For adequate turbine protection, these gases must be sufficiently cleaned to bring particulate erosion and alkali vapor corrosion to a level acceptable to gas turbine manufacturers. At the same time, the total particulate content of the flue gas must be reduced to the limit set by the Environmental Protection Agency. To accomplish particulate removal from a dust-laden gas stream, a number of separation devices have been developed. These include conventional and augmented cyclones; porous metal, fiber, fabric, and ceramic filters, as well as fixed, moving, and fluidized-bed granular filters; and electrostatic precipitators. Several other novel separation devices have been proposed and developed to different degrees such as: contactors using molten salt, metal, or glass, dry scrubbers, acoustic agglomerators, as well as cyclones and granular-bed filters with external electrostatic or magnetic fields. Some of these separation devices in various combinations have been tested in process development units or in hot gas simulators by ANL, CPC, CURL, C-W, Exxon, GE, Westinghouse, etc. The results are discussed and evaluated for PFBC applications.

  9. Structure determination of the high-pressure phase of CdSe

    SciTech Connect (OSTI)

    Li, Yanchun, E-mail: liyc@ihep.ac.cn, E-mail: liuj@ihep.ac.cn; Lin, Chuanlong; Li, Xiaodong; Liu, Jing, E-mail: liyc@ihep.ac.cn, E-mail: liuj@ihep.ac.cn [Beijing Synchrotron Radiation Facility, Institute of High Energy Physics, Chinese Academy of Science, 100049 Beijing (China); Li, Gong [State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 (China); Xu, Jian [Institute of Fluid Physics, China Academy of Engineering Physics, P. O. Box 919-102, Mianyang, Sichuan 621900 (China)

    2014-06-14T23:59:59.000Z

    Structural phase transition sequence of CdSe has been investigated at pressures up to 60?GPa under quasi-hydrostatic conditions using synchrotron X-ray diffraction. A phase transition from the wurtzite type (B4) to the NaCl-type (B1) structure has been observed, followed by another phase transition to an orthorhombic structure at 27?GPa, in agreement with previous reports. We show that this high-pressure orthorhombic phase has a Pnma symmetry rather than being a Cmcm-symmetric structure as previously suggested. From our observations, the appearance of the new reflections and reflection splitting with increasing pressure is due to the change of atomic relative positions in crystal lattice and the difference in the compression ratio of lattice parameters for the Pnma structure, and we find no evidence for the third phase transition reported previously. The pressure-induced phase transition of CdSe has been further confirmed by the density-functional theory calculations.

  10. Predictive modeling and high-pressure-high-temperature synthesis of perovskites containing monovalent silver

    SciTech Connect (OSTI)

    Park, J.H.; Parise, J.B. [State Univ. of New York, Stony Brook, NY (United States)] [State Univ. of New York, Stony Brook, NY (United States); Woodward, P.M. [Brookhaven National Lab., Upton, NY (United States). Physics Dept.] [Brookhaven National Lab., Upton, NY (United States). Physics Dept.

    1998-10-01T23:59:59.000Z

    The program POTATO, which was developed to model distorted perovskite structures, has been used to assess the stability of hypothetical compositions and guide the synthesis of new materials at high pressures and high temperatures. The initial result of this effort is the synthesis of two new perovskites, Ca{sub 2}NdAgTi{sub 4}O{sub 12} and NdAgTi{sub 2}O{sub 6}, which were synthesized at 14--14.5 GPa and 1000 C using the uniaxial split sphere anvil type press (USSA-2000). Both compounds are perovskites distorted from the ideal cubic structure by octahedral tilting distortions. Ca{sub 2}NdAgTi{sub 4}O{sub 12} contains a random distribution of Ca{sup 2+}/Nd{sup 3+}/Ag{sup +} ions on the A-site, whereas NdAgTi{sub 2}O{sub 6} has a partially ordered distribution of Nd{sup 3+}/Ag{sup +} ions. Ca{sub 2}NdAgTi{sub 4}O{sub 12} adopts the GdFeO{sub 3} structure. NdAgTi{sub 2}O{sub 6} belongs to the tetragonal space group P4/nbm. This structure can be derived from the simple cubic perovskite structure by rotations of the octahedra about the c-axis and partial ordering of Nd{sup 3+} and Ag{sup +} ions into alternating layers, perpendicular to the c-axis.

  11. Study of liquid gallium at high pressure using synchrotron x-ray

    SciTech Connect (OSTI)

    Yu, Tony; Guo Quanzhong; Parise, John [Department of Geosciences, Mineral Physics Institute, Stony Brook University, Stony Brook, New York 11794-2100 (United States); Chen Jiuhua [Department of Geosciences, Mineral Physics Institute, Stony Brook University, Stony Brook, New York 11794-2100 (United States); Department of Mechanical and Materials Engineering, Center for the Study of Matters at Extreme Conditions, Florida International University, Miami, Florida 33199 (United States); Ehm, Lars [Department of Geosciences, Mineral Physics Institute, Stony Brook University, Stony Brook, New York 11794-2100 (United States); National Synchrotron Light Source, Brookhaven National Laboratory, Upton, New York 11973-5000 (United States); Huang Shu [Department of Mechanical and Materials Engineering, Center for the Study of Matters at Extreme Conditions, Florida International University, Miami, Florida 33199 (United States); Luo Shengnian [Physics Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

    2012-06-01T23:59:59.000Z

    Liquid gallium has been studied at high pressure up to 2 GPa and ambient temperature in a diamond anvil cell using high energy synchrotron x-ray beam. The total x-ray scattering data of liquid gallium were collected up to Q = 12 A{sup -1} and analyzed using pair distribution functions (PDF). The results indicate that the first nearest neighbor peak and second nearest neighbor (shoulder) peak of PDF in liquid gallium does not change with pressure, whereas the higher order (i.e., third and fourth) nearest neighbor peaks shift towards shorter distance with increasing pressure. Reverse Monte Carlo modeling based on the observed data shows that the coordination number in the liquid gallium increases with pressure from 10.5 at 0.3 GPa to 11.6 at 2 GPa. An atomic arrangement similar to the crystalline phase of Ga(II) with coordination number of 12 is proposed for the locally dense-packed rigid unit in liquid gallium. The volume compression data derived from the structure modeling yield a bulk modulus of 12.1(6) GPa for liquid gallium.

  12. Comparison of high pressure transient PVT measurements and model predictions. Part I.

    SciTech Connect (OSTI)

    Felver, Todd G.; Paradiso, Nicholas Joseph; Evans, Gregory Herbert; Rice, Steven F.; Winters, William Stanley, Jr.

    2010-07-01T23:59:59.000Z

    A series of experiments consisting of vessel-to-vessel transfers of pressurized gas using Transient PVT methodology have been conducted to provide a data set for optimizing heat transfer correlations in high pressure flow systems. In rapid expansions such as these, the heat transfer conditions are neither adiabatic nor isothermal. Compressible flow tools exist, such as NETFLOW that can accurately calculate the pressure and other dynamical mechanical properties of such a system as a function of time. However to properly evaluate the mass that has transferred as a function of time these computational tools rely on heat transfer correlations that must be confirmed experimentally. In this work new data sets using helium gas are used to evaluate the accuracy of these correlations for receiver vessel sizes ranging from 0.090 L to 13 L and initial supply pressures ranging from 2 MPa to 40 MPa. The comparisons show that the correlations developed in the 1980s from sparse data sets perform well for the supply vessels but are not accurate for the receivers, particularly at early time during the transfers. This report focuses on the experiments used to obtain high quality data sets that can be used to validate computational models. Part II of this report discusses how these data were used to gain insight into the physics of gas transfer and to improve vessel heat transfer correlations. Network flow modeling and CFD modeling is also discussed.

  13. Engineering properties of miniature cement - fly ash compacts prepared by high pressure compaction

    E-Print Network [OSTI]

    Bormann, Jeffrey Ray

    1985-01-01T23:59:59.000Z

    ENGINEERING PROPERTIES OF MINIATURE CEMENT - FLY ASH COMPACTS PREPARED BY HIGH PRESSURE COMPACTION E NGIRPR OT SFMMAFU AEU C-ALEYY HDOBPvvIi va vGI ge(iD(vI oannItI au NId(R E)L xrP1IeRPvT 9(evP(n uDnuPnnBIrv au vGI eI0DPeIBIrvR uae vGI i...?H?? NId(R E)L xrP1IeRPvT oG(PeB(r au Ei1PRaeT oaBBPvvII? ?e? ??C? ?IiOIvvIe oDeeIrv 9e(8vP8IR (ri vGIaeT 8aruaeB va vGI 8ar8I9v vG(v uae R9I8P(nP?Ii DRIR ( 9aevn(ri 8IBIrv 8ar8eIvI B(vIeP(n ?PvG RveIrtvG (99ea(8GPrt ?????? 9RP B(T OI 9eaiD8Ii OT eIiD8...

  14. High pressure pair distribution function studies of Green River oil shale.

    SciTech Connect (OSTI)

    Chapman, K. W.; Chupas, P. J.; Locke, D. R.; Winans, R. E.; Pugmire, R. J.; Univ. of Utah

    2008-01-01T23:59:59.000Z

    The compression behavior of a silicate-rich oil shale from the Green River formation in the pressure range 0.0-2.4 GPa was studied using in situ high pressure X-ray pair distribution function (PDF) measurements for the sample contained within a Paris-Edinburgh cell. The real-space local structural information in the PDF, G(r), was used to evaluate the compressibility of the oil shale. Specifically, the pressure-induced reduction in the medium- to long-range atom distances ({approx}6-20 {angstrom}) yielded an average sample compressibility corresponding to a bulk modulus of ca. 61-67 GPa. A structural model consisting of a three phase mixture of the principal crystalline oil shale components (quartz, albite and Illite) provided a good fit to the ambient pressure PDF data (R {approx} 30.7%). Indeed the features in the PDF beyond {approx} {angstrom}, were similarly well fit by a single phase model of the highest symmetry, highly crystalline quartz component. The factors influencing the observed compression behavior are discussed.

  15. Complete temperature profiles in ultra-high pressure liquid chromatography columns

    SciTech Connect (OSTI)

    Gritti, Fabrice [University of Tennessee, Knoxville (UTK); Guiochon, Georges A [ORNL

    2008-01-01T23:59:59.000Z

    The temperature profiles were calculated along and across seven packed columns (lengths 30, 50, 100, and 150 mm, i.d., 1 and 2.1 mm, all packed with Acquity UPLC, BEH-C{sub 18} particles, average d{sub p} {approx} 1.7 {micro}m) and their stainless steel tubes (o.d. 4.53 and 6.35 mm). These columns were kept horizontal and sheltered from forced air convection (i.e., under still air conditions), at room temperature. They were all percolated with pure acetonitrile, either under the maximum pressure drop (1034 bar) or at the maximum flow rate (2 mL/min) permitted by the chromatograph. The heat balance equation of chromatographic columns was discretized and solved numerically with minimum approximation. Both the compressibility and the thermal expansion of the eluent were taken into account. The boundary conditions were determined from the experimental measurements of the column inlet pressure and of the temperature profile along the column wall, which were made with a precision better than {+-}0.1 K. These calculation results provide the 3-D temperature profiles along and across the columns. The axial and radial temperature gradients are discussed in relationship with the experimental conditions used. The temperature map obtained permits a prediction of the chromatographic data obtained under a very high pressure gradient.

  16. Multi-temperature method for high-pressure sorption measurements on moist shales

    SciTech Connect (OSTI)

    Gasparik, Matus; Ghanizadeh, Amin; Gensterblum, Yves; Krooss, Bernhard M. [Energy and Mineral Resources Group (EMR), Institute of Geology and Geochemistry of Petroleum and Coal, Lochnerstr. 4-20, RWTH Aachen University, 52056 Aachen (Germany)] [Energy and Mineral Resources Group (EMR), Institute of Geology and Geochemistry of Petroleum and Coal, Lochnerstr. 4-20, RWTH Aachen University, 52056 Aachen (Germany)

    2013-08-15T23:59:59.000Z

    A simple and effective experimental approach has been developed and tested to study the temperature dependence of high-pressure methane sorption in moist organic-rich shales. This method, denoted as multi-temperature (short multi-T) method, enables measuring multiple isotherms at varying temperatures in a single run. The measurement of individual sorption isotherms at different temperatures takes place in a closed system ensuring that the moisture content remains constant. The multi-T method was successfully tested for methane sorption on an organic-rich shale sample. Excess sorption isotherms for methane were measured at pressures of up to 25 MPa and at temperatures of 318.1 K, 338.1 K, and 348.1 K on dry and moisture-equilibrated samples. The measured isotherms were parameterized with a 3-parameter Langmuir-based excess sorption function, from which thermodynamic sorption parameters (enthalpy and entropy of adsorption) were obtained. Using these, we show that by taking explicitly into account water vapor as molecular species in the gas phase with temperature-dependent water vapor pressure during the experiment, more meaningful results are obtained with respect to thermodynamical considerations. The proposed method can be applied to any adsorbent system (coals, shales, industrial adsorbents) and any supercritical gas (e.g., CH{sub 4}, CO{sub 2}) and is particularly suitable for sorption measurements using the manometric (volumetric) method.

  17. Method for cutting steam heat losses during cyclic steam injection of wells. Final report

    SciTech Connect (OSTI)

    Gondouin, M.

    1995-12-01T23:59:59.000Z

    Heavy Oil is abundant in California. It is a very viscous fluid, which must be thinned in order to flow from wells at economical rates. The best method of oil viscosity reduction is by cyclic steam injection into the oil-containing rock formations. Making steam in conventional generators fueled with Natural Gas is, however, a costly process. The main objective of this Project is to reduce the cost of the required steam, per Barrel of Oil produced. This is made possible by a combination of Patented new technologies with several known methods. The best known method for increasing the production rate from oil wells is to use horizontal drainholes, which provide a much greater flow area from the oil zone into the well. A recent statistic based on 344 horizontal wells in 21 Canadian Oil fields containing Heavy Oil shows that these are, on the average six times more prolific than vertical wells. The cost of horizontal wells, however, is generally two to three times that of a vertical well, in the same field, so our second goal is to reduce the net cost of horizontal wells by connecting two of them to the same vertical casing, well head and pumping system. With such a well configuration, it is possible to get two horizontal wells for the price of about one and a half times the price of a single vertical well.

  18. Design and Development of a Mid-Infrared Carbon Monoxide Sensor for a High-Pressure Combustor Rig

    E-Print Network [OSTI]

    Camou, Alejandro

    2014-05-03T23:59:59.000Z

    -strengths compared to the overtone bands near 2.3 ?m and 1.55 ?m. The mid-IR sensor was applied to a high-pressure combustor to determine the time-history of carbon monoxide and compare it to other measured combustor parameters to fully characterize the combustors...

  19. Mechanical behaviors and phase transition of Ho{sub 2}O{sub 3} nanocrystals under high pressure

    SciTech Connect (OSTI)

    Yan, Xiaozhi [Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065 (China); Center for High Pressure Science and Technology Advanced Research (HPSTAR), 1690 Cailun Rd., Pudong, Shanghai 201203 (China); Ren, Xiangting [Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065 (China); He, Duanwei, E-mail: duanweihe@scu.edu.cn, E-mail: yangwg@hpstar.ac.cn [Institute of Atomic and Molecular Physics, Sichuan University, Chengdu 610065 (China); Institute of Fluid Physics and National Key Laboratory of Shockwave and Detonation Physic, China Academy of Engineering Physics, Mianyang 621900 (China); Chen, Bin [Center for High Pressure Science and Technology Advanced Research (HPSTAR), 1690 Cailun Rd., Pudong, Shanghai 201203 (China); Yang, Wenge, E-mail: duanweihe@scu.edu.cn, E-mail: yangwg@hpstar.ac.cn [Center for High Pressure Science and Technology Advanced Research (HPSTAR), 1690 Cailun Rd., Pudong, Shanghai 201203 (China); High Pressure Synergetic Consortium (HPSynC), Geophysical Laboratory, Carnegie Institution of Washington, 9700 S Cass Avenue, Argonne, Illinois 60439 (United States)

    2014-07-21T23:59:59.000Z

    Mechanical properties and phase transition often show quite large crystal size dependent behavior, especially at nanoscale under high pressure. Here, we have investigated Ho{sub 2}O{sub 3} nanocrystals with in-situ x-ray diffraction and Raman spectroscopy under high pressure up to 33.5?GPa. When compared to the structural transition routine cubic -> monoclinic -> hexagonal phase in bulk Ho{sub 2}O{sub 3} under high pressure, the nano-sized Ho{sub 2}O{sub 3} shows a much higher onset transition pressure from cubic to monoclinic structure and followed by a pressure-induced-amorphization under compression. The detailed analysis on the Q (Q?=?2?/d) dependent bulk moduli reveals the nanosized Ho{sub 2}O{sub 3} particles consist of a clear higher compressible shell and a less compressible core. Insight into these phenomena shed lights on micro-mechanism studies of the mechanical behavior and phase evolution for nanomaterials under high pressure, in general.

  20. High-pressure X-ray absorption fine structure in the diamond anvil cell and its applications in geological materials

    E-Print Network [OSTI]

    Duffy, Thomas S.

    nano- polycrystalline diamond instead of single crystal anvils, the influence of diamond diffractionHigh-pressure X-ray absorption fine structure in the diamond anvil cell and its applications fine structure in the diamond anvil cell and its applications in geological materials Xinguo Hong1

  1. Vehicle Technologies Office 2013 Merit Review: A University Consortium on Efficient and Clean High-Pressure, Lean Burn (HPLB) Engines

    Broader source: Energy.gov [DOE]

    A presentation given by the University of Michigan at the 2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting about a university consortium to research efficient and clean high-pressure lean burn engines.

  2. Iron under Earth's core conditions: Liquid-state thermodynamics and high-pressure melting curve from ab initio calculations

    E-Print Network [OSTI]

    Alfè, Dario

    Hugoniot curves cross the melting line, and the sound speed and Gru¨neisen parameter along the HugoniotIron under Earth's core conditions: Liquid-state thermodynamics and high-pressure melting curve-augmented-wave implementation are used to calculate the free energy and a range of other thermodynamic properties of liquid iron

  3. High pressure synthesis of late rare earth RFeAs(O,F) superconductors; R = Tb and Dy

    E-Print Network [OSTI]

    Attfield, J.P.; Huxley A.D.; Sokolov D.A.; Rodgers J.A.; Penny G.B.S.; Bos J.W.G.

    2008-01-01T23:59:59.000Z

    New TbFeAs(O,F) and DyFeAs(O,F) superconductors with critical temperatures T-c = 46 and 45 K and very high critical fields, >= 100 T, have been prepared at 1100-1150 degrees C and 10-12 GPa, demonstrating that high pressure ...

  4. ACS Div of Fuel Chem Preprints 44:4, 1016-1019 (August, 1999) KINETICS OF HIGH PRESSURE CHAR OXIDATION

    E-Print Network [OSTI]

    Fletcher, Thomas H.

    ACS Div of Fuel Chem Preprints 44:4, 1016-1019 (August, 1999) KINETICS OF HIGH PRESSURE CHAR) by devolatilizing Pittsburgh #8 coal at #12;ACS Div of Fuel Chem Preprints 44:4, 1016-1019 (August, 1999) high

  5. Incorporating supercritical steam turbines into molten-salt power tower plants : feasibility and performance.

    SciTech Connect (OSTI)

    Pacheco, James Edward; Wolf, Thorsten [Siemens Energy, Inc., Orlando, FL; Muley, Nishant [Siemens Energy, Inc., Orlando, FL

    2013-03-01T23:59:59.000Z

    Sandia National Laboratories and Siemens Energy, Inc., examined 14 different subcritical and supercritical steam cycles to determine if it is feasible to configure a molten-salt supercritical steam plant that has a capacity in the range of 150 to 200 MWe. The effects of main steam pressure and temperature, final feedwater temperature, and hot salt and cold salt return temperatures were determined on gross and half-net efficiencies. The main steam pressures ranged from 120 bar-a (subcritical) to 260 bar-a (supercritical). Hot salt temperatures of 566 and 600%C2%B0C were evaluated, which resulted in main steam temperatures of 553 and 580%C2%B0C, respectively. Also, the effects of final feedwater temperature (between 260 and 320%C2%B0C) were evaluated, which impacted the cold salt return temperature. The annual energy production and levelized cost of energy (LCOE) were calculated using the System Advisory Model on 165 MWe subcritical plants (baseline and advanced) and the most promising supercritical plants. It was concluded that the supercritical steam plants produced more annual energy than the baseline subcritical steam plant for the same-size heliostat field, receiver, and thermal storage system. Two supercritical steam plants had the highest annual performance and had nearly the same LCOE. Both operated at 230 bar-a main steam pressure. One was designed for a hot salt temperature of 600%C2%B0C and the other 565%C2%B0C. The LCOEs for these plants were about 10% lower than the baseline subcritical plant operating at 120 bar-a main steam pressure and a hot salt temperature of 565%C2%B0C. Based on the results of this study, it appears economically and technically feasible to incorporate supercritical steam turbines in molten-salt power tower plants.

  6. High pressure sulfuric acid decomposition experiments for the sulfur-iodine thermochemical cycle.

    SciTech Connect (OSTI)

    Velasquez, Carlos E; Reay, Andrew R.; Andazola, James C.; Naranjo, Gerald E.; Gelbard, Fred

    2005-09-01T23:59:59.000Z

    A series of three pressurized sulfuric acid decomposition tests were performed to (1) obtain data on the fraction of sulfuric acid catalytically converted to sulfur dioxide, oxygen, and water as a function of temperature and pressure, (2) demonstrate real-time measurements of acid conversion for use as process control, (3) obtain multiple measurements of conversion as a function of temperature within a single experiment, and (4) assess rapid quenching to minimize corrosion of metallic components by undecomposed acid. All four of these objectives were successfully accomplished. This report documents the completion of the NHI milestone on high pressure H{sub 2}SO{sub 4} decomposition tests for the Sulfur-Iodine (SI) thermochemical cycle project. All heated sections of the apparatus, (i.e. the boiler, decomposer, and condenser) were fabricated from Hastelloy C276. A ceramic acid injection tube and a ceramic-sheathed thermocouple were used to minimize corrosion of hot liquid acid on the boiler surfaces. Negligible fracturing of the platinum on zirconia catalyst was observed in the high temperature decomposer. Temperature measurements at the exit of the decomposer and at the entry of the condenser indicated that the hot acid vapors were rapidly quenched from about 400 C to less than 20 C within a 14 cm length of the flow path. Real-time gas flow rate measurements of the decomposition products provided a direct measurement of acid conversion. Pressure in the apparatus was preset by a pressure-relief valve that worked well at controlling the system pressure. However, these valves sometimes underwent abrupt transitions that resulted in rapidly varying gas flow rates with concomitant variations in the acid conversion fraction.

  7. Development of high temperature, high pressure rotating shaft seals: Final report

    SciTech Connect (OSTI)

    Heshmat, H.; Shapiro, W.

    1987-06-01T23:59:59.000Z

    Rotating shaft seals used in coal gasification equipment are exposed to difficult environmental conditions including temperature from 430/sup 0/C to 816/sup 0/C (800/sup 0/F to 1500/sup 0/F), high pressure (to 10 MPa or 1500 psig), and high levels of particulate contamination (50,000 to 100,000 ppM). The program reported upon was designed to develop long-life seals that would not require external flushing or cooling. The approach taken was to develop unbalanced face that would remain closed and prevent particulate entry into the interface. Wear resistant materials and coatings with low friction coefficients are required. Significant results of the program are enumerated: The selected material combination was a rotating runner of Kentanium K162B mating against a non-rotating seal ring of Kentanium K162B. Kentanium is the trade name of a series of hard carbide alloys with pure titanium carbide as the principal ingredient. Nickel and nickel molybdenum are used as binder materials. Kentanium retains most of its strength at temperatures ..mu..p to 1100/sup 0/C (2000/sup 0/F). Since hard materials are required to resist wear and withstand the temperatures, mechanical compliance must be built into the seal configuration for the opposed faces to follow runner nutations and remain closed. Environmental and frictional heating caused the formation of very small particles of titanium oxide which lodged in the face wave formations and acted as an interfacial lubricant. The results of this program provide encouragement and optimism that dry contact face seals can be developed for long unattended operation in the hostile environment of a coal gasification plant. 40 refs., 98 figs., 20 tabs.

  8. Steam Conservation and Boiler Plant Efficiency Advancements

    E-Print Network [OSTI]

    Fiorino, D. P.

    This paper examines several cost-effective steam conservation and boiler plant efficiency advancements that were implemented during a recently completed central steam boiler plant replacement project at a very large semiconductor manufacturing...

  9. Compressor & Steam Turbine Efficiency Improvements & Revamping Opportunities

    E-Print Network [OSTI]

    Hata, S.; Horiba, J.; Sicker, M.

    2011-01-01T23:59:59.000Z

    of the plant and introduce the history of efficiency improvements for compressors and steam turbines in the Petrochemical Industry. Since heat balance configurations affect the plant's steam consumption, the authors will explain several cases of heat balance...

  10. Compressor & Steam Turbine Efficiency Improvements & Revamping Opportunities

    E-Print Network [OSTI]

    Hata, S.; Horiba, J.; Sicker, M.

    2011-01-01T23:59:59.000Z

    of the plant and introduce the history of efficiency improvements for compressors and steam turbines in the Petrochemical Industry. Since heat balance configurations affect the plant's steam consumption, the authors will explain several cases of heat balance...

  11. The Economics of Steam Electric Generation

    E-Print Network [OSTI]

    Ophaug, R. A.; Birget, C. D.

    1980-01-01T23:59:59.000Z

    The economics of combining steam and electric generation for companies requiring both steam and electric services develop a challenge which few engineers and economists can realize. This paper outlines the general approach to this challenge...

  12. Training: Steam Systems | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Steam Systems Training: Steam Systems April 16, 2014 - 6:31pm Addthis Learn about the diverse training sessions offered. The courses are taught by highly qualified instructors who...

  13. DOE's BestPractices Steam End User Training Steam End User Training

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    DOE's BestPractices Steam End User Training Steam End User Training Navigational Tutorial - 1 8/27/2010 Steam End User Training Navigational Tutorial Module Slide 1 Introduction Hello, and welcome to the Steam End User Training. I would like to take a few minutes to show you how to navigate through

  14. DOE's BestPractices Steam End User Training Steam End User Training

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    DOE's BestPractices Steam End User Training Steam End User Training Introduction Module - 1 8/27/2010 Steam End User Training Introduction Module Slide 1 - Introduction Title Page Hello, and welcome to the Steam System End User training. In this training, we will investigate how to assess, evaluate

  15. Identifying Steam Opportunity "Impact" Inputs for the Steam System Assessment Tool (SSAT)

    E-Print Network [OSTI]

    Harrell, G.; Jendrucko, R.; Wright, A.

    2004-01-01T23:59:59.000Z

    The U.S. DOE BestPractices Steam "Steam System Assessment Tool" (SSAT) is a powerful tool for quantifying potential steam improvement opportunities in steam systems. However, all assessment tools are only as good as the validity of the modeling...

  16. Optimisation of Fuel Usage and Steam Availability in the Power and Steam

    E-Print Network [OSTI]

    Cambridge, University of

    the medium pressure manifold (nominally operated at 14 bar), through a steam turbine that can be usedOptimisation of Fuel Usage and Steam Availability in the Power and Steam Plant of a Paper Mill KEYWORDS: Model Predictive Control, Improved Efficiency, Optimisation, Power and Steam Supply System

  17. FLUIDIZED BED STEAM REFORMER MONOLITH FORMATION

    SciTech Connect (OSTI)

    Jantzen, C

    2006-12-22T23:59:59.000Z

    Fluidized Bed Steam Reforming (FBSR) is being considered as an alternative technology for the immobilization of a wide variety of aqueous high sodium containing radioactive wastes at various DOE facilities in the United States. The addition of clay, charcoal, and a catalyst as co-reactants converts aqueous Low Activity Wastes (LAW) to a granular or ''mineralized'' waste form while converting organic components to CO{sub 2} and steam, and nitrate/nitrite components, if any, to N{sub 2}. The waste form produced is a multiphase mineral assemblage of Na-Al-Si (NAS) feldspathoid minerals with cage-like structures that atomically bond radionuclides like Tc-99 and anions such as SO{sub 4}, I, F, and Cl. The granular product has been shown to be as durable as LAW glass. Shallow land burial requires that the mineralized waste form be able to sustain the weight of soil overburden and potential intrusion by future generations. The strength requirement necessitates binding the granular product into a monolith. FBSR mineral products were formulated into a variety of monoliths including various cements, Ceramicrete, and hydroceramics. All but one of the nine monoliths tested met the <2g/m{sup 2} durability specification for Na and Re (simulant for Tc-99) when tested using the Product Consistency Test (PCT; ASTM C1285). Of the nine monoliths tested the cements produced with 80-87 wt% FBSR product, the Ceramicrete, and the hydroceramic produced with 83.3 wt% FBSR product, met the compressive strength and durability requirements for an LAW waste form.

  18. Steam Systems | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33Frequently AskedEnergyIssues DOE's NuclearSpurringSteam Systems Steam Systems Many

  19. ORIGINAL ARTICLE Characterization of the cellulolytic and hydrogen-producing

    E-Print Network [OSTI]

    or acid rain (Nath and Das 2004). Moreover, H2 can be produced biologically from renew- able resources this efficiently through physicochemical techniques such as steam explo- sion and dilute-acid pretreatment, as well

  20. Capturing Energy Savings with Steam Traps

    E-Print Network [OSTI]

    Bockwinkel, R. G.; French, S. A.

    , it's important to select and install the correct type and size steam trap for each application. This means a corruninnent must be made to training those who select, install, test and maintain steam traps on a. daily Scott A. French Application... generated. This paper will review each of these topics and then explore some of the new services, products, practices and technology available to help you maintain or improve the efficiency of your steam system. COSTLY STEAM LEAKS ENERGY RESOURCES...

  1. ProSteam- A Structured Approach to Steam System Improvement

    E-Print Network [OSTI]

    Eastwood, A.

    and of any operational constraints. It can also be used to determine the true cost of improvement projects, relating any changes in steam demand back to purchased utilities (fuel, power, and make-up water) at the site boundary. Example projects could include...

  2. Best Management Practice #8: Steam Boiler Systems

    Broader source: Energy.gov [DOE]

    Boilers and steam generators are commonly used in large heating systems, institutional kitchens, or in facilities where large amounts of process steam are used. This equipment consumes varying amounts of water depending on system size, the amount of steam used, and the amount of condensate returned.

  3. STEAM-WATER RELATIVE PERMEABILITY A DISSERTATION

    E-Print Network [OSTI]

    Stanford University

    STEAM-WATER RELATIVE PERMEABILITY A DISSERTATION SUBMITTED TO THE DEPARTMENT OF PETROLEUM Laboratory. iv #12;ABSTRACT Steam-water relative permeability curves are required for mathematical models of two-phase geothermal reservoirs. In this study, drainage steam- water relative permeabilities were

  4. Steam Sterilization Cycles for Lab Applications

    E-Print Network [OSTI]

    Farritor, Shane

    Steam Sterilization Cycles for Lab Applications Presented by Gary Butler STERIS Life Sciences August 2009 #12;Early Steam Sterilizers Koch Upright Sterilizer · First Pressurized Sterilizer · First OPERATING END (NO PRINTER) PRIMARY OPERATING END WITH PRINTER SAFETY VALVE CHAMBER PRESSURE GAUGE Steam

  5. Reviving Abandoned Reservoirs with High-Pressure Air Injection: Application in a Fractured and Karsted Dolomite Reservoir

    SciTech Connect (OSTI)

    Robert Loucks; Stephen C. Ruppel; Dembla Dhiraj; Julia Gale; Jon Holder; Jeff Kane; Jon Olson; John A. Jackson; Katherine G. Jackson

    2006-09-30T23:59:59.000Z

    Despite declining production rates, existing reservoirs in the United States contain vast volumes of remaining oil that is not being effectively recovered. This oil resource constitutes a huge target for the development and application of modern, cost-effective technologies for producing oil. Chief among the barriers to the recovery of this oil are the high costs of designing and implementing conventional advanced recovery technologies in these mature, in many cases pressure-depleted, reservoirs. An additional, increasingly significant barrier is the lack of vital technical expertise necessary for the application of these technologies. This lack of expertise is especially notable among the small operators and independents that operate many of these mature, yet oil-rich, reservoirs. We addressed these barriers to more effective oil recovery by developing, testing, applying, and documenting an innovative technology that can be used by even the smallest operator to significantly increase the flow of oil from mature U.S. reservoirs. The Bureau of Economic Geology and Goldrus Producing Company assembled a multidisciplinary team of geoscientists and engineers to evaluate the applicability of high-pressure air injection (HPAI) in revitalizing a nearly abandoned carbonate reservoir in the Permian Basin of West Texas. The Permian Basin, the largest oil-bearing basin in North America, contains more than 70 billion barrels of remaining oil in place and is an ideal venue to validate this technology. We have demonstrated the potential of HPAI for oil-recovery improvement in preliminary laboratory tests and a reservoir pilot project. To more completely test the technology, this project emphasized detailed characterization of reservoir properties, which were integrated to access the effectiveness and economics of HPAI. The characterization phase of the project utilized geoscientists and petroleum engineers from the Bureau of Economic Geology and the Department of Petroleum Engineering (both at The University of Texas at Austin) to define the controls on fluid flow in the reservoir as a basis for developing a reservoir model. The successful development of HPAI technology has tremendous potential for increasing the flow of oil from deep carbonate reservoirs in the Permian Basin, a target resource that can be conservatively estimated at more than 1.5 billion barrels. Successful implementation in the field chosen for demonstration, for example, could result in the recovery of more than 34 million barrels of oil that will not otherwise be produced. Geological and petrophysical analysis of available data at Barnhart field reveals the following important observations: (1) the Barnhart Ellenburger reservoir is similar to most other Ellenburger reservoirs in terms of depositional facies, diagenesis, and petrophysical attributes; (2) the reservoir is characterized by low to moderate matrix porosity much like most other Ellenburger reservoirs in the Permian Basin; (3) karst processes (cave formation, infill, and collapse) have substantially altered stratigraphic architecture and reservoir properties; (4) porosity and permeability increase with depth and may be associated with the degree of karst-related diagenesis; (5) tectonic fractures overprint the reservoir, improving overall connectivity; (6) oil-saturation profiles show that the oil-water contact (OWC) is as much as 125 ft lower than previous estimations; (7) production history and trends suggest that this reservoir is very similar to other solution-gas-drive reservoirs in the Permian Basin; and (8) reservoir simulation study showed that the Barnhart reservoir is a good candidate for HPAI and that application of horizontal-well technology can improve ultimate resource recovery from the reservoir.

  6. DECOMMISSIONING THE HIGH PRESSURE TRITIUM LABORATORY AT LOS ALAMOS NATIONAL LABORATORY

    SciTech Connect (OSTI)

    Peifer, M.J.; Rendell, K.; Hearnsberger, D.W.

    2003-02-27T23:59:59.000Z

    In May 0f 2000, the Cerro Grande wild land fire burned approximately 48,000 acres in and around Los Alamos. In addition to the many buildings that were destroyed in the town site, many structures were also damaged and destroyed within the 43 square miles that comprise the Los Alamos National Laboratory (LANL). A special Act of Congress provided funding to remove Laboratory structures that were damaged by the fire, or that could be threatened by subsequent catastrophic wild land fires. The High Pressure Tritium Laboratory (HPTL) is located at Technical Area (TA) 33, building 86 in the far southeast corner of the Laboratory property. It is immediately adjacent to Bandelier National Park. Because it was threatened by both the Cerro Grande fire in 2000, and the 16,000- acre Dome fire in 1996, the former tritium processing facility was placed on the list of facilities scheduled for Decontamination and Decommissioning under the Cerro Grande Rehabilitation Project. The work was performed through the Facilities and Waste Operations (FWO) Division and is integrated with other Laboratory D&D efforts. The primary demolition contractor was Clauss Construction of San Diego, California. Earth Tech Global Environmental Services of San Antonio, Texas was sub-contracted to Clauss Construction, and provided radiological decontamination support to the project. Although the forty-seven year old facility had been in a state of safe-shutdown since operations ceased in 1990, a significant amount of tritium remained in the rooms where process systems were located. Tritium was the only radiological contaminant associated with this facility. Since no specific regulatory standards have been set for the release of volumetrically contaminated materials, concentration guidelines were derived in order to meet other established regulatory criteria. A tritium removal system was developed for this project with the goal of reducing the volume of tritium concentrated in the concrete of the building. The derived concentration guidelines, combined with the tritium removal system that was developed for this project, provided a significant timesaving for decontamination as well as an overall cost savings for waste disposal.

  7. Ultra high pressure liquid chromatography column permeability and changes of the eluent properties

    SciTech Connect (OSTI)

    Gritti, Fabrice [University of Tennessee, Knoxville (UTK); Guiochon, Georges A [ORNL

    2008-01-01T23:59:59.000Z

    The behavior of four similar liquid chromatography columns (2.1 mm i.d. x30, 50, 100, and 150 mm, all packed with fine particles, average d{sub p} {approx} 1.7 {micro}m, of bridged ethylsiloxane/silica hybrid-C{sub 18}, named BEH-C{sub 18}) was studied in wide ranges of temperature and pressure. The pressure and the temperature dependencies of the viscosity and the density of the eluent (pure acetonitrile) along the columns were also derived, using the column permeabilities and applying the Kozeny-Carman and the heat balance equations. The heat lost through the external surface area of the chromatographic column was directly derived from the wall temperature of the stainless steel tube measured with a precision of C in still air and C in the oven compartment. The variations of the density and viscosity of pure acetonitrile as a function of the temperature and pressure was derived from empirical correlations based on precise experimental data acquired between 298 and 373 K and at pressures up to 1.5 kbar. The measurements were made with the Acquity UPLC chromatograph that can deliver a maximum flow rate of 2 mL/min and apply a maximum column inlet pressure of 1038 bar. The average Kozeny-Carman permeability constant of the columns was 144 {+-} 3.5%. The temperature hence the viscosity and the density profiles of the eluent along the column deviate significantly from linear behavior under high-pressure gradients. For a 1000 bar pressure drop, we measured {Delta}T = 25-30 K, ({Delta}{eta}/{eta}) {approx_equal} 100%, and ({Delta}{rho}/{rho}) {approx_equal} 10%. These results show that the radial temperature profiles are never fully developed within 1% for any of the columns, even under still-air conditions. This represents a practical advantage regarding the apparent column efficiency at high flow rates, since the impact of the differential analyte velocity between the column center and the column wall is not maximum. The interpretation of the peak profiles recorded in UPLC is discussed.

  8. New downhole steam generator tested

    SciTech Connect (OSTI)

    Bleakley, W.B.

    1981-07-01T23:59:59.000Z

    Completion of 2 field tests of a new-model down-hole steam generator paves the way for further evaluation and development of a system destined to increase California's heavy oil production. Current air pollution restrictions there prevent installation of conventional steam generators in several areas of interest to oil operators. The current series of tests, conducted by Chemical Oil Recovery Co. (CORCO) of Bakersfield, California, follows an earlier prototype operation conducted by Sandia National Laboratories in conjunction with the US Department of Energy. The CORCO tests were conducted on the surface with the generator's output going into Tenneco Oil Exploration and Production Co.'s overland-Riokern Well No. 80, located in the Kern River field 4 miles north of Bakersfield. The first test was concluded with just under 1000 bbl of steam injected, less than planned due to a higher-than-expected injection pressure. The unit operated at less than 25% capacity because of the air compressor limitation. Compressor output was only 285 psi, not enough to inject the desired volumes into the reservoir. Test data shows that injection amounted to 150 bpd of 90 to 95% quality steam at 225-psi wellhead pressure. After injection, the well was shut in for 3 days to allow soaking, then put on production. Initial production was 40 bopd at 175 F.

  9. Geismar TDI Plant Steam Optimization

    E-Print Network [OSTI]

    Baily, M.

    2013-01-01T23:59:59.000Z

    Inlet isolation valve o Outlet isolation valve o Built-in strainer o Upstream blow down o Downstream blow down (or test port) o 2-bolt connection for K port steam trap ? Valves on V2 stations are bellows sealed valves ? high integrity seal...

  10. Generating Steam by Waste Incineration

    E-Print Network [OSTI]

    Williams, D. R.; Darrow, L. A.

    1981-01-01T23:59:59.000Z

    Combustible waste is a significant source of steam at the new John Deere Tractor Works assembly plant in Waterloo, Iowa. The incinerators, each rated to consume two tons of solid waste per hour, are expected to provide up to 100 percent of the full...

  11. Fixed Bed Counter Current Gasification of Mesquite and Juniper Biomass Using Air-steam as Oxidizer

    E-Print Network [OSTI]

    Chen, Wei 1981-

    2012-11-27T23:59:59.000Z

    contains high percentage of Nitrogen, the heating value of the gasification gas is very low. The oxygen-blow gasification produce a syngas with medium heating value and steam blow gasification lead to the production of a syngas with an acceptable HHV... schematic flow diagram of an integrated Gasification Combined Cycle (IGCC) plan. Coal, heavy petroleum residues, or biomass is gasified in the gasifier using air or steam media to generate syngas under high temperature and pressure. The syngas was first...

  12. High pressure elastic properties of minerals from ab initio simulations: The case of pyrope, grossular and andradite silicate garnets

    SciTech Connect (OSTI)

    Erba, A., E-mail: alessandro.erba@unito.it; Mahmoud, A.; Dovesi, R. [Dipartimento di Chimica and Centre of Excellence NIS (Nanostructured Interfaces and Surfaces), Universit di Torino, via Giuria 5, IT-10125 Torino (Italy)] [Dipartimento di Chimica and Centre of Excellence NIS (Nanostructured Interfaces and Surfaces), Universit di Torino, via Giuria 5, IT-10125 Torino (Italy); Belmonte, D. [DISTAV, Universit di Genova, Corso Europa 26, 16132 Genoa (Italy)] [DISTAV, Universit di Genova, Corso Europa 26, 16132 Genoa (Italy)

    2014-03-28T23:59:59.000Z

    A computational strategy is devised for the accurate ab initio simulation of elastic properties of crystalline materials under pressure. The proposed scheme, based on the evaluation of the analytical stress tensor and on the automated computation of pressure-dependent elastic stiffness constants, is implemented in the CRYSTAL solid state quantum-chemical program. Elastic constants and related properties (bulk, shear and Young moduli, directional seismic wave velocities, elastic anisotropy index, Poisson's ratio, etc.) can be computed for crystals of any space group of symmetry. We apply such a technique to the study of high-pressure elastic properties of three silicate garnet end-members (namely, pyrope, grossular, and andradite) which are of great geophysical interest, being among the most important rock-forming minerals. The reliability of this theoretical approach is proved by comparing with available experimental measurements. The description of high-pressure properties provided by several equations of state is also critically discussed.

  13. Consider Installing High-Pressure Boilers with Backpressure Turbine-Generators, Energy Tips: STEAM, Steam Tip Sheet #22 (Fact Sheet), Advanced Manufacturing Office (AMO), Energy Efficiency & Renewable Energy (EERE)

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742Energy China U.S. DepartmentEnergy This partAs theFebruary09 FY1, 20005, 2013April 21,

  14. High-pressure synthesis and structure of a new aurate, CaAu{sub 2}O{sub 4}

    SciTech Connect (OSTI)

    Park, J.H.; Parise, J.B. [State Univ. of New York, Stony Brook, NY (United States)

    1995-06-01T23:59:59.000Z

    A novel aurate, CaAu{sub 2}O{sub 4}, after synthesis under high-pressure conditions was recovered to room temperature by quenching. The structure, determined with synchrotron powder X-ray diffraction and single-crystal X-ray data by model building, was refined using the Rietveld techniques. It contains corner-shared AuO{sub 4} square planes and CaO{sub 8} dodecahedra. 25 refs., 2 figs., 1 tab.

  15. The effect of condensate dropout on pressure transient analysis of a high-pressure gas condensate well

    E-Print Network [OSTI]

    Briens, Frederic Jean-Louis

    1986-01-01T23:59:59.000Z

    of drawdown or buildup tests, the formation permeability can be estimated. Although these conventional techniques have been successfully applied to 'dry' gas well analysis, they have not been extended to high-pressure gas condensate wells. The application... Condensate Reser voir Data. . 43 Elf Aquitaine Gas Condensate Reservoir Fluid Composition Elf Aquitaine Gas Condensate Well Production Test Data. Drawdown Test F1 of Elf Aquitaine Gas Condensate Mell 45 46 Drawdown Test F2 of Elf Aquitaine Gas...

  16. High-pressure sound velocities and elasticity of aluminous MgSiO3 perovskite to 45 GPa: Implications for lateral heterogeneity in Earth's

    E-Print Network [OSTI]

    Jackson, Jennifer M.

    High-pressure sound velocities and elasticity of aluminous MgSiO3 perovskite to 45 GPa lateral variations of seismic wave speeds in Earth's lower mantle are due at least in part to a chemical, J. M., J. Zhang, J. Shu, S. V. Sinogeikin, and J. D. Bass (2005), High-pressure sound velocities

  17. Thermodynamics of Hydrogen Production from Dimethyl Ether Steam Reforming and Hydrolysis

    SciTech Connect (OSTI)

    T.A. Semelsberger

    2004-10-01T23:59:59.000Z

    The thermodynamic analyses of producing a hydrogen-rich fuel-cell feed from the process of dimethyl ether (DME) steam reforming were investigated as a function of steam-to-carbon ratio (0-4), temperature (100 C-600 C), pressure (1-5 atm), and product species: acetylene, ethanol, methanol, ethylene, methyl-ethyl ether, formaldehyde, formic acid, acetone, n-propanol, ethane and isopropyl alcohol. Results of the thermodynamic processing of dimethyl ether with steam indicate the complete conversion of dimethyl ether to hydrogen, carbon monoxide and carbon dioxide for temperatures greater than 200 C and steam-to-carbon ratios greater than 1.25 at atmospheric pressure (P = 1 atm). Increasing the operating pressure was observed to shift the equilibrium toward the reactants; increasing the pressure from 1 atm to 5 atm decreased the conversion of dimethyl ether from 99.5% to 76.2%. The order of thermodynamically stable products in decreasing mole fraction was methane, ethane, isopropyl alcohol, acetone, n-propanol, ethylene, ethanol, methyl-ethyl ether and methanol--formaldehyde, formic acid, and acetylene were not observed. The optimal processing conditions for dimethyl ether steam reforming occurred at a steam-to-carbon ratio of 1.5, a pressure of 1 atm, and a temperature of 200 C. Modeling the thermodynamics of dimethyl ether hydrolysis (with methanol as the only product considered), the equilibrium conversion of dimethyl ether is limited. The equilibrium conversion was observed to increase with temperature and steam-to-carbon ratio, resulting in a maximum dimethyl ether conversion of approximately 68% at a steam-to-carbon ratio of 4.5 and a processing temperature of 600 C. Thermodynamically, dimethyl ether processed with steam can produce hydrogen-rich fuel-cell feeds--with hydrogen concentrations exceeding 70%. This substantiates dimethyl ether as a viable source of hydrogen for PEM fuel cells.

  18. Steam cooling system for a gas turbine

    DOE Patents [OSTI]

    Wilson, Ian David (Mauldin, SC); Barb, Kevin Joseph (Halfmoon, NY); Li, Ming Cheng (Cincinnati, OH); Hyde, Susan Marie (Schenectady, NY); Mashey, Thomas Charles (Coxsackie, NY); Wesorick, Ronald Richard (Albany, NY); Glynn, Christopher Charles (Hamilton, OH); Hemsworth, Martin C. (Cincinnati, OH)

    2002-01-01T23:59:59.000Z

    The steam cooling circuit for a gas turbine includes a bore tube assembly supplying steam to circumferentially spaced radial tubes coupled to supply elbows for transitioning the radial steam flow in an axial direction along steam supply tubes adjacent the rim of the rotor. The supply tubes supply steam to circumferentially spaced manifold segments located on the aft side of the 1-2 spacer for supplying steam to the buckets of the first and second stages. Spent return steam from these buckets flows to a plurality of circumferentially spaced return manifold segments disposed on the forward face of the 1-2 spacer. Crossover tubes couple the steam supply from the steam supply manifold segments through the 1-2 spacer to the buckets of the first stage. Crossover tubes through the 1-2 spacer also return steam from the buckets of the second stage to the return manifold segments. Axially extending return tubes convey spent cooling steam from the return manifold segments to radial tubes via return elbows.

  19. First principle study of elastic and thermodynamic properties of FeB{sub 4} under high pressure

    SciTech Connect (OSTI)

    Zhang, Xinyu, E-mail: xyzhang@ysu.edu.cn, E-mail: jiaqianqin@gmail.com, E-mail: riping@ysu.edu.cn; Ning, Jinliang; Sun, Xiaowei; Li, Xinting; Ma, Mingzhen; Liu, Riping, E-mail: xyzhang@ysu.edu.cn, E-mail: jiaqianqin@gmail.com, E-mail: riping@ysu.edu.cn [State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 (China); Qin, Jiaqian, E-mail: xyzhang@ysu.edu.cn, E-mail: jiaqianqin@gmail.com, E-mail: riping@ysu.edu.cn [Metallurgy and Materials Science Research Institute, Chulalongkorn University, Bangkok 10330 (Thailand); State Key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao 066004 (China)

    2013-11-14T23:59:59.000Z

    The elastic properties, elastic anisotropy, and thermodynamic properties of the lately synthesized orthorhombic FeB{sub 4} at high pressures are investigated using first-principles density functional calculations. The calculated equilibrium parameters are in good agreement with the available experimental and theoretical data. The obtained normalized volume dependence of high pressure is consistent with the previous experimental data investigated using high-pressure synchrotron x-ray diffraction. The complete elastic tensors and crystal anisotropies of the FeB{sub 4} are also determined in the pressure range of 0100?GPa. By the elastic stability criteria and vibrational frequencies, it is predicted that the orthorhombic FeB{sub 4} is stable up to 100 GPa. In addition, the calculated B/G ratio reveals that FeB{sub 4} possesses brittle nature in the range of pressure from 0 to 100?GPa. The calculated elastic anisotropic factors suggest that FeB{sub 4} is elastically anisotropic. By using quasi-harmonic Debye model, the compressibility, bulk modulus, the coefficient of thermal expansion, the heat capacity, and the Grneisen parameter of FeB{sub 4} are successfully obtained in the present work.

  20. Cast Alloys for Advanced Ultra Supercritical Steam Turbines

    SciTech Connect (OSTI)

    G. R. Holcomb, P. Wang, P. D. Jablonski, and J. A. Hawk,

    2010-05-01T23:59:59.000Z

    The proposed steam inlet temperature in the Advanced Ultra Supercritical (A-USC) steam turbine is high enough (760 C) that traditional turbine casing and valve body materials such as ferritic/martensitic steels will not suffice due to temperature limitations of this class of materials. Cast versions of several traditionally wrought Ni-based superalloys were evaluated for use as casing or valve components for the next generation of industrial steam turbines. The full size castings are substantial: 2-5,000 kg each half and on the order of 100 cm thick. Experimental castings were quite a bit smaller, but section size was retained and cooling rate controlled to produce equivalent microstructures. A multi-step homogenization heat treatment was developed to better deploy the alloy constituents. The most successful of these cast alloys in terms of creep strength (Haynes 263, Haynes 282, and Nimonic 105) were subsequently evaluated by characterizing their microstructure as well as their steam oxidation resistance (at 760 and 800 C).

  1. Hydrogen Selective Inorganic membranes for Gas Separations under High Pressure Intermediate Temperature Hydrocarbonic Envrionment

    SciTech Connect (OSTI)

    Rich Ciora; Paul KT Liu

    2012-06-27T23:59:59.000Z

    In this project, we have successfully developed a full scale commercially ready carbon molecular sieve (CMS) based membrane for applications in H{sub 2} recovery from refinery waste and other aggressive gas streams. Field tests at a refinery pilot plant and a coal gasification facility have successfully demonstrated its ability to recovery hydrogen from hydrotreating and raw syngas respectively. High purity H{sub 2} and excellent stability of the membrane permeance and selectivity were obtained in testing conducted over >500 hours at each site. The results from these field tests as well as laboratory testing conclude that the membranes can be operated at high pressures (up to 1,000 psig) and temperatures (up to 300 C) in presence of aggressive contaminants, such as sulfur and nitrogen containing species (H{sub 2}S, CO{sub 2}, NH{sub 3}, etc), condensable hydrocarbons, tar-like species, heavy metals, etc. with no observable effect on membrane performance. By comparison, similar operating conditions and/or environments would rapidly destroy competing membranes, such as polymeric, palladium, zeolitic, etc. Significant cost savings can be achieved through recovering H{sub 2} from refinery waste gas using this newly developed CMS membrane. Annual savings of $2 to 4MM/year (per 20,000 scfd of waste gas) can be realized by recovering the H{sub 2} for reuse (versus fuel). Projecting these values over the entire US market, potential H{sub 2} savings from refinery waste gases on the order of 750 to 1,000MM scfd and $750 to $1,000MM per year are possible. In addition to the cost savings, potential energy savings are projected to be ca. 150 to 220 tBTU/yr and CO{sub 2} gas emission reductions are projected to be ca. 5,000 to 6,500MMtons/year. The full scale membrane bundle developed as part of this project, i.e., 85 x 30 inch ceramic membrane tubes packaged into a full ceramic potting, is an important accomplishment. No comparable commercial scale product exists in the inorganic membrane field. Further, this newly developed full scale bundle concept can be extended to other thin film inorganic membrane technology (Pd, zeolite, etc), providing a potential commercialization pathway for these membrane materials that demonstrate high potential in a variety of separation applications yet remain a laboratory 'novelty' for lack of a full scale support. Overall, the project has been highly successful and all of the project objectives have been met. We have developed the first of its kind commercial scale carbon molecular sieve membrane and demonstrated its performance in field testing under aggressive operating conditions and in the presence of chemical contaminants that would rapidly destroy alternative organic and inorganic membranes. This innovative membrane permits H{sub 2} recovery from gas streams that up until now have not been successfully treated with membrane or conventional technology. Our end user participant is currently pursuing the field demonstration of this membrane for hydrogen recovery at its refinery site.

  2. Steam atmosphere drying concepts using steam exhaust recompression

    SciTech Connect (OSTI)

    DiBella, F.A. (TECOGEN, Inc., Waltham, MA (United States))

    1992-08-01T23:59:59.000Z

    In the US industrial drying accounts for approximately 1.5 quads of energy use per year. Annual industrial dryer expenditures are estimated to be in the $500 million range. Industrial drying is a significant energy and monetary expense. For the thermal drying processes in which water is removed via evaporation from the feedstock, attempts have been made to reduce the consumption of energy using exhaust waste heat recovery techniques, improved dryer designs, or even the deployment of advanced mechanical dewatering techniques. Despite these efforts, it is obvious that a large amount of thermal energy is often still lost if the latent heat of evaporation from the evaporated water cannot be recovered and/or in some way be utilized as direct heat input into the dryer. Tecogen Inc. is conducting research and development on an industrial drying concept. That utilizes a directly or indirectly superheated steam cycle atmosphere with exhaust steam recompression to recover the latent heat in the exhaust that would otherwise be lost. This approach has the potential to save 55 percent of the energy required by a conventional air dryer. Other advantages to the industrial dryer user include: A 35-percent reduction in the yearly cost per kg[sub evap] to dry wet feedstock, Reduced airborne emissions, Reduced dry dust fire/explosion risks, Hot product not exposed to oxygen thus, the product quality is enhanced, Constant rate drying in steam atmosphere, Reduced dryer size and cost, Reduced dryer heat losses due to lower dryer inlet temperatures. Tecogen has projected that the steam atmosphere drying system is most suitable as a replacement technology for state-of-the-art spray, flash, and fluidized bed drying systems. Such systems are utilized in the food and kindred products; rubber products; chemical and allied products; stone, clay, and glass; textiles; and pulp and paper industrial sectors.

  3. Steam atmosphere drying concepts using steam exhaust recompression

    SciTech Connect (OSTI)

    DiBella, F.A. [TECOGEN, Inc., Waltham, MA (United States)

    1992-08-01T23:59:59.000Z

    In the US industrial drying accounts for approximately 1.5 quads of energy use per year. Annual industrial dryer expenditures are estimated to be in the $500 million range. Industrial drying is a significant energy and monetary expense. For the thermal drying processes in which water is removed via evaporation from the feedstock, attempts have been made to reduce the consumption of energy using exhaust waste heat recovery techniques, improved dryer designs, or even the deployment of advanced mechanical dewatering techniques. Despite these efforts, it is obvious that a large amount of thermal energy is often still lost if the latent heat of evaporation from the evaporated water cannot be recovered and/or in some way be utilized as direct heat input into the dryer. Tecogen Inc. is conducting research and development on an industrial drying concept. That utilizes a directly or indirectly superheated steam cycle atmosphere with exhaust steam recompression to recover the latent heat in the exhaust that would otherwise be lost. This approach has the potential to save 55 percent of the energy required by a conventional air dryer. Other advantages to the industrial dryer user include: A 35-percent reduction in the yearly cost per kg{sub evap} to dry wet feedstock, Reduced airborne emissions, Reduced dry dust fire/explosion risks, Hot product not exposed to oxygen thus, the product quality is enhanced, Constant rate drying in steam atmosphere, Reduced dryer size and cost, Reduced dryer heat losses due to lower dryer inlet temperatures. Tecogen has projected that the steam atmosphere drying system is most suitable as a replacement technology for state-of-the-art spray, flash, and fluidized bed drying systems. Such systems are utilized in the food and kindred products; rubber products; chemical and allied products; stone, clay, and glass; textiles; and pulp and paper industrial sectors.

  4. Steam in Distribution and Use: Steam Quality Redefined

    E-Print Network [OSTI]

    Deacon, W. T.

    in the system at regular intervals. 2) Control valves should be protected by a strainer which is free from condensate accumulation. Heat Transfer potential. 1) Use steam at the lowest possible pressure to take advantage of low pressure latent heat...) A special situation exists ahead of valves that are protected by a strainer. The strainer body is a low point and accumulates condensate naturally, reducing the effective area of the strainer screen. (See Figure 4.) KI!?: Fig. 4. Automatic...

  5. Multilevel Methods to Solve the Neutron Di usion Equation ?

    E-Print Network [OSTI]

    Marn, Jos

    and high pressure. The steam produced is then expanded in the turbine producing mechanical work ? This work generates electricity using steam. This kind of plants basically consist of a steam supply system, called to produce electricity. The steam then condenses into water which is returned to the reactor core as feed

  6. Chemical filtration for steam purity

    SciTech Connect (OSTI)

    Kovalcik, F.

    1985-03-01T23:59:59.000Z

    Few industrial process systems are as vulnerable to corrosion as the steam generating loop of an electric power plant. Impurities inevitably migrate into the steam cycle, and must be removed to prevent turbine blade corrosion. It is critical to understand the behavior of the condensate polishing resins used to remove the impurities. The Electric Power Research Institute (EPRI) participated in investigations involving ion chromatography which identified chloride as a problem in studies of regeneration and polishing procedures. A modified regeneration procedure consists of ammonium sulfate treatment of the resin before and after ammonia recirculation, followed by a dilute ammonia rinse. A joint study with Southern California Edison also simulated condenser leaks to find the effect of cooling water intrusion.

  7. Closed loop steam cooled airfoil

    DOE Patents [OSTI]

    Widrig, Scott M.; Rudolph, Ronald J.; Wagner, Gregg P.

    2006-04-18T23:59:59.000Z

    An airfoil, a method of manufacturing an airfoil, and a system for cooling an airfoil is provided. The cooling system can be used with an airfoil located in the first stages of a combustion turbine within a combined cycle power generation plant and involves flowing closed loop steam through a pin array set within an airfoil. The airfoil can comprise a cavity having a cooling chamber bounded by an interior wall and an exterior wall so that steam can enter the cavity, pass through the pin array, and then return to the cavity to thereby cool the airfoil. The method of manufacturing an airfoil can include a type of lost wax investment casting process in which a pin array is cast into an airfoil to form a cooling chamber.

  8. Managing the Steam Trap Population

    E-Print Network [OSTI]

    Atlas, R. D.

    1983-01-01T23:59:59.000Z

    item? .However, some converts to the gospel of enlighten ed steam trap management expect to achieve the following benefits: A 95% trap performance level which is a better than 30% improvement over the industry norm. Plus, we have found a well... trained. This may six surveys per year with a guaf'8nteed performance level involve two days of training per man including of better than 9596. This program usually has the best cash classroom and field instruction plus periodic flow, and faster...

  9. Steam Turbine Materials and Corrosion

    SciTech Connect (OSTI)

    Holcomb, G.H.; Hsu, D.H.

    2008-07-01T23:59:59.000Z

    Ultra-supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions. Current goals of the U.S. Department of Energys Advanced Power Systems Initiatives include coal generation at 60% efficiency, which would require steam temperatures of up to 760 C. In prior years this project examined the steamside oxidation of alloys for use in high- and intermediate-pressure USC turbines. This steamside oxidation research is continuing and progress is presented, with emphasis on chromia evaporation.

  10. Advanced Production Surface Preparation Technology Development for Ultra-High Pressure Diesel Injection

    SciTech Connect (OSTI)

    Grant, Marion B.

    2012-04-30T23:59:59.000Z

    In 2007, An Ultra High Injection Pressure (UHIP) fueling method has been demonstrated by Caterpillar Fuel Systems - Product Development, demonstrating ability to deliver U.S. Environment Protection Agency (EPA) Tier 4 Final diesel engine emission performance with greatly reduced emissions handling components on the engine, such as without NOx reduction after-treatment and with only a through-flow 50% effective diesel particulate trap (DPT). They have shown this capability using multiple multi-cylinder engine tests of an Ultra High Pressure Common Rail (UHPCR) fuel system with higher than traditional levels of CEGR and an advanced injector nozzle design. The system delivered better atomization of the fuel, for more complete burn, to greatly reduce diesel particulates, while CEGR or high efficiency NOx reduction after-treatment handles the NOx. With the reduced back pressure of a traditional DPT, and with the more complete fuel burn, the system reduced levels of fuel consumption by 2.4% for similar delivery of torque and horsepower over the best Tier 4 Interim levels of fuel consumption in the diesel power industry. The challenge is to manufacture the components in high-volume production that can withstand the required higher pressure injection. Production processes must be developed to increase the toughness of the injector steel to withstand the UHIP pulsations and generate near perfect form and finish in the sub-millimeter size geometries within the injector. This project resulted in two developments in 2011. The first development was a process and a machine specification by which a high target of compressive residual stress (CRS) can be consistently imparted to key surfaces of the fuel system to increase the toughness of the steel, and a demonstration of the feasibility of further refinement of the process for use in volume production. The second development was the demonstration of the feasibility of a process for imparting near perfect, durable geometry to these same feature surfaces to withstand the pulsating UHIP diesel injection without fatigue failure, through the expected life of the fuel system's components (10,000 hours for the pump and common rail, 5000 hours for the injector). The potential to Caterpillar of this fueling approach and the overall emissions reduction system is the cost savings of the fuel, the cost savings of not requiring a full emissions module and other emissions hardware, and the enabling of the use of biodiesel fuel due to the reduced dependency on after-treatment. A proprietary production CRS generating process was developed to treat the interior of the sac-type injector nozzle tip region (particularly for the sac region). Ninety-five tips passed ultra high pulsed pressure fatigue testing with no failures assignable to treated surfaces or materials. It was determined that the CRS impartation method does not weaken the tip internal seat area. Caterpillar Fuel Systems - Product Development accepts that the CRS method initial production technical readiness level has been established. A method to gage CRS levels in production was not yet accomplished, but it is believed that monitoring process parameters call be used to guarantee quality. A precision profiling process for injector seat and sac regions has been shown to be promising but not yet fully confirmed. It was demonstrated that this precision profiling process can achieve form and geometry to well under an aggressively small micron peak-to-valley and that there are no surface flaws that approach an even tighter micron peak-to-valley tolerance. It is planned to purchase machines to further develop and move the process towards production. The system is targeted towards the high-power diesel electric power generators and high-power diesel marine power generators, with displacement from 20 liters to 80 liters and with power from 800 brake horsepower (BHP) to 3200BHP (0.6 megawatts to 2.4 megawatts). However, with market adoption, this system has the potential to meet EPA exhaust standards for all diesel engines nine liters and up, or 300B

  11. Impedance-matching experiments using high-pressure, laser-driven shock waves

    SciTech Connect (OSTI)

    Veeser, L.R.; Reeves, G.A.; Holmes, N.C.; Trainor, R.J.; Anderson, R.A.

    1981-01-01T23:59:59.000Z

    A high-power laser was used to produce shock waves with pressures of 300 to 700 GPa. A series of impedance-matching experiments on aluminum-copper systems with 10% accuracy indicate several areas in which the experiment can be improved to reduce the errors. Several such improvements are now being made, including upgrading both the laser and recording systems and modifying the target characterization techniques.

  12. DOE BestPractices Steam End User Training

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    DOE BestPractices Steam End User Training Guide Alternate Text Narratives and Graphic Descriptions June 29, 2010 #12;DOE BestPractices Steam End User Training Steam End User Training Table ............................................................................................................................................................................201 #12;DOE's BestPractices Steam End User Training Welcome Module 1 June 28, 2010 Steam End

  13. System and method for coproduction of activated carbon and steam/electricity

    DOE Patents [OSTI]

    Srinivasachar, Srivats (Sturbridge, MA); Benson, Steven (Grand Forks, ND); Crocker, Charlene (Newfolden, MN); Mackenzie, Jill (Carmel, IN)

    2011-07-19T23:59:59.000Z

    A system and method for producing activated carbon comprising carbonizing a solid carbonaceous material in a carbonization zone of an activated carbon production apparatus (ACPA) to yield a carbonized product and carbonization product gases, the carbonization zone comprising carbonaceous material inlet, char outlet and carbonization gas outlet; activating the carbonized product via activation with steam in an activation zone of the ACPA to yield activated carbon and activation product gases, the activation zone comprising activated carbon outlet, activation gas outlet, and activation steam inlet; and utilizing process gas comprising at least a portion of the carbonization product gases or a combustion product thereof; at least a portion of the activation product gases or a combustion product thereof; or a combination thereof in a solid fuel boiler system that burns a solid fuel boiler feed with air to produce boiler-produced steam and flue gas, the boiler upstream of an air heater within a steam/electricity generation plant, said boiler comprising a combustion zone, a boiler-produced steam outlet and at least one flue gas outlet.

  14. Optical steam quality measurement system and method

    DOE Patents [OSTI]

    Davidson, James R.; Partin, Judy K.

    2006-04-25T23:59:59.000Z

    An optical measurement system is presented that offers precision on-line monitoring of the quality of steam. Multiple wavelengths of radiant energy are passed through the steam from an emitter to a detector. By comparing the amount of radiant energy absorbed by the flow of steam for each wavelength, a highly accurate measurement of the steam quality can be determined on a continuous basis in real-time. In an embodiment of the present invention, the emitter, comprises three separate radiant energy sources for transmitting specific wavelengths of radiant energy through the steam. In a further embodiment, the wavelengths of radiant energy are combined into a single beam of radiant energy for transmission through the steam using time or wavelength division multiplexing. In yet a further embodiment, the single beam of radiant energy is transmitted using specialized optical elements.

  15. Steam Challenge: Developing A New DOE Program to Help Industry be Steam Smart

    E-Print Network [OSTI]

    Jones, T.; Hart, F.

    1998-01-01T23:59:59.000Z

    traps, insulation, and boiler controls. The Partnership should investigate linking these software tools together and incorporating other steam "modules" (i.e., water treatment, boiler tune-up, common steam applications) in order to estimate...

  16. Identifying Steam Opportunity "Impact" Inputs for the Steam System Assessment Tool (SSAT)

    E-Print Network [OSTI]

    Harrell, G.; Jendrucko, R.; Wright, A.

    2004-01-01T23:59:59.000Z

    IDENTIFYING STEAM OPPORTUNITY "IMPACT" INPUTS FOR THE STEAM SYSTEM ASSESSMENT TOOL (SSAT) Dr. Greg Harrell, University of Tennessee/Knoxville Dr. Richard Jendrucko, University of Tennessee/Knoxville Dr. Anthony Wright, Oak Ridge National...

  17. The Steam System Assessment Tool (SSAT): Estimating Steam System Energy, Cost, and Emission Savings

    E-Print Network [OSTI]

    Wright, A.; Bealing, C.; Eastwood, A.; Tainsh, R.; Hahn, G.; Harrell, G.

    The U. S. Department of Energy's (DOE) Industrial Technology Program BestPractices Steam effort is developing a number of software tools to assist industrial energy users to improve the efficiency of their steam system. A major new Best...

  18. Design of a continuous fiber ceramic composite heat exchanger for high-temperature, high-pressure applications

    SciTech Connect (OSTI)

    Cho, S.M.; Seltzer, A.H.; Narayanan, T.V. [Foster Wheeler Development Corp., Livingston, NJ (United States); Shah, A.C.; Weddell, J.K. [DuPont Lanxide Composites Inc., Newark, DE (United States)

    1996-12-31T23:59:59.000Z

    A conceptual design of a continuous fiber ceramic composite (CFCC) heat exchanger for high-temperature, high-pressure applications is presented. The CFCC materials under consideration are SiC reinforced with SiC fibers manufactured using the continuous vapor infiltration process and alumina reinforced with SiC or alumina fibers manufactured using the directed metal oxidation process. These composite materials are highly resistant to high-temperature corrosive environment and possess a greater creep strength than metallic materials. Heat exchangers constructed of CFCC material may be utilized for high-temperature, high-pressure applications such as air/gas heaters in advanced energy systems and high-temperature energy recovery systems. This paper presents a design of a gas-to-air CFCC heat exchanger for the high temperature advanced furnace (HITAF) in the high-performance power system (HIPPS). The 1.38 MPa (200 psia) air is heated from 760 C (1,400 F) to 982 C (1,800 F) using the combustion products at 1,650 C (3,000 F). The heat exchanger is of a cross-parallel/counter flow type in which the tube-side air flow makes a combined parallel and counter flow arrangement with a cross-flowing combustion gas in such a way that the maximum CFCC tube temperature will not exceed a 1,260 C (2,300 F) design limit. The main heat transfer mechanism from the external hot gas to the tube-side air is that of gaseous radiation for the first few rows of the tubes, followed by convective heat transfer across the remainder of the tube bundle. The design characteristics of this high-temperature, high-pressure CFCC heat exchanger with supporting thermal, flow, structural, and vibrational analyses are presented in detail in the paper.

  19. Steam System Improvements at a Manufacturing Plant

    E-Print Network [OSTI]

    Compher, J.; Morcom, B.

    1999-01-01T23:59:59.000Z

    for more detailed information on boiler control upgrades were initiated. While reviewing steam trap options, NNFD was contacted by Dibert Valve & Fitting Company, which was marketing a new steam trap system that allowed easier testing and repair..., a detailed workscope for the boiler control upgrades, and a quote was obtained. After review by maintenance management and mechanics, orders for both the boiler control package and the steam trap system's components were placed. BOILER CONTROLS...

  20. The Future of Steam: A Preliminary Discussion

    E-Print Network [OSTI]

    Russell, C.; Harrell, G.; Moore, J.; French, S.

    alternatives to steam turbines. Gas turbines, microturbines, and fuel cells are emerging technologies to watch in lhis regard. Greater acceptance of the CHP concept is in part related to concerns with reliability in power supply. Deregulation... monitored steam operations will give the system operator better diagnostic capabilities Periodic measures of fuel consumption, emissions content, and steam deliveries per volume of product are a few examples of operational metrics. The collection...

  1. Method of steam reforming methanol to hydrogen

    DOE Patents [OSTI]

    Beshty, Bahjat S. (Lower Makefield, PA)

    1990-01-01T23:59:59.000Z

    The production of hydrogen by the catalyzed steam reforming of methanol is accomplished using a reformer of greatly reduced size and cost wherein a mixture of water and methanol is superheated to the gaseous state at temperatures of about 800.degree. to about 1,100.degree. F. and then fed to a reformer in direct contact with the catalyst bed contained therein, whereby the heat for the endothermic steam reforming reaction is derived directly from the superheated steam/methanol mixture.

  2. Steam Pressure Reduction Opportunities and Issues

    E-Print Network [OSTI]

    Berry, J.; Griffin, B.; Wright, A. L.

    2006-01-01T23:59:59.000Z

    - use, and recovery. In addition to reduced energy losses, fuel consumption can be reduced, boiler efficiency can be improved, and process energy needs can be met with a reduced steam flow rate. Changes in system parameters can vary with the design... steam trap to discharge the required flow of condensate, resulting in water- logging of steam-heated equipment (e.g., dryers, water heaters, reactors). For example, consider a makeup air unit that operates at the main system pressure...

  3. Steam reforming utilizing high activity catalyst

    SciTech Connect (OSTI)

    Setzer, H. J.

    1985-03-05T23:59:59.000Z

    High activity, sulfur tolerant steam reforming catalysts are described comprising rhodium or nickel supported on lanthanum stabilized alumina or magnesium promoted lanthanum stabilized alumina. The catalysts have improved activity over conventionally used catalysts in the presence of sulfur containing hydrocarbon fuel (such as No. 2 fuel oil) in a steam reforming environment. The material has particular utility in autothermal, tubular, cyclic and adiabatic steam reforming processes.

  4. Optimized Control Of Steam Heating Coils

    E-Print Network [OSTI]

    Ali, Mir Muddassir

    2012-02-14T23:59:59.000Z

    cooling. II. Flooding of coils with condensate and its subsequent freezing when outside air temperature falls below 32?F. III. Increased maintenance cost due to water hammer, corrosion of coils in the presence of non-condensable gases and leaking steam... monotonically as the steam pressure increases, a higher steam pressure may lead to overheating of the air and result in simultaneous heating and cooling. In addition to energy waste due to simultaneous heating and cooling, an improper operating strategy can...

  5. World launch! Hot-Steam Aerostat

    E-Print Network [OSTI]

    Berlin,Technische Universität

    Info HeiDAS UH World launch! Hot-Steam Aerostat #12;"If you intend to view the land, if you plan Verne: "Fife weeks on a balloon". HeiDAS stands for Hei?DampfAeroStat (Hot-Steam AeroStat) and it refers to the first operable balloon ever that became buoyant by means of superheated steam. The performance of Hei

  6. Industrial Heat Pumps for Steam and Fuel Savings: A BestPractices Steam Technical Brief

    SciTech Connect (OSTI)

    Not Available

    2003-06-01T23:59:59.000Z

    The purpose of this Steam Techcial Brief is to introduce heat-pump technology and its applicaiton in industrial processes.

  7. Loss of feed flow, steam generator tube rupture and steam line break thermohydraulic experiments

    SciTech Connect (OSTI)

    Mendler, O J; Takeuchi, K; Young, M Y

    1986-10-01T23:59:59.000Z

    The Westinghouse Model Boiler No. 2 (MB-2) steam generator test model at the Engineering Test Facility in Tampa, Florida, was reinstrumented and modified for performing a series of tests simulating steam generator accident transients. The transients simulated were: loss of feed flow, steam generator tube rupture, and steam line break events. This document presents a description of (1) the model boiler and the associated test facility, (2) the tests performed, and (3) the analyses of the test results.

  8. The Enbridge "Steam Saver" Program: Steam Boiler Plant Efficiency-Update to Year End 2005

    E-Print Network [OSTI]

    Griffin, B.; Johnson, D.

    2006-01-01T23:59:59.000Z

    and incentive grants. Stand-alone projects encompass a wide range of projects. Examples include: -conversion of steam heated Air Handling Units from steam to natural gas. -Heat Recovery Projects. -Installation of RO water treatment systems.... These facilities have large Central Heating Plants. Some institutions have installed co- generation, replacing boilers with Heat Recovery Steam Generators. TABLE 2 BOILER POPULATION FOR STEAM PLANTS WITH ANNUAL FUEL CONSUMPTION GREATER THAN 70 MILLION CUBIC...

  9. Design and operation of an in situ high pressure reaction cell for x-ray absorption spectroscopy.

    SciTech Connect (OSTI)

    Bare, S. R.; Yang, N.; Kelly, S. D.; Mickelson, G. E.; Modica, F. S.; UOP LLC; EXAFS Analysis

    2007-01-01T23:59:59.000Z

    The design and initial operation of an in situ catalysis reaction cell for x-ray absorption spectroscopy measurements at high pressure is described. The design is based on an x-ray transparent tube fabricated from beryllium. This forms a true plug flow reactor for catalysis studies. The reactor is coupled to a portable microprocessor-controlled versatile feed system, and incorporates on-line analysis of reaction products. XAFS data recorded during the reduction of a NiRe/carbon catalyst at 4 bar are used to illustrate the performance of the reactor.

  10. Thermodynamics of the ferromagnetic phase transition in nearly half metallic CoS2 at high pressures

    SciTech Connect (OSTI)

    Elkin, F. S. [Institute for High Pressure Physics of Russian Academy of Sciences; Zibrov, I. P. [Institute for High Pressure Physics of Russian Academy of Sciences; Novikov, A. P. [Institute for High Pressure Physics of Russian Academy of Sciences; Khasanov, S. S. [Institute for Solid State Physics Russian Academy of Sciences; Sidorov, V. A. [Institute for High Pressure Physics of Russian Academy of Sciences; Petrova, A. E. [Institute for High Pressure Physics of Russian Academy of Sciences; Lograsso, Thomas A. [Ames Laboratory; Thompson, J. D. [Los Alamos National Laboratory; Stishov, S. M. [Institute for High Pressure Physics of Russian Academy of Sciences

    2013-12-06T23:59:59.000Z

    The volume change and heat capacity at the ferromagnetic phase transition in COS2 were measured at high pressures using X-rays generated by the Argonne synchrotron light source and by ac-calorimetry, respectively. The transition entropy, calculated on the basis of these experimental data, drops along the transition line due to quantum degradation, as required by Nernst's law. The volume change increases strongly along the transition line, which is explained by specifics of the compressibility difference of coexisting phases that results from nearly half metallic nature of the ferromagnetic phase of COS2. (C) 2013 Elsevier Ltd. All rights reserved.

  11. Using field emission to control the electron energy distribution in high-pressure microdischarges at microscale dimensions

    SciTech Connect (OSTI)

    Li, Yingjie; Go, David B. [Department of Aerospace and Mechanical Engineering, University of Notre Dame, Notre Dame, Indiana 46556 (United States)] [Department of Aerospace and Mechanical Engineering, University of Notre Dame, Notre Dame, Indiana 46556 (United States)

    2013-12-02T23:59:59.000Z

    Particle simulations of high-pressure microdischarges at gaps below 10 ?m show that the electron energy distribution becomes non-continuous, with discrete peaks corresponding to specific inelastic collisions. The relative magnitude of these peaks and shape of the energy distribution can be directly controlled by the parameter pressure times distance (pd) and the applied potential across the gap. These parameters dictate inelastic collisions experienced by electrons and as both increase the distribution smooths into a Maxwellian-like distribution. By capitalizing on field emission at these dimensions, it is possible to control the energy distribution of free electrons to target specific, energy dependent reactions.

  12. Engineering task plan for the development of a high pressure water drill system for BY-105 saltwell screen installation

    SciTech Connect (OSTI)

    RITTER, G.A.

    1999-02-24T23:59:59.000Z

    This engineering task plan identifies the activities required for developing an ultra high pressure water drill system for installation of a saltwell screen in Tank BY-105. A water drill system is needed to bore through the hard waste material in this tank because of the addition of Portland cement in the 1960s and/or 1970s. The activities identified in this plan include the design, procurement, and qualification testing of the water drill along with readiness preparations including developing operating procedures, training Operations personnel, and conducting an assessment of readiness.

  13. The effect of high-pressure injection of gas on the reservoir volume factor of a crude oil

    E-Print Network [OSTI]

    Honeycutt, Baxter Bewitt

    1957-01-01T23:59:59.000Z

    . The gas was taken from the casing annulus at 180 psig pressure after the well had flowed for about 3 hours. An analysis of the gas is given in Table 4. Gravity of the oil was 37. 3 API at 60oF. Reservoir pressure in the Charlotte Field... are different at different locations in the reservoir. In the high-pressure zone about the injection well ? a substantial amount of the oil dissolves in the gas, leaving a low residual oil saturation consisting of the heaviest fraction of the oil...

  14. Design and Operation of an In Situ High Pressure Reaction Cell for X-Ray Absorption Spectroscopy

    SciTech Connect (OSTI)

    Bare, Simon R.; Mickelson, G. E.; Modica, F. S. [UOP LLC, Des Plaines, IL, 60016 (United States); Yang, N. [Argonne National Laboratory, Argonne, IL 60439 (United States); Kelly, S. D. [EXAFS Analysis, Bolingbrook, IL 6044 (United States)

    2007-02-02T23:59:59.000Z

    The design and initial operation of an in situ catalysis reaction cell for x-ray absorption spectroscopy measurements at high pressure is described. The design is based on an x-ray transparent tube fabricated from beryllium. This forms a true plug flow reactor for catalysis studies. The reactor is coupled to a portable microprocessor-controlled versatile feed system, and incorporates on-line analysis of reaction products. XAFS data recorded during the reduction of a NiRe/carbon catalyst at 4 bar are used to illustrate the performance of the reactor.

  15. High-Pressure Thermodynamic Properties of f-electron Metals, Transition Metal Oxides, and Half-Metallic Magnets

    SciTech Connect (OSTI)

    Richard T. Scalettar; Warren E. Pickett

    2005-08-02T23:59:59.000Z

    This project involves research into the thermodynamic properties of f-electron metals, transition metal oxides, and half-metallic magnets at high pressure. These materials are ones in which the changing importance of electron-electron interactions as the distance between atoms is varied can tune the system through phase transitions from localized to delocalized electrons, from screened to unscreened magnetic moments, and from normal metal to one in which only a single spin specie can conduct. Three main thrusts are being pursued: (i) Mott transitions in transition metal oxides, (ii) magnetism in half-metallic compounds, and (iii) large volume-collapse transitions in f-band metals.

  16. Steam methane reforming in molten carbonate salt. Final report

    SciTech Connect (OSTI)

    Erickson, D.C.

    1996-05-01T23:59:59.000Z

    This report documents the work accomplished on the project {open_quotes}Steam Methane Reforming in Molten Carbonate Salt.{close_quotes}. This effort has established the conceptual basis for molten carbonate-based steam reforming of methane. It has not proceeded to prototype verification, because corrosion concerns have led to reluctance on the part of large hydrogen producers to adopt the technology. Therefore the focus was shifted to a less corrosive embodiment of the same technology. After considerable development effort it was discovered that a European company (Catalysts and Chemicals Europe) was developing a similar process ({open_quotes}Regate{close_quotes}). Accordingly the focus was shifted a second time, to develop an improvement which is generic to both types of reforming. That work is still in progress, and shows substantial promise.

  17. Aerogel-Based Insulation for Industrial Steam Distribution Systems

    SciTech Connect (OSTI)

    John Williams

    2011-03-30T23:59:59.000Z

    Thermal losses in industrial steam distribution systems account for 977 trillion Btu/year in the US, more than 1% of total domestic energy consumption. Aspen Aerogels worked with Department of Energys Industrial Technologies Program to specify, develop, scale-up, demonstrate, and deliver Pyrogel XT, an aerogel-based pipe insulation, to market to reduce energy losses in industrial steam systems. The product developed has become Aspens best selling flexible aerogel blanket insulation and has led to over 60 new jobs. Additionally, this product has delivered more than ~0.7 TBTU of domestic energy savings to date, and could produce annual energy savings of 149 TBTU by 2030. Pyrogel XTs commercial success has been driven by its 2-4X better thermal performance, improved durability, greater resistance to corrosion under insulation (CUI), and faster installation times than incumbent insulation materials.

  18. Liquid Fuel Production from Biomass via High Temperature Steam Electrolysis

    SciTech Connect (OSTI)

    Grant L. Hawkes; Michael G. McKellar

    2009-11-01T23:59:59.000Z

    A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to heat steam for the hydrogen production via the high temperature steam electrolysis process. Hydrogen from electrolysis allows a high utilization of the biomass carbon for syngas production. Oxygen produced form the electrolysis process is used to control the oxidation rate in the oxygen-fed biomass gasifier. Based on the gasifier temperature, 94% to 95% of the carbon in the biomass becomes carbon monoxide in the syngas (carbon monoxide and hydrogen). Assuming the thermal efficiency of the power cycle for electricity generation is 50%, (as expected from GEN IV nuclear reactors), the syngas production efficiency ranges from 70% to 73% as the gasifier temperature decreases from 1900 K to 1500 K. Parametric studies of system pressure, biomass moisture content and low temperature alkaline electrolysis are also presented.

  19. Covered Product Category: Commercial Steam Cookers

    Broader source: Energy.gov [DOE]

    The Federal Energy Management Program (FEMP) provides acquisition guidance for commercial steam cookers, which are covered by the ENERGY STAR program.

  20. Pre-In-Plant Training Webinar (Steam)

    Broader source: Energy.gov [DOE]

    This pre-In-Plant training webinar for the Better Plants Program covers how to find energy savings in steam systems.

  1. Superheater Corrosion Produced By Biomass Fuels

    SciTech Connect (OSTI)

    Sharp, William (Sandy) [SharpConsultant] [SharpConsultant; Singbeil, Douglas [FPInnovations] [FPInnovations; Keiser, James R [ORNL] [ORNL

    2012-01-01T23:59:59.000Z

    About 90% of the world's bioenergy is produced by burning renewable biomass fuels. Low-cost biomass fuels such as agricultural wastes typically contain more alkali metals and chlorine than conventional fuels. Although the efficiency of a boiler's steam cycle can be increased by raising its maximum steam temperature, alkali metals and chlorine released in biofuel boilers cause accelerated corrosion and fouling at high superheater steam temperatures. Most alloys that resist high temperature corrosion protect themselves with a surface layer of Cr{sub 2}O{sub 3}. However, this Cr{sub 2}O{sub 3} can be fluxed away by reactions that form alkali chromates or volatilized as chromic acid. This paper reviews recent research on superheater corrosion mechanisms and superheater alloy performance in biomass boilers firing black liquor, biomass fuels, blends of biomass with fossil fuels and municipal waste.

  2. Achieve Steam System Excellence - Steam Overview | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the YouTube platform is alwaysISO 50001 Energy ManagementPatriciaUCNIAchieve Steam System

  3. Achieve Steam System Excellence - Steam Overview | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: The Future of1 AAccelerated aging of roofingDepartmentAchieve Steam System

  4. DOE's BestPractices Steam End User Training Steam EndUser Training

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    DOE's BestPractices Steam End User Training Steam EndUser Training Resource Utilization End User Training Resource Utilization Analysis Module 1 June 28, 2010 #12; DOE's BestPractices Steam End User Training Slide 3 Fuel Selection 1 Fuel purchases typically dominate the operating cost

  5. US Department of Energy`s high-temperature and high-pressure particulate cleanup for advanced coal-based power systems

    SciTech Connect (OSTI)

    Dennis, R.A.

    1997-05-01T23:59:59.000Z

    The availability of reliable, low-cost electricity is a cornerstone for the United States` ability to compete in the world market. The Department of Energy (DOE) projects the total consumption of electricity in the US to rise from 2.7 trillion kilowatt-hours in 1990 to 3.5 trillion in 2010. Although energy sources are diversifying, fossil fuel still produces 90 percent of the nation`s energy. Coal is our most abundant fossil fuel resource and the source of 56 percent of our electricity. It has been the fuel of choice because of its availability and low cost. A new generation of high-efficiency power systems has made it possible to continue the use of coal while still protecting the environment. Such power systems greatly reduce the pollutants associated with cola-fired plants built before the 1970s. To realize this high efficiency and superior environmental performance, advanced coal-based power systems will require gas stream cleanup under high-temperature and high-pressure (HTHP) process conditions. Presented in this paper are the HTHP particulate capture requirements for the Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized-Bed Combustion (PFBC) power systems, the HTHP particulate cleanup systems being implemented in the PFBC and IGCC Clean Coal Technology (CCT) Projects, and the currently available particulate capture performance results.

  6. Standard practice for evaluation of disbonding of bimetallic stainless alloy/steel plate for use in high-pressure, high-temperature refinery hydrogen service

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2001-01-01T23:59:59.000Z

    1.1 This practice covers a procedure for the evaluation of disbonding of bimetallic stainless alloy/steel plate for use in refinery high-pressure/high-temperature (HP/HT) gaseous hydrogen service. It includes procedures to (1) produce suitable laboratory test specimens, (2) obtain hydrogen charging conditions in the laboratory that are similar to those found in refinery HP/HT hydrogen gas service for evaluation of bimetallic specimens exposed to these environments, and (3) perform analysis of the test data. The purpose of this practice is to allow for comparison of data among test laboratories on the resistance of bimetallic stainless alloy/steels to hydrogen-induced disbonding (HID). 1.2 This practice applies primarily to bimetallic products fabricated by weld overlay of stainless alloy onto a steel substrate. Most of the information developed using this practice has been obtained for such materials. The procedures described herein, may also be appropriate for evaluation of hot roll bonded, explosive bonded...

  7. High voltage ignition of high pressure microwave powered UV light sources

    SciTech Connect (OSTI)

    Frank, J.D.; Cekic, M.; Wood, C.H. [Fusion U.V. Curing Systems Corp., Gaithersburg, MD (United States)

    1997-12-31T23:59:59.000Z

    Industrial microwave powered (electrodeless) light sources have been limited to quiescent pressures of {approximately}300 Torr of buffer gas and metal-halide fills. The predominant reason for such restrictions has been the inability to microwave ignite the plasma due to the collisionality of higher pressure fills and/or the electronegativity of halide bulb chemistries. Commercially interesting bulb fills require electric fields for ionization that are often large multiples of the breakdown voltage for air. Many auxiliary ignition methods are evaluated for efficiency and practicality before the choice of a high-voltage system with a retractable external electrode. The scheme utilizes a high voltage pulse power supply and a novel field emission source. Acting together they create localized condition of pressure reduction and high free electron density. This allows the normal microwave fields to drive this small region into avalanche, ignite the bulb, and heat the plasma to its operating point (T{sub e} {approx} 0.5 eV). This process is currently being used in a new generation of lamps, which are using multi-atmospheric excimer laser chemistries and pressure and constituent enhanced metal-halide systems. At the present time, production prototypes produce over 900 W of radiation in a 30 nm band, centered at 308 nm. Similarly, these prototypes when loaded with metal-halide bulb fills produce over 1 kW of radiation in 30 nm wide bands, centered about the wavelength of interest.

  8. Bench-Scale Development of a Hot Carbonate Absorption Process with Crystallization-Enabled High-Pressure Stripping for Post-Combustion CO{sub 2} Capture

    SciTech Connect (OSTI)

    Lu, Yongqi; DeVries, Nicholas; Ruhter, David; Manoranjan, Sahu; Ye, Qing; Ye, Xinhuai; Zhang, Shihan; Chen, Scott; Li, Zhiwei; O'Brien, Kevin

    2014-03-31T23:59:59.000Z

    A novel Hot Carbonate Absorption Process with Crystallization-Enabled High-Pressure Stripping (Hot-CAP) has been developed by the University of Illinois at Urbana-Champaign and Carbon Capture Scientific, LLC in this three-year, bench-scale project. The Hot-CAP features a concentrated carbonate solution (e.g., K{sub 2}CO{sub 3}) for CO{sub 2} absorption and a bicarbonate slurry (e.g., KHCO{sub 3}) for high-pressure CO{sub 2} stripping to overcome the energy use and other disadvantages associated with the benchmark monoethanolamine (MEA) process. The project was aimed at performing laboratory- and bench-scale experiments to prove its technical feasibility and generate process engineering and scale-up data, and conducting a techno-economic analysis (TEA) to demonstrate its energy use and cost competitiveness over MEA. To meet project goals and objectives, a combination of experimental, modeling, process simulation, and economic analysis studies were applied. Carefully designed and intensive experiments were conducted to measure thermodynamic and reaction engineering data relevant to four major unit operations in the Hot-CAP (i.e., CO{sub 2} absorption, CO{sub 2} stripping, bicarbonate crystallization, and sulfate reclamation). The rate promoters that could accelerate the CO{sub 2} absorption rate into the potassium carbonate/bicarbonate (PCB) solution to a level greater than that into the 5 M MEA solution were identified, and the superior performance of CO{sub 2} absorption into PCB was demonstrated in a bench-scale packed-bed column. Kinetic data on bicarbonate crystallization were developed and applied for crystallizer design and sizing. Parametric testing of high-pressure CO{sub 2} stripping with concentrated bicarbonate-dominant slurries at high temperatures ({>=}140{degrees}C) in a bench-scale stripping column demonstrated lower heat use than with MEA. The feasibility of a modified process for combining SO{sub 2} removal with CO{sub 2} capture was preliminarily demonstrated. In addition to the experimental studies, the technical challenges pertinent to fouling of slurry-handling equipment and the design of the crystallizer and stripper were addressed through consultation with vendors and engineering analyses. A process flow diagram of the Hot-CAP was then developed and a TEA was performed to compare the energy use and cost performance of a nominal 550-MWe subcritical pulverized coal (PC)-fired power plant without CO{sub 2} capture (DOE/NETL Case 9) with the benchmark MEA-based post-combustion CO{sub 2} capture (PCC; DOE/NETL Case 10) and the Hot-CAP-based PCC. The results revealed that the net power produced in the PC + Hot-CAP is 609 MWe, greater than the PC + MEA (550 MWe). The 20-year levelized cost of electricity (LCOE) for the PC + Hot-CAP, including CO{sub 2} transportation and storage, is 120.3 mills/kWh, a 60% increase over the base PC plant without CO{sub 2} capture. The LCOE increase for the Hot-CAP is 29% lower than that for MEA. TEA results demonstrated that the Hot-CAP is energy-efficient and cost-effective compared with the benchmark MEA process.

  9. High-temperature/high-pressure x-ray diffraction: Recent developments

    SciTech Connect (OSTI)

    Schiferl, D.; Johnson, S.W.; Zinn, A.S.

    1989-01-01T23:59:59.000Z

    We have developed two Merrill-Bassett diamond-anvil cells for specialized high-temperature uses. The first is constructed largely of rhenium to provide uniform, constant P and T on the order of 20 GPa at 1200 K for extended periods. The second is for single-crystal x-ray diffraction, but can be heated to 630 K at 20 GPa to grow single-crystal samples which cannot be produced at room temperature. With this cell, the crystal structure of /var epsilon/-O/sub 2/ was shown to be monoclinic with a = 3.649 A, b = 5.493 A, c = 7.701 A, and /Beta/ = 116.11/degree/ at 19.7 GPa. 15 refs.

  10. Petrological and geochronological constraints on the metamorphic evolution of high-pressure granulites and eclogites of the Snowbird tectonic zone, Canada

    E-Print Network [OSTI]

    Baldwin, Julia A. (Julia Ann), 1974-

    2003-01-01T23:59:59.000Z

    This thesis examines the petrology and geochronology of high-pressure granulites and eclogites within the Snowbird tectonic zone of the western Canadian Shield. The focus of this study is the East Athabasca mylonite triangle ...

  11. Experimental verification of the high pressure crystal structures in NH{sub 3}BH{sub 3}

    SciTech Connect (OSTI)

    Huang, Yanping; Huang, Xiaoli; Zhao, Zhonglong; Li, Wenbo; Jiang, Shuqing; Duan, Defang; Bao, Kuo; Zhou, Qiang; Liu, Bingbing; Cui, Tian, E-mail: cuitian@jlu.edu.cn [State Key Laboratory of Superhard Materials, College of Physics, Jilin University, Changchun 130012 (China)

    2014-06-28T23:59:59.000Z

    A detailed high-pressure study on NH{sub 3}BH{sub 3} has been carried out using in situ synchrotron X-ray diffraction (XRD) and Raman scattering with a diamond anvil cell up to 20 and 33 GPa, respectively. The Rietveld refinement based on the XRD pattern and analysis of Raman data indicate two first-order phase transitions from the ambient pressure I4 mm structure (?-NH{sub 3}BH{sub 3}) to a high pressure Cmc2{sub 1} phase (?-NH{sub 3}BH{sub 3}) at 2.14 GPa, and further into a monoclinic P2{sub 1} (Z = 2) phase (?-NH{sub 3}BH{sub 3}) at 9.67 GPa. Fitting the measured volumetric compression data to the third order Birch-Murnaghan equation of state reveals a bulk modulus of B{sub 0} = 9.9 0.5 and 17.0 3.0 GPa (with fixed B{sub 0}{sup ?} = 4) for the ?-NH{sub 3}BH{sub 3} below and above 5 GPa, respectively. Still, with the splitting of the NBH rock mode in Raman experiment, it is concluded that a second-order isostructural phase transition occurs at 5 GPa. By analyzing the dihydrogen bonding framework, the origin of the isostructural phase transition is attributed to the number of dihydrogen bondings per molecule in the Cmc2{sub 1} phase increasing from 12 to 14 at 5 GPa.

  12. The ReactorSTM: Atomically resolved scanning tunneling microscopy under high-pressure, high-temperature catalytic reaction conditions

    SciTech Connect (OSTI)

    Herbschleb, C. T.; Tuijn, P. C. van der; Roobol, S. B.; Navarro, V.; Bakker, J. W.; Liu, Q.; Stoltz, D.; Caas-Ventura, M. E.; Verdoes, G.; Spronsen, M. A. van; Bergman, M.; Crama, L.; Taminiau, I.; Frenken, J. W. M., E-mail: frenken@physics.leidenuniv.nl [Huygens-Kamerlingh Onnes Laboratory, Leiden University, P.O. box 9504, 2300 RA Leiden (Netherlands); Ofitserov, A.; Baarle, G. J. C. van [Leiden Probe Microscopy B.V., J.H. Oortweg 21, 2333 CH Leiden (Netherlands)

    2014-08-15T23:59:59.000Z

    To enable atomic-scale observations of model catalysts under conditions approaching those used by the chemical industry, we have developed a second generation, high-pressure, high-temperature scanning tunneling microscope (STM): the ReactorSTM. It consists of a compact STM scanner, of which the tip extends into a 0.5 ml reactor flow-cell, that is housed in a ultra-high vacuum (UHV) system. The STM can be operated from UHV to 6 bars and from room temperature up to 600 K. A gas mixing and analysis system optimized for fast response times allows us to directly correlate the surface structure observed by STM with reactivity measurements from a mass spectrometer. The in situ STM experiments can be combined with ex situ UHV sample preparation and analysis techniques, including ion bombardment, thin film deposition, low-energy electron diffraction and x-ray photoelectron spectroscopy. The performance of the instrument is demonstrated by atomically resolved images of Au(111) and atom-row resolution on Pt(110), both under high-pressure and high-temperature conditions.

  13. Steam Field | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to:Ezfeedflag JumpID-f < RAPID‎SolarCityInformation Glass Buttes AreaStea DivisioneSteam

  14. Author's personal copy Novel high-pressure structures of MgCO3, CaCO3 and CO2 and their role in

    E-Print Network [OSTI]

    Oganov, Artem R.

    Author's personal copy Novel high-pressure structures of MgCO3, CaCO3 and CO2 and their role's lower mantle is believed to be stored in the high-pressure forms of MgCO3 and/or CaCO3 or possibly even picture of phase transformations of CaCO3 at mantle pressures was obtained. Here, using the same approach

  15. A Better Steam Engine: Designing a Distributed Concentrating Solar Combined Heat and Power System

    E-Print Network [OSTI]

    Norwood, Zachary Mills

    2011-01-01T23:59:59.000Z

    of the collector, turbine, and steam accumulator arehigher efficiencies with wet steam, but turbines often see

  16. Method for producing viscous hydrocarbons

    DOE Patents [OSTI]

    Poston, Robert S. (Winter Park, FL)

    1982-01-01T23:59:59.000Z

    A method for recovering viscous hydrocarbons and synthetic fuels from a subterranean formation by drilling a well bore through the formation and completing the well by cementing a casing means in the upper part of the pay zone. The well is completed as an open hole completion and a superheated thermal vapor stream comprised of steam and combustion gases is injected into the lower part of the pay zone. The combustion gases migrate to the top of the pay zone and form a gas cap which provides formation pressure to produce the viscous hydrocarbons and synthetic fuels.

  17. An Object-Oriented Algebraic Steam-Boiler Control Specification

    E-Print Network [OSTI]

    ?lveczky, Peter Csaba

    An Object-Oriented Algebraic Steam-Boiler Control Specification computations cannot happen. 1 Introduction The steam-boiler control specification problem has been

  18. analyzing steam generator: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    We present ow simulations in the Steam Generator of a pressurized water nuclear reactor using coherence between the zoom and the full domain. Key words: Steam Generator,...

  19. advanced steam generators: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    We present ow simulations in the Steam Generator of a pressurized water nuclear reactor using coherence between the zoom and the full domain. Key words: Steam Generator,...

  20. asco steam generators: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    We present ow simulations in the Steam Generator of a pressurized water nuclear reactor using coherence between the zoom and the full domain. Key words: Steam Generator,...

  1. alloy n06600 steam: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    paper, and many other industries depend heavily on extensive complex steam systems for thermal and mechanical energy delivery. Steam's versatility and desirable characteristics as...

  2. Recent Progress on Steam Hydrogasification of Carbonaceous Matter...

    Broader source: Energy.gov (indexed) [DOE]

    Recent Progress on Steam Hydrogasification of Carbonaceous Matter to Clean Synthetic Diesel Fuel Recent Progress on Steam Hydrogasification of Carbonaceous Matter to Clean...

  3. Improving Steam System Performance: A Sourcebook for Industry...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Improving Steam System Performance: A Sourcebook for Industry, Second Edition Improving Steam System Performance: A Sourcebook for Industry, Second Edition This sourcebook is...

  4. Dow Chemical Company: Assessment Leads to Steam System Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Dow Chemical Company: Assessment Leads to Steam System Energy Savings in a Petrochemical Plant Dow Chemical Company: Assessment Leads to Steam System Energy Savings in a...

  5. Steam System Efficiency Optimized After J.R. Simplot Fertilizer...

    Broader source: Energy.gov (indexed) [DOE]

    Steam System Efficiency Optimized After J.R. Simplot Fertilizer Plant Receives Energy Assessment Steam System Efficiency Optimized After J.R. Simplot Fertilizer Plant Receives...

  6. Comparative Investigation of Benzene Steam Reforming over Spinel...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Investigation of Benzene Steam Reforming over Spinel Supported Rh and Ir Catalysts. Comparative Investigation of Benzene Steam Reforming over Spinel Supported Rh and Ir Catalysts....

  7. High-temperature, high-pressure bonding of nested tubular metallic components

    DOE Patents [OSTI]

    Quinby, Thomas C. (Kingston, TN)

    1980-01-01T23:59:59.000Z

    This invention is a tool for effecting high-temperature, high-compression bonding between the confronting faces of nested, tubular, metallic components. In a typical application, the tool is used to produce tubular target assemblies for irradiation in nuclear reactors or particle accelerators, the target assembly comprising a uranium foil and an aluminum-alloy substrate. The tool preferably is composed throughout of graphite. It comprises a tubular restraining member in which a mechanically expandable tubular core is mounted to form an annulus with the member. The components to be bonded are mounted in nested relation in the annulus. The expandable core is formed of individually movable, axially elongated segments whose outer faces cooperatively define a cylindrical pressing surface and whose inner faces cooperatively define two opposed, inwardly tapered, axial bores. Tapered rams extend respectively into the bores. The loaded tool is mounted in a conventional hot-press provided with evacuation means, heaters for maintaining its interior at bonding temperature, and hydraulic cylinders for maintaining a selected inwardly directed pressure on the tapered rams. With the hot-press evacuated and the loaded tool at the desired temperature, the cylinders are actuated to apply the selected pressure to the rams. The rams in turn expand the segmented core to maintain the nested components in compression against the restraining member. These conditions are maintained until the confronting faces of the nested components are joined in a continuous, uniform bond characterized by high thermal conductivity.

  8. Cage occupancies in the high pressure structure H methane hydrate: A neutron diffraction study

    SciTech Connect (OSTI)

    Tulk, Christopher A [ORNL; Klug, Dennis D [National Research Council of Canada; Moreira Dos Santos, Antonio F [ORNL; Karotsis, Georgios [ORNL; Guthrie, Malcolm [Carnegie Institution of Washington; Molaison, Jamie J [ORNL; Pradhan, Neelam [ORNL

    2012-01-01T23:59:59.000Z

    A neutron diffraction study was performed on the CD{sub 4}: D{sub 2}O structure H clathrate hydrate to refine its CD{sub 4} fractional cage occupancies. Samples of ice VII and hexagonal (sH) methane hydrate were produced in a Paris-Edinburgh press and in situ neutron diffraction data collected. The data were analyzed with the Rietveld method and yielded average cage occupancies of 3.1 CD{sub 4} molecules in the large 20-hedron (5{sup 12}6{sup 8}) cages of the hydrate unit cell. Each of the pentagonal dodecahedron (5{sup 12}) and 12-hedron (4{sup 3}5{sup 6}6{sup 3}) cages in the sH unit cell are occupied with on average 0.89 and 0.90 CD{sub 4} molecules, respectively. This experiment avoided the co-formation of Ice VI and sH hydrate, this mixture is more difficult to analyze due to the proclivity of ice VI to form highly textured crystals, and overlapping Bragg peaks of the two phases. These results provide essential information for the refinement of intermolecular potential parameters for the water methane hydrophobic interaction in clathrate hydrates and related dense structures.

  9. Optimizing Steam & Condensate System: A Case Study

    E-Print Network [OSTI]

    Venkatesan, V. V.; Norris, C.

    2011-01-01T23:59:59.000Z

    for electricity). The site generates steam for its process operation from 3 gas fired boilers at 525-psig pressure. The steam is consumed at 5 process areas; Acid, Basics, Crystals, Derivatives & Hydrogen plants. All of the process areas recover condensate inside...

  10. Coreflood experimental study of steam displacement

    E-Print Network [OSTI]

    Cerutti, Andres Enrique

    1997-01-01T23:59:59.000Z

    in which steam was injected into a core or a sand pack. Liquid saturation profiles in the core or sand pack were constructed from X-ray CT scan cross-sectional images. The liquid saturation profiles indicate the presence of three zones, namely, the steam...

  11. Energy Management - Using Steam Pressure Efficiently

    E-Print Network [OSTI]

    Jiandani, N.

    1983-01-01T23:59:59.000Z

    Saturated steam contains heat in two different forms. Sensible heat and latent heat. Due to the nature of this vapor, the relative proportion of latent heat is higher at lower pressures compared to higher pressures. When steam is used for heating...

  12. Program assists steam drive design project

    SciTech Connect (OSTI)

    Mendez, A.A.

    1984-08-27T23:59:59.000Z

    A new program for the HP-41CV programmable calculator will compute all parameters required for a steam drive project design. The Marx and Langenheim model assumptions are used to solve a more advanced version of the Myhill and Stegemeier model. Also, the Mandl and Volek model assuptions are used to compute the size of the steam zone.

  13. Energy Management - Using Steam Pressure Efficiently

    E-Print Network [OSTI]

    Jiandani, N.

    1983-01-01T23:59:59.000Z

    Saturated steam contains heat in two different forms. Sensible heat and latent heat. Due to the nature of this vapor, the relative proportion of latent heat is higher at lower pressures compared to higher pressures. When steam is used for heating...

  14. Circumferential cracking of steam generator tubes

    SciTech Connect (OSTI)

    Karwoski, K.J.

    1997-04-01T23:59:59.000Z

    On April 28, 1995, the U.S. Nuclear Regulatory Commission (NRC) issued Generic Letter (GL) 95-03, {open_quote}Circumferential Cracking of Steam Generator Tubes.{close_quote} GL 95-03 was issued to obtain information needed to verify licensee compliance with existing regulatory requirements regarding the integrity of steam generator tubes in domestic pressurized-water reactors (PWRs). This report briefly describes the design and function of domestic steam generators and summarizes the staff`s assessment of the responses to GL 95-03. The report concludes with several observations related to steam generator operating experience. This report is intended to be representative of significant operating experience pertaining to circumferential cracking of steam generator tubes from April 1995 through December 1996. Operating experience prior to April 1995 is discussed throughout the report, as necessary, for completeness.

  15. High Temperature, high pressure equation of state density correlations and viscosity correlations

    SciTech Connect (OSTI)

    Tapriyal, D.; Enick, R.; McHugh, M.; Gamwo, I.; Morreale, B.

    2012-07-31T23:59:59.000Z

    Global increase in oil demand and depleting reserves has derived a need to find new oil resources. To find these untapped reservoirs, oil companies are exploring various remote and harsh locations such as deep waters in Gulf of Mexico, remote arctic regions, unexplored deep deserts, etc. Further, the depth of new oil/gas wells being drilled has increased considerably to tap these new resources. With the increase in the well depth, the bottomhole temperature and pressure are also increasing to extreme values (i.e. up to 500 F and 35,000 psi). The density and viscosity of natural gas and crude oil at reservoir conditions are critical fundamental properties required for accurate assessment of the amount of recoverable petroleum within a reservoir and the modeling of the flow of these fluids within the porous media. These properties are also used to design appropriate drilling and production equipment such as blow out preventers, risers, etc. With the present state of art, there is no accurate database for these fluid properties at extreme conditions. As we have begun to expand this experimental database it has become apparent that there are neither equations of state for density or transport models for viscosity that can be used to predict these fundamental properties of multi-component hydrocarbon mixtures over a wide range of temperature and pressure. Presently, oil companies are using correlations based on lower temperature and pressure databases that exhibit an unsatisfactory predictive capability at extreme conditions (e.g. as great as {+-} 50%). From the perspective of these oil companies that are committed to safely producing these resources, accurately predicting flow rates, and assuring the integrity of the flow, the absence of an extensive experimental database at extreme conditions and models capable of predicting these properties over an extremely wide range of temperature and pressure (including extreme conditions) makes their task even more daunting.

  16. Fixed bed testing of durable, steam resistant zinc oxide containing sorbents

    SciTech Connect (OSTI)

    Siriwardane, R.V.; Grimm, U.; Poston, J. [USDOE Morgantown Energy Technology Center, WV (United States); Monaco, S.J. [EG& G dTechnical Services of West Virginia, Inc., Morgantown, WV (United States)

    1994-12-31T23:59:59.000Z

    The US Department of Energy is currently developing Integrated Gasification combined Cycle (IGCC) systems for electrical power generation. It has been predicted that IGCC plants with hot gas cleanup will be superior to conventional pulverized coal-fired power plants in overall plant efficiency and environmental performance. Development of a suitable regenerable sorbent is a major barrier issue in the hot gas cleanup program for IGCC systems. This has been a challenging problem during the last 20 years, since many of the sorbents developed in the program could not retain their reactivity and physical integrity during repeated cycles of sulfidation and regeneration reactions. Two promising sorbents and (METC6), which were capable of sustaining their reactivity and physical integrity during repeated sulfidation/regeneration cycles, have been developed at the Morgantown Energy Technology Center (METC) during the past year. These sorbents were tested (sulfided) both in low-pressure (260 kPa/37.7 psia) and high-pressure (1034 kPa/150 psia) fixed-bed reactors at 538{degrees}C (1000{degrees}F) with simulated KRW coal gas. High-pressure testing was continued for 20 cycles with steam regeneration. There were no appreciable changes in sulfidation capacity of the sorbents during the 20-cycle testing. The crush strength of the sorbent actually improved after 20 cycles and there were no indications of spalling or any other physical deterioration of the sorbents. In testing to date, these sorbents exhibit better overall sulfur capture performance than the conventional sorbents.

  17. A compact high-performance low-field NMR apparatus for measurements on fluids at very high pressures and temperatures

    SciTech Connect (OSTI)

    Freedman, R.; Anand, V., E-mail: VAnand@slb.com; Ganesan, K.; Tabrizi, P.; Torres, R. [Schlumberger Technology Corp., 110 Schlumberger Drive, Sugar Land, Texas 77478 (United States)] [Schlumberger Technology Corp., 110 Schlumberger Drive, Sugar Land, Texas 77478 (United States); Grant, B. [Grant Innovation, 618 Mesquite Drive, Cedar Creek, Texas 78612 (United States)] [Grant Innovation, 618 Mesquite Drive, Cedar Creek, Texas 78612 (United States); Catina, D. [National Oilwell Varco, 10302 Mula Road, Stafford, Texas 77477 (United States)] [National Oilwell Varco, 10302 Mula Road, Stafford, Texas 77477 (United States); Ryan, D.; Borman, C.; Krueckl, C. [Schlumberger DBR Technology Center, 945017 Avenue NW, Edmonton, Alberta (Canada)] [Schlumberger DBR Technology Center, 945017 Avenue NW, Edmonton, Alberta (Canada)

    2014-02-15T23:59:59.000Z

    We discuss an innovative new high-performance apparatus for performing low-field Nuclear Magnetic Resonance (NMR) relaxation times and diffusion measurements on fluids at very high pressures and high temperatures. The apparatus sensor design and electronics specifications allow for dual deployment either in a fluid sampling well logging tool or in a laboratory. The sensor and electronics were designed to function in both environments. This paper discusses the use of the apparatus in a laboratory environment. The operating temperature and pressure limits, and the signal-to-noise ratio (SNR) of the new system exceed by a very wide margin what is currently possible. This major breakthrough was made possible by a revolutionary new sensor design that breaks many of the rules of conventional high pressure NMR sensor design. A metallic sample holder capable of operating at high pressures and temperatures is provided to contain the fluid under study. The sample holder has been successfully tested for operation up to 36 Kpsi. A solenoid coil wound on a slotted titanium frame sits inside the metallic sample holder and serves as an antenna to transmit RF pulses and receive NMR signals. The metal sample holder is sandwiched between a pair of gradient coils which provide a linear field gradient for pulsed field gradient diffusion measurements. The assembly sits in the bore of a low-gradient permanent magnet. The system can operate over a wide frequency range without the need for tuning the antenna to the Larmor frequency. The SNR measured on a water sample at room temperature is more than 15 times greater than that of the commercial low-field system in our laboratory. Thus, the new system provides for data acquisition more than 200 times faster than was previously possible. Laboratory NMR measurements of relaxations times and diffusion coefficients performed at pressures up to 25 Kpsi and at temperatures up to 175?C with crude oils enlivened with dissolved hydrocarbon gases (referred to as live oils) are shown. This is the first time low-field NMR measurements have been performed at such high temperatures and pressures on live crude oil samples. We discuss the details of the apparatus design, tuning, calibration, and operation. NMR data acquired at multiple temperatures and pressures on a live oil sample are discussed.

  18. Technical evaluation: 300 Area steam line valve accident

    SciTech Connect (OSTI)

    Not Available

    1993-08-01T23:59:59.000Z

    On June 7, 1993, a journeyman power operator (JPO) was severely burned and later died as a result of the failure of a 6-in. valve that occurred when he attempted to open main steam supply (MSS) valve MSS-25 in the U-3 valve pit. The pit is located northwest of Building 331 in the 300 Area of the Hanford Site. Figure 1-1 shows a layout of the 300 Area steam piping system including the U-3 steam valve pit. Figure 1-2 shows a cutaway view of the approximately 10- by 13- by 16-ft-high valve pit with its various steam valves and connecting piping. Valve MSS-25, an 8-in. valve, is located at the bottom of the pit. The failed 6-in. valve was located at the top of the pit where it branched from the upper portion of the 8-in. line at the 8- by 8- by 6-in. tee and was then ``blanked off`` with a blind flange. The purpose of this technical evaluation was to determine the cause of the accident that led to the failure of the 6-in. valve. The probable cause for the 6-in. valve failure was determined by visual, nondestructive, and destructive examination of the failed valve and by metallurgical analysis of the fractured region of the valve. The cause of the accident was ultimately identified by correlating the observed failure mode to the most probable physical phenomenon. Thermal-hydraulic analyses, component stress analyses, and tests were performed to verify that the probable physical phenomenon could be reasonably expected to produce the failure in the valve that was observed.

  19. Effect of Ti doping on high pressure behavior of BiMn{sub 2}O{sub 5}

    SciTech Connect (OSTI)

    Pandey, K. K., E-mail: kkpandey@barc.gov.in; Poswal, H. K., E-mail: kkpandey@barc.gov.in; Sharma, Surinder M. [High Pressure and Synchrotron Radiation Physics Division, Bhabha Atomic Research Centre, Trombay, Mumbai 40008 (India); Kumar, Ravi [Centre for Materials Science and Engineering, National Institute of Technology, Hamirpur-177005 (India)

    2014-04-24T23:59:59.000Z

    Our high pressure x-ray diffraction studies on BiMn{sub 1.5}Ti{sub 0.5}O{sub 5} show iso-structural phase transition above 12 GPa similar to the one observed in undoped BiMn{sub 2}O{sub 5}; however anisotropic compressional behavior is found to be more enhanced in the doped case. Unlike undoped system, an anomalous lattice expansion along c axis has been observed in BiMn{sub 1.5}Ti{sub 0.5}O{sub 5} above 12 GPa; whereas the b lattice parameter has been found to be more compressible as compared to BiMn{sub 2}O{sub 5}. As doping with Ti reduces the magnetic interactions among Mn ions, the observed changes are suggestive of having adverse magnetic implications in the observed iso-structural phase transition.

  20. Properties of molecular solids and fluids at high pressure and temperatures. Progress report, July 1, 1989--July 1, 1992

    SciTech Connect (OSTI)

    Etters, R.D.

    1992-03-01T23:59:59.000Z

    This renewal request for DOE grant DE-FG02-86ER45238, is dedicated to providing a complete thermodynamic profile of solids fluids, and fluid mixtures, over a wide range of temperatures and pressures. We are partially motivated by technological interest in detonation, combustion, superhard high pressure materials, and high temperature superconductors, which are important components of interest of various DOE laboratories. Our work on fluids and solids, composed of simple molecules, involves the determination of structures, phase transitions, pressure-volume relations, phonon, vibron, and libron modes of excitation, sound velocities, specific heats, thermal expansion, virial coefficients, sublimation energies, and orientational translational, and magnetic correlations. We hope that the study of these systems under extreme thermodynamic conditions will lead to exotic new materials of value, as well as enhanced fundamental understanding.