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Sample records for high temperature chemical

  1. Institute of Chemical Engineering and High Temperature Chemical...

    Open Energy Info (EERE)

    Institute of Chemical Engineering and High Temperature Chemical Processes ICEHT Jump to: navigation, search Name: Institute of Chemical Engineering and High Temperature Chemical...

  2. Deconfinement Transition at High Isospin Chemical Potential and Low Temperature

    E-Print Network [OSTI]

    Cohen, Thomas D

    2015-01-01

    We consider QCD with two degenerate flavors of light quarks(up and down) at asymptotically high isospin and zero baryon chemical potential. In this regime and sufficiently low temperatures this theory becomes equivalent to a pure Yang-Mills theory and accordingly has a first order phase transition. This paper relates the parameters of this equivalent Yang-Mills theory to those of the underlying theory. Physically, the picture is that in this limit anti-up quarks and down quarks have Fermi surfaces with radii equal to half of the chemical potential. At high temperatures, the gluons are Debye-screened by quark quasi-particles around the Fermi surface. As the temperature is lowered, a Fermi liquid with Cooper pairing of pairs of anti-up and down quarks forms giving rise to U(1)em superconductivity. The condensate is parity odd and color neutral. The gluons do not pick up Meissner mass due to the color neutrality of the condensate. At temperatures much lower than the gap, Debye screening is absent too, as the fer...

  3. High Temperature Chemical Kinetic Combustion Modeling of Lightly Methylated Alkanes

    SciTech Connect (OSTI)

    Sarathy, S M; Westbrook, C K; Pitz, W J; Mehl, M

    2011-03-01

    Conventional petroleum jet and diesel fuels, as well as alternative Fischer-Tropsch (FT) fuels and hydrotreated renewable jet (HRJ) fuels, contain high molecular weight lightly branched alkanes (i.e., methylalkanes) and straight chain alkanes (n-alkanes). Improving the combustion of these fuels in practical applications requires a fundamental understanding of large hydrocarbon combustion chemistry. This research project presents a detailed high temperature chemical kinetic mechanism for n-octane and three lightly branched isomers octane (i.e., 2-methylheptane, 3-methylheptane, and 2,5-dimethylhexane). The model is validated against experimental data from a variety of fundamental combustion devices. This new model is used to show how the location and number of methyl branches affects fuel reactivity including laminar flame speed and species formation.

  4. Development of High Temperature/High Sensitivity Novel Chemical Resistive Sensor

    SciTech Connect (OSTI)

    Chen, Chonglin; Nash, Patrick; Ma, Chunrui; Enriquez, Erik; Wang, Haibing; Xu, Xing; Bao, Shangyong; Collins, Gregory

    2013-08-13

    The research has been focused to design, fabricate, and develop high temperature/high sensitivity novel multifunctional chemical sensors for the selective detection of fossil energy gases used in power and fuel systems. By systematically studying the physical properties of the LnBaCo{sub 2}O{sub 5+d} (LBCO) [Ln=Pr or La] thin?films, a new concept chemical sensor based high temperature chemical resistant change has been developed for the application for the next generation highly efficient and near zero emission power generation technologies. We also discovered that the superfast chemical dynamic behavior and an ultrafast surface exchange kinetics in the highly epitaxial LBCO thin films. Furthermore, our research indicates that hydrogen can superfast diffuse in the ordered oxygen vacancy structures in the highly epitaxial LBCO thin films, which suggest that the LBCO thin film not only can be an excellent candidate for the fabrication of high temperature ultra sensitive chemical sensors and control systems for power and fuel monitoring systems, but also can be an excellent candidate for the low temperature solid oxide fuel cell anode and cathode materials.

  5. THE HIGH TEMPERATURE CHEMICAL REACTIVITY OF LI2O

    SciTech Connect (OSTI)

    Kessinger, G.; Missimer, D.

    2009-11-13

    The ultimate purpose of this study was to investigate the use of a Li-Ca mixture for direct reduction of actinide oxides to actinide metals at temperatures below 1500 C. For such a process to be successful, the products of the reduction reaction, actinide metals, Li{sub 2}O, and CaO, must all be liquid at the reaction temperature so the resulting actinide metal can coalesce and be recovered as a monolith. Since the established melting temperature of Li{sub 2}O is in the range 1427-1700 C and the melting temperature of CaO is 2654 C, the Li{sub 2}O-CaO (lithium oxidecalcium oxide) pseudo-binary system was investigated in an attempt to identify the presence of low-melting eutectic compositions. The results of our investigation indicate that there is no evidence of ternary Li-Ca-O phases or solutions melting below 1200 C. In the 1200-1500 C range utilizing MgO crucibles, there is some evidence for the formation of a ternary phase; however, it was not possible to determine the phase composition. The results of experiments performed with ZrO{sub 2} crucibles in the same temperature range did not show the formation of the possible ternary phase seen in the earlier experiment involving MgO crucibles, so it was not possible to confirm the possibility that a ternary Li-Ca-O or Li-Mg-O phase was formed. It appears that the Li{sub 2}O-CaO materials reacted, to some extent, with all of the container materials, alumina (Al{sub 2}O{sub 3}), magnesia (MgO), zirconia (ZrO{sub 2}), and 95% Pt-5% Au; however, to clarify the situation additional experiments are required. In addition to the primary purpose of this study, the results of this investigation led to the conclusions that: (1) The melting temperature of Li{sub 2}O may be as low as 1250 C, which is considerably lower than the previously published values in the range 1427-1700 C; (2) Lithium oxide (Li{sub 2}O) vaporizes congruently; (3) Lithium carbonate and Li2O react with 95% Pt-5% Au, and also reacts with pure Pt; and (4) It is likely that some or all of the past high temperature phase behavior and vaporization experiments involving Li{sub 2}O(s) at temperatures above 1250 C have actually involved Li{sub 2}O(l). If these past measurements were actually measurements performed on Li{sub 2}O(l) instead of the solid, the thermochemical data for phases and species in the Li-O system will require reevaluation.

  6. Enhanced Oil Recovery in High Salinity High Temperature Reservoir by Chemical Flooding 

    E-Print Network [OSTI]

    Bataweel, Mohammed Abdullah

    2012-02-14

    that contain high concentrations of divalent cations without the need to recondition the reservoir by flooding it with less saline/ less hardness brines. This strategy was found ineffective in preparing the reservoir for chemical flooding. Surfactants used...

  7. Low-temperature germanium ultra-high vacuum chemical vapor deposition for back-end photonic integration

    E-Print Network [OSTI]

    Kimerling, Lionel C.

    Polycrystalline germanium (poly-Ge) grown on amorphous Si (a-Si) by ultra-high vacuum chemical vapor deposition (UHVCVD) over oxide barriers at low temperatures (Tles450degC) exhibits a larger grain size and lower defect ...

  8. Chemical reactivity of CVC and CVD SiC with UO2 at high temperatures

    SciTech Connect (OSTI)

    Silva, Chinthaka M; Katoh, Yutai; Voit, Stewart L; Snead, Lance Lewis

    2015-01-01

    Two types of silicon carbide (SiC) synthesized using two different vapor deposition processes were embedded in UO2 pellets and evaluated for their potential chemical reaction with UO2. While minor reactivity between chemical-vapor-composited (CVC) SiC and UO2 was observed at comparatively low temperatures of 1100 and 1300 C, chemical-vapor-deposited (CVD) SiC did not show any such reactivity, according to microstructural investigations. However, both CVD and CVC SiCs showed some reaction with UO2 at a higher temperature (1500 C). Elemental maps supported by phase maps obtained using electron backscatter diffraction indicated that CVC SiC was more reactive than CVD SiC at 1500 C. Furthermore, this investigation indicated the formation of uranium carbides and uranium silicide chemical phases such as UC, USi2, and U3Si2 as a result of SiC reaction with UO2.

  9. Chemical interaction in the B-BN system at high pressures and temperatures

    SciTech Connect (OSTI)

    Solozhenko, Vladimir L.; Kurakevych, Oleksandr O.

    2009-06-15

    Chemical interaction and phase transformations in the B-BN system have been in situ studied by X-ray diffraction with synchrotron radiation at pressures up to 5.3 GPa and temperatures up to 2800 K using multianvil press. New rhombohedral boron subnitride B{sub 13}N{sub 2} has been synthesized by crystallization from the B-BN melt at 5 GPa. The structure of B{sub 13}N{sub 2} belongs to the R-3m space group (a=5.4455(2) A, c=12.2649(9) A) and represents a new structural type. The subnitride is an individual compound and not a solid solution, in contrast to boron carbide. Besides, the formation of two other boron-rich B-N phases denoted as 'B{sub 6}N' and 'B{sub 50}N{sub 2}' has been observed. Their structures seem to be much more sophisticated and have not been even resolved to present time. - Graphical abstract: Chemical interaction and phase transformations in the B-BN system have been in situ studied by X-ray diffraction with synchrotron radiation at pressures up to 5.3 GPa and temperatures up to 2800 K using multianvil press. Three boron subnitrides have been synthesized and characterized.

  10. The Effect of High Temperature Annealing on the Grain Characteristics of a Thin Chemical Vapor Deposition Silicon Carbide Layer.

    SciTech Connect (OSTI)

    Isabella J van Rooyen; Philippus M van Rooyen; Mary Lou Dunzik-Gougar

    2013-08-01

    The unique combination of thermo-mechanical and physiochemical properties of silicon carbide (SiC) provides interest and opportunity for its use in nuclear applications. One of the applications of SiC is as a very thin layer in the TRi-ISOtropic (TRISO) coated fuel particles for high temperature gas reactors (HTGRs). This SiC layer, produced by chemical vapor deposition (CVD), is designed to withstand the pressures of fission and transmutation product gases in a high temperature, radiation environment. Various researchers have demonstrated that macroscopic properties can be affected by changes in the distribution of grain boundary plane orientations and misorientations [1 - 3]. Additionally, various researchers have attributed the release behavior of Ag through the SiC layer as a grain boundary diffusion phenomenon [4 - 6]; further highlighting the importance of understanding the actual grain characteristics of the SiC layer. Both historic HTGR fission product release studies and recent experiments at Idaho National Laboratory (INL) [7] have shown that the release of Ag-110m is strongly temperature dependent. Although the maximum normal operating fuel temperature of a HTGR design is in the range of 1000-1250°C, the temperature may reach 1600°C under postulated accident conditions. The aim of this specific study is therefore to determine the magnitude of temperature dependence on SiC grain characteristics, expanding upon initial studies by Van Rooyen et al, [8; 9].

  11. High Temperatures & Electricity Demand

    E-Print Network [OSTI]

    High Temperatures & Electricity Demand An Assessment of Supply Adequacy in California Trends.......................................................................................................1 HIGH TEMPERATURES AND ELECTRICITY DEMAND.....................................................................................................................7 SECTION I: HIGH TEMPERATURES AND ELECTRICITY DEMAND ..........................9 BACKGROUND

  12. High-temperature Chemical Compatibility of As-fabricated TRIGA Fuel and Type 304 Stainless Steel Cladding

    SciTech Connect (OSTI)

    Dennis D. Keiser, Jr.; Jan-Fong Jue; Eric Woolstenhulme; Kurt Terrani; Glenn A. Moore

    2012-09-01

    Chemical interaction between TRIGA fuel and Type-304 stainless steel cladding at relatively high temperatures is of interest from the point of view of understanding fuel behavior during different TRIGA reactor transient scenarios. Since TRIGA fuel comes into close contact with the cladding during irradiation, there is an opportunity for interdiffusion between the U in the fuel and the Fe in the cladding to form an interaction zone that contains U-Fe phases. Based on the equilibrium U-Fe phase diagram, a eutectic can develop at a composition between the U6Fe and UFe2 phases. This eutectic composition can become a liquid at around 725°C. From the standpoint of safe operation of TRIGA fuel, it is of interest to develop better understanding of how a phase with this composition may develop in irradiated TRIGA fuel at relatively high temperatures. One technique for investigating the development of a eutectic phase at the fuel/cladding interface is to perform out-of-pile diffusion-couple experiments at relatively high temperatures. This information is most relevant for lightly irradiated fuel that just starts to touch the cladding due to fuel swelling. Similar testing using fuel irradiated to different fission densities should be tested in a similar fashion to generate data more relevant to more heavily irradiated fuel. This report describes the results for TRIGA fuel/Type-304 stainless steel diffusion couples that were annealed for one hour at 730 and 800°C. Scanning electron microscopy with energy- and wavelength-dispersive spectroscopy was employed to characterize the fuel/cladding interface for each diffusion couple to look for evidence of any chemical interaction. Overall, negligible fuel/cladding interaction was observed for each diffusion couple.

  13. Use of High Temperature Electrochemical Cells for Co-Generation of Chemicals and Electricity

    SciTech Connect (OSTI)

    Scott Barnett

    2007-09-30

    In this project, two key issues were addressed to show the feasibility of electrochemical partial oxidation (EPOx) in a SOFC. First, it was demonstrated that SOFCs can reliably operate directly with natural gas. These results are relevant to both direct-natural-gas SOFCs, where the aim is solely electrical power generation, and to EPOx. Second, it must be shown that SOFCs can work effectively as partial oxidation reactors, i.e, that they can provide high conversion efficiency of natural gas to syngas. The results of this study in both these areas look extremely promising. The main results are summarized briefly: (1) Stability and coke-free direct-methane SOFC operation is promoted by the addition of a thin porous inert barrier layer to the anode and the addition of small amounts of CO{sub 2} or air to the fuel stream; (2) Modeling results readily explained these improvements by a change in the gas composition at the Ni-YSZ anode to a non-coking condition; (3) The operation range for coke-free operation is greatly increased by using a cell geometry with a thin Ni-YSZ anode active layer on an inert porous ceramic support, i.e., (Sr,La)TiO{sub 3} or partially-stabilized zirconia (in segmented-in-series arrays); (4) Ethane and propane components in natural gas greatly increase coking both on the SOFC anode and on gas-feed tubes, but this can be mitigated by preferentially oxidizing these components prior to introduction into the fuel cell, the addition of a small amount of air to the fuel, and/or the use of ceramic-supported SOFC; (5) While a minimum SOFC current density was generally required to prevent coking, current interruptions of up to 8 minutes yielded only slight anode coking that caused no permanent damage and was completely reversible when the cell current was resumed; (6) Stable direct-methane SOFC operation was demonstrated under EPOx conditions in a 350 h test; (7) EPOx operation was demonstrated at 750 C that yielded 0.9 W/cm{sup 2} and a syngas production rate of 30 sccm/cm{sup 2}, and the reaction product composition was close to the equilibrium prediction during the early stages of cell testing; (8) The methane conversion to syngas continuously decreased during the first 100 h of cell testing, even though the cell electrical characteristics did not change, due to a steady decrease in the reforming activity of Ni-YSZ anodes; (9) The stability of methane conversion was substantially improved via the addition of a more stable reforming catalyst to the SOFC anode; (10) Modeling results indicated that a SOFC with anode barrier provides similar non-coking performance as an internal reforming SOFC, and provides a simpler approach with no need for a high-temperature exhaust-gas recycle pump; (11) Since there is little or no heat produced in the EPOx reaction, overall efficiency of the SOFC operated in this mode can, in theory, approach 100%; and (12) The combined value of the electricity and syngas produced allows the EPOx generator to be economically viable at a >2x higher cost/kW than a conventional SOFC.

  14. A New Shock-Tube Facility for the Study of High-Temperature Chemical Kinetics 

    E-Print Network [OSTI]

    Vivanco, Jose E

    2014-09-30

    and pressures between 1 and 100 atm behind the reflected shock wave. The facility includes a high-vacuum system capable of achieving ultimate pressures on the order of 1x10^-6 torr, a new gas-delivery system, a shock velocity-measurement scheme, a computer...

  15. Novel Refractory Materials for High-Temperature, High-Alkaline...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications Can be used in high-temperature, high-alkaline furnaces and process vessels found in aluminum, chemical, forest products, glass, and steel industries....

  16. High Temperature ESP Monitoring

    Broader source: Energy.gov [DOE]

    The purpose of the High Temperature ESP Monitoring project is to develop a down-hole monitoring system to be used in wells with bottom hole temperature up to 300 °C for measuring motor temperature; pump discharge pressure; and formation temperature and pressure.

  17. Chemical changes in carbon Nanotube-Nickel/Nickel Oxide Core/Shell nanoparticle heterostructures treated at high temperatures

    SciTech Connect (OSTI)

    Chopra, Nitin; McWhinney, Hylton G.; Shi Wenwu

    2011-06-15

    Heterostructures composed of carbon nanotube (CNT) coated with Ni/NiO core/shell nanoparticles (denoted as CNC heterostructures) were synthesized in a wet-chemistry and single-step synthesis route involving direct nucleation of nanoparticles on CNT surface. Two different aspects of CNC heterostructures were studied here. First, it was observed that the nanoparticle coatings were more uniform on the as-produced and non-purified CNTs compared to purified (or acid treated) CNTs. These heterostructures were characterized using electron microscopy, Raman spectroscopy, and energy dispersive spectroscopy. Second, thermal stability of CNC heterostructures was studied by annealing them in N{sub 2}-rich (O{sub 2}-lean) environment between 125 and 750 deg. C for 1 h. A detailed X-ray photoelectron spectroscopy and Raman spectroscopy analysis was performed to evaluate the effects of annealing temperatures on chemical composition, phases, and stability of the heterostructures. It was observed that the CNTs present in the heterostructures completely decomposed and core Ni nanoparticle oxidized significantly between 600 and 750 deg. C. - Research Highlights: {yields} Heterostructures composed of CNTs coated with Ni/NiO core/shell nanoparticles. {yields} Poor nanoparticle coverage on purified CNT surface compared to non-purified CNTs. {yields} CNTs in heterostructures decompose between 600 and 750 deg. C in N{sub 2}-rich atmosphere. {yields} Metallic species in heterostructures were oxidized at higher temperatures.

  18. The Progress on Low-Cost, High-Quality, High-Temperature Superconducting Tapes Deposited by the Combustion Chemical Vapor Deposition Process

    SciTech Connect (OSTI)

    Shoup, S.S.; White, M.K.; Krebs, S.L.; Darnell, N.; King, A.C.; Mattox, D.S.; Campbell, I.H.; Marken, K.R.; Hong, S.; Czabaj, B.; Paranthaman, M.; Christen, H.M.; Zhai, H.-Y. Specht, E.

    2008-06-24

    The innovative Combustion Chemical Vapor Deposition (CCVD) process is a non-vacuum technique that is being investigated to enable next generation products in several application areas including high-temperature superconductors (HTS). In combination with the Rolling Assisted Biaxially Textured Substrate (RABiTS) technology, the CCVD process has significant promise to provide low-cost, high-quality lengths of YBCO coated conductor. Over 100 meter lengths of both Ni and Ni-W (3 at. Wt.%) substrates with a surface roughness of 12-18 nm were produced. The CCVD technology has been used to deposit both buffer layer coatings as well as YBCO superconducting layers. Buffer layer architecture of strontium titanate (SrTiO{sub 3}) and ceria (CeO{sub 2}) have been deposited by CCVD on textured nickel substrates and optimized to appropriate thicknesses and microstructures to provide templates for growing PLD YBCO with a J{sub c} of 1.1 MA/cm{sup 2} at 77 K and self-field. The CCVD buffer layers have been scaled to meter plus lengths with good epitaxial uniformity along the length. A short sample cut from one of the lengths enabled high critical current density PLD YBCO. Films of CCVD YBCO superconductors have been grown on single crystal substrates with critical current densities over 1 MA/cm{sup 2}. In addition, superconducting YBCO films with an I{sub c} of 60 A/cm-width (J{sub c} = 1.5 MA/cm{sup 2}) were grown on ORNL RABiTS (CeO{sub 2}/YSZ/Y{sub 2}O{sub 3}/Ni/Ni-3W) using CCVD process.

  19. High-temperature sensor

    DOE Patents [OSTI]

    Not Available

    1981-01-29

    A high temperature sensor is described which includes a pair of electrical conductors separated by a mass of electrical insulating material. The insulating material has a measurable resistivity within the sensor that changes in relation to the temperature of the insulating material within a high temperature range (1000 to 2000/sup 0/K). When required, the sensor can be encased within a ceramic protective coating.

  20. High-Temperature Superconductivity

    ScienceCinema (OSTI)

    Peter Johnson

    2010-01-08

    Like astronomers tweaking images to gain a more detailed glimpse of distant stars, physicists at Brookhaven National Laboratory have found ways to sharpen images of the energy spectra in high-temperature superconductors ? materials that carry electrical c

  1. High temperature pressure gauge

    DOE Patents [OSTI]

    Echtler, J. Paul (Pittsburgh, PA); Scandrol, Roy O. (Library, PA)

    1981-01-01

    A high temperature pressure gauge comprising a pressure gauge positioned in fluid communication with one end of a conduit which has a diaphragm mounted in its other end. The conduit is filled with a low melting metal alloy above the diaphragm for a portion of its length with a high temperature fluid being positioned in the remaining length of the conduit and in the pressure gauge.

  2. High Temperature ESP Monitoring

    SciTech Connect (OSTI)

    Jack Booker; Brindesh Dhruva

    2011-06-20

    The objective of the High Temperature ESP Monitoring project was to develop a downhole monitoring system to be used in wells with bottom hole well temperatures up to 300°C for measuring motor temperature, formation pressure, and formation temperature. These measurements are used to monitor the health of the ESP motor, to track the downhole operating conditions, and to optimize the pump operation. A 220 şC based High Temperature ESP Monitoring system was commercially released for sale with Schlumberger ESP motors April of 2011 and a 250 şC system with will be commercially released at the end of Q2 2011. The measurement system is now fully qualified, except for the sensor, at 300 °C.

  3. Conversion of Waste CO2 and Shale Gas to High-Value Chemicals

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conversion of Waste CO 2 and Shale Gas to High-Value Chemicals Enabling high-yield, low-cost, low- temperature production of chemical intermediates Chemical intermediates,...

  4. High temperature storage battery

    SciTech Connect (OSTI)

    Sammells, A.F.

    1988-06-07

    A high temperature electrochemical cell is described comprising: a solid-state divalent cation conducting electrolyte; a positive electrode in contact with the electrolyte; a solid-state negative electrode contacting a divalent cation conducting molten salt mediating agent providing ionic mediation between the solid-state negative electrode and the solid-state electrolyte.

  5. High temperature thermometric phosphors

    DOE Patents [OSTI]

    Allison, Stephen W. (Knoxville, TN); Cates, Michael R. (Oak Ridge, TN); Boatner, Lynn A. (Oak Ridge, TN); Gillies, George T. (Earlysville, VA)

    1999-03-23

    A high temperature phosphor consists essentially of a material having the general formula LuPO.sub.4 :Dy.sub.(x),Eu.sub.y) wherein: 0.1 wt %.ltoreq.x.ltoreq.20 wt % and 0.1 wt %.ltoreq.y.ltoreq.20 wt %. The high temperature phosphor is in contact with an article whose temperature is to be determined. The article having the phosphor in contact with it is placed in the environment for which the temperature of the article is to be determined. The phosphor is excited by a laser causing the phosphor to fluoresce. The emission from the phosphor is optically focused into a beam-splitting mirror which separates the emission into two separate emissions, the emission caused by the dysprosium dopant and the emission caused by the europium dopent. The separated emissions are optically filtered and the intensities of the emission are detected and measured. The ratio of the intensity of each emission is determined and the temperature of the article is calculated from the ratio of the intensities of the separate emissions.

  6. High temperature thermometric phosphors

    DOE Patents [OSTI]

    Allison, S.W.; Cates, M.R.; Boatner, L.A.; Gillies, G.T.

    1999-03-23

    A high temperature phosphor consists essentially of a material having the general formula LuPO{sub 4}:Dy{sub x},Eu{sub y} wherein: 0.1 wt % {<=} x {<=} 20 wt % and 0.1 wt % {<=} y {<=} 20 wt %. The high temperature phosphor is in contact with an article whose temperature is to be determined. The article having the phosphor in contact with it is placed in the environment for which the temperature of the article is to be determined. The phosphor is excited by a laser causing the phosphor to fluoresce. The emission from the phosphor is optically focused into a beam-splitting mirror which separates the emission into two separate emissions, the emission caused by the dysprosium dopant and the emission caused by the europium dopant. The separated emissions are optically filtered and the intensities of the emission are detected and measured. The ratio of the intensity of each emission is determined and the temperature of the article is calculated from the ratio of the intensities of the separate emissions. 2 figs.

  7. Enabling Low Temperature Combustion Through Thermo-Chemical Recuperati...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Temperature Combustion Through Thermo-Chemical Recuperation Enabling Low Temperature Combustion Through Thermo-Chemical Recuperation Poster presentation from the 2007 Diesel...

  8. Low Temperature Combustion with Thermo-chemical Recuperation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Temperature Combustion with Thermo-chemical Recuperation to Maximize In-use Engine Efficiency Low Temperature Combustion with Thermo-chemical Recuperation to Maximize In-use...

  9. High Temperature Membrane Working Group

    Broader source: Energy.gov [DOE]

    This presentation provides an overview of the High Temperature Membrane Working Group Meeting in May 2007.

  10. Optical Fiber Chemical Sensor with Sol-Gel Derived Refractive Material as Transducer for High Temperature Gas Sensing in Clean Coal Technology

    SciTech Connect (OSTI)

    Shiquan Tao

    2006-12-31

    The chemistry of sol-gel derived silica and refractive metal oxide has been systematically studied. Sol-gel processes have been developed for preparing porous silica and semiconductor metal oxide materials. Micelle/reversed micelle techniques have been developed for preparing nanometer sized semiconductor metal oxides and noble metal particles. Techniques for doping metal ions, metal oxides and nanosized metal particles into porous sol-gel material have also been developed. Optical properties of sol-gel derived materials in ambient and high temperature gases have been studied by using fiber optic spectroscopic techniques, such as fiber optic ultraviolet/visible absorption spectrometry, fiber optic near infrared absorption spectrometry and fiber optic fluorescence spectrometry. Fiber optic spectrometric techniques have been developed for investigating the optical properties of these sol-gel derived materials prepared as porous optical fibers or as coatings on the surface of silica optical fibers. Optical and electron microscopic techniques have been used to observe the microstructure, such as pore size, pore shape, sensing agent distribution, of sol-gel derived material, as well as the size and morphology of nanometer metal particle doped in sol-gel derived porous silica, the nature of coating of sol-gel derived materials on silica optical fiber surface. In addition, the chemical reactions of metal ion, nanostructured semiconductor metal oxides and nanometer sized metal particles with gas components at room temperature and high temperatures have also been investigated with fiber optic spectrometric methods. Three classes of fiber optic sensors have been developed based on the thorough investigation of sol-gel chemistry and sol-gel derived materials. The first group of fiber optic sensors uses porous silica optical fibers doped with metal ions or metal oxide as transducers for sensing trace NH{sub 3} and H{sub 2}S in high temperature gas samples. The second group of fiber optic sensors uses sol-gel derived porous silica materials doped with nanometer particles of noble metals in the form of fiber or coating for sensing trace H{sub 2}, NH{sub 3} and HCl in gas samples at for applications ambient temperature. The third classes of fiber optic sensors use sol-gel derived semiconductor metal oxide coating on the surface of silica optical fiber as transducers for selectively sensing H{sub 2}, CH{sub 4} and CO at high temperature. In addition, optical fiber temperature sensors use the fluorescence signal of rare-earth metal ions doped porous silica optical fiber or the optical absorption signal of thermochromic metal oxide materials coated on the surface of silica optical fibers have also been developed for monitoring gas temperature of corrosive gas. Based on the results obtained from this project, the principle of fiber optic sensor techniques for monitoring matrix gas components as well as trace components of coal gasification derived syngas has been established. Prototype sensors for sensing trace ammonia and hydrogen sulfide in gasification derived syngas have been built up in our laboratory and have been tested using gas samples with matrix gas composition similar to that of gasification derived fuel gas. Test results illustrated the feasibility of these sensors for applications in IGCC processes.

  11. RECHARGEABLE HIGH-TEMPERATURE BATTERIES

    E-Print Network [OSTI]

    Cairns, Elton J.

    2014-01-01

    F. Eshman, High-Performance Batteries for Electric-VehicleS. Sudar, High Performance Batteries for Electric-VehicleHIGH-TEMPERATURE BATTERIES Elton J. Cairns January 1981 TWO-

  12. High temperature interfacial superconductivity

    DOE Patents [OSTI]

    Bozovic, Ivan (Mount Sinai, NY); Logvenov, Gennady (Port Jefferson Station, NY); Gozar, Adrian Mihai (Port Jefferson, NY)

    2012-06-19

    High-temperature superconductivity confined to nanometer-scale interfaces has been a long standing goal because of potential applications in electronic devices. The spontaneous formation of a superconducting interface in bilayers consisting of an insulator (La.sub.2CuO.sub.4) and a metal (La.sub.1-xSr.sub.xCuO.sub.4), neither of which is superconducting per se, is described. Depending upon the layering sequence of the bilayers, T.sub.c may be either .about.15 K or .about.30 K. This highly robust phenomenon is confined to within 2-3 nm around the interface. After exposing the bilayer to ozone, T.sub.c exceeds 50 K and this enhanced superconductivity is also shown to originate from a 1 to 2 unit cell thick interfacial layer. The results demonstrate that engineering artificial heterostructures provides a novel, unconventional way to fabricate stable, quasi two-dimensional high T.sub.c phases and to significantly enhance superconducting properties in other superconductors. The superconducting interface may be implemented, for example, in SIS tunnel junctions or a SuFET.

  13. Nuclear fuels for very high temperature applications

    SciTech Connect (OSTI)

    Lundberg, L.B.; Hobbins, R.R.

    1992-08-01

    The success of the development of nuclear thermal propulsion devices and thermionic space nuclear power generation systems depends on the successful utilization of nuclear fuel materials at temperatures in the range 2000 to 3500 K. Problems associated with the utilization of uranium bearing fuel materials at these very high temperatures while maintaining them in the solid state for the required operating times are addressed. The critical issues addressed include evaporation, melting, reactor neutron spectrum, high temperature chemical stability, fabrication, fission induced swelling, fission product release, high temperature creep, thermal shock resistance, and fuel density, both mass and fissile atom. Candidate fuel materials for this temperature range are based on UO{sub 2} or uranium carbides. Evaporation suppression, such as a sealed cladding, is required for either fuel base. Nuclear performance data needed for design are sparse for all candidate fuel forms in this temperature range, especially at the higher temperatures.

  14. Nuclear fuels for very high temperature applications

    SciTech Connect (OSTI)

    Lundberg, L.B.; Hobbins, R.R.

    1992-01-01

    The success of the development of nuclear thermal propulsion devices and thermionic space nuclear power generation systems depends on the successful utilization of nuclear fuel materials at temperatures in the range 2000 to 3500 K. Problems associated with the utilization of uranium bearing fuel materials at these very high temperatures while maintaining them in the solid state for the required operating times are addressed. The critical issues addressed include evaporation, melting, reactor neutron spectrum, high temperature chemical stability, fabrication, fission induced swelling, fission product release, high temperature creep, thermal shock resistance, and fuel density, both mass and fissile atom. Candidate fuel materials for this temperature range are based on UO{sub 2} or uranium carbides. Evaporation suppression, such as a sealed cladding, is required for either fuel base. Nuclear performance data needed for design are sparse for all candidate fuel forms in this temperature range, especially at the higher temperatures.

  15. High-Temperature-High-Volume Lifting for Enhanced Geothermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Temperature-High-Volume Lifting for Enhanced Geothermal Systems High-Temperature-High-Volume Lifting for Enhanced Geothermal Systems High-Temperature-High-Volume Lifting for...

  16. Philosophy 26 High Temperature Superconductivity

    E-Print Network [OSTI]

    Callender, Craig

    Philosophy 26 High Temperature Superconductivity By Ohm's Law, resistance will dim. Low temperature superconductivity was discovered in 1911 by Heike was explained by BCS theory. BCS theory explains superconductivity microscopically

  17. High temperature lubricating process

    DOE Patents [OSTI]

    Taylor, Robert W. (Livermore, CA); Shell, Thomas E. (Livermore, CA)

    1982-01-01

    It has been difficult to provide adaquate lubrication for load bearing, engine components when such engines are operating in excess of about 475.degree. C. The present invention is a process for providing a solid lubricant on a load bearing, solid surface (14), such as in an engine (10) being operated at temperatures in excess of about 475.degree. C. The process comprises contacting and maintaining steps. A gas phase (42) is provided which includes at least one component reactable in a temperature dependent reaction to form a solid lubricant. The gas phase is contacted with the load bearing surface. The load bearing surface is maintained at a temperature which causes reaction of the gas phase component and the formation of the solid lubricant. The solid lubricant is formed directly on the load bearing surface. The method is particularly suitable for use with ceramic engines.

  18. High-temperature-measuring device

    DOE Patents [OSTI]

    Not Available

    1981-01-27

    A temperature measuring device for very high design temperatures (to 2000/sup 0/C) is described. The device comprises a homogenous base structure preferably in the form of a sphere or cylinder. The base structure contains a large number of individual walled cells. The base structure has a decreasing coefficient of elasticity within the temperature range being monitored. A predetermined quantity of inert gas is confined within each cell. The cells are dimensonally stable at the normal working temperature of the device. Increases in gaseous pressure within the cells will permanently deform the cell walls at temperatures within the high temperature range to be measured. Such deformation can be correlated to temperature by calibrating similarly constructed devices under known time and temperature conditions.

  19. Microlaminated high temperature intermetallic composites

    SciTech Connect (OSTI)

    Rowe, R.G.; Skelly, D.W.; Larsen, M. (GE Corporate Research and Development, Schenectady, NY (United States)); Heathcote, J.; Odette, G.R.; Lucas, G.E. (Univ. of California, Santa Barbara, CA (United States). Materials Dept.)

    1994-12-01

    The thrust to weight ratio of aircraft engines is limited by the density and elevated temperature capability of high temperature turbine materials. Single crystal superalloys, which are the current state-of-the-art in high temperature turbine blade materials, have limited potential for further increases in temperature capability. High temperature intermetallics offer the advantage of higher specific strength and higher temperature capability, but lack ductility and fracture toughness below 1,000 C. By compositing these very high temperature intermetallics with ductile metals, toughening may be improved to the point where the composites have applicability in aircraft engine turbine sections. Lamination of ductile metals with continuous intermetallic layers offers one means of producing such composites. Small lamellae thicknesses may have advantages related to intrinsic defect sizes and the effectiveness of ductile reinforcements in load-controlled applications where strength is important. Intermetallic composites will require a refractory metal for toughening because of the need for metal strength at temperatures above 1,100 C. Niobium-base alloys were selected as the toughening layer in this study because of experience with oxidation-resistant niobium alloys with low densities compared to superalloys and the existence of metal-intermetallic systems in equilibrium at high temperatures. Two microlaminated composite systems, Nb[sub 3]Al-Nb and Cr[sub 2]Nb(Cr) were chosen for microstructural and mechanical property evaluation. The choice of systems was partially based upon knowledge of phase relations between the metal and the intermetallic compositions.

  20. Chemical Equilibration at the Hagedorn Temperature

    E-Print Network [OSTI]

    J. Noronha-Hostler; C. Greiner; I. A. Shovkovy

    2007-03-23

    One important question in relativistic heavy ion collisions is if hadrons, specifically anti-hyperons, are in equilibrium before thermal freezeout because strangeness enhancement has long been pointed to as a signature for Quark Gluon Plasma. Because anti-baryons have long equilibration times in the hadron gas phase it has been suggested that they are "born" into equilibrium. However, Hagedorn states, massive resonances, which are thought to appear near the critical temperature, contribute to fast chemical equilibration times for a hadron gas by providing extra degrees of freedom. Here we use master equations to describe the interplay between Hagedorn resonances, pions, and baryon anti-baryon pairs as they equilibrate over time and observe if the baryons and anti-baryons are fully equilibrated within the fireball.

  1. Encapsulation of High Temperature Thermoelectric Modules | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Encapsulation of High Temperature Thermoelectric Modules Encapsulation of High Temperature Thermoelectric Modules Presents concept for hermetic encapsulation of TE modules...

  2. High temperature turbine engine structure

    DOE Patents [OSTI]

    Boyd, Gary L. (Tempe, AZ)

    1990-01-01

    A high temperature turbine engine includes a hybrid ceramic/metallic rotor member having ceramic/metal joint structure. The disclosed joint is able to endure higher temperatures than previously possible, and aids in controlling heat transfer in the rotor member.

  3. High temperature lightweight foamed cements

    DOE Patents [OSTI]

    Sugama, Toshifumi (Mastic Beach, NY)

    1989-01-01

    Cement slurries are disclosed which are suitable for use in geothermal wells since they can withstand high temperatures and high pressures. The formulation consists of cement, silica flour, water, a retarder, a foaming agent, a foam stabilizer, and a reinforcing agent. A process for producing these cements is also disclosed.

  4. Temperature controlled high voltage regulator

    DOE Patents [OSTI]

    Chiaro, Jr., Peter J. (Clinton, TN); Schulze, Gerald K. (Knoxville, TN)

    2004-04-20

    A temperature controlled high voltage regulator for automatically adjusting the high voltage applied to a radiation detector is described. The regulator is a solid state device that is independent of the attached radiation detector, enabling the regulator to be used by various models of radiation detectors, such as gas flow proportional radiation detectors.

  5. High temperature lightweight foamed cements

    DOE Patents [OSTI]

    Sugama, Toshifumi.

    1989-10-03

    Cement slurries are disclosed which are suitable for use in geothermal wells since they can withstand high temperatures and high pressures. The formulation consists of cement, silica flour, water, a retarder, a foaming agent, a foam stabilizer, and a reinforcing agent. A process for producing these cements is also disclosed. 3 figs.

  6. Chemical and Isotopic Prediction of Aquifer Temperatures in the...

    Open Energy Info (EERE)

    Help Apps Datasets Community Login | Sign Up Search Page Edit with form History Chemical and Isotopic Prediction of Aquifer Temperatures in the Geothermal System at Long...

  7. Application of Reversible Chemical Reactions for Temperature Amplification 

    E-Print Network [OSTI]

    Ally, M. R.; Rebello, W. J.; Suciu, D. F.

    1985-01-01

    temperature thermal energy, mechanical and absorption type heat pumps have been proposed and developed so far. This paper addresses itself to the concept of a heat reaction chemical heat pump (HRCHP). The HRCHP concept is aimed to upgrade low temperature...

  8. Low Cost, High Temperature, High Ripple Current DC Bus Capacitors...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Cost, High Temperature, High Ripple Current DC Bus Capacitors Low Cost, High Temperature, High Ripple Current DC Bus Capacitors 2010 DOE Vehicle Technologies and Hydrogen...

  9. High temperature superconductor current leads

    DOE Patents [OSTI]

    Hull, John R. (Hinsdale, IL); Poeppel, Roger B. (Glen Ellyn, IL)

    1995-01-01

    An electrical lead having one end for connection to an apparatus in a cryogenic environment and the other end for connection to an apparatus outside the cryogenic environment. The electrical lead includes a high temperature superconductor wire and an electrically conductive material distributed therein, where the conductive material is present at the one end of the lead at a concentration in the range of from 0 to about 3% by volume, and at the other end of the lead at a concentration of less than about 20% by volume. Various embodiments are shown for groups of high temperature superconductor wires and sheaths.

  10. HIGH TEMPERATURE GEOTHERMAL RESERVOIR ENGINEERING

    E-Print Network [OSTI]

    Schroeder, R.C.

    2009-01-01

    on the Cerro P r i e t o Geothermal F i e l d , Mexicali,e C e r r o P r i e t o Geothermal F i e l d , Baja C a l i1979 HIGH TEMPERATURE GEOTHERMAL RESERVOIR ENGINEERING R.

  11. High temperature turbine engine structure

    DOE Patents [OSTI]

    Boyd, Gary L. (Tempe, AZ)

    1991-01-01

    A high temperature turbine engine includes a rotor portion having axially stacked adjacent ceramic rotor parts. A ceramic/ceramic joint structure transmits torque between the rotor parts while maintaining coaxial alignment and axially spaced mutually parallel relation thereof despite thermal and centrifugal cycling.

  12. Low GWP Working Fluid for High Temperature Heat Pumps

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    Low GWP Working Fluid for High Temperature Heat Pumps: DR-2 Chemical Stability at High Temperatures Temp Heat Pumps: DR-2 Very Low GWP AND Non-Flammable HFC-245fa DR-2 Chemical Formula CF3CH2CHF2 HFO 171.3 Pcr [MPa] 3.65 2.9 Kontomaris-DuPont; European Heat Pump Summit, Nuremberg, October 15th, 2013

  13. HYDROGEN SULFIDE -HIGH TEMPERATURE DRILLING CONTINGENCY PLAN

    E-Print Network [OSTI]

    HYDROGEN SULFIDE - HIGH TEMPERATURE DRILLING CONTINGENCY PLAN OCEAN DRILLING PROGRAM TEXAS A Foundation. ii #12;HYDROGEN SULFIDE-HIGH TEMPERATURE DRILLING CONTINGENCY PLAN OCEAN DRILLING PROGRAM LEG 139

  14. Acid Doped Membranes for High Temperature PEMFC

    Broader source: Energy.gov [DOE]

    Presentation on Acid Doped Membranes for High Temperature PEMFC to the High Temperature Membrane Working Group, May 25, 2004 in Philadelphia, PA.

  15. High-Temperature Thermoelectric Materials Characterization for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Temperature Thermoelectric Materials Characterization for Automotive Waste Heat Recovery: Success Stories from the High Temperature Materials Laboratory (HTML) User Program...

  16. High Temperature Thermoelectric Materials Characterization for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Temperature Thermoelectric Materials Characterization for Automotive Waste Heat Recovery: Success Stories from the High Temperature Materials Laboratory (HTML) User Program...

  17. Manufacturing Barriers to High Temperature PEM Commercialization...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Barriers to High Temperature PEM Commercialization Manufacturing Barriers to High Temperature PEM Commercialization Presented at the NREL Hydrogen and Fuel Cell Manufacturing R&D...

  18. High pressure and high temperature apparatus

    DOE Patents [OSTI]

    Voronov, Oleg A.

    2005-09-13

    A design for high pressure/high temperature apparatus and reaction cell to achieve .about.30 GPa pressure in .about.1 cm volume and .about.100 GPa pressure in .about.1 mm volumes and 20-5000.degree. C. temperatures in a static regime. The device includes profiled anvils (28) action on a reaction cell (14, 16) containing the material (26) to be processed. The reaction cell includes a heater (18) surrounded by insulating layers and screens. Surrounding the anvils are cylindrical inserts and supporting rings (30-48) whose hardness increases towards the reaction cell. These volumes may be increased considerably if applications require it, making use of presses that have larger loading force capability, larger frames and using larger anvils.

  19. High temperature turbine engine structure

    DOE Patents [OSTI]

    Carruthers, William D. (Mesa, AZ); Boyd, Gary L. (Tempe, AZ)

    1993-01-01

    A high temperature ceramic/metallic turbine engine includes a metallic housing which journals a rotor member of the turbine engine. A ceramic disk-like shroud portion of the engine is supported on the metallic housing portion and maintains a close running clearance with the rotor member. A ceramic spacer assembly maintains the close running clearance of the shroud portion and rotor member despite differential thermal movements between the shroud portion and metallic housing portion.

  20. High temperature turbine engine structure

    DOE Patents [OSTI]

    Carruthers, William D. (Mesa, AZ); Boyd, Gary L. (Tempe, AZ)

    1994-01-01

    A high temperature ceramic/metallic turbine engine includes a metallic housing which journals a rotor member of the turbine engine. A ceramic disk-like shroud portion of the engine is supported on the metallic housing portion and maintains a close running clearance with the rotor member. A ceramic spacer assembly maintains the close running clearance of the shroud portion and rotor member despite differential thermal movements between the shroud portion and metallic housing portion.

  1. High temperature turbine engine structure

    DOE Patents [OSTI]

    Carruthers, William D. (Mesa, AZ); Boyd, Gary L. (Tempe, AZ)

    1992-01-01

    A high temperature ceramic/metallic turbine engine includes a metallic housing which journals a rotor member of the turbine engine. A ceramic disk-like shroud portion of the engine is supported on the metallic housing portion and maintains a close running clearance with the rotor member. A ceramic spacer assembly maintains the close running clearance of the shroud portion and rotor member despite differential thermal movements between the shroud portion and metallic housing portion.

  2. High Efficiency Modular Chemical Processes (HEMCP)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    - ADVANCED MANUFACTURING OFFICE High Efficiency Modular Chemical Processes (HEMCP) Modular Process Intensification Framework for R&D Targets Advanced Manufacturing Office...

  3. Chemical, Electronic and Nanostructure Dynamics on Sr(Ti1-xFex)O3 Thin-Film Surfaces at High Temperatures

    E-Print Network [OSTI]

    Yildiz, Bilge

    from solid oxide fuel cells (SOFC) at intermediate temperatures. Surface oxygen exchange and oxygen microstructure (3-6). However, the harsh operating environments of the SOFC make it difficult to probe on SOFC cathode surfaces. The material we chose to study is the Sr(Ti1-xFex)O3 (STF) solid solution system

  4. Optical characterization of InN layers grown by high-pressure chemical vapor deposition

    E-Print Network [OSTI]

    Dietz, Nikolaus

    Optical characterization of InN layers grown by high-pressure chemical vapor deposition M. Alevli properties of InN layers grown by high-pressure chemical vapor deposition have been studied. Raman, infrared at elevated temperatures, a high-pressure chemical vapor deposition HPCVD system has been established at GSU.6

  5. Faraday imaging at high temperatures

    DOE Patents [OSTI]

    Hackel, L.A.; Reichert, P.

    1997-03-18

    A Faraday filter rejects background light from self-luminous thermal objects, but transmits laser light at the passband wavelength, thus providing an ultra-narrow optical bandpass filter. The filter preserves images so a camera looking through a Faraday filter at a hot target illuminated by a laser will not see the thermal radiation but will see the laser radiation. Faraday filters are useful for monitoring or inspecting the uranium separator chamber in an atomic vapor laser isotope separation process. Other uses include viewing welds, furnaces, plasma jets, combustion chambers, and other high temperature objects. These filters are can be produced at many discrete wavelengths. A Faraday filter consists of a pair of crossed polarizers on either side of a heated vapor cell mounted inside a solenoid. 3 figs.

  6. Faraday imaging at high temperatures

    DOE Patents [OSTI]

    Hackel, Lloyd A. (Livermore, CA); Reichert, Patrick (Hayward, CA)

    1997-01-01

    A Faraday filter rejects background light from self-luminous thermal objects, but transmits laser light at the passband wavelength, thus providing an ultra-narrow optical bandpass filter. The filter preserves images so a camera looking through a Faraday filter at a hot target illuminated by a laser will not see the thermal radiation but will see the laser radiation. Faraday filters are useful for monitoring or inspecting the uranium separator chamber in an atomic vapor laser isotope separation process. Other uses include viewing welds, furnaces, plasma jets, combustion chambers, and other high temperature objects. These filters are can be produced at many discrete wavelengths. A Faraday filter consists of a pair of crossed polarizers on either side of a heated vapor cell mounted inside a solenoid.

  7. High temperature control rod assembly

    DOE Patents [OSTI]

    Vollman, Russell E. (Solana Beach, CA)

    1991-01-01

    A high temperature nuclear control rod assembly comprises a plurality of substantially cylindrical segments flexibly joined together in succession by ball joints. The segments are made of a high temperature graphite or carbon-carbon composite. The segment includes a hollow cylindrical sleeve which has an opening for receiving neutron-absorbing material in the form of pellets or compacted rings. The sleeve has a threaded sleeve bore and outer threaded surface. A cylindrical support post has a threaded shaft at one end which is threadably engaged with the sleeve bore to rigidly couple the support post to the sleeve. The other end of the post is formed with a ball portion. A hollow cylindrical collar has an inner threaded surface engageable with the outer threaded surface of the sleeve to rigidly couple the collar to the sleeve. the collar also has a socket portion which cooperates with the ball portion to flexibly connect segments together to form a ball and socket-type joint. In another embodiment, the segment comprises a support member which has a threaded shaft portion and a ball surface portion. The threaded shaft portion is engageable with an inner threaded surface of a ring for rigidly coupling the support member to the ring. The ring in turn has an outer surface at one end which is threadably engageably with a hollow cylindrical sleeve. The other end of the sleeve is formed with a socket portion for engagement with a ball portion of the support member. In yet another embodiment, a secondary rod is slidably inserted in a hollow channel through the center of the segment to provide additional strength. A method for controlling a nuclear reactor utilizing the control rod assembly is also included.

  8. LOW TEMPERATURE PHYSICS RADIATION EFFECTS ON HIGH

    E-Print Network [OSTI]

    McDonald, Kirk

    LOW TEMPERATURE PHYSICS RADIATION EFFECTS ON HIGH TEMPERATURE SUPERCONDUCTORS Harald W. Weber-induced Defects in HTS Practical Materials HTS4Fusion Conductor Workshop, KIT, 27 May 2011 #12;LOW TEMPERATURE;LOW TEMPERATURE PHYSICS Options / Materials "Demo" design (magnetic field, temperature, fluence

  9. Thermal disconnect for high-temperature batteries

    DOE Patents [OSTI]

    Jungst, Rudolph George (Albuquerque, NM); Armijo, James Rudolph (Albuquerque, NM); Frear, Darrel Richard (Austin, TX)

    2000-01-01

    A new type of high temperature thermal disconnect has been developed to protect electrical and mechanical equipment from damage caused by operation at extreme temperatures. These thermal disconnects allow continuous operation at temperatures ranging from 250.degree. C. to 450.degree. C., while rapidly terminating operation at temperatures 50.degree. C. to 150.degree. C. higher than the continuous operating temperature.

  10. Recent Developments in High Temperature Superconductivity 

    E-Print Network [OSTI]

    Hor, P. H.

    1988-01-01

    New material systems and the experimental progress of high temperature superconductivity are briefly reviewed. We examine both oxides and non-oxides which exhibit stable and/or unstable superconductivity at high temperatures....

  11. Highly Hazardous Chemicals and Chemical Spills EPA Compliance Fact Sheet

    E-Print Network [OSTI]

    Wikswo, John

    will be the direct cost charged to VEHS by our disposal contractor. VEHS does not mark up the disposal charges chemicals in your laboratory, leave them alone and notify VEHS immediately to arrange for disposal. Highly spills must be disposed of as hazardous waste. · Clean up spills when they happen or contact VEHS

  12. Agenda: High Temperature Membrane Working Group Meeting

    Broader source: Energy.gov [DOE]

    Agenda for the High Temperature Membrane Working Group (HTMWG) meeting on May 18, 2009, in Arlington, Virginia

  13. Process safety management for highly hazardous chemicals

    SciTech Connect (OSTI)

    1996-02-01

    Purpose of this document is to assist US DOE contractors who work with threshold quantities of highly hazardous chemicals (HHCs), flammable liquids or gases, or explosives in successfully implementing the requirements of OSHA Rule for Process Safety Management of Highly Hazardous Chemicals (29 CFR 1910.119). Purpose of this rule is to prevent releases of HHCs that have the potential to cause catastrophic fires, explosions, or toxic exposures.

  14. A High-Temperature Fuel Cell to Provide On-Site Process Reducing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    nitrogen gas often provides a reducing atmosphere for these processes. High-temperature fuel cells directly convert the chemical energy in its fuel to electricity, with water,...

  15. NOvel Refractory Materials for High Alkali, High Temperature Environments

    SciTech Connect (OSTI)

    Hemrick, J.G.; Griffin, R.

    2011-08-30

    Refractory materials can be limited in their application by many factors including chemical reactions between the service environment and the refractory material, mechanical degradation of the refractory material by the service environment, temperature limitations on the use of a particular refractory material, and the inability to install or repair the refractory material in a cost effective manner or while the vessel was in service. The objective of this project was to address the need for new innovative refractory compositions by developing a family of novel MgO-Al2O3 spinel or other similar magnesia/alumina containing unshaped refractory composition (castables, gunnables, shotcretes, etc) utilizing new aggregate materials, bond systems, protective coatings, and phase formation techniques (in-situ phase formation, altered conversion temperatures, accelerated reactions, etc). This family of refractory compositions would then be tailored for use in high-temperature, highalkaline industrial environments like those found in the aluminum, chemical, forest products, glass, and steel industries. A research team was formed to carry out the proposed work led by Oak Ridge National Laboratory (ORNL) and was comprised of the academic institution Missouri University of Science and Technology (MS&T), and the industrial company MINTEQ International, Inc. (MINTEQ), along with representatives from the aluminum, chemical, glass, and forest products industries. The two goals of this project were to produce novel refractory compositions which will allow for improved energy efficiency and to develop new refractory application techniques which would improve the speed of installation. Also methods of hot installation were sought which would allow for hot repairs and on-line maintenance leading to reduced process downtimes and eliminating the need to cool and reheat process vessels.

  16. High Temperature Superconducting Underground Cable

    SciTech Connect (OSTI)

    Farrell, Roger, A.

    2010-02-28

    The purpose of this Project was to design, build, install and demonstrate the technical feasibility of an underground high temperature superconducting (HTS) power cable installed between two utility substations. In the first phase two HTS cables, 320 m and 30 m in length, were constructed using 1st generation BSCCO wire. The two 34.5 kV, 800 Arms, 48 MVA sections were connected together using a superconducting joint in an underground vault. In the second phase the 30 m BSCCO cable was replaced by one constructed with 2nd generation YBCO wire. 2nd generation wire is needed for commercialization because of inherent cost and performance benefits. Primary objectives of the Project were to build and operate an HTS cable system which demonstrates significant progress towards commercial progress and addresses real world utility concerns such as installation, maintenance, reliability and compatibility with the existing grid. Four key technical areas addressed were the HTS cable and terminations (where the cable connects to the grid), cryogenic refrigeration system, underground cable-to-cable joint (needed for replacement of cable sections) and cost-effective 2nd generation HTS wire. This was the world’s first installation and operation of an HTS cable underground, between two utility substations as well as the first to demonstrate a cable-to-cable joint, remote monitoring system and 2nd generation HTS.

  17. New High-Temperature Superconductors

    E-Print Network [OSTI]

    Xie, Xiaoliang Sunney

    -TEMPERATURE superconductors, materials that carry electricity without resistance at temperatures inexplicably far above one finds its target. Computa- tional biologists in Germany and the United States offered bold new plenty going for them. They're abundant and carbon-free, and their prices are dropping. But they're part

  18. High temperature superconducting fault current limiter

    DOE Patents [OSTI]

    Hull, J.R.

    1997-02-04

    A fault current limiter for an electrical circuit is disclosed. The fault current limiter includes a high temperature superconductor in the electrical circuit. The high temperature superconductor is cooled below its critical temperature to maintain the superconducting electrical properties during operation as the fault current limiter. 15 figs.

  19. High temperature superconducting fault current limiter

    DOE Patents [OSTI]

    Hull, John R. (Hinsdale, IL)

    1997-01-01

    A fault current limiter (10) for an electrical circuit (14). The fault current limiter (10) includes a high temperature superconductor (12) in the electrical circuit (14). The high temperature superconductor (12) is cooled below its critical temperature to maintain the superconducting electrical properties during operation as the fault current limiter (10).

  20. Measurement of thermodynamic temperature of high temperature fixed points

    SciTech Connect (OSTI)

    Gavrilov, V. R.; Khlevnoy, B. B.; Otryaskin, D. A.; Grigorieva, I. A.; Samoylov, M. L.; Sapritsky, V. I.

    2013-09-11

    The paper is devoted to VNIIOFI's measurements of thermodynamic temperature of the high temperature fixed points Co-C, Pt-C and Re-C within the scope of the international project coordinated by the Consultative Committee for Thermometry working group 5 'Radiation Thermometry'. The melting temperatures of the fixed points were measured by a radiance mode radiation thermometer calibrated against a filter radiometer with known irradiance spectral responsivity via a high temperature black body. This paper describes the facility used for the measurements, the results and estimated uncertainties.

  1. Electronically conductive ceramics for high temperature oxidizing environments

    DOE Patents [OSTI]

    Kucera, Gene H. (Downers Grove, IL); Smith, James L. (Lemont, IL); Sim, James W. (Evergreen Park, IL)

    1986-01-01

    A high temperature, ceramic composition having electronic conductivity as measured by resistivity below about 500 ohm-cm, chemical stability particularly with respect to cathode conditions in a molten carbonate fuel cell, and composed of an alkali metal, transition metal oxide containing a dopant metal in the crystalline structure to replace a portion of the alkali metal or transition metal.

  2. Electronically conductive ceramics for high temperature oxidizing environments

    DOE Patents [OSTI]

    Kucera, G.H.; Smith, J.L.; Sim, J.W.

    1983-11-10

    This invention pertains to a high temperature, ceramic composition having electronic conductivity as measured by resistivity below about 500 ohm-cm, chemical stability particularly with respect to cathode conditions in a molten carbonate fuel cell, and composed of an alkali metal, transition metal oxide containing a dopant metal in the crystalline structure to replace a portion of the alkali metal or transition metal.

  3. LALP-06-043 MATERIALSSCIENCEANDTECHNOLOGYDIVISIONRESEARCHHIGHLIGHTMATERIALSSCIENCEANDTECHNOLOGYDIVISIONRESEARCHHIGHLIGHT High temperature separation membranes

    E-Print Network [OSTI]

    membrane in a synthesis gas separation requires a membrane that is thermally, chemically, and mechanically MATERIALSSCIENCEANDTECHNOLOGYDIVISIONRESEARCHHIGHLIGHTMATERIALSSCIENCEANDTECHNOLOGYDIVISIONRESEARCHHIGHLIGHT High temperature separation membranes for hydrogen purification and carbon capture K.A. Berchtold, polymer-based membrane separations are less energy intensive, requiring no phase change in the process

  4. Materials Characterization Capabilities at the High Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Laboratory and HTML User Program Success Stories Materials Characterization Capabilities at the High Temperature Materials Laboratory and HTML User Program Success Stories 2012 DOE...

  5. Materials Characterization Capabilities at the High Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    on Carbon Fiber and Composites Materials Characterization Capabilities at the High Temperature Materials Laboratory: Focus on Carbon Fiber and Composites 2011 DOE Hydrogen and Fuel...

  6. Materials Characterization Capabilities at the High Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    May 18-22, 2009 -- Washington D.C. lm01laracurzio.pdf More Documents & Publications Materials Characterization Capabilities at the High Temperature Materials Laboratory and HTML...

  7. Materials Characterization Capabilities at the High Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2010 -- Washington D.C. lm028laracurzio2010o.pdf More Documents & Publications Materials Characterization Capabilities at the High Temperature Materials Laboratory and HTML...

  8. Materials Characterization Capabilities at the High Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Review and Peer Evaluation lm028laracurzio2011o.pdf More Documents & Publications Materials Characterization Capabilities at the High Temperature Materials Laboratory and HTML...

  9. High-temperature brazed ceramic joints

    DOE Patents [OSTI]

    Jarvinen, Philip O. (Amherst, NH)

    1986-01-01

    High-temperature joints formed from metallized ceramics are disclosed wherein the metal coatings on the ceramics are vacuum sputtered thereon.

  10. Materials Characterization Capabilities at the High Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    at the High Temperature Materials Laboratory and HTML User Program Success Stories Low-Cost Magnesium Sheet Production using the Twin Roll Casting Process and Asymmetric Rolling...

  11. Quantitative Modeling of High Temperature Magnetization Dynamics

    SciTech Connect (OSTI)

    Zhang, Shufeng

    2009-03-01

    Final Technical Report Project title: Quantitative Modeling of High Temperature Magnetization Dynamics DOE/Office of Science Program Manager Contact: Dr. James Davenport

  12. BARNSTEAD|THERMOLYNE CORPORATION High Temperature

    E-Print Network [OSTI]

    Walker, D. Greg

    1 BARNSTEAD|THERMOLYNE CORPORATION High Temperature Muffle Furnace OPERATION MANUAL AND PARTS LIST ....................................................................................................................................................13 Furnace Connection: .........................................................................................................................13 General Operation of Furnace

  13. Photonic crystals for high temperature applications

    E-Print Network [OSTI]

    Yeng, Yi Xiang

    2014-01-01

    This thesis focuses on the design, optimization, fabrication, and experimental realization of metallic photonic crystals (MPhCs) for high temperature applications, for instance thermophotovoltaic (TPV) energy conversion ...

  14. Nanostructured High Temperature Bulk Thermoelectric Energy Conversion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    stage expected to show a 5% fuel efficiency improvement in vehicle platform under US06 drive cycle caylor.pdf More Documents & Publications Nanostructured High-Temperature Bulk...

  15. High Temperature Interactions of Antimony with Nickel

    SciTech Connect (OSTI)

    Marina, Olga A.; Pederson, Larry R.

    2012-07-01

    In this chapter, the surface and bulk interactions of antimony with the Ni-based anodes in solid oxide fuel cells (SOFC) will be discussed. High fuel flexibility is a significant advantage of SOFCs, allowing the direct use of fossil and bio fuels without a hydrogen separation unit. Synthesis gas derived from coal and biomass consists of a mixture of hydrogen, carbon monoxide, carbon dioxide, and steam, but finite amounts of tars and trace impurities such as S, Se, P, As, Sb, Cd, Pb, Cl, etc, are also always present. While synthesis gas is commonly treated with a series of chemical processes and scrubbers to remove the impurities, complete purification is not economical. Antimony is widely distributed in coals. During coal gasification antimony is volatilized, such that contact with the SOFC anodes and other SOFC parts, e.g., interconnect, current collecting wires, fuel gas supplying tubing, is most likely. This chapter addresses the following topics: high temperature Ni - Sb interactions; alteration phase, Ni3Sb, Ni5Sb2, NiSb, formation; thermochemical modeling; impact of Sb on the electrocatalytic activity of Ni toward the fuel oxidation and the presence of other impurities (sulfur, in particular); converted anode structural instability during long-term SOFC operation; comparison with nickel heterogeneous catalysts.

  16. Investigations into High Temperature Components and Packaging

    SciTech Connect (OSTI)

    Marlino, L.D.; Seiber, L.E.; Scudiere, M.B.; M.S. Chinthavali, M.S.; McCluskey, F.P.

    2007-12-31

    The purpose of this report is to document the work that was performed at the Oak Ridge National Laboratory (ORNL) in support of the development of high temperature power electronics and components with monies remaining from the Semikron High Temperature Inverter Project managed by the National Energy Technology Laboratory (NETL). High temperature electronic components are needed to allow inverters to operate in more extreme operating conditions as required in advanced traction drive applications. The trend to try to eliminate secondary cooling loops and utilize the internal combustion (IC) cooling system, which operates with approximately 105 C water/ethylene glycol coolant at the output of the radiator, is necessary to further reduce vehicle costs and weight. The activity documented in this report includes development and testing of high temperature components, activities in support of high temperature testing, an assessment of several component packaging methods, and how elevated operating temperatures would impact their reliability. This report is organized with testing of new high temperature capacitors in Section 2 and testing of new 150 C junction temperature trench insulated gate bipolar transistor (IGBTs) in Section 3. Section 4 addresses some operational OPAL-GT information, which was necessary for developing module level tests. Section 5 summarizes calibration of equipment needed for the high temperature testing. Section 6 details some additional work that was funded on silicon carbide (SiC) device testing for high temperature use, and Section 7 is the complete text of a report funded from this effort summarizing packaging methods and their reliability issues for use in high temperature power electronics. Components were tested to evaluate the performance characteristics of the component at different operating temperatures. The temperature of the component is determined by the ambient temperature (i.e., temperature surrounding the device) plus the temperature increase inside the device due the internal heat that is generated due to conduction and switching losses. Capacitors and high current switches that are reliable and meet performance specifications over an increased temperature range are necessary to realize electronics needed for hybrid-electric vehicles (HEVs), fuel cell (FC) and plug-in HEVs (PHEVs). In addition to individual component level testing, it is necessary to evaluate and perform long term module level testing to ascertain the effects of high temperature operation on power electronics.

  17. High Temperature | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas: Energy Resources Jump to:Hershey, Pennsylvania:HiddenTemperature Cements Jump

  18. SiC Field-Effect Devices Operating at High Temperature RUBY N. GHOSH13

    E-Print Network [OSTI]

    Ghosh, Ruby N.

    by monitoring the adhesion of the metal gates during high-temperature thermal cycling. A schematic of ourSiC Field-Effect Devices Operating at High Temperature RUBY N. GHOSH1­3 and PETER TOBIAS2 1 250°C. The MOS device operation in chemically corrosive, high-temperature environments places

  19. Development of a 100-Watt High Temperature Thermoelectric Generator...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a 100-Watt High Temperature Thermoelectric Generator Development of a 100-Watt High Temperature Thermoelectric Generator Test results for low and high temperature thermoelectric...

  20. High Temperature Electrochemistry Center - HiTEC

    SciTech Connect (OSTI)

    McVay, G.; Williams, M.

    2005-01-27

    This presentation discusses the High Temperature Electrochemistry Center (HiTEC). The mission of HiTEC is to advance the solid oxide technology, such as solid oxide, high temperature electrolysers, reversible fuel cells, energy storage devices, proton conductors, etc., for use in DG and FutureGen applications, and to conduct fundamental research that aids the general development of all solid oxide technology.

  1. High-performance chemical-bath deposited CdS thin-film transistors with ZrO2 gate dielectric

    E-Print Network [OSTI]

    Dondapati, Hareesh; Ha, Duc; Jenrette, Erin; Xiao, Bo; Pradhan, A. K

    2014-01-01

    2014) High-performance chemical-bath deposited CdS thin-filmWe demonstrate high performance chemical bath deposited CdSgeneration, inexpensive chemical-based low temperature

  2. Application of High Temperature Superconductors to Accelerators

    E-Print Network [OSTI]

    Ballarino, A

    2000-01-01

    Since the discovery of high temperature superconductivity, a large effort has been made by the scientific community to investigate this field towards a possible application of the new oxide superconductors to different devices like SMES, magnetic bearings, flywheels energy storage, magnetic shielding, transmission cables, fault current limiters, etc. However, all present day large scale applications using superconductivity in accelerator technology are based on conventional materials operating at liquid helium temperatures. Poor mechanical properties, low critical current density and sensitivity to the magnetic field at high temperature are the key parameters whose improvement is essential for a large scale application of high temperature superconductors to such devices. Current leads, used for transferring currents from the power converters, working at room temperature, into the liquid helium environment, where the magnets are operating, represent an immediate application of the emerging technology of high t...

  3. High Temperature Materials for Aerospace Applications 

    E-Print Network [OSTI]

    Adamczak, Andrea Diane

    2011-08-08

    ), bismaleimide (b), cyanate ester (c), and imide (d). ....................................................................................... 11 2.4 Use temperatures for common resin matrix composite materials. ............. 12 2.5 PMR-15 chemistry... properties.1-2 Additionally, fiber-reinforced high temperature polymer matrix composites are particularly attractive for aerospace structures because of their low density,2-3 high mechanical strength,2,4-10 high modulus,2,5,7-9 thermo-oxidative stability...

  4. High temperature solar selective coatings

    DOE Patents [OSTI]

    Kennedy, Cheryl E

    2014-11-25

    Improved solar collectors (40) comprising glass tubing (42) attached to bellows (44) by airtight seals (56) enclose solar absorber tubes (50) inside an annular evacuated space (54. The exterior surfaces of the solar absorber tubes (50) are coated with improved solar selective coatings {48} which provide higher absorbance, lower emittance and resistance to atmospheric oxidation at elevated temperatures. The coatings are multilayered structures comprising solar absorbent layers (26) applied to the meta surface of the absorber tubes (50), typically stainless steel, topped with antireflective Savers (28) comprising at least two layers 30, 32) of refractory metal or metalloid oxides (such as titania and silica) with substantially differing indices of refraction in adjacent layers. Optionally, at least one layer of a noble metal such as platinum can be included between some of the layers. The absorbent layers cars include cermet materials comprising particles of metal compounds is a matrix, which can contain oxides of refractory metals or metalloids such as silicon. Reflective layers within the coating layers can comprise refractory metal silicides and related compounds characterized by the formulas TiSi. Ti.sub.3SiC.sub.2, TiAlSi, TiAN and similar compounds for Zr and Hf. The titania can be characterized by the formulas TiO.sub.2, Ti.sub.3O.sub.5. TiOx or TiO.sub.xN.sub.1-x with x 0 to 1. The silica can be at least one of SiO.sub.2, SiO.sub.2x or SiO.sub.2xN.sub.1-x with x=0 to 1.

  5. Institute of Chemical Engineering and High Temperature Chemical Processes

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas: Energy ResourcesOrder at 8, 13 (Vt.InfinifuelInova Energy JumpEnvironmentalICEHT |

  6. High temperature ceramic/metal joint structure

    DOE Patents [OSTI]

    Boyd, Gary L. (Tempe, AZ)

    1991-01-01

    A high temperature turbine engine includes a hybrid ceramic/metallic rotor member having ceramic/metal joint structure. The disclosed joint is able to endure higher temperatures than previously possible, and aids in controlling heat transfer in the rotor member.

  7. Nonlinear high-temperature superconducting terahertz metamaterials

    E-Print Network [OSTI]

    Grady, Nathaniel K.

    We report the observation of a nonlinear terahertz response of split-ring resonator arrays made of high-temperature superconducting films. Intensity-dependent transmission measurements indicate that the resonance strength ...

  8. Development of a 500 Watt High Temperature Thermoelectric Generator...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a 500 Watt High Temperature Thermoelectric Generator Development of a 500 Watt High Temperature Thermoelectric Generator A low temperature TEG has been built and tested providing...

  9. High temperature thermometric phosphors for use in a temperature sensor

    DOE Patents [OSTI]

    Allison, Stephen W. (Knoxville, TN); Cates, Michael R. (Oak Ridge, TN); Boatner, Lynn A. (Oak Ridge, TN); Gillies, George T. (Earlysville, VA)

    1998-01-01

    A high temperature phosphor consists essentially of a material having the general formula LuPO.sub.4 :Dy.sub.(x),Eu.sub.(y), wherein: 0.1 wt %.ltoreq.x.ltoreq.20 wt % and 0.1 wt %.ltoreq.y.ltoreq.20 wt %. The high temperature phosphor is in contact with an article whose temperature is to be determined. The article having the phosphor in contact with it is placed in the environment for which the temperature of the article is to be determined. The phosphor is excited by a laser causing the phosphor to fluoresce. The emission from the phosphor is optically focused into a beam-splitting mirror which separates the emission into two separate emissions, the emission caused by the dysprosium dopant and the emission caused by the europium dopent. The separated emissions are optically filtered and the intensities of the emission are detected and measured. The ratio of the intensity of each emission is determined and the temperature of the article is calculated from the ratio of the intensities of the separate emissions.

  10. High temperature thermometric phosphors for use in a temperature sensor

    DOE Patents [OSTI]

    Allison, S.W.; Cates, M.R.; Boatner, L.A.; Gillies, G.T.

    1998-03-24

    A high temperature phosphor consists essentially of a material having the general formula LuPO{sub 4}:Dy{sub (x)},Eu{sub (y)}, wherein: 0.1 wt %{<=}x{<=}20 wt % and 0.1 wt %{<=}y{<=}20 wt %. The high temperature phosphor is in contact with an article whose temperature is to be determined. The article having the phosphor in contact with it is placed in the environment for which the temperature of the article is to be determined. The phosphor is excited by a laser causing the phosphor to fluoresce. The emission from the phosphor is optically focused into a beam-splitting mirror which separates the emission into two separate emissions, the emission caused by the dysprosium dopant and the emission caused by the europium dopant. The separated emissions are optically filtered and the intensities of the emission are detected and measured. The ratio of the intensity of each emission is determined and the temperature of the article is calculated from the ratio of the intensities of the separate emissions. 2 figs.

  11. Low Temperature Chemical Vapor Deposition Of Thin Film Magnets

    DOE Patents [OSTI]

    Miller, Joel S. (Salt Lake City, UT); Pokhodnya, Kostyantyn I. (Salt Lake City, UT)

    2003-12-09

    A thin-film magnet formed from a gas-phase reaction of tetracyanoetheylene (TCNE) OR (TCNQ), 7,7,8,8-tetracyano-P-quinodimethane, and a vanadium-containing compound such as vanadium hexcarbonyl (V(CO).sub.6) and bis(benzene)vanalium (V(C.sub.6 H.sub.6).sub.2) and a process of forming a magnetic thin film upon at least one substrate by chemical vapor deposition (CVD) at a process temperature not exceeding approximately 90.degree. C. and in the absence of a solvent. The magnetic thin film is particularly suitable for being disposed upon rigid or flexible substrates at temperatures in the range of 40.degree. C. and 70.degree. C. The present invention exhibits air-stable characteristics and qualities and is particularly suitable for providing being disposed upon a wide variety of substrates.

  12. Non-graphite crucible for high temperature applications

    DOE Patents [OSTI]

    Holcombe, Cressie E. (Knoxville, TN); Pfeiler, William A. (Norris, TN)

    1996-01-01

    A multi-piece crucible for high temperature applications comprises a tubular side wall member having a lip on the inside surface and a bottom member or members forming a container for containing a melt of a material during a high temperature melt-casting operations. The multi-piece design prevents cracking of the crucible or leakage of the melt from the crucible during the melt-casting operation. The lip of the tubular member supports the bottom member. The contacting surfaces where the lip of the tubular side wall member contacts the bottom member of the multi-piece crucible contains a ceramic sealing material. The ceramic sealing material forms a seal sufficient to prevent the melt of the material from leaking out of the multi-piece crucible during the melt-casting process. The multi-piece crucible is made of a material which is chemically inert to the melt and has structural integrity at the melting point temperature of the melt, or of a material coated with such a material. The multi-piece crucible is contained in a thermal can assembly of a high temperature induction furnace during a high temperature melt-casting operation. One embodiment of the multi-piece crucible comprises a tubular member having a vertical slot filled with a ceramic sealing material to provide expansion of the tubular member without cracking during the high temperature melt-casting operation.

  13. Non-graphite crucible for high temperature applications

    DOE Patents [OSTI]

    Holcombe, C.E.; Pfeiler, W.A.

    1996-01-09

    A multi-piece crucible for high temperature applications comprises a tubular side wall member having a lip on the inside surface and a bottom member or members forming a container for containing a melt of a material during a high temperature melt-casting operations. The multi-piece design prevents cracking of the crucible or leakage of the melt from the crucible during the melt-casting operation. The lip of the tubular member supports the bottom member. The contacting surfaces where the lip of the tubular side wall member contacts the bottom member of the multi-piece crucible contains a ceramic sealing material. The ceramic sealing material forms a seal sufficient to prevent the melt of the material from leaking out of the multi-piece crucible during the melt-casting process. The multi-piece crucible is made of a material which is chemically inert to the melt and has structural integrity at the melting point temperature of the melt, or of a material coated with such a material. The multi-piece crucible is contained in a thermal can assembly of a high temperature induction furnace during a high temperature melt-casting operation. One embodiment of the multi-piece crucible comprises a tubular member having a vertical slot filled with a ceramic sealing material to provide expansion of the tubular member without cracking during the high temperature melt-casting operation. 9 figs.

  14. Apparatus and method for high temperature viscosity and temperature measurements

    DOE Patents [OSTI]

    Balasubramaniam, Krishnan (Mississippi State, MS); Shah, Vimal (Houston, TX); Costley, R. Daniel (Mississippi State, MS); Singh, Jagdish P. (Mississippi State, MS)

    2001-01-01

    A probe for measuring the viscosity and/or temperature of high temperature liquids, such as molten metals, glass and similar materials comprises a rod which is an acoustical waveguide through which a transducer emits an ultrasonic signal through one end of the probe, and which is reflected from (a) a notch or slit or an interface between two materials of the probe and (b) from the other end of the probe which is in contact with the hot liquid or hot melt, and is detected by the same transducer at the signal emission end. To avoid the harmful effects of introducing a thermally conductive heat sink into the melt, the probe is made of relatively thermally insulative (non-heat-conductive) refractory material. The time between signal emission and reflection, and the amplitude of reflections, are compared against calibration curves to obtain temperature and viscosity values.

  15. High Temperature, Permanent Magnet Biased Magnetic Bearings 

    E-Print Network [OSTI]

    Gandhi, Varun R.

    2010-07-14

    performance, high speed and high temperature applications like space vehicles, jet engines and deep sea equipment. The bearing system had a target design to carry a load equal to 500 lb-f (2225N). Another objective was to design and build a test rig fixture...

  16. Materials and Process Design for High-Temperature Carburizing...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials and Process Design for High-Temperature Carburizing Materials and Process Design for High-Temperature Carburizing New Class of High-Performance Carburized Steels Saves...

  17. Survival of charged rho condensation at high temperature and density

    E-Print Network [OSTI]

    Liu, Hao; Huang, Mei

    2015-01-01

    The charged vector $\\rho$ mesons in the presence of external magnetic fields at finite temperature $T$ and chemical potential $\\mu$ have been investigated in the framework of the Nambu--Jona-Lasinio model. We compute the masses of charged $\\rho$ mesons numerically as a function of the magnetic field for different values of temperature and chemical potential. The self-energy of the $\\rho$ meson contains the quark-loop contribution, i.e. the leading order contribution in $1/N_c$ expansion. The charged $\\rho$ meson mass decreases with the magnetic field and drops to zero at a critical magnetic field $eB_c$, which means that the charged vector meson condensation, i.e. the electromagnetic superconductor can be induced above the critical magnetic field. Surprisingly, it is found that the charged $\\rho$ condensation can even survive at high temperature and density. At zero temperature, the critical magnetic field just increases slightly with the chemical potential, which indicates that the charged $\\rho$ condensatio...

  18. Development of a High Temperature Gas-Cooled Reactor TRISO-coated particle fuel chemistry model

    E-Print Network [OSTI]

    Diecker, Jane T

    2005-01-01

    The first portion of this work is a comprehensive analysis of the chemical environment in a High Temperature Gas-Cooled Reactor TRISO fuel particle. Fission product inventory versus burnup is calculated. Based on those ...

  19. Field Demonstration of High Efficiency Ultra-Low-Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ultra-Low-Temperature Laboratory Freezers Field Demonstration of High Efficiency Ultra-Low-Temperature Laboratory Freezers Ultra-low temperature laboratory freezers (ULTs) are some...

  20. High Temperature Materials Interim Data Qualification Report

    SciTech Connect (OSTI)

    Nancy Lybeck

    2010-08-01

    ABSTRACT Projects for the very high temperature reactor (VHTR) Technology Development Office provide data in support of Nuclear Regulatory Commission licensing of the VHTR. Fuel and materials to be used in the reactor are tested and characterized to quantify performance in high temperature and high fluence environments. The VHTR program has established the NGNP Data Management and Analysis System (NDMAS) to ensure that VHTR data are qualified for use, stored in a readily accessible electronic form, and analyzed to extract useful results. This document focuses on the first NDMAS objective. It describes the High Temperature Materials characterization data stream, the processing of these data within NDMAS, and reports the interim FY2010 qualification status of the data. Data qualification activities within NDMAS for specific types of data are determined by the data qualification category assigned by the data generator. The High Temperature Materials data are being collected under NQA-1 guidelines, and will be qualified data. For NQA-1 qualified data, the qualification activities include: (1) capture testing, to confirm that the data stored within NDMAS are identical to the raw data supplied, (2) accuracy testing to confirm that the data are an accurate representation of the system or object being measured, and (3) documenting that the data were collected under an NQA-1 or equivalent Quality Assurance program. Currently, data from two test series within the High Temperature Materials data stream have been entered into the NDMAS vault: 1. Tensile Tests for Sm (i.e., Allowable Stress) Confirmatory Testing – 1,403,994 records have been inserted into the NDMAS database. Capture testing is in process. 2. Creep-Fatigue Testing to Support Determination of Creep-Fatigue Interaction Diagram – 918,854 records have been processed and inserted into the NDMAS database. Capture testing is in process.

  1. Shock-induced synthesis of high temperature superconducting materials

    DOE Patents [OSTI]

    Ginley, D.S.; Graham, R.A.; Morosin, B.; Venturini, E.L.

    1987-06-18

    It has now been determined that the unique features of the high pressure shock method, especially the shock-induced chemical synthesis technique, are fully applicable to high temperature superconducting materials. Extraordinarily high yields are achievable in accordance with this invention, e.g., generally in the range from about 20% to about 99%, often in the range from about 50% to about 90%, lower and higher yields, of course, also being possible. The method of this invention involves the application of a controlled high pressure shock compression pulse which can be produced in any conventional manner, e.g., by detonation of a high explosive material, the impact of a high speed projectile or the effect of intense pulsed radiation sources such as lasers or electron beams. Examples and a discussion are presented.

  2. Safety Issues for High Temperature Gas Reactors

    E-Print Network [OSTI]

    . · Behavior of fuel, fission product release behavior in reactor building and structures under accidentSafety Issues for High Temperature Gas Reactors Andrew C. Kadak Professor of the Practice #12;Major Consequences AOO AC SPC Challenges DESIGN BASIS * Severe challenge to the Fission Products Confinement Function

  3. ELECTRONIC CERAMICS IN HIGH TEMPERATURE ENVIRONMENTS

    E-Print Network [OSTI]

    Searcy, A.W.

    2010-01-01

    o n on E l e c t r o n i c Ceramics i n Severe Environments,d i n t h e B u l l e t i n o f the American Ceramic S o c ie t y ELECTRONIC CERAMICS IN HIGH TEMPERATURE ENVIRONMENTS

  4. Fabrication and Characterization of Uranium-based High Temperature...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    bed chemical vapor deposition in a 50-mm diameter conical chamber within the coating furnace. Computer control of temperature and gas composition ensures reproducibility and...

  5. High Country Rose Greenhouses Greenhouse Low Temperature Geothermal...

    Open Energy Info (EERE)

    High Country Rose Greenhouses Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name High Country Rose Greenhouses Greenhouse Low Temperature Geothermal...

  6. Enhanced High Temperature Performance of NOx Storage/Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CLEERS Aftertreatment Modeling and Analysis Enhanced High Temperature Performance of NOx StorageReduction (NSR) Materials Enhanced High and Low Temperature Performance of NOx...

  7. Project Profile: Fundamental Corrosion Studies in High-Temperature...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fundamental Corrosion Studies in High-Temperature Molten Salt Systems for Next-Generation CSP Systems Project Profile: Fundamental Corrosion Studies in High-Temperature Molten Salt...

  8. High Temperature Fuel Cells in the European Union

    Broader source: Energy.gov [DOE]

    Presentation on High Temperature Fuel Cells in the European Union to the High Temperature Membrane Working Group, May 25, 2004 in Philadelphia, PA.

  9. A High Temperature Direct Vehicle Exhaust Flowmeter for Heavy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A High Temperature Direct Vehicle Exhaust Flowmeter for Heavy Duty Diesel Emission Measurements. A High Temperature Direct Vehicle Exhaust Flowmeter for Heavy Duty Diesel Emission...

  10. High Temperature Thermal Array for Next Generation Solar Thermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Temperature Thermal Array for Next Generation Solar Thermal Power Production High Temperature Thermal Array for Next Generation Solar Thermal Power Production This...

  11. Development of Advanced High Temperature Fuel Cell Membranes

    Broader source: Energy.gov [DOE]

    Presentation on Development of Advanced High Temperature Fuel Cell Membranes to the High Temperature Membrane Working Group Meeting held in Arlington, Virginia, May 26,2005.

  12. Syngas Enhanced High Efficiency Low Temperature Combustion for...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Enhanced High Efficiency Low Temperature Combustion for Clean Diesel Engines Syngas Enhanced High Efficiency Low Temperature Combustion for Clean Diesel Engines A significant...

  13. Low Temperature Combustion Demonstrator for High Efficiency Clean...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Demonstrator for High Efficiency Clean Combustion Low Temperature Combustion Demonstrator for High Efficiency Clean Combustion Applied low temperature combustion to the Navistar...

  14. Low-Temperature Combustion Demonstrator for High-Efficiency Clean...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low-Temperature Combustion Demonstrator for High-Efficiency Clean Combustion Low-Temperature Combustion Demonstrator for High-Efficiency Clean Combustion 2010 DOE Vehicle...

  15. Low Temperature Combustion Demonstrator for High Efficiency Clean...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Temperature Combustion Demonstrator for High Efficiency Clean Combustion Low Temperature Combustion Demonstrator for High Efficiency Clean Combustion 2009 DOE Hydrogen Program...

  16. Nanostructured High-Temperature Bulk Thermoelectric Energy Conversion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Temperature Bulk Thermoelectric Energy Conversion for Efficient Automotive Waste Heat Recovery Nanostructured High-Temperature Bulk Thermoelectric Energy Conversion for...

  17. High Operating Temperature Heat Transfer Fluids for Solar Thermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Operating Temperature Heat Transfer Fluids for Solar Thermal Power Generation FY13 Q1 High Operating Temperature Heat Transfer Fluids for Solar Thermal Power Generation FY13...

  18. Low and high Temperature Dual Thermoelectric Generation Waste...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and high Temperature Dual Thermoelectric Generation Waste Heat Recovery System for Light-Duty Vehicles Low and high Temperature Dual Thermoelectric Generation Waste Heat Recovery...

  19. High Temperature Polymer Membrane Development at Argonne National Laboratory

    Broader source: Energy.gov [DOE]

    Summary of ANL’s high temperature polymer membrane work presented to the High Temperature Membrane Working Group Meeting, Orlando FL, October 17, 2003

  20. Chemical Elements at High and Low Redshifts

    E-Print Network [OSTI]

    Max Pettini

    2006-03-02

    The past few years have seen a steady progress in the determination of element abundances at high redshifts, with new and more accurate measures of metallicities in star-forming galaxies, in QSO absorbers, and in the intergalactic medium. We have also become more aware of the limitations of the tools at our disposal in such endeavours. I summarise these recent developments and--in tune with the theme of this meeting--consider the clues which chemical abundance studies offer to the links between the high redshift galaxy populations and today's galaxies. The new data are `fleshing out' the overall picture of element abundances at redshifts z = 2 - 3 which has been gradually coming into focus over the last decade. In particular, we can now account for at least 40% of the metals produced by the global star formation activity in the universe from the Big Bang to z = 2.5, and we have strong indications of where the remainder are likely to be found.

  1. Compliant high temperature seals for dissimilar materials

    DOE Patents [OSTI]

    Rynders, Steven Walton (Fogelsville, PA); Minford, Eric (Laurys Station, PA); Tressler, Richard Ernest (Boalsburg, PA); Taylor, Dale M. (Salt Lake City, UT)

    2001-01-01

    A high temperature, gas-tight seal is formed by utilizing one or more compliant metallic toroidal ring sealing elements, where the applied pressure serves to activate the seal, thus improving the quality of the seal. The compliant nature of the sealing element compensates for differences in thermal expansion between the materials to be sealed, and is particularly useful in sealing a metallic member and a ceramic tube art elevated temperatures. The performance of the seal may be improved by coating the sealing element with a soft or flowable coating such as silver or gold and/or by backing the sealing element with a bed of fine powder. The material of the sealing element is chosen such that the element responds to stress elastically, even at elevated temperatures, permitting the seal to operate through multiple thermal cycles.

  2. A Detailed Chemical Kinetic Analysis of Low Temperature Non-Sooting Diesel Combustion

    SciTech Connect (OSTI)

    Aceves, S M; Flowers, D L

    2004-10-01

    We have developed a model of the diesel fuel injection process for application to analysis of low temperature non-sooting combustion. The model uses a simplified mixing correlation and detailed chemical kinetics, and analyzes a parcel of fuel as it moves along the fuel jet, from injection into evaporation and ignition. The model predicts chemical composition and soot precursors, and is applied at conditions that result in low temperature non-sooting combustion. Production of soot precursors is the first step toward production of soot, and modeling precursor production is expected to give insight into the overall evolution of soot inside the engine. The results of the analysis show that the model has been successful in describing many of the observed characteristics of low temperature combustion. The model predicts results that are qualitatively similar to those obtained for soot formation experiments at conditions in which the EGR rate is increased from zero to very high values as the fueling rate is kept constant. The model also describes the two paths to achieve non-sooting combustion. The first is smokeless rich combustion and the second is modulated kinetics (MK). The importance of the temperature after ignition and the equivalence ratio at the time of ignition is demonstrated, as these parameters can be used to collapse onto a single line all the results for soot precursors for multiple fueling rates. A parametric analysis indicates that precursor formation increases considerably as the gas temperature in the combustion chamber and the characteristic mixing time are increased. The model provides a chemical kinetic description of low temperature diesel combustion that improves the understanding of this clean and efficient regime of operation.

  3. Thermal fuse for high-temperature batteries

    DOE Patents [OSTI]

    Jungst, Rudolph G. (Albuquerque, NM); Armijo, James R. (Albuquerque, NM); Frear, Darrel R. (Austin, TX)

    2000-01-01

    A thermal fuse, preferably for a high-temperature battery, comprising leads and a body therebetween having a melting point between approximately 400.degree. C. and 500.degree. C. The body is preferably an alloy of Ag--Mg, Ag--Sb, Al--Ge, Au--In, Bi--Te, Cd--Sb, Cu--Mg, In--Sb, Mg--Pb, Pb--Pd, Sb--Zn, Sn--Te, or Mg--Al.

  4. Electronic Applications of High Temperature Superconductors 

    E-Print Network [OSTI]

    Kroger, H.; Miracky, R. F.

    1988-01-01

    of the high temperature superconductors in advanced radar systems. The low loss microwave properties of superconductors have already been exploited by Lincoln Laboratory in demonstrating signal processing systems whose capabilities greatly exceed any... from estimates of its surface im pedance for naturally occurring low-frequency electromagnetic waves. Low-frequen y (10. 3 to let Hz) fluctuations in the earth's magnetic field induce eddy currents at its surface; the size of the induced voltage...

  5. Advanced High-Temperature, High-Pressure Transport Reactor Gasification

    SciTech Connect (OSTI)

    Michael Swanson; Daniel Laudal

    2008-03-31

    The U.S. Department of Energy (DOE) National Energy Technology Laboratory Office of Coal and Environmental Systems has as its mission to develop advanced gasification-based technologies for affordable, efficient, zero-emission power generation. These advanced power systems, which are expected to produce near-zero pollutants, are an integral part of DOE's Vision 21 Program. DOE has also been developing advanced gasification systems that lower the capital and operating costs of producing syngas for chemical production. A transport reactor has shown potential to be a low-cost syngas producer compared to other gasification systems since its high-throughput-per-unit cross-sectional area reduces capital costs. This work directly supports the Power Systems Development Facility utilizing the KBR transport reactor located at the Southern Company Services Wilsonville, Alabama, site. Over 2800 hours of operation on 11 different coals ranging from bituminous to lignite along with a petroleum coke has been completed to date in the pilot-scale transport reactor development unit (TRDU) at the Energy & Environmental Research Center (EERC). The EERC has established an extensive database on the operation of these various fuels in both air-blown and oxygen-blown modes utilizing a pilot-scale transport reactor gasifier. This database has been useful in determining the effectiveness of design changes on an advanced transport reactor gasifier and for determining the performance of various feedstocks in a transport reactor. The effects of different fuel types on both gasifier performance and the operation of the hot-gas filter system have been determined. It has been demonstrated that corrected fuel gas heating values ranging from 90 to 130 Btu/scf have been achieved in air-blown mode, while heating values up to 230 Btu/scf on a dry basis have been achieved in oxygen-blown mode. Carbon conversions up to 95% have also been obtained and are highly dependent on the oxygen-coal ratio. Higher-reactivity (low-rank) coals appear to perform better in a transport reactor than the less reactive bituminous coals. Factors that affect TRDU product gas quality appear to be coal type, temperature, and air/coal ratios. Testing with a higher-ash, high-moisture, low-rank coal from the Red Hills Mine of the Mississippi Lignite Mining Company has recently been completed. Testing with the lignite coal generated a fuel gas with acceptable heating value and a high carbon conversion, although some drying of the high-moisture lignite was required before coal-feeding problems were resolved. No ash deposition or bed material agglomeration issues were encountered with this fuel. In order to better understand the coal devolatilization and cracking chemistry occurring in the riser of the transport reactor, gas and solid sampling directly from the riser and the filter outlet has been accomplished. This was done using a baseline Powder River Basin subbituminous coal from the Peabody Energy North Antelope Rochelle Mine near Gillette, Wyoming.

  6. Conformal Properties in High Temperature QCD

    E-Print Network [OSTI]

    Ishikawa, K -I; Nakayama, Yu; Yoshie, T

    2015-01-01

    We investigate the properties of quarks and gluons above the chiral phase transition temperature $T_c,$ using the RG improved gauge action and the Wilson quark action with two degenerate quarks mainly on a $32^3\\times 16$ lattice. In the one-loop perturbation theory, the thermal ensemble is dominated by the gauge configurations with effectively $Z(3)$ center twisted boundary conditions, making the thermal expectation value of the spatial Polyakov loop take a non-trivial $Z(3)$ center. This is in agreement with our lattice simulation of high temperature QCD. We further observe that the temporal propagator of massless quarks at extremely high temperature $\\beta=100.0 \\, (T \\simeq10^{58} T_c)$ remarkably agrees with the temporal propagator of free quarks with the $Z(3)$ twisted boundary condition for $t/L_t \\geq 0.2$, but differs from that with the $Z(3)$ trivial boundary condition. As we increase the mass of quarks $m_q$, we find that the thermal ensemble continues to be dominated by the $Z(3)$ twisted gauge fi...

  7. High temperature behavior of zirconium germanates

    SciTech Connect (OSTI)

    Utkin, A.V., E-mail: utkinalex@hotmail.com [Institute of Solid State Chemistry and Mechanochemistry SB RAS, 18 Kutateladze st., Novosibirsk 630128 (Russian Federation); Baklanova, N.I. [Institute of Solid State Chemistry and Mechanochemistry SB RAS, 18 Kutateladze st., Novosibirsk 630128 (Russian Federation); Vasilyeva, I.G. [Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Acad. Lavrentiev ave, Novosibirsk 630090 (Russian Federation)

    2013-05-01

    The high temperature behavior of zirconium germanates ZrGeO? and Zr?GeO? up to 2300 °C has been studied using the original photoemission thermal analysis technique with the comprehensive physicochemical study of solid and gaseous intermediate and final products. The two-stage process of incongruent sublimation of GeO? was established and the phase boundary of the homogeneity range for ZrGeO? and Zr?GeO? were deduced from the thermal analysis, X-ray diffraction and Raman spectroscopy studies. A high tendency to sintering of the final ZrO? product is discussed. - Graphical abstract: The decomposition of zirconium germanates leads to the formation of gaseous GeO? and solid sintered ZrO? and occurs via two stages with the formation of intermediate ZrO?-rich solid solution. Highlights: •Thermal behavior of ZrGeO? and Zr?GeO? was studied using the original thermal analysis technique in wide temperature range. •The decomposition occurs via two stages with the formation of intermediate ZrO?-rich solid solution. •The decomposition of zirconium germanates leads to the formation of gaseous GeO? and solid sintered ZrO?. •The temperature of decomposition is strongly depended on the total gas pressure.

  8. Nanoscale Morphological and Chemical Changes of High Voltage...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanoscale Morphological and Chemical Changes of High Voltage Lithium-Manganese Rich NMC Composite Cathodes with Cycling Friday, August 29, 2014 Renewable energy is critical for the...

  9. Low Temperature Combustion with Thermo-Chemical Recuperation to Maximize In-Use Engine Efficiency

    SciTech Connect (OSTI)

    Nigel N. Clark; Francisco Posada; Clinton Bedick; John Pratapas; Aleksandr Kozlov; Martin Linck; Dmitri Boulanov

    2009-03-30

    The key to overcome Low Temperature Combustion (LTC) load range limitations in reciprocating engines is based on proper control over the thermo-chemical properties of the in-cylinder charge. The studied alternative to achieve the required control of LTC is the use of two separate fuel streams to regulate timing and heat release at specific operational points, where the secondary fuel is a reformed product of the primary fuel in the tank. It is proposed in this report that the secondary fuel can be produced using exhaust heat and Thermo-Chemical Recuperation (TCR). TCR for reciprocating engines is a system that employs high efficiency recovery of sensible heat from engine exhaust gas and uses this energy to transform fuel composition. The recuperated sensible heat is returned to the engine as chemical energy. Chemical conversions are accomplished through catalytic and endothermic reactions in a specially designed reforming reactor. An equilibrium model developed by Gas Technology Institute (GTI) for heptane steam reforming was applied to estimate reformed fuel composition at different reforming temperatures. Laboratory results, at a steam/heptane mole ratio less than 2:1, confirm that low temperature reforming reactions, in the range of 550 K to 650 K, can produce 10-30% hydrogen (by volume, wet) in the product stream. Also, the effect of trading low mean effective pressure for displacement to achieve power output and energy efficiency has been explored by WVU. A zerodimensional model of LTC using heptane as fuel and a diesel Compression Ignition (CI) combustion model were employed to estimate pressure, temperature and total heat release as inputs for a mechanical and thermal loss model. The model results show that the total cooling burden on an LTC engine with lower power density and higher displacement was 14.3% lower than the diesel engine for the same amount of energy addition in the case of high load (43.57mg fuel/cycle). These preliminary modeling and experimental results suggest that the LTC-TCR combination may offer a high efficiency solution to engine operation. A single zone model using a detailed chemical kinetic mechanism was implemented in CHEMKIN and to study the effects of base fuel and steam-fuel reforming products on the ignition timing and heat release characteristics. The study was performed considering the reformed fuel species composition for total n-heptane conversion (ideal case) and also at the composition corresponding to a specific set of operational reforming temperatures (real case). The computational model confirmed that the reformed products have a strong influence on the low temperature heat release (LTHR) region, affecting the onset of the high temperature heat release (HTHR). The ignition timing was proportionally delayed with respect to the baseline fuel case when higher concentrations of reformed gas were used. For stoichiometric concentration of RG, it was found that by increasing the proportion of reformed fuel to total fuel (RG), from 0% to 30%, the amount of energy released during the LTHR regime, or HR{sub L}, was reduced by 48% and the ignition timing was delayed 10.4 CA degrees with respect to the baseline fuel case. For RG composition corresponding to certain operational reforming temperatures, it was found that the most significant effects on the HCCI combustion, regarding HR{sub L} reduction and CA50 delay, was obtained by RG produced at a reforming temperature range of 675 K-725 K.

  10. Heterogeneous metasurface for high temperature selective emission

    SciTech Connect (OSTI)

    Woolf, D., E-mail: dwoolf@psicorp.com; Hensley, J. [Physical Sciences, Inc., 20 New England Business Center, Andover, Massachusetts 01810 (United States); Cederberg, J. G.; Bethke, D. T.; Grine, A. D.; Shaner, E. A. [Sandia National Laboratories, P.O. Box 5800, Albuquerque, New Mexico 87185 (United States)

    2014-08-25

    We demonstrate selective emission from a heterogeneous metasurface that can survive repeated temperature cycling at 1300?K. Simulations, fabrication, and characterization were performed for a cross-over-a-backplane metasurface consisting of platinum and alumina layers on a sapphire substrate. The structure was stabilized for high temperature operation by an encapsulating alumina layer. The geometry was optimized for integration into a thermophotovoltaic (TPV) system, and was designed to have its emissivity matched to the external quantum efficiency spectrum of 0.6?eV InGaAs TPV material. We present spectral measurements of the metasurface that result in a predicted 22% optical-to-electrical power conversion efficiency in a simplified model at 1300?K. Furthermore, this broadly adaptable selective emitter design can be easily integrated into full-scale TPV systems.

  11. High Temperature 300°C Directional Drilling System

    SciTech Connect (OSTI)

    Chatterjee, Kamalesh; Aaron, Dick; Macpherson, John

    2015-07-31

    Many countries around the world, including the USA, have untapped geothermal energy potential. Enhanced Geothermal Systems (EGS) technology is needed to economically utilize this resource. Temperatures in some EGS reservoirs can exceed 300°C. To effectively utilize EGS resources, an array of injector and production wells must be accurately placed in the formation fracture network. This requires a high temperature directional drilling system. Most commercial services for directional drilling systems are rated for 175°C while geothermal wells require operation at much higher temperatures. Two U.S. Department of Energy (DOE) Geothermal Technologies Program (GTP) projects have been initiated to develop a 300°C capable directional drilling system, the first developing a drill bit, directional motor, and drilling fluid, and the second adding navigation and telemetry systems. This report is for the first project, “High Temperature 300°C Directional Drilling System, including drill bit, directional motor and drilling fluid, for enhanced geothermal systems,” award number DE-EE0002782. The drilling system consists of a drill bit, a directional motor, and drilling fluid. The DOE deliverables are three prototype drilling systems. We have developed three drilling motors; we have developed four roller-cone and five Kymera® bits; and finally, we have developed a 300°C stable drilling fluid, along with a lubricant additive for the metal-to-metal motor. Metal-to-metal directional motors require coatings to the rotor and stator for wear and corrosion resistance, and this coating research has been a significant part of the project. The drill bits performed well in the drill bit simulator test, and the complete drilling system has been tested drilling granite at Baker Hughes’ Experimental Test Facility in Oklahoma. The metal-to-metal motor was additionally subjected to a flow loop test in Baker Hughes’ Celle Technology Center in Germany, where it ran for more than 100 hours.

  12. High power densities from high-temperature material interactions

    SciTech Connect (OSTI)

    Morris, J.F.

    1981-01-01

    Thermionic energy conversion (TEC) and metallic-fluid heat pipes (MFHPs) offer important and unique advantages in terrestrial and space energy processing. And they are well suited to serve together synergistically. TEC and MFHPs operate through working-fluid vaporization, condensation cycles that accept great thermal power densities at high temperatures. TEC and MFHPs have apparently simple, isolated performance mechanisms that are somewhat similar. And they also have obviously difficult, complected material problems that again are somewhat similar. Intensive investigation reveals that aspects of their operating cycles and material problems tend to merge: high-temperature material effects determine the level and lifetime of performance. Simplified equations verify the preceding statement for TEC and MFHPs. Material properties and interactions exert primary influences on operational effectiveness. And thermophysicochemical stabilities dictate operating temperatures which regulate the thermoemissive currents of TEC and the vaporization flow rates of MFHPs. Major high-temperature material problems of TEC and MFHPs have been solved. These solutions lead to productive, cost-effective applications of current TEC and MFHPs - and point to significant improvements with anticipated technological gains.

  13. Cobalt doped lanthanum chromite material suitable for high temperature use

    DOE Patents [OSTI]

    Ruka, R.J.

    1986-12-23

    A high temperature, solid electrolyte electrochemical cell, subject to thermal cycling temperatures of between about 25 C and about 1,200 C, capable of electronic interconnection to at least one other electrochemical cell and capable of operating in an environment containing oxygen and a fuel, is made; where the cell has a first and second electrode with solid electrolyte between them, where an improved interconnect material is applied along a portion of a supporting electrode; where the interconnect is made of a chemically modified lanthanum chromite, containing cobalt as the important additive, which interconnect allows for adjustment of the thermal expansion of the interconnect material to more nearly match that of other cell components, such as zirconia electrolyte, and is stable in oxygen containing atmospheres such as air and in fuel environments. 2 figs.

  14. Cobalt doped lanthanum chromite material suitable for high temperature use

    DOE Patents [OSTI]

    Ruka, Roswell J. (Churchill, PA)

    1986-01-01

    A high temperature, solid electrolyte electrochemical cell, subject to thermal cycling temperatures of between about 25.degree. C. and about 1200.degree. C., capable of electronic interconnection to at least one other electrochemical cell and capable of operating in an environment containing oxygen and a fuel, is made; where the cell has a first and second electrode with solid electrolyte between them, where an improved interconnect material is applied along a portion of a supporting electrode; where the interconnect is made of a chemically modified lanthanum chromite, containing cobalt as the important additive, which interconnect allows for adjustment of the thermal expansion of the interconnect material to more nearly match that of other cell components, such as zirconia electrolyte, and is stable in oxygen containing atmospheres such as air and in fuel environments.

  15. Ultra High Temperature | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page| Open Energy Information Serbia-EnhancingEt Al.,Turin, New York: EnergyU.S. EPAEnergyUltra High Temperature Jump to:

  16. Sandia Energy - High-Temperature Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation of Fe(II)Geothermal Energy & Drilling TechnologyHeavyHigh-Temperature Materials

  17. Linear Sigma Model at Finite Temperature and Baryonic Chemical Potential Using the Midpoint Technique

    E-Print Network [OSTI]

    M. Abu-Shady

    2014-03-13

    A baryonic chemical potential is included in the linear sigma model at finite temperature. The effective mesonic potential is numerically calculated using the midpoint technique. The meson masses are investigated as functions of the temperature at fixed value of baryonic chemical potential. The pressure and energy density are investigated as functions of temperature at fixed value of chemical potential. The obtained results are in good agreement in comparison with other techniques. We conclude that the calculated effective potential successfully predicts the meson properties and thermodynamic properties at finite baryonic chemical potential.

  18. Molecular dynamics simulations of a chemical reaction; conditions for local equilibrium in a temperature gradient

    E-Print Network [OSTI]

    Kjelstrup, Signe

    Molecular dynamics simulations of a chemical reaction; conditions for local equilibrium have examined a simple chemical reaction in a temperature gradient; 2F $ F2. A mechanical model molecular dynamics simulations showed that the chemical reaction is in local thermodynamic as well

  19. Temperature-compensated chemical reactions Kanaka Rajan and L. F. Abbott

    E-Print Network [OSTI]

    Abbott, Laurence

    Temperature-compensated chemical reactions Kanaka Rajan and L. F. Abbott Center for Neurobiology oscillations in mRNA and protein levels, the question of how to construct a network of chemical reactions The rates of most chemical reactions are sensitive to tem- perature with, in simple cases, an exponential

  20. High temperature insulation for ceramic matrix composites

    DOE Patents [OSTI]

    Merrill, Gary B. (Monroeville, PA); Morrison, Jay Alan (Orlando, FL)

    2001-01-01

    A ceramic composition is provided to insulate ceramic matrix composites under high temperature, high heat flux environments. The composition comprises a plurality of hollow oxide-based spheres of various dimensions, a phosphate binder, and at least one oxide filler powder, whereby the phosphate binder partially fills gaps between the spheres and the filler powders. The spheres are situated in the phosphate binder and the filler powders such that each sphere is in contact with at least one other sphere. The spheres may be any combination of Mullite spheres, Alumina spheres, or stabilized Zirconia spheres. The filler powder may be any combination of Alumina, Mullite, Ceria, or Hafnia. Preferably, the phosphate binder is Aluminum Ortho-Phosphate. A method of manufacturing the ceramic insulating composition and its application to CMC substrates are also provided.

  1. High temperature insulation for ceramic matrix composites

    DOE Patents [OSTI]

    Merrill, Gary B.; Morrison, Jay Alan

    2004-01-13

    A ceramic composition is provided to insulate ceramic matrix composites under high temperature, high heat flux environments. The composition comprises a plurality of hollow oxide-based spheres of various dimensions, a phosphate binder, and at least one oxide filler powder, whereby the phosphate binder partially fills gaps between the spheres and the filler powders. The spheres are situated in the phosphate binder and the filler powders such that each sphere is in contact with at least one other sphere. The spheres may be any combination of Mullite spheres, Alumina spheres, or stabilized Zirconia spheres. The filler powder may be any combination of Alumina, Mullite, Ceria, or Hafnia. Preferably, the phosphate binder is Aluminum Ortho-Phosphate. A method of manufacturing the ceramic insulating composition and its application to CMC substrates are also provided.

  2. High temperature insulation for ceramic matrix composites

    DOE Patents [OSTI]

    Merrill, Gary B. (Monroeville, PA); Morrison, Jay Alan (Orlando, FL)

    2000-01-01

    A ceramic composition is provided to insulate ceramic matrix composites under high temperature, high heat flux environments. The composite comprises a plurality of hollow oxide-based spheres of varios dimentions, a phosphate binder, and at least one oxide filler powder, whereby the phosphate binder partially fills gaps between the spheres and the filler powders. The spheres are situated in the phosphate binder and the filler powders such that each sphere is in contact with at least one other sphere. The spheres may be any combination of Mullite spheres, Alumina spheres, or stabilized Zirconia spheres. The filler powder may be any combination of Alumina, Mullite, Ceria, or Hafnia. Preferably, the phosphate binder is Aluminum Ortho-Phosphate. A method of manufacturing the ceramic insulating composition and its application to CMC substates are also provided.

  3. Carbon Capture Turned Upside Down: High-Temperature Adsorption...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon Capture Turned Upside Down: High-Temperature Adsorption & Low-Temperature Desorption (HALD) Previous Next List Joos, Lennart; Lejaeghere, Kurt; Huck, Johanna M.; Van...

  4. A potential Rosetta Stone of high temperature superconductivity...

    Office of Science (SC) Website

    for the high temperature superconductivity. Summary Superconductivity enables the flow of electricity without any loss of energy, but this extremely-low temperature...

  5. High-Temperature, Air-Cooled Traction Drive Inverter Packaging...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Temperature, Air-Cooled Traction Drive Inverter Packaging High-Temperature, Air-Cooled Traction Drive Inverter Packaging 2010 DOE Vehicle Technologies and Hydrogen Programs Annual...

  6. Enhanced High and Low Temperature Performance of NOx Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Low Temperature Performance of NOx Reduction Materials Enhanced High and Low Temperature Performance of NOx Reduction Materials 2013 DOE Hydrogen and Fuel Cells Program and...

  7. High Temperature Thin Film Polymer Dielectric Based Capacitors...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Temperature Thin Film Polymer Dielectric Based Capacitors for HEV Power Electronic Systems High Temperature Thin Film Polymer Dielectric Based Capacitors for HEV Power Electronic...

  8. Enabling High Efficiency Low Temperature Combustion by Adaptive...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Temperature Combustion by Adaptive In-Situ Jet Cooling Enabling High Efficiency Low Temperature Combustion by Adaptive In-Situ Jet Cooling A new approach, called...

  9. High temperature lined conduits, elbows and tees

    DOE Patents [OSTI]

    De Feo, Angelo (Passaic, NJ); Drewniany, Edward (Bergen, NJ)

    1982-01-01

    A high temperature lined conduit comprising, a liner, a flexible insulating refractory blanket around and in contact with the liner, a pipe member around the blanket and spaced therefrom, and castable rigid refractory material between the pipe member and the blanket. Anchors are connected to the inside diameter of the pipe and extend into the castable material. The liner includes male and female slip joint ends for permitting thermal expansion of the liner with respect to the castable material and the pipe member. Elbows and tees of the lined conduit comprise an elbow liner wrapped with insulating refractory blanket material around which is disposed a spaced elbow pipe member with castable refractory material between the blanket material and the elbow pipe member. A reinforcing band is connected to the elbow liner at an intermediate location thereon from which extend a plurality of hollow tubes or pins which extend into the castable material to anchor the lined elbow and permit thermal expansion. A method of fabricating the high temperature lined conduit, elbows and tees is also disclosed which utilizes a polyethylene layer over the refractory blanket after it has been compressed to maintain the refractory blanket in a compressed condition until the castable material is in place. Hot gases are then directed through the interior of the liner for evaporating the polyethylene and setting the castable material which permits the compressed blanket to come into close contact with the castable material.

  10. Baseline Concept Description of a Small Modular High Temperature Reactor

    SciTech Connect (OSTI)

    Hans Gougar

    2014-05-01

    The objective of this report is to provide a description of generic small modular high temperature reactors (herein denoted as an smHTR), summarize their distinguishing attributes, and lay out the research and development (R&D) required for commercialization. The generic concepts rely heavily on the modular high temperature gas-cooled reactor designs developed in the 1980s which were never built but for which pre-licensing or certification activities were conducted. The concept matured more recently under the Next Generation Nuclear Plant (NGNP) project, specifically in the areas of fuel and material qualification, methods development, and licensing. As all vendor-specific designs proposed under NGNP were all both ‘small’ or medium-sized and ‘modular’ by International Atomic Energy Agency (IAEA) and Department of Energy (DOE) standards, the technical attributes, challenges, and R&D needs identified, addressed, and documented under NGNP are valid and appropriate in the context of Small Modular Reactor (SMR) applications. Although the term High Temperature Reactor (HTR) is commonly used to denote graphite-moderated, thermal spectrum reactors with coolant temperatures in excess of 650oC at the core outlet, in this report the historical term High Temperature Gas-Cooled Reactor (HTGR) will be used to distinguish the gas-cooled technology described herein from its liquid salt-cooled cousin. Moreover, in this report it is to be understood that the outlet temperature of the helium in an HTGR has an upper limit of 950 degrees C which corresponds to the temperature to which certain alloys are currently being qualified under DOE’s ARC program. Although similar to the HTGR in just about every respect, the Very High Temperature Reactor (VHTR) may have an outlet temperature in excess of 950 degrees C and is therefore farther from commercialization because of the challenges posed to materials exposed to these temperatures. The VHTR is the focus of R&D under the Generation IV program and its specific R&D needs will be included in this report when appropriate for comparison. The distinguishing features of the HTGR are the refractory (TRISO) coated particle fuel, the low-power density, graphite-moderated core, and the high outlet temperature of the inert helium coolant. The low power density and fuel form effectively eliminate the possibility of core melt, even upon a complete loss of coolant pressure and flow. The graphite, which constitutes the bulk of the core volume and mass, provides a large thermal buffer that absorbs fission heat such that thermal transients occur over a timespan of hours or even days. As chemically-inert helium is already a gas, there is no coolant temperature or void feedback on the neutronics and no phase change or corrosion product that could degrade heat transfer. Furthermore, the particle coatings and interstitial graphite retain fission products such that the source terms at the plant boundary remain well below actionable levels under all anticipated nominal and off-normal operating conditions. These attributes enable the reactor to supply process heat to a collocated industrial plant with negligible risk of contamination and minimal dynamic coupling of the facilities (Figure 1). The exceptional retentive properties of coated particle fuel in a graphite matrix were first demonstrated in the DRAGON reactor, a European research facility that began operation in 1964.

  11. Baseline Concept Description of a Small Modular High Temperature Reactor

    SciTech Connect (OSTI)

    Gougar, Hans D.

    2014-10-01

    The objective of this report is to provide a description of generic small modular high temperature reactors (herein denoted as an smHTR), summarize their distinguishing attributes, and lay out the research and development (R&D) required for commercialization. The generic concepts rely heavily on the modular high temperature gas-cooled reactor designs developed in the 1980s which were never built but for which pre-licensing or certification activities were conducted. The concept matured more recently under the Next Generation Nuclear Plant (NGNP) project, specifically in the areas of fuel and material qualification, methods development, and licensing. As all vendor-specific designs proposed under NGNP were all both ‘small’ or medium-sized and ‘modular’ by International Atomic Energy Agency (IAEA) and Department of Energy (DOE) standards, the technical attributes, challenges, and R&D needs identified, addressed, and documented under NGNP are valid and appropriate in the context of Small Modular Reactor (SMR) applications. Although the term High Temperature Reactor (HTR) is commonly used to denote graphite-moderated, thermal spectrum reactors with coolant temperatures in excess of 650oC at the core outlet, in this report the historical term High Temperature Gas-Cooled Reactor (HTGR) will be used to distinguish the gas-cooled technology described herein from its liquid salt-cooled cousin. Moreover, in this report it is to be understood that the outlet temperature of the helium in an HTGR has an upper limit of 950 degrees C which corresponds to the temperature to which certain alloys are currently being qualified under DOE’s ARC program. Although similar to the HTGR in just about every respect, the Very High Temperature Reactor (VHTR) may have an outlet temperature in excess of 950 degrees C and is therefore farther from commercialization because of the challenges posed to materials exposed to these temperatures. The VHTR is the focus of R&D under the Generation IV program and its specific R&D needs will be included in this report when appropriate for comparison. The distinguishing features of the HTGR are the refractory (TRISO) coated particle fuel, the low-power density, graphite-moderated core, and the high outlet temperature of the inert helium coolant. The low power density and fuel form effectively eliminate the possibility of core melt, even upon a complete loss of coolant pressure and flow. The graphite, which constitutes the bulk of the core volume and mass, provides a large thermal buffer that absorbs fission heat such that thermal transients occur over a timespan of hours or even days. As chemically-inert helium is already a gas, there is no coolant temperature or void feedback on the neutronics and no phase change or corrosion product that could degrade heat transfer. Furthermore, the particle coatings and interstitial graphite retain fission products such that the source terms at the plant boundary remain well below actionable levels under all anticipated nominal and off-normal operating conditions. These attributes enable the reactor to supply process heat to a collocated industrial plant with negligible risk of contamination and minimal dynamic coupling of the facilities (Figure 1). The exceptional retentive properties of coated particle fuel in a graphite matrix were first demonstrated in the DRAGON reactor, a European research facility that began operation in 1964.

  12. Non-graphite crucible for high temperature applications

    DOE Patents [OSTI]

    Holcombe, Cressie E. (Knoxville, TN); Pfeiler, William A. (Norris, TN)

    1994-01-01

    A multi-piece crucible for high temperature applications comprises a tubular side wall member having a lip on the inside surface and a bottom member or members forming a container for containing a melt of a material during a high temperature melt-casting operations. The multi-piece design prevents cracking of the crucible or leakage of the melt from the crucible during the melt-casting operation. The lip of the tubular member supports the bottom member. The contacting surfaces where the lip of the tubular side wall member contacts the bottom member of the multi-piece crucible contains a ceramic sealing material. The ceramic sealing material forms a seal sufficient to prevent the melt of the material from leaking out of the multi-piece crucible during the melt-casting process. The multi-piece crucible is made of a material which is chemically inert to the melt and has structural integrity at the melting point temperature of the melt, or of a material coated with such a material.

  13. Non-graphite crucible for high temperature applications

    DOE Patents [OSTI]

    Holcombe, C.E.; Pfeiler, W.A.

    1994-08-02

    A multi-piece crucible for high temperature applications comprises a tubular side wall member having a lip on the inside surface and a bottom member or members forming a container for containing a melt of a material during a high temperature melt-casting operations. The multi-piece design prevents cracking of the crucible or leakage of the melt from the crucible during the melt-casting operation. The lip of the tubular member supports the bottom member. The contacting surfaces where the lip of the tubular side wall member contacts the bottom member of the multi-piece crucible contains a ceramic sealing material. The ceramic sealing material forms a seal sufficient to prevent the melt of the material from leaking out of the multi-piece crucible during the melt-casting process. The multi-piece crucible is made of a material which is chemically inert to the melt and has structural integrity at the melting point temperature of the melt, or of a material coated with such a material. 6 figs.

  14. Multilayer ultra-high-temperature ceramic coatings

    DOE Patents [OSTI]

    Loehman, Ronald E. (Albuquerque, NM); Corral, Erica L. (Tucson, AZ)

    2012-03-20

    A coated carbon-carbon composite material with multiple ceramic layers to provide oxidation protection from ultra-high-temperatures, where if the carbon-carbon composite material is uninhibited with B.sub.4C particles, then the first layer on the composite material is selected from ZrB.sub.2 and HfB.sub.2, onto which is coated a layer of SiC coated and if the carbon-carbon composite material is inhibited with B.sub.4C particles, then protection can be achieved with a layer of SiC and a layer of either ZrB.sub.2 and HfB.sub.2 in any order.

  15. High temperature coatings for gas turbines

    DOE Patents [OSTI]

    Zheng, Xiaoci Maggie

    2003-10-21

    Coating for high temperature gas turbine components that include a MCrAlX phase, and an aluminum-rich phase, significantly increase oxidation and cracking resistance of the components, thereby increasing their useful life and reducing operating costs. The aluminum-rich phase includes aluminum at a higher concentration than aluminum concentration in the MCrAlX alloy, and an aluminum diffusion-retarding composition, which may include cobalt, nickel, yttrium, zirconium, niobium, molybdenum, rhodium, cadmium, indium, cerium, iron, chromium, tantalum, silicon, boron, carbon, titanium, tungsten, rhenium, platinum, and combinations thereof, and particularly nickel and/or rhenium. The aluminum-rich phase may be derived from a particulate aluminum composite that has a core comprising aluminum and a shell comprising the aluminum diffusion-retarding composition.

  16. Turbine vane with high temperature capable skins

    DOE Patents [OSTI]

    Morrison, Jay A. (Oviedo, FL)

    2012-07-10

    A turbine vane assembly includes an airfoil extending between an inner shroud and an outer shroud. The airfoil can include a substructure having an outer peripheral surface. At least a portion of the outer peripheral surface is covered by an external skin. The external skin can be made of a high temperature capable material, such as oxide dispersion strengthened alloys, intermetallic alloys, ceramic matrix composites or refractory alloys. The external skin can be formed, and the airfoil can be subsequently bi-cast around or onto the skin. The skin and the substructure can be attached by a plurality of attachment members extending between the skin and the substructure. The skin can be spaced from the outer peripheral surface of the substructure such that a cavity is formed therebetween. Coolant can be supplied to the cavity. Skins can also be applied to the gas path faces of the inner and outer shrouds.

  17. Refractory thermowell for continuous high temperature measurement of molten metal

    DOE Patents [OSTI]

    Thiesen, Todd J. (Idaho Falls, ID)

    1992-01-01

    An apparatus for the continuous high temperature measurement of materials in vessels lined with rammed or cast refractory materials. A refractory housing member is integral with the refractory lining of the vessel and contains a plurality of high temperature sensing means, such as thermocouples. A face of the housing is flush with the refractory lining and contacts the high temperature material contained in the vessel. Continuous temperature measurement is achieved by a means which is coupled to the thermocouples for indicating the temperature.

  18. High-Temperature High-Efficiency Solar Thermoelectric Generators

    SciTech Connect (OSTI)

    Baranowski, LL; Warren, EL; Toberer, ES

    2014-03-01

    Inspired by recent high-efficiency thermoelectric modules, we consider thermoelectrics for terrestrial applications in concentrated solar thermoelectric generators (STEGs). The STEG is modeled as two subsystems: a TEG, and a solar absorber that efficiently captures the concentrated sunlight and limits radiative losses from the system. The TEG subsystem is modeled using thermoelectric compatibility theory; this model does not constrain the material properties to be constant with temperature. Considering a three-stage TEG based on current record modules, this model suggests that 18% efficiency could be experimentally expected with a temperature gradient of 1000A degrees C to 100A degrees C. Achieving 15% overall STEG efficiency thus requires an absorber efficiency above 85%, and we consider two methods to achieve this: solar-selective absorbers and thermally insulating cavities. When the TEG and absorber subsystem models are combined, we expect that the STEG modeled here could achieve 15% efficiency with optical concentration between 250 and 300 suns.

  19. High Temperature Integrated Thermoelectric Ststem and Materials

    SciTech Connect (OSTI)

    Mike S. H. Chu

    2011-06-06

    The final goal of this project is to produce, by the end of Phase II, an all ceramic high temperature thermoelectric module. Such a module design integrates oxide ceramic n-type, oxide ceramic p-type materials as thermoelectric legs and oxide ceramic conductive material as metalizing connection between n-type and p-type legs. The benefits of this all ceramic module are that it can function at higher temperatures (> 700 C), it is mechanically and functionally more reliable and it can be scaled up to production at lower cost. With this all ceramic module, millions of dollars in savings or in new opportunities recovering waste heat from high temperature processes could be made available. A very attractive application will be to convert exhaust heat from a vehicle to reusable electric energy by a thermoelectric generator (TEG). Phase I activities were focused on evaluating potential n-type and p-type oxide compositions as the thermoelectric legs. More than 40 oxide ceramic powder compositions were made and studied in the laboratory. The compositions were divided into 6 groups representing different material systems. Basic ceramic properties and thermoelectric properties of discs sintered from these powders were measured. Powders with different particles sizes were made to evaluate the effects of particle size reduction on thermoelectric properties. Several powders were submitted to a leading thermoelectric company for complete thermoelectric evaluation. Initial evaluation showed that when samples were sintered by conventional method, they had reasonable values of Seebeck coefficient but very low values of electrical conductivity. Therefore, their power factors (PF) and figure of merits (ZT) were too low to be useful for high temperature thermoelectric applications. An unconventional sintering method, Spark Plasma Sintering (SPS) was determined to produce better thermoelectric properties. Particle size reduction of powders also was found to have some positive benefits. Two composition systems, specifically 1.0 SrO - 0.8 x 1.03 TiO2 - 0.2 x 1.03 NbO2.5 and 0.97 TiO2 - 0.03 NbO2.5, have been identified as good base line compositions for n-type thermoelectric compositions in future module design. Tests of these materials at an outside company were promising using that company's processing and material expertise. There was no unique p-type thermoelectric compositions identified in phase I work other than several current cobaltite materials. Ca3Co4O9 will be the primary p-type material for the future module design until alternative materials are developed. BaTiO3 and rare earth titanate based dielectric compositions show both p-type and n-type behavior even though their electrical conductivities were very low. Further research and development of these materials for thermoelectric applications is planned in the future. A preliminary modeling and optimization of a thermoelectric generator (TEG) that uses the n-type 1.0 SrO - 1.03 x 0.8 TiO2 - 1.03 x 0.2 NbO2.5 was performed. Future work will combine development of ceramic powders and manufacturing expertise at TAM, development of SPS at TAM or a partner organization, and thermoelectric material/module testing, modeling, optimization, production at several partner organizations.

  20. Mold, flow, and economic considerations in high temperature precision casting

    E-Print Network [OSTI]

    Humbert, Matthew S

    2013-01-01

    Casting high temperature alloys that solidify through a noticeable two phase region, specifically platinum-ruthenium alloys, is a particularly challenging task due to their high melting temperature and this necessitates ...

  1. Development of a 100-Watt High Temperature Thermoelectric Generator

    Broader source: Energy.gov [DOE]

    Test results for low and high temperature thermoelectric generators (TEG) those for a 530-watt BiTe TEG; design and construction of a 100-watt high temperature TEG currently in fabrication.

  2. Development of a High-Temperature Diagnostics-While-Drilling...

    Office of Environmental Management (EM)

    Development of a High-Temperature Diagnostics-While-Drilling Tool Development of a High-Temperature Diagnostics-While-Drilling Tool This report documents work performed in the...

  3. Project Profile: High-Temperature Thermochemical Storage with...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    fluidized bed to provide high-temperature heat exchange above the storage temperature to drive high-efficiency power cycles, such as super-critical CO2. Approach The research...

  4. Agenda for the High Temperature Membrane Working Group Meeting

    Broader source: Energy.gov [DOE]

    This agenda provides information about the Agenda for the High Temperature Membrane Working Group Meeting on September 14, 2006.

  5. High Temperature Membrane Working Group Meeting, May 14, 2007

    Broader source: Energy.gov [DOE]

    This agenda provides information about the High Temperature Membrane Working Group Meeting on May 14, 2007 in Arlington, Va.

  6. High-Temperature-High-Volume Lifting For Enhanced Geothermal Systems

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas: Energy Resources Jump to:Hershey,High-Temperature Downhole Tools Jump to:Geothermal

  7. Cedarville Elementary & High School Space Heating Low Temperature...

    Open Energy Info (EERE)

    Cedarville Elementary & High School Space Heating Low Temperature Geothermal Facility Jump to: navigation, search Name Cedarville Elementary & High School Space Heating Low...

  8. Deposition of silicon carbide films using a high vacuum metalorganic chemical vapor deposition method with a single source precursor

    E-Print Network [OSTI]

    Boo, Jin-Hyo

    , high temperature, and high radiation environments. Conventional silicon carbide chemical vapor deposition CVD processes generally utilized multiple precursors such as silane and hydrocarbons, and required temperature alternatives to the conventional SiC CVD methods must be considered. To do this, a relatively

  9. High performance internal reforming unit for high temperature fuel cells

    DOE Patents [OSTI]

    Ma, Zhiwen (Sandy Hook, CT); Venkataraman, Ramakrishnan (New Milford, CT); Novacco, Lawrence J. (Brookfield, CT)

    2008-10-07

    A fuel reformer having an enclosure with first and second opposing surfaces, a sidewall connecting the first and second opposing surfaces and an inlet port and an outlet port in the sidewall. A plate assembly supporting a catalyst and baffles are also disposed in the enclosure. A main baffle extends into the enclosure from a point of the sidewall between the inlet and outlet ports. The main baffle cooperates with the enclosure and the plate assembly to establish a path for the flow of fuel gas through the reformer from the inlet port to the outlet port. At least a first directing baffle extends in the enclosure from one of the sidewall and the main baffle and cooperates with the plate assembly and the enclosure to alter the gas flow path. Desired graded catalyst loading pattern has been defined for optimized thermal management for the internal reforming high temperature fuel cells so as to achieve high cell performance.

  10. SHEAR LOCALIZATION AND CHEMICAL REACTION IN HIGH-STRAIN, HIGH-STRAIN-RATE DEFORMATION OF

    E-Print Network [OSTI]

    Meyers, Marc A.

    SHEAR LOCALIZATION AND CHEMICAL REACTION IN HIGH-STRAIN, HIGH-STRAIN-RATE DEFORMATION OF Ti regions can initiate chemical reaction inside a reac- tive powder mixture. The shear band spacing was H0-induced chemical reactions in silicide systems have been investigated in recent years. Vreeland and coworkers [7

  11. Secondary calcium solid electrolyte high temperature battery

    SciTech Connect (OSTI)

    Sammells, A.F.; Schumacher, B.

    1986-01-01

    The authors report on recent work directed towards determining the viability of polycrystalline Ca/sup 2 +/ conducting ..beta..''-alumina solid electrolytes as the basis for a new type of high temperature battery. In this battery system the negative electrode consisted of a calcium-silicon alloy whose redox electro-chemistry was mediated to the calcium conducting solid electrolyte via the use of the molten salt eutectic CaCl/sub 2/ (51.4/sup M//0), CaI/sub 2/ (mp 550/sup 0/C). Both the molten salt and the calcium-alloy negative active material were separated from the positive active material via the Ca/sup 2 +/ conducting polycrystalline solid electrolyte. The positive electrode consisted of a solid-state matrix having a somewhat related crystallographic structure to Ca/sup 2 +/ ..beta..''-alumina, but where a significant fraction of the A1/sup 3 +/ sites located within this solid electrolyte's spinel block were replaced by immobile transition metal species. These species were available for participating in solid-state redox electrochemistry upon electrochemical cell cycling.

  12. Austenitic stainless steel for high temperature applications

    DOE Patents [OSTI]

    Johnson, Gerald D. (Kennewick, WA); Powell, Roger W. (Pasco, WA)

    1985-01-01

    This invention describes a composition for an austenitic stainless steel which has been found to exhibit improved high temperature stress rupture properties. The composition of this alloy is about (in wt. %): 12.5 to 14.5 Cr; 14.5 to 16.5 Ni; 1.5 to 2.5 Mo; 1.5 to 2.5 Mn; 0.1 to 0.4 Ti; 0.02 to 0.08 C; 0.5 to 1.0 Si; 0.01 maximum, N; 0.02 to 0.08 P; 0.002 to 0.008 B; 0.004-0.010 S; 0.02-0.05 Nb; 0.01-0.05 V; 0.005-0.02 Ta; 0.02-0.05 Al; 0.01-0.04 Cu; 0.02-0.05 Co; 0.03 maximum, As; 0.01 maximum, O; 0.01 maximum, Zr; and with the balance of the alloy being essentially iron. The carbon content of the alloy is adjusted such that wt. % Ti/(wt. % C+wt. % N) is between 4 and 6, and most preferably about 5. In addition the sum of the wt. % P+wt. % B+wt. % S is at least 0.03 wt. %. This alloy is believed to be particularly well suited for use as fast breeder reactor fuel element cladding.

  13. High Temperature Gas-cooled Reactor Projected Markets and Scoping Economics

    SciTech Connect (OSTI)

    Larry Demick

    2010-08-01

    The NGNP Project has the objective of developing the high temperature gas-cooled reactor (HTGR) technology to supply high temperature process heat to industrial processes as a substitute for burning of fossil fuels, such as natural gas. Applications of the HTGR technology that have been evaluated by the NGNP Project for supply of process heat include supply of electricity, steam and high-temperature gas to a wide range of industrial processes, and production of hydrogen and oxygen for use in petrochemical, refining, coal to liquid fuels, chemical, and fertilizer plants.

  14. Low temperature chemical vapor deposition of Co thin films from Co2(CO)8

    E-Print Network [OSTI]

    Wang, Gwo-Ching

    Low temperature chemical vapor deposition of Co thin films from Co2(CO)8 D.-X. Yea,*, S. Pimanpanga chemical vapor deposition with a metallorganic Co2(CO)8 precursor. After Ar sputtering of the surface, Co2(CO)8, has been extensively used in cobalt CVD and is attractive, since Co is in its elemental

  15. High-flux magnetorheology at elevated temperatures

    E-Print Network [OSTI]

    Ocalan, Murat

    Commercial applications of magnetorheological (MR) fluids often require operation at elevated temperatures as a result of surrounding environmental conditions or intense localized viscous heating. Previous experimental ...

  16. Thermochemical Recuperation for High Temperature Furnaces

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    methods, in preheat combus- tion air temperatures. Applications in Our Nation's Industry Because both steam and CO 2 can be utilized in the TCR process, it is advantageous...

  17. High Temperature 300°C Directional Drilling System

    Broader source: Energy.gov [DOE]

    Project objective: provide a directional drilling system that can be used at environmental temperatures of up to 300°C; and at depths of 10; 000 meters.

  18. High temperature pressurized high frequency testing rig and test method

    DOE Patents [OSTI]

    De La Cruz, Jose; Lacey, Paul

    2003-04-15

    An apparatus is described which permits the lubricity of fuel compositions at or near temperatures and pressures experienced by compression ignition fuel injector components during operation in a running engine. The apparatus consists of means to apply a measured force between two surfaces and oscillate them at high frequency while wetted with a sample of the fuel composition heated to an operator selected temperature. Provision is made to permit operation at or near the flash point of the fuel compositions. Additionally a method of using the subject apparatus to simulate ASTM Testing Method D6079 is disclosed, said method involving using the disclosed apparatus to contact the faces of prepared workpieces under a measured load, sealing the workface contact point into the disclosed apparatus while immersing said contact point between said workfaces in a lubricating media to be tested, pressurizing and heating the chamber and thereby the fluid and workfaces therewithin, using the disclosed apparatus to impart a differential linear motion between the workpieces at their contact point until a measurable scar is imparted to at least one workpiece workface, and then evaluating the workface scar.

  19. Calcite Mineral Scaling Potentials of High-Temperature Geothermal Wells

    E-Print Network [OSTI]

    Karlsson, Brynjar

    #12;i Calcite Mineral Scaling Potentials of High-Temperature Geothermal Wells Alvin I. Remoroza-Temperature Geothermal Wells Alvin I. Remoroza 60 ECTS thesis submitted in partial fulfillment of a Magister Scientiarum #12;iv Calcite Mineral Scaling Potentials of High-Temperature Geothermal Wells 60 ECTS thesis

  20. Design of High Field Solenoids made of High Temperature Superconductors

    SciTech Connect (OSTI)

    Bartalesi, Antonio; /Pisa U.

    2010-12-01

    This thesis starts from the analytical mechanical analysis of a superconducting solenoid, loaded by self generated Lorentz forces. Also, a finite element model is proposed and verified with the analytical results. To study the anisotropic behavior of a coil made by layers of superconductor and insulation, a finite element meso-mechanic model is proposed and designed. The resulting material properties are then used in the main solenoid analysis. In parallel, design work is performed as well: an existing Insert Test Facility (ITF) is adapted and structurally verified to support a coil made of YBa{sub 2}Cu{sub 3}O{sub 7}, a High Temperature Superconductor (HTS). Finally, a technological winding process was proposed and the required tooling is designed.

  1. Ultra-High Temperature Distributed Wireless Sensors

    SciTech Connect (OSTI)

    May, Russell; Rumpf, Raymond; Coggin, John; Davis, Williams; Yang, Taeyoung; O'Donnell, Alan; Bresnahan, Peter

    2013-03-31

    Research was conducted towards the development of a passive wireless sensor for measurement of temperature in coal gasifiers and coal-fired boiler plants. Approaches investigated included metamaterial sensors based on guided mode resonance filters, and temperature-sensitive antennas that modulate the frequency of incident radio waves as they are re-radiated by the antenna. In the guided mode resonant filter metamaterial approach, temperature is encoded as changes in the sharpness of the filter response, which changes with temperature because the dielectric loss of the guided mode resonance filter is temperature-dependent. In the mechanically modulated antenna approach, the resonant frequency of a vibrating cantilever beam attached to the antenna changes with temperature. The vibration of the beam perturbs the electrical impedance of the antenna, so that incident radio waves are phase modulated at a frequency equal to the resonant frequency of the vibrating beam. Since the beam resonant frequency depends on temperature, a Doppler radar can be used to remotely measure the temperature of the antenna. Laboratory testing of the guided mode resonance filter failed to produce the spectral response predicted by simulations. It was concluded that the spectral response was dominated by spectral reflections of radio waves incident on the filter. Laboratory testing of the mechanically modulated antenna demonstrated that the device frequency shifted incident radio waves, and that the frequency of the re-radiated waves varied linearly with temperature. Radio wave propagation tests in the convection pass of a small research boiler plant identified a spectral window between 10 and 13 GHz for low loss propagation of radio waves in the interior of the boiler.

  2. High temperature, minimally invasive optical sensing modules

    DOE Patents [OSTI]

    Riza, Nabeel Agha (Oviedo, FL); Perez, Frank (Tujunga, CA)

    2008-02-05

    A remote temperature sensing system includes a light source selectively producing light at two different wavelengths and a sensor device having an optical path length that varies as a function of temperature. The sensor receives light emitted by the light source and redirects the light along the optical path length. The system also includes a detector receiving redirected light from the sensor device and generating respective signals indicative of respective intensities of received redirected light corresponding to respective wavelengths of light emitted by the light source. The system also includes a processor processing the signals generated by the detector to calculate a temperature of the device.

  3. High-temperature fiber optic cubic-zirconia pressure sensor - article no. 124402

    SciTech Connect (OSTI)

    Peng, W.; Pickrell, G.R.; Wang, A.B.

    2005-12-15

    There is a critical need for pressure sensors that can operate reliably at high temperatures in many industrial segments such as in the combustion section of gas turbine engines for both transportation and power generation, coal gasifiers, coal fired boilers, etc. Optical-based sensors are particularly attractive for the measurement of a wide variety of physical and chemical parameters in high-temperature and high-pressure industrial environments due to their small size and immunity to electromagnetic interference. A fiber optic pressure sensor utilizing single-crystal cubic zirconia as the sensing element is reported. The pressure response of this sensor has been measured at temperatures up to 1000{sup o}C. Additional experimental results show that cubic zirconia could be used for pressure sensing at temperatures over 1000{sup o}C. This study demonstrates the feasibility of using a novel cubic-zirconia sensor for pressure measurement at high temperatures.

  4. High throughput chemical munitions treatment system

    DOE Patents [OSTI]

    Haroldsen, Brent L. (Manteca, CA); Stofleth, Jerome H. (Albuquerque, NM); Didlake, Jr., John E. (Livermore, CA); Wu, Benjamin C-P (San Ramon, CA)

    2011-11-01

    A new High-Throughput Explosive Destruction System is disclosed. The new system is comprised of two side-by-side detonation containment vessels each comprising first and second halves that feed into a single agent treatment vessel. Both detonation containment vessels further comprise a surrounding ventilation facility. Moreover, the detonation containment vessels are designed to separate into two half-shells, wherein one shell can be moved axially away from the fixed, second half for ease of access and loading. The vessels are closed by means of a surrounding, clam-shell type locking seal mechanisms.

  5. SU(2) Lattice Gauge Theory at Nonzero Chemical Potential and Temperature

    E-Print Network [OSTI]

    John B. Kogut

    2002-08-30

    SU(2) lattice gauge theory with four flavors of quarks is simulated at nonzero chemical potential mu and temperature T and the results are compared to the predictions of Effective Lagrangians. Simulations on 16^4 lattices indicate that at zero T the theory experiences a second order phase transition to a diquark condensate state which is well described by mean field theory. Nonzero T and mu are studied on 12^3 times 6 lattices. For low T, increasing mu takes the system through a line of second order phase transitions to a diquark condensed phase. Increasing T at high mu, the system passes through a line of first order transitions from the diquark phase to the quark-gluon plasma phase.

  6. Expansion Joint Concepts for High Temperature Insulation Systems 

    E-Print Network [OSTI]

    Harrison, M. R.

    1980-01-01

    As high temperature steam and process piping expands with heat, joints begin to open between the insulation sections, resulting in increased energy loss and possible unsafe surface temperatures. Many different expansion joint designs are presently...

  7. The equation of state at high temperatures from lattice QCD

    E-Print Network [OSTI]

    G. Endrodi; Z. Fodor; S. D. Katz; K. K. Szabo

    2007-10-23

    We present results for the equation of state upto previously unreachable, high temperatures. Since the temperature range is quite large, a comparison with perturbation theory can be done directly.

  8. Study of Catcher Bearings for High Temperature Magnetic Bearing Application 

    E-Print Network [OSTI]

    Narayanaswamy, Ashwanth

    2011-08-08

    temperature permanent magnet based magnetic bearings. The magnetic bearings are made of high temperature resistant permanent magnets (up to 1000 degrees F). A test rig has been developed to test these magnetic bearings. The test rig mainly consists of two...

  9. High Temperature Tolerant Ceramic Composites Having Porous Interphases

    DOE Patents [OSTI]

    Kriven, Waltraud M. (Champaign, IL); Lee, Sang-Jin (Chonnam, KR)

    2005-05-03

    In general, this invention relates to a ceramic composite exhibiting enhanced toughness and decreased brittleness, and to a process of preparing the ceramic composite. The ceramic composite comprises a first matrix that includes a first ceramic material, preferably selected from the group including alumina (Al2O3), mullite (3Al2O3.2SiO2), yttrium aluminate garnet (YAG), yttria stabilized zirconia (YSZ), celsian (BaAl2Si2O8) and nickel aluminate (NiAl2O4). The ceramic composite also includes a porous interphase region that includes a substantially non-sinterable material. The non-sinterable material can be selected to include, for example, alumina platelets. The platelets lie in random 3-D orientation and provide a debonding mechanism, which is independent of temperature in chemically compatible matrices. The non-sinterable material induces constrained sintering of a ceramic powder resulting in permanent porosity in the interphase region. For high temperature properties, addition of a sinterable ceramic powder to the non-sinterable material provides sufficiently weak debonding interphases. The ceramic composite can be provided in a variety of forms including a laminate, a fibrous monolith, and a fiber-reinforced ceramic matrix. In the laminated systems, intimate mixing of strong versus tough microstructures were tailored by alternating various matrix-to-interphase thickness ratios to provide the bimodal laminate.

  10. High temperature cooling system and method

    DOE Patents [OSTI]

    Loewen, Eric P.

    2006-12-12

    A method for cooling a heat source, a method for preventing chemical interaction between a vessel and a cooling composition therein, and a cooling system. The method for cooling employs a containment vessel with an oxidizable interior wall. The interior wall is oxidized to form an oxide barrier layer thereon, the cooling composition is monitored for excess oxidizing agent, and a reducing agent is provided to eliminate excess oxidation. The method for preventing chemical interaction between a vessel and a cooling composition involves introducing a sufficient quantity of a reactant which is reactive with the vessel in order to produce a barrier layer therein that is non-reactive with the cooling composition. The cooling system includes a containment vessel with oxidizing agent and reducing agent delivery conveyances and a monitor of oxidation and reduction states so that proper maintenance of a vessel wall oxidation layer occurs.

  11. High Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells

    Broader source: Energy.gov [DOE]

    DOE Geothermal Peer Review 2010 - Presentation. Project objectives: Design, demonstrate, and qualify high-temperature high pressure zonal isolation devices compatible with the high temperature downhole Enhanced Geothermal Systems (EGS) environment.

  12. Metallic substrates for high temperature superconductors

    DOE Patents [OSTI]

    Truchan, Thomas G. (Chicago, IL); Miller, Dean J. (Darien, IL); Goretta, Kenneth C. (Downers Grove, IL); Balachandran, Uthamalingam (Hinsdale, IL); Foley, Robert (Chicago, IL)

    2002-01-01

    A biaxially textured face-centered cubic metal article having grain boundaries with misorientation angles greater than about 8.degree. limited to less than about 1%. A laminate article is also disclosed having a metal substrate first rolled to at least about 95% thickness reduction followed by a first annealing at a temperature less than about 375.degree. C. Then a second rolling operation of not greater than about 6% thickness reduction is provided, followed by a second annealing at a temperature greater than about 400.degree. C. A method of forming the metal and laminate articles is also disclosed.

  13. DEGRADATION ISSUES IN SOLID OXIDE CELLS DURING HIGH TEMPERATURE ELECTROLYSIS

    SciTech Connect (OSTI)

    M. S. Sohal; J. E. O'Brien; C. M. Stoots; V. I. Sharma; B. Yildiz; A. Virkar

    2012-02-01

    Idaho National Laboratory (INL) is performing high-temperature electrolysis research to generate hydrogen using solid oxide electrolysis cells (SOECs). The project goals are to address the technical and degradation issues associated with the SOECs. This paper provides a summary of various ongoing INL and INL sponsored activities aimed at addressing SOEC degradation. These activities include stack testing, post-test examination, degradation modeling, and a list of issues that need to be addressed in future. Major degradation issues relating to solid oxide fuel cells (SOFC) are relatively better understood than those for SOECs. Some of the degradation mechanisms in SOFCs include contact problems between adjacent cell components, microstructural deterioration (coarsening) of the porous electrodes, and blocking of the reaction sites within the electrodes. Contact problems include delamination of an electrode from the electrolyte, growth of a poorly (electronically) conducting oxide layer between the metallic interconnect plates and the electrodes, and lack of contact between the interconnect and the electrode. INL's test results on high temperature electrolysis (HTE) using solid oxide cells do not provide a clear evidence whether different events lead to similar or drastically different electrochemical degradation mechanisms. Post-test examination of the solid oxide electrolysis cells showed that the hydrogen electrode and interconnect get partially oxidized and become non-conductive. This is most likely caused by the hydrogen stream composition and flow rate during cool down. The oxygen electrode side of the stacks seemed to be responsible for the observed degradation due to large areas of electrode delamination. Based on the oxygen electrode appearance, the degradation of these stacks was largely controlled by the oxygen electrode delamination rate. University of Utah (Virkar) has developed a SOEC model based on concepts in local thermodynamic equilibrium in systems otherwise in global thermodynamic non-equilibrium. This model is under continued development. It shows that electronic conduction through the electrolyte, however small, must be taken into account for determining local oxygen chemical potential, within the electrolyte. The chemical potential within the electrolyte may lie out of bounds in relation to values at the electrodes in the electrolyzer mode. Under certain conditions, high pressures can develop in the electrolyte just under the oxygen electrode (anode)/electrolyte interface, leading to electrode delamination. This theory is being further refined and tested by introducing some electronic conduction in the electrolyte.

  14. Detecting Fractures Using Technology at High Temperatures and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Detecting Fractures Using Technology at High Temperatures and Depths - Geothermal Ultrasonic Fracture Imager (GUFI); 2010 Geothermal Technology Program Peer Review Report Detecting...

  15. Enhanced High Temperature Performance of NOx Storage/Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Program Annual Merit Review and Peer Evaluation ace026peden2011o.pdf More Documents & Publications Enhanced High Temperature Performance of NOx StorageReduction (NSR) Materials...

  16. High-Speed, Temperature Programmable Gas Chromatography Utilizing...

    Office of Scientific and Technical Information (OSTI)

    High-Speed, Temperature Programmable Gas Chromatography Utilizing a Microfabricated Chip with an Improved Carbon Nanotube Stationary Phase Citation Details In-Document Search...

  17. Microchannel High-Temperature Recuperator for Fuel Cell Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    heat recuperator for a high-temperature fuel cell system. This technology increases the efficiency of fuel cells and improves their performance in distributed energy...

  18. Aerogel-Based Insulation for High-Temperature Industrial Processes...

    Office of Scientific and Technical Information (OSTI)

    Aerogel-Based Insulation for High-Temperature Industrial Processes Dr. Owen Evans 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; COMPETITION; ENERGY CONSUMPTION; MARKET;...

  19. Microchannel High-Temperature Recuperator for Fuel Cell Systems

    SciTech Connect (OSTI)

    2010-02-01

    This factsheet describes a research project whose goal is to build an efficient, microchannel-based waste heat recuperator for a high-temperature fuel cell system.

  20. Microchannel High-Temperature Recuperator for Fuel Cell Systems...

    Broader source: Energy.gov (indexed) [DOE]

    developed an efficient, microchannel-based waste heat recuperator for a high-temperature fuel cell system. This technology increases the efficiency of fuel cells and improves...

  1. Feasibility and Design Studies for a High Temperature Downhole Tool

    Office of Energy Efficiency and Renewable Energy (EERE)

    Project objective: Perform feasibility and design studies for a high temperature downhole tool; which uses nuclear techniques for characterization purposes; using measurements and modeling/simulation.

  2. Alternative Refrigerant Evaluation for High-Ambient-Temperature...

    Office of Environmental Management (EM)

    Alternative Refrigerant Evaluation for High-Ambient-Temperature Environments: R-22 and R-410A Alternatives for Mini-Split Air Conditioners Alternative Refrigerant Evaluation for...

  3. High Temperature BOP and Fuel Processing | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    11-12, 2011. High Temperature BOP and Fuel Processing More Documents & Publications Biogas Impurities and Cleanup for Fuel Cells Fuel Quality Issues in Stationary Fuel Cell...

  4. Project Profile: High-Temperature Solar Selective Coating Development...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solar Selective Coating Development for Power Tower Receivers Project Profile: High-Temperature Solar Selective Coating Development for Power Tower Receivers Sandia National...

  5. Exploration Guides For Active High-Temperature Geothermal Systems...

    Open Energy Info (EERE)

    V. Bouchot,A. Genter. 2009. Exploration Guides For Active High-Temperature Geothermal Systems As Modern Analogs For Epithermal Paleosystems. In: () ; () ; () . () : GRC; p....

  6. High Temperature Materials Overview Richard Wright Idaho National...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    final action Fossil Energy Ultra- supercritical Materials research in US and Europe Partners in Generation IV International Forum ASME High Temperature Materials Code...

  7. FISSION REACTORS KEYWORDS: high-temperature

    E-Print Network [OSTI]

    Yildiz, Bilge

    REACTORS WITH SUPERCRITICAL CO2 CYCLES BILGE YILDIZ,* KATHERINE J. HOHNHOLT, and MUJID S. KAZIMI-temperature steam electrolysis (HTSE) supported by a supercritical CO2 (SCO2) recompression Brayton cycle by a supercritical CO2 ~SCO2! power conversion system that is directly coupled to an advanced gas-cooled reactor

  8. Scaling Studies for High Temperature Test Facility and Modular High Temperature Gas-Cooled Reactor

    SciTech Connect (OSTI)

    Richard R. Schult; Paul D. Bayless; Richard W. Johnson; James R. Wolf; Brian Woods

    2012-02-01

    The Oregon State University (OSU) High Temperature Test Facility (HTTF) is an integral experimental facility that will be constructed on the OSU campus in Corvallis, Oregon. The HTTF project was initiated, by the U.S. Nuclear Regulatory Commission (NRC), on September 5, 2008 as Task 4 of the 5-year High Temperature Gas Reactor Cooperative Agreement via NRC Contract 04-08-138. Until August, 2010, when a DOE contract was initiated to fund additional capabilities for the HTTF project, all of the funding support for the HTTF was provided by the NRC via their cooperative agreement. The U.S. Department of Energy (DOE) began their involvement with the HTTF project in late 2009 via the Next Generation Nuclear Plant (NGNP) project. Because the NRC's interests in HTTF experiments were only centered on the depressurized conduction cooldown (DCC) scenario, NGNP involvement focused on expanding the experimental envelope of the HTTF to include steady-state operations and also the pressurized conduction cooldown (PCC).

  9. High-Temperature-High-Volume Lifting for Enhanced Geothermal Systems

    Broader source: Energy.gov [DOE]

    Project objective: Advance the technology for well fluids lifting systems to meet the foreseeable pressure; temperature; and longevity needs of the Enhanced Geothermal Systems (EGS) industry.

  10. High temperature expanding cement composition and use

    DOE Patents [OSTI]

    Nelson, Erik B. (Tulsa County, OK); Eilers, Louis H. (Rogers County, OK)

    1982-01-01

    A hydratable cement composition useful for preparing a pectolite-containing expanding cement at temperatures above about 150.degree. C. comprising a water soluble sodium salt of a weak acid, a 0.1 molar aqueous solution of which salt has a pH of between about 7.5 and about 11.5, a calcium source, and a silicon source, where the atomic ratio of sodium to calcium to silicon ranges from about 0.3:0.6:1 to about 0.03:1:1; aqueous slurries prepared therefrom and the use of such slurries for plugging subterranean cavities at a temperature of at least about 150.degree. C. The invention composition is useful for preparing a pectolite-containing expansive cement having about 0.2 to about 2 percent expansion, by volume, when cured at at least 150.degree. C.

  11. High-Temperature Viscosity Of Commercial Glasses

    SciTech Connect (OSTI)

    Hrma, Pavel R.; See, Clem A.; Lam, Oanh P.; Minister, Kevin B.

    2005-01-01

    Viscosity was measured for six types of commercial glasses: low-expansion-borosilicate glasses, E glasses, fiberglass wool glasses, TV panel glasses, container glasses, and float glasses. Viscosity data were obtained with rotating spindle viscometers within the temperature range between 900°C and 1550°C; the viscosity varied from 1 Pa?s to 750 Pa?s. Arrhenius coefficients were calculated for individual glasses and linear models were applied to relate them to the mass fractions of 11 major components (SiO2, CaO, Na2O, Al2O3, B2O3, BaO, SrO, K2O, MgO, PbO, and ZrO2) and 12 minor components (Fe2O3, ZnO, Li2O, TiO2, CeO2, F, Sb2O3, Cr2O3, As2O3, MnO2, SO3, and Co3O4). The models are recommended for glasses containing 42 to 84 mass% SiO2 to estimate viscosities or temperatures at a constant viscosity for melts within both the temperature range from 1100°C to 1550°C and viscosity range from 10 to 400 Pa?s.

  12. Three-loop HTLpt thermodynamics at finite temperature and isospin chemical potential

    E-Print Network [OSTI]

    Andersen, Jens O; Mustafa, Munshi G; Strickland, Michael

    2015-01-01

    In a previous paper (JHEP {\\bf 05} (2014) 27), we calculated the three-loop thermodynamic potential of QCD at finite temperature $T$ and quark chemical potentials $\\mu_q$ using the hard-thermal-loop perturbation theory (HTLpt) reorganization of finite temperature and density QCD. The result allows us to study the thermodynamics of QCD at finite temperature and isospin chemical potential $\\mu_I$. We calculate the pressure, energy density, and entropy density, the trace anomaly, and the speed of sound at zero and nonzero $\\mu_I$. The second, fourth, and sixth-order isospin susceptibilities are calculated at zero $\\mu_I$. Our results can be directly compared to lattice QCD without Taylor expansions around $\\mu_q=0$ since QCD has no sign problem at finite isospin chemical potential.

  13. Enabling high-temperature nanophotonics for energy applications

    E-Print Network [OSTI]

    suppressed by 50% at 75° compared to nor- mal incidence. Finally, a precise high-temperature measurement applications, especially high-efficiency energy conversion systems encompassing hydrocarbon and radio- isotope

  14. Advancing the technology base for high-temperature membranes

    SciTech Connect (OSTI)

    Dye, R.C.; Birdsell, S.A.; Snow, R.C. [and others

    1997-10-01

    This is the final report of a two-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). This project addresses the major issues confronting the implementation of high-temperature membranes for separations and catalysis. We are pursuing high-temperature membrane systems that can have a large impact for DOE and be industrially relevant. A major obstacle for increased use of membranes is that most applications require the membrane material to withstand temperatures above those acceptable for polymer-based systems. Advances made by this project have helped industry and DOE move toward high-temperature membrane applications to improve overall energy efficiency.

  15. Apparatus for monitoring high temperature ultrasonic characterization

    DOE Patents [OSTI]

    Lanagan, M.T.; Kupperman, D.S.; Yaconi, G.A.

    1998-03-24

    A method and an apparatus for nondestructive detecting and evaluating changes in the microstructural properties of a material by employing one or more magnetostrictive transducers linked to the material by means of one or more sonic signal conductors. The magnetostrictive transducer or transducers are connected to a pulser/receiver which in turn is connected to an oscilloscope. The oscilloscope is connected to a computer which employs an algorithm to evaluate changes in the velocity of a signal transmitted to the material sample as function of time and temperature. 6 figs.

  16. Apparatus for monitoring high temperature ultrasonic characterization

    DOE Patents [OSTI]

    Lanagan, Michael T. (Woodridge, IL); Kupperman, David S. (Oak Park, IL); Yaconi, George A. (Berwyn, IL)

    1998-01-01

    A method and an apparatus for nondestructive detecting and evaluating chas in the microstructural properties of a material by employing one or more magnetostrictive transducers linked to the material by means of one or more sonic signal conductors. The magnetostrictive transducer or transducers are connected to a pulser/receiver which in turn is connected to an oscilloscope. The oscilloscope is connected to a computer which employs an algorithm to evaluate changes in the velocity of a signal transmitted to the material sample as function of time and temperature.

  17. High temperature solid oxide fuel development activities

    SciTech Connect (OSTI)

    Ray, E.R.

    1993-11-01

    This paper presents an overview of the Westinghouse tubular SOFC development activities and current program status. Goal is to develop a cell that can operate for 50,000 to 100,000 h. Test results are presented for multiple single cell tests which have now successfully exceeded 40,000 hours of continuous power operation at temperature. Two 25-kW SOFC customer tests units were delivered in 1992; a 20-kW SOFC system is bein manufactured and will be operated by Southern California Edison in 1995. Megawatt class generators are being developed.

  18. High Temperature Cements | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas: Energy Resources Jump to:Hershey, Pennsylvania:HiddenTemperature Cements Jump to:

  19. To Crack or Not to Crack: Strain in High Temperature Superconductors

    E-Print Network [OSTI]

    Godeke, Arno

    2008-01-01

    in High Temperature Superconductors Arno Godeke August 22,in High Temperature Superconductors Motivation Magneticin High Temperature Superconductors How do Nb 3 Sn magnets

  20. High Temperature Evaluation of Tantalum Capacitors - Test 1

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Cieslewski, Grzegorz

    2014-09-28

    Tantalum capacitors can provide much higher capacitance at high-temperatures than the ceramic capacitors. This study evaluates selected tantalum capacitors at high temperatures to determine their suitability for you in geothermal field. This data set contains results of the first test where three different types of capacitors were evaluated at 260C.

  1. ANALYSIS OF FUTURE PRICES AND MARKETS FOR HIGH TEMPERATURE SUPERCONDUCTORS

    E-Print Network [OSTI]

    1 ANALYSIS OF FUTURE PRICES AND MARKETS FOR HIGH TEMPERATURE SUPERCONDUCTORS BY JOSEPH MULHOLLAND temperature superconductors (HTS) may impact the national electrical system over the next 25 years dollars. However, the savings from superconductivity are offset somewhat by the high cost of manufacturing

  2. High Temperature Evaluation of Tantalum Capacitors - Test 1

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Cieslewski, Grzegorz

    Tantalum capacitors can provide much higher capacitance at high-temperatures than the ceramic capacitors. This study evaluates selected tantalum capacitors at high temperatures to determine their suitability for you in geothermal field. This data set contains results of the first test where three different types of capacitors were evaluated at 260C.

  3. Calculated Phonon Spectra of Plutonium at High Temperatures

    E-Print Network [OSTI]

    Savrasov, Sergej Y.

    Calculated Phonon Spectra of Plutonium at High Temperatures X. Dai,1 S. Y. Savrasov,2 * G. Kotliar dynamical proper- ties of plutonium using an electronic structure method, which incorporates correlation anharmonic and can be stabilized at high temperatures by its phonon entropy. Plutonium (Pu) is a material

  4. Considerations of Alloy N for Fluoride Salt-Cooled High-Temperature Reactor Applications

    SciTech Connect (OSTI)

    Ren, Weiju [ORNL; Muralidharan, Govindarajan [ORNL; Wilson, Dane F [ORNL; Holcomb, David Eugene [ORNL

    2011-01-01

    Fluoride Salt-Cooled High-Temperature Reactors (FHRs) are a promising new class of thermal-spectrum nuclear reactors. The reactor structural materials must possess high-temperature strength and chemical compatibility with the liquid fluoride salt as well as with a power cycle fluid such as supercritical water while remaining resistant to residual air within the containment. Alloy N was developed for use with liquid fluoride salts and it possesses adequate strength and chemical compatibility up to about 700 C. A distinctive property of FHRs is that their maximum allowable coolant temperature is restricted by their structural alloy maximum service temperature. As the reactor thermal efficiency directly increases with the maximum coolant temperature, higher temperature resistant alloys are strongly desired. This paper reviews the current status of Alloy N and its relevance to FHRs including its design principles, development history, high temperature strength, environmental resistance, metallurgical stability, component manufacturability, ASME codification status, and reactor service requirements. The review will identify issues and provide guidance for improving the alloy properties or implementing engineering solutions.

  5. Fractured rock stress-permeability relationships from in situ data and effects of temperature and chemical-mechanical couplings

    SciTech Connect (OSTI)

    Rutqvist, J.

    2014-09-19

    The purpose of this paper is to (i) review field data on stress-induced permeability changes in fractured rock; (ii) describe estimation of fractured rock stress-permeability relationships through model calibration against such field data; and (iii) discuss observations of temperature and chemically mediated fracture closure and its effect on fractured rock permeability. The field data that are reviewed include in situ block experiments, excavation-induced changes in permeability around tunnels, borehole injection experiments, depth (and stress) dependent permeability, and permeability changes associated with a large-scale rock-mass heating experiment. Data show how the stress-permeability relationship of fractured rock very much depends on local in situ conditions, such as fracture shear offset and fracture infilling by mineral precipitation. Field and laboratory experiments involving temperature have shown significant temperature-driven fracture closure even under constant stress. Such temperature-driven fracture closure has been described as thermal overclosure and relates to better fitting of opposing fracture surfaces at high temperatures, or is attributed to chemically mediated fracture closure related to pressure solution (and compaction) of stressed fracture surface asperities. Back-calculated stress-permeability relationships from field data may implicitly account for such effects, but the relative contribution of purely thermal-mechanical and chemically mediated changes is difficult to isolate. Therefore, it is concluded that further laboratory and in situ experiments are needed to increase the knowledge of the true mechanisms behind thermally driven fracture closure, and to further assess the importance of chemical-mechanical coupling for the long-term evolution of fractured rock permeability.

  6. Fractured rock stress-permeability relationships from in situ data and effects of temperature and chemical-mechanical couplings

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rutqvist, J.

    2014-09-19

    The purpose of this paper is to (i) review field data on stress-induced permeability changes in fractured rock; (ii) describe estimation of fractured rock stress-permeability relationships through model calibration against such field data; and (iii) discuss observations of temperature and chemically mediated fracture closure and its effect on fractured rock permeability. The field data that are reviewed include in situ block experiments, excavation-induced changes in permeability around tunnels, borehole injection experiments, depth (and stress) dependent permeability, and permeability changes associated with a large-scale rock-mass heating experiment. Data show how the stress-permeability relationship of fractured rock very much depends on localmore »in situ conditions, such as fracture shear offset and fracture infilling by mineral precipitation. Field and laboratory experiments involving temperature have shown significant temperature-driven fracture closure even under constant stress. Such temperature-driven fracture closure has been described as thermal overclosure and relates to better fitting of opposing fracture surfaces at high temperatures, or is attributed to chemically mediated fracture closure related to pressure solution (and compaction) of stressed fracture surface asperities. Back-calculated stress-permeability relationships from field data may implicitly account for such effects, but the relative contribution of purely thermal-mechanical and chemically mediated changes is difficult to isolate. Therefore, it is concluded that further laboratory and in situ experiments are needed to increase the knowledge of the true mechanisms behind thermally driven fracture closure, and to further assess the importance of chemical-mechanical coupling for the long-term evolution of fractured rock permeability.« less

  7. Development of high temperature solid lubricant coatings. Final report, 15 August 1997--14 August 1998

    SciTech Connect (OSTI)

    Bhattacharya, R.S.; Keller, S.

    1999-01-29

    The primary research objective of this work was to develop a solid lubricant coating that can function over a broad temperature range. The approach investigated consisted of developing adaptive lubricant coating from materials that undergo chemical change with increasing temperature by reacting together and with the environment. To test this approach, UES and Cleveland State University have conducted experiments to form cesium oxythiotungstate, a high temperature lubricant, on Inconel 718 surface from composite coatings of cesium tungstate and tungsten sulfide. The coatings were deposited by RF sputtering and characterized by X-ray Photoelectron Spectroscopy (XPS). The results indicate that sulfur escapes from the composite coating upon exposure to temperature above 5000C in air. Thus, the desired adaptive lubricant phase, cesium oxythiotungstate could not be formed. However, cesium oxythiotungstate phase has been found to form upon annealing at high temperature in vacuum. The friction coefficients of sputtered cesium oxythiotungstate and cesium tungstate coatings have been measured.

  8. On Extraction of Chemical Potentials of Quarks from Particle Transverse Momentum Spectra in High Energy Collisions

    E-Print Network [OSTI]

    Zhao, Hong

    2015-01-01

    We present two methods to extract the chemical potentials of quarks in high energy collisions. The first method is based on the ratios of negatively/positively charged particles, and the temperatures extracted from the transverse momentum spectra of related hadrons are needed. The second method is based on the chemical potentials of some particles, and we also need the transverse momentum spectra of related hadrons. To extract the quark chemical potentials, we would like to propose experimental collaborations to measure simultaneously not only the transverse momentum spectra of anti-p, p, K^-, K^+, pion^-, and pion^+, but also those of D^-, D^+, B^-, and B^+ (even those of Delta^++, Delta^-, and Omega^-) in high energy nuclear collisions

  9. Gas Viscosity at High Pressure and High Temperature 

    E-Print Network [OSTI]

    Ling, Kegang

    2012-02-14

    . Although viscosity of some pure components such as methane, ethane, propane, butane, nitrogen, carbon dioxide and binary mixtures of these components at low-intermediate pressure and temperature had been studied intensively and been understood thoroughly...

  10. Preparation of thin film high temperature superconductors

    SciTech Connect (OSTI)

    VenKatesan, X.X.T.; Li, Q.; Findikoglu, A.; Hemmick, D. . Dept. of Physics); Wu, X.D. ); Inam, A.; Chang, C.C.; Ramesh, R.; Hwang, D.M.; Ravi, T.S.; Etemad, S.; Martinez, J.A.; Wilkens, B. )

    1991-03-01

    This paper addresses fundamental issues in preparing high quality high T{sub c} YBa{sub 2}Cu{sub 3}O{sub 7{minus}x} thin films. The techniques of inverted cylindrical magnetron sputtering and pulsed laser deposition are chosen as successful examples to illustrate how the key problems can be solved. The fabrication of YBa{sub 2}Cu{sub 3}O{sub 7{minus}x}/PrBa{sub 2}Cu{sub 3}O{sub 7{minus}x} superlattices where superconductivity in a single unit cell layer of YBa{sub 2}Cu{sub 3}O{sub 7{minus}x} was observed demonstrates the state of the art of thin film deposition of high T{sub c} materials. Systematic variations of the deposition parameters result in changes of superconducting and structural properties of the films that correlate with their microwave and infrared characteristics.

  11. High Temperature Superconductivity in Cuprates: a model

    E-Print Network [OSTI]

    P. R. Silva

    2010-07-16

    A model is proposed such that quasi-particles (electrons or holes) residing in the CuO2 planes of cuprates may interact leading to metallic or superconducting behaviors. The metallic phase is obtained when the quasi-particles are treated as having classical kinetic energies and the superconducting phase occurs when the quasi-particles are taken as extremely relativistic objects. The interaction between both kinds of particles is provided by a force dependent-on-velocity. In the case of the superconducting behavior, the motion of apical oxygen ions provides the glue to establish the Cooper pair. The model furnishes explicit relations for the Fermi velocity, the perpendicular and the in-plane coherence lengths, the zero-temperature energy gap, the critical current density, the critical parallel and perpendicular magnetic fields. All these mentioned quantities are expressed in terms of fundamental physical constants as: charge and mass of the electron, light velocity in vacuum, Planck constant, electric permittivity of the vacuum. Numerical evaluation of these quantities show that their values are close those found for the superconducting YBaCuO, leading to think the model as being a possible scenario to explain superconductivity in cuprates.

  12. Sandia Energy - High-Pressure and High-Temperature Neutron Reflectomet...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High-Temperature Neutron Reflectometry Cell for Solid-Fluid Interface Studies Home Carbon Capture & Storage Climate News News & Events Carbon Capture Carbon Storage High-Pressure...

  13. High Temperature Superconductivity Partners | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancing ProgramsDepartment of¡High HIGHof

  14. Control of the water fugacity at high pressures and temperatures: Applications to the incorporation mechanisms of water in olivine

    E-Print Network [OSTI]

    Control of the water fugacity at high pressures and temperatures: Applications to the incorporation t A new method is developed to control water fugacity at a fixed pressure and temperature. We use two. The chemical environment of the olivine crystal was controlled by the water fugacity buffer, the Ni­NiO oxygen

  15. High-temperature electron emission from diamond films Department of Mechanical Engineering, Vanderbilt University, Nashville, Tennessee 37235

    E-Print Network [OSTI]

    Walker, D. Greg

    High-temperature electron emission from diamond films S. H. Shin Department of Mechanical This work examines electron field-emission characteristics of polycrystalline diamond films at elevated-enhanced chemical-vapor deposition. To investigate the effect of increased temperatures on field emission, current

  16. Effect of Engine Operating Condition and Coolant Temperature on EGR Cooler Deposit Microstructure and Chemical Composition

    Office of Energy Efficiency and Renewable Energy (EERE)

    In this work, the performance of a stand-alone EGR cooler attached to a 6.4L turbodiesel engine is being investigated by analyzing the microstructure and chemical composition of the deposits in the fouled heat exchanger surfaces, at two engine loads: medium and low, and at two coolant temperatures: 85?C and 40?C.

  17. Nanoimprint mold fabrication and replication by room-temperature conformal chemical vapor deposition

    E-Print Network [OSTI]

    Nanoimprint mold fabrication and replication by room-temperature conformal chemical vapor for the replication of molds for nanoimprint lithography NIL without solvents or etching. A thin hard amorphous from the polymer original, the thin hard film forms a NIL mold that is the inverse of the polymer

  18. To the Non-Local Theory of the High Temperature Superconductivity

    E-Print Network [OSTI]

    Boris V. Alexeev

    2012-01-30

    The possibility of the non local physics application in the theory of superconductivity is investigated. It is shown that by the superconducting conditions the relay ("estafette") motion of the soliton' system ("attice ion - electron") is realizing by the absence of chemical bonds. From the position of the quantum hydrodynamics the problem of creation of the high temperature superconductors leads to finding of materials which lattices could realize the soliton' motion without destruction. These materials should be created using the technology of quantum dots. Key words: Foundations of the theory of transport processes; The theory of solitons; Generalized hydrodynamic equations; Foundations of quantum mechanics; high temperature superconductivity.

  19. Modeling Coupled THM Processes and Brine Migration in Salt at High Temperatures

    SciTech Connect (OSTI)

    Rutqvist, Jonny; Blanco-Martin, Laura; Molins, Sergi; Trebotich, David; Birkholzer, Jens

    2015-09-01

    In this report, we present FY2015 progress by Lawrence Berkeley National Laboratory (LBNL) related to modeling of coupled thermal-hydrological-mechanical-chemical (THMC) processes in salt and their effect on brine migration at high temperatures. This is a combined milestone report related to milestone Salt R&D Milestone “Modeling Coupled THM Processes and Brine Migration in Salt at High Temperatures” (M3FT-15LB0818012) and the Salt Field Testing Milestone (M3FT-15LB0819022) to support the overall objectives of the salt field test planning.

  20. High Temperature Materials Laboratory (HTML) - PSD Directorate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory of rare Kaonforsupernovae model (Journal About DOE ButtonFSOWiki AppsAboutHigh

  1. High Temperature Thermoelectric Materials Characterization for Automotive

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancing ProgramsDepartment of¡High HIGHofWaste Heat Recovery:

  2. High Temperature Thermoelectric Materials | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancing ProgramsDepartment of¡High HIGHofWaste Heat

  3. High Temperature Calcination - MACT Upgrade Equipment Pilot Plant Test

    SciTech Connect (OSTI)

    Richard D. Boardman; B. H. O'Brien; N. R. Soelberg; S. O. Bates; R. A. Wood; C. St. Michel

    2004-02-01

    About one million gallons of acidic, hazardous, and radioactive sodium-bearing waste are stored in stainless steel tanks at the Idaho Nuclear Technology and Engineering Center (INTEC), which is a major operating facility of the Idaho National Engineering and Environmental Laboratory. Calcination at high-temperature conditions (600 C, with alumina nitrate and calcium nitrate chemical addition to the feed) is one of four options currently being considered by the Department of Energy for treatment of the remaining tank wastes. If calcination is selected for future processing of the sodium-bearing waste, it will be necessary to install new off-gas control equipment in the New Waste Calcining Facility (NWCF) to comply with the Maximum Achievable Control Technology (MACT) standards for hazardous waste combustors and incinerators. This will require, as a minimum, installing a carbon bed to reduce mercury emissions from their current level of up to 7,500 to <45 {micro}g/dscm, and a staged combustor to reduce unburned kerosene fuel in the off-gas discharge to <100 ppm CO and <10 ppm hydrocarbons. The staged combustor will also reduce NOx concentrations of about 35,000 ppm by 90-95%. A pilot-plant calcination test was completed in a newly constructed 15-cm diameter calciner vessel. The pilot-plant facility was equipped with a prototype MACT off-gas control system, including a highly efficient cyclone separator and off-gas quench/venturi scrubber for particulate removal, a staged combustor for unburned hydrocarbon and NOx destruction, and a packed activated carbon bed for mercury removal and residual chloride capture. Pilot-plant testing was performed during a 50-hour system operability test January 14-16, followed by a 100-hour high-temperature calcination pilot-plant calcination run January 19-23. Two flowsheet blends were tested: a 50-hour test with an aluminum-to-alkali metal molar ratio (AAR) of 2.25, and a 50-hour test with an AAR of 1.75. Results of the testing indicate that sodium-bearing waste can be successfully calcined at 600 C with an AAR of 1.75. Unburned hydrocarbons are reduced to less than 10 ppm (7% O2, dry basis), with >90% reduction of NOx emissions. Mercury removal by the carbon bed reached 99.99%, surpassing the control efficiency needed to meet MACT emissions standards. No deleterious impacts on the carbon bed were observed during the tests. The test results imply that upgrading the NWCF calciner with a more efficient cyclone separator and the proposed MACT equipment can process the remaining tanks wastes in 3 years or less, and comply with the MACT standards.

  4. Development of Metal Oxide Nanostructure-based Optical Sensors for Fossil Fuel Derived Gases Measurement at High Temperature

    SciTech Connect (OSTI)

    Chen, Kevin

    2014-08-31

    This final technical report details research works performed supported by a Department of Energy grant (DE-FE0003859), which was awarded under the University Coal Research Program administrated by National Energy Technology Laboratory. This research program studied high temperature fiber sensor for harsh environment applications. It developed two fiber optical sensor platform technology including regenerative fiber Bragg grating sensors and distributed fiber optical sensing based on Rayleigh backscattering optical frequency domain reflectometry. Through the studies of chemical and thermal regenerative techniques for fiber Bragg grating (FBG) fabrication, high-temperature stable FBG sensors were successfully developed and fabricated in air-hole microstructured fibers, high-attenuation fibers, rare-earth doped fibers, and standard telecommunication fibers. By optimizing the laser processing and thermal annealing procedures, fiber grating sensors with stable performance up to 1100oC have been developed. Using these temperature-stable FBG gratings as sensor platform, fiber optical flow, temperature, pressure, and chemical sensors have been developed to operate at high temperatures up to 800oC. Through the integration of on-fiber functional coating, the use of application-specific air-hole microstructural fiber, and application of active fiber sensing scheme, distributed fiber sensor for temperature, pressure, flow, liquid level, and chemical sensing have been demonstrated with high spatial resolution (1-cm or better) with wide temperature ranges. These include the demonstration of 1) liquid level sensing from 77K to the room temperature, pressure/temperature sensing from the room temperature to 800C and from the 15psi to 2000 psi, and hydrogen concentration measurement from 0.2% to 10% with temperature ranges from the room temperature to 700C. Optical sensors developed by this program has broken several technical records including flow sensors with the highest operation temperature up to 750oC, first distributed chemical measurements at the record high temperature up to 700oC, first distributed pressure measurement at the record high temperature up to 800oC, and the fiber laser sensors with the record high operation temperature up to 700oC. The research performed by this program dramatically expand the functionality, adaptability, and applicability of distributed fiber optical sensors with potential applications in a number of high-temperature energy systems such as fossil-fuel power generation, high-temperature fuel cell applications, and potential for nuclear energy systems.

  5. Toward Oxide Scale Behavior Management At High Temperature

    SciTech Connect (OSTI)

    Deltombe, R.; Dubar, M.; Dubois, A.; Dubar, L.

    2011-01-17

    Oxide scales grow freely on bare metallic surface under environmental conditions such as high temperature and oxygen. These act as thermal and mechanical shields, especially during high hot forming processes (>1000 deg. C). But product quality can be impacted by these oxide scales due to scale remaining on product or sticking on tools. Thus the TEMPO laboratory has created an original methodology in order to characterize oxide scale under high temperature, pressure and strain gradients. An experimental device has been developed. The final purpose of this work is to understand the scale behavior as a function of temperature, reduction ratio and steel composition.

  6. Method for Synthesizing Extremeley High Temperature Melting Materials

    DOE Patents [OSTI]

    Saboungi, Marie-Louise and Glorieux, Benoit

    2005-11-22

    The invention relates to a method of synthesizing high-temperature melting materials. More specifically the invention relates to a containerless method of synthesizing very high temperature melting materials such as borides, carbides and transition-metal, lanthanide and actinide oxides, using an Aerodynamic Levitator and a laser. The object of the invention is to provide a method for synthesizing extremely high-temperature melting materials that are otherwise difficult to produce, without the use of containers, allowing the manipulation of the phase (amorphous/crystalline/metastable) and permitting changes of the environment such as different gaseous compositions.

  7. Method for synthesizing extremely high-temperature melting materials

    DOE Patents [OSTI]

    Saboungi, Marie-Louise (Chicago, IL); Glorieux, Benoit (Perpignan, FR)

    2007-11-06

    The invention relates to a method of synthesizing high-temperature melting materials. More specifically the invention relates to a containerless method of synthesizing very high temperature melting materials such as carbides and transition-metal, lanthanide and actinide oxides, using an aerodynamic levitator and a laser. The object of the invention is to provide a method for synthesizing extremely high-temperature melting materials that are otherwise difficult to produce, without the use of containers, allowing the manipulation of the phase (amorphous/crystalline/metastable) and permitting changes of the environment such as different gaseous compositions.

  8. Method For Synthesizing Extremely High-Temperature Melting Materials

    DOE Patents [OSTI]

    Saboungi, Marie-Louise (Chicago, IL); Glorieux, Benoit (Perpignan, FR)

    2005-11-22

    The invention relates to a method of synthesizing high-temperature melting materials. More specifically the invention relates to a containerless method of synthesizing very high temperature melting materials such as borides, carbides and transition-metal, lanthanide and actinide oxides, using an Aerodynamic Levitator and a laser. The object of the invention is to provide a method for synthesizing extremely high-temperature melting materials that are otherwise difficult to produce, without the use of containers, allowing the manipulation of the phase (amorphous/crystalline/metastable) and permitting changes of the environment such as different gaseous compositions.

  9. Liquid Fuel Production from Biomass via High Temperature Steam Electrolysis

    SciTech Connect (OSTI)

    Grant L. Hawkes; Michael G. McKellar

    2009-11-01

    A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to heat steam for the hydrogen production via the high temperature steam electrolysis process. Hydrogen from electrolysis allows a high utilization of the biomass carbon for syngas production. Oxygen produced form the electrolysis process is used to control the oxidation rate in the oxygen-fed biomass gasifier. Based on the gasifier temperature, 94% to 95% of the carbon in the biomass becomes carbon monoxide in the syngas (carbon monoxide and hydrogen). Assuming the thermal efficiency of the power cycle for electricity generation is 50%, (as expected from GEN IV nuclear reactors), the syngas production efficiency ranges from 70% to 73% as the gasifier temperature decreases from 1900 K to 1500 K. Parametric studies of system pressure, biomass moisture content and low temperature alkaline electrolysis are also presented.

  10. Acidizing High-Temperature Carbonate Formations Using Methanesulfonic Acid 

    E-Print Network [OSTI]

    Ortega, Alexis

    2015-03-25

    Hydrochloric acid (HCl) is the most commonly used stimulation fluid for high-temperature wells drilled in carbonate reservoirs due to its high dissolving power and low cost. However, the high corrosion rate of HCl on well tubulars could make its use...

  11. Protecting Your Precious Recuperators in High Temperature Processes 

    E-Print Network [OSTI]

    Reed, R. J.

    1983-01-01

    -water-with a high latent heat, making it very forgiving. The flow of air coolant through a recuperator diminishes as the burner input is turned down to lower firing rates. But, the furnace temperature, and therefore the flue gas temperature, stays at about...

  12. High Temperature, High Pressure Devices for Zonal Isolation in...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Pressure Devices for Zonal Isolation in Geothermal Wells track 3: enhanced geothermal systems (EGS) | geothermal 2015 peer review Complete FiberCopper Cable Solution for...

  13. Assessment of Moderate- and High-Temperature Geothermal Resources...

    Open Energy Info (EERE)

    Assessment of Moderate- and High-Temperature Geothermal Resources of the United States Jump to: navigation, search OpenEI Reference LibraryAdd to library Report: Assessment of...

  14. Energy Savings with High Temperature Water Generation Systems 

    E-Print Network [OSTI]

    Manicke, A. C.

    1982-01-01

    rapidly. This paper will present and evaluate the use of a high temperature water (HTW) system and a conventional steam system. Solid, liquid and gaseous fuel applications will be presented along with the application of HTW to Cogeneration Systems. Life...

  15. Enabling high-temperature nanophotonics for energy applications

    E-Print Network [OSTI]

    Yeng, YiXiang

    The nascent field of high-temperature nanophotonics could potentially enable many important solid-state energy conversion applications, such as thermophotovoltaic energy generation, selective solar absorption, and selective ...

  16. High Temperature Irradiation Resistant Thermocouple (HTIR-TC)

    ScienceCinema (OSTI)

    None

    2013-05-28

    INL researchers have created a new thermocouple that can resist high temperature and radiation. This device will improve safety and reduce costs associated with unit failures. Learn more about INL research at http://www.facebook.com/idahonationallaboratory

  17. Stability and quench protection of high-temperature superconductors

    E-Print Network [OSTI]

    Ang, Ing Chea

    2006-01-01

    In the design and operation of a superconducting magnet, stability and protection are two key issues that determine the magnet's reliability and safe operation. Although the high-temperature superconductor (HTS) is considered ...

  18. Energy Recovery for Medium- and High-Temperature Industrial Furnaces 

    E-Print Network [OSTI]

    Krumm, E. D.

    1981-01-01

    The application of metallic heat exchangers on medium- and high-temperature industrial furnaces is examined. A thorough technical understanding of all furnace operating conditions and the duties imposed upon heat exchangers is identified as a key...

  19. Reducing PM Concentrations in Simulated High Temperature Gas Streams 

    E-Print Network [OSTI]

    Luehrs, Daniel R

    2014-08-07

    F). These high temperatures impact the cyclone inlet velocities as a consequence of the reduced gas densities. Changes in gas densities will influence the cyclone design. It was hypothesized that changes in cyclone performances as a consequence lower gas...

  20. Copper Aluminate as a potential material for high temperature...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Copper Aluminate as a potential material for high temperature thermoelectric power generation Home Author: D. T. Morelli, E. D. Case, B. D. Hall, S. Wang Year: 2008 Abstract: URL:...

  1. Microwave characterization of high-temperature superconductors

    SciTech Connect (OSTI)

    Cooke, D.W.; Gray, E.R.; Arendt, P.N.; Beery, J.G.; Bennett, B.L.; Brown, D.R.; Houlton, R.J.; Jahan, M.S.; Klapetzky, A.J.; Maez, M.A.; Raistrick, I.D.; Reeves, G.A.; Rusnak, B.

    1989-01-01

    Thick (10-15 {mu}m) Tl-Ba-Ca-Cu-O films have been deposited onto yttria-stabilized zirconia and Ag substrates by d.c. magnetron sputtering techniques. Direct deposition onto 1'' diameter yttria-stabilized zirconia yields films with typical 22 GHz surface resistance (R{sub s}) values of 5.2 {plus minus} 2 m{Omega} and 52 {plus minus} 2 m{Omega} at 10 K and 77 K, respectively. For comparison, R{sub s} of Cu at this same frequency is 10 m{Omega} at 4 K and 22 m{Omega} at 77 K. Tl-Ba-Ca-Cu-O films have also been deposited onto 1'' diameter Ag substrates using Au/Cu, Cu, and BaF{sub 2} buffer layers. The lowest R{sub s} values were obtained on films with a BaF{sub 2} buffer layer, typical values being 7.8 {plus minus} 2 m{Omega} and 30.6 {plus minus} 2 m{Omega} (measured at 22 GHz) at 10 K and 77 K, respectively. Larger films (1.5'' diameter) with similar R{sub s} values were prepared using this same technique, demonstrating that the fabrication process can be scaled to larger surface areas. These films are promising for radiofrequency cavity applications because they are thick (50-75 times the London penetration depth), have relatively large surface areas, are fabricated on metallic substrates, and have R{sub s} values that are competitive with Cu at 77 K and are lower than Cu at 4 K. Because they are polycrystalline and unoriented, it is anticipated that their R{sub s} values can be lowered by improving the processing technique. High-quality films of YBa{sub 2}Cu{sub 3}O{sub 7} have been electron-beam deposited onto 1'' LaGaO{sub 3} and 1.5'' LaAlO{sub 3} substrates. The 1'' sample is characterized by R{sub s} values of 0.2 {plus minus} 0.1 m{Omega} at 4 K and 18.6 {plus minus} 2 m{Omega} at 77 K. The 4-K value is only 2-4 times higher than Nb. The 1.5'' sample has R{sub s} values (measured at 18 GHz) of 0.93 {plus minus} 2 m{Omega} and 71 {plus minus} 3 m{Omega} at 10 K and 77 K, respectively. 18 refs., 8 figs.

  2. Liquidus temperature and chemical durability of selected glasses to immobilize rare earth oxides waste

    SciTech Connect (OSTI)

    Mohd Fadzil, Syazwani Binti; Hrma, Pavel R.; Schweiger, Michael J.; Riley, Brian J.

    2015-06-30

    Pyroprocessing is a reprocessing method for managing and reusing used nuclear fuel (UNF) by dissolving it in an electrorefiner with a molten alkali or alkaline earth chloride salt mixture while avoiding wet reprocessing. Pyroprocessing UNF with a LiCl-KCl eutectic salt releases the fission products from the fuel and generates a variety of metallic and salt-based species, including rare earth (RE) chlorides. If the RE-chlorides are converted to oxides, borosilicate glass is a prime candidate for their immobilization because of its durability and ability to dissolve almost any RE waste component into the matrix at high loadings. Crystallization that occurs in waste glasses as the waste loading increases may complicate glass processing and affect the product quality. This work compares three types of borosilicate glasses in terms of liquidus temperature (TL): the International Simple Glass designed by the International Working Group, sodium borosilicate glass developed by Korea Hydro and Nuclear Power, and the lanthanide aluminoborosilicate (LABS) glass established in the United States. The LABS glass allows the highest waste loadings (over 50 mass% RE2O3) while possessing an acceptable chemical durability.

  3. 1 6 High-Temperature-High-Pressure Diffractometry R. J. Angel*

    E-Print Network [OSTI]

    Downs, Robert T.

    1 6 High- Temperature-High-Pressure Diffractometry R. J. Angel* Bayerisches Geoinstitut 20015 *Present address: Department ofGeological Sciences, Virginia Tech, Blacksburg, VA 24061 INTRODUCTION Effective techniques for conducting high-pressure and high-temperature single-crystal X

  4. Diamond anvil cell for spectroscopic investigation of materials at high temperature, high pressure and shear

    DOE Patents [OSTI]

    Westerfield, Curtis L. (Espanola, NM); Morris, John S. (Los Alamos, NM); Agnew, Stephen F. (Los Alamos, NM)

    1997-01-01

    Diamond anvil cell for spectroscopic investigation of materials at high temperature, high pressure and shear. A cell is described which, in combination with Fourier transform IR spectroscopy, permits the spectroscopic investigation of boundary layers under conditions of high temperature, high pressure and shear.

  5. Diamond anvil cell for spectroscopic investigation of materials at high temperature, high pressure and shear

    DOE Patents [OSTI]

    Westerfield, C.L.; Morris, J.S.; Agnew, S.F.

    1997-01-14

    Diamond anvil cell is described for spectroscopic investigation of materials at high temperature, high pressure and shear. A cell is described which, in combination with Fourier transform IR spectroscopy, permits the spectroscopic investigation of boundary layers under conditions of high temperature, high pressure and shear. 4 figs.

  6. Transport and spectral functions in high-temperature QCD

    E-Print Network [OSTI]

    Gert Aarts

    2007-10-03

    The current status of transport coefficients in relativistic field theories at high temperature is reviewed. I contrast weak coupling results obtained using kinetic theory/diagrammatic techniques with strong coupling results obtained using gauge/gravity duality, and describe the recent developments in extracting transport coefficients and spectral functions from lattice QCD simulations. The fate of quarkonium at high temperature as seen from the lattice is briefly mentioned as well.

  7. High Temperature, High Pressure Devices for Zonal Isolation in Geothermal

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas: Energy Resources Jump to:Hershey, Pennsylvania:HiddenTemperature Cements JumpWells

  8. Viscosities of natural gases at high pressures and high temperatures 

    E-Print Network [OSTI]

    Viswanathan, Anup

    2007-09-17

    Estimation of viscosities of naturally occurring petroleum gases provides the information needed to accurately work out reservoir-engineering problems. Existing models for viscosity prediction are limited by data, especially at high pressures...

  9. Design of high temperature high speed electromagnetic axial thrust bearing 

    E-Print Network [OSTI]

    Mohiuddin, Mohammad Waqar

    2002-01-01

    The National Aeronautics and Space Administration (NASA) is researching the magnetic bearings to use it as a better alternative to conventional bearings. This research was to develop an axial thrust electromagnetic bearing for high performance jet...

  10. Vibration Combined High Temperature Cycle Tests for Capacitive MEMS Accelerometers

    E-Print Network [OSTI]

    Z. Szucs; G. Nagy; S. Hodossy; M. Rencz; A. Poppe

    2008-01-07

    In this paper vibration combined high temperature cycle tests for packaged capacitive SOI-MEMS accelerometers are presented. The aim of these tests is to provide useful Design for Reliability information for MEMS designers. A high temperature test chamber and a chopper-stabilized read-out circuitry were designed and realized at BME - DED. Twenty thermal cycles of combined Temperature Cycle Test and Fatigue Vibration Test has been carried out on 5 samples. Statistical evaluation of the test results showed that degradation has started in 3 out of the 5 samples.

  11. High Reliability, High TemperatureThermoelectric Power Generation Materials

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancing ProgramsDepartment of¡High HIGH PERFORMANCE and1Highand

  12. Porous nuclear fuel element with internal skeleton for high-temperature gas-cooled nuclear reactors

    DOE Patents [OSTI]

    Youchison, Dennis L.; Williams, Brian E.; Benander, Robert E.

    2013-09-03

    Porous nuclear fuel elements for use in advanced high temperature gas-cooled nuclear reactors (HTGR's), and to processes for fabricating them. Advanced uranium bi-carbide, uranium tri-carbide and uranium carbonitride nuclear fuels can be used. These fuels have high melting temperatures, high thermal conductivity, and high resistance to erosion by hot hydrogen gas. Tri-carbide fuels, such as (U,Zr,Nb)C, can be fabricated using chemical vapor infiltration (CVI) to simultaneously deposit each of the three separate carbides, e.g., UC, ZrC, and NbC in a single CVI step. By using CVI, the nuclear fuel may be deposited inside of a highly porous skeletal structure made of, for example, reticulated vitreous carbon foam.

  13. Porous nuclear fuel element for high-temperature gas-cooled nuclear reactors

    DOE Patents [OSTI]

    Youchison, Dennis L. (Albuquerque, NM); Williams, Brian E. (Pacoima, CA); Benander, Robert E. (Pacoima, CA)

    2011-03-01

    Porous nuclear fuel elements for use in advanced high temperature gas-cooled nuclear reactors (HTGR's), and to processes for fabricating them. Advanced uranium bi-carbide, uranium tri-carbide and uranium carbonitride nuclear fuels can be used. These fuels have high melting temperatures, high thermal conductivity, and high resistance to erosion by hot hydrogen gas. Tri-carbide fuels, such as (U,Zr,Nb)C, can be fabricated using chemical vapor infiltration (CVI) to simultaneously deposit each of the three separate carbides, e.g., UC, ZrC, and NbC in a single CVI step. By using CVI, the nuclear fuel may be deposited inside of a highly porous skeletal structure made of, for example, reticulated vitreous carbon foam.

  14. Methods for manufacturing porous nuclear fuel elements for high-temperature gas-cooled nuclear reactors

    DOE Patents [OSTI]

    Youchison, Dennis L. (Albuquerque, NM); Williams, Brian E. (Pocoima, CA); Benander, Robert E. (Pacoima, CA)

    2010-02-23

    Methods for manufacturing porous nuclear fuel elements for use in advanced high temperature gas-cooled nuclear reactors (HTGR's). Advanced uranium bi-carbide, uranium tri-carbide and uranium carbonitride nuclear fuels can be used. These fuels have high melting temperatures, high thermal conductivity, and high resistance to erosion by hot hydrogen gas. Tri-carbide fuels, such as (U,Zr,Nb)C, can be fabricated using chemical vapor infiltration (CVI) to simultaneously deposit each of the three separate carbides, e.g., UC, ZrC, and NbC in a single CVI step. By using CVI, a thin coating of nuclear fuel may be deposited inside of a highly porous skeletal structure made, for example, of reticulated vitreous carbon foam.

  15. Standard Operating Procedures Template for Highly Hazardous Chemicals Title of Procedure

    E-Print Network [OSTI]

    1 Standard Operating Procedures Template for Highly Hazardous Chemicals Title of Procedure: Date/Date: Risk Assessment Hazardous Chemicals: (List chemicals used. Include chemical name, common name and abbreviation) Potential Hazard(s): (Describe the potential hazards associated with the chemicals

  16. Three-loop HTLpt thermodynamics at finite temperature and chemical potential

    E-Print Network [OSTI]

    Bandyopadhyay, Aritra; Mustafa, Munshi G; Strickland, Michael; Su, Nan

    2015-01-01

    In this proceedings we present a state-of-the-art method of calculating thermodynamic potential at finite temperature and finite chemical potential, using Hard Thermal Loop perturbation theory (HTLpt) up to next-to-next-leading-order (NNLO). The resulting thermodynamic potential enables us to evaluate different thermodynamic quantities including pressure and various quark number susceptibilities (QNS). Comparison between our analytic results for those thermodynamic quantities with the available lattice data shows a good agreement.

  17. High Temperature, High Pressure Devices for Zonal Isolation in Geothermal

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancing ProgramsDepartment of¡High HIGHofWaste

  18. A process for the chemical preparation of high-field ZnO varistors

    DOE Patents [OSTI]

    Brooks, R.A.; Dosch, R.G.; Tuttle, B.A.

    1986-02-19

    Chemical preparation techniques involving co-precipitation of metals are used to provide microstructural characteristics necessary in order to produce ZnO varistors and their precursors for high field applications. The varistors produced have homogeneous and/or uniform dopant distributions and a submicron average grain size with a narrow size distribution. Precursor powders are prepared via chemical precipitation techniques and varistors made by sintering uniaxially and/or isostatically pressed pellets. Using these methods, varistors were made which were suitable for high-power applications, having values of breakdown field, E/sub B/, in the 10 to 100 kV/cm range, ..cap alpha.. > 30 and densities in the range of 65 to 99% of theoretical, depending on both composition and sintering temperature.

  19. Process for the chemical preparation of high-field ZnO varistors

    DOE Patents [OSTI]

    Brooks, Robert A. (Tijeras, NM); Dosch, Robert G. (Albuquerque, NM); Tuttle, Bruce A. (Albuquerque, NM)

    1987-01-01

    Chemical preparation techniques involving co-precipitation of metals are used to provide micro-structural characteristics necessary in order to produce ZnO varistors and their precursors for high field applications. The varistors produced have homogeneous and/or uniform dopant distributions and a submicron average grain size with a narrow size distribution. Precursor powders are prepared via chemical precipitation techniques and varistors made by sintering uniaxially and/or isostatically pressed pellets. Using these methods, varistors were made which were suitable for high-power applications, having values of breakdown field, E.sub.B, in the 10-100 kV/cm range, .alpha.>30 and densities in the range of 65-99% of theoretical, depending on both composition and sintering temperature.

  20. Method for high temperature mercury capture from gas streams

    DOE Patents [OSTI]

    Granite, E.J.; Pennline, H.W.

    2006-04-25

    A process to facilitate mercury extraction from high temperature flue/fuel gas via the use of metal sorbents which capture mercury at ambient and high temperatures. The spent sorbents can be regenerated after exposure to mercury. The metal sorbents can be used as pure metals (or combinations of metals) or dispersed on an inert support to increase surface area per gram of metal sorbent. Iridium and ruthenium are effective for mercury removal from flue and smelter gases. Palladium and platinum are effective for mercury removal from fuel gas (syngas). An iridium-platinum alloy is suitable for metal capture in many industrial effluent gas streams including highly corrosive gas streams.

  1. Optical Fiber High Temperature Sensor Instrumentation for Energy Intensive Industries

    SciTech Connect (OSTI)

    Cooper, Kristie L.; Wang, Anbo; Pickrell, Gary R.

    2006-11-14

    This report summarizes technical progress during the program “Optical Fiber High Temperature Sensor Instrumentation for Energy Intensive Industries”, performed by the Center for Photonics Technology of the Bradley Department of Electrical and Computer Engineering at Virginia Tech. The objective of this program was to use technology recently invented at Virginia Tech to develop and demonstrate the application of self-calibrating optical fiber temperature and pressure sensors to several key energy-intensive industries where conventional, commercially available sensors exhibit greatly abbreviated lifetimes due primarily to environmental degradation. A number of significant technologies were developed under this program, including • a laser bonded silica high temperature fiber sensor with a high temperature capability up to 700°C and a frequency response up to 150 kHz, • the world’s smallest fiber Fabry-Perot high temperature pressure sensor (125 x 20 ?m) with 700°C capability, • UV-induced intrinsic Fabry-Perot interferometric sensors for distributed measurement, • a single crystal sapphire fiber-based sensor with a temperature capability up to 1600°C. These technologies have been well demonstrated and laboratory tested. Our work plan included conducting major field tests of these technologies at EPRI, Corning, Pratt & Whitney, and Global Energy; field validation of the technology is critical to ensuring its usefulness to U.S. industries. Unfortunately, due to budget cuts, DOE was unable to follow through with its funding commitment to support Energy Efficiency Science Initiative projects and this final phase was eliminated.

  2. High Temperature, High Voltage Fully Integrated Gate Driver Circuit |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancing ProgramsDepartment of¡High HIGHofWasteDepartment of

  3. High Temperature, High Voltage Fully Integrated Gate Driver Circuit |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancing ProgramsDepartment of¡High HIGHofWasteDepartment

  4. High-Temperature Nuclear Reactors for In-Situ Recovery of Oil from Oil Shale

    SciTech Connect (OSTI)

    Forsberg, Charles W.

    2006-07-01

    The world is exhausting its supply of crude oil for the production of liquid fuels (gasoline, jet fuel, and diesel). However, the United States has sufficient oil shale deposits to meet our current oil demands for {approx}100 years. Shell Oil Corporation is developing a new potentially cost-effective in-situ process for oil recovery that involves drilling wells into oil shale, using electric heaters to raise the bulk temperature of the oil shale deposit to {approx}370 deg C to initiate chemical reactions that produce light crude oil, and then pumping the oil to the surface. The primary production cost is the cost of high-temperature electrical heating. Because of the low thermal conductivity of oil shale, high-temperature heat is required at the heater wells to obtain the required medium temperatures in the bulk oil shale within an economically practical two to three years. It is proposed to use high-temperature nuclear reactors to provide high-temperature heat to replace the electricity and avoid the factor-of-2 loss in converting high-temperature heat to electricity that is then used to heat oil shale. Nuclear heat is potentially viable because many oil shale deposits are thick (200 to 700 m) and can yield up to 2.5 million barrels of oil per acre, or about 125 million dollars/acre of oil at $50/barrel. The concentrated characteristics of oil-shale deposits make it practical to transfer high-temperature heat over limited distances from a reactor to the oil shale deposits. (author)

  5. Nanofluid-based receivers for high-temperature, high-flux direct solar collectors

    E-Print Network [OSTI]

    Lenert, Andrej

    2010-01-01

    Solar power plants with surface receivers have low overall energy conversion efficiencies due to large emissive losses at high temperatures. Alternatively, volumetric receivers promise increased performance because solar ...

  6. Ultra-narrow ferromagnetic resonance in organic-based thin films grown via low temperature chemical vapor deposition

    SciTech Connect (OSTI)

    Yu, H.; Harberts, M.; Adur, R.; Hammel, P. Chris; Johnston-Halperin, E., E-mail: ejh@physics.osu.edu, E-mail: epstein@physics.osu.edu [Department of Physics, The Ohio State University, Columbus, Ohio 43210-1117 (United States); Lu, Y. [Department of Chemistry, The Ohio State University, Columbus, Ohio 43210-1173 (United States); Epstein, A. J., E-mail: ejh@physics.osu.edu, E-mail: epstein@physics.osu.edu [Department of Physics, The Ohio State University, Columbus, Ohio 43210-1117 (United States); Department of Chemistry, The Ohio State University, Columbus, Ohio 43210-1173 (United States)

    2014-07-07

    We present the growth of thin films of the organic-based ferrimagnetic semiconductor V[TCNE]{sub x} (x???2, TCNE: tetracyanoethylene) via chemical vapor deposition. Under optimized growth conditions, we observe a significant increase in magnetic homogeneity, as evidenced by a Curie temperature above 600?K and sharp magnetization switching. Further, ferromagnetic resonance studies reveal a single resonance with full width at half maximum linewidth of 1.4?G, comparable to the narrowest lines measured in inorganic magnetic materials and in contrast to previous studies that showed multiple resonance features. These characteristics are promising for the development of high frequency electronic devices that take advantage of the unique properties of this organic-based material, such as the potential for low cost synthesis combined with low temperature and conformal deposition on a wide variety of substrates.

  7. Furnace Controls Using High Temperature Preheated Combustion Air 

    E-Print Network [OSTI]

    Gonzales, J. M.; Rebello, W. J.

    1981-01-01

    FURNACE CONTROLS USING HIGH TEMPERATURE PREHEATED COMBUSTION AIR Jeffrey M. Gonzalez Wilfred J. Rebello GTE Products Corporation PAR Enterprises, Inc. Towanda, Pennsylvania Fairfax, Virginia ABSTRACT GTE Products Corporation (Towanda... available ratio control apparatus. Various control sys (I) was the development of a different way of looking at combustion. As preheated combustion air temperatures increase, excess air Industrial furnaces generally utilize air as the basic source...

  8. Deposition method for producing silicon carbide high-temperature semiconductors

    DOE Patents [OSTI]

    Hsu, George C. (La Crescenta, CA); Rohatgi, Naresh K. (W. Corine, CA)

    1987-01-01

    An improved deposition method for producing silicon carbide high-temperature semiconductor material comprising placing a semiconductor substrate composed of silicon carbide in a fluidized bed silicon carbide deposition reactor, fluidizing the bed particles by hydrogen gas in a mildly bubbling mode through a gas distributor and heating the substrate at temperatures around 1200.degree.-1500.degree. C. thereby depositing a layer of silicon carbide on the semiconductor substrate.

  9. Cryocooler applications for high-temperature superconductor magnetic bearings.

    SciTech Connect (OSTI)

    Niemann, R. C.

    1998-05-22

    The efficiency and stability of rotational magnetic suspension systems are enhanced by the use of high-temperature superconductor (HTS) magnetic bearings. Fundamental aspects of the HTS magnetic bearings and rotational magnetic suspension are presented. HTS cooling can be by liquid cryogen bath immersion or by direct conduction, and thus there are various applications and integration issues for cryocoolers. Among the numerous cryocooler aspects to be considered are installation; operating temperature; losses; and vacuum pumping.

  10. Sealed glass coating of high temperature ceramic superconductors

    DOE Patents [OSTI]

    Wu, Weite (Tainan, TW); Chu, Cha Y. (Garnerville, NY); Goretta, Kenneth C. (Downers Grove, IL); Routbort, Jules L. (Darien, IL)

    1995-01-01

    A method and article of manufacture of a lead oxide based glass coating on a high temperature superconductor. The method includes preparing a dispersion of glass powders in a solution, applying the dispersion to the superconductor, drying the dispersion before applying another coating and heating the glass powder dispersion at temperatures below oxygen diffusion onset and above the glass melting point to form a continuous glass coating on the superconductor to establish compressive stresses which enhance the fracture strength of the superconductor.

  11. Nearly Perfect Fluidity in a High Temperature Superconductor

    SciTech Connect (OSTI)

    Rameau, J. D.; Reber, T. J.; Yang, H. -B.; Akhanjee, S.; Gu, G. D.; Johnson, P. D.; Campbell, S.

    2014-10-13

    Perfect fluids are characterized as having the smallest ratio of shear viscosity to entropy density, ?/s, consistent with quantum uncertainty and causality. So far, nearly perfect fluids have only been observed in the quark-gluon plasma and in unitary atomic Fermi gases, exotic systems that are amongst the hottest and coldest objects in the known universe, respectively. We use angle resolved photoemission spectroscopy to measure the temperature dependence of an electronic analog of ?/s in an optimally doped cuprate high-temperature superconductor, finding it too is a nearly perfect fluid around, and above, its superconducting transition temperature Tc.

  12. Nearly Perfect Fluidity in a High Temperature Superconductor

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rameau, J. D.; Reber, T. J.; Yang, H. -B.; Akhanjee, S.; Gu, G. D.; Johnson, P. D.; Campbell, S.

    2014-10-13

    Perfect fluids are characterized as having the smallest ratio of shear viscosity to entropy density, ?/s, consistent with quantum uncertainty and causality. So far, nearly perfect fluids have only been observed in the quark-gluon plasma and in unitary atomic Fermi gases, exotic systems that are amongst the hottest and coldest objects in the known universe, respectively. We use angle resolved photoemission spectroscopy to measure the temperature dependence of an electronic analog of ?/s in an optimally doped cuprate high-temperature superconductor, finding it too is a nearly perfect fluid around, and above, its superconducting transition temperature Tc.

  13. Final Scientific Report - "Novel Steels for High Temperature Carburizing"

    SciTech Connect (OSTI)

    McKimpson, Marvin G.; Liu, Tianjun; Maniruzzaman, Md

    2012-07-27

    This program was undertaken to develop a microalloy-modified grade of standard carburizing steel that can successfully exploit the high temperature carburizing capabilities of current commercial low pressure (i.e. 'vacuum') carburizing systems. Such steels can lower the amount of energy required for commercial carburizing operations by reducing the time required for deep-case carburizing operations. The specific technical objective of the work was to demonstrate a carburizing steel composition capable of maintaining a prior austenite grain size no larger than ASTM grain size number 5 after exposure to simulated carburizing conditions of 1050 C for 8 hr. Such thermal exposure should be adequate for producing carburized case depths up to about 2 mm. Such carburizing steels are expected to be attractive for use across a wide range of industries, including the petroleum, chemical, forest products, automotive, mining and industrial equipment industries. They have potential for reducing energy usage during low pressure carburizing by more than 25%, as well as reducing cycle times and process costs substantially. They also have potential for reducing greenhouse gas emissions from existing low pressure carburizing furnaces by more than 25%. High temperature carburizing can be done in most modern low pressure carburizing systems with no additional capital investment. Accordingly, implementing this technology on carburizing furnaces will provide a return on investment significantly greater than 10%. If disseminated throughout the domestic carburizing community, the technology has potential for saving on the order of 23 to 34 trillion BTU/year in industrial energy usage. Under the program, two compositions of microalloyed, coarsening-resistant low alloy carburizing steels were developed, produced and evaluated. After vacuum annealing at 1050oC for 8 hrs and high pressure gas quenching, both steels exhibited a prior austenite ASTM grain size number of 5.0 or finer. For comparison, a control alloy of similar composition but without the microalloy additions exhibited a duplex prior austenite grain size with grains ranging from ASTM grain size 3 down to ASTM grain size 1 after similar processing and thermal exposure. These results confirm the potential for using microalloy additions of Ti, B, Nb, Al, rare earths and/or N for austenite grain size control in Cr-Mo (i.e. 4000-series) low alloy carburizing steels. They also demonstrate that these microalloy additions will not compromise the processability of the steel; all three materials produced under the program could be hot worked readily using normal steel processing protocols. To fully realize the technical and commercial potential of these steels, there is a need to continue development work using larger-scale heats. These larger-scale heats are needed to provide adequate material for fatigue testing of quenched and tempered alloys, to conduct more complete investigations of potential alloy chemistries and to provide additional material for processing studies. It will also be beneficial to carefully review intellectual property issues associated with this family of steels, since existing Japanese patent literature suggests that significant microstructural and/or process characterization work may be needed on new materials to confirm that these materials fall outside existing patent claims.

  14. High- and low-temperature-stable thermite composition for producing high-pressure, high-velocity gases

    DOE Patents [OSTI]

    Halcomb, Danny L. (Camden, OH); Mohler, Jonathan H. (Spring Valley, OH)

    1990-10-16

    A high- and low-temperature-stable thermite composition for producing high-pressure and high-velocity gases comprises an oxidizable metal, an oxidizing reagent, and a high-temperature-stable gas-producing additive selected from the group consisting of metal carbides and metal nitrides.

  15. High-temperature corrosion control of lagged piping system components

    SciTech Connect (OSTI)

    Parks, R. (Dept. of the Navy, Naval Sea Systems Command, Code 05M11, Washington, DC (US)); Kogler, R.A. (Advanced Technology Inc., Arlington, VA (US))

    1990-07-01

    Over the past several years, the U.S. Navy has stepped up efforts to eliminate corrosion aboard its ships. One of the most effective techniques the Navy has employed is the application of sprayed aluminum for high-temperature corrosion protection. This sacrificial coating has performed well in the corrosion protection of high-temperature lagged steam valves and associated piping systems. Because of the superiority of the sprayed aluminum system over the conventional methods of protection for these piping systems, the Navy has realized considerable cost savings. These savings are the direct result of major reductions in routine maintenance associated with the application of sprayed aluminum coatings for corrosion protection purposes. This article discusses specific U.S. Navy experience with the use of sprayed aluminum coatings for high-temperature applications as well as current Navy practice regarding the use of this corrosion control coating.

  16. Silicon Carbide Temperature Monitor Measurements at the High Temperature Test Laboratory

    SciTech Connect (OSTI)

    J. L. Rempe; K. G. Condie; D. L. Knudson; L. L. Snead

    2010-01-01

    Silicon carbide (SiC) temperature monitors are now available for use as temperature sensors in Advanced Test Reactor (ATR) irradiation test capsules. Melt wires or paint spots, which are typically used as temperature sensors in ATR static capsules, are limited in that they can only detect whether a single temperature is or is not exceeded. SiC monitors are advantageous because a single monitor can be used to detect for a range of temperatures that may have occurred during irradiation. As part of the efforts initiated by the ATR National Scientific User Facility (NSUF) to make SiC temperature monitors available, a capability was developed to complete post-irradiation evaluations of these monitors. As discussed in this report, the Idaho National Laboratory (INL) selected the resistance measurement approach for detecting peak irradiation temperature from SiC temperature monitors. This document describes the INL efforts to develop the capability to complete these resistance measurements. In addition, the procedure is reported that was developed to assure that high quality measurements are made in a consistent fashion.

  17. Quantum tunneling, quantum computing, and high temperature superconductivity 

    E-Print Network [OSTI]

    Wang, Qian

    2005-02-17

    -1 QUANTUM TUNNELING, QUANTUM COMPUTING, AND HIGH TEMPERATURE SUPERCONDUCTIVITY A Dissertation by QIAN WANG Submitted to the O?ce of Graduate Studies of Texas A&M University in partial ful?llment of the requirements for the degree of DOCTOR OF PHILOSOPHY... December 2003 Major Subject: Physics QUANTUM TUNNELING, QUANTUM COMPUTING, AND HIGH TEMPERATURE SUPERCONDUCTIVITY A Dissertation by QIAN WANG Submitted to Texas A&M University in partial ful?llment of the requirements for the degree of DOCTOR OF PHILOSOPHY...

  18. Which Chiral Symmetry is Restored in High Temperature QCD?

    E-Print Network [OSTI]

    Claude Bernard; Tom Blum; Carleton DeTar; Steven Gottlieb; Urs M. Heller; James E. Hetrick; K. Rummukainen; R. Sugar; D. Toussaint; Matthew Wingate

    1996-11-27

    Sigma models for the high temperature phase transition in quantum chromodynamics (QCD) suggest that at high temperature the SU(N_f) x SU(N_f) chiral symmetry becomes exact, but the anomalous axial U(1) symmetry need not be restored. In numerical lattice simulations, traditional methods for detecting symmetry restoration have sought multiplets in the screening mass spectrum. However, these methods were imprecise and the results, so far, incomplete. With improved statistics and methodology, we are now able to offer evidence for a restoration of the SU(2) x SU(2) chiral symmetry just above the crossover, but not of the axial U(1) chiral symmetry.

  19. Silver-bearing, high-temperature, superconducting (HTS) paint

    SciTech Connect (OSTI)

    Ferrando, W.A.

    1990-02-15

    A substantial set of device applications awaits development of a workable, durable, high-temperature superconducting (HTS) paint. Such a paint should be truly superconducting with its critical temperature T sub c>77K. For most of these applications, a high critical current (J sub c) is not required, although probably desirable. A process is described which can be used to produce silver-bearing HTS paint coatings on many engineering materials. Preliminary tests have shown good adherence to several ceramics and the ability to meet the superconducting criteria. Moreover, the coatings withstand multiple thermal cycling and stability under laboratory ambient storage conditions for periods of at least several months.

  20. Microsoft Word - NETL-TRS-5-2014_High-Temperature, High-Pressure...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    values at 533 K (gray dashed line). Suggested Citation: Gamwo, I. K.; Tapriyal, D.; Enick, R. M.; McHugh, M. A.; Morreale, B. D. High Temperature, High Pressure Equation of...

  1. Growth of highly oriented carbon nanotubes by plasma-enhanced hot filament chemical vapor deposition

    SciTech Connect (OSTI)

    Huang, Z.P.; Xu, J.W.; Ren, Z.F.; Wang, J.H.; Siegal, M.P.; Provencio, P.N.

    1998-12-01

    Highly oriented, multiwalled carbon nanotubes were grown on polished polycrystalline and single crystal nickel substrates by plasma enhanced hot filament chemical vapor deposition at temperatures below 666 {degree}C. The carbon nanotubes range from 10 to 500 nm in diameter and 0.1 to 50 {mu}m in length depending on growth conditions. Acetylene is used as the carbon source for the growth of the carbon nanotubes and ammonia is used for dilution gas and catalysis. The plasma intensity, acetylene to ammonia gas ratio, and their flow rates, etc. affect the diameters and uniformity of the carbon nanotubes. {copyright} {ital 1998 American Institute of Physics.}

  2. High-Temperature Quantum Coherence from Dissipative Environments

    E-Print Network [OSTI]

    George E. Cragg

    2014-11-14

    The Feynman-Vernon path integral formalism is used to derive the density matrix of a quantum oscillator that is linearly coupled to an environmental reservoir. Although low-temperature reservoirs thermalize the oscillator to the usual Boltzmann distribution, reservoirs at intermediate temperatures reduce this distribution to a single, coherent ground state. Associated with this state is an imaginary frequency indicating an environment which absorbs energy from the oscillator through the suppression of all excited modes. Further increase of the environmental temperature results again in the thermalization of the quantum oscillator to the expected Boltzmann distribution. Qualitatively, this result could account for high-temperature quantum effects including the superconducting properties of graphite grains as well as the quantum coherence observed in photosynthetic systems.

  3. Advances in downhole sampling of high temperature solutions

    SciTech Connect (OSTI)

    Bayhurst, G.K.; Janecky, D.R.

    1991-01-01

    A fluid sampler capable of sampling hot and/or deep wells has been developed at Los Alamos National Laboratory. In collaboration with Leutert Instruments, an off-the-shelf sampler design was modified to meet gas-tight and minimal chemical reactivity/contamination specifications for use in geothermal wells and deep ocean drillholes. This downhole sampler has been routinely used at temperatures up to 300{degrees}C and hole depths of greater than 5 km. We have tested this sampler in various continental wells, including Valles Caldera VC-2a and VC-2b, German KTB, Cajon Pass, and Yellowstone Y-10. Both the standard commercial and enhanced samplers have also been used to obtain samples from a range of depths in the Ocean Drilling Project's hole 504B and during recent mid-ocean ridge drilling efforts. The sampler has made it possible to collect samples at temperatures and conditions beyond the limits of other tools with the added advantage of chemical corrosion resistance.

  4. High Temperature Materials Interim Data Qualification Report FY 2011

    SciTech Connect (OSTI)

    Nancy Lybeck

    2011-08-01

    Projects for the very high temperature reactor (VHTR) Technology Development Office provide data in support of Nuclear Regulatory Commission licensing of the VHTR. Fuel and materials to be used in the reactor are tested and characterized to quantify performance in high temperature and high fluence environments. The VHTR program has established the Next Generation Nuclear Plant (NGNP) Data Management and Analysis System (NDMAS) to ensure that VHTR data are qualified for use, stored in a readily accessible electronic form, and analyzed to extract useful results. This document focuses on the first NDMAS objective. It describes the High Temperature Materials characterization data stream, the processing of these data within NDMAS, and reports the interim fiscal year (FY) 2011 qualification status of the data. Data qualification activities within NDMAS for specific types of data are determined by the data qualification category assigned by the data generator. The High Temperature Materials data are being collected under the Nuclear Quality Assurance (NQA)-1 guidelines and will be qualified data. For NQA-1 qualified data, the qualification activities include: (1) capture testing to confirm that the data stored within NDMAS are identical to the raw data supplied, (2) accuracy testing to confirm that the data are an accurate representation of the system or object being measured, and (3) documenting that the data were collected under an NQA-1 or equivalent Quality Assurance program. Currently, data from seven test series within the High Temperature Materials data stream have been entered into the NDMAS vault, including tensile tests, creep tests, and cyclic tests. Of the 5,603,682 records currently in the vault, 4,480,444 have been capture passed, and capture testing is in process for the remaining 1,123,238.

  5. Materials for the scavanging of hydrogen at high temperatures

    DOE Patents [OSTI]

    Shepodd, Timothy J. (330 Thrasher Ave., Livermore, Alameda County, CA 94550); Phillip, Bradley L. (20976 Fairmount Blvd., Shaker Heights, Cuyahoga County, OH 44120)

    1997-01-01

    A hydrogen getter composition comprising a double or triple bonded hydrocarbon with a high melting point useful for removing hydrogen gas, to partial pressures below 0.01 torr, from enclosed spaces and particularly from vessels used for transporting or containing fluids at elevated temperatures. The hydrogen getter compostions disclosed herein and their reaction products will neither melt nor char at temperatures in excess of 100C. They possess significant advantages over conventional hydrogen getters, namely low risk of fire or explosion, no requirement for high temperature activation or operation, the ability to absorb hydrogen even in the presence of contaminants such as water, water vapor, common atmospheric gases and oil mists and are designed to be disposed within the confines of the apparatus. These getter materials can be mixed with binders, such as fluropolymers, which permit the getter material to be fabricated into useful shapes and/or impart desirable properties such as water repellency or impermeability to various gases.

  6. Materials for the scavanging of hydrogen at high temperatures

    DOE Patents [OSTI]

    Shepodd, Timothy J. (Livermore, CA); Phillip, Bradley L. (Shaker Heights, OH)

    1997-01-01

    A hydrogen getter composition comprising a double or triple bonded hydrocarbon with a high melting point useful for removing hydrogen gas, to partial pressures below 0.01 torr, from enclosed spaces and particularly from vessels used for transporting or containing fluids at elevated temperatures. The hydrogen getter compositions disclosed herein and their reaction products will neither melt nor char at temperatures in excess of 100.degree. C. They possess significant advantages over conventional hydrogen getters, namely low risk of fire or explosion, no requirement for high temperature activation or operation, the ability to absorb hydrogen even in the presence of contaminants such as water, water vapor, common atmospheric gases and oil mists and are designed to be disposed within the confines of the apparatus. These getter materials can be mixed with binders, such as fluropolymers, which permit the getter material to be fabricated into useful shapes and/or impart desirable properties such as water repellency or impermeability to various gases.

  7. High Operating Temperature Liquid Metal Heat Transfer Fluids (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-12-01

    The University of California, Los Angeles, the University of California, Berkeley, and Yale University is one of the 2012 SunShot CSP R&D awardees for their Multidisciplinary University Research Initiative (MURI): High Operating Temperature (HOT) Fluids. This fact sheet explains the motivation, description, and impact of the project.

  8. Author's Accepted Manuscript High-temperature-oxidation-induced ordered struc-

    E-Print Network [OSTI]

    Laughlin, David E.

    and turbine power generation system, turbine alloys are exposed to high temperature and an atmosphere comprised of steam, CO2 and O2. While surface and internal oxidation of the alloy takes place-fuel combustion turbine power generation systems are being developed, materials performance of candidate

  9. PSO project: 4760 High Temperature PEM Fuel Cell

    E-Print Network [OSTI]

    PSO project: 4760 High Temperature PEM Fuel Cell Final report - Public part - #12;Project, Technical University of Denmark Partners: IRD Fuel Cells A/S Danish Power Systems Aps DONG Energy Authors, and a steady reduction of production cost is also desired (as in general for fuel cells). However, during

  10. POWER-TO-GAS PROCESS WITH HIGH TEMPERATURE ELECTROLYSIS

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    · Transportation of energy from production areas to consumption areas Substitute Natural Gas (methane) Myriam DeP · Use of existing natural gas network · Mid or long term storage · Transportation · Production. Energy background 2. Power-to-Substitute Natural Gas process with high temperature steam electrolysis

  11. Well Productivity Enhancement of High Temperature Heterogeneous Carbonate Reservoirs 

    E-Print Network [OSTI]

    Wang, Guanqun

    2014-05-08

    . Uneven acid distribution always results in productivity enhancement under expectation. When such a well is drilled, the temperature of the well could be too high to keep the acid reaction under control. The acid used in the treatment fluid, most commonly...

  12. Control of High-Temperature Supersonic Impinging Jets Using Microjets

    E-Print Network [OSTI]

    Control of High-Temperature Supersonic Impinging Jets Using Microjets Rajan Kumar, Sladana Lazic.2514/1.39061 The flowfield associated with supersonic impinging jets has been of interest to both engineers and researchers fluid dynamic point of view. An example of supersonic impinging jets occurs in short takeoff

  13. Free energy of Lorentz-violating QED at high temperature

    E-Print Network [OSTI]

    M. Gomes; T. Mariz; J. R. Nascimento; A. Yu. Petrov; A. F. Santos; A. J. da Silva

    2010-02-25

    In this paper we study the one- and two-loop contribution to the free energy in QED with the Lorentz symmetry breaking introduced via constant CPT-even Lorentz-breaking parameters at the high temperature limit. We find the impact of the Lorentz-violating term for the free energy and carry out a numerical estimation for the Lorentz-breaking parameter.

  14. High Temperature coatings based on {beta}-NiAI

    SciTech Connect (OSTI)

    Severs, Kevin

    2012-07-10

    High temperature alloys are reviewed, focusing on current superalloys and their coatings. The synthesis, characerization, and oxidation performance of a NiAl–TiB{sub 2} composite are explained. A novel coating process for Mo–Ni–Al alloys for improved oxidation performance is examined. The cyclic oxidation performance of coated and uncoated Mo–Ni–Al alloys is discussed.

  15. Thermally Stable Nanocatalyst for High Temperature Reactions: Pt-Mesoporous Silica Core-Shell Nanoparticles

    SciTech Connect (OSTI)

    Joo, Sang Hoon; Park, J.Y.; Tsung, C.-K.; Yamada, Y.; Yang, P.; Somorjai, G.A.

    2008-10-25

    Recent advances in colloidal synthesis enabled the precise control of size, shape and composition of catalytic metal nanoparticles, allowing their use as model catalysts for systematic investigations of the atomic-scale properties affecting catalytic activity and selectivity. The organic capping agents stabilizing colloidal nanoparticles, however, often limit their application in high-temperature catalytic reactions. Here we report the design of a high-temperature stable model catalytic system that consists of Pt metal core coated with a mesoporous silica shell (Pt{at}mSiO{sub 2}). While inorganic silica shells encaged the Pt cores up to 750 C in air, the mesopores directly accessible to Pt cores made the Pt{at}mSiO{sub 2} nanoparticles as catalytically active as bare Pt metal for ethylene hydrogenation and CO oxidation. The high thermal stability of Pt{at}mSiO{sub 2} nanoparticles permitted high-temperature CO oxidation studies, including ignition behavior, which was not possible for bare Pt nanoparticles because of their deformation or aggregation. The results suggest that the Pt{at}mSiO{sub 2} nanoparticles are excellent nanocatalytic systems for high-temperature catalytic reactions or surface chemical processes, and the design concept employed in the Pt{at}mSiO{sub 2} core-shell catalyst can be extended to other metal-metal oxide compositions.

  16. The influence of substrate polarity on the structural quality of InN layers grown by high-pressure chemical vapor deposition

    E-Print Network [OSTI]

    Dietz, Nikolaus

    the growth temperatures to below 650 °C for low-pressure metal organic chemical vapor depo- sition MOCVDThe influence of substrate polarity on the structural quality of InN layers grown by high-pressure chemical vapor deposition N. Dietz,1,a M. Alevli,1 R. Atalay,1 G. Durkaya,1 R. Collazo,2 J. Tweedie,2 S

  17. Enhancements to High Temperature In-Pile Thermocouple Performance

    SciTech Connect (OSTI)

    J.C. Crepeau; J.L. Rempe; J.E. Daw; D.L. Knudson: K.G. Condie; S.C. Wilkins

    2008-03-31

    A joint University of Idaho (UI) and Idaho National Laboratory (INL) University Nuclear Research Initiative (UNERI) was to initiated to extend initial INL efforts to develop doped molybdenum/niobium alloy High Temperature Irradiation Resistant Thermocouples (HTIR-TCs). The overall objective of this UNERI was to develop recommendations for an optimized thermocouple design for high temperature, long duration, in-pile testing by expanding upon results from initial INL efforts. Tasks to quantify the impact of candidate enhancements, such as alternate alloys, alternate geometries, and alternate thermocouple fabrication techniques, on thermocouple performance were completed at INL's High Temperature Test Laboratory (HTTL), a state of the art facility equipped with specialized equipment and trained staff in the area of high temperature instrumentation development and evaluation. Key results of these evaluations, which are documented in this report, are as follows. The doped molybdenum and Nb-1%Zr, which were proposed in the initial INL HTIR-TC design, were found to retain ductility better than the developmental molybdenum-low niobium alloys and the niobium-low molybdenum alloys evaluated. Hence, the performance and lower cost of the commercially available KW-Mo makes a thermocouple containing KW-Mo and Nb-1%Zr the best option at this time. HTIR-TCs containing larger diameter wires offer the potential to increase HTIR-TC stability and reliability at higher temperatures. HTIR-TC heat treatment temperatures and times should be limited to not more than 100 C above the proposed operating temperatures and to durations of at least 4 to 5 hours. Preliminary investigations suggest that the performance of swaged and loose assembly HTIR-TC designs is similar. However, the swaged designs are less expensive and easier to construct. In addition to optimizing HTIR-TC performance, This UNERI project provided unique opportunities to several University of Idaho students, allowing them to become familiar with the techniques and equipment used for specialized high temperature instrumentation fabrication and evaluation and to author/coauthor several key conference papers and journal articles.

  18. Enhancements to High Temperature In-Pile Thermocouple Performance

    SciTech Connect (OSTI)

    J. C. Crepeau; J. L. Rempe; J. E. Daw; D. L. Knudson; K. G. Condie; S. C. Wilkins

    2008-03-01

    A joint University of Idaho (UI) and Idaho National Laboratory (INL) University Nuclear Research Initiative (UNERI) was to initiated to extend initial INL efforts to develop doped lybdenum/niobium alloy High Temperature Irradiation Resistant Thermocouples (HTIR-TCs). The overall objective of this UNERI was to develop recommendations for an optimized thermocouple design for high temperature, long duration, in-pile testing by expanding upon results from initial INL efforts. Tasks to quantify the impact of candidate enhancements, such as alternate alloys, alternate geometries, and alternate thermocouple fabrication techniques, on thermocouple performance were completed at INL's High Temperature Test Laboratory (HTTL), a state of the art facility equipped with specialized equipment and trained staff in the area of high temperature instrumentation development and evaluation. Key results of these evaluations, which are documented in this report, are as follows. The doped molybdenum and Nb-1%Zr, which were proposed in the initial INL HTIR-TC design, were found to retain ductility better than the developmental molybdenum-low niobium alloys and the niobium-low molybdenum alloys evaluated. Hence, the performance and lower cost of the commercially available KW-Mo makes a thermocouple containing KW-Mo and Nb-1%Zr the best option at this time. HTIR-TCs containing larger diameter wires offer the potential to increase HTIR-TC stability and reliability at higher temperatures. HTIR-TC heat treatment temperatures and times should be limited to not more than 100 °C above the proposed operating temperatures and to durations of at least 4 to 5 hours. Preliminary investigations suggest that the performance of swaged and loose assembly HTIR-TC designs is similar. However, the swaged designs are less expensive and easier to construct. In addition to optimizing HTIR-TC performance, This UNERI project provided unique opportunities to several University of Idaho students, allowing them to become familiar with the techniques and equipment used for specialized high temperature instrumentation fabrication and evaluation and to author/coauthor several key conference papers and journal articles.

  19. High-Concentration Chemical Computing Techniques for Solving Hard-To-Solve Problems,

    E-Print Network [OSTI]

    Kreinovich, Vladik

    . University El Paso, TX 79968, USA {vladik, ofuentes}@utep.edu Abstract Chemical computing ­ using chemicalHigh-Concentration Chemical Computing Techniques for Solving Hard-To-Solve Problems. Chemical computing is promising because it has the potential of using up to 1023 molecules as processors

  20. Preparation of high porosity xerogels by chemical surface modification.

    DOE Patents [OSTI]

    Deshpande, Ravindra (51 Michelle Dr. Apt. A 11, Lancaster, PA 17603); Smith, Douglas M. (1412 Marquette Pl. NE., Albuquerque, NM 87122); Brinker, C. Jeffrey (14 Eagle Nest Dr. NE., Albuquerque, NM 87122)

    1996-01-01

    This invention provides an extremely porous xerogel dried at vacuum-to-below supercritical pressures but having the properties of aerogels which are typically dried at supercritical pressures. This is done by reacting the internal pore surface of the wet gel with organic substances in order to change the contact angle of the fluid meniscus in the pores during drying. Shrinkage of the gel (which is normally prevented by use of high autoclave pressures, such that the pore fluid is at temperature and pressure above its critical values) is avoided even at vacuum or ambient pressures.

  1. The effect of different annealing temperatures on tin and cadmium telluride phases obtained by a modified chemical route

    SciTech Connect (OSTI)

    Mesquita, Anderson Fuzer; Porto, Arilza de Oliveira; Magela de Lima, Geraldo; Paniago, Roberto; Ardisson, José Domingos

    2012-11-15

    Graphical abstract: Display Omitted Highlights: ? Synthesis of cadmium and tin telluride. ? Chemical route to obtain pure crystalline cadmium and tin telluride. ? Effect of the annealing temperature on the crystalline phases. ? Removal of tin oxide as side product through thermal treatment. -- Abstract: In this work tin and cadmium telluride were prepared by a modification of a chemical route reported in the literature to obtain metallacycles formed by oxidative addition of tin-tellurium bonds to platinum (II). Through this procedure it was possible to obtain tin and cadmium telluride. X-ray diffraction and X-ray photoelectron spectroscopy were used to identify the crystalline phases obtained as well as the presence of side products. In the case of tin telluride it was identified potassium chloride, metallic tellurium and tin oxide as contaminants. The tin oxidation states were also monitored by {sup 119}Sn Mössbauer spectroscopy. The annealing in hydrogen atmosphere was chosen as a strategy to reduce the tin oxide and promote its reaction with the excess of tellurium present in the medium. The evolution of this tin oxide phase was studied through the annealing of the sample at different temperatures. Cadmium telluride was obtained with high degree of purity (98.5% relative weight fraction) according to the Rietveld refinement of X-ray diffraction data. The modified procedure showed to be very effective to obtain amorphous tin and cadmium telluride and the annealing at 450 °C has proven to be useful to reduce the amount of oxide produced as side product.

  2. Direct Utilization of Coal Syngas in High Temperature Fuel Cells

    SciTech Connect (OSTI)

    Celik, Ismail B.

    2014-10-30

    This EPSCoR project had two primary goals: (i) to build infrastructure and work force at WVU to support long-term research in the area of fuel cells and related sciences; (ii) study effects of various impurities found in coal-syngas on performance of Solid Oxide Fuel Cells (SOFC). As detailed in this report the WVU research team has made significant accomplishments in both of these areas. What follows is a brief summary of these accomplishments: State-of-the-art test facilities and diagnostic tools have been built and put into use. These include cell manufacturing, half-cell and full-cell test benches, XPS, XRD, TEM, Raman, EDAX, SEM, EIS, and ESEM equipment, unique in-situ measurement techniques and test benches (Environmental EM, Transient Mass-Spectrometer-MS, and IR Optical Temperature measurements). In addition, computational capabilities have been developed culminating in a multi-scale multi-physics fuel cell simulation code, DREAM-SOFC, as well as a Beowulf cluster with 64 CPU units. We have trained 16 graduate students, 10 postdoctoral fellows, and recruited 4 new young faculty members who have actively participated in the EPSCoR project. All four of these faculty members have already been promoted to the tenured associate professor level. With the help of these faculty and students, we were able to secure 14 research awards/contracts amounting to a total of circa $5.0 Million external funding in closely related areas of research. Using the facilities mentioned above, the effects of PH3, HCl, Cl2, and H2S on cell performance have been studied in detail, mechanisms have been identified, and also remedies have been proposed and demonstrated in the laboratory. For example, it has been determined that PH3 reacts rapidly with Ni to from secondary compounds which may become softer or even melt at high temperature and then induce Ni migration to the surface of the cell changing the material and micro-structural properties of the cell drastically. It is found that the extent of steam and current load accelerate the degradation caused by PH3. A unique filtering technique has been proposed to reduce the effect of PH3. In addition, various cell materials have been proposed to reduce the rate of degradation caused by H2S. Furthermore, a three-dimensional, transient multi-physics model has been formulated to describe primary transport processes and electro-chemical reactions occurring within the cell. This model has been validated using data gathered from accelerated tests. The validated model then has been used to study the degradation rates under a range of operating conditions and impurity levels. This has resulted in a procedure that uses both experiments and simulations to predict the life-time of a cell operating with syngas with known concentration of trace impurities. Finally all the experience and knowledge gained has been disseminated via 39 journal papers and 43 presentations/posters/conference papers.

  3. Understanding Fundamental Material Degradation Processes in High Temperature Aggressive Chemomechanical Environments

    SciTech Connect (OSTI)

    Stubbins, James; Gewirth, Andrew; Sehitoglu, Huseyin; Sofronis, Petros; Robertson, Ian

    2014-01-16

    The objective of this project is to develop a fundamental understanding of the mechanisms that limit materials durability for very high-temperature applications. Current design limitations are based on material strength and corrosion resistance. This project will characterize the interactions of high-temperature creep, fatigue, and environmental attack in structural metallic alloys of interest for the very high-temperature gas-cooled reactor (VHTR) or Next–Generation Nuclear Plant (NGNP) and for the associated thermo-chemical processing systems for hydrogen generation. Each of these degradation processes presents a major materials design challenge on its own, but in combination, they can act synergistically to rapidly degrade materials and limit component lives. This research and development effort will provide experimental results to characterize creep-fatigue-environment interactions and develop predictive models to define operation limits for high-temperature structural material applications. Researchers will study individually and in combination creep-fatigue-environmental attack processes in Alloys 617, 230, and 800H, as well as in an advanced Ni-Cr oxide dispersion strengthened steel (ODS) system. For comparison, the study will also examine basic degradation processes in nichrome (Ni-20Cr), which is a basis for most high-temperature structural materials, as well as many of the superalloys. These materials are selected to represent primary candidate alloys, one advanced developmental alloy that may have superior high-temperature durability, and one model system on which basic performance and modeling efforts can be based. The research program is presented in four parts, which all complement each other. The first three are primarily experimental in nature, and the last will tie the work together in a coordinated modeling effort. The sections are (1) dynamic creep-fatigue-environment process, (2) subcritical crack processes, (3) dynamic corrosion – crack initiation processes, and (4) modeling.

  4. Isobutane ignition delay time measurements at high pressure and detailed chemical kinetic simulations

    SciTech Connect (OSTI)

    Healy, D.; Curran, H.J.; Donato, N.S.; Aul, C.J.; Petersen, E.L.; Zinner, C.M.; Bourque, G.

    2010-08-15

    Rapid compression machine and shock-tube ignition experiments were performed for real fuel/air isobutane mixtures at equivalence ratios of 0.3, 0.5, 1, and 2. The wide range of experimental conditions included temperatures from 590 to 1567 K at pressures of approximately 1, 10, 20, and 30 atm. These data represent the most comprehensive set of experiments currently available for isobutane oxidation and further accentuate the complementary attributes of the two techniques toward high-pressure oxidation experiments over a wide range of temperatures. The experimental results were used to validate a detailed chemical kinetic model composed of 1328 reactions involving 230 species. This mechanism has been successfully used to simulate previously published ignition delay times as well. A thorough sensitivity analysis was performed to gain further insight to the chemical processes occurring at various conditions. Additionally, useful ignition delay time correlations were developed for temperatures greater than 1025 K. Comparisons are also made with available isobutane data from the literature, as well as with 100% n-butane and 50-50% n-butane-isobutane mixtures in air that were presented by the authors in recent studies. In general, the kinetic model shows excellent agreement with the data over the wide range of conditions of the present study. (author)

  5. Toluene pyrolysis studies and high temperature reactions of propargyl chloride

    SciTech Connect (OSTI)

    Kern, R.D.; Chen, H.; Qin, Z. [Univ. of New Orleans, LA (United States)

    1993-12-01

    The main focus of this program is to investigate the thermal decompositions of fuels that play an important role in the pre-particle soot formation process. It has been demonstrated that the condition of maximum soot yield is established when the reaction conditions of temperature and pressure are sufficient to establish a radical pool to support the production of polyaromatic hydrocarbon species and the subsequent formation of soot particles. However, elevated temperatures result in lower soot yields which are attributed to thermolyses of aromatic ring structures and result in the bell-shaped dependence of soot yield on temperature. The authors have selected several acyclic hydrocarbons to evaluate the chemical thermodynamic and kinetic effects attendant to benzene formation. To assess the thermal stability of the aromatic ring, the authors have studied the pyrolyses of benzene, toluene, ethylbenzene, chlorobenzene and pyridine. Time-of-flight mass spectrometry (TOF) is employed to analyze the reaction zone behind reflected shock waves. Reaction time histories of the reactants, products, and intermediates are constructed and mechanisms are formulated to model the experimental data. The TOF work is often performed with use of laser schlieren densitometry (LS) to measure density gradients resulting from the heats of various reactions involved in a particular pyrolytic system. The two techniques, TOF and LS, provide independent and complementary information about ring formation and ring rupture reactions.

  6. Polymer nanocomposites for high-temperature composite repair

    SciTech Connect (OSTI)

    Sheng, Xia

    2008-12-01

    A novel repair agent for resin-injection repair of advanced high temperature composites was developed and characterized. The repair agent was based on bisphenol E cyanate ester (BECy) and reinforced with alumina nanoparticles. To ensure good dispersion and compatibility with the BECy matrix in nanocomposites, the alumina nanoparticles were functionalized with silanes. The BECy nanocomposites, containing bare and functionalized alumina nanoparticles, were prepared and evaluated for their thermal, mechanical, rheological, and viscoelastic properties. The monomer of BECy has an extremely low viscosity at ambient temperature, which is good for processability. The cured BECy polymer is a highly cross-linked network with excellent thermal mechanical properties, with a high glass transition temperature (T{sub g}) of 270 C and decomposition temperature above 350 C. The incorporation of alumina nanoparticles enhances the mechanical and rheological properties of the BECy nanocomposites. Additionally, the alumina nanoparticles are shown to catalyze the cure of BECy. Characterization of the nanocomposites included dynamic mechanical analysis, differential scanning calorimetry, thermogravimetric analysis, rheological and rheokinetic evaluation, and transmission electron microscopy. The experimental results show that the BECy nanocomposite is a good candidate as repair agent for resin-injection repair applications.

  7. Optimum Reactor Outlet Temperatures for High Temperature Gas-Cooled Reactors Integrated with Industrial Processes

    SciTech Connect (OSTI)

    Lee O. Nelson

    2011-04-01

    This report summarizes the results of a temperature sensitivity study conducted to identify the optimum reactor operating temperatures for producing the heat and hydrogen required for industrial processes associated with the proposed new high temperature gas-cooled reactor. This study assumed that primary steam outputs of the reactor were delivered at 17 MPa and 540°C and the helium coolant was delivered at 7 MPa at 625–925°C. The secondary outputs of were electricity and hydrogen. For the power generation analysis, it was assumed that the power cycle efficiency was 66% of the maximum theoretical efficiency of the Carnot thermodynamic cycle. Hydrogen was generated via the hightemperature steam electrolysis or the steam methane reforming process. The study indicates that optimum or a range of reactor outlet temperatures could be identified to further refine the process evaluations that were developed for high temperature gas-cooled reactor-integrated production of synthetic transportation fuels, ammonia, and ammonia derivatives, oil from unconventional sources, and substitute natural gas from coal.

  8. Sealed glass coating of high temperature ceramic superconductors

    DOE Patents [OSTI]

    Wu, W.; Chu, C.Y.; Goretta, K.C.; Routbort, J.L.

    1995-05-02

    A method and article of manufacture of a lead oxide based glass coating on a high temperature superconductor is disclosed. The method includes preparing a dispersion of glass powders in a solution, applying the dispersion to the superconductor, drying the dispersion before applying another coating and heating the glass powder dispersion at temperatures below oxygen diffusion onset and above the glass melting point to form a continuous glass coating on the superconductor to establish compressive stresses which enhance the fracture strength of the superconductor. 8 figs.

  9. Support for Cost Analyses on Solar-Driven High Temperature Thermochemi...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Support for Cost Analyses on Solar-Driven High Temperature Thermochemical Water-Splitting Cycles Support for Cost Analyses on Solar-Driven High Temperature Thermochemical...

  10. A Discussion of Conductivity Testing in High Temperature Membranes (lessons learned in assessing transport)

    Broader source: Energy.gov [DOE]

    Presentation on conductivity testing in high temperature membranes given by Jim Boncella of Los Alamos National Laboratory at the High Temperature Membrane Working Group meeting in October 2005.

  11. CARISMA: A Networking Project for High Temperature PEMFC MEA Activities in Europe

    Office of Energy Efficiency and Renewable Energy (EERE)

    This presentation on high temperature proton exchange membrane fuel cells was given at the High Temperature Membrane Working Group Meeting in May 2007.

  12. Thermal Conductivity Enhancement of High Temperature Phase Change Materials for Concentrating Solar Power Plant Applications

    E-Print Network [OSTI]

    Roshandell, Melina

    2013-01-01

    that can operate with Stirling engines at 42% efficiency andfor high temperature Stirling engines which operates at 42%turbines such as Stirling engines, while high-temperature (>

  13. High-Temperature Zirconia Oxygen Sensor with Sealed Metal/Metal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference...

  14. Universal Membrane Classification Scheme: Maximizing the Return on High Temperature PEM Membrane Research

    Broader source: Energy.gov [DOE]

    This presentation on maximizing the return of high temperature PEM membrane research was given at the High Temperature Membrane Working Group Meeting in May 2007.

  15. High-Temperature Thermoelectric Characterization of III–V Semiconductor Thin Films by Oxide Bonding

    E-Print Network [OSTI]

    2010-01-01

    High-Temperature Thermoelectric Characterization of III–Vfor high-temperature thermoelectric charac- terization ofdiffusion barrier. A thermoelectric material, thin-?lm ErAs:

  16. Growth of Highly-Oriented Carbon Nanotubes by Plasma-Enhanced Hot Filament Chemical Vapor Deposition

    SciTech Connect (OSTI)

    Huang, Z.P.; Provencio, P.N.; Ren, Z.F.; Siegal, M.P.; Wang, J.H.; Xu, J.W.

    1998-10-11

    Highly-oriented, multi-walled carbon nanotubes were grown on polished polycrystalline and single crystal nickel substrates by plasma enhanced hot filament chemical vapor deposition at temperatures below 666"C. The carbon nanotubes range from 10 to 500 nm in diameter and 0.1 to 50 pm in length depending on growth conditions. Acetylene is used as the carbon source for the growth of the carbon nanotubes and ammonia is used for dilution gas and catalysis. The plasma intensity, acetylene to ammonia gas ratio and their flow rates, etc. affect the diameters and uniformity of the carbon nanotubes. In summary, we synthesized large-area highly-oriented carbon nanotubes at temperatures below 666C by plasma-enhanced hot filament chemical vapor deposition. Acetylene gas is used to provide carbon for nanotube growth and ammonia gas is used for dilution and catalysis. Plasma intensity is critical in determining the nanotube aspect ratios (diameter and length), and range of both site and height distributions within a given film.

  17. 9 Cr-- 1 Mo steel material for high temperature application

    DOE Patents [OSTI]

    Jablonski, Paul D; Alman, David; Dogan, Omer; Holcomb, Gordon; Cowen, Christopher

    2012-11-27

    One or more embodiments relates to a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650.degree. C. The 9 Cr-1 Mo steel has a tempered martensite microstructure and is comprised of both large (0.5-3 .mu.m) primary titanium carbides and small (5-50 nm) secondary titanium carbides in a ratio of. from about 1:1.5 to about 1.5:1. The 9 Cr-1 Mo steel may be fabricated using exemplary austenizing, rapid cooling, and tempering steps without subsequent hot working requirements. The 9 Cr-1 Mo steel exhibits improvements in total mass gain, yield strength, and time-to-rupture over ASTM P91 and ASTM P92 at the temperature and time conditions examined.

  18. LX-17 Deflagration at High Pressures and Temperatures

    SciTech Connect (OSTI)

    Koerner, J; Maienschein, J; Black, K; DeHaven, M; Wardell, J

    2006-10-23

    We measure the laminar deflagration rate of LX-17 (92.5 wt% TATB, 7.5 wt% Kel-F 800) at high pressure and temperature in a strand burner, thereby obtaining reaction rate data for prediction of thermal explosion violence. Simultaneous measurements of flame front time-of-arrival and temporal pressure history allow for the direct calculation of deflagration rate as a function of pressure. Additionally, deflagrating surface areas are calculated in order to provide quantitative insight into the dynamic surface structure during deflagration and its relationship to explosion violence. Deflagration rate data show that LX-17 burns in a smooth fashion at ambient temperature and is represented by the burn rate equation B = 0.2P{sup 0.9}. At 225 C, deflagration is more rapid and erratic. Dynamic deflagrating surface area calculations show that ambient temperature LX-17 deflagrating surface areas remain near unity over the pressure range studied.

  19. High Temperature Gas-Cooled Reactor Projected Markets and Preliminary Economics

    SciTech Connect (OSTI)

    Larry Demick

    2011-08-01

    This paper summarizes the potential market for process heat produced by a high temperature gas-cooled reactor (HTGR), the environmental benefits reduced CO2 emissions will have on these markets, and the typical economics of projects using these applications. It gives examples of HTGR technological applications to industrial processes in the typical co-generation supply of process heat and electricity, the conversion of coal to transportation fuels and chemical process feedstock, and the production of ammonia as a feedstock for the production of ammonia derivatives, including fertilizer. It also demonstrates how uncertainties in capital costs and financial factors affect the economics of HTGR technology by analyzing the use of HTGR technology in the application of HTGR and high temperature steam electrolysis processes to produce hydrogen.

  20. High temperature solar thermal technology: The North Africa Market

    SciTech Connect (OSTI)

    Not Available

    1990-12-01

    High temperature solar thermal (HTST) technology offers an attractive option for both industrialized and non-industrialized countries to generate electricity and industrial process steam. The purpose of this report is to assess the potential market for solar thermal applications in the North African countries of Algeria, Egypt, Morocco and Tunisia. North Africa was selected because of its outstanding solar resource base and the variety of applications to be found there. Diminishing oil and gas resources, coupled with expanding energy needs, opens a large potential market for the US industry. The US high temperature solar trough industry has little competition globally and could build a large market in these areas. The US is already familiar with certain solar markets in North Africa due to the supplying of substantial quantities of US-manufactured flat plate collectors to this region.

  1. Theory of intertwined orders in high temperature superconductors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fradkin, Eduardo; Tranquada, John M.; Kivelson, Steven A.

    2015-03-26

    The electronic phase diagrams of many highly correlated systems, and in particular the cuprate high temperature superconductors, are complex, with many different phases appearing with similar—sometimes identical—ordering temperatures even as material properties, such as a dopant concentration, are varied over wide ranges. This complexity is sometimes referred to as “competing orders.” However, since the relation is intimate, and can even lead to the existence of new phases of matter such as the putative “pair-density-wave,” the general relation is better thought of in terms of “intertwined orders.” We selectively analyze some of the experiments in the cuprates which suggest that essentialmore »aspects of the physics are reflected in the intertwining of multiple orders—not just in the nature of each order by itself. We also summarize and critique several theoretical ideas concerning the origin and implications of this complexity.« less

  2. Iron aluminide alloys with improved properties for high temperature applications

    DOE Patents [OSTI]

    McKamey, Claudette G. (Knoxville, TN); Liu, Chain T. (Oak Ridge, TN)

    1990-01-01

    An improved iron aluminide alloy of the DO.sub.3 type that has increased room temperature ductility and improved high elevated temperature strength. The alloy system further is resistant to corrosive attack in the environments of advanced energy corrosion systems such as those using fossil fuels. The resultant alloy is relatively inexpensive as contrasted to nickel based and high nickel steels currently utilized for structural components. The alloy system consists essentially of 26-30 at. % aluminum, 0.5-10 at. % chromium, 0.02-0.3 at. % boron plus carbon, up to 2 at. % molybdenum, up to 1 at. % niobium, up to 0.5 at. % zirconium, up to 0.1 at. % yttrium, up to 0.5 at. % vanadium and the balance iron.

  3. Iron aluminide alloys with improved properties for high temperature applications

    DOE Patents [OSTI]

    McKamey, C.G.; Liu, C.T.

    1990-10-09

    An improved iron aluminide alloy of the DO[sub 3] type is described that has increased room temperature ductility and improved high elevated temperature strength. The alloy system further is resistant to corrosive attack in the environments of advanced energy conversion systems such as those using fossil fuels. The resultant alloy is relatively inexpensive as contrasted to nickel based and high nickel steels currently utilized for structural components. The alloy system consists essentially of 26--30 at. % aluminum, 0.5--10 at. % chromium, 0.02--0.3 at. % boron plus carbon, up to 2 at. % molybdenum, up to 1 at. % niobium, up to 0.5 at. % zirconium, up to 0.1 at. % yttrium, up to 0.5 at. % vanadium and the balance iron. 3 figs.

  4. Theory of intertwined orders in high temperature superconductors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fradkin, Eduardo [Univ. of Illinois at Urbana-Champaign, Urbana, IL (United States); Tranquada, John M. [Brookhaven National Lab. (BNL), Upton, NY (United States); Kivelson, Steven A. [Stanford Univ., Stanford, CA (United States)

    2015-05-01

    The electronic phase diagrams of many highly correlated systems, and in particular the cuprate high temperature superconductors, are complex, with many different phases appearing with similar—sometimes identical—ordering temperatures even as material properties, such as a dopant concentration, are varied over wide ranges. This complexity is sometimes referred to as “competing orders.” However, since the relation is intimate, and can even lead to the existence of new phases of matter such as the putative “pair-density-wave,” the general relation is better thought of in terms of “intertwined orders.” We selectively analyze some of the experiments in the cuprates which suggest that essential aspects of the physics are reflected in the intertwining of multiple orders—not just in the nature of each order by itself. We also summarize and critique several theoretical ideas concerning the origin and implications of this complexity.

  5. Chemical distribution in high-solids paint overspray aerosols

    SciTech Connect (OSTI)

    D'Arcy, J.B.; Chan, T.L. )

    1990-03-01

    The chemical composition of high-solids basecoat paint overspray aerosols was determined as a function of particle size. Detailed information on the chemical composition of the overspray aerosols is important in health hazard evaluation since the composition and distribution within the airborne particles may differ significantly from the bulk paint material. This study was conducted in a typical down-draft paint booth equipped with air-atomized spray painting equipment. A fixed paint target was used to simulate typical overspray generation conditions and the aerosols were collected isokinetically with a seven-stage cascade impactor for size-fractionated analysis. The overspray aerosol from six paints consisted of organic paint binders with varying amounts of inorganic species as pigments or luster enhancers. These overspray aerosols had mass median aerodynamic diameters (MMAD) ranging from 2.9 to 9.7 microns. The size-fractionated paint samples collected on the impaction stages were analyzed by energy dispersive X-ray spectrometry on a scanning electron microscope (SEM-EDXRS) to identify the metallic elements. Atomic absorption spectrometry was used to determine the mass distribution of aluminum and iron as indicators of nonuniform distribution. Three of the aerosols containing aluminum were found to have bimodal distributions with most aluminum distributions having cumulative MMADs larger than the total aerosol. Iron in the aerosols was bimodal for three of the paints with all samples having an overall iron MMAD less than or equal to the overspray aerosol MMAD. Analysis using ultraviolet spectrometry revealed that the organic compounds present in the size-fractionated particulate samples consisted of a single, polydispersed mode with an MMAD similar to that of the total overspray aerosol.

  6. Volume 107, number 3 CHEMICAL PHYSICS LETTERS 1 June 1984 UNEQUAL FREEZiNG AND MELTING TEMPERATURES FOR CLUSTERS

    E-Print Network [OSTI]

    Berry, R. Stephen

    Volume 107, number 3 CHEMICAL PHYSICS LETTERS 1 June 1984 UNEQUAL FREEZiNG AND MELTING TEMPERATURES have sharp freezing and melting temperatures limiting the ranges of phase stability and thaf to exhibit sharp freezing tem- peratures Tr- below which no hquid-me form may exist, and sharp melting

  7. High temperature superconductivity in metallic region near Mott transition

    E-Print Network [OSTI]

    Tian De Cao

    2009-09-11

    The spin-singlet superconductivity without phonons is examined in consideration of correlations on an extended Hubbard model. It is shown that the superconductivity requires not only the total correlation should be strong enough but also the density of state around Fermi energy should be large enough, which shows that the high temperature superconductivity could only be found in the metallic region near the Mott metal insulator transition (MIT). Other properties of superconductors are also discussed on these conclusions.

  8. High-Temperature Downhole Tools | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas: Energy Resources Jump to:Hershey,High-Temperature Downhole Tools Jump to:

  9. Microstructure, Processing, Performance Relationships for High Temperature Coatings

    SciTech Connect (OSTI)

    Thomas M. Lillo

    2011-04-01

    This work evaluates the suitability of iron aluminide coatings for use in high temperature fossil fuel combustion environments, such as boiler applications. The coatings are applied using High Velocity Oxy-Fuel (HVOF) thermal spray techniques. Iron aluminide coatings, with the nominal composition of Fe3Al, were applied to various high temperature structural materials (316 Stainless Steel, 9Cr-1Mo steel and Inconel 600) that typically lack inherent resistance to environmental degradation found in fossil fuel combustion atmospheres. Coating/substrate combinations were subjected to thermal cycling to evaluate the effect of HVOF parameters, coating thickness, substrate material and substrate surface roughness on the resistance to coating delamination and cracking. It was found that substrate surface roughness had a profound influence on the performance of a given substrate/coating system and that surface preparation techniques will need to be tailored to the specific substrate material. Also, higher particle velocity during HVOF thermal spray deposition of the iron aluminide coatings tended to result in better-performing coating/substrate systems with less delamination at the coating/substrate interface. Some combinations of HVOF parameters, coating thickness and substrate materials were found to perform extremely well even at temperatures up to 900oC. However, in some cases, substantial reactions at the interface were observed.

  10. Improved Durability of SOEC Stacks for High Temperature Electrolysis

    SciTech Connect (OSTI)

    James E. O'Brien; Robert C. O'Brien; Xiaoyu Zhang; Joseph J. Hartvigsen; Greg Tao

    2013-01-01

    High temperature steam electrolysis is a promising technology for efficient and sustainable large-scale hydrogen production. Solid oxide electrolysis cells (SOECs) are able to utilize high temperature heat and electric power from advanced high-temperature nuclear reactors or renewable sources to generate carbon-free hydrogen at large scale. However, long term durability of SOECs needs to be improved significantly before commercialization of this technology can be realized. A degradation rate of 1%/khr or lower is proposed as a threshold value for commercialization of this technology. Solid oxide electrolysis stack tests have been conducted at Idaho National Laboratory to demonstrate recent improvements in long-term durability of SOECs. Electrolyte-supported and electrode-supported SOEC stacks were provided by Ceramatec Inc. and Materials and Systems Research Inc. (MSRI), respectively, for these tests. Long-term durability tests were generally operated for a duration of 1000 hours or more. Stack tests based on technologies developed at Ceramatec and MSRI have shown significant improvement in durability in the electrolysis mode. Long-term degradation rates of 3.2%/khr and 4.6%/khr were observed for MSRI and Ceramatec stacks, espectively. One recent Ceramatec stack even showed negative degradation (performance improvement) over 1900 hours of operation. Optimization of electrode materials, interconnect coatings, and electrolyte-electrode interface microstructures contribute to better durability of SOEC stacks.

  11. High Temperature Fuel Cell Performance High Temperature Fuel Cell Performance of of Sulfonated Sulfonated Poly(phenylene Poly(phenylene) Proton) Proton Conducting Conducting Polymers

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation by Sandia National Laboratories to the High Temperature Membrane Working Group Meeting held in Honolulu, Hawaii October 8, 2004.

  12. NREL Particle Receiver Will Enable High-Temperature CSP (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-08-01

    Near-blackbody enclosed particle receiver can support high-temperature thermal energy storage and high-efficiency power cycles.

  13. High-temperature Hydrogen Permeation in Nickel Alloys

    SciTech Connect (OSTI)

    P. Calderoni; M. Ebner; R. Pawelko

    2010-10-01

    In gas cooled Very High Temperature Reactor concepts, tritium is produced as a tertiary fission product and by activation of graphite core contaminants, such as lithium; of the helium isotope, He-3, that is naturally present in the He gas coolant; and the boron in the B4C burnable poison. Because of its high mobility at the reactor outlet temperatures, tritium poses a risk of permeating through the walls of the intermediate heat exchanger (IHX) or steam generator (SG) systems, potentially contaminating the environment and in particular the hydrogen product when the reactor heat is utilized in connection with a hydrogen generation plant. An experiment to measure tritium permeation in structural materials at temperatures up to 1000 C has been constructed at the Idaho National Laboratory Safety and Tritium Applied Research (STAR) facility within the Next Generation Nuclear Plant program. The design is based on two counter flowing helium loops to represent heat exchanger conditions and was optimized to allow control of the materials surface condition and the investigation of the effects of thermal fatigue. In the ongoing campaign three nickel alloys are being considered because of their high-temperature creep properties, alloy 617, 800H and 230. This paper introduces the general issues related to tritium in the on-going assessment of gas cooled VHTR systems fission product transport and outlines the planned research activities in this area; outlines the features and capabilities of the experimental facility being operated at INL; presents and discusses the initial results of hydrogen permeability measurements in two of the selected alloys and compares them with the available database from previous studies.

  14. 11th Topical conference high-temperature plasma diagnostics. Book of abstracts

    SciTech Connect (OSTI)

    1996-06-01

    This report contains abstracts from the 11th topical conference on high-temperature plasma diagnostics.

  15. Minutes of the October 2008 Meeting of the High Temperature Membrane Working Group

    Broader source: Energy.gov [DOE]

    Meeting minutes of the High Temperature Membrane Working Group from October 16, 2008, in Honolulu, Hawaii.

  16. High temperature measurement using very high shutter speed to avoid image saturation

    SciTech Connect (OSTI)

    Ma, Zhen; Zhang, Yang

    2014-04-11

    This paper explores the adaptation of the two-colour principle to develop a high-speed colour temperature correlation system, which is able to cover a range of temperature that is challenging to achieve before. A colour digital camera has built in RGB filters. It is possible to measure the temperature from the ratio of intensity of the green and red pixels using the two-colour principle based on the expansion of the Plank’s radiation law. In this study, experiments were carried out using a temperature calibrated tungsten ribbon lamp which can be tuned to vary from 1300 to 2200°C. Using very high shutter speed and small aperture, the high-speed camera successfully captured the tungsten ribbon without image saturation at the full temperature scale. Tests have been carried out at different temperature and camera settings. The sensitivity and errors have been analysed, and experiment results demonstrate the potential of using very high shutter speed is available for measuring the temperature even beyond 2200°C.

  17. Low Energy Effective Theory of QCD at High Isospin Chemical Potential

    E-Print Network [OSTI]

    Cohen, Thomas D

    2015-01-01

    The goal of this paper is to arrive at a low energy effective theory of QCD with two massless flavors of quarks at very high isospin density and zero baryon density. In a seminal paper by Son and Stephanov in the year 2001, it was conjectured that the low energy dynamics of QCD with two light flavors at asymptotically high isospin density was described by that of a pure Yang-Mills effective Lagrangian. Since the existence of a first order deconfinement phase transition with increasing temperature is a feature of every pure SU(N) Yang-Mills theory with N greater than or equal to 3, the regime considered in this paper is also expected to exhibit a first order deconfinement phase transition with increasing temperature. However, the low energy constants(LEC) of this pure Yang-Mills theory have not been calculated till date. We calculate the LEC s for this effective theory which in turn enables us to calculate the critical temperature of the deconfinement transition as a function of the isospin chemical potential ...

  18. Radial convection of finite ion temperature, high amplitude plasma blobs

    SciTech Connect (OSTI)

    Wiesenberger, M. Kendl, A.; Madsen, J.

    2014-09-15

    We present results from simulations of seeded blob convection in the scrape-off-layer of magnetically confined fusion plasmas. We consistently incorporate high fluctuation amplitude levels and finite Larmor radius (FLR) effects using a fully nonlinear global gyrofluid model. This is in line with conditions found in tokamak scrape-off-layers (SOL) regions. Varying the ion temperature, the initial blob width, and the initial amplitude, we found an FLR dominated regime where the blob behavior is significantly different from what is predicted by cold-ion models. The transition to this regime is very well described by the ratio of the ion gyroradius to the characteristic gradient scale length of the blob. We compare the global gyrofluid model with a partly linearized local model. For low ion temperatures, we find that simulations of the global model show more coherent blobs with an increased cross-field transport compared to blobs simulated with the local model. The maximal blob amplitude is significantly higher in the global simulations than in the local ones. When the ion temperature is comparable to the electron temperature, global blob simulations show a reduced blob coherence and a decreased cross-field transport in comparison with local blob simulations.

  19. Test-Theory Correlation Study for an Ultra High Temperature Thrust Magnetic Bearing 

    E-Print Network [OSTI]

    Desireddy, Vijesh R.

    2010-01-14

    1000 lb-f of axial thrust load, when rotating at high speed, in a high temperature environment of 1000 0F. This high temperature magnetic bearing system would be used in high performance, high speed and high temperature applications like space vehicles...

  20. Microstructure, Processing, Performance Relationships for High Temperature Coatings

    SciTech Connect (OSTI)

    Thomas M. Lillo; Richard N. Wright; W. David Swank; D.C Haggard; Dennis C. Kunerth; Denis E. Clark

    2008-07-01

    HVOF coating have shown high resistance to corrosion in fossil energy applications and it is generally accepted that mechanical failure, e.g. cracking or spalling, ultimately will determine coating lifetime. The high velocity oxygen-fuel method (HVOF) of applying coatings is one of the most commercially viable and allows the control of various parameters including powder particle velocity and temperature which influence coating properties, such as residual stress, bond coat strength and microstructure. Methods of assessing the mechanical durability of coatings are being developed in order to explore the relationship between HVOF spraying parameters and the mechanical properties of the coating and coating bond strength. The room temperature mechanical strength, as well as the resistance of the coating to cracking/spalling during thermal transients, is of considerable importance. Eddy current, acoustic emission and thermal imaging methods are being developed to detect coating failure during thermal cycling tests and room temperature tensile tests. Preliminary results on coating failure of HVOF FeAl coatings on carbon steel, as detected by eddy current measurements during thermal cycling, are presented. The influence of HVOF coating parameters of iron aluminides - applied to more relevant structural steels, like 316 SS and Grade 91 steel, - on coating durability will be explored once reliable methods for identification of coating failure have been developed.

  1. Materials for the scavenging of hydrogen at high temperatures

    DOE Patents [OSTI]

    Shepodd, T.J.; Phillip, B.L.

    1997-04-29

    A hydrogen getter composition is described comprising a double or triple bonded hydrocarbon with a high melting point useful for removing hydrogen gas, to partial pressures below 0.01 torr, from enclosed spaces and particularly from vessels used for transporting or containing fluids at elevated temperatures. The hydrogen getter compositions disclosed herein and their reaction products will neither melt nor char at temperatures in excess of 100C. They possess significant advantages over conventional hydrogen getters, namely low risk of fire or explosion, no requirement for high temperature activation or operation, the ability to absorb hydrogen even in the presence of contaminants such as water, water vapor, common atmospheric gases and oil mists and are designed to be disposed within the confines of the apparatus. These getter materials can be mixed with binders, such as fluoropolymers, which permit the getter material to be fabricated into useful shapes and/or impart desirable properties such as water repellency or impermeability to various gases. 7 figs.

  2. Materials for the scavenging of hydrogen at high temperatures

    DOE Patents [OSTI]

    Shepodd, T.J.; Phillip, B.L.

    1997-12-30

    A hydrogen getter composition is described comprising a double or triple bonded hydrocarbon with a high melting point useful for removing hydrogen gas, to partial pressures below 0.01 torr, from enclosed spaces and particularly from vessels used for transporting or containing fluids at elevated temperatures. The hydrogen getter compositions disclosed herein and their reaction products will neither melt nor char at temperatures in excess of 100 C. They possess significant advantages over conventional hydrogen getters, namely low risk of fire or explosion, no requirement for high temperature activation or operation, the ability to absorb hydrogen even in the presence of contaminants such as water, water vapor, common atmospheric gases and oil mists and are designed to be disposed within the confines of the apparatus. These getter materials can be mixed with binders, such as fluoropolymers, which permit the getter material to be fabricated into useful shapes and/or impart desirable properties such as water repellency or impermeability to various gases. 7 figs.

  3. Low temperature high frequency coaxial pulse tube for space application

    SciTech Connect (OSTI)

    Charrier, Aurelia; Charles, Ivan; Rousset, Bernard; Duval, Jean-Marc [SBT, UMR-E CEA / UJF-Grenoble 1, INAC, 17, rue des Martyrs, Grenoble, F-38054 (France); Daniel, Christophe [CNES, 18, avenue Edouard Belin, Toulouse, F-31401 (France)

    2014-01-29

    The 4K stage is a critical step for space missions. The Hershel mission is using a helium bath, which is consumed day by day (after depletion, the space mission is over) while the Plank mission is equipped with one He4 Joule-Thomson cooler. Cryogenic chain without helium bath is a challenge for space missions and 4.2K Pulse-Tube working at high frequency (around 30Hz) is one option to take it up. A low temperature Pulse-Tube would be suitable for the ESA space mission EChO (Exoplanet Characterisation Observatory, expected launch in 2022), which requires around 30mW cooling power at 6K; and for the ESA space mission ATHENA (Advanced Telescope for High ENergy Astrophysics), to pre-cool the sub-kelvin cooler (few hundreds of mW at 15K). The test bench described in this paper combines a Gifford-McMahon with a coaxial Pulse-Tube. A thermal link is joining the intercept of the Pulse-Tube and the second stage of the Gifford-McMahon. This intercept is a separator between the hot and the cold regenerators of the Pulse-Tube. The work has been focused on the cold part of this cold finger. Coupled with an active phase shifter, this Pulse-Tube has been tested and optimized and temperatures as low as 6K have been obtained at 30Hz with an intercept temperature at 20K.

  4. Rotational Rehybridization and the High Temperature Phase of UC2

    SciTech Connect (OSTI)

    Wen, Xiaodong; Rudin, Sven P.; Batista, Enrique R.; Clark, David L.; Scuseria, Gustavo E.; Martin, Richard L.

    2012-12-03

    The screened hybrid approximation (HSE) of density functional theory (DFT) is used to examine the structural, optical, and electronic properties of the high temperature phase, cubic UC(2). This phase contains C(2) units with a computed C-C distance of 1.443 Ĺ which is in the range of a CC double bond; U is formally 4+, C(2) 4-. The closed shell paramagnetic state (NM) was found to lie lowest. Cubic UC(2) is found to be a semiconductor with a narrow gap, 0.4 eV. Interestingly, the C(2) units connecting two uranium sites can rotate freely up to an angle of 30°, indicating a hindered rotational solid. Ab-initio molecular dynamic simulations (HSE) show that the rotation of C(2) units in the low temperature phase (tetragonal UC(2)) occurs above 2000 K, in good agreement with experiment. The computed energy barrier for the phase transition from tetragonal UC(2) to cubic UC(2) is around 1.30 eV per UC(2). What is fascinating about this system is that at high temperature, the phase transformation to the cubic phase is associated with a rehybridization of the C atoms from sp to sp(3).

  5. Metal Hydrides for High-Temperature Power Generation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ronnebro, Ewa; Whyatt, Greg A.; Powell, Michael R.; Westman, Matthew P.; Zheng, Feng; Fang, Zhigang Zak

    2015-08-10

    Metal hydrides can be utilized for hydrogen storage and for thermal energy storage (TES) applications. By using TES with solar technologies, heat can be stored from sun energy to be used later which enables continuous power generation. We are developing a TES technology based on a dual-bed metal hydride system, which has a high-temperature (HT) metal hydride operating reversibly at 600-800°C to generate heat as well as a low-temperature (LT) hydride near room temperature that is used for hydrogen storage during sun hours until there is a need to produce electricity, such as during night time, a cloudy day, ormore »during peak hours. We proceeded from selecting a high-energy density, low-cost HT-hydride based on performance characterization on gram size samples, to scale-up to kilogram quantities and design, fabrication and testing of a 1.5kWh, 200kWh/m3 bench-scale TES prototype based on a HT-bed of titanium hydride and a hydrogen gas storage instead of a LT-hydride. COMSOL Multiphysics was used to make performance predictions for cylindrical hydride beds with varying diameters and thermal conductivities. Based on experimental and modeling results, a bench-scale prototype was designed and fabricated and we successfully showed feasibility to meet or exceed all performance targets.« less

  6. Oxygen Handling and Cooling Options in High Temperature Electrolysis Plants

    SciTech Connect (OSTI)

    Manohar S. Sohal; J. Stephen Herring

    2008-07-01

    Idaho National Laboratory is working on a project to generate hydrogen by high temperature electrolysis (HTE). In such an HTE system, safety precautions need to be taken to handle high temperature oxygen at ~830°C. This report is aimed at addressing oxygen handling in a HTE plant.. Though oxygen itself is not flammable, most engineering material, including many gases and liquids, will burn in the presence of oxygen under some favorable physicochemical conditions. At present, an absolute set of rules does not exist that can cover all aspects of oxygen system design, material selection, and operating practices to avoid subtle hazards related to oxygen. Because most materials, including metals, will burn in an oxygen-enriched environment, hazards are always present when using oxygen. Most materials will ignite in an oxygen-enriched environment at a temperature lower than that in air, and once ignited, combustion rates are greater in the oxygen-enriched environment. Even many metals, if ignited, burn violently in an oxygen-enriched environment. However, these hazards do not preclude the operations and systems involving oxygen. Oxygen can be safely handled and used if all the materials in a system are not flammable in the end-use environment or if ignition sources are identified and controlled. In fact, the incidence of oxygen system fires is reported to be low with a probability of about one in a million. This report is a practical guideline and tutorial for the safe operation and handling of gaseous oxygen in high temperature electrolysis system. The intent is to provide safe, practical guidance that permits the accomplishment of experimental operations at INL, while being restrictive enough to prevent personnel endangerment and to provide reasonable facility protection. Adequate guidelines are provided to govern various aspects of oxygen handling associated with high temperature electrolysis system to generate hydrogen. The intent here is to present acceptable oxygen standards and practices for minimum safety requirements. A summary of operational hazards, along with oxygen safety and emergency procedures, are provided.

  7. Sorbents for High Temperature Removal of Arsenic from Coal-Derived Synthesis Gas

    SciTech Connect (OSTI)

    Alptekin, G.O.; Copeland, R.; Dubovik, M.; Gershanovich, Y.

    2002-09-20

    Gasification technologies convert coal and other heavy feedstocks into synthesis gas feed streams that can be used in the production of a wide variety of chemicals, ranging from hydrogen through methanol, ammonia, acetic anhydride, dimethyl ether (DME), methyl tertiary butyl ether (MTBE), high molecular weight liquid hydrocarbons and waxes. Syngas can also be burned directly as a fuel in advanced power cycles to generate electricity with very high efficiency. However, the coal-derived synthesis gas contains a myriad of trace contaminants that may poison the catalysts that are used in the downstream manufacturing processes and may also be regulated in power plant emissions. Particularly, the catalysts used in the conversion of synthesis gas to methanol and other liquid fuels (Fischer-Tropsch liquids) have been found to be very sensitive to the low levels of poisons, especially arsenic, that are present in the synthesis gas from coal. TDA Research, Inc. (TDA) is developing an expendable high capacity, low-cost chemical absorbent to remove arsenic from coal-derived syngas. Unlike most of the commercially available sorbents that physically adsorb arsenic, TDA's sorbent operates at elevated temperatures and removes the arsenic through chemical reaction. The arsenic content in the coal gas stream is reduced to ppb levels with the sorbent by capturing and stabilizing the arsenic gas (As4) and arsenic hydrides (referred to as arsine, AsH3) in the solid state. To demonstrate the concept of high temperature arsenic removal from coal-derived syngas, we carried out bench-scale experiments to test the absorption capacity of a variety of sorbent formulations under representative conditions. Using on-line analysis techniques, we monitored the pre- and post-breakthrough arsine concentrations over different sorbent samples. Some of these samples exhibited pre-breakthrough arsine absorption capacity over 40% wt. (capacity is defined as lb of arsenic absorbed/lb of sorbent), while maintaining an arsine outlet concentration at less than 10 ppb.

  8. Advancing the Technology Base for High Temperature Hydrogen Membranes

    SciTech Connect (OSTI)

    Dye, Robert C.; Moss, Thomas S.

    1997-12-31

    High purity hydrogen is a critical component for at least two major industrial processes: 1) the refining of conventional steels and raw pig iron into low carbon steels and high purity iron used for high performance magnets in motors, generators, alternators, transformers, and etc.; and 2) refining metallurgical grade silicon to the high- purity, polycrystalline silicon used in fabricating single crystal silicon wafers for semiconductor manufacturing. In the process of producing low carbon iron products, CO and CO2 impurities prevent efficient removal of the carbon already in the raw iron. In the refining of metallurgical grade silicon, the presence of any impurity above the part-per- million level prevents the ultimate fabrication of the large scale single crystals that are essential to the semiconductor device. In a lesser magnitude role, high quality hydrogen is used in a variety of other processes, including specialty metals refining (e.g., iridium, osmium, palladium, platinum, and ruthenium) and R{ampersand}D in areas such as organic synthesis and development of certain types of fuel cells. In all of these applications, a high-temperature hydrogen membrane can provide a method for achieving a very high purity level of hydrogen in a manner that is more economical and/or more rugged than existing techniques.

  9. Controlled Chemistry Helium High Temperature Materials Test Loop

    SciTech Connect (OSTI)

    Richard N. WRight

    2005-08-01

    A system to test aging and environmental effects in flowing helium with impurity content representative of the Next Generation Nuclear Plant (NGNP) has been designed and assembled. The system will be used to expose microstructure analysis coupons and mechanical test specimens for up to 5,000 hours in helium containing potentially oxidizing or carburizing impurities controlled to parts per million levels. Impurity levels in the flowing helium are controlled through a feedback mechanism based on gas chromatography measurements of the gas chemistry at the inlet and exit from a high temperature retort containing the test materials. Initial testing will focus on determining the nature and extent of combined aging and environmental effects on microstructure and elevated temperature mechanical properties of alloys proposed for structural applications in the NGNP, including Inconel 617 and Haynes 230.

  10. Remote high-temperature insulatorless heat-flux gauge

    DOE Patents [OSTI]

    Noel, Bruce W. (Espanola, NM)

    1993-01-01

    A remote optical heat-flux gauge for use in extremely high temperature environments is described. This application is possible because of the use of thermographic phosphors as the sensing media, and the omission of the need for an intervening layer of insulator between phosphor layers. The gauge has no electrical leads, but is interrogated with ultraviolet or laser light. The luminescence emitted by the two phosphor layers, which is indicative of the temperature of the layers, is collected and analyzed in order to determine the heat flux incident on the surface being investigated. The two layers of thermographic phosphor must be of different materials to assure that the spectral lines collected will be distinguishable. Spatial heat-flux measurements can be made by scanning the light across the surface of the gauge.

  11. Remote high-temperature insulatorless heat-flux gauge

    DOE Patents [OSTI]

    Noel, B.W.

    1993-12-28

    A remote optical heat-flux gauge for use in extremely high temperature environments is described. This application is possible because of the use of thermographic phosphors as the sensing media, and the omission of the need for an intervening layer of insulator between phosphor layers. The gauge has no electrical leads, but is interrogated with ultraviolet or laser light. The luminescence emitted by the two phosphor layers, which is indicative of the temperature of the layers, is collected and analyzed in order to determine the heat flux incident on the surface being investigated. The two layers of thermographic phosphor must be of different materials to assure that the spectral lines collected will be distinguishable. Spatial heat-flux measurements can be made by scanning the light across the surface of the gauge. 3 figures.

  12. Development of high temperature superconductors for electric power applications

    SciTech Connect (OSTI)

    Schiff, N. [American Superconductor Corp., Westborough, MA (United States)

    1995-09-01

    The Nobel Prize-winning discovery in 1986 of a new family of superconductors that exhibited the property of no resistance at temperatures more than ten times greater than the traditional low temperature superconductors (LTS) currently used in MRI and high field magnets, made it possible to foresee a new era for the production, transmission and distribution of electrical power. Smaller, more efficient motors, generators, power cables, transformers, inductors, and superconducting magnetic energy storage (SMES) for power quality were applications immediately envisioned for these high temperature superconductors (HTS), promising enhanced capabilities and lower costs. Work also began on new product concepts, such as more effective fault current limiters for both transmission and distribution systems that could protect expensive hardware and avoid the cost of upgrading circuit breakers as system capacity is increased. The interest of industry and utilities has been increased by successful demonstrations of small-scale prototypes. Recent demonstrations include a one meter conductor for an underground transmission cable produced by American Superconductor which carried over 4,200 amps, a 5 hp synchronous motor produced by Reliance Electric Company, magnet systems which generated over 2 Tesla at temperatures over 20 Kelvin (K) by both American Superconductor Corporation (ASC) and Sumitomo Electric Industries. The Department of Energy, under the Superconductivity Partnership Initiative Program (SPI), recently funded four application development projects: a 100 hp HTS motor demonstration, design of a generator rotor, a fault current limiter for distribution systems, and a 30 meter HTS power transmission cable. This paper will review the progress in application development of HTS products. The specific benefits and costs associated with this technology in power applications will be examined.

  13. Enhanced High Temperature Performance of NOx Reduction Catalyst Materials

    SciTech Connect (OSTI)

    Gao, Feng; Kim, Do Heui; Luo, Jinyong; Muntean, George G.; Peden, Charles HF; Howden, Ken; Currier, Neal; Kamasamudram, Krishna; Kumar, Ashok; Li, Junhui; Stafford, Randy; Yezerets, Aleksey; Castagnola, Mario; Chen, Hai Ying; Hess, Howard ..

    2012-12-31

    Two primary NOx after-treatment technologies have been recognized as the most promising approaches for meeting stringent NOx emission standards for diesel vehicles within the Environmental Protection Agency’s (EPA’s) 2007/2010 mandated limits, NOx Storage Reduction (NSR) and NH3 selective catalytic reduction (SCR); both are, in fact being commercialized for this application. However, in looking forward to 2015 and beyond with expected more stringent regulations, the continued viability of the NSR technology for controlling NOx emissions from lean-burn engines such as diesels will require at least two specific, significant and inter-related improvements. First, it is important to reduce system costs by, for example, minimizing the precious metal content while maintaining, even improving, performance and long-term stability. A second critical need for future NSR systems, as well as for NH3 SCR, will be significantly improved higher and lower temperature performance and stability. Furthermore, these critically needed improvements will contribute significantly to minimizing the impacts to fuel economy of incorporating these after-treatment technologies on lean-burn vehicles. To meet these objectives will require, at a minimum an improved scientific understanding of the following things: i) the various roles for the precious and coinage metals used in these catalysts; ii) the mechanisms for these various roles; iii) the effects of high temperatures on the active metal performance in their various roles; iv) mechanisms for higher temperature NOx storage performance for modified and/or alternative storage materials; v) the interactions between the precious metals and the storage materials in both optimum NOx storage performance and long term stability; vi) the sulfur adsorption and regeneration mechanisms for NOx reduction materials; vii) materials degradation mechanisms in CHA-based NH3 SCR catalysts. The objective of this CRADA project between PNNL and Cummins, Inc. is to develop a fundamental understanding of the above-listed issues. Model catalysts that are based on literature formulations are the focus of the work being carried out at PNNL. In addition, the performance and stability of more realistic high temperature NSR catalysts, supplied by JM, are being studied in order to provide baseline data for the model catalysts that are, again, based on formulations described in the open literature. For this short summary, we will primarily highlight representative results from our recent studies of the stability of candidate high temperature NSR materials.

  14. Solar High Temperature Water-Splitting Cycle with Quantum Boost

    SciTech Connect (OSTI)

    Taylor, Robin; Davenport, Roger; Talbot, Jan; Herz, Richard; Genders, David; Symons, Peter; Brown, Lloyd

    2014-04-25

    A sulfur family chemical cycle having ammonia as the working fluid and reagent was developed as a cost-effective and efficient hydrogen production technology based on a solar thermochemical water-splitting cycle. The sulfur ammonia (SA) cycle is a renewable and sustainable process that is unique in that it is an all-fluid cycle (i.e., with no solids handling). It uses a moderate temperature solar plant with the solar receiver operating at 800°C. All electricity needed is generated internally from recovered heat. The plant would operate continuously with low cost storage and it is a good potential solar thermochemical hydrogen production cycle for reaching the DOE cost goals. Two approaches were considered for the hydrogen production step of the SA cycle: (1) photocatalytic, and (2) electrolytic oxidation of ammonium sulfite to ammonium sulfate in aqueous solutions. Also, two sub-cycles were evaluated for the oxygen evolution side of the SA cycle: (1) zinc sulfate/zinc oxide, and (2) potassium sulfate/potassium pyrosulfate. The laboratory testing and optimization of all the process steps for each version of the SA cycle were proven in the laboratory or have been fully demonstrated by others, but further optimization is still possible and needed. The solar configuration evolved to a 50 MW(thermal) central receiver system with a North heliostat field, a cavity receiver, and NaCl molten salt storage to allow continuous operation. The H2A economic model was used to optimize and trade-off SA cycle configurations. Parametric studies of chemical plant performance have indicated process efficiencies of ~20%. Although the current process efficiency is technically acceptable, an increased efficiency is needed if the DOE cost targets are to be reached. There are two interrelated areas in which there is the potential for significant efficiency improvements: electrolysis cell voltage and excessive water vaporization. Methods to significantly reduce water evaporation are proposed for future activities. Electrolysis membranes that permit higher temperatures and lower voltages are attainable. The oxygen half cycle will need further development and improvement.

  15. Power efficiency for very high temperature solar thermal cavity receivers

    DOE Patents [OSTI]

    McDougal, Allan R. (LaCanada-Flintridge, CA); Hale, Robert R. (Upland, CA)

    1984-01-01

    This invention is an improved solar energy cavity receiver for exposing materials and components to high temperatures. The receiver includes a housing having an internal reflective surface defining a cavity and having an inlet for admitting solar radiation thereto. A photothermal absorber is positioned in the cavity to receive radiation from the inlet. A reflective baffle is positioned between the absorber and the inlet to severely restrict the re-radiation of energy through the inlet. The front surface of the baffle defines a narrow annulus with the internal reflective surface of the housing. The front surface of the baffle is contoured to reflect incoming radiation onto the internal surface of the housing, from which it is reflected through the annulus and onto the front surface of the absorber. The back surface of the baffle intercepts infrared radiation from the front of the absorber. With this arrangement, a high percentage of the solar power input is retained in the cavity; thus, high internal temperatures are attained.

  16. Small, high frequency probe for internal magnetic field measurements in high temperature plasmas

    E-Print Network [OSTI]

    Washington at Seattle, University of

    temperature 50 eV , high density ( 1020 m 3 ) plasmas such as the field-reversed configuration FRC , it has eV , high density ( 1020 m 3 ) plasmas such as the field-reversed configuration FRC , it has be exposed to the plasma. An estimate of the limiting probe size for the FRC can be obtained from

  17. Comparison of diesel spray combustion in different high-temperature, high-pressure facilities.

    SciTech Connect (OSTI)

    Christiansen, Caspar; Hermant, Laurent; Malbec, Louis-Marie; Bruneaux, Gilles; Genzale, Caroline L.; Pickett, Lyle M.; Schramm, Jesper

    2010-05-01

    Diesel spray experiments at controlled high-temperature and high-pressure conditions offer the potential for an improved understanding of diesel combustion, and for the development of more accurate CFD models that will ultimately be used to improve engine design. Several spray chamber facilities capable of high-temperature, high-pressure conditions typical of engine combustion have been developed, but uncertainties about their operation exist because of the uniqueness of each facility. For the IMEM meeting, we describe results from comparative studies using constant-volume vessels at Sandia National Laboratories and IFP. Targeting the same ambient gas conditions (900 K, 60 bar, 22.8 kg/m{sup 3}, 15% oxygen) and sharing the same injector (common rail, 1500 bar, KS1.5/86 nozzle, 0.090 mm orifice diameter, n-dodecane, 363 K), we describe detailed measurements of the temperature and pressure boundary conditions at each facility, followed by observations of spray penetration, ignition, and combustion using high-speed imaging. Performing experiments at the same high-temperature, high-pressure operating conditions is an objective of the Engine Combustion Network (http://www.ca.sandia.gov/ECN/), which seeks to leverage the research capabilities and advanced diagnostics of all participants in the ECN. We expect that this effort will generate a high-quality dataset to be used for advanced computational model development at engine conditions.

  18. Electrical conductivity of wadsleyite at high temperatures and high pressures Lidong Dai a,b

    E-Print Network [OSTI]

    Electrical conductivity of wadsleyite at high temperatures and high pressures Lidong Dai a,b , Shun 2009 Editor: L. Stixrude Keywords: electrical conductivity wadsleyite oxygen fugacity frequency water The electrical conductivity of wadsleyite aggregates has been determined under the broad range of thermodynamic

  19. An Ising-Anderson model of localisation in high-temperature QCD

    E-Print Network [OSTI]

    Matteo Giordano; Tamas G. Kovacs; Ferenc Pittler

    2015-02-09

    We discuss a possible mechanism leading to localisation of the low-lying Dirac eigenmodes in high-temperature lattice QCD, based on the spatial fluctuations of the local Polyakov lines in the partially ordered configurations above $T_c$. This mechanism provides a qualitative explanation of the dependence of localisation on the temperature and on the lattice spacing, and also of the phase diagram of QCD with an imaginary chemical potential. To test the viability of this mechanism we propose a three-dimensional effective, Anderson-like model, mimicking the effect of the Polyakov lines on the quarks. The diagonal, on-site disorder is governed by a three-dimensional Ising-like spin model with continuous spins. Our numerical results show that localised modes are indeed present in the ordered phase of the Ising model, thus supporting the proposed mechanism for localisation in QCD.

  20. An Ising-Anderson model of localisation in high-temperature QCD

    E-Print Network [OSTI]

    Giordano, Matteo; Pittler, Ferenc

    2015-01-01

    We discuss a possible mechanism leading to localisation of the low-lying Dirac eigenmodes in high-temperature lattice QCD, based on the spatial fluctuations of the local Polyakov lines in the partially ordered configurations above $T_c$. This mechanism provides a qualitative explanation of the dependence of localisation on the temperature and on the lattice spacing, and also of the phase diagram of QCD with an imaginary chemical potential. To test the viability of this mechanism we propose a three-dimensional effective, Anderson-like model, mimicking the effect of the Polyakov lines on the quarks. The diagonal, on-site disorder is governed by a three-dimensional Ising-like spin model with continuous spins. Our numerical results show that localised modes are indeed present in the ordered phase of the Ising model, thus supporting the proposed mechanism for localisation in QCD.

  1. Spectroscopy and kinetics of combustion gases at high temperatures

    SciTech Connect (OSTI)

    Hanson, R.K.; Bowman, C.T. [Stanford Univ., CA (United States)

    1993-12-01

    This program involves two complementary activities: (1) development and application of cw ring dye laser absorption methods for sensitive detection of radical species and measurement of fundamental spectroscopic parameters at high temperatures; and (2) shock tube studies of reaction kinetics relevant to combustion. Species currently under investigation in the spectroscopic portion of the research include NO and CH{sub 3}; this has necessitated the continued operated at wavelengths in the range 210-230 nm. Shock tube studies of reaction kinetics currently are focussed on reactions involving CH{sub 3} radicals.

  2. Narrowband high temperature superconducting receiver for low frequency radio waves

    DOE Patents [OSTI]

    Reagor, David W. (Los Alamos, NM)

    2001-01-01

    An underground communicating device has a low-noise SQUID using high temperature superconductor components connected to detect a modulated external magnetic flux for outputting a voltage signal spectrum that is related to the varying magnetic flux. A narrow bandwidth filter may be used to select a portion of the voltage signal spectrum that is relatively free of power line noise to output a relatively low noise output signal when operating in a portion of the electromagnetic spectra where such power line noise exists. A demodulator outputs a communication signal, which may be an FM signal, indicative of a modulation on the modulated external magnetic flux.

  3. Evaluation of permanent magnets for high temperature operations 

    E-Print Network [OSTI]

    Van Hees, Elizabeth

    1985-01-01

    as 3H F = x. m. H- &x where x = the magnetic susceptibility, which is the magnetic moment, M, divided by H, the field strength. The partial differential, 3H/ax, is the field gradient of the magnet, and m is the mass of the sample. This equation... is to inves- tigate the relevent magnetic properties of commercially availalbe magnetic materials for prolonged use in a high temperature environment (200'C to 450'C). Such materials can be utilized in geothermal and petroleum well logging. A device...

  4. Conductor requirements for high-temperature superconducting utility power transformers

    SciTech Connect (OSTI)

    Pleva, E. F. [Waukesha Electric Systems, Waukesha, WI; Mehrotra, V. [Waukesha Electric Systems, Waukesha, WI; Schwenterly, S W [ORNL

    2010-01-01

    High-temperature superconducting (HTS) coated conductors in utility power transformers must satisfy a set of operating requirements that are driven by two major considerations-HTS transformers must be economically competitive with conventional units, and the conductor must be robust enough to be used in a commercial manufacturing environment. The transformer design and manufacturing process will be described in order to highlight the various requirements that it imposes on the HTS conductor. Spreadsheet estimates of HTS transformer costs allow estimates of the conductor cost required for an HTS transformer to be competitive with a similarly performing conventional unit.

  5. Control for monitoring thickness of high temperature refractory

    DOE Patents [OSTI]

    Caines, M.J.

    1982-11-23

    This invention teaches an improved monitoring device for detecting the changes in thickness of high-temperature refractory, the device consists of a probe having at least two electrically conductive generally parallel elements separated by a dielectric material. The probe is implanted or embedded directly in the refractory and is elongated to extend in line with the refractory thickness to be measured. Electrical inputs to the conductive elements provide that either or both the electrical conductance or capacitance can be found, so that charges over lapsed time periods can be compared in order to detect changes in the thickness of the refractory.

  6. High Temperature Materials Overview Richard Wright Idaho National Laboratory

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancing ProgramsDepartment of¡High HIGHof EnergyTemperature

  7. High Temperature Polymer Capacitor Dielectric Films | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancing ProgramsDepartment of¡High HIGHof EnergyTemperature2

  8. High Temperature Polymer Capacitor Dielectric Films | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancing ProgramsDepartment of¡High HIGHof EnergyTemperature21

  9. High Temperature Polymer Capacitor Dielectric Films | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12,ExecutiveFinancing ProgramsDepartment of¡High HIGHof EnergyTemperature210

  10. Microstructure, Processing, Performance Relationships for High Temperature Coatings

    SciTech Connect (OSTI)

    Thomas Lillo; Richard Wright

    2009-05-01

    HVOF coatings have shown high resistance to corrosion in fossil energy applications and it is generally accepted that mechanical failure, e.g. cracking or spalling, ultimately will determine coating lifetime. The high velocity oxygen-fuel method (HVOF) for applying coatings is one of the most commercially viable and allows the control of various parameters including powder particle velocity and temperature which influence coating properties, such as residual stress, bond coat strength and microstructure. The mechanical durability of coatings is being assessed using a dual eddy current coil method to monitor crack formation in real time during thermal cycling. Absolute impedence signals from two coils, which interrogate two different areas on the sample, are collected. Crack detection can be determined from the differential signal generated from these absolute signals. The coils are operated at two different frequencies, resulting in two differential signals used for crack detection. Currently this crack detection method is being used to elucidate the influence of thermal cycling temperature and coating thickness on cracking. Recent results (cycles to failure) will be presented for FeAl coatings thermally sprayed (HVOF) onto carbon steel to two coating thicknesses (160 microns and 250 microns thick) and subsequently cycled at temperatures up to 700oC. Thinner coatings exhibit greater resistance to cracking. Ultimately the resistance to cracking will be used to explore the relationship between HVOF spraying parameters, the mechanical properties of the coating and coating bond strength to develop optimized thermal spray parameters. To this end thermal spray coatings (FeAl and Fe3Al) have been applied to additional alloy substrates (Grade 91 steel, 316 SS, etc.) relevant to the fossil industry. Future plans also include a direct comparison to conventional weld overlay coatings currently used in the industry as well as exploration of new coatings. The room temperature mechanical strength and coating adhesion to the substrate is also of considerable importance. Eddy current methods are being developed to detect coating failure during room temperature tensile tests to optimize surface preparation as well as aid in the optimization of the HVOF thermal spray parameters.

  11. The Fuel Accident Condition Simulator (FACS) furnace system for high temperature performance testing of VHTR fuel

    SciTech Connect (OSTI)

    Paul A. Demkowicz; David V. Laug; Dawn M. Scates; Edward L. Reber; Lyle G. Roybal; John B. Walter; Jason M. Harp; Robert N. Morris

    2012-10-01

    The AGR-1 irradiation of TRISO-coated particle fuel specimens was recently completed and represents the most successful such irradiation in US history, reaching peak burnups of greater than 19% FIMA with zero failures out of 300,000 particles. An extensive post-irradiation examination (PIE) campaign will be conducted on the AGR-1 fuel in order to characterize the irradiated fuel properties, assess the in-pile fuel performance in terms of coating integrity and fission metals release, and determine the fission product retention behavior during high temperature safety testing. A new furnace system has been designed, built, and tested to perform high temperature accident tests. The Fuel Accident Condition Simulator furnace system is designed to heat fuel specimens at temperatures up to 2000 degrees C in helium while monitoring the release of volatile fission metals (e.g. Cs, Ag, Sr, and Eu), iodine, and fission gases (Kr, Xe). Fission gases released from the fuel to the sweep gas are monitored in real time using dual cryogenic traps fitted with high purity germanium detectors. Condensable fission products are collected on a plate attached to a water-cooled cold finger that can be exchanged periodically without interrupting the test. Analysis of fission products on the condensation plates involves dry gamma counting followed by chemical analysis of selected isotopes. This paper will describe design and operational details of the Fuel Accident Condition Simulator furnace system and the associated fission gas monitoring system, as well as preliminary system calibration results.

  12. Novel High Temperature Materials for In-Situ Sensing Devices

    SciTech Connect (OSTI)

    Florian Solzbacher; Anil Virkar; Loren Rieth; Srinivasan Kannan; Xiaoxin Chen; Hannwelm Steinebach

    2009-12-31

    The overriding goal of this project was to develop gas sensor materials and systems compatible with operation at temperatures from 500 to 700 C. Gas sensors operating at these temperatures would be compatible with placement in fossil-energy exhaust streams close to the combustion chamber, and therefore have advantages for process regulation, and feedback for emissions controls. The three thrusts of our work included investigating thin film gas sensor materials based on metal oxide materials and electroceramic materials, and also development of microhotplate devices to support the gas sensing films. The metal oxide materials NiO, In{sub 2}O{sub 3}, and Ga{sub 2}O{sub 3} were investigated for their sensitivity to H{sub 2}, NO{sub x}, and CO{sub 2}, respectively, at high temperatures (T > 500 C), where the sensing properties of these materials have received little attention. New ground was broken in achieving excellent gas sensor responses (>10) for temperatures up to 600 C for NiO and In{sub 2}O{sub 3} materials. The gas sensitivity of these materials was decreasing as temperatures increased above 500 C, which indicates that achieving strong sensitivities with these materials at very high temperatures (T {ge} 650 C) will be a further challenge. The sensitivity, selectivity, stability, and reliability of these materials were investigated across a wide range of deposition conditions, temperatures, film thickness, as using surface active promoter materials. We also proposed to study the electroceramic materials BaZr{sub (1-x)}Y{sub x}O{sub (3-x/2)} and BaCe{sub (2-x)}Ca{sub x}S{sub (4-x/2)} for their ability to detect H{sub 2}O and H{sub 2}S, respectively. This report focuses on the properties and gas sensing characteristics of BaZr{sub (1-x)}Y{sub x}O{sub (3-x/2)} (Y-doped BaZrO{sub 3}), as significant difficulties were encounter in generating BaCe{sub (2-x)}Ca{sub x}S{sub (4-x/2)} sensors. Significant new results were achieved for Y-doped BaZrO{sub 3}, including sensitivities of more than 60 atm{sup -1} for H{sub 2}O vapor at 400 C. These results were achieved despite significant difficulties with a strong Ba deficiency in the deposited films, and difficulties with stress in the targets and films. Ultimately, these films achieved good sensitivity, selectivity, and reliability in our gas sensing tests. The final thrust of our project was to develop microhotpates. We proposed the use of SiC thin films for the heater of the microhotplate, but despite extensive efforts we were not able to secure a reliable source of SiC. An alternative microhotplate architecture using SiO{sub 2} and Si{sub 3}N{sub 4} suspended membrane structures, and a polysilicon heater were developed, which could be fabricate at commercial MEMs foundries. These microhotplates were fabricated at Microtechnology Services Frankfurt (MSF) in Germany. The fabricated heaters were able to achieve temperatures > 600 C using {approx} 0.25 W, and when combined with In{sub 2}O{sub 3} films demonstrated sensor systems with sensor responses up to 50 for 25 ppm NO{sub x}, and time constants of less than 10 s.

  13. Damping in high-temperature superconducting levitation systems

    DOE Patents [OSTI]

    Hull, John R.

    2009-12-15

    Methods and apparatuses for improved damping in high-temperature superconducting levitation systems are disclosed. A superconducting element (e.g., a stator) generating a magnetic field and a magnet (e.g. a rotor) supported by the magnetic field are provided such that the superconducting element is supported relative to a ground state with damped motion substantially perpendicular to the support of the magnetic field on the magnet. Applying this, a cryostat housing the superconducting bearing may be coupled to the ground state with high damping but low radial stiffness, such that its resonant frequency is less than that of the superconducting bearing. The damping of the cryostat may be substantially transferred to the levitated magnetic rotor, thus, providing damping without affecting the rotational loss, as can be derived applying coupled harmonic oscillator theory in rotor dynamics. Thus, damping can be provided to a levitated object, without substantially affecting the rotational loss.

  14. Sequential high temperature reduction, low temperature hydrolysis for the regeneration of sulfated NOx trap catalysts

    SciTech Connect (OSTI)

    Kim, Do Heui; Kwak, Ja Hun; Wang, Xianqin; Szanyi, Janos; Peden, Charles HF

    2008-07-15

    We describe a new method that minimizes irreversible Pt sintering during the desulfation of sulfated Pt/BaO/Al2O3 lean NOx trap (LNT) catalysts. While it is known that the addition of H2O to H2 promotes desulfation, we find that the significant and irreversible Pt sintering arising from the presence of water is unavoidable. Control of precious metal sintering is considered to be one of the critical issues in the development of durable LNT catalysts. The new method described here is a sequential desulfation process: the first step is to reduce the sulfates with hydrogen only at higher temperatures to form BaS, followed by a treatment of the thus reduced sample with water at low to moderate temperatures to convert BaS to BaO and H2S. The data showed that Pt sintering was significantly inhibited due to the absence of H2O during the desulfation at high temperatures, and also demonstrates the similar NOx uptake with the desulfated sample cooperatively with H2 and H2O. Therefore, the sequential desulfation process may find applications in realistic systems to inhibit the irreversible sintering of the Pt in the lean NOx trap catalyst, leading to a longer catalyst life.

  15. Studies of nonlinear electrodynamics of high-temperature superconductors

    SciTech Connect (OSTI)

    Lam, Quan-Chiu H.

    1991-08-01

    Nonlinear electrodynamics of high-{Tc} superconductors are studied both theoretically and experimentally. For powdered samples, a novel model is presented in which the metallographically observed superconducting grains in the powder are modeled as superconducting current loops of various areas with weak links. Surprising harmonic generation behavior in an arc field, H{sub 1} cos({omega}t), is predicted by the model; the power at high harmonics show sharp dips almost periodic in a superposing dc magnetic field, revealing flux quantization in the prototype loops in the model. Such oscillation of the harmonic power in dc magnetic field P{sub nf}(H{sub dc}), is indeed experimentally observed in powdered YBa{sub 2}Cu{sub 3}O{sub 7}. Other experimental aspects also agree with model predictions. For bulk sintered cylindrical samples, a generalized critical state model is presented. In this model, the nonlinear electrodynamics are due to flux-pinning, somewhat similar to low-temperature type-II superconductors, but with a more generalized critical current densities' dependence on magnetic field -- J{sub c}(H){approximately}H{sub local}{sup -{beta}}, with {beta} being an adjustable parameter. Experiments in ac and dc magnetic fields on a sintered cylindrical rod of YBa{sub 2}Cu{sub 3}O{sub 7} yield unambiguous evidence of independent inter- and intragranular contributions to the complex harmonic permeability {tilde {mu}}{sub n} = {mu}{prime}{sub n} -i{mu}{double prime}{sub n}. Temperature- dependence measurements reveal that, while the intragranular supercurrents disappear at {Tc}{ge}91.2 K, the intergranular supercurrents disappear at T{ge}86.6 K. This result is, to our knowledge, the first clear measurement of the phase-locking temperature of the 3-D matrix formed by YBa{sub 2}Cu{sub 3}O{sub 7} grains, which are in electrical contact with one another through weak links.

  16. Studies of nonlinear electrodynamics of high-temperature superconductors

    SciTech Connect (OSTI)

    Lam, Quan-Chiu H.

    1991-08-01

    Nonlinear electrodynamics of high-{Tc} superconductors are studied both theoretically and experimentally. For powdered samples, a novel model is presented in which the metallographically observed superconducting grains in the powder are modeled as superconducting current loops of various areas with weak links. Surprising harmonic generation behavior in an arc field, H{sub 1} cos({omega}t), is predicted by the model; the power at high harmonics show sharp dips almost periodic in a superposing dc magnetic field, revealing flux quantization in the prototype loops in the model. Such oscillation of the harmonic power in dc magnetic field P{sub nf}(H{sub dc}), is indeed experimentally observed in powdered YBa{sub 2}Cu{sub 3}O{sub 7}. Other experimental aspects also agree with model predictions. For bulk sintered cylindrical samples, a generalized critical state model is presented. In this model, the nonlinear electrodynamics are due to flux-pinning, somewhat similar to low-temperature type-II superconductors, but with a more generalized critical current densities` dependence on magnetic field -- J{sub c}(H){approximately}H{sub local}{sup -{beta}}, with {beta} being an adjustable parameter. Experiments in ac and dc magnetic fields on a sintered cylindrical rod of YBa{sub 2}Cu{sub 3}O{sub 7} yield unambiguous evidence of independent inter- and intragranular contributions to the complex harmonic permeability {tilde {mu}}{sub n} = {mu}{prime}{sub n} -i{mu}{double_prime}{sub n}. Temperature- dependence measurements reveal that, while the intragranular supercurrents disappear at {Tc}{ge}91.2 K, the intergranular supercurrents disappear at T{ge}86.6 K. This result is, to our knowledge, the first clear measurement of the phase-locking temperature of the 3-D matrix formed by YBa{sub 2}Cu{sub 3}O{sub 7} grains, which are in electrical contact with one another through weak links.

  17. Exploring high temperature phenomena related to post-detonation using an electric arc

    SciTech Connect (OSTI)

    Dai, Z. R. Crowhurst, J. C.; Grant, C. D.; Knight, K. B.; Tang, V.; Chernov, A. A.; Cook, E. G.; Lotscher, J. P.; Hutcheon, I. D.

    2013-11-28

    We report a study of materials recovered from a uranium-containing plasma generated by an electric arc. The device used to generate the arc is capable of sustaining temperatures of an eV or higher for up to 100??s. Samples took the form of a 4??m-thick film deposited onto 8 pairs of 17??m-thick Cu electrodes supported on a 25??m-thick Kapton backing and sandwiched between glass plates. Materials recovered from the glass plates and around the electrode tips after passage of an arc were characterized using scanning and transmission electron microscopy. Recovered materials included a variety of crystalline compounds (e.g., UO{sub 2}, UC{sub 2}, UCu{sub 5},) as well as mixtures of uranium and amorphous glass. Most of the materials collected on the glass plates took the form of spherules having a wide range of diameters from tens of nanometers to tens of micrometers. The composition and size of the spherules depended on location, indicating different chemical and physical environments. A theoretical analysis we have carried out suggests that the submicron spherules presumably formed by deposition during the arc discharge, while at the same time the glass plates were strongly heated due to absorption of plasma radiation mainly by islands of deposited metals (Cu, U). The surface temperature of the glass plates is expected to have risen to ?2300?K thus producing a liquefied glass layer, likely diffusions of the deposited metals on the hot glass surface and into this layer were accompanied by chemical reactions that gave rise to the observed materials. These results, together with the compact scale and relatively low cost, suggest that the experimental technique provides a practical approach to investigate the complex physical and chemical processes that occur when actinide-containing material interacts with the environment at high temperature, for example, during fallout formation following a nuclear detonation.

  18. Low-temperature growth and orientational control in RuO{sub 2} thin films by metal-organic chemical vapor deposition

    SciTech Connect (OSTI)

    Bai, G.R.; Wang, A.; Foster, C.M.; Vetrone, J.; Patel, J.; Wu, X.

    1996-08-01

    For growth temperatures in the range of 275 C to 425 C, highly conductive RuO{sub 2} thin films with either (110)- or (101)-textured orientations have been grown by metal-organic chemical vapor deposition (MOCVD) on both SiO{sub 2}/Si(001) and Pt/Ti/SiO{sub 2}/Si(001) substrates. Both the growth temperature and growth rate were used to control the type and degree of orientational texture of the RuO{sub 2} films. In the upper part of this growth temperature range ({approximately} 350 C) and at a low growth rate (< 30 {angstrom}/min.), the RuO{sub 2} films favored a (110)-textured. In contrast, at the lower part of this growth temperature range ({approximately} 300 C) and at a high growth rate (> 30 {angstrom}/min.), the RuO{sub 2} films favored a (101)-textured. In contrast, a higher growth temperatures (> 425 C) always produced randomly-oriented polycrystalline films. For either of these low-temperature growth processes, the films produced were crack-free, well-adhered to the substrates, and had smooth, specular surfaces. Atomic force microscopy showed that the films had a dense microstructure with an average grain size of 50--80 nm and a rms. surface roughness of {approximately} 3--10 nm. Four-probe electrical transport measurements showed that the films were highly conductive with resistivities of 34--40 {micro}{Omega}-cm ({at} 25 C).

  19. A High Temperature Liquid Plasma Model of the Sun

    E-Print Network [OSTI]

    Robitaille, P M

    2004-01-01

    In this work, a liquid model of the Sun is presented wherein the entire solar mass is viewed as a high density/high energy plasma. This model challenges our current understanding of the densities associated with the internal layers of the Sun, advocating a relatively constant density, almost independent of radial position. The incompressible nature of liquids is advanced to prevent solar collapse from gravitational forces. The liquid plasma model of the Sun is a non-equilibrium approach, where nuclear reactions are free to occur throughout the solar mass. The primary means of addressing internal heat transfer are convection and conduction. As a result of the convective prodesses on the solar surface, the liquid model brings into question the established temperature of the solar photosphere by highlighting a violation of Kirchhoff's law of thermal emission. Along these lines, the model emphasizes that radiative emission is a surface phenomenon. Strong evidence is provided that the Sun is a high density/high en...

  20. Native Chemical Ligation at Asx-Cys, Glx-Cys: Chemical Synthesis and High-Resolution Xray Structure of ShK Toxin by Racemic Protein

    E-Print Network [OSTI]

    Bezanilla, Francisco

    Native Chemical Ligation at Asx-Cys, Glx-Cys: Chemical Synthesis and High-Resolution Xray Structure Supporting Information ABSTRACT: We have re-examined the utility of native chemical ligation at -Gln- mercaptophenylacetic acid (MPAA), native chemical ligation could be performed at -Gln-Cys- and Asn-Cys- sites without

  1. Fabrication of Tungsten-Rhenium Cladding materials via Spark Plasma Sintering for Ultra High Temperature Reactor Applications

    SciTech Connect (OSTI)

    Charit, Indrajit; Butt, Darryl; Frary, Megan; Carroll, Mark

    2012-11-05

    This research will develop an optimized, cost-effective method for producing high-purity tungsten-rhenium alloyed fuel clad forms that are crucial for the development of a very high-temperature nuclear reactor. The study will provide critical insight into the fundamental behavior (processing-microstructure- property correlations) of W-Re alloys made using this new fabrication process comprising high-energy ball milling (HEBM) and spark plasma sintering (SPS). A broader goal is to re-establish the U.S. lead in the research field of refractory alloys, such as W-Re systems, with potential applications in very high-temperature nuclear reactors. An essential long-term goal for nuclear power is to develop the capability of operating nuclear reactors at temperatures in excess of 1,000K. This capability has applications in space exploration and some special terrestrial uses where high temperatures are needed in certain chemical or reforming processes. Refractory alloys have been identified as being capable of withstanding temperatures in excess of 1,000K and are considered critical for the development of ultra hightemperature reactors. Tungsten alloys are known to possess extraordinary properties, such as excellent high-temperature capability, including the ability to resist leakage of fissile materials when used as a fuel clad. However, there are difficulties with the development of refractory alloys: 1) lack of basic experimental data on thermodynamics and mechanical and physical properties, and 2) challenges associated with processing these alloys.

  2. Reactor User Interface Technology Development Roadmaps for a High Temperature Gas-Cooled Reactor Outlet Temperature of 750 degrees C

    SciTech Connect (OSTI)

    Ian Mckirdy

    2010-12-01

    This report evaluates the technology readiness of the interface components that are required to transfer high-temperature heat from a High Temperature Gas-Cooled Reactor (HTGR) to selected industrial applications. This report assumes that the HTGR operates at a reactor outlet temperature of 750°C and provides electricity and/or process heat at 700°C to conventional process applications, including the production of hydrogen.

  3. Femtosecond Chemically Activated Reactions: Concept of Nonstatistical Activation at High Thermal Energies

    E-Print Network [OSTI]

    Kim, Sang Kyu

    Femtosecond Chemically Activated Reactions: Concept of Nonstatistical Activation at High Thermal Femtosecond chemical activation of reactions at very high thermal energies, much above the bond energy activation, collision-free, and temporally and spatially defined. Introduction Since the work in the 1920s

  4. OPTIMAL DESIGN OF A HIGH PRESSURE ORGANOMETALLIC CHEMICAL VAPOR DEPOSITION REACTOR

    E-Print Network [OSTI]

    OPTIMAL DESIGN OF A HIGH PRESSURE ORGANOMETALLIC CHEMICAL VAPOR DEPOSITION REACTOR K.J. BACHMANN simulations as a fundamental design tool in developing a new prototype high pressure organometallic chemical vapor deposition (HPOMCVD) reactor for use in thin film crystal growth. The advantages of such a reactor

  5. Development of Designer Diamond Technology for High-Pressure-High Temperature Experiments in Support of the Stockpile Stewardship

    SciTech Connect (OSTI)

    Vohra, Yogesh, K.

    2003-08-27

    OAK B127 Development of Designer Diamond Technology for High-Pressure-High Temperature Experiments in Support of the Stockpile Stewardship

  6. Bio-Fuel Production Assisted with High Temperature Steam Electrolysis

    SciTech Connect (OSTI)

    Grant Hawkes; James O'Brien; Michael McKellar

    2012-06-01

    Two hybrid energy processes that enable production of synthetic liquid fuels that are compatible with the existing conventional liquid transportation fuels infrastructure are presented. Using biomass as a renewable carbon source, and supplemental hydrogen from high-temperature steam electrolysis (HTSE), these two hybrid energy processes have the potential to provide a significant alternative petroleum source that could reduce dependence on imported oil. The first process discusses a hydropyrolysis unit with hydrogen addition from HTSE. Non-food biomass is pyrolyzed and converted to pyrolysis oil. The pyrolysis oil is upgraded with hydrogen addition from HTSE. This addition of hydrogen deoxygenates the pyrolysis oil and increases the pH to a tolerable level for transportation. The final product is synthetic crude that could then be transported to a refinery and input into the already used transportation fuel infrastructure. The second process discusses a process named Bio-Syntrolysis. The Bio-Syntrolysis process combines hydrogen from HTSE with CO from an oxygen-blown biomass gasifier that yields syngas to be used as a feedstock for synthesis of liquid synthetic crude. Conversion of syngas to liquid synthetic crude, using a biomass-based carbon source, expands the application of renewable energy beyond the grid to include transportation fuels. It can also contribute to grid stability associated with non-dispatchable power generation. The use of supplemental hydrogen from HTSE enables greater than 90% utilization of the biomass carbon content which is about 2.5 times higher than carbon utilization associated with traditional cellulosic ethanol production. If the electrical power source needed for HTSE is based on nuclear or renewable energy, the process is carbon neutral. INL has demonstrated improved biomass processing prior to gasification. Recyclable biomass in the form of crop residue or energy crops would serve as the feedstock for this process. A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to heat steam for the hydrogen production via the high temperature steam electrolysis process. Oxygen produced form the electrolysis process is used to control the oxidation rate in the oxygen-blown biomass gasifier.

  7. Air Cooling for High Temperature Power Electronics (Presentation)

    SciTech Connect (OSTI)

    Waye, S.; Musselman, M.; King, C.

    2014-09-01

    Current emphasis on developing high-temperature power electronics, including wide-bandgap materials such as silicon carbide and gallium nitride, increases the opportunity for a completely air-cooled inverter at higher powers. This removes the liquid cooling system for the inverter, saving weight and volume on the liquid-to-air heat exchanger, coolant lines, pumps, and coolant, replacing them with just a fan and air supply ducting. We investigate the potential for an air-cooled heat exchanger from a component and systems-level approach to meet specific power and power density targets. A proposed baseline air-cooled heat exchanger design that does not meet those targets was optimized using a parametric computational fluid dynamics analysis, examining the effects of heat exchanger geometry and device location, fixing the device heat dissipation and maximum junction temperature. The CFD results were extrapolated to a full inverter, including casing, capacitor, bus bar, gate driver, and control board component weights and volumes. Surrogate ducting was tested to understand the pressure drop and subsequent system parasitic load. Geometries that met targets with acceptable loads on the system were down-selected for experimentation. Nine baseline configuration modules dissipated the target heat dissipation, but fell below specific power and power density targets. Six optimized configuration modules dissipated the target heat load, exceeding the specific power and power density targets. By maintaining the same 175 degrees C maximum junction temperature, an optimized heat exchanger design and higher device heat fluxes allowed a reduction in the number of modules required, increasing specific power and power density while still maintaining the inverter power.

  8. Ultra high temperature ceramics for hypersonic vehicle applications.

    SciTech Connect (OSTI)

    Tandon, Rajan; Dumm, Hans Peter; Corral, Erica L.; Loehman, Ronald E.; Kotula, Paul Gabriel

    2006-01-01

    HfB{sub 2} and ZrB{sub 2} are of interest for thermal protection materials because of favorable thermal stability, mechanical properties, and oxidation resistance. We have made dense diboride ceramics with 2 to 20 % SiC by hot pressing at 2000 C and 5000 psi. High-resolution transmission electron microscopy (TEM) shows very thin grain boundary phases that suggest liquid phase sintering. Fracture toughness measurements give RT values of 4 to 6 MPam{sup 1/2}. Four-pt flexure strengths measured in air up to 1450 C were as high as 450-500 MPa. Thermal diffusivities were measured to 2000 C for ZrB{sub 2} and HfB{sub 2} ceramics with SiC contents from 2 to 20%. Thermal conductivities were calculated from thermal diffusivities and measured heat capacities. Thermal diffusivities were modeled using different two-phase composite models. These materials exhibit excellent high temperature properties and are attractive for further development for thermal protection systems.

  9. High-temperature zirconia insulation and method for making same

    DOE Patents [OSTI]

    Wrenn, G.E. Jr.; Holcombe, C.E. Jr.; Lewis, J. Jr.

    1988-05-10

    The present invention is directed to a highly pure, partially stabilized, fibrous zirconia composite for use as thermal insulation in environments where temperatures up to about 2,000 C are utilized. The composite of the present invention is fabricated into any suitable configuration such as a cone, cylinder, dome or the like by vacuum molding an aqueous slurry of partially stabilized zirconia fibers into a desired configuration on a suitably shaped mandrel. The molded fibers are infiltrated with zirconyl nitrate and the resulting structure is then dried to form a rigid structure which may be removed and placed in a furnace. The structure is then heated in air to a temperature of about 600 C for driving off the nitrate from the structure and for oxidizing the zirconyl ion to zirconia. Thereafter, the structure is heated to about 950 to 1,250 C to fuse the zirconia fibers at their nexi in a matrix of zirconia. The composite produced by the present invention is self-supporting and can be readily machined to desired final dimensions. Additional heating to about 1,800 to 2,000 C further improves structural rigidity.

  10. High-temperature zirconia insulation and method for making same

    DOE Patents [OSTI]

    Wrenn, Jr., George E. (Clinton, TN); Holcombe, Jr., Cressie E. (Knoxville, TN); Lewis, Jr., John (Oak Ridge, TN)

    1988-01-01

    The present invention is directed to a highly pure, partially stabilized, fibrous zirconia composite for use as thermal insulation in environments where temperatures up to about 2000.degree. C. are utilized. The composite of the present invention is fabricated into any suitable configuration such as a cone, cylinder, dome or the like by vacuum molding an aqueous slurry of partially stabilized zirconia fibers into a desired configuration on a suitably shaped mandrel. The molded fibers are infiltrated with zirconyl nitrate and the resulting structure is then dried to form a rigid structure which may be removed and placed in a furnace. The structure is then heated in air to a temperature of about 600.degree. C. for driving off the nitrate from the structure and for oxidizing the zirconyl ion to zirconia. Thereafter, the structure is heated to about 950.degree. to 1,250.degree. C. to fuse the zirconia fibers at their nexi in a matrix of zirconia. The composite produced by the present invention is self-supporting and can be readily machined to desired final dimensions. Additional heating to about 1800.degree. to 2000.degree. C. further improves structural rigidity.

  11. High temperature concrete composites containing organosiloxane crosslinked copolymers

    DOE Patents [OSTI]

    Zeldin, Arkady (Rego Park, NY); Carciello, Neal (Patchogue, NY); Kukacka, Lawrence (Port Jefferson, NY); Fontana, Jack (Shoreham, NY)

    1980-01-01

    This invention relates to high temperature polymer concrete composites comprising about 10-30% by weight of a liquid monomer mixture consisting essentially of an organosiloxane polymer crosslinked with an olefinically unsaturated monomer selected from the group consisting of styrene, methyl methacrylate, trimethylolpropane trimethacrylate, triallyl cyanurate, n-phenylmalimide, divinyl benzene and mixtures theroef; and about 70-90% by weight of an inert inorganic filler system containing silica sand and preferably a member selected from the group consisting of portland cement, Fe.sub.2 O.sub.3, carbon black and mixtures thereof; and optionally a free radical initiator such as di-tert-butyl peroxide, azobisisobutyronitrile, benzoyl peroxide, lauryl peroxide and other organic peroxides to initiate crosspolymerization of the monomer mixture in the presence of the inorganic filler.

  12. Application & testing of high temperature materials for solenoid coils

    SciTech Connect (OSTI)

    Sanchez, R.O.; Archer, W.E.; Zich, J.L.

    1997-08-01

    Sandia National Laboratories has designed and proven-in two new Solenoid coils for a highly-reliable electromechanical switch. Mil-Spec Magnetics Inc., Walnut CA manufactured the coils. The new design utilizes two new materials: Liquid Crystal Polymer (Vectra C130) for the bobbin and Thermal Barrier Silicone (VI-SIL V-658) for the encapsulant. The use of these two new materials solved most of the manufacturing problems inherent in the old Sandia design. The coils are easier to precision wind and more robust for handling, testing, and storage. The coils have some unique weapon related safety requirements. The most severe of these requirements is the 400{degrees}C, 1600 V test. The coils must not, and did not, produce any outgassing products to affect the voltage breakdown between contacts in the switch at these temperatures and voltages. Actual coils in switches were tested under these conditions. This paper covers the prove-in of this new coil design.

  13. Flexible high-temperature pH probe

    DOE Patents [OSTI]

    Bielawski, John C. (Scotia, NY); Outwater, John O. (Cambridge, MA); Halbfinger, George P. (Schenectady, NY)

    2003-04-22

    A flexible pH probe device is provided for use in hot water and other high temperature environments up to about 590.degree. F. The pH probe includes a flexible, inert tubular probe member, an oxygen anion conducting, solid state electrolyte plug located at the distal end of the tubular member, oxide powder disposed at the distal end of the tubular member; a metal wire extending along the tubular member and having a distal end in contact with the oxide powder so as to form therewith an internal reference electrode; and a compression fitting forming a pressure boundary seal around a portion of the tubular member remote from the distal end thereof. Preferably, the tubular member is made of polytetrafluoroethylene, and the solid state electrolyte plug is made of stabilized zirconia. The flexibility of the probe member enables placement of the electrode into the area of interest, including around corners, into confined areas and the like.

  14. High temperature seal for joining ceramics and metal alloys

    DOE Patents [OSTI]

    Maiya, P. Subraya (Darien, IL); Picciolo, John J. (Lockport, IL); Emerson, James E. (Plainfield, IL); Dusek, Joseph T. (Lombard, IL); Balachandran, Uthamalingam (Hinsdale, IL)

    1998-01-01

    For a combination of a membrane of SrFeCo.sub.0.5 O.sub.x and an Inconel alloy, a high-temperature seal is formed between the membrane and the alloy. The seal is interposed between the alloy and the membrane, and is a fritted compound of Sr oxide and boric oxide and a fritted compound of Sr, Fe and Co oxides. The fritted compound of SrFeCo.sub.0.50 O.sub.x is present in the range of from about 30 to 70 percent by weight of the total sealant material and the fritted compound of Sr oxide and boric oxide has a mole ratio of 2 moles of the Sr oxide for each mole of boric oxide. A method of sealing a ceramic to an Inconel metal alloy is also disclosed.

  15. Leaching behaviour of bottom ash from RDF high-temperature gasification plants

    SciTech Connect (OSTI)

    Gori, M.; Pifferi, L.; Sirini, P.

    2011-07-15

    This study investigated the physical properties, the chemical composition and the leaching behaviour of two bottom ash (BA) samples from two different refuse derived fuel high-temperature gasification plants, as a function of particle size. The X-ray diffraction patterns showed that the materials contained large amounts of glass. This aspect was also confirmed by the results of availability and ANC leaching tests. Chemical composition indicated that Fe, Mn, Cu and Cr were the most abundant metals, with a slight enrichment in the finest fractions. Suitability of samples for inert waste landfilling and reuse was evaluated through the leaching test EN 12457-2. In one sample the concentration of all metals was below the limit set by law, while limits were exceeded for Cu, Cr and Ni in the other sample, where the finest fraction showed to give the main contribution to leaching of Cu and Ni. Preliminary results of physical and geotechnical characterisation indicated the suitability of vitrified BA for reuse in the field of civil engineering. The possible application of a size separation pre-treatment in order to improve the chemical characteristics of the materials was also discussed.

  16. High strength porous support tubes for high temperature solid electrolyte electrochemical cells

    DOE Patents [OSTI]

    Rossing, Barry R. (Churchill, PA); Zymboly, Gregory E. (Penn Hills, PA)

    1986-01-01

    A high temperature, solid electrolyte electrochemical cell is made, having an electrode and a solid electrolyte disposed on a porous, sintered support material containing thermally stabilized zirconia powder particles and from about 3 wt. % to about 45 wt. % of thermally stable oxide fibers.

  17. Towards the development of high temperature comparison artifacts for radiation thermometry

    SciTech Connect (OSTI)

    Teixeira, R. N. [Inmetro, Duque de Caxias, RJ (Brazil)] [Inmetro, Duque de Caxias, RJ (Brazil); Machin, G. [NPL, Teddington (United Kingdom)] [NPL, Teddington (United Kingdom); Orlando, A. [PUC-Rio, Rio de Janeiro, RJ (Brazil)] [PUC-Rio, Rio de Janeiro, RJ (Brazil)

    2013-09-11

    This paper describes the methodology and first results of the development of high temperature fixed point artifacts of unknown temperature suitable for scale comparison purposes. This study is being undertaken at the Thermal Metrology Division of Inmetro, Brazil, as part of PhD studies. In this initial phase of the study two identical cobalt carbon eutectic cells were constructed and one doped with a known amount of copper. This was an attempt to achieve a controlled change in the transition temperature of the alloy during melting. Copper was chosen due to the relatively simple phase diagram it forms with carbon and cobalt. The cobalt, in powder form, was supplied by Alfa Aesar at 99.998 % purity, and was mixed with carbon powder (1,9 % by weight) of 99.9999 % purity. Complete filling of the crucible took 6 steps and was performed in a vertical furnace with graphite heating elements, in an inert gas atmosphere. The temperature measurements were performed using a KE LP3 radiation thermometer, which was previously evaluated for spectral responsivity, linearity and size-of-source effect (SSE). During these measurements, the thermometer stability was periodically checked using a silver fixed point blackbody maintained in a three zone furnace. The main purpose of the first part of this study is to dope a series of Co-C blackbody with differing amounts of copper, in order to alter their temperatures whilst still retaining good melting plateau performance. The long-term stability of the adjusted transition temperatures will also be investigated. Other dopants will be studied as the research progresses, and thermo chemical modeling will be performed in an attempt to understand the change in temperature with dopant concentration and so help select suitable dopants in the future. The overall objective is to construct comparison artifacts that have good performance, in terms of plateau shape and long-term temperature stability, but with unknown temperatures. These can then be used as comparison artifacts with no participant, except the pilot, knowing the temperature a priori.

  18. Chemical synthesis of monodisperse -FeNi magnetic nanoparticles with tunable Curie temperatures for self-regulated hyperthermia

    E-Print Network [OSTI]

    Laughlin, David E.

    magnetic field, MNPs in fer- rofluids dissipate heat via Néel and Brownian relaxation losses.3 Losses heating rate in ferrofluids is achievable for metallic nanoparticles having the largest satu- rationChemical synthesis of monodisperse -Fe­Ni magnetic nanoparticles with tunable Curie temperatures

  19. THE HIGH TEMPERATURE BEHAVIOR OF METALLIC INCLUSIONS IN URANIUM DIOXIDE.

    E-Print Network [OSTI]

    Yang, Rosa Lu.

    2010-01-01

    Products in Irradiated Uranium Dioxide," UKAEA Report AERE-OF METALLIC INCLUSIONS IN URANIUM DIOXIDE Rosa Lu Yang (Chemical State of Irradiated Uranium- Plutonium Oxide Fuel

  20. Cryogenic Heat Pipe for Cooling High Temperature Superconductors with Application to

    E-Print Network [OSTI]

    Cryogenic Heat Pipe for Cooling High Temperature Superconductors with Application;#12;Cryogenic Heat Pipe for Cooling High Temperature Superconductors with Application to Electromagnetic Superconductors with Application to Electromagnetic Formation Flight Satellites by Daniel W. Kwon Submitted

  1. Experimental investigation of sand consolidation using high-temperature alkaline solution 

    E-Print Network [OSTI]

    Moreno Romero, Fidel Enrique

    2000-01-01

    An experimental study was conducted to better understand the sand consolidation process under high-temperature alkaline solution. Wilmington Tar sand samples were successfully consolidated in the laboratory using high-temperature (250-260?C...

  2. Low-Temperature Combustion for High-Efficiency, Ultra-Low Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low-Temperature Combustion for High-Efficiency, Ultra-Low Emission Engines Low-Temperature Combustion for High-Efficiency, Ultra-Low Emission Engines Presentation given at DEER...

  3. New Polymeric Proton Conductors for Water-free and High-temperature Fuel Cells

    Broader source: Energy.gov [DOE]

    Presentation on New Polymeric Proton Conductors for Water-free and High-temperature Fuel Cells to the High Temperature Membrane Working Group Meeting held in Arlington, Virginia, May 26,2005.

  4. CF8C PLus: A New Cast Stainless Steel for High-Temperature Diesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CF8C PLus: A New Cast Stainless Steel for High-Temperature Diesel Exhaust Components CF8C PLus: A New Cast Stainless Steel for High-Temperature Diesel Exhaust Components...

  5. High Temperature/Low Humidity Polymer Electrolytes Derived from Ionic Liquids

    Broader source: Energy.gov [DOE]

    Presentation on High Temperature/Low Humidity Polymer Electrolytes Derived from Ionic Liquids to the High Temperature Membrane Working Group Meeting held in Arlington, Virginia, May 26,2005.

  6. High-Temperature High-Power Packaging Techniques for HEV Traction Applications

    SciTech Connect (OSTI)

    Barlow, F.D.; Elshabini, A.

    2006-11-30

    A key issue associated with the wider adoption of hybrid-electric vehicles (HEV) and plug in hybrid-electric vehicles (PHEV) is the implementation of the power electronic systems that are required in these products [1]. To date, many consumers find the adoption of these technologies problematic based on a financial analysis of the initial cost versus the savings available from reduced fuel consumption. Therefore, one of the primary industry goals is the reduction in the price of these vehicles relative to the cost of traditional gasoline powered vehicles. Part of this cost reduction must come through optimization of the power electronics required by these vehicles. In addition, the efficiency of the systems must be optimized in order to provide the greatest range possible. For some drivers, any reduction in the range associated with a potential HEV or PHEV solution in comparison to a gasoline powered vehicle represents a significant barrier to adoption and the efficiency of the power electronics plays an important role in this range. Likewise, high efficiencies are also important since lost power further complicates the thermal management of these systems. Reliability is also an important concern since most drivers have a high level of comfort with gasoline powered vehicles and are somewhat reluctant to switch to a less proven technology. Reliability problems in the power electronics or associated components could not only cause a high warranty cost to the manufacturer, but may also taint these technologies in the consumer's eyes. A larger vehicle offering in HEVs is another important consideration from a power electronics point of view. A larger vehicle will need more horsepower, or a larger rated drive. In some ways this will be more difficult to implement from a cost and size point of view. Both the packaging of these modules and the thermal management of these systems at competitive price points create significant challenges. One way in which significant cost reduction of these systems could be achieved is through the use of a single coolant loop for both the power electronics as well as the internal combustion engine (ICE) [2]. This change would reduce the complexity of the cooling system which currently relies on two loops to a single loop [3]. However, the current nominal coolant temperature entering these inverters is 65 C [3], whereas a normal ICE coolant temperature would be much higher at approximately 100 C. This change in coolant temperature significantly increases the junction temperatures of the devices and creates a number of challenges for both device fabrication and the assembly of these devices into inverters and converters for HEV and PHEV applications. With this change in mind, significant progress has been made on the use of SiC devices for inverters that can withstand much higher junction temperatures than traditional Si based inverters [4,5,6]. However, a key problem which the single coolant loop and high temperature devices is the effective packaging of these devices and related components into a high temperature inverter. The elevated junction temperatures that exist in these modules are not compatible with reliable inverters based on existing packaging technology. This report seeks to provide a literature survey of high temperature packaging and to highlight the issues related to the implementation of high temperature power electronic modules for HEV and PHEV applications. For purposes of discussion, it will be assumed in this report that 200 C is the targeted maximum junction temperature.

  7. Membrane Development for Medium and High Temperature PEMFC in Europe (Presentation)

    Broader source: Energy.gov [DOE]

    Presented at the High Temperature Membrane Working Group Meeting (HTMWG) held October 10, 2007 in Washington, D.C.

  8. Performance and Reliability of Bonded Interfaces for High-Temperature Packaging (Presentation)

    SciTech Connect (OSTI)

    Devoto, D.

    2014-06-01

    This presentation reviews the status of the performance and reliability of bonded interfaces for high-temperature packaging.

  9. Anomalous deformation twinning in fcc metals at high temperatures Tanushree Sinha and Yashashree Kulkarnia)

    E-Print Network [OSTI]

    Kulkarni, Yashashree

    of nanotwinned metals, especially at high temperatures. Recent studies by Shute et al.18 and Saldana et al.19

  10. High-Temperature Air-Cooled Power Electronics Thermal Design (Presentation)

    SciTech Connect (OSTI)

    Waye, S.

    2014-06-01

    This presentation discusses the status of research at NREL on high temperature air-cooled power electronics thermal design.

  11. High-Temperature Circuit Boards for Use in Geothermal Well Monitoring Applications

    Broader source: Energy.gov [DOE]

    Project objective: Develop and demonstrate high-temperature; multilayer electronic circuits capable of sustained operation at 300? C.

  12. Low and high Temperature Dual Thermoelectric Generation Waste Heat Recovery System for Light-Duty Vehicles

    Broader source: Energy.gov [DOE]

    Developing a low and high temperature dual thermoelectric generation waste heat recovery system for light-duty vehicles.

  13. AOI [3] High-Temperature Nano-Derived Micro-H2 and - H2S Sensors

    SciTech Connect (OSTI)

    Perepezko, John; Lu-Steffes, Otto

    2014-08-31

    The emissions from coal-fired power plants remain a significant concern for air quality. This environmental challenge must be overcome by controlling the emission of sulfur dioxide (SO2) and hydrogen sulfide (H2S) throughout the entire coal combustion process. One of the processes which could specifically benefit from robust, low cost, and high temperature compatible gas sensors is the coal gasification process which converts coal and/or biomass into syngas. Hydrogen (H2), carbon monoxide (CO) and sulfur compounds make up 33%, 43% and 2% of syngas, respectively. Therefore, development of a high temperature (>500°C) chemical sensor for in-situ monitoring of H2, H2S and SO2 levels during coal gasification is strongly desired. The selective detection of SO2/H2S in the presence of H2, is a formidable task for a sensor designer. In order to ensure effective operation of these chemical sensors, the sensor system must inexpensively function within harsh temperature and chemical environment. Currently available sensing approaches, which are based on gas chromatography, electrochemistry, and IR-spectroscopy, do not satisfy the required cost and performance targets. This work focused on the development microsensors that can be applied to this application. In order to develop the high- temperature compatible microsensor, this work addressed various issues related to sensor stability, selectivity, and miniaturization. In the research project entitled “High-Temperature Nano-Derived Micro-H2 and -H2S Sensors”, the team worked to develop micro-scale, chemical sensors and sensor arrays composed of nano-derived, metal-oxide composite materials to detect gases like H2, SO2, and H2S within high-temperature environments (>500?C). The research was completed in collaboration with NexTech Materials, Ltd. (Lewis Center, Ohio). NexTech assisted in the testing of the sensors in syngas with contaminate levels of H2S. The idea of including nanomaterials as the sensing material within resistive-type chemical sensor platforms was to increase the sensitivity (as shown for room temperature applications). Unfortunately, nanomaterials are not stable at high temperatures due to sintering and coarsening processes that are driven by their high surface to volume ratio. Therefore, new hydrogen and sulfur selective nanomaterial systems with high selectivity and stability properties in the proposed harsh environment were investigated. Different nano-morphologies of zirconate, molybdate, and tungstate compounds were investigated. The fabrication of the microsensors consisted of the deposition of the selective nanomaterial systems over metal based interconnects on an inert substrate. This work utilized the chemi-resistive (resistive- type) microsensor architecture where the chemically and structurally stable, high temperature compatible electrodes were sputtered onto a ceramic substrate. The nanomaterial sensing systems were deposited over the electrodes using a lost mold method patterned by conventional optical lithography. The microsensor configuration with optimized nanomaterial system was tested and compared to a millimeter-size sensor e outcomes of this research will contribute to the economical application of sensor arrays for simultaneous sensing of H2, H2S, and SO2.

  14. High-field magnets using high-critical-temperature superconducting thin films

    DOE Patents [OSTI]

    Mitlitsky, F.; Hoard, R.W.

    1994-05-10

    High-field magnets fabricated from high-critical-temperature superconducting ceramic (HTSC) thin films which can generate fields greater than 4 Tesla are disclosed. The high-field magnets are made of stackable disk-shaped substrates coated with HTSC thin films, and involves maximizing the critical current density, superconducting film thickness, number of superconducting layers per substrate, substrate diameter, and number of substrates while minimizing substrate thickness. The HTSC thin films are deposited on one or both sides of the substrates in a spiral configuration with variable line widths to increase the field. 4 figures.

  15. High-field magnets using high-critical-temperature superconducting thin films

    DOE Patents [OSTI]

    Mitlitsky, Fred (Livermore, CA); Hoard, Ronald W. (Livermore, CA)

    1994-01-01

    High-field magnets fabricated from high-critical-temperature superconducting ceramic (HTSC) thin films which can generate fields greater than 4 Tesla. The high-field magnets are made of stackable disk-shaped substrates coated with HTSC thin films, and involves maximizing the critical current density, superconducting film thickness, number of superconducting layers per substrate, substrate diameter, and number of substrates while minimizing substrate thickness. The HTSC thin films are deposited on one or both sides of the substrates in a spiral configuration with variable line widths to increase the field.

  16. Enhanced High and Low Temperature Performance of NOx Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    temperature performance loss; * characterization of material changes with hydrothermal aging * the sulfur adsorption and regeneration mechanisms for modified andor alternative...

  17. Amorphous Alloy Membranes for High Temperature Hydrogen Separation

    SciTech Connect (OSTI)

    Coulter, K

    2013-09-30

    At the beginning of this project, thin film amorphous alloy membranes were considered a nascent but promising new technology for industrial-scale hydrogen gas separations from coal- derived syngas. This project used a combination of theoretical modeling, advanced physical vapor deposition fabricating, and laboratory and gasifier testing to develop amorphous alloy membranes that had the potential to meet Department of Energy (DOE) targets in the testing strategies outlined in the NETL Membrane Test Protocol. The project is complete with Southwest Research Institute® (SwRI®), Georgia Institute of Technology (GT), and Western Research Institute (WRI) having all operated independently and concurrently. GT studied the hydrogen transport properties of several amorphous alloys and found that ZrCu and ZrCuTi were the most promising candidates. GT also evaluated the hydrogen transport properties of V, Nb and Ta membranes coated with different transition-metal carbides (TMCs) (TM = Ti, Hf, Zr) catalytic layers by employing first-principles calculations together with statistical mechanics methods and determined that TiC was the most promising material to provide catalytic hydrogen dissociation. SwRI developed magnetron coating techniques to deposit a range of amorphous alloys onto both porous discs and tubular substrates. Unfortunately none of the amorphous alloys could be deposited without pinhole defects that undermined the selectivity of the membranes. WRI tested the thermal properties of the ZrCu and ZrNi alloys and found that under reducing environments the upper temperature limit of operation without recrystallization is ~250 °C. There were four publications generated from this project with two additional manuscripts in progress and six presentations were made at national and international technical conferences. The combination of the pinhole defects and the lack of high temperature stability make the theoretically identified most promising candidate amorphous alloys unsuitable for application as hydrogen separation membranes in coal fire systems.

  18. Multiyear Program Plan for the High Temperature Materials Laboratory

    SciTech Connect (OSTI)

    Arvid E. Pasto

    2000-03-17

    Recently, the U.S. Department of Energy's (DOE) Office of Heavy Vehicle Technologies (OHVT) prepared a Technology Roadmap describing the challenges facing development of higher fuel efficiency, less polluting sport utility vehicles, vans, and commercial trucks. Based on this roadmap, a multiyear program plan (MYPP) was also developed, in which approaches to solving the numerous challenges are enumerated. Additional planning has been performed by DOE and national laboratory staff, on approaches to solving the numerous challenges faced by heavy vehicle system improvements. Workshops and planning documents have been developed concerning advanced aerodynamics, frictional and other parasitic losses, and thermal management. Similarly, the Heavy Vehicle Propulsion Materials Program has developed its own multiyear program plan. The High Temperature Materials Laboratory, a major user facility sponsored by OHVT, has now developed its program plan, described herein. Information was gathered via participation in the development of OHVT's overall Technology Roadmap and MYPP, through personal contacts within the materials-user community, and from attendance at conferences and expositions. Major materials issues for the heavy vehicle industry currently center on trying to increase efficiency of (diesel) engines while at the same time reducing emissions (particularly NO{sub x} and particulates). These requirements dictate the use of increasingly stronger, higher-temperature capable and more corrosion-resistant materials of construction, as well as advanced catalysts, particulate traps, and other pollution-control devices. Exhaust gas recirculation (EGR) is a technique which will certainly be applied to diesel engines in the near future, and its use represents a formidable challenge, as will be described later. Energy-efficient, low cost materials processing methods and surface treatments to improve wear, fracture, and corrosion resistance are also required.

  19. Characterization of Composite Cores for High Temperature-Low Sag (HTLS)

    E-Print Network [OSTI]

    Characterization of Composite Cores for High Temperature-Low Sag (HTLS) Conductors Final Project/University Cooperative Research Center since 1996 PSERC #12;Characterization of Composite Cores for High Temperature project T-33 titled "Characterization of Composite Cores for High Temperature-Low Sag (HTLS) Conductors

  20. Low temperature and high frequency effects on polymer-stabilized blue phase liquid crystals with

    E-Print Network [OSTI]

    Wu, Shin-Tson

    Low temperature and high frequency effects on polymer-stabilized blue phase liquid crystals*a and Yasuhiro Hasebab We report the low temperature and high frequency effects on polymer-stabilized blue phase temperature and high frequency operations are critical issues, especially for outdoor applications or color

  1. Infrared emission spectroscopy of CO2 at high temperature. Part I: Experimental setup and source

    E-Print Network [OSTI]

    Boyer, Edmond

    Infrared emission spectroscopy of CO2 at high temperature. Part I: Experimental setup and source measurement, tube effects, CO2 infrared radiation 1. Introduction The knowledge of very high temperature for instance that the IR emission of the CO2 molecule remains predominant at temperatures as high as 4000 K [1

  2. Method of manufacturing a high temperature superconductor with improved transport properties

    DOE Patents [OSTI]

    Balachandran, Uthamalingam (Hinsdale, IL); Siegel, Richard W. (Hinsdale, IL); Askew, Thomas R. (Kalamazoo, MI)

    2001-01-01

    A method of preparing a high temperature superconductor. A method of preparing a superconductor includes providing a powdered high temperature superconductor and a nanophase paramagnetic material. These components are combined to form a solid compacted mass with the paramagnetic material disposed on the grain boundaries of the polycrystaline high temperature superconductor.

  3. Thermal-stress modeling of an optical microphone at high temperature...

    Office of Scientific and Technical Information (OSTI)

    Thermal-stress modeling of an optical microphone at high temperature. Citation Details In-Document Search Title: Thermal-stress modeling of an optical microphone at high...

  4. Advancement of High Temperature Black Liquor Gasification Technology

    SciTech Connect (OSTI)

    Craig Brown; Ingvar Landalv; Ragnar Stare; Jerry Yuan; Nikolai DeMartini; Nasser Ashgriz

    2008-03-31

    Weyerhaeuser operates the world's only commercial high-temperature black liquor gasifier at its pulp mill in New Bern, NC. The unit was started-up in December 1996 and currently processes about 15% of the mill's black liquor. Weyerhaeuser, Chemrec AB (the gasifier technology developer), and the U.S. Department of Energy recognized that the long-term, continuous operation of the New Bern gasifier offered a unique opportunity to advance the state of high temperature black liquor gasification toward the commercial-scale pressurized O2-blown gasification technology needed as a foundation for the Forest Products Bio-Refinery of the future. Weyerhaeuser along with its subcontracting partners submitted a proposal in response to the 2004 joint USDOE and USDA solicitation - 'Biomass Research and Development Initiative'. The Weyerhaeuser project 'Advancement of High Temperature Black Liquor Gasification' was awarded USDOE Cooperative Agreement DE-FC26-04NT42259 in November 2004. The overall goal of the DOE sponsored project was to utilize the Chemrec{trademark} black liquor gasification facility at New Bern as a test bed for advancing the development status of molten phase black liquor gasification. In particular, project tasks were directed at improvements to process performance and reliability. The effort featured the development and validation of advanced CFD modeling tools and the application of these tools to direct burner technology modifications. The project also focused on gaining a fundamental understanding and developing practical solutions to address condensate and green liquor scaling issues, and process integration issues related to gasifier dregs and product gas scrubbing. The Project was conducted in two phases with a review point between the phases. Weyerhaeuser pulled together a team of collaborators to undertake these tasks. Chemrec AB, the technology supplier, was intimately involved in most tasks, and focused primarily on the design, specification and procurement of facility upgrades. Chemrec AB is also operating a pressurized, O2-blown gasifier pilot facility in Piteaa, Sweden. There was an exchange of knowledge with the pressurized projects including utilization of the experimental results from facilities in Piteaa, Sweden. Resources at the Georgia Tech Research Corporation (GTRC, a.k.a., the Institute of Paper Science and Technology) were employed primarily to conduct the fundamental investigations on scaling and plugging mechanisms and characterization of green liquor dregs. The project also tapped GTRC expertise in the development of the critical underlying black liquor gasification rate subroutines employed in the CFD code. The actual CFD code development and application was undertaken by Process Simulation, Ltd (PSL) and Simulent, Ltd. PSL focused on the overall integrated gasifier CFD code, while Simulent focused on modeling the black liquor nozzle and description of the black liquor spray. For nozzle development and testing Chemrec collaborated with ETC (Energy Technology Centre) in Piteae utilizing their test facility for nozzle spray investigation. GTI (Gas Technology Institute), Des Plains, IL supported the team with advanced gas analysis equipment during the gasifier test period in June 2005.

  5. Characterization of high-current, high-temperature superconductor current lead elements

    SciTech Connect (OSTI)

    Niemann, R.C.; Evans, D.J.; Fisher, B.L.; Brockenborough, W.E.; Roberts, P.R.; Rodenbush, A.J.

    1996-08-01

    The refrigeration loads of current leads for superconducting magnets can be significantly reduced by using high-temperature superconductor (HTS) leads. An HTS conductor type that is well suited for this application is a laminated sintered stack of HTS powder-in-tube (PIT) tapes. The superconducting elements are normally characterized by their manufacturer by measuring critical currents at 77 K in self field. Additional characterization, which correlates electrical performance at 77 K and at lower temperatures with applied magnetic fields, provides the current lead designer and conductor element manufacturer with critical information. For HTS conductor elements comprising a laminated and sintered stack of Bi-2223 PIT tapes having an alloyed Ag sheath, this characterization uses variable applied fields and operating temperatures.

  6. Nanoscale Morphological and Chemical Changes of High Voltage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines lightGeospatialDevelopmentEnergyApplications -Nanoscale Chemical

  7. Equations of state of ice VI and ice VII at high pressure and high temperature

    SciTech Connect (OSTI)

    Bezacier, Lucile; Hanfland, Michael; Journaux, Baptiste; Perrillat, Jean-Philippe; Cardon, Hervé; Daniel, Isabelle

    2014-09-14

    High-pressure H{sub 2}O polymorphs among which ice VI and ice VII are abundant in the interiors of large icy satellites and exo-planets. Knowledge of the elastic properties of these pure H{sub 2}O ices at high-temperature and high-pressure is thus crucial to decipher the internal structure of icy bodies. In this study we assess for the first time the pressure-volume-temperature (PVT) relations of both polycrystalline pure ice VI and ice VII at high pressures and temperatures from 1 to 9 GPa and 300 to 450 K, respectively, by using in situ synchrotron X-ray diffraction. The PVT data are adjusted to a second-order Birch-Murnaghan equation of state and give V{sub 0} = 14.17(2) cm{sup 3}?mol{sup ?1}, K{sub 0} = 14.05(23) GPa, and ?{sub 0} = 14.6(14) × 10{sup ?5} K{sup ?1} for ice VI and V{sub 0} = 12.49(1) cm{sup 3}?mol{sup ?1}, K{sub 0} = 20.15(16) GPa, and ?{sub 0} = 11.6(5) × 10{sup ?5} K{sup ?1} for ice VII.

  8. Lee-Yang zero distribution of high temperature QCD and Roberge-Weiss phase transition

    E-Print Network [OSTI]

    Keitaro Nagata; Kouji Kashiwa; Atsushi Nakamura; Shinsuke M. Nishigaki

    2015-05-16

    Canonical partition functions and Lee-Yang zeros of QCD at finite density and high temperature are studied. Recent lattice simulations have confirmed that the free energy of QCD is a quartic function of quark chemical potential at temperature slightly above pseudo-critical temperature $T_c$, as in the case with a gas of free massless fermions. We present analytic derivation of the canonical partition functions and Lee-Yang zeros for this type of free energy using the saddle point approximation. We also perform lattice QCD simulation in a canonical approach using the fugacity expansion of the fermion determinant, and carefully examine its reliability. By comparing the analytic and numerical results, we conclude that the canonical partition functions follow the Gaussian distribution of the baryon number, and the accumulation of Lee-Yang zeros of these canonical partition functions exhibit the first-order Roberge-Weiss phase transition. We discuss the validity and applicable range of the result and its implications both for theoretical and experimental studies.

  9. High-Temperature Phase Change Materials (PCM) Candidates for Thermal Energy Storage (TES) Applications

    SciTech Connect (OSTI)

    Gomez, J. C.

    2011-09-01

    It is clearly understood that lower overall costs are a key factor to make renewable energy technologies competitive with traditional energy sources. Energy storage technology is one path to increase the value and reduce the cost of all renewable energy supplies. Concentrating solar power (CSP) technologies have the ability to dispatch electrical output to match peak demand periods by employing thermal energy storage (TES). Energy storage technologies require efficient materials with high energy density. Latent heat TES systems using phase change material (PCM) are useful because of their ability to charge and discharge a large amount of heat from a small mass at constant temperature during a phase transformation like melting-solidification. PCM technology relies on the energy absorption/liberation of the latent heat during a physical transformation. The main objective of this report is to provide an assessment of molten salts and metallic alloys proposed as candidate PCMs for TES applications, particularly in solar parabolic trough electrical power plants at a temperature range from 300..deg..C to 500..deg.. C. The physical properties most relevant for PCMs service were reviewed from the candidate selection list. Some of the PCM candidates were characterized for: chemical stability with some container materials; phase change transformation temperatures; and latent heats.

  10. Evolution of the stratospheric temperature and chemical composition over one Titanian year

    SciTech Connect (OSTI)

    Coustenis, Athena; Bampasidis, G.; Vinatier, S. [Laboratoire d'Etudes Spatiales et d'Instrumentation en Astrophysique (LESIA), Observatoire de Paris, CNRS, UPMC Univ. Paris 06, Univ. Paris-Diderot, 5, place Jules Janssen, F-92195 Meudon Cedex (France); Achterberg, R. K.; Jennings, D. E.; Nixon, C. A.; Flasar, F. M.; Carlson, R. C.; Romani, P. N.; Guandique, E. A. [NASA/Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Lavvas, P. [GSMA, Université Reims Champagne-Ardenne, F-51687 Reims Cedex 2 (France); Teanby, N. A. [School of Earth Sciences, University of Bristol, Bristol BS8 1RJ (United Kingdom); Orton, G. [MS 183-501, Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109 (United States); Stamogiorgos, S., E-mail: athena.coustenis@obspm.fr [Faculty of Physics, National and Kapodistrian University of Athens, Panepistimioupolis, GR 15783 Zographos, Athens (Greece)

    2013-12-20

    Since the Voyager 1 (V1) flyby in 1980, Titan's exploration from space and the ground has been ongoing for more than a full revolution of Saturn around the Sun (one Titanian year or 29.5 Earth years had elapsed in 2010 May). In this study, we search for temporal variations affecting Titan's atmospheric thermal and chemical structure within that year. We process Cassini/CIRS data taken during the Titan flybys from 2006-2013 and find a rather uneventful equatorial evolution. Conversely, at northern latitudes, we found enhanced abundances around the period of the northern spring equinox in mid-2009, which subsequently decreased (from 2010 to 2012), returning to values similar to those found in the V1 epoch, one Titanian year before. In the southern latitudes, since 2012, we see a trend for an increase of several trace gases (C{sub 4}H{sub 2}, C{sub 3}H{sub 4}, and HCN), indicative of a seasonal atmospheric reversal setting in. When we compare the CIRS 2010 and the 1980 V1/IRIS spectra (reanalyzed here), we find limited inter-annual variations. A return to the 1980 stratospheric temperatures and abundances is generally achieved from 50°N to 50°S, indicative of the solar radiation being the dominating energy source at 10 AU, as for the Earth, as predicted by general circulation and photochemical models. Exceptions concern the most complex hydrocarbons (C{sub 4}H{sub 2} and C{sub 3}H{sub 4}). We also consider data from ground-based and Earth-orbiting observatories (such as from the Infrared Space Observatory, revisited here) and discuss possible atmospheric composition trends during a Titanian year.

  11. High temperature performance of high-efficiency, multi-layer solar selective coatings for tower applications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gray, M. H.; Tirawat, R.; Kessinger, K. A.; Ndione, P. F.

    2015-05-01

    The roadmap to next-generation concentrating solar power plants anticipates a progression to central towers with operating temperatures in excess of 650°C. These higher temperatures are required to drive higher power-cycle efficiencies, resulting in lower cost energy. However, these conditions also place a greater burden on the materials making up the receiver. Any novel absorber material developed for next-generation receivers must be stable in air, cost effective, and survive thousands of heating and cooling cycles. The collection efficiency of a power tower plant can be increased if the energy absorbed by the receiver is maximized while the heat loss from themore »receiver to the environment is minimized. Thermal radiation losses can be significant (>7% annual energy loss) with receivers at temperatures above 650°C. We present progress toward highly efficient and durable solar selective absorbers (SSAs) intended for operating temperatures from 650°C to 1000°C. Selective efficiency (?sel) is defined as the energy retained by the absorber, accounting for both absorptance and emittance, relative to the energy incident on the surface. The low emittance layers of multilayer SSAs are binary compounds of refractory metals whose material properties indicate that coatings formed of these materials should be oxidation resistant in air to 800-1200°C. On this basis, we initially developed a solar selective coating for parabolic troughs. This development has been successfully extended to meet the absorptance and emittance objectives for the more demanding, high temperature regime. We show advancement in coating materials, processing and designs resulting in the initial attainment of target efficiencies ?sel > 0.91 for proposed tower conditions. Additionally, spectral measurements show that these coatings continue to perform at targeted levels after cycling to temperatures of 1000°C in environments of nitrogen and forming gas.« less

  12. High temperature performance of high-efficiency, multi-layer solar selective coatings for tower applications

    SciTech Connect (OSTI)

    Gray, M. H.; Tirawat, R.; Kessinger, K. A.; Ndione, P. F.

    2015-05-01

    The roadmap to next-generation concentrating solar power plants anticipates a progression to central towers with operating temperatures in excess of 650°C. These higher temperatures are required to drive higher power-cycle efficiencies, resulting in lower cost energy. However, these conditions also place a greater burden on the materials making up the receiver. Any novel absorber material developed for next-generation receivers must be stable in air, cost effective, and survive thousands of heating and cooling cycles. The collection efficiency of a power tower plant can be increased if the energy absorbed by the receiver is maximized while the heat loss from the receiver to the environment is minimized. Thermal radiation losses can be significant (>7% annual energy loss) with receivers at temperatures above 650°C. We present progress toward highly efficient and durable solar selective absorbers (SSAs) intended for operating temperatures from 650°C to 1000°C. Selective efficiency (?sel) is defined as the energy retained by the absorber, accounting for both absorptance and emittance, relative to the energy incident on the surface. The low emittance layers of multilayer SSAs are binary compounds of refractory metals whose material properties indicate that coatings formed of these materials should be oxidation resistant in air to 800-1200°C. On this basis, we initially developed a solar selective coating for parabolic troughs. This development has been successfully extended to meet the absorptance and emittance objectives for the more demanding, high temperature regime. We show advancement in coating materials, processing and designs resulting in the initial attainment of target efficiencies ?sel > 0.91 for proposed tower conditions. Additionally, spectral measurements show that these coatings continue to perform at targeted levels after cycling to temperatures of 1000°C in environments of nitrogen and forming gas.

  13. Method for preparing high cure temperature rare earth iron compound magnetic material

    DOE Patents [OSTI]

    Huang, Yuhong (West Hills, CA); Wei, Qiang (West Hills, CA); Zheng, Haixing (Oak Park, CA)

    2002-01-01

    Insertion of light elements such as H,C, or N in the R.sub.2 Fe.sub.17 (R=rare earth metal) series has been found to modify the magnetic properties of these compounds, which thus become prospective candidates for high performance permanent magnets. The most spectacular changes are increases of the Curie temperature, T.sub.c, of the magnetization, M.sub.s, and of coercivity, H.sub.c, upon interstitial insertion. A preliminary product having a component R--Fe--C,N phase is produced by a chemical route. Rare earth metal and iron amides are synthesized followed by pyrolysis and sintering in an inert or reduced atmosphere, as a result of which, the R--Fe--C,N phases are formed. Fabrication of sintered rare earth iron nitride and carbonitride bulk magnet is impossible via conventional process due to the limitation of nitridation method.

  14. High temperature gas-cooled reactor (HTGR) graphite pebble fuel: Review of technologies for reprocessing

    SciTech Connect (OSTI)

    Mcwilliams, A. J.

    2015-09-08

    This report reviews literature on reprocessing high temperature gas-cooled reactor graphite fuel components. A basic review of the various fuel components used in the pebble bed type reactors is provided along with a survey of synthesis methods for the fabrication of the fuel components. Several disposal options are considered for the graphite pebble fuel elements including the storage of intact pebbles, volume reduction by separating the graphite from fuel kernels, and complete processing of the pebbles for waste storage. Existing methods for graphite removal are presented and generally consist of mechanical separation techniques such as crushing and grinding chemical techniques through the use of acid digestion and oxidation. Potential methods for reprocessing the graphite pebbles include improvements to existing methods and novel technologies that have not previously been investigated for nuclear graphite waste applications. The best overall method will be dependent on the desired final waste form and needs to factor in the technical efficiency, political concerns, cost, and implementation.

  15. Surface structure, composition, and polarity of indium nitride grown by high-pressure chemical vapor deposition

    E-Print Network [OSTI]

    Dietz, Nikolaus

    grown by high-pressure chemical vapor deposition have been studied. Atomic hydrogen cleaning produced and heterostructures--which can be accomplished by low- pressure metalorganic chemical vapor deposition MOCVD --the- rium vapor pressure of nitrogen during growth. This requires different approaches in growing structures

  16. Highly oriented, free-standing, superconducting NbN films growth on chemical vapor deposited graphene

    E-Print Network [OSTI]

    Raychaudhuri, Pratap

    Highly oriented, free-standing, superconducting NbN films growth on chemical vapor deposited oriented, free-standing, superconducting NbN films growth on chemical vapor deposited graphene Garima field of 33 T. In addition, we demonstrate a process for obtaining flexible, free-standing NbN films

  17. Electrically Heated High Temperature Incineration of Air Toxics 

    E-Print Network [OSTI]

    Agardy, F. J.; Wilcox, J. B.

    1990-01-01

    In-Process Technology has placed a prototype of its patented, electrically heated, packed-bed air toxics oxidizer at a northern California chemical plant. This thermal oxidizer is capable of handling a wide range of chlorinated and non...

  18. Modular high voltage power supply for chemical analysis

    DOE Patents [OSTI]

    Stamps, James F. (Livermore, CA); Yee, Daniel D. (Dublin, CA)

    2007-01-09

    A high voltage power supply for use in a system such as a microfluidics system, uses a DC--DC converter in parallel with a voltage-controlled resistor. A feedback circuit provides a control signal for the DC--DC converter and voltage-controlled resistor so as to regulate the output voltage of the high voltage power supply, as well as, to sink or source current from the high voltage supply.

  19. Modular high voltage power supply for chemical analysis

    DOE Patents [OSTI]

    Stamps, James F. (Livermore, CA); Yee, Daniel D. (Dublin, CA)

    2008-07-15

    A high voltage power supply for use in a system such as a microfluidics system, uses a DC-DC converter in parallel with a voltage-controlled resistor. A feedback circuit provides a control signal for the DC-DC converter and voltage-controlled resistor so as to regulate the output voltage of the high voltage power supply, as well as, to sink or source current from the high voltage supply.

  20. Modular high voltage power supply for chemical analysis

    DOE Patents [OSTI]

    Stamps, James F. (Livermore, CA); Yee, Daniel D. (Dublin, CA)

    2010-05-04

    A high voltage power supply for use in a system such as a microfluidics system, uses a DC-DC converter in parallel with a voltage-controlled resistor. A feedback circuit provides a control signal for the DC-DC converter and voltage-controlled resistor so as to regulate the output voltage of the high voltage power supply, as well as, to sink or source current from the high voltage supply.

  1. Pressure Resistance Welding of High Temperature Metallic Materials

    SciTech Connect (OSTI)

    N. Jerred; L. Zirker; I. Charit; J. Cole; M. Frary; D. Butt; M. Meyer; K. L. Murty

    2010-10-01

    Pressure Resistance Welding (PRW) is a solid state joining process used for various high temperature metallic materials (Oxide dispersion strengthened alloys of MA957, MA754; martensitic alloy HT-9, tungsten etc.) for advanced nuclear reactor applications. A new PRW machine has been installed at the Center for Advanced Energy Studies (CAES) in Idaho Falls for conducting joining research for nuclear applications. The key emphasis has been on understanding processing-microstructure-property relationships. Initial studies have shown that sound joints can be made between dissimilar materials such as MA957 alloy cladding tubes and HT-9 end plugs, and MA754 and HT-9 coupons. Limited burst testing of MA957/HT-9 joints carried out at various pressures up to 400oC has shown encouraging results in that the joint regions do not develop any cracking. Similar joint strength observations have also been made by performing simple bend tests. Detailed microstructural studies using SEM/EBSD tools and fatigue crack growth studies of MA754/HT-9 joints are ongoing.

  2. Novel Gas Sensors for High-Temperature Fossil Fuel Applications

    SciTech Connect (OSTI)

    Palitha Jayaweera; Francis Tanzella

    2005-03-01

    SRI International (SRI) is developing ceramic-based microsensors to detect exhaust gases such as NO, NO{sub 2}, and CO in advanced combustion and gasification systems under this DOE NETL-sponsored research project. The sensors detect the electrochemical activity of the exhaust gas species on catalytic electrodes attached to a solid state electrolyte and are designed to operate at the high temperatures, elevated pressures, and corrosive environments typical of large power generation exhausts. The sensors can be easily integrated into online monitoring systems for active emission control. The ultimate objective is to develop sensors for multiple gas detection in a single package, along with data acquisition and control software and hardware, so that the information can be used for closed-loop control in novel advanced power generation systems. This report details the Phase I Proof-of-Concept, research activities performed from October 2003 to March 2005. SRI's research work includes synthesis of catalytic materials, sensor design and fabrication, software development, and demonstration of pulse voltammetric analysis of NO, NO{sub 2}, and CO gases on catalytic electrodes.

  3. NETL - Chemical Looping Reactor

    SciTech Connect (OSTI)

    2013-07-24

    NETL's Chemical Looping Reactor unit is a high-temperature integrated CLC process with extensive instrumentation to improve computational simulations. A non-reacting test unit is also used to study solids flow at ambient temperature. The CLR unit circulates approximately 1,000 pounds per hour at temperatures around 1,800 degrees Fahrenheit.

  4. NETL - Chemical Looping Reactor

    ScienceCinema (OSTI)

    None

    2014-06-26

    NETL's Chemical Looping Reactor unit is a high-temperature integrated CLC process with extensive instrumentation to improve computational simulations. A non-reacting test unit is also used to study solids flow at ambient temperature. The CLR unit circulates approximately 1,000 pounds per hour at temperatures around 1,800 degrees Fahrenheit.

  5. High-temperature, high-pressure bonding of nested tubular metallic components

    DOE Patents [OSTI]

    Quinby, Thomas C. (Kingston, TN)

    1980-01-01

    This invention is a tool for effecting high-temperature, high-compression bonding between the confronting faces of nested, tubular, metallic components. In a typical application, the tool is used to produce tubular target assemblies for irradiation in nuclear reactors or particle accelerators, the target assembly comprising a uranium foil and an aluminum-alloy substrate. The tool preferably is composed throughout of graphite. It comprises a tubular restraining member in which a mechanically expandable tubular core is mounted to form an annulus with the member. The components to be bonded are mounted in nested relation in the annulus. The expandable core is formed of individually movable, axially elongated segments whose outer faces cooperatively define a cylindrical pressing surface and whose inner faces cooperatively define two opposed, inwardly tapered, axial bores. Tapered rams extend respectively into the bores. The loaded tool is mounted in a conventional hot-press provided with evacuation means, heaters for maintaining its interior at bonding temperature, and hydraulic cylinders for maintaining a selected inwardly directed pressure on the tapered rams. With the hot-press evacuated and the loaded tool at the desired temperature, the cylinders are actuated to apply the selected pressure to the rams. The rams in turn expand the segmented core to maintain the nested components in compression against the restraining member. These conditions are maintained until the confronting faces of the nested components are joined in a continuous, uniform bond characterized by high thermal conductivity.

  6. Evaluation of High-Temperature Exposure of Photovoltaic Modules: Preprint

    SciTech Connect (OSTI)

    Kurtz, S.; Miller, D.; Kempe, M.; Bosco, N.; Whitefield, K.; Wohlgemuth, J.; Dhere, N.; Zgonena, T.

    2009-06-01

    This paper documents measured and modeled PV-module temperatures and evaluates these in the context of the requirements for accelerated testing.

  7. High Temperature Fuel Cell (Phosphoric Acid) Manufacturing R...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Temperature Fuel Cell (Phosphoric Acid) Manufacturing R&D More Documents & Publications Molten Carbonate and Phosphoric Acid Stationary Fuel Cells: Overview and Gap Analysis 2011...

  8. Development of a 500 Watt High Temperature Thermoelectric Generator

    Broader source: Energy.gov [DOE]

    A low temperature TEG has been built and tested providing over 500 watts electric power at a ?T of 2000C

  9. Project Profile: High-Temperature Falling-Particle Receiver ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    nearby. The concept enables higher temperatures and greater efficiencies at a lower cost as compared to today's receivers. The research team is pursuing technical innovations...

  10. Technique for the Estimation of Surface Temperatures from Embedded Temperature Sensing for Rapid, High Energy Surface Deposition

    SciTech Connect (OSTI)

    Watkins, Tyson R.; Schunk, Peter Randall; Roberts, Scott A.

    2014-07-01

    Temperature histories on the surface of a body that has been subjected to a rapid, high-energy surface deposition process can be di#14;fficult to determine, especially if it is impossible to directly observe the surface or attach a temperature sensor to it. In this report, we explore two methods for estimating the temperature history of the surface through the use of a sensor embedded within the body very near to the surface. First, the maximum sensor temperature is directly correlated with the peak surface temperature. However, it is observed that the sensor data is both delayed in time and greatly attenuated in magnitude, making this approach unfeasible. Secondly, we propose an algorithm that involves fitting the solution to a one-dimensional instantaneous energy solution problem to both the sensor data and to the results of a one-dimensional CVFEM code. This algorithm is shown to be able to estimate the surface temperature {+-}~20#14;{degrees}C.

  11. A High Temperature Hermetic Primer and a Variable Spring Tester

    SciTech Connect (OSTI)

    Begeal, D.R.

    1994-05-01

    Percussion primers are used at Sandia to ignite energetic components such as pyrotechnic actuators and thermal batteries. This report describes a High Temperature Hermetic Primer (HTHP) that was developed to replace a previous G16 Percussion Primer Subassembly (Gl6PPS). The ignition mix in these primers is the same as in the discontinued Remington 44G16 (KC1O{sub 3}, SbS{sub 3}, and Ca{sub 2}Si). The HTHP has nearly the same sensitivity as the 44G16 and a significantly lower sensitivity than the G16PPS. In parallel with the HTHP development, we also designed a Variable Spring Tester (VST) to determine percussion primer ignition sensitivity with firing pins that have the same mass as those used in field applications. The tester is capable of accelerating firing pins over a velocity range of 100 to 600 inches per second for pins weighing up to 6 grams. The desired impulse can be preselected with an accuracy of better than {plus_minus}1%. The actual impulse is measured on every shot. The VST was characterized using the WW42Cl primer, as well as with the G16PPS and the HTHP. Compared to data from conventional ball drop testers, we found that ignition sensitivities were lower and there was less scatter in the sensitivity data. Our experiments indicate that ignition sensitivity is not strictly energy dependent, but also depends on the rate of deposition, or firing pin velocity in this case. Development results for the HTHP and Variable Spring Tester are discussed and design details are shown.

  12. Holographic Calculation for Large Interval Rényi Entropy at High Temperature

    E-Print Network [OSTI]

    Bin Chen; Jie-qiang Wu

    2015-06-10

    In this paper, we study the holographic R\\'enyi entropy of a large interval on a circle at high temperature for the two-dimensional CFT dual to pure AdS$_3$ gravity. In the field theory, the R\\'enyi entropy is encoded in the CFT partition function on $n$-sheeted torus connected with each other by a large branch cut. As proposed in 1412.0763, the effective way to read the entropy in the large interval limit is to insert a complete set of state bases of the twist sector at the branch cut. Then the calculation transforms into an expansion of four-point functions in the twist sector with respect to $e^{-\\frac{2\\pi TR}{n}}$. By using the operator product expansion of the twist operators at the branch points, we read the first few terms of the R\\'enyi entropy, including the leading and next-leading contributions in the large central charge limit. Moreover, we show that the leading contribution is actually captured by the twist vacuum module. In this case by the Ward identity the four-point functions can be derived from the correlation function of four twist operators, which is related to double interval entanglement entropy. Holographically, we apply the recipe in 1303.7221 and 1306.4682 to compute the classical R\\'enyi entropy and its 1-loop quantum correction, after imposing a new set of monodromy conditions. The holographic classical result matches exactly with the leading contribution in the field theory up to $e^{-4\\pi TR}$ and $l^6$, while the holographical 1-loop contribution is in exact agreement with next-leading results in field theory up to $e^{-\\frac{6\\pi TR}{n}}$ and $l^4$ as well.

  13. Protective interlayer for high temperature solid electrolyte electrochemical cells

    DOE Patents [OSTI]

    Singh, Prabhakar (Export, PA); Vasilow, Theodore R. (Manor, PA); Richards, Von L. (Angola, IN)

    1996-01-01

    The invention comprises of an electrically conducting doped or admixed cerium oxide composition with niobium oxide and/or tantalum oxide for electrochemical devices, characterized by the general formula: Nb.sub.x Ta.sub.y Ce.sub.1-x-y O.sub.2 where x is about 0.0 to 0.05, y is about 0.0 to 0.05, and x+y is about 0.02 to 0.05, and where x is preferably about 0.02 to 0.05 and y is 0, and a method of making the same. This novel composition is particularly applicable in forming a protective interlayer of a high temperature, solid electrolyte electrochemical cell (10), characterized by a first electrode (12); an electrically conductive interlayer (14) of niobium and/or tantalum doped cerium oxide deposited over at least a first portion (R) of the first electrode; an interconnect (16) deposited over the interlayer; a solid electrolyte (18) deposited over a second portion of the first electrode, the first portion being discontinuous from the second portion; and, a second electrode (20) deposited over the solid electrolyte. The interlayer (14) is characterized as being porous and selected from the group consisting of niobium doped cerium oxide, tantalum doped cerium oxide, and niobium and tantalum doped cerium oxide or admixtures of the same. The first electrode (12), an air electrode, is a porous layer of doped lanthanum manganite, the solid electrolyte layer (18) is a dense yttria stabilized zirconium oxide, the interconnect layer (16) is a dense, doped lanthanum chromite, and the second electrode (20), a fuel electrode, is a porous layer of nickel-zirconium oxide cermet. The electrochemical cell (10) can take on a plurality of shapes such as annular, planar, etc. and can be connected to a plurality of electrochemical cells in series and/or in parallel to generate electrical energy.

  14. High Temperature Gas Reactors: Assessment of Applicable Codes and Standards

    SciTech Connect (OSTI)

    McDowell, Bruce K.; Nickolaus, James R.; Mitchell, Mark R.; Swearingen, Gary L.; Pugh, Ray

    2011-10-31

    Current interest expressed by industry in HTGR plants, particularly modular plants with power up to about 600 MW(e) per unit, has prompted NRC to task PNNL with assessing the currently available literature related to codes and standards applicable to HTGR plants, the operating history of past and present HTGR plants, and with evaluating the proposed designs of RPV and associated piping for future plants. Considering these topics in the order they are arranged in the text, first the operational histories of five shut-down and two currently operating HTGR plants are reviewed, leading the authors to conclude that while small, simple prototype HTGR plants operated reliably, some of the larger plants, particularly Fort St. Vrain, had poor availability. Safety and radiological performance of these plants has been considerably better than LWR plants. Petroleum processing plants provide some applicable experience with materials similar to those proposed for HTGR piping and vessels. At least one currently operating plant - HTR-10 - has performed and documented a leak before break analysis that appears to be applicable to proposed future US HTGR designs. Current codes and standards cover some HTGR materials, but not all materials are covered to the high temperatures envisioned for HTGR use. Codes and standards, particularly ASME Codes, are under development for proposed future US HTGR designs. A 'roadmap' document has been prepared for ASME Code development; a new subsection to section III of the ASME Code, ASME BPVC III-5, is scheduled to be published in October 2011. The question of terminology for the cross-duct structure between the RPV and power conversion vessel is discussed, considering the differences in regulatory requirements that apply depending on whether this structure is designated as a 'vessel' or as a 'pipe'. We conclude that designing this component as a 'pipe' is the more appropriate choice, but that the ASME BPVC allows the owner of the facility to select the preferred designation, and that either designation can be acceptable.

  15. Catalytic CVD generation of high-purity single-walled carbon nanotubes at low temperature

    E-Print Network [OSTI]

    Maruyama, Shigeo

    CVD Catalytic CVD generation of high-purity single-walled carbon nanotubes at low temperature-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656 We have demonstrated the high-quality and low-temperature generation on the generation temperature and gas flow rate. In order to create nanotube devices, we tried to generate SWNTs

  16. Aalborg Universitet Performance and endurance of a high temperature PEM fuel cell operated on methanol

    E-Print Network [OSTI]

    Berning, Torsten

    Aalborg Universitet Performance and endurance of a high temperature PEM fuel cell operated temperature PEM fuel cell operated on methanol reformate. International Journal of Hydrogen Energy, 39 from vbn.aau.dk on: juli 05, 2015 #12;Performance and endurance of a high temperature PEM fuel cell

  17. Low Temperature Combustion Demonstrator for High Efficiency Clean Combustion

    SciTech Connect (OSTI)

    Ojeda, William de

    2010-07-31

    The project which extended from November 2005 to May of 2010 demonstrated the application of Low Temperature Combustion (LTC) with engine out NOx levels of 0.2 g/bhp-hr throughout the program target load of 12.6bar BMEP. The project showed that the range of loads could be extended to 16.5bar BMEP, therefore matching the reference lug line of the base 2007 MY Navistar 6.4L V8 engine. Results showed that the application of LTC provided a dramatic improvement over engine out emissions when compared to the base engine. Furthermore LTC improved thermal efficiency by over 5% from the base production engine when using the steady state 13 mode composite test as a benchmark. The key enablers included improvements in the air, fuel injection, and cooling systems made in Phases I and II. The outcome was the product of a careful integration of each component under an intelligent control system. The engine hardware provided the conditions to support LTC and the controller provided the necessary robustness for a stable combustion. Phase III provided a detailed account on the injection strategy used to meet the high load requirements. During this phase, the control strategy was implemented in a production automotive grade ECU to perform cycle-by-cycle combustion feedback on each of the engine cylinders. The control interacted on a cycle base with the injection system and with the Turbo-EGR systems according to their respective time constants. The result was a unique system that could, first, help optimize the combustion system and maintain high efficiency, and secondly, extend the steady state results to the transient mode of operation. The engine was upgraded in Phase IV with a Variable Valve Actuation system and a hybrid EGR loop. The impact of the more versatile EGR loop did not provide significant advantages, however the application of VVA proved to be an enabler to further extend the operation of LTC and gain considerable benefits in fuel economy and soot reduction. Finally, the transient demonstration was performed in Phase IV. The project demonstrated the achievement of meeting US10 emissions without NOx aftertreatment. The successful execution of the project has served to highlight the effectiveness of closely matched combustion predictive tools to engine testing. It has further served to highlight the importance of key technologies and future areas of research and development. In this regard, recommendations are made towards further improvements in the areas of engine hardware, fuel injection systems, controls and fuels.

  18. Low and High Temperature Combustion Chemistry of Butanol Isomers in Premixed Flames and Autoignition Systems

    SciTech Connect (OSTI)

    Sarathy, S M; Pitz, W J; Westbrook, C K; Mehl, M; Yasunaga, K; Curran, H J; Tsujimura, T; Osswald, P; Kohse-Hoinghaus, K

    2010-12-12

    Butanol is a fuel that has been proposed as a bio-derived alternative to conventional petroleum derived fuels. The structural isomer in traditional 'bio-butanol' fuel is n-butanol, but newer conversion technologies produce iso-butanol as a fuel. In order to better understand the combustion chemistry of bio-butanol, this study presents a comprehensive chemical kinetic model for all the four isomers of butanol (e.g., 1-, 2-, iso- and tert-butanol). The proposed model includes detailed high temperature and low temperature reaction pathways. In this study, the primary experimental validation target for the model is premixed flat low-pressure flame species profiles obtained using molecular beam mass spectrometry (MBMS). The model is also validated against previously published data for premixed flame velocity and n-butanol rapid compression machine and shock tube ignition delay. The agreement with these data sets is reasonably good. The dominant reaction pathways at the various pressures and temperatures studied are elucidated. At low temperature conditions, we found that the reaction of alphahydroxybutyl with O{sub 2} was important in controlling the reactivity of the system, and for correctly predicting C{sub 4} aldehyde profiles in low pressure premixed flames. Enol-keto isomerization reactions assisted by HO{sub 2} were also found to be important in converting enols to aldehydes and ketones in the low pressure premixed flames. In the paper, we describe how the structural features of the four different butanol isomers lead to differences in the combustion properties of each isomer.

  19. Materials Properties Database for Selection of High-Temperature Alloys and Concepts of Alloy Design for SOFC Applications

    SciTech Connect (OSTI)

    Yang, Z Gary; Paxton, Dean M.; Weil, K. Scott; Stevenson, Jeffry W.; Singh, Prabhakar

    2002-11-24

    To serve as an interconnect / gas separator in an SOFC stack, an alloy should demonstrate the ability to provide (i) bulk and surface stability against oxidation and corrosion during prolonged exposure to the fuel cell environment, (ii) thermal expansion compatibility with the other stack components, (iii) chemical compatibility with adjacent stack components, (iv) high electrical conductivity of the surface reaction products, (v) mechanical reliability and durability at cell exposure conditions, (vii) good manufacturability, processability and fabricability, and (viii) cost effectiveness. As the first step of this approach, a composition and property database was compiled for high temperature alloys in order to assist in determining which alloys offer the most promise for SOFC interconnect applications in terms of oxidation and corrosion resistance. The high temperature alloys of interest included Ni-, Fe-, Co-base superal

  20. Metagenomes from high-temperature chemotrophic systems reveal geochemical controls on microbial community structure and function

    SciTech Connect (OSTI)

    Frank Roberto

    2010-03-01

    The Yellowstone caldera contains the most numerous and diverse geothermal systems on Earth, yielding an extensive array of unique high-temperature environments that host numerous deeply-rooted and understudied Archaea, Bacteria and Eukarya. The combination of extreme temperature and chemical conditions encountered in geothermal environments often results in considerably less microbial diversity than other terrestrial habitats and offers a tremendous opportunity for studying the structure and function of indigenous microbial communities and for establishing linkages between putative metabolisms and element cycling. Metagenome sequence (14-15,000 Sanger reads per site) was obtained for five high-temperature (> 65 oC) chemotrophic microbial communities sampled from geothermal springs (or pools) in Yellowstone National Park (YNP) that exhibit a wide range in geochemistry including pH, dissolved sulfide, dissolved O2 and ferrous Fe. Metagenome data revealed significant differences in the predominant phyla associated with each of these geochemical environments. Novel members of the Sulfolobales are dominant in low pH environments, while other Crenarchaeota including distantly-related Thermoproteales and Desulfurococcales populations dominate in suboxic sulfidic sediments. Several novel archaeal groups are well represented in an acidic (pH 3) Fe-oxyhydroxide mat, where a higher O2 influx is accompanied with an increase in archaeal diversity. The presence or absence of genes and pathways important in S oxidation-reduction, H2-oxidation, and aerobic respiration (terminal oxidation) provide insight regarding the metabolic strategies of indigenous organisms present in geothermal systems. Multiple-pathway and protein-specific functional analysis of metagenome sequence data corroborated results from phylogenetic analyses and clearly demonstrate major differences in metabolic potential across sites. The distribution of functional genes involved in electron transport is consistent with the hypothesis that geochemical parameters (e.g., pH, sulfide, Fe, O2) control microbial community structure and function in YNP geothermal springs.