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Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
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1

Thermal stability of high temperature structural alloys  

SciTech Connect

High temperature structural alloys were evaluated for suitability for long term operation at elevated temperatures. The effect of elevated temperature exposure on the microstructure and mechanical properties of a number of alloys was characterized. Fe-based alloys (330 stainless steel, 800H, and mechanically alloyed MA 956), and Ni-based alloys (Hastelloy X, Haynes 230, Alloy 718, and mechanically alloyed MA 758) were evaluated for room temperature tensile and impact toughness properties after exposure at 750 C for 10,000 hours. Of the Fe-based alloys evaluated, 330 stainless steel and 800H showed secondary carbide (M{sub 23}C{sub 6}) precipitation and a corresponding reduction in ductility and toughness as compared to the as-received condition. Within the group of Ni-based alloys tested, Alloy 718 showed the most dramatic structure change as it formed delta phase during 10,000 hours of exposure at 750 C with significant reductions in strength, ductility, and toughness. Haynes 230 and Hastelloy X showed significant M{sub 23}C{sub 6} carbide precipitation and a resulting reduction in ductility and toughness. Haynes 230 was also evaluated after 10,000 hours of exposure at 850, 950, and 1050 C. For the 750--950 C exposures the M{sub 23}C{sub 6} carbides in Haynes 230 coarsened. This resulted in large reductions in impact strength and ductility for the 750, 850 and 950 C specimens. The 1050 C exposure specimens showed the resolution of M{sub 23}C{sub 6} secondary carbides, and mechanical properties similar to the as-received solution annealed condition.

Jordan, C.E.; Rasefske, R.K.; Castagna, A. [Lockheed Martin Corp., Schenectady, NY (United States)

1999-03-01T23:59:59.000Z

2

High-Temperature Aluminum Alloys | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting pm044smith2012o.pdf More Documents & Publications High-Temperature Aluminum Alloys Vehicle...

3

CoNiGa High Temperature Shape Memory Alloys  

E-Print Network (OSTI)

commercially successful SMAs such as NiTi and Cu-based alloys. In recent years, the CoNiGa system has emerged as a new ferromagnetic shape memory alloy with some compositions exhibiting high martensitic transformation temperatures which makes CoNiGa a potential...

Dogan, Ebubekir

2011-10-21T23:59:59.000Z

4

Computational and Experimental Development of Novel High-Temperature Alloys  

NLE Websites -- All DOE Office Websites (Extended Search)

Development of Novel High-Temperature Alloys Background The need for fossil-fueled power plants to run cleaner and more efficiently leads toward ever-higher operating temperatures and pressures. Gas turbines, which can be fueled by natural gas, synthetic gas (syngas), or a high-hydrogen stream derived from coal, are critical components in this development. High-temperature operation of turbines is generally achieved by using nickel-chrome superalloys with coatings

5

TEMPERATURE DEPENDENCE OF ELECTRICAL RESISTIVITY IN HIGHLY RESISTIVE ALLOYS  

E-Print Network (OSTI)

L-323 TEMPERATURE DEPENDENCE OF ELECTRICAL RESISTIVITY IN HIGHLY RESISTIVE ALLOYS F. BROUERS at finite temperature yields an expression for the resistivity which is consistent with a gene- ral analysis-dependence of the resistivity and appears as an alternative model to describe the resistivity of crystalline, liquid

Boyer, Edmond

6

Improved high temperature creep resistant austenitic alloy  

DOE Patents (OSTI)

An improved austenitic alloy having in wt% 19-21 Cr, 30-35 Ni, 1.5-2.5 Mn, 2-3 Mo, 0.1-0.4 Si, 0.3-0.5 Ti, 0.1-0.3 Nb, 0.1-0.5 V, 0.001-0.005 P, 0.08-0.12 C, 0.01-0.03 N, 0.005-0.01 B and the balance iron that is further improved by annealing for up to 1 hour at 1150-1200/degree/C and then cold deforming 5-15%. The alloy exhibits dramatically improved creep rupture resistance and ductility at 700/degree/C. 2 figs.

Maziasz, P.J.; Swindeman, R.W.; Goodwin, G.M.

1988-05-13T23:59:59.000Z

7

Amorphous Alloy Membranes for High Temperature Hydrogen Separation  

SciTech Connect

At the beginning of this project, thin film amorphous alloy membranes were considered a nascent but promising new technology for industrial-scale hydrogen gas separations from coal- derived syngas. This project used a combination of theoretical modeling, advanced physical vapor deposition fabricating, and laboratory and gasifier testing to develop amorphous alloy membranes that had the potential to meet Department of Energy (DOE) targets in the testing strategies outlined in the NETL Membrane Test Protocol. The project is complete with Southwest Research Institute (SwRI), Georgia Institute of Technology (GT), and Western Research Institute (WRI) having all operated independently and concurrently. GT studied the hydrogen transport properties of several amorphous alloys and found that ZrCu and ZrCuTi were the most promising candidates. GT also evaluated the hydrogen transport properties of V, Nb and Ta membranes coated with different transition-metal carbides (TMCs) (TM = Ti, Hf, Zr) catalytic layers by employing first-principles calculations together with statistical mechanics methods and determined that TiC was the most promising material to provide catalytic hydrogen dissociation. SwRI developed magnetron coating techniques to deposit a range of amorphous alloys onto both porous discs and tubular substrates. Unfortunately none of the amorphous alloys could be deposited without pinhole defects that undermined the selectivity of the membranes. WRI tested the thermal properties of the ZrCu and ZrNi alloys and found that under reducing environments the upper temperature limit of operation without recrystallization is ~250 C. There were four publications generated from this project with two additional manuscripts in progress and six presentations were made at national and international technical conferences. The combination of the pinhole defects and the lack of high temperature stability make the theoretically identified most promising candidate amorphous alloys unsuitable for application as hydrogen separation membranes in coal fire systems.

Coulter, K

2013-09-30T23:59:59.000Z

8

High-temperature Hydrogen Permeation in Nickel Alloys  

SciTech Connect

In gas cooled Very High Temperature Reactor concepts, tritium is produced as a tertiary fission product and by activation of graphite core contaminants, such as lithium; of the helium isotope, He-3, that is naturally present in the He gas coolant; and the boron in the B4C burnable poison. Because of its high mobility at the reactor outlet temperatures, tritium poses a risk of permeating through the walls of the intermediate heat exchanger (IHX) or steam generator (SG) systems, potentially contaminating the environment and in particular the hydrogen product when the reactor heat is utilized in connection with a hydrogen generation plant. An experiment to measure tritium permeation in structural materials at temperatures up to 1000 C has been constructed at the Idaho National Laboratory Safety and Tritium Applied Research (STAR) facility within the Next Generation Nuclear Plant program. The design is based on two counter flowing helium loops to represent heat exchanger conditions and was optimized to allow control of the materials surface condition and the investigation of the effects of thermal fatigue. In the ongoing campaign three nickel alloys are being considered because of their high-temperature creep properties, alloy 617, 800H and 230. This paper introduces the general issues related to tritium in the on-going assessment of gas cooled VHTR systems fission product transport and outlines the planned research activities in this area; outlines the features and capabilities of the experimental facility being operated at INL; presents and discusses the initial results of hydrogen permeability measurements in two of the selected alloys and compares them with the available database from previous studies.

P. Calderoni; M. Ebner; R. Pawelko

2010-10-01T23:59:59.000Z

9

High pressure/high temperature hydrogen permeability in candidate stirling engine alloys  

Science Journals Connector (OSTI)

Hydrogen permeation tests of eight high-temperature engineering alloys were conducted in 20.7 MPa hydrogen at 923 to 1088 K for assessing suitability in Stirling engine application for heater head and heater head...

S. Bhattacharyya; E. J. Vesely; V. L. Hill

1982-03-01T23:59:59.000Z

10

Thermomechanical Cyclic Response of TiNiPd High-Temperature Shape Memory Alloys  

E-Print Network (OSTI)

TiNiPd high-temperature shape memory alloys (HTSMAs) have attracted considerable attention as potential solid-state actuators capable of operating at temperatures up to 500 C, exhibiting excellent corrosion resistance, adequate ductility levels...

Atli, Kadri

2012-10-19T23:59:59.000Z

11

High Temperature Corrosion Behavior of Iron Aluminide Alloys and Coatings  

SciTech Connect

A multi-year effort has been focused on optimizing the long-term oxidation performance of ingot-processed (IP) and oxide-dispersion strengthened (ODS) Fe{sub 3}Al and iron aluminide-based coatings. Based on results from several composition iterations, a Hf-doped alloy (Fe-28Al-2Cr-0.05at.%Hf) has been developed with significantly better high temperature oxidation resistance than other iron aluminides. The scale adhesion is not significantly better; however, the {alpha}-Al{sub 2}O{sub 3} scale grows at a slower rate, approximately a factor of 10 less than undoped iron aluminide. The benefit of Hf is greatest at 1100-1200 C. Long-term oxidation resistance of commercially fabricated ODS Fe{sub 3}Al has been determined and compared to commercially available ODS FeCrAl. Scale spallation rates for ODS Fe{sub 3}Al are higher than for ODS FeCrAl. To complement studies of iron-aluminide weld-overlay coatings, carbon steel was coated with Fe-Al-Cr by thermal spraying. These specimens were then exposed in air at 900 and 1000 C and in air-1%SO{sub 2} at 800 C. Most likely due to an inadequate aluminum concentration in the coatings, continuous protective Al{sub 2}O{sub 3} could not be maintained and, consequently, the corrosion performance was significantly worse than what is normally observed for Fe{sub 3}Al.

Pint, B.A.

2001-10-22T23:59:59.000Z

12

Two-phase chromium-niobium alloys exhibiting improved mechanical properties at high temperatures  

DOE Patents (OSTI)

The specification discloses chromium-niobium alloys which exhibit improved mechanical properties at high temperatures in the range of 1250.degree. C. and improved room temperature ductility. The alloys contain a Cr.sub.2 Nb-rich intermetallic phase and a Cr-rich phase with an overall niobium concentration in the range of from about 5 to about 18 at. %. The high temperature strength is substantially greater than that of state of the art nickel-based superalloys for enhanced high temperature service. Further improvements in the properties of the compositions are obtained by alloying with rhenium and aluminum; and additional rare-earth and other elements.

Liu, Chain T. (Oak Ridge, TN); Takeyama, Masao (Tokyo, JP)

1994-01-01T23:59:59.000Z

13

Two-phase chromium-niobium alloys exhibiting improved mechanical properties at high temperatures  

DOE Patents (OSTI)

The specification discloses chromium-niobium alloys which exhibit improved mechanical properties at high temperatures in the range of 1250 C and improved room temperature ductility. The alloys contain a Cr[sub 2]Nb-rich intermetallic phase and a Cr-rich phase with an overall niobium concentration in the range of from about 5 to about 18 at. %. The high temperature strength is substantially greater than that of state of the art nickel-based superalloys for enhanced high temperature service. Further improvements in the properties of the compositions are obtained by alloying with rhenium and aluminum; and additional rare-earth and other elements. 14 figures.

Liu, C.T.; Takeyama, Masao.

1994-02-01T23:59:59.000Z

14

Evaluation of High-Temperature Alloys for Helium Gas Turbines  

Science Journals Connector (OSTI)

C. 1. Mechanical Property / Status of Metallic Materials Development for Application in Advanced High-Temperature Gas-Cooled Reactor / Material

Wolfgang Jakobeit; Jrn-Peter Pfeifer; Georg Ullrich

15

Pitting resistance of Alloy 800 as a function of temperature and prefilming in high temperature water  

SciTech Connect

The pitting behavior of Alloy 800 was investigated as a function of temperature and prefilming in high temperature water. The pitting behavior was characterized in terms of the pitting potential and the pit density. The pitting potential decreases with increasing temperature and chloride activity. Prefilming of test coupons over a time period between 100 and 5,000 hours in ammoniated water at 300 C has no apparent influence on the pitting potential at room temperature, 180 C and 300 C. However, the number of pits in prefilmed coupons is much higher than in coupons covered with an air passive layer. The effect of prefilming on pit nucleation was investigated in more detail with regard to a model and test methods developed by Bianchi and co-workers. Density of pits in prefilmed coupons is at least one order of magnitude higher than in air passive coupons. Maximum pit density was measured after a prefilming period of 1 00 hours. The effect is discussed in terms of Bianchi`s model and in terms of features of passive films. It is outlined that the initially amorphous metastable passive film on Alloy 800 becomes crystalline at increased temperatures. Crystallization induces lattice defects, such as dislocations and grain boundaries, in the passive film. The film grows and slowly transforms into a thick oxide layer. The transformation process is associated with enhanced susceptibility to pit nucleation.

Stellwag, B. [Siemens Power Generation, Erlangen (Germany)

1995-12-31T23:59:59.000Z

16

Computational Thermodynamics of CoNiGa High Temperature Shape Memory Alloys  

E-Print Network (OSTI)

Shape Memory Alloys (SMAs) are advanced materials with interesting properties such as pseudoelasticity (PE) and the shape memory effect (SME). Recently, the CoNiGa system has emerged as the basis for very promising High Temperature Shape Memory...

Chari, Arpita

2012-10-19T23:59:59.000Z

17

Iron-niobium-aluminum alloy having high-temperature corrosion resistance  

DOE Patents (OSTI)

An alloy for use in high temperature sulfur and oxygen containing environments, having aluminum for oxygen resistance, niobium for sulfur resistance and the balance iron, is discussed. 4 figs., 2 tabs.

Hsu, Huey S.

1988-04-14T23:59:59.000Z

18

Copper modified austenitic stainless steel alloys with improved high temperature creep resistance  

DOE Patents (OSTI)

An improved austenitic stainless steel that incorporates copper into a base Fe-Ni-Cr alloy having minor alloying substituents of Mo, Mn, Si, T, Nb, V, C, N, P, B which exhibits significant improvement in high temperature creep resistance over previous steels. 3 figs.

Swindeman, R.W.; Maziasz, P.J.

1987-04-28T23:59:59.000Z

19

Amorphous Alloy Membranes for High Temperature Hydrogen Separations  

NLE Websites -- All DOE Office Websites (Extended Search)

for High for High Temperature Hydrogen Separations Background Coal and biomass are readily available in the United States and can be mixed for thermal processing to produce hydrogen and power. The produced hydrogen can be sent directly to a fuel cell for highly efficient and environmentally clean power generation. For coal and biomass to become economically viable sources of hydrogen, more efficient production processes need to be developed. To meet this

20

High Temperature Oxidation of Iron-Chromium Alloys  

E-Print Network (OSTI)

and Peter H. Larsen for many good discussions during the work. #12;3 Abstract The high temperature oxidation: References: Abstract (max. 2000 char.): See page 3 Information Service Department Risø National Laboratory P of Southern Denmark. The majority of the work is based on studies performed at the SOFC group at the Materials

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Advanced Alloys for Compact, High-Efficiency, High-Temperature Heat-Exchangers  

SciTech Connect

Oak Ridge National Laboratory (ORNL) has conducted research and development for several years which has been focused on the behavior and performance improvements of sheets and foils of various alloys for compact heat-exchangers (recuperators) for advanced microturbines. The performance and reliability of such thin sections are challenged at 650-750 C by fine grain size causing excessive creep, and by moisture effects greatly enhancing oxidation attack in exhaust gas environments. Standard 347 stainless steel has been used successfully at or below 600 C, but has suffered from both of these kinds of degradation at 650 C and above. Alloys have been identified which can have very good properties for such heat-exchangers, especially with careful control of microstructure during processing, including alloy 625, HR120 and the new AL20-25+Nb. These alloys, and the mechanistic understanding behind their behavior, are also applicable to achieving the better heat-exchanger technology needed for fuel cells or other high-temperature, clean-energy applications.

Maziasz, Philip J [ORNL; Pint, Bruce A [ORNL; Shingledecker, John P [ORNL; Evans, Neal D [ORNL; Yamamoto, Yukinori [ORNL; More, Karren Leslie [ORNL; Lara-Curzio, Edgar [ORNL

2006-01-01T23:59:59.000Z

22

Candidate alloys for cost-effective, high-efficiency, high-temperature compact/foil heat-exchangers  

SciTech Connect

Solid oxide fuel cell (SOFC) and molten carbonate fuel cell (MCFC) systems operate at high temperatures (up to 1000 C and 650 C, respectively), which makes them especially attractive sources for combined heat and power (CHP) cogeneration. However, improvements in the efficiency of heat exchange in these fuel cells require both development and careful processing of advanced cost-effective alloys for use in such high-temperature service conditions. The high-temperature properties of both sheet and foil forms of several alloys being considered for use in compact heat-exchangers (recuperators) have been characterized. Mechanical and creep-rupture testing, oxidation studies, and microstructural studies have been performed on commercially available sheet and foil forms of alloy 347, alloys 625, HR230, HR120, and the new AL20-25+Nb. These studies have led to a mechanistic understanding of the responses of these alloys to anticipated service conditions, and suggest that these alloys developed for gas- and micro-turbine recuperator applications are also suitable for use in fuel cell heat-exchangers. Additional work is still required to achieve foil forms with creep life comparable to thicker-section wrought product forms of the same alloys.

Evans, Neal D [ORNL; Maziasz, Philip J [ORNL; Shingledecker, John P [ORNL; Pint, Bruce A [ORNL; Yamamoto, Yukinori [ORNL

2007-01-01T23:59:59.000Z

23

Corrosion and Creep of Candidate Alloys in High Temperature Helium and Steam Environments for the NGNP  

SciTech Connect

This project aims to understand the processes by which candidate materials degrade in He and supercritical water/steam environments characteristic of the current NGNP design. We will focus on understanding the roles of temperature, and carbon and oxygen potential in the 750-850 degree C range on both uniform oxidation and selective internal oxidation along grain boundaries in alloys 617 and 800H in supercritical water in the temperature range 500-600 degree C; and examining the application of static and cyclic stresses in combination with impure He environments in the temperature rang 750-850 degree C; and examining the application of static and cyclic stresses in combination with impure He environments in the temperature range 750-850 degree C over a range of oxygen and carbon potentials in helium. Combined, these studies wil elucidate the potential high damage rate processes in environments and alloys relevant to the NGNP.

Was, Gary; Jones, J. W.

2013-06-21T23:59:59.000Z

24

High temperature solder alloys for underhood applications: Final report  

SciTech Connect

In this continued study, the microstructural evolution and peel strength as a function of thermal aging were evaluated for four Sn-Ag solders deposited on double layered Ag-Pt metallization. Additionally, activation energies for intermetallic growth over the temperature range of 134 to 190{degrees}C were obtained through thickness measurements of the Ag-Sn intermetallic that formed at the solder-metallization interface. It was found that Bi-containing solders yielded higher activation energies for the intermetallic growth, leading to thicker intermetallic layers at 175 and 190{degrees}C for times of 542 and 20.5 hrs, respectively, than the solders free of Bi. Complete reaction of the solder with the metallization occurred and lower peel strengths were measured on the Bi-containing solders. In all solder systems, a Ag-Sn intermetallic thickness of greater than {approximately}7 {mu}m contributed to lower peel strength values. The Ag-Sn binary eutectic composition and the Ag-Sn-Cu ternary eutectic composition solders yielded lower activation energies for intermetallic formation, less microstructural change with time, and higher peel strengths; these solder systems were resilient to the effects of temperatures up to 175{degrees}C. Accelerated isothermal aging studies provide useful criteria for recommendation of materials systems. The Sn-Ag and Sn-Ag-Cu eutectic compositions should be considered for future service life and reliability studies based upon their performance in this study.

Kern, J.A. [Univ. of New Mexico, Albuquerque, NM (United States). Dept. of Mechanical Engineering; Drewien, C.A.; Yost, F.G.; Sackinger, S. [Sandia National Laboratories, Albuquerque, NM (United States); Weiser, M.W. [Johnson-Mathey Electronics Corp., Spokane, WA (United States)

1996-06-01T23:59:59.000Z

25

Mechanical properties of welds in commercial alloys for high-temperature gas-cooled reactor components  

SciTech Connect

Weld properties of Hastelloy-X, Incoloy alloy 800H (with and without Inconel-82 cladding), and 2 1/4 Cr-1 Mo are being studied to provide design data to support the development of steam generator, core auxiliary heat exchanger, and metallic thermal barrier components of the high-temperature gas-cooled reactor (HTGR) steam cycle/cogeneration plant. Tests performed include elevated-temperature creep rupture tests and tensile tests. So far, data from the literature and from relatively short-term tests at GA Technologies Inc. indicate that the weldments are satisfactory for HTGR application.

Lindgren, J.R.; Li, C.C.; Ryder, R.H.; Thurgood, B.E.

1984-07-01T23:59:59.000Z

26

A View of Compatible Heat-Resistant Alloy and Coating Systems at High-Temperatures  

SciTech Connect

Conventional and advanced coatings were reviewed, and it was pointed out that the coated Ni-base superalloys decreased their creep rupture life significantly at higher temperatures, and the advanced high strength superalloy became more remarkably. Concept of diffusion barrier coating system (DBC system) and their formation process was introduced, and the results obtained for several heat-resistant alloys, stainless steel (SUS310S), Ni-Mo base alloy (Hastelloy-X), and 4{sup th} generation single crystal superalloy (TMS-138) were given. It was noted that creep-rupture life of the SUS310S and Hastelloy-X with the DBC system became longer than those of the bare alloys with or without conventional {beta}-NiAl coatings. This is due to slow creep-deformation of the Re-base alloy layer as the diffusion barrier. A novel concept based on combination of superalloys and coatings was proposed, by taking both the materials science and corrosion science into consideration.

Narita, Toshio [Specially Promoted Research Laboratory of Advanced Coatings, Hokkaido University, Kite-13 Nishi-8, Kita-Ku, Sapporo 060-8628 (Japan)

2009-09-14T23:59:59.000Z

27

Microstructure and High Temperature Oxidation Behavior of Cr-W Alloys  

SciTech Connect

Cr alloys containing 0-30%W by weight were investigated for use in elevated temperature applications. The alloys were melted in a water-cooled, copper-hearth arc furnace. Microstructure of the alloys was characterized using x-ray diffraction, scanning electron microscopy, and light microscopy. A pseudocyclic oxidation test was employed to study scale formation at 1000C in dry air. The scale was predominantly chromia and spalled upon cooling. Alloying with aluminum up to 8 weight percent reduced the spalling drastically. Furthermore, aluminizing the surface of the Cr-W alloys completely stopped the spalling.

Dogan, O.N.

2007-02-01T23:59:59.000Z

28

Solid state thin film battery having a high temperature lithium alloy anode  

DOE Patents (OSTI)

An improved rechargeable thin-film lithium battery involves the provision of a higher melting temperature lithium anode. Lithium is alloyed with a suitable solute element to elevate the melting point of the anode to withstand moderately elevated temperatures.

Hobson, David O. (Oak Ridge, TN)

1998-01-01T23:59:59.000Z

29

Fusion neutron irradiation of Ni(Si) alloys at high temperature  

SciTech Connect

Two Ni-4% Si alloys, with different cold work levels, are irradiated with 14 MeV fusion neutrons at 623 K, and their Curie temperatures are monitored during irradiation. The results are compared to those of an identical alloy irradiated by 2 MeV electrons. The results show that increasing dislocation density increases the Curie temperature change rate. At the same damage rate, the Curie temperature change rate for the alloy irradiated by 14 MeV fusion neutrons is only 6 to 7% of that for an identical alloy irradiated by 2 MeV electrons. It is well known that the migration of radiation induced defects contributes to segregation of silicon atoms at sinks in this alloy, causing the Curie temperature changes. The current results imply that the relative free defect production efficiency decreases from one for the electron irradiated sample to 6 to 7% for the fusion neutron irradiated sample. 17 refs., 4 figs., 1 tab.

Huang, J.S.; Guinan, M.W.; Hahn, P.A.

1987-09-01T23:59:59.000Z

30

Pitting resistance of alloy 800 as a function of temperature and prefilming in high-temperature water  

SciTech Connect

Pitting behavior of alloy 800 was investigated as a function of temperature and prefilming in high-temperature water. The behavior was characterized in terms of pitting potential (U{sub p}) and pit density (n{sub p}). U{sub p} decreased with increasing temperature and chloride activity. Prefilming of test coupons over a period between 100 h and 5,000 h in ammoniated water at 300 C had no apparent influence on U{sub p} at room temperature, 180 C, and 300 C. However, the number of pits in prefilmed coupons was much higher than in coupons covered with an air passive layer. The effect of prefilming on pit nucleation was investigated in detail with regard to a model and test methods developed by Bianchi, et al. Density of pits in prefilmed coupons was at least 1 order of magnitude higher than in air passive coupons. Maximum pit density was measured after a prefilming period of 100 h. The effect was discussed in terms of Bianchi`s model and in terms of features of passive films. The initially amorphous metastable passive film on alloy 800 became crystalline at increased temperatures. Crystallization induced lattice defects, such as dislocations and grain boundaries, in the passive film. The film grew and slowly transformed into a thick oxide layer. The transformation process was associated with enhanced susceptibility to pit nucleation.

Stellwag, B. [Siemens Power Generation, Erlangen (Germany)

1997-02-01T23:59:59.000Z

31

Iron-aluminum alloys having high room-temperature and method for making same  

DOE Patents (OSTI)

A wrought and annealed iron-aluminum alloy is described consisting essentially of 8 to 9.5% aluminum, an effective amount of chromium sufficient to promote resistance to aqueous corrosion of the alloy, and an alloying constituent selected from the group of elements consisting of an effective amount of molybdenum sufficient to promote solution hardening of the alloy and resistance of the alloy to pitting when exposed to solutions containing chloride, up to about 0.05% carbon with up to about 0.5% of a carbide former which combines with the carbon to form carbides for controlling grain growth at elevated temperatures, and mixtures thereof, and the balance iron, wherein said alloy has a single disordered [alpha] phase crystal structure, is substantially non-susceptible to hydrogen embrittlement, and has a room-temperature ductility of greater than 20%.

Sikka, V.K.; McKamey, C.G.

1993-08-24T23:59:59.000Z

32

Solid State Joining of High Temperature Alloy Tubes for USC and Heat-Exchanger Systems  

SciTech Connect

The principal objective of this project was to develop materials enabling joining technologies for use in forward looking heat-exchanger fabrication in Brayton cycle HIPPS, IGCC, FutureGen concepts capable of operating at temperatures in excess of 1000{degree}C as well as conventional technology upgrades via Ultra Super-Critical (USC) Rankine-cycle boilers capable of operating at 760{degree}C (1400F)/38.5MPa (5500psi) steam, while still using coal as the principal fossil fuel. The underlying mission in Rankine, Brayton or Brayton-Rankine, or IGCC combined cycle heat engine is a steady quest to improving operating efficiency while mitigating global environmental concerns. There has been a progressive move to higher overall cycle efficiencies, and in the case of fossil fuels this has accelerated recently in part because of concerns about greenhouse gas emissions, notably CO{sub 2}. For a heat engine, the overall efficiency is closely related to the difference between the highest temperature in the cycle and the lowest temperature. In most cases, efficiency gains are prompted by an increase in the high temperature, and this in turn has led to increasing demands on the materials of construction used in the high temperature end of the systems. Our migration to new advanced Ni-base and Oxide Dispersion Strengthened (ODS) alloys poses significant fabrication challenges, as these materials are not readily weldable or the weld performs poorly in the high temperature creep regime. Thus the joining challenge is two-fold to a) devise appropriate joining methodologies for similar/dissimilar Ni-base and ODS alloys while b) preserving the near baseline creep performance in the welded region. Our program focus is on solid state joining of similar and dissimilar metals/alloys for heat exchanger components currently under consideration for the USC, HIPPS and IGCC power systems. The emphasis is to manipulate the joining methods and variables available to optimize joint creep performance compared to the base material creep performance. Similar and dissimilar butt joints were fabricated of MA956, IN740 alloys and using inertia welding techniques. We evaluated joining process details and heat treatments and its overall effect on creep response. Fixed and incrementally accelerated temperature creep tests were performed for similar and dissimilar joints and such incremental creep life data is compiled and reported. Long term MA956-MA556 joint tests indicate a firm 2Ksi creep stress threshold performance at 850{degree}C with a maximum exposure of over 9725 hours recorded in the current program. A Larsen Miller Parameter (LMP) of 48.50 for a 2Ksi test at 850{degree}C was further corroborated with tests at 2Ksi stress at 900{degree}C yielding a LMP=48.80. Despite this threshold the joints exhibit immense temperature sensitivity and fail promptly when test temperature raised above 900{degree}C. In comparison the performance of dissimilar joints was inferior, perhaps dictated by the creep characteristics of the mating nickel-base alloys. We describe a parametric window of joint development, and post weld heat treatment (PWHT) in dissimilar joints with solid solution (IN601, IN617) and precipitate strengthened (IN740) materials. Some concerns are evident regarding the diffusion of aluminum in dissimilar joints during high temperature recrystallization treatments. It is noted that aggressive treatments rapidly deplete the corrosion protecting aluminum reservoir in the vicinity of the joint interface. Subsequently, the impact of varying PWHT has been evaluated in the context on ensuing creep performance.

Bimal Kad

2011-12-31T23:59:59.000Z

33

Enhanced near net-shape ceramic refractory composite high temperature cartridge by VPS metallurgical alloying techniques  

SciTech Connect

High performance cartridges are being developed by vacuum plasma spray (VPS) forming to near net-shape for use in high temperature space furnaces. A VPS metallurgical alloying technique utilizing alloying elements (rhenium, nickel, etc.) has been developed that produces robust physical properties without jeopardizing the unique chemical properties of the VPS formed tungsten structure. Thin walled cartridges, 0.069 mm (0.027 in.) thick, are produced in continuous lengths of 58.4 cm (23 in.). A refractory metal (i.e. tungsten) is VPS formed as the cartridge wall structure, with a protective ceramic (i.e., alumina) coating inside and out. The ceramic-refractory-ceramic composite provides environmental protection to the refractory metal structure from both chemical attack inside and oxidation outside. The VPS metallurgical alloying process interjected during the spraying operation greatly reduces porosity of the microstructure while enhancing the ductility of the cartridge. Thin walled cartridges have been shown to hermetically seal demonstrating no through porosity. Microstructures have been characterized and material properties will be presented.

Krotz, P.D.; Liaw, Y.; McKechnie, T.N. [Rocketdyne, Huntsville, AL (United States); Holmes, R.; Zimmerman, F. [National Aeronautics and Space Administration, Huntsville, AL (United States). Marshall Space Flight Center

1995-12-31T23:59:59.000Z

34

Evaporation behavior of Hastelloy-X alloys in simulated very high temperature reactor environments  

SciTech Connect

A sequential analysis was made on the material degradations during exposure of nickel-base corrosionresistant austenitic alloys to simulated very high temperature reactor environments. The materials tested were two modified versions of Hastelloy-X in terms of both increased manganese content for improved compatibility and decreased manganese content for possible adverse effects. Quantitative analysis of the specimens after exposure for 1000 h at several temperature steps from 850 to 1050/sup 0/C have revealed the temperature-dependent aspects of the processes including the depletion of chromium and manganese due to oxidation, evaporation, and carbon transfer into and/or from the materials. The material with enriched manganese, developed and specified as Hastelloy-XR, showed enhanced resistance to loss of chromium in terms of both oxidation and evaporation.

Shindo, M.; Kondo, T.

1984-08-01T23:59:59.000Z

35

Corrosion of high temperature alloys in solar salt at 400, 500, and 680%C2%B0C.  

SciTech Connect

Corrosion tests at 400, 500, and 680%C2%B0C were performed using four high temperature alloys; 347SS, 321SS In625, and HA230. Molten salt chemistry was monitored over time through analysis of nitrite, carbonate, and dissolved metals. Metallography was performed on alloys at 500 and 680%C2%B0C, due to the relatively thin oxide scale observed at 400%C2%B0C. At 500%C2%B0C, corrosion of iron based alloys took the form of chromium depletion and iron oxides, while nickel based alloys also had chromium depletion and formation of NiO. Chromium was detected in relatively low concentrations at this temperature. At 680%C2%B0C, significant surface corrosion occurred with metal losses greater than 450microns/year after 1025hours of exposure. Iron based alloys formed complex iron, sodium, and chromium oxides. Some data suggests grain boundary chromium depletion of 321SS. Nickel alloys formed NiO and metallic nickel corrosion morphologies, with HA230 displaying significant internal oxidation in the form of chromia. Nickel alloys both exhibited worse corrosion than iron based alloys likely due to preferential dissolution of chromium, molybdenum, and tungsten.

Kruizenga, Alan Michael; Gill, David Dennis; LaFord, Marianne Elizabeth

2013-09-01T23:59:59.000Z

36

Development of High-Temperature Ferritic Alloys and Performance Prediction Methods for Advanced Fission Energy Systems  

SciTech Connect

Reports the results of a comprehensive development and analysis of a database on irradiation hardening and embrittlement of tempered martensitic steels (TMS). Alloy specific quantitative semi-empirical models were derived for the dpa dose, irradiation temperature (ti) and test (Tt) temperature of yield stress hardening (or softening) .

G. RObert Odette; Takuya Yamamoto

2009-08-14T23:59:59.000Z

37

Solid state thin film battery having a high temperature lithium alloy anode  

DOE Patents (OSTI)

An improved rechargeable thin-film lithium battery involves the provision of a higher melting temperature lithium anode. Lithium is alloyed with a suitable solute element to elevate the melting point of the anode to withstand moderately elevated temperatures. 2 figs.

Hobson, D.O.

1998-01-06T23:59:59.000Z

38

Effect of Acid Treatment on the High-Temperature Surface Oxidation Behavior of FeCrAlloy Foil Used for Methane Combustion Catalyst Support  

Science Journals Connector (OSTI)

The catalytic flameless combustion of low alkans improves the efficiency of energy production and reduces NOx emission. ... (3-5) Fe?Cr?Al alloy (FeCrAlloy) has superior stability to other iron-based alloys at high temperatures and has been used in the fabrication of gas burners, industrial heaters, and other high-temperature devices. ... The heating rate was 10 C/min. ...

Dong Zhang; Lihong Zhang; Bin Liang; Yongdan Li

2009-04-24T23:59:59.000Z

39

High emissivity coatings on titanium alloy prepared by micro-arc oxidation for high temperature application  

Science Journals Connector (OSTI)

Micro-arc oxidation coatings were prepared on Ti6Al4V alloy in...3PO4-based electrolyte with different additives such as FeSO4, Co(CH3COO)2, Ni(CH3COO)2, and K2ZrF6. The composition, structure, surface morphology...

H. Tang; Q. Sun; C. G. Yi; Z. H. Jiang; F. P. Wang

2012-03-01T23:59:59.000Z

40

Development of Advanced Corrosion-Resistant Fe-Cr-Ni Austenitic Stainless Steel Alloy with Improved High Temperature Strenth and Creep-Resistance  

SciTech Connect

In February of 1999, a Cooperative Research and Development Agreement (CRADA) was undertaken between Oak Ridge National Laboratory (ORNL) and Special Metals Corporation-Huntington Alloys (formerly INCO Alloys International, Inc.) to develop a modified wrought austenitic stainless alloy with considerably more strength and corrosion resistance than alloy 800H or 800HT, but with otherwise similar engineering and application characteristics. Alloy 800H and related alloys have extensive use in coal flue gas environments, as well as for tubing or structural components in chemical and petrochemical applications. The main concept of the project was make small, deliberate elemental microalloying additions to this Fe-based alloy to produce, with proper processing, fine stable carbide dispersions for enhanced high temperature creep-strength and rupture resistance, with similar or better oxidation/corrosion resistance. The project began with alloy 803, a Fe-25Cr-35NiTi,Nb alloy recently developed by INCO, as the base alloy for modification. Smaller commercial developmental alloy heats were produced by Special Metals. At the end of the project, three rounds of alloy development had produced a modified 803 alloy with significantly better creep resistance above 815EC (1500EC) than standard alloy 803 in the solution-annealed (SA) condition. The new upgraded 803 alloy also had the potential for a processing boost in that creep resistance for certain kinds of manufactured components that was not found in the standard alloy. The upgraded 803 alloy showed similar or slightly better oxidation and corrosion resistance relative to standard 803. Creep strength and oxidation/corrosion resistance of the upgraded 803 alloy were significantly better than found in alloy 800H, as originally intended. The CRADA was terminated in February 2003. A contributing factor was Special Metals Corporation being in Chapter 11 Bankruptcy. Additional testing, further commercial scale-up, and any potential invention disclosures were not pursued. One objective of this project was to improve the high temperature creep resistance of the recently developed 803 alloy, while another was to have a wrought modified 803 alloy with significantly better creep resistance and corrosion resistance than the commonly used alloy 800H. The project was intended to use the established expertise at ORNL to design specific microalloying element additions to appropriately tailor the microstructure during aging or creep so that fine, stable carbides develop for strength. If possible, oxidation/corrosion resistance at high temperatures would also be enhanced. Optimum processing was to be developed for plate and tube products.

Maziasz, PJ

2004-09-30T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

High strength alloys  

DOE Patents (OSTI)

High strength metal alloys are described herein. At least one composition of a metal alloy includes chromium, nickel, copper, manganese, silicon, niobium, tungsten and iron. System, methods, and heaters that include the high strength metal alloys are described herein. At least one heater system may include a canister at least partially made from material containing at least one of the metal alloys. At least one system for heating a subterranean formation may include a tubular that is at least partially made from a material containing at least one of the metal alloys.

Maziasz, Phillip James [Oak Ridge, TN; Shingledecker, John Paul [Knoxville, TN; Santella, Michael Leonard [Knoxville, TN; Schneibel, Joachim Hugo [Knoxville, TN; Sikka, Vinod Kumar [Oak Ridge, TN; Vinegar, Harold J [Bellaire, TX; John, Randy Carl [Houston, TX; Kim, Dong Sub [Sugar Land, TX

2010-08-31T23:59:59.000Z

42

High-temperature low-cycle fatigue and tensile properties of Hastelloy X and alloy 617 in air and HTGR-helium  

SciTech Connect

Results of strain controlled fatigue and tensile tests are presented for two nickel base solution hardened alloys which are reference structural alloys for use in several high temperature gas cooled reactor concepts. These alloys, Hastelloy X Inconel 617, were tested at temperatures ranging from room temperature to 871/sup 0/C in air and impure helium. Materials were tested in the solution annealed as well as in the pre-aged condition where aging consisted of isothermal exposure at one of several temperatures for periods of up to 20,000 h. Comparisons are also given between the strain controlled fatigue lives of these alloys and several other commonly used alloys all tested at 538/sup 0/C.

Strizak, J.P.; Brinkman, C.R.; Rittenhouse, P.L.

1981-01-01T23:59:59.000Z

43

High temperature (600 to 800/sup 0/C) thermally activated deformation behavior of. cap alpha. -Zircaloy-4-oxygen alloys. [DS  

SciTech Connect

The high temperature thermally activated deformation behavior of Zircaloy-4-oxygen alloys containing oxygen up to 1 wt % has been investigated. Decremental unloading technique (Dip technique) was employed to determine the internal stress (tau/sub ..mu../) and thus the effective stress (tau*). Strain rate change tests were done to determine strain rate sensitivity (m) and activation volume (V*). Activation energy (..delta..G/sup ..mu../) was calculated from the above data. Oxygen was found to produce an increase in y.s. (0.2%), tau* and ..delta..G/sub 0//sup ..mu../ and a decrease in m and V* while tau/sub ..mu../ was not affected significantly. These experimental results support the view that the predominant rate controlling mechanism for deformation in this temperature regime is the thermally activated breaking of attractive junctions for these alloys. Oxygen atoms, pairs or clusters of oxygen atoms, are ruled out as barriers, instead the strengthening is attributed to an increase in the core width of the dislocations due to the presence of oxygen. This in turn results in a more stable attractive junction, which is reflected in the increasing values of ..delta..G/sub 0//sup ..mu../ with the increase in oxygen. Finally it is suggested that the atypical temperature dependence of tau/sub ..mu..//..mu.. and ..delta..G/sup ..mu../ is a direct consequence of dynamic recovery.

Mehrotra, B.N.; Tangri, K.

1980-10-01T23:59:59.000Z

44

High-temperature corrosion of metallic alloys in an oxidizing atmosphere containing NaCl  

SciTech Connect

A particular heat-exchanger application involved metallic alloys exposed to flue gases of an aluminum remelt furnace. Because the flue gases might contain NaCl and other halides, the corrosion behavior of the alloys was to be investigated. Planned direct exposure of candidate alloys to the flue gases, however, was not conducted because of premature termination of the project. Complementary laboratory testing was conducted on seven commercially available alloys and two nickel aluminides. These materials were exposed to an oxidizing atmosphere containing 0.06 wt % NaCl for 1100 h at 1000/degree/C. Most of the alloy exhibited grain-boundary attack, which resulted in complete oxidation of enveloped grains. The alloys Incoloy MA-956, Incoloy 800, Inconel 625, Inconel 601, Hastelloy X, Haynes 188, and nickel aluminide IC-50 were substantially more corroded than Alloy 214 and nickel aluminide IC-221. The latter two alloys, therefore, would probably be superior to the others in application involving flue gases containing NaCl. Strength fabricability, and weldability, which are briefly discussed, would also affect selection of materials. 8 refs., 12 figs., 5 tabs.

Federer, J.I.

1989-02-01T23:59:59.000Z

45

Welding of dissimilar alloys for high temperature heat exchangers for SOFC  

SciTech Connect

Reduction in the cost of balance of plant applications is one of the top priority focus areas for the successful implementation of solid oxide fuel cell technology. High temperature heat exchangers are employed to heat cathode air utilizing either hot gases coming from the anode side of the stack or other hot gases generated by external processes. In order to reduce the cost of heat exchangers, it may be necessary to apply several different materials, each in a different temperature zone, for the construction of the heat exchanger. This technique would require the joining of dissimilar materials in the construction. In this work, welding of commercial candidate dissimilar materials is explored. Filler materials were identified using equilibrium phase diagrams and thermodynamic simulation software. Autogenous welding was performed and the welding defects were characterized. Finally, experimental weld microstructures were compared to phases predicted by the simulations.

Wilson, R.D.; Hatem, J.; Dogan, O.N.; King, P.E.

2006-10-01T23:59:59.000Z

46

Characteristics of lead induced stress corrosion cracking of alloy 690 in high temperature  

SciTech Connect

Slow strain rate tests (SSRT) were conducted on alloy 690 in various lead chloride solutions and metal lead added to 100 ppm chloride solution at 288 C. The corrosion potential (rest potential) for the alloy was measured with SSRT tests. The cracking was observed by metallographic examination and electron probe micro analyzer. Also, the corrosion behavior of the alloy was evaluated by anodic polarized measurement at 30 C. Resulting from the tests, cracking was characterized by cracking behavior, crack length and crack growth rate, and lead effects on cracking. The cracking was mainly intergranular in mode, approximately from 60 um to 450 um in crack length, and approximately 10{sup {minus}6} to 10{sup {minus}7} mmS-1 in crack velocity. The cracking was evaluated through the variation the corrosion potential in potential-time and lead behavior during SSRTs. The lead effect in corrosion was evaluated through active to passive transition behavior in anodic polarized curves. The corrosion reactions in the cracking region were confirmed by electron probe microanalysis. Alloy 690 is used for steam generation tubes in pressurized water reactors.

Chung, K.K. [Korea Inst. of Nuclear Safety, Taejon (Korea, Republic of); Lim, J.K. [Chonbuk National Univ., Chonju (Korea, Republic of); Watanabe, Yutaka; Shoji, Tetsuo [Tohoku Univ., Sendai (Japan). Research Inst. for Fracture Technology

1996-10-01T23:59:59.000Z

47

High temperature pressure gauge  

DOE Patents (OSTI)

A high temperature pressure gauge comprising a pressure gauge positioned in fluid communication with one end of a conduit which has a diaphragm mounted in its other end. The conduit is filled with a low melting metal alloy above the diaphragm for a portion of its length with a high temperature fluid being positioned in the remaining length of the conduit and in the pressure gauge.

Echtler, J. Paul (Pittsburgh, PA); Scandrol, Roy O. (Library, PA)

1981-01-01T23:59:59.000Z

48

Standard practice for evaluation of disbonding of bimetallic stainless alloy/steel plate for use in high-pressure, high-temperature refinery hydrogen service  

E-Print Network (OSTI)

1.1 This practice covers a procedure for the evaluation of disbonding of bimetallic stainless alloy/steel plate for use in refinery high-pressure/high-temperature (HP/HT) gaseous hydrogen service. It includes procedures to (1) produce suitable laboratory test specimens, (2) obtain hydrogen charging conditions in the laboratory that are similar to those found in refinery HP/HT hydrogen gas service for evaluation of bimetallic specimens exposed to these environments, and (3) perform analysis of the test data. The purpose of this practice is to allow for comparison of data among test laboratories on the resistance of bimetallic stainless alloy/steels to hydrogen-induced disbonding (HID). 1.2 This practice applies primarily to bimetallic products fabricated by weld overlay of stainless alloy onto a steel substrate. Most of the information developed using this practice has been obtained for such materials. The procedures described herein, may also be appropriate for evaluation of hot roll bonded, explosive bonded...

American Society for Testing and Materials. Philadelphia

2001-01-01T23:59:59.000Z

49

High-temperature oxidation of an alumina-coated Ni-base alloy  

SciTech Connect

Alumina coatings were applied to Ni-20Cr (wt%) using combustion chemical vapor deposition (combustion CVD). Combustion CVD is an open air deposition technique performed in a flame. The oxidation kinetics of coated and uncoated specimens were measured by isothermal oxidation tests carried out in pure flowing air at temperatures of 800, 900, 1,000 and 1,100 C. The alumina coatings reduced the oxidation kinetics at all temperatures. The morphologies and compositions of the alumina coatings were characterized by transmission and scanning electron microscopy, energy dispersive x-ray spectroscopy and x-ray photoelectron spectroscopy.

Hendrick, M.R.; Hampikian, J.M.; Carter, W.B.

1996-06-01T23:59:59.000Z

50

Friction Properties of Molybdenum Alloyed Steel at Elevated Temperatures  

SciTech Connect

The high-temperature properties of steel surface can be improved by molybdenum surface alloying. Molybdenzing was carried out on carbon steel in the multi-function double glow plasma surface alloying furnace. The friction and wear tests were conducted on a high temperature ball-on-disk tribometer under the temperature of 25 deg. C{approx}600 deg. C. The contents of alloy element varied with alloyed layer were detected by SEM attached with EDS. The molybdenized layer is composed of the deposited layer and diffused layer. The micro-hardness of alloyed layer decreases from HV650 on the top layer to HV240. The friction coefficient of molybdenized layer decreases from 0.5{approx}0.6 to 0.2{approx}0.3 and wear rate decreases by 20% at elevated temperature after molybdenizing.

Li Jianliang; Xiong Dangsheng [Department of Material Science and Engineering, Nanjing University of Science and Technology, Nanjing, 210094 (China); Wu Hongyan [College of Math and Physics, Nanjing University of Information and Technology, Nanjing, 210044 (China)

2011-01-17T23:59:59.000Z

51

Embrittlement of Stainless Steels and Nickel-Based Alloys at High Temperature Induced by Neutron Radiation  

Science Journals Connector (OSTI)

... not recovered15. Thus, the precipitation effects are not the prime cause of the embrittlement.Boron-10 appeared the most likely isotope because of its high thermal neutron cross-section. Rather ... metallurgical changes induced) a constant amount of boron was added in the form of either boron-10 or boron-11. Irradiation of these chemically and metallurgically similar steels clearly showed that ...

R. S. BARNES

1965-06-26T23:59:59.000Z

52

High Temperature Oxidation Behavior of gamma-Ni+gamma'-Ni3Al Alloys and Coatings Modified with Pt and Reactive Elements  

SciTech Connect

Materials for high-pressure turbine blades must be able to operate in the high-temperature gases (above 1000 C) emerging from the combustion chamber. Accordingly, the development of nickel-based superalloys has been constantly motivated by the need to have improved engine efficiency, reliability and service lifetime under the harsh conditions imposed by the turbine environment. However, the melting point of nickel (1455 C) provides a natural ceiling for the temperature capability of nickel-based superalloys. Thus, surface-engineered turbine components with modified diffusion coatings and overlay coatings are used. Theses coatings are capable of forming a compact and adherent oxide scale, which greatly impedes the further transport of reactants between the high-temperature gases and the underlying metal and thus reducing attack by the atmosphere. Typically, these coatings contain {beta}-NiAl as a principal constituent phase in order to have sufficient aluminum content to form an Al{sub 2}O{sub 3} scale at elevated temperatures. The drawbacks to the currently-used {beta}-based coatings, such as phase instabilities, associated stresses induced by such phase instabilities, and extensive coating/substrate interdiffusion, are major motivations in this study to seek next-generation coatings. The high-temperature oxidation resistance of novel Pt + Hf-modified {gamma}-Ni + {gamma}-Ni{sub 3}Al-based alloys and coatings were investigated in this study. Both early-stage and 4-days isothermal oxidation behavior of single-phase {gamma}-Ni and {gamma}{prime}-Ni{sub 3}Al alloys were assessed by examining the weight changes, oxide-scale structures, and elemental concentration profiles through the scales and subsurface alloy regions. It was found that Pt promotes Al{sub 2}O{sub 3} formation by suppressing the NiO growth on both {gamma}-Ni and {gamma}{prime}Ni{sub 3}Al single-phase alloys. This effect increases with increasing Pt content. Moreover, Pt exhibits this effect even at lower temperatures ({approx}970 C) in the very early stage of oxidation. It was also inferred that Pt enhances the diffusive flux of aluminum from the substrate to the scale/alloy interface. Relatively low levels of hafnium addition to Pt-free {gamma}{prime}-Ni{sub 3}Al increased the extent of external NiO formation due to non-protective HfO{sub 2} formation. Accordingly, this effect intensified with increasing Hf content from 0.2 to 0.5 at.%.

Nan Mu

2007-12-01T23:59:59.000Z

53

Mold, flow, and economic considerations in high temperature precision casting  

E-Print Network (OSTI)

Casting high temperature alloys that solidify through a noticeable two phase region, specifically platinum-ruthenium alloys, is a particularly challenging task due to their high melting temperature and this necessitates ...

Humbert, Matthew S

2013-01-01T23:59:59.000Z

54

A Metallic Alloy That is Tough and Ductile at Cryogenic Temperature...  

NLE Websites -- All DOE Office Websites (Extended Search)

A Metallic Alloy That is Tough and Ductile at Cryogenic Temperatures Researchers at Berkeley and Oak Ridge Labs Test a Multi-element High-Entropy Alloy with Surprising Results At...

55

Computer Simulation and Experimental Validation on the Oxidation and Sulfate Corrosion Resistance of Novel Chromium-Based High-temperature Alloys  

NLE Websites -- All DOE Office Websites (Extended Search)

Computer Simulation and Experimental Computer Simulation and Experimental Validation on the Oxidation and Sulfate Corrosion Resistance of Novel Chromium-Based High-temperature Alloys Background Advanced coal power generation is a critical component of the U.S. energy portfolio. The U.S. Department of Energy (DOE) is committed to supporting research that will increase the efficiency and decrease the environmental impact of coal-fired plants, thus enabling the long term use of a low cost domestic fuel source. One key factor to

56

Gas-Alloy Interactions at Elevated Temperatures  

SciTech Connect

The understanding of the stability of metals and alloys against oxidation and other detrimental reactions, to the catalysis of important chemical reactions and the minimization of defects associated with processing and synthesis have one thing in common: At the most fundamental level, all these scientific/engineering problems involve interactions between metals and alloys (in the solid or liquid state) and gaseous atmospheres at elevated temperatures. In this special issue, we have collected a series of articles that illustrate the application of different theoretical, computational, and experimental techniques to investigate gas-alloy interactions.

Arroyave, Raymundo; Gao, Michael

2012-12-01T23:59:59.000Z

57

High Temperatures & Electricity Demand  

E-Print Network (OSTI)

High Temperatures & Electricity Demand An Assessment of Supply Adequacy in California Trends.......................................................................................................1 HIGH TEMPERATURES AND ELECTRICITY DEMAND.....................................................................................................................7 SECTION I: HIGH TEMPERATURES AND ELECTRICITY DEMAND ..........................9 BACKGROUND

58

Deformation behavior of laser welds in high temperature oxidation resistant FeCrAl alloys for fuel cladding applications  

Science Journals Connector (OSTI)

Abstract Ferritic-structured FeCrAl alloys are being developed and show promise as oxidation resistant accident tolerant light water reactor fuel cladding. This study focuses on investigating the weldability and post-weld mechanical behavior of three model alloys in a range of Fe(1317.5)Cr(34.4)Al (wt.%) with a minor addition of yttrium using modern laser-welding techniques. A detailed study on the mechanical performance of bead-on-plate welds using sub-sized, flat dog-bone tensile specimens and digital image correlation (DIC) has been carried out to determine the performance of welds as a function of alloy composition. Results indicated a reduction in the yield strength within the fusion zone compared to the base metal. Yield strength reduction was found to be primarily constrained to the fusion zone due to grain coarsening with a less severe reduction in the heat affected zone. For all proposed alloys, laser welding resulted in a defect free weld devoid of cracking or inclusions.

Kevin G. Field; Maxim N. Gussev; Yukinori Yamamoto; Lance L. Snead

2014-01-01T23:59:59.000Z

59

Fundamental studies of stress distributions and stress relaxation in oxide scales on high temperature alloys. [Final progress report  

SciTech Connect

This report summarizes a three-year study of stresses arising in the oxide scale and underlying metal during high temperature oxidation and of scale cracking. In-situ XRD was developed to measure strains during oxidation over 1000{degrees}C on pure metals. Acoustic emission was used to observe scale fracture during isothermal oxidation and cooling, and statistical analysis was used to infer mechanical aspects of cracking. A microscratch technique was used to measure the fracture toughness of scale/metal interface. A theoretical model was evaluated for the development and relaxation of stresses in scale and metal substrate during oxidation.

Shores, D.A.; Stout, J.H.; Gerberich, W.W.

1993-06-01T23:59:59.000Z

60

High temperature low-cycle fatigue of friction welded joints - type 304-304 stainless steel and alloy 718-718 nickel base superalloy  

SciTech Connect

This paper assesses the high-temperature low-cycle fatigue of the Type 304 stainless steel and Alloy 718 superalloy friction-welded joints. Strain controlled low-cycle fatigue tests for 304-304 and 718-718 friction-welded specimens were carried out at 923 K in air to obtain the fatigue strength of the joints. These materials were selected as the cyclic hardening and softening materials, respectively. The 304-304 welded specimens showed inferior fatigue strength in comparison with the base metal while the 718-718 specimens exhibited fatigue strength equivalent to that of the base metal. The difference in the fatigue strength between the two materials is discussed from the viewpoint of the cyclic deformation behavior and strain reduction at weld interface.

Wakai, T. (Power Reactor and Nuclear Fuel Development Corp., Ibaraki (Japan). Oarai Engineering Center); Sakane, M.; Ohnami, M. (Ritsumeikan Univ., Kyoto (Japan). Dept. of Mechanical Engineering); Okita, K. (Hyogo Prefectural Inst. of Industrial Research, Miki (Japan). Technical Center for Machinery and Metals); Fukuchi, Y. (Hyogo Prefectural Inst. of Industrial Research, Kobe (Japan))

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Elevated-Temperature Corrosion of CoCrCuFeNiAl0.5Bx High-Entropy Alloys in Simulated Syngas Containing H2S  

SciTech Connect

High-entropy alloys are formed by synthesizing five or more principal elements in equimolar or near equimolar concentrations. Microstructure of the CoCrCuFeNiAl{sub 0.5}B{sub x} (x = 0, 0.2, 0.6, 1) high-entropy alloys under investigation is composed of a mixture of disordered bcc and fcc phases and borides. These alloys were tested gravimetrically for their corrosion resistance in simulated syngas containing 0, 0.01, 0.1, and 1 % H{sub 2}S at 500 C. The exposed coupons were characterized using XRD and SEM. No significant corrosion was detected at 500 C in syngas containing 0 and 0.01 % H{sub 2}S while significant corrosion was observed in syngas containing 0.1 and 1 % H{sub 2}S. Cu{sub 1.96}S was the primary sulfide in the external corrosion scale on the low-boron high-entropy alloys, whereas FeCo{sub 4}Ni{sub 4}S{sub 8} on the high-boron high-entropy alloys. Multi-phase Cu-rich regions in the low-B high-entropy alloys were vulnerable to corrosive attack.

Dogan, Omer N.; Nielsen, Benjamin C.; Hawk, Jeffrey A.

2013-08-01T23:59:59.000Z

62

Structure of high-temperature nickel alloy ZhS36VI for single-crystal blades of high-pressure turbines  

Science Journals Connector (OSTI)

The fine structure, phase composition, and segregation inhomogeneity of carbonless single-crystal rhenium-alloyed alloy ZhS36VI in cast and heat-treated conditions are studied. The structural and phase stabili...

V. P. Kuznetsov; V. P. Lesnikov; E. V. Moroz

2008-03-01T23:59:59.000Z

63

Effect of aluminizing of Cr-containing ferritic alloys on the seal strength of a novel high-temperature solid oxide fuel cell sealing glass  

SciTech Connect

A novel high-temperature alkaline-earth silicate sealing glass was developed for solid oxide fuel cell (SOFC) applications. The glass was used to join two metallic coupons of Cr-containing ferritic stainless steel for seal strength evaluation. In previous work, SrCrO4 was found to form along the glass/steel interface, which led to severe strength degradation. In the present study, aluminization of the steel surface was investigated as a remedy to minimize or prevent the strontium chromate formation. Three different processes for aluminization were evaluated with Crofer22APU stainless steel: pack cementation, vapor phase deposition, and aerosol spraying. It was found that pack cementation resulted in a rough surface with occasional cracks in the Al-diffused region. Vapor phase deposition yielded a smoother surface, but the resulting high Al content increased the coefficient of thermal expansion (CTE), resulting in failure of joined coupons. Aerosol spraying of an Al-containing salt resulted in formation of a thin aluminum oxide layer without any surface damage. The room temperature seal strength was evaluated in the as-fired state and in environmentally aged conditions. In contrast to earlier results with uncoated Crofer22APU, the aluminized samples showed no strength degradation even for samples aged in air. Interfacial and chemical compatibility was also investigated. The results showed aluminization to be a viable candidate approach to minimize undesirable chromate formation between alkaline earth silicate sealing glass and Cr-containing interconnect alloys for SOFC applications.

Chou, Y. S.; Stevenson, Jeffry W.; Singh, Prabhakar

2008-12-01T23:59:59.000Z

64

CHARACTERIZATION OF ELEVATED TEMPERATURE PROPERTIES OF HEAT EXCHANGER AND STEAM GENERATOR ALLOYS  

SciTech Connect

The Next Generation Nuclear Plant project is considering Alloy 800H and Alloy 617 for steam generator and intermediate heat exchangers. It is envisioned that a steam generator would operate with reactor outlet temperatures from 750 to 800 C, while an intermediate heat exchanger for primary to secondary helium would operate up to an outlet temperature of 950 C. Although both alloys are of interest due in part to their technical maturity, a number of specific properties require further characterization for design of nuclear components. Strain rate sensitivity of both alloys has been characterized and is found to be significant above 600 C. Both alloys also exhibit dynamic strain aging, characterized by serrated flow, over a wide range of temperatures and strain rates. High temperature tensile testing of Alloy 617 has been conducted over a range of temperatures. Dynamic strain aging is a concern for these materials since it is observed to result in reduced ductility for many solid solution alloys. Creep, fatigue, and creep-fatigue properties of Alloy 617 have been measured as well, with the goal of determining the influence of the temperature, strain rate and atmosphere on the creep fatigue life of Alloy 617. Elevated temperature properties and implications for codification of the alloys will be described.

J.K. Wright; L.J. Carroll; C.J. Cabet; T. Lillo; J.K. Benz; J.A. Simpson; A. Chapman; R.N. Wright

2012-10-01T23:59:59.000Z

65

Effect of thermally stable Cu- and Mg-rich aluminides on the high temperature strength of an AlSi12CuMgNi alloy  

SciTech Connect

The internal architecture of an AlSi12CuMgNi piston alloy, revealed by synchrotron tomography, consists of three dimensional interconnected hybrid networks of Cu-rich aluminides, Mg-rich aluminides and eutectic/primary Si embedded in an ?-Al matrix. The strength at room temperature and at 300C is studied as a function of solution treatment time at 490C and compared with results previously reported for an AlSi12Ni alloy. The addition of 1 wt% Cu and 1 wt% Mg to AlSi12CuMgNi increases the room temperature strength by precipitation hardening while the strength at 300C is similar for both alloys in as-cast condition. The strength of AlSi12CuMgNi decreases with solution treatment time and stabilizes at 4 h solution treatment. The effect of solution treatment time on the strength of the AlSi12CuMgNi alloy is less pronounced than for the AlSi12Ni alloy both at room temperature and at 300C. - Highlights: The 3D microstructure of AlSi12CuMgNi is revealed by synchrotron tomography. An imaging analysis procedure to segment phases with similar contrasts is presented. 1 wt% Cu and Mg results in the formation of 3D networks of rigid phases. AlSi12CuMgNi is stronger than AlSi12Ni owing to the stability of the 3D networks.

Asghar, Z., E-mail: zhdasghar@yahoo.com [Materials Division, Directorate of Technology, PINSTECH, P. O. Nilore, Islamabad (Pakistan); Vienna University of Technology, Institute of Materials Science and Technology, Karlsplatz 13/308, A-1040 Vienna (Austria); Requena, G. [Vienna University of Technology, Institute of Materials Science and Technology, Karlsplatz 13/308, A-1040 Vienna (Austria); Zahid, G.H.; Rafi-ud-Din [Materials Division, Directorate of Technology, PINSTECH, P. O. Nilore, Islamabad (Pakistan)

2014-02-15T23:59:59.000Z

66

High-strain-rate nanoindentation behavior of fine-grained magnesium alloys  

E-Print Network (OSTI)

The effects of temperature and alloying elements on deformation in the high-strain-rate regime were investigated by testing fine-grained magnesium alloys with an average grain size of 2 ? 3 ?m by a nanoindentation technique. ...

Somekawa, Hidetoshi

67

High Temperature coatings based on {beta}-NiAI  

SciTech Connect

High temperature alloys are reviewed, focusing on current superalloys and their coatings. The synthesis, characerization, and oxidation performance of a NiAlTiB{sub 2} composite are explained. A novel coating process for MoNiAl alloys for improved oxidation performance is examined. The cyclic oxidation performance of coated and uncoated MoNiAl alloys is discussed.

Severs, Kevin

2012-07-10T23:59:59.000Z

68

Laser assisted high entropy alloy coating on aluminum: Microstructural evolution  

SciTech Connect

High entropy alloy (Al-Fe-Co-Cr-Ni) coatings were synthesized using laser surface engineering on aluminum substrate. Electron diffraction analysis confirmed the formation of solid solution of body centered cubic high entropy alloy phase along with phases with long range periodic structures within the coating. Evolution of such type of microstructure was a result of kinetics associated with laser process, which generates higher temperatures and rapid cooling resulting in retention of high entropy alloy phase followed by reheating and/or annealing in subsequent passes of the laser track giving rise to partial decomposition. The partial decomposition resulted in formation of precipitates having layered morphology with a mixture of high entropy alloy rich phases, compounds, and long range ordered phases.

Katakam, Shravana; Joshi, Sameehan S.; Mridha, Sanghita; Mukherjee, Sundeep; Dahotre, Narendra B., E-mail: Narendra.Dahotre@unt.edu [Department of Materials Science and Engineering, University of North Texas, 1150 Union Circle, 305310 Denton, Texas 76203-5017 (United States)

2014-09-14T23:59:59.000Z

69

High-Temperature Aluminum Alloys  

Energy.gov (U.S. Department of Energy (DOE))

2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

70

Progress in High-Entropy Alloys  

SciTech Connect

Strictly speaking, high-entropy alloys (HEAs) refer to single-phase, solid-solution alloys with multiprincipal elements in an equal or a near-equal molar ratio whose configurational entropy is tremendously high. This special topic was organized to reflect the focus and diversity of HEA research topics in the community.

Gao, Michael C.

2013-12-01T23:59:59.000Z

71

Grain boundary depletion and migration during selective oxidation of Cr in a Ni-5Cr binary alloy exposed to high-temperature hydrogenated water  

SciTech Connect

High-resolution microscopy of a high-purity Ni-5Cr alloy exposed to 360C hydrogenated water reveals intergranular selective oxidation of Cr accompanied by local Cr depletion and diffusion-induced grain boundary migration (DIGM). The corrosion-product oxide consists of a porous, interconnected network of Cr2O3 platelets with no further O ingress into the metal ahead. Extensive grain boundary depletion of Cr (to <0.05at.%) is observed typically 20100 nm wide as a result of DIGM and reaching depths of many micrometers beyond the oxidation front.

Schreiber, Daniel K.; Olszta, Matthew J.; Bruemmer, Stephen M.

2014-10-15T23:59:59.000Z

72

ITP Metal Casting: Corrosion Testing Practices - High Alloy Corrosion...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Metal Casting: Corrosion Testing Practices - High Alloy Corrosion Program ITP Metal Casting: Corrosion Testing Practices - High Alloy Corrosion Program lehighfs.pdf More Documents...

73

High temperature probe  

DOE Patents (OSTI)

A high temperature probe for sampling, for example, smokestack fumes, and is able to withstand temperatures of 3000.degree. F. The probe is constructed so as to prevent leakage via the seal by placing the seal inside the water jacket whereby the seal is not exposed to high temperature, which destroys the seal. The sample inlet of the probe is also provided with cooling fins about the area of the seal to provide additional cooling to prevent the seal from being destroyed. Also, a heated jacket is provided for maintaining the temperature of the gas being tested as it passes through the probe. The probe includes pressure sensing means for determining the flow velocity of an efficient being sampled. In addition, thermocouples are located in various places on the probe to monitor the temperature of the gas passing there through.

Swan, Raymond A. (Fremont, CA)

1994-01-01T23:59:59.000Z

74

High Temperature Superconductors  

Science Journals Connector (OSTI)

Abstract A brief review of the phenomenology of superconductivity, the distinction between type I and type II superconductors, and the application of type II superconductors is followed by a history of the theory of conventional superconductivity. Unconventional high-temperature superconductivity in the copper oxides is reviewed as a phenomenon occurring in narrow two-dimensional bands where the time for an electron transfer between like atoms is comparable to the period of an optical-mode lattice vibration. A family of iron pnictides containing layers of iron atoms may not require an alternative explanation of its high-temperature superconductivity.

J.B. Goodenough

2013-01-01T23:59:59.000Z

75

Erosion-Corrosion of Iron and Nickel Alloys at Elevated Temperature in a Combustion Gas Environment  

SciTech Connect

This paper reports on the results of a study that compares the erosion-corrosion behavior of a variety of alloys (Fe- 2Cr 1Mo, 304 SS, 310 SS, Incoloy 800, Haynes 230 and a Fe3Al) in a combustion environment. Advanced coal combustion environments, with higher temperatures, are driving re-examination of traditional and examination of new alloys in these hostile environments. In order to simulate conditions in advanced coal combustion boilers, a special erosion apparatus was used to allow for impingement of particles under a low abrasive flux in a gaseous environment comprised of 20 % CO2, 0.05 % HCl, 77 % N2, 3 % O2, and 0.1 % SO2. Tests were conducted at room temperature and 700 C with ~ 270 ?m silica, using an impact velocity of 20 m/s in both air and the simulated combustion gas environment. The erosion-corrosion behavior was characterized by gravimetric measurements and by examination of the degraded surfaces optically and by scanning electron microscopy (SEM). At room temperature most of the alloys had similar loss rates. Not surprisingly, at 700 C the lower chrome-iron alloy had a very high loss rate. The nickel alloys tended to have higher loss rates than the high chrome austenitic alloys.

Tylczak, Joseph [NETL] [NETL

2014-05-02T23:59:59.000Z

76

High-temperature gas-cooled reactor helium compatibility studies: results of 10,000-hour exposure of selected alloys in simulated reactor helium  

SciTech Connect

Work on the HTGR Helium Compatibility Task accomplished during the period March 31, 1977 through September 30, 1979, is documented in this report. Emphasis is on the results and analyses of creep data to 10,000 h and the detailed metallurgical evaluations performed on candidate alloy specimens tested for up to 10,000 h. Long-term creep and unstressed aging data in controlled-impurity helium and in air at 800, 900, and 1000/sup 0/C are reported for alloys included in the program in FY-76, including the wrought solid-solution-strengthened alloys, Hastelloy X, Hastelloy S, RA 333, and HD 556, and the centrifugally cast austenitic alloys, HK 40, Supertherm, Manaurite 36X, Manaurite 36XS, and Manaurite 900.

Lechtenberg, T.A.; Stevenson, R.D.; Johnson, W.R.

1980-05-01T23:59:59.000Z

77

Chemistry at High Temperatures  

Science Journals Connector (OSTI)

...347 the condensed phase. Both cases are...show the opposite behavior. These predictions...vapors. Condensed phase B203 B + B203 02...complex silicates and hydrates in high-temperature...characterized by phase diagrams (derived...doubt that thou-sands of new chemical materials...

John L. Margrave

1962-02-02T23:59:59.000Z

78

Turbine vane with high temperature capable skins  

DOE Patents (OSTI)

A turbine vane assembly includes an airfoil extending between an inner shroud and an outer shroud. The airfoil can include a substructure having an outer peripheral surface. At least a portion of the outer peripheral surface is covered by an external skin. The external skin can be made of a high temperature capable material, such as oxide dispersion strengthened alloys, intermetallic alloys, ceramic matrix composites or refractory alloys. The external skin can be formed, and the airfoil can be subsequently bi-cast around or onto the skin. The skin and the substructure can be attached by a plurality of attachment members extending between the skin and the substructure. The skin can be spaced from the outer peripheral surface of the substructure such that a cavity is formed therebetween. Coolant can be supplied to the cavity. Skins can also be applied to the gas path faces of the inner and outer shrouds.

Morrison, Jay A. (Oviedo, FL)

2012-07-10T23:59:59.000Z

79

High temperature thermometric phosphors  

DOE Patents (OSTI)

A high temperature phosphor consists essentially of a material having the general formula LuPO.sub.4 :Dy.sub.(x),Eu.sub.y) wherein: 0.1 wt %.ltoreq.x.ltoreq.20 wt % and 0.1 wt %.ltoreq.y.ltoreq.20 wt %. The high temperature phosphor is in contact with an article whose temperature is to be determined. The article having the phosphor in contact with it is placed in the environment for which the temperature of the article is to be determined. The phosphor is excited by a laser causing the phosphor to fluoresce. The emission from the phosphor is optically focused into a beam-splitting mirror which separates the emission into two separate emissions, the emission caused by the dysprosium dopant and the emission caused by the europium dopent. The separated emissions are optically filtered and the intensities of the emission are detected and measured. The ratio of the intensity of each emission is determined and the temperature of the article is calculated from the ratio of the intensities of the separate emissions.

Allison, Stephen W. (Knoxville, TN); Cates, Michael R. (Oak Ridge, TN); Boatner, Lynn A. (Oak Ridge, TN); Gillies, George T. (Earlysville, VA)

1999-03-23T23:59:59.000Z

80

High Bandgap III-V Alloys for High Efficiency Optoelectronics...  

NLE Websites -- All DOE Office Websites (Extended Search)

bandgap alloys for high efficiency optoelectronics are disclosed. An exemplary optoelectronic device may include a substrate, at least one Al.sub.1-xIn.sub.xP layer, and a...

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Method for low temperature preparation of a noble metal alloy  

DOE Patents (OSTI)

A method for producing fine, essentially contamination free, noble metal alloys is disclosed. The alloys comprise particles in a size range of 5 to 500 nm. The method comprises 1. A method for preparing a noble metal alloy at low temperature, the method comprising the steps of forming solution of organometallic compounds by dissolving the compounds into a quantity of a compatible solvent medium capable of solvating the organometallic, mixing a portion of each solution to provide a desired molarity ratio of ions in the mixed solution, adding a support material, rapidly quenching droplets of the mixed solution to initiate a solute-solvent phase separation as the solvent freezes, removing said liquid cryogen, collecting and freezing drying the frozen droplets to produce a dry powder, and finally reducing the powder to a metal by flowing dry hydrogen over the powder while warming the powder to a temperature of about 150.degree. C.

Even, Jr., William R. (Livermore, CA)

2002-01-01T23:59:59.000Z

82

High Temperature Membrane Working Group  

Energy.gov (U.S. Department of Energy (DOE))

The High Temperature Membrane Working Group consists of government, industry, and university researchers interested in developing high temperature membranes for fuel cells.

83

Temperature and environmentally assisted cracking in low alloy steel  

SciTech Connect

Environmental assisted cracking (EAC) can be defined as the propagation of fatigue cracks in water at rates from 3 to over 40 times the growth rates in air. For low alloy steels with sulfur contents > 0.0125% by weight, EAC is normal behavior in the 240 to 290C range. However, literature yields mixed results for low alloy steels with compositions just below this sulfur level; some reports indicate EAC while others do not. Also, several authors have reported an increased tendency toward EAC when the water temperatures were lowered. In the present work, five ASTM A 508 Class 2 forgings with ladle and check analyses that ranged from 0.010 to 0.019 wt% S were tested in high purity deaerated water in the temperature range of 93 to 260C. At 260C these forgings did not exhibit EAC, reinforcing earlier results for two similar forgings. This broad sampling indicates strong resistance to EAC for this class of forging at 260C. On the other hand, EAC occurred consistently in the three of these forgings that were tested below 204C, provided the test conditions (loading frequency, {Delta}K, and R) were high enough to produce a high baseline fatigue crack growth rate (FCGR), where the baseline FCGR is that expected in air. At 149C, EAC occurred at test conditions that combined to yield a baseline FCGR greater than {approx}2E-6 mm/s. At 204, 121, and 93C, this critical crack growth rate appeared to shift to lower baseline values. The EAC that occurred at lower temperatures was a factor of 3 to 12 times higher than baseline air rates, which was not as strong as the effect for higher sulfur steels at 240 to 290C. Also, no plateau in the growth rates occurred as it does with the higher sulfur steels. In another approach, EAC was induced at 93 and at 260C by raising the dissolved oxygen content of the water from <10 to >15 ppb.

Auten, T.A.; Monter, J.V.

1995-04-01T23:59:59.000Z

84

Thermal fuse for high-temperature batteries  

DOE Patents (OSTI)

A thermal fuse, preferably for a high-temperature battery, comprising leads and a body therebetween having a melting point between approximately 400.degree. C. and 500.degree. C. The body is preferably an alloy of Ag--Mg, Ag--Sb, Al--Ge, Au--In, Bi--Te, Cd--Sb, Cu--Mg, In--Sb, Mg--Pb, Pb--Pd, Sb--Zn, Sn--Te, or Mg--Al.

Jungst, Rudolph G. (Albuquerque, NM); Armijo, James R. (Albuquerque, NM); Frear, Darrel R. (Austin, TX)

2000-01-01T23:59:59.000Z

85

High Temperature Oxidation Performance of Aluminide Coatings  

SciTech Connect

Aluminide coatings are of interest for many high temperature applications because of the possibility of improving the oxidation resistance of structural alloys by forming a protective external alumina scale. Steam and exhaust gas environments are of particular interest because alumina is less susceptible to the accelerated attack due to hydroxide formation observed for chromia- and silica-forming alloys and ceramics. For water vapor testing, one ferritic (Fe-9Cr-1Mo) and one austenitic alloy (304L) have been selected as substrate materials and CVD coatings have been used in order to have a well-controlled, high purity coating. It is anticipated that similar aluminide coatings could be made by a higher-volume, commercial process such as pack cementation. Previous work on this program has examined as-deposited coatings made by high and low Al activity CVD processes and the short-term performance of these coatings. The current work is focusing on the long term behavior in both diffusion tests16 and oxidation tests of the thicker, high Al activity coatings. For long-term coating durability, one area of concern has been the coefficient of thermal expansion (CTE) mismatch between coating and substrate. This difference could cause cracking or deformation that could reduce coating life. Corrosion testing using thermal cycling is of particular interest because of this potential problem and results are presented where a short exposure cycle (1h) severely degraded aluminide coatings on both types of substrates. To further study the potential role of aluminide coatings in fossil energy applications, several high creep strength Ni-base alloys were coated by CVD for testing in a high pressure (20atm) steam-CO{sub 2} environment for the ZEST (zero-emission steam turbine) program. Such alloys would be needed as structural and turbine materials in this concept. For Ni-base alloys, CVD produces a {approx}50{mu}m {beta}-NiAl outer layer with an underlying interdiffusion zone. Specimens of HR160, alloy 601 and alloy 230 were tested with and without coatings at 900 C and preliminary post-test characterization is reported.

Pint, Bruce A [ORNL; Zhang, Ying [Tennessee Technological University; Haynes, James A [ORNL; Wright, Ian G [ORNL

2004-01-01T23:59:59.000Z

86

HIGHLY DISPERSED ALLOY CATHODE CATALYST FOR DURABILITY  

E-Print Network (OSTI)

Understanding high performance materials Pt/C cathode B.S.E. Pt PtCo/C cathode IrB.S.E. Pt Co PtIrCo/C cathodeHIGHLY DISPERSED ALLOY CATHODE CATALYST FOR DURABILITY T. D. Jarvi UTC Power Corporation Electrochemical Area Loss Activity at 900 mVRHE (IR-Free) 0.44 A/mg Pt Specific Activity at 900 m

87

High Temperature Membrane Working Group  

Energy.gov (U.S. Department of Energy (DOE))

This presentation provides an overview of the High Temperature Membrane Working Group Meeting in May 2007.

88

High Temperature | Open Energy Information  

Open Energy Info (EERE)

Temperature Temperature Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Print PDF Sanyal Temperature Classification: High Temperature Dictionary.png High Temperature: No definition has been provided for this term. Add a Definition Sanyal Temp Classification This temperature scheme was developed by Sanyal in 2005 at the request of DOE and GEA, as reported in Classification of Geothermal Systems: A Possible Scheme. Extremely Low Temperature Very Low Temperature Low Temperature Moderate Temperature High Temperature Ultra High Temperature Steam Field Reservoir fluid between 230°C and 300°C is considered by Sanyal to be "high temperature." "Above a temperature level of 230°C, the reservoir would be expected to become two-phase at some point during exploitation. The next higher

89

High temperature detonator  

DOE Patents (OSTI)

A detonator assembly is provided which is usable at high temperatures about 300.degree. C. A detonator body is provided with an internal volume defining an anvil surface. A first acceptor explosive is disposed on the anvil surface. A donor assembly having an ignition element, an explosive material, and a flying plate, are placed in the body effective to accelerate the flying plate to impact the first acceptor explosive on the anvil for detonating the first acceptor explosive. A second acceptor explosive is eccentrically located in detonation relationship with the first acceptor explosive to thereafter effect detonation of a main charge.

Johnson, James O. (Los Alamos, NM); Dinegar, Robert H. (Los Alamos, NM)

1988-01-01T23:59:59.000Z

90

Specific Heats of Zirconium Alloys at Low Temperatures  

Science Journals Connector (OSTI)

The specific heats of dilute alloys of silver, cadmium, indium, tin, and antimony in hexagonal zirconium have been measured from 1.2 to 4.5K. For each alloy the specific heat obeys the relation c=?T+?T3 within the experimental error. All of these solutes increase ? linearly with concentration and d?dx is linearly related to the chemical valence of the solute. The increase in ? in the tin-zirconium alloys shows that all electrons outside closed shells cannot be treated as equivalent in the rigid band model of alloying. All of these solutes increase the density of states of zirconium, providing evidence for a zone overlap in the zirconium d band and for a small number of electrons in a new band. All of the solutes increase the lattice specific heat and the Debye temperature is a linear function of solute concentration for each of these alloy systems. d?dx is not simply related to the solute valence but shows a close correlation with the magnitude of the rate of change of the distance between atoms at (0,0,0) and (13, 23, ) of the hexagonal cell. Additions of tin to zirconium do not change the average interaction potential of the BCS theory appreciably.

G. D. Kneip; Jr.; J. O. Betterton; Jr.; J. O. Scarbrough

1963-09-15T23:59:59.000Z

91

High-Temperature Water Splitting  

Energy.gov (U.S. Department of Energy (DOE))

High-temperature water splitting (a "thermochemical" process) is a long-term technology in the early stages of development.

92

ITP Metal Casting: Corrosion Testing Practices ? High Alloy...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Office of Energy Efficiency and Renewable Energy INDUSTRIAL TECHNOLOGIES PROGRAM Corrosion Testing Practices - High Alloy Corrosion Program This subtask under ESMARRT Material...

93

Method for fabricating wrought components for high-temperature gas-cooled reactors and product  

DOE Patents (OSTI)

A method and alloys for fabricating wrought components of a high-temperature gas-cooled reactor are disclosed. These wrought, nickel-based alloys, which exhibit strength and excellent resistance to carburization at elevated temperatures, include aluminum and titanium in amounts and ratios to promote the growth of carburization resistant films while preserving the wrought character of the alloys. These alloys also include substantial amounts of molybdenum and/or tungsten as solid-solution strengtheners. Chromium may be included in concentrations less than 10% to assist in fabrication. Minor amounts of carbon and one or more carbide-forming metals also contribute to high-temperature strength.

Thompson, Larry D. (San Diego, CA); Johnson, Jr., William R. (San Diego, CA)

1985-01-01T23:59:59.000Z

94

High-temperature Pump Monitoring - High-temperature ESP Monitoring...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Report Detecting Fractures Using Technology at High Temperatures and Depths - Geothermal Ultrasonic Fracture Imager (GUFI); 2010 Geothermal Technology Program Peer Review Report...

95

High Temperature Structural Foam  

Science Journals Connector (OSTI)

The Aerospace Industry is experiencing growing demand for high performance polymer foam. The X-33 program needs structural foam insulation capable of retaining its strength over a wide range of environmental conditions. The High Speed Research Program ...

Weiser Erik S.; Baillif Faye F.; Grimsley Brian W.; Marchello Joseph M.

1998-05-01T23:59:59.000Z

96

Embrittlement and DBTT of High-Burnup PWR Fuel Cladding Alloys | Department  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Embrittlement and DBTT of High-Burnup PWR Fuel Cladding Alloys Embrittlement and DBTT of High-Burnup PWR Fuel Cladding Alloys Embrittlement and DBTT of High-Burnup PWR Fuel Cladding Alloys Structural analyses of high-burnup (HBU) fuel require cladding mechanical properties and failure limits to assess fuel behavior during long-term dry-cask storage and transportation. Pre-storage drying-transfer operations and early stage storage subject cladding to higher temperatures and pressure-induced tensile hoop stresses relative to in-reactor operation and pool storage. Under these conditions, radial hydrides may precipitate during slow cooling and provide an additional embrittlement mechanism as the cladding temperature decreases below the ductile-to-brittle transition temperature (DBTT). Graphic and photographic details of the testing are

97

ELECTRICAL RESISTIVITY OF SOME LIQUID CADMIUM ANTIMONY ALLOYS AS A FUNCTION OF TEMPERATURE  

E-Print Network (OSTI)

L-93 ELECTRICAL RESISTIVITY OF SOME LIQUID CADMIUM ANTIMONY ALLOYS AS A FUNCTION OF TEMPERATURE J The electrical resistivity of several Cd1-xSbx antimony rich alloys has been investiga- ted between the liquidus. 1. Introduction. - The electrical resistivity of Cd1-xSbx alloys has been investigated by Miller

Paris-Sud XI, Université de

98

Project Profile: High Operating Temperature Liquid Metal Heat Transfer Fluids  

Energy.gov (U.S. Department of Energy (DOE))

The University of California, Los Angeles (UCLA), along with partners at the University of California, Berkeley, and Yale University, under the 2012 Multidisciplinary University Research Initiative (MURI): High Operating Temperature (HOT) Fluids funding opportunity, is investigating the use of metal alloys as a heat transfer fluid (HTF) in concentrating solar power (CSP) systems operating at temperatures in excess of 800C. By allowing higher temperature operation, CSP systems can achieve greater efficiencies and thereby reduce the overall cost of electricity production.

99

High Temperature Processing Symposium 2014  

E-Print Network (OSTI)

} High temperature recycling operations } Materials sustainability } New furnace technology (including solar) We look forward to seeing you in February 2014. Dr M Akbar Rhamdhani (Chairman HTPS 2014) Prof

Liley, David

100

Threshold Stress Creep Behavior of Alloy 617 at Intermediate Temperatures  

SciTech Connect

Creep of Alloy 617, a solid solution Ni-Cr-Mo alloy, was studied in the temperature range of 1023 K to 1273 K (750 C to 1000 C). Typical power-law creep behavior with a stress exponent of approximately 5 is observed at temperatures from 1073 K to 1273 K (800 C to 1000 C). Creep at 1023 K (750 C), however, exhibits threshold stress behavior coinciding with the temperature at which a low volume fraction of ordered coherent y' precipitates forms. The threshold stress is determined experimentally to be around 70 MPa at 1023 K (750 C) and is verified to be near zero at 1173 K (900 C)temperatures directly correlating to the formation and dissolution of y' precipitates, respectively. The y' precipitates provide an obstacle to continued dislocation motion and result in the presence of a threshold stress. TEM analysis of specimens crept at 1023 K (750 C) to various strains, and modeling of stresses necessary for y' precipitate dislocation bypass, suggests that the climb of dislocations around the y' precipitates is the controlling factor for continued deformation at the end of primary creep and into the tertiary creep regime. As creep deformation proceeds at an applied stress of 121 MPa and the precipitates coarsen, the stress required for Orowan bowing is reached and this mechanism becomes active. At the minimum creep rate at an applied stress of 145 MPa, the finer precipitate size results in higher Orowan bowing stresses and the creep deformation is dominated by the climb of dislocations around the y' precipitates.

J.K. Benz; L.J. Carroll; J.K. Wright; R.N. Wright; T. Lillo

2014-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Temperature and concentration dependences of the electrical resistivity for alloys of plutonium with americium under normal conditions  

SciTech Connect

The temperature and concentration dependences of the electrical resistivity for alloys of americium with plutonium are analyzed in terms of the multiband conductivity model for binary disordered substitution-type alloys. For the case of high temperatures (T > {Theta}{sub D}, {Theta}{sub D} is the Debye temperature), a system of self-consistent equations of the coherent potential approximation has been derived for the scattering of conduction electrons by impurities and phonons without any constraints on the interaction intensity. The definitions of the shift and broadening operator for a single-electron level are used to show qualitatively and quantitatively that the pattern of the temperature dependence of the electrical resistivity for alloys is determined by the balance between the coherent and incoherent contributions to the electron-phonon scattering and that the interference conduction electron scattering mechanism can be the main cause of the negative temperature coefficient of resistivity observed in some alloys involving actinides. It is shown that the great values of the observed resistivity may be attributable to interband transitions of charge carriers and renormalization of their effective mass through strong s-d band hybridization. The concentration and temperature dependences of the resistivity for alloys of plutonium and americium calculated in terms of the derived conductivity model are compared with the available experimental data.

Tsiovkin, Yu. Yu., E-mail: y.tsiovkin@mail.ustu.ru; Povzner, A. A.; Tsiovkina, L. Yu. [Eltsin Ural Federal University (Russian Federation); Dremov, V. V. [Russian Federal Nuclear Center-Zababakhin All-Russian Research Institute of Technical Physics (Russian Federation); Kabirova, L. R.; Dyachenko, A. A.; Bystrushkin, V. B.; Ryabukhina, M. V. [Eltsin Ural Federal University (Russian Federation); Lukoyanov, A. V.; Shorikov, A. O. [Russian Academy of Sciences, Ural Division, Institute of Metal Physics (Russian Federation)

2010-01-15T23:59:59.000Z

102

Highly Dispersed Alloy Cathode Catalyst for Durability  

Energy.gov (U.S. Department of Energy (DOE))

This presentation, which focuses on alloy cathode catalysts, was given by T. D. Jarvi of UTC Power at a February 2007 meeting on new fuel cell projects.

103

Effects of strain amplitude and temperature on the damping capacity of an Fe-19Mn alloy with different microstructures  

SciTech Connect

The influences of strain amplitude (10{sup -5}-10{sup -4}) and temperature (25 deg. C-500 deg. C) on the internal friction of a cold-drawn and solution treated Fe-19Mn alloy were investigated. The internal friction was measured using reversal torsion pendulum and multifunction internal friction equipment. The microstructure was observed using scanning electron microscopy. The phase transformation temperatures were determined using differential scanning calorimetry. The results indicated that the internal friction of the solution treated alloy was related to strain amplitude, which could be explained using the movement of Shockley partial dislocations (bowing out and breaking away). But the internal friction of the cold-drawn alloy was independent of strain amplitude because of high density dislocations formed by cold forming. Moreover, when the temperature was changed between 25 deg. C and 500 deg. C, the internal friction of the cold-drawn alloy increased slowly from 25 deg. C to 375 deg. C, and then increased quickly from 375 deg. C to 500 deg. C. However, for the solution treated alloy, there was an internal friction peak at about 210 deg. C in the heating process (from 25 deg. C to 500 deg. C), and there was another internal friction peak at about 150 deg. C in the cooling process. These peaks could be explained using the heat-assisted movement of dislocations. - Research Highlights: {yields}Internal friction of solution treated Fe-19Mn alloy is related to strain amplitude. {yields}Internal friction of cold-drawn Fe-19Mn alloy is independent of strain amplitude. {yields}IF of cold-drawn alloy increases from RT to 500 deg. C. {yields}There is an IF peak of solution treated alloy in heating and cooling process separately. {yields}The results can be explained using the movement of dislocations.

Huang Shuke, E-mail: huangshuke@163.com [Institute of Machinery Manufacturing Technology, China Academy of Engineering Physics, Mianyang, Sichuan 621900 (China); Zhou Danchen; Liu Jianhui [Institute of Machinery Manufacturing Technology, China Academy of Engineering Physics, Mianyang, Sichuan 621900 (China); Teng Jin; Li Ning; Wen Yuhua [School of Manufacturing Science and Engineering, Sichuan University, Chengdu, Sichuan 610065 (China)

2010-11-15T23:59:59.000Z

104

Evaluation of high strength, high conductivity CuNiBe alloys for fusion energy applications  

SciTech Connect

The unirradiated tensile properties for several different heats and thermomechanical treatment conditions of precipitation strengthened Hycon 3HPTM CuNiBe (Cu-2%Ni-0.35%Be in wt.%) have been measured over the temperature range of 20-500 C for longitudinal and long transverse orientations. The room temperature electrical conductivity has also been measured for several heats, and the precipitate microstructure was characterized using transmission electron microscopy. The CuNiBe alloys exhibit very good combination of strength and conductivity at room temperature, with yield strengths of 630-725 MPa and electrical conductivities of 65-72% International Annealed Copper Standard (IACS). The strength remained relatively high at all test temperatures, with yield strengths of 420-520 MPa at 500 C. However, low levels of ductility (<5% uniform elongation) were observed at test temperatures above 200-250 C, due to flow localization near grain boundaries (exacerbated by having only 10-20 grains across the gage thickness of the miniaturized sheet tensile specimens). Scanning electron microscopy observation of the fracture surfaces found a transition from ductile transgranular to ductile intergranular fracture with increasing test temperature. Fission neutron irradiation to a dose of ~0.7 displacements per atom (dpa) at temperatures between 100 and 240 C produced a slight increase in strength and a significant decrease in ductility. The measured tensile elongation increased with increasing irradiation temperature, with a uniform elongation of ~3.3% observed at 240 C. The electrical conductivity decreased slightly following irradiation, due to the presence of defect clusters and Ni, Zn, Co transmutation products. Considering also previously published fracture toughness data, this indicates that CuNiBe alloys have irradiated tensile and electrical properties comparable or superior to CuCrZr and oxide dispersion strengthened copper at temperatures <250 C, and may be an attractive candidate for certain fusion energy structural applications. Conversely, CuNiBe may not be preferred at intermediate temperatures of 250-500 C due to the poor ductility and fracture toughness of CuNiBe alloys at temperatures >250 C. The potential deformation mechanisms responsible for the transition from transgranular to intergranular fracture are discussed. The possible implications for other precipitation hardened alloys such as nickel based superalloys are briefly discussed.

Zinkle, Steven J [ORNL] [ORNL

2014-01-01T23:59:59.000Z

105

Philosophy 26 High Temperature Superconductivity  

E-Print Network (OSTI)

is the ratio of voltage to current. The resistance of a material tells us how a low resistance, and they are therefore good conductors; other materials, likePhilosophy 26 High Temperature Superconductivity By Ohm's Law, resistance

Callender, Craig

106

Experiment Hazard Class 3 - High Temperatures  

NLE Websites -- All DOE Office Websites (Extended Search)

Operation * APS Base Low Temperatures * Cryogenic Systems High Temperatures * Electric Furnace * Optical Furnace * Other High Temperature Lasers * Laser, Class 2 * Laser,...

107

Continuous electric resistance heatingHot forming system for high-alloy metals with poor workability  

Science Journals Connector (OSTI)

A new hot forming system for high-alloy metals with poor workability is developed. This forming system is a direct combination of a forming machine and continuous electric resistance heating, and is capable of the high-speed forming of metals with flexible and precise control of elevated temperature. The prototype of the new forming system is applied to the forming of high-alloy metals with poor formability, such as a Ti6Al4V bar, and the basic characteristics of this forming system are clarified. Using this system, sound, high speed forming of high alloys becomes possible, and the Ti6Al4V bar is successfully formed without fracture.

Jun Yanagimoto; Ryo Izumi

2009-01-01T23:59:59.000Z

108

Temperature controlled high voltage regulator  

DOE Patents (OSTI)

A temperature controlled high voltage regulator for automatically adjusting the high voltage applied to a radiation detector is described. The regulator is a solid state device that is independent of the attached radiation detector, enabling the regulator to be used by various models of radiation detectors, such as gas flow proportional radiation detectors.

Chiaro, Jr., Peter J. (Clinton, TN); Schulze, Gerald K. (Knoxville, TN)

2004-04-20T23:59:59.000Z

109

High temperature lightweight foamed cements  

DOE Patents (OSTI)

Cement slurries are disclosed which are suitable for use in geothermal wells since they can withstand high temperatures and high pressures. The formulation consists of cement, silica flour, water, a retarder, a foaming agent, a foam stabilizer, and a reinforcing agent. A process for producing these cements is also disclosed. 3 figs.

Sugama, Toshifumi.

1989-10-03T23:59:59.000Z

110

Electrical resistivity and thermal conductivity of liquid Fe alloys at high P and T, and  

E-Print Network (OSTI)

Electrical resistivity and thermal conductivity of liquid Fe alloys at high P and T, and heat flux to crystallize (1, 4). Existing estimates of thermal conductivity (kel) and electrical resistivity (el) of Earth of electrical resistivity to temperature, its invariability along and across the Fe liquidus, and adherence

Steinle-Neumann, Gerd

111

High Temperature Optical Gas Sensing  

NLE Websites -- All DOE Office Websites (Extended Search)

Optical Gas Sensing Optical Gas Sensing Opportunity Research is active on optical sensors integrated with advanced sensing materials for high temperature embedded gas sensing applications. Patent applications have been filed for two inventions in this area and several other methods are currently under development. These technologies are available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory (NETL). Organizations or individuals with capabilities in optical sensor packaging for harsh environment and high temperature applications are encouraged to contact NETL to explore potential collaborative opportunities. Overview Contact NETL Technology Transfer Group techtransfer@netl.doe.gov

112

High temperature superconductor current leads  

DOE Patents (OSTI)

An electrical lead is disclosed having one end for connection to an apparatus in a cryogenic environment and the other end for connection to an apparatus outside the cryogenic environment. The electrical lead includes a high temperature superconductor wire and an electrically conductive material distributed therein, where the conductive material is present at the one end of the lead at a concentration in the range of from 0 to about 3% by volume, and at the other end of the lead at a concentration of less than about 20% by volume. Various embodiments are shown for groups of high temperature superconductor wires and sheaths. 9 figs.

Hull, J.R.; Poeppel, R.B.

1995-06-20T23:59:59.000Z

113

Sandia National Laboratories: Sandia-Developed Alloy Has Potential...  

NLE Websites -- All DOE Office Websites (Extended Search)

contain lead. Read the Sandia news release. Tagged with: downhole electronics * Geothermal Energy * gold-silver-germanium alloy * High Temperature Electronics * lead-free alloy *...

114

CompositionStructureFunction Diagrams of TiNiAu Thin Film Shape Memory Alloys  

Science Journals Connector (OSTI)

thin films; annealing; high temperature shape memory alloys; combinatorial materials science; phase transformation ...

Pio John S. Buenconsejo; Alfred Ludwig

2014-11-04T23:59:59.000Z

115

Method for high temperature mercury capture from gas streams  

DOE Patents (OSTI)

A process to facilitate mercury extraction from high temperature flue/fuel gas via the use of metal sorbents which capture mercury at ambient and high temperatures. The spent sorbents can be regenerated after exposure to mercury. The metal sorbents can be used as pure metals (or combinations of metals) or dispersed on an inert support to increase surface area per gram of metal sorbent. Iridium and ruthenium are effective for mercury removal from flue and smelter gases. Palladium and platinum are effective for mercury removal from fuel gas (syngas). An iridium-platinum alloy is suitable for metal capture in many industrial effluent gas streams including highly corrosive gas streams.

Granite, E.J.; Pennline, H.W.

2006-04-25T23:59:59.000Z

116

High temperature turbine engine structure  

DOE Patents (OSTI)

A high temperature turbine engine includes a rotor portion having axially stacked adjacent ceramic rotor parts. A ceramic/ceramic joint structure transmits torque between the rotor parts while maintaining coaxial alignment and axially spaced mutually parallel relation thereof despite thermal and centrifugal cycling.

Boyd, Gary L. (Tempe, AZ)

1991-01-01T23:59:59.000Z

117

Experimental study of a structural magnesium alloy with high absorption energy under dynamic loading  

SciTech Connect

It has been demonstrated that pure Mg exhibits low ductility under dynamic loading at room temperature owing to its HCP structure. Very limited data are currently available for magnesium alloys under dynamic loading. In order to be used for structural components, it is necessary to improve the mechanical properties of magnesium alloys. Lahaise et al. reported the yield strength of the AZ91 magnesium alloy increased with refining its microstructure. Mohri et al. has already been reported the ductility enhancement of a Mg-Y-RE(Rare Earth) alloy by hot extrusion. They mentioned the enhancement of ductility is due to the refining microstructure of magnesium. Thus refining microstructure enables to raise the possibility for the development of a structural magnesium alloy with high ductility at dynamic strain rate. In this paper, the possibility of a fine-grained WE43 magnesium alloy is investigated to raise the high speed impact performance against the foreign object damage by the enhancement of ductility and absorption energy under dynamic loading.

Mukai, T.; Ishikawa, K. [Osaka Municipal Technical Research Inst. (Japan). Mechanical Engineering Dept.] [Osaka Municipal Technical Research Inst. (Japan). Mechanical Engineering Dept.; Mohri, T. [Nagoya Municipal Industrial Research Inst. Rokuban, Atsuta (Japan)] [Nagoya Municipal Industrial Research Inst. Rokuban, Atsuta (Japan); Nakamura, M. [National Industrial Research Inst., Nagoya (Japan)] [National Industrial Research Inst., Nagoya (Japan); Higashi, K. [Osaka Prefecture Univ., Sakai (Japan)] [Osaka Prefecture Univ., Sakai (Japan)

1998-10-05T23:59:59.000Z

118

Acid Doped Membranes for High Temperature PEMFC  

Energy.gov (U.S. Department of Energy (DOE))

Presentation on Acid Doped Membranes for High Temperature PEMFC to the High Temperature Membrane Working Group, May 25, 2004 in Philadelphia, PA.

119

Joint Institute for High Temperatures  

National Nuclear Security Administration (NNSA)

Joint Institute for High Temperatures of Russian Academy of Sciences Moscow Institute of Physics and Technology Extended title Extended title Excited state of warm dense matter or Exotic state of warm dense matter or Novel form of warm dense matter or New form of plasma Three sources of generation similarity: solid state density, two temperatures: electron temperature about tens eV, cold ions keep original crystallographic positions, but electron band structure and phonon dispersion are changed, transient but steady (quasi-stationary for a short time) state of non-equilibrium, uniform plasmas (no reference to non-ideality, both strongly and weakly coupled plasmas can be formed) spectral line spectra are emitted by ion cores embedded in plasma environment which influences the spectra strongly,

120

High Reliability, High TemperatureThermoelectric Power Generation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Reliability, High TemperatureThermoelectric Power Generation Materials and Technologies High Reliability, High TemperatureThermoelectric Power Generation Materials and Technologies...

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

High temperature turbine engine structure  

DOE Patents (OSTI)

A high temperature ceramic/metallic turbine engine includes a metallic housing which journals a rotor member of the turbine engine. A ceramic disk-like shroud portion of the engine is supported on the metallic housing portion and maintains a close running clearance with the rotor member. A ceramic spacer assembly maintains the close running clearance of the shroud portion and rotor member despite differential thermal movements between the shroud portion and metallic housing portion.

Carruthers, William D. (Mesa, AZ); Boyd, Gary L. (Tempe, AZ)

1994-01-01T23:59:59.000Z

122

High temperature turbine engine structure  

DOE Patents (OSTI)

A high temperature ceramic/metallic turbine engine includes a metallic housing which journals a rotor member of the turbine engine. A ceramic disk-like shroud portion of the engine is supported on the metallic housing portion and maintains a close running clearance with the rotor member. A ceramic spacer assembly maintains the close running clearance of the shroud portion and rotor member despite differential thermal movements between the shroud portion and metallic housing portion.

Carruthers, William D. (Mesa, AZ); Boyd, Gary L. (Tempe, AZ)

1993-01-01T23:59:59.000Z

123

High temperature turbine engine structure  

DOE Patents (OSTI)

A high temperature ceramic/metallic turbine engine includes a metallic housing which journals a rotor member of the turbine engine. A ceramic disk-like shroud portion of the engine is supported on the metallic housing portion and maintains a close running clearance with the rotor member. A ceramic spacer assembly maintains the close running clearance of the shroud portion and rotor member despite differential thermal movements between the shroud portion and metallic housing portion.

Carruthers, William D. (Mesa, AZ); Boyd, Gary L. (Tempe, AZ)

1992-01-01T23:59:59.000Z

124

Ultra High Temperature | Open Energy Information  

Open Energy Info (EERE)

Ultra High Temperature Ultra High Temperature Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Print PDF Sanyal Temperature Classification: Ultra High Temperature Dictionary.png Ultra High Temperature: No definition has been provided for this term. Add a Definition Sanyal Temp Classification This temperature scheme was developed by Sanyal in 2005 at the request of DOE and GEA, as reported in Classification of Geothermal Systems: A Possible Scheme. Extremely Low Temperature Very Low Temperature Low Temperature Moderate Temperature High Temperature Ultra High Temperature Steam Field Reservoir fluid greater than 300°C is considered by Sanyal to be "ultra high temperature". "Such reservoirs are characterized by rapid development of steam saturation in the reservoir and steam fraction in the mobile fluid phase upon

125

Materials Characterization Capabilities at the High Temperature...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Characterization Capabilities at the High Temperature Materials Laboratory: Focus on Carbon Fiber and Composites Materials Characterization Capabilities at the High...

126

THE USE OF TERNARY PHASE DIAGRAMS IN THE STUDY OF HIGH TEMPERATURE CORROSION  

E-Print Network (OSTI)

THE USE OF TERNARY PHASE DIAGRAMS IN THE STUDY OF HIGH TEMPERATURE CORROSION PRODUCTS FORMED ON Fe'' and resulting morphologies that may occur during formation of corrosion scales from high temperature gaseous the previously formed reaction products was found to produce internal corrosion phases within the alloy

DuPont, John N.

127

High temperature corrosion research at the Albany Research Center  

SciTech Connect

The Severe Environment Corrosion and Erosion Research Facility (SECERF) at the Albany Research Center is operational. SECERF consists of 6 modules that share the availability of up to 10 different gases to produce environments for high temperature corrosion and erosion research. Projects to be conducted in the modules include: corrosion sensors for fossil energy systems, thermal gradient effects on high temperature corrosion, the development of sulfidation resistant alloys, determination of the effects of ash on the corrosion of metals and alloys in coal and waste combustion and coal gasification environments, high temperature erosion-corrosion of metals, and molten slag effects on refractories. Results from two areas, the effect of ash deposits on alloy corrosion and thermal gradient effects on the corrosion of metals, will be highlighted. Ash produced in coal gasifiers, coal combustors, and waste combustors, when deposited on metal surfaces, provides sites for corrosion attack and contributes chemical species that participate in the corrosion reaction. Results are presented for the corrosion of 304L stainless steel, that was either uncoated or coated with ash or with ash containing NaCl or Na2SO4, in air-water vapor mixtures at 600 C. The presence of high heat fluxes and temperature gradients in many fossil energy systems creates the need for an understanding of their effects on corrosion and oxidation. Such information would be useful for both improved alloy design and for better translation of isothermal laboratory results to field use. Temperature gradients in a solid oxide result in two changes that modify diffusion within the oxide. The first is when a gradient in point defect concentration is created within the oxide, for example, where more vacancies are expected at a higher temperature. The second change is when the presence of a temperature gradient biases the diffusion jump of an atom. Results of tests are presented for cobalt with metal surface temperatures of approximately 920-950 C in N2 plus 1-10 vol% O2 environments with a heat flux of about 40 kW/m2. Non-equilibrium thermodynamics were used to develop oxidation rate equations in temperature gradients that were combined with point defect information of CoO to predict oxidation rates.

Covino, Bernard S., Jr.; Holcomb, Gordon R.; Russell, James H.; Cramer, Stephen D.; Bullard, Sophie J.; Ziomek-Moroz, Margaret; Matthes, Steven A.; Chinn, R.E.

2002-01-01T23:59:59.000Z

128

Insulator coating for high temperature alloys method for producing insulator coating for high temperature alloys  

DOE Patents (OSTI)

A method for fabricating an electrically insulating coating on a surface is disclosed comprising coating the surface with a metal, and reacting the metal coated surface with a nonmetal so as to create a film on the metal-coated surface. Alternatively, the invention provides for a method for producing a noncorrosive, electrically insulating coating on a surface saturated with a nonmetal comprising supplying a molten fluid, dissolving a metal in the molten fluid to create a mixture, and contacting the mixture with the saturated surface. Lastly, the invention provides an electrically insulative coating comprising an underlying structural substrate coated with an oxide or nitride compound. 2 figs.

Park, J.H.

1998-06-23T23:59:59.000Z

129

High Operating Temperature Liquid Metal Heat Transfer Fluids  

Energy.gov (U.S. Department of Energy (DOE))

This fact sheet describes a UCLA-led solar project to investigate high operating temperature liquid metal heat transfer fluids, funded by the SunShot initiative. The project team is using a combination of modeling along with a variety of property measurement and validation studies to demonstrate that the metal alloys identified can meet all the needs of a concentrating solar power plant. A successful candidate fluid would allow for the reduction of the levelized cost of energy by increasing the operating temperature for the CSP plant power cycle, which would increase thermal-to-electric conversion efficiency.

130

High Temperature Mechanical Properties as Design Parameters  

Science Journals Connector (OSTI)

...corrosion resistance or high proof strength...development of more efficient power plant, process...Figure 2 shows a high temperature bolt...S.O.) of a Boiler Code (I968...power plant for high temperature pipework, boiler headers, valve...

1976-01-01T23:59:59.000Z

131

Facile synthesis of PtAu alloy nanoparticles with high activity...  

NLE Websites -- All DOE Office Websites (Extended Search)

synthesis of PtAu alloy nanoparticles with high activity for formic acid oxidation. Facile synthesis of PtAu alloy nanoparticles with high activity for formic acid oxidation....

132

Sandia National Laboratories: High-Pressure and High-Temperature...  

NLE Websites -- All DOE Office Websites (Extended Search)

ClimateECClimateCarbon CaptureHigh-Pressure and High-Temperature Neutron Reflectometry Cell for Solid-Fluid Interface Studies High-Pressure and High-Temperature Neutron...

133

Fabrication of Tungsten-Rhenium Cladding materials via Spark Plasma Sintering for Ultra High Temperature Reactor Applications  

SciTech Connect

This research will develop an optimized, cost-effective method for producing high-purity tungsten-rhenium alloyed fuel clad forms that are crucial for the development of a very high-temperature nuclear reactor. The study will provide critical insight into the fundamental behavior (processing-microstructure- property correlations) of W-Re alloys made using this new fabrication process comprising high-energy ball milling (HEBM) and spark plasma sintering (SPS). A broader goal is to re-establish the U.S. lead in the research field of refractory alloys, such as W-Re systems, with potential applications in very high-temperature nuclear reactors. An essential long-term goal for nuclear power is to develop the capability of operating nuclear reactors at temperatures in excess of 1,000K. This capability has applications in space exploration and some special terrestrial uses where high temperatures are needed in certain chemical or reforming processes. Refractory alloys have been identified as being capable of withstanding temperatures in excess of 1,000K and are considered critical for the development of ultra hightemperature reactors. Tungsten alloys are known to possess extraordinary properties, such as excellent high-temperature capability, including the ability to resist leakage of fissile materials when used as a fuel clad. However, there are difficulties with the development of refractory alloys: 1) lack of basic experimental data on thermodynamics and mechanical and physical properties, and 2) challenges associated with processing these alloys.

Indrajit Charit; Darryl Butt; Megan Frary; Mark Carroll

2012-11-05T23:59:59.000Z

134

High-temperature thermocouples and related methods  

DOE Patents (OSTI)

A high-temperature thermocouple and methods for fabricating a thermocouple capable of long-term operation in high-temperature, hostile environments without significant signal degradation or shortened thermocouple lifetime due to heat induced brittleness.

Rempe, Joy L. (Idaho Falls, ID); Knudson, Darrell L. (Firth, ID); Condie, Keith G. (Idaho Falls, ID); Wilkins, S. Curt (Idaho Falls, ID)

2011-01-18T23:59:59.000Z

135

High-temperature Pump Monitoring - High-temperature ESP Monitoring...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

at least at the outset, exclude new ideas. The drift issue appears to have brought a new search for materials into this research. * Objectives: Develop temperature and pressure...

136

Reciprocity theorem in high-temperature superconductors  

E-Print Network (OSTI)

This article is devoted to the problem of the validity of the reciprocity theorem in high-temperature

Ivan Jane?ek

2002-01-01T23:59:59.000Z

137

Scaling in high-temperature superconductors by  

E-Print Network (OSTI)

A Hartree approximation is used to study the interplay of two kinds of scaling which arise in high-temperature

Ian D Lawrie

1994-01-01T23:59:59.000Z

138

Agenda: High Temperature Membrane Working Group Meeting  

Energy.gov (U.S. Department of Energy (DOE))

Agenda for the High Temperature Membrane Working Group (HTMWG) meeting on May 18, 2009, in Arlington, Virginia

139

Materials Degradation Studies for High Temperature Steam Electrolysis Systems  

SciTech Connect

Experiments are currently in progress to assess the high temperature degradation behavior of materials in solid oxide electrolysis systems. This research includes the investigation of various electrolysis cell components and balance of plant materials under both anodic and cathodic gas atmospheres at temperatures up to 850C. Current results include corrosion data for a high temperature nickel alloy used for the air-side flow field in electrolysis cells and a commercial ferritic stainless steel used as the metallic interconnect. Three different corrosion inhibiting coatings were also tested on the steel material. The samples were tested at 850C for 500 h in both air and H2O/H2 atmospheres. The results of this research will be used to identify degradation mechanisms and demonstrate the suitability of candidate materials for long-term operation in electrolysis cells.

Paul Demkowicz; Pavel Medvedev; Kevin DeWall; Paul Lessing

2007-06-01T23:59:59.000Z

140

High Temperature Superconducting Underground Cable  

SciTech Connect

The purpose of this Project was to design, build, install and demonstrate the technical feasibility of an underground high temperature superconducting (HTS) power cable installed between two utility substations. In the first phase two HTS cables, 320 m and 30 m in length, were constructed using 1st generation BSCCO wire. The two 34.5 kV, 800 Arms, 48 MVA sections were connected together using a superconducting joint in an underground vault. In the second phase the 30 m BSCCO cable was replaced by one constructed with 2nd generation YBCO wire. 2nd generation wire is needed for commercialization because of inherent cost and performance benefits. Primary objectives of the Project were to build and operate an HTS cable system which demonstrates significant progress towards commercial progress and addresses real world utility concerns such as installation, maintenance, reliability and compatibility with the existing grid. Four key technical areas addressed were the HTS cable and terminations (where the cable connects to the grid), cryogenic refrigeration system, underground cable-to-cable joint (needed for replacement of cable sections) and cost-effective 2nd generation HTS wire. This was the worlds first installation and operation of an HTS cable underground, between two utility substations as well as the first to demonstrate a cable-to-cable joint, remote monitoring system and 2nd generation HTS.

Farrell, Roger, A.

2010-02-28T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

High-temperature fabricable nickel-iron aluminides  

DOE Patents (OSTI)

Nickel-iron aluminides are described that are based on Ni.sub.3 Al, and have significant iron content, to which additions of hafnium, boron, carbon and cerium are made resulting in Ni.sub.3 Al base alloys that can be fabricated at higher temperatures than similar alloys previously developed. Further addition of molybdenum improves oxidation and cracking resistance. These alloys possess the advantages of ductility, hot fabricability, strength, and oxidation resistance.

Liu, Chain T. (Oak Ridge, TN)

1988-02-02T23:59:59.000Z

142

High-Temperature Galling Characteristics of Ti-6Al-4V with and without Surface Treatments  

SciTech Connect

Galling is a severe form of surface damage in metals and alloys that typically arises under relatively high normal force, low-sliding speed, and in the absence of effective lubrication. It can lead to macroscopic surface roughening and seizure. The occurrence of galling can be especially problematic in high-temperature applications like diesel engine exhaust gas recirculation system components and adjustable turbocharger vanes, because suitable lubricants may not be available, moisture desorption promotes increased adhesion, and the yield strength of metals decreases with temperature. Oxidation can counteract these effects to some extent by forming lubricative oxide films. Two methods to improve the galling resistance of titanium alloy Ti-6Al-4V were investigated: (a) applying an oxygen diffusion treatment, and (b) creating a metal-matrix composite with TiB2 using a high-intensity infrared heating source. A new, oscillating three-pin-on-flat, high-temperature test method was developed and used to characterize galling behavior relative to a cobalt-based alloy (Stellite 6B ). The magnitude of the oscillating torque, the surface roughness, and observations of surface damage were used as measures of galling resistance. Owing to the formation of lubricative oxide films, the galling resistance of the Ti-alloy at 485o C, even non-treated, was considerably better than it was at room temperature. The IR-formed composite displayed reduced surface damage and lower torque than the substrate titanium alloy.

Blau, Peter Julian [ORNL; ERDMAN III, DONALD L [ORNL; Ohriner, Evan Keith [ORNL; Jolly, Brian C [ORNL

2011-01-01T23:59:59.000Z

143

Highly mismatched crystalline and amorphous GaN(1-x)As(x) alloys in the whole composition range  

SciTech Connect

Alloying is a commonly accepted method to tailor properties of semiconductor materials for specific applications. Only a limited number of semiconductor alloys can be easily synthesized in the full composition range. Such alloys are, in general, formed of component elements that are well matched in terms of ionicity, atom size, and electronegativity. In contrast there is a broad class of potential semiconductor alloys formed of component materials with distinctly different properties. In most instances these mismatched alloys are immiscible under standard growth conditions. Here we report on the properties of GaN1-xAsx, a highly mismatched, immiscible alloy system that was successfully synthesized in the whole composition range using a nonequilibrium low temperature molecular beam epitaxy technique. The alloys are amorphous in the composition range of 0.17alloys with x>0.2, and to the upward movement of the valence band for alloys with x<0.2. The unique features of the band structure offer an opportunity of using GaN1-xAsx alloys for various types of solar power conversion devices.

Yu, K. M.; Novikov, S. V.; Broesler, R.; Demchenko, I. N.; Denlinger, J. D.; Liliental-Weber, Z.; Luckert, F.; Martin, R. W.; Walukiewicz, W.; Foxon, C. T.

2009-08-29T23:59:59.000Z

144

Electrochemical investigations of various high-temperature superconductor phases  

Science Journals Connector (OSTI)

Electrochemical investigations of various high-temperature superconductor phases ... Electrochemistry of High-Temperature Superconductors ...

David R. Riley; A. Manthiram; John T. McDevitt

1992-11-01T23:59:59.000Z

145

High permeance sulfur tolerant Pd/Cu alloy membranes  

DOE Patents (OSTI)

A method of making a membrane permeable to hydrogen gas (H.sub.2.uparw.) is disclosed. The membrane is made by forming a palladium layer, depositing a layer of copper on the palladium layer, and galvanically displacing a portion of the copper with palladium. The membrane has improved resistance to poisoning by H.sub.2S compared to a palladium membrane. The membrane also has increased permeance of hydrogen gas compared to palladium-copper alloys. The membrane can be annealed at a lower temperature for a shorter amount of time.

Ma, Yi Hua; Pomerantz, Natalie

2014-02-18T23:59:59.000Z

146

Adjusting alloy compositions for selected properties in temperature limited heaters  

DOE Patents (OSTI)

Heaters for treating a subsurface formation are described herein. Such heaters can be obtained by using the systems and methods described herein. The heater includes a heater section including iron, cobalt, and carbon. The heater section has a Curie temperature less than a phase transformation temperature. The Curie temperature is at least 740.degree. C. The heater section provides, when time varying current is applied to the heater section, an electrical resistance.

Brady; Michael Patrick (Oak Ridge, TN), Horton, Jr.; Joseph Arno (Oak Ridge, TN), Vitek; John Michael (Oak Ridge, TN)

2010-03-23T23:59:59.000Z

147

Long, Highly-Ordered High-Temperature Superconductor Nanowire Arrays  

Science Journals Connector (OSTI)

Long, Highly-Ordered High-Temperature Superconductor Nanowire Arrays ... For bulk superconductors, the electrical resistance drops precipitously to zero below the superconducting transition temperature (Tc). ... Even these temperatures are considerably higher than those found in conventional superconductor NWs of similar widths, which are typically below liquid helium temperature (4.2 K). ...

Ke Xu; James R. Heath

2008-10-28T23:59:59.000Z

148

9 Cr-- 1 Mo steel material for high temperature application  

DOE Patents (OSTI)

One or more embodiments relates to a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650.degree. C. The 9 Cr-1 Mo steel has a tempered martensite microstructure and is comprised of both large (0.5-3 .mu.m) primary titanium carbides and small (5-50 nm) secondary titanium carbides in a ratio of. from about 1:1.5 to about 1.5:1. The 9 Cr-1 Mo steel may be fabricated using exemplary austenizing, rapid cooling, and tempering steps without subsequent hot working requirements. The 9 Cr-1 Mo steel exhibits improvements in total mass gain, yield strength, and time-to-rupture over ASTM P91 and ASTM P92 at the temperature and time conditions examined.

Jablonski, Paul D; Alman, David; Dogan, Omer; Holcomb, Gordon; Cowen, Christopher

2012-11-27T23:59:59.000Z

149

An internal winding high temperature heater  

Science Journals Connector (OSTI)

An internal winding high temperature heater ... General principles are outlined for the construction of compact heaters that are suitable for heating small containers or reaction vessels at constant temperature and up to about 1000 C. ...

A. J. Delbouille; E. G. Derouane

1973-01-01T23:59:59.000Z

150

A Comparison of the Corrosion Resistance of Iron-Based Amorphous Metals and Austenitic Alloys in Synthetic Brines at Elevated Temperature  

SciTech Connect

Several hard, corrosion-resistant and neutron-absorbing iron-based amorphous alloys have now been developed that can be applied as thermal spray coatings. These new alloys include relatively high concentrations of Cr, Mo, and W for enhanced corrosion resistance, and substantial B to enable both glass formation and neutron absorption. The corrosion resistances of these novel alloys have been compared to that of several austenitic alloys in a broad range of synthetic brines, with and without nitrate inhibitor, at elevated temperature. Linear polarization and electrochemical impedance spectroscopy have been used for in situ measurement of corrosion rates for prolonged periods of time, while scanning electron microscopy (SEM) and energy dispersive analysis of X-rays (EDAX) have been used for ex situ characterization of samples at the end of tests. The application of these new coatings for the protection of spent nuclear fuel storage systems, equipment in nuclear service, steel-reinforced concrete will be discussed.

Farmer, J C

2008-11-25T23:59:59.000Z

151

High-Temperature-High-Volume Lifting for Enhanced Geothermal Systems  

Energy.gov (U.S. Department of Energy (DOE))

High-Temperature-High-Volume Lifting for Enhanced Geothermal Systems presentation at the April 2013 peer review meeting held in Denver, Colorado.

152

High Temperature Solar Splitting of Methane  

E-Print Network (OSTI)

-term commercialization opportunities #12;Why Use Solar Energy?Why Use Solar Energy? · High concentrations possible (>1000High Temperature Solar Splitting of Methane to Hydrogen and Carbon High Temperature Solar Splitting and worldwide) ­ Sufficient to power the world (if we choose to) · Advantages tradeoff against collection area

153

QED3 Theory of High Temperature Superconductors  

E-Print Network (OSTI)

QED3 Theory of High Temperature Superconductors Zlatko Tesanovi´c The Johns Hopkins University is The Problem in high Tc superconductors? · Superconducting state appears dx2-y2 "BCS-like". Low energy: · Today, everything seems to be a high temperature superconduc- tor (cuprates, C60's, MgB2

Tesanovic, Zlatko

154

Nanostructured High Temperature Bulk Thermoelectric Energy Conversion...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Efficient Automotive Waste Heat Recovery Multi-physics modeling of thermoelectric generators for waste heat recovery applications Nanostructured High-Temperature Bulk...

155

High Temperature Thermoelectric Materials Characterization for...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

2009 -- Washington D.C. lmp06wang.pdf More Documents & Publications High-Temperature Thermoelectric Materials Characterization for Automotive Waste Heat Recovery: Success...

156

Materials Characterization Capabilities at the High Temperature...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Laboratory and HTML User Program Success Stories Materials Characterization Capabilities at the High Temperature Materials Laboratory: Focus on Carbon Fiber and Composites...

157

High Temperature Materials Laboratory (HTML) - PSD Directorate  

NLE Websites -- All DOE Office Websites (Extended Search)

filler A National Resource for Collaborative Materials Research The High Temperature Materials Laboratory (HTML) User Program is on hiatus due to federal budget reductions....

158

Project Profile: High Operating Temperature Liquid Metal Heat...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

investigating the use of metal alloys as a heat transfer fluid (HTF) in concentrating solar power (CSP) systems operating at temperatures in excess of 800C. By allowing higher...

159

The resistivity-temperature-concentration relationships in ?-phase titanium-hydrogen alloys  

Science Journals Connector (OSTI)

An attempt has been made to test the tentative conclusion reached in earlier work on the resistivity/ composition curves for ?-phase titanium-niobium alloys that the extrapolated resistivity/temperature relationship for unalloyed ?-titanium at temperatures below the ?-? transformation temperature would have a form more to be expected from a semiconductor than from a pure metal. This has been done by means of similar studies of ?-phase titanium-hydrogen alloys in which resistivity measurements were made over a temperature range of 400904C and at compositions up to TiH. The form of the resistivity/composition curves has precluded their direct extrapolation to zero hydrogen content except at temperatures only just below the transformation temperature, but a more detailed analysis of the experimental results has provided some basis for a not unreasonable extrapolation of the resistivity/composition isotherms at lower temperatures, and the results thus obtained agree qualitatively with those of the earlier work. The validity of the various assumptions made is discussed. The present results indicate that at 480C, below the transformation temperature, the resistivity of ?-titanium would have fallen only 2% below the value of the resistivity immediately above the transformation temperature, and not by the 40% to be expected of a normal metal.

S.L Ames; A.D McQuillan

1956-01-01T23:59:59.000Z

160

Experimental study of the relationship between temperature and adhesive forces for low-alloyed steel, stainless steel, and titanium using atomic force microscopy in ultrahigh vacuum  

Science Journals Connector (OSTI)

Dry sliding contact between metallic surfaces is often associated with high surfacetemperatures due to frictional heating and adhesive wear resulting in high friction and severe surface damage. In the present research the dependence of adhesive forces on temperature for commercial low-alloyed steel stainless steel and pure titanium was investigated in ultrahigh vacuum at elevated temperatures using atomic force microscopy. It was found that adhesive forces increased as the temperature increased. Room-temperature values of adhesive forces decreased in the order Ti stainless steel and low-alloyed steel which agreed with the values of the electron work function measured by a Kelvin probe. The findings correlate well with results observed for the same materials using conventional macroscopic tribotesters.

A. Grd; P. Krakhmalev; J. Bergstrm; J. Hirvonen Grytzelius; H. M. Zhang

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Processes yielding high superconducting temperatures  

SciTech Connect

It is pointed out that any microscopic description of the new high-T/sub c/ superconductors should take into account a number of important points concerning strong couplings, whatever their nature: absence of the MacMillan limit, absence of a Migdal theorem, and importance of the Brovman-Kagan type of vertices with different singularities depending on the dimensionality. As a consequence, the applicability of standard techniques such as the Eliashberg theory in particular, may be questioned in high-T/sub c/ superconductors.

Beal-Monod, M.T.

1987-12-01T23:59:59.000Z

162

Hole doping in high temperature superconductors using the XANES technique  

E-Print Network (OSTI)

Hole doping in high temperature superconductors using the1994 Thallium-Based High Temperature Superconductors ed A M1994 Thallium-Based High Temperature Superconductors ed A M

Hamdan, Nasser

2012-01-01T23:59:59.000Z

163

Energy-Saving Melting and Revert Reduction Technology (E-SMARRT): Development of Elevated Temperature Aluminum Metal Matrix Composite (MMC) Alloy and Its Processing Technology  

SciTech Connect

The objective of this project was to provide a production capable cast aluminum metal matrix composite (MMC) alloy with an operating temperature capability of 250-300C. Important industrial sectors as well as the military now seek lightweight aluminum alloy castings that can operate in temperature ranges of 250-300C. Current needs in this temperature range are being satisfied by the use of titanium alloy castings. These have the desired strength properties but the end components are heavier and significantly more costly. Also, the energy requirements for production of titanium alloy castings are significantly higher than those required for production of aluminum alloys and aluminum alloy castings.

Weiss, David C. [Eck Industreis, Inc.] [Eck Industreis, Inc.; Gegal, Gerald A.

2014-04-15T23:59:59.000Z

164

Development of a Two-Phase Model for the Hot Deformation of Highly-Alloyed Aluminum  

SciTech Connect

Conventional processing methods for highly alloyed aluminum consist of ingot casting, followed by hot rolling and thermal treatments. Defects result in lost productivity and wasted energy through the need to remelt and reprocess the material. This research centers on developing a fundamental understanding for deformation of wrought 705X series alloys, a key alloy system used in structural airframe applications. The development of damage at grain boundaries is characterized through a novel test that provides initiation of failure while preserving a controlled deformation response. Data from these mechanical tests are linked to computer simulations of the hot rolling process through a critical measure of damage. Transmission electron microscopy provides fundamental insight into deformation at these high working temperatures, and--in a novel link between microscale and macroscale response--the evolution of microstructure (crystallographic orientation) provides feedback for tuning of friction in the hot rolling process. The key product of this research is a modeling framework for the analysis of industrial hot rolling.

A. J. Beaudoin; J. A. Dantzig; I. M. Robertson; B. E. Gore; S. F. Harnish; H. A. Padilla

2005-10-31T23:59:59.000Z

165

HIGH TEMPERATURE SULFIDATION BEHAVIOR OF LOW Al IRON-ALUMINUM COMPOSITIONS  

E-Print Network (OSTI)

HIGH TEMPERATURE SULFIDATION BEHAVIOR OF LOW Al IRON-ALUMINUM COMPOSITIONS S.W. Banovic, J.N. Du (Received January 5, 1998) (Accepted March 23, 1998) Introduction Iron-aluminum weld overlay coatings, the application of iron-aluminum alloys is currently limited due to hydrogen cracking susceptibility subsequent

DuPont, John N.

166

Overcharge tolerant high-temperature cells and batteries  

DOE Patents (OSTI)

In a lithium-alloy/metal sulfide high temperature electrochemical cell, cell damage caused by overcharging is avoided by providing excess lithium in a high-lithium solubility phase alloy in the negative electrode and a specified ratio maximum of the capacity of a matrix metal of the negative electrode in the working phase to the capacity of a transition metal of the positive electrode. In charging the cell, or a plurality of such cells in series and/or parallel, chemical transfer of elemental lithium from the negative electrode through the electrolyte to the positive electrode provides sufficient lithium to support an increased self-charge current to avoid anodic dissolution of the positive electrode components above a critical potential. The lithium is subsequently electrochemically transferred back to the negative electrode in an electrochemical/chemical cycle which maintains high self-discharge currents on the order of 3-15 mA/cm.sup.2 in the cell to prevent overcharging.

Redey, Laszlo (Downers Grove, IL); Nelson, Paul A. (Wheaton, IL)

1989-01-01T23:59:59.000Z

167

High temperature solar selective coatings  

DOE Patents (OSTI)

Improved solar collectors (40) comprising glass tubing (42) attached to bellows (44) by airtight seals (56) enclose solar absorber tubes (50) inside an annular evacuated space (54. The exterior surfaces of the solar absorber tubes (50) are coated with improved solar selective coatings {48} which provide higher absorbance, lower emittance and resistance to atmospheric oxidation at elevated temperatures. The coatings are multilayered structures comprising solar absorbent layers (26) applied to the meta surface of the absorber tubes (50), typically stainless steel, topped with antireflective Savers (28) comprising at least two layers 30, 32) of refractory metal or metalloid oxides (such as titania and silica) with substantially differing indices of refraction in adjacent layers. Optionally, at least one layer of a noble metal such as platinum can be included between some of the layers. The absorbent layers cars include cermet materials comprising particles of metal compounds is a matrix, which can contain oxides of refractory metals or metalloids such as silicon. Reflective layers within the coating layers can comprise refractory metal silicides and related compounds characterized by the formulas TiSi. Ti.sub.3SiC.sub.2, TiAlSi, TiAN and similar compounds for Zr and Hf. The titania can be characterized by the formulas TiO.sub.2, Ti.sub.3O.sub.5. TiOx or TiO.sub.xN.sub.1-x with x 0 to 1. The silica can be at least one of SiO.sub.2, SiO.sub.2x or SiO.sub.2xN.sub.1-x with x=0 to 1.

Kennedy, Cheryl E

2014-11-25T23:59:59.000Z

168

Thermally activated low temperature creep and primary water stress corrosion cracking of NiCrFe alloys  

SciTech Connect

A phenomenological SCC-CGR model is developed based on an apriori assumption that the SCC-CGR is controlled by low temperature creep (LTC). This mode of low temperature time dependent deformation occurs at stress levels above the athermal flow stress by a dislocation glide mechanism that is thermally activated and may be environmentally assisted. The SCC-CGR model equations developed contain thermal activation parameters descriptive of the dislocation creep mechanism. Thermal activation parameters are obtained by fitting the CGR model to SCC-CGR data obtained on Alloy 600 and Alloy X-750. These SCC-CGR activation parameters are compared to LTC activation parameters obtained from stress relaxation tests. When the high concentration of hydrogen at the tip of an SCC crack is considered, the SCC-CGR activation energies and rate sensitivities are shown to be quantitatively consistent with hydrogen reducing the activation energy and increasing the strain rate sensitivity in LTC stress relaxation tests. Stress dependence of SCC-CGR activation energy consistent with that found for the LTC activation energy. Comparisons between temperature dependence of the SCC-CGR stress sensitivity and LTC stress sensitivity provide a basis for speculation on effects of hydrogen and solute carbon on SCC crack growth rates.

Hall, M.M. Jr.

1993-10-01T23:59:59.000Z

169

High Temperature, High Pressure Devices for Zonal Isolation in...  

Open Energy Info (EERE)

remotely and autonomous deployable structures for space and our high temperature composite technology developed for downhole applications. These devices offer several...

170

High-Temperature-High-Volume Lifting for Enhanced Geothermal...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Norman Turnquist GE Global Research High Temperature Tools and Sensors, Down-hole Pumps and Drilling May 19, 2010 This presentation does not contain any proprietary...

171

Effect of laser tempering of high alloy powder metallurgical tool steels after laser cladding  

Science Journals Connector (OSTI)

Abstract The effect of tempering after laser cladding of a high alloyed powder metallurgical tool steel was studied for die repairing purposes. In particular, a high power diode laser with scanning optics was employed for tempering. The laser tempering temperature was proven to be a critical factor in improving the mechanical properties of the coatings. In order to measure and evaluate the effect of different processing parameters (mainly laser power and linear speed) on the achieved temperature, an infrared camera and a two-color pyrometer were used. The tempering effect was mainly evaluated through cross-section microhardness profiles. The microstructure of the coatings was also studied using optical and scanning electron microscope, and the volumetric fraction of retained austenite was determined by X-ray diffraction. Experimental results demonstrated that laser tempering is a useful and appealing technique to improve the hardness of laser deposited coatings of high alloyed tool steels, which is a clear advantage when large parts have to be repaired or reinforced by laser cladding.

Josu Leunda; Virginia Garca Navas; Carlos Soriano; Carmen Sanz

2014-01-01T23:59:59.000Z

172

Highly Mismatched Alloys for Intermediate Band Solar Cells  

SciTech Connect

It has long been recognized that the introduction of a narrow band of states in a semiconductor band gap could be used to achieve improved power conversion efficiency in semiconductor-based solar cells. The intermediate band would serve as a ''stepping stone'' for photons of different energy to excite electrons from the valence to the conduction band. An important advantage of this design is that it requires formation of only a single p-n junction, which is a crucial simplification in comparison to multijunction solar cells. A detailed balance analysis predicts a limiting efficiency of more than 50% for an optimized, single intermediate band solar cell. This is higher than the efficiency of an optimized two junction solar cell. Using ion beam implantation and pulsed laser melting we have synthesized Zn{sub 1-y}Mn{sub y}O{sub x}Te{sub 1-x} alloys with x<0.03. These highly mismatched alloys have a unique electronic structure with a narrow oxygen-derived intermediate band. The width and the location of the band is described by the Band Anticrossing model and can be varied by controlling the oxygen content. This provides a unique opportunity to optimize the absorption of solar photons for best solar cell performance. We have carried out systematic studies of the effects of the intermediate band on the optical and electrical properties of Zn{sub 1-y}Mn{sub y}O{sub x}Te{sub 1-x} alloys. We observe an extension of the photovoltaic response towards lower photon energies, which is a clear indication of optical transitions from the valence to the intermediate band.

Walukiewicz, W.; Yu, K.M.; Wu, J.; Ager III, J.W.; Shan, W.; Scrapulla, M.A.; Dubon, O.D.; Becla, P.

2005-03-21T23:59:59.000Z

173

Symposium on high temperature and materials chemistry  

SciTech Connect

This volume contains the written proceedings of the Symposium on High Temperature and Materials Chemistry held in Berkeley, California on October 24--25, 1989. The Symposium was sponsored by the Materials and Chemical Sciences Division of Lawrence Berkeley Laboratory and by the College of Chemistry of the University of California at Berkeley to discuss directions, trends, and accomplishments in the field of high temperature and materials chemistry. Its purpose was to provide a snapshot of high temperature and materials chemistry and, in so doing, to define status and directions.

Not Available

1989-10-01T23:59:59.000Z

174

Temperature dependence of vortex charges in high-temperature superconductors  

Science Journals Connector (OSTI)

Using a model Hamiltonian with d-wave superconductivity and competing antiferromagnetic (AF) interactions, the temperature (T) dependence of the vortex charge in high-Tc superconductors is investigated by numerically solving the Bogoliubovde Gennes equations. The strength of the induced AF order inside the vortex core is T dependent. The vortex charge could be negative when the AF order with sufficient strength is present at low temperatures. At higher temperatures, the AF order may be completely suppressed and the vortex charge becomes positive. A first-order-like transition in the T-dependent vortex charge is seen near the critical temperature TAF. For an underdoped sample, the spatial profiles of the induced spin-density wave and the charge-density wave orders could have stripelike structures at TTs. As a result, a vortex charge discontinuity occurs at Ts.

Yan Chen; Z. D. Wang; C. S. Ting

2003-06-03T23:59:59.000Z

175

Methods for nondestructive testing of austenitic high-temperature gas-cooled reactor components  

SciTech Connect

Safety-relevant components of high-temperature gas-cooled reactor components are mostly fabricated in nickel-based alloys and austenitic materials like Inconel-617, Hastelloy-X, Nimonic-86, or Incoloy-800H. Compared to ferritic steels, these austenitic materials can have a coarse-grained microstructure, especially in weldments and castings. Coarse-grained or elastic anisotropic materials are difficult to inspect with ultrasonics due to strong attenuation, high noise level (scattering, ''grass'' indications), and sound beam distortions (skewing, splitting, and mode conversion). Only few results dealing with the nondestructive testing of nickel-based alloys are known. The problem area, solutions, and first experiences are reported.

Gobbels, K.; Kapitza, H.

1984-09-01T23:59:59.000Z

176

Advanced high temperature materials for the energy efficient automotive Stirling engine  

SciTech Connect

The Stirling engine is under investigation jointly by the Department of Energy and NASA Lewis as an alternative to the internal combustion engine for automotive applications. The Stirling engine is an external combustion engine that offers the advantage of high fuel economy, low emissions, low noise, and low vibrations compared to current internal combustion automotive engines. The most critical component from a materials viewpoint is the heater head consisting of the cylinders, heating tubes, and regenerator housing. Materials requirements for the heater head include compatibility with hydrogen, resistance to hydrogen permeation, high temperature oxidation/corrosion resistance and high temperature creep-rupture and fatigue properties. A continuing supporting materials research and technology program has identified the wrought alloys CG-27 and 12RN72 and the cast alloys XF-818 and NASAUT 4G-A1 as candidate replacements for the cobalt containing alloys used in current prototype engines. Based on the materials research program in support of the automotive Stirling engine it is concluded that manufacture of the engine is feasible from low cost iron-base alloys rather than the cobalt alloys used in prototype engines. This paper will present results of research that led to this conclusion.

Titran, R.H.; Stephens, J.R.

1984-01-01T23:59:59.000Z

177

Metallic Hydrogen: A High-Temperature Superconductor?  

Science Journals Connector (OSTI)

Application of the BCS theory to the proposed metallic modification of hydrogen suggests that it will be a high-temperature superconductor. This prediction has interesting astrophysical consequences, as well as implications for the possible development of a superconductor for use at elevated temperatures.

N. W. Ashcroft

1968-12-23T23:59:59.000Z

178

Noise Absorbing High-Temperature Insulation  

Science Journals Connector (OSTI)

Until recently simple heat shields on the engine, in the engine space or on the subframe of a vehicle had given protection against radiant heat from hot components. Today, complex high-temperature insulation syst...

Peter Cappellucci

2013-07-01T23:59:59.000Z

179

Thermodynamics of high-temperature nuclear fuel  

Science Journals Connector (OSTI)

A method for performing a thermodynamic analysis of the high-temperature nuclear fuel using the ASTA computer program is substantiated. Calculations of the chemical composition and pressure of the gas phase of...

I. A. Belov; A. S. Ivanov

180

High Temperature Corrosion Test Facilities and High Pressure Test  

NLE Websites -- All DOE Office Websites (Extended Search)

High Temperature High Temperature Corrosion Test Facilities and High Pressure Test Facilities for Metal Dusting Test Facilities for Metal Dusting Overview Other Facilities Work with Argonne Contact us For Employees Site Map Help Join us on Facebook Follow us on Twitter NE on Flickr High Temperature Corrosion Test Facilities and High Pressure Test Facilities for Metal Dusting Six corrosion test facilities and two thermogravimetric systems for conducting corrosion tests in complex mixed gas environments, in steam and in the presence of deposits, and five facilities for metal dusting degradation Bookmark and Share The High Temperature Corrosion Test Facilities and High Pressure Test Facilities for Metal Dusting include: High Pressure Test Facility for Metal Dusting Resistance:

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

High temperature thermometric phosphors for use in a temperature sensor  

DOE Patents (OSTI)

A high temperature phosphor consists essentially of a material having the general formula LuPO.sub.4 :Dy.sub.(x),Eu.sub.(y), wherein: 0.1 wt %.ltoreq.x.ltoreq.20 wt % and 0.1 wt %.ltoreq.y.ltoreq.20 wt %. The high temperature phosphor is in contact with an article whose temperature is to be determined. The article having the phosphor in contact with it is placed in the environment for which the temperature of the article is to be determined. The phosphor is excited by a laser causing the phosphor to fluoresce. The emission from the phosphor is optically focused into a beam-splitting mirror which separates the emission into two separate emissions, the emission caused by the dysprosium dopant and the emission caused by the europium dopent. The separated emissions are optically filtered and the intensities of the emission are detected and measured. The ratio of the intensity of each emission is determined and the temperature of the article is calculated from the ratio of the intensities of the separate emissions.

Allison, Stephen W. (Knoxville, TN); Cates, Michael R. (Oak Ridge, TN); Boatner, Lynn A. (Oak Ridge, TN); Gillies, George T. (Earlysville, VA)

1998-01-01T23:59:59.000Z

182

High Growth Rate of Epitaxial Silicon-Carbon Alloys by High-Order Silane Precursor and Chemical Vapor Deposition  

E-Print Network (OSTI)

rates typically achieved by disilane and silane, respectively, at 575o C. The rate at present is limited precursor HOS than disilane in CVD, even at lower temperatures. Our current growth rates of Si1-yCy alloys

183

Materials Reliability Program Low-Temperature Cracking of Nickel-Based Alloys and Weld Metals (MRP-108)  

SciTech Connect

OAK-B135 A rising load test in low-temperature (50-100 degree C) pH 10 water containing a high concentration of dissolved hydrogen (150 cc/kg) has demonstrated that Alloy 690 as well as weld metals 82 and 52 exhibit a marked loss of ductility. A similar loss of ductility has been shown to occur in widely used weld metal 182 under replica test conditions and simulated PWR primary water containing 100 cc/kg of hydrogen. The objective of this report was to confirm the Bettis test results for weld metal 82 and determine whether weld metal 182 is susceptible to the same reductions in toughness. This report documents the first industry effort to reckon with the low temperature crack propagation (LTCP) issue.

B. Young

2004-02-01T23:59:59.000Z

184

High temperature crystalline superconductors from crystallized glasses  

DOE Patents (OSTI)

A method of preparing a high temperature superconductor from an amorphous phase. The method involves preparing a starting material of a composition of Bi.sub.2 Sr.sub.2 Ca.sub.3 Cu.sub.4 Ox or Bi.sub.2 Sr.sub.2 Ca.sub.4 Cu.sub.5 Ox, forming an amorphous phase of the composition and heat treating the amorphous phase for particular time and temperature ranges to achieve a single phase high temperature superconductor.

Shi, Donglu (Downers Grove, IL)

1992-01-01T23:59:59.000Z

185

Apparatus and method for high temperature viscosity and temperature measurements  

DOE Patents (OSTI)

A probe for measuring the viscosity and/or temperature of high temperature liquids, such as molten metals, glass and similar materials comprises a rod which is an acoustical waveguide through which a transducer emits an ultrasonic signal through one end of the probe, and which is reflected from (a) a notch or slit or an interface between two materials of the probe and (b) from the other end of the probe which is in contact with the hot liquid or hot melt, and is detected by the same transducer at the signal emission end. To avoid the harmful effects of introducing a thermally conductive heat sink into the melt, the probe is made of relatively thermally insulative (non-heat-conductive) refractory material. The time between signal emission and reflection, and the amplitude of reflections, are compared against calibration curves to obtain temperature and viscosity values.

Balasubramaniam, Krishnan (Mississippi State, MS); Shah, Vimal (Houston, TX); Costley, R. Daniel (Mississippi State, MS); Singh, Jagdish P. (Mississippi State, MS)

2001-01-01T23:59:59.000Z

186

In-situ investigation of phase formation in nanocrystalline (Co97.5Fe2.5)89Zr7B4 alloy by high temperature x-ray diffraction  

E-Print Network (OSTI)

National Energy Technology Laboratory, Chemistry and Surface Science Division, Pittsburgh, Pennsylvania and the presence of at least two phases. HTXRD results show preferential body centered cubic (bcc) nucleation remained at temperatures above 600 C. On heating, the lattice parameter of the fcc phase increases

McHenry, Michael E.

187

Understanding Fundamental Material Degradation Processes in High Temperature Aggressive Chemomechanical Environments  

SciTech Connect

The objective of this project is to develop a fundamental understanding of the mechanisms that limit materials durability for very high-temperature applications. Current design limitations are based on material strength and corrosion resistance. This project will characterize the interactions of high-temperature creep, fatigue, and environmental attack in structural metallic alloys of interest for the very high-temperature gas-cooled reactor (VHTR) or NextGeneration Nuclear Plant (NGNP) and for the associated thermo-chemical processing systems for hydrogen generation. Each of these degradation processes presents a major materials design challenge on its own, but in combination, they can act synergistically to rapidly degrade materials and limit component lives. This research and development effort will provide experimental results to characterize creep-fatigue-environment interactions and develop predictive models to define operation limits for high-temperature structural material applications. Researchers will study individually and in combination creep-fatigue-environmental attack processes in Alloys 617, 230, and 800H, as well as in an advanced Ni-Cr oxide dispersion strengthened steel (ODS) system. For comparison, the study will also examine basic degradation processes in nichrome (Ni-20Cr), which is a basis for most high-temperature structural materials, as well as many of the superalloys. These materials are selected to represent primary candidate alloys, one advanced developmental alloy that may have superior high-temperature durability, and one model system on which basic performance and modeling efforts can be based. The research program is presented in four parts, which all complement each other. The first three are primarily experimental in nature, and the last will tie the work together in a coordinated modeling effort. The sections are 1) dynamic creep-fatigue-environment process, 2) subcritical crack processes, 3) dynamic corrosion crack initiation processes, and 4) modeling.

Stubbins, James; Gewirth, Andrew; Sehitoglu, Huseyin; Sofronis, Petros; Robertson, Ian

2014-01-16T23:59:59.000Z

188

High Temperature, Permanent Magnet Biased Magnetic Bearings  

E-Print Network (OSTI)

performance, high speed and high temperature applications like space vehicles, jet engines and deep sea equipment. The bearing system had a target design to carry a load equal to 500 lb-f (2225N). Another objective was to design and build a test rig fixture...

Gandhi, Varun R.

2010-07-14T23:59:59.000Z

189

Low-temperature magnetization in Ni-rich gamma-Ni100-x-yFexVy alloys  

E-Print Network (OSTI)

is antiferromagnetic) suppresses the ferromagnetic order in the NiFe binary alloys. The magnetization of the alloys with low V (y less than or equal to 11 at. %) has shown a good fit to only the spin-wave T-3/2 term whereas the data for the high V (gamma greater than...

Chakraborty, S.; Mukherjee, GD; Rathnayaka, KDD; Naugle, Donald G.; Majumdar, AK.

2000-01-01T23:59:59.000Z

190

Method of treating intermetallic alloy hydrogenation/oxidation catalysts for improved impurity poisoning resistance, regeneration and increased activity  

DOE Patents (OSTI)

Alternate, successive high temperature oxidation and reduction treatments, in either order, of intermetallic alloy hydrogenation and intermetallic alloy oxidation catalysts unexpectedly improves the impurity poisoning resistance, regeneration capacity and/or activity of the catalysts. The particular alloy, and the final high temperature treatment given alloy (oxidation or reduction) will be chosen to correspond to the function of the catalyst (oxidation or hydrogenation).

Wright, Randy B. (Idaho Falls, ID)

1992-01-01T23:59:59.000Z

191

High Temperature Materials for Aerospace Applications  

E-Print Network (OSTI)

below 430 ?C for exposure times up to 20 minutes. Transition-metal carbides were initially synthesized by carbothermal reduction of transition-metal halides and polymer precursor mixtures, at temperatures that range from 900 to 1500 ?C in an argon... ........................................ 20 2.3 Present/Future Aerospace Applications ......................................... 24 2.4 Ultra-High Temperature Materials ................................................. 27 2.4.1 Transition-Metal Carbides...

Adamczak, Andrea Diane

2011-08-08T23:59:59.000Z

192

Laves phase hydrogen storage alloys for super-high-pressure metal hydride hydrogen compressors  

Science Journals Connector (OSTI)

Ti-Cr- and Ti-Mn-based alloys were prepared to be low- and high-pressure stage metals for a double-stage super-high-pressure metal hydride hydrogen compressor. Their crystallographic characteristics and hydrogen

Xiumei Guo; Shumao Wang; Xiaopeng Liu; Zhinian Li; Fang L; Jing Mi; Lei Hao

2011-06-01T23:59:59.000Z

193

High Temperature Cements | Open Energy Information  

Open Energy Info (EERE)

High Temperature Cements High Temperature Cements Jump to: navigation, search Geothermal ARRA Funded Projects for High Temperature Cements Loading map... {"format":"googlemaps3","type":"ROADMAP","types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"limit":200,"offset":0,"link":"all","sort":[""],"order":[],"headers":"show","mainlabel":"","intro":"","outro":"","searchlabel":"\u2026 further results","default":"","geoservice":"google","zoom":false,"width":"600px","height":"350px","centre":false,"layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","icon":"","visitedicon":"","forceshow":true,"showtitle":true,"hidenamespace":false,"template":false,"title":"","label":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"locations":[{"text":"

194

High Temperature Membrane & Advanced Cathode Catalyst Development  

SciTech Connect

Current project consisted of three main phases and eighteen milestones. Short description of each phase is given below. Table 1 lists program milestones. Phase 1--High Temperature Membrane and Advanced Catalyst Development. New polymers and advanced cathode catalysts were synthesized. The membranes and the catalysts were characterized and compared against specifications that are based on DOE program requirements. The best-in-class membranes and catalysts were downselected for phase 2. Phase 2--Catalyst Coated Membrane (CCM) Fabrication and Testing. Laboratory scale catalyst coated membranes (CCMs) were fabricated and tested using the down-selected membranes and catalysts. The catalysts and high temperature membrane CCMs were tested and optimized. Phase 3--Multi-cell stack fabrication. Full-size CCMs with the down-selected and optimized high temperature membrane and catalyst were fabricated. The catalyst membrane assemblies were tested in full size cells and multi-cell stack.

Protsailo, Lesia

2006-04-20T23:59:59.000Z

195

Manufacturing Barriers to High Temperature PEM Commercialization  

NLE Websites -- All DOE Office Websites (Extended Search)

9/2011 9/2011 1 BASF Fuel Cell, Inc. Manufacturing Barriers to high temperature PEM commercialization 39 Veronica Ave Somerset , NJ 08873 Tel : (732) 545-5100 9/9/2011 2 Background on BASF Fuel Cell  BASF Fuel Cell was established in 2007, formerly PEMEAS Fuel Cells (including E-TEK)  Product line is high temperature MEAs (Celtec ® P made from PBI-phosphoric acid)  Dedicated a new advanced pilot manufacturing facility in Somerset NJ May 2009. Ribbon-cutting hosted by Dr. Kreimeyer (BASF BoD, right) and attended by various US pubic officials including former NJ Governor Jon Corzine (left) 9/9/2011 3 Multi-layer product of membrane (polybenzimidazole and phosphoric acid), gas diffusion material and catalysts Unique characteristics:  High operating temperature

196

DEFORMATION BEHAVIOR OF A535 ALUMINUM ALLOY UNDER DIFFERENT STRAIN RATE AND TEMPERATURE CONDITIONS.  

E-Print Network (OSTI)

??Aluminum alloys are a suitable substitution for heavy ferrous alloys in automobile structures. The purpose of this study was to investigate the flow stress behavior (more)

Rezaei, Mojgan

2015-01-01T23:59:59.000Z

197

Frustrated phase separation and high temperature superconductivity  

SciTech Connect

A dilute system of neutral holes in an antiferromagnet separates into a hole-rich and a hole-poor phase. The phase separation is frustrated by long-range Coulomb interactions but, provided the dielectric constant is sufficiently large, there remain large-amplitude low-energy fluctuations in the hole density at intermediate length scales. The extensive experimental evidence showing that this behavior giver, a reasonable picture of high temperature superconductors is surveyed. Further, it is shown that the scattering of mobile holes from the local density fluctuations may account for the anomalous normal-state properties of high temperature superconductors and also provide the mechanism of pairing.

Emery, V.J. [Brookhaven National Lab., Upton, NY (United States); Kivelson, S.A. [California Univ., Los Angeles, CA (United States). Dept. of Physics

1992-09-01T23:59:59.000Z

198

Frustrated phase separation and high temperature superconductivity  

SciTech Connect

A dilute system of neutral holes in an antiferromagnet separates into a hole-rich and a hole-poor phase. The phase separation is frustrated by long-range Coulomb interactions but, provided the dielectric constant is sufficiently large, there remain large-amplitude low-energy fluctuations in the hole density at intermediate length scales. The extensive experimental evidence showing that this behavior giver, a reasonable picture of high temperature superconductors is surveyed. Further, it is shown that the scattering of mobile holes from the local density fluctuations may account for the anomalous normal-state properties of high temperature superconductors and also provide the mechanism of pairing.

Emery, V.J. (Brookhaven National Lab., Upton, NY (United States)); Kivelson, S.A. (California Univ., Los Angeles, CA (United States). Dept. of Physics)

1992-01-01T23:59:59.000Z

199

2. HIGH-LOv~ JUNCTION FORY_,\\'UO AN EXPERIMENTAL STUDY OF AL-ALLOYED:'p+ JUNCT;[ONS FOR SSF SOLAR CELT.S As temperature rises en..!."  

E-Print Network (OSTI)

cells. Nowadays this technology has stirred new interest in prGducing high efficiency ~lIS-SSF solar+pp+ bifacial SSF solar cells are used to experimentally analyse the interphase in a similar way a 5i layer. These conclusions are checked with ex-, perimental results of other workers. Recommendations for BSF solar cell

del Alamo, Jesús A.

200

High-temperature corrosion in advanced combustion systems  

SciTech Connect

Conceptual designs of advanced combustion systems that utilize coal as a feedstock require high temperature furnaces and heat transfer surfaces capable of operation at much elevated temperatures than those prevalent in current coal-fired power plants. The combination of elevated temperatures and hostile combustion environments necessitate development/application of advanced ceramic materials in these designs. The present paper characterizes the chemistry of coal-fired combustion environments over a wide temperature range of interest in these systems and discusses preliminary experimental results on several materials with potential for application in these systems. An experimental program has been initiated to evaluate materials for advanced combustion systems. Several candidate materials have been identified for evaluation. The candidates included advanced metallic alloys, monolithic ceramics, ceramic particulate/ceramic matrix composites, ceramic fiber/ceramic matrix composites, and ceramic whisker/ceramic matrix composites. The materials examined so far included nickel-base superalloys, alumina, stabilized zirconia, different types of silicon carbide, and silicon nitride. Coupon specimens of several of the materials have been tested in an air environment at 1000, 1200, and 1400{degree}C for 168 h. In addition, specimens were exposed to sodium-sulfate-containing salts at temperatures of 1000 and 1200{degree}C for 168 h. Extensive microstructural analyses were conducted on the exposed specimens to evaluate the corrosion performance of the materials for service in air and fireside environments of advanced coal-fired boilers. Additional tests are underway with several of the materials to evaluate their corrosion performance as a function of salt chemistry, alkali vapor concentration, gas chemistry, exposure temperature, and exposure time.

Natesan, K.; Yanez-Herrero, M.; Fornasieri, C.

1993-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

High temperature storage loop : final design report.  

SciTech Connect

A three year plan for thermal energy storage (TES) research was created at Sandia National Laboratories in the spring of 2012. This plan included a strategic goal of providing test capability for Sandia and for the nation in which to evaluate high temperature storage (>650%C2%B0C) technology. The plan was to scope, design, and build a flow loop that would be compatible with a multitude of high temperature heat transfer/storage fluids. The High Temperature Storage Loop (HTSL) would be reconfigurable so that it was useful for not only storage testing, but also for high temperature receiver testing and high efficiency power cycle testing as well. In that way, HTSL was part of a much larger strategy for Sandia to provide a research and testing platform that would be integral for the evaluation of individual technologies funded under the SunShot program. DOE's SunShot program seeks to reduce the price of solar technologies to 6/kWhr to be cost competitive with carbon-based fuels. The HTSL project sought to provide evaluation capability for these SunShot supported technologies. This report includes the scoping, design, and budgetary costing aspects of this effort

Gill, David Dennis; Kolb, William J.

2013-07-01T23:59:59.000Z

202

High-Temperature-High-Volume Lifting | Open Energy Information  

Open Energy Info (EERE)

source source History View New Pages Recent Changes All Special Pages Semantic Search/Querying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit History Facebook icon Twitter icon » High-Temperature-High-Volume Lifting Jump to: navigation, search Geothermal ARRA Funded Projects for High-Temperature-High-Volume Lifting Loading map... {"format":"googlemaps3","type":"ROADMAP","types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"limit":200,"offset":0,"link":"all","sort":[""],"order":[],"headers":"show","mainlabel":"","intro":"","outro":"","searchlabel":"\u2026

203

High Shear Deformation to Produce High Strength and Energy Absorption in Mg Alloys  

SciTech Connect

Magnesium alloys have the potential to reduce the mass of transportation systems however to fully realize the benefits it must be usable in more applications including those that require higher strength and ductility. It has been known that fine grain size in Mg alloys leads to high strength and ductility. However, the challenge is how to achieve this optimal microstructure in a cost effective way. This work has shown that by using optimized high shear deformation and second phase particles of Mg2Si and MgxZnZry the energy absorption of the extrusions can exceed that of AA6061. The extrusion process under development described in this presentation appears to be scalable and cost effective. In addition to process development a novel modeling approach to understand the roles of strain and state-of-strain on particle fracture and grain size control has been developed

Joshi, Vineet V.; Jana, Saumyadeep; Li, Dongsheng; Garmestani, Hamid; Nyberg, Eric A.; Lavender, Curt A.

2014-02-01T23:59:59.000Z

204

Improved Martensitic Steel for High Temperature Applications  

NLE Websites -- All DOE Office Websites (Extended Search)

Improved Martensitic Steel Improved Martensitic Steel for High Temperature Applications Opportunity Research is active on the patented technology, titled "Heat-Treated 9 Cr-1 Mo Steel for High Temperature Application." This technology is available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory (NETL). Overview The operating efficiency of coal-fired power plants is directly related to combustion system temperature and pressure. Incorporation of ultra- supercritical (USC) steam conditions into new or existing power plants can achieve increased efficiency and reduce coal consumption, while reducing carbon dioxide emissions as well as other pollutants. Traditionally used materials do not possess the optimal characteristics for operation

205

Magnetism in Iron at High Temperatures  

Science Journals Connector (OSTI)

Magnetism in iron at high temperature is investigated by calculating the total electronic band-structure energy for four types of spin arrangements. A slow smooth spatial variation of spin direction costs relatively little energy and the atomic moment m is reduced only ? 10%. More rapid variations have considerably higher energy, which may explain the high degree of short-range order and small ?m observed at T?TC. Other aspects are also discussed.

M. V. You; V. Heine; A. J. Holden; P. J. Lin-Chung

1980-05-12T23:59:59.000Z

206

High Temperature, High Pressure Devices for Zonal Isolation in Geothermal  

Open Energy Info (EERE)

Temperature, High Pressure Devices for Zonal Isolation in Geothermal Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells Geothermal Project Jump to: navigation, search Last modified on July 22, 2011. Project Title High Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells Project Type / Topic 1 Recovery Act: Enhanced Geothermal Systems Component Research and Development/Analysis Project Type / Topic 2 Zonal Isolation Project Description For Enhanced Geothermal Systems (EGS), high-temperature high-pressure zonal isolation tools capable of withstanding the downhole environment are needed. In these wells the packers must withstand differential pressures of 5,000 psi at more than 300°C, as well as pressures up to 20,000 psi at 200°C to 250°C. Furthermore, when deployed these packers and zonal isolation tools must form a reliable seal that eliminates fluid loss and mitigates short circuiting of flow from injectors to producers. At this time, general purpose open-hole packers do not exist for use in geothermal environments, with the primary technical limitation being the poor stability of existing elastomeric seals at high temperatures.

207

High-Temperature-High-Volume Lifting For Enhanced Geothermal Systems  

Open Energy Info (EERE)

Temperature-High-Volume Lifting For Enhanced Geothermal Systems Temperature-High-Volume Lifting For Enhanced Geothermal Systems Geothermal Project Jump to: navigation, search Last modified on July 22, 2011. Project Title High-Temperature-High-Volume Lifting For Enhanced Geothermal Systems Project Type / Topic 1 Recovery Act: Enhanced Geothermal Systems Component Research and Development/Analysis Project Type / Topic 2 High-Temperature-High-Volume Lifting Project Description The proposed scope of work is divided into three Phases. Overall system requirements will be established in Phase 1, along with an evaluation of existing lifting system capability, identification of technology limitations, and a conceptual design of an overall lifting system. In developing the system components in Phase 2, component-level tests will be conducted using GE facilities. Areas of development will include high-temperature drive system materials, journal and thrust bearings, and corrosion and erosion-resistant lifting pump components. Finally, in Phase 3, the overall lab-scale lifting system will be demonstrated in a flow loop that will be constructed at GE Global Research.

208

Potential applications of high temperature helium  

SciTech Connect

This paper discusses the DOE MHTGR-SC program`s recent activity to improve the economics of the MHTGR without sacrificing safety performance and two potential applications of high temperature helium, the MHTGR gas turbine plant and a process heat application for methanol production from coal.

Schleicher, R.W. Jr.; Kennedy, A.J.

1992-09-01T23:59:59.000Z

209

Potential applications of high temperature helium  

SciTech Connect

This paper discusses the DOE MHTGR-SC program's recent activity to improve the economics of the MHTGR without sacrificing safety performance and two potential applications of high temperature helium, the MHTGR gas turbine plant and a process heat application for methanol production from coal.

Schleicher, R.W. Jr.; Kennedy, A.J.

1992-09-01T23:59:59.000Z

210

The High-Temperature Oxidation of Propane  

Science Journals Connector (OSTI)

...research-article The High-Temperature Oxidation of Propane J. W. Falconer J. H. Knox Above 400 degrees C propane is oxidized by a two-stage degenerately...of propylene becomes important. While propane still in the main reacts to form propylene...

1959-01-01T23:59:59.000Z

211

Flux noise in high-temperature superconductors  

Science Journals Connector (OSTI)

Spontaneously created vortex-antivortex pairs are the predominant source of flux noise in high-temperature superconductors. In principle, flux noise measurements allow to check theoretical predictions for both the distribution of vortex-pair sizes and for the vortex diffusivity. In this paper the flux-noise power spectrum is calculated for the highly anisotropic high-temperature superconductor Bi2Sr2CaCu2O8+?, both for bulk crystals and for ultrathin films. The spectrum is basically given by the Fourier transform of the temporal magnetic-field correlation function. We start from a Berezinskii-Kosterlitz-Thouless-type theory and incorporate vortex diffusion, intrapair vortex interaction, and annihilation of pairs by means of a Fokker-Planck equation to determine the noise spectrum below and above the superconducting transition temperature. We find white noise at low frequencies ? and a spectrum proportional to 1/?3/2 at high frequencies. The crossover frequency between these regimes strongly depends on temperature. The results are compared with earlier results of computer simulations.

Carsten Timm

1997-02-01T23:59:59.000Z

212

High temperature intermetallic binders for HVOF carbides  

SciTech Connect

Gas turbines technology has a long history of employing the desirable high temperature physical attributes of ceramic-metallic (cermet) materials. The most commonly used coatings incorporate combinations of WC-Co and Cr{sub 3}C{sub 2}-NiCr, which have also been successfully utilized in other non-turbine coating applications. Increased turbine operating temperatures and other high temperature service conditions have made apparent the attractive notion of increasing the temperature capability and corrosion resistance of these coatings. In this study the intermetallic binder NiAl has been used to replace the cobalt and NiCr constituents of conventional WC and Cr{sub 3}C{sub 2} cermet powders. The composite carbide thermal spray powders were fabricated for use in the HVOF coating process. The structure of HVOF deposited NiAl-carbide coatings are compared directly to the more familiar WC-Co and Cr{sub 3}C{sub 2}-NiCr coatings using X-ray diffraction, back-scattered electron imaging (BEI) and electron dispersive spectroscopy (EDS). Hardness variations with temperature are reported and compared between the NiAl and Co/NiCr binders.

Shaw, K.G. [Xform, Inc., Cohoes, NY (United States); Gruninger, M.F.; Jarosinski, W.J. [Praxair Specialty Powders, Indianapolis, IN (United States)

1994-12-31T23:59:59.000Z

213

Baseline Concept Description of a Small Modular High Temperature Reactor  

SciTech Connect

The objective of this report is to provide a description of generic small modular high temperature reactors (herein denoted as an smHTR), summarize their distinguishing attributes, and lay out the research and development (R&D) required for commercialization. The generic concepts rely heavily on the modular high temperature gas-cooled reactor designs developed in the 1980s which were never built but for which pre-licensing or certification activities were conducted. The concept matured more recently under the Next Generation Nuclear Plant (NGNP) project, specifically in the areas of fuel and material qualification, methods development, and licensing. As all vendor-specific designs proposed under NGNP were all both small or medium-sized and modular by International Atomic Energy Agency (IAEA) and Department of Energy (DOE) standards, the technical attributes, challenges, and R&D needs identified, addressed, and documented under NGNP are valid and appropriate in the context of Small Modular Reactor (SMR) applications. Although the term High Temperature Reactor (HTR) is commonly used to denote graphite-moderated, thermal spectrum reactors with coolant temperatures in excess of 650oC at the core outlet, in this report the historical term High Temperature Gas-Cooled Reactor (HTGR) will be used to distinguish the gas-cooled technology described herein from its liquid salt-cooled cousin. Moreover, in this report it is to be understood that the outlet temperature of the helium in an HTGR has an upper limit of 950 degrees C which corresponds to the temperature to which certain alloys are currently being qualified under DOEs ARC program. Although similar to the HTGR in just about every respect, the Very High Temperature Reactor (VHTR) may have an outlet temperature in excess of 950 degrees C and is therefore farther from commercialization because of the challenges posed to materials exposed to these temperatures. The VHTR is the focus of R&D under the Generation IV program and its specific R&D needs will be included in this report when appropriate for comparison. The distinguishing features of the HTGR are the refractory (TRISO) coated particle fuel, the low-power density, graphite-moderated core, and the high outlet temperature of the inert helium coolant. The low power density and fuel form effectively eliminate the possibility of core melt, even upon a complete loss of coolant pressure and flow. The graphite, which constitutes the bulk of the core volume and mass, provides a large thermal buffer that absorbs fission heat such that thermal transients occur over a timespan of hours or even days. As chemically-inert helium is already a gas, there is no coolant temperature or void feedback on the neutronics and no phase change or corrosion product that could degrade heat transfer. Furthermore, the particle coatings and interstitial graphite retain fission products such that the source terms at the plant boundary remain well below actionable levels under all anticipated nominal and off-normal operating conditions. These attributes enable the reactor to supply process heat to a collocated industrial plant with negligible risk of contamination and minimal dynamic coupling of the facilities (Figure 1). The exceptional retentive properties of coated particle fuel in a graphite matrix were first demonstrated in the DRAGON reactor, a European research facility that began operation in 1964.

Hans Gougar

2014-05-01T23:59:59.000Z

214

Ni{sub 3}Al aluminide alloys  

SciTech Connect

This paper provides a brief review of the recent progress in research and development of Ni{sub 3}Al and its alloys. Emphasis has been placed on understanding low ductility and brittle fracture of Ni{sub 3}Al alloys at ambient and elevated temperatures. Recent studies have resulted in identifying both intrinsic and extrinsic factors governing the fracture behavior of Ni{sub 3}Al alloys. Parallel efforts on alloy design using physical metallurgy principles have led to properties for structural use. Industrial interest in these alloys is high, and examples of industrial involvement in processing and utilization of these alloys are briefly mentioned.

Liu, C.T.

1993-10-01T23:59:59.000Z

215

Application of high temperature superconductors for fusion  

Science Journals Connector (OSTI)

The use of High Temperature Superconductor (HTS) materials in future fusion machines can increase the efficiency drastically. For ITER, W7-X and JT-60SA the economic benefit of HTS current leads was recognized after a 70kA HTS current lead demonstrator was designed, fabricated and successfully tested by Karlsruhe Institute of Technology (KIT, which is a merge of former Forschungszentrum Karlsruhe and University of Karlsruhe). For ITER, the Chinese Domestic Agency will provide the current leads as a part of the superconducting feeder system. KIT is in charge of design, construction and test of HTS current leads for W7-X and JT-60SA. For W7-X 14 current leads with a maximum current of 18.2kA are required that are oriented with the room temperature end at the bottom. JT60-SA will need 26 current leads (20 leads @ 20kA and 6 leads @ 25.7kA) which are mounted in vertical, normal position. These current leads are based on BiSCCO HTS superconductors, demonstrating that HTS material is now state of the art for highly efficient current leads. With respect to future fusion reactors, it would be very promising to use HTS material not only in current leads but also in coils. This would allow a large increase of efficiency if the coils could be operated at temperatures ?65K. With such a high temperature it would be possible to omit the radiation shield of the coils, resulting in a less complex cryostat and a size reduction of the machine. In addition less refrigeration power is needed saving investment and operating costs. However, to come to an HTS fusion coil it is necessary to develop low ac loss HTS cables for currents well above 20kA at high fields well above 10T. The high field rules BiSCCO superconductors out at temperatures above 50K, but RE-123 superconductors are promising. The development of a high current, high field RE-123 HTS fusion cable will not be targeted outside fusion community and has to be in the frame of a long term development programme for DEMO. KIT has already demonstrated a scalable concept using RE-123 HTS tapes that are assembled to Roebel type conductors. This concept can be expanded to form Rutherford cables as starting point for a development of a high current fusion cable. The status and prospect of using HTS conductors for fusion is discussed.

W.H. Fietz; R. Heller; S.I. Schlachter; W. Goldacker

2011-01-01T23:59:59.000Z

216

Vehicle Technologies Office: ORNL's High Temperature Materials Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

ORNL's High Temperature ORNL's High Temperature Materials Laboratory Assists NASCAR Teams to someone by E-mail Share Vehicle Technologies Office: ORNL's High Temperature Materials Laboratory Assists NASCAR Teams on Facebook Tweet about Vehicle Technologies Office: ORNL's High Temperature Materials Laboratory Assists NASCAR Teams on Twitter Bookmark Vehicle Technologies Office: ORNL's High Temperature Materials Laboratory Assists NASCAR Teams on Google Bookmark Vehicle Technologies Office: ORNL's High Temperature Materials Laboratory Assists NASCAR Teams on Delicious Rank Vehicle Technologies Office: ORNL's High Temperature Materials Laboratory Assists NASCAR Teams on Digg Find More places to share Vehicle Technologies Office: ORNL's High Temperature Materials Laboratory Assists NASCAR Teams on AddThis.com...

217

Syngas Enhanced High Efficiency Low Temperature Combustion for...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Enhanced High Efficiency Low Temperature Combustion for Clean Diesel Engines Syngas Enhanced High Efficiency Low Temperature Combustion for Clean Diesel Engines A significant...

218

Vehicle Technologies Office Merit Review 2014: High-Temperature...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

High-Temperature Air-Cooled Power Electronics Thermal Design Vehicle Technologies Office Merit Review 2014: High-Temperature Air-Cooled Power Electronics Thermal Design...

219

High Temperature Polymer Membrane Development at Argonne National...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Polymer Membrane Development at Argonne National Laboratory High Temperature Polymer Membrane Development at Argonne National Laboratory Summary of ANL's high temperature polymer...

220

High Temperature Fuel Cells in the European Union  

Energy.gov (U.S. Department of Energy (DOE))

Presentation on High Temperature Fuel Cells in the European Union to the High Temperature Membrane Working Group, May 25, 2004 in Philadelphia, PA.

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Low and high Temperature Dual Thermoelectric Generation Waste...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Low and high Temperature Dual Thermoelectric Generation Waste Heat Recovery System for Light-Duty Vehicles Low and high Temperature Dual Thermoelectric Generation Waste Heat...

222

High temperature membranes for DMFC (and PEFC) applications  

Energy.gov (U.S. Department of Energy (DOE))

Presentation on High temperature membranes for DMFCs (and PEFCs) to the High Temperature Membrane Working Group, May 25, 2004 in Philadelphia, PA.

223

Development of Advanced High Temperature Fuel Cell Membranes  

Energy.gov (U.S. Department of Energy (DOE))

Presentation on Development of Advanced High Temperature Fuel Cell Membranes to the High Temperature Membrane Working Group Meeting held in Arlington, Virginia, May 26,2005.

224

Development of a 100-Watt High Temperature Thermoelectric Generator...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Generator Development of a 100-Watt High Temperature Thermoelectric Generator Test results for low and high temperature thermoelectric generators (TEG) those for a...

225

A Discussion of Conductivity Testing in High Temperature Membranes...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

A Discussion of Conductivity Testing in High Temperature Membranes (lessons learned in assessing transport) A Discussion of Conductivity Testing in High Temperature Membranes...

226

High Temperature Polymer Membrane Development at Argonne National Laboratory  

Energy.gov (U.S. Department of Energy (DOE))

Summary of ANLs high temperature polymer membrane work presented to the High Temperature Membrane Working Group Meeting, Orlando FL, October 17, 2003

227

Nanostructured High-Temperature Bulk Thermoelectric Energy Conversion...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Nanostructured High-Temperature Bulk Thermoelectric Energy Conversion for Efficient Automotive Waste Heat Recovery Nanostructured High-Temperature Bulk Thermoelectric Energy...

228

Microchannel High-Temperature Recuperator for Fuel Cell Systems...  

Office of Environmental Management (EM)

Microchannel High-Temperature Recuperator for Fuel Cell Systems - Fact Sheet, 2014 Microchannel High-Temperature Recuperator for Fuel Cell Systems - Fact Sheet, 2014 FuelCell...

229

Enhanced High and Low Temperature Performance of NOx Reduction...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Enhanced High and Low Temperature Performance of NOx Reduction Materials Enhanced High and Low Temperature Performance of NOx Reduction Materials 2013 DOE Hydrogen and Fuel Cells...

230

High Resolution and Low-Temperature Photoelectron Spectroscopy...  

NLE Websites -- All DOE Office Websites (Extended Search)

High Resolution and Low-Temperature Photoelectron Spectroscopy of an Oxygen-Linked Fullerene Dimer Dianion: C120O2-. High Resolution and Low-Temperature Photoelectron Spectroscopy...

231

Polyelectrolyte Materials for High Temperature Fuel Cells | Department...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Polyelectrolyte Materials for High Temperature Fuel Cells Polyelectrolyte Materials for High Temperature Fuel Cells This presentation, which focuses on polyelectrolyte materials...

232

Compliant high temperature seals for dissimilar materials  

DOE Patents (OSTI)

A high temperature, gas-tight seal is formed by utilizing one or more compliant metallic toroidal ring sealing elements, where the applied pressure serves to activate the seal, thus improving the quality of the seal. The compliant nature of the sealing element compensates for differences in thermal expansion between the materials to be sealed, and is particularly useful in sealing a metallic member and a ceramic tube art elevated temperatures. The performance of the seal may be improved by coating the sealing element with a soft or flowable coating such as silver or gold and/or by backing the sealing element with a bed of fine powder. The material of the sealing element is chosen such that the element responds to stress elastically, even at elevated temperatures, permitting the seal to operate through multiple thermal cycles.

Rynders, Steven Walton (Fogelsville, PA); Minford, Eric (Laurys Station, PA); Tressler, Richard Ernest (Boalsburg, PA); Taylor, Dale M. (Salt Lake City, UT)

2001-01-01T23:59:59.000Z

233

Recombination dynamics and carrier lifetimes in highly mismatched ZnTeO alloys  

SciTech Connect

This study investigates the recombination dynamics in highly mismatched ZnTeO alloys using time-resolved photoluminescence (PL) spectroscopy. The large PL energy redshift with increasing O content and the disappearance of the ZnTe emission verify the O-induced conduction band anticrossing effect. The incorporation of O generates electron localization below the E{sub ?} conduction subband tail, which provide additional optical transitions and cause complex recombination mechanisms. Photoexcited free electrons in both the E{sub +} and the E{sub ?} conduction subbands favor rapid relaxation to low energy states. Additionally, temperature-independent long carrier lifetimes (>130.0?ns) that are induced by localized electrons increase with O concentration.

Lin, Yan-Cheng, E-mail: bryanlin@mail.nctu.edu.tw, E-mail: wuchingchou@mail.nctu.edu.tw; Tasi, Ming-Jui; Chou, Wu-Ching, E-mail: bryanlin@mail.nctu.edu.tw, E-mail: wuchingchou@mail.nctu.edu.tw; Chang, Wen-Hao; Chen, Wei-Kuo [Department of Electrophysics, National Chiao Tung University, Hsinchu 30010, Taiwan (China)] [Department of Electrophysics, National Chiao Tung University, Hsinchu 30010, Taiwan (China); Tanaka, Tooru [Department of Electrical and Electronic Engineering, Saga University, Saga 840-8502 (Japan) [Department of Electrical and Electronic Engineering, Saga University, Saga 840-8502 (Japan); PRESTO, Japan Science and Technology Agency (JST), Kawaguchi, Saitama 332-0012 (Japan); Guo, Qixin [Synchrotron Light Application Center, Saga University, 1 Honjo, Saga 840-8502 (Japan)] [Synchrotron Light Application Center, Saga University, 1 Honjo, Saga 840-8502 (Japan); Nishio, Mitsuhiro [Department of Electrical and Electronic Engineering, Saga University, Saga 840-8502 (Japan)] [Department of Electrical and Electronic Engineering, Saga University, Saga 840-8502 (Japan)

2013-12-23T23:59:59.000Z

234

Vehicle Technologies Office Merit Review 2014: High Energy Novel Cathode / Alloy Automotive Cell  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by 3M at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high energy novel cathode / alloy...

235

Temperature dependence of dynamic Young's modulus and internal friction in three plasma sprayed NiCrAlY coating alloys  

E-Print Network (OSTI)

TEMPERATURE DEPENDENCE OF DYNAM'IIC YOUNG'S MODULUS AND INTERNAL FRICTION IN THREE PLASMA SPRAYED NiCrAlY COATING -ALLOYS A Thesis LLOYD STEVEN COOK Submitted to the 08ice of Graduate Studies of Texas AE M University in part. al full...'illment of the requirement for the degree of MASTER OF SCIENCE August 1989 Itiajor Subject: l'dechanical Engineering TEMPERATURE DEPENDENCE OF DYNAMIC YOUNG'S MODULUS AND INTERNAL FRICTION IN THREE PLASMA SPRAYED NiCrAIY COATING ALLOYS A Thesis by LLOYD STEVEN COOK...

Cook, Lloyd Steven

1989-01-01T23:59:59.000Z

236

High Permeability Ternary Palladium Alloy Membranes with Improved Sulfur and Halide Tolerance  

NLE Websites -- All DOE Office Websites (Extended Search)

9 9 HigH Permeability ternary Palladium alloy membranes witH imProved sulfur and Halide tolerance Description A critical step in the transition to the hydrogen economy is the separation of hydrogen from coal gasification gases (syngas) or methane. This is typically accomplished through membrane separation. Past research has shown that palladium (Pd) alloys possess great potential as robust and economical membranes. However, the search for the optimal binary or ternary alloys is an involved and costly process due to the immense number of alloy variations that could be prepared and tested. Recent modeling work at Georgia Institute of Technology using density functional theory (DFT) identified several promising ternary alloy compositions with improved

237

1.26 - High Temperature Corrosion of Ceramics and Refractory Materials  

Science Journals Connector (OSTI)

This chapter on ceramics and refractories summarizes firstly the differences between metal and alloy corrosion, before describing briefly the main mechanisms and kinetic laws. Divided into sections on oxides (alumina, zirconia, and cordierite), carbides (boron and silicon carbide), nitrides (silicon nitride, boron nitride, carbonitrides), titanium compounds (TiC, TiN), and ultrahigh temperature ceramics, the corrosion behavior of ceramics for use at high temperature is reviewed and referenced. Because of their high variability, the section on refractories focuses on the physics, laws, and mechanisms observed in the application with the largest volume, i.e., the steel- and iron-making industries.

K.G. Nickel; P. Quirmbach; J. Ptschke

2010-01-01T23:59:59.000Z

238

Brazing Refractory Metals Used In High-Temperature Nuclear Instrumentation  

SciTech Connect

As part of the U. S. Department of Energy (DOE) sponsored Next Generation Nuclear Project (NGNP) currently ongoing at Idaho National Laboratory (INL), the irradiation performance of candidate high-temperature gas reactor fuels and materials is being evaluated at INLs Advanced Test Reactor (ATR). The design of the first Advanced Gas Reactor (AGR 1) experiment, currently being irradiated in the ATR, required development of special techniques for brazing niobium and molybdenum. Brazing is one technique used to join refractory metals to each other and to stainless steel alloys. Although brazing processes are well established, it is difficult to braze niobium, molybdenum, and most other refractory metals because they quickly develop adherent oxides when exposed to room-temperature air. Specialized techniques and methods were developed by INL to overcome these obstacles. This paper describes the techniques developed for removing these oxides, as well as the ASME Section IX-qualified braze procedures that were developed as part of the AGR-1 project. All brazes were made using an induction coil with an inert or reducing atmosphere at low pressure. Other parameters, such as filler metals, fluxes used, and general setup procedures, are also discussed.

A. J. Palmer; C. J. Woolstenhulme

2009-06-01T23:59:59.000Z

239

Establishment of Harrop, High-Temperature Viscometer  

SciTech Connect

This report explains how the Harrop, High-Temperature Viscometer was installed, calibrated, and operated. This report includes assembly and alignment of the furnace, viscometer, and spindle, and explains the operation of the Brookfield Viscometer, the Harrop furnace, and the UDC furnace controller. Calibration data and the development of the spindle constant from NIST standard reference glasses is presented. A simple operational procedure is included.

Schumacher, R.F.

1999-11-05T23:59:59.000Z

240

Charged Vortices in High Temperature Superconductors  

Science Journals Connector (OSTI)

It is argued that in the mixed state of a type II superconductor, because of the difference of the chemical potential in a superconducting versus normal state, the vortex cores may become charged. The extra electron density is estimated. The extra charge contributes to the dynamics of the vortices; in particular, it can explain in certain cases the change of the sign of the Hall coefficient below Tc frequently observed in the high temperature superconductors.

D. I. Khomskii and A. Freimuth

1995-08-14T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Polyelectrolyte Materials for High Temperature Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Polyelectrolyte Materials for High Polyelectrolyte Materials for High 3M (3M) Temperature Fuel Cells John B. Kerr Lawrence Berkeley National Laboratory (LBNL) Collaborators: Los Alamos National Laboratory (LANL). February 13, 2007 This presentation does not contain any proprietary or confidential information Team Members: Nitash Blasara, Rachel Segalman, Adam Weber (LBNL). Bryan Pivovar, James Boncella (LANL) Steve Hamrock Objectives * Investigate the use of solid polyelectrolyte proton conductors that do not require the presence of water. * Prepare solid electrolytes where only the proton moves. - Measure conductivity, mechanical/thermal properties of Nafion® and other polyelectrolytes doped with imidazoles. Compare with water doped materials. - Covalently attach imidazoles to side chains of ionomers with

242

3 - High temperature superconductor (HTS) cables  

Science Journals Connector (OSTI)

Abstract: Many superconductor applications such as rotating machinery, transformers and magnets with low inductance require high current cables with low AC losses. This chapter gives an overview on cabling techniques for the high temperature superconductors (HTS) BSCCO (2212), BSCCO (2223) and (RE)BCO. A short review is given of the basic properties of HTS wires and tapes and the basic requirements of HTS cables for different applications. Cabling concepts for the different HTS materials are presented, and current performance and AC loss behaviour are discussed. After a short description of remaining challenges and future trends, cabling techniques are summarized.

S.I. Schlachter; W. Goldacker

2012-01-01T23:59:59.000Z

243

Enhanced high-field current carrying capacities and pinning behavior of NbTi-based superconducting alloys  

SciTech Connect

High-field critical current densities J/sub c/ and pinning behavior are discussed for Nb-63a/oTi, Nb-61.7a/oTi-3a/oHf, and Nb-64.7a/oTi-7.2a/oTa superconducting alloys. J/sub c/ properties for 8--12 T in these alloy superconductors under superfluid helium environments can be even superior to those in Nb/sub 3/Sn at 4.2 K, when they are heavily cold-worked after final heat treatments. A temperature scaling law of the flux pinning force F/sub p/ is found to hold for these alloys in the form of F/sub P/ = K (B/sub c/2(T))/sup n/b/sup p/(1-b)/sup q/, where B/sub c/2 is the upper critical field and bequivalentB/B/sub c/2. The peak reduced field, b/sub m/, in the F/sub p/-b curve depends upon how the alloys have been processed. The origins of n, p, and q are discussed in terms of the processing condition.

Wada, H.; Itoh, K.; Tachikawa, K.; Yamada, Y.; Murase, S.

1985-05-01T23:59:59.000Z

244

High Operating Temperature Liquid Metal Heat Transfer Fluids  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquid Metal Liquid Metal Heat Transfer Fluids UCLA, UCB, Yale DE-EE0005941 | April 15, 2013 | Ju 1.1 Thermochemistry modeling * Continue CALPHAD based calculations to search for optimal ternary alloy compositions. * Initiate development of liquid density models. 1.2 Combinatorial synthesis and characterization * Pipe-Liquid interaction of compositional library * More alloys, alloy additions and effect on liquidus temperatures * Iteratively optimize the compositions. 1.3 Corrosion characterization and mitigation * Tune static corrosion testing systems for testing over an extended period of time. * Perform analysis of the micro mechanical testing on the oxide layers. 1.4 Heat transfer characterization and modeling * Complete the construction of the flow loop and perform experiments to measure

245

NOVEL REFRACTORY MATERIALS FOR HIGH ALKALI, HIGH TEMPERATURE ENVIRONMENTS  

SciTech Connect

Refractory materials can be limited in their application by many factors including chemical reactions between the service environment and the refractory material, mechanical degradation of the refractory material by the service environment, temperature limitations on the use of a particular refractory material, and the inability to install or repair the refractory material in a cost effective manner or while the vessel was in service. The objective of this project was to address the need for new innovative refractory compositions by developing a family of novel MgO-Al 2O3 spinel or other similar magnesia/alumina containing unshaped refractory composition (castables, gunnables, shotcretes, etc) utilizing new aggregate materials, bond systems, protective coatings, and phase formation techniques (in-situ phase formation, altered conversion temperatures, accelerated reactions, etc). This family of refractory compositions would then be tailored for use in high-temperature, high-alkaline industrial environments like those found in the aluminum, chemical, forest products, glass, and steel industries.

Hemrick, James Gordon [ORNL

2011-09-01T23:59:59.000Z

246

SunShot Initiative: High Operating Temperature Liquid Metal Heat Transfer  

NLE Websites -- All DOE Office Websites (Extended Search)

High Operating Temperature Liquid Metal Heat Transfer Fluids High Operating Temperature Liquid Metal Heat Transfer Fluids UCLA logo University of California Berkeley logo Yale logo Four graphics in a grid that represent the sputtering technique being used in this project. Combinatorial screening and high throughput characterization of materials will be used to identify, develop, and demonstrate metal alloys that meet the MURI HOT Fluids targets suitable for CSP applications. The University of California, Los Angeles, the University of California, Berkeley, and Yale University The University of California, Los Angeles (UCLA), along with partners at the University of California, Berkeley, and Yale University, under the 2012 Multidisciplinary University Research Initiative (MURI): High Operating Temperature (HOT) Fluids funding opportunity, is investigating the use of metal alloys as a heat transfer fluid (HTF) in concentrating solar power (CSP) systems operating at temperatures in excess of 800°C. By allowing higher temperature operation, CSP systems can achieve greater efficiencies and thereby reduce the overall cost of electricity production.

247

Advanced nickel base alloys for high strength, corrosion applications  

DOE Patents (OSTI)

Improved nickel-base alloys of enhanced strength and corrosion resistance, produced by atomization of an alloy melt under an inert gas atmosphere and of composition 0--20Fe, 10--30Cr, 2--12Mo, 6 max. Nb, 0.05--3 V, 0.08 max. Mn, 0.5 max. Si, less than 0.01 each of Al and Ti, less than 0.05 each of P and S, 0.01--0.08C, less than 0.2N, 0.1 max. 0, bal. Ni. 3 figs.

Flinn, J.E.

1998-11-03T23:59:59.000Z

248

Diamond switches for high temperature electronics  

SciTech Connect

Diamond switches are well suited for use in high temperature electronics. Laboratory feasibility of diamond switching at 1 kV and 18 A was demonstrated. DC blocking voltages up to 1 kV were demonstrated. A 50 {Omega} load line was switched using a diamond switch, with switch on-state resistivity {approx}7 {Omega}-cm. An electron beam, {approx}150 keV energy, {approx}2 {mu}s full width at half maximum was used to control the 5 mm x 5 mm x 100 {mu}m thick diamond switch. The conduction current temporal history mimics that of the electron beam. These data were taken at room temperature.

Prasad, R.R.; Rondeau, G.; Qi, Niansheng [Alameda Applied Sciences Corp., San Leandro, CA (United States)] [and others

1996-04-25T23:59:59.000Z

249

Fermi liquid theory for high temperature superconductors  

SciTech Connect

In this article the Fermi liquid theory of metals is discussed starting from Luttinger's theorem. The content of Luttinger's Theorem and its implications for microscopic theories of high temperature superconductors are discussed. A simple quasi-2d Fermi liquid theory is introduced and some of its properties are calculated. It is argued that a number of experiments on YBa/sub 2/Cu/sub 3/O/sub 6+x/, x > 0.5, strongly suggest the existence of a Fermi surface and thereby a Fermi liquid normal state. 25 refs., 1 fig.

Bedell, K.S.

1988-01-01T23:59:59.000Z

250

5 - High temperature superconductor (HTS) magnets  

Science Journals Connector (OSTI)

Abstract: At the time of writing, high temperature superconducting magnets have not fulfilled their early promise, mainly because of the difficulties in getting these reactive and brittle ceramics into wire form and, consequently, their expense. However, for some niche applications, HTS magnets have been developed. In this chapter, the author outlines his experience of building four such systems after introductory discussions about superconducting magnets in general and design considerations. The recent commercial availability of so-called second-generation (2G) coated conductors opens up a more promising scenario, provided the cost can come down. This scenario is discussed and some conclusions are drawn.

H. Jones

2012-01-01T23:59:59.000Z

251

Boson linewidth in high-temperature superconductors  

Science Journals Connector (OSTI)

We have considered boson exchange models of high-temperature superconductors which use Eliashberg theory and in which the bare bosons have sharp spectral features. In particular, we have calculated the boson linewidth due to the interaction with the charge carriers. We find for a recent model of Arnold, Mueller, and Swihart that the width of the 10-meV peak in their ?2F is consistent with a broadened boson peak. However, for a weak-coupling model with the boson peak in the eV range, the interaction causes a broadening in the boson peak that is comparable to or larger than the energy of the peak.

James C. Swihart; William H. Butler; Fred M. Mueller; Gerald B. Arnold

1992-09-01T23:59:59.000Z

252

Applications of bulk high-temperature superconductors  

SciTech Connect

The development of high-temperature superconductors (HTSs) can be broadly generalized into thin-film electronics, wire applications, and bulk applications. We consider bulk HTSs to include sintered or crystallized forms that do not take the geometry of filaments or tapes, and we discuss major applications for these materials. For the most part applications may be realized with the HTSs cooled to 77 K, and the properties of the bulk HTSs are often already sufficient for commercial use. A non-exhaustive list of applications for bulk HTSs includes trapped field magnets, hysteresis motors, magnetic shielding, current leads, and magnetic bearings. These applications are briefly discussed in this paper.

Hull, J.R.

1995-06-01T23:59:59.000Z

253

High Temperature Materials Laboratory third annual report  

SciTech Connect

The High Temperature Materials Laboratory has completed its third year of operation as a designated DOE User Facility at the Oak Ridge National Laboratory. Growth of the user program is evidenced by the number of outside institutions who have executed user agreements since the facility began operation in 1987. A total of 88 nonproprietary agreements (40 university and 48 industry) and 20 proprietary agreements (1 university, 19 industry) are now in effect. Sixty-eight nonproprietary research proposals (39 from university, 28 from industry, and 1 other government facility) and 8 proprietary proposals were considered during this reporting period. Research projects active in FY 1990 are summarized.

Tennery, V.J.; Foust, F.M.

1990-12-01T23:59:59.000Z

254

Superconductivity Program Overview High-Temperature Superconductivity  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

SuperconducTiviTy program haS Three FocuS areaS: SuperconducTiviTy program haS Three FocuS areaS: SuperconducTiviTy applicaTionS Developing HTS-based electric power equipment such as transmission and distribution cables and fault current limiters Second-generaTion Wire developmenT Developing high-performance, low-cost, second- generation HTS wire at long lengths STraTegic reSearch Supporting fundamental research activities to better understand relationships between the microstructure of HTS materials and their ability to carry large electric currents over long lengths Superconductivity Program Overview High-Temperature Superconductivity for Electric Systems Office of Electricity Delivery and Energy Reliability www.oe.energy.gov Office of Electricity Delivery and Energy Reliability, OE-1 U.S. Department of Energy - 1000 Independence Avenue, SW - Washington, DC 20585

255

Correlated electrons in high-temperature superconductors Elbio Dagotto  

E-Print Network (OSTI)

Correlated electrons in high-temperature superconductors Elbio Dagotto Department of Physics Theoretical ideas and experimental results concerning high-temperature superconductors are reviewed. Special, National High Magnetic Field Laboratory, and MAR TECH, Florida State University, Tallahassee, Florida 32308

Wu, Zhigang

256

Phenotyping of High Temperature Susceptibility in Garden Roses (Rosa xhybrida)  

E-Print Network (OSTI)

cultivars. Adaptation to high temperature stress is viewed as high priority in breeding programs of all major crops. High temperature stress negatively affects garden rose performance and the quality of flowers produced. The work described...

Greyvenstein, Ockert Frederick

2013-12-10T23:59:59.000Z

257

High temperature lined conduits, elbows and tees  

DOE Patents (OSTI)

A high temperature lined conduit comprising, a liner, a flexible insulating refractory blanket around and in contact with the liner, a pipe member around the blanket and spaced therefrom, and castable rigid refractory material between the pipe member and the blanket. Anchors are connected to the inside diameter of the pipe and extend into the castable material. The liner includes male and female slip joint ends for permitting thermal expansion of the liner with respect to the castable material and the pipe member. Elbows and tees of the lined conduit comprise an elbow liner wrapped with insulating refractory blanket material around which is disposed a spaced elbow pipe member with castable refractory material between the blanket material and the elbow pipe member. A reinforcing band is connected to the elbow liner at an intermediate location thereon from which extend a plurality of hollow tubes or pins which extend into the castable material to anchor the lined elbow and permit thermal expansion. A method of fabricating the high temperature lined conduit, elbows and tees is also disclosed which utilizes a polyethylene layer over the refractory blanket after it has been compressed to maintain the refractory blanket in a compressed condition until the castable material is in place. Hot gases are then directed through the interior of the liner for evaporating the polyethylene and setting the castable material which permits the compressed blanket to come into close contact with the castable material.

De Feo, Angelo (Passaic, NJ); Drewniany, Edward (Bergen, NJ)

1982-01-01T23:59:59.000Z

258

High temperature electrochemical corrosion rate probes  

SciTech Connect

Corrosion occurs in the high temperature sections of energy production plants due to a number of factors: ash deposition, coal composition, thermal gradients, and low NOx conditions, among others. Electrochemical corrosion rate (ECR) probes have been shown to operate in high temperature gaseous environments that are similar to those found in fossil fuel combustors. ECR probes are rarely used in energy production plants at the present time, but if they were more fully understood, corrosion could become a process variable at the control of plant operators. Research is being conducted to understand the nature of these probes. Factors being considered are values selected for the Stern-Geary constant, the effect of internal corrosion, and the presence of conductive corrosion scales and ash deposits. The nature of ECR probes will be explored in a number of different atmospheres and with different electrolytes (ash and corrosion product). Corrosion rates measured using an electrochemical multi-technique capabilities instrument will be compared to those measured using the linear polarization resistance (LPR) technique. In future experiments, electrochemical corrosion rates will be compared to penetration corrosion rates determined using optical profilometry measurements.

Bullard, Sophie J.; Covino, Bernard S., Jr.; Holcomb, Gordon R.; Ziomek-Moroz, M.

2005-09-01T23:59:59.000Z

259

High-Temperature, Air-Cooled Traction Drive Inverter Packaging...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Temperature, Air-Cooled Traction Drive Inverter Packaging High-Temperature, Air-Cooled Traction Drive Inverter Packaging 2010 DOE Vehicle Technologies and Hydrogen Programs Annual...

260

Amorphous and nanocrystalline phase formation in highly-driven Al-based binary alloys  

SciTech Connect

Remarkable advances have been made since rapid solidification was first introduced to the field of materials science and technology. New types of materials such as amorphous alloys and nanostructure materials have been developed as a result of rapid solidification techniques. While these advances are, in many respects, ground breaking, much remains to be discerned concerning the fundamental relationships that exist between a liquid and a rapidly solidified solid. The scope of the current dissertation involves an extensive set of experimental, analytical, and computational studies designed to increase the overall understanding of morphological selection, phase competition, and structural hierarchy that occurs under far-from equilibrium conditions. High pressure gas atomization and Cu-block melt-spinning are the two different rapid solidification techniques applied in this study. The research is mainly focused on Al-Si and Al-Sm alloy systems. Silicon and samarium produce different, yet favorable, systems for exploration when alloyed with aluminum under far-from equilibrium conditions. One of the main differences comes from the positions of their respective T{sub 0} curves, which makes Al-Si a good candidate for solubility extension while the plunging T{sub 0} line in Al-Sm promotes glass formation. The rapidly solidified gas-atomized Al-Si powders within a composition range of 15 to 50 wt% Si are examined using scanning and transmission electron microscopy. The non-equilibrium partitioning and morphological selection observed by examining powders at different size classes are described via a microstructure map. The interface velocities and the amount of undercooling present in the powders are estimated from measured eutectic spacings based on Jackson-Hunt (JH) and Trivedi-Magnin-Kurz (TMK) models, which permit a direct comparison of theoretical predictions. For an average particle size of 10 {micro}m with a Peclet number of {approx}0.2, JH and TMK deviate from each other. This deviation indicates an adiabatic type solidification path where heat of fusion is reabsorbed. It is interesting that this particle size range is also consistent with the appearance of a microcellular growth. While no glass formation is observed within this system, the smallest size powders appear to consist of a mixture of nanocrystalline Si and Al. Al-Sm alloys have been investigated within a composition range of 34 to 42 wt% Sm. Gas atomized powders of Al-Sm are investigated to explore the morphological and structural hierarchy that correlates with different degrees of departure from full equilibrium conditions. The resultant powders show a variety of structural selection with respect to amount of undercooling, with an amorphous structure appearing at the highest cooling rates. Because of the chaotic nature of gas atomization, Cu-block melt-spinning is used to produce a homogeneous amorphous structure. The as-quenched structure within Al-34 to 42 wt% Sm consists of nanocrystalline fcc-Al (on the order of 5 nm) embedded in an amorphous matrix. The nucleation density of fcc-Al after initial crystallization is on the order of 10{sup 22}-10{sup 23} m{sup -3}, which is 10{sup 5}-10{sup 6} orders of magnitude higher than what classical nucleation theory predicts. Detailed analysis of liquid and as-quenched structures using high energy synchrotron X-ray diffraction, high energy transmission electron microscopy, and atom probe tomography techniques revealed an Al-Sm network similar in appearance to a medium range order (MRO) structure. A model whereby these MRO clusters promote the observed high nucleation density of fcc-Al nanocrystals is proposed. The devitrification path was identified using high temperature, in-situ, high energy synchrotron X-ray diffraction techniques and the crystallization kinetics were described using an analytical Johnson-Mehl-Avrami (JMA) approach.

Kalay, Yunus Eren

2008-10-15T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Levitation Performance of Bulk High Temperature Superconductor Above the Permanent Magnet Guideway atDifferent Temperatures  

Science Journals Connector (OSTI)

The levitation performance of a high temperature superconducting (HTS) Maglev system was investigated at different temperatures for HTS Maglev vehicle application. Using a cryogenic measurement system, we stud...

Hua Jing; Suyu Wang; Ming Jiang; Jiasu Wang

2010-12-01T23:59:59.000Z

262

Quantitative Evaluation of Bulk and Interface Microstructures in Al-3003 Alloy Builds Made by Very High Power Ultrasonic Additive Manufacturing  

Science Journals Connector (OSTI)

Ultrasonically consolidated 3003 aluminum alloy builds were prepared with constituent tapes by using a very high power ultrasonic additive manufacturing (UAM) process. Microstructures of interface and...

Hiromichi T. Fujii; M. R. Sriraman

2011-12-01T23:59:59.000Z

263

Complex magnetic behavior and high spin polarization in Fe3-xMnxSi alloys  

Science Journals Connector (OSTI)

Fe3Si is a ferromagnetic material with possible applications in magnetic tunnel junctions. When doped with Mn, the material shows a complex magnetic behavior, as suggested by older experiments. We employed the Korringa-Kohn-Rostoker Green-function method within density-functional theory in order to study the alloy Fe3-xMnxSi, with 0?x?1. Chemical disorder is described within the coherent potential approximation. In agreement with experiment, we find that the Mn atoms align ferromagnetically to the Fe atoms, and that the magnetization and Curie temperature drop with increasing Mn concentration x. The calculated spin polarization P at the Fermi level varies strongly with x, from P=-0.3 at x=0 (ordered Fe3Si) through P=0 at x=0.28, to P=+1 for x>0.75; i.e., at high Mn concentrations the system is half metallic. We discuss the origin of the trends of magnetic moments, exchange interactions, Curie temperature, and the spin polarization.

Marjana Leai?, Phivos Mavropoulos, Stefan Blgel, and Hubert Ebert

2011-03-30T23:59:59.000Z

264

Scaling in high-temperature superconductors  

Science Journals Connector (OSTI)

A Hartree approximation is used to study the interplay of two kinds of scaling which arise in high-temperature superconductors, namely critical-point scaling and that due to the confinement of electron pairs to their lowest Landau level in the presence of an applied magnetic field. In the neighborhood of the zero-field critical point, thermodynamic functions scale with the scaling variable [T-Tc2(B)]/B1/2?, which differs from the variable [T-Tc(0)]/B1/2? suggested by the Gaussian approximation. Lowest-Landau-level (LLL) scaling occurs in a region of high field surrounding the upper critical-field line but not in the vicinity of the zero-field transition. For YBa2Cu3O7-? in particular, a field of at least 10 T is needed to observe LLL scaling. These results are consistent with a range of recent experimental measurements of the magnetization, transport properties, and, especially, the specific heat of high-Tc materials.

Ian D. Lawrie

1994-10-01T23:59:59.000Z

265

The New England High-Resolution Temperature Program  

Science Journals Connector (OSTI)

The New England High-Resolution Temperature Program seeks to improve the accuracy of summertime 2-m temperature and dewpoint temperature forecasts in the New England region through a collaborative effort between the research and operational ...

David J. Stensrud; Nusrat Yussouf; Michael E. Baldwin; Jeffery T. McQueen; Jun Du; Binbin Zhou; Brad Ferrier; Geoffrey Manikin; F. Martin Ralph; James M. Wilczak; Allen B. White; Irina Djlalova; Jian-Wen Bao; Robert J. Zamora; Stanley G. Benjamin; Patricia A. Miller; Tracy Lorraine Smith; Tanya Smirnova; Michael F. Barth

2006-04-01T23:59:59.000Z

266

High Temperature Materials Laboratory (HTML) - PSD Directorate  

NLE Websites -- All DOE Office Websites (Extended Search)

filler A National Resource for Collaborative Materials Research The High Temperature Materials Laboratory (HTML) User Program is on hiatus due to federal budget reductions. However, research projects at the HTML still may be conducted on a cost-recovery basis through the Work for Others (WFO) Program or under a Cooperative R&D Agreement (CRADA). Dr. Edgar Lara-Curzio, HTML Director Tel: 865.574.1749 Fax: 865.574.4913 laracurzioe@ornl.gov Christine Goudy, Administrative Specialist Tel: 865.574.8295 Fax: 865.574.4913 goudyc@ornl.gov Oak Ridge National Laboratory [MST Home] [ORNL Home] [Site Index] [Search][Disclaimer] [Webmaster] Oak Ridge National Laboratory is a national multi-program research and development facility managed by UT-Battelle, LLC for the U.S. Department of Energy

267

Multilayer ultra-high-temperature ceramic coatings  

DOE Patents (OSTI)

A coated carbon-carbon composite material with multiple ceramic layers to provide oxidation protection from ultra-high-temperatures, where if the carbon-carbon composite material is uninhibited with B.sub.4C particles, then the first layer on the composite material is selected from ZrB.sub.2 and HfB.sub.2, onto which is coated a layer of SiC coated and if the carbon-carbon composite material is inhibited with B.sub.4C particles, then protection can be achieved with a layer of SiC and a layer of either ZrB.sub.2 and HfB.sub.2 in any order.

Loehman, Ronald E. (Albuquerque, NM); Corral, Erica L. (Tucson, AZ)

2012-03-20T23:59:59.000Z

268

High temperature low friction surface coating  

DOE Patents (OSTI)

A high temperature, low friction, flexible coating for metal surfaces which are subject to rubbing contact includes a mixture of three parts graphite and one part cadmium oxide, ball milled in water for four hours, then mixed with thirty percent by weight of sodium silicate in water solution and a few drops of wetting agent. The mixture is sprayed 12-15 microns thick onto an electro-etched metal surface and air dried for thirty minutes, then baked for two hours at 65.degree. C. to remove the water and wetting agent, and baked for an additional eight hours at about 150.degree. C. to produce the optimum bond with the metal surface. The coating is afterwards burnished to a thickness of about 7-10 microns.

Bhushan, Bharat (Watervliet, NY)

1980-01-01T23:59:59.000Z

269

Development of CSS-42L{trademark}, a high performance carburizing stainless steel for high temperature aerospace applications  

SciTech Connect

Today`s aerospace engineering challenges demand materials which can operate under conditions of temperature extremes, high loads and harsh, corrosive environments. This paper presents a technical overview of the on-going development of CSS-42L (US Patent No. 5,424,028). This alloy is a case-carburizable, stainless steel alloy suitable for use in applications up to 427 C, particularly suited to high performance rolling element bearings, gears, shafts and fasteners. The nominal chemistry of CSS-42L includes: (by weight) 0.12% carbon, 14.0% chromium, 0.60% vanadium, 2.0% nickel, 4.75% molybdenum and 12.5% cobalt. Careful balancing of these components combined with VIM-VAR melting produces an alloy that can be carburized and heat treated to achieve a high surface hardness (>58 HRC at 1mm (0.040 in) depth) with excellent corrosion resistance. The hot hardness of the carburized case is equal to or better than all competitive grades, exceeding 60 HRC at 427 C. The fracture toughness and impact resistance of the heat treated core material have likewise been evaluated in detail and found to be better than M50-NiL steel. The corrosion resistance has been shown to be equivalent to that of 440C steel in tests performed to date.

Burrier, H.I.; Milam, L. [Timken Co., Canton, OH (United States); Tomasello, C.M.; Balliett, S.A.; Maloney, J.L. [Latrobe Steel Co., Latrobe, PA (United States); Ogden, W.P. [MPB Corp., Lebanon, NH (United States)

1998-12-31T23:59:59.000Z

270

High Temperature Steam Electrolysis Materials Degradation: Preliminary Results of Corrosion Tests on Ceramatec Electrolysis Cell Components  

SciTech Connect

Corrosion tests were performed on stainless steel and nickel alloy coupons in H2O/H2 mixtures and dry air to simulate conditions experienced in high temperature steam electrolysis systems. The stainless steel coupons were tested bare and with one of three different proprietary coatings applied. Specimens were corroded at 850C for 500 h with weight gain data recorded at periodic intervals. Post-test characterization of the samples included surface and cross-section scanning electron microscopy, grazing incidence x-ray diffraction, and area-specific resistance measurements. The uncoated nickel alloy outperformed the ferritic stainless steel under all test conditions based on weight gain data. Parabolic rate constants for corrosion of these two uncoated alloys were consistent with values presented in the literature under similar conditions. The steel coatings reduced corrosion rates in H2O/H2 mixtures by as much as 50% compared to the untreated steel, but in most cases showed negligible corrosion improvement in air. The use of a rare-earth-based coating on stainless steel did not result in a significantly different area specific resistance values after corrosion compared to the untreated alloy. Characterization of the samples is still in progress and the findings will be revised when the complete data set is available.

Paul Demkowicz; Prateek Sachdev; Kevin DeWall; Pavel Medvedev

2007-06-01T23:59:59.000Z

271

Assessment of microelectronics packaging for high temperature, high reliability applications  

SciTech Connect

This report details characterization and development activities in electronic packaging for high temperature applications. This project was conducted through a Department of Energy sponsored Cooperative Research and Development Agreement between Sandia National Laboratories and General Motors. Even though the target application of this collaborative effort is an automotive electronic throttle control system which would be located in the engine compartment, results of this work are directly applicable to Sandia`s national security mission. The component count associated with the throttle control dictates the use of high density packaging not offered by conventional surface mount. An enabling packaging technology was selected and thermal models defined which characterized the thermal and mechanical response of the throttle control module. These models were used to optimize thick film multichip module design, characterize the thermal signatures of the electronic components inside the module, and to determine the temperature field and resulting thermal stresses under conditions that may be encountered during the operational life of the throttle control module. Because the need to use unpackaged devices limits the level of testing that can be performed either at the wafer level or as individual dice, an approach to assure a high level of reliability of the unpackaged components was formulated. Component assembly and interconnect technologies were also evaluated and characterized for high temperature applications. Electrical, mechanical and chemical characterizations of enabling die and component attach technologies were performed. Additionally, studies were conducted to assess the performance and reliability of gold and aluminum wire bonding to thick film conductor inks. Kinetic models were developed and validated to estimate wire bond reliability.

Uribe, F.

1997-04-01T23:59:59.000Z

272

High Temperature Integrated Thermoelectric Ststem and Materials  

SciTech Connect

The final goal of this project is to produce, by the end of Phase II, an all ceramic high temperature thermoelectric module. Such a module design integrates oxide ceramic n-type, oxide ceramic p-type materials as thermoelectric legs and oxide ceramic conductive material as metalizing connection between n-type and p-type legs. The benefits of this all ceramic module are that it can function at higher temperatures (> 700 C), it is mechanically and functionally more reliable and it can be scaled up to production at lower cost. With this all ceramic module, millions of dollars in savings or in new opportunities recovering waste heat from high temperature processes could be made available. A very attractive application will be to convert exhaust heat from a vehicle to reusable electric energy by a thermoelectric generator (TEG). Phase I activities were focused on evaluating potential n-type and p-type oxide compositions as the thermoelectric legs. More than 40 oxide ceramic powder compositions were made and studied in the laboratory. The compositions were divided into 6 groups representing different material systems. Basic ceramic properties and thermoelectric properties of discs sintered from these powders were measured. Powders with different particles sizes were made to evaluate the effects of particle size reduction on thermoelectric properties. Several powders were submitted to a leading thermoelectric company for complete thermoelectric evaluation. Initial evaluation showed that when samples were sintered by conventional method, they had reasonable values of Seebeck coefficient but very low values of electrical conductivity. Therefore, their power factors (PF) and figure of merits (ZT) were too low to be useful for high temperature thermoelectric applications. An unconventional sintering method, Spark Plasma Sintering (SPS) was determined to produce better thermoelectric properties. Particle size reduction of powders also was found to have some positive benefits. Two composition systems, specifically 1.0 SrO - 0.8 x 1.03 TiO2 - 0.2 x 1.03 NbO2.5 and 0.97 TiO2 - 0.03 NbO2.5, have been identified as good base line compositions for n-type thermoelectric compositions in future module design. Tests of these materials at an outside company were promising using that company's processing and material expertise. There was no unique p-type thermoelectric compositions identified in phase I work other than several current cobaltite materials. Ca3Co4O9 will be the primary p-type material for the future module design until alternative materials are developed. BaTiO3 and rare earth titanate based dielectric compositions show both p-type and n-type behavior even though their electrical conductivities were very low. Further research and development of these materials for thermoelectric applications is planned in the future. A preliminary modeling and optimization of a thermoelectric generator (TEG) that uses the n-type 1.0 SrO - 1.03 x 0.8 TiO2 - 1.03 x 0.2 NbO2.5 was performed. Future work will combine development of ceramic powders and manufacturing expertise at TAM, development of SPS at TAM or a partner organization, and thermoelectric material/module testing, modeling, optimization, production at several partner organizations.

Mike S. H. Chu

2011-06-06T23:59:59.000Z

273

Weldable ductile molybdenum alloy development  

SciTech Connect

Molybdenum and its alloys are attractive structural materials for high-temperature applications. However, various practical issues have limited its use. One concern relates to the loss of ductility occurring in the heat-affected weld zone caused by segregation of oxygen to grain boundaries. In this study, a series of arc melted molybdenum alloys have been produced containing controlled additions of B, C, Zr, and Al. These alloys were characterized with respect to their tensile properties, smooth bend properties, and impact energy for both the base metal and welds. These alloys were compared with a very high purity low carbon arc cast molybdenum reference. For discussion purposes the alloys produced are separated into two categories: Mo Al B alloys, and Mo Zr B alloys. The properties of Mo Zr B alloy welds containing higher carbon levels exhibited slight improvement over unalloyed molybdenum, though the base-metal properties for all Mo Zr B alloys were somewhat inconsistent with properties better, or worse, than unalloyed molybdenum. A Mo Al B alloy exhibited the best DBTT values for welds, and the base metal properties were comparable to or slightly better than unalloyed molybdenum. The Mo Al B alloy contained a low volume fraction of second-phase particles, with segregation of boron and carbon to grain boundaries believed to displace oxygen resulting in improved weld properties. The volume fractions of second-phase particles are higher for the Mo Zr B alloys, and these alloys were prone to brittle fracture. It is also noted that these Mo Zr B alloys exhibited segregation of zirconium, boron and carbon to the grain boundaries.

Cockeram, B. V. [Bettis Atomic Power Laboratory, West Mifflin, PA; Ohriner, Evan Keith [ORNL; Byun, Thak Sang [ORNL; Schneibel, Joachim H [ORNL; Miller, Michael K [ORNL; Snead, Lance Lewis [ORNL

2008-01-01T23:59:59.000Z

274

Corrosion resistant positive electrode for high-temperature, secondary electrochemical cell  

DOE Patents (OSTI)

The corrosion rate of low carbon steel within a positive electrode of a high-temperature, secondary electrochemical cell that includes FeS as active material is substantially reduced by incorporating therein finely divided iron powder in stoichiometric excess to the amount required to form FeS in the fully charged electrode. The cell typically includes an alkali metal or alkaline earth metal as negative electrode active material and a molten metal halide salt as electrolyte. The excess iron permits use of inexpensive carbon steel alloys that are substantially free of the costly corrosion resistant elements chromium, nickel and molybdenum while avoiding shorten cell life resulting from high corrosion rates.

Otto, N.C.; Warner, B.T.; Smaga, J.A.; Battles, J.E.

1982-07-07T23:59:59.000Z

275

E-Print Network 3.0 - alloy-c-103 Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

materials are illustrated in Fig. 6(a): a Niobium alloy (C... -103), the ceramic matrix composite C-SiC (benchmark material), a high-temperature Copper alloy (Gr Source:...

276

Fuel Cell Technologies Office: 2009 High Temperature Membrane Working Group  

NLE Websites -- All DOE Office Websites (Extended Search)

9 High Temperature 9 High Temperature Membrane Working Group Meeting Archives to someone by E-mail Share Fuel Cell Technologies Office: 2009 High Temperature Membrane Working Group Meeting Archives on Facebook Tweet about Fuel Cell Technologies Office: 2009 High Temperature Membrane Working Group Meeting Archives on Twitter Bookmark Fuel Cell Technologies Office: 2009 High Temperature Membrane Working Group Meeting Archives on Google Bookmark Fuel Cell Technologies Office: 2009 High Temperature Membrane Working Group Meeting Archives on Delicious Rank Fuel Cell Technologies Office: 2009 High Temperature Membrane Working Group Meeting Archives on Digg Find More places to share Fuel Cell Technologies Office: 2009 High Temperature Membrane Working Group Meeting Archives on AddThis.com...

277

High-Temperature Solar Selective Coating Development for Power...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

High-Temperature Solar Selective Coating Development for Power Tower Receivers - FY13 Q2 High-Temperature Solar Selective Coating Development for Power Tower Receivers - FY13 Q2...

278

Development of a 100-Watt High Temperature Thermoelectric Generator  

Energy.gov (U.S. Department of Energy (DOE))

Test results for low and high temperature thermoelectric generators (TEG) those for a 530-watt BiTe TEG; design and construction of a 100-watt high temperature TEG currently in fabrication.

279

Corrosion Studies in High-Temperature Molten Salt Systems for...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Corrosion Studies in High-Temperature Molten Salt Systems for CSP Applications - FY13 Q1 Corrosion Studies in High-Temperature Molten Salt Systems for CSP Applications - FY13 Q1...

280

Motor Using High Temperature Superconductor as a Rotor  

Science Journals Connector (OSTI)

It is found that a high temperature superconductor rotates in the rotating magnetic field at ... authors and a small motor is made using high temperature superconductor as a rotor. This motor rotates at...

Makoto Takenaka; Masaharu Minami; Kazuo Morimoto

1994-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

High and Low Temperature Series Estimates for the Critical Temperature of the 3D Ising Model  

E-Print Network (OSTI)

High and Low Temperature Series Estimates for the Critical Temperature of the 3D Ising Model Zaher Abstract We have analysed low and high temperature series expansions for the three­dimensional Ising model temperature of the three­dimensional (3d) Ising model on the simple cubic lattice has been exhaustively

Adler, Joan

282

TEM Characterization of High Burn-up Microstructure of U-7Mo Alloy  

SciTech Connect

As an essential part of global nuclear non-proliferation effort, the RERTR program is developing low enriched U-Mo fuels (< 20% U-235) for use in research and test reactors that currently employ highly enriched uranium fuels. One type of fuel being developed is a dispersion fuel plate comprised of U-7Mo particles dispersed in Al alloy matrix. Recent TEM characterizations of the ATR irradiated U-7Mo dispersion fuel plates include the samples with a local fission densities of 4.5, 5.2, 5.6 and 6.3 E+21 fissions/cm3 and irradiation temperatures of 101-136?C. The development of the irradiated microstructure of the U-7Mo fuel particles consists of fission gas bubble superlattice, large gas bubbles, solid fission product precipitates and their association to the large gas bubbles, grain subdivision to tens or hundreds of nanometer size, collapse of bubble superlattice, and amorphisation. This presentation will describe the observed microstructures specifically focusing on the U-7Mo fuel particles. The impact of the observed microstructure on the fuel performance and the comparison of the relevant features with that of the high burn-up UO2 fuels will be discussed.

Jian Gan; Brandon Miller; Dennis Keiser; Adam Robinson; James Madden; Pavel Medvedev; Daniel Wachs

2014-04-01T23:59:59.000Z

283

Hydrogen Production from Nuclear Energy via High Temperature Electrolysis  

SciTech Connect

This paper presents the technical case for high-temperature nuclear hydrogen production. A general thermodynamic analysis of hydrogen production based on high-temperature thermal water splitting processes is presented. Specific details of hydrogen production based on high-temperature electrolysis are also provided, including results of recent experiments performed at the Idaho National Laboratory. Based on these results, high-temperature electrolysis appears to be a promising technology for efficient large-scale hydrogen production.

James E. O'Brien; Carl M. Stoots; J. Stephen Herring; Grant L. Hawkes

2006-04-01T23:59:59.000Z

284

Agenda for the High Temperature Membrane Working Group Meeting  

Energy.gov (U.S. Department of Energy (DOE))

This agenda provides information about the Agenda for the High Temperature Membrane Working Group Meeting on September 14, 2006.

285

High Temperature Membrane Working Group Meeting, May 14, 2007  

Energy.gov (U.S. Department of Energy (DOE))

This agenda provides information about the High Temperature Membrane Working Group Meeting on May 14, 2007 in Arlington, Va.

286

Nanostructured High-Temperature Bulk Thermoelectric Energy Conversion...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

More Documents & Publications Nanostructured High-Temperature Bulk Thermoelectric Energy Conversion for Efficient Automotive Waste Heat Recovery Vehicle Technologies Office...

287

ANALYSIS OF FUTURE PRICES AND MARKETS FOR HIGH TEMPERATURE SUPERCONDUCTORS  

E-Print Network (OSTI)

1 ANALYSIS OF FUTURE PRICES AND MARKETS FOR HIGH TEMPERATURE SUPERCONDUCTORS BY JOSEPH MULHOLLAND of Future Prices and Markets for High Temperature Superconductors 2 I . PURPOSE, SCOPE AND APPROACH analysts to make estimates about the future of high temperature superconductor (HTS) technology

288

Vibrational Raman Spectroscopy of High-temperature Superconductors  

E-Print Network (OSTI)

Vibrational Raman Spectroscopy of High-temperature Superconductors C. Thomsen and G. Kaczmarczyk after the discovery of high- critical-temperature Tc superconductors:2 while reports on Raman scattering Wiley & Sons Ltd, Chichester, 2002 #12;Vibrational Raman Spectroscopy of High-temperature

Nabben, Reinhard

289

High performance internal reforming unit for high temperature fuel cells  

DOE Patents (OSTI)

A fuel reformer having an enclosure with first and second opposing surfaces, a sidewall connecting the first and second opposing surfaces and an inlet port and an outlet port in the sidewall. A plate assembly supporting a catalyst and baffles are also disposed in the enclosure. A main baffle extends into the enclosure from a point of the sidewall between the inlet and outlet ports. The main baffle cooperates with the enclosure and the plate assembly to establish a path for the flow of fuel gas through the reformer from the inlet port to the outlet port. At least a first directing baffle extends in the enclosure from one of the sidewall and the main baffle and cooperates with the plate assembly and the enclosure to alter the gas flow path. Desired graded catalyst loading pattern has been defined for optimized thermal management for the internal reforming high temperature fuel cells so as to achieve high cell performance.

Ma, Zhiwen (Sandy Hook, CT); Venkataraman, Ramakrishnan (New Milford, CT); Novacco, Lawrence J. (Brookfield, CT)

2008-10-07T23:59:59.000Z

290

Project Profile: High-Temperature Solar Selective Coating Development...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

water droplets falling on a flat, dust-covered surface. The research team is exploring materials with high melting temperatures, intrinsic oxidation resistance, high thermal...

291

Structural alloy with a protective coating containing silicon or silicon-oxide  

DOE Patents (OSTI)

An iron-based alloy is described containing chromium and optionally, nickel. The alloy has a surface barrier of silicon or silicon plus oxygen which converts at high temperature to a protective silicon compound. The alloy can be used in oxygen-sulfur mixed gases at temperatures up to about 1100 C. 8 figures.

Natesan, K.

1994-12-27T23:59:59.000Z

292

Structural alloy with a protective coating containing silicon or silicon-oxide  

DOE Patents (OSTI)

This invention is comprised of an iron-based alloy containing chromium and optionally, nickel. The alloy has a surface barrier of silicon or silicon plus oxygen which converts at high temperature to a protective silicon compound. The alloy can be used in oxygen-sulfur mixed gases at temperatures up to about 1100{degrees}C.

Natesan, K.

1992-01-01T23:59:59.000Z

293

Free energy of QCD at high temperature  

Science Journals Connector (OSTI)

Effective-field-theory methods are used to separate the free energy for a non-Abelian gauge theory at high temperature T into the contributions from the momentum scales T, gT, and g2T, where g is the coupling constant at the scale 2?T. The effects of the scale T enter through the coefficients in the effective Lagrangian for the three-dimensional effective theory obtained by dimensional reduction. These coefficients can be calculated as power series in g2. The contribution to the free energy from the scale gT can be calculated using perturbative methods in the effective theory. It can be expressed as an expansion in g starting at order g3. The contribution from the scale g2T must be calculated using nonperturbative methods, but nevertheless it can be expanded in powers of g beginning at order g6. We calculate the free energy explicitly to order g5. We also outline the calculations necessary to obtain the free energy to order g6.

Eric Braaten and Agustin Nieto

1996-03-15T23:59:59.000Z

294

Development of Strengthened Bundle High Temperature Superconductors  

SciTech Connect

In the process of developing high temperature superconducting (HTS) transmission cables, it was found that mechanical strength of the superconducting tape is the most crucial property that needs to be improved. It is also desirable to increase the current carrying capacity of the conductor so that fewer layers are needed to make the kilo-amp class cables required for electric utility usage. A process has been developed by encapsulating a stack of Bi-2223/Ag tapes with a silver or non-silver sheath to form a strengthened bundle superconductor. This process was applied to HTS tapes made by the Continuous Tube Forming and Filling (CTFF) technique pursued by Plastronic Inc. and HTS tapes obtained from other manufacturers. Conductors with a bundle of 2 to 6 HTS tapes have been made. The bundled conductor is greatly strengthened by the non-silver sheath. No superconductor degradation as compared to the sum of the original critical currents of the individual tapes was seen on the finished conductors.

Lue, J.W.; Lubell, M.S. [Oak Ridge National Lab., TN (United States); Demko, J.A. [Oak Ridge Inst. for Science and Education, TN (United States); Tomsic, M. [Plastronic, Inc., Troy, OH (United States); Sinha, U. [Southwire Company, Carollton, GA (United States)

1997-12-31T23:59:59.000Z

295

F A T I G U E 2 0 0 2 HIGH-CYCLE FATIGUE OF BETA TITANIUM ALLOYS  

E-Print Network (OSTI)

-object damage on jet engine fan blades is used as an engineering example of potential HCF applicationsF A T I G U E 2 0 0 2 HIGH-CYCLE FATIGUE OF BETA TITANIUM ALLOYS J. O. Peters*+ , G. Lütjering*, R) properties of the high-strength titanium alloys -Cez and Ti-6246 (in two distinctly different + processed

Ritchie, Robert

296

High Temperature 300C Directional Drilling System  

Energy.gov (U.S. Department of Energy (DOE))

Project objective: provide a directional drilling system that can be used at environmental temperatures of up to 300C; and at depths of 10; 000 meters.

297

High temperature, optically transparent plastics from biomass  

NLE Websites -- All DOE Office Websites (Extended Search)

temperature, optically transparent plastics from biomass At a Glance Rapid, selective catalytic system to produce vinyl plastics from renewable biomass Stereoregular...

298

The corrosion performance of high chromium stainless steels and titanium alloys at a reverse osmosis plant in Arabian Gulf seawater  

SciTech Connect

Electrochemical impedance spectroscopy (EIS) was used to evaluate the corrosion performance of four high chromium stainless steels and Grade 2 titanium in flowing Arabian Gulf natural seawater. The EIS provided information concerning the changes to the interfacial impedance as a function of exposure time for these alloys. The impedance spectra for all the alloys showed slight changes at the low frequency region over the exposure period. The open-circuit potentials (OCP) of these alloys were also monitored as a function of exposure time. The stainless steel alloys exhibited slight fluctuation in potential around the initial exposure potential. However, Grade 2 titanium initial potential was more active and then gradually shifted towards the noble direction. The linear polarization resistance (LPR) method indicated that Grade 2 titanium exhibited the lowest corrosion rate with respect to the stainless steel alloys. The results of the EIS analysis and OCP indicated that Grade 2 titanium performed better than the four high chromium stainless steel alloys.

Al-Odwani, A.; Al-Tabatabaei, M.; Carew, J.; Al-Hashem, A. [Kuwait Inst. for Scientific Research, Safat (Kuwait)

1997-08-01T23:59:59.000Z

299

NOvel Refractory Materials for High Alkali, High Temperature Environments  

SciTech Connect

Refractory materials can be limited in their application by many factors including chemical reactions between the service environment and the refractory material, mechanical degradation of the refractory material by the service environment, temperature limitations on the use of a particular refractory material, and the inability to install or repair the refractory material in a cost effective manner or while the vessel was in service. The objective of this project was to address the need for new innovative refractory compositions by developing a family of novel MgO-Al2O3 spinel or other similar magnesia/alumina containing unshaped refractory composition (castables, gunnables, shotcretes, etc) utilizing new aggregate materials, bond systems, protective coatings, and phase formation techniques (in-situ phase formation, altered conversion temperatures, accelerated reactions, etc). This family of refractory compositions would then be tailored for use in high-temperature, highalkaline industrial environments like those found in the aluminum, chemical, forest products, glass, and steel industries. A research team was formed to carry out the proposed work led by Oak Ridge National Laboratory (ORNL) and was comprised of the academic institution Missouri University of Science and Technology (MS&T), and the industrial company MINTEQ International, Inc. (MINTEQ), along with representatives from the aluminum, chemical, glass, and forest products industries. The two goals of this project were to produce novel refractory compositions which will allow for improved energy efficiency and to develop new refractory application techniques which would improve the speed of installation. Also methods of hot installation were sought which would allow for hot repairs and on-line maintenance leading to reduced process downtimes and eliminating the need to cool and reheat process vessels.

Hemrick, J.G.; Griffin, R. (MINTEQ International, Inc.)

2011-08-30T23:59:59.000Z

300

Fracture Behavior of a Laser Beam Welded High-strength Al-Zn Alloy  

Science Journals Connector (OSTI)

Abstract Laser beam welding of butt joints made of the newly developed high-strength Al-Zn alloy PA734 is conducted. A new approach of the Helmholtz-Zentrum Geesthacht is used to solve the problems of weldability and softening. The results of the fatigue, fatigue crack propagation and fracture toughness tests are discussed relating to the microstructural characteristics and the mechanical properties of the laser welded joints and compared to the base material. The obtained data can be used for the assessment of the damage tolerance behaviour of the laser welded integral aircraft structures made of Al-Zn alloys.

J. Enz; H. Iwan; S. Riekehr; V. Ventzke; N. Kashaev

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Ultra-High Temperature Distributed Wireless Sensors  

SciTech Connect

Research was conducted towards the development of a passive wireless sensor for measurement of temperature in coal gasifiers and coal-fired boiler plants. Approaches investigated included metamaterial sensors based on guided mode resonance filters, and temperature-sensitive antennas that modulate the frequency of incident radio waves as they are re-radiated by the antenna. In the guided mode resonant filter metamaterial approach, temperature is encoded as changes in the sharpness of the filter response, which changes with temperature because the dielectric loss of the guided mode resonance filter is temperature-dependent. In the mechanically modulated antenna approach, the resonant frequency of a vibrating cantilever beam attached to the antenna changes with temperature. The vibration of the beam perturbs the electrical impedance of the antenna, so that incident radio waves are phase modulated at a frequency equal to the resonant frequency of the vibrating beam. Since the beam resonant frequency depends on temperature, a Doppler radar can be used to remotely measure the temperature of the antenna. Laboratory testing of the guided mode resonance filter failed to produce the spectral response predicted by simulations. It was concluded that the spectral response was dominated by spectral reflections of radio waves incident on the filter. Laboratory testing of the mechanically modulated antenna demonstrated that the device frequency shifted incident radio waves, and that the frequency of the re-radiated waves varied linearly with temperature. Radio wave propagation tests in the convection pass of a small research boiler plant identified a spectral window between 10 and 13 GHz for low loss propagation of radio waves in the interior of the boiler.

May, Russell; Rumpf, Raymond; Coggin, John; Davis, Williams; Yang, Taeyoung; O'Donnell, Alan; Bresnahan, Peter

2013-03-31T23:59:59.000Z

302

Vibration Combined High Temperature Cycle Tests for Capacitive MEMS  

E-Print Network (OSTI)

Vibration Combined High Temperature Cycle Tests for Capacitive MEMS Accelerometers Z. Szcs, G. Nagy|nagyg|hodossy|rencz|poppe>@eet.bme.hu Abstract - In this paper vibration combined high temperature cycle tests for packaged capacitive SOI- MEMS designed and realized at BME ­ DED. Twenty thermal cycles of combined Temperature Cycle Test and Fatigue

Boyer, Edmond

303

High temperature, minimally invasive optical sensing modules  

DOE Patents (OSTI)

A remote temperature sensing system includes a light source selectively producing light at two different wavelengths and a sensor device having an optical path length that varies as a function of temperature. The sensor receives light emitted by the light source and redirects the light along the optical path length. The system also includes a detector receiving redirected light from the sensor device and generating respective signals indicative of respective intensities of received redirected light corresponding to respective wavelengths of light emitted by the light source. The system also includes a processor processing the signals generated by the detector to calculate a temperature of the device.

Riza, Nabeel Agha (Oviedo, FL); Perez, Frank (Tujunga, CA)

2008-02-05T23:59:59.000Z

304

A Successful Synthesis of the CoCrFeNiAl{sub 0.3} Single-Crystal, High-Entropy Alloy by Bridgman Solidification  

SciTech Connect

For the first time, a face-centered-cubic, single-crystal CoCrFeNiAl{sub 0.3} (designated as Al0.3), high-entropy alloy (HEA) was successfully synthesized by the Bridgman solidification (BS) method, at an extremely low withdrawal velocity through a constant temperature gradient, for which it underwent two BS steps. Specially, at the first BS step, the alloy sample underwent several morphological transitions accompanying the crystal growth from the melt. This microstructure evolves from as-cast dendrites, to equiaxed grains, and then to columnar crystals, and last to the single crystal. In particular, at the equiaxed-grain region, some visible annealing twins were observed, which indicates a low stacking fault energy of the Al0.3 alloy. Although a body-centered- cubic CoCrFeNiAl (Al1) HEA was also prepared under the same conditions, only a single columnar-crystal structure with instinctively preferential crystallographic orientations was obtained by the same procedure. A similar morphological transition from dendrites to equiaxed grains occurred at the equiaxed-grain region in Al1 alloy, but the annealing twins were not observed probably because a higher Al addition leads to a higher stacking fault energy for this alloy.

Ma, S. G.; Zhang, S. F.; Gao, M. C.; Liaw, P. K.; Zhang, Y.

2013-12-01T23:59:59.000Z

305

Highly temperature insensitive quantum cascade lasers  

SciTech Connect

An InP based quantum cascade laser (QCL) heterostructure emitting around 5 {mu}m is grown with gas-source molecular beam epitaxy. The QCL core design takes a shallow-well approach to maximize the characteristic temperatures, T{sub 0} and T{sub 1}, for operations above room temperature. A T{sub 0} value of 383 K and a T{sub 1} value of 645 K are obtained within a temperature range of 298-373 K. In room temperature continuous wave operation, this design gives a single facet output power of 3 W and a wall plug efficiency of 16% from a device with a cavity length of 5 mm and a ridge width of 8 {mu}m.

Bai, Y.; Bandyopadhyay, N.; Tsao, S.; Selcuk, E.; Slivken, S.; Razeghi, M. [Department of Electrical Engineering and Computer Science, Center for Quantum Devices, Northwestern University, Evanston, Illinois 60208 (United States)

2010-12-20T23:59:59.000Z

306

Mechanical characterization of metallic materials for high-temperature gas-cooled reactors in air and in helium environments  

SciTech Connect

In the French R and D program for high-temperature gas-cooled reactors (HTGRs), three metallic alloys were studied: steel Chromesco-3 with 2.25% chromium, alloy 800H, and Hastelloy-X. The Chromesco-3 and alloy 800H creep behavior is the same in air and in HTGR atmosphere (helium). The tensile tests of Hastelloy-X specimens reveal that aging has embrittlement and hardening effects up to 700/sup 0/C, but the creep tests at 800/sup 0/C show opposite effects. This particular behavior could be due to induced precipitation by aging and the depletion of hardening elements from the matrix. Tests show a low influence of cobalt content on mechanical properties of Hastelloy-X.

Sainfort, G.; Cappelaere, M.; Gregoire, J.; Sannier, J.

1984-07-01T23:59:59.000Z

307

Fuel Cell Technologies Office: High Temperature Membrane Working Group  

NLE Websites -- All DOE Office Websites (Extended Search)

High Temperature Membrane Working Group High Temperature Membrane Working Group The High Temperature Membrane Working Group consists of government, industry, and university researchers interested in developing high temperature membranes for fuel cells. Description Technical Targets Meetings Contacts Description Polymer electrolyte membrane (PEM) fuel cells typically operate at temperatures no higher than 60°C-80°C due to structural limitations of the membrane. Operating PEM fuel cell stacks at higher temperatures (120°C for transportation and 150°C for stationary applications), however, would yield significant energy benefits. For example, heat rejection is easier at higher temperatures, which would allow use of smaller heat exchangers in fuel cell power systems. In addition, for reformate fuel cell systems, carbon monoxide (CO) tolerance of the stack is less problematic at higher temperatures, which would reduce the size requirements or possibly eliminate the need for some CO clean-up beds in the fuel processor.

308

High-temperature neutron diffraction study of deuterated brucite  

Science Journals Connector (OSTI)

To study the structural behavior of brucite at high temperature, we conducted in situ neutron diffraction experiments of a deuterated brucite powder sample, Mg(OD)2, in the temperature range 313583K. The sample...

Hongwu Xu; Yusheng Zhao; Donald D. Hickmott

2013-11-01T23:59:59.000Z

309

Cryogenic deformation of high temperature superconductive composite structures  

DOE Patents (OSTI)

An improvement in a process of preparing a composite high temperature oxide superconductive wire is provided and involves conducting at least one cross-sectional reduction step in the processing preparation of the wire at sub-ambient temperatures.

Roberts, Peter R. (Groton, MA); Michels, William (Brookline, MA); Bingert, John F. (Jemez Springs, NM)

2001-01-01T23:59:59.000Z

310

Vortices in high-temperature superconductors  

Science Journals Connector (OSTI)

With the high-temperature superconductors a qualitatively new regime in the phenomenology of type-II superconductivity can be accessed. The key elements governing the statistical mechanics and the dynamics of the vortex system are (dynamic) thermal and quantum fluctuations and (static) quenched disorder. The importance of these three sources of disorder can be quantified by the Ginzburg number Gi=(TcHc2??3)22, the quantum resistance Qu=(e2?)(?n??), and the critical current-density ratio jcjo, with jc and jo denoting the depinning and depairing current densities, respectively (?n is the normal-state resistivity and ?2=mMsuperconductors, leading to interesting effects such as the melting of the vortex lattice, the creation of new vortex-liquid phases, and the appearance of macroscopic quantum phenomena. Introducing quenched disorder into the system turns the Abrikosov lattice into a vortex glass, whereas the vortex liquid remains a liquid. The terms "glass" and "liquid" are defined in a dynamic sense, with a sublinear response ?=?E?j|j?0 characterizing the truly superconducting vortex glass and a finite resistivity ?(j?0)>0 being the signature of the liquid phase. The smallness of jcjo allows one to discuss the influence of quenched disorder in terms of the weak collective pinning theory. Supplementing the traditional theory of weak collective pinning to take into account thermal and quantum fluctuations, as well as the new scaling concepts for elastic media subject to a random potential, this modern version of the weak collective pinning theory consistently accounts for a large number of novel phenomena, such as the broad resistive transition, thermally assisted flux flow, giant and quantum creep, and the glassiness of the solid state. The strong layering of the oxides introduces additional new features into the thermodynamic phase diagram, such as a layer decoupling transition, and modifies the mechanism of pinning and creep in various ways. The presence of strong (correlated) disorder in the form of twin boundaries or columnar defects not only is technologically relevant but also provides the framework for the physical realization of novel thermodynamic phases such as the Bose glass. On a macroscopic scale the vortex system exhibits self-organized criticality, with both the spatial and the temporal scale accessible to experimental investigations.

G. Blatter; M. V. Feigel'man; V. B. Geshkenbein; A. I. Larkin; V. M. Vinokur

1994-10-01T23:59:59.000Z

311

Fuel Cell Technologies Office: 2005 High Temperature Membrane Working Group  

NLE Websites -- All DOE Office Websites (Extended Search)

About About Printable Version Share this resource Send a link to Fuel Cell Technologies Office: 2005 High Temperature Membrane Working Group Meeting Archives to someone by E-mail Share Fuel Cell Technologies Office: 2005 High Temperature Membrane Working Group Meeting Archives on Facebook Tweet about Fuel Cell Technologies Office: 2005 High Temperature Membrane Working Group Meeting Archives on Twitter Bookmark Fuel Cell Technologies Office: 2005 High Temperature Membrane Working Group Meeting Archives on Google Bookmark Fuel Cell Technologies Office: 2005 High Temperature Membrane Working Group Meeting Archives on Delicious Rank Fuel Cell Technologies Office: 2005 High Temperature Membrane Working Group Meeting Archives on Digg Find More places to share Fuel Cell Technologies Office: 2005 High

312

Fuel Cell Technologies Office: 2004 High Temperature Membrane Working Group  

NLE Websites -- All DOE Office Websites (Extended Search)

About About Printable Version Share this resource Send a link to Fuel Cell Technologies Office: 2004 High Temperature Membrane Working Group Meeting Archives to someone by E-mail Share Fuel Cell Technologies Office: 2004 High Temperature Membrane Working Group Meeting Archives on Facebook Tweet about Fuel Cell Technologies Office: 2004 High Temperature Membrane Working Group Meeting Archives on Twitter Bookmark Fuel Cell Technologies Office: 2004 High Temperature Membrane Working Group Meeting Archives on Google Bookmark Fuel Cell Technologies Office: 2004 High Temperature Membrane Working Group Meeting Archives on Delicious Rank Fuel Cell Technologies Office: 2004 High Temperature Membrane Working Group Meeting Archives on Digg Find More places to share Fuel Cell Technologies Office: 2004 High

313

Fuel Cell Technologies Office: 2010 High Temperature Membrane Working Group  

NLE Websites -- All DOE Office Websites (Extended Search)

About About Printable Version Share this resource Send a link to Fuel Cell Technologies Office: 2010 High Temperature Membrane Working Group Meeting Archives to someone by E-mail Share Fuel Cell Technologies Office: 2010 High Temperature Membrane Working Group Meeting Archives on Facebook Tweet about Fuel Cell Technologies Office: 2010 High Temperature Membrane Working Group Meeting Archives on Twitter Bookmark Fuel Cell Technologies Office: 2010 High Temperature Membrane Working Group Meeting Archives on Google Bookmark Fuel Cell Technologies Office: 2010 High Temperature Membrane Working Group Meeting Archives on Delicious Rank Fuel Cell Technologies Office: 2010 High Temperature Membrane Working Group Meeting Archives on Digg Find More places to share Fuel Cell Technologies Office: 2010 High

314

Fuel Cell Technologies Office: 2007 High Temperature Membrane Working Group  

NLE Websites -- All DOE Office Websites (Extended Search)

About About Printable Version Share this resource Send a link to Fuel Cell Technologies Office: 2007 High Temperature Membrane Working Group Meeting Archives to someone by E-mail Share Fuel Cell Technologies Office: 2007 High Temperature Membrane Working Group Meeting Archives on Facebook Tweet about Fuel Cell Technologies Office: 2007 High Temperature Membrane Working Group Meeting Archives on Twitter Bookmark Fuel Cell Technologies Office: 2007 High Temperature Membrane Working Group Meeting Archives on Google Bookmark Fuel Cell Technologies Office: 2007 High Temperature Membrane Working Group Meeting Archives on Delicious Rank Fuel Cell Technologies Office: 2007 High Temperature Membrane Working Group Meeting Archives on Digg Find More places to share Fuel Cell Technologies Office: 2007 High

315

Structural and electronic properties of Si{sub 1-x}Ge{sub x} binary semiconducting alloys under the effect of temperature and pressure  

SciTech Connect

Based on the empirical pseudo-potential method which incorporates compositional disorder as an effective potential, the band structure of Si{sub 1-x}Ge{sub x} alloy are calculated for different alloy composition x. The effect of temperature and pressure on the electronic band structure of the considered alloy has been studied. Monotonic decreasing and increasing functions are obtained for the temperature and pressure dependent form factors respectively. Some physical quantities as band gaps, bowing parameters, and the refractive index of the considered alloy with different Ge concentration and under the effect of temperature and pressure are calculated. The results obtained are found in good agreement with the experimental and published data.

Degheidy, A. R.; Elkenany, E. B., E-mail: kena@mans.edu.eg [Mansoura University, Department of Physics, Faculty of Science (Egypt)

2013-10-15T23:59:59.000Z

316

Three-point bending test at extremely high temperature enhanced by real-time observation and measurement  

Science Journals Connector (OSTI)

Abstract We developed a three-point bending test equipment with a heating chamber to provide a high temperature environment. An observation window was intentionally opened in the chamber wall for image capture. A high speed camera is integrated to record the surface evolution of the specimen through the observation window. The fixture stage for the specimens was made of Al2O3 ceramic (>99% pure) and could resist extremely high temperature. This testing platform provides the specimens with an environment that is up to 1600C in atmosphere for three-point bending test. Experiments were conducted for refractory alloy and C/SiC (carbon fiber reinforced silicon carbide composites) and the surface evolution of these specimens at high temperature was recorded. The crack propagation of the specimens was captured real-time and provided more detailed information for study of fracture behavior of the materials at high temperature.

Xufei Fang; Jingmin Jia; Xue Feng

2015-01-01T23:59:59.000Z

317

E-Print Network 3.0 - alloyed molybdenum disilicide Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

Ecole Polytechnique, Centre de mathmatiques Collection: Mathematics 2 FATIGUE AND FRACTURE BEHAVIOR OF HIGH TEMPERATURE MATERIALS Summary: . These alloys can Boron-containing...

318

Viscosity of high-temperature iodine  

Science Journals Connector (OSTI)

The viscosity coefficient of iodine in the temperature range 500?T?3000 K is calculated. Because of the low dissociation energy of the I2 molecules, the dissociation degree of the gas increases quickly with temperature, and I+I2 and I+I collisions must be taken into account in calculations of viscosity at temperatures greater than 1000. Several possible channels for atom-atom interaction are considered, and the resulting collision integrals are averaged over all the important channels. It is also shown that the rigid-sphere model is inaccurate in predictions of the viscosity. The approach of the present work is general and can be used for other diatomic gases with arbitrary dissociation degree.

Steve H. Kang and Joseph A. Kunc

1991-09-15T23:59:59.000Z

319

Impurity effects on electronmode coupling in high-temperature superconductors  

E-Print Network (OSTI)

LETTERS Impurity effects on electron­mode coupling in high-temperature superconductors K. TERASHIMA espite years of intensive research on copper oxide superconductors with high transition temperatures (Tc in the high-Tc superconductors. The interaction of electrons with bosonic excitations (phonons or spin

Loss, Daniel

320

Heat treatment of NiCrFe alloy to optimize resistance to intergrannular stress corrosion  

DOE Patents (OSTI)

A process of producing a NiCrFe alloy having a high resistance to stress corrosion cracking comprising heating a NiCrFe alloy to a temperature sufficient to enable the carbon present in the alloy body in the form of carbide deposits to enter into solution, rapidly cool the alloy body, and heat the cooled body to a temperature between 1100.degree. to 1500.degree. F. for about 1 to 30 hours.

Steeves, Arthur F. (Schenectady, NY); Bibb, Albert E. (Clifton Park, NY)

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

High-temperature for improved ES  

E-Print Network (OSTI)

standard requires tests both for u powered systems. For the latter testin temperature has to be taken a perfect electric insulation active device. Regarding ESD r proposed protection should provide current: We propose a new MOS-IGB robustness ESD protection with low temp diffusions in the drain with various

Paris-Sud XI, Université de

322

High Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells  

Energy.gov (U.S. Department of Energy (DOE))

DOE Geothermal Peer Review 2010 - Presentation. Project objectives: Design, demonstrate, and qualify high-temperature high pressure zonal isolation devices compatible with the high temperature downhole Enhanced Geothermal Systems (EGS) environment.

323

First high-temperature electronics products survey 2005.  

SciTech Connect

On April 4-5, 2005, a High-Temperature Electronics Products Workshop was held. This workshop engaged a number of governmental and private industry organizations sharing a common interest in the development of commercially available, high-temperature electronics. One of the outcomes of this meeting was an agreement to conduct an industry survey of high-temperature applications. This report covers the basic results of this survey.

Normann, Randy Allen

2006-04-01T23:59:59.000Z

324

Rotational viscometer for high-pressure, high-temperature fluids  

DOE Patents (OSTI)

The invention is a novel rotational viscometer which is well adapted for use with fluids at high temperatures and/or pressures. In one embodiment, the viscometer include a substantially non-magnetic tube having a closed end and having an open end in communication with a fluid whose viscosity is to be determined. An annular drive magnet is mounted for rotation about the tube. The tube encompasses and supports a rotatable shaft assembly which carries a rotor, or bob, for insertion in the fluid. Affixed to the shaft are (a) a second magnet which is magnetically coupled to the drive magnet and (b) a third magnet. In a typical operation, the drive magnet is rotated to turn the shaft assembly while the shaft rotor is immersed in the fluid. The viscous drag on the rotor causes the shaft assembly to lag the rotation of the drive magnet by an amount which is a function of the amount of viscous drag. A first magnetic pickup generates a waveform whose phase is a function of the angular position of the drive magnet. A second magnetic pickup generates a waveform whose phase is a function of the angular position of the third magnet. Means are provided to generate an output indicative of the phase difference between the two waveforms. The viscometer is comparatively simple, inexpensive, rugged, and does not require shaft seals.

Carr, K.R.

1983-06-06T23:59:59.000Z

325

High pressure--high temperature research using high energy synchrotron radiation at the TRISTAN accumulation ring  

SciTech Connect

High energy synchrotron radiation emitted from the bending magnet of the TRISTAN accumulation ring (6.5 GeV) at the National Laboratory for High Energy Physics has been used for the high pressure--high temperature diffraction experiments using a multianvil press system, MAX80. Owing to the specific features of high energy synchroton radiation, significant improvements have been brought to the high pressure research. The wide energy range of diffraction spectrum leads to an increase in the number of observable diffraction peaks in an energy-dispersive method, resulting in an increase in the accuracy of the measurements of the lattice and thermal parameters. Due to the high penetrating power of radiation, diffraction patterns can be taken in a short time from materials containing heavy elements or materials surrounded by a metal foil. Typical examples of high pressure--high temperature experiments with high energy synchrotron radiation are also described.

Kikegawa, T.; Shimomura, O.; Iwasaki, H.; Sato, S.; Mikuni, A.; Iida, A.; Kamiya, N.

1989-07-01T23:59:59.000Z

326

ANALYSIS OF A HIGH TEMPERATURE GAS-COOLED REACTOR POWERED HIGH TEMPERATURE ELECTROLYSIS HYDROGEN PLANT  

SciTech Connect

An updated reference design for a commercial-scale high-temperature electrolysis (HTE) plant for hydrogen production has been developed. The HTE plant is powered by a high-temperature gas-cooled reactor (HTGR) whose configuration and operating conditions are based on the latest design parameters planned for the Next Generation Nuclear Plant (NGNP). The current HTGR reference design specifies a reactor power of 600 MWt, with a primary system pressure of 7.0 MPa, and reactor inlet and outlet fluid temperatures of 322C and 750C, respectively. The reactor heat is used to produce heat and electric power to the HTE plant. A Rankine steam cycle with a power conversion efficiency of 44.4% was used to provide the electric power. The electrolysis unit used to produce hydrogen includes 1.1 million cells with a per-cell active area of 225 cm2. The reference hydrogen production plant operates at a system pressure of 5.0 MPa, and utilizes a steam-sweep system to remove the excess oxygen that is evolved on the anode (oxygen) side of the electrolyzer. The overall system thermal-to-hydrogen production efficiency (based on the higher heating value of the produced hydrogen) is 42.8% at a hydrogen production rate of 1.85 kg/s (66 million SCFD) and an oxygen production rate of 14.6 kg/s (33 million SCFD). An economic analysis of this plant was performed with realistic financial and cost estimating The results of the economic analysis demonstrated that the HTE hydrogen production plant driven by a high-temperature helium-cooled nuclear power plant can deliver hydrogen at a competitive cost. A cost of $3.03/kg of hydrogen was calculated assuming an internal rate of return of 10% and a debt to equity ratio of 80%/20% for a reactor cost of $2000/kWt and $2.41/kg of hydrogen for a reactor cost of $1400/kWt.

M. G. McKellar; E. A. Harvego; A. M. Gandrik

2010-11-01T23:59:59.000Z

327

Overview of Fraunhofer IPM Activities in High Temperature Bulk...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Workshop including an overview about Fraunhofer IPM, new funding situation in Germany, high temperature material and modules, energy-autarkic sensors, and thermoelectric...

328

Development of a 500 Watt High Temperature Thermoelectric Generator...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

More Documents & Publications Development of a 100-Watt High Temperature Thermoelectric Generator Automotive Waste Heat Conversion to Power Program Automotive Waste Heat...

329

Institute of Chemical Engineering and High Temperature Chemical...  

Open Energy Info (EERE)

Chemical Processes ICEHT Jump to: navigation, search Name: Institute of Chemical Engineering and High Temperature Chemical Processes (ICEHT) Place: Hellas, Greece Zip:...

330

Variable Temperature Ultra-High Vacuum Scanning Tunneling Microscope...  

NLE Websites -- All DOE Office Websites (Extended Search)

Vacuum Scanning Tunneling Microscope The Omicron variable temperature ultra-high vacuum (UHV) scanning tunneling microscope (VTSTM) is designed to study the structure of both clean...

331

High Temperature Superconducting Fault Current Limiter for Utility Applications  

Science Journals Connector (OSTI)

One of the most near term High Temperature Superconductor (HTS) applications is the Fault Current Limiter (FCL). It is a device that...

E. M. W. Leung; G. W. Albert; M. Dew

1997-01-01T23:59:59.000Z

332

Fundamental Corrosion Studies in High-Temperature Molten Salt...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Studies in High-Temperature Molten Salt Systems for CSP Applications Savannah River National Laboratory April 15, 2013 | Garcia-Diaz * The overall project approach will combine...

333

Corrosion Studies in High-Temperature Molten Salt Systems for...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Studies in High-Temperature Molten Salt Systems for CSP Applications Savannah River National Laboratory Garcia-Diaz A 1152013:Garcia-Diaz * The overall project approach will...

334

High Temperature Superconductor Cable Concepts for Fusion Magnets.  

E-Print Network (OSTI)

??Three concepts of high temperature superconductor cables carrying kA currents (RACC, CORC and TSTC) are investigated, optimized and evaluated in the scope of their applicability (more)

Barth, Christian

2013-01-01T23:59:59.000Z

335

Solid oxide steam electrolysis for high temperature hydrogen production .  

E-Print Network (OSTI)

??This study has focused on solid oxide electrolyser cells for high temperature steam electrolysis. Solid oxide electrolysis is the reverse operation of solid oxide fuel (more)

Eccleston, Kelcey L.

2007-01-01T23:59:59.000Z

336

Detecting Fractures Using Technology at High Temperatures and...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Fractures Using Technology at High Temperatures and Depths - Geothermal Ultrasonic Fracture Imager (GUFI); 2010 Geothermal Technology Program Peer Review Report Detecting...

337

Detecting Fractures Using Technology at High Temperatures and...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Fractures Using Technology at High Temperatures and Depths - Geothermal Ultrasonic Fracture Imager (GUFI) Presentation Number: 015 Investigator: Patterson, Doug (Baker Hughes...

338

Nanostructured High-Temperature Bulk Thermoelectric Energy Conversion...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

High Temperature Bulk Thermoelectric Energy Conversion for Efficient Waste Heat Recovery Project Overview 2 * Start: October 2011 * End: September 2015 * Percent complete -...

339

Feasibility and Design Studies for a High Temperature Downhole Tool  

Energy.gov (U.S. Department of Energy (DOE))

Project objective: Perform feasibility and design studies for a high temperature downhole tool; which uses nuclear techniques for characterization purposes; using measurements and modeling/simulation.

340

High Temperature, High Voltage Fully Integrated Gate Driver Circuit  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

driver circuit, 5-V on- chip voltage regulator, short-circuit protection, undervoltage lockout, bootstrap capacitor, dead time controller and temperature sensor * 0.8-micron,...

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

High-Temperature Superconductivity Cable Demonstration Projects  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Temperature Temperature Superconductivity Cable Demonstration Projects Superconductivity Power Equipment www.oe.energy.gov Phone: 202-586-1411 Office of Electricity Delivery and Energy Reliability, OE-1 U.S. Department of Energy - 1000 Independence Avenue, SW - Washington, DC 20585. Plugging America Into the Future of Power "A National Effort to Introduce New Technology into the Power Delivery Infrastructure" "In order to meet President Obama's ambitious energy goals, we must modernize the nation's electrical grid to improve the transmission, storage and reliability of clean energy across the country and help to move renewable energy from the places it can be produced to the places it can be used. The Department of Energy is working with industry partners to develop the

342

Method of treating intermetallic alloy hydrogenation/oxidation catalysts for improved impurity poisoning resistance, regeneration and increased activity  

DOE Patents (OSTI)

Alternate, successive high temperature oxidation and reduction treatments, in either order, of intermetallic alloy hydrogenation and intermetallic alloy oxidation catalysts unexpectedly improves the impurity poisoning resistance, regeneration capacity and/or activity of the catalysts. The particular alloy, and the final high temperature treatment given alloy (oxidation or reduction) will be chosen to correspond to the function of the catalyst (oxidation or hydrogenation). 23 figs.

Wright, R.B.

1992-01-14T23:59:59.000Z

343

Sulfur Tolerant Pd/Cu and Pd/Au Alloy Membranes for H2 Separation with High Pressure CO2 for Sequestration  

SciTech Connect

The effect of H{sub 2}S poisoning on Pd, Pd/Cu, and Pd/Au alloy composite membranes prepared by the electroless deposition method on porous Inconel supports was investigated to provide a fundamental understanding of the durability and preparation of sulfur tolerant membranes. X-ray photoelectron spectroscopy (XPS) studies showed that the exposure of pure Pd to 50 ppm H{sub 2}S/H{sub 2} mixtures caused bulk sulfide formation at lower temperatures and surface sulfide formation at higher temperatures. Lower temperatures, longer exposure times, and higher H{sub 2}S concentrations resulted in a higher degree of sulfidation. In a Pd membrane, the bulk sulfide formation caused a drastic irrecoverable H{sub 2} permeance decline and an irreparable loss in selectivity. Pd/Cu and Pd/Au alloy membranes exhibited permeance declines due to surface sulfide formation upon exposure to 50 ppm H{sub 2}S/H{sub 2} gas mixtures. However in contrast to the pure Pd membrane, the permeances of the Pd/Cu and Pd/Au alloy membranes were mostly recovered in pure H{sub 2} and the selectivity of the Pd alloy layers remained essentially intact throughout the characterization in H{sub 2}, He and H{sub 2}S/H{sub 2} mixtures which lasted several thousand hours. The amount of irreversible sulfur poisoning decreased with increasing temperature due to the exothermicity of H{sub 2}S adsorption. Longer exposure times increased the amount of irreversible poisoning of the Pd/Cu membrane but not the Pd/Au membrane. Pd/Au coupon studies of the galvanic displacement method showed that higher Au{sup 3+} concentrations, lower pH values, higher bath temperatures and stirring the bath at a rate of 200 rpm yielded faster displacement rates, more uniform depositions, and a higher Au content within the layers. While 400 C was found to be sufficient to form a Pd/Au alloy on the surface, high temperature X-ray diffraction (HTXRD) studies showed that even after annealing between 500-600 C, the Pd/Cu alloys could have part or all of the surface in the less sulfur resistant {beta} phase.

Yi Hua Ma; Natalie Pomerantz; Chao-Huang Chen

2008-09-30T23:59:59.000Z

344

High Temperature Oxidation Resistance and Surface Electrical...  

NLE Websites -- All DOE Office Websites (Extended Search)

plates with oxidation resistant coatings. Candidate coatings must exhibit chemical and thermal-mechanical stability and high electrical conductivity during long-term...

345

High temperature elemental losses and mineralogical  

E-Print Network (OSTI)

future energy crops. Combustion in biomass fueled boilers,in ash during combustion of biomass fuels is important forC. Combustion characteristics of high alkali biomass. Final

Thy, P.; Jenkins, B. M.; Grundvig, S.; Shiraki, R.; Lesher, C. E.

2006-01-01T23:59:59.000Z

346

Advanced High-Temperature, High-Pressure Transport Reactor Gasification  

SciTech Connect

The U.S. Department of Energy (DOE) National Energy Technology Laboratory Office of Coal and Environmental Systems has as its mission to develop advanced gasification-based technologies for affordable, efficient, zero-emission power generation. These advanced power systems, which are expected to produce near-zero pollutants, are an integral part of DOE's Vision 21 Program. DOE has also been developing advanced gasification systems that lower the capital and operating costs of producing syngas for chemical production. A transport reactor has shown potential to be a low-cost syngas producer compared to other gasification systems since its high-throughput-per-unit cross-sectional area reduces capital costs. This work directly supports the Power Systems Development Facility utilizing the KBR transport reactor located at the Southern Company Services Wilsonville, Alabama, site. Over 2800 hours of operation on 11 different coals ranging from bituminous to lignite along with a petroleum coke has been completed to date in the pilot-scale transport reactor development unit (TRDU) at the Energy & Environmental Research Center (EERC). The EERC has established an extensive database on the operation of these various fuels in both air-blown and oxygen-blown modes utilizing a pilot-scale transport reactor gasifier. This database has been useful in determining the effectiveness of design changes on an advanced transport reactor gasifier and for determining the performance of various feedstocks in a transport reactor. The effects of different fuel types on both gasifier performance and the operation of the hot-gas filter system have been determined. It has been demonstrated that corrected fuel gas heating values ranging from 90 to 130 Btu/scf have been achieved in air-blown mode, while heating values up to 230 Btu/scf on a dry basis have been achieved in oxygen-blown mode. Carbon conversions up to 95% have also been obtained and are highly dependent on the oxygen-coal ratio. Higher-reactivity (low-rank) coals appear to perform better in a transport reactor than the less reactive bituminous coals. Factors that affect TRDU product gas quality appear to be coal type, temperature, and air/coal ratios. Testing with a higher-ash, high-moisture, low-rank coal from the Red Hills Mine of the Mississippi Lignite Mining Company has recently been completed. Testing with the lignite coal generated a fuel gas with acceptable heating value and a high carbon conversion, although some drying of the high-moisture lignite was required before coal-feeding problems were resolved. No ash deposition or bed material agglomeration issues were encountered with this fuel. In order to better understand the coal devolatilization and cracking chemistry occurring in the riser of the transport reactor, gas and solid sampling directly from the riser and the filter outlet has been accomplished. This was done using a baseline Powder River Basin subbituminous coal from the Peabody Energy North Antelope Rochelle Mine near Gillette, Wyoming.

Michael Swanson; Daniel Laudal

2008-03-31T23:59:59.000Z

347

High Permeability Ternary Palladium Alloy Membranes with Improved Sulfur and Halide Tolerances  

SciTech Connect

The project team consisting of Southwest Research Institute{reg_sign} (SwRI{reg_sign}), Georgia Institute of Technology (GT), the Colorado School of Mines (CSM), TDA Research, and IdaTech LLC was focused on developing a robust, poison-tolerant, hydrogen selective free standing membrane to produce clean hydrogen. The project completed on schedule and on budget with SwRI, GT, CSM, TDA and IdaTech all operating independently and concurrently. GT has developed a robust platform for performing extensive DFT calculations for H in bulk palladium (Pd), binary alloys, and ternary alloys of Pd. Binary alloys investigated included Pd96M4 where M = Li, Na, Mg, Al, Si, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Y, Zr, Nb, Mo, Tc, Ru, Rh, Ag, Cd, In, Sn, Sb, Te, Hf, Ta, W, Re, Os, Ir, Pt, Au, Tl, Pb, Bi, Ce, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu. They have also performed a series of calculations on Pd{sub 70}Cu{sub 26}Ag{sub 4}, Pd{sub 70}Cu{sub 26}Au{sub 4}, Pd{sub 70}Cu{sub 26}Ni{sub 4}, Pd{sub 70}Cu{sub 26}Pt{sub 4}, and Pd{sub 70}Cu{sub 26}Y{sub 4}. SwRI deposited and released over 160 foils of binary and ternary Pd alloys. There was considerable work on characterizing and improving the durability of the deposited foils using new alloy compositions, post annealing and ion bombardment. The 10 and 25 {micro}m thick films were sent to CSM, TDA and IdaTech for characterization and permeation testing. CSM conducted over 60 pure gas permeation tests with SwRI binary and ternary alloy membranes. To date the PdAu and PdAuPt membranes have exhibited the best performance at temperatures in the range of 423-773 C and their performance correlates well with the predictions from GT. TDA completed testing under the Department of Energy (DOE) WGS conditions on over 16 membranes. Of particular interest are the PdAuPt alloys that exhibited only a 20% drop in flux when sulfur was added to the gas mixture and the flux was completely recovered when the sulfur flow was stopped. IdaTech tested binary and ternary membranes on a simulated flue gas stream and experienced significant difficulty in mounting and testing the sputter deposited membranes. IdaTech was able to successfully test PdAu and PdAuPt membranes and saw similar sulfur tolerance to what TDA found. The Program met all the deliverables on schedule and on budget. Over ten presentations at national and international conferences were made, four papers were published (two in progress) in technical journals, and three students (2 at GT and 1 at CSM) completed their doctorates using results generated during the course of the program. The three major findings of program were; (1) the DFT modeling was verified as a predictive tool for the permeability of Pd based ternary alloys, (2) while magnetron sputtering is useful in precisely fabricating binary and ternary alloys, the mechanical durability of membranes fabricated using this technique are inferior compared to cold rolled membranes and this preparation method is currently not ready for industrial environments, (3) based on both modeling and experimental verification in pure gas and mixed gas environments PdAu and PdAuPt alloys were found to have the combination of the highest permeability and tolerance to sulfur.

K. Coulter

2010-12-31T23:59:59.000Z

348

Thermodynamics and Transport Phenomena in High Temperature Steam Electrolysis Cells  

SciTech Connect

Hydrogen can be produced from water splitting with relatively high efficiency using high temperature electrolysis. This technology makes use of solid-oxide cells, running in the electrolysis mode to produce hydrogen from steam, while consuming electricity and high temperature process heat. The overall thermal-to-hydrogen efficiency for high temperature electrolysis can be as high as 50%, which is about double the overall efficiency of conventional low-temperature electrolysis. Current large-scale hydrogen production is based almost exclusively on steam reforming of methane, a method that consumes a precious fossil fuel while emitting carbon dioxide to the atmosphere. An overview of high temperature electrolysis technology will be presented, including basic thermodynamics, experimental methods, heat and mass transfer phenomena, and computational fluid dynamics modeling.

James E. O'Brien

2012-03-01T23:59:59.000Z

349

A simple, inexpensive device for measuring the critical temperature of a high-temperature superconductor  

Science Journals Connector (OSTI)

A simple, inexpensive device for measuring the critical temperature of a high-temperature superconductor ... This note describes a simple, inexpensive method of measuring the temperature at which the Meissner effect exists in a disk of YBa2Cu3O7-x. ...

David B. Green; Dijon Douphner; Bennett Hutchinson

1992-01-01T23:59:59.000Z

350

Temperature dependence of the lower critical field and strong pinning in high-temperature superconductors  

Science Journals Connector (OSTI)

We show, within the framework of the Ginzburg-Landau theory, that both the conventional and the anomalous temperature dependence of the lower critical field observed in high-temperature superconductors may result from the flux penetration through a set of separated microdefects. Microdefects modeled by normal layers with proximity-induced superconductivity can produce drastic enhancement of the lower critical field at low temperatures and can provide strong-pinning centers. The pinning interaction between an isolated vortex and the normal layer is primarily magnetic at high temperatures. At low temperatures, magnetic interaction is reduced, due to the increase of the normal-layer coherence length.

Dragomir Davidovi? and Ljiljana Dobrosavljevi?-Gruji?

1991-02-01T23:59:59.000Z

351

Advancing the technology base for high-temperature membranes  

SciTech Connect

This is the final report of a two-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). This project addresses the major issues confronting the implementation of high-temperature membranes for separations and catalysis. We are pursuing high-temperature membrane systems that can have a large impact for DOE and be industrially relevant. A major obstacle for increased use of membranes is that most applications require the membrane material to withstand temperatures above those acceptable for polymer-based systems. Advances made by this project have helped industry and DOE move toward high-temperature membrane applications to improve overall energy efficiency.

Dye, R.C.; Birdsell, S.A.; Snow, R.C. [and others

1997-10-01T23:59:59.000Z

352

POWER-TO-GAS PROCESS WITH HIGH TEMPERATURE ELECTROLYSIS  

E-Print Network (OSTI)

POWER-TO-GAS PROCESS WITH HIGH TEMPERATURE ELECTROLYSIS AND CO2 METHANATION NOVEMBER 19th 2013 IRES. Energy background 2. Power-to-Substitute Natural Gas process with high temperature steam electrolysis Gas-to-heat Gas-to-mobility Gas-to-power Excess Production = Consumption Distribution and storing

Paris-Sud XI, Université de

353

High Temperature Evaluation of Tantalum Capacitors - Test 1  

DOE Data Explorer (OSTI)

Tantalum capacitors can provide much higher capacitance at high-temperatures than the ceramic capacitors. This study evaluates selected tantalum capacitors at high temperatures to determine their suitability for you in geothermal field. This data set contains results of the first test where three different types of capacitors were evaluated at 260C.

Grzegorz Cieslewski

354

High Temperature Evaluation of Tantalum Capacitors - Test 1  

SciTech Connect

Tantalum capacitors can provide much higher capacitance at high-temperatures than the ceramic capacitors. This study evaluates selected tantalum capacitors at high temperatures to determine their suitability for you in geothermal field. This data set contains results of the first test where three different types of capacitors were evaluated at 260C.

Cieslewski, Grzegorz

2014-09-28T23:59:59.000Z

355

Low-temperature stress corrosion cracking of alloy 601 in thiosulfate and chloride solutions  

SciTech Connect

The stress corrosion cracking (SCC) susceptibility of unsensitized and sensitized alloy 601 (UNS N06601) was studied in sodium thiosulfate (Na{sub 2}S{sub 2}O{sub 3}) and sodium chloride (NaCl) solutions using slow strain rate testing (SSRT). Specimens were tested in the as-received condition (mill-annealed) after solution annealing at 1,050 C for 30 min and after solution annealing and sensitizing for 2, 5, 24, or 772 h at 700 for 30 min. Environments included Na{sub 2}S{sub 2}O{sub 3} and NaCl at different concentrations ranging from 0.01 M to 1.0 M at 25 C and 95 C. Double-loop electrochemical potentiokinetic reactivation (DL-EPR) tests in 0.01 M sulfuric acid (H{sub 2}SO{sub 4}) + 0.001 M potassium thiocyanate (KSCN) and immersion tests in boiling 25% nitric acid (HNO{sub 3}) solution were used to evaluate the effect of heat treatment on the degree of sensitization (DOS) and on intergranular corrosion (IGC) of alloy 601. In all environments tested, the unsensitized alloy was immune to SCC and showed only ductile failure. The alloy sensitized for 24 h showed the highest degree of susceptibility to SCC in 0.1 M Na{sub 2}S{sub 2}O{sub 3}, followed by the alloys sensitized for 72, 5, and 2 h, followed by the as-received and solution-annealed alloys. Except for the other times of sensitization, ductility for the specimen sensitized for 24 h was always lower at 25 C than at 95 C. The modified Huey and the DL-EPR tests also revealed the highest susceptibility to IGC for specimens sensitized for 24 h. This susceptibility did not change as Na{sub 2}S{sub 2}O{sub 3} concentration decreased from 0.5 M to 0.01 M, but ductility decreased as solution pH was increased from 3 to 7. Addition of NaCl to Na{sub 2}S{sub 2}O{sub 3} did not have a clear effect on susceptibility to SCC of the sensitized alloy since ductility sometimes increased but at other times decreased.

Gonzalez-Rodriguez, J.G. [U.A.E.M., Cuernavaca (Mexico). Facultad de Ciencias Quimicas e Ingenieria; Salinas-Bravo, V.M. [I.I.E., Cuernavaca (Mexico); Martinez-Villafane, A. [CIMAV, Chihuahua (Mexico)

1999-01-01T23:59:59.000Z

356

Gas Viscosity at High Pressure and High Temperature  

E-Print Network (OSTI)

. Although viscosity of some pure components such as methane, ethane, propane, butane, nitrogen, carbon dioxide and binary mixtures of these components at low-intermediate pressure and temperature had been studied intensively and been understood thoroughly...

Ling, Kegang

2012-02-14T23:59:59.000Z

357

An unusual isotope effect in a high-transition-temperature superconductor  

E-Print Network (OSTI)

coupling in high-temperature superconductors. Nature 412,Properties of High Temperature Superconductors IV (ed.in a high-transition-temperature superconductor G. -H. Gweon

2004-01-01T23:59:59.000Z

358

To Crack or Not to Crack: Strain in High Temperature Superconductors  

E-Print Network (OSTI)

Strain in High Temperature Superconductors Arno GodekeCrack: Strain in High Temperature Superconductors MotivationCrack: Strain in High Temperature Superconductors How do Nb

Godeke, Arno

2008-01-01T23:59:59.000Z

359

X-ray diffuse scattering studies of the local structural inhomogeneities in high temperature superconductors  

E-Print Network (OSTI)

in high temperature superconductors A dissertation submittedChemistry of High-Temperature Superconductors. Word Scienti?work on the high temperature superconductors, one of the

Liu, Xuerong

2009-01-01T23:59:59.000Z

360

Temperature dependence of the gaps of high-temperature superconductors in the Fermi-arc region  

Science Journals Connector (OSTI)

It is shown how in a high-temperature superconductor, the length of the Fermi arc can be obtained from the doping dependence of the pseudogap and the superconducting gap. In the momentum region spanned by the Fermi arc, the pseudogap temperature dependence follows that of the superconducting gap. The close interconnection of the two gaps suggests that they are both an essential part of the high-temperature superconductivity.

S. Hfner and F. Mller

2008-07-23T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

HIGH TEMPERATURE ELECTROLYZER MATERIALS PROJECT GOAL  

E-Print Network (OSTI)

with compatible electrodes to develop reversible solid oxide fuel cells for low-cost, high efficient power and solid oxide fuel cells. Notable reversible fuel cell achievements have been demonstrated by Proton of traditional oxide ion conductor-based solid oxide fuel cell (SOFC) materials. [2 ,3 ,4 ] Significantly

Mease, Kenneth D.

362

"Exploring damage management of high performance metallic alloys in critical  

E-Print Network (OSTI)

. of Materials Science & Engineering University of Virginia Charlottesville, VA 434.982.5782 High Performance in aerospace, transportation infrastructure, military, power generation, and petrochemical technologies. Our promotes a variety of cracking modes in metals. The opportunity exists to implement advanced prognosis

Acton, Scott

363

Effects of alloying elements on microstructure, hardness, and fracture toughness of centrifugally cast high-speed steel rolls  

Science Journals Connector (OSTI)

A study was made of the effects of alloying elements on the microstructure, hardness, and fracture toughness of centrifugally cast high-speed steel (HSS) rolls. Particular emphasis was placed on the role of ha...

Chang Kyu Kim; Yong Chan Kim; Jong Il Park

2005-01-01T23:59:59.000Z

364

The Stress Corrosion Crack Growth Rate of Alloy 600 Heat Affected Zones Exposed to High Purity Water  

SciTech Connect

Grain boundary chromium carbides improve the resistance of nickel based alloys to primary water stress corrosion cracking (PWSCC). However, in weld heat affected zones (HAZ's), thermal cycles from fusion welding can solutionize beneficial grain boundary carbides, produce locally high residual stresses and strains, and promote PWSCC. The present research investigates the crack growth rate of an A600 HAZ as a function of test temperature. The A600 HAZ was fabricated by building up a gas-tungsten-arc-weld deposit of EN82H filler metal onto a mill-annealed A600 plate. Fracture mechanics based, stress corrosion crack growth rate testing was performed in high purity water between 600 F and 680 F at an initial stress intensity factor of 40 ksi {radical}in and at a constant electrochemical potential. The HAZ samples exhibited significant SCC, entirely within the HAZ at all temperatures tested. While the HAZ samples showed the same temperature dependence for SCC as the base material (HAZ: 29.8 {+-} 11.2{sub 95%} kcal/mol vs A600 Base: 35.3 {+-} 2.58{sub 95%} kcal/mol), the crack growth rates were {approx} 30X faster than the A600 base material tested at the same conditions. The increased crack growth rates of the HAZ is attributed to fewer intergranular chromium rich carbides and to increased plastic strain in the HAZ as compared to the unaffected base material.

George A. Young; Nathan Lewis

2003-04-05T23:59:59.000Z

365

Apparatus for accurately measuring high temperatures  

DOE Patents (OSTI)

The present invention is a thermometer used for measuring furnace temperaes in the range of about 1800.degree. to 2700.degree. C. The thermometer comprises a broadband multicolor thermal radiation sensor positioned to be in optical alignment with the end of a blackbody sight tube extending into the furnace. A valve-shutter arrangement is positioned between the radiation sensor and the sight tube and a chamber for containing a charge of high pressure gas is positioned between the valve-shutter arrangement and the radiation sensor. A momentary opening of the valve shutter arrangement allows a pulse of the high gas to purge the sight tube of air-borne thermal radiation contaminants which permits the radiation sensor to accurately measure the thermal radiation emanating from the end of the sight tube.

Smith, Douglas D. (Knoxville, TN)

1985-01-01T23:59:59.000Z

366

Optimization of High Temperature Hoop Creep Response in ODS-Fe3Al Tubes  

SciTech Connect

Oxide dispersion strengthened (ODS) Fe3Al alloys are currently being developed for heat-exchanger tubes for eventual use at operating temperatures of up to 1100 C in the power generation industry. The development challenges include (a) efforts to produce thin walled ODS-Fe3Al tubes, employing powder extrusion methodologies, with (b) adequate increased strength for service at operating temperatures to (c) mitigate creep failures by enhancing the as-processed grain size. A detailed and comprehensive research and development methodology is prescribed to produce ODS-Fe3Al thin walled tubes. Current single step extrusion consolidation methodologies typically yield 8ft. lengths of 1-3/8 inch diameter, 1/8 inch wall thickness ODS-Fe3Al tubes. The process parameters for such consolidation methodologies have been prescribed and evaluated as being routinely reproducible. Recrystallization treatments at 1200 C produce elongated grains (with their long axis parallel to the extrusion axis), typically 200-2000 {micro}m in diameter, and several millimeters long. The dispersion distribution is unaltered on a micro scale by recrystallization, but the high aspect ratio grain shape typically obtained limits grain spacing and consequently the hoop creep response. Improving hoop creep in ODS-alloys requires an understanding and manipulating the factors that control grain alignment and recrystallization behavior. Current efforts are focused on examining the processing dependent longitudinal vs. transverse creep anisotropy, and exploring post-extrusion methods to improve hoop creep response in ODS-Fe3Al alloy tubes. In this report we examine the mechanisms of hoop creep failure and describe our efforts to improve creep performance via variations in thermal-mechanical treatments.

Kad, B.K.; Heatherington, J.H.; McKamey, C.; Wright, I.; Sikka, V.; Judkins, R.

2003-04-22T23:59:59.000Z

367

DOE Hydrogen Analysis Repository: High Temperature Electrolysis (HTE)  

NLE Websites -- All DOE Office Websites (Extended Search)

High Temperature Electrolysis (HTE) High Temperature Electrolysis (HTE) Project Summary Full Title: High Temperature Electrolysis (HTE) Project ID: 159 Principal Investigator: Steve Herring Brief Description: A three-dimensional computational fluid dynamics (CFD) model was created to model high-temperature steam electrolysis in a planar solid oxide electrolysis cell (SOEC). A solid-oxide fuel cell model adds the electrochemical reactions and loss mechanisms and computation of the electric field throughout the cell. Keywords: Solid oxide fuel cell; solid oxide elctrolysis cell; nuclear; model Purpose Assess the performance of solid-oxide cells operating in the steam electrolysis mode for hydrogen production over a temperature range of 800 to 900ºC. Performer Principal Investigator: Steve Herring

368

High-Pressure and High-Temperature Powder Diffraction  

Science Journals Connector (OSTI)

...pressure and varies the motor speed is often used...12.398 is from the quantum mechanical relationship...detectors could in the future reduce data collection...kind of studies in the future. Other more fundamental...addressed in the near future. Temperature gradients...

Yingwei Fei; Yanbin Wang

369

A diamond-window XAFS cell for studies of high-temperature, high-pressure aqueous solutions  

SciTech Connect

We describe a method to collect x-ray absorption fine structure (XAFS) spectra of ions in a supercritical water solvent. Supercritical water (SCW), at temperatures above water{close_quote}s critical point of 374{degree}C, is an interesting solvent for chemical reactions and hazardous waste destruction due to the high solubility of organics and the aggressive oxidizing environment. XAFS may provide a better understanding of the solvent environment in SCW. The XAFS cell used in these studies was composed of a block of high-nickel alloy, Hastelloy C-22, containing two windows for transmission of the x-ray beam and a single optical view window. All internal wetted surfaces were platinum plated. The maximum operating conditions for this design were 500{degree}C and 700 bar. The x-ray transmission windows consisted of CVD (chemical vapor deposition) diamond windows (3 mm diameter {times}0.5 mm thick) that were brazed to the tip of a standard 1/4-in. high-pressure, coned-shape fitting. Spectra are reported for strontium and rubidium ions in a supercritical water solvent. This cell design could be used for a variety of other solvent systems at high temperatures and high pressures. {copyright} {ital 1996 American Institute of Physics.}

Fulton, J.L.; Pfund, D.M. [Chemical Sciences Department, Pacific Northwest Laboratory, Richland, WA 99352 (United States)] [Chemical Sciences Department, Pacific Northwest Laboratory, Richland, WA 99352 (United States); Ma, Y. [Brookhaven National Laboratory, Bldg 510 E, Upton, NY 11973 (United States)] [Brookhaven National Laboratory, Bldg 510 E, Upton, NY 11973 (United States)

1996-09-01T23:59:59.000Z

370

4 - Bulk high temperature superconductor (HTS) materials  

Science Journals Connector (OSTI)

Abstract: This chapter concentrates on bulk materials. A bulk superconductor is one in which the superconductor has been formed into a lump, usually cylindrically shaped, but can also be hexagonal, rectangular or even square. Bulk superconductors are typically 35cm across and 1cm thick. They have many uses but the principal one is as extremely compact high-field permanent magnets in superconducting machines. A 2.6cm (RE)BCO puck has been magnetised to 17.24 T: this is an order of magnitude greater than the flux density available from a conventional permanent magnet. This chapter describes the materials, manufacturing process, magnetisation process and some examples of machines.

T. Coombs

2012-01-01T23:59:59.000Z

371

Thermomagnetic phenomena in the mixed state of high temperature superconductors  

SciTech Connect

Galvano- and thermomagnetic-phenomena in high temperature superconductors, based on kinetic coefficients, are discussed, along with a connection between the electric field and the heat flow in superconductor mixed state. The relationship that determines the transport coefficients of high temperature superconductors in the mixed state based on Seebeck and Nernst effects is developed. It is shown that this relationship is true for a whole transition region of the resistive mixed state of a superconductor. Peltier, Ettingshausen and Righi-Leduc effects associated with heat conductivity as related to high temperature superconductors are also addressed.

Meilikhov, E.Z.

1995-04-01T23:59:59.000Z

372

High temperature alkali corrosion of ceramics in coal gas  

SciTech Connect

High temperature alkali corrosion has been known to cause premature failure of ceramic components used in advanced high temperature coal combustion systems such as coal gasification and clean-up, coal fired gas turbines, and high efficiency heat engines. The objective of this research is to systematically evaluate the alkali corrosion resistance of the most commonly used structural ceramics including silicon carbide, silicon nitride, cordierite, mullite, alumina, aluminum titanate, zirconia, and fireclay glass. The study consists of identification of the alkali reaction products (phase equilibria) and the kinetics of the alkali reactions as a function of temperature and time.

Pickrell, G.R.; Sun, T.; Brown, J.J.

1992-05-27T23:59:59.000Z

373

Method for Synthesizing Extremeley High Temperature Melting Materials  

DOE Patents (OSTI)

The invention relates to a method of synthesizing high-temperature melting materials. More specifically the invention relates to a containerless method of synthesizing very high temperature melting materials such as borides, carbides and transition-metal, lanthanide and actinide oxides, using an Aerodynamic Levitator and a laser. The object of the invention is to provide a method for synthesizing extremely high-temperature melting materials that are otherwise difficult to produce, without the use of containers, allowing the manipulation of the phase (amorphous/crystalline/metastable) and permitting changes of the environment such as different gaseous compositions.

Saboungi, Marie-Louise and Glorieux, Benoit

2005-11-22T23:59:59.000Z

374

Method For Synthesizing Extremely High-Temperature Melting Materials  

DOE Patents (OSTI)

The invention relates to a method of synthesizing high-temperature melting materials. More specifically the invention relates to a containerless method of synthesizing very high temperature melting materials such as borides, carbides and transition-metal, lanthanide and actinide oxides, using an Aerodynamic Levitator and a laser. The object of the invention is to provide a method for synthesizing extremely high-temperature melting materials that are otherwise difficult to produce, without the use of containers, allowing the manipulation of the phase (amorphous/crystalline/metastable) and permitting changes of the environment such as different gaseous compositions.

Saboungi, Marie-Louise (Chicago, IL); Glorieux, Benoit (Perpignan, FR)

2005-11-22T23:59:59.000Z

375

Method for synthesizing extremely high-temperature melting materials  

SciTech Connect

The invention relates to a method of synthesizing high-temperature melting materials. More specifically the invention relates to a containerless method of synthesizing very high temperature melting materials such as carbides and transition-metal, lanthanide and actinide oxides, using an aerodynamic levitator and a laser. The object of the invention is to provide a method for synthesizing extremely high-temperature melting materials that are otherwise difficult to produce, without the use of containers, allowing the manipulation of the phase (amorphous/crystalline/metastable) and permitting changes of the environment such as different gaseous compositions.

Saboungi, Marie-Louise (Chicago, IL); Glorieux, Benoit (Perpignan, FR)

2007-11-06T23:59:59.000Z

376

Thermodynamics of high-temperature, high-pressure water electrolysis  

Science Journals Connector (OSTI)

Abstract We report on a thermodynamic analysis for water electrolysis from normal conditions (P=0.1MPa, T=298K) up to heretofore unaddressed temperatures of 1000K and pressures of 100MPa. Thermoneutral and reversible potentials are determined using equations-of-state published by the International Association for the Properties of Water and Steam and the National Institute of Standards and Technology. The need for using accurate property models at these elevated temperatures and pressures is exemplified by contrasting results with those obtained via ideal assumptions. The utility of our results is demonstrated by their application in an analysis comparing pressurized electrolysis versus mechanical gas compression. Within the limits of our analysis, pressurized electrolysis demonstrates lower energy requirements albeit with electrical work composing a greater proportion of the total energy input.

Devin Todd; Maximilian Schwager; Walter Mrida

2014-01-01T23:59:59.000Z

377

Experimental Analysis of Water Based Drilling Fluid Aging Processes at High Temperature and High Pressure Conditions  

E-Print Network (OSTI)

! ! EXPERIMENTAL ANALYSIS OF WATER BASED DRILLING FLUID AGING PROCESSES AT HIGH TEMPERATURE AND HIGH PRESSURE CONDITIONS A Thesis by BRANDON SCOTT ZIGMOND Submitted to the Office of Graduate Studies of Texas A&M University... Temperature and High Pressure Conditions Copyright 2012 Brandon Scott Zigmond ! ! EXPERIMENTAL ANALYSIS OF WATER BASED DRILLING FLUID AGING PROCESSES AT HIGH TEMPERATURE AND HIGH PRESSURE CONDITIONS A Thesis by BRANDON SCOTT ZIGMOND Submitted...

Zigmond, Brandon

2012-10-19T23:59:59.000Z

378

Liquid Fuel Production from Biomass via High Temperature Steam Electrolysis  

SciTech Connect

A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to heat steam for the hydrogen production via the high temperature steam electrolysis process. Hydrogen from electrolysis allows a high utilization of the biomass carbon for syngas production. Oxygen produced form the electrolysis process is used to control the oxidation rate in the oxygen-fed biomass gasifier. Based on the gasifier temperature, 94% to 95% of the carbon in the biomass becomes carbon monoxide in the syngas (carbon monoxide and hydrogen). Assuming the thermal efficiency of the power cycle for electricity generation is 50%, (as expected from GEN IV nuclear reactors), the syngas production efficiency ranges from 70% to 73% as the gasifier temperature decreases from 1900 K to 1500 K. Parametric studies of system pressure, biomass moisture content and low temperature alkaline electrolysis are also presented.

Grant L. Hawkes; Michael G. McKellar

2009-11-01T23:59:59.000Z

379

Estimation of Atmospheric Corrosion of High-Strength, Low-Alloy Steels  

E-Print Network (OSTI)

the corrosion resistance of low-alloy weathering steels from chemical composition data and from actual

380

Microwave characterization of high-temperature superconductors  

SciTech Connect

Thick (10-15 {mu}m) Tl-Ba-Ca-Cu-O films have been deposited onto yttria-stabilized zirconia and Ag substrates by d.c. magnetron sputtering techniques. Direct deposition onto 1'' diameter yttria-stabilized zirconia yields films with typical 22 GHz surface resistance (R{sub s}) values of 5.2 {plus minus} 2 m{Omega} and 52 {plus minus} 2 m{Omega} at 10 K and 77 K, respectively. For comparison, R{sub s} of Cu at this same frequency is 10 m{Omega} at 4 K and 22 m{Omega} at 77 K. Tl-Ba-Ca-Cu-O films have also been deposited onto 1'' diameter Ag substrates using Au/Cu, Cu, and BaF{sub 2} buffer layers. The lowest R{sub s} values were obtained on films with a BaF{sub 2} buffer layer, typical values being 7.8 {plus minus} 2 m{Omega} and 30.6 {plus minus} 2 m{Omega} (measured at 22 GHz) at 10 K and 77 K, respectively. Larger films (1.5'' diameter) with similar R{sub s} values were prepared using this same technique, demonstrating that the fabrication process can be scaled to larger surface areas. These films are promising for radiofrequency cavity applications because they are thick (50-75 times the London penetration depth), have relatively large surface areas, are fabricated on metallic substrates, and have R{sub s} values that are competitive with Cu at 77 K and are lower than Cu at 4 K. Because they are polycrystalline and unoriented, it is anticipated that their R{sub s} values can be lowered by improving the processing technique. High-quality films of YBa{sub 2}Cu{sub 3}O{sub 7} have been electron-beam deposited onto 1'' LaGaO{sub 3} and 1.5'' LaAlO{sub 3} substrates. The 1'' sample is characterized by R{sub s} values of 0.2 {plus minus} 0.1 m{Omega} at 4 K and 18.6 {plus minus} 2 m{Omega} at 77 K. The 4-K value is only 2-4 times higher than Nb. The 1.5'' sample has R{sub s} values (measured at 18 GHz) of 0.93 {plus minus} 2 m{Omega} and 71 {plus minus} 3 m{Omega} at 10 K and 77 K, respectively. 18 refs., 8 figs.

Cooke, D.W.; Gray, E.R.; Arendt, P.N.; Beery, J.G.; Bennett, B.L.; Brown, D.R.; Houlton, R.J.; Jahan, M.S.; Klapetzky, A.J.; Maez, M.A.; Raistrick, I.D.; Reeves, G.A.; Rusnak, B.

1989-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Development of Brazing Technology for Use in High- Temperature Gas Separation Equipment  

SciTech Connect

The development of high-temperature electrochemical devices such as oxygen and hydrogen separators, fuel gas reformers, solid oxide fuel cells, and chemical sensors is part of a rapidly expanding segment of the solid state technology market. These devices employ an ionic conducting ceramic as the active membrane that establishes the electrochemical potential of the device, either under voltage (i.e. to carry out gas separation) or under chemical gradient (to develop an electrical potential and thereby generate electrical power). Because the device operates under an ionic gradient that develops across the electrolyte, hermiticity across this layer is paramount. That is, not only must this thin ceramic membrane be dense with no interconnected porosity, but it must be connected to the rest of the device, typically constructed from a heat resistant alloy, with a high-temperature, gas-tight seal. A significant engineering challenge in fabricating these devices is how to effectively join the thin electrochemically active membrane to the metallic body of the device such that the resulting seal is hermetic, rugged, and stable during continuous high temperature operation. Active metal brazing is the typical method of joining ceramic and metal engineering components. It employs a braze alloy that contains one or more reactive elements, often titanium, which will chemically reduce the ceramic faying surface and greatly improve its wetting behavior and adherence with the braze. However, recent studies of these brazes for potential use in fabricating high-temperature electrochemical devices revealed problems with interfacial oxidation and subsequent joint failure [1,2]. Specifically, it was found that the introduction of the ceramic electrolyte and/or heat resistant metal substrate dramatically affects the inherent oxidation behavior of the braze, often in a deleterious manner. These conclusions pointed to the need for an oxidation resistant, high-temperature ceramic-to-metal braze and consequently lead to the development of the novel reactive air brazing (RAB) concept. The goal in RAB is to reactively modify one or both oxide faying surfaces with an oxide compound dissolved in a molten noble metal alloy such that the newly formed surface is readily wetted by the remaining liquid filler material. In many respects, this concept is similar to active metal brazing, except that joining can be conducted in air and the final joint will be resistant to oxidation at high temperature. Potentially, there are a number of metal oxide-noble metal systems that can be considered for RAB, including Ag-CuO, Ag-V2O5, and Pt-Nb2O5. Our current interest is in determining whether the Ag-CuO system is suitable for air brazing functional ceramic-to-metal joints such as those needed in practical electrochemical devices. In a series of studies, the wetting behavior of the Ag-CuO braze was investigated with respect to a number of potential hydrogen separation, oxygen separation, and fuel cell electrolyte membrane materials and heat resistant metal systems, including: alumina, (La0.6Sr0.4)(Co0.2Fe0.8)O3, (La0.8Sr0.2)FeO3, YSZ, fecralloy, and Crofer-22APU. Selected findings from these studies as well as from our work on joint strength and durability during high-temperature exposure testing will be discussed.

Weil, K.S.; Hardy, J.S.; Kim, J.Y.

2003-04-23T23:59:59.000Z

382

FATIGUE AND FRACTURE BEHAVIOR OF HIGH TEMPERATURE MATERIALS  

E-Print Network (OSTI)

of damagetolerance in Ti3SiC,; (above the "ductile-brittle" transition temperature), where in fact, the plastic behavior in general is unusual for carbides and significant high-temperature deformation and damage are first is believed to be due to its layered structure and the metallic apparent. Of the two

Ritchie, Robert

383

Temperature evolution of the spectral peak in high-temperature superconductors  

Science Journals Connector (OSTI)

Recent photoemission data in the high-temperature cuprate superconductor Bi2212 have been interpreted in terms of a sharp spectral peak with a temperature-independent lifetime, whose weight strongly decreases upon heating. By a detailed analysis of the data, we are able to extract the temperature dependence of the electron self-energy, and demonstrate that this interpretation is misleading. Rather, the spectral peak loses its integrity above Tc due to a large reduction in the electron lifetime.

M. R. Norman; A. Kaminski; J. Mesot; J. C. Campuzano

2001-03-22T23:59:59.000Z

384

An experimental investigation of high temperature, high pressure paper drying  

E-Print Network (OSTI)

CONCLUSIONS RECOMMENDATIONS 50 51 REFERENCES APPENDIX A EXPERIMENTAL DATA 52 54 VITA 105 vail LIST OF FIGURES Page Fig. 1 Schematic of test facility 13 Fig. 2 Comparison of Texas A&M drying facility operating ranges to other drying processes... of number of drying passes for drying temperatures of 93, 149, and 204 'C (200, 300, and 400 'F), a contact pressure of 1. 4 MPa (200 psi), a basis weight of 25 g/m' (0. 005 lb/ft'), and contact times between 20 to 180 msec with same side drying...

Patel, Kamal Raoji

2012-06-07T23:59:59.000Z

385

Temperature variations in the flux of high-energy muons  

Science Journals Connector (OSTI)

The flux of high-energy muons (threshold energy, 220 GeV) as a function of ... the correlation coefficient between the counting rate of muons and the temperature of the atmosphere at...

M. G. Kostyuk; V. B. Petkov

2011-06-01T23:59:59.000Z

386

High Temperature Superconducting Racetrack Coils for Electric Motor Applications  

Science Journals Connector (OSTI)

American Superconductor Corporation (ASC) has designed and fabricated racetrack-shaped field coils from PbBSSCO-2223 high temperature superconducting (HTS) wire for a 125 HP, four-pole motor currently being devel...

J. P. Voccio; C. B. Prum; M. J. Navarro

1997-01-01T23:59:59.000Z

387

Multidisciplinary University Research Initiative: High Operating Temperature Fluids  

Energy.gov (U.S. Department of Energy (DOE))

In August 2012, DOE announced two awards under the Multidisciplinary University Research Initiative (MURI) to develop high-operating temperature heat-transfer fluids for concentrating solar power (CSP) applications, managed by the SunShot Initiative.

388

High Temperature Fuel Cell (Phosphoric Acid) Manufacturing R...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Fuel Cell (Phosphoric Acid) Manufacturing R&D High Temperature Fuel Cell (Phosphoric Acid) Manufacturing R&D Presented at the NREL Hydrogen and Fuel Cell Manufacturing R&D Workshop...

389

Structural Integrity Assessment of Very High Temperature Nuclear...  

NLE Websites -- All DOE Office Websites (Extended Search)

Structural Integrity Assessment of Very High Temperature Nuclear Reactor Core Components Oct 20 2014 09:00 AM - 10:00 AM Gyanendar Singh, The University of Minnesota, Minneapolis...

390

Copper Aluminate as a potential material for high temperature...  

NLE Websites -- All DOE Office Websites (Extended Search)

Copper Aluminate as a potential material for high temperature thermoelectric power generation Home Author: D. T. Morelli, E. D. Case, B. D. Hall, S. Wang Year: 2008 Abstract: URL:...

391

18th Topical Conference High-Temperature Plasma Diagnostics ...  

NLE Websites -- All DOE Office Websites (Extended Search)

May 16, 2010, 9:00am to May 20, 2010, 5:00pm Conference Wildwood, New Jersey 18th Topical Conference High-Temperature Plasma Diagnostics (HTPD) The 18th Topical Conference on...

392

Electronic properties of doped Mott insulators and high temperature superconductors  

E-Print Network (OSTI)

High-temperature superconducting cuprates, which are the quintessential example of a strongly correlated system and the most extensively studied materials after semiconductors, spurred the development in the fields of ...

Ribeiro, Tiago Castro

2005-01-01T23:59:59.000Z

393

Cryocooler Applications for High-Temperature Superconductor Magnetic Bearings  

Science Journals Connector (OSTI)

The efficiency and stability of rotational magnetic suspension systems are enhanced by the use of high-temperature superconductor (HTS) magnetic bearings. Fundamental aspects of ... aspects to be considered are i...

R. C. Niemann; J. R. Hull

2002-01-01T23:59:59.000Z

394

Growth of high-temperature superconductor crystals from flux  

Science Journals Connector (OSTI)

Crystallization of high-temperature superconductors was studied in La-Sr-Cu-O,...2Cu3O6.5+x were obtained by spontaneous crystallization from homogeneous nonstoichiometric melts enriched in bariu...

L N Demianets; A B Bykov; O K Melnikov; S M Stishov

1991-04-01T23:59:59.000Z

395

Engineering Design of A High-Temperature Superconductor Current Lead  

Science Journals Connector (OSTI)

As part of the U.S. Department of Energys Superconductivity Pilot Center Program, Argonne National Laboratory and Superconductivity, Inc., are developing high-temperature superconductor (HTS) current leads suita...

R. C. Niemann; Y. S. Cha; J. R. Hull; M. A. Daugherty; W. E. Buckles

1994-01-01T23:59:59.000Z

396

Experimental demonstration of vortex pancake in high temperature superconductor  

Science Journals Connector (OSTI)

In order to demonstrate the existence of the vortex pancake in high temperature superconductor experimentally, a configuration in which the current...E-j relation obtained with this electrodes spatial configurati...

Wei-xian Wang; Yu-heng Zhang

2006-09-01T23:59:59.000Z

397

High-temperature superconductor applications development at Argonne National Laboratory  

SciTech Connect

Developments at Argonne National Laboratory of near and intermediate term applications using high-temperature superconductors are discussed. Near-term applications of liquid-nitrogen depth sensors, current leads, and magnetic bearings are discussed in detail.

Hull, J.R.; Poeppel, R.B.

1992-02-09T23:59:59.000Z

398

High temperature solid electrolyte fuel cell configurations and interconnections  

DOE Patents (OSTI)

High temperature fuel cell configurations and interconnections are made including annular cells having a solid electrolyte sandwiched between thin film electrodes. The cells are electrically interconnected along an elongated axial outer surface.

Isenberg, Arnold O. (Forest Hills, PA)

1984-01-01T23:59:59.000Z

399

High-Temperature Thermal Array for Next Generation Solar Thermal...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

3 Q1 High-Temperature Thermal Array for Next Generation Solar Thermal Power Production - FY13 Q1 This document summarizes the progress of this Los Alamos National Laboratory...

400

Stability and quench protection of high-temperature superconductors  

E-Print Network (OSTI)

In the design and operation of a superconducting magnet, stability and protection are two key issues that determine the magnet's reliability and safe operation. Although the high-temperature superconductor (HTS) is considered ...

Ang, Ing Chea

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Next-generation nuclear fuel withstands high-temperature accident...  

NLE Websites -- All DOE Office Websites (Extended Search)

teri.ehresman@inl.gov Bill Cabage (ORNL), 865-574-4399, cabagewh@ornl.gov Next-generation nuclear fuel withstands high-temperature accident conditions IDAHO FALLS - A safer...

402

3 - High temperature materials issues in the design and operation of coal-fired steam turbines and plant  

Science Journals Connector (OSTI)

Abstract: The basic design of steam plant is outlined, and it is emphasised how the increase in steam temperatures has required high steam pressures. High efficiency requires the use of feedheating, and reheating operation at high pressure and temperature has implications for superheaters. Critical issues are creep strength, resistance to fireside attack and oxide spallation from steam side surfaces. Coal-fired plant is increasingly required to operate in a two shift manner and to compensate for the effects of the intermittency of wind energy; the implications are summarised. Operation at steam temperatures in excess of 600C will require the use of even stronger austenitics. In 700C plants, precipitation-hardened nickel-based alloys will be required for superheaters.

F. Starr

2014-01-01T23:59:59.000Z

403

Low GWP Working Fluid for High Temperature Heat Pumps  

E-Print Network (OSTI)

Low GWP Working Fluid for High Temperature Heat Pumps: DR-2 Chemical Stability at High Temperatures Temp Heat Pumps: DR-2 Very Low GWP AND Non-Flammable HFC-245fa DR-2 Chemical Formula CF3CH2CHF2 HFO 171.3 Pcr [MPa] 3.65 2.9 Kontomaris-DuPont; European Heat Pump Summit, Nuremberg, October 15th, 2013

Oak Ridge National Laboratory

404

High temperature latent heat thermal energy storage: Phase change materials, design considerations and performance enhancement techniques  

Science Journals Connector (OSTI)

Abstract A very common problem in solar power generation plants and various other industrial processes is the existing gap between the period of thermal energy availability and its period of usage. This situation creates the need for an effective method by which excess heat can be stored for later use. Latent heat thermal energy storage is one of the most efficient ways of storing thermal energy through which the disparity between energy production or availability and consumption can be corrected, thus avoiding wastage and increasing the process efficiency. This paper reviews a series of phase change materials, mainly inorganic salt compositions and metallic alloys, which could potentially be used as storage media in a high temperature (above 300C) latent heat storage system, seeking to serve the reader as a comprehensive thermophysical properties database to facilitate the material selection task for high temperature applications. Widespread utilization of latent heat storage systems has been held back by the poor thermal conductivity and some other inherent drawbacks of the use of PCMs; this paper reviews several heat transfer and performance enhancement techniques proposed in the literature and discusses a number of design considerations that must be taken into account aiming to provide a broad overview for the design of high temperature latent heat based thermal energy storage systems.

Bruno Crdenas; Noel Len

2013-01-01T23:59:59.000Z

405

Electron-Phonon Coupling in High-Temperature Cuprate Superconductors as Revealed by Angle-resolved Photoemisson Spectroscopy  

E-Print Network (OSTI)

Cuprate oxide high-temperature superconductors are dopedsuperconductivity. High temperature superconductors arein understanding high-temperature superconductors, such as

Zhou, X.J.; Hussain, Z.; Shen, Z.-X.

2005-01-01T23:59:59.000Z

406

Vibration Combined High Temperature Cycle Tests for Capacitive MEMS Accelerometers  

E-Print Network (OSTI)

In this paper vibration combined high temperature cycle tests for packaged capacitive SOI-MEMS accelerometers are presented. The aim of these tests is to provide useful Design for Reliability information for MEMS designers. A high temperature test chamber and a chopper-stabilized read-out circuitry were designed and realized at BME - DED. Twenty thermal cycles of combined Temperature Cycle Test and Fatigue Vibration Test has been carried out on 5 samples. Statistical evaluation of the test results showed that degradation has started in 3 out of the 5 samples.

Z. Szucs; G. Nagy; S. Hodossy; M. Rencz; A. Poppe

2008-01-07T23:59:59.000Z

407

Instrument Series: Microscopy Ultra-High Vacuum, Low- Temperature Scanning  

NLE Websites -- All DOE Office Websites (Extended Search)

Low- Low- Temperature Scanning Probe Microscope EMSL's ultra-high vacuum, low-temperature scanning probe microscope instrument, or UHV LT SPM, is the preeminent system dedicated to surface chemistry and physics at low temperatures down to 5 K. Operating at low temperatures provides high mechanical stability, superior vacuum conditions, and negligible drift for long-term experiments. With thermal diffusion being entirely suppressed, stable imaging becomes possible even for weakly bound species. The system is primarily used for probing single-site chemical reactivity, while the combination with a hyperthermal molecular beam allows the study of important chemical processes at energies corresponding to the operational temperatures well beyond typical UHV studies. The LT SPM provides

408

DOE Science Showcase - Understanding High-Temperature Superconductors |  

Office of Scientific and Technical Information (OSTI)

Understanding High-Temperature Superconductors Understanding High-Temperature Superconductors Credit: DOE Scientists have long worked to understand one of the great mysteries of modern physics - the origin and behavior of high-temperature superconductors (HTS) that are uniquely capable of transmitting electricity with zero loss when chilled to subzero temperatures. For decades there have been competing theories and misunderstandings of how HTS materials actually work and they have remained fundamentally puzzling to physicists. Solving this mystery has the potential to revolutionize the planet's energy infrastructure from generation to transmission and grid-scale storage. Recent technical breakthroughs in this quest are being discovered by DOE scientists and their collaborators. Read about HTS technology, basic

409

Fabrication and Characterization of Uranium-based High Temperature Reactor  

NLE Websites -- All DOE Office Websites (Extended Search)

Fabrication and Characterization of Uranium-based High Temperature Reactor Fabrication and Characterization of Uranium-based High Temperature Reactor Fuel June 01, 2013 The Uranium Fuel Development Laboratory is a modern R&D scale lab for the fabrication and characterization of uranium-based high temperature reactor fuel. A laboratory-scale coater manufactures tri-isotropic (TRISO) coated fuel particles (CFPs), state-of-the-art materials property characterization is performed, and the CFPs are then pressed into fuel compacts for irradiation testing, all under a NQA-1 compliant Quality Assurance Program. After fuel kernel size and shape are measured by optical shadow imaging, the TRISO coatings are deposited via fluidized bed chemical vapor deposition in a 50-mm diameter conical chamber within the coating furnace. Computer control of temperature and gas composition ensures reproducibility

410

Non-graphite crucible for high temperature applications  

DOE Patents (OSTI)

A multi-piece crucible for high temperature applications comprises a tubular side wall member having a lip on the inside surface and a bottom member or members forming a container for containing a melt of a material during a high temperature melt-casting operations. The multi-piece design prevents cracking of the crucible or leakage of the melt from the crucible during the melt-casting operation. The lip of the tubular member supports the bottom member. The contacting surfaces where the lip of the tubular side wall member contacts the bottom member of the multi-piece crucible contains a ceramic sealing material. The ceramic sealing material forms a seal sufficient to prevent the melt of the material from leaking out of the multi-piece crucible during the melt-casting process. The multi-piece crucible is made of a material which is chemically inert to the melt and has structural integrity at the melting point temperature of the melt, or of a material coated with such a material. The multi-piece crucible is contained in a thermal can assembly of a high temperature induction furnace during a high temperature melt-casting operation. One embodiment of the multi-piece crucible comprises a tubular member having a vertical slot filled with a ceramic sealing material to provide expansion of the tubular member without cracking during the high temperature melt-casting operation. 9 figs.

Holcombe, C.E.; Pfeiler, W.A.

1996-01-09T23:59:59.000Z

411

A temperature compensated pressure transducer for high temperature, high pressure applications  

E-Print Network (OSTI)

will work only if the cliange in deflectiou due to tenrperature ivas constant for all pressures. which is uot the case. At 0 ksi, the rliaphragni deflection is constant (zerol for all possible temperatures. At 40 ksi. however, the deflection is much... temperature. 3, 3 Basic Dimensioning After selecting the basic configuration and material for the transclucer body a diaphragm cap, it ivas next necessary to determine the actual defle& tion of the diaphragni and any thermally induced affects. Prior to a...

Lippka, Sandra Margaret

1991-01-01T23:59:59.000Z

412

Creep-fatigue of High Temperature Materials for VHTR: Effect of Cyclic Loading and Environment  

SciTech Connect

Alloy 617 is the one of the leading candidate materials for Intermediate Heat eXchangers (IHX) of a Very High Temperature Reactor (VHTR). System start-ups and shut-downs as well as power transients will produce low cycle fatigue (LCF) loadings of components. Furthermore, the anticipated IHX operating temperature, up to 950C, is in the range of creep so that creep-fatigue interaction, which can significantly increase the fatigue crack growth, may be one of the primary IHX damage modes. To address the needs for Alloy 617 codification and licensing, a significant creep-fatigue testing program is underway at Idaho National Laboratory. Strain controlled LCF tests including hold times up to 1800s at maximum tensile strain were conducted at total strain range of 0.3% and 0.6% in air at 950C. Creep-fatigue testing was also performed in a simulated VHTR impure helium coolant for selected experimental conditions. The creep-fatigue tests resulted in failure times up to 1000 hrs. Fatigue resistance was significantly decreased when a hold time was added at peak stress and when the total strain was increased. The fracture mode also changed from transgranular to intergranular with introduction of a tensile hold. Changes in the microstructure were methodically characterized. A combined effect of temperature, cyclic and static loading and environment was evidenced in the targeted operating conditions of the IHX. This paper This paper reviews the data previously published by Carroll and co-workers in references 10 and 11 focusing on the role of inelastic strain accumulation and of oxidation in the initiation and propagation of surface fatigue cracks.

Celine Cabet; L. Carroll; R. Wright; R. Madland

2011-05-01T23:59:59.000Z

413

Pseudogap and Superconducting Gap in High-Temperature Superconductors  

NLE Websites -- All DOE Office Websites (Extended Search)

Pseudogap and Superconducting Gap in Pseudogap and Superconducting Gap in High-Temperature Superconductors Two decades after the discovery of first high temperature superconductors, the microscopic mechanism of high-Tc superconductivity remains elusive. In conventional superconductors, it has been well established that electrons form so-called "Cooper pairs" to give rise to superconductivity. The pair binding manifests itself as an energy gap in many spectroscopic measurements. This energy gap, known as superconducting gap, appears at the superconducting transition temperature Tc where the resistance also vanishes. For high temperature superconductors, the story is more complicated. Over a wide region of compositions and temperatures, there exists an energy gap well above Tc. This energy gap is called pseudogap [1], because there is no direct correlation to the superconducting transition. The origin of this pseudogap and its relation to the superconducting gap are believed to hold the key for understanding the mechanism of high-Tc superconductivity - one of the outstanding problems in condensed matter physics. In this regard, researchers Kiyohisa Tanaka and Wei-Sheng Lee, along with their co-workers in Prof. Zhi-Xun Shen's group at Stanford University, have recently made an important discovery about the coexistence of two distinct energy gaps that have opposite doping dependence. Their observation not only provides a natural explanation for the contradictory results about the superconducting gap deduced from different experimental techniques, but also has profound implications on the mechanism of high-Tc superconductivity.

414

Method of forming components for a high-temperature secondary electrochemical cell  

DOE Patents (OSTI)

A method of forming a component for a high-temperature secondary electrochemical cell having a positive electrode including a sulfide selected from the group consisting of iron sulfides, nickel sulfides, copper sulfides and cobalt sulfides, a negative electrode including an alloy of aluminum and an electrically insulating porous separator between said electrodes. The improvement comprises forming a slurry of solid particles dispersed in a liquid electrolyte such as the lithium chloride-potassium chloride eutetic, casting the slurry into a form having the shape of one of the components and smoothing the exposed surface of the slurry, cooling the cast slurry to form the solid component, and removing same. Electrodes and separators can be thus formed.

Mrazek, Franklin C. (Hickory Hills, IL); Battles, James E. (Oak Forest, IL)

1983-01-01T23:59:59.000Z

415

Multi-range force sensors utilizing shape memory alloys  

DOE Patents (OSTI)

The present invention provides a multi-range force sensor comprising a load cell made of a shape memory alloy, a strain sensing system, a temperature modulating system, and a temperature monitoring system. The ability of the force sensor to measure contact forces in multiple ranges is effected by the change in temperature of the shape memory alloy. The heating and cooling system functions to place the shape memory alloy of the load cell in either a low temperature, low strength phase for measuring small contact forces, or a high temperature, high strength phase for measuring large contact forces. Once the load cell is in the desired phase, the strain sensing system is utilized to obtain the applied contact force. The temperature monitoring system is utilized to ensure that the shape memory alloy is in one phase or the other.

Varma, Venugopal K. (Knoxville, TN)

2003-04-15T23:59:59.000Z

416

CF8C PLus: A New Cast Stainless Steel for High-Temperature Diesel...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

exhaust components turbo-housing exhaust manifold C-15, 14.6L HD On- Highway Diesel Engine Materials Need: High Performance Low-Cost Alloy was Needed to Replace SiMo Cast Iron...

417

Cedarville Elementary & High School Space Heating Low Temperature  

Open Energy Info (EERE)

Cedarville Elementary & High School Space Heating Low Temperature Cedarville Elementary & High School Space Heating Low Temperature Geothermal Facility Jump to: navigation, search Name Cedarville Elementary & High School Space Heating Low Temperature Geothermal Facility Facility Cedarville Elementary & High School Sector Geothermal energy Type Space Heating Location Cedarville, California Coordinates 41.5290606°, -120.1732781° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[]}

418

The Northwest Geysers High-Temperature Reservoir- Evidence For Active  

Open Energy Info (EERE)

Geysers High-Temperature Reservoir- Evidence For Active Geysers High-Temperature Reservoir- Evidence For Active Magmatic Degassing And Implications For The Origin Of The Geysers Geothermal Field Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: The Northwest Geysers High-Temperature Reservoir- Evidence For Active Magmatic Degassing And Implications For The Origin Of The Geysers Geothermal Field Details Activities (2) Areas (1) Regions (0) Abstract: Noble gas isotope abundances in steam from the Coldwater Creek field of the Northwest Geysers, California, show mixing between a nearly pure mid-ocean ridge (MOR) type magmatic gas with high 3He/4He and low radiogenic 40*Ar (R/Ra > 8.3 and 40*Ar/4He < 0.07), and a magmatic gas diluted with crustal gas (R/Ra 0.25). The

419

Cotulla High School Space Heating Low Temperature Geothermal Facility |  

Open Energy Info (EERE)

Cotulla High School Space Heating Low Temperature Geothermal Facility Cotulla High School Space Heating Low Temperature Geothermal Facility Jump to: navigation, search Name Cotulla High School Space Heating Low Temperature Geothermal Facility Facility Cotulla High School Sector Geothermal energy Type Space Heating Location Cotulla, Texas Coordinates 28.436934°, -99.2350322° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[]}

420

Henley High School Space Heating Low Temperature Geothermal Facility | Open  

Open Energy Info (EERE)

Henley High School Space Heating Low Temperature Geothermal Facility Henley High School Space Heating Low Temperature Geothermal Facility Jump to: navigation, search Name Henley High School Space Heating Low Temperature Geothermal Facility Facility Henley High School Sector Geothermal energy Type Space Heating Location Klamath Falls, Oregon Coordinates 42.224867°, -121.7816704° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[]}

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Modoc High School Space Heating Low Temperature Geothermal Facility | Open  

Open Energy Info (EERE)

Modoc High School Space Heating Low Temperature Geothermal Facility Modoc High School Space Heating Low Temperature Geothermal Facility Jump to: navigation, search Name Modoc High School Space Heating Low Temperature Geothermal Facility Facility Modoc High School Sector Geothermal energy Type Space Heating Location Alturas, California Coordinates 41.4871146°, -120.5424555° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[]}

422

TPV Power Generation System Using a High Temperature Metal Radiant Burner  

Science Journals Connector (OSTI)

Interest has grown in micro?combined heat and power (micro?CHP). Thermophotovoltaic (TPV) generation of electricity in fuel?fired furnaces is one of the micro?CHP technologies that are attracting technical attention. Previous investigations have shown that a radiant burner that can efficiently convert fuel chemical energy into radiation energy is crucial to realize a practical TPV power system. In this work we developed a TPV power generation system using a gas?fired metal radiant burner. The burner consists of a high temperature alloy emitter which could have an increased emissivity at short wavelengths and low emissivity at long wavelengths. The metal emitter is capable of bearing high temperatures of interest to fuel?fired TPV power conversion. GaSb TPV cells were tested in the combustion?driven radiant source. Electric output characteristics of the TPV cells were investigated at various operating conditions. The electric power output of the TPV cells was demonstrated to be promising. At an emitter temperature of 1185C an electric power density of 0.476 W/cm2 was generated by the GaSb cells. It is shown that the metal emitter is attractive and could be applied to practical fuel?fired TPV power systems.

K. Qiu; A. C. S. Hayden; E. Entchev

2007-01-01T23:59:59.000Z

423

Heat and corrosion resistant cast CN-12 type stainless steel with improved high temperature strength and ductility  

DOE Patents (OSTI)

A cast stainless steel alloy and articles formed therefrom containing about 0.5 wt. % to about 10 wt. % manganese, 0.02 wt. % to 0.50 wt. % N, and less than 0.15 wt. % sulfur provides high temperature strength both in the matrix and at the grain boundaries without reducing ductility due to cracking along boundaries with continuous or nearly-continuous carbides. Alloys of the present invention also have increased nitrogen solubility thereby enhancing strength at all temperatures because nitride precipitates or nitrogen porosity during casting are not observed. The solubility of nitrogen is dramatically enhanced by the presence of manganese, which also retains or improves the solubility of carbon thereby providing additional solid solution strengthening due to the presence of manganese and nitrogen, and combined carbon. Such solution strengthening enhances the high temperature precipitation-strengthening benefits of fine dispersions of NbC. Such solid solution effects also enhance the stability of the austenite matrix from resistance to excess sigma phase or chrome carbide formation at higher service temperatures. The presence of sulfides is substantially eliminated.

Mazias, Philip J. (Oak Ridge, TN); McGreevy, Tim (Morton, IL); Pollard,Michael James (East Peoria, IL); Siebenaler, Chad W. (Peoria, IL); Swindeman, Robert W. (Oak Ridge, TN)

2007-08-14T23:59:59.000Z

424

High-Temperature Superconducting Cable Testing Gregory S. Boebinger, National High Magnetic Field Laboratory  

E-Print Network (OSTI)

High-Temperature Superconducting Cable Testing Gregory S. Boebinger, National High Magnetic Field-Temperature Superconducting (HTS) Cables are desirable for application in large high-field magnets (>20 T), especially when). Of the three HTS magnet cable concepts emerging, the Conductor On Round Core was the first that was tested

Weston, Ken

425

INNOVATIVE INSTRUMENTATION AND ANALYSIS OF THE TEMPERATURE MEASUREMENT FOR HIGH TEMPERATURE GASIFICATION  

SciTech Connect

The systematic tests of the gasifier simulator on the ultrasonic vibration application for cleaning method were completed in this reporting period. Within the systematic tests on the ultrasonic vibration application, the ambient temperature and high temperature status condition were tested separately. The sticky dirt on the thermocouple tip was simulated by the cement-covered layer on the thermocouple tip. At the ambient temperature status, four (4) factors were considered as the input factors affecting the response variable of peeling off rate. The input factors include the shape of the cement-covered layer (thickness and length), the ultrasonic vibration output power, and application time. At the high temperature tests, four (4) different environments were considered as the experimental parameters including air flow supply, water and air supply environment, water/air/fine dust particle supply, and air/water/ammonia/fine dust particle supply environment. The factorial design method was used in the experiment design with twelve (12) data sets of readings. Analysis of Variances (ANOVA) was applied to the results from systematic tests. The ANOVA results show that the thickness and length of the cement-covered layer have the significant impact on the peeling off rate of ultrasonic vibration application at the ambient temperature environment. For the high temperature tests, the different environments do not seem to have significant impact on the temperature changes. These results may indicate that the ultrasonic vibration is one of best cleaning methods for the thermocouple tip.

Seong W. Lee

2005-04-01T23:59:59.000Z

426

Atomic dynamics in molten AlCu alloys of different compositions and at different temperatures by cold neutron scattering  

SciTech Connect

The atomic motions in molten Al1?xCux (x=0.10, 0.171 and 0.25) around the eutectic composition (x=0.171) were studied by cold neutron inelastic scattering at three different temperatures (973 K, 1173 K and 1373 K). An alloy of eutectic composition containing the 63Cu isotope was also studied. Self-diffusion coefficients for the Cu ions were determined from the width of quasielastic peaks and were found to decrease slightly with increasing Cu concentration. Longitudinal current correlation functions Jl(Q,E) exhibit at all temperatures and at all compositions a shoulder at energies below 10 meV and one main maximum at higher energies. These features can be interpreted in terms of excitations of acoustic and optic nature. The shape of Jl(Q,E) is sensitive to composition, being considerably more structured for larger Cu content. This can be coupled to the existence of a prepeak in the measured zeroth moment of dynamic scattering function indicating an increased chemical ordering with increasing Cu concentration for all temperatures. Indications for an existence of a liquidliquid phase transition are presented.

Dahlborg, U. [University of Rouen; Besser, M. [Ames Laboratory; Kramer, Matthew J. [Ames Laboratory; Morris, J. R. [Oak Ridge National Laboratory; Calvo-Dahlborg, M. [University of Rouen

2013-12-21T23:59:59.000Z

427

Two Phase Transitions Make a High-Temperature Superconductor  

NLE Websites -- All DOE Office Websites (Extended Search)

Two Phase Transitions Make a High-Temperature Superconductor Print Two Phase Transitions Make a High-Temperature Superconductor Print Superconductivity-conceptually remarkable and practically revolutionary-is a quantum phenomenon in which bound electron pairs flow through a material in perfect synchrony, without friction. Conventional superconducting materials reach this state via a single thermal phase transition at a critical temperature (Tc). It was generally believed that such a picture also applied to the copper oxide (cuprate) superconductors-first discovered 25 years ago and the current record holders for highest Tc. However, three groups of researchers who performed measurements on the same cuprate material recently joined forces to prove that this view is inaccurate. Their work showed that another phase transition actually exists at a higher temperature in the cuprate phase diagram, below which electrons, instead of pairing up, organize themselves in a drastically different way.

428

Two Phase Transitions Make a High-Temperature Superconductor  

NLE Websites -- All DOE Office Websites (Extended Search)

Two Phase Transitions Make a High-Temperature Superconductor Print Two Phase Transitions Make a High-Temperature Superconductor Print Superconductivity-conceptually remarkable and practically revolutionary-is a quantum phenomenon in which bound electron pairs flow through a material in perfect synchrony, without friction. Conventional superconducting materials reach this state via a single thermal phase transition at a critical temperature (Tc). It was generally believed that such a picture also applied to the copper oxide (cuprate) superconductors-first discovered 25 years ago and the current record holders for highest Tc. However, three groups of researchers who performed measurements on the same cuprate material recently joined forces to prove that this view is inaccurate. Their work showed that another phase transition actually exists at a higher temperature in the cuprate phase diagram, below which electrons, instead of pairing up, organize themselves in a drastically different way.

429

Two Phase Transitions Make a High-Temperature Superconductor  

NLE Websites -- All DOE Office Websites (Extended Search)

Two Phase Transitions Make a High-Temperature Superconductor Print Two Phase Transitions Make a High-Temperature Superconductor Print Superconductivity-conceptually remarkable and practically revolutionary-is a quantum phenomenon in which bound electron pairs flow through a material in perfect synchrony, without friction. Conventional superconducting materials reach this state via a single thermal phase transition at a critical temperature (Tc). It was generally believed that such a picture also applied to the copper oxide (cuprate) superconductors-first discovered 25 years ago and the current record holders for highest Tc. However, three groups of researchers who performed measurements on the same cuprate material recently joined forces to prove that this view is inaccurate. Their work showed that another phase transition actually exists at a higher temperature in the cuprate phase diagram, below which electrons, instead of pairing up, organize themselves in a drastically different way.

430

Two Phase Transitions Make a High-Temperature Superconductor  

NLE Websites -- All DOE Office Websites (Extended Search)

Two Phase Transitions Make a High-Temperature Superconductor Print Two Phase Transitions Make a High-Temperature Superconductor Print Superconductivity-conceptually remarkable and practically revolutionary-is a quantum phenomenon in which bound electron pairs flow through a material in perfect synchrony, without friction. Conventional superconducting materials reach this state via a single thermal phase transition at a critical temperature (Tc). It was generally believed that such a picture also applied to the copper oxide (cuprate) superconductors-first discovered 25 years ago and the current record holders for highest Tc. However, three groups of researchers who performed measurements on the same cuprate material recently joined forces to prove that this view is inaccurate. Their work showed that another phase transition actually exists at a higher temperature in the cuprate phase diagram, below which electrons, instead of pairing up, organize themselves in a drastically different way.

431

Quench development in a high temperature superconducting tape  

SciTech Connect

Normal zone propagation experiments have been performed on a long length of Bi-2223/Ag high temperature superconducting (HTS) tape. Tests were conducted with liquid nitrogen and gaseous helium cooling in temperatures from 5 to 77 K. No sustained expansion of a {open_quotes}normal{close_quotes} zone was observed with a short resistive heater. Non-uniform critical currents were, however, observed over the length of the conductor. When the conductor was charged and held at a current above the critical currents of weaker sections, a quench was being developed without distinctive {open_quotes}normal{close_quotes} zone propagation. Because of the high temperature margin and broad resistive transition of the superconductor, and the good thermal conductivity of the Ag-matrix, the quench process was very slow. and no large temperature gradient along the conductor was observed.

Lue, J.W.; Lubell, M.S. [Oak Ridge National Lab., TN (United States); Aized, D.; Campbell, J.M.; Schwall, R.E. [American Superconductor Corporation, Westborough, MA (United States)

1996-12-31T23:59:59.000Z

432

Quench development in a high temperature superconducting tape  

SciTech Connect

Normal zone propagation experiments have been per-formed on a long length of Bi2223/Ag high temperature superconducting (HTS) tape. Tests were performed in liquid nitrogen and with gaseous helium cooling in temperatures ranging from 4.2 K to 77 K. No sustained expansion of a ``normal`` zone was observed with a short resistive heater. Non-uniform critical currents were, however, observed over the length of the conductor. When the conductor was charged and held at a current above the critical currents of weaker sections, a quench was being developed without distinctive ``normal`` zone propagation. Because of the high temperature margin and broad resistive transition of the superconductor, and the good thermal conductivity of the Ag-matrix, the quench process was very slow, and no large temperature gradient along the conductor was observed in the test duration of a few minutes.

Lue, J.W.; Lubell, M.S. [Argonne National Lab., IL (United States); Aized, D.; Campbell, J.M.; Schwall, R.E. [American Superconductor Corp., Westborough, MA (United States)

1995-12-01T23:59:59.000Z

433

NETL: Mercury Emissions Control Technologies - Enhanced High Temperature  

NLE Websites -- All DOE Office Websites (Extended Search)

Enhanced High Temperature Mercury Oxidation and Enhanced High Temperature Mercury Oxidation and In-Situ Active Carbon Generation for Low Cost Mercury Capture Mercury oxidation phenomenon and the studies of this phenomenon have generally focused on lower temperatures, typically below 650°F. This has been based on the mercury vapor equilibrium speciation curve. The baseline extents of mercury oxidation as reported in the ICR dataset and observed during subsequent tests has shown a tremendous amount of scatter. The objective of this project is to examine, establish and demonstrate the effect of higher temperature kinetics on mercury oxidation rates. Further, it is the objective of this project to demonstrate how the inherent mercury oxidation kinetics can be influenced to dramatically increase the mercury oxidation.

434

Acoustic studies of single?crystal high?temperature superconductors  

Science Journals Connector (OSTI)

The acoustic properties of single crystals of the high?temperature superconductor YBa 2 Cu 3 O 7 have been measured at temperatures between 0.1 and 300 K for frequencies near 103 and 109 Hz. In the GHz regime longitudinal modes have been studied for propagation directions parallel and perpendicular to the c axis. At Tc there is a discontinuity in the soundvelocities and their temperature derivatives from which the anisotropic strain dependences of Tc are obtained. In the kHz regime resonant excitation of flexural modes in thin reeds of YBa 2 Cu 3 O 7 crystals has permitted precise measurement of acoustic damping and dispersion. The temperature?dependent damping is characterized by at least five features associated with the relaxation of defects. At temperatures below 1 K the velocity of sound is consistent with the presence of a broad glasslike distribution of tunneling modes.

Brage Golding; W. H. Haemmerle; L. F. Schneemeyer

1988-01-01T23:59:59.000Z

435

Advanced High-Temperature, High-Pressure Transport Reactor Gasification  

SciTech Connect

The transport reactor development unit (TRDU) was modified to accommodate oxygen-blown operation in support of a Vision 21-type energy plex that could produce power, chemicals, and fuel. These modifications consisted of changing the loop seal design from a J-leg to an L-valve configuration, thereby increasing the mixing zone length and residence time. In addition, the standpipe, dipleg, and L-valve diameters were increased to reduce slugging caused by bubble formation in the lightly fluidized sections of the solid return legs. A seal pot was added to the bottom of the dipleg so that the level of solids in the standpipe could be operated independently of the dipleg return leg. A separate coal feed nozzle was added that could inject the coal upward into the outlet of the mixing zone, thereby precluding any chance of the fresh coal feed back-mixing into the oxidizing zone of the mixing zone; however, difficulties with this coal feed configuration led to a switch back to the original downward configuration. Instrumentation to measure and control the flow of oxygen and steam to the burner and mix zone ports was added to allow the TRDU to be operated under full oxygen-blown conditions. In total, ten test campaigns have been conducted under enriched-air or full oxygen-blown conditions. During these tests, 1515 hours of coal feed with 660 hours of air-blown gasification and 720 hours of enriched-air or oxygen-blown coal gasification were completed under this particular contract. During these tests, approximately 366 hours of operation with Wyodak, 123 hours with Navajo sub-bituminous coal, 143 hours with Illinois No. 6, 106 hours with SUFCo, 110 hours with Prater Creek, 48 hours with Calumet, and 134 hours with a Pittsburgh No. 8 bituminous coal were completed. In addition, 331 hours of operation on low-rank coals such as North Dakota lignite, Australian brown coal, and a 90:10 wt% mixture of lignite and wood waste were completed. Also included in these test campaigns was 50 hours of gasification on a petroleum coke from the Hunt Oil Refinery and an additional 73 hours of operation on a high-ash coal from India. Data from these tests indicate that while acceptable fuel gas heating value was achieved with these fuels, the transport gasifier performs better on the lower-rank feedstocks because of their higher char reactivity. Comparable carbon conversions have been achieved at similar oxygen/coal ratios for both air-blown and oxygen-blown operation for each fuel; however, carbon conversion was lower for the less reactive feedstocks. While separation of fines from the feed coals is not needed with this technology, some testing has suggested that feedstocks with higher levels of fines have resulted in reduced carbon conversion, presumably due to the inability of the finer carbon particles to be captured by the cyclones. These data show that these low-rank feedstocks provided similar fuel gas heating values; however, even among the high-reactivity low-rank coals, the carbon conversion did appear to be lower for the fuels (brown coal in particular) that contained a significant amount of fines. The fuel gas under oxygen-blown operation has been higher in hydrogen and carbon dioxide concentration since the higher steam injection rate promotes the water-gas shift reaction to produce more CO{sub 2} and H{sub 2} at the expense of the CO and water vapor. However, the high water and CO{sub 2} partial pressures have also significantly reduced the reaction of (Abstract truncated)

Michael L. Swanson

2005-08-30T23:59:59.000Z

436

Deposition method for producing silicon carbide high-temperature semiconductors  

DOE Patents (OSTI)

An improved deposition method for producing silicon carbide high-temperature semiconductor material comprising placing a semiconductor substrate composed of silicon carbide in a fluidized bed silicon carbide deposition reactor, fluidizing the bed particles by hydrogen gas in a mildly bubbling mode through a gas distributor and heating the substrate at temperatures around 1200.degree.-1500.degree. C. thereby depositing a layer of silicon carbide on the semiconductor substrate.

Hsu, George C. (La Crescenta, CA); Rohatgi, Naresh K. (W. Corine, CA)

1987-01-01T23:59:59.000Z

437

Sealed glass coating of high temperature ceramic superconductors  

DOE Patents (OSTI)

A method and article of manufacture of a lead oxide based glass coating on a high temperature superconductor. The method includes preparing a dispersion of glass powders in a solution, applying the dispersion to the superconductor, drying the dispersion before applying another coating and heating the glass powder dispersion at temperatures below oxygen diffusion onset and above the glass melting point to form a continuous glass coating on the superconductor to establish compressive stresses which enhance the fracture strength of the superconductor.

Wu, Weite (Tainan, TW); Chu, Cha Y. (Garnerville, NY); Goretta, Kenneth C. (Downers Grove, IL); Routbort, Jules L. (Darien, IL)

1995-01-01T23:59:59.000Z

438

Nearly Perfect Fluidity in a High Temperature Superconductor  

E-Print Network (OSTI)

Perfect fluids are characterized as having the smallest ratio of shear viscosity to entropy density, {\\eta}/s, consistent with quantum uncertainty and causality. So far, nearly perfect fluids have only been observed in the Quark-Gluon Plasma (QGP) and in unitary atomic Fermi gases (UFG), exotic systems that are amongst the hottest and coldest objects in the known universe, respectively. We use Angle Resolve Photoemission Spectroscopy (ARPES) to measure the temperature dependence of an electronic analogue of {\\eta}/s in an optimally doped cuprate high temperature superconductor, finding it too is a nearly perfect fluid around, and above, its superconducting transition temperature Tc.

J. D. Rameau; T. J. Reber; H. -B. Yang; S. Akhanjee; G. D. Gu; S. Campbell; P. D. Johnson

2014-09-19T23:59:59.000Z

439

Nearly Perfect Fluidity in a High Temperature Superconductor  

E-Print Network (OSTI)

Perfect fluids are characterized as having the smallest ratio of shear viscosity to entropy density, {\\eta}/s, consistent with quantum uncertainty and causality. So far, nearly perfect fluids have only been observed in the Quark-Gluon Plasma (QGP) and in unitary atomic Fermi gases (UFG), exotic systems that are amongst the hottest and coldest objects in the known universe, respectively. We use Angle Resolve Photoemission Spectroscopy (ARPES) to measure the temperature dependence of an electronic analogue of {\\eta}/s in an optimally doped cuprate high temperature superconductor, finding it too is a nearly perfect fluid around, and above, its superconducting transition temperature Tc.

Rameau, J D; Yang, H -B; Akhanjee, S; Gu, G D; Campbell, S; Johnson, P D

2014-01-01T23:59:59.000Z

440

Nearly perfect fluidity in a high-temperature superconductor  

Science Journals Connector (OSTI)

Perfect fluids are characterized as having the smallest ratio of shear viscosity to entropy density, ?/s, consistent with quantum uncertainty and causality. So far, nearly perfect fluids have only been observed in the quark-gluon plasma and in unitary atomic Fermi gases, exotic systems that are amongst the hottest and coldest objects in the known universe, respectively. We use angle resolved photoemission spectroscopy to measure the temperature dependence of an electronic analog of ?/s in an optimally doped cuprate high-temperature superconductor, finding it too is a nearly perfect fluid around, and above, its superconducting transition temperature Tc.

J. D. Rameau; T. J. Reber; H.-B. Yang; S. Akhanjee; G. D. Gu; P. D. Johnson; S. Campbell

2014-10-13T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
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441

HIGH TEMPERATURE CONDUCTIVITY PROBE FOR MONITORING CONTAMINATION LEVELS IN POWER PLANT BOILER WATER.  

E-Print Network (OSTI)

??A high temperature/high pressure flow through probe was designed to measure high temperature electrical conductivity of aqueous (aq) dilute electrolyte solutions, an application which can (more)

Hipple, Sarah

2008-01-01T23:59:59.000Z

442

Refueling Liquid-Salt-Cooled Very High-Temperature Reactors  

SciTech Connect

The liquid-salt-cooled very high-temperature reactor (LS-VHTR), also called the Advanced High-Temperature Reactor (AHTR), is a new reactor concept that combines in a novel way four established technologies: (1) coated-particle graphite-matrix nuclear fuels, (2) Brayton power cycles, (3) passive safety systems and plant designs previously developed for liquid-metal-cooled fast reactors, and (4) low-pressure liquid-salt coolants. Depending upon goals, the peak coolant operating temperatures are between 700 and 1000 deg. C, with reactor outputs between 2400 and 4000 MW(t). Several fluoride salt coolants that are being evaluated have melting points between 350 and 500 deg. C, values that imply minimum refueling temperatures between 400 and 550 deg. C. At operating conditions, the liquid salts are transparent and have physical properties similar to those of water. A series of refueling studies have been initiated to (1) confirm the viability of refueling, (2) define methods for safe rapid refueling, and (3) aid the selection of the preferred AHTR design. Three reactor cores with different fuel element designs (prismatic, pebble bed, and pin-type fuel assembly) are being evaluated. Each is a liquid-salt-cooled variant of a graphite-moderated high-temperature reactor. The refueling studies examined applicable refueling experience from high-temperature reactors (similar fuel element designs) and sodium-cooled fast reactors (similar plant design with liquid coolant, high temperatures, and low pressures). The findings indicate that refueling is viable, and several approaches have been identified. The study results are described in this paper. (authors)

Forsberg, Charles W. [Oak Ridge National Laboratory, P.O. Box 2008 Oak Ridge, TN 37831 (United States); Peterson, Per F. [Nuclear Engineering Department, University of California at Berkeley, 6124a Etcheverry Hall, Berkeley, CA 94720 (United States); Cahalan, James E. [Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, IL 60439 (United States); Enneking, Jeffrey A. [Areva NP (United States); Phil MacDonald [Consultant, Cedar Hill, TX (United States)

2006-07-01T23:59:59.000Z

443

High-Temperature Downhole Tools | Open Energy Information  

Open Energy Info (EERE)

Tools Tools Jump to: navigation, search Contents 1 Geothermal Lab Call Projects for High-Temperature Downhole Tools 2 Geothermal ARRA Funded Projects for High-Temperature Downhole Tools Geothermal Lab Call Projects for High-Temperature Downhole Tools Loading map... {"format":"googlemaps3","type":"ROADMAP","types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"limit":200,"offset":0,"link":"all","sort":[""],"order":[],"headers":"show","mainlabel":"","intro":"","outro":"","searchlabel":"\u2026 further results","default":"","geoservice":"google","zoom":false,"width":"600px","height":"350px","centre":false,"layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","icon":"","visitedicon":"","forceshow":true,"showtitle":true,"hidenamespace":false,"template":false,"title":"","label":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"locations":[{"text":"

444

High- and low-temperature-stable thermite composition for producing high-pressure, high-velocity gases  

DOE Patents (OSTI)

A high- and low-temperature-stable thermite composition for producing high-pressure and high-velocity gases comprises an oxidizable metal, an oxidizing reagent, and a high-temperature-stable gas-producing additive selected from the group consisting of metal carbides and metal nitrides.

Halcomb, Danny L. (Camden, OH); Mohler, Jonathan H. (Spring Valley, OH)

1990-10-16T23:59:59.000Z

445

High-Temperature Gas-Stream Cleanup Test Facility  

SciTech Connect

In support of METC`s hot-gas filter development program, the high- temperature, gas-stream cleanup test facility was designed to: investigate conventional and novel approaches to high-temperature filtration; conduct detailed parametric studies that characterize particulate control devices under well-controlled conditions; and screen new materials for other high-temperature applications, such as heat exchanger tubes. This new facility utilizes a natural gas-fueled combustor to produce high-temperature process gas, and a screw feeder to inject ash, or other fine media, into the gas stream. The vessel that surrounds the particulate control devices has an inside diameter of roughly 0.20 meters (8 inches) and is about 3 meters (10 feet) long. Three commercial-size filter elements can be tested simultaneously, and the facility is capable of operating over a wide range of conditions. Operating temperatures can vary from 540 to 870{degrees}C (1,000 to 1,600 {degrees}F), and the operating pressure can vary from 0 to 400 kPa (0 to 60 psig).

Straub, D.; Chiang, Ta-Kuan, Schultz, J.

1996-12-31T23:59:59.000Z

446

Margins in high temperature leak-before-break assessments  

SciTech Connect

Developments in the defect assessment procedure R6 to include high-temperature mechanisms in Leak-before-Break arguments are described. In particular, the effect of creep on the time available to detect a leak and on the crack opening area, and hence leak rate, is discussed. The competing influence of these two effects is emphasized by an example. The application to Leak-before-Break of the time-dependent failure assessment diagram approach for high temperature defect assessment is then outlined. The approach is shown to be of use in assessing the erosion of margins by creep.

Budden, P.J.; Hooton, D.G.

1997-04-01T23:59:59.000Z

447

Electronic-Structure of High-Temperature Superconductors  

E-Print Network (OSTI)

, and for the corresponding metal atoms in related high-temperature superconductors. These peaks should be observable in electron energy-loss spectroscopy's and 6nal-state photoemission spectrosco- py 20 The calculated valences d,n are again given in Table II. Notice... again neatly cancel in YBa2Cu307. In summary, we have calculated the electronic struc- tures of the most typical members of the two known classes of high-temperature superconductors. The present results, obtained with a simple tight-binding model...

RICHERT, BA; Allen, Roland E.

1988-01-01T23:59:59.000Z

448

High temperature alkali corrosion of ceramics in coal gas  

SciTech Connect

The high temperature alkali corrosion kinetics of SiC have been systematically investigated from 950 to 1100[degrees]C at 0.63 vol % alkali vapor concentration. The corrosion rate in the presence of alkaliis approximately 10[sup 4] to 10[sup 5] times faster than the oxidation rate of SiC in air. The activation energy associated with the alkali corrosion is 406 kJ/mol, indicating a highly temperature-dependent reaction rate. The rate-controlling step of the overall reaction is likely to be the dissolution of silica in the sodium silicate liquid, based on the oxygen diffusivity data.

Pickrell, G.R.; Sun, T.; Brown, J.J.

1992-02-24T23:59:59.000Z

449

Silicon Carbide Temperature Monitor Measurements at the High Temperature Test Laboratory  

SciTech Connect

Silicon carbide (SiC) temperature monitors are now available for use as temperature sensors in Advanced Test Reactor (ATR) irradiation test capsules. Melt wires or paint spots, which are typically used as temperature sensors in ATR static capsules, are limited in that they can only detect whether a single temperature is or is not exceeded. SiC monitors are advantageous because a single monitor can be used to detect for a range of temperatures that may have occurred during irradiation. As part of the efforts initiated by the ATR National Scientific User Facility (NSUF) to make SiC temperature monitors available, a capability was developed to complete post-irradiation evaluations of these monitors. As discussed in this report, the Idaho National Laboratory (INL) selected the resistance measurement approach for detecting peak irradiation temperature from SiC temperature monitors. This document describes the INL efforts to develop the capability to complete these resistance measurements. In addition, the procedure is reported that was developed to assure that high quality measurements are made in a consistent fashion.

J. L. Rempe; K. G. Condie; D. L. Knudson; L. L. Snead

2010-01-01T23:59:59.000Z

450

Erosion-Corrosion of Iron and Nickel Alloys at Elevated Temperature...  

Office of Scientific and Technical Information (OSTI)

g(cm 2 min), which is similar to what is found in a PC boiler. The time of the test at temperature was 120 h (5 days). 2. EXPERIMENTAL PROCEDURE 2.1 Erosion-corrosion...

451

Mesoscale Climatic Simulation of Surface Air Temperature Cooling by Highly  

NLE Websites -- All DOE Office Websites (Extended Search)

Mesoscale Climatic Simulation of Surface Air Temperature Cooling by Highly Mesoscale Climatic Simulation of Surface Air Temperature Cooling by Highly Reflective Greenhouses in SE Spain Title Mesoscale Climatic Simulation of Surface Air Temperature Cooling by Highly Reflective Greenhouses in SE Spain Publication Type Journal Article Year of Publication 2013 Authors Campra, Pablo, and Dev Millstein Journal Environmental Science & Technology Volume 47 Issue 21 Pagination 12284 - 12290 Date Published 11/2013 ISSN 0013-936X Keywords buildings, Heat Island Group Abstract A long-term local cooling trend in surface air temperature has been monitored at the largest concentration of reflective greenhouses in the world, at the Province of Almeria, SE Spain, associated with a dramatic increase in surface albedo in the area. The availability of reliable long-term climatic field data at this site offers a unique opportunity to test the skill of mesoscale meteorological models describing and predicting the impacts of land use change on local climate. Using the Weather Research and Forecast (WRF) mesoscale model, we have run a sensitivity experiment to simulate the impact of the observed surface albedo change on monthly and annual surface air temperatures. The model output showed a mean annual cooling of 0.25 °C associated with a 0.09 albedo increase, and a reduction of 22.8 W m-2 of net incoming solar radiation at surface. Mean reduction of summer daily maximum temperatures was 0.49 °C, with the largest single-day decrease equal to 1.3 °C. WRF output was evaluated and compared with observations. A mean annual warm bias (MBE) of 0.42 °C was estimated. High correlation coefficients (R2 > 0.9) were found between modeled and observed values. This study has particular interest in the assessment of the potential for urban temperature cooling by cool roofs deployment projects, as well as in the evaluation of mesoscale climatic models performance.

452

Fracture mechanics investigations on high-temperature gas-cooled reactor materials  

SciTech Connect

The prototype nuclear process heat plant and the high-temperature gas-cooled reactor need materials that can withstand temperatures up to 1223 K (950/sup 0/C). An elaboration of fracture mechanics concepts that holds for the complete temperature regime must consider all possible phenomena like creep damage and precipitation during exposure, etc. In tests on the Inconel-617, Hastelloy-X, and Nimonic-86 alloys with respect to fatigue crack growth, creep crack growth, and toughness (J integral R curves) up to 1273 K (1000/sup 0/C), the first creep crack growth results were obtained in helium to compare with the air results. It was shown that pure fatigue crack growth behavior can be described by linear elastic fracture mechanics up to 1273 K. An example of Hastelloy-X at 1223 K proves that evaluating fatigue crack growth according to the J intergral concept gives, within a small scatterband, the same results as by following the linear elastic concept. Hastelloy-X shows a decreasing fracture toughness with increasing temperatures. It is emphasized that the J integral concept holds only if creep deformation can be neglected. The experimental evidence at highest temperatures shows that the J integral R curve is not at all similar to that found at lower temperatures under ideal conditions. Creep crack growth for Nimonic-86 at 1073 less than or equal to T/K less than or equal to 1273 shows that crack growth at 1223 K in helium is found to be larger than in air. Problems arise when correlating the creep crack growth results. The application of the energy rate integral C* seems promising, but this has yet to be proven. A combination of long-term creep with fatigue crack growth is presently impossible.

Krompholz, K.; Bodmann, E.; Gnirss, G.K.; Huthmann, H.

1984-08-01T23:59:59.000Z

453

A high temperature fatigue life prediction computer code based on the total strain version of StrainRange Partitioning (SRP)  

SciTech Connect

A recently developed high-temperature fatigue life prediction computer code is presented and an example of its usage given. The code discussed is based on the Total Strain version of Strainrange Partitioning (TS-SRP). Included in this code are procedures for characterizing the creep-fatigue durability behavior of an alloy according to TS-SRP guidelines and predicting cyclic life for complex cycle types for both isothermal and thermomechanical conditions. A reasonably extensive materials properties database is included with the code.

Mcgaw, M.A.; Saltsman, J.F.

1993-10-01T23:59:59.000Z

454

DEVELOPMENT OF HIGH PERFORMANCE BS-PT BASED PIEZOELECTRIC TRANSDUCERS FOR HIGH-TEMPERATURE  

E-Print Network (OSTI)

-TEMPERATURE APPLICATIONS Yu-Hung Li1 , Sang Jong Kim2 , Nathan Salowitz2 , Fu-Kuo Chang2 1 Department of Materials Science processes in industries like aerospace. However, similar ultrasonic SHM techniques for high downhole casings). Recent research in high-temperature piezoelectric materials has facilitated

Boyer, Edmond

455

High Country Rose Greenhouses Greenhouse Low Temperature Geothermal  

Open Energy Info (EERE)

Country Rose Greenhouses Greenhouse Low Temperature Geothermal Country Rose Greenhouses Greenhouse Low Temperature Geothermal Facility Jump to: navigation, search Name High Country Rose Greenhouses Greenhouse Low Temperature Geothermal Facility Facility High Country Rose Greenhouses Sector Geothermal energy Type Greenhouse Location Helena, Montana Coordinates 46.6002123°, -112.0147188° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[]}

456

Adaptable Sensor Packaging for High Temperature Fossil Fuel Energy System  

NLE Websites -- All DOE Office Websites (Extended Search)

Adaptable Sensor Packaging for High Adaptable Sensor Packaging for High Temperature Fossil Fuel Energy Systems Background The Advanced Research Sensors and Controls Program is leading the effort to develop sensing and control technologies and methods to achieve automated and optimized intelligent power systems. The program is led by the U.S. Department of Energy (DOE) Office of Fossil Energy National Energy Technology Laboratory (NETL) and is implemented through research and development agreements with other

457

Silicide-matrix materials for high-temperature applications  

SciTech Connect

Intermetallic-matrix composites are attractive alternatives to carbon/carbon and ceramic/ceramic composities for applications up to 1,600 C. Recent work on the intermetallic compounds MoSi2 and Ti5Si3 has included determination of their mechanical properties and deformation behavior, selection of thermodynamically compatible high-strength and ductile reinforcements, and strengthening and toughening mechanisms in silicide-matrix composites for high-temperature service. 11 refs.

Meschter, P.J.; Schwartz, D.S. (McDonnell Douglas Research Laboratories, Saint Louis, MO (USA))

1989-11-01T23:59:59.000Z

458

A novel low Cr-containing FeCrCo alloy for metallic interconnects in planar intermediate temperature solid oxide fuel cells  

Science Journals Connector (OSTI)

Abstract A newly developed low-Cr containing FeCrCo alloy, named as FeCro, is evaluated as a candidate material of metallic interconnects for intermediate temperature solid oxide fuel cells (IT-SOFCs). This alloy possesses excellent oxidation resistance and adequate electrical conductivity at 750C in air, and shows slight Cr deposition in/around La0.72Sr0.18MnO3(LSM) electrode under a harsh accelerating condition of 400mAcm?2 and 850C. The thickness of the oxide scale thermally grown at 750C in air for 1000 his less than 1?m, presenting a double-layered structure with dense (Mn, Cr)3O4 on the top of Cr2O3. The oxidation kinetics at 750C obeys the parabolic law with a low rate constant of1.42נ10?15g2cm?4s?1. The Cr deposition in/around the LSM electrode in the presence of the FeCro alloy is remarkably reduced, compared to the commercial Crofer 22H alloy. The measured area specific resistance (ASR) at 750C in air after 1000h isothermal oxidation is 14m?cm2. It is the unique microstructure of the formed oxide scale that significantly enhances the resistances of the FeCro alloy to oxidation and Cr volatilization.

Wenying Zhang; Dong Yan; Jie Yang; Jing Chen; Bo Chi; Jian Pu; Jian Li

2014-01-01T23:59:59.000Z

459

Modular Pebble Bed Reactor High Temperature Gas Reactor  

E-Print Network (OSTI)

Modular Pebble Bed Reactor High Temperature Gas Reactor Andrew C Kadak Massachusetts Institute For 1150 MW Combined Heat and Power Station Oil Refinery Hydrogen Production Desalinization Plant VHTR/Graphite Discrimination system Damaged Sphere ContainerGraphiteReturn FuelReturn Fresh Fuel Container Spent Fuel Tank #12

460

Titanium dioxide based high temperature carbon monoxide selective sensor  

E-Print Network (OSTI)

Titanium dioxide based high temperature carbon monoxide selective sensor Nancy O. Savagea , Sheikh as a trap for the oxidation products of CO and CH4. Upon oxidation of CO on ALC, carbonate species were detected, whereas the reaction of CH4 produced negligible carbonate species. The insensitivity of the ALC

Dutta, Prabir K.

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Free energy of Lorentz-violating QED at high temperature  

E-Print Network (OSTI)

In this paper we study the one- and two-loop contribution to the free energy in QED with the Lorentz symmetry breaking introduced via constant CPT-even Lorentz-breaking parameters at the high temperature limit. We find the impact of the Lorentz-violating term for the free energy and carry out a numerical estimation for the Lorentz-breaking parameter.

M. Gomes; T. Mariz; J. R. Nascimento; A. Yu. Petrov; A. F. Santos; A. J. da Silva

2009-10-23T23:59:59.000Z

462

Free energy of Lorentz-violating QED at high temperature  

Science Journals Connector (OSTI)

In this paper we study the one- and two-loop contribution to the free energy in QED with Lorentz symmetry breaking introduced via constant CPT-even Lorentz-breaking parameters at the high temperature limit. We find the impact of the Lorentz-violating term for the free energy and carry out a numerical estimation for the Lorentz-breaking parameter.

M. Gomes; T. Mariz; J. R. Nascimento; A. Yu. Petrov; A. F. Santos; A. J. da Silva

2010-02-17T23:59:59.000Z

463

High Temperature and Pressure reactive flows through porous media.  

E-Print Network (OSTI)

of Ceramic Matrix Composite (CMC), used as high temperature material for combustion chamber or stagnation and chemical composition (Gas Chromatograph, Mass Spectrometer, Infra-Red spectrometer) in stationary and transient conditions. The tests on metallic and composite samples have been conducted with N2, CH4, H2+CH4

Boyer, Edmond

464

Sulfonated Polybenzimidazoles for High Temperature PEM Fuel Cells  

Science Journals Connector (OSTI)

Sulfonated Polybenzimidazoles for High Temperature PEM Fuel Cells ... An optimization series of polymerizations with final polymer concentrations from 2.5 to 6.0 wt % was conducted and the inherent viscosity of each polymer was measured. ... The membrane with an optimized compn. ...

Jordan A. Mader; Brian C. Benicewicz

2010-07-28T23:59:59.000Z

465

High temperature, permanent magnet biased, homopolar magnetic bearing actuator  

E-Print Network (OSTI)

current resistance and improves the system efficiency because the magnetic field of the HTPM can suspend the major portion of the static load on bearing. A high temperature radial magnetic bearing was designed via an iterative search employing 3D finite...

Hossain, Mohammad Ahsan

2006-10-30T23:59:59.000Z

466

Selection of materials for high temperature sensible energy storage  

Science Journals Connector (OSTI)

Abstract Availability of thermal energy storage systems (TES) is a key to ensuring continuous power supply from solar thermal power plants. The application of sensible heat storage (SHS) in solid media is an attractive economic option, but is dependent on identifying suitable SHS media. Given the growing number of new materials available today, finding a suitable material is a time-consuming and difficult process. This paper demonstrates the use of a materials selection software package and identifies suitable SHS materials for high temperature (>500C) TES systems. The environmental performance of some selected materials was also evaluated using the package. Common materials such as alumina, silicon carbide, high temperature concrete, graphite, cast iron and steel were found to be highly suitable for SHS for the duty considered (500750C). For cost comparison, a simple heat exchanger, consisting of a packed bed of the materials (in brick or block form) heated by an inert gas, was considered. On the basis of equivalent gas phase heat transfer, high alumina cement concrete blocks had the lowest cost, followed by a common refractory brick at High temperature concretes, such as the high alumina cement-based materials and aluminasilicate geoploymers, were identified as having potential for SHS media as they are cheap composite materials. Their thermophysical properties could be optimised for SHS by a suitable choice of aggregates, binders and additives.

S. Khare; M. Dell'Amico; C. Knight; S. McGarry

2013-01-01T23:59:59.000Z

467

The performance of High-Temperature Reactor fuel particles at extreme temperatures  

SciTech Connect

Coated particles embedded in graphitic elements are the fuel for the High-Temperature Reactor (HTR). Experimental investigations of the performance of particles at extremely high temperatures have been conducted to achieve an understanding of coating failure mechanisms and to establish the data base for safety and risk analyses of hypothetical accidents in large- and medium-sized HTRs. The primary mechanism for coating failure and fission product release in the 1900 to 2500/sup 0/C temperature range is thermal decomposition of silicon carbide (SiC). Heating tests have provided the activation energy of this process and the correlation of SiC decomposition with coating failure and subsequent fission product release.

Nabielek, H.; Schenk, W.; Heit, W.; Mehner, A.W.; Goodin, D.T.

1989-01-01T23:59:59.000Z

468

Towards the development of high temperature comparison artifacts for radiation thermometry  

SciTech Connect

This paper describes the methodology and first results of the development of high temperature fixed point artifacts of unknown temperature suitable for scale comparison purposes. This study is being undertaken at the Thermal Metrology Division of Inmetro, Brazil, as part of PhD studies. In this initial phase of the study two identical cobalt carbon eutectic cells were constructed and one doped with a known amount of copper. This was an attempt to achieve a controlled change in the transition temperature of the alloy during melting. Copper was chosen due to the relatively simple phase diagram it forms with carbon and cobalt. The cobalt, in powder form, was supplied by Alfa Aesar at 99.998 % purity, and was mixed with carbon powder (1,9 % by weight) of 99.9999 % purity. Complete filling of the crucible took 6 steps and was performed in a vertical furnace with graphite heating elements, in an inert gas atmosphere. The temperature measurements were performed using a KE LP3 radiation thermometer, which was previously evaluated for spectral responsivity, linearity and size-of-source effect (SSE). During these measurements, the thermometer stability was periodically checked using a silver fixed point blackbody maintained in a three zone furnace. The main purpose of the first part of this study is to dope a series of Co-C blackbody with differing amounts of copper, in order to alter their temperatures whilst still retaining good melting plateau performance. The long-term stability of the adjusted transition temperatures will also be investigated. Other dopants will be studied as the research progresses, and thermo chemical modeling will be performed in an attempt to understand the change in temperature with dopant concentration and so help select suitable dopants in the future. The overall objective is to construct comparison artifacts that have good performance, in terms of plateau shape and long-term temperature stability, but with unknown temperatures. These can then be used as comparison artifacts with no participant, except the pilot, knowing the temperature a priori.

Teixeira, R. N. [Inmetro, Duque de Caxias, RJ (Brazil)] [Inmetro, Duque de Caxias, RJ (Brazil); Machin, G. [NPL, Teddington (United Kingdom)] [NPL, Teddington (United Kingdom); Orlando, A. [PUC-Rio, Rio de Janeiro, RJ (Brazil)] [PUC-Rio, Rio de Janeiro, RJ (Brazil)

2013-09-11T23:59:59.000Z

469

Low-temperature solution synthesis of alloys and intermetallic compounds as nanocrystals  

E-Print Network (OSTI)

were synthesized via solution techniques where metal compounds are reduced by NaBH4 or n-butyllithium at temperatures below 300C. To form hollow particles, metal nanoparticles of Co, Ni, Pb were synthesized via reduction by NaBH4 in water and reacted...

Vasquez, Yolanda

2009-05-15T23:59:59.000Z

470

High Strain-Rate Response of High Purity Aluminum at Temperatures Approaching Melt  

SciTech Connect

High-temperature, pressure-shear plate impact experiments were conducted to investigate the rate-controlling mechanisms of the plastic response of high-purity aluminum at high strain rates (10{sup 6} s{sup -1}) and at temperatures approaching melt. Since the melting temperature of aluminum is pressure dependent, and a typical pressure-shear plate impact experiment subjects the sample to large pressures (2 GPa-7 GPa), a pressure-release type experiment was used to reduce the pressure in order to measure the shearing resistance at temperatures up to 95% of the current melting temperature. The measured shearing resistance was remarkably large (50 MPa at a shear strain of 2.5) for temperatures this near melt. Numerical simulations conducted using a version of the Nemat-Nasser/Isaacs constitutive equation, modified to model the mechanism of geometric softening, appear to capture adequately the hardening/softening behavior observed experimentally.

Grunschel, S E; Clifton, R J; Jiao, T

2010-01-28T23:59:59.000Z

471

Oxidation of advanced steam turbine alloys  

SciTech Connect

Advanced or ultra supercritical (USC) steam power plants offer the promise of higher efficiencies and lower emissions. Current goals of the U.S. Department of Energys Advanced Power Systems Initiatives include coal generation at 60% efficiency, which would require steam temperatures of up to 760C. This research examines the steamside oxidation of advanced alloys for use in USC systems, with emphasis placed on alloys for high- and intermediate-pressure turbine sections.

Holcomb, G.R.; Covino, B.S., Jr.; Bullard, S.J.; Ziomek-Moroz, M.

2006-03-01T23:59:59.000Z

472

Particle-hole symmetry broken pseudogap in high temperature superconductors  

NLE Websites -- All DOE Office Websites (Extended Search)

Particle-hole symmetry broken pseudogap in Particle-hole symmetry broken pseudogap in high temperature superconductors High-temperature (Tc) superconductivity is one of the most important topics in condensed matter physics. Despite extensive studies over more than two decades, the microscopic mechanism of high temperature superconductivity still remains elusive due to many unconventional properties that are not well understood. Among them, the most mysterious behavior of high-Tc superconductor is the nature of so called "pseudogap", which has been a focus of the field for many years. In conventional superconductors, a gap exists in the energy absorption spectrum only below Tc, corresponding to the energy price to pay for breaking a Cooper pair of electrons. In high-Tc cuprate superconductors, an energy gap called the pseudogap exists above Tc but below T*, and is controversially attributed either to pre-formed superconducting pairs or to competing phases. Recently, by carefully studying the "symmetry" of the gap, researchers Makoto Hashimoto and Rui-Hua He, along with their co-workers in Prof. Zhi-Xun Shen's group at Stanford University, have found crucial evidence suggesting that the particle-hole symmetry required by superconductivity is broken in the pseudogap state.

473

Shock-induced synthesis of high temperature superconducting materials  

DOE Patents (OSTI)

It has now been determined that the unique features of the high pressure shock method, especially the shock-induced chemical synthesis technique, are fully applicable to high temperature superconducting materials. Extraordinarily high yields are achievable in accordance with this invention, e.g., generally in the range from about 20% to about 99%, often in the range from about 50% to about 90%, lower and higher yields, of course, also being possible. The method of this invention involves the application of a controlled high pressure shock compression pulse which can be produced in any conventional manner, e.g., by detonation of a high explosive material, the impact of a high speed projectile or the effect of intense pulsed radiation sources such as lasers or electron beams. Examples and a discussion are presented.

Ginley, D.S.; Graham, R.A.; Morosin, B.; Venturini, E.L.

1987-06-18T23:59:59.000Z

474

Note: Zeeman splitting measurements in a high-temperature plasma  

SciTech Connect

The Zeeman effect has been used for measurement of magnetic fields in low-temperature plasma, but the diagnostic technique is difficult to implement in a high-temperature plasma. This paper describes new instrumentation and methodology for simultaneous measurement of the entire Doppler-broadened left and right circularly polarized Zeeman spectra in high-temperature plasmas. Measurements are made using spectra emitted parallel to the magnetic field by carbon impurities in high-temperature plasma. The Doppler-broadened width is much larger than the magnitude of the Zeeman splitting, thus simultaneous recording of the two circularly polarized Zeeman line profiles is key to accurate measurement of the magnetic field in the ZaP Z-pinch plasma device. Spectral data are collected along multiple chords on both sides of the symmetry axis of the plasma. This enables determination of the location of the current axis of the Z-pinch and of lower-bound estimates of the local magnetic field at specific radial locations in the plasma.

Golingo, R. P.; Shumlak, U.; Den Hartog, D. J. [Aerospace and Energetics Research Program, University of Washington, Seattle, Washington 98195-2250 (United States)

2010-12-15T23:59:59.000Z

475

A high pressure, high temperature study of 1,1-diamino-2,2-dinitro ethylene  

SciTech Connect

We report a synchrotron energy-dispersive X-ray diffraction study of the novel high explosive 1,1-diamino-2,2-dinitroethylene at high pressures and high temperatures. Pressure was generated using a Paris-Edinburgh cell to employ larger sample volumes. High temperatures were created using a resistive graphite cylinder surrounding the sample. The PT phase diagram was explored in the 3.3 GPa pressure range and in the {approx} 400 C temperature range. We believe that the sample commenced in the {alpha}-phase and then ended up in an amorphous phase when the temperature increased beyond 280 C near 2 GPa, which we believe to be the {gamma}-phase. Further pressure and temperature cycling suggests that the sample transformed reversibly into and out of the amorphous phase near the phase line.

Pravica, Michael; Galley, Martin; Park, Changyong; Ruiz, Harrison; Wojno, Jennifer (UNLV); (CIW)

2012-08-29T23:59:59.000Z

476

Optimum Reactor Outlet Temperatures for High Temperature Gas-Cooled Reactors Integrated with Industrial Processes  

SciTech Connect

This report summarizes the results of a temperature sensitivity study conducted to identify the optimum reactor operating temperatures for producing the heat and hydrogen required for industrial processes associated with the proposed new high temperature gas-cooled reactor. This study assumed that primary steam outputs of the reactor were delivered at 17 MPa and 540C and the helium coolant was delivered at 7 MPa at 625925C. The secondary outputs of were electricity and hydrogen. For the power generation analysis, it was assumed that the power cycle efficiency was 66% of the maximum theoretical efficiency of the Carnot thermodynamic cycle. Hydrogen was generated via the hightemperature steam electrolysis or the steam methane reforming process. The study indicates that optimum or a range of reactor outlet temperatures could be identified to further refine the process evaluations that were developed for high temperature gas-cooled reactor-integrated production of synthetic transportation fuels, ammonia, and ammonia derivatives, oil from unconventional sources, and substitute natural gas from coal.

Lee O. Nelson

2011-04-01T23:59:59.000Z

477

High temperature gas cooled reactor steam-methane reformer design  

SciTech Connect

The concept of the long distance transportation of process heat energy from a High Temperature Gas Cooled Reactor (HTGR) heat source, based on the steam-methane reforming reaction, is being evaluated by the Department of Energy as an energy source/application for use early in the 21st century. This paper summaries the design of a helium heated steam reformer utilized in conjunction with an intermediate loop, 850/degree/C reactor outlet temperature, HTGR process heat plant concept. This paper also discusses various design considerations leading to the mechanical design features, the thermochemical performance, the materials selection and the structural design analysis. 12 refs.

Impellezzeri, J.R.; Drendel, D.B.; Odegaard, T.K.

1981-01-01T23:59:59.000Z

478

Sealed glass coating of high temperature ceramic superconductors  

DOE Patents (OSTI)

A method and article of manufacture of a lead oxide based glass coating on a high temperature superconductor is disclosed. The method includes preparing a dispersion of glass powders in a solution, applying the dispersion to the superconductor, drying the dispersion before applying another coating and heating the glass powder dispersion at temperatures below oxygen diffusion onset and above the glass melting point to form a continuous glass coating on the superconductor to establish compressive stresses which enhance the fracture strength of the superconductor. 8 figs.

Wu, W.; Chu, C.Y.; Goretta, K.C.; Routbort, J.L.

1995-05-02T23:59:59.000Z

479

Localized effects of macrofouling species on electrochemical corrosion of high grade alloys  

SciTech Connect

Interactions between macrofouling and corrosion on some stainless steels, UNS N06625 and UNS R30006 have been studied in long-term tests conducted in natural seawater off the west coast of Scotland. After a 18-month exposure period, the specimens were heavily fouled primarily with barnacles and mussels and all the materials exhibited crevice corrosion although this was less extensive on the Ni-base alloy. Localized corrosion was observed under the base of live barnacles on UNS S31603 stainless steel. DC electrochemical anodic polarization tests undertaken after the 18-month exposure period, yielded unusually high currents in the range of potential between the free corrosion value and the breakdown potential. This observation was associated with the appearance, after the anodic polarization, of black sulfide corrosion products at the specimen/resin crevices, around barnacles and around mussel byssus threads.

Hodgkiess, T. [Univ. of Glasgow (United Kingdom). Dept. of Mechanical Engineering; Nevilie, A. [Heriot Watt Univ., Edinburgh (United Kingdom). Dept. of Mechanical and Chemical Engineering

1998-12-31T23:59:59.000Z

480

Electric-field dependence of pairing temperature and tunneling in high-temperature superconductors  

Science Journals Connector (OSTI)

Using the Bethe-Salpeter equation including high electric fields, the dependence of the critical temperature of onsetting superconductivity on the applied field is calculated analytically. The critical temperature of pairing is shown to increase with the applied field strength. This is a new field effect and could contribute to the explanation of recent experiments on field-induced superconductivity. From the field dependence of the Bethe-Salpeter equation, the two-particle bound-state solution is obtained as a resonance with a tunneling probability analogous to the WKB solution of a single particle confined in a potential and coupled to an electrical field.

K. Morawetz

2002-11-27T23:59:59.000Z