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Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

High Temperature Shape Memory Alloys  

Science Conference Proceedings (OSTI)

Mar 5, 2013 ... Shape Memory Response of NiTiHfPd High Strength and High Hysteresis Shape Memory Alloys: Emre Acar1; Haluk Karaca1; Hirobumi Tobe1; ...

2

High-temperature alloys for high-power thermionic systems  

DOE Green Energy (OSTI)

The need for structural materials with useful strength above 1600 k has stimulated interest in refractory-metal alloys. Tungsten possesses an extreme high modulus of elasticity as well as the highest melting temperature among metals, and hence is being considered as one of the most promising candidate materials for high temperature structural applications such as space nuclear power systems. This report is divided into three chapters covering the following: (1) the processing of tungsten base alloys; (2) the tensile properties of tungsten base alloys; and (3) creep behavior of tungsten base alloys. Separate abstracts were prepared for each chapter. (SC)

Shin, Kwang S.; Jacobson, D.L.; D'cruz, L.; Luo, Anhua; Chen, Bor-Ling.

1990-08-01T23:59:59.000Z

3

Environmental Degradation and Protection of High Temperature Alloys  

Science Conference Proceedings (OSTI)

Scope, Nickel-base superalloys and other high temperature alloys have been successfully used in turbine engine propulsion, power generation and many other ...

4

Creep Behavior of High Temperature Alloys for Generation IV ...  

Science Conference Proceedings (OSTI)

Presentation Title, Creep Behavior of High Temperature Alloys for Generation IV Nuclear Power Plant Applications. Author(s), Xingshuo Wen, Laura J. Carroll, ...

5

High Temperature Stainless Steel Alloy with Low Cost Manganese  

High Temperature Stainless Steel Alloy with Low Cost Manganese ... ••Power industry components such as boiler tubing and piping, pressure vessels, chemical

6

Creep Behavior of High Temperature Alloys for Intermediate Heat ...  

Science Conference Proceedings (OSTI)

Presentation Title, Creep Behavior of High Temperature Alloys for Intermediate Heat Exchanger in Next Generation Nuclear Plant. Author(s), Xingshuo Wen, ...

7

Ir-based alloys for ultra-high temperature applications ...  

Site Map; Printable Version; Share this resource. Send a link to Ir-based alloys for ultra-high temperature applications - Energy Innovation Portalto someone by E-mail

8

Ductile aluminide alloys for high temperature applications  

DOE Patents (OSTI)

Alloys are described which contain nickel, aluminum, boron, iron and in some instances manganese, niobium and titanium.

Liu, Chain T. (Oak Ridge, TN); Koch, Carl C. (Oak Ridge, TN)

1987-01-01T23:59:59.000Z

9

Ductile aluminide alloys for high temperature applications  

DOE Patents (OSTI)

Improved Ni.sub.3 Al alloys are provided by inclusion of boron, hafnium or zirconium, and in some species, iron.

Liu, Chain T. (Oak Ridge, TN); Stiegler, James O. (Lenoir City, TN)

1986-01-01T23:59:59.000Z

10

Computational and Experimental Development of Novel High-Temperature Alloys  

NLE Websites -- All DOE Office Websites (Extended Search)

Development of Novel High-Temperature Alloys Background The need for fossil-fueled power plants to run cleaner and more efficiently leads toward ever-higher operating temperatures and pressures. Gas turbines, which can be fueled by natural gas, synthetic gas (syngas), or a high-hydrogen stream derived from coal, are critical components in this development. High-temperature operation of turbines is generally achieved by using nickel-chrome superalloys with coatings

11

Iron aluminide alloys with improved properties for high temperature applications  

DOE Patents (OSTI)

An improved iron aluminide alloy of the DO[sub 3] type is described that has increased room temperature ductility and improved high elevated temperature strength. The alloy system further is resistant to corrosive attack in the environments of advanced energy conversion systems such as those using fossil fuels. The resultant alloy is relatively inexpensive as contrasted to nickel based and high nickel steels currently utilized for structural components. The alloy system consists essentially of 26--30 at. % aluminum, 0.5--10 at. % chromium, 0.02--0.3 at. % boron plus carbon, up to 2 at. % molybdenum, up to 1 at. % niobium, up to 0.5 at. % zirconium, up to 0.1 at. % yttrium, up to 0.5 at. % vanadium and the balance iron. 3 figs.

McKamey, C.G.; Liu, C.T.

1990-10-09T23:59:59.000Z

12

Iron aluminide alloys with improved properties for high temperature applications  

DOE Patents (OSTI)

An improved iron aluminide alloy of the DO.sub.3 type that has increased room temperature ductility and improved high elevated temperature strength. The alloy system further is resistant to corrosive attack in the environments of advanced energy corrosion systems such as those using fossil fuels. The resultant alloy is relatively inexpensive as contrasted to nickel based and high nickel steels currently utilized for structural components. The alloy system consists essentially of 26-30 at. % aluminum, 0.5-10 at. % chromium, 0.02-0.3 at. % boron plus carbon, up to 2 at. % molybdenum, up to 1 at. % niobium, up to 0.5 at. % zirconium, up to 0.1 at. % yttrium, up to 0.5 at. % vanadium and the balance iron.

McKamey, Claudette G. (Knoxville, TN); Liu, Chain T. (Oak Ridge, TN)

1990-01-01T23:59:59.000Z

13

Improved high temperature creep resistant austenitic alloy  

DOE Patents (OSTI)

An improved austenitic alloy having in wt% 19-21 Cr, 30-35 Ni, 1.5-2.5 Mn, 2-3 Mo, 0.1-0.4 Si, 0.3-0.5 Ti, 0.1-0.3 Nb, 0.1-0.5 V, 0.001-0.005 P, 0.08-0.12 C, 0.01-0.03 N, 0.005-0.01 B and the balance iron that is further improved by annealing for up to 1 hour at 1150-1200/degree/C and then cold deforming 5-15%. The alloy exhibits dramatically improved creep rupture resistance and ductility at 700/degree/C. 2 figs.

Maziasz, P.J.; Swindeman, R.W.; Goodwin, G.M.

1988-05-13T23:59:59.000Z

14

High-temperature Hydrogen Permeation in Nickel Alloys  

DOE Green Energy (OSTI)

In gas cooled Very High Temperature Reactor concepts, tritium is produced as a tertiary fission product and by activation of graphite core contaminants, such as lithium; of the helium isotope, He-3, that is naturally present in the He gas coolant; and the boron in the B4C burnable poison. Because of its high mobility at the reactor outlet temperatures, tritium poses a risk of permeating through the walls of the intermediate heat exchanger (IHX) or steam generator (SG) systems, potentially contaminating the environment and in particular the hydrogen product when the reactor heat is utilized in connection with a hydrogen generation plant. An experiment to measure tritium permeation in structural materials at temperatures up to 1000 C has been constructed at the Idaho National Laboratory Safety and Tritium Applied Research (STAR) facility within the Next Generation Nuclear Plant program. The design is based on two counter flowing helium loops to represent heat exchanger conditions and was optimized to allow control of the materials surface condition and the investigation of the effects of thermal fatigue. In the ongoing campaign three nickel alloys are being considered because of their high-temperature creep properties, alloy 617, 800H and 230. This paper introduces the general issues related to tritium in the on-going assessment of gas cooled VHTR systems fission product transport and outlines the planned research activities in this area; outlines the features and capabilities of the experimental facility being operated at INL; presents and discusses the initial results of hydrogen permeability measurements in two of the selected alloys and compares them with the available database from previous studies.

P. Calderoni; M. Ebner; R. Pawelko

2010-10-01T23:59:59.000Z

15

High pressure/high temperature hydrogen permeability in candidate Stirling engine alloys  

SciTech Connect

Hydrogen permeation tests of eight high-temperature alloys were conducted in 20.7 MPa hydrogen at 923 to 1088 K for assessing suitability in Stirling engine application for heater head and heater head tubing. The iron-nickel-base alloys investigated included N-155, Incoloy 800 (IN 800), A-286, and 19-9DL, and cast alloys CRM-6D, SAF-11, and XF-818. Low carbon alloys Stellite 6B (6BLC), a cobalt-base wrought alloy, was also investigated. 15 refs.

Bhattacharyya, S.; Vesely, E.J. Jr.; Hill, V.L.

1982-03-01T23:59:59.000Z

16

Two-phase chromium-niobium alloys exhibiting improved mechanical properties at high temperatures  

DOE Patents (OSTI)

The specification discloses chromium-niobium alloys which exhibit improved mechanical properties at high temperatures in the range of 1250.degree. C. and improved room temperature ductility. The alloys contain a Cr.sub.2 Nb-rich intermetallic phase and a Cr-rich phase with an overall niobium concentration in the range of from about 5 to about 18 at. %. The high temperature strength is substantially greater than that of state of the art nickel-based superalloys for enhanced high temperature service. Further improvements in the properties of the compositions are obtained by alloying with rhenium and aluminum; and additional rare-earth and other elements.

Liu, Chain T. (Oak Ridge, TN); Takeyama, Masao (Tokyo, JP)

1994-01-01T23:59:59.000Z

17

Two-phase chromium-niobium alloys exhibiting improved mechanical properties at high temperatures  

DOE Patents (OSTI)

The specification discloses chromium-niobium alloys which exhibit improved mechanical properties at high temperatures in the range of 1250 C and improved room temperature ductility. The alloys contain a Cr[sub 2]Nb-rich intermetallic phase and a Cr-rich phase with an overall niobium concentration in the range of from about 5 to about 18 at. %. The high temperature strength is substantially greater than that of state of the art nickel-based superalloys for enhanced high temperature service. Further improvements in the properties of the compositions are obtained by alloying with rhenium and aluminum; and additional rare-earth and other elements. 14 figures.

Liu, C.T.; Takeyama, Masao.

1994-02-01T23:59:59.000Z

18

Evaluation of High-Temperature Alloys for Helium Gas Turbines  

Science Conference Proceedings (OSTI)

C. 1. Mechanical Property / Status of Metallic Materials Development for Application in Advanced High-Temperature Gas-Cooled Reactor / Material

Wolfgang Jakobeit; Jörn-Peter Pfeifer; Georg Ullrich

19

Corrosion of Candidate Alloys in High Temperature Supercritical  

Science Conference Proceedings (OSTI)

Materials corrosion in high temperature supercritical CO2 will be an important consideration for this application. The results of corrosion evaluations of a wide ...

20

Materials Properties Database for Selection of High-Temperature Alloys and Concepts of Alloy Design for SOFC Applications  

Science Conference Proceedings (OSTI)

To serve as an interconnect / gas separator in an SOFC stack, an alloy should demonstrate the ability to provide (i) bulk and surface stability against oxidation and corrosion during prolonged exposure to the fuel cell environment, (ii) thermal expansion compatibility with the other stack components, (iii) chemical compatibility with adjacent stack components, (iv) high electrical conductivity of the surface reaction products, (v) mechanical reliability and durability at cell exposure conditions, (vii) good manufacturability, processability and fabricability, and (viii) cost effectiveness. As the first step of this approach, a composition and property database was compiled for high temperature alloys in order to assist in determining which alloys offer the most promise for SOFC interconnect applications in terms of oxidation and corrosion resistance. The high temperature alloys of interest included Ni-, Fe-, Co-base superal

Yang, Z Gary; Paxton, Dean M.; Weil, K. Scott; Stevenson, Jeffry W.; Singh, Prabhakar

2002-11-24T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Copper modified austenitic stainless steel alloys with improved high temperature creep resistance  

DOE Patents (OSTI)

An improved austenitic stainless steel that incorporates copper into a base Fe-Ni-Cr alloy having minor alloying substituents of Mo, Mn, Si, T, Nb, V, C, N, P, B which exhibits significant improvement in high temperature creep resistance over previous steels. 3 figs.

Swindeman, R.W.; Maziasz, P.J.

1987-04-28T23:59:59.000Z

22

Iron-niobium-aluminum alloy having high-temperature corrosion resistance  

DOE Patents (OSTI)

An alloy for use in high temperature sulfur and oxygen containing environments, having aluminum for oxygen resistance, niobium for sulfur resistance and the balance iron, is discussed. 4 figs., 2 tabs.

Hsu, Huey S.

1988-04-14T23:59:59.000Z

23

Modification of Alloy 706 for High Temperature Steam Turbine Rotor ...  

Science Conference Proceedings (OSTI)

Alloy706 is a gas-turbine disk material. However, since Alloy706 suffers from a solidification defect (freckle defect) due to segregation of Nb, it is difficult to make  ...

24

(Ni,Pt)Ti High Temperature Shape Memory Alloys  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, Materials Science & Technology 2011. Symposium, Shape Memory Alloys. Presentation Title, Phase Field Modeling of P-Phase ...

25

High Temperature Degradation of Alloy 718 after Longtime Exposures  

Science Conference Proceedings (OSTI)

Idaho National Engineering Laboratory. Idaho Falls, ID 834152218. Abstract. An isothermal aging study was carried out on alloy 718 for up to 50,000 hours in a.

26

Creep Behavior of High Temperature Alloys as Structural Materials ...  

Science Conference Proceedings (OSTI)

Symposium, Materials and Fuels for the Current and Advanced Nuclear Reactors II ... Alloys as Structural Materials in Generation IV Nuclear Power Plant.

27

Dynamic compressive behavior of Pr-Nd alloy at high strain rates and temperatures  

Science Conference Proceedings (OSTI)

Based on compressive tests, static on 810 material test system and dynamic on the first compressive loading in split Hopkinson pressure bar (SHPB) tests for Pr-Nd alloy cylinder specimens at high strain rates and temperatures, this study determined a J-C type [G. R. Johnson and W. H. Cook, in Proceedings of Seventh International Symposium on Ballistics (The Hague, The Netherlands, 1983), pp. 541-547] compressive constitutive equation of Pr-Nd alloy. It was recorded by a high speed camera that the Pr-Nd alloy cylinder specimens fractured during the first compressive loading in SHPB tests at high strain rates and temperatures. From high speed camera images, the critical strains of the dynamic shearing instability for Pr-Nd alloy in SHPB tests were determined, which were consistent with that estimated by using Batra and Wei's dynamic shearing instability criterion [R. C. Batra and Z. G. Wei, Int. J. Impact Eng. 34, 448 (2007)] and the determined compressive constitutive equation of Pr-Nd alloy. The transmitted and reflected pulses of SHPB tests for Pr-Nd alloy cylinder specimens computed with the determined compressive constitutive equation of Pr-Nd alloy and Batra and Wei's dynamic shearing instability criterion could be consistent with the experimental data. The fractured Pr-Nd alloy cylinder specimens of compressive tests were investigated by using 3D supper depth digital microscope and scanning electron microscope.

Wang Huanran; Cai Canyuan; Chen Danian [Mechanics and Materials Science Research Center, Ningbo University, Ningbo, Zhejiang 315211 (China); Ma Dongfang [Mechanics and Materials Science Research Center, Ningbo University, Ningbo, Zhejiang 315211 (China); School of Civil Engineering, Henan Polytechnic University, Jiaozuo, Henan 454000 (China)

2012-07-01T23:59:59.000Z

28

Amorphous Alloy Membranes for High Temperature Hydrogen Separations  

NLE Websites -- All DOE Office Websites (Extended Search)

for High for High Temperature Hydrogen Separations Background Coal and biomass are readily available in the United States and can be mixed for thermal processing to produce hydrogen and power. The produced hydrogen can be sent directly to a fuel cell for highly efficient and environmentally clean power generation. For coal and biomass to become economically viable sources of hydrogen, more efficient production processes need to be developed. To meet this

29

SCC Initiation in Alloy 600 Heat Affected Zones Exposed to High Temperature Water  

Science Conference Proceedings (OSTI)

Studies have shown that grain boundary chromium carbides improve the stress corrosion cracking (SCC) resistance of nickel based alloys exposed to high temperature, high purity water. However, thermal cycles from welding can significantly alter the microstructure of the base material near the fusion line. In particular, the heat of welding can solutionize grain boundary carbides and produce locally high residual stresses and strains, reducing the SCC resistance of the Alloy 600 type material in the heat affected zone (HAZ). Testing has shown that the SCC growth rate in Alloy 600 heat affected zone samples can be {approx}30x faster than observed in the Alloy 600 base material under identical testing conditions due to fewer intergranular chromium rich carbides and increased plastic strain in the HAZ [1, 2]. Stress corrosion crack initiation tests were conducted on Alloy 600 HAZ samples at 360 C in hydrogenated, deaerated water to determine if these microstructural differences significantly affect the SCC initiation resistance of Alloy 600 heat affected zones compared to the Alloy 600 base material. Alloy 600 to EN82H to Alloy 600 heat-affected-zone (HAZ) specimens where fabricated from an Alloy 600 to Alloy 600 narrow groove weld with EN82H filler metal. The approximate middle third of the specimen gauge region was EN82H such that each specimen had two HAZ regions. Tests were conducted with in-situ monitored smooth tensile specimens under a constant load, and a direct current electric potential drop was used for in-situ detection of SCC. Test results suggest that the SCC initiation resistance of Alloy 600 and its weld metal follows the following order: EN82H > Alloy 600 HAZ > Alloy 600. The high SCC initiation resistance observed to date in Alloy 600 heat affected zones compared to wrought Alloy 600 is unexpected based on the microstructure of HAZ versus wrought material and based on prior SCC growth rate studies. The observed behavior for the HAZ specimens is likely not related to differences in the environment, differences in surface stress/strain between the various specimen regions (weld, HAZ, wrought), differences in surface residual stress, or differences in the microstructure of the various specimen regions (weld, HAZ, wrought). The behavior may be related to differences in the creep behavior of the various weld regions or differences in the surface area of the various materials (weld, HAZ, wrought) exposed to high temperature water.

E Richey; DS Morton; RA Etien; GA Young; RB Bucinell

2006-11-03T23:59:59.000Z

30

Advanced Alloys for Compact, High-Efficiency, High-Temperature Heat-Exchangers  

Science Conference Proceedings (OSTI)

Oak Ridge National Laboratory (ORNL) has conducted research and development for several years which has been focused on the behavior and performance improvements of sheets and foils of various alloys for compact heat-exchangers (recuperators) for advanced microturbines. The performance and reliability of such thin sections are challenged at 650-750 C by fine grain size causing excessive creep, and by moisture effects greatly enhancing oxidation attack in exhaust gas environments. Standard 347 stainless steel has been used successfully at or below 600 C, but has suffered from both of these kinds of degradation at 650 C and above. Alloys have been identified which can have very good properties for such heat-exchangers, especially with careful control of microstructure during processing, including alloy 625, HR120 and the new AL20-25+Nb. These alloys, and the mechanistic understanding behind their behavior, are also applicable to achieving the better heat-exchanger technology needed for fuel cells or other high-temperature, clean-energy applications.

Maziasz, Philip J [ORNL; Pint, Bruce A [ORNL; Shingledecker, John P [ORNL; Evans, Neal D [ORNL; Yamamoto, Yukinori [ORNL; More, Karren Leslie [ORNL; Lara-Curzio, Edgar [ORNL

2006-01-01T23:59:59.000Z

31

Considerations of Alloy N for Fluoride Salt-Cooled High-Temperature Reactor Applications  

SciTech Connect

Fluoride Salt-Cooled High-Temperature Reactors (FHRs) are a promising new class of thermal-spectrum nuclear reactors. The reactor structural materials must possess high-temperature strength and chemical compatibility with the liquid fluoride salt as well as with a power cycle fluid such as supercritical water while remaining resistant to residual air within the containment. Alloy N was developed for use with liquid fluoride salts and it possesses adequate strength and chemical compatibility up to about 700 C. A distinctive property of FHRs is that their maximum allowable coolant temperature is restricted by their structural alloy maximum service temperature. As the reactor thermal efficiency directly increases with the maximum coolant temperature, higher temperature resistant alloys are strongly desired. This paper reviews the current status of Alloy N and its relevance to FHRs including its design principles, development history, high temperature strength, environmental resistance, metallurgical stability, component manufacturability, ASME codification status, and reactor service requirements. The review will identify issues and provide guidance for improving the alloy properties or implementing engineering solutions.

Ren, Weiju [ORNL; Muralidharan, Govindarajan [ORNL; Wilson, Dane F [ORNL; Holcomb, David Eugene [ORNL

2011-01-01T23:59:59.000Z

32

Flow Behavior of Three 625-Type Alloys During High Temperature ...  

Science Conference Proceedings (OSTI)

heat exchangers, and piping. The alloy ..... H.H. Ruble and S.L. Semiatin, Metal;s Handbook Ninth Edition (Metals Park, OH: ASM. International, 1988), 261-266.

33

Deployment of New High Temperature Alloys for Power Generation ...  

Science Conference Proceedings (OSTI)

Abstract Scope, Two Fe-base alloys developed at ORNL, alumina-forming austenitic (AFA) steel and cast austenitic CF8C-Plus, ... Definite: A CD-only volume ...

34

HIGH TEMPERATURE BRAZING ALLOY FOR JOINT Fe-Cr-Al MATERIALS AND AUSTENITIC AND FERRITIC STAINLESS STEELS  

DOE Patents (OSTI)

A new high temperature brazing alloy is described that is particularly suitable for brazing iron-chromiumaluminum alloys. It consists of approximately 20% Cr, 6% Al, 10% Si, and from 1.5 to 5% phosphorus, the balance being iron.

Cost, R.C.

1958-07-15T23:59:59.000Z

35

DEVELOPMENT AND PROPERTIES OF URANIUM-BASE ALLOYS CORROSION RESISTANT IN HIGH TEMPERATURE WATER. PART III. CORROSION MECHANISM OF URANIUM-BASE ALLOYS IN HIGH TEMPERATURE WATER  

DOE Green Energy (OSTI)

The factors affecting corrosion resistance both of bare and of clad uranium-base alloys are reviewed and a mechanism proposed for their corrosion behavior. For unclad gamma-phase uranium alloys exposed to a high temperature water corrodent, it is proposed that the corrosion rate is determined primarily by the oxidation of the alloy by water. This behavior is contrary to that of alpha uranium in which the corrosion rate is primarily determined by the formation and subsequent oxidation of a nonadherent hydride layer. In gamma- phase alloys the hydrogen released by the corrosion reaction, rather than forming the thermodynamically stable UH/sub 3/ phase, dissolves (at least in part) in the base metal where it precipitates as a metastable hydride. The amount of hydrogen absorbed by the metal and hence precipitating as the metastable hydride may be markedly reduced by the addition of hydrogen depolarizers such as nickel or platinum to the water or to the metal. Similarly the amount of absorbed hydrogen may be reduced by introducing sinks that preferentially absorb hydrogen. Both alpha uranium and zirconium were shown to be suitable sinks. Precipitated hydride hardens and embrittles the matrix and by its preferential corrosion eventually leads to discontinuous failure. The hydride may be made to precipitate in a less harmful manner by heat treatments which precipitate nucleating and hardening impurities. The mode of the precipitation is shown to be sensitive to stress; in fact, the assumption of elastic stress as contributing to hydride precipitation is considered necessary to explain the distribution of the precipitate during corrosion. In order to apply a gammaphase fuel alloy as a fuel element material, it is necessary primarily to reduce the amount of hydrogen absorbed by the fuel. This can be done by cladding the fuel with a zirconium- base alloy. Under such conditions it has been shown that fuel element lives in excess of 4 years should be obtainable with properly fabricated fuel elements before they are subject to corrosion failure. Optimum fuel element corrosion life can be achieved by decreasing the general corrosion rate, increasing the hydrogen solubility, increasing the hydrogen diffusion rate, and maintaining a proper clad-fuel bond. For uranium-base alloys such as U/sub 3/Si that do not form a hydride during hot water corrosion, use of a Zircaloy clad is unnecessary. Therefore, the development of alternate cladding materials such as Al for corrosion resistant fuel elements is predicted upon the development of uranium- base alloys that do not corrode by a hydride mechanism. In addition to U/sub 3/ both Zr-U alloys and the strained alpha uranium-base alloys do not appear to corrode by a hydride mechanism. (auth)

Burkart, M.W. ed.

1956-07-01T23:59:59.000Z

36

High Temperature Corrosion Behavior of Oxidation Resistant Alloys under SOFC Interconnect Dual Exposures  

Science Conference Proceedings (OSTI)

The steady reduction in SOFC operating temperatures has led to increased interest in using metals and alloys to construct the stack interconnects that are exposed simultaneously to a fuel at the anode-side and air at the cathode-side during SOFC operation. Previous work has found that the high temperature oxidation and corrosion behavior of alloys under the dual exposure conditions can be significantly different from that in a single atmosphere exposure. To fully understand the anomalous oxidation and corrosion behavior under the interconnect dual exposure conditions, a number of metals and alloys were investigated under a variety of conditions, including both hydrogen and hydrocarbon fuels. This paper will present details of this work and discuss our current understanding on the anomalous oxidation behavior of metals and alloys observed under the interconnect dual exposure conditions.

Yang, Z Gary; Coffey, Greg W.; Rice, Joseph P.; Singh, Prabhakar; Stevenson, Jeffry W.; Xia, Gordon

2006-02-03T23:59:59.000Z

37

Effect of High Temperature Aging on the Corrosion Resistance of Iron Based Amorphous Alloys  

SciTech Connect

Iron-based amorphous alloys can be more resistant to corrosion than polycrystalline materials of similar compositions. However, when the amorphous alloys are exposed to high temperatures they may recrystallize (or devitrify) thus losing their resistance to corrosion. Four different types of amorphous alloys melt spun ribbon specimens were exposed to several temperatures for short periods of time. The resulting corrosion resistance was evaluated in seawater at 90 C and compared with the as-prepared ribbons. Results show that the amorphous alloys can be exposed to 600 C for 1-hr. without losing the corrosion resistance; however, when the ribbons were exposed at 800 C for 1-hr. their localized corrosion resistance decreased significantly.

Day, S D; Haslam, J J; Farmer, J C; Rebak, R B

2007-08-10T23:59:59.000Z

38

Pu-Zr alloy for high-temperature foil-type fuel  

DOE Patents (OSTI)

A nuclear reactor fuel alloy consists essentially of from slightly greater than 7 to about 4 w/o zirconium, balance plutonium, and is characterized in that the alloy is castable and is rollable to thin foils. A preferred embodiment of about 7 w/o zirconium, balance plutonium, has a melting point substantially above the melting point of plutonium, is rollable to foils as thin as 0.0005 inch thick, and is compatible with cladding material when repeatedly cycled to temperatures above 650.degree. C. Neutron reflux densities across a reactor core can be determined with a high-temperature activation-measurement foil which consists of a fuel alloy foil core sandwiched and sealed between two cladding material jackets, the fuel alloy foil core being a 7 w/o zirconium, plutonium foil which is from 0.005 to 0.0005 inch thick.

McCuaig, Franklin D. (LaGrange, IL)

1977-01-01T23:59:59.000Z

39

Pu-ZR Alloy high-temperature activation-measurement foil  

DOE Patents (OSTI)

A nuclear reactor fuel alloy consists essentially of from slightly greater than 7 to about 4 w/o zirconium, balance plutonium, and is characterized in that the alloy is castable and is rollable to thin foils. A preferred embodiment of about 7 w/o zirconium, balance plutonium, has a melting point substantially above the melting point of plutonium, is rollable to foils as thin as 0.0005 inch thick, and is compatible with cladding material when repeatedly cycled to temperatures above 650.degree. C. Neutron flux densities across a reactor core can be determined with a high-temperature activation-measurement foil which consists of a fuel alloy foil core sandwiched and sealed between two cladding material jackets, the fuel alloy foil core being a 7 w/o zirconium, plutonium foil which is from 0.005 to 0.0005 inch thick.

McCuaig, Franklin D. (Westmont, IL)

1977-08-02T23:59:59.000Z

40

Consequences of water injection into high-temperature lithium-lead alloy breeder material  

Science Conference Proceedings (OSTI)

A fusion safety experiment was conducted to determine the consequences of water injection into high-temperature lithium-lead alloy under postulated reactor accident conditions. The temperature and pressure response, fraction of water reacted, quantity of hydrogen produced, and behavior of radioactive species associated with the use of this alloy as a breeder material were determined. The reaction products were identified and the aerosol was characterized for particle size, chemical composition, and deposition rate. The water injection was shown to be self limiting for a blanket module designed to withstand the pressure of the water coolant. Radioactive doses associated with the aerosol release from a high-temperature alloy breeder module were determined to be several orders of magnitude below the dose limit for acute health effects. The results were compared to previous experiments and recommendations were made. 5 refs., 7 figs., 6 tabs.

Jeppson, D.W. (Westinghouse Hanford Co., Richland, WA (USA)); Savatteri, C. (Commission of the European Communities, Ispra (Italy))

1990-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Candidate alloys for cost-effective, high-efficiency, high-temperature compact/foil heat-exchangers  

SciTech Connect

Solid oxide fuel cell (SOFC) and molten carbonate fuel cell (MCFC) systems operate at high temperatures (up to 1000 C and 650 C, respectively), which makes them especially attractive sources for combined heat and power (CHP) cogeneration. However, improvements in the efficiency of heat exchange in these fuel cells require both development and careful processing of advanced cost-effective alloys for use in such high-temperature service conditions. The high-temperature properties of both sheet and foil forms of several alloys being considered for use in compact heat-exchangers (recuperators) have been characterized. Mechanical and creep-rupture testing, oxidation studies, and microstructural studies have been performed on commercially available sheet and foil forms of alloy 347, alloys 625, HR230, HR120, and the new AL20-25+Nb. These studies have led to a mechanistic understanding of the responses of these alloys to anticipated service conditions, and suggest that these alloys developed for gas- and micro-turbine recuperator applications are also suitable for use in fuel cell heat-exchangers. Additional work is still required to achieve foil forms with creep life comparable to thicker-section wrought product forms of the same alloys.

Evans, Neal D [ORNL; Maziasz, Philip J [ORNL; Shingledecker, John P [ORNL; Pint, Bruce A [ORNL; Yamamoto, Yukinori [ORNL

2007-01-01T23:59:59.000Z

42

High Temperature Microstructural Degradation of Haynes Alloy 230  

Science Conference Proceedings (OSTI)

the case for the higher temperature tests DLH, COD and COG. In these latter three ... in the gauge lengths of COD and COG have only been observed in material ...

43

Stress corrosion cracking behavior of Alloy 600 in high temperature water  

Science Conference Proceedings (OSTI)

SCC susceptibility of Alloy 600 in deaerated water at 360 C (statically loaded U-bend specimens) is dependent on microstructure and whether the material was cold-worked and annealed (CWA) or hot-worked and annealed (HWA). All cracking was intergranular, and materials lacking grain boundary carbides were most susceptible to SCC initiation. CWA tubing materials are more susceptible to SCC initiation than HWA ring-rolled forging materials with similar microstructures (optical metallography). In CWA tubing materials, one crack dominated and grew to a visible size. HWA materials with a low hot-working finishing temperature (980 C) and a high-temperature final anneal (>1040 C), with grain boundaries that are fully decorated, developed only microcracks in all specimens. These materials did not develop large, visually detectable cracks, even after more than 300 weeks exposure. A low-temperature thermal treatment (610 C for 7h), which reduces or eliminates SCC in Alloy 600, did not eliminate microcrack formation in high temperature processed HWA materials. Conventional metallographic and analytical electron microscopy (AEM) were done on selected materials to identify the factors responsible for the observed differences in cracking behavior. Major difference between high-temperature HWA and low-temperature HWA and CWA materials was that the high temperature processing and final annealing produced predominantly ``semi-continuous`` dendritic M{sub 7}C{sub 3} carbides along grain boundaries with a minimal amount of intragranular carbides. Lower temperature processing produced intragranular M7C3 carbides, with less intergranular carbides.

Webb, G.L.; Burke, M.G.

1995-07-01T23:59:59.000Z

44

Strees Corrosion Cracking Initiation of Ni-Bassed Alloys in High Temperature Water  

DOE Green Energy (OSTI)

The goal of the work is to provide stress corrosion cracking (SCC) initiation data for Alloy 600 that is not compromised by (1) specimens that suffer from stress relaxation, (2) specimens which have an unknown stress state, (3) specimens which are tested at unknown positions electrochemically relative to the Ni/NiO phase transition, and (4) testing which relies on the period of time between specimen inspection intervals to estimate SCC initiation times. The current study was aimed at studying the effects of temperature and coolant hydrogen concentration on SCC initiation in high purity, high temperature water.

E Richey; D Morton

2005-03-21T23:59:59.000Z

45

Solidification processing and phase transformations in ordered high temperature alloys. Final report, 30 March 1990-30 September 1992  

SciTech Connect

Useful high temperature alloys generally have microstructures consisting of more than one phase. Multiphase microstructures are necessary to develop acceptable toughness and creep strength in high temperature intermetallic alloy matrices. The optimum microstructures must be developed by a careful selection of processing path that includes both solidification and solid state heat treatment. Research has been conducted on the rapid solidification of selected intermetallic alloys and on the phase transformation paths that occur during cooling, primarily in the Ti-Al-Nb system. This report describes research performed in the Metallurgy Division at NIST under DARPA order 7469 between 1/1/89 and 12/31/92. Various research tasks were completed and the results have been published or have been submitted for publication.... Intermetallics, Ti-Al-Nb Alloys, Phase Diagrams, Phase Transformations, Ti-Al-Ta Alloys, MoSi2 Alloys.

Boettinger, W.J.; Bendersky, L.A.; Kattner, U.R.

1993-01-20T23:59:59.000Z

46

Microstructure and High Temperature Oxidation Behavior of Cr-W Alloys  

Science Conference Proceedings (OSTI)

Cr alloys containing 0-30%W by weight were investigated for use in elevated temperature applications. The alloys were melted in a water-cooled, copper-hearth arc furnace. Microstructure of the alloys was characterized using x-ray diffraction, scanning electron microscopy, and light microscopy. A pseudocyclic oxidation test was employed to study scale formation at 1000ºC in dry air. The scale was predominantly chromia and spalled upon cooling. Alloying with aluminum up to 8 weight percent reduced the spalling drastically. Furthermore, aluminizing the surface of the Cr-W alloys completely stopped the spalling.

Dogan, O.N.

2007-02-01T23:59:59.000Z

47

Solid state thin film battery having a high temperature lithium alloy anode  

SciTech Connect

An improved rechargeable thin-film lithium battery involves the provision of a higher melting temperature lithium anode. Lithium is alloyed with a suitable solute element to elevate the melting point of the anode to withstand moderately elevated temperatures.

Hobson, David O. (Oak Ridge, TN)

1998-01-01T23:59:59.000Z

48

Computational Thermodynamics of CoNiGa High Temperature Shape Memory Alloys  

E-Print Network (OSTI)

Shape Memory Alloys (SMAs) are advanced materials with interesting properties such as pseudoelasticity (PE) and the shape memory effect (SME). Recently, the CoNiGa system has emerged as the basis for very promising High Temperature Shape Memory Alloys (HTSMAs), with possible applications in the aerospace and automotive industries. Although the CoNiGa system shows significant promise for its use as HTSMAs, limited studies are available on them. Hence, a more intensive investigation of these alloys is necessary to understand their phase stability over a wide range of temperature and compositions in order for further development of CoNiGabased HTSMAs and future use of the model in alloy design. This formed the basis of motivation for the present work. In this work, a thermodynamic model of the ternary system is calculated based on the CALPHAD approach, to investigate the thermodynamic properties, phase stability and shape memory properties of these alloys. The CALPHAD approach is a computational method that enables the calculations of thermodynamic properties of systems. This method uses all available experimental and theoretical data in order to calculate the Gibbs energies of the phases in the system. The software used to carry out the calculations is "ThermoCalc," which is a computational software using CALPHAD principles, based on the minimization of Gibbs energy, and is enhanced by a global minimization technique on the system. The stability of the beta phase at high temperatures was enforced accurately by remodeling the CoGa system. The binary CoGa system that makes up the ternary was remodeled, as the beta phase (which is very important as it dominates the central region of the ternary CoNiGa system where the shape memory effect is observed), re-stabilizes as the temperature increases above the liquidus in the CoGa system. Phase relations and thermodynamic properties of the CoNiGa system based on all experimental information were evaluated. Different properties like enthalpies, activities, sublattice site fraction of vacancies and phase fractions calculated in the system matched well compared to the experimental information used to model the system. Also, the phase equilibria among the gamma (fcc), beta, gamma'(Ni3Ga), delta (Ni5Ga3) and epsilon (Ni13Ga9) were determined at various temperatures.

Chari, Arpita

2011-08-01T23:59:59.000Z

49

Solid State Joining of High Temperature Alloy Tubes for USC and Heat-Exchanger Systems  

Science Conference Proceedings (OSTI)

The principal objective of this project was to develop materials enabling joining technologies for use in forward looking heat-exchanger fabrication in Brayton cycle HIPPS, IGCC, FutureGen concepts capable of operating at temperatures in excess of 1000{degree}C as well as conventional technology upgrades via Ultra Super-Critical (USC) Rankine-cycle boilers capable of operating at 760{degree}C (1400F)/38.5MPa (5500psi) steam, while still using coal as the principal fossil fuel. The underlying mission in Rankine, Brayton or Brayton-Rankine, or IGCC combined cycle heat engine is a steady quest to improving operating efficiency while mitigating global environmental concerns. There has been a progressive move to higher overall cycle efficiencies, and in the case of fossil fuels this has accelerated recently in part because of concerns about greenhouse gas emissions, notably CO{sub 2}. For a heat engine, the overall efficiency is closely related to the difference between the highest temperature in the cycle and the lowest temperature. In most cases, efficiency gains are prompted by an increase in the high temperature, and this in turn has led to increasing demands on the materials of construction used in the high temperature end of the systems. Our migration to new advanced Ni-base and Oxide Dispersion Strengthened (ODS) alloys poses significant fabrication challenges, as these materials are not readily weldable or the weld performs poorly in the high temperature creep regime. Thus the joining challenge is two-fold to a) devise appropriate joining methodologies for similar/dissimilar Ni-base and ODS alloys while b) preserving the near baseline creep performance in the welded region. Our program focus is on solid state joining of similar and dissimilar metals/alloys for heat exchanger components currently under consideration for the USC, HIPPS and IGCC power systems. The emphasis is to manipulate the joining methods and variables available to optimize joint creep performance compared to the base material creep performance. Similar and dissimilar butt joints were fabricated of MA956, IN740 alloys and using inertia welding techniques. We evaluated joining process details and heat treatments and its overall effect on creep response. Fixed and incrementally accelerated temperature creep tests were performed for similar and dissimilar joints and such incremental creep life data is compiled and reported. Long term MA956-MA556 joint tests indicate a firm 2Ksi creep stress threshold performance at 850{degree}C with a maximum exposure of over 9725 hours recorded in the current program. A Larsen Miller Parameter (LMP) of 48.50 for a 2Ksi test at 850{degree}C was further corroborated with tests at 2Ksi stress at 900{degree}C yielding a LMP=48.80. Despite this threshold the joints exhibit immense temperature sensitivity and fail promptly when test temperature raised above 900{degree}C. In comparison the performance of dissimilar joints was inferior, perhaps dictated by the creep characteristics of the mating nickel-base alloys. We describe a parametric window of joint development, and post weld heat treatment (PWHT) in dissimilar joints with solid solution (IN601, IN617) and precipitate strengthened (IN740) materials. Some concerns are evident regarding the diffusion of aluminum in dissimilar joints during high temperature recrystallization treatments. It is noted that aggressive treatments rapidly deplete the corrosion protecting aluminum reservoir in the vicinity of the joint interface. Subsequently, the impact of varying PWHT has been evaluated in the context on ensuing creep performance.

Bimal Kad

2011-12-31T23:59:59.000Z

50

Grain growth behavior and high-temperature high-strain-rate tensile ductility of iridium alloy DOP-26  

DOE Green Energy (OSTI)

This report summarizes results of studies conducted to date under the Iridium Alloy Characterization and Development subtask of the Radioisotope Power System Materials Production and Technology Program to characterize the properties of the new-process iridium-based DOP-26 alloy used for the Cassini space mission. This alloy was developed at Oak Ridge National Laboratory (ORNL) in the early 1980`s and is currently used by NASA for cladding and post-impact containment of the radioactive fuel in radioisotope thermoelectric generator (RTG) heat sources which provide electric power for interplanetary spacecraft. Included within this report are data generated on grain growth in vacuum or low-pressure oxygen environments; a comparison of grain growth in vacuum of the clad vent set cup material with sheet material; effect of grain size, test temperature, and oxygen exposure on high-temperature high-strain-rate tensile ductility; and grain growth in vacuum and high-temperature high-strain-rate tensile ductility of welded DOP-26. The data for the new-process material is compared to available old-process data.

McKamey, C.G.; Gubbi, A.N.; Lin, Y.; Cohron, J.W.; Lee, E.H.; George, E.P.

1998-04-01T23:59:59.000Z

51

Influence of dissolved hydrogen on nickel alloy SCC in high temperature water  

DOE Green Energy (OSTI)

Stress corrosion crack growth rate (SCCGR) tests of nickel alloys were conducted at 338 C and 360 C as a function of the hydrogen concentration in high purity water. Test results identified up to a 7 x effect of hydrogen levels in the water on crack growth rate, where the lowest growth rates were associated with the highest hydrogen levels. At 338 C, the crack growth rate decreased as the hydrogen levels were increased. However, different results were observed for the test conducted at 360 C. As the hydrogen level was increased in the 360 C tests, the crack growth rate initially increased, a maximum was exhibited at a hydrogen level of {approximately} 20 scc/kg, and thereafter the crack growth rate decreased. Based on this testing and a review of the commercial literature, the thermodynamic stability of nickel oxide, not the dissolved hydrogen concentration, was identified as a fundamental parameter influencing the susceptibility of nickel alloys to SCC. These test results are discussed in relation to the accuracy of extrapolating high temperature SCC results to lower temperatures.

Morton, D.S.; Attanasio, S.A.; Fish, J.S.; Schurman, M.K. [Lockheed Martin, Schenectady, NY (United States)

1999-03-01T23:59:59.000Z

52

Controlled Temperature Shape Rolling of Alloy 718  

Science Conference Proceedings (OSTI)

Incentive. Program (IMIP) to develop a bar mill for high temperature alloys .... and energy can be saved and that tool life ... enough to achieve steady-state.

53

PALLADIUM/COPPER ALLOY COMPOSITE MEMBRANES FOR HIGH TEMPERATURE HYDROGEN SEPARATION  

DOE Green Energy (OSTI)

This report summarizes progress made during the first year of research funding from DOE Grant No. DE-FG26-03NT41792 at the Colorado School of Mines. The period of performance was September 1, 2003 through August of 2004. Composite membranes, consisting of a thin Pd alloy film supported on a porous substrate have been investigated as a means of reducing the membrane cost and improving H{sub 2} flux. An electroless plating technique was utilized to deposit subsequent layers of palladium and copper over zirconia and alumina-based microfilters. The composite membranes thus made were annealed and tested at temperatures ranging from 250 to 500 C, under very high feed pressures (up to 450 psig) using pure gases and gaseous mixtures containing H{sub 2}, CO, CO{sub 2}, H{sub 2}O and H{sub 2}S, with the purpose of determining the effects these variables had on the H{sub 2} permeation rate, selectivity and percent recovery. The inhibition caused by CO/CO{sub 2} gases on a 7 {micro}m thick Pd-Cu composite membrane was less than 17% over a wide range of compositions at 350 C. H{sub 2}S caused a strong inhibition of the H{sub 2} flux of the same Pd-Cu composite membrane, which is accentuated at levels of 100 ppm or higher. The membrane was exposed to 50 ppm three times without permanent damage. At higher H{sub 2}S levels, above 100 ppm the membrane suffered some physical degradation and its performances was severely affected. The use of sweep gases improved the hydrogen flux and recovery of a Pd-Cu composite membrane. Recently, we have been able to dramatically reduce the thickness of these Pd alloy membranes to approximately one micron. This is significant because at this thickness, it is the cost of the porous support that controls the materials cost of a composite Pd alloy membrane, not the palladium inventory. Very recent results show that the productivity of our membranes is very high, essentially meeting the DOE pure hydrogen flux target value set by the DOE Hydrogen Program. These results were obtained when a 1.3-micron-thick Pd{sub 95}Cu{sub 5} (composition given in mass %) alloy film was coated on a Pall Corporation Membralox{reg_sign} T1-70 tubular ceramic substrate. The flux of this membrane would be even higher if the alloy composition was 40 wt. % Cu.

J. Douglas Way

2004-08-31T23:59:59.000Z

54

Corrosion of high temperature alloys in solar salt at 400, 500, and 680%C2%B0C.  

SciTech Connect

Corrosion tests at 400, 500, and 680%C2%B0C were performed using four high temperature alloys; 347SS, 321SS In625, and HA230. Molten salt chemistry was monitored over time through analysis of nitrite, carbonate, and dissolved metals. Metallography was performed on alloys at 500 and 680%C2%B0C, due to the relatively thin oxide scale observed at 400%C2%B0C. At 500%C2%B0C, corrosion of iron based alloys took the form of chromium depletion and iron oxides, while nickel based alloys also had chromium depletion and formation of NiO. Chromium was detected in relatively low concentrations at this temperature. At 680%C2%B0C, significant surface corrosion occurred with metal losses greater than 450microns/year after 1025hours of exposure. Iron based alloys formed complex iron, sodium, and chromium oxides. Some data suggests grain boundary chromium depletion of 321SS. Nickel alloys formed NiO and metallic nickel corrosion morphologies, with HA230 displaying significant internal oxidation in the form of chromia. Nickel alloys both exhibited worse corrosion than iron based alloys likely due to preferential dissolution of chromium, molybdenum, and tungsten.

Kruizenga, Alan Michael; Gill, David Dennis; LaFord, Marianne Elizabeth

2013-09-01T23:59:59.000Z

55

High-temperature corrosion behavior of iron-aluminide alloys and coatings  

DOE Green Energy (OSTI)

An Fe-28 at.% Al-2% Cr alloy doped with Y{sub 2}O{sub 3} showed improved scale adhesion relative to a dispersion-free form of the same composition. However, doping with CeO{sub 2} or La{sub 2}O{sub 3} was detrimental to oxidation behavior. A study of weld-overlay iron-aluminide coatings showed that, those with sufficiently high aluminum concentrations had sulfidation resistance in H{sub 2}S-H{sub 2}-H{sub 2}O-Ar at 800 C equivalent to the most resistant bulk iron aluminides. These corrosion-resistant coatings have the potential to be effective barriers in high-temperature sulfidizing environments provided the appropriate combinations of filler metal, process parameters, and substrate are used to produce adequate aluminum concentrations and minimal chromium contents. Exposures in an oxidizing/sulfidizing environment containing varying amounts of HCI at 450 and 550 C showed that Fe{sub 3}Al alloys had good corrosion resistance.

Tortorelli, P.F.; DeVan, J.H.; Pint, B.A.; Wright, I.G. [Oak Ridge National Lab., TN (United States); Saunders, S.R.J. [National Physical Lab., Teddington (United Kingdom)

1995-07-01T23:59:59.000Z

56

Development of High-Temperature Ferritic Alloys and Performance Prediction Methods for Advanced Fission Energy Systems  

Science Conference Proceedings (OSTI)

Reports the results of a comprehensive development and analysis of a database on irradiation hardening and embrittlement of tempered martensitic steels (TMS). Alloy specific quantitative semi-empirical models were derived for the dpa dose, irradiation temperature (ti) and test (Tt) temperature of yield stress hardening (or softening) .

G. RObert Odette; Takuya Yamamoto

2009-08-14T23:59:59.000Z

57

MULTI-PHASE HIGH TEMPERATURE ALLOYS AND PROGRESS IN CONTROLLED OXIDATION FOR FUNCTIONAL AND PROTECTIVE SURFACES  

E-Print Network (OSTI)

-phase strengthened Fe-base alloys for improved elevated temperature strength in fossil energy system components-temperature strength is a major issue for hot components in advanced fossil energy conversion and combustion systems-containing environments such as those encountered in advanced fossil energy steam plants. Controlled Oxidation for Near

58

Solid state thin film battery having a high temperature lithium alloy anode  

DOE Patents (OSTI)

An improved rechargeable thin-film lithium battery involves the provision of a higher melting temperature lithium anode. Lithium is alloyed with a suitable solute element to elevate the melting point of the anode to withstand moderately elevated temperatures. 2 figs.

Hobson, D.O.

1998-01-06T23:59:59.000Z

59

HIGH TEMPERATURE OXIDATION/CORROSION BEHAVIOR OF METALS AND ALLOYS UNDER A HYDROGEN GRADIENT  

Science Conference Proceedings (OSTI)

Metallic interconnects in SOFC stacks, perform in challenging environment, as they are simultaneously exposed to a reducing environment (e.g. hydrogen, reformate) on one side and an oxidizing environment (e.g. air) on the other side at elevated temperatures. To understand the oxidation/corrosion behavior of metals and alloys under the dual exposures and assess their suitability, selected metals and alloys, including nickel, Fe-Cr and Ni-Cr base chromia forming alloys, alumina forming Fecralloy®, were investigated. It was found that the oxidation/corrosion behavior of metals and alloys in the presence of dual environment can be significantly different in terms of scale structure and/or chemistry from their exposure in a single oxidizing or reducing atmosphere. The anomalous oxidization/corrosion is attributed to the presence of hydrogen diffusion flux from the fuel side to the air side under the influence of a hydrogen gradient across the metallic substrates.

Yang, Z Gary; Xia, Gordon; Walker, Matthew S.; Wang, Chong M.; Stevenson, Jeffry W.; Singh, Prabhakar

2007-11-01T23:59:59.000Z

60

The influence of FeTi and NiTi intermetallide additions on high-temperature oxidation of permalloy alloy  

Science Conference Proceedings (OSTI)

As a rule powder metallurgy Permalloy alloys are used in production of parts for electronic instruments. For the purpose of controlling the magnetic and electrical properties and also the wear (in the case of production of magnetic heads) and corrosion resistance appropriate additions of metals or such compounds as carbides and oxides are added to the alloy. In this work use of FeTi and NiTi intermetallides produced by reaction sintering of powders of pure metals in a protective atmosphere as alloying additions to Permalloy is recommended. The size of the original powders is less than 100 {mu}m. For reaction sintering at temperature 50{degrees}C above the eutectic temperature in the Ti-TiFe and TiNi-Ni systems was selected. The contents of titanium, iron, and oxygen in the FeTi alloy is 51.9, 45.7, and 2.4 wt.%, respectively, and of titanium, nickel, and oxygen in the NiTi alloy 59.6, 31.9, and 4.6 wt.%. High-temperature oxidation in air up to 1300{degrees}C with a rate of change in temperature of 15{degrees}C of type 78N Permalloy with additions of FeTi and NiTi alloys was investigated with use of methods of differential thermal and differential thermogravimetric analyses on an OD-103 derivatograph under nonisothermal conditions. The reaction products were studied by x-ray diffraction phase analysis on a DRON-3 instrument in CoK{sub {alpha}}-radiation. Pure 78N alloy powder with a composition of 78.1% Ni + 19.3% Fe (specimen 1) and also with additions of 1% FeTi (specimen 2) and 1% NiTi (specimen 3) were subjected to oxidation.

Klimenko, V.N.; Lavrenko, V.A.; Panasyuk, O.A.; Blasova, O.V.; Protsenko, T.G. [Inst. of Materials Science, Kiev (Ukraine)

1995-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
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61

Stoichiometric growth of high Curie temperature heavily alloyed GaMnAs  

SciTech Connect

Heavily alloyed, 100 nm Ga{sub 1-x}Mn{sub x}As (x>0.1) films are obtained via low-temperature molecular beam epitaxy by utilizing a combinatorial technique which allows systematic control of excess arsenic during growth. Reproducible electronic, magnetic, and structural properties are optimized in a narrow range of stoichiometric growth conditions. In contrast to a prediction of the Zener model of hole-mediated ferromagnetism, the Curie temperature of the stoichiometric material is independent of x (for x>0.1), while substitutional Mn content is proportional to x within a large window of growth conditions.

Mack, S.; Myers, R. C.; Heron, J. T.; Gossard, A. C.; Awschalom, D. D. [Center for Spintronics and Quantum Computation, University of California, Santa Barbara, California 93106 (United States)

2008-05-12T23:59:59.000Z

62

High Temperature Oxidation of Silicon Carbide and Advanced Iron-Based Alloys in Steam-Hydrogen Environments  

SciTech Connect

A side by side comparison of the oxidation behavior of zirconium alloys with SiC materials and advanced iron-based alloys is provided. Oxidation tests were conducted in steam and steam-hydrogen environments at 800-1350 C and 0.34-2MPa for durations up to 48 hours. Monolithic SiC specimens as well as SiC/SiC composites were examined during the study where the material recession mechanism appeared to be governed by silica layer volatilization at the surface for CVD SiC. A wide set of austenitic and ferritic steels were also examined where a critical Cr content (>20 wt.%) was shown to be necessary to achieve oxidation resistance at high temperatures. SiC materials and alumina-forming ferritic steels exhibited slowest oxidation kinetics; roughly two orders of magnitude lower than zirconium alloys.

Terrani, Kurt A [ORNL; Keiser, James R [ORNL; Brady, Michael P [ORNL; Cheng, Ting [ORNL; Silva, G W Chinthaka M [ORNL; Pint, Bruce A [ORNL; Snead, Lance Lewis [ORNL

2012-01-01T23:59:59.000Z

63

Development of Advanced Corrosion-Resistant Fe-Cr-Ni Austenitic Stainless Steel Alloy with Improved High Temperature Strenth and Creep-Resistance  

Science Conference Proceedings (OSTI)

In February of 1999, a Cooperative Research and Development Agreement (CRADA) was undertaken between Oak Ridge National Laboratory (ORNL) and Special Metals Corporation-Huntington Alloys (formerly INCO Alloys International, Inc.) to develop a modified wrought austenitic stainless alloy with considerably more strength and corrosion resistance than alloy 800H or 800HT, but with otherwise similar engineering and application characteristics. Alloy 800H and related alloys have extensive use in coal flue gas environments, as well as for tubing or structural components in chemical and petrochemical applications. The main concept of the project was make small, deliberate elemental microalloying additions to this Fe-based alloy to produce, with proper processing, fine stable carbide dispersions for enhanced high temperature creep-strength and rupture resistance, with similar or better oxidation/corrosion resistance. The project began with alloy 803, a Fe-25Cr-35NiTi,Nb alloy recently developed by INCO, as the base alloy for modification. Smaller commercial developmental alloy heats were produced by Special Metals. At the end of the project, three rounds of alloy development had produced a modified 803 alloy with significantly better creep resistance above 815EC (1500EC) than standard alloy 803 in the solution-annealed (SA) condition. The new upgraded 803 alloy also had the potential for a processing boost in that creep resistance for certain kinds of manufactured components that was not found in the standard alloy. The upgraded 803 alloy showed similar or slightly better oxidation and corrosion resistance relative to standard 803. Creep strength and oxidation/corrosion resistance of the upgraded 803 alloy were significantly better than found in alloy 800H, as originally intended. The CRADA was terminated in February 2003. A contributing factor was Special Metals Corporation being in Chapter 11 Bankruptcy. Additional testing, further commercial scale-up, and any potential invention disclosures were not pursued. One objective of this project was to improve the high temperature creep resistance of the recently developed 803 alloy, while another was to have a wrought modified 803 alloy with significantly better creep resistance and corrosion resistance than the commonly used alloy 800H. The project was intended to use the established expertise at ORNL to design specific microalloying element additions to appropriately tailor the microstructure during aging or creep so that fine, stable carbides develop for strength. If possible, oxidation/corrosion resistance at high temperatures would also be enhanced. Optimum processing was to be developed for plate and tube products.

Maziasz, PJ

2004-09-30T23:59:59.000Z

64

Stress Corrosion Cracking of Alloy 690tt in High Temperature High ...  

Science Conference Proceedings (OSTI)

Design of Pre-Weakening and Evaluation of Structural Safety for Explosive ... Crystallization Temperature of Pd-Cu-Si System Using Integrated Thin Film Samples ... Mechanical Properties of 5083 Aluminium Welds after Manual and Automatic ...

65

High Temperature Corrosion Resistance of Fe-Ni-Cr Alloys in CO2 ...  

Science Conference Proceedings (OSTI)

Austenitic Steel Oxidation in Steam: Alloy Composition and Surface Modification ... Ni-Base Alloys for Use as Components in Advanced-USC Steam Turbines.

66

High-temperature Creep-Fatigue Behavior Study of INCONEL Alloy ...  

Science Conference Proceedings (OSTI)

Abstract Scope, Spallation-neutron-source-yielded multiple diffraction combining with the in-situ high-temperature experimental environment was applied to ...

67

High Temperature Aging Study on Long-Term Aged Alloy 617 and ...  

Science Conference Proceedings (OSTI)

In order to gain a better understanding of the high-temperature degradation process of these materials, long-term (up to 10000 hours) aging experiments have ...

68

Mechanical Properties of Welds in Commercial Alloys for High-Temperature Gas-Cooled Reactor Components  

Science Conference Proceedings (OSTI)

C. 1. Mechanical Property / Status of Metallic Materials Development for Application in Advanced High-Temperature Gas-Cooled Reactor / Material

James R. Lindgren; Brian E. Thurgood; Robin H. Ryder; Chia-Chuan Li

69

High strength alloys  

DOE Patents (OSTI)

High strength metal alloys are described herein. At least one composition of a metal alloy includes chromium, nickel, copper, manganese, silicon, niobium, tungsten and iron. System, methods, and heaters that include the high strength metal alloys are described herein. At least one heater system may include a canister at least partially made from material containing at least one of the metal alloys. At least one system for heating a subterranean formation may include a tubular that is at least partially made from a material containing at least one of the metal alloys.

Maziasz, Phillip James [Oak Ridge, TN; Shingledecker, John Paul [Knoxville, TN; Santella, Michael Leonard [Knoxville, TN; Schneibel, Joachim Hugo [Knoxville, TN; Sikka, Vinod Kumar [Oak Ridge, TN; Vinegar, Harold J [Bellaire, TX; John, Randy Carl [Houston, TX; Kim, Dong Sub [Sugar Land, TX

2010-08-31T23:59:59.000Z

70

Palladium/Copper Alloy Composite Membranes for High Temperature Hydrogen Separation  

DOE Green Energy (OSTI)

This report summarizes progress made during the a three year University Coal Research grant (DEFG26-03NT41792) at the Colorado School of Mines. The period of performance was September 1, 2003 through August of 2006. We made excellent progress toward our goal of contributing to the development of high productivity, sulfur tolerant composite metal membranes for hydrogen production and membrane reactors. Composite Pd and Pd alloy metal membranes with thin metal films (1-7 {micro}m) were prepared on porous stainless steel and ceramic supports that meet or exceed the DOE 2010 and 2015 pure hydrogen flux targets at differential pressure of only 20 psi. For example, a 2 {micro}m pure Pd membrane on a Pall AccuSep{reg_sign} substrate achieved an ideal H{sub 2}/N{sub 2} separation factor of over 6000, with a pure hydrogen flux of 210 SCFH/ft{sup 2} at only 20 psig feed pressure. Similar performance was achieved with a Pd{sub 80}Au{sub 20} composite membrane on a similar stainless steel substrate. Extrapolating the pure hydrogen flux of this PdAu membrane to the DOE Fossil Energy target conditions of 150 psia feed pressure and 50 psia permeate pressure gives a value of 508 SCFH/ft{sup 2}, exceeding the 2015 target. At these thicknesses, it is the support cost that will dominate the cost of a large scale module. In a direct comparison of FCC phase PdCu and PdAu alloys on identical supports, we showed that a Pd{sub 85}Au{sub 15} (mass %) alloy membrane is not inhibited by CO, CO{sub 2}, or steam present in a water-gas shift feed mixture at 400 C, has better resistance to sulfur than a Pd{sub 94}Cu{sub 6} membrane, and has over twice the hydrogen permeance.

J. Douglas Way; Paul M. Thoen

2006-08-31T23:59:59.000Z

71

Improved Martensitic Steel for High Temperature Applications  

NETL has developed a stainless steel composition and heat treatment process for a high-temperature, titanium alloyed 9 Cr-1 molybdenum alloy ...

72

CORROSION STUDIES OF TERNARY ZIRCONIUM ALLOYS IN HIGH-TEMPERATURE WATER AND STEAM  

DOE Green Energy (OSTI)

The alloying of zirconium to improve corrosion resistance has an empirical basis, and satisfactory explanations for the alloying effects are not available. A theory of compensating valencies in the corrosion oxide is proposed, in which cations of lower and higher valence than zirconium (+4) are present in ratios such that electrostatic neutrality is ensured. An example is an alloy containing equimolar amounts of scandium (+3) and niobium (+5). A number of zirconium alloys were prepared in which scandium or yttrium were paired with elements capable of a +5 or +6 valence. The ternary alloys containing scanadium were superior to the alloys combining yttrium. The alloys containing scandium plus molybdenum, tantalum, or tungsten had relatively long lifetimes in steam at 540 deg C and 600 psi as compared with other alloy combinations, including Zircaloy-2. A quenched alloy containing 0.025 wt% Sc and 0.053 at.% Mlo, that is, 0.05 mol.% of each additive, corroded approximately according to a cubic law up to 758 hr, at which potnt the rate suddenly increased in a manner suggesting hydrogen damage. Examination of the oxide film from alloys containing scandium and molybdenum showed only monoclinic ZrO/sub 2/. It is believed that stabilization of this form of ZrO/sub 2/ instead of the cubic or tetragonal forms is a factor in promoting corrosion resistance. In this way the protective character of the film can be improved independently of the addition of cathodes. (auth)

Misch, R.D.; Van Drunen, C.

1961-07-01T23:59:59.000Z

73

The Behaviour Of Zirconium Alloys In Santowax OM Organic Coolant At High Temperature  

DOE Green Energy (OSTI)

Zirconium alloys have been exposed to Santowax OM at temperatures of 320 to 400 deg C for times as long as 5000 hours. Short-term experiments (less than 2 weeks) were done in stainless-steel bombs and small out-of-pile loops. The X-7 organic loop in the NRX reactor was used to study long-term oxidation and hydriding both in-flux and out-of-flux. The results obtained lead to several tentative conclusions. 1. Aluminum cladding serves as an effective hydrogen barrier. 2. Considerable protection against hydriding is given by zirconium oxide, provided impurities in the organic are carefully controlled. Hydriding is greatly enhanced by the presence of chlorine in the coolant. 4. Hydriding is somewhat enhanced by neutron irradiation. Of considerable significance is the fact that a Zircaloy-4 in-reactor test section of the X-7 loop was exposed to Santowax OM at 320 to 400 deg C for more than 5000 hours without excessive hydriding. (auth)

Sawatzky, A.

1964-10-15T23:59:59.000Z

74

High-temperature corrosion-resistant iron-aluminide (FeAl) alloys exhibiting improved weldability  

DOE Patents (OSTI)

This invention relates to improved corrosion-resistant iron-aluminide intermetallic alloys. The alloys of this invention comprise, in atomic percent, from about 30% to about 40% aluminum alloyed with from about 0.1% to about 0.5% carbon, no more than about 0.04% boron such that the atomic weight ratio of boron to carbon in the alloy is in the range of from about 0.01:1 to about 0.08:1, from about 0.01 to about 3.5% of one or more transition metals selected from Group IVB, VB, and VIB elements and the balance iron wherein the alloy exhibits improved resistance to hot cracking during welding.

Maziasz, Philip J. (Oak Ridge, TN); Goodwin, Gene M. (Lenoir City, TN); Liu, Chain T. (Oak Ridge, TN)

1996-01-01T23:59:59.000Z

75

High-temperature corrosion-resistant iron-aluminide (FeAl) alloys exhibiting improved weldability  

DOE Patents (OSTI)

This invention relates to improved corrosion-resistant iron-aluminide intermetallic alloys. The alloys of this invention comprise, in atomic percent, from about 30% to about 40% aluminum alloyed with from about 0.1% to about 0.5% carbon, no more than about 0.04% boron such that the atomic weight ratio of boron to carbon in the alloy is in the range of from about 0.01:1 to about 0.08:1, from about 0.01 to about 3.5% of one or more transition metals selected from Group IVB, VB, and VIB elements and the balance iron wherein the alloy exhibits improved resistance to hot cracking during welding. 13 figs.

Maziasz, P.J.; Goodwin, G.M.; Liu, C.T.

1996-08-13T23:59:59.000Z

76

NiTiHf High-Temperature Shape-Memory Alloys for near Term ...  

Science Conference Proceedings (OSTI)

Development of a SMA-Based Drive Unit for Prehension Orthoses to Support Disabled People · Effect of H in Metals and Alloys: An Application to bcc W and NiTi ...

77

Environmental-temperature Effect on a Ductile High-entropy Alloy ...  

Science Conference Proceedings (OSTI)

Atomic Dynamics and Viscosity in the Liquid ... Measuring Strains In Operando in Alloy-based Anodes for Lithium Ion Batteries Using X-ray Diffraction ... Synchrotron X-ray Diffraction Study of the Plasticity of Bulk Metallic Glass Composites.

78

PALLADIUM/COPPER ALLOY COMPOSITE MEMBRANES FOR HIGH TEMPERATURE HYDROGEN SEPARATION FROM COAL-DERIVED GAS STREAMS  

DOE Green Energy (OSTI)

For hydrogen from coal gasification to be used economically, processing approaches that produce a high purity gas must be developed. Palladium and its alloys, nickel, platinum and the metals in Groups 3 to 5 of the Periodic Table are all permeable to hydrogen. Hydrogen permeable metal membranes made of palladium and its alloys are the most widely studied due to their high hydrogen permeability, chemical compatibility with many hydrocarbon containing gas streams, and infinite hydrogen selectivity. Our Pd composite membranes have demonstrated stable operation at 450 C for over 70 days. Coal derived synthesis gas will contain up to 15000 ppm H{sub 2}S as well as CO, CO{sub 2}, N{sub 2} and other gases. Highly selectivity membranes are necessary to reduce the H{sub 2}S concentration to acceptable levels for solid oxide and other fuel cell systems. Pure Pd-membranes are poisoned by sulfur, and suffer from mechanical problems caused by thermal cycling and hydrogen embrittlement. Recent advances have shown that Pd-Cu composite membranes are not susceptible to the mechanical, embrittlement, and poisoning problems that have prevented widespread industrial use of Pd for high temperature H{sub 2} separation. These membranes consist of a thin ({le} 5 {micro}m) film of metal deposited on the inner surface of a porous metal or ceramic tube. With support from this DOE Grant, we have fabricated thin, high flux Pd-Cu alloy composite membranes using a sequential electroless plating approach. Thin, Pd{sub 60}Cu{sub 40} films exhibit a hydrogen flux more than ten times larger than commercial polymer membranes for H{sub 2} separation, resist poisoning by H{sub 2}S and other sulfur compounds typical of coal gas, and exceed the DOE Fossil Energy target hydrogen flux of 80 ml/cm{sup 2} {center_dot} min = 0.6 mol/m{sup 2} {center_dot} s for a feed pressure of 40 psig. Similar Pd-membranes have been operated at temperatures as high as 750 C. We have developed practical electroless plating procedures for fabrication of thin Pd-Cu composite membranes at any scale.

J. Douglas Way

2003-01-01T23:59:59.000Z

79

Welding of dissimilar alloys for high temperature heat exchangers for SOFC  

DOE Green Energy (OSTI)

Reduction in the cost of balance of plant applications is one of the top priority focus areas for the successful implementation of solid oxide fuel cell technology. High temperature heat exchangers are employed to heat cathode air utilizing either hot gases coming from the anode side of the stack or other hot gases generated by external processes. In order to reduce the cost of heat exchangers, it may be necessary to apply several different materials, each in a different temperature zone, for the construction of the heat exchanger. This technique would require the joining of dissimilar materials in the construction. In this work, welding of commercial candidate dissimilar materials is explored. Filler materials were identified using equilibrium phase diagrams and thermodynamic simulation software. Autogenous welding was performed and the welding defects were characterized. Finally, experimental weld microstructures were compared to phases predicted by the simulations.

Wilson, R.D.; Hatem, J.; Dogan, O.N.; King, P.E.

2006-10-01T23:59:59.000Z

80

Palladium/Copper Alloy Composite Membranes for High Temperature Hydrogen Separation  

DOE Green Energy (OSTI)

This report summarizes progress made during the second year of research funding from DOE Grant DE-FG26-03NT41792 at the Colorado School of Mines. The period of performance was September 1, 2004 through August of 2005. We have reformulated our Pd plating process to minimize the presence of carbon contamination in our membranes. This has improved durability and increased permeability. We have developed techniques for plating the outside diameter of ceramic and metal substrate tubes. This configuration has numerous advantages including a 40% increase in specific surface area, the ability to assay the alloy composition non-destructively, the ability to potentially repair defects in the plated surface, and the ability to visually examine the plated surfaces. These improvements have allowed us to already meet the 2007 DOE Fossil Energy pure H{sub 2} flux target of 100 SCFH/ft{sup 2} for a hydrogen partial pressure difference of 100 psi with several Pd-Cu alloy membranes on ceramic microfilter supports. Our highest pure H{sub 2} flux on inexpensive, porous alumina support tubes at the DOE target conditions is 215 SCFH/ft{sup 2}. Progress toward meeting the other DOE Fossil Energy performance targets is also summarized. Additionally, we have adapted our membrane fabrication procedure to apply Pd and Pd alloy films to commercially available porous stainless steel substrates. Stable performance of Pd-Cu films on stainless steel substrates was demonstrated over a three week period at 400 C. Finally, we have fabricated and tested Pd-Au alloy membranes. These membranes also exceed both the 2007 and 2010 DOE pure H{sub 2} flux targets and exhibit ideal H{sub 2}/N{sub 2} selectivities of over 1000 at partial pressure difference of 100 psi.

J. Douglas Way; Paul M. Thoen

2005-08-31T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Standard practice for evaluation of disbonding of bimetallic stainless alloy/steel plate for use in high-pressure, high-temperature refinery hydrogen service  

E-Print Network (OSTI)

1.1 This practice covers a procedure for the evaluation of disbonding of bimetallic stainless alloy/steel plate for use in refinery high-pressure/high-temperature (HP/HT) gaseous hydrogen service. It includes procedures to (1) produce suitable laboratory test specimens, (2) obtain hydrogen charging conditions in the laboratory that are similar to those found in refinery HP/HT hydrogen gas service for evaluation of bimetallic specimens exposed to these environments, and (3) perform analysis of the test data. The purpose of this practice is to allow for comparison of data among test laboratories on the resistance of bimetallic stainless alloy/steels to hydrogen-induced disbonding (HID). 1.2 This practice applies primarily to bimetallic products fabricated by weld overlay of stainless alloy onto a steel substrate. Most of the information developed using this practice has been obtained for such materials. The procedures described herein, may also be appropriate for evaluation of hot roll bonded, explosive bonded...

American Society for Testing and Materials. Philadelphia

2001-01-01T23:59:59.000Z

82

High-temperature oxidation of an alumina-coated Ni-base alloy  

Science Conference Proceedings (OSTI)

Alumina coatings were applied to Ni-20Cr (wt%) using combustion chemical vapor deposition (combustion CVD). Combustion CVD is an open air deposition technique performed in a flame. The oxidation kinetics of coated and uncoated specimens were measured by isothermal oxidation tests carried out in pure flowing air at temperatures of 800, 900, 1,000 and 1,100 C. The alumina coatings reduced the oxidation kinetics at all temperatures. The morphologies and compositions of the alumina coatings were characterized by transmission and scanning electron microscopy, energy dispersive x-ray spectroscopy and x-ray photoelectron spectroscopy.

Hendrick, M.R.; Hampikian, J.M.; Carter, W.B.

1996-06-01T23:59:59.000Z

83

Corrosion Behavior of NiCrFe Alloy 600 in High Temperature, Hydrogenated Water  

SciTech Connect

The corrosion behavior of Alloy 600 (UNS N06600) is investigated in hydrogenated water at 260 C. The corrosion kinetics are observed to be parabolic, the parabolic rate constant being determined by chemical descaling to be 0.055 mg dm{sup -2} hr{sup -1/2}. A combination of scanning and transmission electron microscopy, supplemented by energy dispersive X-ray spectroscopy and grazing incidence X-ray diffraction, are used to identify the oxide phases present (i.e., spinel) and to characterize their morphology and thickness. Two oxide layers are identified: an outer, ferrite-rich layer and an inner, chromite-rich layer. X-ray photoelectron spectroscopy with argon ion milling and target factor analysis is applied to determine spinel stoichiometry; the inner layer is (Ni{sub 0.7}Fe{sub 0.3})(Fe{sub 0.3}Cr{sub 0.7}){sub 2}O{sub 4}, while the outer layer is (Ni{sub 0.9}Fe{sub 0.1})(Fe{sub 0.85}Cr{sub 0.15}){sub 2}O{sub 4}. The distribution of trivalent iron and chromium cations in the inner and outer oxide layers is essentially the same as that found previously in stainless steel corrosion oxides, thus confirming their invariant nature as solvi in the immiscible spinel binary Fe{sub 3}O{sub 4}-FeCr{sub 2}O{sub 4} (or NiFe{sub 2}O{sub 4}-NiCr{sub 2}O{sub 4}). Although oxidation occurred non-selectively, excess quantities of nickel(II) oxide were not found. Instead, the excess nickel was accounted for as recrystallized nickel metal in the inner layer, as additional nickel ferrite in the outer layer, formed by pickup of iron ions from the aqueous phase, and by selective release to the aqueous phase.

SE Ziemniak; ME Hanson

2004-11-02T23:59:59.000Z

84

Co-Cr-Mo Alloys Production by Self Propagating High Temperature ...  

Science Conference Proceedings (OSTI)

Chemical Enrichment of Precious Metals in Iron Sulfides Using Microwave Energy · Chloridizing ... Co-Gasification Behavior of Metallurgical Coke with High and Low Reactivity .... Thermal Plasma Torches for Metallurgical Applications.

85

Phase transformations in the Zn-Al eutectoid alloy after quenching from the high temperature triclinic beta phase  

Science Conference Proceedings (OSTI)

Ribbons of the Zn-Al eutectoid alloy obtained by melt-spinning, were heat treated at 350 deg. C during 30 min in a free atmosphere furnace, and then quenched in liquid nitrogen. The temperature correspond to {beta} phase zone, which has a triclinic crystalline structure [1, 2]. Some evidence, obtained by X-ray diffraction, show that the structures present in the just quenched material are both close-packed hexagonal ({eta}-phase) and rhombohedral (R-phase). X-ray diffractograms taken in the same ribbons after annealed 500 h at room temperature, show that the R phase its transform to {alpha} and {eta} phases.

Sandoval-Jimenez, A., E-mail: asandovalj@correo.unam.mx [Instituto Nacional de Investigaciones Nucleares, Dpto. de Aceleradores, Carretera Mexico-Toluca S/N, La Marquesa, Ocoyoacac, Mexico, C.P. 52750, ESIME, Unidad Culhuacan, Dpto. Ing. Mecanica, IPN (Mexico); Negrete, J. [Instituto de Metalurgia, Universidad Autonoma de San Luis Potosi, SLP 78210 (Mexico); Torres-Villasenor, G. [Instituto de Investigaciones en Materiales, Universidad Nacional Autonoma de Mexico, Apdo. Postal 70-360, Mexico D.F. 04510 (Mexico)

2010-11-15T23:59:59.000Z

86

Processing of High-temperature Structural Materials I  

Science Conference Proceedings (OSTI)

Subsurface Alloy Microstructural Changes During High Temperature Reaction of Fe-Cr Alloys in CO2: David Young1; Thuan Nguyen1; Jianqiang Zhang1; ...

87

Tungsten-Rhenium Super Alloy Development for Ultra High ...  

Science Conference Proceedings (OSTI)

Presentation Title, Tungsten-Rhenium Super Alloy Development for Ultra High Temperature Space Fission and Fusion Reactors. Author(s), Jonathan Webb, ...

88

Mold, flow, and economic considerations in high temperature precision casting  

E-Print Network (OSTI)

Casting high temperature alloys that solidify through a noticeable two phase region, specifically platinum-ruthenium alloys, is a particularly challenging task due to their high melting temperature and this necessitates ...

Humbert, Matthew S

2013-01-01T23:59:59.000Z

89

Effect of Environment and Microstructure on the High Temperature ...  

Science Conference Proceedings (OSTI)

EFFECT OF ENVIRONMENT AND MICROSTRUCTURE ON THE HIGH. TEMPERATURE BEHAVIOR OF ALLOY 718. E. Andrieu",. R. Cozar** and A. Pineau".

90

High Temperature Fatigue Life of Coated and Uncoated Valve ...  

Science Conference Proceedings (OSTI)

Symposium, Properties, Processing, and Performance of Steels and Ni-Based Alloys for Advanced Steam Conditions. Presentation Title, High Temperature ...

91

Computer Simulation and Experimental Validation on the Oxidation and Sulfate Corrosion Resistance of Novel Chromium-Based High-temperature Alloys  

NLE Websites -- All DOE Office Websites (Extended Search)

Computer Simulation and Experimental Computer Simulation and Experimental Validation on the Oxidation and Sulfate Corrosion Resistance of Novel Chromium-Based High-temperature Alloys Background Advanced coal power generation is a critical component of the U.S. energy portfolio. The U.S. Department of Energy (DOE) is committed to supporting research that will increase the efficiency and decrease the environmental impact of coal-fired plants, thus enabling the long term use of a low cost domestic fuel source. One key factor to

92

Short-Crack Response of Alloy 182 Weld Metal Undergoing Stress Corrosion Cracking in High-Temperature PWR Primary Water  

Science Conference Proceedings (OSTI)

Mechanistic investigations of environmentally assisted cracking (EAC), to date, have focused more on propagation relative to initiation. At the same time, components spend most of their life in the initiation and "short-crack" growth regimes. Prior exploratory work conducted at General Electric Global Research Center (GE GRC) showed that stainless steels, Alloy 600, and Alloy 182 weld metal exhibit lower average growth rates when the cracks are very short or small (1050 m). In those tests, the transition...

2008-10-31T23:59:59.000Z

93

High Temperatures & Electricity Demand  

E-Print Network (OSTI)

High Temperatures & Electricity Demand An Assessment of Supply Adequacy in California Trends.......................................................................................................1 HIGH TEMPERATURES AND ELECTRICITY DEMAND.....................................................................................................................7 SECTION I: HIGH TEMPERATURES AND ELECTRICITY DEMAND ..........................9 BACKGROUND

94

Chemical thermodynamics of nuclear materials. IX. High temperature heat capacity of plutonium-3. 2 at. % gallium alloy  

Science Conference Proceedings (OSTI)

The heat capacity of delta-stabilized plutonium (Pu - 3.2 at. % Ga) has been determined from 330 to 700/sup 0/K by an adiabatic calorimeter. The heat capacity for this alloy may be expressed by: Cp (Pu-3.2 at. % Ga)/(J K/sup -1/ mol/sup -1/) = 39.249 - 0.0264 (T/K) + 3.595 x 10/sup 5/ (T/K)/sup 2/ - 2.506 x 10/sup 5/ (K/T)/sup 2/. It was found that a large contribution to the heat capacity is due to the electronic heat capacity. The thermal functions for this plutonium-gallium alloy are calculated to 700/sup 0/K.

Adams, R.O.; Oetting, F.L.

1982-01-01T23:59:59.000Z

95

Effect of aluminizing of Cr-containing ferritic alloys on the seal strength of a novel high-temperature solid oxide fuel cell sealing glass  

Science Conference Proceedings (OSTI)

A novel high-temperature alkaline-earth silicate sealing glass was developed for solid oxide fuel cell (SOFC) applications. The glass was used to join two metallic coupons of Cr-containing ferritic stainless steel for seal strength evaluation. In previous work, SrCrO4 was found to form along the glass/steel interface, which led to severe strength degradation. In the present study, aluminization of the steel surface was investigated as a remedy to minimize or prevent the strontium chromate formation. Three different processes for aluminization were evaluated with Crofer22APU stainless steel: pack cementation, vapor phase deposition, and aerosol spraying. It was found that pack cementation resulted in a rough surface with occasional cracks in the Al-diffused region. Vapor phase deposition yielded a smoother surface, but the resulting high Al content increased the coefficient of thermal expansion (CTE), resulting in failure of joined coupons. Aerosol spraying of an Al-containing salt resulted in formation of a thin aluminum oxide layer without any surface damage. The room temperature seal strength was evaluated in the as-fired state and in environmentally aged conditions. In contrast to earlier results with uncoated Crofer22APU, the aluminized samples showed no strength degradation even for samples aged in air. Interfacial and chemical compatibility was also investigated. The results showed aluminization to be a viable candidate approach to minimize undesirable chromate formation between alkaline earth silicate sealing glass and Cr-containing interconnect alloys for SOFC applications.

Chou, Y. S.; Stevenson, Jeffry W.; Singh, Prabhakar

2008-12-01T23:59:59.000Z

96

Irradiation Resistance of High-Entropy Alloys  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, Materials Science & Technology 2012. Symposium, Fundamental Understanding of High-Entropy Alloy Formation and their ...

97

CHARACTERIZATION OF ELEVATED TEMPERATURE PROPERTIES OF HEAT EXCHANGER AND STEAM GENERATOR ALLOYS  

Science Conference Proceedings (OSTI)

The Next Generation Nuclear Plant project is considering Alloy 800H and Alloy 617 for steam generator and intermediate heat exchangers. It is envisioned that a steam generator would operate with reactor outlet temperatures from 750 to 800 C, while an intermediate heat exchanger for primary to secondary helium would operate up to an outlet temperature of 950 C. Although both alloys are of interest due in part to their technical maturity, a number of specific properties require further characterization for design of nuclear components. Strain rate sensitivity of both alloys has been characterized and is found to be significant above 600 C. Both alloys also exhibit dynamic strain aging, characterized by serrated flow, over a wide range of temperatures and strain rates. High temperature tensile testing of Alloy 617 has been conducted over a range of temperatures. Dynamic strain aging is a concern for these materials since it is observed to result in reduced ductility for many solid solution alloys. Creep, fatigue, and creep-fatigue properties of Alloy 617 have been measured as well, with the goal of determining the influence of the temperature, strain rate and atmosphere on the creep fatigue life of Alloy 617. Elevated temperature properties and implications for codification of the alloys will be described.

J.K. Wright; L.J. Carroll; C.J. Cabet; T. Lillo; J.K. Benz; J.A. Simpson; A. Chapman; R.N. Wright

2012-10-01T23:59:59.000Z

98

High temperature furnace  

DOE Patents (OSTI)

A high temperature furnace for use above 2000.degree.C is provided that features fast initial heating and low power consumption at the operating temperature. The cathode is initially heated by joule heating followed by electron emission heating at the operating temperature. The cathode is designed for routine large temperature excursions without being subjected to high thermal stresses. A further characteristic of the device is the elimination of any ceramic components from the high temperature zone of the furnace.

Borkowski, Casimer J. (Oak Ridge, TN)

1976-08-03T23:59:59.000Z

99

High Temperature coatings based on {beta}-NiAI  

Science Conference Proceedings (OSTI)

High temperature alloys are reviewed, focusing on current superalloys and their coatings. The synthesis, characerization, and oxidation performance of a NiAl–TiB{sub 2} composite are explained. A novel coating process for Mo–Ni–Al alloys for improved oxidation performance is examined. The cyclic oxidation performance of coated and uncoated Mo–Ni–Al alloys is discussed.

Severs, Kevin

2012-07-10T23:59:59.000Z

100

High temperature sensor  

DOE Patents (OSTI)

A high temperature sensor includes a pair of electrical conductors separated by a mass of electrical insulating material. The insulating material has a measurable resistivity within the sensor that changes in relation to the temperature of the insulating material within a high temperature range (1,000 to 2,000 K.). When required, the sensor can be encased within a ceramic protective coating.

Tokarz, Richard D. (West Richland, WA)

1982-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

High temperature refrigerator  

SciTech Connect

A high temperature magnetic refrigerator which uses a Stirling-like cycle in which rotating magnetic working material is heated in zero field and adiabatically magnetized, cooled in high field, then adiabatically demagnetized. During this cycle said working material is in heat exchange with a pumped fluid which absorbs heat from a low temperature heat source and deposits heat in a high temperature reservoir. The magnetic refrigeration cycle operates at an efficiency 70% of Carnot.

Steyert, Jr., William A. (Los Alamos, NM)

1978-01-01T23:59:59.000Z

102

High Temperature Corrosion  

Science Conference Proceedings (OSTI)

Oct 18, 2010 ... Protective Coatings for Corrosion Resistance at High Temperatures: Vilupanur Ravi1; Thuan Nguyen1; Alexander Ly1; Kameron Harmon1; ...

103

High-temperature sensor  

DOE Patents (OSTI)

A high temperature sensor is described which includes a pair of electrical conductors separated by a mass of electrical insulating material. The insulating material has a measurable resistivity within the sensor that changes in relation to the temperature of the insulating material within a high temperature range (1000 to 2000/sup 0/K). When required, the sensor can be encased within a ceramic protective coating.

Not Available

1981-01-29T23:59:59.000Z

104

Electrolysis – High Temperature – Hydrogen  

INL has developed a high-temperature process the utilizes solid oxide fuel cells that are operated in the electrolytic mode. The first process includes combining a high-temperature heat source (e.g. nuclear reactor) with a hydrogen production facility ...

105

Development of Semi-Stochastic Algorithm for Optimizing Alloy Composition of High-Temperature Austenitic Stainless Steels (H-Series) for Desired Mechanical and Corrosion Properties.  

SciTech Connect

The goal of this project was to adapt and use an advanced semi-stochastic algorithm for constrained multiobjective optimization and combine it with experimental testing and verification to determine optimum concentrations of alloying elements in heat-resistant and corrosion-resistant H-series stainless steel alloys that will simultaneously maximize a number of alloy's mechanical and corrosion properties.

Dulikravich, George S.; Sikka, Vinod K.; Muralidharan, G.

2006-06-01T23:59:59.000Z

106

High-Strength Alloys; Precipitation  

Science Conference Proceedings (OSTI)

Mar 1, 2011 ... Precipitation Hardenable Mg-Ca-Al Alloys: J. Jayaraj1; C.L. Mendis1; T. Ohkubo1 ; K. Oh-ishi1; K. Hono1; 1National Institute for Materials ...

107

High Temperature Capacitor Development  

Science Conference Proceedings (OSTI)

The absence of high-temperature electronics is an obstacle to the development of untapped energy resources (deep oil, gas and geothermal). US natural gas consumption is projected to grow from 22 trillion cubic feet per year (tcf) in 1999 to 34 tcf in 2020. Cumulatively this is 607 tcf of consumption by 2020, while recoverable reserves using current technology are 177 tcf. A significant portion of this shortfall may be met by tapping deep gas reservoirs. Tapping these reservoirs represents a significant technical challenge. At these depths, temperatures and pressures are very high and may require penetrating very hard rock. Logistics of supporting 6.1 km (20,000 ft) drill strings and the drilling processes are complex and expensive. At these depths up to 50% of the total drilling cost may be in the last 10% of the well depth. Thus, as wells go deeper it is increasingly important that drillers are able to monitor conditions down-hole such as temperature, pressure, heading, etc. Commercial off-the-shelf electronics are not specified to meet these operating conditions. This is due to problems associated with all aspects of the electronics including the resistors and capacitors. With respect to capacitors, increasing temperature often significantly changes capacitance because of the strong temperature dependence of the dielectric constant. Higher temperatures also affect the equivalent series resistance (ESR). High-temperature capacitors usually have low capacitance values because of these dielectric effects and because packages are kept small to prevent mechanical breakage caused by thermal stresses. Electrolytic capacitors do not operate at temperatures above 150oC due to dielectric breakdown. The development of high-temperature capacitors to be used in a high-pressure high-temperature (HPHT) drilling environment was investigated. These capacitors were based on a previously developed high-voltage hybridized capacitor developed at Giner, Inc. in conjunction with a unique high-temperature electrolyte developed during the course of the program. During this program the feasibility of operating a high voltage hybridized capacitor at 230oC was demonstrated. Capacitor specifications were established in conjunction with potential capacitor users. A method to allow for capacitor operation at both ambient and elevated temperatures was demonstrated. The program was terminated prior to moving into Phase II due to a lack of cost-sharing funds.

John Kosek

2009-06-30T23:59:59.000Z

108

Development of High Strength Alloys 945 / 945X for HPHT ...  

Science Conference Proceedings (OSTI)

These alloys are manufactured as rods, mechanical tubes, pump shafts and wires. ... A High-Strength Ni-Cr-Mo Alloy for Severe Oil and Gas Environments.

109

High Temperature ESP Monitoring  

SciTech Connect

The objective of the High Temperature ESP Monitoring project was to develop a downhole monitoring system to be used in wells with bottom hole well temperatures up to 300°C for measuring motor temperature, formation pressure, and formation temperature. These measurements are used to monitor the health of the ESP motor, to track the downhole operating conditions, and to optimize the pump operation. A 220 ºC based High Temperature ESP Monitoring system was commercially released for sale with Schlumberger ESP motors April of 2011 and a 250 ºC system with will be commercially released at the end of Q2 2011. The measurement system is now fully qualified, except for the sensor, at 300 °C.

Jack Booker; Brindesh Dhruva

2011-06-20T23:59:59.000Z

110

High-Temperature Materials  

Science Conference Proceedings (OSTI)

"Producing Carbon-Free Cr/Cr Alloys Using a Reverse-Polarity Transferred-Arc Plasma" (Research Summary), Patrick R. Taylor and Wenming Wang, January ...

111

High Temperature Measurements Of Martensitic transformations Using Digital Holography  

SciTech Connect

During thermal cycling of nickel-aluminum-platinum (NiAlPt) and single crystal Fe-15Cr-15Ni alloys, the structural changes associated with the martensite to austenite phase transformation were measured using dual-wavelength digital holography. Real-time in-situ measurements reveal the formation of striations within the NiPtAl alloy at 70 C and the FeCrNi alloy at 520 C. The results demonstrate that digital holography is an effective technique for acquiring non-contact, high precision information of the surface evolution of alloys at high temperatures.

Thiesing, Benjamin [Northern Arizona University; Mann, Christopher J [Northern Arizona University; Dryepondt, Sebastien N [ORNL

2013-01-01T23:59:59.000Z

112

High-temperature gas-cooled reactor helium compatibility studies: results of 10,000-hour exposure of selected alloys in simulated reactor helium  

SciTech Connect

Work on the HTGR Helium Compatibility Task accomplished during the period March 31, 1977 through September 30, 1979, is documented in this report. Emphasis is on the results and analyses of creep data to 10,000 h and the detailed metallurgical evaluations performed on candidate alloy specimens tested for up to 10,000 h. Long-term creep and unstressed aging data in controlled-impurity helium and in air at 800, 900, and 1000/sup 0/C are reported for alloys included in the program in FY-76, including the wrought solid-solution-strengthened alloys, Hastelloy X, Hastelloy S, RA 333, and HD 556, and the centrifugally cast austenitic alloys, HK 40, Supertherm, Manaurite 36X, Manaurite 36XS, and Manaurite 900.

Lechtenberg, T.A.; Stevenson, R.D.; Johnson, W.R.

1980-05-01T23:59:59.000Z

113

High temperature thermometric phosphors  

SciTech Connect

A high temperature phosphor consists essentially of a material having the general formula LuPO.sub.4 :Dy.sub.(x),Eu.sub.y) wherein: 0.1 wt %.ltoreq.x.ltoreq.20 wt % and 0.1 wt %.ltoreq.y.ltoreq.20 wt %. The high temperature phosphor is in contact with an article whose temperature is to be determined. The article having the phosphor in contact with it is placed in the environment for which the temperature of the article is to be determined. The phosphor is excited by a laser causing the phosphor to fluoresce. The emission from the phosphor is optically focused into a beam-splitting mirror which separates the emission into two separate emissions, the emission caused by the dysprosium dopant and the emission caused by the europium dopent. The separated emissions are optically filtered and the intensities of the emission are detected and measured. The ratio of the intensity of each emission is determined and the temperature of the article is calculated from the ratio of the intensities of the separate emissions.

Allison, Stephen W. (Knoxville, TN); Cates, Michael R. (Oak Ridge, TN); Boatner, Lynn A. (Oak Ridge, TN); Gillies, George T. (Earlysville, VA)

1999-03-23T23:59:59.000Z

114

Turbine vane with high temperature capable skins  

Science Conference Proceedings (OSTI)

A turbine vane assembly includes an airfoil extending between an inner shroud and an outer shroud. The airfoil can include a substructure having an outer peripheral surface. At least a portion of the outer peripheral surface is covered by an external skin. The external skin can be made of a high temperature capable material, such as oxide dispersion strengthened alloys, intermetallic alloys, ceramic matrix composites or refractory alloys. The external skin can be formed, and the airfoil can be subsequently bi-cast around or onto the skin. The skin and the substructure can be attached by a plurality of attachment members extending between the skin and the substructure. The skin can be spaced from the outer peripheral surface of the substructure such that a cavity is formed therebetween. Coolant can be supplied to the cavity. Skins can also be applied to the gas path faces of the inner and outer shrouds.

Morrison, Jay A. (Oviedo, FL)

2012-07-10T23:59:59.000Z

115

Thermal fuse for high-temperature batteries  

SciTech Connect

A thermal fuse, preferably for a high-temperature battery, comprising leads and a body therebetween having a melting point between approximately 400.degree. C. and 500.degree. C. The body is preferably an alloy of Ag--Mg, Ag--Sb, Al--Ge, Au--In, Bi--Te, Cd--Sb, Cu--Mg, In--Sb, Mg--Pb, Pb--Pd, Sb--Zn, Sn--Te, or Mg--Al.

Jungst, Rudolph G. (Albuquerque, NM); Armijo, James R. (Albuquerque, NM); Frear, Darrel R. (Austin, TX)

2000-01-01T23:59:59.000Z

116

Temperature and environmentally assisted cracking in low alloy steel  

Science Conference Proceedings (OSTI)

Environmental assisted cracking (EAC) can be defined as the propagation of fatigue cracks in water at rates from 3 to over 40 times the growth rates in air. For low alloy steels with sulfur contents > 0.0125% by weight, EAC is normal behavior in the 240 to 290C range. However, literature yields mixed results for low alloy steels with compositions just below this sulfur level; some reports indicate EAC while others do not. Also, several authors have reported an increased tendency toward EAC when the water temperatures were lowered. In the present work, five ASTM A 508 Class 2 forgings with ladle and check analyses that ranged from 0.010 to 0.019 wt% S were tested in high purity deaerated water in the temperature range of 93 to 260C. At 260C these forgings did not exhibit EAC, reinforcing earlier results for two similar forgings. This broad sampling indicates strong resistance to EAC for this class of forging at 260C. On the other hand, EAC occurred consistently in the three of these forgings that were tested below 204C, provided the test conditions (loading frequency, {Delta}K, and R) were high enough to produce a high baseline fatigue crack growth rate (FCGR), where the baseline FCGR is that expected in air. At 149C, EAC occurred at test conditions that combined to yield a baseline FCGR greater than {approx}2E-6 mm/s. At 204, 121, and 93C, this critical crack growth rate appeared to shift to lower baseline values. The EAC that occurred at lower temperatures was a factor of 3 to 12 times higher than baseline air rates, which was not as strong as the effect for higher sulfur steels at 240 to 290C. Also, no plateau in the growth rates occurred as it does with the higher sulfur steels. In another approach, EAC was induced at 93 and at 260C by raising the dissolved oxygen content of the water from 15 ppb.

Auten, T.A.; Monter, J.V.

1995-04-01T23:59:59.000Z

117

High Temperature | Open Energy Information  

Open Energy Info (EERE)

Temperature Temperature Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Print PDF Sanyal Temperature Classification: High Temperature Dictionary.png High Temperature: No definition has been provided for this term. Add a Definition Sanyal Temp Classification This temperature scheme was developed by Sanyal in 2005 at the request of DOE and GEA, as reported in Classification of Geothermal Systems: A Possible Scheme. Extremely Low Temperature Very Low Temperature Low Temperature Moderate Temperature High Temperature Ultra High Temperature Steam Field Reservoir fluid between 230°C and 300°C is considered by Sanyal to be "high temperature." "Above a temperature level of 230°C, the reservoir would be expected to become two-phase at some point during exploitation. The next higher

118

Nanocomposite Alloy Design for High Frequency Power Conversion ...  

Science Conference Proceedings (OSTI)

Presentation Title, Nanocomposite Alloy Design for High Frequency Power ... of power electronic components and systems for power conditioning and grid ...

119

Synthesis of High-temperature Lead-free Nanosolders and Their ...  

Science Conference Proceedings (OSTI)

One high melting temperature alloy candidate, Au-20Sn, has shown to be a strong contender for the transition into lead-free interconnects with its bulk melting ...

120

High-Strength Low-Alloy Steels  

Science Conference Proceedings (OSTI)

Table 2 Summary of characteristics and intended uses of HSLA steels described in ASTM specifications...le 485 MPa (70 ksi) High-pressure gas and oil transmission lines A 871 High-strength low-alloy steel with atmospheric corrosion resistance V, Nb, Ti, Cu, Mo, Cr As-rolled plate le 35 mm (1 [MathExpression] in.) in thickness Atmospheric-corrosion resistance four

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

High temperature interfacial superconductivity  

DOE Patents (OSTI)

High-temperature superconductivity confined to nanometer-scale interfaces has been a long standing goal because of potential applications in electronic devices. The spontaneous formation of a superconducting interface in bilayers consisting of an insulator (La.sub.2CuO.sub.4) and a metal (La.sub.1-xSr.sub.xCuO.sub.4), neither of which is superconducting per se, is described. Depending upon the layering sequence of the bilayers, T.sub.c may be either .about.15 K or .about.30 K. This highly robust phenomenon is confined to within 2-3 nm around the interface. After exposing the bilayer to ozone, T.sub.c exceeds 50 K and this enhanced superconductivity is also shown to originate from a 1 to 2 unit cell thick interfacial layer. The results demonstrate that engineering artificial heterostructures provides a novel, unconventional way to fabricate stable, quasi two-dimensional high T.sub.c phases and to significantly enhance superconducting properties in other superconductors. The superconducting interface may be implemented, for example, in SIS tunnel junctions or a SuFET.

Bozovic, Ivan (Mount Sinai, NY); Logvenov, Gennady (Port Jefferson Station, NY); Gozar, Adrian Mihai (Port Jefferson, NY)

2012-06-19T23:59:59.000Z

122

Tribological behavior of NiTi alloy against 52100 steel and WC at elevated temperatures  

SciTech Connect

The dry tribological behavior of a Ti-50.3 at.% Ni alloy at temperatures of 25 deg. C, 50 deg. C and 200 deg. C was studied. The wear tests were performed on a high temperature pin-on-disk tribometer using 52100 steel and tungsten carbide pins. The worn surfaces of the NiTi alloy were examined by scanning electron microscope. The results showed that in the wear tests involving steel pins, the wear rate of the NiTi decreased as the wear testing temperature was increased. However, for the NiTi/WC contact, a reverse trend was observed. There was also a large decrease in the coefficient of friction for the NiTi/steel contact with increasing wear testing temperature. The formation of compact tribological layers could be the main reason for the reduction of the wear rate and coefficient of friction of the NiTi/steel contact at higher wear testing temperatures.

Abedini, M. [School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); Ghasemi, H.M., E-mail: hghasemi@ut.ac.ir [School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of); Ahmadabadi, M. Nili [School of Metallurgy and Materials Engineering, University of Tehran, Tehran (Iran, Islamic Republic of)

2010-07-15T23:59:59.000Z

123

Elastic Properties and Internal Friction of Two Magnesium Alloys at Elevated Temperatures  

SciTech Connect

The elastic properties and internal friction of two magnesium alloys were studied from 25 C to 450 C using Resonant Ultrasound Spectroscopy (RUS). The Young's moduli decrease with increasing temperature. At 200 C, a change in the temperature dependence of the elastic constants is observed. The internal friction increases significantly with increasing temperature above 200 C. The observed changes in the temperature dependence of the elastic constants and the internal friction are the result of anelastic relaxation by grain boundary sliding at elevated temperatures. Elastic properties govern the behavior of a materials subjected to stress over a region of strain where the material behaves elastically. The elastic properties, including the Young's modulus (E), shear modulus (G), bulk modulus (B), and Poisson's ratio (?), are of significant interest to many design and engineering applications. The choice of the most appropriate material for a particular application at elevated temperatures therefore requires knowledge of its elastic properties as a function of temperature. In addition, mechanical vibration can cause significant damage in the automotive, aerospace, and architectural industries and thus, the ability of a material to dissipate elastic strain energy in materials, known as damping or internal friction, is also important property. Internal friction can be the result of a wide range of physical mechanisms, and depends on the material, temperature, and frequency of the loading. When utilized effectively in engineering applications, the damping capacity of a material can remove undesirable noise and vibration as heat to the surroundings. The elastic properties of materials can be determined by static or dynamic methods. Resonant Ultrasound Spectroscopy (RUS), used in this study, is a unique and sophisticated non-destructive dynamic technique for determining the complete elastic tensor of a solid by measuring the resonant spectrum of mechanical resonance for a sample of known geometry, dimensions, and mass. In addition, RUS allows determination of internal friction, or damping, at different frequencies and temperatures. Polycrystalline pure magnesium (Mg) exhibits excellent high damping properties. However, the poor mechanical properties limit the applications of pure Mg. Although alloying can improve the mechanical properties of Mg, the damping properties are reduced with additions of alloying elements. Therefore, it becomes necessary to study and develop Mg-alloys with simultaneous high damping capacity and improved mechanical properties. Moreover, studies involving the high temperature dynamic elastic properties of Mg alloys are limited. In this study, the elastic properties and internal friction of two magnesium alloys were studied at elevated temperatures using RUS. The effect of alloy composition and grain size was investigated. The wrought magnesium alloys AZ31 and ZK60 were employed. Table 1 gives the nominal chemical compositions of these two alloys. The ZK60 alloy is a commercial extruded plate with a T5 temper, i.e. solution-treated at 535 C for two hours, quenched in hot water, and aged at 185 C for 24 hours. The AZ31 alloy is a commercial rolled plate with a H24 temper, i.e. strain hardened and partially annealed.

Freels, M.; Liaw, P. K.; Garlea, E.; Morrell, J. S.; Radiovic, M.

2011-06-01T23:59:59.000Z

124

High Temperature Superconductivity Partners | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

High Temperature Superconductivity Partners High Temperature Superconductivity Partners Map showing DOE's partnersstakeholders in the High Temperature Superconductivity Program...

125

Tailoring Fe-Base Alloys for Intermediate Temperature SOFC Interconnect Application  

DOE Green Energy (OSTI)

This report summarized the research efforts and major conclusions for our SECA Phase I and II project focused on Cr-free or low Cr Fe-Ni based alloy development for intermediate temperature solid oxide fuel cell (SOFC) interconnect application. Electrical conductivity measurement on bulk (Fe,Ni){sub 3}O{sub 4} coupons indicated that this spinel phase possessed a higher electrical conductivity than Cr{sub 1.5}Mn{sub 1.5}O{sub 4} spinel and Cr{sub 2}O{sub 3}, which was consistent with the low area specific resistance (ASR) of the oxide scale formed on these Fe-Ni based alloys. For Cr-free Fe-Ni binary alloys, although the increase in Ni content in the alloys improved the oxidation resistance, and the Fe-Ni binary alloys exhibited adequate CTE and oxide scale ASR, their oxidation resistance needs to be further improved. Systematic alloy design efforts have led to the identification of one low-Cr (6wt.%) Fe-Ni-Co based alloy which formed a protective, electrically-conductive Cr{sub 2}O{sub 3} inner layer underneath a Cr-free, highly conductive spinel outer layer. This low-Cr, Fe-Ni-Co alloy has demonstrated a good CTE match with other cell components; high oxidation resistance comparable to that of Crofer; low oxide scale ASR with the formation of electrically-insulating phases in the oxide scale; no scale spallation during thermal cycling; adequate compatibility with cathode materials; and comparable mechanical properties with Crofer. The existence of the Cr-free (Fe,Co,Ni){sub 3}O{sub 4} outer layer effectively reduced the Cr evaporation and in transpiration testing resulted in a 6-fold decrease in Cr evaporation as compared to a state-of-the-art ferritic interconnect alloy. In-cell testing using an anode supported cell with a configuration of Alloy/Pt/LSM/YSZ/Ni+YSZ indicates that the formation of the Cr-free spinel layer via thermal oxidation was effective in blocking the Cr migration and thus improving the cell performance stability. Electroplating of the Fe-Ni-Co alloys as precursor to synthesize a protective spinel layer on commercial ferritic steels has been initiated to facilitate the utilization of the Cr-free spinel as a surface seal to block Cr evaporation. It is suggested that low-cost Fe-Ni-Co alloy coating on commercial ferritic steels might be the best approach to completely eliminate the Cr poisoning problem in SOFC stacks, while maintaining the relatively low overall cost of the interconnect component.

J.H. Zhu; M.P. Brady; H.U. Anderson

2007-12-31T23:59:59.000Z

126

ANNEALING BEHAVIOR OF HIGH PERMEABILITY AMORPHOUS ALLOYS  

E-Print Network (OSTI)

thermal stability for power transformer applications. Alloysinduction amorphous alloys in power transformers results in

Rabenberg, L.

2010-01-01T23:59:59.000Z

127

Method of making high strength, tough alloy steel  

DOE Patents (OSTI)

A high strength, tough alloy steel, particularly suitable for the mining industry, is formed by heating the steel to a temperature in the austenite range (1000.degree.-1100.degree. C.) to form a homogeneous austenite phase and then cooling the steel to form a microstructure of uniformly dispersed dislocated martensite separated by continuous thin boundary films of stabilized retained austenite. The steel includes 0.2-0.35 weight % carbon, at least 1% and preferably 3-4.5% chromium, and at least one other subsitutional alloying element, preferably manganese or nickel. The austenite film is stable to subsequent heat treatment as by tempering (below 300.degree. C.) and reforms to a stable film after austenite grain refinement.

Thomas, Gareth (Berkeley, CA); Rao, Bangaru V. N. (Albany, CA)

1979-01-01T23:59:59.000Z

128

Highly Dispersed Alloy Cathode Catalyst for Durability  

NLE Websites -- All DOE Office Websites (Extended Search)

calculate: METHODS G rxni G rxni l Alloy - G rxni l Pt Computational chemistry methods help to understand catalytic activity and metal If G < 0 alloy atom easier to...

129

High Cycle Fatigue of ULTIMET Alloy  

Science Conference Proceedings (OSTI)

curves of this alloy regardless of the testing frequencies and environments. At 20 Hz ... The availability of fatigue data in ULTIMET alloy will provide new commercial .... perchloric, 90 ml distilled water, and 100 ml butylcellosolve was used for ...

130

Fabrication of Amorphous Alloy Surface Composites by High ... - TMS  

Science Conference Proceedings (OSTI)

Jun 1, 2007 ... Fabrication of Amorphous Alloy Surface Composites by High-Energy Electron- Beam Irradiation by K. Lee, S. Lee, and N.J. Kim ...

131

Fundamental Understanding of High-Entropy Alloy Formation and ...  

Science Conference Proceedings (OSTI)

Organizer(s), Michael Gao, National Energy Technology Lab Peter K Liaw, University of Tennessee. Scope, Recently, high-entropy alloys (HEAs) have attracted ...

132

Computational Thermodynamics Aided High-Entropy Alloy Design  

Science Conference Proceedings (OSTI)

Presentation Title, Computational Thermodynamics Aided High-Entropy Alloy Design. Author(s), Fan Zhang, Chuan Zhang, Weisheng Cao, Shuanglin Chen.

133

High Temperature and Electrical Properties  

Science Conference Proceedings (OSTI)

Mar 5, 2013... and Nanomaterials: High Temperature and Electrical Properties ... thermomechanical (or in cyclic power) loading of electronic devices is an ...

134

Ultra High Temperature Ceramic Composites  

Science Conference Proceedings (OSTI)

Oct 9, 2012 ... These ceramics, often combined with 20-30% SiC, have been studied extensively in monolithic form, demonstrating excellent high-temperature ...

135

High strength uranium-tungsten alloys  

SciTech Connect

Alloys of uranium and tungsten and a method for making the alloys. The amount of tungsten present in the alloys is from about 4 wt % to about 35 wt %. Tungsten particles are dispersed throughout the uranium and a small amount of tungsten is dissolved in the uranium.

Dunn, Paul S. (Santa Fe, NM); Sheinberg, Haskell (Los Alamos, NM); Hogan, Billy M. (Los Alamos, NM); Lewis, Homer D. (Bayfield, CO); Dickinson, James M. (Los Alamos, NM)

1991-01-01T23:59:59.000Z

136

High strength uranium-tungsten alloy process  

SciTech Connect

Alloys of uranium and tungsten and a method for making the alloys. The amount of tungsten present in the alloys is from about 4 wt % to about 35 wt %. Tungsten particles are dispersed throughout the uranium and a small amount of tungsten is dissolved in the uranium.

Dunn, Paul S. (Santa Fe, NM); Sheinberg, Haskell (Los Alamos, NM); Hogan, Billy M. (Los Alamos, NM); Lewis, Homer D. (Bayfield, CO); Dickinson, James M. (Los Alamos, NM)

1990-01-01T23:59:59.000Z

137

High-temperature ceramic receivers  

DOE Green Energy (OSTI)

An advanced ceramic dome cavity receiver is discussed which heats pressurized gas to temperatures above 1800/sup 0/F (1000/sup 0/C) for use in solar Brayton power systems of the dispersed receiver/dish or central receiver type. Optical, heat transfer, structural, and ceramic material design aspects of the receiver are reported and the development and experimental demonstration of a high-temperature seal between the pressurized gas and the high-temperature silicon carbide dome material is described.

Jarvinen, P. O.

1980-01-01T23:59:59.000Z

138

The Ductility of Haynes(r) 242 Alloy as a Function of Temperature ...  

Science Conference Proceedings (OSTI)

The Ductility of HAYNES@ 242TM Alloy as a Function of. Temperature, Strain Rate and Environment. Stephen D. Antolovich. Professor of Mechanical and ...

139

Embrittlement and DBTT of High-Burnup PWR Fuel Cladding Alloys | Department  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Embrittlement and DBTT of High-Burnup PWR Fuel Cladding Alloys Embrittlement and DBTT of High-Burnup PWR Fuel Cladding Alloys Embrittlement and DBTT of High-Burnup PWR Fuel Cladding Alloys Structural analyses of high-burnup (HBU) fuel require cladding mechanical properties and failure limits to assess fuel behavior during long-term dry-cask storage and transportation. Pre-storage drying-transfer operations and early stage storage subject cladding to higher temperatures and pressure-induced tensile hoop stresses relative to in-reactor operation and pool storage. Under these conditions, radial hydrides may precipitate during slow cooling and provide an additional embrittlement mechanism as the cladding temperature decreases below the ductile-to-brittle transition temperature (DBTT). Graphic and photographic details of the testing are

140

Discussion of High-Temperature Vacuum Creep for Selected ...  

Science Conference Proceedings (OSTI)

Precipitation strengthened refractory alloys are particularly of interest for Stirling engine application where temperature capability approaching 1200°C is ...

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Characterization of Elevated Temperature Properties of Heat Exchanger and Steam Generator Alloys  

Science Conference Proceedings (OSTI)

The Next Generation Nuclear Plant project is considering Alloy 800H and Alloy 617 for steam generator and intermediate heat exchangers. It is envisioned that a steam generator would operate with reactor outlet temperatures from 750 to 800°C, while an intermediate heat exchanger for primary to secondary helium would operate up to an outlet temperature of 950°C. Although both alloys are of interest due in part to their technical maturity, a number of specific properties require further characterization for design of nuclear components. Strain rate sensitivity of both alloys has been characterized and is found to be significant above 600°C. Both alloys also exhibit dynamic strain aging, characterized by serrated flow, over a wide range of temperatures and strain rates. In general dynamic strain aging is observed to begin at higher temperatures and serrated flow persists to higher temperatures in Alloy 617 compared to Alloy 800H. Dynamic strain aging is a concern for these materials since it is observed to result in reduced ductility for many solid solution alloys. The role of dynamic strain aging in the creep-fatigue behavior of Alloy 617 at temperatures of 800°C and above has also been examined in detail. Serrated flow is found to persist in cyclic stress-strain curves up to nearly the cycle to failure in some temperature and strain regimes. Results of those experiments and implications for creep-fatigue testing protocols will be described.

J.K. Wright; L.J. Carroll; J.K. Benz; J.A. Simpson; R.N. Wright; W.R. Lloyd; J.A. Chapman

2010-10-01T23:59:59.000Z

142

Titanium Alloys Production for High Temperature Applications  

Science Conference Proceedings (OSTI)

Lignocellulosic-Based Carbon Fibers from Biofuel Production Wastes · Magnesium Sheets Produced by Extrusion · Magnetite Formation Observed with TEM on ...

143

high temperature intergranular oxidation of alloy 718  

Science Conference Proceedings (OSTI)

Framatome ANP Fuel Division ; 10, rue J. Récamier ; 69456 Lyon Cedex, France. 2. Centre Inter-Universitaire de Recherche et d'Ingénierie des Matériaux ...

144

Performance of Metal Alloys at High Temperature  

Science Conference Proceedings (OSTI)

Oct 9, 2012... Sanchez1; Frances Perez1; Nayomi Plaza1; Wesly Cuadrado1; Andrea Lopez 1; Marcelo Suarez1; 1University of Puerto Rico, Mayaguez

145

New Environmental Challenges on High Temperature Alloys  

Science Conference Proceedings (OSTI)

Oct 27, 2009 ... Corrosion Resistant Metallic Materials for Ultra-deep Well Drilling ... tubular components during ultra-deep drilling of oil and natural gas shale.

146

N 18, a New Damage Tolerant PM Superalloy for High Temperature ...  

Science Conference Proceedings (OSTI)

and the properties of N 18. This new. P.M. alloy was designed for application in high temperature turbine discs. N 18 is strengthened by a high volume fraction.

147

High temperature turbine engine structure  

DOE Patents (OSTI)

A high temperature turbine engine includes a hybrid ceramic/metallic rotor member having ceramic/metal joint structure. The disclosed joint is able to endure higher temperatures than previously possible, and aids in controlling heat transfer in the rotor member.

Boyd, Gary L. (Tempe, AZ)

1990-01-01T23:59:59.000Z

148

High temperature structural insulating material  

DOE Patents (OSTI)

A high temperature structural insulating material useful as a liner for cylinders of high temperature engines through the favorable combination of high service temperature (above about 800/sup 0/C), low thermal conductivity (below about 0.2 W/m/sup 0/C), and high compressive strength (above about 250 psi). The insulating material is produced by selecting hollow ceramic beads with a softening temperature above about 800/sup 0/C, a diameter within the range of 20-200 ..mu..m, and a wall thickness in the range of about 2 to 4 ..mu..m; compacting the beads and a compatible silicate binder composition under pressure and sintering conditions to provide the desired structural form with the structure having a closed-cell, compact array of bonded beads.

Chen, W.Y.

1984-07-27T23:59:59.000Z

149

Temperature Effects on Impact Energy of Tungsten Alloy  

Science Conference Proceedings (OSTI)

Conference Tools for Materials Science & Technology 2010 ... made of these alloys could defeat the armour irrespective of extreme weather conditions.

150

High temperature lightweight foamed cements  

DOE Patents (OSTI)

Cement slurries are disclosed which are suitable for use in geothermal wells since they can withstand high temperatures and high pressures. The formulation consists of cement, silica flour, water, a retarder, a foaming agent, a foam stabilizer, and a reinforcing agent. A process for producing these cements is also disclosed. 3 figs.

Sugama, Toshifumi.

1989-10-03T23:59:59.000Z

151

High temperature lightweight foamed cements  

DOE Patents (OSTI)

Cement slurries are disclosed which are suitable for use in geothermal wells since they can withstand high temperatures and high pressures. The formulation consists of cement, silica flour, water, a retarder, a foaming agent, a foam stabilizer, and a reinforcing agent. A process for producing these cements is also disclosed.

Sugama, Toshifumi (Mastic Beach, NY)

1989-01-01T23:59:59.000Z

152

High temperature electronic gain device  

SciTech Connect

An integrated thermionic device suitable for use in high temperature, high radiation environments. Cathode and control electrodes are deposited on a first substrate facing an anode on a second substrate. The substrates are sealed to a refractory wall and evacuated to form an integrated triode vacuum tube.

McCormick, J. Byron (Los Alamos, NM); Depp, Steven W. (Los Alamos, NM); Hamilton, Douglas J. (Tucson, AZ); Kerwin, William J. (Tucson, AZ)

1979-01-01T23:59:59.000Z

153

Relative effects of enthalpy and entropy on the phase stability of equiatomic high-entropy alloys  

SciTech Connect

High configurational entropies have been hypothesized to stabilize solid solutions in equiatomic, multi-element alloys which have attracted much attention recently as high-entropy alloys with potentially interesting properties. To evaluate the usefulness of configurational entropy as a predictor of single-phase (solid solution) stability, we prepared five new equiatomic, quinary alloys by replacing individual elements one at a time in a CoCrFeMnNi alloy that was previously shown to be single-phase [1]. An implicit assumption here is that, if any one element is replaced by another, while keeping the total number of elements constant, the configurational entropy of the alloy is unchanged; therefore, the new alloys should also be single-phase. Additionally, the substitute elements that we chose, Ti for Co, Mo or V for Cr, V for Fe, and Cu for Ni, had the same room-temperature crystal structure and comparable size/electronegativity as the elements being replaced to maximize solid solubility consistent with the Hume-Rothery rules. For comparison, the base CoCrFeMnNi alloy was also prepared. After three-day anneals at elevated temperatures, multiple phases were observed in all but the base CoCrFeMnNi alloy suggesting that, by itself, configurational entropy is generally not able to override competing driving forces that also govern phase stability. Thermodynamic analyses were carried out for each of the constituent binaries in the investigated alloys (Co-Cr, Fe-Ni, Mo-Mn, etc,). Experimental results combined with the thermodynamic analyses suggest that, in general, enthalpy and non-configurational entropy have bigger influences on phase stability in equiatomic, multi-component alloys. Only when the alloy microstructure is a single-phase, approximately ideal solid solution does the contribution of configurational entropy to the total Gibbs free energy become dominant. Thus, high configurational entropy provides a way to rationalize, after the fact, why a solid solution forms (if it forms) but it is not a useful a priori predictor of which of the so-called high-entropy alloys will form single-phase solid solutions.

Otto, Frederik [ORNL; Yang, Ying [ORNL; Bei, Hongbin [ORNL; George, Easo P [ORNL

2013-01-01T23:59:59.000Z

154

High Temperature Optical Gas Sensing  

NLE Websites -- All DOE Office Websites (Extended Search)

Optical Gas Sensing Optical Gas Sensing Opportunity Research is active on optical sensors integrated with advanced sensing materials for high temperature embedded gas sensing applications. Patent applications have been filed for two inventions in this area and several other methods are currently under development. These technologies are available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory (NETL). Organizations or individuals with capabilities in optical sensor packaging for harsh environment and high temperature applications are encouraged to contact NETL to explore potential collaborative opportunities. Overview Contact NETL Technology Transfer Group techtransfer@netl.doe.gov

155

High temperature superconductor current leads  

DOE Patents (OSTI)

An electrical lead having one end for connection to an apparatus in a cryogenic environment and the other end for connection to an apparatus outside the cryogenic environment. The electrical lead includes a high temperature superconductor wire and an electrically conductive material distributed therein, where the conductive material is present at the one end of the lead at a concentration in the range of from 0 to about 3% by volume, and at the other end of the lead at a concentration of less than about 20% by volume. Various embodiments are shown for groups of high temperature superconductor wires and sheaths.

Hull, John R. (Hinsdale, IL); Poeppel, Roger B. (Glen Ellyn, IL)

1995-01-01T23:59:59.000Z

156

The Time-Temperature-Transformation Behavior of Alloy 706  

Science Conference Proceedings (OSTI)

that of the well documented INCONEL@ alloy 718. The effect ... then oil quenched (OC). Pieces from ... only a very small proportion of total y” and IJ . Annealed ...

157

High-strength, creep-resistant molybdenum alloy and process for producing the same  

DOE Patents (OSTI)

A wet-doping process for producing an oxide-dispersion strengthened (ODS), creep-resistant molybdenum alloy is disclosed. The alloy is made by adding nitrate or acetate salts of lanthanum, cerium, thorium, or yttrium to molybdenum oxide to produce a slurry, heating the slurry in a hydrogen atmosphere to produce a powder, mixing and cold isostatically pressing the powder, sintering in a hydrogen atmosphere, and thermomechanically processing (swaging, extruding, cold drawing) the product. The ODS molybdenum alloy produced by the process contains 2--4% by volume ({approximately}1--4% by weight) of an oxide of lanthanum, cerium, thorium, or yttrium. The alloy has high strength and improved creep-resistance at temperatures greater than 0.55T{sub m} of molybdenum.

Bianco, Robert; Buckman, Jr. William R.; Geller, Clint B.

1997-12-01T23:59:59.000Z

158

High-temperature plasma physics  

SciTech Connect

Both magnetic and inertial confinement research are entering the plasma parameter range of fusion reactor interest. This paper reviews the individual and common technical problems of these two approaches to the generation of thermonuclear plasmas, and describes some related applications of high-temperature plasma physics.

Furth, H.P.

1988-03-01T23:59:59.000Z

159

High temperature turbine engine structure  

DOE Patents (OSTI)

A high temperature turbine engine includes a rotor portion having axially stacked adjacent ceramic rotor parts. A ceramic/ceramic joint structure transmits torque between the rotor parts while maintaining coaxial alignment and axially spaced mutually parallel relation thereof despite thermal and centrifugal cycling.

Boyd, Gary L. (Tempe, AZ)

1991-01-01T23:59:59.000Z

160

High temperature size selective membranes  

DOE Green Energy (OSTI)

The objective of this research is to develop a high temperature size selective membrane capable of separating gas mixture components from each other based on molecular size, using a molecular sieving mechanism. The authors are evaluating two concepts: a composite of a carbon molecular sieve (CMS) with a tightly defined pore size distribution between 3 and 4 {angstrom}, and a microporous supporting matrix which provides mechanical strength and resistance to thermal degradation, and a sandwich of a CMS film between the porous supports. The high temperature membranes the authors are developing can be used to replace the current low-temperature unit operations for separating gaseous mixtures, especially hydrogen, from the products of the water gas shift reaction at high temperatures. Membranes that have a high selectivity and have both thermal and chemical stability would improve substantially the economics of the coal gasification process. These membranes can also improve other industrial processes such as the ammonia production and oil reform processes where hydrogen separation is crucial. Results of tests on a supported membrane and an unsupported carbon film are presented.

Yates, S.F.; Zhou, S.J.; Anderson, D.J.; Til, A.E. van

1994-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Geothermal high temperature instrumentation applications  

DOE Green Energy (OSTI)

A quick look at the geothermal industry shows a small industry producing about $1 billion in electric sales annually. The industry is becoming older and in need of new innovative solutions to instrumentation problems. A quick look at problem areas is given along with basic instrumentation requirements. The focus of instrumentation is on high temperature electronics.

Normann, R.A. [Sandia National Labs., Albuquerque, NM (United States); Livesay, B.J. [Livesay Consultants (United States)

1998-06-11T23:59:59.000Z

162

High temperature mineral fiber binder  

SciTech Connect

A modified phenol formaldehyde condensate is reacted with boric acid and cured in the presence of a polyfunctional nitrogeneous compound to provide a binder for mineral wool fibers which is particularly suited for thermal insulation products intended for high temperature service.

Miedaner, P.M.

1980-11-25T23:59:59.000Z

163

HIGH TEMPERATURE GEOTHERMAL RESERVOIR ENGINEERING  

E-Print Network (OSTI)

on the Cerro P r i e t o Geothermal F i e l d , Mexicali,e C e r r o P r i e t o Geothermal F i e l d , Baja C a l i1979 HIGH TEMPERATURE GEOTHERMAL RESERVOIR ENGINEERING R.

Schroeder, R.C.

2009-01-01T23:59:59.000Z

164

High-Dielectric Constant, High-Temperature Ceramic Capacitors for ...  

Science Conference Proceedings (OSTI)

Growth of Thick, On-Axis SiC Epitaxial Layers by High Temperature Halide CVD for High Voltage Power Devices · High-Dielectric Constant, High-Temperature ...

165

High temperature nuclear gas turbine  

SciTech Connect

Significance of gas turbine cycle, process of the development of gas turbines, cycle and efficiency of high-temperature gas turbines, history of gas turbine plants and application of nuclear gas turbines are described. The gas turbines are directly operated by the heat from nuclear plants. The gas turbines are classified into two types, namely open cycle and closed cycle types from the point of thermal cycle, and into two types of internal combustion and external combustion from the point of heating method. The hightemperature gas turbines are tbe type of internal combustion closed cycle. Principle of the gas turbines of closed cycle and open cycle types is based on Brayton, Sirling, and Ericsson cycles. Etficiency of the turbines is decided only by pressure ratio, and is independent of gas temperature. An example of the turbine cycle for the nuclear plant Gestacht II is explained. The thermal efficiency of that plant attains 37%. Over the gas temperature of about 750 deg C, the thermal efficiency of the gas turbine cycle is better than that of steam turbine cycle. As the nuclear fuel, coated particle fuel is used, and this can attain higher temperature of core outlet gas. Direct coupling of the nuclear power plants and the high temperature gas turbines has possibility of the higher thermal efficiency. (JA)

Kurosawa, A.

1973-01-01T23:59:59.000Z

166

Method for high temperature mercury capture from gas streams  

DOE Patents (OSTI)

A process to facilitate mercury extraction from high temperature flue/fuel gas via the use of metal sorbents which capture mercury at ambient and high temperatures. The spent sorbents can be regenerated after exposure to mercury. The metal sorbents can be used as pure metals (or combinations of metals) or dispersed on an inert support to increase surface area per gram of metal sorbent. Iridium and ruthenium are effective for mercury removal from flue and smelter gases. Palladium and platinum are effective for mercury removal from fuel gas (syngas). An iridium-platinum alloy is suitable for metal capture in many industrial effluent gas streams including highly corrosive gas streams.

Granite, E.J.; Pennline, H.W.

2006-04-25T23:59:59.000Z

167

Joint Institute for High Temperatures  

National Nuclear Security Administration (NNSA)

Joint Institute for High Temperatures of Russian Academy of Sciences Moscow Institute of Physics and Technology Extended title Extended title Excited state of warm dense matter or Exotic state of warm dense matter or Novel form of warm dense matter or New form of plasma Three sources of generation similarity: solid state density, two temperatures: electron temperature about tens eV, cold ions keep original crystallographic positions, but electron band structure and phonon dispersion are changed, transient but steady (quasi-stationary for a short time) state of non-equilibrium, uniform plasmas (no reference to non-ideality, both strongly and weakly coupled plasmas can be formed) spectral line spectra are emitted by ion cores embedded in plasma environment which influences the spectra strongly,

168

High Temperature Heat Exchanger Project  

Science Conference Proceedings (OSTI)

The UNLV Research Foundation assembled a research consortium for high temperature heat exchanger design and materials compatibility and performance comprised of university and private industry partners under the auspices of the US DOE-NE Nuclear Hydrogen Initiative in October 2003. The objectives of the consortium were to conduct investigations of candidate materials for high temperature heat exchanger componets in hydrogen production processes and design and perform prototypical testing of heat exchangers. The initial research of the consortium focused on the intermediate heat exchanger (located between the nuclear reactor and hydrogen production plan) and the components for the hydrogen iodine decomposition process and sulfuric acid decomposition process. These heat exchanger components were deemed the most challenging from a materials performance and compatibility perspective

Anthony E. Hechanova, Ph.D.

2008-09-30T23:59:59.000Z

169

High-temperature geothermal cableheads  

DOE Green Energy (OSTI)

Two high-temperature, corrosion-resistant logging cableheads which use metal seals and a stable fluid to achieve proper electrical terminations and cable-sonde interfacings are described. A tensile bar provides a calibrated yield point, and a cone assembly anchors the cable armor to the head. Electrical problems of the sort generally ascribable to the cable-sonde interface were absent during demonstration hostile-environment loggings in which these cableheads were used.

Coquat, J.A.; Eifert, R.W.

1981-11-01T23:59:59.000Z

170

HIGH TEMPERATURE MICROSCOPE AND FURNACE  

DOE Patents (OSTI)

A high-temperature microscope is offered. It has a reflecting optic situated above a molten specimen in a furnace and reflecting the image of the same downward through an inert optic member in the floor of the furnace, a plurality of spaced reflecting plane mirrors defining a reflecting path around the furnace, a standard microscope supported in the path of and forming the end terminus of the light path.

Olson, D.M.

1961-01-31T23:59:59.000Z

171

High temperature turbine engine structure  

DOE Patents (OSTI)

A high temperature ceramic/metallic turbine engine includes a metallic housing which journals a rotor member of the turbine engine. A ceramic disk-like shroud portion of the engine is supported on the metallic housing portion and maintains a close running clearance with the rotor member. A ceramic spacer assembly maintains the close running clearance of the shroud portion and rotor member despite differential thermal movements between the shroud portion and metallic housing portion.

Carruthers, William D. (Mesa, AZ); Boyd, Gary L. (Tempe, AZ)

1992-01-01T23:59:59.000Z

172

High temperature turbine engine structure  

DOE Patents (OSTI)

A high temperature ceramic/metallic turbine engine includes a metallic housing which journals a rotor member of the turbine engine. A ceramic disk-like shroud portion of the engine is supported on the metallic housing portion and maintains a close running clearance with the rotor member. A ceramic spacer assembly maintains the close running clearance of the shroud portion and rotor member despite differential thermal movements between the shroud portion and metallic housing portion.

Carruthers, William D. (Mesa, AZ); Boyd, Gary L. (Tempe, AZ)

1993-01-01T23:59:59.000Z

173

High temperature turbine engine structure  

DOE Patents (OSTI)

A high temperature ceramic/metallic turbine engine includes a metallic housing which journals a rotor member of the turbine engine. A ceramic disk-like shroud portion of the engine is supported on the metallic housing portion and maintains a close running clearance with the rotor member. A ceramic spacer assembly maintains the close running clearance of the shroud portion and rotor member despite differential thermal movements between the shroud portion and metallic housing portion.

Carruthers, William D. (Mesa, AZ); Boyd, Gary L. (Tempe, AZ)

1994-01-01T23:59:59.000Z

174

High temperature catalytic membrane reactors  

DOE Green Energy (OSTI)

Current state-of-the-art inorganic oxide membranes offer the potential of being modified to yield catalytic properties. The resulting modules may be configured to simultaneously induce catalytic reactions with product concentration and separation in a single processing step. Processes utilizing such catalytically active membrane reactors have the potential for dramatically increasing yield reactions which are currently limited by either thermodynamic equilibria, product inhibition, or kinetic selectivity. Examples of commercial interest include hydrogenation, dehydrogenation, partial and selective oxidation, hydrations, hydrocarbon cracking, olefin metathesis, hydroformylation, and olefin polymerization. A large portion of the most significant reactions fall into the category of high temperature, gas phase chemical and petrochemical processes. Microporous oxide membranes are well suited for these applications. A program is proposed to investigate selected model reactions of commercial interest (i.e. dehydrogenation of ethylbenzene to styrene and dehydrogenation of butane to butadiene) using a high temperature catalytic membrane reactor. Membranes will be developed, reaction dynamics characterized, and production processes developed, culminating in laboratory-scale demonstration of technical and economic feasibility. As a result, the anticipated increased yield per reactor pass economic incentives are envisioned. First, a large decrease in the temperature required to obtain high yield should be possible because of the reduced driving force requirement. Significantly higher conversion per pass implies a reduced recycle ratio, as well as reduced reactor size. Both factors result in reduced capital costs, as well as savings in cost of reactants and energy.

Not Available

1990-03-01T23:59:59.000Z

175

High-Temperature Superconductivity Cable Demonstration Projects...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

High-Temperature Superconductivity Cable Demonstration Projects High-Temperature Superconductivity Cable Demonstration Projects A National Effort to Introduce New Technology into...

176

High Performance Alloys for Advanced Combustion Systems  

Science Conference Proceedings (OSTI)

For steam turbines, it is necessary to raise temperatures in excess of 700?C. For gas turbines, raising the temperature also works but migrating the combustion ...

177

Precipitate Phases in Several High Temperature Shape Memory ...  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, Materials Science & Technology 2011. Symposium, Shape Memory Alloys. Presentation Title, Precipitate Phases in Several High ...

178

Ultra High Temperature | Open Energy Information  

Open Energy Info (EERE)

Ultra High Temperature Ultra High Temperature Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Print PDF Sanyal Temperature Classification: Ultra High Temperature Dictionary.png Ultra High Temperature: No definition has been provided for this term. Add a Definition Sanyal Temp Classification This temperature scheme was developed by Sanyal in 2005 at the request of DOE and GEA, as reported in Classification of Geothermal Systems: A Possible Scheme. Extremely Low Temperature Very Low Temperature Low Temperature Moderate Temperature High Temperature Ultra High Temperature Steam Field Reservoir fluid greater than 300°C is considered by Sanyal to be "ultra high temperature". "Such reservoirs are characterized by rapid development of steam saturation in the reservoir and steam fraction in the mobile fluid phase upon

179

A 5th Generation SC Superalloy with Balanced High Temperature ...  

Science Conference Proceedings (OSTI)

Alloy development for turbine blade materials with higher temperature capability is crucial in order to improve the thermal efficiency in gas turbine systems for ...

180

Hydrogen induced surface cracking in an 8090 Al-Li alloy during high cycle fatigue  

Science Conference Proceedings (OSTI)

In recent years, there has been an increasing interest in understanding the effects of aggressive or moist environments on the properties of Al-Li alloys. However, most of the existing work has been focused on their stress corrosion cracking resistance. Consequently, only a few reports are available on the environmental fatigue strength of these alloys. Upon exposure to aggressive environments, the fatigue crack propagation resistance can be detrimentally affected. R. Piascik and R. Gangloff found enhanced cyclic crack growth rates in an Al-Li-Cu alloy when a critical water vapor pressure was exceeded. Thermodynamically, at atmospheric pressures, strong interactions between hydrogen and lithium are expected to give rise to stable lithium hydrides. Evidence for the development of hydride phases in Al-Li alloys exposed to hydrogen environments has been reported by various workers. Thus, it is likely that HE via hydride formation can be the relevant mechanisms in Al-Li alloys that have been in contact with hydrogen. Since lithium hydrides are stable up to temperatures of 773 K, previous hydrogen exposure can lead to an irreversible mode of embrittlement. Thus, it was the objective of the present work to investigate the effects of hydrogen during aging on the ensuing high cycle fatigue (HCF) performance of an 8090 Al-Li alloy.

Laffin, C.; Raghunath, C.R.; Lopez, H.F. (Univ. of Wisconsin, Milwaukee, WI (United States). Materials Dept.)

1993-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

CONFINEMENT OF HIGH TEMPERATURE PLASMA  

DOE Patents (OSTI)

The confinement of a high temperature plasma in a stellarator in which the magnetic confinement has tended to shift the plasma from the center of the curved, U-shaped end loops is described. Magnetic means are provided for counteracting this tendency of the plasma to be shifted away from the center of the end loops, and in one embodiment this magnetic means is a longitudinally extending magnetic field such as is provided by two sets of parallel conductors bent to follow the U-shaped curvature of the end loops and energized oppositely on the inside and outside of this curvature. (AEC)

Koenig, H.R.

1963-05-01T23:59:59.000Z

182

High-Temperature Experiments using a Resistively-Heated High-Pressure Membrane Diamond Anvil Cell  

SciTech Connect

A reliable high-performance heating method using resistive heaters and a membrane driven diamond anvil cell (mDAC) is presented. Two micro-heaters are mounted in a mDAC and use electrical power of less than 150 W to achieve sample temperatures up to 1200 K. For temperature measurement we use two K-type thermocouples mounted near the sample. The approach can be used for in-situ Raman spectroscopy and x-ray diffraction at high pressures and temperatures. A W-Re alloy gasket material permits stable operation of mDAC at high temperature. Using this method, we made an isothermal compression at 900 K to pressures in excess of 100 GPa and isobaric heating at 95 GPa to temperatures in excess of 1000 K. As an example, we present high temperature Raman spectroscopy measurements of nitrogen at high pressures.

Jenei, Z; Visbeck, K; Cynn, H; Yoo, C; Evans, W

2009-04-22T23:59:59.000Z

183

HIGH TEMPERATURE SUPERCONDUCTORS-SYNTHESIS ... - TMS  

Science Conference Proceedings (OSTI)

... Anaheim, California. HIGH TEMPERATURE SUPERCONDUCTORS- SYNTHESIS, PROCESSING, AND LARGE SCALE APPLICATIONS VII: Characterization ...

184

HIGH TEMPERATURE SUPERCONDUCTORS: III: YBCO Conductor ...  

Science Conference Proceedings (OSTI)

HIGH TEMPERATURE SUPERCONDUCTORS: Session III: YBCO Conductor Development. Sponsored by: Jt: EMPMD/SMD Superconducting Materials ...

185

Optimization of high-temperature superconductor current leads  

SciTech Connect

Methods to improve the performance of high-temperature superconducting current leads are analyzed. Designs are considered that are inherently safe from burnup, even if the lead enters the normal state. The effect of a tapered lead that takes advantage of the increase in critical current density with decreasing temperature will decrease helium boiloff by about a factor of two for an area ratio of four. A new concept, in which Ag powder is distributed in increasing concentration from the cold end to the hot end of the lead in sintered YBCO, is shown to have comparable performance to that of leads made with Ag-alloy sheaths. Performance of the best inherently safe designs is about one order of magnitude better than that of optimized nonsuperconducting leads. BSCCO leads with Ag-alloy sheaths show improved performance for Au fractions up to about 3%, after which increases in Au fraction yield negligible performance improvement.

Seol, S.Y. [Chonnam National Univ., Kwangju (Korea, Democratic People`s Republic of); Hull, J.R. [Argonne National Lab., IL (United States); Chyu, M.C. [Texas Tech Univ., Lubbock, TX (United States). Dept. of Mechanical Engineering

1995-02-01T23:59:59.000Z

186

Insulator coating for high temperature alloys method for producing insulator coating for high temperature alloys  

DOE Patents (OSTI)

A method for fabricating an electrically insulating coating on a surface is disclosed comprising coating the surface with a metal, and reacting the metal coated surface with a nonmetal so as to create a film on the metal-coated surface. Alternatively, the invention provides for a method for producing a noncorrosive, electrically insulating coating on a surface saturated with a nonmetal comprising supplying a molten fluid, dissolving a metal in the molten fluid to create a mixture, and contacting the mixture with the saturated surface. Lastly, the invention provides an electrically insulative coating comprising an underlying structural substrate coated with an oxide or nitride compound. This invention has applications to breeding blankets for fusion reactors as well as to alkali metal thermal to electric converters.

Park, J.H.

1994-12-31T23:59:59.000Z

187

Oxidation of Fuel Cladding Candidate Materials in Steam Environments at High Temperature and Pressure  

SciTech Connect

Under certain severe accident conditions, the fuel rods of nuclear power plants are exposed to high temperature/pressure steam environments in which the Zr alloy cladding is rapidly oxidized. As alternative claddings, the oxidation resistances of SiC-based materials and stainless steels with high Cr and/or Al additions have been examined from 800-1200 C in high-pressure steam environments. Very low reaction kinetics were observed with alumina-forming FeCrAl alloys at 1200 C while Fe-Cr alloys with only 15-20% Cr were rapidly attacked.

Cheng, Ting [ORNL; Keiser, James R [ORNL; Brady, Michael P [ORNL; Terrani, Kurt A [ORNL; Pint, Bruce A [ORNL

2012-01-01T23:59:59.000Z

188

High-Yield Solvothermal Formation of Magnetic CoPt Alloy Nanowires  

SciTech Connect

One-dimensional (1D) magnetic nanomaterials have attracted much attention recently because of their applications in magnetic recording and spintronics. Nevertheless, it remains a challenge to prepare free-standing magnetic nanowires in high yield. This Communication reports the successful high-yield synthesis of an interesting 1D ferromagnetic CoPt alloy by direct decomposition of platinum acetylacetonate and cobalt carbonyl compound in ethylenediamine solvent through a solvothermal reaction. The CoPt alloy nanowires obtained have a tunable diameter of 10-50 nm and a length along the longitudinal axis of up to several microns, depending on crystallization temperature and reaction time. A unique formation mechanism involving coarsening and ripening under solvothermal conditions was discovered. This research opens new opportunities in synthesizing nanomaterials through low-temperature solvothermal processes.

Zhang, Zongtao [ORNL; Blom, Douglas Allen [ORNL; Gai, Zheng [ORNL; Thompson, James R [ORNL; Shen, Jian [ORNL; Dai, Sheng [ORNL

2003-01-01T23:59:59.000Z

189

Thermal disconnect for high-temperature batteries  

DOE Patents (OSTI)

A new type of high temperature thermal disconnect has been developed to protect electrical and mechanical equipment from damage caused by operation at extreme temperatures. These thermal disconnects allow continuous operation at temperatures ranging from 250.degree. C. to 450.degree. C., while rapidly terminating operation at temperatures 50.degree. C. to 150.degree. C. higher than the continuous operating temperature.

Jungst, Rudolph George (Albuquerque, NM); Armijo, James Rudolph (Albuquerque, NM); Frear, Darrel Richard (Austin, TX)

2000-01-01T23:59:59.000Z

190

Recent Developments in High Temperature Superconductivity  

E-Print Network (OSTI)

New material systems and the experimental progress of high temperature superconductivity are briefly reviewed. We examine both oxides and non-oxides which exhibit stable and/or unstable superconductivity at high temperatures.

Hor, P. H.

1988-09-01T23:59:59.000Z

191

High-temperature thermocouples and related methods  

DOE Patents (OSTI)

A high-temperature thermocouple and methods for fabricating a thermocouple capable of long-term operation in high-temperature, hostile environments without significant signal degradation or shortened thermocouple lifetime due to heat induced brittleness.

Rempe, Joy L. (Idaho Falls, ID); Knudson, Darrell L. (Firth, ID); Condie, Keith G. (Idaho Falls, ID); Wilkins, S. Curt (Idaho Falls, ID)

2011-01-18T23:59:59.000Z

192

High-temperature borehole instrumentation  

DOE Green Energy (OSTI)

A new method of extracting natural heat from the earth's crust was invented at the Los Alamos National Laboratory in 1970. It uses fluid pressures (hydraulic fracturing) to produce cracks that connect two boreholes drilled into hot rock formations of low initial permeability. Pressurized water is then circulated through this connected underground loop to extract heat from the rock and bring it to the surface. The creation of the fracture reservior began with drilling boreholes deep within the Precambrian basement rock at the Fenton Hill Test Site. Hydraulic fracturing, flow testing, and well-completion operations required unique wellbore measurements using downhole instrumentation systems that would survive the very high borehole temperatures, 320/sup 0/C (610/sup 0/F). These instruments were not available in the oil and gas industrial complex, so the Los Alamos National Laboratory initiated an intense program upgrading existing technology where applicable, subcontracting materials and equipment development to industrial manufactures, and using the Laboratory resource to develop the necessary downhole instruments to meet programmatic schedules. 60 refs., 11 figs.

Dennis, B.R.; Koczan, S.P.; Stephani, E.L.

1985-10-01T23:59:59.000Z

193

High Temperature Superconducting Underground Cable  

SciTech Connect

The purpose of this Project was to design, build, install and demonstrate the technical feasibility of an underground high temperature superconducting (HTS) power cable installed between two utility substations. In the first phase two HTS cables, 320 m and 30 m in length, were constructed using 1st generation BSCCO wire. The two 34.5 kV, 800 Arms, 48 MVA sections were connected together using a superconducting joint in an underground vault. In the second phase the 30 m BSCCO cable was replaced by one constructed with 2nd generation YBCO wire. 2nd generation wire is needed for commercialization because of inherent cost and performance benefits. Primary objectives of the Project were to build and operate an HTS cable system which demonstrates significant progress towards commercial progress and addresses real world utility concerns such as installation, maintenance, reliability and compatibility with the existing grid. Four key technical areas addressed were the HTS cable and terminations (where the cable connects to the grid), cryogenic refrigeration system, underground cable-to-cable joint (needed for replacement of cable sections) and cost-effective 2nd generation HTS wire. This was the world’s first installation and operation of an HTS cable underground, between two utility substations as well as the first to demonstrate a cable-to-cable joint, remote monitoring system and 2nd generation HTS.

Farrell, Roger, A.

2010-02-28T23:59:59.000Z

194

Elevated Temperature Compression Testing of the U-10 wt% Mo Alloy  

Science Conference Proceedings (OSTI)

Abstract Scope, In order to satisfy non-proliferation treaties the metallic U-10 wt% Mo (U-10Mo) alloy in low enrichments is under development to replace highly ...

195

Compact High-Temperature Superconducting Cable Wins ' ...  

Science Conference Proceedings (OSTI)

Compact High-Temperature Superconducting Cable Wins 'R&D 100' Award. From NIST Tech Beat: June 22, 2011. ...

2011-07-06T23:59:59.000Z

196

High temperature electronics application in well logging  

DOE Green Energy (OSTI)

Some limitations, problems, and needs are briefly reviewed for neutron logging tools used in high-temperature geothermal environments. (ACR)

Traeger, R.K.; Lysne, P.C.

1987-01-01T23:59:59.000Z

197

High Temperature Strain Gages for SOFC Application  

DOE Green Energy (OSTI)

This presentation discusses the investigation/extension of high temperature strain gage applications sensors to SOFC applications.

Pineault, R.L.; Johnson, C.; Gemmen, R.S.; Gregory, O.; You, T.

2005-01-27T23:59:59.000Z

198

HIGH TEMPERATURE SUPERCONDUCTORS: IV: BSCCO and ...  

Science Conference Proceedings (OSTI)

HIGH TEMPERATURE SUPERCONDUCTORS: Session IV: BSCCO and TBCCO Conductor Development. Sponsored by: Jt. EMPMD/SMD Superconducting ...

199

Experiment Hazard Class 3 - High Temperatures  

NLE Websites -- All DOE Office Websites (Extended Search)

* RF and Microwave * UV Light Hydrogen * Hydrogen Electronics * Electrical Equipment * High Voltage Other * Other Class 3 - High Temperatures Applicability The hazard controls...

200

Materials Degradation Studies for High Temperature Steam Electrolysis Systems  

DOE Green Energy (OSTI)

Experiments are currently in progress to assess the high temperature degradation behavior of materials in solid oxide electrolysis systems. This research includes the investigation of various electrolysis cell components and balance of plant materials under both anodic and cathodic gas atmospheres at temperatures up to 850°C. Current results include corrosion data for a high temperature nickel alloy used for the air-side flow field in electrolysis cells and a commercial ferritic stainless steel used as the metallic interconnect. Three different corrosion inhibiting coatings were also tested on the steel material. The samples were tested at 850ºC for 500 h in both air and H2O/H2 atmospheres. The results of this research will be used to identify degradation mechanisms and demonstrate the suitability of candidate materials for long-term operation in electrolysis cells.

Paul Demkowicz; Pavel Medvedev; Kevin DeWall; Paul Lessing

2007-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Environmental Cracking Resistance of High Nickel Alloys (CRAs  

Science Conference Proceedings (OSTI)

Environmentally Assisted Cracking of Carbon Steel in High Temperature Geothermal Well · Evaluation of the Susceptibility to Hydrogen Assisted Cracking in ...

202

High Temperature Optical Gas Sensing  

This series of inventions addresses harsh environment sensing at temperatures above approximately 400-500oC using novel sensing materials that are compatible with optical sensing platforms as well as more conventional resistive platforms. The sensors ...

203

High temperature superconducting fault current limiter  

DOE Patents (OSTI)

A fault current limiter for an electrical circuit is disclosed. The fault current limiter includes a high temperature superconductor in the electrical circuit. The high temperature superconductor is cooled below its critical temperature to maintain the superconducting electrical properties during operation as the fault current limiter. 15 figs.

Hull, J.R.

1997-02-04T23:59:59.000Z

204

Quantifying the economic and commercial potential of a high strength, low thermal coefficient super-alloy  

E-Print Network (OSTI)

Inspired by the importance of having a favourable sheathing material for superconducting wires, a high-strength, low thermal coefficient (CTE) super-alloy has been developed. Known as Incoloy 908, this super-alloy's material ...

Liew, Heng Lee Henry

2008-01-01T23:59:59.000Z

205

Deep Trek High Temperature Electronics Project  

Science Conference Proceedings (OSTI)

This report summarizes technical progress achieved during the cooperative research agreement between Honeywell and U.S. Department of Energy to develop high-temperature electronics. Objects of this development included Silicon-on-Insulator (SOI) wafer process development for high temperature, supporting design tools and libraries, and high temperature integrated circuit component development including FPGA, EEPROM, high-resolution A-to-D converter, and a precision amplifier.

Bruce Ohme

2007-07-31T23:59:59.000Z

206

High Temperature Creep Characterization of A380 Cast Aluminum ...  

Science Conference Proceedings (OSTI)

High Strength Aluminum Brazing Sheets for Condenser Fins of Automotive Heat ... for the Phase Formation in a Wide Range of Commercial Aluminum Alloys.

207

High-Temperature Galling Characteristics of Ti-6Al-4V with and without Surface Treatments  

SciTech Connect

Galling is a severe form of surface damage in metals and alloys that typically arises under relatively high normal force, low-sliding speed, and in the absence of effective lubrication. It can lead to macroscopic surface roughening and seizure. The occurrence of galling can be especially problematic in high-temperature applications like diesel engine exhaust gas recirculation system components and adjustable turbocharger vanes, because suitable lubricants may not be available, moisture desorption promotes increased adhesion, and the yield strength of metals decreases with temperature. Oxidation can counteract these effects to some extent by forming lubricative oxide films. Two methods to improve the galling resistance of titanium alloy Ti-6Al-4V were investigated: (a) applying an oxygen diffusion treatment, and (b) creating a metal-matrix composite with TiB2 using a high-intensity infrared heating source. A new, oscillating three-pin-on-flat, high-temperature test method was developed and used to characterize galling behavior relative to a cobalt-based alloy (Stellite 6B ). The magnitude of the oscillating torque, the surface roughness, and observations of surface damage were used as measures of galling resistance. Owing to the formation of lubricative oxide films, the galling resistance of the Ti-alloy at 485o C, even non-treated, was considerably better than it was at room temperature. The IR-formed composite displayed reduced surface damage and lower torque than the substrate titanium alloy.

Blau, Peter Julian [ORNL; ERDMAN III, DONALD L [ORNL; Ohriner, Evan Keith [ORNL; Jolly, Brian C [ORNL

2011-01-01T23:59:59.000Z

208

9 Cr-- 1 Mo steel material for high temperature application  

DOE Patents (OSTI)

One or more embodiments relates to a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650.degree. C. The 9 Cr-1 Mo steel has a tempered martensite microstructure and is comprised of both large (0.5-3 .mu.m) primary titanium carbides and small (5-50 nm) secondary titanium carbides in a ratio of. from about 1:1.5 to about 1.5:1. The 9 Cr-1 Mo steel may be fabricated using exemplary austenizing, rapid cooling, and tempering steps without subsequent hot working requirements. The 9 Cr-1 Mo steel exhibits improvements in total mass gain, yield strength, and time-to-rupture over ASTM P91 and ASTM P92 at the temperature and time conditions examined.

Jablonski, Paul D; Alman, David; Dogan, Omer; Holcomb, Gordon; Cowen, Christopher

2012-11-27T23:59:59.000Z

209

Nanotwins in Nanocrystalline Mg Alloys: An Insight from High ...  

Science Conference Proceedings (OSTI)

Characterisation of Nano-scaled Precipitates in a Peak Aged Mg-8Gd-2Dy Alloy ... of Nanostructured AZ91D Magnesium Alloy Under Oil-Lubricated Conditions.

210

HIGH TEMPERATURE SUPERCONDUCTORS: V: BSCCO ...  

Science Conference Proceedings (OSTI)

Transport current properties in bias fields for the other magnet with the outer ... Two obstacles to high field Jc over long lengths are poor flux pinning and ...

211

HIGH TEMPERATURE SUPERCONDUCTORS: I: BSCCO ...  

Science Conference Proceedings (OSTI)

Recently the high tensile strength conductor 100 m long was successfully fabricated and wound for the energizing test at 21 Tesla back up filed. The coil was ...

212

Research on Very High Temperature Gas Reactors  

Science Conference Proceedings (OSTI)

Very high temperature gas reactors are helium-cooled, graphite-moderated advanced reactors that show potential for generating low-cost electricity via gas turbines or cogeneration with process-heat applications. This investigation addresses the development status of advanced coatings for nuclear-fuel particles and high-temperature structural materials and evaluates whether these developments are likely to lead to economically competitive applications of the very high temperature gas reactor concept.

1991-08-08T23:59:59.000Z

213

Highly Dispersed Alloy Catalyst for Durability  

DOE Green Energy (OSTI)

Achieving DOE�¢����s stated 5000-hr durability goal for light-duty vehicles by 2015 will require MEAs with characteristics that are beyond the current state of the art. Significant effort was placed on developing advanced durable cathode catalysts to arrive at the best possible electrode for high performance and durability, as well as developing manufacturing processes that yield significant cost benefit. Accordingly, the overall goal of this project was to develop and construct advanced MEAs that will improve performance and durability while reducing the cost of PEMFC stacks. The project, led by UTC Power, focused on developing new catalysts/supports and integrating them with existing materials (membranes and gas diffusion layers (GDLs)) using state-of-the-art fabrication methods capable of meeting the durability requirements essential for automotive applications. Specifically, the project work aimed to lower platinum group metals (PGM) loading while increasing performance and durability. Appropriate catalysts and MEA configuration were down-selected that protects the membrane, and the layers were tailored to optimize the movements of reactants and product water through the cell to maximize performance while maintaining durability.

Vivek S. Murthi (Primary Contact), Elise Izzo, Wu Bi, Sandra Guerrero and Lesia Protsailo

2013-01-08T23:59:59.000Z

214

High-temperature brazed ceramic joints  

DOE Patents (OSTI)

High-temperature joints formed from metallized ceramics are disclosed wherein the metal coatings on the ceramics are vacuum sputtered thereon.

Jarvinen, Philip O. (Amherst, NH)

1986-01-01T23:59:59.000Z

215

High Temperature Interfacial Superconductivity - Energy Innovation ...  

Cuprate superconductors exhibit relatively high transition temperatures, but their unit cells are complex and large. Localizing a superconducting layer to a small ...

216

Development of Inorganic High Temperature Proton Exchange ...  

Science Conference Proceedings (OSTI)

For fuel cell systems directly coupled to a reformer, the primary advantage of high temperatures is the elimination of CO poisoning. Direct methanol fuel cells ...

217

Recent Developments in High Temperature Superconductivity  

Science Conference Proceedings (OSTI)

Scope, Recently, significant progress has been made world-wide in both fabrication and fundamental understanding of high-temperature superconductors (HTS) ...

218

Thermodynamic and Kinetic Properties of High Temperature ...  

Science Conference Proceedings (OSTI)

Perspectives on Phonons and Electron-Phonon Scattering in High-Temperature Superconductors · Prediction and Design of Materials from Crystal Structures to ...

219

Pressure Resistance Welding of High Temperature Metallic Materials  

Science Conference Proceedings (OSTI)

Pressure Resistance Welding (PRW) is a solid state joining process used for various high temperature metallic materials (Oxide dispersion strengthened alloys of MA957, MA754; martensitic alloy HT-9, tungsten etc.) for advanced nuclear reactor applications. A new PRW machine has been installed at the Center for Advanced Energy Studies (CAES) in Idaho Falls for conducting joining research for nuclear applications. The key emphasis has been on understanding processing-microstructure-property relationships. Initial studies have shown that sound joints can be made between dissimilar materials such as MA957 alloy cladding tubes and HT-9 end plugs, and MA754 and HT-9 coupons. Limited burst testing of MA957/HT-9 joints carried out at various pressures up to 400oC has shown encouraging results in that the joint regions do not develop any cracking. Similar joint strength observations have also been made by performing simple bend tests. Detailed microstructural studies using SEM/EBSD tools and fatigue crack growth studies of MA754/HT-9 joints are ongoing.

N. Jerred; L. Zirker; I. Charit; J. Cole; M. Frary; D. Butt; M. Meyer; K. L. Murty

2010-10-01T23:59:59.000Z

220

Investigations into High Temperature Components and Packaging  

SciTech Connect

The purpose of this report is to document the work that was performed at the Oak Ridge National Laboratory (ORNL) in support of the development of high temperature power electronics and components with monies remaining from the Semikron High Temperature Inverter Project managed by the National Energy Technology Laboratory (NETL). High temperature electronic components are needed to allow inverters to operate in more extreme operating conditions as required in advanced traction drive applications. The trend to try to eliminate secondary cooling loops and utilize the internal combustion (IC) cooling system, which operates with approximately 105 C water/ethylene glycol coolant at the output of the radiator, is necessary to further reduce vehicle costs and weight. The activity documented in this report includes development and testing of high temperature components, activities in support of high temperature testing, an assessment of several component packaging methods, and how elevated operating temperatures would impact their reliability. This report is organized with testing of new high temperature capacitors in Section 2 and testing of new 150 C junction temperature trench insulated gate bipolar transistor (IGBTs) in Section 3. Section 4 addresses some operational OPAL-GT information, which was necessary for developing module level tests. Section 5 summarizes calibration of equipment needed for the high temperature testing. Section 6 details some additional work that was funded on silicon carbide (SiC) device testing for high temperature use, and Section 7 is the complete text of a report funded from this effort summarizing packaging methods and their reliability issues for use in high temperature power electronics. Components were tested to evaluate the performance characteristics of the component at different operating temperatures. The temperature of the component is determined by the ambient temperature (i.e., temperature surrounding the device) plus the temperature increase inside the device due the internal heat that is generated due to conduction and switching losses. Capacitors and high current switches that are reliable and meet performance specifications over an increased temperature range are necessary to realize electronics needed for hybrid-electric vehicles (HEVs), fuel cell (FC) and plug-in HEVs (PHEVs). In addition to individual component level testing, it is necessary to evaluate and perform long term module level testing to ascertain the effects of high temperature operation on power electronics.

Marlino, L.D.; Seiber, L.E.; Scudiere, M.B.; M.S. Chinthavali, M.S.; McCluskey, F.P.

2007-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Fusion blanket high-temperature heat transfer  

DOE Green Energy (OSTI)

Deep penetration of 14 MeV neutrons makes two-temperature region blankets feasible. A relatively low-temperature (approx. 300/sup 0/C) metallic structure is the vacuum/coolant pressure boundary, while the interior of the blanket, which is a simple packed bed of nonstructural material, operates at very high temperatures (>1000/sup 0/C). The water-cooled shell structure is thermally insulated from the steam-cooled interior. High-temperature steam can dramatically increase the efficiency of electric power generation, as well as produce hydrogen and oxygen-based synthetic fuels at high-efficiency.

Fillo, J.A.

1983-01-01T23:59:59.000Z

222

High Quality, Dense Thin Films Using Metal/Metal Alloy ...  

Berkeley Lab researchers Mike Tucker, Grace Lau, and Craig Jacobson have invented a novel layered structure for preparing a high-operating temperature ...

223

High Entropy Alloys a New Class of Structural Materials: Magnetism ...  

Science Conference Proceedings (OSTI)

Perspectives on Phonons and Electron-Phonon Scattering in High-Temperature Superconductors · Prediction and Design of Materials from Crystal Structures to ...

224

High-temperature borehole instrumentation  

DOE Green Energy (OSTI)

Research in materials, equipment, and instrument development was required in the Hot Dry Rock Energy Extraction Demonstration at Fenton Hill located in northern New Mexico. The new Phase II Energy Extraction System at the Fenton Hill Test Site will consist of two wellbores drilled to a depth of about 4570 m (15,000 ft) and then connected by a series of hydraulic-induced fractures. The first borehole (EE-2) was completed in May of 1980, at a depth of 4633 m (15,200 ft) of which approximately 3960 m (13,000 ft) is in Precambrian granitic rock. Starting at a depth of approximately 2930 m (9600 ft), the borehole was inclined up to 35/sup 0/ from vertical. Bottom-hole temperature in EE-2 is 317/sup 0/C. The EE-3 borehole was then drilled to a depth of 4236 m (13,900 ft). Its inclined part is positioned directly over the EE-2 wellbore with a vertical separation of about 450 m (1500 ft) between them. The materials development programs cover all aspects of geothermal energy extraction. Research on drilling, hydraulic fracturing, and wellbore logging were necessary to determine the technical and economic feasibility of the hot dry rock concepts.

Dennis, B.R.; Koczan, S.; Cruz, J.

1982-01-01T23:59:59.000Z

225

High-temperature electronics: an overview  

DOE Green Energy (OSTI)

A summary is presented providing an overview of contemporary high-temperature electronics and identifying the major areas where developments are needed and the laboratories where research is being conducted. The geothermal program, high-temperature oil and gas well logging, jet engine monitors, and circuits for operation in the sodium coolant loop of the Clinch River Breeder reactor have stimulated research. (FS)

Heckman, R.C.

1979-01-01T23:59:59.000Z

226

High Temperature Electrochemistry Center - HiTEC  

DOE Green Energy (OSTI)

This presentation discusses the High Temperature Electrochemistry Center (HiTEC). The mission of HiTEC is to advance the solid oxide technology, such as solid oxide, high temperature electrolysers, reversible fuel cells, energy storage devices, proton conductors, etc., for use in DG and FutureGen applications, and to conduct fundamental research that aids the general development of all solid oxide technology.

McVay, G.; Williams, M.

2005-01-27T23:59:59.000Z

227

The Effects of Test Temperature, Temper, and Alloyed Copper on the Hydrogen-Controlled Crack Growth Rate of an Al-Zn-Mg-(Cu) Alloy  

DOE Green Energy (OSTI)

The hydrogen embrittlement controlled stage II crack growth rate of AA 7050 (6.09 wt.% Zn, 2.14 wt% Mg, 2.19 wt.% Cu) was investigated as a function of temper and alloyed copper level in a humid air environment at various temperatures. Three tempers representing the underaged, peak aged, and overaged conditions were tested in 90% relative humidity (RH) air at temperatures between 25 and 90 C. At all test temperatures, an increased degree of aging (from underaged to overaged) produced slower stage II crack growth rates. The stage II crack growth rate of each alloy and temper displayed Arrhenius-type temperature dependence with activation energies between 58 and 99 kJ/mol. For both the normal copper and low copper alloys, the fracture path was predominantly intergranular at all test temperatures (25-90 C) in each temper investigated. Comparison of the stage II crack growth rates for normal (2.19 wt.%) and low (0.06 wt.%) copper alloys in the peak aged and overaged tempers showed the beneficial effect of copper additions on stage II crack growth rate in humid air. In the 2.19 wt.% copper alloy, the significant decrease ({approx} 10 times at 25 C) in stage II crack growth rate upon overaging is attributed to an increase in the apparent activation energy for crack growth. IN the 0.06 wt.% copper alloy, overaging did not increase the activation energy for crack growth but did lower the pre-exponential factor, {nu}{sub 0}, resulting in a modest ({approx} 2.5 times at 25 C) decrease in crack growth rate. These results indicate that alloyed copper and thermal aging affect the kinetic factors that govern stage II crack growth rate. Overaged, copper bearing alloys are not intrinsically immune to hydrogen environment assisted cracking but are more resistant due to an increased apparent activation energy for stage II crack growth.

G.A. Young, Jr.; J.R. Scully

2000-09-17T23:59:59.000Z

228

NGNP/HTE full-power operation at reduced high-temperature heat exchanger temperatures.  

Science Conference Proceedings (OSTI)

Operation of the Next Generation Nuclear Plant (NGNP) with reduced reactor outlet temperature at full power was investigated for the High Temperature Electrolysis (HTE) hydrogen-production application. The foremost challenge for operation at design temperature is achieving an acceptably long service life for heat exchangers. In both the Intermediate Heat Exchanger (IHX) and the Process Heat Exchanger (PHX) (referred to collectively as high temperature heat exchangers) a pressure differential of several MPa exists with temperatures at or above 850 C. Thermal creep of the heat exchanger channel wall may severely limit heat exchanger life depending on the alloy selected. This report investigates plant performance with IHX temperatures reduced by lowering reactor outlet temperature. The objective is to lower the temperature in heat transfer channels to the point where existing materials can meet the 40 year lifetime needed for this component. A conservative estimate for this temperature is believed to be about 700 C. The reactor outlet temperature was reduced from 850 C to 700 C while maintaining reactor power at 600 MWt and high pressure compressor outlet at 7 MPa. We included a previously reported design option for reducing temperature at the PHX. Heat exchanger lengths were adjusted to reflect the change in performance resulting from coolant property changes and from resizing related to operating-point change. Turbomachine parameters were also optimized for the new operating condition. An integrated optimization of the complete system including heat transfer equipment was not performed. It is estimated, however, that by performing a pinch analysis the combined plant efficiency can be increased from 35.5 percent obtained in this report to a value between 38.5 and 40.1 percent. Then after normalizing for a more than three percent decrease in commodities inventory compared to the reference plant, the commodities-normalized efficiency lies between 40.0 and 41.3. This compares with a value of 43.9 for the reference plant. This latter plant has a reactor outlet temperature of 850 C and the two high temperature heat exchangers. The reduction in reactor outlet temperature from 850 C to 700 C reduces the tritium permeability rate in the IHX metal by a factor of three and thermal creep by five orders of magnitude. The design option for reducing PHX temperature from 800 C to 200 C reduces the permeability there by three orders of magnitude. In that design option this heat exchanger is the single 'choke-point' for tritium migration from the nuclear to the chemical plant.

VIlim, R.; Nuclear Engineering Division

2009-03-12T23:59:59.000Z

229

High pressure-high temperature effect on the HTSC ceramics structure and properties  

Science Conference Proceedings (OSTI)

Keywords: high pressures-high temperatures, high temperature superconductors, mechanical properties, structure, superconductive

T. A. Prikhna

1995-12-01T23:59:59.000Z

230

Fabrication and Design Aspects of High-Temperature Compact Diffusion Bonded Heat Exchangers  

SciTech Connect

The very high temperature reactor (VHTR), using gas-cooled reactor technology, is one of the six reactor concepts selected by the Generation IV International Forum and is anticipated to be the reactor type for the next generation nuclear plant (NGNP). In this type of reactor with an indirect power cycle system, a high-temperature and high integrity intermediate heat exchanger (IHX) with high effectiveness is required to efficiently transfer the core thermal output to secondary fluid for electricity production, process heat, or hydrogen cogeneration. The current Technology Readiness Level status issued by NGNP to all components associated with the IHX for reactor core outlet temperatures of 750-800oC is 3 on a scale of 1 to 10 with 10 being the most ready. At present, there is no proven high-temperature IHX concept for VHTRs. Amongst the various potential IHX concepts available, diffusion bonded heat exchangers (henceforth called printed circuit heat exchangers, or PCHEs) appear promising for NGNP applications. The design and fabrication of this key component of NGNP is the primary focus of this paper. In the current study, two PCHEs were fabricated using Alloy 617 plates and will be experimentally investigated for their thermal-hydraulic performance in a high-temperature helium test facility (HTHF). The HTHF was primarily designed and constructed to test the thermal-hydraulic performance of PCHEs The test facility is primarily of Alloy 800H construction and is designed to facilitate experiments at temperatures and pressures up to 800oC and 3 MPa, respectively. The PCHE fabrication related processes, i.e., photochemical machining and diffusion bonding are briefly discussed for Alloy 617 plates. Diffusion bonding of Alloy 617 plates with and without a Ni interlayer is discussed. Furthermore, preliminary microstructural and mechanical characterization studies of representative diffusion bonded Alloy 617 specimens are presented.

Mylavarapu, Sai K. [Ohio State University; Sun, Xiaodong [Ohio State University; Christensen, Richard N. [Ohio State University; Glosup, Richard E. [Ohio State University; Unocic, Raymond R [ORNL

2012-01-01T23:59:59.000Z

231

Radiation Effects on a High Strength, High Conductivity Copper Alloy  

Science Conference Proceedings (OSTI)

Presentation Title, Radiation Effects on a High Strength, High Conductivity Copper ... of Zircaloy during Low Dose Neutron Irradiation at Nominally 375-440° C.

232

High Temperature Titanium: Applications, Processing, and Properties  

Science Conference Proceedings (OSTI)

Oct 20, 2010 ... Other potential applications for titanium aluminides are casings or compressor blades. Titanium aluminide alloys with intermediate niobium ...

233

Overcharge tolerant high-temperature cells and batteries  

DOE Patents (OSTI)

In a lithium-alloy/metal sulfide high temperature electrochemical cell, cell damage caused by overcharging is avoided by providing excess lithium in a high-lithium solubility phase alloy in the negative electrode and a specified ratio maximum of the capacity of a matrix metal of the negative electrode in the working phase to the capacity of a transition metal of the positive electrode. In charging the cell, or a plurality of such cells in series and/or parallel, chemical transfer of elemental lithium from the negative electrode through the electrolyte to the positive electrode provides sufficient lithium to support an increased self-charge current to avoid anodic dissolution of the positive electrode components above a critical potential. The lithium is subsequently electrochemically transferred back to the negative electrode in an electrochemical/chemical cycle which maintains high self-discharge currents on the order of 3-15 mA/cm.sup.2 in the cell to prevent overcharging.

Redey, Laszlo (Downers Grove, IL); Nelson, Paul A. (Wheaton, IL)

1989-01-01T23:59:59.000Z

234

High-throughput Evaluation of Crystallization Temperature of Pd-Cu ...  

Science Conference Proceedings (OSTI)

Temperature and Magnetic Field Dependence of Electrical Resistance in Trilayer and Fourlayer Graphene ... Tool Failure Criteria while Drilling Titanium Alloys.

235

Symposium on high temperature and materials chemistry  

SciTech Connect

This volume contains the written proceedings of the Symposium on High Temperature and Materials Chemistry held in Berkeley, California on October 24--25, 1989. The Symposium was sponsored by the Materials and Chemical Sciences Division of Lawrence Berkeley Laboratory and by the College of Chemistry of the University of California at Berkeley to discuss directions, trends, and accomplishments in the field of high temperature and materials chemistry. Its purpose was to provide a snapshot of high temperature and materials chemistry and, in so doing, to define status and directions.

1989-10-01T23:59:59.000Z

236

Band anticrossing effects in highly mismatched semiconductor alloys  

DOE Green Energy (OSTI)

The first five chapters of this thesis focus on studies of band anticrossing (BAC) effects in highly electronegativity- mismatched semiconductor alloys. The concept of bandgap bowing has been used to describe the deviation of the alloy bandgap from a linear interpolation. Bowing parameters as large as 2.5 eV (for ZnSTe) and close to zero (for AlGaAs and ZnSSe) have been observed experimentally. Recent advances in thin film deposition techniques have allowed the growth of semiconductor alloys composed of significantly different constituents with ever- improving crystalline quality (e.g., GaAs{sub 1-x}N{sub x} and GaP{sub 1-x}N{sub x} with x {approx}< 0.05). These alloys exhibit many novel and interesting properties including, in particular, a giant bandgap bowing (bowing parameters > 14 eV). A band anticrossing model has been developed to explain these properties. The model shows that the predominant bowing mechanism in these systems is driven by the anticrossing interaction between the localized level associated with the minority component and the band states of the host. In this thesis I discuss my studies of the BAC effects in these highly mismatched semiconductors. It will be shown that the results of the physically intuitive BAC model can be derived from the Hamiltonian of the many-impurity Anderson model. The band restructuring caused by the BAC interaction is responsible for a series of experimental observations such as a large bandgap reduction, an enhancement of the electron effective mass, and a decrease in the pressure coefficient of the fundamental gap energy. Results of further experimental investigations of the optical properties of quantum wells based on these materials will be also presented. It will be shown that the BAC interaction occurs not only between localized states and conduction band states at the Brillouin zone center, but also exists over all of k-space. Finally, taking ZnSTe and ZnSeTe as examples, I show that BAC also occurs between localized states and the valence band states. Soft x-ray fluorescence experiments provide direct evidence of the BAC interaction in these systems. In the final chapter of the thesis, I describe and summarize my studies of optical properties of wurtzite InN and related alloys. Early studies performed on InN films grown by sputtering techniques suggested a direct bandgap of {approx}1.9 eV for this semiconductor. Very recently, high-quality InN films with much higher mobility have become available by using the molecular beam epitaxy growth method. Optical experiments carried out on these samples reveal a narrow bandgap for InN of 0.77 eV, much lower than the previously accepted value. Optical properties of InGaN and InAlN ternaries on the In rich side have also been characterized and are found to be consistent with the narrow bandgap of InN. The bandgap bowing parameters in these alloys were determined. In the context of these findings, the bandgap energies of InGaN and InAlN were found to cover a wide spectral range from the infrared for InN to the ultraviolet for GaN and deep ultraviolet for AlN. The significance of this work is rooted in many important applications of nitride semiconductors in optoelectronics and solar energy conversion devices.

Wu, Junqiao

2002-09-09T23:59:59.000Z

237

Processing of High Performance Alloys for A-USC Steam Turbine ...  

Science Conference Proceedings (OSTI)

Fracture Toughness Evaluation of Polymeric Materials for Wind Turbine Blades Using the Spiral Notch Torsion Test · High Performance Alloys for Advanced ...

238

Alloy Design of 9% Cr Steel for High Efficiency Ultra-Supercritical ...  

Science Conference Proceedings (OSTI)

Presentation Title, Alloy Design of 9% Cr Steel for High Efficiency Ultra- Supercritical Power Plants. Author(s), Fujio Abe. On-Site Speaker (Planned), Fujio Abe.

239

High temperature spectral gamma well logging  

Science Conference Proceedings (OSTI)

A high temperature spectral gamma tool has been designed and built for use in small-diameter geothermal exploration wells. Several engineering judgments are discussed regarding operating parameters, well model selection, and signal processing. An actual well log at elevated temperatures is given with spectral gamma reading showing repeatability.

Normann, R.A.; Henfling, J.A.

1997-01-01T23:59:59.000Z

240

High temperature ceramic/metal joint structure  

DOE Patents (OSTI)

A high temperature turbine engine includes a hybrid ceramic/metallic rotor member having ceramic/metal joint structure. The disclosed joint is able to endure higher temperatures than previously possible, and aids in controlling heat transfer in the rotor member.

Boyd, Gary L. (Tempe, AZ)

1991-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Live Work with High Temperature Conductors  

Science Conference Proceedings (OSTI)

This report examines issues that may arise when live work is undertaken on conductors that operate at high temperatures (HT conductors) and provides the results from selected tests on the temperature levels reached by tools in contact with hot conductors. It also discusses possible concerns that may arise during de-energized work on lines that use HT conductors.

2009-12-15T23:59:59.000Z

242

High temperature materials technology research for advanced thermionic systems. Final report  

DOE Green Energy (OSTI)

Tungsten and tungsten alloys are candidate materials for the thermionic emitter in the space nuclear power convertor. In this work, the creep behavior of HfC strengthened tungsten alloys was studied. An ultrahigh vacuum, high precision creep test system was constructed for this purpose so that the samples could be heated up to 3,000 K for heat treatment and creep strain could be measured from the creep sample inside the UHV chamber. To explain the creep behavior observed in this dispersion strengthened alloy, a creep model was proposed which accounted for the presence of HfC particles in the form of a back stress generated by these particles. This model was verified by the creep test data of W-0.37 HfC alloys tested under both extruded and recrystallized microstructural conditions. According to this model, the steady state creep of this type of alloys was expected to increase with time due to coarsening of HfC particle and recrystallization of the alloys under high temperatures. In contrast, conventional simple power law creep model only predicts a constant steady state creep for these materials, which does not represent the microstructural evolution of the materials. The creep of solid solution alloys such as W-Re, W-Nb and W-Hf and Mo-Nb was also studied. These materials are expected to be more stable in creep properties due to the absence of coarsening particles. These solid solution alloys, in their single crystalline state, are reported possessing better corrosion resistance over their polycrystalline counterparts. Existing creep data of both solid solution tungsten and molybdenum alloys were re-analyzed. The data of these alloys showed two distinct different creep mechanisms: Class I and Class II. The dominating creep mechanism at low stresses could be explained by the Takuchi-Argon model (Class I). At higher stresses, the data could not be explained by any of the existing creep models. A creep model was thus proposed that contained a shift factor due to the effect of the solute in these alloys. In this model, the Class II creep behavior of these solution alloys were found as a function of the alloy concentration and atomic size mismatch.

Zee, R.H.; Rose, M.F.

1998-09-01T23:59:59.000Z

243

High temperature thermometric phosphors for use in a temperature sensor  

SciTech Connect

A high temperature phosphor consists essentially of a material having the general formula LuPO.sub.4 :Dy.sub.(x),Eu.sub.(y), wherein: 0.1 wt %.ltoreq.x.ltoreq.20 wt % and 0.1 wt %.ltoreq.y.ltoreq.20 wt %. The high temperature phosphor is in contact with an article whose temperature is to be determined. The article having the phosphor in contact with it is placed in the environment for which the temperature of the article is to be determined. The phosphor is excited by a laser causing the phosphor to fluoresce. The emission from the phosphor is optically focused into a beam-splitting mirror which separates the emission into two separate emissions, the emission caused by the dysprosium dopant and the emission caused by the europium dopent. The separated emissions are optically filtered and the intensities of the emission are detected and measured. The ratio of the intensity of each emission is determined and the temperature of the article is calculated from the ratio of the intensities of the separate emissions.

Allison, Stephen W. (Knoxville, TN); Cates, Michael R. (Oak Ridge, TN); Boatner, Lynn A. (Oak Ridge, TN); Gillies, George T. (Earlysville, VA)

1998-01-01T23:59:59.000Z

244

Thermally activated low temperature creep and primary water stress corrosion cracking of NiCrFe alloys  

Science Conference Proceedings (OSTI)

A phenomenological SCC-CGR model is developed based on an apriori assumption that the SCC-CGR is controlled by low temperature creep (LTC). This mode of low temperature time dependent deformation occurs at stress levels above the athermal flow stress by a dislocation glide mechanism that is thermally activated and may be environmentally assisted. The SCC-CGR model equations developed contain thermal activation parameters descriptive of the dislocation creep mechanism. Thermal activation parameters are obtained by fitting the CGR model to SCC-CGR data obtained on Alloy 600 and Alloy X-750. These SCC-CGR activation parameters are compared to LTC activation parameters obtained from stress relaxation tests. When the high concentration of hydrogen at the tip of an SCC crack is considered, the SCC-CGR activation energies and rate sensitivities are shown to be quantitatively consistent with hydrogen reducing the activation energy and increasing the strain rate sensitivity in LTC stress relaxation tests. Stress dependence of SCC-CGR activation energy consistent with that found for the LTC activation energy. Comparisons between temperature dependence of the SCC-CGR stress sensitivity and LTC stress sensitivity provide a basis for speculation on effects of hydrogen and solute carbon on SCC crack growth rates.

Hall, M.M. Jr.

1993-10-01T23:59:59.000Z

245

Variable pressure insulating jackets for high-temperature batteries  

DOE Green Energy (OSTI)

A new method is proposed for controlling the temperature of high-temperature batteries namely, varying the hydrogen pressure inside of multifoil insulation by varying the temperature of a reversible hydrogen getter. Calculations showed that the rate of heat loss through 1.5 cm of multifoil insulation between a hot-side temperature of 425[degrees]C and a cold-side temperature of 25[degrees]C could be varied between 17.6 W/m[sup 2] and 7,000 W/m[sup 2]. This change in heat transfer rate can be achieved by varying the hydrogen pressure between 1.0 Pa and 1,000 Pa, which can be done with an available hydrogen gettering alloy operating in the range of 50[degrees]C to 250[degrees]C. This approach to battery cooling requires cylindrical insulating jackets, which are best suited for bipolar batteries having round cells approximately 10 to 18 cm in diameter.

Nelson, P.A.; Chilenskas, A.A.; Malecha, R.F.

1992-01-01T23:59:59.000Z

246

Variable pressure insulating jackets for high-temperature batteries  

DOE Green Energy (OSTI)

A new method is proposed for controlling the temperature of high-temperature batteries namely, varying the hydrogen pressure inside of multifoil insulation by varying the temperature of a reversible hydrogen getter. Calculations showed that the rate of heat loss through 1.5 cm of multifoil insulation between a hot-side temperature of 425{degrees}C and a cold-side temperature of 25{degrees}C could be varied between 17.6 W/m{sup 2} and 7,000 W/m{sup 2}. This change in heat transfer rate can be achieved by varying the hydrogen pressure between 1.0 Pa and 1,000 Pa, which can be done with an available hydrogen gettering alloy operating in the range of 50{degrees}C to 250{degrees}C. This approach to battery cooling requires cylindrical insulating jackets, which are best suited for bipolar batteries having round cells approximately 10 to 18 cm in diameter.

Nelson, P.A.; Chilenskas, A.A.; Malecha, R.F.

1992-12-31T23:59:59.000Z

247

Live Work on High Temperature Conductors  

Science Conference Proceedings (OSTI)

Feedback from field personnel working with high-temperature conductors indicates that when a dead-end compression yoke assembly (DCYA) is installed on the conductor according to normal utility procedures, the soft aluminum strands are deformed and "birdcage." This is of course a concern to the field crews and the utility operating the line. This report presents results of research and tests performed on selected conductors operating at high temperature (approximately 250-260°C) with selected live wor...

2011-12-13T23:59:59.000Z

248

Heat-pipe development for high-temperature recuperator application  

SciTech Connect

Heat pipes have been developed for operation in oxidizing atmospheres at temperatures above 1100/sup 0/K. The heat pipes comprise a metallic liner and wick structure with a protective outer shell of an oxidation resistant material. The working fluids used in the heat pipes are alkali metals. A number of configurations have been evaluated, ranging from pipes using a metallic inner liner of a chemically vapor deposited (CVD) refractory metal applied to ceramic tubing, to one utilizing ferrous materials with an outer layer of a developed oxide. A promising intermediate configuration consisting of free-standing refractory tubing covered with a layered structure of fine grain, equi-axed CVD silicon carbide has also been evaluated. The test heat pipe was fabricated using low-carbon, arc-cast molybdenum tubing and a wick composed of 150 mesh molybdenum screen. Hafnium gettering was used with sodium working fluid. Assembly of the pipe was by electron beam welding. Following closure and capping of the fill tube the assembly was operated in a vacuum for several hours prior to the chemical vapor deposition of the exterior ceramic coating. After coating, the pipe was operated in air and in combustion gases for performance evaluation. The use of iron-chromium-aluminum alloys as container materials for operating in high temperature oxidizing and sulfiding gas streams has been investigated. Alloys of this type develop heavy, protective oxide surface layers when exposed to high temperature oxidizing atmospheres, and are commonly used in electrical heating elements because of their exceptional oxidation resistance.

Merrigan, M.; Dunwoody, W.; Lundberg, L.

1981-01-01T23:59:59.000Z

249

High Temperature Corrosion Test Facilities and High Pressure Test  

NLE Websites -- All DOE Office Websites (Extended Search)

High Temperature High Temperature Corrosion Test Facilities and High Pressure Test Facilities for Metal Dusting Test Facilities for Metal Dusting Overview Other Facilities Work with Argonne Contact us For Employees Site Map Help Join us on Facebook Follow us on Twitter NE on Flickr High Temperature Corrosion Test Facilities and High Pressure Test Facilities for Metal Dusting Six corrosion test facilities and two thermogravimetric systems for conducting corrosion tests in complex mixed gas environments, in steam and in the presence of deposits, and five facilities for metal dusting degradation Bookmark and Share The High Temperature Corrosion Test Facilities and High Pressure Test Facilities for Metal Dusting include: High Pressure Test Facility for Metal Dusting Resistance:

250

High temperature crystalline superconductors from crystallized glasses  

DOE Patents (OSTI)

A method of preparing a high temperature superconductor from an amorphous phase. The method involves preparing a starting material of a composition of Bi.sub.2 Sr.sub.2 Ca.sub.3 Cu.sub.4 Ox or Bi.sub.2 Sr.sub.2 Ca.sub.4 Cu.sub.5 Ox, forming an amorphous phase of the composition and heat treating the amorphous phase for particular time and temperature ranges to achieve a single phase high temperature superconductor.

Shi, Donglu (Downers Grove, IL)

1992-01-01T23:59:59.000Z

251

Apparatus and method for high temperature viscosity and temperature measurements  

DOE Patents (OSTI)

A probe for measuring the viscosity and/or temperature of high temperature liquids, such as molten metals, glass and similar materials comprises a rod which is an acoustical waveguide through which a transducer emits an ultrasonic signal through one end of the probe, and which is reflected from (a) a notch or slit or an interface between two materials of the probe and (b) from the other end of the probe which is in contact with the hot liquid or hot melt, and is detected by the same transducer at the signal emission end. To avoid the harmful effects of introducing a thermally conductive heat sink into the melt, the probe is made of relatively thermally insulative (non-heat-conductive) refractory material. The time between signal emission and reflection, and the amplitude of reflections, are compared against calibration curves to obtain temperature and viscosity values.

Balasubramaniam, Krishnan (Mississippi State, MS); Shah, Vimal (Houston, TX); Costley, R. Daniel (Mississippi State, MS); Singh, Jagdish P. (Mississippi State, MS)

2001-01-01T23:59:59.000Z

252

High temperature simulation of petroleum formation  

Science Conference Proceedings (OSTI)

Petroleum formation has been simulated in the laboratory with emphasis on the effects of temperature, mineral catalysis, and starting material structure on the yield and composition of the liquid and gaseous hydrocarbon products. In an attempt to prove the hypothesis that petroleum formation can be simulated using high temperatures, Green River Shale from Colorado, USA, was subjected to pyrolysis for 16 hours at temperatures ranging from 300 to 500/sup 0/C. The sequence of products formed over this temperature range was used as the basis for defining five different zones of maturation reaction: 1) a heterobond cracking zone; 2) a labile carbon bond cracking zone; 3) a free radical synthesis zone; 4) a wet gas formation zone; and 5) an aromatization zone. The role of some typical inorganic components of sedimentary rocks in the origin and maturation of petroleum has been investigated using this high temperature model. The importance of the structure of organic matter in petroelum formation has also been investigated using this high temperature model. Lignin and cellulose are poor sources of liquid hydrocarbons, but cellulose in the presence of carbonate gives a high yield of gaseous hydrocarbons. Protein pyrolysis gives a high oil yield with an alkane distribution similar to petroleum. The lipids produced the highest oil yield of the substances tested but the n-alkanes show an odd carbon length predominance unlike the distribution found in petroleum.

Evans, R.J.

1982-01-01T23:59:59.000Z

253

Phase Separation and Intermetallic Formation in "High-entropy" Alloys  

Science Conference Proceedings (OSTI)

In AlCoCrFeNi HEA, high-temperature neutron diffraction indicates A2-B2 phase ... Shared Research Equipment (ShaRE) and Spallation Neutron Source (SNS) ...

254

Topological Inversion during High Temperature Creep of  

Science Conference Proceedings (OSTI)

fourth generation superalloy [11] (also known as MC-NG), on a modified MC544 alloy with a reduced content of ?' phase, named. MC544-LGP (Low Gamma ...

255

Characterization of high-current, high-temperature superconductor current lead elements  

DOE Green Energy (OSTI)

The refrigeration loads of current leads for superconducting magnets can be significantly reduced by using high-temperature superconductor (HTS) leads. An HTS conductor type that is well suited for this application is a laminated sintered stack of HTS powder-in-tube (PIT) tapes. The superconducting elements are normally characterized by their manufacturer by measuring critical currents at 77 K in self field. Additional characterization, which correlates electrical performance at 77 K and at lower temperatures with applied magnetic fields, provides the current lead designer and conductor element manufacturer with critical information. For HTS conductor elements comprising a laminated and sintered stack of Bi-2223 PIT tapes having an alloyed Ag sheath, this characterization uses variable applied fields and operating temperatures.

Niemann, R.C.; Evans, D.J.; Fisher, B.L. [Argonne National Lab., IL (United States); Brockenborough, W.E.; Roberts, P.R.; Rodenbush, A.J. [American Superconductor Corp., Westborough, MA (United States)

1996-08-01T23:59:59.000Z

256

High Growth Rate of Epitaxial Silicon-Carbon Alloys by High-Order Silane Precursor and Chemical Vapor Deposition  

E-Print Network (OSTI)

rates typically achieved by disilane and silane, respectively, at 575o C. The rate at present is limited precursor HOS than disilane in CVD, even at lower temperatures. Our current growth rates of Si1-yCy alloys

257

Valence Band Structure of Highly Efficient p-type Thermoelectric PbTe-PbS Alloys  

Science Conference Proceedings (OSTI)

New experimental evidence is given relevant to the temperature-dependence of valence band structure of PbTe and PbTe1-xSx alloys (0.04 x 0.12), and its effect on the thermoelectric figure of merit zT. The x = 0.08 sample has zT ~ 1.55 at 773K. The magnetic field dependence of the high-temperature Hall resistivity of heavily p-type (> 1019 cm-3) Na-doped PbTe1-xSx reveals the presence of high-mobility electrons. This put in question prior analyses of the Hall coefficient and the conclusion that PbTe would be an indirect gap semiconductor at temperatures where its zT is optimal. Possible origins for these electrons are discussed: they can be induced by photoconductivity, or by the topology of the Fermi surface when the L and -bands merge. Negative values for the low-temperature thermopower are also observed. Our data show that PbTe continues to be a direct gap semiconductor at temperatures where the zT and S2 of p-type PbTe are optimal e.g. 700-900K. The previously suggested temperature induced rapid rise in energy of the heavy hole LVB relative to the light hole UVB is not supported by the experimental data.

Jaworski, C. M. [Ohio State University; Nielsen, Mechele [Ohio State University; Wang, Hsin [ORNL; Girard, Steven N. [Northwestern University, Evanston; Cai, Wei [ORNL; Porter, Wallace D [ORNL; Kanatzidis, Mercouri G. [Northwestern University, Evanston; Heremans, J. P. [Ohio State University

2013-01-01T23:59:59.000Z

258

High-temperature helium-loop facility  

Science Conference Proceedings (OSTI)

The high-temperature helium loop is a facility for materials testing in ultrapure helium gas at high temperatures. The closed loop system is capable of recirculating high-purity helium or helium with controlled impurities. The gas loop maximum operating conditions are as follows: 300 psi pressure, 500 lb/h flow rate, and 2100/sup 0/F temperature. The two test sections can accept samples up to 3.5 in. diameter and 5 ft long. The gas loop is fully instrumented to continuously monitor all parameters of loop operation as well as helium impurities. The loop is fully automated to operate continuously and requires only a daily servicing by a qualified operator to replenish recorder charts and helium makeup gas. Because of its versatility and high degree of parameter control, the helium loop is applicable to many types of materials research. This report describes the test apparatus, operating parameters, peripheral systems, and instrumentation system.

Tokarz, R.D.

1981-09-01T23:59:59.000Z

259

Low temperature photochemical vapor deposition of alloy and mixed metal oxide films  

DOE Patents (OSTI)

Method and apparatus for formation of an alloy thin film, or a mixed metal oxide thin film, on a substrate at relatively low temperatures. Precursor vapor(s) containing the desired thin film constituents is positioned adjacent to the substrate and irradiated by light having wavelengths in a selected wavelength range, to dissociate the gas(es) and provide atoms or molecules containing only the desired constituents. These gases then deposit at relatively low temperatures as a thin film on the substrate. The precursor vapor(s) is formed by vaporization of one or more precursor materials, where the vaporization temperature(s) is selected to control the ratio of concentration of metals present in the precursor vapor(s) and/or the total precursor vapor pressure.

Liu, David K. (San Pablo, CA)

1992-01-01T23:59:59.000Z

260

High Temperature Oxidation Issues in Fossil Boilers  

SciTech Connect

This report covers the conclusion of a multi-year project that examined the oxidation resistance of Al-rich coatings and a new project examining the effect of higher CO{sub 2} contents on corrosion mechanisms in oxy-fired coal-fueled boilers. The coating work primarily examined diffusion coatings for the steam side of typical ferritic (9-12%Cr) and austenitic (e.g., Type 304L) tube materials in accelerated testing at 650-800 C in wet air. The final phase of this work has attempted to obtain additional coating failures to determine a critical Al content (at coating failure) as a function of exposure temperature. However, no failures have been observed for austenitic substrates including >25 kh at 700 C and >6 kh at 800 C. Preliminary results are presented from the oxy-firing project, where the initial focus is on ferritic alloys. Initial coal-ash experiments were conducted at 600 C to evaluate some of the test parameters and three different levels of CO{sub 2} were investigated. An in-situ creep rig is being constructed to evaluate the effect of environment on creep properties. Initial ex-situ creep experiments are presented as a baseline.

Pint, Bruce A [ORNL; Bestor, Michael A [ORNL; Dryepondt, Sebastien N [ORNL; Zhang, Ying [Tennessee Technological University

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
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261

High strength and density tungsten-uranium alloys  

DOE Patents (OSTI)

Alloys of tungsten and uranium and a method for making the alloys. The amount of tungsten present in the alloys is from about 55 vol % to about 85 vol %. A porous preform is made by sintering consolidated tungsten powder. The preform is impregnated with molten uranium such that (1) uranium fills the pores of the preform to form uranium in a tungsten matrix or (2) uranium dissolves portions of the preform to form a continuous uranium phase containing tungsten particles.

Sheinberg, Haskell (Los Alamos, NM)

1993-01-01T23:59:59.000Z

262

High Temperature Cements | Open Energy Information  

Open Energy Info (EERE)

High Temperature Cements High Temperature Cements Jump to: navigation, search Geothermal ARRA Funded Projects for High Temperature Cements Loading map... {"format":"googlemaps3","type":"ROADMAP","types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"limit":200,"offset":0,"link":"all","sort":[""],"order":[],"headers":"show","mainlabel":"","intro":"","outro":"","searchlabel":"\u2026 further results","default":"","geoservice":"google","zoom":false,"width":"600px","height":"350px","centre":false,"layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","icon":"","visitedicon":"","forceshow":true,"showtitle":true,"hidenamespace":false,"template":false,"title":"","label":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"locations":[{"text":"

263

High Temperature Membrane & Advanced Cathode Catalyst Development  

DOE Green Energy (OSTI)

Current project consisted of three main phases and eighteen milestones. Short description of each phase is given below. Table 1 lists program milestones. Phase 1--High Temperature Membrane and Advanced Catalyst Development. New polymers and advanced cathode catalysts were synthesized. The membranes and the catalysts were characterized and compared against specifications that are based on DOE program requirements. The best-in-class membranes and catalysts were downselected for phase 2. Phase 2--Catalyst Coated Membrane (CCM) Fabrication and Testing. Laboratory scale catalyst coated membranes (CCMs) were fabricated and tested using the down-selected membranes and catalysts. The catalysts and high temperature membrane CCMs were tested and optimized. Phase 3--Multi-cell stack fabrication. Full-size CCMs with the down-selected and optimized high temperature membrane and catalyst were fabricated. The catalyst membrane assemblies were tested in full size cells and multi-cell stack.

Protsailo, Lesia

2006-04-20T23:59:59.000Z

264

Manufacturing Barriers to High Temperature PEM Commercialization  

NLE Websites -- All DOE Office Websites (Extended Search)

9/2011 9/2011 1 BASF Fuel Cell, Inc. Manufacturing Barriers to high temperature PEM commercialization 39 Veronica Ave Somerset , NJ 08873 Tel : (732) 545-5100 9/9/2011 2 Background on BASF Fuel Cell  BASF Fuel Cell was established in 2007, formerly PEMEAS Fuel Cells (including E-TEK)  Product line is high temperature MEAs (Celtec ® P made from PBI-phosphoric acid)  Dedicated a new advanced pilot manufacturing facility in Somerset NJ May 2009. Ribbon-cutting hosted by Dr. Kreimeyer (BASF BoD, right) and attended by various US pubic officials including former NJ Governor Jon Corzine (left) 9/9/2011 3 Multi-layer product of membrane (polybenzimidazole and phosphoric acid), gas diffusion material and catalysts Unique characteristics:  High operating temperature

265

Final Scientific Report - "Novel Steels for High Temperature Carburizing"  

Science Conference Proceedings (OSTI)

This program was undertaken to develop a microalloy-modified grade of standard carburizing steel that can successfully exploit the high temperature carburizing capabilities of current commercial low pressure (i.e. 'vacuum') carburizing systems. Such steels can lower the amount of energy required for commercial carburizing operations by reducing the time required for deep-case carburizing operations. The specific technical objective of the work was to demonstrate a carburizing steel composition capable of maintaining a prior austenite grain size no larger than ASTM grain size number 5 after exposure to simulated carburizing conditions of 1050 C for 8 hr. Such thermal exposure should be adequate for producing carburized case depths up to about 2 mm. Such carburizing steels are expected to be attractive for use across a wide range of industries, including the petroleum, chemical, forest products, automotive, mining and industrial equipment industries. They have potential for reducing energy usage during low pressure carburizing by more than 25%, as well as reducing cycle times and process costs substantially. They also have potential for reducing greenhouse gas emissions from existing low pressure carburizing furnaces by more than 25%. High temperature carburizing can be done in most modern low pressure carburizing systems with no additional capital investment. Accordingly, implementing this technology on carburizing furnaces will provide a return on investment significantly greater than 10%. If disseminated throughout the domestic carburizing community, the technology has potential for saving on the order of 23 to 34 trillion BTU/year in industrial energy usage. Under the program, two compositions of microalloyed, coarsening-resistant low alloy carburizing steels were developed, produced and evaluated. After vacuum annealing at 1050oC for 8 hrs and high pressure gas quenching, both steels exhibited a prior austenite ASTM grain size number of 5.0 or finer. For comparison, a control alloy of similar composition but without the microalloy additions exhibited a duplex prior austenite grain size with grains ranging from ASTM grain size 3 down to ASTM grain size 1 after similar processing and thermal exposure. These results confirm the potential for using microalloy additions of Ti, B, Nb, Al, rare earths and/or N for austenite grain size control in Cr-Mo (i.e. 4000-series) low alloy carburizing steels. They also demonstrate that these microalloy additions will not compromise the processability of the steel; all three materials produced under the program could be hot worked readily using normal steel processing protocols. To fully realize the technical and commercial potential of these steels, there is a need to continue development work using larger-scale heats. These larger-scale heats are needed to provide adequate material for fatigue testing of quenched and tempered alloys, to conduct more complete investigations of potential alloy chemistries and to provide additional material for processing studies. It will also be beneficial to carefully review intellectual property issues associated with this family of steels, since existing Japanese patent literature suggests that significant microstructural and/or process characterization work may be needed on new materials to confirm that these materials fall outside existing patent claims.

McKimpson, Marvin G.; Liu, Tianjun; Maniruzzaman, Md

2012-07-27T23:59:59.000Z

266

PM Alloy 625M for High Strength Corrosion Resistant Applications  

Science Conference Proceedings (OSTI)

Mechanical properties and stress corrosion cracking data of PM 625M are presented ... However, these alloys have shown a tendency to fail by stress corrosion.

267

Initial stages of high temperature metal oxidation  

Science Conference Proceedings (OSTI)

The application of XPS and UPS to the study of the initial stages of high temperature (> 350/sup 0/C) electrochemical oxidation of iron and nickel is discussed. In the high temperature experiments, iron and nickel electrodes were electrochemically oxidized in contact with a solid oxide electrolyte in the uhv system. The great advantages of this technique are that the oxygen activity at the interface may be precisely controlled and the ability to run the reactions in uhv allows the simultaneous observation of the reactions by XPS.

Yang, C.Y.; O'Grady, W.E.

1981-01-01T23:59:59.000Z

268

Effect of small additions of silicon, iron, and aluminum on the room-temperature tensile properties of high-purity uranium  

DOE Green Energy (OSTI)

Eleven binary and ternary alloys of uranium and very low concentrations of iron, silicon, and aluminum were prepared and tested for room-temperature tensile properties after various heat treatments. A yield strength approximately double that of high-purity derby uranium was obtained from a U-400 ppM Si-200 ppM Fe alloy after beta solution treatment and alpha aging. Higher silicon plus iron alloy contents resulted in increased yield strength, but showed an unacceptable loss of ductility.

Ludwig, R.L.

1983-11-14T23:59:59.000Z

269

High-Temperature-High-Volume Lifting | Open Energy Information  

Open Energy Info (EERE)

source source History View New Pages Recent Changes All Special Pages Semantic Search/Querying Get Involved Help Apps Datasets Community Login | Sign Up Search Page Edit History Facebook icon Twitter icon » High-Temperature-High-Volume Lifting Jump to: navigation, search Geothermal ARRA Funded Projects for High-Temperature-High-Volume Lifting Loading map... {"format":"googlemaps3","type":"ROADMAP","types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"limit":200,"offset":0,"link":"all","sort":[""],"order":[],"headers":"show","mainlabel":"","intro":"","outro":"","searchlabel":"\u2026

270

High Temperature Materials Interim Data Qualification Report  

SciTech Connect

ABSTRACT Projects for the very high temperature reactor (VHTR) Technology Development Office provide data in support of Nuclear Regulatory Commission licensing of the VHTR. Fuel and materials to be used in the reactor are tested and characterized to quantify performance in high temperature and high fluence environments. The VHTR program has established the NGNP Data Management and Analysis System (NDMAS) to ensure that VHTR data are qualified for use, stored in a readily accessible electronic form, and analyzed to extract useful results. This document focuses on the first NDMAS objective. It describes the High Temperature Materials characterization data stream, the processing of these data within NDMAS, and reports the interim FY2010 qualification status of the data. Data qualification activities within NDMAS for specific types of data are determined by the data qualification category assigned by the data generator. The High Temperature Materials data are being collected under NQA-1 guidelines, and will be qualified data. For NQA-1 qualified data, the qualification activities include: (1) capture testing, to confirm that the data stored within NDMAS are identical to the raw data supplied, (2) accuracy testing to confirm that the data are an accurate representation of the system or object being measured, and (3) documenting that the data were collected under an NQA-1 or equivalent Quality Assurance program. Currently, data from two test series within the High Temperature Materials data stream have been entered into the NDMAS vault: 1. Tensile Tests for Sm (i.e., Allowable Stress) Confirmatory Testing – 1,403,994 records have been inserted into the NDMAS database. Capture testing is in process. 2. Creep-Fatigue Testing to Support Determination of Creep-Fatigue Interaction Diagram – 918,854 records have been processed and inserted into the NDMAS database. Capture testing is in process.

Nancy Lybeck

2010-08-01T23:59:59.000Z

271

Improved Martensitic Steel for High Temperature Applications  

NLE Websites -- All DOE Office Websites (Extended Search)

Improved Martensitic Steel Improved Martensitic Steel for High Temperature Applications Opportunity Research is active on the patented technology, titled "Heat-Treated 9 Cr-1 Mo Steel for High Temperature Application." This technology is available for licensing and/or further collaborative research from the U.S. Department of Energy's National Energy Technology Laboratory (NETL). Overview The operating efficiency of coal-fired power plants is directly related to combustion system temperature and pressure. Incorporation of ultra- supercritical (USC) steam conditions into new or existing power plants can achieve increased efficiency and reduce coal consumption, while reducing carbon dioxide emissions as well as other pollutants. Traditionally used materials do not possess the optimal characteristics for operation

272

Ceramic heat pipes for high temperature heat removal  

SciTech Connect

Difficulties in finding metal or protected metal components that exhibit both strength and corrosion resistance at high temperature have severely restricted the application of effective heat recovery techniques to process heat furnaces. A potential method of overcoming this restriction is to use heat pipes fabricated from ceramic materials to construct counterflow recuperators. A development program has been initiated to demonstrate the technical and eventually the economical feasibility of ceramic heat pipes and ceramic heat pipe recuperators. The prime candidate for heat pipe construction is SiC. Closed-end tubes of this material have been prepared by chemical vapor deposition (CVD). These tubes were lined internally with tungsten by a subsequent CVD operation, partially filled with sodium, and sealed by brazing a tungsten lined SiC plug into the open-end with a palladium--cobalt alloy. Heat pipes constructed in this manner have been successfully operated in vacuum at temperatures of 1225/sup 0/K and in air at a temperature of 1125/sup 0/K. The heat source used initially for the air testing was an induction heated metallic sleeve in thermal contact with the test unit. Subsequent testing has shown that a silicon carbide heat pipe can be successfully operated with natural gas burners providing the input heat. Methods of fabricating and testing these devices are described.

Keddy, E.S.; Ranken, W.A.

1978-01-01T23:59:59.000Z

273

Safety Issues for High Temperature Gas Reactors  

E-Print Network (OSTI)

Safety Issues for High Temperature Gas Reactors Andrew C. Kadak Professor of the Practice #12;Major regulation) 50mSv/a (Could be exceeded for rear recovery events) 50 mSv/a 20 mSv/a (average 5 y) (5 m performance of safety systems - natural circulation - heat conduction and convection. #12;Issues · Fuel

274

Microscopic Probes of High-Temperature Superconductivity  

Science Conference Proceedings (OSTI)

The granularity of the cuprate superconductors limits the effectiveness of many experimental probes that average over volumes containing many atoms. This report presents theoretical studies on muon spin relaxation and positron annihilation, two microscopic experimental techniques that can probe the properties of both high- and low-temperature superconductors on the atomic scale.

1992-07-01T23:59:59.000Z

275

High Temperature, High Pressure Devices for Zonal Isolation in Geothermal  

Open Energy Info (EERE)

Temperature, High Pressure Devices for Zonal Isolation in Geothermal Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells Geothermal Project Jump to: navigation, search Last modified on July 22, 2011. Project Title High Temperature, High Pressure Devices for Zonal Isolation in Geothermal Wells Project Type / Topic 1 Recovery Act: Enhanced Geothermal Systems Component Research and Development/Analysis Project Type / Topic 2 Zonal Isolation Project Description For Enhanced Geothermal Systems (EGS), high-temperature high-pressure zonal isolation tools capable of withstanding the downhole environment are needed. In these wells the packers must withstand differential pressures of 5,000 psi at more than 300°C, as well as pressures up to 20,000 psi at 200°C to 250°C. Furthermore, when deployed these packers and zonal isolation tools must form a reliable seal that eliminates fluid loss and mitigates short circuiting of flow from injectors to producers. At this time, general purpose open-hole packers do not exist for use in geothermal environments, with the primary technical limitation being the poor stability of existing elastomeric seals at high temperatures.

276

High-Temperature-High-Volume Lifting For Enhanced Geothermal Systems  

Open Energy Info (EERE)

Temperature-High-Volume Lifting For Enhanced Geothermal Systems Temperature-High-Volume Lifting For Enhanced Geothermal Systems Geothermal Project Jump to: navigation, search Last modified on July 22, 2011. Project Title High-Temperature-High-Volume Lifting For Enhanced Geothermal Systems Project Type / Topic 1 Recovery Act: Enhanced Geothermal Systems Component Research and Development/Analysis Project Type / Topic 2 High-Temperature-High-Volume Lifting Project Description The proposed scope of work is divided into three Phases. Overall system requirements will be established in Phase 1, along with an evaluation of existing lifting system capability, identification of technology limitations, and a conceptual design of an overall lifting system. In developing the system components in Phase 2, component-level tests will be conducted using GE facilities. Areas of development will include high-temperature drive system materials, journal and thrust bearings, and corrosion and erosion-resistant lifting pump components. Finally, in Phase 3, the overall lab-scale lifting system will be demonstrated in a flow loop that will be constructed at GE Global Research.

277

Fabrication and Design Aspects of High-Temperature Compact Diffusion Bonded Heat Exchangers  

Science Conference Proceedings (OSTI)

The Very High Temperature Reactor (VHTR) using gas-cooled reactor technology is anticipated to be the reactor type for the Next Generation Nuclear Plant (NGNP). In this reactor concept with an indirect power cycle system, a high-temperature and high integrity Intermediate Heat Exchanger (IHX) with high effectiveness is required to efficiently transfer the core thermal output to a secondary fluid for electricity generation, hydrogen production, and/or industrial process heat applications. At present, there is no proven IHX concept for VHTRs. The current Technology Readiness Level (TRL) status issued by NGNP to all components associated with the IHX for reduced nominal reactor outlet temperatures of 750–800 degrees C is 3 on a 1–10 scale, with 10 indicating omplete technological maturity. Among the various potential IHX concepts available, diffusion bonded heat exchangers (henceforth called printed circuit heat exchangers, or PCHEs) appear promising for NGNP applications. The design and fabrication of this key component of NGNP with Alloy 617, a candidate high-temperature structural material for NGNP applications, are the primary focus of this paper. In the current study, diffusion bonding of Alloy 617 has been demonstrated, although the optimum diffusion bonding process parameters to engineer a quasi interface-free joint are yet to be determined. The PCHE fabrication related processes, i.e., photochemical etching and diffusion bonding are discussed for Alloy 617 plates. In addition, the authors’ experiences with these non-conventional machining and joining techniques are discussed. Two PCHEs are fabricated using Alloy 617 plates and are being experimentally investigated for their thermal-hydraulic performance in a High-Temperature Helium Facility (HTHF). The HTHF is primarily of Alloy 800H construction and is designed to facilitate experiments at temperatures and pressures up to 800 degrees C and 3 MPa, respectively. Furthermore, some preliminary microstructural and mechanical property characterization studies of representative diffusion bonded Alloy 617 specimens are presented. The characterization studies are restricted and less severe from an NGNP perspective but provide sufficient confidence to ensure safe operation of the heat exchangers in the HTHF. The test results are used to determine the design operating conditions for the PCHEs fabricated.

Sai K. Mylavarapu; Richard N. Christensen; Raymond R. Unocic; Richard E. Glosup; Mike W. Patterson

2012-08-01T23:59:59.000Z

278

New Waste Calciner High Temperature Operation  

SciTech Connect

A new Calciner flowsheet has been developed to process the sodium-bearing waste (SBW) in the INTEC Tank Farm. The new flowsheet increases the normal Calciner operating temperature from 500 C to 600 C. At the elevated temperature, sodium in the waste forms stable aluminates, instead of nitrates that melt at calcining temperatures. From March through May 2000, the new high-temperature flowsheet was tested in the New Waste Calcining Facility (NWCF) Calciner. Specific test criteria for various Calciner systems (feed, fuel, quench, off-gas, etc.) were established to evaluate the long-term operability of the high-temperature flowsheet. This report compares in detail the Calciner process data with the test criteria. The Calciner systems met or exceeded all test criteria. The new flowsheet is a visible, long-term method of calcining SBW. Implementation of the flowsheet will significantly increase the calcining rate of SBW and reduce the amount of calcine produced by reducing the amount of chemical additives to the Calciner. This will help meet the future waste processing milestones and regulatory needs such as emptying the Tank Farm.

Swenson, M.C.

2000-09-01T23:59:59.000Z

279

Design and Manufacturing Guidelines for High-Strength Components in LWRs--Alloy X-750  

Science Conference Proceedings (OSTI)

Alloy X-750, commonly used in high-strength internal reactor components, occasionally experiences intergranular stress corrosion cracking (IGSCC). EPRI's new design and manufacturing guidelines, specifying parameters that can influence IGSCC resistance, will assist utilities in reducing the probability of in-service failures of alloy X-750 components.

1991-05-01T23:59:59.000Z

280

Urania vapor composition at very high temperatures  

SciTech Connect

Due to the chemically unstable nature of uranium dioxide its vapor composition at very high temperatures is, presently, not sufficiently studied though more experimental knowledge is needed for risk assessment of nuclear reactors. We used laser vaporization coupled to mass spectrometry of the produced vapor to study urania vapor composition at temperatures in the vicinity of its melting point and higher. The very good agreement between measured melting and freezing temperatures and between partial pressures measured on the temperature increase and decrease indicated that the change in stoichiometry during laser heating was very limited. The evolutions with temperature (in the range 2800-3400 K) of the partial pressures of the main vapor species (UO{sub 2}, UO{sub 3}, and UO{sub 2}{sup +}) were compared with theoretically predicted evolutions for equilibrium noncongruent gas-liquid and gas-solid phase coexistences and showed very good agreement. The measured main relative partial pressure ratios around 3300 K all agree with calculated values for total equilibrium between condensed and vapor phases. It is the first time the three main partial pressure ratios above stoichiometric liquid urania have been measured at the same temperature under conditions close to equilibrium noncongruent gas-liquid phase coexistence.

Pflieger, Rachel [Institute for Transuranium Elements, Joint Research Centre, European Commission, P.O. Box 2340, 76125 Karlsruhe (Germany); Marcoule Institute for Separation Chemistry (ICSM), UMR 5257, CEA-CNRS-UMII-ENSCM, Bagnols sur Ceze Cedex (France); Colle, Jean-Yves [Institute for Transuranium Elements, Joint Research Centre, European Commission, P.O. Box 2340, 76125 Karlsruhe (Germany); Iosilevskiy, Igor [Joint Institute for High Temperature, Russian Academy of Science, 125412 Moscow (Russian Federation); Moscow Institute of Physics and Technology, State University, 141700 Moscow (Russian Federation); Extreme Matter Institute (EMMI), 64291 Darmstadt (Germany); Sheindlin, Michael [Institute for Transuranium Elements, Joint Research Centre, European Commission, P.O. Box 2340, 76125 Karlsruhe (Germany); Joint Institute for High Temperature, Russian Academy of Science, 125412 Moscow (Russian Federation)

2011-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

High-temperature directional drilling turbodrill  

DOE Green Energy (OSTI)

The development of a high-temperature turbodrill for directional drilling of geothermal wells in hard formations is summarized. The turbodrill may be used for straight-hole drilling but was especially designed for directional drilling. The turbodrill was tested on a dynamometer stand, evaluated in laboratory drilling into ambient temperature granite blocks, and used in the field to directionally drill a 12-1/4-in.-diam geothermal well in hot 200/sup 0/C (400/sup 0/F) granite at depths to 10,5000 ft.

Neudecker, J.W.; Rowley, J.C.

1982-02-01T23:59:59.000Z

282

NUCLEAR RESONANT SCATTERING AT HIGH PRESSURE AND HIGH TEMPERATURE  

E-Print Network (OSTI)

NUCLEAR RESONANT SCATTERING AT HIGH PRESSURE AND HIGH TEMPERATURE JIYONG ZHAOa,Ã? , WOLFGANG, The University of Chicago, Chicago, IL 60637, USA We introduce the combination of nuclear resonant inelastic X the thermal radiation spectra fitted to the Planck radiation function up to 1700 K. Nuclear resonant

Shen, Guoyin

283

Compliant high temperature seals for dissimilar materials  

DOE Patents (OSTI)

A high temperature, gas-tight seal is formed by utilizing one or more compliant metallic toroidal ring sealing elements, where the applied pressure serves to activate the seal, thus improving the quality of the seal. The compliant nature of the sealing element compensates for differences in thermal expansion between the materials to be sealed, and is particularly useful in sealing a metallic member and a ceramic tube art elevated temperatures. The performance of the seal may be improved by coating the sealing element with a soft or flowable coating such as silver or gold and/or by backing the sealing element with a bed of fine powder. The material of the sealing element is chosen such that the element responds to stress elastically, even at elevated temperatures, permitting the seal to operate through multiple thermal cycles.

Rynders, Steven Walton (Fogelsville, PA); Minford, Eric (Laurys Station, PA); Tressler, Richard Ernest (Boalsburg, PA); Taylor, Dale M. (Salt Lake City, UT)

2001-01-01T23:59:59.000Z

284

Temperature Dependent Electrical Transport Properties of Ni-Cr and Co-Cr Binary Alloys  

Science Conference Proceedings (OSTI)

The temperature dependent electrical transport properties viz. electrical resistivity and thermal conductivity of Ni{sub 10}Cr{sub 90} and Co{sub 20}Cr{sub 80} alloys are computed at various temperatures. The electrical resistivity has been calculated according to Faber-Ziman model combined with Ashcroft-Langreth partial structure factors. In the present work, to include the ion-electron interaction, we have used a well tested local model potential. For exchange-correlation effects, five different forms of local field correction functions due to Hartree (H), Taylor (T), Ichimaru and Utsumi (IU), Farid et al (F) and Sarkar et al (S) are used. The present results due to S function are in good agreement with the experimental data as compared to results obtained using other four functions. The S functions satisfy compressibility sum rule in long wave length limit more accurately as compared to T, IU and F functions, which may be responsible for better agreement of results, obtained using S function. Also, present result confirms the validity of present approach in determining the transport properties of alloys like Ni-Cr and Co-Cr.

Thakore, B. Y.; Khambholja, S. G.; Bhatt, N. K.; Jani, A. R. [Department of Physics, S P University, Vallabh Vidhyanagar, 388 120, Gujarat (India); Suthar, P. H. [Department of Physics, C U Shah Science College, Ahmedabad, 380 014, Gujarat (India); Gajjar, P. N. [Department of Physics, University Schools of Sciences, Gujarat University, Ahmedabad, 380 009, Gujarat (India)

2011-12-12T23:59:59.000Z

285

Microstructural evolution in nickel alloy C-276 after Ar-ion irradiation at elevated temperature  

SciTech Connect

In present work, the irradiation damage in nickel-base alloy C-276 irradiated with Ar-ions was studied. Specimens of C-276 alloy were subjected to an irradiation of Ar-ions (with 120 keV) to dose levels of 6 and 10 dpa at 300 and 550 Degree-Sign C, respectively. The size distributions and densities of dislocation loops caused by irradiation were investigated with transmission electron microscopy. Irradiation hardening due to the formation of the loops was calculated using the dispersed barrier-hardening model, showing that irradiation hardening was greatest at 300 Degree-Sign C/6 dpa. The microstructure evolution induced by Ar-ion irradiation (0-10 dpa) in nickel-base alloy C-276 has been studied using a multi-scale modeling code Radieff constructed based on rate theory, and the size of dislocation loops simulated by Radieff was in good agreement with the experiment. - Highlights: Black-Right-Pointing-Pointer High density of dislocation loops appeared after Ar ions irradiation. Black-Right-Pointing-Pointer Irradiation hardening due to the formation of loops was calculated by the DBH model. Black-Right-Pointing-Pointer Size of loops simulated by Radieff was in good agreement with the experiment.

Jin, Shuoxue [Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education and School of Physics and Technology, Wuhan University, Wuhan 430072 (China)] [Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education and School of Physics and Technology, Wuhan University, Wuhan 430072 (China); He, Xinfu [China Institute of Atomic Energy, Beijing 102413 (China)] [China Institute of Atomic Energy, Beijing 102413 (China); Li, Tiecheng [Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education and School of Physics and Technology, Wuhan University, Wuhan 430072 (China)] [Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education and School of Physics and Technology, Wuhan University, Wuhan 430072 (China); Ma, Shuli; Tang, Rui [Nuclear Power Institute of China, Chengdu 610041 (China)] [Nuclear Power Institute of China, Chengdu 610041 (China); Guo, Liping, E-mail: guolp@whu.edu.cn [Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education and School of Physics and Technology, Wuhan University, Wuhan 430072 (China)] [Key Laboratory of Artificial Micro- and Nano-structures of Ministry of Education and School of Physics and Technology, Wuhan University, Wuhan 430072 (China)

2012-10-15T23:59:59.000Z

286

Precision control of high temperature furnaces  

DOE Patents (OSTI)

It is an object of the present invention to provide precision control of high temperature furnaces. It is another object of the present invention to combine the power of two power supplies of greatly differing output capacities in a single furnace. This invention combines two power supplies to control a furnace. A main power supply heats the furnace in the traditional manner, while the power from the auxiliary supply is introduced as a current flow through charged particles existing due to ionized gas or thermionic emission. The main power supply provides the bulk heating power and the auxiliary supply provides a precise and fast power source such that the precision of the total power delivered to the furnace is improved. Further, this invention comprises a means for high speed measurement of temperature of the process by the method of measuring the amount of current flow in a deliberately induced charged particle current.

Pollock, G.G.

1994-12-31T23:59:59.000Z

287

A High Strength, Oxidation Resistant DS Turbine Airfoil Alloy  

Science Conference Proceedings (OSTI)

Particular thanks go to Dr. Robert E. Allen of EMTL who sustained funding for the development of Rene'142 and led the scale-up and introduction of the alloy ...

288

Geochemistry of Aluminum in High Temperature Brines  

DOE Green Energy (OSTI)

geothermal industry to predict the chemistry ofthe reservoirs; these calculations will be tested for reliability against our laboratory results and field observations. Moreover, based on the success of the experimental methods developed in this program, we intend to use our unique high temperature pH easurement capabilities to make kinetic and equilibrium studies of pH-dependent aluminosilicate transformation reactions and other pH-dependent heterogeneous reactions.

Benezeth, P.; Palmer, D.A.; Wesolowski, D.J.

1999-05-18T23:59:59.000Z

289

Establishment of Harrop, High-Temperature Viscometer  

Science Conference Proceedings (OSTI)

This report explains how the Harrop, High-Temperature Viscometer was installed, calibrated, and operated. This report includes assembly and alignment of the furnace, viscometer, and spindle, and explains the operation of the Brookfield Viscometer, the Harrop furnace, and the UDC furnace controller. Calibration data and the development of the spindle constant from NIST standard reference glasses is presented. A simple operational procedure is included.

Schumacher, R.F.

1999-11-05T23:59:59.000Z

290

Effect of hydrogen-sulfide on the hydrogen permeance of palladium–copper alloys at elevated temperatures  

E-Print Network (OSTI)

The hydrogen permeance of several 0.1 mm thick Pd–Cu alloy foils (80 wt. % Pd–20 wt. % Cu, 60 wt. % Pd–40 wt. % Cu and 53 wt.% Pd–47 wt. % Cu) was evaluated using transient flux measurements at temperatures ranging from 603 to 1123 K and pressures up to 620 kPa both in the presence and absence of 1000 ppm H2S. Sulfur resistance, as evidenced by no significant change in permeance, was correlated with the temperatures associated with the face-centered-cubic crystalline structure for the alloys in this study. The permeance of the body-centered cubic phase, however, was up to two orders of magnitude lower when exposed to H2S. A smooth transition from sulfur poisoning to sulfur resistance with increasing temperature was correlated with the alloy transition from a body-centered-cubic structure to a face-centered-cubic structure. © 2004 Elsevier B.V. All rights reserved.

B. D. Morreale B; M. V. Ciocco B; B. H. Howard A

2004-01-01T23:59:59.000Z

291

Vehicle Technologies Office: ORNL's High Temperature Materials Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

ORNL's High Temperature ORNL's High Temperature Materials Laboratory Assists NASCAR Teams to someone by E-mail Share Vehicle Technologies Office: ORNL's High Temperature Materials Laboratory Assists NASCAR Teams on Facebook Tweet about Vehicle Technologies Office: ORNL's High Temperature Materials Laboratory Assists NASCAR Teams on Twitter Bookmark Vehicle Technologies Office: ORNL's High Temperature Materials Laboratory Assists NASCAR Teams on Google Bookmark Vehicle Technologies Office: ORNL's High Temperature Materials Laboratory Assists NASCAR Teams on Delicious Rank Vehicle Technologies Office: ORNL's High Temperature Materials Laboratory Assists NASCAR Teams on Digg Find More places to share Vehicle Technologies Office: ORNL's High Temperature Materials Laboratory Assists NASCAR Teams on AddThis.com...

292

Hydrogen at high pressure and temperatures  

DOE Green Energy (OSTI)

Hydrogen at high pressures and temperatures is challenging scientifically and has many real and potential applications. Minimum metallic conductivity of fluid hydrogen is observed at 140 GPa and 2600 K, based on electrical conductivity measurements to 180 GPa (1.8 Mbar), tenfold compression, and 3000 K obtained dynamically with a two-stage light-gas gun. Conditions up to 300 GPa, sixfold compression, and 30,000 K have been achieved in laser-driven Hugoniot experiments. Implications of these results for the interior of Jupiter, inertial confinement fusion, and possible uses of metastable solid hydrogen, if the metallic fluid could be quenched from high pressure, are discussed.

Nellis, W J

1999-09-30T23:59:59.000Z

293

Polyelectrolyte Materials for High Temperature Fuel Cells  

NLE Websites -- All DOE Office Websites (Extended Search)

Polyelectrolyte Materials for High Polyelectrolyte Materials for High 3M (3M) Temperature Fuel Cells John B. Kerr Lawrence Berkeley National Laboratory (LBNL) Collaborators: Los Alamos National Laboratory (LANL). February 13, 2007 This presentation does not contain any proprietary or confidential information Team Members: Nitash Blasara, Rachel Segalman, Adam Weber (LBNL). Bryan Pivovar, James Boncella (LANL) Steve Hamrock Objectives * Investigate the use of solid polyelectrolyte proton conductors that do not require the presence of water. * Prepare solid electrolytes where only the proton moves. - Measure conductivity, mechanical/thermal properties of Nafion® and other polyelectrolytes doped with imidazoles. Compare with water doped materials. - Covalently attach imidazoles to side chains of ionomers with

294

Novel High-Temperature Austenitic Alloys for Energy Conversion ...  

Science Conference Proceedings (OSTI)

has been shown to have a strong effect on precipitation within the matrix.This work was supported by ACS PRF Grant #49157-ND10. Proceedings Inclusion?

295

The High Temperature Stability of IN718 Derivative Alloys  

Science Conference Proceedings (OSTI)

standard specimens due to the limited availability of material. ... characterized using a transmission electron microscope (TEM) operated at 120 KeV and.

296

Advantages of High HIP Temperature for Titanium-based Alloys ...  

Science Conference Proceedings (OSTI)

Numerical Modeling of Centrifugally Cast HSS Rolls · Numerical Simulation of Electro-magnetic Turbulent Inhibitor Technology in a Tundish · Optimizing the ...

297

Titanium Alloys for High Temperature Applications - A Symposium ...  

Science Conference Proceedings (OSTI)

the Structural Materials Division (SMD) of ... A Publication of TMS (The Minerals, Metals & Materials Society) ... directly to the Copyright Clearance Center, Inc.,.

298

Corrosion of High Temperature Alloys in Molten Salts  

Science Conference Proceedings (OSTI)

Fluoride and chloride salts are among the candidates for this application. However, materials corrosion is an issue in these molten salts, particularly in molten ...

299

High Temperature Deformation Behavior of Cast Alloy 718  

Science Conference Proceedings (OSTI)

Currently with University of Kentucky, Lexington, KY. Superalloys 718,625,706 and Various Derivatives. Edited by E.A. Loria. The Minerals, Metals &Materials ...

300

Mechanistic-Based Lifetime Predictions for High Temperature Alloys ...  

Science Conference Proceedings (OSTI)

... is a continuing goal for power generation whether it is fossil energy, solar power or transportation because it lowers costs, fuel consumption and emissions.

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

The Effect of Temperature on the Breakdown and Repassivation Potentials of Welded Alloy 22 In 5 M CACI2  

Science Conference Proceedings (OSTI)

The study of the electrochemical behavior of wrought and welded Alloy 22 was carried out in 5 M CaCl{sub 2} as a function of temperatures between 45 and 120 C with Multiple Crevice Assembly (MCA) specimens. The susceptibility to corrosion was found to increase with increase in electrolyte temperature in both the wrought (in the mill annealed condition) and the welded forms of the alloy. The weld metal was found to be less susceptible to localized corrosion under the conditions tested.

G.O. IIevbare

2006-07-05T23:59:59.000Z

302

High Operating Temperature Liquid Metal Heat Transfer Fluids  

NLE Websites -- All DOE Office Websites (Extended Search)

Liquid Metal Liquid Metal Heat Transfer Fluids UCLA, UCB, Yale DE-EE0005941 | April 15, 2013 | Ju 1.1 Thermochemistry modeling * Continue CALPHAD based calculations to search for optimal ternary alloy compositions. * Initiate development of liquid density models. 1.2 Combinatorial synthesis and characterization * Pipe-Liquid interaction of compositional library * More alloys, alloy additions and effect on liquidus temperatures * Iteratively optimize the compositions. 1.3 Corrosion characterization and mitigation * Tune static corrosion testing systems for testing over an extended period of time. * Perform analysis of the micro mechanical testing on the oxide layers. 1.4 Heat transfer characterization and modeling * Complete the construction of the flow loop and perform experiments to measure

303

NOVEL REFRACTORY MATERIALS FOR HIGH ALKALI, HIGH TEMPERATURE ENVIRONMENTS  

Science Conference Proceedings (OSTI)

Refractory materials can be limited in their application by many factors including chemical reactions between the service environment and the refractory material, mechanical degradation of the refractory material by the service environment, temperature limitations on the use of a particular refractory material, and the inability to install or repair the refractory material in a cost effective manner or while the vessel was in service. The objective of this project was to address the need for new innovative refractory compositions by developing a family of novel MgO-Al 2O3 spinel or other similar magnesia/alumina containing unshaped refractory composition (castables, gunnables, shotcretes, etc) utilizing new aggregate materials, bond systems, protective coatings, and phase formation techniques (in-situ phase formation, altered conversion temperatures, accelerated reactions, etc). This family of refractory compositions would then be tailored for use in high-temperature, high-alkaline industrial environments like those found in the aluminum, chemical, forest products, glass, and steel industries.

Hemrick, James Gordon [ORNL

2011-09-01T23:59:59.000Z

304

High Permeability Ternary Palladium Alloy Membranes with Improved Sulfur and Halide Tolerance  

NLE Websites -- All DOE Office Websites (Extended Search)

9 9 HigH Permeability ternary Palladium alloy membranes witH imProved sulfur and Halide tolerance Description A critical step in the transition to the hydrogen economy is the separation of hydrogen from coal gasification gases (syngas) or methane. This is typically accomplished through membrane separation. Past research has shown that palladium (Pd) alloys possess great potential as robust and economical membranes. However, the search for the optimal binary or ternary alloys is an involved and costly process due to the immense number of alloy variations that could be prepared and tested. Recent modeling work at Georgia Institute of Technology using density functional theory (DFT) identified several promising ternary alloy compositions with improved

305

High mobility two-dimensional electron gases in nitride heterostructures with high Al composition AlGaN alloy barriers  

Science Conference Proceedings (OSTI)

We report high-electron mobility nitride heterostructures with >70% Al composition AlGaN alloy barriers grown by molecular beam epitaxy. Direct growth of such AlGaN layers on GaN resulted in hexagonal trenches and a low mobility polarization-induced charge. By applying growth interruption at the heterojunction, the surface morphology improved dramatically and the room temperature two-dimensional electron gas (2DEG) mobility increased by an order of magnitude, exceeding 1300 cm{sup 2}/V s. The 2DEG density was tunable at 0.4-3.7x10{sup 13}/cm{sup 2} by varying the total barrier thickness (t). Surface barrier heights of the heterostructures were extracted and exhibited dependence on t.

Li Guowang; Cao Yu; Xing Huili Grace; Jena, Debdeep [Department of Electrical Engineering, University of Notre Dame, Indiana 46556 (United States)

2010-11-29T23:59:59.000Z

306

Stress corrosion cracking and hydrogen embrittlement of thick section high strength low alloy steel  

E-Print Network (OSTI)

An experimental study was conducted to evaluate the corrosion performance of weldments of a high strength low alloy(HSLA) steel in a simulated seawater environment. This steel, designated HSLA80, was developed by the United ...

Needham, William Donald

1986-01-01T23:59:59.000Z

307

CoNiFe Alloy Powder Synthesis by High Energy Milling  

Science Conference Proceedings (OSTI)

CoNiFe alloy powder was synthesized by high energy milling of mixtures of Co, Ni and Fe powder as a bulk processing method for producing powder. A milling ...

308

Ultrasonic properties of low solvus high refractory (LSHR) super alloy disk material  

Science Conference Proceedings (OSTI)

Measurements are made for ultrasonic linear and nonlinear properties of the powder metallurgy disk alloy LSHR material designed with a relatively low {gamma}' precipitate solvus temperature and high refractory element content. This allows versatile heat treatment processing which results in high tensile, creep and fatigue properties depending on the grain size controlled through proper selection of solution heat treatment temperatures relative to the {gamma}' precipitate solvus temperature. Sound velocity and attenuation for both longitudinal and shear modes at various frequencies from 5 to 20 MHz help to identify and quantify the size of transition zone nondestructively between the small grain ({approx}10 {mu}m) and the large grain ({approx}100 {mu}m) zones. The shear wave velocity measurements taken by aligning the transducer polarization direction parallel and perpendicular to the grain transition direction reveal some results that we do not fully understand at this time and will be the basis of future research. Similarly, measurements of the acoustic nonlinearity parameter show some variations that may originate from uncertain sources.

Na, Jeong K. [University of Dayton Research Institute, 300 College Park, Dayton, OH 45469 (United States); Blodgett, Mark [Air Force Research Laboratory (AFRL/RXLP) Wright-Patterson AFB, OH 45433 (United States)

2011-06-23T23:59:59.000Z

309

High Temperature Battery for Drilling Applications  

SciTech Connect

In this project rechargeable cells based on the high temperature electrochemical system Na/beta''-alumina/S(IV) in AlCl3/NaCl were developed for application as an autonomous power source in oil/gas deep drilling wells. The cells operate in the temperature range from 150 C to 250 C. A prototype DD size cell was designed and built based on the results of finite element analysis and vibration testing. The cell consisted of stainless steel case serving as anode compartment with cathode compartment installed in it and a seal closing the cell. Critical element in cell design and fabrication was hermetically sealing the cell. The seal had to be leak tight, thermally and vibration stable and compatible with electrode materials. Cathode compartment was built of beta''-alumina tube which served as an electrolyte, separator and cathode compartment.

Josip Caja

2009-12-31T23:59:59.000Z

310

High-temperature superconducting current leads  

Science Conference Proceedings (OSTI)

Use of high-temperature superconductors (HTSs) for current leads to deliver power to devices at liquid helium temperature can reduce refrigeration requirements to values significantly below those achievable with conventional leads. HTS leads are now near commercial realization. Argonne National Laboratory (ANL) has developed a sinter-forge process to fabricate current leads from bismuth-based superconductors. The current-carrying capacity of these leads is five times better than that of HTS leads made by a conventional fabrication process. ANL along with Superconductivity, Inc., has developed a 1500 ampere current lead for an existing superconducting magnetic energy storage (SMES) device. With Babcock & Wilcox Company, Argonne is creating 16-kiloampere leads for use in a 0.5 MWh SMES. In a third project Argonne performed characterization testing of a existing, proprietary conduction-cooled lead being developed by Zer Res Corp.

Niemann, R.C.

1995-03-01T23:59:59.000Z

311

High-temperature, high-pressure bonding of nested tubular metallic components  

DOE Patents (OSTI)

This invention is a tool for effecting high-temperature, high-compression bonding between the confronting faces of nested, tubular, metallic components. In a typical application, the tool is used to produce tubular target assemblies for irradiation in nuclear reactors or particle accelerators, the target assembly comprising a uranium foil and an aluminum-alloy substrate. The tool preferably is composed throughout of graphite. It comprises a tubular restraining member in which a mechanically expandable tubular core is mounted to form an annulus with the member. The components to be bonded are mounted in nested relation in the annulus. The expandable core is formed of individually movable, axially elongated segments whose outer faces cooperatively define a cylindrical pressing surface and whose inner faces cooperatively define two opposed, inwardly tapered, axial bores. Tapered rams extend respectively into the bores. The loaded tool is mounted in a conventional hot-press provided with evacuation means, heaters for maintaining its interior at bonding temperature, and hydraulic cylinders for maintaining a selected inwardly directed pressure on the tapered rams. With the hot-press evacuated and the loaded tool at the desired temperature, the cylinders are actuated to apply the selected pressure to the rams. The rams in turn expand the segmented core to maintain the nested components in compression against the restraining member. These conditions are maintained until the confronting faces of the nested components are joined in a continuous, uniform bond characterized by high thermal conductivity.

Quinby, Thomas C. (Kingston, TN)

1980-01-01T23:59:59.000Z

312

High power densities from high-temperature material interactions  

DOE Green Energy (OSTI)

Thermionic energy conversion (TEC) and metallic-fluid heat pipes (MFHPs) offer important and unique advantages in terrestrial and space energy processing. And they are well suited to serve together synergistically. TEC and MFHPs operate through working-fluid vaporization, condensation cycles that accept great thermal power densities at high temperatures. TEC and MFHPs have apparently simple, isolated performance mechanisms that are somewhat similar. And they also have obviously difficult, complected material problems that again are somewhat similar. Intensive investigation reveals that aspects of their operating cycles and material problems tend to merge: high-temperature material effects determine the level and lifetime of performance. Simplified equations verify the preceding statement for TEC and MFHPs. Material properties and interactions exert primary influences on operational effectiveness. And thermophysicochemical stabilities dictate operating temperatures which regulate the thermoemissive currents of TEC and the vaporization flow rates of MFHPs. Major high-temperature material problems of TEC and MFHPs have been solved. These solutions lead to productive, cost-effective applications of current TEC and MFHPs - and point to significant improvements with anticipated technological gains.

Morris, J.F.

1981-01-01T23:59:59.000Z

313

Live Working Tools for High Temperature Conductors  

Science Conference Proceedings (OSTI)

In long-duration (several days) tests, strain link sticks used for live work were removed from service and exposed to conductors operating at high temperature of about 250-260C. Only strain link sticks were tested to date. Results obtained do not indicate damage or deterioration of the tested sticks. The research is a joint effort between project 35.010 Live Working Research for Overhead Transmission Equipment, Techniques, Procedures and Protective Grounding and project 35.015 Advanced Conductors to inve...

2010-12-17T23:59:59.000Z

314

Advanced nickel base alloys for high strength, corrosion applications  

SciTech Connect

Improved nickel-base alloys of enhanced strength and corrosion resistance, produced by atomization of an alloy melt under an inert gas atmosphere and of composition 0-20Fe, 10-30Cr, 2-12Mo, 6 max. Nb, 0.05-3 V, 0.08 max. Mn, 0.5 max. Si, less than 0.01 each of Al and Ti, less than 0.05 each of P and S, 0.01-0.08C, less than 0.2N, 0.1 max. 0, bal. Ni.

Flinn, John E. (Idaho Falls, ID)

1998-01-01T23:59:59.000Z

315

SunShot Initiative: High Operating Temperature Liquid Metal Heat Transfer  

NLE Websites -- All DOE Office Websites (Extended Search)

High Operating Temperature Liquid Metal Heat Transfer Fluids High Operating Temperature Liquid Metal Heat Transfer Fluids UCLA logo University of California Berkeley logo Yale logo Four graphics in a grid that represent the sputtering technique being used in this project. Combinatorial screening and high throughput characterization of materials will be used to identify, develop, and demonstrate metal alloys that meet the MURI HOT Fluids targets suitable for CSP applications. The University of California, Los Angeles, the University of California, Berkeley, and Yale University The University of California, Los Angeles (UCLA), along with partners at the University of California, Berkeley, and Yale University, under the 2012 Multidisciplinary University Research Initiative (MURI): High Operating Temperature (HOT) Fluids funding opportunity, is investigating the use of metal alloys as a heat transfer fluid (HTF) in concentrating solar power (CSP) systems operating at temperatures in excess of 800°C. By allowing higher temperature operation, CSP systems can achieve greater efficiencies and thereby reduce the overall cost of electricity production.

316

Superconductivity Program Overview High-Temperature Superconductivity  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

SuperconducTiviTy program haS Three FocuS areaS: SuperconducTiviTy program haS Three FocuS areaS: SuperconducTiviTy applicaTionS Developing HTS-based electric power equipment such as transmission and distribution cables and fault current limiters Second-generaTion Wire developmenT Developing high-performance, low-cost, second- generation HTS wire at long lengths STraTegic reSearch Supporting fundamental research activities to better understand relationships between the microstructure of HTS materials and their ability to carry large electric currents over long lengths Superconductivity Program Overview High-Temperature Superconductivity for Electric Systems Office of Electricity Delivery and Energy Reliability www.oe.energy.gov Office of Electricity Delivery and Energy Reliability, OE-1 U.S. Department of Energy - 1000 Independence Avenue, SW - Washington, DC 20585

317

Amorphous metal alloy and composite  

DOE Patents (OSTI)

Amorphous metal alloys of the iron-chromium and nickel-chromium type have excellent corrosion resistance and high temperature stability and are suitable for use as a protective coating on less corrosion resistant substrates. The alloys are stabilized in the amorphous state by one or more elements of titanium, zirconium, hafnium, niobium, tantalum, molybdenum, and tungsten. The alloy is preferably prepared by sputter deposition.

Wang, Rong (Richland, WA); Merz, Martin D. (Richland, WA)

1985-01-01T23:59:59.000Z

318

Methanol electro-oxidation on unsupported Pt-Ru alloys at different temperatures  

Science Conference Proceedings (OSTI)

A wide compositional range of unsupported platinum-ruthenium alloy catalysts were prepared by thermal decomposition of the chlorides and chloroacids. The electrocatalysts were characterized by cyclic voltammetry, X-ray diffraction, and energy-dispersive X-ray spectroscopy. The BET surface area of the electrocatalysts increases with increasing Ru content up to {approximately}70 atomic percent (a/o) and then reaches a plateau value. Electrodes fabricated from the electrocatalysts were also evaluated as anodes for methanol electro-oxidation in sulfuric acid over a range of temperatures. Unlike the situation for pure Pt, Ru is inactive for methanol electro-oxidation at 25 C but becomes active at higher temperatures. The peak current observed during an anodic potential scan gradually shifts to more cathodic potentials with increasing temperature. When a comparison is made on the basis of electrode geometric surface area, a {approximately}50 a/o ruthenium electrocatalyst provides the highest activity for methanol electro-oxidation at both 25 and 60C. The methanol electro-oxidation rate is 0.5 orders with respect to methanol concentration (between 0.1 and 2 M) for the Pt-Ru ({approximately}50:50) electrode.

Chu, D.; Gilman, S. [Army Research Lab., Fort Monmouth, NJ (United States). Physical Sciences Directorate

1996-05-01T23:59:59.000Z

319

TUNGSTEN BASE ALLOYS  

DOE Patents (OSTI)

A high-density quaternary tungsten-base alloy having high mechanical strength and good machinability composed of about 2 wt.% Ni, 3 wt.% Cu, 5 wt.% Pb, and 90wt.% W is described. This alloy can be formed by the powder metallurgy technique of hot pressing in a graphite die without causing a reaction between charge and the die and without formation of a carbide case on the final compact, thereby enabling re-use of the graphite die. The alloy is formable at hot- pressing temperatures of from about 1200 to about 1350 deg C. In addition, there is little component shrinkage, thereby eliminating the necessity of subsequent extensive surface machining.

Schell, D.H.; Sheinberg, H.

1959-12-15T23:59:59.000Z

320

High pressure/high temperature thermogravimetric apparatus. Final report  

DOE Green Energy (OSTI)

The purpose of this instrumentation grant was to acquire a state-of-the-art, high pressure, high temperature thermogravimetric apparatus (HP/HT TGA) system for the study of the interactions between gases and carbonaceous solids for the purpose of solving problems related to coal utilization and applications of carbon materials. The instrument that we identified for this purpose was manufactured by DMT (Deutsche Montan Technologies)--Institute of Cokemaking and Coal Chemistry of Essen, Germany. Particular features of note include: Two reactors: a standard TGA reactor, capable of 1100 C at 100 bar; and a high temperature (HT) reactor, capable of operation at 1600 C and 100 bar; A steam generator capable of generating steam to 100 bar; Flow controllers and gas mixing system for up to three reaction gases, plus a separate circuit for steam, and another for purge gas; and An automated software system for data acquisition and control. The HP/TP DMT-TGA apparatus was purchased in 1996 and installed and commissioned during the summer of 1996. The apparatus was located in Room 128 of the Prince Engineering Building at Brown University. A hydrogen alarm and vent system were added for safety considerations. The system has been interfaced to an Ametek quadruple mass spectrometer (MA 100), pumped by a Varian V250 turbomolecular pump, as provided for in the original proposed. With this capability, a number of gas phase species of interest can be monitored in a near-simultaneous fashion. The MS can be used in a few different modes. During high pressure, steady-state gasification experiments, it is used to sample, measure, and monitor the reactant/product gases. It can also be used to monitor gas phase species during nonisothermal temperature programmed reaction (TPR) or temperature programmed desorption (TPD) experiments.

Calo, J.M.; Suuberg, E.M.

1999-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
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321

Constitution Diagram for Dissimilar Metal Welds in Alloy Steels and ...  

Science Conference Proceedings (OSTI)

Explosive Bonding of 316L to C18150 CuCrZr Alloy for ITER Applications · Failure Mechanisms of Dissimilar Metal Welds During High Temperature Service.

322

High Temperature Borehole Televiewer software user manual  

DOE Green Energy (OSTI)

The High Temperature Borehole Televiewer is a downhole instrument which provides acoustic pictures of the borehole walls that are suitable for casing inspection and fracture detection in geothermal wells. The Geothermal Drilling Organization has funded the development of a commercial tool survivable to temperatures of 275{degree}C and pressures of 5000 psi. A real-time display on an IBM-compatible PC was included as part of the development effort. This report contains a User Manual which describes the operation of this software. The software is designed in a menu format allowing the user to change many of the parameters which control both the acquisition and the display of the Televiewer data. An internal data acquisition card digitizes the waveform from the tool at a rate of 100,000 samples per second. The data from the tool, both the range or arrival time and the amplitude of the return signal, are displayed in color on the CRT screen of the computer during the logging operation. This data may be stored on the hard disk for later display and analysis. The software incorporates many features which aid in the setup of the tool for proper operation. These features include displaying and storing the captured waveform data to check the voltage and time windows selected by the user. 17 refs., 28 figs., 15 tabs.

Duda, L.E.

1989-11-01T23:59:59.000Z

323

High Temperature Materials Laboratory (HTML) - PSD Directorate  

NLE Websites -- All DOE Office Websites (Extended Search)

filler A National Resource for Collaborative Materials Research The High Temperature Materials Laboratory (HTML) User Program is on hiatus due to federal budget reductions. However, research projects at the HTML still may be conducted on a cost-recovery basis through the Work for Others (WFO) Program or under a Cooperative R&D Agreement (CRADA). Dr. Edgar Lara-Curzio, HTML Director Tel: 865.574.1749 Fax: 865.574.4913 laracurzioe@ornl.gov Christine Goudy, Administrative Specialist Tel: 865.574.8295 Fax: 865.574.4913 goudyc@ornl.gov Oak Ridge National Laboratory [MST Home] [ORNL Home] [Site Index] [Search][Disclaimer] [Webmaster] Oak Ridge National Laboratory is a national multi-program research and development facility managed by UT-Battelle, LLC for the U.S. Department of Energy

324

Multilayer ultra-high-temperature ceramic coatings  

SciTech Connect

A coated carbon-carbon composite material with multiple ceramic layers to provide oxidation protection from ultra-high-temperatures, where if the carbon-carbon composite material is uninhibited with B.sub.4C particles, then the first layer on the composite material is selected from ZrB.sub.2 and HfB.sub.2, onto which is coated a layer of SiC coated and if the carbon-carbon composite material is inhibited with B.sub.4C particles, then protection can be achieved with a layer of SiC and a layer of either ZrB.sub.2 and HfB.sub.2 in any order.

Loehman, Ronald E. (Albuquerque, NM); Corral, Erica L. (Tucson, AZ)

2012-03-20T23:59:59.000Z

325

Pressure sensor for high-temperature liquids  

DOE Patents (OSTI)

A pressure sensor for use in measuring pressures in liquid at high temperatures, especially such as liquid sodium or liquid potassium, comprises a soft diaphragm in contact with the liquid. The soft diaphragm is coupled mechanically to a stiff diaphragm. Pressure is measured by measuring the displacment of both diaphragms, typically by measuring the capacitance between the stiff diaphragm and a fixed plate when the stiff diaphragm is deflected in response to the measured pressure through mechanical coupling from the soft diaphragm. Absolute calibration is achieved by admitting gas under pressure to the region between diaphragms and to the region between the stiff diaphragm and the fixed plate, breaking the coupling between the soft and stiff diaphragms. The apparatus can be calibrated rapidly and absolutely.

Forster, George A. (Westmont, IL)

1978-01-01T23:59:59.000Z

326

Permanent Mold Casting of JIS-AC4C Aluminum Alloy Using a Low-Temperature Mold  

Science Conference Proceedings (OSTI)

Permanent mold casting using mold temperatures below 200 deg. C was conducted to obtain a high-strength, thin-walled casting. Al-7.36 mass% Si -0.18 Cu- 0.27Mg-0.34Fe alloy JIS-AC4C was cast using a bottom pouring cast plan. The product had a rectangular tube shape (70 mm W x 68 mm D x 180 mm H) with wall thicknesses of 1, 3 and 5 mm. The effect of heat insulation at the melt path was compared when using a sand runner insert and when using a steel runner insert as well as a powder mold release agent. Fine microstructures were observed in the casting. The smaller the thickness, the higher the hardness with smaller secondary dendrite arm spacing (SDAS). However, the hardness and the SDAS were unaffected by the mold temperature. It was proposed that the avoidance of the formation of primary {alpha} dendrite at the melt path generates a higher strength casting with adequate mold filling.

Yamagata, Hiroshi; Nikawa, Makoto

2011-01-17T23:59:59.000Z

327

Assessment of microelectronics packaging for high temperature, high reliability applications  

DOE Green Energy (OSTI)

This report details characterization and development activities in electronic packaging for high temperature applications. This project was conducted through a Department of Energy sponsored Cooperative Research and Development Agreement between Sandia National Laboratories and General Motors. Even though the target application of this collaborative effort is an automotive electronic throttle control system which would be located in the engine compartment, results of this work are directly applicable to Sandia`s national security mission. The component count associated with the throttle control dictates the use of high density packaging not offered by conventional surface mount. An enabling packaging technology was selected and thermal models defined which characterized the thermal and mechanical response of the throttle control module. These models were used to optimize thick film multichip module design, characterize the thermal signatures of the electronic components inside the module, and to determine the temperature field and resulting thermal stresses under conditions that may be encountered during the operational life of the throttle control module. Because the need to use unpackaged devices limits the level of testing that can be performed either at the wafer level or as individual dice, an approach to assure a high level of reliability of the unpackaged components was formulated. Component assembly and interconnect technologies were also evaluated and characterized for high temperature applications. Electrical, mechanical and chemical characterizations of enabling die and component attach technologies were performed. Additionally, studies were conducted to assess the performance and reliability of gold and aluminum wire bonding to thick film conductor inks. Kinetic models were developed and validated to estimate wire bond reliability.

Uribe, F.

1997-04-01T23:59:59.000Z

328

High Temperature Integrated Thermoelectric Ststem and Materials  

DOE Green Energy (OSTI)

The final goal of this project is to produce, by the end of Phase II, an all ceramic high temperature thermoelectric module. Such a module design integrates oxide ceramic n-type, oxide ceramic p-type materials as thermoelectric legs and oxide ceramic conductive material as metalizing connection between n-type and p-type legs. The benefits of this all ceramic module are that it can function at higher temperatures (> 700 C), it is mechanically and functionally more reliable and it can be scaled up to production at lower cost. With this all ceramic module, millions of dollars in savings or in new opportunities recovering waste heat from high temperature processes could be made available. A very attractive application will be to convert exhaust heat from a vehicle to reusable electric energy by a thermoelectric generator (TEG). Phase I activities were focused on evaluating potential n-type and p-type oxide compositions as the thermoelectric legs. More than 40 oxide ceramic powder compositions were made and studied in the laboratory. The compositions were divided into 6 groups representing different material systems. Basic ceramic properties and thermoelectric properties of discs sintered from these powders were measured. Powders with different particles sizes were made to evaluate the effects of particle size reduction on thermoelectric properties. Several powders were submitted to a leading thermoelectric company for complete thermoelectric evaluation. Initial evaluation showed that when samples were sintered by conventional method, they had reasonable values of Seebeck coefficient but very low values of electrical conductivity. Therefore, their power factors (PF) and figure of merits (ZT) were too low to be useful for high temperature thermoelectric applications. An unconventional sintering method, Spark Plasma Sintering (SPS) was determined to produce better thermoelectric properties. Particle size reduction of powders also was found to have some positive benefits. Two composition systems, specifically 1.0 SrO - 0.8 x 1.03 TiO2 - 0.2 x 1.03 NbO2.5 and 0.97 TiO2 - 0.03 NbO2.5, have been identified as good base line compositions for n-type thermoelectric compositions in future module design. Tests of these materials at an outside company were promising using that company's processing and material expertise. There was no unique p-type thermoelectric compositions identified in phase I work other than several current cobaltite materials. Ca3Co4O9 will be the primary p-type material for the future module design until alternative materials are developed. BaTiO3 and rare earth titanate based dielectric compositions show both p-type and n-type behavior even though their electrical conductivities were very low. Further research and development of these materials for thermoelectric applications is planned in the future. A preliminary modeling and optimization of a thermoelectric generator (TEG) that uses the n-type 1.0 SrO - 1.03 x 0.8 TiO2 - 1.03 x 0.2 NbO2.5 was performed. Future work will combine development of ceramic powders and manufacturing expertise at TAM, development of SPS at TAM or a partner organization, and thermoelectric material/module testing, modeling, optimization, production at several partner organizations.

Mike S. H. Chu

2011-06-06T23:59:59.000Z

329

The New England High-Resolution Temperature Program  

Science Conference Proceedings (OSTI)

The New England High-Resolution Temperature Program seeks to improve the accuracy of summertime 2-m temperature and dewpoint temperature forecasts in the New England region through a collaborative effort between the research and operational ...

David J. Stensrud; Nusrat Yussouf; Michael E. Baldwin; Jeffery T. McQueen; Jun Du; Binbin Zhou; Brad Ferrier; Geoffrey Manikin; F. Martin Ralph; James M. Wilczak; Allen B. White; Irina Djlalova; Jian-Wen Bao; Robert J. Zamora; Stanley G. Benjamin; Patricia A. Miller; Tracy Lorraine Smith; Tanya Smirnova; Michael F. Barth

2006-04-01T23:59:59.000Z

330

High Temperature Interactions of Antimony with Nickel  

SciTech Connect

In this chapter, the surface and bulk interactions of antimony with the Ni-based anodes in solid oxide fuel cells (SOFC) will be discussed. High fuel flexibility is a significant advantage of SOFCs, allowing the direct use of fossil and bio fuels without a hydrogen separation unit. Synthesis gas derived from coal and biomass consists of a mixture of hydrogen, carbon monoxide, carbon dioxide, and steam, but finite amounts of tars and trace impurities such as S, Se, P, As, Sb, Cd, Pb, Cl, etc, are also always present. While synthesis gas is commonly treated with a series of chemical processes and scrubbers to remove the impurities, complete purification is not economical. Antimony is widely distributed in coals. During coal gasification antimony is volatilized, such that contact with the SOFC anodes and other SOFC parts, e.g., interconnect, current collecting wires, fuel gas supplying tubing, is most likely. This chapter addresses the following topics: high temperature Ni - Sb interactions; alteration phase, Ni3Sb, Ni5Sb2, NiSb, formation; thermochemical modeling; impact of Sb on the electrocatalytic activity of Ni toward the fuel oxidation and the presence of other impurities (sulfur, in particular); converted anode structural instability during long-term SOFC operation; comparison with nickel heterogeneous catalysts.

Marina, Olga A.; Pederson, Larry R.

2012-07-01T23:59:59.000Z

331

High Temperature Steam Electrolysis Materials Degradation: Preliminary Results of Corrosion Tests on Ceramatec Electrolysis Cell Components  

DOE Green Energy (OSTI)

Corrosion tests were performed on stainless steel and nickel alloy coupons in H2O/H2 mixtures and dry air to simulate conditions experienced in high temperature steam electrolysis systems. The stainless steel coupons were tested bare and with one of three different proprietary coatings applied. Specimens were corroded at 850°C for 500 h with weight gain data recorded at periodic intervals. Post-test characterization of the samples included surface and cross-section scanning electron microscopy, grazing incidence x-ray diffraction, and area-specific resistance measurements. The uncoated nickel alloy outperformed the ferritic stainless steel under all test conditions based on weight gain data. Parabolic rate constants for corrosion of these two uncoated alloys were consistent with values presented in the literature under similar conditions. The steel coatings reduced corrosion rates in H2O/H2 mixtures by as much as 50% compared to the untreated steel, but in most cases showed negligible corrosion improvement in air. The use of a rare-earth-based coating on stainless steel did not result in a significantly different area specific resistance values after corrosion compared to the untreated alloy. Characterization of the samples is still in progress and the findings will be revised when the complete data set is available.

Paul Demkowicz; Prateek Sachdev; Kevin DeWall; Pavel Medvedev

2007-06-01T23:59:59.000Z

332

NOVEL REFRACTORY MATERIALS FOR HIGH ALKALI, HIGH TEMPERATURE ENVIRONMENTS  

SciTech Connect

A project was led by Oak Ridge National Laboratory (ORNL) in collaboration with a research team comprised of the academic institution Missouri University of Science and Technology (MS&T), and the industrial company MINTEQ International, Inc. (MINTEQ), along with representatives from the aluminum, chemical, glass, and forest products industries. The project was to address the need for new innovative refractory compositions by developing a family of novel MgO-Al 2O3, MgAl2O4, or other similar spinel structured or alumina-based unshaped refractory compositions (castables, gunnables, shotcretes, etc.) utilizing new aggregate materials, bond systems, protective coatings, and phase formation techniques (in-situ phase formation, altered conversion temperatures, accelerated reactions, etc). This family of refractory compositions would then be tailored for use in high-temperature, high-alkaline industrial environments like those found in the aluminum, chemical, forest products, glass, and steel industries. Both practical refractory development experience and computer modeling techniques were used to aid in the design of this new family of materials. The newly developed materials were expected to offer alternative material choices for high-temperature, high-alkali environments that were capable of operating at higher temperatures (goal of increasing operating temperature by 100-200oC depending on process) or for longer periods of time (goal of twice the life span of current materials or next process determined service increment). This would lead to less process down time, greater energy efficiency for associated manufacturing processes (more heat kept in process), and materials that could be installed/repaired in a more efficient manner. The overall project goal was a 5% improvement in energy efficiency (brought about through a 20% improvement in thermal efficiency) resulting in a savings of 3.7 TBtu/yr (7.2 billion ft3 natural gas) by the year 2030. Additionally, new application techniques and systems were developed as part of this project to optimize the installation of this new family of refractory materials to maximize the properties of installed linings and to facilitate nuances such as hot installation and repair. Under this project, seven new shotcrete materials were developed for both primary and repair applications in aluminum, black liquor, coal gasification, and lime kiln environments. Developed materials were based on alumino-silicate, magnesia, and spinel forming systems. One of the developed materials was an insulating shotcrete to be used behind the high conductivity spinel linings developed under this project. Fundamental research work was carried out at MS&T throughout the life of the project to provide support for the development and production of the experimental refractory materials being developed. Work was also ongoing at ORNL and MS&T through the duration of the project on the measurement and characterization of key refractory properties as identified during year one of the project. Both materials currently being used in the industrial processes as identified and supplied by the industrial partners of this project and new materials being provided and developed by MINTEQ were evaluated as necessary. Additionally, energy savings estimates based on measured properties of the experimentally developed refractory systems from this project were made at MINTEQ to validate the energy savings estimates originally proposed for the project. As another part of the project, on-line inspection and hot repair techniques were considered. It was determined that although repair materials were successfully developed under this project for aluminum, black liquor, and coal gasification systems which enable hot repair, there was only minor interest from industry in implementing these materials. On-line inspection techniques were also identified under this project which are currently used in the steel industry, but implementation of these techniques in applications such as black liquor and coal gasification where higher temperature

Hemrick, James Gordon [ORNL; Smith, Jeffrey D [ORNL; O'Hara, Kelley [University of Missouri, Rolla; Rodrigues-Schroer, Angela [Minteq International, Inc.; Colavito, [Minteq International, Inc.

2012-08-01T23:59:59.000Z

333

Gas Viscosity at High Pressure and High Temperature  

E-Print Network (OSTI)

Gas viscosity is one of the gas properties that is vital to petroleum engineering. Its role in the oil and gas production and transportation is indicated by its contribution in the resistance to the flow of a fluid both in porous media and pipes. Although viscosity of some pure components such as methane, ethane, propane, butane, nitrogen, carbon dioxide and binary mixtures of these components at low-intermediate pressure and temperature had been studied intensively and been understood thoroughly, very few investigations were performed on viscosity of naturally occurring gases, especially gas condensates at low-intermediate pressure and temperature, even fewer lab data were published. No gas viscosity data at high pressures and high temperatures (HPHT) is available. Therefore this gap in the oil industry still needs to be filled. Gas viscosity at HPHT becomes crucial to modern oil industry as exploration and production move to deep formation or deep water where HPHT is not uncommon. Therefore, any hydrocarbon encountered there is more gas than oil due to the chemical reaction causing oil to transfer to gas as temperature increases. We need gas viscosity to optimize production rate for production system, estimate reserves, model gas injection, design drilling fluid, and monitor gas movement in well control. Current gas viscosity correlations are derived using measured data at low-moderate pressures and temperatures, and then extrapolated to HPHT. No measured gas viscosities at HPHT are available so far. The validities of these correlations for gas viscosity at HPHT are doubted due to lack of experimental data. In this study, four types of viscometers are evaluated and their advantages and disadvantages are listed. The falling body viscometer is used to measure gas viscosity at a pressure range of 3000 to 25000 psi and a temperature range of 100 to 415 oF. Nitrogen viscosity is measured to take into account of the fact that the concentration of nonhydrocarbons increase drastically in HPHT reservoir. More nitrogen is found as we move to HPHT reservoirs. High concentration nitrogen in natural gas affects not only the heat value of natural gas, but also gas viscosity which is critical to petroleum engineering. Nitrogen is also one of common inject gases in gas injection projects, thus an accurate estimation of its viscosity is vital to analyze reservoir performance. Then methane viscosity is measured to honor that hydrocarbon in HPHT which is almost pure methane. From our experiments, we found that while the Lee-Gonzalez-Eakin correlation estimates gas viscosity at a low-moderate pressure and temperature accurately, it cannot give good match of gas viscosity at HPHT. Apparently, current correlations need to be modified to predict gas viscosity at HPHT. New correlations constructed for HPHT conditions based on our experiment data give more confidence on gas viscosity.

Ling, Kegang

2010-12-01T23:59:59.000Z

334

High performance internal reforming unit for high temperature fuel cells  

DOE Patents (OSTI)

A fuel reformer having an enclosure with first and second opposing surfaces, a sidewall connecting the first and second opposing surfaces and an inlet port and an outlet port in the sidewall. A plate assembly supporting a catalyst and baffles are also disposed in the enclosure. A main baffle extends into the enclosure from a point of the sidewall between the inlet and outlet ports. The main baffle cooperates with the enclosure and the plate assembly to establish a path for the flow of fuel gas through the reformer from the inlet port to the outlet port. At least a first directing baffle extends in the enclosure from one of the sidewall and the main baffle and cooperates with the plate assembly and the enclosure to alter the gas flow path. Desired graded catalyst loading pattern has been defined for optimized thermal management for the internal reforming high temperature fuel cells so as to achieve high cell performance.

Ma, Zhiwen (Sandy Hook, CT); Venkataraman, Ramakrishnan (New Milford, CT); Novacco, Lawrence J. (Brookfield, CT)

2008-10-07T23:59:59.000Z

335

Corrosion resistant positive electrode for high-temperature, secondary electrochemical cell  

DOE Patents (OSTI)

The corrosion rate of low carbon steel within a positive electrode of a high-temperature, secondary electrochemical cell that includes FeS as active material is substantially reduced by incorporating therein finely divided iron powder in stoichiometric excess to the amount required to form FeS in the fully charged electrode. The cell typically includes an alkali metal or alkaline earth metal as negative electrode active material and a molten metal halide salt as electrolyte. The excess iron permits use of inexpensive carbon steel alloys that are substantially free of the costly corrosion resistant elements chromium, nickel and molybdenum while avoiding shorten cell life resulting from high corrosion rates.

Otto, N.C.; Warner, B.T.; Smaga, J.A.; Battles, J.E.

1982-07-07T23:59:59.000Z

336

Corrosion resistant positive electrode for high-temperature, secondary electrochemical cell  

DOE Patents (OSTI)

The corrosion rate of low carbon steel within a positive electrode of a high-temperature, secondary electrochemical cell that includes FeS as active material is substantially reduced by incorporating therein finely divided iron powder in stoichiometric excess to the amount required to form FeS in the fully charged electrode. The cell typically includes an alkali metal or alkaline earth metal as negative electrode active material and a molten metal halide salt as electrolyte. The excess iron permits use of inexpensive carbon steel alloys that are substantially free of the costly corrosion resistant elements chromium, nickel and molybdenum while avoiding shorten cell life resulting from high corrosion rates.

Otto, Neil C. (Chicago, IL); Warner, Barry T. (South Holland, IL); Smaga, John A. (Lemont, IL); Battles, James E. (Oak Forest, IL)

1983-01-01T23:59:59.000Z

337

Analytic Models of High-Temperature Hohlraums  

SciTech Connect

A unified set of high-temperature-hohlraum models has been developed. For a simple hohlraum, P{sub s} = [A{sub s}+(1{minus}{alpha}{sub W})A{sub W}+A{sub H}]{sigma}T{sub R}{sup 4} + (4V{sigma}/c)(dT{sub R}{sup r}/dt) where P{sub S} is the total power radiated by the source, A{sub s} is the source area, A{sub W} is the area of the cavity wall excluding the source and holes in the wall, A{sub H} is the area of the holes, {sigma} is the Stefan-Boltzmann constant, T{sub R} is the radiation brightness temperature, V is the hohlraum volume, and c is the speed of light. The wall albedo {alpha}{sub W} {triple_bond} (T{sub W}/T{sub R}){sup 4} where T{sub W} is the brightness temperature of area A{sub W}. The net power radiated by the source P{sub N} = P{sub S}-A{sub S}{sigma}T{sub R}{sup 4}, which suggests that for laser-driven hohlraums the conversion efficiency {eta}{sub CE} be defined as P{sub N}/P{sub LASER}. The characteristic time required to change T{sub R}{sup 4} in response to a change in P{sub N} is 4V/C[(l{minus}{alpha}{sub W})A{sub W}+A{sub H}]. Using this model, T{sub R}, {alpha}{sub W}, and {eta}{sub CE} can be expressed in terms of quantities directly measurable in a hohlraum experiment. For a steady-state hohlraum that encloses a convex capsule, P{sub N} = {l_brace}(1{minus}{alpha}{sub W})A{sub W}+A{sub H}+[(1{minus}{alpha}{sub C})(A{sub S}+A{sub W}{alpha}{sub W})A{sub C}/A{sub T}]{r_brace}{sigma}T{sub RC}{sup 4} where {alpha}{sub C} is the capsule albedo, A{sub C} is the capsule area, A{sub T} {triple_bond} (A{sub S}+A{sub W}+A{sub H}), and T{sub RC} is the brightness temperature of the radiation that drives the capsule. According to this relation, the capsule-coupling efficiency of the baseline National-Ignition-Facility (NIF) hohlraum is 15% higher than predicted by previous analytic expressions. A model of a hohlraum that encloses a z pinch is also presented.

Stygar, W.A.; Olson, R.E.; Spielman, R.B.; Leeper, R.J.

2000-11-29T23:59:59.000Z

338

Fuel Cell Technologies Office: 2009 High Temperature Membrane Working Group  

NLE Websites -- All DOE Office Websites (Extended Search)

9 High Temperature 9 High Temperature Membrane Working Group Meeting Archives to someone by E-mail Share Fuel Cell Technologies Office: 2009 High Temperature Membrane Working Group Meeting Archives on Facebook Tweet about Fuel Cell Technologies Office: 2009 High Temperature Membrane Working Group Meeting Archives on Twitter Bookmark Fuel Cell Technologies Office: 2009 High Temperature Membrane Working Group Meeting Archives on Google Bookmark Fuel Cell Technologies Office: 2009 High Temperature Membrane Working Group Meeting Archives on Delicious Rank Fuel Cell Technologies Office: 2009 High Temperature Membrane Working Group Meeting Archives on Digg Find More places to share Fuel Cell Technologies Office: 2009 High Temperature Membrane Working Group Meeting Archives on AddThis.com...

339

Hydrogen production from fusion reactors coupled with high temperature electrolysis  

SciTech Connect

An initial study was conducted on a fusion reactor and high temperature electrolyzer system for the production of synthetic fuel. The design temperatures in the fusion reactor blanket were above 1380/sup 0/C. Electrolytic hydrogen production at the high temperatures consumes a high ratio of thermal to electric energy and increases the efficiency of the plant and an overall efficiency of approximately 50% appeared possible. The concepts of the system and the design considerations of the high temperature electrolyzer will be presented.

Isaacs, H.S.; Fillo, J.A.; Dang, V.; Powell, J.R.; Steinberg, M.; Salzano, F.; Benenati, R.

1978-01-01T23:59:59.000Z

340

Improved Growth of High-Temperature Superconductors with ...  

Visual Patent Search; Success Stories; News; Events; Electricity Transmission Improved Growth of High-Temperature Superconductors with HF Pressure ...

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

WEB RESOURCE: High Temperature Materials 21 Project (Phase 2)  

Science Conference Proceedings (OSTI)

Feb 10, 2007... thermal efficiency of power generation systems and advanced aeroengines. ... SOURCE: Harada, H. "High Temperature Materials 21 Project ...

342

A Possible Pressure-Induced High-Temperature-Superconducting  

Science Conference Proceedings (OSTI)

... Materials Forensics, Three-dimensional Modeling and Fractal Characterization · Vortex Physics in Oxide and Pnictide High Temperature Superconductors.

343

Hydrogen Production from Nuclear Energy via High Temperature Electrolysis  

DOE Green Energy (OSTI)

This paper presents the technical case for high-temperature nuclear hydrogen production. A general thermodynamic analysis of hydrogen production based on high-temperature thermal water splitting processes is presented. Specific details of hydrogen production based on high-temperature electrolysis are also provided, including results of recent experiments performed at the Idaho National Laboratory. Based on these results, high-temperature electrolysis appears to be a promising technology for efficient large-scale hydrogen production.

James E. O'Brien; Carl M. Stoots; J. Stephen Herring; Grant L. Hawkes

2006-04-01T23:59:59.000Z

344

High Temperature Materials I - Programmaster.org  

Science Conference Proceedings (OSTI)

Feb 28, 2011 ... To increase efficiency and reduce carbon emissions, boilers, heat exchangers, and turbines all will be asked to perform at higher temperature ...

345

Novel Techniques for Investigating the High Temperature ...  

Science Conference Proceedings (OSTI)

(enriched to 87%, ga=O.87) for 4 hours and 62 hours at the same temperature. ... Neglecting any contribution from 170-, which has a natural abundance of ...

346

New Ultra-High Temperature Material Systems  

Science Conference Proceedings (OSTI)

Oct 9, 2012 ... Hafnium Based Coatings for Non-Oxide Ultrahigh Temperature ... the fracture properties and resistance to thermal shock were evaluated before ...

347

Applications of High-temperature Structural Materials  

Science Conference Proceedings (OSTI)

Aug 9, 2013 ... The development of advanced ultra-supercritical coal-fired power plants with operating temperature beyond 700°C requires the partial ...

348

Fuel Cell Technologies Office: 2006 High Temperature Membrane...  

NLE Websites -- All DOE Office Websites (Extended Search)

Systems for High Temperature, Low Relative Humidity Polymer-Type Membranes, Andrew Herring, Colorado School of Mines (PDF 213 KB) Design and Development of High-Performance...

349

High temperatures drove record electricity demand and very ...  

U.S. Energy Information Administration (EIA)

Therefore, the high prices for Friday were set on Thursday when ERCOT had called a supply emergency and temperatures were expected to remain high on ...

350

Response of aluminum and its alloys to exposure in the high flux isotope reactor  

DOE Green Energy (OSTI)

Pure aluminum and some aluminum alloys were irradiated to very high neutron fluences in the cooling water at 328 K in the high flux region of HFIR. Displacement levels of 270 dpa and transmutation-produced silicon levels of 7.15 wt % were reached. Damage microstructures consisted of dislocations, cavities, and precipitates which caused substantial strengthening and associated loss in ductility. Formation of cavities and related swelling were considerably reduced by alloying elements and by the presence of fine Mg/sub 2/Si precipitate.

Farrell, K.

1983-01-01T23:59:59.000Z

351

NOvel Refractory Materials for High Alkali, High Temperature Environments  

SciTech Connect

Refractory materials can be limited in their application by many factors including chemical reactions between the service environment and the refractory material, mechanical degradation of the refractory material by the service environment, temperature limitations on the use of a particular refractory material, and the inability to install or repair the refractory material in a cost effective manner or while the vessel was in service. The objective of this project was to address the need for new innovative refractory compositions by developing a family of novel MgO-Al2O3 spinel or other similar magnesia/alumina containing unshaped refractory composition (castables, gunnables, shotcretes, etc) utilizing new aggregate materials, bond systems, protective coatings, and phase formation techniques (in-situ phase formation, altered conversion temperatures, accelerated reactions, etc). This family of refractory compositions would then be tailored for use in high-temperature, highalkaline industrial environments like those found in the aluminum, chemical, forest products, glass, and steel industries. A research team was formed to carry out the proposed work led by Oak Ridge National Laboratory (ORNL) and was comprised of the academic institution Missouri University of Science and Technology (MS&T), and the industrial company MINTEQ International, Inc. (MINTEQ), along with representatives from the aluminum, chemical, glass, and forest products industries. The two goals of this project were to produce novel refractory compositions which will allow for improved energy efficiency and to develop new refractory application techniques which would improve the speed of installation. Also methods of hot installation were sought which would allow for hot repairs and on-line maintenance leading to reduced process downtimes and eliminating the need to cool and reheat process vessels.

Hemrick, J.G.; Griffin, R. (MINTEQ International, Inc.)

2011-08-30T23:59:59.000Z

352

Fusion reactors-high temperature electrolysis (HTE)  

DOE Green Energy (OSTI)

Results of a study to identify and develop a reference design for synfuel production based on fusion reactors are given. The most promising option for hydrogen production was high-temperature electrolysis (HTE). The main findings of this study are: 1. HTE has the highest potential efficiency for production of synfuels from fusion; a fusion to hydrogen energy efficiency of about 70% appears possible with 1800/sup 0/C HTE units and 60% power cycle efficiency; an efficiency of about 50% possible with 1400/sup 0/C HTE units and 40% power cycle efficiency. 2. Relative to thermochemical or direct decomposition methods HTE technology is in a more advanced state of development, 3. Thermochemical or direct decomposition methods must have lower unit process or capital costs if they are to be more attractive than HTE. 4. While design efforts are required, HTE units offer the potential to be quickly run in reverse as fuel cells to produce electricity for restart of Tokamaks and/or provide spinning reserve for a grid system. 5. Because of the short timescale of the study, no detailed economic evaluation could be carried out.A comparison of costs could be made by employing certain assumptions. For example, if the fusion reactor-electrolyzer capital installation is $400/(KW(T) ($1000/KW(E) equivalent), the H/sub 2/ energy production cost for a high efficiency (about 70 %) fusion-HTE system is on the same order of magnitude as a coal based SNG plant based on 1976 dollars. 6. The present reference design indicates that a 2000 MW(th) fusion reactor could produce as much at 364 x 10/sup 6/ scf/day of hydrogen which is equivalent in heating value to 20,000 barrels/day of gasoline. This would fuel about 500,000 autos based on average driving patterns. 7. A factor of three reduction in coal feed (tons/day) could be achieved for syngas production if hydrogen from a fusion-HTE system were used to gasify coal, as compared to a conventional syngas plant using coal-derived hydrogen.

Fillo, J.A. (ed.)

1978-01-01T23:59:59.000Z

353

Candidate Alloys for Cost-Effective, High-Efficiency, High ... - TMS  

Science Conference Proceedings (OSTI)

Sep 16, 2007... attractive sources for combined heat and power (CHP) cogeneration. ... and suggest that these alloys developed for gas- and micro-turbine ...

354

Design of High Field Solenoids made of High Temperature Superconductors  

Science Conference Proceedings (OSTI)

This thesis starts from the analytical mechanical analysis of a superconducting solenoid, loaded by self generated Lorentz forces. Also, a finite element model is proposed and verified with the analytical results. To study the anisotropic behavior of a coil made by layers of superconductor and insulation, a finite element meso-mechanic model is proposed and designed. The resulting material properties are then used in the main solenoid analysis. In parallel, design work is performed as well: an existing Insert Test Facility (ITF) is adapted and structurally verified to support a coil made of YBa{sub 2}Cu{sub 3}O{sub 7}, a High Temperature Superconductor (HTS). Finally, a technological winding process was proposed and the required tooling is designed.

Bartalesi, Antonio; /Pisa U.

2010-12-01T23:59:59.000Z

355

Passive Corrosion Behavior of Alloy 22  

SciTech Connect

Alloy 22 (NO6022) was designed to stand the most aggressive industrial applications, including both reducing and oxidizing acids. Even in the most aggressive environments, if the temperature is lower than 150 F (66 C) Alloy 22 would remain in the passive state having particularly low corrosion rates. In multi-ionic solutions that may simulate the behavior of concentrated ground water, even at near boiling temperatures, the corrosion rate of Alloy 22 is only a few nano-meters per year because the alloy is in the complete passive state. The corrosion rate of passive Alloy 22 decreases as the time increases. Immersion corrosion testing also show that the newer generation of Ni-Cr-Mo alloys may offer a better corrosion resistance than Alloy 22 only in some highly aggressive conditions such as in hot acids.

R.B. Rebak; J.H. Payer

2006-01-20T23:59:59.000Z

356

High temperature, minimally invasive optical sensing modules  

DOE Patents (OSTI)

A remote temperature sensing system includes a light source selectively producing light at two different wavelengths and a sensor device having an optical path length that varies as a function of temperature. The sensor receives light emitted by the light source and redirects the light along the optical path length. The system also includes a detector receiving redirected light from the sensor device and generating respective signals indicative of respective intensities of received redirected light corresponding to respective wavelengths of light emitted by the light source. The system also includes a processor processing the signals generated by the detector to calculate a temperature of the device.

Riza, Nabeel Agha (Oviedo, FL); Perez, Frank (Tujunga, CA)

2008-02-05T23:59:59.000Z

357

High Alloyed Steels for Energy Applications - Programmaster.org  

Science Conference Proceedings (OSTI)

Oct 10, 2012... to low temperature services with a big cost competitiveness, in particular structural materials for LNG storage and transportation, and so on.

358

Tritium Formation and Mitigation in High-Temperature Reactor Systems  

SciTech Connect

Tritium is a radiologically active isotope of hydrogen. It is formed in nuclear reactors by neutron absorption and ternary fission events and can subsequently escape into the environment. To prevent the tritium contamination of proposed reactor buildings and surrounding sites, this study examines the root causes and potential mitigation strategies for permeation of tritium (such as: materials selection, inert gas sparging, etc...). A model is presented that can be used to predict permeation rates of hydrogen through metallic alloys at temperatures from 450–750 degrees C. Results of the diffusion model are presented for a steady production of tritium

Piyush Sabharwall; Carl Stoots; Hans A. Schmutz

2013-03-01T23:59:59.000Z

359

Tritium Formation and Mitigation in High Temperature Reactors  

SciTech Connect

Tritium is a radiologically active isotope of hydrogen. It is formed in nuclear reactors by neutron absorption and ternary fission events and can subsequently escape into the environment. In order to prevent the tritium contamination of proposed reactor buildings and surrounding sites, this paper examines the root causes and potential solutions for the production of this radionuclide, including materials selection and inert gas sparging. A model is presented that can be used to predict permeation rates of hydrogen through metallic alloys at temperatures from 450–750°C. Results of the diffusion model are presented for one steadystate value of tritium production in the reactor.

Piyush Sabharwall; Carl Stoots

2012-08-01T23:59:59.000Z

360

Tritium Formation and Mitigation in High-Temperature Reactors  

SciTech Connect

Tritium is a radiologically active isotope of hydrogen. It is formed in nuclear reactors by neutron absorption and ternary fission events and can subsequently escape into the environment. To prevent the tritium contamination of proposed reactor buildings and surrounding sites, this study examines the root causes and potential mitigation strategies for permeation of tritium (such as: materials selection, inert gas sparging, etc...). A model is presented that can be used to predict permeation rates of hydrogen through metallic alloys at temperatures from 450–750 degrees C. Results of the diffusion model are presented for a steady production of tritium

Piyush Sabharwall; Carl Stoots

2012-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

High Temperature Hold Time Effects on Fine Grain Processed 718 ...  

Science Conference Proceedings (OSTI)

Abstract. Fine Grain Alloy 718 is a relatively cost effective turbine and compressor disk alloy with superior yield strength and low cycle fatigue properties.

362

Metallic substrates for high temperature superconductors  

DOE Patents (OSTI)

A biaxially textured face-centered cubic metal article having grain boundaries with misorientation angles greater than about 8.degree. limited to less than about 1%. A laminate article is also disclosed having a metal substrate first rolled to at least about 95% thickness reduction followed by a first annealing at a temperature less than about 375.degree. C. Then a second rolling operation of not greater than about 6% thickness reduction is provided, followed by a second annealing at a temperature greater than about 400.degree. C. A method of forming the metal and laminate articles is also disclosed.

Truchan, Thomas G. (Chicago, IL); Miller, Dean J. (Darien, IL); Goretta, Kenneth C. (Downers Grove, IL); Balachandran, Uthamalingam (Hinsdale, IL); Foley, Robert (Chicago, IL)

2002-01-01T23:59:59.000Z

363

High Temperature Compressive Behavior of Ni-Fe-Cr-Al Powder ...  

Science Conference Proceedings (OSTI)

K2: Microstructural Development of Plutonium Alloys via Cooling Curve Analysis · K3: Preparation of High Purity Tellurium by Zone Refining Process.

364

Structural alloy with a protective coating containing silicon or silicon-oxide  

DOE Patents (OSTI)

This invention is comprised of an iron-based alloy containing chromium and optionally, nickel. The alloy has a surface barrier of silicon or silicon plus oxygen which converts at high temperature to a protective silicon compound. The alloy can be used in oxygen-sulfur mixed gases at temperatures up to about 1100{degrees}C.

Natesan, K.

1992-01-01T23:59:59.000Z

365

High-field superconductivity in some bcc Ti-Mo and Nb-Zr alloys  

Science Conference Proceedings (OSTI)

Zero electrical resistance at unusually high magnetic field strengths has been observed in the bcc alloys Ti-16 a/o (atomic percent) Mo, Nb-12 a/o Zr, and Nb-25 a/o Zr. The maximum highfield zero-resistance current density, Jc, in these ...

R. R. Hake; T. G. Berlincourt; D. H. Leslie

1962-01-01T23:59:59.000Z

366

Fuel Cell Technologies Office: High Temperature Membrane Working Group  

NLE Websites -- All DOE Office Websites (Extended Search)

High Temperature Membrane Working Group High Temperature Membrane Working Group The High Temperature Membrane Working Group consists of government, industry, and university researchers interested in developing high temperature membranes for fuel cells. Description Technical Targets Meetings Contacts Description Polymer electrolyte membrane (PEM) fuel cells typically operate at temperatures no higher than 60°C-80°C due to structural limitations of the membrane. Operating PEM fuel cell stacks at higher temperatures (120°C for transportation and 150°C for stationary applications), however, would yield significant energy benefits. For example, heat rejection is easier at higher temperatures, which would allow use of smaller heat exchangers in fuel cell power systems. In addition, for reformate fuel cell systems, carbon monoxide (CO) tolerance of the stack is less problematic at higher temperatures, which would reduce the size requirements or possibly eliminate the need for some CO clean-up beds in the fuel processor.

367

Cryogenic deformation of high temperature superconductive composite structures  

DOE Patents (OSTI)

An improvement in a process of preparing a composite high temperature oxide superconductive wire is provided and involves conducting at least one cross-sectional reduction step in the processing preparation of the wire at sub-ambient temperatures.

Roberts, Peter R. (Groton, MA); Michels, William (Brookline, MA); Bingert, John F. (Jemez Springs, NM)

2001-01-01T23:59:59.000Z

368

High Temperature Gas Reactors The Next Generation ?  

E-Print Network (OSTI)

HPT CCS Reactor CBCS #12;14 Integrated Plant Systems #12;15 Differences Between LWRS · Higher Thermal - Not shown Fresh Fuel Storage Used Fuel Storage Tanks #12;39 MPBR Specifications Thermal Power 250 MW Core temperatures about 1670 C. #12;MPBRBUSBARGENERATIONCOSTS(`92$) ReactorThermal Power (MWt) 10x250 Net Efficiency

369

High Temperature Gas Reactors Briefing to  

E-Print Network (OSTI)

· Nuclear Power 2010 · Next Generation Nuclear Plant (NGNP) · Generation IV Nuclear Plants · NRC Regulatory Specifications · Rated Power per Module 165-175 MW(e) depending on injection temperature · Eight-pack Plant 1320 - Indirect Cycle - Core Options Available - Waste Minimization #12;Modular Pebble Bed Reactor Thermal Power

370

High-Temperature Viscosity of Commercial Glasses  

SciTech Connect

Arrhenius models were developed for glass viscosity within the processing temperature of six types of commercial glasses: low-expansion-borosilicate glasses, E glasses, fiberglass wool glasses, TV panel glasses, container glasses, and float glasses. Both local models (for each of the six glass types) and a global model (for the composition region of commercial glasses, i.e., the six glass types taken together) are presented. The models are based on viscosity data previously obtained with rotating spindle viscometers within the temperature range between 900 C and 1550 C; the viscosity varied from 1 Pa?s to 750 Pa?s. First-order models were applied to relate Arrhenius coefficients to the mass fractions of 15 components: SiO2, TiO2, ZrO2, Al2O3, Fe2O3, B2O3, MgO, CaO, SrO, BaO, PbO, ZnO, Li2O, Na2O, K2O. The R2 is 0.98 for the global model and ranges from .097 to 0.99 for the six local models. The models are recommended for glasses containing 42 to 84 mass% SiO2 to estimate viscosities or temperatures at a constant viscosity for melts within both the temperature range from 1100 C to 1550 C and viscosity range from 5 to 400 Pa?s.

Hrma, Pavel R.

2006-08-31T23:59:59.000Z

371

Dual-phase membrane for High temperature CO2 separation  

NLE Websites -- All DOE Office Websites (Extended Search)

2 CO 2 High temp. membrane for CO 2 removal High Temperature CO 2 Selective Membranes Syngas gas CO 2 enriched gas CO 2 High pressure H 2 0 100 200 300 400 500 600 700 1 10 100...

372

Fuel Cell Technologies Office: 2005 High Temperature Membrane Working Group  

NLE Websites -- All DOE Office Websites (Extended Search)

About About Printable Version Share this resource Send a link to Fuel Cell Technologies Office: 2005 High Temperature Membrane Working Group Meeting Archives to someone by E-mail Share Fuel Cell Technologies Office: 2005 High Temperature Membrane Working Group Meeting Archives on Facebook Tweet about Fuel Cell Technologies Office: 2005 High Temperature Membrane Working Group Meeting Archives on Twitter Bookmark Fuel Cell Technologies Office: 2005 High Temperature Membrane Working Group Meeting Archives on Google Bookmark Fuel Cell Technologies Office: 2005 High Temperature Membrane Working Group Meeting Archives on Delicious Rank Fuel Cell Technologies Office: 2005 High Temperature Membrane Working Group Meeting Archives on Digg Find More places to share Fuel Cell Technologies Office: 2005 High

373

Fuel Cell Technologies Office: 2004 High Temperature Membrane Working Group  

NLE Websites -- All DOE Office Websites (Extended Search)

About About Printable Version Share this resource Send a link to Fuel Cell Technologies Office: 2004 High Temperature Membrane Working Group Meeting Archives to someone by E-mail Share Fuel Cell Technologies Office: 2004 High Temperature Membrane Working Group Meeting Archives on Facebook Tweet about Fuel Cell Technologies Office: 2004 High Temperature Membrane Working Group Meeting Archives on Twitter Bookmark Fuel Cell Technologies Office: 2004 High Temperature Membrane Working Group Meeting Archives on Google Bookmark Fuel Cell Technologies Office: 2004 High Temperature Membrane Working Group Meeting Archives on Delicious Rank Fuel Cell Technologies Office: 2004 High Temperature Membrane Working Group Meeting Archives on Digg Find More places to share Fuel Cell Technologies Office: 2004 High

374

Fuel Cell Technologies Office: 2010 High Temperature Membrane Working Group  

NLE Websites -- All DOE Office Websites (Extended Search)

About About Printable Version Share this resource Send a link to Fuel Cell Technologies Office: 2010 High Temperature Membrane Working Group Meeting Archives to someone by E-mail Share Fuel Cell Technologies Office: 2010 High Temperature Membrane Working Group Meeting Archives on Facebook Tweet about Fuel Cell Technologies Office: 2010 High Temperature Membrane Working Group Meeting Archives on Twitter Bookmark Fuel Cell Technologies Office: 2010 High Temperature Membrane Working Group Meeting Archives on Google Bookmark Fuel Cell Technologies Office: 2010 High Temperature Membrane Working Group Meeting Archives on Delicious Rank Fuel Cell Technologies Office: 2010 High Temperature Membrane Working Group Meeting Archives on Digg Find More places to share Fuel Cell Technologies Office: 2010 High

375

Fuel Cell Technologies Office: 2007 High Temperature Membrane Working Group  

NLE Websites -- All DOE Office Websites (Extended Search)

About About Printable Version Share this resource Send a link to Fuel Cell Technologies Office: 2007 High Temperature Membrane Working Group Meeting Archives to someone by E-mail Share Fuel Cell Technologies Office: 2007 High Temperature Membrane Working Group Meeting Archives on Facebook Tweet about Fuel Cell Technologies Office: 2007 High Temperature Membrane Working Group Meeting Archives on Twitter Bookmark Fuel Cell Technologies Office: 2007 High Temperature Membrane Working Group Meeting Archives on Google Bookmark Fuel Cell Technologies Office: 2007 High Temperature Membrane Working Group Meeting Archives on Delicious Rank Fuel Cell Technologies Office: 2007 High Temperature Membrane Working Group Meeting Archives on Digg Find More places to share Fuel Cell Technologies Office: 2007 High

376

Nanoparticles as Reactive Precursors: Synthesis of Alloys, Intermetallic Compounds, and Multi-Metal Oxides Through Low-Temperature Annealing and Conversion Chemistry  

E-Print Network (OSTI)

Alloys, intermetallic compounds and multi-metal oxides are generally made by traditional solid-state methods that often require melting or grinding/pressing powders followed by high temperature annealing (> 1000 degrees C) for days or weeks. The research presented here takes advantage of the fact that nanoparticles have a large fraction of their atoms on the surface making them highly reactive and their small size virtually eliminates the solid-solid diffusion process as the rate limiting step. Materials that normally require high temperatures and long annealing times become more accessible at relatively low-temperatures because of the increased interfacial contact between the nanoparticle reactants. Metal nanoparticles, formed via reduction of metal salts in an aqueous solution and stabilized by PVP (polyvinylpyrrolidone), were mixed into nanoparticle composites in stoichometric proportions. The composite mixtures were then annealed at relatively low temperatures to form alloy and intermetallic compounds at or below 600 degrees C. This method was further extended to synthesizing multi-metal oxide systems by annealing metal oxide nanoparticle composites hundreds of degrees lower than more traditional methods. Nanoparticles of Pt (supported or unsupported) were added to a metal salt solution of tetraethylene glycol and heated to obtain alloy and intermetallic nanoparticles. The supported intermetallic nanoparticles were tested as catalysts and PtPb/Vulcan XC-72 showed enhanced catalytic activity for formic acid oxidation while Pt3Sn/Vulcan XC-72 and Cu3Pt/y-Al2O3 catalyzed CO oxidiation at lower temperatures than supported Pt. Intermetallic nanoparticles of Pd were synthesized by conversion chemistry methods previously mentioned and were supported on carbon and alumina. These nanoparticles were tested for Suzuki cross-coupling reactions. However; the homocoupled product was generally favored. The catalytic activity of Pd3Pb/y-Al2O3 was tested for the Heck reaction and gave results comparable to Pd/y-Al2O3 with a slightly better selectivity. Conversion chemistry techniques were used to convert Pt nanocubes into Ptbased intermetallic nanocrystals in solution. It was discovered that aggregated clusters of Pt nanoparticles were capable of converting to FePt3; however, when Pt nanocubes were used the intermetallic phase did not form. Alternatively, it was possible to form PtSn nanocubes by a conversion reaction with SnCl2.

Bauer, John C.

2009-05-01T23:59:59.000Z

377

High-power laser and arc welding of thorium-doped iridium alloys  

SciTech Connect

The arc and laser weldabilities of two Ir-0.3% W alloys containing 60 and 200 wt ppM Th have been investigated. The Ir-.03% W alloy containing 200 wt ppM Th is severely prone to hot cracking during gas tungsten-arc welding. Weld metal cracking results from the combined effects of heat-affected zone liquation cracking and solidification cracking. Scanning electron microscopic analysis of the fractured surface revealed patches of low-melting eutectic. The cracking is influenced to a great extent by the fusion zone microstructure and thorium content. The alloy has been welded with a continuous-wave high-power CO/sub 2/ laser system with beam power ranging from 5 to 10 kW and welding speeds of 8 to 25 mm/s. Successful laser welds without hot cracking have been obtained in this particular alloy. This is attributable to the highly concentrated heat source available in the laser beam and the refinement in fusion zone microstructure obtained during laser welding. Efforts to refine the fusion zone structure during gas tungsten-arc welding of Ir-0.3 % W alloy containing 60 wt ppM Th were partially successful. Here transverse arc oscillation during gas tungsten-arc welding refines the fusion zone structure to a certain extent. However, microstructural analysis of this alloy's laser welds indicates further refinement in the fusion zone microstructure than in that from the gas tungsten-arc process using arc oscillations. The fusion zone structure of the laser weld is a strong function of welding speed.

David, S.A.; Liu, C.T.

1980-05-01T23:59:59.000Z

378

High-power laser and arc welding of thorium-doped iridium alloys  

DOE Green Energy (OSTI)

The arc and laser weldabilities of two Ir-0.3% W alloys containing 60 and 200 wt ppM Th have been investigated. The Ir-.03% W alloy containing 200 wt ppM Th is severely prone to hot cracking during gas tungsten-arc welding. Weld metal cracking results from the combined effects of heat-affected zone liquation cracking and solidification cracking. Scanning electron microscopic analysis of the fractured surface revealed patches of low-melting eutectic. The cracking is influenced to a great extent by the fusion zone microstructure and thorium content. The alloy has been welded with a continuous-wave high-power CO/sub 2/ laser system with beam power ranging from 5 to 10 kW and welding speeds of 8 to 25 mm/s. Successful laser welds without hot cracking have been obtained in this particular alloy. This is attributable to the highly concentrated heat source available in the laser beam and the refinement in fusion zone microstructure obtained during laser welding. Efforts to refine the fusion zone structure during gas tungsten-arc welding of Ir-0.3 % W alloy containing 60 wt ppM Th were partially successful. Here transverse arc oscillation during gas tungsten-arc welding refines the fusion zone structure to a certain extent. However, microstructural analysis of this alloy's laser welds indicates further refinement in the fusion zone microstructure than in that from the gas tungsten-arc process using arc oscillations. The fusion zone structure of the laser weld is a strong function of welding speed.

David, S.A.; Liu, C.T.

1980-05-01T23:59:59.000Z

379

High-Temperature Superconductivity Cable Demonstration Projects  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Temperature Temperature Superconductivity Cable Demonstration Projects Superconductivity Power Equipment www.oe.energy.gov Phone: 202-586-1411 Office of Electricity Delivery and Energy Reliability, OE-1 U.S. Department of Energy - 1000 Independence Avenue, SW - Washington, DC 20585. Plugging America Into the Future of Power "A National Effort to Introduce New Technology into the Power Delivery Infrastructure" "In order to meet President Obama's ambitious energy goals, we must modernize the nation's electrical grid to improve the transmission, storage and reliability of clean energy across the country and help to move renewable energy from the places it can be produced to the places it can be used. The Department of Energy is working with industry partners to develop the

380

ANALYSIS OF A HIGH TEMPERATURE GAS-COOLED REACTOR POWERED HIGH TEMPERATURE ELECTROLYSIS HYDROGEN PLANT  

DOE Green Energy (OSTI)

An updated reference design for a commercial-scale high-temperature electrolysis (HTE) plant for hydrogen production has been developed. The HTE plant is powered by a high-temperature gas-cooled reactor (HTGR) whose configuration and operating conditions are based on the latest design parameters planned for the Next Generation Nuclear Plant (NGNP). The current HTGR reference design specifies a reactor power of 600 MWt, with a primary system pressure of 7.0 MPa, and reactor inlet and outlet fluid temperatures of 322°C and 750°C, respectively. The reactor heat is used to produce heat and electric power to the HTE plant. A Rankine steam cycle with a power conversion efficiency of 44.4% was used to provide the electric power. The electrolysis unit used to produce hydrogen includes 1.1 million cells with a per-cell active area of 225 cm2. The reference hydrogen production plant operates at a system pressure of 5.0 MPa, and utilizes a steam-sweep system to remove the excess oxygen that is evolved on the anode (oxygen) side of the electrolyzer. The overall system thermal-to-hydrogen production efficiency (based on the higher heating value of the produced hydrogen) is 42.8% at a hydrogen production rate of 1.85 kg/s (66 million SCFD) and an oxygen production rate of 14.6 kg/s (33 million SCFD). An economic analysis of this plant was performed with realistic financial and cost estimating The results of the economic analysis demonstrated that the HTE hydrogen production plant driven by a high-temperature helium-cooled nuclear power plant can deliver hydrogen at a competitive cost. A cost of $3.03/kg of hydrogen was calculated assuming an internal rate of return of 10% and a debt to equity ratio of 80%/20% for a reactor cost of $2000/kWt and $2.41/kg of hydrogen for a reactor cost of $1400/kWt.

M. G. McKellar; E. A. Harvego; A. M. Gandrik

2010-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

High Temperature Oxidation Testing of Reverse Infiltrated Ultra High ...  

Science Conference Proceedings (OSTI)

Fracture Criterion of Discontinuous Carbon Fiber Dispersed SiC Matrix ... Issues for the Development of Fatigue Resistant CMC at Intermediate Temperatures.

382

Scaling Studies for High Temperature Test Facility and Modular High Temperature Gas-Cooled Reactor  

SciTech Connect

The Oregon State University (OSU) High Temperature Test Facility (HTTF) is an integral experimental facility that will be constructed on the OSU campus in Corvallis, Oregon. The HTTF project was initiated, by the U.S. Nuclear Regulatory Commission (NRC), on September 5, 2008 as Task 4 of the 5-year High Temperature Gas Reactor Cooperative Agreement via NRC Contract 04-08-138. Until August, 2010, when a DOE contract was initiated to fund additional capabilities for the HTTF project, all of the funding support for the HTTF was provided by the NRC via their cooperative agreement. The U.S. Department of Energy (DOE) began their involvement with the HTTF project in late 2009 via the Next Generation Nuclear Plant (NGNP) project. Because the NRC's interests in HTTF experiments were only centered on the depressurized conduction cooldown (DCC) scenario, NGNP involvement focused on expanding the experimental envelope of the HTTF to include steady-state operations and also the pressurized conduction cooldown (PCC).

Richard R. Schult; Paul D. Bayless; Richard W. Johnson; James R. Wolf; Brian Woods

2012-02-01T23:59:59.000Z

383

High Temperature Corrosion and Oxidation of Materials  

Science Conference Proceedings (OSTI)

Mar 31, 2013... oil and gas, and propulsion industries, materials with improved high ... and interdiffusion, and cost-effective materials processing protocols.

384

High temperature elemental losses and mineralogical  

E-Print Network (OSTI)

future energy crops. Combustion in biomass fueled boilers,in ash during combustion of biomass fuels is important forC. Combustion characteristics of high alkali biomass. Final

Thy, P.; Jenkins, B. M.; Grundvig, S.; Shiraki, R.; Lesher, C. E.

2006-01-01T23:59:59.000Z

385

High Temperature Oxidation and Design for Resistance  

Science Conference Proceedings (OSTI)

Mar 2, 2011 ... Overall weight uptakes followed linear kinetics in dry CO2, but additions of H2O caused a transition to parabolic kinetics. In contrast, high ...

386

Spectral Emissivity Measurements of High Temperature Reactor ...  

Science Conference Proceedings (OSTI)

CASL: The Consortium for Advanced Simulation of Light Water Reactors: A U.S. ... Strategies for Studying High Dose Irradiation Effects in Reactor Components.

387

Hydrogen in titanium alloys  

DOE Green Energy (OSTI)

The titanium alloys that offer properties worthy of consideration for fusion reactors are Ti-6Al-4V, Ti-6Al-2Sn-4Zr-2Mo-Si (Ti-6242S) and Ti-5Al-6Sn-2Zr-1Mo-Si (Ti-5621S). The Ti-6242S and Ti-5621S are being considered because of their high creep resistance at elevated temperatures of 500/sup 0/C. Also, irradiation tests on these alloys have shown irradiation creep properties comparable to 20% cold worked 316 stainless steel. These alloys would be susceptible to slow strain rate embrittlement if sufficient hydrogen concentrations are obtained. Concentrations greater than 250 to 500 wppm hydrogen and temperatures lower than 100 to 150/sup 0/C are approximate threshold conditions for detrimental effects on tensile properties. Indications are that at the elevated temperature - low hydrogen pressure conditions of the reactors, there would be negligible hydrogen embrittlement.

Wille, G.W.; Davis, J.W.

1981-04-01T23:59:59.000Z

388

Status of Testing and Characterization of CMS Alloy 617 and Alloy 230  

Science Conference Proceedings (OSTI)

Status and progress in testing and characterizing CMS Alloy 617 and Alloy 230 tasks in FY06 at ORNL and INL are described. ORNL research has focused on CMS Alloy 617 development and creep and tensile properties of both alloys. In addition to refurbishing facilities to conduct tests, a significant amount of creep and tensile data on Alloy 230, worth several years of research funds and time, has been located and collected from private enterprise. INL research has focused on the creep-fatigue behavior of standard chemistry Alloy 617 base metal and fusion weldments. Creep-fatigue tests have been performed in air, vacuum, and purified Ar environments at 800 and 1000 C. Initial characterization and high-temperature joining work has also been performed on Alloy 230 and CCA Alloy 617 in preparation for creep-fatigue testing.

Ren, Weiju [ORNL; Santella, Michael L [ORNL; Battiste, Rick [ORNL; Terry, Totemeier [Idaho National Laboratory (INL); Denis, Clark [Idaho National Laboratory (INL)

2006-08-01T23:59:59.000Z

389

First high-temperature electronics products survey 2005.  

Science Conference Proceedings (OSTI)

On April 4-5, 2005, a High-Temperature Electronics Products Workshop was held. This workshop engaged a number of governmental and private industry organizations sharing a common interest in the development of commercially available, high-temperature electronics. One of the outcomes of this meeting was an agreement to conduct an industry survey of high-temperature applications. This report covers the basic results of this survey.

Normann, Randy Allen

2006-04-01T23:59:59.000Z

390

Advanced High-Temperature, High-Pressure Transport Reactor Gasification  

Science Conference Proceedings (OSTI)

The U.S. Department of Energy (DOE) National Energy Technology Laboratory Office of Coal and Environmental Systems has as its mission to develop advanced gasification-based technologies for affordable, efficient, zero-emission power generation. These advanced power systems, which are expected to produce near-zero pollutants, are an integral part of DOE's Vision 21 Program. DOE has also been developing advanced gasification systems that lower the capital and operating costs of producing syngas for chemical production. A transport reactor has shown potential to be a low-cost syngas producer compared to other gasification systems since its high-throughput-per-unit cross-sectional area reduces capital costs. This work directly supports the Power Systems Development Facility utilizing the KBR transport reactor located at the Southern Company Services Wilsonville, Alabama, site. Over 2800 hours of operation on 11 different coals ranging from bituminous to lignite along with a petroleum coke has been completed to date in the pilot-scale transport reactor development unit (TRDU) at the Energy & Environmental Research Center (EERC). The EERC has established an extensive database on the operation of these various fuels in both air-blown and oxygen-blown modes utilizing a pilot-scale transport reactor gasifier. This database has been useful in determining the effectiveness of design changes on an advanced transport reactor gasifier and for determining the performance of various feedstocks in a transport reactor. The effects of different fuel types on both gasifier performance and the operation of the hot-gas filter system have been determined. It has been demonstrated that corrected fuel gas heating values ranging from 90 to 130 Btu/scf have been achieved in air-blown mode, while heating values up to 230 Btu/scf on a dry basis have been achieved in oxygen-blown mode. Carbon conversions up to 95% have also been obtained and are highly dependent on the oxygen-coal ratio. Higher-reactivity (low-rank) coals appear to perform better in a transport reactor than the less reactive bituminous coals. Factors that affect TRDU product gas quality appear to be coal type, temperature, and air/coal ratios. Testing with a higher-ash, high-moisture, low-rank coal from the Red Hills Mine of the Mississippi Lignite Mining Company has recently been completed. Testing with the lignite coal generated a fuel gas with acceptable heating value and a high carbon conversion, although some drying of the high-moisture lignite was required before coal-feeding problems were resolved. No ash deposition or bed material agglomeration issues were encountered with this fuel. In order to better understand the coal devolatilization and cracking chemistry occurring in the riser of the transport reactor, gas and solid sampling directly from the riser and the filter outlet has been accomplished. This was done using a baseline Powder River Basin subbituminous coal from the Peabody Energy North Antelope Rochelle Mine near Gillette, Wyoming.

Michael Swanson; Daniel Laudal

2008-03-31T23:59:59.000Z

391

HIGH CREEP-STRENGTH ALLOYS P.J. Maziasz, J.P Shingledecker, R.W. Swindeman, R.L. Klueh and N.D. Evans  

E-Print Network (OSTI)

power plants [1-3]. While such alloys for boiler application must also be construction-code approved resistance in ultra- supercritical (USC) boiler conditions at 700o C and above [1,2]. This new alloy is also one of the candidate alloys being studied by the U.S. USC Boiler Consortium for steam temperatures

392

2nd International Symposium on High-Temperature Metallurgical ...  

Science Conference Proceedings (OSTI)

Aug 2, 2010... with reduced energy consumption and reduced emission of pollutants. ... A Breakthrough Application of Electricity at High Temperature for ...

393

Ionic Solid Oxides for High Temperature Optical Gas Sensing in ...  

Science Conference Proceedings (OSTI)

Presentation Title, Ionic Solid Oxides for High Temperature Optical Gas Sensing in Fossil Fuel Based Power Plants. Author(s), Junhang Dong, Xiling Tang, Kurtis  ...

394

High Temperature Modules and Materials for Thermoelectric Power ...  

Science Conference Proceedings (OSTI)

We fabricated oxide-based thermoelectric modules for high temperature electrical-power generation. Potentials for a development of a thermoelectric generation ...

395

Next Generation High-Temperature Materials - Programmaster.org  

Science Conference Proceedings (OSTI)

Advanced, super high efficiency gas turbine systems will necessarily need to operate in severe conditions that correspond to blade metal temperatures in excess ...

396

Fracturing fluid high-temperature breaker for improving well performance  

Science Conference Proceedings (OSTI)

Oxidative breakers are currently being used in fracturing treatments to reduce polymeric gel damage in high-temperature reservoirs. Dissolved high-temperature oxidative breakers are very reactive at high temperatures (275 to 350 F), typically requiring less than 0.25 lbm/1,000 gal of fluid. Recent introduction of a new nonpersulfate oxidative high-temperature encapsulated breaker (HTEB) provides controlled degradation of the fracturing fluid polymers. Laboratory tests show viscosity reduction and delayed release of active oxidizer breaker. HTEB conductivity data show a two-fold increase in retained permeability at 300 F in a borate-crosslinked fluid system.

McConnell, B.

1994-05-01T23:59:59.000Z

397

BSA 08-04: High Temperature Interfacial Superconductivity  

Cuprate superconductors exhibit relatively high transition temperatures, but their unit cells are complex and large. Localizing a superconducting layer to a small ...

398

High-temperature Erosion Behavior of Aluminide-coated Turbine ...  

Science Conference Proceedings (OSTI)

The high-temperature erosion behavior of an aluminide-coated turbine blade ... The Tensile Property Of A Gas Turbine Engine Fan Blade And Casing Material.

399

Available Technologies: High Temperature Strain Cell for X-ray ...  

High Temperature Strain Cell for X-ray ... Six hexapole infrared lamps focus inside the sample chamber onto a ceramic material sample with a spherical ...

400

Advanced High Temperature Corrosion and Wear Resistant Internal ...  

Science Conference Proceedings (OSTI)

Presentation Title, Advanced High Temperature Corrosion and Wear Resistant Internal Coating for Oil Industry applications. Author(s), William Boardman, Rahul  ...

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Developing a High-Temperature Superconducting Bulk Magnet for ...  

Science Conference Proceedings (OSTI)

In addition to these well-developed technologies, high-critical temperature superconductors that show superconductivity at liquid nitrogen are also prospective ...

402

High-Temperature Reactor for Diffuse Reflectance Infrared ...  

High-Temperature Reactor for Diffuse Reflectance Infrared Fourier-Transform Spectroscopy Note: The technology described above is an early stage ...

403

High Temperature Fatigue Behavior of Laser Shock Peened ...  

Science Conference Proceedings (OSTI)

Presentation Title, High Temperature Fatigue Behavior of Laser Shock Peened IN718Plus Superalloy. Author(s), Vibhor Chaswal, S R Mannava, Dong Qian, ...

404

Liquid Metal, a Heat Transport Fluid for High Temperature Solar ...  

Science Conference Proceedings (OSTI)

The need for high efficiency and direct heat conversion into hydrogen, process heat and energy storage pushes the temperature for solar concentrator systems.

405

Direct Fired Reciprocating Engine and Bottoming High Temperature...  

NLE Websites -- All DOE Office Websites (Extended Search)

exhaust is split between fuel feeds and air feeds to the high temperature fuel cell. NOX reduction can be achieved using an autothermal reformer. By hybridizing the production...

406

High-temperature Material Systems for Energy Conversion and ...  

Science Conference Proceedings (OSTI)

Ionic Solid Oxides for High Temperature Optical Gas Sensing in Fossil Fuel Based Power Plants · Mitigation of Chromium Poisoning in Solid Oxide Fuel Cell

407

High-Temperature Lead-Free Solder Alternatives: Possibilities and ...  

Science Conference Proceedings (OSTI)

The development of high-temperature lead-free solders has become an important issue for both the electronics and automobile industries because of the health ...

408

SLAC National Accelerator Laboratory - High-temperature Superconductor...  

NLE Websites -- All DOE Office Websites (Extended Search)

evidence yet that a puzzling gap in the electronic structures of some high-temperature superconductors could indicate a new phase of matter. Understanding this "pseudogap" has...

409

High Temperature Universal Silicon on Insulator (SOI) Gate Drive  

higher current drive, on-chip regulation capacitors, and more space efficient and robust on-chip layout. ... •Development of high temperature galvanic isolation

410

High-temperature Foam-reinforced Thermal Insulation  

Science Conference Proceedings (OSTI)

Symposium, Advanced Materials for Harsh Environments. Presentation Title, High-temperature Foam-reinforced Thermal Insulation. Author(s), Jacob J. Stiglich, ...

411

MESON CORRELATION FUNCTIONS AT HIGH TEMPERATURES.  

Science Conference Proceedings (OSTI)

We present preliminary results for the correlation- and spectral functions of different meson channels on the lattice. The main focus lies on gaining control over cut-off as well as on the finite-volume effects. Extrapolations of screening masses above the deconfining temperature are guided by the result of the free (T = {infinity}) case on the lattice and in the continuum. We study the quenched non-perturbatively improved Wilson-clover fermion as well as the hypercube fermion action which might show less cut-off effects.

WISSEL, S.; DATTA, S.; KARSCH, F.; LAERMANN, E.; SHCHEREDIN, S.

2005-07-25T23:59:59.000Z

412

High temperature solid oxide fuel development activities  

DOE Green Energy (OSTI)

This paper presents an overview of the Westinghouse tubular SOFC development activities and current program status. Goal is to develop a cell that can operate for 50,000 to 100,000 h. Test results are presented for multiple single cell tests which have now successfully exceeded 40,000 hours of continuous power operation at temperature. Two 25-kW SOFC customer tests units were delivered in 1992; a 20-kW SOFC system is bein manufactured and will be operated by Southern California Edison in 1995. Megawatt class generators are being developed.

Ray, E.R.

1993-11-01T23:59:59.000Z

413

Copper Casting Alloys  

Science Conference Proceedings (OSTI)

Table 8 Compositions, uses, and characteristics of copper alloy castings...operating at moderate-to-high speeds, as in electric motors and appliances. Alloy C93200 is

414

Method for the production of electrodes for lead--acid storage batteries. [drying by inert gas at high temperature  

SciTech Connect

A method for the production of lead--acid storage batteries having a grid of lead alloy filled with active materials consisting of lead oxides, lead powder, sulfuric acid, and water is described. The electrodes are subjected to a jet of an inert gas at a high temperature and velocity for several seconds to dry the surface of the electrodes while leaving the interior thereof moist.

Nikolaou, P.

1978-08-29T23:59:59.000Z

415

Thermodynamics and Transport Phenomena in High Temperature Steam Electrolysis Cells  

DOE Green Energy (OSTI)

Hydrogen can be produced from water splitting with relatively high efficiency using high temperature electrolysis. This technology makes use of solid-oxide cells, running in the electrolysis mode to produce hydrogen from steam, while consuming electricity and high temperature process heat. The overall thermal-to-hydrogen efficiency for high temperature electrolysis can be as high as 50%, which is about double the overall efficiency of conventional low-temperature electrolysis. Current large-scale hydrogen production is based almost exclusively on steam reforming of methane, a method that consumes a precious fossil fuel while emitting carbon dioxide to the atmosphere. An overview of high temperature electrolysis technology will be presented, including basic thermodynamics, experimental methods, heat and mass transfer phenomena, and computational fluid dynamics modeling.

James E. O'Brien

2012-03-01T23:59:59.000Z

416

Processing of Soft Magnetic Alloys in High Magnetic Field  

Science Conference Proceedings (OSTI)

... Magnetic Materials for Use in Energy-efficient Distribution Transformers ... Novel Morphology of Highly Efficient Two-phase Ferrite Cores for Power Systems

417

Characterization of U-7Mo Alloy Microstructure Irradiated to High ...  

Science Conference Proceedings (OSTI)

Abstract Scope, The Reduced Enrichment for Research and Test Reactor ... for use in reactors that currently employ fuels containing highly enriched uranium.

418

Microstructure Control of Ni Base Alloys with High Volume Fraction ...  

Science Conference Proceedings (OSTI)

hypo-stoichiometric composition of Ni3V, formation of "multi- variant structure ... reasons; one is the high TC (1318 K) at its stoichiometric composition [1, 2], and ...

419

High Temperature, Buried Permanent Magnet, Brushless DC Motor  

E-Print Network (OSTI)

A high temperature magnetic bearing system using high temperature permanent magnets from Electron Energy Corporation (EEC) is under development. The system consists of two radial bearings, one thrust bearing, two radial catcher bearings and one motor. The purpose of this research is to develop one of the critical components of the system, namely, the High Temperature Permanent Magnet motor. A novel High Temperature Permanent Magnet (HTPM) Brushless DC(BLDC) motor capable of operating at 1000 degrees F (538 degrees C) is designed. HTPMs developed at Electron Energy Corporation are buried into the rotor. The high temperature motor is designed to produce 5.1kw of power at a top running speed of 20000 rpm. The numerical values of the motor voltage, power and torque output are predicted from calculations of the nonlinear finite element model of the motor. The motor stator is wound, potted, cured and high potential tested at 1000 degrees F. A servo amplifier from Advanced Motion Control is used to drive the high temperature motor. High temperature displacement sensors are set up for sensing the rotor position to form a closed loop motion control. However, the noise problem of the high temperature sensors causes a failure of this approach. An open loop approach is then developed and this approach succeeds in spinning the rotor with the capability of self-starting. The status of the full system assembling is introduced. Some other components of the system are briefly presented.

Zhang, Zhengxin

2010-08-01T23:59:59.000Z

420

HYFIRE: a tokamak/high-temperature electrolysis system  

DOE Green Energy (OSTI)

The HYFIRE studies to date have investigated a number of technical approaches for using the thermal energy produced in a high-temperature Tokamak blanket to provide the electrical and thermal energy required to drive a high-temperature (> 1000/sup 0/C) water electrolysis process. Current emphasis is on two design points, one consistent with electrolyzer peak inlet temperatures of 1400/sup 0/C, which is an extrapolation of present experience, and one consistent with a peak electrolyzer temperature of 1100/sup 0/C. This latter condition is based on current laboratory experience with high-temperature solid electrolyte fuel cells. Our major conclusion to date is that the technical integration of fusion and high-temperature electrolysis appears to be feasible and that overall hydrogen production efficiencies of 50 to 55% seem possible.

Fillo, J.A.; Powell, J.P.; Benenati, R.; Varljen, T.C.; Chi, J.W.H.; Karbowski, J.S.

1981-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Advancing the technology base for high-temperature membranes  

DOE Green Energy (OSTI)

This is the final report of a two-year, Laboratory Directed Research and Development (LDRD) project at the Los Alamos National Laboratory (LANL). This project addresses the major issues confronting the implementation of high-temperature membranes for separations and catalysis. We are pursuing high-temperature membrane systems that can have a large impact for DOE and be industrially relevant. A major obstacle for increased use of membranes is that most applications require the membrane material to withstand temperatures above those acceptable for polymer-based systems. Advances made by this project have helped industry and DOE move toward high-temperature membrane applications to improve overall energy efficiency.

Dye, R.C.; Birdsell, S.A.; Snow, R.C. [and others

1997-10-01T23:59:59.000Z

422

High Temperature Superconductivity in Cuprates: a model  

E-Print Network (OSTI)

A model is proposed such that quasi-particles (electrons or holes) residing in the CuO2 planes of cuprates may interact leading to metallic or superconducting behaviors. The metallic phase is obtained when the quasi-particles are treated as having classical kinetic energies and the superconducting phase occurs when the quasi-particles are taken as extremely relativistic objects. The interaction between both kinds of particles is provided by a force dependent-on-velocity. In the case of the superconducting behavior, the motion of apical oxygen ions provides the glue to establish the Cooper pair. The model furnishes explicit relations for the Fermi velocity, the perpendicular and the in-plane coherence lengths, the zero-temperature energy gap, the critical current density, the critical parallel and perpendicular magnetic fields. All these mentioned quantities are expressed in terms of fundamental physical constants as: charge and mass of the electron, light velocity in vacuum, Planck constant, electric permittivity of the vacuum. Numerical evaluation of these quantities show that their values are close those found for the superconducting YBaCuO, leading to think the model as being a possible scenario to explain superconductivity in cuprates.

P. R. Silva

2010-07-16T23:59:59.000Z

423

Advanced High Temperature Reactor Neutronic Core Design  

Science Conference Proceedings (OSTI)

The AHTR is a 3400 MW(t) FHR class reactor design concept intended to serve as a central generating station type power plant. While significant technology development and demonstration remains, the basic design concept appears sound and tolerant of much of the remaining performance uncertainty. No fundamental impediments have been identified that would prevent widespread deployment of the concept. This paper focuses on the preliminary neutronic design studies performed at ORNL during the fiscal year 2011. After a brief presentation of the AHTR design concept, the paper summarizes several neutronic studies performed at ORNL during 2011. An optimization study for the AHTR core is first presented. The temperature and void coefficients of reactivity are then analyzed for a few configurations of interest. A discussion of the limiting factors due to the fast neutron fluence follows. The neutronic studies conclude with a discussion of the control and shutdown options. The studies presented confirm that sound neutronic alternatives exist for the design of the AHTR to maintain full passive safety features and reasonable operation conditions.

Ilas, Dan [ORNL; Holcomb, David Eugene [ORNL; Varma, Venugopal Koikal [ORNL

2012-01-01T23:59:59.000Z

424

Apparatus for accurately measuring high temperatures  

DOE Patents (OSTI)

The present invention is a thermometer used for measuring furnace temperaes in the range of about 1800.degree. to 2700.degree. C. The thermometer comprises a broadband multicolor thermal radiation sensor positioned to be in optical alignment with the end of a blackbody sight tube extending into the furnace. A valve-shutter arrangement is positioned between the radiation sensor and the sight tube and a chamber for containing a charge of high pressure gas is positioned between the valve-shutter arrangement and the radiation sensor. A momentary opening of the valve shutter arrangement allows a pulse of the high gas to purge the sight tube of air-borne thermal radiation contaminants which permits the radiation sensor to accurately measure the thermal radiation emanating from the end of the sight tube.

Smith, Douglas D. (Knoxville, TN)

1985-01-01T23:59:59.000Z

425

Description of a high temperature downhole fluid sampler  

DOE Green Energy (OSTI)

Downhole fluid samplers have been used for years with limited success in high temperature geothermal wells. This paper discusses the development and operating principles of a high temperature downhole fluid sampler, reliable at obtaining samples at temperatures of up to 350/sup 0/C. The sampler was used successfully for recovering a brine sample from a depth of 10,200 ft in the Salton Sea Scientific Drilling Project well.

Solbau, R.; Weres, O.; Hansen, L.; Dudak, B.

1986-05-01T23:59:59.000Z

426

Effect of High Temperature Cycling on Conductor Systems  

Science Conference Proceedings (OSTI)

One of the alternatives for increasing power flow on an existing transmission line is to raise the operating temperature of its conductor. The effects of high operating temperature on the conductor, however, include loss in conductor strength and reduction in conductor clearance to ground. The high temperature also affects the short- and long-term performance of the conductor connections and conductor accessories. All of these effects must be assessed for an overhead line to operate safely and reliably a...

2007-12-18T23:59:59.000Z

427

Hydrogen production from high temperature electrolysis and fusion reactor  

SciTech Connect

Production of hydrogen from high temperature electrolysis of steam coupled with a fusion reactor is studied. The process includes three major components: the fusion reactor, the high temperature electrolyzer and the power conversion cycle each of which is discussed in the paper. Detailed process design and analysis of the system is examined. A parametric study on the effect of process efficiency is presented.

Dang, V.D.; Steinberg, J.F.; Issacs, H.S.; Lazareth, O.; Powell, J.R.; Salzano, F.J.

1978-01-01T23:59:59.000Z

428

High Permeability Ternary Palladium Alloy Membranes with Improved Sulfur and Halide Tolerances  

DOE Green Energy (OSTI)

The project team consisting of Southwest Research Institute{reg_sign} (SwRI{reg_sign}), Georgia Institute of Technology (GT), the Colorado School of Mines (CSM), TDA Research, and IdaTech LLC was focused on developing a robust, poison-tolerant, hydrogen selective free standing membrane to produce clean hydrogen. The project completed on schedule and on budget with SwRI, GT, CSM, TDA and IdaTech all operating independently and concurrently. GT has developed a robust platform for performing extensive DFT calculations for H in bulk palladium (Pd), binary alloys, and ternary alloys of Pd. Binary alloys investigated included Pd96M4 where M = Li, Na, Mg, Al, Si, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Y, Zr, Nb, Mo, Tc, Ru, Rh, Ag, Cd, In, Sn, Sb, Te, Hf, Ta, W, Re, Os, Ir, Pt, Au, Tl, Pb, Bi, Ce, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu. They have also performed a series of calculations on Pd{sub 70}Cu{sub 26}Ag{sub 4}, Pd{sub 70}Cu{sub 26}Au{sub 4}, Pd{sub 70}Cu{sub 26}Ni{sub 4}, Pd{sub 70}Cu{sub 26}Pt{sub 4}, and Pd{sub 70}Cu{sub 26}Y{sub 4}. SwRI deposited and released over 160 foils of binary and ternary Pd alloys. There was considerable work on characterizing and improving the durability of the deposited foils using new alloy compositions, post annealing and ion bombardment. The 10 and 25 {micro}m thick films were sent to CSM, TDA and IdaTech for characterization and permeation testing. CSM conducted over 60 pure gas permeation tests with SwRI binary and ternary alloy membranes. To date the PdAu and PdAuPt membranes have exhibited the best performance at temperatures in the range of 423-773 C and their performance correlates well with the predictions from GT. TDA completed testing under the Department of Energy (DOE) WGS conditions on over 16 membranes. Of particular interest are the PdAuPt alloys that exhibited only a 20% drop in flux when sulfur was added to the gas mixture and the flux was completely recovered when the sulfur flow was stopped. IdaTech tested binary and ternary membranes on a simulated flue gas stream and experienced significant difficulty in mounting and testing the sputter deposited membranes. IdaTech was able to successfully test PdAu and PdAuPt membranes and saw similar sulfur tolerance to what TDA found. The Program met all the deliverables on schedule and on budget. Over ten presentations at national and international conferences were made, four papers were published (two in progress) in technical journals, and three students (2 at GT and 1 at CSM) completed their doctorates using results generated during the course of the program. The three major findings of program were; (1) the DFT modeling was verified as a predictive tool for the permeability of Pd based ternary alloys, (2) while magnetron sputtering is useful in precisely fabricating binary and ternary alloys, the mechanical durability of membranes fabricated using this technique are inferior compared to cold rolled membranes and this preparation method is currently not ready for industrial environments, (3) based on both modeling and experimental verification in pure gas and mixed gas environments PdAu and PdAuPt alloys were found to have the combination of the highest permeability and tolerance to sulfur.

K. Coulter

2010-12-31T23:59:59.000Z

429

Sulfur Tolerant Pd/Cu and Pd/Au Alloy Membranes for H2 Separation with High Pressure CO2 for Sequestration  

DOE Green Energy (OSTI)

The effect of H{sub 2}S poisoning on Pd, Pd/Cu, and Pd/Au alloy composite membranes prepared by the electroless deposition method on porous Inconel supports was investigated to provide a fundamental understanding of the durability and preparation of sulfur tolerant membranes. X-ray photoelectron spectroscopy (XPS) studies showed that the exposure of pure Pd to 50 ppm H{sub 2}S/H{sub 2} mixtures caused bulk sulfide formation at lower temperatures and surface sulfide formation at higher temperatures. Lower temperatures, longer exposure times, and higher H{sub 2}S concentrations resulted in a higher degree of sulfidation. In a Pd membrane, the bulk sulfide formation caused a drastic irrecoverable H{sub 2} permeance decline and an irreparable loss in selectivity. Pd/Cu and Pd/Au alloy membranes exhibited permeance declines due to surface sulfide formation upon exposure to 50 ppm H{sub 2}S/H{sub 2} gas mixtures. However in contrast to the pure Pd membrane, the permeances of the Pd/Cu and Pd/Au alloy membranes were mostly recovered in pure H{sub 2} and the selectivity of the Pd alloy layers remained essentially intact throughout the characterization in H{sub 2}, He and H{sub 2}S/H{sub 2} mixtures which lasted several thousand hours. The amount of irreversible sulfur poisoning decreased with increasing temperature due to the exothermicity of H{sub 2}S adsorption. Longer exposure times increased the amount of irreversible poisoning of the Pd/Cu membrane but not the Pd/Au membrane. Pd/Au coupon studies of the galvanic displacement method showed that higher Au{sup 3+} concentrations, lower pH values, higher bath temperatures and stirring the bath at a rate of 200 rpm yielded faster displacement rates, more uniform depositions, and a higher Au content within the layers. While 400 C was found to be sufficient to form a Pd/Au alloy on the surface, high temperature X-ray diffraction (HTXRD) studies showed that even after annealing between 500-600 C, the Pd/Cu alloys could have part or all of the surface in the less sulfur resistant {beta} phase.

Yi Hua Ma; Natalie Pomerantz; Chao-Huang Chen

2008-09-30T23:59:59.000Z

430

Short-Term Solubility of Eight Alloys Circulating in Mercury at Room Temperature  

E-Print Network (OSTI)

on the alloy. To make the posttest mass measurements, those samples that were compatible with nitric acid were briefly rinsed in 8N nitric acid, washed in water and alcohol, and then dried. This was not possible in Table 2. Although the copper and aluminum experienced considerable mass loss due to dissolution

McDonald, Kirk

431

TEM Study on Microstructure Behavior of Alloy 718 After Long Time ...  

Science Conference Proceedings (OSTI)

Besides 6 phase formation, y” , y' and 6 coarsening and solution were observed. The softening mechanisms of. Alloy 718 at high temperatures have been ...

432

Corrosion of Metals and Alloys in High Radiation Fields  

DOE Green Energy (OSTI)

This paper rationalizes the impact of high radiation fields on corrosion, hydrogen embrittlement and corrosion fatigue and relates that impact to radiation induced changes in chemical reactivity, hydrogen fugacity, and surface chemistry.

Sindelar, R.L.

1999-11-19T23:59:59.000Z

433

Heat treatment of NiCrFe alloy to optimize resistance to intergrannular stress corrosion  

DOE Patents (OSTI)

A process of producing a NiCrFe alloy having a high resistance to stress corrosion cracking comprising heating a NiCrFe alloy to a temperature sufficient to enable the carbon present in the alloy body in the form of carbide deposits to enter into solution, rapidly cool the alloy body, and heat the cooled body to a temperature between 1100.degree. to 1500.degree. F. for about 1 to 30 hours.

Steeves, Arthur F. (Schenectady, NY); Bibb, Albert E. (Clifton Park, NY)

1984-01-01T23:59:59.000Z

434

Fracture and fatigue properties of Mo-Mo{sub 3}Si-Mo{sub 5}SiB{sub 2} refractory intermetallic alloys at ambient to elevated temperatures (25-1300 degrees Centigrade)  

Science Conference Proceedings (OSTI)

The need for structural materials with high-temperature strength and oxidation resistance coupled with adequate lower-temperature toughness for potential use at temperatures above {approx} 1000 degrees C has remained a persistent challenge in materials science. In this work, one promising class of intermetallic alloys is examined, namely boron-containing molybdenum silicides, with compositions in the range Mo (bal), 12-17 at. percentSi, 8.5 at. percentB, processed using both ingot (I/M) and powder (P/M) metallurgy methods. Specifically, the oxidation (''pesting''), fracture toughness and fatigue-crack propagation resistance of four such alloys, which consisted of {approx}21 to 38 vol. percent a-Mo phase in an intermetallic matrix of Mo3Si and Mo5SiB2 (T2), were characterized at temperatures between 25 degrees and 1300 degrees C. The boron additions were found to confer superior ''pest'' resistance (at 400 degrees to 900 degrees C) as compared to unmodified molybdenum silicides, such as Mo5Si3. Moreover , although the fracture and fatigue properties of the finer-scale P/M alloys were only marginally better than those of MoSi2, for the I/M processed microstructures with coarse distributions of the a-Mo phase, fracture toughness properties were far superior, rising from values above 7 MPa sqrt m at ambient temperatures to almost 12 MPa sqrt m at 1300 degrees C.

Choe, Heeman; Schneibel, J.H.; Ritchie, R.O.

2002-08-01T23:59:59.000Z

435

Electrodeposition of cobalt and cobalt-aluminum alloys from a room temperature chloroaluminate molten salt  

Science Conference Proceedings (OSTI)

The electrodeposition of magnetic cobalt-aluminum alloys was investigated in the Lewis acidic aluminum chloride-1-methyl-3-ethylimidazolium chloride [60.0--40.0 mole percent (m/o)] molten salt containing electrogenerated Co(II) at 25 C. rotating disk electrode voltammetry indicated that it is possible to produce alloy deposits containing up to 62 atomic (a/o) aluminum at potentials positive of that for the bulk deposition of aluminum. The onset of the underpotential-driven aluminum codeposition process occurred at around 0.40 V vs. the Al/Al(III) couple in a 5.00 mmol/liter Co(II) solution but decreased as the Co(II) concentration increased. The Co-Al alloy composition displayed an inverse dependence on the Co(II) concentration but tended to become independent of concentration as the potential was decreased to 0 V. A rotating ring-disk electrode voltammetry technique was developed to analyze the composition and structure of the Co-Al alloy deposits. This technique takes advantage of the fact that the mass-transport-limited reduction of cobalt(II) occurs at potentials considerably more positive than that at which aluminum codeposition occurs. Scanning electron microscopy and energy dispersive X-ray analysis of bulk electrodeposits revealed that deposit morphology depends strongly upon aluminum content/deposition potential; deposits produced at 0.40 V from 50.0 mmol/liter Co(II) solutions consisted of 10 to 20 {micro}m diam multifaceted nodules of pure hcp cobalt, whereas those obtained at 0.20 V were dense and fine grained, containing about 4 a/o Al. Deposits produced at 0 V had the visual appearance of a loosely adherent black powder. X-ray diffraction measurements revealed a lattice expansion and a decrease in grain size as the hcp cobalt was alloyed with increasing amounts of aluminum.

Mitchell, J.A.; Pitner, W.R.; Hussey, C.L. [Univ. of Mississippi, University, MS (United States). Dept. of Chemistry; Stafford, G.R. [National Inst. of Standards and Technology, Gaithersburg, MD (United States). Materials Science and Engineering Lab.

1996-11-01T23:59:59.000Z

436

DOE Hydrogen Analysis Repository: High Temperature Electrolysis (HTE)  

NLE Websites -- All DOE Office Websites (Extended Search)

High Temperature Electrolysis (HTE) High Temperature Electrolysis (HTE) Project Summary Full Title: High Temperature Electrolysis (HTE) Project ID: 159 Principal Investigator: Steve Herring Brief Description: A three-dimensional computational fluid dynamics (CFD) model was created to model high-temperature steam electrolysis in a planar solid oxide electrolysis cell (SOEC). A solid-oxide fuel cell model adds the electrochemical reactions and loss mechanisms and computation of the electric field throughout the cell. Keywords: Solid oxide fuel cell; solid oxide elctrolysis cell; nuclear; model Purpose Assess the performance of solid-oxide cells operating in the steam electrolysis mode for hydrogen production over a temperature range of 800 to 900ºC. Performer Principal Investigator: Steve Herring

437

Method And Apparatus For Evaluatin Of High Temperature Superconductors  

DOE Patents (OSTI)

A technique for evaluation of high-T.sub.c superconducting films and single crystals is based on measurement of temperature dependence of differential optical reflectivity of high-T.sub.c materials. In the claimed method, specific parameters of the superconducting transition such as the critical temperature, anisotropy of the differential optical reflectivity response, and the part of the optical losses related to sample quality are measured. The apparatus for performing this technique includes pump and probe sources, cooling means for sweeping sample temperature across the critical temperature and polarization controller for controlling a state of polarization of a probe light beam.

Fishman, Ilya M. (Palo Alto, CA); Kino, Gordon S. (Stanford, CA)

1996-11-12T23:59:59.000Z

438

High Temperature and Pressure Steam-H2 Interaction with Candidate Advanced LWR Fuel Claddings  

SciTech Connect

This report summarizes the work completed to evaluate cladding materials that could serve as improvements to Zircaloy in terms of accident tolerance. This testing involved oxidation resistance to steam or H{sub 2}-50% steam environments at 800-1350 C at 1-20 bar for short times. A selection of conventional alloys, SiC-based ceramics and model alloys were used to explore a wide range of materials options and provide guidance for future materials development work. Typically, the SiC-based ceramic materials, alumina-forming alloys and Fe-Cr alloys with {ge}25% Cr showed the best potential for oxidation resistance at {ge}1200 C. At 1350 C, FeCrAl alloys and SiC remained oxidation resistant in steam. Conventional austenitic steels do not have sufficient oxidation resistance with only {approx}18Cr-10Ni. Higher alloyed type 310 stainless steel is protective but Ni is not a desirable alloy addition for this application and high Cr contents raise concern about {alpha}{prime} formation. Higher pressures (up to 20.7 bar) and H{sub 2} additions appeared to have a limited effect on the oxidation behavior of the most oxidation resistant alloys but higher pressures accelerated the maximum metal loss for less oxidation resistant steels and less metal loss was observed in a H{sub 2}-50%H{sub 2}O environment at 10.3 bar. As some of the results regarding low-alloyed FeCrAl and Fe-Cr alloys were unexpected, further work is needed to fundamentally understand the minimum Cr and Al alloy contents needed for protective behavior in these environments in order to assist in alloy selection and guide alloy development.

Pint, Bruce A [ORNL

2012-08-01T23:59:59.000Z

439

Real Time Synchrotron Radiography of High Temperature High ...  

Science Conference Proceedings (OSTI)

... Magnetic Composite Materials · X-Ray Studies of Structural Effects Induced by Pulsed (30 Tesla), High Magnetic Fields at the Advanced Photon Source ...

440

Low-Temperature Solution-Phase Synthesis of NiAu Alloy Nanoparticles via Butyllithium Reduction: Influences of Synthesis Details and Application as the Precursor to Active Au0NiO/Si02 Catalysts Through Proper Pretreatments  

SciTech Connect

Bimetallic nanoparticles (NPs) have wide applications in electronics, photonics, and catalysis. However, it is particularly challenging to synthesize size-controllable alloy nanoparticles (e.g., NiAu) with bulk immiscible metals as the components. Here we report the synthesis of isolable NiAu alloy nanoparticles with tunable and relatively uniform sizes via a coreduction method employing butyllithium as the reducing agent and trioctylphosphine as the protecting agent. The influences of synthesis conditions (e.g., protecting agent, aging temperature, and the solvent used to wash the product) were investigated, and the synthesis mechanism was preliminarily surveyed. The NiAu alloy nanoparticles obtained were then used as the precursor to prepare an Au-NiO/SiO2 catalyst highly active in low-temperature CO oxidation, and the effects of pretreatment details and catalyst compositions on catalytic activity were studied. Relevant characterization employing XRD, TEM, UV-vis, TG/DTG, and FT-IR was conducted. In addition, the importance of the current synthesis of NiAu alloy NPs and the contribution of the catalyst design were discussed in the context of the literature.

Zhou, Shenghu [ORNL; Ma, Zhen [ORNL; Yin, Hongfeng [ORNL; Wu, Zili [ORNL; Eichhorn, Bryan [University of Maryland; Overbury, Steven {Steve} H [ORNL; Dai, Sheng [ORNL

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Method for Synthesizing Extremeley High Temperature Melting Materials  

DOE Patents (OSTI)

The invention relates to a method of synthesizing high-temperature melting materials. More specifically the invention relates to a containerless method of synthesizing very high temperature melting materials such as borides, carbides and transition-metal, lanthanide and actinide oxides, using an Aerodynamic Levitator and a laser. The object of the invention is to provide a method for synthesizing extremely high-temperature melting materials that are otherwise difficult to produce, without the use of containers, allowing the manipulation of the phase (amorphous/crystalline/metastable) and permitting changes of the environment such as different gaseous compositions.

Saboungi, Marie-Louise and Glorieux, Benoit

2005-11-22T23:59:59.000Z

442

Goa, India Permeability of Charnokite Rock at High Temperatures  

E-Print Network (OSTI)

ABSTRACT: Permeability at high temperature is a very important parameter to be considered for designing underground high level nuclear waste repository (HLW) in rock mass. The surrounding rock mass is exposed to heat radiated by HLW when it is buried underground and development or extension of micro-cracks takes place in the host rock due to rise in temperature. Keeping this in view, the permeability study was conducted for Charnokite rock at high temperatures in the range from room temperature, 30 to 200 o C. The cylindrical rock samples of 36mm diameter and 150mm in length were used as per the required size for the equipment permeameter, TEMCO, USA. Total thirty rock samples were tested at various temperatures using nitrogen gas as fluid. The permeability tests were conducted at confining pressure of around 4MPa in order to simulate the horizontal in situ stress conditions in Charnokite rock at the depth of 400m for construction of HLW repository. 1

R. D. Dwivedi; R. K. Goel; A. Swarup; V. V. R. Prasad; R. K. Bajpai; P. K. Narayan; V. Arumugam

2008-01-01T23:59:59.000Z

443

Liquid Fuel Production from Biomass via High Temperature Steam Electrolysis  

DOE Green Energy (OSTI)

A process model of syngas production using high temperature electrolysis and biomass gasification is presented. Process heat from the biomass gasifier is used to heat steam for the hydrogen production via the high temperature steam electrolysis process. Hydrogen from electrolysis allows a high utilization of the biomass carbon for syngas production. Oxygen produced form the electrolysis process is used to control the oxidation rate in the oxygen-fed biomass gasifier. Based on the gasifier temperature, 94% to 95% of the carbon in the biomass becomes carbon monoxide in the syngas (carbon monoxide and hydrogen). Assuming the thermal efficiency of the power cycle for electricity generation is 50%, (as expected from GEN IV nuclear reactors), the syngas production efficiency ranges from 70% to 73% as the gasifier temperature decreases from 1900 K to 1500 K. Parametric studies of system pressure, biomass moisture content and low temperature alkaline electrolysis are also presented.

Grant L. Hawkes; Michael G. McKellar

2009-11-01T23:59:59.000Z

444

VANADIUM ALLOYS  

DOE Patents (OSTI)

This patent deals with vanadium based ternary alloys useful as fuel element jackets. According to the invention the ternary vanadium alloys, prepared in an arc furnace, contain from 2.5 to 15% by weight titanium and from 0.5 to 10% by weight niobium. Characteristics of these alloys are good thermal conductivity, low neutron capture cross section, good corrosion resistance, good welding and fabricating properties, low expansion coefficient, and high strength.

Smith, K.F.; Van Thyne, R.J.

1959-05-12T23:59:59.000Z

445

Shape memory effect associated with a deformation at a temperature just below A[sub S] in a Fe-Mn-Cr-Si-Ni shape memory alloy  

SciTech Connect

The shape memory effect of Fe-Mn based shape memory alloys is due to the formation of stress-induced [var epsilon]-martensite by deformation and to its reversion by heating over A[sub f], which permit it to recover a part of the original shape. The shape memory effect is directly associated with the [gamma][yields][var epsilon] transformation. For this reason, the authors have established the best conditions to induce the [var epsilon]-martensite inside an austenitic matrix: the deformation must take place at a temperature close to the M[sub s]. It has been established that a deformation made at a higher temperature degrades the shape memory effect. The purpose of this paper is to evaluate the shape memory effect in the case of a deformation applied at a relatively high temperature (just below A[sub s]) on samples containing a high volume fraction of [var epsilon]-martensite before the deformation. It is shown that an other mechanism of shape memory effect occurs in these conditions and allows to reach an interesting shape memory effect ([approximately]2%).

Federzoni, L.; Guenin, G. (G.E.M.P.P.M., Villeurbanne (France))

1994-07-01T23:59:59.000Z

446

HIGH TEMPERATURE THERMAL AND STRUCTURAL MATERIAL PROPERTIES FOR METALS USED IN LWR VESSELS  

Science Conference Proceedings (OSTI)

Because of the impact that melt relocation and vessel failure may have on subsequent progression and associated consequences of a Light Water Reactor (LWR) accident, it is important to accurately predict heating and relocation of materials within the reactor vessel, heat transfer to and from the reactor vessel, and the potential for failure of the vessel and structures within it. Accurate predictions of such phenomena require high temperature thermal and structural properties. However, a review of vessel and structural steel material properties used in severe accident analysis codes reveals that the required high temperature material properties are extrapolated with little, if any, data above 1000 K. To reduce uncertainties in predictions relying upon extrapolated high temperature data, Idaho National Laboratory (INL) obtained high data for two metals used in LWR vessels: SA 533 Grade B, Class 1 (SA533B1) low alloy steel, which is used to fabricate most US LWR reactor vessels; and Type 304 Stainless Steel SS304, which is used in LWR vessel piping, penetration tubes, and internal structures. This paper summarizes the new data, and compares it to existing data.

J.L. Rempe; D.L. Knudson; J. E. Daw; J. C. Crepeau

2008-06-01T23:59:59.000Z

447

High-temperature seal development for the share receiver  

DOE Green Energy (OSTI)

The development and experimental demonstration of a high-temperature seal for the SHARE ceramic dome cavity receiver is reported. The mechanical contact seal which was tested on one-foot diameter silicon carbide ceramic dome hardware at pressure differentials to four atmospheres and dome temperatures to 2200/sup 0/F (1200/sup 0/C) showed negligible leakage at expected receiver operating conditions.

Jarvinen, P. O.

1979-01-01T23:59:59.000Z

448

30vol%SiC at Ultra-high Temperatures  

Science Conference Proceedings (OSTI)

Presentation Title, SiC-depletion in ZrB2-30vol%SiC at Ultra-high Temperatures. Author(s), K N Shugart, E. J. Opila. On-Site Speaker (Planned), K N Shugart.

449

High temperature solid electrolyte fuel cell configurations and interconnections  

DOE Patents (OSTI)

High temperature fuel cell configurations and interconnections are made including annular cells having a solid electrolyte sandwiched between thin film electrodes. The cells are electrically interconnected along an elongated axial outer surface.

Isenberg, Arnold O. (Forest Hills, PA)

1984-01-01T23:59:59.000Z

450

Enabling high-temperature nanophotonics for energy applications  

E-Print Network (OSTI)

The nascent field of high-temperature nanophotonics could potentially enable many important solid-state energy conversion applications, such as thermophotovoltaic energy generation, selective solar absorption, and selective ...

Yeng, YiXiang

451

DEVELOPMENT OF HIGH TEMPERATURE ULTRASONIC TRANSDUCER FOR STRUCTURAL HEALTH MONITORING  

Science Conference Proceedings (OSTI)

Structural health monitoring (SHM) techniques are needed to maintain the reliability of aging power plants for long term operation. The high temperature transducers are necessary to realize SHM (monitor wall thickness of the pipings

A. Baba; C. T. Searfass; B. R. Tittmann

2011-01-01T23:59:59.000Z

452

Apparatus for preventing high temperatures in a glazed solar collector  

DOE Patents (OSTI)

Venting the glazing (i.e., transparent cover) of a solar collector can be used to prevent the collector's absorber surface from reaching too high a temperature.

Buckley, Bruce S. (410 Memorial Dr., #154, Cambridge, MA 02139)

1979-01-01T23:59:59.000Z

453

Electronic properties of doped Mott insulators and high temperature superconductors  

E-Print Network (OSTI)

High-temperature superconducting cuprates, which are the quintessential example of a strongly correlated system and the most extensively studied materials after semiconductors, spurred the development in the fields of ...

Ribeiro, Tiago Castro

2005-01-01T23:59:59.000Z

454

Comparative Assessment of Direct Drive High Temperature Superconductin...  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy, LLC. Contract No. DE-AC36-08GO28308 Comparative Assessment of Direct Drive High Temperature Superconducting Generators in Multi-Megawatt Class Wind Turbines B....

455

Stability and quench protection of high-temperature superconductors  

E-Print Network (OSTI)

In the design and operation of a superconducting magnet, stability and protection are two key issues that determine the magnet's reliability and safe operation. Although the high-temperature superconductor (HTS) is considered ...

Ang, Ing Chea

2006-01-01T23:59:59.000Z

456

Toward material-specific simulations of high temperature superconductivity  

Science Conference Proceedings (OSTI)

High temperature superconductors could potentially revolutionize the use and transmission of electric power. This along with intriguing scientific questions have motivated an enormous research effort over the past twenty years, since the discovery of ...

Thomas C. Schulthess

2006-11-01T23:59:59.000Z

457

HALLIBURTON SPERRY-SUN DOE HIGH TEMPERATURE LWD PROJECT  

SciTech Connect

The objective of this project was to build a high temperature, cost-effective, logging while drilling (HT-LWD) system with the ability to operate at 175 C with more than 100 hours mean time between failures (MTBF). Such a commercial real-time formation evaluation (FE) system would help operators to drill and produce hydrocarbon resources from moderately deep, hot reservoirs which otherwise might be uneconomic to drill. The project plan was to combine the existing Sperry-Sun high temperature directional and gamma logging system with lower temperature FE sensors which were upgraded to higher temperature operation as part of the project. The project was to be completed in two phases. Phase I included the development of the HT system, building two complete systems, demonstrating operational capability at 175 C and survivability at 200 C in the laboratory, and successfully testing the system in two low temperature field tests. Phase II was to test the system in a well with a bottom hole temperature of 175 C. The high temperature FE sensors developed as part of this project include gamma ray (DGR), resistivity (EWR-Phase 4), neutron (CTN), and density (SLD). The existing high temperature pulser and telemetry system was upgraded to accommodate the data and bandwidth requirements of the additional sensors. Environmental and lifetime testing of system components and modules indicates that system life and reliability goals will be substantially exceeded. The system has performed well in domestic and international high temperature wells (to 175 C). In addition to the sensor modules specified in the project contract, Sperry has now upgraded other system components to higher temperature as well. These include a LWD sonic sensor (BAT), pressure while drilling sensor (PWD), and a more powerful central system controller (CIM).

Ronald L. Spross

2005-03-15T23:59:59.000Z

458

Development of Brazing Technology for Use in High- Temperature Gas Separation Equipment  

DOE Green Energy (OSTI)

The development of high-temperature electrochemical devices such as oxygen and hydrogen separators, fuel gas reformers, solid oxide fuel cells, and chemical sensors is part of a rapidly expanding segment of the solid state technology market. These devices employ an ionic conducting ceramic as the active membrane that establishes the electrochemical potential of the device, either under voltage (i.e. to carry out gas separation) or under chemical gradient (to develop an electrical potential and thereby generate electrical power). Because the device operates under an ionic gradient that develops across the electrolyte, hermiticity across this layer is paramount. That is, not only must this thin ceramic membrane be dense with no interconnected porosity, but it must be connected to the rest of the device, typically constructed from a heat resistant alloy, with a high-temperature, gas-tight seal. A significant engineering challenge in fabricating these devices is how to effectively join the thin electrochemically active membrane to the metallic body of the device such that the resulting seal is hermetic, rugged, and stable during continuous high temperature operation. Active metal brazing is the typical method of joining ceramic and metal engineering components. It employs a braze alloy that contains one or more reactive elements, often titanium, which will chemically reduce the ceramic faying surface and greatly improve its wetting behavior and adherence with the braze. However, recent studies of these brazes for potential use in fabricating high-temperature electrochemical devices revealed problems with interfacial oxidation and subsequent joint failure [1,2]. Specifically, it was found that the introduction of the ceramic electrolyte and/or heat resistant metal substrate dramatically affects the inherent oxidation behavior of the braze, often in a deleterious manner. These conclusions pointed to the need for an oxidation resistant, high-temperature ceramic-to-metal braze and consequently lead to the development of the novel reactive air brazing (RAB) concept. The goal in RAB is to reactively modify one or both oxide faying surfaces with an oxide compound dissolved in a molten noble metal alloy such that the newly formed surface is readily wetted by the remaining liquid filler material. In many respects, this concept is similar to active metal brazing, except that joining can be conducted in air and the final joint will be resistant to oxidation at high temperature. Potentially, there are a number of metal oxide-noble metal systems that can be considered for RAB, including Ag-CuO, Ag-V2O5, and Pt-Nb2O5. Our current interest is in determining whether the Ag-CuO system is suitable for air brazing functional ceramic-to-metal joints such as those needed in practical electrochemical devices. In a series of studies, the wetting behavior of the Ag-CuO braze was investigated with respect to a number of potential hydrogen separation, oxygen separation, and fuel cell electrolyte membrane materials and heat resistant metal systems, including: alumina, (La0.6Sr0.4)(Co0.2Fe0.8)O3, (La0.8Sr0.2)FeO3, YSZ, fecralloy, and Crofer-22APU. Selected findings from these studies as well as from our work on joint strength and durability during high-temperature exposure testing will be discussed.

Weil, K.S.; Hardy, J.S.; Kim, J.Y.

2003-04-23T23:59:59.000Z

459

Microstructure and Mechanical Properties of 3003 Aluminum Alloy ...  

Science Conference Proceedings (OSTI)

... reason of property improvement, especially high temperature performance. ... High Strength Aluminum Brazing Sheets for Condenser Fins of Automotive ... predictions for the phase formation in a wide range of commercial aluminum alloys.

460

Vibration Combined High Temperature Cycle Tests for Capacitive MEMS Accelerometers  

E-Print Network (OSTI)

In this paper vibration combined high temperature cycle tests for packaged capacitive SOI-MEMS accelerometers are presented. The aim of these tests is to provide useful Design for Reliability information for MEMS designers. A high temperature test chamber and a chopper-stabilized read-out circuitry were designed and realized at BME - DED. Twenty thermal cycles of combined Temperature Cycle Test and Fatigue Vibration Test has been carried out on 5 samples. Statistical evaluation of the test results showed that degradation has started in 3 out of the 5 samples.

Szucs, Z; Hodossy, S; Rencz, M; Poppe, A

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "high temperature alloys" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Vibration Combined High Temperature Cycle Tests for Capacitive MEMS Accelerometers  

E-Print Network (OSTI)

In this paper vibration combined high temperature cycle tests for packaged capacitive SOI-MEMS accelerometers are presented. The aim of these tests is to provide useful Design for Reliability information for MEMS designers. A high temperature test chamber and a chopper-stabilized read-out circuitry were designed and realized at BME - DED. Twenty thermal cycles of combined Temperature Cycle Test and Fatigue Vibration Test has been carried out on 5 samples. Statistical evaluation of the test results showed that degradation has started in 3 out of the 5 samples.

Z. Szucs; G. Nagy; S. Hodossy; M. Rencz; A. Poppe

2008-01-07T23:59:59.000Z

462

Instrument Series: Microscopy Ultra-High Vacuum, Low- Temperature Scanning  

NLE Websites -- All DOE Office Websites (Extended Search)

Low- Low- Temperature Scanning Probe Microscope EMSL's ultra-high vacuum, low-temperature scanning probe microscope instrument, or UHV LT SPM, is the preeminent system dedicated to surface chemistry and physics at low temperatures down to 5 K. Operating at low temperatures provides high mechanical stability, superior vacuum conditions, and negligible drift for long-term experiments. With thermal diffusion being entirely suppressed, stable imaging becomes possible even for weakly bound species. The system is primarily used for probing single-site chemical reactivity, while the combination with a hyperthermal molecular beam allows the study of important chemical processes at energies corresponding to the operational temperatures well beyond typical UHV studies. The LT SPM provides

463

Infrared Imaging of Temperature Distribution in a High Temperature X-Ray Diffraction Furnace  

Science Conference Proceedings (OSTI)

High Temperature X-ray Diffraction (HTXRD) is a very powerful tool for studies of reaction kinetics, phase transformations, and lattice thermal expansion of advanced materials. Accurate temperature measurement is a critical part of the technique. Traditionally, thermocouples, thermistors, and optical pyrometers have been used for temperature control and measurement and temperature could only be measured at a single point. Infrared imaging was utilized in this study to characterize the thermal gradients resulting from various sample and furnace configurations in a commercial strip heater furnace. Furnace configurations include a metallic strip heater, with and without a secondary surround heater, or a surround heater alone. Sample configurations include low and high thermal conductivity powders and solids. The IR imaging results have been used to calibrate sample temperatures in the HTXRD furnace.

Payzant, E.A.; Wang, H.

1999-04-05T23:59:59.000Z

464

Materials and mechanisms of high temperature lithium sulfide batteries  

DOE Green Energy (OSTI)

New materials have encouraged development of bipolar Li-Al/FeS{sub 2} batteries for electric vehicle (EV) applications. Current technology employs a two-phase Li-alloy negative electrode low-melting, LiCl-rich LiCl-LiBr-KBr molten salt electrolyte, and either an FeS or an upper-plateau (UP) FeS{sub 2} positive electrode. These components are assembled in a sealed bipolar battery configuration. Use of the two-phase Li-alloy ({alpha} + {beta} Li-Al and Li{sub 5}Al{sub 5}Fe{sub 2}) negative electrode provides in situ overcharge tolerance that renders the bipolar design viable. Employing LiCl-rich LiCl-LiBr-KBr electrolyte in ``electrolyte-starved`` calls achieves low-burdened cells, that possess low area-specific impedance; comparable to that of flooded cells using LiCl-LiBr-KBr eutectic electrolyte. The combination of dense UP FeS{sub 2} electrodes and low-melting electrolyte produces a stable and reversible couple, achieving over 1000 cycle life in flooded cells, with high power capabilities. In addition, a family of stable sulfide ceramic/sealant materials was developed that produce high-strength bonds between a variety of metals and ceramics, which renders lithium/iron suffide bipolar stacks practical. Bipolar Li-Al/FeS{sub 2} cells and four-cell stacks using these seals are being built and tested in the 13 cm diameter size for EV applications. To date, Li-Al/FeS{sub 2} cells have attained 400 W/kg power at 80% DOD and 180 Wh/kg energy at the 30 W/kg rate. When cell performance characteristics are used to model full-scale EV and hybrid vehicle (HV) batteries, they are projected to meet or exceed the performance requirements for a large variety of EV and HV applications. Efficient production and application of Li-alloys and Li-salt electrolyte are critical to approaching battery cost objectives.

Kaun, T.D.; Hash, M.C.; Henriksen, G.L.; Jansen, A.N.; Vissers, D.R.

1994-05-01T23:59:59.000Z

465

Fabrication and Characterization of Uranium-based High Temperature Reactor  

NLE Websites -- All DOE Office Websites (Extended Search)

Fabrication and Characterization of Uranium-based High Temperature Reactor Fabrication and Characterization of Uranium-based High Temperature Reactor Fuel June 01, 2013 The Uranium Fuel Development Laboratory is a modern R&D scale lab for the fabrication and characterization of uranium-based high temperature reactor fuel. A laboratory-scale coater manufactures tri-isotropic (TRISO) coated fuel particles (CFPs), state-of-the-art materials property characterization is performed, and the CFPs are then pressed into fuel compacts for irradiation testing, all under a NQA-1 compliant Quality Assurance Program. After fuel kernel size and shape are measured by optical shadow imaging, the TRISO coatings are deposited via fluidized bed chemical vapor deposition in a 50-mm diameter conical chamber within the coating furnace. Computer control of temperature and gas composition ensures reproducibility

466

DOE Science Showcase - Understanding High-Temperature Superconductors |  

Office of Scientific and Technical Information (OSTI)

Understanding High-Temperature Superconductors Understanding High-Temperature Superconductors Credit: DOE Scientists have long worked to understand one of the great mysteries of modern physics - the origin and behavior of high-temperature superconductors (HTS) that are uniquely capable of transmitting electricity with zero loss when chilled to subzero temperatures. For decades there have been competing theories and misunderstandings of how HTS materials actually work and they have remained fundamentally puzzling to physicists. Solving this mystery has the potential to revolutionize the planet's energy infrastructure from generation to transmission and grid-scale storage. Recent technical breakthroughs in this quest are being discovered by DOE scientists and their collaborators. Read about HTS technology, basic