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Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

High-Sulfur Coal for Generating Electricity  

Science Journals Connector (OSTI)

...amounts of coal, because...Director-Mineral Re-sources...of Gas from Coal through a...on coals of high ash-fusion temperature...per ton of high-sulfur coal burned. Absorp-tion...particulate matter as well as...capable of remov-ing up to...

James T. Dunham; Carl Rampacek; T. A. Henrie

1974-04-19T23:59:59.000Z

2

High-Sulfur Coal for Generating Electricity  

Science Journals Connector (OSTI)

High-Sulfur...FLUIDIZED-BED COMBUSTORS, COMBUSTION...MAY FLUE GAS DES S E...1971 ). High-sulfur...was brief. Natural gas became...overdependent on natural gas and oil to...elevated pressure with a downward...coals of high ash-fusion...

James T. Dunham; Carl Rampacek; T. A. Henrie

1974-04-19T23:59:59.000Z

3

High-Sulfur Coal for Generating Electricity  

Science Journals Connector (OSTI)

...made historically by heating bitumi-nous coal in...heart of the anthracite district only about 5 years ago...energy, wind, and geothermal steam and brines, will...15.7 Nuclear 3.1 Geothermal Negligible 1973, use...home and commercial heating, transporta-tion...

James T. Dunham; Carl Rampacek; T. A. Henrie

1974-04-19T23:59:59.000Z

4

Extraction, separation, and analysis of high sulfur coal. Final report  

SciTech Connect (OSTI)

The work described in this report studies the removal of sulfur by oxidative interaction of various cupric salts with coal and also considers the possibility of removing organic sulfur by the selective interaction of supercritical ethanol with the organic coal matrix. Either one of these methods could potentially be used to pretreat coals before burning. The primary purpose of these studies is to ascertain the nature of the chemical reactions occurring, the chemical composition of the resultant products, and information on possible reaction mechanisms. This information should allow prediction of reasonable reaction conditions for the removal of organosulfur compound from coal.

Olesik, S.V.; Pekay, L.A.; Larkins, W. Jr. [comps.

1992-05-31T23:59:59.000Z

5

Extraction, separation, and analysis of high sulfur coal  

SciTech Connect (OSTI)

The work described in this report studies the removal of sulfur by oxidative interaction of various cupric salts with coal and also considers the possibility of removing organic sulfur by the selective interaction of supercritical ethanol with the organic coal matrix. Either one of these methods could potentially be used to pretreat coals before burning. The primary purpose of these studies is to ascertain the nature of the chemical reactions occurring, the chemical composition of the resultant products, and information on possible reaction mechanisms. This information should allow prediction of reasonable reaction conditions for the removal of organosulfur compound from coal.

Olesik, S.V.; Pekay, L.A.; Larkins, W. Jr. (comps.)

1992-05-31T23:59:59.000Z

6

Extraction, separation, and analysis of high sulfur coal  

SciTech Connect (OSTI)

Coal Reaction Study: The results of the reaction of aqueous cupric chloride with Illinois {number sign}6 coal are listed on page 21. These results indicate that the oxidative desulfurization of coal with cupric chloride is more complex and less effective than previously reported. Although almost all the pyritic and sulfate sulfur are removed from the coal, the organic sulfur is actually reported to have increased. This may be due to an actual increase in the organic sulfur through a side reaction of the pyrite, or it may be caused by inaccuracy of the ASTM method when large proportions of chloro substituents are present. The amount of chlorine added to the coal (from 0 to 3.18%) is quite large and counterproductive. Most importantly, the amount of non-combustible ash has increased from 15.48 to 51.21%, most likely in the form of copper. This will dramatically decrease both the efficiency of combustion in terms of altering the heat capacity of the coal as well as decrease the amount of energy produced per ton of coal. As a result, it is quite evident that this method of desulfurization needs some modification prior to further exploitation.

Olesik, S. (comp.)

1990-01-01T23:59:59.000Z

7

Extraction, separation, and analysis of high sulfur coal  

SciTech Connect (OSTI)

The work completed this past quarter has centered around the further study and characterization of the selective desulfurization of coal through the oxidative interaction of aqueous copper chloride. The reaction of the CuCl{sub 2} with the particular model compounds is conducted at a series of reaction times and reaction temperatures. The reaction times studied were 1, 3, 6, 12, and 24 hours. The reaction temperatures studied were 50, 130, 210, and 295{degree}C. After the reaction, the organic compounds were extracted with methylene chloride. These products were then analyzed via GC/IRD/MS and SFC/SCD (sulfur chemiluminescence detector). Model Coal Compounds reacted include: tetrahydrothiophene, methyl p-tolyl sulfide, cyclohexyl mercaptan, and thiophenol. At 130{degree}C, in addition to these compounds reacting, reactions were also detected for phenyl sulfide and benzo(b)thiophene. 14 figs.

Olesik, S. (comp.)

1990-01-01T23:59:59.000Z

8

Clean coal technology and emissions trading: Is there a future for high-sulfur coal under the Clean Air Act Amendments of 1990?  

SciTech Connect (OSTI)

The near-term and long-term fate of high-sulfur coal is linked to utility compliance plans, the evolution of emission allowance trading, state and federal regulation, and technological innovation. All of these factors will play an implicit role in the demand for high-sulfur coal. This paper will explore the potential impact that emissions trading will have on high-sulfur coal utilization by electric utilities. 28 refs., 6 figs., 4 tabs.

Bailey, K.A.; South, D.W. [Argonne National Lab., IL (United States); McDermott, K.A. [Argonne National Lab., IL (United States)]|[Illinois State Univ., Normal, IL (United States)

1991-12-31T23:59:59.000Z

9

Clean coal technology and emissions trading: Is there a future for high-sulfur coal under the Clean Air Act Amendments of 1990  

SciTech Connect (OSTI)

The near-term and long-term fate of high-sulfur coal is linked to utility compliance plans, the evolution of emission allowance trading, state and federal regulation, and technological innovation. All of these factors will play an implicit role in the demand for high-sulfur coal. This paper will explore the potential impact that emissions trading will have on high-sulfur coal utilization by electric utilities. 28 refs., 6 figs., 4 tabs.

Bailey, K.A.; South, D.W. (Argonne National Lab., IL (United States)); McDermott, K.A. (Argonne National Lab., IL (United States) Illinois State Univ., Normal, IL (United States))

1991-01-01T23:59:59.000Z

10

NETL: News Release - Florida Demo Tames High Sulfur Coal: Delivers Power at  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

March 11, 2005 March 11, 2005 Florida Demo Tames High Sulfur Coal: Delivers Power at Very Low Emissions Shows that New Technology Cuts Pollutants to Fractions of Federal Clean Air Limits JACKSONVILLE, FL - Recent tests with one of the nation's mid- to high-sulfur coals have further verified that a new electric generation technology in its first large-scale utility demonstration here is one of the world's cleanest coal-based power plants. This city's municipal utility JEA logged the achievement at its Northside Generating Station using Illinois No. 6 coal in a 300 megawatt demonstration of circulating fluidized bed (CFB) combustion, which is the largest application yet of the new form in the United States. It almost triples the size of a previous demonstration and scales up the technology to the sizes preferred for adding new plants and replacing old ones, also called repowering.

11

Development of advanced, dry, SO{sub x}/NO{sub x} emission control technologies for high-sulfur coal. Final report, April 1, 1993--December 31, 1994  

SciTech Connect (OSTI)

Dry Scrubbing is a common commercial process that has been limited to low- and medium-sulfur coal applications because high-sulfur coal requires more reagent than can be efficiently injected into the process. Babcock & Wilcox has made several advances that extend dry scrubbing technologies to higher sulfur coals by allowing deposit-free operation at low scrubber exit temperatures. This not only increases the amount of reagent that can be injected into the scrubber, but also increases SO{sub 2} removal efficiency and sorbent utilization. The objectives of this project were to demonstrate, at pilot scale, that advanced, dry-scrubbing-based technologies can attain the performance levels specified by the 1990 Clean Air Act Amendments for SO{sub 2} and NO{sub x} emissions while burning high-sulfur coal, and that these technologies are economically competitive with wet scrubber systems. The use of these technologies by utilities in and around Ohio, on new or retrofit applications, will ensure the future of markets for high-sulfur coal by creating cost effective options to coal switching.

Amrhein, G.T.

1994-12-23T23:59:59.000Z

12

Combustion of high-sulfur coal and anthracite wastes in a rotary kiln combustor with an advanced internal air distributor  

SciTech Connect (OSTI)

Fluid bed combustors have received extensive testing with both high-sulfur coal and anthracite wastes. Rotary kilns are effective and popular devices for waste combustion. The Angelo Rotary Furnace{trademark} has been developed to improve the operation of rotary pyrolyzer/combustor systems through enhanced air distribution, which in this process is defined as staged, swirled combustion air injection. Fourteen of these new furnaces have been installed worldwide. Two units in Thailand, designed for rice hull feed with occasional lignite feed, have been recently started up. An older unit in Pennsylvania is being upgraded with a new, more advanced air distribution system for a series of tests this fall in which inexpensive high-sulfur coal and anthracite wastes will be fired with limestone. The purposes of these tests are to determine the burning characteristics of these two fuels in this system, to discover the Ca/S ratios necessary for operation of a rotary kiln combusting these fuels, and to observe the gas-borne emissions from the furnace. An extensive preliminary design study will be performed on a commercial installation for combustion of anthracite wastes. 14 refs., 5 figs., 1 tab.

Cobb, J.T. Jr. (Pittsburgh Univ., PA (USA)); Ahn, Y.K. (Gilbert/Commonwealth, Inc., Reading, PA (USA)); Angelo, J.F. (Universal Energy International, Inc., Little Rock, AR (USA))

1990-01-01T23:59:59.000Z

13

Extraction, separation, and analysis of high sulfur coal. Technical progress report No. 13, June 22, 1990--October 15, 1990  

SciTech Connect (OSTI)

Coal Reaction Study: The results of the reaction of aqueous cupric chloride with Illinois {number_sign}6 coal are listed on page 21. These results indicate that the oxidative desulfurization of coal with cupric chloride is more complex and less effective than previously reported. Although almost all the pyritic and sulfate sulfur are removed from the coal, the organic sulfur is actually reported to have increased. This may be due to an actual increase in the organic sulfur through a side reaction of the pyrite, or it may be caused by inaccuracy of the ASTM method when large proportions of chloro substituents are present. The amount of chlorine added to the coal (from 0 to 3.18%) is quite large and counterproductive. Most importantly, the amount of non-combustible ash has increased from 15.48 to 51.21%, most likely in the form of copper. This will dramatically decrease both the efficiency of combustion in terms of altering the heat capacity of the coal as well as decrease the amount of energy produced per ton of coal. As a result, it is quite evident that this method of desulfurization needs some modification prior to further exploitation.

Olesik, S. [comp.

1990-12-31T23:59:59.000Z

14

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO[sub x]) emissions from high-sulfur coal-fired boilers  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO[sub x]) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO[sub x] to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe, there are numerous technical uncertainties associated with applying SCR to US coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in US coals that are not present in other fuels. (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO[sub 2] and SO[sub 3]. (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties will be explored by constructing a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U. S. coal.

Not Available

1992-08-01T23:59:59.000Z

15

Method of removal of sulfur from coal and petroleum products  

DOE Patents [OSTI]

A method for the removal of sulfur from sulfur-bearing materials such as coal and petroleum products using organophosphine and organophosphite compounds is provided.

Verkade, John G. (Ames, IA); Mohan, Thyagarajan (Ames, IA); Angelici, Robert J. (Ames, IA)

1995-01-01T23:59:59.000Z

16

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 2: SOx/Nox/Hg Removal for High Sulfur Coal  

SciTech Connect (OSTI)

The goal of this project is to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxy-combustion technology. The objective of Task 2 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning high sulfur coal in oxy-combustion power plants. The goal of the program was not only to investigate a new method of flue gas purification but also to produce useful acid byproduct streams as an alternative to using a traditional FGD and SCR for flue gas processing. During the project two main constraints were identified that limit the ability of the process to achieve project goals. 1) Due to boiler island corrosion issues >60% of the sulfur must be removed in the boiler island with the use of an FGD. 2) A suitable method could not be found to remove NOx from the concentrated sulfuric acid product, which limits sale-ability of the acid, as well as the NOx removal efficiency of the process. Given the complexity and safety issues inherent in the cycle it is concluded that the acid product would not be directly saleable and, in this case, other flue gas purification schemes are better suited for SOx/NOx/Hg control when burning high sulfur coal, e.g. this project's Task 3 process or a traditional FGD and SCR.

Nick Degenstein; Minish Shah; Doughlas Louie

2012-05-01T23:59:59.000Z

17

Innovative clean coal technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Fourth quarterly progress report  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe, there are numerous technical uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in US coals that are not present in other fuels; (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}; and (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties will be explored by constructing a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur US coal.

NONE

1992-12-31T23:59:59.000Z

18

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NOx) emissions from high-sulfur coal-fired boilers  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor.

Not Available

1991-11-01T23:59:59.000Z

19

Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Quarterly report No. 6, October--December, 1991  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1992-02-01T23:59:59.000Z

20

Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO sub x ) emissions from high-sulfur coal-fired boilers  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1992-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Quarterly report No. 2, October--December 1990  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide NO{sub x} control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor.

Not Available

1991-02-01T23:59:59.000Z

22

Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO sub x ) emissions from high-sulfur coal-fired boilers  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide NO{sub x} control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor.

Not Available

1991-02-01T23:59:59.000Z

23

Innovative clean coal technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Quarterly report No. 3, January--March 1991  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1991-07-01T23:59:59.000Z

24

Innovative clean coal technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO sub x ) emissions from high-sulfur coal-fired boilers  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1991-07-01T23:59:59.000Z

25

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Quarterly report No. 8, April--June, 1992  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe, there are numerous technical uncertainties associated with applying SCR to US coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in US coals that are not present in other fuels. (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}. (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties will be explored by constructing a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U. S. coal.

Not Available

1992-08-01T23:59:59.000Z

26

Demonstration of Selective Catalytic Reduction Technology to Control Nitrogen Oxice Emissions From High-Sulfur, Coal-Fired Boilers: A DOE Assessment  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2000/1111 2000/1111 Demonstration of Selective Catalytic Reduction Technology to Control Nitrogen Oxide Emissions From High-Sulfur, Coal- Fired Boilers: A DOE Assessment August 1998 U.S. Department of Energy Office of Fossil Energy Federal Energy Technology Center Morgantown, WV/Pittsburgh, PA 2 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or respon- sibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference

27

Effects of paleolatitude on coal quality - model for organic sulfur distribution in US coal  

SciTech Connect (OSTI)

In the conterminous US, most Carboniferous peats accumulated at latitudes of 0/degrees/-15/degrees/S, Cretaceous Rocky Mountain province peats at 30/degrees/-45/degrees/N, Tertiary northern Great Plains peats at 40/degrees/-55/degrees/N, and Tertiary Gulf Coast peats at 30/degrees/-40/degrees/N. Alaskan Cretaceous and Tertiary peats accumulated at latitudes above 70/degrees/N. A comparison of paleolatitudes calculated from paleomagnetic poles and organic sulfur contents for more than 7000 coal samples indicates that the higher the latitude in which a peat swamp developed, the lower the mean organic sulfur content of the subsequent coal (correlation coefficient - 0.4; significant at the 99% confidence level). Mean organic sulfur contents range from 0.90% (range = 0.01-5.08%, standard deviation = 0.56) in low-latitude Carboniferous coal to 0.25% (range = 0.01-1.41%, standard deviation = 0.23) in high-latitude Alaskan Cretaceous and Tertiary coal.

Affolter, R.H.; Stricker, G.D.

1989-03-01T23:59:59.000Z

28

Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Technical progress report, first and second quarters 1994  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from U.S., Japanese and European catalyst suppliers on a high-sulfur U.S. coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involve injecting ammonia into the flue gas generated from coal combustion in a boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to form nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe on gas-, oil-, and low-sulfur coal-fired boilers, there are several technical uncertainties associated with applying SCR to U.S. coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in U.S. coals that are not present in other fuels; (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}; and (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties are being explored by operating a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U.S. coal. The project is being conducted in the following three phases: permitting, environmental monitoring plan and preliminary engineering; detailed design engineering and construction; and operation, testing, disposition and final report. The project was in the operation and testing phase during this reporting period. Accomplishments for this period are described.

NONE

1995-11-01T23:59:59.000Z

29

Review of Mid- to High-Temperature Sulfur Sorbents for Desulfurization of Biomass- and Coal-derived Syngas  

Science Journals Connector (OSTI)

Biomass feedstocks contain low percentages of protein-derived sulfur that is converted primarily to H2S, as well as small amounts of carbonyl sulfide (COS) and organosulfur compounds during pyrolysis and gasification. ...

Singfoong Cheah; Daniel L. Carpenter; Kimberly A. Magrini-Bair

2009-10-16T23:59:59.000Z

30

Chemical looping combustion of high-sulfur coal with NiFe2O4-combined oxygen carrier  

Science Journals Connector (OSTI)

Chemical looping combustion (CLC) of coal has gained increasing attention as a novel combustion technology for its attractive advantage in the...2. In relative to the single metal oxide-based oxygen carrier (OC),...

Baowen Wang; Gan Xiao; Xiaoyong Song…

2014-12-01T23:59:59.000Z

31

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NOx) emissions from high-sulfur coal-fired boilers. Quarterly report No. 5, July--September 1991  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor.

Not Available

1991-11-01T23:59:59.000Z

32

Sulfur meter for blending coal at Plant Monroe: Final report  

SciTech Connect (OSTI)

An on-line sulfur analyzer, installed at the Detroit Edison, Monroe Power station, was placed into service and evaluated for coal blending optimization to minimize the cost of complying with changing stack gas sulfur dioxide regulations. The project involved debugging the system which consisted of an /open quotes/as-fired/close quotes/ sampler and nuclear source sulfur analyzer. The system was initially plagued with mechanical and electronic problems ranging from coal flow pluggages to calibration drifts in the analyzer. Considerable efforts were successfully made to make the system reliable and accurate. On-line testing showed a major improvement in control of sulfur dioxide emission rates and fuel blending optimization equivalent to as much as $6 million in fuel costs at the time of the evaluation. 7 refs., 14 figs., 12 tabs.

Trentacosta, S.D.; Yurko, J.O.

1988-04-01T23:59:59.000Z

33

Using ISC & GIS to predict sulfur deposition from coal-fired power plants  

E-Print Network [OSTI]

The goal of this research project was to determine if atmospheric sources have the potential of contributing significantly to the sulfur content of grazed forage. Sulfur deposition resulting from sulfur dioxide emissions from coal- fired power...

Lopez, Jose Ignacio

2012-06-07T23:59:59.000Z

34

Dependence of liquefaction behavior on coal characteristics. Part VI. Relationship of liquefaction behavior of a set of high sulfur coals to chemical structural characteristics. Final technical report, March 1981 to February 1984  

SciTech Connect (OSTI)

The initial aim of this research was to use empirical mathematical relationships to formulate a better understanding of the processes involved in the liquefaction of a set of medium rank high sulfur coals. In all, just over 50 structural parameters and yields of product classes were determined. In order to gain a more complete understanding of the empirical relationships between the various properties, a number of relatively complex statistical procedures and tests were applied to the data, mostly selected from the field of multivariate analysis. These can be broken down into two groups. The first group included grouping techniques such as non-linear mapping, hierarchical and tree clustering, and linear discriminant analyses. These techniques were utilized in determining if more than one statistical population was present in the data set; it was concluded that there was not. The second group of techniques included factor analysis and stepwise multivariate linear regressions. Linear discriminant analyses were able to show that five distinct groups of coals were represented in the data set. However only seven of the properties seemed to follow this trend. The chemical property that appeared to follow the trend most closely was the aromaticity, where a series of five parallel straight lines was observed for a plot of f/sub a/ versus carbon content. The factor patterns for each of the product classes indicated that although each of the individual product classes tended to load on factors defined by specific chemical properties, the yields of the broader product classes, such as total conversion to liquids + gases and conversion to asphaltenes, tended to load largely on factors defined by rank. The variance explained and the communalities tended to be relatively low. Evidently important sources of variance have still to be found.

Neill, P. H.; Given, P. H.

1984-09-01T23:59:59.000Z

35

Alaska has 4. 0 trillion tons of low-sulfur coal: Is there a future for this resource  

SciTech Connect (OSTI)

The demand for and use of low-sulfur coal may increase because of concern with acid rain. Alaska's low-sulfur coal resources can only be described as enormous: 4.0 trillion tons of hypothetical onshore coal. Mean total sulfur content is 0.34% (range 0.06-6.6%, n = 262) with a mean apparent rank of subbituminous B. There are 50 coal fields in Alaska; the bulk of the resources are in six major fields or regions: Nenana, Cook Inlet, Matanuska, Chignik-Herendeen Bay, North Slope, and Bering River. For comparison, Carboniferous coals in the Appalachian region and Interior Province have a mean total sulfur content of 2.3% (range 0.1-19.0%, n = 5,497) with a mean apparent rank of high-volatile A bituminous coal, and Rocky Mountain and northern Great Plains Cretaceous and Tertiary coals have a mean total sulfur content of 0.86% (range 0.02-19.0%, n = 2,754) with a mean apparent rank of subbituminous B. Alaskan coal has two-fifths the total sulfur of western US coals and one-sixth that of Carboniferous US coals. Even though Alaska has large resources of low-sulfur coal, these resources have not been developed because of (1) remote locations and little infrastructure, (2) inhospitable climate, and (3) long distances to potential markets. These resources will not be used in the near future unless there are some major, and probably violent, changes in the world energy picture.

Stricker, G.D. (Geological Survey, Denver, CO (USA))

1990-05-01T23:59:59.000Z

36

Sulfur isotopes in coal constrain the evolution of the Phanerozoic sulfur cycle  

Science Journals Connector (OSTI)

...obviously influence the average isotope values. For the other data, samples...pp 87–105 . 19 Price FT Casagrande DJ ( 1991 ) Sulfur...coals. Geology of Fossil Fuels, Proc 30th Int Geol Congress...Jersey Pinelands and its effect on stream water chemistry...223 – 248 . 29 Price FT Shieh YN ( 1979 ) Fractionation...

Donald E. Canfield

2013-01-01T23:59:59.000Z

37

Central Appalachia: Production potential of low-sulfur coal  

SciTech Connect (OSTI)

The vast preponderance of eastern US low sulfur and 1.2-lbs SO{sub 2}/MMBtu compliance coal comes from a relatively small area composed of 14 counties located in eastern Kentucky, southern West Virginia and western Virginia. These 14 counties accounted for 68% of all Central Appalachian coal production in 1989 as well as 85% of all compliance coal shipped to electric utilities from this region. A property-by-property analysis of total production potential in 10 of the 14 counties (Floyd, Knott, Letcher, Harlan, Martin and Pike in Kentucky and Boone, Kanawha, Logan and Mingo in West Virginia) resulted in the following estimates of active and yet to be developed properties: (1) total salable reserves for all sulfur levels were 5.9 billion tons and (2) 1.2-lbs. SO{sub 2}/MMBtu compliance'' reserves totaled 2.38 billion tons. This potential supply of compliance coal is adequate to meet the expanded utility demand expected under acid rain for the next 20 years. Beyond 2010, compliance supplies will begin to reach depletion levels in some areas of the study region. A review of the cost structure for all active mines was used to categorize the cost structure for developing potential supplies. FOB cash costs for all active mines in the ten counties ranged from $15 per ton to $35 per ton and the median mine cost was about $22 per ton. A total of 47 companies with the ability to produce and ship coal from owned or leased reserves are active in the ten-county region. Identified development and expansion projects controlled by active companies are capable of expanding the region's current production level by over 30 million tons per year over the next twenty years. Beyond this period the issue of reserve depletion for coal of all sulfur levels in the ten county region will become a pressing issue. 11 figs., 12 tabs.

Watkins, J. (Hill and Associates, Inc., Annapolis, MD (United States))

1991-09-01T23:59:59.000Z

38

Direct determination of organic and inorganic sulfur in coal by controlled oxidation  

SciTech Connect (OSTI)

The overall objective of this project is to develop an analytical method to directly measure the forms of organic sulfur in coal. The method will provide a route to monitor the effectiveness of coal preparation research directed toward removal of organic sulfur in coal. The approach involves subjecting diluted coal samples simultaneously to an oxygen flow and a linear increase in temperature. Distinctive sulfur dioxide evolution patterns are observed among coals of different rank and between raw and treated coals. Assignments have been made relating each specific sulfur dioxide evolution to the non-aromatic organic, aromatic organic, and inorganic sulfur present in coals and treated coals. Work is progressing on schedule to optimize experimental conditions and to improve the efficiency of the controlled-atmosphere programmed-temperature oxidation (CAPTO) method by developing a multiple sample instrumental system.

LaCount, R.B.

1992-01-01T23:59:59.000Z

39

Direct determination of organic and inorganic sulfur in coal by controlled oxidation  

SciTech Connect (OSTI)

The overall objective of this project is to develop an analytical method to directly measure the forms of organic sulfur in coal. The method will provide a route to monitor the effectiveness of coal preparation research directed toward removal of organic sulfur in coal. The approach involves subjecting diluted coal samples simultaneously to an oxygen flow and a linear increase in temperature. Distinctive sulfur dioxide evolution patterns are observed among coals of different rank and between raw and treated coals. Assignments have been made relating each specific sulfur dioxide evolution to the non-aromatic organic, aromatic organic, and inorganic sulfur present in coals and treated coals. Work is progressing on schedule to optimize experimental conditions and to improve the efficiency of the controlled-atmosphere programmed-temperature oxidation (CAPTO) method by developing a multiple sample instrumental system.

LaCount, R.B.

1992-12-31T23:59:59.000Z

40

NONEQUILIBRIUM SULFUR CAPTURE AND RETENTION IN AN AIR COOLED SLAGGING COAL COMBUSTOR  

SciTech Connect (OSTI)

Calcium oxide injected in a slagging combustor reacts with the sulfur from coal combustion to form sulfur-bearing particles. They are deposited on the liquid slag layer on the combustor wall. Due to the low solubility of sulfur in slag, slag must be rapidly drained from the combustor to limit sulfur gas re-evolution. Analysis indicated that slag mass flow rates in excess of 400 lb/hr should limit sulfur re-evolution. The objective of this 42-month project was to perform a series of tests to determine the factors that control the retention of the sulfur in the slag. 36 days of testing on the combustor were completed prior to the end of this reporting period, 12/31/98. This compares with 16 tests required in the original project plan. Combustor tests in early 1997 with high (37%) ash, Indian coal confirmed that high slag mass flow rates of about 500 lb/hr resulted in retention in the slag of up to 20% of the injected sulfur content mineral matter. To further increase the slag flow rate, rice husks, which contain 20% ash, and rice husk char, which contain 70% ash, were co-fired with coal in the combustor. A series of 13 combustor tests were performed in fourth quarter of 1997 and a further 6 tests were performed in January 1998 and in the summer of 1998. The test objective was to achieve slag flow rates between 500 and 1,000 lb/hr. Due to the very low bulk density of rice husk, compared to pulverized coal, almost the entire test effort focused on developing methods for feeding the rice husks into combustor. In the last test of December 1997, a peak mineral matter, injection rate of 592 lb/hr was briefly achieved by injection of coal, rice husk char, gypsum, and limestone into the combustor. However, no significant sulfur concentration was measured in the slag removed from the combustor. The peak injection rate reached with biomass in the 1997 tests was 310 lb/hr with rice husk, and 584 lb/hr with rice husk char.

Dr. Bert Zauderer

1999-03-15T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

VHF EPR analysis of organic sulfur in coal. Technical report, December 1, 1991--February 29, 1992  

SciTech Connect (OSTI)

This is a report of the second quarter of a two-year investigation exploiting electron paramagnetic resonance (EPR), especially novel, very high frequency (VHF) spectroscopy techniques and instrumentation (the only high-modulation W-band EPR spectrometer in the world) developed earlier by these authors, to conduct further qualitative and quantitative studies of heteroatomic organic molecules in coal with particular emphasis on sulfur. New model compounds have been prepared in EPR-active forms and surveyed with X-band EPR. Previous W-band (96 GHz) VHF-EPR work is being extended to studies of these new model compounds as well as to a variety of coal and desulfurized coal samples. Typically, the model compounds under investigation and their analogues are found in coals as stable free radicals which give rise to an EPR signal.

Clarkson, R.B.; Belford, R.L.

1992-08-01T23:59:59.000Z

42

Selective Catalytic Oxidation of Hydrogen Sulfide to Elemental Sulfur from Coal-Derived Fuel Gases  

SciTech Connect (OSTI)

The development of low cost, highly efficient, desulfurization technology with integrated sulfur recovery remains a principle barrier issue for Vision 21 integrated gasification combined cycle (IGCC) power generation plants. In this plan, the U. S. Department of Energy will construct ultra-clean, modular, co-production IGCC power plants each with chemical products tailored to meet the demands of specific regional markets. The catalysts employed in these co-production modules, for example water-gas-shift and Fischer-Tropsch catalysts, are readily poisoned by hydrogen sulfide (H{sub 2}S), a sulfur contaminant, present in the coal-derived fuel gases. To prevent poisoning of these catalysts, the removal of H{sub 2}S down to the parts-per-billion level is necessary. Historically, research into the purification of coal-derived fuel gases has focused on dry technologies that offer the prospect of higher combined cycle efficiencies as well as improved thermal integration with co-production modules. Primarily, these concepts rely on a highly selective process separation step to remove low concentrations of H{sub 2}S present in the fuel gases and produce a concentrated stream of sulfur bearing effluent. This effluent must then undergo further processing to be converted to its final form, usually elemental sulfur. Ultimately, desulfurization of coal-derived fuel gases may cost as much as 15% of the total fixed capital investment (Chen et al., 1992). It is, therefore, desirable to develop new technology that can accomplish H{sub 2}S separation and direct conversion to elemental sulfur more efficiently and with a lower initial fixed capital investment.

Gardner, Todd H.; Berry, David A.; Lyons, K. David; Beer, Stephen K.; Monahan, Michael J.

2001-11-06T23:59:59.000Z

43

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 130-156 seconds at 120-140 C to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases, evaluate removal capabilities of hydrogen sulfide and COS from coal gases with formulated catalysts, and develop an economic regeneration method of deactivated catalysts. Simulated coal gas mixtures consist of 3,300-3,800-ppmv hydrogen sulfide, 1,600-1,900 ppmv sulfur dioxide, 18-21 v% hydrogen, 29-34 v% CO, 8-10 v% CO{sub 2}, 5-18 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 114-132 SCCM. The temperature of the reactor is controlled in an oven at 120-140 C. The pressure of the reactor is maintained at 116-129 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is

K. C. Kwon

2007-09-30T23:59:59.000Z

44

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash coat, and catalytic metals, to develop a regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor. The task of developing kinetic rate equations and modeling the direct oxidation process to assist in the design of large-scale plants will be abandoned since formulation of catalysts suitable for the removal of H{sub 2}S and COS is being in progress. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 46-570 seconds under reaction conditions to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases and evaluate their capabilities in reducing hydrogen sulfide and COS in coal gases. Simulated coal gas mixtures consist of 3,200-4,000-ppmv hydrogen sulfide, 1,600-20,000-ppmv sulfur dioxide, 18-27 v% hydrogen, 29-41 v% CO, 8-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of simulated coal gas mixtures to the reactor are 30 - 180 cm{sup 3}/min at 1 atm and 25 C (SCCM). The temperature of the reactor is controlled in an oven at 120-155 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio

K.C. Kwon

2009-09-30T23:59:59.000Z

45

Kinetics of Direct Oxidation of H2S in Coal Gas to Elemental Sulfur  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced Vision 21 plants that produce electric power and clean transportation fuels with coal and natural gas. These Vision 21 plants will require highly clean coal gas with H{sub 2}S below 1 ppm and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation Vision 21 plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and 400 square cells/inch{sup 2}, {gamma}-Al{sub 2}O{sub 3}-wash-coated monolithic catalyst, and various reactors such as a micro packed-bed reactor, a micro bubble reactor, and a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam.

K.C. Kwon

2005-11-01T23:59:59.000Z

46

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2} in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives using a monolithic catalyst reactor, experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 40-560 seconds at 120-150 C to evaluate effects of reaction temperatures, total pressure, space time, and catalyst regeneration on conversion of hydrogen sulfide into elemental sulfur and formation of COS. Simulated coal gas mixtures consist of 3,600-4,000-ppmv hydrogen sulfide, 1,800-2,000 ppmv sulfur dioxide, 23-27 v% hydrogen, 36-41 v% CO, 10-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 30-180 SCCM. The temperature of the reactor is controlled in an oven at 120-150 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is mai

K. C. Kwon

2006-09-30T23:59:59.000Z

47

High Hydrogen, Low Methane Syngas from Low-Rank Coals for Coal-to-Liquids  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

High Hydrogen, Low Methane Syngas from Low-Rank Coals for Coal-to-Liquids Production High Hydrogen, Low Methane Syngas from Low-Rank Coals for Coal-to-Liquids Production Southern Research Institute (SRI) Project Number: FE0012054 Project Description The focus of the project will be to develop, test, and optimize steam-reforming catalysts for converting tars, C2+ hydrocarbons, NH3, and CH4 in high-temperature and sulfur environments, increasing the ratio of hydrogen in syngas, as part of a modified, advanced gasification platform for the conversion of low-rank coals to syngas for coal-to-liquid and integrated gasification combined cycle applications. Project Details Program Background and Project Benefits Project Scope and Technology Readiness Level Accomplishments Contacts, Duration, and Cost Project Images Abstract Performer website: Southern Research Institute

48

The use of ethanol to remove sulfur from coal. Final report, September 1991--December 1992; Revision  

SciTech Connect (OSTI)

The initial technical goal in the project was to develop a chemical method for the cost effective removal of both inorganic and organic sulfur from Ohio coals. Verifying and using a process of reacting ethanol vapors with coal under conditions disclosed in U.S. Patent 4,888,029, the immediate technical objectives were to convert a small scale laborative batch process to a larger scale continuous process which can serve as the basis for commercial development of the technology. This involved getting as much information as possible from small scale batch autoclave or fluid bed laboratory reactors for use in pilot plant studies. The laboratory data included material balances on the coal and sulfur, temperature and pressure ranges for the reaction, minimum reaction times at different conditions, the effectiveness of different activators such as oxygen and nitric oxide, the amount and nature of by-products such as sulfur dioxide, hydrogen sulfide and acetaldehyde, the effect of coal particle size on the speed and completeness of the reaction, and the effectiveness of the reaction on different Ohio coals. Because the laboratory experiments using the method disclosed in U.S. 4,888,029 were not successful, the objective for the project was changed to develop a new laboratory process to use ethanol to remove sulfur from coal. Using copper as a catalyst and as an H{sub 2}S scavenger, a new laboratory procedure to use ethanol to remove sulfur from coal has been developed at Ohio University and a patent application covering this process was filed in March, 1993. The process is based on the use of copper as a catalyst for the dehydrogenation of ethanol to produce nascent hydrogen to remove sulfur from the coal and the use of copper as a scavenger to capture the hydrogen sulfide formed from the sulfur removed from coal.

Savage, R.L.; Lazarov, L.K.; Prudich, M.E.; Lange, C.A.; Kumar, N.

1994-03-10T23:59:59.000Z

49

Steam–Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture  

Science Journals Connector (OSTI)

These two coals represent the two main types of non-lignite coals currently used in the U.S.: a medium-sulfur eastern bituminous coal and a low-sulfur western sub-bituminous coal. ... At a commercial scale, this would likely mean that there could be a roughly 3-fold decrease in the size of the gasifier compared to the case of dry mixing coal and the regenerated calcium oxide. ...

Nicholas S. Siefert; Dushyant Shekhawat; Shawn Litster; David A. Berry

2013-03-03T23:59:59.000Z

50

Behavior of sulfur and chlorine in coal during combustion and boiler corrosion. Final technical report, 1 September, 1992--31 August, 1993  

SciTech Connect (OSTI)

The goals of this project are to investigate the behavior of sulfur and chlorine during pyrolysis and combustion of Illinois coals, the chemistry and mineralogy of boiler deposits, the effects of combustion gases on boiler materials, and remedial measures to reduce the sulfur and chlorine compounds in combustion gases. Replicate determinations of chlorine and sulfur evolution during coal pyrolysis-gas combustion were conducted using a pyrolysis apparatus in conjunction with a quadrupole gas analyzer. HCl is the only gaseous chlorine species measured in combustion gases. Pyrolysis of coal IBC-109 spiked with NaCl solution shows a strong peak of HCl evolution above 700C. The absence of this peak during pyrolysis of Illinois coal indicates that little chlorine in Illinois coal occurs in the NaCl form. Evolution of sulfur during coal pyrolysis was studied; the sulfur evolution profile may be explained by the sulfur forms in coal. To determine the fate of sulfur and chlorine during combustion, a set of six samples of boiler deposits from superheater and reheater tubes of an Illinois power plant was investigated. Scanning electron microscopy shows microscopic calcium sulfate droplets on cenospheres. Superheater deposits are high in mullite, hematite, and cristobalite, whereas a reheater deposit is enriched in anhydrite. The chlorine content is very low, indicating that most of the chlorine in the feed coal is lost as volatile HCl during he combustion process. The profiles of SO{sub 2} released during combustion experiments at 825 C indicate that calcium hydroxide added to the coal has a significant effect on reducing the SO{sub 2} vapors in combustion gases.

Chou, C.L.; Hackley, K.C.; Cao, J.; Moore, D.M.; Xu, J.; Ruch, R.R. [Illinois State Geological Survey, Champaign, IL (United States); Pan, W.P.; Upchurch, M.L.; Cao, H.B. [Western Kentucky Univ., Bowling Green, KY (United States)

1993-12-31T23:59:59.000Z

51

Reserves and potential supply of low-sulfur Appalachian coal. Final report  

SciTech Connect (OSTI)

This project has two objectives. The first is to develop and test a methodology for determining economically mineable reserves of low-sulfur Appalachian coal. The second is to appraise the potential supply response to a very large increase in demand for low-sulfur Appalachian coal. The reserve determination procedure developed in the project applies criteria similar to those employed by mining engineers in assessing the commercial feasibility of mining properties. The procedure is relatively easy to apply, could be used to develop reserve estimates for a large sample of mining blocks for under $500,000, and produces reserve estimates very different from those produced from the criteria that have been used by the United States Bureau of Mines: with the more rigorous method developed in this project surface mineable reserves are much larger and deep mineable reserves are less than with the Bureau of Mines method. The appraisal of potential low-sulfur coal supply response assessed excess capacity, coal mining company outlook on reserves, and coal quality requirements. The appraisal concluded that ample coal meeting most buyers' requirements will probably be available in the near or long term at a price under $45 in 1984 dollars. However, coal quality requirements may prove a constraint for some buyers, and an upward surge in prices would probably occur in the event of legislation imposing requirements leading to greatly increased low-sulfur coal demand. 14 refs., 24 figs., 15 tabs.

Hughes, W.R.

1986-09-01T23:59:59.000Z

52

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Draft final report  

SciTech Connect (OSTI)

The primary goal of this project was to demonstrate the use of Selective Catalytic Reduction (SCR) to reduce NO{sub x} emissions from pulverized-coal utility boilers using medium- to high-sulfur US coal. The prototype SCR facility, built in and around the ductwork of Plant Crist Unit 5, consisted of three large SCR reactor units (Reactors A, B, and C), each with a design capacity of 5,000 standard cubic feet per minute (scfm) of flue gas, and six smaller reactors (Reactors D through J), each with a design capacity of 400 scfm of flue gas. The three large reactors contained commercially available SCR catalysts as offered by SCR catalyst suppliers. These reactors were coupled with small-scale air preheaters to evaluate (1) the long-term effects of SCR reaction chemistry on air preheater deposit formation and (2) the impact of these deposits on the performance of air preheaters. The small reactors were used to test additional varieties of commercially available catalysts. The demonstration project was organized into three phases: (1) Permitting, Environmental Monitoring Plan (EMP) Preparation, and Preliminary Engineering; (2) Detail Design Engineering and Construction; and (3) Operation, Testing, Disposition, and Final Report Preparation. Section 2 discusses the planned and actual EMP monitoring for gaseous, aqueous, and solid streams over the course of the SCR demonstration project; Section 3 summarizes sampling and analytical methods and discusses exceptions from the methods specified in the EMP; Section 4 presents and discusses the gas stream monitoring results; Section 5 presents and discusses the aqueous stream monitoring results; Section 6 presents and discusses the solid stream monitoring results; Section 7 discusses EMP-related quality assurance/quality control activities performed during the demonstration project; Section 8 summarizes compliance monitoring reporting activities; and Section 9 presents conclusions based on the EMP monitoring results.

NONE

1996-06-14T23:59:59.000Z

53

Additives and Cathode Materials for High-Energy Lithium Sulfur...  

Broader source: Energy.gov (indexed) [DOE]

Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries 2013 DOE Hydrogen and Fuel Cells...

54

Coal Cleaning Using Resonance Disintegration for Mercury and Sulfur Reduction Prior to Combustion  

SciTech Connect (OSTI)

Coal-cleaning processes have been utilized to increase the heating value of coal by extracting ash-forming minerals in the coal. These processes involve the crushing or grinding of raw coal followed by physical separation processes, taking advantage of the density difference between carbonaceous particles and mineral particles. In addition to the desired increase in the heating value of coal, a significant reduction of the sulfur content of the coal fed to a combustion unit is effected by the removal of pyrite and other sulfides found in the mineral matter. WRI is assisting PulseWave to develop an alternate, more efficient method of liberating and separating the undesirable mineral matter from the carbonaceous matter in coal. The approach is based on PulseWave's patented resonance disintegration technology that reduces that particle size of materials by application of destructive resonance, shock waves, and vortex generating forces. Illinois No.5 coal, a Wyodak coal, and a Pittsburgh No.8 coal were processed using the resonance disintegration apparatus then subjected to conventional density separations. Initial microscopic results indicate that up to 90% of the pyrite could be liberated from the coal in the machine, but limitations in the density separations reduced overall effectiveness of contaminant removal. Approximately 30-80% of the pyritic sulfur and 30-50% of the mercury was removed from the coal. The three coals (both with and without the pyritic phase separated out) were tested in WRI's 250,000 Btu/hr Combustion Test Facility, designed to replicate a coal-fired utility boiler. The flue gases were characterized for elemental, particle bound, and total mercury in addition to sulfur. The results indicated that pre-combustion cleaning could reduce a large fraction of the mercury emissions.

Andrew Lucero

2005-04-01T23:59:59.000Z

55

High gradient magnetic beneficiation of dry pulverized coal via upwardly directed recirculating fluidization  

DOE Patents [OSTI]

This invention relates to an improved device and method for the high gradient magnetic beneficiation of dry pulverized coal, for the purpose of removing sulfur and ash from the coal whereby the product is a dry environmentally acceptable, low-sulfur fuel. The process involves upwardly directed recirculating air fluidization of selectively sized powdered coal in a separator having sections of increasing diameters in the direction of air flow, with magnetic field and flow rates chosen for optimum separations depending upon particulate size.

Eissenberg, David M. (Oak Ridge, TN); Liu, Yin-An (Opelika, AL)

1980-01-01T23:59:59.000Z

56

Sulfur and ash in Paleocene Wyodak-Anderson coal in the Powder River Basin, Wyoming and Montana: A fuel source beyond 2000  

SciTech Connect (OSTI)

When coal-fired power plants are required by the Environmental Protection Agency (EPA) to meet more stringent sulfur emission standards (0.6 pound per million Btu) after the year 2000, most of the clean and compliant coals will come from the Powder River Basin in Wyoming and Montana. In 1996 more than 300 million short toms of these clean and compliant coals were produced from the Paleocene Fort Union Formation in the northern Rocky Mountains and Great Plans region. This is more than 30% of the total US coal production of 1.03 billion short tons in 1996. Future demand for clean and compliant coals can probably be met through production of more F or Union coals in the region. It is projected by the Energy Information Agency (1996) that most of the low-sulfur and low-ash coals in the northern Rocky Mountains and Great Plains region will be produced from the Wyodak-Anderson coal bed/zone of the Paleocene Fort Union Formation in the Powder River Basin. To date, coal produced from the Wyodak-Anderson coal bed/zone, containing 0.5% sulfur, 1.2 lb SO{sub 2} per million btu, and 6% ash (mean values on an as-received basis) meet current EPA regulatory compliance. This coal bed/zone alone produced 262 million short toms of >26% of the total US coal production in 1996. Based on the current consumption rates of coal and a forecast by the EIA (1996), the Wyodak-Anderson coals are projected to produce an additional 153 million short tons a year by the year 2016. At this rate of production, high quality Wyodak-Anderson coals may be adequate to fill future energy needs.

Ellis, M.S.; Stricker, G.D.; Flores, R.M.; Bader, L.R.

1998-07-01T23:59:59.000Z

57

Sulfur and ash in paleocene Wyodak-Anderson coal in the Powder River Basin, Wyoming and Montana: A fuel source beyond 2000  

SciTech Connect (OSTI)

When coal-fired power plants are required by the Environmental Protection Agency (EPA) to meet more stringent sulfur emission standards (0.6 pound per million Btu) after the year 2000, most of the clean and compliant coals will come from the Powder River Basin in Wyoming and Montana. In 1996 more than 300 million short tons of these clean and compliant coals were produced from the Paleocene Fort Union Formation in the northern Rocky Mountains and Great Plains region. This is more than 30 percent of the total US coal production of 1.03 billion short tons in 1996. Future demand for clean and compliant coals can probably be met through production of more Fort Union coals in the region. It is projected by the Energy Information Agency (1996) that most of the low-sulfur and low-ash coals in the northern Rocky Mountains and Great Plains region will be produced from the Wyodak-Anderson coal bed/zone of the Paleocene Fort Union Formation in the Powder River Basin. To date, coal produced from the Wyodak-Anderson coal bed/zone, containing 0.5 percent sulfur, 1.2 lb SO{sub 2} per million btu, and 6 percent ash (mean values on an as-received basis) meet current EPA regulatory compliance. This coal bed/zone alone produced 262 million short tons or >26 percent of the total U.S. coal production in 1996. Based on the current consumption rates of coal and a forecast by the EIA (1996), the Wyodak-Anderson coals are projected to produce an additional 153 million short tons a year by the year 2016. At this rate of production, high quality Wyodak-Anderson coals may be adequate to fill our future energy needs.

Ellis, M.S.; Stricker, G.D.; Flores, R.M.; Bader, L.R. [Geological Survey, Denver, CO (United States)

1998-04-01T23:59:59.000Z

58

U.S. Coal Reserves: An Update by Heat and Sulfur Content  

Gasoline and Diesel Fuel Update (EIA)

2) 2) Distribution Category UC-98 U.S. Coal Reserves: An Update by Heat and Sulfur Content February 1993 Energy Information Administration Office of Coal, Nuclear, Electric and Alternate Fuels U.S. Department of Energy Washington, DC 20585 Energy Information Administration/ U.S. Coal Reserves: An Update by Heat and Sulfur Content ii This report was prepared by the Energy Information Administration, the independent statistical and analytical agency within the Department of Energy. The information contained herein should not be construed as advocating or reflecting any policy position of the Department of Energy or of any other organization. Energy Information Administration/ U.S. Coal Reserves: An Update by Heat and Sulfur Content iii Contacts This report was prepared by the staff of the Energy

59

Transformations and affinities for sulfur of Chinese Shenmu coal ash in a pulverized coal-fired boiler  

SciTech Connect (OSTI)

The self-desulfurization efficiency of Shenmu coal with a high initial Ca/S molar ratio of 2.02 was measured in a 1,025 t/h pulverized coal-fired boiler. It increases from 29% to 32% when the power capacity decreases from 100% to 70%. About 60% of the mineral matter and calcium element fed into the furnace is retained in the fly ash, while less than 10% is retained in the bottom ash. About 70% of the sulfur element fed into the furnace is emitted as SO{sub 2} in the flue gas, while less than 10% is retained in the fly ash and less than 1% is retained in the bottom ash. The mineralogical compositions of feed coal, fly ash, and bottom ash were obtained by X-ray diffraction analysis. It is found that the initial amorphous phase content is 91.17% and the initial CaCO{sub 3} phase content is 2.07% in Shenmu coal. The vitreous phase and sulfation product CaSO{sub 4} contents are, respectively, 70.47% and 3.36% in the fly ash obtained at full capacity, while the retained CaCO{sub 3} and CaO contents are, respectively, 4.73% and 2.15%. However, the vitreous phase content is only 25.68% and no CaSO{sub 4} is detected in the bottom ash obtained at full capacity. When the power capacity decreases from 100% to 70%, the vitreous phase content in fly ash decreases from 70.47% to 67.41% and that in bottom ash increases from 25.68% to 28.10%.

Cheng, J.; Zhou, J.H.; Liu, J.Z.; Cao, X.Y.; Cen, K.F. [Zhejiang University, Hangzhou (China)

2009-07-01T23:59:59.000Z

60

Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...  

Broader source: Energy.gov (indexed) [DOE]

CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries 2011 DOE...

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

The use of ethanol to remove sulfur from coal. Final report, September 1991--December 1992  

SciTech Connect (OSTI)

In developing the new Ohio University procedure the thermodynamic limitations of the reactions for removal of both pyritic and organic sulfur from coal at 400--600{degrees}C were studied using copper as a very strong H{sub 2}S-acceptor. Copper serves as a catalyst for ethanol dehydrogenation to form nascent hydrogen. Copper also serves as a scavenger to form copper sulfide from the hydrogen sulfide evolved during the reaction. Copper sulfide in turn serves as a catalyst for organic sulfur hydrodesulfurization reactions. If the coal to be desulfurized contains pyrite (FeS{sub 2}) or FeS, the copper scavenger effect reduces any back reaction of hydrogen sulfide with the iron and increases the removal of sulfur from the carbonaceous material. The desired effect of using copper can be achieved by using copper or copper containing alloys as materials of construction or as liners for a regenerable reactor. During the time period that Ohio Coal Development Office supported this work, small scale (560 grams) laboratory experiments with coals containing about 3.5% sulfur have achieved up to 90% desulfurization at temperatures of 500{degrees}C when using a copper reactor. Results from the autoclave experiments have identified the nature of the chemical reactions taking place. Because the process removes both pyritic and organic sulfur in coal, the successful scale up of the process would have important economic significance to the coal industry. Even though this and other chemical processes may be relatively expensive and far from being commercial, the reason for further development is that this process may hold the promise of achieving much greater sulfur reduction and of producing a cleaner coal than other methods. This would be especially important for small or older power plants and industrial boilers.

Not Available

1993-04-15T23:59:59.000Z

62

Nonequilibrium sulfur capture and retention in an air cooled slagging coal combustor. Quarterly technical progress report, 1996  

SciTech Connect (OSTI)

The objective of this 24 month project is to determine the degree of sulfur retention in slag in a full scale cyclone coal combustor with sulfur capture by calcium oxide sorbent injection into the combustor. This sulfur capture process consists of two steps: Capture of sulfur with calcined calcium oxide followed by impact of the reacted sulfur-calcium particles on the liquid slag lining the combustor. The sulfur bearing slag must be removed within several minutes from the combustor to prevent re-evolution of the sulfur from the slag. To accomplish this requires slag mass flow rates in the range of several 100 lb/hr. To study this two step process in the combustor, two groups of tests are being implemented. In the first group, calcium sulfate in the form of gypsum, or plaster of Paris, was injected in the combustor to determine sulfur evolution from slag. In the second group, the entire process is tested with limestone and/or calcium hydrate injected into the combustor. This entire effort consists of a series of up to 16 parametric tests in a 20 MMtu/hr slagging, air cooled, cyclone combustor. During the present quarterly reporting period ending September 30,1996, three tests in this project were implemented, bringing the total tests to 5. In addition, a total of 10 test days were completed during this quarter on the parallel project that utilizes the same 20 MMtu/hr combustor. The results of that project, especially those related to improved slagging performance, have a direct bearing on this project in assuring proper operation at the high slag flow rates that may be necessary to achieve high sulfur retention in slag.

Zauderer, B.

1996-11-01T23:59:59.000Z

63

Coal Study Guide - High School | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

High School Coal Study Guide - High School Coal Study Guide - High School More Documents & Publications Coal Study Guide - Middle School Coal Study Guide for Elementary School...

64

Graphene-wrapped sulfur nanospheres with ultra-high sulfur loading for high energy density lithium–sulfur batteries  

Science Journals Connector (OSTI)

Abstract Lithium–sulfur (Li–S) battery with high theoretical energy density is one of the most promising energy storage systems for electric vehicles and intermittent renewable energy. However, due to the poor conductivity of the active material, considerable weight of the electrode is occupied by the conductive additives. Here we report a graphene-wrapped sulfur nanospheres composite (S-nanosphere@G) with sulfur content up to 91 wt% as the high energy density cathode material for Li–S battery. The sulfur nanospheres with diameter of 400–500 nm are synthesized through a solution-based approach with the existence of polyvinylpyrrolidone (PVP). Then the sulfur nanospheres are uniformly wrapped by conductive graphene sheets through the electrostatic interaction between graphene oxide and PVP, followed by reducing of graphene oxide with hydrazine. The design of graphene wrapped sulfur nanoarchitecture provides flexible conductive graphene coating with void space to accommodate the volume expansion of sulfur and to minimize polysulfide dissolution. As a result, the S-nanosphere@G nanocomposite with 91 wt% sulfur shows a reversible initial capacity of 970 mA h g?1 and an average columbic efficiency > 96% over 100 cycles at a rate of 0.2 C. Taking the total mass of electrode into account, the S-nanosphere@G composite is a promising cathode material for high energy density Li–S batteries.

Ya Liu; Jinxin Guo; Jun Zhang; Qingmei Su; Gaohui Du

2015-01-01T23:59:59.000Z

65

High-pressure coal fuel processor development  

SciTech Connect (OSTI)

The objective of Subtask 1.1 Engine Feasibility was to conduct research needed to establish the technical feasibility of ignition and stable combustion of directly injected, 3,000 psi, low-Btu gas with glow plug ignition assist at diesel engine compression ratios. This objective was accomplished by designing, fabricating, testing and analyzing the combustion performance of synthesized low-Btu coal gas in a single-cylinder test engine combustion rig located at the Caterpillar Technical Center engine lab in Mossville, Illinois. The objective of Subtask 1.2 Fuel Processor Feasibility was to conduct research needed to establish the technical feasibility of air-blown, fixed-bed, high-pressure coal fuel processing at up to 3,000 psi operating pressure, incorporating in-bed sulfur and particulate capture. This objective was accomplished by designing, fabricating, testing and analyzing the performance of bench-scale processors located at Coal Technology Corporation (subcontractor) facilities in Bristol, Virginia. These two subtasks were carried out at widely separated locations and will be discussed in separate sections of this report. They were, however, independent in that the composition of the synthetic coal gas used to fuel the combustion rig was adjusted to reflect the range of exit gas compositions being produced on the fuel processor rig. Two major conclusions resulted from this task. First, direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize these low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risks associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept.

Greenhalgh, M.L.

1992-11-01T23:59:59.000Z

66

Estimates of central Appalachian coal reserves by cost of production and sulfur content  

SciTech Connect (OSTI)

This study provides information on the quantity, quality, and production costs for all minable coal reserves in the major coal-producing counties of central Appalachia, a region that contains the large majority of low-sulfur and compliance coal reserves in the eastern US. Presently, the best source of detailed reserve information in the Appalachian region is the estimates produced by the mining and land holding companies that control the reserves. The authors have been able to obtain overall reserve estimates based on the detailed geological and engineering studies conducted by these companies. In areas where this information does not exist, the authors have relied on published estimates of reserves and modified these estimates based on known conditions on surrounding properties. This reserve information has been combined with data on coal quality and mining costs to produce cost curves for all minable coal reserves by sulfur content. Results to date indicate that most of the major coal-producing counties in central Appalachia will be able to increase production levels significantly on a sustainable basis for at least the next 20 years, without major real increases in coal prices.

Watkins, J.

1988-08-01T23:59:59.000Z

67

Adequacy of low-sulfur coal supplies for meeting acid rain requirements  

SciTech Connect (OSTI)

As we have shown, acid rain legislation would create a large demand for low-sulfur bituminous coals. These coals are primarily found in Central Appalachia and in parts of the West, and would displace much of the highersulfur coal production now coming from the Midwest and Northern Appalachia. The magnitude of the related shifts in coal production are potentially huge. Previously, it has been assumed that these shifts in demands could be met by the industry. This paper has tried to highlight possible difficulties in actually meeting such demands. In the near-term, these difficulties concern the ability of the industry to develop mines and of the transportation industry to ship the coal. In the longer-term, questions can be raised regarding the amount, the quality, and the mineability of low-sulfur bituminous coal reserves. These potential difficulties in coal supply could affect attainment of the legislative goals. If not addressed and resolved in a timely fashion, the results could be a higher cost to meeting legislative goals and/or a longer time required to meet them.

Klein, D.E.

1983-06-01T23:59:59.000Z

68

THE USE OF FERRIC SULFATE - ACID MEDIA FOR THE DESULFURIZATION OF MODEL COMPOUNDS OF COAL  

E-Print Network [OSTI]

1 (W.Va. ) Sulfate Organic Ash (%) Coal (ref. 32) Total Sin slag or bottom ash, coal gasification or liquefaction asthe Sulfur and Ash Content of High-Sulfur Coals by Peroxide-

Clary, Lloyd R.

2014-01-01T23:59:59.000Z

69

Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

& Publications Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries...

70

Sulfur in the Changuinola peat deposit, Panama, as an indicator of the environments of deposition of peat and coal  

SciTech Connect (OSTI)

The sulfur (S) content of coal is often used to infer aspects of paleoclimate, trophic state, and proximity to marine influence, of the mire in which it was deposited. In this study, the S content of peat in a large back-barrier mire complex on the Caribbean coast of Panama is related to climatic, biological, and tectonic factors of the depositional environment. The S content is in proportion to the degree of humidification of the peat, and both are independent of the pH of the groundwater. The distribution of forms of organic and inorganic sulfur in the tropical peats are found to be comparable to published values for temperate and subtropical peats, despite differences in vegetation and climate.The distribution of high-sulfur peats in the eastern part of the deposit and low-sulfur peats in the western part, and the SE-NW transgression parallel to the trend of the coastline, reflects the regional structural trend of coseismic subsidence greatest to the southeast.

Phillips, S.; Bustin, R.M. [Univ. of British Columbia, Vancouver, British Columbia (Canada). Dept. of Geological Sciences

1996-01-01T23:59:59.000Z

71

Sulfur nanocrystals anchored graphene composite with highly improved electrochemical performance for lithium–sulfur batteries  

Science Journals Connector (OSTI)

Abstract Two kinds of graphene–sulfur composites with 50 wt% of sulfur are prepared using hydrothermal method and thermal mixing, respectively. Transmission Electron Microscopy (TEM) and Energy Dispersive X-ray Spectra mapping show that sulfur nanocrystals with size of ?5 nm dispersed on graphene sheets homogeneously for the sample prepared by hydrothermal method (NanoS@G). While for the thermal mixed graphene–sulfur composite (S–G mixture), sulfur shows larger and uneven size (50–200 nm). X-ray Photoelectron Spectra (XPS) reveals the strong chemical bonding between the sulfur nanocrystals and graphene. Comparing with the S–G mixture, the NanoS@G composite shows highly improved electrochemical performance as cathode for lithium–sulfur (Li–S) battery. The NanoS@G composite delivers an initial capacity of 1400 mAh g?1 with the sulfur utilization of 83.7% at a current density of 335 mA g?1. The capacity keeps above 720 mAh g?1 over 100 cycles. The strong adherence of the sulfur nanocrystals on graphene immobilizes sulfur and polysulfides species and suppressed the “shuttle effect”, resulting higher coulombic efficiency and better capacity retention. Electrochemical impedance also suggests that the strong bonding enabled rapid electronic/ionic transport and improved electrochemical kinetics, therefore good rate capability is obtained. These results demonstrate that the NanoS@G composite is a very promising candidate for high-performance Li–S batteries.

Jun Zhang; Zimin Dong; Xiuli Wang; Xuyang Zhao; Jiangping Tu; Qingmei Su; Gaohui Du

2014-01-01T23:59:59.000Z

72

Sorbent Injection for Small ESP Mercury Control in Low Sulfur Eastern Bituminous Coal Flue Gas  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Sorbent InjectIon for Small eSP Sorbent InjectIon for Small eSP mercury control In low Sulfur eaStern bItumInouS coal flue GaS Background Full-scale field testing has demonstrated the effectiveness of activated carbon injection (ACI) as a mercury-specific control technology for certain coal-fired power plants, depending on the plant's coal feedstock and existing air pollution control device configuration. In a typical configuration, powdered activated carbon (PAC) is injected downstream of the plant's air heater and upstream of the existing particulate control device - either an electrostatic precipitator (ESP) or a fabric filter (FF). The PAC adsorbs the mercury from the combustion flue gas and is subsequently captured along with the fly ash in the ESP or FF. ACI can have some negative side

73

Synthesis and development of processes for the recovery of sulfur from acid gases. Part 1, Development of a high-temperature process for removal of H{sub 2}S from coal gas using limestone -- thermodynamic and kinetic considerations; Part 2, Development of a zero-emissions process for recovery of sulfur from acid gas streams  

SciTech Connect (OSTI)

Limestone can be used more effectively as a sorbent for H{sub 2}S in high-temperature gas-cleaning applications if it is prevented from undergoing calcination. Sorption of H{sub 2}S by limestone is impeded by sintering of the product CaS layer. Sintering of CaS is catalyzed by CO{sub 2}, but is not affected by N{sub 2} or H{sub 2}. The kinetics of CaS sintering was determined for the temperature range 750--900{degrees}C. When hydrogen sulfide is heated above 600{degrees}C in the presence of carbon dioxide elemental sulfur is formed. The rate-limiting step of elemental sulfur formation is thermal decomposition of H{sub 2}S. Part of the hydrogen thereby produced reacts with CO{sub 2}, forming CO via the water-gas-shift reaction. The equilibrium of H{sub 2}S decomposition is therefore shifted to favor the formation of elemental sulfur. The main byproduct is COS, formed by a reaction between CO{sub 2} and H{sub 2}S that is analogous to the water-gas-shift reaction. Smaller amounts of SO{sub 2} and CS{sub 2} also form. Molybdenum disulfide is a strong catalyst for H{sub 2}S decomposition in the presence of CO{sub 2}. A process for recovery of sulfur from H{sub 2}S using this chemistry is as follows: Hydrogen sulfide is heated in a high-temperature reactor in the presence of CO{sub 2} and a suitable catalyst. The primary products of the overall reaction are S{sub 2}, CO, H{sub 2} and H{sub 2}O. Rapid quenching of the reaction mixture to roughly 600{degrees}C prevents loss Of S{sub 2} during cooling. Carbonyl sulfide is removed from the product gas by hydrolysis back to CO{sub 2} and H{sub 2}S. Unreacted CO{sub 2} and H{sub 2}S are removed from the product gas and recycled to the reactor, leaving a gas consisting chiefly of H{sub 2} and CO, which recovers the hydrogen value from the H{sub 2}S. This process is economically favorable compared to the existing sulfur-recovery technology and allows emissions of sulfur-containing gases to be controlled to very low levels.

Towler, G.P.; Lynn, S.

1993-05-01T23:59:59.000Z

74

Graphene-Wrapped Sulfur Particles as a Rechargeable Lithium–Sulfur Battery Cathode Material with High Capacity and Cycling Stability  

Science Journals Connector (OSTI)

Graphene-Wrapped Sulfur Particles as a Rechargeable Lithium–Sulfur Battery Cathode Material with High Capacity and Cycling Stability ... The resulting graphene–sulfur composite showed high and stable specific capacities up to ?600 mAh/g over more than 100 cycles, representing a promising cathode material for rechargeable lithium batteries with high energy density. ...

Hailiang Wang; Yuan Yang; Yongye Liang; Joshua Tucker Robinson; Yanguang Li; Ariel Jackson; Yi Cui; Hongjie Dai

2011-06-24T23:59:59.000Z

75

Coal-oil slurry preparation  

DOE Patents [OSTI]

A pumpable slurry of pulverized coal in a coal-derived hydrocarbon oil carrier which slurry is useful as a low-ash, low-sulfur clean fuel, is produced from a high sulfur-containing coal. The initial pulverized coal is separated by gravity differentiation into (1) a high density refuse fraction containing the major portion of non-coal mineral products and sulfur, (2) a lowest density fraction of low sulfur content and (3) a middlings fraction of intermediate sulfur and ash content. The refuse fraction (1) is gasified by partial combustion producing a crude gas product from which a hydrogen stream is separated for use in hydrogenative liquefaction of the middlings fraction (3). The lowest density fraction (2) is mixed with the liquefied coal product to provide the desired fuel slurry. Preferably there is also separately recovered from the coal liquefaction LPG and pipeline gas.

Tao, John C. (Perkiomenville, PA)

1983-01-01T23:59:59.000Z

76

Ancillary operations in coal preparation instrumentation on-line low cost sulfur and ash analyzer  

SciTech Connect (OSTI)

A program of design, fabrication, and field testing of an on-line sulfur and ash analyzer was undertaken by The Babcock Wilcox Company. The analyzer is intended for use on coal slurry streams such as those found at coal cleaning facilities. The analyzer design consists of a sample preparation and delivery system (SPAD) and an inductively coupled plasma atomic emission spectrometer (ICP-AES). The program consisted of the following major tasks: Selection and screening of delivery systems; Design of the analyzer system; Fabrication of SPAD system; Field testing of the SPAD system; and Laboratory ICP testing of field collected samples. The field testing was conducted at CQ Inc., (Homer City, Pa. pilot plant). Testing was completed without taking the ICP to the field, since the analysis of coal slurry by ICP had been demonstrated during the delivery system screening tests and the field tests were aimed primarily at demonstrating the performance of the SPAD system. Although the ICP was not deployed to the field, the subsequent laboratory testing of field collected samples simulated the performance of the entire system. 16 refs., 103 figs., 38 tabs.

Malito, M.L.

1991-07-01T23:59:59.000Z

77

Analyzing organic sulfur in coal/char: Integrated mild degradation/XANES methods. Final technical report, September 1, 1993--November 30, 1994  

SciTech Connect (OSTI)

The overall goal of this study is to improve the understanding of sulfur in coals/chars via the use of combined advanced nondestructive and advanced destructive methods of sulfur analysis. This study combines selective oxidation, analytical pyrolysis, and sulfur X-ray Absorption Near Edge Structure Spectroscopy (XANES) analysis. Samples with a wide variety of sulfur contents, (0.63%--4.40%) have been prepared for use in this study. This includes steam gasification chars, oxidized coals and desulfurized coals as well of the original unaltered coals. Mild pyrolysis and XANES data shows that the sulfur chemistry of gasification chars is significantly different from that of the original coals. Mild pyrolysis of the samples that were oxidized with peroxyacetic acid showed that the level of simple thiophene structures observed in the pyrolysis products declines with increasing levels of oxidation. Sulfur XANES spectra of treated samples showed various effects depending on the treatment severity. The XANES spectra of less severely treated samples were similar, although not identical, to the untreated coal spectra. XANES of gasification chars indicated conversion of pyrite to pyrrhotite, removal of organic sulfide sulfur and dissolution of soluble inorganic sulfur species during gasification. Mild oxidation with peroxyacetic acid results in preferential oxidation of sulfide forms before thiophene forms but increasing oxidation severity leads to virtually all sulfur species being oxidized. Good agreement between W-band EPR and XANES data for aromatic sulfur contents were obtained. The TPR analysis of coal indicated that organic sulfur was present as alkyl-aryl sulfide, aryl-aryl sulfides, simple thiophenes and condensed thiophenes. TPR shows that non-thiophenic compounds are removed by PAA oxidation, and that the longer the oxidation is performed the greater is the removal of non-thiophenic sulfur structures.

Palmer, S.R. [Southern Illinois Univ., Carbondale, IL (United States); Huffman, G.P. [Univ. of Kentucky, Lexington, KY (United States)

1994-12-31T23:59:59.000Z

78

Sulfur/three-dimensional graphene composite for high performance lithium–sulfur batteries  

Science Journals Connector (OSTI)

Abstract A sulfur/graphene composite is prepared by loading elemental sulfur into three-dimensional graphene (3D graphene), which is assembled using a metal ions assisted hydrothermal method. When used as cathode materials for lithium–sulfur (Li–S) batteries, the sulfur/graphene composite (S@3D-graphene) with 73 wt % sulfur shows a significantly enhanced cycling performance (>700 mAh g?1 after 100 cycles at 0.1C rate with a Coulombic efficiency > 96%) as well as high rate capability with a capacity up to 500 mAh g?1 at 2C rate (3.35 A g?1). The superior electrochemical performance could be attributed to the highly porous structure of three-dimensional graphene that not only enables stable and continue pathway for rapid electron and ion transportation, but also restrain soluble polysulfides and suppress the “shuttle effect”. Moreover, the robust structure of 3D graphene can keep cathode integrity and accommodate the volume change during high-rate charge/discharge processes, making it a promising candidate as cathode for high performance Li–S batteries.

Chunmei Xu; Yishan Wu; Xuyang Zhao; Xiuli Wang; Gaohui Du; Jun Zhang; Jiangping Tu

2015-01-01T23:59:59.000Z

79

Direct Determination of Pyrite Content in Argonne Premium Coals by the Use of Sulfur X-ray Near Edge Absorption Spectroscopy (S-XANES)  

Science Journals Connector (OSTI)

Direct Determination of Pyrite Content in Argonne Premium Coals by the Use of Sulfur X-ray Near Edge Absorption Spectroscopy (S-XANES) ... Argonne National Laboratory, Argonne, Illinois 60439 ... Argonne premium coal samples are used by researchers worldwide as standards in coal research. ...

Trudy B. Bolin

2010-10-01T23:59:59.000Z

80

Analysis of organic sulfur and nitrogen in coal via tandem degradation methods. Final technical report, 1 September 1991--31 October 1992  

SciTech Connect (OSTI)

With the recent increase in concern for environmental issues and the implication of sulfur and nitrogen in coal combustion preducts as prime causes of acid rain, it has become clear that there is an urgent need for alternative methods for determining the nature of organic sulfur and nitrogen compounds in coal. The principal impediment to the molecular characterization of organic sulfur and nitrogen forms in coal is the polymeric nature of coal`s molecular structure, rendering coal insoluble and impossible to analyze by the necessary gas chromatographic (GC) methods. In our research, we apply mild chemical degradation techniques in order to render coal soluble in common organic solvents and thus amenable to standard GC characterization. The study also seeks to apply the degradative techniques to coal asphaltenes, since they are believed to be polymeric structures similar to the whole coal, but smaller and more readily analyzed. Of the degradation techniques used to date, oxidation by sodium dichromate provides the best chemical structure information. A variety of major sulfur compounds were detected in the dichromate oxidation products of demineralized IBC101 coal, including thiazoles (compounds which contains both sulfur and nitrogen) and a series of isomers of C{sub 2}-, C{sub 3}- and C{sub 4}-alkylthiophene derivatives. Precise agreement between GC-MS and sulfur-selective GC-FPD data was obtained for these compounds, which probably originated as short alkyl chains on exterior portions of the original peat macromolecular structure that were sulfurized shortly after burial by H{sub 2}S. The results were further confirmed by the analysis of a non-Illinois Basin coal with nearly twice the organic sulfur content of IBC101.

Kruge, M.A.; Palmer, S.R. [Southern Illinois Univ., Carbondale, IL (United States)

1992-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Removal of organic and inorganic sulfur from Ohio coal by combined physical and chemical process. Final report  

SciTech Connect (OSTI)

This project consisted of three sections. In the first part, the physical cleaning of Ohio coal by selective flocculation of ultrafine slurry was considered. In the second part, the mild oxidation process for removal of pyritic and organic sulfur.was investigated. Finally, in-the third part, the combined effects of these processes were studied. The physical cleaning and desulfurization of Ohio coal was achieved using selective flocculation of ultrafine coal slurry in conjunction with froth flotation as flocs separation method. The finely disseminated pyrite particles in Ohio coals, in particular Pittsburgh No.8 seam, make it necessary to use ultrafine ({minus}500 mesh) grinding to liberate the pyrite particles. Experiments were performed to identify the ``optimum`` operating conditions for selective flocculation process. The results indicated that the use of a totally hydrophobic flocculant (FR-7A) yielded the lowest levels of mineral matters and total sulfur contents. The use of a selective dispersant (PAAX) increased the rejection of pyritic sulfur further. In addition, different methods of floc separation techniques were tested. It was found that froth flotation system was the most efficient method for separation of small coal flocs.

Attia, Y.A.; Zeky, M.El.; Lei, W.W.; Bavarian, F.; Yu, S. [Ohio State Univ., Columbus, OH (United States). Dept. of Materials Science and Engineering

1989-04-28T23:59:59.000Z

82

Reducing the sulfur content of coke by increasing the content of thermally conditioned g coal in the batch  

Science Journals Connector (OSTI)

In periods of economic growth, Ukrainian coke plants face a shortage of Zh and K coal, because of the high demand. In periods of economic stagnation, conversely, there is an excess of Zh coal, on account of the d...

E. I. Malyi

2014-05-01T23:59:59.000Z

83

Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...  

Broader source: Energy.gov (indexed) [DOE]

May 2011 CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries "This presentation does not contain any proprietary, confidential, or otherwise...

84

Analysis of organic sulfur and nitrogen in coal via tandem degradation methods. [Quarterly] technical report, 1 March--31 May 1992  

SciTech Connect (OSTI)

Sporinite, vitrinite and semi-fusinite single macerals were separated from the IBC 101 coal by the density gradient technique. In addition, a gel permeation chromatography (GPC) system was assembled and the GPC column calibrated with four polystyrene molecular weight standards. A variety of sulfur compounds were identified in the dichromate oxidation products of the IBC 101 coal, including a thiazole and isomers of C2-, C3- and C4-alkyl thiophene carboxylic acids. Precise agreement between GC-MS and FPD chromatograms were obtained for these compounds. These compounds probably originated as short alkyl chains on exterior portions of the original peat macromolecular structures and were sulfurized by H{sub 2}S shortly after burial. Thus the dichromate oxidation appears useful for the characterization of sulfur compounds. Unfortunately, this treatment yields only small amounts of products, but the reaction is relatively mild. On the other hand the peroxyacetic acid gives a very good yield in only a single step, but seems to be very degradative. It was difficult to isolate the products after lithium aluminum hydride reduction of oxidation products. It is believed that this is due to the formation of polyalcohols from polycarboxyl compounds. However polyalcohols were successfully converted to their parent hydrocarbons by the LAH reduction of tosylate intermediates. This allows for much easier separation and characterization and leads to enhanced elucidation of coal structures. To test the hypothesis that asphaltenes are similar in structure to their parent coal, IBC101 asphaltenes and the extracted coal were subjected to PAA oxidation and analytical pyrolysis. The PAA products as well as the pyrolysates show very good correlation. This indicates a very strong relationship between the organic structure of the coal and that of the asphaltenes derived from them.

Kruge, M.A.; Palmer, S.R.; Baudet, N.

1992-10-01T23:59:59.000Z

85

EIS-0004: Coal Loan Guarantee Program (P.L. 94-163)  

Broader source: Energy.gov [DOE]

The U.S. Department of Energy prepared this EIS to address the potential impacts of implementing the Coal Loan Guarantee Program to encourage the production of low and high sulfur coal by small underground coal producers.

86

Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds  

E-Print Network [OSTI]

removal from flue gas of coal-fired power plants. Environ.Speciation in a 100-MW Coal-Fired Boiler with Low-NOxControl Technologies for Coal-Fired Power Plants, DOE/NETL

Miller, Nai-Qiang Yan-Zan Qu Yao Chi Shao-Hua Qiao Ray Dod Shih-Ger Chang Charles

2008-01-01T23:59:59.000Z

87

DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS  

E-Print Network [OSTI]

Pollutants Associated With Coal Combustion. • E.P.A.Control Guidelines for Coal-Derived Pollutants .Forms of Sulfur in Coal • . . . . Coal Desulfurization

Wrathall, James Anthony

2011-01-01T23:59:59.000Z

88

Fate of Sulfur, Chlorine, Alkali Metal, and Vanadium Species during High-Temperature Gasification of Canadian Tar Sand Products  

Science Journals Connector (OSTI)

Co-feed of alternative fuels, e.g., petcoke, gains increasing importance for energy conversion in not only Germany but also worldwide. ... The aim of this work was to obtain detailed information on the influence of fuel composition of the refinery product line tar sand, bitumen, and petcoke in comparison to the standard fuel hard coal on the release of sodium, potassium, chlorine, sulfur, and vanadium species during high-temperature gasification. ... In addition to the pure fuels, blends of hard coal and petcoke were gasified in lab-scale experiments in a helium/oxygen atmosphere at 1500 °C. ...

Marc Bläsing; Kaveh Nazeri; Michael Müller

2014-10-01T23:59:59.000Z

89

Chemical comminution of coal  

SciTech Connect (OSTI)

The objective of the present research is to study the chemical reactivity of a mixture of methyl alcohol and aqueous sodium hydroxide solution in the temperature range 298 to 363 K, and a caustic concentration of 0 to 10 wt. %, on an Iowa bituminous coal. The sample studied was collected from coal zone 4, equivalent to most historical references to Laddsdale coal. The coals in this zone are typical high-sulfur, high-ash middle Pennsylvania Cherokee group coals. The apparent rank is high-volatile C bituminous coal. The relatively high content of sulfur and 23 other elements in these coals is related to near neutral (6-8) pH conditions in the depositional and early diagenetic environments, and to postdepositional sphalerite/calcite/pyrite/kaolinite/barite mineralization.

Mamaghani, A.H.; Beddow, J.K.; Vetter, A.F.

1987-02-01T23:59:59.000Z

90

HIGH PRESSURE COAL COMBUSTON KINETICS PROJECT  

SciTech Connect (OSTI)

As part of the U.S. Department of Energy (DoE) initiative to improve the efficiency of coal-fired power plants and reduce the pollution generated by these facilities, DOE has funded the High-Pressure Coal Combustion Kinetics (HPCCK) Projects. A series of laboratory experiments were conducted on selected pulverized coals at elevated pressures with the specific goals to provide new data for pressurized coal combustion that will help extend to high pressure and validate models for burnout, pollutant formation, and generate samples of solid combustion products for analyses to fill crucial gaps in knowledge of char morphology and fly ash formation. Two series of high-pressure coal combustion experiments were performed using SRI's pressurized radiant coal flow reactor. The first series of tests characterized the near burner flame zone (NBFZ). Three coals were tested, two high volatile bituminous (Pittsburgh No.8 and Illinois No.6), and one sub-bituminous (Powder River Basin), at pressures of 1, 2, and 3 MPa (10, 20, and 30 atm). The second series of experiments, which covered high-pressure burnout (HPBO) conditions, utilized a range of substantially longer combustion residence times to produce char burnout levels from 50% to 100%. The same three coals were tested at 1, 2, and 3 MPa, as well as at 0.2 MPa. Tests were also conducted on Pittsburgh No.8 coal in CO2 entrainment gas at 0.2, 1, and 2 MPa to begin establishing a database of experiments relevant to carbon sequestration techniques. The HPBO test series included use of an impactor-type particle sampler to measure the particle size distribution of fly ash produced under complete burnout conditions. The collected data have been interpreted with the help of CFD and detailed kinetics simulation to extend and validate devolatilization, char combustion and pollutant model at elevated pressure. A global NOX production sub-model has been proposed. The submodel reproduces the performance of the detailed chemical reaction mechanism for the NBFZ tests.

Stefano Orsino

2005-03-30T23:59:59.000Z

91

High pressure sulfuric acid decomposition experiments for the sulfur-iodine thermochemical cycle.  

SciTech Connect (OSTI)

A series of three pressurized sulfuric acid decomposition tests were performed to (1) obtain data on the fraction of sulfuric acid catalytically converted to sulfur dioxide, oxygen, and water as a function of temperature and pressure, (2) demonstrate real-time measurements of acid conversion for use as process control, (3) obtain multiple measurements of conversion as a function of temperature within a single experiment, and (4) assess rapid quenching to minimize corrosion of metallic components by undecomposed acid. All four of these objectives were successfully accomplished. This report documents the completion of the NHI milestone on high pressure H{sub 2}SO{sub 4} decomposition tests for the Sulfur-Iodine (SI) thermochemical cycle project. All heated sections of the apparatus, (i.e. the boiler, decomposer, and condenser) were fabricated from Hastelloy C276. A ceramic acid injection tube and a ceramic-sheathed thermocouple were used to minimize corrosion of hot liquid acid on the boiler surfaces. Negligible fracturing of the platinum on zirconia catalyst was observed in the high temperature decomposer. Temperature measurements at the exit of the decomposer and at the entry of the condenser indicated that the hot acid vapors were rapidly quenched from about 400 C to less than 20 C within a 14 cm length of the flow path. Real-time gas flow rate measurements of the decomposition products provided a direct measurement of acid conversion. Pressure in the apparatus was preset by a pressure-relief valve that worked well at controlling the system pressure. However, these valves sometimes underwent abrupt transitions that resulted in rapidly varying gas flow rates with concomitant variations in the acid conversion fraction.

Velasquez, Carlos E; Reay, Andrew R.; Andazola, James C.; Naranjo, Gerald E.; Gelbard, Fred

2005-09-01T23:59:59.000Z

92

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 3: SOx/NOx/Hg Removal for Low Sulfur Coal  

SciTech Connect (OSTI)

The goal of this project was to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxycombustion technology. The objective of Task 3 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning low sulfur coal in oxy-combustion power plants. The goal of the program was to conduct an experimental investigation and to develop a novel process for simultaneously removal of SOx and NOx from power plants that would operate on low sulfur coal without the need for wet-FGD & SCRs. A novel purification process operating at high pressures and ambient temperatures was developed. Activated carbonâ??s catalytic and adsorbent capabilities are used to oxidize the sulfur and nitrous oxides to SO{sub 3} and NO{sub 2} species, which are adsorbed on the activated carbon and removed from the gas phase. Activated carbon is regenerated by water wash followed by drying. The development effort commenced with the screening of commercially available activated carbon materials for their capability to remove SO{sub 2}. A bench-unit operating in batch mode was constructed to conduct an experimental investigation of simultaneous SOx and NOx removal from a simulated oxyfuel flue gas mixture. Optimal operating conditions and the capacity of the activated carbon to remove the contaminants were identified. The process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx. In the longevity tests performed on a batch unit, the retention capacity could be maintained at high level over 20 cycles. This process was able to effectively remove up to 4000 ppm SOx from the simulated feeds corresponding to oxyfuel flue gas from high sulfur coal plants. A dual bed continuous unit with five times the capacity of the batch unit was constructed to test continuous operation and longevity. Full-automation was implemented to enable continuous operation (24/7) with minimum operator supervision. Continuous run was carried out for 40 days. Very high SOx (>99.9%) and NOx (98%) removal efficiencies were also achieved in a continuous unit. However, the retention capacity of carbon beds for SOx and NOx was decreased from ~20 hours to ~10 hours over a 40 day period of operation, which was in contrast to the results obtained in a batch unit. These contradictory results indicate the need for optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level and thus minimize the capital cost of the system. In summary, the activated carbon process exceeded performance targets for SOx and NOx removal efficiencies and it was found to be suitable for power plants burning both low and high sulfur coals. More efforts are needed to optimize the system performance.

Monica Zanfir; Rahul Solunke; Minish Shah

2012-06-01T23:59:59.000Z

93

Advances of flue gas desulfurization technology for coal-fired boilers and strategies for sulfur dioxide pollution prevention in China  

SciTech Connect (OSTI)

Coal is one of the most important kinds of energy resources at the present time and in the immediate future in China. Sulfur dioxide resulting from combustion of coal is one of the principle pollutants in the air. Control of SO{sub 2} discharge is still a major challenge for environmental protection in developing China. In this paper, research, development and application of technology of flue gas desulfurization (FGD) for coal-fired boilers in China will be reviewed with emphasis on cost-effective technology, and the development trends of FGD technology, as well as the strategy for SO{sub 2} discharge control in China, will be analyzed. A practical technology for middle-small-sized boilers developed by the primary author and the field investigation results will also be presented. At present, there are four major kinds of FGD technologies that are practical to be applied in China for their cost-effectiveness and efficiency to middle-small-sized boilers. An important development trend of the FGD technology for middle-small-sized boilers for the next decade is improvement of the existing cost-effective wet-type FGD technology, and in the future it will be the development of dry-type FGD technology. For middle-sized generating boilers, the development direction of the FGD technology is the spraying and drying process. For large-sized generating boilers, the wet-type limestone-plaster process will still be applied in the immediate future, and dry-type FGD technologies, such as ammonia with electron beam irradiation, will be developed in the future. State strategies for the control of SO{sub 2} discharge will involve the development and popularization of efficient coal-fired devices, extension of gas coal and liquefied coal, spreading coal washing, and centralized heating systems.

Yang, C.; Zeng, G.; Li, G.; Qiu, J.

1999-07-01T23:59:59.000Z

94

ADVANCED SULFUR CONTROL CONCEPTS  

SciTech Connect (OSTI)

Conventional sulfur removal in integrated gasification combined cycle (IGCC) power plants involves numerous steps: COS (carbonyl sulfide) hydrolysis, amine scrubbing/regeneration, Claus process, and tail-gas treatment. Advanced sulfur removal in IGCC systems involves typically the use of zinc oxide-based sorbents. The sulfides sorbent is regenerated using dilute air to produce a dilute SO{sub 2} (sulfur dioxide) tail gas. Under previous contracts the highly effective first generation Direct Sulfur Recovery Process (DSRP) for catalytic reduction of this SO{sub 2} tail gas to elemental sulfur was developed. This process is currently undergoing field-testing. In this project, advanced concepts were evaluated to reduce the number of unit operations in sulfur removal and recovery. Substantial effort was directed towards developing sorbents that could be directly regenerated to elemental sulfur in an Advanced Hot Gas Process (AHGP). Development of this process has been described in detail in Appendices A-F. RTI began the development of the Single-step Sulfur Recovery Process (SSRP) to eliminate the use of sorbents and multiple reactors in sulfur removal and recovery. This process showed promising preliminary results and thus further process development of AHGP was abandoned in favor of SSRP. The SSRP is a direct Claus process that consists of injecting SO{sub 2} directly into the quenched coal gas from a coal gasifier, and reacting the H{sub 2}S-SO{sub 2} mixture over a selective catalyst to both remove and recover sulfur in a single step. The process is conducted at gasifier pressure and 125 to 160 C. The proposed commercial embodiment of the SSRP involves a liquid phase of molten sulfur with dispersed catalyst in a slurry bubble-column reactor (SBCR).

Apostolos A. Nikolopoulos; Santosh K. Gangwal; William J. McMichael; Jeffrey W. Portzer

2003-01-01T23:59:59.000Z

95

Energy Policy Act transportation rate study: Interim report on coal transportation  

SciTech Connect (OSTI)

The primary purpose of this report is to examine changes in domestic coal distribution and railroad coal transportation rates since enactment of the Clean Air Act Amendments of 1990 (CAAA90). From 1988 through 1993, the demand for low-sulfur coal increased, as a the 1995 deadline for compliance with Phase 1 of CAAA90 approached. The shift toward low-sulfur coal came sooner than had been generally expected because many electric utilities switched early from high-sulfur coal to ``compliance`` (very low-sulfur) coal. They did so to accumulate emissions allowances that could be used to meet the stricter Phase 2 requirements. Thus, the demand for compliance coal increased the most. The report describes coal distribution and sulfur content, railroad coal transportation and transportation rates, and electric utility contract coal transportation trends from 1979 to 1993 including national trends, regional comparisons, distribution patterns and regional profiles. 14 figs., 76 tabs.

NONE

1995-10-01T23:59:59.000Z

96

Composition and properties of coals from the Yurty coal occurrence  

SciTech Connect (OSTI)

Coals from the Yurty coal occurrence were studied. It was found that the samples were brown non-coking coals with low sulfur contents (to 1%) and high yields of volatile substances. The high heat value of coals was 20.6-27.7 MJ/kg. The humic acid content varied from 5.45 to 77.62%. The mineral matter mainly consisted of kaolinite, a-quartz, and microcline. The concentration of toxic elements did not reach hazardous values.

N.G. Vyazova; L.N. Belonogova; V.P. Latyshev; E.A. Pisar'kova [Irkutsk State University, Irkutsk (Russia). Research Institute of Oil and Coal Chemistry and Synthesis

2008-10-15T23:59:59.000Z

97

High-pressure coal fuel processor development  

SciTech Connect (OSTI)

Caterpillar shares DOE/METC interest in demonstrating the technology required to displace petroleum-based engine fuels with various forms of low cost coal. Current DOE/METC programs on mild gasification and coal-water-slurries are addressing two approaches to this end. Engine and fuel processor system concept studies by Caterpillar have identified a third, potentially promising, option. This option includes high-pressure fuel processing of run-of-the-mine coal and direct injection of the resulting low-Btu gas stream into an ignition assisted, high compression ratio diesel engine. The compactness and predicted efficiency of the system make it suitable for application to line-haul railroad locomotives. Two overall conclusions resulted from Task 1. First direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risk associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept. The significant conclusions from Task 2 were: An engine concept, derived from a Caterpillar 3600 series engine, and a fuel processor concept, based on scaling up a removable-canister configuration from the test rig, appear feasible; and although the results of this concept study are encouraging, further, full-scale component research and development are required before attempting a full-scale integrated system demonstration effort.

Greenhalgh, M.L. (Caterpillar, Inc., Peoria, IL (United States))

1992-12-01T23:59:59.000Z

98

Reductive burning of high-yield spent pulping liquors by the addition of pulverized coal  

SciTech Connect (OSTI)

This paper reports on the reductive burning of high-yield spent pulping liquors which can be accomplished by the addition of pulverized coal to increase the heat content and generate the proper reducing conditions. Samples from a 78%-yield sodium bisulfite pulping process employing a hardwood furnish were mixed with 10-50% pulveriized coal and burned at 950[degrees]C under reducing conditions in a box furnace. Even in these uncontrolled combustion conditions 76. 5% of the sulfur found in the soluble portion of the smelt was converted from lignousulfonates to useful sulfide ion. For the remainder of the sulfur, analyses determined it to be 19. 5% as sulfite ion, 3. 1% as thiosulfate ion, and 0.9% as sulfate ion.

Sell, N.J.; Norman, J.C. (Natural and Applied Sciences, Univ. of Wisconsin-Green Bay, Green Bay, WI (United States))

1992-10-01T23:59:59.000Z

99

Distribution of hazardous air pollutant trace elements, total sulfur, and ash in coals from five Tertiary basins in the Rocky Mountain Region  

SciTech Connect (OSTI)

Arithmetic mean values of the contents of hazardous air pollutant (HAP) trace elements named in the 1990 Clean Air Act Amendments (antimony, arsenic, beryllium, cadmium, chromium, cobalt, lead, manganese, mercury, nickel, selenium, and uranium), ash, and total sulfur were statistically compared on a whole-coal basis for Paleocene coals from five Tertiary basins in the Rocky Mountain Region. The study of proximate and elemental analyses indicate a relationship between trace element contents and paleogeography.

Ellis, M.S.; Stricker, G.D.; Flores, R.M. [Geological Survey, Denver, CO (United States)

1994-12-31T23:59:59.000Z

100

High Permeability Ternary Palladium Alloy Membranes with Improved Sulfur and Halide Tolerance  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

9 9 HigH Permeability ternary Palladium alloy membranes witH imProved sulfur and Halide tolerance Description A critical step in the transition to the hydrogen economy is the separation of hydrogen from coal gasification gases (syngas) or methane. This is typically accomplished through membrane separation. Past research has shown that palladium (Pd) alloys possess great potential as robust and economical membranes. However, the search for the optimal binary or ternary alloys is an involved and costly process due to the immense number of alloy variations that could be prepared and tested. Recent modeling work at Georgia Institute of Technology using density functional theory (DFT) identified several promising ternary alloy compositions with improved

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Ash limitation of physical coal beneficiation for medium–high ash coal—A geochemistry perspective  

Science Journals Connector (OSTI)

Abstract Nowadays the industrial coal beneficiation in China could only reduce the ash yield to about 10%, which could not meet the requirement or standard of environment protection. In this work, the possibility of reducing the ash yield was studied from the aspect of geochemistry. The channel samples were collected from two coal seams in Guizhou and Shanxi province, China and then conducted analysis by combining data from coals worldwide. The result reveals that the same coal seam or the coals deposited in the same peat swamp show a significantly positive correlation between ash yield and Al2O3 + SiO2 content, and the intercept of regression equation on the ash axis is always less than 5% (generally 2–5%). Overall, the coal from China is featured with a higher intercept compared with that in the other countries. The intercept of 2–5% on the ash axis indicates an original inorganic component in coal-forming peat. The research result also presents a theoretical limitation of coal ash by coal cleaning, because 2–5% of inorganic components in medium–high quality ash coal could hardly be separated by traditional physical coal beneficiation.

Wenfeng Wang; Weiduo Hao; Simon Xu; Fuchang Qian; Shuxun Sang; Yong Qin

2014-01-01T23:59:59.000Z

102

Integrated Process Configuration for High-Temperature Sulfur Mitigation during Biomass Conversion via Indirect Gasification  

SciTech Connect (OSTI)

Sulfur present in biomass often causes catalyst deactivation during downstream operations after gasification. Early removal of sulfur from the syngas stream post-gasification is possible via process rearrangements and can be beneficial for maintaining a low-sulfur environment for all downstream operations. High-temperature sulfur sorbents have superior performance and capacity under drier syngas conditions. The reconfigured process discussed in this paper is comprised of indirect biomass gasification using dry recycled gas from downstream operations, which produces a drier syngas stream and, consequently, more-efficient sulfur removal at high temperatures using regenerable sorbents. A combination of experimental results from NREL's fluidizable Ni-based reforming catalyst, fluidizable Mn-based sulfur sorbent, and process modeling information show that using a coupled process of dry gasification with high-temperature sulfur removal can improve the performance of Ni-based reforming catalysts significantly.

Dutta. A.; Cheah, S.; Bain, R.; Feik, C.; Magrini-Bair, K.; Phillips, S.

2012-06-20T23:59:59.000Z

103

ZINC CHLORIDE-CATALYZED REACTIONS OF OXYGEN- AND SULFUR-CONTAINING COMPOUNDS WITH MODEL STRUCTURES IN COAL  

E-Print Network [OSTI]

H. H. , ed. , "Chemistry of Coal Utilization", Suppl. Vol. ,H. H. , ed. , "Chemistry of Coal Utilization", Suppl. Vol. ,Internat. Conf. Bituminous Coal, 3d Con£. , 2, 35 (1932);

Mobley, David Paul

2013-01-01T23:59:59.000Z

104

DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS  

E-Print Network [OSTI]

fixation in slag or bottom ash, coal gasification, or coallimestone and coal that form little fly ash and trap sulfurSulfate Organic Ash (%) "Organic Sulfur", in Wheelock, Coal

Wrathall, James Anthony

2011-01-01T23:59:59.000Z

105

Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds  

SciTech Connect (OSTI)

Oxidation of Hg0 with any oxidant or converting it to a particle-bound form can facilitate its removal. Two sulfur-chlorine compounds, sulfur dichloride (SCl2) and sulfur monochloride (S2Cl2), were investigated as oxidants for Hg0 by gas phase reaction and by surface-involved reactions in the presence of flyash or activated carbon. The gas phase reaction rate constants between Hg0 and the sulfur/chlorine compounds were determined, and the effects of temperature and the main components in flue gases were studied. The gas phase reaction between Hg0 and SCl2 is shown to be more rapid than the gas phase reaction with chlorine, and the second order rate constant was 9.1(+-0.5) x 10-18 mL-molecules-1cdots-1 at 373oK. Nitric oxide (NO) inhibited the gas phase reaction of Hg0 with sulfur-chlorine compounds. The presence of flyash or powdered activated carbon in flue gas can substantially accelerate the reaction. The predicted Hg0 removal is about 90percent with 5 ppm SCl2 or S2Cl2 and 40 g/m3 of flyash in flue gas. The combination of activated carbon and sulfur-chlorine compounds is an effective alternative. We estimate that co-injection of 3-5 ppm of SCl2 (or S2Cl2) with 2-3 Lb/MMacf of untreated Darco-KB is comparable in efficiency to the injection of 2-3 Lb/MMacf Darco-Hg-LH. Extrapolation of kinetic results also indicates that 90percent of Hg0 can be removed if 3 Lb/MMacf of Darco-KB pretreated with 3percent of SCl2 or S2Cl2 is used. Unlike gas phase reactions, NO exhibited little effect on Hg0 reactions with SCl2 or S2Cl2 on flyash or activated carbon. Mercuric sulfide was identified as one of the principal products of the Hg0/SCl2 or Hg0/S2Cl2 reactions. Additionally, about 8percent of SCl2 or S2Cl2 in aqueous solutions is converted to sulfide ions, which would precipitate mercuric ion from FGD solution.

Chang, Shih-Ger; Yan, Nai-Qiang; Qu, Zan; Chi, Yao; Qiao, Shao-Hua; Dod, Ray; Chang, Shih-Ger; Miller, Charles

2008-07-02T23:59:59.000Z

106

Catalytic steam gasification of coals  

Science Journals Connector (OSTI)

Catalytic steam gasification of coals ... Steam–Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture ... Steam–Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture ...

P. Pereira; G. A. Somorjai; H. Heinemann

1992-07-01T23:59:59.000Z

107

Today's high coal prices: correction or crisis?  

SciTech Connect (OSTI)

Eastern spot prices for coal have risen 25% since the start of 2004, reaching their highest levels in more than 25 years. This spike represents the second time in four years that coal prices have risen to more than double their pre-2000 price levels. Years of famine (from a coal producer's point of view) have been replaced by periods of plenty, with increasing consequences for coal's customers. How long will this spike last? This article, based on studies carried out by EPRI, attempts to answer this question. 3 figs., 1 tab.

Platt, J. [EPRI (US)

2005-06-01T23:59:59.000Z

108

Innovative Drying Technology Extracts More Energy from High Moisture Coal |  

Broader source: Energy.gov (indexed) [DOE]

Innovative Drying Technology Extracts More Energy from High Innovative Drying Technology Extracts More Energy from High Moisture Coal Innovative Drying Technology Extracts More Energy from High Moisture Coal March 11, 2010 - 12:00pm Addthis Washington, DC - An innovative coal-drying technology that will extract more energy from high moisture coal at less cost and simultaneously reduce potentially harmful emissions is ready for commercial use after successful testing at a Minnesota electric utility. The DryFining(TM) technology was developed with funding from the first round of the U.S. Department of Energy's Clean Coal Power Initiative (CCPI). Great River Energy of Maple Grove, Minn., has selected the WorleyParsons Group to exclusively distribute licenses for the technology, which essentially uses waste heat from a power plant to reduce moisture content

109

Modified approaches for high pressure filtration of fine clean coal  

SciTech Connect (OSTI)

Removal of moisture from fine (minus 28 mesh) clean coal to 20% or lower level is difficult using the conventional vacuum dewatering technique. High pressure filtration technique provides an avenue for obtaining low moisture in fine clean coal. This paper describes a couple of novel approaches for dewatering of fine clean coal using pressure filtration which provides much lower moisture in fine clean coal than that obtained using conventional pressure filter. The approaches involve (a) split stream dewatering and (b) addition of paper pulp to the coal slurry. For Pittsburgh No. 8 coal slurry, split stream dewatering at 400 mesh provided filter cake containing 12.9% moisture compared to 24.9% obtained on the feed material. The addition of paper pulp to the slurry provided filter cake containing about 17% moisture.

Yang, J.; Groppo, J.G.; Parekh, B.K. [Center for Applied Energy Research, Lexington, KY (United States)

1995-12-31T23:59:59.000Z

110

Sulfur and ash reduction potential and selected chemical and physical properties of United States coals  

SciTech Connect (OSTI)

This report summarizes the washability and comprehensive characterization of 975 raw coal channel samples collected from the Eastern, Central, and Western Regions (including Alaska) of the United States. All of this information is sorted in the Pittsburgh Energy Technology Center (PETC) Coal Technology Data Base. Individual reports for each region were completed previously as Volumes 1, 2, and 3 and included the detailed data for each of the 975 samples. This report is a summation of the results of those three reports on a state- and region-wide basis only, and does not include the data for individual samples, but only includes the composite data for each state and region. Graphical summations are presented by state, section or rank, and region showing the effects of crushing on impurity reductions and showing the distribution of raw and clean coal samples meeting various levels of SO{sub 2} emissions. The statistical evaluations in the Appendices present the composited washability data of 1.30, 1.40, and 1.60 specific gravities of separation, the selected chemical and physical properties, and the composited washability data interpolated at various levels of Btu recovery. 13 refs., 93 figs., 9 tabs.

Cavallaro, J.A.; Deurbrouck, A.W.; Killmeyer, R.P.; Fuchs, W. (USDOE Pittsburgh Energy Technology Center, PA (USA)); Jacobsen, P.S. (Burns and Roe Services Corp., Pittsburgh, PA (USA))

1991-09-01T23:59:59.000Z

111

Florida CFB demo plant yields low emissions on variety of coals  

SciTech Connect (OSTI)

The US Department of Energy (DOE) has reported results of tests conducted at Jacksonville Electric Authority (JEA)'s Northside power plant using mid-to-low-sulfur coal, which indicate the facility is one of the cleanest burning coal-fired power plants in the world. A part of DOE's Clean Coal Technology Demonstration Program, the JEA project is a repowering demonstration of the operating and environmental performance of Foster Wheeler's utility-scale circulating fluidized bed combustion (CFB) technology on a range of high-sulfur coals and blends of coal and high-sulfur petroleum coke. The 300 MW demonstration unit has a non-demonstration 300 MW twin unit.

NONE

2005-07-01T23:59:59.000Z

112

High-Resolution Simulations of Coal Injection in A Gasifier  

Science Journals Connector (OSTI)

High-Resolution Simulations of Coal Injection in A Gasifier ... The shrinkage of the coal particles because of devolatilization and drying was ignored, and a single mean particle size was used. ... Simulations with three different grid resolutions were conducted (denoted by coarse, medium, and fine). ...

Tingwen Li; Aytekin Gel; Madhava Syamlal; Chris Guenther; Sreekanth Pannala

2010-07-15T23:59:59.000Z

113

High-pressure coal fuel processor development. Task 1, Proof of principle testing  

SciTech Connect (OSTI)

The objective of Subtask 1.1 Engine Feasibility was to conduct research needed to establish the technical feasibility of ignition and stable combustion of directly injected, 3,000 psi, low-Btu gas with glow plug ignition assist at diesel engine compression ratios. This objective was accomplished by designing, fabricating, testing and analyzing the combustion performance of synthesized low-Btu coal gas in a single-cylinder test engine combustion rig located at the Caterpillar Technical Center engine lab in Mossville, Illinois. The objective of Subtask 1.2 Fuel Processor Feasibility was to conduct research needed to establish the technical feasibility of air-blown, fixed-bed, high-pressure coal fuel processing at up to 3,000 psi operating pressure, incorporating in-bed sulfur and particulate capture. This objective was accomplished by designing, fabricating, testing and analyzing the performance of bench-scale processors located at Coal Technology Corporation (subcontractor) facilities in Bristol, Virginia. These two subtasks were carried out at widely separated locations and will be discussed in separate sections of this report. They were, however, independent in that the composition of the synthetic coal gas used to fuel the combustion rig was adjusted to reflect the range of exit gas compositions being produced on the fuel processor rig. Two major conclusions resulted from this task. First, direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize these low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risks associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept.

Greenhalgh, M.L.

1992-11-01T23:59:59.000Z

114

High temperature alkali corrosion of ceramics in coal gas  

SciTech Connect (OSTI)

High temperature alkali corrosion has been known to cause premature failure of ceramic components used in advanced high temperature coal combustion systems such as coal gasification and clean-up, coal fired gas turbines, and high efficiency heat engines. The objective of this research is to systematically evaluate the alkali corrosion resistance of the most commonly used structural ceramics including silicon carbide, silicon nitride, cordierite, mullite, alumina, aluminum titanate, zirconia, and fireclay glass. The study consists of identification of the alkali reaction products (phase equilibria) and the kinetics of the alkali reactions as a function of temperature and time.

Pickrell, G.R.; Sun, T.; Brown, J.J.

1992-05-27T23:59:59.000Z

115

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures  

DOE Patents [OSTI]

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, John E. (Woodridge, IL); Jalan, Vinod M. (Concord, MA)

1984-01-01T23:59:59.000Z

116

High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures  

DOE Patents [OSTI]

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, J.E.; Jalan, V.M.

1982-07-07T23:59:59.000Z

117

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures  

DOE Patents [OSTI]

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, J.E.; Jalan, V.M.

1984-06-19T23:59:59.000Z

118

Process for converting coal into liquid fuel and metallurgical coke  

DOE Patents [OSTI]

A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

Wolfe, Richard A. (Abingdon, VA); Im, Chang J. (Abingdon, VA); Wright, Robert E. (Bristol, TN)

1994-01-01T23:59:59.000Z

119

Small Scale Coal Biomass Liquids Production Using Highly Selective Fischer  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Small Scale Coal Biomass Liquids Production Using Highly Selective Fischer Tropsch Catalyst Small Scale Coal Biomass Liquids Production Using Highly Selective Fischer Tropsch Catalyst Southern Research Institute Project Number: FE0010231 Project Description Fischer-Tropsch (FT) process converts a mixture of carbon monoxide and hydrogen, called syngas, into liquid hydrocarbons. It is a leading technology for converting syngas derived from gasification of coal and coal-biomass mixtures to hydrocarbons in coal to liquids (CTL) and coal-biomass to liquids (CBTL) processes. However, conventional FTS catalysts produce undesirable waxes (C21+) that need to be upgraded to liquids (C5-C20) by hydrotreating. This adds significantly to the cost of FTS. The objectives of this project are (i) to demonstrate potential for CBTL cost reduction by maximizing the production of C5-C20 hydrocarbon liquids using a selective FTS catalyst and (ii) to evaluate the impacts of the addition of biomass to coal on product characteristics, carbon foot print, and economics.

120

Chapter 3 - Coal-fired Power Plants  

Science Journals Connector (OSTI)

Abstract Coal provides around 40% of the world’s electricity, more than any other source. Most modern coal-fired power stations burn pulverized coal in a boiler to raise steam for a steam turbine. High efficiency is achieved by using supercritical boilers made of advanced alloys that produce high steam temperatures, and large, high-efficiency steam turbines. Alternative types of coal-fired power plants include fluidized bed boilers that can burn a variety of poor fuels, as well as coal gasifiers that allow coal to be turned into a combustible gas that can be burned in a gas turbine. Emissions from coal plants include sulfur dioxide, nitrogen oxide, and trace metals, all of which must be controlled. Capturing carbon dioxide from a coal plant is also under consideration. This can be achieved using post-combustion capture, a pre-combustion gasification process, or by burning coal in oxygen instead of air.

Paul Breeze

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

A simple approach to synthesize nanosized sulfur/graphene oxide materials for high-performance lithium/sulfur batteries  

Science Journals Connector (OSTI)

We report on a simple and facile synthesis route for the sulfur/graphene oxide composite via ultrasonic mixing of the nano-sulfur and graphene oxide aqueous suspensions followed by a low-temperature heat treat...

Yongguang Zhang; Yan Zhao; Zhumabay Bakenov

2014-07-01T23:59:59.000Z

122

HIGH PRESSURE COAL COMBUSTION KINETICS PROJECT  

SciTech Connect (OSTI)

The modifications to the SRT-RCFR facility described in the June report were completed. As a result of these changes, the furnace hot zone was increased in length from 7 cm to 15.5 cm. The injector region of the furnace, providing entrainment and sheath flows, was unchanged, while the flow path from the exit of the furnace to the sample collection section was shortened by approximately 10 cm. The modified facility was used to resume testing of Pittsburgh No. 8 coal at 10 atm. The first goal was to confirm that the facility now provides true secondary pyrolysis test conditions. That is, the tar product should be completely converted to soot even in the absence of oxygen in the gas stream. We have now performed four tests with pure argon carrier gas, and have consistently observed voluminous soot product with little or no evidence of tar. Thus, this objective was met. The clogging problems for Pittsburgh No. 8 coal under secondary pyrolysis test conditions may preclude achieving this data point. In that case, we will make measurements under oxidizing conditions, which are expected to eliminate the clogging, and to gradually reduce the oxygen content to the point where product yields can reliably be extrapolated to the zero oxygen case.

Chris Guenther

2002-10-28T23:59:59.000Z

123

HIGH PRESSURE COAL COMBUSTION KINETICS PROJECT  

SciTech Connect (OSTI)

The HPCCK project was initiated with a kickoff meeting held on June 12, 2001 in Morgantown, WV, which was attended by all project participants. SRI's existing g-RCFR reactor was reconfigured to a SRT-RCFR geometry (Task 1.1). This new design is suitable for performing the NBFZ experiments of Task 1.2. It was decided that the SRT-RCFR apparatus could be modified and used for the HPBO experiments. The purchase, assembly, and testing of required instrumentation and hardware is nearly complete (Task 1.1 and 1.2). Initial samples of PBR coal have been shipped from FWC to SRI (Task 1.1). The ECT device for coal flow measurements used at FWC will not be used in the SRI apparatus and a screw type feeder has been suggested instead (Task 5.1). NEA has completed a upgrade of an existing Fluent simulator for SRI's RCFR to a version that is suitable for interpreting results from tests in the NBFZ configuration (Task 1.3) this upgrade includes finite-rate submodels for devolatilization, secondary volatiles pyrolysis, volatiles combustion, and char oxidation. Plans for an enhanced version of CBK have been discussed and development of this enhanced version has begun (Task 2.5). A developmental framework for implementing pressure and oxygen effects on ash formation in an ash formation model (Task 3.3) has begun.

Chris Guenther; Bill Rogers

2001-09-15T23:59:59.000Z

124

Conventional coal preparation in the United States  

SciTech Connect (OSTI)

Processing of bituminous and anthracite coal is widely practiced in the United States and, as mentioned earlier, about 80 percent of the production of these coals is processed as clean coal in preparation plants. Subbituminous coal is not widely processed, primarily because these low rank raw coals are low in sulfur (0.5 to 1.0 percent) and relatively low in ash (8 to 15 percent). They are also relatively low in heat content due to their high inherent moisture. Lignite coals, to the best of the authors{close_quote} knowledge, are not presently being processed in Conventional Coal Preparation plants. This is due to their unstable nature and putting them in water in a coal preparation plant is likely to cause severe degradation in particle size and add to their already high inherent moisture content. The following are the benefits of clean coal processing: produces a uniform product which can be utilized more efficiently; produces a higher quality product which results in higher efficiency at the power station or the steel mill; reduces sulfur dioxide and other adverse stack emissions during coal firing which is a very important environmental consideration; reduces ash or slag handling costs by the user; reduces shipping costs; and reduces handling and storage costs. Processing any stable raw coal in a coal preparation plant will always produce a higher grade product which is a more efficient and a more environmentally acceptable fuel for use at power stations, steel mills, home heating or industrial boilers.

Beck, M.K.; Taylor, B.

1993-12-31T23:59:59.000Z

125

A combustion/deposition entrained reactor for high?temperature/pressure studies of coal and coal minerals  

Science Journals Connector (OSTI)

The combustion of coal and coal?derived fuels in heat engines poses significant technical challenges in terms of establishing high combustion rates and efficiencies controlling emissions and minimizing the impact of fuel contaminants on engine components. An entrained reactor has been designed and constructed to study coal particle combustion the tendency of coal ash to form deposits on heat engine components and the effects of fuel additives on residual ash composition. The reactor is designed for high temperature/pressure conditions similar to those of a coal?fired gas turbine. Optical access ports and advanced instrumentation allow the i n s i t u measurement of gas and particle temperatures and vapor phase alkali concentrations. The reactor has been used to study the deposition potential of several coals as a function of process conditions and to determine the effects of selected additives on the deposition rate.

Rodney J. Anderson; Ronald G. Logan; Charles T. Meyer; Richard A. Dennis

1990-01-01T23:59:59.000Z

126

Coal-fueled high-speed diesel engine development  

SciTech Connect (OSTI)

The objectives of this program are to study combustion feasibility by running Series 149 engine tests at high speeds with a fuel injection and combustion system designed for coal-water-slurry (CWS). The following criteria will be used to judge feasibility: (1) engine operation for sustained periods over the load range at speeds from 600 to 1900 rpm. The 149 engine for mine-haul trucks has a rated speed of 1900 rpm; (2) reasonable fuel economy and coal burnout rate; (3) reasonable cost of the engine design concept and CWS fuel compared to future oil prices.

Not Available

1991-11-01T23:59:59.000Z

127

High temperature ceramic membrane reactors for coal liquid upgrading  

SciTech Connect (OSTI)

Membrane reactors are today finding extensive applications for gas and vapor phase catalytic reactions (see discussion in the introduction and recent reviews by Armor [92], Hsieh [93] and Tsotsis et al. [941]). There have not been any published reports, however, of their use in high pressure and temperature liquid-phase applications. The idea to apply membrane reactor technology to coal liquid upgrading has resulted from a series of experimental investigations by our group of petroleum and coal asphaltene transport through model membranes. Coal liquids contain polycyclic aromatic compounds, which not only present potential difficulties in upgrading, storage and coprocessing, but are also bioactive. Direct coal liquefaction is perceived today as a two-stage process, which involves a first stage of thermal (or catalytic) dissolution of coal, followed by a second stage, in which the resulting products of the first stage are catalytically upgraded. Even in the presence of hydrogen, the oil products of the second stage are thought to equilibrate with the heavier (asphaltenic and preasphaltenic) components found in the feedstream. The possibility exists for this smaller molecular fraction to recondense with the unreacted heavy components and form even heavier undesirable components like char and coke. One way to diminish these regressive reactions is to selectively remove these smaller molecular weight fractions once they are formed and prior to recondensation. This can, at least in principle, be accomplished through the use of high temperature membrane reactors, using ceramic membranes which are permselective for the desired products of the coal liquid upgrading process. An additional incentive to do so is in order to eliminate the further hydrogenation and hydrocracking of liquid products to undesirable light gases.

Tsotsis, T.T. (University of Southern California, Los Angeles, CA (United States). Dept. of Chemical Engineering); Liu, P.K.T. (Aluminum Co. of America, Pittsburgh, PA (United States)); Webster, I.A. (Unocal Corp., Los Angeles, CA (United States))

1992-01-01T23:59:59.000Z

128

Blending high sulfer coal with refuse derived fuel to make SO{sub 2} compliant slurry fuels  

SciTech Connect (OSTI)

The need for a better method of disposing of the international community`s garbage hardly needs emphasizing. In 1993, the United States alone generated approximately 207 million ton per year of Municipal Solid Waste (MSW), with 62% landfilled, 220/6 recycled, and 16% combusted for energy recovery. Despite strenuous efforts to make these disposal methods meet present needs, the cost of disposal is rising dramatically. Concurrently, the Clean Air Act Amendments (CAAA) of 1990 have severely restricted the SO{sub 2} emissions from coal fired boilers. Medium and high sulfur coals will not comply with the Phase II CAAA regulation limit of 1.2 lb SO{sub 2}/MM Btu, without advanced coal cleaning technologies or flue gas desulfurization, including the majority of the North Dakota lignite reserves. Utility power plants have attempted to burn refuse derived fuel (RDF), a heterogeneous solid fuel produced from MSW, with coal in utility scale boilers (generally referred to as co-firing). Co-firing of RDF with coal has been attempted in sixteen different boilers, five commercially. While lower SO{sub 2} emissions provided the impetus, co-firing RDF with coal suffered from several disadvantages including increased solids handling, increased excess air requirements, higher HCI, CO, NO{sub x} and chlorinated organic emissions, increased slag formation in the boiler, and higher fly ash resistivity. Currently, only two of the sixteen boilers are still regularly used to co-fire RDF. The overall objective of this research program was to assess the feasibility of blending RDF with lignite coal to form SO{sub 2} Compliant slurry fuels using EnerTech`s SlurryCarb{trademark} process. In particular, the objective was to overcome the difficulties of conventional co-firing. Blended slurry fuels were produced with the Energy & Environmental Research Center`s (EERC) bench-scale autoclave and were combusted in a pressurized fluidized-bed reactor (PFBR).

Klosky, M. [EnerTech Environmental, Inc., Atlanta, GA (United States); Anderson, C. [Energy & Environmental Research Center, Grand Forks, ND (United States)

1995-12-31T23:59:59.000Z

129

Coal-fired high performance power generating system. Final report  

SciTech Connect (OSTI)

As a result of the investigations carried out during Phase 1 of the Engineering Development of Coal-Fired High-Performance Power Generation Systems (Combustion 2000), the UTRC-led Combustion 2000 Team is recommending the development of an advanced high performance power generation system (HIPPS) whose high efficiency and minimal pollutant emissions will enable the US to use its abundant coal resources to satisfy current and future demand for electric power. The high efficiency of the power plant, which is the key to minimizing the environmental impact of coal, can only be achieved using a modern gas turbine system. Minimization of emissions can be achieved by combustor design, and advanced air pollution control devices. The commercial plant design described herein is a combined cycle using either a frame-type gas turbine or an intercooled aeroderivative with clean air as the working fluid. The air is heated by a coal-fired high temperature advanced furnace (HITAF). The best performance from the cycle is achieved by using a modern aeroderivative gas turbine, such as the intercooled FT4000. A simplified schematic is shown. In the UTRC HIPPS, the conversion efficiency for the heavy frame gas turbine version will be 47.4% (HHV) compared to the approximately 35% that is achieved in conventional coal-fired plants. This cycle is based on a gas turbine operating at turbine inlet temperatures approaching 2,500 F. Using an aeroderivative type gas turbine, efficiencies of over 49% could be realized in advanced cycle configuration (Humid Air Turbine, or HAT). Performance of these power plants is given in a table.

NONE

1995-08-31T23:59:59.000Z

130

Reduced Sulfur in Ashes and Slags from the Gasification of Coals: Availability for Chemical and Microbial Oxidation  

Science Journals Connector (OSTI)

...9 by 30 cm) ofa coal gasifier slag (1.5 kg [air-dried...rates. Ten grams of gasifier ash was suspended in...most-probable-number (MPN) medium de- scribed below except...99. Growth in the medium was scored positive if...S OXIDATION IN COAL GASIFIER SOLID WASTES 745 6 E...

Richard F. Strayer; Edward C. Davis

1983-03-01T23:59:59.000Z

131

The Pittsburg & Midway Coal Mining Co. Kemmerer Mine coal blending facility  

SciTech Connect (OSTI)

The Pittsburg & Midway Coal Mining Company`s Kemmerer Mine recently completed a new coal processing facility for blending the mine`s low, medium, and high sulfur coals to meet the needs of our customers. This article will discuss the geology; mining and market conditions that led to the need for this facility; design considerations; the construction; and the system`s controls and performance.

Mulhall, K.; Crank, G. [Pittsburg & Midway Coal Mining Co., Kemmerer, WY (United States)

1995-08-01T23:59:59.000Z

132

High Purity Hydrogen Production with In-Situ Carbon Dioxide and Sulfur Capture in a Single Stage Reactor  

SciTech Connect (OSTI)

Enhancement in the production of high purity hydrogen (H{sub 2}) from fuel gas, obtained from coal gasification, is limited by thermodynamics of the water gas shift (WGS) reaction. However, this constraint can be overcome by conducting the WGS in the presence of a CO{sub 2}-acceptor. The continuous removal of CO{sub 2} from the reaction mixture helps to drive the equilibrium-limited WGS reaction forward. Since calcium oxide (CaO) exhibits high CO{sub 2} capture capacity as compared to other sorbents, it is an ideal candidate for such a technique. The Calcium Looping Process (CLP) developed at The Ohio State University (OSU) utilizes the above concept to enable high purity H{sub 2} production from synthesis gas (syngas) derived from coal gasification. The CLP integrates the WGS reaction with insitu CO{sub 2}, sulfur and halide removal at high temperatures while eliminating the need for a WGS catalyst, thus reducing the overall footprint of the hydrogen production process. The CLP comprises three reactors - the carbonator, where the thermodynamic constraint of the WGS reaction is overcome by the constant removal of CO{sub 2} product and high purity H{sub 2} is produced with contaminant removal; the calciner, where the calcium sorbent is regenerated and a sequestration-ready CO{sub 2} stream is produced; and the hydrator, where the calcined sorbent is reactivated to improve its recyclability. As a part of this project, the CLP was extensively investigated by performing experiments at lab-, bench- and subpilot-scale setups. A comprehensive techno-economic analysis was also conducted to determine the feasibility of the CLP at commercial scale. This report provides a detailed account of all the results obtained during the project period.

Nihar Phalak; Shwetha Ramkumar; Daniel Connell; Zhenchao Sun; Fu-Chen Yu; Niranjani Deshpande; Robert Statnick; Liang-Shih Fan

2011-07-31T23:59:59.000Z

133

Coal quality and estimated coal resources in the proposed Colville Mining District, central North Slope, Alaska  

SciTech Connect (OSTI)

The proposed Colville Mining District (CMD) encompasses 27,340 mi{sup 2} (70,800 km{sup 2}) in the central part of the North Slope. Known coal deposits within the proposed district range from Mississippian to Tertiary in age. Available information indicates that neither Mississippian and Tertiary coals in the CMD constitute a significant resource because they are excessively deep, thin, or high in ash content; however, considerable amount of low-sulfur Cretaceous coal is present. The paper briefly describes the geology and quality of these coal reserves. Difficult conditions will restrict mining of these coals in the near future.

Stricker, G.D. [Geological Survey, Denver, CO (United States); Clough, J.G. [Alaska Department of Natural Resources, Fairbanks, AK (United States). Division of Geological and Geophysical Surveys

1994-12-31T23:59:59.000Z

134

High-pressure coal fuel processor development. Final report  

SciTech Connect (OSTI)

Caterpillar shares DOE/METC interest in demonstrating the technology required to displace petroleum-based engine fuels with various forms of low cost coal. Current DOE/METC programs on mild gasification and coal-water-slurries are addressing two approaches to this end. Engine and fuel processor system concept studies by Caterpillar have identified a third, potentially promising, option. This option includes high-pressure fuel processing of run-of-the-mine coal and direct injection of the resulting low-Btu gas stream into an ignition assisted, high compression ratio diesel engine. The compactness and predicted efficiency of the system make it suitable for application to line-haul railroad locomotives. Two overall conclusions resulted from Task 1. First direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risk associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept. The significant conclusions from Task 2 were: An engine concept, derived from a Caterpillar 3600 series engine, and a fuel processor concept, based on scaling up a removable-canister configuration from the test rig, appear feasible; and although the results of this concept study are encouraging, further, full-scale component research and development are required before attempting a full-scale integrated system demonstration effort.

Greenhalgh, M.L. [Caterpillar, Inc., Peoria, IL (United States)

1992-12-01T23:59:59.000Z

135

Gasifier feed: Tailor-made from Illinois coals. Final technical report, September 1, 1991--December 31, 1992  

SciTech Connect (OSTI)

The main purpose of this project was to produce a feedstock from preparation plant fines from an Illinois (IL) coal that is ideal for a slurry fed, slagging, entrained-flow coal gasifier. The high-sulfur content and high-Btu value of IL coals are Particularly advantageous in such a gasifier; preliminary-calculations indicate that the increased cost of removing sulfur from the gas from a high-sulfur coal is more than offset b the increased revenue from the sale of the elemental sulfur; additionally the high-Btu IL coal concentrates more energy into the slurry of a given coal to water ratio. The Btu is--higher not only because of the hither Btu value of the coal but also because IL coal requires less water to produce a pumpable slurry than western coal, i.e., as little as 30--35% water may be used for IL coal as compared to approximately 45% for most western coals. During the contract extension, additional coal testing was completed confirming the fact that coal concentrates can be made from plant waste under a variety of flotation conditions 33 tests were conducted, yielding an average of 13326 Btu with 9.6% ash while recovering 86.0%-Of the energy value.

Ehrlinger, H.P. III [Illinois State Geological Survey, Champaign, IL (United States); Lytle, J.M.; Frost, R.R.; Lizzio, A.A.; Kohlenberger, L.B.; Brewer, K.K. [Illinois State Geological Survey, Champaign, IL (United States)]|[DESTEC Energy (United States)]|[Williams Technologies, Inc. (United States)]|[Illinois Coal Association (United States)

1992-12-31T23:59:59.000Z

136

Production of High-Hydrogen Content Coal-Derived Liquids [Part 2 of 3  

SciTech Connect (OSTI)

The primary goal of this project has been to evaluate and compare the effect of the intrinsic differences between cobalt (Co) and iron (Fe) catalysts for Fischer-Tropsch (FT) synthesis using coal-derived syngas. Crude oil, especially heavy, high-sulfur crude, is no longer the appropriate source for the additional, or marginal, amounts of middle-distillate fuels needed to meet growing US and world demand for diesel and jet fuels. Only about 1/3 of the marginal crude oil barrel can be made into diesel and jet fuels. The remaining 2/3 contributes further to global surpluses of by-products. FT can produce these needed marginal, low-sulfur middle-distillate fuels more efficiently, with less environmental impact, and from abundant US domestic resources. Cobalt FT catalyst is more efficient, and less expensive overall, than iron FT catalyst. Mechanisms of cobalt FT catalyst functioning, and poisoning, have been elucidated. Each of these primary findings is amplified by several secondary findings, and these are presented, and verified in detail. The most effective step the United States can take to begin building toward improved long-term national energy security, and to reduce dependence, over time, on imported crude oil from unfriendly and increasingly unstable areas of the world, is to begin producing additional, or marginal amounts of, middle-distillate-type fuels, such as ultralow sulfur diesel (ULSD) and jet fuel (not gasoline) from US domestic resources other than petroleum. FT synthesis of these middle distillate fuels offers the advantage of being able to use abundant and affordable US coal and biomass as the primary feedstocks. Use of the cobalt FT catalyst system has been shown conclusively to be more effective and less expensive than the use of iron FT catalyst with syngas derived from coal, or from coal and biomass combined. This finding is demonstrated in detail for the initial case of a relatively small FT plant of about 2000 barrels per day based upon coal and biomass. The primary feature of such a plant, in the current situation in which no commercial FT plants are operating in the US, is that it requires a relatively modest capital investment, meaning that such a plant could actually be built, operated, and replicated in the near term. This is in contrast to the several-billion dollar investment, and accompanying risk, that would be required for a plant of more than an order of magnitude greater capacity, which has been referred to in the technical literature on fuel production as the capacity required to be considered "commercial-scale." The effects of more than ten different potential poisons for cobalt FT catalyst have been studied extensively and in detail using laboratory continuous-stirred tank reactors (CSTRs) and bottled laboratory syngas "spiked" with precisely controlled amounts of the poisons, typically at the levels of 10s or 100s of parts per billion. This data set has been generated and interpreted by world-renowned experts on FT catalysis at the University of Kentucky Center for Applied Energy Research (UK-CAER), and has enabled unprecedented insight regarding the many molecular-scale mechanisms that can play a role in the "poisoning" of cobalt FT catalyst.

Stephen Bergin

2011-03-30T23:59:59.000Z

137

PENETRATION OF COAL SLAGS INTO HIGH-CHROMIA REFRACTORIES  

SciTech Connect (OSTI)

Slagging coal gasifiers are used for the production of electricity and synthetic gases, as well as chemicals. High temperatures in the reaction chamber, typically between 1250ºC and 1600ºC, high pressure, generally greater than 400 psi, and corrosive slag place severe demands on the refractory materials. Slag produced during the combustion of coal flows over the refractory surface and penetrates the porous material. Slag penetration is typically followed by spalling of a brick that significantly decreases the service life of gasifier refractories. Laboratory tests were conducted to determine the penetration depth of slags into high-chromia refractories as a function of time and temperature for various refractory-slag combinations.

Longanbach, Sara C.; Matyas, Josef; Sundaram, S. K.

2009-10-05T23:59:59.000Z

138

Gasifier feed: Tailor-made from Illinois coals. Interim final technical report, September 1, 1991--August 31, 1992  

SciTech Connect (OSTI)

The main purpose of this project is to produce a feedstock from preparation plant fines from an Illinois coal that is ideal for a slurry fed, slagging, entrained-flow coal gasifier. The high sulfur content and high Btu value of Illinois coals are particularly advantageous in such a gasifier; preliminary calculations indicate that the increased cost of removing sulfur from the gas from a high sulfur coal is more than offset by the increased revenue from the sale of the elemental sulfur; additionally the high Btu Illinois coal concentrates more energy into the slurry of a given coal to water ratio. The Btu is higher not only because of the higher Btu value of the coal but also because Illinois coal requires less water to produce a pumpable slurry than western coal, i.e., as little as 30--35% water may be used for Illinois coal as compared to approximately 45% for most western coals. Destec Energy, a wholly-owned subsidiary of Dow Chemical Company, will provide guidelines and test compatibility of the slurries developed for gasification feedstock. Williams Technologies, Inc., will provide their expertise in long distance slurry pumping, and test selected products for viscosity, pumpability, and handleability. The Illinois State Geological Survey will study methods for producing clean coal/water slurries from preparation plant wastes including the concentration of pyritic sulfur into the coal slurry to increase the revenue from elemental sulfur produced during gasification operations, and decrease the pyritic sulfur content of the waste streams. ISGS will also test the gasification reactivity of the coals.

Ehrlinger, H.P. III; Lytle, J.; Frost, R.R.; Lizzio, A.; Kohlenberger, L.; Brewer, K. [Illinois State Geological Survey, Champaign, IL (United States)

1992-12-31T23:59:59.000Z

139

A graphene foam electrode with high sulfur loading for flexible and high energy Li-S batteries  

Science Journals Connector (OSTI)

Abstract Lithium-sulfur (Li-S) batteries have attracted great attention as next-generation high specific energy density storage devices. However, the low sulfur loading in the cathode for Li-S battery greatly offsets its advantage in high energy density and limits the practical applications of such battery concepts. Flexible energy storage devices are also becoming increasingly important for future applications but are limited by the lack of suitable lightweight electrode materials with robust electrochemical performance under cyclic mechanical strain. Here, we proposed an effective strategy to obtain flexible Li-S battery electrodes with high energy density, high power density, and long cyclic life by adopting graphene foam-based electrodes. Graphene foam can provide a highly electrically conductive network, robust mechanical support and sufficient space for a high sulfur loading. The sulfur loading in graphene foam-based electrodes can be tuned from 3.3 to 10.1 mg cm?2. The electrode with 10.1 mg cm?2 sulfur loading could deliver an extremely high areal capacity of 13.4 mAh cm?2, much higher than the commonly reported Li-S electrodes and commercially used lithium cobalt oxide cathode with a value of ~3–4 mAh cm?2. Meanwhile, the high sulfur-loaded electrodes retain a high rate performance with reversible capacities higher than 450 mAh g?1 under a large current density of 6 A g?1 and preserve stable cycling performance with ~0.07% capacity decay per cycle over 1000 cycles. These impressive results indicate that such electrodes could enable high performance, fast-charging, and flexible Li-S batteries that show stable performance over extended charge/discharge cycling.

Guangmin Zhou; Lu Li; Chaoqun Ma; Shaogang Wang; Ying Shi; Nikhil Koratkar; Wencai Ren; Feng Li; Hui-Ming Cheng

2015-01-01T23:59:59.000Z

140

Production of high-energy fuel with low volatile content from 3B and D coal  

Science Journals Connector (OSTI)

Experiments on the carbonization of coal show that high-energy fuel with satisfactory piece strength (?8 MPa in compression) may be produced in the nonoxidative heating of 3B and D coal, with gradual increase ...

M. V. Kulesh; S. R. Islamov

2012-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Sulfur and ash reduction potential and selected chemical and physical properties of United States coals. [Contains glossary  

SciTech Connect (OSTI)

This report presents the washability and comprehensive characterization results of 247 raw coal channel samples, including anthracite, bituminous and lignite coals, collected from the Western Region of the United States. Although the Western Region includes Alaska, coal data from this state will often be cited apart from the Western Region data from the lower United States. This is the third of a three volume report on the coals of the United States. All the data are presented in six appendices. Statistical techniques and definitions are presented in Appendix A, and a glossary of terms is presented in Appendix B. The complete washability data and an in-depth characterization of each sample are presented alphabetically by state in Appendix C. In Appendix D, a statistical evaluation is given for the composited washability data, selected chemical and physical properties, and washability data interpolated at various levels of Btu recovery. This presentation is shown by state, section, and region where four or more samples were collected. Appendix E presents coalbed codes and names for the Western Region coals. Graphical summations are presented by state, rank, and region showing the effects of crushing on impurity reductions, and the distribution of raw and clean coal samples meeting various levels of SO{sub 2} emissions. 35 figs., 3 tabs.

Cavallaro, J.A.; Deurbrouck, A.W.; Killmeyer, R.P.; Fuchs, W. (USDOE Pittsburgh Energy Technology Center, PA (USA). Coal Preparation Div.); Jacobsen, P.S. (Burns and Roe Services Corp., Pittsburgh, PA (USA))

1991-06-01T23:59:59.000Z

142

Integrated Process Configuration for High-Temperature Sulfur Mitigation during Biomass Conversion via Indirect Gasification  

Science Journals Connector (OSTI)

Integrated Process Configuration for High-Temperature Sulfur Mitigation during Biomass Conversion via Indirect Gasification ... National Bioenergy Center, National Renewable Energy Laboratory, 1617 Cole Blvd., Golden, Colorado 80401, United States ... Similar activation energies (9-10 kcal/mol) were measured for ZnO and Zn-Ti-O sulfidation. ...

Abhijit Dutta; Singfoong Cheah; Richard Bain; Calvin Feik; Kim Magrini-Bair; Steven Phillips

2012-05-23T23:59:59.000Z

143

Secondary economic impact of acid deposition control legislation in six coal producing states: Final report  

SciTech Connect (OSTI)

Among the difficult policy questions on the US environmental agenda is what to do about emissions to the earth's atmosphere of pollutants that may result in ''acid rain''. The Congress has considered several pieces of legislation spelling out potential approaches to the problem and setting goals for emission reduction, mostly emphasizing the control of oxides of sulfur and nitrogen. Significant policy concern is the dollar costs to the nation's economy of achieving the intended effects of the legislation and the potential impacts on economic activity---in particular, losses of both coal mining and secondary service sector employment in states and regions dependent on the mining of high sulfur coal. There are several direct economic effects of regulations such as the acid rain control legislation. One of the more obvious effects was the switching from high sulfur coal to low sulfur coal. This would result in increases in employment and coal business procurements in low sulfur coal mining regions, but also would result in lower employment and lower coal business procurements in high sulfur coal mining areas. The potential negative effects are the immediate policy concern and are the focus of this report. 15 refs., 1 fig., 17 tabs.

Scott, M.J.; Guthrie, S.J.

1988-12-01T23:59:59.000Z

144

Coal surface control for advanced fine coal flotation  

SciTech Connect (OSTI)

The initial goal of the research project was to develop methods of coal surface control in advanced froth flotation to achieve 90% pyritic sulfur rejection, while operating at Btu recoveries above 90% based on run-of-mine quality coal. Moreover, the technology is to concomitantly reduce the ash content significantly (to six percent or less) to provide a high-quality fuel to the boiler (ash removal also increases Btu content, which in turn decreases a coal's emission potential in terms of lbs SO{sub 2}/million Btu). (VC)

Fuerstenau, D.W.; Hanson, J.S.; Diao, J.; Harris, G.H.; De, A.; Sotillo, F. (California Univ., Berkeley, CA (United States)); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. (Columbia Univ., New York, NY (United States)); Hu, W.; Zou, Y.; Chen, W. (Utah Univ., Salt Lake City, UT (United States)); Choudhry, V.; Shea, S.; Ghosh, A.; Sehgal, R. (Praxis Engineers, Inc., Milpitas, CA (United States))

1992-03-01T23:59:59.000Z

145

Coal plasticity at high heating rates and temperatures. Final technical progress report  

SciTech Connect (OSTI)

Plastic coals are important feedstocks in coke manufacture, coal liquefaction, gasification, and combustion. During these processes, the thermoplastic behavior of these coals is also important since it may contribute to desirable or undesirable characteristics. For example, during liquefaction, the plastic behavior is desired since it leads to liquid-liquid reactions which are faster than solid-liquid reactions. During gasification, the elastic behavior is undesired since it leads to caking and agglomeration of coal particles which result in bed bogging in fixed or fluidized bed gasifiers. The plastic behavior of different coals was studied using a fast-response plastometer. A modified plastometer was used to measure the torque required to turn at constant angular speed a cone-shaped disk embedded in a thin layer of coal. The coal particles were packed between two metal plates which are heated electrically. Heating rates, final temperatures, pressures, and durations of experiment ranged from 200--800 K/s, 700--1300 K, vacuum-50 atm helium, and 0--40 s, respectively. The apparent viscosity of the molten coal was calculated from the measured torque using the governing equation of the cone-and-plate viscometer. Using a concentrated suspension model, the molten coal`s apparent viscosity was related to the quantity of the liquid metaplast present during pyrolysis. Seven coals from Argonne National Laboratory Premium Coal Sample Bank were studied. Five bituminous coals, from high-volatile to low-volatile bituminous, were found to have very good plastic behavior. Coal type strongly affects the magnitude and duration of plasticity. Hvb coals were most plastic. Mvb and lvb coals, though the maximum plasticity and plastic period were less. Low rank coals such as subbituminous and lignite did not exhibit any plasticity in the present studies. Coal plasticity is moderately well correlated with simple indices of coal type such as the elemental C,O, and H contents.

Gerjarusak, S.; Peters, W.A.; Howard, J.B.

1995-05-01T23:59:59.000Z

146

HIGH PRESSURE COAL COMBUSTION KINETICS PROJECT  

SciTech Connect (OSTI)

SRI has completed the NBFZ test program, made modification to the experimental furnace for the HPBO test. The NBFZ datasets provide the information NEA needs to simulate the combustion and fuel-N conversion with detailed chemical reaction mechanisms. BU has determined a linear swell of 1.55 corresponding to a volumetric increase of a factor of 3.7 and a decrease in char density by the same factor. These results are highly significant, and indicate significantly faster burnout at elevated pressure due to the low char density and large diameter.

Chris Guenther, Ph.D.

2003-01-28T23:59:59.000Z

147

Steam-Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture  

SciTech Connect (OSTI)

We present experimental results of coal gasification with and without the addition of calcium oxide and potassium hydroxide as dual-functioning catalyst–capture agents. Using two different coal types and temperatures between 700 and 900 °C, we studied the effect of these catalyst–capture agents on (1) the syngas composition, (2) CO{sub 2} and H{sub 2}S capture, and (3) the steam–coal gasification kinetic rate. The syngas composition from the gasifier was roughly 20% methane, 70% hydrogen, and 10% other species when a CaO/C molar ratio of 0.5 was added. We demonstrated significantly enhanced steam–coal gasification kinetic rates when adding small amounts of potassium hydroxide to coal when operating a CaO–CaCO{sub 3} chemical looping gasification reactor. For example, the steam–coal gasification kinetic rate increased 250% when dry mixing calcium oxide at a Ca/C molar ratio of 0.5 with a sub-bituminous coal, and the kinetic rate increased 1000% when aqueously mixing calcium oxide at a Ca/C molar ratio of 0.5 along with potassium hydroxide at a K/C molar ratio of 0.06. In addition, we conducted multi-cycle studies in which CaCO{sub 3} was calcined by heating to 900 °C to regenerate the CaO, which was then reused in repeated CaO–CaCO{sub 3} cycles. The increased steam–coal gasification kinetics rates for both CaO and CaO + KOH persisted even when the material was reused in six cycles of gasification and calcination. The ability of CaO to capture carbon dioxide decreased roughly 2–4% per CaO–CaCO{sub 3} cycle. We also discuss an important application of this combined gasifier–calciner to electricity generation and selling the purge stream as a precalcined feedstock to a cement kiln. In this scenario, the amount of purge stream required is fixed not by the degradation in the capture ability but rather by the requirements at the cement kiln on the amount of CaSO{sub 4} and ash in the precalcined feedstock.

Siefert, Nicholas S.; Shekhawat, Dushyant; Litster, Shawn; Berry, David, A

2013-08-01T23:59:59.000Z

148

Prediction of oxy-coal flame stand-off using high-fidelity thermochemical models  

E-Print Network [OSTI]

Prediction of oxy-coal flame stand-off using high-fidelity thermochemical models and the one Abstract An Eulerian one-dimensional turbulence (ODT) model is applied to simulate oxy-coal combustion temperature and mixing rate on oxy-coal flame is simulated and discussed where flame stand-off is used

149

Reduced Sulfur in Ashes and Slags from the Gasification of Coals: Availability for Chemical and Microbial Oxidation  

Science Journals Connector (OSTI)

...the TXB-thiosulfate medium described by Brannan...replaced the sulfates. The medium con- tained the following...99. Growth in the medium was scored positive if...Ash and slag particle size distribu- tions were...S OXIDATION IN COAL GASIFIER SOLID WASTES 745 6 E...

Richard F. Strayer; Edward C. Davis

1983-03-01T23:59:59.000Z

150

NETL: Clean Coal Technology Demonstration Program (CCTDP) - Round 2  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2 2 Environmental Control Technologies - NOx Control Technologies Demonstration of Selective Catalytic Reduction Technology for the Control of NOx Emissions from High-Sulfur Coal-Fired Boilers - Project Brief [PDF-247KB] Southern Company Services, Pensacola, FL PROGRAM PUBLICATIONS Final Reports Innovative Clean Coal Technologies (ICCT) Demonstration of Selective Catalytic Reduction (SCR) Technology for the Control of Nitrogen Oxide (NOx) Emissions from High-Sulfur Coal-Fired Boilers Volume 1, Final Report [PDF-29MB] (Oct 1996) Volume 2, Appendices A-N [PDF-20.2MB] (Oct 1996) Volume 3, Appendices O-T [PDF-17.9MB] (Oct 1996) CCT Reports: Project Performance Summaries, Post-Project Assessments, & Topical Reports Demonstration Of Selective Catalytic Reduction For The Control Of NOx Emissions From High-Sulfur Coal-Fired Boilers, Project Performance Summary [PDF-1.1MB] (Nov 2002)

151

Manganese and Ceria Sorbents for High Temperature Sulfur Removal from Biomass-Derived Syngas -- The Impact of Steam on Capacity and Sorption Mode  

SciTech Connect (OSTI)

Syngas derived from biomass and coal gasification for fuel synthesis or electricity generation contains sulfur species that are detrimental to downstream catalysts or turbine operation. Sulfur removal in high temperature, high steam conditions has been known to be challenging, but experimental reports on methods to tackle the problem are not often reported. We have developed sorbents that can remove hydrogen sulfide from syngas at high temperature (700 C), both in dry and high steam conditions. The syngas composition chosen for our experiments is derived from statistical analysis of the gasification products of wood under a large variety of conditions. The two sorbents, Cu-ceria and manganese-based, were tested in a variety of conditions. In syngas containing steam, the capacity of the sorbents is much lower, and the impact of the sorbent in lowering H{sub 2}S levels is only evident in low space velocities. Spectroscopic characterization and thermodynamic consideration of the experimental results suggest that in syngas containing 45% steam, the removal of H{sub 2}S is primarily via surface chemisorptions. For the Cu-ceria sorbent, analysis of the amount of H{sub 2}S retained by the sorbent in dry syngas suggests both copper and ceria play a role in H{sub 2}S removal. For the manganese-based sorbent, in dry conditions, there is a solid state transformation of the sorbent, primarily into the sulfide form.

Cheah, S.; Parent, Y. O.; Jablonski, W. S.; Vinzant, T.; Olstad, J. L.

2012-07-01T23:59:59.000Z

152

Coal surface control for advanced fine coal flotation. Final report, October 1, 1988--March 31, 1992  

SciTech Connect (OSTI)

The initial goal of the research project was to develop methods of coal surface control in advanced froth flotation to achieve 90% pyritic sulfur rejection, while operating at Btu recoveries above 90% based on run-of-mine quality coal. Moreover, the technology is to concomitantly reduce the ash content significantly (to six percent or less) to provide a high-quality fuel to the boiler (ash removal also increases Btu content, which in turn decreases a coal`s emission potential in terms of lbs SO{sub 2}/million Btu). (VC)

Fuerstenau, D.W.; Hanson, J.S.; Diao, J.; Harris, G.H.; De, A.; Sotillo, F. [California Univ., Berkeley, CA (United States); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. [Columbia Univ., New York, NY (United States); Hu, W.; Zou, Y.; Chen, W. [Utah Univ., Salt Lake City, UT (United States); Choudhry, V.; Shea, S.; Ghosh, A.; Sehgal, R. [Praxis Engineers, Inc., Milpitas, CA (United States)

1992-03-01T23:59:59.000Z

153

High Resolution He-like Argon And Sulfur Spectra From The PSI ECRIT  

E-Print Network [OSTI]

We present new results on the X-ray spectroscopy of multicharged argon, sulfur and chlorine obtained with the Electron Cyclotron Resonance Ion Trap (ECRIT) in operation at the Paul Scherrer Institut (Villigen, Switzerland). We used a Johann-type Bragg spectrometer with a spherically-bent crystal, with an energy resolution of about 0.4 eV. The ECRIT itself is of a hybrid type, with a superconducting split coil magnet, special iron inserts which provides the mirror field, and a permanent magnetic hexapole. The high frequency was provided by a 6.4 GHz microwave emitter. We obtained high intensity X-ray spectra of multicharged F-like to He-like argon, sulfur and chlorine with one 1s hole. In particular, we observed the $1s2s^{3}S_1 \\to 1s^2^{1}S_0 M1$ and $1s2p^{3}P_2 \\to 1s^2^{1}S_0 M2$ transitions in He-like argon, sulfur and chlorine with unprecedented statistics and resolution. The energies of the observed lines are being determined with good accuracy using the He-like M1 line as a reference.

Trassinelli, M; Boucard, S; Covita, D S; Dos Santos, J M F; Gotta, D; Hirtl, A; Indelicato, P J; Le Bigot, E O; Leoni, B; Simons, L M; Stingelin, L; Veloso, J F C; Wasser, A; Zmeskal, J; Bigot, Eric-Olivier Le; Biri, Sandor; Boucard, Stephane; Covita, Daniel S.; Gotta, Detlev; Hirtl, Albert; Indelicato, Paul; Leoni, Bruno; Santos, Joaquim M.F. Dos; Simons, Leopold M.; Stingelin, Lucas; Trassinelli, Martino; Veloso, Joao F.C.A.; Wasser, Alfred; Zmeskal, Johann; ccsd-00003163, ccsd

2004-01-01T23:59:59.000Z

154

The Shenhua coal direct liquefaction plant  

Science Journals Connector (OSTI)

Hydrocarbon Technologies (HTI) has been working on a feasibility study for the construction of a Direct Coal Liquefaction Plant in Shenhua coalfield of China. HTI's direct coal liquefaction process, consisting primarily of two backmixed reactor stages plus a fixed-bed inline hydrotreater, operates at a pressure of 17 \\{MPa\\} and reactor temperatures in the range of 400–460°C. A dispersed superfine iron catalyst, GelCat®, is used in the process. Phase I of the study was successfully completed. Two coal sample from a coal mine in Shenhua coalfield were tested on HTI's continuous flow unit (CFU). Results were very encouraging. Though Shenhua coals are high in inert materials, HTI's coal liquefaction process has been able to achieve coal conversion of higher than 91 wt.% (on moisture and ash free, maf, coal) under all test conditions. Under the best conditions tested, distillate product yields from Shenhua coals are between 63–68 wt.% (maf coal). Liquid products are very low in sulfur and nitrogen, thus, very clean. Phase II is now underway. An additional test was conducted on a coal from another coal mine in Shenhua coalfield, which showed similar performance on liquefaction. Preliminary economic assessment is also discussed.

Alfred G. Comolli; Theo L.K. Lee; Gabriel A. Popper; Peizheng Zhou

1999-01-01T23:59:59.000Z

155

Encoal mild coal gasification project: Final design modifications report  

SciTech Connect (OSTI)

The design, construction and operation Phases of the Encoal Mild Coal Gasification Project have been completed. The plant, designed to process 1,000 ton/day of subbituminous Power River Basin (PRB) low-sulfur coal feed and to produce two environmentally friendly products, a solid fuel and a liquid fuel, has been operational for nearly five years. The solid product, Process Derived Fuel (PDF), is a stable, low-sulfur, high-Btu fuel similar in composition and handling properties to bituminous coal. The liquid product, Coal Derived Liquid (CDL), is a heavy, low-sulfur, liquid fuel similar in properties to heavy industrial fuel oil. Opportunities for upgrading the CDL to higher value chemicals and fuels have been identified. Significant quantities of both PDF and CDL have been delivered and successfully burned in utility and industrial boilers. A summary of the Project is given.

NONE

1997-07-01T23:59:59.000Z

156

PRODUCTION OF HYDROGEN AND ELECTRICITY FROM COAL WITH CO2 CAPTURE  

E-Print Network [OSTI]

gasification, quench cooled and shifted to (pri- marily) H2 and CO2 via sulfur-tolerant water-gas shift (WGS with sulfur-bearing waste gases, H2S and SO2. I. INTRODUCTION Carbon-free energy carriers, H2 and electricity relative abundance, high carbon intensity, and low cost. Coal-to-H2 plants based on gasification have been

157

DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS  

E-Print Network [OSTI]

of coal sulfur K-T gasification process SRC I process U. S.flow sheet of a K-T coal gasification complex for producingProduction via K-T Gasification" © CEP Aug. 78. Feed

Wrathall, James Anthony

2011-01-01T23:59:59.000Z

158

POC-SCALE TESTING OF AN ADVANCED FINE COAL DEWATERING EQUIPMENT/TECHNIQUE  

SciTech Connect (OSTI)

The main objective of the proposed program is to evaluate a novel surface modification technique, which utilizes the synergistic effect of metal ions-surfactant combination, for dewatering of ultra-fine clean coal on a proof-of-concept scale of 1 to 2 tph. The novel surface modification technique developed at the UKCAER will be evaluated using vacuum, centrifuge, and hyperbaric filtration equipment. Dewatering tests will be conducted using the fine clean-coal froth produced by the column flotation units at the Powell Mountain Coal Company, Mayflower Preparation Plant in St. Charles, Virginia. The POC-scale studies will be conducted on two different types of clean coal, namely, high-sulfur and low-sulfur clean coal. The Mayflower Plant processes coals from five different seams, thus the dewatering studies results could be generalized for most of the bituminous coals.

B.K. PAREKH; D. TAO; J.G. GROPPO

1998-02-03T23:59:59.000Z

159

Coal-fueled high-speed diesel engine development: Task 2, Market assessment and economic analysis  

SciTech Connect (OSTI)

Based on the preliminary coal engine design developed, this task was conducted to identify the best opportunity(s) to enter the market with the future coal-fueled, high-speed diesel engine. The results of this market and economic feasibility assessment will be used to determine what specific heavy duty engine application(s) are most attractive for coal fuel, and also define basic economic targets for the engine to be competitive.

Not Available

1991-12-01T23:59:59.000Z

160

THE COMBUSTION OF SOLVENT REPINED COAL IN AN OPPOSED FLOW DIFFUSION FLAME  

E-Print Network [OSTI]

refining, the sulfur and ash levels of coal may be reduced.pressed pulverized coal with significant ash production inin both sulfur and ash in comparison with the parent coal.

Chin, W.K.

2011-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS  

SciTech Connect (OSTI)

The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to maintain a cost-competitive, environmentally acceptable coal-based electric generation option. High sulfur coals will specifically benefit in this respect by having these advanced materials evaluated in high-sulfur coal firing conditions and from the significant reductions in waste generation inherent in the increased operational efficiency. Second, from a national prospective, the results of this program will enable domestic boiler manufacturers to successfully compete in world markets for building high-efficiency coal-fired power plants.

R. Viswanathan; K. Coleman; R.W. Swindeman; J. Sarver; J. Blough; W. Mohn; M. Borden; S. Goodstine; I. Perrin

2003-10-20T23:59:59.000Z

162

BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS  

SciTech Connect (OSTI)

The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to maintain a cost-competitive, environmentally acceptable coal-based electric generation option. High sulfur coals will specifically benefit in this respect by having these advanced materials evaluated in high-sulfur coal firing conditions and from the significant reductions in waste generation inherent in the increased operational efficiency. Second, from a national prospective, the results of this program will enable domestic boiler manufacturers to successfully compete in world markets for building high-efficiency coal-fired power plants.

R. Viswanathan; K. Coleman; R.W. Swindeman; J. Sarver; J. Blough; W. Mohn; M. Borden; S. Goodstine; I. Perrin

2003-08-04T23:59:59.000Z

163

Why sequence Alkaliphilic sulfur oxidizing bacteria for sulfur pollution  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Alkaliphilic sulfur oxidizing Alkaliphilic sulfur oxidizing bacteria for sulfur pollution remediation? Burning sulfur-containing fuels, such as coal, oil, and natural gas, contributes significantly to global environmental problems, such as air pollution and acid rain, besides contributing to the loss of the ozone layer. One method of managing sulfur compounds released as byproducts from industrial processes is to scrub them out using chemical treatments and activated charcoal beds. A lower-cost solution relies on incorporating alkaliphic sulfur-oxidizing bacteria into biofilters to convert the volatile and toxic compounds into insoluble sulfur for easier removal. Discovered in the last decade, these bacteria have been found to thrive in habitats that span the full pH range. The bacteria could have applications

164

Development of a new FGD process that converts sulfur dioxide to salable ammonium phosphate fertilizer  

SciTech Connect (OSTI)

Rich mineral resources have enabled Chinese coal output and energy consumption to rank second and third in the world, respectively. In 1992, up to 70 percent of the country`s electric power was generated by the combustion of some 300 million tons of coal. Although the average sulfur content level in Chinese coals is only about 0.8 percent, the share of high- sulfur coals with 2 percent or more sulfur content is as high as 18 percent. As a result, air pollution accompanied by acid rain now occurs over most of the country, especially in southwestern China. Currently, the area comprising Guangdong, Guangxi, the Sichuan Basin, and the greater part of Gueizhou, where the sulfur content in coal is between 2 and 7 percent and the average pH values of rain water are between 4 and 5 per annum, has become one of the three biggest acid rain-affected areas in the world. In 1992, the national installed coal-fired electricity generation capacity exceeded 100,000 MWe. By the year 2000, it is expected to reach as much as 200,000 MWe, according to a new scheduled program. Environmental pollution caused by large-scale coal combustion is a very important issue that needs to be considered in the implementation of the program. To ensure that the effects of coal-fired power generation on the environment can be properly controlled in the near future, TPRI (Thermal Power Research Institute), the sole thermal power engineering research institution within the Ministry of Electric Power Industry (MOEPI), has conducted a long-term research program to develop sulfur emission control technologies suitable to the special conditions prevalent in China since the early 1970s. The details are summarized. The objective of this chapter is to describe the fundamental concept and major pilot test results and present an economic evaluation of a new process combining flue gas desulfurization (FGD) and ammonium phosphate fertilizer production.

Ji-lu Chen

1993-12-31T23:59:59.000Z

165

Opening New Avenues for High-Efficiency, Low-Emission Coal Gasification |  

Broader source: Energy.gov (indexed) [DOE]

Opening New Avenues for High-Efficiency, Low-Emission Coal Opening New Avenues for High-Efficiency, Low-Emission Coal Gasification Opening New Avenues for High-Efficiency, Low-Emission Coal Gasification April 10, 2012 - 1:00pm Addthis A rendering of the Pratt & Whitney Rocketdyne high pressure, dry-solids feed pump. A rendering of the Pratt & Whitney Rocketdyne high pressure, dry-solids feed pump. Washington, DC - Gasification. It's a versatile technology that uses coal to produce power, chemicals, and fuels. Inherently low in air emissions, solid byproducts, and wastewater, commercial gasification plants have proven capable of exceeding the most stringent regulations for air- and solids-emissions. However, capital and operational costs have prohibited the widespread adoption of gasification, especially for power

166

Simulation and modeling of atmospheric fluidized bed combustors for high sulfur coals  

SciTech Connect (OSTI)

The principal issues in modeling atmospheric fluidized bed combustors (AFBC) are described using the Oak Ridge National Laboratory (ORNL) - Tennessee Valley Authority (TVA) steady state AFBC model as an example. Comparisons are made between model predictions of boiler performance with experimental data from the TVA 20 MW(e) AFBC pilot plant data. Recent FBC models are briefly reviewed and compared with the ORNL-TVA model. The paper also describes the ongoing effort at TVA on transient modeling of AFBC and presents some preliminary results from the TVA AFBC transient model.

Krishnan, R.P.; Daw, C.S.; Byrd, J.; Zielke, R.; Wells, J.W.

1986-01-01T23:59:59.000Z

167

Pyrolysis behavior of coal and petroleum coke at high temperature and high pressure.  

E-Print Network [OSTI]

??While pyrolysis of coal is a well-studied thermal process, little is known about pressurized pyrolysis of coal and petroleum coke. This study aims to interpret… (more)

Wagner, David Ray

2011-01-01T23:59:59.000Z

168

Underground coal gasification field experiment in the high-dipping coal seams  

SciTech Connect (OSTI)

In this article the experimental conditions and process of the underground gasification in the Woniushan Mine, Xuzhou, Jiangsu Province are introduced, and the experimental results are analyzed. By adopting the new method of long-channel, big-section, and two-stage underground coal gasification, the daily gas production reaches about 36,000 m{sup 3}, with the maximum output of 103,700 m{sup 3}. The daily average heating value of air gas is 5.04 MJ/m{sup 3}, with 13.57 MJ/m{sup 3} for water gas. In combustible compositions of water gas, H{sub 2} contents stand at over 50%, with both CO and CH{sub 4} contents over 6%. Experimental results show that the counter gasification can form new temperature conditions and increase the gasification efficiency of coal seams.

Yang, L.H.; Liu, S.Q.; Yu, L.; Zhang, W. [China University of Mining & Technology, Xuzhou (China). College of Resources & Geoscience

2009-07-01T23:59:59.000Z

169

The Argonne Premium Coal Sample Program  

Science Journals Connector (OSTI)

The Argonne Premium Coal Sample Program ... Direct Determination of Sulfur Species in Coals from the Argonne Premium Sample Program by Solid Sampling Electrothermal Vaporization Inductively Coupled Plasma Optical Emission Spectrometry ... Direct Determination of Sulfur Species in Coals from the Argonne Premium Sample Program by Solid Sampling Electrothermal Vaporization Inductively Coupled Plasma Optical Emission Spectrometry ...

Karl S. Vorres

1990-09-01T23:59:59.000Z

170

Selective flotation of inorganic sulfides from coal  

DOE Patents [OSTI]

Pyritic sulfur is removed from coal or other carbonaceous material through the use of humic acid as a coal flotation depressant. Following the removal of coarse pyrite, the carbonaceous material is blended with humic acid, a pyrite flotation collector and a frothing agent within a flotation cell to selectively float pyritic sulfur leaving clean coal as an underflow. 1 fig., 2 tabs.

Miller, K.J.; Wen, Wu-Wey

1988-05-31T23:59:59.000Z

171

Selective flotation of inorganic sulfides from coal  

DOE Patents [OSTI]

Pyritic sulfur is removed from coal or other carbonaceous material through the use of humic acid as a coal flotation depressant. Following the removal of coarse pyrite, the carbonaceous material is blended with humic acid, a pyrite flotation collector and a frothing agent within a flotation cell to selectively float pyritic sulfur leaving clean coal as an underflow.

Miller, Kenneth J. (Floreffe, PA); Wen, Wu-Wey (Murrysville, PA)

1989-01-01T23:59:59.000Z

172

EIS-0282: McIntosh Unit 4 TCFB Demonstration Project, Clean Coal Technology Program, Lakeland, Florida (also see EIS-0304)  

Broader source: Energy.gov [DOE]

The proposed project, selected under DOE’s Clean Coal Technology Program, would demonstrate both Pressurized Circulating Fluidized Bed (PCFB) and Topped PCFB technologies. The proposed project would involve the construction and operation of a nominal 238 MWe (megawatts of electric power) combined-cycle power plant designed to burn a range of low- to high-sulfur coals.

173

High temperature ceramic membrane reactors for coal liquid upgrading  

SciTech Connect (OSTI)

In this project we will study a novel process concept, i.e., the use of ceramic membrane reactors in upgrading of coal model compounds and coal derived liquids. In general terms, the USC research team is responsible for constructing and operating the membrane reactor apparatus and for testing various inorganic membranes for the upgrading of coal derived asphaltenes and coal model compounds. The USC effort will involve the principal investigator of this project and two graduate research assistants. The ALCOA team is responsible for the preparation of the inorganic membranes, for construction and testing of the ceramic membrane modules, and for measurement of their transport properties. The ALCOA research effort will involve Dr. Paul K. T. Liu, who is the project manager of the ALCOA research team, an engineer and a technician. UNOCAL's contribution will be limited to overall technical assistance in catalyst preparation and the operation of the laboratory upgrading membrane reactor and for analytical back-up and expertise in oil analysis and materials characterization. UNOCAL is a no-cost contractor but will be involved in all aspects of the project, as deemed appropriate.

Tsotsis, T.T.

1992-01-01T23:59:59.000Z

174

Desulfurization of coal: enhanced selectivity using phase transfer catalysts. Quarterly report, March 1 - May 31, 1996  

SciTech Connect (OSTI)

Due to environmental problems related to the combustion of high sulfur Illinois coal, there continues to be interest in the development in viable pre-combustion desulfurization processes. Recent studies by the authors have obtained very good sulfur removals but the reagents that are used are too expensive. Use of cheaper reagents leads to a loss of desired coal properties. This study investigated the application phase transfer catalysts to the selective oxidation of sulfur in coal using air and oxygen as oxidants. The phase transfer catalyst is expected to function as a selectivity moderator by permitting the use of milder reaction conditions that otherwise necessary. This would enhance the sulfur selectivity and help retain the heating value of the coal. The use of certain coal combustion wastes for desulfurization, and the application of cerium (IV) catalyzed air oxidation for selective sulfur oxidation are also being studied. If successful, this project could lead to the rapid development of a commercially viable desulfurization process. This would significantly improve the marketability of Illinois coal.

Palmer, S.R.; Hippo, E.J. [Southern Illinois Univ., Carbondale, IL (United States)

1996-12-31T23:59:59.000Z

175

HYBRID SULFUR CYCLE FLOWSHEETS FOR HYDROGEN PRODUCTION USING HIGH-TEMPERATURE GAS-COOLED REACTORS  

SciTech Connect (OSTI)

Two hybrid sulfur (HyS) cycle process flowsheets intended for use with high-temperature gas-cooled reactors (HTGRs) are presented. The flowsheets were developed for the Next Generation Nuclear Plant (NGNP) program, and couple a proton exchange membrane (PEM) electrolyzer for the SO2-depolarized electrolysis step with a silicon carbide bayonet reactor for the high-temperature decomposition step. One presumes an HTGR reactor outlet temperature (ROT) of 950 C, the other 750 C. Performance was improved (over earlier flowsheets) by assuming that use of a more acid-tolerant PEM, like acid-doped poly[2,2'-(m-phenylene)-5,5'-bibenzimidazole] (PBI), instead of Nafion{reg_sign}, would allow higher anolyte acid concentrations. Lower ROT was accommodated by adding a direct contact exchange/quench column upstream from the bayonet reactor and dropping the decomposition pressure. Aspen Plus was used to develop material and energy balances. A net thermal efficiency of 44.0% to 47.6%, higher heating value basis is projected for the 950 C case, dropping to 39.9% for the 750 C case.

Gorensek, M.

2011-07-06T23:59:59.000Z

176

Sulfur removal and comminution of carbonaceous material  

DOE Patents [OSTI]

Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product. 2 figs.

Narain, N.K.; Ruether, J.A.; Smith, D.N.

1987-10-07T23:59:59.000Z

177

Sulfur removal and comminution of carbonaceous material  

DOE Patents [OSTI]

Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product.

Narain, Nand K. (Bethel Park, PA); Ruether, John A. (McMurray, PA); Smith, Dennis N. (Herminie, PA)

1988-01-01T23:59:59.000Z

178

NETL: Coal & Coal Biomass to Liquids - NETL H2-from-Coal Separations  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Coal/Biomass to Liquids - Reference Shelf and Coal/Biomass to Liquids - Reference Shelf NETL H2-from-Coal Separations Project Reviews April 29-30, 2008 National Energy Technology Laboratory Morgantown, WV Presentations NETL/ORD In-House Membrane Research Bryan Morreale - National Energy Technology Laboratory Development of Mixed-Conducting Dense Ceramic Membranes for Hydrogen Separation [PDF-1.4MB] Hydrogen Production by Water Dissociation Using Ceramic Membranes Balu Balachandran - Argonne National Laboratory High Flux Metallic Membranes for Hydrogen Recovery and Membrane Reactors [PDF-505KB] Robert Buxbaum - REB Research and Consulting Scale-Up of Hydrogen Transport Membranes for IGCC and FutureGen Plants Doug Jack - Eltron Research Sulfur and Halide Tolerance Kent Coulter - Southwest Research Institute

179

Assessment of the effect of high ash content in pulverized coal combustion  

SciTech Connect (OSTI)

The existing literature on CFD-based coal combustion modelling is applicable mainly for coals of low ash content and the calculations are done on an ash-free basis. In Indian coals, the ash content may be significantly higher, up to 40% or more. Studies reported in the literature show that the mineral matter in the coal may have a number of effects on the combustion characteristics. In the present study, a sensitivity analysis is performed, using the CFD code CFX of AEA Technology, on the likely effect of ash content on the char reactivity, oxygen diffusion rate for char combustion and on the radiative heat transfer parameters. The results show that the effect of enhanced char reactivity is negligible whereas reduced oxygen diffusion rates due to a thicker ash layer may result in a significant reduction in char oxidation rates with a resultant decrease in the peak temperature in the furnace. The global parameters such as the peak temperature and the flue gas temperature remain relatively insensitive to the presence of high ash content. These results are consistent with the experimental observations of Kurose et al. . Kurose, M. Ikeda, H. Makino, Combustion characteristics of high ash coal in pulverized coal combustion, J. Fuel 80 (2001) 1447-1455).

Jayanti, S.; Maheswaran, K.; Saravanan, V. [Indian Institute of Technology, Madras (India). Dept. of Chemical Engineering

2007-05-15T23:59:59.000Z

180

NETL: Clean Coal Demonstrations - Coal 101  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A "Bed" for Burning Coal A "Bed" for Burning Coal Clean Coal 101 Lesson 4: A "Bed" for Burning Coal? It was a wet, chilly day in Washington DC in 1979 when a few scientists and engineers joined with government and college officials on the campus of Georgetown University to celebrate the completion of one of the world's most advanced coal combustors. It was a small coal burner by today's standards, but large enough to provide heat and steam for much of the university campus. But the new boiler built beside the campus tennis courts was unlike most other boilers in the world. A Fluidized Bed Boiler A Fluidized Bed Boiler In a fluidized bed boiler, upward blowing jets of air suspend burning coal, allowing it to mix with limestone that absorbs sulfur pollutants.

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Dynamic accident modeling for high-sulfur natural gas gathering station  

Science Journals Connector (OSTI)

Abstract Dynamic accident modeling for a gas gathering station is implemented to prevent high-sulfur natural gas leakage and develop equipment inspection strategy. The progress of abnormal event occurring in the gas gathering station is modeled by the combination of fault tree and event sequence diagram, based on accident causal chain theory, i.e. the progress is depicted as sequential failure of safety barriers, then, the occurrence probability of the consequence of abnormal event is predicted. Consequences of abnormal events are divided into accidents and accident precursors which include incidents, near misses and so on. The Bayesian theory updates failure probability of safety barrier when a new observation (i.e. accident precursors or accidents data) arrives. Bayesian network then correspondingly updates failure probabilities of basic events of the safety barriers with the ability of abductive reasoning. Consequence occurrence probability is also updated. The results show that occurrence probability trend of different consequences and failure probability trend of safety barriers and basic events of the safety barriers can be obtained using this method. In addition, the critical basic events which play an important role in accidents occurrence are also identified. All of these provide useful information for the maintenance and inspection of the gas gathering station.

Qinglei Tan; Guoming Chen; Lei Zhang; Jianmin Fu; Zemin Li

2014-01-01T23:59:59.000Z

182

Effect of bituminous coal properties on carbon dioxide and methane high pressure sorption  

Science Journals Connector (OSTI)

Abstract High pressure sorption experiments with carbon dioxide and methane were carried out at a temperature of 45 °C and at pressures up to 15 MPa with three samples of methane-bearing, medium-rank coals in a moisture-equilibrated state using a manometric method. The samples were taken from selected positions of drill cores from exploration boreholes in the Bohemian part of the Upper Silesian Basin, and were characterized by a narrow range of degree of coalification and markedly different petrographic compositions, including a different mineral matter content. The total porosity of the coal samples was between 9% and 10%. A positive correlation was found between the equilibrium moisture in the coal samples and the total abundance of oxygen functional groups determined by FTIR. The excess sorption capacities ranged from 0.78 to 0.91 mmol g?1 for CO2 and from 0.45 to 0.52 mmol g?1 for CH4, and after recalculation to coal organic matter, the excess sorption capacities increased by up to 14% in the coal with the highest mineral fraction. The highest CO2/CH4 ratio was found in the sample that had the highest inertinite and liptinite content. The experimental isotherm data was fitted by modified Langmuir and Dubinin–Radushkevich sorption isotherms. The parameters obtained by these two methods were in good agreement for carbon dioxide. It was found that the sorption capacity of the organic matter in a coal sample with prevalence of inertinite (63.0 vol.%) was lower only by 14% for CO2 and by 18% for CH4 than the sorption capacity of the organic matter in a coal sample with prevalence of vitrinite (65.3 vol.%). This provided confirmation that the petrographic composition of a coal has an ambiguous effect.

Zuzana Weishauptová; Old?ich P?ibyl; Ivana Sýkorová; Vladimír Machovi?

2015-01-01T23:59:59.000Z

183

In-plant testing of a novel coal cleaning circuit using advanced technologies. Final technical report, September 1, 1995--August 31, 1996  

SciTech Connect (OSTI)

A circuit comprised of advanced fine coal cleaning technologies was evaluated in an operating preparation plant to determine circuit performance and to compare the performance with current technologies used to treat -16 mesh fine coal. The circuit integrated a Floatex hydrosizer, a Falcon enhanced gravity concentrator and a Jameson flotation cell. A Packed-Column was used to provide additional reductions in the pyritic sulfur and ash contents by treatment of the Floatex-Falcon-Jameson circuit product. For a low sulfur Illinois No. 5 coal, the pyritic sulfur content was reduced from 0.67% to 0.34% at a combustible recovery of 93.2%. The ash content was decreased from 27.6% to 5.84%, which equates to an organic efficiency of 95% according to gravity-based washability data. The separation performance achieved on a high sulfur Illinois No. 5 coal resulted in the rejection of 72.7% of the pyritic sulfur and 82.3% of the ash-forming material at a recovery of 8 1 %. Subsequent pulverization of the cleaned product and retreatment in a Falcon concentrator and Packed-Column resulted in overall circuit ash and pyritic sulfur rejections of 89% and 93%, respectively, which yielded a pyritic sulfur content reduction from 2.43% to 0.30%. This separation reduced the sulfur dioxide emission rating of an Illinois No. 5 coal from 6.21 to 1.75 lbs SO{sub 2}/MBTU, which is Phase I compliance coal. A comparison of the results obtained from the Floatex-Falcon-Jameson circuit with those of the existing circuit revealed that the novel fine coal circuit provides 10% to 20% improvement in mass yield to the concentrate while rejecting greater amounts of ash and pyritic sulfur.

Honaker, R.Q. [Southern Illinois Univ., Carbondale, IL (United States). Dept. of Mining Engineering; Reed, S.; Mohanty, M.K.

1997-05-01T23:59:59.000Z

184

Coal combustion and cogeneration at New York Institute of Technology, Central Islip campus. Final report. [NYIT CI campus  

SciTech Connect (OSTI)

The purpose of this project is to study the technical and economic feasibility of conversion to coal with possible implementation of cogeneration at the central power plant of the New York Institute of Technology Central Islip (NYIT CI) campus. The existing facility contains five moderate pressure (155 psig) 60,000 pph boilers installed in 1953-1954 which were originally designed for coal firing. Among the several systems assessed, three potential projects were identified as having economic merit and conceptual designs for their implementation were developed. The final decision as to which should be pursued must await a final determination of environmental issues related to sulfur dioxide emissions and manufacturer recommendations on the ability to reconvert one of the existing boilers back to coal. The three projects, in order of economic merit, are as follows: (1) reconversion of one of the existing 60,000 pph stoker boilers back to firing coal; (2) installation of a new 60,000 pph stoker fired, high pressure coal boiler with a 2300 kW backpressure steam turbine, the turbine to provide some cogeneration capability. Compliance, low sulfur, coal is to be burned; (3) installation of a new 50,000 pph, low pressure, firetube, fluidized bed combustion (FBC), boiler burning high sulfur coal but including sulfur dioxide capture. The first two projects are predicated on the burning of a compliance, low sulfur, coal. This may be allowed under ''grandfather'' clauses in the regulations that permit such burning in boilers that once fired coal. If not permitted, the installation of the low pressure FBC boiler would be the only remaining viable coal conversion option. Though it has a smaller payback, it still provides significant savings to the college.

Not Available

1984-04-01T23:59:59.000Z

185

Sorbent utilization prediction methodology: sulfur control in fluidized-bed combustors  

SciTech Connect (OSTI)

The United States Government has embarked on an ambitious program to develop and commercialize technologies to efficiently extract energy from coal in an environmentally acceptable manner. One of the more promising new technologies for steam and power generation is the fluidized-bed combustion of coal. In this process, coal is burned in a fluidized bed composed mainly of calcined limestone sorbent. The calcium oxide reacts chemically to capture the sulfur dioxide formed during the combustion and to maintain the stack gas sulfur emissions at acceptable levels. The spent sulfur sorbent, containing calcium sulfate, is a dry solid that can be disposed of along with coal ash or potentially used. Other major advantages of fluidized-bed combustion are the reduction in nitrogen oxide emissions because of the relatively low combustion temperatures, the capability of burning wide varieties of fuel, the high carbon combustion efficiencies, and the high heat-transfer coefficients. A key to the widespread commercialization of fluidized-bed technology is the ability to accurately predict the amount of sulfur that will be captured by a given sorbent. This handbook meets this need by providing a simple, yet reliable, user-oriented methodology (the ANL method) that allows performance of a sorbent to be predicted. The methodology is based on only three essential sorbent parameters, each of which can be readily obtained from standardized laboratory tests. These standard tests and the subsequent method of data reduction are described in detail.

Fee, D.C.; Wilson, W.I.; Shearer, J.A.; Smith, G.W.; Lenc, J.F.; Fan, L.S.; Myles, K.M.; Johnson, I.

1980-09-01T23:59:59.000Z

186

Bioprocessing of High-sulfur Crudes Via Appliaction of Critical Fluid Biocatalysis  

SciTech Connect (OSTI)

This experimental research project investigated protein-based biocatalysis in supercritical fluid solvents as an integrated process approach to catalyze the removal of sulfur atoms from crude oils and fuels. The work focused on the oxidation of model sulfur-containing compounds in supercritical reaction media and included three major tasks: microbiological induction experiments, proteincatalyzed biooxidation in supercritical solvents, and a work-in-kind cooperative research and development agreement (CRADA). This work demonstrated that the biooxidation reaction could be improved by an order-of-magnitude by carrying out the reaction in emulsions in supercritical fluids.

Ginosar, Daniel Michael; Bala, Greg Alan; Anderson, Raymond Paul; Fox, Sandra Lynn; Stanescue, Marina A.

2002-05-01T23:59:59.000Z

187

Geochemistry of coal from Cretaceous Corwin and Chandler formations, National Petroleum Reserve in Alaska (NPRA)  

SciTech Connect (OSTI)

Ninety coal samples from these formations within NPRA were collected and analyzed in order to evaluate coal quality and elemental distribution. Their apparent rank ranges from lignite A in the northern part of NPRA to high-volatile AS bituminous coal in the southern part. Mean vitrinite reflectance values range from 0.65 to 0.74%. Some Corwin Formation coal samples west of NPRA have coking potential with free-swelling indexes between 3.0 and 5.0. Compared to other western United States Cretaceous coal, NPRA coal is significantly lower in ash, volatile matter, O, Si, Al, Ca, Fe, Ti, Cu, F, Li, Mn, Mo, Pb, Sb, Se, Th, and Zn. Statistical comparisons of element concentrations indicate that the mean content of Si, Al, K, Li, Sc, Y, and Yb increases as the mean ash content increases (correlation coefficient at least 0.7). Sulfur values are extremely low (0.1%), and elements that normally show positive correlation with sulfur, such as Fe, As, Cd, Co, Cu, Mo, Pb, and Zn, are also low. Therefore, coal from NPRA can be characterized by low ash and sulfur contents and low contents of elements of environmental concern, such as As, Be, Hg, Mo, Sb, and Se. The elements found to have positive correlations with ash content are probably present as aluminosilicate or stable oxide minerals. Variations in element content and quality of NPRA coal were probably influenced by the geochemical conditions that existed in the Corwin and Umiat delta systems.

Affolter, R.H.; Stricker, G.D.

1985-04-01T23:59:59.000Z

188

BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS  

SciTech Connect (OSTI)

The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. In the 21st century, the world faces the critical challenge of providing abundant, cheap electricity to meet the needs of a growing global population while at the same time preserving environmental values. Most studies of this issue conclude that a robust portfolio of generation technologies and fuels should be developed to assure that the United States will have adequate electricity supplies in a variety of possible future scenarios. The use of coal for electricity generation poses a unique set of challenges. On the one hand, coal is plentiful and available at low cost in much of the world, notably in the U.S., China, and India. Countries with large coal reserves will want to develop them to foster economic growth and energy security. On the other hand, traditional methods of coal combustion emit pollutants and CO{sub 2} at high levels relative to other generation options. Maintaining coal as a generation option in the 21st century will require methods for addressing these environmental issues. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to maintain a cost-competitive, environmentally acceptable coal-based electric generation option. High sulfur coals will specifically benefit in this respect by having these advanced materials evaluated in high-sulfur coal firing conditions and from the significant reductions in waste generation inherent in the increased operational efficiency. Second, from a national prospective, the results of this program will enable domestic boiler manufacturers to successfully compete in world markets for building high-efficiency coal-fired power plants.

R. Viswanathan; K. Coleman

2003-01-20T23:59:59.000Z

189

BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS  

SciTech Connect (OSTI)

The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. In the 21st century, the world faces the critical challenge of providing abundant, cheap electricity to meet the needs of a growing global population while at the same time preserving environmental values. Most studies of this issue conclude that a robust portfolio of generation technologies and fuels should be developed to assure that the United States will have adequate electricity supplies in a variety of possible future scenarios. The use of coal for electricity generation poses a unique set of challenges. On the one hand, coal is plentiful and available at low cost in much of the world, notably in the U.S., China, and India. Countries with large coal reserves will want to develop them to foster economic growth and energy security. On the other hand, traditional methods of coal combustion emit pollutants and CO{sub 2} at high levels relative to other generation options. Maintaining coal as a generation option in the 21st century will require methods for addressing these environmental issues. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to maintain a cost-competitive, environmentally acceptable coal-based electric generation option. High sulfur coals will specifically benefit in this respect by having these advanced materials evaluated in high-sulfur coal firing conditions and from the significant reductions in waste generation inherent in the increased operational efficiency. Second, from a national prospective, the results of this program will enable domestic boiler manufacturers to successfully compete in world markets for building high-efficiency coal-fired power plants.

R. Viswanathan; K. Coleman

2002-10-15T23:59:59.000Z

190

BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS  

SciTech Connect (OSTI)

The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), and up to 5500 psi with emphasis upon 35 MPa (5000 psi) steam. In the 21st century, the world faces the critical challenge of providing abundant, cheap electricity to meet the needs of a growing global population while at the same time preserving environmental values. Most studies of this issue conclude that a robust portfolio of generation technologies and fuels should be developed to assure that the United States will have adequate electricity supplies in a variety of possible future scenarios. The use of coal for electricity generation poses a unique set of challenges. On the one hand, coal is plentiful and available at low cost in much of the world, notably in the U.S., China, and India. Countries with large coal reserves will want to develop them to foster economic growth and energy security. On the other hand, traditional methods of coal combustion emit pollutants and CO{sub 2} at high levels relative to other generation options. Maintaining coal as a generation option in the 21st century will require methods for addressing these environmental issues. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to maintain a cost-competitive, environmentally-acceptable coal-based electric generation option. High sulfur coals will specifically benefit in this respect by having these advanced materials evaluated in high-sulfur coal firing conditions and from the significant reductions in waste generation inherent in the increased operational efficiency. Second, from a national perspective, the results of this program will enable domestic boiler manufacturers to successfully compete in world markets for building high-efficiency coal-fired power plants.

R. Viswanathan

2002-04-15T23:59:59.000Z

191

BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS  

SciTech Connect (OSTI)

The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. In the 21st century, the world faces the critical challenge of providing abundant, cheap electricity to meet the needs of a growing global population while at the same time preserving environmental values. Most studies of this issue conclude that a robust portfolio of generation technologies and fuels should be developed to assure that the United States will have adequate electricity supplies in a variety of possible future scenarios. The use of coal for electricity generation poses a unique set of challenges. On the one hand, coal is plentiful and available at low cost in much of the world, notably in the U.S., China, and India. Countries with large coal reserves will want to develop them to foster economic growth and energy security. On the other hand, traditional methods of coal combustion emit pollutants and CO{sub 2} at high levels relative to other generation options. Maintaining coal as a generation option in the 21st century will require methods for addressing these environmental issues. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to maintain a cost-competitive, environmentally acceptable coal-based electric generation option. High sulfur coals will specifically benefit in this respect by having these advanced materials evaluated in high-sulfur coal firing conditions and from the significant reductions in waste generation inherent in the increased operational efficiency. Second, from a national prospective, the results of this program will enable domestic boiler manufacturers to successfully compete in world markets for building high-efficiency coal-fired power plants.

R. Viswanathan; K. Coleman

2002-07-15T23:59:59.000Z

192

Elemental sulfur recovery process  

DOE Patents [OSTI]

An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO[sub 2] in the regenerator off gas stream to elemental sulfur in the presence of a catalyst. 4 figures.

Flytzani-Stephanopoulos, M.; Zhicheng Hu.

1993-09-07T23:59:59.000Z

193

Status of coal ash corrosion resistant materials test program  

SciTech Connect (OSTI)

In November of 1998, Babcock and Wilcox (B and W) began development of a system to permit testing of several advanced tube materials at metal temperatures typical of advanced supercritical steam conditions of 1100 F and higher in a boiler exhibiting coal ash corrosive conditions. The U.S. Department of Energy (DOE), the Ohio Coal Development Office (OCDO), B and W, and First Energy's Ohio Edison jointly fund the project. CONSOL Energy Company is also participating as an advisor. Several materials producers including Oak Ridge National Laboratory (ORNL) contributed advanced materials to the project. The coal-ash corrosion resistant materials test program will provide full scale, in-situ testing of recently developed boiler superheater and reheater tube materials. These newer materials may be capable of operating at higher steam temperatures while resisting external/fire-side corrosion. For high sulfur coal applications, this is a key issue for advanced cycle pulverized coal-fired plants. Fireside corrosion is also a critical issue for many existing plants. Previous testing of high temperature materials in the United States has been based primarily on using laboratory test coupons. The test coupons did not operate at conditions representative of a high sulfur coal-fired boiler. Testing outside of the United States has been with low sulfur coal or natural gas firing and has not addressed corrosion issues. This test program takes place in an actual operating boiler and is expected to confirm the performance of these materials with high sulfur coal. The system consists of three identical sections, each containing multiple pieces of twelve different materials. They are cooled by reheater steam, and are located just above the furnace exit in Ohio Edison's Niles Unit No.1, a 110 MWe unit firing high sulfur Ohio coal. After one year of operation, the first section will be removed for thorough metallurgical evaluation. The second and third sections will operate for three and five years respectively prior to removal and evaluation. The objective is to determine how well each material resists corrosion at different operating temperatures and over different time periods and provide characteristic data. Selection of the test materials, system engineering, fabrication, installation and startup of this system is now completed and data acquisition is in progress. This paper gives an overview of the program and its objectives, explains the system, describes section fabrication, identifies the materials selected, and describes ORNL's experience in fabricating four of the advanced materials.

McDonald, D.K.; Meisenhelter, D.K.; Sikka, V.K.

1999-07-01T23:59:59.000Z

194

Co-gasification Reactivity of Coal and Woody Biomass in High-Temperature Gasification  

Science Journals Connector (OSTI)

(20) Although the total pressure was 0.5 MPa and lower than the usual conditions of the gasifier, it has been confirmed that the total pressure has little influence on the gasification rate of char when the partial pressure of the gasifying agent is the same and the total pressure is less than 2 MPa. ... While the pyrolysis and the char gasification were tested separately in the above experiments, raw samples of coals, cedar bark, and the mixtures were gasified with carbon dioxide at high temperature using the PDTF facility in this section, the same as the reductor in the air-blown two-stage entrained flow coal gasifier. ...

Shiro Kajitani; Yan Zhang; Satoshi Umemoto; Masami Ashizawa; Saburo Hara

2009-09-24T23:59:59.000Z

195

Modelling of High-Chromia Refractory Spalling in Slagging Coal Gasifiers  

SciTech Connect (OSTI)

The economic viability of converting coal into clean burning liquid fuels in slagging coal gasifiers is compromised by the limited service lifetime of hot-face refractories. One of the most severe refractory degradation mechanisms is spalling, which can occur by either volume expansion phenomena (compressive stresses) or by volume shrinkage phenomena (tensile stresses). A volume shrinkage model is benchmarked to high-chromia refractory material properties and performance under gasifier operating conditions. The model is found to be appropriate for first order estimates of gasifier refractory lifetime when the apparent diffusivity of volatized Cr in the refractory includes the effects of slag-filled pores and cracks.

Williford, Rick E.; Johnson, Kenneth I.; Sundaram, S. K.

2008-10-31T23:59:59.000Z

196

Rationale for continuing R&D in direct coal conversion to produce high quality transportation fuels  

SciTech Connect (OSTI)

For the foreseeable future, liquid hydrocarbon fuels will play a significant role in the transportation sector of both the United States and the world. Factors favoring these fuels include convenience, high energy density, and the vast existing infrastructure for their production and use. At present the U.S. consumes about 26% of the world supply of petroleum, but this situation is expected to change because of declining domestic production and increasing competition for imports from countries with developing economies. A scenario and time frame are developed in which declining world resources will generate a shortfall in petroleum supply that can be allieviated in part by utilizing the abundant domestic coal resource base. One option is direct coal conversion to liquid transportation fuels. Continued R&D in coal conversion technology will results in improved technical readiness that can significantly reduce costs so that synfuels can compete economically in a time frame to address the shortfall.

Srivastava, R.D.; McIlvried, H.G. [Burns and Roe Services Corp., Pittsburgh, PA (United States); Gray, D. [Mitre Corp, McLean, VA (United States)] [and others

1995-12-31T23:59:59.000Z

197

Coal-water-slurry autoignition in a high-speed Detroit diesel engine  

SciTech Connect (OSTI)

Autoignition of coal-water-slurry (CWS) fuel in a two-stroke engine operating at 1900 RPM has been achieved. A Pump-Line-Nozzle (PLN) injection system, delivering 400mm{sup 3} injection of CWS, was installed in one modified cylinder of a Detroit Diesel Corporation (DDC) 8V-149TI engine, while the other seven cylinders remained configured for diesel fuel. Coal Combustion was sustained by maintaining high gas and surface temperatures with a combination of hot residual gases, warm inlet air admission, ceramic insulated components and increased compression ratio. The coal-fueled cylinder generated 85kW indicated power (80 percent of rated power), and lower NO{sub x} levels with a combustion efficiency of 99.2 percent. 6 refs., 15 figs., 4 tabs.

Schwalb, J.A.; Ryan, T.W. III.; Kakwani, R.M.; Winsor, R.E.

1994-10-01T23:59:59.000Z

198

Experimental studies on hydrophobic flocculation of coal fines in aqueous solutions and flotation of flocculated coal  

Science Journals Connector (OSTI)

Hydrophobic flocculation of fine bituminous coal particles in aqueous solutions under mechanical conditioning and without any surfactants has been experimentally studied through the measurements of aggregative efficiency, zeta potential and contact angle in this work. The results have shown that the hydrophobic coal fines strongly aggregated in a wide pH range (3.5â??9.5), even though the particle surfaces were highly charged. This hydrophobic flocculation closely correlated with particle hydrophobicity, having a stronger aggregation for more hydrophobic coal fines. It reaches the maximum degree only if a sufficient kinetic energy is applied to the coal slurry. Also, it has been found that the hydrophobic flocculation could be greatly enhanced by adding a little amount of nonpolar oil. In addition, the flotation of flocculated coal fines was tested on the fine Prince coal for the deep elimination of ash and pyrite from coals in this work. An ultraclean coal with 1.3% ash remaining was produced with 87% combustible recovery. The ash rejection and pyritic sulfur rejection were about 93% and 66%, respectively.

Shaoxian Song

2008-01-01T23:59:59.000Z

199

Selective catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly technical progress report No. 6, October--December 1993  

SciTech Connect (OSTI)

Elemental sulfur recovery from SO{sub 2}-containing gas stream is highly attractive as it produces a salable product and no waste to dispose of. However, commercially available schemes are complex and involve multi-stage reactors, such as, most notably in the Resox (reduction of SO{sub 2} with coke) and Claus plant (reaction of SO{sub 2} with H{sub 2}S over catalyst). This project will investigate a cerium oxide catalyst for the single stage selective reduction of SO{sub 2} to elemental sulfur by a reductant, such as carbon monoxide. Cerium oxide has been identified in recent work at MIT as a superior catalyst for SO{sub 2} reduction by CO to elemental sulfur because its high activity and high selectivity to sulfur over COS over a wide temperature range (400--650{degree}C). The detailed kinetic and parametric studies of SO{sub 2} reduction planned in this work over various CeO{sub 2} formulations will provide the necessary basis for development of a very simplified process, namely that of a single-stage elemental sulfur recovery scheme from variable concentration gas streams. The potential cost- and energy-efficiency benefits from this approach can not be overstated. A first apparent application is treatment of a regenerator off-gases in power plants using regenerative flue gas desulfurization. Such a simple catalytic converter may offer the long-sought ``Claus-alternative`` for coal-fired power plant applications.

Liu, W.; Flytzani-Stephanopoulos, M.; Sarofim, A.F.

1993-12-31T23:59:59.000Z

200

Selective catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly technical progress report No. 4, April--June 1993  

SciTech Connect (OSTI)

Elemental sulfur recovery from SO{sub 2}-containing gas stream is highly attractive as it produces a salable product and no waste to dispose of. However, commercially available schemes are complex and involve multi-stage reactors, such as, most notably in the Resox (reduction of SO{sub 2} with coke) and Claus plant(reaction of SO{sub 2} with H{sub 2}S over catalyst). This project will investigate a cerium oxide catalyst for the single stage selective reduction of SO{sub 2} to elemental sulfur by a reductant, such as carbon monoxide. Cerium oxide has been identified in recent work at MIT as a superior catalyst for SO{sub 2} reduction by CO to elemental sulfur because its high activity and high selectivity to sulfur over COS over a wide temperature range(400--650{degrees}C). The detailed kinetic and parametric studies of SO{sub 2} reduction planned in this work over various CeO{sub 2}-formulations will provide the necessary basis for development of a very simplified process, namely that of a single-stage elemental sulfur recovery scheme from variable concentration gas streams, The potential cost- and energy-efficiency benefits from this approach can not be overstated. A first apparent application is treatment of a regenerator off-gases in power plants using regenerative flue gas desulfurization. Such a simple catalytic converter may offer the long-sought ``Claus-alternative`` for coal-fired power plant applications.

Liu, Wei; Flytzani-Stephanopoulos, M.; Sarofim, A.F.; Williams, R.S.

1993-12-31T23:59:59.000Z

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201

Coal Study Guide - Middle School | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Middle School Coal Study Guide - Middle School Coal Study Guide - Middle School More Documents & Publications Coal Study Guide for Elementary School Coal Study Guide - High School...

202

Engineering development of coal-fired high-performance power systems  

SciTech Connect (OSTI)

In Phase I of the project, a conceptual design of a coal-fired high performance power system was developed, and small scale R&D was done in critical areas of the design. The current Phase Of the project includes development through the pilot plant stage, and design of a prototype plant that would be built in Phase 3. Foster Wheeler Development Corporation is leading a team of companies in this effort: AlliedSignal Aerospace Equipment Systems, Bechtel Corporation, University of Tennessee Space Institute (UTSI), and Westinghouse Electric Corporation. The power generating system being developed in this project will be an improvement over current coal-fired systems. The following goals have been identified that relate to the efficiency,emissions, costs and general operation of the system: total station efficiency of at least 4 percent on a higher heating value basis; emissions--NOx {lt} 0.06 lb/MMBtu, SOx {lt} 0.06 lb/MMBtu, particulates {lt} 0.003 lb/MMBtu; all solid wastes must be benign with regard to disposal; over 95 percent of the total heat input is ultimately from coal, with initial systems capable of using coal for at least 65 percent of the heat input; 10 percent lower cost of electricity relative to a modern coal-fired plant conforming to NSPS. The base case arrangement of the HIPPS cycle is a combined cycle plant, and is referred to as the All Coal HIPPS because it does not require any other fuels for normal operation. An alternative HIPPS cycle uses a ceramic air heater to heat the air to temperatures above what can be achieved with alloy tubes. This arrangement is referred to as the 35 percent natural gas HIPPS. 2 refs., 11 figs. 3 tabs.

NONE

1996-06-01T23:59:59.000Z

203

Combustion of Illinois coals and chars with natural gas. Final technical report, September 1, 1991--August 31, 1992  

SciTech Connect (OSTI)

Combined combustion of coal and natural gas offers advantages compared to burning coal or natural gas alone. For example, low volatile coals (or chars) derived from treatment or gasification processes can be of limited use due to their poor flammability characteristics. However, the use of natural gas in conjunction with the solid fuel can provide the necessary ``volatiles`` to enhance the combustion. Also, natural gas provides a clean cofiring fuel source which can enhance the usefulness of coals with high sulfur content. Addition of natural gas may reduce SO{sub x} emissions through increased sulfur retention in the ash and reduce NO{sub x} emissions by varying local stoichiometry and temperature levels. This research program addresses the contributions and the mechanisms of cofiring natural gas with Illinois coal through studies of particle ignition, burning rates and ash characterization.

Buckius, R.O.; Peters, J.E.; Krier, H. [Illinois Univ., Urbana-Champaign, IL (United States)

1992-12-31T23:59:59.000Z

204

Role of coal in the world and Asia  

SciTech Connect (OSTI)

This paper examines the changing role of coal in the world and in Asia. Particular attention is given to the rapidly growing demand for coal in electricity generation, the importance of China as a producer and consumer of coal, and the growing environmental challenge to coal. Attention is given to the increasing importance of low sulfur coal and Clean Coal Technologies in reducing the environmental impacts of coal burning.

Johnson, C.J.; Li, B.

1994-10-01T23:59:59.000Z

205

Exploration of coal-based pitch precursors for ultra-high thermal conductivity graphite fibers. Final report  

SciTech Connect (OSTI)

Goal was to explore the utility of coal-based pitch precursors for use in ultra high thermal conductivity carbon (graphite) fibers. From graphite electrode experience, it was established that coal-based pitches tend to form more highly crystalline graphite at lower temperatures. Since the funding was limited to year 1 effort of the 3 year program, the goal was only partially achieved. The coal-base pitches can form large domain mesophase in spite of high N and O contents. The mesophase reactivity test performed on one of the variants of coal-based pitch (DO84) showed that it was not a good candidate for carbon fiber processing. Optimization of WVU`s isotropic pitch process is required to tailor the pitch for carbon fiber processing. The hetero atoms in the coal pitch need to be reduced to improve mesophase formation.

Deshpande, G.V. [Amoco Performance Products, Inc., Alpharetta, GA (United States)

1996-12-27T23:59:59.000Z

206

Clean coal technology applications  

SciTech Connect (OSTI)

{open_quotes}Coal is a stratified rock formed of the more or less altered remains of plants (together with associated mineral matter) which flourished in past ages{hor_ellipsis} The problem of the origin and maturing of coal is complicated by the fact that every coal contains, in addition to carbon, hydrogen and oxygen, variable proportions of nitrogen and sulfur which are combined in unknown ways in the organic molecules...{close_quotes}. The challenge with coal has always been the management of its mineral matter, sulfur and nitrogen contents during use. The carbon content of fuels, including coal, is a more recent concern. With clean coal technologies, there are opportunities for ensuring the sustained use of coal for a very long time. The clean coal technologies of today are already capable of reducing, if not eliminating, harmful emissions. The technologies of the future will allow coal to be burned with greatly reduced emissions, thus eliminating the necessity to treat them after they occur.

Bharucha, N.

1993-12-31T23:59:59.000Z

207

Advanced byproduct recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Fourth quarterly technical progress report  

SciTech Connect (OSTI)

The team of Arthur D. Little, Tufts University and Engelhard Corporation are conducting Phase 1 of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an on-going DOE-sponsored, University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicate that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. The performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams.

NONE

1997-01-01T23:59:59.000Z

208

Coal preparation: The essential clean coal technology  

SciTech Connect (OSTI)

This chapter is a brief introduction to a broad topic which has many highly specialized areas. The aim is to summarize the essential elements of coal preparation and illustrate its important role in facilitating the clean use of coal. Conventional coal preparation is the essential first step in ensuring the economic and environmentally acceptable use of coal. The aim of coal preparation is to produce saleable products of consistent, specified quality which satisfy customer requirements while optimizing the utilization of the coal resource. Coal preparation covers all aspects of preparing coal for the market. It includes size reduction, blending and homogenization and, most importantly, the process of physical beneficiation or washing, which involves separation of undesirable mineral matter from the coal substance itself. Coal preparation can be performed at different levels of sophistication and cost. The degree of coal preparation required is decided by considering the quality of the raw coal, transport costs and, in particular, the coal quality specified by the consumer. However, the cost of coal beneficiation rises rapidly with the complexity of the process and some coal is lost with the waste matter because of process inefficiencies, therefore each situation requires individual study to determine the optimum coal preparation strategy. The necessary expertise is available within APEC countries such as Australia. Coals destined for iron making are almost always highly beneficiated. Physical beneficiation is mostly confined to the higher rank, hard coals, but all other aspects of coal preparation can be applied to subbituminous and lignitic coals to improve their utilization. Also, there are some interesting developments aimed specifically at reducing the water content of lower rank coals.

Cain, D.

1993-12-31T23:59:59.000Z

209

Entrained-flow dry-bottom gasification of high-ash coals in coal-water slurries  

SciTech Connect (OSTI)

It was shown that the effective use of dry ash removal during entrained-flow gasification of coal-water slurries consists in simplification of the ash storage system and utilization of coal ash, a decrease in the coal demand, a reduction in the atmospheric emissions of noxious substances and particulate matter, and abandonment of the discharge of water used for ash slurry. According to the results of gasification of coal-water slurries (5-10 {mu}m) in a pilot oxygen-blow unit at a carbon conversion of >91%, synthesis gas containing 28.5% CO, 32.5% H{sub 2}, 8.2% CO{sub 2}, 1.5% CH{sub 4}, the rest being nitrogen, was obtained. The fly ash in its chemical composition, particle size, and density meets the requirements of the European standard EN 450 as a cement additive for concrete manufacture.

E.G. Gorlov; V.G. Andrienko; K.B. Nefedov; S.V. Lutsenko; B.K. Nefedov [Institute for Fossil Fuels, Moscow (Russian Federation)

2009-04-15T23:59:59.000Z

210

High temperature alkali corrosion of ceramics in coal gas. Quarterly progress report No. 3, March 1, 1992--May 31, 1992  

SciTech Connect (OSTI)

High temperature alkali corrosion has been known to cause premature failure of ceramic components used in advanced high temperature coal combustion systems such as coal gasification and clean-up, coal fired gas turbines, and high efficiency heat engines. The objective of this research is to systematically evaluate the alkali corrosion resistance of the most commonly used structural ceramics including silicon carbide, silicon nitride, cordierite, mullite, alumina, aluminum titanate, zirconia, and fireclay glass. The study consists of identification of the alkali reaction products (phase equilibria) and the kinetics of the alkali reactions as a function of temperature and time.

Pickrell, G.R.; Sun, T.; Brown, J.J.

1992-05-27T23:59:59.000Z

211

ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE  

E-Print Network [OSTI]

sulfur plus 10 to 40% of the coal ash. It also increases theto extract most of the coal ash. Heavy metals are alsotons of scrubber and coal ash sludge per year. By 1980, a

Ferrell, G.C.

2010-01-01T23:59:59.000Z

212

Performance and cost models for the direct sulfur recovery process. Task 1 Topical report, Volume 3  

SciTech Connect (OSTI)

The purpose of this project is to develop performance and cost models of the Direct Sulfur Recovery Process (DSRP). The DSRP is an emerging technology for sulfur recovery from advanced power generation technologies such as Integrated Gasification Combined Cycle (IGCC) systems. In IGCC systems, sulfur present in the coal is captured by gas cleanup technologies to avoid creating emissions of sulfur dioxide to the atmosphere. The sulfur that is separated from the coal gas stream must be collected. Leading options for dealing with the sulfur include byproduct recovery as either sulfur or sulfuric acid. Sulfur is a preferred byproduct, because it is easier to handle and therefore does not depend as strongly upon the location of potential customers as is the case for sulfuric acid. This report describes the need for new sulfur recovery technologies.

Frey, H.C. [North Carolina State Univ., Raleigh, NC (United States); Williams, R.B. [Carneigie Mellon Univ., Pittsburgh, PA (United States)

1995-09-01T23:59:59.000Z

213

A BLOCH DECAY AND ULTRA HIGH SPEED CP/MAS 13C NMR STUDY OF THE ARGONNE PREMIUM COALS AND SELECTED OXIDISED LOW-RANK COALS  

Science Journals Connector (OSTI)

Publisher Summary This chapter presents the results of a Bloch decay and ultrahigh speed cross-polarization/magic angle spinning (CP/MAS) 13C nuclear magnetic resonance (NMR) study of the Argonne premium coals and selected oxidized low-rank coals. A Varian Associates VXR-300 NMR spectrometer operating at 75.4 \\{MHz\\} (13C) equipped with a Doty, Scientific, Inc. high-speed cross-polarization/magic angle probe was employed. Solid-state Bloch decay 13C NMR spectra were determined using 90° carbon pulse, 74 kHz dipolar proton decoupling during acquisition, and a 200-s recycle delay with 13 kHz magic angle spinning. The probe and sample rotor exhibited a background signal amounting to ca. 20% of the total intensity of the coal spectrum, and required careful FID scaling and subtraction of the signal obtained from the empty rotor and caps. CP/MAS spectra were determined at variable contact times from 25 ?S to 25 ms, with 5 s recycle times. The chapter presents a comparison of CP/MAS and Bloch decay results for the Argonne premium coals, a standard humic acid, and for a selection of oxidized coals.

J.C. Linehan; J.A. Franz

1991-01-01T23:59:59.000Z

214

Proximate analysis of coal  

SciTech Connect (OSTI)

This lab experiment illustrates the use of thermogravimetric analysis (TGA) to perform proximate analysis on a series of coal samples of different rank. Peat and coke are also examined. A total of four exercises are described. These are dry exercises as students interpret previously recorded scans. The weight percent moisture, volatile matter, fixed carbon, and ash content are determined for each sample and comparisons are made. Proximate analysis is performed on a coal sample from a local electric utility. From the weight percent sulfur found in the coal (determined by a separate procedure the Eschka method) and the ash content, students calculate the quantity of sulfur dioxide emissions and ash produced annually by a large coal-fired electric power plant.

Donahue, C.J.; Rais, E.A. [University of Michigan, Dearborn, MI (USA)

2009-02-15T23:59:59.000Z

215

High-Fidelity Multi-Phase Radiation Module for Modern Coal Combustion Systems  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Task Task Description Sample calculations LBL-PMC Future Work High-Fidelity Multi-Phase Radiation Module for Modern Coal Combustion Systems Jian Cai 1 Ricardo Marquez 1 Michael F. Modest 2 1 Postdoctoral Research Associate 2 Shaffer and George Professor of Engineering University of California Merced Merced, CA 95343, USA DE-FG26-10FE0003801 May 2012 - Pittsburgh 2/17 Introduction Task Description Sample calculations LBL-PMC Future Work Radiation Challenges in Multi-Phase Reacting Flows Radiative heat transfer in high temperature combustion systems Thermal radiation becomes very important at elevated temperatures Coal and hydrocarbon fuels C n H m → H 2 O, CO 2 , CO, NO x , soot, char, ash CO 2 , H 2 O, soot, char and ash strongly emit and absorb radiative energy (lower temperature levels) Radiative effects are conveniently ignored or treated with very crude models Neglecting

216

Characterization of selected Ohio coals to predict their conversion behavior relative to 104 North American Coals. [Factors correlating with liquefaction behavior  

SciTech Connect (OSTI)

Twenty-six coal samples from Ohio were collected as washed and seam samples, and lithobodies within the seams. Characterization of these samples included determination of % maceral, % anti R/sub max/, LTA, chlorine content and proximate/ultimate and qualitative mineral analyses. These data were compared to data from a similar project by Yarzab, R.F., et al., 1980 completed at Pennsylvania State University using tetralin as the hydrogen donor solvent. The characteristics of these coals were correlated with liquefaction conversion and other data accrued on 104 North American coals by statistical analyses. Utilizing percent carbon, sulfur, volatile matter, reflectance, vitrinite and total reactive macerals, Q-mode cluster analysis demonstrated that Ohio coals are more similar to the coals of the Interior province than to those of the Appalachian province. Linear multiple regression analysis for the 104 North American coals provided a prediction equation for conversion (R = .96). The predicted conversion values for the samples range from 58.8 to 79.6%, with the Lower Kittanning (No. 5) and the Middle Kittanning (No. 6) coal seams showing the highest predicted percent conversion (respectively, 73.4 and 72.2%). The moderately low FSI values for the No. 5 and No. 6 coals (respectively, 2.5 and 3) and their moderately high alkaline earth content (respectively, 0.69 and 0.74%) suggest that these coals possess the best overall properties for conversion. Stepwise regression has indicated that the most important coal characteristics affecting conversion are, in decreasing order of importance: % volatile matter, % vitrinite and % total sulfur. Conversion processes can be expected to produce higher yields with Ohio coals due to the presence of such mineral catalysts as pyrite and kaolinite. It is believed that the presence of these disposable catalysts increases the marketability of Ohio coals.

Whitacre, T. P.; Hunt, T. J.; Kneller, W. A.

1982-02-01T23:59:59.000Z

217

High temperature alkali corrosion of ceramics in coal gas  

SciTech Connect (OSTI)

The high temperature alkali corrosion kinetics of SiC have been systematically investigated from 950 to 1100[degrees]C at 0.63 vol % alkali vapor concentration. The corrosion rate in the presence of alkaliis approximately 10[sup 4] to 10[sup 5] times faster than the oxidation rate of SiC in air. The activation energy associated with the alkali corrosion is 406 kJ/mol, indicating a highly temperature-dependent reaction rate. The rate-controlling step of the overall reaction is likely to be the dissolution of silica in the sodium silicate liquid, based on the oxygen diffusivity data.

Pickrell, G.R.; Sun, T.; Brown, J.J.

1992-02-24T23:59:59.000Z

218

Central Appalachia: Coal industry profile  

SciTech Connect (OSTI)

Central Appalachia, the most complex and diverse coal-producing region in the United States, is also the principal source of very low sulfur coal in the East. This report provides detailed profiles of companies and facilities responsible for about 90% of the area's production, conveying a unique view of the aggregate industry as well as its many parts.

McMahan, R.L.; Kendall, L.K. (Resource Data International, Inc., Boulder, CO (USA))

1991-05-01T23:59:59.000Z

219

High temperature properties and reactivity of coal and coke for ironmaking.  

E-Print Network [OSTI]

??Rapid growth of the steel industry in coming years will be strongly dependent upon coal. Understanding of coal behavior in current or emerging ironmaking processes… (more)

Kim, Byong-Chul

2012-01-01T23:59:59.000Z

220

Annual Energy Outlook with Projections to 2025-Market Trends - Coal  

Gasoline and Diesel Fuel Update (EIA)

Coal Coal Index (click to jump links) Coal Production and Prices Coal Mining Labor Productivity Coal Consumption Coal Production and Prices Emissions Caps Lead to More Use of Low-Sulfur Coal From Western Mines Continued improvements in mine productivity (which have averaged 5.9 percent per year since 1980) are projected to cause falling real minemouth prices throughout the forecast relative to historical levels. Higher electricity demand and lower prices, in turn, are projected to yield increasing coal demand, but the demand is subject to the overall sulfur emissions cap in the Clean Air Act Amendments of 1990, which encourages progressively greater reliance on the lowest sulfur coals (from Wyoming, Montana, Colorado, and Utah). Figure 106. Coal production by region, 1970-2025 (million short tons). Having problems, call our National Energy Information Center at 202-586-8800 for help.

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

High Permeability Ternary Palladium Alloy Membranes with Improved Sulfur and Halide Tolerances  

SciTech Connect (OSTI)

The project team consisting of Southwest Research Institute{reg_sign} (SwRI{reg_sign}), Georgia Institute of Technology (GT), the Colorado School of Mines (CSM), TDA Research, and IdaTech LLC was focused on developing a robust, poison-tolerant, hydrogen selective free standing membrane to produce clean hydrogen. The project completed on schedule and on budget with SwRI, GT, CSM, TDA and IdaTech all operating independently and concurrently. GT has developed a robust platform for performing extensive DFT calculations for H in bulk palladium (Pd), binary alloys, and ternary alloys of Pd. Binary alloys investigated included Pd96M4 where M = Li, Na, Mg, Al, Si, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Y, Zr, Nb, Mo, Tc, Ru, Rh, Ag, Cd, In, Sn, Sb, Te, Hf, Ta, W, Re, Os, Ir, Pt, Au, Tl, Pb, Bi, Ce, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu. They have also performed a series of calculations on Pd{sub 70}Cu{sub 26}Ag{sub 4}, Pd{sub 70}Cu{sub 26}Au{sub 4}, Pd{sub 70}Cu{sub 26}Ni{sub 4}, Pd{sub 70}Cu{sub 26}Pt{sub 4}, and Pd{sub 70}Cu{sub 26}Y{sub 4}. SwRI deposited and released over 160 foils of binary and ternary Pd alloys. There was considerable work on characterizing and improving the durability of the deposited foils using new alloy compositions, post annealing and ion bombardment. The 10 and 25 {micro}m thick films were sent to CSM, TDA and IdaTech for characterization and permeation testing. CSM conducted over 60 pure gas permeation tests with SwRI binary and ternary alloy membranes. To date the PdAu and PdAuPt membranes have exhibited the best performance at temperatures in the range of 423-773 C and their performance correlates well with the predictions from GT. TDA completed testing under the Department of Energy (DOE) WGS conditions on over 16 membranes. Of particular interest are the PdAuPt alloys that exhibited only a 20% drop in flux when sulfur was added to the gas mixture and the flux was completely recovered when the sulfur flow was stopped. IdaTech tested binary and ternary membranes on a simulated flue gas stream and experienced significant difficulty in mounting and testing the sputter deposited membranes. IdaTech was able to successfully test PdAu and PdAuPt membranes and saw similar sulfur tolerance to what TDA found. The Program met all the deliverables on schedule and on budget. Over ten presentations at national and international conferences were made, four papers were published (two in progress) in technical journals, and three students (2 at GT and 1 at CSM) completed their doctorates using results generated during the course of the program. The three major findings of program were; (1) the DFT modeling was verified as a predictive tool for the permeability of Pd based ternary alloys, (2) while magnetron sputtering is useful in precisely fabricating binary and ternary alloys, the mechanical durability of membranes fabricated using this technique are inferior compared to cold rolled membranes and this preparation method is currently not ready for industrial environments, (3) based on both modeling and experimental verification in pure gas and mixed gas environments PdAu and PdAuPt alloys were found to have the combination of the highest permeability and tolerance to sulfur.

K. Coulter

2010-12-31T23:59:59.000Z

222

Short-Term Fates of High Sulfur Inputs in Northern California Vineyard Soils  

SciTech Connect (OSTI)

The widespread application of elemental sulfur (S{sup 0}) to vineyards may have ecosystem effects at multiple scales. We evaluated the short-term fates of applied S{sup 0} in a Napa Valley vineyard; we determined changes in soil sulfur (S) speciation (measured by X-ray absorption near-edge structure (XANES) spectroscopy), soil pH, extractable sulfate (SO{sub 4}{sup 2-}), and total S to evaluate changes in acidity and soil S within the vineyard over time. Surface soil samples were collected immediately prior to and following two applications of S{sup 0} (6.7 kg S{sup 0} ha{sup -1}), with weekly collections in the 2 weeks between applications and following the last application. XANES spectra indicated that the majority of soil S persists in the +6 oxidation state and that S{sup 0} oxidizes within 7 days following application. Soil pH and extractable SO{sub 4}{sup 2-} measurements taken at 30 min after S{sup 0} application revealed generation of acidity and an increase in extractable SO{sub 4}{sup 2-}, but by 12 days after application, soil pH increased to approximately pre-application levels. These data suggest that the major consequence of reactive S applications in vineyards may be the accumulation of soil SO{sub 4}{sup 2-} and organic S during the growing season, which can be mobilized during storm events during the dormant (wet) season. In spatially-extensive winegrowing regions where these applications are made by hundreds of individual farmers each year, it will be important to understand the long-term implications of this perturbation to the regional S cycle.

E Hinckley; S Fendorf; P Matson

2011-12-31T23:59:59.000Z

223

Rationale for continuing R&D in direct coal conversion to produce high quality transportation fuels  

SciTech Connect (OSTI)

Liquid hydrocarbon fuels will continue to play a significant role in the transportation sector in the future of both the world and the United States because of the their convenience, high energy density, and vast existing infrastructure. At present the U.S. consumes about 26% of the world supply of petroleum, but this situation is expected to change because of declining domestic production and increasing competition for imports by developing overseas economies. A scenario and time frame are developed in which declining world resources will generate a shortfall in petroleum supply that can be alleviated in part by utilizing the abundant domestic coal resource base. Continued R&D in coal conversion technology is expected to significantly reduce costs so that synfuels can compete economically at a much earlier date than previously forecast.

Srivastava, R.; McIlvried, H.G. [Burns and Roe Services Co., Pittsburgh, PA (United States); Gray, D.; Klunder, E.B.

1995-12-31T23:59:59.000Z

224

ENGINEERING DEVELOPMENT OF COAL-FIRED HIGH PERFORMANCE POWER SYSTEMS PHASE II AND III  

SciTech Connect (OSTI)

This report presents work carried out under contract DE-AC22-95PC95144 "Engineering Development of Coal-Fired High Performance Systems Phase II and III." The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) that is capable of: à thermal efficiency (HHV) >47%; à NOx, SOx, and particulates <10% NSPS (New Source Performance Standard); à coal providing >65% of heat input; à all solid wastes benign; à cost of electricity <90% of present plants. Phase I, which began in 1992, focused on the analysis of various configurations of indirectly fired cycles and on technical assessments of alternative plant subsystems and components, including performance requirements, developmental status, design options, complexity and reliability, and capital and operating costs. Phase I also included preliminary R&D and the preparation of designs for HIPPS commercial plants approximately 300 MWe in size. This phase, Phase II, involves the development and testing of plant subsystems, refinement and updating of the HIPPS commercial plant design, and the site selection and engineering design of a HIPPS prototype plant. Work reported herein is from: à Task 2.2 HITAF Air Heaters; à Task 6 HIPPS Commercial Plant Design Update.

NONE

1998-09-30T23:59:59.000Z

225

Method of extracting coal from a coal refuse pile  

DOE Patents [OSTI]

A method of extracting coal from a coal refuse pile comprises soaking the coal refuse pile with an aqueous alkali solution and distributing an oxygen-containing gas throughout the coal refuse pile for a time period sufficient to effect oxidation of coal contained in the coal refuse pile. The method further comprises leaching the coal refuse pile with an aqueous alkali solution to solubilize and extract the oxidized coal as alkali salts of humic acids and collecting the resulting solution containing the alkali salts of humic acids. Calcium hydroxide may be added to the solution of alkali salts of humic acid to form precipitated humates useable as a low-ash, low-sulfur solid fuel.

Yavorsky, Paul M. (Monongahela, PA)

1991-01-01T23:59:59.000Z

226

TRP0033 - PCI Coal Combustion Behavior and Residual Coal Char Carryover in the Blast Furnace of 3 American Steel Companies during Pulverized Coal Injection (PCI) at High Rates  

SciTech Connect (OSTI)

Combustion behavior of pulverized coals (PC), gasification and thermal annealing of cokes were investigated under controlled environments. Physical and chemical properties of PCI, coke and carbon residues of blast furnace dust/sludge samples were characterized. The strong influence of carbon structure and minerals on PCI reactivity was demonstrated. A technique to characterize char carryover in off gas emissions was established.

Veena Sahajwalla; Sushil Gupta

2005-04-15T23:59:59.000Z

227

Supercritical thermodynamics of sulfur and nitrogen species. Final technical report, October 1, 1991--September 30, 1994  

SciTech Connect (OSTI)

Significant opportunity exists for the application of supercritical fluid (SCF) technology to coal processing, both for pretreatment of high sulfur coals, as well as liquefaction and treatment of coal liquids. Supercritical fluids are attractive solvents for a variety of coal processing applications because of their unusual solvating and mass transfer properties. Solubility studies have been carried out for a number of model coal and coal-liquid compounds, primarily in pure supercritical fluids. We have extended this database of model coal compound equilibria using modern techniques that have the advantage of being much more rapid than traditional techniques. Cosolvent effects on solubility have also been investigated over a variety of solvent properties. In addition, specific molecular interactions have been investigated through spectroscopic techniques. The resulting data has been used to develop a physical-chemical equation of state (EOS) model of SCF solutions with meaningful parameters. This equation of state model has been used to predict solubility behavior, which will permit the design and tailoring of SCF cosolvent systems for specific coal processing applications.

Eckert, C.A.

1994-12-31T23:59:59.000Z

228

Coal gasification power generation, and product market study. Topical report, March 1, 1995--March 31, 1996  

SciTech Connect (OSTI)

This Western Research Institute (WRI) project was part of a WRI Energy Resource Utilization Program to stimulate pilot-scale improved technologies projects to add value to coal resources in the Rocky Mountain region. The intent of this program is to assess the application potential of emerging technologies to western resources. The focus of this project is on a coal resource near the Wyoming/Colorado border, in Colorado. Energy Fuels Corporation/Kerr Coal Company operates a coal mine in Jackson County, Colorado. The coal produces 10,500 Btu/lb and has very low sulfur and ash contents. Kerr Coal Company is seeking advanced technology for alternate uses for this coal. This project was to have included a significant cost-share from the Kerr Coal Company ownership for a market survey of potential products and technical alternatives to be studied in the Rocky Mountain Region. The Energy Fuels Corporation/Kerr Coal Company and WRI originally proposed this work on a cost reimbursable basis. The total cost of the project was priced at $117,035. The Kerr Coal Company had scheduled at least $60,000.00 to be spent on market research for the project that never developed because of product market changes for the company. WRI and Kerr explored potential markets and new technologies for this resource. The first phase of this project as a preliminary study had studied fuel and nonfuel technical alternatives. Through related projects conducted at WRI, resource utilization was studied to find high-value materials that can be targeted for fuel and nonfuel use and eventually include other low-sulfur coals in the Rocky Mountain region. The six-month project work was spread over about a three-year period to observe, measure, and confirm over time-any trends in technology development that would lead to economic benefits in northern Colorado and southern Wyoming from coal gasification and power generation.

Sheesley, D.; King, S.B.

1998-12-31T23:59:59.000Z

229

Coal upgrading program for Usti nad Labem, Czech Republic: Task 8.3. Topical report, October 1994--August 1995  

SciTech Connect (OSTI)

Coal has been a major energy source in the Czech Republic given its large coal reserves, especially brown coal and lignite (almost 4000 million metric tons) and smaller reserves of hard, mainly bituminous, coal (over 800 million tons). Political changes since 1989 have led to the reassessment of the role of coal in the future economy as increasing environmental regulations affect the use of the high-sulfur and high-ash brown coal and lignite as well as the high-ash hard coal. Already, the production of brown coal has declined from 87 million metric tons per year in 1989 to 67 million metric tons in 1993 and is projected to decrease further to 50 million metric tons per year of brown coal by the year 2000. As a means of effectively utilizing its indigenous coal resources, the Czech Republic is upgrading various technologies, and these are available at different stages of development, demonstration, and commercialization. The purpose of this review is to provide a database of information on applicable technologies that reduce the impact of gaseous (SO{sub 2}, NO{sub x}, volatile organic compounds) and particulate emissions from the combustion of coal in district and residential heating systems.

Young, B.C.; Musich, M.A.

1995-10-01T23:59:59.000Z

230

Coal-fired high performance power generating system. Quarterly progress report, April 1--June 30, 1993  

SciTech Connect (OSTI)

This report covers work carried out under Task 2, Concept Definition and Analysis, Task 3, Preliminary R&D and Task 4, Commercial Generating Plant Design, under Contract AC22-92PC91155, ``Engineering Development of a Coal Fired High Performance Power Generation System`` between DOE Pittsburgh Energy Technology Center and United Technologies Research Center. The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) by the year 2000 that is capable of: >47% thermal efficiency; NO{sub x}, SO{sub x} and Particulates {le}25% NSPS; cost {ge}65% of heat input; all solid wastes benign. In order to achieve these goals our team has outlined a research plan based on an optimized analysis of a 250 MW{sub e} combined cycle system applicable to both frame type and aeroderivative gas turbines. Under the constraints of the cycle analysis we have designed a high temperature advanced furnace (HITAF) which integrates several combustor and air heater designs with appropriate ash management procedures. A survey of currently available high temperature alloys has been completed and some of their high temperature properties are shown for comparison. Several of the most promising candidates will be selected for testing to determine corrosion resistance and high temperature strength. The corrosion resistance testing of candidate refractory coatings is continuing and some of the recent results are presented. This effort will provide important design information that will ultimately establish the operating ranges of the HITAF.

Not Available

1993-11-01T23:59:59.000Z

231

TRW advanced slagging coal combustor utility demonstration  

SciTech Connect (OSTI)

The TRW Advanced Entrained Coal Combustor Demonstration Project consists of retrofitting Orange and Rockland (O R) Utility Corporation's Lovett Plant Unit No. 3 with four (4) slagging combustors which will allow the gas/oil unit to fire 2.5% sulfur coal. The slagging combustor process will provide NO{sub x} and SO{sub x} emissions that meet NSPS and New York State Environmental Standards. The TRW-Utility Demonstration Unit (UDU) is responsible for the implementation of program policies and overall direction of the project. The following projects will be carried out: process and design development of clean coal technology CCT-1 the development and operation of the entrained coal combustor will enable the boiler to burn low and medium sulfur coal while meeting all the Federal/State emission requirements; demonstrate sulfur dioxide emissions control by pulverized limestone injection into the entrained coal combustor system.

Not Available

1990-01-01T23:59:59.000Z

232

Compilation of data on strippable Fort Union coals in the northern Rocky Mountains and Great Plains region: A CD-ROM presentation  

SciTech Connect (OSTI)

The Fort Union Formation and equivalent formations of Paleocene age in the northern Rocky Mountains and Great Plains region contain 14 strippable coals that yielded more than 30 percent of the 1.03 billion short tons produced in the United States in 1996. These thick, low contaminant, compliant coals, which are utilized by electric power plants in 28 States, are being assessed by the US Geological Survey. The minable coals occur in the Powder River Basin in Wyoming and Montana, Hanna, Carbon and Greater Green River Basins in Wyoming, and Williston Basin in North Dakota. Production during the past 25 years of thick, high quality Fort Union and equivalent coal beds and zones in the region increased from 40 to more than 340 million short tons. The Powder River Basin is projected to produce 416 million short tons of coal in 2015. Major production in the Powder River Basin is from the Wyodak-Anderson, Anderson-Dietz, and Rosebud coal deposits. Producing Fort Union coals in the Williston Basin include the Beulah-Zap, Hagel, and Harmon coal deposits. Producing Fort Union coals in the Greater Green River Basin are in five beds of the Deadman coal zone. Coal production in the Hanna Basin is from eight beds in the Ferris and Hanna Formations. Coals in the Powder River Basin and Williston Basin contain much less sulfur and ash than coals produced in other regions in the conterminous US. When sulfur values are compared as pounds of SO{sub 2} per million Btu (as received basis), Powder River Basin and Williston Basin coals have the lowest amounts of any coals in the conterminous US.

Flores, R.M.; Bader, L.R.; Cavaroc, V.V. [Geological Survey, Denver, CO (United States)] [and others

1998-04-01T23:59:59.000Z

233

Central Appalachia: Coal mine productivity and expansion  

SciTech Connect (OSTI)

Coal mine productivity is a key determinant of coal prices and vice versa. This report, focusing on supplies of very low sulfur coal in the eastern United States, presents alternative scenarios of how the price-productivity relationship may evolve in response to growing utility demand. It also documents the next tier of projects where the coal industry is prepared to expand capacity. 19 refs., 14 figs., 6 tabs.

Suboleski, S.C.; Frantz, R.L.; Ramani, R.V.; Rao, G.P. (Pennsylvania State Univ., University Park, PA (United States). Mining Engineering Section); Price, J.P. (Resource Dynamics Corp., Vienna, VA (United States))

1991-09-01T23:59:59.000Z

234

Coal surface control for advanced physical fine coal cleaning technologies  

SciTech Connect (OSTI)

This final report presents the research work carried out on the Coal Surface Control for Advanced Physical Fine Coal Cleaning Technologies project, sponsored by the US Department of Energy, Pittsburgh Energy Technology Center (DOE/PETC). The project was to support the engineering development of the selective agglomeration technology in order to reduce the sulfur content of US coals for controlling SO[sub 2] emissions (i.e., acid rain precursors). The overall effort was a part of the DOE/PETCs Acid Rain Control Initiative (ARCI). The overall objective of the project is to develop techniques for coal surface control prior to the advanced physical fine coal cleaning process of selective agglomeration in order to achieve 85% pyrite sulfur rejection at an energy recovery greater than 85% based on run-of-mine coal. The surface control is meant to encompass surface modification during grinding and laboratory beneficiation testing. The project includes the following tasks: Project planning; methods for analysis of samples; development of standard beneficiation test; grinding studies; modification of particle surface; and exploratory R D and support. The coal samples used in this project include three base coals, Upper Freeport - Indiana County, PA, Pittsburgh NO. 8 - Belmont County, OH, and Illinois No. 6 - Randolph County, IL, and three additional coals, Upper Freeport - Grant County- WV, Kentucky No. 9 Hopkins County, KY, and Wyodak - Campbell County, WY. A total of 149 drums of coal were received.

Morsi, B.I.; Chiang, S.H.; Sharkey, A.; Blachere, J.; Klinzing, G.; Araujo, G.; Cheng, Y.S.; Gray, R.; Streeter, R.; Bi, H.; Campbell, P.; Chiarlli, P.; Ciocco, M.; Hittle, L.; Kim, S.; Kim, Y.; Perez, L.; Venkatadri, R.

1992-01-01T23:59:59.000Z

235

Process for coal liquefaction employing selective coal feed  

DOE Patents [OSTI]

An improved coal liquefaction process is provided whereby coal conversion is improved and yields of pentane soluble liquefaction products are increased. In this process, selected feed coal is pulverized and slurried with a process derived solvent, passed through a preheater and one or more dissolvers in the presence of hydrogen-rich gases at elevated temperatures and pressures, following which solids, including mineral ash and unconverted coal macerals, are separated from the condensed reactor effluent. The selected feed coals comprise washed coals having a substantial amount of mineral matter, preferably from about 25-75%, by weight, based upon run-of-mine coal, removed with at least 1.0% by weight of pyritic sulfur remaining and exhibiting vitrinite reflectance of less than about 0.70%.

Hoover, David S. (New Tripoli, PA); Givens, Edwin N. (Bethlehem, PA)

1983-01-01T23:59:59.000Z

236

Assumptions to the Annual Energy Outlook 1999 - Coal Market Module  

Gasoline and Diesel Fuel Update (EIA)

coal.gif (4423 bytes) coal.gif (4423 bytes) The NEMS Coal Market Module (CMM) provides forecasts of U.S. coal production, consumption, exports, distribution, and prices. The CMM comprises three functional areas: coal production, coal distribution, and coal exports. A detailed description of the CMM is provided in the EIA publication, Model Documentation: Coal Market Module of the National Energy Modeling System, DOE/EIA-MO60. Key Assumptions Coal Production The coal production submodule of the CMM generates a different set of supply curves for the CMM for each year of the forecast. Separate supply curves are developed for each of 11 supply regions, and 12 coal types (unique combinations of thermal grade, sulfur content, and mine type). The modeling approach used to construct regional coal supply curves addresses the relationship between the minemouth price of coal and corresponding levels of coal production, labor productivity, and the cost of factor inputs (mining equipment, mine labor, and fuel requirements).

237

Moist caustic leaching of coal  

DOE Patents [OSTI]

A process for reducing the sulfur and ash content of coal. Particulate coal is introduced into a closed heated reaction chamber having an inert atmosphere to which is added 50 mole percent NaOH and 50 mole percent KOH moist caustic having a water content in the range of from about 15% by weight to about 35% by weight and in a caustic to coal weight ratio of about 5 to 1. The coal and moist caustic are kept at a temperature of about 300.degree. C. Then, water is added to the coal and caustic mixture to form an aqueous slurry, which is washed with water to remove caustic from the coal and to produce an aqueous caustic solution. Water is evaporated from the aqueous caustic solution until the water is in the range of from about 15% by weight to about 35% by weight and is reintroduced to the closed reaction chamber. Sufficient acid is added to the washed coal slurry to neutralize any remaining caustic present on the coal, which is thereafter dried to produce desulfurized coal having not less than about 90% by weight of the sulfur present in the coal feed removed and having an ash content of less than about 2% by weight.

Nowak, Michael A. (Elizabeth, PA)

1994-01-01T23:59:59.000Z

238

Effects of high pressure-dependent leakoff and high process-zone stress in coal-stimulation treatments  

SciTech Connect (OSTI)

Hydraulic fracturing in coals has been studied extensively over the last two decades; however, there are factors that were often ignored or incorrectly diagnosed, resulting in screenouts. Assuming that a majority of the perforations are open and there are no problems with the stimulation fluids, screenouts during coal hydraulic-fracture treatments can be attributed to either high pressure-dependent leakoff (PDL), high process-zone stress (PZS) or in some cases both. The objective of this work is to discuss, help identify, and present solutions to address these reservoir-related issues such that screenouts can be avoided in optimized refracture treatments and new well stimulations. The tools for identifying these reservoir-related parameters include a diagnostic fracture-injection test (DFIT) and a grid-oriented fully functional 3D fracture simulator with shear decoupling. An example for each respective case is presented in this paper. In the first example, in which high PZS was considered to be the dominant reason for screenout or pressure out, the well was restimulated successfully by implementing the solutions presented in this paper. In the second example, in which high PDL was considered to be the main reason for screenout, there were several wells in the same project area that exhibited the same behavior resulting in screenouts. After implementing the solutions presented in this paper to address high PDL, all new wells were stimulated successfully without any issues.

Ramurthy, M.; Lyons, B.; Hendrickson, R.B.; Barree, R.D.; Magill, D.R. [Halliburton, Denver, CO (United States)

2009-08-15T23:59:59.000Z

239

The National Energy Modeling System: An Overview 2000 - Coal Market Module  

Gasoline and Diesel Fuel Update (EIA)

coal market module (CMM) represents the mining, transportation, and pricing of coal, subject to end-use demand. Coal supplies are differentiated by heat and sulfur content. CMM also determines the minimum cost pattern of coal supply to meet exogenously defined U.S. coal export demands as a part of the world coal market. Coal supply is projected on a cost-minimizing basis, constrained by existing contracts. Twelve different coal types are differentiated with respect to thermal grade, sulfur content, and underground or surface mining. The domestic production and distribution of coal is forecast for 13 demand regions and 11 supply regions (Figures 19 and 20). coal market module (CMM) represents the mining, transportation, and pricing of coal, subject to end-use demand. Coal supplies are differentiated by heat and sulfur content. CMM also determines the minimum cost pattern of coal supply to meet exogenously defined U.S. coal export demands as a part of the world coal market. Coal supply is projected on a cost-minimizing basis, constrained by existing contracts. Twelve different coal types are differentiated with respect to thermal grade, sulfur content, and underground or surface mining. The domestic production and distribution of coal is forecast for 13 demand regions and 11 supply regions (Figures 19 and 20). Figure 19. Coal Market Module Demand Regions Figure 20. Coal Market Module Supply Regions

240

Measurement and modeling of advanced coal conversion processes, Volume I, Part 2. Final report, September 1986--September 1993  

SciTech Connect (OSTI)

This report describes work pertaining to the development of models for coal gasification and combustion processes. This volume, volume 1, part 2, contains research progress in the areas of large particle oxidation at high temperatures, large particle, thick-bed submodels, sulfur oxide/nitrogen oxides submodels, and comprehensive model development and evaluation.

Solomon, P.R.; Serio, M.A.; Hamblen, D.G. [and others

1995-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Two stage sorption of sulfur compounds  

DOE Patents [OSTI]

A two stage method for reducing the sulfur content of exhaust gases is disclosed. Alkali- or alkaline-earth-based sorbent is totally or partially vaporized and introduced into a sulfur-containing gas stream. The activated sorbent can be introduced in the reaction zone or the exhaust gases of a combustor or a gasifier. High efficiencies of sulfur removal can be achieved.

Moore, William E. (Manassas, VA)

1992-01-01T23:59:59.000Z

242

LOW-COST, HIGH-PERFORMANCE MATERIALS USING ILLINOIS COAL COMBUSTION BY-PRODUCTS  

E-Print Network [OSTI]

conventional and clean coal technologies. This project was primarily directed toward developing concrete, mineralogical, and microstructural properties. A clean coal ash is defined as the ash derived from SO2 control technologies. Based on these properties, two sources of both conventional and clean coal ashes were selected

Wisconsin-Milwaukee, University of

243

The National Energy Modeling System: An Overview 1998 - Coal Market Module  

Gasoline and Diesel Fuel Update (EIA)

COAL MARKET MODULE COAL MARKET MODULE blueball.gif (205 bytes) Coal Production Submodule blueball.gif (205 bytes) Coal Distribution Submodule blueball.gif (205 bytes) Coal Export Component The coal market module (CMM) represents the mining, transportation, and pricing of coal, subject to end-use demand. Coal supplies are differentiated by heat and sulfur content. The CMM also determines the minimum cost pattern of coal supply to meet exogenously defined U.S. coal export demands as a part of the world coal market. Coal supply is projected on a cost-minimizing basis, constrained by existing contracts. Twelve different coal types are differentiated with respect to thermal grade, sulfur content, and underground or surface mining. The domestic production and distribution of coal is forecast for 13 demand regions and 11 supply

244

Molten iron oxysulfide as a superior sulfur sorbent. Final report, [September 1989--1993  

SciTech Connect (OSTI)

The studies had as original objective the analysis of conditions for using liquid iron oxysulfide as a desulfuring agent during coal gasification. Ancillary was a comparison of iron oxysulfide with lime as sorbents under conditions where lime reacts with S-bearing gases to form Ca sulfate or sulfide. Primary thrust is to determine the thermodynamic requirements for desulfurization by iron additions (e.g., taconite concentrate) during combustion in gasifiers operating at high equivalence ratios. Thermodynamic analysis of lime-oxygen-sulfur system shows why lime is injected into burners under oxidizing conditions; reducing conditions forms CaS, requiring its removal, otherwise oxidation and release of S would occur. Iron as the oxysulfide liquid has a range of stability and can be used as a desulfurizing agent, if the burner/gasifier operates in a sufficiently reducing regime (high equivalence ratio); this operating range is given and is calculable for a coal composition, temperature, stoichiometry. High moisture or hydrogen contents of the coal yield a poorer degree of desulfurization. Kinetic tests on individual iron oxide particles on substrates or Pt cups with a TGA apparatus fail to predict reaction rates within a burner. Preliminary tests on the Dynamic Containment Burner with acetylene give some promise that this system can produce the proper conditions of coal gasification for use of added iron as a sulfur sorbent.

Hepworth, M.T.

1993-03-31T23:59:59.000Z

245

Crystallization of Coal Ash Slags at High Temperatures and Effects on the Viscosity  

Science Journals Connector (OSTI)

The coal samples were ashed in a muffle furnace at 815 °C, according to the Chinese Standard GB/T1574-2007. ... Shenfu and Beisu coals are enriched in glass modifying oxides (CaO + Fe2O3 + MgO > 30%), while the contents of Al2O3 in Baodian coal ash is higher than 30%; therefore, they exhibit the crystalline slag behavior. ... compn. of coals and coal ashes from a wide variety of deposits (41) were studied by a melting test, x-ray diffractometry, light microscopy, differential-thermal, thermogravimetric and chem. ...

Haiping Yuan; Qinfeng Liang; Xin Gong

2012-04-16T23:59:59.000Z

246

Selective catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly technical progress report No. 6, October 1993--December 1993  

SciTech Connect (OSTI)

Elemental sulfur recovery from SO{sub 2}-containing gas stream is highly attractive as it produces a salable product and no waste to dispose of. However, commercially available schemes are complex and involve multi-stage reactors, such as, most notably in the Resox (reduction of SO{sub 2} with coke) and Claus plant (reaction of SO{sub 2} with H{sub 2}S over catalyst). This project will investigate a cerium oxide catalyst for the single stage selective reduction of SO{sub 2} to elemental sulfur by a reductant, such as carbon monoxide. Cerium oxide has been identified in recent work at MIT as a superior catalyst for SO{sub 2} reduction by CO to elemental sulfur because its high activity and high selectivity to sulfur over COS over a wide temperature range(400-650 {degrees}C). The detailed kinetic and parametric studies of SO{sub 2} reduction planned in this work over various CeO{sub 2}-formulations will provide the necessary basis for development of a very simplified process, namely that of a single-stage elemental sulfur recovery scheme from variable concentration gas streams. The potential cost- and energy-efficiency benefits from this approach can not be overstated. A first apparent application is treatment of a regenerator off-gases in power plants using regenerative flue gas desulfurization. Such a simple catalytic converter may offer the long-sought {open_quotes}Claus-alternative{close_quotes} for coal-fired power plant applications.

Liu, W.; Flytzani-Stephanopoulos, M.; Sarofim, A.F.

1996-01-01T23:59:59.000Z

247

Coal Science: Basic Research Opportunities  

Science Journals Connector (OSTI)

...carbon is arranged in coal becomes real. What...NMR experiments at high temperatures. This...of characterizing high-boiling coal "liquids" which...reactions. Coal mineral matter. Most U.S. coals...burned is called ash. Techniques are...

Martin L. Gorbaty; Franklin J. Wright; Richard K. Lyon; Robert B. Long; Richard H. Schlosberg; Zeinab Baset; Ronald Liotta; Bernard G. Silbernagel; Dan R. Neskora

1979-11-30T23:59:59.000Z

248

Fluidized bed combustion of a high-sulphur eastern Canadian coal  

SciTech Connect (OSTI)

A high-sulphur bituminous coal from Nova Scotia has been tested in a pilot scale FBC (Fluidized Bed Combustor) and an industrial FBC boiler. A comprehensive pilot plant program involved 28 tests at a nominal bed temperature of 850/sup 0/C (1560/sup 0/F) and fluidizing velocities of 1.2, 2.1 and 3 m/s (4,7 and 10 ft/sec) with and without fly ash recycle. Two different sizes of limestone were used for sulphur sorption. The industrial boiler trials involved two tests at 65% and 100% MCR (Maximum Continuous Rating). Pilot scaling results indicate that high combustion efficiencies are achievable. Sulphur capture of over 80% (meeting the SO/sub 2/ emission standard of 705 ng/J or 1.64 lbs/MBTU input) is possible with a Ca/S molar ratio <3 with fly ash recycle.

Desai, D.L.; Anthony, E.J.; Friedrich, F.D.; Razbin, V.V.

1986-01-01T23:59:59.000Z

249

Engineering development of coal-fired high performance power systems phase 2 and 3  

SciTech Connect (OSTI)

The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) that is capable of: thermal efficiency (HHV) {ge} 47%; NOx, SOx, and particulates {le}10% NSPS (New Source Performance Standard); coal providing {ge} 65% of heat input; all solid wastes benign; and cost of electricity {le} 90% of present plants. Phase 1, which began in 1992, focused on the analysis of various configurations of indirectly fired cycles and on technical assessments of alternative plant subsystems and components, including performance requirements, developmental status, design options, complexity and reliability, and capital and operating costs. Phase 1 also included preliminary R and D and the preparation of designs for HIPPS commercial plants approximately 300 MWe in size. This phase, Phase 2, involves the development and testing of plant subsystems, refinement and updating of the HIPPS commercial plant design, and the site selection and engineering design of a HIPPS prototype plant. Work reported herein is from: Task 2.2 HITAF Air Heaters; and Task 2.4 Duct Heater and Gas Turbine Integration.

Unknown

1999-08-01T23:59:59.000Z

250

Coal Gasification  

Broader source: Energy.gov [DOE]

DOE's Office of Fossil Energy supports activities to advance coal-to-hydrogen technologies, specifically via the process of coal gasification with sequestration. DOE anticipates that coal...

251

Coal Gasification Systems Solicitations  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Low Cost Coal Conversion to High Hydrogen Syngas; FE0023577 Alstom's Limestone Chemical Looping Gasification Process for High Hydrogen Syngas Generation; FE0023497 OTM-Enhanced...

252

Novel bimetallic dispersed catalysts for temperature-programmed coal liquefaction. Final report  

SciTech Connect (OSTI)

Development of new catalysts is a promising approach to more efficient coal liquefaction. It has been recognized that dispersed catalysts are superior to supported catalysts for primary liquefaction of coals, because the control of initial coal dissolution or depolymerization requires intimate contact between the catalyst and coal. This research is a fundamental and exploratory study on catalytic coal liquefaction, with the emphasis on exploring novel bimetallic dispersed catalysts for coal liquefaction and the effectiveness of temperature-programmed liquefaction using dispersed catalysts. The primary objective of this research was to explore novel bimetallic dispersed catalysts from organometallic molecular precursors, that could be used in low concentrations but exhibit relatively high activity for efficient hydroliquefaction of coals under temperature-programmed conditions. We have synthesized and tested various catalyst precursors in liquefaction of subbituminous and bituminous coals and in model compound studies to examine how do the composition and structure of the catalytic precursors affect their effectiveness for coal liquefaction under different reaction conditions, and how do these factors affect their catalytic functions for hydrogenation of polyaromatic hydrocarbons, for cleavage of C-C bonds in polycyclic systems such as 4-(1-naphthylmethyl)bibenzyl, for hydrogenolysis of C-O bond such as that in dinaphthylether, for hydrodeoxygenation of phenolic compounds and other oxygen-containing compounds such as xanthene, and for hydrodesulfurization of polycyclic sulfur compounds such as dibenzothiophene. The novel bimetallic and monometallic precursors synthesized and tested in this project include various Mo- and Fe-based compounds.

Chunshan Song; Schobert, H.H.; Parfitt, D.P. [and others

1997-11-01T23:59:59.000Z

253

Coal combustion under conditions of blast furnace injection; [Quarterly] technical report, September 1--November 30, 1993  

SciTech Connect (OSTI)

A potentially new use for Illinois coal is its use as a fuel injected into a blast furnace to produce molten iron as the first step in steel production. Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of coal during the blast furnace injection process and to delineate the optimum properties of the feed coal. This investigation is significant to the use of Illinois coal in that the limited research to date suggests that coals of low fluidity and moderate to high sulfur and chlorine contents are suitable feedstocks for blast furnace injection. This study is unique in that it will be the first North American effort to directly determine the nature of the combustion of coal injected into a blast furnace. This proposal is a follow-up to one funded for the 1992--1993 period. It is intended to complete the study already underway with the Armco Inc. steel company and to initiate a new cooperative study along somewhat similar lines with the Inland Steel Company. The results of this study will lead to the development of a testing and evaluation protocol that will give a unique and much needed understanding of the behavior of coal in the injection process and prove the potential of Illinois coals f or such use.

Crelling, J.C.

1993-12-31T23:59:59.000Z

254

Advanced byproduct recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly report, April 1--June 30, 1997  

SciTech Connect (OSTI)

The team of Arthur D. Little, Tufts University and Engelhard Corporation are conducting Phase 1 of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an on-going DOE-sponsored, University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicate that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. The performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams. The principal objective of the Phase 1 program is to identify and evaluate the performance of a catalyst which is robust and flexible with regard to choice of reducing gas. In order to achieve this goal, the authors have planned a structured program including: Market/process/cost/evaluation; Lab-scale catalyst preparation/optimization studies; Lab-scale, bulk/supported catalyst kinetic studies; Bench-scale catalyst/process studies; and Utility review. Progress is reported from all three organizations.

NONE

1997-12-31T23:59:59.000Z

255

High-resolution 2D surface seismic reflection survey to detect abandoned old coal mine works to improve mine safety  

Science Journals Connector (OSTI)

...coal seismic studies in the Appalachia Coal Basin, the calculated average...seismic method in the U.K. coal mining industrya by Fairbairn et al...interpretation workstation for the coal industrya by Gochioco (Mining Engineering, 1991). a Modeling...

Lawrence M. Gochioco; Tim Miller; Fred Ruev; Jr.

256

Sulfur: its clinical and toxicologic aspects  

Science Journals Connector (OSTI)

Although there is no known dietary requirement for inorganic sulfur, it is an essential element for all animal species in as much as they all require the sulfur-containing amino acid methionine. There are three predominate forms of organic sulfur in animals and humans: 1) the thiomethyl of methionine residues in protein; 2) the sulfhydryl disulfides of protein; and 3) the compounds containing ester or amide bound sulfates of glycosaminoglycans, steroids, and many xenobiotic metabolites. Thus, sulfur becomes an important constituent of amino acids, proteins, enzymes, vitamins and other biomolecules. Unlike mammalian species, plants can use inorganic sulfur and synthesize methionine from which are synthesized all the other important sulfur compounds. Hence, sulfur deficiency occurs mainly when plants are grown in sulfur-depleted soils and when humans and animals consume low-protein diets. In recent times, however, the increasing prevalence of refining petroleum and smelting sulfur compounds of metallic minerals into free metals are having a large impact on the balance of sulfur in the environment. Sulfur toxicity is associated mainly with high levels of the element and its toxic volatile substances in the environment. Sulfur dioxide (SO2), a major air pollutant, may adversely affect animal and human health by causing bronchitis, bronchoconstriction, and increased pulmonary resistance.

Lioudmila A Komarnisky; Robert J Christopherson; Tapan K Basu

2003-01-01T23:59:59.000Z

257

ENGINEERING DEVELOPMENT OF COAL-FIRED HIGH-PERFORMANCE POWER SYSTEMS  

SciTech Connect (OSTI)

A High Performance Power System (HIPPS) is being developed. This system is a coal-fired, combined cycle plant with indirect heating of gas turbine air. Foster Wheeler Development Corporation and a team consisting of Foster Wheeler Energy Corporation, Bechtel Corporation, University of Tennessee Space Institute and Westinghouse Electric Corporation are developing this system. In Phase 1 of the project, a conceptual design of a commercial plant was developed. Technical and economic analyses indicated that the plant would meet the goals of the project which include a 47 percent efficiency (HHV) and a 10 percent lower cost of electricity than an equivalent size PC plant. The concept uses a pyrolysis process to convert coal into fuel gas and char. The char is fired in a High Temperature Advanced Furnace (HITAF). The HITAF is a pulverized fuel-fired boiler/air heater where steam is generated and gas turbine air is indirectly heated. The fuel gas generated in the pyrolyzer is then used to heat the gas turbine air further before it enters the gas turbine. The project is currently in Phase 2 which includes engineering analysis, laboratory testing and pilot plant testing. Research and development is being done on the HIPPS systems that are not commercial or being developed on other projects. Pilot plant testing of the pyrolyzer subsystem and the char combustion subsystem are being done separately, and after each experimental program has been completed, a larger scale pyrolyzer will be tested at the Power Systems Development Facility (PSDF) in Wilsonville, AL. The facility is equipped with a gas turbine and a topping combustor, and as such, will provide an opportunity to evaluate integrated pyrolyzer and turbine operation. This report addresses the areas of technical progress for this quarter. A general arrangement drawing of the char transfer system was forwarded to SCS for their review. Structural steel drawings were used to generate a three-dimensional model of the char transfer system including all pressure vessels and major piping components. Experimental testing at the Combustion and Environmental Test Facility continued during this quarter. Performance of the char burner, as benchmarked by flame stability and low NOx, has been exceptional. The burner was operated successfully both without natural gas and supplemental pulverized coal.

Unknown

1999-02-01T23:59:59.000Z

258

Sorbents for High Temperature Removal of Arsenic from Coal-Derived Synthesis Gas  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Gokhan O. Alptekin, PhD Robert Copeland, PhD Gokhan O. Alptekin, PhD Robert Copeland, PhD (Primary Contact) TDA Research, Inc TDA Research, Inc 12345 W. 52 nd Avenue 12345 W. 52 nd Avenue Wheat Ridge, CO 80033 Wheat Ridge, CO 80033 Email: copeland@tda.com Email: galptekin@tda.com Tel: (303) 940-2323 Tel: (303) 940-2349 Fax: (303) 422-7763 Fax: (303) 422-7763 Margarita Dubovik Yevgenia Gershanovich TDA Research, Inc TDA Research, Inc 12345 W. 52 nd Avenue 12345 W. 52 nd Avenue Wheat Ridge, CO 80033 Wheat Ridge, CO 80033 Email: dubovik@tda.com Email: ygershan@tda.com Tel: (303) 940-2316 Tel: (303) 940-2346 Fax: (303) 422-7763 Fax: (303) 422-7763 Sorbents for High Temperature Removal of Arsenic from Coal-Derived Synthesis Gas

259

Refractory oxides for high?temperature coal?fired MHD air heaters  

Science Journals Connector (OSTI)

In a coal?burning MHD (Magnetohydrodynamic) power plant the use of a regenerative air heater is one option for producing the required high plasma temperatures. However thermal mechanical and chemical stresses which the MHD environment places on materials are enormous and candidate materials must be carefully tested. We report on the results of such testing for a variety of materials studied in heater test facilities at both FluiDyne Engineering Corporation and at Montana State University. We describe the experimental program and test facilities for MHD heater development the rationale for the choice of materials and their performance (success or failure) under various envirnoments (slagging and nonslagging). Future materials needs are discussed in light of the observed effects.

Richard J. Pollina; Ronald R. Smyth

1981-01-01T23:59:59.000Z

260

Large Field Erected and Packaged High Temperature Water (HTW) Generators for Coal Firing  

E-Print Network [OSTI]

and closer temperature control. The heat storage capacity of water per cubic foot is considerably greater than steam at equivalent saturation pressures, as shown in Table No. II (below). This inherent reserve or "fly wheel" effect permits closer... furnace and convection section. Coal ash fouling characteristics will have a bearing on the convection section tube spacing. Low grade coals should be reviewed for their slagging and fouling characteristics. For example, lignite and low grade coals...

Boushell, C. C.

1980-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Hydrogen production by high-temperature steam gasification of biomass and coal  

SciTech Connect (OSTI)

High-temperature steam gasification of paper, yellow pine woodchips, and Pittsburgh bituminous coal was investigated in a batch-type flow reactor at temperatures in the range of 700 to 1,200{sup o}C at two different ratios of steam to feedstock molar ratios. Hydrogen yield of 54.7% for paper, 60.2% for woodchips, and 57.8% for coal was achieved on a dry basis, with a steam flow rate of 6.3 g/min at steam temperature of 1,200{sup o}C. Yield of both the hydrogen and carbon monoxide increased while carbon dioxide and methane decreased with the increase in gasification temperature. A 10-fold reduction in tar residue was obtained at high-temperature steam gasification, compared to low temperatures. Steam and gasification temperature affects the composition of the syngas produced. Higher steam-to-feedstock molar ratio had negligible effect on the amount of hydrogen produced in the syngas in the fixed-batch type of reactor. Gasification temperature can be used to control the amounts of hydrogen or methane produced from the gasification process. This also provides mean to control the ratio of hydrogen to CO in the syngas, which can then be processed to produce liquid hydrocarbon fuel since the liquid fuel production requires an optimum ratio between hydrogen and CO. The syngas produced can be further processed to produce pure hydrogen. Biomass fuels are good source of renewable fuels to produce hydrogen or liquid fuels using controlled steam gasification.

Kriengsak, S.N.; Buczynski, R.; Gmurczyk, J.; Gupta, A.K. [University of Maryland, College Park, MD (United States). Dept. of Mechanical Engineering

2009-04-15T23:59:59.000Z

262

Engineering development of coal-fired high-performance power systems. Technical report, July - September 1996  

SciTech Connect (OSTI)

A High Performance Power System (HIPPS) is being developed. This system is a coal-fired, combined cycle plant with indirect heating of gas turbine air. Foster Wheeler Development Corporation and a team consisting of Foster Wheeler Energy Corporation, AlliedSignal Aerospace Equipment Systems, Bechtel Corporation, University of Tennessee Space Institute and Westinghouse Electric Corporation are developing this system. In Phase I of the project, a conceptual design of a commercial plant was developed. Technical and economic analyses indicated that the plant would meet the goals of the project which include a 47 percent efficiency (HHV) and a 10 percent lower cost of electricity than an equivalent size PC plant. The concept uses a pyrolyzation process to convert coal into fuel gas and char. The char is fired in a High Temperature Advanced Furnace (HITAF). It is a pulverized fuel-fired boiler/airheater where steam and gas turbine air are indirectly heated. The fuel gas generated in the pyrolyzer is then used to heat the gas turbine air further before it enters the gas turbine. The project is currently in Phase 2 which includes engineering analysis, laboratory testing and pilot plant testing. Research and development is being done on the HIPPS systems that are not commercial or being developed on other projects. Pilot plant testing of the pyrolyzer subsystem and the char combustion subsystem are being done separately, and then a pilot plant with integrated pyrolyzer and char combustion systems will be tested. In this report, progress in the pyrolyzer pilot plant preparation is reported. The results of extensive laboratory and bench scale testing of representative char are also reported. Preliminary results of combustion modeling of the char combustion system are included. There are also discussions of the auxiliary systems that are planned for the char combustion system pilot plant and the status of the integrated system pilot plant.

NONE

1996-11-01T23:59:59.000Z

263

Engineering Development of Coal-Fired High-Performance Power Systems  

SciTech Connect (OSTI)

A High Performance Power System (HIPPS) is being developed. This system is a coal-fired, combined cycle plant with indirect heating of gas turbine air. Foster Wheeler Development Corporation and a team consisting of Foster Wheeler Energy Corporation, Bechtel Corporation, University of Tennessee Space Institute and Westinghouse Electric Corporation are developing this system. In Phase 1 of the project, a conceptual design of a commercial plant was developed. Technical and economic analyses indicated that the plant would meet the goals of the project which include a 47 percent efficiency (HHV) and a 10 percent lower cost of electricity than an equivalent size PC plant. The concept uses a pyrolysis process to convert coal into fuel gas and char. The char is fired in a High Temperature Advanced Furnace (HITAF). The HITAF is a pulverized fuel-fired boiler/air heater where steam is generated and gas turbine air is indirectly heated. The fuel gas generated in the pyrolyzer is then used to heat the gas turbine air further before it enters the gas turbine. The project is currently in Phase 2 which includes engineering analysis, laboratory testing and pilot plant testing. Research and development is being done on the HIPPS systems that are not commercial or being developed on other projects. Pilot plant testing of the pyrolyzer subsystem and the char combustion subsystem are being done separately. This report addresses the areas of technical progress for this quarter. The detail of syngas cooler design is given in this report. The final construction work of the CFB pyrolyzer pilot plant has started during this quarter. No experimental testing was performed during this quarter. The proposed test matrix for the future CFB pyrolyzer tests is given in this report. Besides testing various fuels, bed temperature will be the primary test parameter.

York Tsuo

2000-12-31T23:59:59.000Z

264

NETL: Coal and Power Systems  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Systems Systems Technologies Coal and Power Systems Advancing our Nation's Portfolio of Coal RD&D Technologies - Rotating Images Advancing our Nation's Portfolio of Coal RD&D Technologies - Read More! Focus of NETL RD&D RD&D efforts in coal and power systems fall into three categories: Technologies that enable existing coal power plants to cost-effectively meet environmental requirements. NETL and its research partners are developing environmental control technologies for retrofitting existing power plants, with application to new plants as well. Key areas of research include cost-effective control of mercury, nitrogen oxides, sulfur dioxide, and fine particulate emissions; beneficial uses for coal utilization byproducts; and innovations to minimize the impact of

265

Permeabilities of coal-biomass mixtures for high pressure gasifier feeds.  

E-Print Network [OSTI]

??Complete measurements of permeability on coal-biomass mixtures as a potential feedstock to gasifiers to reduce net carbon emissions were performed. Permeability is measured under anticipated… (more)

Belvalkar, Rohan

2012-01-01T23:59:59.000Z

266

High ash non-coking coal preparation by tribo-electrostatic dry process.  

E-Print Network [OSTI]

??Coal is the single largest fossil fuel used world-wide and accounts for more than 60% of the total commercial energy consumed. Between 60 to 80%… (more)

Ranjan Dwari

2008-01-01T23:59:59.000Z

267

Effects of hydrogen donor additives on the coking properties of high-temperature coal extracts.  

E-Print Network [OSTI]

?? Refcoal is a carbon precursor obtained by alkali-mediated extraction of coal with aprotic solvents such as DMF. Refcoal can be converted into a graphitic… (more)

Makgato, Matlou Hector

2009-01-01T23:59:59.000Z

268

Coal-fueled high-speed diesel engine development. Annual technical progress report, October 1990--September 1991  

SciTech Connect (OSTI)

The objectives of this program are to study combustion feasibility by running Series 149 engine tests at high speeds with a fuel injection and combustion system designed for coal-water-slurry (CWS). The following criteria will be used to judge feasibility: (1) engine operation for sustained periods over the load range at speeds from 600 to 1900 rpm. The 149 engine for mine-haul trucks has a rated speed of 1900 rpm; (2) reasonable fuel economy and coal burnout rate; (3) reasonable cost of the engine design concept and CWS fuel compared to future oil prices.

Not Available

1991-11-01T23:59:59.000Z

269

Studies of the mechanism of Coal Hydrogenation by Electron Spin Resonance. Quarterly technical progress report, March 1-May 31, 1980. [For high-temperature, high pressure measurements  

SciTech Connect (OSTI)

This is the first quarterly report on the program Studies of Coal Hydrogenation by Electron Spin Resonance. This quarter has been devoted to constructing apparatus for high temperature-high pressure electron paramagnetic resonance (EPR) measurements, characterizing the performance of the microwave cavity, and carrying out preliminary room temperature studies on coals and coal products. At the start of this program, there were no microwave cavities available to study high pressure-high temperature reactions. A system was constructed which can be used to study coal hydrogenation, and satisfies the conditions described in the report. This cavity was constructed using funding from Rockwell International, and will be used on this program. Because of the dependence of the work to be done with this device for this program, the construction is described in detail. This report, therefore, considers the design philosophy, construction of the device, a preliminary discussion of its performance, and application of the cavity for room temperature studies on several varieties of coal.

Goldberg, Ira B.

1980-07-01T23:59:59.000Z

270

(Fluidized bed combustion of high-ash Indian coals): Foreign trip report, January 5, 1988--March 16, 1988  

SciTech Connect (OSTI)

The foreign research assignment at BHEL, Trichy, was undertaken to participate in the ongoing USAID/BHEL joint program in fluidized bed combustion (FBC). As part of this program, an experimental FBC research test facility has been designed, erected and commissioned at BHEL, Trichy, to conduct experiments on the combustion of high-ash Indian coals and coal washery rejects. The data will be used to optimize the design and to select the operational parameters for large scale industrial and utility FBC boilers. ORNL has been providing technical assistance to BHEL since the initiation of the project in November 1983. The US team visited at 10 MW(e) FBC boiler fired with coal washery rejects at the Tata Iron and Steel Company (supplied by BHEL). The tour was very informative and gave the US team a good first-hand perspective of the Indian experience and concerns with FBC technology.

Krishnan, R.P.; Daw, C.S.

1988-03-01T23:59:59.000Z

271

coking coal  

Science Journals Connector (OSTI)

coking coal [A caking coal suitable for the production of coke for metallurgical use] ? Kokskohle f, verkokbare Kohle

2014-08-01T23:59:59.000Z

272

Low-grade coals: a review of some prospective upgrading technologies  

SciTech Connect (OSTI)

There is a growing need of using low-grade coals because of higher quest for power generation. In the present carbon-constrained environment, there is a need of upgrading these coals in terms of moisture, ash, and/or other trace elements. The current paper reviews technologies used mainly categorized as drying for reducing moisture and cleaning the coal for reducing mineral content of coal and related harmful constituents, such as sulfur and mercury. The earliest upgrading of high-moisture lignite involved drying and manufacturing of briquettes. Drying technologies consist of both evaporative and non-evaporative (dewatering) types. The conventional coal cleaning used density separation in water medium. However, with water being a very important resource, conservation of water is pushing toward the development of dry cleaning of coal. There are also highly advanced coal-cleaning technologies that produce ultra-clean coals and produce coals with less than 0.1% of ash. The paper discusses some of the promising upgrading technologies aimed at improving these coals in terms of their moisture, ash, and other pollutant components. It also attempts to present the current status of the technologies in terms of development toward commercialization and highlights on problems encountered. It is obvious that still the upgrading goal has not been realized adequately. It can therefore be concluded that, because reserves for low-grade coals are quite plentiful, it is important to intensify efforts that will make these coals usable in an acceptable manner in terms of energy efficiency and environmental protection. 68 refs., 7 figs.

Hassan Katalambula; Rajender Gupta [University of Alberta, Edmonton, AB (Canada). Department of Chemical and Materials Engineering

2009-07-15T23:59:59.000Z

273

SULFUR POLYMER ENCAPSULATION.  

SciTech Connect (OSTI)

Sulfur polymer cement (SPC) is a thermoplastic polymer consisting of 95 wt% elemental sulfur and 5 wt% organic modifiers to enhance long-term durability. SPC was originally developed by the U.S. Bureau of Mines as an alternative to hydraulic cement for construction applications. Previous attempts to use elemental sulfur as a construction material in the chemical industry failed due to premature degradation. These failures were caused by the internal stresses that result from changes in crystalline structure upon cooling of the material. By reacting elemental sulfur with organic polymers, the Bureau of Mines developed a product that successfully suppresses the solid phase transition and significantly improves the stability of the product. SPC, originally named modified sulfur cement, is produced from readily available, inexpensive waste sulfur derived from desulfurization of both flue gases and petroleum. The commercial production of SPC is licensed in the United States by Martin Resources (Odessa, Texas) and is marketed under the trade name Chement 2000. It is sold in granular form and is relatively inexpensive ({approx}$0.10 to 0.12/lb). Application of SPC for the treatment of radioactive, hazardous, and mixed wastes was initially developed and patented by Brookhaven National Laboratory (BNL) in the mid-1980s (Kalb and Colombo, 1985; Colombo et al., 1997). The process was subsequently investigated by the Commission of the European Communities (Van Dalen and Rijpkema, 1989), Idaho National Engineering Laboratory (Darnell, 1991), and Oak Ridge National Laboratory (Mattus and Mattus, 1994). SPC has been used primarily in microencapsulation applications but can also be used for macroencapsulation of waste. SPC microencapsulation has been demonstrated to be an effective treatment for a wide variety of wastes, including incinerator hearth and fly ash; aqueous concentrates such as sulfates, borates, and chlorides; blowdown solutions; soils; and sludges. It is not recommended for treatment of wastes containing high concentrations of nitrates because of potentially dangerous reactions between sulfur, nitrate, and trace quantities of organics. Recently, the process has been adapted for the treatment of liquid elemental mercury and mercury contaminated soil and debris.

KALB, P.

2001-08-22T23:59:59.000Z

274

High temperature ceramic membrane reactors for coal liquid upgrading. Final report, September 21, 1989--November 20, 1992  

SciTech Connect (OSTI)

Membrane reactors are today finding extensive applications for gas and vapor phase catalytic reactions (see discussion in the introduction and recent reviews by Armor [92], Hsieh [93] and Tsotsis et al. [941]). There have not been any published reports, however, of their use in high pressure and temperature liquid-phase applications. The idea to apply membrane reactor technology to coal liquid upgrading has resulted from a series of experimental investigations by our group of petroleum and coal asphaltene transport through model membranes. Coal liquids contain polycyclic aromatic compounds, which not only present potential difficulties in upgrading, storage and coprocessing, but are also bioactive. Direct coal liquefaction is perceived today as a two-stage process, which involves a first stage of thermal (or catalytic) dissolution of coal, followed by a second stage, in which the resulting products of the first stage are catalytically upgraded. Even in the presence of hydrogen, the oil products of the second stage are thought to equilibrate with the heavier (asphaltenic and preasphaltenic) components found in the feedstream. The possibility exists for this smaller molecular fraction to recondense with the unreacted heavy components and form even heavier undesirable components like char and coke. One way to diminish these regressive reactions is to selectively remove these smaller molecular weight fractions once they are formed and prior to recondensation. This can, at least in principle, be accomplished through the use of high temperature membrane reactors, using ceramic membranes which are permselective for the desired products of the coal liquid upgrading process. An additional incentive to do so is in order to eliminate the further hydrogenation and hydrocracking of liquid products to undesirable light gases.

Tsotsis, T.T. [University of Southern California, Los Angeles, CA (United States). Dept. of Chemical Engineering; Liu, P.K.T. [Aluminum Co. of America, Pittsburgh, PA (United States); Webster, I.A. [Unocal Corp., Los Angeles, CA (United States)

1992-12-31T23:59:59.000Z

275

Low-rank coal oil agglomeration  

DOE Patents [OSTI]

A low-rank coal oil agglomeration process. High mineral content, a high ash content subbituminous coals are effectively agglomerated with a bridging oil which is partially water soluble and capable of entering the pore structure, and usually coal derived.

Knudson, Curtis L. (Grand Forks, ND); Timpe, Ronald C. (Grand Forks, ND)

1991-01-01T23:59:59.000Z

276

Assumptions to the Annual Energy Outlook 2001 - Coal Market Module  

Gasoline and Diesel Fuel Update (EIA)

Coal Market Module Coal Market Module The NEMS Coal Market Module (CMM) provides forecasts of U.S. coal production, consumption, exports, distribution, and prices. The CMM comprises three functional areas: coal production, coal distribution, and coal exports. A detailed description of the CMM is provided in the EIA publication, Coal Market Module of the National Energy Modeling System 2001, DOE/EIA-M060(2001) January 2001. Key Assumptions Coal Production The coal production submodule of the CMM generates a different set of supply curves for the CMM for each year of the forecast. Separate supply curves are developed for each of 11 supply regions, and 12 coal types (unique combinations of thermal grade, sulfur content, and mine type). The modeling approach used to construct regional coal supply curves

277

Assumptions to the Annual Energy Outlook 2002 - Coal Market Module  

Gasoline and Diesel Fuel Update (EIA)

Coal Market Module Coal Market Module The NEMS Coal Market Module (CMM) provides forecasts of U.S. coal production, consumption, exports, distribution, and prices. The CMM comprises three functional areas: coal production, coal distribution, and coal exports. A detailed description of the CMM is provided in the EIA publication, Coal Market Module of the National Energy Modeling System 2002, DOE/EIA-M060(2002) (Washington, DC, January 2002). Key Assumptions Coal Production The coal production submodule of the CMM generates a different set of supply curves for the CMM for each year of the forecast. Separate supply curves are developed for each of 11 supply regions and 12 coal types (unique combinations of thermal grade, sulfur content, and mine type). The modeling approach used to construct regional coal supply curves

278

ENGINEERING DEVELOPMENT OF COAL-FIRED HIGH-PERFORMANCE POWER SYSTEMS  

SciTech Connect (OSTI)

A High Performance Power System (HIPPS) is being developed. This system is a coal-fired, combined cycle plant with indirect heating of gas turbine air. Foster Wheeler Development Corporation and a team consisting of Foster Wheeler Energy Corporation, Bechtel Corporation, University of Tennessee Space Institute and Westinghouse Electric Corporation are developing this system. In Phase 1 of the project, a conceptual design of a commercial plant was developed. Technical and economic analyses indicated that the plant would meet the goals of the project which include a 47 percent efficiency (HHV) and a 10 percent lower cost of electricity than an equivalent size PC plant. The concept uses a pyrolyzation process to convert coal into fuel gas and char. The char is fired in a High Temperature Advanced Furnace (HITAF). The HITAF is a pulverized fuel-fired boiler/air heater where steam is generated and gas turbine air is indirectly heated. The fuel gas generated in the pyrolyzer is then used to heat the gas turbine air further before it enters the gas turbine. The project is currently in Phase 2, which includes engineering analysis, laboratory testing and pilot plant testing. Research and development is being done on the HIPPS systems that are not commercial or being developed on other projects. Pilot plant testing of the pyrolyzer subsystem and the char combustion subsystem are being done separately, and after each experimental program has been completed, a larger scale pyrolyzer will be tested at the Power Systems Development Facility (PSDF) in Wilsonville, Al. The facility is equipped with a gas turbine and a topping combustor, and as such, will provide an opportunity to evaluate integrated pyrolyzer and turbine operation. The design of the char burner was completed during this quarter. The burner is designed for arch-firing and has a maximum capacity of 30 MMBtu/hr. This size represents a half scale version of a typical commercial burner. The burner is outfitted with nozzles for separate injection of char, coal, and limestone. Burner performance will be rated according to three criteria, carbon conversion efficiency, NOx generation, and flame stability. If initial testing in the arch configuration proves successful, further tests will be performed in the wall-fired arrangement. A complete set of process and instrumentation drawings (P/ID's) were completed for the Combustion and Environmental Test Facility (CETF) this quarter. These drawings established an ISA approved instrument tagging structure, and provided a coherent database for the development of a data acquisition system. The data acquisition system polls tag information (value, range, engineering units, etc.) from the distributed control system (DCS) highway, and provides a platform for data reduction. The quadrupole mass spectrometer, used during the pyrolyzer tests performed at the pilot plant in Livingston, N.J., has been redesigned for use at the CETF. The mass spectrometer is designed to provide on-line gas analysis by identifying all of the chemical components within the secondary air line, the flue gas recycle line, and the furnace exit ducting. The construction effort at the CETF continued this quarter with the completion of the char storage system, reheat burner, flue gas recycle piping, and the pulverized coal feed system.

NONE

1998-11-01T23:59:59.000Z

279

STEO November 2012 - coal supplies  

U.S. Energy Information Administration (EIA) Indexed Site

Despite drop in domestic coal production, U.S. coal exports to reach Despite drop in domestic coal production, U.S. coal exports to reach record high in 2012. While U.S. coal production is down 7 percent this year due in part to utilities switching to low-priced natural gas to generate electricity, American coal is still finding plenty of buyers in overseas markets. U.S. coal exports are expected to hit a record 125 million tons in 2012, the U.S. Energy Information Administration says in its new monthly short-term energy outlook. Coal exports are expected to decline in 2013, primarily because of continuing economic weakness in Europe, lower international coal prices, and higher coal production in Asia. However, U.S. coal exports next year are still expected to top 100 million tons for the third year in a row

280

Use of high-temperature, high-torque rheometry to study the viscoelastic properties of coal during carbonization  

SciTech Connect (OSTI)

When coal is heated in the absence of oxygen it softens at approximately 400 degrees C, becomes viscoelastic, and volatiles are driven off. With further heating, the viscous mass reaches a minimum viscosity in the range of 10{sup 3}-10{sup 5} Pa s and then begins to resolidify. A high-torque, high-temperature, controlled-strain rheometer with parallel plates has been used to study the theology during this process. Under shear, the viscosity of the softening mass decreases with increasing shear rate. During resolidification, the viscosity increases as C-C bond formation and physical interactions gives rise to an aromatic network, but, under shear, the network breaks apart and flows. This is viewed as a yielding of the structure. The higher the shear rate, the earlier the yielding occurs, such that if the shear rate is low enough, the structure is able to build. Also, further into resolidification lower shear rates are able to break the structure. It is proposed that resolidification occurs through the formation of aromatic clusters that grow and become crosslinked by non-covalent interactions. As the clusters grow, the amount of liquid surrounding them decreases and it is thought that the non-covalent interactions between clusters and liquid could decrease and the ability of growing clusters to move past each other increases, which would explain the weakening of the structure under shear. This work is part of a program of work aimed at attaining a greater understanding of microstructural changes taking place during carbonization for different coals, in order to understand the mechanisms that give rise to good quality cokes and coke oven problems such as excessive wall pressure.

Diaz, M.C.; Duffy, J.J.; Snape, C.E.; Steel, K.M. [University of Nottingham, Nottingham (United Kingdom)

2007-09-15T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Coal based electric generation comparative technologies report  

SciTech Connect (OSTI)

Ohio Clean Fuels, Inc., (OCF) has licensed technology that involves Co-Processing (Co-Pro) poor grade (high sulfur) coal and residual oil feedstocks to produce clean liquid fuels on a commercial scale. Stone Webster is requested to perform a comparative technologies report for grassroot plants utilizing coal as a base fuel. In the case of Co-Processing technology the plant considered is the nth plant in a series of applications. This report presents the results of an economic comparison of this technology with other power generation technologies that use coal. Technologies evaluated were:Co-Processing integrated with simple cycle combustion turbine generators, (CSC); Co-Processing integrated with combined cycle combustion turbine generators, (CCC); pulverized coal-fired boiler with flue gas desulfurization and steam turbine generator, (PC) and Circulating fluidized bed boiler and steam turbine generator, (CFB). Conceptual designs were developed. Designs were based on approximately equivalent net electrical output for each technology. A base case of 310 MWe net for each technology was established. Sensitivity analyses at other net electrical output sizes varying from 220 MWe's to 1770 MWe's were also performed. 4 figs., 9 tabs.

Not Available

1989-10-26T23:59:59.000Z

282

High opacity white plumes from coal-fired and oil-fired sources  

SciTech Connect (OSTI)

In recent years, with the installation of high efficiency particulate emission control devices on utility and industrial boilers, high-opacity white plumes have become more of a problem because formerly the emissions of primary particulate matter obscured and/or served as a condensing surface for the condensable material. The problem common to some of these installations is the violation of opacity standards due to the presence of a high-opacity persistent plume that emits from the stack. Oil fired boilers violating opacity standards typically comply with mass emission standards while coal fired boilers typically violate visual emission standards when simultaneously violating mass emission standards. The investigation reported here focuses on the atypical case when in-situ transmissometer measurements show compliance but plume opacity as measured by Reference Method 9 or LIDAR exceeds opacity standards. This case comes about due to gas phase reactions that produce fine aerosols, vapor phase condensation and physical agglomeration of sub-micron sized clusters and particles. The plume opacity control technology applicable to these aerosols which are created and/or grown in white plume is discussed in this paper.

Lee, K.T. (National Cheng Kung Univ. (TW))

1988-01-01T23:59:59.000Z

283

Adsorption Behavior of CO2 in Coal and Coal Char  

Science Journals Connector (OSTI)

Coals of diverse characteristics have been chosen to provide a better understanding on the influence of various coal properties, such as maceral, volatile matter, and ash contents. ... In addition, char samples from two of these coals (a non-coking coal A and a coking coal B) were prepared by pyrolysis at 800 and 1000 °C in a nitrogen atmosphere and were tested for CO2 adsorption capacity. ... As stated earlier, virgin coal samples considered for the adsorption measurements include coals A, C, and D, which are of low-, high-, and medium-volatile sub-bituminous rank, respectively. ...

Shanmuganathan Ramasamy; Pavan Pramod Sripada; Md Moniruzzaman Khan; Su Tian; Japan Trivedi; Rajender Gupta

2014-07-01T23:59:59.000Z

284

Investigate the effectivness of calcium-treated coals in the capture of sulfur gases generated in staged fired combustors. Third quarterly technical progress report, May 1-July 31, 1983  

SciTech Connect (OSTI)

In this quarter's work, a new procedure was developed to add calcium to pulverized coal. The method has been found to increase the calcium content of bituminous coal to 12% calcium by weight, which corresponds to a Ca/S ratio of greater than 2. Progress was also made on the combustion test facility this quarter. A new modification of the low-flow coal feeder has made that system steady and reliable. With the furnace wired and plumbed, and the other subsystems complete, the facility is almost ready to burn the treated coals.

Porter, J. H.; Manning, M. P.; Benedek, K. R.; Sharma, P. K.

1983-09-01T23:59:59.000Z

285

Engineering development of coal-fired high-performance power systems. Progress report, April 1--June 30, 1996  

SciTech Connect (OSTI)

In Phase 1 of the project, a conceptual design of a coal-fired, high-performance power system (HIPPS) was developed, and small-scale R and D was done in critical areas of the design. The current phase of the project includes development through the pilot plant stage and design of a prototype plant that would be built in Phase 3. The power-generating system being developed in this project will be an improvement over current coal-fired systems. It is a combined-cycle plant. This arrangement is referred to as the All Coal HIPPS because it does not require any other fuels for normal operation. A fluidized bed, air-blown pyrolyzer converts coal into fuel gas and char. The char is fired in a high-temperature advanced furnace (HITAF) which heats both air for a gas turbine and steam for a steam turbine. The fuel gas from the pyrolyzer goes to a topping combustor where it is used to raise the air entering the gas turbine to 1288 C. In addition to the HITAF, steam duty is achieved with a heat-recovery steam generator (HRSG) in the gas turbine exhaust stream and economizers in the HITAF flue gas exhaust stream. Progress during the quarter is described.

NONE

1996-12-31T23:59:59.000Z

286

DOE`s high performance power systems program: Development of advanced coal-fired combined-cycle systems  

SciTech Connect (OSTI)

Coal currently provides more than one third of the world`s electricity and more than one half of the US`s electricity. However, for coal to be the fuel of choice in the future, highly efficient, environmentally acceptable, and economically competitive, coal-fired power plants are needed. The US Department of Energy, Federal Energy Technology Center, under its High Performance Power Systems (HIPPS) Program, has two contracts in place, one with Foster Wheeler Development Corporation and one with United Technologies Research Center, to develop advanced power generation systems. Based on an indirectly fired cycle, HIPPS uses a combined cycle for power generation at efficiencies of 47--50% (HHV) with superior environmental performance (1/10 of New Source Performance Standards) and a lower cost-of-electricity (10% reduction relative to current coal-fired plants). HIPPS, scheduled to be ready for commercialization by the year 2005, could provide a solution to the anticipated worldwide demand for clean, efficient electricity generation. In this paper, the two HIPPS designs are reviewed and on-going research is discussed.

Ruth, L.; Plasynski, S.; Shaffer, F. [Dept. of Energy, Pittsburgh, PA (United States). Federal Energy Technology Center; Ramezan, M. [Burns and Roe Services Corp., Pittsburgh, PA (United States)

1997-09-01T23:59:59.000Z

287

Status of Coal Gasification: 1977  

Science Journals Connector (OSTI)

High-pressure technology is important to coal gasification for several reasons. When the end product ... of high pressures in all types of coal gasification reduces the pressure drop throughout the equipment,...

F. C. Schora; W. G. Bair

1979-01-01T23:59:59.000Z

288

Coal surface control for advanced fine coal flotation  

SciTech Connect (OSTI)

The primary objective of this research project is to develop advanced flotation methods for coal cleaning in order to achieve near total pyritic-sulfur removal at 90% Btu recovery, using coal samples procured from six major US coal seams. Concomitantly, the ash content of these coals is to be reduced to 6% or less. Work this quarter concentrated on the following: washability studies, which included particle size distribution of the washability samples, and chemical analysis of washability test samples; characterization studies of induction time measurements, correlation between yield, combustible-material recovery (CMR), and heating-value recovery (HVR), and QA/QC for standard flotation tests and coal analyses; surface modification and control including testing of surface-modifying reagents, restoration of hydrophobicity to lab-oxidized coals, pH effects on coal flotation, and depression of pyritic sulfur in which pyrite depression with calcium cyanide and pyrite depression with xanthated reagents was investigated; flotation optimization and circuitry included staged reagent addition, cleaning and scavenging, and scavenging and middling recycling. Weathering studies are also discussed. 19 figs., 28 tabs.

Fuerstenau, D.W.; Sastry, K.V.S.; Hanson, J.S.; Harris, G.; Sotillo, F.; Diao, J. (California Univ., Berkeley, CA (USA)); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. (Columbia Univ., New York, NY (USA)); Hu, Weibai; Zou, Y.; Chen, W. (Utah Univ., Salt Lake City, UT (USA)); Choudhry, V.; Sehgal, R.; Ghosh, A. (Praxis Engineers, Inc., Milpitas, CA (USA))

1990-08-15T23:59:59.000Z

289

Discharge produces hydrocarbons from coal  

Science Journals Connector (OSTI)

Discharge produces hydrocarbons from coal ... Studies of the reactions of coal in electric discharges by two chemists at the U.S. Bureau of Mines' Pittsburgh Coal Research Center may lead to improved ways of producing acetylene and other useful chemicals from coal. ... Other workers have produced high yields of acetylene from coal by extremely rapid pyrolysis using energy sources such as plasma jets, laser beams, arc-image reactors, and flash heaters. ...

1968-01-22T23:59:59.000Z

290

Coal in the Northern Rocky Mountains and Great Plains Region -- Clean, compliant, and available  

SciTech Connect (OSTI)

The Northern Rocky Mountains and Great Plains region produced over 340 million short tons of coal in 1997, approximately 30 percent of the nation`s total coal production. Coals from this region are shipped to 26 states in the western, midwest, southern, and eastern US and production is projected to increase to 415 million short tons by 2015; the projected increase will be utilized primarily for production of electric power. The coals are economically attractive because they can be produced by surface mining, and do not require costly beneficiation to be compliant with emission standards. The coals are compliant because their chemical composition was influenced by tectonic settings of the coal basins and provenance of the sediments entering the basins. Tectonics during the Paleocene also influenced rates of precipitation and depositional systems. These factors, in concert, controlled the amount, distribution, and levels of sulfur, ash, and trace elements of environmental concern in the region`s coals. The emphasis of this paper is on the chemistry of these thick, high-quality coals and the geologic controls that resulted in their accumulation.

Stricker, G.D.; Ellis, M.S.; Flores, R.M.; Bader, L.R. [Geological Survey, Denver, CO (United States)

1998-12-31T23:59:59.000Z

291

High pressure water pyrolysis of coal to evaluate the role of pressure on hydrocarbon generation and source rock maturation at high maturities under geological conditions  

Science Journals Connector (OSTI)

Abstract This study investigates the effect of water pressure on hydrocarbon generation and source rock maturation at high maturities for a perhydrous Tertiary Arctic coal, Svalbard. Using a 25 ml Hastalloy vessel, the coal was pyrolysed under low water pressure (230–300 bar) and high water pressure (500, 700 and 900 bar) conditions between 380 °C and 420 °C for 24 h. At 380 °C and 420 °C, gas yields were not affected by pressure up to 700 bar, but were reduced slightly at 900 bar. At 380 °C, the expelled oil yield was highest at 230 bar, but reduced significantly at 900 bar. At 420 °C cracking of expelled oil to gas was retarded at 700 and 900 bar. As well as direct cracking of the coal, the main source of gas generation at high pressure at both 380 °C and 420 °C is from bitumen trapped in the coal, indicating that this is a key mechanism in high pressure geological basins. Vitrinite reflectance (VR) was reduced by 0.16 %Ro at 380 °C and by 0.27 %Ro at 420 °C at 900 bar compared to the low pressure runs, indicating that source rock maturation will be more retarded at higher maturities in high pressure geological basins.

Clement N. Uguna; Andrew D. Carr; Colin E. Snape; Will Meredith

2015-01-01T23:59:59.000Z

292

Clean Coal Technology Demonstration Program  

Broader source: Energy.gov [DOE]

The Office of Fossil Energy’s Clean Coal Technology Demonstration Program (1986-1993) laid the foundation for effective technologies now in use that have helped significantly lower emissions of sulfur dioxide (SO2), nitrogen oxides (NOx) and airborne particulates (PM10).

293

Engineering development of coal-fired high-performance power systems  

SciTech Connect (OSTI)

A High Performance Power System (HIPPS) is being developed. This system is a coal-fired, combined cycle plant with indirect heating of gas turbine air. Foster Wheeler Development Corporation and a team consisting of Foster Wheeler Energy Corporation, Bechtel Corporation, University of Tennessee Space Institute and Westinghouse Electric Corporation are developing this system. In Phase 1 of the project, a conceptual design of a commercial plant was developed. Technical and economic analyses indicated that the plant would meet the goals of the project which include a 47 percent efficiency (HHV) and a 10 percent lower cost of electricity than an equivalent size PC plant. The concept uses a pyrolysis process to convert coal into fuel gas and char. The char is fired in a High Temperature Advanced Furnace (HITAF). The HITAF is a pulverized fuel-fired boiler/air heater where steam is generated and gas turbine air is indirectly heated. The fuel gas generated in the pyrolyzer is then used to heat the gas turbine air further before it enters the gas turbine. The project is currently in Phase 2 which includes engineering analysis, laboratory testing and pilot plant testing. Research and development is being done on the HIPPS systems that are not commercial or being developed on other projects. Pilot plant testing of the pyrolyzer subsystem and the char combustion subsystem are being done separately, and after each experimental program has been completed, a larger scale pyrolyzer will be tested at the Power Systems Development Facility (PSDF) in Wilsonville, AL. The facility is equipped with a gas turbine and a topping combustor, and as such, will provide an opportunity to evaluate integrated pyrolyzer and turbine operation. This report addresses the areas of technical progress for this quarter. The char combustion tests in the arch-fired arrangement were completed this quarter. A total of twenty-one setpoints were successfully completed, firing both synthetically-made char, and char generated from the pyrolyzer tests performed at FWDC's pilot plant in Livingston, New Jersey. Construction is to begin next quarter to retrofit the CETF for additional HIPPS char combustion studies in a wall-fired configuration. Design of the char transfer system for the PSDF also progressed during this quarter. A number of arrangements have been developed to modify the existing N-Valve configuration. As an experimental test facility, the PSDF needs to maintain operating flexibility in order to test under a wide range of conditions. Although a new char transfer design is needed to support the HIPPS testing at the facility, the Second Generation PFB program will also utilize this system.

NONE

1999-05-01T23:59:59.000Z

294

Engineering Development of Coal-Fired High-Performance Power Systems  

SciTech Connect (OSTI)

A High Performance Power System (HIPPS) is being developed. This system is a coal-fired, combined cycle plant with indirect heating of gas turbine air. Foster Wheeler Development Corporation and a team consisting of Foster Wheeler Energy Corporation, Bechtel Corporation, University of Tennessee Space Institute and Westinghouse Electric Corporation are developing this system. In Phase 1 of the project, a conceptual design of a commercial plant was developed. Technical and economic analyses indicated that the plant would meet the goals of the project which include a 47 percent efficiency (HHV) and a 10 percent lower cost of electricity than an equivalent size PC plant. The concept uses a pyrolysis process to convert coal into fuel gas and char. The char is fired in a High Temperature Advanced Furnace (HITAF). The HITAF is a pulverized fuel-fired boiler/air heater where steam is generated and gas turbine air is indirectly heated. The fuel gas generated in the pyrolyzer is then used to heat the gas turbine air further before it enters the gas turbine. The project is currently in Phase 2 which includes engineering analysis, laboratory testing and pilot plant testing. Research and development is being done on the HIPPS systems that are not commercial or being developed on other projects. Pilot plant testing of the pyrolyzer subsystem and the char combustion subsystem are being done separately, and after each experimental program has been completed, a larger scale pyrolyzer will be tested at the Power Systems Development Facility (PSDF) in Wilsonville, AL. The facility is equipped with a gas turbine and a topping combustor, and as such, will provide an opportunity to evaluate integrated pyrolyzer and turbine operation. This report addresses the areas of technical progress for this quarter. Detailed design of the components to be used to for the circulating bed gasification tests is underway. The circulating fluidized bed will allow for easy scale-up to larger size plants. The existing pyrolyzer will be outfitted with a cyclone and a j-valve to capture and reinject char into the lower combustion zone. Additional development work has been performed to evaluate advanced cycles utilizing the HIPPS system concept.

York Tsuo

1999-12-31T23:59:59.000Z

295

Coal-fired high performance power generating system. Quarterly progress report, July 1, 1993--September 30, 1993  

SciTech Connect (OSTI)

This report covers work carried out under Task 3, Preliminary Research and Development, and Task 4, Commercial Generating Plant Design, under contract DE-AC22-92PC91155, {open_quotes}Engineering Development of a Coal Fired High Performance Power Generation System{close_quotes} between DOE Pittsburgh Energy Technology Center and United Technologies Research Center. The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) by the year 2000 that is capable of >47% thermal efficiency; NO{sub x}, SO{sub x}, and particulates {le} 25% NSPS; cost {ge} 65% of heat input; and all solid wastes benign. The report discusses progress in cycle analysis, chemical reactor modeling, ash deposition rate calculations for HITAF (high temperature advanced furnace) convective air heater, air heater materials, and deposit initiation and growth on ceramic substrates.

Not Available

1993-12-31T23:59:59.000Z

296

Healy Clean Coal Project  

SciTech Connect (OSTI)

The Healy Clean Coal Project, selected by the U.S. Department of Energy under Round 111 of the Clean Coal Technology Program, has been constructed and is currently in the Phase 111 Demonstration Testing. The project is owned and financed by the Alaska Industrial Development and Export Authority (AIDEA), and is cofunded by the U.S. Department of Energy. Construction was 100% completed in mid-November of 1997, with coal firing trials starting in early 1998. Demonstration testing and reporting of the results will take place in 1998, followed by commercial operation of the facility. The emission levels of nitrogen oxides (NOx), sulfur dioxide (S02), and particulate from this 50-megawatt plant are expected to be significantly lower than current standards.

None

1997-12-31T23:59:59.000Z

297

Coal: the new black  

SciTech Connect (OSTI)

Long eclipsed by oil and natural gas as a raw material for high-volume chemicals, coal is making a comeback, with oil priced at more than $100 per barrel. It is relatively cheap feedstock for chemicals such as methanol and China is building plants to convert coal to polyolefins on a large scale and interest is spreading worldwide. Over the years several companies in the US and China have made fertilizers via the gasification of coal. Eastman in Tennessee gasifies coal to make methanol which is then converted to acetic acid, acetic anhydride and acetate fiber. The future vision is to convert methanol to olefins. UOP and Lurgi are the major vendors of this technology. These companies are the respective chemical engineering arms of Honeywell and Air Liquide. The article reports developments in China, USA and India on coal-to-chemicals via coal gasification or coal liquefaction. 2 figs., 2 photo.

Tullo, A.H.; Tremblay, J.-F.

2008-03-15T23:59:59.000Z

298

Evaluation of sulfur-reducing microorganisms for organic desulfurization. [Pyrococcus furiosus  

SciTech Connect (OSTI)

Because of substantial portion of the sulfur in Illinois coal is organic, microbial desulfurization of sulfidic and thiophenic functionalities could hold great potential for completing pyritic sulfur removal. We are testing the hypothesis that organic sulfur can be reductively removed as H{sub 2}S through the activities of anaerobic microorganisms. Our objectives for this year include the following: (1) To obtain cultures that will reductively desulfurize thiophenic model compounds. In addition to crude oil enrichments begun last year, we sampled municipal sewage sludge. (2) To continue to work toward optimizing the activity of the DBDS-reducing cultures obtained during the previous year. (3) To expand coal desulfurization work to include other coals including Illinois Basin Coal 101 and a North Dakota lignite, which might be more susceptible to the dibenzyldisulfide reducing cultures due to its lower rank. (4) To address the problem of sulfide sorption, by investigating the sorption capacity of coals in addition to Illinois Basin Coal 108.

Miller, K.W.

1991-01-01T23:59:59.000Z

299

NETL: Clean Coal Technology Demonstration Program (CCTDP) - Round 1  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

1 1 Industrial Applications Advanced Cyclone Combustor with Internal Sulfur, Nitrogen, and Ash Control - Project Brief [PDF-302KB] Coal Tech Corp., Williamsport, PA PROGRAM PUBLICATIONS Final Reports Demonstration of an Advanced Cyclone Coal Combustor with Internal Sulfur Nitrogen, and Ash Control for the Conversion of a 23-MMBtu/Hour Oil Fired Boiler to Pulverized Coal (Aug 1991) Volume 1: Final Technical Report [PDF-5.9MB] Appendixes I through VI [PDF-8.9MB] CCT Reports: Project Performance Summaries, Post-Project Assessments, & Topical Reports The Coal Tech Advanced Cyclone Combustor Demonstration Project -- A DOE Assessment [PDF-234KB] (May 1993) Environmental Reports Annual Environmental Report for The Demonstration of an Advanced Cyclone Coal Combustor, with Internal Sulfur, Nitrogen, and Ash Control for the Conversion of a 23 MMBtu/Hour Boiler to Coal [PDF-812KB] (Sept 1987)

300

Sulfur minimization in bacterial leaching  

SciTech Connect (OSTI)

The production of sewage biosolids in Ontario in 1989 was estimated to be 7 million m{sup 3} of wet sludge per year. Of this amount, land application accounts for between 20 and 30% of the total. Unfortunately, the use of sewage biosolids on agricultural land is often prohibited because of heavy metal contamination of the biosolids. High cost and operational problems have made chemical methods of metal extraction unattractive. Consequently, microbiological methods of leaching of heavy metals have been studied for over a decade. A relatively simple microbiological process has been investigated in recent years in flask level experiments and recently in a semicontinuous system. The process exploits nonacidophilic and acidophilic indigenous thiobacilli to extract heavy metals from sewage biosolids. These thiobacilli use elemental sulfur as the energy source, producing sulfuric acid. However, the resulting decontaminated biosolids can cause environmental problems like acidification of the soil, when acid is generated from the residual sulfur in the biosolids. The present study examines the possibility of reducing the amount of sulfur added in batch and semicontinuous bacterial leaching systems, and maximizing sulfur oxidation efficiency, thereby reducing the residual sulfur in leached biosolids.

Seth, R.; Prasad, D.; Henry, J.G. [Univ. of Toronto, Ontario (Canada). Dept. of Civil Engineering

1996-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
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301

Caustic washing for refining of direct coal liquefaction products  

SciTech Connect (OSTI)

Extensive research and development sponsored by the U.S. DOE/PETC over the past two decades has resulted in dramatic improvements in the quality of direct coal liquefaction products. High-quality coal-derived distillates are obtainable from catalytic two-stage liquefaction (TSL) processes, such as those developed at the Wilsonville, AL pilot plant and the Hydrocarbon Technologies Inc. (HTI) pilot plant and bench units. The products of the Wilsonville and HTI TSL operations are suitable as high quality feedstocks for producing transportation fuels in a refinery. These products have important quality advantages over crude petroleum: they are distillates boiling below about 700{degrees}F and are thus virtually free of resid and metals, and they have very low sulfur contents and low nitrogen contents. The coal liquids have carbon and hydrogen contents and Watson characterization factors within the range of crude petroleums. However, relative to crude petroleum, the crude coal products have elevated oxygen contents. This report describes the removal of phenols from coal liquids by caustic washing, and the the recovery of the cresylic acid by-product.

Winschel, R.A.; Burke, F.P.; Robbins, G.A.; Brandes, S.D. [CONSOL, Inc., Library, PA (United States); Zhou, P. [Burns and Roe Services Corp., Pittsburgh, PA (United States)

1995-12-31T23:59:59.000Z

302

NETL: CCPI/Clean Coal Demonstrations  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Topical Reports Topical Reports CCPI/Clean Coal Demonstrations Topical Reports General Topical Report #18: Environmental Benefits of Clean Coal Technologies[PDF-2MB] (Apr 2001) This report describes a variety of processes that are capable of meeting existing and emerging environmental regulations and competing economically in a deregulated electric power marketplace. Topical Report #17: Software Systems in Clean Coal Demonstration Projects [PDF-650KB] (Dec 2001) This report describes computer software systems used to optimize coal utilization technologies. Environmental Control Technologies Sulfur Dioxide Control Technologies Topical Report #12: Advanced Technologies for the Control of Sulfur Dioxide Emissions from Coal-Fired Boilers [PDF-1.6MB] (June 1999) A discussion of three CCT projects that demonstrate innovative wet flue gas desulfurization technologies to remove greater than 90% SO2.

303

Upgrading low-rank coals using the liquids from coal (LFC) process  

SciTech Connect (OSTI)

Three unmistakable trends characterize national and international coal markets today that help to explain coal`s continuing and, in some cases, increasing share of the world`s energy mix: the downward trend in coal prices is primarily influenced by an excess of increasing supply relative to increasing demand. Associated with this trend are the availability of capital to expand coal supplies when prices become firm and the role of coal exports in international trade, especially for developing nations; the global trend toward reducing the transportation cost component relative to the market, preserves or enhances the producer`s profit margins in the face of lower prices. The strong influence of transportation costs is due to the geographic relationships between coal producers and coal users. The trend toward upgrading low grade coals, including subbituminous and lignite coals, that have favorable environmental characteristics, such as low sulfur, compensates in some measure for decreasing coal prices and helps to reduce transportation costs. The upgrading of low grade coal includes a variety of precombustion clean coal technologies, such as deep coal cleaning. Also included in this grouping are the coal drying and mild pyrolysis (or mild gasification) technologies that remove most of the moisture and a substantial portion of the volatile matter, including organic sulfur, while producing two or more saleable coproducts with considerable added value. SGI International`s Liquids From Coal (LFC) process falls into this category. In the following sections, the LFC process is described and the coproducts of the mild pyrolysis are characterized. Since the process can be applied widely to low rank coals all around the world, the characteristics of coproducts from three different regions around the Pacific Rim-the Powder River Basin of Wyoming, the Beluga Field in Alaska near the Cook Inlet, and the Bukit Asam region in south Sumatra, Indonesia - are compared.

Nickell, R.E.; Hoften, S.A. van

1993-12-31T23:59:59.000Z

304

NETL: Coal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

use of our domestic energy resources and infrastructure. Gasification Systems | Advanced Combustion | Coal & Coal-Biomass to Liquids | Solid Oxide Fuel Cells | Turbines CO2...

305

A NOVEL APPROACH TO CATALYTIC DESULFURIZATION OF COAL  

SciTech Connect (OSTI)

Column chromatographic separation of the S=PBu{sub 3}/PBu{sub 3} product mixture followed by weighing the S=PBu{sub 3}, and by vacuum distillation of S=PBu{sub 3}/PBu{sub 3}mixture followed by gas chromatographic analysis are described. Effects of coal mesh size, pre-treatment with methanol Coal (S) + excess PR{sub 3} {yields} Coal + S=PR{sub 3}/PBu{sub 3} and sonication on sulfur removal by PBu{sub 3} revealed that particle size was not observed to affect desulfurization efficiency in a consistent manner. Coal pretreatment with methanol to induce swelling or the addition of a filter aid such as Celite reduced desulfurization efficiency of the PBu{sub 3} and sonication was no more effective than heating. A rationale is put forth for the lack of efficacy of methanol pretreatment of the coal in desulfurization runs with PBu{sub 3}. Coal desulfurization with PBu{sub 3} was not improved in the presence of miniscule beads of molten lithium or sodium as a desulfurizing reagent for SPBu{sub 3} in a strategy aimed at regenerating PBu{sub 3} inside coal pores. Although desulfurization of coals did occur in sodium solutions in liquid ammonia, substantial loss of coal mass was also observed. Of particular concern is the mass balance in the above reaction, a problem which is described in some detail. In an effort to solve this difficulty, a specially designed apparatus is described which we believe can solve this problem reasonably effectively. Elemental sodium was found to remove sulfur quantitatively from a variety of polycyclic organosulfur compounds including dibenzothiophene and benzothiophene under relatively mild conditions (150 C) in a hydrocarbon solvent without requiring the addition of a hydrogen donor. Lithium facilitates the same reaction at a higher temperature (254 C). Mechanistic pathways are proposed for these transformations. Curiously, dibenzothiophene and its corresponding sulfone was virtually quantitatively desulfurized in sodium solutions in liquid ammonia at -33 C, although the yield of biphenyl was only about 20 to 30%. On the other hand, benzothiophene gave a high yield of 2-ethylthiophenol under these conditions. Although our superbase P(MeNCH{sub 2}CH{sub 2}){sub 3}N, which is now commercially available, is a more effective desulfurizing agent for a variety of organophosphorus compounds than PPh{sub 3} or its acyclic analogue P(NMe){sub 3}, it does not desulfurize benzothiophene or dibenzothiophene.

John G. Verkade

2001-11-01T23:59:59.000Z

306

Advanced product recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Third quarterly technical progress report  

SciTech Connect (OSTI)

More than 170 wet scrubber systems applied to 72,000 MW of US, coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed form the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. Arthur D. Little, Inc., together with its industry and commercialization advisor, Engelhard Corporation, and its university partner, Tufts, plans to develop and scale-up an advanced, byproduct recovery technology that is a direct, catalytic process for reducing sulfur dioxide to elemental sulfur. The principal objective of the Phase 1 program is to identify and evaluate the performance of a catalyst which is robust and flexible with regard to choice of reducing gas. In order to achieve this goal, they have planned a structured program including: market/process/cost/evaluation; lab-scale catalyst preparation/optimization studies; lab-scale, bulk/supported catalyst kinetic studies; bench-scale catalyst/process studies; and utility review. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning.

NONE

1996-07-01T23:59:59.000Z

307

Modeling high-pressure adsorption of gas mixtures on activated carbon and coal using a simplified local-density model  

SciTech Connect (OSTI)

The simplified local-density (SLD) theory was investigated regarding its ability to provide accurate representations and predictions of high-pressure supercritical adsorption isotherms encountered in coalbed methane (CBM) recovery and CO{sub 2} sequestration. Attention was focused on the ability of the SLD theory to predict mixed-gas adsorption solely on the basis of information from pure gas isotherms using a modified Peng-Robinson (PR) equation of state (EOS). An extensive set of high-pressure adsorption measurements was used in this evaluation. These measurements included pure and binary mixture adsorption measurements for several gas compositions up to 14 MPa for Calgon F-400 activated carbon and three water-moistened coals. Also included were ternary measurements for the activated carbon and one coal. For the adsorption of methane, nitrogen, and CO{sub 2} on dry activated carbon, the SLD-PR can predict the component mixture adsorption within about 2.2 times the experimental uncertainty on average solely on the basis of pure-component adsorption isotherms. For the adsorption of methane, nitrogen, and CO{sub 2} on two of the three wet coals, the SLD-PR model can predict the component adsorption within the experimental uncertainties on average for all feed fractions (nominally molar compositions of 20/80, 40/60, 60/40, and 80/20) of the three binary gas mixture combinations, although predictions for some specific feed fractions are outside of their experimental uncertainties.

Fitzgerald, J.E.; Robinson, R.L.; Gasem, K.A.M. [Oklahoma State University, Stillwater, OK (United States). School of Chemical Engineering

2006-11-07T23:59:59.000Z

308

Coal Ash Corrosion Resistant Materials Testing  

SciTech Connect (OSTI)

In April 1999, three identical superheater test sections were installed into the Niles Unit No.1 for the purpose of testing and ranking the coal ash corrosion resistance of candidate superheater alloys. The Niles boiler burns high sulfur coal (3% to 3.5%) that has a reasonably high alkali content, thus the constituents necessary for coal ash corrosion are present in the ash. The test sections were controlled to operate with an average surface metal temperature from approximately 1060 F to 1210 F which was well within the temperature range over which coal ash corrosion occurs. Thus, this combination of aggressive environment and high temperature was appropriate for testing the performance of candidate corrosion-resistant tube materials. Analyses of the deposit and scale confirmed that the aggressive alkali-iron-trisulfate constituent was present at the metal surface and active in tube metal wastage. The test sections were constructed so that the response of twelve different candidate tube and/or coating materials could be studied. The plan was to remove and evaluate one of the three test sections at time intervals of 1 year, 3 years, and 5 years. This would permit an assessment of performance of the candidate materials as a function of time. This report provides the results of the evaluation of Test Section C, including the samples that remained in the Test Section for the full exposure period as well as those that were removed early. The analysis of Test Section C followed much the same protocol that was employed in the assessment of Test Section A. Again, the focus was on determining and documenting the relative corrosion rates of the candidate materials. The detailed results of the investigation are included in this report as a series of twelve appendices. Each appendix is devoted to the performance of one of the candidate alloys. The table below summarizes metal loss rate for the worst case sample of each of the candidate materials for both Test Sections A and C. The body of this report compares these for all of the samples in the test section. The 'Coal Ash Corrosion Resistant Materials Testing Program' is being conducted by The Babcock & Wilcox Company (B&W), the U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) at Reliant Energy's Niles plant in Niles, Ohio to provide full-scale, in-situ testing of recently developed boiler superheater materials. Fireside corrosion is a key issue for improving efficiency of new coal fired power plants and improving service life in existing plants. In November 1998, B&W began development of a system to permit testing of advanced tube materials at metal temperatures typical of advanced supercritical steam temperatures (1100 F and higher) in a boiler exhibiting coal ash corrosive conditions. Several materials producers including Oak Ridge National Laboratory (ORNL) contributed advanced materials to the project. In the spring of 1999 a system consisting of three identical sections, each containing multiple segments of twelve different materials, was installed. The sections are cooled by reheat steam, and are located just above the furnace entrance in Niles Unit No.1, a 110 MWe unit firing high sulfur Ohio coal. In November 2001 the first section was removed for thorough metallurgical evaluation after 29 months of operation. The second section was removed in August of 2003. Its evaluation has been completed and is the subject of this report. The final section remains in service and is expected to be removed in the spring of 2005. This paper describes the program; its importance, the design, fabrication, installation and operation of the test system, materials utilized, and experience to date. This report briefly reviews the results of the evaluation of the first section and then presents the results of the evaluation of the second section.

D. K. McDonald; P. L. Daniel; D. J. DeVault

2003-08-31T23:59:59.000Z

309

NETL: News Release - Projects Selected to Study Coal Plant Particulate  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

5, 2004 5, 2004 Projects Selected to Study Coal Plant Particulate Matter, Human Health PITTSBURGH, PA - The Department of Energy has selected three projects to help determine whether fine particulates emitted from coal-fired power plants affect human health, and which components of the particulates may be most problematic. Past studies have established that particulate matter smaller than 2.5 microns in diameter from all sources does affect human health, but there is scant information to provide a link between PM2.5 emitted specifically from coal plants and cardiac or respiratory health problems in humans. PM2.5 refers to particles-invisible to the eye-no more than 1/30th of the width of a human hair Coal plants emit only small quantities of "primary" PM2.5 (e.g., fly ash) because all plants have high-efficiency particulate-collection devices. However, coal plants are responsible for a great deal of "secondary" PM2.5, which forms in the atmosphere from emissions of sulfur dioxide (SO2) and nitrogen oxides (NOx). Data collected in the new studies will be used to help design standards reviews and to devise strategies for controlling power plant emissions of PM2.5, SO2, and NOx.

310

POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly technical progress report No. 5, October--December, 1995  

SciTech Connect (OSTI)

Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74{mu}m) clean coal. Economical dewatering of an ultrafine clean coal product to a 20% level moisture will be an important step in successful implementation of the advanced cleaning processes. The main objective of the proposed program is to evaluate a novel surface modification technique, which utilizes the synergistic effect of metal ions-surfactant combination, for dewatering of ultra-fine clean coal on a proof-of-concept scale of 1 to 2 tph. The novel surface modification technique developed at the the University of Kentucky Center for Applied Energy Research will be evaluated using vacuum, centrifuge, and hyperbaric filtration equipment. Dewatering tests will be conducted using the fine clean coal froth produced by the column flotation units at the Powell Mountain Coal Company, Mayflower Preparation Plant in St. Charles, Virginia. The POC-scale studies will be conducted on two different types of clean coal, namely, high sulfur and low sulfur clean coal. Accomplishments for the past quarter are described.

Groppo, J.G.; Parekh, B.K.

1996-02-01T23:59:59.000Z

311

Assumptions to the Annual Energy Outlook 2000 - Coal Market Module  

Gasoline and Diesel Fuel Update (EIA)

The NEMS Coal Market Module (CMM) provides forecasts of U.S. coal production, consumption, exports, distribution, and prices. The CMM comprises three functional areas: coal production, coal distribution, and coal exports. A detailed description of the CMM is provided in the EIA publication, Coal Market Module of the National Energy Modeling System 2000, DOE/EIA-M060(2000) January 2000. The NEMS Coal Market Module (CMM) provides forecasts of U.S. coal production, consumption, exports, distribution, and prices. The CMM comprises three functional areas: coal production, coal distribution, and coal exports. A detailed description of the CMM is provided in the EIA publication, Coal Market Module of the National Energy Modeling System 2000, DOE/EIA-M060(2000) January 2000. Key Assumptions Coal Production The coal production submodule of the CMM generates a different set of supply curves for the CMM for each year of the forecast. Separate supply curves are developed for each of 11 supply regions, and 12 coal types (unique combinations of thermal grade, sulfur content, and mine type). The modeling approach used to construct regional coal supply curves addresses the relationship between the minemouth price of coal and corresponding levels of coal production, labor productivity, and the cost of factor inputs (mining equipment, mine labor, and fuel requirements).

312

Coal Ash Corrosion Resistant Materials Testing Program  

SciTech Connect (OSTI)

The "Coal Ash Corrosion Resistant Materials Testing Program" is being conducted by The Babcock & Wilcox Company (B&W), the U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) at Reliant Energy?s Niles plant in Niles, Ohio to provide full-scale, in-situ testing of recently developed boiler superheater materials. Fireside corrosion is a key issue for improving efficiency of new coal fired power plants and improving service life in existing plants. In November 1998, B&W began development of a system to permit testing of advanced tube materials at metal temperatures typical of advanced supercritical steam temperatures (1100°F and higher) in a boiler exhibiting coal ash corrosive conditions. Several materials producers including Oak Ridge National Laboratory (ORNL) contributed advanced materials to the project. In the spring of 1999 a system consisting of three identical sections, each containing multiple segments of twelve different materials, was installed. The sections are cooled by reheat steam, and are located just above the furnace entrance in Niles? Unit #1, a 110 MWe unit firing high sulfur Ohio coal. In November 2001 the first section was removed for thorough metallurgical evaluation after 33 months of operation. The second and third sections remain in service and the second is expected to be removed in the fall of 2003; the last is tentatively planned for the fall of 2004. This paper describes the program; its importance; the design, fabrication, installation and operation of the test system; materials utilized; experience to date; and results of the evaluation of the first section.

McDonald, D.K.

2003-04-22T23:59:59.000Z

313

Small boiler uses waste coal  

SciTech Connect (OSTI)

Burning coal waste in small boilers at low emissions poses considerable problem. While larger boiler suppliers have successfully installed designs in the 40 to 80 MW range for some years, the author has been developing small automated fluid bed boiler plants for 25 years that can be applied in the range of 10,000 to 140,000 lbs/hr of steam. Development has centered on the use of an internally circulating fluid bed (CFB) boiler, which will burn waste fuels of most types. The boiler is based on the traditional D-shaped watertable boiler, with a new type of combustion chamber that enables a three-to-one turndown to be achieved. The boilers have all the advantages of low emissions of the large fluid boilers while offering a much lower height incorporated into the package boiler concept. Recent tests with a waste coal that had a high nitrogen content of 1.45% demonstrated a NOx emission below the federal limit of 0.6 lbs/mm Btu. Thus a NOx reduction on the order of 85% can be demonstrate by combustion modification alone. Further reductions can be made by using a selective non-catalytic reduction (SNCR) system and sulfur absorption of up to 90% retention is possible. The article describes the operation of a 30,000 lbs/hr boiler at the Fayette Thermal LLC plant. Spinheat has installed three ICFB boilers at a nursing home and a prison, which has been tested on poor-grade anthracite and bituminous coal. 2 figs.

Virr, M.J. [Spinheat Ltd. (United States)

2009-07-15T23:59:59.000Z

314

Coal-fueled high-speed diesel engine development. Final report, September 28, 1990--November 30, 1993  

SciTech Connect (OSTI)

The goal of this program was to study the feasibility of operating a Detroit Diesel Series 149 engine at high speeds using a Coal-Water-Slurry (CWS) fuel. The CWS-fueled 149 engine is proposed for the mine-haul off-highway truck and work boat marine markets. Economic analysis studies indicate that, for these markets, the use of CWS fuel could have sufficient operating cost savings, depending upon the future diesel fuel price, emission control system capital and operating costs, and maintenance and overhaul costs. A major portion of the maintenance costs is expected to be due to lower life and higher cost of the CWS injectors. Injection and combustion systems were specially designed for CWS, and were installed in one cylinder of a Detroit Diesel 8V-149TI engine for testing. The objective was to achieve engine operation for sustained periods at speeds up to 1,900 rpm with reasonable fuel economy and coal burnout rate. A computer simulation predicted autoignition of coal fuel at 1,900 rpm would require an average droplet size of 18 microns and 19:1 compression ratio, so the injection system, and pistons were designed accordingly. The injection system was capable of supplying the required volume of CWS/injection with a duration of approximately 25 crank angle degrees and peak pressures on the order of 100 mpa. In addition to the high compression ratio, the combustion system also utilized hot residual gases in the cylinder, warm inlet air admission and ceramic insulated engine components to enhance combustion. Autoignition of CWS fuel was achieved at 1900 rpm, at loads ranging from 20--80 percent of the rated load of diesel-fuel powered cylinders. Limited emissions data indicates coal burnout rates in excess of 99 percent. NO{sub x} levels were significantly lower, while unburned hydrocarbon levels were higher for the CWS fueled cylinder than for corresponding diesel-fuel powered cylinders.

Kakwani, R.M.; Winsor, R.E.; Ryan, T.W. III; Schwalb, J.A.; Wahiduzzaman, S.; Wilson, R.P. Jr.

1993-09-01T23:59:59.000Z

315

A novel concept for high conversion of coal to liquids. Final report, 1 September 1988--31 August 1992  

SciTech Connect (OSTI)

A batch microreactor was designed and fabricated as a means of investigating maximum yields of liquids obtainable in very short reaction times of the order of a few seconds, and the maximum ratios of liquids/hydrocarbon (HC) gases obtainable under those conditions. A Wyodak sub-bituminous coal, crushed and sieved to {minus}200 mesh particle size, was used in the experiments, with a temperature of 500{degrees}C and a pressure of 1500 psi. The fine coal particles were fed dry to the reactor and heated to reaction temperature in times of one to two seconds. At a time of 3 seconds at reaction temperature, in a single pass a liquid yield of 60% by weight of the coal was obtained, accompanied by a ratio of liquids/(HC) gases of 30/1. When the unreacted solids were recycled to the reactor, and the results combined with those of the first pass, a liquid yield of 82% by weight of the coal was achieved, accompanied by a ratio of liquids/HC gases of 30/1. This ratio represents only about 3 wt percent HC gases, much lower that is produced in current advanced technologies, and represents a large saving in hydrogen consumption. A simulated distillation technique was applied to the liquids. The liquid product contained 86% by weight (of the liquids) total distillables (boiling point below 538{degrees}C), including 70% by weight of low-boiling fractions in the gasoline, kerosene and gas oil range (boiling point up to 325{degrees}C). The liquid product exhibited a H/C ratio of 1.5, which is considerably higher than observed in current advanced technologies for the primary liquids. Several catalysts were investigated. Iron catalysts, specifically ferric chloride hexahydrate and ferric sulfate pentahydrate, each produced these high conversions and high ratios of liquids/HC gases.

Wiser, W.H.; Shabtai, J.

1994-04-01T23:59:59.000Z

316

Laboratory Study on Gasification Reactivity of Coals and Petcokes in CO2/Steam at High Temperatures  

Science Journals Connector (OSTI)

A diffusion term associated with the carbon structure may be needed for modelling the gasification behaviors of the petcoke-like materials. ... Gasification technology is used to convert feedstocks, not only coal but also petcoke and other carbonaceous materials, to fuel gas or syngas,(1, 2) which can be used to generate electricity and heat or to synthesize liquid fuel and chemicals. ... It is certain that petcoke, derived from oil refinery coke units or other cracking processes, has a much lower gasification reactivity than coal chars, especially at low temperatures. ...

Liwei Ren; Jianli Yang; Feng Gao; Jinding Yan

2013-07-30T23:59:59.000Z

317

Calcium looping process for high purity hydrogen production integrated with capture of carbon dioxide, sulfur and halides  

DOE Patents [OSTI]

A process for producing hydrogen comprising the steps of: (i) gasifying a fuel into a raw synthesis gas comprising CO, hydrogen, steam, sulfur and halide contaminants in the form of H.sub.2S, COS, and HX, wherein X is a halide; (ii) passing the raw synthesis gas through a water gas shift reactor (WGSR) into which CaO and steam are injected, the CaO reacting with the shifted gas to remove CO.sub.2, sulfur and halides in a solid-phase calcium-containing product comprising CaCO.sub.3, CaS and CaX.sub.2; (iii) separating the solid-phase calcium-containing product from an enriched gaseous hydrogen product; and (iv) regenerating the CaO by calcining the solid-phase calcium-containing product at a condition selected from the group consisting of: in the presence of steam, in the presence of CO.sub.2, in the presence of synthesis gas, in the presence of H.sub.2 and O.sub.2, under partial vacuum, and combinations thereof.

Ramkumar, Shwetha; Fan, Liang-Shih

2013-07-30T23:59:59.000Z

318

Low severity coal liquefaction promoted by cyclic olefins. Quarterly report, January--March 1994  

SciTech Connect (OSTI)

Previous research has suggested that using a more effective hydrogen donor solvent in the low severity coal liquefaction reaction improves coal conversion. In order to understand the results of these methods, both independently and combined, a factorial experiment was designed. Pretreating coal with hydrochloric and sulfurous acid solutions in both water and methanol is compared with pretreating coal using only methanol and with no pretreatment. The effects of these pretreatments on coal liquefaction behavior are contrasted with the ammonium acetate pretreatment. Within each of these, individual reactions are performed with the hydroaromatic 1,2,3,4-tetrahydronaphthalene (tetralin, TET) and the cyclic olefin 1,4,5,8-tetrahydronaphthalene (isotetralin, ISO). The final aspect of the factorial experiment is the comparison of Wyodak subbituminous coal (WY) from the Argonne Premium Sample Bank and Black Thunder subbituminous coal (BT) provided by Amoco. Half of the reactions in the matrix have now been completed. In all but one case, Black Thunder-HCl/H{sub 2}O, the ISO proved to be more reactive than TET. After the other four reactions using this combination are complete, the average conversion may be greater with the cyclic olefin. The second part of this paper describes the current and future work with Fourier transform infrared spectroscopy. The objective of this work is to determine the kinetics of reaction of isotetralin at high temperatures and pressures. This quarter combinations of three products typically produced from isotetralin were used in spectral subtraction.

Curtis, C.W.

1994-06-01T23:59:59.000Z

319

Development of a high-performance coal-fired power generating system with pyrolysis gas and char-fired high temperature furnace (HITAF)  

SciTech Connect (OSTI)

A concept for an advanced coal-fired combined-cycle power generating system is currently being developed. The first phase of this three-phase program consists of conducting the necessary research and development to define the system, evaluating the economic and technical feasibility of the concept, and preparing an R D plan to develop the concept further. The power generating system being developed in this project will be an improvement over current coal-fired systems. Goals have been specified that relate to the efficiency, emissions, costs, and general operation of the system. The system proposed to meet these goals is a combined-cycle system where air for a gas turbine is indirectly heated to approximately 1800[degrees]F in furnaces fired with coal-derived fuels and then directly heated in a natural-gas-fired combustor to about 2400[degrees]F. The system is based on a pyrolyzing process that converts the coal into a low-Btu fuel gas and char. The fuel gas is relatively clean, and it is fired to heat tube surfaces that are susceptible to corrosion and problems from ash deposition. In particular, the high-temperature air heater tubes, which will need to be a ceramic material, will be located in a separate furnace or region of a furnace that is exposed to combustion products from the low-Btu fuel gas only.

Not Available

1993-02-01T23:59:59.000Z

320

The structure and reactivity of a low-sulfur lacustrine oil shale (Colorado U.S.A.) compared with those of a high-sulfur marine oil shale (Julia Creek, Queensland, Australia)  

Science Journals Connector (OSTI)

Abstract Oil shales from two different continents (Australia and North America) of different ages (100 and 40 million years) and origins (one marine, one lacustrine) have been reacted in the range 355–425 °C under H2 or N2 for 1 or 5 h with or without the addition of catalyst. The shales differed in S content, and the nature of the mineral matter, but both had high atomic H/C ratios. The overall reactivity of the two shales was similar and high yields of soluble products could be obtained under relatively mild conditions with only small CO2 yields, but the temperature dependence of reactivity and the effect of potential catalysts differed markedly. Increasing the temperature and time led to increases in conversion but of different extents. Substituting H2 for N2 led to a large increase to conversion for the lower-atomic-H/C ratio marine oil shale. The \\{CH2Cl2\\} solubles from the marine oil shale showed a larger range of compounds than those from the lacustrine oil shale which resembled the \\{CH2Cl2\\} solubles from torbanite, a coal-like material derived from lacustrine algae.

Mohammad W. Amer; Marc Marshall; Yi Fei; W. Roy Jackson; Martin L. Gorbaty; Peter J. Cassidy; Alan L. Chaffee

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Offshore Sulfur Comes In  

Science Journals Connector (OSTI)

Offshore Sulfur Comes In ... "The deposit is a major new source of sulfur," say Hines H. Baker, president of Humble Oil, and Langbourne M. Williams, president of Freeport Sulphur. ... Humble's deposit, known as Grand Isle (Block 18), was discovered in the course of offshore oil exploration and it ranks among the most important sulfur discoveries of recent years. ...

1956-10-01T23:59:59.000Z

322

High-Temperature Air/Steam-Blown Gasification of Coal in a Pressurized Spout-Fluid Bed  

Science Journals Connector (OSTI)

7-10 However, in the MEET system a pebble bed slagging entrained-flow gasifier was used that had to be operated at very high temperatures (1350?1550 °C), which required excessive energy input to maintain such a high gasification temperature when compared with fluidized bed gasifiers, such as spout-fluid bed gasifiers which used medium temperatures (800?1100 °C) to convert coal to fuel gas. ... The typical size distribution is shown in Table 2, where is specific surface-equivalent diameter. ...

Rui Xiao; Mingyao Zhang; Baosheng Jin; Yaji Huang; Hongcang Zhou

2006-02-10T23:59:59.000Z

323

Coal Ranks and Geothermal Gradients in High-volatile Bituminous Coalfields  

Science Journals Connector (OSTI)

... 380; Sw. No., 6. If it is assumed that no great changes in geothermal gradient have occurred since the early Pleistocene, this coal was metamorphosed at a temperature ... Silesia5. The most obvious explanation is that of a nearly two to one difference in geothermal gradient. Comparison of data from the Carboniferous coalfields of the Netherlands with analyses of ...

R. P. SUGGATE; J. O. ELPHICK

1964-07-04T23:59:59.000Z

324

Next Generation Pressurized Oxy-Coal Combustion: High Efficiency and No Flue Gas Recirculation  

SciTech Connect (OSTI)

The Gas Technology Institute (GTI) has developed a pressurized oxy-coal fired molten bed boiler (MBB) concept, in which coal and oxygen are fired directly into a bed of molten coal slag through burners located on the bottom of the boiler and fired upward. Circulation of heat by the molten slag eliminates the need for a flue gas recirculation loop and provides excellent heat transfer to steam tubes in the boiler walls. Advantages of the MBB technology over other boilers include higher efficiency (from eliminating flue gas recirculation), a smaller and less expensive boiler, modular design leading to direct scalability, decreased fines carryover and handling costs, smaller exhaust duct size, and smaller emissions control equipment sizes. The objective of this project was to conduct techno-economic analyses and an engineering design of the MBB project and to support this work with thermodynamic analyses and oxy-coal burner testing. Techno-economic analyses of GTI’s pressurized oxy-coal fired MBB technology found that the overall plant with compressed CO2 has an efficiency of 31.6%. This is a significant increase over calculated 29.2% efficiency of first generation oxy-coal plants. Cost of electricity (COE) for the pressurized MBB supercritical steam power plant with CO2 capture and compression was calculated to be 134% of the COE for an air-coal supercritical steam power plant with no CO2 capture. This compares positively with a calculated COE for first generation oxy-coal supercritical steam power plants with CO2 capture and compression of 164%. The COE for the MBB power plant is found to meet the U.S. Department of Energy (DOE) target of 135%, before any plant optimization. The MBB power plant was also determined to be simpler than other oxy-coal power plants with a 17% lower capital cost. No other known combustion technology can produce higher efficiencies or lower COE when CO2 capture and compression are included. A thermodynamic enthalpy and exergy analysis found a number of modifications and adjustments that could provide higher efficiency and better use of available work. Conclusions from this analysis will help guide the analyses and CFD modeling in future process development. The MBB technology has the potential to be a disruptive technology that will enable coal combustion power plants to be built and operated in a cost effective way, cleanly with no carbon dioxide emissions. A large amount of work is needed to quantify and confirm the great promise of the MBB technology. A Phase 2 proposal was submitted to DOE and other sponsors to address the most critical MBB process technical gaps. The Phase 2 proposal was not accepted for current DOE support.

Rue, David

2013-09-30T23:59:59.000Z

325

Low severity coal liquefaction promoted by cyclic olefins  

SciTech Connect (OSTI)

Low severity coal liquefaction allows for solubilization of coal with reduced gas make. These lower severity conditions may result in some selective bond rupture. Promotion of coal solubilization through hydrogen transfer using highly active and effective hydrogen donors is the objective of this study. The highly effective donors being tested are cyclic olefins. Representative cyclic olefins are isotetralin, which is 1,4,5,8-tetrahydronaphthalene, and 1,4,5,8,9,10-hexahydroanthracene. These compounds are hydroaromatics without aromatic rings and have been shown to be highly effective donors. The objective of the work performed in this study during this quarter was to evaluate reaction parameters for low severity liquefaction reactions using the cyclic olefin, hexahydroanthracene, and the aromatic, anthracene. These model compounds were reacted under a variety of conditions to evaluate their reactivity without coal. The reactions were performed under both thermal and catalytic conditions. Finely divided catalysts from different molybdenum precursors were used to determine their activity in promoting hydrogenation and hydrogen transfer at low severity conditions. The catalysts used were Molyvan L, sulfurized oxymolybdenum dithiocarbamate, molybdenum naphthenate, and Molyvan 822, organo molybdenum dithiocarbamate.

Curtis, C.W.

1992-07-27T23:59:59.000Z

326

Investigation of the effects of various water mediums on desulfurization and deashing of a coal sample by flotation  

SciTech Connect (OSTI)

The aim of this study was to investigate the effects of various water mediums on desulfurization and deashing of a coal sample using flotation. For this purpose, experimental studies were conducted on a coal sample containing high ash and sulfur contents. The effects of pH, solid concentration, collector amount and frother amount on the flotation were investigated separately in Mediterranean Sea water, Cermik thermal spring water, snow water and tap water. Flotation, results indicated that, when comparing the various water mediums, the following order for the ash content was obtained: snow water < Cermik thermal spring water < tap water < the Mediterranean Sea water. For the reduction of total sulfur, the following order was obtained: snow water > Cermik thermal spring water > Mediterranean Sea water > tap water. When snow water was used as a flotation medium, it was found that a concentrate containing 3.01% total sulfur and 27.64% ash with a total sulfur reduction of 57.06% was obtained from a feed containing 7.01% total sulfur and 4.1.17% ash.

Ayhan, F.D. [Dicle University, Diyarbakir (Turkey)

2009-08-15T23:59:59.000Z

327

Assessment of the impacts on health due to the emissions of Cuban power plants that use fossil fuel oils with high content of sulfur. Estimation of external costs  

Science Journals Connector (OSTI)

Fossil fuel electricity generation has been demonstrated to be a main source of atmospheric pollution. The necessity of finding out a balance between the costs of achieving a lower level of environmental and health injury and the benefits of providing electricity at a reasonable cost have lead to the process of estimating the external costs derived from these impacts and not included in the electricity prices as a quantitative measure of it that, even when there are large uncertainties involved, can be used by decision makers in the process of achieving a global sustainable development. The external costs of the electricity generation in three Cuban power plants that use fossil fuel oils with high sulfur content have been assessed. With that purpose a specific implementation of the Impact Pathways Methodology for atmospheric emissions was developed. Dispersion of atmospheric pollutants is modeled at local and regional scales in a detailed way. Health impacts include mortality and those morbidity effects that showed relation with the increment of selected pollutant concentration in national studies. The external cost assessed for the three plants was 40,588,309 USD yr?1 (min./max.: 10,194,833/169,013,252), representing 1.06 USD Cent kWh?1. Costs derived from sulfur species (SO2 and sulfate aerosol) stand for 93% of the total costs.

L. Turtós Carbonell; E. Meneses Ruiz; M. Sánchez Gácita; J. Rivero Oliva; N. Díaz Rivero

2007-01-01T23:59:59.000Z

328

Quantitative Determination of Aliphatic Sulfur-Containing Additives by Pyrolysis-Gas Chromatography  

Science Journals Connector (OSTI)

......pyrolysis (7), infrared (8), combustion to SO4 = with subsequent determination...Drushel. The Analytical Chemistry of Sulfur and Its Compounds...London, p. 358. Sulfur in Coal and Coke by the Bomb Washing...organic materials by oxygen bomb combustion. Anal. Chem. 33:1760......

J.W. Sinclair; L. Schall; N.T. Crabb

1980-01-01T23:59:59.000Z

329

Problems of Expanding Coal Production  

Science Journals Connector (OSTI)

...metallurgical or coking coal marketed widely here and abroad. Appalachian coal generally has a high...are characteristic of Appalachia, al-though there has also been extensive strip mining including destructive...Mid-western bituminous coal has a large market as...

John Walsh

1974-04-19T23:59:59.000Z

330

Alaska coal geology, resources, and coalbed methane potential  

SciTech Connect (OSTI)

Estimated Alaska coal resources are largely in Cretaceous and Tertiary rocks distributed in three major provinces, Northern Alaska-Slope, Central Alaska-Nenana, and Southern Alaska-Cook Inlet. Cretaceous resources, predominantly bituminous coal and lignite, are in the Northern Alaska-Slope coal province. Most of the Tertiary resources, mainly lignite to subbituminous coal with minor amounts of bituminous and semianthracite coals, are in the other two provinces. The combined measured, indicated, inferred, and hypothetical coal resources in the three areas are estimated to be 5,526 billion short tons (5,012 billion metric tons), which constitutes about 87 percent of Alaska's coal and surpasses the total coal resources of the conterminous United States by 40 percent. Coal mining has been intermittent in the Central Alaskan-Nenana and Southern Alaska-Cook Inlet coal provinces, with only a small fraction of the identified coal resource having been produced from some dozen underground and strip mines. Alaskan coals have a lower sulfur content (averaging 0.3 percent) than most coals in the conterminous United States and are within or below the minimum sulfur value mandated by the 1990 Clean Air Act amendments. Another untapped potential resource is coalbed methane estimated to total 1,000 trillion cubic feet (28 trillion cubic meters).

Romeo M. Flores; Gary D. Stricker; Scott A. Kinney

2005-11-15T23:59:59.000Z

331

Computational Fluid Dynamics (CFD) Modeling for High Rate Pulverized Coal Injection (PCI) into the Blast Furnace  

SciTech Connect (OSTI)

Pulverized coal injection (PCI) into the blast furnace (BF) has been recognized as an effective way to decrease the coke and total energy consumption along with minimization of environmental impacts. However, increasing the amount of coal injected into the BF is currently limited by the lack of knowledge of some issues related to the process. It is therefore important to understand the complex physical and chemical phenomena in the PCI process. Due to the difficulty in attaining trus BF measurements, Computational fluid dynamics (CFD) modeling has been identified as a useful technology to provide such knowledge. CFD simulation is powerful for providing detailed information on flow properties and performing parametric studies for process design and optimization. In this project, comprehensive 3-D CFD models have been developed to simulate the PCI process under actual furnace conditions. These models provide raceway size and flow property distributions. The results have provided guidance for optimizing the PCI process.

Dr. Chenn Zhou

2008-10-15T23:59:59.000Z

332

Sulfur behavior in the Sasol-Lurgi fixed-bed dry-bottom gasification process  

SciTech Connect (OSTI)

This article reports on the findings of a study regarding the sulfur behavior across a Sasol-Lurgi gasifier. This was undertaken to understand the behavior of the various sulfur-bearing components in the coal, as they are exposed to the conditions in the gasifier. In this study, conventional characterization techniques were employed to monitor the behavior of sulfur-bearing mineral matter across the gasifier. It was observed from the study that the sulfur-bearing mineral (pyrite) in the coal structure undergoes various changes with pyrite being transformed to pyrrhotite and then to various oxides of iron with the subsequent loss of sulfur to form H{sub 2}S. A low proportion of the sulfur species including the organically associated sulfur was encapsulated by a melt that was formed by the interaction between kaolinite and fluxing minerals (pyrite, calcite, and dolomite/ankerite) present in the coal at elevated temperatures and pressure, thereby ending up in the ash. The remaining small proportions of sulfur-bearing mineral matter including pyrite and organically bound sulfur in the unburned carbon in the carbonaceous shales also report to the ash. 18 refs., 8 figs., 2 tabs.

M. Pat Skhonde; R. Henry Matjie; J. Reginald Bunt; A. Christien Strydom; H. Schobert [Sasol Technology R& amp; D, Sasolburg (South Africa)

2009-01-15T23:59:59.000Z

333

Determination of the effects caused by different polymers on coal fluidity during carbonization using high-temperature {sup 1}H NMR and rheometry  

SciTech Connect (OSTI)

The effects of blending polyethylene (PE), polystyrene (PS), poly(ethyleneterephthalate) (PET), a flexible polyurethane (FPU), and a car shredded fluff waste (CSF) on fluidity development of a bituminous coal during carbonization have been studied by means of high-torque, small-amplitude controlled-strain rheometry and in situ high-temperature {sup 1}H NMR spectroscopy. The most detrimental effects were caused by PET and PS, which completely destroyed the fluidity of the coal. The CSF had a deleterious effect on coal fluidity similar to that of PET, although the deleterious effect on the viscoelastic properties of the coal were less pronounced than those of PET and PS. On the contrary, the addition of 10 wt % PE caused a slight reduction in the concentration of fluid hydrogen and an increase in the minimum complex viscosity, and the addition of 10 wt % FPU reduced the concentration of fluid hydrogen without changing the viscoelastic properties of the coal. Although these results suggest that these two plastics could potentially be used as additives in coking blends without compromising coke porosity, it was found that the semicoke strengths were reduced by adding 2 wt % FPU and 5 wt % PE. Therefore, it is unlikely that more than 2 wt % of a plastic waste could be added to a coal blend without deterioration in coke quality. 35 refs., 11 figs., 3 tabs.

Miguel Castro Diaz; Lucky Edecki; Karen M. Steel; John W. Patrick; Colin E. Snape [Nottingham University, Nottingham (United Kingdom). Nottingham Fuel and Energy Centre, School of Chemical, Environmental and Mining Engineering

2008-01-15T23:59:59.000Z

334

Evaluation of sulfur-reducing microorganisms for organic desulfurization. Final technical report, September 1, 1990--August 31, 1991  

SciTech Connect (OSTI)

Because of substantial portion of the sulfur in Illinois coal is organic, microbial desulfurization of sulfidic and thiophenic functionalities could hold great potential for completing pyritic sulfur removal. We are testing the hypothesis that organic sulfur can be reductively removed as H{sub 2}S through the activities of anaerobic microorganisms. Our objectives for this year include the following: (1) To obtain cultures that will reductively desulfurize thiophenic model compounds. In addition to crude oil enrichments begun last year, we sampled municipal sewage sludge. (2) To continue to work toward optimizing the activity of the DBDS-reducing cultures obtained during the previous year. (3) To expand coal desulfurization work to include other coals including Illinois Basin Coal 101 and a North Dakota lignite, which might be more susceptible to the dibenzyldisulfide reducing cultures due to its lower rank. (4) To address the problem of sulfide sorption, by investigating the sorption capacity of coals in addition to Illinois Basin Coal 108.

Miller, K.W.

1991-12-31T23:59:59.000Z

335

The production of high surface carbons from coal using pre-swelling in solvents to disperse coking catalysts  

Science Journals Connector (OSTI)

Carbons have been produced from Amaga coal using ZnCl2 as a catalyst to increase carbon yields during pyrolysis. It was found that the surface area and micropore volume could be increased by swelling the coal ...

F MONDRAGON; G QUINTERO; A JARAMILLO; J FERNANDEZ…

336

EIA - The National Energy Modeling System: An Overview 2003-Coal Market  

Gasoline and Diesel Fuel Update (EIA)

Coal Market Module Coal Market Module The National Energy Modeling System: An Overview 2003 Coal Market Module Figure 19. Coal Market Module Demand Regions. Need help, contact the National Energy Information Center at 202-586-8800. Figure 20. Coal Market Module Supply Regions. Need help, contact the National Energy Information Center at 202-586-8800. Figure 21. Coal Market Module Structure. Need help, contact the National Energy Information Center at 202-586-8800. Coal Market Module Table. Need help, contact the National Energy Information Center at 202-586-8800. The coal market module (CMM) represents the mining, transportation, and pricing of coal, subject to end–use demand. Coal supplies are differentiated by heat and sulfur content. CMM also determines the minimum cost pattern of coal supply to meet exogenously defined U.S. coal

337

Pilot-scale study of the effect of selective catalytic reduction catalyst on mercury speciation in Illinois and Powder River Basin coal combustion flue gases  

SciTech Connect (OSTI)

A study was conducted to investigate the effect of selective catalytic reduction (SCR) catalyst on mercury (Hg) speciation in bituminous and subbituminous coal combustion flue gases. Three different Illinois Basin bituminous coals (from high to low sulfur (S) and chlorine (Cl)) and one Powder River Basin (PRB) subbituminous coal with very low S and very low Cl were tested in a pilot-scale combustor equipped with an SCR reactor for controlling nitrogen oxides (NO{sub x}) emissions. The SCR catalyst induced high oxidation of elemental Hg (Hg{sup 0}), decreasing the percentage of Hg{sup 0} at the outlet of the SCR to values <12% for the three Illinois coal tests. The PRB coal test indicated a low oxidation of Hg{sup 0} by the SCR catalyst, with the percentage of Hg{sup 0} decreasing from {approximately} 96% at the inlet of the reactor to {approximately} 80% at the outlet. The low Cl content of the PRB coal and corresponding low level of available flue gas Cl species were believed to be responsible for low SCR Hg oxidation for this coal type. The test results indicated a strong effect of coal type on the extent of Hg oxidation. 16 refs., 4 figs., 3 tabs.

Lee, C.W.; Srivastava, R.K.; Ghorishi, S.B.; Karwowski, J.; Hastings, T.H.; Hirschi, J.C. [US Environmental Protection Agency, Triangle Park, NC (United States)

2006-05-15T23:59:59.000Z

338

Coal pump  

DOE Patents [OSTI]

A device for pressurizing pulverized coal and circulating a carrier gas is disclosed. This device has utility in a coal gasification process and eliminates the need for a separate collection hopper and eliminates the separate compressor.

Bonin, John H. (Sunnyvale, CA); Meyer, John W. (Palo Alto, CA); Daniel, Jr., Arnold D. (Alameda County, CA)

1983-01-01T23:59:59.000Z

339

3 - High temperature materials issues in the design and operation of coal-fired steam turbines and plant  

Science Journals Connector (OSTI)

Abstract: The basic design of steam plant is outlined, and it is emphasised how the increase in steam temperatures has required high steam pressures. High efficiency requires the use of feedheating, and reheating operation at high pressure and temperature has implications for superheaters. Critical issues are creep strength, resistance to fireside attack and oxide spallation from steam side surfaces. Coal-fired plant is increasingly required to operate in a two shift manner and to compensate for the effects of the intermittency of wind energy; the implications are summarised. Operation at steam temperatures in excess of 600 °C will require the use of even stronger austenitics. In 700 °C plants, precipitation-hardened nickel-based alloys will be required for superheaters.

F. Starr

2014-01-01T23:59:59.000Z

340

Sulfur Tolerant Pd/Cu and Pd/Au Alloy Membranes for H2 Separation with High Pressure CO2 for Sequestration  

SciTech Connect (OSTI)

The effect of H{sub 2}S poisoning on Pd, Pd/Cu, and Pd/Au alloy composite membranes prepared by the electroless deposition method on porous Inconel supports was investigated to provide a fundamental understanding of the durability and preparation of sulfur tolerant membranes. X-ray photoelectron spectroscopy (XPS) studies showed that the exposure of pure Pd to 50 ppm H{sub 2}S/H{sub 2} mixtures caused bulk sulfide formation at lower temperatures and surface sulfide formation at higher temperatures. Lower temperatures, longer exposure times, and higher H{sub 2}S concentrations resulted in a higher degree of sulfidation. In a Pd membrane, the bulk sulfide formation caused a drastic irrecoverable H{sub 2} permeance decline and an irreparable loss in selectivity. Pd/Cu and Pd/Au alloy membranes exhibited permeance declines due to surface sulfide formation upon exposure to 50 ppm H{sub 2}S/H{sub 2} gas mixtures. However in contrast to the pure Pd membrane, the permeances of the Pd/Cu and Pd/Au alloy membranes were mostly recovered in pure H{sub 2} and the selectivity of the Pd alloy layers remained essentially intact throughout the characterization in H{sub 2}, He and H{sub 2}S/H{sub 2} mixtures which lasted several thousand hours. The amount of irreversible sulfur poisoning decreased with increasing temperature due to the exothermicity of H{sub 2}S adsorption. Longer exposure times increased the amount of irreversible poisoning of the Pd/Cu membrane but not the Pd/Au membrane. Pd/Au coupon studies of the galvanic displacement method showed that higher Au{sup 3+} concentrations, lower pH values, higher bath temperatures and stirring the bath at a rate of 200 rpm yielded faster displacement rates, more uniform depositions, and a higher Au content within the layers. While 400 C was found to be sufficient to form a Pd/Au alloy on the surface, high temperature X-ray diffraction (HTXRD) studies showed that even after annealing between 500-600 C, the Pd/Cu alloys could have part or all of the surface in the less sulfur resistant {beta} phase.

Yi Hua Ma; Natalie Pomerantz; Chao-Huang Chen

2008-09-30T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Controlling mercury emissions from coal-fired power plants  

SciTech Connect (OSTI)

Increasingly stringent US federal and state limits on mercury emissions form coal-fired power plants demand optimal mercury control technologies. This article summarises the successful removal of mercury emissions achieved with activated carbon injection and boiler bromide addition, technologies nearing commercial readiness, as well as several novel control concepts currently under development. It also discusses some of the issues standing in the way of confident performance and cost predictions. In testing conducted on western coal-fired units with fabric filters or TOXECON to date, ACI has generally achieved mercury removal rates > 90%. At units with ESPs, similar performance requires brominated ACI. Alternatively, units firing western coals can use boiler bromide addition to increase flue gas mercury oxidation and downstream capture in a wet scrubber, or to enhance mercury removal by ACI. At eastern bituminous fired units with ESPs, ACI is not as effective, largely due to SO{sub 3} resulting from the high sulfur content of the coal or the use of SO{sub 3} flue gas conditioning to improve ESP performance. 7 refs., 3 figs.

Chang, R. [Electric Power Research Institute, Palo Alto, CA (United States)

2009-07-15T23:59:59.000Z

342

Optimization of regimes for the feed of highly concentrated culm-anthracite coal dust for burning in a TPP-210A boiler  

SciTech Connect (OSTI)

Results are presented for regime adjustment of feed systems for a TPP-210A boiler for the burning of highly concentrated culm-anthracite coal dust. As compared with nonoptimal regimes, optimal regimes of high-concentration-feed systems improve the economy of the boiler by 1.7% on average.

L.V. Golyshev; G.A. Dovgoteles [JSC 'L'vovORGRES', L'vov (Ukraine)

2007-05-15T23:59:59.000Z

343

Section 5 - Coal  

Science Journals Connector (OSTI)

Coal has the longest history of use among the fossil fuels, with use as a fuel dating to 3000 BC in China and Wales. Marco Polo’s “Description of the World” (1298) comments on many novel customs and practices of China, including the use of “stones that burn like logs” (coal). By the thirteenth century the mining of coal was widespread in England in regions such as Durham, Nottinghamshire, Derbyshire, Staffordshire, and North and South Wales. By the early seventeenth century nearly half of England’s maritime trade consisted of coal exports. Coal was the fuel that launched the Industrial Revolution in Europe and then the United States. By the late 1890s, the U.S. assumed the lead in world coal production. Britain now ranked second, after having been the world leader since the beginnings of the formal industry in the 1500s. Germany was third, an indication of its growing industrial power relative to continental rival France. Coal’s leading role in energy use peaked in the early twentieth century, after which it was supplanted by oil and natural gas. By the late twentieth century China’s rapid economic expansion, surging demand for electricity, and prodigious coal resources combined to propel it to become the world leader in production. Continuous improvements in coal mining technology have produced lower costs, improved safety, and greater labor productivity. John Buddle introduced the first air pump to ventilate coal mines (1803), followed shortly by the miner’s safety lamps that were developed independently by Sir Humphry Davy, William Clanny, and George Stephenson (1813-1816). Coal mining underwent a rapid transition in the 1880s to mechanical coal cutting in mines in the United Kingdom, the United States, and Russia. The St. Joseph Lead Company of Missouri (1900) invented the first underground mine roof bolts that became a key safety feature in underground coal mines. The first commercially successful bucket wheel excavator was used at the Luise Mine in Braunkohlemwerke, Germany (1925), followed by the first successful continuous miners in U.S. underground coal mining (1948). The first mechanized U.S. longwall mining system appeared in 1951, and was followed by the self-advancing hydraulic longwall support system that provided greater support for the roof of the mine. LeTourneau Technologies, Inc. of Texas manufactured the largest rubber tired front-end wheel loader in the world, the L-2350, which would play an important role in loading coal in Wyoming’s large surface mines (2005). Coal mining has always been a very hazardous occupation, and has produced some of history’s worst industrial disasters. The Courrières mine disaster, Europe's worst mining accident, caused the death of 1,099 miners in Northern France (1906). An explosion in a coal mine in Liaoning province in northeastern China killed more than 1,500 Chinese miners (1942), as did other major accidents in Ky?sh?, Japan (1914), Wankie, Rhodesia (1972), Wales (1913), Bihar, India (1965), and West Virginia, U.S. (1907), to name just a few. Legislation such as the Federal Coal Mine Health and Safety Act in the U.S. (1969) improved working conditions in many nations. The Great Smog of London (1952) occurred after an exceptionally cold winter forced homes and factories to burn large quantities of coal. A temperature inversion formed, trapping pollutants above the ground. More than 4,000 people died from respiratory ailments within the following week. The use of coal has been impacted by legislation to control the environmental impacts associated with its mining and combustion. The first known environmental regulation of coal dates to 1306 when King Edward II of England prohibited burning sea coal while Parliament was in session because of its offensive smoke. Sulfur dioxide from coal combustion was tied to acid rain in the 1960s, and carbon dioxide emissions became a concern beginning in the 1980s when climate change emerged as a critical environmental issue.

Cutler J. Cleveland; Christopher Morris

2014-01-01T23:59:59.000Z

344

Low Temperature Sorbents for removal of Sulfur Compounds from fluid feed Streams  

SciTech Connect (OSTI)

A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

Siriwardane, Ranjan

1999-09-30T23:59:59.000Z

345

Low Temperature Sorbents for Removal of Sulfur Compounds from Fluid Feed Streams  

DOE Patents [OSTI]

A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

Siriwardane, Ranjani

2004-06-01T23:59:59.000Z

346

Sulfur@Carbon Cathodes for Lithium Sulfur Batteries > Research...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electrode Channel Flow DEMS Cell Sulfur@Carbon Cathodes for Lithium Sulfur Batteries Better Ham & Cheese: Enhanced Anodes and Cathodes for Fuel Cells Epitaxial Single...

347

Sulfur-Graphene Oxide Nanocomposite Cathodes for Lithium/Sulfur...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Advanced Materials Advanced Materials Find More Like This Return to Search Sulfur-Graphene Oxide Nanocomposite Cathodes for LithiumSulfur Cells Lawrence Berkeley National...

348

Production of High Purity Hydrogen from Domestic Coal: Assessing the Techno-Economic Impact of Emerging Technologies  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Production of High Purity Production of High Purity Hydrogen from Domestic Coal: Assessing the Techno-Economic Impact of Emerging Technologies August 30, 2010 DOE/NETL-2010/1432 Disclaimer This report was prepared as an account of work sponsored by an agency of the United States (U.S.) government. Neither the U.S., nor any agency thereof, nor any of their employees, nor any of their contractors, subcontractors, or their employees makes any warranty, expressed or implied, or assumes any legal liability or responsibility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily

349

Catalyst for elemental sulfur recovery process  

DOE Patents [OSTI]

A catalytic reduction process is described for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(FO[sub 2])[sub 1[minus]n](RO)[sub n

Flytzani-Stephanopoulos, M.; Liu, W.

1995-01-24T23:59:59.000Z

350

IN THIS ISSUE Clean Coal Efforts  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Clean Coal Efforts Clean Coal Efforts ......................... 1 News Bytes ................................... 1 Virtual Energy Plants .................... 3 Sulfur Removal Efforts ................ 4 Environmental Benefits Topical ... 6 R&D Milestones ........................... 6 Hydrogen Program Activities ........ 7 Gasification Workshop ................. 8 Sensors and Controls Workshop ... 9 Upcoming Events ........................ 10 International Initiatives ............... 11 Status of CCT Projects ................ 14 A NEWSLETTER ABOUT INNOVATIVE TECHNOLOGIES FOR COAL UTILIZATION NEWS BYTES OFFICE OF FOSSIL ENERGY, U.S. DEPARTMENT OF ENERGY * DOE/FE-0215P-45 ISSUE NO. 45, SUMMER 2001 See "News Bytes" on page 2 ... The Port Authority of Port Arthur, Texas and Sabine Power I Ltd have

351

Advanced byproduct recovery: Direct catalytic reduction of SO{sub 2} to elemental sulfur. First quarterly technical progress report, [October--December 1995  

SciTech Connect (OSTI)

The team of Arthur D. Little, Tufts University and Engelhard Corporation will be conducting Phase I of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. this catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria or zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an ongoing DOE-sponsored University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicates that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. the performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams.

Benedek, K. [Little (Arthur D.), Inc., Cambridge, MA (United States); Flytzani-Stephanopoulos, M. [Tufts Univ., Medford, MA (United States)

1996-02-01T23:59:59.000Z

352

Phase-equilibria for design of coal-gasification processes: dew points of hot gases containing condensible tars. Final report  

SciTech Connect (OSTI)

This research is concerned with the fundamental physical chemistry and thermodynamics of condensation of tars (dew points) from the vapor phase at advanced temperatures and pressures. Fundamental quantitative understanding of dew points is important for rational design of heat exchangers to recover sensible heat from hot, tar-containing gases that are produced in coal gasification. This report includes essentially six contributions toward establishing the desired understanding: (1) Characterization of Coal Tars for Dew-Point Calculations; (2) Fugacity Coefficients for Dew-Point Calculations in Coal-Gasification Process Design; (3) Vapor Pressures of High-Molecular-Weight Hydrocarbons; (4) Estimation of Vapor Pressures of High-Boiling Fractions in Liquefied Fossil Fuels Containing Heteroatoms Nitrogen or Sulfur; and (5) Vapor Pressures of Heavy Liquid Hydrocarbons by a Group-Contribution Method.

Prausnitz, J.M.

1980-05-01T23:59:59.000Z

353

Sulfide catalysts for reducing SO2 to elemental sulfur  

DOE Patents [OSTI]

A highly efficient sulfide catalyst for reducing sulfur dioxide to elemental sulfur, which maximizes the selectivity of elemental sulfur over byproducts and has a high conversion efficiency. Various feed stream contaminants, such as water vapor are well tolerated. Additionally, hydrogen, carbon monoxide, or hydrogen sulfides can be employed as the reducing gases while maintaining high conversion efficiency. This allows a much wider range of uses and higher level of feed stream contaminants than prior art catalysts.

Jin, Yun (Peking, CN); Yu, Qiquan (Peking, CN); Chang, Shih-Ger (El Cerrito, CA)

2001-01-01T23:59:59.000Z

354

Chapter 11 - Sulfur Recovery  

Science Journals Connector (OSTI)

Abstract Sulfur is present in many raw industrial gases and in natural gas in the form of hydrogen sulfide. Sulfur removal facilities are located at the majority of oil and gas processing facilities throughout the world. The sulfur recovery unit does not make a profit for the operator but it is an essential processing step to allow the overall facility to operate, as the discharge of sulfur compounds to the atmosphere is severely restricted by environmental regulations. Concentration levels of H2S vary significantly depending upon their source. H2S produced from absorption processes, such as amine treating of natural gas or refinery gas, can contain 50–75% H2S by volume or higher. This chapter provides information about fundamentals of sulfur removal facilities in the natural gas industry.

Alireza Bahadori

2014-01-01T23:59:59.000Z

355

INTERACTION OF ORGANIC SOLVENTS WITH A SUBBITUMINOUS COAL BELOW PYROLYSIS TEMPERATURE  

E-Print Network [OSTI]

and P. Fugassi, Phenanthrene Extraction of Bituminous Coal,Coal Science, Advances in Chemistry Series No. 55, 448 C.Mechanism of High Volatile Coal, Coal Science, Advances in

Dorighi, G.P.

2010-01-01T23:59:59.000Z

356

Assumptions to the Annual Energy Outlook - Coal Market Module  

Gasoline and Diesel Fuel Update (EIA)

Coal Market Module Coal Market Module Assumption to the Annual Energy Outlook Coal Market Module The NEMS Coal Market Module (CMM) provides forecasts of U.S. coal production, consumption, exports, imports, distribution, and prices. The CMM comprises three functional areas: coal production, coal distribution, and coal exports. A detailed description of the CMM is provided in the EIA publication, Coal Market Module of the National Energy Modeling System 2004, DOE/EIA-M060(2004) (Washington, DC, 2004). Key Assumptions Coal Production The coal production submodule of the CMM generates a different set of supply curves for the CMM for each year of the forecast. Separate supply curves are developed for each of 11 supply regions and 12 coal types (unique combinations of thermal grade, sulfur content, and mine type). The modeling approach used to construct regional coal supply curves addresses the relationship between the minemouth price of coal and corresponding levels of capacity utilization of mines, mining capacity, labor productivity, and the cost of factor inputs (mining equipment, mine labor, and fuel requirements).

357

Formation and retention of methane in coal  

SciTech Connect (OSTI)

The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

Hucka, V.J.; Bodily, D.M.; Huang, H.

1992-05-15T23:59:59.000Z

358

Improvement of the Coal Ash Slagging Tendency by Coal Washing and Additive Blending with Mullite Generation  

Science Journals Connector (OSTI)

Four typical coals and two pretreatment methods were investigated to prevent slagging by facilitating mullite formation in coal ash at a high temperature. ... Both security and economy in power plant can be improved substantially as long as ash deposition and slagging tendency alleviated. ... Pilot-projects about coal washing and coal blending economic benefit are looking forward to put into practice. ...

Zhenyu Huang; Yan Li; Dan Lu; Zhijun Zhou; Zhihua Wang; Junhu Zhou; Kefa Cen

2013-03-11T23:59:59.000Z

359

Improved Fischer-Tropsch catalysts for indirect coal liquefaction  

SciTech Connect (OSTI)

The Fischer-Tropsch synthesis (FTS)reaction is the established technology for the production of liquid fuels from coal by an indirect route using coal-derived syngas (CO + H{sub 2}). Modern FTS catalysts are potassium- and copper-promoted iron preparations. These catalysts exhibit moderate activity with carbon monoxide-rich feedstocks such as the syngas produced by advanced coal gasification processes. However, the relatively large yields of by-product methane and high-molecular-weight hydrocarbon waxes detract from the production of desired liquid products in the C{sub 5}-C{sub 16} range needed for motor and aviation fuel. The goal of this program is to decrease undesirable portions of the FTS hydrocarbon yield by altering the Schultz-Flory polymerization product distribution through design and formulation of improved catalysts. Two approaches were taken: (1) reducing the yield of high-molecular-weight hydrocarbon waxes by using highly dispersed catalysts produced from surface-confined multiatomic clusters on acid supports and (2) suppressing methane production by uniformly pretreating active, selective conventional FTS catalysts with submonolayer levels of sulfur.

Wilson, R.B. Jr.; Tong, G.T.; Chan, Y.W.; Huang, H.W.; McCarty, J.G.

1989-02-01T23:59:59.000Z

360

Bacterial Sulfur Storage Globules  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

by I. J. Pickering and G. N. George by I. J. Pickering and G. N. George Sulfur is essential for all life, but it plays a particularly central role in the metabolism of many anaerobic microorganisms. Prominent among these are the sulfide-oxidizing bacteria that oxidize sulfide (S2-) to sulfate (SO42-). Many of these organisms can store elemental sulfur (S0) in "globules" for use when food is in short supply (Fig. 1). The chemical nature of the sulfur in these globules has been an enigma since they were first described as far back as 1887 (1); all known forms (or allotropes) of elemental sulfur are solid at room temperature, but globule sulfur has been described as "liquid", and it apparently has a low density – 1.3 compared to 2.1 for the common yellow allotrope a-sulfur. Various exotic forms of sulfur have been proposed to explain these properties, including micelles (small bubble-like structures) formed from long-chain polythionates, but all of these deductions have been based upon indirect evidence (for example the density was estimated by flotation of intact cells), and many questions remained.

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
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361

Characterization of fly ashes from circulating fluidized bed combustion (CFBC) boilers cofiring coal and petroleum coke  

SciTech Connect (OSTI)

The chemistry, mineralogy, morphology, and particle size distribution were investigated in fly ashes from the burning of Datong (ShanXi, China) bituminous coal and the cofiring of Mideast high-sulfur petroleum coke (PC) with 30:70 (cal %) and 50:50 (cal %) blends of Datong bituminous coal in two commercial CFBC boilers. With the exception of CaO, the amounts of major oxides in the fly ashes from cofiring PC and coal were close to those of the common coal fly ashes. The PC-coal fly ashes were enriched in Ni, V, and Mo, implying these trace elements were mainly derived from PC. Ni and V, along with several other elements, such as Cr, Cu, Se, Pb, U, Th, and possibly As and Cd, increased in content with a decrease in temperature of the electrostatic precipitator (ESP). The results of chemistry, mineralogy, and morphology studies suggested that the desulfurization rate of the CFBC boilers at current conditions was low, and the PC tends to coarsen the fly ash particles and increase the loss on ignition (LOI) values, making these fly ashes unsuitable for use as a cement additive or a mineral admixture in concrete. Further studies on the combustion status of the CFBC boilers are needed if we want to be able to increase the desulfurization rate and produce high-quality fly ashes for broader and full utilization. 22 refs., 4 figs., 4 tabs.

Feihu Li; Jianping Zhai; Xiaoru Fu; Guanghong Sheng [Nanjing University, Nanjing (China). State Key Laboratory of Pollution Control & Resource Reuse, School of the Environment

2006-08-15T23:59:59.000Z

362

Coal-fired high performance power generating system. Quarterly progress report, October 1, 1994--December 31, 1994  

SciTech Connect (OSTI)

This report covers work carried out under Task 3, Preliminary R and D, under contract DE-AC22-92PC91155, {open_quotes}Engineering Development of a Coal-Fired High Performance Power Generation System{close_quotes} between DOE Pittsburgh Energy Technology Center and United Technologies Research Center. The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) by the year 2000 that is capable of (1) > 47% thermal efficiency; (2) NO{sub x}, SO{sub x} and particulates {<=}25% NSPS; (3) cost {>=}65% of heat input; (4) all solid wastes benign. In our design consideration, we have tried to render all waste streams benign and if possible convert them to a commercial product. It appears that vitrified slag has commercial values. If the flyash is reinjected through the furnace, along with the dry bottom ash, then the amount of the less valuable solid waste stream (ash) can be minimized. A limitation on this procedure arises if it results in the buildup of toxic metal concentrations in either the slag, the flyash or other APCD components. We have assembled analytical tools to describe the progress of specific toxic metals in our system. The outline of the analytical procedure is presented in the first section of this report. The strengths and corrosion resistance of five candidate refractories have been studied in this quarter. Some of the results are presented and compared for selected preparation conditions (mixing, drying time and drying temperatures). A 100 hour pilot-scale stagging combustor test of the prototype radiant panel is being planned. Several potential refractory brick materials are under review and five will be selected for the first 100 hour test. The design of the prototype panel is presented along with some of the test requirements.

NONE

1995-08-01T23:59:59.000Z

363

Forward and reverse combustion gasification of coal with production of high-quality syngas in a simulated pilot system for in situ gasification  

Science Journals Connector (OSTI)

Abstract This research focused on the feasibility and stability of applying the forward and reverse combustion approach to the in situ gasification of lignite and bituminous coal with oxygen or oxygen–steam mixtures as gasification agents, especially reverse combustion gasification. A high-quality syngas (H2 and CO) could be obtained using the reverse combustion gasification technique combined with forward combustion gasification in a pilot system for in situ gasification. The gasification time was extended more than 25% using the reverse combustion approach. The controlling conditions for reverse combustion gasification were obtained by comparing and analyzing experimental data. The results show the relationship between the inject gas flow within certain limits and velocity of the gasification flame was linear during reverse combustion. The underground conditions of the coal seam and strata were simulated in a pilot-scale underground gasifier during experiments. The combustion gasification of coal was carried out experimentally for over 5 days. The average effective content (H2 and CO) of syngas was in the range of 60–70%, meeting the requirement of synthesis gas. The optimal ranges of gasifying lignite and bituminous coal were found to be 1.5–2.0 and 1.3–1.75, respectively. The product gas flow was proportional to oxygen blast. These are expected to provide useful guidance on practical underground coal gasification operations and to give experimental evidence in support of theory.

Yong Cui; Jie Liang; Zhangqing Wang; Xiaochun Zhang; Chenzi Fan; Dongyu Liang; Xuan Wang

2014-01-01T23:59:59.000Z

364

Steam reforming utilizing sulfur tolerant catalyst  

SciTech Connect (OSTI)

This patent describes a steam reforming process for converting hydrocarbon material to hydrogen gas in the presence of sulfur which consists of: adding steam to the hydrocarbon material and passing the steam and hydrocarbon material over catalyst material at elevated temperatures. The improvement comprises utilizing as a catalyst material high activity, sulfur tolerant catalyst of platinum supported on lanthanum stabilized alumina or magnesium promoted lanthanum stabilized alumina. It also describes a steam process for converting hydrocarbon material to hydrogen gas in the presence of sulfur which consists of steam to the hydrocarbon material over catalyst material at elevated temperatures. The improvement comprises utilizing as a catalyst material high activity, sulfur tolerant catalysts consisting essentially of iridium supported on lanthanum stabilized alumina or magnesium promoted lanthanum stabilized alumina. In addition a steam reforming process is described for converting hydrocarbon material to hydrogen gas in the presence of sulfur comprising adding steam to the hydrocarbon material and passing the steam and hydrocarbon material over catalyst material at elevated temperatures. The improvement comprises utilizing as a catalyst material high activity sulfur tolerant catalysts consisting essentially of palladium supported on lanthanum stabilized alumina or magnesium promoted lanthanum stabilized alumina.

Setzer, H.J.; Karavolis, S.; Bett, J.A.S.

1987-09-15T23:59:59.000Z

365

Development of a coal cleaning control system  

SciTech Connect (OSTI)

The US Department of Energy selected the Battelle-Electric Power Research Institute-Science Applications International Corporation team to evaluate and develop on-line slurry ash, percent solids, and sulfur analysis instrumentation and process control technology. The project's objectives were (1) to develop an accurate, versatile, easy to use, on-line coal slurry analyzer and (2) to develop control strategies for analysis, control, and optimization of advanced and conventional coal-cleaning plant. The project's scope included (1) the installation of a slurry test loop, ash, percent solids, and sulfur instruments; (2) evaluation of instrument accuracy with various coals, under various slurry conditions; and (3) assessment of the cost and benefits to be derived from on-line analysis and control 12 refs., 40 figs., 16 tabs.

Conkle, H.N.; Barnes, R.H.; Orban, J.E.; Webb, P.R.

1990-03-09T23:59:59.000Z

366

Engineering development of coal-fired high performance power systems, Phase II and Phase III. Quarter progress report, April 1, 1996--June 30, 1996  

SciTech Connect (OSTI)

Work is presented on the development of a coal-fired high performance power generation system by the year 2000. This report describes the design of the air heater, duct heater, system controls, slag viscosity, and design of a quench zone.

NONE

1996-11-01T23:59:59.000Z

367

Application of wavelength-scanned wavelength-modulation spectroscopy H2O absorption measurements in an engineering-scale high-pressure coal gasifier  

Science Journals Connector (OSTI)

A real-time, in situ water vapor (H2O) sensor using a tunable diode laser near 1,352 nm was developed to continuously monitor water vapor in the synthesis gas of an engineering-scale high-pressure coal gasifier....

Kai Sun; Ritobrata Sur; Jay B. Jeffries; Ronald K. Hanson; Tommy Clark…

2014-10-01T23:59:59.000Z

368

Removal of mercury from coal via a microbial pretreatment process  

SciTech Connect (OSTI)

A process for the removal of mercury from coal prior to combustion is disclosed. The process is based on use of microorganisms to oxidize iron, sulfur and other species binding mercury within the coal, followed by volatilization of mercury by the microorganisms. The microorganisms are from a class of iron and/or sulfur oxidizing bacteria. The process involves contacting coal with the bacteria in a batch or continuous manner. The mercury is first solubilized from the coal, followed by microbial reduction to elemental mercury, which is stripped off by sparging gas and captured by a mercury recovery unit, giving mercury-free coal. The mercury can be recovered in pure form from the sorbents via additional processing.

Borole, Abhijeet P. (Knoxville, TN); Hamilton, Choo Y. (Knoxville, TN)

2011-08-16T23:59:59.000Z

369

Degradation of solid oxide fuel cell metallic interconnects in fuels containing sulfur  

SciTech Connect (OSTI)

Hydrogen is the main fuel for all types of fuel cells except direct methanol fuel cells. Hydrogen can be generated from all manner of fossil fuels, including coal, natural gas, diesel, gasoline, other hydrocarbons, and oxygenates (e.g., methanol, ethanol, butanol, etc.). Impurities in the fuel can cause significant performance problems and sulfur, in particular, can decrease the cell performance of fuel cells, including solid oxide fuel cells (SOFC). In the SOFC, the high (800-1000°C) operating temperature yields advantages (e.g., internal fuel reforming) and disadvantages (e.g., material selection and degradation problems). Significant progress in reducing the operating temperature of the SOFC from ~1000 ºC to ~750 ºC may allow less expensive metallic materials to be used for interconnects and as balance of plant (BOP) materials. This paper provides insight on the material performance of nickel, ferritic steels, and nickel-based alloys in fuels containing sulfur, primarily in the form of H2S, and seeks to quantify the extent of possible degradation due to sulfur in the gas stream.

Ziomek-Moroz, M.; Hawk, Jeffrey A.

2005-01-01T23:59:59.000Z

370

Development of a high-performance coal-fired power generating system with pyrolysis gas and char-fired high temperature furnace (HITAF)  

SciTech Connect (OSTI)

A concept for an advanced coal-fired combined-cycle power generating system is currently being developed. The first phase of this three-phase program consists of conducting the necessary research and development to define the system, evaluate the economic and technical feasibility of the concept, and prepare an R D plan to develop the concept further. Foster Wheeler Development Corporation is leading a team ofcompanies involved in this effort. The system proposed to meet these goals is a combined-cycle system where air for a gas turbine is indirectly heated to approximately 1800[degrees]F in furnaces fired with cool-derived fuels and then directly heated in a natural-gas-fired combustor up to about 2400[degrees]F. The system is based on a pyrolyzing process that converts the coal into a low-Btu fuel gas and char. The fuelgas is a relatively clean fuel, and it is fired to heat tube surfaces that are susceptible to corrosion and problems from ash deposition. In particular, the high-temperature air heater tubes, which will need tobe a ceramic material, will be located in a separate furnace or region of a furnace that is exposed to combustion products from the low-Btu fuel gas only. A simplified process flow diagram is shown.

Not Available

1992-11-01T23:59:59.000Z

371

Comparison of high-pressure CO2 sorption isotherms on Eastern and Western US coals  

SciTech Connect (OSTI)

Accurate estimation of carbon dioxide (CO2) sorption capacity of coal is important for planning the CO2 sequestration efforts. In this work, we investigated sorption and swelling behavior of several Eastern and Western US coal samples from the Central Appalachian Basin and from San Juan Basin. The CO2 sorption isotherms have been completed at 55°C for as received and dried samples. The role of mineral components in coal, the coal swelling, the effects of temperature and moisture, and the error propagation have been analyzed. Changes in void volume due to dewatering and other factors such as temporary caging of carbon dioxide molecules in coal matrix were identified among the main factors affecting accuracy of the carbon dioxide sorption isotherms. The (helium) void volume in the sample cells was measured before and after the sorption isotherm experiments and was used to build the volume-corrected data plots.

Romanov, V.; Hur, T.-B.; Fazio, J.; Howard, B

2012-10-01T23:59:59.000Z

372

New developments in coal briquetting technology  

SciTech Connect (OSTI)

Briquetting of coal has been with us for well over a century. In the earliest applications of coal briquetting, less valuable fine coal was agglomerated into briquettes using a wide variety of binders, including coal tar, pitch and asphalt. Eventually, roll briquetters came into more widespread use, permitting the process to become a continuous one. Coal briquetting went out of favor during the 1950s in most of the industrialized world. The major reason for this decline in use was the discovery that the coal gas distillates used for binders were harmful to human health. Also, the abundance of cheap petroleum made coal briquettes a less attractive alternative as an industrial or domestic fuel. The re-emergence of coal as a primary industrial fuel and also its increased prominence as a fuel for thermal electric power stations led to a large increase in the annual volume of coal being mined worldwide. Coal preparation technology steadily improved over the years with the general exception of fine coal preparation. The processes available for treating this size range were considerably more expensive per unit mass of coal treated than coarse coal processes. Also, costly dewatering equipment was required after cleaning to remove surface moisture. Even with dewatering, the high surface area per unit mass of fine coal versus coarse coal resulted in high moisture contents. Therefore, little incentive existed to improve the performance of fine coal processes since this would only increase the amount of wet coal fines which would have to be dealt with. With such an ever-increasing volume of coal fines being created each year, there emerged an interest in recovering this valuable product. Several schemes were developed to recover coal fines discarded in abandoned tailings impoundments by previous operations.

Tucker, P.V. [Kilborn Inc., Ontario (Canada); Bosworth, G.B. [Kilborn Engineering Pacific Ltd., Vancouver, British Columbia (Canada); Kalb, G.W. [KKS Systems Inc., Wheeling, WV (United States)

1993-12-31T23:59:59.000Z

373

Conceptual design of a coal-fired MHD retrofit plant. Topical report, Seed Regeneration System Study 2  

SciTech Connect (OSTI)

Westinghouse Advanced Energy Systems (WAES), through Contract No. DE-AC22-87PC79668 funded by US DOE/PETC, is conducting a conceptual design study to evaluate a coal-fired magnetohydrodynamic (MHD) retrofit of a utility plant of sufficient size to demonstrate the technical and future economic viability of an MHD system operating within an electric utility environment. The objective of this topical report is to document continuing seed regeneration system application studies and the definition of will system integration requirements for the Scholz MHD retrofit plant design. MHD power plants require the addition of a seeding material in the form of potassium to enhance the ionization of the high temperature combustion gas in the MHD channel. This process has an added environmental advantage compared to other types of coal-fired power plants in that the potassium combines with the naturally occurring sulfur in the coal to form a potassium sulfate flyash (K{sub 2}SO{sub 4}) which can be removed from the process by appropriate particulate control equipment. Up to 100% of the Sulfur in the coal can be removed by this process thereby providing environmentally clean power plant operation that is better than required by present and anticipated future New Source Performance Standards (NSPS).

Not Available

1992-11-01T23:59:59.000Z

374

Russian coking coal in 2008 and 2009  

Science Journals Connector (OSTI)

Coal resources and coke production in the second half of 2009 ... are considered. The unsuitability of the available coal for the production of high-strength coke is analyzed.

B. P. Kiselev

2010-10-01T23:59:59.000Z

375

Leaching of boron from coal ash  

Science Journals Connector (OSTI)

Leaching of boron from coal ash ... First High-Resolution 11B Nuclear Magnetic Resonance (NMR) Spectra of Coal Fly Ash by Satellite-Transition Magic Angle Spinning (STMAS) NMR ... First High-Resolution 11B Nuclear Magnetic Resonance (NMR) Spectra of Coal Fly Ash by Satellite-Transition Magic Angle Spinning (STMAS) NMR ...

James A. Cox; Gary L. Lundquist; Andrzej Przyjazny; C. David Schmulbach

1978-06-01T23:59:59.000Z

376

Low-rank coal oil agglomeration  

DOE Patents [OSTI]

A low-rank coal oil agglomeration process is described. High mineral content, a high ash content subbituminous coals are effectively agglomerated with a bridging oil which is partially water soluble and capable of entering the pore structure, and is usually coal-derived.

Knudson, C.L.; Timpe, R.C.

1991-07-16T23:59:59.000Z

377

Coal surface control for advanced physical fine coal cleaning technologies. Final report, September 19, 1988--August 31, 1992  

SciTech Connect (OSTI)

This final report presents the research work carried out on the Coal Surface Control for Advanced Physical Fine Coal Cleaning Technologies project, sponsored by the US Department of Energy, Pittsburgh Energy Technology Center (DOE/PETC). The project was to support the engineering development of the selective agglomeration technology in order to reduce the sulfur content of US coals for controlling SO{sub 2} emissions (i.e., acid rain precursors). The overall effort was a part of the DOE/PETCs Acid Rain Control Initiative (ARCI). The overall objective of the project is to develop techniques for coal surface control prior to the advanced physical fine coal cleaning process of selective agglomeration in order to achieve 85% pyrite sulfur rejection at an energy recovery greater than 85% based on run-of-mine coal. The surface control is meant to encompass surface modification during grinding and laboratory beneficiation testing. The project includes the following tasks: Project planning; methods for analysis of samples; development of standard beneficiation test; grinding studies; modification of particle surface; and exploratory R&D and support. The coal samples used in this project include three base coals, Upper Freeport - Indiana County, PA, Pittsburgh NO. 8 - Belmont County, OH, and Illinois No. 6 - Randolph County, IL, and three additional coals, Upper Freeport - Grant County- WV, Kentucky No. 9 Hopkins County, KY, and Wyodak - Campbell County, WY. A total of 149 drums of coal were received.

Morsi, B.I.; Chiang, S.H.; Sharkey, A.; Blachere, J.; Klinzing, G.; Araujo, G.; Cheng, Y.S.; Gray, R.; Streeter, R.; Bi, H.; Campbell, P.; Chiarlli, P.; Ciocco, M.; Hittle, L.; Kim, S.; Kim, Y.; Perez, L.; Venkatadri, R.

1992-12-31T23:59:59.000Z

378

Illinois coal reserve assessment and database development. Final report  

SciTech Connect (OSTI)

The new demonstrated reserve base estimate of coal of Illinois is 105 billion short tons. This estimate is an increase from the 78 billion tons in the Energy Information Administration`s demonstrated reserve base of coal, as of January 1, 1994. The new estimate arises from revised resource calculations based on recent mapping in a number of countries, as well as significant adjustments for depletion due to past mining. The new estimate for identified resources is 199 billion tons, a revision of the previous estimate of 181 billion tons. The new estimates incorporate the available analyses of sulfur, heat content, and rank group appropriate for characterizing the remaining coal resources in Illinois. Coal-quality data were examined in conjunction with coal resource mapping. Analyses of samples from exploration drill holes, channel samples from mines and outcrops, and geologic trends were compiled and mapped to allocate coal resource quantities to ranges of sulfur, heat content, and rank group. The new allocations place almost 1% of the demonstrated reserve base of Illinois in the two lowest sulfur categories, in contrast to none in the previous allocation used by the Energy Information Administration (EIA). The new allocations also place 89% of the demonstrated reserve base in the highest sulfur category, in contrast to the previous allocation of 69% in the highest category.

Treworgy, C.G.; Prussen, E.I.; Justice, M.A.; Chenoweth, C.A. [and others

1997-11-01T23:59:59.000Z

379

Coal extraction  

SciTech Connect (OSTI)

Coal is extracted using a mixed solvent which includes a substantially aromatic component and a substantially naphthenic component, at a temperature of 400/sup 0/ to 500/sup 0/C. Although neither component is an especially good solvent for coal by itself, the use of mixed solvent gives greater flexibility to the process and offers efficiency gains.

Clarke, J.W.; Kimber, G.M.; Rantell, T.D.; Snape, C.E.

1985-06-04T23:59:59.000Z

380

Assessment of modular IGCC plants based on entrained flow coal gasification supplemental studies  

SciTech Connect (OSTI)

In a previous study (1), Foster Wheeler made an assessment of modular IGCC power systems employing Texaco entrained flow gasification of Illinois No. 6 coal. In that study, five case studies were developed in order to compare the relative performance and economics of air vs. oxygen blown gasification and high temperature vs. low temperature gas cleanup. As a supplemental study, two additional IGCC design cases were developed as alternate to the original Case 2 and Case 3 configurations. The objective of the Case 2 alternate study was to assess the potential of zinc titanate in place of zinc ferrite. Compared to zinc ferrite, the zinc titanate system offered the following potential advantages: Does not require steam conditioning of the feed gas to avoid carbon formation; does not require reductive regeneration and the corresponding use of fuel gas; operates at higher temperature, about 1350{degree}F; and has a longer projected sorbent life. The objective of the alternate Case 3 study was to determine the economic impact of producing sulfuric acid, instead of elemental sulfur, as the by-product from high temperature desulfurization using zinc ferrite. Sulfur recovery as by-product sulfuric acid therefore offered the potential for reducing both the capital and operating costs. 6 refs., 5 figs., 15 tabs.

Fu, R.K.

1989-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Chemical composition and some trace element contents in coals and coal ash from Tamnava-Zapadno Polje Coal Field, Serbia  

SciTech Connect (OSTI)

The chemical compositions and trace element contents (Zn, Cu, Co, Cr, Ni, Pb, Cd, As, B, Hg, Sr, Se, Be, Ba, Mn, Th, V, U) in coal and coal ash samples from Tamnava-Zapadno Polje coal field in Serbia were studied. The coal from this field belongs to lignite. This high volatility coal has high moisture and low S contents, moderate ash yield, and high calorific value. The coal ash is abundant in alumosilicates. Many trace elements such as Ni > Cd > Cr > B > As > Cu > Co > Pb > V > Zn > Mn in the coal and Ni > Cr > As > B > Cu > Co = Pb > V > Zn > Mn in the coal ash are enriched in comparison with Clarke concentrations.

Vukasinovic-Pesic, V.; Rajakovic, L.J. [University of Montenegro, Podgorica (Montenegro)

2009-07-01T23:59:59.000Z

382

U.S. zero emission coal alliance techology  

SciTech Connect (OSTI)

For coal to maintain its major role in supplying the world's energy, eventually all emissions to the atmosphere must be eliminated. Not only must conventional pollutants, like sulfur compounds and dust particles be kept out of the air, but also the far larger quantities of carbon dioxide that result from the combustion of carbon. We present a new technology for coal-based power that generates hydrogen from carbon and water, avoids emissions to the atmosphere, and disposes of the carbon dioxide as inert, solid mineral carbonates. Based on the available resources, coal power is sustainable for centuries. Our zero emission technology makes coal energy as clean as renewable energy.

Lackner, K. S. (Klaus S.); Ziock, H. J. (Hans-Joachim)

2001-01-01T23:59:59.000Z

383

Ultrasound-promoted chemical desulfurization of Illinois coals  

SciTech Connect (OSTI)

The overall objectives of the program were to investigate the use of ultrasound to promote coal desulfurization reactions and to evaluate chemical coal desulfurization schemes under mild conditions through a fundamental understanding of their reaction mechanisms and kinetics. The ultimate goal was to develop an economically feasible mild chemical process to reduce the total sulfur content of Illinois Basin Coals, while retaining their original physical characteristics, such as calorific value and volatile matter content. During the program, potential chemical reactions with coal were surveyed under various ultrasonic irradiation conditions for desulfurization, to formulate preliminary reaction pathways, and to select a few of the more promising chemical processes for more extensive study.

Chao, S.S.

1991-01-01T23:59:59.000Z

384

Theoretical principles of use of coal fractions with different densities for combustion  

Science Journals Connector (OSTI)

It is reasonable to complement the conventional preparation of steam coal involving the removal of ash components and pyritic sulfur by the isolation of the lightest organic fractions, which possess enhanced p...

S. G. Gagarin; A. M. Gyul’maliev

2009-02-01T23:59:59.000Z

385

Preliminary observations of the thermodynamic predictions of Fe-Cr-Ni alloys in coal gasifier environments  

Science Journals Connector (OSTI)

The construction of thermodynamic stability diagrams for the Fe-Cr-Ni systems is discussed. The constructed diagrams are used to predict materials behavior at coal gasifier oxygen and sulfur pote...

B. A. Gordon; V. Nagarajan

1979-04-01T23:59:59.000Z

386

Thermodynamic predictions of the behavior of Fe-Cr-Al alloys in coal gasifier environments  

Science Journals Connector (OSTI)

The construction of thermodynamic stability diagrams for the Fe-Cr-Al system is discussed. The constructed diagrams are used to predict materials behavior at coal gasifier oxygen and sulfur potentials. Experiment...

B. A. Gordon; W. Worrell; V. Nagarajan

1979-02-01T23:59:59.000Z

387

Advanced Byproduct Recovery: Direct Catalytic Reduction of Sulfur Dioxide to Elemental Sulfur.  

SciTech Connect (OSTI)

More than 170 wet scrubber systems applied, to 72,000 MW of U.S., coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed from the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). Due to the abundance and low cost of naturally occurring gypsum, and the costs associated with producing an industrial quality product, less than 7% of these scrubbers are configured to produce usable gypsum (and only 1% of all units actually sell the byproduct). The disposal of solid waste from each of these scrubbers requires a landfill area of approximately 200 to 400 acres. In the U.S., a total of 19 million tons of disposable FGD byproduct are produced, transported and disposed of in landfills annually. The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. In a regenerable sorbent system, the sulfur dioxide in the boiler flue gas is removed by the sorbent in an adsorber. The S0{sub 2}s subsequently released, in higher concentration, in a regenerator. All regenerable systems produce an off-gas stream from the regenerator that must be processed further in order to obtain a salable byproduct, such as elemental sulfur, sulfuric acid or liquid S0{sub 2}.

NONE

1997-06-01T23:59:59.000Z

388

SYNTHESIS OF SULFUR-BASED WATER TREATMENT AGENT FROM SULFUR DIOXIDE WASTE STREAMS  

SciTech Connect (OSTI)

We propose a process that uses sulfur dioxide from coal combustion as a raw material to synthesize polymeric ferric sulfate (PFS), a water treatment agent. The process uses sodium chlorate as an oxidant and ferrous sulfate as an absorbent. The major chemical mechanisms in this reaction system include oxidation, hydrolysis, and polymerization. Oxidation determines sulfur conversion efficiency while hydrolysis and polymerization control the quality of product. Many factors, including SO{sub 2} inlet concentration, flow rate of simulated flue gas, reaction temperature, addition rate of oxidant and stirring rate, may affect the efficiencies of SO{sub 2} removal. Currently, the effects of SO{sub 2} inlet concentration, the flow rate of simulated flue gas and addition rate of flue gas on removal efficiencies of SO{sub 2}, are being investigated. Experiments shown in this report have demonstrated that the conversion efficiencies of sulfur dioxide with ferrous sulfate as an absorbent are in the range of 60-80% under the adopted process conditions. However, the conversion efficiency of sulfur dioxide may be improved by optimizing reaction conditions to be investigated. Partial quality indices of the synthesized products, including Fe{sup 2+} concentration and total iron concentration, have been evaluated.

Robert C. Brown; Maohong Fan

2001-12-01T23:59:59.000Z

389

Physico-chemical fracturing and cleaning of coal. [Treatment with CO/sub 2/ in water at high pressure  

DOE Patents [OSTI]

This invention relates to a method of producing a crushable coal and reducing the metallic values in coal represented by Si, Al, Ca, Na, K, and Mg, which comprises contacting a coal/water mix in a weight ratio of from about 4:1 to 1:6 in the presence of CO/sub 2/ at pressures of about 100 to 1400 psi and a minimum temperature of about 15/sup 0/C for a period of about one or more hours to produce a treated coal/water mix. In the process the treated coal/water mix has reduced values for Ca and Mg of up to 78% over the starting mix and the advantageous CO/sub 2/ concentration is in the range of about 3 to 30 g/L. Below 5 g/L CO/sub 2/ only small effects are observed and above 30 g/L no further special advantages are achieved. The coal/water ratios in the range 1:2 to 2:1 are particularly desirable and such ratios are compatible with coal water slurry applications.

Sapienza, R.S.; Slegeir, W.A.R.

1983-09-30T23:59:59.000Z

390

Low temperature pyrolysis of coal or oil shale in the presence of calcium compounds  

DOE Patents [OSTI]

A coal pyrolysis technique or process is described in which particulate coal is pyrolyzed in the presence of about 5 to 21 wt. % of a calcium compound selected from calcium oxide, calcined (hydrate) dolomite, or calcined calcium hydrate to produce a high quality hydrocarbon liquid and a combustible product gas which are characterized by low sulfur content. The pyrolysis is achieved by heating the coal-calcium compound mixture at a relatively slow rate at a temperature of about 450.degree. to 700.degree. C. over a duration of about 10 to 60 minutes in a fixed or moving bed reactor. The gas exhibits an increased yield in hydrogen and C.sub.1 -C.sub.8 hydrocarbons and a reduction in H.sub.2 S over gas obtainable by pyrolyzing cola without the calcium compound. The liquid product obtained is of a sufficient quality to permit its use directly as a fuel and has a reduced sulfur and oxygen content which inhibits polymerization during storage.

Khan, M. Rashid (Morgantown, WV)

1988-01-01T23:59:59.000Z

391

Coal-derived promoters for the liquefaction of Illinois coal. [Quarterly] technical report, December 1, 1991--February 29, 1992  

SciTech Connect (OSTI)

The objective of this program is to investigate the use of liquids derived from coal either by mild gasification or supercritical extraction (SCE) to promote direct liquefaction of Illinois coal. Some organic sulfur-, nitrogen-, and oxygen-containing compounds have been found to enhance liquefaction reactions. The use of Illinois coal to produce liquid fractions rich in these types of compounds could increase the rates of liquefaction reactions, thus improving the process economics. An integrated process combining direct liquefaction with mild gasification or SCE of coal is being developed by IGT.

Carty, R.H.; Knight, R.A.

1992-08-01T23:59:59.000Z

392

Lithium–sulfur batteries: Influence of C-rate, amount of electrolyte and sulfur loading on cycle performance  

Science Journals Connector (OSTI)

Abstract In the past four years major improvement of the lithium sulfur battery technology has been reported. Novel carbon cathode materials offer high sulfur loading, sulfur utilization and cycle stability. An often neglected aspect is that sulfur loading and amount of electrolyte strongly impact the performance. In this paper, we demonstrate how the amount of electrolyte, sulfur loading, lithium excess and cycling rate influences the cycle stability and sulfur utilization. We chose vertically aligned carbon nanotubes (VA-CNT) as model system with a constant areal loading of carbon. For a high reproducibility, decreased weight of current collector and good mechanical adhesion of the VA-CNTs we present a layer transfer technique that enables a light-weight sulfur cathode. The sulfur loading of the cathode was adjusted from 20 to 80 wt.-%. Keeping the total amount of electrolyte constant and varying the C-rate, we are able to demonstrate that the capacity degradation is reduced for high rates, high amount of electrolyte and low sulfur loading. In addition idle periods in the cycling regiment and lower rates result in an increased degradation. We attribute this to the redox-reaction between reactive lithium and polysulfides that correlates with the cycling time, rather than cycle number.

Jan Brückner; Sören Thieme; Hannah Tamara Grossmann; Susanne Dörfler; Holger Althues; Stefan Kaskel

2014-01-01T23:59:59.000Z

393

The role of combustion diagnostics in coal quality impact and NO{sub x} emissions field test programs  

SciTech Connect (OSTI)

Many utilities are examining low sulfur coal or coal blending options to comply with the Clean Air Act Amendment SO{sub 2} emission limits. Test burns have been conducted with the more promising candidate coals to characterize the potential impact of a change in coal quality on boiler operation and performance. Utilities are also under considerable pressure to evaluate NO{sub x} control options and develop a compliance plan to meet strict NO{sub x} regulations, particularly in high population density metropolitan areas on the Eastern seaboard. Field test programs have been conducted to characterize baseline NO{sub x} emissions, evaluate the NO{sub x} reduction potential of combustion modifications, and assess the potential of combustion tuning as an alternative to burner replacement. Coal quality impacts (slagging, fouling, heat absorption, ash removal) and NO{sub x} emissions are both strongly dependent upon the coal combustion process and site-specific boiler firing practices. Non-uniform combustion in the burner region can result in adverse ash deposition characteristics, carbon carryover problems, high furnace exit gas temperatures, and NO{sub x}emission characteristics that are not representative of the coal or the combustion equipment. Advanced combustion diagnostic test procedures have been developed to evaluate and improve burner zone combustion uniformity, even in cases where the coal flow to the individual burners may be non-uniform. The paper outlines a very practical solving approach to identifying combustion related problems that affect ash deposition and NO{sub x} emissions. The benefits of using advanced diagnostic instrumentation to identify problems and tune combustion conditions is illustrated using test data from recent quality field test programs.

Thompson, R.E. [Fossil Energy Research Corp., Laguna Hills, CA (United States); Dyas, B. [New England Power Company, Westborough, MA (United States)

1995-03-01T23:59:59.000Z

394

The relationship between coal quality and coal resource parameters of Powder River and Williston Basin coal, Wyoming, Montana, and North Dakota  

SciTech Connect (OSTI)

Clean, compliant coal from mines in the Northern Rocky Mountain and Great Plains region is utilized as fuel for coal-fired power plants in 26 states. More than 30 percent of the nation`s 1997 production was from Montana, North Dakota, and Wyoming. Production of clean, compliant coal from the region is estimated to increase to 415 million short tons by the year 2015. Studies in this region indicate a relationship between percent sulfur and ash and pounds of SO{sub 2} per million Btu and the resource parameters of coal thickness and overburden. The trends that the authors have observed indicate that both coal quality and the thickness of the coal and associated rocks are controlled by paleoenvironment and depositional setting.

Ellis, M.S.; Stricker, G.D.; Gunther, G.; Ochs, A.M.; Flores, R.M.

1998-12-31T23:59:59.000Z

395

Low severity coal liquefaction promoted by cyclic olefins. Quarterly report, April--June 1992  

SciTech Connect (OSTI)

Low severity coal liquefaction allows for solubilization of coal with reduced gas make. These lower severity conditions may result in some selective bond rupture. Promotion of coal solubilization through hydrogen transfer using highly active and effective hydrogen donors is the objective of this study. The highly effective donors being tested are cyclic olefins. Representative cyclic olefins are isotetralin, which is 1,4,5,8-tetrahydronaphthalene, and 1,4,5,8,9,10-hexahydroanthracene. These compounds are hydroaromatics without aromatic rings and have been shown to be highly effective donors. The objective of the work performed in this study during this quarter was to evaluate reaction parameters for low severity liquefaction reactions using the cyclic olefin, hexahydroanthracene, and the aromatic, anthracene. These model compounds were reacted under a variety of conditions to evaluate their reactivity without coal. The reactions were performed under both thermal and catalytic conditions. Finely divided catalysts from different molybdenum precursors were used to determine their activity in promoting hydrogenation and hydrogen transfer at low severity conditions. The catalysts used were Molyvan L, sulfurized oxymolybdenum dithiocarbamate, molybdenum naphthenate, and Molyvan 822, organo molybdenum dithiocarbamate.

Curtis, C.W.

1992-07-27T23:59:59.000Z

396

The changing structure of the US coal industry: An update, July 1993  

SciTech Connect (OSTI)

Section 205(a)(2) of the Department of Energy Organization Act of 1977 requires the Administrator of the Energy Information Administration (EIA) to carry out a central, comprehensive, and unified energy data and information program that will collect, evaluate, assemble, analyze, and disseminate data and information relevant to energy resources, reserves, production, demand, technology, and related economic and statistical information. The purpose of this report is to provide a comprehensive overview of changes in the structure of the US coal industry between 1976 and 1991. The structural elements examined include the number of mines, average mine size, the size distribution of mines, and the size distribution of coal firms. The report measures changes in the market shares of the largest coal producers at the national level and in various regions. The Central Appalachian low-sulfur coal market is given special attention, and the market for coal reserves is examined. A history of mergers in the coal industry is presented, and changes in the proportions of US coal output that are produced by various types of companies, including foreign-controlled firms, are described. Finally, the impact of post-1991 mergers on the structure of the industry is estimated. The legislation that created the EIA vested the organization with an element of statutory independence. The EIA does not take positions on policy questions. The EIA`s responsibility is to provide timely, high-quality information and to perform objective, credible analyses in support of deliberations by both public and private decisionmakers. Accordingly, this report does not purport to represent the policy positions of the US Department of Energy or the Administration.

Not Available

1993-07-29T23:59:59.000Z

397

Modernization of Ohio's coal reserves, Phase 1  

SciTech Connect (OSTI)

The objectives of this project were to determine state-level totals of the estimated economic resource, minable reserve base, and recoverable coal in Ohio, allocated to specified ranges of sulfur and heat content. In addition, resources and reserves were to be categorized by mining methods (surface and underground). Land use and environmental restrictions, needed to determine remaining minable reserves, were to be delineated and percentages of restricted coal calculated. In context of a Phase 1, one-year project, the objectives of this project were to update Ohio's coal reserves and resources for as many counties as time allowed, and to deplete production tonnages to January 1, 1991, on the remaining coal-producing counties. For the depleted counties, only estimated economic resources were required or possible with the data available. 24 refs., 9 figs., 3 tabs.

Carlton, R.W.

1991-09-27T23:59:59.000Z

398

Confined-Unconfined Changes above Longwall Coal  

Science Journals Connector (OSTI)

...was about 2 m from coal extraction about...and space by the mining and subsidence rates...In studies in Appalachia, Moebs and Barton...high-extraction coal mining. The rapid change...effects of longwall coal mining on overlying aquifers...

COLIN J BOOTH

399

Sulfur Behavior in the Sasol?Lurgi Fixed-Bed Dry-Bottom Gasification Process  

Science Journals Connector (OSTI)

This article reports on the findings of a study regarding the sulfur behavior across a Sasol?Lurgi gasifier. ... (2) This ash, referred to as “coarse ash”, is a combination of red and white to gray sintered clinkers with heterogeneous texture varying from fine material to large irregularly shaped aggregates of sizes ranging from 4 to 75 mm. ... South African coals that are used for the Sasol?Lurgi gasification process are normally low-grade medium rank C (bituminous) coal with a total sulfur content of approximately 1?2 wt %, on an as-received basis. ...

M. Pat Skhonde; R. Henry Matjie; J. Reginald Bunt; A. Christien Strydom; Herold Schobert

2008-12-05T23:59:59.000Z

400

High pressure/high temperature vapor liquid equilibrium study of light gases in hydrogen-coal liquid model compound systems using perturbation chromatography  

SciTech Connect (OSTI)

Perturbation chromatography or gas-liquid partition chromatography (GLPC) provides a powerful tool for making physicochemical measurements. In this investigation GLPC was applied to study the vapor-liquid equilibrium behavior of light gases in nonvolatile coal liquid model compound solvents at high temperatures and high pressures. Improvements made in existing GLPC techniques include: the use of a high pressure tandem proportioning pump to give precise control of the carrier gas flow rate and low pressure drops; a high pressure ionization chamber to detect the injection of very dilute radioactive sample gases; and the use of a microcomputer to provide instantaneous integration and very precise retention times of the chromatographic peaks. Infinite dilution K-values for methane, ethane, propane, n-butane, carbon dioxide, and hydrogen sulfide in hydrogen-dibenzofuran systems were obtained at 100 and 125 C and up to 800 psia. Infinite dilution K-values for the same light gases in hydrogen-9-methylanthracene systems were obtained at 100, 125, 150, 175, and 200 C and up to 3000 psia. Henry's constants were determined for the light gases in 9-methylanthracene. Second cross virial coefficients and vapor phase infinite dilution fugacity coefficients were calculated for methane, ethane, propane, and n-butane in hydrogen. These results were combined with the experimental K-value measurements to obtain Henry's constants in hydrogen-9-methylanthracene mixtures of fixed liquid compositions. Infinite dilution heats of solution of the solute gases in the mixtures were calculated.

Kragas, T.K.

1983-01-01T23:59:59.000Z