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1

High-sulfur coals in the eastern Kentucky coal field  

SciTech Connect (OSTI)

The Eastern Kentucky coal field is notable for relatively low-sulfur, [open quotes]compliance[close quotes] coals. Virtually all of the major coals in this area do have regions in which higher sulfur lithotypes are common, if not dominant, within the lithologic profile. Three Middle Pennsylvanian coals, each representing a major resource, exemplify this. The Clintwood coal bed is the stratigraphically lowest coal bed mined throughout the coal field. In Whitley County, the sulfur content increase from 0.6% at the base to nearly 12% in the top lithotype. Pyrite in the high-sulfur lithotype is a complex mixture of sub- to few-micron syngenetic forms and massive epigenetic growths. The stratigraphically higher Pond Creek coal bed is extensively mined in portions of the coal field. Although generally low in sulfur, in northern Pike and southern Martin counties the top one-third can have up to 6% sulfur. Uniformly low-sulfur profiles can occur within a few hundred meters of high-sulfur coal. Pyrite occurs as 10-50 [mu]m euhedra and coarser massive forms. In this case, sulfur distribution may have been controlled by sandstone channels in the overlying sediments. High-sulfur zones in the lower bench of the Fire Clay coal bed, the stratigraphically highest coal bed considered here, are more problematical. The lower bench, which is of highly variable thickness and quality, generally is overlain by a kaolinitic flint clay, the consequence of a volcanic ash fall into the peat swamp. In southern Perry and Letcher counties, a black, illite-chlorite clay directly overlies the lower bench. General lack of lateral continuity of lithotypes in the lower bench suggests that the precursor swamp consisted of discontinuous peat-forming environments that were spatially variable and regularly inundated by sediments. Some of the peat-forming areas may have been marshlike in character.

Hower, J.C.; Graham, U.M. (Univ. of Kentucky Center for Applied Energy Research, Lexington, KY (United States)); Eble, C.F. (Kentucky Geological Survey, Lexington, KY (United States))

1993-08-01T23:59:59.000Z

2

Co-firing high sulfur coal with refuse derived fuels. Final report  

SciTech Connect (OSTI)

This project was designed to evaluate the combustion performance of and emissions from a fluidized bed combustor during the combustion of mixtures of high sulfur and/or high chlorine coals and municipal solid waste (MSW). The project included four major tasks, which were as follows: (1) Selection, acquisition, and characterization of raw materials for fuels and the determination of combustion profiles of combination fuels using thermal analytical techniques; (2) Studies of the mechanisms for the formation of chlorinated organics during the combustion of MSW using a tube furnace; (3) Investigation of the effect of sulfur species on the formation of chlorinated organics; and (4) Examination of the combustion performance of combination fuels in a laboratory scale fluidized bed combustor. Several kinds of coals and the major combustible components of the MSW, including PVC, newspaper, and cellulose were tested in this project. Coals with a wide range of sulfur and chlorine contents were used. TGA/MS/FTIR analyses were performed on the raw materials and their blends. The possible mechanism for the formation of chlorinated organics during combustion was investigated by conducting a series of experiments in a tube furnace. The effect of sulfur dioxide on the formation of molecular chlorine during combustion processes was examined in this study.

Pan, W.P.; Riley, J.T.; Lloyd, W.G.

1997-11-30T23:59:59.000Z

3

Co-firing high sulfur coal with refuse derived fuels. Quarterly report, October - December 1996  

SciTech Connect (OSTI)

The objectives of this quarter of study on the co-firing of high sulfur coal with refuse derived fuels project were two-fold. First, the effect of S0{sub 2} on the formation of chlorine during combustion processes was examined. To simulate the conditions used in the AFBC system, experiments were conducted in a quartz tube in an electrically heated furnace. The principle analytical technique used for identification of the products from this study was GC/MS. The evolved gas was trapped by an absorbent and analyzed with a GC/MS system. The preliminary results indicate an inhibiting effect of S0{sub 2} on the Deacon Reaction. Secondly, information on the evolution of chlorine, sulfur and organic compounds from coals 95031 and 95011 were studied with the AFBC system. 2 figs., 1 tab.

Pan, W.-P.; Riley, J.T.; Lloyd, W.G.

1996-12-01T23:59:59.000Z

4

Petrography and chemistry of sized fly ash from low-sulfur and high-sulfur coal sources  

SciTech Connect (OSTI)

Fly ash samples were collected in November and December, 1994, from two units representing high- and low-sulfur feed coals at a Kentucky power station. The ashes were wet screened at 100, 200, 325, and 500 mesh. The dried ({approximately}40 C) fractions were then weighed, split for petrographic and chemical analysis, mounted in epoxy and prepared as polished pellets, and analyzed for ash yield and carbon content. The November ashes had a similar size distribution in the +325 mesh fractions. The low-sulfur hot side and cool side ashes had a similar size distribution in the November ashes. In contrast, the December fly ashes showed the typical trend, the cool-side ash being finer (over 20% more ash in the {minus}500 mesh fraction) than the hot-side ash. Carbon tends to be relatively concentrated in the coarse fractions. The dominance of the {minus}325 mesh fractions in the overall size analysis implies, though, that carbon in the fine sizes is an important consideration in the utilization potential of the fly ash.

Hower, J.C. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research; Trimble, A.S. [Franklin County High School, Frankfort, KY (United States); Eble, C.F. [Kentucky Geological Survey, Lexington, KY (United States); Palmer, C. [Geological Survey, Reston, VA (United States)

1996-12-31T23:59:59.000Z

5

Influence of coal quality parameters on utilization of high-sulfur coals: Examples from Springfield (western Kentucky No. 9) coal bed  

SciTech Connect (OSTI)

The Springfield (Western Kentucky No. 9) coal bed is the most important energy resource in the Western Kentucky coalfield (Eastern Interior coalfield), accounting for over 30 million tons of annual production from remaining resources of over 9 billion tons. For many coal quality parameters, the quality of the coal bed is relatively consistent throughout the region. For example, the Springfield has about 80-85% vitrinite, 10% ash, and 3.5-4.5% total sulfur at most sites in the coalfield. However, coal quality variation is more than just the changes in ash and sulfur. As demonstrated by the Springfield coal bed, it is a complex interaction of related and unrelated variables many of which directly affect utilization of the coal. Significant, though generally predictable, changes are observed in other parameters. Comparison of data from the Millport (Muhlenberg and Hopkins Countries), Providence (Hopkins and Webster Counties), and Waverly (Union County) 7{1/2} Quadrangles illustrated such variations.

Griswold, T.B.; Hower, J.C.; Cobb, J.C. (Kentucky Energy Cabinet, Lexington (USA))

1989-08-01T23:59:59.000Z

6

Iron distribution among phases in high- and low-sulfur coal fly ash  

SciTech Connect (OSTI)

Moessbauer spectroscopy, reflected-light optical microscopy, scanning-electron microscopy, wet chemical, and X-ray diffraction studies were conducted on six fly ash samples. The fly ashes, representing the combustion by-products of coals with total sulfur contents of less than 2% to greater than 4%, ranged from 17.6 to 32.0% Fe{sub 2}O{sub 3} by XRF analysis. Wet chemical analysis was used to determine the Fe{sup 3+}/{summation}Fe content of the ashes, which ranged from 72% to 83%. Optical analysis of the ashes indicated that the spinel, encompassing iron oxides of various compositions, ranges from 4.0 to 12.6% (vol.). Moessbauer analyses confirmed the presence of three Fe-bearing phases: magnetite, hematite (possibly of two different compositions), and glass. The variation in the Fe-oxidation state follows the variation in the sulfur, consequently pyrite, content of the feed coal.

Hower, J.C.; Graham, U.M.; Rathbone, R.F. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research; Dyar, M.D.; Taylor, M.E. [West Chester Univ., PA (United States). Dept. of Geology and Astronomy

1995-12-31T23:59:59.000Z

7

Co-firing high sulfur coal with refuse derived fuels. Technical progress report No. 6, January--March 1996  

SciTech Connect (OSTI)

The objectives for this quarter of study on the co-firing of high sulfur coals with refuse derived fuels were two-fold. First, the effects of different experimental parameters such as temperature, flow rates and reaction times on the formation of chlorinated organic compounds were studied using the tubular furnace as a reactor followed by GC/MS analysis. Secondly, the effect of fuel/air ratio on the flue gas composition and combustion efficiency were studied with the AFBC system.

Pan, W.P.; Riley, J.T.; Lloyd, W.G.

1996-02-29T23:59:59.000Z

8

Development of advanced, dry, SO{sub x}/NO{sub x} emission control technologies for high-sulfur coal. Final report, April 1, 1993--December 31, 1994  

SciTech Connect (OSTI)

Dry Scrubbing is a common commercial process that has been limited to low- and medium-sulfur coal applications because high-sulfur coal requires more reagent than can be efficiently injected into the process. Babcock & Wilcox has made several advances that extend dry scrubbing technologies to higher sulfur coals by allowing deposit-free operation at low scrubber exit temperatures. This not only increases the amount of reagent that can be injected into the scrubber, but also increases SO{sub 2} removal efficiency and sorbent utilization. The objectives of this project were to demonstrate, at pilot scale, that advanced, dry-scrubbing-based technologies can attain the performance levels specified by the 1990 Clean Air Act Amendments for SO{sub 2} and NO{sub x} emissions while burning high-sulfur coal, and that these technologies are economically competitive with wet scrubber systems. The use of these technologies by utilities in and around Ohio, on new or retrofit applications, will ensure the future of markets for high-sulfur coal by creating cost effective options to coal switching.

Amrhein, G.T.

1994-12-23T23:59:59.000Z

9

Characterization of fly ash from low-sulfur and high-sulfur coal sources: Partitioning of carbon and trace elements with particle size  

SciTech Connect (OSTI)

Fly ash samples were collected in November and December of 1994, from generating units at a Kentucky power station using high- and low-sulfur feed coals. The samples are part of a two-year study of the coal and coal combustion byproducts from the power station. The ashes were wet screened at 100, 200, 325, and 500 mesh (150, 75, 42, and 25 {micro}m, respectively). The size fractions were then dried, weighed, split for petrographic and chemical analysis, and analyzed for ash yield and carbon content. The low-sulfur heavy side and light side ashes each have a similar size distribution in the November samples. In contrast, the December fly ashes showed the trend observed in later months, the light-side ash being finer (over 20% more ash in the {minus}500 mesh [{minus}25 {micro}m] fraction) than the heavy-side ash. Carbon tended to be concentrated in the coarse fractions in the December samples. The dominance of the {minus}325 mesh ({minus}42 {micro}m) fractions in the overall size analysis implies, though, that carbon in the fine sizes may be an important consideration in the utilization of the fly ash. Element partitioning follows several patterns. Volatile elements, such as Zn and As, are enriched in the finer sizes, particularly in fly ashes collected at cooler, light-side electrostatic precipitator (ESP) temperatures. The latter trend is a function of precipitation at the cooler-ESP temperatures and of increasing concentration with the increased surface area of the finest fraction. Mercury concentrations are higher in high-carbon fly ashes, suggesting Hg adsorption on the fly ash carbon. Ni and Cr are associated, in part, with the spinel minerals in the fly ash.

Hower, J.C.; Trimble, A.S. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research]|[Franklin County High School, Frankfort, KY (United States); Eble, C.F. [Kentucky Geological survey, Lexington, KY (United States); Palmer, C.A.; Kolker, A. [Geological Survey, Reston, VA (United States)

1999-07-01T23:59:59.000Z

10

Combustion of high-sulfur coal and anthracite wastes in a rotary kiln combustor with an advanced internal air distributor  

SciTech Connect (OSTI)

Fluid bed combustors have received extensive testing with both high-sulfur coal and anthracite wastes. Rotary kilns are effective and popular devices for waste combustion. The Angelo Rotary Furnace{trademark} has been developed to improve the operation of rotary pyrolyzer/combustor systems through enhanced air distribution, which in this process is defined as staged, swirled combustion air injection. Fourteen of these new furnaces have been installed worldwide. Two units in Thailand, designed for rice hull feed with occasional lignite feed, have been recently started up. An older unit in Pennsylvania is being upgraded with a new, more advanced air distribution system for a series of tests this fall in which inexpensive high-sulfur coal and anthracite wastes will be fired with limestone. The purposes of these tests are to determine the burning characteristics of these two fuels in this system, to discover the Ca/S ratios necessary for operation of a rotary kiln combusting these fuels, and to observe the gas-borne emissions from the furnace. An extensive preliminary design study will be performed on a commercial installation for combustion of anthracite wastes. 14 refs., 5 figs., 1 tab.

Cobb, J.T. Jr. (Pittsburgh Univ., PA (USA)); Ahn, Y.K. (Gilbert/Commonwealth, Inc., Reading, PA (USA)); Angelo, J.F. (Universal Energy International, Inc., Little Rock, AR (USA))

1990-01-01T23:59:59.000Z

11

Co-firing high sulfur coal with refuse derived fuels. Technical report {number_sign}4  

SciTech Connect (OSTI)

In order to study combustion performance under conditions similar to that in the AFBC system, the authors conducted a series of experiments at a heating rate of 100 C/min using the TGA/FTIR/MS system. Results indicate that more hydrocarbons are evolved at the faster heating rate, owing to incomplete combustion of the fuel. Chlorinated organic compounds can be formed at high heating rates. Certain oxidation products such as organic acids and alcohols are obtained at the slow heating rate. To simulate the conditions used in the atmospheric fluidized bed combustor (AFBC) at Western Kentucky University, studies were also conducted using a quartz tube in a tube furnace. The temperature conditions were kept identical to those of the combustor. The products evolved from the combustion of coal, PVC, and mixtures of the two were trapped in suitable solvents at different temperatures, and analyzed using the Shimadzu GC/MS system. The detection limits and the GC/MS analytical parameters were also established. The experiments were conducted keeping in mind the broader perspective; that of studying conditions conducive to the formation of chlorinated organic compounds from the combustion of coal/MSW blends. 32 figs., 16 tabs.

Pan, W.P.; Riley, J.T.; Lloyd, W.G.

1995-08-03T23:59:59.000Z

12

Method of removal of sulfur from coal and petroleum products  

DOE Patents [OSTI]

A method for the removal of sulfur from sulfur-bearing materials such as coal and petroleum products using organophosphine and organophosphite compounds is provided.

Verkade, John G. (Ames, IA); Mohan, Thyagarajan (Ames, IA); Angelici, Robert J. (Ames, IA)

1995-01-01T23:59:59.000Z

13

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 2: SOx/Nox/Hg Removal for High Sulfur Coal  

SciTech Connect (OSTI)

The goal of this project is to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxy-combustion technology. The objective of Task 2 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning high sulfur coal in oxy-combustion power plants. The goal of the program was not only to investigate a new method of flue gas purification but also to produce useful acid byproduct streams as an alternative to using a traditional FGD and SCR for flue gas processing. During the project two main constraints were identified that limit the ability of the process to achieve project goals. 1) Due to boiler island corrosion issues >60% of the sulfur must be removed in the boiler island with the use of an FGD. 2) A suitable method could not be found to remove NOx from the concentrated sulfuric acid product, which limits sale-ability of the acid, as well as the NOx removal efficiency of the process. Given the complexity and safety issues inherent in the cycle it is concluded that the acid product would not be directly saleable and, in this case, other flue gas purification schemes are better suited for SOx/NOx/Hg control when burning high sulfur coal, e.g. this project's Task 3 process or a traditional FGD and SCR.

Nick Degenstein; Minish Shah; Doughlas Louie

2012-05-01T23:59:59.000Z

14

Innovative Clean Coal Technology (ICCT): Demonstration of selective catalytic reduction technology for the control of nitrogen oxide emissions from high-sulfur coal-fired boilers. First and second quarterly technical progress reports, [January--June 1995]. Final report  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia (NH{sub 3}) into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor containing a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe on gas-, oil-, and low-sulfur coal-fired boilers, there are several technical uncertainties associated with applying SCR to US coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in US coals that are not present in other fuels. (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}. (3) performance of a wide variety of SCR catalyst compositions, geometries, and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties are being explored by operating a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur US coal. The demonstration is being performed at Gulf Power Company`s Plant Crist Unit No. 5 (75 MW nameplate capacity) near Pensacola, Florida. The project is funded by the US Department of Energy (DOE), Southern Company Services, Inc. (SCS on behalf of the entire Southern electric system), the Electric Power Research Institute (EPRI), and Ontario Hydro. SCS is the participant responsible for managing all aspects of this project.

NONE

1995-12-31T23:59:59.000Z

15

Innovative Clean Coal Technology (ICCT). Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers: Volume 1. Final report  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from U.S., Japanese and European catalyst suppliers on a high-sulfur U.S. coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO.) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO. to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe on gas-, oil-, and low-sulfur coal- fired boilers, there are several technical uncertainties associated with applying SCR to U.S. coals. These uncertainties include: 1) potential catalyst deactivation due to poisoning by trace metal species present in U.S. coals that are not present in other fuels. 2) performance of the technology and effects on the balance-of- plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}. 3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacturer under typical high-sulfur coal-fired utility operating conditions. These uncertainties were explored by operating nine small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U.S. coal. In addition, the test facility operating experience provided a basis for an economic study investigating the implementation of SCR technology.

NONE

1996-10-01T23:59:59.000Z

16

Process for removing sulfur from coal  

DOE Patents [OSTI]

A process is disclosed for the removal of divalent organic and inorganic sulfur compounds from coal and other carbonaceous material. A slurry of pulverized carbonaceous material is contacted with an electrophilic oxidant which selectively oxidizes the divalent organic and inorganic compounds to trivalent and tetravalent compounds. The carbonaceous material is then contacted with a molten caustic which dissolves the oxidized sulfur compounds away from the hydrocarbon matrix.

Aida, T.; Squires, T.G.; Venier, C.G.

1983-08-11T23:59:59.000Z

17

Innovative clean coal technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Fourth quarterly progress report  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe, there are numerous technical uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in US coals that are not present in other fuels; (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}; and (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties will be explored by constructing a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur US coal.

NONE

1992-12-31T23:59:59.000Z

18

Management of high sulfur coal combustion residues, issues and practices: Proceedings  

SciTech Connect (OSTI)

Papers presented at the following sessions are included in this proceedings: (1) overview topic; (2) characterization of coal combustion residues; (3) environmental impacts of residues management; (4) materials handling and utilization, Part I; and (5) materials handling and utilization, Part II. Selected paper have been processed separately for inclusion in the Energy Science and Technology Database.

Chugh, Y.P.; Beasley, G.A. [eds.

1994-10-01T23:59:59.000Z

19

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NOx) emissions from high-sulfur coal-fired boilers  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to convert it to nitrogen and water vapor.

Not Available

1991-11-01T23:59:59.000Z

20

Innovative clean coal technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Quarterly report No. 3, January--March 1991  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1991-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Innovative clean coal technology (ICCT): Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO sub x ) emissions from high-sulfur coal-fired boilers  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1991-07-01T23:59:59.000Z

22

Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Quarterly report No. 6, October--December, 1991  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1992-02-01T23:59:59.000Z

23

Innovative Clean Coal Technology (ICCT): Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO sub x ) emissions from high-sulfur coal-fired boilers  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from US, Japanese and European catalyst suppliers on a high-sulfur US coal-fired boiler. SCR is a post-combustion nitrogen oxide (NOx) control technology that involves injecting ammonia into the flue gas generated from coal combustion in an electric utility boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NOx to convert it to nitrogen and water vapor.

Not Available

1992-02-01T23:59:59.000Z

24

Process for removing pyritic sulfur from bituminous coals  

DOE Patents [OSTI]

A process is provided for removing pyritic sulfur and lowering ash content of bituminous coals by grinding the feed coal, subjecting it to micro-agglomeration with a bridging liquid containing heavy oil, separating the microagglomerates and separating them to a water wash to remove suspended pyritic sulfur. In one embodiment the coal is subjected to a second micro-agglomeration step.

Pawlak, Wanda (Edmonton, CA); Janiak, Jerzy S. (Edmonton, CA); Turak, Ali A. (Edmonton, CA); Ignasiak, Boleslaw L. (Edmonton, CA)

1990-01-01T23:59:59.000Z

25

Co-firing high sulfur coal with refuse derived fuels. Progress report No. 3, [April--June 1995  

SciTech Connect (OSTI)

The Thermogravimetric Analyzer-Fourier Transform Infrared Spectrometer-Mass Spectrometer (TG-FTIR-MS) system was used to identify molecular chlorine, along with HCl, CO, CO{sub 2}, H{sub 2}O, and various hydrocarbons in the gaseous products of the combustion of PVC resin in air. This is a significant finding that will lead us to examine this combustion step further to look for the formation of chlorinated organic compounds. The combination of TG-FTIR and TG-MS offers complementary techniques for the detection and identification of combustion products from coals PVC, cellulose, shredded newspaper, and various blends of these materials. The pilot atmospheric fluidized bed combustor (AFBC) at Western Kentucky University has been tested. The main purpose of these preliminary AFBC runs were to determine the compatibility of coal and pelletized wood in blends and to explore the effects of flue/air ratio. Our objective is to conduct AFBC burns with 90 percent sulfur capture and more then 96% combustion efficiency.

Pan, Wei-Ping; Riley, J.T.; Lloyd, W.G.

1995-05-31T23:59:59.000Z

26

Geologic controls on sulfur content of the Blue Gem coal seam, southeastern Kentucky  

SciTech Connect (OSTI)

Detailed petrographic and lithologic data on the Blue Gem coal seam for a local area in Knox County, Kentucky, suggest that a relationship may exist between overlying roof lithology, petrographic composition of the coal, and sulfur content. In the western part of the area, where thick (20-40 feet) shale sequences overlie the coal, sulfur contents are low (less than 1%). In isolated areas where discontinuous sandstones occur within 6 feet of the coal, sulfur contents range from 1% to over 3%. In the east, a sandstone body usually overlies and frequently scours out the coal, yet sulfur content varies independently of roof lithology. Towards the east, there is an increase in abundance, thickness and variability of fusain bands within the coal and an increase in pyrite and siderite either as cell fillings in fusinite or as masses within vitrinite; early emplacement of these minerals is indicated by compaction features. Data suggest the importance of depositional environment of the peat and overlying sediments as a control on sulfur occurrence. High sulfur contents in the west are related to sandstone bodies which may have allowed sulfate-bearing waters to permeate into the peat. In the east, where increases in pyrite, siderite and fusain content of the coal and coarsening of the overlying sediments suggest a change in environment, the presence or absence of pyrite-containing fusain bands may account for sulfur variability. Siderite occurrence may reflect local fluctuations in sulfate supply to the peat swamp.

Rimmer, S.M.; Moore, T.A.; Esterle, J.S.; Hower, J.C.

1985-01-01T23:59:59.000Z

27

Effects of paleolatitude on coal quality - model for organic sulfur distribution in US coal  

SciTech Connect (OSTI)

In the conterminous US, most Carboniferous peats accumulated at latitudes of 0/degrees/-15/degrees/S, Cretaceous Rocky Mountain province peats at 30/degrees/-45/degrees/N, Tertiary northern Great Plains peats at 40/degrees/-55/degrees/N, and Tertiary Gulf Coast peats at 30/degrees/-40/degrees/N. Alaskan Cretaceous and Tertiary peats accumulated at latitudes above 70/degrees/N. A comparison of paleolatitudes calculated from paleomagnetic poles and organic sulfur contents for more than 7000 coal samples indicates that the higher the latitude in which a peat swamp developed, the lower the mean organic sulfur content of the subsequent coal (correlation coefficient - 0.4; significant at the 99% confidence level). Mean organic sulfur contents range from 0.90% (range = 0.01-5.08%, standard deviation = 0.56) in low-latitude Carboniferous coal to 0.25% (range = 0.01-1.41%, standard deviation = 0.23) in high-latitude Alaskan Cretaceous and Tertiary coal.

Affolter, R.H.; Stricker, G.D.

1989-03-01T23:59:59.000Z

28

Demonstration of Selective Catalytic Reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Technical progress report, first and second quarters 1994  

SciTech Connect (OSTI)

The objective of this project is to demonstrate and evaluate commercially available Selective Catalytic Reduction (SCR) catalysts from U.S., Japanese and European catalyst suppliers on a high-sulfur U.S. coal-fired boiler. SCR is a post-combustion nitrogen oxide (NO{sub x}) control technology that involve injecting ammonia into the flue gas generated from coal combustion in a boiler. The flue gas containing ammonia is then passed through a reactor that contains a specialized catalyst. In the presence of the catalyst, the ammonia reacts with NO{sub x} to form nitrogen and water vapor. Although SCR is widely practiced in Japan and Europe on gas-, oil-, and low-sulfur coal-fired boilers, there are several technical uncertainties associated with applying SCR to U.S. coals. These uncertainties include: (1) potential catalyst deactivation due to poisoning by trace metal species present in U.S. coals that are not present in other fuels; (2) performance of the technology and effects on the balance-of-plant equipment in the presence of high amounts of SO{sub 2} and SO{sub 3}; and (3) performance of a wide variety of SCR catalyst compositions, geometries and methods of manufacture under typical high-sulfur coal-fired utility operating conditions. These uncertainties are being explored by operating a series of small-scale SCR reactors and simultaneously exposing different SCR catalysts to flue gas derived from the combustion of high sulfur U.S. coal. The project is being conducted in the following three phases: permitting, environmental monitoring plan and preliminary engineering; detailed design engineering and construction; and operation, testing, disposition and final report. The project was in the operation and testing phase during this reporting period. Accomplishments for this period are described.

NONE

1995-11-01T23:59:59.000Z

29

NONEQUILIBRIUM SULFUR CAPTURE & RETENTION IN AN AIR COOLED SLAGGING COAL COMBUSTOR  

SciTech Connect (OSTI)

Calcium oxide injected in a slagging combustor reacts with the sulfur from coal combustion to form sulfur-bearing particles. The reacted particles impact and melt in the liquid slag layer on the combustor wall by the centrifugal force of the swirling combustion gases. Due to the low solubility of sulfur in slag, it must be rapidly drained from the combustor to limit sulfur gas re-evolution. Prior analyses and laboratory scale data indicated that for Coal Tech's 20 MMBtu/hour, air-cooled, slagging coal combustor slag mass flow rates in excess of 400 lb/hr should limit sulfur re-evolution. The objective of this 42-month project was to validate this sulfur-in-slag model in a group of combustor tests. A total of 36 days of testing on the combustor were completed during the period of performance of this project. This was more that double the 16 test days that were required in the original work statement. The extra tests were made possible by cost saving innovations that were made in the operation of the combustor test facility and in additional investment of Coal Tech resources in the test effort. The original project plan called for two groups of tests. The first group of tests involved the injection of calcium sulfate particles in the form of gypsum or plaster of Paris with the coal into the 20 MMBtu/hour-combustor. The second group of tests consisted of the entire two-step process, in which lime or limestone is co-injected with coal and reacts with the sulfur gas released during combustion to form calcium sulfate particles that impact and dissolve in the slag layer. Since this sulfur capture process has been validated in numerous prior tests in this combustor, the primary effort in the present project was on achieving the high slag flow rates needed to retain the sulfur in the slag.

Bert Zauderer

2003-04-21T23:59:59.000Z

30

Sulfur meter for blending coal at Plant Monroe: Final report  

SciTech Connect (OSTI)

An on-line sulfur analyzer, installed at the Detroit Edison, Monroe Power station, was placed into service and evaluated for coal blending optimization to minimize the cost of complying with changing stack gas sulfur dioxide regulations. The project involved debugging the system which consisted of an /open quotes/as-fired/close quotes/ sampler and nuclear source sulfur analyzer. The system was initially plagued with mechanical and electronic problems ranging from coal flow pluggages to calibration drifts in the analyzer. Considerable efforts were successfully made to make the system reliable and accurate. On-line testing showed a major improvement in control of sulfur dioxide emission rates and fuel blending optimization equivalent to as much as $6 million in fuel costs at the time of the evaluation. 7 refs., 14 figs., 12 tabs.

Trentacosta, S.D.; Yurko, J.O.

1988-04-01T23:59:59.000Z

31

Co-firing High Sulfur Coal with Refuse Derived Fuels. Technical Progress Report {number_sign}11  

SciTech Connect (OSTI)

The objective of this quarter of study was to prepare fuel pellets containing PVC, newspaper and plastics to be co-fired with coal in the AFBC combustor. The Western Kentucky University atmospheric fluidized bed combustion system requires the fuel to fall from a bunker into a lock-hopper, and from there into a mixing box where the fuel is auger-fed under pressure into the bottom of the fluidized bed. The fuel must flow freely out of the bunker and through the lock- hopper for proper feeding into the combustor. In order for the fuel to continuously fall through these units and into the mixing box during combustion, the density of the fuel and the size of the particles must meet certain requirements. The particles must be no larger than 3/8 inches in diameter and must have a density approaching that of coal. Loose materials such as sawdust, shredded paper products and most shredded plastics do not feed properly in the WKU AFBC system. Bridging and blockage of feed chutes result, even with constant vibration of parts of the feed mechanism. It is not possible to run the AFBC system powered solely by these loose materials.

Pan, Wei-Ping; Riley, John T.; Lloyd, William G.

1997-05-31T23:59:59.000Z

32

Co-firing high sulfur coal with refuse derived fuels. Technical progress report No. 8, July 1996--August 1996  

SciTech Connect (OSTI)

The objective of this study was to examine the possible formation of chlorinated organic compounds during the combustion of blends of refuse derived fuels (RDF) and coal under conditions similar to those of an atmospheric fluidized bed combustion (AFBC) system. A series of experiments were conducted using a TGA interfaced to FTIR. Additional experiments using a tube furnace preheated to AFBC operating temperatures were also conducted. The combustion products were cryogenically trapped and analyzed with a GC/MS system. The chlorination of phenols and the condensation reactions of chlorophenols were investigated in this study. A possible mechanism for the formation of chlorinated organic compounds such as dibenzodioxins and dibenzofurans, by chlorination and condensation reactions involving phenols, was proposed.

Pan, Wei-Ping; Riley, J.T.; Lloyd, W.G.

1996-08-31T23:59:59.000Z

33

Co-firing high sulfur coal with refuse derived fuels. Technical progress report No. 5, [October--December 1995  

SciTech Connect (OSTI)

Studies involving the tubular furnace are in the process of identifying the ideal experimental coal-to-refuse derived fuel(RDF) ratio for use in the AFBC system. A series of experiments with this furnace has been performed to determine the possible chemical pathway for formation of chlorinated organic compounds during the combustion of various RDF sources. Phenol and chlorine appear to be likely reactants necessary for the formation of these compounds. The main goal of these experiment is to determine the exact experimental conditions for the formation of chlorinated organic compounds, as well as methods to inhibit their development. Work on the fluidized bed combustor has involved five combustion runs, in which a combustion efficiency of greater than 96% and with a consistent CO{sub 2} concentration of approximately 13% was obtained. Modifications responsible for these improvements include the addition of the underbed fuel feed system and revision of the flue gas sampling system. New methods of determining combustion efficiency and percentage of SO{sub 2} capture using TG techniques to analyze combustion products are being developed. The current outlook using this TGA/FTIR method is very promising, since previously obscured reactions are being studied. the analysis of combustion products is revealing a more complete picture of the combustion process within the AFBC system.

Pan, Wei-Ping; Riley, J.T.; Lloyd, W.G.

1995-11-30T23:59:59.000Z

34

Dependence of liquefaction behavior on coal characteristics. Part VI. Relationship of liquefaction behavior of a set of high sulfur coals to chemical structural characteristics. Final technical report, March 1981 to February 1984  

SciTech Connect (OSTI)

The initial aim of this research was to use empirical mathematical relationships to formulate a better understanding of the processes involved in the liquefaction of a set of medium rank high sulfur coals. In all, just over 50 structural parameters and yields of product classes were determined. In order to gain a more complete understanding of the empirical relationships between the various properties, a number of relatively complex statistical procedures and tests were applied to the data, mostly selected from the field of multivariate analysis. These can be broken down into two groups. The first group included grouping techniques such as non-linear mapping, hierarchical and tree clustering, and linear discriminant analyses. These techniques were utilized in determining if more than one statistical population was present in the data set; it was concluded that there was not. The second group of techniques included factor analysis and stepwise multivariate linear regressions. Linear discriminant analyses were able to show that five distinct groups of coals were represented in the data set. However only seven of the properties seemed to follow this trend. The chemical property that appeared to follow the trend most closely was the aromaticity, where a series of five parallel straight lines was observed for a plot of f/sub a/ versus carbon content. The factor patterns for each of the product classes indicated that although each of the individual product classes tended to load on factors defined by specific chemical properties, the yields of the broader product classes, such as total conversion to liquids + gases and conversion to asphaltenes, tended to load largely on factors defined by rank. The variance explained and the communalities tended to be relatively low. Evidently important sources of variance have still to be found.

Neill, P. H.; Given, P. H.

1984-09-01T23:59:59.000Z

35

Alaska has 4. 0 trillion tons of low-sulfur coal: Is there a future for this resource  

SciTech Connect (OSTI)

The demand for and use of low-sulfur coal may increase because of concern with acid rain. Alaska's low-sulfur coal resources can only be described as enormous: 4.0 trillion tons of hypothetical onshore coal. Mean total sulfur content is 0.34% (range 0.06-6.6%, n = 262) with a mean apparent rank of subbituminous B. There are 50 coal fields in Alaska; the bulk of the resources are in six major fields or regions: Nenana, Cook Inlet, Matanuska, Chignik-Herendeen Bay, North Slope, and Bering River. For comparison, Carboniferous coals in the Appalachian region and Interior Province have a mean total sulfur content of 2.3% (range 0.1-19.0%, n = 5,497) with a mean apparent rank of high-volatile A bituminous coal, and Rocky Mountain and northern Great Plains Cretaceous and Tertiary coals have a mean total sulfur content of 0.86% (range 0.02-19.0%, n = 2,754) with a mean apparent rank of subbituminous B. Alaskan coal has two-fifths the total sulfur of western US coals and one-sixth that of Carboniferous US coals. Even though Alaska has large resources of low-sulfur coal, these resources have not been developed because of (1) remote locations and little infrastructure, (2) inhospitable climate, and (3) long distances to potential markets. These resources will not be used in the near future unless there are some major, and probably violent, changes in the world energy picture.

Stricker, G.D. (Geological Survey, Denver, CO (USA))

1990-05-01T23:59:59.000Z

36

Control of Sulfur Dioxide Emissions from Pulverized Coal-Fired Boilers by Dry Removal with Lime and Limestone Sorbants  

E-Print Network [OSTI]

sulfur content is highly dependent upon coal type. In gen~ral, conventional coal cleaning does not effect sufficient sulfur reduction to permit combustion without! i additional flue gas desulfurization. Several novel technologies now under development..., or equilibrium limita tions requires that super stoichiometric quantities of CaO be charged to the boiler. Operationally the introduction of large amounts of calcium additive can pose increased problems due to slagging and fouling in the combustion chamber...

Schwartz, M. H.

1979-01-01T23:59:59.000Z

37

A novel coal feeder for production of low sulfur fuel  

SciTech Connect (OSTI)

A dual-screw feeder was designed for desulfurization of coal. This reactor contains two screw tubes, the inner tube acting as a coal pyrolizer and the outer tube acting as a desulfurizer with hot calcined lime pellets or other renewable sorbent pellets. The objectives of this project is to study the feasibility of an advanced concept of desulfurization and possibly some denitrification in this coal feeder. In this year, two basic studies have been performed: (1) the desulfurization and (2) the denitrification due to mild pyrolysis. Specifically, the following tasks have been performed: (1) Setting up the Dual-Screw reactor, (2) Determination of the pyrolysis product and the sulfur distribution in char, tar and gas based on experimental data, (3) Study of the devolatilization, the desulfurization kinetics and the denitrification kinetics and obtaining the basic kinetic parameters, (4) Study of the sulfur removal efficiency of lime pellets fed into the outer tube of the dual-feeder reactor, (5) Study of the effect of the coal particle size on pyrolysis and desulfurization, (6) Study of the coal pyrolysis and desulfurization using a TGA(Thermal Gravimetric Analyzer).

Khang, S.J.; Lin, L.; Keener, T.C.; Yeh, P.

1991-01-01T23:59:59.000Z

38

VHF EPR analysis of organic sulfur in coal. Technical report, December 1, 1991--February 29, 1992  

SciTech Connect (OSTI)

This is a report of the second quarter of a two-year investigation exploiting electron paramagnetic resonance (EPR), especially novel, very high frequency (VHF) spectroscopy techniques and instrumentation (the only high-modulation W-band EPR spectrometer in the world) developed earlier by these authors, to conduct further qualitative and quantitative studies of heteroatomic organic molecules in coal with particular emphasis on sulfur. New model compounds have been prepared in EPR-active forms and surveyed with X-band EPR. Previous W-band (96 GHz) VHF-EPR work is being extended to studies of these new model compounds as well as to a variety of coal and desulfurized coal samples. Typically, the model compounds under investigation and their analogues are found in coals as stable free radicals which give rise to an EPR signal.

Clarkson, R.B.; Belford, R.L.

1992-08-01T23:59:59.000Z

39

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash coat, and catalytic metals, to develop a regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor. The task of developing kinetic rate equations and modeling the direct oxidation process to assist in the design of large-scale plants will be abandoned since formulation of catalysts suitable for the removal of H{sub 2}S and COS is being in progress. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 46-570 seconds under reaction conditions to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases and evaluate their capabilities in reducing hydrogen sulfide and COS in coal gases. Simulated coal gas mixtures consist of 3,200-4,000-ppmv hydrogen sulfide, 1,600-20,000-ppmv sulfur dioxide, 18-27 v% hydrogen, 29-41 v% CO, 8-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of simulated coal gas mixtures to the reactor are 30 - 180 cm{sup 3}/min at 1 atm and 25 C (SCCM). The temperature of the reactor is controlled in an oven at 120-155 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio

K.C. Kwon

2009-09-30T23:59:59.000Z

40

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. Experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 130-156 seconds at 120-140 C to formulate catalysts suitable for the removal of H{sub 2}S and COS from coal gases, evaluate removal capabilities of hydrogen sulfide and COS from coal gases with formulated catalysts, and develop an economic regeneration method of deactivated catalysts. Simulated coal gas mixtures consist of 3,300-3,800-ppmv hydrogen sulfide, 1,600-1,900 ppmv sulfur dioxide, 18-21 v% hydrogen, 29-34 v% CO, 8-10 v% CO{sub 2}, 5-18 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 114-132 SCCM. The temperature of the reactor is controlled in an oven at 120-140 C. The pressure of the reactor is maintained at 116-129 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is

K. C. Kwon

2007-09-30T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Vhf EPR quantitation and speciation of organic sulfur in coal. [Quarterly] technical report, December 1, 1993--February 28, 1994  

SciTech Connect (OSTI)

The existence of free electrons in coals` natural site offers a great attraction for Electron Paramagnetic Resonance (EPR) analysis to aid in the study of the structure and composition of coal. This direct and non-destructive approach to coal analysis has been hindered by the problem of resolution using the conventional 9.5 GHz EPR spectrometers. In the past few years, we have developed techniques including W-band Very High Frequency EPR spectroscopy as a means of determining the quantity and structure of organic sulfur in native and desulfurized coals. The state of the art 95 GHz (W-band) EPR spectrometer which we have constructed shows a well resolved spectrum including the interaction between unpaired electrons and the heteroatom like sulfur. The spectra also provide quantitative as well as qualitative information regarding different sulfur species. In collaboration with researchers at the University of Kentucky, we are also analyzing the result of desulfurization techniques on the presence of various sulfur species in coal. In the past, we have tried to synthesize various model compounds comparing their W-band spectra with other models, the predictions of theoretical models, and with the W-band spectra of coal specimens. In this quarter, we have been concentrating our efforts on developing a new standard protocol in handling and preparing the coal samples for EPR measurements to provide a quantitative comparison between the EPR spectra of coal in the natural state and desulfurized. Ten coal samples, both native and desulfurized, have been provided to us. These samples have been run in both laboratories. The simulation of coal EPR spectra has been carried out using several mathematical models. EPR results now are being compared with XANES data.

Clarkson, R.B.; Belford, R.I. [Illinois Univ., Urbana, IL (United States)

1994-06-01T23:59:59.000Z

42

Kinetics of Direct Oxidation of H2S in Coal Gas to Elemental Sulfur  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced Vision 21 plants that produce electric power and clean transportation fuels with coal and natural gas. These Vision 21 plants will require highly clean coal gas with H{sub 2}S below 1 ppm and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation Vision 21 plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2}S in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. The direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The objectives of this research are to measure kinetics of direct oxidation of H{sub 2}S to elemental sulfur in the presence of a simulated coal gas mixture containing SO{sub 2}, H{sub 2}, and moisture, using 160-{micro}m C-500-04 alumina catalyst particles and 400 square cells/inch{sup 2}, {gamma}-Al{sub 2}O{sub 3}-wash-coated monolithic catalyst, and various reactors such as a micro packed-bed reactor, a micro bubble reactor, and a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam.

K.C. Kwon

2005-11-01T23:59:59.000Z

43

Conversion of Hydrogen Sulfide in Coal Gases to Liquid Elemental Sulfur with Monolithic Catalysts  

SciTech Connect (OSTI)

Removal of hydrogen sulfide (H{sub 2}S) from coal gasifier gas and sulfur recovery are key steps in the development of Department of Energy's (DOE's) advanced power plants that produce electric power and clean transportation fuels with coal and natural gas. These plants will require highly clean coal gas with H{sub 2}S below 1 ppmv and negligible amounts of trace contaminants such as hydrogen chloride, ammonia, alkali, heavy metals, and particulate. The conventional method of sulfur removal and recovery employing amine, Claus, and tail-gas treatment is very expensive. A second generation approach developed under DOE's sponsorship employs hot-gas desulfurization (HGD) using regenerable metal oxide sorbents followed by Direct Sulfur Recovery Process (DSRP). However, this process sequence does not remove trace contaminants and is targeted primarily towards the development of advanced integrated gasification combined cycle (IGCC) plants that produce electricity (not both electricity and transportation fuels). There is an immediate as well as long-term need for the development of cleanup processes that produce highly clean coal gas for next generation power plants. To this end, a novel process is now under development at several research organizations in which the H{sub 2} in coal gas is directly oxidized to elemental sulfur over a selective catalyst. Such a process is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S In the Single-Step Sulfur Recovery Process (SSRP), the direct oxidation of H{sub 2}S to elemental sulfur in the presence of SO{sub 2} is ideally suited for coal gas from commercial gasifiers with a quench system to remove essentially all the trace contaminants except H{sub 2}S. This direct oxidation process has the potential to produce a super clean coal gas more economically than both conventional amine-based processes and HGD/DSRP. The H{sub 2} and CO components of syngas appear to behave as inert with respect to sulfur formed at the SSRP conditions. One problem in the SSRP process that needs to be eliminated or minimized is COS formation that may occur due to reaction of CO with sulfur formed from the Claus reaction. The objectives of this research are to formulate monolithic catalysts for removal of H{sub 2}S from coal gases and minimum formation of COS with monolithic catalyst supports, {gamma}-alumina wash or carbon coats, and catalytic metals, to develop a catalytic regeneration method for a deactivated monolithic catalyst, to measure kinetics of both direct oxidation of H{sub 2}S to elemental sulfur with SO{sub 2} as an oxidizer and formation of COS in the presence of a simulated coal gas mixture containing H{sub 2}, CO, CO{sub 2}, and moisture, using a monolithic catalyst reactor, and to develop kinetic rate equations and model the direct oxidation process to assist in the design of large-scale plants. This heterogeneous catalytic reaction has gaseous reactants such as H{sub 2}S and SO{sub 2}. However, this heterogeneous catalytic reaction has heterogeneous products such as liquid elemental sulfur and steam. To achieve the above-mentioned objectives using a monolithic catalyst reactor, experiments on conversion of hydrogen sulfide into elemental sulfur and formation of COS were carried out for the space time range of 40-560 seconds at 120-150 C to evaluate effects of reaction temperatures, total pressure, space time, and catalyst regeneration on conversion of hydrogen sulfide into elemental sulfur and formation of COS. Simulated coal gas mixtures consist of 3,600-4,000-ppmv hydrogen sulfide, 1,800-2,000 ppmv sulfur dioxide, 23-27 v% hydrogen, 36-41 v% CO, 10-12 v% CO{sub 2}, 0-10 vol % moisture, and nitrogen as remainder. Volumetric feed rates of a simulated coal gas mixture to the reactor are 30-180 SCCM. The temperature of the reactor is controlled in an oven at 120-150 C. The pressure of the reactor is maintained at 40-210 psia. The molar ratio of H{sub 2}S to SO{sub 2} in the monolithic catalyst reactor is mai

K. C. Kwon

2006-09-30T23:59:59.000Z

44

Coal-firing sulfur coal with refuse derived fuels. Technical progress report {number_sign}7, [April--June 1996  

SciTech Connect (OSTI)

The objectives for this quarter of study on the co-firing of high sulfur coal with refuse derived fuels project were two-fold. First, the organic compounds tentatively identified as combustion products in the previous report were confirmed by comparing retention times with pure samples. Secondly, a reduced amount of unburned carbon in the fly ash and an oxygen concentration at about 3--6% in the flue gases were achieved by the addition of removable heat exchange tubes in the AFBC system.

Pan, Wei-Ping, Riley, J.T.; Lloyd, W.G.

1996-05-31T23:59:59.000Z

45

Biodesulfurization techniques: Application of selected microorganisms for organic sulfur removal from coals. Final report  

SciTech Connect (OSTI)

As an alternative to post-combustion desulfurization of coal and pre-combustion desulfurization using physicochemical techniques, the microbial desulfurization of coal may be accomplished through the use of microbial cultures that, in an application of various microbial species, may remove both the pyritic and organic fractions of sulfur found in coal. Organisms have been isolated that readily depyritize coal but often at prohibitively low rates of desulfurization. Microbes have also been isolated that may potentially remove the organic-sulfur fraction present in coal (showing promise when acting on organic sulfur model compounds such as dibenzothiophene). The isolation and study of microorganisms demonstrating a potential for removing organic sulfur from coal has been undertaken in this project. Additionally, the organisms and mechanisms by which coal is microbially depyritized has been investigated. Three cultures were isolated that grew on dibenzothiophene (DBT), a model organic-sulfur compound, as the sole sulfur source. These cultures (UMX3, UMX9, and IGTS8) also grew on coal samples as the sole sulfur source. Numerous techniques for pretreating and ``cotreating`` coal for depyritization were also evaluated for the ability to improve the rate or extent of microbial depyritization. These include prewashing the coal with various solvents and adding surfactants to the culture broth. Using a bituminous coal containing 0.61% (w/w) pyrite washed with organic solvents at low slurry concentrations (2% w/v), the extent of depyritization was increased approximately 25% in two weeks as compared to controls. At slurry concentrations of 20% w/v, a tetrachloroethylene treatment of the coal followed by depyritization with Thiobacillus ferrooxidans increased both the rate and extent of depyritization by approximately 10%.

Elmore, B.B.

1993-08-01T23:59:59.000Z

46

VHF EPR quantitation and speciation of organic sulfur in coal. Technical report, September 1, 1993--November 30, 1993  

SciTech Connect (OSTI)

Over the last few years, we have developed a non-destructive technique called Very High Frequency Electron Paramagnetic Resonance (VHF-EPR) that is proving to be a practical and very sensitive analytical method for the organic sulfur in coal. Already, although still under development, the technique rapidly can quantify organic sulfur, and perhaps provide information on organic oxygen and nitrogen, in typical Illinois coals. At this stage, the precision is not well enough calibrated, and specificity for particular species needs more development. This year`s proposal outlined a 12 month work plan designed to improve and extend the utility of VHF-EPR. Two main goals of the work are: (1) refinement and calibration of organic sulfur analysis, in coals of differing rank, over a concentration range from 0.1% to 5%, and (2) better utilization of VHF-EPR coal spectral data for sulfur speciation. This quarter, goal (1) is being pursued; results will be ready to describe in a future report. Meanwhile, work toward goal (2) has produced detailed information about the VHF-EPR spectral behavior of several comparison compounds -- sulfur -- containing thiophenic fused-ring molecules.

Clarkson, R.B.; Belford, R.L. [Illinois Univ., Urbana, IL (United States)

1993-12-31T23:59:59.000Z

47

VHF EPR quantitation and speciation of organic sulfur in coal. Technical report, 1 March--31 May 1994  

SciTech Connect (OSTI)

The existence of free electrons in coals` natural state offers a great attraction for Electron Paramagnetic Resonance (EPR) analysis to aid in the study of the structure and composition of coal. This direct and non-destructive approach to coal analysis has been hindered by the problem of resolution using the conventional 9.5 GHz EPR spectrometers. In the past few years, the authors have developed techniques including W-band Very High Frequency EPR spectroscopy as a means of determining the quantity and structure of organic sulfur in native and desulfurized coals. The state-of-the-art 95 GHz (W-band) EPR spectrometer which they have constructed shows a well resolved spectrum including the interaction between unpaired electrons and the heteroatom like sulfur. The spectra also provide quantitative as well as qualitative information regarding different sulfur species. In this quarter, the authors have been concentrating their efforts on developing a new standard protocol in handling and preparing the coal samples for EPR measurements to provide a quantitative comparison between the EPR spectra of coal in the natural state and desulfurized. Sixteen new coal samples, both native and desulfurized, have been provided to us as well as to the University of Kentucky for analysis by XANES. These samples have been run in both laboratories. The results from these samples, which were kept in an oxygen-free environment, are compared to those of 10 previous samples, which were air-oxidized. Significant differences in the EPR spectra of air-oxidized and oxygen free samples are noted; results from Kentucky are not yet available. Desulfurized samples show a significant decrease in organic sulfur as measured by the VHF-EPR method.

Clarkson, R.B.; Belford, R.L.

1994-09-01T23:59:59.000Z

48

The use of ethanol to remove sulfur from coal. Final report, September 1991--December 1992; Revision  

SciTech Connect (OSTI)

The initial technical goal in the project was to develop a chemical method for the cost effective removal of both inorganic and organic sulfur from Ohio coals. Verifying and using a process of reacting ethanol vapors with coal under conditions disclosed in U.S. Patent 4,888,029, the immediate technical objectives were to convert a small scale laborative batch process to a larger scale continuous process which can serve as the basis for commercial development of the technology. This involved getting as much information as possible from small scale batch autoclave or fluid bed laboratory reactors for use in pilot plant studies. The laboratory data included material balances on the coal and sulfur, temperature and pressure ranges for the reaction, minimum reaction times at different conditions, the effectiveness of different activators such as oxygen and nitric oxide, the amount and nature of by-products such as sulfur dioxide, hydrogen sulfide and acetaldehyde, the effect of coal particle size on the speed and completeness of the reaction, and the effectiveness of the reaction on different Ohio coals. Because the laboratory experiments using the method disclosed in U.S. 4,888,029 were not successful, the objective for the project was changed to develop a new laboratory process to use ethanol to remove sulfur from coal. Using copper as a catalyst and as an H{sub 2}S scavenger, a new laboratory procedure to use ethanol to remove sulfur from coal has been developed at Ohio University and a patent application covering this process was filed in March, 1993. The process is based on the use of copper as a catalyst for the dehydrogenation of ethanol to produce nascent hydrogen to remove sulfur from the coal and the use of copper as a scavenger to capture the hydrogen sulfide formed from the sulfur removed from coal.

Savage, R.L.; Lazarov, L.K.; Prudich, M.E.; Lange, C.A.; Kumar, N.

1994-03-10T23:59:59.000Z

49

Behavior of sulfur and chlorine in coal during combustion and boiler corrosion. Final technical report, 1 September, 1992--31 August, 1993  

SciTech Connect (OSTI)

The goals of this project are to investigate the behavior of sulfur and chlorine during pyrolysis and combustion of Illinois coals, the chemistry and mineralogy of boiler deposits, the effects of combustion gases on boiler materials, and remedial measures to reduce the sulfur and chlorine compounds in combustion gases. Replicate determinations of chlorine and sulfur evolution during coal pyrolysis-gas combustion were conducted using a pyrolysis apparatus in conjunction with a quadrupole gas analyzer. HCl is the only gaseous chlorine species measured in combustion gases. Pyrolysis of coal IBC-109 spiked with NaCl solution shows a strong peak of HCl evolution above 700C. The absence of this peak during pyrolysis of Illinois coal indicates that little chlorine in Illinois coal occurs in the NaCl form. Evolution of sulfur during coal pyrolysis was studied; the sulfur evolution profile may be explained by the sulfur forms in coal. To determine the fate of sulfur and chlorine during combustion, a set of six samples of boiler deposits from superheater and reheater tubes of an Illinois power plant was investigated. Scanning electron microscopy shows microscopic calcium sulfate droplets on cenospheres. Superheater deposits are high in mullite, hematite, and cristobalite, whereas a reheater deposit is enriched in anhydrite. The chlorine content is very low, indicating that most of the chlorine in the feed coal is lost as volatile HCl during he combustion process. The profiles of SO{sub 2} released during combustion experiments at 825 C indicate that calcium hydroxide added to the coal has a significant effect on reducing the SO{sub 2} vapors in combustion gases.

Chou, C.L.; Hackley, K.C.; Cao, J.; Moore, D.M.; Xu, J.; Ruch, R.R. [Illinois State Geological Survey, Champaign, IL (United States); Pan, W.P.; Upchurch, M.L.; Cao, H.B. [Western Kentucky Univ., Bowling Green, KY (United States)

1993-12-31T23:59:59.000Z

50

Demonstration of selective catalytic reduction (SCR) technology for the control of nitrogen oxide (NO{sub x}) emissions from high-sulfur coal-fired boilers. Draft final report  

SciTech Connect (OSTI)

The primary goal of this project was to demonstrate the use of Selective Catalytic Reduction (SCR) to reduce NO{sub x} emissions from pulverized-coal utility boilers using medium- to high-sulfur US coal. The prototype SCR facility, built in and around the ductwork of Plant Crist Unit 5, consisted of three large SCR reactor units (Reactors A, B, and C), each with a design capacity of 5,000 standard cubic feet per minute (scfm) of flue gas, and six smaller reactors (Reactors D through J), each with a design capacity of 400 scfm of flue gas. The three large reactors contained commercially available SCR catalysts as offered by SCR catalyst suppliers. These reactors were coupled with small-scale air preheaters to evaluate (1) the long-term effects of SCR reaction chemistry on air preheater deposit formation and (2) the impact of these deposits on the performance of air preheaters. The small reactors were used to test additional varieties of commercially available catalysts. The demonstration project was organized into three phases: (1) Permitting, Environmental Monitoring Plan (EMP) Preparation, and Preliminary Engineering; (2) Detail Design Engineering and Construction; and (3) Operation, Testing, Disposition, and Final Report Preparation. Section 2 discusses the planned and actual EMP monitoring for gaseous, aqueous, and solid streams over the course of the SCR demonstration project; Section 3 summarizes sampling and analytical methods and discusses exceptions from the methods specified in the EMP; Section 4 presents and discusses the gas stream monitoring results; Section 5 presents and discusses the aqueous stream monitoring results; Section 6 presents and discusses the solid stream monitoring results; Section 7 discusses EMP-related quality assurance/quality control activities performed during the demonstration project; Section 8 summarizes compliance monitoring reporting activities; and Section 9 presents conclusions based on the EMP monitoring results.

NONE

1996-06-14T23:59:59.000Z

51

Coal Cleaning Using Resonance Disintegration for Mercury and Sulfur Reduction Prior to Combustion  

SciTech Connect (OSTI)

Coal-cleaning processes have been utilized to increase the heating value of coal by extracting ash-forming minerals in the coal. These processes involve the crushing or grinding of raw coal followed by physical separation processes, taking advantage of the density difference between carbonaceous particles and mineral particles. In addition to the desired increase in the heating value of coal, a significant reduction of the sulfur content of the coal fed to a combustion unit is effected by the removal of pyrite and other sulfides found in the mineral matter. WRI is assisting PulseWave to develop an alternate, more efficient method of liberating and separating the undesirable mineral matter from the carbonaceous matter in coal. The approach is based on PulseWave's patented resonance disintegration technology that reduces that particle size of materials by application of destructive resonance, shock waves, and vortex generating forces. Illinois No.5 coal, a Wyodak coal, and a Pittsburgh No.8 coal were processed using the resonance disintegration apparatus then subjected to conventional density separations. Initial microscopic results indicate that up to 90% of the pyrite could be liberated from the coal in the machine, but limitations in the density separations reduced overall effectiveness of contaminant removal. Approximately 30-80% of the pyritic sulfur and 30-50% of the mercury was removed from the coal. The three coals (both with and without the pyritic phase separated out) were tested in WRI's 250,000 Btu/hr Combustion Test Facility, designed to replicate a coal-fired utility boiler. The flue gases were characterized for elemental, particle bound, and total mercury in addition to sulfur. The results indicated that pre-combustion cleaning could reduce a large fraction of the mercury emissions.

Andrew Lucero

2005-04-01T23:59:59.000Z

52

Sulfur and ash in Paleocene Wyodak-Anderson coal in the Powder River Basin, Wyoming and Montana: A fuel source beyond 2000  

SciTech Connect (OSTI)

When coal-fired power plants are required by the Environmental Protection Agency (EPA) to meet more stringent sulfur emission standards (0.6 pound per million Btu) after the year 2000, most of the clean and compliant coals will come from the Powder River Basin in Wyoming and Montana. In 1996 more than 300 million short toms of these clean and compliant coals were produced from the Paleocene Fort Union Formation in the northern Rocky Mountains and Great Plans region. This is more than 30% of the total US coal production of 1.03 billion short tons in 1996. Future demand for clean and compliant coals can probably be met through production of more F or Union coals in the region. It is projected by the Energy Information Agency (1996) that most of the low-sulfur and low-ash coals in the northern Rocky Mountains and Great Plains region will be produced from the Wyodak-Anderson coal bed/zone of the Paleocene Fort Union Formation in the Powder River Basin. To date, coal produced from the Wyodak-Anderson coal bed/zone, containing 0.5% sulfur, 1.2 lb SO{sub 2} per million btu, and 6% ash (mean values on an as-received basis) meet current EPA regulatory compliance. This coal bed/zone alone produced 262 million short toms of >26% of the total US coal production in 1996. Based on the current consumption rates of coal and a forecast by the EIA (1996), the Wyodak-Anderson coals are projected to produce an additional 153 million short tons a year by the year 2016. At this rate of production, high quality Wyodak-Anderson coals may be adequate to fill future energy needs.

Ellis, M.S.; Stricker, G.D.; Flores, R.M.; Bader, L.R.

1998-07-01T23:59:59.000Z

53

Sulfur and ash in paleocene Wyodak-Anderson coal in the Powder River Basin, Wyoming and Montana: A fuel source beyond 2000  

SciTech Connect (OSTI)

When coal-fired power plants are required by the Environmental Protection Agency (EPA) to meet more stringent sulfur emission standards (0.6 pound per million Btu) after the year 2000, most of the clean and compliant coals will come from the Powder River Basin in Wyoming and Montana. In 1996 more than 300 million short tons of these clean and compliant coals were produced from the Paleocene Fort Union Formation in the northern Rocky Mountains and Great Plains region. This is more than 30 percent of the total US coal production of 1.03 billion short tons in 1996. Future demand for clean and compliant coals can probably be met through production of more Fort Union coals in the region. It is projected by the Energy Information Agency (1996) that most of the low-sulfur and low-ash coals in the northern Rocky Mountains and Great Plains region will be produced from the Wyodak-Anderson coal bed/zone of the Paleocene Fort Union Formation in the Powder River Basin. To date, coal produced from the Wyodak-Anderson coal bed/zone, containing 0.5 percent sulfur, 1.2 lb SO{sub 2} per million btu, and 6 percent ash (mean values on an as-received basis) meet current EPA regulatory compliance. This coal bed/zone alone produced 262 million short tons or >26 percent of the total U.S. coal production in 1996. Based on the current consumption rates of coal and a forecast by the EIA (1996), the Wyodak-Anderson coals are projected to produce an additional 153 million short tons a year by the year 2016. At this rate of production, high quality Wyodak-Anderson coals may be adequate to fill our future energy needs.

Ellis, M.S.; Stricker, G.D.; Flores, R.M.; Bader, L.R. [Geological Survey, Denver, CO (United States)

1998-04-01T23:59:59.000Z

54

Effect of Prussian blue on organic sulfur of coal in aqueous medium  

SciTech Connect (OSTI)

This study is an attempt to desulfurize organic sulfur from coal samples with ferric hexacyanoferrate (II), Fe{sub 4} (Fe(CN){sub 6}), as the desulfurization agent. Effect of temperature, particle size and concentration of ferrocyanide ion on desulfurization from the coal samples has been investigated. The temperature and stirring time are the most important parameters for the level of desulfurization of organic sulfur. Removal of organic sulfur content increased continuously with increasing temperature from 298 to 368 K. The organic sulfur removal rate sharply increases from 10 min to 30 min stirring time. After 30 min, it reaches a value of plateau. Particle size between -100 mesh and -200 mesh slightly affects the amount of organic sulfur removal. Gradual increase in the concentration of ferric hexacyanoferrate (II) raised the magnitude of desulfurization, but at higher concentration, the variation is not significant.

Demirbas, A. [Selcuk University, Konya (Turkey). Dept. of Chemical Engineering

2007-01-15T23:59:59.000Z

55

Additives and Cathode Materials for High-Energy Lithium Sulfur...  

Broader source: Energy.gov (indexed) [DOE]

Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries 2013 DOE Hydrogen and Fuel Cells...

56

The use of ethanol to remove sulfur from coal. Final report, September 1991--December 1992  

SciTech Connect (OSTI)

In developing the new Ohio University procedure the thermodynamic limitations of the reactions for removal of both pyritic and organic sulfur from coal at 400--600{degrees}C were studied using copper as a very strong H{sub 2}S-acceptor. Copper serves as a catalyst for ethanol dehydrogenation to form nascent hydrogen. Copper also serves as a scavenger to form copper sulfide from the hydrogen sulfide evolved during the reaction. Copper sulfide in turn serves as a catalyst for organic sulfur hydrodesulfurization reactions. If the coal to be desulfurized contains pyrite (FeS{sub 2}) or FeS, the copper scavenger effect reduces any back reaction of hydrogen sulfide with the iron and increases the removal of sulfur from the carbonaceous material. The desired effect of using copper can be achieved by using copper or copper containing alloys as materials of construction or as liners for a regenerable reactor. During the time period that Ohio Coal Development Office supported this work, small scale (560 grams) laboratory experiments with coals containing about 3.5% sulfur have achieved up to 90% desulfurization at temperatures of 500{degrees}C when using a copper reactor. Results from the autoclave experiments have identified the nature of the chemical reactions taking place. Because the process removes both pyritic and organic sulfur in coal, the successful scale up of the process would have important economic significance to the coal industry. Even though this and other chemical processes may be relatively expensive and far from being commercial, the reason for further development is that this process may hold the promise of achieving much greater sulfur reduction and of producing a cleaner coal than other methods. This would be especially important for small or older power plants and industrial boilers.

Not Available

1993-04-15T23:59:59.000Z

57

High-pressure coal fuel processor development  

SciTech Connect (OSTI)

The objective of Subtask 1.1 Engine Feasibility was to conduct research needed to establish the technical feasibility of ignition and stable combustion of directly injected, 3,000 psi, low-Btu gas with glow plug ignition assist at diesel engine compression ratios. This objective was accomplished by designing, fabricating, testing and analyzing the combustion performance of synthesized low-Btu coal gas in a single-cylinder test engine combustion rig located at the Caterpillar Technical Center engine lab in Mossville, Illinois. The objective of Subtask 1.2 Fuel Processor Feasibility was to conduct research needed to establish the technical feasibility of air-blown, fixed-bed, high-pressure coal fuel processing at up to 3,000 psi operating pressure, incorporating in-bed sulfur and particulate capture. This objective was accomplished by designing, fabricating, testing and analyzing the performance of bench-scale processors located at Coal Technology Corporation (subcontractor) facilities in Bristol, Virginia. These two subtasks were carried out at widely separated locations and will be discussed in separate sections of this report. They were, however, independent in that the composition of the synthetic coal gas used to fuel the combustion rig was adjusted to reflect the range of exit gas compositions being produced on the fuel processor rig. Two major conclusions resulted from this task. First, direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize these low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risks associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept.

Greenhalgh, M.L.

1992-11-01T23:59:59.000Z

58

Nonequilibrium sulfur capture and retention in an air cooled slagging coal combustor. Quarterly technical progress report, 1996  

SciTech Connect (OSTI)

The objective of this 24 month project is to determine the degree of sulfur retention in slag in a full scale cyclone coal combustor with sulfur capture by calcium oxide sorbent injection into the combustor. This sulfur capture process consists of two steps: Capture of sulfur with calcined calcium oxide followed by impact of the reacted sulfur-calcium particles on the liquid slag lining the combustor. The sulfur bearing slag must be removed within several minutes from the combustor to prevent re-evolution of the sulfur from the slag. To accomplish this requires slag mass flow rates in the range of several 100 lb/hr. To study this two step process in the combustor, two groups of tests are being implemented. In the first group, calcium sulfate in the form of gypsum, or plaster of Paris, was injected in the combustor to determine sulfur evolution from slag. In the second group, the entire process is tested with limestone and/or calcium hydrate injected into the combustor. This entire effort consists of a series of up to 16 parametric tests in a 20 MMtu/hr slagging, air cooled, cyclone combustor. During the present quarterly reporting period ending September 30,1996, three tests in this project were implemented, bringing the total tests to 5. In addition, a total of 10 test days were completed during this quarter on the parallel project that utilizes the same 20 MMtu/hr combustor. The results of that project, especially those related to improved slagging performance, have a direct bearing on this project in assuring proper operation at the high slag flow rates that may be necessary to achieve high sulfur retention in slag.

Zauderer, B.

1996-11-01T23:59:59.000Z

59

Adsorption of sulfur dioxide from coal combustion gases on natural zeolite  

SciTech Connect (OSTI)

In this study, better efficiency of SO{sub 2} removal in flue gas from lignite coal combustion by adding of NZ in the gas phase was achieved. Natural zeolite was exposed to flue gas containing sulfur dioxide at varying conditions of relative humidity and temperature. It was found that the amount of sulfate on the zeolite increased with increasing relative humidity and temperature. The percents of adsorbed sulfur dioxide were 86, 74, 56, and 35, while the values of relative humidity (RH) were 75, 60, 45, and 30% for 40 minutes, respectively. The percents of adsorbed sulfur dioxide sharply increased within the first 40 min for the values of RH were 75 and 60, and after 40 min, slightly increased, then reached a plateau. In general, as increasing the RH increased the amount of sulfur dioxide adsorbed by natural zeolite. The amounts of adsorbed sulfur dioxide increased with exposure time. It increased and reached 30.2 mg/g for 40 min. After 40 min, it slightly increased and then reached a plateau. The NZ adsorbs 35.1 mg SO{sub 2} per gram adsorbent with 75% RH at 298 K from a simulated coal combustion flue gas. The amounts of adsorbed sulfur dioxide increased with increasing temperature. The NZ adsorbs 71.5 mg SO{sub 2} per gram adsorbent with 75% RH for 100 min exposure time from the flue gas mixture.

Demirbas, A. [Selcuk University, Konya (Turkey). Dept. for Chemical Engineering

2006-10-15T23:59:59.000Z

60

Non-matrix corrected organic sulfur determination by energy dispersive X-ray spectroscopy for western Kentucky coals and residues  

SciTech Connect (OSTI)

A method for non-matrix corrected organic sulfur analysis by energy dispersive X-ray spectroscopy has been developed using petroleum coke standards. Typically, electron beam microanalysis is a rapid, nondestructive analytical technique to quantitatively measure organic sulfur in coal. The results show good correlation to ASTM values for numerous well characterized coals with a wide range in total and pyritic sulfur content. This direct analysis is capable of reducing error commonly associated with the present ASTM method which relies on an indirect measure of organic sulfur by difference. The precision of the organic sulfur values determined in the present study is comparable to that obtained by ZAF matrix corrected microanalysis. The energy dispersive microanalysis is capable of measuring micro as well as bulk organic sulfur levels.

Clark, C.P.; Freeman, G.B.; Hower, J.C.

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Documents & Publications CarbonSulfur Nanocomposites and Additives for High-Energy Lithium Sulfur Batteries Additives and Cathode Materials for High-Energy Lithium Sulfur...

62

Coal Liquefaction desulfurization process  

DOE Patents [OSTI]

In a solvent refined coal liquefaction process, more effective desulfurization of the high boiling point components is effected by first stripping the solvent-coal reacted slurry of lower boiling point components, particularly including hydrogen sulfide and low molecular weight sulfur compounds, and then reacting the slurry with a solid sulfur getter material, such as iron. The sulfur getter compound, with reacted sulfur included, is then removed with other solids in the slurry.

Givens, Edwin N. (Bethlehem, PA)

1983-01-01T23:59:59.000Z

63

Steam-Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture  

E-Print Network [OSTI]

looping gasification using a calcium oxide-carbonate cycle, in which a pure stream of CO2 is generatedSteam-Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture Nicholas S. Siefert operating a CaO-CaCO3 chemical looping gasification reactor. For example, the steam-coal gasification

Litster, Shawn

64

Coal-oil slurry preparation  

DOE Patents [OSTI]

A pumpable slurry of pulverized coal in a coal-derived hydrocarbon oil carrier which slurry is useful as a low-ash, low-sulfur clean fuel, is produced from a high sulfur-containing coal. The initial pulverized coal is separated by gravity differentiation into (1) a high density refuse fraction containing the major portion of non-coal mineral products and sulfur, (2) a lowest density fraction of low sulfur content and (3) a middlings fraction of intermediate sulfur and ash content. The refuse fraction (1) is gasified by partial combustion producing a crude gas product from which a hydrogen stream is separated for use in hydrogenative liquefaction of the middlings fraction (3). The lowest density fraction (2) is mixed with the liquefied coal product to provide the desired fuel slurry. Preferably there is also separately recovered from the coal liquefaction LPG and pipeline gas.

Tao, John C. (Perkiomenville, PA)

1983-01-01T23:59:59.000Z

65

Synthesis and development of processes for the recovery of sulfur from acid gases. Part 1, Development of a high-temperature process for removal of H{sub 2}S from coal gas using limestone -- thermodynamic and kinetic considerations; Part 2, Development of a zero-emissions process for recovery of sulfur from acid gas streams  

SciTech Connect (OSTI)

Limestone can be used more effectively as a sorbent for H{sub 2}S in high-temperature gas-cleaning applications if it is prevented from undergoing calcination. Sorption of H{sub 2}S by limestone is impeded by sintering of the product CaS layer. Sintering of CaS is catalyzed by CO{sub 2}, but is not affected by N{sub 2} or H{sub 2}. The kinetics of CaS sintering was determined for the temperature range 750--900{degrees}C. When hydrogen sulfide is heated above 600{degrees}C in the presence of carbon dioxide elemental sulfur is formed. The rate-limiting step of elemental sulfur formation is thermal decomposition of H{sub 2}S. Part of the hydrogen thereby produced reacts with CO{sub 2}, forming CO via the water-gas-shift reaction. The equilibrium of H{sub 2}S decomposition is therefore shifted to favor the formation of elemental sulfur. The main byproduct is COS, formed by a reaction between CO{sub 2} and H{sub 2}S that is analogous to the water-gas-shift reaction. Smaller amounts of SO{sub 2} and CS{sub 2} also form. Molybdenum disulfide is a strong catalyst for H{sub 2}S decomposition in the presence of CO{sub 2}. A process for recovery of sulfur from H{sub 2}S using this chemistry is as follows: Hydrogen sulfide is heated in a high-temperature reactor in the presence of CO{sub 2} and a suitable catalyst. The primary products of the overall reaction are S{sub 2}, CO, H{sub 2} and H{sub 2}O. Rapid quenching of the reaction mixture to roughly 600{degrees}C prevents loss Of S{sub 2} during cooling. Carbonyl sulfide is removed from the product gas by hydrolysis back to CO{sub 2} and H{sub 2}S. Unreacted CO{sub 2} and H{sub 2}S are removed from the product gas and recycled to the reactor, leaving a gas consisting chiefly of H{sub 2} and CO, which recovers the hydrogen value from the H{sub 2}S. This process is economically favorable compared to the existing sulfur-recovery technology and allows emissions of sulfur-containing gases to be controlled to very low levels.

Towler, G.P.; Lynn, S.

1993-05-01T23:59:59.000Z

66

Removal of organic and inorganic sulfur from Ohio coal by combined physical and chemical process. Final report  

SciTech Connect (OSTI)

This project consisted of three sections. In the first part, the physical cleaning of Ohio coal by selective flocculation of ultrafine slurry was considered. In the second part, the mild oxidation process for removal of pyritic and organic sulfur.was investigated. Finally, in-the third part, the combined effects of these processes were studied. The physical cleaning and desulfurization of Ohio coal was achieved using selective flocculation of ultrafine coal slurry in conjunction with froth flotation as flocs separation method. The finely disseminated pyrite particles in Ohio coals, in particular Pittsburgh No.8 seam, make it necessary to use ultrafine ({minus}500 mesh) grinding to liberate the pyrite particles. Experiments were performed to identify the ``optimum`` operating conditions for selective flocculation process. The results indicated that the use of a totally hydrophobic flocculant (FR-7A) yielded the lowest levels of mineral matters and total sulfur contents. The use of a selective dispersant (PAAX) increased the rejection of pyritic sulfur further. In addition, different methods of floc separation techniques were tested. It was found that froth flotation system was the most efficient method for separation of small coal flocs.

Attia, Y.A.; Zeky, M.El.; Lei, W.W.; Bavarian, F.; Yu, S. [Ohio State Univ., Columbus, OH (United States). Dept. of Materials Science and Engineering

1989-04-28T23:59:59.000Z

67

Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Additives and Cathode Materials for High-Energy Lithium Sulfur Batteries CarbonSulfur Nanocomposites and Additives for High-Energy Lithium...

68

Quarterly technical progress report No. 2, December 20-March 19, 1982. Second quarterly report on the effect of rapid heating rate on coal nitrogen and sulfur release  

SciTech Connect (OSTI)

A laser pyrolysis technique is applied to the investigation of the effects of heating rate on release of coal-bound sulfur and nitrogen. An experimental system characterization and calibration has been completed. A detailed documentation was prepared describing the 3-color pyrometer and the data analysis technique. The coal particle feed system has been calibrated to provide accurate mass flow rate at pre-selected particle velocities. The first batch of samples submitted for chemical analysis will be used for the determination of kinetics parameters at a high heating rate (approximately equal to 10/sup 6/ K/s). The coal used presently is a Montana Rosebud. Two other coals are available; one is ILL No. 6 (through EERC) which will need to be pulverized and the second is a Pitt. hv-A (through KVB). It was confirmed that sieve and drag size distribution of coal differ significantly, and that particle shape effects may be significant in the modelling of particle dynamics.

Gat, N.

1982-04-26T23:59:59.000Z

69

EIS-0004: Coal Loan Guarantee Program (P.L. 94-163)  

Broader source: Energy.gov [DOE]

The U.S. Department of Energy prepared this EIS to address the potential impacts of implementing the Coal Loan Guarantee Program to encourage the production of low and high sulfur coal by small underground coal producers.

70

A novel coal feeder for production of low sulfur fuel. Annual technical progress report, October 1, 1990--October 1, 1991  

SciTech Connect (OSTI)

A dual-screw feeder was designed for desulfurization of coal. This reactor contains two screw tubes, the inner tube acting as a coal pyrolizer and the outer tube acting as a desulfurizer with hot calcined lime pellets or other renewable sorbent pellets. The objectives of this project is to study the feasibility of an advanced concept of desulfurization and possibly some denitrification in this coal feeder. In this year, two basic studies have been performed: (1) the desulfurization and (2) the denitrification due to mild pyrolysis. Specifically, the following tasks have been performed: (1) Setting up the Dual-Screw reactor, (2) Determination of the pyrolysis product and the sulfur distribution in char, tar and gas based on experimental data, (3) Study of the devolatilization, the desulfurization kinetics and the denitrification kinetics and obtaining the basic kinetic parameters, (4) Study of the sulfur removal efficiency of lime pellets fed into the outer tube of the dual-feeder reactor, (5) Study of the effect of the coal particle size on pyrolysis and desulfurization, (6) Study of the coal pyrolysis and desulfurization using a TGA(Thermal Gravimetric Analyzer).

Khang, S.J.; Lin, L.; Keener, T.C.; Yeh, P.

1991-12-31T23:59:59.000Z

71

DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS  

E-Print Network [OSTI]

Pollutants Associated With Coal Combustion. • E.P.A.Control Guidelines for Coal-Derived Pollutants .Forms of Sulfur in Coal • . . . . Coal Desulfurization

Wrathall, James Anthony

2011-01-01T23:59:59.000Z

72

Chemical comminution of coal  

SciTech Connect (OSTI)

The objective of the present research is to study the chemical reactivity of a mixture of methyl alcohol and aqueous sodium hydroxide solution in the temperature range 298 to 363 K, and a caustic concentration of 0 to 10 wt. %, on an Iowa bituminous coal. The sample studied was collected from coal zone 4, equivalent to most historical references to Laddsdale coal. The coals in this zone are typical high-sulfur, high-ash middle Pennsylvania Cherokee group coals. The apparent rank is high-volatile C bituminous coal. The relatively high content of sulfur and 23 other elements in these coals is related to near neutral (6-8) pH conditions in the depositional and early diagenetic environments, and to postdepositional sphalerite/calcite/pyrite/kaolinite/barite mineralization.

Mamaghani, A.H.; Beddow, J.K.; Vetter, A.F.

1987-02-01T23:59:59.000Z

73

HIGH PRESSURE COAL COMBUSTON KINETICS PROJECT  

SciTech Connect (OSTI)

As part of the U.S. Department of Energy (DoE) initiative to improve the efficiency of coal-fired power plants and reduce the pollution generated by these facilities, DOE has funded the High-Pressure Coal Combustion Kinetics (HPCCK) Projects. A series of laboratory experiments were conducted on selected pulverized coals at elevated pressures with the specific goals to provide new data for pressurized coal combustion that will help extend to high pressure and validate models for burnout, pollutant formation, and generate samples of solid combustion products for analyses to fill crucial gaps in knowledge of char morphology and fly ash formation. Two series of high-pressure coal combustion experiments were performed using SRI's pressurized radiant coal flow reactor. The first series of tests characterized the near burner flame zone (NBFZ). Three coals were tested, two high volatile bituminous (Pittsburgh No.8 and Illinois No.6), and one sub-bituminous (Powder River Basin), at pressures of 1, 2, and 3 MPa (10, 20, and 30 atm). The second series of experiments, which covered high-pressure burnout (HPBO) conditions, utilized a range of substantially longer combustion residence times to produce char burnout levels from 50% to 100%. The same three coals were tested at 1, 2, and 3 MPa, as well as at 0.2 MPa. Tests were also conducted on Pittsburgh No.8 coal in CO2 entrainment gas at 0.2, 1, and 2 MPa to begin establishing a database of experiments relevant to carbon sequestration techniques. The HPBO test series included use of an impactor-type particle sampler to measure the particle size distribution of fly ash produced under complete burnout conditions. The collected data have been interpreted with the help of CFD and detailed kinetics simulation to extend and validate devolatilization, char combustion and pollutant model at elevated pressure. A global NOX production sub-model has been proposed. The submodel reproduces the performance of the detailed chemical reaction mechanism for the NBFZ tests.

Stefano Orsino

2005-03-30T23:59:59.000Z

74

Near-Zero Emissions Oxy-Combustion Flue Gas Purification Task 3: SOx/NOx/Hg Removal for Low Sulfur Coal  

SciTech Connect (OSTI)

The goal of this project was to develop a near-zero emissions flue gas purification technology for existing PC (pulverized coal) power plants that are retrofitted with oxycombustion technology. The objective of Task 3 of this project was to evaluate an alternative method of SOx, NOx and Hg removal from flue gas produced by burning low sulfur coal in oxy-combustion power plants. The goal of the program was to conduct an experimental investigation and to develop a novel process for simultaneously removal of SOx and NOx from power plants that would operate on low sulfur coal without the need for wet-FGD & SCRs. A novel purification process operating at high pressures and ambient temperatures was developed. Activated carbonâ??s catalytic and adsorbent capabilities are used to oxidize the sulfur and nitrous oxides to SO{sub 3} and NO{sub 2} species, which are adsorbed on the activated carbon and removed from the gas phase. Activated carbon is regenerated by water wash followed by drying. The development effort commenced with the screening of commercially available activated carbon materials for their capability to remove SO{sub 2}. A bench-unit operating in batch mode was constructed to conduct an experimental investigation of simultaneous SOx and NOx removal from a simulated oxyfuel flue gas mixture. Optimal operating conditions and the capacity of the activated carbon to remove the contaminants were identified. The process was able to achieve simultaneous SOx and NOx removal in a single step. The removal efficiencies were >99.9% for SOx and >98% for NOx. In the longevity tests performed on a batch unit, the retention capacity could be maintained at high level over 20 cycles. This process was able to effectively remove up to 4000 ppm SOx from the simulated feeds corresponding to oxyfuel flue gas from high sulfur coal plants. A dual bed continuous unit with five times the capacity of the batch unit was constructed to test continuous operation and longevity. Full-automation was implemented to enable continuous operation (24/7) with minimum operator supervision. Continuous run was carried out for 40 days. Very high SOx (>99.9%) and NOx (98%) removal efficiencies were also achieved in a continuous unit. However, the retention capacity of carbon beds for SOx and NOx was decreased from ~20 hours to ~10 hours over a 40 day period of operation, which was in contrast to the results obtained in a batch unit. These contradictory results indicate the need for optimization of adsorption-regeneration cycle to maintain long term activity of activated carbon material at a higher level and thus minimize the capital cost of the system. In summary, the activated carbon process exceeded performance targets for SOx and NOx removal efficiencies and it was found to be suitable for power plants burning both low and high sulfur coals. More efforts are needed to optimize the system performance.

Monica Zanfir; Rahul Solunke; Minish Shah

2012-06-01T23:59:59.000Z

75

Energy Policy Act transportation rate study: Interim report on coal transportation  

SciTech Connect (OSTI)

The primary purpose of this report is to examine changes in domestic coal distribution and railroad coal transportation rates since enactment of the Clean Air Act Amendments of 1990 (CAAA90). From 1988 through 1993, the demand for low-sulfur coal increased, as a the 1995 deadline for compliance with Phase 1 of CAAA90 approached. The shift toward low-sulfur coal came sooner than had been generally expected because many electric utilities switched early from high-sulfur coal to ``compliance`` (very low-sulfur) coal. They did so to accumulate emissions allowances that could be used to meet the stricter Phase 2 requirements. Thus, the demand for compliance coal increased the most. The report describes coal distribution and sulfur content, railroad coal transportation and transportation rates, and electric utility contract coal transportation trends from 1979 to 1993 including national trends, regional comparisons, distribution patterns and regional profiles. 14 figs., 76 tabs.

NONE

1995-10-01T23:59:59.000Z

76

High pressure sulfuric acid decomposition experiments for the sulfur-iodine thermochemical cycle.  

SciTech Connect (OSTI)

A series of three pressurized sulfuric acid decomposition tests were performed to (1) obtain data on the fraction of sulfuric acid catalytically converted to sulfur dioxide, oxygen, and water as a function of temperature and pressure, (2) demonstrate real-time measurements of acid conversion for use as process control, (3) obtain multiple measurements of conversion as a function of temperature within a single experiment, and (4) assess rapid quenching to minimize corrosion of metallic components by undecomposed acid. All four of these objectives were successfully accomplished. This report documents the completion of the NHI milestone on high pressure H{sub 2}SO{sub 4} decomposition tests for the Sulfur-Iodine (SI) thermochemical cycle project. All heated sections of the apparatus, (i.e. the boiler, decomposer, and condenser) were fabricated from Hastelloy C276. A ceramic acid injection tube and a ceramic-sheathed thermocouple were used to minimize corrosion of hot liquid acid on the boiler surfaces. Negligible fracturing of the platinum on zirconia catalyst was observed in the high temperature decomposer. Temperature measurements at the exit of the decomposer and at the entry of the condenser indicated that the hot acid vapors were rapidly quenched from about 400 C to less than 20 C within a 14 cm length of the flow path. Real-time gas flow rate measurements of the decomposition products provided a direct measurement of acid conversion. Pressure in the apparatus was preset by a pressure-relief valve that worked well at controlling the system pressure. However, these valves sometimes underwent abrupt transitions that resulted in rapidly varying gas flow rates with concomitant variations in the acid conversion fraction.

Velasquez, Carlos E; Reay, Andrew R.; Andazola, James C.; Naranjo, Gerald E.; Gelbard, Fred

2005-09-01T23:59:59.000Z

77

Composition and properties of coals from the Yurty coal occurrence  

SciTech Connect (OSTI)

Coals from the Yurty coal occurrence were studied. It was found that the samples were brown non-coking coals with low sulfur contents (to 1%) and high yields of volatile substances. The high heat value of coals was 20.6-27.7 MJ/kg. The humic acid content varied from 5.45 to 77.62%. The mineral matter mainly consisted of kaolinite, a-quartz, and microcline. The concentration of toxic elements did not reach hazardous values.

N.G. Vyazova; L.N. Belonogova; V.P. Latyshev; E.A. Pisar'kova [Irkutsk State University, Irkutsk (Russia). Research Institute of Oil and Coal Chemistry and Synthesis

2008-10-15T23:59:59.000Z

78

High-pressure coal fuel processor development  

SciTech Connect (OSTI)

Caterpillar shares DOE/METC interest in demonstrating the technology required to displace petroleum-based engine fuels with various forms of low cost coal. Current DOE/METC programs on mild gasification and coal-water-slurries are addressing two approaches to this end. Engine and fuel processor system concept studies by Caterpillar have identified a third, potentially promising, option. This option includes high-pressure fuel processing of run-of-the-mine coal and direct injection of the resulting low-Btu gas stream into an ignition assisted, high compression ratio diesel engine. The compactness and predicted efficiency of the system make it suitable for application to line-haul railroad locomotives. Two overall conclusions resulted from Task 1. First direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risk associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept. The significant conclusions from Task 2 were: An engine concept, derived from a Caterpillar 3600 series engine, and a fuel processor concept, based on scaling up a removable-canister configuration from the test rig, appear feasible; and although the results of this concept study are encouraging, further, full-scale component research and development are required before attempting a full-scale integrated system demonstration effort.

Greenhalgh, M.L. (Caterpillar, Inc., Peoria, IL (United States))

1992-12-01T23:59:59.000Z

79

Advances of flue gas desulfurization technology for coal-fired boilers and strategies for sulfur dioxide pollution prevention in China  

SciTech Connect (OSTI)

Coal is one of the most important kinds of energy resources at the present time and in the immediate future in China. Sulfur dioxide resulting from combustion of coal is one of the principle pollutants in the air. Control of SO{sub 2} discharge is still a major challenge for environmental protection in developing China. In this paper, research, development and application of technology of flue gas desulfurization (FGD) for coal-fired boilers in China will be reviewed with emphasis on cost-effective technology, and the development trends of FGD technology, as well as the strategy for SO{sub 2} discharge control in China, will be analyzed. A practical technology for middle-small-sized boilers developed by the primary author and the field investigation results will also be presented. At present, there are four major kinds of FGD technologies that are practical to be applied in China for their cost-effectiveness and efficiency to middle-small-sized boilers. An important development trend of the FGD technology for middle-small-sized boilers for the next decade is improvement of the existing cost-effective wet-type FGD technology, and in the future it will be the development of dry-type FGD technology. For middle-sized generating boilers, the development direction of the FGD technology is the spraying and drying process. For large-sized generating boilers, the wet-type limestone-plaster process will still be applied in the immediate future, and dry-type FGD technologies, such as ammonia with electron beam irradiation, will be developed in the future. State strategies for the control of SO{sub 2} discharge will involve the development and popularization of efficient coal-fired devices, extension of gas coal and liquefied coal, spreading coal washing, and centralized heating systems.

Yang, C.; Zeng, G.; Li, G.; Qiu, J.

1999-07-01T23:59:59.000Z

80

ADVANCED SULFUR CONTROL CONCEPTS  

SciTech Connect (OSTI)

Conventional sulfur removal in integrated gasification combined cycle (IGCC) power plants involves numerous steps: COS (carbonyl sulfide) hydrolysis, amine scrubbing/regeneration, Claus process, and tail-gas treatment. Advanced sulfur removal in IGCC systems involves typically the use of zinc oxide-based sorbents. The sulfides sorbent is regenerated using dilute air to produce a dilute SO{sub 2} (sulfur dioxide) tail gas. Under previous contracts the highly effective first generation Direct Sulfur Recovery Process (DSRP) for catalytic reduction of this SO{sub 2} tail gas to elemental sulfur was developed. This process is currently undergoing field-testing. In this project, advanced concepts were evaluated to reduce the number of unit operations in sulfur removal and recovery. Substantial effort was directed towards developing sorbents that could be directly regenerated to elemental sulfur in an Advanced Hot Gas Process (AHGP). Development of this process has been described in detail in Appendices A-F. RTI began the development of the Single-step Sulfur Recovery Process (SSRP) to eliminate the use of sorbents and multiple reactors in sulfur removal and recovery. This process showed promising preliminary results and thus further process development of AHGP was abandoned in favor of SSRP. The SSRP is a direct Claus process that consists of injecting SO{sub 2} directly into the quenched coal gas from a coal gasifier, and reacting the H{sub 2}S-SO{sub 2} mixture over a selective catalyst to both remove and recover sulfur in a single step. The process is conducted at gasifier pressure and 125 to 160 C. The proposed commercial embodiment of the SSRP involves a liquid phase of molten sulfur with dispersed catalyst in a slurry bubble-column reactor (SBCR).

Apostolos A. Nikolopoulos; Santosh K. Gangwal; William J. McMichael; Jeffrey W. Portzer

2003-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Characterization of the chemical variation of feed coal and coal combustion products from a power plant utilizing low sulfur Powder River Basin coal  

SciTech Connect (OSTI)

The US Geological Survey and the University of Kentucky Center for Applied Energy Research, in collaboration with an Indiana utility, are studying a coal-fired power plant burning Powder River Basin coal. This investigation involves a systematic study of the chemical and mineralogical characteristics of feed coal and coal combustion products (CCPs) from a 1,300-megawatt (MW) power unit. The main goal of this study is to characterize the temporal chemical variability of the feed coal, fly ash, and bottom ash by looking at the major-, minor-, and trace-element compositions and their associations with the feed coal mineralogy. Emphasis is also placed on the abundance and modes of occurrence of elements of potential environmental concern that may affect the utilization of these CCPs and coals.

Affolter, R.H.; Brownfield, M.E.; Cathcart, J.D.; Brownfield, I.K.

2000-07-01T23:59:59.000Z

82

Distribution of hazardous air pollutant trace elements, total sulfur, and ash in coals from five Tertiary basins in the Rocky Mountain Region  

SciTech Connect (OSTI)

Arithmetic mean values of the contents of hazardous air pollutant (HAP) trace elements named in the 1990 Clean Air Act Amendments (antimony, arsenic, beryllium, cadmium, chromium, cobalt, lead, manganese, mercury, nickel, selenium, and uranium), ash, and total sulfur were statistically compared on a whole-coal basis for Paleocene coals from five Tertiary basins in the Rocky Mountain Region. The study of proximate and elemental analyses indicate a relationship between trace element contents and paleogeography.

Ellis, M.S.; Stricker, G.D.; Flores, R.M. [Geological Survey, Denver, CO (United States)

1994-12-31T23:59:59.000Z

83

Illinois coal/RDF coprocessing to produce high quality solids and liquids. Technical report, March 1, 1994--May 31, 1994  

SciTech Connect (OSTI)

It is the aim of this study to provide information pertinent to the development of a coal/RDF pyrolysis process capable of economically creating valuable products from high sulfur Illinois coal. This project will be carried out in a systematic manner. First, samples will be properly selected prepared, preserved and characterized. Then coals, various plastics, cellulose, and a high quality RDF will be pyrolyzed, steam pyrolyzed, hydro-pyrolyzed, and liquefied at various conditions. Next, blends of coal with various RDF components will be reacted under the same conditions. From this work, synergistic effects will be identified and process parametric studies will be conducted on the appropriate mixtures and single components. Product quality and mass balances will be obtained on systems showing promise. Preliminary pyrolysis work will be conducted on a TGA. The majority of reactions will be conducted in microautoclaves. If this research is successful, a new market for high sulfur, high mineral Illinois coal would emerge. Samples needed for this project have been obtained and sample preparation have been completed. A Perkin Elmer TGA-7 was employed to study pyrolysis. significant interactions have been observed. About 200 microreactor experiments have been performed and the acquisition of products for analysis has been achieved. Interactions occur between 400-450{degrees}C. Synergism occurs at short reaction time. High temperature and long reaction times result in higher residue yields and a loss of synergisms. Reactive species may be required to stabilize intermediate products.

Hippo, E.J.; Palmer, S.R.; Blankenship, M. [Southern Illinois Univ., Carbondale, IL (United States)

1994-09-01T23:59:59.000Z

84

ZINC CHLORIDE-CATALYZED REACTIONS OF OXYGEN- AND SULFUR-CONTAINING COMPOUNDS WITH MODEL STRUCTURES IN COAL  

E-Print Network [OSTI]

H. H. , ed. , "Chemistry of Coal Utilization", Suppl. Vol. ,H. H. , ed. , "Chemistry of Coal Utilization", Suppl. Vol. ,Internat. Conf. Bituminous Coal, 3d Con£. , 2, 35 (1932);

Mobley, David Paul

2013-01-01T23:59:59.000Z

85

Integrated Process Configuration for High-Temperature Sulfur Mitigation during Biomass Conversion via Indirect Gasification  

SciTech Connect (OSTI)

Sulfur present in biomass often causes catalyst deactivation during downstream operations after gasification. Early removal of sulfur from the syngas stream post-gasification is possible via process rearrangements and can be beneficial for maintaining a low-sulfur environment for all downstream operations. High-temperature sulfur sorbents have superior performance and capacity under drier syngas conditions. The reconfigured process discussed in this paper is comprised of indirect biomass gasification using dry recycled gas from downstream operations, which produces a drier syngas stream and, consequently, more-efficient sulfur removal at high temperatures using regenerable sorbents. A combination of experimental results from NREL's fluidizable Ni-based reforming catalyst, fluidizable Mn-based sulfur sorbent, and process modeling information show that using a coupled process of dry gasification with high-temperature sulfur removal can improve the performance of Ni-based reforming catalysts significantly.

Dutta. A.; Cheah, S.; Bain, R.; Feik, C.; Magrini-Bair, K.; Phillips, S.

2012-06-20T23:59:59.000Z

86

Development of High Energy Density Lithium-Sulfur Cells  

Broader source: Energy.gov (indexed) [DOE]

for increased sulfur loading Cathode Anode Investigatingoptimizing Li and Si composite anodes Exploring polymer electrolytes Electrolyte Determining new...

87

Today's high coal prices: correction or crisis?  

SciTech Connect (OSTI)

Eastern spot prices for coal have risen 25% since the start of 2004, reaching their highest levels in more than 25 years. This spike represents the second time in four years that coal prices have risen to more than double their pre-2000 price levels. Years of famine (from a coal producer's point of view) have been replaced by periods of plenty, with increasing consequences for coal's customers. How long will this spike last? This article, based on studies carried out by EPRI, attempts to answer this question. 3 figs., 1 tab.

Platt, J. [EPRI (US)

2005-06-01T23:59:59.000Z

88

Process for removing sulfur from sulfur-containing gases: high calcium fly-ash  

DOE Patents [OSTI]

The present disclosure relates to improved processes for treating hot sulfur-containing flue gas to remove sulfur therefrom. Processes in accordance with the present invention include preparing an aqueous slurry composed of a calcium alkali source and a source of reactive silica and/or alumina, heating the slurry to above-ambient temperatures for a period of time in order to facilitate the formation of sulfur-absorbing calcium silicates or aluminates, and treating the gas with the heat-treated slurry components. Examples disclosed herein demonstrate the utility of these processes in achieving improved sulfur-absorbing capabilities. Additionally, disclosure is provided which illustrates preferred configurations for employing the present processes both as a dry sorbent injection and for use in conjunction with a spray dryer and/or bagfilter. Retrofit application to existing systems is also addressed.

Rochelle, Gary T. (Austin, TX); Chang, John C. S. (Cary, NC)

1991-01-01T23:59:59.000Z

89

Modified approaches for high pressure filtration of fine clean coal  

SciTech Connect (OSTI)

Removal of moisture from fine (minus 28 mesh) clean coal to 20% or lower level is difficult using the conventional vacuum dewatering technique. High pressure filtration technique provides an avenue for obtaining low moisture in fine clean coal. This paper describes a couple of novel approaches for dewatering of fine clean coal using pressure filtration which provides much lower moisture in fine clean coal than that obtained using conventional pressure filter. The approaches involve (a) split stream dewatering and (b) addition of paper pulp to the coal slurry. For Pittsburgh No. 8 coal slurry, split stream dewatering at 400 mesh provided filter cake containing 12.9% moisture compared to 24.9% obtained on the feed material. The addition of paper pulp to the slurry provided filter cake containing about 17% moisture.

Yang, J.; Groppo, J.G.; Parekh, B.K. [Center for Applied Energy Research, Lexington, KY (United States)

1995-12-31T23:59:59.000Z

90

Enhanced Elemental Mercury Removal from Coal-fired Flue Gas by Sulfur-chlorine Compounds  

SciTech Connect (OSTI)

Oxidation of Hg0 with any oxidant or converting it to a particle-bound form can facilitate its removal. Two sulfur-chlorine compounds, sulfur dichloride (SCl2) and sulfur monochloride (S2Cl2), were investigated as oxidants for Hg0 by gas phase reaction and by surface-involved reactions in the presence of flyash or activated carbon. The gas phase reaction rate constants between Hg0 and the sulfur/chlorine compounds were determined, and the effects of temperature and the main components in flue gases were studied. The gas phase reaction between Hg0 and SCl2 is shown to be more rapid than the gas phase reaction with chlorine, and the second order rate constant was 9.1(+-0.5) x 10-18 mL-molecules-1cdots-1 at 373oK. Nitric oxide (NO) inhibited the gas phase reaction of Hg0 with sulfur-chlorine compounds. The presence of flyash or powdered activated carbon in flue gas can substantially accelerate the reaction. The predicted Hg0 removal is about 90percent with 5 ppm SCl2 or S2Cl2 and 40 g/m3 of flyash in flue gas. The combination of activated carbon and sulfur-chlorine compounds is an effective alternative. We estimate that co-injection of 3-5 ppm of SCl2 (or S2Cl2) with 2-3 Lb/MMacf of untreated Darco-KB is comparable in efficiency to the injection of 2-3 Lb/MMacf Darco-Hg-LH. Extrapolation of kinetic results also indicates that 90percent of Hg0 can be removed if 3 Lb/MMacf of Darco-KB pretreated with 3percent of SCl2 or S2Cl2 is used. Unlike gas phase reactions, NO exhibited little effect on Hg0 reactions with SCl2 or S2Cl2 on flyash or activated carbon. Mercuric sulfide was identified as one of the principal products of the Hg0/SCl2 or Hg0/S2Cl2 reactions. Additionally, about 8percent of SCl2 or S2Cl2 in aqueous solutions is converted to sulfide ions, which would precipitate mercuric ion from FGD solution.

Chang, Shih-Ger; Yan, Nai-Qiang; Qu, Zan; Chi, Yao; Qiao, Shao-Hua; Dod, Ray; Chang, Shih-Ger; Miller, Charles

2008-07-02T23:59:59.000Z

91

Florida CFB demo plant yields low emissions on variety of coals  

SciTech Connect (OSTI)

The US Department of Energy (DOE) has reported results of tests conducted at Jacksonville Electric Authority (JEA)'s Northside power plant using mid-to-low-sulfur coal, which indicate the facility is one of the cleanest burning coal-fired power plants in the world. A part of DOE's Clean Coal Technology Demonstration Program, the JEA project is a repowering demonstration of the operating and environmental performance of Foster Wheeler's utility-scale circulating fluidized bed combustion (CFB) technology on a range of high-sulfur coals and blends of coal and high-sulfur petroleum coke. The 300 MW demonstration unit has a non-demonstration 300 MW twin unit.

NONE

2005-07-01T23:59:59.000Z

92

High Temperature High Pressure Thermodynamic Measurements for Coal Model Compounds  

SciTech Connect (OSTI)

The overall objective of this project is to develop a better thermodynamic model for predicting properties of high-boiling coal derived liquids, especially the phase equilibria of different fractions at elevated temperatures and pressures. The development of such a model requires data on vapor-liquid equilibria (VLE), enthalpy, and heat capacity which would be experimentally determined for binary systems of coal model compounds and compiled into a database. The data will be used to refine existing models such as UNIQUAC and UNIFAC. The flow VLE apparatus designed and built for a previous project was upgraded and recalibrated for data measurements for thk project. The modifications include better and more accurate sampling technique and addition of a digital recorder to monitor temperature, pressure and liquid level inside the VLE cell. VLE data measurements for system benzene-ethylbenzene have been completed. The vapor and liquid samples were analysed using the Perkin-Elmer Autosystem gas chromatography.

John C. Chen; Vinayak N. Kabadi

1998-11-12T23:59:59.000Z

93

High-pressure coal fuel processor development. Task 1, Proof of principle testing  

SciTech Connect (OSTI)

The objective of Subtask 1.1 Engine Feasibility was to conduct research needed to establish the technical feasibility of ignition and stable combustion of directly injected, 3,000 psi, low-Btu gas with glow plug ignition assist at diesel engine compression ratios. This objective was accomplished by designing, fabricating, testing and analyzing the combustion performance of synthesized low-Btu coal gas in a single-cylinder test engine combustion rig located at the Caterpillar Technical Center engine lab in Mossville, Illinois. The objective of Subtask 1.2 Fuel Processor Feasibility was to conduct research needed to establish the technical feasibility of air-blown, fixed-bed, high-pressure coal fuel processing at up to 3,000 psi operating pressure, incorporating in-bed sulfur and particulate capture. This objective was accomplished by designing, fabricating, testing and analyzing the performance of bench-scale processors located at Coal Technology Corporation (subcontractor) facilities in Bristol, Virginia. These two subtasks were carried out at widely separated locations and will be discussed in separate sections of this report. They were, however, independent in that the composition of the synthetic coal gas used to fuel the combustion rig was adjusted to reflect the range of exit gas compositions being produced on the fuel processor rig. Two major conclusions resulted from this task. First, direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize these low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risks associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept.

Greenhalgh, M.L.

1992-11-01T23:59:59.000Z

94

DERAILMENT IN WYOMING (2005) http://www.bigcountry.coop/coal.html  

E-Print Network [OSTI]

Administration said. With tight supplies and high demand, spot market prices for Powder River Basin coal jumped 41 DERAILMENT IN WYOMING (2005) http://www.bigcountry.coop/coal.html [Johnson, 2005] Steven Johnson bottleneck in shipments from the nation's most important vein of low-sulfur coal has cut into coal supplies

Tesfatsion, Leigh

95

Additives and Cathode Materials for High-Energy Lithium Sulfur...  

Broader source: Energy.gov (indexed) [DOE]

of long cycle-life in half cells and expand the synthesis of sulfurcarbon composite materials of various sulfur loadings 2. Compare the performance for different...

96

Integrated High Temperature Coal-to-Hydrogen System with CO2 Separation  

SciTech Connect (OSTI)

A significant barrier to the commercialization of coal-to-hydrogen technologies is high capital cost. The purity requirements for H{sub 2} fuels are generally met by using a series of unit clean-up operations for residual CO removal, sulfur removal, CO{sub 2} removal and final gas polishing to achieve pure H{sub 2}. A substantial reduction in cost can be attained by reducing the number of process operations for H{sub 2} cleanup, and process efficiency can be increased by conducting syngas cleanup at higher temperatures. The objective of this program was to develop the scientific basis for a single high-temperature syngas-cleanup module to produce a pure stream of H{sub 2} from a coal-based system. The approach was to evaluate the feasibility of a 'one box' process that combines a shift reactor with a high-temperature CO{sub 2}-selective membrane to convert CO to CO{sub 2}, remove sulfur compounds, and remove CO{sub 2} in a simple, compact, fully integrated system. A system-level design was produced for a shift reactor that incorporates a high-temperature membrane. The membrane performance targets were determined. System level benefits were evaluated for a coal-to-hydrogen system that would incorporate membranes with properties that would meet the performance targets. The scientific basis for high temperature CO{sub 2}-selective membranes was evaluated by developing and validating a model for high temperature surface flow membranes. Synthesis approaches were pursued for producing membranes that integrated control of pore size with materials adsorption properties. Room temperature reverse-selectivity for CO{sub 2} was observed and performance at higher temperatures was evaluated. Implications for future membrane development are discussed.

James A. Ruud; Anthony Ku; Vidya Ramaswamy; Wei Wei; Patrick Willson

2007-05-31T23:59:59.000Z

97

Aspects of coal pyrogenation with high heating rates  

SciTech Connect (OSTI)

The present paper describes the conversion of different rank coals into coke of required quality, influenced by heating rate variation. The study has been made for romanian coals and the imported coals too. Theoretical aspects of the coking process kinetics with special practical applications are shown. In Romania, classical coke making technology involves some theoretical and practical problems because of the local coal supply, weak in coking coals. Petrographical methods, as a complementary source of information for coking mechanisms understanding were used, for blends with high content of weakly coking coals. The results reveal the importance of rank and petrographical composition determinations for complex blends making. The paper continues previous studies of coke making kinetics, influenced by heating rate variation. On the basis of the relationship between coal charge composition and coke structure, including its use in the blast furnace, the influence of an increase in heating rate on the structure of the coke produced from different rank and petrographical composition coals, was studied. The heating rates ranged between 3 and 40 C/min. The structural changes produced during pyrogenation were more evident for the heating rates: 3, 6, 10 and 40 C/min. Table 2 reveals the optical aspects of coke matrix and inertinitic inclusions evolution, that is, the differences in structure arrangement by changing the plastic phase characteristics due to the increase in the heating rate.

Panaitescu, C.; Barca, F. [Politehnica Univ., Bucharest (Romania); Predeanu, G.; Albastroiu, P. [Metallurgical Research Inst., Bucharest (Romania)

1994-12-31T23:59:59.000Z

98

Process for converting coal into liquid fuel and metallurgical coke  

DOE Patents [OSTI]

A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

Wolfe, Richard A. (Abingdon, VA); Im, Chang J. (Abingdon, VA); Wright, Robert E. (Bristol, TN)

1994-01-01T23:59:59.000Z

99

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures  

DOE Patents [OSTI]

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, John E. (Woodridge, IL); Jalan, Vinod M. (Concord, MA)

1984-01-01T23:59:59.000Z

100

High-temperature sorbent method for removal of sulfur-containing gases from gaseous mixtures  

DOE Patents [OSTI]

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorbtion capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, J.E.; Jalan, V.M.

1982-07-07T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

High-temperature sorbent method for removal of sulfur containing gases from gaseous mixtures  

DOE Patents [OSTI]

A copper oxide-zinc oxide mixture is used as a sorbent for removing hydrogen sulfide and other sulfur containing gases at high temperatures from a gaseous fuel mixture. This high-temperature sorbent is especially useful for preparing fuel gases for high temperature fuel cells. The copper oxide is initially reduced in a preconditioning step to elemental copper and is present in a highly dispersed state throughout the zinc oxide which serves as a support as well as adding to the sulfur sorption capacity. The spent sorbent is regenerated by high-temperature treatment with an air fuel, air steam mixture followed by hydrogen reduction to remove and recover the sulfur.

Young, J.E.; Jalan, V.M.

1984-06-19T23:59:59.000Z

102

Designing and Validating Ternary Pd Alloys for Optimum Sulfur/Carbon Resistance in Hydrogen Separation and Carbon Capture Membrane Systems Using High-Throughput Combinatorial Methods  

SciTech Connect (OSTI)

This report summarizes the work completed under the U.S. Department of Energy Project Award No.: DE-FE0001181 titled “Designing and Validating Ternary Pd Alloys for Optimum Sulfur/Carbon Resistance in Hydrogen Separation and Carbon Capture Membrane Systems Using High-Throughput Combinatorial Methods.” The project started in October 1, 2009 and was finished September 30, 2014. Pall Corporation worked with Cornell University to sputter and test palladium-based ternary alloys onto silicon wafers to examine many alloys at once. With the specialized equipment at Georgia Institute of Technology that analyzed the wafers for adsorbed carbon and sulfur species six compositions were identified to have resistance to carbon and sulfur species. These compositions were deposited on Pall AccuSep® supports by Colorado School of Mines and then tested in simulated synthetic coal gas at the Pall Corporation. Two of the six alloys were chosen for further investigations based on their performance. Alloy reproducibility and long-term testing of PdAuAg and PdZrAu provided insight to the ability to manufacture these compositions for testing. PdAuAg is the most promising alloy found in this work based on the fabrication reproducibility and resistance to carbon and sulfur. Although PdZrAu had great initial resistance to carbon and sulfur species, the alloy composition has a very narrow range that hindered testing reproducibility.

Lewis, Amanda; Zhao, Hongbin; Hopkins, Scott

2014-09-30T23:59:59.000Z

103

Environmental data energy technology characterizations: coal  

SciTech Connect (OSTI)

This document describes the activities leading to the conversion of coal to electricity. Specifically, the activities consist of coal mining and beneficiation, coal transport, electric power generation, and power transmission. To enhance the usefulness of the material presented, resource requirements, energy products, and residuals for each activity area are normalized in terms of 10/sup 12/ Btus of energy produced. Thus, the total effect of producing electricity from coal can be determined by combining the residuals associated with the appropriate activity areas. Emissions from the coal cycle are highly dependent upon the type of coal consumed as well as the control technology assigned to the activity area. Each area is assumed to be equipped with currently available control technologies that meet environmental regulations. The conventional boiler, for example, has an electrostatic precipitator and a flue gas desulfurization scrubber. While this results in the removal of most of the particulate matter and sulfur dioxide in the flue gas stream, it creates other new environmental residuals -- solid waste, sludge, and ash. There are many different types of mined coal. For informational purposes, two types from two major producing regions, the East and the West, are characterized here. The eastern coal is typical of the Northern Appalachian coal district with a high sulfur and heat content. The western coal, from the Powder River Basin, has much less sulfur, but also has a substantially lower heating value.

Not Available

1980-04-01T23:59:59.000Z

104

HIGH PRESSURE COAL COMBUSTION KINETICS PROJECT  

SciTech Connect (OSTI)

The modifications to the SRT-RCFR facility described in the June report were completed. As a result of these changes, the furnace hot zone was increased in length from 7 cm to 15.5 cm. The injector region of the furnace, providing entrainment and sheath flows, was unchanged, while the flow path from the exit of the furnace to the sample collection section was shortened by approximately 10 cm. The modified facility was used to resume testing of Pittsburgh No. 8 coal at 10 atm. The first goal was to confirm that the facility now provides true secondary pyrolysis test conditions. That is, the tar product should be completely converted to soot even in the absence of oxygen in the gas stream. We have now performed four tests with pure argon carrier gas, and have consistently observed voluminous soot product with little or no evidence of tar. Thus, this objective was met. The clogging problems for Pittsburgh No. 8 coal under secondary pyrolysis test conditions may preclude achieving this data point. In that case, we will make measurements under oxidizing conditions, which are expected to eliminate the clogging, and to gradually reduce the oxygen content to the point where product yields can reliably be extrapolated to the zero oxygen case.

Chris Guenther

2002-10-28T23:59:59.000Z

105

Tribological behavior of near-frictionless carbon coatings in high- and low-sulfur diesel fuels.  

SciTech Connect (OSTI)

The sulfur content in diesel fuel has a significant effect on diesel engine emissions, which are currently subject to environmental regulations. It has been observed that engine particulate and gaseous emissions are directly proportional to fuel sulfur content. With the introduction of low-sulfur fuels, significant reductions in emissions are expected. The process of sulfur reduction in petroleum-based diesel fuels also reduces the lubricity of the fuel, resulting in premature failure of fuel injectors. Thus, another means of preventing injector failures is needed for engines operating with low-sulfur diesel fuels. In this study, the authors evaluated a near-frictionless carbon (NFC) coating (developed at Argonne National Laboratory) as a possible solution to the problems associated with fuel injector failures in low-lubricity fuels. Tribological tests were conducted with NFC-coated and uncoated H13 and 52100 steels lubricated with high- and low- sulfur diesel fuels in a high-frequency reciprocating test machine. The test results showed that the NFC coatings reduced wear rates by a factor of 10 over those of uncoated steel surfaces. In low-sulfur diesel fuel, the reduction in wear rate was even greater (i.e., by a factor of 12 compared to that of uncoated test pairs), indicating that the NFC coating holds promise as a potential solution to wear problems associated with the use of low-lubricity diesel fuels.

Alzoubi, M. F.; Ajayi, O. O.; Eryilmaz, O. L.; Ozturk, O.; Erdemir, A.; Fenske, G.

2000-01-19T23:59:59.000Z

106

PALLADIUM/COPPER ALLOY COMPOSITE MEMBRANES FOR HIGH TEMPERATURE HYDROGEN SEPARATION FROM COAL-DERIVED GAS STREAMS  

SciTech Connect (OSTI)

Recent advances have shown that Pd-Cu composite membranes are not susceptible to the mechanical, embrittlement, and poisoning problems that have prevented widespread industrial use of Pd for high temperature H{sub 2} separation. These membranes consist of a thin ({approx}10 {micro}m) film of metal deposited on the inner surface of a porous metal or ceramic tube. Based on preliminary results, thin Pd{sub 60}Cu{sub 40} films are expected to exhibit hydrogen flux up to ten times larger than commercial polymer membranes for H{sub 2} separation, and resist poisoning by H{sub 2}S and other sulfur compounds typical of coal gas. Similar Pd-membranes have been operated at temperatures as high as 750 C. The overall objective of the proposed project is to demonstrate the feasibility of using sequential electroless plating to fabricate Pd{sub 60}Cu{sub 40} alloy membranes on porous supports for H{sub 2} separation. These following advantages of these membranes for processing of coal-derived gas will be demonstrated: High H{sub 2} flux; Sulfur tolerant, even at very high total sulfur levels (1000 ppm); Operation at temperatures well above 500 C; and Resistance to embrittlement and degradation by thermal cycling. The proposed research plan is designed to providing a fundamental understanding of: Factors important in membrane fabrication; Optimization of membrane structure and composition; Effect of temperature, pressure, and gas composition on H{sub 2} flux and membrane selectivity; and How this membrane technology can be integrated in coal gasification-fuel cell systems.

J. Douglas Way; Robert L. McCormick

2001-06-01T23:59:59.000Z

107

Conventional coal preparation in the United States  

SciTech Connect (OSTI)

Processing of bituminous and anthracite coal is widely practiced in the United States and, as mentioned earlier, about 80 percent of the production of these coals is processed as clean coal in preparation plants. Subbituminous coal is not widely processed, primarily because these low rank raw coals are low in sulfur (0.5 to 1.0 percent) and relatively low in ash (8 to 15 percent). They are also relatively low in heat content due to their high inherent moisture. Lignite coals, to the best of the authors{close_quote} knowledge, are not presently being processed in Conventional Coal Preparation plants. This is due to their unstable nature and putting them in water in a coal preparation plant is likely to cause severe degradation in particle size and add to their already high inherent moisture content. The following are the benefits of clean coal processing: produces a uniform product which can be utilized more efficiently; produces a higher quality product which results in higher efficiency at the power station or the steel mill; reduces sulfur dioxide and other adverse stack emissions during coal firing which is a very important environmental consideration; reduces ash or slag handling costs by the user; reduces shipping costs; and reduces handling and storage costs. Processing any stable raw coal in a coal preparation plant will always produce a higher grade product which is a more efficient and a more environmentally acceptable fuel for use at power stations, steel mills, home heating or industrial boilers.

Beck, M.K.; Taylor, B.

1993-12-31T23:59:59.000Z

108

Upgrading low rank coal using the Koppelman Series C process  

SciTech Connect (OSTI)

Development of the K-Fuel technology began after the energy shortage of the early 1970s in the United States led energy producers to develop the huge deposits of low-sulfur coal in the Powder River Basin (PRB) of Wyoming. PRB coal is a subbituminous C coal containing about 30 wt % moisture and having heating values of about 18.6 megajoules/kg (8150 Btu/lb). PRB coal contains from 0.3 to 0.5 wt % sulfur, which is nearly all combined with the organic matrix in the coal. It is in much demand for boiler fuel because of the low-sulfur content and the low price. However, the low-heating value limits the markets for PRB coal to boilers specially designed for the high- moisture coal. Thus, the advantages of the low-sulfur content are not available to many potential customers having boilers that were designed for bituminous coal. This year about 250 million tons of coal is shipped from the Powder River Basin of Wyoming. The high- moisture content and, consequently, the low-heating value of this coal causes the transportation and combustion of the coal to be inefficient. When the moisture is removed and the heating value increased the same bundle of energy can be shipped using one- third less train loads. Also, the dried product can be burned much more efficiently in boiler systems. This increase in efficiency reduces the carbon dioxide emissions caused by use of the low-heating value coal. Also, the processing used to remove water and restructure the coal removes sulfur, nitrogen, mercury, and chlorides from the coal. This precombustion cleaning is much less costly than stack scrubbing. PRB coal, and other low-rank coals, tend to be highly reactive when freshly mined. These reactive coals must be mixed regularly (every week or two) when fresh, but become somewhat more stable after they have aged for several weeks. PRB coal is relatively dusty and subject to self-ignition compared to bituminous coals. When dried using conventional technology, PRB coal is even more dusty and more susceptible to spontaneous combustion than the raw coal. Also, PRB coal, if dried at low temperature, typically readsorbs about two- thirds of the moisture removed by drying. This readsorption of moisture releases the heat of adsorption of the water which is a major cause of self- heating of low-rank coals at low temperature.

Merriam, N.W., Western Research Institute

1998-01-01T23:59:59.000Z

109

Coal-fueled high-speed diesel engine development  

SciTech Connect (OSTI)

The objectives of this program are to study combustion feasibility by running Series 149 engine tests at high speeds with a fuel injection and combustion system designed for coal-water-slurry (CWS). The following criteria will be used to judge feasibility: (1) engine operation for sustained periods over the load range at speeds from 600 to 1900 rpm. The 149 engine for mine-haul trucks has a rated speed of 1900 rpm; (2) reasonable fuel economy and coal burnout rate; (3) reasonable cost of the engine design concept and CWS fuel compared to future oil prices.

Kakwani, R. M.; Winsor, R. E.; Ryan, III, T. W.; Schwalb, J. A.; Wahiduzzaman, S.; Wilson, Jr., R. P.

1991-11-01T23:59:59.000Z

110

Coal-fired high performance power generating system. Final report  

SciTech Connect (OSTI)

As a result of the investigations carried out during Phase 1 of the Engineering Development of Coal-Fired High-Performance Power Generation Systems (Combustion 2000), the UTRC-led Combustion 2000 Team is recommending the development of an advanced high performance power generation system (HIPPS) whose high efficiency and minimal pollutant emissions will enable the US to use its abundant coal resources to satisfy current and future demand for electric power. The high efficiency of the power plant, which is the key to minimizing the environmental impact of coal, can only be achieved using a modern gas turbine system. Minimization of emissions can be achieved by combustor design, and advanced air pollution control devices. The commercial plant design described herein is a combined cycle using either a frame-type gas turbine or an intercooled aeroderivative with clean air as the working fluid. The air is heated by a coal-fired high temperature advanced furnace (HITAF). The best performance from the cycle is achieved by using a modern aeroderivative gas turbine, such as the intercooled FT4000. A simplified schematic is shown. In the UTRC HIPPS, the conversion efficiency for the heavy frame gas turbine version will be 47.4% (HHV) compared to the approximately 35% that is achieved in conventional coal-fired plants. This cycle is based on a gas turbine operating at turbine inlet temperatures approaching 2,500 F. Using an aeroderivative type gas turbine, efficiencies of over 49% could be realized in advanced cycle configuration (Humid Air Turbine, or HAT). Performance of these power plants is given in a table.

NONE

1995-08-31T23:59:59.000Z

111

Coal quality and estimated coal resources in the proposed Colville Mining District, central North Slope, Alaska  

SciTech Connect (OSTI)

The proposed Colville Mining District (CMD) encompasses 27,340 mi{sup 2} (70,800 km{sup 2}) in the central part of the North Slope. Known coal deposits within the proposed district range from Mississippian to Tertiary in age. Available information indicates that neither Mississippian and Tertiary coals in the CMD constitute a significant resource because they are excessively deep, thin, or high in ash content; however, considerable amount of low-sulfur Cretaceous coal is present. The paper briefly describes the geology and quality of these coal reserves. Difficult conditions will restrict mining of these coals in the near future.

Stricker, G.D. [Geological Survey, Denver, CO (United States); Clough, J.G. [Alaska Department of Natural Resources, Fairbanks, AK (United States). Division of Geological and Geophysical Surveys

1994-12-31T23:59:59.000Z

112

Illinois coal/RDF coprocessing to produce high quality solids and liquids; [Quarterly] technical report, September 1--November 30, 1993  

SciTech Connect (OSTI)

It is the aim of this study to provide information pertinent to the development of a coal/RDF pyrolysis process capable of economically creating valuable products from high sulfur Illinois coal. This project will be carried out in a systematic manner. First, samples will be properly selected prepared, preserved and characterized. Then coals, various plastics, cellulose, and a high quality RDF will be pyrolyzed, steam pyrolyzed, hydro-pyrolyzed, and liquefied at various conditions. Next, blends of coal with various RDF components will be reacted under the same conditions. From this work synergistic effects will be identified and process parametric studies will be conducted on the appropriate mixtures and single components. Product quality and mass balances will be obtained on systems showing promise. Preliminary pyrolysis work will be conducted on a TGA. A Perkin Elmer TGA-7 Thermogravimetric Analyzer was employed to study pyrolysis. Significant interactions have been observed. Very preliminary microreactor experiments have been performed and the acquisition of some products for analysis has been achieved. Although, these results are preliminary they are also very encouraging.

Hippo, E.J.; Palmer, S.R.

1994-03-01T23:59:59.000Z

113

High-pressure coal fuel processor development. Final report  

SciTech Connect (OSTI)

Caterpillar shares DOE/METC interest in demonstrating the technology required to displace petroleum-based engine fuels with various forms of low cost coal. Current DOE/METC programs on mild gasification and coal-water-slurries are addressing two approaches to this end. Engine and fuel processor system concept studies by Caterpillar have identified a third, potentially promising, option. This option includes high-pressure fuel processing of run-of-the-mine coal and direct injection of the resulting low-Btu gas stream into an ignition assisted, high compression ratio diesel engine. The compactness and predicted efficiency of the system make it suitable for application to line-haul railroad locomotives. Two overall conclusions resulted from Task 1. First direct injected, ignition assisted Diesel cycle engine combustion systems can be suitably modified to efficiently utilize low-Btu gas fuels. Second, high pressure gasification of selected run-of-the-mine coals in batch-loaded fuel processors is feasible. These two findings, taken together, significantly reduce the perceived technical risk associated with the further development of the proposed coal gas fueled Diesel cycle power plant concept. The significant conclusions from Task 2 were: An engine concept, derived from a Caterpillar 3600 series engine, and a fuel processor concept, based on scaling up a removable-canister configuration from the test rig, appear feasible; and although the results of this concept study are encouraging, further, full-scale component research and development are required before attempting a full-scale integrated system demonstration effort.

Greenhalgh, M.L. [Caterpillar, Inc., Peoria, IL (United States)

1992-12-01T23:59:59.000Z

114

National Coal Quality Inventory (NACQI)  

SciTech Connect (OSTI)

The U.S. Geological Survey (USGS) conducted the National Coal Quality Inventory (NaCQI) between 1999 and 2005 to address a need for quality information on coals that will be mined during the next 20-30 years. Collaboration between the USGS, State geological surveys, universities, coal burning utilities, and the coal mining industry plus funding support from the Electric Power Research Institute (EPRI) and the U.S. Department of Energy (DOE) permitted collection and submittal of coal samples for analysis. The chemical data (proximate and ultimate analyses; major, minor and trace element concentrations) for 729 samples of raw or prepared coal, coal associated shale, and coal combustion products (fly ash, hopper ash, bottom ash and gypsum) from nine coal producing States are included. In addition, the project identified a new coal reference analytical standard, to be designated CWE-1 (West Elk Mine, Gunnison County, Colorado) that is a high-volatile-B or high-volatile-A bituminous coal with low contents of ash yield and sulfur, and very low, but detectable contents of chlorine, mercury and other trace elements.

Robert Finkelman

2005-09-30T23:59:59.000Z

115

Air/water oxydesulfurization of coal: laboratory investigation  

SciTech Connect (OSTI)

Air/water oxidative desulfurization has been demonstrated in autoclave experiments at the Pittsburgh Energy Technology Center for various coals representative of the major US coal basins. This experimentation has shown that the reaction proceeds effectively for pulverized coals at temperatures of 150 to 200/sup 0/C with air at a total system pressure of 500 to 1500 psig. Above 200/sup 0/C, the loss of coal and product heating value increases due to oxidative consumption of carbon and hydrogen. The pyritic sulfur solubilization reactions are typically complete (95 percent removal) within 15 to 40 minutes at temperature; however, significant apparent organic sulfur removal requires residence times of up to 60 minutes at the higher temperatures. The principal products of the reaction are sulfuric acid, which can be neutralized with limestone, and iron oxide. Under certain conditions, especially for high pyritic sulfur coals, the precipitation of sulfur-containing compounds from the products of the pyrite reaction may cause anomalous variations in the sulfur form data. The influence of various parameters on the efficiency of sulfur removal from coal by air/water oxydesulfurization has been studied.

Warzinski, R. P.; Friedman, S.; Ruether, J. A.; LaCount, R. B.

1980-08-01T23:59:59.000Z

116

Gasifier feed: Tailor-made from Illinois coals. Final technical report, September 1, 1991--December 31, 1992  

SciTech Connect (OSTI)

The main purpose of this project was to produce a feedstock from preparation plant fines from an Illinois (IL) coal that is ideal for a slurry fed, slagging, entrained-flow coal gasifier. The high-sulfur content and high-Btu value of IL coals are Particularly advantageous in such a gasifier; preliminary-calculations indicate that the increased cost of removing sulfur from the gas from a high-sulfur coal is more than offset b the increased revenue from the sale of the elemental sulfur; additionally the high-Btu IL coal concentrates more energy into the slurry of a given coal to water ratio. The Btu is--higher not only because of the hither Btu value of the coal but also because IL coal requires less water to produce a pumpable slurry than western coal, i.e., as little as 30--35% water may be used for IL coal as compared to approximately 45% for most western coals. During the contract extension, additional coal testing was completed confirming the fact that coal concentrates can be made from plant waste under a variety of flotation conditions 33 tests were conducted, yielding an average of 13326 Btu with 9.6% ash while recovering 86.0%-Of the energy value.

Ehrlinger, H.P. III [Illinois State Geological Survey, Champaign, IL (United States); Lytle, J.M.; Frost, R.R.; Lizzio, A.A.; Kohlenberger, L.B.; Brewer, K.K. [Illinois State Geological Survey, Champaign, IL (United States)]|[DESTEC Energy (United States)]|[Williams Technologies, Inc. (United States)]|[Illinois Coal Association (United States)

1992-12-31T23:59:59.000Z

117

Production of High-Hydrogen Content Coal-Derived Liquids [Part 1 of 3  

SciTech Connect (OSTI)

The primary goal of this project has been to evaluate and compare the effect of the intrinsic differences between cobalt (Co) and iron (Fe) catalysts for Fischer-Tropsch (FT) synthesis using coal-derived syngas. Crude oil, especially heavy, high-sulfur crude, is no longer the appropriate source for the additional, or marginal, amounts of middle-distillate fuels needed to meet growing US and world demand for diesel and jet fuels. Only about 1/3 of the marginal crude oil barrel can be made into diesel and jet fuels. The remaining 2/3 contributes further to global surpluses of by-products. FT can produce these needed marginal, low-sulfur middle-distillate fuels more efficiently, with less environmental impact, and from abundant US domestic resources. Cobalt FT catalyst is more efficient, and less expensive overall, than iron FT catalyst. Mechanisms of cobalt FT catalyst functioning, and poisoning, have been elucidated. Each of these primary findings is amplified by several secondary findings, and these are presented, and verified in detail. The most effective step the United States can take to begin building toward improved long-term national energy security, and to reduce dependence, over time, on imported crude oil from unfriendly and increasingly unstable areas of the world, is to begin producing additional, or marginal amounts of, middle-distillate-type fuels, such as ultralow sulfur diesel (ULSD) and jet fuel (not gasoline) from US domestic resources other than petroleum. FT synthesis of these middle distillate fuels offers the advantage of being able to use abundant and affordable US coal and biomass as the primary feedstocks. Use of the cobalt FT catalyst system has been shown conclusively to be more effective and less expensive than the use of iron FT catalyst with syngas derived from coal, or from coal and biomass combined. This finding is demonstrated in detail for the initial case of a relatively small FT plant of about 2000 barrels per day based upon coal and biomass. The primary feature of such a plant, in the current situation in which no commercial FT plants are operating in the US, is that it requires a relatively modest capital investment, meaning that such a plant could actually be built, operated, and replicated in the near term. This is in contrast to the several-billion dollar investment, and accompanying risk, that would be required for a plant of more than an order of magnitude greater capacity, which has been referred to in the technical literature on fuel production as the capacity required to be considered "commercial-scale." The effects of more than ten different potential poisons for cobalt FT catalyst have been studied extensively and in detail using laboratory continuous-stirred tank reactors (CSTRs) and bottled laboratory syngas "spiked" with precisely controlled amounts of the poisons, typically at the levels of 10s or 100s of parts per billion. This data set has been generated and interpreted by world-renowned experts on FT catalysis at the University of Kentucky Center for Applied Energy Research (UK-CAER), and has enabled unprecedented insight regarding the many molecular-scale mechanisms that can play a role in the "poisoning" of cobalt FT catalyst.

Stephen Bergin

2011-03-30T23:59:59.000Z

118

Production of High-Hydrogen Content Coal-Derived Liquids [Part 2 of 3  

SciTech Connect (OSTI)

The primary goal of this project has been to evaluate and compare the effect of the intrinsic differences between cobalt (Co) and iron (Fe) catalysts for Fischer-Tropsch (FT) synthesis using coal-derived syngas. Crude oil, especially heavy, high-sulfur crude, is no longer the appropriate source for the additional, or marginal, amounts of middle-distillate fuels needed to meet growing US and world demand for diesel and jet fuels. Only about 1/3 of the marginal crude oil barrel can be made into diesel and jet fuels. The remaining 2/3 contributes further to global surpluses of by-products. FT can produce these needed marginal, low-sulfur middle-distillate fuels more efficiently, with less environmental impact, and from abundant US domestic resources. Cobalt FT catalyst is more efficient, and less expensive overall, than iron FT catalyst. Mechanisms of cobalt FT catalyst functioning, and poisoning, have been elucidated. Each of these primary findings is amplified by several secondary findings, and these are presented, and verified in detail. The most effective step the United States can take to begin building toward improved long-term national energy security, and to reduce dependence, over time, on imported crude oil from unfriendly and increasingly unstable areas of the world, is to begin producing additional, or marginal amounts of, middle-distillate-type fuels, such as ultralow sulfur diesel (ULSD) and jet fuel (not gasoline) from US domestic resources other than petroleum. FT synthesis of these middle distillate fuels offers the advantage of being able to use abundant and affordable US coal and biomass as the primary feedstocks. Use of the cobalt FT catalyst system has been shown conclusively to be more effective and less expensive than the use of iron FT catalyst with syngas derived from coal, or from coal and biomass combined. This finding is demonstrated in detail for the initial case of a relatively small FT plant of about 2000 barrels per day based upon coal and biomass. The primary feature of such a plant, in the current situation in which no commercial FT plants are operating in the US, is that it requires a relatively modest capital investment, meaning that such a plant could actually be built, operated, and replicated in the near term. This is in contrast to the several-billion dollar investment, and accompanying risk, that would be required for a plant of more than an order of magnitude greater capacity, which has been referred to in the technical literature on fuel production as the capacity required to be considered "commercial-scale." The effects of more than ten different potential poisons for cobalt FT catalyst have been studied extensively and in detail using laboratory continuous-stirred tank reactors (CSTRs) and bottled laboratory syngas "spiked" with precisely controlled amounts of the poisons, typically at the levels of 10s or 100s of parts per billion. This data set has been generated and interpreted by world-renowned experts on FT catalysis at the University of Kentucky Center for Applied Energy Research (UK-CAER), and has enabled unprecedented insight regarding the many molecular-scale mechanisms that can play a role in the "poisoning" of cobalt FT catalyst.

Stephen Bergin

2011-03-30T23:59:59.000Z

119

Production of High-Hydrogen Content Coal-Derived Liquids [Part 3 of 3  

SciTech Connect (OSTI)

The primary goal of this project has been to evaluate and compare the effect of the intrinsic differences between cobalt (Co) and iron (Fe) catalysts for Fischer-Tropsch (FT) synthesis using coal-derived syngas. Crude oil, especially heavy, high-sulfur crude, is no longer the appropriate source for the additional, or marginal, amounts of middle-distillate fuels needed to meet growing US and world demand for diesel and jet fuels. Only about 1/3 of the marginal crude oil barrel can be made into diesel and jet fuels. The remaining 2/3 contributes further to global surpluses of by-products. FT can produce these needed marginal, low-sulfur middle-distillate fuels more efficiently, with less environmental impact, and from abundant US domestic resources. Cobalt FT catalyst is more efficient, and less expensive overall, than iron FT catalyst. Mechanisms of cobalt FT catalyst functioning, and poisoning, have been elucidated. Each of these primary findings is amplified by several secondary findings, and these are presented, and verified in detail. The most effective step the United States can take to begin building toward improved long-term national energy security, and to reduce dependence, over time, on imported crude oil from unfriendly and increasingly unstable areas of the world, is to begin producing additional, or marginal amounts of, middle-distillate-type fuels, such as ultralow sulfur diesel (ULSD) and jet fuel (not gasoline) from US domestic resources other than petroleum. FT synthesis of these middle distillate fuels offers the advantage of being able to use abundant and affordable US coal and biomass as the primary feedstocks. Use of the cobalt FT catalyst system has been shown conclusively to be more effective and less expensive than the use of iron FT catalyst with syngas derived from coal, or from coal and biomass combined. This finding is demonstrated in detail for the initial case of a relatively small FT plant of about 2000 barrels per day based upon coal and biomass. The primary feature of such a plant, in the current situation in which no commercial FT plants are operating in the US, is that it requires a relatively modest capital investment, meaning that such a plant could actually be built, operated, and replicated in the near term. This is in contrast to the several-billion dollar investment, and accompanying risk, that would be required for a plant of more than an order of magnitude greater capacity, which has been referred to in the technical literature on fuel production as the capacity required to be considered "commercial-scale." The effects of more than ten different potential poisons for cobalt FT catalyst have been studied extensively and in detail using laboratory continuous-stirred tank reactors (CSTRs) and bottled laboratory syngas "spiked" with precisely controlled amounts of the poisons, typically at the levels of 10s or 100s of parts per billion. This data set has been generated and interpreted by world-renowned experts on FT catalysis at the University of Kentucky Center for Applied Energy Research (UK-CAER), and has enabled unprecedented insight regarding the many molecular-scale mechanisms that can play a role in the "poisoning" of cobalt FT catalyst.

Stephen Bergin

2011-03-30T23:59:59.000Z

120

Gasifier feed: Tailor-made from Illinois coals. Interim final technical report, September 1, 1991--August 31, 1992  

SciTech Connect (OSTI)

The main purpose of this project is to produce a feedstock from preparation plant fines from an Illinois coal that is ideal for a slurry fed, slagging, entrained-flow coal gasifier. The high sulfur content and high Btu value of Illinois coals are particularly advantageous in such a gasifier; preliminary calculations indicate that the increased cost of removing sulfur from the gas from a high sulfur coal is more than offset by the increased revenue from the sale of the elemental sulfur; additionally the high Btu Illinois coal concentrates more energy into the slurry of a given coal to water ratio. The Btu is higher not only because of the higher Btu value of the coal but also because Illinois coal requires less water to produce a pumpable slurry than western coal, i.e., as little as 30--35% water may be used for Illinois coal as compared to approximately 45% for most western coals. Destec Energy, a wholly-owned subsidiary of Dow Chemical Company, will provide guidelines and test compatibility of the slurries developed for gasification feedstock. Williams Technologies, Inc., will provide their expertise in long distance slurry pumping, and test selected products for viscosity, pumpability, and handleability. The Illinois State Geological Survey will study methods for producing clean coal/water slurries from preparation plant wastes including the concentration of pyritic sulfur into the coal slurry to increase the revenue from elemental sulfur produced during gasification operations, and decrease the pyritic sulfur content of the waste streams. ISGS will also test the gasification reactivity of the coals.

Ehrlinger, H.P. III; Lytle, J.; Frost, R.R.; Lizzio, A.; Kohlenberger, L.; Brewer, K. [Illinois State Geological Survey, Champaign, IL (United States)

1992-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

High Purity Hydrogen Production with In-Situ Carbon Dioxide and Sulfur Capture in a Single Stage Reactor  

SciTech Connect (OSTI)

Enhancement in the production of high purity hydrogen (H{sub 2}) from fuel gas, obtained from coal gasification, is limited by thermodynamics of the water gas shift (WGS) reaction. However, this constraint can be overcome by conducting the WGS in the presence of a CO{sub 2}-acceptor. The continuous removal of CO{sub 2} from the reaction mixture helps to drive the equilibrium-limited WGS reaction forward. Since calcium oxide (CaO) exhibits high CO{sub 2} capture capacity as compared to other sorbents, it is an ideal candidate for such a technique. The Calcium Looping Process (CLP) developed at The Ohio State University (OSU) utilizes the above concept to enable high purity H{sub 2} production from synthesis gas (syngas) derived from coal gasification. The CLP integrates the WGS reaction with insitu CO{sub 2}, sulfur and halide removal at high temperatures while eliminating the need for a WGS catalyst, thus reducing the overall footprint of the hydrogen production process. The CLP comprises three reactors - the carbonator, where the thermodynamic constraint of the WGS reaction is overcome by the constant removal of CO{sub 2} product and high purity H{sub 2} is produced with contaminant removal; the calciner, where the calcium sorbent is regenerated and a sequestration-ready CO{sub 2} stream is produced; and the hydrator, where the calcined sorbent is reactivated to improve its recyclability. As a part of this project, the CLP was extensively investigated by performing experiments at lab-, bench- and subpilot-scale setups. A comprehensive techno-economic analysis was also conducted to determine the feasibility of the CLP at commercial scale. This report provides a detailed account of all the results obtained during the project period.

Nihar Phalak; Shwetha Ramkumar; Daniel Connell; Zhenchao Sun; Fu-Chen Yu; Niranjani Deshpande; Robert Statnick; Liang-Shih Fan

2011-07-31T23:59:59.000Z

122

Coal plasticity at high heating rates and temperatures. Final technical progress report  

SciTech Connect (OSTI)

Plastic coals are important feedstocks in coke manufacture, coal liquefaction, gasification, and combustion. During these processes, the thermoplastic behavior of these coals is also important since it may contribute to desirable or undesirable characteristics. For example, during liquefaction, the plastic behavior is desired since it leads to liquid-liquid reactions which are faster than solid-liquid reactions. During gasification, the elastic behavior is undesired since it leads to caking and agglomeration of coal particles which result in bed bogging in fixed or fluidized bed gasifiers. The plastic behavior of different coals was studied using a fast-response plastometer. A modified plastometer was used to measure the torque required to turn at constant angular speed a cone-shaped disk embedded in a thin layer of coal. The coal particles were packed between two metal plates which are heated electrically. Heating rates, final temperatures, pressures, and durations of experiment ranged from 200--800 K/s, 700--1300 K, vacuum-50 atm helium, and 0--40 s, respectively. The apparent viscosity of the molten coal was calculated from the measured torque using the governing equation of the cone-and-plate viscometer. Using a concentrated suspension model, the molten coal`s apparent viscosity was related to the quantity of the liquid metaplast present during pyrolysis. Seven coals from Argonne National Laboratory Premium Coal Sample Bank were studied. Five bituminous coals, from high-volatile to low-volatile bituminous, were found to have very good plastic behavior. Coal type strongly affects the magnitude and duration of plasticity. Hvb coals were most plastic. Mvb and lvb coals, though the maximum plasticity and plastic period were less. Low rank coals such as subbituminous and lignite did not exhibit any plasticity in the present studies. Coal plasticity is moderately well correlated with simple indices of coal type such as the elemental C,O, and H contents.

Gerjarusak, S.; Peters, W.A.; Howard, J.B.

1995-05-01T23:59:59.000Z

123

Development of an advanced high efficiency coal combustor for boiler retrofit  

SciTech Connect (OSTI)

The objective of the program was to develop an advanced coal combustion system for firing beneficiated coal fuels (BCFs) capable of being retrofitted to industrial boilers originally designed for firing natural gas. The High Efficiency Advanced Coal Combustor system is capable of firing microfine coal-water fuel (MCWF), MCWF with alkali sorbent (for SO{sub 2} reduction), and dry microfine coal. Design priorities for the system were that it be simple to operate and offer significant reductions in NO{sub x}, SO{sub x}, and particulate emissions as compared with current coal-fired combustor technology. (VC)

LaFlesh, R.C.; Rini, M.J.; McGowan, J.G.; Beer, J.M.; Toqan, M.A.

1990-04-01T23:59:59.000Z

124

Development of an advanced high efficiency coal combustor for boiler retrofit. Summary report  

SciTech Connect (OSTI)

The objective of the program was to develop an advanced coal combustion system for firing beneficiated coal fuels (BCFs) capable of being retrofitted to industrial boilers originally designed for firing natural gas. The High Efficiency Advanced Coal Combustor system is capable of firing microfine coal-water fuel (MCWF), MCWF with alkali sorbent (for SO{sub 2} reduction), and dry microfine coal. Design priorities for the system were that it be simple to operate and offer significant reductions in NO{sub x}, SO{sub x}, and particulate emissions as compared with current coal-fired combustor technology. (VC)

LaFlesh, R.C.; Rini, M.J.; McGowan, J.G.; Beer, J.M.; Toqan, M.A.

1990-04-01T23:59:59.000Z

125

Coal surface control for advanced fine coal flotation  

SciTech Connect (OSTI)

The initial goal of the research project was to develop methods of coal surface control in advanced froth flotation to achieve 90% pyritic sulfur rejection, while operating at Btu recoveries above 90% based on run-of-mine quality coal. Moreover, the technology is to concomitantly reduce the ash content significantly (to six percent or less) to provide a high-quality fuel to the boiler (ash removal also increases Btu content, which in turn decreases a coal's emission potential in terms of lbs SO{sub 2}/million Btu). (VC)

Fuerstenau, D.W.; Hanson, J.S.; Diao, J.; Harris, G.H.; De, A.; Sotillo, F. (California Univ., Berkeley, CA (United States)); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. (Columbia Univ., New York, NY (United States)); Hu, W.; Zou, Y.; Chen, W. (Utah Univ., Salt Lake City, UT (United States)); Choudhry, V.; Shea, S.; Ghosh, A.; Sehgal, R. (Praxis Engineers, Inc., Milpitas, CA (United States))

1992-03-01T23:59:59.000Z

126

Performance of a high efficiency advanced coal combustor  

SciTech Connect (OSTI)

Under contract from DOE-PETC, Combustion Engineering, Inc. undertook the lead-role in a multi-task R D program aimed at development of a new burner system for coal-based fuels; the goal was that this burner system should be capable of being retrofitted in oil- or gas-fired industrial boilers, or usable in new units. In the first phase of this program a high efficiency advanced coal combustor was designed jointly by CE and MIT. Its burner is of the multiannular design with a fixed shrouded swirler in the center immediately surrounding the atomizer gun to provide the primary act,'' and three further annuli for the supply of the secondary air.'' The degree of rotation (swirl) in the secondary air is variable. The split of the combustion air into primary and secondary air flows serves the purpose of flame stabilization and combustion staging, the latter to reduce NO{sub x} formation.

Toqan, M.A.; Paloposki, T.; Yu, T.; Teare, J.D.; Beer, J.M. (Massachusetts Inst. of Tech., Cambridge, MA (United States))

1989-12-01T23:59:59.000Z

127

High frequency electromagnetic burn monitoring for underground coal gasification  

SciTech Connect (OSTI)

This paper describes the use of high frequency electromagnetic waves to monitor an in-situ coal gasification burn process, and presents some recent results obtained with the method. Both the technique, called HFEM (high frequency electromagnetic) probing, the HFEM hardware used are described, and some of the data obtained from the LLNL Hoe Creek No. 3 underground coal gasification experiment conducted near Gillette, Wyoming are presented. HFEM was found to be very useful for monitoring the burn activity found in underground coal gasification. The technique, being a remote sensing method which does not require direct physical contact, does not suffer from burnout problems as found with thermocouples, and can continue to function even as the burn progresses on through the region of interest. While HFEM does not replace more conventional instrumentation such as thermocouples, the method does serve to provide data which is unobtainable by other means, and in so doing it complements the other data to help form a picture of what cannot be seen underground.

Deadrick, F.J.; Hill, R.W.; Laine, E.F.

1981-06-17T23:59:59.000Z

128

Advanced Coal Conversion Process Demonstration. Technical progress report, April 1, 1993--June 30, 1993  

SciTech Connect (OSTI)

This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from April 1, 1993, through June 30, 1993. The ACCP Demonstration Project is a US DOE Clean Coal Technology Project. This project demonstrates an advanced thermal coal drying process coupled with physical cleaning techniques that are designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel registered as the SynCoal{reg_sign} process. The coal is processed through three stages of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After drying, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal.

Not Available

1994-03-01T23:59:59.000Z

129

Advanced Coal Conversion Process Demonstration. Technical progress report, July 1, 1993--September 30, 1993  

SciTech Connect (OSTI)

This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from July 1, 1993, through September 30, 1993. The ACCP Demonstration Project is a US DOE Clean Coal Technology Project. This project demonstrates an advanced thermal coal drying process coupled with physical cleaning techniques that are designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel registered as the SynCoal{reg_sign} process. The coal is processed through three stages of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After drying, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal.

Not Available

1994-03-01T23:59:59.000Z

130

Advanced Coal Conversion Process Demonstration. Technical progress report, January 1, 1993--March 31, 1993  

SciTech Connect (OSTI)

This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from January 1, 1993, through May 31, 1993. The ACCP Demonstration Project is a US DOE Clean Coal Technology Project. This project demonstrates an advanced thermal coal drying process coupled with physical cleaning techniques that are designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel registered as the SynCoal{reg_sign} process. The coal is processed through three stages of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After drying, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal.

Not Available

1994-03-01T23:59:59.000Z

131

Sulfur and ash reduction potential and selected chemical and physical properties of United States coals. [Contains glossary  

SciTech Connect (OSTI)

This report presents the washability and comprehensive characterization results of 184 raw coal channel samples, including anthracite, bituminous and lignite coals, collected from the Central Region of the United States. This is the second of a three volume report on the coals of the United States. All the data are presented in six appendices. Statistical techniques and definitions are presented in Appendix A, and a glossary of terms is presented in Appendix B. The complete washability data and an in-depth characterization of each sample are presented alphabetically by state in Appendix C. In Appendix D, a statistical evaluation is given for the composited washability data, selected chemical and physical properties and washability data interpolated at various levels of Btu recovery. This presentation is shown by state, section, and region where four or more samples were collected. Appendix E presents coalbed codes and names for the Central Region coals. Graphical summations are presented by state, section and region showing the effects of crushing on impurity reductions, and the distribution of raw and clean coal samples meeting various levels of SO{sub 2} emissions. 35 figs., 5 tabs.

Cavallaro, J.A.; Deurbrouck, A.W.; Killmeyer, R.P.; Fuchs, W. (USDOE Pittsburgh Energy Technology Center, PA (USA). Coal Preparation Div.); Jacobsen, P.S. (Burns and Roe Services Corp., Pittsburgh, PA (USA))

1991-02-01T23:59:59.000Z

132

Steam-Coal Gasification Using CaO and KOH for in Situ Carbon and Sulfur Capture  

SciTech Connect (OSTI)

We present experimental results of coal gasification with and without the addition of calcium oxide and potassium hydroxide as dual-functioning catalyst–capture agents. Using two different coal types and temperatures between 700 and 900 °C, we studied the effect of these catalyst–capture agents on (1) the syngas composition, (2) CO{sub 2} and H{sub 2}S capture, and (3) the steam–coal gasification kinetic rate. The syngas composition from the gasifier was roughly 20% methane, 70% hydrogen, and 10% other species when a CaO/C molar ratio of 0.5 was added. We demonstrated significantly enhanced steam–coal gasification kinetic rates when adding small amounts of potassium hydroxide to coal when operating a CaO–CaCO{sub 3} chemical looping gasification reactor. For example, the steam–coal gasification kinetic rate increased 250% when dry mixing calcium oxide at a Ca/C molar ratio of 0.5 with a sub-bituminous coal, and the kinetic rate increased 1000% when aqueously mixing calcium oxide at a Ca/C molar ratio of 0.5 along with potassium hydroxide at a K/C molar ratio of 0.06. In addition, we conducted multi-cycle studies in which CaCO{sub 3} was calcined by heating to 900 °C to regenerate the CaO, which was then reused in repeated CaO–CaCO{sub 3} cycles. The increased steam–coal gasification kinetics rates for both CaO and CaO + KOH persisted even when the material was reused in six cycles of gasification and calcination. The ability of CaO to capture carbon dioxide decreased roughly 2–4% per CaO–CaCO{sub 3} cycle. We also discuss an important application of this combined gasifier–calciner to electricity generation and selling the purge stream as a precalcined feedstock to a cement kiln. In this scenario, the amount of purge stream required is fixed not by the degradation in the capture ability but rather by the requirements at the cement kiln on the amount of CaSO{sub 4} and ash in the precalcined feedstock.

Siefert, Nicholas S.; Shekhawat, Dushyant; Litster, Shawn; Berry, David, A

2013-08-01T23:59:59.000Z

133

Coal surface control for advanced fine coal flotation. Final report, October 1, 1988--March 31, 1992  

SciTech Connect (OSTI)

The initial goal of the research project was to develop methods of coal surface control in advanced froth flotation to achieve 90% pyritic sulfur rejection, while operating at Btu recoveries above 90% based on run-of-mine quality coal. Moreover, the technology is to concomitantly reduce the ash content significantly (to six percent or less) to provide a high-quality fuel to the boiler (ash removal also increases Btu content, which in turn decreases a coal`s emission potential in terms of lbs SO{sub 2}/million Btu). (VC)

Fuerstenau, D.W.; Hanson, J.S.; Diao, J.; Harris, G.H.; De, A.; Sotillo, F. [California Univ., Berkeley, CA (United States); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. [Columbia Univ., New York, NY (United States); Hu, W.; Zou, Y.; Chen, W. [Utah Univ., Salt Lake City, UT (United States); Choudhry, V.; Shea, S.; Ghosh, A.; Sehgal, R. [Praxis Engineers, Inc., Milpitas, CA (United States)

1992-03-01T23:59:59.000Z

134

ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE  

E-Print Network [OSTI]

Synthetic Fuel from Coal," Federal Energy Administration,Chemical Refining of Coal," Battelle Energy Program Report,reserves coal characteristics energy content sulfur ash ni

Ferrell, G.C.

2010-01-01T23:59:59.000Z

135

Pelletization of fine coals. Final report  

SciTech Connect (OSTI)

Coal is one of the most abundant energy resources in the US with nearly 800 million tons of it being mined annually. Process and environmental demands for low-ash, low-sulfur coals and economic constraints for high productivity are leading the coal industry to use such modern mining methods as longwall mining and such newer coal processing techniques as froth flotation, oil agglomeration, chemical cleaning and synthetic fuel production. All these processes are faced with one common problem area--fine coals. Dealing effectively with these fine coals during handling, storage, transportation, and/or processing continues to be a challenge facing the industry. Agglomeration by the unit operation of pelletization consists of tumbling moist fines in drums or discs. Past experimental work and limited commercial practice have shown that pelletization can alleviate the problems associated with fine coals. However, it was recognized that there exists a serious need for delineating the fundamental principles of fine coal pelletization. Accordingly, a research program has been carried involving four specific topics: (i) experimental investigation of coal pelletization kinetics, (ii) understanding the surface principles of coal pelletization, (iii) modeling of coal pelletization processes, and (iv) simulation of fine coal pelletization circuits. This report summarizes the major findings and provides relevant details of the research effort.

Sastry, K.V.S.

1995-12-31T23:59:59.000Z

136

High-pressure gasification of Montana subbituminous coal  

SciTech Connect (OSTI)

A data base for the fluidized-bed gasification of different coals at elevated pressures has been developed at the Institute of Gas Technology (IGT) with different ranks of coal at pressures up to 450 psig and at temperatures dictated by the individual coals. Adequate data have been obtained to characterize the effect of pressure on the gasification of Montana Rosebud subbituminous coal and North Dakota lignite. The results obtained with Montana Rosebud subbituminous coal are presented here. This program was funded by the Gas Research Institute. 9 refs., 10 figs., 3 tabs.

Goyal, A.; Bryan, B.; Rehmat, A.

1991-01-01T23:59:59.000Z

137

Encoal mild coal gasification project: Final design modifications report  

SciTech Connect (OSTI)

The design, construction and operation Phases of the Encoal Mild Coal Gasification Project have been completed. The plant, designed to process 1,000 ton/day of subbituminous Power River Basin (PRB) low-sulfur coal feed and to produce two environmentally friendly products, a solid fuel and a liquid fuel, has been operational for nearly five years. The solid product, Process Derived Fuel (PDF), is a stable, low-sulfur, high-Btu fuel similar in composition and handling properties to bituminous coal. The liquid product, Coal Derived Liquid (CDL), is a heavy, low-sulfur, liquid fuel similar in properties to heavy industrial fuel oil. Opportunities for upgrading the CDL to higher value chemicals and fuels have been identified. Significant quantities of both PDF and CDL have been delivered and successfully burned in utility and industrial boilers. A summary of the Project is given.

NONE

1997-07-01T23:59:59.000Z

138

Manganese and Ceria Sorbents for High Temperature Sulfur Removal from Biomass-Derived Syngas -- The Impact of Steam on Capacity and Sorption Mode  

SciTech Connect (OSTI)

Syngas derived from biomass and coal gasification for fuel synthesis or electricity generation contains sulfur species that are detrimental to downstream catalysts or turbine operation. Sulfur removal in high temperature, high steam conditions has been known to be challenging, but experimental reports on methods to tackle the problem are not often reported. We have developed sorbents that can remove hydrogen sulfide from syngas at high temperature (700 C), both in dry and high steam conditions. The syngas composition chosen for our experiments is derived from statistical analysis of the gasification products of wood under a large variety of conditions. The two sorbents, Cu-ceria and manganese-based, were tested in a variety of conditions. In syngas containing steam, the capacity of the sorbents is much lower, and the impact of the sorbent in lowering H{sub 2}S levels is only evident in low space velocities. Spectroscopic characterization and thermodynamic consideration of the experimental results suggest that in syngas containing 45% steam, the removal of H{sub 2}S is primarily via surface chemisorptions. For the Cu-ceria sorbent, analysis of the amount of H{sub 2}S retained by the sorbent in dry syngas suggests both copper and ceria play a role in H{sub 2}S removal. For the manganese-based sorbent, in dry conditions, there is a solid state transformation of the sorbent, primarily into the sulfide form.

Cheah, S.; Parent, Y. O.; Jablonski, W. S.; Vinzant, T.; Olstad, J. L.

2012-07-01T23:59:59.000Z

139

A high-efficiency indirect lighting system utilizing the solar 1000 sulfur lamp  

SciTech Connect (OSTI)

High-lumen light sources represent unique challenges and opportunities for the design of practical and efficient interior lighting systems. High-output sources require a means of large-scale distribution and avoidance of high-luminance glare while providing efficient delivery. An indirect lighting system has been developed for use with a 1,000 Watt sulfur lamp that efficiently utilizes the high-output source to provide quality interior lighting. This paper briefly describes the design and initial testing of this new system.

Siminovitch, M.; Gould, C.; Page, E.

1997-06-01T23:59:59.000Z

140

Petrographic characterization of Kentucky coals. Final report. Part VI. The nature of pseudovitrinites in Kentucky coals  

SciTech Connect (OSTI)

Overall average pseudovitrinite content for 1055 eastern Kentucky coal samples is nearly 9% while average percentage of pseudovitrinite for 551 western Kentucky coals is approximately 4%. Examination of variation in pseudovitrinite content relative to rank changes shows uniformity in pseudovitrinite percentages within the 4 to 7 V-type interval for eastern Kentucky coals but a gradual increase in pseudovitrinite content for western Kentucky coals over the same rank interval. Coals from both coal fields show similar, distinct increases in pseudovitrinite percentage in the highest V-type categories. However, it is suggested here that these supposed increases in pseudovitrinite percentages are not real but rather, indicate distinct increase in the brightness of nitrinite resulting from increased alteration of vitrinite beginning at this stage of coalification and continuing into the higher rank stages. This conclusion is reached when it is found that differences between pseudovitrinite and vitrinite reflectance are least in coals at these high rank intervals of Kentucky and, also, when vitrinite particles are often visually observed having brightness equal to that of pseudovitrinite particles. Relation of pseudovitrinite to other sulfur forms and total sulfur in general shows no significant trends, although the relatively high pyritic sulfur content in western Kentucky coals, coupled with relatively low inert percentages suggest the existence of predominantly reducing, or at least non-oxidizing conditions in the Pennsylvanian peat swamps of western Kentucky. Initial work involving Vicker's microhardness testing of coals indicates that microhardness values for pseudovitrinite are higher than those for vitrinite within the same sample regardless of coal rank or coal field from which the sample was collected. 15 references, 9 figures, 9 tables.

Trinkle, E.J.; Hower, J.C.

1984-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

PRODUCTION OF HYDROGEN AND ELECTRICITY FROM COAL WITH CO2 CAPTURE  

E-Print Network [OSTI]

gasification, quench cooled and shifted to (pri- marily) H2 and CO2 via sulfur-tolerant water-gas shift (WGS with sulfur-bearing waste gases, H2S and SO2. I. INTRODUCTION Carbon-free energy carriers, H2 and electricity relative abundance, high carbon intensity, and low cost. Coal-to-H2 plants based on gasification have been

142

DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS  

E-Print Network [OSTI]

of coal sulfur K-T gasification process SRC I process U. S.flow sheet of a K-T coal gasification complex for producingProduction via K-T Gasification" © CEP Aug. 78. Feed

Wrathall, James Anthony

2011-01-01T23:59:59.000Z

143

Petrology, geochemistry, and palynology of Joggins Formation (Westphalian A) coals, Cumberland basin, Nova Scotia  

SciTech Connect (OSTI)

Five Westphalian A coals were collected from the Joggins Formation section exposed along Chignecto Bay at Joggins, Nova Scotia. Several of the coal beds along the bay were mined beginning in the early 17th century. There has been little detailed investigation of the coal beds of this classic section. The lowermost coal, the Upper Coal 29 (Fundy), is a high-vitrinite coal with a spore assemblage dominated by arboreous lycopod spores with tree ferns subdominant. The upper portions of the coal bed have the highest ratio of well-preserved to poorly-preserved telinite of any of the coals investigated. Coal 19 (Forty Brine) has 88% total vitrinite but, unlike the Fundy coal bed, the telinite has a poor preservation ratio and half of the total vitrinite population comprises gelocollinite and vitrodetrinite. The latter coal bed is directly overlain by a basin-wide limestone bed. The Lower Kimberly (Coal 15) shows good preservation of vitrinite with relatively abundant telinite among the total vitrinite. The Upper Kimberly, which underlies the tetrapod-bearing lycopsid trees found by Lyell and Dawson in 1852, exhibits an upward decrease in arboreous lycopod spores and an increase in the tree fern spore Punctatisporites minutus. The megaspore record is similarly dominated by Lagenicularugosa paralycopodites and tree fern spores. Telinite preservation increases upwards in the Upper Kimberly but overall is well below the preservation ratio of the Fundy coal bed. The coals are all high sulfur, up to 13.7% total sulfur for the lower lithotype of the Fundy coal bed. The Kimberly coals are not only high in total and pyritic sulfur, but also have high concentrations of chalcophile elements.

Hower, J.C. [Univ. of Kentucky Center for Applied Energy Research, Lexington, KY (United States); Calder, J.H. [Nova Scotia Dept. of Natural Resources, Halifax (Canada); Cortland, F.E. [Kentucky Geological Survey, Lexington, KY (United States)] [and others

1996-09-01T23:59:59.000Z

144

POC-SCALE TESTING OF AN ADVANCED FINE COAL DEWATERING EQUIPMENT/TECHNIQUE  

SciTech Connect (OSTI)

The main objective of the proposed program is to evaluate a novel surface modification technique, which utilizes the synergistic effect of metal ions-surfactant combination, for dewatering of ultra-fine clean coal on a proof-of-concept scale of 1 to 2 tph. The novel surface modification technique developed at the UKCAER will be evaluated using vacuum, centrifuge, and hyperbaric filtration equipment. Dewatering tests will be conducted using the fine clean-coal froth produced by the column flotation units at the Powell Mountain Coal Company, Mayflower Preparation Plant in St. Charles, Virginia. The POC-scale studies will be conducted on two different types of clean coal, namely, high-sulfur and low-sulfur clean coal. The Mayflower Plant processes coals from five different seams, thus the dewatering studies results could be generalized for most of the bituminous coals.

B.K. PAREKH; D. TAO; J.G. GROPPO

1998-02-03T23:59:59.000Z

145

PALLADIUM/COPPER ALLOY COMPOSITE MEMBRANES FOR HIGH TEMPERATURE HYDROGEN SEPARATION FROM COAL-DERIVED GAS STREAMS  

SciTech Connect (OSTI)

For hydrogen from coal gasification to be used economically, processing approaches that produce a high purity gas must be developed. Palladium and its alloys, nickel, platinum and the metals in Groups 3 to 5 of the Periodic Table are all permeable to hydrogen. Hydrogen permeable metal membranes made of palladium and its alloys are the most widely studied due to their high hydrogen permeability, chemical compatibility with many hydrocarbon containing gas streams, and infinite hydrogen selectivity. Our Pd composite membranes have demonstrated stable operation at 450 C for over 70 days. Coal derived synthesis gas will contain up to 15000 ppm H{sub 2}S as well as CO, CO{sub 2}, N{sub 2} and other gases. Highly selectivity membranes are necessary to reduce the H{sub 2}S concentration to acceptable levels for solid oxide and other fuel cell systems. Pure Pd-membranes are poisoned by sulfur, and suffer from mechanical problems caused by thermal cycling and hydrogen embrittlement. Recent advances have shown that Pd-Cu composite membranes are not susceptible to the mechanical, embrittlement, and poisoning problems that have prevented widespread industrial use of Pd for high temperature H{sub 2} separation. These membranes consist of a thin ({le} 5 {micro}m) film of metal deposited on the inner surface of a porous metal or ceramic tube. With support from this DOE Grant, we have fabricated thin, high flux Pd-Cu alloy composite membranes using a sequential electroless plating approach. Thin, Pd{sub 60}Cu{sub 40} films exhibit a hydrogen flux more than ten times larger than commercial polymer membranes for H{sub 2} separation, resist poisoning by H{sub 2}S and other sulfur compounds typical of coal gas, and exceed the DOE Fossil Energy target hydrogen flux of 80 ml/cm{sup 2} {center_dot} min = 0.6 mol/m{sup 2} {center_dot} s for a feed pressure of 40 psig. Similar Pd-membranes have been operated at temperatures as high as 750 C. We have developed practical electroless plating procedures for fabrication of thin Pd-Cu composite membranes at any scale.

J. Douglas Way

2003-01-01T23:59:59.000Z

146

DSRP, direct sulfur production  

SciTech Connect (OSTI)

The objective of this work is to demonstrate on a bench-scale the Direct Sulfur Recovery Process (DSRP) for up to 99 percent or higher recovery of sulfur (as elemental sulfur) from regeneration off-gases and coal-gas produced in integrated gasification combined cycle (IGCC) power generating systems. Fundamental kinetic and thermodynamic studies will also be conducted to enable development of a model to predict DSRP performance in large-scale reactors and to shed light on the mechanism of DSRP reactions. The ultimate goal of the project is to advance the DSRP technology to the point where industry is willing to support its further development.

McMichael, W.J.; Agarwal, S.K.; Jang, B.L.; Howe, G.B. [Research Triangle Institute, Research Triangle Park, NC (United States); Chen, D.H.; Hopper, J.R. [Lamar Univ., Beaumont, TX (United States)

1993-06-01T23:59:59.000Z

147

HIGH TEMPERATURE HIGH PRESSURE THERMODYNAMIC MEASUREMENTS FOR COAL MODEL COMPOUNDS  

SciTech Connect (OSTI)

It is well known that the fluid phase equilibria can be represented by a number of {gamma}-models , but unfortunately most of them do not function well under high temperature. In this calculation, we mainly investigate the performance of UNIQUAC and NRTL models under high temperature, using temperature dependent parameters rather than using the original formulas. the other feature of this calculation is that we try to relate the excess Gibbs energy G{sup E}and enthalpy of mixing H{sup E}simultaneously. In other words, we will use the high temperature and pressure G{sup E} and H{sup E}data to regress the temperature dependant parameters to find out which model and what kind of temperature dependant parameters should be used.

Vinayak N. Kabadi

1999-02-20T23:59:59.000Z

148

BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS  

SciTech Connect (OSTI)

The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), 35 MPa (5000 psi) steam. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop of advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to maintain a cost-competitive, environmentally acceptable coal-based electric generation option. High sulfur coals will specifically benefit in this respect by having these advanced materials evaluated in high-sulfur coal firing conditions and from the significant reductions in waste generation inherent in the increased operational efficiency. Second, from a national prospective, the results of this program will enable domestic boiler manufacturers to successfully compete in world markets for building high-efficiency coal-fired power plants.

R. Viswanathan; K. Coleman; R.W. Swindeman; J. Sarver; J. Blough; W. Mohn; M. Borden; S. Goodstine; I. Perrin

2003-10-20T23:59:59.000Z

149

Hardgrove grindability study of Powder River Basin and Appalachian coal components in the blend to a midwestern power station  

SciTech Connect (OSTI)

Five coals representing four distinct coal sources blended at a midwestern power station were subjected to detailed analysis of their Hardgrove grindability. The coals are: a low-sulfur, high volatile A bituminous Upper Elkhorn No. 3 coal (Pike County, KY); a medium-sulfur, high volatile A bituminous Pittsburgh coal (southwestern PA); a low-sulfur, subbituminous Wyodak coal from two mines in the eastern Powder River Basin (Campbell County, WY). The feed and all samples processed in the Hardgrove grindability test procedure were analyzed for their maceral and microlithotype content. The high-vitrinite Pittsburgh coal and the relatively more petrographically complex Upper Elkhorn No. 3 coal exhibit differing behavior in grindability. The Pittsburgh raw feed, 16x30 mesh fraction (HGI test fraction), and the {minus}30 mesh fraction (HGI reject) are relatively similar petrographically, suggesting that the HGI test fraction is reasonably representative of the whole feed. The eastern Kentucky coal is not as representative of the whole feed, the HGI test fraction having lower vitrinite than the rejected {minus}30 mesh fraction. The Powder River Basin coals are high vitrinite and show behavior similar to the Pittsburgh coal.

Padgett, P.L.; Hower, J.C. [Univ. of Kentucky, Lexington, KY (United States)

1996-12-31T23:59:59.000Z

150

Illinois coal/RDF coprocessing to produce high quality solids and liquids. [Quarterly] technical report, December 1, 1993--February 28, 1994  

SciTech Connect (OSTI)

It is the aim of this study to provide information pertinent to the development of a coal/RDF pyrolysis process capable of economically creating valuable products from high sulfur Illinois coal. This project will be carried out in a systematic manner. First, samples will be properly selected prepared, preserved and characterized. Then coals, various plastics, cellulose, and a high quality RDF will be pyrolyzed, steam pyrolyzed, hydro-pyrolyzed, and liquefied at various conditions. Next, blends of coal with various RDF components will be reacted under the same conditions. From this work synergistic effects will be identified and process parametric studies will be conducted on the appropriate mixtures and single components. Product quality and mass balances will be obtained on systems showing promise. Preliminary pyrolysis work will be conducted on a TGA. Over 100 microreactor experiments have been performed and the acquisition of products for analysis has been achieved. Interactions occur between 400--450{degrees}C. The use of higher temperatures should be avoided if liquids are the.desired product. Although, these results are preliminary they are also very encouraging.

Hippo, E.J.; Palmer, S.R.; Blankenship, M. [Southern Illinois Univ., Carbondale, IL (United States)

1994-06-01T23:59:59.000Z

151

Advanced coal conversion process demonstration. Technical progress report for the period July 1, 1995--September 30, 1995  

SciTech Connect (OSTI)

This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from July 1, 1995 through September 30, 1995. The ACCP Demonstration Project is a US Department of Energy (DOE) Clean Coal Technology Project. This project demonstrates an advanced, thermal, coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal upgrading, the cola is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal.

NONE

1997-05-01T23:59:59.000Z

152

Advanced coal conversion process demonstration. Progress report, January 1, 1992--December 31, 1992  

SciTech Connect (OSTI)

This report contains a description of the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from January 1, 1992, through December 31, 1992. This project demonstrates an advanced thermal coal drying process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal{reg_sign} process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After drying, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. The SynCoal{reg_sign} process enhances low-rank, western coals, usually with a moisture content of 25 to 55 percent, sulfur content of 0.5 to 1.5 percent, and heating value of 5,500 to 9,000 British thermal units per pound (Btu/lb), by producing a stable, upgraded, coal product with a moisture content as low as 1 percent, sulfur content as low as 0.3 percent, and heating value up to 12,000 Btu/lb. The 45-ton-per-hour unit is located adjacent to a unit train loadout facility at Western Energy Company`s Rosebud coal mine near Colstrip, Montana. The demonstration plant is sized at about one-tenth the projected throughput of a multiple processing train commercial facility. The demonstration drying and cooling equipment is currently near commercial size. Rosebud SynCoal Partnership`s ACCP Demonstration Facility entered Phase III, Demonstration Operation, in April 1992 and has been operating in an extended startup mode since that time. As with any new developing technology, a number of unforeseen obstacles have been encountered; however, Rosebud SynCoal Partnership has instituted an aggressive program to overcome these obstacles.

NONE

1993-12-01T23:59:59.000Z

153

The demonstration of an advanced cyclone coal combustor, with internal sulfur, nitrogen, and ash control for the conversion of a 23 MMBTU/hour oil fired boiler to pulverized coal  

SciTech Connect (OSTI)

This work contains to the final report of the demonstration of an advanced cyclone coal combustor. Titles include: Chronological Description of the Clean Coal Project Tests,'' Statistical Analysis of Operating Data for the Coal Tech Combustor,'' Photographic History of the Project,'' Results of Slag Analysis by PA DER Module 1 Procedure,'' Properties of the Coals Limestone Used in the Test Effort,'' Results of the Solid Waste Sampling Performed on the Coal Tech Combustor by an Independent Contractor During the February 1990 Tests.'' (VC)

Zauderer, B.; Fleming, E.S.

1991-08-30T23:59:59.000Z

154

Development of a new FGD process that converts sulfur dioxide to salable ammonium phosphate fertilizer  

SciTech Connect (OSTI)

Rich mineral resources have enabled Chinese coal output and energy consumption to rank second and third in the world, respectively. In 1992, up to 70 percent of the country`s electric power was generated by the combustion of some 300 million tons of coal. Although the average sulfur content level in Chinese coals is only about 0.8 percent, the share of high- sulfur coals with 2 percent or more sulfur content is as high as 18 percent. As a result, air pollution accompanied by acid rain now occurs over most of the country, especially in southwestern China. Currently, the area comprising Guangdong, Guangxi, the Sichuan Basin, and the greater part of Gueizhou, where the sulfur content in coal is between 2 and 7 percent and the average pH values of rain water are between 4 and 5 per annum, has become one of the three biggest acid rain-affected areas in the world. In 1992, the national installed coal-fired electricity generation capacity exceeded 100,000 MWe. By the year 2000, it is expected to reach as much as 200,000 MWe, according to a new scheduled program. Environmental pollution caused by large-scale coal combustion is a very important issue that needs to be considered in the implementation of the program. To ensure that the effects of coal-fired power generation on the environment can be properly controlled in the near future, TPRI (Thermal Power Research Institute), the sole thermal power engineering research institution within the Ministry of Electric Power Industry (MOEPI), has conducted a long-term research program to develop sulfur emission control technologies suitable to the special conditions prevalent in China since the early 1970s. The details are summarized. The objective of this chapter is to describe the fundamental concept and major pilot test results and present an economic evaluation of a new process combining flue gas desulfurization (FGD) and ammonium phosphate fertilizer production.

Ji-lu Chen

1993-12-31T23:59:59.000Z

155

Engineering development of advanced physical fine coal cleaning technologies - froth flotation. Quarterly technical progress report No. 24, July 1, 1994--September 30, 1994  

SciTech Connect (OSTI)

A study conducted by Pittsburgh Energy Technology Center of sulfur emissions from about 1,300 United States coal-fired utility boilers indicated that half of the emissions were the result of burning coals having greater than 1.2 pounds of SO{sub 2} per million BTU. This was mainly attributed to the high pyritic sulfur content of the boiler fuel. A significant reduction in SO{sub 2} emissions could be accomplished by removing the pyrite from the coals by advanced physical fine coal cleaning. An engineering development project was prepared to build upon the basic research effort conducted under a solicitation for research into Fine Coal Surface Control. The engineering development project is intended to use general plant design knowledge and conceptualize a plant to utilize advanced froth flotation technology to process coal and produce a product having maximum practical pyritic sulfur reduction consistent with maximum practical BTU recovery.

NONE

1995-04-01T23:59:59.000Z

156

Selective flotation of inorganic sulfides from coal  

DOE Patents [OSTI]

Pyritic sulfur is removed from coal or other carbonaceous material through the use of humic acid as a coal flotation depressant. Following the removal of coarse pyrite, the carbonaceous material is blended with humic acid, a pyrite flotation collector and a frothing agent within a flotation cell to selectively float pyritic sulfur leaving clean coal as an underflow. 1 fig., 2 tabs.

Miller, K.J.; Wen, Wu-Wey

1988-05-31T23:59:59.000Z

157

Selective flotation of inorganic sulfides from coal  

DOE Patents [OSTI]

Pyritic sulfur is removed from coal or other carbonaceous material through the use of humic acid as a coal flotation depressant. Following the removal of coarse pyrite, the carbonaceous material is blended with humic acid, a pyrite flotation collector and a frothing agent within a flotation cell to selectively float pyritic sulfur leaving clean coal as an underflow.

Miller, Kenneth J. (Floreffe, PA); Wen, Wu-Wey (Murrysville, PA)

1989-01-01T23:59:59.000Z

158

High performance materials in coal conversion utilization. Technical progress report, April 1, 1996--June 30, 1996  

SciTech Connect (OSTI)

Object is to test, analyze, and improve the heat and coal-slag corrosion resistance of a SiC(p)/Al{sub 2}O{sub 3} ceramic composite tubular material. The material will be evaluated for resistance to pressures, temperatures, and corrosion within a coal-fired high- temperature, high-pressure air heater. Microstructures and some mechanical properties of composite tubes were studied. Other studies include corrosion thermodynamic analysis of Al oxide coated composite.

NONE

1996-07-01T23:59:59.000Z

159

Combustion of calcium-exchanged coal. First quarterly report  

SciTech Connect (OSTI)

The work performed during this first period includes equipment modification, development of analytical methods, oxidative pretreatment runs and combustion runs. The coal feeding section of an existing furnace was modified for uninterrupted feeding and better control of residence time. Analytical methods for sulfur and calcium in the coal and ash and for gaseous SO/sub 2/ were standardized. Oxidative pretreatment experiments were conducted in a fluidized bed at temperatures about 200/sup 0/C to evaluate the potential of this method for increasing the ion exchange capacity of coals and determine the accompanying loss of heating value. Combustion experiments were carried out at very high particle temperatures (2000/sup 0/K) at which a large fraction of the calcium additive was vaporized while 50 to 80% of the sulfur evolved as sulfur oxide. Continuing combustion experiments will be conducted at lower particle temperatures.

Gavalas, G.R.; Flagan, R.C.

1984-02-10T23:59:59.000Z

160

EIS-0282: McIntosh Unit 4 TCFB Demonstration Project, Clean Coal Technology Program, Lakeland, Florida (also see EIS-0304)  

Broader source: Energy.gov [DOE]

The proposed project, selected under DOE’s Clean Coal Technology Program, would demonstrate both Pressurized Circulating Fluidized Bed (PCFB) and Topped PCFB technologies. The proposed project would involve the construction and operation of a nominal 238 MWe (megawatts of electric power) combined-cycle power plant designed to burn a range of low- to high-sulfur coals.

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
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to obtain the most current and comprehensive results.


161

Advanced Coal Conversion Process Demonstration Project. Final technical progress report, January 1, 1995--December 31, 1995  

SciTech Connect (OSTI)

This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from January 1, 1995 through December 31, 1995. This project demonstrates an advanced, thermal, coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal Process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal upgrading, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. The SynCoal Process enhances low-rank, western coals, usually with a moisture content of 25 to 55 percent, sulfur content of 0.5 to 1.5 percent, and heating value of 5,5000 to 9,000 British thermal units per pound (Btu/lb), by producing a stable, upgraded, coal product with a moisture content as low as 1 percent, sulfur content as low as 0.3 percent, and heating value up to 12,000 Btu/lb. During this reporting period, the primary focus for the ACCP Demonstration Project team was to expand SynCoal market awareness and acceptability for both the products and the technology. The ACCP Project team continued to focus on improving the operation, developing commercial markets, and improving the SynCoal products as well as the product`s acceptance.

NONE

1997-05-01T23:59:59.000Z

162

High performance materials in coal conversion utilization. Technical progress report, October 1, 1994--December 31, 1994  

SciTech Connect (OSTI)

This is the fifth quarterly report on a three year grant regarding {open_quotes}High Performance Materials in Coal Conversion Utilization.{close_quotes} The grant is for a joint university/industry effort under the US Department of Energy (DOE) University Coal Research Program. The University of Tennessee Space Institute (UTSI) is the prime contractor and The University of Pennsylvania and Lanxide Corporation are subcontractors. UTSI has completed the planned laboratory exposure tests involving pulverized coal slag on the production Lanxide DIMOX{trademark} ceramic composite material. In addition, the strength testing (at temperature) of C-ring sections of the production composite is complete.

NONE

1995-01-01T23:59:59.000Z

163

High temperature ceramic membrane reactors for coal liquid upgrading  

SciTech Connect (OSTI)

In this project we will study a novel process concept, i.e., the use of ceramic membrane reactors in upgrading of coal model compounds and coal derived liquids. In general terms, the USC research team is responsible for constructing and operating the membrane reactor apparatus and for testing various inorganic membranes for the upgrading of coal derived asphaltenes and coal model compounds. The USC effort will involve the principal investigator of this project and two graduate research assistants. The ALCOA team is responsible for the preparation of the inorganic membranes, for construction and testing of the ceramic membrane modules, and for measurement of their transport properties. The ALCOA research effort will involve Dr. Paul K. T. Liu, who is the project manager of the ALCOA research team, an engineer and a technician. UNOCAL's contribution will be limited to overall technical assistance in catalyst preparation and the operation of the laboratory upgrading membrane reactor and for analytical back-up and expertise in oil analysis and materials characterization. UNOCAL is a no-cost contractor but will be involved in all aspects of the project, as deemed appropriate.

Tsotsis, T.T.

1992-01-01T23:59:59.000Z

164

Advanced Coal Conversion Process Demonstration Project. Quarterly technical progress report, January 1, 1994--March 31, 1994  

SciTech Connect (OSTI)

This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from January 1, 1994, through March 31, 1994. This project demonstrates an advanced, thermal, coal drying process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal{reg_sign} process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal processing, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. Rosebud SynCoal Partnership`s ACCP Demonstration Facility entered Phase III, Demonstration Operation, in April 1992 and operated in an extended startup mode through August 10, 1993, when the facility became commercial. Rosebud SynCoal Partnership instituted an aggressive program to overcome startup obstacles and now focuses on supplying product coal to customers. Significant accomplishments in the history of the SynCoal{reg_sign} process development are shown in Appendix A.

NONE

1996-02-01T23:59:59.000Z

165

Advanced Coal Conversion Process Demonstration Project. Technical progress report, January 1, 1993--December 31, 1993  

SciTech Connect (OSTI)

This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from January 1, 1993, through December 31, 1993. This project demonstrates an advanced, thermal, coal drying process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low- rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal{reg_sign} process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal processing, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. Rosebud SynCoal Partnership`s ACCP Demonstration Facility entered Phase III, Demonstration Operation, in April 1992 and operated in an extended startup mode through August 10, 1993, when the facility became commercial. Rosebud SynCoal Partnership instituted an aggressive program to overcome startup obstacles and now focuses on supplying product coal to customers. Significant accomplishments in the history of the SynCoal{reg_sign} process development are shown in Appendix A.

NONE

1995-02-01T23:59:59.000Z

166

Carbon/Sulfur Nanocomposites and Additives for High-Energy Lithium...  

Broader source: Energy.gov (indexed) [DOE]

of long cycle life in half cells and expand the synthesis of sulfurcarbon composite materials of various sulfur loading 2. Compare the performance for different...

167

Influence of Romanian steam coal quality on power plants environmental impact  

SciTech Connect (OSTI)

Coal provides about 25% of primary energy resources for electricity generation in Romania. Coal is burned in pulverized coal (PC) boilers without flue gas desulfurization (FGD). The coal demands are 90% covered by country`s reserves out of which 80% is lignite. The lignite from Oltenia basin represents about 90% of the domestic lignite quantity used in Romanian power plants. The characteristics defining the typical Romanian lignite are: moisture 40--43%; ash dry basis 37--48%; low heat value 6.0--7.5 MJ/kg; sulfur 0.8--1.2%; volatile matter 17--23%. There are some sorts of lignite which have a higher content of sulfur, but these are used in smaller quantities. RENEL`s strategy includes the preferential utilization of domestic fuels (lignite, hard coal) with imported fuels priority in order natural gas, low sulfur content heavy oil and steam hard coal. Low grade quality of Romanian lignites creates many problems, and due to its high ash and water contents, large quantities of raw coal are required in order to generate energy. The high content of sulfur in coal produces high SO{sub 2} emissions. On the other hand, the very low power values of Romanian lignite generate a low flame temperature, so that, even using fuel oil or gas support for lignite combustion, the NOx emissions are low. Environmental laws have been in force in Romania since December 30, 1995. The Waters Forests and Environment Protection Ministry regulated the pollutant concentration for both new and existing coal fired boilers, beginning in January 1998. Comparing the measured values of SO{sub 2}, NOx and CO contents measured in flue gas from some boilers running on different coal types with the pollutants` emissions limits it is obvious that clean coal technologies (CCT) implementation is necessary, especially for SO{sub 2} reduction.

Matei, M. [Romanian Electricity Authority, Bucharest (Romania). Study, Research and Engineering Group

1998-12-31T23:59:59.000Z

168

Desulfurization of coal: Enhanced selectivity using phase transfer catalysts. Final technical report, September 1, 1995--August 31, 1996  

SciTech Connect (OSTI)

Due to environmental problems related to the combustion of high sulfur Illinois coal, there continues to be interest in the development of viable pre-combustion desulfurization processes. Recent studies by the authors have obtained very good sulfur removals but the reagents that are used are too expensive. Use of cheaper reagents leads to a loss of desired coal properties. This study investigated the application of phase transfer catalysts to the selective oxidation of sulfur in coal using air and oxygen as oxidants. The phase transfer catalyst was expected to function as a selectivity moderator by permitting the use of milder reaction conditions than otherwise necessary. This would enhance the sulfur selectivity and help retain the heating value of the coal. The use of certain coal combustion wastes for desulfurization, and the application of cerium (IV) catalyzed air oxidations for selective sulfur oxidation were also studied. If successful this project would have lead to the rapid development of a commercially viable desulfurization process. This would have significantly improved the marketability of Illinois coal. However, the phase transfer catalysts, the cerium and the scrubber sledge did not catalize the sulfur removal significantly.

Palmer, S.R.; Hippo, E.J.

1997-05-01T23:59:59.000Z

169

Desulfurization of coal: enhanced selectivity using phase transfer catalysts. Quarterly report, March 1 - May 31, 1996  

SciTech Connect (OSTI)

Due to environmental problems related to the combustion of high sulfur Illinois coal, there continues to be interest in the development in viable pre-combustion desulfurization processes. Recent studies by the authors have obtained very good sulfur removals but the reagents that are used are too expensive. Use of cheaper reagents leads to a loss of desired coal properties. This study investigated the application phase transfer catalysts to the selective oxidation of sulfur in coal using air and oxygen as oxidants. The phase transfer catalyst is expected to function as a selectivity moderator by permitting the use of milder reaction conditions that otherwise necessary. This would enhance the sulfur selectivity and help retain the heating value of the coal. The use of certain coal combustion wastes for desulfurization, and the application of cerium (IV) catalyzed air oxidation for selective sulfur oxidation are also being studied. If successful, this project could lead to the rapid development of a commercially viable desulfurization process. This would significantly improve the marketability of Illinois coal.

Palmer, S.R.; Hippo, E.J. [Southern Illinois Univ., Carbondale, IL (United States)

1996-12-31T23:59:59.000Z

170

Control of cooling losses at high pulverized coal injection rates  

SciTech Connect (OSTI)

One of the problems which is encountered by many blast furnace operators is the appropriate control of the cooling losses of the blast furnace. This problem has been aggravated by the introduction of pulverized coal injection. Even with equal burden and coke composition, both Sidmar furnaces behave differently with respect to the cooling losses. This phenomenon is possibly attributable to the different profile and cooling circuitry of the furnaces. Among other parameters the angles of bosh and stack may favor the formation of scabs or not. Some operators experience a decrease of their cooling losses, other operators have problems to limit their cooling losses to an acceptable level. As a result, different operating practices exist with respect to the burden distribution. The increase of the ore to coke ratio with pulverized coal injection suggests that the coke and sinter quality has to be monitored very carefully in order to avoid permeability problems.

Bonte, L.; Nieuwerburgh, H. Van [Sidmar N.V., Gent (Belgium)

1996-12-31T23:59:59.000Z

171

Preparation for upgrading western subbituminous coal  

SciTech Connect (OSTI)

The objective of this project was to establish the physical and chemical characteristics of western coal and determine the best preparation technologies for upgrading this resource. Western coal was characterized as an abundant, easily mineable, clean, low-sulfur coal with low heating value, high moisture, susceptibility to spontaneous ignition, and considerable transit distances from major markets. Project support was provided by the Morgantown Energy Technology Center (METC) of the US Department of Energy (DOE). The research was conducted by the Western Research Institute, (WRI) in Laramie, Wyoming. The project scope of work required the completion of four tasks: (1) project planning, (2) literature searches and verbal contacts with consumers and producers of western coal, (3) selection of the best technologies to upgrade western coal, and (4) identification of research needed to develop the best technologies for upgrading western coals. The results of this research suggest that thermal drying is the best technology for upgrading western coals. There is a significant need for further research in areas involving physical and chemical stabilization of the dried coal product. Excessive particle-size degradation and resulting dustiness, moisture reabsorption, and high susceptibility to spontaneous combustion are key areas requiring further research. Improved testing methods for the determination of equilibrium moisture and susceptibility to spontaneous ignition under various ambient conditions are recommended.

Grimes, R.W.; Cha, C.Y.; Sheesley, D.C.

1990-11-01T23:59:59.000Z

172

[Advanced Coal Conversion Process Demonstration Project]. Technical progress report: April 1, 1992--June 30, 1992  

SciTech Connect (OSTI)

This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from April 1, 1992, through June 30, 1992. This project demonstrates an advanced thermal coal drying process coupled with physical cleaning techniques designed to upgrade high-moisture, low-rank coals into a high-quality, low-sulfur fuel, registered as the SynCoal{reg_sign} process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After drying, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. The SynCoal{reg_sign} process enhances low-rank, western coals, usually with a moisture content of 25 to 55 percent, sulfur content of 0.5 to 1.5 percent, and heating value of 5,500 to 9,000 British thermal units per pound (Btu/Ib), by producing a stable, upgraded coal product with a moisture content as low as 1 percent, sulfur content as low as 0.3 percent, and heating value up to 12,000 Btu/lb. The 45-ton-per-hour unit is located adjacent to a unit train loadout facility at Western Energy Company`s Rosebud coal mine near Colstrip, Montana. The demonstration plant is sized at about one-tenth the projected throughput of a multiple processing train commercial facility. The demonstration drying and cooling equipment is currently near commercial size.

Not Available

1993-10-01T23:59:59.000Z

173

Correlation for the total sulfur content in char after devolatilization  

SciTech Connect (OSTI)

The overall process of coal combustion takes place in two successive steps: devolatilization and char combustion. The fate of sulfur during the devolatilization of coal of different rank was investigated. The significance of the investigation is in fact that a major part of sulfur release occurs during devolatilization of coal, (i.e., emission of sulfur oxides during combustion of coal largely depends on sulfur release during devolatilization). The experimental investigations were conducted to obtain the data about the quantitative relation between sulfur content in the coal and sulfur content in the char. Standard procedures were used for obtaining the chars in a laboratory oven and determining the sulfur forms in the coal and char samples. The experiments were done with ground coal samples ({lt}0.2 mm), at the temperatures in the range of 500-1000{sup o}C. We showed that the amount of sulfur remaining in the char decreases, but not significantly in the temperature range 600-900{sup o}C. On the basis of the theoretical consideration of behavior of sulfur forms during devolatilization, certain simplifying assumptions, and obtained experimental data, we propose two correlations to associate the content of sulfur in the coal and in the char. The correlations are based on the results of the proximate analysis and sulfur forms in coal. Good agreement was found when the proposed correlations were compared with the experimental results obtained for investigated coals. Moreover, the correlations were verified by results found in the literature for numerous Polish, Albanian, and Turkish coals. Significant correlations (P {lt}0.05) between observed and calculated data with correlation coefficient, R {gt}0.9, were noticed in the case of all coals. 25 refs., 3 figs., 2 tabs.

Vasilije Manovic; Borislav Grubor [University of Belgrade, Belgrade (Serbia & Montenegro)

2006-02-01T23:59:59.000Z

174

Sulfur removal and comminution of carbonaceous material  

DOE Patents [OSTI]

Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product.

Narain, Nand K. (Bethel Park, PA); Ruether, John A. (McMurray, PA); Smith, Dennis N. (Herminie, PA)

1988-01-01T23:59:59.000Z

175

Sulfur removal and comminution of carbonaceous material  

DOE Patents [OSTI]

Finely divided, clean coal or other carbonaceous material is provided by forming a slurry of coarse coal in aqueous alkali solution and heating the slurry under pressure to above the critical conditions of steam. The supercritical fluid penetrates and is trapped in the porosity of the coal as it swells in a thermoplastic condition at elevated temperature. By a sudden, explosive release of pressure the coal is fractured into finely divided particles with release of sulfur-containing gases and minerals. The finely divided coal is recovered from the minerals for use as a clean coal product. 2 figs.

Narain, N.K.; Ruether, J.A.; Smith, D.N.

1987-10-07T23:59:59.000Z

176

Wabash River Coal Gasification Repowering Project. Topical report, July 1992--December 1993  

SciTech Connect (OSTI)

The Wabash River Coal Gasification Repowering Project (WRCGRP, or Wabash Project) is a joint venture of Destec Energy, Inc. of Houston, Texas and PSI Energy, Inc. of Plainfield, Indiana, who will jointly repower an existing 1950 vintage coal-fired steam generating plant with coal gasification combined cycle technology. The Project is located in West Terre Haute, Indiana at PSI`s existing Wabash River Generating Station. The Project will process locally-mined Indiana high-sulfur coal to produce 262 megawatts of electricity. PSI and Destec are participating in the Department of Energy Clean Coal Technology Program to demonstrate coal gasification repowering of an existing generating unit affected by the Clean Air Act Amendments. As a Clean Coal Round IV selection, the project will demonstrate integration of an existing PSI steam turbine generator and auxiliaries, a new combustion turbine generator, heat recovery steam generator tandem, and a coal gasification facility to achieve improved efficiency, reduced emissions, and reduced installation costs. Upon completion in 1995, the Project will not only represent the largest coal gasification combined cycle power plant in the United States, but will also emit lower emissions than other high sulfur coal-fired power plants and will result in a heat rate improvement of approximately 20% over the existing plant configuration. As of the end of December 1993, construction work is approximately 20% complete for the gasification portion of the Project and 25% complete for the power generation portion.

Not Available

1994-01-01T23:59:59.000Z

177

COMPCOAL{trademark}: A profitable process for production of a stable high-Btu fuel from Powder River Basin coal  

SciTech Connect (OSTI)

Western Research Institute (WRI) is developing a process to produce a stable, clean-burning, premium fuel from Powder River Basin (PRB) coal and other low-rank coals. This process is designed to overcome the problems of spontaneous combustion, dust formation, and readsorption of moisture that are experienced with PRB coal and with processed PRB coal. This process, called COMPCOAL{trademark}, results in high-Btu product that is intended for burning in boilers designed for midwestern coals or for blending with other coals. In the COMPCOAL process, sized coal is dried to zero moisture content and additional oxygen is removed from the coal by partial decarboxylation as the coal is contacted by a stream of hot fluidizing gas in the dryer. The hot, dried coal particles flow into the pyrolyzer where they are contacted by a very small flow of air. The oxygen in the air reacts with active sites on the surface of the coal particles causing the temperature of the coal to be raised to about 700{degrees}F (371{degrees}C) and oxidizing the most reactive sites on the particles. This ``instant aging`` contributes to the stability of the product while only reducing the heating value of the product by about 50 Btu/lb. Less than 1 scf of air per pound of dried coal is used to avoid removing any of the condensible liquid or vapors from the coal particles. The pyrolyzed coal particles are mixed with fines from the dryer cyclone and dust filter and the resulting mixture at about 600{degrees}F (316{degrees}C) is fed into a briquettor. Briquettes are cooled to about 250{degrees}F (121{degrees}C) by contact with a mist of water in a gas-tight mixing conveyor. The cooled briquettes are transferred to a storage bin where they are accumulated for shipment.

Smith, V.E.; Merriam, N.W.

1994-10-01T23:59:59.000Z

178

High performance materials in coal conversion utilization. Technical progress report, January 1, 1996--March 31, 1996  

SciTech Connect (OSTI)

This is the tenth quarterly report on a three year grant regarding ``High Performance Materials in Coal Conversion Utilization.`` The grant is for a joint university/industry effort under the US Department of Energy (DOE) University Coal Research Program. The University of Tennessee Space Institute (UTSI) is the prime contractor and The University of Pennsylvania and Lanxide Corporation are subcontractors. The object of this grant is to test, analyze, and improve the heat and coal-slag corrosion resistance of a SiC{sub (p)}/Al{sub 2}O{sub 3} ceramic composite tubular material. The material will be evaluated for its ability to withstand the pressures, temperatures and corrosion attack which would be encountered within a coal-fired high-temperature, high pressure air heater. The evaluation includes strength testing at elevated temperatures of production tubes as well as one tube manufactured with an innovative new technology. The feasibility of several joining and coating techniques will also be investigated. UTSI has completed all the initially planned laboratory exposure tests involving pulverized coal slag on the production Lanxide DIMOX{trademark} ceramic composite material. In addition, the strength testing (at temperature) and analysis of C-ring sections of the exposed production composite is complete. The evaluation of a laser-induced coating to laser coat the material has been the major activity this quarter while awaiting an innovatively produced new DIMOX{trademark} test sample.

NONE

1996-04-01T23:59:59.000Z

179

High performance materials in coal conversion utilization. Technical progress report, July 1, 1995--September 30, 1995  

SciTech Connect (OSTI)

This is the eighth quarterly report on a three year grant regarding ``High Performance Materials in Coal Conversion Utilization.`` The grant is for a joint university/industry effort under the US Department of Energy (DOE) University Coal Research Program. The University of Tennessee Space Institute (UTSI) is the prime contractor and the University of Pennsylvania and Lanxide Corporation are subcontractors. The object of this grant is to test, analyze, and improve the heat and coal-slag corrosion resistance of a SiC{sub (p)}/Al{sub 2}O{sub 3} ceramic composite tubular material. The material will be evaluated for its ability to withstand the pressures, temperatures and corrosion attack which would be encountered within a coal-fired high-temperature, high pressure air heater. The evaluation includes strength testing at elevated temperatures of production tubes as well as one manufactured with an innovative new technology. The feasibility of several joining and coating techniques are also being investigated. UTSI has completed all the initially planned laboratory exposure tests involving pulverized coal slag on the production Lanxide DIMOX{trademark} ceramic composite material. In addition, the strength testing (at temperature) and analysis of C- ring sections of the exposed production composite are complete.

NONE

1995-10-01T23:59:59.000Z

180

HYBRID SULFUR CYCLE FLOWSHEETS FOR HYDROGEN PRODUCTION USING HIGH-TEMPERATURE GAS-COOLED REACTORS  

SciTech Connect (OSTI)

Two hybrid sulfur (HyS) cycle process flowsheets intended for use with high-temperature gas-cooled reactors (HTGRs) are presented. The flowsheets were developed for the Next Generation Nuclear Plant (NGNP) program, and couple a proton exchange membrane (PEM) electrolyzer for the SO2-depolarized electrolysis step with a silicon carbide bayonet reactor for the high-temperature decomposition step. One presumes an HTGR reactor outlet temperature (ROT) of 950 C, the other 750 C. Performance was improved (over earlier flowsheets) by assuming that use of a more acid-tolerant PEM, like acid-doped poly[2,2'-(m-phenylene)-5,5'-bibenzimidazole] (PBI), instead of Nafion{reg_sign}, would allow higher anolyte acid concentrations. Lower ROT was accommodated by adding a direct contact exchange/quench column upstream from the bayonet reactor and dropping the decomposition pressure. Aspen Plus was used to develop material and energy balances. A net thermal efficiency of 44.0% to 47.6%, higher heating value basis is projected for the 950 C case, dropping to 39.9% for the 750 C case.

Gorensek, M.

2011-07-06T23:59:59.000Z

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181

Assessment of coal liquids as refinery feedstocks  

SciTech Connect (OSTI)

The R&D of direct coal liquefaction has reached such a stage that current two-stage processes can produce coal liquids with high yields and improved quality at a reasonable cost. To fully realize the potential value, these coal liquids should be refined into high-value liquid transportation fuels. The purpose of this study is to assess coal liquids as feedstocks to be processed by modern petroleum refining technologies. After the introduction, Section 2.0 summarizes ASTM specifications for major transportation fuels: gasoline, jet fuel, and diesel fuel, which serve as a target for coal-liquid refining. A concise description of modern refining processes follows with an emphasis on the requirements for the raw materials. These provide criteria to judge the quality of coal liquids as a refinery feedstock for the production of marketable liquid fuels. Section 3.0 surveys the properties of coal liquids produced by various liquefaction processes. Compared with typical petroleum oils, the current two-stage coal liquids are: Light in boiling range and free of resids and metals; very low in sulfur but relatively high in oxygen; relatively low in hydrogen and high in cyclics content; and essentially toxicologically inactive when end point is lower than 650{degrees}F, particularly after hydroprocessing. Despite these characteristics, the coal liquids are basically similar to petroleum. The modern refining technology is capable of processing coal liquids into transportation fuels meeting all specifications, and hydroprocessinq is obviously the major tool. The important point is the determination of a reasonable product slate and an appropriate refining scheme.

Zhou, P.

1992-02-01T23:59:59.000Z

182

Assessment of coal liquids as refinery feedstocks  

SciTech Connect (OSTI)

The R D of direct coal liquefaction has reached such a stage that current two-stage processes can produce coal liquids with high yields and improved quality at a reasonable cost. To fully realize the potential value, these coal liquids should be refined into high-value liquid transportation fuels. The purpose of this study is to assess coal liquids as feedstocks to be processed by modern petroleum refining technologies. After the introduction, Section 2.0 summarizes ASTM specifications for major transportation fuels: gasoline, jet fuel, and diesel fuel, which serve as a target for coal-liquid refining. A concise description of modern refining processes follows with an emphasis on the requirements for the raw materials. These provide criteria to judge the quality of coal liquids as a refinery feedstock for the production of marketable liquid fuels. Section 3.0 surveys the properties of coal liquids produced by various liquefaction processes. Compared with typical petroleum oils, the current two-stage coal liquids are: Light in boiling range and free of resids and metals; very low in sulfur but relatively high in oxygen; relatively low in hydrogen and high in cyclics content; and essentially toxicologically inactive when end point is lower than 650[degrees]F, particularly after hydroprocessing. Despite these characteristics, the coal liquids are basically similar to petroleum. The modern refining technology is capable of processing coal liquids into transportation fuels meeting all specifications, and hydroprocessinq is obviously the major tool. The important point is the determination of a reasonable product slate and an appropriate refining scheme.

Zhou, P.

1992-02-01T23:59:59.000Z

183

BOILER MATERIALS FOR ULTRASUPERCRITICAL COAL POWER PLANTS  

SciTech Connect (OSTI)

The principal objective of this project is to develop materials technology for use in ultrasupercritical (USC) plant boilers capable of operating with 760 C (1400 F), and up to 5500 psi with emphasis upon 35 MPa (5000 psi) steam. In the 21st century, the world faces the critical challenge of providing abundant, cheap electricity to meet the needs of a growing global population while at the same time preserving environmental values. Most studies of this issue conclude that a robust portfolio of generation technologies and fuels should be developed to assure that the United States will have adequate electricity supplies in a variety of possible future scenarios. The use of coal for electricity generation poses a unique set of challenges. On the one hand, coal is plentiful and available at low cost in much of the world, notably in the U.S., China, and India. Countries with large coal reserves will want to develop them to foster economic growth and energy security. On the other hand, traditional methods of coal combustion emit pollutants and CO{sub 2} at high levels relative to other generation options. Maintaining coal as a generation option in the 21st century will require methods for addressing these environmental issues. This project has established a government/industry consortium to undertake a five-year effort to evaluate and develop advanced materials that allow the use of advanced steam cycles in coal-based power plants. These advanced cycles, with steam temperatures up to 760 C, will increase the efficiency of coal-fired boilers from an average of 35% efficiency (current domestic fleet) to 47% (HHV). This efficiency increase will enable coal-fired power plants to generate electricity at competitive rates (irrespective of fuel costs) while reducing CO{sub 2} and other fuel-related emissions by as much as 29%. Success in achieving these objectives will support a number of broader goals. First, from a national prospective, the program will identify advanced materials that will make it possible to maintain a cost-competitive, environmentally-acceptable coal-based electric generation option. High sulfur coals will specifically benefit in this respect by having these advanced materials evaluated in high-sulfur coal firing conditions and from the significant reductions in waste generation inherent in the increased operational efficiency. Second, from a national perspective, the results of this program will enable domestic boiler manufacturers to successfully compete in world markets for building high-efficiency coal-fired power plants.

R. Viswanathan

2002-04-15T23:59:59.000Z

184

Geochemistry of coal from Cretaceous Corwin and Chandler formations, National Petroleum Reserve in Alaska (NPRA)  

SciTech Connect (OSTI)

Ninety coal samples from these formations within NPRA were collected and analyzed in order to evaluate coal quality and elemental distribution. Their apparent rank ranges from lignite A in the northern part of NPRA to high-volatile AS bituminous coal in the southern part. Mean vitrinite reflectance values range from 0.65 to 0.74%. Some Corwin Formation coal samples west of NPRA have coking potential with free-swelling indexes between 3.0 and 5.0. Compared to other western United States Cretaceous coal, NPRA coal is significantly lower in ash, volatile matter, O, Si, Al, Ca, Fe, Ti, Cu, F, Li, Mn, Mo, Pb, Sb, Se, Th, and Zn. Statistical comparisons of element concentrations indicate that the mean content of Si, Al, K, Li, Sc, Y, and Yb increases as the mean ash content increases (correlation coefficient at least 0.7). Sulfur values are extremely low (0.1%), and elements that normally show positive correlation with sulfur, such as Fe, As, Cd, Co, Cu, Mo, Pb, and Zn, are also low. Therefore, coal from NPRA can be characterized by low ash and sulfur contents and low contents of elements of environmental concern, such as As, Be, Hg, Mo, Sb, and Se. The elements found to have positive correlations with ash content are probably present as aluminosilicate or stable oxide minerals. Variations in element content and quality of NPRA coal were probably influenced by the geochemical conditions that existed in the Corwin and Umiat delta systems.

Affolter, R.H.; Stricker, G.D.

1985-04-01T23:59:59.000Z

185

Sustainable development with clean coal  

SciTech Connect (OSTI)

This paper discusses the opportunities available with clean coal technologies. Applications include new power plants, retrofitting and repowering of existing power plants, steelmaking, cement making, paper manufacturing, cogeneration facilities, and district heating plants. An appendix describes the clean coal technologies. These include coal preparation (physical cleaning, low-rank upgrading, bituminous coal preparation); combustion technologies (fluidized-bed combustion and NOx control); post-combustion cleaning (particulate control, sulfur dioxide control, nitrogen oxide control); and conversion with the integrated gasification combined cycle.

NONE

1997-08-01T23:59:59.000Z

186

Ashing properties of coal blends  

SciTech Connect (OSTI)

The fusion properties of sulfur materials present in coals were investigated. The treatment of the samples of eleven different coals is described. Thermal treatment of low temperature ashing (LTA) concentrates of eight of the coals was performed, and raw and wash ashing curves were examined to determine what quantitative correlations, if any, exist between ashing parameters and rank of coal. The actual form of the function which describes the ashing curve is derived.

Biggs, D.L.

1982-03-01T23:59:59.000Z

187

ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE  

E-Print Network [OSTI]

Kansas New Mexico Sulfur Content Feed Coal (%) Sulfurcoal from different sections of the Navajo mine in New Mexico (

Ferrell, G.C.

2010-01-01T23:59:59.000Z

188

Ohio Coal Research Consortium fifth year final reports summary, September 1, 1994--February 29, 1996  

SciTech Connect (OSTI)

As part of its efforts to improve the use of high-sulfur Ohio coal within environmental limits, the Ohio Coal Development Office, an entity within the Ohio Department of Development (OCDO/ODOD), in late 1988 established a consortium of four Ohio universities. The purpose of the Ohio Coal Research Consortium is to conduct a multi-year fundamental research programs focused on: (1) the enhancement or development of dry sorption processes for the economical removal of high levels of SO{sub 2} and other pollutants, and (2) an increased understanding of methods for reduction in air toxics emissions from combustion gases produced by burning high-sulfur Ohio coal. This report contains summaries of eleven studies in these areas.

NONE

1996-12-01T23:59:59.000Z

189

Ohio Coal Research Consortium fourth year final summary report, September 1, 1993--August 31, 1994  

SciTech Connect (OSTI)

As a part of its efforts to improve the use of high-sulfur Ohio coal within environmental limits, the Ohio Coal Development Office, an entity within the Ohio Department of Development (OCDO/ODOD), in late 1988 established a consortium of four Ohio universities. The purpose of the Ohio Coal Research Consortium is to conduct a multi-year fundamental research program focused on (1) the enhancement or development of dry sorption processes for the economical removal of high levels of SO{sub 2} and other pollutants and (2) an increased understanding of methods for reduction in air toxics emissions from combustion gases produced by burning high-sulfur Ohio coal. This report contains summaries of twelve studies in these areas.

NONE

1995-05-01T23:59:59.000Z

190

High performance materials in coal conversion utilization. Technical progress report, April 1, 1995--June 30, 1995  

SciTech Connect (OSTI)

This is the seventh quarterly report on a three year grant regarding {open_quotes}High Performance Materials in Coal Conversion Utilization.{close_quotes} The grant is for a joint university/industry effort under the US Department of Energy (DOE) University Coal Research Program. The University of Tennessee Space Institute (UTSI) is the prime contractor and The University of Pennsylvania and Lanxide Corporation are subcontractors. UTSI has completed the planned laboratory exposure tests involving pulverized coal slag on the production of Lanxide DIMOX{trademark} ceramic composite material. In addition, the strength testing (at temperature) of C-ring sections of the production composite is complete and the analysis of the data is reported in a thesis which was submitted toward a M.S. degree.

NONE

1995-07-01T23:59:59.000Z

191

High performance materials in coal conversion utilization. Technical progress report, October 1, 1995--December 31, 1995  

SciTech Connect (OSTI)

This is the ninth quarterly report on a three year grant regarding {open_quotes}High Performance Materials in Coal Conversion Utilization.{close_quotes} The grant is for a joint university/industry effort under the U.S. Department of Energy (DOE) University Coal Research Program. The University of Tennessee Space Institute (UTSI) is the prime contractor and The University of Pennsylvania and Lanxide Corporation are subcontractors. UTSI has completed all the initially planned laboratory exposure tests involving pulverized coal slag on the production Lanxide DIMOX{trademark} ceramic composite material. In addition, the strength testing (at temperature) and analysis of C-ring sections of the exposed production composite is complete. The development of a technique to laser coat the material has been the major activity while awaiting an innovatively produced new test sample. This sample will be tested and compared to the production tubes tested at UTSI.

NONE

1996-01-01T23:59:59.000Z

192

High performance materials in coal conversion utilization. Technical progress report, April 1, 1994--June 30, 1994  

SciTech Connect (OSTI)

This is the third quarterly report concerning this three year grant on {open_quotes}High Performance Materials in Coal Conversion Utilization.{close_quotes} The grant is for a joint university/industry effort under the US Department of Energy (DOE) University Coal Research Program. The University of Tennessee Space Institute (UTSI) is the prime contractor and The University of Pennsylvania and Lanxide Corporation are subcontractors. UTSI has completed one third of the planned laboratory exposure tests involving pulverized coal slag on the production of Lanxide DIMOS{sup TM} ceramic composite material. The upgrade of the MTS testing machine is underway and the strength testing (at temperature) of C-ring sections of the composite will begin next quarter.

Not Available

1994-10-01T23:59:59.000Z

193

Catalyst for the reduction of sulfur dioxide to elemental sulfur  

DOE Patents [OSTI]

The inventive catalysts allow for the reduction of sulfur dioxide to elemental sulfur in smokestack scrubber environments. The catalysts have a very high sulfur yield of over 90% and space velocity of 10,000 h.sup.-1. They also have the capacity to convert waste gases generated during the initial conversion into elemental sulfur. The catalysts have inexpensive components, and are inexpensive to produce. The net impact of the invention is to make this technology practically available to industrial applications.

Jin, Yun (Peking, CN); Yu, Qiquan (Peking, CN); Chang, Shih-Ger (El Cerrito, CA)

1996-01-01T23:59:59.000Z

194

Coal combustion by wet oxidation  

SciTech Connect (OSTI)

The combustion of coal by wet oxidation was studied by the Center for Waste Management Programs, of Michigan Technological University. In wet oxidation a combustible material, such as coal, is reacted with oxygen in the presence of liquid water. The reaction is typically carried out in the range of 204/sup 0/C (400/sup 0/F) to 353/sup 0/C (650/sup 0/F) with sufficient pressure to maintain the water present in the liquid state, and provide the partial pressure of oxygen in the gas phase necessary to carry out the reaction. Experimental studies to explore the key reaction parameters of temperature, time, oxidant, catalyst, coal type, and mesh size were conducted by running batch tests in a one-gallon stirred autoclave. The factors exhibiting the greatest effect on the extent of reaction were temperature and residence time. The effect of temperature was studied from 204/sup 0/C (400/sup 0/F) to 260/sup 0/C (500/sup 0/F) with a residence time from 600 to 3600 seconds. From this data, the reaction activation energy of 2.7 x 10/sup 4/ calories per mole was determined for a high-volatile-A-Bituminous type coal. The reaction rate constant may be determined at any temperature from the activation energy using the Arrhenius equation. Additional data were generated on the effect of mesh size and different coal types. A sample of peat was also tested. Two catalysts were evaluated, and their effects on reaction rate presented in the report. In addition to the high temperature combustion, low temperature desulfurization is discussed. Desulfurization can improve low grade coal to be used in conventional combustion methods. It was found that 90% of the sulfur can be removed from the coal by wet oxidation with the carbon untouched. Further desulfurization studies are indicated.

Bettinger, J.A.; Lamparter, R.A.; McDowell, D.C.

1980-11-15T23:59:59.000Z

195

High performance materials in coal conversion utilization. Technical progress report, October 1, 1993--December 31, 1993  

SciTech Connect (OSTI)

This is the first quarterly report for this three year grant on {open_quotes}High Performance Materials in Coal Conversion Utilization.{close_quotes} The grant is a joint university/industry effort under the Department of Energy (DOE) University Coal Research program. The University of Tennessee Space Institute (UTSI) is the prime contractor and The University of Pennsylvania and Lanxide Corporation are subcontractors. It was initially planned to field test ceramic composite tubes furnished by Lanxide Corporation in conjunction with an on-going DOE magnetohydrodynamic (MHD) test series at UTSI. The MHD test program was curtailed due to funding limitations near the beginning of the grant so that the field test portion is now greatly reduced. Bench scale testing will replace most of the field testing. This development should have minimal effect on this research since there is now little interest in the affects of the potassium seeded MHD coal ash on heat exchanger surfaces. The objective is to test and analyze the heat and corrosion resistance of a SiC(p)/Al{sub 2}O{sub 3} ceramic composite tubular material. The material will be evaluated for its ability to withstand the pressures, temperatures and corrosion attack which will be encountered within a coal-fired high-temperature, high-pressure air heater. The evaluation will include strength testing at elevated temperatures.

Not Available

1994-02-01T23:59:59.000Z

196

Coal-fired high performance power generating system. Quarterly progress report, January 1--March 31, 1992  

SciTech Connect (OSTI)

This report covers work carried out under Task 2, Concept Definition and Analysis, and Task 3, Preliminary R and D, under contract DE-AC22-92PC91155, ``Engineering Development of a Coal Fired High Performance Power Generation System`` between DOE Pittsburgh Energy Technology Center and United Technologies Research Center. The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) by the year 2000 that is capable of: > 47% thermal efficiency; NO{sub x}, SO{sub x} and Particulates {le} 25% NSPS; cost {ge} 65% of heat input; and all solid wastes benign. In order to achieve these goals our team has outlined a research plan based on an optimized analysis of a 250 MW{sub e} combined cycle system applicable to both frame type and aeroderivative gas turbines. Under the constraints of the cycle analysis we have designed a high temperature advanced furnace (FHTAF) which integrates several combustor and air heater designs with appropriate ash management procedures. The cycle optimization effort has brought about several revisions to the system configuration resulting from: (1) the use of Illinois No. 6 coal instead of Utah Blind Canyon; (2) the use of coal rather than methane as a reburn fuel; (3) reducing radiant section outlet temperatures to 1700F (down from 1800F); and (4) the need to use higher performance (higher cost) steam cycles to offset losses introduced as more realistic operating and construction constraints are identified.

Not Available

1992-12-31T23:59:59.000Z

197

Bioprocessing of High-sulfur Crudes Via Appliaction of Critical Fluid Biocatalysis  

SciTech Connect (OSTI)

This experimental research project investigated protein-based biocatalysis in supercritical fluid solvents as an integrated process approach to catalyze the removal of sulfur atoms from crude oils and fuels. The work focused on the oxidation of model sulfur-containing compounds in supercritical reaction media and included three major tasks: microbiological induction experiments, proteincatalyzed biooxidation in supercritical solvents, and a work-in-kind cooperative research and development agreement (CRADA). This work demonstrated that the biooxidation reaction could be improved by an order-of-magnitude by carrying out the reaction in emulsions in supercritical fluids.

Ginosar, Daniel Michael; Bala, Greg Alan; Anderson, Raymond Paul; Fox, Sandra Lynn; Stanescue, Marina A.

2002-05-01T23:59:59.000Z

198

Coal-bench architecture as a means of understanding regional changes in coal thickness and quality  

SciTech Connect (OSTI)

Analysis of the Fire Creek (Westphalian B), Pond Creek (lower Westphalian B), and Stockton (Westphalian B) coals, three of the most heavily mined coals in the Central Appalachian Basin, shows that all have a similar multiple-bench architecture of at least two benches split by a regional clastic parting or durain. Coal benches beneath regionally extensive partings are generally less continuous, thinner, more palynologically variable, higher in ash yield, and higher in sulfur content than coal benches above regional partings in all three coals. Where thick, benches above regional partings tend to exhibit temporal palynological changes from lycopod- to fern-dominant. Where inertinite-rich/fern-dominant benches are overlain by additional benches, the upper benches are limited in extent, variable in thickness, high in sulfur content and ash yield, and split away from the coal. The multiple-bench architecture exhibited by these coals is interpreted to represent a cyclic mire succession that was common in the Middle Pennsylvanian. Peats began as planar mires infilling an irregular topography during rising base level. When the topography was infilled, unconfined flooding was possible and resulted in widespread partings. Ponding above these clay-rich flood deposits led to re-establishment of new planar mires with greater continuity than the underlying mires. The extent of these mires provided buffers to clastic influx and, in many cases, allowed domed conditions to develop. Doming resulted in thick, high-quality coal benches. In some cases, a third stage of planar peats, with similar characteristics to the planar peats at the base of the beds, developed on the unevenly distributed clastics that buried underlying mires during continued base-level rise.

Greb, S.F.; Eble, C.F. [Kentucy Geological Survey, Lexington, KY (United States); Hower, J.C. [Center for Applied Research, Lexington, KY (United States)

1996-09-01T23:59:59.000Z

199

Role of coal in the world and Asia  

SciTech Connect (OSTI)

This paper examines the changing role of coal in the world and in Asia. Particular attention is given to the rapidly growing demand for coal in electricity generation, the importance of China as a producer and consumer of coal, and the growing environmental challenge to coal. Attention is given to the increasing importance of low sulfur coal and Clean Coal Technologies in reducing the environmental impacts of coal burning.

Johnson, C.J.; Li, B.

1994-10-01T23:59:59.000Z

200

Coal preparation: The essential clean coal technology  

SciTech Connect (OSTI)

This chapter is a brief introduction to a broad topic which has many highly specialized areas. The aim is to summarize the essential elements of coal preparation and illustrate its important role in facilitating the clean use of coal. Conventional coal preparation is the essential first step in ensuring the economic and environmentally acceptable use of coal. The aim of coal preparation is to produce saleable products of consistent, specified quality which satisfy customer requirements while optimizing the utilization of the coal resource. Coal preparation covers all aspects of preparing coal for the market. It includes size reduction, blending and homogenization and, most importantly, the process of physical beneficiation or washing, which involves separation of undesirable mineral matter from the coal substance itself. Coal preparation can be performed at different levels of sophistication and cost. The degree of coal preparation required is decided by considering the quality of the raw coal, transport costs and, in particular, the coal quality specified by the consumer. However, the cost of coal beneficiation rises rapidly with the complexity of the process and some coal is lost with the waste matter because of process inefficiencies, therefore each situation requires individual study to determine the optimum coal preparation strategy. The necessary expertise is available within APEC countries such as Australia. Coals destined for iron making are almost always highly beneficiated. Physical beneficiation is mostly confined to the higher rank, hard coals, but all other aspects of coal preparation can be applied to subbituminous and lignitic coals to improve their utilization. Also, there are some interesting developments aimed specifically at reducing the water content of lower rank coals.

Cain, D.

1993-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Final Report - Management of High Sulfur HLW, VSL-13R2920-1, Rev. 0, dated 10/31/2013  

SciTech Connect (OSTI)

The present report describes results from a series of small-scale crucible tests to determine the extent of corrosion associated with sulfur containing HLW glasses and to develop a glass composition for a sulfur-rich HLW waste stream, which was then subjected to small-scale melter testing to determine the maximum acceptable sulfate loadings. In the present work, a new glass formulation was developed and tested for a projected Hanford HLW composition with sulfate concentrations high enough to limit waste loading. Testing was then performed on the DM10 melter system at successively higher waste loadings to determine the maximum waste loading without the formation of a separate sulfate salt phase. Small scale corrosion testing was also conducted using the glass developed in the present work, the glass developed in the initial phase of this work [26], and a high iron composition, all at maximum sulfur concentrations determined from melter testing, in order to assess the extent of Inconel 690 and MA758 corrosion at elevated sulfate contents.

Kruger, Albert A.; Gan, H.; Pegg, I. L.; Feng, Z.; Gan, H,; Joseph, I.; Matlack, K. S.

2013-11-13T23:59:59.000Z

202

Exploration of coal-based pitch precursors for ultra-high thermal conductivity graphite fibers. Final report  

SciTech Connect (OSTI)

Goal was to explore the utility of coal-based pitch precursors for use in ultra high thermal conductivity carbon (graphite) fibers. From graphite electrode experience, it was established that coal-based pitches tend to form more highly crystalline graphite at lower temperatures. Since the funding was limited to year 1 effort of the 3 year program, the goal was only partially achieved. The coal-base pitches can form large domain mesophase in spite of high N and O contents. The mesophase reactivity test performed on one of the variants of coal-based pitch (DO84) showed that it was not a good candidate for carbon fiber processing. Optimization of WVU`s isotropic pitch process is required to tailor the pitch for carbon fiber processing. The hetero atoms in the coal pitch need to be reduced to improve mesophase formation.

Deshpande, G.V. [Amoco Performance Products, Inc., Alpharetta, GA (United States)

1996-12-27T23:59:59.000Z

203

State coal profiles, January 1994  

SciTech Connect (OSTI)

The purpose of State Coal Profiles is to provide basic information about the deposits, production, and use of coal in each of the 27 States with coal production in 1992. Although considerable information on coal has been published on a national level, there is a lack of a uniform overview for the individual States. This report is intended to help fill that gap and also to serve as a framework for more detailed studies. While focusing on coal output, State Coal Profiles shows that the coal-producing States are major users of coal, together accounting for about three-fourths of total US coal consumption in 1992. Each coal-producing State is profiled with a description of its coal deposits and a discussion of the development of its coal industry. Estimates of coal reserves in 1992 are categorized by mining method and sulfur content. Trends, patterns, and other information concerning production, number of mines, miners, productivity, mine price of coal, disposition, and consumption of coal are detailed in statistical tables for selected years from 1980 through 1992. In addition, coal`s contribution to the State`s estimated total energy consumption is given for 1991, the latest year for which data are available. A US summary of all data is provided for comparing individual States with the Nation as a whole. Sources of information are given at the end of the tables.

Not Available

1994-02-02T23:59:59.000Z

204

Clean coal technology applications  

SciTech Connect (OSTI)

{open_quotes}Coal is a stratified rock formed of the more or less altered remains of plants (together with associated mineral matter) which flourished in past ages{hor_ellipsis} The problem of the origin and maturing of coal is complicated by the fact that every coal contains, in addition to carbon, hydrogen and oxygen, variable proportions of nitrogen and sulfur which are combined in unknown ways in the organic molecules...{close_quotes}. The challenge with coal has always been the management of its mineral matter, sulfur and nitrogen contents during use. The carbon content of fuels, including coal, is a more recent concern. With clean coal technologies, there are opportunities for ensuring the sustained use of coal for a very long time. The clean coal technologies of today are already capable of reducing, if not eliminating, harmful emissions. The technologies of the future will allow coal to be burned with greatly reduced emissions, thus eliminating the necessity to treat them after they occur.

Bharucha, N.

1993-12-31T23:59:59.000Z

205

Elemental sulfur recovery process  

DOE Patents [OSTI]

An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO[sub 2] in the regenerator off gas stream to elemental sulfur in the presence of a catalyst. 4 figures.

Flytzani-Stephanopoulos, M.; Zhicheng Hu.

1993-09-07T23:59:59.000Z

206

Characterization of feed coal and coal combustion products from power plants in Indiana and Kentucky  

SciTech Connect (OSTI)

The US Geological Survey, Kentucky Geological Survey, and the University of Kentucky Center for Applied Energy Research are collaborating with Indiana and Kentucky utilities to determine the physical and chemical properties of feed coal and coal combustion products (CCP) from three coal-fired power plants. These three plants are designated as Units K1, K2, and I1 and burn high-, moderate-, and low-sulfur coals, respectively. Over 200 samples of feed coal and CCP were analyzed by various chemical and mineralogical methods to determine mode of occurrence and distribution of trace elements in the CCP. Generally, feed coals from all 3 Units contain mostly well-crystallized kaolinite and quartz. Comparatively, Unit K1 feed coals have higher amounts of carbonates, pyrite and sphalerite. Unit K2 feed coals contain higher kaolinite and illite/muscovite when compared to Unit K1 coals. Unit I1 feed coals contain beta-form quartz and alumino-phosphates with minor amounts of calcite, micas, anatase, and zircon when compared to K1 and K2 feed coals. Mineralogy of feed coals indicate that the coal sources for Units K1 and K2 are highly variable, with Unit K1 displaying the greatest mineralogic variability; Unit I1 feed coal however, displayed little mineralogic variation supporting a single source. Similarly, element contents of Units K1 and K2 feed coals show more variability than those of Unit I1. Fly ash samples from Units K1 and K2 consist mostly of glass, mullite, quartz, and spines group minerals. Minor amounts of illite/muscovite, sulfates, hematite, and corundum are also present. Spinel group minerals identified include magnetite, franklinite, magnesioferrite, trevorite, jacobisite, and zincochromite. Scanning Electron Microscope analysis reveals that most of the spinel minerals are dendritic intergrowths within aluminum silicate glass. Unit I1 fly ash samples contain glass, quartz, perovskite, lime, gehlenite, and apatite with minor amounts of periclase, anhydrite, carbonates, pyroxenes, and spinels. The abundant Ca mineral phases in the Unit I1 fly ashes are attributed to the presence of carbonate, clay and phosphate minerals in the coal.

Brownfield, M.E.; Affolter, R.H.; Cathcart, J.D.; O'Connor, J.T.; Brownfield, I.K.

1999-07-01T23:59:59.000Z

207

Autothermal reforming of sulfur-free and sulfur-containing hydrocarbon liquids  

SciTech Connect (OSTI)

The mechanisms by which various fuel component hydrocarbons related to both heavy petroleum and coal-derived liquids are converted to hydrogen without forming carbon were investigated. Reactive differences between paraffins and aromatics in autothermal reforming (ATR) were shown to be responsible for the observed fuel-specific carbon formation characteristics. The types of carbon formed in the reformer were identified by SEM and XRD analyses of catalyst samples and carbon deposits. From tests with both light and heavy paraffins and aromatics, it is concluded that high boiling point hydrocarbons and polynuclear aromatics enhance the propensity for carbon formation. The effects of propylene addition on the ATR performance of benzene are described. In ATR tests with mixtures of paraffins and aromatics, synergistic effects on conversion characteristics were identified. Indications that the sulfur content of the fuel may be the limiting factor for efficient ATR operation were found. The conversion and degradation effects of the sulfur additive (thiophene) were examined.

Not Available

1981-10-01T23:59:59.000Z

208

Selective catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly technical progress report No. 6, October--December 1993  

SciTech Connect (OSTI)

Elemental sulfur recovery from SO{sub 2}-containing gas stream is highly attractive as it produces a salable product and no waste to dispose of. However, commercially available schemes are complex and involve multi-stage reactors, such as, most notably in the Resox (reduction of SO{sub 2} with coke) and Claus plant (reaction of SO{sub 2} with H{sub 2}S over catalyst). This project will investigate a cerium oxide catalyst for the single stage selective reduction of SO{sub 2} to elemental sulfur by a reductant, such as carbon monoxide. Cerium oxide has been identified in recent work at MIT as a superior catalyst for SO{sub 2} reduction by CO to elemental sulfur because its high activity and high selectivity to sulfur over COS over a wide temperature range (400--650{degree}C). The detailed kinetic and parametric studies of SO{sub 2} reduction planned in this work over various CeO{sub 2} formulations will provide the necessary basis for development of a very simplified process, namely that of a single-stage elemental sulfur recovery scheme from variable concentration gas streams. The potential cost- and energy-efficiency benefits from this approach can not be overstated. A first apparent application is treatment of a regenerator off-gases in power plants using regenerative flue gas desulfurization. Such a simple catalytic converter may offer the long-sought ``Claus-alternative`` for coal-fired power plant applications.

Liu, W.; Flytzani-Stephanopoulos, M.; Sarofim, A.F.

1993-12-31T23:59:59.000Z

209

Selective catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly technical progress report No. 4, April--June 1993  

SciTech Connect (OSTI)

Elemental sulfur recovery from SO{sub 2}-containing gas stream is highly attractive as it produces a salable product and no waste to dispose of. However, commercially available schemes are complex and involve multi-stage reactors, such as, most notably in the Resox (reduction of SO{sub 2} with coke) and Claus plant(reaction of SO{sub 2} with H{sub 2}S over catalyst). This project will investigate a cerium oxide catalyst for the single stage selective reduction of SO{sub 2} to elemental sulfur by a reductant, such as carbon monoxide. Cerium oxide has been identified in recent work at MIT as a superior catalyst for SO{sub 2} reduction by CO to elemental sulfur because its high activity and high selectivity to sulfur over COS over a wide temperature range(400--650{degrees}C). The detailed kinetic and parametric studies of SO{sub 2} reduction planned in this work over various CeO{sub 2}-formulations will provide the necessary basis for development of a very simplified process, namely that of a single-stage elemental sulfur recovery scheme from variable concentration gas streams, The potential cost- and energy-efficiency benefits from this approach can not be overstated. A first apparent application is treatment of a regenerator off-gases in power plants using regenerative flue gas desulfurization. Such a simple catalytic converter may offer the long-sought ``Claus-alternative`` for coal-fired power plant applications.

Liu, Wei; Flytzani-Stephanopoulos, M.; Sarofim, A.F.; Williams, R.S.

1993-12-31T23:59:59.000Z

210

The magnetohydrodynamics Coal-Fired Flow Facility  

SciTech Connect (OSTI)

In this quarterly technical progress report, UTSI reports on progress on a multi-task contract to develop the technology for the steam bottoming plant for an MHD Steam Combined Cycle power plant. Two proof-of-concept (POC) tests totaling 614 hours of coal fired operation were conducted during the quarter using low sulfur Montana Rosebud coal. The results of these tests are summarized. Operational aspects of the particulate control devices being evaluated, a dry electrostatic precipitator (ESP) and a reverse air baghouse, are discussed. A sootblowing control system for the convective heat transfer surfaces that senses the need to clean the tubes by temperatures is described. Environmental reporting includes measurement of levels of ground water wells over time and the remote air quality measurements of impact of the stack emissions from the two tests. Results of testing candidate ceramic tubes for a recuperative high temperature air heater are included. Analyses of the tube materials tested in the 2000 hour test series previously completed on high sulfur Illinois No. 6 coal are summarized. Facility maintenance and repair activities for the DOE Coal Fired Flow Facility are summarized. The major facility modification discussed is the completion of the installation of a Wet ESP with rotary vacuum filter which is replacing the venturi scrubber as the primary facility particulate control device for any exhaust gases that are not routed through the dry ESP or baghouse.

Not Available

1993-02-01T23:59:59.000Z

211

Low-rank coal study : national needs for resource development. Volume 2. Resource characterization  

SciTech Connect (OSTI)

Comprehensive data are presented on the quantity, quality, and distribution of low-rank coal (subbituminous and lignite) deposits in the United States. The major lignite-bearing areas are the Fort Union Region and the Gulf Lignite Region, with the predominant strippable reserves being in the states of North Dakota, Montana, and Texas. The largest subbituminous coal deposits are in the Powder River Region of Montana and Wyoming, The San Juan Basin of New Mexico, and in Northern Alaska. For each of the low-rank coal-bearing regions, descriptions are provided of the geology; strippable reserves; active and planned mines; classification of identified resources by depth, seam thickness, sulfur content, and ash content; overburden characteristics; aquifers; and coal properties and characteristics. Low-rank coals are distinguished from bituminous coals by unique chemical and physical properties that affect their behavior in extraction, utilization, or conversion processes. The most characteristic properties of the organic fraction of low-rank coals are the high inherent moisture and oxygen contents, and the correspondingly low heating value. Mineral matter (ash) contents and compositions of all coals are highly variable; however, low-rank coals tend to have a higher proportion of the alkali components CaO, MgO, and Na/sub 2/O. About 90% of the reserve base of US low-rank coal has less than one percent sulfur. Water resources in the major low-rank coal-bearing regions tend to have highly seasonal availabilities. Some areas appear to have ample water resources to support major new coal projects; in other areas such as Texas, water supplies may be constraining factor on development.

Not Available

1980-11-01T23:59:59.000Z

212

Characterization of selected Ohio coals to predict their conversion behavior relative to 104 North American Coals. [Factors correlating with liquefaction behavior  

SciTech Connect (OSTI)

Twenty-six coal samples from Ohio were collected as washed and seam samples, and lithobodies within the seams. Characterization of these samples included determination of % maceral, % anti R/sub max/, LTA, chlorine content and proximate/ultimate and qualitative mineral analyses. These data were compared to data from a similar project by Yarzab, R.F., et al., 1980 completed at Pennsylvania State University using tetralin as the hydrogen donor solvent. The characteristics of these coals were correlated with liquefaction conversion and other data accrued on 104 North American coals by statistical analyses. Utilizing percent carbon, sulfur, volatile matter, reflectance, vitrinite and total reactive macerals, Q-mode cluster analysis demonstrated that Ohio coals are more similar to the coals of the Interior province than to those of the Appalachian province. Linear multiple regression analysis for the 104 North American coals provided a prediction equation for conversion (R = .96). The predicted conversion values for the samples range from 58.8 to 79.6%, with the Lower Kittanning (No. 5) and the Middle Kittanning (No. 6) coal seams showing the highest predicted percent conversion (respectively, 73.4 and 72.2%). The moderately low FSI values for the No. 5 and No. 6 coals (respectively, 2.5 and 3) and their moderately high alkaline earth content (respectively, 0.69 and 0.74%) suggest that these coals possess the best overall properties for conversion. Stepwise regression has indicated that the most important coal characteristics affecting conversion are, in decreasing order of importance: % volatile matter, % vitrinite and % total sulfur. Conversion processes can be expected to produce higher yields with Ohio coals due to the presence of such mineral catalysts as pyrite and kaolinite. It is believed that the presence of these disposable catalysts increases the marketability of Ohio coals.

Whitacre, T. P.; Hunt, T. J.; Kneller, W. A.

1982-02-01T23:59:59.000Z

213

Advanced byproduct recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Fourth quarterly technical progress report  

SciTech Connect (OSTI)

The team of Arthur D. Little, Tufts University and Engelhard Corporation are conducting Phase 1 of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an on-going DOE-sponsored, University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicate that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. The performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams.

NONE

1997-01-01T23:59:59.000Z

214

High temperature properties and reactivity of coal and coke for ironmaking.  

E-Print Network [OSTI]

??Rapid growth of the steel industry in coming years will be strongly dependent upon coal. Understanding of coal behavior in current or emerging ironmaking processes… (more)

Kim, Byong-Chul

2012-01-01T23:59:59.000Z

215

Performance and cost models for the direct sulfur recovery process. Task 1 Topical report, Volume 3  

SciTech Connect (OSTI)

The purpose of this project is to develop performance and cost models of the Direct Sulfur Recovery Process (DSRP). The DSRP is an emerging technology for sulfur recovery from advanced power generation technologies such as Integrated Gasification Combined Cycle (IGCC) systems. In IGCC systems, sulfur present in the coal is captured by gas cleanup technologies to avoid creating emissions of sulfur dioxide to the atmosphere. The sulfur that is separated from the coal gas stream must be collected. Leading options for dealing with the sulfur include byproduct recovery as either sulfur or sulfuric acid. Sulfur is a preferred byproduct, because it is easier to handle and therefore does not depend as strongly upon the location of potential customers as is the case for sulfuric acid. This report describes the need for new sulfur recovery technologies.

Frey, H.C. [North Carolina State Univ., Raleigh, NC (United States); Williams, R.B. [Carneigie Mellon Univ., Pittsburgh, PA (United States)

1995-09-01T23:59:59.000Z

216

Mining conditions and deposition in the Amburgy (Westphalian B) coal, Breathitt Group, central Appalachian basin  

SciTech Connect (OSTI)

Carbonate concretions called clay balls are rare in the Central Appalachian Basin, but were found in the Amburgy coal overlain by the Kendrick Shale Member. In the study area, the Amburgy coal is 0.7 to 0.9 meters thick, moderate to high in sulfur content, moderate to high in ash yield, and mostly bright clarain, except at the top near the area of coal balls, where durain of limited extent occurs. The coal is co-dominated by lycopod and cordaites; tree spores, with subordinate Calamites. The local durain layer is dominated by Densosporites, produced by the shrubby lycopod Ompbalophloios. Coal balls were encountered where the durain is immediately overlain by a coquinoid hash of broken and whole marine fossils, along a trend of coal thinning. The coal balls contain permineralized cordaites, lycopods, calamites, and ferns. The Amburgy coal accumulated as a succession of planar mires. Local splits in the seam are common, indicating contemporaneous clastic influx. The abundance of Cordaites may indicate brackish mire waters related to a coastal position and initial eustatic rise of the marginal Kendrick seas. Near the end of the Amburgy mires, the high ash-Omphalopbloios association is interpreted as a local area that was being drowned by the Kendrick transgression. Ravinement within this local embayment, rapid inundation by marine waters, and concentration of carbonate-bearing waters within transgressive scours may have contributed to the formation of coal balls and pyritic concretions in the upper part of the coal bed.

Greb, S.F.; Eble, C.F. [Kentucky Geological Survey, Lexington, KY (United States); Hower, J.C. [Center for Applied Research, Lexington, KY (United States); Phillips, T.L. [Univ. of illinois, Urbana, IL (United States)

1996-09-01T23:59:59.000Z

217

Coal Study Guide - High School | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTieCelebrate Earth DayFuelsDepartmentPolicyClean, EEREClosureHigh School

218

Method of extracting coal from a coal refuse pile  

DOE Patents [OSTI]

A method of extracting coal from a coal refuse pile comprises soaking the coal refuse pile with an aqueous alkali solution and distributing an oxygen-containing gas throughout the coal refuse pile for a time period sufficient to effect oxidation of coal contained in the coal refuse pile. The method further comprises leaching the coal refuse pile with an aqueous alkali solution to solubilize and extract the oxidized coal as alkali salts of humic acids and collecting the resulting solution containing the alkali salts of humic acids. Calcium hydroxide may be added to the solution of alkali salts of humic acid to form precipitated humates useable as a low-ash, low-sulfur solid fuel.

Yavorsky, Paul M. (Monongahela, PA)

1991-01-01T23:59:59.000Z

219

High performance materials in coal conversion utilization. Technical progress report, January 1, 1994--March 31, 1994  

SciTech Connect (OSTI)

This is the second quarterly report concerning this three year grant on {open_quotes}High Performance Materials in Coal Conversion Utilization.{close_quotes} The grant is for a joint university/industry effort under the US Department of Energy (DOE) University Coal Research Program. The University of Tennessee Space Institute (UTSI) is the prime contractor and The University of Pennsylvania and Lanxide Corporation are subcontractors. The administrative details involved in the finalizing of the subcontracts and the acquisition of the cost shared equipment by UTSI and the U of Pa has slowed progress somewhat, however, the project should go smoothly from this point on. Most of the efforts of this quarter have gone toward preparing the equipment and plans for the laboratory tests. Research into the identification of a suitable protective coating based on thermodynamic considerations and the development of techniques for their application as well as joining ceramic materials has been initiated.

Not Available

1994-04-01T23:59:59.000Z

220

Performance of a high efficiency advanced coal combustor. Task 2, Pilot scale combustion tests: Final report  

SciTech Connect (OSTI)

Under contract from DOE-PETC, Combustion Engineering, Inc. undertook the lead-role in a multi-task R&D program aimed at development of a new burner system for coal-based fuels; the goal was that this burner system should be capable of being retrofitted in oil- or gas-fired industrial boilers, or usable in new units. In the first phase of this program a high efficiency advanced coal combustor was designed jointly by CE and MIT. Its burner is of the multiannular design with a fixed shrouded swirler in the center immediately surrounding the atomizer gun to provide the ``primary act,`` and three further annuli for the supply of the ``secondary air.`` The degree of rotation (swirl) in the secondary air is variable. The split of the combustion air into primary and secondary air flows serves the purpose of flame stabilization and combustion staging, the latter to reduce NO{sub x} formation.

Toqan, M.A.; Paloposki, T.; Yu, T.; Teare, J.D.; Beer, J.M. [Massachusetts Inst. of Tech., Cambridge, MA (United States)

1989-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

ENGINEERING DEVELOPMENT OF COAL-FIRED HIGH PERFORMANCE POWER SYSTEMS PHASE II AND III  

SciTech Connect (OSTI)

This report presents work carried out under contract DE-AC22-95PC95144 "Engineering Development of Coal-Fired High Performance Systems Phase II and III." The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) that is capable of: à thermal efficiency (HHV) >47%; à NOx, SOx, and particulates <10% NSPS (New Source Performance Standard); à coal providing >65% of heat input; à all solid wastes benign; à cost of electricity <90% of present plants. Phase I, which began in 1992, focused on the analysis of various configurations of indirectly fired cycles and on technical assessments of alternative plant subsystems and components, including performance requirements, developmental status, design options, complexity and reliability, and capital and operating costs. Phase I also included preliminary R&D and the preparation of designs for HIPPS commercial plants approximately 300 MWe in size. This phase, Phase II, involves the development and testing of plant subsystems, refinement and updating of the HIPPS commercial plant design, and the site selection and engineering design of a HIPPS prototype plant. Work reported herein is from: à Task 2.2 HITAF Air Heaters; à Task 6 HIPPS Commercial Plant Design Update.

NONE

1998-09-30T23:59:59.000Z

222

TRP0033 - PCI Coal Combustion Behavior and Residual Coal Char Carryover in the Blast Furnace of 3 American Steel Companies during Pulverized Coal Injection (PCI) at High Rates  

SciTech Connect (OSTI)

Combustion behavior of pulverized coals (PC), gasification and thermal annealing of cokes were investigated under controlled environments. Physical and chemical properties of PCI, coke and carbon residues of blast furnace dust/sludge samples were characterized. The strong influence of carbon structure and minerals on PCI reactivity was demonstrated. A technique to characterize char carryover in off gas emissions was established.

Veena Sahajwalla; Sushil Gupta

2005-04-15T23:59:59.000Z

223

A LOW COST AND HIGH QUALITY SOLID FUEL FROM BIOMASS AND COAL FINES  

SciTech Connect (OSTI)

Use of biomass wastes as fuels in existing boilers would reduce greenhouse gas emissions, SO2 and NOx emissions, while beneficially utilizing wastes. However, the use of biomass has been limited by its low energy content and density, high moisture content, inconsistent configuration and decay characteristics. If biomass is upgraded by conventional methods, the cost of the fuel becomes prohibitive. Altex has identified a process, called the Altex Fuel Pellet (AFP) process, that utilizes a mixture of biomass wastes, including municipal biosolids, and some coal fines, to produce a strong, high energy content, good burning and weather resistant fuel pellet, that is lower in cost than coal. This cost benefit is primarily derived from fees that are collected for accepting municipal biosolids. Besides low cost, the process is also flexible and can incorporate several biomass materials of interest The work reported on herein showed the technical and economic feasibility of the AFP process. Low-cost sawdust wood waste and light fractions of municipal wastes were selected as key biomass wastes to be combined with biosolids and coal fines to produce AFP pellets. The process combines steps of dewatering, pellet extrusion, drying and weatherizing. Prior to pilot-scale tests, bench-scale test equipment was used to produce limited quantities of pellets for characterization. These tests showed which pellet formulations had a high potential. Pilot-scale tests then showed that extremely robust pellets could be produced that have high energy content, good density and adequate weatherability. It was concluded that these pellets could be handled, stored and transported using equipment similar to that used for coal. Tests showed that AFP pellets have a high combustion rate when burned in a stoker type systems. While NOx emissions under stoker type firing conditions was high, a simple air staging approach reduced emissions to below that for coal. In pulverized-fuel-fired tests it was found that the ground pellets could be used as an effective NOx control agent for pulverized-coal-fired systems. NOx emissions reductions up to 63% were recorded, when using AFP as a NOx control agent. In addition to performance benefits, economic analyses showed the good economic benefits of AFP fuel. Using equipment manufacturer inputs, and reasonable values for biomass, biosolids and coal fines costs, it was determined that an AFP plant would have good profitability. For cases where biosolids contents were in the range of 50%, the after tax Internal Rates of Return were in the range of 40% to 50%. These are very attractive returns. Besides the baseline analysis for the various AFP formulations tested at pilot scale, sensitivity analysis showed the impact of important parameters on return. From results, it was clear that returns are excellent for a range of parameters that could be expected in practice. Importantly, these good returns are achieved even without incentives related to the emissions control benefits of biomass.

John T. Kelly; George Miller; Mehdi Namazian

2001-07-01T23:59:59.000Z

224

Coal gasification power generation, and product market study. Topical report, March 1, 1995--March 31, 1996  

SciTech Connect (OSTI)

This Western Research Institute (WRI) project was part of a WRI Energy Resource Utilization Program to stimulate pilot-scale improved technologies projects to add value to coal resources in the Rocky Mountain region. The intent of this program is to assess the application potential of emerging technologies to western resources. The focus of this project is on a coal resource near the Wyoming/Colorado border, in Colorado. Energy Fuels Corporation/Kerr Coal Company operates a coal mine in Jackson County, Colorado. The coal produces 10,500 Btu/lb and has very low sulfur and ash contents. Kerr Coal Company is seeking advanced technology for alternate uses for this coal. This project was to have included a significant cost-share from the Kerr Coal Company ownership for a market survey of potential products and technical alternatives to be studied in the Rocky Mountain Region. The Energy Fuels Corporation/Kerr Coal Company and WRI originally proposed this work on a cost reimbursable basis. The total cost of the project was priced at $117,035. The Kerr Coal Company had scheduled at least $60,000.00 to be spent on market research for the project that never developed because of product market changes for the company. WRI and Kerr explored potential markets and new technologies for this resource. The first phase of this project as a preliminary study had studied fuel and nonfuel technical alternatives. Through related projects conducted at WRI, resource utilization was studied to find high-value materials that can be targeted for fuel and nonfuel use and eventually include other low-sulfur coals in the Rocky Mountain region. The six-month project work was spread over about a three-year period to observe, measure, and confirm over time-any trends in technology development that would lead to economic benefits in northern Colorado and southern Wyoming from coal gasification and power generation.

Sheesley, D.; King, S.B.

1998-12-31T23:59:59.000Z

225

A simple synthesis method of sulfur-free Fe-N-C catalyst witih high ORR activity  

SciTech Connect (OSTI)

To try to deconvolute which factors affect the activity and durability of metal-nitrogen-carbon (M-N-C) type non-precious catalysts for oxygen reduction reaction (ORR), M-N-C catalysts based on ion chloride, polyaniline (PANI) and Ketjen Black carbon support were synthesized using different synthetic conditions. The catalysts were characterized electrochemically and tested as cathodes for Hydrogen fuel cells. PANI is usually chemically oxidative polymerized using ammonium persulfate (APS) as oxidant. To eliminate sulfur in the synthesized catalysts, a simple synthesis method using ion chloride as oxidant for aniline polymerization was developed. Two different aniline polymerization conditions led to very different product morphologies. Synthesized at low initial proton concentration, the final product was composed of dense micrometer sized particles. A decomposable salt was found to be able to prohibit PANI cross linking during the drying and annealing process and thus led to porous product. The porous catalyst has much higher ORR activity than the dense product due to more accessible active sites. Synthesized at high proton concentration, the catalyst appeared to be porous. The decomposable salt treatment did not make too much improvement in the porous structure and electrochemical activity. However, fuel cell testing using air as cathode feeder indicates that the salt treatment improves mass transfer in the cathode layer. Catalyst synthesized using this simple method has performance comparable to our state-of-the art catalyst synthesized in a much more complicated procedure. The factor that sulfur sources are completely eliminated in the synthesis suggests that sulfur is not necessary for the ORR catalysis activity.

Ding, Zhongfen [Los Alamos National Laboratory; Johnston, Christina M [Los Alamos National Laboratory; Zelenay, Piotr [Los Alamos National Laboratory

2010-01-01T23:59:59.000Z

226

Coal upgrading program for Usti nad Labem, Czech Republic: Task 8.3. Topical report, October 1994--August 1995  

SciTech Connect (OSTI)

Coal has been a major energy source in the Czech Republic given its large coal reserves, especially brown coal and lignite (almost 4000 million metric tons) and smaller reserves of hard, mainly bituminous, coal (over 800 million tons). Political changes since 1989 have led to the reassessment of the role of coal in the future economy as increasing environmental regulations affect the use of the high-sulfur and high-ash brown coal and lignite as well as the high-ash hard coal. Already, the production of brown coal has declined from 87 million metric tons per year in 1989 to 67 million metric tons in 1993 and is projected to decrease further to 50 million metric tons per year of brown coal by the year 2000. As a means of effectively utilizing its indigenous coal resources, the Czech Republic is upgrading various technologies, and these are available at different stages of development, demonstration, and commercialization. The purpose of this review is to provide a database of information on applicable technologies that reduce the impact of gaseous (SO{sub 2}, NO{sub x}, volatile organic compounds) and particulate emissions from the combustion of coal in district and residential heating systems.

Young, B.C.; Musich, M.A.

1995-10-01T23:59:59.000Z

227

Coal-fired high performance power generating system. Quarterly progress report, April 1--June 30, 1993  

SciTech Connect (OSTI)

This report covers work carried out under Task 2, Concept Definition and Analysis, Task 3, Preliminary R&D and Task 4, Commercial Generating Plant Design, under Contract AC22-92PC91155, ``Engineering Development of a Coal Fired High Performance Power Generation System`` between DOE Pittsburgh Energy Technology Center and United Technologies Research Center. The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) by the year 2000 that is capable of: >47% thermal efficiency; NO{sub x}, SO{sub x} and Particulates {le}25% NSPS; cost {ge}65% of heat input; all solid wastes benign. In order to achieve these goals our team has outlined a research plan based on an optimized analysis of a 250 MW{sub e} combined cycle system applicable to both frame type and aeroderivative gas turbines. Under the constraints of the cycle analysis we have designed a high temperature advanced furnace (HITAF) which integrates several combustor and air heater designs with appropriate ash management procedures. A survey of currently available high temperature alloys has been completed and some of their high temperature properties are shown for comparison. Several of the most promising candidates will be selected for testing to determine corrosion resistance and high temperature strength. The corrosion resistance testing of candidate refractory coatings is continuing and some of the recent results are presented. This effort will provide important design information that will ultimately establish the operating ranges of the HITAF.

Not Available

1993-11-01T23:59:59.000Z

228

Supercritical thermodynamics of sulfur and nitrogen species. Quarterly progress report, January 1, 1993--March 31, 1993  

SciTech Connect (OSTI)

Significant opportunity exists for the application of supercritical fluid (SCF) technology to coal processing, both for pretreatment of high sulfur coals, as well as liquefaction and treatment of coal liquids. Supercritical fluids are attractive solvents for a variety of coal processing applications because of their unusual solvating and mass transfer properties. Solubility studies have been carried out for a number of model coal and coal-liquid compounds, primarily in pure supercritical fluids. We are extending this database of model coal compound equilibria using modem techniques that have the advantage of being much more rapid than traditional techniques. Cosolvent effects on solubility are being investigated over a variety of solvent properties. In addition, specific molecular interactions are being investigated through spectroscopic techniques. The resulting data are being used to develop a chemical-physical equation of state (EOS) model of SCF solution with meaningful parameters. The equation of state wig be used to predict solubility behavior, which will permit the design and tailoring of SCF cosolvent systems for specific coal processing applications.

Eckert, C.A.

1993-07-01T23:59:59.000Z

229

Supercritical thermodynamics of sulfur and nitrogen species. Quarterly progress report, July 1, 1992--September 30, 1992  

SciTech Connect (OSTI)

Significant opportunity exists for the application of supercritical fluid (SCF) technology to coal processing, both for pretreatment of high sulfur coals, as well as liquefaction and treatment of coal liquids. Supercritical fluids are attractive solvents for a variety of coal processing applications because of their unusual solvating and mass transfer properties. Solubility studies have been carried out for a number of model coal and coal-liquid compounds, primarily in pure supercritical fluids. We are extending this database of model coal compound equilibria using modern techniques that have the advantage of being much more rapid than traditional techniques. Cosolvent effects on solubility are being investigated over a variety of solvent properties. In addition, specific molecular interactions are being investigated through spectroscopic techniques. The resulting data are being used to develop a chemical-physical equation of state (EOS) model of SCF solution with meaningful parameters. The equation of state will be used to predict solubility behavior, which will permit the desip and tailoring of SCF cosolvent systems for specific coal processing applications.

Eckert, C.A.

1991-10-01T23:59:59.000Z

230

High performance materials in coal conversion utilization. Final report, October 1, 1993--September 30, 1996  

SciTech Connect (OSTI)

This report describes the research conducted at the University of Tennessee Space Institute on high performance materials for use in corrosive environments. The work was supported by a US Department of Energy University Coal Research grant. Particular attention was given to the silicon carbide particulate reinforced alumina matrix ceramic composite manufactured by Lanxide Corporation as a potential tubular component in a coal-fired recuperative high-temperature air heater. Extensive testing was performed to determine the high temperature corrosion effects on the strength of the material. A computer modeling of the corrosion process was attempted but the problem proved to be too complex and was not successful. To simplify the situation, a computer model was successfully produced showing the corrosion thermodynamics involved on a monolithic ceramic under the High Performance Power System (HIPPS) conditions (see Appendix A). To seal the material surface and thus protect the silicon carbide particulate from corrosive attack, a dense non porous alumina coating was applied to the material surface. The coating was induced by a defocused carbon dioxide laser beam. High temperature corrosion and strength tests proved the effectiveness of the coating. The carbon dioxide laser was also used to successfully join two pieces of the Lanxide material, however, resources did not allow for the testing of the resulting joint.

McCay, T.D.; Boss, W.H. [ed.; Dahotre, N. [and others

1996-12-01T23:59:59.000Z

231

High Permeability Ternary Palladium Alloy Membranes with Improved Sulfur and Halide Tolerances  

SciTech Connect (OSTI)

The project team consisting of Southwest Research Institute{reg_sign} (SwRI{reg_sign}), Georgia Institute of Technology (GT), the Colorado School of Mines (CSM), TDA Research, and IdaTech LLC was focused on developing a robust, poison-tolerant, hydrogen selective free standing membrane to produce clean hydrogen. The project completed on schedule and on budget with SwRI, GT, CSM, TDA and IdaTech all operating independently and concurrently. GT has developed a robust platform for performing extensive DFT calculations for H in bulk palladium (Pd), binary alloys, and ternary alloys of Pd. Binary alloys investigated included Pd96M4 where M = Li, Na, Mg, Al, Si, Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Y, Zr, Nb, Mo, Tc, Ru, Rh, Ag, Cd, In, Sn, Sb, Te, Hf, Ta, W, Re, Os, Ir, Pt, Au, Tl, Pb, Bi, Ce, Sm, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu. They have also performed a series of calculations on Pd{sub 70}Cu{sub 26}Ag{sub 4}, Pd{sub 70}Cu{sub 26}Au{sub 4}, Pd{sub 70}Cu{sub 26}Ni{sub 4}, Pd{sub 70}Cu{sub 26}Pt{sub 4}, and Pd{sub 70}Cu{sub 26}Y{sub 4}. SwRI deposited and released over 160 foils of binary and ternary Pd alloys. There was considerable work on characterizing and improving the durability of the deposited foils using new alloy compositions, post annealing and ion bombardment. The 10 and 25 {micro}m thick films were sent to CSM, TDA and IdaTech for characterization and permeation testing. CSM conducted over 60 pure gas permeation tests with SwRI binary and ternary alloy membranes. To date the PdAu and PdAuPt membranes have exhibited the best performance at temperatures in the range of 423-773 C and their performance correlates well with the predictions from GT. TDA completed testing under the Department of Energy (DOE) WGS conditions on over 16 membranes. Of particular interest are the PdAuPt alloys that exhibited only a 20% drop in flux when sulfur was added to the gas mixture and the flux was completely recovered when the sulfur flow was stopped. IdaTech tested binary and ternary membranes on a simulated flue gas stream and experienced significant difficulty in mounting and testing the sputter deposited membranes. IdaTech was able to successfully test PdAu and PdAuPt membranes and saw similar sulfur tolerance to what TDA found. The Program met all the deliverables on schedule and on budget. Over ten presentations at national and international conferences were made, four papers were published (two in progress) in technical journals, and three students (2 at GT and 1 at CSM) completed their doctorates using results generated during the course of the program. The three major findings of program were; (1) the DFT modeling was verified as a predictive tool for the permeability of Pd based ternary alloys, (2) while magnetron sputtering is useful in precisely fabricating binary and ternary alloys, the mechanical durability of membranes fabricated using this technique are inferior compared to cold rolled membranes and this preparation method is currently not ready for industrial environments, (3) based on both modeling and experimental verification in pure gas and mixed gas environments PdAu and PdAuPt alloys were found to have the combination of the highest permeability and tolerance to sulfur.

K. Coulter

2010-12-31T23:59:59.000Z

232

Electric Power Research Institute, High Sulfur Test Center report to the Steering Committee, March 1994. [Monthly report  

SciTech Connect (OSTI)

Operations and maintenance continued this month at the Electric Power Research Institute`s High Sulfur Test Center. The Suncor Limestone Reagent and Dewatering tests were completed on the Pilot unit this month. As this test block ended, the Pilot unit was modified for the High Velocity Scrubbing tests. This testing began on March 28, 1994 with test PHV-AN. As Phase II of the Mini-Pilot Clear Liquor Scrubbing test block was completed this month, the unit was taken off-line. Testing on the Cold-Side Selective Catalytic Reduction (SCR) unit continued this month as ammonia slip measurements were conducted. Catalyst material from the reactor was inspected and sampled during a scheduled outage this month in preparation for a low temperature test block.

Not Available

1994-08-01T23:59:59.000Z

233

Compilation of data on strippable Fort Union coals in the northern Rocky Mountains and Great Plains region: A CD-ROM presentation  

SciTech Connect (OSTI)

The Fort Union Formation and equivalent formations of Paleocene age in the northern Rocky Mountains and Great Plains region contain 14 strippable coals that yielded more than 30 percent of the 1.03 billion short tons produced in the United States in 1996. These thick, low contaminant, compliant coals, which are utilized by electric power plants in 28 States, are being assessed by the US Geological Survey. The minable coals occur in the Powder River Basin in Wyoming and Montana, Hanna, Carbon and Greater Green River Basins in Wyoming, and Williston Basin in North Dakota. Production during the past 25 years of thick, high quality Fort Union and equivalent coal beds and zones in the region increased from 40 to more than 340 million short tons. The Powder River Basin is projected to produce 416 million short tons of coal in 2015. Major production in the Powder River Basin is from the Wyodak-Anderson, Anderson-Dietz, and Rosebud coal deposits. Producing Fort Union coals in the Williston Basin include the Beulah-Zap, Hagel, and Harmon coal deposits. Producing Fort Union coals in the Greater Green River Basin are in five beds of the Deadman coal zone. Coal production in the Hanna Basin is from eight beds in the Ferris and Hanna Formations. Coals in the Powder River Basin and Williston Basin contain much less sulfur and ash than coals produced in other regions in the conterminous US. When sulfur values are compared as pounds of SO{sub 2} per million Btu (as received basis), Powder River Basin and Williston Basin coals have the lowest amounts of any coals in the conterminous US.

Flores, R.M.; Bader, L.R.; Cavaroc, V.V. [Geological Survey, Denver, CO (United States)] [and others

1998-04-01T23:59:59.000Z

234

Cokemaking from coals of Kuzbas and Donbas  

SciTech Connect (OSTI)

The paper discusses features of Donetsk and Kuznetsk coals, the export capability of Ukraine coking industry, the selection of coal blends involving coals from different basins, and practical recommendations and techno-economic considerations. It is concluded that by raising the share of low-sulfur Kuznetsk coal in the blend to 50%, coke produced will meet all the requirements of European and American consumers.

Umansky, R.Z. [Resourcecomplect, Donetsk (Ukraine); Kovalev, E.T.; Drozdnik, I.D. [UKHIN, Kharkov (Ukraine)

1997-12-31T23:59:59.000Z

235

Durable zinc ferrite sorbent pellets for hot coal gas desulfurization  

DOE Patents [OSTI]

Durable, porous sulfur sorbents useful in removing hydrogen sulfide from hot coal gas are prepared by water pelletizing a mixture of fine zinc oxide and fine iron oxide with inorganic and organic binders and small amounts of activators such as sodium carbonate and molybdenite; the pellets are dried and then indurated at a high temperature, e.g., 1800.degree. C., for a time sufficient to produce crush-resistant pellets.

Jha, Mahesh C. (Arvada, CO); Blandon, Antonio E. (Thornton, CO); Hepworth, Malcolm T. (Edina, MN)

1988-01-01T23:59:59.000Z

236

Catalyst for the reduction of sulfur dioxide to elemental sulfur  

DOE Patents [OSTI]

The inventive catalysts allow for the reduction of sulfur dioxide to elemental sulfur in smokestack scrubber environments. The catalysts have a very high sulfur yield of over 90% and space velocity of 10,000 h{sup {minus}1}. They also have the capacity to convert waste gases generated during the initial conversion into elemental sulfur. The catalysts have inexpensive components, and are inexpensive to produce. The net impact of the invention is to make this technology practically available to industrial applications. 21 figs.

Jin, Y.; Yu, Q.; Chang, S.G.

1996-02-27T23:59:59.000Z

237

Briquette comprising caking coal and municipal solid waste  

SciTech Connect (OSTI)

Briquettes of specified geometry and composition are produced to serve as feed material or ''burden'' in a moving-burden gasifier for the production of a synthesis or fuel gas from organic solid waste materials and coal, including especially, the so-called ''caking'' coals, as in the process of copending application number 675,918. The briquettes are formed from a well-blended mixture of shredded organic solid wastes, including especially, municipal solid waste (Msw) or biomass, and crushed caking coal, including coal fines. A binder material may or may not be required, depending on the coal/msw ratio and the compaction pressure employed. The briquettes may be extruded, stamped, or pressed, employing compaction pressures in excess of 1000 psi, and preferably in the range of 2000 to 10,000 psi. The briquettes may be circular, polygonal, or irregular in cross-section; they may be solid, or concentrically perforated to form a hollow cylinder or polygon; they may be formed into saddles, pillows or doughnuts. The ratio of caking coal to shredded municipal solid waste is controlled so that each part of the predominantly cellulosic organic solid waste will be blended with 0.5 to 3.0 parts of crushed coal. Suitable binder materials include dewatered sewage slude (Dss), ''black liquor'' rich in lignin derivatives, black strap molasses, waste oil, and starch. The binder concentration is preferably in the range of 2 to 6 percent. If coals high in sulfur content are to be processed, at least a stoichiometric equivalent of dolomite may be included in the briquette formulation to eliminate a major fraction of the sulfur with the slag.

Schulz, H.W.

1980-09-30T23:59:59.000Z

238

Moist caustic leaching of coal  

DOE Patents [OSTI]

A process for reducing the sulfur and ash content of coal. Particulate coal is introduced into a closed heated reaction chamber having an inert atmosphere to which is added 50 mole percent NaOH and 50 mole percent KOH moist caustic having a water content in the range of from about 15% by weight to about 35% by weight and in a caustic to coal weight ratio of about 5 to 1. The coal and moist caustic are kept at a temperature of about 300.degree. C. Then, water is added to the coal and caustic mixture to form an aqueous slurry, which is washed with water to remove caustic from the coal and to produce an aqueous caustic solution. Water is evaporated from the aqueous caustic solution until the water is in the range of from about 15% by weight to about 35% by weight and is reintroduced to the closed reaction chamber. Sufficient acid is added to the washed coal slurry to neutralize any remaining caustic present on the coal, which is thereafter dried to produce desulfurized coal having not less than about 90% by weight of the sulfur present in the coal feed removed and having an ash content of less than about 2% by weight.

Nowak, Michael A. (Elizabeth, PA)

1994-01-01T23:59:59.000Z

239

Effects of high pressure-dependent leakoff and high process-zone stress in coal-stimulation treatments  

SciTech Connect (OSTI)

Hydraulic fracturing in coals has been studied extensively over the last two decades; however, there are factors that were often ignored or incorrectly diagnosed, resulting in screenouts. Assuming that a majority of the perforations are open and there are no problems with the stimulation fluids, screenouts during coal hydraulic-fracture treatments can be attributed to either high pressure-dependent leakoff (PDL), high process-zone stress (PZS) or in some cases both. The objective of this work is to discuss, help identify, and present solutions to address these reservoir-related issues such that screenouts can be avoided in optimized refracture treatments and new well stimulations. The tools for identifying these reservoir-related parameters include a diagnostic fracture-injection test (DFIT) and a grid-oriented fully functional 3D fracture simulator with shear decoupling. An example for each respective case is presented in this paper. In the first example, in which high PZS was considered to be the dominant reason for screenout or pressure out, the well was restimulated successfully by implementing the solutions presented in this paper. In the second example, in which high PDL was considered to be the main reason for screenout, there were several wells in the same project area that exhibited the same behavior resulting in screenouts. After implementing the solutions presented in this paper to address high PDL, all new wells were stimulated successfully without any issues.

Ramurthy, M.; Lyons, B.; Hendrickson, R.B.; Barree, R.D.; Magill, D.R. [Halliburton, Denver, CO (United States)

2009-08-15T23:59:59.000Z

240

Sensitivity of Fischer-Tropsch Synthesis and Water-Gas Shift Catalysts to Poisons from High-Temperature High-Pressure Entrained-Flow (EF) Oxygen-Blown Gasifier Gasification of Coal/Biomass Mixtures  

SciTech Connect (OSTI)

The successful adaptation of conventional cobalt and iron-based Fischer-Tropsch synthesis catalysts for use in converting biomass-derived syngas hinges in part on understanding their susceptibility to byproducts produced during the biomass gasification process. With the possibility that oil production will peak in the near future, and due to concerns in maintaining energy security, the conversion of biomass-derived syngas and syngas derived from coal/biomass blends to Fischer-Tropsch synthesis products to liquid fuels may provide a sustainable path forward, especially considering if carbon sequestration can be successfully demonstrated. However, one current drawback is that it is unknown whether conventional catalysts based on iron and cobalt will be suitable without proper development because, while ash, sulfur compounds, traces of metals, halide compounds, and nitrogen-containing chemicals will likely be lower in concentration in syngas derived from mixtures of coal and biomass (i.e., using an entrained-flow oxygen-blown gasifier) than solely from coal, other byproducts may be present in higher concentrations. The current project examines the impact of a number of potential byproducts of concern from the gasification of biomass process, including compounds containing alkali chemicals like the chlorides of sodium and potassium. In the second year, researchers from the University of Kentucky Center for Applied Energy Research (UK-CAER) continued the project by evaluating the sensitivity of a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to a number of different compounds, including KHCO{sub 3}, NaHCO{sub 3}, HCl, HBr, HF, H{sub 2}S, NH{sub 3}, and a combination of H{sub 2}S and NH{sub 3}. Cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts were also subjected to a number of the same compounds in order to evaluate their sensitivities.

Burtron Davis; Gary Jacobs; Wenping Ma; Khalid Azzam; Dennis Sparks; Wilson Shafer

2010-09-30T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Advanced coal-fueled gas turbine systems reference system definition update  

SciTech Connect (OSTI)

The objective of the the Direct Coal-Fueled 80 MW Combustion Turbine Program is to establish the technology required for private sector use of an advanced coal-fueled combustion turbine power system. Under this program the technology for a direct coal-fueled 80 MW combustion turbine is to be developed. This unit would be an element in a 207 MW direct coal-fueled combustion turbine combined cycle which includes two combustion turbines, two heat recovery steam generators and a steam turbine. Key to meeting the program objectives is the development of a successful high pressure slagging combustor that burns coal, while removing sulfur, particulates, and corrosive alkali matter from the combustion products. Westinghouse and Textron (formerly AVCO Research Laboratory/Textron) have designed and fabricated a subscale slagging combustor. This slagging combustor, under test since September 1988, has been yielding important experimental data, while having undergone several design iterations.

Not Available

1991-09-01T23:59:59.000Z

242

COMBINED RETENTION OF MOLYBDENUM AND SULFUR IN SIMULATED HIGH LEVEL WASTE GLASS  

SciTech Connect (OSTI)

This study was undertaken to investigate the effect of elevated sulfate and molybdenum concentrations in nuclear waste glasses. A matrix of 24 glasses was developed and the glasses were tested for acceptability based on visual observations, canister centerline-cooled heat treatments, and chemical composition analysis. Results from the chemical analysis of the rinse water from each sample were used to confirm the presence of SO{sup 2-}{sub 4} and MoO{sub 3} on the surface of glasses as well as other components which might form water soluble compounds with the excess sulfur and molybdenum. A simple, linear model was developed to show acceptable concentrations of SO{sub 4}{sup 2-} and MoO{sub 3} in an example waste glass composition. This model was constructed for scoping studies only and is not ready for implementation in support of actual waste vitrification. Several other factors must be considered in determining the limits of sulfate and molybdenum concentrations in the waste vitrification process, including but not limited to, impacts on refractory and melter component corrosion, effects on the melter off-gas system, and impacts on the chemical durability and crystallization of the glass product.

Fox, K.

2009-10-16T23:59:59.000Z

243

LOW-COST, HIGH-PERFORMANCE MATERIALS USING ILLINOIS COAL COMBUSTION BY-PRODUCTS  

E-Print Network [OSTI]

conventional and clean coal technologies. This project was primarily directed toward developing concrete, mineralogical, and microstructural properties. A clean coal ash is defined as the ash derived from SO2 control technologies. Based on these properties, two sources of both conventional and clean coal ashes were selected

Wisconsin-Milwaukee, University of

244

Highly Dispersed Pseudo-Homogeneous and Heterogeneous Catalysts Synthesized via Inverse Micelle Solutions for the Liquefaction of Coal  

SciTech Connect (OSTI)

The mission of this project was to use inverse micelle solutions to synthesize nanometer sized metal particles and test the particles as catalysts in the liquefaction of coal and other related reactions. The initial focus of the project was the synthesis of iron based materials in pseudo-homogeneous form. The frost three chapters discuss the synthesis, characterization, and catalyst testing in coal liquefaction and model coal liquefaction reactions of iron based pseudo-homogeneous materials. Later, we became interested in highly dispersed catalysts for coprocessing of coal and plastic waste. Bifunctional catalysts . to hydrogenate the coal and depolymerize the plastic waste are ideal. We began studying, based on our previously devised synthesis strategies, the synthesis of heterogeneous catalysts with a bifunctional nature. In chapter 4, we discuss the fundamental principles in heterogeneous catalysis synthesis with inverse micelle solutions. In chapter 5, we extend the synthesis of chapter 4 to practical systems and use the materials in catalyst testing. Finally in chapter 6, we return to iron and coal liquefaction now studied with the heterogeneous catalysts.

Hampden-Smith, M.; Kawola, J.S.; Martino, A.; Sault, A.G.; Yamanaka, S.A.

1999-01-05T23:59:59.000Z

245

Nature of petrographic variation in Taylor-Copland Coal of middle Pennsylvanian Breathitt Formation of eastern Kentucky  

SciTech Connect (OSTI)

The Taylor-Copland Coal is petrographically distinctive in that it has lowest average vitrinite content (63%) and concomitant highest inertinite (25%) and exinite (12%) of all eastern Kentucky coals. Additionally, average total sulfur is 3.4%, or nearly twice the 1.8% figure determined for all eastern Kentucky samples. Deviations from the maceral averages are equally distinctive. Particularly interesting is an areally extensive, though discontinuous, sample sequence showing significantly lower vitrinites (commonly 40%), very high inertinites (40%), and high exinite content (15-20%). The high-inertinite and high total-sulfur trends and variations for each were presumed to be related to proximity to the coal of marine lithologic units of the overlying Magoffin Member. However, it was found that maceral and possible sulfur trends are probably unrelated to roof rock variation, but are related to existence or absence of a thick durain coal lithotype toward the middle of some coal beds. Palynology reveals that spores in the durain-rich samples are poorly preserved (micrinitized), but assemblages and relative percentages of genera forming the assemblages remained unchanged from those found in high-vitrinite (durain-free) samples. Unchanged spore assemblages possibly indicate that unchanging plant communities existed through the durain-forming episode of the Taylor-Copland swamp. Rather, the effect of the durain phase on the Taylor-Copland swamp was to accelerate degradation (oxidation) of peat deposits associated with the surrounding plant community.

Trinkle, E.J.; Hower, J.C.; Tully, D.G.; Helfrich, C.T.

1984-12-01T23:59:59.000Z

246

Implications of heavy-ion-induced satellite x-ray emission. III. Chemical effects in high resolution sulfur K/sub. cap alpha. / x-ray spectra  

SciTech Connect (OSTI)

High resolution (approx. 7 eV at 2.3 keV) sulfur K/sub ..cap alpha../ x-ray spectra have been obtained for a series of sulfur compound targets under heavy ion impact at the Holified Heavy Ion Facility. The spectra observed are dominated by a series of satellite peaks arising from varying degrees of L-shell ionization at the time of x-ray emission. Each spectral profile has been parameterized by a single variable p/sub L/, the apparent average L-shell ionization probability. Correlations are evident between p/sub L/ and the corresponding sulfur atom chemical environment. Much stronger correlations are however found for variations of some individual peak intensities with specific chemical parameters. Comparison of results for Ar/sup q+/ and Kr/sup q+/ projectiles shows that while L-shell ionization probability has increased, chemical sensitivity has apparently saturated.

Vane, C.R.; Hulett, L.D. Jr.; Kahane, S.; McDaniel, F.D.; Milner, W.T.; Raman, S.; Rosseel, T.M.; Slaughter, G.G.; Varghese, S.L.; Young, J.P.

1983-01-01T23:59:59.000Z

247

Sensitivity of Fischer-Tropsch Synthesis and Water-Gas Shift Catalysts to Poisons from High-Temperature High-Pressure Entrained-Flow (EF) Oxygen-Blown Gasifier Gasification of Coal/Biomass Mixtures  

SciTech Connect (OSTI)

There has been a recent shift in interest in converting not only natural gas and coal derived syngas to Fischer-Tropsch synthesis products, but also converting biomass-derived syngas, as well as syngas derived from coal and biomass mixtures. As such, conventional catalysts based on iron and cobalt may not be suitable without proper development. This is because, while ash, sulfur compounds, traces of metals, halide compounds, and nitrogen-containing chemicals will likely be lower in concentration in syngas derived from mixtures of coal and biomass (i.e., using entrained-flow oxygen-blown gasifier gasification gasification) than solely from coal, other compounds may actually be increased. Of particular concern are compounds containing alkali chemicals like the chlorides of sodium and potassium. In the first year, University of Kentucky Center for Applied Energy Research (UK-CAER) researchers completed a number of tasks aimed at evaluating the sensitivity of cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts and a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to alkali halides. This included the preparation of large batches of 0.5%Pt-25%Co/Al{sub 2}O{sub 3} and 100Fe: 5.1Si: 3.0K: 2.0Cu (high alpha) catalysts that were split up among the four different entities participating in the overall project; the testing of the catalysts under clean FT and WGS conditions; the testing of the Fe-Cr WGS catalyst under conditions of co-feeding NaCl and KCl; and the construction and start-up of the continuously stirred tank reactors (CSTRs) for poisoning investigations. In the second and third years, researchers from the University of Kentucky Center for Applied Energy Research (UK-CAER) continued the project by evaluating the sensitivity of a commercial iron-chromia high temperature water-gas shift catalyst (WGS) to a number of different compounds, including KHCO{sub 3}, NaHCO{sub 3}, HCl, HBr, HF, H{sub 2}S, NH{sub 3}, and a combination of H{sub 2}S and NH{sub 3}. Cobalt and iron-based Fischer-Tropsch synthesis (FT) catalysts were also subjected to a number of the same compounds in order to evaluate their sensitivities at different concentration levels of added contaminant.

Burton Davis; Gary Jacobs; Wenping Ma; Dennis Sparks; Khalid Azzam; Janet Chakkamadathil Mohandas; Wilson Shafer; Venkat Ramana Rao Pendyala

2011-09-30T23:59:59.000Z

248

ADVANCED SULFUR CONTROL CONCEPTS FOR HOT-GAS DESULFURIZATION TECHNOLOGY  

SciTech Connect (OSTI)

This research project examined the feasibility of a second generation high-temperature coal gas desulfurization process in which elemental sulfur is produced directly during the sorbent regeneration phase. Two concepts were evaluated experimentally. In the first, FeS was regenerated in a H2O-O2 mixture. Large fractions of the sulfur were liberated in elemental form when the H2O-O2 ratio was large. However, the mole percent of elemental sulfur in the product was always quite small (<<1%) and a process based on this concept was judged to be impractical because of the low temperature and high energy requirements associated with condensing the sulfur. The second concept involved desulfurization using CeO2 and regeneration of the sulfided sorbent, Ce2O2S, using SO2 to produce elemental sulfur directly. No significant side reactions were observed and the reaction was found to be quite rapid over the temperature range of 500°C to 700°C. Elemental sulfur concentrations (as S2) as large as 20 mol% were produced. Limitations associated with the cerium sorbent process are concentrated in the desulfurization phase. High temperature and highly reducing coal gas such as produced in the Shell gasification process are required if high sulfur removal efficiencies are to be achieved. For example, the equilibrium H2S concentration at 800°C from a Shell gas in contact with CeO2 is about 300 ppmv, well above the allowable IGCC specification. In this case, a two-stage desulfurization process using CeO2 for bulk H2S removal following by a zinc sorbent polishing step would be required. Under appropriate conditions, however, CeO2 can be reduced to non-stoichiometric CeOn (n<2) which has significantly greater affinity for H2S. Pre-breakthrough H2S concentrations in the range of 1 ppmv to 5 ppmv were measured in sulfidation tests using CeOn at 700°C in highly reducing gases, as measured by equilibrium O2 concentration, comparable to the Shell gas. Good sorbent durability was indicated in a twenty-five-cycle test. The sorbent was exposed for 58 consecutive days to temperatures between 600°C and 800°C and gas atmospheres from highly reducing to highly oxidizing without measurable loss of sulfur capacity or reactivity. In the process analysis phase of this study, a two-stage desulfurization process using cerium sorbent with SO2 regeneration followed by zinc sorbent with dilute O2 regeneration was compared to a single-stage process using zinc sorbent and O2 regeneration with SO2 in the regeneration product gas converted to elemental sulfur using the direct sulfur recovery process (DSRP). Material and energy balances were calculated using the process simulation package PRO/II. Major process equipment was sized and a preliminary economic analysis completed. Sorbent replacement rate, which is determined by the multicycle sorbent durability, was found to be the most significant factor in both processes. For large replacement rates corresponding to average sorbent lifetimes of 250 cycles or less, the single-stage zinc sorbent process with DSRP was estimated to be less costly. However, the cost of the two-stage cerium sorbent process was more sensitive to sorbent replacement rate, and, as the required replacement rate decreased, the economics of the two-stage process improved. For small sorbent replacement rates corresponding to average sorbent lifetimes of 1000 cycles or more, the two-stage cerium process was estimated to be less costly. In the relatively wide middle range of sorbent replacement rates, the relative economics of the two processes depends on other factors such as the unit cost of sorbents, oxygen, nitrogen, and the relative capital costs.

A. LOPEZ ORTIZ; D.P. HARRISON; F.R. GROVES; J.D. WHITE; S. ZHANG; W.-N. HUANG; Y. ZENG

1998-10-31T23:59:59.000Z

249

High conversion of coal to transportation fuels for the future with low HC gas production. Progress report, October 1, 1995--December 31, 1995  

SciTech Connect (OSTI)

Experimental coal liquefaction studies conducted in a batch microreactor in our laboratory have demonstrated potential for high conversions of coal to liquids with low yields of hydrocarbon (HC) gases, hence a small consumption of hydrogen in the primary liquefaction step. Ratios of liquids/HC gases as high as 30/1, at liquid yields as high as 82% of the coal by weight, have been achieved. The principal objective of this work is to examine how nearly we may approach these results in a continuous-flow system, at a size sufficient to evaluate the process concept for production of transportation fuels from coal.

Wiser, W.H.; Oblad, A.G.

1996-01-01T23:59:59.000Z

250

Engineering development of coal-fired high performance power systems, Phase II and III  

SciTech Connect (OSTI)

The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) that is capable of: thermal efficiency (HHV) {ge} 47%; NOx, SOx, and particulates {le} 10% NSPS (New Source Performance Standard) coal providing {ge} 65% of heat input; all solid wastes benign; cost of electricity {le} 90% of present plants. Phase 1, which began in 1992, focused on the analysis of various configurations of indirectly fired cycles and on technical assessments of alternative plant subsystems and components, including performance requirements, developmental status, design options, complexity and reliability, and capital and operating costs. Phase 1 also included preliminary R and D and the preparation of designs for HIPPS commercial plants approximately 300 MWe in size. This phase, Phase 2, involves the development and testing of plant subsystems, refinement and updating of the HIPPS commercial plant design, and the site selection and engineering design of a HIPPS prototype plant. Work reported herein is from: Task 2.1 HITAC Combustors; Task 2.2 HITAF Air Heaters; Task 6 HIPPS Commercial Plant Design Update.

None

1999-01-01T23:59:59.000Z

251

Engineering development of coal-fired high performance power systems phase 2 and 3  

SciTech Connect (OSTI)

The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) that is capable of: thermal efficiency (HHV) {ge} 47%; NOx, SOx, and particulates {le}10% NSPS (New Source Performance Standard); coal providing {ge} 65% of heat input; all solid wastes benign; and cost of electricity {le} 90% of present plants. Phase 1, which began in 1992, focused on the analysis of various configurations of indirectly fired cycles and on technical assessments of alternative plant subsystems and components, including performance requirements, developmental status, design options, complexity and reliability, and capital and operating costs. Phase 1 also included preliminary R and D and the preparation of designs for HIPPS commercial plants approximately 300 MWe in size. This phase, Phase 2, involves the development and testing of plant subsystems, refinement and updating of the HIPPS commercial plant design, and the site selection and engineering design of a HIPPS prototype plant. Work reported herein is from: Task 2.2 HITAF Air Heaters; and Task 2.4 Duct Heater and Gas Turbine Integration.

Unknown

1999-08-01T23:59:59.000Z

252

Coal Gasification Systems Solicitations  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Low Cost Coal Conversion to High Hydrogen Syngas; FE0023577 Alstom's Limestone Chemical Looping Gasification Process for High Hydrogen Syngas Generation; FE0023497 OTM-Enhanced...

253

Operational results for high pulverized coal injection rate at Kimitsu No. 3 blast furnace  

SciTech Connect (OSTI)

In order to further develop the technology for high-rate pulverized coal injection (PCI), namely over 200 kg/t-pig, Nippon Steel performed a high injection rate test at the Kimitsu No. 3 blast furnace in November, 1993. The paper describes PCI equipment; the operational design of the test, including blast conditions, reducibility of sinter, coke strength and burden distribution; and test results. These results include a discussion of the transition of operation, burden distribution control, replacement ratio of coke, permeability at upper and lower parts of the furnace, reducibility at lower part of the furnace, accumulation of fines in the deadman, and generation and accumulation of unburnt char. Stable operation was achieved at a PCI rate of 190 kg/t-pig. With injection rates between 200--300 kg/t-pig, the problem becomes how to improve the reduction-meltdown behavior in the lower part of the furnace.

Ueno, Hiromitsu; Matsunaga, Shin`ichi; Kakuichi, Kazumoto; Amano, Shigeru; Yamaguchi, Kazuyoshi

1995-12-01T23:59:59.000Z

254

Molten iron oxysulfide as a superior sulfur sorbent. Final report, [September 1989--1993  

SciTech Connect (OSTI)

The studies had as original objective the analysis of conditions for using liquid iron oxysulfide as a desulfuring agent during coal gasification. Ancillary was a comparison of iron oxysulfide with lime as sorbents under conditions where lime reacts with S-bearing gases to form Ca sulfate or sulfide. Primary thrust is to determine the thermodynamic requirements for desulfurization by iron additions (e.g., taconite concentrate) during combustion in gasifiers operating at high equivalence ratios. Thermodynamic analysis of lime-oxygen-sulfur system shows why lime is injected into burners under oxidizing conditions; reducing conditions forms CaS, requiring its removal, otherwise oxidation and release of S would occur. Iron as the oxysulfide liquid has a range of stability and can be used as a desulfurizing agent, if the burner/gasifier operates in a sufficiently reducing regime (high equivalence ratio); this operating range is given and is calculable for a coal composition, temperature, stoichiometry. High moisture or hydrogen contents of the coal yield a poorer degree of desulfurization. Kinetic tests on individual iron oxide particles on substrates or Pt cups with a TGA apparatus fail to predict reaction rates within a burner. Preliminary tests on the Dynamic Containment Burner with acetylene give some promise that this system can produce the proper conditions of coal gasification for use of added iron as a sulfur sorbent.

Hepworth, M.T.

1993-03-31T23:59:59.000Z

255

Novel bimetallic dispersed catalysts for temperature-programmed coal liquefaction. Final report  

SciTech Connect (OSTI)

Development of new catalysts is a promising approach to more efficient coal liquefaction. It has been recognized that dispersed catalysts are superior to supported catalysts for primary liquefaction of coals, because the control of initial coal dissolution or depolymerization requires intimate contact between the catalyst and coal. This research is a fundamental and exploratory study on catalytic coal liquefaction, with the emphasis on exploring novel bimetallic dispersed catalysts for coal liquefaction and the effectiveness of temperature-programmed liquefaction using dispersed catalysts. The primary objective of this research was to explore novel bimetallic dispersed catalysts from organometallic molecular precursors, that could be used in low concentrations but exhibit relatively high activity for efficient hydroliquefaction of coals under temperature-programmed conditions. We have synthesized and tested various catalyst precursors in liquefaction of subbituminous and bituminous coals and in model compound studies to examine how do the composition and structure of the catalytic precursors affect their effectiveness for coal liquefaction under different reaction conditions, and how do these factors affect their catalytic functions for hydrogenation of polyaromatic hydrocarbons, for cleavage of C-C bonds in polycyclic systems such as 4-(1-naphthylmethyl)bibenzyl, for hydrogenolysis of C-O bond such as that in dinaphthylether, for hydrodeoxygenation of phenolic compounds and other oxygen-containing compounds such as xanthene, and for hydrodesulfurization of polycyclic sulfur compounds such as dibenzothiophene. The novel bimetallic and monometallic precursors synthesized and tested in this project include various Mo- and Fe-based compounds.

Chunshan Song; Schobert, H.H.; Parfitt, D.P. [and others

1997-11-01T23:59:59.000Z

256

Energy and environmental research emphasizing low-rank coal -- Task 5.1, Stability issues  

SciTech Connect (OSTI)

Low-sulfur subbituminous and lignite coals have high moisture content and, consequently, low heating value, leading to boiler derating in US midwestern and eastern utilities as well as switching and/or blending coals to achieve SO{sub 2} compliance. In the drive to develop cost-effective coal-drying processes, coal developers have focused on heat content of the products and generally neglected the critical stability issues of friability and dusting, moisture reabsorption, and spontaneous heating. The Energy and Environmental Research Center (EERC), in an effort to establish new standards for dried products, has used established methods and has developed new ones to evaluate the propensity of lump western coals, raw and dried, to produce dust and absorb water. Three drying methods--air, hydrothermal, and saturated steam--were used to generate low-moisture upgraded products. New indices for dust generation and friability were determined to assess the effects of moisture removal and upgrading methodology on coal stability. Analysis of the dried coals using various strength tests indicated that the reduction in moisture made the lump coal unstable, yielding substantially higher dust and friability indices relative to those of the raw coals.

Anderson, C.M.; Musich, M.A.; Dewall, R.A.; Richter, J.J.

1995-04-01T23:59:59.000Z

257

Coal combustion under conditions of blast furnace injection; [Quarterly] technical report, September 1--November 30, 1993  

SciTech Connect (OSTI)

A potentially new use for Illinois coal is its use as a fuel injected into a blast furnace to produce molten iron as the first step in steel production. Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of coal during the blast furnace injection process and to delineate the optimum properties of the feed coal. This investigation is significant to the use of Illinois coal in that the limited research to date suggests that coals of low fluidity and moderate to high sulfur and chlorine contents are suitable feedstocks for blast furnace injection. This study is unique in that it will be the first North American effort to directly determine the nature of the combustion of coal injected into a blast furnace. This proposal is a follow-up to one funded for the 1992--1993 period. It is intended to complete the study already underway with the Armco Inc. steel company and to initiate a new cooperative study along somewhat similar lines with the Inland Steel Company. The results of this study will lead to the development of a testing and evaluation protocol that will give a unique and much needed understanding of the behavior of coal in the injection process and prove the potential of Illinois coals f or such use.

Crelling, J.C.

1993-12-31T23:59:59.000Z

258

Two stage sorption of sulfur compounds  

DOE Patents [OSTI]

A two stage method for reducing the sulfur content of exhaust gases is disclosed. Alkali- or alkaline-earth-based sorbent is totally or partially vaporized and introduced into a sulfur-containing gas stream. The activated sorbent can be introduced in the reaction zone or the exhaust gases of a combustor or a gasifier. High efficiencies of sulfur removal can be achieved.

Moore, William E. (Manassas, VA)

1992-01-01T23:59:59.000Z

259

Alaska coal gasification feasibility studies - Healy coal-to-liquids plant  

SciTech Connect (OSTI)

The Alaska Coal Gasification Feasibility Study entailed a two-phase analysis of the prospects for greater use of Alaska's abundant coal resources in industrial applications. Phase 1, Beluga Coal Gasification Feasibility Study (Report DOE/NETL 2006/1248) assessed the feasibility of using gasification technology to convert the Agrium fertilizer plant in Nikiski, Alaska, from natural gas to coal feedstock. The Phase 1 analysis evaluated coals from the Beluga field near Anchorage and from the Usibelli Coal Mine near Healy, both of which are low in sulfur and high in moisture. This study expands the results of Phase 1 by evaluating a similar sized gasification facility at the Usibelli Coal mine to supply Fischer-Tropsch (F-T) liquids to central Alaska. The plant considered in this study is small (14,640 barrels per day, bbl/d) compared to the recommended commercial size of 50,000 bbl/d for coal-to-liquid plants. The coal supply requirements for the Phase 1 analysis, four million tons per year, were assumed for the Phase 2 analysis to match the probable capacity of the Usibelli mining operations. Alaska refineries are of sufficient size to use all of the product, eliminating the need for F-T exports out of the state. The plant could produce marketable by-products such as sulfur as well as electric power. Slag would be used as backfill at the mine site and CO{sub 2} could be vented, captured or used for enhanced coalbed methane recovery. The unexpected curtailment of oil production from Prudhoe Bay in August 2006 highlighted the dependency of Alaskan refineries (with the exception of the Tesoro facility in Nikiski) on Alaska North Slope (ANS) crude. If the flow of oil from the North Slope declines, these refineries may not be able to meet the in-state needs for diesel, gasoline, and jet fuel. Additional reliable sources of essential fuel products would be beneficial. 36 refs., 14 figs., 29 tabs., 3 apps.

Lawrence Van Bibber; Charles Thomas; Robert Chaney [Research & Development Solutions, LLC (United States)

2007-07-15T23:59:59.000Z

260

Applications of micellar enzymology to clean coal technology. Tenth quarterly report  

SciTech Connect (OSTI)

Full implementation of coal fuel sources will require more effective methods of providing ``clean coal`` as a fuel source. Methods must be developed to reduce the sulfur content of coal which significantly contributes to environmental pollution. This project is designed to develop methods for pre-combustion coal remediation by implementing recent advances in enzyme biochemistry. The novel approach of this study is incorporation of hydrophilic oxidative enzymes in reverse micelles in an organic solvent. Enzymes from commercial sources or microbial extracts are being investigated for their capacity to remove organic sulfur from coal by oxidation of the sulfur groups, splitting of C-S bonds and loss of sulfur as sulfuric acid. Dibenzothiophene (DBT) and ethylphenylsulfide (EPS) are serving as models of organic sulfur-containing components of coal in initial studies.

Walsh, C.T.

1992-04-29T23:59:59.000Z

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261

Method for desulfurization of coal  

DOE Patents [OSTI]

A process and apparatus for desulfurizing coal which removes sulfur in the inorganic and organic form by preferentially heating the inorganic iron sulfides in coal in a flowing gas to convert some of the inorganic iron sulfides from a pyrite form FeS.sub.2 to a troilite FeS form or a pyrrhotite form Fe.sub.1-x S and release some of the sulfur as a gaseous compound. The troilite and pyrrhotite forms are convenient catalyst for removing the organic sulfur in the next step, which is to react the coal with chemical agents such as alcohol, thus removing the organic sulfur as a liquid or a gas such as H.sub.2 S. The remaining inorganic sulfur is left in the predominantly higher magnetic form of pyrrhotite and is then removed by magnetic separation techniques. Optionally, an organic flocculant may be added after the organic sulfur has been removed and before magnetic separation. The flocculant attaches non-pyrite minerals with the pyrrhotite for removal by magnetic separation to reduce the ash-forming contents.

Kelland, David R. (Lexington, MA)

1987-01-01T23:59:59.000Z

262

Method for desulfurization of coal  

DOE Patents [OSTI]

A process and apparatus are disclosed for desulfurizing coal which removes sulfur in the inorganic and organic form by preferentially heating the inorganic iron sulfides in coal in a flowing gas to convert some of the inorganic iron sulfides from a pyrite form FeS[sub 2] to a troilite FeS form or a pyrrhotite form Fe[sub 1[minus]x]S and release some of the sulfur as a gaseous compound. The troilite and pyrrhotite forms are convenient catalyst for removing the organic sulfur in the next step, which is to react the coal with chemical agents such as alcohol, thus removing the organic sulfur as a liquid or a gas such as H[sub 2]S. The remaining inorganic sulfur is left in the predominantly higher magnetic form of pyrrhotite and is then removed by magnetic separation techniques. Optionally, an organic flocculant may be added after the organic sulfur has been removed and before magnetic separation. The flocculant attaches non-pyrite minerals with the pyrrhotite for removal by magnetic separation to reduce the ash-forming contents. 2 figs.

Kelland, D.R.

1987-07-07T23:59:59.000Z

263

Assessment of advanced coal-gasification processes. [AVCO high throughput gasification in process; Bell High Mass Flux process; CS-R process; and Exxon Gasification process  

SciTech Connect (OSTI)

This report represents a technical assessment of the following advanced coal gasification processes: AVCO High Throughput Gasification (HTG) Process, Bell Single - Stage High Mass Flux (HMF) Process, Cities Service/Rockwell (CS/R) Hydrogasification Process, and the Exxon Catalytic Coal Gasification (CCG) Process. Each process is evaluated for its potential to produce SNG from a bituminous coal. In addition to identifying the new technology these processes represent, key similarities/differences, strengths/weaknesses, and potential improvements to each process are identified. The AVCO HTG and the Bell HMF gasifiers share similarities with respect to: short residence time (SRT), high throughput rate, slagging and syngas as the initial raw product gas. The CS/R Hydrogasifier is also SRT but is non-slagging and produces a raw gas high in methane content. The Exxon CCG gasifier is a long residence time, catalytic fluidbed reactor producing all of the raw product methane in the gasifier.

McCarthy, J.; Ferrall, J.; Charng, T.; Houseman, J.

1981-06-01T23:59:59.000Z

264

Selective catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly technical progress report No. 6, October 1993--December 1993  

SciTech Connect (OSTI)

Elemental sulfur recovery from SO{sub 2}-containing gas stream is highly attractive as it produces a salable product and no waste to dispose of. However, commercially available schemes are complex and involve multi-stage reactors, such as, most notably in the Resox (reduction of SO{sub 2} with coke) and Claus plant (reaction of SO{sub 2} with H{sub 2}S over catalyst). This project will investigate a cerium oxide catalyst for the single stage selective reduction of SO{sub 2} to elemental sulfur by a reductant, such as carbon monoxide. Cerium oxide has been identified in recent work at MIT as a superior catalyst for SO{sub 2} reduction by CO to elemental sulfur because its high activity and high selectivity to sulfur over COS over a wide temperature range(400-650 {degrees}C). The detailed kinetic and parametric studies of SO{sub 2} reduction planned in this work over various CeO{sub 2}-formulations will provide the necessary basis for development of a very simplified process, namely that of a single-stage elemental sulfur recovery scheme from variable concentration gas streams. The potential cost- and energy-efficiency benefits from this approach can not be overstated. A first apparent application is treatment of a regenerator off-gases in power plants using regenerative flue gas desulfurization. Such a simple catalytic converter may offer the long-sought {open_quotes}Claus-alternative{close_quotes} for coal-fired power plant applications.

Liu, W.; Flytzani-Stephanopoulos, M.; Sarofim, A.F.

1996-01-01T23:59:59.000Z

265

High ash non-coking coal preparation by tribo-electrostatic dry process.  

E-Print Network [OSTI]

??Coal is the single largest fossil fuel used world-wide and accounts for more than 60% of the total commercial energy consumed. Between 60 to 80%… (more)

Ranjan Dwari

2008-01-01T23:59:59.000Z

266

Effects of hydrogen donor additives on the coking properties of high-temperature coal extracts.  

E-Print Network [OSTI]

?? Refcoal is a carbon precursor obtained by alkali-mediated extraction of coal with aprotic solvents such as DMF. Refcoal can be converted into a graphitic… (more)

Makgato, Matlou Hector

2009-01-01T23:59:59.000Z

267

Hydrogen production by high-temperature steam gasification of biomass and coal  

SciTech Connect (OSTI)

High-temperature steam gasification of paper, yellow pine woodchips, and Pittsburgh bituminous coal was investigated in a batch-type flow reactor at temperatures in the range of 700 to 1,200{sup o}C at two different ratios of steam to feedstock molar ratios. Hydrogen yield of 54.7% for paper, 60.2% for woodchips, and 57.8% for coal was achieved on a dry basis, with a steam flow rate of 6.3 g/min at steam temperature of 1,200{sup o}C. Yield of both the hydrogen and carbon monoxide increased while carbon dioxide and methane decreased with the increase in gasification temperature. A 10-fold reduction in tar residue was obtained at high-temperature steam gasification, compared to low temperatures. Steam and gasification temperature affects the composition of the syngas produced. Higher steam-to-feedstock molar ratio had negligible effect on the amount of hydrogen produced in the syngas in the fixed-batch type of reactor. Gasification temperature can be used to control the amounts of hydrogen or methane produced from the gasification process. This also provides mean to control the ratio of hydrogen to CO in the syngas, which can then be processed to produce liquid hydrocarbon fuel since the liquid fuel production requires an optimum ratio between hydrogen and CO. The syngas produced can be further processed to produce pure hydrogen. Biomass fuels are good source of renewable fuels to produce hydrogen or liquid fuels using controlled steam gasification.

Kriengsak, S.N.; Buczynski, R.; Gmurczyk, J.; Gupta, A.K. [University of Maryland, College Park, MD (United States). Dept. of Mechanical Engineering

2009-04-15T23:59:59.000Z

268

Engineering Development of Coal-Fired High-Performance Power Systems  

SciTech Connect (OSTI)

A High Performance Power System (HIPPS) is being developed. This system is a coal-fired, combined cycle plant with indirect heating of gas turbine air. Foster Wheeler Development Corporation and a team consisting of Foster Wheeler Energy Corporation, Bechtel Corporation, University of Tennessee Space Institute and Westinghouse Electric Corporation are developing this system. In Phase 1 of the project, a conceptual design of a commercial plant was developed. Technical and economic analyses indicated that the plant would meet the goals of the project which include a 47 percent efficiency (HHV) and a 10 percent lower cost of electricity than an equivalent size PC plant. The concept uses a pyrolysis process to convert coal into fuel gas and char. The char is fired in a High Temperature Advanced Furnace (HITAF). The HITAF is a pulverized fuel-fired boiler/air heater where steam is generated and gas turbine air is indirectly heated. The fuel gas generated in the pyrolyzer is then used to heat the gas turbine air further before it enters the gas turbine. The project is currently in Phase 2 which includes engineering analysis, laboratory testing and pilot plant testing. Research and development is being done on the HIPPS systems that are not commercial or being developed on other projects. Pilot plant testing of the pyrolyzer subsystem and the char combustion subsystem are being done separately. This report addresses the areas of technical progress for this quarter. The detail of syngas cooler design is given in this report. The final construction work of the CFB pyrolyzer pilot plant has started during this quarter. No experimental testing was performed during this quarter. The proposed test matrix for the future CFB pyrolyzer tests is given in this report. Besides testing various fuels, bed temperature will be the primary test parameter.

York Tsuo

2000-12-31T23:59:59.000Z

269

Coal-fueled high-speed diesel engine development. Annual technical progress report, October 1990--September 1991  

SciTech Connect (OSTI)

The objectives of this program are to study combustion feasibility by running Series 149 engine tests at high speeds with a fuel injection and combustion system designed for coal-water-slurry (CWS). The following criteria will be used to judge feasibility: (1) engine operation for sustained periods over the load range at speeds from 600 to 1900 rpm. The 149 engine for mine-haul trucks has a rated speed of 1900 rpm; (2) reasonable fuel economy and coal burnout rate; (3) reasonable cost of the engine design concept and CWS fuel compared to future oil prices.

Not Available

1991-11-01T23:59:59.000Z

270

Low-rank coal oil agglomeration  

DOE Patents [OSTI]

A low-rank coal oil agglomeration process. High mineral content, a high ash content subbituminous coals are effectively agglomerated with a bridging oil which is partially water soluble and capable of entering the pore structure, and usually coal derived.

Knudson, Curtis L. (Grand Forks, ND); Timpe, Ronald C. (Grand Forks, ND)

1991-01-01T23:59:59.000Z

271

Advanced Coal Conversion Process Demonstration Project. Technical progress report, January 1, 1995--March 31, 1995  

SciTech Connect (OSTI)

This detailed report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project. This U.S. Department of Energy (DOE) Clean Coal Technology Project demonstrates an advanced thermal coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to high-quality, low-sulfur fuel. During this reporting period, the primary focus for the project was to expand market awareness and acceptability for the products and the technology. The use of covered hopper cars has been successful and marketing efforts have focused on this technique. Operational improvements are currently aimed at developing fines marketing systems, increasing throughput capacity, decreasing operation costs, and developing standardized continuous operator training. Testburns at industrial user sites were also conducted. A detailed process description; technical progress report including facility operations/plant production, facility testing, product testing, and testburn product; and process stability report are included. 3 figs., 8 tabs.

NONE

1996-06-01T23:59:59.000Z

272

Studies of the mechanism of Coal Hydrogenation by Electron Spin Resonance. Quarterly technical progress report, March 1-May 31, 1980. [For high-temperature, high pressure measurements  

SciTech Connect (OSTI)

This is the first quarterly report on the program Studies of Coal Hydrogenation by Electron Spin Resonance. This quarter has been devoted to constructing apparatus for high temperature-high pressure electron paramagnetic resonance (EPR) measurements, characterizing the performance of the microwave cavity, and carrying out preliminary room temperature studies on coals and coal products. At the start of this program, there were no microwave cavities available to study high pressure-high temperature reactions. A system was constructed which can be used to study coal hydrogenation, and satisfies the conditions described in the report. This cavity was constructed using funding from Rockwell International, and will be used on this program. Because of the dependence of the work to be done with this device for this program, the construction is described in detail. This report, therefore, considers the design philosophy, construction of the device, a preliminary discussion of its performance, and application of the cavity for room temperature studies on several varieties of coal.

Goldberg, Ira B.

1980-07-01T23:59:59.000Z

273

Neutron based elemental characterization of coal  

SciTech Connect (OSTI)

An elemental characterization system based on a 14 MeV neutron generator is described. The results of sulfur content measurement in coal with a precision acceptable to the coal industry are presented. The preliminary results of measuring carbon, oxygen, and sodium are shown.

Dep, L.; Vourvopoulos, G. [Western Kentucky Univ., Bowling Green, KY (United States)

1996-12-31T23:59:59.000Z

274

The magnetohydrodynamics Coal-Fired Flow Facility  

SciTech Connect (OSTI)

In this Quarterly Technical Progress Report, UTSI reports on a continuing proof-of-concept (POC) test program for the steam bottoming plant of an MHD/steam combined cycle power plant. In this report, the first POC test on western, low sulfur coal is reported. Analyses of tube materials from the previously completed 2004 hour POC tests on eastern, high sulfur coal are also included. The first test results with the wet electrostatic precipitator (ESP), which was installed to replace the wet venturi scrubber are reported. Detailed results of testing ceramic tubes and test components under a variety of high temperature conditions, for application to a high temperature air heater are included. Progress in application of advanced diagnostics equipment by both UTSI and Mississippi State University (MSU) is summarized. In addition, the laboratory effort to measure the transmissivity and absorption coefficient of the gas in the temperature range of condensing slag and potassium compounds is described. The current status of the CFFF environmental program is summarized.

Not Available

1993-02-01T23:59:59.000Z

275

Advanced byproduct recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Quarterly report, April 1--June 30, 1997  

SciTech Connect (OSTI)

The team of Arthur D. Little, Tufts University and Engelhard Corporation are conducting Phase 1 of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an on-going DOE-sponsored, University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicate that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. The performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams. The principal objective of the Phase 1 program is to identify and evaluate the performance of a catalyst which is robust and flexible with regard to choice of reducing gas. In order to achieve this goal, the authors have planned a structured program including: Market/process/cost/evaluation; Lab-scale catalyst preparation/optimization studies; Lab-scale, bulk/supported catalyst kinetic studies; Bench-scale catalyst/process studies; and Utility review. Progress is reported from all three organizations.

NONE

1997-12-31T23:59:59.000Z

276

Coal based electric generation comparative technologies report  

SciTech Connect (OSTI)

Ohio Clean Fuels, Inc., (OCF) has licensed technology that involves Co-Processing (Co-Pro) poor grade (high sulfur) coal and residual oil feedstocks to produce clean liquid fuels on a commercial scale. Stone Webster is requested to perform a comparative technologies report for grassroot plants utilizing coal as a base fuel. In the case of Co-Processing technology the plant considered is the nth plant in a series of applications. This report presents the results of an economic comparison of this technology with other power generation technologies that use coal. Technologies evaluated were:Co-Processing integrated with simple cycle combustion turbine generators, (CSC); Co-Processing integrated with combined cycle combustion turbine generators, (CCC); pulverized coal-fired boiler with flue gas desulfurization and steam turbine generator, (PC) and Circulating fluidized bed boiler and steam turbine generator, (CFB). Conceptual designs were developed. Designs were based on approximately equivalent net electrical output for each technology. A base case of 310 MWe net for each technology was established. Sensitivity analyses at other net electrical output sizes varying from 220 MWe's to 1770 MWe's were also performed. 4 figs., 9 tabs.

Not Available

1989-10-26T23:59:59.000Z

277

High opacity white plumes from coal-fired and oil-fired sources  

SciTech Connect (OSTI)

In recent years, with the installation of high efficiency particulate emission control devices on utility and industrial boilers, high-opacity white plumes have become more of a problem because formerly the emissions of primary particulate matter obscured and/or served as a condensing surface for the condensable material. The problem common to some of these installations is the violation of opacity standards due to the presence of a high-opacity persistent plume that emits from the stack. Oil fired boilers violating opacity standards typically comply with mass emission standards while coal fired boilers typically violate visual emission standards when simultaneously violating mass emission standards. The investigation reported here focuses on the atypical case when in-situ transmissometer measurements show compliance but plume opacity as measured by Reference Method 9 or LIDAR exceeds opacity standards. This case comes about due to gas phase reactions that produce fine aerosols, vapor phase condensation and physical agglomeration of sub-micron sized clusters and particles. The plume opacity control technology applicable to these aerosols which are created and/or grown in white plume is discussed in this paper.

Lee, K.T. (National Cheng Kung Univ. (TW))

1988-01-01T23:59:59.000Z

278

Process for measuring degradation of sulfur hexafluoride in high voltage systems  

DOE Patents [OSTI]

This invention is a method of detecting the presence of toxic and corrosive by-products in high voltage systems produced by electrically induced degradation of SF/sub 6/ insulating gas in the presence of certain impurities. It is an improvement over previous methods because it is extremely sensitive, detecting by-products present in parts per billion concentrations, and because the device employed is of a simple design and takes advantage of the by-products natural affinity for fluoride ions. The method employs an ion-molecule reaction cell in which negative ions of the by-products are produced by fluorine attachment. These ions are admitted to a negative ion mass spectrometer and identified by their spectra. This spectrometry technique is an improvement over conventional techniques because the negative ion peaks are strong and not obscured by a major ion spectra of the SF/sub 6/ component as is the case in positive ion mass spectrometry.

Sauers, I.

1985-04-23T23:59:59.000Z

279

Coal in the Northern Rocky Mountains and Great Plains Region -- Clean, compliant, and available  

SciTech Connect (OSTI)

The Northern Rocky Mountains and Great Plains region produced over 340 million short tons of coal in 1997, approximately 30 percent of the nation`s total coal production. Coals from this region are shipped to 26 states in the western, midwest, southern, and eastern US and production is projected to increase to 415 million short tons by 2015; the projected increase will be utilized primarily for production of electric power. The coals are economically attractive because they can be produced by surface mining, and do not require costly beneficiation to be compliant with emission standards. The coals are compliant because their chemical composition was influenced by tectonic settings of the coal basins and provenance of the sediments entering the basins. Tectonics during the Paleocene also influenced rates of precipitation and depositional systems. These factors, in concert, controlled the amount, distribution, and levels of sulfur, ash, and trace elements of environmental concern in the region`s coals. The emphasis of this paper is on the chemistry of these thick, high-quality coals and the geologic controls that resulted in their accumulation.

Stricker, G.D.; Ellis, M.S.; Flores, R.M.; Bader, L.R. [Geological Survey, Denver, CO (United States)

1998-12-31T23:59:59.000Z

280

Coal: the new black  

SciTech Connect (OSTI)

Long eclipsed by oil and natural gas as a raw material for high-volume chemicals, coal is making a comeback, with oil priced at more than $100 per barrel. It is relatively cheap feedstock for chemicals such as methanol and China is building plants to convert coal to polyolefins on a large scale and interest is spreading worldwide. Over the years several companies in the US and China have made fertilizers via the gasification of coal. Eastman in Tennessee gasifies coal to make methanol which is then converted to acetic acid, acetic anhydride and acetate fiber. The future vision is to convert methanol to olefins. UOP and Lurgi are the major vendors of this technology. These companies are the respective chemical engineering arms of Honeywell and Air Liquide. The article reports developments in China, USA and India on coal-to-chemicals via coal gasification or coal liquefaction. 2 figs., 2 photo.

Tullo, A.H.; Tremblay, J.-F.

2008-03-15T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Investigate the effectivness of calcium-treated coals in the capture of sulfur gases generated in staged fired combustors. Third quarterly technical progress report, May 1-July 31, 1983  

SciTech Connect (OSTI)

In this quarter's work, a new procedure was developed to add calcium to pulverized coal. The method has been found to increase the calcium content of bituminous coal to 12% calcium by weight, which corresponds to a Ca/S ratio of greater than 2. Progress was also made on the combustion test facility this quarter. A new modification of the low-flow coal feeder has made that system steady and reliable. With the furnace wired and plumbed, and the other subsystems complete, the facility is almost ready to burn the treated coals.

Porter, J. H.; Manning, M. P.; Benedek, K. R.; Sharma, P. K.

1983-09-01T23:59:59.000Z

282

Coal-fired high performance power generating system. Quarterly progress report, July 1, 1993--September 30, 1993  

SciTech Connect (OSTI)

This report covers work carried out under Task 3, Preliminary Research and Development, and Task 4, Commercial Generating Plant Design, under contract DE-AC22-92PC91155, {open_quotes}Engineering Development of a Coal Fired High Performance Power Generation System{close_quotes} between DOE Pittsburgh Energy Technology Center and United Technologies Research Center. The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) by the year 2000 that is capable of >47% thermal efficiency; NO{sub x}, SO{sub x}, and particulates {le} 25% NSPS; cost {ge} 65% of heat input; and all solid wastes benign. The report discusses progress in cycle analysis, chemical reactor modeling, ash deposition rate calculations for HITAF (high temperature advanced furnace) convective air heater, air heater materials, and deposit initiation and growth on ceramic substrates.

Not Available

1993-12-31T23:59:59.000Z

283

Coal-fired high performance power generating system. Draft quarterly progress report, January 1--March 31, 1995  

SciTech Connect (OSTI)

This report covers work carried out under Task 3, Preliminary R and D, under contract DE-AC22-92PC91155, ``Engineering Development of a Coal-Fired High Performance Power Generation System`` between DOE Pittsburgh Energy Technology Center and United Technologies Research Center. The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) by the year 2000 that is capable of >47% thermal efficiency; NO{sub x}, SO{sub x} and particulates {le} 25% NSPS; cost {ge}65% of heat input; all solid wastes benign. A crucial aspect of the authors design is the integration of the gas turbine requirements with the HITAF output and steam cycle requirements. In order to take full advantage of modern highly efficient aeroderivative gas turbines they have carried out a large number of cycle calculations to optimize their commercial plant designs for both greenfield and repowering applications.

NONE

1995-10-01T23:59:59.000Z

284

Healy Clean Coal Project  

SciTech Connect (OSTI)

The Healy Clean Coal Project, selected by the U.S. Department of Energy under Round 111 of the Clean Coal Technology Program, has been constructed and is currently in the Phase 111 Demonstration Testing. The project is owned and financed by the Alaska Industrial Development and Export Authority (AIDEA), and is cofunded by the U.S. Department of Energy. Construction was 100% completed in mid-November of 1997, with coal firing trials starting in early 1998. Demonstration testing and reporting of the results will take place in 1998, followed by commercial operation of the facility. The emission levels of nitrogen oxides (NOx), sulfur dioxide (S02), and particulate from this 50-megawatt plant are expected to be significantly lower than current standards.

None

1997-12-31T23:59:59.000Z

285

SULFUR POLYMER ENCAPSULATION.  

SciTech Connect (OSTI)

Sulfur polymer cement (SPC) is a thermoplastic polymer consisting of 95 wt% elemental sulfur and 5 wt% organic modifiers to enhance long-term durability. SPC was originally developed by the U.S. Bureau of Mines as an alternative to hydraulic cement for construction applications. Previous attempts to use elemental sulfur as a construction material in the chemical industry failed due to premature degradation. These failures were caused by the internal stresses that result from changes in crystalline structure upon cooling of the material. By reacting elemental sulfur with organic polymers, the Bureau of Mines developed a product that successfully suppresses the solid phase transition and significantly improves the stability of the product. SPC, originally named modified sulfur cement, is produced from readily available, inexpensive waste sulfur derived from desulfurization of both flue gases and petroleum. The commercial production of SPC is licensed in the United States by Martin Resources (Odessa, Texas) and is marketed under the trade name Chement 2000. It is sold in granular form and is relatively inexpensive ({approx}$0.10 to 0.12/lb). Application of SPC for the treatment of radioactive, hazardous, and mixed wastes was initially developed and patented by Brookhaven National Laboratory (BNL) in the mid-1980s (Kalb and Colombo, 1985; Colombo et al., 1997). The process was subsequently investigated by the Commission of the European Communities (Van Dalen and Rijpkema, 1989), Idaho National Engineering Laboratory (Darnell, 1991), and Oak Ridge National Laboratory (Mattus and Mattus, 1994). SPC has been used primarily in microencapsulation applications but can also be used for macroencapsulation of waste. SPC microencapsulation has been demonstrated to be an effective treatment for a wide variety of wastes, including incinerator hearth and fly ash; aqueous concentrates such as sulfates, borates, and chlorides; blowdown solutions; soils; and sludges. It is not recommended for treatment of wastes containing high concentrations of nitrates because of potentially dangerous reactions between sulfur, nitrate, and trace quantities of organics. Recently, the process has been adapted for the treatment of liquid elemental mercury and mercury contaminated soil and debris.

KALB, P.

2001-08-22T23:59:59.000Z

286

Method for the desulfurization of hot product gases from coal gasifier  

DOE Patents [OSTI]

The gasification of sulfur-bearing coal produces a synthesis gas which contains a considerable concentration of sulfur compounds especially hydrogen sulfide that renders the synthesis gas environmentally unacceptable unless the concentration of the sulfur compounds is significantly reduced. To provide for such a reduction in the sulfur compounds a calcium compound is added to the gasifier with the coal to provide some sulfur absorption. The synthesis gas from the gasifier contains sulfur compounds and is passed through an external bed of a regenerable solid absorbent, preferably zinc ferrite, for essentially completed desulfurizing the hot synthesis gas. This absorbent is, in turn, periodically or continuously regenerated by passing a mixture of steam and air or oxygen through the bed for converting absorbed hydrogen sulfide to sulfur dioxide. The resulting tail gas containing sulfur dioxide and steam is injected into the gasifier where the sulfur dioxide is converted by the calcium compound into a stable form of sulfur such as calcium sulfate.

Grindley, Thomas (Morgantown, WV)

1988-01-01T23:59:59.000Z

287

US Department of Energy`s high-temperature and high-pressure particulate cleanup for advanced coal-based power systems  

SciTech Connect (OSTI)

The availability of reliable, low-cost electricity is a cornerstone for the United States` ability to compete in the world market. The Department of Energy (DOE) projects the total consumption of electricity in the US to rise from 2.7 trillion kilowatt-hours in 1990 to 3.5 trillion in 2010. Although energy sources are diversifying, fossil fuel still produces 90 percent of the nation`s energy. Coal is our most abundant fossil fuel resource and the source of 56 percent of our electricity. It has been the fuel of choice because of its availability and low cost. A new generation of high-efficiency power systems has made it possible to continue the use of coal while still protecting the environment. Such power systems greatly reduce the pollutants associated with cola-fired plants built before the 1970s. To realize this high efficiency and superior environmental performance, advanced coal-based power systems will require gas stream cleanup under high-temperature and high-pressure (HTHP) process conditions. Presented in this paper are the HTHP particulate capture requirements for the Integrated Gasification Combined Cycle (IGCC) and Pressurized Fluidized-Bed Combustion (PFBC) power systems, the HTHP particulate cleanup systems being implemented in the PFBC and IGCC Clean Coal Technology (CCT) Projects, and the currently available particulate capture performance results.

Dennis, R.A.

1997-05-01T23:59:59.000Z

288

Sulfuric acid-sulfur heat storage cycle  

DOE Patents [OSTI]

A method of storing heat is provided utilizing a chemical cycle which interconverts sulfuric acid and sulfur. The method can be used to levelize the energy obtained from intermittent heat sources, such as solar collectors. Dilute sulfuric acid is concentrated by evaporation of water, and the concentrated sulfuric acid is boiled and decomposed using intense heat from the heat source, forming sulfur dioxide and oxygen. The sulfur dioxide is reacted with water in a disproportionation reaction yielding dilute sulfuric acid, which is recycled, and elemental sulfur. The sulfur has substantial potential chemical energy and represents the storage of a significant portion of the energy obtained from the heat source. The sulfur is burned whenever required to release the stored energy. A particularly advantageous use of the heat storage method is in conjunction with a solar-powered facility which uses the Bunsen reaction in a water-splitting process. The energy storage method is used to levelize the availability of solar energy while some of the sulfur dioxide produced in the heat storage reactions is converted to sulfuric acid in the Bunsen reaction.

Norman, John H. (LaJolla, CA)

1983-12-20T23:59:59.000Z

289

Pressurized fluidized-bed hydroretorting of Eastern oil shales -- Sulfur control  

SciTech Connect (OSTI)

This topical report on Sulfur Control'' presents the results of work conducted by the Institute of Gas Technology (IGT), the Illinois Institute of Technology (IIT), and the Ohio State University (OSU) to develop three novel approaches for desulfurization that have shown good potential with coal and could be cost-effective for oil shales. These are (1) In-Bed Sulfur Capture using different sorbents (IGT), (2) Electrostatic Desulfurization (IIT), and (3) Microbial Desulfurization and Denitrification (OSU and IGT). The objective of the task on In-Bed Sulfur Capture was to determine the effectiveness of different sorbents (that is, limestone, calcined limestone, dolomite, and siderite) for capturing sulfur (as H{sub 2}S) in the reactor during hydroretorting. The objective of the task on Electrostatic Desulfurization was to determine the operating conditions necessary to achieve a high degree of sulfur removal and kerogen recovery in IIT's electrostatic separator. The objectives of the task on Microbial Desulfurization and Denitrification were to (1) isolate microbial cultures and evaluate their ability to desulfurize and denitrify shale, (2) conduct laboratory-scale batch and continuous tests to improve and enhance microbial removal of these components, and (3) determine the effects of processing parameters, such as shale slurry concentration, solids settling characteristics, agitation rate, and pH on the process.

Roberts, M.J.; Abbasian, J.; Akin, C.; Lau, F.S.; Maka, A.; Mensinger, M.C.; Punwani, D.V.; Rue, D.M. (Institute of Gas Technology, Chicago, IL (United States)); Gidaspow, D.; Gupta, R.; Wasan, D.T. (Illinois Inst. of Tech., Chicago, IL (United States)); Pfister, R.M.: Krieger, E.J. (Ohio State Univ., Columbus, OH (United States))

1992-05-01T23:59:59.000Z

290

DEVELOPMENT OF DISPOSABLE SORBENTS FOR CHLORIDE REMOVAL FROM HIGH TEMPERATURE COAL-DERIVED GASES  

SciTech Connect (OSTI)

Advanced integrated-gasification combined-cycle (IGCC) and integrated-gasification fuel cell (IGFC) systems require the development of high temperature sorbents for the removal of hydrogen chloride (HCl) vapor to less than 1 parts-per-million (ppm) levels. HCl is a highly reactive, corrosive, and toxic gas which must be removed to meet environmental regulations, to protect power generation equipment, and to minimize deterioration of hot gas desulfurization sorbents. The objective of this program was to develop disposable, alkali-based sorbents capable of reducing HCl vapor levels to less than 1 ppm in the temperature range from 400 to 750 C and pressures in the range from 1 to 20 atm. The primary areas of focus of this program were to investigate different methods of sorbent fabrication, testing their suitability for different reactor configurations, obtaining reaction kinetics data, and conducting a preliminary economic feasibility assessment. This program was a joint effort between SRI International (SRI), Research Triangle Institute (RTI), and General Electric Corporate Research and Development (GE-CRD). SRI, the prime contractor and RTI, a major subcontractor, performed most of the work in this program. Thermochemical calculations indicated that sodium-based sorbents were capable of reducing HCl vapor levels to less than 1 ppm at temperatures up to 650 C, but the regeneration of spent sorbents would require complex process steps. Nahcolite (NaHCO{sub 3}), a naturally-occurring mineral, could be used as an inexpensive sorbent to remove HCl vapor in hot coal gas streams. In the current program, nahcolite powder was used to fabricate pellets suitable for fixed-bed reactors and granules suitable for fluidized-bed reactors. Pilot-scale equipment were used to prepare sorbents in large batches: pellets by disk pelletization and extrusion techniques, and granules by granulation and spray-drying techniques. Bench-scale fixed- and fluidized-bed reactors were assembled at SRI and RTI to conduct tests at high-temperature, high-pressure conditions (HTHP). The HTHP tests confirmed the ability of nahcolite pellets and granules to reduce the HCl vapor levels to less than 1 ppm levels with a very high sorbent utilization for chloride capture. The effect of several operating variables such as temperature, pressure, presence of hydrogen sulfide, and sorbent preparation methods was studied on the efficacy of HCl removal by the sorbent. Pilot-scale tests were performed in the fluidized-bed mode at the gasifier facility at the GE-CRD. Sorbent exposure tests were also conducted using a hot coal gas stream from the DOE/FETC's fluidized-bed gasifier at Morgantown, WV. These tests confirmed the results obtained at SRI and RTI. A preliminary economic assessment showed that the cost of HCl removal in a commercial IGCC system will be about $0.001/kWh (1 mills/kWh).

Gopala Krishnan; Raghubir Gupta

1999-09-01T23:59:59.000Z

291

Upgrading low-rank coals using the liquids from coal (LFC) process  

SciTech Connect (OSTI)

Three unmistakable trends characterize national and international coal markets today that help to explain coal`s continuing and, in some cases, increasing share of the world`s energy mix: the downward trend in coal prices is primarily influenced by an excess of increasing supply relative to increasing demand. Associated with this trend are the availability of capital to expand coal supplies when prices become firm and the role of coal exports in international trade, especially for developing nations; the global trend toward reducing the transportation cost component relative to the market, preserves or enhances the producer`s profit margins in the face of lower prices. The strong influence of transportation costs is due to the geographic relationships between coal producers and coal users. The trend toward upgrading low grade coals, including subbituminous and lignite coals, that have favorable environmental characteristics, such as low sulfur, compensates in some measure for decreasing coal prices and helps to reduce transportation costs. The upgrading of low grade coal includes a variety of precombustion clean coal technologies, such as deep coal cleaning. Also included in this grouping are the coal drying and mild pyrolysis (or mild gasification) technologies that remove most of the moisture and a substantial portion of the volatile matter, including organic sulfur, while producing two or more saleable coproducts with considerable added value. SGI International`s Liquids From Coal (LFC) process falls into this category. In the following sections, the LFC process is described and the coproducts of the mild pyrolysis are characterized. Since the process can be applied widely to low rank coals all around the world, the characteristics of coproducts from three different regions around the Pacific Rim-the Powder River Basin of Wyoming, the Beluga Field in Alaska near the Cook Inlet, and the Bukit Asam region in south Sumatra, Indonesia - are compared.

Nickell, R.E.; Hoften, S.A. van

1993-12-31T23:59:59.000Z

292

Coal quality trends and distribution of Title III trace elements in Eastern Kentucky coals  

SciTech Connect (OSTI)

The quality characteristics of eastern Kentucky coal beds vary both spatially and stratigraphically. Average total sulfur contents are lowest, and calorific values highest, in the Big Sandy and Upper Cumberland Reserve Districts. Average coal thickness is greatest in these two districts as well. Conversely, the thinnest coal with the highest total sulfur content, and lowest calorific value, on average, occurs in the Princess and Southwest Reserve Districts. Several Title III trace elements, notably arsenic, cadmium, lead, mercury, and nickel, mirror this distribution (lower average concentrations in the Big Sandy and Upper Cumberland Districts, higher average concentrations in the Princess and Southwest Districts), probably because these elements are primarily associated with sulfide minerals in coal. Ash yields and total sulfur contents are observed to increase in a stratigraphically older to younger direction. Several Title III elements, notably cadmium, chromium, lead, and selenium follow this trend, with average concentrations being higher in younger coals. Average chlorine concentration shows a reciprocal distribution, being more abundant in older coals. Some elements, such as arsenic, manganese, mercury, cobalt, and, to a lesser extent, phosphorus show concentration spikes in coal beds directly above, or below, major marine zones. With a few exceptions, average Title III trace element concentrations for eastern Kentucky coals are comparable with element distributions in other Appalachian coal-producing states.

Eble, C.F. [Kentucky Geological Survey, Lexington, KY (United States); Hower, J.C. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

1995-12-31T23:59:59.000Z

293

Modeling high-pressure adsorption of gas mixtures on activated carbon and coal using a simplified local-density model  

SciTech Connect (OSTI)

The simplified local-density (SLD) theory was investigated regarding its ability to provide accurate representations and predictions of high-pressure supercritical adsorption isotherms encountered in coalbed methane (CBM) recovery and CO{sub 2} sequestration. Attention was focused on the ability of the SLD theory to predict mixed-gas adsorption solely on the basis of information from pure gas isotherms using a modified Peng-Robinson (PR) equation of state (EOS). An extensive set of high-pressure adsorption measurements was used in this evaluation. These measurements included pure and binary mixture adsorption measurements for several gas compositions up to 14 MPa for Calgon F-400 activated carbon and three water-moistened coals. Also included were ternary measurements for the activated carbon and one coal. For the adsorption of methane, nitrogen, and CO{sub 2} on dry activated carbon, the SLD-PR can predict the component mixture adsorption within about 2.2 times the experimental uncertainty on average solely on the basis of pure-component adsorption isotherms. For the adsorption of methane, nitrogen, and CO{sub 2} on two of the three wet coals, the SLD-PR model can predict the component adsorption within the experimental uncertainties on average for all feed fractions (nominally molar compositions of 20/80, 40/60, 60/40, and 80/20) of the three binary gas mixture combinations, although predictions for some specific feed fractions are outside of their experimental uncertainties.

Fitzgerald, J.E.; Robinson, R.L.; Gasem, K.A.M. [Oklahoma State University, Stillwater, OK (United States). School of Chemical Engineering

2006-11-07T23:59:59.000Z

294

Coal Ash Corrosion Resistant Materials Testing Program  

SciTech Connect (OSTI)

The "Coal Ash Corrosion Resistant Materials Testing Program" is being conducted by The Babcock & Wilcox Company (B&W), the U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) at Reliant Energy?s Niles plant in Niles, Ohio to provide full-scale, in-situ testing of recently developed boiler superheater materials. Fireside corrosion is a key issue for improving efficiency of new coal fired power plants and improving service life in existing plants. In November 1998, B&W began development of a system to permit testing of advanced tube materials at metal temperatures typical of advanced supercritical steam temperatures (1100°F and higher) in a boiler exhibiting coal ash corrosive conditions. Several materials producers including Oak Ridge National Laboratory (ORNL) contributed advanced materials to the project. In the spring of 1999 a system consisting of three identical sections, each containing multiple segments of twelve different materials, was installed. The sections are cooled by reheat steam, and are located just above the furnace entrance in Niles? Unit #1, a 110 MWe unit firing high sulfur Ohio coal. In November 2001 the first section was removed for thorough metallurgical evaluation after 33 months of operation. The second and third sections remain in service and the second is expected to be removed in the fall of 2003; the last is tentatively planned for the fall of 2004. This paper describes the program; its importance; the design, fabrication, installation and operation of the test system; materials utilized; experience to date; and results of the evaluation of the first section.

McDonald, D.K.

2003-04-22T23:59:59.000Z

295

Small boiler uses waste coal  

SciTech Connect (OSTI)

Burning coal waste in small boilers at low emissions poses considerable problem. While larger boiler suppliers have successfully installed designs in the 40 to 80 MW range for some years, the author has been developing small automated fluid bed boiler plants for 25 years that can be applied in the range of 10,000 to 140,000 lbs/hr of steam. Development has centered on the use of an internally circulating fluid bed (CFB) boiler, which will burn waste fuels of most types. The boiler is based on the traditional D-shaped watertable boiler, with a new type of combustion chamber that enables a three-to-one turndown to be achieved. The boilers have all the advantages of low emissions of the large fluid boilers while offering a much lower height incorporated into the package boiler concept. Recent tests with a waste coal that had a high nitrogen content of 1.45% demonstrated a NOx emission below the federal limit of 0.6 lbs/mm Btu. Thus a NOx reduction on the order of 85% can be demonstrate by combustion modification alone. Further reductions can be made by using a selective non-catalytic reduction (SNCR) system and sulfur absorption of up to 90% retention is possible. The article describes the operation of a 30,000 lbs/hr boiler at the Fayette Thermal LLC plant. Spinheat has installed three ICFB boilers at a nursing home and a prison, which has been tested on poor-grade anthracite and bituminous coal. 2 figs.

Virr, M.J. [Spinheat Ltd. (United States)

2009-07-15T23:59:59.000Z

296

POC-scale testing of an advanced fine coal dewatering equipment/technique. Quarterly technical progress report No. 5, October--December, 1995  

SciTech Connect (OSTI)

Froth flotation technique is an effective and efficient process for recovering of ultra-fine (minus 74{mu}m) clean coal. Economical dewatering of an ultrafine clean coal product to a 20% level moisture will be an important step in successful implementation of the advanced cleaning processes. The main objective of the proposed program is to evaluate a novel surface modification technique, which utilizes the synergistic effect of metal ions-surfactant combination, for dewatering of ultra-fine clean coal on a proof-of-concept scale of 1 to 2 tph. The novel surface modification technique developed at the the University of Kentucky Center for Applied Energy Research will be evaluated using vacuum, centrifuge, and hyperbaric filtration equipment. Dewatering tests will be conducted using the fine clean coal froth produced by the column flotation units at the Powell Mountain Coal Company, Mayflower Preparation Plant in St. Charles, Virginia. The POC-scale studies will be conducted on two different types of clean coal, namely, high sulfur and low sulfur clean coal. Accomplishments for the past quarter are described.

Groppo, J.G.; Parekh, B.K.

1996-02-01T23:59:59.000Z

297

AISI/DOE Technology Roadmap Program: A Technology of Low Coal Rate and High Productivity of RHF Ironmaking  

SciTech Connect (OSTI)

An economical and environment-friendly ironmaking process based on heating the chemiexecy self-sufficient green balls of iron ore and coal in a hearth furnace is being developed with financial support from AISI members and DOE. DRI, which is hot (1400 C), dense (3.2 g/cm) and of high degree of metallization (95%), has been produced in laboratory and in a pilot plant in Genoa, Italy. Products of such quality have been made from American and Brazilian ores, BOF sludge, EAF dust/BOF sludge mixtures and millscale. The removal of zinc and lead from green balls by this process is essentially complete. In comparison with typical blast furnace operation, the new technology with a melter would have a lower total coal rate by 200kg.THM. The elimination of cokemaking and high temperature agglomeration steps, and a simpler gas handling system would lead to lower capital and operating costs. In comparison with commercial RHF practice it is different in atmosphere (fully oxidized at 1600 to 1650 C), in bed height (120 mm instead of 20-25 mm) and in pellet composition (much less coal but of higher VM). The combined effect leads to three times higher furnace productivity, lower coal consumption and superior DRI quality. The risk of re-oxidation (slag formation) and dusty operation are practiexecy eliminated. The process is stable, tolerant and independent of the size, shape and movement of the hearth. However, materials handling (e.g., discharge of hot DRI) and the exact energy savings have to be established in a larger furnace, straight or rotary, and in a continuous mode of operation.

Wei-Kao Lu

2002-09-15T23:59:59.000Z

298

Coal-fueled high-speed diesel engine development. Final report, September 28, 1990--November 30, 1993  

SciTech Connect (OSTI)

The goal of this program was to study the feasibility of operating a Detroit Diesel Series 149 engine at high speeds using a Coal-Water-Slurry (CWS) fuel. The CWS-fueled 149 engine is proposed for the mine-haul off-highway truck and work boat marine markets. Economic analysis studies indicate that, for these markets, the use of CWS fuel could have sufficient operating cost savings, depending upon the future diesel fuel price, emission control system capital and operating costs, and maintenance and overhaul costs. A major portion of the maintenance costs is expected to be due to lower life and higher cost of the CWS injectors. Injection and combustion systems were specially designed for CWS, and were installed in one cylinder of a Detroit Diesel 8V-149TI engine for testing. The objective was to achieve engine operation for sustained periods at speeds up to 1,900 rpm with reasonable fuel economy and coal burnout rate. A computer simulation predicted autoignition of coal fuel at 1,900 rpm would require an average droplet size of 18 microns and 19:1 compression ratio, so the injection system, and pistons were designed accordingly. The injection system was capable of supplying the required volume of CWS/injection with a duration of approximately 25 crank angle degrees and peak pressures on the order of 100 mpa. In addition to the high compression ratio, the combustion system also utilized hot residual gases in the cylinder, warm inlet air admission and ceramic insulated engine components to enhance combustion. Autoignition of CWS fuel was achieved at 1900 rpm, at loads ranging from 20--80 percent of the rated load of diesel-fuel powered cylinders. Limited emissions data indicates coal burnout rates in excess of 99 percent. NO{sub x} levels were significantly lower, while unburned hydrocarbon levels were higher for the CWS fueled cylinder than for corresponding diesel-fuel powered cylinders.

Kakwani, R.M.; Winsor, R.E.; Ryan, T.W. III; Schwalb, J.A.; Wahiduzzaman, S.; Wilson, R.P. Jr.

1993-09-01T23:59:59.000Z

299

A novel concept for high conversion of coal to liquids. Final report, 1 September 1988--31 August 1992  

SciTech Connect (OSTI)

A batch microreactor was designed and fabricated as a means of investigating maximum yields of liquids obtainable in very short reaction times of the order of a few seconds, and the maximum ratios of liquids/hydrocarbon (HC) gases obtainable under those conditions. A Wyodak sub-bituminous coal, crushed and sieved to {minus}200 mesh particle size, was used in the experiments, with a temperature of 500{degrees}C and a pressure of 1500 psi. The fine coal particles were fed dry to the reactor and heated to reaction temperature in times of one to two seconds. At a time of 3 seconds at reaction temperature, in a single pass a liquid yield of 60% by weight of the coal was obtained, accompanied by a ratio of liquids/(HC) gases of 30/1. When the unreacted solids were recycled to the reactor, and the results combined with those of the first pass, a liquid yield of 82% by weight of the coal was achieved, accompanied by a ratio of liquids/HC gases of 30/1. This ratio represents only about 3 wt percent HC gases, much lower that is produced in current advanced technologies, and represents a large saving in hydrogen consumption. A simulated distillation technique was applied to the liquids. The liquid product contained 86% by weight (of the liquids) total distillables (boiling point below 538{degrees}C), including 70% by weight of low-boiling fractions in the gasoline, kerosene and gas oil range (boiling point up to 325{degrees}C). The liquid product exhibited a H/C ratio of 1.5, which is considerably higher than observed in current advanced technologies for the primary liquids. Several catalysts were investigated. Iron catalysts, specifically ferric chloride hexahydrate and ferric sulfate pentahydrate, each produced these high conversions and high ratios of liquids/HC gases.

Wiser, W.H.; Shabtai, J.

1994-04-01T23:59:59.000Z

300

The determination of sulfur-containing surfactants with a high pressure liquid chromatography-inductively coupled plasma emission spectrometry system  

E-Print Network [OSTI]

of the blank millivolt intensities 78 17 Average millivolt intensities for the nickel standard solution 79 Table Page 18 Standard deviations of the nickel standard millivolt intensities 80 19 Slopes of the calibration lines calculated from the blank... widely used sulfur-containing surfactants. The alkylbenzenesulfonates 1 strongly absorb in the UV region and, therefore are easily monitored by UV detectors. Other surfactants, such as alkyl sulfates 2 [13-17], alpha olefin sulfonates 3 [16...

Hobill, Jonathan Edward

1987-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Sulfur oxide adsorbents and emissions control  

DOE Patents [OSTI]

High capacity sulfur oxide absorbents utilizing manganese-based octahedral molecular sieve (Mn--OMS) materials are disclosed. An emissions reduction system for a combustion exhaust includes a scrubber 24 containing these high capacity sulfur oxide absorbents located upstream from a NOX filter 26 or particulate trap.

Li, Liyu (Richland, WA); King, David L. (Richland, WA)

2006-12-26T23:59:59.000Z

302

Sulfur minimization in bacterial leaching  

SciTech Connect (OSTI)

The production of sewage biosolids in Ontario in 1989 was estimated to be 7 million m{sup 3} of wet sludge per year. Of this amount, land application accounts for between 20 and 30% of the total. Unfortunately, the use of sewage biosolids on agricultural land is often prohibited because of heavy metal contamination of the biosolids. High cost and operational problems have made chemical methods of metal extraction unattractive. Consequently, microbiological methods of leaching of heavy metals have been studied for over a decade. A relatively simple microbiological process has been investigated in recent years in flask level experiments and recently in a semicontinuous system. The process exploits nonacidophilic and acidophilic indigenous thiobacilli to extract heavy metals from sewage biosolids. These thiobacilli use elemental sulfur as the energy source, producing sulfuric acid. However, the resulting decontaminated biosolids can cause environmental problems like acidification of the soil, when acid is generated from the residual sulfur in the biosolids. The present study examines the possibility of reducing the amount of sulfur added in batch and semicontinuous bacterial leaching systems, and maximizing sulfur oxidation efficiency, thereby reducing the residual sulfur in leached biosolids.

Seth, R.; Prasad, D.; Henry, J.G. [Univ. of Toronto, Ontario (Canada). Dept. of Civil Engineering

1996-11-01T23:59:59.000Z

303

The development of coal-based technologies for Department of Defense facilities. Volume 1, Technical report. Semiannual technical progress report, September 28, 1994--March 27, 1995  

SciTech Connect (OSTI)

This program is being conducted as a cooperative agreement between the Consortium for Coal Water Mixture Technology and the U.S. Department of Energy. Activities this reporting period are summarized by phase. Phase I is nearly completed. During this reporting period, coal beneficiation/preparation studies, engineering designs and economics for retrofitting the Crane, Indiana boiler to fire coal-based fuels, and a 1,000-hour demonstration of dry, micronized coal were completed. In addition, a demonstration-scale micronized-coal water mixture (MCWM) preparation circuit was constructed and a 1,000-hour demonstration firing MCWM began. Work in Phase II focused on emissions reductions, coal beneficiation/preparation studies, and economic analyses of coal use. Emissions reductions investigations involved literature surveys of NO{sub x}, SO{sub 2}, trace metals, volatile organic compounds, and fine particulate matter capture. In addition, vendors and engineering firms were contacted to identify the appropriate emissions technologies for the installation of commercial NO{sub x} and SO{sub 2} removal systems on the demonstration boiler. Information from the literature surveys and engineering firms will be used to identify, design, and install a control system(s). Work continued on the refinement and optimization of coal grinding and MCWM preparation procedures, and on the development of advanced processes for beneficiating high ash, high sulfur coals. Work also continued on determining the basic cost estimation of boiler retrofits, and evaluating environmental, regulatory, and regional economic impacts. In addition, the feasibility of technology adoption, and the public`s perception of the benefits and costs of coal usage was studied. A coal market analysis was completed. Work in Phase III focused on coal preparation studies, emissions reductions and economic analyses of coal use.

Miller, B.G.; Bartley, D.A.; Hatcher, P. [Pennsylvania State Univ., University Park, PA (United States). Energy and Fuels Research Center] [and others

1996-10-15T23:59:59.000Z

304

Prediction of oxy-coal flame stand-off using high-fidelity thermochemical models  

E-Print Network [OSTI]

, char oxi- dation and gasification are both considered. Results indicate that char oxidation and gasification are both significant during the later stages of devolatilization. The impact of radiative-coal combustion and gasification physics, in particular the ignition delay, flame stability and temperature, flame

305

Next Generation Pressurized Oxy-Coal Combustion: High Efficiency and No Flue Gas Recirculation  

SciTech Connect (OSTI)

The Gas Technology Institute (GTI) has developed a pressurized oxy-coal fired molten bed boiler (MBB) concept, in which coal and oxygen are fired directly into a bed of molten coal slag through burners located on the bottom of the boiler and fired upward. Circulation of heat by the molten slag eliminates the need for a flue gas recirculation loop and provides excellent heat transfer to steam tubes in the boiler walls. Advantages of the MBB technology over other boilers include higher efficiency (from eliminating flue gas recirculation), a smaller and less expensive boiler, modular design leading to direct scalability, decreased fines carryover and handling costs, smaller exhaust duct size, and smaller emissions control equipment sizes. The objective of this project was to conduct techno-economic analyses and an engineering design of the MBB project and to support this work with thermodynamic analyses and oxy-coal burner testing. Techno-economic analyses of GTI’s pressurized oxy-coal fired MBB technology found that the overall plant with compressed CO2 has an efficiency of 31.6%. This is a significant increase over calculated 29.2% efficiency of first generation oxy-coal plants. Cost of electricity (COE) for the pressurized MBB supercritical steam power plant with CO2 capture and compression was calculated to be 134% of the COE for an air-coal supercritical steam power plant with no CO2 capture. This compares positively with a calculated COE for first generation oxy-coal supercritical steam power plants with CO2 capture and compression of 164%. The COE for the MBB power plant is found to meet the U.S. Department of Energy (DOE) target of 135%, before any plant optimization. The MBB power plant was also determined to be simpler than other oxy-coal power plants with a 17% lower capital cost. No other known combustion technology can produce higher efficiencies or lower COE when CO2 capture and compression are included. A thermodynamic enthalpy and exergy analysis found a number of modifications and adjustments that could provide higher efficiency and better use of available work. Conclusions from this analysis will help guide the analyses and CFD modeling in future process development. The MBB technology has the potential to be a disruptive technology that will enable coal combustion power plants to be built and operated in a cost effective way, cleanly with no carbon dioxide emissions. A large amount of work is needed to quantify and confirm the great promise of the MBB technology. A Phase 2 proposal was submitted to DOE and other sponsors to address the most critical MBB process technical gaps. The Phase 2 proposal was not accepted for current DOE support.

Rue, David

2013-09-30T23:59:59.000Z

306

Low severity coal liquefaction promoted by cyclic olefins  

SciTech Connect (OSTI)

Low severity coal liquefaction allows for solubilization of coal with reduced gas make. These lower severity conditions may result in some selective bond rupture. Promotion of coal solubilization through hydrogen transfer using highly active and effective hydrogen donors is the objective of this study. The highly effective donors being tested are cyclic olefins. Representative cyclic olefins are isotetralin, which is 1,4,5,8-tetrahydronaphthalene, and 1,4,5,8,9,10-hexahydroanthracene. These compounds are hydroaromatics without aromatic rings and have been shown to be highly effective donors. The objective of the work performed in this study during this quarter was to evaluate reaction parameters for low severity liquefaction reactions using the cyclic olefin, hexahydroanthracene, and the aromatic, anthracene. These model compounds were reacted under a variety of conditions to evaluate their reactivity without coal. The reactions were performed under both thermal and catalytic conditions. Finely divided catalysts from different molybdenum precursors were used to determine their activity in promoting hydrogenation and hydrogen transfer at low severity conditions. The catalysts used were Molyvan L, sulfurized oxymolybdenum dithiocarbamate, molybdenum naphthenate, and Molyvan 822, organo molybdenum dithiocarbamate.

Curtis, C.W.

1992-07-27T23:59:59.000Z

307

Coal desulfurization by bacterial treatment and column flotation. Final report  

SciTech Connect (OSTI)

A review of the literature showed that bacterial leaching, using the microorganism Thiobacillus ferrooxidans, was a very effective technique for removing pyrite from coal, as it could dissolve even the finest pyrite particles without the need for expensive reagents or extreme processing conditions. Unfortunately, bacterial leaching is also rather slow, and so the initial goal of this research was to decrease the leaching time as much as possible. However, this still left the bacteria needing approximately a week to remove half of the pyritic sulfur, and so a faster technique was sought. Since it had been reported in the literature that T. ferrooxidans could be used to depress the flotation of pyrite during froth flotation of coal, this was investigated further. By studying the recovery mechanisms of coal-pyrite in froth flotation, it was found that pyrite was being recovered by entrainment and by locking to coal particles, not by true flotation of hydrophobic pyrite. Therefore, no pyrite depressant could be of any significant benefit for keeping pyrite out of the coal froth product, and it was much more important to prevent entrainment from occurring. Countercurrent flotation columns were invented to essentially eliminate entrainment effects, by washing the froth and reducing mixing of the froth and tailings products. Existing flotation columns tend to be quite simple, and in order to give reasonable product quality they must be very tall (typically 30--45 feet). As a result, they have difficulty in handling the high froth volumes which occur in coal flotation, and are awkward to install in existing plants. The bulk of this project therefore concentrated on developing an improved coal flotation column, and testing it under actual plant conditions.

Kawatra, S.K. [Michigan Technological Univ., Houghton, MI (United States)

1994-06-01T23:59:59.000Z

308

Advanced product recovery: Direct catalytic reduction of sulfur dioxide to elemental sulfur. Third quarterly technical progress report  

SciTech Connect (OSTI)

More than 170 wet scrubber systems applied to 72,000 MW of US, coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed form the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. Arthur D. Little, Inc., together with its industry and commercialization advisor, Engelhard Corporation, and its university partner, Tufts, plans to develop and scale-up an advanced, byproduct recovery technology that is a direct, catalytic process for reducing sulfur dioxide to elemental sulfur. The principal objective of the Phase 1 program is to identify and evaluate the performance of a catalyst which is robust and flexible with regard to choice of reducing gas. In order to achieve this goal, they have planned a structured program including: market/process/cost/evaluation; lab-scale catalyst preparation/optimization studies; lab-scale, bulk/supported catalyst kinetic studies; bench-scale catalyst/process studies; and utility review. This catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria and zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning.

NONE

1996-07-01T23:59:59.000Z

309

Compositional characteristics of the Fire Clay coal bed in a portion of eastern Kentucky  

SciTech Connect (OSTI)

The Fire Clay (Hazard No. 4) coal bed (Middle Pennsylvanian Breathitt Formation) is one of the most extensively mined coal in eastern Kentucky. The coal is used for metallurgical and steam end uses and, with its low sulfur content, should continue to be a prime steam coal. This study focuses on the petrology, mineralogy, ash geochemistry, and palynology of the coal in an eight 7.5-min quadrangle area of Leslie, Perry, Knott, and Letcher counties.

Hower, J.C.; Andrews, W.M. Jr.; Rimmer, S.M. (Univ. of Kentucky, Lexington (United States)); Eble, C.F. (Kentucky Geological Survey, Lexington (United States))

1991-08-01T23:59:59.000Z

310

Alaska coal geology, resources, and coalbed methane potential  

SciTech Connect (OSTI)

Estimated Alaska coal resources are largely in Cretaceous and Tertiary rocks distributed in three major provinces, Northern Alaska-Slope, Central Alaska-Nenana, and Southern Alaska-Cook Inlet. Cretaceous resources, predominantly bituminous coal and lignite, are in the Northern Alaska-Slope coal province. Most of the Tertiary resources, mainly lignite to subbituminous coal with minor amounts of bituminous and semianthracite coals, are in the other two provinces. The combined measured, indicated, inferred, and hypothetical coal resources in the three areas are estimated to be 5,526 billion short tons (5,012 billion metric tons), which constitutes about 87 percent of Alaska's coal and surpasses the total coal resources of the conterminous United States by 40 percent. Coal mining has been intermittent in the Central Alaskan-Nenana and Southern Alaska-Cook Inlet coal provinces, with only a small fraction of the identified coal resource having been produced from some dozen underground and strip mines. Alaskan coals have a lower sulfur content (averaging 0.3 percent) than most coals in the conterminous United States and are within or below the minimum sulfur value mandated by the 1990 Clean Air Act amendments. Another untapped potential resource is coalbed methane estimated to total 1,000 trillion cubic feet (28 trillion cubic meters).

Romeo M. Flores; Gary D. Stricker; Scott A. Kinney

2005-11-15T23:59:59.000Z

311

Improved heat recovery and high-temperature clean-up for coal-gas fired combustion turbines  

SciTech Connect (OSTI)

This study investigates the performance of an Improved Heat Recovery Method (IHRM) applied to a coal-gas fired power-generating system using a high-temperature clean-up. This heat recovery process has been described by Higdon and Lynn (1990). The IHRM is an integrated heat-recovery network that significantly increases the thermal efficiency of a gas turbine in the generation of electric power. Its main feature is to recover both low- and high-temperature heat reclaimed from various gas streams by means of evaporating heated water into combustion air in an air saturation unit. This unit is a packed column where compressed air flows countercurrently to the heated water prior to being sent to the combustor, where it is mixed with coal-gas and burned. The high water content of the air stream thus obtained reduces the amount of excess air required to control the firing temperature of the combustor, which in turn lowers the total work of compression and results in a high thermal efficiency. Three designs of the IHRM were developed to accommodate three different gasifying process. The performances of those designs were evaluated and compared using computer simulations. The efficiencies obtained with the IHRM are substantially higher those yielded by other heat-recovery technologies using the same gasifying processes. The study also revealed that the IHRM compares advantageously to most advanced power-generation technologies currently available or tested commercially. 13 refs., 34 figs., 10 tabs.

Barthelemy, N.M.; Lynn, S.

1991-07-01T23:59:59.000Z

312

The magnetohydrodynamics Coal-Fired Flow Facility. Technical progress report, July 1, 1992--September 30, 1992  

SciTech Connect (OSTI)

In this quarterly technical progress report, UTSI reports on progress on a multi-task contract to develop the technology for the steam bottoming plant for an MHD Steam Combined Cycle power plant. Two proof-of-concept (POC) tests totaling 614 hours of coal fired operation were conducted during the quarter using low sulfur Montana Rosebud coal. The results of these tests are summarized. Operational aspects of the particulate control devices being evaluated, a dry electrostatic precipitator (ESP) and a reverse air baghouse, are discussed. A sootblowing control system for the convective heat transfer surfaces that senses the need to clean the tubes by temperatures is described. Environmental reporting includes measurement of levels of ground water wells over time and the remote air quality measurements of impact of the stack emissions from the two tests. Results of testing candidate ceramic tubes for a recuperative high temperature air heater are included. Analyses of the tube materials tested in the 2000 hour test series previously completed on high sulfur Illinois No. 6 coal are summarized. Facility maintenance and repair activities for the DOE Coal Fired Flow Facility are summarized. The major facility modification discussed is the completion of the installation of a Wet ESP with rotary vacuum filter which is replacing the venturi scrubber as the primary facility particulate control device for any exhaust gases that are not routed through the dry ESP or baghouse.

Not Available

1993-02-01T23:59:59.000Z

313

Computational Fluid Dynamics (CFD) Modeling for High Rate Pulverized Coal Injection (PCI) into the Blast Furnace  

SciTech Connect (OSTI)

Pulverized coal injection (PCI) into the blast furnace (BF) has been recognized as an effective way to decrease the coke and total energy consumption along with minimization of environmental impacts. However, increasing the amount of coal injected into the BF is currently limited by the lack of knowledge of some issues related to the process. It is therefore important to understand the complex physical and chemical phenomena in the PCI process. Due to the difficulty in attaining trus BF measurements, Computational fluid dynamics (CFD) modeling has been identified as a useful technology to provide such knowledge. CFD simulation is powerful for providing detailed information on flow properties and performing parametric studies for process design and optimization. In this project, comprehensive 3-D CFD models have been developed to simulate the PCI process under actual furnace conditions. These models provide raceway size and flow property distributions. The results have provided guidance for optimizing the PCI process.

Dr. Chenn Zhou

2008-10-15T23:59:59.000Z

314

Progressive flow cracking of coal/oil mixtures with high metals content catalyst  

SciTech Connect (OSTI)

This patent describes a process for economically producing liquid fuel products at least partly from coal. It comprises: introducing a progressive flow catalytic cracking zone a charge stock comprising a pumpable mixture of solid, particulate coal and carbo-metallic oil and forming within the zone a stream having a linear velocity of at least about 25 feet per second. The stream comprising the charge stock and a hydrocarbon zeolite cracking catalyst promoting dehydrogenation of the charge stock; forming mobile hydrogen within the zone by the dehydrogenation; introducing the mobile hydrogen into the stream by dehydrogenation of the charge stock in the absence of added molecular hydrogen, thereby producing liquid products from the charge stock while laying down coke on the hydrocarbon cracking catalyst in the range of about 0.3% to about 3% and thereby producing spent catalyst; separating from the spent catalyst the liquid products.

Zandona, O.J.

1989-10-10T23:59:59.000Z

315

Calcium looping process for high purity hydrogen production integrated with capture of carbon dioxide, sulfur and halides  

DOE Patents [OSTI]

A process for producing hydrogen comprising the steps of: (i) gasifying a fuel into a raw synthesis gas comprising CO, hydrogen, steam, sulfur and halide contaminants in the form of H.sub.2S, COS, and HX, wherein X is a halide; (ii) passing the raw synthesis gas through a water gas shift reactor (WGSR) into which CaO and steam are injected, the CaO reacting with the shifted gas to remove CO.sub.2, sulfur and halides in a solid-phase calcium-containing product comprising CaCO.sub.3, CaS and CaX.sub.2; (iii) separating the solid-phase calcium-containing product from an enriched gaseous hydrogen product; and (iv) regenerating the CaO by calcining the solid-phase calcium-containing product at a condition selected from the group consisting of: in the presence of steam, in the presence of CO.sub.2, in the presence of synthesis gas, in the presence of H.sub.2 and O.sub.2, under partial vacuum, and combinations thereof.

Ramkumar, Shwetha; Fan, Liang-Shih

2013-07-30T23:59:59.000Z

316

Determination of the effects caused by different polymers on coal fluidity during carbonization using high-temperature {sup 1}H NMR and rheometry  

SciTech Connect (OSTI)

The effects of blending polyethylene (PE), polystyrene (PS), poly(ethyleneterephthalate) (PET), a flexible polyurethane (FPU), and a car shredded fluff waste (CSF) on fluidity development of a bituminous coal during carbonization have been studied by means of high-torque, small-amplitude controlled-strain rheometry and in situ high-temperature {sup 1}H NMR spectroscopy. The most detrimental effects were caused by PET and PS, which completely destroyed the fluidity of the coal. The CSF had a deleterious effect on coal fluidity similar to that of PET, although the deleterious effect on the viscoelastic properties of the coal were less pronounced than those of PET and PS. On the contrary, the addition of 10 wt % PE caused a slight reduction in the concentration of fluid hydrogen and an increase in the minimum complex viscosity, and the addition of 10 wt % FPU reduced the concentration of fluid hydrogen without changing the viscoelastic properties of the coal. Although these results suggest that these two plastics could potentially be used as additives in coking blends without compromising coke porosity, it was found that the semicoke strengths were reduced by adding 2 wt % FPU and 5 wt % PE. Therefore, it is unlikely that more than 2 wt % of a plastic waste could be added to a coal blend without deterioration in coke quality. 35 refs., 11 figs., 3 tabs.

Miguel Castro Diaz; Lucky Edecki; Karen M. Steel; John W. Patrick; Colin E. Snape [Nottingham University, Nottingham (United Kingdom). Nottingham Fuel and Energy Centre, School of Chemical, Environmental and Mining Engineering

2008-01-15T23:59:59.000Z

317

Pressurized fluidized-bed hydroretorting of Eastern oil shales -- Sulfur control. Topical report for Subtask 3.1, In-bed sulfur capture tests; Subtask 3.2, Electrostatic desulfurization; Subtask 3.3, Microbial desulfurization and denitrification  

SciTech Connect (OSTI)

This topical report on ``Sulfur Control`` presents the results of work conducted by the Institute of Gas Technology (IGT), the Illinois Institute of Technology (IIT), and the Ohio State University (OSU) to develop three novel approaches for desulfurization that have shown good potential with coal and could be cost-effective for oil shales. These are (1) In-Bed Sulfur Capture using different sorbents (IGT), (2) Electrostatic Desulfurization (IIT), and (3) Microbial Desulfurization and Denitrification (OSU and IGT). The objective of the task on In-Bed Sulfur Capture was to determine the effectiveness of different sorbents (that is, limestone, calcined limestone, dolomite, and siderite) for capturing sulfur (as H{sub 2}S) in the reactor during hydroretorting. The objective of the task on Electrostatic Desulfurization was to determine the operating conditions necessary to achieve a high degree of sulfur removal and kerogen recovery in IIT`s electrostatic separator. The objectives of the task on Microbial Desulfurization and Denitrification were to (1) isolate microbial cultures and evaluate their ability to desulfurize and denitrify shale, (2) conduct laboratory-scale batch and continuous tests to improve and enhance microbial removal of these components, and (3) determine the effects of processing parameters, such as shale slurry concentration, solids settling characteristics, agitation rate, and pH on the process.

Roberts, M.J.; Abbasian, J.; Akin, C.; Lau, F.S.; Maka, A.; Mensinger, M.C.; Punwani, D.V.; Rue, D.M. [Institute of Gas Technology, Chicago, IL (United States); Gidaspow, D.; Gupta, R.; Wasan, D.T. [Illinois Inst. of Tech., Chicago, IL (United States); Pfister, R.M.: Krieger, E.J. [Ohio State Univ., Columbus, OH (United States)

1992-05-01T23:59:59.000Z

318

Petrography and chemistry of high-carbon fly ash from the Shawnee Power Station, Kentucky  

SciTech Connect (OSTI)

The Shawnee power station in western Kentucky consists of ten 150-MW units, eight of which burn low-sulfur (< 1 wt %) eastern Kentucky and central West Virginia coal. The other units burn medium- and high-sulfur (> 1 wt %) coal in an atmospheric fluidized-bed combustion unit and in a research unit. The eight low-sulfur coal units were sampled in a 1992 survey of Kentucky utilities. Little between-unit variation is seen in the ash-basis major oxide and minor element chemistry. The carbon content of the fly ashes varies from 5 to 25 wt %. Similarly, the isotropic and anisotropic coke in the fly ash varies from 6% to 42% (volume basis). Much of the anisotropic coke is a thin-walled macroporous variety, but there is a portion that is a thick-walled variety similar to a petroleum coke.

Hower, J.C.; Thomas, G.A.; Robertson, J.D.; Wong, A.S. [Univ. of Kentucky, Lexington, KY (United States); Clifford, D.S.; Eady, J.D. [Tennessee Valley Authority, Chattanooga, TN (United States)

1996-01-01T23:59:59.000Z

319

Coal pump  

DOE Patents [OSTI]

A device for pressurizing pulverized coal and circulating a carrier gas is disclosed. This device has utility in a coal gasification process and eliminates the need for a separate collection hopper and eliminates the separate compressor.

Bonin, John H. (Sunnyvale, CA); Meyer, John W. (Palo Alto, CA); Daniel, Jr., Arnold D. (Alameda County, CA)

1983-01-01T23:59:59.000Z

320

Sixth annual coal preparation, utilization, and environmental control contractors conference  

SciTech Connect (OSTI)

A conference was held on coal preparation, utilization and environmental control. Topics included: combustion of fuel slurries; combustor performance; desulfurization chemically and by biodegradation; coal cleaning; pollution control of sulfur oxides and nitrogen oxides; particulate control; and flue gas desulfurization. Individual projects are processed separately for the databases. (CBS).

Not Available

1990-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

The development of coal-based technologies for Department of Defense facilities. Semiannual technical progress report, September 28, 1992--March 27, 1993  

SciTech Connect (OSTI)

The US Department of Defense (DOD), through an Interagency Agreement with the US Department of Energy (DOE), has initiated a three-phase program with the Consortium for Coal-Water Slurry Fuel Technology, with the aim of decreasing DOD`s reliance on imported oil by increasing its use of coal. The program is being conducted as a cooperative agreement between the Consortium and DOE and the first phase of the program is underway. Phase I activities are focused on developing clean, coal-based combustion technologies for the utilization of both micronized coal-water mixtures (MCWMs) and dry, micronized coal (MC) in fuel oil-designed industrial boilers. Phase II research and development activities will continue to focus on industrial boiler retrofit technologies by addressing emissions control and pre-combustion (i.e., slagging combustion and/or gasification) strategies for the utilization of high ash and high sulfur coals. Phase III activities will examine coal-based fuel combustion systems that cofire wastes. Each phase includes an engineering cost analysis and technology assessment. The activities and status of Phase I are described below. The objective in Phase I is to deliver fully engineered retrofit options for a fuel oil- designed watertube boiler located on a DOD installation to fire either MCWM or MC. This will be achieved through a program consisting of the following five tasks: (1) Coal Beneficiation and Preparation; (2) Combustion Performance Evaluation; (3) Engineering Design; (4) Engineering and Economic Analysis; (5) Final Report/Submission of Design Package.

Miller, B.G.; Scaroni, A.W.; Hogg, R. [and others

1993-05-13T23:59:59.000Z

322

High conversion of coal to transportation fuels for the future with low HC gas production. Progress report No. 14, January 1--March 31, 1996  

SciTech Connect (OSTI)

The objective of this project is to produce a synthetic crude from coal at a cost lower than $30.00 per barrel (Task A). A second objective, reflecting a recent change in direction in the synthetic fuels effort of DOE, is to produce a fuel which is low in aromatics, yet of sufficiently high octane number for use in the gasoline- burning transportation vehicles of today. To meet this second objective, research was proposed, and funding awarded, for conversion of the highly-aromatic liquid product from coal conversion to a product high in isoparaffins, which compounds in the gasoline range exhibit a high octane number (Task B). Experimental coal liquefaction studies conducted in a batch microreactor in our laboratory have demonstrated potential for high conversions of coal to liquids with low yields of hydrocarbon (HC) gases, hence small consumption of hydrogen in the primary liquefaction step. Ratios of liquids/HC gases as high as 30/1, at liquid yields as high as 82% of the coal by weight, have been achieved. The principal objective of this work is to examine how nearly we may approach these results in a continuous- flow system, at a size sufficient to evaluate the process concept for production of transportation fuels from coal. A continuous system has been constructed and operated, with a one-half inch inside diameter (ID) tube as the reaction vessel. As the work in this project proceeded toward its conclusion, an unexpected benefit was discovered. As the residence times were decreased to values of 10 seconds or less, ratios of liquids/HC gases of 20/1 or higher were achieved. But very importantly, it was discovered that the chemical reactions which produce the primary liquids can be carried to high conversions at pressures much lower than reported, and indeed required, in the processes at longer times.

Wiser, W.H.; Oblad, A.G.

1996-04-01T23:59:59.000Z

323

Petrographic characterization of Kentucky coal. Final report. Part III. Petrographic characterization of the Upper Elkhorn No. 2 coal zone of eastern Kentucky  

SciTech Connect (OSTI)

This report presents the study of the Upper Elkhorn No. 2 coal zone in the Big Sandy Reserve District and the surrounding area of eastern Kentucky. The seams were analyzed using megascopic and microscopic petrography and chemical methods. The Upper Elkhorn No. 2 consists predominantly of clarain. A fair degree of correlation of fusain bands and clay partings between data sites is apparent. Microscopically, the vitrinite group of macerals are dominant. A rank increase from high volatile B to high volatile A bituminous to the southwest was noted. Pseudovitrinite is associated negatively with vitrinite and has a higher reflectance and microhardness than vitrinite. Both factors may indicate source material and/or environmental differences in the respective origins of the maceral. High inertinite and lipinite areas, low ash and sulfur contents, and the distribution of thin coals may be indicative of paleotopographic highs. 62 references, 26 figures, 8 tables.

Raione, R.P.; Hower, J.C.

1984-01-01T23:59:59.000Z

324

Coal markets squeeze producers  

SciTech Connect (OSTI)

Supply/demand fundamentals seem poised to keep prices of competing fossil fuels high, which could cushion coal prices, but increased mining and transportation costs may squeeze producer profits. Are markets ready for more volatility?

Ryan, M.

2005-12-01T23:59:59.000Z

325

Highly Selective H2 Separation Zeolite Membranes for Coal Gasification Membrane Reactor Applications  

SciTech Connect (OSTI)

Zeolite membranes are thermally, chemically, and mechanically stable. They also have tunable molecular sieving and catalytic ability. These unique properties make zeolite membrane an excellent candidate for use in catalytic membrane reactor applications related to coal conversion and gasification, which need high temperature and high pressure range separation in chemically challenging environment where existing technologies are inefficient or unable to operate. Small pore, good quality, and thin zeolite membranes are needed for highly selective H{sub 2} separation from other light gases (CO{sub 2}, CH{sub 4}, CO). However, zeolite membranes have not been successful for H{sub 2} separation from light gases because the zeolite pores are either too big or the membranes have a large number of defects. The objective of this study is to develop zeolite membranes that are more suitable for H{sub 2} separation. In an effort to tune the size of zeolite pores and/or to decrease the number of defects, medium-pore zeolite B-ZSM-5 (MFI) membranes were synthesized and silylated. Silylation on B-ZSM-5 crystals reduced MFI-zeolite pore volume, but had little effect on CO{sub 2} and CH{sub 4} adsorption. Silylation on B-ZSM-5 membranes increased H{sub 2} selectivity both in single component and in mixtures with CO{sub 2}CO{sub 2}, CH{sub 4}, or N2. Single gas and binary mixtures of H{sub 2}/CO{sub 2} and H{sub 2}/CH{sub 4} were separated through silylated B-ZSM-5 membranes at feed pressures up to 1.7 MPa and temperatures up to 773 K. For one BZSM-5 membrane after silylation, the H2/CO{sub 2} separation selectivity at 473 K increased from 1.4 to 37, whereas the H{sub 2}/CH{sub 4} separation selectivity increased from 1.6 to 33. Hydrogen permeance through a silylated B-ZSM-5 membrane was activated, but the CO{sub 2} and CH4 permeances decreased slightly with temperature in both single gas and in mixtures. Therefore, the H{sub 2} permeance and H{sub 2}/CO{sub 2} and H{sup 2} /CH{sub 4} separation selectivities increased with temperature. At 673 K, the H2 permeance was 1.0x10-7 molxm-2xs-1xPa-1, and the H{sub 2}/CO{sub 2} separation selectivity was 47. Above 673 K, the silylated membrane catalyzed reverse water gas shift reaction and still separated H{sub 2} with high selectivity; and it was thermally stable. However, silylation decreased H{sub 2} permeance more than one order of magnitude. The H{sub 2} separation performance of the silylated B-ZSM-5 membranes depended on the initial membrane quality and acidity, as well as the silane precursors. Increasing the membrane feed pressure also increased the H{sub 2} flux and the H{sub 2} mole fraction in the permeate stream for both mixtures. Another approach used in this study is optimizing the synthesis of small-pore SAPO-34 (CHA) membranes and/or modifying SAPO-34 membranes by silylation or ion exchange. For SAPO-34 membranes, strong CO{sub 2} adsorption inhibited H{sub 2} adsorption and decreased H2 permeances, especially at low temperatures. At 253 K, CO{sub 2}/H{sub 2} separation selectivities of a SAPO-34 membrane were greater than 100 with CO{sub 2} permeances of about 3 x 10-8 mol m-2 s-1 Pa-1. The high reverse-selectivity of the SAPO-34 membranes can minimize H{sub 2} recompression because H{sub 2} remained in the retentate stream at a higher pressure. The CO{sub 2}/H{sub 2} separation selectivity exhibited a maximum with CO{sub 2} feed concentration possibly caused by a maximum in the CO{sub 2}/H{sub 2} sorption selectivity with increased CO{sub 2} partial pressure. The SAPO-34 membrane separated H{sub 2} from CH{sub 4} because CH{sub 4} is close to the SAPO-34 pore size so its diffusivity is much lower than the H{sup 2} diffusivity. The H{sub 2}/CH{sub 4} separation selectivity was almost independent of temperature, pressure, and feed composition. Silylation on SAPO-34 membranes increased H{sup 2}/CH{sub 4} and CO{sub 2}/CH{sub 4} selectivities but did not increase H{sub 2}/CO{sub 2} and H{sub 2}/N{sub 2} selectivities because silylation only blocked defects in SAPO-34 membranes. Hydr

Mei Hong; Richard D. Noble; John L. Falconer

2006-09-24T23:59:59.000Z

326

Highly Selective H2 Separation Zeolite Membranes for Coal Gasification Membrane Reactor Applications  

SciTech Connect (OSTI)

Zeolite membranes are thermally, chemically, and mechanically stable. They also have tunable molecular sieving and catalytic ability. These unique properties make zeolite membrane an excellent candidate for use in catalytic membrane reactor applications related to coal conversion and gasification, which need high temperature and high pressure range separation in chemically challenging environment where existing technologies are inefficient or unable to operate. Small pore, good quality, and thin zeolite membranes are needed for highly selective H2 separation from other light gases (CO2, CH4, CO). However, current zeolite membranes have either too big zeolite pores or a large number of defects and have not been successful for H2 separation from light gases. The objective of this study is to develop zeolite membranes that are more suitable for H2 separation. In an effort to tune the size of zeolite pores and/or to decrease the number of defects, medium-pore zeolite B-ZSM-5 (MFI) membranes were synthesized and silylated. Silylation on B-ZSM-5 crystals reduced MFI-zeolite pore volume, but had little effect on CO2 and CH4 adsorption. Silylation on B-ZSM-5 membranes increased H2 selectivity both in single component and in mixtures with CO2, CH4, or N2. Single gas and binary mixtures of H2/CO2 and H2/CH4 were permeated through silylated B-ZSM-5 membranes at feed pressures up to 1.7 MPa and temperatures up to 773 K. For one B-ZSM-5 membrane after silylation, the H2/CO2 separation selectivity at 473 K increased from 1.4 to 37, whereas the H2/CH4 separation selectivity increased from 1.6 to 33. Hydrogen permeance through a silylated BZSM-5 membrane was activated with activation energy of {approx}10 kJ/mol, but the CO2 and CH4 permeances decreased slightly with temperature in both single gas and in mixtures. Therefore, the H2 permeance and H2/CO2 and H2/CH4 separation selectivities increased with temperature. At 673 K, the H2 permeance was 1.0x10-7 mol{center_dot}m-2{center_dot}s-1{center_dot}Pa-1, and the H2/CO2 separation selectivity was 47. Above 673 K, the silylated membrane catalyzed reverse water gas shift reaction and still separated H2 with high selectivity; and it was thermally stable. However, silylation decreased H2 permeance more than one order of magnitude. Increasing the membrane feed pressure increased the H2 flux and the H2 mole fraction in the permeate stream for both H2/CO2 and H2/CH4 mixtures. The H2 separation performance of the silylated B-ZSM-5 membranes depended on the initial membrane quality and acidity, as well as the silane precursors. Another approach used in this study is optimizing the synthesis of small-pore SAPO-34 (CHA) membranes and/or modifying SAPO-34 membranes by silylation or ion exchange. For SAPO-34 membranes, strong CO2 adsorption inhibited H2 adsorption and decreased H2 permeances, especially at low temperatures. At 253 K, CO2/H2 separation selectivities of a SAPO-34 membrane were greater than 100 with CO2 permeances of about 3 x 10-8 mol{center_dot}m-2{center_dot}s-1{center_dot}Pa-1. The high reverse-selectivity of the SAPO-34 membranes can minimize H2 recompression because H2 remained in the retentate stream at a higher pressure. The CO2/H2 separation selectivity exhibited a maximum with CO2 feed concentration possibly caused by a maximum in the CO2/H2 sorption selectivity with increased CO2 partial pressure. The SAPO-34 membrane separated H2 from CH4 because CH4 is close to the SAPO-34 pore size so its diffusivity (ABSTRACT TRUNCATED)

Mei Hong; Richard Noble; John Falconer

2007-09-24T23:59:59.000Z

327

Techno-Economic Analysis of Scalable Coal-based Fuel Cells  

SciTech Connect (OSTI)

Researchers at The University of Akron (UA) have demonstrated the technical feasibility of a laboratory coal fuel cell that can economically convert high sulfur coal into electricity with near zero negative environmental impact. Scaling up this coal fuel cell technology to the megawatt scale for the nation’s electric power supply requires two key elements: (i) developing the manufacturing technology for the components of the coal-based fuel cell, and (ii) long term testing of a kW scale fuel cell pilot plant. This project was expected to develop a scalable coal fuel cell manufacturing process through testing, demonstrating the feasibility of building a large-scale coal fuel cell power plant. We have developed a reproducible tape casting technique for the mass production of the planner fuel cells. Low cost interconnect and cathode current collector material was identified and current collection was improved. In addition, this study has demonstrated that electrochemical oxidation of carbon can take place on the Ni anode surface and the CO and CO2 product produced can further react with carbon to initiate the secondary reactions. One important secondary reaction is the reaction of carbon with CO2 to produce CO. We found CO and carbon can be electrochemically oxidized simultaneously inside of the anode porous structure and on the surface of anode for producing electricity. Since CH4 produced from coal during high temperature injection of coal into the anode chamber can cause severe deactivation of Ni-anode, we have studied how CH4 can interact with CO2 to produce in the anode chamber. CO produced was found able to inhibit coking and allow the rate of anode deactivation to be decreased. An injection system was developed to inject the solid carbon and coal fuels without bringing air into the anode chamber. Five planner fuel cells connected in a series configuration and tested. Extensive studies on the planner fuels and stack revealed that the planner fuel cell stack is not suitable for operation with carbon and coal fuels due to lack of mechanical strength and difficulty in sealing. We have developed scalable processes for manufacturing of process for planner and tubular cells. Our studies suggested that tubular cell stack could be the only option for scaling up the coal-based fuel cell. Although the direct feeding of coal into fuel cell can significantly simplify the fuel cell system, the durability of the fuel cell needs to be further improved before scaling up. We are developing a tubular fuel cell stack with a coal injection and a CO2 recycling unit.

Chuang, Steven

2014-08-31T23:59:59.000Z

328

Heat removal from high temperature tubular solid oxide fuel cells utilizing product gas from coal gasifiers.  

SciTech Connect (OSTI)

In this work we describe the results of a computer study used to investigate the practicality of several heat exchanger configurations that could be used to extract heat from tubular solid oxide fuel cells (SOFCs) . Two SOFC feed gas compositions were used in this study. They represent product gases from two different coal gasifier designs from the Zero Emission Coal study at Los Alamos National Laboratory . Both plant designs rely on the efficient use of the heat produced by the SOFCs . Both feed streams are relatively rich in hydrogen with a very small hydrocarbon content . One feed stream has a significant carbon monoxide content with a bit less hydrogen . Since neither stream has a significant hydrocarbon content, the common use of the endothermic reforming reaction to reduce the process heat is not possible for these feed streams . The process, the method, the computer code, and the results are presented as well as a discussion of the pros and cons of each configuration for each process .

Parkinson, W. J. (William Jerry),

2003-01-01T23:59:59.000Z

329

Refinery Integration of By-Products from Coal-Derived Jet Fuels  

SciTech Connect (OSTI)

This report summarizes the accomplishments toward project goals during the first six months of the third year of the project to assess the properties and performance of coal based products. These products are in the gasoline, diesel and fuel oil range and result from coal based jet fuel production from an Air Force funded program. Specific areas of progress include generation of coal based material that has been fractionated into the desired refinery cuts, acquisition and installation of a research gasoline engine, and modification of diesel engines for use in evaluating diesel produced in the project. Characterization of the gasoline fuel indicates a dominance of single ring alkylcycloalkanes that have a low octane rating; however, blends containing these compounds do not have a negative effect upon gasoline when blended in refinery gasoline streams. Characterization of the diesel fuel indicates a dominance of 3-ring aromatics that have a low cetane value; however, these compounds do not have a negative effect upon diesel when blended in refinery diesel streams. The desulfurization of sulfur containing components of coal and petroleum is being studied so that effective conversion of blended coal and petroleum streams can be efficiently converted to useful refinery products. Equipment is now in place to begin fuel oil evaluations to assess the quality of coal based fuel oil. Combustion and characterization of fuel oil indicates that the fuel is somewhere in between a No. 4 and a No. 6 fuel oil. Emission testing indicates the fuel burns similarly to these two fuels, but trace metals for the coal-based material are different than petroleum-based fuel oils. Co-coking studies using cleaned coal are highly reproducible in the pilot-scale delayed coker. Evaluation of the coke by Alcoa, Inc. indicated that while the coke produced is of very good quality, the metals content of the carbon is still high in iron and silica. Coke is being evaluated for other possible uses. Methods to reduce metal content are being evaluated.

Caroline E. Burgess Clifford; Andre Boehman; Chunshan Song; Bruce Miller; Gareth Mitchell

2006-05-17T23:59:59.000Z

330

Phase-equilibria for design of coal-gasification processes: dew points of hot gases containing condensible tars. Final report  

SciTech Connect (OSTI)

This research is concerned with the fundamental physical chemistry and thermodynamics of condensation of tars (dew points) from the vapor phase at advanced temperatures and pressures. Fundamental quantitative understanding of dew points is important for rational design of heat exchangers to recover sensible heat from hot, tar-containing gases that are produced in coal gasification. This report includes essentially six contributions toward establishing the desired understanding: (1) Characterization of Coal Tars for Dew-Point Calculations; (2) Fugacity Coefficients for Dew-Point Calculations in Coal-Gasification Process Design; (3) Vapor Pressures of High-Molecular-Weight Hydrocarbons; (4) Estimation of Vapor Pressures of High-Boiling Fractions in Liquefied Fossil Fuels Containing Heteroatoms Nitrogen or Sulfur; and (5) Vapor Pressures of Heavy Liquid Hydrocarbons by a Group-Contribution Method.

Prausnitz, J.M.

1980-05-01T23:59:59.000Z

331

Formation and retention of methane in coal  

SciTech Connect (OSTI)

The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

Hucka, V.J.; Bodily, D.M.; Huang, H.

1992-05-15T23:59:59.000Z

332

Sulfur Tolerant Pd/Cu and Pd/Au Alloy Membranes for H2 Separation with High Pressure CO2 for Sequestration  

SciTech Connect (OSTI)

The effect of H{sub 2}S poisoning on Pd, Pd/Cu, and Pd/Au alloy composite membranes prepared by the electroless deposition method on porous Inconel supports was investigated to provide a fundamental understanding of the durability and preparation of sulfur tolerant membranes. X-ray photoelectron spectroscopy (XPS) studies showed that the exposure of pure Pd to 50 ppm H{sub 2}S/H{sub 2} mixtures caused bulk sulfide formation at lower temperatures and surface sulfide formation at higher temperatures. Lower temperatures, longer exposure times, and higher H{sub 2}S concentrations resulted in a higher degree of sulfidation. In a Pd membrane, the bulk sulfide formation caused a drastic irrecoverable H{sub 2} permeance decline and an irreparable loss in selectivity. Pd/Cu and Pd/Au alloy membranes exhibited permeance declines due to surface sulfide formation upon exposure to 50 ppm H{sub 2}S/H{sub 2} gas mixtures. However in contrast to the pure Pd membrane, the permeances of the Pd/Cu and Pd/Au alloy membranes were mostly recovered in pure H{sub 2} and the selectivity of the Pd alloy layers remained essentially intact throughout the characterization in H{sub 2}, He and H{sub 2}S/H{sub 2} mixtures which lasted several thousand hours. The amount of irreversible sulfur poisoning decreased with increasing temperature due to the exothermicity of H{sub 2}S adsorption. Longer exposure times increased the amount of irreversible poisoning of the Pd/Cu membrane but not the Pd/Au membrane. Pd/Au coupon studies of the galvanic displacement method showed that higher Au{sup 3+} concentrations, lower pH values, higher bath temperatures and stirring the bath at a rate of 200 rpm yielded faster displacement rates, more uniform depositions, and a higher Au content within the layers. While 400 C was found to be sufficient to form a Pd/Au alloy on the surface, high temperature X-ray diffraction (HTXRD) studies showed that even after annealing between 500-600 C, the Pd/Cu alloys could have part or all of the surface in the less sulfur resistant {beta} phase.

Yi Hua Ma; Natalie Pomerantz; Chao-Huang Chen

2008-09-30T23:59:59.000Z

333

Market effects of environmental regulation: coal, railroads, and the 1990 Clean Air Act  

SciTech Connect (OSTI)

Many environmental regulations encourage the use of 'clean' inputs. When the suppliers of such an input have market power, environmental regulation will affect not only the quantity of the input used but also its price. We investigate the effect of the Title IV emissions trading program for sulfur dioxide on the market for low-sulfur coal. We find that the two railroads transporting coal were able to price discriminate on the basis of environmental regulation and geographic location. Delivered prices rose for plants in the trading program relative to other plants, and by more at plants near a low-sulfur coal source.

Busse, M.R.; Keohane, N.O. [University of California Berkeley, Berkeley, CA (United States)

2007-01-01T23:59:59.000Z

334

Coal-fired high performance power generating system. Quarterly progress report, October 1, 1994--December 31, 1994  

SciTech Connect (OSTI)

This report covers work carried out under Task 3, Preliminary R and D, under contract DE-AC22-92PC91155, {open_quotes}Engineering Development of a Coal-Fired High Performance Power Generation System{close_quotes} between DOE Pittsburgh Energy Technology Center and United Technologies Research Center. The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) by the year 2000 that is capable of (1) > 47% thermal efficiency; (2) NO{sub x}, SO{sub x} and particulates {<=}25% NSPS; (3) cost {>=}65% of heat input; (4) all solid wastes benign. In our design consideration, we have tried to render all waste streams benign and if possible convert them to a commercial product. It appears that vitrified slag has commercial values. If the flyash is reinjected through the furnace, along with the dry bottom ash, then the amount of the less valuable solid waste stream (ash) can be minimized. A limitation on this procedure arises if it results in the buildup of toxic metal concentrations in either the slag, the flyash or other APCD components. We have assembled analytical tools to describe the progress of specific toxic metals in our system. The outline of the analytical procedure is presented in the first section of this report. The strengths and corrosion resistance of five candidate refractories have been studied in this quarter. Some of the results are presented and compared for selected preparation conditions (mixing, drying time and drying temperatures). A 100 hour pilot-scale stagging combustor test of the prototype radiant panel is being planned. Several potential refractory brick materials are under review and five will be selected for the first 100 hour test. The design of the prototype panel is presented along with some of the test requirements.

NONE

1995-08-01T23:59:59.000Z

335

Advanced byproduct recovery: Direct catalytic reduction of SO{sub 2} to elemental sulfur. First quarterly technical progress report, [October--December 1995  

SciTech Connect (OSTI)

The team of Arthur D. Little, Tufts University and Engelhard Corporation will be conducting Phase I of a four and a half year, two-phase effort to develop and scale-up an advanced byproduct recovery technology that is a direct, single-stage, catalytic process for converting sulfur dioxide to elemental sulfur. this catalytic process reduces SO{sub 2} over a fluorite-type oxide (such as ceria or zirconia). The catalytic activity can be significantly promoted by active transition metals, such as copper. More than 95% elemental sulfur yield, corresponding to almost complete sulfur dioxide conversion, was obtained over a Cu-Ce-O oxide catalyst as part of an ongoing DOE-sponsored University Coal Research Program. This type of mixed metal oxide catalyst has stable activity, high selectivity for sulfur production, and is resistant to water and carbon dioxide poisoning. Tests with CO and CH{sub 4} reducing gases indicates that the catalyst has the potential for flexibility with regard to the composition of the reducing gas, making it attractive for utility use. the performance of the catalyst is consistently good over a range of SO{sub 2} inlet concentration (0.1 to 10%) indicating its flexibility in treating SO{sub 2} tail gases as well as high concentration streams.

Benedek, K. [Little (Arthur D.), Inc., Cambridge, MA (United States); Flytzani-Stephanopoulos, M. [Tufts Univ., Medford, MA (United States)

1996-02-01T23:59:59.000Z

336

Amphiphilic Surface Modification of Hollow Carbon Nanofibers for Improved Cycle Life of Lithium Sulfur Batteries  

E-Print Network [OSTI]

lithium sulfur batteries, due to their high specific energy and relatively low cost. Despite recent progress in addressing the various problems of sulfur cathodes, lithium sulfur batteries still exhibit at C/2. KEYWORDS: Lithium sulfur batteries; energy storage; surface modification Increasing the energy

Cui, Yi

337

Low Temperature Sorbents for Removal of Sulfur Compounds from Fluid Feed Streams  

DOE Patents [OSTI]

A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

Siriwardane, Ranjani

2004-06-01T23:59:59.000Z

338

Low Temperature Sorbents for removal of Sulfur Compounds from fluid feed Streams  

SciTech Connect (OSTI)

A sorbent material is provided comprising a material reactive with sulfur, a binder unreactive with sulfur and an inert material, wherein the sorbent absorbs the sulfur at temperatures between 30 and 200 C. Sulfur absorption capacity as high as 22 weight percent has been observed with these materials.

Siriwardane, Ranjan

1999-09-30T23:59:59.000Z

339

Engineering development of coal-fired high performance power systems, Phase II and Phase III. Quarter progress report, April 1, 1996--June 30, 1996  

SciTech Connect (OSTI)

Work is presented on the development of a coal-fired high performance power generation system by the year 2000. This report describes the design of the air heater, duct heater, system controls, slag viscosity, and design of a quench zone.

NONE

1996-11-01T23:59:59.000Z

340

Removal of mercury from coal via a microbial pretreatment process  

SciTech Connect (OSTI)

A process for the removal of mercury from coal prior to combustion is disclosed. The process is based on use of microorganisms to oxidize iron, sulfur and other species binding mercury within the coal, followed by volatilization of mercury by the microorganisms. The microorganisms are from a class of iron and/or sulfur oxidizing bacteria. The process involves contacting coal with the bacteria in a batch or continuous manner. The mercury is first solubilized from the coal, followed by microbial reduction to elemental mercury, which is stripped off by sparging gas and captured by a mercury recovery unit, giving mercury-free coal. The mercury can be recovered in pure form from the sorbents via additional processing.

Borole, Abhijeet P. (Knoxville, TN); Hamilton, Choo Y. (Knoxville, TN)

2011-08-16T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Catalyst for elemental sulfur recovery process  

DOE Patents [OSTI]

A catalytic reduction process is described for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides high activity and selectivity, as well as stability in the reaction atmosphere, for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over a metal oxide composite catalyst having one of the following empirical formulas: [(FO[sub 2])[sub 1[minus]n](RO)[sub n

Flytzani-Stephanopoulos, M.; Liu, W.

1995-01-24T23:59:59.000Z

342

New developments in coal briquetting technology  

SciTech Connect (OSTI)

Briquetting of coal has been with us for well over a century. In the earliest applications of coal briquetting, less valuable fine coal was agglomerated into briquettes using a wide variety of binders, including coal tar, pitch and asphalt. Eventually, roll briquetters came into more widespread use, permitting the process to become a continuous one. Coal briquetting went out of favor during the 1950s in most of the industrialized world. The major reason for this decline in use was the discovery that the coal gas distillates used for binders were harmful to human health. Also, the abundance of cheap petroleum made coal briquettes a less attractive alternative as an industrial or domestic fuel. The re-emergence of coal as a primary industrial fuel and also its increased prominence as a fuel for thermal electric power stations led to a large increase in the annual volume of coal being mined worldwide. Coal preparation technology steadily improved over the years with the general exception of fine coal preparation. The processes available for treating this size range were considerably more expensive per unit mass of coal treated than coarse coal processes. Also, costly dewatering equipment was required after cleaning to remove surface moisture. Even with dewatering, the high surface area per unit mass of fine coal versus coarse coal resulted in high moisture contents. Therefore, little incentive existed to improve the performance of fine coal processes since this would only increase the amount of wet coal fines which would have to be dealt with. With such an ever-increasing volume of coal fines being created each year, there emerged an interest in recovering this valuable product. Several schemes were developed to recover coal fines discarded in abandoned tailings impoundments by previous operations.

Tucker, P.V. [Kilborn Inc., Ontario (Canada); Bosworth, G.B. [Kilborn Engineering Pacific Ltd., Vancouver, British Columbia (Canada); Kalb, G.W. [KKS Systems Inc., Wheeling, WV (United States)

1993-12-31T23:59:59.000Z

343

Low-rank coal oil agglomeration  

DOE Patents [OSTI]

A low-rank coal oil agglomeration process is described. High mineral content, a high ash content subbituminous coals are effectively agglomerated with a bridging oil which is partially water soluble and capable of entering the pore structure, and is usually coal-derived.

Knudson, C.L.; Timpe, R.C.

1991-07-16T23:59:59.000Z

344

Coal extraction  

SciTech Connect (OSTI)

Coal is extracted using a mixed solvent which includes a substantially aromatic component and a substantially naphthenic component, at a temperature of 400/sup 0/ to 500/sup 0/C. Although neither component is an especially good solvent for coal by itself, the use of mixed solvent gives greater flexibility to the process and offers efficiency gains.

Clarke, J.W.; Kimber, G.M.; Rantell, T.D.; Snape, C.E.

1985-06-04T23:59:59.000Z

345

Comparison of high-pressure CO2 sorption isotherms on Eastern and Western US coals  

SciTech Connect (OSTI)

Accurate estimation of carbon dioxide (CO2) sorption capacity of coal is important for planning the CO2 sequestration efforts. In this work, we investigated sorption and swelling behavior of several Eastern and Western US coal samples from the Central Appalachian Basin and from San Juan Basin. The CO2 sorption isotherms have been completed at 55°C for as received and dried samples. The role of mineral components in coal, the coal swelling, the effects of temperature and moisture, and the error propagation have been analyzed. Changes in void volume due to dewatering and other factors such as temporary caging of carbon dioxide molecules in coal matrix were identified among the main factors affecting accuracy of the carbon dioxide sorption isotherms. The (helium) void volume in the sample cells was measured before and after the sorption isotherm experiments and was used to build the volume-corrected data plots.

Romanov, V.; Hur, T.-B.; Fazio, J.; Howard, B

2012-10-01T23:59:59.000Z

346

Chemical composition and some trace element contents in coals and coal ash from Tamnava-Zapadno Polje Coal Field, Serbia  

SciTech Connect (OSTI)

The chemical compositions and trace element contents (Zn, Cu, Co, Cr, Ni, Pb, Cd, As, B, Hg, Sr, Se, Be, Ba, Mn, Th, V, U) in coal and coal ash samples from Tamnava-Zapadno Polje coal field in Serbia were studied. The coal from this field belongs to lignite. This high volatility coal has high moisture and low S contents, moderate ash yield, and high calorific value. The coal ash is abundant in alumosilicates. Many trace elements such as Ni > Cd > Cr > B > As > Cu > Co > Pb > V > Zn > Mn in the coal and Ni > Cr > As > B > Cu > Co = Pb > V > Zn > Mn in the coal ash are enriched in comparison with Clarke concentrations.

Vukasinovic-Pesic, V.; Rajakovic, L.J. [University of Montenegro, Podgorica (Montenegro)

2009-07-01T23:59:59.000Z

347

Conceptual design of a coal-fired MHD retrofit plant. Topical report, Seed Regeneration System Study 2  

SciTech Connect (OSTI)

Westinghouse Advanced Energy Systems (WAES), through Contract No. DE-AC22-87PC79668 funded by US DOE/PETC, is conducting a conceptual design study to evaluate a coal-fired magnetohydrodynamic (MHD) retrofit of a utility plant of sufficient size to demonstrate the technical and future economic viability of an MHD system operating within an electric utility environment. The objective of this topical report is to document continuing seed regeneration system application studies and the definition of will system integration requirements for the Scholz MHD retrofit plant design. MHD power plants require the addition of a seeding material in the form of potassium to enhance the ionization of the high temperature combustion gas in the MHD channel. This process has an added environmental advantage compared to other types of coal-fired power plants in that the potassium combines with the naturally occurring sulfur in the coal to form a potassium sulfate flyash (K{sub 2}SO{sub 4}) which can be removed from the process by appropriate particulate control equipment. Up to 100% of the Sulfur in the coal can be removed by this process thereby providing environmentally clean power plant operation that is better than required by present and anticipated future New Source Performance Standards (NSPS).

Not Available

1992-11-01T23:59:59.000Z

348

POC-SCALE TESTING OF A DRY TRIBOELECTROSTATIC SEPARATOR FOR FINE COAL CLEANING  

SciTech Connect (OSTI)

Numerous advanced coal cleaning processes have been developed in recent years that are capable of substantially reducing both ash- and sulfur-forming minerals from coal. However, most of the processes involve fine grinding and use water as the cleaning medium; therefore, the clean coal products must be dewatered before they can be transported and burned. Unfortunately, dewatering fine coal is costly, which makes it difficult to deploy advanced coal cleaning processes for commercial applications. As a means of avoiding problems associated with the fine coal dewatering, the National Energy Technology Laboratory (NETL) developed a dry coal cleaning process in which mineral matter is separated from coal without using water. In this process, pulverized coal is subjected to triboelectrification before being placed in an electric field for electrostatic separation. The triboelectrification is accomplished by passing a pulverized coal through an in-line mixer made of copper. Copper has a work function that lies between that of carbonaceous material (coal) and mineral matter. Thus, coal particles impinging on the copper wall lose electrons to the metal thereby acquiring positive charges, while mineral matter impinging on the wall gain electrons to acquire negative charges. The charged particles then pass through an electric field where they are separated according to their charges into two or more products depending on the configuration of the separator. The results obtained at NETL showed that it is capable of removing more than 90% of the pyritic sulfur and 70% of the ash-forming minerals from a number of eastern U.S. coals. However, the BTU recoveries were less than desirable. The laboratory-scale batch triboelectrostatic separator (TES) used by NETL relied on adhering charged particles on parallel electrode surfaces and scraping them off. Therefore, its throughput will be proportional to the electrode surface area. If this laboratory device is scaled-up as is, it would suffer from low throughput capacities and high maintenance requirements. In general, surface area-based separators (e.g., shaking tables, magnetic drum separator, electrodynamic separator, etc.) have lower throughput capacities than volume-based separators (e.g., flotation cell, dense-medium bath, cyclones, etc.) by an order of magnitude. Furthermore, the electrodes of the laboratory unit need to be cleaned frequently, creating a high maintenance requirement if it is scaled-up to a commercial unit. The bench-scale continuous TES unit developed at NETL, on the other hand, separates positively and negatively charged particles by splitting the gaseous stream containing these particles in an electric field by means of a flow splitter, so that the oppositely charged particles can be directed into different compartments. This device is fundamentally different from the laboratory unit in that the former is a surface area-based separator, while the latter is a volume-based separator. The bench-scale unit is referred to as an entrained flow separator by the in-house researchers at NETL. Thus, the entrained flow TES unit is a significant improvement over the laboratory unit with regard to throughput capacity. In the present work, the entrained flow separator concept will be utilized for developing a proof-of concept (POC) separator that can be scaled-up to commercial size units. To accomplish this, it is necessary to develop a bench-scale separator that can achieve high Btu recoveries while maintaining the high degree of separation efficiencies. It is the objective of the present investigation to develop an efficient separator by studying the mechanisms of triboelectrification and investigating better ways of separating the charged particles. An important criterion for developing efficient separators is that they not only provide high separation efficiencies but also have high throughput capacities, which are essential ingredients for successful commercialization.

R.H. Yoon; G.H. Luttrell; E.S. Yan; A.D. Walters

2001-04-30T23:59:59.000Z

349

High temperature regenerable hydrogen sulfide removal agents  

DOE Patents [OSTI]

A system for high temperature desulfurization of coal-derived gases using regenerable sorbents. One sorbent is stannic oxide (tin oxide, SnO.sub.2), the other sorbent is a metal oxide or mixed metal oxide such as zinc ferrite (ZnFe.sub.2 O.sub.4). Certain otherwise undesirable by-products, including hydrogen sulfide (H.sub.2 S) and sulfur dioxide (SO.sub.2) are reused by the system, and elemental sulfur is produced in the regeneration reaction. A system for refabricating the sorbent pellets is also described.

Copeland, Robert J. (Wheat Ridge, CO)

1993-01-01T23:59:59.000Z

350

U.S. zero emission coal alliance techology  

SciTech Connect (OSTI)

For coal to maintain its major role in supplying the world's energy, eventually all emissions to the atmosphere must be eliminated. Not only must conventional pollutants, like sulfur compounds and dust particles be kept out of the air, but also the far larger quantities of carbon dioxide that result from the combustion of carbon. We present a new technology for coal-based power that generates hydrogen from carbon and water, avoids emissions to the atmosphere, and disposes of the carbon dioxide as inert, solid mineral carbonates. Based on the available resources, coal power is sustainable for centuries. Our zero emission technology makes coal energy as clean as renewable energy.

Lackner, K. S. (Klaus S.); Ziock, H. J. (Hans-Joachim)

2001-01-01T23:59:59.000Z

351

Ultrasound-promoted chemical desulfurization of Illinois coals  

SciTech Connect (OSTI)

The overall objectives of the program were to investigate the use of ultrasound to promote coal desulfurization reactions and to evaluate chemical coal desulfurization schemes under mild conditions through a fundamental understanding of their reaction mechanisms and kinetics. The ultimate goal was to develop an economically feasible mild chemical process to reduce the total sulfur content of Illinois Basin Coals, while retaining their original physical characteristics, such as calorific value and volatile matter content. During the program, potential chemical reactions with coal were surveyed under various ultrasonic irradiation conditions for desulfurization, to formulate preliminary reaction pathways, and to select a few of the more promising chemical processes for more extensive study.

Chao, S.S.

1991-01-01T23:59:59.000Z

352

Engineering development of coal-fired high performance power systems, Phase 2 and 3. Quarterly progress report, October 1--December 31, 1995  

SciTech Connect (OSTI)

The goals of the program are to develop a coal-fired high performance power generation system (HIPPS) by the year 2000 that is capable of: >47% thermal efficiency (HHV); NO{sub x}, SO{sub x} and particulates {ge} 10% NSPS; coal {ge} 65% of heat input; all solid wastes benign; and cost of electricity 90% of present plant. The HIPPS generating plant integrates a combustion gas turbine/HRSG combined cycle arrangement with an advanced coal-fired boiler. The unique feature of the HIPPS plant is the partial heating of gas turbine (GT) compressor outlet air using energy released by firing coal in the high temperature advanced furnace (HITAF). The compressed air is additionally heated prior to entering the GT expander section by burning natural gas. Energy available, in the gas turbine exhaust and in the HITAF flue gas are used in a steam cycle to maximize energy production. The HIPPS plant arrangement is thus a combination of existing technologies (gas turbine, heat recovery boilers, conventional steam cycle) and new technologies (the HITAF design especially the heater located in the radiant section). Work reported herein is from Task 1.3, HIPPS Commercial Design and Task 2.2, HITAF Air Heaters.

NONE

1995-12-31T23:59:59.000Z

353

Degradation of solid oxide fuel cell metallic interconnects in fuels containing sulfur  

SciTech Connect (OSTI)

Hydrogen is the main fuel for all types of fuel cells except direct methanol fuel cells. Hydrogen can be generated from all manner of fossil fuels, including coal, natural gas, diesel, gasoline, other hydrocarbons, and oxygenates (e.g., methanol, ethanol, butanol, etc.). Impurities in the fuel can cause significant performance problems and sulfur, in particular, can decrease the cell performance of fuel cells, including solid oxide fuel cells (SOFC). In the SOFC, the high (800-1000°C) operating temperature yields advantages (e.g., internal fuel reforming) and disadvantages (e.g., material selection and degradation problems). Significant progress in reducing the operating temperature of the SOFC from ~1000 ºC to ~750 ºC may allow less expensive metallic materials to be used for interconnects and as balance of plant (BOP) materials. This paper provides insight on the material performance of nickel, ferritic steels, and nickel-based alloys in fuels containing sulfur, primarily in the form of H2S, and seeks to quantify the extent of possible degradation due to sulfur in the gas stream.

Ziomek-Moroz, M.; Hawk, Jeffrey A.

2005-01-01T23:59:59.000Z

354

Physico-chemical fracturing and cleaning of coal. [Treatment with CO/sub 2/ in water at high pressure  

DOE Patents [OSTI]

This invention relates to a method of producing a crushable coal and reducing the metallic values in coal represented by Si, Al, Ca, Na, K, and Mg, which comprises contacting a coal/water mix in a weight ratio of from about 4:1 to 1:6 in the presence of CO/sub 2/ at pressures of about 100 to 1400 psi and a minimum temperature of about 15/sup 0/C for a period of about one or more hours to produce a treated coal/water mix. In the process the treated coal/water mix has reduced values for Ca and Mg of up to 78% over the starting mix and the advantageous CO/sub 2/ concentration is in the range of about 3 to 30 g/L. Below 5 g/L CO/sub 2/ only small effects are observed and above 30 g/L no further special advantages are achieved. The coal/water ratios in the range 1:2 to 2:1 are particularly desirable and such ratios are compatible with coal water slurry applications.

Sapienza, R.S.; Slegeir, W.A.R.

1983-09-30T23:59:59.000Z

355

Bioconversion of coal-derived synthesis gas to liquid fuels. [Butyribacterium methylotrophicum  

SciTech Connect (OSTI)

The use of coal-derived synthesis gas as an industrial feedstock for production of fuels and chemicals has become an increasingly attractive alternative to present petroleum-based chemicals production. However, one of the major limitations in developing such a process is the required removal of catalyst poisons such as hydrogen sulfide (H{sub 2}S), carbonyl sulfide (COS), and other trace contaminants from the synthesis gas. Purification steps necessary to remove these are energy intensive and add significantly to the production cost, particularly for coals having a high sulfur content such as Illinois coal. A two-stage, anaerobic bioconversion process requiring little or no sulfur removal is proposed, where in the first stage the carbon monoxide (CO) gas is converted to butyric and acetic acids by the CO strain of Butyribacterium methylotrophicum. In the second stage, these acids along with the hydrogen (H{sub 2}) gas are converted to butanol, ethanol, and acetone by an acid utilizing mutant of Clostridium acetobutylicum. 18 figs., 18 tabs.

Jain, M.K.

1991-01-01T23:59:59.000Z

356

Low temperature pyrolysis of coal or oil shale in the presence of calcium compounds  

DOE Patents [OSTI]

A coal pyrolysis technique or process is described in which particulate coal is pyrolyzed in the presence of about 5 to 21 wt. % of a calcium compound selected from calcium oxide, calcined (hydrate) dolomite, or calcined calcium hydrate to produce a high quality hydrocarbon liquid and a combustible product gas which are characterized by low sulfur content. The pyrolysis is achieved by heating the coal-calcium compound mixture at a relatively slow rate at a temperature of about 450.degree. to 700.degree. C. over a duration of about 10 to 60 minutes in a fixed or moving bed reactor. The gas exhibits an increased yield in hydrogen and C.sub.1 -C.sub.8 hydrocarbons and a reduction in H.sub.2 S over gas obtainable by pyrolyzing cola without the calcium compound. The liquid product obtained is of a sufficient quality to permit its use directly as a fuel and has a reduced sulfur and oxygen content which inhibits polymerization during storage.

Khan, M. Rashid (Morgantown, WV)

1988-01-01T23:59:59.000Z

357

ENCOAL mild coal gasification project public design and construction report  

SciTech Connect (OSTI)

This Public Design Report describes the 1000 ton per day ENCOAL mild coal gasification demonstration plant now in operation at the Buckskin Mine near Gillette, Wyoming. The objective of the project is to demonstrate that the proprietary Liquids From Coal (LFC) technology can reliably and economically convert low Btu PRB coal into a superior, high-Btu solid fuel (PDF), and an environmentally attractive low-sulfur liquid fuel (CDL). The Project`s plans also call for the production of sufficient quantities of PDF and CDL to permit utility companies to carry out full scale burn tests. While some process as well as mechanical design was done in 1988, the continuous design effort was started in July 1990. Civil construction was started in October 1990; mechanical erection began in May 1991. Virtually all of the planned design work was completed by July 1991. Most major construction was complete by April 1992 followed by plant testing and commissioning. Plant operation began in late May 1992. This report covers both the detailed design and initial construction aspects of the Project.

NONE

1994-12-01T23:59:59.000Z

358

Corrosion and mechanical behavior of materials for coal gasification applications  

SciTech Connect (OSTI)

A state-of-the-art review is presented on the corrosion and mechanical behavior of materials at elevated temperatures in coal-gasification environments. The gas atmosphere in coal-conversion processes are, in general, complex mixtures which contain sulfur-bearing components (H/sub 2/S, SO/sub 2/, and COS) as well as oxidants (CO/sub 2//CO and H/sub 2/O/H/sub 2/). The information developed over the last five years clearly shows sulfidation to be the major mode of material degradation in these environments. The corrosion behavior of structural materials in complex gas environments is examined to evaluate the interrelationships between gas chemistry, alloy chemistry, temperature, and pressure. Thermodynamic aspects of high-temperature corrosion processes that pertain to coal conversion are discussed, and kinetic data are used to compare the behavior of different commercial materials of interest. The influence of complex gas environments on the mechanical properties such as tensile, stress-rupture, and impact on selected alloys is presented. The data have been analyzed, wherever possible, to examine the role of environment on the property variation. The results from ongoing programs on char effects on corrosion and on alloy protection via coatings, cladding, and weld overlay are presented. Areas of additional research with particular emphasis on the development of a better understanding of corrosion processes in complex environments and on alloy design for improved corrosion resistance are discussed. 54 references, 65 figures, 24 tables.

Natesan, K.

1980-05-01T23:59:59.000Z

359

The relationship between coal quality and coal resource parameters of Powder River and Williston Basin coal, Wyoming, Montana, and North Dakota  

SciTech Connect (OSTI)

Clean, compliant coal from mines in the Northern Rocky Mountain and Great Plains region is utilized as fuel for coal-fired power plants in 26 states. More than 30 percent of the nation`s 1997 production was from Montana, North Dakota, and Wyoming. Production of clean, compliant coal from the region is estimated to increase to 415 million short tons by the year 2015. Studies in this region indicate a relationship between percent sulfur and ash and pounds of SO{sub 2} per million Btu and the resource parameters of coal thickness and overburden. The trends that the authors have observed indicate that both coal quality and the thickness of the coal and associated rocks are controlled by paleoenvironment and depositional setting.

Ellis, M.S.; Stricker, G.D.; Gunther, G.; Ochs, A.M.; Flores, R.M.

1998-12-31T23:59:59.000Z

360

Coal industry annual 1994  

SciTech Connect (OSTI)

This report presents data on coal consumption, distribution, coal stocks, quality, prices, coal production information, and emissions for a wide audience.

NONE

1995-10-01T23:59:59.000Z

Note: This page contains sample records for the topic "high sulfur coal" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

The role of combustion diagnostics in coal quality impact and NO{sub x} emissions field test programs  

SciTech Connect (OSTI)

Many utilities are examining low sulfur coal or coal blending options to comply with the Clean Air Act Amendment SO{sub 2} emission limits. Test burns have been conducted with the more promising candidate coals to characterize the potential impact of a change in coal quality on boiler operation and performance. Utilities are also under considerable pressure to evaluate NO{sub x} control options and develop a compliance plan to meet strict NO{sub x} regulations, particularly in high population density metropolitan areas on the Eastern seaboard. Field test programs have been conducted to characterize baseline NO{sub x} emissions, evaluate the NO{sub x} reduction potential of combustion modifications, and assess the potential of combustion tuning as an alternative to burner replacement. Coal quality impacts (slagging, fouling, heat absorption, ash removal) and NO{sub x} emissions are both strongly dependent upon the coal combustion process and site-specific boiler firing practices. Non-uniform combustion in the burner region can result in adverse ash deposition characteristics, carbon carryover problems, high furnace exit gas temperatures, and NO{sub x}emission characteristics that are not representative of the coal or the combustion equipment. Advanced combustion diagnostic test procedures have been developed to evaluate and improve burner zone combustion uniformity, even in cases where the coal flow to the individual burners may be non-uniform. The paper outlines a very practical solving approach to identifying combustion related problems that affect ash deposition and NO{sub x} emissions. The benefits of using advanced diagnostic instrumentation to identify problems and tune combustion conditions is illustrated using test data from recent quality field test programs.

Thompson, R.E. [Fossil Energy Research Corp., Laguna Hills, CA (United States); Dyas, B. [New England Power Company, Westborough, MA (United States)

1995-03-01T23:59:59.000Z

362

Corrosion behavior of a high-chromium duplex stainless steel with minor additions of ruthenium in sulfuric acid  

SciTech Connect (OSTI)

The influence of small ruthenium additions on the corrosion behavior of high-chromium duplex stainless steels (DSS) was studied. Ruthenium additions ({le} 0.28%) increased the corrosion resistance of the base alloy by simultaneously improving hydrogen evolution efficiency and inhibiting anodic dissolution. The corrosion behavior of the high-chromium DSS with small ruthenium additions differed somewhat from behavior of similar duplex alloys of the 22%-Cr type. The lowering of hydrogen overpotential, which promotes an elevated corrosion potential leading to passivity, was much more significant in the 29%-Cr duplex alloys than in the 22%-Cr types.

Potgieter, J.H. [Pretoria Portland Cement, Johannesburg (South Africa). Technical Services Dept.; Brookes, H.C. [Univ. of Natal, Durban (South Africa). Dept. of Chemistry

1995-04-01T23:59:59.000Z

363

Low severity coal liquefaction promoted by cyclic olefins. Quarterly report, April--June 1992  

SciTech Connect (OSTI)

Low severity coal liquefaction allows for solubilization of coal with reduced gas make. These lower severity conditions may result in some selective bond rupture. Promotion of coal solubilization through hydrogen transfer using highly active and effective hydrogen donors is the objective of this study. The highly effective donors being tested are cyclic olefins. Representative cyclic olefins are isotetralin, which is 1,4,5,8-tetrahydronaphthalene, and 1,4,5,8,9,10-hexahydroanthracene. These compounds are hydroaromatics without aromatic rings and have been shown to be highly effective donors. The objective of the work performed in this study during this quarter was to evaluate reaction parameters for low severity liquefaction reactions using the cyclic olefin, hexahydroanthracene, and the aromatic, anthracene. These model compounds were reacted under a variety of conditions to evaluate their reactivity without coal. The reactions were performed under both thermal and catalytic conditions. Finely divided catalysts from different molybdenum precursors were used to determine their activity in promoting hydrogenation and hydrogen transfer at low severity conditions. The catalysts used were Molyvan L, sulfurized oxymolybdenum dithiocarbamate, molybdenum naphthenate, and Molyvan 822, organo molybdenum dithiocarbamate.

Curtis, C.W.

1992-07-27T23:59:59.000Z

364

Sulfur Dioxide Regulations (Ohio)  

Broader source: Energy.gov [DOE]

This chapter of the law establishes that the Ohio Environmental Protection Agency provides sulfur dioxide emission limits for every county, as well as regulations for the emission, monitoring and...

365

The changing structure of the US coal industry: An update, July 1993  

SciTech Connect (OSTI)

Section 205(a)(2) of the Department of Energy Organization Act of 1977 requires the Administrator of the Energy Information Administration (EIA) to carry out a central, comprehensive, and unified energy data and information program that will collect, evaluate, assemble, analyze, and disseminate data and information relevant to energy resources, reserves, production, demand, technology, and related economic and statistical information. The purpose of this report is to provide a comprehensive overview of changes in the structure of the US coal industry between 1976 and 1991. The structural elements examined include the number of mines, average mine size, the size distribution of mines, and the size distribution of coal firms. The report measures changes in the market shares of the largest coal producers at the national level and in various regions. The Central Appalachian low-sulfur coal market is given special attention, and the market for coal reserves is examined. A history of mergers in the coal industry is presented, and changes in the proportions of US coal output that are produced by various types of companies, including foreign-controlled firms, are described. Finally, the impact of post-1991 mergers on the structure of the industry is estimated. The legislation that created the EIA vested the organization with an element of statutory independence. The EIA does not take positions on policy questions. The EIA`s responsibility is to provide timely, high-quality information and to perform objective, credible analyses in support of deliberations by both public and private decisionmakers. Accordingly, this report does not purport to represent the policy positions of the US Department of Energy or the Administration.

Not Available

1993-07-29T23:59:59.000Z

366

Development and testing of a high efficiency advanced coal combustor phase III industrial boiler retrofit. Quarterly technical progress report No. 9, 1 October 1993--31 December 1993  

SciTech Connect (OSTI)

This report documents the technical aspects of this project during the ninth quarter of the program. During this quarter, the natural gas baseline testing at the Penn State demonstration boiler was completed, results were analyzed and are presented here. The burner operates in a stable manner over an 8/1 turndown, however due to baghouse temperature limitations (300{degrees}F for acid dewpoint), the burner is not operated for long periods of time below 75% load. Boiler efficiency averaged 83.1% at the 100 percent load rate while increasing to 83.7% at 75% load. NO{sub x} emissions ranged from a low of 0.17 Lbs/MBtu to a high of 0.24 Lbs/MBtu. After the baseline natural gas testing was completed, work continued on hardware optimization and testing with the goal of increasing carbon conversion efficiency on 100% coal firing from {approx}95% to 98%. Several coal handling and feeding problems were encountered during this quarter and no long term testing was conducted. While resolving these problems several shorter term (less than 6 hour) tests were conducted. These included, 100% coal firing tests, 100% natural gas firing tests, testing of air sparges on coal to simulate more primary air and a series of cofiring tests. For 100% coal firing, the carbon conversion efficiency (CCE) obtained this quarter did not exceed the 95-96% barrier previously reached. NO{sub x} emissions on coal only ranged from {approx} 0.42 to {approx} 0.78 Lbs/MBtu. The burner has not been optimized for low NO{sub x} yet, however, due to the short furnace residence time, meeting the goals of 98% CCE and <0.6 Lbs/MBtu NO{sub x} simultaneously will be difficult. Testing on 100% natural gas in the boiler after coal firing indicated no changes in efficiency due to firing in a `dirty` boiler. The co-firing tests showed that increased levels of natural gas firing proportionately decreased NO{sub x}, SO{sub 2}, and CO.

Jennings, P.; Borio, R. [ABB/Combustion Engineering, Windsor, CT (United States); Scaroni, A.W.; Miller, B.G. [Penn State Univ., University Park, PA (United States); McGowan, J.G. [Univ. of Massachusetts, Amherst, MA (United States)

1994-03-01T23:59:59.000Z

367

CO-FIRING COAL: FEEDLOT AND LITTER BIOMASS (CFB AND CLB) FUELS IN PULVERIZED FUEL AND FIXED BED BURNERS  

SciTech Connect (OSTI)

Intensive animal feeding operations create large amounts of animal waste that must be safely disposed of in order to avoid environmental degradation. Cattle feedlots and chicken houses are two examples. In feedlots, cattle are confined to small pens and fed a high calorie grain-diet diet in preparation for slaughter. In chicken houses, thousands of chickens are kept in close proximity. In both of these operations, millions of tons of manure are produced every year. The manure could be used as a fuel by mixing it with coal in a 90:10 blend and firing it in an existing coal suspension fired combustion systems. This technique is known as co-firing, and the high temperatures produced by the coal will allow the biomass to be completely combusted. Reburn is a process where a small percentage of fuel called reburn fuel is injected above the NO{sub x} producing, conventional coal fired burners in order to reduce NO{sub x}. The manure could also be used as reburn fuel for reducing NO{sub x} in coal fired plants. An alternate approach of using animal waste is to adopt the gasification process using a fixed bed gasifier and then use the gases for firing in gas turbine combustors. In this report, the cattle manure is referred to as feedlot biomass (FB) and chicken manure as litter biomass (LB). The report generates data on FB and LB fuel characteristics. Co-firing, reburn, and gasification tests of coal, FB, LB, coal: FB blends, and coal: LB blends and modeling on cofiring, reburn systems and economics of use of FB and LB have also been conducted. The biomass fuels are higher in ash, lower in heat content, higher in moisture, and higher in nitrogen and sulfur (which can cause air pollution) compared to coal. Small-scale cofiring experiments revealed that the biomass blends can be successfully fired, and NO{sub x} emissions will be similar to or lower than pollutant emissions when firing coal. Further experiments showed that biomass is twice or more effective than coal when used in a reburning process. Computer simulations for coal: LB blends were performed by modifying an existing computer code to include the drying and phosphorus (P) oxidation models. The gasification studies revealed that there is bed agglomeration in the case of chicken litter biomass due to its higher alkaline oxide content in the ash. Finally, the results of the economic analysis show that considerable fuel cost savings can be achieved with the use of biomass. In the case of higher ash and moisture biomass, the fuel cost savings is reduced.

Kalyan Annamalai; John Sweeten; Saqib Mukhtar; Ben Thein; Gengsheng Wei; Soyuz Priyadarsan; Senthil Arumugam; Kevin Heflin

2003-08-28T23:59:59.000Z

368

Advanced Byproduct Recovery: Direct Catalytic Reduction of Sulfur Dioxide to Elemental Sulfur.  

SciTech Connect (OSTI)

More than 170 wet scrubber systems applied, to 72,000 MW of U.S., coal-fired, utility boilers are in operation or under construction. In these systems, the sulfur dioxide removed from the boiler flue gas is permanently bound to a sorbent material, such as lime or limestone. The sulfated sorbent must be disposed of as a waste product or, in some cases, sold as a byproduct (e.g. gypsum). Due to the abundance and low cost of naturally occurring gypsum, and the costs associated with producing an industrial quality product, less than 7% of these scrubbers are configured to produce usable gypsum (and only 1% of all units actually sell the byproduct). The disposal of solid waste from each of these scrubbers requires a landfill area of approximately 200 to 400 acres. In the U.S., a total of 19 million tons of disposable FGD byproduct are produced, transported and disposed of in landfills annually. The use of regenerable sorbent technologies has the potential to reduce or eliminate solid waste production, transportation and disposal. In a regenerable sorbent system, the sulfur dioxide in the boiler flue gas is removed by the sorbent in an adsorber. The S0{sub 2}s subsequently released, in higher concentration, in a regenerator. All regenerable systems produce an off-gas stream from the regenerator that must be processed further in order to obtain a salable byproduct, such as elemental sulfur, sulfuric acid or liquid S0{sub 2}.

NONE

1997-06-01T23:59:59.000Z

369

Analysis of liquified coal for nitrogenous bases; separation by high performance liquid chromatography and identification by probe microdistillation/mass spectrometry  

E-Print Network [OSTI]

ANALYSIS OF LIQUIFIED COAL FOR NITROGENOUS BASES; SEPARATION BY HIGH PERFORMANCE LIQUID CHROMATOGRAPHY AND IDENTIFICATION BY PROBE MICRODISTILLATION/MASS SPECTROMETRY A Thesis by LEONARD ROYCE SCHRONK Submitted to the Graduate College... AND IDENTIFICATION BY PROBE MICRODISTILLATION/MASS SPECTROMETRY A Thesis by LEONARD ROYCE SCHRONK Approved as to style and content by: Co-Charrman o Commlxtte ) (Co-Chazrman o Committee Me er Hea of Department December 1978 ABSTRACT Analysis of Liquified...

Schronk, Leonard Royce

1978-01-01T23:59:59.000Z

370

Low-rank coal research. Quarterly report, January--March 1990  

SciTech Connect (OSTI)

This document contains several quarterly progress reports for low-rank coal research that was performed from January-March 1990. Reports in Control Technology and Coal Preparation Research are in Flue Gas Cleanup, Waste Management, and Regional Energy Policy Program for the Northern Great Plains. Reports in Advanced Research and Technology Development are presented in Turbine Combustion Phenomena, Combustion Inorganic Transformation (two sections), Liquefaction Reactivity of Low-Rank Coals, Gasification Ash and Slag Characterization, and Coal Science. Reports in Combustion Research cover Fluidized-Bed Combustion, Beneficiation of Low-Rank Coals, Combustion Characterization of Low-Rank Coal Fuels, Diesel Utilization of Low-Rank Coals, and Produce and Characterize HWD (hot-water drying) Fuels for Heat Engine Applications. Liquefaction Research is reported in Low-Rank Coal Direct Liquefaction. Gasification Research progress is discussed for Production of Hydrogen and By-Products from Coal and for Chemistry of Sulfur Removal in Mild Gas.

Not Available

1990-08-01T23:59:59.000Z

371

Integrated coal cleaning, liquefaction, and gasification process  

DOE Patents [OSTI]

Coal is finely ground and cleaned so as to preferentially remove denser ash-containing particles along with some coal. The resulting cleaned coal portion having reduced ash content is then fed to a coal hydrogenation system for the production of desirable hydrocarbon gases and liquid products. The remaining ash-enriched coal portion is gasified to produce a synthesis gas, the ash is removed from the gasifier usually as slag, and the synthesis gas is shift converted with steam and purified to produce the high purity hydrogen needed in the coal hydrogenation system. This overall process increases the utilization of as-mined coal, reduces the problems associated with ash in the liquefaction-hydrogenation system, and permits a desirable simplification of a liquids-solids separation step otherwise required in the coal hydrogenation system.

Chervenak, Michael C. (Pennington, NJ)

1980-01-01T23:59:59.000Z

372

Western Canadian coking coals -- Thermal rheology and coking quality  

SciTech Connect (OSTI)

Methods of predicting coke strength developed from the thermal rheological properties of Carboniferous coals frequently indicate that Cretaceous coals would not make high quality coke -- yet both types of coals produce coke suitable for the iron blast furnace. This paper will discuss the reasons why Western Canadian coals exhibit lower rheological values and how to predict the strength of coke produced from them.

Leeder, W.R. [Teck Corp. (Canada); Price, J.T.; Gransden, J.F. [CANMET Energy Technology Centre, Ottawa, Ontario (Canada)

1997-12-31T23:59:59.000Z

373

Method for increasing steam decomposition in a coal gasification process  

DOE Patents [OSTI]

The gasification of coal in the presence of steam and oxygen is significantly enhanced by introducing a thermochemical water-splitting agent such as sulfuric acid, into the gasifier for decomposing the steam to provide additional oxygen and hydrogen usable in the gasification process for the combustion of the coal and enrichment of the gaseous gasification products. The addition of the water-splitting agent into the gasifier also allows for the operation of the reactor at a lower temperature.

Wilson, Marvin W. (Fairview, WV)

1988-01-01T23:59:59.000Z

374

Method for increasing steam decomposition in a coal gasification process  

DOE Patents [OSTI]

The gasification of coal in the presence of steam and oxygen is significantly enhanced by introducing a thermochemical water- splitting agent such as sulfuric acid, into the gasifier for decomposing the steam to provide additional oxygen and hydrogen usable in the gasification process for the combustion of the coal and enrichment of the gaseous gasification products. The addition of the water-splitting agent into the gasifier also allows for the operation of the reactor at a lower temperature.

Wilson, M.W.

1987-03-23T23:59:59.000Z

375

Production of High Quality Dust Control Foam to Minimize Moisture Addition to Coal  

E-Print Network [OSTI]

of their suitability. Seven foam generators were evaluated: two were packed columns of honeycomb, two were static mixers with different mixing media, one was a tube containing a concentric fritted air pipe, and two were low- and high-pressure venturi mi xers.... The air and solution have a common inlet to the packed column and static mixer type foamers. The air for the venturi foamers is added to the turbulent solution after the venturi throat. The mixing in the tube foamer is achieved by blowing air through...

Termine, F.; Jordan, S. T.

376

Pyrolysis of coal  

DOE Patents [OSTI]

A method for mild gasification of crushed coal in a single vertical elongated reaction vessel providing a fluidized bed reaction zone, a freeboard reaction zone, and an entrained reaction zone within the single vessel. Feed coal and gas may be fed separately to each of these reaction zones to provide different reaction temperatures and conditions in each reaction zone. The reactor and process of this invention provides for the complete utilization of a coal supply for gasification including utilization of caking and non-caking or agglomerating feeds in the same reactor. The products may be adjusted to provide significantly greater product economic value, especially with respect to desired production of char having high surface area.

Babu, Suresh P. (Willow Springs, IL); Bair, Wilford G. (Morton Grove, IL)

1992-01-01T23:59:59.000Z

377

Manganese-based sorbents for coal gas desulfurization  

SciTech Connect (OSTI)

The intent of this study is to perform a preliminary screening on a particular Mn-based sorbent, CST-939 (from Chemetals), for hot gas desulfurization. The purpose of the preliminary screening is to determine which temperature and type of coal gas this sorbent demonstrates the greatest capacity and efficiency for sulfur removal. The following conclusions were made from the data collected on the CST-939 sorbent: The sorbent efficiency and capacity are much greater at 343{degrees}C (650{degrees}F) than at 871{degrees}C (1,600{degrees}F). The sorbent efficiency and capacity are much greater in the presence of the more highly-reducing Shell gas than with the less-reducing KRW gas. The sorbent showed tremendous capacity for sulfur pickup, with actual loadings as high as 21 weight percent. Oxidative regeneration at 871{degrees}C (1,600{degrees}F) appeared to decompose sulfate; however, unusually high SO{sub 2} release during the second sulfidations and/or reductive regenerations indicated incomplete regeneration. The average crush strength of the reacted sorbent did not indicate any loss of strength as compared to the fresh sorbent. Superior sorbent performance was obtained in the presence of simulated Shell gas at 538{degrees}C (1,000{degrees}F).

Gasper-Galvin, L.D.; Fisher, E.P. [USDOE Morgantown Energy Technology Center, WV (United States); Goyette, W.J. [Chemetals, Inc., Baltimore, MD (United States)

1996-12-31T23:59:59.000Z

378

China's Coal: Demand, Constraints, and Externalities  

SciTech Connect (OSTI)

This study analyzes China's coal industry by focusing on four related areas. First, data are reviewed to identify the major drivers of historical and future coal demand. Second, resource constraints and transport bottlenecks are analyzed to evaluate demand and growth scenarios. The third area assesses the physical requirements of substituting coal demand growth with other primary energy forms. Finally, the study examines the carbon- and environmental implications of China's past and future coal consumption. There are three sections that address these areas by identifying particular characteristics of China's coal industry, quantifying factors driving demand, and analyzing supply scenarios: (1) reviews the range of Chinese and international estimates of remaining coal reserves and resources as well as key characteristics of China's coal industry including historical production, resource requirements, and prices; (2) quantifies the largest drivers of coal usage to produce a bottom-up reference projection of 2025 coal demand; and (3) analyzes coal supply constraints, substitution options, and environmental externalities. Finally, the last section presents conclusions on the role of coal in China's ongoing energy and economic development. China has been, is, and will continue to be a coal-powered economy. In 2007 Chinese coal production contained more energy than total Middle Eastern oil production. The rapid growth of coal demand after 2001 created supply strains and bottlenecks that raise questions about sustainability. Urbanization, heavy industrial growth, and increasing per-capita income are the primary interrelated drivers of rising coal usage. In 2007, the power sector, iron and steel, and cement production accounted for 66% of coal consumption. Power generation is becoming more efficient, but even extensive roll-out of the highest efficiency units would save only 14% of projected 2025 coal demand for the power sector. A new wedge of future coal consumption is likely to come from the burgeoning coal-liquefaction and chemicals industries. If coal to chemicals capacity reaches 70 million tonnes and coal-to-liquids capacity reaches 60 million tonnes, coal feedstock requirements would add an additional 450 million tonnes by 2025. Even with more efficient growth among these drivers, China's annual coal demand is expected to reach 3.9 to 4.3 billion tonnes by 2025. Central government support for nuclear and renewable energy has not reversed China's growing dependence on coal for primary energy. Substitution is a matter of scale: offsetting one year of recent coal demand growth of 200 million tonnes would require 107 billion cubic meters of natural gas (compared to 2007 growth of 13 BCM), 48 GW of nuclear (compared to 2007 growth of 2 GW), or 86 GW of hydropower capacity (compared to 2007 growth of 16 GW). Ongoing dependence on coal reduces China's ability to mitigate carbon dioxide emissions growth. If coal demand remains on a high growth path, carbon dioxide emissions from coal combustion alone would exceed total US energy-related carbon emissions by 2010. Within China's coal-dominated energy system, domestic transportation has emerged as the largest bottleneck for coal industry growth and is likely to remain a constraint to further expansion. China has a low proportion of high-quality reserves, but is producing its best coal first. Declining quality will further strain production and transport capacity. Furthermore, transporting coal to users has overloaded the train system and dramatically increased truck use, raising transportation oil demand. Growing international imports have helped to offset domestic transport bottlenecks. In the long term, import demand is likely to exceed 200 million tonnes by 2025, significantly impacting regional markets.

Aden, Nathaniel; Fridley, David; Zheng, Nina

2009-07-01T23:59:59.000Z

379

The magnetohydrodynamics Coal-Fired Flow Facility. Technical progress report, April 1, 1992--June 30, 1992  

SciTech Connect (OSTI)

In this Quarterly Technical Progress Report, UTSI reports on a continuing proof-of-concept (POC) test program for the steam bottoming plant of an MHD/steam combined cycle power plant. In this report, the first POC test on western, low sulfur coal is reported. Analyses of tube materials from the previously completed 2004 hour POC tests on eastern, high sulfur coal are also included. The first test results with the wet electrostatic precipitator (ESP), which was installed to replace the wet venturi scrubber are reported. Detailed results of testing ceramic tubes and test components under a variety of high temperature conditions, for application to a high temperature air heater are included. Progress in application of advanced diagnostics equipment by both UTSI and Mississippi State University (MSU) is summarized. In addition, the laboratory effort to measure the transmissivity and absorption coefficient of the gas in the temperature range of condensing slag and potassium compounds is described. The current status of the CFFF environmental program is summarized.

Not Available

1993-02-01T23:59:59.000Z

380

Molybdenum-based additives to mixed-metal oxides for use in hot gas cleanup sorbents for the catalytic decomposition of ammonia in coal gases  

DOE Patents [OSTI]

This invention relates to additives to mixed-metal oxides that act simultaneously as sorbents and catalysts in cleanup systems for hot coal gases. Such additives of this type, generally, act as a sorbent to remove sulfur from the coal gases while substantially simultaneously, catalytically decomposing appreciable amounts of ammonia from the coal gases.

Ayala, Raul E. (Clifton Park, NY)

1993-01-01T23:59:59.000Z