National Library of Energy BETA

Sample records for high octane rating

  1. High Octane Fuels Can Make Better Use of Renewable Transportation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Octane Fuels Can Make Better Use of Renewable Transportation Fuels High Octane Fuels Can Make Better Use of Renewable Transportation Fuels Breakout Session 1C-Fostering Technology ...

  2. Method for determining the octane rating of gasoline samples by observing corresponding acoustic resonances therein

    DOE Patents [OSTI]

    Sinha, D.N.; Anthony, B.W.

    1997-02-25

    A method is described for determining the octane rating of gasoline samples by observing corresponding acoustic resonances therein. A direct correlation between the octane rating of gasoline and the frequency of corresponding acoustic resonances therein has been experimentally observed. Therefore, the octane rating of a gasoline sample can be directly determined through speed of sound measurements instead of by the cumbersome process of quantifying the knocking quality of the gasoline. Various receptacle geometries and construction materials may be employed. Moreover, it is anticipated that the measurements can be performed on flowing samples in pipes, thereby rendering the present method useful in refineries and distilleries. 3 figs.

  3. Method for determining the octane rating of gasoline samples by observing corresponding acoustic resonances therein

    DOE Patents [OSTI]

    Sinha, Dipen N.; Anthony, Brian W.

    1997-01-01

    A method for determining the octane rating of gasoline samples by observing corresponding acoustic resonances therein. A direct correlation between the octane rating of gasoline and the frequency of corresponding acoustic resonances therein has been experimentally observed. Therefore, the octane rating of a gasoline sample can be directly determined through speed of sound measurements instead of by the cumbersome process of quantifying the knocking quality of the gasoline. Various receptacle geometries and construction materials may be employed. Moreover, it is anticipated that the measurements can be performed on flowing samples in pipes, thereby rendering the present method useful in refineries and distilleries.

  4. High-Octane Mid-Level Ethanol Blend Market Assessment

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    High-Octane Mid-Level Ethanol Blend Market Assessment Caley Johnson, Emily Newes, Aaron Brooker, and Robert McCormick National Renewable Energy Laboratory Steve Peterson Lexidyne, LLC Paul Leiby, Rocio Uria Martinez, and Gbadebo Oladosu Oak Ridge National Laboratory Maxwell L. Brown Colorado School of Mines Technical Report NREL/TP-5400-63698 December 2015 NREL is a national laboratory of the U.S. Department of Energy Office of Energy Efficiency & Renewable Energy Operated by the Alliance

  5. High-Octane Fuel from Refinery Exhaust Gas: Upgrading Refinery Off-Gas to High-Octane Alkylate

    SciTech Connect (OSTI)

    2009-12-01

    Broad Funding Opportunity Announcement Project: Exelus is developing a method to convert olefins from oil refinery exhaust gas into alkylate, a clean-burning, high-octane component of gasoline. Traditionally, olefins must be separated from exhaust before they can be converted into another source of useful fuel. Exelus’ process uses catalysts that convert the olefin to alkylate without first separating it from the exhaust. The ability to turn up to 50% of exhaust directly into gasoline blends could result in an additional 46 million gallons of gasoline in the U.S. each year.

  6. High Octane Fuels Can Make Better Use of Renewable Transportation Fuels

    Broader source: Energy.gov [DOE]

    Breakout Session 1C—Fostering Technology Adoption I: Building the Market for Renewables with High Octane Fuels High Octane Fuels Can Make Better Use of Renewable Transportation Fuels Brian West, Deputy Director, Engines and Emissions Research Center; Oak Ridge National Laboratory

  7. High octane ethers from synthesis gas-derived alcohol

    SciTech Connect (OSTI)

    Klier, K.; Herman, R.G.; Bastian, R.D.; DeTavernier, S. . Dept. of Chemistry Lehigh Univ., Bethlehem, PA . Zettlemoyer Center for Surface Studies)

    1991-01-01

    The objective of the proposed research is to synthesize high octane ethers directly from coal-derived synthesis gas via alcohol mixtures that are rich in methanol and isobutanol. The overall scheme involves gasification of coal, purification and shifting of the synthesis gas, higher alcohol synthesis, and direct synthesis of ethers. Commercial acid and superacid resin catalysts were obtained and tested under one set of conditions to compare the activities and selectivities for forming the unsymmetric methylisobutylether (MIBE) by coupling methanol with isobutanol. It was found that both Nafion-H microsaddles and Amberlyst-15 resins are active for this synthesis reaction. While and the Nafion-H catalyst does form the MIBE product fairly selectively under the reaction conditions utilized, the Amberlyst-15 catalyst formed dimethylether (DME) as the major product. In addition, significantly larger quantities of the C{sub 4} hydrocarbon products were observed over the Amberlyst-15 catalyst at 123{degree}C and 13.6 atm. It has been demonstrated that methyltertiarybutylether (MTBE) MIBE, DME and diisobutylether (DIBE) are separated and quantitatively determined by using the proper analytical conditions. In order to gain insight into the role of superacidity in promoting the selective coupling of the alcohols to form the unsymmetric ether, the strengths of the acid sites on the catalysts are being probed by thermometric titrations in non-aqueous solutions. 18 refs., 20 figs., 4 tabs.

  8. Effects of High Octane Ethanol Blends on Four Legacy Flex-Fuel Vehicles, and a Turbocharged GDI Vehicle

    SciTech Connect (OSTI)

    Thomas, John F; West, Brian H; Huff, Shean P

    2015-03-01

    The U.S. Department of Energy (DOE) is supporting engine and vehicle research to investigate the potential of high-octane fuels to improve fuel economy. Ethanol has very high research octane number (RON) and heat of vaporization (HoV), properties that make it an excellent spark ignition engine fuel. The prospects of increasing both the ethanol content and the octane number of the gasoline pool has the potential to enable improved fuel economy in future vehicles with downsized, downsped engines. This report describes a small study to explore the potential performance benefits of high octane ethanol blends in the legacy fleet. There are over 17 million flex-fuel vehicles (FFVs) on the road today in the United States, vehicles capable of using any fuel from E0 to E85. If a future high-octane blend for dedicated vehicles is on the horizon, the nation is faced with the classic chicken-and-egg dilemma. If today’s FFVs can see a performance advantage with a high octane ethanol blend such as E25 or E30, then perhaps consumer demand for this fuel can serve as a bridge to future dedicated vehicles. Experiments were performed with four FFVs using a 10% ethanol fuel (E10) with 88 pump octane, and a market gasoline blended with ethanol to make a 30% by volume ethanol fuel (E30) with 94 pump octane. The research octane numbers were 92.4 for the E10 fuel and 100.7 for the E30 fuel. Two vehicles had gasoline direct injected (GDI) engines, and two featured port fuel injection (PFI). Significant wide open throttle (WOT) performance improvements were measured for three of the four FFVs, with one vehicle showing no change. Additionally, a conventional (non-FFV) vehicle with a small turbocharged direct-injected engine was tested with a regular grade of gasoline with no ethanol (E0) and a splash blend of this same fuel with 15% ethanol by volume (E15). RON was increased from 90.7 for the E0 to 97.8 for the E15 blend. Significant wide open throttle and thermal efficiency performance

  9. A Vehicle Manufacturer's Perspective on Higher-Octane Fuels

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Vehicle Manufacturer's Perspective on Higher-Octane Fuels Tom Leone, Ford Motor Company DOE "Biomass 2014" meeting Washington, D.C. July 29, 2014 2 Octane rating of fuel The octane ...

  10. Process for producing gasoline of high octane number and particularly lead free gasoline, from olefininc c3-c4 cuts

    SciTech Connect (OSTI)

    Hellin, M.; Juguin, B.; Torck, B.; Vu, Q. D.

    1981-05-19

    Lead free gasoline of high octane number is obtained from C/sub 3/ and C/sub 4/ olefinic cuts as follows: propylene contained in the C/sub 3/ cut is oligomerized, at least 80% of the isobutene and less than 40% of the n-butenes of the C/sub 4/ cut are oligomerized to form an oligomerizate distilling in the gasoline range, which is separated from the unreacted C/sub 4/ hydrocarbons, the latter are subsequently alkylated to form a gasoline fraction which can be admixed with the oligomerizates of the Cnumber and the C/sub 4/ cuts to produce the desired high octane gasoline.

  11. Conceptual process design and economics for the production of high-octane gasoline blendstock via indirect liquefaction of biomass through methanol/dimethyl ether intermediates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tan, Eric C. D.; Talmadge, Michael; Dutta, Abhijit; Hensley, Jesse; Snowden-Swan, Lesley J.; Humbird, David; Schaidle, Joshua; Biddy, Mary

    2015-10-28

    This paper describes in detail one potential conversion process for the production of high-octane gasoline blendstock via indirect liquefaction of biomass. The processing steps of this pathway include the conversion of biomass to synthesis gas via indirect gasification, gas clean-up via reforming of tars and other hydrocarbons, catalytic conversion of syngas to methanol, methanol dehydration to dimethyl ether (DME), and the homologation of DME over a zeolite catalyst to high-octane gasoline-range hydrocarbon products. The current process configuration has similarities to conventional methanol-to-gasoline (MTG) technologies, but there are key distinctions, specifically regarding the product slate, catalysts, and reactor conditions. A techno-economicmore » analysis is performed to investigate the production of high-octane gasoline blendstock. The design features a processing daily capacity of 2000 tonnes (2205 short tons) of dry biomass. The process yields 271 liters of liquid fuel per dry tonne of biomass (65 gal/dry ton), for an annual fuel production rate of 178 million liters (47 MM gal) at 90% on-stream time. The estimated total capital investment for an nth-plant is $438 million. The resulting minimum fuel selling price (MFSP) is $0.86 per liter or $3.25 per gallon in 2011 US dollars. A rigorous sensitivity analysis captures uncertainties in costs and plant performance. Sustainability metrics for the conversion process are quantified and assessed. The potential premium value of the high-octane gasoline blendstock is examined and found to be at least as competitive as fossil-derived blendstocks. A simple blending strategy is proposed to demonstrate the potential for blending the biomass-derived blendstock with petroleum-derived intermediates. Published 2015. This article is a U.S. Government work and is in the public domain in the USA. Biofuels, Bioproducts and Biorefining published by Society of Industrial Chemistry and John Wiley & Sons Ltd.« less

  12. Conceptual process design and economics for the production of high-octane gasoline blendstock via indirect liquefaction of biomass through methanol/dimethyl ether intermediates

    SciTech Connect (OSTI)

    Tan, Eric C. D.; Talmadge, Michael; Dutta, Abhijit; Hensley, Jesse; Snowden-Swan, Lesley J.; Humbird, David; Schaidle, Joshua; Biddy, Mary

    2015-10-28

    This paper describes in detail one potential conversion process for the production of high-octane gasoline blendstock via indirect liquefaction of biomass. The processing steps of this pathway include the conversion of biomass to synthesis gas via indirect gasification, gas clean-up via reforming of tars and other hydrocarbons, catalytic conversion of syngas to methanol, methanol dehydration to dimethyl ether (DME), and the homologation of DME over a zeolite catalyst to high-octane gasoline-range hydrocarbon products. The current process configuration has similarities to conventional methanol-to-gasoline (MTG) technologies, but there are key distinctions, specifically regarding the product slate, catalysts, and reactor conditions. A techno-economic analysis is performed to investigate the production of high-octane gasoline blendstock. The design features a processing daily capacity of 2000 tonnes (2205 short tons) of dry biomass. The process yields 271 liters of liquid fuel per dry tonne of biomass (65 gal/dry ton), for an annual fuel production rate of 178 million liters (47 MM gal) at 90% on-stream time. The estimated total capital investment for an nth-plant is $438 million. The resulting minimum fuel selling price (MFSP) is $0.86 per liter or $3.25 per gallon in 2011 US dollars. A rigorous sensitivity analysis captures uncertainties in costs and plant performance. Sustainability metrics for the conversion process are quantified and assessed. The potential premium value of the high-octane gasoline blendstock is examined and found to be at least as competitive as fossil-derived blendstocks. A simple blending strategy is proposed to demonstrate the potential for blending the biomass-derived blendstock with petroleum-derived intermediates. Published 2015. This article is a U.S. Government work and is in the public domain in the USA. Biofuels, Bioproducts and Biorefining published by Society of Industrial Chemistry and John Wiley & Sons Ltd.

  13. Supply Chain Sustainability Analysis of Indirect Liquefaction of Blended Biomass to Produce High Octane Gasoline

    SciTech Connect (OSTI)

    Cai, Hao; Canter, Christina E.; Dunn, Jennifer B.; Tan, Eric; Biddy, Mary; Talmadge, Michael; Hartley, Damon S.; Snowden-Swan, Lesley

    2015-09-01

    The Department of Energy’s (DOE) Bioenergy Technologies Office (BETO) aims at developing and deploying technologies to transform renewable biomass resources into commercially viable, high-performance biofuels, bioproducts and biopower through public and private partnerships (DOE, 2015). BETO also performs a supply chain sustainability analysis (SCSA). This report describes the SCSA of the production of renewable high octane gasoline (HOG) via indirect liquefaction (IDL) of lignocellulosic biomass. This SCSA was developed for the 2017 design case for feedstock logistics (INL, 2014) and for the 2022 target case for HOG production via IDL (Tan et al., 2015). The design includes advancements that are likely and targeted to be achieved by 2017 for the feedstock logistics and 2022 for the IDL conversion process. The 2017 design case for feedstock logistics demonstrated a delivered feedstock cost of $80 per dry U.S. short ton by the year 2017 (INL, 2014). The 2022 design case for the conversion process, as modeled in Tan et al. (2015), uses the feedstock 2017 design case blend of biomass feedstocks consisting of pulpwood, wood residue, switchgrass, and construction and demolition waste (C&D) with performance properties consistent with a sole woody feedstock type (e.g., pine or poplar). The HOG SCSA case considers the 2017 feedstock design case (the blend) as well as individual feedstock cases separately as alternative scenarios when the feedstock blend ratio varies as a result of a change in feedstock availability. These scenarios could be viewed as bounding SCSA results because of distinctive requirements for energy and chemical inputs for the production and logistics of different components of the blend feedstocks.

  14. Combined Sustainability Assessment and Techno-Economic Analysis for the Production of Biomass-Derived High-Octane Gasoline Blendstock

    SciTech Connect (OSTI)

    Tan, Eric C. D.; Talmadge, Michael; Dutta, Abhijit

    2015-11-13

    Conversion technologies for biomass to liquid hydrocarbon fuels are being actively developed. Converting biomass into advanced hydrocarbon fuels requires detailed assessments to help prioritize research; techno-economic analysis (TEA) is a long established tool used to assess feasibility and progress. TEA provides information needed to make informed judgments about the viability of any given conceptual conversion process; it is particularly useful to identify technical barriers and measure progress toward overcoming those barriers. Expansion of the cellulosic biofuels industry at the scale needed to meet the Renewable Fuel Standard goals is also expected to have environmental impacts. Hence, the success of the biofuels industry depends not only on economic viability, but also on environmental sustainability. A biorefinery process that is economically feasible but suffers from key sustainability drawbacks is not likely to represent a long-term solution to replace fossil-derived fuels. Overarching concerns like environmental sustainability need to be addressed for biofuels production. Combined TEA and environmental sustainability assessment of emerging pathways helps facilitate biorefinery designs that are both economically feasible and minimally impactful to the environment. This study focuses on environmental sustainability assessment and techno-economic analysis for the production of high-octane gasoline blendstock via gasification and methanol/dimethyl ether intermediates. Results from the conceptual process design with economic analysis, along with the quantification and assessment of the environmental sustainability, are presented and discussed. Sustainability metrics associated with the production of high-octane gasoline include carbon conversion efficiency, consumptive water use, life-cycle greenhouse gas emissions, fossil energy consumption, energy return on investment and net energy value.

  15. Process Design and Economics for the Conversion of Lignocellulosic Biomass to High Octane Gasoline: Thermochemical Research Pathway with Indirect Gasification and Methanol Intermediate

    SciTech Connect (OSTI)

    Tan, Eric; Talmadge, M.; Dutta, Abhijit; Hensley, Jesse; Schaidle, Josh; Biddy, Mary J.; Humbird, David; Snowden-Swan, Lesley J.; Ross, Jeff; Sexton, Danielle; Yap, Raymond; Lukas, John

    2015-03-01

    The U.S. Department of Energy (DOE) promotes research for enabling cost-competitive liquid fuels production from lignocellulosic biomass feedstocks. The research is geared to advance the state of technology (SOT) of biomass feedstock supply and logistics, conversion, and overall system sustainability. As part of their involvement in this program, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) investigate the economics of conversion pathways through the development of conceptual biorefinery process models. This report describes in detail one potential conversion process for the production of high octane gasoline blendstock via indirect liquefaction (IDL). The steps involve the conversion of biomass to syngas via indirect gasification followed by gas cleanup and catalytic syngas conversion to a methanol intermediate; methanol is then further catalytically converted to high octane hydrocarbons. The conversion process model leverages technologies previously advanced by research funded by the Bioenergy Technologies Office (BETO) and demonstrated in 2012 with the production of mixed alcohols from biomass. Biomass-derived syngas cleanup via tar and hydrocarbons reforming was one of the key technology advancements as part of that research. The process described in this report evaluates a new technology area with downstream utilization of clean biomass-syngas for the production of high octane hydrocarbon products through a methanol intermediate, i.e., dehydration of methanol to dimethyl ether (DME) which subsequently undergoes homologation to high octane hydrocarbon products.

  16. A Vehicle Manufacturer’s Perspective on Higher-Octane Fuels

    Broader source: Energy.gov [DOE]

    Breakout Session 1C—Fostering Technology Adoption I: Building the Market for Renewables with High Octane Fuels A Vehicle Manufacturer’s Perspective on Higher-Octane Fuels Tom Leone, Technical Expert, Powertrain Evaluation and Analysis, Ford Motor Company

  17. Experimental Investigation of Spark-Ignited Combustion with High-Octane Biofuels and EGR. 2. Fuel and EGR Effects on Knock-Limited Load and Speed

    SciTech Connect (OSTI)

    Splitter, Derek A; Szybist, James P

    2013-01-01

    The present study experimentally investigates spark-ignited combustion with 87 AKI E0 gasoline in its neat form and in midlevel alcohol gasoline blends with 24% vol/vol isobutanol gasoline (IB24) and 30% vol/vol ethanol gasoline (E30). A single-cylinder research engine is used with an 11.85:1 compression ratio, hydraulically actuated valves, laboratory intake air, and was capable of external exhaust gas recirculation (EGR). Experiments were conducted with all fuels to full-load conditions with = 1, using both 0% and 15% external-cooled EGR. Higher octane number biofuel blends exhibited increased stoichiometric torque capability at this compression ratio, where the unique properties of ethanol enabled a doubling of the stoichiometric torque capability with E30 as compared to that of 87AKI, up to 20 bar IMEPg (indicating mean effective pressure gross) at = 1. The results demonstrate that for all fuels, EGR is a key enabler for increasing engine efficiency but is less useful for knock mitigation with E30 than for 87AKI gasoline or IB24. Under knocking conditions, 15% EGR is found to offer 1 CA of CA50 timing advance with E30, whereas up to 5 CA of CA50 advance is possible with knock-limited 87AKI gasoline. Compared to 87AKI, both E30 and IB24 are found to have reduced adiabatic flame temperature and shorter combustion durations, which reduce knocking propensity beyond that indicated by the octane number. However, E30+0% EGR is found to exhibit the better antiknock properties than either 87AKI+15% EGR or IB24+15% EGR, expanding the knock limited operating range and engine stoichiometric torque capability at high compression ratio. Furthermore, the fuel sensitivity (S) of E30 was attributed to reduced speed sensitivity of E30, expanding the low-speed stoichiometric torque capability at high compression ratio. The results illustrate that intermediate alcohol gasoline blends exhibit exceptional antiknock properties and performance beyond that indicated by the octane

  18. Process Design and Economics for the Conversion of Lignocellulosic Biomass to Hydrocarbons via Indirect Liquefaction. Thermochemical Research Pathway to High-Octane Gasoline Blendstock Through Methanol/Dimethyl Ether Intermediates

    SciTech Connect (OSTI)

    Tan, Eric C. D.; Talmadge, Michael; Dutta, Abhijit; Hensley, Jesse; Schaidle, Josh; Biddy, Mary; Humbird, David; Snowden-Swan, Lesley J.; Ross, Jeff; Sexton, Danielle; Yap, Raymond; Lukas, John

    2015-03-01

    This report was developed as part of the U.S. Department of Energy’s Bioenergy Technologies Office’s (BETO’s) efforts to enable the development of technologies for the production of infrastructure-compatible, cost-competitive liquid hydrocarbon fuels from lignocellulosic biomass feedstocks. The research funded by BETO is designed to advance the state of technology of biomass feedstock supply and logistics, conversion, and overall system sustainability. It is expected that these research improvements will be made within the 2022 timeframe. As part of their involvement in this research and development effort, the National Renewable Energy Laboratory and the Pacific Northwest National Laboratory investigate the economics of conversion pathways through the development of conceptual biorefinery process models and techno-economic analysis models. This report describes in detail one potential conversion process for the production of high-octane gasoline blendstock via indirect liquefaction of biomass. The processing steps of this pathway include the conversion of biomass to synthesis gas or syngas via indirect gasification, gas cleanup, catalytic conversion of syngas to methanol intermediate, methanol dehydration to dimethyl ether (DME), and catalytic conversion of DME to high-octane, gasoline-range hydrocarbon blendstock product. The conversion process configuration leverages technologies previously advanced by research funded by BETO and demonstrated in 2012 with the production of mixed alcohols from biomass. Biomass-derived syngas cleanup via reforming of tars and other hydrocarbons is one of the key technology advancements realized as part of this prior research and 2012 demonstrations. The process described in this report evaluates a new technology area for the downstream utilization of clean biomass-derived syngas for the production of high-octane hydrocarbon products through methanol and DME intermediates. In this process, methanol undergoes dehydration to

  19. High octane ethers from synthesis gas-derived alcohols. Quarterly technical progress report, April--June 1993

    SciTech Connect (OSTI)

    Klier, K.; Herman, R.G.; Menszak, J.; Johansson, M.A.; Feeley, O.C.; Kim, D.

    1993-07-01

    The results shown in Figures 10 and 11 demonstrate that the formation of butenes was very sensitive to the alcohol partial pressure. A small elevation of the alcohol pressure suppressed the formation of butenes rather drastically at both 90 and 117{degree}C. The synthesis rates of DME, MIBE, and MTBE ethers were not significantly affected at 90{degree}C, although there was a trend to increase the space time yield of DME as the alcohol pressure was increased. At the reaction temperature of 117{degree}C, all of the ethers showed increasing productivities as the pressure of the reactants was increased (Figure 11). An isotope labelling experiment was carried out to provide mechanistic insight into the manner in which methanol and isobutanol react together to form DME, MIBE, and MTBE ethers and to determine if MTBE were derived from MIBE.

  20. An Experimental Investigation of Low Octane Gasoline in Diesel Engines |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Low Octane Gasoline in Diesel Engines An Experimental Investigation of Low Octane Gasoline in Diesel Engines Presentation given at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. deer10_ciatti.pdf (1.34 MB) More Documents & Publications Use of Low Cetane Fuel to Enable Low Temperature Combustion High-Efficiency, Ultra-Low Emission Combustion in a Heavy-Duty Engine via Fuel Reactivity Control

  1. Bio Octane Energias Renov veis | Open Energy Information

    Open Energy Info (EERE)

    Octane Energias Renov veis Jump to: navigation, search Name: Bio-Octane Energias Renovveis Place: Minas Gerais, Brazil Product: Brazil-based biodiesel producer, located in the...

  2. The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Optimization | Department of Energy The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization The Impact of Low Octane Hydrocarbon Blending Streams on "E85" Engine Optimization deer12_szybist.pdf (3.46 MB) More Documents & Publications High Octane Fuels Can Make Better Use of Renewable Transportation Fuels Making Better Use of Ethanol as a Transportation Fuel With "Renewable Super Premium" Gasoline-Like Fuel Effects on Advanced

  3. BiOctane | Open Energy Information

    Open Energy Info (EERE)

    Product: Biofuel start-up planning to design and develop a biodiesel and ethanol refinery. References: BiOctane1 This article is a stub. You can help OpenEI by expanding it....

  4. Experimental Investigation of Spark-Ignited Combustion with High-Octane Biofuels and EGR. 1. Engine Load Range and Downsize Downspeed Opportunity

    SciTech Connect (OSTI)

    Splitter, Derek A; Szybist, James P

    2013-01-01

    The present study experimentally investigates spark-ignited combustion with 87 AKI E0 gasoline in its neat form and in midlevel alcohol gasoline blends with 24% vol/vol isobutanol gasoline (IB24) and 30% vol/vol ethanol gasoline (E30). A single-cylinder research engine was used with an 11.85:1 compression ratio, hydraulically actuated valves, laboratory intake air, and was capable of external exhaust gas recirculation (EGR). Experiments were conducted with all fuels to full-load conditions with = 1, using both 0% and 15% external cooled EGR. Higher octane number biofuel blends exhibited increased stoichiometric torque capability at this compression ratio, where the unique properties of ethanol enabled a doubling of the stoichiometric torque capability with E30 as compared to 87 AKI, up to 20 bar IMEPg (indicated mean effective pressure gross) at = 1. EGR provided thermodynamic advantages and was a key enabler for increasing engine efficiency for all fuel types. However, with E30, EGR was less useful for knock mitigation than gasoline or IB24. Torque densities with E30 with 15% EGR at = 1 operation were similar or better than a modern EURO IV calibration turbo-diesel engine. The results of the present study suggest that it could be possible to implement a 40% downsize + downspeed configuration (1.2 L engine) into a representative midsize sedan. For example, for a midsize sedan at a 65 miles/h cruise, an estimated fuel consumption of 43.9 miles per gallon (MPG) (engine out 102 g-CO2/km) could be achieved with similar reserve power to a 2.0 L engine with 87AKI (38.6 MPG, engine out 135 g-CO2/km). Data suggest that, with midlevel alcohol gasoline blends, engine and vehicle optimization can offset the reduced fuel energy content of alcohol gasoline blends and likely reduce vehicle fuel consumption and tailpipe CO2 emissions.

  5. A high rate proportional chamber

    SciTech Connect (OSTI)

    Henderson, R.; Fraszer, W.; Openshaw, R.; Sheffer, G.; Salomon, M.; Dew, S.; Marans, J.; Wilson, P.

    1987-02-01

    Gas mixtures with high specific ionization allow the use of small interelectrode distances while still maintaining full efficiency. With the short electron drift distances the timing resolution is also improved. The authors have built and operated two 25 cm/sup 2/ chambers with small interelectrode distances. Also single wire detector cells have been built to test gas mixture lifetimes. Various admixtures of CF/sub 4/, DME, Isobutane, Ethane and Argon have been tested. Possible applications of such chambers are as beam profile monitors, position tagging of rare events and front end chambers in spectrometers.

  6. The Impact of Low Octane Hydrocarbon Blending Streams on Ethanol Engine Optimization

    SciTech Connect (OSTI)

    Szybist, James P; West, Brian H

    2013-01-01

    Ethanol is a very attractive fuel from an end-use perspective because it has a high chemical octane number and a high latent heat of vaporization. When an engine is optimized to take advantage of these fuel properties, both efficiency and power can be increased through higher compression ratio, direct fuel injection, higher levels of boost, and a reduced need for enrichment to mitigate knock or protect the engine and aftertreatment system from overheating. The ASTM D5798 specification for high level ethanol blends, commonly called E85, underwent a major revision in 2011. The minimum ethanol content was revised downward from 68 vol% to 51 vol%, which combined with the use of low octane blending streams such as natural gasoline introduces the possibility of a lower octane E85 fuel. While this fuel is suitable for current ethanol tolerant flex fuel vehicles, this study experimentally examines whether engines can still be aggressively optimized for the resultant fuel from the revised ASTM D5798 specification. The performance of six ethanol fuel blends, ranging from 51-85% ethanol, is compared to a premium-grade certification gasoline (UTG-96) in a single-cylinder direct-injection (DI) engine with a compression ratio of 12.9:1 at knock-prone engine conditions. UTG-96 (RON = 96.1), light straight run gasoline (RON = 63.6), and n-heptane (RON = 0) are used as the hydrocarbon blending streams for the ethanol-containing fuels in an effort to establish a broad range of knock resistance for high ethanol fuels. Results show that nearly all ethanol-containing fuels are more resistant to engine knock than UTG-96 (the only exception being the ethanol blend with 49% n-heptane). This knock resistance allows ethanol blends made with 33 and 49% light straight run gasoline, and 33% n-heptane to be operated at significantly more advanced combustion phasing for higher efficiency, as well as at higher engine loads. While experimental results show that the octane number of the hydrocarbon

  7. An experimental investigation of low octane gasoline in diesel engines.

    SciTech Connect (OSTI)

    Ciatti, S. A.; Subramanian, S.

    2011-09-01

    Conventional combustion techniques struggle to meet the current emissions norms. In particular, oxides of nitrogen (NO{sub x}) and particulate matter (PM) emissions have limited the utilization of diesel fuel in compression ignition engines. Advance combustion concepts have proved the potential to combine fuel efficiency and improved emission performance. Low-temperature combustion (LTC) offers reduced NO{sub x} and PM emissions with comparable modern diesel engine efficiencies. The ability of premixed, low-temperature compression ignition to deliver low PM and NO{sub x} emissions is dependent on achieving optimal combustion phasing. Diesel operated LTC is limited by early knocking combustion, whereas conventional gasoline operated LTC is limited by misfiring. So the concept of using an unconventional fuel with the properties in between those two boundary fuels has been experimented in this paper. Low-octane (84 RON) gasoline has shown comparable diesel efficiencies with the lowest NO{sub x} emissions at reasonable high power densities (NO{sub x} emission was 1 g/kW h at 12 bar BMEP and 2750 rpm).

  8. High-Rate, High-Capacity Binder-Free Electrode

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Office of Energy Efficiency and Renewable Energy operated by the Alliance for Sustainable Energy, LLC High-Rate, High-Capacity Binder-Free Electrode Patent: PCT-09-41 Chunmei Ban ...

  9. Detailed Chemical Kinetic Reaction Mechanisms for Primary Reference Fuels for Diesel Cetane Number and Spark-Ignition Octane Number

    SciTech Connect (OSTI)

    Westbrook, C K; Pitz, W J; Mehl, M; Curran, H J

    2010-03-03

    For the first time, a detailed chemical kinetic reaction mechanism is developed for primary reference fuel mixtures of n-hexadecane and 2,2,4,4,6,8,8-heptamethyl nonane for diesel cetane ratings. The mechanisms are constructed using existing rules for reaction pathways and rate expressions developed previously for the primary reference fuels for gasoline octane ratings, n-heptane and iso-octane. These reaction mechanisms are validated by comparisons between computed and experimental results for shock tube ignition and for oxidation under jet-stirred reactor conditions. The combined kinetic reaction mechanism contains the submechanisms for the primary reference fuels for diesel cetane ratings and submechanisms for the primary reference fuels for gasoline octane ratings, all in one integrated large kinetic reaction mechanism. Representative applications of this mechanism to two test problems are presented, one describing fuel/air autoignition variations with changes in fuel cetane numbers, and the other describing fuel combustion in a jet-stirred reactor environment with the fuel varying from pure 2,2,4,4,6,8,8-heptamethyl nonane (Cetane number of 15) to pure n-hexadecane (Cetane number of 100). The final reaction mechanism for the primary reference fuels for diesel fuel and gasoline is available on the web.

  10. HIGH ENERGY RATE EXTRUSION OF URANIUM

    DOE Patents [OSTI]

    Lewis, L.

    1963-07-23

    A method of extruding uranium at a high energy rate is described. Conditions during the extrusion are such that the temperature of the metal during extrusion reaches a point above the normal alpha to beta transition, but the metal nevertheless remains in the alpha phase in accordance with the Clausius- Clapeyron equation. Upon exiting from the die, the metal automatically enters the beta phase, after which the metal is permitted to cool. (AEC)

  11. Dehydrogenation links LPG to more octanes

    SciTech Connect (OSTI)

    Gussow, S.; Spence, D.C.; White, E.A.

    1980-01-01

    Air Products and Chemicals Inc.'s Houdry Catofin process, a new application of well-known Houdry catalytic dehydrogenation technology, is an adiabatic, fixed-bed, multireactor catalytic process which produces propylene, isobutylene, and mixed n-butylenes by dehydrogenation of the corresponding saturates. The process is very flexible in that propylene, isobutylene, and mixed n-butylenes can be produced either separately or simultaneously from the corresponding saturates. The process will be used to prepare purity propylene at a Morelos, Mex., plant, which is now in the engineering stage. Five variations of the procedure for producing propylene; methyl tert.-butyl ether; propylene and alkylate; methyl tert.-butyl ether and alkylate; and methyl tert.-butyl ether, alkylate, and 1-butylene are compared with respect to typical product yields, costs and values for process economics, the dehydrogenation route to the three products, manufacturing costs, the sensitivity of return on investment to feedstock costs, and the return on investment, which varies from a low of 11.5% for the third case to a high of 14.4% for the fourth case. The Catofin process is discussed.

  12. FCC LPG olefinicity and branching enhanced by octane catalysts

    SciTech Connect (OSTI)

    Keyworth, D.A.; Reid, T.A.; Kreider, K.R.; Yatsu, C.A.

    1989-05-29

    Refiners are increasingly recognizing the downstream opportunities for fluid catalytic cracking LPG olefins for the production of methyl tertiary butyl ether (MTBE), ethyl tertiary butyl ether (ETBE, if the ethanol subsidy is extended to the production of ETBE), and as petrochemical feedstocks. Some of new gasoline FCC octane-enhancing catalysts can support those opportunities because their low non-framework alumina (low NFA) preserve both LPG olefinicity and promote branching of the LPG streams from the FCCU. The combined effect results in more isobutane for alkylate feed, more propylene in the propane/propylene stream, and more isobutene - which makes the addition of an MTBE unit very enticing.

  13. High-Rate, High-Capacity Binder-Free Electrode

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Office of Energy Efficiency and Renewable Energy operated by the Alliance for Sustainable Energy, LLC High-Rate, High-Capacity Binder-Free Electrode Patent: PCT-09-41 Chunmei Ban Zhuangchun Wu Anne Dillon National Renewable Energy Laboratory PCT: 09-41 Binderfree electrode 2 Outline  What is the technology  Why it is better than other technologies  How far away from market  Technical details  Market analysis National Renewable Energy Laboratory PCT: 09-41 Binderfree electrode 3

  14. High resolution, high rate x-ray spectrometer

    DOE Patents [OSTI]

    Goulding, F.S.; Landis, D.A.

    1983-07-14

    It is an object of the invention to provide a pulse processing system for use with detected signals of a wide dynamic range which is capable of very high counting rates, with high throughput, with excellent energy resolution and a high signal-to-noise ratio. It is a further object to provide a pulse processing system wherein the fast channel resolving time is quite short and substantially independent of the energy of the detected signals. Another object is to provide a pulse processing system having a pile-up rejector circuit which will allow the maximum number of non-interfering pulses to be passed to the output. It is also an object of the invention to provide new methods for generating substantially symmetrically triangular pulses for use in both the main and fast channels of a pulse processing system.

  15. HIgh Rate X-ray Fluorescence Detector

    SciTech Connect (OSTI)

    Grudberg, Peter Matthew

    2013-04-30

    The purpose of this project was to develop a compact, modular multi-channel x-ray detector with integrated electronics. This detector, based upon emerging silicon drift detector (SDD) technology, will be capable of high data rate operation superior to the current state of the art offered by high purity germanium (HPGe) detectors, without the need for liquid nitrogen. In addition, by integrating the processing electronics inside the detector housing, the detector performance will be much less affected by the typically noisy electrical environment of a synchrotron hutch, and will also be much more compact than current systems, which can include a detector involving a large LN2 dewar and multiple racks of electronics. The combined detector/processor system is designed to match or exceed the performance and features of currently available detector systems, at a lower cost and with more ease of use due to the small size of the detector. In addition, the detector system is designed to be modular, so a small system might just have one detector module, while a larger system can have many ?? you can start with one detector module, and add more as needs grow and budget allows. The modular nature also serves to simplify repair. In large part, we were successful in achieving our goals. We did develop a very high performance, large area multi-channel SDD detector, packaged with all associated electronics, which is easy to use and requires minimal external support (a simple power supply module and a closed-loop water cooling system). However, we did fall short of some of our stated goals. We had intended to base the detector on modular, large-area detectors from Ketek GmbH in Munich, Germany; however, these were not available in a suitable time frame for this project, so we worked instead with pnDetector GmbH (also located in Munich). They were able to provide a front-end detector module with six 100 m^2 SDD detectors (two monolithic arrays of three elements each) along with

  16. High Octane Fuels Can Make Better use of Renewable Transportation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CAFE and RFS simultaneously? 70% less PM Ethanol blends can also help mitigate particle ... Billion Gallons per Year Year US Production US Consumption Ethanol is currently largest ...

  17. Ionization of ethane, butane, and octane in strong laser fields

    SciTech Connect (OSTI)

    Palaniyappan, Sasi; Mitchell, Rob; Ekanayake, N.; Watts, A. M.; White, S. L.; Sauer, Rob; Howard, L. E.; Videtto, M.; Mancuso, C.; Wells, S. J.; Stanev, T.; Wen, B. L.; Decamp, M. F.; Walker, B. C.

    2010-10-15

    Strong-field photoionization of ethane, butane, and octane are reported at intensities from 10{sup 14} to 10{sup 17} W/cm{sup 2}. The molecular fragment ions, C{sup +} and C{sup 2+}, are created in an intensity window from 10{sup 14} to 10{sup 15} W/cm{sup 2} and have intensity-dependent yields similar to the molecular fragments C{sub m}H{sub n}{sup +} and C{sub m}H{sub n}{sup 2+}. In the case of C{sup +}, the yield is independent of the molecular parent chain length. The ionization of more tightly bound valence electrons in carbon (C{sup 3+} and C{sup 4+}) has at least two contributing mechanisms, one influenced by the parent molecule size and one resulting from the tunneling ionization of the carbon ion.

  18. CRC program for quantifying performance of knock-sensor-equipped vehicles with varying octane level

    SciTech Connect (OSTI)

    Not Available

    1990-08-01

    A pilot study was conducted under the auspices of the Coordinating Research Council, Inc. (CRC) to assess the potential effects of gasoline octane quality on acceleration performance, fuel economy and driveability in vehicles equipped with electronic spark control systems (knock sensors). Fourteen vehicles were tested by five participating laboratories on CRC unleaded reference fuels of varying octane quality (78 to 104 RON). The test vehicles included nine naturally-aspirated and five turbocharged models. The results showed that acceleration performance was the parameter most sensitive to octane quality changes, particularly in the turbocharged models.

  19. Methyl aryl ethers from coal liquids as gasoline extenders and octane improvers

    SciTech Connect (OSTI)

    Singerman, G.M.

    1980-11-01

    A mixture of methyl aryl ethers derived from the phenols present in direct liquefaction coal liquids shows considerable promise as a gasoline blending agent and octane improver. The mixture of methyl aryl ethers was blended at five volume percent with a commercial, unleaded gasoline. The properties and performance of the blend in a variety of laboratory and automotive tests is reported. The tests show that the mixture of methyl aryl ethers improves gasoline octane without degrading other gasoline properties.

  20. Figure 7. Projected Production for the High Development Rate...

    U.S. Energy Information Administration (EIA) Indexed Site

    7. Projected Production for the High Development Rate of Technically Recoverable Oil Estimated at 5 Percent, Mean, and 95 Percent Probabilities for the ANWR Coastal Plain of the...

  1. High Rate and Stable Cycling of Lithium Metal Anode (Journal...

    Office of Scientific and Technical Information (OSTI)

    Title: High Rate and Stable Cycling of Lithium Metal Anode Lithium (Li) metal is an ideal anode material for rechargeable batteries. However, dendritic Li growth and limited ...

  2. High-shear-rate capillary viscometer for inkjet inks

    SciTech Connect (OSTI)

    Wang Xi; Carr, Wallace W.; Bucknall, David G.; Morris, Jeffrey F.

    2010-06-15

    A capillary viscometer developed to measure the apparent shear viscosity of inkjet inks at high apparent shear rates encountered during inkjet printing is described. By using the Weissenberg-Rabinowitsch equation, true shear viscosity versus true shear rate is obtained. The device is comprised of a constant-flow generator, a static pressure monitoring device, a high precision submillimeter capillary die, and a high stiffness flow path. The system, which is calibrated using standard Newtonian low-viscosity silicone oil, can be easily operated and maintained. Results for measurement of the shear-rate-dependent viscosity of carbon-black pigmented water-based inkjet inks at shear rates up to 2x10{sup 5} s{sup -1} are discussed. The Cross model was found to closely fit the experimental data. Inkjet ink samples with similar low-shear-rate viscosities exhibited significantly different shear viscosities at high shear rates depending on particle loading.

  3. HIGH-RATE FORMABILITY OF HIGH-STRENGTH ALUMINUM ALLOYS: A STUDY ON OBJECTIVITY OF MEASURED STRAIN AND STRAIN RATE

    SciTech Connect (OSTI)

    Upadhyay, Piyush; Rohatgi, Aashish; Stephens, Elizabeth V.; Davies, Richard W.; Catalini, David

    2015-02-18

    Al alloy AA7075 sheets were deformed at room temperature at strain-rates exceeding 1000 /s using the electrohydraulic forming (EHF) technique. A method that combines high speed imaging and digital image correlation technique, developed at Pacific Northwest National Laboratory, is used to investigate high strain rate deformation behavior of AA7075. For strain-rate sensitive materials, the ability to accurately model their high-rate deformation behavior is dependent upon the ability to accurately quantify the strain-rate that the material is subjected to. This work investigates the objectivity of software-calculated strain and strain rate by varying different parameters within commonly used commercially available digital image correlation software. Except for very close to the time of crack opening the calculated strain and strain rates are very consistent and independent of the adjustable parameters of the software.

  4. DETAILED CHEMICAL KINETIC MODELING OF ISO-OCTANE SI-HCCI TRANSITION

    SciTech Connect (OSTI)

    Havstad, M A; Aceves, S M; McNenly, M J; Piggott, W T; Edwards, K D; Wagner, R M; Daw, C S; Finney, C A

    2009-10-12

    The authors describe a CHEMKIN-based multi-zone model that simulates the expected combustion variations in a single-cylinder engine fueled with iso-octane as the engine transitions from spark-ignited (ST) combustion to homogeneous charge compression ignition (HCCI) combustion. The model includes a 63-species reaction mechanism and mass and energy balances for the cylinder and the exhaust flow. For this study they assumed that the SI-to-HCCI transition is implemented by means of increasing the internal exhaust gas recirculation (EGR) at constant engine speed. This transition scneario is consistent with that implemented in previously reported experimental measurements on an experimental engine equipped with variable valve actuation. They find that the model captures many of the important experimental trends, including stable SI combustion at low EGR ({approx} 0.10), a transition to highly unstable combustion at intermediate EGR, and finally stable HCCI combustion at very high EGR ({approx} 0.75). Remaining differences between the predicted and experimental instability patterns indicate that there is further room for model improvement.

  5. Detailed Chemical Kinetic Modeling of Iso-octane SI-HCCI Transition

    SciTech Connect (OSTI)

    Havstad, Mark A; Aceves, Salvador M; McNenly, Matthew J; Piggott, William T; Edwards, Kevin Dean; Wagner, Robert M; Daw, C Stuart; FINNEY, Charles E A

    2010-01-01

    We describe a CHEMKIN-based multi-zone model that simulates the expected combustion variations in a single-cylinder engine fueled with iso-octane as the engine transitions from spark-ignited (SI) combustion to homogenous charge compression ignition (HCCI) combustion. The model includes a 63-species reaction mechanism and mass and energy balances for the cylinder and the exhaust flow. For this study we assumed that the SI-to-HCCI transition is implemented by means of increasing the internal exhaust gas recirculation (EGR) at constant engine speed. This transition scenario is consistent with that implemented in previously reported experimental measurements on an experimental engine equipped with variable valve actuation. We find that the model captures many of the important experimental trends, including stable SI combustion at low EGR (-0.10), a transition to highly unstable combustion at intermediate EGR, and finally stable HCCI combustion at very high EGR (-0.75). Remaining differences between the predicted and experimental instability patterns indicate that there is further room for model improvement.

  6. Proton NMR analysis of octane number for motor gasoline: Part IV

    SciTech Connect (OSTI)

    Ichikawa, M.; Nonaka, N.; Amano, H.; Takada, I.; Ishimori, S.; Andoh, H.; Kumamoto, K.

    1992-08-01

    Software for predicting the octane number of motor gasoline by proton magnetic resonance (PMR) spectrometry has been formulated. At the same time, a method has been studied to predict the composition of gasoline (in terms of the contents of paraffin, olefin, and aromatic compounds). The formulated program was evaluated by using it to predict the octane numbers of 31 samples of marketed summer gasoline (including 16 regular and 15 premium products), whose octane numbers and compositions were identified according to the ASTM standards. Also, the relationship between the PMR spectrum and gasoline composition was subjected to linear regression analysis by using the 31 samples whose octane numbers were calculated, and the appropriateness of the resultant regression equations was assessed. This report concerns the results of the study in which the octane numbers of the 31 samples were satisfactorily predicted by the formulated program and useful linear regression equation were obtained for the prediction of the composition of gasoline. 9 refs., 9 figs., 3 tabs.

  7. Solidification at the High and Low Rate Extreme

    SciTech Connect (OSTI)

    Halim Meco

    2004-12-19

    The microstructures formed upon solidification are strongly influenced by the imposed growth rates on an alloy system. Depending on the characteristics of the solidification process, a wide range of growth rates is accessible. The prevailing solidification mechanisms, and thus the final microstructure of the alloy, are governed by these imposed growth rates. At the high rate extreme, for instance, one can have access to novel microstructures that are unattainable at low growth rates. While the low growth rates can be utilized for the study of the intrinsic growth behavior of a certain phase growing from the melt. Although the length scales associated with certain processes, such as capillarity, and the diffusion of heat and solute, are different at low and high rate extremes, the phenomena that govern the selection of a certain microstructural length scale or a growth mode are the same. Consequently, one can analyze the solidification phenomena at both high and low rates by using the same governing principles. In this study, we examined the microstructural control at both low and high extremes. For the high rate extreme, the formation of crystalline products and factors that control the microstructure during rapid solidification by free-jet melt spinning are examined in Fe-Si-B system. Particular attention was given to the behavior of the melt pool at different quench-wheel speeds. Since the solidification process takes place within the melt-pool that forms on the rotating quench-wheel, we examined the influence of melt-pool dynamics on nucleation and growth of crystalline solidification products and glass formation. High-speed imaging of the melt-pool, analysis of ribbon microstructure, and measurement of ribbon geometry and surface character all indicate upper and lower limits for melt-spinning rates for which nucleation can be avoided, and fully amorphous ribbons can be achieved. Comparison of the relevant time scales reveals that surface-controlled melt

  8. Using SiO Anodes for High Capacity, High Rate Electrodes for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Using SiO Anodes for High Capacity, High Rate Electrodes for Lithium Ion Batteries ... areal capacities and good capacity retention for application in lithium ion batteries. ...

  9. High Thermal Efficiency and Low Emissions with Supercritical...

    Broader source: Energy.gov (indexed) [DOE]

    Gasoline Injection-Ignition in a Light Duty Engine An Experimental Investigation of Low Octane Gasoline in Diesel Engines Low Temperature Combustion Demonstrator for High ...

  10. High Rate and Stable Cycling of Lithium Metal Anode

    SciTech Connect (OSTI)

    Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu; Bhattacharya, Priyanka; Engelhard, Mark H.; Borodin, Oleg; Zhang, Jiguang

    2015-02-20

    Lithium (Li) metal is an ideal anode material for rechargeable batteries. However, dendritic Li growth and limited Coulombic efficiency (CE) during repeated Li deposition/stripping processes have prevented the application of this anode in rechargeable Li metal batteries, especially for use at high current densities. Herein, we report that the use of highly concentrated electrolytes composed of ether solvents and the lithium bis(fluorosulfonyl)imide (LiFSI) salt enables the high rate cycling of a Li metal anode at high CE (up to 99.1 %) without dendrite growth. With 4 M LiFSI in 1,2-dimethoxyethane (DME) as the electrolyte, a Li|Li cell can be cycled at high rates (10 mA cm-2) for more than 6000 cycles with no increase in the cell impedance, and a Cu|Li cell can be cycled at 4 mA cm-2 for more than 1000 cycles with an average CE of 98.4%. These excellent high rate performances can be attributed to the increased solvent coordination and increased availability of Li+ concentration in the electrolyte. Further development of this electrolyte may lead to practical applications for Li metal anode in rechargeable batteries. The fundamental mechanisms behind the high rate ion exchange and stability of the electrolytes also shine light on the stability of other electrochemical systems.

  11. High rate and stable cycling of lithium metal anode

    SciTech Connect (OSTI)

    Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu; Bhattacharya, Priyanka; Engelhard, Mark H.; Borodin, Oleg; Zhang, Jiguang

    2015-02-20

    Lithium (Li) metal is an ideal anode material for rechargeable batteries. However, dendritic Li growth and limited Coulombic efficiency (CE) during repeated Li deposition/stripping processes have prevented the application of this anode in rechargeable Li metal batteries, especially for use at high current densities. Here, we report that the use of highly concentrated electrolytes composed of ether solvents and the lithium bis(fluorosulfonyl)imide (LiFSI) salt enables the high rate cycling of a Li metal anode at high CE (up to 99.1 %) without dendrite growth. With 4 M LiFSI in 1,2-dimethoxyethane (DME) as the electrolyte, a Li|Li cell can be cycled at high rates (10 mA cm-2) for more than 6000 cycles with no increase in the cell impedance, and a Cu|Li cell can be cycled at 4 mA cm-2 for more than 1000 cycles with an average CE of 98.4%. These excellent high rate performances can be attributed to the increased solvent coordination and increased availability of Li+ concentration in the electrolyte. Lastly, further development of this electrolyte may lead to practical applications for Li metal anode in rechargeable batteries. The fundamental mechanisms behind the high rate ion exchange and stability of the electrolytes also shine light on the stability of other electrochemical systems.

  12. High rate and stable cycling of lithium metal anode

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu; Bhattacharya, Priyanka; Engelhard, Mark H.; Borodin, Oleg; Zhang, Jiguang

    2015-02-20

    Lithium (Li) metal is an ideal anode material for rechargeable batteries. However, dendritic Li growth and limited Coulombic efficiency (CE) during repeated Li deposition/stripping processes have prevented the application of this anode in rechargeable Li metal batteries, especially for use at high current densities. Here, we report that the use of highly concentrated electrolytes composed of ether solvents and the lithium bis(fluorosulfonyl)imide (LiFSI) salt enables the high rate cycling of a Li metal anode at high CE (up to 99.1 %) without dendrite growth. With 4 M LiFSI in 1,2-dimethoxyethane (DME) as the electrolyte, a Li|Li cell can be cycledmore » at high rates (10 mA cm-2) for more than 6000 cycles with no increase in the cell impedance, and a Cu|Li cell can be cycled at 4 mA cm-2 for more than 1000 cycles with an average CE of 98.4%. These excellent high rate performances can be attributed to the increased solvent coordination and increased availability of Li+ concentration in the electrolyte. Lastly, further development of this electrolyte may lead to practical applications for Li metal anode in rechargeable batteries. The fundamental mechanisms behind the high rate ion exchange and stability of the electrolytes also shine light on the stability of other electrochemical systems.« less

  13. Semi-solid electrodes having high rate capability

    DOE Patents [OSTI]

    Chiang, Yet-Ming; Duduta, Mihai; Holman, Richard; Limthongkul, Pimpa; Tan, Taison

    2015-11-10

    Embodiments described herein relate generally to electrochemical cells having high rate capability, and more particularly to devices, systems and methods of producing high capacity and high rate capability batteries having relatively thick semi-solid electrodes. In some embodiments, an electrochemical cell includes an anode, a semi-solid cathode that includes a suspension of an active material and a conductive material in a liquid electrolyte, and an ion permeable membrane disposed between the anode and the cathode. The semi-solid cathode has a thickness in the range of about 250 .mu.m-2,500 .mu.m, and the electrochemical cell has an area specific capacity of at least 5 mAh/cm.sup.2 at a C-rate of C/2.

  14. High strain rate deformation of NiAl

    SciTech Connect (OSTI)

    Maloy, S.A.; Gray, G.T. III; Darolia, R.

    1994-07-01

    NiAl is a potential high temperature structural material. Applications for which NiAl is being considered (such as rotating components in jet engines) requires knowledge of mechanical properties over a wide range of strain rates. Single crystal NiAl (stoichiometric and Ni 49.75Al 0.25Fe) has been deformed in compression along [100] at strain rates of 0.001, 0.1/s and 2000/s and temperatures of 76,298 and 773K. <111> slip was observed after 76K testing at a strain rate of 0.001/s and 298K testing at a strain rate of 2000/s. Kinking was observed after deformation at 298K and a strain rate of 0.001/s and sometimes at 298 K and a strain rate of 0.1/s. Strain hardening rates of 8200 and 4000 MPa were observed after 773 and 298K testing respectively, at a strain rate of 2000/s. Results are discussed in reference to resulting dislocation substructure.

  15. High removal rate laser-based coating removal system

    DOE Patents [OSTI]

    Matthews, Dennis L.; Celliers, Peter M.; Hackel, Lloyd; Da Silva, Luiz B.; Dane, C. Brent; Mrowka, Stanley

    1999-11-16

    A compact laser system that removes surface coatings (such as paint, dirt, etc.) at a removal rate as high as 1000 ft.sup.2 /hr or more without damaging the surface. A high repetition rate laser with multiple amplification passes propagating through at least one optical amplifier is used, along with a delivery system consisting of a telescoping and articulating tube which also contains an evacuation system for simultaneously sweeping up the debris produced in the process. The amplified beam can be converted to an output beam by passively switching the polarization of at least one amplified beam. The system also has a personal safety system which protects against accidental exposures.

  16. Ultra High-Rate Germanium (UHRGe) Modeling Status Report

    SciTech Connect (OSTI)

    Warren, Glen A.; Rodriguez, Douglas C.

    2012-06-07

    The Ultra-High Rate Germanium (UHRGe) project at Pacific Northwest National Laboratory (PNNL) is conducting research to develop a high-purity germanium (HPGe) detector that can provide both the high resolution typical of germanium and high signal throughput. Such detectors may be beneficial for a variety of potential applications ranging from safeguards measurements of used fuel to material detection and verification using active interrogation techniques. This report describes some of the initial radiation transport modeling efforts that have been conducted to help guide the design of the detector as well as a description of the process used to generate the source spectrum for the used fuel application evaluation.

  17. High strain-rate model for fiber-reinforced composites

    SciTech Connect (OSTI)

    Aidun, J.B.; Addessio, F.L.

    1995-07-01

    Numerical simulations of dynamic uniaxial strain loading of fiber-reinforced composites are presented that illustrate the wide range of deformation mechanisms that can be captured using a micromechanics-based homogenization technique as the material model in existing continuum mechanics computer programs. Enhancements to the material model incorporate high strain-rate plastic response, elastic nonlinearity, and rate-dependent strength degradation due to material damage, fiber debonding, and delamination. These make the model relevant to designing composite structural components for crash safety, armor, and munitions applications.

  18. High Pressure Burn Rate Measurements on an Ammonium Perchlorate Propellant

    SciTech Connect (OSTI)

    Glascoe, E A; Tan, N

    2010-04-21

    High pressure deflagration rate measurements of a unique ammonium perchlorate (AP) based propellant are required to design the base burn motor for a Raytheon weapon system. The results of these deflagration rate measurements will be key in assessing safety and performance of the system. In particular, the system may experience transient pressures on the order of 100's of MPa (10's kPSI). Previous studies on similar AP based materials demonstrate that low pressure (e.g. P < 10 MPa or 1500 PSI) burn rates can be quite different than the elevated pressure deflagration rate measurements (see References and HPP results discussed herein), hence elevated pressure measurements are necessary in order understand the deflagration behavior under relevant conditions. Previous work on explosives have shown that at 100's of MPa some explosives will transition from a laminar burn mechanism to a convective burn mechanism in a process termed deconsolidative burning. The resulting burn rates that are orders-of-magnitude faster than the laminar burn rates. Materials that transition to the deconsolidative-convective burn mechanism at elevated pressures have been shown to be considerably more violent in confined heating experiments (i.e. cook-off scenarios). The mechanisms of propellant and explosive deflagration are extremely complex and include both chemical, and mechanical processes, hence predicting the behavior and rate of a novel material or formulation is difficult if not impossible. In this work, the AP/HTPB based material, TAL-1503 (B-2049), was burned in a constant volume apparatus in argon up to 300 MPa (ca. 44 kPSI). The burn rate and pressure were measured in-situ and used to calculate a pressure dependent burn rate. In general, the material appears to burn in a laminar fashion at these elevated pressures. The experiment was reproduced multiple times and the burn rate law using the best data is B = (0.6 {+-} 0.1) x P{sup (1.05{+-}0.02)} where B is the burn rate in mm/s and

  19. Electrochemical cell with high discharge/charge rate capability

    DOE Patents [OSTI]

    Redey, Laszlo

    1988-01-01

    A fully charged positive electrode composition for an electrochemical cell includes FeS.sub.2 and NiS.sub.2 in about equal molar amounts along with about 2-20 mole percent of the reaction product Li.sub.2 S. Through selection of appropriate electrolyte compositions, high power output or low operating temperatures can be obtained. The cell includes a substantially constant electrode impedance through most of its charge and discharge range. Exceptionally high discharge rates and overcharge protection are obtainable through use of the inventive electrode composition.

  20. Method for generating high-energy and high repetition rate laser pulses from CW amplifiers

    DOE Patents [OSTI]

    Zhang, Shukui

    2013-06-18

    A method for obtaining high-energy, high repetition rate laser pulses simultaneously using continuous wave (CW) amplifiers is described. The method provides for generating micro-joule level energy in pico-second laser pulses at Mega-hertz repetition rates.

  1. Multianode cylindrical proportional counter for high count rates

    DOE Patents [OSTI]

    Hanson, James A.; Kopp, Manfred K.

    1981-01-01

    A cylindrical, multiple-anode proportional counter is provided for counting of low-energy photons (<60 keV) at count rates of greater than 10.sup.5 counts/sec. A gas-filled proportional counter cylinder forming an outer cathode is provided with a central coaxially disposed inner cathode and a plurality of anode wires disposed in a cylindrical array in coaxial alignment with and between the inner and outer cathodes to form a virtual cylindrical anode coaxial with the inner and outer cathodes. The virtual cylindrical anode configuration improves the electron drift velocity by providing a more uniform field strength throughout the counter gas volume, thus decreasing the electron collection time following the detection of an ionizing event. This avoids pulse pile-up and coincidence losses at these high count rates. Conventional RC position encoding detection circuitry may be employed to extract the spatial information from the counter anodes.

  2. Multianode cylindrical proportional counter for high count rates

    DOE Patents [OSTI]

    Hanson, J.A.; Kopp, M.K.

    1980-05-23

    A cylindrical, multiple-anode proportional counter is provided for counting of low-energy photons (< 60 keV) at count rates of greater than 10/sup 5/ counts/sec. A gas-filled proportional counter cylinder forming an outer cathode is provided with a central coaxially disposed inner cathode and a plurality of anode wires disposed in a cylindrical array in coaxial alignment with and between the inner and outer cathodes to form a virtual cylindrical anode coaxial with the inner and outer cathodes. The virtual cylindrical anode configuration improves the electron drift velocity by providing a more uniform field strength throughout the counter gas volume, thus decreasing the electron collection time following the detection of an ionizing event. This avoids pulse pile-up and coincidence losses at these high count rates. Conventional RC position encoding detection circuitry may be employed to extract the spatial information from the counter anodes.

  3. Low resistance bakelite RPC study for high rate working capability

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dai, T.; Han, L.; Hou, S.; Liu, M.; Li, Q.; Song, H.; Xia, L.; Zhang, Z.

    2014-11-19

    This paper presents series efforts to lower resistance of bakelite electrode plate to improve the RPC capability under high rate working condition. New bakelite material with alkali metallic ion doping has been manufactured and tested. This bakelite is found unstable under large charge flux and need further investigation. A new structure of carbon-embedded bakelite RPC has been developed, which can reduce the effective resistance of electrode by a factor of 10. The prototype of the carbon-embedded chamber could function well under gamma radiation source at event rate higher than 10 kHz/cm2. The preliminary tests show that this kind of newmore » structure performs as efficiently as traditional RPCs.« less

  4. Low resistance bakelite RPC study for high rate working capability

    SciTech Connect (OSTI)

    Dai, T.; Han, L.; Hou, S.; Liu, M.; Li, Q.; Song, H.; Xia, L.; Zhang, Z.

    2014-11-19

    This paper presents series efforts to lower resistance of bakelite electrode plate to improve the RPC capability under high rate working condition. New bakelite material with alkali metallic ion doping has been manufactured and tested. This bakelite is found unstable under large charge flux and need further investigation. A new structure of carbon-embedded bakelite RPC has been developed, which can reduce the effective resistance of electrode by a factor of 10. The prototype of the carbon-embedded chamber could function well under gamma radiation source at event rate higher than 10 kHz/cm2. The preliminary tests show that this kind of new structure performs as efficiently as traditional RPCs.

  5. Diamond detector for high rate monitors of fast neutrons beams

    SciTech Connect (OSTI)

    Giacomelli, L.; Rebai, M.; Cippo, E. Perelli; Tardocchi, M.; Fazzi, A.; Andreani, C.; Pietropaolo, A.; Frost, C. D.; Rhodes, N.; Schooneveld, E.; Gorini, G.

    2012-06-19

    A fast neutron detection system suitable for high rate measurements is presented. The detector is based on a commercial high purity single crystal diamond (SDD) coupled to a fast digital data acquisition system. The detector was tested at the ISIS pulsed spallation neutron source. The SDD event signal was digitized at 1 GHz to reconstruct the deposited energy (pulse amplitude) and neutron arrival time; the event time of flight (ToF) was obtained relative to the recorded proton beam signal t{sub 0}. Fast acquisition is needed since the peak count rate is very high ({approx}800 kHz) due to the pulsed structure of the neutron beam. Measurements at ISIS indicate that three characteristics regions exist in the biparametric spectrum: i) background gamma events of low pulse amplitudes; ii) low pulse amplitude neutron events in the energy range E{sub dep}= 1.5-7 MeV ascribed to neutron elastic scattering on {sup 12}C; iii) large pulse amplitude neutron events with E{sub n} < 7 MeV ascribed to {sup 12}C(n,{alpha}){sup 9}Be and 12C(n,n')3{alpha}.

  6. Picosecond to Nanosecond Measurements at High Repetition Rate | Stanford

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synchrotron Radiation Lightsource Picosecond to Nanosecond Measurements at High Repetition Rate Since FY2012, SSRL is now scheduling three to four three-day periods each year dedicated to running SPEAR3 in hybrid low-alpha operation. In this mode the SPEAR3 ring has 1-4 camshaft pulses with very low current, and pulse duration of 5-20 picoseconds, for timing measurements. The rest of the buckets are filled to provide 100-200 mA current for other users not involved in timing experiments. The

  7. High Rate Laser Pitting Technique for Solar Cell Texturing

    SciTech Connect (OSTI)

    Hans J. Herfurth; Henrikki Pantsar

    2013-01-10

    High rate laser pitting technique for solar cell texturing Efficiency of crystalline silicon solar cells can be improved by creating a texture on the surface to increase optical absorption. Different techniques have been developed for texturing, with the current state-of-the-art (SOA) being wet chemical etching. The process has poor optical performance, produces surfaces that are difficult to passivate or contact and is relatively expensive due to the use of hazardous chemicals. This project shall develop an alternative process for texturing mc-Si using laser micromachining. It will have the following features compared to the current SOA texturing process: -Superior optical surfaces for reduced front-surface reflection and enhanced optical absorption in thin mc-Si substrates -Improved surface passivation -More easily integrated into advanced back-contact cell concepts -Reduced use of hazardous chemicals and waste treatment -Similar or lower cost The process is based on laser pitting. The objective is to develop and demonstrate a high rate laser pitting process which will exceed the rate of former laser texturing processes by a factor of ten. The laser and scanning technologies will be demonstrated on a laboratory scale, but will use inherently technologies that can easily be scaled to production rates. The drastic increase in process velocity is required for the process to be implemented as an in-line process in PV manufacturing. The project includes laser process development, development of advanced optical systems for beam manipulation and cell reflectivity and efficiency testing. An improvement of over 0.5% absolute in efficiency is anticipated after laser-based texturing. The surface textures will be characterized optically, and solar cells will be fabricated with the new laser texturing to ensure that the new process is compatible with high-efficiency cell processing. The result will be demonstration of a prototype process that is suitable for scale-up to a

  8. Engine autoignition: The relationship between octane numbers and autoignition delay times

    SciTech Connect (OSTI)

    Bradley, Derek; Head, R.A.

    2006-11-15

    The research octane (RON) and motor octane (MON) numbers, carefully measured in standardized tests, are the principal parameters for characterizing autoignition of gasoline in engines. Increasingly, engines operate under different conditions of temperature, pressure, and mixture strength from those in these tests. As a result, RON and MON values become an incomplete guide to the onset of knock, and the octane index (OI), an octane number under operational conditions, is often measured. Values of the OI were measured with different fuels in a controlled autoignition single-cylinder engine, at different initial temperatures and pressures, at the instant of 10% heat release. Fundamental understanding of engine autoignition was sought by finding the OIs of different non-primary reference fuels (non-PRFs) by identifying the corresponding PRFs that give 10% heat release under identical conditions. The autoignition delay times of the PRFs were obtained from the shock tube data, for different temperatures and pressures, of the Aachen group. It was sufficiently accurate to equate the delay time of a non-PRF to that of the corresponding PRF under the same conditions for 10% heat release. The PRFs exhibited a higher value of the inverse pressure exponent for the delay time than the non-PRFs. Together with different temperature dependencies, these gave autoignition delay times of non-PRFs that could be higher than those of their associated RONs. This tendency increased with pressure and decreased with temperature and was most marked with olefenic and toluenic fuels. This could result in values of the OI that were higher than the RON of the fuel. This is important because, for a number of evolutionary reasons, engine pressures are tending to increase and temperatures to decrease. (author)

  9. Final Report, Photocathodes for High Repetition Rate Light Sources

    SciTech Connect (OSTI)

    Ben-Zvi, Ilan

    2014-04-20

    This proposal brought together teams at Brookhaven National Laboratory (BNL), Lawrence Berkeley National Laboratory (LBNL) and Stony Brook University (SBU) to study photocathodes for high repetition rate light sources such as Free Electron Lasers (FEL) and Energy Recovery Linacs (ERL). The work done under this grant comprises a comprehensive program on critical aspects of the production of the electron beams needed for future user facilities. Our program pioneered in situ and in operando diagnostics for alkali antimonide growth. The focus is on development of photocathodes for high repetition rate Free Electron Lasers (FELs) and Energy Recovery Linacs (ERLs), including testing SRF photoguns, both normal-conducting and superconducting. Teams from BNL, LBNL and Stony Brook University (SBU) led this research, and coordinated their work over a range of topics. The work leveraged a robust infrastructure of existing facilities and the support was used for carrying out the research at these facilities. The program concentrated in three areas: a) Physics and chemistry of alkali-antimonide cathodes b) Development and testing of a diamond amplifier for photocathodes c) Tests of both cathodes in superconducting RF photoguns and copper RF photoguns

  10. High dose rate intraluminal irradiation in recurrent endobronchial carcinoma

    SciTech Connect (OSTI)

    Seagren, S.L.; Harrell, J.H.; Horn, R.A.

    1985-12-01

    Palliative therapy for previously irradiated patients with symptomatic recurrent endobronchial malignancy is a difficult problem. We have had the opportunity to treat 20 such patients with high dose rate (50-100 rad/min) endobronchial brachytherapy. Eligible patients had received previous high dose thoracic irradiation (TDF greater than or equal to 90), a performance status of greater than or equal to 50, and symptoms caused by a bronchoscopically defined and implantable lesion. The radiation is produced by a small cobalt-60 source (0.7 Ci) remotely afterloaded by cable control. The source is fed into a 4 mm diameter catheter which is placed with bronchoscopic guidance; it may oscillate if necessary to cover the lesion. A dose of 1,000 rad at 1 cm from the source is delivered. We have performed 22 procedures in 20 patients, four following YAG laser debulking. Most had cough, some with hemoptysis. Eight had dyspnea secondary to obstruction and three had obstructive pneumonitis. In 12, symptoms recurred with a mean time to recurrence of 4.3 months (range 1-9 months). Eighteen patients were followed-up and reexamined via bronchoscope 1-2.5 months following the procedure; two were lost to follow-up. All had at least 50 percent clearance of tumor, and six had complete clearance; most regressions were documented on film or videotape. In six, the palliation was durable. The procedure has been well tolerated with no toxicity. We conclude that palliative endobronchial high dose rate brachytherapy is a useful palliative modality in patients with recurrent endobronchial symptomatic carcinoma.

  11. An Experimental Investigation of Low Octane Gasoline in Diesel...

    Broader source: Energy.gov (indexed) [DOE]

    Enable Low Temperature Combustion High-Efficiency, Ultra-Low Emission Combustion in a Heavy-Duty Engine via Fuel ... of Two-Stage Combustion in Low-Emissions Diesel Engines

  12. A Detailed Chemical Kinetic Reaction Mechanism for n-Alkane Hydrocarbons From n-Octane to n-Hexadecane

    SciTech Connect (OSTI)

    Westbrook, C K; Pitz, W J; Herbinet, O; Curran, H J; Silke, E J

    2008-02-08

    Detailed chemical kinetic reaction mechanisms have been developed to describe the pyrolysis and oxidation of nine n-alkanes larger than n-heptane, including n-octane (n-C{sub 8}H{sub 18}), n-nonane (n-C{sub 9}H{sub 20}), n-decane (n-C{sub 10}H{sub 22}), n-undecane (n-C{sub 11}H{sub 24}), n-dodecane (n-C{sub 12}H{sub 26}), n-tridecane (n-C{sub 13}H{sub 28}), n-tetradecane (n-C{sub 14}H{sub 30}), n-pentadecane (n-C{sub 15}H{sub 32}), and n-hexadecane (n-C{sub 16}H{sub 34}). These mechanisms include both high temperature and low temperature reaction pathways. The mechanisms are based on our previous mechanisms for the primary reference fuels n-heptane and iso-octane, using the reaction class mechanism construction first developed for n-heptane. Individual reaction class rules are as simple as possible in order to focus on the parallelism between all of the n-alkane fuels included in the mechanisms, and these mechanisms will be refined further in the future to incorporate greater levels of accuracy and predictive capability. These mechanisms are validated through extensive comparisons between computed and experimental data from a wide variety of different sources. In addition, numerical experiments are carried out to examine features of n-alkane combustion in which the detailed mechanisms can be used to compare reactivities of different n-alkane fuels. The mechanisms for all of these n-alkanes are presented as a single detailed mechanism, which can be edited to produce efficient mechanisms for any of the n-alkanes included, and the entire mechanism, with supporting thermochemical and transport data, together with an explanatory glossary explaining notations and structural details, will be available for download from our web page.

  13. ASIC for High Rate 3D Position Sensitive Detectors

    SciTech Connect (OSTI)

    Vernon, E.; De Geronimo, G.; Ackley, K.; Fried, J.; He, Z.; Herman, C.; Zhang, F.

    2010-06-16

    We report on the development of an application specific integrated circuit (ASIC) for 3D position sensitive detectors (3D PSD). The ASIC is designed to operate with pixelated wide bandgap sensors like Cadmium-Zinc-Telluride (CZT), Mercuric Iodide (Hgl2) and Thallium Bromide (TIBr). It measures the amplitudes and timings associated with an ionizing event on 128 anodes, the anode grid, and the cathode. Each channel provides low-noise charge amplification, high-order shaping with peaking time adjustable from 250 ns to 12 {micro}s, gain adjustable to 20 mV/fC or 120 mV/fC (for a dynamic range of 3.2 MeV and 530 keV in CZT), amplitude discrimination with 5-bit trimming, and positive and negative peak and timing detections. The readout can be full or sparse, based on a flag and single- or multi-cycle token passing. All channels, triggered channels only, or triggered with neighbors can be read out thus increasing the rate capability of the system to more than 10 kcps. The ASIC dissipates 330 mW which corresponds to about 2.5 mW per channel.

  14. Substrate inhibition and control for high rate biogas production

    SciTech Connect (OSTI)

    Shin, H.S.

    1982-01-01

    This research addresses a critical aspect of the technical feasibility of biogas recovery with poultry manure using anaerobic digestion, namely, inhibition and toxicity factors limiting methane generation under high rate conditions. The research was designed to identify the limiting factors and to examine alternative pretreatment and in situ control methods for the anaerobic digestion of poultry manure as an energy producing system. Biogas production was indicated by the daily gas volume produced per unit digester capacity. Enhanced biogas generation from the anaerobic digester systems using poultry manure was studied in laboratory- and pilot-scale digester operations. It was found that ammonia nitrogen concentration above 4000 mg/l was inhibitory to biogas production. Pretreatment of the manure by elutriation was effective for decreasing inhibitory/toxic conditions. Increased gas production resulted without an indication of serious inhibition by increased volatile acids, indicating a limitation of available carbon sources. For poultry manure digestion, the optimum pH range was 7.1 to 7.6. Annual costs for pretreatment/biogas systems for 10,000, 30,000 and 50,000 birds were estimated and compared with annual surplus energy produced. The economic break-even point was achieved in digesters for greater than 30,000 birds. Capital cost of the digester system was estimated to be $18,300 with annual costs around $4000. It is anticipated that the digester system could be economically applied to smaller farms as energy costs increase.

  15. Cryogenic, high-resolution x-ray detector with high count rate capability

    DOE Patents [OSTI]

    Frank, Matthias; Mears, Carl A.; Labov, Simon E.; Hiller, Larry J.; Barfknecht, Andrew T.

    2003-03-04

    A cryogenic, high-resolution X-ray detector with high count rate capability has been invented. The new X-ray detector is based on superconducting tunnel junctions (STJs), and operates without thermal stabilization at or below 500 mK. The X-ray detector exhibits good resolution (.about.5-20 eV FWHM) for soft X-rays in the keV region, and is capable of counting at count rates of more than 20,000 counts per second (cps). Simple, FET-based charge amplifiers, current amplifiers, or conventional spectroscopy shaping amplifiers can provide the electronic readout of this X-ray detector.

  16. High-order harmonic generation using a high-repetition-rate turnkey laser

    SciTech Connect (OSTI)

    Lorek, E. Larsen, E. W.; Heyl, C. M.; Carlström, S.; Mauritsson, J.; Paleček, D.; Zigmantas, D.

    2014-12-15

    We generate high-order harmonics at high pulse repetition rates using a turnkey laser. High-order harmonics at 400 kHz are observed when argon is used as target gas. In neon, we achieve generation of photons with energies exceeding 90 eV (∼13 nm) at 20 kHz. We measure a photon flux of up to 4.4 × 10{sup 10} photons per second per harmonic in argon at 100 kHz. Many experiments employing high-order harmonics would benefit from higher repetition rates, and the user-friendly operation opens up for applications of coherent extreme ultra-violet pulses in new research areas.

  17. TRP 9904 - Constitutive Behavior of High Strength Multiphase Sheel Steel Under High Strain Rate Deformation

    SciTech Connect (OSTI)

    David Matlock; John Speer

    2005-03-31

    The focus of the research project was to systematically assess the strain rate dependence of strengthening mechanisms in new advanced high strength sheet steels. Data were obtained on specially designed and produced Duel Phase and TRIP steels and compared to the properties of automotive steels currently in use.

  18. High Rate and High Capacity Li-Ion Electrodes for Vehicular Applications

    SciTech Connect (OSTI)

    Dillon, A. C.

    2012-01-01

    Significant advances in both energy density and rate capability for Li-ion batteries are necessary for implementation in electric vehicles. We have employed two different methods to improve the rate capability of high capacity electrodes. For example, we previously demonstrated that thin film high volume expansion MoO{sub 3} nanoparticle electrodes ({approx}2 {micro}m thick) have a stable capacity of {approx}630 mAh/g, at C/2 (charge/dicharge in 2 hours). By fabricating thicker conventional electrodes, an improved reversible capacity of {approx}1000 mAh/g is achieved, but the rate capability decreases. To achieve high-rate capability, we applied a thin Al{sub 2}O{sub 3} atomic layer deposition coating to enable the high volume expansion and prevent mechanical degradation. Also, we recently reported that a thin ALD Al{sub 2}O{sub 3} coating can enable natural graphite (NG) electrodes to exhibit remarkably durable cycling at 50 C. Additionally, Al{sub 2}O{sub 3} ALD films with a thickness of 2 to 4 {angstrom} have been shown to allow LiCoO{sub 2} to exhibit 89% capacity retention after 120 charge-discharge cycles performed up to 4.5 V vs. Li/Li{sup +}. Capacity fade at this high voltage is generally caused by oxidative decomposition of the electrolyte or cobalt dissolution. We have recently fabricated full cells of NG and LiCoO{sub 2} and coated both electrodes, one or the other electrode as well as neither electrode. In creating these full cells, we observed some surprising results that lead us to obtain a greater understanding of the ALD coatings. In a different approach we have employed carbon single-wall nanotubes (SWNTs) to synthesize binder-free, high-rate capability electrodes, with 95 wt.% active materials. In one case, Fe{sub 3}O{sub 4} nanorods are employed as the active storage anode material. Recently, we have also employed this method to demonstrate improved conductivity and highly improved rate capability for a LiNi{sub 0.4}Mn{sub 0.4}Co{sub 0.2}O{sub 2

  19. Solubilities of toluene and n-octane in aqueous protosurfactant and surfactant solutions

    SciTech Connect (OSTI)

    Ho, P.C.

    1985-01-01

    The solubilities of toluene and n-octane in aqueous protosurfactant and surfactant solutins were determined at 25/sup 0/C. The protosurfactants studied are sodium salts of cyclohexanecarboxylic acid, 2,5-diisopropylbenzenesulfonic acid, and 3,5-diisopropyisalicylic acid. Each of them has six alkyl carbons (S /SUB AC/ =6) and does not form micelles in water. The two micelle-forming surfactants used are sodium n-hexanoate with six alkyl carbons (S /SUB AC/ =6) and sodium n-octanoate with eight alkyl carbons (S /SUB AC/ =8). In three-component systems of toluene or n-octane with water and organic salt (either protosurfactant or surfactant), the solubility of the hydrocarbon in the aqueous phase increases as the number of alkyl carbons of the organic salt and as the aqueous concentration of the organic salt increases. However, in this study we found that sodium 3,5-diisopropyisalicylate causes much more pronounced increases in hydrocarbon solubility than these two surfactants. Sodium 2,5-diisopropylbenzenesulfonate, although not as effective in solubilization as the salicylate, has much stronger hydrotropic properties for hydrocarbons than either of these two surfactants. Sodium cyclohexanoate, with a compact arrangement of the six alkyl carbons, shows a higher hydrotropic effect than sodium n-hexanoate.

  20. High heating rate thermal desorption for molecular surface sampling

    DOE Patents [OSTI]

    Ovchinnikova, Olga S.; Van Berkel, Gary J.

    2016-03-29

    A method for analyzing a sample having at least one analyte includes the step of heating the sample at a rate of at least 10.sup.6 K/s to thermally desorb at least one analyte from the sample. The desorbed analyte is collected. The analyte can then be analyzed.

  1. High Strain Rate Tensile Testing of DOP-26 Iridium

    SciTech Connect (OSTI)

    Schneibel, Joachim H; Carmichael Jr, Cecil Albert; George, Easo P

    2007-11-01

    The iridium alloy DOP-26 was developed through the Radioisotope Power Systems Program in the Office of Nuclear Energy of the Department of Energy. It is used for clad vent set cups containing radioactive fuel in radioisotope thermoelectric generator (RTG) heat sources which provide electric power for spacecraft. This report describes mechanical testing results for DOP-26. Specimens were given a vacuum recrystallization anneal of 1 hour at 1375 C and tested in tension in orientations parallel and perpendicular to the rolling direction of the sheet from which they were fabricated. The tests were performed at temperatures ranging from room temperature to 1090 C and strain rates ranging from 1 x 10{sup -3} to 50 s{sup -1}. Room temperature testing was performed in air, while testing at elevated temperatures was performed in a vacuum better than 1 x 10{sup -4} Torr. The yield stress (YS) and the ultimate tensile stress (UTS) decreased with increasing temperature and increased with increasing strain rate. Between 600 and 1090 C, the ductility showed a slight increase with increasing temperature. Within the scatter of the data, the ductility did not depend on the strain rate. The reduction in area (RA), on the other hand, decreased with increasing strain rate. The YS and UTS values did not differ significantly for the longitudinal and transverse specimens. The ductility and RA values of the transverse specimens were marginally lower than those of the longitudinal specimens.

  2. High Metal Removal Rate Process for Machining Difficult Materials

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Titanium Alloy Production ADVANCED MANUFACTURING OFFICE Low-Cost Titanium Alloy Production Titanium for Energy Efficient Mechanical Systems. Titanium (Ti) is highly valued for its ...

  3. Electrochemical and rate performance study of high-voltagelithium...

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Journal Article: ... Citation Details In-Document Search Title: Electrochemical ... We report electrochemical studies of high voltage cathodes ...

  4. High Metal Removal Rate Process for Machining Difficult Materials

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to 10 times higher than lithium-ion), using raw materials that are low cost or even free. ... that PLE-based batteries can be manufactured and scaled to high-volume production. ...

  5. High Metal Removal Rate Process for Machining Difficult Materials

    Broader source: Energy.gov [DOE]

    The goal of the project is to develop an automated, ultrafast laser machining device that will be used to prototype GDI injectors. The platform will turn CAD drawings into high-precision prototypes.

  6. High-Field High-Repetition-Rate Sources for the Coherent THz Control of Matter

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Green, B.; Kovalev, S.; Asgekar, V.; Geloni, G.; Lehnert, U.; Golz, T.; Kuntzsch, M.; Bauer, C.; Hauser, J.; Voigtlaender, J.; et al

    2016-02-29

    Ultrashort flashes of THz light with low photon energies of a few meV, but strong electric or magnetic field transients have recently been employed to prepare various fascinating nonequilibrium states in matter. Here we present a new class of sources based on superradiant enhancement of radiation from relativistic electron bunches in a compact electron accelerator that we believe will revolutionize experiments in this field. Our prototype source generates high-field THz pulses at unprecedented quasi-continuous-wave repetition rates up to the MHz regime. We demonstrate parameters that exceed state-of-the-art laser-based sources by more than 2 orders of magnitude. The peak fields andmore » the repetition rates are highly scalable and once fully operational this type of sources will routinely provide 1 MV/cm electric fields and 0.3 T magnetic fields at repetition rates of few 100 kHz. In conclusion, we benchmark the unique properties by performing a resonant coherent THz control experiment with few 10 fs resolution.« less

  7. High frame-rate, large field wavefront sensor

    SciTech Connect (OSTI)

    Avicola, K.; Salmon, J.T.; Brase, J.; Waltjen, K.; Presta, R.; Balch, K.S.

    1992-03-01

    A two-stage intensified 192 {times} 239 pixel imager developed by Eastman Kodak for motion analysis was used to construct a 1 kHz frame-rate Hartmann wavefront sensor. The sensor uses a monolithic array of lenslets with a focal length that is adjusted by an index fluid between the convex surface and an optical flat. The accuracy of the calculated centroid position, which is related to wavefront measurement accuracy, was obtained as a function of spot power and spot size. The sensor was then dynamically tested at a 1 kHz frame-rate with a 9 {times} 9 lenslet array and a fast steering mirror, which swept a plane wavefront across the wavefront sensor. An 8 cm diameter subaperture will provide a return signal (589 nm) level of about 1000 photons/ms using the AVLIS 1 kW laser (stretched pulse) as guide star source, which is sufficient to yield a wavefront measurement of better than {gamma}/10 rms. If an area of 6 {times} 6 pixels per Hartmann spot were allocated, this wavefront sensor could support a 32 {times} 32, or 1024, element deformable mirror.

  8. Raw material preparation for ultra high production rate sintering

    SciTech Connect (OSTI)

    Kortmann, H.A.; Ritz, V.J.; Cappel, F.; Weisel, H.; Richter, G.

    1995-12-01

    An R and D program in pot grate sintering showed, that an intensive preparation of ores, additives and coke breeze improves the sintering capacity. The tests were conducted using an ore mixture composed of typical ores imported to Europe. The highest capacities were attained up to 63.8 t/m{sup 2} {times} 24 h maximum for a sinter which well fulfills the high requirements on chemical, physical and metallurgical properties.

  9. A comprehensive detailed chemical kinetic reaction mechanism for combustion of n-alkane hydrocarbons from n-octane to n-hexadecane

    SciTech Connect (OSTI)

    Westbrook, Charles K.; Pitz, William J.; Herbinet, Olivier; Silke, Emma J.; Curran, Henry J.

    2009-01-15

    Detailed chemical kinetic reaction mechanisms have been developed to describe the pyrolysis and oxidation of nine n-alkanes larger than n-heptane, including n-octane (n-C{sub 8}H{sub 18}), n-nonane (n-C{sub 9}H{sub 20}), n-decane (n-C{sub 10}H{sub 22}), n-undecane (n-C{sub 11}H{sub 24}), n-dodecane (n-C{sub 12}H{sub 26}), n-tridecane (n-C{sub 13}H{sub 28}), n-tetradecane (n-C{sub 14}H{sub 30}), n-pentadecane (n-C{sub 15}H{sub 32}), and n-hexadecane (n-C{sub 16}H{sub 34}). These mechanisms include both high temperature and low temperature reaction pathways. The mechanisms are based on previous mechanisms for the primary reference fuels n-heptane and iso-octane, using the reaction classes first developed for n-heptane. Individual reaction class rules are as simple as possible in order to focus on the parallelism between all of the n-alkane fuels included in the mechanisms. These mechanisms are validated through extensive comparisons between computed and experimental data from a wide variety of different sources. In addition, numerical experiments are carried out to examine features of n-alkane combustion in which the detailed mechanisms can be used to compare reactivities of different n-alkane fuels. The mechanisms for these n-alkanes are presented as a single detailed mechanism, which can be edited to produce efficient mechanisms for any of the n-alkanes included, and the entire mechanism, with supporting thermochemical and transport data, together with an explanatory glossary explaining notations and structural details, is available for download from our web page. (author)

  10. High Rate Deposition of High Quality ZnO:Al by Filtered Cathodic Arc

    SciTech Connect (OSTI)

    Mendelsberg, Rueben J.; Lim, S.H.N.; Milliron, D.J.; Anders, Andre

    2010-11-18

    High quality ZnO:Al (AZO) thin films were prepared on glass substrates by direct current filtered cathodic arc deposition. Substrate temperature was varied from room temperature to 425oC, and samples were grown with and without the assistance of low power oxygen plasma (75W). For each growth condition, at least 3 samples were grown to give a statistical look at the effect of the growth environment on the film properties and to explore the reproducibility of the technique. Growth rate was in the 100-400 nm/min range but was apparently random and could not be easily traced to the growth conditions explored. For optimized growth conditions, 300-600 nm AZO films had resistivities of 3-6 x 10-4 ?Omega cm, carrier concentrations in the range of 2-4 x 1020 cm3, Hall mobility as high as 55 cm2/Vs, and optical transmittance greater than 90percent. These films are also highly oriented with the c-axis perpendicular to the substrate and a surface roughness of 2-4 nm.

  11. A Long-Life, High-Rate Lithium/Sulfur Cell: A Multifaceted Approach...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Long-Life, High-Rate LithiumSulfur Cell: A Multifaceted Approach to Enhancing Cell Performance Min-Kyu Song, , Yuegang Zhang,* ,, and Elton J. Cairns* ,, The...

  12. Recent federal initiatives to promote unconventional gas: High octane delivery of just hot air?

    SciTech Connect (OSTI)

    Griff, M.T.

    1995-10-01

    This paper provides an overview of recent initiatives of the United States which promote greater use of natural gas and unconventional gas as one part of this nations`s larger response to the global warming threat. Measurable increases in greenhouse gas concentrations since the beginning of the industrial revolution have led to the belief in the existence of a global warming problem. The international community has responded to the global warming threat with the United Nations Framework Convention on Climate Change which is directed toward the stabilization of greenhouse gases in the atmosphere. The Climate Change Action Plan is the Clinton Administration`s detailed response to the global warming threat. It is designed to return United States emissions of greenhouse gases to their 1990 levels by the year 2000. The Action Plan targets all greenhouse gases and emphasizes energy efficiency. Significant regulatory reformation designed to increase the efficiency of the natural gas industry has already occurred and will be continued. Recovery of methane emissions from landfills will be encouraged through indentification of suitable sites and use of existing technology and development of new technology. Recovery of methane from coal mining operations will be promoted by targeting 50 of the gassiest mines in the United States. Even if the Action Plan is fully implemented. legitimate questions arise as to whether its goals will be achieved as a result of funding shortfalls.

  13. A Detailed Chemical Kinetic Reaction Mechanism for n-Alkane Hydrocarbons from n-Octane to n-Hexadecane

    SciTech Connect (OSTI)

    Westbrook, C K; Pitz, W J; Herbinet, O; Silke, E J; Curran, H J

    2007-09-25

    Detailed chemical kinetic reaction mechanisms have been developed to describe the pyrolysis and oxidation of the n-alkanes, including n-octane (n-C{sub 8}H{sub 18}), n-nonane (n-C{sub 9}H{sub 20}), n-decane (n-C{sub 10}H{sub 22}), n-undecane (n-C{sub 11}H{sub 24}), n-dodecane (n-C{sub 12}H{sub 26}), n-tridecane (n-C{sub 13}H{sub 28}), n-tetradecane (n-C{sub 14}H{sub 30}), n-pentadecane (n-C{sub 15}H{sub 32}), and n-hexadecane (n-C{sub 16}H{sub 34}). These mechanisms include both high temperature and low temperature reaction pathways. The mechanisms are based on previous mechanisms for n-heptane, using the same reaction class mechanism construction developed initially for n-heptane. Individual reaction class rules are as simple as possible in order to focus on the parallelism between all of the n-alkane fuels included in the mechanisms, and there is an intent to develop these mechanisms further in the future to incorporate greater levels of accuracy and predictive capability. Several of these areas for improvement are identified and explained in detail. These mechanisms are validated through comparisons between computed and experimental data from as many different sources as possible. In addition, numerical experiments are carried out to examine features of n-alkane combustion in which the detailed mechanisms can be used to compare processes in all of the n-alkane fuels. The mechanisms for all of these n-alkanes are presented as a single detailed mechanism, which can be edited to produce efficient mechanisms for any of the n-alkanes included, and the entire mechanism, with supporting thermochemical and transport data, together with an explanatory glossary explaining notations and structural details, will be available on our web page when the paper is accepted for publication.

  14. Workshop: Time Resolved X-Ray Science at High Repetition Rate | Stanford

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synchrotron Radiation Lightsource Time Resolved X-Ray Science at High Repetition Rate Saturday, October 22, 2011 - 8:30am SSRL Conference Room 137-322 In conjunction with the 2011 LCLS/SSRL User Meeting, SSRL and the APS will jointly host a two-day workshop focused on opportunities with short-pulse, high-repetition rate X-ray Science. The workshop will feature international speakers and panel experts presenting the scientific basis, preliminary results and future potential of high rep-rate

  15. An Improved Reaction Rate Equation for Simulating the Ignition and Growth of Reaction in High Explosives

    SciTech Connect (OSTI)

    Murphy, M J

    2010-03-08

    We describe an improved reaction rate equation for simulating ignition and growth of reaction in high explosives. It has been implemented into CALE and ALE3D as an alternate to the baseline the Lee-Tarver reactive flow model. The reactive flow model treats the explosive in two phases (unreacted/reactants and reacted/products) with a reaction rate equation to determine the fraction reacted, F. The improved rate equation has fewer parameters, is continuous with continuous derivative, results in a unique set of reaction rate parameters for each explosive while providing the same functionality as the baseline rate equation. The improved rate equation uses a cosine function in the ignition term and a sine function in the growth and completion terms. The improved rate equation is simpler with fewer parameters.

  16. Centerra Earns High Performance Rating for Savannah River Site Security Operations

    Broader source: Energy.gov [DOE]

    AIKEN, S.C. – The Savannah River Site (SRS) security contractor Centerra received high performance ratings from DOE in fiscal year 2015, earning $5,280,546 of the available $5,739,724 fee.

  17. Mechanical and microstructural response of Ni sub 3 Al at high strain rate and elevated temperatures

    SciTech Connect (OSTI)

    Sizek, H.W.; Gray, G.T. III.

    1990-01-01

    In this paper, the effect of strain rate and temperature on the substructure evolution and mechanical response of Ni{sub 3}Al will be presented. The strain rate response of Ni{sub 3}Al was studied at strain rates from 10{sup {minus}3} s{sup {minus}1} (quasi-static) to 10{sup 4} s{sup {minus}1} using a Split Hopkinson Pressure Bar. The Hopkinson Bar tests were conducted at temperatures ranging from 77K to 1273K. At high strain rates the flow strength increased significantly with increasing temperature, similar to the behavior observed at quasi-static rates. The work hardening rates increased with strain rate and varied with temperatures. The work hardening rates, appeared to be significantly higher than those found for Ni270. The substructure evolution was characterized utilizing TEM. The defect generation and rate sensitivity of Ni{sub 3}Al are also discussed as a function of strain rate and temperature. 15 refs., 4 figs.

  18. High-order harmonic generation at a repetition rate of 100 kHz

    SciTech Connect (OSTI)

    Lindner, F.; Stremme, W.; Schaetzel, M. G.; Grasbon, F.; Paulus, G. G.; Walther, H.; Hartmann, R.; Strueder, L.

    2003-07-01

    We report high-order harmonic generation (HHG) in rare gases using a femtosecond laser system with a very high repetition rate (100 kHz) and low pulse energy (7 {mu}J). To our knowledge, this is the highest repetition rate reported to date for HHG. The tight focusing geometry required to reach sufficiently high intensities implies low efficiency of the process. Harmonics up to the 45th order are nevertheless generated and detected. We show evidence of clear separation and selection of quantum trajectories by moving the gas jet with respect to the focus, in agreement with the theoretical predictions of the semiclassical model of HHG.

  19. Dual-axis high-data-rate atom interferometer via cold ensemble exchange

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Journal Article: Dual-axis high-data-rate atom interferometer via cold ensemble exchange Citation Details In-Document Search Title: Dual-axis high-data-rate atom interferometer via cold ensemble exchange We demonstrate a dual-axis accelerometer and gyroscope atom interferometer, which can form the building blocks of a six-axis inertial measurement unit. By recapturing the atoms after the interferometer sequence, we maintain a large atom number at high data

  20. Transient x-ray diffraction with simultaneous imaging under high strain-rate loading

    SciTech Connect (OSTI)

    Fan, D.; E, J. C.; Zhao, F.; Luo, S. N.; Lu, L.; Li, B.; Qi, M. L.; Sun, T.; Fezzaa, K.; Chen, W.

    2014-11-15

    Real time, in situ, multiframe, diffraction, and imaging measurements on bulk samples under high and ultrahigh strain-rate loading are highly desirable for micro- and mesoscale sciences. We present an experimental demonstration of multiframe transient x-ray diffraction (TXD) along with simultaneous imaging under high strain-rate loading at the Advanced Photon Source beamline 32ID. The feasibility study utilizes high strain-rate Hopkinson bar loading on a Mg alloy. The exposure time in TXD is 2–3 μs, and the frame interval is 26.7–62.5 μs. Various dynamic deformation mechanisms are revealed by TXD, including lattice expansion or compression, crystal plasticity, grain or lattice rotation, and likely grain refinement, as well as considerable anisotropy in deformation. Dynamic strain fields are mapped via x-ray digital image correlation, and are consistent with the diffraction measurements and loading histories.

  1. High Rate and Stable Cycling of Lithium Metal Anode - Joint Center for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Storage Research November 10, 2014, Research Highlights High Rate and Stable Cycling of Lithium Metal Anode Coulombic efficiency (CE) of Li plating/stripping is > 99.1% in concentrated LiFSI-DME electrolyte Scientific Achievement Lithium metal is an ideal battery anode. However, dendrite growth and limited CE during cycling have limited its practical applications. High CE (up to 99.1%) without dendrite growth is achieved by using highly concentrated electrolytes for lithium

  2. Operational results for high pulverized coal injection rate at Kimitsu No. 3 blast furnace

    SciTech Connect (OSTI)

    Ueno, Hiromitsu; Matsunaga, Shin`ichi; Kakuichi, Kazumoto; Amano, Shigeru; Yamaguchi, Kazuyoshi

    1995-12-01

    In order to further develop the technology for high-rate pulverized coal injection (PCI), namely over 200 kg/t-pig, Nippon Steel performed a high injection rate test at the Kimitsu No. 3 blast furnace in November, 1993. The paper describes PCI equipment; the operational design of the test, including blast conditions, reducibility of sinter, coke strength and burden distribution; and test results. These results include a discussion of the transition of operation, burden distribution control, replacement ratio of coke, permeability at upper and lower parts of the furnace, reducibility at lower part of the furnace, accumulation of fines in the deadman, and generation and accumulation of unburnt char. Stable operation was achieved at a PCI rate of 190 kg/t-pig. With injection rates between 200--300 kg/t-pig, the problem becomes how to improve the reduction-meltdown behavior in the lower part of the furnace.

  3. Deflagration Rate Measurements of Three Insensitive High Explosives: LLM-105, TATB, and DAAF

    SciTech Connect (OSTI)

    Glascoe, E A; Maienschein, J L; Lorenz, K T; Tan, N; Koerner, J G

    2010-03-08

    The pressure dependent deflagration rates of LLM-105, DAAF and TATB based formulations were measured in the LLNL high pressure strand burner. The role of binder amount, explosive type, and thermal damage and their effects on the deflagration rate will be discussed. One DAAF formulation, two different formulations of LLM-105, and four formulations of TATB were studied; results indicate that binder amount and type play a minor role in the deflagration behavior. This is in sharp contrast to the HMX based formulations which strongly depend on binder amount and type. The effect of preheating these samples was considerably more dramatic. In the case of LLM-105, preheating the sample appears to have little effect on the deflagration rate. In contrast, preheating DAAF and TATB formulations causes the deflagration rate to accelerate. The thermal and mechanical properties of these formulations will be discussed in the context of their pressure and temperature dependent deflagration rates.

  4. Room temperature single-photon detectors for high bit rate quantum key distribution

    SciTech Connect (OSTI)

    Comandar, L. C.; Patel, K. A.; Frhlich, B. Lucamarini, M.; Sharpe, A. W.; Dynes, J. F.; Yuan, Z. L.; Shields, A. J.; Penty, R. V.

    2014-01-13

    We report room temperature operation of telecom wavelength single-photon detectors for high bit rate quantum key distribution (QKD). Room temperature operation is achieved using InGaAs avalanche photodiodes integrated with electronics based on the self-differencing technique that increases avalanche discrimination sensitivity. Despite using room temperature detectors, we demonstrate QKD with record secure bit rates over a range of fiber lengths (e.g., 1.26 Mbit/s over 50?km). Furthermore, our results indicate that operating the detectors at room temperature increases the secure bit rate for short distances.

  5. Isotopic Analysis of Spent Nuclear Fuel with an Ultra-High Rate HPGe Spectrometer

    SciTech Connect (OSTI)

    Fast, James E.; Glasgow, Brian D.; Rodriguez, Douglas C.; VanDevender, Brent A.; Wood, Lynn S.

    2014-06-06

    A longstanding challenge is the assay of spent nuclear fuel (SNF). Determining the isotopic content of SNF requires gamma-ray spectroscopy. PNNL has developed new digital filtering and analysis techniques to produce an ultra high-rate gamma-ray spectrometer from a standard coaxial high-purity germanium (HPGe) crystal. This ~40% efficient detector has been operated for SNF measurements at a throughput of about 400k gamma-ray counts per second (kcps) at an input rate of 1.3 Mcps. Optimized filtering algorithms preserve the spectroscopic capability of the system even at these high rates. This talk will present the results of a SNF measurement with aged SNF pellets at PNNL’s Radiochemical Processing Laboratory, first results with a FPGA front end processor capable of processing the data in real time, and the development path toward a multi-element system to assay fuel assemblies.

  6. Injector Beam Dynamics for a High-Repetition Rate 4th-Generation Light Source

    SciTech Connect (OSTI)

    Papadopoulos, C. F.; Corlett, J.; Emma, P.; Filippetto, D.; Penn, G.; Qiang, J.; Reinsch, M.; Sannibale, F.; Steier, C.; Venturini, M.; Wells, R.

    2013-05-20

    We report on the beam dynamics studies and optimization methods for a high repetition rate (1 MHz) photoinjector based on a VHF normal conducting electron source. The simultaneous goals of beamcompression and reservation of 6-dimensional beam brightness have to be achieved in the injector, in order to accommodate a linac driven FEL light source. For this, a parallel, multiobjective optimization algorithm is used. We discuss the relative merits of different injector design points, as well as the constraints imposed on the beam dynamics by technical considerations such as the high repetition rate.

  7. High rate chemical vapor deposition of carbon films using fluorinated gases

    DOE Patents [OSTI]

    Stafford, Byron L.; Tracy, C. Edwin; Benson, David K.; Nelson, Arthur J.

    1993-01-01

    A high rate, low-temperature deposition of amorphous carbon films is produced by PE-CVD in the presence of a fluorinated or other halide gas. The deposition can be performed at less than 100.degree. C., including ambient room temperature, with a radio frequency plasma assisted chemical vapor deposition process. With less than 6.5 atomic percent fluorine incorporated into the amorphous carbon film, the characteristics of the carbon film, including index of refraction, mass density, optical clarity, and chemical resistance are within fifteen percent (15%) of those characteristics for pure amorphous carbon films, but the deposition rates are high.

  8. Radiation bronchitis and stenosis secondary to high dose rate endobronchial irradiation

    SciTech Connect (OSTI)

    Speiser, B.L. ); Spratling, L.

    1993-03-15

    The purpose of the study was to describe a new clinical entity observed in follow-up bronchoscopies in patients who were treated with high dose rate and medium dose rate remote afterloading brachytherapy of the tracheobronchial tree. Patients were treated by protocol with medium dose rate, 47 patients receiving 1000 cGy at a 5 mm depth times three fractions, high dose rate 144 patients receiving 1000 cGy at a 10 mm depth for three fractions and high dose rate 151 patients receiving cGy at a 10 mm depth for three fractions followed by bronchoscopy. Incidence of this entity was 9% for the first group, 12% for the second, and 13% for the third group. Reactions were grade 1 consisting of mild inflammatory response with a partial whitish circumferential membrane in an asymptomatic patient; grade 2, thicker complete white circumferential membrane with cough and/or obstructive problems requiring intervention; grade 3, severe inflammatory response with marked membranous exudate and mild fibrotic reaction; and grade 4 a predominant fibrotic reaction with progressive stenosis. Variables associated with a slightly increased incidence of radiation bronchitis and stenosis included: large cell carcinoma histology, curative intent, prior laser photoresection, and/or concurrent external radiation. Survival was the strongest predictor of the reaction. Radiation bronchitis and stenosis is a new clinical entity that must be identified in bronchial brachytherapy patients and treated appropriately. 23 refs., 3 figs., 7 tabs.

  9. An optical parametric chirped-pulse amplifier for seeding high repetition rate free-electron lasers

    SciTech Connect (OSTI)

    Höppner, H.; Tanikawa, T.; Schulz, M.; Riedel, R.; Teubner, U.; Faatz, B.; Tavella, F.

    2015-05-15

    High repetition rate free-electron lasers (FEL), producing highly intense extreme ultraviolet and x-ray pulses, require new high power tunable femtosecond lasers for FEL seeding and FEL pump-probe experiments. A tunable, 112 W (burst mode) optical parametric chirped-pulse amplifier (OPCPA) is demonstrated with center frequencies ranging from 720–900 nm, pulse energies up to 1.12 mJ and a pulse duration of 30 fs at a repetition rate of 100 kHz. Since the power scalability of this OPCPA is limited by the OPCPA-pump amplifier, we also demonstrate a 6.7–13.7 kW (burst mode) thin-disk OPCPA-pump amplifier, increasing the possible OPCPA output power to many hundreds of watts. Furthermore, third and fourth harmonic generation experiments are performed and the results are used to simulate a seeded FEL with high-gain harmonic generation.

  10. High power pulsed magnetron sputtering: A method to increase deposition rate

    SciTech Connect (OSTI)

    Raman, Priya McLain, Jake; Ruzic, David N; Shchelkanov, Ivan A.

    2015-05-15

    High power pulsed magnetron sputtering (HPPMS) is a state-of-the-art physical vapor deposition technique with several industrial applications. One of the main disadvantages of this process is its low deposition rate. In this work, the authors report a new magnetic field configuration, which produces deposition rates twice that of conventional magnetron's dipole magnetic field configuration. Three different magnet pack configurations are discussed in this paper, and an optimized magnet pack configuration for HPPMS that leads to a higher deposition rate and nearly full-face target erosion is presented. The discussed magnetic field produced by a specially designed magnet assembly is of the same size as the conventional magnet assembly and requires no external fields. Comparison of deposition rates with different power supplies and the electron trapping efficiency in complex magnetic field arrangements are discussed.

  11. Device for testing closure disks at high rates of change of pressure

    DOE Patents [OSTI]

    Merten, Jr., Charles W.

    1993-11-09

    A device for testing the burst pressure of closure disks which provides high pressure to both sides of a disk and rapidly releases pressure from one side thereof causing a high rate of change of pressure. A hollow notched plug allows the rapid release of pressure upon rupturing. A means is also disclosed for transmitting a tensile load from a piston to a hollow notched plug and for sealing the means for transmitting load within a hole in a piston.

  12. Low-mass, high-rate cylindrical MWPC's for the MEGA experiment

    SciTech Connect (OSTI)

    Mischke, R.E.; Armijo, V.; Black, J.K.; Bolton, R.D.; Carius, S.; Cooper, M.D.; Espinoza, C.; Hart, G.W.; Hogan, G.E.; Piilonen, L.E.; Sandoval, J.; Schilling, S.; Sena, J.; Stanislaus, S.; Suazo, G.; Szymanski, J.J.; Whitehouse, D.A.; Wilkinson, C.A. ); Fisk, R.; Koetke, D.D.; Manweiler, R.W. ); Jui, C. )

    1990-01-01

    The construction of MWPCs for the MEGA experiment at LAMPF are described. The chambers are cylindrical, low mass (3 {times} 10{sup {minus}4} radiation lengths), and are designed to operate at high rates (3 {times} 10{sup 4} /mm{sup 2}/s). Several novel construction techniques have been developed and custom electronics have been designed to help achieve the required performance, which corresponds to that needed at high luminosity colliders. 4 refs., 3 figs.

  13. A method to quench and recharge avalanche photo diodes for use in high rate situations

    SciTech Connect (OSTI)

    Regan, T.O.; Fenker, H.C.; Thomas, J.; Oliver, J.

    1992-06-01

    We present a new method of using Avalanche Photo Diodes (APDS) for low level light detection in Geiger mode in high rate situations such as those encountered at the Superconducting Super Collider (SSC). The new technique is readily adaptable to implementation in CMOS VLSI.

  14. Figure 7. Projected Production for the High Development Rate of Technically

    U.S. Energy Information Administration (EIA) Indexed Site

    Recoverable Oil 7. Projected Production for the High Development Rate of Technically Recoverable Oil Estimated at 5 Percent, Mean, and 95 Percent Probabilities for the ANWR Coastal Plain of the Alaska North Slope fig7.jpg (43335 bytes) Source

  15. High-Purity Germanium Spectroscopy at Rates in Excess of 10^{6} Events/s

    SciTech Connect (OSTI)

    VanDevender, Brent A.; Dion, Michael P.; Fast, James E.; Rodriguez, Douglas C.; Taubman, Matthew S.; Wilen, Christopher D.; Wood, Lynn S.; Wright, Michael E.

    2014-10-01

    AbstractIn gamma spectroscopy, a compromise must be made between energy resolution and event-rate capability. Some foreseen nuclear material safeguards applications require a spectrometer with energy resolution typical of high purity germanium (HPGe) detectors, operated at rates up to and exceeding 106 events per second. We report the performance of an HPGe spectrometer adapted to run at such rates. Our system consists of a commercial semi-coaxial HPGe detector, a modified high-voltagerail, resistive-feedback, charge-sensitive preamplifier and a continuous waveform digitizer. Digitized waveforms are analyzed offline with a novel time-variant trapezoidal filter algorithm. Several time-invariant trapezoidal filters are run in parallel and the slowest one not rejected by instantaneous pileup conditions is used to measure each pulse height. We have attained full-widthat- half-maximum energy resolution of less than 8 keV measured at 662 keV with 1:08*106 per second incoming event rate and 38% throughput. An additional constraint on the width of the fast trigger filter removes a significant amount of edge pileup that passes the first pileup cut, reducing throughput to 26%. While better resolution has been reported by other authors, our throughput is over an order of magnitude higher than any other reported HPGe system operated at such an event rate.

  16. Ultrashort pulse high repetition rate laser system for biological tissue processing

    DOE Patents [OSTI]

    Neev, J.; Da Silva, L.B.; Matthews, D.L.; Glinsky, M.E.; Stuart, B.C.; Perry, M.D.; Feit, M.D.; Rubenchik, A.M.

    1998-02-24

    A method and apparatus are disclosed for fast, efficient, precise and damage-free biological tissue removal using an ultrashort pulse duration laser system operating at high pulse repetition rates. The duration of each laser pulse is on the order of about 1 fs to less than 50 ps such that energy deposition is localized in a small depth and occurs before significant hydrodynamic motion and thermal conduction, leading to collateral damage, can take place. The depth of material removed per pulse is on the order of about 1 micrometer, and the minimal thermal and mechanical effects associated with this ablation method allows for high repetition rate operation, in the region 10 to over 1000 Hertz, which, in turn, achieves high material removal rates. The input laser energy per ablated volume of tissue is small, and the energy density required to ablate material decreases with decreasing pulse width. The ablation threshold and ablation rate are only weakly dependent on tissue type and condition, allowing for maximum flexibility of use in various biological tissue removal applications. The use of a chirped-pulse amplified Titanium-doped sapphire laser is disclosed as the source in one embodiment. 8 figs.

  17. Ultrashort pulse high repetition rate laser system for biological tissue processing

    DOE Patents [OSTI]

    Neev, Joseph; Da Silva, Luiz B.; Matthews, Dennis L.; Glinsky, Michael E.; Stuart, Brent C.; Perry, Michael D.; Feit, Michael D.; Rubenchik, Alexander M.

    1998-01-01

    A method and apparatus is disclosed for fast, efficient, precise and damage-free biological tissue removal using an ultrashort pulse duration laser system operating at high pulse repetition rates. The duration of each laser pulse is on the order of about 1 fs to less than 50 ps such that energy deposition is localized in a small depth and occurs before significant hydrodynamic motion and thermal conduction, leading to collateral damage, can take place. The depth of material removed per pulse is on the order of about 1 micrometer, and the minimal thermal and mechanical effects associated with this ablation method allows for high repetition rate operation, in the region 10 to over 1000 Hertz, which, in turn, achieves high material removal rates. The input laser energy per ablated volume of tissue is small, and the energy density required to ablate material decreases with decreasing pulse width. The ablation threshold and ablation rate are only weakly dependent on tissue type and condition, allowing for maximum flexibility of use in various biological tissue removal applications. The use of a chirped-pulse amplified Titanium-doped sapphire laser is disclosed as the source in one embodiment.

  18. Gas Dynamics in an X-ray FEL Gas Attenuator under High Repetition Rate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Operation | Stanford Synchrotron Radiation Lightsource Gas Dynamics in an X-ray FEL Gas Attenuator under High Repetition Rate Operation Wednesday, August 17, 2016 - 3:00pm SLAC, Redtail Hawk Conference Room 108A Speaker: Bo Yang, Department of Mechanical Engineering, University of Texas at Arlington Program Description The LCLS-II project seeks to increase the repetition rate of the LCLS X-ray Free-Electron Laser by many orders, up to 1 MHz from the current 120 Hz maximum. It calls into

  19. High-Dose-Rate Brachytherapy Alone for Localized Prostate Cancer in Patients at Moderate or High Risk of Biochemical Recurrence

    SciTech Connect (OSTI)

    Hoskin, Peter; Rojas, Ana; Lowe, Gerry; Bryant, Linda; Ostler, Peter; Hughes, Rob; Milner, Jessica; Cladd, Helen

    2012-03-15

    Purpose: To evaluate genitourinary (GU) and gastrointestinal (GI) morbidity and biochemical control of disease in patients with localized prostate adenocarcinoma treated with escalating doses per fraction of high-dose rate brachytherapy alone. Methods and Materials: A total of 197 patients were treated with 34 Gy in four fractions, 36 Gy in four fractions, 31.5 Gy in three fractions, or 26 Gy in two fractions. Median follow-up times were 60, 54, 36, and 6 months, respectively. Results: Incidence of early Grade {>=} 3 GU morbidity was 3% to 7%, and Grade 4 was 0% to 4%. During the first 12 weeks, the highest mean International Prostate Symptom Score (IPSS) value was 14, and between 6 months and 5 years it was 8. Grade 3 or 4 early GI morbidity was not observed. The 3-year actuarial rate of Grade 3 GU was 3% to 16%, and was 3% to 7% for strictures requiring surgery (4-year rate). An incidence of 1% Grade 3 GI events was seen at 3 years. Late Grade 4 GU or GI events were not observed. At 3 years, 99% of patients with intermediate-risk and 91% with high-risk disease were free of biochemical relapse (log-rank p = 0.02). Conclusions: There was no significant difference in urinary and rectal morbidity between schedules. Biochemical control of disease in patients with intermediate and high risk of relapse was good.

  20. High-rate Plastic Deformation of Nanocrystalline Tantalum to Large Strains: Molecular Dynamics Simulation

    SciTech Connect (OSTI)

    Rudd, R E

    2009-02-05

    Recent advances in the ability to generate extremes of pressure and temperature in dynamic experiments and to probe the response of materials has motivated the need for special materials optimized for those conditions as well as a need for a much deeper understanding of the behavior of materials subjected to high pressure and/or temperature. Of particular importance is the understanding of rate effects at the extremely high rates encountered in those experiments, especially with the next generation of laser drives such as at the National Ignition Facility. Here we use large-scale molecular dynamics (MD) simulations of the high-rate deformation of nanocrystalline tantalum to investigate the processes associated with plastic deformation for strains up to 100%. We use initial atomic configurations that were produced through simulations of solidification in the work of Streitz et al [Phys. Rev. Lett. 96, (2006) 225701]. These 3D polycrystalline systems have typical grain sizes of 10-20 nm. We also study a rapidly quenched liquid (amorphous solid) tantalum. We apply a constant volume (isochoric), constant temperature (isothermal) shear deformation over a range of strain rates, and compute the resulting stress-strain curves to large strains for both uniaxial and biaxial compression. We study the rate dependence and identify plastic deformation mechanisms. The identification of the mechanisms is facilitated through a novel technique that computes the local grain orientation, returning it as a quaternion for each atom. This analysis technique is robust and fast, and has been used to compute the orientations on the fly during our parallel MD simulations on supercomputers. We find both dislocation and twinning processes are important, and they interact in the weak strain hardening in these extremely fine-grained microstructures.

  1. A historical analysis of the co-evolution of gasoline octane number and spark-ignition engines

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Splitter, Derek A.; Pawlowski, Alex E.; Wagner, Robert M.

    2016-01-06

    In our work, the authors reviewed engine, vehicle, and fuel data since 1925 to examine the historical and recent coupling of compression ratio and fuel antiknock properties (i.e., octane number) in the U.S. light-duty vehicle market. The analysis identified historical timeframes, trends, and illustrated how three factors: consumer preferences, technical capabilities, and regulatory legislation, affect personal mobility. Data showed that throughout history these three factors have a complex and time sensitive interplay. Long term trends in the data were identified where interaction and evolution between all three factors was observed. Transportation efficiency per unit power (gal/ton-mi/hp) was found to bemore » a good metric to integrate technical, societal, and regulatory effects into the evolutional pathway of personal mobility. From this framework, discussions of future evolutionary changes to personal mobility are also presented.« less

  2. General Purpose Graphics Processing Unit Based High-Rate Rice Decompression and Reed-Solomon Decoding.

    SciTech Connect (OSTI)

    Loughry, Thomas A.

    2015-02-01

    As the volume of data acquired by space-based sensors increases, mission data compression/decompression and forward error correction code processing performance must likewise scale. This competency development effort was explored using the General Purpose Graphics Processing Unit (GPGPU) to accomplish high-rate Rice Decompression and high-rate Reed-Solomon (RS) decoding at the satellite mission ground station. Each algorithm was implemented and benchmarked on a single GPGPU. Distributed processing across one to four GPGPUs was also investigated. The results show that the GPGPU has considerable potential for performing satellite communication Data Signal Processing, with three times or better performance improvements and up to ten times reduction in cost over custom hardware, at least in the case of Rice Decompression and Reed-Solomon Decoding.

  3. Dynamic High-temperature Testing of an Iridium Alloy in Compression at High-strain Rates: Dynamic High-temperature Testing

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Song, B.; Nelson, K.; Lipinski, R.; Bignell, J.; Ulrich, G.; George, E. P.

    2014-08-21

    Iridium alloys have superior strength and ductility at elevated temperatures, making them useful as structural materials for certain high-temperature applications. However, experimental data on their high-strain -rate performance are needed for understanding high-speed impacts in severe environments. Kolsky bars (also called split Hopkinson bars) have been extensively employed for high-strain -rate characterization of materials at room temperature, but it has been challenging to adapt them for the measurement of dynamic properties at high temperatures. In our study, we analyzed the difficulties encountered in high-temperature Kolsky bar testing of thin iridium alloy specimens in compression. We made appropriate modifications using themore » current high-temperature Kolsky bar technique in order to obtain reliable compressive stress–strain response of an iridium alloy at high-strain rates (300–10 000 s-1) and temperatures (750 and 1030°C). The compressive stress–strain response of the iridium alloy showed significant sensitivity to both strain rate and temperature.« less

  4. Dynamic High-temperature Testing of an Iridium Alloy in Compression at High-strain Rates: Dynamic High-temperature Testing

    SciTech Connect (OSTI)

    Song, B.; Nelson, K.; Lipinski, R.; Bignell, J.; Ulrich, G.; George, E. P.

    2014-08-21

    Iridium alloys have superior strength and ductility at elevated temperatures, making them useful as structural materials for certain high-temperature applications. However, experimental data on their high-strain -rate performance are needed for understanding high-speed impacts in severe environments. Kolsky bars (also called split Hopkinson bars) have been extensively employed for high-strain -rate characterization of materials at room temperature, but it has been challenging to adapt them for the measurement of dynamic properties at high temperatures. In our study, we analyzed the difficulties encountered in high-temperature Kolsky bar testing of thin iridium alloy specimens in compression. We made appropriate modifications using the current high-temperature Kolsky bar technique in order to obtain reliable compressive stress–strain response of an iridium alloy at high-strain rates (300–10 000 s-1) and temperatures (750 and 1030°C). The compressive stress–strain response of the iridium alloy showed significant sensitivity to both strain rate and temperature.

  5. Shock tube measurements of high temperature rate constants for OH with cycloalkanes and methylcycloalkanes.

    SciTech Connect (OSTI)

    Sivaramakrishnan, R.; Michael, J. V.; Chemical Sciences and Engineering Division

    2009-05-01

    High temperature experiments were performed with the reflected shock tube technique using multi-pass absorption spectrometric detection of OH radicals at 308 nm. The present experiments span a wide T-range, 801-1347 K, and represent the first direct measurements of the title rate constants at T>500 K for cyclopentane and cyclohexane and the only high temperature measurements for the corresponding methyl derivatives. The present work utilized 48 optical passes corresponding to a total path length 4.2 m. As a result of this increased path length, the high [OH] detection sensitivity permitted unambiguous analyses for measuring the title rate constants. The experimental rate constants in units, cm3 molecule-1 s-1, can be expressed in Arrhenius form as k{sub OH+Cyclopentane} = (1.90 {+-} 0.30) x 10{sup -10} exp(-1705 {+-} 156 K/T) (813-1341 K), k{sub OH+Cyclohexane} = (1.86 {+-} 0.24) x 10{sup -10} exp(-1513 {+-} 123 K/T) (801-1347 K), k{sub OH+Methylcyclopentane} = (2.02 {+-} 0.19) x 10{sup -10} exp(-1799 {+-} 96 K/T) (859-1344 K), k{sub OH+Methylcyclohexane} = (2.55 {+-} 0.30) x 10{sup -10} exp(-1824 {+-} 114 K/T) (836-1273 K). These results and lower-T experimental data were used to obtain three parameter evaluations of the experimental rate constants for the title reactions over an even wider T-range. These experimental three parameter fits to the rate constants in units, cm{sup 3} molecule{sup -1} s{sup -1}, are k{sub OH+Cyclopentane} = 1.390 x 10{sup -16}T{sup 1.779} exp(97 K/T) cm{sup 3} molecule{sup -1} s{sup -1} (209-1341 K), k{sub OH+Cyclohexane} = 3.169 x 10{sup -16} T{sup 1.679} exp(119 K/T) cm{sup 3} molecule{sup -1} s{sup -1} (225-1347 K), k{sub OH+Methylcyclopentane} = 6.903 x 10{sup -18}T{sup 2.148} exp(536 K/T) cm{sup 3} molecule{sup -1} s{sup -1} (296-1344 K), k{sub OH+Methylcyclohexane} = 2.341 x 10{sup -18}T{sup 2.325} exp(602 K/T) cm{sup 3} molecule{sup -1} s{sup -1} (296-1273 K). High level electronic structure methods were used to characterize the

  6. Shock tube measurements of high temperature rate constants for OH with cycloalkanes and methylcycloalkanes

    SciTech Connect (OSTI)

    Sivaramakrishnan, R.; Michael, J.V.

    2009-05-15

    High temperature experiments were performed with the reflected shock tube technique using multi-pass absorption spectrometric detection of OH radicals at 308 nm. The present experiments span a wide T-range, 801-1347 K, and represent the first direct measurements of the title rate constants at T>500 K for cyclopentane and cyclohexane and the only high temperature measurements for the corresponding methyl derivatives. The present work utilized 48 optical passes corresponding to a total path length {proportional_to}4.2 m. As a result of this increased path length, the high [OH] detection sensitivity permitted unambiguous analyses for measuring the title rate constants. The experimental rate constants in units, cm{sup 3} molecule{sup -1} s{sup -1}, can be expressed in Arrhenius form as k{sub OH+Cyclopentane}=(1.90{+-}0.30) x 10{sup -10}exp(-1705{+-}56 K/T) (813-1341 K), k{sub OH+Cyclohexane}=(1.86{+-}0.24) x 10{sup -10}exp(-1513{+-}123 K/T) (801-1347 K), k{sub OH+Methylcyclopentane}=(2.02{+-}0.19) x 10{sup -10}exp(-1799{+-}96 K/T) (859-1344 K), k{sub OH+Methylcyclohexane}=(2.55{+-}0.30) x 10{sup -10}exp(-1824{+-}114 K/T) (836-1273 K). These results and lower-T experimental data were used to obtain three parameter evaluations of the experimental rate constants for the title reactions over an even wider T-range. These experimental three parameter fits to the rate constants in units, cm{sup 3} molecule{sup -1} s{sup -1}, are k{sub OH+Cyclopentane}=1.390 x 10{sup -16}T{sup 1.779}exp(97 K/T)cm{sup 3} molecule{sup -1}s{sup -1} (209-1341 K), k{sub OH+Cyclohexane}=3.169 x 10{sup -16}T{sup 1.679}exp(119 K/T)cm{sup 3}molecule{sup -1}s{sup -1} (225-1347 K), k{sub OH+Methylcyclopentane}=6.903 x 10{sup -18}T{sup 2.148}exp(536 K/T)cm{sup 3}molecule{sup -1}s{sup -1} (296-1344 K), k{sub OH+Methylcyclohexane}=2.341 x 10{sup -18}T{sup 2.325}exp(602 K/T)cm{sup 3}molecule{sup -1}s{sup -1} (296-1273 K). High level electronic structure methods were used to characterize the first three

  7. Device for testing closure disks at high rates of change of pressure

    DOE Patents [OSTI]

    Merten, C.W. Jr.

    1993-11-09

    A device is described for testing the burst pressure of closure disks which provides high pressure to both sides of a disk and rapidly releases pressure from one side thereof causing a high rate of change of pressure. A hollow notched plug allows the rapid release of pressure upon rupturing. A means is also disclosed for transmitting a tensile load from a piston to a hollow notched plug and for sealing the means for transmitting load within a hole in a piston. 5 figures.

  8. MELT RATE ENHANCEMENT FOR HIGH ALUMINUM HLW (HIGH LEVEL WASTE) GLASS FORMULATION FINAL REPORT 08R1360-1

    SciTech Connect (OSTI)

    KRUGER AA; MATLACK KS; KOT W; PEGG IL; JOSEPH I; BARDAKCI T; GAN H; GONG W; CHAUDHURI M

    2010-01-04

    This report describes the development and testing of new glass formulations for high aluminum waste streams that achieve high waste loadings while maintaining high processing rates. The testing was based on the compositions of Hanford High Level Waste (HLW) with limiting concentrations of aluminum specified by the Office of River Protection (ORP). The testing identified glass formulations that optimize waste loading and waste processing rate while meeting all processing and product quality requirements. The work included preparation and characterization of crucible melts and small scale melt rate screening tests. The results were used to select compositions for subsequent testing in a DuraMelter 100 (DM100) system. These tests were used to determine processing rates for the selected formulations as well as to examine the effects of increased glass processing temperature, and the form of aluminum in the waste simulant. Finally, one of the formulations was selected for large-scale confirmatory testing on the HLW Pilot Melter (DM1200), which is a one third scale prototype of the Hanford Tank Waste Treatment and Immobilization Plant (WTP) HLW melter and off-gas treatment system. This work builds on previous work performed at the Vitreous State Laboratory (VSL) for Department of Energy (DOE) to increase waste loading and processing rates for high-iron HLW waste streams as well as previous tests conducted for ORP on the same high-aluminum waste composition used in the present work and other Hanford HLW compositions. The scope of this study was outlined in a Test Plan that was prepared in response to an ORP-supplied statement of work. It is currently estimated that the number of HLW canisters to be produced in the WTP is about 13,500 (equivalent to 40,500 MT glass). This estimate is based upon the inventory of the tank wastes, the anticipated performance of the sludge treatment processes, and current understanding of the capability of the borosilicate glass waste form

  9. Development of High Rate Coating Technology for Low Cost Electrochromic Dynamic Windows

    SciTech Connect (OSTI)

    Kwak, B.; Joshi, Ajey

    2013-03-31

    Objectives of the Project: The objective of this project was to develop and demonstrate the feasibility of depositing critical electrochromic layers at high rate using new novel vacuum coating sources, to develop a full electrochromic process flow by combining conventional processes with new deposition sources, to characterize, test, evaluate, and optimize the resulting coatings and devices, and, to demonstrate an electrochromic device using the new process flow and sources. As addendum objectives, this project was to develop and demonstrate direct patterning methods with novel integration schemes. The long term objective, beyond this program, is to integrate these innovations to enable production of low-cost, high-performance electrochromic windows produced on highly reliable and high yielding manufacturing equipment and systems.

  10. STANFORD IN-SITU HIGH RATE YBCO PROCESS: TRANSFER TO METAL TAPES AND PROCESS SCALE UP

    SciTech Connect (OSTI)

    Malcolm R. Beasley; Robert H.Hammond

    2009-04-14

    Executive Summary The materials science understanding of high rate low cost processes for Coated Conductor will benefit the application to power utilities for low loss energy transportation and power generation as well for DOD applications. The research in this program investigated several materials processing approaches that are new and original, and are not being investigated elsewhere. This work added to the understanding of the material science of high rate PVD growth of HTSC YBCO assisted by a liquid phase. A new process discovered uses amorphous glassy precursors which can be made at high rate under flexible conditions of temperature and oxygen, and later brought to conditions of oxygen partial pressure and temperature for rapid conversion to YBCO superconductor. Good critical current densities were found, but further effort is needed to optimize the vortex pinning using known artificial inclusions. A new discovery of the physics and materials science of vortex pinning in the HTSC system using Sm in place of Y came at growth at unusually low oxygen pressure resulting in clusters of a low or non superconducting phase within the nominal high temperature phase. The driving force for this during growth is new physics, perhaps due to the low oxygen. This has the potential for high current in large magnetic fields at low cost, applicable to motors, generators and transformers. The technical demands of this project were the motivation for the development of instrumentation that could be essential to eventual process scale up. These include atomic absorption based on tunable diode lasers for remote monitoring and control of evaporation sources (developed under DARPA support), and the utility of Fourier Transform Infrared Reflectivity (FTIR) for aid in the synthesis of complex thin film materials (purchased by a DURIP-AFOSR grant).

  11. An optical parametric chirped-pulse amplifier for seeding high repetition rate free-electron lasers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Höppner, H.; Hage, A.; Tanikawa, T.; Schulz, M.; Riedel, R.; Teubner, U.; Prandolini, M. J.; Faatz, B.; Tavella, F.

    2015-05-15

    High repetition rate free-electron lasers (FEL), producing highly intense extreme ultraviolet and x-ray pulses, require new high power tunable femtosecond lasers for FEL seeding and FEL pump-probe experiments. A tunable, 112 W (burst mode) optical parametric chirped-pulse amplifier (OPCPA) is demonstrated with center frequencies ranging from 720–900 nm, pulse energies up to 1.12 mJ and a pulse duration of 30 fs at a repetition rate of 100 kHz. Since the power scalability of this OPCPA is limited by the OPCPA-pump amplifier, we also demonstrate a 6.7–13.7 kW (burst mode) thin-disk OPCPA-pump amplifier, increasing the possible OPCPA output power to manymore » hundreds of watts. Furthermore, third and fourth harmonic generation experiments are performed and the results are used to simulate a seeded FEL with high-gain harmonic generation.« less

  12. Hysteresis-free high rate reactive sputtering of niobium oxide, tantalum oxide, and aluminum oxide

    SciTech Connect (OSTI)

    Srhammar, Erik, E-mail: erik.sarhammar@angstrom.uu.se; Berg, Sren; Nyberg, Tomas [Department of Solid State Electronics, The ngstrm Laboratory, Uppsala University, Box 534, SE-751 21 Uppsala (Sweden)

    2014-07-01

    This work reports on experimental studies of reactive sputtering from targets consisting of a metal and its oxide. The composition of the targets varied from pure metal to pure oxide of Al, Ta, and Nb. This combines features from both the metal target and oxide target in reactive sputtering. If a certain relation between the metal and oxide parts is chosen, it may be possible to obtain a high deposition rate, due to the metal part, and a hysteresis-free process, due to the oxide part. The aim of this work is to quantify the achievable boost in oxide deposition rate from a hysteresis-free process by using a target consisting of segments of a metal and its oxide. Such an increase has been previously demonstrated for Ti using a homogeneous substoichiometric target. The achievable gain in deposition rate depends on transformation mechanisms from oxide to suboxides due to preferential sputtering of oxygen. Such mechanisms are different for different materials and the achievable gain is therefore material dependent. For the investigated materials, the authors have demonstrated oxide deposition rates that are 1.510 times higher than what is possible from metal targets in compound mode. However, although the principle is demonstrated for oxides of Al, Ta, and Nb, a similar behavior is expected for most oxides.

  13. Laminar burn rates of gun propellants measured in the high-pressure strand burner

    SciTech Connect (OSTI)

    Reaugh, J. E., LLNL

    1997-10-01

    The pressure dependence of the laminar burn rate of gun propellants plays a role in the design and behavior of high-performance guns. We have begun a program to investigate the effects of processing variables on the laminar burn rates, using our high-pressure strand burner to measure these rates at pressures exceeding 700 MPa. We have burned JA2 and M43 propellant samples, provided by Dr. Arpad Juhasz, ARL, from propellant lots previously used in round-robin tests. Our results at room temperature are in accord with other measurements. In addition, we present results measured for propellant that has been preheated to 50 C before burning. We used our thermochemical equilibrium code, CHEETAH, to help interpret the simultaneous pressure and temperature measurements taken during the testing, and show examples of its use. It has been modified to provide performance measures and equations of state for the products that are familiar to the gun-propellant community users of BLAKE.

  14. High rate capacitive performance of single-walled carbon nanotube aerogels

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Van Aken, Katherine L.; Pérez, Carlos R.; Oh, Youngseok; Beidaghi, Majid; Joo Jeong, Yeon; Islam, Mohammad F.; Gogotsi, Yury

    2015-05-30

    Single-walled carbon nanotube (SWCNT) aerogels produced by critical-point-drying of wet-gel precursors exhibit unique properties, such as high surface-area-to-volume and strength-to-weight ratios. They are free-standing, are binder-free, and can be scaled to thicknesses of more than 1 mm. In this paper, we examine the electric double layer capacitive behavior of these materials using a common room temperature ionic liquid electrolyte, 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EMI-TFSI). Electrochemical performance is assessed through galvanostatic cycling, cyclic voltammetry and impedance spectroscopy. Results indicate stable capacitive performance over 10,000 cycles as well as an impressive performance at high charge and discharge rates, due to accessible pore networks andmore » enhanced electronic and ionic conductivities of SWCNT aerogels. Finally, these materials can find applications in mechanically compressible and flexible supercapacitor devices with high power requirements.« less

  15. Understanding the origin of high-rate intercalation pseudocapacitance in Nb2O5 crystals

    SciTech Connect (OSTI)

    Ganesh, Panchapakesan; Kent, P. R. C.; Sumpter, Bobby G; Lubimtsev, Andrew A

    2013-01-01

    Pseudocapacitors aim to maintain the high power density of supercapacitors while increasing the energy density towards those of energy dense storage systems such as lithium ion batteries. Recently discovered intercalation pseudocapacitors (e.g. Nb2O5) are particularly interesting because their performance is seemingly not limited by surface reactions or structures, but instead determined by the bulk crystalline structure of the material. We study ordered polymorphs of Nb2O5 and detail the mechanism for the intrinsic high rates and energy density observed for this class of materials. We find that the intercalating atom (lithium) forms a solid solution adsorbing at specific sites in a network of quasi-2D NbOx faces with x {1.3, 1.67, or 2}, donating electrons locally to its neighboring atoms, reducing niobium. Open channels in the structure have low diffusion barriers for ions to migrate between these sites (Eb 0.28 0.44 eV) comparable to high-performance solid electrolytes. Using a combination of complementary theoretical methods we rationalize this effect in LixNb2O5 for a wide range of compositions (x) and at finite temperatures. Multiple adsorption sites per unit-cell with similar adsorption energies and local charge transfer result in high capacity and energy density, while the interconnected open channels lead to low cost diffusion pathways between these sites, resulting in high power density. The nano-porous structure exhibiting local chemistry in a crystalline framework is the origin of high-rate pseudocapacitance in this new class of intercalation pseudocapacitor materials. This new insight provides guidance for improving the performance of this family of materials.

  16. Results from beam tests of MEGA's low-mass, high-rate cylindrical MWPCs

    SciTech Connect (OSTI)

    Stanislaus, S.; Armijo, V.; Black, J.K.; Bolton, R.D.; Carius, S.; Cooper, M.D.; Espinoza, C.; Hart, G.; Hogan, G.; Gonzales, A.; Mischke, R.E.; Piilonen, L.E.; Sandoval, J.; Schilling, S.; Sena, J.; Suazo, G.; Szymanski, J.J.; Whitehouse, D.A.; Wilkinson, C.A. ); Fisk, R.; Koetke, D.D.; Manweiler, R.W. ); Jui, C.C. (Stanford Univ., CA

    1991-01-01

    One of the leading experimental projects at LAMPF has been the MEGA experiment. This is an experiment to search for the rare decay {mu} {yields} e{gamma} with a sensitivity of 10{sup {minus}13}. A prime component of this project has been the design and construction of high-rate, low mass MWPCs for the tracking of positrons from muon decay. With rate capabilities of 2 {times} 10{sup 4} e{sup +}/mm{sup 2}/s and a thickness of 3 {times} 10{sup {minus}4} radiation lengths, these chambers are state-of-the-art cylindrical MWPCs. Cylindrical chambers of this size (0.9 m{sup 2}) and thinness have never been previously constructed. The MEGA project at LAMPF has recently succeeded in building chambers with these necessary performance characteristics as demonstrated by data taken from muon decays, cosmic rays, and sources.

  17. Laminar burning velocities at high pressure for primary reference fuels and gasoline: Experimental and numerical investigation

    SciTech Connect (OSTI)

    Jerzembeck, S.; Peters, N. [RWTH, Aachen (Germany); Pepiot-Desjardins, P.; Pitsch, H. [Department of Mechanical Engineering, Stanford University, CA (United States)

    2009-02-15

    Spherical flames of n-heptane, iso-octane, PRF 87 and gasoline/air mixtures are experimentally investigated to determine laminar burning velocities and Markstein lengths under engine-relevant conditions by using the constant volume bomb method. Data are obtained for an initial temperature of 373 K, equivalence ratios varying from {phi}=0.7 to {phi}=1.2, and initial pressures from 10 to 25 bar. To track the flame front in the vessel a dark field He-Ne laser Schlieren measurement technique and digital image processing were used. The propagating speed with respect to the burned gases and the stretch rate are determined from the rate of change of the flame radius. The laminar burning velocities are obtained through a linear extrapolation to zero stretch. The experimentally determined Markstein numbers are compared to theoretical predictions. A reduced chemical kinetic mechanism for n-heptane and iso-octane was derived from the Lawrence Livermore comprehensive mechanisms. This mechanism was validated for ignition delay times and flame propagation at low and high pressures. In summary an overall good agreement with the various experimental data sets used in the validation was obtained. (author)

  18. A Multi-Contact, Low Capacitance HPGe Detector for High Rate Gamma Spectroscopy

    SciTech Connect (OSTI)

    Cox, Christopher

    2014-12-04

    The detection, identification and non-destructive assay of special nuclear materials and nuclear fission by-products are critically important activities in support of nuclear non-proliferation programs. Both national and international nuclear safeguard agencies recognize that current accounting methods for spent nuclear fuel are inadequate from a safeguards perspective. Radiation detection and analysis by gamma-ray spectroscopy is a key tool in this field, but no instrument exists that can deliver the required performance (energy resolution and detection sensitivity) in the presence of very high background count rates encountered in the nuclear safeguards arena. The work of this project addresses this critical need by developing a unique gamma-ray detector based on high purity germanium that has the previously unachievable property of operating in the 1 million counts-per-second range while achieving state-of-the-art energy resolution necessary to identify and analyze the isotopes of interest. The technical approach was to design and fabricate a germanium detector with multiple segmented electrodes coupled to multi-channel high rate spectroscopy electronics. Dividing the germanium detector’s signal electrode into smaller sections offers two advantages; firstly, the energy resolution of the detector is potentially improved, and secondly, the detector is able to operate at higher count rates. The design challenges included the following; determining the optimum electrode configuration to meet the stringent energy resolution and count rate requirements; determining the electronic noise (and therefore energy resolution) of the completed system after multiple signals are recombined; designing the germanium crystal housing and vacuum cryostat; and customizing electronics to perform the signal recombination function in real time. In this phase I work, commercial off-the-shelf electrostatic modeling software was used to develop the segmented germanium crystal geometry

  19. Paradoxical roles of hydrogen in electrochemical performance of graphene: High rate capacity and atomistic origins

    SciTech Connect (OSTI)

    Ye, Jianchao C.; Ong, Mitchell T.; Heo, Tae Wook; Campbell, Patrick G.; Worsley, Marcus A.; Liu, Yuanyue Y.; Charnvanichborikarn, Supakit; Matthews, Manyalibo J.; Bagge-Hansen, Michael; Lee, Jonathan R. I.; Wood, Brandon C.; Wang, Y. Morris; Shin, Swanee J.

    2015-11-05

    Atomic hydrogen exists ubiquitously in graphene materials made by chemical methods. Yet determining the effect of hydrogen on the electrochemical performance of graphene remains a significant challenge. Here we report the experimental observations of high rate capacity in hydrogen-treated 3-dimensional (3D) graphene nanofoam electrodes for lithium ion batteries. Structural and electronic characterization suggests that defect sites and hydrogen play synergistic roles in disrupting sp2 graphene to facilitate fast lithium transport and reversible surface binding, as evidenced by the fast charge-transfer kinetics and increased capacitive contribution in hydrogen-treated 3D graphene. In concert with experiments, multiscale calculations reveal that defect complexes in graphene are prerequisite for low-temperature hydrogenation, and that the hydrogenation of defective or functionalized sites at strained domain boundaries plays a beneficial role in improving rate capacity by opening gaps to facilitate easier Li penetration. Additional reversible capacity is provided by enhanced lithium binding near hydrogen-terminated edge sites. Furthermore, these findings provide qualitative insights in helping the design of graphene-based materials for high-power electrodes.

  20. Paradoxical roles of hydrogen in electrochemical performance of graphene: High rate capacity and atomistic origins

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ye, Jianchao C.; Ong, Mitchell T.; Heo, Tae Wook; Campbell, Patrick G.; Worsley, Marcus A.; Liu, Yuanyue Y.; Charnvanichborikarn, Supakit; Matthews, Manyalibo J.; Bagge-Hansen, Michael; Lee, Jonathan R. I.; et al

    2015-11-05

    Atomic hydrogen exists ubiquitously in graphene materials made by chemical methods. Yet determining the effect of hydrogen on the electrochemical performance of graphene remains a significant challenge. Here we report the experimental observations of high rate capacity in hydrogen-treated 3-dimensional (3D) graphene nanofoam electrodes for lithium ion batteries. Structural and electronic characterization suggests that defect sites and hydrogen play synergistic roles in disrupting sp2 graphene to facilitate fast lithium transport and reversible surface binding, as evidenced by the fast charge-transfer kinetics and increased capacitive contribution in hydrogen-treated 3D graphene. In concert with experiments, multiscale calculations reveal that defect complexes inmore » graphene are prerequisite for low-temperature hydrogenation, and that the hydrogenation of defective or functionalized sites at strained domain boundaries plays a beneficial role in improving rate capacity by opening gaps to facilitate easier Li penetration. Additional reversible capacity is provided by enhanced lithium binding near hydrogen-terminated edge sites. Furthermore, these findings provide qualitative insights in helping the design of graphene-based materials for high-power electrodes.« less

  1. Reliable, high repetition rate thyratron grid driver used with a magnetic modulator

    SciTech Connect (OSTI)

    Hill, J.V.; Ball, D.G.; Garrett, D.N.

    1991-06-14

    The Atomic Vapor Laser Isotope Separation (AVLIS) Program at Lawrence Livermore National Laboratory uses a magnetic modulator switched by a high voltage thyratron to drive a gas discharge laser. The thyratron trigger source must provide an extremely reliable, low jitter, high- rep-rate grid pulse. This paper describes a thyratron grid driver which delivers a 1.2 kV, 80 ns rise time grid pulse into a 50 ohm load at up to 4.5 kHz repetition rate and has demonstrated approximately 10,000 hours MTBF. Since the thyratron is used with a magnetic compression circuit having a delay time of 1.4 ms this grid driver incorporates a jitter compensation circuit to adjust the trigger timing of the thyratron to provide overall modulator/laser jitter of less than {plus minus} 2 ns. The specific grid driver requirements will be discussed followed by a description of the circuit design and theory of operation. Construction comments will be followed by performance data (for a specific thyratron and magnetic compression circuit), including pulse shape, jitter, and lifetime. 1 ref., 10 figs.

  2. Supported plasma sputtering apparatus for high deposition rate over large area

    DOE Patents [OSTI]

    Moss, Ronald W.; McClanahan, Jr., Edwin D.; Laegreid, Nils

    1977-01-01

    A supported plasma sputtering apparatus is described having shaped electrical fields in the electron discharge region between the cathode and anode and the sputter region between the target and substrate while such regions are free of any externally applied magnetic field to provide a high deposition rate which is substantially uniform over a wide area. Plasma shaping electrodes separate from the anode and target shape the electrical fields in the electron discharge region and the sputter region to provide a high density plasma. The anode surrounds the target to cause substantially uniform sputtering over a large target area. In one embodiment the anode is in the form of an annular ring surrounding a flat target surface, such anode being provided with a ribbed upper surface which shields portions of the anode from exposure to sputtered material to maintain the electron discharge for a long stable operation. Several other embodiments accomplish the same result by using different anodes which either shield the anode from sputtered material, remove the sputtered coating on the anode by heating, or simultaneously mix sputtered metal from the auxiliary target with sputtered insulator from the main target so the resultant coating is conductive. A radio frequency potential alone or together with a D.C. potential, may be applied to the target for a greater sputtering rate.

  3. High-repetition rate and mode-locked phosphate glass laser

    SciTech Connect (OSTI)

    He; Lu; Li; Qian; Gu

    1986-04-04

    High-repetition-rate operation of a picosecond glass laser up to 10 Hz was achieved by using a new kind of phosphate glass. The pulse duration is 24 ps, the spectral width is 0.84 A and the total energy of the pulse train is 6 mJ. The key to the operation of glass materials at high repetition rates lies not only in an improvement of their thermal conductivity, but also in an avoidance or elimination of the undesired optical-pumping-induced thermal effects, such as the optical path change due to change in the index of refraction with temperature, and the linear expansion coefficient. For silicate glass, both are positive. The new type of phosphate glass adopted in this study exhibits negative and positive linear expansion coefficient behavior, so that changes in the optical path resulting from both of them can be compensated by each other. As a result, such a change can reach a minimum value each time when light travels back and forth in a laser cavity.

  4. Effect of Premixed Fuel Preparation for Partially Premixed Combustion with a Low Octane Gasoline on a Light-Duty Multi-Cylinder Compression Ignition Engine

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dempsey, Adam B.; Curran, Scott; Wagner, Robert M.; Cannella, William C.

    2015-05-12

    has relatively high fuel reactivity with a research octane number of 68. The results of this experimental campaign indicate that the highest brake thermal efficiency and lowest emissions are achieved simultaneously with the earliest pilot injection timings (i.e., during the intake stroke).« less

  5. Effect of Premixed Fuel Preparation for Partially Premixed Combustion with a Low Octane Gasoline on a Light-Duty Multi-Cylinder Compression Ignition Engine

    SciTech Connect (OSTI)

    Dempsey, Adam B.; Curran, Scott; Wagner, Robert M.; Cannella, William C.

    2015-05-12

    relatively high fuel reactivity with a research octane number of 68. The results of this experimental campaign indicate that the highest brake thermal efficiency and lowest emissions are achieved simultaneously with the earliest pilot injection timings (i.e., during the intake stroke).

  6. Nano-sized structured layered positive electrode materials to enable high energy density and high rate capability lithium batteries

    DOE Patents [OSTI]

    Deng, Haixia; Belharouak, Ilias; Amine, Khalil

    2012-10-02

    Nano-sized structured dense and spherical layered positive active materials provide high energy density and high rate capability electrodes in lithium-ion batteries. Such materials are spherical second particles made from agglomerated primary particles that are Li.sub.1+.alpha.(Ni.sub.xCo.sub.yMn.sub.z).sub.1-tM.sub.tO.sub.2-dR.sub.d- , where M is selected from can be Al, Mg, Fe, Cu, Zn, Cr, Ag, Ca, Na, K, In, Ga, Ge, V, Mo, Nb, Si, Ti, Zr, or a mixture of any two or more thereof, R is selected from F, Cl, Br, I, H, S, N, or a mixture of any two or more thereof, and 0.ltoreq..alpha..ltoreq.0.50; 0

  7. Delayed Workforce Entry and High Emigration Rates for Recent Canadian Radiation Oncology Graduates

    SciTech Connect (OSTI)

    Loewen, Shaun K.; Halperin, Ross; Lefresne, Shilo; Trotter, Theresa; Stuckless, Teri; Brundage, Michael

    2015-10-01

    Purpose: To determine the employment status and location of recent Canadian radiation oncology (RO) graduates and to identify current workforce entry trends. Methods and Materials: A fill-in-the-blank spreadsheet was distributed to all RO program directors in December 2013 and June 2014, requesting the employment status and location of their graduates over the last 3 years. Visa trainee graduates were excluded. Results: Response rate from program directors was 100% for both survey administrations. Of 101 graduates identified, 99 (98%) had known employment status and location. In the December survey, 5 2013 graduates (16%), 17 2012 graduates (59%), and 18 2011 graduates (75%) had permanent staff employment. Six months later, 5 2014 graduates (29%), 15 2013 graduates (48%), 24 2012 graduates (83%), and 21 2011 graduates (88%) had secured staff positions. Fellowships and temporary locums were common for those without staff employment. The proportion of graduates with staff positions abroad increased from 22% to 26% 6 months later. Conclusions: Workforce entry for most RO graduates was delayed but showed steady improvement with longer time after graduation. High emigration rates for jobs abroad signify domestic employment challenges for newly certified, Canadian-trained radiation oncologists. Coordination on a national level is required to address and regulate radiation oncologist supply and demand disequilibrium in Canada.

  8. Limits of survivability and damage for optical components used in a high repetition rate visible laser

    SciTech Connect (OSTI)

    Taylor, J.R.; Stolz, C.J.; Sarginson, T.G.

    1991-10-01

    An effort is being made to understand the limits of survivability and damage for optical components exposed to a visible laser operating continuously at a high repetition rate over 4 kHz. Results of this work are reported and related to the materials and manufacturing conditions for coatings and substrates as well as defects seen at the surface under laser illumination. These results were obtained for a variety of optical coatings and conditions using lasers from the Laser Demonstration Facility, part of the Atomic Vapor Laser Isotope Separation (AVLIS) Program at LLNL. Better understanding of the reliability of optical components in this environment could lead to improvements in design and manufacture that would result in reduced size for the laser optical system and correspondingly lower costs for the facilities that can use this technology.

  9. Pressure dependence on the reaction propagation rate of PETN at high pressure

    SciTech Connect (OSTI)

    Foltz, M.F.

    1993-04-01

    The reaction propagation rate (RPR) of the sensitive high explosive pentaerythritol tetranitrate (PETN) was measured in a diamond anvil cell (DAC) over the pressure range of 2--20 GPa. The experimental technique used is the same as that previously reported. The RPR data shows that it burns one to two orders of magnitude faster in the DAC than 1,3,5,-triamino-2,4,6-trinitrobenzene (TATB) and nitromethane (CH{sub 3}NO{sub 2}) respectively. The PETN RPR curve did not show sample pressure-dependent behavior like that of nitromethane, but instead varied abruptly like the RPR curve of TATB. In order to interpret these changes, static-pressure DAC mid-IR FTIR spectra were taken of micro-pellets of PETN embedded in KBr. The relationship between changes in the spectra, the RPR curve, and published single crystal PETN wedge test data are discussed.

  10. Dual-axis high-data-rate atom interferometer via cold ensemble exchange

    SciTech Connect (OSTI)

    Rakholia, Akash V.; McGuinness, Hayden J.; Biedermann, Grant W.

    2014-11-24

    We demonstrate a dual-axis accelerometer and gyroscope atom interferometer, which can form the building blocks of a six-axis inertial measurement unit. By recapturing the atoms after the interferometer sequence, we maintain a large atom number at high data rates of 50 to 100 measurements per second. Two cold ensembles are formed in trap zones located a few centimeters apart and are launched toward one another. During their ballistic trajectory, they are interrogated with a stimulated Raman sequence, detected, and recaptured in the opposing trap zone. As a result, we achieve sensitivities at ?g/ ?Hz and ?rad/s/ ?Hz levels, making this a compelling prospect for expanding the use of atom interferometer inertial sensors beyond benign laboratory environments.

  11. Dual-axis high-data-rate atom interferometer via cold ensemble exchange

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rakholia, Akash V.; McGuinness, Hayden J.; Biedermann, Grant W.

    2014-11-24

    We demonstrate a dual-axis accelerometer and gyroscope atom interferometer, which can form the building blocks of a six-axis inertial measurement unit. By recapturing the atoms after the interferometer sequence, we maintain a large atom number at high data rates of 50 to 100 measurements per second. Two cold ensembles are formed in trap zones located a few centimeters apart and are launched toward one another. During their ballistic trajectory, they are interrogated with a stimulated Raman sequence, detected, and recaptured in the opposing trap zone. As a result, we achieve sensitivities at μg/ √Hz and μrad/s/ √Hz levels, making thismore » a compelling prospect for expanding the use of atom interferometer inertial sensors beyond benign laboratory environments.« less

  12. Apparatus and method for tuned unsteady flow purging of high pulse rate spark gaps

    DOE Patents [OSTI]

    Thayer, III, William J.

    1990-01-01

    A spark gap switch apparatus is disclosed which is capable of operating at a high pulse rate which comprises an insulated housing; a pair of spaced apart electrodes each having one end thereof within a first bore formed in the housing and defining a spark gap therebetween; a pressure wave reflector in the first bore in the housing and spaced from the spark gap and capable of admitting purge flow; and a second enlarged bore contiguous with the first bore and spaced from the opposite side of the spark gap; whereby pressure waves generated during discharge of a spark across the spark gap will reflect off the wave reflector and back from the enlarged bore to the spark gap to clear from the spark gap hot gases residues generated during the discharge and simultaneously restore the gas density and pressure in the spark gap to its initial value.

  13. Modeling of transient ionizing radiation effects in bipolar devices at high dose-rates

    SciTech Connect (OSTI)

    FJELDLY,T.A.; DENG,Y.; SHUR,M.S.; HJALMARSON,HAROLD P.; MUYSHONDT,ARNOLDO

    2000-04-25

    To optimally design circuits for operation at high intensities of ionizing radiation, and to accurately predict their a behavior under radiation, precise device models are needed that include both stationary and dynamic effects of such radiation. Depending on the type and intensity of the ionizing radiation, different degradation mechanisms, such as photoelectric effect, total dose effect, or single even upset might be dominant. In this paper, the authors consider the photoelectric effect associated with the generation of electron-hole pairs in the semiconductor. The effects of low radiation intensity on p-II diodes and bipolar junction transistors (BJTs) were described by low-injection theory in the classical paper by Wirth and Rogers. However, in BJTs compatible with modem integrated circuit technology, high-resistivity regions are often used to enhance device performance, either as a substrate or as an epitaxial layer such as the low-doped n-type collector region of the device. Using low-injection theory, the transient response of epitaxial BJTs was discussed by Florian et al., who mainly concentrated on the effects of the Hi-Lo (high doping - low doping) epilayer/substrate junction of the collector, and on geometrical effects of realistic devices. For devices with highly resistive regions, the assumption of low-level injection is often inappropriate, even at moderate radiation intensities, and a more complete theory for high-injection levels was needed. In the dynamic photocurrent model by Enlow and Alexander. p-n junctions exposed to high-intensity radiation were considered. In their work, the variation of the minority carrier lifetime with excess carrier density, and the effects of the ohmic electric field in the quasi-neutral (q-n) regions were included in a simplified manner. Later, Wunsch and Axness presented a more comprehensive model for the transient radiation response of p-n and p-i-n diode geometries. A stationary model for high-level injection in p

  14. Combustion rates of chars from high-volatile fuels for FBC application

    SciTech Connect (OSTI)

    Masi, S.; Salatino, P.; Senneca, O.

    1997-12-31

    The fluidized bed combustion of high volatile fuels is often associated with huge occurrence of comminution phenomena. These result into in-bed generation of substantial amounts of carbon fines which further undergo competitive processes of combustion and elutriation. The small size of carbon fines generated by comminution is such that their further combustion is largely controlled by the intrinsic kinetics of carbon oxidation, alone or in combination with intraparticle diffusion. The competition between fine combustion and elutriation strongly affects the efficiency of fixed carbon conversion and calls for thorough characterization of the combustion kinetics and of residence times of fines in a fluidized bed of coarse solids. In this paper a collection of intrinsic combustion kinetic and porosimetric data for chars from three high-volatile fuels suitable for FBC application is presented. Chars from a Refuse Derived Fuel (RDF), a Tyre Derived Fuel (TDF) and a biomass (Robinia Pseudoacacia) are obtained from devolatilization, in fluidized bed, of fuel samples. Thermogravimetric analysis, mercury porosimetry and helium pycnometry are used to characterize the reactivity and the pore structure of the chars. Combustion rates are characterized over a wide range of temperatures (320--850 C) and oxygen partial pressures, covering the entire range of interest in fluidized bed combustion. Analysis of thermogravimetric and porosimetric data is directed to obtaining the parameters (pre-exponential factors, reaction orders, activation energies, intraparticle diffusivities) of combustion kinetic submodels for application in fluidized bed combustor modeling.

  15. Is the Use of a Surrogate Urethra an Option in Prostate High-Dose-Rate Brachytherapy?

    SciTech Connect (OSTI)

    Nilsson, Josef Kaelkner, Karl Mikael; Berg, Lars; Levitt, Seymour; Holmberg, Carina; Nilsson, Sten; Lundell, Marie

    2008-05-01

    Purpose: To investigate the accuracy and the dosimetric consequences of substituting a surrogate urethra assumed to be at the geometric center of the prostate, in place of the true urethra when using high-dose-rate (HDR) brachytherapy for the treatment of prostate cancer. Methods and Materials: One hundred prostate cancer patients treated with HDR brachytherapy constituted the study group. A pre-plan was made with the urethra visualized. The true urethra was defined, and a surrogate urethra was placed at the geometric center of the prostate. The distance between the two urethras was measured. The deviation was evaluated at the base, middle, and apex. To evaluate the dosimetric consequences for the true urethra when using a surrogate urethra, two different dose plans were made: one based on the true urethra and one based on the surrogate urethra. The dose-volume histograms for the true urethra were analyzed. Results: The deviation between the true urethra and the surrogate urethra was greatest at the base of the prostate. A statistically significant difference was seen between the dosimetric parameters for the true and the surrogate urethra when the dose plan was made using the surrogate urethra. In this situation the dose to the true urethra was increased above our defined maximum tolerance limit. Conclusions: When using dose plans made according to a surrogate urethra the dose to the true urethra might be too high to be acceptable. If the true urethra is not visualized, severe damage could easily develop in a significant number of patients.

  16. Adherence to Vaginal Dilation Following High Dose Rate Brachytherapy for Endometrial Cancer

    SciTech Connect (OSTI)

    Friedman, Lois C., E-mail: Lois.Friedman@UHhospitals.org [Department of Psychiatry, CASE Comprehensive Cancer Center and University Hospitals of Cleveland, Cleveland, OH (United States); Abdallah, Rita [Ireland Cancer Center, CASE Comprehensive Cancer Center and University Hospitals of Cleveland, Cleveland, OH (Ireland); Schluchter, Mark; Panneerselvam, Ashok [Department of Epidemiology and Biostatistics, CASE Comprehensive Cancer Center and University Hospitals of Cleveland, Cleveland, OH (United States); Kunos, Charles A. [Department of Radiation Oncology, CASE Comprehensive Cancer Center and University Hospitals of Cleveland, Cleveland, OH (United States)

    2011-07-01

    Purpose: We report demographic, clinical, and psychosocial factors associated with adherence to vaginal dilation and describe the sexual and marital or nonmarital dyadic functioning of women following high dose rate (HDR) brachytherapy for endometrial cancer. Methods and Materials: We retrospectively evaluated women aged 18 years or older in whom early-stage endometrial (IAgr3-IIB) cancers were treated by HDR intravaginal brachytherapy within the past 3.5 years. Women with or without a sexual partner were eligible. Patients completed questionnaires by mail or by telephone assessing demographic and clinical variables, adherence to vaginal dilation, dyadic satisfaction, sexual functioning, and health beliefs. Results: Seventy-eight of 89 (88%) eligible women with early-stage endometrial cancer treated with HDR brachytherapy completed questionnaires. Only 33% of patients were adherers, based on reporting having used a dilator more than two times per week in the first month following radiation. Nonadherers who reported a perceived change in vaginal dimension following radiation reported that their vaginas were subjectively smaller after brachytherapy (p = 0.013). Adherers reported more worry about their sex lives or lack thereof than nonadherers (p = 0.047). Patients reported considerable sexual dysfunction following completion of HDR brachytherapy. Conclusions: Adherence to recommendations for vaginal dilator use following HDR brachytherapy for endometrial cancer is poor. Interventions designed to educate women about dilator use benefit may increase adherence. Although sexual functioning was compromised, it is likely that this existed before having cancer for many women in our study.

  17. Deposition of device quality, low hydrogen content, hydrogenated amorphous silicon at high deposition rates

    DOE Patents [OSTI]

    Mahan, Archie Harvin; Molenbroek, Edith C.; Gallagher, Alan C.; Nelson, Brent P.; Iwaniczko, Eugene; Xu, Yueqin

    2002-01-01

    A method of fabricating device quality, thin-film a-Si:H for use as semiconductor material in photovoltaic and other devices, comprising in any order; positioning a substrate in a vacuum chamber adjacent a plurality of heatable filaments with a spacing distance L between the substrate and the filaments; heating the filaments to a temperature that is high enough to obtain complete decomposition of silicohydride molecules that impinge said filaments into Si and H atomic species; providing a flow of silicohydride gas, or a mixture of silicohydride gas containing Si and H, in said vacuum chamber while maintaining a pressure P of said gas in said chamber, which, in combination with said spacing distance L, provides a P.times.L product in a range of 10-300 mT-cm to ensure that most of the Si atomic species react with silicohydride molecules in the gas before reaching the substrate, to thereby grow a a-Si:H film at a rate of at least 50 .ANG./sec.; and maintaining the substrate at a temperature that balances out-diffusion of H from the growing a-Si:H film with time needed for radical species containing Si and H to migrate to preferred bonding sites.

  18. Low-coke rate operation under high PCI at Kobe No. 3 BF

    SciTech Connect (OSTI)

    Matsuo, Tadasu; Kanazuka, Yasuo; Hoshino, Koichi; Yoshida, Yasuo; Kitayama, Syuji; Ishiwaki, Shiro

    1997-12-31

    Kobe No. 3 blast furnace (BF) suffered tremendous damage when the Great Hanshin-Awaji Earthquake rocked the area on January 17, 1995. However, working as quickly as possible to dig out of the burden and rehabilitate various facilities, the company managed to restart the No. 3 BF on April 2. After the restart, which went smoothly, production was shifted into the low coke rate operation which was being promoted before the disaster. In October, 1995, only seven months after the restart, the nation record of 296 kg/t low coke rate could be achieved. Subsequently, in January, 1996, coke rate reached 290 kg/t and the low coke rate operation was renewed. Since that time the same level of coke rate has been maintained. The paper discusses how low coke rate operation was achieved.

  19. In vivo real-time dosimetric verification in high dose rate prostate brachytherapy

    SciTech Connect (OSTI)

    Seymour, Erin L.; Downes, Simon J.; Fogarty, Gerald B.; Izard, Michael A.; Metcalfe, Peter

    2011-08-15

    Purpose: To evaluate the performance of a diode array in the routine verification of planned dose to points inside the rectum from prostate high dose rate (HDR) brachytherapy using a real-time planning system. Methods: A dosimetric study involving 28 patients was undertaken where measured doses received during treatment were compared to those calculated by the treatment planning system (TPS). After the ultrasound imaging required for treatment planning had been recorded, the ultrasound probe was replaced with a geometric replica that contained an 8 mm diameter cylindrical cavity in which a PTW diode array type 9112 was placed. The replica probe was then positioned inside the rectum with the individual diode positions determined using fluoroscopy. Dose was then recorded during the patients' treatment and compared to associated coordinates in the planning system. Results: Factors influencing diode response and experimental uncertainty were initially investigated to estimate the overall uncertainty involved in dose measurements, which was determined to be {+-}10%. Data was acquired for 28 patients' first fractions, 11 patients' second fractions, and 13 patients' third fractions with collection dependent upon circumstances. Deviations between the diode measurements and predicted values ranged from -42% to +35% with 71% of measurements experiencing less than a 10% deviation from the predicted values. If the {+-}10% measurement uncertainty was combined with a tolerated dose discrepancy of {+-}10% then over 95% of the diode results exhibited agreement with the calculated data to within {+-}20%. It must also be noted that when large dose discrepancies were apparent they did not necessarily occur for all five diodes in the one measurement. Conclusions: This technique provided a method that could be utilized to detect gross errors in dose delivery of a real-time prostate HDR plan. Limitations in the detection system used must be well understood if meaningful results are to

  20. a-Si:H Grown by Hot-Wire CVD at Ultra-High Deposition Rates

    SciTech Connect (OSTI)

    Xu, Y.; Nelson, B. P.; Mahan, A. H.; Williamson, D. L.; Crandall, R. S.; Iwaniczko, E.; Wang, Q.

    2000-01-01

    We increase the deposition rate of growing hydrogenated amorphous-silicon (a-Si:H) by the hot-wire chemical vapor depositon (HWCVD) technique by adding filaments (two) and decreasing the filament(s) to substrate distance.

  1. Bright high-repetition-rate source of narrowband extreme-ultraviolet...

    Office of Scientific and Technical Information (OSTI)

    femtosecond extreme-ultraviolet pulses at 50-kHz repetition rate, utilizing the ... Spectral isolation of a single 72-meV-wide harmonic renders this bright, 50-kHz ...

  2. A high sensitivity fiber optic macro-bend based gas flow rate transducer for low flow rates: Theory, working principle, and static calibration

    SciTech Connect (OSTI)

    Schena, Emiliano; Saccomandi, Paola; Silvestri, Sergio

    2013-02-15

    A novel fiber optic macro-bend based gas flowmeter for low flow rates is presented. Theoretical analysis of the sensor working principle, design, and static calibration were performed. The measuring system consists of: an optical fiber, a light emitting diode (LED), a Quadrant position sensitive Detector (QD), and an analog electronic circuit for signal processing. The fiber tip undergoes a deflection in the flow, acting like a cantilever. The consequent displacement of light spot center is monitored by the QD generating four unbalanced photocurrents which are function of fiber tip position. The analog electronic circuit processes the photocurrents providing voltage signal proportional to light spot position. A circular target was placed on the fiber in order to increase the sensing surface. Sensor, tested in the measurement range up to 10 l min{sup -1}, shows a discrimination threshold of 2 l min{sup -1}, extremely low fluid dynamic resistance (0.17 Pa min l{sup -1}), and high sensitivity, also at low flow rates (i.e., 33 mV min l{sup -1} up to 4 l min{sup -1} and 98 mV min l{sup -1} from 4 l min{sup -1} up to 10 l min{sup -1}). Experimental results agree with the theoretical predictions. The high sensitivity, along with the reduced dimension and negligible pressure drop, makes the proposed transducer suitable for medical applications in neonatal ventilation.

  3. The susceptibility of TaOx-based memristors to high dose rate ionizing radiation and total ionizing dose

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    McLain, Michael Lee; Sheridan, Timothy J.; Hjalmarson, Harold Paul; Mickel, Patrick R.; Hanson, Donald J.; McDonald, Joseph K.; Hughart, David Russell; Marinella, Matthew J.

    2014-11-11

    This paper investigates the effects of high dose rate ionizing radiation and total ionizing dose (TID) on tantalum oxide (TaOx) memristors. Transient data were obtained during the pulsed exposures for dose rates ranging from approximately 5.0 ×107 rad(Si)/s to 4.7 ×108 rad(Si)/s and for pulse widths ranging from 50 ns to 50 μs. The cumulative dose in these tests did not appear to impact the observed dose rate response. Static dose rate upset tests were also performed at a dose rate of ~3.0 ×108 rad(Si)/s. This is the first dose rate study on any type of memristive memory technology. Inmore » addition to assessing the tolerance of TaOx memristors to high dose rate ionizing radiation, we also evaluated their susceptibility to TID. The data indicate that it is possible for the devices to switch from a high resistance off-state to a low resistance on-state in both dose rate and TID environments. The observed radiation-induced switching is dependent on the irradiation conditions and bias configuration. Furthermore, the dose rate or ionizing dose level at which a device switches resistance states varies from device to device; the enhanced susceptibility observed in some devices is still under investigation. As a result, numerical simulations are used to qualitatively capture the observed transient radiation response and provide insight into the physics of the induced current/voltages.« less

  4. High rate, long cycle life battery electrode materials with an open framework structure

    DOE Patents [OSTI]

    Wessells, Colin; Huggins, Robert; Cui, Yi; Pasta, Mauro

    2015-02-10

    A battery includes a cathode, an anode, and an aqueous electrolyte disposed between the cathode and the anode and including a cation A. At least one of the cathode and the anode includes an electrode material having an open framework crystal structure into which the cation A is reversibly inserted during operation of the battery. The battery has a reference specific capacity when cycled at a reference rate, and at least 75% of the reference specific capacity is retained when the battery is cycled at 10 times the reference rate.

  5. Adaptation of the CVT algorithm for catheter optimization in high dose rate brachytherapy

    SciTech Connect (OSTI)

    Poulin, Eric; Fekete, Charles-Antoine Collins; Beaulieu, Luc; Létourneau, Mélanie; Fenster, Aaron; Pouliot, Jean

    2013-11-15

    Purpose: An innovative, simple, and fast method to optimize the number and position of catheters is presented for prostate and breast high dose rate (HDR) brachytherapy, both for arbitrary templates or template-free implants (such as robotic templates).Methods: Eight clinical cases were chosen randomly from a bank of patients, previously treated in our clinic to test our method. The 2D Centroidal Voronoi Tessellations (CVT) algorithm was adapted to distribute catheters uniformly in space, within the maximum external contour of the planning target volume. The catheters optimization procedure includes the inverse planning simulated annealing algorithm (IPSA). Complete treatment plans can then be generated from the algorithm for different number of catheters. The best plan is chosen from different dosimetry criteria and will automatically provide the number of catheters and their positions. After the CVT algorithm parameters were optimized for speed and dosimetric results, it was validated against prostate clinical cases, using clinically relevant dose parameters. The robustness to implantation error was also evaluated. Finally, the efficiency of the method was tested in breast interstitial HDR brachytherapy cases.Results: The effect of the number and locations of the catheters on prostate cancer patients was studied. Treatment plans with a better or equivalent dose distributions could be obtained with fewer catheters. A better or equal prostate V100 was obtained down to 12 catheters. Plans with nine or less catheters would not be clinically acceptable in terms of prostate V100 and D90. Implantation errors up to 3 mm were acceptable since no statistical difference was found when compared to 0 mm error (p > 0.05). No significant difference in dosimetric indices was observed for the different combination of parameters within the CVT algorithm. A linear relation was found between the number of random points and the optimization time of the CVT algorithm. Because the

  6. Neutron diffraction measurements of dislocation density in copper crystals deformed at high strain rate

    SciTech Connect (OSTI)

    Rao, Mala N.; Chaplot, S. L.; Rawat, S.

    2013-02-05

    Neutron diffraction measurements of the rocking curves were carried out for single crystals of copper subjected to dynamic compression at 10{sup 3}/s strain rate. The line broadening is expected to be produced by dislocations, and an analysis of this broadening gives the dislocation density. Dislocation density is found to increase with increase of pressure.

  7. Damping rate and Lyapunov exponent of a Higgs field at high temperature

    SciTech Connect (OSTI)

    Biro, T.S.; Thoma, M.H.

    1996-09-01

    The damping rate of a Higgs field at zero momentum is calculated using the Braaten-Pisarski method and compared to the Lyapunov exponent of the classical SU(2) Yang-Mills Higgs system. {copyright} {ital 1996 The American Physical Society.}

  8. INTERNATIONAL STUDIES OF ENHANCED WASTE LOADING AND IMPROVED MELT RATE FOR HIGH ALUMINA CONCENTRATION NUCLEAR WASTE GLASSES

    SciTech Connect (OSTI)

    Fox, K; David Peeler, D; James Marra, J

    2008-09-11

    The goal of this study was to determine the impacts of glass compositions with high aluminum concentrations on melter performance, crystallization and chemical durability for Savannah River Site (SRS) and Hanford waste streams. Glass compositions for Hanford targeted both high aluminum concentrations in waste sludge and a high waste loading in the glass. Compositions for SRS targeted Sludge Batch 5, the next sludge batch to be processed in the Defense Waste Processing Facility (DWPF), which also has a relatively high aluminum concentration. Three frits were selected for combination with the SRS waste to evaluate their impact on melt rate. The glasses were melted in two small-scale test melters at the V. G. Khlopin Radium Institute. The results showed varying degrees of spinel formation in each of the glasses. Some improvements in melt rate were made by tailoring the frit composition for the SRS feeds. All of the Hanford and SRS compositions had acceptable chemical durability.

  9. Elementary reaction rate measurements at high temperatures by tunable-laser flash-absorption

    SciTech Connect (OSTI)

    Hessler, J.P.

    1993-12-01

    The major objective of this program is to measure thermal rate coefficients and branching ratios of elementary reactions. To perform these measurements, the authors constructed an ultrahigh-purity shock tube to generate temperatures between 1000 and 5500 K. The tunable-laser flash-absorption technique is used to measure the rate of change of the concentration of species which absorb below 50,000 cm{sup {minus}1} e.g.: OH, CH, and CH{sub 3}. This technique is being extended into the vacuum-ultraviolet spectral region where one can measure atomic species e.g.: H, D, C, O, and N; and diatomic species e.g.: O{sub 2}, CO, and OH.

  10. Method to grow pure nanocrystalline diamond films at low temperatures and high deposition rates

    DOE Patents [OSTI]

    Carlisle, John A.; Gruen, Dieter M.; Auciello, Orlando; Xiao, Xingcheng

    2009-07-07

    A method of depositing nanocrystalline diamond film on a substrate at a rate of not less than about 0.2 microns/hour at a substrate temperature less than about 500.degree. C. The method includes seeding the substrate surface with nanocrystalline diamond powder to an areal density of not less than about 10.sup.10sites/cm.sup.2, and contacting the seeded substrate surface with a gas of about 99% by volume of an inert gas other than helium and about 1% by volume of methane or hydrogen and one or more of acetylene, fullerene and anthracene in the presence of a microwave induced plasma while maintaining the substrate temperature less than about 500.degree. C. to deposit nanocrystalline diamond on the seeded substrate surface at a rate not less than about 0.2 microns/hour. Coatings of nanocrystalline diamond with average particle diameters of less than about 20 nanometers can be deposited with thermal budgets of 500.degree. C.-4 hours or less onto a variety of substrates such as MEMS devices.

  11. High Efficiency and High Rate Deposited Amorphous Silicon-Based Solar Cells: Final Technical Report, 1 September 2001--6 March 2005

    SciTech Connect (OSTI)

    Deng, X.

    2006-01-01

    The objectives for the University of Toledo are to: (1) establish a transferable knowledge and technology base for fabricating high-efficiency triple-junction a-Si-based solar cells, and (2) develop high-rate deposition techniques for the growing a-Si-based and related alloys, including poly-Si, c-Si, a-SiGe, and a-Si films and photovoltaic devices with these materials.

  12. Characteristics of high-rate energy spectroscopy systems using HPGe coaxial detectors and time-variant filters

    SciTech Connect (OSTI)

    Britton, C.L.; Becker, T.H.; Paulus, T.J.; Trammell, R.C.

    1984-02-01

    A high-rate, high-resolution gamma spectrometer system is described. The system consists of a reverse electrode HPGe coaxial detector, a transistor reset preamplifier, an active, semi-Gaussian prefilter, a gated integrator, and a unique data acquisition system consisting of a 10 ..mu..s, 13 bit ADC, fast FIFO memory, 8k by 23 bit data memory, and computer interface circuitry under the control of a Z-80A ..mu..P. The effects of the various components on the throughput are described and throughput data is presented. The resolution and peak shift for various shaping times are presented for count rates up to 1 Mcps input rate using a mixed /sup 22/Na and /sup 60/Co source. The low rate resolutions of /sup 57/Co and /sup 60/Co for various shaping times using either the semi-Gaussian or gated integrator output are discussed as well as the low energy resolution and peak shifts in the presence of high energy events.

  13. Bifurcation and neck formation as a precursor to ductile fracture during high rate extension

    SciTech Connect (OSTI)

    Freund, L.B.; Soerensen, N.J.

    1997-12-31

    A block of ductile material, typically a segment of a plate or shell, being deformed homogeneously in simple plane strain extension commonly undergoes a bifurcation in deformation mode to nonuniform straining in the advanced stages of plastic flow. The focus here is on the influence of material inertia on the bifurcation process, particularly on the formation of diffuse necks as precursors to dynamic ductile fracture. The issue is considered from two points of view, first within the context of the theory of bifurcation of rate-independent, incrementally linear materials and then in terms of the complete numerical solution of a boundary value problem for an elastic-viscoplastic material. It is found that inertia favors the formation of relatively short wavelength necks as observed in shaped charge break-up and dynamic fragmentation.

  14. Remotely-interrogated high data rate free space laser communications link

    DOE Patents [OSTI]

    Ruggiero, Anthony J.

    2007-05-29

    A system and method of remotely extracting information from a communications station by interrogation with a low power beam. Nonlinear phase conjugation of the low power beam results in a high power encoded return beam that automatically tracks the input beam and is corrected for atmospheric distortion. Intracavity nondegenerate four wave mixing is used in a broad area semiconductor laser in the communications station to produce the return beam.

  15. High rate buffer layer for IBAD MgO coated conductors

    DOE Patents [OSTI]

    Foltyn, Stephen R.; Jia, Quanxi; Arendt, Paul N.

    2007-08-21

    Articles are provided including a base substrate having a layer of an oriented material thereon, and, a layer of hafnium oxide upon the layer of an oriented material. The layer of hafnium oxide can further include a secondary oxide such as cerium oxide, yttrium oxide, lanthanum oxide, scandium oxide, calcium oxide and magnesium oxide. Such articles can further include thin films of high temperature superconductive oxides such as YBCO upon the layer of hafnium oxide or layer of hafnium oxide and secondary oxide.

  16. High flow rate nozzle system with production of uniform size droplets

    DOE Patents [OSTI]

    Stockel, I.H.

    1990-10-16

    Method steps for production of substantially uniform size droplets from a flow of liquid include forming the flow of liquid, periodically modulating the momentum of the flow of liquid in the flow direction at controlled frequency, generating a cross flow direction component of momentum and modulation of the cross flow momentum of liquid at substantially the same frequency and phase as the modulation of flow direction momentum, and spraying the so formed modulated flow through a first nozzle outlet to form a desired spray configuration. A second modulated flow through a second nozzle outlet is formed according to the same steps, and the first and second modulated flows impinge upon each other generating a liquid sheet. Nozzle apparatus for modulating each flow includes rotating valving plates interposed in the annular flow of liquid. The plates are formed with radial slots. Rotation of the rotating plates is separably controlled at differential angular velocities for a selected modulating frequency to achieve the target droplet size and production rate for a given flow. The counter rotating plates are spaced to achieve a desired amplitude of modulation in the flow direction, and the angular velocity of the downstream rotating plate is controlled to achieve the desired amplitude of modulation of momentum in the cross flow direction. Amplitude of modulation is set according to liquid viscosity. 5 figs.

  17. High flow rate nozzle system with production of uniform size droplets

    DOE Patents [OSTI]

    Stockel, Ivar H.

    1990-01-01

    Method steps for production of substantially uniform size droplets from a flow of liquid include forming the flow of liquid, periodically modulating the momentum of the flow of liquid in the flow direction at controlled frequency, generating a cross flow direction component of momentum and modulation of the cross flow momentum of liquid at substantially the same frequency and phase as the modulation of flow direction momentum, and spraying the so formed modulated flow through a first nozzle outlet to form a desired spray configuration. A second modulated flow through a second nozzle outlet is formed according to the same steps, and the first and second modulated flows impinge upon each other generating a liquid sheet. Nozzle apparatus for modulating each flow includes rotating valving plates interposed in the annular flow of liquid. The plates are formed with radial slots. Rotation of the rotating plates is separably controlled at differential angular velocities for a selected modulating frequency to achieve the target droplet size and production rate for a given flow. The counter rotating plates are spaced to achieve a desired amplitude of modulation in the flow direction, and the angular velocity of the downstream rotating plate is controlled to achieve the desired amplitude of modulation of momentum in the cross flow direction. Amplitude of modulation is set according to liquid viscosity.

  18. The Stress Corrosion Crack Growth Rate of Alloy 600 Heat Affected Zones Exposed to High Purity Water

    SciTech Connect (OSTI)

    George A. Young; Nathan Lewis

    2003-04-05

    Grain boundary chromium carbides improve the resistance of nickel based alloys to primary water stress corrosion cracking (PWSCC). However, in weld heat affected zones (HAZ's), thermal cycles from fusion welding can solutionize beneficial grain boundary carbides, produce locally high residual stresses and strains, and promote PWSCC. The present research investigates the crack growth rate of an A600 HAZ as a function of test temperature. The A600 HAZ was fabricated by building up a gas-tungsten-arc-weld deposit of EN82H filler metal onto a mill-annealed A600 plate. Fracture mechanics based, stress corrosion crack growth rate testing was performed in high purity water between 600 F and 680 F at an initial stress intensity factor of 40 ksi {radical}in and at a constant electrochemical potential. The HAZ samples exhibited significant SCC, entirely within the HAZ at all temperatures tested. While the HAZ samples showed the same temperature dependence for SCC as the base material (HAZ: 29.8 {+-} 11.2{sub 95%} kcal/mol vs A600 Base: 35.3 {+-} 2.58{sub 95%} kcal/mol), the crack growth rates were {approx} 30X faster than the A600 base material tested at the same conditions. The increased crack growth rates of the HAZ is attributed to fewer intergranular chromium rich carbides and to increased plastic strain in the HAZ as compared to the unaffected base material.

  19. Size control, quantum confinement, and oxidation kinetics of silicon nanocrystals synthesized at a high rate by expanding thermal plasma

    SciTech Connect (OSTI)

    Han, Lihao E-mail: A.H.M.Smets@tudelft.nl; Zeman, Miro; Smets, Arno H. M. E-mail: A.H.M.Smets@tudelft.nl

    2015-05-25

    The growth mechanism of silicon nanocrystals (Si NCs) synthesized at a high rate by means of expanding thermal plasma chemical vapor deposition technique are studied in this letter. A bimodal Gaussian size distribution is revealed from the high-resolution transmission electron microscopy images, and routes to reduce the unwanted large Si NCs are discussed. Photoluminescence and Raman spectroscopies are employed to study the size-dependent quantum confinement effect, from which the average diameters of the small Si NCs are determined. The surface oxidation kinetics of Si NCs are studied using Fourier transform infrared spectroscopy and the importance of post-deposition passivation treatments of hydrogenated crystalline silicon surfaces are demonstrated.

  20. Nature of high-energy ions in the cathode plasma jet of a vacuum arc with high rate of current rise

    SciTech Connect (OSTI)

    Beilis, I.I.

    2004-10-04

    The production mechanism of extremely high-energy (up to 10 keV) ions observed in vacuum arcs having only a few tens of volts of arc voltage was considered. A model was developed for the plasma acceleration in a high-current ({>=}1 kA) short pulsed (<1 {mu}s) vacuum arc, taking into account the high rate of rise of the spot current (dI/dt>100 MA/s). A system of equations, including equations for the cathode spot and the plasma jet, was solved self-consistently with dI/dt in the range of 0.1-10 GA/s. It was shown that the plasma could be accelerated to the measured energy in the near spot region due to a gas dynamic mechanism and that the ion energy depends on the ratio of the ion flux to the electron flux. This ratio is determined by the cathode erosion rate. The calculated cathode erosion rate varies from 200 to 10 {mu}g/C when the ion energy increases from 0.1 to 10 keV and well agrees with measurements.

  1. Extremely high-rate, uniform dissolution of alloy C-22 in anhydrous organic solutions at room temperature

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schindelholz, Eric J.; Christie, Michael A.; Allwein, Shawn P.; Kelly, Robert G.

    2016-06-21

    During routine pharmaceutical development and scale-up work, severe corrosion of a Hastelloy Alloy C-22 filter dryer was observed after single, short (several hours) contact with the product slurry at room temperature. Initial investigations showed that the presence of both 2,3-dichloro-5,6-dicyano-1,4-benzoquinone (DDQ) and HCl was sufficient in an acetonitrile solution to cause rapid corrosion of C-22. More detailed mass loss studies showed initial corrosion rates exceeding25 mm/year that then decreased over several hours to steady state rates of 3-5 mm/year. The corrosion was highly uniform. Electrochemical measurements demonstrated that although C-22 is spontaneously passive in acetonitrile solution, the presence of HClmore » leads to the development of a transpassive region. Furthermore, DDQ is a sufficiently strong oxidizer, particularly in acidic solutions, to polarize the C-22 well into the transpassive region, leading to the observed high corrosion rates.« less

  2. Simultaneous X-ray diffraction and phase-contrast imaging for investigating material deformation mechanisms during high-rate loading

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hudspeth, M.; Sun, T.; Parab, N.; Guo, Z.; Fezzaa, K.; Luo, S.; Chen, W.

    2015-01-01

    Using a high-speed camera and an intensified charge-coupled device (ICCD), a simultaneous X-ray imaging and diffraction technique has been developed for studying dynamic material behaviors during high-rate tensile loading. A Kolsky tension bar has been used to pull samples at 1000 s–1and 5000 s–1strain-rates for super-elastic equiatomic NiTi and 1100-O series aluminium, respectively. By altering the ICCD gating time, temporal resolutions of 100 ps and 3.37 µs have been achieved in capturing the diffraction patterns of interest, thus equating to single-pulse and 22-pulse X-ray exposure. Furthermore, the sample through-thickness deformation process has been simultaneously imagedviaphase-contrast imaging. It is also shownmore » that adequate signal-to-noise ratios are achieved for the detected white-beam diffraction patterns, thereby allowing sufficient information to perform quantitative data analysis diffractionviain-house software (WBXRD_GUI). Finally, of current interest is the ability to evaluate crystald-spacing, texture evolution and material phase transitions, all of which will be established from experiments performed at the aforementioned elevated strain-rates.« less

  3. Rapid heating tensile tests of hydrogen-charged high-energy-rate-forged 316L stainless steel

    SciTech Connect (OSTI)

    Mosley, W.C.

    1989-05-19

    316L stainless steel is a candidate material for construction of equipment that will be exposed to tritium. Proper design of the equipment will require an understanding of how tritium and its decay product helium affect mechanical properties. This memorandum describes results of rapid heating tensile testing of hydrogen-charged specimens of high-energy-rate-forged (HERF) 316L stainless steel. These results provide a data base for comparison with uncharged and tritium-charged-and-aged specimens to distinguish the effects of hydrogen and helium. Details of the experimental equipment and procedures and results for uncharged specimens were reported previously. 3 refs., 10 figs.

  4. 'In vivo' Dose Measurements in High-Dose-Rate Brachytherapy Treatments for Cervical Cancer: A Project Proposal

    SciTech Connect (OSTI)

    Reynoso Mejia, C. A.; Buenfil Burgos, A. E.; Ruiz Trejo, C.; Mota Garcia, A.; Trejo Duran, E.; Rodriguez Ponce, M.; Gamboa de Buen, I.

    2010-12-07

    The aim of this thesis project is to compare doses calculated from the treatment planning system using computed tomography images, with those measured 'in vivo' by using thermoluminescent dosimeters placed at different regions of the rectum and bladder of a patient during high-dose-rate intracavitary brachytherapy treatment of uterine cervical carcinoma. The experimental dosimeters characterisation and calibration have concluded and the protocol to carry out the 'in vivo' measurements has been established. In this work, the calibration curves of two types of thermoluminescent dosimeters (rods and chips) are presented, and the proposed protocol to measure the 'in vivo' dose is fully described.

  5. Outcomes of High-Dose-Rate Interstitial Brachytherapy in the Treatment of Locally Advanced Cervical Cancer: Long-term Results

    SciTech Connect (OSTI)

    Pinn-Bingham, Melva; Puthawala, Ajmel A.; Syed, A.M. Nisar; Sharma, Anil; DiSaia, Philip; Berman, Michael; Tewari, Krishnansu S.; Randall-Whitis, Leslie; Mahmood, Usama; Ramsinghani, Nilam; Kuo, Jeffrey; Chen, Wen-Pin; McLaren, Christine E.

    2013-03-01

    Purpose: The purpose of this study was to determine locoregional control (LRC), disease-free survival (DFS), and toxicity of high-dose-rate interstitial brachytherapy (HDR-ISBT) in the treatment of locally advanced cervical cancer. Methods and Materials: Between March 1996 and May 2009, 116 patients with cervical cancer were treated. Of these, 106 (91%) patients had advanced disease (International Federation of Gynecology and Obstetrics stage IIB-IVA). Ten patients had stage IB, 48 had stage II, 51 had stage III, and 7 had stage IVA disease. All patients were treated with a combination of external beam radiation therapy (EBRT) to the pelvis (5040 cGy) and 2 applications of HDR-ISBT to a dose of 3600 cGy to the implanted volume. Sixty-one percent of patients also received interstitial hyperthermia, and 94 (81%) patients received chemotherapy. Results: Clinical LRC was achieved in 99 (85.3%) patients. Three-year DFS rates were 59%, 67%, 71%, and 57% for patients with stage IB, II, III, and IVA disease, respectively. The 5-year DFS and overall survival rates for the entire group were 60% and 44%, respectively. Acute and late toxicities were within acceptable limits. Conclusions: Locally advanced cervical cancer patients for whom intracavitary BT is unsuitable can achieve excellent LRC and OS with a combination of EBRT and HDR-ISBT.

  6. Effect of cooling rate on the properties of high density polyethylene/multi-walled carbon nanotube composites

    SciTech Connect (OSTI)

    Xiang, Dong; Harkin-Jones, Eileen; Linton, David

    2015-05-22

    High density polyethylene (HDPE)/multi-walled carbon nanotube (MWCNT) nanocomposites were prepared by melt mixing using twin-screw extrusion. The extruded pellets were compression moulded at 200°C for 5min followed by cooling at different cooling rates (20°C/min and 300°C/min respectively) to produce sheets for characterization. Scanning electron microscopy (SEM) shows that the MWCNTs are uniformly dispersed in the HDPE. At 4 wt% addition of MWCNTs composite modulus increased by over 110% compared with the unfilled HDPE (regardless of the cooling rate). The yield strength of both unfilled and filled HDPE decreased after rapid cooling by about 10% due to a lower crystallinity and imperfect crystallites. The electrical percolation threshold of composites, irrespective of the cooling rate, is between a MWCNT concentration of 1∼2 wt%. Interestingly, the electrical resistivity of the rapidly cooled composite with 2 wt% MWCNTs is lower than that of the slowly cooled composites with the same MWCNT loading. This may be due to the lower crystallinity and smaller crystallites facilitating the formation of conductive pathways. This result may have significant implications for both process control and the tailoring of electrical conductivity in the manufacture of conductive HDPE/MWCNT nanocomposites.

  7. High-nitrogen-metal complexes as burning-rate modifiers for the aluminum-water propellant system

    SciTech Connect (OSTI)

    Tappan, Bryce C; Mason, Benjamin A

    2009-01-01

    The reactions of electropositive metals, such as aluminum, with water have long been utilized in explosive and propellant formulations, but until recently this has mostly been limited to the water formed as a product gas from the decomposition of another energetic system . Recently, however, with the increased availability of nano-particulate materials, the direct reaction of nano-aluminum (nAl) with water as an oxidizer has been investigated as a propellant system due to high reaction temperatures and the production of hydrogen as the primary gaseous species. This system could be useful for intra-planetary travel where non-terrestrial water is harvested for the oxidizer. Here we present the study of nAl, mixed at a stoichiometric ratio with water ({Phi} = 1) with the highly water soluble metal complexes of bis(tetrazolato)amine (BTA) added at 5, 15,30 and 50 wt% in the case of FeBTA and 5 and 15 wt% in the case of NiBTA and CoBTA. The basic structure of the BTA complexes is shown below where M = Fe, Ni or Co, and x = 3 for Fe and Co and x = 2 for Ni. The particle size of nAl studied was primarily 38 nm with various studies with the particle size of 80 nm. The FeBT A at a loading of 15 wt% gave the highest burning rate enhancement (4.6x at {approx}6.8 MPa), while retaining a low pressure exponent (0.21 compared to 0.24 for nA/H{sub 2}O). At 15 wt% the Ni and Co increased the burning rate, but also increased the pressure exponents. The burning rate of the FeBTA modified material with 80 nm Al decreased as the weight percent of FeBTA was increased, which also tracked decrease in the calculated specific impulse of the mixtures.

  8. Intense high repetition rate Mo Kα x-ray source generated from laser solid interaction for imaging application

    SciTech Connect (OSTI)

    Huang, K.; Li, M. H.; Yan, W. C.; Ma, Y.; Zhao, J. R.; Li, Y. F.; Chen, L. M.; Guo, X.; Li, D. Z.; Chen, Y. P.; Zhang, J.

    2014-11-15

    We report an efficient Mo Kα x-ray source produced by interaction of femtosecond Ti: sapphire laser pulses with a solid Molybdenum target working at 1 kHz repetition rate. The generated Mo Kα x-ray intensity reaches to 4.7 × 10{sup 10} photons sr{sup −1} s{sup −1}, corresponding to an average power of 0.8 mW into 2π solid angle. The spatial resolution of this x-ray source is measured to be 26 lp/mm. With the high flux and high spatial resolution characteristics, high resolving in-line x-ray radiography was realized on test objects and large size biological samples within merely half a minute. This experiment shows the possibility of laser plasma hard x-ray source as a new low cost and high resolution system for radiography and its ability of ultrafast x-ray pump-probe study of matter.

  9. Investigations of DNA damage induction and repair resulting from cellular exposure to high dose-rate pulsed proton beams

    SciTech Connect (OSTI)

    Renis, M.; Malfa, G.; Tomasello, B.; Borghesi, M.; Schettino, G.; Favetta, M.; Romano, F.; Cirrone, G. A. P.; Manti, L.

    2013-07-26

    Studies regarding the radiobiological effects of low dose radiation, microbeam irradiation services have been developed in the world and today laser acceleration of protons and heavy ions may be used in radiation therapy. The application of different facilities is essential for studying bystander effects and relating signalling phenomena in different cells or tissues. In particular the use of ion beams results advantageous in cancer radiotherapy compared to more commonly used X-rays, since the ability of ions in delivering lethal amount of doses into the target tumour avoiding or limiting damage to the contiguous healthy tissues. At the INFN-LNS in Catania, a multidisciplinary radiobiology group is strategically structured aimed to develop radiobiological research, finalised to therapeutic applications, compatible with the use of high dose laser-driven ion beams. The characteristic non-continuous dose rates with several orders of magnitude of laser-driven ion beams makes this facility very interesting in the cellular systems' response to ultra-high dose rates with non-conventional pulse time intervals cellular studies. Our group have projected to examine the effect of high dose laser-driven ion beams on two cellular types: foetal fibroblasts (normal control cells) and DU145 (prostate cancer cells), studying the modulation of some different bio-molecular parameters, in particular cell proliferation and viability, DNA damage, redox cellular status, morphological alterations of both the cytoskeleton components and some cell organelles and the possible presence of apoptotic or necrotic cell death. Our group performed preliminary experiments with high energy (60 MeV), dose rate of 10 Gy/min, doses of 1, 2, 3 Gy and LET 1 keV/?m on human foetal fibroblasts (control cells). We observed that cell viability was not influenced by the characteristics of the beam, the irradiation conditions or the analysis time. Conversely, DNA damage was present at time 0, immediately

  10. Supermassive black holes with high accretion rates in active galactic nuclei. II. The most luminous standard candles in the universe

    SciTech Connect (OSTI)

    Wang, Jian-Min; Du, Pu; Hu, Chen; Qiu, Jie; Li, Yan-Rong [Key Laboratory for Particle Astrophysics, Institute of High Energy Physics, Chinese Academy of Sciences, 19B Yuquan Road, Beijing 100049 (China); Netzer, Hagai; Kaspi, Shai [Wise Observatory, School of Physics and Astronomy, Tel-Aviv University, Tel-Aviv 69978 (Israel); Bai, Jin-Ming; Wang, Fang [Yunnan Observatory, Chinese Academy of Sciences, Kunming 650011, Yunnan (China); Lu, Kai-Xing [Astronomy Department, Beijing Normal University, Beijing 100875 (China); Collaboration: SEAMBH collaboration

    2014-10-01

    This is the second in a series of papers reporting on a large reverberation mapping (RM) campaign to measure black hole (BH) mass in high accretion rate active galactic nuclei (AGNs). The goal is to identify super-Eddington accreting massive black holes (SEAMBHs) and to use their unique properties to construct a new method for measuring cosmological distances. Based on theoretical models, the saturated bolometric luminosity of such sources is proportional to the BH mass, which can be used to obtain their distance. Here we report on five new RM measurements and show that in four of the cases, we can measure the BH mass and three of these sources are SEAMBHs. Together with the three sources from our earlier work, we now have six new sources of this type. We use a novel method based on a minimal radiation efficiency to identify nine additional SEAMBHs from earlier RM-based mass measurements. We use a Bayesian analysis to determine the parameters of the new distance expression and the method uncertainties from the observed properties of the objects in the sample. The ratio of the newly measured distances to the standard cosmological ones has a mean scatter of 0.14 dex, indicating that SEAMBHs can be use as cosmological distance probes. With their high luminosity, long period of activity, and large numbers at high redshifts, SEAMBHs have a potential to extend the cosmic distance ladder beyond the range now explored by Type Ia supernovae.

  11. High-Dose-Rate Brachytherapy for Non-Small-Cell Lung Carcinoma: A Retrospective Study of 226 Patients

    SciTech Connect (OSTI)

    Aumont-le Guilcher, Maud; Prevost, Bernard; Sunyach, Marie Pierre; Peiffert, Didier; Maingon, Philippe; Thomas, Laurence; Williaume, Daniele; Begue, Mickael; Lerouge, Delphine; Campion, Loic; Mahe, Marc-Andre

    2011-03-15

    Purpose: To evaluate the efficacy and toxicity of high-dose-rate (HDR) brachytherapy in patients with inoperable endobronchial carcinoma. Methods and Materials: We retrospectively reviewed the records (April 1991-May 2004) of patients with non-small-cell carcinoma, with no extrabronchial spread on computed tomography scans, who underwent HDR brachytherapy because of contraindications to surgery and external beam radiation therapy. Kaplan-Meier survival curves were compared by the log-rank test. Prognostic factors were analyzed by multivariate analysis. Results: 226 patients (223 men, 3 women, mean age: 62.2 years (range, 40-84)) were included. Of those, 217 (97%) had squamous cell carcinoma (Tis/T1/T2/Tx: 60/153/9/4). Dose was prescribed at 1 cm from the radius (24-35 Gy in 4-6 fractions). Mean follow-up was 30.4 months (range, 9-116). Complete endoscopic response rate was 93.6% at 3 months. One hundred twenty-eight patients (56%) died of intercurrent disease (n = 45), local failure (n = 36), metastasis (n = 10), local failure and metastasis (n = 11), complications (n = 13), and other causes (n = 12). The 2-year and 5-year survival rates were, respectively, 57% and 29% (overall) (median, 28.6 months), 81% and 56% (cancer-specific), and 68% and 50% (local disease-free). Acute toxicity included pneumothorax (1.5%) and mucosal inflammation (10%). Late complications were hemoptysis (6.6% with 5% of fatalities), bronchitis (19.5%), and necrosis (3.5%). In multivariate analysis, a distal tumor location and the use of two catheters were associated with improved local disease-free survival (p = 0.003 and p = 0.007, respectively) and a distal tumor location with improved overall survival (p = 0.0001). Conclusions: This large retrospective study confirms that HDR brachytherapy is an efficient and safe treatment in patients with inoperable endobronchial carcinoma.

  12. A model for plasticity kinetics and its role in simulating the dynamic behavior of Fe at high strain rates

    SciTech Connect (OSTI)

    Colvin, J D; Minich, R W; Kalantar, D H

    2007-03-29

    The recent diagnostic capability of the Omega laser to study solid-solid phase transitions at pressures greater than 10 GPa and at strain rates exceeding 10{sup 7} s{sup -1} has also provided valuable information on the dynamic elastic-plastic behavior of materials. We have found, for example, that plasticity kinetics modifies the effective loading and thermodynamic paths of the material. In this paper we derive a kinetics equation for the time-dependent plastic response of the material to dynamic loading, and describe the model's implementation in a radiation-hydrodynamics computer code. This model for plasticity kinetics incorporates the Gilman model for dislocation multiplication and saturation. We discuss the application of this model to the simulation of experimental velocity interferometry data for experiments on Omega in which Fe was shock compressed to pressures beyond the {alpha}-to-{var_epsilon} phase transition pressure. The kinetics model is shown to fit the data reasonably well in this high strain rate regime and further allows quantification of the relative contributions of dislocation multiplication and drag. The sensitivity of the observed signatures to the kinetics model parameters is presented.

  13. Combustion Targets for Low Emissions and High Efficiency | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Targets for Low Emissions and High Efficiency Combustion Targets for Low Emissions and High Efficiency 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters 2005_deer_ryan.pdf (1.01 MB) More Documents & Publications Diesel Engine Alternatives An Experimental Investigation of Low Octane Gasoline in Diesel Engines SwRI's HEDGE Technology for High Efficiency, Low Emissions Gasoline Engines

  14. High rate mesophilic, thermophilic, and temperature phased anaerobic digestion of waste activated sludge: A pilot scale study

    SciTech Connect (OSTI)

    Bolzonella, David; Cavinato, Cristina; Fatone, Francesco; Pavan, Paolo; Cecchi, Franco

    2012-06-15

    Highlights: Black-Right-Pointing-Pointer High temperatures were tested in single and two-stage anaerobic digestion of waste activated sludge. Black-Right-Pointing-Pointer The increased temperature demonstrated the possibility of improving typical yields of the conventional mesophilic process. Black-Right-Pointing-Pointer The temperature phased anaerobic digestion process (65 + 55 Degree-Sign C) showed the best performances with yields of 0.49 m{sup 3}/kgVS{sub fed}. Black-Right-Pointing-Pointer Ammonia and phosphate released from solids destruction determined the precipitation of struvite in the reactor. - Abstract: The paper reports the findings of a two-year pilot scale experimental trial for the mesophilic (35 Degree-Sign C), thermophilic (55 Degree-Sign C) and temperature phased (65 + 55 Degree-Sign C) anaerobic digestion of waste activated sludge. During the mesophilic and thermophilic runs, the reactor operated at an organic loading rate of 2.2 kgVS/m{sup 3}d and a hydraulic retention time of 20 days. In the temperature phased run, the first reactor operated at an organic loading rate of 15 kgVS/m{sup 3}d and a hydraulic retention time of 2 days while the second reactor operated at an organic loading rate of 2.2 kgVS/m{sup 3}d and a hydraulic retention time of 18 days (20 days for the whole temperature phased system). The performance of the reactor improved with increases in temperature. The COD removal increased from 35% in mesophilic conditions, to 45% in thermophilic conditions, and 55% in the two stage temperature phased system. As a consequence, the specific biogas production increased from 0.33 to 0.45 and to 0.49 m{sup 3}/kgVS{sub fed} at 35, 55, and 65 + 55 Degree-Sign C, respectively. The extreme thermophilic reactor working at 65 Degree-Sign C showed a high hydrolytic capability and a specific yield of 0.33 gCOD (soluble) per gVS{sub fed}. The effluent of the extreme thermophilic reactor showed an average concentration of soluble COD and volatile

  15. ROLE OF MANGANESE REDUCTION/OXIDATION (REDOX) ON FOAMING AND MELT RATE IN HIGH LEVEL WASTE (HLW) MELTERS (U)

    SciTech Connect (OSTI)

    Jantzen, C; Michael Stone, M

    2007-03-30

    High-level nuclear waste is being immobilized at the Savannah River Site (SRS) by vitrification into borosilicate glass at the Defense Waste Processing Facility (DWPF). Control of the Reduction/Oxidation (REDOX) equilibrium in the DWPF melter is critical for processing high level liquid wastes. Foaming, cold cap roll-overs, and off-gas surges all have an impact on pouring and melt rate during processing of high-level waste (HLW) glass. All of these phenomena can impact waste throughput and attainment in Joule heated melters such as the DWPF. These phenomena are caused by gas-glass disequilibrium when components in the melter feeds convert to glass and liberate gases such as H{sub 2}O vapor (steam), CO{sub 2}, O{sub 2}, H{sub 2}, NO{sub x}, and/or N{sub 2}. During the feed-to-glass conversion in the DWPF melter, multiple types of reactions occur in the cold cap and in the melt pool that release gaseous products. The various gaseous products can cause foaming at the melt pool surface. Foaming should be avoided as much as possible because an insulative layer of foam on the melt surface retards heat transfer to the cold cap and results in low melt rates. Uncontrolled foaming can also result in a blockage of critical melter or melter off-gas components. Foaming can also increase the potential for melter pressure surges, which would then make it difficult to maintain a constant pressure differential between the DWPF melter and the pour spout. Pressure surges can cause erratic pour streams and possible pluggage of the bellows as well. For these reasons, the DWPF uses a REDOX strategy and controls the melt REDOX between 0.09 {le} Fe{sup 2+}/{summation}Fe {le} 0.33. Controlling the DWPF melter at an equilibrium of Fe{sup +2}/{summation}Fe {le} 0.33 prevents metallic and sulfide rich species from forming nodules that can accumulate on the floor of the melter. Control of foaming, due to deoxygenation of manganic species, is achieved by converting oxidized MnO{sub 2} or Mn

  16. PULSAR: A High-Repetition-Rate, High-Power, CE Phase-Locked Laser for the J.R. Macdonald Laboratory at Kansas State University

    SciTech Connect (OSTI)

    Ben-Itzhak, Itzik; Carnes, Kevin D.; Cocke, C. Lew; Fehrenbach, Charles W.; Kumarappan, Vinod; Rudenko, Artem; Trallero, Carlos

    2014-05-09

    This instrumentation grant funded the development and installation of a state-of-the-art laser system to be used for the DOE funded research at the J.R. Macdonald Laboratory at Kansas State University. Specifically, we purchased a laser based on the KMLABs Red-Dragon design, which has a high repetition rate of 10-20 kHz crucial for multi-parameter coincidence measurements conducted in our lab. This laser system is carrier-envelope phase (CEP) locked and provides pulses as short as 21 fs directly from the amplifier (see details below). In addition, we have developed a pulse compression setup that provides sub 5 fs pulses and a CEP tagging capability that allows for long measurements of CEP dependent processes.

  17. Nanoscale LiFePO4 and Li4Ti5O12 for High Rate Li-ion Batteries

    SciTech Connect (OSTI)

    Jaiswal, A.; Horne, C.R.; Chang, O.; Zhang, W.; Kong, W.; Wang, E.; Chern, T.; Doeff, M. M.

    2009-08-04

    The electrochemical performances of nanoscale LiFePO4 and Li4Ti5O12 materials are described in this communication. The nanomaterials were synthesized by pyrolysis of an aerosol precursor. Both compositions required moderate heat-treatment to become electrochemically active. LiFePO4 nanoparticles were coated with a uniform, 2-4 nm thick carbon-coating using an organic precursor in the heat treatment step and showed high tap density of 1.24 g/cm3, in spite of 50-100 nm particle size and 2.9 wtpercent carbon content. Li4Ti5O12 nanoparticles were between 50-200 nm in size and showed tap density of 0.8 g/cm3. The nanomaterials were tested both in half cell configurations against Li-metal and also in LiFePO4/Li4Ti5O12 full cells. Nano-LiFePO4 showed high discharge rate capability with values of 150 and 138 mAh/g at C/25 and 5C, respectively, after constant C/25 charges. Nano-Li4Ti5O12 also showed high charge capability with values of 148 and 138 mAh/g at C/25 and 5C, respectively, after constant C/25 discharges; the discharge (lithiation) capability was comparatively slower. LiFePO4/Li4Ti5O12 full cells deliver charge/discharge capacity values of 150 and 122 mAh/g at C/5 and 5C, respectively.

  18. AISI/DOE Technology Roadmap Program: A Technology of Low Coal Rate and High Productivity of RHF Ironmaking

    SciTech Connect (OSTI)

    Wei-Kao Lu

    2002-09-15

    An economical and environment-friendly ironmaking process based on heating the chemiexecy self-sufficient green balls of iron ore and coal in a hearth furnace is being developed with financial support from AISI members and DOE. DRI, which is hot (1400 C), dense (3.2 g/cm) and of high degree of metallization (95%), has been produced in laboratory and in a pilot plant in Genoa, Italy. Products of such quality have been made from American and Brazilian ores, BOF sludge, EAF dust/BOF sludge mixtures and millscale. The removal of zinc and lead from green balls by this process is essentially complete. In comparison with typical blast furnace operation, the new technology with a melter would have a lower total coal rate by 200kg.THM. The elimination of cokemaking and high temperature agglomeration steps, and a simpler gas handling system would lead to lower capital and operating costs. In comparison with commercial RHF practice it is different in atmosphere (fully oxidized at 1600 to 1650 C), in bed height (120 mm instead of 20-25 mm) and in pellet composition (much less coal but of higher VM). The combined effect leads to three times higher furnace productivity, lower coal consumption and superior DRI quality. The risk of re-oxidation (slag formation) and dusty operation are practiexecy eliminated. The process is stable, tolerant and independent of the size, shape and movement of the hearth. However, materials handling (e.g., discharge of hot DRI) and the exact energy savings have to be established in a larger furnace, straight or rotary, and in a continuous mode of operation.

  19. High Temperature Chemical Kinetic Combustion Modeling of Lightly Methylated Alkanes

    SciTech Connect (OSTI)

    Sarathy, S M; Westbrook, C K; Pitz, W J; Mehl, M

    2011-03-01

    Conventional petroleum jet and diesel fuels, as well as alternative Fischer-Tropsch (FT) fuels and hydrotreated renewable jet (HRJ) fuels, contain high molecular weight lightly branched alkanes (i.e., methylalkanes) and straight chain alkanes (n-alkanes). Improving the combustion of these fuels in practical applications requires a fundamental understanding of large hydrocarbon combustion chemistry. This research project presents a detailed high temperature chemical kinetic mechanism for n-octane and three lightly branched isomers octane (i.e., 2-methylheptane, 3-methylheptane, and 2,5-dimethylhexane). The model is validated against experimental data from a variety of fundamental combustion devices. This new model is used to show how the location and number of methyl branches affects fuel reactivity including laminar flame speed and species formation.

  20. Rate Information

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases Rate Information Current Power Rates Current Transmission Rates...

  1. HDRMC, an accelerated Monte Carlo dose calculator for high dose rate brachytherapy with CT-compatible applicators

    SciTech Connect (OSTI)

    Chibani, Omar C-M Ma, Charlie

    2014-05-15

    Purpose: To present a new accelerated Monte Carlo code for CT-based dose calculations in high dose rate (HDR) brachytherapy. The new code (HDRMC) accounts for both tissue and nontissue heterogeneities (applicator and contrast medium). Methods: HDRMC uses a fast ray-tracing technique and detailed physics algorithms to transport photons through a 3D mesh of voxels representing the patient anatomy with applicator and contrast medium included. A precalculated phase space file for the{sup 192}Ir source is used as source term. HDRM is calibrated to calculated absolute dose for real plans. A postprocessing technique is used to include the exact density and composition of nontissue heterogeneities in the 3D phantom. Dwell positions and angular orientations of the source are reconstructed using data from the treatment planning system (TPS). Structure contours are also imported from the TPS to recalculate dose-volume histograms. Results: HDRMC was first benchmarked against the MCNP5 code for a single source in homogenous water and for a loaded gynecologic applicator in water. The accuracy of the voxel-based applicator model used in HDRMC was also verified by comparing 3D dose distributions and dose-volume parameters obtained using 1-mm{sup 3} versus 2-mm{sup 3} phantom resolutions. HDRMC can calculate the 3D dose distribution for a typical HDR cervix case with 2-mm resolution in 5 min on a single CPU. Examples of heterogeneity effects for two clinical cases (cervix and esophagus) were demonstrated using HDRMC. The neglect of tissue heterogeneity for the esophageal case leads to the overestimate of CTV D90, CTV D100, and spinal cord maximum dose by 3.2%, 3.9%, and 3.6%, respectively. Conclusions: A fast Monte Carlo code for CT-based dose calculations which does not require a prebuilt applicator model is developed for those HDR brachytherapy treatments that use CT-compatible applicators. Tissue and nontissue heterogeneities should be taken into account in modern HDR

  2. A Phase II Study of High-Dose-Rate Afterloading Brachytherapy as Monotherapy for the Treatment of Localized Prostate Cancer

    SciTech Connect (OSTI)

    Corner, Carie Rojas, Ana Maria; Bryant, Linda; Ostler, Peter; Hoskin, Peter

    2008-10-01

    Purpose: A Phase II dose escalation study has been undertaken to evaluate high-dose-rate brachytherapy (HDRBT) monotherapy for prostate cancer. Methods and Materials: A total of 110 patients have been entered, all with locally advanced cancer. Three dose levels have been used; 34 Gy in four fractions, 36 Gy in four fractions, and 31.5 Gy in three fractions. These equate to 226Gy{sub 1.5}, 252Gy{sub 1.5}, and 252Gy{sub 1.5}, respectively. Thirty patients have received 34 Gy, 25 received 36 Gy, and 55 patients received 31.5 Gy. Acute and late toxicity was analyzed using the International Prostate Symptom Score, and urologic and rectal events were scored using the Radiation Therapy Oncology Group/Common Terminology Criteria scoring systems. Results: Seven patients required urethral catheterization at 2 weeks; 3 receiving 34 Gy, 1 receiving 36 Gy, and 3 receiving 31.5 Gy. Only 3 patients remained catheterized at 12 weeks. Radiation Therapy Oncology Group 1 and 2 gastrointestinal toxicity at 2 weeks was seen in 61%, 68%, and 77%, respectively. Grade 3 bladder toxicity was seen in 2 patients at 6 months, 1 each from the 36 Gy and 31.5 Gy arms. One patient from the 31.5-Gy cohort reported Grade 2 bowel toxicity at 6 months. Prostate-specific antigen (PSA), stratified for androgen deprivation therapy (ADT) and no-ADT patients ranged from 16.1-22.9 {mu}g/L and 11.1-12.5 {mu}g/L, respectively. This fell at 12 months to 0.2-0.6 {mu}g/L and 0.5-1.4 {mu}g/L, respectively. No PSA relapses have yet been seen with a median follow-up of 30 months (34 Gy), 18 months (36 Gy), and 11.8 months (31.5 Gy). Conclusions: Early results suggest an excellent biochemical response with no differences seen in acute and late toxicity between doses of 34 Gy/four fractions, 36 Gy/four fractions, or 31.5 Gy/three fractions.

  3. Structure and Dynamics of Fuel Jets Injected into a High-Temperature Subsonic Crossflow: High-Data-Rate Laser Diagnostic Investigation under Steady and Oscillatory Conditions

    SciTech Connect (OSTI)

    Lucht, Robert; Anderson, William

    2015-01-23

    An investigation of subsonic transverse jet injection into a subsonic vitiated crossflow is discussed. The reacting jet in crossflow (RJIC) system investigated as a means of secondary injection of fuel in a staged combustion system. The measurements were performed in test rigs featuring (a) a steady, swirling crossflow and (b) a crossflow with low swirl but significant oscillation in the pressure field and in the axial velocity. The rigs are referred to as the steady state rig and the instability rig. Rapid mixing and chemical reaction in the near field of the jet injection is desirable in this application. Temporally resolved velocity measurements within the wake of the reactive jets using 2D-PIV and OH-PLIF at a repetition rate of 5 kHz were performed on the RJIC flow field in a steady state water-cooled test rig. The reactive jets were injected through an extended nozzle into the crossflow which is located in the downstream of a low swirl burner (LSB) that produced the swirled, vitiated crossflow. Both H2/N2 and natural gas (NG)/air jets were investigated. OH-PLIF measurements along the jet trajectory show that the auto-ignition starts on the leeward side within the wake region of the jet flame. The measurements show that jet flame is stabilized in the wake of the jet and wake vortices play a significant role in this process. PIV and OH–PLIF measurements were performed at five measurement planes along the cross- section of the jet. The time resolved measurements provided significant information on the evolution of complex flow structures and highly transient features like, local extinction, re-ignition, vortex-flame interaction prevalent in a turbulent reacting flow. Nanosecond-laser-based, single-laser-shot coherent anti-Stokes Raman scattering (CARS) measurements of temperature and H2 concentraiton were also performed. The structure and dynamics of a reacting transverse jet injected into a vitiated oscillatory crossflow presents a unique opportunity for

  4. Measurement of the radiative cooling rates for high-ionization species of krypton using an electron beam ion trap

    SciTech Connect (OSTI)

    Radtke, R.; Biedermann, C.; Fuchs, T.; Fussmann, G.; Beiersdorfer, P.

    2000-02-01

    We describe a measurement of the radiative cooling rate for krypton made at the Berlin electron beam ion trap (EBIT). The EBIT was tuned to a charge-state distribution approaching the ionization balance of a plasma at a temperature of about 5 keV. To determine the cooling rate, we made use of EBIT's capabilities to sample a wide range of electron-beam energies and distinguish between different radiation channels. We have measured the x-ray emission from bremsstrahlung, radiative recombination, dielectronic recombination, and line radiation following electron-impact excitation. The dominant contribution to the cooling rate is made by the n=3-2, n=4-2,... x rays of the L-shell spectra of krypton, which produce more than 75% of the total radiation loss. A difference with theoretical calculations is noted for the measured total cooling rate. The predicted values are lower by a factor of 1.5-2, depending on the theoretical model. For our measurement of the cooling rate, we estimate an uncertainty interval of 22-30 %. (c) 2000 The American Physical Society.

  5. Vapor pressure and evaporation rate of certain heat-resistant compounds in a vacuum at high temperatures

    SciTech Connect (OSTI)

    Bolgar, A.S.; Verkhoglyadova, T.S.; Samsonov, G.V.

    1985-02-01

    The vapor pressure and evaporation rate of borides of titanium, zirconium, and chrome and of strontium and carbides of titanium, zirconium, and chrome, molybdenum silicide and nitrides of titanium, niobium, and tantalum in a vacuum were studied. It is concluded that all subject compounds evaporate by molecular structures except AlB sub 12' which dissociates, losing the aluminum.

  6. Well-to-Wheels Greenhouse Gas Emissions Analysis of High-Octane Fuels with Various Market Shares and Ethanol Blending Levels

    SciTech Connect (OSTI)

    Han, Jeongwoo; Elgowainy, Amgad; Wang, Michael; Divita, Vincent

    2015-07-14

    In this study, we evaluated the impacts of producing HOF with a RON of 100, using a range of ethanol blending levels (E10, E25, and E40), vehicle efficiency gains, and HOF market penetration scenarios (3.4% to 70%), on WTW petroleum use and GHG emissions. In particular, we conducted LP modeling of petroleum refineries to examine the impacts of different HOF production scenarios on petroleum refining energy use and GHG emissions. We compared two cases of HOF vehicle fuel economy gains of 5% and 10% in terms of MPGGE to baseline regular gasoline vehicles. We incorporated three key factors in GREET — (1) refining energy intensities of gasoline components for the various ethanol blending options and market shares, (2) vehicle efficiency gains, and (3) upstream energy use and emissions associated with the production of different crude types and ethanol — to compare the WTW GHG emissions of various HOF/vehicle scenarios with the business-as-usual baseline regular gasoline (87 AKI E10) pathway.

  7. Sphere-Shaped Hierarchical Cathode with Enhanced Growth of Nanocrystal Planes for High-Rate and Cycling-Stable Li-Ion Batteries

    SciTech Connect (OSTI)

    Zhang, Linjing; Li, Ning; Wu, Borong; Xu, Hongliang; Wang, Lei; Yang, Xiao-Qing; Wu, Feng

    2015-01-14

    High-energy and high-power Li-ion batteries have been intensively pursued as power sources in electronic vehicles and renewable energy storage systems in smart grids. With this purpose, developing high-performance cathode materials is urgently needed. Here we report an easy and versatile strategy to fabricate high-rate and cycling-stable hierarchical sphered cathode Li1.2Ni0.13Mn0.54Co0.13O2, by using an ionic interfusion method. The sphere-shaped hierarchical cathode is assembled with primary nanoplates with enhanced growth of nanocrystal planes in favor of Li+ intercalation/deintercalation, such as (010), (100), and (110) planes. This material with such unique structural features exhibits outstanding rate capability, cyclability, and high discharge capacities, achieving around 70% (175 mAhg–1) of the capacity at 0.1 C rate within about 2.1 min of ultrafast charging. Such cathode is feasible to construct high-energy and high-power Li-ion batteries.

  8. Sphere-Shaped Hierarchical Cathode with Enhanced Growth of Nanocrystal Planes for High-Rate and Cycling-Stable Li-Ion Batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Linjing; Li, Ning; Wu, Borong; Xu, Hongliang; Wang, Lei; Yang, Xiao-Qing; Wu, Feng

    2015-01-14

    High-energy and high-power Li-ion batteries have been intensively pursued as power sources in electronic vehicles and renewable energy storage systems in smart grids. With this purpose, developing high-performance cathode materials is urgently needed. Here we report an easy and versatile strategy to fabricate high-rate and cycling-stable hierarchical sphered cathode Li1.2Ni0.13Mn0.54Co0.13O2, by using an ionic interfusion method. The sphere-shaped hierarchical cathode is assembled with primary nanoplates with enhanced growth of nanocrystal planes in favor of Li+ intercalation/deintercalation, such as (010), (100), and (110) planes. This material with such unique structural features exhibits outstanding rate capability, cyclability, and high discharge capacities, achievingmore » around 70% (175 mAhg–1) of the capacity at 0.1 C rate within about 2.1 min of ultrafast charging. Such cathode is feasible to construct high-energy and high-power Li-ion batteries.« less

  9. High rate reactive magnetron sputter deposition of Al-doped ZnO with unipolar pulsing and impedance control system

    SciTech Connect (OSTI)

    Nishi, Yasutaka; Hirohata, Kento; Tsukamoto, Naoki; Sato, Yasushi; Oka, Nobuto; Shigesato, Yuzo

    2010-07-15

    Al-doped ZnO (AZO) films were deposited on quartz glass substrates, unheated and heated to 200 deg. C, using reactive sputtering with a special feedback system of discharge impedance combined with midfrequency pulsing. A planar Zn-Al alloy target was connected to the switching unit, which was operated in a unipolar pulse mode. The oxidation of the target surface was precisely controlled by a feedback system for the entire O{sub 2} flow ratio including ''the transition region''. The deposition rate was about 10-20 times higher than that for films deposited by conventional sputtering using an oxide target. A deposition rate of AZO films of 390 nm/min with a resistivity of 3.8x10{sup -4} {Omega} cm and a transmittance in the visible region of 85% was obtained when the films were deposited on glass substrates heated to 200 deg. C with a discharge power of 4 kW.

  10. Another short-burst host galaxy with an optically obscured high star formation rate: The case of GRB 071227

    SciTech Connect (OSTI)

    Nicuesa Guelbenzu, A.; Klose, S.; Kann, D. A.; Rossi, A.; Schmidl, S. [Thringer Landessternwarte Tautenburg, Sternwarte 5, D-07778 Tautenburg (Germany); Micha?owski, M. J.; McKenzie, M. R. G. [Scottish Universities Physics Alliance, Institute for Astronomy, University of Edinburgh, Royal Observatory, Edinburgh, EH9 3HJ (United Kingdom); Savaglio, S.; Greiner, J. [Max-Planck-Institut fr Extraterrestrische Physik, Giessenbachstrae, D-85748 Garching (Germany); Hunt, L. K. [INAF-Osservatorio Astrofisico di Arcetri, Largo E. Fermi 5, I-50125 Firenze (Italy); Gorosabel, J. [Instituto de Astrofsica de Andaluca, Consejo Superior de Investigaciones Cientficas (IAA-CSIC), Glorieta de la Astronoma s/n, E-18008 Granada (Spain); Palazzi, E. [INAF-IASF Bologna, Via Gobetti 101, I-40129 Bologna (Italy)

    2014-07-01

    We report on radio continuum observations of the host galaxy of the short gamma-ray burst 071227 (z = 0.381) with the Australia Telescope Compact Array. We detect the galaxy in the 5.5 GHz band with an integrated flux density of F {sub ?} = 43 11 ?Jy, corresponding to an unobscured star-formation rate of about 24 M {sub ?} yr{sup 1}, 40 times higher than what was found from optical emission lines. Among the ?30 well-identified and studied host galaxies of short bursts this is the third case where the host is found to undergo an episode of intense star formation. This suggests that a fraction of all short-burst progenitors hosted in star-forming galaxies could be physically related to recent star formation activity, implying a relatively short merger timescale.

  11. Thermoelastic study of nanolayered structures using time-resolved X-ray diffraction at high repetition rate

    SciTech Connect (OSTI)

    Navirian, H. A.; Schick, D. Leitenberger, W.; Bargheer, M.; Gaal, P.; Shayduk, R.

    2014-01-13

    We investigate the thermoelastic response of a nanolayered sample composed of a metallic SrRuO{sub 3} electrode sandwiched between a ferroelectric Pb(Zr{sub 0.2}Ti{sub 0.8})O{sub 3} film with negative thermal expansion and a SrTiO{sub 3} substrate. SrRuO{sub 3} is rapidly heated by fs-laser pulses with 208?kHz repetition rate. Diffraction of X-ray pulses derived from a synchrotron measures the transient out-of-plane lattice constant c of all three materials simultaneously from 120?ps to 5??s with a relative accuracy up to ?c/c?=?10{sup ?6}. The in-plane propagation of sound is essential for understanding the delayed out-of-plane compression of Pb(Zr{sub 0.2}Ti{sub 0.8})O{sub 3}.

  12. High quantum efficiency and low dark count rate in multi-layer superconducting nanowire single-photon detectors

    SciTech Connect (OSTI)

    Jafari Salim, A. Eftekharian, A.; Hamed Majedi, A.

    2014-02-07

    In this paper, we theoretically show that a multi-layer superconducting nanowire single-photon detector (SNSPD) is capable of approaching characteristics of an ideal SNSPD in terms of the quantum efficiency, dark count, and band-width. A multi-layer structure improves the performance in two ways. First, the potential barrier for thermally activated vortex crossing, which is the major source of dark counts and the reduction of the critical current in SNSPDs is elevated. In a multi-layer SNSPD, a vortex is made of 2D-pancake vortices that form a stack. It will be shown that the stack of pancake vortices effectively experiences a larger potential barrier compared to a vortex in a single-layer SNSPD. This leads to an increase in the experimental critical current as well as significant decrease in the dark count rate. In consequence, an increase in the quantum efficiency for photons of the same energy or an increase in the sensitivity to photons of lower energy is achieved. Second, a multi-layer structure improves the efficiency of single-photon absorption by increasing the effective optical thickness without compromising the single-photon sensitivity.

  13. Low-level measuring techniques for neutrons: High accuracy neutron source strength determination and fluence rate measurement at an underground laboratory

    SciTech Connect (OSTI)

    Zimbal, Andreas; Reginatto, Marcel; Schuhmacher, Helmut; Wiegel, Burkhard; Degering, Detlev; Zuber, Kai

    2013-08-08

    We report on measuring techniques for neutrons that have been developed at the Physikalisch-Technische Bundesanstalt (PTB), the German National Metrology Institute. PTB has characterized radioactive sources used in the BOREXINO and XENON100 experiments. For the BOREXINO experiment, a {sup 228}Th gamma radiation source was required which would not emit more than 10 neutrons per second. The determination of the neutron emission rate of this specially designed {sup 228}Th source was challenging due to the low neutron emission rate and because the ratio of neutron to gamma radiation was expected to be extremely low, of the order of 10{sup −6}. For the XENON100 detector, PTB carried out a high accuracy measurement of the neutron emission rate of an AmBe source. PTB has also done measurements in underground laboratories. A two month measurement campaign with a set of {sup 3}He-filled proportional counters was carried out in PTB's former UDO underground laboratory at the Asse salt mine. The aim of the campaign was to determine the intrinsic background of detectors, which is needed for the analysis of data taken in lowintensity neutron fields. At a later time, PTB did a preliminary measurement of the neutron fluence rate at the underground laboratory Felsenkeller operated by VKTA. By taking into account data from UDO, Felsenkeller, and detector calibrations made at the PTB facility, it was possible to estimate the neutron fluence rate at the Felsenkeller underground laboratory.

  14. An Investigation of Enhanced Formability in AA5182-O Al During High-Rate Fre-Forming at Room-Temperature: Quantification of Deformation History

    SciTech Connect (OSTI)

    Rohatgi, Aashish; Soulami, Ayoub; Stephens, Elizabeth V.; Davies, Richard W.; Smith, Mark T.

    2014-03-01

    Following the two prior publication of PNNL Pulse-Pressure research in the Journal of Materials Processing Technology, this manuscript continues to describe PNNLs advances in getting a better understanding of sheet metal formability under high strain-rate conditions. Specifically, using a combination of numerical modeling and novel experiments, we quantitatively demonstrate the deformation history associated with enhanced formability (~2.5X) in Al under room temperature forming.

  15. Rate Schedules

    Broader source: Energy.gov [DOE]

    One of the major responsibilities of Southeastern is to design, formulate, and justify rate schedules. Repayment studies prepared by the agency determine revenue requirements and appropriate rate...

  16. Final Report - Melt Rate Enhancement for High Aluminum HLW Glass Formulation, VSL-08R1360-1, Rev. 0, dated 12/19/08

    SciTech Connect (OSTI)

    Kruger, Albert A.; Pegg, I. L.; Chaudhuri, M.; Gong, W.; Gan, H.; Matlack, K. S.; Bardakci, T.; Kot, W.

    2013-11-13

    The principal objective of the work reported here was to develop and identify HLW glass compositions that maximize waste processing rates for the aluminum limted waste composition specified by ORP while maintaining high waste loadings and acceptable glass properties. This was accomplished through a combination of crucible-scale tests, confirmation tests on the DM100 melter system, and demonstration at pilot scale (DM1200). The DM100-BL unit was selected for these tests since it was used previously with the HLW waste streams evaluated in this study, was used for tests on HLW glass compositions to support subsequent tests on the HLW Pilot Melter, conduct tests to determine the effect of various glass properties (viscosity and conductivity) and oxide concentrations on glass production rates with HLW feed streams, and to assess the volatility of cesium and technetium during the vitrification of an HLW AZ-102 composition. The same melter was selected for the present tests in order to maintain comparisons between the previously collected data. These tests provide information on melter processing characteristics and off-gas data, including formation of secondary phases and partitioning. Once DM100 tests were completed, one of the compositions was selected for further testing on the DM1200; the DM1200 system has been used for processing a variety of simulated Hanford waste streams. Tests on the larger melter provide processing data at one third of the scale of the actual WTP HLW melter and, therefore, provide a more accurate and reliable assessment of production rates and potential processing issues. The work focused on maximizing waste processing rates for high aluminum HLW compositions. In view of the diversity of forms of aluminum in the Hanford tanks, tests were also conducted on the DM100 to determine the effect of changes in the form of aluminum on feed properties and production rate. In addition, the work evaluated the effect on production rate of modest increases

  17. Sexual Functioning Among Endometrial Cancer Patients Treated With Adjuvant High-Dose-Rate Intra-Vaginal Radiation Therapy

    SciTech Connect (OSTI)

    Damast, Shari; Alektiar, Kaled M.; Goldfarb, Shari; Eaton, Anne; Patil, Sujata; Mosenkis, Jeffrey; Bennett, Antonia; Atkinson, Thomas; Jewell, Elizabeth; Leitao, Mario; Barakat, Richard; Carter, Jeanne; Basch, Ethan

    2012-10-01

    Purpose: We used the Female Sexual Function Index (FSFI) to investigate the prevalence of sexual dysfunction (SD) and factors associated with diminished sexual functioning in early stage endometrial cancer (EC) patients treated with simple hysterectomy and adjuvant brachytherapy. Methods and Materials: A cohort of 104 patients followed in a radiation oncology clinic completed questionnaires to quantify current levels of sexual functioning. The time interval between hysterectomy and questionnaire completion ranged from <6 months to >5 years. Multivariate regression was performed using the FSFI as a continuous variable (score range, 1.2-35.4). SD was defined as an FSFI score of <26, based on the published validation study. Results: SD was reported by 81% of respondents. The mean ({+-} standard deviation) domain scores in order of highest-to-lowest functioning were: satisfaction, 2.9 ({+-}2.0); orgasm, 2.5 ({+-}2.4); desire, 2.4 ({+-}1.3); arousal, 2.2 ({+-}2.0); dryness, 2.1 ({+-}2.1); and pain, 1.9 ({+-}2.3). Compared to the index population in which the FSFI cut-score was validated (healthy women ages 18-74), all scores were low. Compared to published scores of a postmenopausal population, scores were not statistically different. Multivariate analysis isolated factors associated with lower FSFI scores, including having laparotomy as opposed to minimally invasive surgery (effect size, -7.1 points; 95% CI, -11.2 to -3.1; P<.001), lack of vaginal lubricant use (effect size, -4.4 points; 95% CI, -8.7 to -0.2, P=.040), and short time interval (<6 months) from hysterectomy to questionnaire completion (effect size, -4.6 points; 95% CI, -9.3-0.2; P=.059). Conclusions: The rate of SD, as defined by an FSFI score <26, was prevalent. The postmenopausal status of EC patients alone is a known risk factor for SD. Additional factors associated with poor sexual functioning following treatment for EC included receipt of laparotomy and lack of vaginal lubricant use.

  18. High-Rate Fabrication of a-Si-Based Thin-Film Solar Cells Using Large-Area VHF PECVD Processes

    SciTech Connect (OSTI)

    Deng, Xunming; Fan, Qi Hua

    2011-12-31

    The University of Toledo (UT), working in concert with it’s a-Si-based PV industry partner Xunlight Corporation (Xunlight), has conducted a comprehensive study to develop a large-area (3ft x 3ft) VHF PECVD system for high rate uniform fabrication of silicon absorber layers, and the large-area VHF PECVD processes to achieve high performance a-Si/a-SiGe or a-Si/nc-Si tandem junction solar cells during the period of July 1, 2008 to Dec. 31, 2011, under DOE Award No. DE-FG36-08GO18073. The project had two primary goals: (i) to develop and improve a large area (3 ft × 3 ft) VHF PECVD system for high rate fabrication of > = 8 Å/s a-Si and >= 20 Å/s nc-Si or 4 Å/s a-SiGe absorber layers with high uniformity in film thicknesses and in material structures. (ii) to develop and optimize the large-area VHF PECVD processes to achieve high-performance a-Si/nc-Si or a-Si/a-SiGe tandem-junction solar cells with >= 10% stable efficiency. Our work has met the goals and is summarized in “Accomplishments versus goals and objectives”.

  19. CHEMICAL ABUNDANCE EVIDENCE OF ENDURING HIGH STAR FORMATION RATES IN AN EARLY-TYPE GALAXY: HIGH [Ca/Fe] IN NGC 5128 GLOBULAR CLUSTERS

    SciTech Connect (OSTI)

    Colucci, Janet E.; Duran, Maria Fernanda; Bernstein, Rebecca A.

    2013-08-20

    We present [Fe/H], ages, and Ca abundances for an initial sample of 10 globular clusters in NGC 5128 obtained from high-resolution, high signal-to-noise ratio echelle spectra of their integrated light. All abundances and ages are obtained using our original technique for high-resolution integrated light abundance analysis of globular clusters. The clusters have a range in [Fe/H] between -1.6 and -0.2. In this sample, the average [Ca/Fe] for clusters with [Fe/H] <-0.4 is +0.37 {+-} 0.07, while the average [Ca/Fe] in our Milky Way (MW) and M31 GC samples is +0.29 {+-} 0.09 and +0.24 {+-} 0.10, respectively. This may imply a more rapid chemical enrichment history for NGC 5128 than for either the MW or M31. This sample provides the first quantitative picture of the chemical history of NGC 5128 that is directly comparable to what is available for the MW. Data presented here were obtained with the MIKE echelle spectrograph on the Magellan Clay Telescope.

  20. Long-Term Efficacy and Toxicity of Low-Dose-Rate {sup 125}I Prostate Brachytherapy as Monotherapy in Low-, Intermediate-, and High-Risk Prostate Cancer

    SciTech Connect (OSTI)

    Kittel, Jeffrey A.; Reddy, Chandana A.; Smith, Kristin L.; Stephans, Kevin L.; Tendulkar, Rahul D.; Ulchaker, James; Angermeier, Kenneth; Campbell, Steven; Stephenson, Andrew; Klein, Eric A.; Wilkinson, D. Allan; Ciezki, Jay P.

    2015-07-15

    Purpose/Objectives: To report long-term efficacy and toxicity for a single-institution cohort of patients treated with low-dose-rate prostate brachytherapy permanent implant (PI) monotherapy. Methods and Materials: From 1996 to 2007, 1989 patients with low-risk (61.3%), intermediate-risk (29.8%), high-intermediate-risk (4.5%), and high-risk prostate cancer (4.4%) were treated with PI and followed up prospectively in a registry. All patients were treated with {sup 125}I monotherapy to 144 Gy. Late toxicity was coded retrospectively according to a modified Common Terminology Criteria for Adverse Events 4.0 scale. The rates of biochemical relapse-free survival (bRFS), distant metastasis-free survival (DMFS), overall survival (OS), and prostate cancer–specific mortality (PCSM) were calculated. We identified factors associated with late grade ≥3 genitourinary (GU) and gastrointestinal (GI) toxicity, bRFS, DMFS, OS, PCSM, and incontinence. Results: The median age of the patients was 67 years, and the median overall and prostate-specific antigen follow-up times were 6.8 years and 5.8 years, respectively. The overall 5-year rates for bRFS, DMFS, OS, and PCSM were 91.9%, 97.8%, 93.7%, and 0.71%, respectively. The 10-year rates were 81.5%, 91.5%, 76.1%, and 2.5%, respectively. The overall rates of late grade ≥3 GU and GI toxicity were 7.6% and 0.8%, respectively. On multivariable analysis, age and prostate length were significantly associated with increased risk of late grade ≥3 GU toxicity. The risk of incontinence was highly correlated with both pre-PI and post-PI transurethral resection of the prostate. Conclusions: Prostate brachytherapy as monotherapy is an effective treatment for low-risk and low-intermediate-risk prostate cancer and appears promising as a treatment for high-intermediate-risk and high-risk prostate cancer. Significant long-term toxicities are rare when brachytherapy is performed as monotherapy.

  1. Ultra-high-resolution inelastic X-ray scattering at high-repetition-rate self-seeded X-ray free-electron lasers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chubar, Oleg; Geloni, Gianluca; Kocharyan, Vitali; Madsen, Anders; Saldin, Evgeni; Serkez, Svitozar; Shvyd'ko, Yuri; Sutter, John

    2016-02-12

    Inelastic X-ray scattering (IXS) is an important tool for studies of equilibrium dynamics in condensed matter. A new spectrometer recently proposed for ultra-high-resolution IXS (UHRIX) has achieved 0.6 meV and 0.25 nm₋1spectral and momentum-transfer resolutions, respectively. However, further improvements down to 0.1 meV and 0.02 nm₋1are required to close the gap in energy–momentum space between high- and low-frequency probes. It is shown that this goal can be achieved by further optimizing the X-ray optics and by increasing the spectral flux of the incident X-ray pulses. UHRIX performs best at energies from 5 to 10 keV, where a combination of self-seedingmore » and undulator tapering at the SASE-2 beamline of the European XFEL promises up to a 100-fold increase in average spectral flux compared with nominal SASE pulses at saturation, or three orders of magnitude more than what is possible with storage-ring-based radiation sources. Wave-optics calculations show that about 7 × 1012 photons s₋1in a 90 µeV bandwidth can be achieved on the sample. Ultimately, this will provide unique new possibilities for dynamics studies by IXS.« less

  2. Preliminary Assessment of the Impact on Reactor Vessel dpa Rates Due to Installation of a Proposed Low Enriched Uranium (LEU) Core in the High Flux Isotope Reactor (HFIR)

    SciTech Connect (OSTI)

    Daily, Charles R.

    2015-10-01

    An assessment of the impact on the High Flux Isotope Reactor (HFIR) reactor vessel (RV) displacements-per-atom (dpa) rates due to operations with the proposed low enriched uranium (LEU) core described by Ilas and Primm has been performed and is presented herein. The analyses documented herein support the conclusion that conversion of HFIR to low-enriched uranium (LEU) core operations using the LEU core design of Ilas and Primm will have no negative impact on HFIR RV dpa rates. Since its inception, HFIR has been operated with highly enriched uranium (HEU) cores. As part of an effort sponsored by the National Nuclear Security Administration (NNSA), conversion to LEU cores is being considered for future HFIR operations. The HFIR LEU configurations analyzed are consistent with the LEU core models used by Ilas and Primm and the HEU balance-of-plant models used by Risner and Blakeman in the latest analyses performed to support the HFIR materials surveillance program. The Risner and Blakeman analyses, as well as the studies documented herein, are the first to apply the hybrid transport methods available in the Automated Variance reduction Generator (ADVANTG) code to HFIR RV dpa rate calculations. These calculations have been performed on the Oak Ridge National Laboratory (ORNL) Institutional Cluster (OIC) with version 1.60 of the Monte Carlo N-Particle 5 (MCNP5) computer code.

  3. Evaluating temperature and fuel stratification for heat-release rate control in a reactivity-controlled compression-ignition engine using optical diagnostics and chemical kinetics modeling

    SciTech Connect (OSTI)

    Musculus, Mark P. B.; Kokjohn, Sage L.; Reitz, Rolf D.

    2015-04-23

    We investigated the combustion process in a dual-fuel, reactivity-controlled compression-ignition (RCCI) engine using a combination of optical diagnostics and chemical kinetics modeling to explain the role of equivalence ratio, temperature, and fuel reactivity stratification for heat-release rate control. An optically accessible engine is operated in the RCCI combustion mode using gasoline primary reference fuels (PRF). A well-mixed charge of iso-octane (PRF = 100) is created by injecting fuel into the engine cylinder during the intake stroke using a gasoline-type direct injector. Later in the cycle, n-heptane (PRF = 0) is delivered through a centrally mounted diesel-type common-rail injector. This injection strategy generates stratification in equivalence ratio, fuel blend, and temperature. The first part of this study uses a high-speed camera to image the injection events and record high-temperature combustion chemiluminescence. Moreover, the chemiluminescence imaging showed that, at the operating condition studied in the present work, mixtures in the squish region ignite first, and the reaction zone proceeds inward toward the center of the combustion chamber. The second part of this study investigates the charge preparation of the RCCI strategy using planar laser-induced fluorescence (PLIF) of a fuel tracer under non-reacting conditions to quantify fuel concentration distributions prior to ignition. The fuel-tracer PLIF data show that the combustion event proceeds down gradients in the n-heptane distribution. The third part of the study uses chemical kinetics modeling over a range of mixtures spanning the distributions observed from the fuel-tracer fluorescence imaging to isolate the roles of temperature, equivalence ratio, and PRF number stratification. The simulations predict that PRF number stratification is the dominant factor controlling the ignition location and growth rate of the reaction zone. Equivalence ratio has a smaller, but still significant

  4. Significant Increase in Hydrogen Photoproduction Rates and Yields by Wild-Type Algae is Detected at High Photobioreactor Gas Phase Volume (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-07-01

    This NREL Hydrogen and Fuel Cell Technical Highlight describes how hydrogen photoproduction activity in algal cultures can be improved dramatically by increasing the gas-phase to liquid-phase volume ratio of the photobioreactor. NREL, in partnership with subcontractors from the Institute of Basic Biological Problems in Pushchino, Russia, demonstrated that the hydrogen photoproduction rate in algal cultures always decreases exponentially with increasing hydrogen partial pressure above the culture. The inhibitory effect of high hydrogen concentrations in the photobioreactor gas phase on hydrogen photoproduction by algae is significant and comparable to the effect observed with some anaerobic bacteria.

  5. Finance & Rates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    all of its costs in the rates it charges customers for wholesale electricity and transmission services. The agency is committed to careful cost management consistent with its...

  6. Direct 2-Arm Comparison Shows Benefit of High-Dose-Rate Brachytherapy Boost vs External Beam Radiation Therapy Alone for Prostate Cancer

    SciTech Connect (OSTI)

    Khor, Richard; Duchesne, Gillian; Monash University, Melbourne ; Tai, Keen-Hun; Foroudi, Farshad; Chander, Sarat; Van Dyk, Sylvia; Garth, Margaret; Williams, Scott

    2013-03-01

    Purpose: To evaluate the outcomes of patients treated for intermediate- and high-risk prostate cancer with a single schedule of either external beam radiation therapy (EBRT) and high-dose-rate brachytherapy (HDRB) boost or EBRT alone. Methods and Materials: From 2001-2006, 344 patients received EBRT with HDRB boost for definitive treatment of intermediate- or high-risk prostate cancer. The prescribed EBRT dose was 46 Gy in 23 fractions, with a HDR boost of 19.5 Gy in 3 fractions. This cohort was compared to a contemporaneously treated cohort who received EBRT to 74 Gy in 37 fractions, using a matched pair analysis. Three-dimensional conformal EBRT was used. Matching was performed using a propensity score matching technique. High-risk patients constituted 41% of the matched cohorts. Five-year clinical and biochemical outcomes were analyzed. Results: Initial significant differences in prognostic indicators between the unmatched treatment cohorts were rendered negligible after matching, providing a total of 688 patients. Median biochemical follow-up was 60.5 months. The 5-year freedom from biochemical failure was 79.8% (95% confidence interval [CI], 74.3%-85.0%) and 70.9% (95% CI, 65.4%-76.0%) for the HDRB and EBRT groups, respectively, equating to a hazard ratio of 0.59 (95% CI, 0.43-0.81, P=.0011). Interaction analyses showed no alteration in HDR efficacy when planned androgen deprivation therapy was administered (P=.95), but a strong trend toward reduced efficacy was shown compared to EBRT in high-risk cases (P=.06). Rates of grade 3 urethral stricture were 0.3% (95% CI, 0%-0.9%) and 11.8% (95% CI, 8.1%-16.5%) for EBRT and HDRB, respectively (P<.0001). No differences in clinical outcomes were observed. Conclusions: This comparison of 2 individual contemporaneously treated HDRB and EBRT approaches showed improved freedom from biochemical progression with the HDR approach. The benefit was more pronounced in intermediate- risk patients but needs to be weighed against

  7. Assessment of High Rates of Precocious Male Maturation in a Spring Chinook Salmon Supplementation Hatchery Program, Annual Report 2002-2003.

    SciTech Connect (OSTI)

    Larsen, Donald; Beckman, Brian; Cooper, Kathleen

    2003-08-01

    The Yakima River Spring Chinook Salmon Supplementation Project in Washington State is currently one of the most ambitious efforts to enhance a natural salmon population in the United States. Over the past five years we have conducted research to characterize the developmental physiology of naturally- and hatchery-reared wild progeny spring chinook salmon (Oncorhynchus tshawytscha) in the Yakima River basin. Fish were sampled at the main hatchery in Cle Elum, at remote acclimation sites and, during smolt migration, at downstream dams. Throughout these studies the maturational state of all fish was characterized using combinations of visual and histological analysis of testes, gonadosomatic index (GSI), and measurement of plasma 11-ketotestosterone (11-KT). We established that a plasma 11-KT threshold of 0.8 ng/ml could be used to designate male fish as either immature or precociously maturing approximately 8 months prior to final maturation (1-2 months prior to release as 'smolts'). Our analyses revealed that 37-49% of the hatchery-reared males from this program undergo precocious maturation at 2 years of age and a proportion of these fish appear to residualize in the upper Yakima River basin throughout the summer. An unnaturally high incidence of precocious male maturation may result in loss of potential returning anadromous adults, skewing of female: male sex ratios, ecological, and genetic impacts on wild populations and other native species. Precocious male maturation is significantly influenced by growth rate at specific times of year and future studies will be conducted to alter maturation rates through seasonal growth rate manipulations.

  8. Three-dimensional hollow-structured binary oxide particles as an advanced anode material for high-rate and long cycle life lithium-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Deli; Wang, Jie; He, Huan; Han, Lili; Lin, Ruoqian; Xin, Huolin L.; Wu, Zexing; Liu, Hongfang

    2015-12-30

    Transition metal oxides are among the most promising anode candidates for next-generation lithium-ion batteries for their high theoretical capacity. However, the large volume expansion and low lithium ion diffusivity leading to a poor charging/discharging performance. In this study, we developed a surfactant and template-free strategy for the synthesis of a composite of CoxFe3–xO4 hollow spheres supported by carbon nanotubes via an impregnation–reduction–oxidation process. The synergy of the composite, as well as the hollow structures in the electrode materials, not only facilitate Li ion and electron transport, but also accommodate large volume expansion. Using state-of-the-art electron tomography, we directly visualize themore » particles in 3-D, where the voids in the hollow structures serve to buffer the volume expansion of the material. These improvements result in a high reversible capacity as well as an outstanding rate performance for lithium-ion battery applications. As a result, this study sheds light on large-scale production of hollow structured metal oxides for commercial applications in energy storage and conversion.« less

  9. Three-dimensional hollow-structured binary oxide particles as an advanced anode material for high-rate and long cycle life lithium-ion batteries

    SciTech Connect (OSTI)

    Wang, Deli; Wang, Jie; He, Huan; Han, Lili; Lin, Ruoqian; Xin, Huolin L.; Wu, Zexing; Liu, Hongfang

    2015-12-30

    Transition metal oxides are among the most promising anode candidates for next-generation lithium-ion batteries for their high theoretical capacity. However, the large volume expansion and low lithium ion diffusivity leading to a poor charging/discharging performance. In this study, we developed a surfactant and template-free strategy for the synthesis of a composite of CoxFe3–xO4 hollow spheres supported by carbon nanotubes via an impregnation–reduction–oxidation process. The synergy of the composite, as well as the hollow structures in the electrode materials, not only facilitate Li ion and electron transport, but also accommodate large volume expansion. Using state-of-the-art electron tomography, we directly visualize the particles in 3-D, where the voids in the hollow structures serve to buffer the volume expansion of the material. These improvements result in a high reversible capacity as well as an outstanding rate performance for lithium-ion battery applications. As a result, this study sheds light on large-scale production of hollow structured metal oxides for commercial applications in energy storage and conversion.

  10. A generic high-dose rate {sup 192}Ir brachytherapy source for evaluation of model-based dose calculations beyond the TG-43 formalism

    SciTech Connect (OSTI)

    Ballester, Facundo; Carlsson Tedgren, sa; Granero, Domingo; Haworth, Annette; Mourtada, Firas; Fonseca, Gabriel Paiva; Rivard, Mark J.; Siebert, Frank-Andr; Sloboda, Ron S.; and others

    2015-06-15

    Purpose: In order to facilitate a smooth transition for brachytherapy dose calculations from the American Association of Physicists in Medicine (AAPM) Task Group No. 43 (TG-43) formalism to model-based dose calculation algorithms (MBDCAs), treatment planning systems (TPSs) using a MBDCA require a set of well-defined test case plans characterized by Monte Carlo (MC) methods. This also permits direct dose comparison to TG-43 reference data. Such test case plans should be made available for use in the software commissioning process performed by clinical end users. To this end, a hypothetical, generic high-dose rate (HDR) {sup 192}Ir source and a virtual water phantom were designed, which can be imported into a TPS. Methods: A hypothetical, generic HDR {sup 192}Ir source was designed based on commercially available sources as well as a virtual, cubic water phantom that can be imported into any TPS in DICOM format. The dose distribution of the generic {sup 192}Ir source when placed at the center of the cubic phantom, and away from the center under altered scatter conditions, was evaluated using two commercial MBDCAs [Oncentra{sup } Brachy with advanced collapsed-cone engine (ACE) and BrachyVision ACUROS{sup TM}]. Dose comparisons were performed using state-of-the-art MC codes for radiation transport, including ALGEBRA, BrachyDose, GEANT4, MCNP5, MCNP6, and PENELOPE2008. The methodologies adhered to recommendations in the AAPM TG-229 report on high-energy brachytherapy source dosimetry. TG-43 dosimetry parameters, an along-away dose-rate table, and primary and scatter separated (PSS) data were obtained. The virtual water phantom of (201){sup 3} voxels (1 mm sides) was used to evaluate the calculated dose distributions. Two test case plans involving a single position of the generic HDR {sup 192}Ir source in this phantom were prepared: (i) source centered in the phantom and (ii) source displaced 7 cm laterally from the center. Datasets were independently produced by

  11. Dual Phase Li4 Ti5O12TiO2 Nanowire Arrays As Integrated Anodes For High-rate Lithium-ion Batteries

    SciTech Connect (OSTI)

    Liao, Jin; Chabot, Victor; Gu, Meng; Wang, Chong M.; Xiao, Xingcheng; Chen, Zhongwei

    2014-08-19

    Lithium titanate (Li4Ti5O12) is well known as a zero strain material inherently, which provides excellent long cycle stability as a negative electrode for lithium ion batteries. However, the low specific capacity (175 mA h g?1) limits it to power batteries although the low electrical conductivity is another intrinsic issue need to be solved. In this work, we developed a facile hydrothermal and ion-exchange route to synthesize the self-supported dual-phase Li4Ti5O12TiO2 nanowire arrays to further improve its capacity as well as rate capability. The ratio of Li4Ti5O12 to TiO2 in the dual phase Li4Ti5O12TiO2 nanowire is around 2:1. The introduction of TiO2 into Li4Ti5O12 increases the specific capacity. More importantly, by interface design, it creates a dual-phase nanostructure with high grain boundary density that facilitates both electron and Li ion transport. Compared with phase-pure nanowire Li4Ti5O12 and TiO2 nanaowire arrays, the dual-phase nanowire electrode yielded superior rate capability (135.5 at 5 C, 129.4 at 10 C, 120.2 at 20 C and 115.5 mA h g?1 at 30 C). In-situ transmission electron microscope clearly shows the near zero deformation of the dual phase structure, which explains its excellent cycle stability.

  12. SU-C-16A-02: A Beryllium Oxide (BeO) Fibre-Coupled Luminescence Dosimeter for High Dose Rate Brachytherapy

    SciTech Connect (OSTI)

    Santos, A; Mohammadi, M; Afshar, V.S.

    2014-06-15

    Purpose: Beryllium oxide (BeO) ceramics have an effective atomic number, zeff ∼7.1, closely matched to water, zeff ∼7.4. The purpose of this study was to evaluate the use of a beryllium oxide (BeO) ceramic fibrecoupled luminescence dosimeter, named RL/OSL BeO FOD, for high dose rate (HDR) brachytherapy dosimetry. In our dosimetry system the radioluminescence (RL) of BeO ceramics is utilized for dose-rate measurements, and the optically stimulated luminescence (OSL) can be read post exposure for accumulated dose measurements. Methods: The RL/OSL BeO FOD consists of a 1 mm diameter × 1 mm long cylinder of BeO ceramic coupled to a 15 m long silica-silica optical fibre. The optical fibre is connected to a custom developed portable RL and OSL reader, located outside of the treatment suite. The x-ray energy response was evaluated using superficial x-rays, an Ir-192 source and high energy linear accelerators. The RL/OSL BeO FOD was then characterised for an Ir-192 source, investigating the dose response and angular dependency. A depth dose curve for the Ir-192 source was also measured. Results: The RL/OSL BeO FOD shows an under-response at low energy x-rays as expected. Though at higher x-ray energies, the OSL response continued to increase, while the RL response remained relatively constant. The dose response for the RL is found to be linear up to doses of 15 Gy, while the OSL response becomes more supralinear to doses above 15 Gy. Little angular dependency is observed and the depth dose curve measured agreed within 4% of that calculated based on TG-43. Conclusion: This works shows that the RL/OSL BeO FOD can be useful in HDR dosimetry. With the RL/OSL BeO FODs current size, it is capable of being inserted into intraluminal catheters and interstitial needles to verify HDR treatments.

  13. Dynamic response of Cu4Zr54 metallic glass to high strain rate shock loading: plasticity, spall and atomic-level structures

    SciTech Connect (OSTI)

    Luo, Shengnian; Arman, Bedri; Germann, Timothy C; Cagin, Tahir

    2009-01-01

    We investigate dynamic response of Cu{sub 46}Zr{sub 54} metallic glass under adiabatic planar shock wave loading (one-dimensional strain) wjth molecular dynamics simulations, including Hugoniot (shock) states, shock-induced plasticity and spallation. The Hugoniot states are obtained up to 60 CPa along with the von Mises shear flow strengths, and the dynamic spall strength, at different strain rates and temperatures. The spall strengths likely represent the limiting values achievable in experiments such as laser ablation. For the steady shock states, a clear elastic-plastic transition is identified (e.g., in the shock velocity-particle velocity curve), and the shear strength shows strain-softening. However, the elastic-plastic transition across the shock front displays transient stress overshoot (hardening) above the Hugoniot elastic limit followed by a relatively sluggish relaxation to the steady shock state, and the plastic shock front steepens with increasing shock strength. The local von Mises shear strain analysis is used to characterize local deformation, and the Voronoi tessellation analysis, the corresponding short-range structures at various stages of shock, release, tension and spallation. The plasticity in this glass is manifested as localized shear transformation zones and of local structure rather than thermal origin, and void nucleation occurs preferentially at the highly shear-deformed regions. The Voronoi and shear strain analyses show that the atoms with different local structures are of different shear resistances that lead to shear localization (e.g., the atoms indexed with (0,0,12,0) are most shear-resistant, and those with (0,2,8,1) are highly prone to shear flow). The dynamic changes in local structures are consistent with the observed deformation dynamics.

  14. Direct injection of natural gas in blast furnaces at high rates: Preliminary statistical analysis of blast furnace carbon balance at Armco-Middletown. Topical report, January 1990-September 1992

    SciTech Connect (OSTI)

    Neels, J.K.; Brown, F.C.

    1992-09-01

    The economic benefits of supplemental fuel injections depend, in part, on the coke replacement ratio. An assessment of the accuracy with which blast furnace coke rate may be measured and a determination of the key drivers of coke rate uncertainty are offered, to provide guidance for experiments in high-rate gas injection. Using statistical analysis tools, an expression for the measurement error associated with the various terms of blast furnace carbon balance is developed. Coke rate calculations based on the material balance are most sensitive to coke carbon content and to proper tracking of hot metal tapping schedule.

  15. Corrosion fatigue crack growth in clad low-alloy steel. Part 2, Water flow rate effects in high sulfur plate steel

    SciTech Connect (OSTI)

    James, L.A; Lee, H.B.; Wire, G.L.; Novak, S.R.; Cullen, W.H.

    1996-04-01

    Corrosion fatigue crack propagation tests were conducted on a high- sulfur ASTM A302-B plate steel overlaid with weld-deposited Alloy EN82H cladding. The specimens featured semi-elliptical surface cracks penetrating approximately 6.3 mm of cladding into the underlying steel. The initial crack sizes were relatively large with surface lengths of 22.8--27.3 mm, and depths of 10.5--14.1 mm. The experiments were initiated in a quasi-stagnant low-oxygen (O{sub 2} < 10 ppb) aqueous environment at 243{degrees}C, under loading conditions ({Delta}K, R, cyclic frequency) conducive to environmentally-assisted cracking (EAC) under quasi-stagnant conditions. Following fatigue testing under quasi-stagnant conditions where EAC was observed, the specimens were then fatigue tested under conditions where active water flow of either 1.7 m/sec. or 4.7 m/sec. was applied parallel to the crack. Earlier experiments on unclad surface-cracked specimens of the same steel exhibited EAC under quasi- stagnant conditions, but water flow rates at 1.7 m/sec. and 5.0 m/sec. parallel to the crack mitigated EAC. In the present experiments on clad specimens, water flow at approximately the same as the lower of these velocities did not mitigate EAC, and a free stream velocity approximately the same as the higher of these velocities resulted in sluggish mitigation of EAC. The lack of robust EAC mitigation was attributed to the greater crack surface roughness in the cladding interfering with flow induced within the crack cavity. An analysis employing the computational fluid dynamics code, FIDAP, confirmed that frictional forces associated with the cladding crack surface roughness reduced the interaction between the free stream and the crack cavity.

  16. Posttraumatic Stress Disorder After High-Dose-Rate Brachytherapy for Cervical Cancer With 2 Fractions in 1 Application Under Spinal/Epidural Anesthesia: Incidence and Risk Factors

    SciTech Connect (OSTI)

    Kirchheiner, Kathrin; Czajka-Pepl, Agnieszka; Scharbert, Gisela; Wetzel, Léonore; Sturdza, Alina; Dörr, Wolfgang; Pötter, Richard

    2014-06-01

    Purpose: To investigate the psychological consequences of high-dose-rate brachytherapy with 2 fractions in 1 application under spinal/epidural anesthesia in the treatment of locally advanced cervical cancer. Methods and Materials: In 50 patients with locally advanced cervical cancer, validated questionnaires were used for prospective assessment of acute and posttraumatic stress disorder (ASD/PTSD) (Impact of Event Scale–Revision), anxiety/depression (Hospital Anxiety and Depression Scale), quality of life (European Organization for Research and Treatment of Cancer Quality of Life Questionnaire Core 30/Cervical Cancer 24), physical functioning (World Health Organization performance status), and pain (visual analogue scale), before and during treatment and 1 week and 3 months after treatment. Qualitative interviews were recorded in open format for content analysis. Results: Symptoms of ASD occurred in 30% of patients 1 week after treatment; and of PTSD in 41% 3 months after treatment in association with this specific brachytherapy procedure. Pretreatment predictive variables explain 82% of the variance of PTSD symptoms. Helpful experiences were the support of the treatment team, psychological support, and a positive attitude. Stressful factors were pain, organizational problems during treatment, and immobility between brachytherapy fractions. Conclusions: The specific brachytherapy procedure, as performed in the investigated mono-institutional setting with 2 fractions in 1 application under spinal/epidural anesthesia, bears a considerable risk of traumatization. The source of stress seems to be not the brachytherapy application itself but the maintenance of the applicator under epidural anesthesia in the time between fractions. Patients at risk may be identified before treatment, to offer targeted psycho-social support. The patients' open reports regarding helpful experiences are an encouraging feedback for the treatment team; the reported stressful factors

  17. A Prospective Longitudinal Clinical Trial Evaluating Quality of Life After Breast-Conserving Surgery and High-Dose-Rate Interstitial Brachytherapy for Early-Stage Breast Cancer

    SciTech Connect (OSTI)

    Garsa, Adam A.; Ferraro, Daniel J.; DeWees, Todd A.; Deshields, Teresa L.; Margenthaler, Julie A.; Cyr, Amy E.; Naughton, Michael; Aft, Rebecca; Gillanders, William E.; Eberlein, Timothy; Matesa, Melissa A.; Ochoa, Laura L.; Zoberi, Imran

    2013-12-01

    Purpose: To prospectively examine quality of life (QOL) of patients with early stage breast cancer treated with accelerated partial breast irradiation (APBI) using high-dose-rate (HDR) interstitial brachytherapy. Methods and Materials: Between March 2004 and December 2008, 151 patients with early stage breast cancer were enrolled in a phase 2 prospective clinical trial. Eligible patients included those with Tis-T2 tumors measuring ?3 cm excised with negative surgical margins and with no nodal involvement. Patients received 3.4 Gy twice daily to a total dose of 34 Gy. QOL was measured using European Organization for Research and Treatment of Cancer (EORTC) QLQ-C30, version 3.0, and QLQ-BR23 questionnaires. The QLQ-C30 and QLQ-BR23 questionnaires were evaluated during pretreatment and then at 6 to 8 weeks, 3 to 4 months, 6 to 8 months, and 1 and 2 years after treatment. Results: The median follow-up was 55 months. Breast symptom scores remained stable in the months after treatment, and they significantly improved 6 to 8 months after treatment. Scores for emotional functioning, social functioning, and future perspective showed significant improvement 2 years after treatment. Symptomatic fat necrosis was associated with several changes in QOL, including increased pain, breast symptoms, systemic treatment side effects, dyspnea, and fatigue, as well as decreased role functioning, emotional functioning, and social functioning. Conclusions: HDR multicatheter interstitial brachytherapy was well tolerated, with no significant detrimental effect on measured QOL scales/items through 2 years of follow-up. Compared to pretreatment scores, there was improvement in breast symptoms, emotional functioning, social functioning, and future perspective 2 years after treatment.

  18. Rates Meetings and Workshops (pbl/rates)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rate Case Workshops Other Power Rates-Related Workshops July 1, 2004 - Rates and Finances Workshop (updated June 25, 2004) (financial and rate forecasts and scenarios for FY...

  19. Real-time catheter tracking for high-dose-rate prostate brachytherapy using an electromagnetic 3D-guidance device: A preliminary performance study

    SciTech Connect (OSTI)

    Zhou Jun; Sebastian, Evelyn; Mangona, Victor; Yan Di

    2013-02-15

    Purpose: In order to increase the accuracy and speed of catheter reconstruction in a high-dose-rate (HDR) prostate implant procedure, an automatic tracking system has been developed using an electromagnetic (EM) device (trakSTAR, Ascension Technology, VT). The performance of the system, including the accuracy and noise level with various tracking parameters and conditions, were investigated. Methods: A direct current (dc) EM transmitter (midrange model) and a sensor with diameter of 1.3 mm (Model 130) were used in the trakSTAR system for tracking catheter position during HDR prostate brachytherapy. Localization accuracy was assessed under both static and dynamic analyses conditions. For the static analysis, a calibration phantom was used to investigate error dependency on operating room (OR) table height (bottom vs midposition vs top), sensor position (distal tip of catheter vs connector end of catheter), direction [left-right (LR) vs anterior-posterior (AP) vs superior-inferior (SI)], sampling frequency (40 vs 80 vs 120 Hz), and interference from OR equipment (present vs absent). The mean and standard deviation of the localization offset in each direction and the corresponding error vectors were calculated. For dynamic analysis, the paths of five straight catheters were tracked to study the effects of directions, sampling frequency, and interference of EM field. Statistical analysis was conducted to compare the results in different configurations. Results: When interference was present in the static analysis, the error vectors were significantly higher at the top table position (3.3 {+-} 1.3 vs 1.8 {+-} 0.9 mm at bottom and 1.7 {+-} 1.0 mm at middle, p < 0.001), at catheter end position (3.1 {+-} 1.1 vs 1.4 {+-} 0.7 mm at the tip position, p < 0.001), and at 40 Hz sampling frequency (2.6 {+-} 1.1 vs 2.4 {+-} 1.5 mm at 80 Hz and 1.8 {+-} 1.1 at 160 Hz, p < 0.001). So did the mean offset errors in the LR direction (-1.7 {+-} 1.4 vs 0.4 {+-} 0.5 mm in AP and 0

  20. Analysis of High Precision GPS Time Series and Strain Rates for the Geothermal Play Fairway Analysis of Washington State Prospects Project

    SciTech Connect (OSTI)

    Michael Swyer

    2015-02-22

    Global Positioning System (GPS) time series from the National Science Foundation (NSF) Earthscope’s Plate Boundary Observatory (PBO) and Central Washington University’s Pacific Northwest Geodetic Array (PANGA). GPS station velocities were used to infer strain rates using the ‘splines in tension’ method. Strain rates were derived separately for subduction zone locking at depth and block rotation near the surface within crustal block boundaries.

  1. Analysis of High Precision GPS Time Series and Strain Rates for the Geothermal Play Fairway Analysis of Washington State Prospects Project

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Michael Swyer

    2015-02-22

    Global Positioning System (GPS) time series from the National Science Foundation (NSF) Earthscopes Plate Boundary Observatory (PBO) and Central Washington Universitys Pacific Northwest Geodetic Array (PANGA). GPS station velocities were used to infer strain rates using the splines in tension method. Strain rates were derived separately for subduction zone locking at depth and block rotation near the surface within crustal block boundaries.

  2. Comparison of 2D and 3D Imaging and Treatment Planning for Postoperative Vaginal Apex High-Dose Rate Brachytherapy for Endometrial Cancer

    SciTech Connect (OSTI)

    Russo, James K.; Armeson, Kent E.; Richardson, Susan

    2012-05-01

    Purpose: To evaluate bladder and rectal doses using two-dimensional (2D) and 3D treatment planning for vaginal cuff high-dose rate (HDR) in endometrial cancer. Methods and Materials: Ninety-one consecutive patients treated between 2000 and 2007 were evaluated. Seventy-one and 20 patients underwent 2D and 3D planning, respectively. Each patient received six fractions prescribed at 0.5 cm to the superior 3 cm of the vagina. International Commission on Radiation Units and Measurements (ICRU) doses were calculated for 2D patients. Maximum and 2-cc doses were calculated for 3D patients. Organ doses were normalized to prescription dose. Results: Bladder maximum doses were 178% of ICRU doses (p < 0.0001). Two-cubic centimeter doses were no different than ICRU doses (p = 0.22). Two-cubic centimeter doses were 59% of maximum doses (p < 0.0001). Rectal maximum doses were 137% of ICRU doses (p < 0.0001). Two-cubic centimeter doses were 87% of ICRU doses (p < 0.0001). Two-cubic centimeter doses were 64% of maximum doses (p < 0.0001). Using the first 1, 2, 3, 4 or 5 fractions, we predicted the final bladder dose to within 10% for 44%, 59%, 83%, 82%, and 89% of patients by using the ICRU dose, and for 45%, 55%, 80%, 85%, and 85% of patients by using the maximum dose, and for 37%, 68%, 79%, 79%, and 84% of patients by using the 2-cc dose. Using the first 1, 2, 3, 4 or 5 fractions, we predicted the final rectal dose to within 10% for 100%, 100%, 100%, 100%, and 100% of patients by using the ICRU dose, and for 60%, 65%, 70%, 75%, and 75% of patients by using the maximum dose, and for 68%, 95%, 84%, 84%, and 84% of patients by using the 2-cc dose. Conclusions: Doses to organs at risk vary depending on the calculation method. In some cases, final dose accuracy appears to plateau after the third fraction, indicating that simulation and planning may not be necessary in all fractions. A clinically relevant level of accuracy should be determined and further research conducted to address

  3. Power Rates Announcements (pbl/rates)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    WP-10 Rate Case WP-07 Rate Case WP-07 Supplemental Rate Case ASC Methodology Adjustments (2007-2009) Adjustments (2002-2006) Previous Rate Cases Financial Choices (2003-06) Power...

  4. Current BPA Power Rates (pbl/rates)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Workshops WP-10 Rate Case WP-07 Rate Case WP-07 Supplemental Rate Case ASC Methodology Adjustments (2007-2009) Adjustments (2002-2006) Previous Rate Cases Financial...

  5. Injection of natural gas in the blast furnace at high rates: Field experiments at Armco Steel Company. Topical technical report, January 1990-September 1992

    SciTech Connect (OSTI)

    Agarwall, J.C.; Brown, F.C.; Chin, D.L.; Frydenlund, A.R.

    1993-04-01

    A study of the benefits of the injection of natural gas as a supplemental fuel for commercial blast furnaces is presented. Tests were carried out for sustained periods at natural gas injection levels of 150 and 200 pounds per therm (lb/thm). Average coke replacement ratios of 1.30 pounds of coke per pound of natural gas injected and productivity increases of about 10% were achieved at a gas injection rate of 200 lb/thm. The results were obtained without adverse effects on hot metal chemistry or furnace operability. The ability of natural gas to effectively replace an appreciable amount of coke should enable a decrease in coke production levels.

  6. National Utility Rate Database: Preprint

    SciTech Connect (OSTI)

    Ong, S.; McKeel, R.

    2012-08-01

    When modeling solar energy technologies and other distributed energy systems, using high-quality expansive electricity rates is essential. The National Renewable Energy Laboratory (NREL) developed a utility rate platform for entering, storing, updating, and accessing a large collection of utility rates from around the United States. This utility rate platform lives on the Open Energy Information (OpenEI) website, OpenEI.org, allowing the data to be programmatically accessed from a web browser, using an application programming interface (API). The semantic-based utility rate platform currently has record of 1,885 utility rates and covers over 85% of the electricity consumption in the United States.

  7. Use of the slow-strain-rate technique for the evaluation of structural materials for application in high-temperature gaseous environments

    SciTech Connect (OSTI)

    Johnson, C.E.; Ugiansky, G.M.

    1981-01-01

    Types 309, 310, 310S, 347 and 446 stainless steels, Incoloy 800, and Inconel 671 were tested at temperatures from 370 to 1040/sup 0/C at strain rates from 10/sup -4/ to 10/sup -7//s in H/sub 2/S plus water, gaseous mixtures of CO, CO/sub 2/, H/sub 2/, CH/sub 4/, H/sub 2/S, and H/sub 2/O, and in nominally inert environments of He and Ar. Type 310 steel showed a marked reduction in mechanical properties at low strain rates (< 10/sup -5//s) in H/sub 2/S/H/sub 2/O at 540/sup 0/C, and this was associated with the occurrence of a large degree of secondary intergranular cracking in addition to the main ductile fracture mode. The occurrence of the secondary cracking was taken as the primary indication of embrittlement in subsequent tests. It occurred to some degree in all alloys tested in the simulated coal-gasification environments at 600/sup 0/C. The mechanism(s) of the embrittlement phenomena remain uncertain; a number of possible causes including creep and several environmentally-induced fracture processes are outlined. It is shown that the overall results of the test program are in good agreement with in-plant experience.

  8. Evaluating temperature and fuel stratification for heat-release rate control in a reactivity-controlled compression-ignition engine using optical diagnostics and chemical kinetics modeling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Musculus, Mark P. B.; Kokjohn, Sage L.; Reitz, Rolf D.

    2015-04-23

    We investigated the combustion process in a dual-fuel, reactivity-controlled compression-ignition (RCCI) engine using a combination of optical diagnostics and chemical kinetics modeling to explain the role of equivalence ratio, temperature, and fuel reactivity stratification for heat-release rate control. An optically accessible engine is operated in the RCCI combustion mode using gasoline primary reference fuels (PRF). A well-mixed charge of iso-octane (PRF = 100) is created by injecting fuel into the engine cylinder during the intake stroke using a gasoline-type direct injector. Later in the cycle, n-heptane (PRF = 0) is delivered through a centrally mounted diesel-type common-rail injector. This injectionmore » strategy generates stratification in equivalence ratio, fuel blend, and temperature. The first part of this study uses a high-speed camera to image the injection events and record high-temperature combustion chemiluminescence. Moreover, the chemiluminescence imaging showed that, at the operating condition studied in the present work, mixtures in the squish region ignite first, and the reaction zone proceeds inward toward the center of the combustion chamber. The second part of this study investigates the charge preparation of the RCCI strategy using planar laser-induced fluorescence (PLIF) of a fuel tracer under non-reacting conditions to quantify fuel concentration distributions prior to ignition. The fuel-tracer PLIF data show that the combustion event proceeds down gradients in the n-heptane distribution. The third part of the study uses chemical kinetics modeling over a range of mixtures spanning the distributions observed from the fuel-tracer fluorescence imaging to isolate the roles of temperature, equivalence ratio, and PRF number stratification. The simulations predict that PRF number stratification is the dominant factor controlling the ignition location and growth rate of the reaction zone. Equivalence ratio has a smaller, but still

  9. Current Power Rates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases Rate Information Current Power Rates Current Transmission Rates...

  10. Current Transmission Rates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    links Financial Information Financial Public Processes Asset Management Cost Verification Process Rate Cases Rate Information Current Power Rates Current Transmission Rates...