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Sample records for high fossil fuel

  1. Fossil Fuels Study Guide - High School | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuels Study Guide - High School Fossil Fuels Study Guide - High School Fossil Fuels Study Guide - High School (63.66 KB) More Documents & Publications Coal Study Guide for ...

  2. Fossil fuels -- future fuels

    SciTech Connect (OSTI)

    1998-03-01

    Fossil fuels -- coal, oil, and natural gas -- built America`s historic economic strength. Today, coal supplies more than 55% of the electricity, oil more than 97% of the transportation needs, and natural gas 24% of the primary energy used in the US. Even taking into account increased use of renewable fuels and vastly improved powerplant efficiencies, 90% of national energy needs will still be met by fossil fuels in 2020. If advanced technologies that boost efficiency and environmental performance can be successfully developed and deployed, the US can continue to depend upon its rich resources of fossil fuels.

  3. High Efficiency Direct Carbon and Hydrogen Fuel Cells for Fossil Fuel Power Generation

    SciTech Connect (OSTI)

    Steinberg, M; Cooper, J F; Cherepy, N

    2002-01-02

    Hydrogen he1 cells have been under development for a number of years and are now nearing commercial applications. Direct carbon fuel cells, heretofore, have not reached practical stages of development because of problems in fuel reactivity and cell configuration. The carbon/air fuel cell reaction (C + O{sub 2} = CO{sub 2}) has the advantage of having a nearly zero entropy change. This allows a theoretical efficiency of 100 % at 700-800 C. The activities of the C fuel and CO{sub 2} product do not change during consumption of the fuel. Consequently, the EMF is invariant; this raises the possibility of 100% fuel utilization in a single pass. (In contrast, the high-temperature hydrogen fuel cell has a theoretical efficiency of and changes in fuel activity limit practical utilizations to 75-85%.) A direct carbon fuel cell is currently being developed that utilizes reactive carbon particulates wetted by a molten carbonate electrolyte. Pure COZ is evolved at the anode and oxygen from air is consumed at the cathode. Electrochemical data is reported here for the carbon/air cell utilizing carbons derived from he1 oil pyrolysis, purified coal, purified bio-char and petroleum coke. At 800 O C, a voltage efficiency of 80% was measured at power densities of 0.5-1 kW/m2. Carbon and hydrogen fuels may be produced simultaneously at lugh efficiency from: (1) natural gas, by thermal decomposition, (2) petroleum, by coking or pyrolysis of distillates, (3) coal, by sequential hydrogasification to methane and thermal pyrolysis of the methane, with recycle of the hydrogen, and (4) biomass, similarly by sequential hydrogenation and thermal pyrolysis. Fuel production data may be combined with direct C and H2 fuel cell operating data for power cycle estimates. Thermal to electric efficiencies indicate 80% HHV [85% LHV] for petroleum, 75.5% HHV [83.4% LHV] for natural gas and 68.3% HHV [70.8% LHV] for lignite coal. Possible benefits of integrated carbon and hydrogen fuel cell power

  4. Standard for the qualification of high capacity fossil fuel fired plant operators

    SciTech Connect (OSTI)

    Axtman, W.

    1996-12-31

    The American Society of Mechanical Engineers, at the request of the U.S. Environmental Protection Agency (EPA) and, in recognition of the needs and benefits associated with standard qualifications of operators of high capacity fossil fuel fired plants, established the Qualifications of High Capacity Fossil Fuel Fired Operator (QFO) Committee in 1994. The purpose of the QFO Committee is to develop and maintain such a standard for operators. This standard includes qualifications, duties, responsibilities and the certification requirements for operators as appropriate to The Clean Air Act as amended in 1990 for fossil fuel fired plants with inputs equal to or greater than 10,000 Btu/hr. This Standard does not cover the certification or validation of fossil plant operating procedures, operating practices, facility performance, nor compliance with any particular permit requirement. This standard recognizes the titles or positions to which any particular fossil plant operator may apply, will vary within a facility. Therefore, this standard does not attempt to identify the individual who is required to obtain certification in any class designation. The fossil plant owner is urged to contact the local jurisdiction in which the fossil plant is located in this regard. This standard does not in itself require certification but rather it serves as a means for complying with federal, state, and local regulations which require operators of fossil fuel fired boilers with inputs equal to or greater than 10,000,000 But/hr to be certified. Safety codes and standards are intended to enhance public health and safety. Revisions to this Standard result from committee considerations of factors such as technological advances, new data, and changing environmental and industry needs. Revisions do not imply that previous editions of this standard were inadequate.

  5. DOE - Fossil Energy: How Fossil Fuels Were Formed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fossil Fuel Formation Fossil Energy Study Guides How Fossil Fuels were Formed Contrary to what many people believe, fossil fuels are not the remains of dead dinosaurs. In fact,...

  6. Advanced fossil fuel combustor

    SciTech Connect (OSTI)

    Rogers, B.

    1995-05-01

    Charged with enhancing the use of US fossil energy resources, the Morgantown Energy Technology Center (METC) is a federal Department of Energy research center that performs its own research and also manages the work of contractors. One interesting recent METC project is the effort to develop a ``multiannular swirl burner`` (MSB) for use in an advanced fossil fuel combustion system. The design is being developed by an outside contractor with funding and technical assistance from METC. Recently, EG and G Technical Services of West Virginia was asked to provide analytical support to the contractor developing the MSB. Design projects like this usually require building and testing a series of very expensive prototypes. Recent success with computational fluid dynamic (CFD) design techniques, however, have generated a great deal of excitement because of its ability to reduce research and development costs. Using FLUENT, a CFD package from Fluent Inc., EG and G was able to predict, with a high degree of accuracy, the performance of one of the MSB combustor prototypes. Furthermore, the model provided researchers with a more detailed understanding of the proposed design`s performance characteristics.

  7. No Fossil Fuel - Kingston | Open Energy Information

    Open Energy Info (EERE)

    Fossil Fuel - Kingston Jump to: navigation, search Name No Fossil Fuel - Kingston Facility No Fossil Fuel - Kingston Sector Wind energy Facility Type Commercial Scale Wind Facility...

  8. Novel Gas Sensors for High-Temperature Fossil Fuel Applications

    SciTech Connect (OSTI)

    Palitha Jayaweera; Francis Tanzella

    2005-03-01

    SRI International (SRI) is developing ceramic-based microsensors to detect exhaust gases such as NO, NO{sub 2}, and CO in advanced combustion and gasification systems under this DOE NETL-sponsored research project. The sensors detect the electrochemical activity of the exhaust gas species on catalytic electrodes attached to a solid state electrolyte and are designed to operate at the high temperatures, elevated pressures, and corrosive environments typical of large power generation exhausts. The sensors can be easily integrated into online monitoring systems for active emission control. The ultimate objective is to develop sensors for multiple gas detection in a single package, along with data acquisition and control software and hardware, so that the information can be used for closed-loop control in novel advanced power generation systems. This report details the Phase I Proof-of-Concept, research activities performed from October 2003 to March 2005. SRI's research work includes synthesis of catalytic materials, sensor design and fabrication, software development, and demonstration of pulse voltammetric analysis of NO, NO{sub 2}, and CO gases on catalytic electrodes.

  9. Fossil fuel furnace reactor

    DOE Patents [OSTI]

    Parkinson, William J.

    1987-01-01

    A fossil fuel furnace reactor is provided for simulating a continuous processing plant with a batch reactor. An internal reaction vessel contains a batch of shale oil, with the vessel having a relatively thin wall thickness for a heat transfer rate effective to simulate a process temperature history in the selected continuous processing plant. A heater jacket is disposed about the reactor vessel and defines a number of independent controllable temperature zones axially spaced along the reaction vessel. Each temperature zone can be energized to simulate a time-temperature history of process material through the continuous plant. A pressure vessel contains both the heater jacket and the reaction vessel at an operating pressure functionally selected to simulate the continuous processing plant. The process yield from the oil shale may be used as feedback information to software simulating operation of the continuous plant to provide operating parameters, i.e., temperature profiles, ambient atmosphere, operating pressure, material feed rates, etc., for simulation in the batch reactor.

  10. Greening up fossil fuels with carbon sequestration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Greening up fossil fuels with carbon sequestration 1663 Los Alamos science and technology magazine Latest Issue:October 2015 past issues All Issues submit Greening up fossil...

  11. High capacity fossil fuel fired plant operator training program. Student handbook. Final report

    SciTech Connect (OSTI)

    Pearson, S.; Gardner, M.; Nguyen, Q.

    1994-09-30

    The operator of fossil fuel-fired boilers has a significant responsibility in assuring that the unit is continuously operated in a manner which complies with the various state and federal regulations. The course will emphasize the operating principles for all types of boilers and for all types of control equipment used for controlling air emissions from boilers. The course will emphasize the significant operating parameters that directly influence air emissions.

  12. An optical gas temperature probe for high temperature fossil fuel process streams

    SciTech Connect (OSTI)

    Bauman, L.E.; Cook, R.L.; Lineberry, J.T.; Litchford, R.J.

    1995-12-31

    Reported here are the results of a feasibility study of a modular optical gas temperature probe for direct measurement of gas temperature in fossil-fueled combustion streams. A probe based upon the spectroscopic technique of line reversal would be superior to currently available gas temperature technology. The study concluded that a modular form of the line reversal optical temperature probe is feasible and, as such. the probe should be a commercially viable product with potential economic benefits from improved monitoring and control of utility furnaces. Such a probe will have the capability of making direct measurements of gas temperature in hot (>1500 K) process streams of coal combustion systems and large-scale power plant facilities.

  13. 2016 Bioenergizeme Infographic Challenge: Biofuels vs Fossil Fuels |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Biofuels vs Fossil Fuels 2016 Bioenergizeme Infographic Challenge: Biofuels vs Fossil Fuels 2016 Bioenergizeme Infographic Challenge: Biofuels vs Fossil Fuels This infographic was created by students from General Douglas MacArthur High School in Levittown, NY, as part of the U.S. Department of Energy-BioenergizeME Infographic Challenge. The BioenergizeME Infographic Challenge encourages young people to improve their foundational understanding of bioenergy, which is a

  14. Greening up fossil fuels with carbon sequestration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Greening up fossil fuels with carbon sequestration 1663 Los Alamos science and technology magazine Latest Issue:July 2016 past issues All Issues » submit Greening up fossil fuels with carbon sequestration Researchers make progress fighting climate change by capturing carbon dioxide from power plants and storing it deep underground in geological reservoirs March 25, 2013 Greening up fossil fuels with carbon sequestration Most of the world's existing energy supply is stored underground in

  15. Synthetic fossil fuel technologies: health problems and intersociety...

    Office of Scientific and Technical Information (OSTI)

    Conference: Synthetic fossil fuel technologies: health problems and intersociety cooperation Citation Details In-Document Search Title: Synthetic fossil fuel technologies: health ...

  16. Fossil Fuel-Generated Energy Consumption Reduction for New Federal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fossil Fuel-Generated Energy Consumption Reduction for New Federal Buildings and Major Renovations of Federal Buildings Document details Fossil Fuel-Generated Energy Consumption ...

  17. fossil fuels | OpenEI Community

    Open Energy Info (EERE)

    energy becomes more competitive with fossil fuels in OECD countries, reports of this nature can go a long way to supporting more and more development. The four new reports in...

  18. Development of Nano-crystalline Doped-Ceramic Enabled Fiber Sensors for High Temperature In-Situ Monitoring of Fossil Fuel Gases

    SciTech Connect (OSTI)

    Xiao, Hai; Dong, Junhang; Lin, Jerry; Romero, Van

    2012-03-01

    This is a final technical report for the first project year from July 1, 2005 to Jan 31, 2012 for DoE/NETL funded project DE-FC26-05NT42439: Development of Nanocrystalline Doped-Ceramic Enabled Fiber Sensors for High Temperature In-Situ Monitoring of Fossil Fuel Gases. This report summarizes the technical progresses and achievements towards the development of novel nanocrystalline doped ceramic material-enabled optical fiber sensors for in situ and real time monitoring the gas composition of flue or hot gas streams involved in fossil-fuel based power generation and hydrogen production.

  19. No Fossils in This Fuel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... that burn diesel fuel. biomass - any organic plant or animal matter (wood, wood wastes, agricultural residues, animal wastes, micro-algae and other aquatic plants) that can be ...

  20. Development of Metal Oxide Nanostructure-based Optical Sensors for Fossil Fuel Derived Gases Measurement at High Temperature

    SciTech Connect (OSTI)

    Chen, Kevin

    2014-08-31

    operation temperature up to 750oC, first distributed chemical measurements at the record high temperature up to 700oC, first distributed pressure measurement at the record high temperature up to 800oC, and the fiber laser sensors with the record high operation temperature up to 700oC. The research performed by this program dramatically expand the functionality, adaptability, and applicability of distributed fiber optical sensors with potential applications in a number of high-temperature energy systems such as fossil-fuel power generation, high-temperature fuel cell applications, and potential for nuclear energy systems.

  1. Replace Fossil Fuels, Final Technical Report Roberts, William...

    Office of Scientific and Technical Information (OSTI)

    Crude Glycerol as Cost-Effective Fuel for Combined Heat and Power to Replace Fossil Fuels, Final Technical Report Roberts, William L 09 BIOMASS FUELS biofuels, glycerin, glycerol,...

  2. Solubilities of heavy fossil fuels in compressed gases

    SciTech Connect (OSTI)

    Monge, A. Jr.

    1982-01-01

    Design of processes for upgrading heavy fossil fuels such as coal-derived liquids, heavy petroleum fractions, tar sands, and shale oil, requires quantitative information for equilibrium properties of the fossil fuel in the presence of compressed light gases at elevated temperatures. Presented here are methods to predict and measure solubilities of heavy fossil fuels in compressed gases in the region ambient to 100 bar and 600 K. A molecular-thermodynamic model is used to predict heavy fossil-fuel solubilities. The heavy fuel is fractionated ina spinning-band column at low pressure and high reflux; each fraction is considered to be a pseudo-component. Each fraction is characterized by one vapor-pressure datum (obtained during fractionation), elemental analysis, and proton-NMR spectra (to determine aromaticity). Liquid-phase properties are obtained from the SWAP equation for vapor pressure and from a density correlation. Vapor-phase properties are obtained using the virial equation of state with virial coefficients from Kaul's correlation. The molecular-thermodynamic model has been used to establish a design-oriented computer program for calculating heavy, fossil-fuel solubility for general application in process design and, in particular, for isobaric condensation as a function of temperature as required for design of a continuous-flow heat exchanger. A total-vaporization technique is used to measure the solubilities of narrow-boiling, heavy fossil-fuel fractions in compressed gases. The solubility of a heavy fraction is determined from the volume of gas required to vaporize completely a small, measured mass of fossil-fuel sample. To test the molecular-thermodynamic model, the total-vaporization technique has been used to measure the solubilities of two Lurgi coal-tar fractions in compressed methane. Predicted and experimental solubilities agree well.

  3. Some aspects of the selection of materials for high temperature service in fossil fuel power generation

    SciTech Connect (OSTI)

    Birks, N.

    1999-07-01

    The electric power industry, converting heat into electricity, is concerned with two primary parameters, reliability and efficiency. In order to satisfy the reliability criteria, it is preferred to use well known and well tried materials well within their ultimate performance limits. In order to improve the economics of the process, it is attempted first to optimize the process and then to alter the operational parameters in order to increase the efficiency of the cycle used. The efficiency of the thermal cycle used depends primarily on its upper and lower temperature limits. For instance, it is well known that a plant operating in regions where the water supply is cooler demonstrate higher efficiencies than a plant that operates in warmer climates. For practical purposes however, it is the upper temperature limit of the cycle that must be increased to improve efficiency. This immediately requires that materials be selected, for the high temperature components, that can operate safely and continuously under these conditions, that also include aggressive, corrosive atmospheres. The need to consider higher operating temperatures opens up the range of materials being studied to include alloys that are established for high temperature use in other applications as well as new, mainly untried materials. The conditions under which a heat exchanger for electric power generation must operate are so different from other applications that nearly all materials, alternative to those now in use, must be approached as new and undergo extensive testing for coding. Few materials are available for use in this application off the shelf.

  4. Impact of cycle chemistry on fossil-fueled high pressure boilers - BHEL approach and experience

    SciTech Connect (OSTI)

    Somu, M.; Gourishankar, S.

    1995-01-01

    Cycle chemistry in high pressure boilers plays an important role as far as availability and reliability of the boilers are concerned. Up keep of proper cycle chemistry is a stupendous task and care must be taken, right from design stage to commissioning and operation of the boilers. It calls for selection of proper design, method of manufacture of critical components and practicing proper procedures during commissioning and regular operation of boilers. Control of cycle chemistry is important from the view point of proper quality of steam and prevention of corrosion. The corrosion is like a double edged knife which reduces the boiler availability on one side and steam quality on the other. The steam quality dictates the efficiency of the turbine. Apart from the internal and external Water Treatment practices, selection of proper deaerator, sizing of drum, steam loading, selection of appropriate drum internals etc. help achieve the desired cycle chemistry. The impact of such cycle chemistry, selection of equipment, Water Treatment practice and operational practices are presented in this paper, in the back drop of BHEL`s design, fabrication and operational guidelines and experience on high pressure boilers. The critical components in the pre-boiler circuit as well as in the main circuit are assessed from the point of view of appropriate water chemistry parameters.

  5. Fossil fuels supplies modeling and research

    SciTech Connect (OSTI)

    Leiby, P.N.

    1996-06-01

    The fossil fuel supplies modeling and research effort focuses on models for US Strategic Petroleum Reserve (SPR) planning and management. Topics covered included new SPR oil valuation models, updating models for SPR risk analysis, and fill-draw planning. Another task in this program area is the development of advanced computational tools for three-dimensional seismic analysis.

  6. Thermal dissolution of solid fossil fuels

    SciTech Connect (OSTI)

    E.G. Gorlov

    2007-10-15

    The use of oil shales and coals in the processes of thermal dissolution is considered. It is shown that thermal dissolution is a mode of liquefaction of solid fossil fuels and can be used both independently and in combination with liquefaction of coals and processing of heavy petroleum residues.

  7. Carbon Dioxide Information Analysis Center (CDIAC)-Fossil Fuel...

    Open Energy Info (EERE)

    Fuel CO2 Emissions Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Carbon Dioxide Information Analysis Center (CDIAC)-Fossil Fuel CO2 Emissions AgencyCompany...

  8. Fossil

    Broader source: Energy.gov [DOE]

    Fossil fuels -- which contain carbon and include coal, oil and natural gas -- are drilled or mined before being burned to produce electricity, or refined for use as fuel for heating or transportation.

  9. Fossil fuel is king with energy producers

    SciTech Connect (OSTI)

    Hansen, T.

    1996-11-01

    Worldwide energy consumption is expected to double today`s levels by 2020, according to the World Energy Council. As diverse energy needs develop, fossil fuels are expected to continue to be the major source for power generation throughout the world. In the United States, utility deregulation is making low-cost fuel and power plant efficiency more important than ever. Electricity generators see both natural gas and coal as the fuels that will allow them to best meet the nation`s future energy needs. Coal will see less increase in its share of electricity generation than natural gas due to the costs associated with meeting the Clean Air Act Amendments` (CAAA) requirements. According to Organizations for Economic Cooperation Development, coal in both the United States and Europe will experience a 12 percent growth by 2010. Even with this somewhat slow growth, coal will remain the nation`s number one fuel for electricity generation well into the next century.

  10. Fossil fuel conversion--measurement and modeling

    SciTech Connect (OSTI)

    Solomon, P.R.; Smoot, L.D.; Serio, M.A.; Hamblen, D.G.; Brewster, B.S.; Radulovic, P.T.

    1994-10-01

    The main objective of this program is to understand the chemical and physical mechanisms in coal conversion processes and incorporate this knowledge in computer-aided reactor engineering technology for the purposes of development, evaluation, design, scale-up, simulation, control and feedstock evaluation in advanced coal conversion devices. To accomplish this objective, this program will: (1) provide critical data on the physical and chemical processes in fossil fuel gasifiers and combustors; (2) further develop a set of comprehensive codes; and (3) apply these codes to model various types of combustors and gasifiers (fixed-bed, transport reactor, and fluidized-bed for coal and gas turbines for natural gas).

  11. Norwegian carbon taxes and their implication for fossil fuels

    SciTech Connect (OSTI)

    Kaarstad, O.

    1995-12-31

    The Scandinavian countries, and in particular Norway and Sweden, have since 1990/91 taxed CO{sub 2}-emissions with carbon tax of about US $150 per ton of CO{sub 2}. One may therefore say that these countries have placed themselves in a role as {open_quotes}carbon tax laboratories{close_quotes}. These very high CO{sub 2}-taxes have been in place for about four years and the first lessons from this experience are reported. In general it would seem as if the taxation mechanism is less efficient than economists have expected. The CO{sub 2}-emissions are increasing in both Norway and Sweden and the stabilization goal to the year 2000 will not be achieved in spite of the high taxation. The fossil fuel industry will have to learn to live with the climate change question which is inherently hostile to fossil fuels. It is argued that a more informed and active participation by the fossil fuel industry is needed in the climate change discussion. In addition the image of fossil fuels will benefit from showing real and potential improvement in the area of greenhouse gas emissions in the whole energy chain from production to combustion. The R&D effort being done into CO{sub 2}-capture and -disposal is creating such an option for the future. It is argued that the image of the entire fossil fuel industry will benefit from the creation of a {open_quotes}CO{sub 2}-free{close_quote} option or vision for oil, gas and coal. A number of examples are shown where today (or in the near future) actual CO{sub 2}-disposal in underground formations are taking place.

  12. High efficiency, quasi-instantaneous steam expansion device utilizing fossil or nuclear fuel as the heat source

    SciTech Connect (OSTI)

    Claudio Filippone, Ph.D.

    1999-06-01

    Thermal-hydraulic analysis of a specially designed steam expansion device (heat cavity) was performed to prove the feasibility of steam expansions at elevated rates for power generation with higher efficiency. The steam expansion process inside the heat cavity greatly depends on the gap within which the steam expands and accelerates. This system can be seen as a miniaturized boiler integrated inside the expander where steam (or the proper fluid) is generated almost instantaneously prior to its expansion in the work-producing unit. Relatively cold water is pulsed inside the heat cavity, where the heat transferred causes the water to flash to steam, thereby increasing its specific volume by a large factor. The gap inside the heat cavity forms a special nozzle-shaped system in which the fluid expands rapidly, accelerating toward the system outlet. The expansion phenomenon is the cause of ever-increasing fluid speed inside the cavity system, eliminating the need for moving parts (pumps, valves, etc.). In fact, the subsequent velocity induced by the sudden fluid expansion causes turbulent conditions, forcing accelerating Reynolds and Nusselt numbers which, in turn, increase the convective heat transfer coefficient. When the combustion of fossil fuels constitutes the heat source, the heat cavity concept can be applied directly inside the stator of conventional turbines, thereby greatly increasing the overall system efficiency.

  13. Minimising greenhouse gas emissions from fossil fuels

    SciTech Connect (OSTI)

    Freund, P.

    1997-07-01

    Combustion of fossil fuels is the main anthropogenic source of carbon dioxide, the principal greenhouse gas. Generation of electricity is the single largest user of fossil fuels, world-wide. If there is international agreement about the need to make substantial reductions in greenhouse gas emissions, then having access to suitable, effective technology would be important. This would help avoid the need for precipitate action, such as radical changes in the energy supply systems. Capture and disposal of greenhouse gases from flue gases can achieve substantial reductions in greenhouse gas emissions. This can be realized with known technology. In this paper, the range of options will be summarized and steps needed to achieve further progress will be identified. Emissions of other gases, such as methane, are also expected to influence the climate. Methane is emitted from many anthropogenic sources; the IEA Greenhouse Gas programme is investigating ways of reducing these emissions. Opportunities for abatement of methane emissions associated with coal mining will be described. Reduction in emissions from drainage gas is relatively straightforward and can, in appropriate circumstances, generate useful income for the none operator. More substantial amounts of methane are discharged in mine ventilation air but these are more difficult to deal with. In this paper, a summary will be given of recent progress in reducing methane emissions. Opportunities will be examined for further research to progress these technologies.

  14. EMGeo: Risk Minimizing Software for Finding Offshore Fossil Fuels...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Find More Like This Return to Search EMGeo: Risk Minimizing Software for Finding Offshore ... developed advanced software for discovering and mapping offshore fossil fuel deposits. ...

  15. Brazil-NETL Advanced Fossil Fuels Partnerships | Open Energy...

    Open Energy Info (EERE)

    Brazil-NETL Advanced Fossil Fuels Partnerships (Redirected from Brazil-NETL Cooperation) Jump to: navigation, search Logo: Brazil-NETL Cooperation Name Brazil-NETL Cooperation...

  16. Brazil-NETL Advanced Fossil Fuels Partnerships | Open Energy...

    Open Energy Info (EERE)

    Brazil-NETL Advanced Fossil Fuels Partnerships Jump to: navigation, search Logo: Brazil-NETL Cooperation Name Brazil-NETL Cooperation AgencyCompany Organization National Energy...

  17. Fossil Fuel-Generated Energy Consumption Reduction for New Federal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Consumption Reduction for New Federal Buildings and Major Renovations of Federal Buildings OIRA Comparison Document Document details the Fossil Fuel-Generated Energy Consumption ...

  18. U.S. DOE fossil energy fuel cell program

    SciTech Connect (OSTI)

    Wayne Surdoval

    2007-07-01

    The U.S. Department of Energy's Office of Fossil Energy's National Energy Technology Laboratory, in partnership with private industry, educational institutions, and national laboratories, is leading the research, development, and demonstration of high efficiency, fuel flexible solid oxide fuel cells (SOFCs) and coal based SOFC power generation systems for stationary markets. This Fuel Cell Program has three parts: Solid State Energy Conversion Alliance (SECA) cost reduction, SECA fuel cell coal based systems, and advanced SECA systems. The SECA cost reduction goal is to have SOFCs capable of being mass manufactured at $400 per kilowatt by 2010. Concurrently, the scale-up, aggregation, and integration of the technology will progress in parallel leading to prototype validation of megawatt class products by 2012 with potential testing at FutureGen. The SECA coal-based and advanced systems goals are the development of megawatt-class fuel cell power systems that will enable affordable, reliable, efficient, and environmentally-friendly electrical power from coal.

  19. An oxy-hydrocarbon model of fossil fuels

    SciTech Connect (OSTI)

    Fred D. Lang; Tom Canning

    2007-09-15

    This paper asserts a new method of analyzing fossil fuels, useful for sorting coals into well-defined categories and for the identification of outlying ultimate analysis data. It describes a series of techniques starting with a new multivariant approach for describing the lower ranks of coal, progressing to a classical, but modified, single-variant approach for the volatile and high-energy ranks. In addition, for a few special cases, multiple low and high ranks are also well described by the multivariant approach. As useful as these techniques are for analyzing fuel chemistry in the laboratory arena, this work was initiated in support of Exergetic Systems' Input/Loss Method. At commercial coal-fired power plants, Input/Loss allows the determination of fuel chemistry based on combustion effluents. The methods presented allow equations to be developed independent of combustion stoichiometrics, which improve Input/Loss accuracy in determining fuel chemistry on-line and in real time.

  20. Optimization of fossil fuel sources: An exergy approach

    SciTech Connect (OSTI)

    Camdali, U.

    2007-02-15

    We performed linear programming for optimization of fossil fuel supply in 2000 in Turkey. For this, an exergy analysis is made because the second law of thermodynamics takes into account the quality of energy as well as quantity of energy. Our analyses showed that the interfuel substitution between different fossil fuels will lead to a best energy mix of the country. The total retail price of fossil fuels can be lowered to 11.349 billion US$ from 13.012 billion US$ by increasing the domestic production of oil, lignite, and hard coal and by decreasing imports. The remaining demand can be met by natural gas imports. In conclusion, our analysis showed that a reduction of 1.663 billion US$ in fossil fuel cost can be made possible by giving more emphasis on domestic production, particularly of oil, lignite and hard coal.

  1. Sales of Fossil Fuels Produced from Federal and Indian Lands...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    of Energy Washington, DC 20585 U.S. Energy Information Administration | Sales of Fossil Fuels Produced on Federal and Indian Lands, FY 2003 through FY 2012 ii This report...

  2. A review of METC`S continuous process monitoring devices for application to high temperature and pressure fossil fuel process streams

    SciTech Connect (OSTI)

    Chisholm, W.P.

    1994-12-31

    The Morgantown Energy Technology Center of the United States Department of Energy, in support of advanced fossil fuel technologies, is developing and applying a number of innovative continuous process monitors. These include an inductively coupled plasma spectrometer, an alkali monitor, a particle counter and sizer, and a water vapor monitor. The alkali monitor is a flame emission spectrometer currently undergoing field trials. Alkali emission from gasifiers and combustors is of interest because it causes corrosion and deposition on downstream components, such as particle filters, sulfur compound sorbents, turbine blades, etc. This device can measure alkali concentrations at the part-per-billion level. The particle monitoring devices use laser light scattering to count and size particles. By measuring particle concentration around a particulate removal device, capture efficiency can be measured in real time with a resolution of one minute. Particles between .45 and 80 microns can be counted at rates as high as one million per second in 5 bar, 350 degree celsius environments. The optical water vapor monitor uses near-infrared light absorption to monitor and control steam injection in an advanced heat exchanger. It is targeted for a 300 degrees celsius and 5 bar environment. The inductively coupled plasma system uses a helium and argon plasma discharge within a torch assembly capable of accepting a high temperature and pressure sample stream. An artificial neural network is being developed to interpret its data. Real-time data from a bench-scale coal gasifier will be presented and discussed.

  3. Fe-Al Weld Overlay and High Velocity Oxy-Fuel Thermal Spray Coatings for Corrosion Protection of Waterwalls in Fossil Fired Plants with Low NOx Burners

    SciTech Connect (OSTI)

    Regina, J.R.

    2002-02-08

    Iron-aluminum-chromium coatings were investigated to determine the best candidates for coatings of boiler tubes in Low NOx fossil fueled power plants. Ten iron-aluminum-chromium weld claddings with aluminum concentrations up to 10wt% were tested in a variety of environments to evaluate their high temperature corrosion resistance. The weld overlay claddings also contained titanium additions to investigate any beneficial effects from these ternary and quaternary alloying additions. Several High-Velocity Oxy-Fuel (HVOF) thermal spray coatings with higher aluminum concentrations were investigated as well. Gaseous corrosion testing revealed that at least 10wt%Al is required for protection in the range of environments examined. Chromium additions were beneficial in all of the environments, but additions of titanium were beneficial only in sulfur rich atmospheres. Similar results were observed when weld claddings were in contact with corrosive slag while simultaneously, exposed to the corrosive environments. An aluminum concentration of 10wt% was required to prevent large amounts of corrosion to take place. Again chromium additions were beneficial with the greatest corrosion protection occurring for welds containing both 10wt%Al and 5wt%Cr. The exposed thermal spray coatings showed either significant cracking within the coating, considerable thickness loss, or corrosion products at the coating substrate interface. Therefore, the thermal spray coatings provided the substrate very little protection. Overall, it was concluded that of the coatings studied weld overlay coatings provide superior protection in these Low NOx environments; specifically, the ternary weld composition of 10wt%Al and 5wt%Cr provided the best corrosion protection in all of the environments tested.

  4. Determination of the Average Aromatic Cluster Size of Fossil Fuels by Solid-State NMR at High Magnetic Field

    SciTech Connect (OSTI)

    Mao, Kanmi; Kennedy, Gordon J.; Althaus, Stacey M.; Pruski, Marek

    2013-01-07

    We show that the average aromatic cluster size in complex carbonaceous materials can be accurately determined using fast magic-angle spinning (MAS) NMR at a high magnetic field. To accurately quantify the nonprotonated aromatic carbon, we edited the 13C spectra using the recently reported MAS-synchronized spinecho, which alleviated the problem of rotational recoupling of 1H-13C dipolar interactions associated with traditional dipolar dephasing experiments. The dependability of this approach was demonstrated on selected Argonne Premium coal standards, for which full sets of basic structural parameters were determined with high accuracy.

  5. Hydrogen Separation Membranes for Vision 21 Fossil Fuel Plants

    SciTech Connect (OSTI)

    Roark, Shane E.; Mackay, Richard; Sammells, Anthony F.

    2001-11-06

    Eltron Research and team members CoorsTek, McDermott Technology, Sued Chemie, Argonne National Laboratory, and Oak Ridge National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. This project was motivated by the Department of Energy (DOE) National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. The proposed technology addresses the DOE Vision 21 initiative in two ways. First, this process offers a relatively inexpensive solution for pure hydrogen separation that can be easily incorporated into Vision 21 fossil fuel plants. Second, this process could reduce the cost of hydrogen, which is a clean burning fuel under increasing demand as supporting technologies are developed for hydrogen utilization and storage. Additional motivation for this project arises from the potential of this technology for other applications. By appropriately changing the catalysts coupled with the membrane, essentially the same system can be used to facilitate alkane dehydrogenation and coupling, aromatics processing, and hydrogen sulfide decomposition.

  6. Fossil fuels in a sustainable energy future

    SciTech Connect (OSTI)

    Bechtel, T.F.

    1995-12-01

    The coal industry in the United States has become a world leader in safety, productivity, and environmental protection in the mining of coal. The {open_quotes}pick-and-shovel{close_quotes} miner with mangled limbs and black lung disease has been replaced by the highly skilled technicians that lead the world in tons per man-hour. The gob piles, polluted streams, and scared land are a thing of the past. The complementary efforts of the DOE and EPRI-funded programs in coal utilization R&D and the Clean Coal Technology Program commercial demonstrations, have positioned the power generation industry to utilize coal in a way that doesn`t pollute the air or water, keeps electrical power costs low, and avoids the mountains of waste material. This paper reviews the potential for advanced coal utilization technologies in new power generation applications as well as the repowering of existing plants to increase their output, raise their efficiency, and reduce pollution. It demonstrates the potential for these advanced coal-fueled plants to play a complementary role in future planning with the natural gas and oil fired units currently favored in the market place. The status of the US program to demonstrate these technologies at commercial scale is reviewed in some detail.

  7. New Optimal Sensor Suite for Ultrahigh Temperature Fossil Fuel Applications

    SciTech Connect (OSTI)

    John Coggin; Jonas Ivasauskas; Russell G. May; Michael B. Miller; Rena Wilson

    2006-09-30

    Accomplishments during Phase II of a program to develop and demonstrate photonic sensor technology for the instrumentation of advanced powerplants are described. The goal of this project is the research and development of advanced, robust photonic sensors based on improved sapphire optical waveguides, and the identification and demonstration of applications of the new sensors in advanced fossil fuel power plants, where the new technology will contribute to improvements in process control and monitoring. During this program work period, major progress has been experienced in the development of the sensor hardware, and the planning of the system installation and operation. The major focus of the next work period will be the installation of sensors in the Hamilton, Ohio power plant, and demonstration of high-temperature strain gages during mechanical testing of SOFC components.

  8. Fossil fuel combined cycle power system

    DOE Patents [OSTI]

    Labinov, Solomon Davidovich; Armstrong, Timothy Robert; Judkins, Roddie Reagan

    2006-10-10

    A system for converting fuel energy to electricity includes a reformer for converting a higher molecular weight gas into at least one lower molecular weight gas, at least one turbine to produce electricity from expansion of at least one of the lower molecular weight gases, and at least one fuel cell. The system can further include at least one separation device for substantially dividing the lower molecular weight gases into at least two gas streams prior to the electrochemical oxidization step. A nuclear reactor can be used to supply at least a portion of the heat the required for the chemical conversion process.

  9. New Optical Sensor Suite for Ultrahigh Temperature Fossil Fuel Application

    SciTech Connect (OSTI)

    John Coggin; Tom Flynn; Jonas Ivasauskas; Daniel Kominsky; Carrie Kozikowski; Russell May; Michael Miller; Tony Peng; Gary Pickrell; Raymond Rumpf; Kelly Stinson-Bagby; Dan Thorsen; Rena Wilson

    2007-12-31

    Accomplishments of a program to develop and demonstrate photonic sensor technology for the instrumentation of advanced powerplants and solid oxide fuel cells are described. The goal of this project is the research and development of advanced, robust photonic sensors based on improved sapphire optical waveguides, and the identification and demonstration of applications of the new sensors in advanced fossil fuel power plants, where the new technology will contribute to improvements in process control and monitoring.

  10. Fossil fuel combined cycle power generation method

    DOE Patents [OSTI]

    Labinov, Solomon D [Knoxville, TN; Armstrong, Timothy R [Clinton, TN; Judkins, Roddie R [Knoxville, TN

    2008-10-21

    A method for converting fuel energy to electricity includes the steps of converting a higher molecular weight gas into at least one mixed gas stream of lower average molecular weight including at least a first lower molecular weight gas and a second gas, the first and second gases being different gases, wherein the first lower molecular weight gas comprises H.sub.2 and the second gas comprises CO. The mixed gas is supplied to at least one turbine to produce electricity. The mixed gas stream is divided after the turbine into a first gas stream mainly comprising H.sub.2 and a second gas stream mainly comprising CO. The first and second gas streams are then electrochemically oxidized in separate fuel cells to produce electricity. A nuclear reactor can be used to supply at least a portion of the heat the required for the chemical conversion process.

  11. US fossil fuel technologies for Thailand

    SciTech Connect (OSTI)

    Buehring, W.A.; Dials, G.E.; Gillette, J.L.; Szpunar, C.B.; Traczyk, P.A.

    1990-10-01

    The US Department of Energy has been encouraging other countries to consider US coal and coal technologies in meeting their future energy needs. Thailand is one of three developing countries determined to be a potentially favorable market for such exports. This report briefly profiles Thailand with respect to population, employment, energy infrastructure and policies, as well as financial, economic, and trade issues. Thailand is shifting from a traditionally agrarian economy to one based more strongly on light manufacturing and will therefore require increased energy resources that are reliable and flexible in responding to anticipated growth. Thailand has extensive lignite deposits that could fuel a variety of coal-based technologies. Atmospheric fluidized-bed combustors could utilize this resource and still permit Thailand to meet emission standards for sulfur dioxide. This option also lends itself to small-scale applications suitable for private-sector power generation. Slagging combustors and coal-water mixtures also appear to have potential. Both new construction and refurbishment of existing plants are planned. 18 refs., 3 figs., 7 tabs.

  12. Fossil fuel decarbonization technology for mitigating global warming

    SciTech Connect (OSTI)

    Steinberg, M.

    1998-09-01

    It has been understood that production of hydrogen from fossil and carbonaceous fuels with reduced CO{sub 2} emission to the atmosphere is key to the production of hydrogen-rich fuels for mitigating the CO{sub 2} greenhouse gas climate change problem. The conventional methods of hydrogen production from fossil fuels (coal, oil, gas and biomass) include steam reforming and water gas shift mainly of natural gas (SRM). In order to suppress CO{sub 2} emission from the steam reforming process, CO{sub 2} must be concentrated and sequestered either in or under the ocean or underground (in aquifers, or depleted oil or gas wells). Up to about 40% of the energy is lost in this process. An alternative process is the pyrolysis or the thermal decomposition of methane, natural gas (TDM) to hydrogen and carbon. The carbon can either be sequestered or sold on the market as a materials commodity or used as a fuel at a later date under less severe CO{sub 2} restraints. The energy sequestered in the carbon amounts to about 42% of the energy in the natural gas resource which is stored and not destroyed. A comparison is made between the well developed conventional SRM and the less developed TDM process including technological status, efficiency, carbon management and cost. The TDM process appears to have advantages over the well developed SRM process. It is much easier to sequester carbon as a stable solid than CO{sub 2} as a reactive gas or low temperature liquid. It is also possible to reduce cost by marketing the carbon as a filler or construction material. The potential benefits of the TDM process justifies its further efficient development. The hydrogen can be used as a transportation fuel or converted to methanol by reaction with CO{sub 2} from fossil fuel fired power plant stack gases, thus allowing reuse of the carbon in conventional IC automobile engines or in advanced fuel cell vehicles.

  13. Fossil fuel decarbonization technology for mitigating global warming

    SciTech Connect (OSTI)

    Steinberg, M.

    1998-07-01

    It has been understood that production of hydrogen from fossil and carbonaceous fuels with reduced CO{sub 2} emission to the atmosphere is key to the production of hydrogen-rich fuels for mitigating the CO{sub 2} greenhouse gas climate change problem. The conventional methods of hydrogen production from fossil fuels (coal, oil, gas and biomass) include steam reforming and water gas shift mainly of natural gas (SRM). In order to suppress CO{sub 2} emission from the steam reforming process, CO{sub 2} must be concentrated and sequestered either in or under the ocean or in or underground (in aquifers, or depleted oil or gas wells). Up to about 40% of the energy is lost in this process. An alternative process is the pyrolysis or the thermal decomposition of methane, natural gas (TDM) to hydrogen and carbon. The carbon can either be sequestered or sold on the market as a materials commodity or used as a fuel at a later date under less severe CO{sub 2} restraints. The energy sequestered in the carbon amounts to about 42% of the energy in the natural gas resource which is stored and not destroyed. A comparison is made between the well developed conventional SRB and the less developed TDM process including technological status, efficiency, carbon management and cost. The TDM process appears to have advantages over the well developed SRM process. It is much easier to sequester carbon as a stable solid than CO{sub 2} as a reactive gas or low temperature liquid. It is also possible to reduce cost by marketing the carbon as a filler or construction material. The potential benefits of the TDM process justifies its further efficient development. The hydrogen can be used as a transportation fuel or converted to methanol by reaction with CO{sub 2} from fossil fuel fired power plant stack gases, thus allowing reuse of the carbon in conventional IC automobile engines or in advanced fuel cell vehicles.

  14. Fossil fuel decarbonization technology for mitigating global warming

    SciTech Connect (OSTI)

    Steinberg, M.

    1998-04-01

    It has been understood that production of hydrogen from fossil and carbonaceous fuels with reduced CO{sub 2} emission to the atmosphere is key to the production of hydrogen-rich fuels for mitigating the CO{sub 2} greenhouse gas climate change problem. The conventional methods of hydrogen production from fossil fuels (coal, oil, gas and biomass) include steam reforming process, mainly of natural gas (SRM). In order to suppress CO{sub 2} emission from the steam reforming process, CO{sub 2} must be concentrated and sequestered either in or under the ocean or in or underground (in aquifers, or depleted oil or gas wells). Up to about 40% of the energy is lost in this process. An alternative process is the pyrolysis or the thermal decomposition of methane, natural gas (TDM) to hydrogen and carbon. The carbon can either be sequestered or sold on the market as a materials commodity or used as a fuel at a later date under less severe CO{sub 2} restraints. The energy sequestered in the carbon amounts to about 42% of the energy in the natural gas resource which is stored and not destroyed. A comparison is made between the well developed conventional SRM and the less developed TDM process including technological status, efficiency, carbon management and cost. The TDM process appears to have advantages over the well developed SRM process. It is much easier to sequester carbon as a stable solid than CO{sub 2} as a reactive gas or low temperature liquid. It is also possible to reduce cost by marketing the carbon as a filler or construction material. The potential benefits of the TDM process justifies its further efficient development. The hydrogen can be used as a transportation fuel or converted to methanol by reaction with CO{sub 2} from fossil fuel fired power plant stack gases, thus allowing reuse of the carbon in conventional IC automobile engines or in advanced fuel cell vehicles.

  15. BIOENERGIZEME INFOGRAPHIC CHALLENGE: Biofuels vs Fossil Fuels

    Broader source: Energy.gov [DOE]

    This infographic was created by students from North Caddo Magnet High School in Vivian, LA, as part of the U.S. Department of Energy-BioenergizeME Infographic Challenge. The BioenergizeME...

  16. EA-1778: Proposed Rule, 10 CFR 433 and 435, Energy Conservation and Fossil Fuel-Generated Energy

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of DOE's Proposed Rule, 10 CFR Part 433, “Energy Conservation and Fossil Fuel-Generated Energy Consumption Reduction Standards for the Design and Construction of New Federal Commercial and Multi-Family High-Rise Residential Buildings” and 10 CFR Part 435, “Energy Conservation and Fossil Fuel-Generated Energy Consumption Reduction Standards for the Design and Construction of New Federal Low-Rise Residential Buildings”.

  17. Impacts of Wind and Solar on Fossil-Fueled Generators: Preprint

    SciTech Connect (OSTI)

    Lew, D.; Brinkman, G.; Kumar, N.; Besuner, P.; Agan, D.; Lefton, S.

    2012-08-01

    High penetrations of wind and solar power will impact the operations of the remaining generators on the power system. Regional integration studies have shown that wind and solar may cause fossil-fueled generators to cycle on and off and ramp down to part load more frequently and potentially more rapidly. Increased cycling, deeper load following, and rapid ramping may result in wear-and-tear impacts on fossil-fueled generators that lead to increased capital and maintenance costs, increased equivalent forced outage rates, and degraded performance over time. Heat rates and emissions from fossil-fueled generators may be higher during cycling and ramping than during steady-state operation. Many wind and solar integration studies have not taken these increased cost and emissions impacts into account because data have not been available. This analysis considers the cost and emissions impacts of cycling and ramping of fossil-fueled generation to refine assessments of wind and solar impacts on the power system.

  18. HIGH EFFICIENCY FOSSIL POWER PLANT (HEFPP) CONCEPTUALIZATION PROGRAM

    SciTech Connect (OSTI)

    J.L. Justice

    1999-03-25

    This study confirms the feasibility of a natural gas fueled, 20 MW M-C Power integrated pressurized molten carbonate fuel cell combined in a topping cycle with a gas turbine generator plant. The high efficiency fossil power plant (HEFPP) concept has a 70% efficiency on a LHV basis. The study confirms the HEFPP has a cost advantage on a cost of electricity basis over the gas turbine based combined cycle plants in the 20 MW size range. The study also identifies the areas of further development required for the fuel cell, gas turbine generator, cathode blower, inverter, and power module vessel. The HEFPP concept offers an environmentally friendly power plant with minuscule emission levels when compared with the combined cycle power plant.

  19. Mitigating environmental pollution and impacts from fossil fuels: The role of alternative fuels

    SciTech Connect (OSTI)

    Liu, L.; Cheng, S.Y.; Li, J.B.; Huang, Y.F.

    2007-07-01

    In order to meet the rising global demand for energy, rapid development of conventional fossil fuels (i.e., coal, oil, and natural gas) have been experienced by many nations, bringing dramatic economic benefit and prosperity to fossil-fuel industries as well as well being of human society. However, various fossil-fuel related activities emit huge quantities of gaseous, liquid, and solid waste materials, posing a variety of impacts, risks, and liabilities to the environment. Therefore, on the one hand, control measures are desired for effectively managing pollution issues; on the other hand, it becomes extremely critical to invest efforts in finding promising alternative energy sources as solutions to the possible energy shortage crisis in future. This article focuses on both aspects through: (1) a discussion of waste materials generated from fossil-fuel industries and waste management measures; and (2) an exploration of some well-recognized alternative fuels in terms of their nature, availability, production, handling, environmental performances, and current and future applications. The conclusion restates the urgency of finding replaceable long-term alternatives to the conventional fuels.

  20. Krakow clean fossil fuels and energy efficiency project

    SciTech Connect (OSTI)

    Butcher, T.A.; Pierce, B.L.

    1995-11-01

    The Support for Eastern European Democracy (SEED) Act of 1989 directed the U.S. Department of Energy (DOE) to undertake an equipment assessment project aimed at developing the capability within Poland to manufacture or modify industrial-scale combustion equipment to utilize fossil fuels cleanly. This project is being implemented in the city of Krakow as the `Krakow Clean Fossil Fuels and Energy Efficiency Project.` Funding is provided through the U.S. Agency for International Development (AID). The project is being conducted in a manner that can be generalized to all of Poland and to the rest of Eastern Europe. The historic city of Krakow has a population of 750,000. Almost half of the heating energy used in Krakow is supplied by low-efficiency boilerhouses and home coal stoves. Within the town, there are more than 1,300 local boilerhouses and 100,000 home stoves. These are collectively referred to as the `low emission sources` and they are the primary sources of particulates and hydrocarbon emissions in the city and major contributors of sulfur dioxide and carbon monoxide.

  1. EPRI-DOE Joint Report on Fossil Fleet Transition with Fuel Changes...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Large Scale Variable Renewable Integration Now Available EPRI-DOE Joint Report on Fossil Fleet Transition with Fuel Changes and Large Scale Variable Renewable Integration ...

  2. Carter, L.D. 20 FOSSIL-FUELED POWER PLANTS; COAL GASIFICATION...

    Office of Scientific and Technical Information (OSTI)

    carbon capture, utilisation, and storage Carter, L.D. 20 FOSSIL-FUELED POWER PLANTS; COAL GASIFICATION; POWER GENERATION; CARBON DIOXIDE; CAPTURE; STORAGE; USA; ENHANCED...

  3. N.R. 20 FOSSIL-FUELED POWER PLANTS; 21 SPECIFIC NUCLEAR REACTORS...

    Office of Scientific and Technical Information (OSTI)

    20 FOSSIL-FUELED POWER PLANTS; 21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS; 14 SOLAR ENERGY; 15 GEOTHERMAL ENERGY; GEOTHERMAL POWER PLANTS; COMPUTERIZED SIMULATION; HEAT...

  4. Rajendran, N. 36 MATERIALS SCIENCE; 20 FOSSIL-FUELED POWER PLANTS...

    Office of Scientific and Technical Information (OSTI)

    ACI Committee 229 Rajendran, N. 36 MATERIALS SCIENCE; 20 FOSSIL-FUELED POWER PLANTS; 01 COAL, LIGNITE, AND PEAT; FLY ASH; WASTE PRODUCT UTILIZATION; BACKFILLING; THERMAL...

  5. Fossil fuel derivatives with reduced carbon. Phase I final report

    SciTech Connect (OSTI)

    Kennel, E.B.; Zondlo, J.W.; Cessna, T.J.

    1999-06-30

    This project involves the simultaneous production of clean fossil fuel derivatives with reduced carbon and sulfur, along with value-added carbon nanofibers. This can be accomplished because the nanofiber production process removes carbon via a catalyzed pyrolysis reaction, which also has the effect of removing 99.9% of the sulfur, which is trapped in the nanofibers. The reaction is mildly endothermic, meaning that net energy production with real reductions in greenhouse emissions are possible. In Phase I research, the feasibility of generating clean fossil fuel derivatives with reduced carbon was demonstrated by the successful design, construction and operation of a facility capable of utilizing coal as well as natural gas as an inlet feedstock. In the case of coal, for example, reductions in CO{sub 2} emissions can be as much as 70% (normalized according to kilowatts produced), with the majority of carbon safely sequestered in the form of carbon nanofibers or coke. Both of these products are value-added commodities, indicating that low-emission coal fuel can be done at a profit rather than a loss as is the case with most clean-up schemes. The main results of this project were as follows: (1) It was shown that the nanofiber production process produces hydrogen as a byproduct. (2) The hydrogen, or hydrogen-rich hydrocarbon mixture can be consumed with net release of enthalpy. (3) The greenhouse gas emissions from both coal and natural gas are significantly reduced. Because coal consumption also creates coke, the carbon emission can be reduced by 75% per kilowatt-hour of power produced.

  6. Progress performance report of clean uses of fossil fuels

    SciTech Connect (OSTI)

    Todd, Jr., Lee T.; Boggess, Ronald J.; Carson, Ronald J.; Falkenberg, Virginia P.; Flanagan, Patrick; Hettinger, Jr., William P.; Kimel, Kris; Kupchella, Charles E.; Magid, Lee J.; McLaughlin, Barbara; Royster, Wimberly C.; Streepey, Judi L.; Wells, James H.; Stencel, John; Derbyshire, Frank J.; Hanley, Thomas R.; Magid, Lee J.; McEllistrem, Marc T.; Riley, John T.; Steffen, Joseph M.

    1992-01-01

    A one-year USDOE/EPSCOR Traineeship Grant, entitled Clean Uses of Fossil Fuels.'' was awarded to the Kentucky EPSCoR Committee in September 1991 and administered through the the DOE/EPSCoR Subcommittee. Ten Traineeships were awarded to doctoral students who are enrolled or accepted into Graduate Programs at either the University of Kentucky or the University of Louisville. The disciplines of these students include Biology, Chemical Engineering, Chemistry, Geological Sciences, and Physics. The methods used for a statewide proposal solicitation and to award the Traineeships are presented. The review panel and Kentucky DOE/EPSCoR Subcommittee involved in awarding the Traineeships are described. A summary of the proposed research to be performed within these awards is presented, along with a description of the qualifications of the faculty and students who proposed projects. Future efforts to increase participation in Traineeship proposals for the succeeding funding period are outlined.

  7. Progress performance report of clean uses of fossil fuels

    SciTech Connect (OSTI)

    Not Available

    1992-09-01

    A one-year USDOE/EPSCOR Traineeship Grant, entitled ``Clean Uses of Fossil Fuels.`` was awarded to the Kentucky EPSCoR Committee in September 1991 and administered through the the DOE/EPSCoR Subcommittee. Ten Traineeships were awarded to doctoral students who are enrolled or accepted into Graduate Programs at either the University of Kentucky or the University of Louisville. The disciplines of these students include Biology, Chemical Engineering, Chemistry, Geological Sciences, and Physics. The methods used for a statewide proposal solicitation and to award the Traineeships are presented. The review panel and Kentucky DOE/EPSCoR Subcommittee involved in awarding the Traineeships are described. A summary of the proposed research to be performed within these awards is presented, along with a description of the qualifications of the faculty and students who proposed projects. Future efforts to increase participation in Traineeship proposals for the succeeding funding period are outlined.

  8. 30 DIRECT ENERGY CONVERSION; 20 FOSSIL-FUELED POWER PLANTS; 32...

    Office of Scientific and Technical Information (OSTI)

    Lee, G.T.; Sudhoff, F.A. 30 DIRECT ENERGY CONVERSION; 20 FOSSIL-FUELED POWER PLANTS; 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; FUEL CELL POWER PLANTS; GAS TURBINE...

  9. The Council of Industrial Boiler Owners special project on non-utility fossil fuel ash classification

    SciTech Connect (OSTI)

    Svendsen, R.L.

    1996-12-31

    Information is outlined on the Council of Industrial Boiler Owners (CIBO) special project on non-utility fossil fuel ash classification. Data are presented on; current (1996) regulatory status of fossil-fuel combustion wastes; FBC technology identified for further study; CIBO special project methods; Bevill amendment study factors; data collection; and CIBO special project status.

  10. Low-emission vortex combustion of biomass and fossil fuel

    SciTech Connect (OSTI)

    Finker, F.Z.; Kubischkin, I.B.; Akhmedov, D.B.

    1995-11-01

    The article introduces the results of development and industrial experience of low-emission vortex combustion technology (LEVC) of biomass and fossil fuel in industrial and utility boilers in Russian timber and paper industries and Polish power plants. The LEVC technology is based on aerodynamics method of multiple circulation of gases and fuel in the furnaces. LEVC technology accumulates the advantages of conventional and fluidized bed combustion technology. Existing boilers could be easily retrofitted for the application of LEVC technology without requiring major investment. The repowering of boiler with LEVC was the result the reduction NOx emission to the level 170g/GJ without installation additional flue gas cleaning equipment and it gave the opportunity for an injection of sulfur sorbent in the furnace. The authors discussed Russian-Polish experiment on utility boiler retrofitted with the application of LEVC. As the result the efficiency of the boiler increased in 2%. The reduction of the emission is: NOx-40%, SO2-17%.

  11. Refractory failure in IGCC fossil fuel power systems

    SciTech Connect (OSTI)

    Dogan, Cynthia P.; Kwong, Kyei-Sing; Bennett, James P.; Chinn, Richard E.

    2001-01-01

    Current generation refractory materials used in slagging gasifiers employed in Integrated Gasification Combined Cycle (IGCC) fossil fuel power systems have unacceptably short service lives, limiting the reliability and cost effectiveness of gasification as a means to generate power. The short service life of the refractory lining results from exposure to the extreme environment inside the operating gasifier, where the materials challenges include temperatures to 1650 C, thermal cycling, alternating reducing and oxidizing conditions, and the presence of corrosive slags and gases. Compounding these challenges is the current push within the industry for fuel flexibility, which results in slag chemistries and operating conditions that can vary widely as the feedstock for the gasifier is supplemented with alternative sources of carbon, such as petroleum coke and biomass. As a step toward our goal of developing improved refractory materials for this application, we have characterized refractory-slag interactions, under a variety of simulated gasifier conditions, utilizing laboratory exposure tests such as the static cup test and a gravimetric test. Combining this information with that gained from the post-mortem analyses of spent refractories removed from working gasifiers, we have developed a better understanding of refractory failure in gasifier environments. In this paper, we discuss refractory failures in slagging gasifiers and possible strategies to reduce them. Emphasis focuses on the refractories employed in gasifier systems which utilize coal as the primary feedstock.

  12. Advanced technologies for co-processing fossil and biomass resources for transportation fuels and power generation

    SciTech Connect (OSTI)

    Steinberg, M.; Dong, Y.

    2004-07-01

    Over the past few decades, a number of processes have been proposed or are under development for coprocessing fossil fuel and biomass for transportation fuels and power generation. The paper gives a brief description of the following processes: the Hydrocarb system for converting biomass and other carbonaceous fuels to elemental carbon and hydrogen, methane or methanol; the Hynol process where the second step of the Hydrocarb process is replaced with a methane steam reformer to convert methane to CO and H{sub 2}S without deposition of carbon; the Carnol process where CO{sub 2} from coal and the biomass power plants is reacted with hydrogen to produce methanol; and advanced biomass high efficiency power generator cycle where a continuous plasma methane decomposition reactor (PDR) is used with direct carbon fuel cell to produce power and carbon and hydrogen. 13 refs., 5 figs., 2 tabs.

  13. Fossil Energy-Developed Fuel Cell Technology Being Adapted by Navy for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Unmanned Undersea Vehicles | Department of Energy Fossil Energy-Developed Fuel Cell Technology Being Adapted by Navy for Advanced Unmanned Undersea Vehicles Fossil Energy-Developed Fuel Cell Technology Being Adapted by Navy for Advanced Unmanned Undersea Vehicles January 31, 2013 - 12:00pm Addthis An unmanned undersea vehicle (UUV) being deployed during a U.S. Office of Naval Research demonstration near Panama City. Solid oxide fuel cell technology being developed by the Office of

  14. INNOVATIVE FOSSIL FUEL FIRED VITRIFICATION TECHNOLOGY FOR SOIL REMEDIATION

    SciTech Connect (OSTI)

    J. Hnat; L.M. Bartone; M. Pineda

    2001-07-13

    This Summary Report summarizes the progress of Phases 3, 3A and 4 of a waste technology Demonstration Project sponsored under a DOE Environmental Management Research and Development Program and administered by the U.S. Department of Energy National Energy Technology Laboratory-Morgantown (DOE-NETL) for an ''Innovative Fossil Fuel Fired Vitrification Technology for Soil Remediation''. The Summary Reports for Phases 1 and 2 of the Program were previously submitted to DOE. The total scope of Phase 3 was to have included the design, construction and demonstration of Vortec's integrated waste pretreatment and vitrification process for the treatment of low level waste (LLW), TSCA/LLW and mixed low-level waste (MLLW). Due to funding limitations and delays in the project resulting from a law suit filed by an environmental activist and the extended time for DOE to complete an Environmental Assessment for the project, the scope of the project was reduced to completing the design, construction and testing of the front end of the process which consists of the Material Handling and Waste Conditioning (MH/C) Subsystem of the vitrification plant. Activities completed under Phases 3A and 4 addressed completion of the engineering, design and documentation of the Material Handling and Conditioning System such that final procurement of the remaining process assemblies can be completed and construction of a Limited Demonstration Project be initiated in the event DOE elects to proceed with the construction and demonstration testing of the MH/C Subsystem.

  15. Emissions from ethanol-blended fossil fuel flames

    SciTech Connect (OSTI)

    Akcayoglu, Azize

    2011-01-15

    A fundamental study to investigate the emission characteristics of ethanol-blended fossil fuels is presented. Employing a heterogeneous experimental setup, emissions are measured from diffusion flames around spherical porous particles. Using an infusion pump, ethanol-fossil fuel blend is transpired into a porous sphere kept in an upward flowing air stream. A typical probe of portable digital exhaust gas analyzer is placed in and around the flame with the help of a multi-direction traversing mechanism to measure emissions such as un-burnt hydrocarbons, carbon monoxide and carbon dioxide. Since ethanol readily mixes with water, emission characteristics of ethanol-water blends are also studied. For comparison purpose, emissions from pure ethanol diffusion flames are also presented. A simplified theoretical analysis has been carried out to determine equilibrium surface temperature, composition of the fuel components in vapor-phase and heat of reaction of each blend. These theoretical predictions are used in explaining the emission characteristics of flames from ethanol blends. (author) This paper presents the results of an experimental study of flow structure in horizontal equilateral triangular ducts having double rows of half delta-wing type vortex generators mounted on the duct's slant surfaces. The test ducts have the same axial length and hydraulic diameter of 4 m and 58.3 mm, respectively. Each duct consists of double rows of half delta wing pairs arranged either in common flow-up or common flow-down configurations. Flow field measurements were performed using a Particle Image Velocimetry Technique for hydraulic diameter based Reynolds numbers in the range of 1000-8000. The secondary flow field differences generated by two different vortex generator configurations were examined in detail. The secondary flow is found stronger behind the second vortex generator pair than behind the first pair but becomes weaker far from the second pair in the case of Duct1. However

  16. Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2014

    U.S. Energy Information Administration (EIA) Indexed Site

    3 Map Appendix State/area maps Figure A1. Fossil fuel production on federal and Indian lands, FY 2014 Source: U.S. Energy Information Administration based on U.S. Department of the Interior, Office of Natural Resources Revenue. "ONNR Statistical Information Site" (http://statistics.onrr.gov). July 2015 U.S. Energy Information Administration | Sales of Fossil Fuels Produced on Federal and Indian Lands, FY 2003 through FY 2014 24 Figure A2. Changes in fossil fuels production (trillion

  17. Fossil Fuel Carbon Dioxide Emissions Data and Data Plots from Project Vulcan

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Gurney, Kevin

    The Vulcan Project is a NASA/DOE funded effort under the North American Carbon Program (NACP) to quantify North American fossil fuel carbon dioxide (CO2) emissions at space and time scales much finer than has been achieved in the past. The purpose is to aid in quantification of the North American carbon budget, to support inverse estimation of carbon sources and sinks, and to support the demands posed by higher resolution CO2 observations (in situ and remotely sensed). The detail and scope of the Vulcan CO2 inventory has also made it a valuable tool for policymakers, demographers, social scientists and the public at large. The Vulcan project has achieved the quantification of the 2002 U.S. fossil fuel CO2 emissions at the scale of individual factories, powerplants, roadways and neighborhoods on an hourly basis. The entire inventory was built on a common 10 km x 10 km grid to facilitate atmospheric modeling. In addition to improvement in space and time resolution, Vulcan is quantified at the level of fuel type, economic sub-sector, and county/state identification. Explore the Vulcan website for the Vulcan gridded data, methodological details, publications, plots and analysis.[Taken from "About Project Vulcan" at http://www.purdue.edu/eas/carbon/vulcan/index.php]Also, see the peer-reviewed paper that provides a "core" description for this project: Gurney, K.R., D. Mendoza, Y. Zhou, M Fischer, S. de la Rue du Can, S. Geethakumar, C. Miller (2009) The Vulcan Project: High resolution fossil fuel combustion CO2 emissions fluxes for the United States, Environ. Sci. Technol., 43, doi:10.1021/es900,806c.

  18. INNOVATIVE FOSSIL FUEL FIRED VITRIFICATION TECHNOLOGY FOR SOIL REMEDIATION

    SciTech Connect (OSTI)

    J. Hnat; L.M. Bartone; M. Pineda

    2001-10-31

    This Final Report summarizes the progress of Phases 3,3A and 4 of a waste technology Demonstration Project sponsored under a DOE Environmental Management Research and Development Program and administered by the U.S. Department of Energy National Energy Technology Laboratory-Morgantown (DOE-NETL) for an ''Innovative Fossil Fuel Fired Vitrification Technology for Soil Remediation''. The Summary Reports for Phases 1 and 2 of the Program were previously submitted to DOE. The total scope of Phase 3 was to have included the design, construction and demonstration of Vortec's integrated waste pretreatment and vitrification process for the treatment of low level waste (LLW), TSCA/LLW and mixed low-level waste (MLLW). Due to funding limitations and delays in the project resulting from a law suit filed by an environmental activist and the extended time for DOE to complete an Environmental Assessment for the project, the scope of the project was reduced to completing the design, construction and testing of the front end of the process which consists of the Material Handling and Waste Conditioning (MH/C) Subsystem of the vitrification plant. Activities completed under Phases 3A and 4 addressed completion of the engineering, design and documentation of the MH/C System such that final procurement of the remaining process assemblies can be completed and construction of a Limited Demonstration Project be initiated in the event DOE elects to proceed with the construction and demonstration testing of the MH/C Subsystem. Because of USEPA policies and regulations that do not require treatment of low level or low-level/PCB contaminated wastes, DOE terminated the project because there is no purported need for this technology.

  19. Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2011

    Broader source: Energy.gov [DOE]

    This paper was prepared in response to recent requests that the U.S. Energy Information Administration (EIA) provide updated summary information regarding fossil fuel production on federal and...

  20. fan blades Karr, O.F.; Brooks, J.B.; Seay, E. 20 FOSSIL-FUELED...

    Office of Scientific and Technical Information (OSTI)

    draft fan blades Karr, O.F.; Brooks, J.B.; Seay, E. 20 FOSSIL-FUELED POWER PLANTS; 32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATION; 42 ENGINEERING NOT INCLUDED IN OTHER...

  1. Fossil fuel potential of Turkey: A statistical evaluation of reserves, production, and consumption

    SciTech Connect (OSTI)

    Korkmaz, S.; Kara-Gulbay, R.; Turan, M.

    2008-07-01

    Since Turkey is a developing country with tremendous economic growth, its energy demand is also getting increased. Of this energy, about 70% is supplied from fossil fuels and the remaining 30% is from renewable sources. Among the fossil fuels, 90% of oil, natural gas, and coal are imported, and only 10% is from domestic sources. All the lignite is supplied from domestic sources. The total share of renewable sources and lignite in the total energy production is 45%. In order for Turkey to have sufficient and reliable energy sources, first the renewable energy sources must be developed, and energy production from fossil fuels, except for lignite, must be minimized. Particularly, scarcity of fossil fuels and increasing oil prices have a strong effect on economic growth of the country.

  2. Allen, C.A. 15 GEOTHERMAL ENERGY; 20 FOSSIL-FUELED POWER PLANTS...

    Office of Scientific and Technical Information (OSTI)

    Liquid-fluidized-bed heat exchanger flow distribution models Cole, L.T.; Allen, C.A. 15 GEOTHERMAL ENERGY; 20 FOSSIL-FUELED POWER PLANTS; FLUIDIZED BED HEAT EXCHANGERS; DESIGN;...

  3. Impacts of Renewable Generation on Fossil Fuel Unit Cycling: Costs and Emissions (Presentation)

    SciTech Connect (OSTI)

    Brinkman, G.; Lew, D.; Denholm, P.

    2012-09-01

    Prepared for the Clean Energy Regulatory Forum III, this presentation looks at the Western Wind and Solar Integration Study and reexamines the cost and emissions impacts of fossil fuel unit cycling.

  4. Fossil Fuel Carbon Dioxide Emissions Data and Data Plots from Project Vulcan

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Gurney, Kevin

    Explore the Vulcan website for the Vulcan gridded data, methodological details, publications, plots and analysis.[Taken from "About Project Vulcan" at http://www.purdue.edu/eas/carbon/vulcan/index.php]Also, see the peer-reviewed paper that provides a "core" description for this project: Gurney, K.R., D. Mendoza, Y. Zhou, M Fischer, S. de la Rue du Can, S. Geethakumar, C. Miller (2009) The Vulcan Project: High resolution fossil fuel combustion CO2 emissions fluxes for the United States, Environ. Sci. Technol., 43, doi:10.1021/es900,806c.

  5. A synthesis of carbon dioxide emissions from fossil-fuel combustion

    SciTech Connect (OSTI)

    Andres, Robert Joseph; Boden, Thomas A; Breon, F.-M.; Erickson, D; Gregg, J. S.; Jacobson, Andrew; Marland, Gregg; Miller, J.; Oda, T; Raupach, Michael; Rayner, P; Treanton, K.

    2012-01-01

    This synthesis discusses the emissions of carbon dioxide from fossil-fuel combustion and cement production. While much is known about these emissions, there is still much that is unknown about the details surrounding these emissions. This synthesis explores 5 our knowledge of these emissions in terms of why there is concern about them; how they are calculated; the major global efforts on inventorying them; their global, regional, and national totals at different spatial and temporal scales; how they are distributed on global grids (i.e. maps); how they are transported in models; and the uncertainties associated with these different aspects of the emissions. The magnitude of emissions 10 from the combustion of fossil fuels has been almost continuously increasing with time since fossil fuels were first used by humans. Despite events in some nations specifically designed to reduce emissions, or which have had emissions reduction as a byproduct of other events, global total emissions continue their general increase with time. Global total fossil-fuel carbon dioxide emissions are known to within 10% uncertainty (95% 15 confidence interval). Uncertainty on individual national total fossil-fuel carbon dioxide emissions range from a few percent to more than 50 %. The information discussed in this manuscript synthesizes global, regional and national fossil-fuel carbon dioxide emissions, their distributions, their transport, and the associated uncertainties.

  6. 2004 Office of Fossil Energy Fuel Cell Program Annual Report

    SciTech Connect (OSTI)

    NETL

    2004-11-01

    Annual report of fuel cell projects sponsored by Department of Energy, National Energy Technology Laboratory.

  7. Hydrogen milestone could help lower fossil fuel refining costs

    ScienceCinema (OSTI)

    McGraw, Jennifer

    2013-05-28

    Hydrogen researchers at the U.S. Department of Energy's Idaho National Laboratory have reached another milestone on the road to reducing carbon emissions and protecting the nation against the effects of peaking world oil production. Stephen Herring, laboratory fellow and technical director of the INL High Temperature Electrolysis team, today announced that the latest fuel cell modification has set a new mark in endurance. The group's Integrated Laboratory Scale experiment has now operated continuously for 2,583 hours at higher efficiencies than previously attained. Learn more about INL research at http://www.facebook.com/idahonationallaboratory.

  8. Hydrogen milestone could help lower fossil fuel refining costs

    SciTech Connect (OSTI)

    McGraw, Jennifer

    2009-01-01

    Hydrogen researchers at the U.S. Department of Energy's Idaho National Laboratory have reached another milestone on the road to reducing carbon emissions and protecting the nation against the effects of peaking world oil production. Stephen Herring, laboratory fellow and technical director of the INL High Temperature Electrolysis team, today announced that the latest fuel cell modification has set a new mark in endurance. The group's Integrated Laboratory Scale experiment has now operated continuously for 2,583 hours at higher efficiencies than previously attained. Learn more about INL research at http://www.facebook.com/idahonationallaboratory.

  9. Identifying fly ash at a distance from fossil fuel power stations

    SciTech Connect (OSTI)

    Flanders, P.J.

    1999-02-15

    A method has been developed to identify fly ash originating at fossil fuel power stations, even at a distance where the ash level is lower by a factor of 1000 from that close to a source. Until now such detection has been difficult and uncertain. The technique combines collection of particles, measurement of magnetization and coercive field, and microscopy. The analysis depends on the fact that ash from iron sulfide in fossil fuels is in the form of spherical magnetite. These particles have a relatively high coercive field H{sub c}, near 135 Oe, compared with airborne particulates from soil erosion which have an H{sub c} of {approximately}35 Oe. The coercive field of any sample therefore gives an indication for the percentage of fly ash relative to the total amount of magnetic material that is airborne. The concentration of ash from a large, isolated coal burning power station is found to fall off with the distance from the source, approximately as D{sup {minus}1}. As D increases there is a drop in H{sub c}, associated with the reduced amount of fly ash relative to the airborne particulates from soil erosion.

  10. Risks to global biodiversity from fossil-fuel production exceed those from biofuel production

    SciTech Connect (OSTI)

    Dale, Virginia H; Parish, Esther S; Kline, Keith L

    2015-01-01

    Potential global biodiversity impacts from near-term gasoline production are compared to biofuel, a renewable liquid transportation fuel expected to substitute for gasoline in the near term (i.e., from now until c. 2030). Petroleum exploration activities are projected to extend across more than 5.8 billion ha of land and ocean worldwide (of which 3.1 billion is on land), much of which is in remote, fragile terrestrial ecosystems or off-shore oil fields that would remain relatively undisturbed if not for interest in fossil fuel production. Future biomass production for biofuels is projected to fall within 2.0 billion ha of land, most of which is located in areas already impacted by human activities. A comparison of likely fuel-source areas to the geospatial distribution of species reveals that both energy sources overlap with areas with high species richness and large numbers of threatened species. At the global scale, future petroleum production areas intersect more than double the area and higher total number of threatened species than future biofuel production. Energy options should be developed to optimize provisioning of ecosystem services while minimizing negative effects, which requires information about potential impacts on critical resources. Energy conservation and identifying and effectively protecting habitats with high-conservation value are critical first steps toward protecting biodiversity under any fuel production scenario.

  11. Risks to global biodiversity from fossil-fuel production exceed those from biofuel production

    SciTech Connect (OSTI)

    Dale, Virginia H.; Parish, Esther S.; Kline, Keith L.

    2014-12-02

    Potential global biodiversity impacts from near-term gasoline production are compared to biofuel, a renewable liquid transportation fuel expected to substitute for gasoline in the near term (i.e., from now until c. 2030). Petroleum exploration activities are projected to extend across more than 5.8 billion ha of land and ocean worldwide (of which 3.1 billion is on land), much of which is in remote, fragile terrestrial ecosystems or off-shore oil fields that would remain relatively undisturbed if not for interest in fossil fuel production. Future biomass production for biofuels is projected to fall within 2.0 billion ha of land, most of which is located in areas already impacted by human activities. A comparison of likely fuel-source areas to the geospatial distribution of species reveals that both energy sources overlap with areas with high species richness and large numbers of threatened species. At the global scale, future petroleum production areas intersect more than double the area and higher total number of threatened species than future biofuel production. Energy options should be developed to optimize provisioning of ecosystem services while minimizing negative effects, which requires information about potential impacts on critical resources. Furthermore, energy conservation and identifying and effectively protecting habitats with high-conservation value are critical first steps toward protecting biodiversity under any fuel production scenario.

  12. Risks to global biodiversity from fossil-fuel production exceed those from biofuel production

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Dale, Virginia H.; Parish, Esther S.; Kline, Keith L.

    2014-12-02

    Potential global biodiversity impacts from near-term gasoline production are compared to biofuel, a renewable liquid transportation fuel expected to substitute for gasoline in the near term (i.e., from now until c. 2030). Petroleum exploration activities are projected to extend across more than 5.8 billion ha of land and ocean worldwide (of which 3.1 billion is on land), much of which is in remote, fragile terrestrial ecosystems or off-shore oil fields that would remain relatively undisturbed if not for interest in fossil fuel production. Future biomass production for biofuels is projected to fall within 2.0 billion ha of land, most ofmore » which is located in areas already impacted by human activities. A comparison of likely fuel-source areas to the geospatial distribution of species reveals that both energy sources overlap with areas with high species richness and large numbers of threatened species. At the global scale, future petroleum production areas intersect more than double the area and higher total number of threatened species than future biofuel production. Energy options should be developed to optimize provisioning of ecosystem services while minimizing negative effects, which requires information about potential impacts on critical resources. Furthermore, energy conservation and identifying and effectively protecting habitats with high-conservation value are critical first steps toward protecting biodiversity under any fuel production scenario.« less

  13. Results of studies on application of CCMHD to advanced fossil fuel power plant cycles

    SciTech Connect (OSTI)

    Foote, J.P.; Wu, Y.C.L.S.; Lineberry, J.T.

    1998-07-01

    A study was conducted to assess the potential for application of a Closed Cycle MHD disk generator (CCMHD) in advanced fossil fuel power generation systems. Cycle analyses were conducted for a variety of candidate power cycles, including simple cycle CCMHD (MHD); a cycle combining CCMHD and gas turbines (MHD/GT); and a triple combined cycle including CCMHD, gas turbines, and steam turbines (MHD/GT/ST). The above cycles were previously considered in cycle studies reported by Japanese researchers. Also considered was a CCMHD cycle incorporating thermochemical heat recovery through reforming of the fuel stream (MHD/REF), which is the first consideration of this approach. A gas turbine/steam turbine combined cycle (GT/ST) was also analyzed for baseline comparison. The only fuel considered in the study was CH4. Component heat and pressure losses were neglected, and the potential for NOx emission due to high combustion temperatures was not considered. Likewise, engineering limitations for cycle components, particularly the high temperature argon heater, were not considered. This approach was adopted to simplify the analysis for preliminary screening of candidate cycles. Cycle calculations were performed using in-house code. Ideal gas thermodynamic properties were calculated using the NASA SP- 273 data base, and thermodynamic properties for steam were calculated using the computerized ASME Steam Tables. High temperature equilibrium compositions for combustion gas were calculated using tabulated values of the equilibrium constants for the important reactions.

  14. Fossil Fuel-Generated Energy Consumption Reduction for New Federal Buildings and Major Renovations of Federal Buildings OIRA Comparison Document

    Office of Energy Efficiency and Renewable Energy (EERE)

    Document details the Fossil Fuel-Generated Energy Consumption Reduction for New Federal Buildings and Major Renovations of Federal Buildings in an OIRA Comparison Document.

  15. Fossil Fuel-Generated Energy Consumption Reduction for New Federal Buildings and Major Renovations of Federal Buildings

    Broader source: Energy.gov [DOE]

    Document details Fossil Fuel-Generated Energy Consumption Reduction for New Federal Buildings and Major Renovations of Federal Buildings in a Supplemental Notice of Proposed Rulemaking.

  16. Municipal waste combustion assessment: Fossil fuel co-firing. Final report, October 1988-July 1989

    SciTech Connect (OSTI)

    Landrum, V.J.; Barton, R.G.

    1989-07-01

    The report identifies refuse derived fuel (RDF) processing operations and various RDF types; describes such fossil fuel co-firing techniques as coal fired spreader stokers, pulverized coal wall fired boilers, pulverized coal tangentially fired boilers, and cyclone fired boilers; and describes the population of coal fired boilers that currently co-fire RDF, have previously co-fired RDF but have ceased to do so, and have been used in RDF co-firing demonstrations. (Fossil fuel co-firing, defined as the combustion of RDF with another fuel (usually coal) in a device designed primarily to burn the other fuel, is generally confined to commercial and utility boilers.) Model plants are developed and good combustion practices are recommended.

  17. Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2014

    U.S. Energy Information Administration (EIA) Indexed Site

    Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2014 July 2015 Independent Statistics & Analysis www.eia.gov U.S. Department of Energy Washington, DC 20585 U.S. Energy Information Administration | Sales of Fossil Fuels Produced on Federal and Indian Lands, FY 2003 through FY 2014 i This report was prepared by the U.S. Energy Information Administration (EIA), the statistical and analytical agency within the U.S. Department of Energy. By law, EIA's data,

  18. Combustion system for hybrid solar fossil fuel receiver

    DOE Patents [OSTI]

    Mehos, Mark S.; Anselmo, Kenneth M.; Moreno, James B.; Andraka, Charles E.; Rawlinson, K. Scott; Corey, John; Bohn, Mark S.

    2004-05-25

    A combustion system for a hybrid solar receiver comprises a pre-mixer which combines air and fuel to form an air-fuel mixture. The mixture is introduced tangentially into a cooling jacket. A burner plenum is fluidically connected to the cooling jacket such that the burner plenum and the cooling jacket are arranged in thermal contact with one another. The air-fuel mixture flows through the cooling jacket cooling the burner plenum to reduce pre-ignition of the air-fuel mixture in the burner plenum. A combustion chamber is operatively associated with and open to the burner plenum to receive the air-fuel mixture from the burner plenum. An igniter is operatively positioned in the combustion chamber to combust the air-fuel mixture, releasing heat. A recuperator is operatively associated with the burner plenum and the combustion chamber and pre-heats the air-fuel mixture in the burner plenum with heat from the combustion chamber. A heat-exchanger is operatively associated and in thermal contact with the combustion chamber. The heat-exchanger provides heat for the hybrid solar receiver.

  19. Further experience for environmental improvement in fossil fuel combustion

    SciTech Connect (OSTI)

    Lazzeri, L.; Santis, R. de

    1998-12-31

    Reburning is a technology which has proven, by plant demonstration, capable of providing compliance with very stringent regulatory emissions requests (less than 90 ppm NO{sub x} firing oil and gas and less than 160--170 ppm firing coal). Designing a Reburn System requires a contemporary control of many parameters like flow rates, local stoichiometries residence times, etc.; it also requires the availability and capability of using complex and sophisticated numerical modeling. Although the system can be adapted to any already installed hardware it should be noted that the availability of reliable LNB`s and of specifically designed OFA`s and Reburn fuel injectors can greatly enhance the system performance. Design of OFA system is a subcase of a Reburn System design, as it implies same concepts of mixing and residence times which are the basis of Reburn System. As shown in the cases previously presented Reburning always provides additional margins to OFA operation specifically when very low emission limits are pursued. Finally it should be noted that the use of Reburning may create problems of unburned specifically when very low local stoichiometries and when very low sulfur oils are used which are often characterized by asphaltene instability especially when STZ oil is the result of blending high and low sulfur oils. A specific know-how has been jointly developed by Ansaldo and ENEL to solve these problems acting on both atomizer type selection and operation.

  20. Nuclear Energy R&D Imperative 3: Enable a Transition Away from Fossil Fuel in the Transportation and Industrial Sectors

    SciTech Connect (OSTI)

    David Petti; J. Stephen Herring

    2010-03-01

    As described in the Department of Energy Office of Nuclear Energy’s Nuclear Energy R&D Roadmap, nuclear energy can play a significant role in supplying energy for a growing economy while reducing both our dependence on foreign energy supplies and emissions from the burning of fossil fuels. The industrial and transportation sectors are responsible for more than half of the greenhouse gas emissions in the U.S., and imported oil supplies 70% of the energy used in the transportation sector. It is therefore important to examine the various ways nuclear energy can facilitate a transition away from fossil fuels to secure environmentally sustainable production and use of energy in the transportation and manufacturing industry sectors. Imperative 3 of the Nuclear Energy R&D Roadmap, entitled “Enable a Transition Away from Fossil Fuels by Producing Process Heat for use in the Transportation and Industrial Sectors”, addresses this need. This document presents an Implementation Plan for R&D efforts related to this imperative. The expanded use of nuclear energy beyond the electrical grid will contribute significantly to overcoming the three inter-linked energy challenges facing U.S. industry: the rising and volatile prices for premium fossil fuels such as oil and natural gas, dependence on foreign sources for these fuels, and the risks of climate change resulting from carbon emissions. Nuclear energy could be used in the industrial and transportation sectors to: • Generate high temperature process heat and electricity to serve industrial needs including the production of chemical feedstocks for use in manufacturing premium fuels and fertilizer products, • Produce hydrogen for industrial processes and transportation fuels, and • Provide clean water for human consumption by desalination and promote wastewater treatment using low-grade nuclear heat as a useful additional benefit. Opening new avenues for nuclear energy will significantly enhance our nation’s energy

  1. CO₂ emission mitigation and fossil fuel markets: Dynamic and international aspects of climate policies

    SciTech Connect (OSTI)

    Bauer, Nico; Bosetti, Valentina; Hamdi-Cherif, Meriem; Kitous, Alban; McCollum, David; Mejean, Aurelie; Rao, Shilpa; Turton, Hal; Paroussos, Leonidas; Ashina, Shuichi; Calvin, Katherine; Wada, Kenichi; van Vuuren, Detlef

    2015-01-01

    This paper explores a multi-model scenario ensemble to assess the impacts of idealized and non-idealized climate change stabilization policies on fossil fuel markets. Under idealized conditions climate policies significantly reduce coal use in the short- and long-term. Reductions in oil and gas use are much smaller, particularly until 2030, but revenues decrease much more because oil and gas prices are higher than coal prices. A first deviation from optimal transition pathways is delayed action that relaxes global emission targets until 2030 in accordance with the Copenhagen pledges. Fossil fuel markets revert back to the no-policy case: though coal use increases strongest, revenue gains are higher for oil and gas. To balance the carbon budget over the 21st century, the long-term reallocation of fossil fuels is significantly larger—twice and more—than the short-term distortion. This amplifying effect results from coal lock-in and inter-fuel substitution effects to balance the full-century carbon budget. The second deviation from the optimal transition pathway relaxes the global participation assumption. The result here is less clear-cut across models, as we find carbon leakage effects ranging from positive to negative because trade and substitution patterns of coal, oil, and gas differ across models. In summary, distortions of fossil fuel markets resulting from relaxed short-term global emission targets are more important and less uncertain than the issue of carbon leakage from early mover action.

  2. CO2 emissions mitigation and fossil fuel markets: Dynamic and international aspects of climate policies

    SciTech Connect (OSTI)

    Bauer, Nico; Bosetti, Valentina; Hamdi-Cherif, Meriem; Kitous, Alban; McCollum, David; Mejean, Aurelie; Rao, Shilpa; Turton, Hal; Paroussos, Leonidas; Ashina, Shuichi; Calvin, Katherine V.; Wada, Kenichi; Van Vuuren, Detlef

    2015-01-01

    This paper explores a multi-model scenario ensemble to assess the impacts of idealized and non-idealized climate change stabilization policies on fossil fuel markets. Under idealized conditions climate policies significantly reduce coal use in the short- and long-term. Reductions in oil and gas use are much smaller, particularly until 2030, but revenues decrease much more because oil and gas prices are higher and decrease with mitigation. A first deviation from the optimal transition pathway relaxes global emission targets until 2030, in accordance with the Copenhagen pledges and regionally-specific low-carbon technology targets. Fossil fuel markets revert back to the no-policy case: though coal use increases strongest, revenue gains are higher for oil and gas. To balance the carbon budget over the 21st century, the long-term reallocation of fossil fuels is significantly larger - twice and more - than the short-term distortion. This amplifying effect results from coal lock-in and inter-fuel substitution effects. The second deviation from the optimal transition pathway relaxes the global participation assumption. The result here is less clear cut across models, as we find carbon leakage effects ranging from positive to negative because leakage and substitution patterns of coal, oil, and gas differ. In summary, distortions of fossil fuel markets resulting from relaxed short-term global emission targets are more important and less uncertain than the issue of carbon leakage from early mover action.

  3. A creep damage estimation method for in-service fossil fuel boiler superheater tubes

    SciTech Connect (OSTI)

    Nogata, F. . Dept. of Mechanical Engineering); Takahashi, H. . Research Inst. of Fracture Technology)

    1995-02-01

    Because mechanical properties of structural materials for high-temperature use, such as boiler tubing, degrade during long-term service, it is essential to detect toughness degradation by means of a nondestructive and simple field test technique. A grain boundary etching technique is developed to detect material degradation, and assess creep strength and notch toughness. An etching test using a picric acid solution with a wetting agent or using 20 percent HNO[sub 3] with alcoholic solution was found to have great potential for the nondestructive estimation of grain boundary embrittlement caused by carbide and sigma precipitation in SUS stainless steel. The feasibility of this estimation procedure was determined showing the relationships between Charpy impact energy (CVN) and grooving width (W[sub GS]), and creep damage ratio ([Phi]) and W[sub GS]. Superheater tubes of fossil fuel boiler were tested on site to demonstrate the validity of this technique.

  4. Direct Carbon Conversion: Application to the Efficient Conversion of Fossil Fuels to Electricity

    SciTech Connect (OSTI)

    Cooper, J F; Cherepy, N; Berry, G; Pasternak, A; Surles, T; Steinberg, M

    2001-03-07

    We introduce a concept for efficient conversion of fossil fuels to electricity that entails the decomposition of fossil-derived hydrocarbons into carbon and hydrogen, and electrochemical conversion of these fuels in separate fuel cells. Carbon/air fuel cells have the advantages of near zero entropy change and associated heat production (allowing 100% theoretical conversion efficiency). The activities of the C fuel and CO{sub 2} product are invariant, allowing constant EMF and full utilization of fuel in single pass mode of operation. System efficiency estimates were conducted for several routes involving sequential extraction of a hydrocarbon from the fossil resource by (hydro) pyrolysis followed by thermal decomposition. The total energy conversion efficiencies of the processes were estimated to be (1) 80% for direct conversion of petroleum coke; (2) 67% HHV for CH{sub 4}; (3) 72% HHV for heavy oil (modeled using properties of decane); (4) 75.5% HHV (83% LHV) for natural gas conversion with a Rankine bottoming cycle for the H{sub 2} portion; and (5) 69% HHV for conversion of low rank coals and lignite through hydrogenation and pyrolysis of the CH{sub 4} intermediate. The cost of carbon fuel is roughly $7/GJ, based on the cost of the pyrolysis step in the industrial furnace black process. Cell hardware costs are estimated to be less than $500/kW.

  5. An overview of alternative fossil fuel price and carbon regulation scenarios

    SciTech Connect (OSTI)

    Wiser, Ryan; Bolinger, Mark

    2004-10-01

    The benefits of the Department of Energy's research and development (R&D) efforts have historically been estimated under business-as-usual market and policy conditions. In recognition of the insurance value of R&D, however, the Office of Energy Efficiency and Renewable Energy (EERE) and the Office of Fossil Energy (FE) have been exploring options for evaluating the benefits of their R&D programs under an array of alternative futures. More specifically, an FE-EERE Scenarios Working Group (the Working Group) has proposed to EERE and FE staff the application of an initial set of three scenarios for use in the Working Group's upcoming analyses: (1) a Reference Case Scenario, (2) a High Fuel Price Scenario, which includes heightened natural gas and oil prices, and (3) a Carbon Cap-and-Trade Scenario. The immediate goal is to use these scenarios to conduct a pilot analysis of the benefits of EERE and FE R&D efforts. In this report, the two alternative scenarios being considered by EERE and FE staff--carbon cap-and-trade and high fuel prices--are compared to other scenarios used by energy analysts and utility planners. The report also briefly evaluates the past accuracy of fossil fuel price forecasts. We find that the natural gas prices through 2025 proposed in the FE-EERE Scenarios Working Group's High Fuel Price Scenario appear to be reasonable based on current natural gas prices and other externally generated gas price forecasts and scenarios. If anything, an even more extreme gas price scenario might be considered. The price escalation from 2025 to 2050 within the proposed High Fuel Price Scenario is harder to evaluate, primarily because few existing forecasts or scenarios extend beyond 2025, but, at first blush, it also appears reasonable. Similarly, we find that the oil prices originally proposed by the Working Group in the High Fuel Price Scenario appear to be reasonable, if not conservative, based on: (1) the current forward market for oil, (2) current oil prices

  6. Environmental review for the conversion of Bellefonte Nuclear Plant to fossil fuel

    SciTech Connect (OSTI)

    Carter, R.; Rucker, H.; Summers, R.

    1998-07-01

    The Tennessee Valley Authority recently issued for public review a Draft Environmental Impact Statement for the conversion of the unfinished Bellefonte Nuclear Plant to fossil fuel. The DEIS was structured to support three tiers of decision making. Tier 1 is to decide between the No-Action Alternative, which is to leave Bellefonte as a partially completed nuclear plant into the indefinite future, and the Proposed Action Alternative, which is to proceed with converting Bellefonte to fossil fuel. Tier 2 is to select one of five conversion options. In the DEIS, TVA indicated no preference among the five competing fossil conversion options. The five conversion pathways would fully repower the plant consistent with fossil fuel availability, would use commercially ready systems and technologies and be designed to fully utilize the capacity of transmission lines serving Bellefonte. Conversion options addressed were pulverized coal (PC), natural gas combined cycle (NGCC), integrated gasification combined cycle (IGCC), IGCC with joint production of electricity and chemicals, and an option, which combines elements of NGCC and IGCC with coproduction. Tier 3 involves decisions about eight sub-option choices, basically types of processes, equipment, and modes of operation, which is part of two or more conversion options. An example of a sub-option choice would be the type of gasifier that would be used in conversion options involving coal or petroleum coke gasification. Other sub-option choices addressed in the DEIS were natural gas pipeline corridors; fuels, feedstocks, and by-products transportation modes; types of combustion turbines; solid fuels; types of boilers for conventional coal-fired options; chemical production mixes; and modes of onsite solid fuel conveyance. The impact of constructing and operating each proposed fossil conversion option at Bellefonte were evaluated for 18 environmental resource and economic categories.

  7. Steam-reforming of fossil fuels and wastes to produce energy and chemicals without greenhouse gases

    SciTech Connect (OSTI)

    Galloway, T.R.

    1998-07-01

    Worldwide concern has demanded a re-examination of the energy- and chemical-producing plants that use fossil fuel sources and release large quantities of greenhouse gases. Plant retrofits with steam-reformer/gasifiers will increase plant efficiencies, improve economics and avoid releasing troublesome amounts of greenhouse gases, such as carbon dioxide. In this paper, the authors describe and illustrate the several new steam-reforming/gasification plants that are processing waste streams and fossil fuels. These plants range in size from 1 ton/day to 2,000 tons/day. They are commercial and economically successful. These new concepts can be used to both upgrade fossil plants for improved economics while eliminating the release of greenhouse gases. By aggressively retrofitting old coal plants and sequestering CO{sub 2}, a 15% reduction in 1990 CO{sub 2} emissions can be met by the US by 2010.

  8. Liquid fossil-fuel technology. Quarterly technical progress report, April-June 1982

    SciTech Connect (OSTI)

    Linville, B.

    1982-10-01

    This report primarily covers in-house oil, gas, and synfuel research and lists the contracted research. The report is broken into the following areas: liquid fossil fuel cycle, extraction, processing, utilization, and project integration and technology transfer. BETC publications are listed. (DLC)

  9. Environmental impact of fossil fuel combustion in power generation

    SciTech Connect (OSTI)

    Allen, J.W.; Beal, P.R.

    1996-12-31

    All the recent developments in the combustion systems employed for power generation have been based on environmental considerations. Combustion modifications have been developed and utilised in order to control NO{sub x} emissions and improvements continue to be made as the legislative requirements tighten. Chemical processes and fuel switching are used to control SO{sub x} emissions. After nitrogen, carbon dioxide is the major gas emitted from the combustion process and its potential potency as a greenhouse gas is well documented. Increased efficiency cycles, mainly based on natural gas as the prime fuel, can minimise the amount of CO{sub x} produced per unit of power generated. As the economics of natural gas utilisation become less favourable a return to clean coal technology based power generation processes may be required.

  10. Orimulsion conversion boosts prospects of `fourth` fossil fuel

    SciTech Connect (OSTI)

    1995-04-01

    This article describes how, by retrofitting a 100-MW oil-fired and a 215-MW coal-fired unit, one utility turned a plant destined for peaking service into a base-load asset with a predictable fuel bill and manageable emissions-even in environmentally sensitive Atlantic Canada. Six years ago, New Brunswick Power Corp (NB Power) found itself on the horns of a dilemma. For years, the utility had been searching for a powerplant fuel with a more stable price than oil, which at the time was fueling one-third of its generating capacity. Buying and burning more domestic coal-even at twice the price of offshore supplies-was the preferred option, because that would also help keep New Brunswick`s coal mines open. But by 1989, federal and provincial legislation had begun to plan for stringent limits on SO{sub 2} emissions that would take the local-coal card out of NB Power`s hand. Containing up to 8% sulfur, New Brunswick coal would be too dirty to burn by itself; emissions from a 200-MW unit would alone use up nearly half of the utility`s system-wide annual quota for SO{sub 2} emissions schedules for imposition in 1994. Enter Bitor America Corp, the Boca Raton (Fla) marketing subsidiary of the world`s third-largest oil company, Petroleos de Venezuela SA (PdVSA). Looking to further the fortunes of Orimulsion, a liquid emulsion of bitumen and water from the Orinoco region of Venezuela, Bitor funded and provided technical support for the first large-scale test burn of the fuel in the 100-MW Unit 1 of NB Power`s Dalhousie station in northern New Brunswick. After making the required modifications, NB Power burned Orimulsion in Unit 1 for two years. By 1991, the utility had cleanly converted more than a million barrels of the fuel to nearly half a million megawatt-hours of electricity-in the process finding few reasons not to commit to permanently converting Dalhousie`s Unit 1, as well as coal fired 215-MW Unit 2, to burn Orimulsion.

  11. Technical considerations in repowering a nuclear plant for fossil fueled operation

    SciTech Connect (OSTI)

    Patti, F.J.

    1996-03-01

    Repowering involves replacement of the reactor by a fossil fuel source of steam. This source can be a conventional fossil fueled boiler or the heat recovery steam generator (HRSG) on a gas turbine exhaust. The existing steam turbine plant is used to the extent possible. Alternative fuels for repowering a nuclear plant are coal, natural gas and oil. In today`s world oil is not usually an alternative. Selection of coal or natural gas is largely a matter of availability of the fuel near the location of the plant. Both the fossil boiler and the HRSG produce steam at higher pressures and temperatures than the throttle conditions for a saturated steam nuclear turbine. It is necessary to match the steam conditions from the new source to the existing turbine as closely as possible. Technical approaches to achieve a match range from using a topping turbine at the front end of the cycle to attemperation of the throttle steam with feedwater. The electrical output from the repowered plant is usually greater than that of the original nuclear fueled design. This requires consideration of the ability to use the excess electricity. Interfacing of the new facility with the existing turbine plant requires consideration of facility layout and design. Site factors must also be considered, especially for a coal fired boiler, since rail and coal handling facilities must be added to a site for which these were not considered. Additional site factors that require consideration are ash handling and disposal.

  12. Timing is everything : along the fossil fuel transition pathway.

    SciTech Connect (OSTI)

    Kobos, Peter Holmes; Walker, La Tonya Nicole; Malczynski, Leonard A.

    2013-10-01

    People save for retirement throughout their career because it is virtually impossible to save all you'll need in retirement the year before you retire. Similarly, without installing incremental amounts of clean fossil, renewable or transformative energy technologies throughout the coming decades, a radical and immediate change will be near impossible the year before a policy goal is set to be in place. Therefore, our research question is,To meet our desired technical and policy goals, what are the factors that affect the rate we must install technology to achieve these goals in the coming decades?' Existing models do not include full regulatory constraints due to their often complex, and inflexible approaches to solve foroptimal' engineering instead ofrobust' and multidisciplinary solutions. This project outlines the theory and then develops an applied software tool to model the laboratory-to-market transition using the traditional technology readiness level (TRL) framework, but develops subsequent and a novel regulatory readiness level (RRL) and market readiness level (MRL). This tool uses the ideally-suited system dynamics framework to incorporate feedbacks and time delays. Future energy-economic-environment models, regardless of their programming platform, may adapt this software model component framework ormodule' to further vet the likelihood of new or innovative technology moving through the laboratory, regulatory and market space. The prototype analytical framework and tool, called the Technology, Regulatory and Market Readiness Level simulation model (TRMsim) illustrates the interaction between technology research, application, policy and market dynamics as they relate to a new or innovative technology moving from the theoretical stage to full market deployment. The initial results that illustrate the model's capabilities indicate for a hypothetical technology, that increasing the key driver behind each of the TRL, RRL and

  13. Assessment of a multi-stage underwater vehicle concept using a fossil-fuel Stirling engine

    SciTech Connect (OSTI)

    Reader, G.T.; Potter, I.J.

    1995-12-31

    The Stirling Engine because of its inherent closed-cycle operation can be readily modified to work in an airless environment even if the primary source of energy is a fossil fuel. Thus, Stirling engines are well suited for use in the underwater environment and have been operated successfully in manned military submarines since the early 1980s. In recent years fossil fueled Stirling systems have been also proposed for use in small unmanned underwater vehicles (UUVs). However, in this case the need to carry an onboard oxygen supply in a very confined space has presented a number of design difficulties. These are identified in the paper. However, if the oxidant supply to the engine is provided by the membrane extraction of dissolved oxygen from seawater and/or disposable fuel/oxidant pods are used then the UUV Stirling system becomes more attractive. If this latter concept is extended to include multi-stage vehicles then it can be shown that fossil fueled Stirlings could also be put to effective use in long range-long endurance underwater vehicular operations.

  14. CO₂ emission mitigation and fossil fuel markets: Dynamic and international aspects of climate policies

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bauer, Nico; Bosetti, Valentina; Hamdi-Cherif, Meriem; Kitous, Alban; McCollum, David; Mejean, Aurelie; Rao, Shilpa; Turton, Hal; Paroussos, Leonidas; Ashina, Shuichi; et al

    2015-01-01

    This paper explores a multi-model scenario ensemble to assess the impacts of idealized and non-idealized climate change stabilization policies on fossil fuel markets. Under idealized conditions climate policies significantly reduce coal use in the short- and long-term. Reductions in oil and gas use are much smaller, particularly until 2030, but revenues decrease much more because oil and gas prices are higher than coal prices. A first deviation from optimal transition pathways is delayed action that relaxes global emission targets until 2030 in accordance with the Copenhagen pledges. Fossil fuel markets revert back to the no-policy case: though coal use increasesmore » strongest, revenue gains are higher for oil and gas. To balance the carbon budget over the 21st century, the long-term reallocation of fossil fuels is significantly larger—twice and more—than the short-term distortion. This amplifying effect results from coal lock-in and inter-fuel substitution effects to balance the full-century carbon budget. The second deviation from the optimal transition pathway relaxes the global participation assumption. The result here is less clear-cut across models, as we find carbon leakage effects ranging from positive to negative because trade and substitution patterns of coal, oil, and gas differ across models. In summary, distortions of fossil fuel markets resulting from relaxed short-term global emission targets are more important and less uncertain than the issue of carbon leakage from early mover action.« less

  15. Chlorine induced corrosion of steels in fossil fuel power plants

    SciTech Connect (OSTI)

    Spiegel, M.; Grabke, H.J.

    1998-12-31

    The corrosion of steels in power plants (coal combustion, waste incineration) is mainly due to condensed chlorides in the ash deposited on the boiler tubes. These chlorides are stabilized by HCl in the combustion gas. In the case of coal as a fuel, chlorine is present as chloride minerals in the raw material which is converted to HCl during the combustion process. Corrosion of steels in chlorine containing environments occurs by the active oxidation mechanism, which is a self-sustaining accelerated oxidation process, catalyzed by chlorine. This study shows that solid chlorides react with the oxide scale of the steels to form chlorine, which initiates active oxidation. In order to prevent chlorine induced corrosion, the deposition of chlorides on the tubes within the coal ash must be avoided. This is possible by the presence of SO{sub 2}, which is present in the combustion gas, converting the chlorides to sulfates in the gas phase. The paper presents an example of a failure case in a coal fired plant in Germany. In this plant, chlorine induced corrosion was observed after effective removal of SO{sub 2} by additions of CaO. From thermodynamic calculations it can be shown that a certain amount of SO{sub 2} is necessary in order to avoid deposition of chlorides and to prevent corrosion.

  16. Fossil fuel-fired peak heating for geothermal greenhouses

    SciTech Connect (OSTI)

    Rafferty, K.

    1997-01-01

    Greenhouses are a major application of low-temperature geothermal resources. In virtually all operating systems, the geothermal fluid is used in a hot water heating system to meet 100% of both the peak and annual heating requirements of the structure. This strategy is a result of the relatively low costs associated with the development of most US geothermal direct-use resources and past tax credit programs which penalized systems using any conventional fuel sources. Increasingly, greenhouse operations will encounter limitations in available geothermal resource flow due either to production or disposal considerations. As a result, it will be necessary to operate additions at reduced water temperatures reflective of the effluent from the existing operations. Water temperature has a strong influence on heating system design. Greenhouse operators tend to have unequivocal preferences regarding heating system equipment. Many growers, particularly cut flower and bedding plant operators, prefer the {open_quotes}bare tube{close_quotes} type heating system. This system places small diameter plastic tubes under the benches or adjacent to the plants. Hot water is circulated through the tubes providing heat to the plants and the air in the greenhouse. Advantages include the ability to provide the heat directly to the plants, low cost, simple installation and the lack of a requirement for fans to circulate air. The major disadvantage of the system is poor performance at low (<140{degrees}F) water temperatures, particularly in cold climates. Under these conditions, the quantity of tubing required to meet the peak heating load is substantial. In fact, under some conditions, it is simply impractical to install sufficient tubing in the greenhouse to meet the peak heating load.

  17. March 2015 Most Viewed Documents for Fossil Fuels | OSTI, US...

    Office of Scientific and Technical Information (OSTI)

    of calcium sulfate: a review of the literature. 62 refs Swift, W M; Panek, A F; Smith, G W; Vogel, G J; Jonke, A A (1976) 50 HIGH EFFICIENCY SYNGAS GENERATION Robert J. ...

  18. 2016 Bioenergizeme Infographic Challenge: Use of Fossil Fuels & Biofuels

    Office of Energy Efficiency and Renewable Energy (EERE)

    This infographic was created by students from High Tech Early College in Denver, CO, as part of the U.S. Department of Energy-BioenergizeME Infographic Challenge. The BioenergizeME Infographic...

  19. 2016 Bioenergizeme Infographic Challenge: Fossil Fuels vs Biofuels

    Office of Energy Efficiency and Renewable Energy (EERE)

    This infographic was created by students from Smithtown High School East in St. James, NY, as part of the U.S. Department of Energy-BioenergizeME Infographic Challenge. The BioenergizeME...

  20. Table 3.1 Fossil Fuel Production Prices, 1949-2011 (Dollars per Million Btu)

    U.S. Energy Information Administration (EIA) Indexed Site

    Fossil Fuel Production Prices, 1949-2011 (Dollars per Million Btu) Year Coal 1 Natural Gas 2 Crude Oil 3 Fossil Fuel Composite 4 Nominal 5 Real 6 Nominal 5 Real 6 Nominal 5 Real 6 Nominal 5 Real 6 Percent Change 7 1949 0.21 1.45 0.05 0.37 0.44 3.02 0.26 1.81 – – 1950 .21 1.41 .06 .43 .43 2.95 [R] .26 1.74 -3.6 1951 .21 1.35 .06 .40 .44 2.78 .26 1.65 -5.4 1952 .21 1.31 [R] .07 .45 .44 2.73 .26 1.63 -1.0 1953 .21 1.29 .08 .50 .46 2.86 .27 1.69 3.3 1954 .19 1.18 .09 .55 .48 2.94 .28 1.70 .7 1955

  1. Formulating Energy Policies Related to Fossil Fuel Use: Critical Uncertainties in the Global Carbon Cycle

    DOE R&D Accomplishments [OSTI]

    Post, W. M.; Dale, V. H.; DeAngelis, D. L.; Mann, L. K.; Mulholland, P. J.; O`Neill, R. V.; Peng, T. -H.; Farrell, M. P.

    1990-02-01

    The global carbon cycle is the dynamic interaction among the earth's carbon sources and sinks. Four reservoirs can be identified, including the atmosphere, terrestrial biosphere, oceans, and sediments. Atmospheric CO{sub 2} concentration is determined by characteristics of carbon fluxes among major reservoirs of the global carbon cycle. The objective of this paper is to document the knowns, and unknowns and uncertainties associated with key questions that if answered will increase the understanding of the portion of past, present, and future atmospheric CO{sub 2} attributable to fossil fuel burning. Documented atmospheric increases in CO{sub 2} levels are thought to result primarily from fossil fuel use and, perhaps, deforestation. However, the observed atmospheric CO{sub 2} increase is less than expected from current understanding of the global carbon cycle because of poorly understood interactions among the major carbon reservoirs.

  2. In-situ FT-IR diagnostics for monitoring and control of fossil fuel combustion

    SciTech Connect (OSTI)

    Bonanno, A.S.; Wojtowicz, M.A.; Serio, M.A.; Nelson, C.M.; Solomon, P.R.

    1995-12-31

    This paper describes the development and testing of a prototype fourier transform infrared (FT-IR) based measurement system for continuous emission monitoring (CEM) and process control in fossil fuel-fired power plants. On several occasions, prototype systems have been transported and assembled at full-scale and pilot-scale fossil fuel-fired combustors. The in-situ version of the prototype is able to measure NH{sub 3} and HCl concentrations, which are difficult to measure extractively, as well as CO, CO{sub 2}, NO{sub x}, H{sub 2}O, and SO{sub x} concentrations. The results of recent tests will be presented which involve in-situ monitoring of selective non-catalytic reduction (SNCR) of NO{sub x} based on simultaneous measurement of NO, NH{sub 3} and CO.

  3. Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2014

    U.S. Energy Information Administration (EIA) Indexed Site

    Table 1. Fossil fuel sales of production from federal lands, FY 2003-14 Fiscal Year Crude Oil and Lease Condensate Natural Gas Plant Liquids 2 Natural Gas Coal Fossil Fuels Million Barrels 1 Trillion Btu Percent of U.S. Total Million Barrels 1 Trillion Btu Percent of U.S. Total Billion Cubic Feet 1 Trillion Btu Percent of U.S. Total Million Short Tons 1 Trillion Btu Percent of U.S. Total Trillion Btu Percent of U.S. Total 2003 679 3,939 33.0% 93 347 14.7% 6,798 6,981 35.7% 436 8,960 40.6%

  4. Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2014

    U.S. Energy Information Administration (EIA) Indexed Site

    3 Table 2. Fossil fuel sales of production from Indian lands, FY 2003-14 Fiscal Year Crude Oil and Lease Condensate Natural Gas Plant Liquids 2 Natural Gas Coal Fossil Fuels Million Barrels 1 Trillion Btu Percent of U.S. Total Million Barrels 1 Trillion Btu Percent of U.S. Total Billion Cubic Feet 1 Trillion Btu Percent of U.S. Total Million Short Tons 1 Trillion Btu Percent of U.S. Total Trillion Btu Percent of U.S. Total 2003 10 59 0.5% 2 6 0.3% 283 291 1.5% 30 616 2.8% 972 1.7% 2004 10 58

  5. NEW OPTICAL SENSOR SUITE FOR ULTRAHIGH TEMPERATURE FOSSIL FUEL APPLICATIONS

    SciTech Connect (OSTI)

    Russell G. May; Tony Peng; Tom Flynn

    2004-04-01

    Accomplishments during the first six months of a program to develop and demonstrate technology for the instrumentation of advanced powerplants are described. Engineers from Prime Research, LC and Babcock and Wilcox Research Center collaborated to generate a list of potential applications for robust photonic sensors in existing and future boiler plants. From that list, three applications were identified as primary candidates for initial development and demonstration of high-temperature sensors in an ultrasupercritical power plant. In addition, progress was made in the development of materials and methods to apply high-temperature optical claddings to sapphire fibers, in order to improve their optical waveguiding properties so that they can be used in the design and fabrication of high-temperature sensors. Through refinements in the processing steps, the quality of the interface between core and cladding of the fibers was improved, which is expected to reduce scattering and attenuation in the fibers.

  6. NEW OPTICAL SENSOR SUITE FOR ULTRAHIGH TEMPERATURE FOSSIL FUEL APPLICATIONS

    SciTech Connect (OSTI)

    Russell G. May; Tony Peng; Tom Flynn

    2004-12-01

    Accomplishments during the Phase I of a program to develop and demonstrate technology for the instrumentation of advanced powerplants are described. Engineers from Prime Research, LC and Babcock and Wilcox Research Center collaborated to generate a list of potential applications for robust photonic sensors in existing and future boiler plants. From that list, three applications were identified as primary candidates for initial development and demonstration of high-temperature sensors in an ultrasupercritical power plant. A matrix of potential fiber optic sensor approaches was derived, and a data set of specifications for high-temperature optical fiber was produced. Several fiber optic sensor configurations, including interferometric (extrinsic and intrinsic Fabry-Perot interferometer), gratings (fiber Bragg gratings and long period gratings), and microbend sensors, were evaluated in the laboratory. In addition, progress was made in the development of materials and methods to apply high-temperature optical claddings to sapphire fibers, in order to improve their optical waveguiding properties so that they can be used in the design and fabrication of high-temperature sensors. Through refinements in the processing steps, the quality of the interface between core and cladding of the fibers was improved, which is expected to reduce scattering and attenuation in the fibers. Numerical aperture measurements of both clad and unclad sapphire fibers were obtained and used to estimate the reduction in mode volume afforded by the cladding. High-temperature sensors based on sapphire fibers were also investigated. The fabrication of an intrinsic Fabry-Perot cavity within sapphire fibers was attempted by the bulk diffusion of magnesium oxide into short localized segments of longer sapphire fibers. Fourier analysis of the fringes that resulted when the treated fiber was interrogated by a swept laser spectrometer suggested that an intrinsic cavity had been formed in the fiber. Also

  7. NREL: Technology Deployment - Fossil Fuel Dependency Falls from 100% to 56%

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on Alcatraz Island Fossil Fuel Dependency Falls from 100% to 56% on Alcatraz Island News Solar Cells Light Up Prison Cells on 'The Rock' Sponsors U.S. National Park Service American Recovery and Reinvestment Act Key Partners National Park Service Golden Gate National Recreation Area National Park Service Denver Services Center Princeton Power Inc. University of Washington Lawrence Berkeley National Laboratory U.S. DOE Federal Energy Management Program Related Stories U.S. Virgin Islands

  8. Reduction of nitrogen oxide emissions from fossil fuels. (Latest citations from Pollution abstracts). Published Search

    SciTech Connect (OSTI)

    1997-05-01

    The bibliography contains citations concerning the removal of nitrogen compounds from fossil fuels and their post-combustion emissions. Removal methods include biological denitrification, fluidized bed combustion, and flue gas denitrification. Applications to utilities, petroleum refineries, and other industries are presented. The design of nitrogen control systems and process optimization are described. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  9. Reduction of nitrogen oxide emissions from fossil fuels. (Latest citations from Pollution abstracts). Published Search

    SciTech Connect (OSTI)

    1996-01-01

    The bibliography contains citations concerning the removal of nitrogen compounds from fossil fuels and their post-combustion emissions. Removal methods include biological denitrification, fluidized bed combustion, and flue gas denitrification. Applications to utilities, petroleum refineries, and other industries are presented. The design of nitrogen control systems and process optimization are described. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  10. September 2013 Most Viewed Documents for Fossil Fuels | OSTI, US Dept of

    Office of Scientific and Technical Information (OSTI)

    Energy Office of Scientific and Technical Information September 2013 Most Viewed Documents for Fossil Fuels EXPERIMENTAL AND THEORETICAL DETERMINATION OF HEAVY OIL VISCOSITY UNDER RESERVOIR CONDITIONS Dr. Jorge Gabitto; Maria Barrufet (2003) 42 Molecular catalytic hydrogenation of aromatic hydrocarbons and hydrotreating of coal liquids. Yang, Shiyong; Stock, L.M. (1996) 36 Fluid Dynamics in Sucker Rod Pumps Cutler, R.P.; Mansure, A.J. (1999) 35 Controlled low strength materials (CLSM),

  11. September 2015 Most Viewed Documents for Fossil Fuels | OSTI, US Dept of

    Office of Scientific and Technical Information (OSTI)

    Energy Office of Scientific and Technical Information September 2015 Most Viewed Documents for Fossil Fuels EXPERIMENTAL AND THEORETICAL DETERMINATION OF HEAVY OIL VISCOSITY UNDER RESERVOIR CONDITIONS Dr. Jorge Gabitto; Maria Barrufet (2003) 141 Decomposition of calcium sulfate: a review of the literature. [62 refs] Swift, W M; Panek, A F; Smith, G W; Vogel, G J; Jonke, A A (1976) 122 Practical hot oiling and hot watering for paraffin control Mansure, A.J. [Sandia National Labs.,

  12. December 2015 Most Viewed Documents for Fossil Fuels | OSTI, US Dept of

    Office of Scientific and Technical Information (OSTI)

    Energy Office of Scientific and Technical Information December 2015 Most Viewed Documents for Fossil Fuels EXPERIMENTAL AND THEORETICAL DETERMINATION OF HEAVY OIL VISCOSITY UNDER RESERVOIR CONDITIONS Dr. Jorge Gabitto; Maria Barrufet (2003) 213 Bamboo: An Overlooked Biomass Resource? Scurlock, J.M.O. (2000) 159 Practical hot oiling and hot watering for paraffin control Mansure, A.J. [Sandia National Labs., Albuquerque, NM (United States)]; Barker, K.M. [Petrolite Corp. (United States)]

  13. July 2013 Most Viewed Documents for Fossil Fuels | OSTI, US Dept of Energy

    Office of Scientific and Technical Information (OSTI)

    Office of Scientific and Technical Information July 2013 Most Viewed Documents for Fossil Fuels EXPERIMENTAL AND THEORETICAL DETERMINATION OF HEAVY OIL VISCOSITY UNDER RESERVOIR CONDITIONS Dr. Jorge Gabitto; Maria Barrufet (2003) 82 Controlled low strength materials (CLSM), reported by ACI Committee 229 Rajendran, N. (1997) 65 Systems and economic analysis of microalgae ponds for conversion of CO{sub 2} to biomass. Final report Benemann, J.R.; Oswald, W.J. (1996) 50 Fluid Dynamics in Sucker

  14. June 2015 Most Viewed Documents for Fossil Fuels | OSTI, US Dept of Energy

    Office of Scientific and Technical Information (OSTI)

    Office of Scientific and Technical Information June 2015 Most Viewed Documents for Fossil Fuels EXPERIMENTAL AND THEORETICAL DETERMINATION OF HEAVY OIL VISCOSITY UNDER RESERVOIR CONDITIONS Dr. Jorge Gabitto; Maria Barrufet (2003) 134 Practical hot oiling and hot watering for paraffin control Mansure, A.J. [Sandia National Labs., Albuquerque, NM (United States)]; Barker, K.M. [Petrolite Corp. (United States)] (1994) 94 Fluid Dynamics in Sucker Rod Pumps Cutler, R.P.; Mansure, A.J. (1999) 92

  15. Most Viewed Documents for Fossil Fuels: December 2014 | OSTI, US Dept of

    Office of Scientific and Technical Information (OSTI)

    Energy Office of Scientific and Technical Information Most Viewed Documents for Fossil Fuels: December 2014 Generalized displacement correlation method for estimating stress intensity factors Fu, P; Johnson, S M; Settgast, R R; Carrigan, C R (2011) 107 EXPERIMENTAL AND THEORETICAL DETERMINATION OF HEAVY OIL VISCOSITY UNDER RESERVOIR CONDITIONS Dr. Jorge Gabitto; Maria Barrufet (2003) 60 DENSE MEDIUM CYCLONE OPTIMIZATON Gerald H. Luttrell; Chris J. Barbee; Peter J. Bethell; Chris J. Wood

  16. Most Viewed Documents for Fossil Fuels: September 2014 | OSTI, US Dept of

    Office of Scientific and Technical Information (OSTI)

    Energy Office of Scientific and Technical Information Most Viewed Documents for Fossil Fuels: September 2014 Generalized displacement correlation method for estimating stress intensity factors Fu, P; Johnson, S M; Settgast, R R; Carrigan, C R (2011) 138 Autothermal Reforming of Natural Gas to Synthesis Gas Steven F. Rice; David P. Mann (2007) 51 Avian Collisions with Wind Turbines: A Summary of Existing Studies and Comparisons to Other Sources of Avian Collision Mortality in the United

  17. Innovative Fresh Water Production Process for Fossil Fuel Plants

    SciTech Connect (OSTI)

    James F. Klausner; Renwei Mei; Yi Li; Jessica Knight; Venugopal Jogi

    2005-09-01

    This project concerns a diffusion driven desalination (DDD) process where warm water is evaporated into a low humidity air stream, and the vapor is condensed out to produce distilled water. Although the process has a low fresh water to feed water conversion efficiency, it has been demonstrated that this process can potentially produce low cost distilled water when driven by low grade waste heat. This report describes the annual progress made in the development and analysis of a Diffusion Driven Desalination (DDD) system. A dynamic analysis of heat and mass transfer demonstrates that the DDD process can yield a fresh water production of 1.03 million gallon/day by utilizing waste heat from a 100 MW steam power plant based on a condensing steam pressure of only 3 Hg. The optimum operating condition for the DDD process with a high temperature of 50 C and sink temperature of 25 C has an air mass flux of 1.5 kg/m{sup 2}-s, air to feed water mass flow ratio of 1 in the diffusion tower, and a fresh water to air mass flow ratio of 2 in the condenser. Operating at these conditions yields a fresh water production efficiency (m{sub fW}/m{sub L}) of 0.031 and electric energy consumption rate of 0.0023 kW-hr/kg{sub fW}. Throughout the past year, the main focus of the desalination process has been on the direct contact condenser. Detailed heat and mass transfer analyses required to size and analyze these heat and mass transfer devices are described. The analyses agree quite well with the current data. Recently, it has been recognized that the fresh water production efficiency can be significantly enhanced with air heating. This type of configuration is well suited for power plants utilizing air-cooled condensers. The experimental DDD facility has been modified with an air heating section, and temperature and humidity data have been collected over a range of flow and thermal conditions. It has been experimentally observed that the fresh water production rate is enhanced when air

  18. Innovative Fresh Water Production Process for Fossil Fuel Plants

    SciTech Connect (OSTI)

    James F. Klausner; Renwei Mei; Yi Li; Jessica Knight

    2006-09-29

    This project concerns a diffusion driven desalination (DDD) process where warm water is evaporated into a low humidity air stream, and the vapor is condensed out to produce distilled water. Although the process has a low fresh water to feed water conversion efficiency, it has been demonstrated that this process can potentially produce low cost distilled water when driven by low grade waste heat. This report summarizes the progress made in the development and analysis of a Diffusion Driven Desalination (DDD) system. Detailed heat and mass transfer analyses required to size and analyze the diffusion tower using a heated water input are described. The analyses agree quite well with the current data and the information available in the literature. The direct contact condenser has also been thoroughly analyzed and the system performance at optimal operating conditions has been considered using a heated water/ambient air input to the diffusion tower. The diffusion tower has also been analyzed using a heated air input. The DDD laboratory facility has successfully been modified to include an air heating section. Experiments have been conducted over a range of parameters for two different cases: heated air/heated water and heated air/ambient water. A theoretical heat and mass transfer model has been examined for both of these cases and agreement between the experimental and theoretical data is good. A parametric study reveals that for every liquid mass flux there is an air mass flux value where the diffusion tower energy consumption is minimal and an air mass flux where the fresh water production flux is maximized. A study was also performed to compare the DDD process with different inlet operating conditions as well as different packing. It is shown that the heated air/heated water case is more capable of greater fresh water production with the same energy consumption than the ambient air/heated water process at high liquid mass flux. It is also shown that there can be

  19. EPRI-DOE Joint Report on Fossil Fleet Transition with Fuel Changes and Large Scale Variable Renewable Integration Now Available

    Broader source: Energy.gov [DOE]

    A new report “Fossil Fleet Transition with Fuel Changes and Large Scale Variable Renewable Integration” from the Electric Power Research Institute (EPRI) and jointly funded by the Offices of...

  20. Development of Nuclear Renewable Oil Shale Systems for Flexible Electricity and Reduced Fossil Fuel Emissions

    SciTech Connect (OSTI)

    Daniel Curtis; Charles Forsberg; Humberto Garcia

    2015-05-01

    We propose the development of Nuclear Renewable Oil Shale Systems (NROSS) in northern Europe, China, and the western United States to provide large supplies of flexible, dispatchable, very-low-carbon electricity and fossil fuel production with reduced CO2 emissions. NROSS are a class of large hybrid energy systems in which base-load nuclear reactors provide the primary energy used to produce shale oil from kerogen deposits and simultaneously provide flexible, dispatchable, very-low-carbon electricity to the grid. Kerogen is solid organic matter trapped in sedimentary shale, and large reserves of this resource, called oil shale, are found in northern Europe, China, and the western United States. NROSS couples electricity generation and transportation fuel production in a single operation, reduces lifecycle carbon emissions from the fuel produced, improves revenue for the nuclear plant, and enables a major shift toward a very-low-carbon electricity grid. NROSS will require a significant development effort in the United States, where kerogen resources have never been developed on a large scale. In Europe, however, nuclear plants have been used for process heat delivery (district heating), and kerogen use is familiar in certain countries. Europe, China, and the United States all have the opportunity to use large scale NROSS development to enable major growth in renewable generation and either substantially reduce or eliminate their dependence on foreign fossil fuel supplies, accelerating their transitions to cleaner, more efficient, and more reliable energy systems.

  1. Long-term tradeoffs between nuclear- and fossil-fuel burning

    SciTech Connect (OSTI)

    Krakowski, R.A.

    1996-12-31

    A global energy/economics/environmental (E{sup 3}) model has been adapted with a nuclear energy/materials model to understand better {open_quotes}top-level{close_quotes}, long-term trade offs between civilian nuclear power, nuclear-weapons proliferation, fossil-fuel burning, and global economic welfare. Using a {open_quotes}business-as-usual{close_quotes} (BAU) point-of-departure case, economic, resource, proliferation-risk implications of plutonium recycle in LAIRs, greenhouse-gas-mitigating carbon taxes, and a range of nuclear energy costs (capital and fuel) considerations have been examined. After describing the essential elements of the analysis approach being developed to support the Los Alamos Nuclear Vision Project, preliminary examples of parametric variations about the BAU base-case scenario are presented. The results described herein represent a sampling from more extensive results collected in a separate report. The primary motivation here is: (a) to compare the BAU basecase with results from other studies; (b) to model on a regionally resolved global basis long-term (to year {approximately}2100) evolution of plutonium accumulation in a variety of forms under a limited range of fuel-cycle scenarios; and (c) to illustrate a preliminary connectivity between risks associated with nuclear proliferation and fossil-fuel burning (e.g., greenhouse-gas accumulations).

  2. Energy-efficient air pollution controls for fossil-fueled plants: Technology assessment

    SciTech Connect (OSTI)

    Sayer, J.H.

    1995-06-01

    The 1990 Clean Air Act Amendments require most fossil-fuel fired power plants to reduce sulfur dioxide, nitrogen oxides, and particulate emissions. While emission-control equipment is available to help most of New York State`s 91 utility units in 31 power plants comply with the new regulations, technologies currently available consume energy, increase carbon dioxide emissions, reduce operating efficiency, and may produce large amounts of solid and/or semisolid byproducts that use additional energy for processing and disposal. This report discribes several pollution-control technologies that are more energy efficient compared to traditional technologies for controlling sulfur dioxide, nitrogen oxide, and particulates, that may have application in New York State. These technologies are either in commercial use, under development, or in the demonstration phase; This report also presents operating characteristics for these technologies and discusses solutions to dispose of pollution-control system byproducts. Estimated energy consumption for emission-control systems relative to a plant`s gross generating capacity is 3 to 5 for reducing up to 90% sulfur dioxide emissions from coal-fired plants. 0.5 to 2.5% for reducing nitrogen oxide emissions by up to 80% from all fossil-fuel fired plants; and 0.5 to 1.5 % for controlling particulate emissions from oil- and coal-fired plants. While fuel switching and/or cofiring with natural gas are options to reduce emissions, these techniques are not considered in this report; the discussion is limited to fossil-fueled steam-generating plants.

  3. Reduced carbon emission estimates from fossil fuel combustion and cement production in China

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Z.; Guan, D.; Wei, W.; Davis, S.; Ciais, P.; Bai, J; Peng, S.; Zhang, Q.; Hubacek, K.; Marland, Gregg; et al

    2015-08-19

    Nearly three-quarters of the growth in global carbon emissions from the burning of fossil fuels and cement production between 2010 and 2012 occurred in China. Yet estimates of Chinese emissions remain subject to large uncertainty; inventories of China’s total fossil fuel carbon emissions in 2008 differ by 0.3 gigatonnes of carbon, or 15 per cent. The primary sources of this uncertainty are conflicting estimates of energy consumption and emission factors, the latter being uncertain because of very few actual measurements representative of the mix of Chinese fuels. Here we re-evaluate China’s carbon emissions using updated and harmonized energy consumption andmore » clinker production data and two new and comprehensive sets of measured emission factors for Chinese coal. We find that total energy consumption in China was 10 per cent higher in 2000–2012 than the value reported by China’s national statistics, that emission factors for Chinese coal are on average 40 per cent lower than the default values recommended by the Intergovernmental Panel on Climate Change, and that emissions from China’s cement production are 45 per cent less than recent estimates. Altogether, our revised estimate of China’s CO2 emissions from fossil fuel combustion and cement production is 2.49 gigatonnes of carbon (2 standard deviations = ±7.3 per cent) in 2013, which is 14 per cent lower than the emissions reported by other prominent inventories. Over the full period 2000 to 2013, our revised estimates are 2.9 gigatonnes of carbon less than previous estimates of China’s cumulative carbon emissions. Our findings suggest that overestimation of China’s emissions in 2000–2013 may be larger than China’s estimated total forest sink in 1990–2007 (2.66 gigatonnes of carbon) or China’s land carbon sink in 2000–2009 (2.6 gigatonnes of carbon).« less

  4. Reduced carbon emission estimates from fossil fuel combustion and cement production in China

    SciTech Connect (OSTI)

    Liu, Z.; Guan, D.; Wei, W.; Davis, S.; Ciais, P.; Bai, J; Peng, S.; Zhang, Q.; Hubacek, K.; Marland, Gregg; Andres, Robert Joseph; Crawford-Brown, D.; Lin, J.; Zhao, H.; Hong, C.; Boden, Thomas A.; Feng, K.; Peters, Glen P.; Xi, F.; Liu, J.; Li, Y.; Zhao, Y.; Zeng, Ning; He, K.

    2015-08-19

    Nearly three-quarters of the growth in global carbon emissions from the burning of fossil fuels and cement production between 2010 and 2012 occurred in China. Yet estimates of Chinese emissions remain subject to large uncertainty; inventories of China’s total fossil fuel carbon emissions in 2008 differ by 0.3 gigatonnes of carbon, or 15 per cent. The primary sources of this uncertainty are conflicting estimates of energy consumption and emission factors, the latter being uncertain because of very few actual measurements representative of the mix of Chinese fuels. Here we re-evaluate China’s carbon emissions using updated and harmonized energy consumption and clinker production data and two new and comprehensive sets of measured emission factors for Chinese coal. We find that total energy consumption in China was 10 per cent higher in 2000–2012 than the value reported by China’s national statistics, that emission factors for Chinese coal are on average 40 per cent lower than the default values recommended by the Intergovernmental Panel on Climate Change, and that emissions from China’s cement production are 45 per cent less than recent estimates. Altogether, our revised estimate of China’s CO2 emissions from fossil fuel combustion and cement production is 2.49 gigatonnes of carbon (2 standard deviations = ±7.3 per cent) in 2013, which is 14 per cent lower than the emissions reported by other prominent inventories. Over the full period 2000 to 2013, our revised estimates are 2.9 gigatonnes of carbon less than previous estimates of China’s cumulative carbon emissions. Our findings suggest that overestimation of China’s emissions in 2000–2013 may be larger than China’s estimated total forest sink in 1990–2007 (2.66 gigatonnes of carbon) or China’s land carbon sink in 2000–2009 (2.6 gigatonnes of carbon).

  5. Toward Verifying Fossil Fuel CO2 Emissions with the CMAQ Model: Motivation, Model Description and Initial Simulation

    SciTech Connect (OSTI)

    Liu, Zhen; Bambha, Ray P.; Pinto, Joseph P.; Zeng, Tao; Boylan, Jim; Huang, Maoyi; Lei, Huimin; Zhao, Chun; Liu, Shishi; Mao, Jiafu; Schwalm, Christopher R.; Shi, Xiaoying; Wei, Yaxing; Michelsen, Hope A.

    2014-03-14

    Motivated by the urgent need for emission verification of CO2 and other greenhouse gases, we have developed regional CO2 simulation with CMAQ over the contiguous U.S. Model sensitivity experiments have been performed using three different sets of inputs for net ecosystem exchange (NEE) and two fossil fuel emission inventories, to understand the roles of fossil fuel emissions, atmosphere-biosphere exchange and transport in regulating the spatial and diurnal variability of CO2 near the surface, and to characterize the well-known signal-to-noise problem, i.e. the interference from the biosphere on the interpretation of atmospheric CO2 observations. It is found that differences in the meteorological conditions for different urban areas strongly contribute to the contrast in concentrations. The uncertainty of NEE, as measured by the difference among the three different NEE inputs, has notable impact on regional distribution of CO2 simulated by CMAQ. Larger NEE uncertainty and impact are found over eastern U.S. urban areas than along the western coast. A comparison with tower CO2 measurements at Boulder Atmospheric Observatory (BAO) shows that the CMAQ model using hourly varied and high-resolution CO2 emission from the Vulcan inventory and CarbonTracker optimized NEE reasonably reproduce the observed diurnal profile, whereas switching to different NEE inputs significantly degrades the model performance. Spatial distribution of CO2 is found to correlate with NOx, SO2 and CO, due to their similarity in emission sources and transport processes. These initial results from CMAQ demonstrate the power of a state-of-the art CTM in helping interpret CO2 observations and verify fossil fuel emissions. The ability to simulate CO2 in CMAQ will also facilitate investigations of the utility of traditionally regulated pollutants and other species as tracers to CO2 source attribution.

  6. Comparison of AB2588 multipathway risk factors for California fossil-fuel power stations

    SciTech Connect (OSTI)

    Gratt, L.B.; Levin, L.

    1997-12-31

    Substances released from power plants may travel through various exposure pathways resulting in human health and environmental risks. The stack air emission`s primary pathway is inhalation from the ambient air. Multipathway factors (adjustment factors to the inhalation risk) are used to evaluate the importance of non-inhalation pathways (such as ingestion and dermal contact). The multipathway factor for a specific substance is the health risk by all pathways divided by the inhalation health risk for that substance. These factors are compared for fossil fuel power stations that submitted regulatory risk assessments in compliance with California Toxic Hot Spots Act (AB2588). Substances representing the largest contributions to the cancer risk are of primary concern: arsenic, beryllium, cadmium, chromium (+6), formaldehyde, nickel, lead, selenium, and PAHs. Comparisons of the chemical-specific multipathway factors show the impacts of regulatory policy decisions on the estimated health risk for trace substances. As an example, point estimates of the soil mixing depth, varying from 1 cm to 15 cm, relate to the relative importance of the pathway. For the deeper mixing depths, the root-zone uptake by homegrown tomato plants (for assumed consumption rate of 15% for San Diego) may result in high multipathway factors for several trace metals. For shallower mixing depths, soil ingestion may become the dominant non-inhalation pathway. These differences may lead to significantly different risk estimates for similar facilities located at different California locations such as to be under local regulatory authorities. The overall multipathway factor for the total cancer risk is about 2, much smaller than some of the chemical-specific factors. Science-based multipathway analysis should reduce much of the concern that may be due to policy-based decisions on pathway selection and high-value point-estimates of the parameters.

  7. Historic Patterns of CO{sub 2} Emissions from Fossil Fuels: Implications for Stabilization of Emissions

    DOE R&D Accomplishments [OSTI]

    Andres, R. J.; Marland, G.

    1994-06-01

    This paper examines the historical record of greenhouse gas emissions since 1950, reviews the prospects for emissions into the future, and projects what would be the short-term outcome if the stated targets of the FCCC were in fact achieved. The examination focuses on the most important of the greenhouse gases, CO{sub 2}. The extensive record of historic CO{sub 2} emissions is explored to ascertain if it is an adequate basis for useful extrapolation into the near future. Global carbon dioxide emissions from fossil fuel consumption have been documented. Emissions grew at 4.3% per year from 1950 until the time of the 1973 oil crisis. Another disruption in growth followed the oil price increases of 1979. Global total emissions have been increasing steadily since the 1982-1983 minimum and have grown by more than 20% since then. At present, emission Of CO{sub 2} from fossil fuel burning is dominated by a few countries: the U.S., the former Soviet Union, China, the developed countries of Europe and Japan. Only 20 countries emit 84% of emissions from all countries. However, rates of growth in many of the developed countries are now very low. In contrast, energy use has grown rapidly over the last 20 years in some of the large, developing economies. Emissions from fossil fuel consumption are now nearly 4 times those from land use change and are the primary cause of measured increases in the atmospheric concentration of CO{sub 2}. The increasing concentration of atmospheric CO{sub 2} has led to rising concern about the possibility of impending changes in the global climate system. In an effort to limit or mitigate potential negative effects of global climate change, 154 countries signed the United Nations Framework Convention on Climate Change (FCCC) in Rio de Janeiro in June, 1992. The FCCC asks all countries to conduct an inventory of their current greenhouse gas emissions setting non-binding targets.

  8. Table 1.15 Non-Combustion Use of Fossil Fuels, 1980-2011

    U.S. Energy Information Administration (EIA) Indexed Site

    5 Non-Combustion Use of Fossil Fuels, 1980-2011 Year Petroleum Products Natural Gas 4 Coal Total Percent of Total Energy Consumption Asphalt and Road Oil Liquefied Petroleum Gases 1 Lubricants Petro- chemical Feedstocks 2 Petroleum Coke Special Naphthas Other 3 Total Physical Units 5<//td> 1980 145 230 58 253 14 [R] 37 58 795 [R] 639 2.4 [ – –] [ – –] 1981 125 229 56 216 15 [R] 27 54 722 [R] 518 [R] 2.1 [ – –] [ – –] 1982 125 256 51 157 15 [R] 25 48 678 [R] 448 [R] 1.4 [ – –] [

  9. Liquid fossil-fuel technology. Quarterly technical progress report, January-March 1983

    SciTech Connect (OSTI)

    Linville, B.

    1983-07-01

    Accomplishments for the quarter ending March 1983 are presented under the following headings: liquid fossil fuel cycle, processing, utilization, and project integration and technology transfer. Feature articles for this quarter are: (1) abandoned oil field reports issued; (2) oilfield water data bank report published; (3) microbial enhanced recovery report issued; (4) polymer-augmented project could be economic today; (5) carbon dioxide EOR estimates given; (6) BETC passes 65th milestone; and (7) fifty achievements for fifty years (1918-1968). BETC publications are also listed. (ATT)

  10. Comparative analysis of monetary estimates of external environmental costs associated with combustion of fossil fuels

    SciTech Connect (OSTI)

    Koomey, J.

    1990-07-01

    Public utility commissions in a number of states have begun to explicitly treat costs of environmental externalities in the resource planning and acquisition process (Cohen et al. 1990). This paper compares ten different estimates and regulatory determinations of external environmental costs associated with fossil fuel combustion, using consistent assumptions about combustion efficiency, emissions factors, and resource costs. This consistent comparison is useful because it makes explicit the effects of various assumptions. This paper uses the results of the comparison to illustrate pitfalls in calculation of external environmental costs, and to derive lessons for design of policies to incorporate these externalities into resource planning. 38 refs., 2 figs., 10 tabs.

  11. Evaluation of innovative fossil fuel power plants with CO{sub 2} removal

    SciTech Connect (OSTI)

    2000-07-15

    This interim report presents initial results of an ongoing study of the potential cost of electricity produced in both conventional and innovative fossil fueled power plants that incorporate carbon dioxide (CO{sub 2}) removal for subsequent sequestration or use. The baseline cases are natural gas combined cycle (NGCC) and ultra-supercritical pulverized coal (PC) plants, with and without post combustion CO{sub 2} removal, and integrated gasification combined cycle (IGCC) plants, with and without pre-combustion CO{sub 2} removal.

  12. Comparison of emissions from landfills, municipal waste combustors, and fossil fuel-fired utilities

    SciTech Connect (OSTI)

    1996-11-01

    Landfilling is the most popular disposal method for managing municipal solid waste (MSW). However, air emissions from MSW landfills have generally been unregulated until recently. Instead, EPA has focused on emissions from municipal waste combustors (MWCs), even though they only manage 15% of MSW generated in the United States. In the past, little data have been available comparing landfill and MWC air emissions. Such information is provided by this paper. It also compares emissions from waste-to-energy MWCs and fossil fuel-fired utilities with equivalent electrical generation capacity. 1 refs., 6 tabs.

  13. USVI Makes Headway Toward Goal to Reduce Fossil Fuel 60% by 2025

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oil prices spike to over $145/ barrel and price of electricity exceeds $0.50/kWh in U.S. Virgin Islands (USVI) USVI announces goal to reduce fossil fuel use 60% by 2025 In 3rd most active hurricane season on record, Earl hits USVI Virgin Islands Energy O ce (VIEO) launches Sun Power Loan Program WAPA installs waste heat recovery plant, adding 19 MW of power without burning a single drop of additional oil VIEO awards nearly $1 million to USVI nonpro ts for energy e ciency and renewable energy

  14. Impacts of Wind and Solar on Fossil-Fueled Generators: Preprint

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Impacts of Wind and Solar on Fossil-Fueled Generators Preprint D. Lew and G. Brinkman National Renewable Energy Laboratory N. Kumar, P. Besuner, D. Agan, and S. Lefton Intertek APTECH Presented at IEEE Power and Energy Society General Meeting San Diego, California July 22-26, 2012 Conference Paper NREL/CP-5500-53504 August 2012 NOTICE The submitted manuscript has been offered by an employee of the Alliance for Sustainable Energy, LLC (Alliance), a contractor of the US Government under

  15. June 2016 Most Viewed Documents for Fossil Fuels | OSTI, US Dept of Energy

    Office of Scientific and Technical Information (OSTI)

    Office of Scientific and Technical Information Fossil Fuels Solubility of methane in water under natural conditions: a laboratory study. Final report, April 1, 1978-June 30, 1982 Blount, C.W.; Price, L.C. (1982) 201 Bamboo: An Overlooked Biomass Resource? Scurlock, J.M.O. (2000) 166 Comparative safety analysis of LNG storage tanks Fecht, B.A.; Gates, T.E.; Nelson, K.O.; Marr, G.D. (1982) 164 EXPERIMENTAL AND THEORETICAL DETERMINATION OF HEAVY OIL VISCOSITY UNDER RESERVOIR CONDITIONS Dr.

  16. June 2014 Most Viewed Documents for Fossil Fuels | OSTI, US Dept of Energy

    Office of Scientific and Technical Information (OSTI)

    Office of Scientific and Technical Information June 2014 Most Viewed Documents for Fossil Fuels Generalized displacement correlation method for estimating stress intensity factors Fu, P; Johnson, S M; Settgast, R R; Carrigan, C R (2011) 95 Evaluation of 2004 Toyota Prius Hybrid Electric Drive System Staunton, R.H.; Ayers, C.W.; Chiasson, J.N. (U Tennessee-Knoxville); Burress, B.A. (ORISE); Marlino, L.D. (2006) 63 Systems and economic analysis of microalgae ponds for conversion of CO{sub 2}

  17. March 2014 Most Viewed Documents for Fossil Fuels | OSTI, US Dept of Energy

    Office of Scientific and Technical Information (OSTI)

    Office of Scientific and Technical Information March 2014 Most Viewed Documents for Fossil Fuels Systems and economic analysis of microalgae ponds for conversion of CO{sub 2} to biomass. Final report Benemann, J.R.; Oswald, W.J. (1996) 65 Avian Collisions with Wind Turbines: A Summary of Existing Studies and Comparisons to Other Sources of Avian Collision Mortality in the United States Wallace P. Erickson, Gregory D. Johnson, M. Dale Strickland, David P. Young, Jr., Karyn J. Sernka, Rhett E.

  18. March 2015 Most Viewed Documents for Fossil Fuels | OSTI, US Dept of Energy

    Office of Scientific and Technical Information (OSTI)

    Office of Scientific and Technical Information 5 Most Viewed Documents for Fossil Fuels EXPERIMENTAL AND THEORETICAL DETERMINATION OF HEAVY OIL VISCOSITY UNDER RESERVOIR CONDITIONS Dr. Jorge Gabitto; Maria Barrufet (2003) 184 A kinetic study of methanol synthesis in a slurry reactor using a CuO/ZnO/Al sub 2 O sub 3 catalyst Al-Adwani, H.A. (1992) 97 Practical hot oiling and hot watering for paraffin control Mansure, A.J. [Sandia National Labs., Albuquerque, NM (United States)]; Barker, K.M.

  19. FutureGen: Stepping-Stone to Sustainable Fossil-Fuel Power Generation

    SciTech Connect (OSTI)

    Zitney, S.E.

    2006-11-01

    This presentation will highlight the U.S. Department of Energy's FutureGen Initiative. The nearly $1 billion government-industry project is a stepping-stone toward future coal-fired power plants that will produce hydrogen and electricity with zero-emissions, including carbon dioxide. The 275-megawatt FutureGen plant will initiate operations around 2012 and employ advanced coal gasification technology integrated with combined cycle electricity generation, hydrogen production, and carbon capture and sequestration. The initiative is a response to a presidential directive to develop a hydrogen economy by drawing upon the best scientific research to address the issue of global climate change. The FutureGen plant will be based on cutting-edge power generation technology as well as advanced carbon capture and sequestration systems. The centerpiece of the project will be coal gasification technology that can eliminate common air pollutants such as sulfur dioxide and nitrogen oxides and convert them to useable by-products. Gasification will convert coal into a highly enriched hydrogen gas, which can be burned much more cleanly than directly burning the coal itself. Alternatively, the hydrogen can be used in a fuel cell to produce ultra-clean electricity, or fed to a refinery to help upgrade petroleum products. Carbon sequestration will also be a key feature that will set the Futuregen plant apart from other electric power plant projects. The initial goal will be to capture 90 percent of the plant's carbon dioxide, but capture of nearly 100 percent may be possible with advanced technologies. Once captured, the carbon dioxide will be injected as a compressed fluid deep underground, perhaps into saline reservoirs. It could even be injected into oil or gas reservoirs, or into unmineable coal seams, to enhance petroleum or coalbed methane recovery. The ultimate goal for the FutureGen plant is to show how new technology can eliminate environmental concerns over the future use of

  20. A brief overview of Chinese Design Code on Fossil-Fueled Power Plants

    SciTech Connect (OSTI)

    Xu Zhongqing; He Yehong

    1996-10-01

    The Chinese Design Code on Fossil Fueled Power Plants (DL 5000-94) was issued in April 1994 by the Ministry of Electric Power Industry, P.R. China, and the English version has been drafted and will be formally published in the near future. Based on the 1984 version and the nation`s current policies, the 1994 version was formed to meet the challenges of the nation`s speedy development of electric power construction. In general, the code is primarily a directive document guiding the planning and engineering of China`s large- and medium-sized fossil-fueled power plants. The preparation of the 1984 version and the revision of it to the 1994 version were all carried out by the East China Electric Power Design Institute under the direction of Electric Power Planning and Engineering Institute. For small-sized power plants with unit rating of 25 MW and below, there is another national design code titled Code for Design of Small Sized Power Plants (GB 50049-94) issued in November 1994 jointly by the China`s National Technology Supervision Administration and the Ministry of Construction.

  1. Fossil Energy | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fossil Energy Fossil Energy Below are resources for Tribes on fossil energy. Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2011 This paper...

  2. Linear regression analysis of emissions factors when firing fossil fuels and biofuels in a commercial water-tube boiler

    SciTech Connect (OSTI)

    Sharon Falcone Miller; Bruce G. Miller

    2007-12-15

    This paper compares the emissions factors for a suite of liquid biofuels (three animal fats, waste restaurant grease, pressed soybean oil, and a biodiesel produced from soybean oil) and four fossil fuels (i.e., natural gas, No. 2 fuel oil, No. 6 fuel oil, and pulverized coal) in Penn State's commercial water-tube boiler to assess their viability as fuels for green heat applications. The data were broken into two subsets, i.e., fossil fuels and biofuels. The regression model for the liquid biofuels (as a subset) did not perform well for all of the gases. In addition, the coefficient in the models showed the EPA method underestimating CO and NOx emissions. No relation could be studied for SO{sub 2} for the liquid biofuels as they contain no sulfur; however, the model showed a good relationship between the two methods for SO{sub 2} in the fossil fuels. AP-42 emissions factors for the fossil fuels were also compared to the mass balance emissions factors and EPA CFR Title 40 emissions factors. Overall, the AP-42 emissions factors for the fossil fuels did not compare well with the mass balance emissions factors or the EPA CFR Title 40 emissions factors. Regression analysis of the AP-42, EPA, and mass balance emissions factors for the fossil fuels showed a significant relationship only for CO{sub 2} and SO{sub 2}. However, the regression models underestimate the SO{sub 2} emissions by 33%. These tests illustrate the importance in performing material balances around boilers to obtain the most accurate emissions levels, especially when dealing with biofuels. The EPA emissions factors were very good at predicting the mass balance emissions factors for the fossil fuels and to a lesser degree the biofuels. While the AP-42 emissions factors and EPA CFR Title 40 emissions factors are easier to perform, especially in large, full-scale systems, this study illustrated the shortcomings of estimation techniques. 23 refs., 3 figs., 8 tabs.

  3. ROSE-based compact simulator for fossil fuel-fired power plant

    SciTech Connect (OSTI)

    Dana, H.; Burelle, R.

    1996-11-01

    Nuclear simulators specifications typically ask for {open_quotes}high fidelity full scope replica simulator{close_quotes}. This request is not only the norm but also mandatory due to the strict regulations and safety concerns in that industry. It is an unquestionable fact that these types of simulators do provide the most realistic and effective environment to train control room operators in normal, abnormal operations, and especially in emergency conditions which would be difficult to rehearse otherwise. Utilities in the fossil industry who could afford the price that these top of the line simulators demand would not hesitate long to acquire one. Fortunately for the others, this industry has the luxury to be more flexible in its simulator`s needs which permits utilities to select a simulator within their specific budget. They may chose from a wide range of different types of simulators, including full scope or partial scope, high fidelity or generic, hardware control rooms replicas or CRT-based graphical emulations. In all cases, a simulator must be economically beneficial to plant operations to justify its cost. Taking into account the distinctive requirements of the fossil industry, including their budget constraints, CAE used its vast experience in nuclear simulators to produce a user-friendly, CRT-based compact fossil simulator, using ROSE (Real-time Object-oriented Software Environment). This paper describes the specifics and characteristics of the ROSE-base compact simulator.

  4. Small Scale SOFC Demonstration Using Bio-Based and Fossil Fuels

    SciTech Connect (OSTI)

    Petrik, Michael; Ruhl, Robert

    2012-05-01

    Technology Management, Inc. (TMI) of Cleveland, Ohio, has completed the project entitled Small Scale SOFC Demonstration using Bio-based and Fossil Fuels. Under this program, two 1-kW systems were engineered as technology demonstrators of an advanced technology that can operate on either traditional hydrocarbon fuels or renewable biofuels. The systems were demonstrated at Patterson's Fruit Farm of Chesterland, OH and were open to the public during the first quarter of 2012. As a result of the demonstration, TMI received quantitative feedback on operation of the systems as well as qualitative assessments from customers. Based on the test results, TMI believes that > 30% net electrical efficiency at 1 kW on both traditional and renewable fuels with a reasonable entry price is obtainable. The demonstration and analysis provide the confidence that a 1 kW entry-level system offers a viable value proposition, but additional modifications are warranted to reduce sound and increase reliability before full commercial acceptance.

  5. Table 3.7 Value of Fossil Fuel Imports, 1949-2011 (Thousand Dollars)

    U.S. Energy Information Administration (EIA) Indexed Site

    7 Value of Fossil Fuel Imports, 1949-2011 (Thousand Dollars) Year Coal Coal Coke Natural Gas Crude Oil 1 Petroleum Products 2 Total Nominal 3 Real 4 Nominal 3 Real 4 Nominal 3 Real 4 Nominal 3 Real 4 Nominal 3 Real 4 Nominal 3 Real 4 1949 2,368 16,332 [R] 3,976 27,423 [R] 0 0 304,658 2,101,235 [R] 137,130 945,789 [R] 448,132 3,090,779 [R] 1950 2,624 17,904 [R] 5,297 36,142 [R] 0 0 369,208 2,519,159 [R] 214,629 1,464,445 [R] 591,758 4,037,650 [R] 1951 2,420 15,402 [R] 1,932 12,296 [R] 0 0 374,869

  6. Table 3.8 Value of Fossil Fuel Exports, 1949-2011 (Thousand Dollars)

    U.S. Energy Information Administration (EIA) Indexed Site

    8 Value of Fossil Fuel Exports, 1949-2011 (Thousand Dollars) Year Coal Coal Coke Natural Gas Crude Oil Petroleum Products 1 Total Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 1949 297,179 2,049,652 [R] 8,323 57,404 [R] 1,823 12,573 [R] 98,425 678,840 [R] 461,439 3,182,557 [R] 867,189 5,981,026 [R] 1950 269,195 1,836,756 [R] 6,159 42,024 [R] 3,199 21,827 [R] 102,717 700,853 [R] 394,434 2,691,280 [R] 775,704 5,292,740 [R] 1951 586,056

  7. Table 3.9 Value of Fossil Fuel Net Imports, 1949-2011 (Thousand Dollars)

    U.S. Energy Information Administration (EIA) Indexed Site

    9 Value of Fossil Fuel Net Imports, 1949-2011 (Thousand Dollars) Year Coal Coal Coke Natural Gas Crude Oil Petroleum Products 1 Total Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 Nominal 2 Real 3 1949 -294,811 -2,033,320 [R] -4,347 -29,981 [R] -1,823 -12,573 [R] 206,233 1,422,395 [R] -324,309 -2,236,768 [R] -419,057 -2,890,248 [R] 1950 -266,571 -1,818,852 [R] -862 -5,882 [R] -3,199 -21,827 [R] 266,491 1,818,306 [R] -179,805 -1,226,835 [R] -183,946

  8. Integrated capture of fossil fuel gas pollutants including CO.sub.2 with energy recovery

    DOE Patents [OSTI]

    Ochs, Thomas L.; Summers, Cathy A.; Gerdemann, Steve; Oryshchyn, Danylo B.; Turner, Paul; Patrick, Brian R.

    2011-10-18

    A method of reducing pollutants exhausted into the atmosphere from the combustion of fossil fuels. The disclosed process removes nitrogen from air for combustion, separates the solid combustion products from the gases and vapors and can capture the entire vapor/gas stream for sequestration leaving near-zero emissions. The invention produces up to three captured material streams. The first stream is contaminant-laden water containing SO.sub.x, residual NO.sub.x particulates and particulate-bound Hg and other trace contaminants. The second stream can be a low-volume flue gas stream containing N.sub.2 and O.sub.2 if CO2 purification is needed. The final product stream is a mixture comprising predominantly CO.sub.2 with smaller amounts of H.sub.2O, Ar, N.sub.2, O.sub.2, SO.sub.X, NO.sub.X, Hg, and other trace gases.

  9. Sales of Fossil Fuels Produced from Federal and Indian Lands, FY 2003 through FY 2014

    U.S. Energy Information Administration (EIA) Indexed Site

    8 Table 7. Sales of fossil fuel production from federal and Indian lands by state/area, FY 2003-14 trillion Btu State 2003 2004 2005 2006 2007 2008 2009 2010 2011 2012 2013 2014 Alabama 75 57 51 47 40 42 60 88 86 71 46 29 Alaska 61 66 68 52 32 28 27 23 21 19 18 21 Arizona 258 273 280 193 180 162 157 154 164 163 167 158 Arkansas 7 8 10 10 10 11 15 18 14 13 11 11 California 141 125 124 139 146 129 116 115 121 125 121 119 Colorado 785 842 960 906 905 931 846 868 917 952 875 877 Florida 0 - - - - -

  10. Device for separating CO2 from fossil-fueled power plant emissions

    DOE Patents [OSTI]

    Burchell, Timothy D [Oak Ridge, TN; Judkins, Roddie R [Knoxville, TN; Wilson, Kirk A [Knoxville, TN

    2002-04-23

    A gas separation device includes an inner conduit, and a concentric outer conduit. An electrically conductive filter media, preferably a carbon fiber composite molecular sieve, is provided in the annular space between the inner conduit and the outer conduit. Gas flows through the inner conduit and the annular space between the inner conduit and the outer conduit, so as to contact the filter media. The filter media preferentially adsorbs at least one constituent of the gas stream. The filter media is regenerated by causing an electric current to flow through the filter media. The inner conduit and outer conduit are preferably electrically conductive whereby the regeneration of the filter media can be electrically stimulated. The invention is particularly useful for the removal of CO.sub.2 from the exhaust gases of fossil-fueled power plants.

  11. sparse-msrf:A package for sparse modeling and estimation of fossil-fuel CO2 emission fields

    SciTech Connect (OSTI)

    2014-10-06

    The software is used to fit models of emission fields (e.g., fossil-fuel CO2 emissions) to sparse measurements of gaseous concentrations. Its primary aim is to provide an implementation and a demonstration for the algorithms and models developed in J. Ray, V. Yadav, A. M. Michalak, B. van Bloemen Waanders and S. A. McKenna, "A multiresolution spatial parameterization for the estimation of fossil-fuel carbon dioxide emissions via atmospheric inversions", accepted, Geoscientific Model Development, 2014. The software can be used to estimate emissions of non-reactive gases such as fossil-fuel CO2, methane etc. The software uses a proxy of the emission field being estimated (e.g., for fossil-fuel CO2, a population density map is a good proxy) to construct a wavelet model for the emission field. It then uses a shrinkage regression algorithm called Stagewise Orthogonal Matching Pursuit (StOMP) to fit the wavelet model to concentration measurements, using an atmospheric transport model to relate emission and concentration fields. Algorithmic novelties described in the paper above (1) ensure that the estimated emission fields are non-negative, (2) allow the use of guesses for emission fields to accelerate the estimation processes and (3) ensure that under/overestimates in the guesses do not skew the estimation.

  12. sparse-msrf:A package for sparse modeling and estimation of fossil-fuel CO2 emission fields

    Energy Science and Technology Software Center (OSTI)

    2014-10-06

    The software is used to fit models of emission fields (e.g., fossil-fuel CO2 emissions) to sparse measurements of gaseous concentrations. Its primary aim is to provide an implementation and a demonstration for the algorithms and models developed in J. Ray, V. Yadav, A. M. Michalak, B. van Bloemen Waanders and S. A. McKenna, "A multiresolution spatial parameterization for the estimation of fossil-fuel carbon dioxide emissions via atmospheric inversions", accepted, Geoscientific Model Development, 2014. The softwaremore » can be used to estimate emissions of non-reactive gases such as fossil-fuel CO2, methane etc. The software uses a proxy of the emission field being estimated (e.g., for fossil-fuel CO2, a population density map is a good proxy) to construct a wavelet model for the emission field. It then uses a shrinkage regression algorithm called Stagewise Orthogonal Matching Pursuit (StOMP) to fit the wavelet model to concentration measurements, using an atmospheric transport model to relate emission and concentration fields. Algorithmic novelties described in the paper above (1) ensure that the estimated emission fields are non-negative, (2) allow the use of guesses for emission fields to accelerate the estimation processes and (3) ensure that under/overestimates in the guesses do not skew the estimation.« less

  13. Strategic backdrop analysis for fossil fuel planning. Task 1. Default Case. Report 468-117-07/01

    SciTech Connect (OSTI)

    Not Available

    1980-06-01

    This report presents data describing a default case analysis performed using the strategic backdrop analytical framework developed to facilitate fossil fuel planning within the DOE. Target years are 1985 and 2025. Residential, commercial, and industrial energy demands are forecast as well as the impacts of energy technology implementation and market penetration using a set of energy technology assumptions. (DMC)

  14. Fossil-fuel power plants and power generation: Economic analysis. (Latest citations from the NTIS data base). Published Search

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    The bibliography contains citations concerning economic analyses and evaluations of utility and industrial fossil-fuel power generation. Coal-fired, oil-fired, and natural gas-fired electric power generating systems are discussed. Specific technologies, experiences, and locations are also considered. (Contains 250 citations and includes a subject term index and title list.)

  15. Fossil-fuel power plants and power generation: Economic analysis. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1995-10-01

    The bibliography contains citations concerning economic analyses and evaluations of utility and industrial fossil-fuel power generation. Coal-fired, oil-fired, and natural gas-fired electric power generating systems are discussed. Specific technologies, experiences, and locations are also considered. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  16. Fossil-fuel power plants and power generation: Economic analysis. (Latest citations from the NTIS Bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-12-01

    The bibliography contains citations concerning economic analyses and evaluations of utility and industrial fossil-fuel power generation. Coal-fired, oil-fired, and natural gas-fired electric power generating systems are discussed. Specific technologies, experiences, and locations are also considered. (Contains 250 citations and includes a subject term index and title list.)

  17. Fossil-fuel power plants and power generation: Economic analysis. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1994-12-01

    The bibliography contains citations concerning economic analyses and evaluations of utility and industrial fossil-fuel power generation. Coal-fired, oil-fired, and natural gas-fired electric power generating systems are discussed. Specific technologies, experiences, and locations are also considered. (Contains 250 citations and includes a subject term index and title list.)

  18. Fossil-fuel power plants and power generation: Economic analysis. (Latest citations from the NTIS Bibliographic database). Published Search

    SciTech Connect (OSTI)

    1993-09-01

    The bibliography contains citations concerning economic analyses and evaluations of utility and industrial fossil-fuel power generation. Coal-fired, oil-fired, and natural gas-fired electric power generating systems are discussed. Specific technologies, experiences, and locations are also considered. (Contains 250 citations and includes a subject term index and title list.)

  19. Fossil-fuel power plants and power generation: Economic analysis. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1997-02-01

    The bibliography contains citations concerning economic analyses and evaluations of utility and industrial fossil-fuel power generation. Coal-fired, oil-fired, and natural gas-fired electric power generating systems are discussed. Specific technologies, experiences, and locations are also considered. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  20. Strategic backdrop analysis for fossil fuel planning. Task 1. Default Case. Report 468-117-07/03

    SciTech Connect (OSTI)

    Not Available

    1980-06-01

    This report presents data describing a default case analysis performed using the strategic backdrop analytical framework developed to facilitate fossil fuel planning within the DOE. Target years are 1985, 2000, and 2025. Residential, commercial, and industrial energy demands and impacts of energy technology implementation and market penetration are forecast using a set of energy technology assumptions.

  1. Strategic backdrop analysis for fossil fuel planning. Task 1. Default Case. Report 468-117-07/02

    SciTech Connect (OSTI)

    Not Available

    1980-06-01

    This report presents data describing a default case analysis performed using the strategic backdrop analytical framework developed to facilitate fossil fuel planning within the DOE. Target years are 1985, 2000, and 2025. Residential, commercial, and industrial energy demands and impacts of energy technology implementation and market penetration are forecast using a set of energy technology assumptions. (DMC)

  2. High Temperature Fuel Cell Performance High Temperature Fuel Cell

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Performance of of Sulfonated Sulfonated Poly(phenylene Poly(phenylene) Proton) Proton Conducting Conducting Polymers | Department of Energy Cell Performance High Temperature Fuel Cell Performance of of Sulfonated Sulfonated Poly(phenylene Poly(phenylene) Proton) Proton Conducting Conducting Polymers High Temperature Fuel Cell Performance High Temperature Fuel Cell Performance of of Sulfonated Sulfonated Poly(phenylene Poly(phenylene) Proton) Proton Conducting Conducting Polymers Presentation

  3. The coprocessing of fossil fuels and biomass for CO{sub 2} emission reduction in the transportation sector

    SciTech Connect (OSTI)

    Steinberg, M.; Dong, Yuanji; Borgwardt, R.H.

    1993-10-01

    Research is underway to evaluate the Hydrocarb process for conversion of carbonaceous raw material to clean carbon and methanol products. These products are valuable in the market either as fuel or as chemical commodities. As fuel, methanol and carbon can be used economically, either independently or in slurry form, in efficient heat energies (turbines and internal combustion engines) for both mobile and stationary single and combined cycle power plants. When considering CO{sub 2} emission control in the utilization of fossil fuels, the copressing of those fossil fuels with biomass (which may include, wood, municipal solid waste and sewage sludge) is a viable mitigation approach. By coprocessing both types of feedstock to produce methanol and carbon while sequestering all or part of the carbon, a significant net CO{sub 2} reduction is achieved if the methanol is substituted for petroleum fuels in the transportation sector. The Hydrocarb process has the potential, if the R&D objectives are achieved, to produce alternative transportation fuel from indigenous resources at lower cost than any other biomass conversion process. These comparisons suggest the resulting fuel can significantly displace gasoline at a competitive price while mitigating CO{sub 2} emissions and reducing ozone and other toxics in urban atmospheres.

  4. Can industry`s `fourth` fossil fuel establish presence in US?

    SciTech Connect (OSTI)

    Armor, A.F.; Dene, C.E.

    1996-09-01

    After five years of commercial experience burning Orimulsion overseas, US utilities are now evaluating the new fuel as a serious alternative to oil. In their relentless drive to remain competitive, electric utilities with oil-fired generating units are searching for lower cost fuel alternatives. Because of high fuel prices, oil-fired units have low capacity factors. Only 23 out of 142 oil-capable units in the US had capacity factors greater than 50% in 1993; the average was a mere 24%. Utility consumption of fuel oil slid from over 600,000 barrels (bbl)/day in 1989 to less than 200,000 bbl/day last year. Orimulsion now fuels nearly 3,000 MW/yr worldwide. The UK`s PowerGen Ltd, currently the world`s largest consumer of Orimulsion, fires some 10-million bbl/yr at two 500-MW units at its Ince plant and three 120-MW units at its Richborough plant. Both plants formerly burned fuel oil, and have been using Orimulsion since 1991. Canada`s New Brunswick Power Corp has fired Orimulsion in two units at its Dalhousie plant since 1994 (Power, April 1995, p 27); one 105-MW unit was originally designed for fuel oil, the other 212-MW unit was designed for coal. Last year, Denmark`s SK Power converted its coal-fired, 700-MW Asnaes Unit 5 to Orimulsion firing. And in the US, Florida Power and Light Co. (FP and L) has signed a 20-yr fuel supply contract with Bitor America Corp (Boca Raton, Fla.), for two 800-MW units at the oil-fired Manatee plant, contingent on securing necessary permits. The Manatee installation (Power, September 1994, p 57) would be the first in the US to burn the fuel. Today, five years after Orimulsion begun to be used commercially, many of the lingering questions involving the new fuel`s handling, transportation, combustion, emissions control, spill control, and waste utilization have been settled. Several US utilities have expressed serious interest in the fuel as an alternative to oil.

  5. Table 3.2 Value of Fossil Fuel Production, 1949-2011 (Billion Dollars)

    U.S. Energy Information Administration (EIA) Indexed Site

    Value of Fossil Fuel Production, 1949-2011 (Billion Dollars) Year Coal 1 Natural Gas 2 Crude Oil 3,4 Total Nominal 5 Real 6 Nominal 5 Real 6 Nominal 5 Real 6 Nominal 5 Real 6 1949 2.52 17.37 [R] 0.33 2.24 4.68 32.27 [R] 7.52 51.88 [R] 1950 2.91 19.84 [R] .44 3.00 4.95 33.80 [R] 8.30 56.64 [R] 1951 3.05 19.40 [R] .52 3.32 [R] 5.69 36.19 [R] 9.26 58.92 [R] 1952 2.67 16.73 [R] .64 4.01 5.79 36.25 [R] 9.11 56.99 [R] 1953 2.55 15.79 [R] .76 4.67 [R] 6.32 39.06 [R] 9.63 59.52 [R] 1954 2.02 12.40 [R]

  6. The impact of environmental regulation on productivity in the US fossil-fueled power plants

    SciTech Connect (OSTI)

    Whang, J.

    1993-12-31

    The purpose of this dissertation is to examine the impact of environmental regulation on productivity in the U.S. fossil fueled electric generating industry. With the oil shocks, environmental regulation has been considered as one of the main culprits for the apparent productivity slowdown during the 1970`s. Even though new pieces of legislation are continuously enacted to regulate hazardous pollutants emitted, it is difficult to find thorough and meaningful analyses on the effects of regulation. Without exact measurement of regulation effects, it is not easy to design socially efficient environmental policies to reconcile several conflicting goals. Using plant-level production and environmental data for the last two decades, the effects of differentiated environmental regulation are carefully examined. Since unbalanced panel data set is used, fixed-effects and random-effects models are also examined. The estimated impact of environmental regulation explains 6 to 10 percent of the variation of total factor productivity growth rates. This appears to be a relatively mild effect compared with several previous studies.

  7. Determining NO{sub x} emissions from fossil fuel-fired sources

    SciTech Connect (OSTI)

    McNeel, A.

    1996-11-01

    To determine nitrogen oxides (NO{sub x}) emissions, the concentration of NO{sub x} within the stack gas must be determined. USEPA Reference Methods 7, 7A, 7C, 7D and/or 7E are the procedures to be used for NO{sub x} measurement as referenced in 40 CFR 60 subparts D, Da, Db and Dc - {open_quotes}Standards of performance for fossil fuel-fired steam generators...{open_quotes}. Depending upon the reason for determining NO{sub x} emissions, information in addition to NO{sub x} concentrations may be needed. Generally, USEPA Reference Methods 1 - 4 will be used to gather the additional data needed to satisfy the specific need for determining NO{sub x} emissions. The following text outlines the individual NO{sub x} sampling methodology, the relative costs of the reference method (RM) sampling, and the use of the resulting reference method data to calculate emissions in units of applicable standards.

  8. Separation of particulate from flue gas of fossil fuel combustion and gasification

    DOE Patents [OSTI]

    Yang, W.C.; Newby, R.A.; Lippert, T.E.

    1997-08-05

    The gas from combustion or gasification of fossil fuel contains fly ash and other particulates. The fly ash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The fly ash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured fly ash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled. 11 figs.

  9. Separation of particulate from flue gas of fossil fuel combustion and gasification

    DOE Patents [OSTI]

    Yang, Wen-Ching; Newby, Richard A.; Lippert, Thomas E.

    1997-01-01

    The gas from combustion or gasification of fossil fuel contains flyash and other particulate. The flyash is separated from the gas in a plurality of standleg moving granular-bed filter modules. Each module includes a dipleg through which the bed media flows into the standleg. The bed media forms a first filter bed having an upper mass having a first frusto-conical surface in a frusto-conical member at the entrance to the standleg and a lower mass having a second frusto-conical surface of substantially greater area than the first surface after it passes through the standleg. A second filter media bed may be formed above the first filter media bed. The gas is fed tangentially into the module above the first surface. The flyash is captured on the first frusto-conical surface and within the bed mass. The processed gas flows out through the second frusto-conical surface and then through the second filter bed, if present. The bed media is cleaned of the captured flyash and recirculated to the moving granular bed filter. Alternatively, the bed media may be composed of the ash from the combustion which is pelletized to form agglomerates. The ash flows through the bed only once; it is not recycled.

  10. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    SciTech Connect (OSTI)

    de la Rue du Can, Stephane; Wenzel, Tom; Price, Lynn

    2008-08-13

    Central to any study of climate change is the development of an emission inventory that identifies and quantifies the State's primary anthropogenic sources and sinks of greenhouse gas (GHG) emissions. CO2 emissions from fossil fuel combustion accounted for 80 percent of California GHG emissions (CARB, 2007a). Even though these CO2 emissions are well characterized in the existing state inventory, there still exist significant sources of uncertainties regarding their accuracy. This report evaluates the CO2 emissions accounting based on the California Energy Balance database (CALEB) developed by Lawrence Berkeley National Laboratory (LBNL), in terms of what improvements are needed and where uncertainties lie. The estimated uncertainty for total CO2 emissions ranges between -21 and +37 million metric tons (Mt), or -6percent and +11percent of total CO2 emissions. The report also identifies where improvements are needed for the upcoming updates of CALEB. However, it is worth noting that the California Air Resources Board (CARB) GHG inventory did not use CALEB data for all combustion estimates. Therefore the range in uncertainty estimated in this report does not apply to the CARB's GHG inventory. As much as possible, additional data sources used by CARB in the development of its GHG inventory are summarized in this report for consideration in future updates to CALEB.

  11. An expanded review and comparison of greenhouse gas emissions from fossil fuel and geothermal electrical generating facilities

    SciTech Connect (OSTI)

    Booth, R.B.; Neil, P.E.

    1998-12-31

    This paper provides a review of the greenhouse gas emissions due to fossil fuel and geothermal electrical generation and to the emissions of their respective support activities. These support activities consist of, exploration, development, and transportation aspects of the fuel source, including waste management. These support activities could amount to an additional 6% for coal, 22% for oil, 13% for natural gas and 1% for geothermal. The presented methodologies and underlying principles can be used to better define the resultant emissions, rankings and global impacts of these electrical generating industries.

  12. Crude Glycerol as Cost-Effective Fuel for Combined Heat and Power to Replace Fossil Fuels, Final Technical Report

    SciTech Connect (OSTI)

    Roberts, William L

    2012-10-31

    The primary objectives of this work can be summed into two major categories. Firstly, the fundamentals of the combustion of glycerol (in both a refined and unrefined form) were to be investigated, with emphasis of the development of a system capable of reliably and repeatedly combusting glycerol as well as an analysis of the emissions produced during glycerol combustion. Focus was placed on quantifying common emissions in comparison to more traditional fuels and this work showed that the burner developed was able to completely combust glycerol within a relatively wide range of operating conditions. Additionally, focus was placed on examining specific emissions in more detail, namely interesting NOx emissions observed in initial trials, acrolein and other volatile organic emissions, and particulate and ash emissions. This work showed that the combustion of crude glycerol could result in significantly reduced NOx emissions as a function of the high fuel bound oxygen content within the glycerol fuel. It also showed that when burned properly, the combustion of crude glycerol did not result in excessive emissions of acrolein or any other VOC compared to the combustion from more traditional fuels. Lastly however, this work has shown that in any practical application in which glycerol is being burned, it will be necessary to explore ash mitigation techniques due to the very high particulate matter concentrations produced during glycerol combustion. These emissions are comparable to unfiltered coal combustion and are directly tied to the biodiesel production method. The second focus of this work was directed to developing a commercialization strategy for the use of glycerol as a fuel replacement. This strategy has identified a 30 month plan for the scaling up of the laboratory scale burner into a pre-pilot scale system. Additionally, financing options were explored and an assessment was made of the economics of replacing a traditional fuel (namely natural gas) with crude

  13. Conclusions drawn from actions implemented within the first stage of the Cracow program of energy conservation and clean fossil fuels

    SciTech Connect (OSTI)

    Bieda, J.; Bardel, J.; Pierce, B.

    1995-12-31

    Since 1992 Brookhaven National Laboratory (BNL) and Pacific Northwest Laboratory (PNL), acting on behalf of the U.S. Department of Energy, executed the first stage of the Cracow Program of Energy Conservation and Clean Fossil Fuels, called also American-Polish Program of Actions for Elimination of Low Emission Sources in Cracow. The main contractor for BNL and PNL was the Cracow Development Office (BRK). The interest in improving the condition of Cracow air results from the fact that the standard for permissible air pollution was exceeded several times in Cracow and especially within the central part of the town. Therefore, air pollution appeared one of the most important problems that faced the municipal authorities. It followed from monitoring investigations that the high level of air pollutant concentration is caused by in-home coal-fired tile stoves operated in winter seasons and by coal- and coke-fired boiler houses simulated mainly in the central part of the town. The results obtained in first stage are presented. This paper is an attempt to formulate conclusions drawn from these works and recommendations with regard to the future policy of the town authorities; selected results are presented to clarify or illustrate the conclusions.

  14. High loading uranium fuel plate

    DOE Patents [OSTI]

    Wiencek, Thomas C.; Domagala, Robert F.; Thresh, Henry R.

    1990-01-01

    Two embodiments of a high uranium fuel plate are disclosed which contain a meat comprising structured uranium compound confined between a pair of diffusion bonded ductile metal cladding plates uniformly covering the meat, the meat having a uniform high fuel loading comprising a content of uranium compound greater than about 45 Vol. % at a porosity not greater than about 10 Vol. %. In a first embodiment, the meat is a plurality of parallel wires of uranium compound. In a second embodiment, the meat is a dispersion compact containing uranium compound. The fuel plates are fabricated by a hot isostatic pressing process.

  15. General circulation model calculations of the direct radiative forcing by anthropogenic sulfate and fossil-fuel soot aerosol

    SciTech Connect (OSTI)

    Haywood, J.M.; Roberts, D.L.; Slingo, A.

    1997-07-01

    A new radiation code within a general circulation model is used to assess the direct solar and thermal radiative forcing by sulfate aerosol of anthropogenic origin and soot aerosol from fossil-fuel burning. The radiative effects of different aerosol profiles, relative humidity parameterizations, chemical compositions, and internal and external mixtures of the two aerosol types are investigated. The contribution to the radiative forcing from cloudy sky regions is found to be negligible for sulfate aerosol; this is in contrast to recent studies where the cloudy sky contribution was estimated using a method in which the spatial correlation between cloud amount and sulfate burden was ignored. However, the radiative forcing due to fossil-fuel soot aerosol is enhanced in cloudy regions if soot aerosol exists within or above the cloud. The global solar radiative forcing due to sulfate aerosol is estimated to be -0.38 W m{sup -2} and the global thermal radiative forcing is estimated to be +0.01 W m{sup -2}. The hemispheric mean radiative forcings vary by only about 10% for reasonable assumptions about the chemical form of the sulfate aerosol and the relative humidity dependence; the uncertainties in the aerosol loading are far more significant. If a soot/sulfate mass ratio of 0.075 is assumed, then the global solar radiative forcing weakens to -0.18 W m{sup -2} for an external mixture and weakens further for an internal mixture. Additionally, the spatial distribution of the radiative forcing shows strong negative/positive forcing contrasts that may influence the dynamical response of the atmosphere. Although these results are extremely sensitive to the adopted soot/sulfate ratio and the assumed vertical profile, they indicate that fossil-fuel soot aerosol may exert a nonnegligible radiative forcing and emphasize the need to consider each anthropogenic aerosol species. 58 refs., 8 figs., 1 tab.

  16. Estimates of health risks associated with radionuclide emissions from fossil-fueled steam-electric generating plants. Final report

    SciTech Connect (OSTI)

    Nelson, C.

    1995-08-01

    Under the Title III, Section 112 of the 1990 Clean Air Act Amendment, Congress directed the U.S. Environmental Protection Agency (EPA) to perform a study of the hazards to public resulting from pollutants emitted by electric utility system generating units. Radionuclides are among the groups of pollutants listed in the amendment. This report updates previously published data and estimates with more recently available information regarding the radionuclide contents of fossil fuels, associated emissions by steam-electric power plants, and potential health effects to exposed population groups.

  17. Boiler and steam generator corrosion: Fossil fuel power plants. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-11-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. The citations examine hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains a minimum of 85 citations and includes a subject term index and title list.)

  18. Boiler and steam generator corrosion: Fossil fuel power plants. (Latest citations from the NTIS database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. The citations examine hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains a minimum of 84 citations and includes a subject term index and title list.)

  19. Boiler and steam generator corrosion: Fossil fuel power plants. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1996-03-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. The citations examine hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  20. Boiler and steam generator corrosion: Fossil fuel power plants. (Latest citations from the NTIS Bibliographic database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1994-11-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. The citations examine hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains a minimum of 119 citations and includes a subject term index and title list.)

  1. Boiler and steam generator corrosion: Fossil fuel power plants. (Latest citations from the NTIS bibliographic database). Published Search

    SciTech Connect (OSTI)

    1996-11-01

    The bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. The citations examine hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  2. High Burnup Fuel Behavior Modeling

    SciTech Connect (OSTI)

    Jahingir, M.; Rand, R.; Stachowski, R.; Miles, B.; Kusagaya, K.

    2007-07-01

    This paper discusses the development and qualification of the PRIME03 code to address high burnup mechanisms and to improve uranium utilization in current and new reactor designs. Materials properties and behavioral models have been updated from previous thermal-mechanical codes to reflect the effects of burnup on fuel pellet thermal conductivity, Zircaloy creep, fuel pellet relocation, and fission gas release. These new models are based on results of in-pool and post irradiation examination (PIE) of commercial boiling water reactor (BWR) fuel rods at high burnup and results from international experimental programs. The new models incorporated into PRIME03 also address specific high burnup effects associated with formation of pellet rim porosity at high exposure. The PRIME03 code is qualified by comparison of predicted and measured fuel performance parameters for a large number of high, low, and moderate burnup test and commercial reactor rod. The extensive experimental qualification of the PRIME03 prediction capabilities confirms that it is a reliable best-estimate predictor of fuel rod thermal-mechanical performance over a wide range of design and operating conditions. (authors)

  3. EPRI-DOE Joint Report Focuses on Fossil Fleet Transition with Fuel Changes and Large Scale Variable Renewable Integration

    Broader source: Energy.gov [DOE]

    The Energy Department released a report on fossil fleet transition with renewable integration, describing operational and engineering challenges to the fossil generation fleet.

  4. TASK 3.4--IMPACTS OF COFIRING BIOMASS WITH FOSSIL FUELS

    SciTech Connect (OSTI)

    Christopher J. Zygarlicke; Donald P. McCollor; Kurt E. Eylands; Melanie D. Hetland; Mark A. Musich; Charlene R. Crocker; Jonas Dahl; Stacie Laducer

    2001-08-01

    % wheat straw fuel compared to the coals. The wheat straw ash was found to show the greatest similarity from the fuel to the ash analyzed. A high percentage of particles from both fuel and ash samples contained both Si and K. While Cl was a significant component in the fuel, very little was detected in the ash sample.

  5. HIGH EFFICIENCY GENERATION OF HYDROGEN FUELS USING NUCLEAR POWER

    SciTech Connect (OSTI)

    BROWN,LC; BESENBRUCH,GE; LENTSCH,RD; SCHULTZ,KR; FUNK,JF; PICKARD,PS; MARSHALL,AC; SHOWALTER,SK

    2003-06-01

    OAK B202 HIGH EFFICIENCY GENERATION OF HYDROGEN FUELS USING NUCLEAR POWER. Combustion of fossil fuels, used to power transportation, generate electricity, heat homes and fuel industry provides 86% of the world's energy. Drawbacks to fossil fuel utilization include limited supply, pollution, and carbon dioxide emissions. Carbon dioxide emissions, thought to be responsible for global warming, are now the subject of international treaties. Together, these drawbacks argue for the replacement of fossil fuels with a less-polluting potentially renewable primary energy such as nuclear energy. Conventional nuclear plants readily generate electric power but fossil fuels are firmly entrenched in the transportation sector. Hydrogen is an environmentally attractive transportation fuel that has the potential to displace fossil fuels. Hydrogen will be particularly advantageous when coupled with fuel cells. Fuel cells have higher efficiency than conventional battery/internal combustion engine combinations and do not produce nitrogen oxides during low-temperature operation. Contemporary hydrogen production is primarily based on fossil fuels and most specifically on natural gas. When hydrogen is produced using energy derived from fossil fuels, there is little or no environmental advantage. There is currently no large scale, cost-effective, environmentally attractive hydrogen production process available for commercialization, nor has such a process been identified. The objective of this work is to find an economically feasible process for the production of hydrogen, by nuclear means, using an advanced high-temperature nuclear reactor as the primary energy source. Hydrogen production by thermochemical water-splitting (Appendix A), a chemical process that accomplishes the decomposition of water into hydrogen and oxygen using only heat or, in the case of a hybrid thermochemical process, by a combination of heat and electrolysis, could meet these goals. Hydrogen produced from fossil

  6. A multiresolution spatial parametrization for the estimation of fossil-fuel carbon dioxide emissions via atmospheric inversions.

    SciTech Connect (OSTI)

    Ray, Jaideep; Lee, Jina; Lefantzi, Sophia; Yadav, Vineet; Michalak, Anna M.; van Bloemen Waanders, Bart Gustaaf; McKenna, Sean Andrew

    2013-04-01

    The estimation of fossil-fuel CO2 emissions (ffCO2) from limited ground-based and satellite measurements of CO2 concentrations will form a key component of the monitoring of treaties aimed at the abatement of greenhouse gas emissions. To that end, we construct a multiresolution spatial parametrization for fossil-fuel CO2 emissions (ffCO2), to be used in atmospheric inversions. Such a parametrization does not currently exist. The parametrization uses wavelets to accurately capture the multiscale, nonstationary nature of ffCO2 emissions and employs proxies of human habitation, e.g., images of lights at night and maps of built-up areas to reduce the dimensionality of the multiresolution parametrization. The parametrization is used in a synthetic data inversion to test its suitability for use in atmospheric inverse problem. This linear inverse problem is predicated on observations of ffCO2 concentrations collected at measurement towers. We adapt a convex optimization technique, commonly used in the reconstruction of compressively sensed images, to perform sparse reconstruction of the time-variant ffCO2 emission field. We also borrow concepts from compressive sensing to impose boundary conditions i.e., to limit ffCO2 emissions within an irregularly shaped region (the United States, in our case). We find that the optimization algorithm performs a data-driven sparsification of the spatial parametrization and retains only of those wavelets whose weights could be estimated from the observations. Further, our method for the imposition of boundary conditions leads to a 10computational saving over conventional means of doing so. We conclude with a discussion of the accuracy of the estimated emissions and the suitability of the spatial parametrization for use in inverse problems with a significant degree of regularization.

  7. Krakow clean fossil fuels and energy efficiency program. Phase 1 report

    SciTech Connect (OSTI)

    Butcher, T.; Pierce, B.

    1995-06-01

    Krakow is one of the largest and oldest cities in Poland. It is situated in the south of the country on the banks of the Vistula River. From the 11th until the 17th centuries, it was the capital of Poland. Today, Krakow is a city of 750,000 residents, one of the largest centers of higher education, an important industrial center, and is of particular importance because of the number and kinds of historic buildings and sites. For this reason, Krakow was included by the UNESCO in the list of the world`s cultural heritages. For about three decades, significant air pollution has been one of Krakow`s most serious problems. Because the city is situated in the Vistula River valley, it is poorly ventilated and experiences a high concentration of air pollutants. The quality of air in Krakow is affected mainly by industry (Sendzimir Steelworks, energy industry, chemical plants), influx from the Silesian industrial region (power plants, metallurgy), transboundary pollution (Ostrava - Czech Republic), and local sources of low pollution, i.e. more than 1,000 boiler houses using solid fuels and more than 100,000 coal-fired home stoves. These local sources, with low stacks and almost no pollution-control equipment, are responsible for about 35-40% of the air pollution. This report presents phase I results of a program to reduce pollution in krakow. Phase I was to gather information on emissions and costs, and to verify assumptions on existing heating methods and alternatives.

  8. Control of SO{sub 2} and NOx emissions from fossil fuel-fired power plants: Research and practice of TPRI

    SciTech Connect (OSTI)

    Ming-Chuan Zhang

    1993-12-31

    The generation of electric power in China has been dominated by coal for many years. By the end of 1990, total installed generating capacity reached 135 GW, of which fossil fuel-fired plants accounted for 74 percent. The total electricity generated reached 615 TWh, with fossil fuels accounting for 80.5 percent. About 276 million tons of raw coal are consumed in these fossil fuel-burning units per year, accounting for about 25 percent of the total output of the country. According to the government, by the year 2000, the total installed capacity of Chinese power systems should be at least 240 GW, of which fossil fuels will account for about 77 percent. The coal required for power generation will increase to about 530 million tons per year, accounting for about 38 percent of the total coal output. So, it is obvious that coal consumed in coal-fired power plants occupies a very important place in the national fuel balance. The current environmental protection standards, which are based on ground-level concentrations of pollutants, do not effectively lead to the control of pollution emission concentrations or total SO{sub 2} emissions. Due to the practical limitations of the Chinese economy, there is a limited capability to introduce advanced sulfur emission control technologies. Thus, except for the two 360 MW units imported from Japan for the Luohuang Power Plant in Shichuan province, all the other fossil fuel-fired units have not yet adopted any kind of SO{sub 2} removal measures. The Luohuang units are equipped with Mitsubishi limestone flue gas desulfurization systems. Because of the lack of effective pollution control technologies, large areas of the country have been seriously polluted by SO{sub 2}, and some of them even by acid rain.

  9. Fossil fuel power plants: Computer systems for power plant control, maintenance, and operation. (Latest citations from the Compendex database). Published Search

    SciTech Connect (OSTI)

    Not Available

    1993-07-01

    The bibliography contains citations concerning fossil fuel power plant computer systems. Minicomputer and microcomputer systems used for monitoring, process control, performance calculations, alarming, and administrative applications are discussed. Topics emphasize power plant control, maintenance and operation. (Contains 250 citations and includes a subject term index and title list.)

  10. High Octane Fuels Can Make Better Use of Renewable Transportation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Octane Fuels Can Make Better Use of Renewable Transportation Fuels High Octane Fuels Can Make Better Use of Renewable Transportation Fuels Breakout Session 1C-Fostering Technology ...

  11. A formalized approach to cycle chemistry improvement in fossil fuel power plants

    SciTech Connect (OSTI)

    Dimmer, J.P.; Dooley, R.B.

    1995-01-01

    The overall cost impact of cycle chemistry problems in fossil plants is typically hidden within the statistics of component forced outages, efficiency losses and premature end of useful component life. Corrosion of components in US utility steam generating plants is responsible for an estimated 50% of forced outages and over three billion dollars a year in additional operating and maintenance costs. These problems are usually the direct result of repeat incidents of impurity ingress, corrosion, and/or corrosion product generation transport, and deposition on heat transfer and power generation process equipment surfaces. The only way to prevent repeat incidents of cycle chemistry corrosion and/or deposition-influenced equipment problems is to implement a formalized cycle chemistry improvement program that addresses the root-causes of these problems. This paper describes such a program being implemented at twelve (12) utilities under EPRI research project RP2712-11, {open_quotes}Cycle Chemistry Improvement Program.{close_quotes} Interim utility results, after almost three years of project participation, have demonstrated substantial reductions in availability/performance losses and water treatment costs due to applications of state-of-the-art cycle chemistry, monitoring equipment and/or process control systems.

  12. Polyelectrolyte Materials for High Temperature Fuel Cells

    Office of Energy Efficiency and Renewable Energy (EERE)

    This presentation, which focuses on polyelectrolyte materials for high temperature fuel cells, was given by John Kerr of Lawrence Berkeley National Laboratory at a meeting on new fuel cell projects in February 2007.

  13. Fossil Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fossil Energy Research and Development Fossil Energy Research and Development Table of Contents Page Appropriation Language .................................................................................................................... FE-3 Overview ............................................................................................................................................ FE-4 Coal

  14. An Internet-based interactive module for air emissions from fossil fuel based power generation

    SciTech Connect (OSTI)

    Karman, D.; O`Leary, K.; O`Reilly, S.

    1997-12-31

    The proliferation of the Internet, Web pages and associated software tools available for developing multimedia material provides significant opportunities in training, education and information transfer. This paper will describe the development, testing and evaluation of an interactive teaching module aimed at college and university students that have previous education in thermodynamics and basic chemistry. The module is currently in development at the Department of Civil and Environmental Engineering at Carleton University with support from Environment Canada. Preliminary testing of this module is expected to begin late January. The module contains options to look at CO, CO{sub 2}, SO{sub 2} and NO{sub x} emissions associated with electric power generation in thermal stations that use coal, natural gas, crude and distillate oil. Factors governing the thermal efficiency of typical boiler systems and the thermodynamic limitations for converting heat into work are discussed. Supporting background information such as emission trends and emission factors used in calculations are also included as part of this module. A simple Rankine cycle without reheat or regeneration is considered to compare the emissions per unit energy delivered from each of the fuels considered. For natural gas and distillate oil, combined cycle operation is considered with a gas turbine-heat recovery steam generator combination replacing the boiler in the simple Rankine cycle. For all fuels, the cogeneration option is investigated by expanding the steam to an intermediate pressure in the turbine and utilizing the remaining heat by condensing the steam in a heat recovery application. Emission factors and basic information on CO, SO{sub 2} and NO{sub x} control technologies are utilized to calculate and report the emissions per unit energy delivered under the various scenarios investigated.

  15. Fossil fuel and hydrocarbon conversion using hydrogen-rich plasmas. Topical report February 1994--February 1995

    SciTech Connect (OSTI)

    1995-02-01

    Experiments were made on use of H and CH plasmas for converting waste materials and heavy oils to H-rich transportation fuels. Batch and continuous experiments were conducted with an industrial microwave generator and a commercial microwave oven. A continuously circulating reactor was constructed for conducting experiments on flowing oils. Experiments on decomposition of scrap tires showed that microwave plasmas can be used to decompose scrap tires into potentially useful liquid products. In a batch experiment using a commercial microwave oven, about 20% of the tire was converted to liquid products in about 9 minutes. Methane was decomposed in a microwave plasma to yield a liquid products composed of various compound types; GC/MS analyses identified unsaturated compounds including benzene, toluene, ethyl benzene, methyl and ethyl naphthalene, small amounts of larger aromatic rings, and olefinic compounds. Experiments on a crude oil in a continuously flowing reactor showed that distillate materials are produced using H and CH plasmas. Also, the recycle oils had an overall carbon aromaticity lower than that of starting feed material, indicating that some hydrogenation and methanation had taken place in the recycle oils.

  16. ABB`s investigations into air toxic emissions from fossil fuel and MSW combustion

    SciTech Connect (OSTI)

    Wesnor, J.D.

    1994-12-31

    Since passage of the Clean Air Act, Asea Brown Boveri (ABB) has been actively developing a knowledge base on the Title 3 hazardous air pollutants, more commonly called air toxics. As ABB is a multinational company, US operating companies are able to call upon work performed by European counterparts, who have faced similar legislation several years ago. In addition to the design experience and database acquired in Europe, ABB Inc. has been pursuing several other avenues to expand its air toxics knowledge. ABB Combustion Engineering (ABB CE) is presently studying the formation of organic pollutants within the combustion furnace and partitioning of trace metals among the furnace outlet streams. ABB Environmental Systems (ABBES) has reviewed available and near-term control technologies and methods. Also, both ABB CE and ABBES have conducted source sampling and analysis at commercial installations for hazardous air pollutants to determine the emission rates and removal performance of various types of equipment. Several different plants hosted these activities, allowing for variation in fuel type and composition, boiler configuration, and air pollution control equipment. This paper discusses the results of these investigations.

  17. China: Emissions pattern of the world leader in CO2 emissions from fossil fuel consumption and cement production

    SciTech Connect (OSTI)

    Gregg, J; Andres, Robert Joseph; Marland, Gregg

    2008-01-01

    Release of carbon dioxide (CO2) from fossil fuel combustion and cement manufacture is the primary anthropogenic driver of climate change. Our best estimate is that China became the largest national source of CO2 emissions during 2006. Previously, the United States (US) had occupied that position. However, the annual emission rate in the US has remained relatively stable between 2001-2006 while the emission rate in China has more than doubled, apparently eclipsing that of the US in late 2006. Here we present the seasonal and spatial pattern of CO2 emissions in China, as well as the sectoral breakdown of emissions. Though our best point estimate places China in the lead position in terms of CO2 emissions, we qualify this statement in a discussion of the uncertainty in the underlying data (3-5% for the US; 15-20% for China). Finally, we comment briefly on the implications of China's new position with respect to international agreements to mitigate climate change.

  18. Technical Potential of Solar Water Heating to Reduce Fossil Fuel Use and Greenhouse Gas Emissions in the United States

    SciTech Connect (OSTI)

    Denholm, P.

    2007-03-01

    Use of solar water heating (SWH) in the United States grew significantly in the late 1970s and early 1980s, as a result of increasing energy prices and generous tax credits. Since 1985, however, expiration of federal tax credits and decreased energy prices have virtually eliminated the U.S. market for SWH. More recently, increases in energy prices, concerns regarding emissions of greenhouse gases, and improvements in SWH systems have created new interest in the potential of this technology. SWH, which uses the sun to heat water directly or via a heat-transfer fluid in a collector, may be particularly important in its ability to reduce natural gas use. Dependence on natural gas as an energy resource in the United States has significantly increased in the past decade, along with increased prices, price volatility, and concerns about sustainability and security of supply. One of the readily deployable technologies available to decrease use of natural gas is solar water heating. This report provides an overview of the technical potential of solar water heating to reduce fossil fuel consumption and associated greenhouse gas emissions in U.S. residential and commercial buildings.

  19. Novel Materials for High Efficiency Direct Methanol Fuel Cells...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Materials for High Efficiency Direct Methanol Fuel Cells Novel Materials for High Efficiency Direct Methanol Fuel Cells Presented at the Department of Energy Fuel Cell Projects ...

  20. Microchannel High-Temperature Recuperator for Fuel Cell Systems...

    Energy Savers [EERE]

    Microchannel High-Temperature Recuperator for Fuel Cell Systems - Fact Sheet, 2014 Microchannel High-Temperature Recuperator for Fuel Cell Systems - Fact Sheet, 2014 FuelCell ...

  1. Carbon Capture and Water Emissions Treatment System (CCWESTRS) at Fossil-Fueled Electric Generating Plants

    SciTech Connect (OSTI)

    P. Alan Mays; Bert R. Bock; Gregory A. Brodie; L. Suzanne Fisher; J. Devereux Joslin; Donald L. Kachelman; Jimmy J. Maddox; N. S. Nicholas; Larry E. Shelton; Nick Taylor; Mark H. Wolfe; Dennis H. Yankee; John Goodrich-Mahoney

    2005-08-30

    The Tennessee Valley Authority (TVA), the Electric Power Research Institute (EPRI), and the Department of Energy-National Energy Technologies Laboratory (DOE-NETL) are evaluating and demonstrating integration of terrestrial carbon sequestration techniques at a coal-fired electric power plant through the use of Flue Gas Desulfurization (FGD) system gypsum as a soil amendment and mulch, and coal fly ash pond process water for periodic irrigation. From January to March 2002, the Project Team initiated the construction of a 40 ha Carbon Capture and Water Emissions Treatment System (CCWESTRS) near TVA's Paradise Fossil Plant on marginally reclaimed surface coal mine lands in Kentucky. The CCWESTRS is growing commercial grade trees and cover crops and is expected to sequester 1.5-2.0 MT/ha carbon per year over a 20-year period. The concept could be used to meet a portion of the timber industry's needs while simultaneously sequestering carbon in lands which would otherwise remain non-productive. The CCWESTRS includes a constructed wetland to enhance the ability to sequester carbon and to remove any nutrients and metals present in the coal fly ash process water runoff. The CCWESTRS project is a cooperative effort between TVA, EPRI, and DOE-NETL, with a total budget of $1,574,000. The proposed demonstration project began in October 2000 and has continued through December 2005. Additional funding is being sought in order to extend the project. The primary goal of the project is to determine if integrating power plant processes with carbon sequestration techniques will enhance carbon sequestration cost-effectively. This goal is consistent with DOE objectives to provide economically competitive and environmentally safe options to offset projected growth in U.S. baseline emissions of greenhouse gases after 2010, achieve the long-term goal of $10/ton of avoided net costs for carbon sequestration, and provide half of the required reductions in global greenhouse gases by 2025

  2. High Density Fuel Development for Research Reactors

    SciTech Connect (OSTI)

    Daniel Wachs; Dennis Keiser; Mitchell Meyer; Douglas Burkes; Curtis Clark; Glenn Moore; Jan-Fong Jue; Totju Totev; Gerard Hofman; Tom Wiencek; Yeon So Kim; Jim Snelgrove

    2007-09-01

    An international effort to develop, qualify, and license high and very high density fuels has been underway for several years within the framework of multi-national RERTR programs. The current development status is the result of significant contributions from many laboratories, specifically CNEA in Argentina, AECL in Canada, CEA in France, TUM in Germany, KAERI in Korea, VNIIM, RDIPE, IPPE, NCCP and RIARR in Russia, INL, ANL and Y-12 in USA. These programs are mainly engaged with UMo dispersion fuels with densities from 6 to 8 gU/cm3 (high density fuel) and UMo monolithic fuel with density as high as 16 gU/cm3 (very high density fuel). This paper, mainly focused on the French & US programs, gives the status of high density UMo fuel development and perspectives on their qualification.

  3. Estimates of global, regional, and national annual CO{sub 2} emissions from fossil-fuel burning, hydraulic cement production, and gas flaring: 1950--1992

    SciTech Connect (OSTI)

    Boden, T.A.; Marland, G.; Andres, R.J.

    1995-12-01

    This document describes the compilation, content, and format of the most comprehensive C0{sub 2}-emissions database currently available. The database includes global, regional, and national annual estimates of C0{sub 2} emissions resulting from fossil-fuel burning, cement manufacturing, and gas flaring in oil fields for 1950--92 as well as the energy production, consumption, and trade data used for these estimates. The methods of Marland and Rotty (1983) are used to calculate these emission estimates. For the first time, the methods and data used to calculate CO, emissions from gas flaring are presented. This C0{sub 2}-emissions database is useful for carbon-cycle research, provides estimates of the rate at which fossil-fuel combustion has released C0{sub 2} to the atmosphere, and offers baseline estimates for those countries compiling 1990 C0{sub 2}-emissions inventories.

  4. Increased cost-effectiveness of low-grade fossil fuels using ammonia FGD

    SciTech Connect (OSTI)

    Ellison, W.

    1998-07-01

    Current worldwide advancements in site-specific application and commercial operation of ammonia-base flue gas desulfurization (FGD), in high-capacity, high-sulfur, electric utility service, economically justified by significant revenues from ammonium sulfate generation and worldwide sale, are detailed. This major new direction in cost-effectiveness in FGD selection/application and in the process design of such flue gas cleaning systems overcomes the problem of FGD waste/byproduct management/utilization and encompasses numerous major performance advancements reviewed herein: (1) Conversion of anions of all captured acid-gas, i.e., SO{sub 2}, HCI, etc., and of all collected residual particulate matter into agriculturally-usable ammonium compounds combined in the single byproduct yield; (2) No discard or long-term, outdoor storage of sulfurous waste byproducts; and (3) No liquid effluent. In the face of a capital-cost penalty in any application of ammonia FGD, an attractive cost effectiveness is nonetheless realized. This favorable process economics, superior to all other available alternatives in high-capacity, high-sulfur electric utility service, is made possible through substantial value added in conversion of ammonia reagent supply to agglomerated sulfur blending stock, i.e., comprised principally of ammonium sulfate, much in demand for increased use in worldwide, large-scale agriculture. The growing, potentially vast size of the international market for ammonium sulfate is quantified herein.

  5. Increased cost-effectiveness of low-grade fossil fuels using ammonia FGD

    SciTech Connect (OSTI)

    Ellison, W.

    1998-04-01

    Current worldwide advancements in site-specific application and commercial operation of ammonia-base flue gas desulfurization, (FGD), in high-capacity, high-sulfur, electric utility service, economically justified by significant revenues from ammonium sulfate generation and worldwide sale, are detailed. This major new direction in cost-effectiveness in FGD selection/application and in the process design of such flue gas cleaning systems overcomes the problem of FGD waste/byproduct management/utilization and encompasses numerous major performance advancements reviewed herein: (1) Conversion of anions of all captured acid-gas, i.e. SO2, HCl, etc., and of all collected residual particulate matter into agriculturally-usable ammonium compounds combined in the single byproduct yield, (2) no discard or long-term, outdoor storage of sulfurous waste byproducts, and (3) no liquid effluent. In the face of a capital-cost penalty in any application of ammonia FGD, an attractive cost effectiveness is nonetheless realized.

  6. Minimizing the life cycle costs attributed to boiler tubing in fossil-fueled plants

    SciTech Connect (OSTI)

    Paterson, S.R.

    1995-08-01

    During the past quarter century, much has been learned about tube degradation, the factors which lead to and influence the rate of damage, and measures to mitigate or eliminate the damage in boiler tubing. This paper will describe some of the knowledge which has been compiled regarding two of the most significant degradation modes--corrosion-fatigue of waterwall tubes and high temperature creep of superheater and reheater tubes.

  7. Removal of Mercury from Aqueous Streams of Fossil Fuel Power Plants Using Novel Functionalized Nanoporous Sorbents

    SciTech Connect (OSTI)

    Mattigod, Shas V.; Fryxell, Glen E.; Feng, X; Parker, Kent E.; Pierce, Eric M.

    2006-01-11

    A new class of hybrid nanoporous materials has been developed at the Pacific Northwest National Laboratory for removing toxic heavy metals such as mercury from aqueous and nonaqueous waste streams. These novel materials consist of functional molecules capable of selectively binding mercury (thiol groups) covalently bound (as densely populated monolayers) to the synthetic nanoporous substrates. Tests indicated that this sorbent (Self-Assembled Monolayers on Mesoporous Silica - SAMMS) can achieve mercury loading as high as {approx}635 mg/g. The high affinity for Hg adsorption by this material was reflected by Kd values as high as 3.5 x 108 ml/g. Data indicated that SAMMS can adsorb both inorganic and organic forms of mercury. Experimental data indicated that mercury adsorption performance of SAMMS was not significantly affected by pH, ionic strength, presence of other cations (Na, Ca, Cd, Cu, Fe, Ni, Pb, and Zn), and complexing anions (Cl, CN, CO3, SO4, and PO4) in solution. Adsorption kinetics studies indicated that SAMMS adsorbed mercury very rapidly (about 99.9% adsorption occurring within first five minutes). Tests conducted using samples of different aqueous and non-aqueous waste streams have confirmed the exemplary performance characteristics of SAMMS sorbents. Preliminary cost estimates indicated that using SAMMS would result in significant savings in mercury remediation costs as compared to the use of conventional adsorbents such as ion exchange resin and activated carbon.

  8. Impacts from a fossil fuel power plant on ozone levels in Memphis, Tennessee

    SciTech Connect (OSTI)

    Mueller, S.F.; Bailey, E.M.

    1998-12-31

    The Tennessee Valley Authority (TVA) Allen power plant is located on the Mississippi River in the southwest corner of Memphis, Tennessee. Allen has three coal-fired cyclone boilers with a rated capacity of 272 MW each. It is a Phase 2 plant under Title IV of the Clean Air Act and is the largest single source of NO{sub x} in the Memphis area. TVA plans to reduce Allen NOx emissions through a combination of burning low-sulfur coal (which has the benefit of reducing NO{sub x} emissions while also reducing SO{sub 2} emissions) and installing gas re-burn technology. A modeling study using the SAI, Inc., UAM-V photochemical model was conducted to examine the potential impacts of NO{sub x} reductions on ozone levels in the Memphis area. A series of four model simulations were made in which different Allen emissions scenarios were examined. The focus period of the photochemical modeling was 11--14 July 1995 when measurements in and near Memphis indicated peak hourly ozone levels of 135--140 ppb. This analysis primarily examined computed impacts within 50 km of Memphis. Allen was computed to contribute as much as 20--30 ppb to ground ozone levels 20-50 km downwind using its NO{sub x} emission rate before Title IV compliance. After compliance it was computed to contribute only about 10--20 ppb. At the same time, maximum daily ozone reductions due to Allen NO{sub x} titration of ozone were between 30 and 60 ppb. These benefits will be reduced by 30--50% after Title IV compliance, and are expected to occur within 30 km of the plant. More model grid cells indicated dis-benefits (net ground-level ozone increases) than benefits on three of the four episode days using the Title IV compliance emission rate. Significant ozone dis-benefits were expected because of the well-documented NO titration of ozone within plumes having a high ratio of NO to volatile organic compounds.

  9. Novel Dual-Functional Membrane for Controlling Carbon Dioxide Emissions from Fossil Fuel Power Plants

    SciTech Connect (OSTI)

    C. Brinker; George Xomeritakis; C.-Y. Tsai; Ying-Bing Jiang

    2009-04-30

    CO{sub 2} captured from coal-fired power plants represents three-quarters of the total cost of an entire carbon sequestration process. Conventional amine absorption or cryogenic separation requires high capital investment and is very energy intensive. Our novel membrane process is energy efficient with great potential for economical CO{sub 2} capture. Three classes of microporous sol-gel derived silica-based membranes were developed for selective CO{sub 2} removal under simulated flue gas conditions (SFG), e.g. feed of 10% vol. CO{sub 22} in N{sub 2}, 1 atm total pressure, T = 50-60 C, RH>50%, SO2>10 ppm. A novel class of amine-functional microporous silica membranes was prepared using an amine-derivatized alkoxysilane precursor, exhibiting enhanced (>70) CO{sub 2}:N{sub 2} selectivity in the presence of H{sub 2}O vapor, but its CO{sub 2} permeance was lagging (<1 MPU). Pure siliceous membranes showed higher CO{sub 2} permeance (1.5-2 MPU) but subsequent densification occurred under prolonged SFG conditions. We incorporated NiO in the microporous network up to a loading of Ni:Si = 0.2 to retard densification and achieved CO2 permeance of 0.5 MPU and CO{sub 2}:N{sub 2} selectivity of 50 after 163 h exposure to SFG conditions. However, CO{sub 2} permeance should reach greater than 2.0 MPU in order to achieve the cost of electricity (COE) goal set by DOE. We introduced the atomic layer deposition (ALD), a molecular deposition technique that substantially reduces membrane thickness with intent to improve permeance and selectivity. The deposition technique also allows the incorporation of Ni or Ag cations by proper selection of metallorganic precursors. In addition, preliminary economic analysis provides a sensitivity study on the performance and cost of the proposed membranes for CO{sub 2} capture. Significant progress has been made toward the practical applications for CO{sub 2} capture. (1 MPU = 1.0 cm{sup 3}(STP){center_dot}cm-2{center_dot}min-1{center_dot}atm-1)

  10. Deep Burn: Development of Transuranic Fuel for High-Temperature...

    Office of Scientific and Technical Information (OSTI)

    discusses: (1) Core and Fuel Analysis; (2) Spent Fuel Management; (3) Fuel Cycle Integration of the HTR (high temperature helium-cooled reactor); (4) TRU (transuranic elements) ...

  11. Design and Development of High-Performance Polymer Fuel Cell...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Design and Development of High-Performance Polymer Fuel Cell Membranes Design and Development of High-Performance Polymer Fuel Cell Membranes A presentation to the High Temperature ...

  12. High Temperature BOP and Fuel Processing | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    BOP and Fuel Processing High Temperature BOP and Fuel Processing Presented at the NREL Hydrogen and Fuel Cell Manufacturing R&D Workshop in Washington, DC, August 11-12, 2011. High Temperature BOP and Fuel Processing (4.07 MB) More Documents & Publications Biogas Impurities and Cleanup for Fuel Cells Workshop on Gas Clean-Up for Fuel Cell Applications Fuel Quality Issues in Stationary Fuel Cell Systems

  13. Effects of aqueous effluents from in situ fossil fuel processing technologies on aquatic systems. Annual progress report, January 1-December 31, 1979

    SciTech Connect (OSTI)

    Bergman, H.L.

    1980-01-04

    This is the third annual progress report for a continuing EPA-DOE jointly funded project to evaluate the effects of aqueous effluents from in situ fossil-fuel processing technologies on aquatic biota. The project is organized into four project tasks: (1) literature review; (2) process water screening; (3) methods development; and (4) recommendations. Our Bibliography of aquatic ecosystem effects, analytical methods and treatment technologies for organic compounds in advanced fossil-fuel processing effluents was submitted to the EPA for publication. The bibliography contains 1314 citations indexed by chemicals, keywords, taxa and authors. We estimate that the second bibliography volume will contain approximately 1500 citations and be completed in February. We compiled results from several laboratories of inorganic characterizations of 19 process waters: 55 simulated in situ oil-shale retort waters; and Hanna-3, Hanna-4B 01W and Lawrence Livermore Hoe Creek underground coal gasification condenser waters. These process waters were then compared to a published summary of the analyses from 18 simulated in situ oil-shale retort waters. We completed this year 96-h flow-through toxicity bioassays with fathead minnows and rainbow trout and 48-h flow-through bioassays with Daphnia pulicaria exposed to 5 oil-shale process waters, 1 tar-sand process water, 2 underground coal gasification condenser waters, 1 post-gasification backflood condenser water, as well as 2 bioassays with fossil-fuel process water constituents. The LC/sub 50/ toxicity values for these respective species when exposed to these waters are given in detail. (LTN)

  14. Los Alamos Lab: Fossil Energy & Environment, Home

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Era for Fossil Fuels The Office of Fossil Energy and Environment (FE) is the focal ... Maintaining a prosperous global economy and a healthy environment will require a diverse ...

  15. Boiler and steam generator corrosion: Fossil-fuel power plants. March 1977-December 1989 (A Bibliography from the NTIS data base). Report for March 1977-December 1989

    SciTech Connect (OSTI)

    Not Available

    1990-05-01

    This bibliography contains citations concerning corrosion effects, mechanisms, detection, and inhibition in fossil fuel fired boilers. Fluidized bed combustors and coal gasification are included in the applications. Hot corrosion, thermal mechanical degradation, and intergranular oxidation corrosion studies performed on the water side and hot gas side of heat exchanger tubes and support structures are presented. Coatings and treatment of material to inhibit corrosion are discussed. Corrosion affecting nuclear powered steam generators is examined in a separate bibliography. (Contains 88 citations fully indexed and including a title list.)

  16. Enhanced High Temperature Corrosion Resistance in Advanced Fossil Energy Systems by Nano-Passive Layer Formation

    SciTech Connect (OSTI)

    Arnold R. Marder

    2007-06-14

    Due to their excellent corrosion resistance, iron aluminum alloys are currently being considered for use as weld claddings in fossil fuel fired power plants. The susceptibility to hydrogen cracking of these alloys at higher aluminum concentrations has highlighted the need for research into the effect of chromium additions on the corrosion resistance of lower aluminum alloys. In the present work, three iron aluminum alloys were exposed to simulated coal combustion environments at 500 C and 700 C for both short (100 hours) and long (5,000 hours) isothermal durations. Scanning electron microscopy was used to analyze the corrosion products. All alloys exhibited excellent corrosion resistance in the short term tests. For longer exposures, increasing the aluminum concentration was beneficial to the corrosion resistance. The addition of chromium to the binary iron aluminum alloy prevented the formation iron sulfide and resulted in lower corrosion kinetics. A classification of the corrosion products that developed on these alloys is presented. Scanning transmission electron microscopy (STEM) of the as-corroded coupons revealed that chromium was able to form chromium sulfides only on the higher aluminum alloy, thereby preventing the formation of deleterious iron sulfides. When the aluminum concentration was too low to permit selective oxidation of only aluminum (upon initial exposure to the corrosion environment), the formation of chromium oxide alongside the aluminum oxide led to depletion of chromium beneath the oxide layer. Upon penetration of sulfur through the oxide into this depletion layer, iron sulfides (rather than chromium sulfides) were found to form on the low aluminum alloy. Thus, it was found in this work that the role of chromium on alloy corrosion resistance was strongly effected by the aluminum concentration of the alloy. STEM analysis also revealed the encapsulation of external iron sulfide products with a thin layer of aluminum oxide, which may provide a

  17. RAIL ROUTING - CURRENT PRACTICES FOR SPENT NUCLEAR FUEL AND HIGH...

    Office of Environmental Management (EM)

    Two types of highly radioactive materials are spent nuclear fuel and high-level radioactive waste that resulted from reprocessing spent fuel. Transportation of these radioactive ...

  18. High Temperature Fuel Cell (Phosphoric Acid) Manufacturing R...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Temperature Fuel Cell (Phosphoric Acid) Manufacturing R&D Presented at the NREL ... DC, August 11-12, 2011. PDF icon High Temperature Fuel Cell (Phosphoric Acid) ...

  19. Supercomputers Fuel Global High-Resolution Climate Models

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Supercomputers Fuel Global High-Resolution Climate Models Supercomputers Fuel Global High-Resolution Climate Models Berkeley Lab Researcher Says Climate Science is Entering New ...

  20. New Membranes for High Temperature Proton Exchange Membrane Fuel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High Temperature Proton Exchange Membrane Fuel Cells Based on Heteropoly Acids New Membranes for High Temperature Proton Exchange Membrane Fuel Cells Based on Heteropoly Acids ...

  1. A research needs assessment for the capture, utilization and disposal of carbon dioxide from fossil fuel-fired power plants. Volume 2, Topical reports: Final report

    SciTech Connect (OSTI)

    Not Available

    1993-07-01

    This study, identifies and assesses system approaches in order to prioritize research needs for the capture and non-atmospheric sequestering of a significant portion of the carbon dioxide (CO{sub 2}) emitted from fossil fuel-fired electric power plants (US power plants presently produce about 7% of the world`s CO{sub 2} emissions). The study considers capture technologies applicable either to existing plants or to those that optimistically might be demonstrated on a commercial scale over the next twenty years. The research needs that have high priority in establishing the technical, environmental, and economic feasibility of large-scale capture and disposal of CO{sub 2} from electric power plants are:(1) survey and assess the capacity, cost, and location of potential depleted gas and oil wells that are suitable CO{sub 2} repositories (with the cooperation of the oil and gas industry); (2) conduct research on the feasibility of ocean disposal, with objectives of determining the cost, residence time, and environmental effects for different methods of CO{sub 2} injection; (3) perform an in-depth survey of knowledge concerning the feasibility of using deep, confined aquifers for disposal and, if feasible, identify potential disposal locations (with the cooperation of the oil and gas industry); (4) evaluate, on a common basis, system and design alternatives for integration of CO{sub 2} capture systems with emerging and advanced technologies for power generation; and prepare a conceptual design, an analysis of barrier issues, and a preliminary cost estimate for pipeline networks necessary to transport a significant portion of the CO{sub 2} to potentially feasible disposal locations.

  2. A research needs assessment for the capture, utilization and disposal of carbon dioxide from fossil fuel-fired power plants. Volume 1, Executive summary: Final report

    SciTech Connect (OSTI)

    Not Available

    1993-07-01

    This study identifies and assesses system approaches in order to prioritize research needs for the capture and non-atmospheric sequestering of a significant portion of the carbon dioxide (CO{sub 2}) emitted from fossil fuel-fired electric power plants (US power plants presently produce about 7% of the world`s CO{sub 2} emissions). The study considers capture technologies applicable either to existing plants or to those that optimistically might be demonstrated on a commercial scale over the next twenty years. Specific conclusions are as follows: (1) To implement CO{sub 2} capture and sequestration on a national scale will decrease power plant net efficiencies and significantly increase the cost of electricity. To make responsible societal decisions, accurate and consistent economic and environmental analysis of all alternatives for atmospheric CO{sub 2} mitigation are required. (2) Commercial CO{sub 2} capture technology, though expensive and energy intensive, exists today. (3) The most promising approach to more economical CO{sub 2} capture is to develop power plant systems that facilitate efficient CO{sub 2} capture. (4) While CO{sub 2} disposal in depleted oil and gas reservoirs is feasible today, the ability to dispose of large quantities Of CO{sub 2} is highly uncertain because of both technical and institutional issues. Disposal into the deep ocean or confined aquifers offers the potential for large quantity disposal, but there are technical, safety, liability, and environmental issues to resolve. Therefore, the highest priority research should focus on establishing the feasibility of large scale disposal options.

  3. Fossil-Fired Boilers

    Energy Science and Technology Software Center (OSTI)

    1993-09-23

    Boiler Performance Model (BPM 3.0S) is a set of computer programs developed to analyze the performance of fossil-fired utility boilers. The programs can model a wide variety of boiler designs, and can model coal, oil, or natural gas firing. The programs are intended for use by engineers performing analyses of alternative fuels, alternative operating modes, or boiler modifications.

  4. Development of a New Generation, High Efficiency PEM Fuel Cell...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    a New Generation, High Efficiency PEM Fuel Cell Based, CHP System Development of a New Generation, High Efficiency PEM Fuel Cell Based, CHP System Part of a 100 million fuel cell ...

  5. CO{sub 2}-mitigation measures through reduction of fossil fuel burning in power utilities. Which road to go?

    SciTech Connect (OSTI)

    Kaupp, A.

    1996-12-31

    Five conditions, at minimum, should be examined in the comparative analysis of CO{sub 2}-mitigation options for the power sector. Under the continuing constraint of scarce financial resources for any private or public investment in the power sector, the following combination of requirements characterise a successful CO{sub 2}-mitigation project: (1) Financial attractiveness for private or public investors. (2) Low, or even negative, long range marginal costs per ton of `CO{sub 2} saved`. (3) High impact on CO{sub 2}-mitigation, which indicates a large market potential for the measure. (4) The number of individual investments required to achieve the impact is relatively small. In other words, logistical difficulties in project implementation are minimised. (5) The projects are `socially fair` and have minimal negative impact on any segment of the society. This paper deals with options to reduce carbonaceous fuel burning in the power sector. Part I explains how projects should be selected and classified. Part II describes the technical options. Since reduction of carbonaceous fuel burning may be achieved through Demand Side Management (DSM) and Supply Side Management (SSM) both are treated. Within the context of this paper SSM does not mean to expand power supply as demand grows. It means to economically generate and distribute power as efficiently as possible. In too many instances DSM has degenerated into efficient lighting programs and utility managed incentives and rebate programs. To what extent this is a desirable situation for utilities in Developing Countries that face totally different problems as their counterparts in highly industrialised countries remains to be seen. Which road to go is the topic of this paper.

  6. Synthetic Fuel

    ScienceCinema (OSTI)

    Idaho National Laboratory - Steve Herring, Jim O'Brien, Carl Stoots

    2010-01-08

    Two global energy priorities today are finding environmentally friendly alternatives to fossil fuels, and reducing greenhouse gass Two global energy priorities today are finding environmentally friendly alternatives to fossil fuels, and reducing greenhous

  7. High pressure operation of tubular solid oxide fuel cells and their intergration with gas turbines

    SciTech Connect (OSTI)

    Haynes, C.; Wepfer, W.J.

    1996-12-31

    Fossil fuels continue to be used at a rate greater than that of their natural formation, and the current byproducts from their use are believed to have a detrimental effect on the environment (e.g. global warming). There is thus a significant impetus to have cleaner, more efficient fuel consumption alternatives. Recent progress has led to renewed vigor in the development of fuel cell technology, which has been shown to be capable of producing high efficiencies with relatively benign exhaust products. The tubular solid oxide fuel cell developed by Westinghouse Electric Corporation has shown significant promise. Modeling efforts have been and are underway to optimize and better understand this fuel cell technology. Thus far, the bulk of modeling efforts has been for operation at atmospheric pressure. There is now interest in developing high-efficiency integrated gas turbine/solid oxide fuel cell systems. Such operation of fuel cells would obviously occur at higher pressures. The fuel cells have been successfully modeled under high pressure operation and further investigated as integrated components of an open loop gas turbine cycle.

  8. Status of fossil energy resources: A global perspective

    SciTech Connect (OSTI)

    Balat, M.

    2007-07-01

    This article deals with recently status of global fossil energy sources. Fossil energy sources have been split into three categories: oil,coal, and natural gas. Fossil fuels are highly efficient and cheap. Currently oil is the fastest primary energy source in the world (39% of world energy consumption). Coal will be a major source of energy for the world for the foreseeable future (24% of world energy consumption). In 2030, coal covers 45% of world energy needs. Natural gas is expected to be the fastest growing component of world energy consumption (23% of world energy consumption). Fossil fuel extraction and conversion to usable energy has several environmental impacts. They could be a major contributor to global warming and greenhouse gases and a cause of acid rain; therefore, expensive air pollution controls are required.

  9. Mechanical Analysis of High Power Internally Cooled Annular Fuel...

    Office of Scientific and Technical Information (OSTI)

    Title: Mechanical Analysis of High Power Internally Cooled Annular Fuel Annular fuel with internal flow is proposed to allow higher power density in pressurized water reactors. The ...

  10. Microchannel High-Temperature Recuperator for Fuel Cell Systems

    Broader source: Energy.gov [DOE]

    Fuel cells are electrochemical devices that produce electricity without combustion. Due to their high efficiency and minimal emissions, fuel cells are an attractive option for distributed power...

  11. High Efficiency Solar Fuels Reactor Concept | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solar Fuels Reactor Concept High Efficiency Solar Fuels Reactor Concept This presentation was delivered at the SunShot Concentrating Solar Power (CSP) Program Review 2013, held ...

  12. High Pressure Fuel Storage Cylinders Periodic Inspection and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Storage Cylinders Periodic Inspection and End of Life Issues High Pressure Fuel Storage Cylinders Periodic Inspection and End of Life Issues These slides were presented at the ...

  13. Energy Department Invests $28 Million to Advance Cleaner Fossil...

    Broader source: Energy.gov (indexed) [DOE]

    ... Solid Oxide Fuel Cell Technology An unmanned undersea vehicle (UUV) being deployed ... Fossil Energy-Developed Fuel Cell Technology Being Adapted by Navy for Advanced Unmanned ...

  14. New Polyelectrolyte Materials for High Temperature Fuel Cells | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Polyelectrolyte Materials for High Temperature Fuel Cells New Polyelectrolyte Materials for High Temperature Fuel Cells Part of a $100 million fuel cell award announced by DOE Secretary Bodman on Oct. 25, 2006. 1_lbnl.pdf (20.59 KB) More Documents & Publications Polyelectrolyte Materials for High Temperature Fuel Cells Nitrided Metallic Bipolar Plates Durable Low Cost Improved Fuel Cell Membranes

  15. Fossil | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sources » Fossil Fossil June 22, 2016 Adv. Fossil Solicitation Part II Due Date ADVANCED FOSSIL ENERGY PROJECTS SOLICITATION PART II DUE DATE Learn more about the Advanced Fossil Energy Projects Solicitation. June 22, 2016 Adv. Fossil Solicitation Part I Due Date ADVANCED FOSSIL ENERGY PROJECTS SOLICITATION PART I DUE DATE Learn more about the Advanced Fossil Energy Projects Solicitation. June 22, 2016 Adv. Fossil Solicitation Part I Due Date ADVANCED FOSSIL ENERGY PROJECTS SOLICITATION PART I

  16. Fossil-fuel power plants: Computer systems for power plant control, maintenance, and operation. October 1976-December 1989 (A Bibliography from the COMPENDEX data base). Report for October 1976-December 1989

    SciTech Connect (OSTI)

    Not Available

    1990-02-01

    This bibliography contains citations concerning fossil-fuel power plant computer systems. Minicomputer and microcomputer systems used for monitoring, process control, performance calculations, alarming, and administrative applications are discussed. Topics emphasize power plant control, maintenance and operation. (Contains 240 citations fully indexed and including a title list.)

  17. Polyelectrolyte Materials for High Temperature Fuel Cells

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Polyelectrolyte Materials for High 3M (3M) Temperature Fuel Cells John B. Kerr Lawrence Berkeley National Laboratory (LBNL) Collaborators: Los Alamos National Laboratory (LANL). February 13, 2007 This presentation does not contain any proprietary or confidential information Team Members: Nitash Blasara, Rachel Segalman, Adam Weber (LBNL). Bryan Pivovar, James Boncella (LANL) Steve Hamrock Objectives * Investigate the use of solid polyelectrolyte proton conductors that do not require the presence

  18. Novel Materials for High Efficiency Direct Methanol Fuel Cells | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Materials for High Efficiency Direct Methanol Fuel Cells Novel Materials for High Efficiency Direct Methanol Fuel Cells Presented at the Department of Energy Fuel Cell Projects Kickoff Meeting, September 1 - October 1, 2009 roger_arkema_kickoff.pdf (394.12 KB) More Documents & Publications Polyvinylidene Fluoride-Based Membranes for Direct Methanol Fuel Cell Applications Advance Patent Waiver W(A)2010-028 Durable, Low Cost, Improved Fuel Cell Membranes

  19. High performance internal reforming unit for high temperature fuel cells

    DOE Patents [OSTI]

    Ma, Zhiwen; Venkataraman, Ramakrishnan; Novacco, Lawrence J.

    2008-10-07

    A fuel reformer having an enclosure with first and second opposing surfaces, a sidewall connecting the first and second opposing surfaces and an inlet port and an outlet port in the sidewall. A plate assembly supporting a catalyst and baffles are also disposed in the enclosure. A main baffle extends into the enclosure from a point of the sidewall between the inlet and outlet ports. The main baffle cooperates with the enclosure and the plate assembly to establish a path for the flow of fuel gas through the reformer from the inlet port to the outlet port. At least a first directing baffle extends in the enclosure from one of the sidewall and the main baffle and cooperates with the plate assembly and the enclosure to alter the gas flow path. Desired graded catalyst loading pattern has been defined for optimized thermal management for the internal reforming high temperature fuel cells so as to achieve high cell performance.

  20. Natural Gas Study Guide - High School | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Natural Gas Study Guide - High School Natural Gas Study Guide - High School (434.33 KB) More Documents & Publications Natural Gas Study Guide - Middle School Fossil Fuels Study ...

  1. High Octane Fuels Can Make Better Use of Renewable Transportation Fuels

    Broader source: Energy.gov [DOE]

    Breakout Session 1C—Fostering Technology Adoption I: Building the Market for Renewables with High Octane Fuels High Octane Fuels Can Make Better Use of Renewable Transportation Fuels Brian West, Deputy Director, Engines and Emissions Research Center; Oak Ridge National Laboratory

  2. Fuel Effects on Mixing-Controlled Combustion Strategies for High...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mixing-Controlled Combustion Strategies for High-Efficiency Clean-Combustion Engines Fuel Effects on Mixing-Controlled Combustion Strategies for High-Efficiency Clean-Combustion ...

  3. Next-generation nuclear fuel withstands high-temperature accident...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Next-generation nuclear fuel withstands high-temperature accident conditions IDAHO FALLS - A safer and more efficient nuclear fuel is on the horizon. A team of researchers at the ...

  4. Evaluation of vost and semivost methods for halogenated compounds in the Clean Air Act amendments title III. Validation study at fossil fuel plant

    SciTech Connect (OSTI)

    Jackson, M.D.; Knoll, J.E.; Midgett, M.R.; McGaughey, J.F.; Bursey, J.T.

    1993-01-01

    The Clean Air Act Amendments of 1990 (CAAA), Title III, present a need for stationary source sampling and analytical methods for the list of 189 toxic air pollutants. The US Environmental Protection Agency (EPA) has used VOST and SemiVOST sampling and analytical methods for a wide variety of volatile and semivolatile organic compounds in the past, but these methodologies have been completely validated for only a few of the organic compounds. The applicability of VOST and SemiVOST techniques to the halogenated organic compounds listed in Title III of the Clean Air Act Amendments of 1990 has been evaluated under laboratory conditions for chromatographic separation, mass spectrometric response, sorbent recovery and analytical method detection limit. Dynamic spiking techniques for the sampling trains (both gaseous and liquid dynamic spiking) were also evaluated in the laboratory. In the study, the VOST and SemiVOST methods were evaluated in the field at a fossil fuel power plant. The source was selected to provide actual stationary source emissions with the compounds of interest present in trace amounts or not present. The paper presents the results of the field validation of the VOST and SemiVOST sampling and analytical methods.

  5. Sensitivity of global-scale climate change attribution results to inclusion of fossil fuel black carbon aerosol - article no. L14701

    SciTech Connect (OSTI)

    Jones, G.S.; Jones, A.; Roberts, D.L.; Stott, P.A.; Williams, K.D.

    2005-07-16

    It is likely that greenhouse gas emissions caused most of the global mean warming observed during the 20th century, and that sulphate aerosols counteracted this warming to some extent, by reflecting solar radiation to space and thereby cooling the planet. However, the importance of another aerosol, namely black carbon, could be underestimated. Here we include fossil fuel black carbon aerosol in a detection and attribution analysis with greenhouse gas and sulphate aerosols. We find that most of the warming of the 20th Century is attributable to changes in greenhouse gases offset by net aerosol cooling. However the pattern of temperature change due to black carbon is currently indistinguishable from the sulphate aerosol pattern of temperature change. The attribution of temperature change due to greenhouse gases is not sensitive to the inclusion of black carbon. We can be confident about the overall attribution of total aerosols, but less so about the contributions of black carbon emissions to 20th century climate change. This work presents no evidence that black carbon aerosol forcing outweighed the cooling due to sulphate aerosol.

  6. Materials for High Pressure Fuel Injection Systems

    Broader source: Energy.gov [DOE]

    2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation

  7. Fossil-fuel processing technical/professional services: comparison of Fischer-Tropsch reactor systems. Phase I, final report

    SciTech Connect (OSTI)

    Thompson, G.J.; Riekena, M.L.; Vickers, A.G.

    1981-09-01

    The Fischer-Tropsch reaction was commercialized in Germany and used to produce military fuels in fixed bed reactors. It was recognized from the start that this reactor system had severe operating and yield limitations and alternative reactor systems were sought. In 1955 the Sasol I complex, using an entrained bed (Synthol) reactor system, was started up in South Africa. Although this reactor was a definite improvement and is still operating, the literature is filled with proponents of other reactor systems, each claiming its own advantages. This report provides a summary of the results of a study to compare the development potential of three of these reactor systems with the commercially operating Synthol-entrained bed reactor system. The commercial Synthol reactor is used as a benchmark against which the development potential of the other three reactors can be compared. Most of the information on which this study is based was supplied by the M.W. Kellogg Co. No information beyond that in the literature on the operation of the Synthol reactor system was available for consideration in preparing this study, nor were any details of the changes made to the original Synthol system to overcome the operating problems reported in the literature. Because of conflicting claims and results found in the literature, it was decided to concentrate a large part of this study on a kinetic analysis of the reactor systems, in order to provide a theoretical analysis of intrinsic strengths and weaknesses of the reactors unclouded by different catalysts, operating conditions and feed compositions. The remainder of the study considers the physical attributes of the four reactor systems and compares their respective investment costs, yields, catalyst requirements and thermal efficiencies from simplified conceptual designs.

  8. High Performance Fuel Desing for Next Generation Pressurized Water Reactors

    SciTech Connect (OSTI)

    Mujid S. Kazimi; Pavel Hejzlar

    2006-01-31

    The use of internally and externally cooled annular fule rods for high power density Pressurized Water Reactors is assessed. The assessment included steady state and transient thermal conditions, neutronic and fuel management requirements, mechanical vibration issues, fuel performance issues, fuel fabrication methods and econmic assessment. The investigation was donducted by a team from MIT, Westinghouse, Gamma Engineering, Framatome ANP, and AECL. The analyses led to the conclusion that raising the power density by 50% may be possible with this advanced fuel. Even at the 150% power level, the fuel temperature would be a few hundred degrees lower than the current fuel temperatre. Significant economic and safety advantages can be obtained by using this fuel in new reactors. Switching to this type of fuel for existing reactors would yield safety advantages, but the economic return is dependent on the duration of plant shutdown to accommodate higher power production. The main feasiblity issue for the high power performance appears to be the potential for uneven splitting of heat flux between the inner and outer fuel surfaces due to premature closure of the outer fuel-cladding gap. This could be overcome by using a very narrow gap for the inner fuel surface and/or the spraying of a crushable zirconium oxide film at the fuel pellet outer surface. An alternative fuel manufacturing approach using vobropacking was also investigated but appears to yield lower than desirable fuel density.

  9. DOE - Fossil Energy: A Brief Overview of Coal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Overview Fossil Energy Study Guides Coal - General Info America has more coal than any other fossil fuel resource. The United States also has more coal reserves than any other ...

  10. High power density solid oxide fuel cells

    DOE Patents [OSTI]

    Pham, Ai Quoc; Glass, Robert S.

    2004-10-12

    A method for producing ultra-high power density solid oxide fuel cells (SOFCs). The method involves the formation of a multilayer structure cells wherein a buffer layer of doped-ceria is deposited intermediate a zirconia electrolyte and a cobalt iron based electrode using a colloidal spray deposition (CSD) technique. For example, a cobalt iron based cathode composed of (La,Sr)(Co,Fe)O (LSCF) may be deposited on a zirconia electrolyte via a buffer layer of doped-ceria deposited by the CSD technique. The thus formed SOFC have a power density of 1400 mW/cm.sup.2 at 600.degree. C. and 900 mW/cm.sup.2 at 700.degree. C. which constitutes a 2-3 times increased in power density over conventionally produced SOFCs.

  11. Highly Efficient, Scalable Microbial Fuel Cell - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen and Fuel Cell Hydrogen and Fuel Cell Biomass and Biofuels Biomass and Biofuels Advanced Materials Advanced Materials Find More Like This Return to Search Highly Efficient, Scalable Microbial Fuel Cell University of Colorado Contact CU About This Technology Publications: PDF Document Publication CU2773D (Microbial Fuel Cell) Marketing Summary (129 KB) Technology Marketing Summary With present day environmental and energy concerns rising, the development of environmentally friendly energy

  12. Development of Advanced High Temperature Fuel Cell Membranes | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Advanced High Temperature Fuel Cell Membranes Development of Advanced High Temperature Fuel Cell Membranes Presentation on Development of Advanced High Temperature Fuel Cell Membranes to the High Temperature Membrane Working Group Meeting held in Arlington, Virginia, May 26,2005. htmwg05_irvin_doe_review.pdf (108.37 KB) More Documents & Publications 2006 DOE Hydrogen Program Poly (p-phenylene Sulfonic Acid)s with Frozen-in Free Volume for use in High Temperature Fuel Cells

  13. Fission gas induced fuel swelling in low and medium burnup fuel during high temperature transients. [PWR

    SciTech Connect (OSTI)

    Vinjamuri, K.

    1980-01-01

    The behavior of light water reactor fuel elements under postulated accident conditions is being studied by the EG and G Idaho, Inc., Thermal Fuels Behavior Program for the Nuclear Regulatory Commission. As a part of this program, unirradiated and previously irradiated, pressurized-water-reactor type fuel rods were tested under power-cooling-mismatch (PCM) conditions in the Power Burst Facility (PBF). During these integral in-reactor experiments, film boiling was produced on the fuel rods which created high fuel and cladding temperatures. Fuel rod diameters increased in the film boiling region to a greater extent for irradiated rods than for unirradiated rods. The purpose of the study was to investigate and assess the fuel swelling which caused the fuel rod diameter increases and to evaluate the ability of an analytical code, the Gas Release and Swelling Subroutine - Steady-State and Transient (GRASS-SST), to predict the results.

  14. Micronized coal-fired retrofit system for SO{sub x} reduction - Krakow Clean Fossil Fuels and Energy Efficiency Program.

    SciTech Connect (OSTI)

    1996-09-30

    the project proposes to install a new TCS micronized coal-fired heating plant for the Produkcja I Hodowla Roslin Ogrodniczych (PHRO) Greenhouse Complex, Krzeszowice, Poland (about 20 miles west of Krakow). PHRO currently utilizes 14 heavy oil-fired boilers to produce heat for its greenhouse facilities and also home heating to several adjacent apartment housing complexes. The boilers currently burn a high-sulfur content heavy crude oil, called Mazute. The micronized coal fired boiler would (1) provide a significant portion of the heat for PHRO and a portion of the adjacent apartment housing complexes, (2) dramatically reduce sulfur dioxide air pollution emission, while satisfying new Polish air regulations, and (3) provide attractive savings to PHRO, based on the quantity of displaced oil.

  15. Microchannel High-Temperature Recuperator for Fuel Cell Systems

    SciTech Connect (OSTI)

    2010-02-01

    This factsheet describes a research project whose goal is to build an efficient, microchannel-based waste heat recuperator for a high-temperature fuel cell system.

  16. On the flexibility of high temperature reactor cores for high-and low-enriched fuel

    SciTech Connect (OSTI)

    Bzandes, S.; Lonhert, G.

    1982-07-01

    The operational flexibility of a high temperature reactor (HTR) is not restricted to either a low- or a high-enriched fuel cycle. Both fuel cycles are possible for the same core design. The fuel cycle cost is, however, penalized for low-enriched fuel; in addition, higher uranium consumption is required. Hence, an HTR is most economical to operate in the high-enriched thorium-uranium fuel cycle.

  17. Opportunity fuels

    SciTech Connect (OSTI)

    Lutwen, R.C.

    1994-12-31

    Opportunity fuels - fuels that can be converted to other forms of energy at lower cost than standard fossil fuels - are discussed in outline form. The type and source of fuels, types of fuels, combustability, methods of combustion, refinery wastes, petroleum coke, garbage fuels, wood wastes, tires, and economics are discussed.

  18. Fabrication of high exposure nuclear fuel pellets

    DOE Patents [OSTI]

    Frederickson, James R.

    1987-01-01

    A method is disclosed for making a fuel pellet for a nuclear reactor. A mixture is prepared of PuO.sub.2 and UO.sub.2 powders, where the mixture contains at least about 30% PuO.sub.2, and where at least about 12% of the Pu is the Pu.sup.240 isotope. To this mixture is added about 0.3 to about 5% of a binder having a melting point of at least about 250.degree. F. The mixture is pressed to form a slug and the slug is granulated. Up to about 4.7% of a lubricant having a melting point of at least about 330.degree. F. is added to the granulated slug. Both the binder and the lubricant are selected from a group consisting of polyvinyl carboxylate, polyvinyl alcohol, naturally occurring high molecular weight cellulosic polymers, chemically modified high molecular weight cellulosic polymers, and mixtures thereof. The mixture is pressed to form a pellet and the pellet is sintered.

  19. DOE - Fossil Energy: Introduction to Coal Technology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Introduction An Energy Lesson Cleaning Up Coal COAL is our most abundant fossil fuel. The United States has more coal than the rest of the world has oil. There is still enough coal ...

  20. Microchannel High-Temperature Recuperator for Fuel Cell Systems - Fact

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sheet, 2014 | Department of Energy Microchannel High-Temperature Recuperator for Fuel Cell Systems - Fact Sheet, 2014 Microchannel High-Temperature Recuperator for Fuel Cell Systems - Fact Sheet, 2014 FuelCell Energy, Inc., in collaboration with Pacific Northwest National Laboratory, the Oregon State University Materials Institute, the Microproducts Breakthrough Institute, and the Oregon Nanoscience and Materials Institute, developed an efficient, microchannel-based waste heat recuperator

  1. A novel technique to control high temperature materials degradation in fossil plants

    SciTech Connect (OSTI)

    Gonzalez-Rodriguez, J.G.; Porcayo-Calderon, J.; Martinez-Villafane, A.

    1995-11-01

    High temperature corrosion of superheater (SH) and, specially, reheater (RH) is strongly dependent on metal temperature. In this work, a way to continuously monitor the metal temperature of SH or RH, elements developed by the Instituto de Investigaciones Electricas (IIE) is described and the effects of operating parameters on metal temperature are evaluated. Also, the effects the steam-generator design and metal temperature on the corrosion rates have been investigated. In some steam generators, corrosion rates were reduced from 0.7 to 0.2 mm/y by changing the tube material and reducing the metal temperature. Also, the effect of metal temperature on the residual life of a 347H tube in a 158MW steam generator is evaluated. It is concluded that metal temperature is the most important parameter in controlling the high-temperature materials behavior in boiler environments.

  2. Development of Erbia-bearing Super High Burnup Fuel

    SciTech Connect (OSTI)

    Akio, Yamamoto; Toshikazu, Takeda; Hironobu, Unesaki; Masaaki, Mori; Masatoshi Yamasaki

    2006-07-01

    In this paper, concept and development plan of the Erbia (Er{sub 2}O{sub 3})-bearing super high burnup (Er-SHB) fuel for LWRs are described. In order to reduce the number of spent fuel assemblies, utilization of high burnup fuels with higher uranium enrichment is effective. However, the upper limitation of enrichment for LWR fuels is 5 wt% and current advanced fuel assemblies for LWRs are already reaching this limit. Though various efforts to overcome the 5 wt% enrichment limit have been undergoing, it will require considerable cost that may offset the economic benefit of high burnup fuels. We are proposing another pathway. By adding low content ({>=}0.2 wt%) of Erbia in all UO{sub 2} powder, reactivity of high enrichment (>5 wt%) fuel is suppressed under that of current fuel assemblies, i.e. we leverage the negative reactivity credit of Erbia. Since Erbia is mixed into UO{sub 2} powder just after the re-conversion, we can avoid most of the criticality safety issues appearing in the front-end stream. Namely, major improvements and re-licensing for equipments in transportation, storage and fabrication process will not be necessary. Therefore, the Er-SHB fuel will significantly contribute to reduction of fuel cycle cost. (authors)

  3. HIGH EFFICIENCY GENERATION OF HYDROGEN FUELS USING NUCLEAR POWER FINAL RECHNICAL REPORT FOR THE PERIOD AUGUST 1, 1999 THROUGH SEPTEMBER 30, 2002 REV. 1

    SciTech Connect (OSTI)

    BROWN,LC; BESENBRUCH,GE; LENTSCH, RD; SCHULTZ,KR; FUNK,JF; PICKARD,PS; MARSHALL,AC; SHOWALTER,SK

    2003-12-01

    OAK-B135 Combustion of fossil fuels, used to power transportation, generate electricity, heat homes and fuel industry provides 86% of the world's energy [1-1,1-2]. Drawbacks to fossil fuel utilization include limited supply, pollution, and carbon dioxide emissions. Carbon dioxide emissions, thought to be responsible for global warming, are now the subject of international treaties [1-3,1-4]. Together, these drawbacks argue for the replacement of fossil fuels with a less-polluting potentially renewable primary energy such as nuclear energy. Conventional nuclear plants readily generate electric power but fossil fuels are firmly entrenched in the transportation sector. Hydrogen is an environmentally attractive transportation fuel that has the potential to displace fossil fuels. Hydrogen will be particularly advantageous when coupled with fuel cells. Fuel cells have higher efficiency than conventional battery/internal combustion engine combinations and do not produce nitrogen oxides during low-temperature operation. Contemporary hydrogen production is primarily based on fossil fuels and most specifically on natural gas. When hydrogen is produced using energy derived from fossil fuels, there is little or no environmental advantage. There is currently no large scale, cost-effective, environmentally attractive hydrogen production process available for commercialization, nor has such a process been identified. The objective of this work is to find an economically feasible process for the production of hydrogen, by nuclear means, using an advanced high-temperature nuclear reactor as the primary energy source. Hydrogen production by thermochemical water-splitting (Appendix A), a chemical process that accomplishes the decomposition of water into hydrogen and oxygen using only heat or, in the case of a hybrid thermochemical process, by a combination of heat and electrolysis, could meet these goals. Hydrogen produced from fossil fuels has trace contaminants (primarily carbon

  4. Transitioning from fossil-fueled ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Chemical Reactions That lithium-ion batteries lose their ... Simulation and Experiment Sandia's BATLab is a leading facility for investigating and understanding battery ...

  5. High Efficiency Fuel Reactivity Controlled Compression Ignition...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    An optimized dual-fuel PCCI concept, RCCI, is proposed. deer10reitz.pdf (960.46 KB) More Documents & Publications Effect of Compression Ratio and Piston Geometry on RCCI load ...

  6. Molten salt fuels with high plutonium solubility

    DOE Patents [OSTI]

    Moir, Ralph W; Turchi, Patrice E.A.; Shaw, Henry F; Kaufman, Larry

    2013-08-13

    The present invention includes a composition of LiF--ThF.sub.4--UF.sub.4--PuF.sub.3 for use as a fuel in a nuclear engine.

  7. Premixed direct injection nozzle for highly reactive fuels

    DOE Patents [OSTI]

    Ziminsky, Willy Steve; Johnson, Thomas Edward; Lacy, Benjamin Paul; York, William David; Uhm, Jong Ho; Zuo, Baifang

    2013-09-24

    A fuel/air mixing tube for use in a fuel/air mixing tube bundle is provided. The fuel/air mixing tube includes an outer tube wall extending axially along a tube axis between an inlet end and an exit end, the outer tube wall having a thickness extending between an inner tube surface having a inner diameter and an outer tube surface having an outer tube diameter. The tube further includes at least one fuel injection hole having a fuel injection hole diameter extending through the outer tube wall, the fuel injection hole having an injection angle relative to the tube axis. The invention provides good fuel air mixing with low combustion generated NOx and low flow pressure loss translating to a high gas turbine efficiency, that is durable, and resistant to flame holding and flash back.

  8. Status of high-density fuel plates fabrication

    SciTech Connect (OSTI)

    Wiencek, T.C.; Domagala, R.F.; Thresh, H.R.

    1989-09-01

    Progress has continued on the fabrication of fuel plates with fuel zone loadings approaching 9gU/cm{sup 3}. Using Hot Isostatic Pressing (HIPping) successful diffusion bonds have been made with 110 Al and 6061 Al alloys. These bonds demonstrated the most critical processing step for proof-of-concept hardware. Two types of prototype highly-loaded fuel plates have been fabricated. First, a fuel plate in which 0.030 in. (0.76 mm) uranium compound wires are bonded within an aluminum cladding and second, a dispersion fuel plate with uniform cladding and fuel zone thickness. The successful fabrication of these fuel plates derives from the unique ability of the HIPping process to produce diffusion bonds with minimal deformation. 2 refs., 3 figs.

  9. Launching the Next Wave of Clean Fossil Energy Innovation | Department...

    Broader source: Energy.gov (indexed) [DOE]

    an advanced power plant that cuts carbon pollution, or building an efficient microgrid network that better utilizes fossil fuels, loan guarantees under this solicitation...

  10. Statement of Christopher Smith Assistant Secretary for Fossil...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    to market revolutionary methods and technologies that ... with fossil fuel power plants, including biological ... production systems into a coal-fired power plant to study the ...

  11. Fuel Flexible Combustion Systems for High-Efficiency Utilization of Opportunity Fuels in Gas Turbines

    SciTech Connect (OSTI)

    Venkatesan, Krishna

    2011-11-30

    The purpose of this program was to develop low-emissions, efficient fuel-flexible combustion technology which enables operation of a given gas turbine on a wider range of opportunity fuels that lie outside of current natural gas-centered fuel specifications. The program encompasses a selection of important, representative fuels of opportunity for gas turbines with widely varying fundamental properties of combustion. The research program covers conceptual and detailed combustor design, fabrication, and testing of retrofitable and/or novel fuel-flexible gas turbine combustor hardware, specifically advanced fuel nozzle technology, at full-scale gas turbine combustor conditions. This project was performed over the period of October 2008 through September 2011 under Cooperative Agreement DE-FC26-08NT05868 for the U.S. Department of Energy/National Energy Technology Laboratory (USDOE/NETL) entitled "Fuel Flexible Combustion Systems for High-Efficiency Utilization of Opportunity Fuels in Gas Turbines". The overall objective of this program was met with great success. GE was able to successfully demonstrate the operability of two fuel-flexible combustion nozzles over a wide range of opportunity fuels at heavy-duty gas turbine conditions while meeting emissions goals. The GE MS6000B ("6B") gas turbine engine was chosen as the target platform for new fuel-flexible premixer development. Comprehensive conceptual design and analysis of new fuel-flexible premixing nozzles were undertaken. Gas turbine cycle models and detailed flow network models of the combustor provide the premixer conditions (temperature, pressure, pressure drops, velocities, and air flow splits) and illustrate the impact of widely varying fuel flow rates on the combustor. Detailed chemical kinetic mechanisms were employed to compare some fundamental combustion characteristics of the target fuels, including flame speeds and lean blow-out behavior. Perfectly premixed combustion experiments were conducted to

  12. High Efficiency Fuel Reactivity Controlled Compression Ignition Combustion

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Fuel Reactivity Controlled Compression Ignition Combustion High Efficiency Fuel Reactivity Controlled Compression Ignition Combustion An optimized dual-fuel PCCI concept, RCCI, is proposed. deer10_reitz.pdf (960.46 KB) More Documents & Publications Effect of Compression Ratio and Piston Geometry on RCCI load limit Optimization of Advanced Diesel Engine Combustion Strategies Comparison of Conventional Diesel and Reactivity Controlled Compression Ignition (RCCI)

  13. Thermal Analysis of ZPPR High Pu Content Stored Fuel

    SciTech Connect (OSTI)

    Charles W. Solbrig; Chad Pope; Jason Andrus

    2014-09-01

    This paper estimates the temperature of high Pu content ZPPR fuel while in storage to determine the probablilty of fuel damage during storage. The Zero Power Physics Reactor (ZPPR) is an experimental reactor which has been decomissioned. It ran only at extremely low power, for testing nuclear reactor designs and was operated as a criticality facility from April 18, 1969 until decommissioned in 1990. Its fuel was manufactured in 1967 and has been in storage since the reactor was decomissioned. Heat is generated in the fuel due to Pu and Am decay and is a concern for possible fuel damage. Any damage to the cladding would be expected to lead to the fuel hydriding and oxidizing over a long period of storage as was described in the analysis of the damage to the ZPPR uranium fuel resulting in the fuel becoming unuseable and a large potential source of contamination. (Ref. Solbrig, 1994). A series of computer runs were made to scope out the range of temperatures that can occur in the ZPPR fuel in storage. The maximum calculated conservative fuel temperature is high (292 degrees C [558 degrees F]) in spite of the fact that the fuel element heat generation rates seem quite low, between 35 and 10 W for containers (called clamshells) full of fuel. However, the ZPPR storage bins, built for safeguards, are very effective insulators. The calculated clamshells and the cavity doors temperatures are also high. No record exists of people receiving skin burns by touching the cavity doors or clamshells, which indicates the computed temperatures may be higher than actual. (Note, gloves are worn when handling hotter clamshells.) Given the high calculated temperatures, a cursory measurement program was conducted to calibrate the calculated results. The measurement of bin doors, cavity doors, and clamshell temperatures would be easy to make if it were not for regulations resulting from security and potential contamination. Due to conservative assumptions in the model like high heat

  14. The Fuel Accident Condition Simulator (FACS) furnace system for high temperature performance testing of VHTR fuel

    SciTech Connect (OSTI)

    Paul A. Demkowicz; David V. Laug; Dawn M. Scates; Edward L. Reber; Lyle G. Roybal; John B. Walter; Jason M. Harp; Robert N. Morris

    2012-10-01

    The AGR-1 irradiation of TRISO-coated particle fuel specimens was recently completed and represents the most successful such irradiation in US history, reaching peak burnups of greater than 19% FIMA with zero failures out of 300,000 particles. An extensive post-irradiation examination (PIE) campaign will be conducted on the AGR-1 fuel in order to characterize the irradiated fuel properties, assess the in-pile fuel performance in terms of coating integrity and fission metals release, and determine the fission product retention behavior during high temperature safety testing. A new furnace system has been designed, built, and tested to perform high temperature accident tests. The Fuel Accident Condition Simulator furnace system is designed to heat fuel specimens at temperatures up to 2000 degrees C in helium while monitoring the release of volatile fission metals (e.g. Cs, Ag, Sr, and Eu), iodine, and fission gases (Kr, Xe). Fission gases released from the fuel to the sweep gas are monitored in real time using dual cryogenic traps fitted with high purity germanium detectors. Condensable fission products are collected on a plate attached to a water-cooled cold finger that can be exchanged periodically without interrupting the test. Analysis of fission products on the condensation plates involves dry gamma counting followed by chemical analysis of selected isotopes. This paper will describe design and operational details of the Fuel Accident Condition Simulator furnace system and the associated fission gas monitoring system, as well as preliminary system calibration results.

  15. New Membranes for High Temperature Proton Exchange Membrane Fuel Cells

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Based on Heteropoly Acids | Department of Energy High Temperature Proton Exchange Membrane Fuel Cells Based on Heteropoly Acids New Membranes for High Temperature Proton Exchange Membrane Fuel Cells Based on Heteropoly Acids "Summary of Colorado School of Mines heteropolyacid research presented to the High Temperature Membrane Working Group Meeting, Orlando FL, October 17, 2003 " htwgf_fall2003.pdf (4.98 MB) More Documents & Publications Novel Approaches to Immobilized

  16. High performance, high durability non-precious metal fuel cell catalysts

    DOE Patents [OSTI]

    Wood, Thomas E.; Atanasoski, Radoslav; Schmoeckel, Alison K.

    2016-03-15

    This invention relates to non-precious metal fuel cell cathode catalysts, fuel cells that contain these catalysts, and methods of making the same. The fuel cell cathode catalysts are highly nitrogenated carbon materials that can contain a transition metal. The highly nitrogenated carbon materials can be supported on a nanoparticle substrate.

  17. Novel Modified Optical Fibers for High Temperature In-Situ Miniaturized Gas Sensors in Advanced Fossil Energy Systems

    SciTech Connect (OSTI)

    Pickrell, Gary; Scott, Brian

    2014-06-30

    This report covers the technical progress on the program “Novel Modified Optical Fibers for High Temperature In-Situ Miniaturized Gas Sensors in Advanced Fossil Energy Systems”, funded by the National Energy Technology Laboratory of the U.S. Department of Energy, and performed by the Materials Science & Engineering and Electrical & Computer Engineering Departments at Virginia Tech, and summarizes technical progress from July 1st, 2005 –June 30th, 2014. The objective of this program was to develop novel fiber materials for high temperature gas sensors based on evanescent wave absorption in optical fibers. This project focused on two primary areas: the study of a sapphire photonic crystal fiber (SPCF) for operation at high temperature and long wavelengths, and a porous glass based fiber optic sensor for gas detection. The sapphire component of the project focused on the development of a sapphire photonic crystal fiber, modeling of the new structures, fabrication of the optimal structure, development of a long wavelength interrogation system, testing of the optical properties, and gas and temperature testing of the final sensor. The fabrication of the 6 rod SPCF gap bundle (diameter of 70μm) with a hollow core was successfully constructed with lead-in and lead-out 50μm diameter fiber along with transmission and gas detection testing. Testing of the sapphire photonic crystal fiber sensor capabilities with the developed long wavelength optical system showed the ability to detect CO2 at or below 1000ppm at temperatures up to 1000°C. Work on the porous glass sensor focused on the development of a porous clad solid core optical fiber, a hollow core waveguide, gas detection capabilities at room and high temperature, simultaneous gas species detection, suitable joining technologies for the lead-in and lead-out fibers and the porous sensor, sensor system sensitivity improvement, signal processing improvement, relationship between pore structure and fiber

  18. Analysis of BWR high burnup fuel in LOCA conditions

    SciTech Connect (OSTI)

    Garcia Sedano, Pablo; Dey Navarro, Jose Manuel; Gallego Cabezon, Ines; Orive Moreno, Raul

    2004-07-01

    High Burnup Fuel Behaviour has been growing in importance since middle 80's when pellet microstructure changes (rim effect) and cladding oxidation rates increase were observed. Later on, Cadarache reactivity tests revealed cladding integrity failures below safety limits. These phenomena, occurred at high burnup, stressed the necessity of having a wide experimental data base that would allow to dispose non-extrapolated data of material properties submitted to higher burnups than 40000 MWd/TM and data of new materials at the same time. One of the objectives of the EPRI's Fuel Reliability Program is to establish the bases for the licensing of nuclear fuel to burnup levels beyond the current licensed value of 62 GWd/MTU rod average burnup. The technical bases to support those high burnup levels are being developed. One of the licensing points of concern is the behaviour of the high burnup fuel in LOCA conditions. To respond to this concern a series of LOCA experiments are being performed at Argonne National Laboratory using fuel rods from Limerick NPP at 57 GWd/TM and H.B. Robinson at 67 GWd/MTU. When the ANL tests have been finished, a conservative Peak Cladding Temperature/ Equivalent Cladding Reacted (PCT/ECR) limit will be determine from the residual ductility tests to be applied to the high burnup fuel. This makes necessary to determine the behaviour of the high burnup fuel in LOCA conditions and to determine the available safety margin. In licensing LOCA calculations, corresponding to present core designs and future core designs, the calculated PCT and ECR values as a function of the fuel burnup could be used to determine the relative severity of LOCA for the high burnup fuel. This report presents the LOCA analyses performed by IBERDROLA (Spanish utility), using results from the Cofrentes NPP (BWR-6) LOCA evaluations. (authors)

  19. HIGH ENERGY LIQUID FUELS FROM PLANTS

    SciTech Connect (OSTI)

    Nemethy, E. K.; Otvos, J. W.; Calvin, M.

    1980-10-01

    The heptane extract of Euphorbia lathyris has a low oxygen content and a heat valve of 42 MJ/kg which is comparable to that of crude oil (44 MJ/kg). These qualities indicate a potential for use as fuel or chemical feedstock material. Therefore we have investigated the chemical composition of this fraction in some detail. Since the amoun of the methanol fraction is quite substantial we have also identified the major components of this fraction.

  20. High temperature solid electrolyte fuel cell configurations and interconnections

    DOE Patents [OSTI]

    Isenberg, Arnold O.

    1984-01-01

    High temperature fuel cell configurations and interconnections are made including annular cells having a solid electrolyte sandwiched between thin film electrodes. The cells are electrically interconnected along an elongated axial outer surface.

  1. High power density fuel cell stack development for automotive applications

    SciTech Connect (OSTI)

    Pow, R.; Reindl, M.; Tilmetz, W.

    1996-12-31

    This paper describes the joint development by Daimler-Benz and Ballard Power Systems of a high power-density fuel cell stack and its demonstration in a 6-passenger Minivan.

  2. 2012 Fuel Economy of New Vehicles Sets Record High: EPA

    Broader source: Energy.gov [DOE]

    The U.S. Environmental Protection Agency (EPA) reported that model year 2012 vehicles achieved an all-time high fuel economy average of 23.6 miles per gallon.

  3. Materials and Modules for Low Cost, High Performance Fuel Cell...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Advance Patent Waiver W(A)2010-041 Kick-Off Meeting for New Fuel Cell Projects CARISMA: A Networking Project for High Temperature PEMFC MEA Activities ...

  4. Investments in fossil energy technology: How the government's fossil energy R&D program has made a difference

    SciTech Connect (OSTI)

    None, None

    1997-03-01

    America has the technological capacity to change its energy future. There is no reason, for example, why our nation must continue following a path of rising oil imports when billions of barrels of crude oil remain in domestic oil fields. There is no reason why we cannot continue to use our abundant supplies of high-value, low-cost coal when we have the scientific know-how to remove virtually all of its pollutants and reduce greenhouse gas emissions. There is no reason why we cannot turn increasingly to clean-burning natural gas and tap the huge supplies we know exist within our borders. We remain a nation rich in the fuels that have powered economic growth. Today 85 percent of the energy we use to heat our homes and businesses, generate our electricity, and fuel our vehicles comes from coal, petroleum and natural gas. As we move toward a new century, the contributions of these fuels will grow. By 2015, the United States is likely to require nearly 20 percent more energy than it uses today, and fossil fuels are projected to supply almost 88 percent of the energy Americans will consume. We have the scientific know-how to continue using our fossil fuel wealth without fear of environmental damage or skyrocketing costs. The key is technology - developing cutting edge concepts that are beyond the private sector's current capabilities. Some of the most important innovations in America's energy industry are the results of investments in the Federal government's fossil energy research and development programs. Today, our air and water are cleaner, our economy is stronger, and our industries are more competitive in the global market because these programs have produced results. This booklet summarizes many of these achievements. It is not a comprehensive list by any means. Still, it provides solid evidence that the taxpayers' investment in government fossil energy research has paid real and measurable dividends.

  5. Investments in Fossil Energy Technology: How the Government's Fossil Energy R&D Program Has Made a Difference

    DOE R&D Accomplishments [OSTI]

    1997-03-01

    America has the technological capacity to change its energy future. There is no reason, for example, why our nation must continue following a path of rising oil imports when billions of barrels of crude oil remain in domestic oil fields. There is no reason why we cannot continue to use our abundant supplies of high-value, low-cost coal when we have the scientific know-how to remove virtually all of its pollutants and reduce greenhouse gas emissions. There is no reason why we cannot turn increasingly to clean-burning natural gas and tap the huge supplies we know exist within our borders. We remain a nation rich in the fuels that have powered economic growth. Today 85 percent of the energy we use to heat our homes and businesses, generate our electricity, and fuel our vehicles comes from coal, petroleum and natural gas. As we move toward a new century, the contributions of these fuels will grow. By 2015, the United States is likely to require nearly 20 percent more energy than it uses today, and fossil fuels are projected to supply almost 88 percent of the energy Americans will consume. We have the scientific know-how to continue using our fossil fuel wealth without fear of environmental damage or skyrocketing costs. The key is technology - developing cutting edge concepts that are beyond the private sector's current capabilities. Some of the most important innovations in America's energy industry are the results of investments in the Federal government's fossil energy research and development programs. Today, our air and water are cleaner, our economy is stronger, and our industries are more competitive in the global market because these programs have produced results. This booklet summarizes many of these achievements. It is not a comprehensive list by any means. Still, it provides solid evidence that the taxpayers' investment in government fossil energy research has paid real and measurable dividends.

  6. Recent advances in high-performance direct methanol fuel cells

    SciTech Connect (OSTI)

    Narayanan, S.R.; Chun, W.; Valdez, T.I.

    1996-12-31

    Direct methanol fuel cells for portable power applications have been advanced significantly under DARPA- and ARO-sponsored programs over the last five years. A liquid-feed direct methanol fuel cell developed under these programs, employs a proton exchange membrane as electrolyte and operates on aqueous solutions of methanol with air or oxygen as the oxidant. Power densities as high as 320 mW/cm{sup 2} have been demonstrated. Demonstration of five-cell stack based on the liquid-feed concept have been successfully performed by Giner Inc. and the Jet Propulsion Laboratory. Over 2000 hours of life-testing have been completed on these stacks. These fuel cells have been also been demonstrated by USC to operate on alternate fuels such as trimethoxymethane, dimethoxymethane and trioxane. Reduction in the parasitic loss of fuel across the fuel cell, a phenomenon termed as {open_quotes}fuel crossover{close_quotes} has been achieved using polymer membranes developed at USC. As a result efficiencies as high as 40% is considered attainable with this type of fuel cell. The state-of-development has reached a point where it is now been actively considered for stationary, portable and transportation applications. The research and development issues have been the subject of several previous articles and the present article is an attempt to summarize the key advances in this technology.

  7. Supercomputers Fuel Global High-Resolution Climate Models

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Supercomputers Fuel Global High-Resolution Climate Models Supercomputers Fuel Global High-Resolution Climate Models Berkeley Lab Researcher Says Climate Science is Entering New Golden Age November 12, 2014 Contact: Julie Chao, jchao@lbl.gov, 510.486.6491 wehnerclimate2 Simulated and observed annual maximum 5 day accumulated precipitation over land points, averaged. Observations are calculated from the period 1979 to 1999. Model results are calculated from the period 1979 to 2005. Not long ago,

  8. High performance fuel element with end seal

    DOE Patents [OSTI]

    Lee, Gary E.; Zogg, Gordon J.

    1987-01-01

    A nuclear fuel element comprising an elongate block of refractory material having a generally regular polygonal cross section. The block includes parallel, spaced, first and second end surfaces. The first end surface has a peripheral sealing flange formed thereon while the second end surface has a peripheral sealing recess sized to receive the flange. A plurality of longitudinal first coolant passages are positioned inwardly of the flange and recess. Elongate fuel holes are separate from the coolant passages and disposed inwardly of the flange and the recess. The block is further provided with a plurality of peripheral second coolant passages in general alignment with the flange and the recess for flowing coolant. The block also includes two bypasses for each second passage. One bypass intersects the second passage adjacent to but spaced from the first end surface and intersects a first passage, while the other bypass intersects the second passage adjacent to but spaced from the second end surface and intersects a first passage so that coolant flowing through the second passages enters and exits the block through the associated first passages.

  9. The Potential for Increased Atmospheric CO2 Emissions and Accelerated Consumption of Deep Geologic CO2 Storage Resources Resulting from the Large-Scale Deployment of a CCS-Enabled Unconventional Fossil Fuels Industry in the U.S.

    SciTech Connect (OSTI)

    Dooley, James J.; Dahowski, Robert T.; Davidson, Casie L.

    2009-11-02

    Desires to enhance the energy security of the United States have spurred significant interest in the development of abundant domestic heavy hydrocarbon resources including oil shale and coal to produce unconventional liquid fuels to supplement conventional oil supplies. However, the production processes for these unconventional fossil fuels create large quantities of carbon dioxide (CO2) and this remains one of the key arguments against such development. Carbon dioxide capture and storage (CCS) technologies could reduce these emissions and preliminary analysis of regional CO2 storage capacity in locations where such facilities might be sited within the U.S. indicates that there appears to be sufficient storage capacity, primarily in deep saline formations, to accommodate the CO2 from these industries. Nevertheless, even assuming wide-scale availability of cost-effective CO2 capture and geologic storage resources, the emergence of a domestic U.S. oil shale or coal-to-liquids (CTL) industry would be responsible for significant increases in CO2 emissions to the atmosphere. The authors present modeling results of two future hypothetical climate policy scenarios that indicate that the oil shale production facilities required to produce 3MMB/d from the Eocene Green River Formation of the western U.S. using an in situ retorting process would result in net emissions to the atmosphere of between 3000-7000 MtCO2, in addition to storing potentially 900-5000 MtCO2 in regional deep geologic formations via CCS in the period up to 2050. A similarly sized, but geographically more dispersed domestic CTL industry could result in 4000-5000 MtCO2 emitted to the atmosphere in addition to potentially 21,000-22,000 MtCO2 stored in regional deep geologic formations over the same period. While this analysis shows that there is likely adequate CO2 storage capacity in the regions where these technologies are likely to deploy, the reliance by these industries on large-scale CCS could result

  10. Fuels and Combustion Strategies for High-Efficiency Clean-Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion Strategies for High-Efficiency Clean-Combustion Engines Fuels and Combustion Strategies for High-Efficiency Clean-Combustion Engines 2012 DOE Hydrogen and Fuel Cells ...

  11. DOE - Fossil Energy:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NEWSALERT - Keep Up to date with e-mail alerts from the Office of Fossil Energy Fossil Energy NEWSALERT is a free, e-mail notification service of the U.S. Department of Energy's ...

  12. High Efficiency Generation of Hydrogen Fuels using Nuclear Power Annual Report August, 2000 - July 2001

    SciTech Connect (OSTI)

    Brown, L.C.

    2002-11-01

    OAK B188 High Efficiency Generation of Hydrogen Fuels using Nuclear Power Annual Report August 2000 - July 2001. Currently no large scale, cost-effective, environmentally attractive hydrogen production process is available for commercialization nor has such a process been identified. Hydrogen is a promising energy carrier, which potentially could replace the fossil fuels used in the transportation sector of our economy. Carbon dioxide emissions from fossil fuel combustion are thought to be responsible for global warming. The purpose of this work is to determine the potential for efficient, cost-effective, large-scale production of hydrogen utilizing high temperature heat from an advanced nuclear power station. The benefits of this work will include the generation of a low-polluting transportable energy feedstock in an efficient method that has little or no implication for greenhouse gas emissions from a primary energy source whose availability and sources are domestically controlled. This will help to ensure energy for a future transportation/energy infrastructure that is not influenced/controlled by foreign governments. This report describes work accomplished during the second year (Phase 2) of a three year project whose objective is to ''define an economically feasible concept for production of hydrogen, by nuclear means, using an advanced high temperature nuclear reactor as the energy source.'' The emphasis of the first year (Phase 1) was to evaluate thermochemical processes which offer the potential for efficient, cost-effective, large-scale production of hydrogen from water, in which the primary energy input is high temperature heat from an advanced nuclear reactor and to select one (or, at most, three) for further detailed consideration. Phase 1 met its goals and did select one process, the sulfur-iodine process, for investigation in Phases 2 and 3. The combined goals of Phases 2 and 3 were to select the advanced nuclear reactor best suited to driving the

  13. Cycles in fossil diversity

    SciTech Connect (OSTI)

    Rohde, Robert A.; Muller, Richard A.

    2004-10-20

    It is well-known that the diversity of life appears to fluctuate during the course the Phanerozoic, the eon during which hard shells and skeletons left abundant fossils (0-542 Ma). Using Sepkoski's compendium of the first and last stratigraphic appearances of 36380 marine genera, we report a strong 62 {+-} 3 Myr cycle, which is particularly strong in the shorter-lived genera. The five great extinctions enumerated by Raup and Sepkoski may be an aspect of this cycle. Because of the high statistical significance, we also consider contributing environmental factors and possible causes.

  14. Energy Department Invests $28 Million to Advance Cleaner Fossil

    Energy Savers [EERE]

    Fuel-Based Power Generation | Department of Energy 28 Million to Advance Cleaner Fossil Fuel-Based Power Generation Energy Department Invests $28 Million to Advance Cleaner Fossil Fuel-Based Power Generation August 24, 2016 - 10:10am Addthis WASHINGTON-The U.S. Department of Energy (DOE) today announced the selection of 14 research and development projects to advance energy systems that will enable cost-competitive, fossil fuel-based power generation with near-zero emissions. The new

  15. Fossil energy biotechnology: A research needs assessment. Final report

    SciTech Connect (OSTI)

    Not Available

    1993-11-01

    The Office of Program Analysis of the US Department of Energy commissioned this study to evaluate and prioritize research needs in fossil energy biotechnology. The objectives were to identify research initiatives in biotechnology that offer timely and strategic options for the more efficient and effective uses of the Nation`s fossil resource base, particularly the early identification of new and novel applications of biotechnology for the use or conversion of domestic fossil fuels. Fossil energy biotechnology consists of a number of diverse and distinct technologies, all related by the common denominator -- biocatalysis. The expert panel organized 14 technical subjects into three interrelated biotechnology programs: (1) upgrading the fuel value of fossil fuels; (2) bioconversion of fossil feedstocks and refined products to added value chemicals; and, (3) the development of environmental management strategies to minimize and mitigate the release of toxic and hazardous petrochemical wastes.

  16. High Temperature BOP and Fuel Processing

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    D e e p p a a r r t t m m e e n n t t o o f f E E n n e e r r g g y y F F u u e e l l l l l l n n g g C C e e M M a a n n u u f f a a c c t t u u r r i i R R & & D D W W o o r r k k s s h h o o p p H H i i g g h h T T e e m m p p e e r r a a t t u u r r e e B B O O P P a a n n d d F F u u e e l l i i n n g g P P r r o o c c e e s s s s A A u u g g u u s s t t 1 1 1 1 - - 1 1 2 2 , , 2 2 0 0 1 1 1 1 A A g g e e n n d d a a Acumentrics Overview & Approach Fuel Preparation Reforming

  17. Humidifier for fuel cell using high conductivity carbon foam

    DOE Patents [OSTI]

    Klett, James W.; Stinton, David P.

    2006-12-12

    A method and apparatus of supplying humid air to a fuel cell is disclosed. The extremely high thermal conductivity of some graphite foams lends itself to enhance significantly the ability to humidify supply air for a fuel cell. By utilizing a high conductivity pitch-derived graphite foam, thermal conductivity being as high as 187 W/m.dot.K, the heat from the heat source is more efficiently transferred to the water for evaporation, thus the system does not cool significantly due to the evaporation of the water and, consequently, the air reaches a higher humidity ratio.

  18. Structure of high-burnup-fuel Zircaloy cladding. [PWR; BWR

    SciTech Connect (OSTI)

    Chung, H.M.

    1983-06-01

    Zircaloy cladding from high-burnup (> 20 MWd/kg U) fuel rods in light-water reactors is characterized by a high density of irradiation-induced defects (RID), compositional changes (e.g., oxygen and hydrogen uptake) associated with in-service corrosion, and geometrical changes produced by creepdown, bowing, and irradiation-induced growth. During a reactor power transient, the cladding is subject to localized stress imposed by thermal expansion of the cracked fuel pellets and to mechanical constraints imposed by pellet-cladding friction. As part of a program to provide a better understanding of brittle-type failure of Zircaloy fuel cladding by pellet-cladding interaction (PCI) phenomenon, the stress-rupture properties and microstructural characteristics of high-burnup spent fuel cladding have been under investigation. This paper reports the results of the microstructural examinations by optical microscopy, scanning (SEM), 100-keV transmission (TEM), and 1 MeV high-voltage (HVEM) electron microscopies of the fractured spent fuel cladding with a specific empahsis on a correlation of the structural characteristics with the fracture behavior.

  19. Modeling Cladding-Coolant Heat Transfer of High-Burnup Fuel During...

    Office of Scientific and Technical Information (OSTI)

    transfer of high burnup fuel during a Reactivity Initiated Accident (RIA) which is ... LIQUIDS; NUCLEAR FUELS; OXIDATION; REACTIVITY; SUBCOOLING; SURFACES; THERMAL ...

  20. From Hydrogen Fuel Cells to High-Altitude-Pilot Protection Suits...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    From Hydrogen Fuel Cells to High-Altitude-Pilot Protection Suits- Mound Science and Energy Museum Programs Cover a Wide Range of Topics From Hydrogen Fuel Cells to ...

  1. Operational considerations for high level blast furnace fuel injection

    SciTech Connect (OSTI)

    Poveromo, J.J.

    1996-12-31

    Injection levels of over 400 lbs/NTHM for coal, over 250 lbs/NTHM for natural gas and over 200 lbs/NTHM for oil have been achieved. Such high levels of fuel injection has a major impact on many aspects of blast furnace operation. In this paper the author begins by reviewing the fundamentals of fuel injection with emphasis on raceway thermochemical phenomena. The operational impacts which are generic to high level injection of any injectant are then outlined. The author will then focus on the particular characteristics of each injectant, with major emphasis on coal and natural gas. Operational considerations for coping with these changes and methods of maximizing the benefits of fuel injection will be reviewed.

  2. Development of technology of high density LEU dispersion fuel fabrication.

    SciTech Connect (OSTI)

    Wiencek, T.; Totev, T.; Nuclear Engineering Division

    2007-01-01

    Advanced Materials Fabrication Facilities at Argonne National Laboratory have been involved in development of LEU dispersion fuel for research and test reactors from the beginning of RERTR program. This paper presents development of technology of high density LEU dispersion fuel fabrication for full size plate type fuel elements. A brief description of Advanced Materials Fabrication Facilities where development of the technology was carried out is given. A flow diagram of the manufacturing process is presented. U-Mo powder was manufactured by the rotating electrode process. The atomization produced a U-Mo alloy powder with a relatively uniform size distribution and a nearly spherical shape. Test plates were fabricated using tungsten and depleted U-7 wt.% Mo alloy, 4043 Al and Al-2 wt% Si matrices with Al 6061 aluminum alloy for the cladding. During the development of the technology of manufacturing of full size high density LEU dispersion fuel plates special attention was paid to meet the required homogeneity, bonding, dimensions, fuel out of zone and other mechanical characteristics of the plates.

  3. Development of technology of high density LEU dispersion fuel fabrication

    SciTech Connect (OSTI)

    Wiencek, Tom; Totev, Totju

    2008-07-15

    Advanced Materials Fabrication Facilities at Argonne National Laboratory have been involved in development of LEU dispersion fuel for research and test reactors from the beginning of RERTR program. This paper presents development of technology of high density LEU dispersion fuel fabrication for full size plate type fuel elements. A brief description of Advanced Materials Fabrication Facilities where development of the technology was carried out is given. A flow diagram of the manufacturing process is presented. U-Mo powder was manufactured by the rotating electrode process. The atomization produced a U-Mo alloy powder with a relatively uniform size distribution and a nearly spherical shape. Test plates were fabricated using tungsten and depleted U-7 wt.% Mo alloy, 4043 Al and Al-2 wt% Si matrices with Al 6061 aluminum alloy for the cladding. During the development of the technology of manufacturing of full size high density LEU dispersion fuel plates special attention was paid to meet the required homogeneity, bonding, dimensions, fuel out of zone and other mechanical characteristics of the plates. (author)

  4. Long-term management of high-level radioactive waste (HLW) and spent nuclear fuel (SNF)

    Broader source: Energy.gov [DOE]

    GC-52 provides legal advice to DOE regarding the long-term management of high-level radioactive waste (HLW) and spent nuclear fuel (SNF). SNF is nuclear fuel that has been used as fuel in a reactor...

  5. Mechanical Fatigue Testing of High Burnup Fuel for Transportation Applications

    SciTech Connect (OSTI)

    Wang, Jy-An John; Wang, Hong

    2015-05-01

    This report describes testing designed to determine the ability of high burnup (HBU) (>45 GWd/MTU) spent fuel to maintain its integrity under normal conditions of transportation. An innovative system, Cyclic Integrated Reversible-bending Fatigue Tester (CIRFT), has been developed at Oak Ridge National Laboratory (ORNL) to test and evaluate the mechanical behavior of spent nuclear fuel (SNF) under conditions relevant to storage and transportation. The CIRFT system is composed of a U-frame equipped with load cells for imposing the pure bending loads on the SNF rod test specimen and measuring the in-situ curvature of the fuel rod during bending using a set up with three linear variable differential transformers (LVDTs).

  6. Fossil | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    by Daniel Wood, Energy Department. Fossil energy sources, including oil, coal and natural gas, are non-renewable resources that formed when prehistoric plants and animals died...

  7. Office of Fossil Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    LNG Imports by Receiving Terminal (Bcf) (Bcf) (Bcf) LNG Imports by Company Office of Fossil Energy Office of Oil & Natural Gas Office of Regulation and International Engagement ...

  8. Office of Fossil Energy

    Broader source: Energy.gov (indexed) [DOE]

    Terminal (Bcf) (Bcf) (Bcf) LNG Imports by Company Office of Fossil Energy Office of Oil & Natural Gas Office of Regulation and International Engagement Division of Natural Gas...

  9. Fossil energy program. Progress report, July 1980

    SciTech Connect (OSTI)

    McNeese, L. E.

    1980-10-01

    This report - the seventy-second of a series - is a compendium of monthly progress reports for the ORNL research and development programs that are in support of the increased utilization of coal and other fossil fuel alternatives to oil and gas as sources of clean energy. The projects reported this month include those for coal conversion development, chemical research and development, materials technology, component development and process evaluation, technical support to major liquefaction projects, process and program analysis, fossil energy environmental analysis, coal preparation and waste utilization, coal preparation plant automation, atmospheric fluidized bed coal combustor for cogeneration, technical support to the TVA fluidized bed combustion demonstration plant program, fossil energy applications assessments, performance assurance system support for fossil energy projects, international assessment of atmospheric fluidized bed combustion technology, and PFBC systems analysis.

  10. Funds Awarded to Historically Black Colleges and Universities for Fossil

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Research | Department of Energy Funds Awarded to Historically Black Colleges and Universities for Fossil Energy Research Funds Awarded to Historically Black Colleges and Universities for Fossil Energy Research October 7, 2014 - 10:26am Addthis Washington, D.C. - The U.S. Department of Energy (DOE) has selected four research projects that will provide educational and research training opportunities for minority students while advancing key technical areas in fossil fuel utilization.

  11. Fossil-energy program. Progress report for June 1981

    SciTech Connect (OSTI)

    Not Available

    1981-08-01

    This report - the eighty-third of series - is a compendium of monthly progress reports for the ORNL research and development programs that are in support of the increased utilization of coal and other fossil fuel alternatives as sources of clean energy. The projects reported this month include those for coal conversion development, chemical research and development, materials technology, component development and process evaluation, technical support to major liquefaction projects, process analysis and engineering evaluations, fossil energy environmental analysis, flue gas desulfurization, coal preparation waste utilization, atmospheric fluidized bed coal combustor for cogeneration, TVA FBC demonstration plant program technical support, PFBC systems analysis, fossil fuel applications assessments, performance assurance system support for fossil energy projects, international energy technology assessment, generalized equilibrium models for liquid and gaseous fuel supplies, analyses of coal production goals, and fossil energy information center.

  12. Fuel Cell/Turbine Ultra High Efficiency Power System

    SciTech Connect (OSTI)

    Hossein, Ghezel-Ayagh

    2001-11-06

    FuelCell Energy, INC. (FCE) is currently involved in the design of ultra high efficiency power plants under a cooperative agreement (DE-FC26-00NT40) managed by the National Energy Technology Laboratory (NETL) as part of the DOE's Vision 21 program. Under this project, FCE is developing a fuel cell/turbine hybrid system that integrates the atmospheric pressure Direct FuelCell{reg_sign} (DFC{reg_sign}) with an unfired Brayton cycle utilizing indirect heat recovery from the power plant. Features of the DFC/T{trademark} system include: high efficiency, minimal emissions, simplicity in design, direct reforming internal to the fuel cell, no pressurization of the fuel cell, independent operating pressure of the fuel cell and turbine, and potential cost competitiveness with existing combined cycle power plants at much smaller sizes. Objectives of the Vision 21 Program include developing power plants that will generate electricity with net efficiencies approaching 75 percent (with natural gas), while producing sulfur and nitrogen oxide emissions of less than 0.01 lb/million BTU. These goals are significant improvements over conventional power plants, which are 35-60 percent efficient and produce emissions of 0.07 to 0.3 lb/million BTU of sulfur and nitrogen oxides. The nitrogen oxide and sulfur emissions from the DFC/T system are anticipated to be better than the Vision 21 goals due to the non-combustion features of the DFC/T power plant. The expected high efficiency of the DFC/T will also result in a 40-50 percent reduction in carbon dioxide emissions compared to conventional power plants. To date, the R&D efforts have resulted in significant progress including proof-of-concept tests of a sub-scale power plant built around a state-of-the-art DFC stack integrated with a modified Capstone Model 330 Microturbine. The objectives of this effort are to investigate the integration aspects of the fuel cell and turbine and to obtain design information and operational data that will

  13. Materials for High-Pressure Fuel Injection Systems

    SciTech Connect (OSTI)

    Blau, P.; Shyam, A.; Hubbard, C.; Howe, J.; Trejo, R.; Yang, N.; Pollard, M.

    2011-09-30

    The high-level goal of this multi-year effort was to facilitate the Advanced Combustion Engine goal of 20% improvement (compared to 2009 baseline) of commercial engine efficiency by 2015. A sub-goal is to increase the reliability of diesel fuel injectors by investigating modelbased scenarios that cannot be achieved by empirical, trial and error methodologies alone. During this three-year project, ORNL developed the methodology to evaluate origins and to record the initiation and propagation of fatigue cracks emanating from holes that were electrodischarge machined (EDM), the method used to form spray holes in fuel injector tips. Both x-ray and neutron-based methods for measuring residual stress at four different research facilities were evaluated to determine which, if any, was most applicable to the fuel injector tip geometry. Owing to the shape and small volumes of material involved in the sack area, residual stress data could only be obtained in the walls of the nozzle a few millimeters back from the tip, and there was a hint of only a small compressive stress. This result was consistent with prior studies by Caterpillar. Residual stress studies were suspended after the second year, reserving the possibility of pursuing this in the future, if and when methodology suitable for injector sacks becomes available. The smooth specimen fatigue behavior of current fuel injector steel materials was evaluated and displayed a dual mode initiation behavior. At high stresses, cracks started at machining flaws in the surface; however, below a critical threshold stress of approximately 800 MPa, cracks initiated in the bulk microstructure, below the surface. This suggests that for the next generation for high-pressure fuel injector nozzles, it becomes increasingly important to control the machining and finishing processes, especially if the stress in the tip approaches or exceeds that threshold level. Fatigue tests were also conducted using EDM notches in the gage sections

  14. Smart Onboard Inspection of High Pressure Gas Fuel Cylinders

    SciTech Connect (OSTI)

    Beshears, D.L.; Starbuck, J.M.

    1999-09-27

    The use of natural gas as an alternative fuel in automotive applications is not widespread primarily because of the high cost and durability of the composite storage tanks. Tanks manufactured using carbon fiber are desirable in weight critical passenger vehicles because of the low density of carbon fiber. The high strength of carbon fiber also translates to a weight reduction because thinner wall designs are possible to withstand the internal pressure loads. However, carbon fiber composites are prone to impact damage that over the life of the storage tank may lead to an unsafe condition for the vehicle operator. A technique that potentially may be a reliable indication of developing hazardous conditions in composite fuel tanks is imbedded fiber optics. The applicability of this technique to onboard inspection is discussed and results from preliminary lab testing indicate that fiber optic sensors can reliably detect impact damage.

  15. Novel Sorbent to Clean Biogas for Fuel Cell Combined Heat and Power

    SciTech Connect (OSTI)

    2009-11-01

    TDA Research Inc., in collaboration with FuelCell Energy, will develop a new, high-capacity sorbent to remove sulfur from anaerobic digester gas. This technology will enable the production of a nearly sulfur-free biogas to replace natural gas in fuel cell power plants while reducing greenhouse gas emissions from fossil fuels.

  16. President's FY 2017 Budget Includes $878 Million for Fossil Energy...

    Office of Environmental Management (EM)

    ... are applicable to both coal and natural gas generation. ... pre-combustion CO2 capture and compression technologies for new and existing fossil fuel-fired power plants and industrial ...

  17. Modular, High-Volume Fuel Cell Leak-Test Suite and Process

    SciTech Connect (OSTI)

    Ru Chen; Ian Kaye

    2012-03-12

    Fuel cell stacks are typically hand-assembled and tested. As a result the manufacturing process is labor-intensive and time-consuming. The fluid leakage in fuel cell stacks may reduce fuel cell performance, damage fuel cell stack, or even cause fire and become a safety hazard. Leak check is a critical step in the fuel cell stack manufacturing. The fuel cell industry is in need of fuel cell leak-test processes and equipment that is automatic, robust, and high throughput. The equipment should reduce fuel cell manufacturing cost.

  18. Deactivation and Storage Issues Shared by Fossil and Nuclear Facilities

    SciTech Connect (OSTI)

    Thomas S. LaGuardia

    1998-12-31

    The deactivation of a power plant, be it nuclear or fossil fueled, requires that the facility be placed in a safe and stable condition to prevent unacceptable exposure of the public or the environment to hazardous materials until the facility can be decommissioned. The conditions at two Texas plants are examined. These plants are fossil fueled, but their conditions might be duplicated at a nuclear plant.

  19. Phosphorus, Sulfur, and Chlorine in Fuel Gases: Impact on High Temperature Fuel Cell Performance and Clean-Up Options

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Phosphorus, Sulfur, and Chlorine in Fuel Gases: Impact on High Temperature Fuel Cell Performance and Clean-Up Options OLGA A MARINA Pacific Northwest National Laboratory Workshop on Gas Clean-Up for Fuel Cell Applications March 6-7, 2014 57% net electrical efficiency on methane 8 SOFC cells per furnace with independent gas flow Multi-cell MCFC test stand 2 High Temperature Fuel Cell R&D at PNNL; Impurities Overview OA Marina Selected Impurities in Biogas/Landfill Gas: Cell/stack/system

  20. 2012 Fuel Economy of New Vehicles Sets Record High: EPA | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2012 Fuel Economy of New Vehicles Sets Record High: EPA 2012 Fuel Economy of New Vehicles Sets Record High: EPA December 18, 2013 - 12:00am Addthis The U.S. Environmental...

  1. Developing Low-Cost, Highly Efficient Heat Recovery for Fuel...

    Broader source: Energy.gov (indexed) [DOE]

    Illustration courtesy of FuelCell Energy, Inc. Project Description The goal of this ... It is now be- ing incorporated into FuelCell Energy's commercial Direct FuelCell ...

  2. EPRI-DOE Joint Report Focuses on Fossil Fleet Transition with...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Changes and Large Scale Variable Renewable Integration EPRI-DOE Joint Report Focuses on Fossil Fleet Transition with Fuel Changes and Large Scale Variable Renewable Integration ...

  3. Locations of Spent Nuclear Fuel and High-Level Radioactive Waste

    Broader source: Energy.gov [DOE]

    Map of the United States of America showing the locations of spent nuclear fuel and high-level radioactive waste.

  4. Deep Burn: Development of Transuranic Fuel for High-Temperature...

    Office of Scientific and Technical Information (OSTI)

    DB HTR (INL, GA, Logos); (2) Spent Fuel Management - (a) TRISO (tri-structural isotropic) ... Reprocessing METROX (metal recovery from oxide fuel) Process Development (ANL). ...

  5. DOE - Fossil Energy:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Services, LLC (Trinidad and Tobago) 1926; 1926-A FE03-30-NG 071103 Mex TransAlta Chihuahua S.A. de C.V. 1877 Page owner: Fossil Energy Office of Communications Page updated...

  6. Office of Fossil Energy

    Energy Savers [EERE]

    LNG Imports by Country of Origin LNG Imports by Receiving Terminal (Bcf) (Bcf) (Bcf) LNG Imports by Company Office of Fossil Energy Office of Oil & Natural Gas Office of Regulation ...

  7. Irradiation performance of AGR-1 high temperature reactor fuel

    SciTech Connect (OSTI)

    Paul A. Demkowicz; John D. Hunn; Robert N. Morris; Charles A. Baldwin; Philip L. Winston; Jason M. Harp; Scott A. Ploger; Tyler Gerczak; Isabella J. van Rooyen; Fred C. Montgomery; Chinthaka M. Silva

    2014-10-01

    The AGR-1 experiment contained 72 low-enriched uranium oxide/uranium carbide TRISO-coated particle fuel compacts in six capsules irradiated to burnups of 11.2 to 19.5% FIMA, with zero TRISO coating failures detected during the irradiation. The irradiation performance of the fuelincluding the extent of fission product release and the evolution of kernel and coating microstructureswas evaluated based on detailed examination of the irradiation capsules, the fuel compacts, and individual particles. Fractional release of 110mAg from the fuel compacts was often significant, with capsule-average values ranging from 0.01 to 0.38. Analysis of silver release from individual compacts indicated that it was primarily dependent on fuel temperature history. Europium and strontium were released in small amounts through intact coatings, but were found to be significantly retained in the outer pyrocrabon and compact matrix. The capsule-average fractional release from the compacts was 110 4 to 510 4 for 154Eu and 810 7 to 310 5 for 90Sr. The average 134Cs release from compacts was <310 6 when all particles maintained intact SiC. An estimated four particles out of 2.98105 experienced partial cesium release due to SiC failure during the irradiation, driving 134Cs release in two capsules to approximately 10 5. Identification and characterization of these particles has provided unprecedented insight into the nature and causes of SiC coating failure in high-quality TRISO fuel. In general, changes in coating morphology were found to be dominated by the behavior of the buffer and inner pyrolytic carbon (IPyC), and infrequently observed SiC layer damage was usually related to cracks in the IPyC. Palladium attack of the SiC layer was relatively minor, except for the particles that released cesium during irradiation, where SiC corrosion was found adjacent to IPyC cracks. Palladium, silver, and uranium were found in the SiC layer of irradiated particles, and characterization of these

  8. Upgrading of biorenewables to high energy density fuels

    SciTech Connect (OSTI)

    Gordon, John C; Batista, Enrique R; Chen, Weizhong; Currier, Robert P; Dirmyer, Matthew R; John, Kevin D; Kim, Jin K; Keith, Jason; Martin, Richard L; Pierpont, Aaron W; Silks Ill, L. A. "" Pete; Smythe, Mathan C; Sutton, Andrew D; Taw, Felicia L; Trovitch, Ryan J; Vasudevan, Kalyan V; Waidmann, Christopher R; Wu, Ruilian; Baker, R. Thomas; Schlaf, Marcel

    2010-12-07

    According to a recent report, lignocellulose is the most abundant renewable biological resource on earth, with an annual production of {approx} 200 x 10{sup 9} tons. Conversion of lignocellulosics derived from wood, agricultural wastes, and woody grasses into liquid fuels and value-added chemical feedstocks is an active area of research that has seen an explosion of effort due to the need to replace petroleum based sources. The carbohydrates D-glucose (C{sub 6}), L-arabinose (C{sub 5}), and D-xylose (C{sub 5}) are readily obtained from the hydrolysis of lignocellulose and constitute the most abundant renewable organic carbon source on the planet. Because they are naturally produced on such a large scale, these sugars have the greatest potential to displace petrochemical derived transportation fuel. Recent efforts in our laboratories aimed towards the production of high energy density transportation fuels from carbohydrates have been structured around the parameters of selective carbohydrate carbon chain extension chemistries, low reaction temperatures, and the desired use of water or neat substrate as the solvent. Some of our efforts in this regard will be presented.

  9. Fact #650: November 22, 2010 Diesel Fuel Prices hit a Two-Year High |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy 50: November 22, 2010 Diesel Fuel Prices hit a Two-Year High Fact #650: November 22, 2010 Diesel Fuel Prices hit a Two-Year High According to the Energy Information Administration's weekly fuel price data, the price of highway diesel fuel on the week of November 17, 2010, reached a 2-year high of $3.18 per gallon. Back in 2008, the prices for gasoline and diesel fuel rose to record levels in mid-summer, but plummeted by about 50% before the end of the year. Though fuel

  10. Fuel Grading Study on a Low-Enriched Uranium Fuel Design for the High Flux Isotope Reactor

    SciTech Connect (OSTI)

    Ilas, Germina; Primm, Trent

    2009-11-01

    An engineering design study that would enable the conversion of the High Flux Isotope Reactor (HFIR) from high-enriched uranium to low-enriched uranium fuel is ongoing at Oak Ridge National Laboratory. The computational models used to search for a low-enriched uranium (LEU) fuel design that would meet the requirements for the conversion study, and the recent results obtained with these models during FY 2009, are documented and discussed in this report. Estimates of relevant reactor performance parameters for the LEU fuel core are presented and compared with the corresponding data for the currently operating high-enriched uranium fuel core. These studies indicate that the LEU fuel design would maintain the current performance of the HFIR with respect to the neutron flux to the central target region, reflector, and beam tube locations.

  11. High Temperature Fuel Cell Tri-Generation of Power, Heat & H2 from Biogas

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    National Fuel Cell Research Center, 2012 1/22 High Temperature Fuel Cell Tri-Generation of Power, Heat & H 2 from Biogas Jack Brouwer, Ph.D. June 19, 2012 DOE/ NREL Biogas Workshop - Golden, CO © National Fuel Cell Research Center, 2012 2/22 Outline * Introduction and Background * Tri-Generation/Poly-Generation Analyses * OCSD Project Introduction © National Fuel Cell Research Center, 2012 3/22 Introduction and Background * Hydrogen fuel cell vehicle performance is outstanding * Energy

  12. Update on US High Density Fuel Fabrication Development

    SciTech Connect (OSTI)

    C.R. Clark; G.A. Moore; J.F. Jue; B.H. Park; N.P. Hallinan; D.M. Wachs; D.E. Burkes

    2007-03-01

    Second generation uranium molybdenum fuel has shown excellent in-reactor irradiation performance. This metallic fuel type is capable of being fabricated at much higher loadings than any presently used research reactor fuel. Due to the broad range of fuel types this alloy system encompasses—fuel powder to monolithic foil and binary fuel systems to multiple element additions—significant amounts of research and development have been conducted on the fabrication of these fuels. This paper presents an update of the US RERTR effort to develop fabrication techniques and the fabrication methods used for the RERTR-9A miniplate test.

  13. Segregated exhaust SOFC generator with high fuel utilization capability

    DOE Patents [OSTI]

    Draper, Robert; Veyo, Stephen E.; Kothmann, Richard E.

    2003-08-26

    A fuel cell generator contains a plurality of fuel cells (6) in a generator chamber (1) and also contains a depleted fuel reactor or a fuel depletion chamber (2) where oxidant (24,25) and fuel (81) is fed to the generator chamber (1) and the depleted fuel reactor chamber (2), where both fuel and oxidant react, and where all oxidant and fuel passages are separate and do not communicate with each other, so that fuel and oxidant in whatever form do not mix and where a depleted fuel exit (23) is provided for exiting a product gas (19) which consists essentially of carbon dioxide and water for further treatment so that carbon dioxide can be separated and is not vented to the atmosphere.

  14. Cost-Benefit Analysis of Flexibility Retrofits for Coal and Gas-Fueled Power Plants: August 2012 - December 2013

    SciTech Connect (OSTI)

    Venkataraman, S.; Jordan, G.; O'Connor, M.; Kumar, N.; Lefton, S.; Lew, D.; Brinkman, G.; Palchak, D.; Cochran, J.

    2013-12-01

    High penetrations of wind and solar power plants can induce on/off cycling and ramping of fossil-fueled generators. This can lead to wear-and-tear costs and changes in emissions for fossil-fueled generators. Phase 2 of the Western Wind and Solar Integration Study (WWSIS-2) determined these costs and emissions and simulated grid operations to investigate the full impact of wind and solar on the fossil-fueled fleet. This report studies the costs and benefits of retrofitting existing units for improved operational flexibility (i.e., capability to turndown lower, start and stop faster, and ramp faster between load set-points).

  15. High Energy Absorption Top Nozzle For A Nuclaer Fuel Assembly

    DOE Patents [OSTI]

    Sparrow, James A.; Aleshin, Yuriy; Slyeptsov, Aleksey

    2004-05-18

    A high energy absorption top nozzle for a nuclear fuel assembly that employs an elongated upper tubular housing and an elongated lower tubular housing slidable within the upper tubular housing. The upper and lower housings are biased away from each other by a plurality of longitudinally extending springs that are restrained by a longitudinally moveable piston whose upward travel is limited within the upper housing. The energy imparted to the nozzle by a control rod scram is mostly absorbed by the springs and the hydraulic affect of the piston within the nozzle.

  16. Chapter 4. Fuel Economy, Consumption and Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    national concerns about dependence on foreign oil and the deleterious effect on the environment of fossil fuel combustion, residential vehicle fleet fuel consumption was...

  17. Fuel flexible fuel injector

    DOE Patents [OSTI]

    Tuthill, Richard S; Davis, Dustin W; Dai, Zhongtao

    2015-02-03

    A disclosed fuel injector provides mixing of fuel with airflow by surrounding a swirled fuel flow with first and second swirled airflows that ensures mixing prior to or upon entering the combustion chamber. Fuel tubes produce a central fuel flow along with a central airflow through a plurality of openings to generate the high velocity fuel/air mixture along the axis of the fuel injector in addition to the swirled fuel/air mixture.

  18. Bio-Fuel Production Assisted with High Temperature Steam Electrolysis

    SciTech Connect (OSTI)

    Grant Hawkes; James O'Brien; Michael McKellar

    2012-06-01

    Two hybrid energy processes that enable production of synthetic liquid fuels that are compatible with the existing conventional liquid transportation fuels infrastructure are presented. Using biomass as a renewable carbon source, and supplemental hydrogen from high-temperature steam electrolysis (HTSE), these two hybrid energy processes have the potential to provide a significant alternative petroleum source that could reduce dependence on imported oil. The first process discusses a hydropyrolysis unit with hydrogen addition from HTSE. Non-food biomass is pyrolyzed and converted to pyrolysis oil. The pyrolysis oil is upgraded with hydrogen addition from HTSE. This addition of hydrogen deoxygenates the pyrolysis oil and increases the pH to a tolerable level for transportation. The final product is synthetic crude that could then be transported to a refinery and input into the already used transportation fuel infrastructure. The second process discusses a process named Bio-Syntrolysis. The Bio-Syntrolysis process combines hydrogen from HTSE with CO from an oxygen-blown biomass gasifier that yields syngas to be used as a feedstock for synthesis of liquid synthetic crude. Conversion of syngas to liquid synthetic crude, using a biomass-based carbon source, expands the application of renewable energy beyond the grid to include transportation fuels. It can also contribute to grid stability associated with non-dispatchable power generation. The use of supplemental hydrogen from HTSE enables greater than 90% utilization of the biomass carbon content which is about 2.5 times higher than carbon utilization associated with traditional cellulosic ethanol production. If the electrical power source needed for HTSE is based on nuclear or renewable energy, the process is carbon neutral. INL has demonstrated improved biomass processing prior to gasification. Recyclable biomass in the form of crop residue or energy crops would serve as the feedstock for this process. A process model

  19. Alternative Fuel School Buses Earn High Marks: Reprint from Alternative Fuel News, Vol. 5, No. 3

    SciTech Connect (OSTI)

    Not Available

    2002-11-01

    A two-page article on school buses that run on alternative fuels including biodiesel and compressed natural gas. Reprinted from Alternative Fuel News, published by the Clean Cities Program of DOE.

  20. Pebble Fuel Handling and Reactivity Control for Salt-Cooled High...

    Office of Scientific and Technical Information (OSTI)

    and Reactivity Control for Salt-Cooled High Temperature Reactors Citation Details In-Document Search Title: Pebble Fuel Handling and Reactivity Control for Salt-Cooled High ...

  1. Embrittlement and DBTT of High-Burnup PWR Fuel Cladding Alloys

    Broader source: Energy.gov [DOE]

    Structural analyses of high-burnup (HBU) fuel require cladding mechanical properties and failure limits to assess fuel behavior during long-term dry-cask storage and transportation.

  2. Atomistic Simulation of High-Density Uranium Fuels

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Garcés, Jorge Eduardo; Bozzolo, Guillermo

    2011-01-01

    We apply an atomistic modeling approach to deal with interfacial phenomena in high-density uranium fuels. The effects of Si, as additive to Al or as U-Mo-particles coating, on the behavior of the Al/U-Mo interface is modeled by using the Bozzolo-Ferrante-Smith (BFS) method for alloys. The basic experimental features characterizing the real system are identified, via simulations and atom-by-atom analysis. These include (1) the trend indicating formation of interfacial compounds, (2) much reduced diffusion of Al into U-Mo solid solution due to the high Si concentration, (3) Si depletion in the Al matrix, (4) an unexpected interaction between Mo and Simore » which inhibits Si diffusion to deeper layers in the U-Mo solid solution, and (5) the minimum amount of Si needed to perform as an effective diffusion barrier. Simulation results related to alternatives to Si dispersed in the Al matrix, such as the use of C coating of U-Mo particles or Zr instead of the Al matrix, are also shown. Recent experimental results confirmed early theoretical proposals, along the lines of the results reported in this work, showing that atomistic computational modeling could become a valuable tool to aid the experimental work in the development of nuclear fuels.« less

  3. Spent Fuel and High-Level Radioactive Waste Transportation Report

    SciTech Connect (OSTI)

    Not Available

    1992-03-01

    This publication is intended to provide its readers with an introduction to the issues surrounding the subject of transportation of spent nuclear fuel and high-level radioactive waste, especially as those issues impact the southern region of the United States. It was originally issued by SSEB in July 1987 as the Spent Nuclear Fuel and High-Level Radioactive Waste Transportation Primer, a document patterned on work performed by the Western Interstate Energy Board and designed as a ``comprehensive overview of the issues.`` This work differs from that earlier effort in that it is designed for the educated layman with little or no background in nuclear waste Issues. In addition. this document is not a comprehensive examination of nuclear waste issues but should instead serve as a general introduction to the subject. Owing to changes in the nuclear waste management system, program activities by the US Department of Energy and other federal agencies and developing technologies, much of this information is dated quickly. While this report uses the most recent data available, readers should keep in mind that some of the material is subject to rapid change. SSEB plans periodic updates in the future to account for changes in the program. Replacement pages will be supplied to all parties in receipt of this publication provided they remain on the SSEB mailing list.

  4. Spent fuel and high-level radioactive waste transportation report

    SciTech Connect (OSTI)

    Not Available

    1989-11-01

    This publication is intended to provide its readers with an introduction to the issues surrounding the subject of transportation of spent nuclear fuel and high-level radioactive waste, especially as those issues impact the southern region of the United States. It was originally issued by the Southern States Energy Board (SSEB) in July 1987 as the Spent Nuclear Fuel and High-Level Radioactive Waste Transportation Primer, a document patterned on work performed by the Western Interstate Energy Board and designed as a ``comprehensive overview of the issues.`` This work differs from that earlier effort in that it is designed for the educated layman with little or no background in nuclear waste issues. In addition, this document is not a comprehensive examination of nuclear waste issues but should instead serve as a general introduction to the subject. Owing to changes in the nuclear waste management system, program activities by the US Department of Energy and other federal agencies and developing technologies, much of this information is dated quickly. While this report uses the most recent data available, readers should keep in mind that some of the material is subject to rapid change. SSEB plans periodic updates in the future to account for changes in the program. Replacement pages sew be supplied to all parties in receipt of this publication provided they remain on the SSEB mailing list.

  5. Spent fuel and high-level radioactive waste transportation report

    SciTech Connect (OSTI)

    Not Available

    1990-11-01

    This publication is intended to provide its readers with an introduction to the issues surrounding the subject of transportation of spent nuclear fuel and high-level radioactive waste, especially as those issues impact the southern region of the United States. It was originally issued by the Southern States Energy Board (SSEB) in July 1987 as the Spent Nuclear Fuel and High-Level Radioactive Waste Transportation Primer, a document patterned on work performed by the Western Interstate Energy Board and designed as a ``comprehensive overview of the issues.`` This work differs from that earlier effort in that it is designed for the educated layman with little or no background in nuclear waste issues. In addition, this document is not a comprehensive examination of nuclear waste issues but should instead serve as a general introduction to the subject. Owing to changes in the nuclear waste management system, program activities by the US Department of Energy and other federal agencies and developing technologies, much of this information is dated quickly. While this report uses the most recent data available, readers should keep in mind that some of the material is subject to rapid change. SSEB plans periodic updates in the future to account for changes in the program. Replacement pages will be supplied to all parties in receipt of this publication provided they remain on the SSEB mailing list.

  6. fuel

    National Nuclear Security Administration (NNSA)

    4%2A en Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:www.nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrogen-powered-cars

  7. fuel

    National Nuclear Security Administration (NNSA)

    4%2A en Cheaper catalyst may lower fuel costs for hydrogen-powered cars http:nnsa.energy.govblogcheaper-catalyst-may-lower-fuel-costs-hydrogen-powered-cars

  8. Regulatory Perspective on Potential Fuel Reconfiguration and Its Implication to High Burnup Spent Fuel Storage and Transportation - 13042

    SciTech Connect (OSTI)

    Li, Zhian; Rahimi, Meraj; Tang, David; Aissa, Mourad; Flaganan, Michelle; Wagner, John C.

    2013-07-01

    The recent experiments conducted by Argonne National Laboratory on high burnup fuel cladding material property show that the ductile to brittle transition temperature of high burnup fuel cladding is dependent on: (1) cladding material, (2) irradiation conditions, and (3) drying-storage histories (stress at maximum temperature) [1]. The experiment results also show that the ductile to brittle temperature increases as the fuel burnup increases. These results indicate that the current knowledge in cladding material property is insufficient to determine the structural performance of the cladding of high burnup fuel after it has been stored in a dry cask storage system for some time. The uncertainties in material property and the elevated ductile to brittle transition temperature impose a challenge to the storage cask and transportation packaging designs because the cask designs may not be able to rely on the structural integrity of the fuel assembly for control of fissile material, radiation source, and decay heat source distributions. The fuel may reconfigure during further storage and/or the subsequent transportation conditions. In addition, the fraction of radioactive materials available for release from spent fuel under normal condition of storage and transport may also change. The spent fuel storage and/or transportation packaging vendors, spent fuel shippers, and the regulator may need to consider this possible fuel reconfiguration and its impact on the packages' ability to meet the safety requirements of Part 72 and Part 71 of Title 10 of the Code of Federal Regulations. The United States Nuclear Regulatory Commission (NRC) is working with the scientists at Oak Ridge National Laboratory (ORNL) to assess the impact of fuel reconfiguration on the safety of the dry storage systems and transportation packages. The NRC Division of Spent Fuel Storage and Transportation has formed a task force to work on the safety and regulatory concerns in relevance to high burnup

  9. Development of a New Generation, High Efficiency PEM Fuel Cell Based, CHP

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    System | Department of Energy a New Generation, High Efficiency PEM Fuel Cell Based, CHP System Development of a New Generation, High Efficiency PEM Fuel Cell Based, CHP System Part of a $100 million fuel cell award announced by DOE Secretary Bodman on Oct. 25, 2006. 7_intelligent.pdf (22.28 KB) More Documents & Publications 2012 Pathways to Commercial Success: Technologies and Products Supported by the Fuel Cell Technologies Program 2011 Pathways to Commercial Success: Technologies and

  10. FORMALDEHYDE AND METHANOL DEUTERATION IN PROTOSTARS: FOSSILS FROM A PAST FAST HIGH-DENSITY PRE-COLLAPSE PHASE

    SciTech Connect (OSTI)

    Taquet, V.; Ceccarelli, C.; Kahane, C.

    2012-03-20

    Extremely high deuteration of several molecules has been observed around low-mass protostars for a decade. Among them, formaldehyde and methanol present particularly high deuteration, with observations of abundant doubly and triply deuterated forms. Both species are thought to be mainly formed on interstellar grains during the low-temperature and dense pre-collapse phase by H and D atom additions on the iced CO. We present here a theoretical study of the formaldehyde and methanol deuteration obtained with our gas-grain model, GRAINOBLE. This model takes into account the multilayer nature of the mantle and explores the robustness of the results against the uncertainties of poorly constrained chemical and surface model parameters. The comparison of the model predictions with the observations leads to two major results: (1) the observed high deuteration is obtained during the last phase of the pre-collapse stage, when the density reaches {approx}5 Multiplication-Sign 10{sup 6} cm{sup -3}, and this phase is fast, lasting only several thousands years; and (2) D and H abstraction and substitution reactions are crucial in making up the observed deuteration ratios. This work shows the power of chemical composition as a tool to reconstruct the past history of protostars.

  11. Fuels

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing ... Heavy Duty Fuels DISI Combustion HCCISCCI Fundamentals Spray Combustion Modeling ...

  12. President Requests $842.1 Million for Fossil Energy Programs | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy 842.1 Million for Fossil Energy Programs President Requests $842.1 Million for Fossil Energy Programs February 2, 2015 - 3:19pm Addthis President Obama's FY 2016 budget seeks $842.1 million for the Office of Fossil Energy (FE) to advance technologies related to the reliable, efficient, affordable and environmentally sound use of fossil fuels, implement ongoing federal responsibilities at the Naval Petroleum and Oil Shale Reserves, and manage the Strategic Petroleum Reserve,

  13. Opportunity fuels

    SciTech Connect (OSTI)

    Lutwen, R.C.

    1996-12-31

    The paper consists of viewgraphs from a conference presentation. A comparison is made of opportunity fuels, defined as fuels that can be converted to other forms of energy at lower cost than standard fossil fuels. Types of fuels for which some limited technical data is provided include petroleum coke, garbage, wood waste, and tires. Power plant economics and pollution concerns are listed for each fuel, and compared to coal and natural gas power plant costs. A detailed cost breakdown for different plant types is provided for use in base fuel pricing.

  14. Impact of High Burnup on PWR Spent Fuel Characteristics (Journal...

    Office of Scientific and Technical Information (OSTI)

    Reducing the burden of management of spent nuclear fuel is important to the future of nuclear energy. The impact of higher pressurized water reactor (PWR) fuel burnup is examined ...

  15. High specific power, direct methanol fuel cell stack

    SciTech Connect (OSTI)

    Ramsey, John C.; Wilson, Mahlon S.

    2007-05-08

    The present invention is a fuel cell stack including at least one direct methanol fuel cell. A cathode manifold is used to convey ambient air to each fuel cell, and an anode manifold is used to convey liquid methanol fuel to each fuel cell. Tie-bolt penetrations and tie-bolts are spaced evenly around the perimeter to hold the fuel cell stack together. Each fuel cell uses two graphite-based plates. One plate includes a cathode active area that is defined by serpentine channels connecting the inlet manifold with an integral flow restrictor to the outlet manifold. The other plate includes an anode active area defined by serpentine channels connecting the inlet and outlet of the anode manifold. Located between the two plates is the fuel cell active region.

  16. Dual fuel control of a high speed turbocharged diesel engine

    SciTech Connect (OSTI)

    Few, P.C.; Sardari, P.

    1987-01-01

    The modification of a Ford 7600 turbocharged diesel engine to a dual fuel engine using methane as the supplementary fuel has been carried out. The paper describes the preliminary work of dual fuel control. Two systems are examined and their behaviour is presented.

  17. Thermal Analysis of ZPPR High Pu Content Stored Fuel

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Solbrig, Charles W.; Pope, Chad L.; Andrus, Jason P.

    2014-01-01

    The Zero Power Physics Reactor (ZPPR) operated from April 18, 1969, until 1990. ZPPR operated at low power for testing nuclear reactor designs. This paper examines the temperature of Pu content ZPPR fuel while it is in storage. Heat is generated in the fuel due to Pu and Am decay and is a concern for possible cladding damage. Damage to the cladding could lead to fuel hydriding and oxidizing. A series of computer simulations were made to determine the range of temperatures potentially occuring in the ZPPR fuel. The maximum calculated fuel temperature is 292°C (558°F). Conservative assumptions in themore » model intentionally overestimate temperatures. The stored fuel temperatures are dependent on the distribution of fuel in the surrounding storage compartments, the heat generation rate of the fuel, and the orientation of fuel. Direct fuel temperatures could not be measured but storage bin doors, storage sleeve doors, and storage canister temperatures were measured. Comparison of these three temperatures to the calculations indicates that the temperatures calculated with conservative assumptions are, as expected, higher than the actual temperatures. The maximum calculated fuel temperature with the most conservative assumptions is significantly below the fuel failure criterion of 600°C (1,112°F).« less

  18. High Burn-Up Spent Nuclear Fuel Vibration Integrity Study

    SciTech Connect (OSTI)

    Wang, Jy-An John; Wang, Hong; Jiang, Hao; Bevard, Bruce Balkcom; Howard, Rob L; Scaglione, John M

    2015-01-01

    The Oak Ridge National Laboratory (ORNL) has developed the cyclic integrated reversible-bending fatigue tester (CIRFT) approach to successfully demonstrate the controllable fatigue fracture on high burnup (HBU) spent nuclear fuel (SNF) in a normal vibration mode. CIRFT enables examination of the underlying mechanisms of SNF system dynamic performance. Due to the inhomogeneous composite structure of the SNF system, the detailed mechanisms of the pellet-pellet and pellet-clad interactions and the stress concentration effects at the pellet-pellet interface cannot be readily obtained from a CIRFT system measurement. Therefore, finite element analyses (FEAs) are used to translate the global moment-curvature measurement into local stress-strain profiles for further investigation. The major findings of CIRFT on the HBU SNF are as follows: SNF system interface bonding plays an important role in SNF vibration performance. Fuel structure contributes to SNF system stiffness. There are significant variations in stress and curvature of SNF systems during vibration cycles resulting from segment pellets and clad interactions. SNF failure initiates at the pellet-pellet interface region and appears to be spontaneous.

  19. Developing a High Thermal Conductivity Fuel with Silicon Carbide Additives

    SciTech Connect (OSTI)

    baney, Ronald; Tulenko, James

    2012-11-20

    The objective of this research is to increase the thermal conductivity of uranium oxide (UO{sub 2}) without significantly impacting its neutronic properties. The concept is to incorporate another high thermal conductivity material, silicon carbide (SiC), in the form of whiskers or from nanoparticles of SiC and a SiC polymeric precursor into UO{sub 2}. This is expected to form a percolation pathway lattice for conductive heat transfer out of the fuel pellet. The thermal conductivity of SiC would control the overall fuel pellet thermal conductivity. The challenge is to show the effectiveness of a low temperature sintering process, because of a UO{sub 2}-SiC reaction at 1,377°C, a temperature far below the normal sintering temperature. Researchers will study three strategies to overcome the processing difficulties associated with pore clogging and the chemical reaction of SiC and UO{sub 2} at temperatures above 1,300°C:

  20. High-Level Functional and Operational Requirements for the Advanced Fuel Cycle Facilty

    SciTech Connect (OSTI)

    Charles Park

    2006-12-01

    High-Level Functional & Operational Requirements for the AFCF -This document describes the principal functional and operational requirements for the proposed Advanced Fuel Cycle Facility (AFCF). The AFCF is intended to be the world's foremost facility for nuclear fuel cycle research, technology development, and demonstration. The facility will also support the near-term mission to develop and demonstrate technology in support of fuel cycle needs identified by industry, and the long-term mission to retain and retain U.S. leadership in fuel cycle operations. The AFCF is essential to demonstrate a more proliferation-resistant fuel cycle and make long-term improvements in fuel cycle effectiveness, performance and economy.

  1. A high-elevation, multi-proxy biotic and environmental record of MIS 64 from the Ziegler Reservoir fossil site, Snowmass Village, Colorado, USA

    SciTech Connect (OSTI)

    Ian M. Miller; Mitchell A. Plummer; Various Others

    2014-10-01

    In North America, terrestrial records of biodiversity and climate change that span Marine Oxygen Isotope Stage (MIS) 5 are rare. Where found, they provide insight into how the coupling of the oceanatmosphere system is manifested in biotic and environmental records and how the biosphere responds to climate change. In 20102011, construction at Ziegler Reservoir near Snowmass Village, Colorado (USA) revealed a nearly continuous, lacustrine/wetland sedimentary sequence that preserved evidence of past plant communities between ~140 and 55 ka, including all of MIS 5. At an elevation of 2705 m, the Ziegler Reservoir fossil site also contained thousands of well-preserved bones of late Pleistocene megafauna, including mastodons, mammoths, ground sloths, horses, camels, deer, bison, black bear, coyotes, and bighorn sheep. In addition, the site contained more than 26,000 bones from at least 30 species of small animals including salamanders, otters, muskrats, minks, rabbits, beavers, frogs, lizards, snakes, fish, and birds. The combination of macro- and micro-vertebrates, invertebrates, terrestrial and aquatic plant macrofossils, a detailed pollen record, and a robust, directly dated stratigraphic framework shows that high-elevation ecosystems in the Rocky Mountains of Colorado are climatically sensitive and varied dramatically throughout MIS 5

  2. Micronized coal-fired retrofit system for SO{sub x} reduction Krakow clean fossil fuels and energy efficiency program. Final report

    SciTech Connect (OSTI)

    1997-04-01

    This report describes results of a technical, financial and environmental assessment study for a project, which would have included a new TCS micronized coal-fired heating plant for the Produkcja I Hodowla Roslin Ogrodniczych (PHRO) Greenhouse Complex; Krzeszowice, Poland. Project site is about 20 miles west of Krakow, Poland. During the project study period, PHRO utilized 14 heavy oil-fired boilers to produce heat for its greenhouse facilities and also home heating to several adjacent apartment housing complexes. The boilers burn a high-sulfur content heavy crude oil, called mazute, The project study was conducted during a period extended from March 1996 through February 1997. For size orientation, the PHRO Greenhouse complex grows a variety of vegetables and flowers for the Southern Poland marketplace. The greenhouse area under glass is very large and equivalent to approximately 50 football fields, The new micronized coal fired boiler would have: (1) provided a significant portion of the heat for PHRO and a portion of the adjacent apartment housing complexes, (2) dramatically reduced sulfur dioxide air pollution emissions, while satisfying new Polish air regulations, and (3) provided attractive savings to PHRO, based on the quantity of displaced oil.

  3. Micronized coal-fired retrofit system for SO{sub x} reduction: Krakow clean fossil fuels and energy efficiency program. Technical progress report number 2

    SciTech Connect (OSTI)

    Not Available

    1994-12-31

    The objective of the project is to retrofit the Balice Boilerhouse with a TCS Coal Micronization System and Amerex baghouses to achieve higher combustion efficiencies and lower air emissions, including S02, NOX, CO and particulate matter. The Balice Boilerhouse is located adjacent to the Krakow Airport and provides heating steam for the Polish Military Unit No. 1616, which is based in the vicinity of the Krakow airport. Sulfur dioxide (SO{sub 2}) reduction during combustion with micronized coal is possible by co-micronizing limestone with coal. Nitrogen oxide reductions utilizing a TCS system result primarily from: the reduced combustion temperature of a micronized coal flame, lower excess air than other conventional coal combustion systems, and staged combustion achieved with the proprietary TCS Low-NO{sub x} burner. Carbon monoxide reductions result because of the extremely high degree of carbon burnout achieved with micronized coal. The original project scope of work envisioned that TCS coal micronization systems would be retrofitted to four existing boilers at the Balice Boilerhouse. However, shortly after the project`s start-up in March 1994, the Polish Military announced that it desired and intended to decommission its existing four boilers (due to old age and poor general condition) and replace them with two new units. As such, the project`s scope of equipment supply and assessment expanded from use of the existing boilers, to requirements for implementing new units. This report describes the progress made to date on the various tasks.

  4. Tsiklauri-Durst combined cycle (T-D Cycle{trademark}) application for nuclear and fossil-fueled power generating plants

    SciTech Connect (OSTI)

    Tsiklauri, B.; Korolev, V.N.; Durst, B.M.; Shen, P.K.

    1998-07-01

    The Tsiklauri-Durst combined cycle is a combination of the best attributes of both nuclear power and combined cycle gas power plants. A technology patented in 1994 by Battelle Memorial Institute offers a synergistic approach to power generation. A typical combined cycle is defined as the combination of gas turbine Brayton Cycle, topping steam turbine Rankine Cycle. Exhaust from the gas turbine is used in heat recovery steam generators to produce steam for a steam turbine. In a standard combined cycle gas turbine-steam turbine application, the gas turbine generates about 65 to 70 percent of system power. The thermal efficiency for such an installation is typically about 45 to 50 percent. A T-D combined cycle takes a new, creative approach to combined cycle design by directly mixing high enthalpy steam from the heat recovery steam generator, involving the steam generator at more than one pressure. Direct mixing of superheated and saturated steam eliminates the requirement for a large heat exchanger, making plant modification simple and economical.

  5. New Polymeric Proton Conductors for Water-free and High-temperature Fuel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cells | Department of Energy Polymeric Proton Conductors for Water-free and High-temperature Fuel Cells New Polymeric Proton Conductors for Water-free and High-temperature Fuel Cells Presentation on New Polymeric Proton Conductors for Water-free and High-temperature Fuel Cells to the High Temperature Membrane Working Group Meeting held in Arlington, Virginia, May 26,2005. htmwg05_kerr.pdf (158.09 KB) More Documents & Publications Polyelectrolyte Materials for High Temperature Fuel Cells

  6. Growing attraction of refuse-derived fuels

    SciTech Connect (OSTI)

    Singh, R.

    1981-09-08

    A review of Dr. Andrew Porteous' book, Refuse Derived Fuels is presented. The escalating price of fossil fuel, particularily oil, together with the high cost of handling and transporting refuse makes the idea of refuse-derived fuel production an attractive and economic proposition. Refuse-derived fuel production is discussed and the various manufacturing processes in the UK and the USA are described. The pyrolysis of refuse for the production of gas, oil or heat and the production of methane and ethyl alcohol or other possibilities for refuse conversion.

  7. APPLICATION OF CERAMICS TO HIGH PRESSURE FUEL SYSTEMS

    SciTech Connect (OSTI)

    Mandler, Jr., William F.

    2000-08-20

    Diesel fuel systems are facing increased demands as engines with reduced emissions are developed. Injection pressures have increased to provide finer atomization of fuel for more efficient combustion, Figure 1. This increases the mechanical loads on the system and requires tighter clearances between plungers and bores to prevent leakage. At the same time, fuel lubricity has decreased as a byproduct of reducing the sulfur levels in fuel. Contamination of fuel by water and debris is an ever-present problem. For oil-lubricated fuel system components, increased soot loading in the oil results in increased wear rates. Additionally, engine manufacturers are lengthening warranty periods for engines and systems. This combination of factors requires the development of new materials to counteract the harsher tribological environment.

  8. FY2015 Status Report: CIRFT Testing of High-Burnup Used Nuclear Fuel Rods

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    from Pressurized Water Reactor and BWR Environments | Department of Energy FY2015 Status Report: CIRFT Testing of High-Burnup Used Nuclear Fuel Rods from Pressurized Water Reactor and BWR Environments FY2015 Status Report: CIRFT Testing of High-Burnup Used Nuclear Fuel Rods from Pressurized Water Reactor and BWR Environments High-burnup spent nuclear fuel cladding has a significant amount of microcracks and hydrides which will reduce the stress intensity required for crack growth.

  9. High power density fuel cell comprising an array of microchannels

    DOE Patents [OSTI]

    Morse, Jeffrey D.; Upadhye, Ravindra S.; Spadaccini, Christopher M.; Park, Hyung Gyu

    2013-10-15

    A fuel cell according to one embodiment includes a porous electrolyte support structure defining an array of microchannels, the microchannels including fuel and oxidant microchannels; fuel electrodes formed along some of the microchannels; and oxidant electrodes formed along other of the microchannels. A method of making a fuel cell according to one embodiment includes forming an array of walls defining microchannels therebetween using at least one of molding, stamping, extrusion, injection and electrodeposition; processing the walls to make the walls porous, thereby creating a porous electrolyte support structure; forming anode electrodes along some of the microchannels; and forming cathode electrodes along other of the microchannels. Additional embodiments are also disclosed.

  10. High Temperature Fuel Cell (Phosphoric Acid) Manufacturing R&D

    Broader source: Energy.gov [DOE]

    Presented at the NREL Hydrogen and Fuel Cell Manufacturing R&D Workshop in Washington, DC, August 11-12, 2011.

  11. Proceedings of the Eight Annual Conference on Fossil Energy Materials

    SciTech Connect (OSTI)

    Cole, N.C.; Judkins, R.R.

    1994-08-01

    Objective of the meeting was to conduct R and D on materials for longer-term fossil energy applications as well as for generic needs of various fossil fuel technologies. The work is divided into ceramics, new alloys, corrosion, and technology assessment/transfer. The 39 papers are arranged under the session headings: ceramics, ceramics and new alloys, and intermetallics and advanced austenitics; a workshop on new materials development and applications is summarized briefly. The papers are processed separately for the data base.

  12. ABSTRACTS: Seventh annual conference on fossil energy materials

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    Objective of the Advanced Research and Technology Development materials program is to conduct R and D on materials for fossil energy applications (coal processing, coal liquefaction, gasification, heat engines and recovery, combustion systems, fuel cells). Research is aimed at better understanding of materials in fossil energy environments and development of new materials for improvement of plant operations and reliability. Abstracts are given of 37 papers on ceramics/composites, intermetallics (iron aluminides, etc.), and advanced austenitics. (DLC)

  13. ABSTRACTS: Seventh annual conference on fossil energy materials

    SciTech Connect (OSTI)

    Not Available

    1993-06-01

    Objective of the Advanced Research and Technology Development materials program is to conduct R and D on materials for fossil energy applications (coal processing, coal liquefaction, gasification, heat engines and recovery, combustion systems, fuel cells). Research is aimed at better understanding of materials in fossil energy environments and development of new materials for improvement of plant operations and reliability. Abstracts are given of 37 papers on ceramics/composites, intermetallics (iron aluminides, etc.), and advanced austenitics. (DLC)

  14. Fossil Energy Advanced Research and Technology Development Materials Program

    SciTech Connect (OSTI)

    Cole, N.C.; Judkins, R.R.

    1992-12-01

    Objective of this materials program is to conduct R and D on materials for fossil energy applications with focus on longer-term and generic needs of the various fossil fuel technologies. The projects are organized according to materials research areas: (1) ceramics, (2) new alloys: iron aluminides, advanced austenitics and chromium niobium alloys, and (3) technology development and transfer. Separate abstracts have been prepared.

  15. DOE-Managed High-Level Radioactive Waste and Spent Nuclear Fuel

    Office of Environmental Management (EM)

    Assessment of Disposal Options for DOE-Managed High-Level Radioactive Waste and Spent ... level radioactive waste and spent nuclear fuel in a single repository or repositories. ...

  16. Fossil Energy Advanced Technologies (2008 - 2009) | Department...

    Office of Environmental Management (EM)

    Fossil Energy Advanced Technologies (2008 - 2009) Fossil Energy Advanced Technologies (2008 - 2009) Fossil Energy Advanced Technologies (2008 - 2009) (383.24 KB) Amendment: Energy ...

  17. Renewable hydrogen production for fossil fuel processing

    SciTech Connect (OSTI)

    Greenbaum, E.; Lee, J.W.; Tevault, C.V.; Blankinship, S.L.

    1996-06-01

    In the current and prevailing concept of photosynthesis, the Z-scheme, first proposed by Hill and Bendall, PSII can split water, but is not thought to be able to perform one of PSI`s assigned functions-the reduction of ferredoxin/NADP{sup +} essential for CO{sub 2} assimilation. The Z-scheme therefore requires both PSII and PSI working in sequence for complete photosynthesis using water as the source of electrons and CO{sub 2} as the terminal electron acceptor. Despite disagreement from several investigators, the Z-scheme has become the textbook model of photosynthesis. Recently, we have demonstrated that sustained photoassimilation of CO{sub 2} and evolution of H{sub 2} and O{sub 2} in minimal medium can be achieved by the PSII light reaction without involvement of PSI in a PSI-deficient mutant of Chlamydomonas grown photoheterotrophically using an organic nutrient (acetate). In this paper, we report a more exciting discovery that PSI-deficient mutants of Chlamydomonas were capable of growing photoautotrophically with CO{sub 2} as the sole source of carbon. Since the Z-scheme requires both PSI and PSII working together in series for complete photosynthesis, it predicts that PSI-deficient mutants of green algae will not grow photoautotrophically. The discovery of photoautotrophic growth of PSI-deficient green algae without any organic nutrients, therefore, provides clear and solid evidence for the existence of a new type of photosynthesis-{open_quotes}PSII photosynthesis{close_quotes} that is an alternative to the Z-scheme. Our discovery may also provide an explanation for many {open_quotes}anomalous{close_quotes} quantum requirements that have been reported over the last 50 years, but failed to be explained by the Z-scheme.

  18. Transitioning from fossil-fueled to electrifie

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    depends on developing batteries that are increasingly economical, reliable, and safe. A vehicle battery is a large investment and carries with it a requirement for a long, reliable life. Substantially improving battery performance requires greatly improving the energy storage community's fundamental understanding of the complex processes active in batteries, particularly those that degrade a battery's service lifetime. As a lithium-ion battery discharges and then is recharged, lithium ions

  19. Enhancing carburization resistance in fossil fuel environments

    SciTech Connect (OSTI)

    Smith, G.D.; Tassen, C.S.

    1995-11-01

    There has been steady progress in the development of wrought alloys for use in gaseous carburizing environments. Contributing significantly to this progress is a growing knowledge base of the role of scales in enhancing carburization resistance. Future improvements in carburization resistance must build upon this level of understanding. This paper seeks to survey some of this wealth of information regarding scale characteristics of commercial wrought nickel-containing alloys as these scales are influenced by environment and alloy composition. Some suggestions as to the future direction of alloy development with regard to scale optimization and minimization of carburization resistance are proposed.

  20. Microsoft Word - Fossil Fuel EA Final EA

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE compared the Proposed Rule with the "no-action alternative" of using the current Federal building energy efficiency standards found at 10 CFR Part 433 and 10 CFR Part 435...

  1. Disclosure of Permitted Communication Concerning Fossil Fuel...

    Broader source: Energy.gov (indexed) [DOE]

    the rulemaking referenced above. The communications occurred at a meeting held on February 13, 2013. DOE 433 ex parte memo.pdf (16.1 KB) More Documents & Publications Disclosure of ...

  2. Fireside corrosion probes for fossil fuel combustion

    SciTech Connect (OSTI)

    Covino, B.S., Jr.; Bullard, S.J.; Ziomek-Moroz, M.; Holcomb, G.R.; Eden, D.A.

    2006-03-01

    Electrochemical corrosion rate probes have been constructed and tested along with mass loss coupons in environments consisting of N2/O2/CO2/SO2 plus water vapor. Temperatures ranged from 450° to 700°C. Results show that electrochemical corrosion rates for ash-covered mild steel are a function of time, temperature, and gaseous environment. Correlation between the electrochemical and mass loss corrosion rates was poor.

  3. Microstructural Characterization of High Burn-up Mixed Oxide Fast Reactor Fuel

    SciTech Connect (OSTI)

    Melissa C. Teague; Brian P. Gorman; Steven L. Hayes; Douglas L. Porter; Jeffrey King

    2013-10-01

    High burn-up mixed oxide fuel with local burn-ups of 3.423.7% FIMA (fissions per initial metal atom) were destructively examined as part of a research project to understand the performance of oxide fuel at extreme burn-ups. Optical metallography of fuel cross-sections measured the fuel-to-cladding gap, clad thickness, and central void evolution in the samples. The fuel-to-cladding gap closed significantly in samples with burn-ups below 79% FIMA. Samples with burn-ups in excess of 79% FIMA had a reopening of the fuel-to-cladding gap and evidence of joint oxide-gain (JOG) formation. Signs of axial fuel migration to the top of the fuel column were observed in the fuel pin with a peak burn-up of 23.7% FIMA. Additionally, high burn-up structure (HBS) was observed in the two highest burn-up samples (23.7% and 21.3% FIMA). The HBS layers were found to be 35 times thicker than the layers found in typical LWR fuel. The results of the study indicate that formation of JOG and or HBS prevents any significant fuel-cladding mechanical interaction from occurring, thereby extending the potential life of the fuel elements.

  4. Hawaii energy strategy project 2: Fossil energy review. Task 1: World and regional fossil energy dynamics

    SciTech Connect (OSTI)

    Breazeale, K.; Isaak, D.T.; Yamaguchi, N.; Fridley, D.; Johnson, C.; Long, S.

    1993-12-01

    This report in the Hawaii Energy Strategy Project examines world and regional fossil energy dynamics. The topics of the report include fossil energy characteristics, the world oil industry including reserves, production, consumption, exporters, importers, refining, products and their uses, history and trends in the global oil market and the Asia-Pacific market; world gas industry including reserves, production, consumption, exporters, importers, processing, gas-based products, international gas market and the emerging Asia-Pacific gas market; the world coal industry including reserves, classification and quality, utilization, transportation, pricing, world coal market, Asia-Pacific coal outlook, trends in Europe and the Americas; and environmental trends affecting fossil fuels. 132 figs., 46 tabs.

  5. Extended Platinum Nanotubes as Fuel Cell Catalysts

    SciTech Connect (OSTI)

    Alia, S.; Pivovar, B. S.; Yan, Y.

    2012-01-01

    Energy consumption has relied principally on fossil fuels as an energy source; fuel cells, however, can provide a clean and sustainable alternative, an answer to the depletion and climate change concerns of fossil fuels. Within proton exchange membrane fuel cells, high catalyst cost and poor durability limit the commercial viability of the device. Recently, platinum nanotubes (PtNTs) were studied as durable, active catalysts, providing a platform to meet US Department of Energy vehicular activity targets.[1] Porous PtNTs were developed to increase nanotube surface area, improving mass activity for oxygen reduction without sacrificing durability.[2] Subsurface platinum was then replaced with palladium, forming platinum-coated palladium nanotubes.[3] By forming a core shell structure, platinum utilization was increased, reducing catalyst cost. Alternative substrates have also been examined, modifying platinum surface facets and increasing oxygen reduction specific activity. Through modification of the PtNT platform, catalyst limitations can be reduced, ensuring a commercially viable device.

  6. Proceedings of the Seventh Annual Conference on Fossil Energy Materials. Fossil Energy AR and TD Materials Program

    SciTech Connect (OSTI)

    Cole, N.C.; Judkins, R.R.

    1993-07-01

    Objective of the AR&TD Materials Program is to conduct research and development on materials for longer-term fossil energy applications as well as for generic needs of various fossil fuel technologies. The 37 papers are arranged into 3 sessions: ceramics, new alloys/intermetallics, and new alloys/advanced austenitics. Selected papers have been indexed separately for inclusion in the Energy Science and Technology Database.

  7. Fossil and synthetic fuels: miscellaneous. Part 1. Hearings before the Subcommittee on Fossil and Synthetic Fuels of the Committee on Energy and Commerce, House of Representatives, Ninety-Seventh Congress, First Session on Extension of IEA antitrust defense authorities, February 26, 1981, H. R. 2166, Department of Transportation authorization request, April 8, 1981, Gasohol usage in federal vehicles, July 30, 1981

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    Part I of the hearing record covers testimony relating to the extension of antitrust defense availability to the International Energy Agency (IEA); an authorization request by the Department of Transportation (DOT) to comply with pipeline safety regulations; and the administration's reluctance to promote gasohol use in federal vehicles. The first day's hearing included discussion of H.R. 2166, which extended the IEA authority by amending the Energy Policy and Conservation Act, and the testimony of four witnesses representing federal agencies involved in international affairs. On the second day, three DOT witnesses described pipeline-safety programs, enforcement, and procedures, with emphasis on the transport of liquefied natural gas. On the third day, nine witnesses representing gasohol-producing states, the US Army Equipment Research and Development Command, federal fleet services, and DOE examined the appropriateness and compliance record of Executive Order 12261 mandating gasohol for federally owned or leased vehicles. At issue was the need to convert Midwest grains to fuel at a time when oil is plentiful, the performance of alcohol fuels, and the administration's preference for working through the marketplace. Additional material submitted for the record follows each day's testimony. (DCK)

  8. Fossil Energy Program semiannual progress report for October 1991--March 1992

    SciTech Connect (OSTI)

    Judkins, R.R.

    1992-11-01

    This report covers progress made during the period October 1, 1991, through March 31, 1992, for research and development projects that contribute to the advancement of various fossil energy technologies. Projects on the Fossil Energy Program are supported by the DOE Office of Fossil Energy, the DOE Morgantown Energy Technology Center, the DOE Pittsburgh Energy Technology Center, the DOE Fossil Energy Clean Coal Technology Program, the DOE Office of Basic Energy Sciences, the DOE Fossil Energy Office of Petroleum Reserves, the DOE Fossil Energy Naval Petroleum and Oil Shale Reserves, and the US Agency for International Development. The Fossil Energy Program organization chart is shown in the appendix. Topics discussed are under the following projects: materials research and developments; environmental analysis support; coal conversion development; coal combustion research; and fossil fuels supplies modeling and research.

  9. Materials and Modules for Low Cost, High Performance Fuel Cell Humidifiers

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Modules for Low Cost, High Performance Fuel Cell Humidifiers Materials and Modules for Low Cost, High Performance Fuel Cell Humidifiers Presented at the Department of Energy Fuel Cell Projects Kickoff Meeting, September 1 - October 1, 2009 johnson_gore_kickoff.pdf (442.96 KB) More Documents & Publications Advance Patent Waiver W(A)2010-041 Kick-Off Meeting for New Fuel Cell Projects CARISMA: A Networking Project for High Temperature PEMFC MEA Activities in Europ

  10. High Pressure Fuel Storage Cylinders Periodic Inspection and End of Life

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Issues | Department of Energy Fuel Storage Cylinders Periodic Inspection and End of Life Issues High Pressure Fuel Storage Cylinders Periodic Inspection and End of Life Issues These slides were presented at the Onboard Storage Tank Workshop on April 29, 2010. highpressure_fuelcylinders_ostw.pdf (1011.45 KB) More Documents & Publications Lessons Learned from Practical Field Experience with High Pressure Gaseous Fuels The Compelling Case for Natural Gas Vehicles U.S. Department of Energy

  11. Process Modeling Results of Bio-Syntrolysis: Converting Biomass to Liquid Fuel with High Temperature Steam Electrolysis

    SciTech Connect (OSTI)

    G. L. Hawkes; M. G. McKellar; R. Wood; M. M. Plum

    2010-06-01

    A new process called Bio-Syntrolysis is being researched at the Idaho National Laboratory (INL) investigating syngas production from renewable biomass that is assisted with high temperature steam electrolysis (HTSE). The INL is the world leader in researching HTSE and has recently produced hydrogen from high temperature solid oxide cells running in the electrolysis mode setting several world records along the way. A high temperature (~800°C) heat source is necessary to heat the steam as it goes into the electrolytic cells. Biomass provides the heat source and the carbon source for this process. Syngas, a mixture of hydrogen and carbon monoxide, can be used for the production of synthetic liquid fuels via Fischer-Tropsch processes. This concept, coupled with fossil-free electricity, provides a possible path to reduced greenhouse gas emissions and increased energy independence, without the major infrastructure shift that would be required for a purely hydrogen-based transportation system. Furthermore, since the carbon source is obtained from recyclable biomass, the entire concept is carbon-neutral

  12. Direct Utilization of Coal Syngas in High Temperature Fuel Cells

    SciTech Connect (OSTI)

    Celik, Ismail B.

    2014-10-30

    This EPSCoR project had two primary goals: (i) to build infrastructure and work force at WVU to support long-term research in the area of fuel cells and related sciences; (ii) study effects of various impurities found in coal-syngas on performance of Solid Oxide Fuel Cells (SOFC). As detailed in this report the WVU research team has made significant accomplishments in both of these areas. What follows is a brief summary of these accomplishments: State-of-the-art test facilities and diagnostic tools have been built and put into use. These include cell manufacturing, half-cell and full-cell test benches, XPS, XRD, TEM, Raman, EDAX, SEM, EIS, and ESEM equipment, unique in-situ measurement techniques and test benches (Environmental EM, Transient Mass-Spectrometer-MS, and IR Optical Temperature measurements). In addition, computational capabilities have been developed culminating in a multi-scale multi-physics fuel cell simulation code, DREAM-SOFC, as well as a Beowulf cluster with 64 CPU units. We have trained 16 graduate students, 10 postdoctoral fellows, and recruited 4 new young faculty members who have actively participated in the EPSCoR project. All four of these faculty members have already been promoted to the tenured associate professor level. With the help of these faculty and students, we were able to secure 14 research awards/contracts amounting to a total of circa $5.0 Million external funding in closely related areas of research. Using the facilities mentioned above, the effects of PH3, HCl, Cl2, and H2S on cell performance have been studied in detail, mechanisms have been identified, and also remedies have been proposed and demonstrated in the laboratory. For example, it has been determined that PH3 reacts rapidly with Ni to from secondary compounds which may become softer or even melt at high temperature and then induce Ni migration to the surface of the cell changing the material and micro-structural properties of the cell drastically. It is found that

  13. Engine with hydraulic fuel injection and ABS circuit using a single high pressure pump

    DOE Patents [OSTI]

    Bartley, Bradley E.; Blass, James R.; Gibson, Dennis H.

    2001-01-01

    An engine system comprises a hydraulically actuated fuel injection system and an ABS circuit connected via a fluid flow passage that provides hydraulic fluid to both the fuel injection system and to the ABS circuit. The hydraulically actuated system includes a high pressure pump. The fluid control passage is in fluid communication with an outlet from the high pressure pump.

  14. High power density fuel cell comprising an array of microchannels

    DOE Patents [OSTI]

    Sopchak, David A; Morse, Jeffrey D; Upadhye, Ravindra S; Kotovsky, Jack; Graff, Robert T

    2014-05-06

    A phosphoric acid fuel cell according to one embodiment includes an array of microchannels defined by a porous electrolyte support structure extending between bottom and upper support layers, the microchannels including fuel and oxidant microchannels; fuel electrodes formed along some of the microchannels; and air electrodes formed along other of the microchannels. A method of making a phosphoric acid fuel cell according to one embodiment includes etching an array of microchannels in a substrate, thereby forming walls between the microchannels; processing the walls to make the walls porous, thereby forming a porous electrolyte support structure; forming anode electrodes along some of the walls; forming cathode electrodes along other of the walls; and filling the porous electrolyte support structure with a phosphoric acid electrolyte. Additional embodiments are also disclosed.

  15. High Temperature Fuel Cell (Phosphoric Acid) Manufacturing R...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Net Shape Flow Field Dry Film Thickness 2.7 mm 0.7 mm 1.7 mm Density 1.4 gmml Density ... Removes CO from anode inlet gas AMMONIA SCRUBBER Removes ammonia from fuel EXHAUST ...

  16. Development of a high-output dual-fuel engine

    SciTech Connect (OSTI)

    Danyluk, P.R. . Fairbanks Morse Engineering Division)

    1993-10-01

    This paper presents the results of a new dual-fuel engine development program. The engine is the largest commercially available in terms of power output (650 hp/cyl) and features very low emissions (1 g/hp-hr NO[sub x]) and excellent fuel consumption (43 percent thermal efficiency). A two-cylinder turbocharged prototype was designed and built for the initial development. Results from testing on 18-cylinder production versions are also reported.

  17. Methods for manufacturing porous nuclear fuel elements for high-temperature gas-cooled nuclear reactors

    DOE Patents [OSTI]

    Youchison, Dennis L.; Williams, Brian E.; Benander, Robert E.

    2010-02-23

    Methods for manufacturing porous nuclear fuel elements for use in advanced high temperature gas-cooled nuclear reactors (HTGR's). Advanced uranium bi-carbide, uranium tri-carbide and uranium carbonitride nuclear fuels can be used. These fuels have high melting temperatures, high thermal conductivity, and high resistance to erosion by hot hydrogen gas. Tri-carbide fuels, such as (U,Zr,Nb)C, can be fabricated using chemical vapor infiltration (CVI) to simultaneously deposit each of the three separate carbides, e.g., UC, ZrC, and NbC in a single CVI step. By using CVI, a thin coating of nuclear fuel may be deposited inside of a highly porous skeletal structure made, for example, of reticulated vitreous carbon foam.

  18. Porous nuclear fuel element with internal skeleton for high-temperature gas-cooled nuclear reactors

    DOE Patents [OSTI]

    Youchison, Dennis L.; Williams, Brian E.; Benander, Robert E.

    2013-09-03

    Porous nuclear fuel elements for use in advanced high temperature gas-cooled nuclear reactors (HTGR's), and to processes for fabricating them. Advanced uranium bi-carbide, uranium tri-carbide and uranium carbonitride nuclear fuels can be used. These fuels have high melting temperatures, high thermal conductivity, and high resistance to erosion by hot hydrogen gas. Tri-carbide fuels, such as (U,Zr,Nb)C, can be fabricated using chemical vapor infiltration (CVI) to simultaneously deposit each of the three separate carbides, e.g., UC, ZrC, and NbC in a single CVI step. By using CVI, the nuclear fuel may be deposited inside of a highly porous skeletal structure made of, for example, reticulated vitreous carbon foam.

  19. Porous nuclear fuel element for high-temperature gas-cooled nuclear reactors

    DOE Patents [OSTI]

    Youchison, Dennis L.; Williams, Brian E.; Benander, Robert E.

    2011-03-01

    Porous nuclear fuel elements for use in advanced high temperature gas-cooled nuclear reactors (HTGR's), and to processes for fabricating them. Advanced uranium bi-carbide, uranium tri-carbide and uranium carbonitride nuclear fuels can be used. These fuels have high melting temperatures, high thermal conductivity, and high resistance to erosion by hot hydrogen gas. Tri-carbide fuels, such as (U,Zr,Nb)C, can be fabricated using chemical vapor infiltration (CVI) to simultaneously deposit each of the three separate carbides, e.g., UC, ZrC, and NbC in a single CVI step. By using CVI, the nuclear fuel may be deposited inside of a highly porous skeletal structure made of, for example, reticulated vitreous carbon foam.

  20. DOE Fuel Cell Pre-Solicitation Workshop - Breakout Group 3: HIGH TEMP

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (SOFC) SYSTEM AND BOP | Department of Energy 3: HIGH TEMP (SOFC) SYSTEM AND BOP DOE Fuel Cell Pre-Solicitation Workshop - Breakout Group 3: HIGH TEMP (SOFC) SYSTEM AND BOP Report from Breakout Group 3 of the DOE Fuel Cell Pre-Solicitation Workshop, March 16-17, 2010 fuelcell_pre-solicitation_wkshop_hi_temp_sofc.pdf (55.86 KB) More Documents & Publications DOE Fuel Cell Pre-Solicitation Workshop - Breakout Group 5: Long-Term Innovative Technologies Solid Oxide Fuel Cell System (SOFC)

  1. Oil Shale and Other Unconventional Fuels Activities | Department...

    Office of Environmental Management (EM)

    Naval Reserves Oil Shale and Other Unconventional Fuels Activities Oil Shale and Other Unconventional Fuels Activities The Fossil Energy program in oil shale focuses on ...

  2. Improving Catalyst Efficiency in Bio-Based Hydrocarbon Fuels...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Converting biomass, an abun- dant and renewable resource, into liquid transportation fuels has attracted significant atten- tion because of depleting fossil fuel reserves and...

  3. Establishing Specifications for Low Enriched Uranium Fuel Operations Conducted Outside the High Flux Isotope Reactor Site

    SciTech Connect (OSTI)

    Pinkston, Daniel; Primm, Trent; Renfro, David G; Sease, John D

    2010-10-01

    The National Nuclear Security Administration (NNSA) has funded staff at Oak Ridge National Laboratory (ORNL) to study the conversion of the High Flux Isotope Reactor (HFIR) from the current, high enriched uranium fuel to low enriched uranium fuel. The LEU fuel form is a metal alloy that has never been used in HFIR or any HFIR-like reactor. This report provides documentation of a process for the creation of a fuel specification that will meet all applicable regulations and guidelines to which UT-Battelle, LLC (UTB) the operating contractor for ORNL - must adhere. This process will allow UTB to purchase LEU fuel for HFIR and be assured of the quality of the fuel being procured.

  4. Materials issues in solid oxide fuel cell systems

    SciTech Connect (OSTI)

    Ziomek-Moroz, M.

    2007-03-02

    Hydrogen is the main fuel for all types of fuel cells except direct methanol fuel cells. Hydrogen can be generated from all manner of fossil fuels, including coal, natural gas, diesel, gasoline, other hydrocarbons, and oxygenates (e.g., methanol, ethanol, butanol, etc.). The presence of carbon oxides in the fuel can cause significant performance problems resulting in decreasing the cell performance of fuel cells, including solid oxide fuel cells (SOFC). In the SOFC, the high (800-1000C) operating temperature yields advantages (e.g., internal fuel reforming) and disadvantages (e.g., material selection and degradation problems). Significant progress in reducing the operating temperature of the SOFC below ~800 C may allow less expensive metallic materials to be used for interconnects. This presentation provides insight on the material performance of ferritic steels in fuels containing carbon oxides and seeks to quantify the extent of possible degradation due to carbon species in the gas stream.

  5. Fossil plant self assessment

    SciTech Connect (OSTI)

    Bozgo, R.H.; Maguire, B.A.

    1996-07-01

    The increasingly competitive environment of the electric utility business is focusing utilities attention on reducing the cost of electricity generation. By using benchmark indicators, gains are being sought in plant material condition with corresponding improvements in operating efficiency and capacity factor as well as reductions in Operating and Maintenance (O&M) costs. In designing a process for improvement, Consolidated Edison Company of New York, Inc. (Con Edison) plant managers were asked to review and approve objectives and criteria for Fossil Plant Operations. The program methods included optimizing work processes (including material condition, maintenance programs, work control systems, and personnel performance); team building techniques to foster personnel buy-in of the process; and long term cultural change to insure an ongoing continuous improvement process with measurable results. The program begins with a self assessment of each plant based upon the approved Objectives and Criteria. The Criteria and Review Approaches (CRAs) are established by senior management and the review team. The criteria cover Management, Operations, Maintenance, and Support Functions including Technical Support, Training and Qualification, Environmental Compliance, Chemistry, and Safety and Emergency Preparedness. The Assessment is followed by a review of corrective action plans and an interim corrective action review. Annual Assessments are planned to ensure continuous improvement. Emphasis is placed on progress made in maintenance at the fossil stations.

  6. DOE - Fossil Energy:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    103098 Can Husky Gas Marketing Inc. 1432 1432-A FE98-87-NG 110408 Can Mex Pemex Gas Y Petroquimica Basica 1435 FE98-92-NG 112098 Can Union Pacific Fuels, Inc. 1444...

  7. High Fuel Economy Heavy-Duty Truck Engine | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuel Economy Heavy-Duty Truck Engine High Fuel Economy Heavy-Duty Truck Engine 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation ace060_tai_2011_o.pdf (434.09 KB) More Documents & Publications Volvo SuperTruck - Powertrain Technologies for Efficiency Improvement Vehicle Technologies Office Merit Review 2016: Volvo SuperTruck - Powertrain Technologies for Efficiency Improvement SuperTruck Program: Engine Project Review

  8. High-burnup core design using minor actinide-containing metal fuel

    SciTech Connect (OSTI)

    Ohta, Hirokazu; Ogata, Takanari; Obara, T.

    2013-07-01

    A neutronic design study of metal fuel fast reactor (FR) cores is conducted on the basis of an innovative fuel design concept to achieve an extremely high burnup and realize an efficient fuel cycle system. Since it is expected that the burnup reactivity swing will become extremely large in an unprecedented high burnup core, minor actinides (MAs) from light water reactors (LWRs) are added to fresh fuel to improve the core internal conversion. Core neutronic analysis revealed that high burnups of about 200 MWd/kg for a small-scale core and about 300 MWd/kg for a large-scale core can be attained while suppressing the burnup reactivity swing to almost the same level as that of conventional cores with normal burnup. An actinide burnup analysis has shown that the MA consumption ratio is improved to about 60% and that the accumulated MAs originating from LWRs can be efficiently consumed by the high-burnup metal fuel FR. (authors)

  9. High Temperature Fuel Cells in the European Union | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cells in the European Union High Temperature Fuel Cells in the European Union Presentation on High Temperature Fuel Cells in the European Union to the High Temperature Membrane Working Group, May 25, 2004 in Philadelphia, PA. euhvh_philadelphia.pdf (1.38 MB) More Documents & Publications CARISMA: A Networking Project for High Temperature PEMFC MEA Activities in Europe Evaluating Exhaust Emission Performance of Urban Buses Using Transient Heavy-Duty Chassis Dynamometer Membrane Development

  10. High temperature fuel/emitter system for advanced thermionic fuel elements

    SciTech Connect (OSTI)

    Moeller, Helen H.; Bremser, Albert H.; Gontar, Alexander; Fiviesky, Evgeny

    1997-01-10

    Specialists in space applications are currently focusing on bimodal power systems designed to provide both electric power and thermal propulsion (Kennedy, 1994 and Houts, 1995). Our work showed that thermionics is a viable technology for nuclear bimodal power systems. We demonstrated that materials for a thermionic fuel-emitter combination capable of performing at operating temperatures of 2473 K are not only possible but available. The objective of this work, funded by the US Department of Energy, Office of Space and Defense Power Systems, was to evaluate the compatibility of fuel material consisting of an uranium carbide/tantalum carbide solid solution with an emitter material consisting of a monocrystalline tungsten-niobium alloy. The uranium loading of the fuel material was 70 mole% uranium carbide. The program was successfully accomplished by a B and W/SIA LUTCH team. Its workscope was integrated with tasks being performed at both Babcock and Wilcox, Lynchburg Research Center, Lynchburg, Virginia, and SIA LUTCH, Podolsk, Russia. Samples were fabricated by LUTCH and seven thermal tests were performed in a hydrogen atmosphere. The first preliminary test was performed at 2273 K by LUTCH, and the remaining six tests were performed At B and W. Three tests were performed at 2273 K, two at 2373 K, and the final test at 2473 K. The results showed that the fuel and emitter materials were compatible in the presence of hydrogen. No evidence of liquid formation, dissolution of the uranium carbide from the uranium carbide/tantalum carbide solid solution, or diffusion of the uranium into the monocrystalline tungsten alloy was observed. Among the highlights of the program was the successful export of the fuel samples from Russia and their import into the US by commercial transport. This paper will discuss the technical aspects of this work.

  11. Used Fuel Disposition Campaign Phase I Ring Compression Testing of High Burnup Cladding

    Office of Energy Efficiency and Renewable Energy (EERE)

    The purpose of ring compression testing is to generate data to support the development of the technical basis for extended storage and transportation of high-burnup fuel. This report highlights the results of completed Phase I testing of high-burnup M5® cladding and the revised three-year test plan. The goal of the ring compression testing is to identify process conditions that would minimize radial-hydride formation and the corresponding DBTT of high-burnup fuel cladding and to generate data and models to support the development of the technical basis for extended storage and transportation of high-burnup fuel.

  12. Graphical and tabular summaries of decay characteristics for once-through PWR, LMFBR, and FFTF fuel cycle materials. [Spent fuel, high-level waste fuel can scrap

    SciTech Connect (OSTI)

    Croff, A.G.; Liberman, M.S.; Morrison, G.W.

    1982-01-01

    Based on the results of ORIGEN2 and a newly developed code called ORMANG, graphical and summary tabular characteristics of spent fuel, high-level waste, and fuel assembly structural material (cladding) waste are presented for a generic pressurized-water reactor (PWR), a liquid-metal fast breeder reactor (LMFBR), and the Fast Flux Test Facility (FFTF). The characteristics include radioactivity, thermal power, and toxicity (water dilution volume). Given are graphs and summary tables containing characteristic totals and the principal nuclide contributors as well as graphs comparing the three reactors for a single material and the three materials for a single reactor.

  13. Turbulent Flame Propagation Characteristics of High Hydrogen Content Fuels

    SciTech Connect (OSTI)

    Seitzman, Jerry; Lieuwen, Timothy

    2014-09-30

    This final report describes the results of an effort to better understand turbulent flame propagation, especially at conditions relevant to gas turbines employing fuels with syngas or hydrogen mixtures. Turbulent flame speeds were measured for a variety of hydrogen/carbon monoxide (H2/CO) and hydrogen/methane (H2/CH4) fuel mixtures with air as the oxidizer. The measurements include global consumption speeds (ST,GC) acquired in a turbulent jet flame at pressures of 1-10 atm and local displacement speeds (ST,LD) acquired in a low-swirl burner at atmospheric pressure. The results verify the importance of fuel composition in determining turbulent flame speeds. For example, different fuel-air mixtures having the same unstretched laminar flame speed (SL,0) but different fuel compositions resulted in significantly different ST,GC for the same turbulence levels (u'). This demonstrates the weakness of turbulent flame speed correlations based simply on u'/SL,0. The results were analyzed using a steady-steady leading points concept to explain the sensitivity of turbulent burning rates to fuel (and oxidizer) composition. Leading point theories suggest that the premixed turbulent flame speed is controlled by the flame front characteristics at the flame brush leading edge, or, in other words, by the flamelets that advance farthest into the unburned mixture (the so-called leading points). For negative Markstein length mixtures, this is assumed to be close to the maximum stretched laminar flame speed (SL,max) for the given fuel-oxidizer mixture. For the ST,GC measurements, the data at a given pressure were well-correlated with an SL,max scaling. However the variation with pressure was not captured, which may be due to non-quasi-steady effects that are not included in the current model. For the ST,LD data, the leading points model again faithfully captured the variation of turbulent flame speed over a wide range of fuel-compositions and turbulence intensities. These results provide

  14. Proceedings of the fourth annual conference on fossil energy materials

    SciTech Connect (OSTI)

    Judkins, R.R.; Braski, D.N.

    1990-08-01

    The Fourth Annual Conference on Fossil Energy Materials was held in Oak Ridge, Tennessee, on may 15--17, 1990. The meeting was sponsored by the US Department of Energy's Office of Fossil Energy through the Advanced Research and Technology Development (AR TD) Materials Program, and ASM International. The objective of the AR TD Materials Program is to conduct research and development on materials for longer-term fossil energy applications as well as for generic needs of various fossil fuel technologies. The work is divided into the following categories: (1) Ceramics, (2) New Alloys, (3) Corrosion and Erosion, and (4) Technology Assessment and Technology Transfer. Individual projects are processed separately for the data bases.

  15. Deep Burn Develpment of Transuranic Fuel for High-Temperature Helium-Cooled Reactors - July 2010

    SciTech Connect (OSTI)

    Snead, Lance Lewis; Besmann, Theodore M; Collins, Emory D; Bell, Gary L

    2010-08-01

    The DB Program Quarterly Progress Report for April - June 2010, ORNL/TM/2010/140, was distributed to program participants on August 4. This report discusses the following: (1) TRU (transuranic elements) HTR (high temperature helium-cooled reactor) Fuel Modeling - (a) Thermochemical Modeling, (b) 5.3 Radiation Damage and Properties; (2) TRU HTR Fuel Qualification - (a) TRU Kernel Development, (b) Coating Development, (c) ZrC Properties and Handbook; and (3) HTR Fuel Recycle - (a) Recycle Processes, (b) Graphite Recycle, (c) Pyrochemical Reprocessing - METROX (metal recovery from oxide fuel) Process Development.

  16. Direct fired reciprocating engine and bottoming high temperature fuel cell hybrid

    DOE Patents [OSTI]

    Geisbrecht, Rodney A.; Holcombe, Norman T.

    2006-02-07

    A system of a fuel cell bottoming an internal combustion engine. The engine exhaust gas may be combined in varying degrees with air and fed as input to a fuel cell. Reformer and oxidizers may be combined with heat exchangers to accommodate rich and lean burn conditions in the engine in peaking and base load conditions without producing high concentrations of harmful emissions.

  17. OFFICE OF FOSSIL ENERGY (FE) PROGRAMS ARE FOCUSED ON ACTIVITIES RELATED TO THE RELIABLE, EFFICIENT, AFFORDABLE

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    gov OFFICE OF FOSSIL ENERGY (FE) PROGRAMS ARE FOCUSED ON ACTIVITIES RELATED TO THE RELIABLE, EFFICIENT, AFFORDABLE AND ENVIRONMENTALLY SOUND USE OF FOSSIL FUELS, AND ENHANC- ING U.S. ECONOMIC, ENVIRONMENTAL AND ENERGY SECURITY. FE MANAGES DOE'S FOSSIL ENERGY RESEARCH AND DEVELOPMENT (FER&D) PROGRAM, WHICH INCLUDES THE CLEAN COAL POWER INITIATIVE (CCPI); CARBON CAPTURE AND STORAGE (CCS) AND POWER SYSTEMS PROGRAM; ADVANCED ENERGY SYSTEMS; THE CROSSCUTTING RESEARCH ACTIVITY; AND NATURAL GAS

  18. Design and Development of High-Performance Polymer Fuel Cell Membranes |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Design and Development of High-Performance Polymer Fuel Cell Membranes Design and Development of High-Performance Polymer Fuel Cell Membranes A presentation to the High Temperature Membranes Working Group meeting, May 19, 2006. hung.pdf (532.06 KB) More Documents & Publications Advanced Materials for Proton Exchange Membranes Energy Storage Systems 2012 Peer Review Presentations - Poster Session 2 (Day 2): SBIR Projects Higher Temperature PEM Composite Systems for

  19. Fossil Energy Program semiannual progress report for April 1991 through September 1991

    SciTech Connect (OSTI)

    Judkins, R.R.

    1992-10-01

    This report covers progress made during the period April 1, 1991, through September 30, 1991, for research and development projects that contribute to the advancement of various fossil energy technologies. Projects on the Fossil Energy Program are supported by the DOE Office of Fossil Energy, the DOE Morgantown Energy Technology Center, the DOE Pittsburgh Energy Technology Center, the DOE Fossil Energy Clean Coal Technology Program, the DOE Fossil Energy Office of Petroleum Reserves, and the US Agency for International Development (USAID). The Fossil Energy Program organization chart is shown in the appendix. Project discussed are: materials research and development; environmental analysis support; coal conversion development; coal combustion research; fossil fuel supplies modeling and research; evaluations and assessments; and coal structure and chemistry.

  20. Shock waves generated by high-pressure fuel sprays directly imaged by x-radiography.

    SciTech Connect (OSTI)

    Wang, J.; MacPhee, A.; Powell, C. F.; Yue, Y.; Narayanan, S.; Tate, M. W.; Renzi, M. J.; Ercan, A.; Fontes, E.; Gruner, S. M.; Walther, J.; Schaller, J.

    2001-12-20

    Synchrotron x-radiography and a novel fast x-ray detector are used to visualize the detailed, time-resolved structure of the fluid jets generated by a high pressure diesel-fuel injection. An understanding of the structure of the high-pressure spray is important in optimizing the injection process to increase fuel efficiency and reduce pollutants. It is shown that x-radiography can provide a quantitative measure of the mass distribution of the fuel. Such analysis has been impossible with optical imaging due to the multiple-scattering of visible light by small atomized fuel droplets surrounding the jet. In addition, direct visualization of the jet-induced shock wave proves that the fuel jets become supersonic under appropriate injection conditions. The radiographic images also allow quantitative analysis of the thermodynamic properties of the shock wave.

  1. Fueling Requirements for Steady State high butane current fraction discharges

    SciTech Connect (OSTI)

    R.Raman

    2003-10-08

    The CT injector originally used for injecting CTs into 1T toroidal field discharges in the TdeV tokamak was shipped PPPL from the Affiliated Customs Brokers storage facility in Montreal during November 2002. All components were transported safely, without damage, and are currently in storage at PPPL, waiting for further funding in order to begin advanced fueling experiments on NSTX. The components are currently insured through the University of Washington. Several technical presentations were made to investigate the feasibility of the CT injector installation on NSTX. These technical presentations, attached to this document, were: (1) Motivation for Compact Toroida Injection in NSTX; (2) Assessment of the Engineering Feasibility of Installing CTF-II on NSTX; (3) Assessment of the Cost for CT Installation on NSTX--A Peer Review; and (4) CT Fueling for NSTX FY 04-08 steady-state operation needs.

  2. Method to fabricate high performance tubular solid oxide fuel cells

    DOE Patents [OSTI]

    Chen, Fanglin; Yang, Chenghao; Jin, Chao

    2013-06-18

    In accordance with the present disclosure, a method for fabricating a solid oxide fuel cell is described. The method includes forming an asymmetric porous ceramic tube by using a phase inversion process. The method further includes forming an asymmetric porous ceramic layer on a surface of the asymmetric porous ceramic tube by using a phase inversion process. The tube is co-sintered to form a structure having a first porous layer, a second porous layer, and a dense layer positioned therebetween.

  3. Advanced Triso fuels with zirconium carbide for high temperature reactors

    SciTech Connect (OSTI)

    Lobach, Sergiy Y.; Knight, Travis W.; Jacob, Norman P.; Athon, Clifton E.

    2007-07-01

    There are several options for the advanced TRISO fuel: one is primarily replacement SiC with ZrC and the other is a concept involving a thin ZrC layer coating on the kernel, which is then enclosed in usual TRISO coatings. An effort at modeling, fabrication and testing of an advanced TRISO coated UO{sub 2} fuel particle design incorporating an added layer of ZrC over the fuel kernel is under investigation. The objectives of the coated particle development program are to define the essentials of a production route for the manufacture of kernels and coated particles and to identify the important process parameters that determine the particle properties. Still, the integrity of the ZrC coating is important, but not the main goal. The primary purpose of a ZrC coating examination in this study is to determine hot it serves as an oxygen getter to limit CO production and hence pressure buildup that would stress coatings leading to failure. This additional ZrC coating also aids in retaining fission products within the kernel, and carbon diffusion in the particle is limited hence kernel migration rates are slowed. The combined result being that failure rates of coated particles should decrease. (authors)

  4. High-Burnup BWR Fuel Behavior Under Simulated Reactivity-Initiated Accident Conditions

    SciTech Connect (OSTI)

    Nakamura, Takehiko; Kusagaya, Kazuyuki; Fuketa, Toyoshi; Uetsuka, Hiroshi

    2002-06-15

    Boiling water reactor (BWR) fuel at 56 to 61 GWd/tonne U was pulse irradiated in the Nuclear Safety Research Reactor (NSRR) to investigate fuel behavior under cold startup reactivity-initiated accident conditions. Current Japanese 8 x 8 type Step II BWR fuel from Fukushima Daini Unit 2 was refabricated to short segments, and thermal energy from 272 to 586 J/g (65 to 140 cal/g) was promptly inserted to the test rods. Cladding deformation of the BWR fuel by the pulse irradiation was smaller than that of pressurized water reactor (PWR) fuels. However, cladding failure occurred in tests with fuel at burnup of 61 GWd/tonne U at fuel enthalpies of 260 to 360 J/g (62 to 86 cal/g) during the early stages of transients, while the cladding remained cool. The failure was comparable to the one observed in high-burnup PWR fuel tests, in which embrittled cladding with dense hydride precipitation near the outer surface was fractured due to pellet cladding mechanical interaction. Transient fission gas release by the pulse irradiation was {approx}9.6 to 17% depending on the peak fuel enthalpy.

  5. NETL - Fuel Reforming Facilities

    SciTech Connect (OSTI)

    2013-06-12

    Research using NETL's Fuel Reforming Facilities explores catalytic issues inherent in fossil-energy related applications, including catalyst synthesis and characterization, reaction kinetics, catalyst activity and selectivity, catalyst deactivation, and stability.

  6. NETL - Fuel Reforming Facilities

    ScienceCinema (OSTI)

    None

    2014-06-27

    Research using NETL's Fuel Reforming Facilities explores catalytic issues inherent in fossil-energy related applications, including catalyst synthesis and characterization, reaction kinetics, catalyst activity and selectivity, catalyst deactivation, and stability.

  7. High Temperature Fuel Cell Tri-Generation of Power, Heat & H2...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tri-Generation of Power, Heat & H2 from Biogas High Temperature Fuel Cell Tri-Generation of Power, Heat & H2 from Biogas Success story about using waste water treatment gas for ...

  8. Converting biomass to fuels and high-value chemicals | The Ames...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Converting biomass to fuels and high-value chemicals The goal of this research is to develop low cost catalysts based on graphene-derived nanomaterials, and use them to improve the...

  9. Strategy for the Management and Disposal of Used Nuclear Fuel and High-Level Radioactive Waste

    Office of Energy Efficiency and Renewable Energy (EERE)

    The Strategy for the Management and Disposal of Used Nuclear Fuel and High-Level Radioactive Waste is a framework for moving toward a sustainable program to deploy an integrated system capable of...

  10. Strategy for the Management and Disposal of Used Nuclear Fuel and High-Level Radioactive Waste

    Office of Energy Efficiency and Renewable Energy (EERE)

    Issued on January 11, 2013, the Strategy for the Management and Disposal of Used Nuclear Fuel and High-Level Radioactive Waste is a framework for moving toward a sustainable program to deploy an...

  11. Composition of high fission product wastes resulting from future reprocessing of commercial nuclear fuels

    SciTech Connect (OSTI)

    Swanson, J.L

    1986-07-01

    Pacific Northwest Laboratory studies, aimed at defining appropriate glass compositions for future disposal of high-level wastes, have developed composition ranges for the waste that will likely result during reprocessing of Light Water Reactor (LWR) and Liquid Metal Reactor (LMR) fuels. The purpose of these studies was to provide baseline waste characterizations for possible future commercial high-level waste so that waste immobilization technologies (e.g., vitrification) can be studied. Ranges in waste composition are emphasized because the waste will vary with time as different fuels are reprocesses, because choice of process chemicals is nuclear, and because fuel burnups will vary. Consequently, composition ranges are based on trends in fuel reprocessing procedures and on achievable burnups in operating reactors. In addition to the fission product and actinide elements, which are the primary hazardous materials in the waste, likely composition ranges are given for inert elements that may be present in the waste. These other elements may be present because of being present in the fuel, because of being added as process chemical during reprocessing, because of being added during equipment decontamination, or because of corrosion of plant equipment and/or fuel element cladding. This report includes a discussion of the chemicals added in variation of the PUREX process, which is likely to remain the favored reprocessing technique for commercial nuclear fuels. Consideration is also given to a pyrochemical process proposed for the reprocessing of some LMR fuels.

  12. Nuclear fuel cycle system simulation tool based on high-fidelity component modeling

    SciTech Connect (OSTI)

    Ames, David E.

    2014-02-01

    The DOE is currently directing extensive research into developing fuel cycle technologies that will enable the safe, secure, economic, and sustainable expansion of nuclear energy. The task is formidable considering the numerous fuel cycle options, the large dynamic systems that each represent, and the necessity to accurately predict their behavior. The path to successfully develop and implement an advanced fuel cycle is highly dependent on the modeling capabilities and simulation tools available for performing useful relevant analysis to assist stakeholders in decision making. Therefore a high-fidelity fuel cycle simulation tool that performs system analysis, including uncertainty quantification and optimization was developed. The resulting simulator also includes the capability to calculate environmental impact measures for individual components and the system. An integrated system method and analysis approach that provides consistent and comprehensive evaluations of advanced fuel cycles was developed. A general approach was utilized allowing for the system to be modified in order to provide analysis for other systems with similar attributes. By utilizing this approach, the framework for simulating many different fuel cycle options is provided. Two example fuel cycle configurations were developed to take advantage of used fuel recycling and transmutation capabilities in waste management scenarios leading to minimized waste inventories.

  13. Secret Mission to Remove Highly Enriched Uranium Spent Nuclear Fuel from

    National Nuclear Security Administration (NNSA)

    Uzbekistan Successfully Completed | National Nuclear Security Administration | (NNSA) Secret Mission to Remove Highly Enriched Uranium Spent Nuclear Fuel from Uzbekistan Successfully Completed April 20, 2006 Four Shipments Have Been Sent to a Secure Facility in Russia WASHINGTON, D.C. -- The Department of Energy's National Nuclear Security Administration (NNSA) announced today that 63 kilograms (139 pounds) of highly enriched uranium (HEU) in spent nuclear fuel were safely and securely

  14. Alternative Fuels Data Center

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Fossil Fuel Use Reduction The state will reduce aggregate fossil fuel use across all owned facilities as compared to a 2005 baseline by 30% by 2020, 40% by 2025, and 540% by 2030. A State Government Energy Committee (SGEC) will advise the State Energy Manager and the State Fleet Manager about energy management within state buildings, operations, and fleets. The state passenger vehicle fleet must also reach the 30% reduction target compared to the 2010 metric ton baseline by 2030. The State

  15. DOE - Fossil Energy: A Brief History of Coal Use in the United...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    History Fossil Energy Study Guides A Brief History of Coal Use Steam Locomotive - In the 1800s, one of the primary uses of coal was to fuel steam engines used to power locomotives. ...

  16. HIGH EFFICIENCY, LOW EMISSIONS, SOLID OXIDE FUEL CELL SYSTEMS FOR MULTIPLE APPLICATIONS

    SciTech Connect (OSTI)

    Sara Ward; Michael A. Petrik

    2004-07-28

    Technology Management Inc. (TMI), teamed with the Ohio Office of Energy Efficiency and Renewable Energy, has engineered, constructed, and demonstrated a stationary, low power, multi-module solid oxide fuel cell (SOFC) prototype system operating on propane and natural gas. Under Phase I, TMI successfully operated two systems in parallel, in conjunction with a single DC-AC inverter and battery bus, and produced net AC electricity. Phase II testing expanded to include alternative and renewable fuels typically available in rural regions of Ohio. The commercial system is expected to have ultra-low pollution, high efficiency, and low noise. The TMI SOFC uses a solid ceramic electrolyte operating at high temperature (800-1000 C) which electrochemically converts gaseous fuels (hydrogen or mixed gases) and oxygen into electricity. The TMI system design oxidizes fuel primarily via electrochemical reactions and uses no burners (which pollute and consume fuel)--resulting in extremely clean exhaust. The use of proprietary sulfur tolerant materials developed by TMI allows system operation without additional fuel pre-processing or sulfur removal. Further, the combination of high operating temperatures and solid state operation increases the potential for higher reliability and efficiencies compared to other types of fuel cells. Applications for the TMI SOFC system cover a wide range of transportation, building, industrial, and military market sectors. A generic technology, fuel cells have the potential to be embodied into multiple products specific to Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy (EERE) program areas including: Fuel Cells and Microturbines, School Buildings, Transportation, and Bioenergy. This program focused on low power stationary applications using a multi-module system operating on a range of common fuels. By producing clean electricity more efficiently (thus using less fuel), fuel cells have the triple effect of cleaning up the

  17. High temperature solid electrolyte fuel cell with ceramic electrodes

    DOE Patents [OSTI]

    Marchant, David D.; Bates, J. Lambert

    1984-01-01

    A solid oxide electrolyte fuel cell is described having a central electrolyte comprised of a HfO.sub.2 or ZrO.sub.2 ceramic stabilized and rendered ionically conductive by the addition of Ca, Mg, Y, La, Nd, Sm, Gd, Dy Er, or Yb. The electrolyte is sandwiched between porous electrodes of a HfO.sub.2 or ZrO.sub.2 ceramic stabilized by the addition of a rare earth and rendered electronically conductive by the addition of In.sub.2 O.sub.3. Alternatively, the anode electrode may be made of a metal such as Co, Ni, Ir Pt, or Pd.

  18. High temperature solid electrolyte fuel cell with ceramic electrodes

    DOE Patents [OSTI]

    Bates, J.L.; Marchant, D.D.

    A solid oxide electrolyte fuel cell is described having a central electrolyte comprised of a HfO/sub 2/ or ZrO/sub 2/ ceramic stabilized and rendered ionically conductive by the addition of Ca, Mg, Y, La, Nd, Sm, Gd, Dy Er, or Yb. The electrolyte is sandwiched between porous electrodes of a HfO/sub 2/ or ZrO/sub 2/ ceramic stabilized by the addition of a rare earth and rendered electronically conductive by the addition of In/sub 2/O/sub 3/. Alternatively, the anode electrode may be made of a metal such as Co, Ni, Ir Pt, or Pd.

  19. Novel Materials for High Efficiency Direct Methanol Fuel Cells

    SciTech Connect (OSTI)

    Carson, Stephen; Mountz, David; He, Wensheng; Zhang, Tao

    2013-12-31

    Direct methanol fuel cell membranes were developed using blends of different polyelectrolytes with PVDF. The membranes showed complex relationships between polyelectrolyte chemistry, morphology, and processing. Although the PVDF grade was found to have little effect on the membrane permselectivity, it does impact membrane conductivity and methanol permeation values. Other factors, such as varying the polyelectrolyte polarity, using varying crosslinking agents, and adjusting the equivalent weight of the membranes impacted methanol permeation, permselectivity, and areal resistance. We now understand, within the scope of the project work completed, how these inter-related performance properties can be tailored to achieve a balance of performance.

  20. High temperature gas-cooled reactor (HTGR) graphite pebble fuel: Review of technologies for reprocessing

    SciTech Connect (OSTI)

    Mcwilliams, A. J.

    2015-09-08

    This report reviews literature on reprocessing high temperature gas-cooled reactor graphite fuel components. A basic review of the various fuel components used in the pebble bed type reactors is provided along with a survey of synthesis methods for the fabrication of the fuel components. Several disposal options are considered for the graphite pebble fuel elements including the storage of intact pebbles, volume reduction by separating the graphite from fuel kernels, and complete processing of the pebbles for waste storage. Existing methods for graphite removal are presented and generally consist of mechanical separation techniques such as crushing and grinding chemical techniques through the use of acid digestion and oxidation. Potential methods for reprocessing the graphite pebbles include improvements to existing methods and novel technologies that have not previously been investigated for nuclear graphite waste applications. The best overall method will be dependent on the desired final waste form and needs to factor in the technical efficiency, political concerns, cost, and implementation.

  1. FRAPCON-3: Modifications to fuel rod material properties and performance models for high-burnup application

    SciTech Connect (OSTI)

    Lanning, D.D.; Beyer, C.E.; Painter, C.L.

    1997-12-01

    This volume describes the fuel rod material and performance models that were updated for the FRAPCON-3 steady-state fuel rod performance code. The property and performance models were changed to account for behavior at extended burnup levels up to 65 Gwd/MTU. The property and performance models updated were the fission gas release, fuel thermal conductivity, fuel swelling, fuel relocation, radial power distribution, solid-solid contact gap conductance, cladding corrosion and hydriding, cladding mechanical properties, and cladding axial growth. Each updated property and model was compared to well characterized data up to high burnup levels. The installation of these properties and models in the FRAPCON-3 code along with input instructions are provided in Volume 2 of this report and Volume 3 provides a code assessment based on comparison to integral performance data. The updated FRAPCON-3 code is intended to replace the earlier codes FRAPCON-2 and GAPCON-THERMAL-2. 94 refs., 61 figs., 9 tabs.

  2. Establishing a Cost Basis for Converting the High Flux Isotope Reactor from High Enriched to Low Enriched Uranium Fuel

    SciTech Connect (OSTI)

    Primm, Trent; Guida, Tracey

    2010-02-01

    Under the auspices of the Global Threat Reduction Initiative Reduced Enrichment for Research and Test Reactors Program, the National Nuclear Security Administration /Department of Energy (NNSA/DOE) has, as a goal, to convert research reactors worldwide from weapons grade to non-weapons grade uranium. The High Flux Isotope Reactor (HFIR) at Oak Ridge National Lab (ORNL) is one of the candidates for conversion of fuel from high enriched uranium (HEU) to low enriched uranium (LEU). A well documented business model, including tasks, costs, and schedules was developed to plan the conversion of HFIR. Using Microsoft Project, a detailed outline of the conversion program was established and consists of LEU fuel design activities, a fresh fuel shipping cask, improvements to the HFIR reactor building, and spent fuel operations. Current-value costs total $76 million dollars, include over 100 subtasks, and will take over 10 years to complete. The model and schedule follows the path of the fuel from receipt from fuel fabricator to delivery to spent fuel storage and illustrates the duration, start, and completion dates of each subtask to be completed. Assumptions that form the basis of the cost estimate have significant impact on cost and schedule.

  3. Superheater Corrosion Produced By Biomass Fuels

    SciTech Connect (OSTI)

    Sharp, William; Singbeil, Douglas; Keiser, James R

    2012-01-01

    About 90% of the world's bioenergy is produced by burning renewable biomass fuels. Low-cost biomass fuels such as agricultural wastes typically contain more alkali metals and chlorine than conventional fuels. Although the efficiency of a boiler's steam cycle can be increased by raising its maximum steam temperature, alkali metals and chlorine released in biofuel boilers cause accelerated corrosion and fouling at high superheater steam temperatures. Most alloys that resist high temperature corrosion protect themselves with a surface layer of Cr{sub 2}O{sub 3}. However, this Cr{sub 2}O{sub 3} can be fluxed away by reactions that form alkali chromates or volatilized as chromic acid. This paper reviews recent research on superheater corrosion mechanisms and superheater alloy performance in biomass boilers firing black liquor, biomass fuels, blends of biomass with fossil fuels and municipal waste.

  4. Hawaii energy strategy project 2: Fossil energy review. Task 2: Fossil energy in Hawaii

    SciTech Connect (OSTI)

    Breazeale, K.; Yamaguchi, N.D.; Keeville, H.

    1993-12-01

    In Task 2, the authors establish a baseline for evaluating energy use in Hawaii, and examine key energy and economic indicators. They provide a detailed look at fossil energy imports by type, current and possible sources of oil, gas and coal, quality considerations, and processing/transformation. They present time series data on petroleum product consumption by end-use sector, though they caution the reader that the data is imperfect. They discuss fuel substitutability to identify those end-use categories that are most easily switched to other fuels. They then define and analyze sequential scenarios of fuel substitution in Hawaii and their impacts on patterns of demand. They also discuss energy security--what it means to Hawaii, what it means to neighboring economies, whether it is possible to achieve energy security. 95 figs., 48 tabs.

  5. California: Agricultural Residues Produce Renewable Fuel | Department...

    Broader source: Energy.gov (indexed) [DOE]

    technology is expected to produce biofuel that reduces greenhouse gas emissions by 80% compared to fossil fuel and help make California a leader in advanced biofuel production. ...

  6. Alternatives to traditional transportation fuels 1993

    SciTech Connect (OSTI)

    Not Available

    1995-01-01

    In recent years, gasoline and diesel fuel have accounted for about 80 percent of total transportation fuel and nearly all of the fuel used in on-road vehicles. Growing concerns about the environmental effects of fossil fuel use and the Nation`s high level of dependence on foreign oil are providing impetus for the development of replacements or alternatives for these traditional transportation fuels. (The Energy Policy Act of 1992 definitions of {open_quotes}replacement{close_quotes} and {open_quotes}alternative{close_quotes} fuels are presented in the following box.) The Alternative Motor Fuels Act of 1988, the Clean Air Act Amendments of 1990 (CAAA90) and the Energy Policy Act of 1992 (EPACT) are significant legislative forces behind the growth of replacement fuel use. Alternatives to Traditional Transportation Fuels 1993 provides the number of on-road alternative fueled vehicles in use in the United States, alternative and replacement fuel consumption, and information on greenhouse gas emissions resulting from the production, delivery, and use of replacement fuels for 1992, 1993, and 1995.

  7. Base-Load and Peak Electricity from a Combined Nuclear Heat and Fossil Combined-Cycle Plant

    SciTech Connect (OSTI)

    Conklin, James C.; Forsberg, Charles W.

    2007-07-01

    A combined-cycle power plant is proposed that uses heat from a high-temperature reactor and fossil fuel to meet base-load and peak electrical demands. The high temperature gas turbine produces shaft power to turn an electric generator. The hot exhaust is then fed to a heat recovery steam generator (HRSG) that provides steam to a steam turbine for added electrical power production. A simplified computational model of the thermal power conversion system was developed in order to parametrically investigate two different steady-state operation conditions: base load nuclear heat only from an Advanced High Temperature Reactor (AHTR), and combined nuclear heat with fossil heat to increase the turbine inlet temperature. These two cases bracket the expected range of power levels, where any intermediate power level can result during electrical load following. The computed results indicate that combined nuclear-fossil systems have the potential to offer both low-cost base-load electricity and lower-cost peak power relative to the existing combination of base-load nuclear plants and separate fossil-fired peak-electricity production units. In addition, electric grid stability, reduced greenhouse gases, and operational flexibility can also result with using the conventional technology presented here for the thermal power conversion system coupled with the AHTR. (authors)

  8. Base-Load and Peak Electricity from a Combined Nuclear Heat and Fossil Combined-Cycle Plant

    SciTech Connect (OSTI)

    Conklin, Jim; Forsberg, Charles W

    2007-01-01

    A combined-cycle power plant is proposed that uses heat from a high-temperature reactor and fossil fuel to meet base-load and peak electrical demands. The high-temperature gas turbine produces shaft power to turn an electric generator. The hot exhaust is then fed to a heat recovery steam generator (HRSG) that provides steam to a steam turbine for added electrical power production. A simplified computational model of the thermal power conversion system was developed in order to parametrically investigate two different steady-state operation conditions: base load nuclear heat only from an Advanced High Temperature Reactor (AHTR), and combined nuclear heat with fossil heat to increase the turbine inlet temperature. These two cases bracket the expected range of power levels, where any intermediate power level can result during electrical load following. The computed results indicate that combined nuclear-fossil systems have the potential to offer both low-cost base-load electricity and lower-cost peak power relative to the existing combination of base-load nuclear plants and separate fossil-fired peak-electricity production units. In addition, electric grid stability, reduced greenhouse gases, and operational flexibility can also result with using the conventional technology presented here for the thermal power conversion system coupled with the AHTR.

  9. FOSSIL2 energy policy model documentation: FOSSIL2 documentation

    SciTech Connect (OSTI)

    1980-10-01

    This report discusses the structure, derivations, assumptions, and mathematical formulation of the FOSSIL2 model. Each major facet of the model - supply/demand interactions, industry financing, and production - has been designed to parallel closely the actual cause/effect relationships determining the behavior of the United States energy system. The data base for the FOSSIL2 program is large, as is appropriate for a system dynamics simulation model. When possible, all data were obtained from sources well known to experts in the energy field. Cost and resource estimates are based on DOE data whenever possible. This report presents the FOSSIL2 model at several levels. Volumes II and III of this report list the equations that comprise the FOSSIL2 model, along with variable definitions and a cross-reference list of the model variables. Volume III lists the model equations and a one line definition for equations, in a short, readable format.

  10. Development of Modified Pag (Polyalkylene Glycol) High VI High Fuel Efficient Lubricant for LDV Applications

    SciTech Connect (OSTI)

    Gangopadhyay, Arup; McWatt, D. G.; Zdrodowski, R. J.; Liu, Zak; Elie, Larry; Simko, S. J.; Erdemir, Ali; Ramirez, Giovanni; Cuthbert, J.; Hock, E. D.

    2015-09-30

    Engine oils play a critical role in friction reduction. Improvements in engine oil technology steadily improved fuel economy as the industry moved through ILSAC GF-1 to GF-5 specifications. These improvements were influenced by changes in base oil chemistry, development of new friction modifiers and their treat levels, and the total additive package consisting of various other components. However, the improvements are incremental and further fuel consumption reduction opportunities are becoming more challenging. Polyalkylene glycol (PAG) based engine oils are being explored as a step forward for significant fuel consumption reduction. Although PAG fluids are used in many industrial applications, its application as an engine oil has been explored in a limited way. The objective of this project is to deep dive in exploring the applicability of PAG technology in engine oil, understanding the benefits, and limitations, elucidating the mechanism(s) for friction benefits, if any, and finally recommending how to address any limitations. The project was designed in four steps, starting with selection of lubricant technology, followed by friction and wear evaluations in laboratory bench tests which are relatively simple and inexpensive and also served as a screener for further evaluation. Selected formulations were chosen for more complex engine component level tests i.e., motored valvetrain friction and wear, piston ring friction using a motored single cylinder, and motored engine tests. A couple of formulations were further selected based on component level tests for engine dyno tests i.e., Sequence VID (ASTM D6709) for fuel economy, Sequence IVA (ASTM D6891) for valvetrain wear, and Sequence VG (ASTM D6593) for sludge and varnish protection. These are some of the industry standard tests required for qualifying engine oils. Out of these tests, a single PAG oil was selected for chassis roll dynamometer tests for fuel economy and emission measurements using FTP (Federal

  11. PIA - Fossil Energy Web System (FEWEB) | Department of Energy

    Energy Savers [EERE]

    Fossil Energy Web System (FEWEB) PIA - Fossil Energy Web System (FEWEB) PIA - Fossil Energy Web System (FEWEB) PDF icon PIA - Fossil Energy Web System (FEWEB) More Documents &...

  12. Office of Fossil Energy's Technical Assistance | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fossil Energy's Technical Assistance Office of Fossil Energy's Technical Assistance Office of Fossil Energys Technical Assistance Office of Fossil Energy's Technical ...

  13. The Advanced High-Temperature Reactor (AHTR) for Producing Hydrogen to Manufacture Liquid Fuels

    SciTech Connect (OSTI)

    Forsberg, C.W.; Peterson, P.F.; Ott, L.

    2004-10-06

    Conventional world oil production is expected to peak within a decade. Shortfalls in production of liquid fuels (gasoline, diesel, and jet fuel) from conventional oil sources are expected to be offset by increased production of fuels from heavy oils and tar sands that are primarily located in the Western Hemisphere (Canada, Venezuela, the United States, and Mexico). Simultaneously, there is a renewed interest in liquid fuels from biomass, such as alcohol; but, biomass production requires fertilizer. Massive quantities of hydrogen (H2) are required (1) to convert heavy oils and tar sands to liquid fuels and (2) to produce fertilizer for production of biomass that can be converted to liquid fuels. If these liquid fuels are to be used while simultaneously minimizing greenhouse emissions, nonfossil methods for the production of H2 are required. Nuclear energy can be used to produce H2. The most efficient methods to produce H2 from nuclear energy involve thermochemical cycles in which high-temperature heat (700 to 850 C) and water are converted to H2 and oxygen. The peak nuclear reactor fuel and coolant temperatures must be significantly higher than the chemical process temperatures to transport heat from the reactor core to an intermediate heat transfer loop and from the intermediate heat transfer loop to the chemical plant. The reactor temperatures required for H2 production are at the limits of practical engineering materials. A new high-temperature reactor concept is being developed for H2 and electricity production: the Advanced High-Temperature Reactor (AHTR). The fuel is a graphite-matrix, coated-particle fuel, the same type that is used in modular high-temperature gas-cooled reactors (MHTGRs). The coolant is a clean molten fluoride salt with a boiling point near 1400 C. The use of a liquid coolant, rather than helium, reduces peak reactor fuel and coolant temperatures 100 to 200 C relative to those of a MHTGR. Liquids are better heat transfer fluids than gases

  14. Publications of the Oak Ridge National Laboratory Fossil Energy Program, October 1, 1991--March 31, 1993

    SciTech Connect (OSTI)

    Carlson, P.T.

    1993-06-01

    The Oak Ridge National Laboratory (ORNL) Fossil Energy Program, organized in FY 1974 as the Coal Technology Program, involves research and development activities for the Department of Energy (DOE) Assistant Secretary for Fossil Energy that cover a wide range of fossil energy technologies. The principal focus of the Laboratory`s fossil energy activities relates to coal, with current emphasis on materials research and development; environmental, health, and safety research; and the bioprocessing of coal to produce liquid or gaseous fuels. This bibliography covers the period of October 1, 1991, through March 31, 1993.

  15. President Requests $638.0 Million for Fossil Energy Programs | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy 38.0 Million for Fossil Energy Programs President Requests $638.0 Million for Fossil Energy Programs April 10, 2013 - 4:00pm Addthis Washington, DC - President Obama's FY 2014 budget seeks $638.0 million for the Office of Fossil Energy (FE) to advance technologies related to the reliable, efficient, affordable and environmentally sound use of fossil fuels as well as manage the Strategic Petroleum Reserve and Northeast Home Heating Oil Reserve to provide strategic and economic

  16. Draft Advanced Fossil Solicitation | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Federal loan guarantee solicitation announcement -- Advanced Fossil Energy Projects. Microsoft Word - Draft Advanced Fossil Solicitation Final Draft.1 (383.34 KB) More Documents & ...

  17. Fossil Gulch Wind Park | Open Energy Information

    Open Energy Info (EERE)

    Gulch Wind Park Jump to: navigation, search Name Fossil Gulch Wind Park Facility Fossil Gulch Wind Park Sector Wind energy Facility Type Commercial Scale Wind Facility Status In...

  18. Evaluation of fission gas release in high-burnup light water reactor fuel rods

    SciTech Connect (OSTI)

    Barner, J.O.; Cunningham, M.E.; Freshley, M.D.; Lanning, D.D. )

    1993-05-01

    Research to define the behavior of Zircaloy-clad light water reactor (LWR) UO[sub 2] fuel irradiated to high burnup levels was conducted as part of the High Burnup Effects Program (HBEP). The HBEP was a 12-yr program that ultimately acquired, characterized, irradiated, and examined after irradiation 82 LWR fuel rods ranging in rod-average fuel burnup from 22 to 69 MWd/kgM with a peak pellet burnup of 83 MWd/kg M. A principal emphasis of the HBEP was to evaluate the effect of high burnup on fission gas release. It was confirmed that fission gas release remained as dependent on design and irradiation history parameters at high burnup levels as at low to moderate burnup levels. One observed high-burnup effect was the development of a burnup-dependent microstructure at the fuel pellet surface when pellet-edge burnup exceeded 65 MWd/kgM. This low-temperature rim region' was characterized by a loss of optically definable grain structure, a high volume of porosity, and diffusion of fission gas from the UO[sub 2] matrix to the porosity. Although the rim region has the potential for enhanced fission gas release, it is concluded that no significant enhancement of rod-average fission gas release at high burnup levels was observed for the examined fuel rods.

  19. Coal-fueled high-speed diesel engine development: Task 2, Market assessment and economic analysis

    SciTech Connect (OSTI)

    Kakwani, R. M.; Wilson, Jr., R. P.; Winsor, R. E.

    1991-12-01

    Based on the preliminary coal engine design developed, this task was conducted to identify the best opportunity(s) to enter the market with the future coal-fueled, high-speed diesel engine. The results of this market and economic feasibility assessment will be used to determine what specific heavy duty engine application(s) are most attractive for coal fuel, and also define basic economic targets for the engine to be competitive.

  20. Options for treating high-temperature gas-cooled reactor fuel for repository disposal

    SciTech Connect (OSTI)

    Lotts, A.L.; Bond, W.D.; Forsberg, C.W.; Glass, R.W.; Harrington, F.E.; Micheals, G.E.; Notz, K.J.; Wymer, R.G.

    1992-02-01

    This report describes the options that can reasonably be considered for disposal of high-temperature gas-cooled reactor (HTGR) fuel in a repository. The options include whole-block disposal, disposal with removal of graphite (either mechanically or by burning), and reprocessing of spent fuel to separate the fuel and fission products. The report summarizes what is known about the options without extensively projecting or analyzing actual performance of waste forms in a repository. The report also summarizes the processes involved in convert spent HTGR fuel into the various waste forms and projects relative schedules and costs for deployment of the various options. Fort St. Vrain Reactor fuel, which utilizes highly-enriched {sup 235}U (plus thorium) and is contained in a prismatic graphite block geometry, was used as the baseline for evaluation, but the major conclusions would not be significantly different for low- or medium-enriched {sup 235}U (without thorium) or for the German pebble-bed fuel. Future US HTGRs will be based on the Fort St. Vrain (FSV) fuel form. The whole block appears to be a satisfactory waste form for disposal in a repository and may perform better than light-water reactor (LWR) spent fuel. From the standpoint of process cost and schedule (not considering repository cost or value of fuel that might be recycled), the options are ranked as follows in order of increased cost and longer schedule to perform the option: (1) whole block, (2a) physical separation, (2b) chemical separation, and (3) complete chemical processing.

  1. Fossil Energy Program annual progress report for April 1994 through March 1995

    SciTech Connect (OSTI)

    1995-06-01

    This report covers progress made during the period April 1, 1994, through March 31, 1995, for research and development projects that contribute to the advancement of various fossil energy technologies. Projects on the Fossil Energy Program are supported by the DOE Office of Fossil Energy, and DOE Morgantown Energy Technology Center, the DOE Pittsburgh Energy Technology Center, the DOE Fossil Energy Clean Coal Technology Program, the DOE Bartlesville Project Office, and the DOE Fossil Energy Office of Strategic Petroleum Reserve. The following research areas are covered in this report: Materials research and development; Environmental analysis support; Bioprocessing research; Coal combustion research; and Fossil fuels supplies modeling and research. Selected papers have been processed separately for inclusion in the Energy Science an Technology database.

  2. Analysis of Experimental Data for High Burnup PWR Spent Fuel Isotopic Validation - Vandellos II Reactor

    SciTech Connect (OSTI)

    Ilas, Germina; Gauld, Ian C

    2011-01-01

    This report is one of the several recent NUREG/CR reports documenting benchmark-quality radiochemical assay data and the use of the data to validate computer code predictions of isotopic composition for spent nuclear fuel, to establish the uncertainty and bias associated with code predictions. The experimental data analyzed in the current report were acquired from a high-burnup fuel program coordinated by Spanish organizations. The measurements included extensive actinide and fission product data of importance to spent fuel safety applications, including burnup credit, decay heat, and radiation source terms. Six unique spent fuel samples from three uranium oxide fuel rods were analyzed. The fuel rods had a 4.5 wt % {sup 235}U initial enrichment and were irradiated in the Vandellos II pressurized water reactor operated in Spain. The burnups of the fuel samples range from 42 to 78 GWd/MTU. The measurements were used to validate the two-dimensional depletion sequence TRITON in the SCALE computer code system.

  3. HIGH-TEMPERATURE TUBULAR SOLID OXIDE FUEL CELL GENERATOR DEVELOPMENT

    SciTech Connect (OSTI)

    S.E. Veyo

    1998-09-01

    During the Westinghouse/USDOE Cooperative Agreement period of November 1, 1990 through November 30, 1997, the Westinghouse solid oxide fuel cell has evolved from a 16 mm diameter, 50 cm length cell with a peak power of 1.27 watts/cm to the 22 mm diameter, 150 cm length dimensions of today's commercial prototype cell with a peak power of 1.40 watts/cm. Accompanying the increase in size and power density was the elimination of an expensive EVD step in the manufacturing process. Demonstrated performance of Westinghouse's tubular SOFC includes a lifetime cell test which ran for a period in excess of 69,000 hours, and a fully integrated 25 kWe-class system field test which operated for over 13,000 hours at 90% availability with less than 2% performance degradation over the entire period. Concluding the agreement period, a 100 kW SOFC system successfully passed its factory acceptance test in October 1997 and was delivered in November to its demonstration site in Westervoort, The Netherlands.

  4. Novel Materials for High Efficiency Direct Methanol Fuel Cells

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Number: Arkema Inc. (1281) This presentation does not contain any proprietary, confidential, or otherwise restricted information Novel Materials for High Efficiency Direct Methanol ...

  5. AIR SHIPMENT OF HIGHLY ENRICHED URANIUM SPENT NUCLEAR FUEL FROM ROMANIA AND LIBYA

    SciTech Connect (OSTI)

    Christopher Landers; Igor Bolshinsky; Ken Allen; Stanley Moses

    2010-07-01

    In June 2009 Romania successfully completed the world’s first air shipment of highly enriched uranium (HEU) spent nuclear fuel transported in Type B(U) casks under existing international laws and without special exceptions for the air transport licenses. Special 20-foot ISO shipping containers and cask tiedown supports were designed to transport Russian TUK 19 shipping casks for the Romanian air shipment and the equipment was certified for all modes of transport, including road, rail, water, and air. In December 2009 Libya successfully used this same equipment for a second air shipment of HEU spent nuclear fuel. Both spent fuel shipments were transported by truck from the originating nuclear facilities to nearby commercial airports, were flown by commercial cargo aircraft to a commercial airport in Yekaterinburg, Russia, and then transported by truck to their final destinations at the Production Association Mayak facility in Chelyabinsk, Russia. Both air shipments were performed under the Russian Research Reactor Fuel Return Program (RRRFR) as part of the U.S. National Nuclear Security Administration (NNSA) Global Threat Reduction Initiative (GTRI). The Romania air shipment of 23.7 kg of HEU spent fuel from the VVR S research reactor was the last of three HEU fresh and spent fuel shipments under RRRFR that resulted in Romania becoming the 3rd RRRFR participating country to remove all HEU. Libya had previously completed two RRRFR shipments of HEU fresh fuel so the 5.2 kg of HEU spent fuel air shipped from the IRT 1 research reactor in December made Libya the 4th RRRFR participating country to remove all HEU. This paper describes the equipment, preparations, and license approvals required to safely and securely complete these two air shipments of spent nuclear fuel.

  6. Fuel-Cycle and Nuclear Material Disposition Issues Associated with High-Temperature Gas Reactors

    SciTech Connect (OSTI)

    Shropshire, D.E.; Herring, J.S.

    2004-10-03

    The objective of this paper is to facilitate a better understanding of the fuel-cycle and nuclear material disposition issues associated with high-temperature gas reactors (HTGRs). This paper reviews the nuclear fuel cycles supporting early and present day gas reactors, and identifies challenges for the advanced fuel cycles and waste management systems supporting the next generation of HTGRs, including the Very High Temperature Reactor, which is under development in the Generation IV Program. The earliest gas-cooled reactors were the carbon dioxide (CO2)-cooled reactors. Historical experience is available from over 1,000 reactor-years of operation from 52 electricity-generating, CO2-cooled reactor plants that were placed in operation worldwide. Following the CO2 reactor development, seven HTGR plants were built and operated. The HTGR came about from the combination of helium coolant and graphite moderator. Helium was used instead of air or CO2 as the coolant. The helium gas has a significant technical base due to the experience gained in the United States from the 40-MWe Peach Bottom and 330-MWe Fort St. Vrain reactors designed by General Atomics. Germany also built and operated the 15-MWe Arbeitsgemeinschaft Versuchsreaktor (AVR) and the 300-MWe Thorium High-Temperature Reactor (THTR) power plants. The AVR, THTR, Peach Bottom and Fort St. Vrain all used fuel containing thorium in various forms (i.e., carbides, oxides, thorium particles) and mixtures with highly enriched uranium. The operational experience gained from these early gas reactors can be applied to the next generation of nuclear power systems. HTGR systems are being developed in South Africa, China, Japan, the United States, and Russia. Elements of the HTGR system evaluated included fuel demands on uranium ore mining and milling, conversion, enrichment services, and fuel fabrication; fuel management in-core; spent fuel characteristics affecting fuel recycling and refabrication, fuel handling, interim

  7. Vortex combustor for low NOX emissions when burning lean premixed high hydrogen content fuel

    DOE Patents [OSTI]

    Steele, Robert C; Edmonds, Ryan G; Williams, Joseph T; Baldwin, Stephen P

    2012-11-20

    A trapped vortex combustor. The trapped vortex combustor is configured for receiving a lean premixed gaseous fuel and oxidant stream, where the fuel includes hydrogen gas. The trapped vortex combustor is configured to receive the lean premixed fuel and oxidant stream at a velocity which significantly exceeds combustion flame speed in a selected lean premixed fuel and oxidant mixture. The combustor is configured to operate at relatively high bulk fluid velocities while maintaining stable combustion, and low NOx emissions. The combustor is useful in gas turbines in a process of burning synfuels, as it offers the opportunity to avoid use of diluent gas to reduce combustion temperatures. The combustor also offers the possibility of avoiding the use of selected catalytic reaction units for removal of oxides of nitrogen from combustion gases exiting a gas turbine.

  8. Vortex combustor for low NOx emissions when burning lean premixed high hydrogen content fuel

    DOE Patents [OSTI]

    Steele, Robert C.; Edmonds, Ryan G.; Williams, Joseph T.; Baldwin, Stephen P.

    2009-10-20

    A trapped vortex combustor. The trapped vortex combustor is configured for receiving a lean premixed gaseous fuel and oxidant stream, where the fuel includes hydrogen gas. The trapped vortex combustor is configured to receive the lean premixed fuel and oxidant stream at a velocity which significantly exceeds combustion flame speed in a selected lean premixed fuel and oxidant mixture. The combustor is configured to operate at relatively high bulk fluid velocities while maintaining stable combustion, and low NOx emissions. The combustor is useful in gas turbines in a process of burning synfuels, as it offers the opportunity to avoid use of diluent gas to reduce combustion temperatures. The combustor also offers the possibility of avoiding the use of selected catalytic reaction units for removal of oxides of nitrogen from combustion gases exiting a gas turbine.

  9. Core-Protected Platinum Monolayer Shell High-Stability Electrocatalysts for Fuel-Cell Cathodes

    SciTech Connect (OSTI)

    Adzic, R.R.; Sasaki, K.; Naohara, H.; Cai, Y.; Choi, Y.M.; Liu, P.; Vukmirovic, M.B.; Wang, J.X.

    2010-11-08

    More than skin deep: Platinum monolayers can act as shells for palladium nanoparticles to lead to electrocatalysts with high activities and an ultralow platinum content, but high platinum utilization. The stability derives from the core protecting the shell from dissolution. In fuel-cell tests, no loss of platinum was observed in 200?000 potential cycles, whereas loss of palladium was significant.

  10. Core-Protected Platinum Monolayer Shell High-Stability Electrocatalysts for Fuel-Cell Cathodes

    SciTech Connect (OSTI)

    K Sasaki; H Naohara; Y Cai; Y Choi; P Liu; M Vukmirovic; J Wang; R Adzic

    2011-12-31

    Platinum monolayers can act as shells for palladium nanoparticles to lead to electrocatalysts with high activities and an ultralow platinum content, but high platinum utilization. The stability derives from the core protecting the shell from dissolution. In fuel-cell tests, no loss of platinum was observed in 200,000 potential cycles, whereas loss of palladium was significant.

  11. Fossil plant decommissioning: Tracking deferred costs in a competitive market

    SciTech Connect (OSTI)

    Ferguson, J.S.

    1995-06-15

    Widespread concern over nuclear plant decommissioning has triggered similar interest in the decommissioning of fossil-fired steam generating stations. This rising interest stems in part from the emergence of a competitive market in electric generation, which, among other things, threatens impairment of assets. Fossil decommissioning issues are not nearly as contentious as those that attend nuclear plants. Nevertheless, the magnitude of cost estimates for fossil decommissioning, when expressed as a percentage of station investment, is high enough to demand attention from accountants and regulators.

  12. High conversion Th-U{sup 233} fuel assembly for current generation of PWRs

    SciTech Connect (OSTI)

    Baldova, D.; Fridman, E.

    2012-07-01

    This paper presents a preliminary design of a high conversion Th-U{sup 233} fuel assembly applicable for current generation of Pressurized Water Reactor (PWRs). The considered fuel assembly has a typical 17 x 17 PWR lattice. However in order to increase the conversion of Th{sup 232} to U{sup 233}, the assembly was subdivided into the two regions called seed and blanket. The central seed region has a higher than blanket U{sup 233} content and acts as a neutron source for the peripheral blanket region. The latest acts as a U{sup 233} breeder. While the seed fuel pins have a standard dimensions the blanket fuel radius was increased in order to reduce the moderation and to facilitate the resonance neutron absorption in blanket Th{sup 232}. The U{sup 233} content in the seed and blanket regions was optimized to achieve maximal initial to discharged fissile inventory ratio (FIR) taking into account the target fuel cycle length of 12 months with 3-batch reloading scheme. In this study the neutronic calculations were performed on the fuel assembly level using Helios deterministic lattice transport code. The fuel cycle length and the core k{sub eff} were estimated by applying the Non Linear Reactivity Model. The applicability of the HELIOS code for the analysis of the Th-based high conversion designs was confirmed with the help of continuous-energy Monte-Carlo code SERPENT. The results of optimization studies show that for the heterogeneous seed and blanket (SB) fuel assembly the FIR of about 0.95 can be achieved. (authors)

  13. Safety analysis of high pressure gasous fuel container punctures

    SciTech Connect (OSTI)

    Swain, M.R.

    1995-09-01

    The following report is divided into two sections. The first section describes the results of ignitability tests of high pressure hydrogen and natural gas leaks. The volume of ignitable gases formed by leaking hydrogen or natural gas were measured. Leaking high pressure hydrogen produced a cone of ignitable gases with 28{degrees} included angle. Leaking high pressure methane produced a cone of ignitable gases with 20{degrees} included angle. Ignition of hydrogen produced larger overpressures than did natural gas. The largest overpressures produced by hydrogen were the same as overpressures produced by inflating a 11 inch child`s balloon until it burst.

  14. TRISO-Coated Fuel Processing to Support High Temperature Gas-Cooled Reactors

    SciTech Connect (OSTI)

    Del Cul, G.D.

    2002-10-01

    The initial objective of the work described herein was to identify potential methods and technologies needed to disassemble and dissolve graphite-encapsulated, ceramic-coated gas-cooled-reactor spent fuels so that the oxide fuel components can be separated by means of chemical processing. The purpose of this processing is to recover (1) unburned fuel for recycle, (2) long-lived actinides and fission products for transmutation, and (3) other fission products for disposal in acceptable waste forms. Follow-on objectives were to identify and select the most promising candidate flow sheets for experimental evaluation and demonstration and to address the needs to reduce technical risks of the selected technologies. High-temperature gas-cooled reactors (HTGRs) may be deployed in the next -20 years to (1) enable the use of highly efficient gas turbines for producing electricity and (2) provide high-temperature process heat for use in chemical processes, such as the production of hydrogen for use as clean-burning transportation fuel. Also, HTGR fuels are capable of significantly higher burn-up than light-water-reactor (LWR) fuels or fast-reactor (FR) fuels; thus, the HTGR fuels can be used efficiently for transmutation of fissile materials and long-lived actinides and fission products, thereby reducing the inventory of such hazardous and proliferation-prone materials. The ''deep-burn'' concept, described in this report, is an example of this capability. Processing of spent graphite-encapsulated, ceramic-coated fuels presents challenges different from those of processing spent LWR fuels. LWR fuels are processed commercially in Europe and Japan; however, similar infrastructure is not available for processing of the HTGR fuels. Laboratory studies on the processing of HTGR fuels were performed in the United States in the 1960s and 1970s, but no engineering-scale processes were demonstrated. Currently, new regulations concerning emissions will impact the technologies used in

  15. Alternative Fuels Data Center: Missouri High School Students...

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Missouri High School Students Get Hands-On Training With Biodiesel See how students in Fenton, Missouri, are learning to convert waste vegetable oil into biodiesel and put it into ...

  16. Thermal Behavior of Advanced UO{sub 2} Fuel at High Burnup

    SciTech Connect (OSTI)

    Muller, E.; Lambert, T.; Silberstein, K.; Therache, B.

    2007-07-01

    To improve the fuel performance, advanced UO{sub 2} products are developed to reduce significantly Pellet-Cladding Interaction and Fission Gas Release to increase high burnup safety margins on Light Water Reactors. To achieve the expected improvements, doping elements are currently used, to produce large grain viscoplastic UO{sub 2} fuel microstructures. In that scope, AREVA NP is conducting the qualification of a new UO{sub 2} fuel pellet obtained by optimum chromium oxide doping. To assess the fuel thermal performance, especially the fuel conductivity degradation with increasing burnup and also the kinetics of fission gas release under transient operating conditions, an instrumented in-pile experiment, called REMORA, has been developed by the CEA. One segment base irradiated for five cycles in a French EDF commercial PWR ({approx} 62 GWd/tM) was consequently re-instrumented with a fuel centerline thermocouple and an advanced pressure sensor. The design of this specific sensor is based on the counter-pressure principle and avoids any drift phenomenon due to nuclear irradiation. This rodlet was then irradiated in the GRIFFONOS rig of the Osiris experimental reactor at CEA Saclay. This device, located in the periphery of the core, is designed to perform test under conditions close to those prevailing in French PWR reactor. Power variations are carried out by translating the device relatively to the core. Self - powered neutron detectors are positioned in the loop in order to monitor the power the whole time of the irradiation. The re-irradiation of the REMORA experiment consisted of a stepped ramp to power in order to point out a potential degradation of the fuel thermal conductivity with increasing burnup. During the first part of the irradiation, most of the measurements were performed at low power in order to take into account the irradiation effects on UO{sub 2} thermal conductivity at high burnup in low range of temperature. The second part of the irradiation

  17. Fuel-Flexible Microturbine and Gasifier System

    SciTech Connect (OSTI)

    2009-12-01

    This factsheet describes a project that will develop and demonstrate a prototype microturbine combined heat and power system fueled by synthesis gas and integrated with a biomass gasifier, enabling reduced fossil fuel consumption and carbon dioxide emissions.

  18. High Pressure Fuel Storage Cylinders Periodic Inspection and End of Life Issues

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    6/2010 www.cleanvehicle.org 1 High Pressure Fuel Storage Cylinders Periodic Inspection and End of Life Issues DOE Vehicular Tank Workshop April 29, 2010 Douglas Horne, PE The Facts  High pressure Type 4 gaseous fuel tanks are now designed under standards that specify finite lifetimes of 15, 20 and 25 years based on specific design and testing (the HGV2 standard under development had a life as short as 10 years as an option)  It is unique within the transportation industry to have a

  19. Experimental and Modeling Study of the Flammability of Fuel Tank Headspace Vapors from High Ethanol Content Fuels

    SciTech Connect (OSTI)

    Gardiner, D.; Bardon, M.; Pucher, G.

    2008-10-01

    Study determined the flammability of fuel tank headspace vapors as a function of ambient temperature for seven E85 fuel blends, two types of gasoline, and denatured ethanol at a low tank fill level.

  20. Comparison of selected foreign plans and practices for spent fuel and high-level waste management

    SciTech Connect (OSTI)

    Schneider, K.J.; Mitchell, S.J.; Lakey, L.T.; Johnson, A.B. Jr.; Hazelton, R.F.; Bradley, D.J.

    1990-04-01

    This report describes the major parameters for management of spent nuclear fuel and high-level radioactive wastes in selected foreign countries as of December 1989 and compares them with those in the United States. The foreign countries included in this study are Belgium, Canada, France, the Federal Republic of Germany, Japan, Sweden, Switzerland, and the United Kingdom. All the countries are planning for disposal of spent fuel and/or high-level wastes in deep geologic repositories. Most countries (except Canada and Sweden) plan to reprocess their spent fuel and vitrify the resultant high-level liquid wastes; in comparison, the US plans direct disposal of spent fuel. The US is planning to use a container for spent fuel as the primary engineered barrier. The US has the most developed repository concept and has one of the earliest scheduled repository startup dates. The repository environment presently being considered in the US is unique, being located in tuff above the water table. The US also has the most prescriptive regulations and performance requirements for the repository system and its components. 135 refs., 8 tabs.