Sample records for hfc hydrofluorocarbon hhs

  1. Atmospheric histories and global emissions of the anthropogenic hydrofluorocarbons HFC-365mfc, HFC-245fa, HFC-227ea, and HFC-236fa

    E-Print Network [OSTI]

    Rigby, Matthew

    We report on ground-based atmospheric measurements and emission estimates of the four anthropogenic hydrofluorocarbons (HFCs) HFC-365mfc (CH[subscript 3]CF[subscript 2]CH[subscript 2]CF[subscript 3], 1,1,1,3,3-pentafluorobutane), ...

  2. Adsorption of Hydrofluorocarbons HFC-134 and HFC-134A on X and Y Zeolites: Effect of Ion-Exchange on Selectivity and Heat of Adsorption

    E-Print Network [OSTI]

    Siperstein, Flor R.

    rapidly as worldwide refrigerator and air-conditioner production rises almost exponentially.1 A byproduct) is a hydrofluorocarbon coolant for refrigerators designated to replace the ozone-damaging chloro- fluorocarbons (CFCs

  3. Recent increases in global HFC-23 emissions

    E-Print Network [OSTI]


    of U.S. greenhouse gas emissions and sinks: 1990-2007, Rep.A. Lindley (2007), Global emissions of HFC-23 estimated to2009), Greenhouse Gas Emissions Data,

  4. Polyol esters as HFC-134a compressor lubricants

    SciTech Connect (OSTI)

    Komatsuzaki, S.; Homma, Y.; Itoh, Y. [Hitachi Ltd. (Japan)] [and others


    A polyol ester-based lubricant has been applied to HFC-134a household refrigerator compressors, because of its good miscibility with HFC-134a refrigerant, and there is a possibility that it will be applied to automobile air conditions. For better performance, further improvements are needed regarding miscibility, lubricity and chemical stability of the lubricant, because such systems are often used under extreme conditions. This report discusses the required properties and ways to improve performance of polyol esters as HFC-134a compressor lubricants. 7 refs., 14 figs., 4 tabs.

  5. Elevated temperature ablation resistance of HfC particle-reinforced tungsten composites

    E-Print Network [OSTI]

    Hong, Soon Hyung

    and spark plasma sintering (SPS) process. HfC was chos Keywords: Composite materials Powder metallurgy Sintering Ablation properties Microstructure The effects

  6. Creating an Account in the Mentor Matching System To view information about the NIH-HHS Mentoring Program, visit

    E-Print Network [OSTI]

    Bezrukov, Sergey M.

    Creating an Account in the Mentor Matching System To view information about the NIH-HHS Mentoring Program, visit: The NIH gateway hosts guidance and information for utilizing the HHS Mentoring Program. 1. Go to the HHS Mentoring Program website at: https://mentoring

  7. HHS Advisory Committee on Blood Safety and Availability On June 10-11, 2010, the HHS Advisory Committee on Blood Safety and Availability

    E-Print Network [OSTI]

    Khan, Javed I.

    HHS Advisory Committee on Blood Safety and Availability On June 10-11, 2010, the HHS Advisory Committee on Blood Safety and Availability (ACBSA) met to discuss the current Food and Drug Administration had sex with other men at any time since 1977 are currently deferred as blood donors. The ACBSA

  8. Global emissions of refrigerants HCFC-22 and HFC-134a: Unforeseen seasonal contributions

    E-Print Network [OSTI]

    Xiang, Bin

    HCFC-22 (CHClF[subscript 2]) and HFC-134a (CH[subscript 2]FCF[subscript 3]) are two major gases currently used worldwide in domestic and commercial refrigeration and air conditioning. HCFC-22 contributes to stratospheric ...

  9. HFC-23 (CHF3) emission trend response to HCFC-22 (CHClF2) production and recent HFC-23 emission abatement measures

    E-Print Network [OSTI]

    Miller, B. R.

    HFC-23 (also known as CHF3 [CHF subscript 3], fluoroform or trifluoromethane) is a potent greenhouse gas (GHG), with a global warming potential (GWP) of 14 800 for a 100-year time horizon. It is an unavoidable by-product ...

  10. An Experimental Investigaton of the Effect of Oil on Convective Heat Trasfer and Pressure Drop of a HFC-32/HRC-125 Mixture

    E-Print Network [OSTI]

    McJimsey, Bert Ashford

    The heat transfer coefficients and pressure drops of HCFC-22 and a 50% mass mixture of HFC-32/HFC-125 were experimentally measured under flow boiling conditions in a smooth tube. The refrigerants were flowed through an 8 mm diameter smooth tube...

  11. Energy and global warming impacts of HFC refrigerants and emerging technologies: TEWI-III

    SciTech Connect (OSTI)

    Sand, J.R.; Fischer, S.K.; Baxter, V.D.


    The use of hydrofluorocarbons (BFCs) which were developed as alternative refrigerants and insulating foam blowing agents to replace chlorofluorocarbons (CFCs) is now being affected by scientific investigations of greenhouse warming and questions about the effects of refrigerants and blowing agents on global warming. A Total Equivalent Warming Impact (TEWI) assessment analyzes the environmental affects of these halogenated working fluids in energy consuming applications by combining a direct effect resulting from the inadvertent release of HFCs to the atmosphere with an indirect effect resulting from the combustion of fossil fuels needed to provide the energy to operate equipment using these compounds as working fluids. TEWI is a more balanced measure of environmental impact because it is not based solely on the global warming potential (GWP) of the working fluid. It also shows the environmental benefit of efficient technologies that result in less CO{sub 2} generation and eventual emission to the earth`s atmosphere. The goal of TEWI is to assess total global warming impact of all the gases released to the atmosphere, including CO{sub 2} emissions from energy conversion. Alternative chemicals and technologies have been proposed as substitutes for HFCs in the vapor-compression cycle for refrigeration and air conditioning and for polymer foams in appliance and building insulations which claim substantial environmental benefits. Among these alternatives are: (1) Hydrocarbon (HC) refrigerants and blowing agents which have zero ozone depleting potential and a negligible global warming potential, (2) CO{sub 2} as a refrigerant and blowing agent, (3) Ammonia (NH{sub 3}) vapor compression systems, (4) Absorption chiller and heat pumping cycles using ammonia/water or lithium bromide/water, and (5) Evacuated panel insulations. This paper summarizes major results and conclusions of the detailed final report on the TEWI-111 study.

  12. Safeguarding Health Information: Building Assurance through HIPAA Security Hosted by the HHS Office for Civil Rights (OCR) and the National Institute of Standards and Technology (NIST)

    E-Print Network [OSTI]

    1 Safeguarding Health Information: Building Assurance through HIPAA Security Hosted by the HHS, Acting Chief, Computer Security Division, Information Technology Laboratory (ITL), NIST 9 Data Using Encryption Matthew Scholl, Computer Security Division, Information Technology Laboratory

  13. A S p e A k e r ' S G u i d e The Heart Truth, its logo and The red dress are registered trademarks of HHS.

    E-Print Network [OSTI]

    Bandettini, Peter A.

    A S p e A k e r ' S G u i d e ģ The Heart Truth, its logo and The red dress are registered ģ The Heart Truth, its logo and The red dress are registered trademarks of HHS. A S p e A k e r ' S G u i d e

  14. 1982 HHS/LIHEAP funds used for weatherization. An analysis of data from twenty states: Task A. Final report

    SciTech Connect (OSTI)

    Not Available


    During the Summer and Fall of 1982, Arawak Consulting Corporation monitored a number of program management functions of the Low Income Weatherization Assistance Program (WAP) in the 20 states under the jurisdiction of the DOE Chicago Operations Office. The monitoring included on-site visits to all 20 state grantees and 85 randomly selected local subgrantees. Although the monitoring was designed to focus only on the DOE funded program, it soon became apparent that funds from the Department of Health and Human Services' Low Income Home Energy Assistance Program (LIHEAP) often had a significant effect on the scope and mode of operation of the weatherization program. As a result of these and other outcomes, DOE asked Arawak to further study the impact of HHS funds on the Weatherization Assistance Program in the same 20 states. This report is the result of that request. It draws on information collected during the monitoring visits which were conducted from mid-July to mid-October 1982, and on additional information obtained in telephone interviews during the last two weeks of February 1983.

  15. Final Technical Report HFC Concrete: A Low-√?¬?√?¬?√?¬?√?¬≠√?¬?√?¬Ę√?¬?√?¬?√?¬?√?¬źEnergy, Carbon-√?¬?√?¬?√?¬?√?¬≠Dioxide-√?¬?√?¬?√?¬?√?¬≠Negative Solution for reducing Industrial Greenhouse Gas Emissions

    SciTech Connect (OSTI)

    Dr. Larry McCandlish, Principal Investigator; Dr. Richard Riman, Co-Principal Investigator


    Solidia/CCSM received funding for further research and development of its Low Temperature Solidification Process (LTS), which is used to create hydrate-free concrete (HFC). LTS/HFC is a technology/materials platform that offers wide applicability in the built infrastructure. Most importantly, it provides a means of making concrete without Portland cement. Cement and concrete production is a major consumer of energy and source of industrial greenhouse gas (GHG) emissions. The primary goal of this project was to develop and commercialize a novel material, HFC, which by replacing traditional concrete and cement, reduces both energy use and GHG emissions in the built infrastructure. Traditional concrete uses Portland Cement (PC) as a binder. PC production involves calcination of limestone at {approx}1450 C, which releases significant amounts of CO{sub 2} gas to the atmosphere and consumes a large amount of energy due to the high temperature required. In contrast, HFC is a carbonate-based hydrate-free concrete (HFC) that consumes CO{sub 2} gas in its production. HFC is made by reaction of silicate minerals with CO{sub 2} at temperatures below 100 C, more than an order-of-magnitude below the temperature required to make PC. Because of this significant difference in temperature, it is estimated that we will be able to reduce energy use in the cement and concrete industry by up to 30 trillion Btu by 2020. Because of the insulating properties of HFC, we believe we will also be able to significantly reduce energy use in the Building sector, though the extent of this saving is not yet quantified. It is estimated that production of a tonne of PC-based concrete requires about 6.2 million Btu of energy and produces over 1 tonne of CO{sub 2} emissions (Choate, 2003). These can be reduced to 1.9 million Btu and 0.025 tonnes of CO{sub 2} emissions per tonne of HFC (with overall CO{sub 2}-negativity possible by increasing carbonation yield). In this way, by replacing PC-based concrete with HFC in infrastructure we can reduce energy use in concrete production by 70%, and reduce CO{sub 2} emissions by 98%; thus the potential to reduce the impact of building materials on global warming and climate change is highly significant. Low Temperature Solidification (LTS) is a breakthrough technology that enables the densification of inorganic materials via a hydrothermal process. The resulting product exhibits excellent control of chemistry and microstructure, to provide durability and mechanical performance that exceeds that of concrete or natural stone. The technology can be used in a wide range of applications including facade panels, interior tiles, roof tiles, countertops, and pre-cast concrete. Replacing traditional building materials and concrete in these applications will result in significant reduction in both energy consumption and CO{sub 2} emissions.


    Broader source: (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742Energy ChinaofSchaefer To: CongestionDevelopmentHEADQUARTERS MEDIATION PROGRAM


    Broader source: (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742Energy ChinaofSchaefer To: CongestionDevelopmentHEADQUARTERS MEDIATION PROGRAMForm 4220.2

  18. Reducing the Carbon Footprint of Commercial Refrigeration Systems Using Life Cycle Climate Performance Analysis: From System Design to Refrigerant Options

    SciTech Connect (OSTI)

    Fricke, Brian A [ORNL] [ORNL; Abdelaziz, Omar [ORNL] [ORNL; Vineyard, Edward Allan [ORNL] [ORNL


    In this paper, Life Cycle Climate Performance (LCCP) analysis is used to estimate lifetime direct and indirect carbon dioxide equivalent gas emissions of various refrigerant options and commercial refrigeration system designs, including the multiplex DX system with various hydrofluorocarbon (HFC) refrigerants, the HFC/R744 cascade system incorporating a medium-temperature R744 secondary loop, and the transcritical R744 booster system. The results of the LCCP analysis are presented, including the direct and indirect carbon dioxide equivalent emissions for each refrigeration system and refrigerant option. Based on the results of the LCCP analysis, recommendations are given for the selection of low GWP replacement refrigerants for use in existing commercial refrigeration systems, as well as for the selection of commercial refrigeration system designs with low carbon dioxide equivalent emissions, suitable for new installations.

  19. Novel hydrofluorocarbon polymers for use as pellicles in 157 nm semiconductor photolithography: fundamentals of transparency

    E-Print Network [OSTI]

    Rollins, Andrew M.

    Pont Photomasks Inc., 4 Finance Dr., Danbury, CT 06810, USA c INEOS, Russian Academy of Sciences, Vavilova 28

  20. Applicant Instructions for Completing Form HHS-745, "HHS ID Badge Request" Section A collects identifying information about Applicants needed to issue an HHS ID Badge. In some

    E-Print Network [OSTI]

    Bandettini, Peter A.

    is 5 U.S.C. ß 301; Presidential Memorandum on Upgrading Security at Federal Facili ties, June 28, 1995; and Homeland Security Presidential Directive 12, August 27, 2004. The authority to request your Social Security be disclosed only with your written consent, except where permitted by the Privacy Act. The disclosures

  1. Growth of climate change commitments from HFC banks and emissions

    E-Print Network [OSTI]

    Velders, G. J. M.

    Chlorofluorocarbons (CFCs) are the primary cause of ozone depletion, and they also contribute to global climate change. With the global phaseout of CFCs and the coming phaseout of hydrochlorofluorocarbons (HCFCs), the ...

  2. Passive Two-Phase Cooling of Automotive Power Electronics: Preprint

    SciTech Connect (OSTI)

    Moreno, G.; Jeffers, J. R.; Narumanchi, S.; Bennion, K.


    Experiments were conducted to evaluate the use of a passive two-phase cooling strategy as a means of cooling automotive power electronics. The proposed cooling approach utilizes an indirect cooling configuration to alleviate some reliability concerns and to allow the use of conventional power modules. An inverter-scale proof-of-concept cooling system was fabricated, and tests were conducted using the refrigerants hydrofluoroolefin HFO-1234yf and hydrofluorocarbon HFC-245fa. Results demonstrated that the system can dissipate at least 3.5 kW of heat with 250 cm3 of HFC-245fa. An advanced evaporator design that incorporates features to improve performance and reduce size was conceived. Simulation results indicate its thermal resistance can be 37% to 48% lower than automotive dual side cooled power modules. Tests were also conducted to measure the thermal performance of two air-cooled condensers--plain and rifled finned tube designs. The results combined with some analysis were then used to estimate the required condenser size per operating conditions and maximum allowable system (i.e., vapor and liquid) temperatures.

  3. Two-Phase Flow of Two HFC Refrigerant Mixtures Through Short Tube Orifices, Draft Final Report†

    E-Print Network [OSTI]

    Payne, W. V.; O'Neal, D. L.


    to commercially available short tubes in residential air conditioners or heat pumps. Figure 2.2 shows the schematic of the orifice test section for routine performance tests. The short tube was made from brass which was bored and reamed to insure a smooth...) measurements of the effects of oil concentration on performance. Conditions were chosen to cover a wide range of operating conditions for a short tube expansion device found in a typical residential heat pump or air-conditioner. The experimental variables...

  4. Elastohydrodynamic Lubrication with Polyolester Lubricants and HFC Refrigerants, Final Report, Volume 1

    SciTech Connect (OSTI)

    Gunsel, Selda; Pozebanchuk, Michael


    The objective of this study was to investigate the film formation properties of refrigeration lubricants using the ultrathin film elastohydrodynamic (EHD) interferometry technique and to study the effects of refrigerants on film formation. Film thickness measurements were conducted as a function of lubricant viscosity, speed, temperature, and refrigerant concentration. Based on the EHD film thickness data, effective pressure-viscosity coefficients were calculated for the test fluids at different temperatures and the effects of refrigerants on pressure-viscosity properties were investigated.

  5. Compatibility of lubricant additives with HFC refrigerants and synthetic lubricants. Final report, Part 1

    SciTech Connect (OSTI)

    Cavestri, R.C. [Imagination Resources, Inc., Dublin, OH (United States)


    Part one of this research provides manufacturers of components of air-conditioning and refrigeration equipment with a useful list of lubricant additives, sources, functional properties and chemical species. The list in part one is comprised of domestic lubricant additive suppliers and the results of a literature search that was specifically targeted for additives reported to be useful in polyolester chemistry.

  6. Elastohydrodynamic Lubrication with Polyolester Lubricants and HFC Refrigerants, Final Report, Volume 2

    SciTech Connect (OSTI)

    Gunsel, Selda; Pozebanchuk, Michael


    Lubrication properties of refrigeration lubricants were investigated in high pressure nonconforming contacts under different conditions of temperature, rolling speed, and refrigerant concentration. The program was based upon the recognition that the lubrication regime in refrigeration compressors is generally elastohydrodynamic or hydrodynamic, as determined by the operating conditions of the compressor and the properties of the lubricant. Depending on the compressor design, elastohydrodynamic lubrication conditions exist in many rolling and sliding elements of refrigeration compressors such as roller element bearings, gears, and rotors. The formation of an elastohydrodynamic film separating rubbing surfaces is important in preventing the wear and failure of compressor elements. It is, therefore, important to predict the elastohydrodynamic (EHD) performance of lubricants under realistic tribocontact renditions. This is, however, difficult as the lubricant properties that control film formation are critically dependent upon pressure and shear, and cannot be evaluated using conventional laboratory instruments. In this study, the elastohydrodynamic behavior of refrigeration lubricants with and without the presence of refrigerants was investigated using the ultrathin film EHD interferometry technique. This technique enables very thin films, down to less than 5 nm, to be measured accurately within an EHD contact under realistic conditions of temperature, shear, and pressure. The technique was adapted to the study of lubricant refrigerant mixtures. Film thickness measurements were obtained on refrigeration lubricants as a function of speed, temperature, and refrigerant concentration. The effects of lubricant viscosity, temperature, rolling speed, and refrigerant concentration on EHD film formation were investigated. From the film thickness measurements, effective pressure-viscosity coefficients were calculated. The lubricants studied in this project included two naphthenic mineral oils (NMO), four polyolesters (POE), and two polyvinyl ether (PVE) fluids. These fluids represented viscosity grades of ISO 32 and ISO 68 and are shown in a table. Refrigerants studied included R-22, R-134a, and R-410A. Film thickness measurements were conducted at 23 C, 45 C, and 65 C with refrigerant concentrations ranging from zero to 60% by weight.

  7. Two-Phase Flow of HCFC-22 and HFC-134a through Short Tube Orifices

    E-Print Network [OSTI]

    Yongchan, K.


    % of the experimental data. However, for the high subcooling region, some deviation, as high as Ī11% of the measured values, was observed due to the imperfection of a selected two-phase critical flow model....

  8. Two-Phase Flow of Two HFC Refrigerant Mixtures Through Short Tube Orifices, Draft Final Report

    E-Print Network [OSTI]

    Payne, W. V.; O'Neal, D. L.


    The present study presents data for flow of two refrigerant mixtures through short tube orifices. The two mixtures were R3211251134a (23%/25%/52% on a mass percentage basis) and R321125 (50%/50%). The following presents results for the flow...

  9. Design and simulation of a heat pump for simultaneous heating and cooling using HFC or CO2

    E-Print Network [OSTI]

    Paris-Sud XI, Universitť de

    subcooling vol volumetric w water 1. Context and objectives Nowadays, global warming being a major concern and the large temperature glide at heat rejection used for DHW production. Keywords: design, simulation, heating;2 NOMENCLATURE c relative clearance volume (-) C electricity consumption (Wh) Cp specific heat (J kg-1 K-1 ) h


    E-Print Network [OSTI]

    Sheffield, University of

    of spent nuclear fuel and vitrified high level waste material [1, 2]. In order to assess the suitability repository concept for the disposal of High Level nuclear Waste (HLW) [1, 2]. This scheme uses large diameter are sealed by recrystallisation, annealing or hydration reactions, preventing the access of hydrous fluids

  11. APHIS Plant Pathogens, HHS Select Infectious Agents, and USDA High Consequence Livestock Pathogens or Toxins 1. African horse sickness virus

    E-Print Network [OSTI]

    . Mycoplasma capricolum / M. F38 / M. mycoides capri (contagious caprine pleuropneumonia agent) u 14. Mycoplasma mycoides mycoides (contagious bovine pleuropneumonia agent) u 15. Ralstonia solanacearum race 3

  12. An Evaluation of the Environmental Impact of Different Commercial Supermarket Refrigeration Systems Using Low Global Warming Potential Refrigerants

    SciTech Connect (OSTI)

    Beshr, Mohamed [University of Maryland, College Park; Aute, Vikrant [University of Maryland, College Park; Abdelaziz, Omar [ORNL; Fricke, Brian A [ORNL; Radermacher, Reinhard [University of Maryland, College Park


    Commercial refrigeration systems consumed 1.21 Quads of primary energy in 2010 and are known to be a major source for refrigerant charge leakage into the environment. Thus, it is important to study the environmental impact of commercial supermarket refrigeration systems and improve their design to minimize any adverse impacts. The system s Life Cycle Climate Performance (LCCP) was presented as a comprehensive metric with the aim of calculating the equivalent mass of carbon dioxide released into the atmosphere throughout its lifetime, from construction to operation and destruction. In this paper, an open source tool for the evaluation of the LCCP of different air-conditioning and refrigeration systems is presented and used to compare the environmental impact of a typical multiplex direct expansion (DX) supermarket refrigeration systems based on three different refrigerants as follows: two hydrofluorocarbon (HFC) refrigerants (R-404A, and R-407F), and a low global warming potential (GWP) refrigerant (N-40). The comparison is performed in 8 US cities representing different climates. The hourly energy consumption of the refrigeration system, required for the calculation of the indirect emissions, is calculated using a widely used building energy modeling tool (EnergyPlus). A sensitivity analysis is performed to determine the impact of system charge and power plant emission factor on the LCCP results. Finally, we performed an uncertainty analysis to determine the uncertainty in total emissions for both R-404A and N-40 operated systems. We found that using low GWP refrigerants causes a considerable drop in the impact of uncertainty in the inputs related to direct emissions on the uncertainty of the total emissions of the system.

  13. Global and regional emissions of HFC-125 (CHF[subscript 2]CF[subscript 3]) from in situ and air archive atmospheric observations at AGAGE and SOGE observatories

    E-Print Network [OSTI]

    O'Doherty, S.

    High-frequency, in situ observations from the Advanced Global Atmospheric Gases Experiment (AGAGE) and System for Observation of halogenated Greenhouse gases in Europe (SOGE) networks for the period 1998 to 2008, combined ...

  14. Demonstration of high efficiency elastocaloric cooling with large DT using Jun Cui,1,2

    E-Print Network [OSTI]

    Rubloff, Gary W.

    of modern compressors approaching the theoretical limit, but its environmental footprint remains a global problem. VC refrigerants such as hydrochloroflurocarbons (HCFCs) and hydrofluorocarbons (HFCs

  15. Using Acid Number as a Leading Indicator of Refrigeration and Air Conditioning System Performance

    SciTech Connect (OSTI)

    Dennis Cartlidge; Hans Schellhase


    This report summarizes a literature review to assess the acidity characteristics of the older mineral oil and newer polyolester (POE) refrigeration systems as well as to evaluate acid measuring techniques used in other non-aqueous systems which may be applicable for refrigeration systems. Failure in the older chlorofluorocarbon/hydrochlorofluorocarbon (CFC/HCFC) / mineral oil systems was primarily due to thermal degradation of the refrigerant which resulted in the formation of hydrochloric and hydrofluoric acids. These are strong mineral acids, which can, over time, severely corrode the system metals and lead to the formation of copper plating on iron surfaces. The oil lubricants used in the older systems were relatively stable and were not prone to hydrolytic degradation due to the low solubility of water in oil. The refrigerants in the newer hydrofluorocarbon (HFC)/POE systems are much more thermally stable than the older CFC/HCFC refrigerants and mineral acid formation is negligible. However, acidity is produced in the new systems by hydrolytic decomposition of the POE lubricants with water to produce the parent organic acids and alcohols used to prepare the POE. The individual acids can therefore vary but they are generally C5 to C9 carboxylic acids. Organic acids are much weaker and far less corrosive to metals than the mineral acids from the older systems but they can, over long time periods, react with metals to form carboxylic metal salts. The salts tend to accumulate in narrow areas such as capillary tubes, particularly if residual hydrocarbon processing chemicals are present in the system, which can lead to plugging. The rate of acid production from POEs varies on a number of factors including chemical structure, moisture levels, temperature, acid concentration and metals. The hydrolysis rate of reaction can be reduced by using driers to reduce the free water concentration and by using scavenging chemicals which react with the system acids. Total acid number (TAN), which includes both mineral acids and organic acids, is therefore a useful indicator which can be used to monitor the condition of the system in order to perform remedial maintenance, when required, to prevent system failure. The critical TAN value is the acid level at which remedial action should be taken to prevent the onset of rapid acid formation which can result in system failure. The level of 0.05 mg KOH/g of oil was established for CFC/mineral oil systems based on analysis of 700 used lubricants from operating systems and failed units. There is no consensus within the refrigeration industry as to the critical TAN value for HFC/POE systems, however, the value will be higher than the CFC/mineral oil systems critical TAN value because of the much weaker organic acids produced from POE. A similar study of used POE lubricants should be performed to establish a critical TAN limit for POE systems. Titrimetric analysis per ASTM procedures is the most commonly used method to determine TAN values in lubricants in the refrigeration industry and other industries dealing with lubricating oils. For field measurements, acid test kits are often used since they provide rapid, semi-quantitative TAN results.

  16. Poverty in the Lesbian, Gay, and Bisexual Community

    E-Print Network [OSTI]

    Albelda, Randy; Badgett, M V Lee; Schneebaum, Alyssa; Gates, Gary


    2007b. Prior HHS Poverty Guidelines and Federal RegisterD.C. (and summary. ? In Measuring Poverty: A new approach .

  17. Poverty in the Lesbian, Gay, and Bisexual

    E-Print Network [OSTI]

    Albelda, Randy; Badgett, M.V. Lee; Schneebaum, Alyssa; Gates, Gary


    Iterated by Income-to- Poverty Ratio and Race. Washington,2007a. The 2007 HHS Poverty Guidelines. Washington, D.C.2007b. Prior HHS Poverty Guidelines and Federal Register

  18. Grant Title: ALCOHOL RESEARCH EDUCATION PROJECT GRANTS (R25) Funding Opportunity Number: PAR -11-205. CFDA Number(s) 93.273.

    E-Print Network [OSTI]

    Farritor, Shane

    -205. CFDA Number(s) 93.273. Agency/Department: Department of Health and Human Services (HHS), National

  19. People's Climate Stewardship / Carbon Fee and Dividend Act of 2010: Proposed Findings

    E-Print Network [OSTI]

    Hansen, James E.

    conventional (non-greenhouse-gas) pollutants emitted by fossil fuel burning which cause health, nitrous oxide, sulfur hexafluoride, hydrofluorocarbons (HFCs) emitted as byproducts, perfluorocarbons and DOE shall annually review greenhouse gas emissions data and determine whether an increase larger than

  20. Only CryoguardTM Thermal Exposure

    E-Print Network [OSTI]

    Haskel, Daniel

    potential for environmentally friendly magnetic refrigera- tion systems. Magnetic refrigeration is a clean. Magnetic refrigeration does not rely on hydrofluorocarbons (HFCs) used in conventional refrigeration.. CCoollllaabboorraattiioonn wwiitthh AAmmeess LLaabboorraattoorryy Materials that change temperature in magnetic fields could

  1. International Journal of Thermophysics, Vol. 20, No. 1, 1999 Vapor-Liquid Equilibria of Alternative Refrigerants

    E-Print Network [OSTI]

    Lisal, Martin

    Refrigerants by Molecular Dynamics Simulations1 M. Lisal,2 R. Budinsky,3 V. Vacek,3 and K. Aim2, 4 Alternative refrigerants HFC-152a (CHF2CH3), HFC-143a (CF3CH3), HFC- 134a (CF3CH2F), and HCFC-142b (CF2ClCH3) are modeled Republic. 4 To whom correspondence should be addressed. KEY WORDS: alternative refrigerants; Gibbs

  2. Estimating Policy-Driven Greenhouse Gas Emissions Trajectories in California: The California Greenhouse Gas Inventory Spreadsheet (GHGIS) Model

    E-Print Network [OSTI]

    Greenblatt, Jeffery B.


    decision support tool for landfill gas-to energy projects,Ēcomponent of landfills to 100% HGWP gases a. HFC phase-out:

  3. Stratospheric ozone, global warming, and the principle of unintended consequences - an ongoing science and policy story

    E-Print Network [OSTI]


    Naturally. 2013. The Coca-Cola Company. Prepared by Unitedwould be HFC free. In 2009, Coca-Cola announced that 100% of

  4. Alternative Refrigerants for Building Air Conditioning†

    E-Print Network [OSTI]

    Bivens, D. B.


    , and HFC-245ca. HCFC-22 is also scheduled for phase-out, and three alternatives for HCFC-22 have been identified: HFC-134a, a near-azeotropic mixture of R32/Rl25, and a zeotropic mixture of R32/R125/R134a. Performance test results, future potential energy...

  5. Federal, State, and Local Coordination | Department of Energy

    Energy Savers [EERE]

    Geospatial Intelligence Agency, Health and Human Services (HHS), Department of Agriculture (DOA), Department of State (DOS), Tennessee Valley Authority (TVA), Department of...

  6. Crop and Soil Science Degree Checklist Name: ____________________________

    E-Print Network [OSTI]

    GrŁnwald, Niklaus J.

    and Soil Science Degree Checklist Name: ____________________________ ID Intensive (SOIL 325) (3) _______ HHS 231 ≠ Lifetime Fitness for Health (2. Global Issues (3) (*soil science electives meeting requirement) _______ Science

  7. Search for Acronyms | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    director DHHS U.S. Department of Health and Human Services (also HHS) DHHX district heating heat exchangers DHI data handler and interface DHR Daily Headquarters Report (NRC)...

  8. Kiran Chandra Sapkota Livelihood strategies and vulnerability of urban poor

    E-Print Network [OSTI]

    Richner, Heinz

    management of drinking water. 97.7 percent HHs have got the electricity and entertainment facilities, electric charge, etc. This study has tried to show five capital assets of urban poor in Khadi Pakha in local social institution but not represented in local government. Above 95 percent HHs involved

  9. HIPAA, Research, and the IRB Michelle Brown, BBA

    E-Print Network [OSTI]

    Chisholm, Rex L.

    of health insurance coverage in the group and individual markets, combat waste, fraud, and abuse in health Department of Health & Human Services (HHS) to adopt national standards for: ∑ electronic health care health information in electronic form in connection with a transaction for which HHS has adopted

  10. Page 1 of 4 3/8/2011

    E-Print Network [OSTI]

    Bandettini, Peter A.

    -76] ======================================================================= DEPARTMENT OF HEALTH AND HUMAN SERVICES Office of the Secretary Annual Update of the HHS Poverty Guidelines of the Department of Health and Human Services (HHS) poverty guidelines to account for last calendar year's increase about poverty figures for immigration forms, the Hill-Burton Uncompensated Services Program

  11. OE Releases Second Issue of Energy Emergency Preparedness Quarterly...

    Broader source: (indexed) [DOE]

    with HHS to install and test a system to monitor the status of power at critical government health facilities. All issues of the EEPQ are available for download from the...

  12. abusing runaway adolescents: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oelklaus, Kirsten; Petr, Chris 2001-11-01 8 From the Adolescent Trauma and Substance Abuse Committee of the National Child Traumatic Stress Network CiteSeer Summary: (HHS)....

  13. September 27, 2013 Dear CDC Grantee

    E-Print Network [OSTI]

    Kroll, Kristen L.

    September 27, 2013 Dear CDC Grantee: As you are aware, the Government Fiscal Year (FY) 2013 ends will be operational and will be accepting applications from prospective grantees. HHS will take action on those

  14. Zevenhoven & Kilpinen List of Abbreviations 13.4.2002 Abb.-1 List of abbreviations

    E-Print Network [OSTI]

    Zevenhoven, Ron

    potential HAP Hazardous air pollutant (USA) HC Hydrocarbon HCFC Hydrogenated chlorofluorocarbon HFC carbon AF Air factor ASR Auto shredder residue ASTM American Society for Testing and Materials BaP Benzo and Development ODP Ozone-depleting potential ODS Ozoen-depleting substance OFA Over-fire air PAH Polycyclic

  15. Peter Bernath Department of Chemistry, University of YorkDepartment of Chemistry, University of York

    E-Print Network [OSTI]

    - 12 11,000 CFC - 113 6,540 Carbon Tetrachloride 2,700 HCFC-142b, CCl4, CH3Cl, CF4, SF6, (HFC-134a-142b CFC-12 SF6 HCFC-22 SF6 #12;N. Allen:N. Allen: Global hydrogenhydrogen peroxide, HOxHOx reservoir

  16. Proceedings of the 1993 non-fluorocarbon insulation, refrigeration and air conditioning technology workshop

    SciTech Connect (OSTI)

    Not Available


    Sessions included: HFC blown polyurethanes, carbon dioxide blown foam and extruded polystyrenes, plastic foam insulations, evacuated panel insulation, refrigeration and air conditioning, absorption and adsorption and stirling cycle refrigeration, innovative cooling technologies, and natural refrigerants. Selected papers have been indexed separately for inclusion in the Energy Science and Technology Database.

  17. Alternative Refrigerants for Building Air Conditioning

    E-Print Network [OSTI]

    Bivens, D. B.


    The majority of building air conditioning has traditionally been achieved with vapor compression technology using CFC-I I or HCFC-22 as refrigerant fluids. CFC-11 is being successfully replaced by HCFC-123 (retrofit or new equipment) or by HFC- 134a...

  18. Performance Evaluation of A Household Refrigerator Using Cuo Nanoparticle Lubricant Mixture and Various Other Compressor Oils with Different Condenser Modes

    E-Print Network [OSTI]

    Sreejith. K

    Abstract:- The objective of this paper was to study the performance of household refrigerator having both air and water-cooled condenser, with 0.06 % mass fraction CuO nanoparticle-lubricant mixture and different types of compressor oils. The experiment was done using HFC134a as the refrigerant, CuO nanoparticles, Polyol-ester oil (POE) oil which is used as the conventional lubricant in the household refrigerator and SUNISO 3GS mineral oil as the lubricant alternatively. The result indicates that the refrigerator performance had improved while using CuO nanoparticle-lubricant mixture. The performance was also improved when HFC134a/SUNISO 3GS mineral oil system was used instead of HFC134a/POE oil system and there was also an enhancement when water-cooled condenser was used instead of the conventional air-cooled condenser on all load conditions. The HFC134a/CuO/SUNISO 3GS mineral oil system works normally and safely in the refrigerator. HFC134a/CuO/SUNISO 3GS mineral oil system reduced the energy consumption between 12 % and 19 % when compared with the HFC134a/POE oil system and between 9 % and 14 % while working with water-cooled condenser on various load conditions. There was also an enhancement in coefficient of performance (COP) when CuO nanoparticle-lubricant mixture was used instead of POE oil as the lubricant. The water cooled heat exchanger was designed and the system was modified by retrofitting it, along with the conventional air-cooled condenser by making a bypass line and thus the system can be utilized as a waste heat recovery unit. Experimental result shows that about 200 litres of hot water at a temperature of about 58ļC over a day can be generated. Techno economic analysis shows that the installation cost and running cost of the waste heat recovery system for a day is much lower than that of a conventional

  19. National Youth Sports Program: Math/Science. Final report, [June 1, 1992--November 30, 1992

    SciTech Connect (OSTI)

    Not Available


    NYSP, a partnership of NCAA, HHS, and colleges and universities, is aimed at sports instruction and physical activity for disadvantaged youth. In 1992, DOE joined in to add a mathematics/science component. Federal funds were used to conduct mathematics and science education components on a limited pilot basis at 16 sites. Recommendations for future improvements are given.

  20. Pre-Law Outreach Program UC Irvine School of Law's Pre-Law Outreach Program ("POP") is sponsored by the

    E-Print Network [OSTI]

    Loudon, Catherine

    of these requirements): Family income within 200% of the federal poverty guidelines per the form and hand-write your answers in blue or black ink, OR b. Save the PDF document to your computer. Then fill out the PDF, and print it for submission. If you cannot save the PDF to your computer, you

  1. In The News Tuesday, January 18, 2011

    E-Print Network [OSTI]

    Arizona, University of

    of the Arizona Cancer Center) 01/18/2011 East Valley Tribune View Clip FOR WHAT IS NEXT OUT OF TUCSON, WE Star - Online Text | View Clip State can't fill Giffords 'vacancy' 01/18/2011 Arizona Daily Sun Text CAUGHT BY VIDEO CAMERAS 01/18/2011 Baltimore Sun Text Arizona's University Medical Center Sues HHS Over

  2. WUSM RA Forum November 10, 2005

    E-Print Network [OSTI]

    Kroll, Kristen L.

    before Funding (handout) The Hand that Feeds (handout) Congress Asks HHS IG to Investigate Use of NIH letter to: Grants & Contracts Office Cancer Research Bldg., Room 114 Campus Box 8018 Phone: 747-4134 Fax. ______________________________________________________________________ Template Letter Format: To: Grants & Contracts Office From: Principal Investigator Name Date: Grant number

  3. An investigation of pinch instabilities in solid sodium plasmas

    E-Print Network [OSTI]

    Henson, Robert Maurice


    e ie ene nacho|9 fox ylaxxDa con~ fine+sax, X'he meehoniea hg which bhs magnexie fiel@ Czaye a ylaemo otal he szyXBinee hp conBMGFinQ G chargse yaz'iiols aov9, ng in n CFOG vezas magnslio field zi The foxes cn hhs pazhiclo io given bp hho chars q...

  4. Office of the Vice President for ResearchOffice of the Vice President for Research New Faculty OrientationNew Faculty Orientation

    E-Print Network [OSTI]

    Krovi, Venkat

    awardsSources of UB Research Expenditures resulting from awards Federal Agencies FY 2005*Federal Agencies 2005 RF Expenditures byFederal Agency DoD 8% DOE 1% HHS 62% NASA 1% NSF 18% Other 10% USDA 0% USDA Do,136,0003,136,000 PharmaceuticsPharmaceutics 2,564,0002,564,000 Electrical EngineeringElectrical Engineering 2

  5. Background: Hurricane Elena, 1985. Image Science and Analysis Laboratory, NASA-Johnson Space Center, Astronaut Photography of Earth.

    E-Print Network [OSTI]

    Plant, Robert

    , but rather the Ekman pumping supports the PV mechanism, as- sisting with ventilation of PV from the boundary, the effects are large (Beare, 2007) [GH] = - hHs h2 (4) ∑ Eq. 4 describes PV generation by surface heat flux most Ekman pumping, especially around the cyclone centre ∑ PV anomaly remains, but is lower

  6. The Virial Method and the Classical Ellipsoids

    E-Print Network [OSTI]

    Norman R. Lebovitz

    Chandra completed his book Hydrodynamic and Hydromagnetic Stability (HHS) in 1960 and, as was his custom, turned his attention to a new area of research. He began to study general relativity at this time, and it appeared that this would be his

  7. Family Fitness = Family Fun! Presented by

    E-Print Network [OSTI]

    ∑ What is holding you back? Source: Summary Health Source: #12;Exercise & play together! ∑ Model habits-ups), at least 3 days per week. ∑ Examples: Tree Climbing, Climbing on playgrounds, Gymnastics, Hiking, Rock

  8. NIH Grants Policy Statement Introduction

    E-Print Network [OSTI]

    Firestone, Jeremy

    Statement (NIHGPS) is intended to make available to NIH grantees, in a single document, the policy to other organizations within the Department of Health and Human Services (HHS); specifies grantee, NIH, grantees, and activities that differ from, supplement, or elaborate on the standard terms and conditions

  9. NIH Grants Policy Statement Introduction

    E-Print Network [OSTI]

    Baker, Chris I.

    Statement (NIHGPS) is intended to make available to NIH grantees, in a single document, the policy to other organizations within the Department of Health and Human Services (HHS); specifies grantee, NIH of grants, grantees, and activities that differ from, supplement, or elaborate on the standard terms

  10. 3593Federal Register / Vol. 79, No. 14 / Wednesday, January 22, 2014 / Notices to read and prepare the information. No

    E-Print Network [OSTI]

    Rau, Don C.

    Poverty Guidelines AGENCY: Department of Health and Human Services. ACTION: Notice. SUMMARY: This notice provides an update of the Department of Health and Human Services (HHS) poverty guidelines to account that is responsible for that program. For information about poverty figures for immigration forms, the Hill

  11. Shrink-Swell Dynamics of Vertisol Catenae under Different Land Uses

    E-Print Network [OSTI]

    Dinka, Takele Mitiku


    NOMENCLATURE b Surface shrinkage ratio COLE Coefficient of Linear Extensibility h Thickness of a soil layer hfc Maximum thickness of a soil layer kPa Killo pascal mw,i Mass of water at a given water potential mt,i Total mass....2 The relationship between COLE with CaCO3 and fine clay content of soils. ........................................................................................................ 44 3.3 The soil subsidence (?Z) between a monument and rod installed...

  12. Low GWP Working Fluid for High Temperature Heat Pumps

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    Low GWP Working Fluid for High Temperature Heat Pumps: DR-2 Chemical Stability at High Temperatures Temp Heat Pumps: DR-2 Very Low GWP AND Non-Flammable HFC-245fa DR-2 Chemical Formula CF3CH2CHF2 HFO 171.3 Pcr [MPa] 3.65 2.9 Kontomaris-DuPont; European Heat Pump Summit, Nuremberg, October 15th, 2013

  13. Cooling season study and economic analysis of a desiccant cooling system

    E-Print Network [OSTI]

    Lee, James Howard


    . This effect stems from using refrigerants which contain fluorocarbons. Fluorocarbons released into the atmosphere react with, and destroy, upper level ozone. As a result several alternative cooling processes have been proposed as replacements. One... of the detrimental effect fluorocarbons have on the environment, legislation has been passed banning their manufacture and sale. Refrigerants proposed as replacements, HFC 134a and HCFC-123, are more costly and less efficient than fluorocarbon , and their long...

  14. Comparison of global warming impacts of automobile air-conditioning concepts

    SciTech Connect (OSTI)



    The global warming impacts of conventional vapor compression automobile air conditioning using HFC-134a are compared with the potential impacts of four alternative concepts. Comparisons are made on the basis of total equivalent warming impact (TEWI) which accounts for the effects of refrigerant emissions, energy use to provide comfort cooling, and fuel consumed to transport the weight of the air conditioning system. Under the most favorable assumptions on efficiency and weight, transcritical compression using CO{sub 2} as the refrigerant and adsorption cooling with water and zeolite beds could reduce TEWI by up to 18%rlative to HFC-134a compression air conditioning. Other assumptions on weight and efficiency lead to significant increases in TEWI relative to HFC-134a, and it is impossible to determine which set of assumptios is valid from existing data, Neither Stirling cycle or thermoelectric cooling will reduce TEWI relative to EFC-134a. Brief comments are also made concerning technical barriers that must be overcome for succesful development of the new technologies.

  15. A B C D E F G H CSULB "Campus Connection" Stop

    E-Print Network [OSTI]

    Sorin, Eric J.


  16. Coolant controversy heats up

    SciTech Connect (OSTI)

    Shanley, A.


    In 1987, nations of the world banded together under the Montreal Protocol to help protect the earth`s ozone layer. Now, ten years and $2.4 billion in new fluorocarbon R and D later, the ozone hole is still with us, as a black market in illegal chlorofluorocarbons thrives and legal trade in recycled CFCs continues. Unfortunately, each alternative to CFCs poses tradeoffs. Some hydrochlorofluorocarbons present lubricant compatibility problems, and, because they are also somewhat ozone depleting, they`ll be phased out in the US between 2010 and 2030, and earlier in Europe. Chlorine-free hydrofluorocarbons contribute to global warming and some require lubricant changes and retooling, while the processes that make them emit halogenated organics. This paper discusses compatibility, flammability, global warming, and supply problems.

  17. Supermarket with Ground Coupled Carbon Dioxide Refrigeration Plant

    E-Print Network [OSTI]

    Rehault, N.


    are massive energy consumers [4] EnOB [5] Kauffeld 2009 ? Fraunhofer ISE 4 Global emissions of fluorinated greenhouse gases Source: UBA ? 12.2010 1,1% 7,9% F-gas contribution to greenhouse effect 1. Backgrounds ? Fraunhofer ISE 5 Energy breakdown... refrigeration remains the last big subsector and the strongest emission source of the fluorinated hydrocarbons (HFC) in Germany? - Kauffeld [4] About 65 % of the cooling needs in Germany for frozen and refrigerated food products ? over 50.000 GWh...

  18. Geology of the Doss-North area, Mason and Gillespie Counties, Texas

    E-Print Network [OSTI]

    Coughran, Theodore


    Subuttted to the Oruguute Sohool of ihe igrioultaral end Weohautoal Solfege of %slue M purtfel falfilluent of the reqafroueute for ihe degree of tuguet ~ l~ S'upon Suh~ jK5r'. '-"'. "V~C4~4m&~;. '. % 'f 84i ' ~'i' $gfg, ( 1', 1 'p Qg ":Wth...~ll) '$, HA . Xi*: '-. ' ' . '. . . . '&Clif '. :Q9 'f/% ' +6 fWLO &&Q LC+&&4ii'aal. ? ~;g:, AQUA'Cli ~f gt OSOLOOV OF TIS SOSS-ARTS JIBE, lIAMS ANI GTLLSSPIR COQSFKS4& TSS44 A Thesis August, l400 kyytsrel as se etF14. ae4 ?safest hFc seas...

  19. The LiveWire Project final report

    SciTech Connect (OSTI)

    Brown, C.D.; Nelson, T.T. [Enova Technology, San Diego, CA (United States); Kelly, J.C.; Dominguez, H.A. [Paragon Consulting Services, La Verne, CA (United States)


    Utilities across the US have begun pilot testing a variety of hardware and software products to develop a two-way communications system between themselves and their customers. Their purpose is to reduce utility operating costs and to provide new and improved services for customers in light of pending changes in the electric industry being brought about by deregulation. A consortium including utilities, national labs, consultants, and contractors, with the support of the Department of Energy (DOE) and the Electric Power Research Institute (EPRI), initiated a project that utilized a hybrid fiber-coax (HFC) wide-area network integrated with a CEBus based local area network within the customers home. The system combined energy consumption data taken within the home, and home automation features to provide a suite of energy management services for residential customers. The information was transferred via the Internet through the HFC network, and presented to the customer on their personal computer. This final project report discusses the design, prototype testing, and system deployment planning of the energy management system.

  20. a b c d e f g h CSULB "Campus Connection" Stop

    E-Print Network [OSTI]

    Sorin, Eric J.

    8 E2 E7 E5 D4 E6 B1 G1 F6 H4 H5 F1 H5 F9 F9 G4 G4 G4 H4 H4 H4 F7 F7 G7 G7 D5 F8 G8 G8 F8 F7 F5 F5 B4 E8 G8 E8 E8 E8 E8 E7 E7 E8 C4 B5 F8 G7 G6 E9 C5 G5 D3 D2 H2 H1 B2 F7 F7 E7 E1 C1 H3 H5 D5 C5 H3 F9 F2 EN3 EN4 ECS ET FM FO2 FO3 FO4 FO5 FCS FA1 FA2 FA3 FA4 HSCI HHS1 HHS2 HSC HC HRL HSD IH JG KIN F8 G

  1. Emissions of greenhouse gases in the United States 1995

    SciTech Connect (OSTI)



    This is the fourth Energy Information Administration (EIA) annual report on US emissions of greenhouse gases. This report presents estimates of US anthropogenic (human-caused) emissions of carbon dioxide, methane, nitrous oxide, and several other greenhouse gases for 1988 through 1994. Estimates of 1995 carbon dioxide, nitrous oxide, and halocarbon emissions are also provided, although complete 1995 estimates for methane are not yet available. Emissions of carbon dioxide increased by 1.9% from 1993 to 1994 and by an additional 0.8% from 1994 to 1995. Most carbon dioxide emissions are caused by the burning of fossil fuels for energy consumption, which is strongly related to economic growth, energy prices, and weather. The US economy grew rapidly in 1994 and slowed in 1995. Estimated emissions of methane increased slightly in 1994, as a result of a rise in emissions from energy and agricultural sources. Estimated nitrous oxide emissions increased by 1.8% in 1995, primarily due to increased use of nitrogen fertilizers and higher output of chemicals linked to nitrous oxide emissions. Estimated emissions of hydrofluorocarbons (HFCs) and perfluorocarbons (PFCs), which are known to contribute to global warming, increased by nearly 11% in 1995, primarily as a result of increasing substitution for chlorofluorocarbons (CFCs). With the exception of methane, the historical emissions estimates presented in this report are only slightly revised from those in last year`s report.

  2. Delocalization and hybridization enhance the magnetocaloric effect in Ni2Mn0.75Cu0.25Ga

    SciTech Connect (OSTI)

    Roy, Sujoy; Blackburn, E.; Valvidares, S. M.; Fitzsimmons, M. R.; Vogel, Sven C.; Khan, M.; Dubenko, I.; Stadler, S.; Ali, N.; Sinha, S. K.; Kortright, J. B.


    In view of the looming energy crisis facing our planet, attention increasingly focuses on materials potentially useful as a basis for energy saving technologies. The discovery of giant magnetocaloric (GMC) compounds - materials that exhibit especially large changes in temperature as the externally applied magnetic field is varied - is one such compound 1. These materials have potential for use in solid state cooling technology as a viable alternative to existing gas based refrigeration technologies that use choro-fluoro - and hydro-fluoro-carbon chemicals known to have a severe detrimental effect on human health and environment 2,3. Examples of GMC compounds include Gd5(SiGe)4 4, MnFeP1-xAsx 5 and Ni-Mn-Ga shape memory alloy based compounds 6-8. Here we explain how the properties of one of these compounds (Ni2MnGa) can be tuned as a function of temperature by adding dopants. By altering the free energy such that the structural and magnetic transitions coincide, a GMC compound that operates at just the right temperature for human requirements can be obtained 9. We show how Cu, substituted for Mn, pulls the magnetic transition downwards in temperature and also, counterintuitively, increases the delocalization of the Mn magnetism. At the same time, this reinforces the Ni-Ga chemical bond, raising the temperature of the martensite-austenite transition. At 25percent doping, the two transitions coincide at 317 K.

  3. Plant Maintenance and Improvement Experiences for Control System in UCN 5 and 6

    SciTech Connect (OSTI)

    Choi, D.R.; Lee, K.B.; Kim, C.J.; Chung, Y.M. [Korea Hydro and Nuclear Power Co., Ltd., no. 84-1, Bugu-ri, Buk-Myeon, Ulchin-gun, Kyong-buk (Korea, Republic of)


    The Plant Control System (PCS) in Korean Standard Nuclear Power Plant (KSNP) is designed to perform data acquisition and transfer function via communication data links to control most of the field components such as pumps, fans, valves, dampers and circuit breakers. The PCS installed at UCN 5 and 6 for both safety related and non -safety related functions is microprocessor based system supplied by HF Controls. Safety related functions are provided by redundant trains of microprocessor based single loop controllers with direct connections to the field input/output instruments but non-safety related functions utilize a similar construction with the input/output boards to be remotely located in cabinet arrangements near the field components. Whatever the functions, the signals to control and monitor field devices are processed through communication master (CM), HFC distributed control system, which uses Multibus I back-plane design to accommodate the requirement of multiple processors. The complex programmable logic device (CPLD) mounted on the A233 back-plane of the CM controls the processors for an adequate access to the bus so that 16 microprocessor based circuitries acting as bus masters share the public memory properly through the common bus. The bus occupation of each processor should not affect overall system response time to keep appropriate system performance. This paper discusses the comparison evaluation between the difference priority techniques and hardware change on A233 back-plane to improve the communication methods, etc., as to the bus arbitration schemes of communication master(CM) applied to UCN site based on the waveform data acquired from A233 CPLD and HFC bus design specification. (authors)

  4. Effects of Water in Synthetic Lubricant Systems and Clathrate Formation: A Literature Search and Review

    SciTech Connect (OSTI)

    Rohatgi, Ngoc Dung T.


    An extensive literature search and a confidential survey were critically analyzed to determine the effects of water on the stability of hydrofluorocarbon/synthetic lubricant systems and to identify key areas requiring further investigation. Following are highlights from the analysis: Clathrate hydrates are solid solutions formed when water molecules are linked through hydrogen bonding creating cavities that can enclose various guest molecules from hydrate formers, such as hydrofluorocarbons R-32, R-125, R-134a, R-407C and R-410A. The four methods for preventing clathrate formation were drying the gas, heating it, reducing its pressure, or using inhibitors. The hydrolysis of polyolester lubricants was mostly acid-catalyzed and its reaction rate constant typically followed the Arrhenius equation of an activated process. Hydrolytic stability improved with hindered molecular structures, and with the presence of acid catcher additives and desiccants. Water vapor can effect the adsorption of long-chain fatty acids and the chemistry of formation of protective oxide film. However, these effects on lubrication can be either positive or negative. Fifty to sixty percent of the moisture injected into an air-conditioning system remained in the refrigerant and the rest mixed with the compressor oil. In an automotive air-conditioning system using R-134a, ice would form at 0 C evaporating temperature when the water content in the vapor refrigerant on the low-pressure side was more than 350 ppm. Moisture would cause the embrittlement of polyethylene terephthalate and the hydrolysis of polyesters, but would reduce the effect of amine additives on fluoroelastomer rubbers. The reactions of water with refrigerants and lubricants would cause formicary and large-pit corrosion in copper tubes, as well as copper plating and sludge formation. Moreover, blockage of capillary tubes increased rapidly in the presence of water. Twenty-four companies responded to the survey. From the responses, the water concentrations specified and expected for different refrigerant/lubricant systems varied depending on the products, their capacities and applications, and also on the companies. Among the problems associated with high moisture level, lubricant breakdown was of greatest concern, followed by acid formation, compressor failure and expansion valve sticking. The following research topics are suggested: 1. The air-conditioning and refrigeration industry needs to measure and record the water content and total acid number of the lubricant of newly installed systems as well as operating systems that are shutdown for service or repair. The reason for the shutdown needs to be documented. A database can then be established to correlate water content with type and cause of breakdown. 2. Detailed studies on the distribution of water in refrigeration and air-conditioning systems should be conducted to pinpoint problem areas associated with free water. 3. Research is needed to validate the current theories and mechanisms of formicary corrosion. Corrosion inhibitors need to be developed. 4. The conditions for clathrate formation and decomposition of other alternative refrigerants, such as R-23, R-41, R-116, R-125, R-143a, R-404A and R-507C, and water should be determined to avoid possible problems associated with tube plugging. The mechanism by which water facilitates or hinders lubrication needs to be studied.

  5. Toxicity of trifluoroacetate to aquatic organisms

    SciTech Connect (OSTI)

    Berends, A.G.; Rooij, C.G. de [Solvay S.A., Brussels (Belgium); Boutonnet, J.C. [Elf Atochem, Levallois-Perret (France); Thompson, R.S. [Zeneca Ltd., Devon (United Kingdom). Brixham Environmental Lab.


    As a result of the atmospheric degradation of several hydrofluorocarbons and hydrochlorofluorocarbons, trifluoroacetate (TFA) will be formed. Through precipitation, TFA will enter aquatic ecosystems. To evaluate the impact on the aquatic environment, an aquatic toxicity testing program was carried out with sodium trifluoroacetate (NaTFA). During acute toxicity tests, no effects of NaTFA on water fleas (Daphnia magna) and zebra fish (Danio retrio) were found at a concentration of 1,200 mg/L. A 7-d study with duckweed (Lemna gibba Ge) revealed a NOEC of 300 mg/L. On the basis of the results of five toxicity tests with Selenastrum capricornutum, they determined a NOEC of 0.12 mg/L. However, algal toxicity tests with NaTFA and Chlorella vulgaris, Scenedesmus subspicatus, Chlamydomonas reinhardtii, Dunaliella tertiolecta, Eugelan gracilis, Phaeodactylum tricornutum, Navicula pelliculosa, Skeletonema costatum, Anabaena flos-aquae, and Microcystis aeruginosa resulted in EC50 values that were all higher than 100 mg/L. The toxicity of TFA to S. capricornutum could be due to metabolic defluorination to monofluoroacetate (MFA), which is known to inhibit the citric acid cycle. A toxicity test with MFA and S. capricornutum revealed it to be about three orders of magnitude more toxic than TFA. However, a bioactivation study revealed that defluorination of TFA was less than 4%. On the other hand, S. capricornutum exposed to a toxic concentration of NaTFA showed a recovery of growth when citric acid was added, suggesting that TFA (or a metabolite of TFA) interferes with the citric acid cycle. A recovery of the growth of S. capricornutum was also found when TFA was removed from the test solutions. Therefore, TFA should be considered algistatic and not algicidic for S. capricornutum. On the basis of the combined results of the laboratory tests and a previously reported semi-field study, they can consider a TFA concentration of 0.10 mg/L as safe for the aquatic ecosystem.

  6. The Climate Change Action Plan: Technical supplement

    SciTech Connect (OSTI)

    Not Available


    This Technical Annex documents the assumptions and parameters used in developing the supporting analysis for the Climate Change Action Plan (the Plan) issued by President Clinton on October 19, 1993. The Annex is intended to meet the needs of independent energy and environmental analysts who wish to better understand the Plan, its analytical underpinnings, and the events that need to transpire for the emissions reductions called for in the Plan to be realized. The Plan documented in this Annex reflects the outcome of a wide-ranging effort by Government agencies and interested members of the public to develop and implement actions that can reduce net greenhouse gas emissions in the year 2000 to their aggregate 1990 level. Based on agency and public input, the Climate Change Mitigation Group, chaired by the White House Office on Environmental Policy, developed the Plan`s content. Many of the actions called for in the Plan are now underway, while others are in advanced planning pending congressional action on the fiscal year 1995 budget. The analysis supporting the Plan represents the results of an interagency effort. The US Department of Energy (DOE) was responsible for the integrated analysis of energy-related options, based on the analysis of individual energy-related options by DOE, the US Environmental Protection Agency (EPA), and the US Department of Transportation (DOT). EPA led in providing analysis for actions related to methane, hydrofluorocarbons, and perfluorocarbons. The US Department of Agriculture (USDA) led the analysis of carbon sequestration actions and cooperated with EPA in the analysis of actions to reduce nitrous oxide emissions.

  7. Demonstration of High Efficiency Elastocaloric Cooling with Large Delta- T Using NiTi Wires

    SciTech Connect (OSTI)

    Cui, Jun; Wu, Yiming; Muehlbauer, Jan; Hwang, Yunho; Radermacher, Reinhard; Fackler, Sean; Wuttig, Manfred; Takeuchi, Ichiro


    Vapor compression (VC) is by far the most dominant technology for meeting all cooling and refrigeration needs around the world. It is a mature technology with the efficiency of modern compressors approaching the theoretical limit, but its envi-ronmental footprint remains a global problem. VC refrigerants such as hydrochlo-roflurocarbons (HCFCs) and hydrofluorocarbons (HFCs) are a significant source of green house gas (GHG) emissions, and their global warming potential (GWP) is as high as 1000 times that of CO2. It is expected that building space cooling and re-frigeration alone will amount to {approx} 5% of primary energy consumption and {approx}5% of all CO2 emission in U.S. in 2030 . As such, there is an urgent need to develop an al-ternative high-efficiency cooling technology that is affordable and environmentally friendly. Among the proposed candidates, magnetocaloric cooling (MC) is currently received a lot of attention because of its high efficiency. However, MC is inherently expensive because of the requirement of large magnetic field and rare earth materi-als. Here, we demonstrate an entirely new type of solid-state cooling mechanism based on the latent heat of reversible martensitic transformation. We call it elasto-caloric cooling (EC) after the superelastic transformation of austenite it utilizes. The solid-state refrigerant of EC is cost-effective, and it completely eliminates the use of any refrigerants including HCFCs/HFCs. We show that the COP (coefficient of per-formance) of a jugular EC with optimized materials can be as high as > 10 with measured {Delta}T of 17 C.

  8. Properties and Cycle Performance of Refrigerant Blends Operating Near and Above the Refrigerant Critical Point, Task 1: Refrigerant Properties

    SciTech Connect (OSTI)

    Mark O. McLinden; Arno Laesecke; Eric W. Lemmon; Joseph W. Magee; Richard A. Perkins


    The main goal of this project was to investigate and compare the performance of an R410A air conditioner to that of an R22 air conditioner, with specific interest in performance at high ambient temperatures at which the condenser of the R410A system may be operating above the refrigerant's critical point. Part 1 of this project consisted of measuring thermodynamic properties R125, R410A and R507A, measuring viscosity and thermal conductivity of R410A and R507A and comparing data to mixture models in NIST REFPROP database. For R125, isochoric (constant volume) heat capacity was measured over a temperature range of 305 to 397 K (32 to 124 C) at pressures up to 20 MPa. For R410A, isochoric heat capacity was measured along 8 isochores with a temperature range of 303 to 397 K (30 to 124 C) at pressures up to 18 MPa. Pressure-density-temperature was also measured along 14 isochores over a temperature range of 200 to 400 K (-73 to 127 C) at pressures up to 35 MPa and thermal conductivity along 6 isotherms over a temperature range of 301 to 404 K (28 to 131 C) with pressures to 38 MPa. For R507A, viscosity was measured along 5 isotherms over a temperature range of 301 to 421 K (28 to 148 C) at pressures up to 83 MPa and thermal conductivity along 6 isotherms over a temperature range of 301 to 404 K (28 to 131 C) with pressures to 38 MPa. Mixture models were developed to calculate the thermodynamic properties of HFC refrigerant mixtures containing R32, R125, R134a and/or R125. The form of the model is the same for all the blends considered, but blend-specific mixing functions are required for the blends R32/125 (R410 blends) and R32/134a (a constituent binary of R407 blends). The systems R125/134a, R125/143a, R134a/143a, and R134a/152a share a common, generalized mixing function. The new equation of state for R125 is believed to be the most accurate and comprehensive formulation of the properties for that fluid. Likewise, the mixture model developed in this work is the latest state-of-the-art for thermodynamic properties of HFC refrigerant blends. These models were incorporated into version 7 of NIST REFPROP database.

  9. DOE Hanford Network Upgrades and Disaster Recovery Exercise Support the Cleanup Mission Now and into the Future

    SciTech Connect (OSTI)

    Eckman, Todd J. [Mission Support Alliance, Richland, WA (United States); Hertzel, Ali K. [Lockheed Martin Services, Inc. (United States); Lane, James J. [Lockheed Martin - Information Systems and Global Solutions (United States)


    In 2013, the U.S. Department of Energy's (DOE) Hanford Site, located in Washington State, funded an update to the critical network infrastructure supporting the Hanford Federal Cloud (HFC). The project, called ET-50, was the final step in a plan that was initiated five years ago called "Hanford's IT Vision, 2015 and Beyond." The ET-50 project upgraded Hanford's core data center switches and routers along with a majority of the distribution layer switches. The upgrades allowed HFC the network intelligence to provide Hanford with a more reliable and resilient network architecture. The culmination of the five year plan improved network intelligence and high performance computing as well as helped to provide 10 Gbps capable links between core backbone devices (10 times the previous bandwidth). These improvements allow Hanford the ability to further support bandwidth intense applications, such as video teleconferencing. The ET-50 switch upgrade, along with other upgrades implemented from the five year plan, have prepared Hanford's network for the next evolution of technology in voice, video, and data. Hand-in-hand with ET-50's major data center outage, Mission Support Alliance's (MSA) Information Management (IM) organization executed a disaster recovery (DR) exercise to perform a true integration test and capability study. The DR scope was planned within the constraints of ET-50's 14 hour datacenter outage window. This DR exercise tested Hanford's Continuity of Operations (COOP) capability and failover plans for safety and business critical Hanford Federal Cloud applications. The planned suite of services to be tested was identified prior to the outage and plans were prepared to test the services ability to failover from the primary Hanford data center to the backup data center. The services tested were: Core Network (backbone, firewall, load balancers); Voicemail; Voice over IP (VoIP); Emergency Notification; Virtual desktops; and, Select set of production applications and data. The primary objective of the exercise was to test COOP around the emergency operations at Hanford to provide information on capabilities and dependencies of the current system to insure improved focus of emergency, safety and security capacity in a disaster situation. The integration of the DR test into the ET-50 project allowed the testing of COOP at Hanford and allowed the lessons learned to be defined. These lessons learned have helped improve the understanding of Hanford's COOP capabilities and will be critical for future planning. With the completion of the Hanford Federal Cloud network upgrades and the disaster recovery exercise, the MSA has a clearer path forward for future technology implementations as well as network improvements to help shape the usability and reliability of the Hanford network in support of the cleanup mission.

  10. Accelerated screening methods for determining chemical and thermal stability of refrigerant-lubricant mixtures, Part 1: Method assessment. Final report

    SciTech Connect (OSTI)

    Kauffman, R.


    This report presents results of a literature search performed to identify analytical techniques suitable for accelerated screening of chemical and thermal stabilities of different refrigerant/lubricant combinations. Search focused on three areas: Chemical stability data of HFC-134a and other non-chlorine containing refrigerant candidates; chemical stability data of CFC-12, HCFC-22, and other chlorine containing refrigerants; and accelerated thermal analytical techniques. Literature was catalogued and an abstract was written for each journal article or technical report. Several thermal analytical techniques were identified as candidates for development into accelerated screening tests. They are easy to operate, are common to most laboratories, and are expected to produce refrigerant/lubricant stability evaluations which agree with the current stability test ANSI/ASHRAE (American National Standards Institute/American Society of Heating, Refrigerating, and Air-Conditioning Engineers) Standard 97-1989, ``Sealed Glass Tube Method to Test the Chemical Stability of Material for Use Within Refrigerant Systems.`` Initial results of one accelerated thermal analytical candidate, DTA, are presented for CFC-12/mineral oil and HCFC-22/mineral oil combinations. Also described is research which will be performed in Part II to optimize the selected candidate.

  11. Performance characteristics of a turbo expander substituted for expansion valve on air-conditioner

    SciTech Connect (OSTI)

    Cho, Soo-Yong [Department of Mechanical and Aerospace Engineering (ReCAPT), Gyeongsang National University, 900 Gajoa-dong, Jinju 660-701 (Korea); Cho, Chong-Hyun [School of Mechanical and Aerospace Engineering, Gyeongsang National University, 900 Gajoa-dong, Jinju 660-701 (Korea); Kim, Chaesil [Department of Mechanical Engineering, Changwon National University, 9 Sarim-dong, Changwon 641-773 (Korea)


    An experimental study is conducted on a small turbo expander which could be applied to the expansion process in place of expansion valves in refrigerator or air-conditioner to improve the cycle efficiency by recovering energy from the throttling process. The operating gas is HFC134a and the maximum cooling capacity of experiment apparatus is 32.7 kW. Four different turbo expanders are tested to find the performance characteristics of the turbo expander when they operate at a low partial admission rate. The partial admission rate is 1.70% or 2.37, and expanders are operated in the supersonic flow. In the experiment, pressure and temperature are measured at 10 different locations in the experimental apparatus. In addition to these measurements, output power at the turbo expander is measured through a generator installed on a rotor shaft with the rotational speed. Performance data of the turbo expander are obtained at many part load operations by adjusting the output power of the generator. A maximum of 15.8% total-to-static efficiency is obtained when the pressure ratio and the partial admission ratio are 2.37 and 1.70%, respectively. Experimental results show that the optimal velocity ratio decreases when the pressure ratio is decreased, and peak efficiencies, which are obtained at locally maximized efficiency depending on the operating condition, vary linearly against the subcooling temperature or the pressure ratio. (author)

  12. Greenhouse Gas Management Program Overview (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available


    Program fact sheet highlighting federal requirements for GHG emissions management, FEMP services to help agencies reduce emissions, and additional resources. The U.S. Department of Energy (DOE) Federal Energy Management Program (FEMP) assists Federal agencies with managing their greenhouse gas (GHG) emissions. GHG management entails measuring emissions and understanding their sources, setting a goal for reducing emissions, developing a plan to meet this goal, and implementing the plan to achieve reductions in emissions. FEMP provides the following services to help Federal agencies meet the requirements of inventorying and reducing their GHG emissions: (1) FEMP offers one-on-one technical assistance to help agencies understand and implement the Federal Greenhouse Gas Accounting and Reporting Guidance and fulfill their inventory reporting requirements. (2) FEMP provides training, tools, and resources on FedCenter to help agencies complete their annual inventories. (3) FEMP serves a leadership role in the interagency Federal Working Group on Greenhouse Gas Accounting and Reporting that develops recommendations to the Council on Environmental Quality (CEQ) for the Federal Greenhouse Gas Accounting and Reporting Guidance. (4) As the focus continues to shift from measuring emissions (completing inventories) to mitigating emissions (achieving reductions), FEMP is developing a strategic planning framework and resources for agencies to prioritize among a variety of options for mitigating their GHG emissions, so that they achieve their reduction goals in the most cost-effective manner. These resources will help agencies analyze their high-quality inventories to make strategic decisions about where to use limited resources to have the greatest impact on reducing emissions. Greenhouse gases trap heat in the lower atmosphere, warming the earth's surface temperature in a natural process known as the 'greenhouse effect.' GHGs include carbon dioxide (CO{sub 2}), methane (CH{sub 4}), nitrous oxide (N{sub 2}O), perfluorocarbons (PFCs), hydrofluorocarbons (HFCs), and sulfur hexafluoride (SF{sub 6}). Human activities have caused a rapid increase in GHG concentrations. This rising level contributes to global climate change, which contributes to environmental and public health problems.

  13. EVermont Renewable Hydrogen Production and Transportation Fueling System

    SciTech Connect (OSTI)

    Garabedian, Harold T.


    A great deal of research funding is being devoted to the use of hydrogen for transportation fuel, particularly in the development of fuel cell vehicles. When this research bears fruit in the form of consumer-ready vehicles, will the fueling infrastructure be ready? Will the required fueling systems work in cold climates as well as they do in warm areas? Will we be sure that production of hydrogen as the energy carrier of choice for our transit system is the most energy efficient and environmentally friendly option? Will consumers understand this fuel and how to handle it? Those are questions addressed by the EVermont Wind to Wheels Hydrogen Project: Sustainable Transportation. The hydrogen fueling infrastructure consists of three primary subcomponents: a hydrogen generator (electrolyzer), a compression and storage system, and a dispenser. The generated fuel is then used to provide transportation as a motor fuel. EVermont Inc., started in 1993 by then governor Howard Dean, is a public-private partnership of entities interested in documenting and advancing the performance of advanced technology vehicles that are sustainable and less burdensome on the environment, especially in areas of cold climates, hilly terrain and with rural settlement patterns. EVermont has developed a demonstration wind powered hydrogen fuel producing filling system that uses electrolysis, compression to 5000 psi and a hydrogen burning vehicle that functions reliably in cold climates. And that fuel is then used to meet transportation needs in a hybrid electric vehicle whose internal combustion engine has been converted to operate on hydrogen Sponsored by the DOE EERE Hydrogen, Fuel Cells & Infrastructure Technologies (HFC&IT) Program, the purpose of the project is to test the viability of sustainably produced hydrogen for use as a transportation fuel in a cold climate with hilly terrain and rural settlement patterns. Specifically, the project addresses the challenge of building a renewable transportation energy capable system. The prime energy for this project comes from an agreement with a wind turbine operator.

  14. Overview of CFC replacement issues for household refrigeration

    SciTech Connect (OSTI)

    Vineyard, E.A. [Oak Ridge National Lab., TN (United States); Roke, L. [Fisher and Paykel, Auckland (New Zealand); Hallett, F. [Frigidaire, Washington, DC (United States)


    In 1974, the famous ozone depletion theory of Rowland and Molina claimed that chlorofluorocarbons (CFCs) diffuse into the stratosphere where they are broken down by photolysis to release chlorine atoms that catalytically destroy ozone. Although the understanding of the science is still imperfect, there is little doubt that CFCs play a major role in the Antarctic ozone hole phenomenon and the decline in ozone observed in the rest of the world. Another issue that has become increasingly important is the potential of CFCs to change the earth`s temperature and to modify the climate. While the main impact in global warming is made by increased concentrations of carbon dioxide, CFCs and other trace gases also contribute to this effect. In an effort to respond to the global environmental threat, a CFC protocol was adopted during a diplomatic conference in Montreal. This document, known as the Montreal Protocol, was ratified in 1988 and put into effect on January 1, 1989. In accordance with Article 6 of the Montreal Protocol, the countries that signed the agreement shall periodically assess the control measures provided for in the Protocol. As part of that assessment process, household refrigeration was investigated to determine the status of CFC-12 replacements. The conclusion was that much progress has been made towards finding a suitable replacement. Compressors designed for HFC-134a have efficiencies comparable to those for CFC-12 and acceptable reliability tests have been obtained with ester lubricants. In addition, other replacements such as R-152a and refrigerant mixtures exist, but will require more study. Cycle options, such as the Stirling cycle, may be viable, but are further out in the future. The impact of new refrigerants is expected to result in elimination of CFC-12 consumption in developed countries by 1997 and in developing countries by 2005.

  15. Development of single crystal filaments. Final report

    SciTech Connect (OSTI)

    Milewski, J.V.; Shoultz, R.A.; Bourque-McConnell, M.M.


    The program just completed addresses a route to a more efficient longer-lasting electric light bulb filament. All current filaments for light bulbs are metallic in nature. They are subject to embrittlement with age (large grain growth) and relatively high vapor pressures which limits their operating temperature. There is evidence which suggests advantages to using high temperature refractory single crystal fibers as a filament for a light bulb. These refractory materials may include materials such as hafnium or tantalum carbide which have melting points about 500{degrees}C higher than tungsten. Another advantage is that single crystal fibers have a very high degree of crystalline perfection with very few voids and dislocations. Without these imperfections, the atomic mobility at high temperatures is highly restricted. Thus single crystal fibers are very stable at high temperature and will last longer. The efficiencies result from running these single crystal ceramic fiber filaments at higher temperatures and the higher emissivity of the carbide filaments compared to tungsten. The amount of visible light is proportional to the 4the power of the temperature thus a 500{degrees}C higher operating give about a 3-fold increase in radiation in the visible range. The program accomplishments can be summarized as follows: (1) Single crystal fibers of JfC sufficient crystal quality for light bulb filament applications were made. (2) The HfC fiber furnace growth chamber, power control and data collection system was developed for the laboratory scale plant. (3) method for mounting and apparatuses for testing the single crystal fiber filaments were developed and built.

  16. Evaluation of design options for improving the energy efficiency of an environmentally safe domestic refrigerator-freezer

    SciTech Connect (OSTI)

    Vineyard, E.A.; Sand, J.R. [Oak Ridge National Lab., TN (United States); Bohman, R.H.


    In order to reduce greenhouse emissions from power plants and respond to regulatory actions arising from the National Appliance Energy Conservation Act (NAECA), several design options were investigated for improving the energy efficiency of a conventionally designed, domestic refrigerator-freezer. The options, such as improved cabinet insulation and high-efficiency compressor and fans, were incorporated into a prototype refrigerator-freezer cabinet and refrigeration system to produce a unit that is superior from an environmental viewpoint due to its lower energy consumption and the use of refrigerant HFC-134a as a replacement for CFC-12. Baseline energy performance of the original 1993 production refrigerator-freezer, along with cabinet heat load and compressor calorimeter test results, were extensively documented to provide a firm basis for experimentally measured energy savings. A detailed refrigerator system computer model was used to evaluate the energy savings for several design modifications that, collectively, could achieve a targeted energy consumption of 1.00 kWh/d for a 20 ft{sup 3} (570 l) top-mount, automatic-defrost, refrigerator-freezer. The energy consumption goal represents a 50% reduction in the 1993 NAECA standard for units of this size. Following the modeling simulation, laboratory prototypes were fabricated and tested to experimentally verify the analytical results and aid in improving the model in those areas where discrepancies occurred. While the 1.00 kWh/d goal was not achieved with the modifications, a substantial energy efficiency improvement of 22% (1.41 kWh/d) was demonstrated using near-term technologies. It is noted that each improvement exacts a penalty in terms of increased cost or system complexity/reliability. Further work on this project will analyze cost-effectiveness of the design changes and investigate alternative, more-elaborate, refrigeration system changes to further reduce energy consumption.

  17. Federal technology transfer requirements :a focused study of principal agencies approaches with implications for the Department of Homeland Security.

    SciTech Connect (OSTI)

    Koker, Denise; Micheau, Jill M.


    This report provides relevant information and analysis to the Department of Homeland Security (DHS) that will assist DHS in determining how to meet the requirements of federal technology transfer legislation. These legal requirements are grouped into five categories: (1) establishing an Office of Research and Technology Applications, or providing the functions thereof; (2) information management; (3) enabling agreements with non-federal partners; (4) royalty sharing; and (5) invention ownership/obligations. These five categories provide the organizing framework for this study, which benchmarks other federal agencies/laboratories engaged in technology transfer/transition Four key agencies--the Department of Health & Human Services (HHS), the U.S. Department of Agriculture (USDA), the Department of Energy (DOE), and the Department of Defense (DoD)--and several of their laboratories have been surveyed. An analysis of DHS's mission needs for commercializing R&D compared to those agencies/laboratories is presented with implications and next steps for DHS's consideration. Federal technology transfer legislation, requirements, and practices have evolved over the decades as agencies and laboratories have grown more knowledgeable and sophisticated in their efforts to conduct technology transfer and as needs and opinions in the federal sector have changed with regards to what is appropriate. The need to address requirements in a fairly thorough manner has, therefore, resulted in a lengthy paper. There are two ways to find summary information. Each chapter concludes with a summary, and there is an overall ''Summary and Next Steps'' chapter on pages 57-60. For those readers who are unable to read the entire document, we recommend referring to these pages.

  18. Weatherization Works: Final Report of the National Weatherization Evaluation

    SciTech Connect (OSTI)

    Brown, M.A.


    In 1990, the US Department of Energy (DOE) sponsored a comprehensive evaluation of its Weatherization Assistance Program, the nation's largest residential energy conservation program. Oak Ridge National Laboratory (ORNL) managed the five-part study. This document summarizes the findings of the evaluation. Its conclusions are based mainly on data from the 1989 program year. The evaluation concludes that the Program meets the objectives of its enabling legislation and fulfills its mission statement. Specifically, it saves energy, lowers fuel bills, and improves the health and safety of dwellings occupied by low-income people. In addition, the Program achieves its mission in a cost-effective manner based on each of three perspectives employed by the evaluators. Finally, the evaluation estimates that the investments made in 1989 will, over a 20-year lifetime, save the equivalent of 12 million barrels of oil, roughly the amount of oil added to the Strategic Petroleum Reserve in each of the past several years. The Program's mission is to reduce the heating and cooling costs for low-income families--particularly the elderly, persons with disabilities, and children by improving the energy efficiency of their homes and ensuring their health and safety. Substantial progress has been made, but the job is far from over. The Department of Health and Human Services (HHS) reports that the average low-income family spends 12 percent of its income on residential energy, compared to only 3% for the average-income family. Homes where low-income families live also have a greater need for energy efficiency improvements, but less money to pay for them.

  19. Properties and Cycle Performance of Refrigerant Blends Operating Near and Above the Refrigerant Critical Point, Task 2: Air Conditioner System Study

    SciTech Connect (OSTI)

    Piotr A. Domanski; W. Vance Payne


    The main goal of this project was to investigate and compare the performance of an R410A air conditioner to that of an R22 air conditioner, with specific interest in performance at high ambient temperatures at which the condenser of the R410A system may be operating above the refrigerant's critical point. Part 1 of this project consisted of conducting comprehensive measurements of thermophysical for refrigerant R125 and refrigerant blends R410A and R507A and developing new equation of state formulations and mixture models for predicting thermophysical properties of HFC refrigerant blends. Part 2 of this project conducted performance measurements of split-system, 3-ton R22 and R410A residential air conditioners in the 80 to 135 F (27.8 to 57.2 C) outdoor temperature range and development of a system performance model. The performance data was used in preparing a beta version of EVAP-COND, a windows-based simulation package for predicting performance of finned-tube evaporators and condensers. The modeling portion of this project also included the formulation of a model for an air-conditioner equipped with a thermal expansion valve (TXV). Capacity and energy efficiency ratio (EER) were measured and compared. The R22 system's performance was measured over the outdoor ambient temperature range of 80 to 135 F (27.8 to 57.2 C). The same test range was planned for the R410A system. However, the compressor's safety system cut off the compressor at the 135.0 F (57.2 C) test temperature. The highest measurement on this system was at 130.0 F (54.4 C). Subsequently, a custom-manufactured R410A compressor with a disabled safety system and a more powerful motor was installed and performance was measured at outdoor temperatures up to 155.0 F (68.3 C). Both systems had similar capacity and EER performance at 82.0 F (27.8 C). The capacity and EER degradation of both systems were nearly linearly dependent with rising ambient outdoor ambient test temperatures. The performance degradation of R410A at higher temperatures was greater than R22. However, the R22 and R410A systems both operated normally during all tests. Visual observations of the R410A system provided no indication of vibrations or TXV hunting at high ambient outdoor test conditions with the compressor operating in the transcritical regime.

  20. DOE/AHAM advanced refrigerator technology development project

    SciTech Connect (OSTI)

    Vineyard, E.A.; Sand, J.R.; Rice, C.K.; Linkous, R.L.; Hardin, C.V.; Bohman, R.H.


    As part of the effort to improve residential energy efficiency and reduce greenhouse emissions from power plants, several design options were investigated for improving the energy efficiency of a conventionally designed domestic refrigerator-freezer. The program goal was to reduce the energy consumption of a 20-ft{sup 3} (570-L) top-mount refrigerator-freeze to 1.00 kWh/d, a 50% reduction from the 1993 National Appliance Energy Conservation Act (NAECA) standard. The options--such as improved cabinet and door insulation, a high-efficiency compressor, a low-wattage fan, a large counterflow evaporator, and adaptive defrost control--were incorporated into prototype refrigerator-freezer cabinets and refrigeration systems. The refrigerant HFC-134a was used as a replacement for CFC-12. The baseline energy performance of the production refrigerator-freezers, along with cabinet heat load and compressor calorimeter test results, were extensively documented to provide a firm basis for experimentally measured energy savings. The project consisted of three main phases: (1) an evaluation of energy-efficient design options using computer simulation models and experimental testing, (2) design and testing of an initial prototype unit, and (3) energy and economic analyses of a final prototype. The final prototype achieved an energy consumption level of 0.93 kWh/d--an improvement of 45% over the baseline unit and 54% over the 1993 NAECA standard for 20-fg{sup 3} (570-L) units. The manufacturer`s cost for those improvements was estimated at $134; assuming that cost is doubled for the consumer, it would take about 11.4 years to pay for the design changes. Since the payback period was thought to be unfeasible, a second, more cost-effective design was also tested. Its energy consumption level was 1.16 kWh/d, a 42% energy savings, at a manufacturer`s cost increase of $53. Again assuming a 100% markup, the payback for this unit would be 6.6 years.

  1. Hybrid Membrane/Absorption Process for Post-combustion CO2 Capture

    SciTech Connect (OSTI)

    Li, Shiguang; Shou, S.; Pyrzynski, Travis; Makkuni, Ajay; Meyer, Howard


    This report summarizes scientific/technical progress made for bench-scale membrane contactor technology for post-combustion CO2 capture from DOE Contract No. DE-FE-0004787. Budget Period 1 (BP1) membrane absorber, Budget Period 2 (BP2) membrane desorber and Budget Period 3 (BP3) integrated system and field testing studies have been completed successfully and met or exceeded the technical targets (? 90% CO2 removal and CO2 purity of 97% in one membrane stage). Significant breakthroughs are summarized below: BP1 research: The feasibility of utilizing the poly (ether ether ketone), PEEK, based hollow fiber contractor (HFC) in combination with chemical solvents to separate and capture at least 90% of the CO2 from simulated flue gases has been successfully established. Excellent progress has been made as we have achieved the BP1 goal: ? 1,000 membrane intrinsic CO2 permeance, ? 90% CO2 removal in one stage, ? 2 psi gas side pressure drop, and ? 1 (sec)-1 mass transfer coefficient. Initial test results also show that the CO2 capture performance, using activated Methyl Diethanol Amine (aMDEA) solvent, was not affected by flue gas contaminants O2 (~3%), NO2 (66 ppmv), and SO2 (145 ppmv). BP2 research: The feasibility of utilizing the PEEK HFC for CO2-loaded solvent regeneration has been successfully established High CO2 stripping flux, one order of magnitude higher than CO2 absorption flux, have been achieved. Refined economic evaluation based on BP1 membrane absorber and BP2 membrane desorber laboratory test data indicate that the CO2 capture costs are 36% lower than DOEís benchmark amine absorption technology. BP3 research: A bench-scale system utilizing a membrane absorber and desorber was integrated into a continuous CO2 capture process using contactors containing 10 to 20 ft2 of membrane area. The integrated process operation was stable through a 100-hour laboratory test, utilizing a simulated flue gas stream. Greater than 90% CO2 capture combined with 97% CO2 product purity was achieved throughout the test. Membrane contactor modules have been scaled from bench scale 2-inch diameter by 12-inch long (20 ft2 membrane surface area) modules to 4-inch diameter by 60-inch long pilot scale modules (165 ft2 membrane surface area). Pilot scale modules were tested in an integrated absorption/regeneration system for CO2 capture field tests at a coal-fired power plant (Midwest Generationís Will County Station located in Romeoville, IL). Absorption and regeneration contactors were constructed utilizing high performance super-hydrophobic, nano-porous PEEK membranes with CO2 gas permeance of 2,000 GPU and a 1,000 GPU, respectively. Field tests using aMDEA solvent achieved greater than 90% CO2 removal in a single stage. The absorption mass transfer coefficient was 1.2 (sec)-1, exceeding the initial target of 1.0 (sec)-1. This mass transfer coefficient is over one order of magnitude greater than that of conventional gas/liquid contacting equipment. The economic evaluation based on field tests data indicates that the CO2 capture cost associated with membrane contactor technology is $54.69 (Yr 2011$)/tonne of CO2 captured when using aMDEA as a solvent. It is projected that the DOEís 2025 cost goal of $40 (Yr 2011$)/tonne of CO2 captured can be met by decreasing membrane module cost and by utilizing advanced CO2 capture solvents. In the second stage of the field test, an advanced solvent, Hitachiís H3-1 was utilized. The use of H3-1 solvent increased mass transfer coefficient by 17% as compared to aMDEA solvent. The high mass transfer coefficient of H3-1 solvent combined with much more favorable solvent regeneration requirements, indicate that the projected savings achievable with membrane contactor process can be further improved. H3-1 solvent will be used in the next pilot-scale development phase. The integrated absorption/regeneration process design and high performance membrane contactors developed in the current bench-scale program will be used as the base technology for future pilot-scale development.

  2. The Evolution of the Federal Monitoring and Assessment Center

    SciTech Connect (OSTI)

    NSTec Aerial Measurement System


    The Federal Radiological Monitoring and Assessment Center (FRMAC) is a federal emergency response asset whose assistance may be requested by the Department of Homeland Security (DHS), the Department of Defense (DoD), the Environmental Protection Agency (EPA), the Nuclear Regulatory Commission (NRC), and state and local agencies to respond to a nuclear or radiological incident. It is an interagency organization with representation from the Department of Energyís National Nuclear Security Administration (DOE/NNSA), the Department of Defense (DoD), the Environmental Protection Agency (EPA), the Department of Health and Human Services (HHS), the Federal Bureau of Investigation (FBI), and other federal agencies. FRMAC, in its present form, was created in 1987 when the radiological support mission was assigned to the DOEís Nevada Operations Office by DOE Headquarters. The FRMAC asset, including its predecessor entities, was created, grew, and evolved to function as a response to radiological incidents. Radiological emergency response exercises showed the need for a coordinated approach to managing federal emergency monitoring and assessment activities. The mission of FRMAC is to coordinate and manage all federal radiological environmental monitoring and assessment activities during a nuclear or radiological incident within the United States in support of state,local, tribal governments, DHS, and the federal coordinating agency. Radiological emergency response professionals with the DOEís national laboratories support the Radiological Assistance Program (RAP), National Atmospheric Release Advisory Center (NARAC), the Aerial MeasuringSystem (AMS), and the Radiation Emergency Assistance Center/Training Site (REAC/TS). These teams support the FRMAC to provide: ? Atmospheric transport modeling ? Radiation monitoring ? Radiological analysis and data assessments ? Medical advice for radiation injuries In support of field operations, the FRMAC provides geographic information systems, communications, mechanical, electrical, logistics, and administrative support. The size of the FRMAC is tailored to the incident and is comprised of emergency response professionals drawn from across the federal government. State and local emergency response teams may also integrate their operations with FRMAC, but are not required to.

  3. Industry

    SciTech Connect (OSTI)

    Bernstein, Lenny; Roy, Joyashree; Delhotal, K. Casey; Harnisch, Jochen; Matsuhashi, Ryuji; Price, Lynn; Tanaka, Kanako; Worrell, Ernst; Yamba, Francis; Fengqi, Zhou; de la Rue du Can, Stephane; Gielen, Dolf; Joosen, Suzanne; Konar, Manaswita; Matysek, Anna; Miner, Reid; Okazaki, Teruo; Sanders, Johan; Sheinbaum Parado, Claudia


    This chapter addresses past, ongoing, and short (to 2010) and medium-term (to 2030) future actions that can be taken to mitigate GHG emissions from the manufacturing and process industries. Globally, and in most countries, CO{sub 2} accounts for more than 90% of CO{sub 2}-eq GHG emissions from the industrial sector (Price et al., 2006; US EPA, 2006b). These CO{sub 2} emissions arise from three sources: (1) the use of fossil fuels for energy, either directly by industry for heat and power generation or indirectly in the generation of purchased electricity and steam; (2) non-energy uses of fossil fuels in chemical processing and metal smelting; and (3) non-fossil fuel sources, for example cement and lime manufacture. Industrial processes also emit other GHGs, e.g.: (1) Nitrous oxide (N{sub 2}O) is emitted as a byproduct of adipic acid, nitric acid and caprolactam production; (2) HFC-23 is emitted as a byproduct of HCFC-22 production, a refrigerant, and also used in fluoroplastics manufacture; (3) Perfluorocarbons (PFCs) are emitted as byproducts of aluminium smelting and in semiconductor manufacture; (4) Sulphur hexafluoride (SF{sub 6}) is emitted in the manufacture, use and, decommissioning of gas insulated electrical switchgear, during the production of flat screen panels and semiconductors, from magnesium die casting and other industrial applications; (5) Methane (CH{sub 4}) is emitted as a byproduct of some chemical processes; and (6) CH{sub 4} and N{sub 2}O can be emitted by food industry waste streams. Many GHG emission mitigation options have been developed for the industrial sector. They fall into three categories: operating procedures, sector-wide technologies and process-specific technologies. A sampling of these options is discussed in Sections 7.2-7.4. The short- and medium-term potential for and cost of all classes of options are discussed in Section 7.5, barriers to the application of these options are addressed in Section 7.6 and the implication of industrial mitigation for sustainable development is discussed in Section 7.7. Section 7.8 discusses the sector's vulnerability to climate change and options for adaptation. A number of policies have been designed either to encourage voluntary GHG emission reductions from the industrial sector or to mandate such reductions. Section 7.9 describes these policies and the experience gained to date. Co-benefits of reducing GHG emissions from the industrial sector are discussed in Section 7.10. Development of new technology is key to the cost-effective control of industrial GHG emissions. Section 7.11 discusses research, development, deployment and diffusion in the industrial sector and Section 7.12, the long-term (post-2030) technologies for GHG emissions reduction from the industrial sector. Section 7.13 summarizes gaps in knowledge.

  4. Ground-Source Integrated Heat Pump for Near-Zero Energy Houses: Technology Status Report

    SciTech Connect (OSTI)

    Murphy, Richard W [ORNL; Rice, C Keith [ORNL; Baxter, Van D [ORNL; Craddick, William G [ORNL


    The energy service needs of a net-zero-energy house (ZEH) include space heating and cooling, water heating, ventilation, dehumidification, and humidification, depending on the requirements of the specific location. These requirements differ in significant ways from those of current housing. For instance, the most recent DOE buildings energy data (DOE/BED 2007) indicate that on average {approx}43% of residential buildings primary energy use is for space heating and cooling, vs. {approx}12% for water heating (about a 3.6:1 ratio). In contrast, for the particular prototype ZEH structures used in the analyses in this report, that ratio ranges from about 0.3:1 to 1.6:1 depending on location. The high-performance envelope of a ZEH results in much lower space heating and cooling loads relative to current housing and also makes the house sufficiently air-tight to require mechanical ventilation for indoor air quality. These envelope characteristics mean that the space conditioning load will be closer in size to the water heating load, which depends on occupant behavior and thus is not expected to drop by any significant amount because of an improved envelope. In some locations such as the Gulf Coast area, additional dehumidification will almost certainly be required during the shoulder and cooling seasons. In locales with heavy space heating needs, supplemental humidification may be needed because of health concerns or may be desired for improved occupant comfort. The U.S. Department of Energy (DOE) has determined that achieving their ZEH goal will require energy service equipment that can meet these needs while using 50% less energy than current equipment. One promising approach to meeting this requirement is through an integrated heat pump (IHP) - a single system based on heat pumping technology. The energy benefits of an IHP stem from the ability to utilize otherwise wasted energy; for example, heat rejected by the space cooling operation can be used for water heating. With the greater energy savings the cost of the more energy efficient components required for the IHP can be recovered more quickly than if they were applied to individual pieces of equipment to meet each individual energy service need. An IHP can be designed to use either outdoor air or geothermal resources (e.g., ground, ground water, surface water) as the environmental energy source/sink. Based on a scoping study of a wide variety of possible approaches to meeting the energy service needs for a ZEH, DOE selected the IHP concept as the most promising and has supported research directed toward the development of both air- and ground-source versions. This report describes the ground-source IHP (GS-IHP) design and includes the lessons learned and best practices revealed by the research and development (R&D) effort throughout. Salient features of the GS-IHP include a variable-speed rotary compressor incorporating a brushless direct current permanent magnet motor which provides all refrigerant compression, a variable-speed fan for the indoor section, a multiple-speed ground coil circuit pump, and a single-speed pump for water heating operation. Laboratory IHP testing has thus far used R-22 because of the availability of the needed components that use this refrigerant. It is expected that HFC R-410A will be used for any products arising from the IHP concept. Data for a variable-speed compressor that uses R-410A has been incorporated into the DOE/ORNL Mark VI Heat Pump Design Model (HPDM). HPDM was then linked to TRNSYS, a time-series-dependent simulation model capable of determining the energy use of building cooling and heating equipment as applied to a defined house on a sub-hourly basis. This provided a highly flexible design analysis capability for advanced heat pump equipment; however, the program also took a relatively long time to run. This approach was used with the initial prototype design reported in Murphy et al. (2007a) and in the business case analysis of Baxter (2007).