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Atmospheric histories and global emissions of the anthropogenic hydrofluorocarbons HFC-365mfc, HFC-245fa, HFC-227ea, and HFC-236fa  

E-Print Network [OSTI]

We report on ground-based atmospheric measurements and emission estimates of the four anthropogenic hydrofluorocarbons (HFCs) HFC-365mfc (CH[subscript 3]CF[subscript 2]CH[subscript 2]CF[subscript 3], 1,1,1,3,3-pentafluorobutane), ...

Rigby, Matthew


Adsorption of Hydrofluorocarbons HFC-134 and HFC-134A on X and Y Zeolites: Effect of Ion-Exchange on Selectivity and Heat of Adsorption  

E-Print Network [OSTI]

rapidly as worldwide refrigerator and air-conditioner production rises almost exponentially.1 A byproduct) is a hydrofluorocarbon coolant for refrigerators designated to replace the ozone-damaging chloro- fluorocarbons (CFCs

Siperstein, Flor R.


Recent increases in global HFC-23 emissions  

E-Print Network [OSTI]

of U.S. greenhouse gas emissions and sinks: 1990-2007, Rep.A. Lindley (2007), Global emissions of HFC-23 estimated to2009), Greenhouse Gas Emissions Data, http://unfccc.int/ghg_



HFC supermarket refrigeration demonstration. Phases 1 and 2  

SciTech Connect (OSTI)

The HFC Supermarket Refrigeration Demonstration tested and evaluated HFC refrigerants in a new Shop `n Save supermarket in Glens Falls, New York. This project included laboratory testing of HFC refrigerants for medium- and low-temperature application, the design of a supermarket refrigeration system to accommodate the new refrigerants, installation, start-up, and field monitoring.

Borhanian, H.; Rafuse, L.



Polyol esters as HFC-134a compressor lubricants  

SciTech Connect (OSTI)

A polyol ester-based lubricant has been applied to HFC-134a household refrigerator compressors, because of its good miscibility with HFC-134a refrigerant, and there is a possibility that it will be applied to automobile air conditions. For better performance, further improvements are needed regarding miscibility, lubricity and chemical stability of the lubricant, because such systems are often used under extreme conditions. This report discusses the required properties and ways to improve performance of polyol esters as HFC-134a compressor lubricants. 7 refs., 14 figs., 4 tabs.

Komatsuzaki, S.; Homma, Y.; Itoh, Y. [Hitachi Ltd. (Japan)] [and others



HFC-134A and HCFC-22 supermarket refrigeration demonstration and laboratory testing. Phase I. Final report  

SciTech Connect (OSTI)

Aspen Systems and a team of nineteen agencies and industry participants conducted a series of tests to determine the performance of HFC-134a, HCFC-22, and CFC-502 for supermarket application. This effort constitutes the first phase of a larger project aimed at carrying out both laboratory and demonstration tests of the most viable HFC refrigerants and the refrigerants they replace. The results of the Phase I effort are presented in the present report. The second phase of the project has also been completed. It centered on testing all viable HFC replacement refrigerants for CFC-502. These were HFC-507, HFC-404A, and HFC-407A. The latter results are published in the Phase II report for this project. As part of Phase I, a refrigeration rack utilizing a horizontal open drive screw compressor was constructed in our laboratory. This refrigeration rack is a duplicate of one we have installed in a supermarket in Clifton Park, NY.




Reduced-temperature processing and consolidation of ultra-refractory Ta4HfC5  

SciTech Connect (OSTI)

TaC, HfC, and WC powders were subjected to high-energy milling and hot pressing to produce Ta4HfC5, a composite of Ta(4)HfC5 + 30 vol.% WC, and a composite of Ta4HfC5 + 50 vol.% WC. Sub-micron powders were examined after four different milling intervals prior to hot pressing. XRD was used to verify proper phase formation. SEM, relative density, and hardness measurements were used to examine the resulting phases. Hot pressed compacts of Ta4HfC5 showed densification as high as 98.6% along with Vickers hardness values of 21.4 GPa. Similarly, Ta4HfC5 + 30 vol.% WC exhibited 99% densification with a Vickers hardness of 22.5 GPa. These levels of densification were achieved at 1500 degrees C, which is lower than any previously reported sintering temperature for Ta4HfC5. Microhardness values measured in this study were higher than those previously reported for Ta4HfC5. The WC additions to Ta4HfC5 were found to improve densification and increase microhardness. (C) 2013 Elsevier Ltd. All rights reserved.

Gaballa, Osama [Ames Laboratory; Cook, B. A. [TRI International; Russell, A. M. [Ames Laboratory



HFC-23 (CHF3) emission trend response to HCFC-22 (CHClF2) production and recent HFC-23 emission abatement measures  

E-Print Network [OSTI]

HFC-23 (also known as CHF3 [CHF subscript 3], fluoroform or trifluoromethane) is a potent greenhouse gas (GHG), with a global warming potential (GWP) of 14 800 for a 100-year time horizon. It is an unavoidable by-product ...

Miller, B. R.


Actinide extraction from simulated and irradiated spent nuclear fuel using TBP solutions in HFC-134a  

SciTech Connect (OSTI)

It was demonstrated that solutions of TBP-nitric acid adduct in liquid Freon HFC-134a (1.2 MPa, 25 deg. C) allowed for recovery of uranium with nearly the same effectiveness as supercritical CO{sub 2} at 30 MPa. At nearly quantitative recovery of U and Pu, a DF of ca. 10 can be attained on dissolution and extraction of simulated SNF samples. The possibility of recovery of actinides contained in cakes produced by oxide conversion of simulated and irradiated SNF with solutions of TBP and DBE in Freon HFC-134a was shown. (authors)

Shadrin, A.; Babain, V.; Kamachev, V.; Murzin, A.; Shafikov, D.; Dormidonova, A. [Khlopin Radium Institute, RPA, 28, 2-nd Murinskii ay., St-Petersburg (Russian Federation)



Evaluation of HFC-245ca for commercial use in low pressure chillers. Final report, Volume I  

SciTech Connect (OSTI)

Federal regulations banned the production of CFC-11 on January 1, 1996. HCFC-123, the only commercial alternative, will be limited to service applications after January 1, 2020 and will be eliminated from production on January 1, 2030. HFC-245ca has been identified as a potential replacement for CFC-11 in retrofit applications and for HCFC-123 in new chillers, but the marginal flammability of HFC-245ca is a major obstacle to its commercial use as a refrigerant in the United States. This report assesses the commercial viability of HFC-245ca based on its experimental performance in a direct drive low pressure centrifugal chiller exclusive of its flammability characteristics. Three different impeller diameters were tested in the chiller, with all impellers having identical discharge blade angles. Experimental work included tests in a 200 ton 3 stage direct drive chiller with 3 impeller sets properly sized for each of three refrigerants, CFC-11, HCFC-123, and HFC-245ca. The commercial viability assessment focused on both retrofit and new product performance and cost.

Keuper, E.F. [Trane Co., LaCrosse, WI (United States)] [Trane Co., LaCrosse, WI (United States)



An Experimental Investigaton of the Effect of Oil on Convective Heat Trasfer and Pressure Drop of a HFC-32/HRC-125 Mixture  

E-Print Network [OSTI]

The heat transfer coefficients and pressure drops of HCFC-22 and a 50% mass mixture of HFC-32/HFC-125 were experimentally measured under flow boiling conditions in a smooth tube. The refrigerants were flowed through an 8 mm diameter smooth tube...

McJimsey, Bert Ashford


Design and simulation of a heat pump for simultaneous heating and cooling using HFC or CO2  

E-Print Network [OSTI]

1 Design and simulation of a heat pump for simultaneous heating and cooling using HFC or CO2: +33 2 23 23 42 97 Fax: +33 2 23 23 40 51 ABSTRACT This article presents a Heat Pump for Simultaneous heat pump i in is isentropic mec mechanical nof without frosting o out r refrigerant S sublimation sc

Paris-Sud XI, Université de


Energy and global warming impacts of HFC refrigerants and emerging technologies: TEWI-III  

SciTech Connect (OSTI)

The use of hydrofluorocarbons (BFCs) which were developed as alternative refrigerants and insulating foam blowing agents to replace chlorofluorocarbons (CFCs) is now being affected by scientific investigations of greenhouse warming and questions about the effects of refrigerants and blowing agents on global warming. A Total Equivalent Warming Impact (TEWI) assessment analyzes the environmental affects of these halogenated working fluids in energy consuming applications by combining a direct effect resulting from the inadvertent release of HFCs to the atmosphere with an indirect effect resulting from the combustion of fossil fuels needed to provide the energy to operate equipment using these compounds as working fluids. TEWI is a more balanced measure of environmental impact because it is not based solely on the global warming potential (GWP) of the working fluid. It also shows the environmental benefit of efficient technologies that result in less CO{sub 2} generation and eventual emission to the earth`s atmosphere. The goal of TEWI is to assess total global warming impact of all the gases released to the atmosphere, including CO{sub 2} emissions from energy conversion. Alternative chemicals and technologies have been proposed as substitutes for HFCs in the vapor-compression cycle for refrigeration and air conditioning and for polymer foams in appliance and building insulations which claim substantial environmental benefits. Among these alternatives are: (1) Hydrocarbon (HC) refrigerants and blowing agents which have zero ozone depleting potential and a negligible global warming potential, (2) CO{sub 2} as a refrigerant and blowing agent, (3) Ammonia (NH{sub 3}) vapor compression systems, (4) Absorption chiller and heat pumping cycles using ammonia/water or lithium bromide/water, and (5) Evacuated panel insulations. This paper summarizes major results and conclusions of the detailed final report on the TEWI-111 study.

Sand, J.R.; Fischer, S.K.; Baxter, V.D.



A review of lubrication and preformance issues in refrigeration systems using an HFC (R-134a) refrigerant  

SciTech Connect (OSTI)

It has been considered critical for refrigerant and compressor lubricant to be miscible with each other over part of the range of operating conditions of refrigerant systems. Adequate miscibility, many believe, provides oil return to the compressor. Presently, synthetic polyol esters have been selected for use with HFC refrigerants, such as R-134a, which are considered appropriate alternatives to CFCs. The authors will review the mechanical issues in miscible vs non-miscible naphthenic hydrocarbon oil-based lubricants. Extensive lab, test stand and cabinet testing has been conducted and data will be presented which show responsible and predictable performance based on the chemical and physical properties of the lubricant and refrigerant. Many non-miscible systems show satisfactory performance with the proper selection of lubricant, additives and mechanical configuration. 3 refs., 3 figs., 5 tabs.

Reyes-Gavilan, J.; Eckard, A.; Flak, T.; Tritak, T. [Witco Corporation, Oakland, NJ (United States)



Heat transfer during condensation of HFC-134a and R-404A inside of a horizontal smooth and micro-fin tube  

SciTech Connect (OSTI)

In recent small and medium capacity refrigeration systems, the condenser tubes are provided with micro-fins from inside. The vapour refrigerant at the compressor outlet and the condenser inlet is in superheat state. As it advances in the condenser it is in two phases and at the outlet it is in sub cooled liquid. The heat transfer coefficient (HTC) during condensation of HFC-134a and R-404A in a smooth (8.56 mm ID) and micro-fin tubes (8.96 mm ID) are experimentally investigated. Different from previous studies, the present experiments are performed for various condensing temperatures, with superheating and sub cooling and using hermetically sealed compressor. The test runs are done at average saturated condensing temperatures ranging from 35 C to 60 C. The mass fluxes are between 90 and 800 kg m{sup -2} s{sup -1}. The experimental results indicate that the average HTC increases with mass flux but decreases with increasing condensing temperature for both smooth and micro-fin tubes. The average condensation HTCs of HFC-134a and R-404A for the micro-fin tubes were 1.5-2.5 and 1.3-2 times larger than that in smooth tube respectively. The HTCs for R-404A are less than that of HFC-134a. New correlations based on the data gathered during the experimentation for predicting condensation HTCs are proposed for wide range of operating conditions. (author)

Sapali, S.N. [Govt. College of Engineering, Department of Mechanical Engineering, Shivaji Nagar, Pune, Maharashtra 411 005 (India); Patil, Pradeep A. [AISSMS College of Engineering, Pune University, Mechanical Engineering Department, Kennedy Road, Near R.T.O., Pune, Maharashtra 411 001 (India)



Final Technical Report HFC Concrete: A Low-√?¬?√?¬?√?¬?√?¬≠√?¬?√?¬Ę√?¬?√?¬?√?¬?√?¬źEnergy, Carbon-√?¬?√?¬?√?¬?√?¬≠Dioxide-√?¬?√?¬?√?¬?√?¬≠Negative Solution for reducing Industrial Greenhouse Gas Emissions  

SciTech Connect (OSTI)

Solidia/CCSM received funding for further research and development of its Low Temperature Solidification Process (LTS), which is used to create hydrate-free concrete (HFC). LTS/HFC is a technology/materials platform that offers wide applicability in the built infrastructure. Most importantly, it provides a means of making concrete without Portland cement. Cement and concrete production is a major consumer of energy and source of industrial greenhouse gas (GHG) emissions. The primary goal of this project was to develop and commercialize a novel material, HFC, which by replacing traditional concrete and cement, reduces both energy use and GHG emissions in the built infrastructure. Traditional concrete uses Portland Cement (PC) as a binder. PC production involves calcination of limestone at {approx}1450 C, which releases significant amounts of CO{sub 2} gas to the atmosphere and consumes a large amount of energy due to the high temperature required. In contrast, HFC is a carbonate-based hydrate-free concrete (HFC) that consumes CO{sub 2} gas in its production. HFC is made by reaction of silicate minerals with CO{sub 2} at temperatures below 100 C, more than an order-of-magnitude below the temperature required to make PC. Because of this significant difference in temperature, it is estimated that we will be able to reduce energy use in the cement and concrete industry by up to 30 trillion Btu by 2020. Because of the insulating properties of HFC, we believe we will also be able to significantly reduce energy use in the Building sector, though the extent of this saving is not yet quantified. It is estimated that production of a tonne of PC-based concrete requires about 6.2 million Btu of energy and produces over 1 tonne of CO{sub 2} emissions (Choate, 2003). These can be reduced to 1.9 million Btu and 0.025 tonnes of CO{sub 2} emissions per tonne of HFC (with overall CO{sub 2}-negativity possible by increasing carbonation yield). In this way, by replacing PC-based concrete with HFC in infrastructure we can reduce energy use in concrete production by 70%, and reduce CO{sub 2} emissions by 98%; thus the potential to reduce the impact of building materials on global warming and climate change is highly significant. Low Temperature Solidification (LTS) is a breakthrough technology that enables the densification of inorganic materials via a hydrothermal process. The resulting product exhibits excellent control of chemistry and microstructure, to provide durability and mechanical performance that exceeds that of concrete or natural stone. The technology can be used in a wide range of applications including facade panels, interior tiles, roof tiles, countertops, and pre-cast concrete. Replacing traditional building materials and concrete in these applications will result in significant reduction in both energy consumption and CO{sub 2} emissions.

Dr. Larry McCandlish, Principal Investigator; Dr. Richard Riman, Co-Principal Investigator



Enhanced naphthenic refrigeration oils for household refrigerator systems  

SciTech Connect (OSTI)

Due to industry concerns about the successful employment of hydrofluorocarbon-immiscible hydrocarbon oils in refrigeration systems, enhanced naphthenic refrigeration oils have been developed. These products have been designed to be more dispersible with hydrofluorocarbon (HFC) refrigerants, such as R-134a, in order to facilitate lubricant return to the compressor and to ensure proper energy efficiency of the system. Bench tests and system performance evaluations indicate the feasibility of these oils for use in household refrigeration applications. Results of these evaluations are compared with those obtained with polyol esters and typical naphthenic mineral oils employed in chlorofluorocarbon (CFC) and hydrochlorofluorocarbon (HCFC) refrigeration applications.

Reyes-Gavilan, J.L.; Flak, G.T.; Tritcak, T.R. [Witco Corp., Oakland, NJ (United States); Barbour, C.B. [Americold, Cullman, AL (United States)




Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists'Montana.ProgramJulietip sheetK-4In 2013 many autoThis road map is a summary of-DOE



Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists'Montana.ProgramJulietip sheetK-4In 2013 many autoThis road map is a summary of-DOEForm



Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

7.104(d)(2) Yes No Is the requirement bundled? If yes, attach supporting documentation 9. Efforts made to locate sources within the last 12 months: YES NO Review...

Note: This page contains sample records for the topic "hfc hydrofluorocarbon hhs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


Recent increases in global HFC-23 emissions  

E-Print Network [OSTI]

Sustainability, Technical University Eindhoven, Eindhoven, Netherlands. Department of Physics and Astronomy, Bowdoin College,



Novel hydrofluorocarbon polymers for use as pellicles in 157 nm semiconductor photolithography: fundamentals of transparency  

E-Print Network [OSTI]

Pont Photomasks Inc., 4 Finance Dr., Danbury, CT 06810, USA c INEOS, Russian Academy of Sciences, Vavilova 28

Rollins, Andrew M.


Reducing the Carbon Footprint of Commercial Refrigeration Systems Using Life Cycle Climate Performance Analysis: From System Design to Refrigerant Options  

SciTech Connect (OSTI)

In this paper, Life Cycle Climate Performance (LCCP) analysis is used to estimate lifetime direct and indirect carbon dioxide equivalent gas emissions of various refrigerant options and commercial refrigeration system designs, including the multiplex DX system with various hydrofluorocarbon (HFC) refrigerants, the HFC/R744 cascade system incorporating a medium-temperature R744 secondary loop, and the transcritical R744 booster system. The results of the LCCP analysis are presented, including the direct and indirect carbon dioxide equivalent emissions for each refrigeration system and refrigerant option. Based on the results of the LCCP analysis, recommendations are given for the selection of low GWP replacement refrigerants for use in existing commercial refrigeration systems, as well as for the selection of commercial refrigeration system designs with low carbon dioxide equivalent emissions, suitable for new installations.

Fricke, Brian A [ORNL] [ORNL; Abdelaziz, Omar [ORNL] [ORNL; Vineyard, Edward Allan [ORNL] [ORNL



Growth of climate change commitments from HFC banks and emissions  

E-Print Network [OSTI]

Chlorofluorocarbons (CFCs) are the primary cause of ozone depletion, and they also contribute to global climate change. With the global phaseout of CFCs and the coming phaseout of hydrochlorofluorocarbons (HCFCs), the ...

Velders, G. J. M.


Passive Two-Phase Cooling of Automotive Power Electronics: Preprint  

SciTech Connect (OSTI)

Experiments were conducted to evaluate the use of a passive two-phase cooling strategy as a means of cooling automotive power electronics. The proposed cooling approach utilizes an indirect cooling configuration to alleviate some reliability concerns and to allow the use of conventional power modules. An inverter-scale proof-of-concept cooling system was fabricated, and tests were conducted using the refrigerants hydrofluoroolefin HFO-1234yf and hydrofluorocarbon HFC-245fa. Results demonstrated that the system can dissipate at least 3.5 kW of heat with 250 cm3 of HFC-245fa. An advanced evaporator design that incorporates features to improve performance and reduce size was conceived. Simulation results indicate its thermal resistance can be 37% to 48% lower than automotive dual side cooled power modules. Tests were also conducted to measure the thermal performance of two air-cooled condensers--plain and rifled finned tube designs. The results combined with some analysis were then used to estimate the required condenser size per operating conditions and maximum allowable system (i.e., vapor and liquid) temperatures.

Moreno, G.; Jeffers, J. R.; Narumanchi, S.; Bennion, K.



Energy and global warming impacts of next generation refrigeration and air conditioning technologies  

SciTech Connect (OSTI)

Significant developments have occurred in hydrofluorocarbon (HFC) and the application of ammonia and hydrocarbons as refrigerant working fluids since the original TEWI (Total Equivalent Warming Impact) report in 1991. System operating and performance data on alternative refrigerants and refrigeration technologies justify and updated evaluation of these new alternative refrigerants and competing technologies in well-characterized applications. Analytical and experimental results are used to show quantitative comparisons between HFCS, HFC blends, hydrocarbons, and ammonia, used as refrigerants. An objective evaluation is presented for commercial and near commercial non-CFC refrigerants/blowing agents and alternative refrigeration technologies. This information is needed for objective and quantitative decisions on policies addressing greenhouse gas emissions from refrigeration and air conditioning equipment. The evaluation assesses the energy use and global warming impacts of refrigeration and air conditioning technologies that could be commercialized during the phase out of HCFCS. Quantitative comparison TEWI for two application areas are presented. Opportunities for significant reductions in TEWI are seen with currently known refrigerants through improved maintenance and servicing practices and improved product designs.

Sand, J.R.; Fischer, S.K.; Baxter, V.D.



Two-Phase Flow of HCFC-22 and HFC-134a through Short Tube Orifices  

E-Print Network [OSTI]

and pressure conditions were those typically found in air-conditioner and heat pump applications. Effects of each operating parameters and short tube geometry on the flow rate were discussed and included in the modeling. Both an analytical and semi...

Yongchan, K.



Performance of a two-cycle refrigerator/freezer using HFC refrigerants  

SciTech Connect (OSTI)

A two-cycle 18 ft{sup 3} (0.51 m{sup 3}) refrigerator/freezer was tested utilizing American National Standards Institute/Association of Home Appliance Manufacturers (ANSI/AHAM) standards for energy consumption testing. A 34.9% energy consumption reduction was realized for a 1984 model refrigerator/freezer (1020 kWh original energy use). This paper presents a proven method of reducing the current Department of Energy (DOE) minimum energy-efficiency standards for refrigerator/freezers to the proposed year 2001 standards utilizing existing technology. For a top-mount, frost-free refrigerator/freezer having the above volume, the current DOE minimum energy standard is 770 kWh/year, and the proposed DOE year 2001 standard is 530 kWh/year (a 31% reduction). Therefore, some significant reductions may be obtained by implementing the modifications discussed in this paper into newer refrigerator/freezer models. The paper gives an overview of the modifications implemented by a Danish university on a US refrigerator/freezer and presents experimental performance testing results of the refrigerator/freezer. The modifications will cause the refrigerator/freezer to be more expensive, but the performance enhancements should offset cost. No cost analysis is presented in this paper, but a detailed cost analysis of a two-cycle refrigerator/freezer is contained in a 1993 US Environmental Protection Agency (EPA) report (EPA 1993). The refrigerator/freezer was tested using four refrigerants and compressors. Two compressors and refrigerants were tested in the freezer cycle, and four were tested in the fresh food cycle.

Baskin, E.; Delafield, F.R.



Elastohydrodynamic Lubrication with Polyolester Lubricants and HFC Refrigerants, Final Report, Volume 1  

SciTech Connect (OSTI)

The objective of this study was to investigate the film formation properties of refrigeration lubricants using the ultrathin film elastohydrodynamic (EHD) interferometry technique and to study the effects of refrigerants on film formation. Film thickness measurements were conducted as a function of lubricant viscosity, speed, temperature, and refrigerant concentration. Based on the EHD film thickness data, effective pressure-viscosity coefficients were calculated for the test fluids at different temperatures and the effects of refrigerants on pressure-viscosity properties were investigated.

Gunsel, Selda; Pozebanchuk, Michael



Compatibility of lubricant additives with HFC refrigerants and synthetic lubricants. Final report, Part 1  

SciTech Connect (OSTI)

Part one of this research provides manufacturers of components of air-conditioning and refrigeration equipment with a useful list of lubricant additives, sources, functional properties and chemical species. The list in part one is comprised of domestic lubricant additive suppliers and the results of a literature search that was specifically targeted for additives reported to be useful in polyolester chemistry.

Cavestri, R.C. [Imagination Resources, Inc., Dublin, OH (United States)



Elevated temperature ablation resistance of HfC particle-reinforced tungsten composites  

E-Print Network [OSTI]

C¬≠W was attributed to the low thermal conductivity, high oxidation resistance, and high melting point of the Hf melting points (e.g., 3440 ¬įC for W), high moduli of elasticity, good thermal shock resistances, and good torch was used to ablate the samples at high temperature. Ablation resistance improved with an in

Hong, Soon Hyung


Elastohydrodynamic Lubrication with Polyolester Lubricants and HFC Refrigerants, Final Report, Volume 2  

SciTech Connect (OSTI)

Lubrication properties of refrigeration lubricants were investigated in high pressure nonconforming contacts under different conditions of temperature, rolling speed, and refrigerant concentration. The program was based upon the recognition that the lubrication regime in refrigeration compressors is generally elastohydrodynamic or hydrodynamic, as determined by the operating conditions of the compressor and the properties of the lubricant. Depending on the compressor design, elastohydrodynamic lubrication conditions exist in many rolling and sliding elements of refrigeration compressors such as roller element bearings, gears, and rotors. The formation of an elastohydrodynamic film separating rubbing surfaces is important in preventing the wear and failure of compressor elements. It is, therefore, important to predict the elastohydrodynamic (EHD) performance of lubricants under realistic tribocontact renditions. This is, however, difficult as the lubricant properties that control film formation are critically dependent upon pressure and shear, and cannot be evaluated using conventional laboratory instruments. In this study, the elastohydrodynamic behavior of refrigeration lubricants with and without the presence of refrigerants was investigated using the ultrathin film EHD interferometry technique. This technique enables very thin films, down to less than 5 nm, to be measured accurately within an EHD contact under realistic conditions of temperature, shear, and pressure. The technique was adapted to the study of lubricant refrigerant mixtures. Film thickness measurements were obtained on refrigeration lubricants as a function of speed, temperature, and refrigerant concentration. The effects of lubricant viscosity, temperature, rolling speed, and refrigerant concentration on EHD film formation were investigated. From the film thickness measurements, effective pressure-viscosity coefficients were calculated. The lubricants studied in this project included two naphthenic mineral oils (NMO), four polyolesters (POE), and two polyvinyl ether (PVE) fluids. These fluids represented viscosity grades of ISO 32 and ISO 68 and are shown in a table. Refrigerants studied included R-22, R-134a, and R-410A. Film thickness measurements were conducted at 23 C, 45 C, and 65 C with refrigerant concentrations ranging from zero to 60% by weight.

Gunsel, Selda; Pozebanchuk, Michael



Experimental study of third (HFC) and fourth generation (HFO) refrigerants during flow boiling in singularities.  

E-Print Network [OSTI]

??La rťduction de charge de fluides frigorigŤnes dans les systŤmes de production de froid est un enjeu important s'inscrivant dans les politiques environnementales sur laÖ (more)

Padilla Gomez, Miguel David



Two-Phase Flow of Two HFC Refrigerant Mixtures Through Short Tube Orifices, Draft Final Report  

E-Print Network [OSTI]

The present study presents data for flow of two refrigerant mixtures through short tube orifices. The two mixtures were R3211251134a (23%/25%/52% on a mass percentage basis) and R321125 (50%/50%). The following presents results for the flow...

Payne, W. V.; O'Neal, D. L.



Global warming impacts of ozone-safe refrigerants and refrigeration, heating, and air-conditioning technologies  

SciTech Connect (OSTI)

International agreements mandate the phase-out of many chlorine containing compounds that are used as the working fluid in refrigeration, air-conditioning, and heating equipment. Many of the chemical compounds that have been proposed, and are being used in place of the class of refrigerants eliminated by the Montreal Protocol are now being questioned because of their possible contributions to global warming. Natural refrigerants are put forth as inherently superior to manufactured refrigerants because they have very low or zero global warming potentials (GWPs). Questions are being raised about whether or not these manufactured refrigerants, primarily hydrofluorocarbons (HFCs), should be regulated and perhaps phased out in much the same manner as CFCs and HCFCs. Several of the major applications of refrigerants are examined in this paper and the results of an analysis of their contributions to greenhouse warming are presented. Supermarket refrigeration is shown to be an application where alternative technologies have the potential to reduce emissions of greenhouse gases (GHG) significantly with no clear advantage to either natural or HFC refrigerants. Mixed results are presented for automobile air conditioners with opportunities to reduce GHG emissions dependent on climate and comfort criteria. GHG emissions for hermetic and factory built systems (i.e. household refrigerators/freezers, unitary equipment, chillers) are shown to be dominated by energy use with much greater potential for reduction through efficiency improvements than by selection of refrigerant. The results for refrigerators also illustrate that hydrocarbon and carbon dioxide blown foam insulation have lower overall effects on GHG emissions than HFC blown foams at the cost of increased energy use.

Fischer, S.; Sand, J.; Baxter, V.



E-Print Network 3.0 - absorber gadolinum comparative Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fluoropolymer; Hydrofluorocarbon; 157 nm; Photolithography; Optical absorbance Source: French, Roger H. - Department of Materials Science and Engineering, University of...


An Evaluation of the Environmental Impact of Different Commercial Supermarket Refrigeration Systems Using Low Global Warming Potential Refrigerants  

SciTech Connect (OSTI)

Commercial refrigeration systems consumed 1.21 Quads of primary energy in 2010 and are known to be a major source for refrigerant charge leakage into the environment. Thus, it is important to study the environmental impact of commercial supermarket refrigeration systems and improve their design to minimize any adverse impacts. The system s Life Cycle Climate Performance (LCCP) was presented as a comprehensive metric with the aim of calculating the equivalent mass of carbon dioxide released into the atmosphere throughout its lifetime, from construction to operation and destruction. In this paper, an open source tool for the evaluation of the LCCP of different air-conditioning and refrigeration systems is presented and used to compare the environmental impact of a typical multiplex direct expansion (DX) supermarket refrigeration systems based on three different refrigerants as follows: two hydrofluorocarbon (HFC) refrigerants (R-404A, and R-407F), and a low global warming potential (GWP) refrigerant (N-40). The comparison is performed in 8 US cities representing different climates. The hourly energy consumption of the refrigeration system, required for the calculation of the indirect emissions, is calculated using a widely used building energy modeling tool (EnergyPlus). A sensitivity analysis is performed to determine the impact of system charge and power plant emission factor on the LCCP results. Finally, we performed an uncertainty analysis to determine the uncertainty in total emissions for both R-404A and N-40 operated systems. We found that using low GWP refrigerants causes a considerable drop in the impact of uncertainty in the inputs related to direct emissions on the uncertainty of the total emissions of the system.

Beshr, Mohamed [University of Maryland, College Park; Aute, Vikrant [University of Maryland, College Park; Abdelaziz, Omar [ORNL; Fricke, Brian A [ORNL; Radermacher, Reinhard [University of Maryland, College Park



TEWI Analysis: Its Utility, Its Shortcomings, and Its Results  

SciTech Connect (OSTI)

The past decade has been a challenging time for the refrigeration and air conditioning industry worldwide. Provisions of the Montreal Protocol and its amendments require the phaseout of chlorofluorocarbon (CFC) and hydrochlorofluorocarbon (HCFC) compounds that have been used extensively as insulating foam blowing agents and refrigerants in refrigeration systems, heat pumps, and air conditioners. In response, hydrofluorocarbon (HFC) compounds were proposed, developed, and are starting to be used as the primary alternatives to CFCs and HCFCs. However, in 1997 under the Kyoto Protocol, industrialized nations have agreed to roll back emissions of HCFCs, carbon dioxide (CO*), and four other greenhouse gases which threaten to cause excessive global warming. The US. Department of Energy and the Alternative Fluorocarbon Environmental Acceptability Study (AFEAS) jointly sponsored research projects to identify the major applications of CFCs, HCFCs, and HFCs and to examine the impacts of these compounds and the energy use of applications employing these compounds on global warming. The five major uses of fluorocarbons based on sales were automobile air conditioning, supermarket refrigeration, unitary heat pumps and air conditioning, chillers for cooling large office buildings, and household refrigeration. Almost all of the refrigerants used in these applications are global warming gases, and if the refrigerant leaks out of the system during operation, is lost during maintenance or is not recovered when the system is scraped, it contributes to global warming. But, it is also true that the energy consumed by refrigeration and air conditioning systems, in the form of electricity or the direct combustion of fossil fuel, results in the release of CO*, the primary cause of atmospheric global warming.

Baxter, V.D.; Fischer, S.K.; Sand, J.R.



Global and regional emissions of HFC-125 (CHF[subscript 2]CF[subscript 3]) from in situ and air archive atmospheric observations at AGAGE and SOGE observatories  

E-Print Network [OSTI]

High-frequency, in situ observations from the Advanced Global Atmospheric Gases Experiment (AGAGE) and System for Observation of halogenated Greenhouse gases in Europe (SOGE) networks for the period 1998 to 2008, combined ...

O'Doherty, S.


Molecular Design Using Quantum Chemical Calculations for Property Estimation  

E-Print Network [OSTI]

techniques for molecular design. A simple hydrofluorocarbon refrigerant design example and a solvent design level information about any system can be predicted (e.g., molecular energies, electronic charge as the target property, motivated by an interest in chemically stable hydrofluorocarbon refrigerants. The second

Maranas, Costas

Note: This page contains sample records for the topic "hfc hydrofluorocarbon hhs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


Using Acid Number as a Leading Indicator of Refrigeration and Air Conditioning System Performance  

SciTech Connect (OSTI)

This report summarizes a literature review to assess the acidity characteristics of the older mineral oil and newer polyolester (POE) refrigeration systems as well as to evaluate acid measuring techniques used in other non-aqueous systems which may be applicable for refrigeration systems. Failure in the older chlorofluorocarbon/hydrochlorofluorocarbon (CFC/HCFC) / mineral oil systems was primarily due to thermal degradation of the refrigerant which resulted in the formation of hydrochloric and hydrofluoric acids. These are strong mineral acids, which can, over time, severely corrode the system metals and lead to the formation of copper plating on iron surfaces. The oil lubricants used in the older systems were relatively stable and were not prone to hydrolytic degradation due to the low solubility of water in oil. The refrigerants in the newer hydrofluorocarbon (HFC)/POE systems are much more thermally stable than the older CFC/HCFC refrigerants and mineral acid formation is negligible. However, acidity is produced in the new systems by hydrolytic decomposition of the POE lubricants with water to produce the parent organic acids and alcohols used to prepare the POE. The individual acids can therefore vary but they are generally C5 to C9 carboxylic acids. Organic acids are much weaker and far less corrosive to metals than the mineral acids from the older systems but they can, over long time periods, react with metals to form carboxylic metal salts. The salts tend to accumulate in narrow areas such as capillary tubes, particularly if residual hydrocarbon processing chemicals are present in the system, which can lead to plugging. The rate of acid production from POEs varies on a number of factors including chemical structure, moisture levels, temperature, acid concentration and metals. The hydrolysis rate of reaction can be reduced by using driers to reduce the free water concentration and by using scavenging chemicals which react with the system acids. Total acid number (TAN), which includes both mineral acids and organic acids, is therefore a useful indicator which can be used to monitor the condition of the system in order to perform remedial maintenance, when required, to prevent system failure. The critical TAN value is the acid level at which remedial action should be taken to prevent the onset of rapid acid formation which can result in system failure. The level of 0.05 mg KOH/g of oil was established for CFC/mineral oil systems based on analysis of 700 used lubricants from operating systems and failed units. There is no consensus within the refrigeration industry as to the critical TAN value for HFC/POE systems, however, the value will be higher than the CFC/mineral oil systems critical TAN value because of the much weaker organic acids produced from POE. A similar study of used POE lubricants should be performed to establish a critical TAN limit for POE systems. Titrimetric analysis per ASTM procedures is the most commonly used method to determine TAN values in lubricants in the refrigeration industry and other industries dealing with lubricating oils. For field measurements, acid test kits are often used since they provide rapid, semi-quantitative TAN results.

Dennis Cartlidge; Hans Schellhase



Natural Refrigerant (R-729) Heat Pump  

Energy Savers [EERE]

Manufactured in the U.S. 2 Problem Statement * Current commercial and industrial heat pumps - Poor coefficient of performance (COP) at low temperatures * HFC refrigerant...


Characterization Studies of Materials and Devices used for Electrochemical Energy Storage  

E-Print Network [OSTI]

for Nafion in hydrogen fuel cell applications is that thebe used to fabricate hydrogen fuel cell (HFC) membranes withmembranes for hydrogen and methanol fuel cells. J Memb Sci

Membreno, Daniel Eduardo



Grant Title: ALCOHOL RESEARCH EDUCATION PROJECT GRANTS (R25) Funding Opportunity Number: PAR -11-205. CFDA Number(s) 93.273.  

E-Print Network [OSTI]

-205. CFDA Number(s) 93.273. Agency/Department: Department of Health and Human Services (HHS), National

Farritor, Shane


Synthesis and Characterization of Single Crystalline Hafnium Carbide Nanowires  

E-Print Network [OSTI]

transition metal carbide (TMC) nanowires has been reported, no HfC nanowires have been successfully syntheSynthesis and Characterization of Single Crystalline Hafnium Carbide Nanowires Jinshi Yuan,,§ Han carbide (HfC) is the most refractory compound known to mankind. A catalyst-assisted chemical vapor deposi

Qin, Lu-Chang


Solubility, viscosity and density of refrigerant/lubricant mixtures  

SciTech Connect (OSTI)

This report presents results for low refrigerant concentration (70, 80, 90 and 100 weight percent lubricant) mixtures of the following fluids: CFC-12/ISO 32 naphthenic mineral oil, HCFC-22/ISO 32 naphthenic mineral oil, CFC-12/ISO 100 naphthenic mineral oil, HFC-134a/ISO 22 pentaerythritol ester mixed acid, HFC-134a/ISO 32 pentaerythritol ester mixed acid [number sign]1, HFC-134a/ISO 68 pentaerythritol ester mixed acid, HFC-134a/ISO 100 pentaerythritol ester mixed acid, HFC-134a/ISO 32 pentaerythritol ester mixed acid [number sign]2, HCFC-123/ISO 32 naphthenic mineral oil, HCFC-123/ISO 100 naphthenic mineral oil, HCFC-123/150 SUS alkylbenzene, HCFC-123/300 SUS alkylbenzene. These data have been reduced to engineering form and are presented in the form of a Daniel Chart. Equations are given along with statistical measures of goodness of fit.

Henderson, D.R.



Solubility, viscosity and density of refrigerant/lubricant mixtures. Quarterly technical progress report, 1 January--31 March 1993  

SciTech Connect (OSTI)

This report presents results for low refrigerant concentration (70, 80, 90 and 100 weight percent lubricant) mixtures of the following fluids: CFC-12/ISO 32 naphthenic mineral oil, HCFC-22/ISO 32 naphthenic mineral oil, CFC-12/ISO 100 naphthenic mineral oil, HFC-134a/ISO 22 pentaerythritol ester mixed acid, HFC-134a/ISO 32 pentaerythritol ester mixed acid {number_sign}1, HFC-134a/ISO 68 pentaerythritol ester mixed acid, HFC-134a/ISO 100 pentaerythritol ester mixed acid, HFC-134a/ISO 32 pentaerythritol ester mixed acid {number_sign}2, HCFC-123/ISO 32 naphthenic mineral oil, HCFC-123/ISO 100 naphthenic mineral oil, HCFC-123/150 SUS alkylbenzene, HCFC-123/300 SUS alkylbenzene. These data have been reduced to engineering form and are presented in the form of a Daniel Chart. Equations are given along with statistical measures of goodness of fit.

Henderson, D.R.



Crop and Soil Science Degree Checklist Name: ____________________________  

E-Print Network [OSTI]

and Soil Science Degree Checklist Name: ____________________________ ID Intensive (SOIL 325) (3) _______ HHS 231 ≠ Lifetime Fitness for Health (2. Global Issues (3) (*soil science electives meeting requirement) _______ Science

GrŁnwald, Niklaus J.


E-Print Network 3.0 - accident experimental facility Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: -Frederick and NCI- Frederick off-site facilities. C. DEFINITIONS NA D. PROCEDURES All accidents involving HHS... 1 - August 2009 REPORTINGINVESTIGATION OF VEHICLE...


Environmental Data Sheet ENVIRONMENTAL DATA SHEET Dell Inc.  

E-Print Network [OSTI]

, the customer should not rely upon this information in making decisions about electrical tolerances or otherwise) other than in cables and interconnect parts · CFCs (chlorofluorocarbons), HCFCs (hydrofluorocarbons in the Montreal Protocol annex A, B, or C is used in Dell's manufacturing plants. Additional Materials Information

Fiebig, Peter


Peter Bernath Department of Chemistry, University of YorkDepartment of Chemistry, University of York  

E-Print Network [OSTI]

- 12 11,000 CFC - 113 6,540 Carbon Tetrachloride 2,700 HCFC-142b, CCl4, CH3Cl, CF4, SF6, (HFC-134a), Carbon Tetrachloride 2,700 HCFC - 22 5,160 HCFC - 141b 2,250 (HFC-134a), F2CO, ClFCO, Cl2CO, HCl, HF Abad, et al., Ethane, ethyne and carbon monoxide concentrations in the upper troposphere and lower


Kiran Chandra Sapkota Livelihood strategies and vulnerability of urban poor  

E-Print Network [OSTI]

management of drinking water. 97.7 percent HHs have got the electricity and entertainment facilities, electric charge, etc. This study has tried to show five capital assets of urban poor in Khadi Pakha in local social institution but not represented in local government. Above 95 percent HHs involved

Richner, Heinz


abusing runaway adolescents: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Oelklaus, Kirsten; Petr, Chris 2001-11-01 8 From the Adolescent Trauma and Substance Abuse Committee of the National Child Traumatic Stress Network CiteSeer Summary: (HHS)....


Proceedings of the 1993 non-fluorocarbon insulation, refrigeration and air conditioning technology workshop  

SciTech Connect (OSTI)

Sessions included: HFC blown polyurethanes, carbon dioxide blown foam and extruded polystyrenes, plastic foam insulations, evacuated panel insulation, refrigeration and air conditioning, absorption and adsorption and stirling cycle refrigeration, innovative cooling technologies, and natural refrigerants. Selected papers have been indexed separately for inclusion in the Energy Science and Technology Database.

Not Available



Accelerated screening methods for determining chemical and thermal stability of refrigerant-lubricant mixtures part II: Experimental comparisons and verification of methods. Quarterly technical progress report, October 1, 1993--March 31, 1994  

SciTech Connect (OSTI)

The research reported herein continued to concentrate on in situ conductivity measurements for development into an accelerated screening method for determining the chemical and thermal stabilities of refrigerant/lubricant mixtures. The work reported herein was performed in two phases. In the first phase, sealed tubes were prepared with steel catalysts and mixtures of CFC-12, HCFC-22, HFC-134a, and HFC-32/HFC-134a (zeotrope 30:70) refrigerants with oils as described in ANSI/ASHRAE Method 97-1989. In the second phase of work, modified sealed tubes, with and without steel catalysts present, were used to perform in situ conductivity measurements on mixtures of CFC-12 refrigerant with oils. The isothermal in situ conductivity measurements were compared with conventional tests, e.g., color measurements, gas chromatography, and trace metals to evaluate the capabilities of in situ conductivity for determining the chemical and thermal stabilities of refrigerant/lubricant mixtures. Other sets of tests were performed using ramped temperature conditions from 175{degrees}C (347{degrees}F) to 205{degrees}C (401{degrees}F) to evaluate the capabilities of in situ conductivity for detecting the onset of rapid degradation in CFC-12, HCFC-22 and HFC-134a refrigerant mixtures with naphthenic oil aged with and without steel catalysts present.

Kauffman, R. [Dayton Univ., OH (United States). Research Inst.



Alternative Refrigerants for Building Air Conditioning  

E-Print Network [OSTI]

The majority of building air conditioning has traditionally been achieved with vapor compression technology using CFC-I I or HCFC-22 as refrigerant fluids. CFC-11 is being successfully replaced by HCFC-123 (retrofit or new equipment) or by HFC- 134a...

Bivens, D. B.



Evaluation of performance and composition shift of zeotropic mixtures in a Lorenz-Meutzner refrigerator/freezer  

SciTech Connect (OSTI)

Results from previous testing of this refrigerator/freezer using a 750 Btu/h compressor and several zeotropic mixtures revealed a performance enhancement up to 16% above that of hydrofluorocarbon R-134a. In the study presented in this paper, the Lorenz-Meutzner (LM) refrigerator/freezer equipped with a 1060 Btu/h compressor, two evaporators, and two intercoolers was experimentally tested in an environmental chamber according to the Association of Home Appliance Manufacturers/Department of Energy (AHAM/DOE) testing standards using several hydrofluoropropane-based zeotropic mixtures. The results are compared to baseline testing with R-134a and results obtained using the 750 Btu/h compressor. Hydrofluorocarbons R-245ca/R-152a performed comparably to R-134a. R-245ca/hydrocarbon R-270 (cyclopropane C{sub 3}H{sub 6}) outperformed all zeotropic mixtures and R-134a by at least 12.2 {+-} 0.7%. All refrigerants performed better using the larger compressor due to its inherently better efficiency. Refrigerant samples taken during refrigerator/freezer operation revealed substantial composition shifts (e.g., a 30% running composition shift of R-134a in the R-245ca/R-134a mixture). Sand et al. (1993) obtained an approximately 20% energy reduction using steady-state on-cycle energy consumption results; a comparison was made between chlorofluorocarbon R-12 and a hydrofluorocarbon R-32/hydrochlorofluorocarbon R-124 mixture. Lorenz and Meutzner (1975), originators of the Lorenz-Meutzner refrigerator/freezer design, state that the following parameters influence the optimum performance of the design: (1) heat exchanger size, (2) capillary tube length, (3) refrigerant charge, and (4) compressor size. This work investigates three of these parameters--capillary tube length, compressor size, and refrigerant charge.

Baskin, E.; Smith, N.D.; Delafield, F.R.; Tufts, M.W.



Empirical correlations for the modeling of R-134a flow through adiabatic capillary tubes  

SciTech Connect (OSTI)

This paper presents the results of an experimental study on capillary tubes commonly used as an expansion device in household refrigerators and freezers. The experiments were performed with the hydrofluorocarbon R-134a at different condensing pressures and levels of subcooling. The pressure and temperature profiles along the capillary tubes were measured in each test run. The data set was then used to evaluate the suitability of some equations previously reported in the literature for the single-phase friction factor, the underpressure of vaporization, and the entrance contraction loss factor. Correlations for the average and local two-phase friction factors were also developed based on the measured data.

Melo, C.; Neto, C.B.; Silva Ferreira, R.T. da



Performance Evaluation of A Household Refrigerator Using Cuo Nanoparticle Lubricant Mixture and Various Other Compressor Oils with Different Condenser Modes  

E-Print Network [OSTI]

Abstract:- The objective of this paper was to study the performance of household refrigerator having both air and water-cooled condenser, with 0.06 % mass fraction CuO nanoparticle-lubricant mixture and different types of compressor oils. The experiment was done using HFC134a as the refrigerant, CuO nanoparticles, Polyol-ester oil (POE) oil which is used as the conventional lubricant in the household refrigerator and SUNISO 3GS mineral oil as the lubricant alternatively. The result indicates that the refrigerator performance had improved while using CuO nanoparticle-lubricant mixture. The performance was also improved when HFC134a/SUNISO 3GS mineral oil system was used instead of HFC134a/POE oil system and there was also an enhancement when water-cooled condenser was used instead of the conventional air-cooled condenser on all load conditions. The HFC134a/CuO/SUNISO 3GS mineral oil system works normally and safely in the refrigerator. HFC134a/CuO/SUNISO 3GS mineral oil system reduced the energy consumption between 12 % and 19 % when compared with the HFC134a/POE oil system and between 9 % and 14 % while working with water-cooled condenser on various load conditions. There was also an enhancement in coefficient of performance (COP) when CuO nanoparticle-lubricant mixture was used instead of POE oil as the lubricant. The water cooled heat exchanger was designed and the system was modified by retrofitting it, along with the conventional air-cooled condenser by making a bypass line and thus the system can be utilized as a waste heat recovery unit. Experimental result shows that about 200 litres of hot water at a temperature of about 58ļC over a day can be generated. Techno economic analysis shows that the installation cost and running cost of the waste heat recovery system for a day is much lower than that of a conventional

Sreejith. K


Aging of Polyurethane Foam Insulation in Simulated Refrigerator Panels--Three-Year Results with Third-Generation Blowing Agents  

SciTech Connect (OSTI)

Laboratory data are presented on the effect of constant-temperature aging on the apparent thermal conductivity of polyurethane foam insulation for refrigerators and freezers. The foam specimens were blown with HCFC-141b and with three of its potential replacements--HFC-134a, HFC-245fa, and cyclopentane. Specimens were aged at constant temperatures of 90 F, 40 F, and -10 F. Thermal conductivity measurements were made on two types of specimens: full-thickness simulated refrigerator panels containing foam enclosed between solid plastic sheets, and thin slices of core foam cut from similar panels. Results are presented for the first three years of a multi-year aging study. Preliminary comparisons of measured data with predictions of a mathematical aging model are presented.

Wilkes, K.E.


Note: This page contains sample records for the topic "hfc hydrofluorocarbon hhs" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


Aging of polyurethane foam insulation in simulated refrigerator panels -- Initial results with third-generation blowing agents  

SciTech Connect (OSTI)

Laboratory data are presented on the effect of constant-temperature aging on the apparent thermal conductivity of polyurethane foam insulation for refrigerators and freezers. The foam specimens were blown with HCFC-141b and with three of its potential replacements -- HFC-134a, HFC-245fa, and cyclopentane. Specimens were aged at constant temperatures of 90 F, 40 F, and {minus}10 F. Thermal conductivity measurements were made on two types of specimens: full-thickness simulated refrigerator panels containing foam enclosed between solid plastic sheets, and thin slices of core foam cut from similar panels. Results are presented for about 250 days of aging for the core-foam specimens and for the first six months of aging for the full-thickness panels.

Wilkes, K.E.; Gabbard, W.A.; Weaver, F.J.



Aging of Polyurethane Foam Insulation in Simulated Refrigerator Panels--Two-Year Results with Third-Generation Blowing Agents  

SciTech Connect (OSTI)

Laboratory data are presented on the effect of constant-temperature aging on the apparent thermal conductivity of polyurethane foam insulation for refrigerators and freezers. The foam specimens were blown with HCFC-141b and with three of its potential replacements--HFC-134a, HFC-245fa, and cyclopentane. Specimens were aged at constant temperatures of 90 F, 40 F, and {minus}10 F. Thermal conductivity measurements were made on two types of specimens: full-thickness simulated refrigerator panels containing foam enclosed between solid plastic sheets, and thin slices of core foam cut from similar panels. Results are presented for the first two years of a multi-year aging study. Preliminary comparisons of measured data with predictions of a mathematical aging model are presented.

Wilkes, K.E.



Aging of Polyurethane Foam Insulation in Simulated Refrigerator Panels--One-Year Results with Third-Generation Blowing Agents  

SciTech Connect (OSTI)

Laboratory data are presented on the effect of constant-temperature aging on the apparent thermal conductivity of polyurethane foam insulation for refrigerators and freezers. The foam specimens were blown with HCFC-141b and with three of its potential replacements--HFC-134a, HFC-245fa, and cyclopentane. Specimens were aged at constant temperatures of 90 F, 40 F, and {minus}10 F. Thermal conductivity measurements were made on two types of specimens: full-thickness simulated refrigerator panels containing foam enclosed between solid plastic sheets, and thin slices of core foam cut from similar panels. Results are presented for the first year of a multi-year study for the full-thickness panels and for about 1-1/2 years of aging for the core-foam specimens.

Gabbard, W.A.; Weaver, F.J.; Wilkes, K.E.



Low GWP Working Fluid for High Temperature Heat Pumps  

E-Print Network [OSTI]

Low GWP Working Fluid for High Temperature Heat Pumps: DR-2 Chemical Stability at High Temperatures Temp Heat Pumps: DR-2 Very Low GWP AND Non-Flammable HFC-245fa DR-2 Chemical Formula CF3CH2CHF2 HFO 171.3 Pcr [MPa] 3.65 2.9 Kontomaris-DuPont; European Heat Pump Summit, Nuremberg, October 15th, 2013

Oak Ridge National Laboratory


Cooling season study and economic analysis of a desiccant cooling system  

E-Print Network [OSTI]

. This effect stems from using refrigerants which contain fluorocarbons. Fluorocarbons released into the atmosphere react with, and destroy, upper level ozone. As a result several alternative cooling processes have been proposed as replacements. One... of the detrimental effect fluorocarbons have on the environment, legislation has been passed banning their manufacture and sale. Refrigerants proposed as replacements, HFC 134a and HCFC-123, are more costly and less efficient than fluorocarbon , and their long...

Lee, James Howard



Comparison of global warming impacts of automobile air-conditioning concepts  

SciTech Connect (OSTI)

The global warming impacts of conventional vapor compression automobile air conditioning using HFC-134a are compared with the potential impacts of four alternative concepts. Comparisons are made on the basis of total equivalent warming impact (TEWI) which accounts for the effects of refrigerant emissions, energy use to provide comfort cooling, and fuel consumed to transport the weight of the air conditioning system. Under the most favorable assumptions on efficiency and weight, transcritical compression using CO{sub 2} as the refrigerant and adsorption cooling with water and zeolite beds could reduce TEWI by up to 18%rlative to HFC-134a compression air conditioning. Other assumptions on weight and efficiency lead to significant increases in TEWI relative to HFC-134a, and it is impossible to determine which set of assumptios is valid from existing data, Neither Stirling cycle or thermoelectric cooling will reduce TEWI relative to EFC-134a. Brief comments are also made concerning technical barriers that must be overcome for succesful development of the new technologies.




The Virial Method and the Classical Ellipsoids  

E-Print Network [OSTI]

Chandra completed his book Hydrodynamic and Hydromagnetic Stability (HHS) in 1960 and, as was his custom, turned his attention to a new area of research. He began to study general relativity at this time, and it appeared that this would be his

Norman R. Lebovitz


Family Fitness = Family Fun! Presented by  

E-Print Network [OSTI]

∑ What is holding you back? Source: http://www.cdc.gov/nchs/fastats/exercise.htm Summary Health Source: http://aspe.hhs.gov/health/reports/child_obesity/ #12;Exercise & play together! ∑ Model habits-ups), at least 3 days per week. ∑ Examples: Tree Climbing, Climbing on playgrounds, Gymnastics, Hiking, Rock


An investigation of pinch instabilities in solid sodium plasmas  

E-Print Network [OSTI]

e ie ene nacho|9 fox ylaxxDa con~ fine+sax, X'he meehoniea hg which bhs magnexie fiel@ Czaye a ylaemo otal he szyXBinee hp conBMGFinQ G chargse yaz'iiols aov9, ng in n CFOG vezas magnslio field zi The foxes cn hhs pazhiclo io given bp hho chars q...

Henson, Robert Maurice



Office of the Vice President for ResearchOffice of the Vice President for Research New Faculty OrientationNew Faculty Orientation  

E-Print Network [OSTI]

awardsSources of UB Research Expenditures resulting from awards Federal Agencies FY 2005*Federal Agencies 2005 RF Expenditures byFederal Agency DoD 8% DOE 1% HHS 62% NASA 1% NSF 18% Other 10% USDA 0% USDA Do,136,0003,136,000 PharmaceuticsPharmaceutics 2,564,0002,564,000 Electrical EngineeringElectrical Engineering 2

Krovi, Venkat


The University of Iowa College of Engineering Engineering Professional Development  

E-Print Network [OSTI]

City, IA Alcon Research Ltd. Irvine, CA Ankh Data Systems Iowa City, IA Athena GTX Des Moines, IA, IL TriCty Energy, LLC Keokuk, IA Tyson Foods Dakota Dunes, SD U.S. HHS Indian Health Service. Kansas City, MO China Agricultural University Beijing, China Civco Medical Instruments Kalona, IA Civco

Casavant, Tom


Recommendations for Use of Antiretroviral Drugs in Pregnant HIV-1-Infected Women for Maternal  

E-Print Network [OSTI]

Health and Interventions to Reduce Perinatal HIV Transmission in the United States Developed by the HHS Panel on Treatment of HIV-Infected Pregnant Women and Prevention of Perinatal Transmission--A Working: Panel on Treatment of HIV-Infected Pregnant Women and Prevention of Perinatal Transmission

Levin, Judith G.


National Youth Sports Program: Math/Science. Final report, [June 1, 1992--November 30, 1992  

SciTech Connect (OSTI)

NYSP, a partnership of NCAA, HHS, and colleges and universities, is aimed at sports instruction and physical activity for disadvantaged youth. In 1992, DOE joined in to add a mathematics/science component. Federal funds were used to conduct mathematics and science education components on a limited pilot basis at 16 sites. Recommendations for future improvements are given.

Not Available



In The News Tuesday, January 18, 2011  

E-Print Network [OSTI]

of the Arizona Cancer Center) 01/18/2011 East Valley Tribune View Clip FOR WHAT IS NEXT OUT OF TUCSON, WE Star - Online Text | View Clip State can't fill Giffords 'vacancy' 01/18/2011 Arizona Daily Sun Text CAUGHT BY VIDEO CAMERAS 01/18/2011 Baltimore Sun Text Arizona's University Medical Center Sues HHS Over

Arizona, University of


18/05/12 9:23 AMFloating robots launched by Berkeley | TPM Idea Lab Page 1 of 4http://idealab.talkingpointsmemo.com/2012/05/uc-berkeley-launches-swarm-of-100-floating-robots.php  

E-Print Network [OSTI]

& News Tips ­ ADVERTISEMENT ­ Where the oil industry answers your tough questions. Ask a question: I!" a protestor interrupted HHS Secretary ­ ADVERTISEMENT ­ ­ ADVERTISEMENT ­ 300x250 PB stations or manned routine and episodic pollution, the main challenge for the Delta system is the management of salinity


Synopsis of residential refrigerator/freezer alternative refrigerants evaluation  

SciTech Connect (OSTI)

The experimental testing on residential refrigerator/freezers (R/Fs) is summarized in this paper. R/F testing focused on two areas: alternative refrigerants and equipment configurations. The refrigerants evaluated consisted of single components, azeotropes, and zeotropes derived from hydrofluorocarbons (HFCs) and hydrocarbons (HCs). These refrigerants were evaluated in conventional and unconventional R/F designs. Major and minor design modifications were studied. Minor modifications consisted of various capillary tube lengths, door insulations, and compressors, while major modifications included two-evaporator and two-cycle R/F systems. Results obtained from testing the two-cycle system will be discussed in a later paper. This paper presents the experimental results of alternative technologies evaluated as replacements for ozone depleting chemicals.

Baskin, E. [Environmental Protection Agency, Research Triangle Park, NC (United States)



Lubricant return comparison of naphthenic and polyol ester oils in R-134a household refrigeration applications  

SciTech Connect (OSTI)

This paper presents mineral oils and polyol esters as possible lubricant options for domestic refrigeration applications employing R-134a as the heat exchange fluid. A performance comparison, based on data presented, is made between the mineral oils and polyol esters evaluated. To more closely examine lubricant return with N-70 and R-134a and ensure that the oil is not contributing to any deterioration in efficiency due to its accumulation in evaporators, a special test unit was designed with a difficult oil return configuration and its performance carefully monitored. Oil return with a hydrofluorocarbon-miscible polyol ester, R-133-O was also evaluated in this setup and its performance results compared to those obtained with the naphthenic refrigeration oil.

Reyes-Gavilan, J.L.; Flak, G.T.; Tritcak, T.R. [Witco Corp., Oakland, NJ (United States)



Solubility, viscosity and density of refrigerant/lubricant mixtures. Quarterly technical progress report, 1 October--31 December 1992  

SciTech Connect (OSTI)

This report presents results on low refrigerant concentration (70, 80, 90, and 100 weight percent lubricant) mixtures of the following fluids: CFC-12/ISO 32 naphthenic mineral oil; HCFC-22/ISO 32 naphthenic mineral oil; and HFC-134a/ISO 32 pentaerythritol ester mixed acid. These data have been reduced to engineering form and are presented in the form of a Daniel Chart. Scatter diagrams are given for the first fluid listed above, with the intent of illustrating the quality of data as well as providing the rationale for selecting the particular functional forms chosen to represent the experimental data. Equations are given along with statistical measures of goodness of fit.

Henderson, D.R.



Solubility, viscosity and density of refrigerant/lubricant mixtures  

SciTech Connect (OSTI)

This report presents results on low refrigerant concentration (70, 80, 90, and 100 weight percent lubricant) mixtures of the following fluids: CFC-12/ISO 32 naphthenic mineral oil; HCFC-22/ISO 32 naphthenic mineral oil; and HFC-134a/ISO 32 pentaerythritol ester mixed acid. These data have been reduced to engineering form and are presented in the form of a Daniel Chart. Scatter diagrams are given for the first fluid listed above, with the intent of illustrating the quality of data as well as providing the rationale for selecting the particular functional forms chosen to represent the experimental data. Equations are given along with statistical measures of goodness of fit.

Henderson, D.R.



Supermarket with Ground Coupled Carbon Dioxide Refrigeration Plant  

E-Print Network [OSTI]

refrigeration remains the last big subsector and the strongest emission source of the fluorinated hydrocarbons (HFC) in Germany? - Kauffeld [4] About 65 % of the cooling needs in Germany for frozen and refrigerated food products ? over 50.000 GWh.../a [2] In 2011, 72.4 % of the sales share of food retail industry realized in discounters and supermarkets in Germany [1] Supermarket: ? 600 ? 2.000 kWh/m2.a (PE) [3] Normal building: 200 ? 400 kWh/m2.a (PE) [4] [1] EHI retail institute 2012...

Rehault, N.


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Subject:Informal Notice about Potential Lapse in Appropriated Funds Date:Thu, 26 Sep 2013 21:51:09 +0000  

E-Print Network [OSTI]

:51:09 +0000 From:NIH-Alert (NIH/OD) nih_alert@OD.NIH.GOV> Reply-To:NIH-Alert (NIH/OD) nih_alert@OD.NIH.GOV> To:NIH-ALERT@LIST.NIH.GOV> September 26, 2013 Dear Grantee: As you are aware, the Government Fiscal that will be affected by a government shutdown. As a result, if there is a lapse in funding, HHS' NIH staff

Eichler, Evan


NIH SBIR/STTR Program Andrea Sawczuk, DDS, PhD  

E-Print Network [OSTI]

NIH SBIR/STTR Program Andrea Sawczuk, DDS, PhD Health Scientist Administrator Division of Clinical, MD 20892-4874 Phone: 301-435-0792 e-mail: sawczuka@mail.nih.gov #12;· SBIR: Small Business Innovation and research institutions #12;· DOD SBIR/STTR (1.4B) · HHS(NIH) SBIR/STTR (717M) ­ SBIR = 2.6% of NIH budget

Nguyen, Danh


The LiveWire Project final report  

SciTech Connect (OSTI)

Utilities across the US have begun pilot testing a variety of hardware and software products to develop a two-way communications system between themselves and their customers. Their purpose is to reduce utility operating costs and to provide new and improved services for customers in light of pending changes in the electric industry being brought about by deregulation. A consortium including utilities, national labs, consultants, and contractors, with the support of the Department of Energy (DOE) and the Electric Power Research Institute (EPRI), initiated a project that utilized a hybrid fiber-coax (HFC) wide-area network integrated with a CEBus based local area network within the customers home. The system combined energy consumption data taken within the home, and home automation features to provide a suite of energy management services for residential customers. The information was transferred via the Internet through the HFC network, and presented to the customer on their personal computer. This final project report discusses the design, prototype testing, and system deployment planning of the energy management system.

Brown, C.D.; Nelson, T.T. [Enova Technology, San Diego, CA (United States); Kelly, J.C.; Dominguez, H.A. [Paragon Consulting Services, La Verne, CA (United States)



Aging of polyurethane insulation foamed with second- and third-generation blowing agents  

SciTech Connect (OSTI)

Results are presented on two studies of the effect of aging on the apparent thermal conductivity of polyurethane foam insulation for refrigerators. Both studies are cooperative projects between the Oak Ridge National Laboratory and the Appliance Research Consortium. The first study has been ongoing for four years and involves evaluation of second generation blowing agents: HCFC-141b and HCFC-142/22 blend with CFC-11 for comparison. The second study has recently started and involves third generation blowing agents: HFC-134a, HFC-245fa. and cyclopentane with HCFC-141b for comparison. Both studies consist of periodic thermal measurements on panels made with solid steel and/or plastic skins and a core of foam to simulate refrigerator walls, and measurements on thin slices with cut faces to characterize the core foam. Laboratory data are presented on four years of aging of panels containing second generation blowing agents. Preliminary data are presented for the third generation blowing agents. The data on panels are compared with predictions of computer models of foam aging.

Wilkes, K.E.; Gabbard, W.A.; Weaver, F.J.



Thermodynamic Prediction of Compositional Phases Confirmed by Transmission Electron Microscopy on Tantalum-Based Alloy Weldments  

SciTech Connect (OSTI)

Tantalum alloys have been used by the U.S. Department of Energy as structural alloys for radioisotope based thermal to electrical power systems since the 1960s. Tantalum alloys are attractive for high temperature structural applications due to their high melting point, excellent formability, good thermal conductivity, good ductility (even at low temperatures), corrosion resistance, and weldability. Tantalum alloys have demonstrated sufficient high-temperature toughness to survive prolonged exposure to the radioisotope power-system working environment. Typically, the fabrication of power systems requires the welding of various components including the structural members made of tantalum alloys. Issues such as thermodynamics, lattice structure, weld pool dynamics, material purity and contamination, and welding atmosphere purity all potentially confound the understanding of the differences between the weldment properties of the different tantalum-based alloys. The objective of this paper is to outline the thermodynamically favorable material phases in tantalum alloys, with and without small amounts of hafnium, during and following solidification, based on the results derived from the FactSage(c) Integrated Thermodynamic Databank. In addition, Transition Electron Microscopy (TEM) data will show for the first time, the changes occurring in the HfC before and after welding, and the data will elucidate the role HfC plays in pinning grain boundaries.

Moddeman, William E.; Birkbeck, Janine C. [BWXT Pantex, Amarillo, Texas 79120-0020 (United States); Barklay, Chadwick D.; Kramer, Daniel P. [University of Dayton Research Institute, Dayton OH 45469-0102 (United States); Miller, Roger G.; Allard, Lawrence F. [Oak Ridge National Laboratory, Oak Ridge, TN 37831-6064 (United States)



The design of a cathode to operate in an oxygen-rich environment  

SciTech Connect (OSTI)

The primary problem with Hall plasma accelerator operation on oxygen is poor cathode performance and short lifetime. The primary problem with micro Hall thrusters is the absence of a stable low power cathode. Cathodes traditionally used for both applications employ thermionic emitters which are not efficient and which are easily oxidized in an oxygen-rich environment. The field emitter cathode presented in this report has the potential of filling both vacancies since it does not require a high-power heater and can be scaled down with the size of the thruster. The advantages to using Hf and HfC as emitting materials are low work functions and high resistance to oxygen poisoning. Preliminary investigations proved that HfC emitters can operate in 7.6 mTorr oxygen pressure environments. The initial cathode design employs an electrostatic lens that also acts as an ion filter to prevent thruster ions from bombarding the field emitters while decelerating the electron beam and keeping it focused to ensure efficient performance. Electron trajectories through the cathode and ion filtering capabilities are presented in this report as predicted by the charged particle code, MAGIC.

Marrese, Colleen M.; Gallimore, Alec D.; Mackie, William A.; Evans, David E. [Plasmadynamic and Electric Propulsion Lab., University of Michigan Dept. of Aerospace Engineering FXB Building, 1320 Beal Ann Arbor, Michigan 48109-2118 (United States); Linfield Research Institute 900 Baker St. McMinnville, Oregon 97128-6894 (United States)



Delocalization and hybridization enhance the magnetocaloric effect in Ni2Mn0.75Cu0.25Ga  

SciTech Connect (OSTI)

In view of the looming energy crisis facing our planet, attention increasingly focuses on materials potentially useful as a basis for energy saving technologies. The discovery of giant magnetocaloric (GMC) compounds - materials that exhibit especially large changes in temperature as the externally applied magnetic field is varied - is one such compound 1. These materials have potential for use in solid state cooling technology as a viable alternative to existing gas based refrigeration technologies that use choro-fluoro - and hydro-fluoro-carbon chemicals known to have a severe detrimental effect on human health and environment 2,3. Examples of GMC compounds include Gd5(SiGe)4 4, MnFeP1-xAsx 5 and Ni-Mn-Ga shape memory alloy based compounds 6-8. Here we explain how the properties of one of these compounds (Ni2MnGa) can be tuned as a function of temperature by adding dopants. By altering the free energy such that the structural and magnetic transitions coincide, a GMC compound that operates at just the right temperature for human requirements can be obtained 9. We show how Cu, substituted for Mn, pulls the magnetic transition downwards in temperature and also, counterintuitively, increases the delocalization of the Mn magnetism. At the same time, this reinforces the Ni-Ga chemical bond, raising the temperature of the martensite-austenite transition. At 25percent doping, the two transitions coincide at 317 K.

Roy, Sujoy; Blackburn, E.; Valvidares, S. M.; Fitzsimmons, M. R.; Vogel, Sven C.; Khan, M.; Dubenko, I.; Stadler, S.; Ali, N.; Sinha, S. K.; Kortright, J. B.



Emissions of greenhouse gases in the United States 1995  

SciTech Connect (OSTI)

This is the fourth Energy Information Administration (EIA) annual report on US emissions of greenhouse gases. This report presents estimates of US anthropogenic (human-caused) emissions of carbon dioxide, methane, nitrous oxide, and several other greenhouse gases for 1988 through 1994. Estimates of 1995 carbon dioxide, nitrous oxide, and halocarbon emissions are also provided, although complete 1995 estimates for methane are not yet available. Emissions of carbon dioxide increased by 1.9% from 1993 to 1994 and by an additional 0.8% from 1994 to 1995. Most carbon dioxide emissions are caused by the burning of fossil fuels for energy consumption, which is strongly related to economic growth, energy prices, and weather. The US economy grew rapidly in 1994 and slowed in 1995. Estimated emissions of methane increased slightly in 1994, as a result of a rise in emissions from energy and agricultural sources. Estimated nitrous oxide emissions increased by 1.8% in 1995, primarily due to increased use of nitrogen fertilizers and higher output of chemicals linked to nitrous oxide emissions. Estimated emissions of hydrofluorocarbons (HFCs) and perfluorocarbons (PFCs), which are known to contribute to global warming, increased by nearly 11% in 1995, primarily as a result of increasing substitution for chlorofluorocarbons (CFCs). With the exception of methane, the historical emissions estimates presented in this report are only slightly revised from those in last year`s report.




Effects of Water in Synthetic Lubricant Systems and Clathrate Formation: A Literature Search and Review  

SciTech Connect (OSTI)

An extensive literature search and a confidential survey were critically analyzed to determine the effects of water on the stability of hydrofluorocarbon/synthetic lubricant systems and to identify key areas requiring further investigation. Following are highlights from the analysis: Clathrate hydrates are solid solutions formed when water molecules are linked through hydrogen bonding creating cavities that can enclose various guest molecules from hydrate formers, such as hydrofluorocarbons R-32, R-125, R-134a, R-407C and R-410A. The four methods for preventing clathrate formation were drying the gas, heating it, reducing its pressure, or using inhibitors. The hydrolysis of polyolester lubricants was mostly acid-catalyzed and its reaction rate constant typically followed the Arrhenius equation of an activated process. Hydrolytic stability improved with hindered molecular structures, and with the presence of acid catcher additives and desiccants. Water vapor can effect the adsorption of long-chain fatty acids and the chemistry of formation of protective oxide film. However, these effects on lubrication can be either positive or negative. Fifty to sixty percent of the moisture injected into an air-conditioning system remained in the refrigerant and the rest mixed with the compressor oil. In an automotive air-conditioning system using R-134a, ice would form at 0 C evaporating temperature when the water content in the vapor refrigerant on the low-pressure side was more than 350 ppm. Moisture would cause the embrittlement of polyethylene terephthalate and the hydrolysis of polyesters, but would reduce the effect of amine additives on fluoroelastomer rubbers. The reactions of water with refrigerants and lubricants would cause formicary and large-pit corrosion in copper tubes, as well as copper plating and sludge formation. Moreover, blockage of capillary tubes increased rapidly in the presence of water. Twenty-four companies responded to the survey. From the responses, the water concentrations specified and expected for different refrigerant/lubricant systems varied depending on the products, their capacities and applications, and also on the companies. Among the problems associated with high moisture level, lubricant breakdown was of greatest concern, followed by acid formation, compressor failure and expansion valve sticking. The following research topics are suggested: 1. The air-conditioning and refrigeration industry needs to measure and record the water content and total acid number of the lubricant of newly installed systems as well as operating systems that are shutdown for service or repair. The reason for the shutdown needs to be documented. A database can then be established to correlate water content with type and cause of breakdown. 2. Detailed studies on the distribution of water in refrigeration and air-conditioning systems should be conducted to pinpoint problem areas associated with free water. 3. Research is needed to validate the current theories and mechanisms of formicary corrosion. Corrosion inhibitors need to be developed. 4. The conditions for clathrate formation and decomposition of other alternative refrigerants, such as R-23, R-41, R-116, R-125, R-143a, R-404A and R-507C, and water should be determined to avoid possible problems associated with tube plugging. The mechanism by which water facilitates or hinders lubrication needs to be studied.

Rohatgi, Ngoc Dung T.



Toxicity of trifluoroacetate to aquatic organisms  

SciTech Connect (OSTI)

As a result of the atmospheric degradation of several hydrofluorocarbons and hydrochlorofluorocarbons, trifluoroacetate (TFA) will be formed. Through precipitation, TFA will enter aquatic ecosystems. To evaluate the impact on the aquatic environment, an aquatic toxicity testing program was carried out with sodium trifluoroacetate (NaTFA). During acute toxicity tests, no effects of NaTFA on water fleas (Daphnia magna) and zebra fish (Danio retrio) were found at a concentration of 1,200 mg/L. A 7-d study with duckweed (Lemna gibba Ge) revealed a NOEC of 300 mg/L. On the basis of the results of five toxicity tests with Selenastrum capricornutum, they determined a NOEC of 0.12 mg/L. However, algal toxicity tests with NaTFA and Chlorella vulgaris, Scenedesmus subspicatus, Chlamydomonas reinhardtii, Dunaliella tertiolecta, Eugelan gracilis, Phaeodactylum tricornutum, Navicula pelliculosa, Skeletonema costatum, Anabaena flos-aquae, and Microcystis aeruginosa resulted in EC50 values that were all higher than 100 mg/L. The toxicity of TFA to S. capricornutum could be due to metabolic defluorination to monofluoroacetate (MFA), which is known to inhibit the citric acid cycle. A toxicity test with MFA and S. capricornutum revealed it to be about three orders of magnitude more toxic than TFA. However, a bioactivation study revealed that defluorination of TFA was less than 4%. On the other hand, S. capricornutum exposed to a toxic concentration of NaTFA showed a recovery of growth when citric acid was added, suggesting that TFA (or a metabolite of TFA) interferes with the citric acid cycle. A recovery of the growth of S. capricornutum was also found when TFA was removed from the test solutions. Therefore, TFA should be considered algistatic and not algicidic for S. capricornutum. On the basis of the combined results of the laboratory tests and a previously reported semi-field study, they can consider a TFA concentration of 0.10 mg/L as safe for the aquatic ecosystem.

Berends, A.G.; Rooij, C.G. de [Solvay S.A., Brussels (Belgium); Boutonnet, J.C. [Elf Atochem, Levallois-Perret (France); Thompson, R.S. [Zeneca Ltd., Devon (United Kingdom). Brixham Environmental Lab.



The Climate Change Action Plan: Technical supplement  

SciTech Connect (OSTI)

This Technical Annex documents the assumptions and parameters used in developing the supporting analysis for the Climate Change Action Plan (the Plan) issued by President Clinton on October 19, 1993. The Annex is intended to meet the needs of independent energy and environmental analysts who wish to better understand the Plan, its analytical underpinnings, and the events that need to transpire for the emissions reductions called for in the Plan to be realized. The Plan documented in this Annex reflects the outcome of a wide-ranging effort by Government agencies and interested members of the public to develop and implement actions that can reduce net greenhouse gas emissions in the year 2000 to their aggregate 1990 level. Based on agency and public input, the Climate Change Mitigation Group, chaired by the White House Office on Environmental Policy, developed the Plan`s content. Many of the actions called for in the Plan are now underway, while others are in advanced planning pending congressional action on the fiscal year 1995 budget. The analysis supporting the Plan represents the results of an interagency effort. The US Department of Energy (DOE) was responsible for the integrated analysis of energy-related options, based on the analysis of individual energy-related options by DOE, the US Environmental Protection Agency (EPA), and the US Department of Transportation (DOT). EPA led in providing analysis for actions related to methane, hydrofluorocarbons, and perfluorocarbons. The US Department of Agriculture (USDA) led the analysis of carbon sequestration actions and cooperated with EPA in the analysis of actions to reduce nitrous oxide emissions.

Not Available



Demonstration of High Efficiency Elastocaloric Cooling with Large Delta- T Using NiTi Wires  

SciTech Connect (OSTI)

Vapor compression (VC) is by far the most dominant technology for meeting all cooling and refrigeration needs around the world. It is a mature technology with the efficiency of modern compressors approaching the theoretical limit, but its envi-ronmental footprint remains a global problem. VC refrigerants such as hydrochlo-roflurocarbons (HCFCs) and hydrofluorocarbons (HFCs) are a significant source of green house gas (GHG) emissions, and their global warming potential (GWP) is as high as 1000 times that of CO2. It is expected that building space cooling and re-frigeration alone will amount to {approx} 5% of primary energy consumption and {approx}5% of all CO2 emission in U.S. in 2030 . As such, there is an urgent need to develop an al-ternative high-efficiency cooling technology that is affordable and environmentally friendly. Among the proposed candidates, magnetocaloric cooling (MC) is currently received a lot of attention because of its high efficiency. However, MC is inherently expensive because of the requirement of large magnetic field and rare earth materi-als. Here, we demonstrate an entirely new type of solid-state cooling mechanism based on the latent heat of reversible martensitic transformation. We call it elasto-caloric cooling (EC) after the superelastic transformation of austenite it utilizes. The solid-state refrigerant of EC is cost-effective, and it completely eliminates the use of any refrigerants including HCFCs/HFCs. We show that the COP (coefficient of per-formance) of a jugular EC with optimized materials can be as high as > 10 with measured {Delta}T of 17 C.

Cui, Jun; Wu, Yiming; Muehlbauer, Jan; Hwang, Yunho; Radermacher, Reinhard; Fackler, Sean; Wuttig, Manfred; Takeuchi, Ichiro



DOE Hanford Network Upgrades and Disaster Recovery Exercise Support the Cleanup Mission Now and into the Future  

SciTech Connect (OSTI)

In 2013, the U.S. Department of Energy's (DOE) Hanford Site, located in Washington State, funded an update to the critical network infrastructure supporting the Hanford Federal Cloud (HFC). The project, called ET-50, was the final step in a plan that was initiated five years ago called "Hanford's IT Vision, 2015 and Beyond." The ET-50 project upgraded Hanford's core data center switches and routers along with a majority of the distribution layer switches. The upgrades allowed HFC the network intelligence to provide Hanford with a more reliable and resilient network architecture. The culmination of the five year plan improved network intelligence and high performance computing as well as helped to provide 10 Gbps capable links between core backbone devices (10 times the previous bandwidth). These improvements allow Hanford the ability to further support bandwidth intense applications, such as video teleconferencing. The ET-50 switch upgrade, along with other upgrades implemented from the five year plan, have prepared Hanford's network for the next evolution of technology in voice, video, and data. Hand-in-hand with ET-50's major data center outage, Mission Support Alliance's (MSA) Information Management (IM) organization executed a disaster recovery (DR) exercise to perform a true integration test and capability study. The DR scope was planned within the constraints of ET-50's 14 hour datacenter outage window. This DR exercise tested Hanford's Continuity of Operations (COOP) capability and failover plans for safety and business critical Hanford Federal Cloud applications. The planned suite of services to be tested was identified prior to the outage and plans were prepared to test the services ability to failover from the primary Hanford data center to the backup data center. The services tested were: Core Network (backbone, firewall, load balancers); Voicemail; Voice over IP (VoIP); Emergency Notification; Virtual desktops; and, Select set of production applications and data. The primary objective of the exercise was to test COOP around the emergency operations at Hanford to provide information on capabilities and dependencies of the current system to insure improved focus of emergency, safety and security capacity in a disaster situation. The integration of the DR test into the ET-50 project allowed the testing of COOP at Hanford and allowed the lessons learned to be defined. These lessons learned have helped improve the understanding of Hanford's COOP capabilities and will be critical for future planning. With the completion of the Hanford Federal Cloud network upgrades and the disaster recovery exercise, the MSA has a clearer path forward for future technology implementations as well as network improvements to help shape the usability and reliability of the Hanford network in support of the cleanup mission.

Eckman, Todd J. [Mission Support Alliance, Richland, WA (United States); Hertzel, Ali K. [Lockheed Martin Services, Inc. (United States); Lane, James J. [Lockheed Martin - Information Systems and Global Solutions (United States)



Properties and Cycle Performance of Refrigerant Blends Operating Near and Above the Refrigerant Critical Point, Task 1: Refrigerant Properties  

SciTech Connect (OSTI)

The main goal of this project was to investigate and compare the performance of an R410A air conditioner to that of an R22 air conditioner, with specific interest in performance at high ambient temperatures at which the condenser of the R410A system may be operating above the refrigerant's critical point. Part 1 of this project consisted of measuring thermodynamic properties R125, R410A and R507A, measuring viscosity and thermal conductivity of R410A and R507A and comparing data to mixture models in NIST REFPROP database. For R125, isochoric (constant volume) heat capacity was measured over a temperature range of 305 to 397 K (32 to 124 C) at pressures up to 20 MPa. For R410A, isochoric heat capacity was measured along 8 isochores with a temperature range of 303 to 397 K (30 to 124 C) at pressures up to 18 MPa. Pressure-density-temperature was also measured along 14 isochores over a temperature range of 200 to 400 K (-73 to 127 C) at pressures up to 35 MPa and thermal conductivity along 6 isotherms over a temperature range of 301 to 404 K (28 to 131 C) with pressures to 38 MPa. For R507A, viscosity was measured along 5 isotherms over a temperature range of 301 to 421 K (28 to 148 C) at pressures up to 83 MPa and thermal conductivity along 6 isotherms over a temperature range of 301 to 404 K (28 to 131 C) with pressures to 38 MPa. Mixture models were developed to calculate the thermodynamic properties of HFC refrigerant mixtures containing R32, R125, R134a and/or R125. The form of the model is the same for all the blends considered, but blend-specific mixing functions are required for the blends R32/125 (R410 blends) and R32/134a (a constituent binary of R407 blends). The systems R125/134a, R125/143a, R134a/143a, and R134a/152a share a common, generalized mixing function. The new equation of state for R125 is believed to be the most accurate and comprehensive formulation of the properties for that fluid. Likewise, the mixture model developed in this work is the latest state-of-the-art for thermodynamic properties of HFC refrigerant blends. These models were incorporated into version 7 of NIST REFPROP database.

Mark O. McLinden; Arno Laesecke; Eric W. Lemmon; Joseph W. Magee; Richard A. Perkins



Evaporation heat transfer and friction characteristics of R-134a flowing downward in a vertical corrugated tube  

SciTech Connect (OSTI)

Differently from most previous studies, the heat transfer and friction characteristics of the pure refrigerant HFC-134a during evaporation inside a vertical corrugated tube are experimentally investigated. The double tube test sections are 0.5 m long with refrigerant flowing in the inner tube and heating water flowing in the annulus. The inner tubes are one smooth tube and two corrugated tubes, which are constructed from smooth copper tube of 8.7 mm inner diameter. The test runs are performed at evaporating temperatures of 10, 15, and 20 C, heat fluxes of 20, 25, and 30 kW/m{sup 2}, and mass fluxes of 200, 300, and 400 kg/m{sup 2} s. The quality of the refrigerant in the test section is calculated using the temperature and pressure obtained from the experiment. The pressure drop across the test section is measured directly by a differential pressure transducer. The effects of heat flux, mass flux, and evaporation temperature on the heat transfer coefficient and two-phase friction factor are also discussed. It is found that the percentage increases of the heat transfer coefficient and the two-phase friction factor of the corrugated tubes compared with those of the smooth tube are approximately 0-10% and 70-140%, respectively. (author)

Aroonrat, Kanit; Wongwises, Somchai [Fluid Mechanics, Thermal Engineering and Multiphase Flow Research Lab. (FUTURE), Department of Mechanical Engineering, King Mongkut's University of Technology Thonburi, Bangmod, Bangkok 10140 (Thailand)



Performance characteristics of a turbo expander substituted for expansion valve on air-conditioner  

SciTech Connect (OSTI)

An experimental study is conducted on a small turbo expander which could be applied to the expansion process in place of expansion valves in refrigerator or air-conditioner to improve the cycle efficiency by recovering energy from the throttling process. The operating gas is HFC134a and the maximum cooling capacity of experiment apparatus is 32.7 kW. Four different turbo expanders are tested to find the performance characteristics of the turbo expander when they operate at a low partial admission rate. The partial admission rate is 1.70% or 2.37, and expanders are operated in the supersonic flow. In the experiment, pressure and temperature are measured at 10 different locations in the experimental apparatus. In addition to these measurements, output power at the turbo expander is measured through a generator installed on a rotor shaft with the rotational speed. Performance data of the turbo expander are obtained at many part load operations by adjusting the output power of the generator. A maximum of 15.8% total-to-static efficiency is obtained when the pressure ratio and the partial admission ratio are 2.37 and 1.70%, respectively. Experimental results show that the optimal velocity ratio decreases when the pressure ratio is decreased, and peak efficiencies, which are obtained at locally maximized efficiency depending on the operating condition, vary linearly against the subcooling temperature or the pressure ratio. (author)

Cho, Soo-Yong [Department of Mechanical and Aerospace Engineering (ReCAPT), Gyeongsang National University, 900 Gajoa-dong, Jinju 660-701 (Korea); Cho, Chong-Hyun [School of Mechanical and Aerospace Engineering, Gyeongsang National University, 900 Gajoa-dong, Jinju 660-701 (Korea); Kim, Chaesil [Department of Mechanical Engineering, Changwon National University, 9 Sarim-dong, Changwon 641-773 (Korea)



Thin Film Solid-State Reactions Forming Carbides as Contact Materials for Carbon-Containing Semiconductors  

SciTech Connect (OSTI)

Metal carbides are good candidates to contact carbon-based semiconductors (SiC, diamond, and carbon nanotubes). Here, we report on an in situ study of carbide formation during the solid-state reaction between thin films. The solid-state reaction was examined between 11 transition metals (W, Mo, Fe, Cr, V, Nb, Mn, Ti, Ta, Zr, and Hf) and an amorphous carbon layer. Capping layers (C or TiN) of different thicknesses were applied to prevent oxidation. Carbide formation is evidenced for nine metals and the phases formed have been identified (for a temperature ranging from 100 to 1100 C). W first forms W{sub 2}C and then WC; Mo forms Mo{sub 2}C; Fe forms Fe{sub 3}C; Cr first forms metastable phases Cr{sub 2}C and Cr{sub 3}C{sub 2-x}, and finally forms Cr{sub 3}C{sub 2}; V forms VC{sub x}; Nb transforms into Nb{sub 2}C followed by NbC; Ti forms TiC; Ta first forms Ta{sub 2}C and then TaC; and Hf transforms into HfC. The activation energy for the formation of the various carbide phases has been obtained by in situ x-ray diffraction.

Leroy,W.; Detavernier, C.; Van Meirhaeghe, R.; Lavoie, C.



An evaluation on the environmental consequences of residual CFCs from obsolete household refrigerators in China  

SciTech Connect (OSTI)

Chlorofluorocarbons (CFCs) contained in household refrigerators consist mainly of CFC-11 and CFC-12, which will be eventually released into the environment. Consequentially, environmental releases of these refrigerants will lead to ozone depletion and contribute significantly to the greenhouse effect, if waste refrigerators are not disposed of properly. In the present paper, the potential release of residual CFCs and their substitutes from obsolete household refrigerators in China is examined, and their contributions to ozone depletion and greenhouse effect are compared with those of other recognized ozone-depleting substances (ODS) and greenhouse gases (GHGs). The results imply that annual potential amounts of released residual CFC-11 and CFC-12 will reach their maximums at 4600 and 2300 tons, respectively in 2011, and then decrease gradually to zero until 2020. Meanwhile, the amounts of their most widely used substitutes HCFC-141b and HFC-134a will keep increasing. Subsequently, the contribution ratio of these CFCs and their substitutes to ozone depletion will remain at 25% through 2011, and reach its peak value of 34% by 2018. The contribution to greenhouse effect will reach its peak value of 0.57% by 2010. Moreover, the contribution ratio of these CFCs to the total global release of CFCs will steadily increase, reaching its peak of 15% by 2018. Thus, this period from 2010 to 2018 is a crucial time during which residual CFCs and their substitutes from obsolete household refrigerators in China will contribute significantly to ozone depletion.

Zhao Xiangyang; Duan Huabo [Department of Environmental Science and Engineering, Tsinghua University, Beijing (China); Li Jinhui, E-mail: jinhui@tsinghua.edu.cn [Department of Environmental Science and Engineering, Tsinghua University, Beijing (China)



Accelerated screening methods for determining chemical and thermal stability of refrigerant-lubricant mixtures, Part 1: Method assessment. Final report  

SciTech Connect (OSTI)

This report presents results of a literature search performed to identify analytical techniques suitable for accelerated screening of chemical and thermal stabilities of different refrigerant/lubricant combinations. Search focused on three areas: Chemical stability data of HFC-134a and other non-chlorine containing refrigerant candidates; chemical stability data of CFC-12, HCFC-22, and other chlorine containing refrigerants; and accelerated thermal analytical techniques. Literature was catalogued and an abstract was written for each journal article or technical report. Several thermal analytical techniques were identified as candidates for development into accelerated screening tests. They are easy to operate, are common to most laboratories, and are expected to produce refrigerant/lubricant stability evaluations which agree with the current stability test ANSI/ASHRAE (American National Standards Institute/American Society of Heating, Refrigerating, and Air-Conditioning Engineers) Standard 97-1989, ``Sealed Glass Tube Method to Test the Chemical Stability of Material for Use Within Refrigerant Systems.`` Initial results of one accelerated thermal analytical candidate, DTA, are presented for CFC-12/mineral oil and HCFC-22/mineral oil combinations. Also described is research which will be performed in Part II to optimize the selected candidate.

Kauffman, R.



Global warming and end-use efficiency implications of replacing CFCs  

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The direct contribution of CFCs to calculated global warming has been recognized for some time. As a result of the international agreement to phase out CFCs due to stratospheric ozone and the ensuing search for suitable alternatives, there has recently been increased attention on the DIRECT global warming potential (GWP) of the fluorocarbon alternatives as greenhouse gases. However, to date there has been little focus on the INDIRECT global warming effect arising from end-use efficiency changes and associated CO{sub 2} emissions. A study being conducted at Oak Ridge National Laboratory (ORNL) addresses this combined or total global warming impact of viable options to replace CFCs in their major energy-related applications. This paper reviews selected results for air-conditioning, refrigeration, and heat pump applications. The analysis indicates that the CFC user industries have made substantial progress in approaching near-equal energy efficiency with the HCFC/HFC alternative refrigerants. The findings also bring into question the relative importance of the DIRECT (chemical-related) effect in many applications. Replacing CFCs is an important step in reducing the total global warming impact, and at present the HCFC and HFCS appear to offer the best efficiency and lowest total impact of options available in the relatively short time period required for the transition away from CFCs.

Fairchild, P.D.; Fischer, S.K.


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Greenhouse Gas Management Program Overview (Fact Sheet)  

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Program fact sheet highlighting federal requirements for GHG emissions management, FEMP services to help agencies reduce emissions, and additional resources. The U.S. Department of Energy (DOE) Federal Energy Management Program (FEMP) assists Federal agencies with managing their greenhouse gas (GHG) emissions. GHG management entails measuring emissions and understanding their sources, setting a goal for reducing emissions, developing a plan to meet this goal, and implementing the plan to achieve reductions in emissions. FEMP provides the following services to help Federal agencies meet the requirements of inventorying and reducing their GHG emissions: (1) FEMP offers one-on-one technical assistance to help agencies understand and implement the Federal Greenhouse Gas Accounting and Reporting Guidance and fulfill their inventory reporting requirements. (2) FEMP provides training, tools, and resources on FedCenter to help agencies complete their annual inventories. (3) FEMP serves a leadership role in the interagency Federal Working Group on Greenhouse Gas Accounting and Reporting that develops recommendations to the Council on Environmental Quality (CEQ) for the Federal Greenhouse Gas Accounting and Reporting Guidance. (4) As the focus continues to shift from measuring emissions (completing inventories) to mitigating emissions (achieving reductions), FEMP is developing a strategic planning framework and resources for agencies to prioritize among a variety of options for mitigating their GHG emissions, so that they achieve their reduction goals in the most cost-effective manner. These resources will help agencies analyze their high-quality inventories to make strategic decisions about where to use limited resources to have the greatest impact on reducing emissions. Greenhouse gases trap heat in the lower atmosphere, warming the earth's surface temperature in a natural process known as the 'greenhouse effect.' GHGs include carbon dioxide (CO{sub 2}), methane (CH{sub 4}), nitrous oxide (N{sub 2}O), perfluorocarbons (PFCs), hydrofluorocarbons (HFCs), and sulfur hexafluoride (SF{sub 6}). Human activities have caused a rapid increase in GHG concentrations. This rising level contributes to global climate change, which contributes to environmental and public health problems.

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Evaluation of design options for improving the energy efficiency of an environmentally safe domestic refrigerator-freezer  

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In order to reduce greenhouse emissions from power plants and respond to regulatory actions arising from the National Appliance Energy Conservation Act (NAECA), several design options were investigated for improving the energy efficiency of a conventionally designed, domestic refrigerator-freezer. The options, such as improved cabinet insulation and high-efficiency compressor and fans, were incorporated into a prototype refrigerator-freezer cabinet and refrigeration system to produce a unit that is superior from an environmental viewpoint due to its lower energy consumption and the use of refrigerant HFC-134a as a replacement for CFC-12. Baseline energy performance of the original 1993 production refrigerator-freezer, along with cabinet heat load and compressor calorimeter test results, were extensively documented to provide a firm basis for experimentally measured energy savings. A detailed refrigerator system computer model was used to evaluate the energy savings for several design modifications that, collectively, could achieve a targeted energy consumption of 1.00 kWh/d for a 20 ft{sup 3} (570 l) top-mount, automatic-defrost, refrigerator-freezer. The energy consumption goal represents a 50% reduction in the 1993 NAECA standard for units of this size. Following the modeling simulation, laboratory prototypes were fabricated and tested to experimentally verify the analytical results and aid in improving the model in those areas where discrepancies occurred. While the 1.00 kWh/d goal was not achieved with the modifications, a substantial energy efficiency improvement of 22% (1.41 kWh/d) was demonstrated using near-term technologies. It is noted that each improvement exacts a penalty in terms of increased cost or system complexity/reliability. Further work on this project will analyze cost-effectiveness of the design changes and investigate alternative, more-elaborate, refrigeration system changes to further reduce energy consumption.

Vineyard, E.A.; Sand, J.R. [Oak Ridge National Lab., TN (United States); Bohman, R.H.



EVermont Renewable Hydrogen Production and Transportation Fueling System  

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A great deal of research funding is being devoted to the use of hydrogen for transportation fuel, particularly in the development of fuel cell vehicles. When this research bears fruit in the form of consumer-ready vehicles, will the fueling infrastructure be ready? Will the required fueling systems work in cold climates as well as they do in warm areas? Will we be sure that production of hydrogen as the energy carrier of choice for our transit system is the most energy efficient and environmentally friendly option? Will consumers understand this fuel and how to handle it? Those are questions addressed by the EVermont Wind to Wheels Hydrogen Project: Sustainable Transportation. The hydrogen fueling infrastructure consists of three primary subcomponents: a hydrogen generator (electrolyzer), a compression and storage system, and a dispenser. The generated fuel is then used to provide transportation as a motor fuel. EVermont Inc., started in 1993 by then governor Howard Dean, is a public-private partnership of entities interested in documenting and advancing the performance of advanced technology vehicles that are sustainable and less burdensome on the environment, especially in areas of cold climates, hilly terrain and with rural settlement patterns. EVermont has developed a demonstration wind powered hydrogen fuel producing filling system that uses electrolysis, compression to 5000 psi and a hydrogen burning vehicle that functions reliably in cold climates. And that fuel is then used to meet transportation needs in a hybrid electric vehicle whose internal combustion engine has been converted to operate on hydrogen Sponsored by the DOE EERE Hydrogen, Fuel Cells & Infrastructure Technologies (HFC&IT) Program, the purpose of the project is to test the viability of sustainably produced hydrogen for use as a transportation fuel in a cold climate with hilly terrain and rural settlement patterns. Specifically, the project addresses the challenge of building a renewable transportation energy capable system. The prime energy for this project comes from an agreement with a wind turbine operator.

Garabedian, Harold T.



Overview of CFC replacement issues for household refrigeration  

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In 1974, the famous ozone depletion theory of Rowland and Molina claimed that chlorofluorocarbons (CFCs) diffuse into the stratosphere where they are broken down by photolysis to release chlorine atoms that catalytically destroy ozone. Although the understanding of the science is still imperfect, there is little doubt that CFCs play a major role in the Antarctic ozone hole phenomenon and the decline in ozone observed in the rest of the world. Another issue that has become increasingly important is the potential of CFCs to change the earth`s temperature and to modify the climate. While the main impact in global warming is made by increased concentrations of carbon dioxide, CFCs and other trace gases also contribute to this effect. In an effort to respond to the global environmental threat, a CFC protocol was adopted during a diplomatic conference in Montreal. This document, known as the Montreal Protocol, was ratified in 1988 and put into effect on January 1, 1989. In accordance with Article 6 of the Montreal Protocol, the countries that signed the agreement shall periodically assess the control measures provided for in the Protocol. As part of that assessment process, household refrigeration was investigated to determine the status of CFC-12 replacements. The conclusion was that much progress has been made towards finding a suitable replacement. Compressors designed for HFC-134a have efficiencies comparable to those for CFC-12 and acceptable reliability tests have been obtained with ester lubricants. In addition, other replacements such as R-152a and refrigerant mixtures exist, but will require more study. Cycle options, such as the Stirling cycle, may be viable, but are further out in the future. The impact of new refrigerants is expected to result in elimination of CFC-12 consumption in developed countries by 1997 and in developing countries by 2005.

Vineyard, E.A. [Oak Ridge National Lab., TN (United States); Roke, L. [Fisher and Paykel, Auckland (New Zealand); Hallett, F. [Frigidaire, Washington, DC (United States)



An investigation of a model of the flow pattern transition mechanism in relation to the identification of annular flow of R134a in a vertical tube using various void fraction models and flow regime maps  

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In the present study, new experimental data are presented for literature on the prediction of film thickness and identification of flow regime during the co-current downward condensation in a vertical smooth copper tube having an inner diameter of 8.1 mm and a length of 500 mm. R134a and water are used as working fluids in the tube side and annular side of a double tube heat exchanger, respectively. Condensation experiments are done at mass fluxes of 300 and 515 kg m{sup -2} s{sup -1}. The condensing temperatures are between 40 and 50 C; heat fluxes are between 12.65 and 66.61 kW m{sup -2}. The average experimental heat transfer coefficient of the refrigerant HFC-134a is calculated by applying an energy balance based on the energy transferred from the test section. A mathematical model by Barnea et al. based on the momentum balance of liquid and vapor phases is used to determine the condensation film thickness of R134a. The comparative film thickness values are determined indirectly using relevant measured data together with various void fraction models and correlations reported in the open literature. The effects of heat flux, mass flux, and condensation temperature on the film thickness and condensation heat transfer coefficient are also discussed for the laminar and turbulent flow conditions. There is a good agreement between the film thickness results obtained from the theoretical model and those obtained from six of 35 void fraction models in the high mass flux region of R134a. In spite of their different valid conditions, six well-known flow regime maps from the literature are found to be predictive for the annular flow conditions in the test tube in spite of their different operating conditions. (author)

Dalkilic, A.S. [Heat and Thermodynamics Division, Department of Mechanical Engineering, Yildiz Technical University, Yildiz, Besiktas, Istanbul 34349 (Turkey); Wongwises, S. [Fluid Mechanics, Thermal Engineering and Multiphase Flow Research Lab. (FUTURE), Department of Mechanical Engineering, King Mongkut's University of Technology Thonburi, Bangmod, Bangkok 10140 (Thailand)



DOE/AHAM advanced refrigerator technology development project  

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As part of the effort to improve residential energy efficiency and reduce greenhouse emissions from power plants, several design options were investigated for improving the energy efficiency of a conventionally designed domestic refrigerator-freezer. The program goal was to reduce the energy consumption of a 20-ft{sup 3} (570-L) top-mount refrigerator-freeze to 1.00 kWh/d, a 50% reduction from the 1993 National Appliance Energy Conservation Act (NAECA) standard. The options--such as improved cabinet and door insulation, a high-efficiency compressor, a low-wattage fan, a large counterflow evaporator, and adaptive defrost control--were incorporated into prototype refrigerator-freezer cabinets and refrigeration systems. The refrigerant HFC-134a was used as a replacement for CFC-12. The baseline energy performance of the production refrigerator-freezers, along with cabinet heat load and compressor calorimeter test results, were extensively documented to provide a firm basis for experimentally measured energy savings. The project consisted of three main phases: (1) an evaluation of energy-efficient design options using computer simulation models and experimental testing, (2) design and testing of an initial prototype unit, and (3) energy and economic analyses of a final prototype. The final prototype achieved an energy consumption level of 0.93 kWh/d--an improvement of 45% over the baseline unit and 54% over the 1993 NAECA standard for 20-fg{sup 3} (570-L) units. The manufacturer`s cost for those improvements was estimated at $134; assuming that cost is doubled for the consumer, it would take about 11.4 years to pay for the design changes. Since the payback period was thought to be unfeasible, a second, more cost-effective design was also tested. Its energy consumption level was 1.16 kWh/d, a 42% energy savings, at a manufacturer`s cost increase of $53. Again assuming a 100% markup, the payback for this unit would be 6.6 years.

Vineyard, E.A.; Sand, J.R.; Rice, C.K.; Linkous, R.L.; Hardin, C.V.; Bohman, R.H.



High Technology Centrifugal Compressor for Commercial Air Conditioning Systems  

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R&D Dynamics, Bloomfield, CT in partnership with the State of Connecticut has been developing a high technology, oil-free, energy-efficient centrifugal compressor called CENVA for commercial air conditioning systems under a program funded by the US Department of Energy. The CENVA compressor applies the foil bearing technology used in all modern aircraft, civil and military, air conditioning systems. The CENVA compressor will enhance the efficiency of water and air cooled chillers, packaged roof top units, and other air conditioning systems by providing an 18% reduction in energy consumption in the unit capacity range of 25 to 350 tons of refrigeration The technical approach for CENVA involved the design and development of a high-speed, oil-free foil gas bearing-supported two-stage centrifugal compressor, CENVA encompassed the following high technologies, which are not currently utilized in commercial air conditioning systems: Foil gas bearings operating in HFC-134a; Efficient centrifugal impellers and diffusers; High speed motors and drives; and System integration of above technologies. Extensive design, development and testing efforts were carried out. Significant accomplishments achieved under this program are: (1) A total of 26 builds and over 200 tests were successfully completed with successively improved designs; (2) Use of foil gas bearings in refrigerant R134a was successfully proven; (3) A high speed, high power permanent magnet motor was developed; (4) An encoder was used for signal feedback between motor and controller. Due to temperature limitations of the encoder, the compressor could not operate at higher speed and in turn at higher pressure. In order to alleviate this problem a unique sensorless controller was developed; (5) This controller has successfully been tested as stand alone; however, it has not yet been integrated and tested as a system; (6) The compressor successfully operated at water cooled condensing temperatures Due to temperature limitations of the encoder, it could not be operated at air cooled condensing temperatures. (7) The two-stage impellers/diffusers worked well separately but combined did not match well.

Ruckes, John



Properties and Cycle Performance of Refrigerant Blends Operating Near and Above the Refrigerant Critical Point, Task 2: Air Conditioner System Study  

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The main goal of this project was to investigate and compare the performance of an R410A air conditioner to that of an R22 air conditioner, with specific interest in performance at high ambient temperatures at which the condenser of the R410A system may be operating above the refrigerant's critical point. Part 1 of this project consisted of conducting comprehensive measurements of thermophysical for refrigerant R125 and refrigerant blends R410A and R507A and developing new equation of state formulations and mixture models for predicting thermophysical properties of HFC refrigerant blends. Part 2 of this project conducted performance measurements of split-system, 3-ton R22 and R410A residential air conditioners in the 80 to 135 F (27.8 to 57.2 C) outdoor temperature range and development of a system performance model. The performance data was used in preparing a beta version of EVAP-COND, a windows-based simulation package for predicting performance of finned-tube evaporators and condensers. The modeling portion of this project also included the formulation of a model for an air-conditioner equipped with a thermal expansion valve (TXV). Capacity and energy efficiency ratio (EER) were measured and compared. The R22 system's performance was measured over the outdoor ambient temperature range of 80 to 135 F (27.8 to 57.2 C). The same test range was planned for the R410A system. However, the compressor's safety system cut off the compressor at the 135.0 F (57.2 C) test temperature. The highest measurement on this system was at 130.0 F (54.4 C). Subsequently, a custom-manufactured R410A compressor with a disabled safety system and a more powerful motor was installed and performance was measured at outdoor temperatures up to 155.0 F (68.3 C). Both systems had similar capacity and EER performance at 82.0 F (27.8 C). The capacity and EER degradation of both systems were nearly linearly dependent with rising ambient outdoor ambient test temperatures. The performance degradation of R410A at higher temperatures was greater than R22. However, the R22 and R410A systems both operated normally during all tests. Visual observations of the R410A system provided no indication of vibrations or TXV hunting at high ambient outdoor test conditions with the compressor operating in the transcritical regime.

Piotr A. Domanski; W. Vance Payne



Federal technology transfer requirements :a focused study of principal agencies approaches with implications for the Department of Homeland Security.  

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This report provides relevant information and analysis to the Department of Homeland Security (DHS) that will assist DHS in determining how to meet the requirements of federal technology transfer legislation. These legal requirements are grouped into five categories: (1) establishing an Office of Research and Technology Applications, or providing the functions thereof; (2) information management; (3) enabling agreements with non-federal partners; (4) royalty sharing; and (5) invention ownership/obligations. These five categories provide the organizing framework for this study, which benchmarks other federal agencies/laboratories engaged in technology transfer/transition Four key agencies--the Department of Health & Human Services (HHS), the U.S. Department of Agriculture (USDA), the Department of Energy (DOE), and the Department of Defense (DoD)--and several of their laboratories have been surveyed. An analysis of DHS's mission needs for commercializing R&D compared to those agencies/laboratories is presented with implications and next steps for DHS's consideration. Federal technology transfer legislation, requirements, and practices have evolved over the decades as agencies and laboratories have grown more knowledgeable and sophisticated in their efforts to conduct technology transfer and as needs and opinions in the federal sector have changed with regards to what is appropriate. The need to address requirements in a fairly thorough manner has, therefore, resulted in a lengthy paper. There are two ways to find summary information. Each chapter concludes with a summary, and there is an overall ''Summary and Next Steps'' chapter on pages 57-60. For those readers who are unable to read the entire document, we recommend referring to these pages.

Koker, Denise; Micheau, Jill M.



Hybrid Membrane/Absorption Process for Post-combustion CO2 Capture  

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This report summarizes scientific/technical progress made for bench-scale membrane contactor technology for post-combustion CO2 capture from DOE Contract No. DE-FE-0004787. Budget Period 1 (BP1) membrane absorber, Budget Period 2 (BP2) membrane desorber and Budget Period 3 (BP3) integrated system and field testing studies have been completed successfully and met or exceeded the technical targets (? 90% CO2 removal and CO2 purity of 97% in one membrane stage). Significant breakthroughs are summarized below: BP1 research: The feasibility of utilizing the poly (ether ether ketone), PEEK, based hollow fiber contractor (HFC) in combination with chemical solvents to separate and capture at least 90% of the CO2 from simulated flue gases has been successfully established. Excellent progress has been made as we have achieved the BP1 goal: ? 1,000 membrane intrinsic CO2 permeance, ? 90% CO2 removal in one stage, ? 2 psi gas side pressure drop, and ? 1 (sec)-1 mass transfer coefficient. Initial test results also show that the CO2 capture performance, using activated Methyl Diethanol Amine (aMDEA) solvent, was not affected by flue gas contaminants O2 (~3%), NO2 (66 ppmv), and SO2 (145 ppmv). BP2 research: The feasibility of utilizing the PEEK HFC for CO2-loaded solvent regeneration has been successfully established High CO2 stripping flux, one order of magnitude higher than CO2 absorption flux, have been achieved. Refined economic evaluation based on BP1 membrane absorber and BP2 membrane desorber laboratory test data indicate that the CO2 capture costs are 36% lower than DOEís benchmark amine absorption technology. BP3 research: A bench-scale system utilizing a membrane absorber and desorber was integrated into a continuous CO2 capture process using contactors containing 10 to 20 ft2 of membrane area. The integrated process operation was stable through a 100-hour laboratory test, utilizing a simulated flue gas stream. Greater than 90% CO2 capture combined with 97% CO2 product purity was achieved throughout the test. Membrane contactor modules have been scaled from bench scale 2-inch diameter by 12-inch long (20 ft2 membrane surface area) modules to 4-inch diameter by 60-inch long pilot scale modules (165 ft2 membrane surface area). Pilot scale modules were tested in an integrated absorption/regeneration system for CO2 capture field tests at a coal-fired power plant (Midwest Generationís Will County Station located in Romeoville, IL). Absorption and regeneration contactors were constructed utilizing high performance super-hydrophobic, nano-porous PEEK membranes with CO2 gas permeance of 2,000 GPU and a 1,000 GPU, respectively. Field tests using aMDEA solvent achieved greater than 90% CO2 removal in a single stage. The absorption mass transfer coefficient was 1.2 (sec)-1, exceeding the initial target of 1.0 (sec)-1. This mass transfer coefficient is over one order of magnitude greater than that of conventional gas/liquid contacting equipment. The economic evaluation based on field tests data indicates that the CO2 capture cost associated with membrane contactor technology is $54.69 (Yr 2011$)/tonne of CO2 captured when using aMDEA as a solvent. It is projected that the DOEís 2025 cost goal of $40 (Yr 2011$)/tonne of CO2 captured can be met by decreasing membrane module cost and by utilizing advanced CO2 capture solvents. In the second stage of the field test, an advanced solvent, Hitachiís H3-1 was utilized. The use of H3-1 solvent increased mass transfer coefficient by 17% as compared to aMDEA solvent. The high mass transfer coefficient of H3-1 solvent combined with much more favorable solvent regeneration requirements, indicate that the projected savings achievable with membrane contactor process can be further improved. H3-1 solvent will be used in the next pilot-scale development phase. The integrated absorption/regeneration process design and high performance membrane contactors developed in the current bench-scale program will be used as the base technology for future pilot-scale development.

Li, Shiguang; Shou, S.; Pyrzynski, Travis; Makkuni, Ajay; Meyer, Howard



The Evolution of the Federal Monitoring and Assessment Center  

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The Federal Radiological Monitoring and Assessment Center (FRMAC) is a federal emergency response asset whose assistance may be requested by the Department of Homeland Security (DHS), the Department of Defense (DoD), the Environmental Protection Agency (EPA), the Nuclear Regulatory Commission (NRC), and state and local agencies to respond to a nuclear or radiological incident. It is an interagency organization with representation from the Department of Energyís National Nuclear Security Administration (DOE/NNSA), the Department of Defense (DoD), the Environmental Protection Agency (EPA), the Department of Health and Human Services (HHS), the Federal Bureau of Investigation (FBI), and other federal agencies. FRMAC, in its present form, was created in 1987 when the radiological support mission was assigned to the DOEís Nevada Operations Office by DOE Headquarters. The FRMAC asset, including its predecessor entities, was created, grew, and evolved to function as a response to radiological incidents. Radiological emergency response exercises showed the need for a coordinated approach to managing federal emergency monitoring and assessment activities. The mission of FRMAC is to coordinate and manage all federal radiological environmental monitoring and assessment activities during a nuclear or radiological incident within the United States in support of state,local, tribal governments, DHS, and the federal coordinating agency. Radiological emergency response professionals with the DOEís national laboratories support the Radiological Assistance Program (RAP), National Atmospheric Release Advisory Center (NARAC), the Aerial MeasuringSystem (AMS), and the Radiation Emergency Assistance Center/Training Site (REAC/TS). These teams support the FRMAC to provide: ? Atmospheric transport modeling ? Radiation monitoring ? Radiological analysis and data assessments ? Medical advice for radiation injuries In support of field operations, the FRMAC provides geographic information systems, communications, mechanical, electrical, logistics, and administrative support. The size of the FRMAC is tailored to the incident and is comprised of emergency response professionals drawn from across the federal government. State and local emergency response teams may also integrate their operations with FRMAC, but are not required to.

NSTec Aerial Measurement System




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This chapter addresses past, ongoing, and short (to 2010) and medium-term (to 2030) future actions that can be taken to mitigate GHG emissions from the manufacturing and process industries. Globally, and in most countries, CO{sub 2} accounts for more than 90% of CO{sub 2}-eq GHG emissions from the industrial sector (Price et al., 2006; US EPA, 2006b). These CO{sub 2} emissions arise from three sources: (1) the use of fossil fuels for energy, either directly by industry for heat and power generation or indirectly in the generation of purchased electricity and steam; (2) non-energy uses of fossil fuels in chemical processing and metal smelting; and (3) non-fossil fuel sources, for example cement and lime manufacture. Industrial processes also emit other GHGs, e.g.: (1) Nitrous oxide (N{sub 2}O) is emitted as a byproduct of adipic acid, nitric acid and caprolactam production; (2) HFC-23 is emitted as a byproduct of HCFC-22 production, a refrigerant, and also used in fluoroplastics manufacture; (3) Perfluorocarbons (PFCs) are emitted as byproducts of aluminium smelting and in semiconductor manufacture; (4) Sulphur hexafluoride (SF{sub 6}) is emitted in the manufacture, use and, decommissioning of gas insulated electrical switchgear, during the production of flat screen panels and semiconductors, from magnesium die casting and other industrial applications; (5) Methane (CH{sub 4}) is emitted as a byproduct of some chemical processes; and (6) CH{sub 4} and N{sub 2}O can be emitted by food industry waste streams. Many GHG emission mitigation options have been developed for the industrial sector. They fall into three categories: operating procedures, sector-wide technologies and process-specific technologies. A sampling of these options is discussed in Sections 7.2-7.4. The short- and medium-term potential for and cost of all classes of options are discussed in Section 7.5, barriers to the application of these options are addressed in Section 7.6 and the implication of industrial mitigation for sustainable development is discussed in Section 7.7. Section 7.8 discusses the sector's vulnerability to climate change and options for adaptation. A number of policies have been designed either to encourage voluntary GHG emission reductions from the industrial sector or to mandate such reductions. Section 7.9 describes these policies and the experience gained to date. Co-benefits of reducing GHG emissions from the industrial sector are discussed in Section 7.10. Development of new technology is key to the cost-effective control of industrial GHG emissions. Section 7.11 discusses research, development, deployment and diffusion in the industrial sector and Section 7.12, the long-term (post-2030) technologies for GHG emissions reduction from the industrial sector. Section 7.13 summarizes gaps in knowledge.

Bernstein, Lenny; Roy, Joyashree; Delhotal, K. Casey; Harnisch, Jochen; Matsuhashi, Ryuji; Price, Lynn; Tanaka, Kanako; Worrell, Ernst; Yamba, Francis; Fengqi, Zhou; de la Rue du Can, Stephane; Gielen, Dolf; Joosen, Suzanne; Konar, Manaswita; Matysek, Anna; Miner, Reid; Okazaki, Teruo; Sanders, Johan; Sheinbaum Parado, Claudia



Ground-Source Integrated Heat Pump for Near-Zero Energy Houses: Technology Status Report  

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The energy service needs of a net-zero-energy house (ZEH) include space heating and cooling, water heating, ventilation, dehumidification, and humidification, depending on the requirements of the specific location. These requirements differ in significant ways from those of current housing. For instance, the most recent DOE buildings energy data (DOE/BED 2007) indicate that on average {approx}43% of residential buildings primary energy use is for space heating and cooling, vs. {approx}12% for water heating (about a 3.6:1 ratio). In contrast, for the particular prototype ZEH structures used in the analyses in this report, that ratio ranges from about 0.3:1 to 1.6:1 depending on location. The high-performance envelope of a ZEH results in much lower space heating and cooling loads relative to current housing and also makes the house sufficiently air-tight to require mechanical ventilation for indoor air quality. These envelope characteristics mean that the space conditioning load will be closer in size to the water heating load, which depends on occupant behavior and thus is not expected to drop by any significant amount because of an improved envelope. In some locations such as the Gulf Coast area, additional dehumidification will almost certainly be required during the shoulder and cooling seasons. In locales with heavy space heating needs, supplemental humidification may be needed because of health concerns or may be desired for improved occupant comfort. The U.S. Department of Energy (DOE) has determined that achieving their ZEH goal will require energy service equipment that can meet these needs while using 50% less energy than current equipment. One promising approach to meeting this requirement is through an integrated heat pump (IHP) - a single system based on heat pumping technology. The energy benefits of an IHP stem from the ability to utilize otherwise wasted energy; for example, heat rejected by the space cooling operation can be used for water heating. With the greater energy savings the cost of the more energy efficient components required for the IHP can be recovered more quickly than if they were applied to individual pieces of equipment to meet each individual energy service need. An IHP can be designed to use either outdoor air or geothermal resources (e.g., ground, ground water, surface water) as the environmental energy source/sink. Based on a scoping study of a wide variety of possible approaches to meeting the energy service needs for a ZEH, DOE selected the IHP concept as the most promising and has supported research directed toward the development of both air- and ground-source versions. This report describes the ground-source IHP (GS-IHP) design and includes the lessons learned and best practices revealed by the research and development (R&D) effort throughout. Salient features of the GS-IHP include a variable-speed rotary compressor incorporating a brushless direct current permanent magnet motor which provides all refrigerant compression, a variable-speed fan for the indoor section, a multiple-speed ground coil circuit pump, and a single-speed pump for water heating operation. Laboratory IHP testing has thus far used R-22 because of the availability of the needed components that use this refrigerant. It is expected that HFC R-410A will be used for any products arising from the IHP concept. Data for a variable-speed compressor that uses R-410A has been incorporated into the DOE/ORNL Mark VI Heat Pump Design Model (HPDM). HPDM was then linked to TRNSYS, a time-series-dependent simulation model capable of determining the energy use of building cooling and heating equipment as applied to a defined house on a sub-hourly basis. This provided a highly flexible design analysis capability for advanced heat pump equipment; however, the program also took a relatively long time to run. This approach was used with the initial prototype design reported in Murphy et al. (2007a) and in the business case analysis of Baxter (2007).

Murphy, Richard W [ORNL; Rice, C Keith [ORNL; Baxter, Van D [ORNL; Craddick, William G [ORNL