National Library of Energy BETA

Sample records for heterogeneous feed biorefinery

  1. IMPROVED BIOREFINERY FOR THE PRODUCTION OF ETHANOL, CHEMICALS, ANIMAL FEED AND BIOMATERIALS FROM SUGAR CANE

    SciTech Connect (OSTI)

    Dr. Donal F. Day

    2009-01-29

    The Audubon Sugar Institute (ASI) of Louisiana State University’s Agricultural Center (LSU AgCenter) and MBI International (MBI) sought to develop technologies that will lead to the development of a sugar-cane biorefinery, capable of supplying fuel ethanol from bagasse. Technology development focused on the conversion of bagasse, cane-leaf matter (CLM) and molasses into high value-added products that included ethanol, specialty chemicals, biomaterials and animal feed; i.e. a sugar cane-based biorefinery. The key to lignocellulosic biomass utilization is an economically feasible method (pretreatment) for separating the cellulose and the hemicellulose from the physical protection provided by lignin. An effective pretreatment disrupts physical barriers, cellulose crystallinity, and the association of lignin and hemicellulose with cellulose so that hydrolytic enzymes can access the biomass macrostructure (Teymouri et al. 2004, Laureano-Perez, 2005). We chose to focus on alkaline pretreatment methods for, and in particular, the Ammonia Fiber Expansion (AFEX) process owned by MBI. During the first two years of this program a laboratory process was established for the pretreatment of bagasse and CLM using the AFEX process. There was significant improvement of both rate and yield of glucose and xylose upon enzymatic hydrolysis of AFEX-treated bagasse and CLM compared with untreated material. Because of reactor size limitation, several other alkaline pretreatment methods were also co-investigated. They included, dilute ammonia, lime and hydroxy-hypochlorite treatments. Scale-up focused on using a dilute ammonia process as a substitute for AFEX, allowing development at a larger scale. The pretreatment of bagasse by an ammonia process, followed by saccharification and fermentation produced ethanol from bagasse. Simultaneous saccharification and fermentation (SSF) allowed two operations in the same vessel. The addition of sugarcane molasses to the hydrolysate/fermentation process yielded improvements beyond what was expected solely from the addition of sugar. In order to expand the economic potential for building a biorefinery, the conversion of enzyme hydrolysates of AFEX-treated bagasse to succinic acid was also investigated. This program established a solid basis for pre-treatment of bagasse in a manner that is feasible for producing ethanol at raw sugar mills.

  2. Mascoma: Frontier Biorefinery Project

    Broader source: Energy.gov [DOE]

    This project involves the construction and operation of a biorefinery that produces ethanol and other co-products from cellulosic materials through advanced consolidated bioprocessing.

  3. Integrated Biorefineries | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Research & Development » Integrated Biorefineries Integrated Biorefineries Conversion Technology Loading... Primary Feedstock Loading... Primary Product Loading... Project Scale Loading... Choose map view BETO Biorefinery Investments by State Display by Project Show Map Labels The interactive map above highlights biorefinery projects funded by the Bioenergy Technologies Office at pilot, demonstration, and pioneer scales. Adjust the map filters to control the information displayed.

  4. Elevance Pilot-Scale Biorefinery

    Broader source: Energy.gov [DOE]

    The Elevance biorefinery uses catalyst technology to produce fuels and chemicals from renewable, natural oils.

  5. Alpena Biorefinery | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Alpena Biorefinery Alpena Biorefinery The Alpena Biorefinery will be constructed in Alpena, Michigan, at the Decorative Panels International hardboard manufacturing facility. PDF icon ibr_arra_api.pdf More Documents & Publications EA-1789: Final Environmental Assessment EA-1789: Finding of No Significant Impact American Process-Alpena Biorefinery Lessons

  6. NREL: Biomass Research - What Is a Biorefinery?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    What Is a Biorefinery? A biorefinery is a facility that integrates biomass conversion processes and equipment to produce fuels, power, and chemicals from biomass. The biorefinery...

  7. Bioenergy Impacts: Biorefineries

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    POET-DSM's Project LIBERTY and Abengoa's Bioenergy Biomass of Kansas are biorefineries that convert corn stover-non-edible corn stalks, stems, and leaves-into cellulosic ethanol, a ...

  8. Integrated Biorefinery Process

    Energy Savers [EERE]

    Int'l Smart Grid Action Network Int'l Smart Grid Action Network International PDF icon Int'l Smart Grid Action Network More Documents & Publications Clean Energy Ministerial Press Fact Sheet IEA: Tracking Clean Energy Progress: Energy Technology Perspectives 2012 Joint Statement by Energy Ministers of G8, The People's Republic of China, India and The Republic of Korea (June 2008) of Energy

    Integrated Biorefineries:Biofuels, Biopower, and Bioproducts Integrated Biorefineries:Biofuels,

  9. Alpena Biorefinery | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Alpena Biorefinery Alpena Biorefinery Alpena Biorefinery The American Process Inc. (API) Alpena Biorefinery converts the industrial waste stream from a neighboring board manufacturing mill into a cellulosic biofuel and by-product. API's innovative conversion process has helped the mill to significantly reduce its waste treatment costs, increase its economic viability, and improve the job retention outlook for its 200 employees. In addition to assisting this major employer in Alpena, Michigan,

  10. Economy Through Product Diversity: Integrated Biorefineries ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Economy Through Product Diversity: Integrated Biorefineries Economy Through Product Diversity: Integrated Biorefineries Achieving national energy and climate goals will require an ...

  11. Economy Through Product Diversity: Integrated Biorefineries

    SciTech Connect (OSTI)

    2010-03-01

    A general discussion of the integrated biorefinery concept, the Biomass Program's related activities and challenges and specific biorefinery projects being funded through the Program.

  12. Economy Through Product Diversity: Integrated Biorefineries ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Economy Through Product Diversity: Integrated Biorefineries Economy Through Product Diversity: Integrated Biorefineries Achieving national energy and climate goals will require an...

  13. Albemarle Biorefinery Inc | Open Energy Information

    Open Energy Info (EERE)

    Biorefinery Inc Jump to: navigation, search Name: Albemarle Biorefinery Inc Place: Raleigh, North Carolina Zip: 27612 Product: A subsidiary of DFI Group that focusses on the...

  14. Integrated Biorefineries | Department of Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Map Labels The interactive map above highlights biorefinery projects funded by the Bioenergy Technologies Office at pilot, demonstration, and pioneer scales. Adjust the map...

  15. Biomass Program 2007 Accomplishments - Integrated Biorefinery Platform

    SciTech Connect (OSTI)

    none,

    2008-06-01

    This document details the accomplishments of the Biomass Program Integrated Biorefinery Platform in 2007.

  16. Biochemical Conversion - Biorefinery Integration | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Research & Development » Conversion Technologies » Biochemical Conversion » Biochemical Conversion - Biorefinery Integration Biochemical Conversion - Biorefinery Integration One of the essential elements in the economical and efficient production of cellulosic biofuels is the development of biorefineries. Similar in concept to traditional petroleum refineries, biorefineries convert various types of biomass feedstock into marketable chemicals, fuels, and products. By taking advantage of

  17. Lignol Innovations, Inc. Demonstration-Scale Biorefinery

    Broader source: Energy.gov [DOE]

    The Lignol Innovations, Inc., biorefinery will produce cellulosic ethanol, high purity lignin, and furfural from hardwoods.

  18. Red Shield Acquisition, LLC, Integrated Biorefinery

    Broader source: Energy.gov [DOE]

    This demonstration-scale biorefinery will produce lignocellulosic sugars for biofuel feedstock from woody biomass.

  19. Development of Integrated Biorefineries | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Integrated Biorefineries » Development of Integrated Biorefineries Development of Integrated Biorefineries The development of the integrated biorefinery was identified as crucial part of achieving alternative fuel production goals. Throughout its stages of development, the integrated biorefinery will utilize input from all of the other platforms as well as the existing biofuels industry. The research and development of feedstocks and the biochemical and thermochemical conversion platforms will

  20. 9003: Biorefinery Assistance Program | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    9003: Biorefinery Assistance Program 9003: Biorefinery Assistance Program Breakout Session 1D-Building Market Confidence and Understanding I: Integrated Biorefinery (Lessons Learned and Best Practices) 9003: Biorefinery Assistance Program Chris Cassidy, National Business Renewable Energy Advisor, U.S. Department of Agriculture PDF icon cassidy_biomass_2014.pdf More Documents & Publications Project Finance and Investments Demonstration and Deployment Workshop - Day 1 American Process-Alpena

  1. Range Fuels Commercial-Scale Biorefinery

    Broader source: Energy.gov [DOE]

    The Range Fuels commercial-scale biorefinery will use a variety of feedstocks to create cellulosic ethanol, methanol, and power.

  2. Abengoa Integrated Biorefineries | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Integrated Biorefineries Abengoa Integrated Biorefineries Demonstration and Deployment Successes Gerson Santos, Executive Vice President, Abengoa PDF icon b13_santos_ap-2.pdf More Documents & Publications 2014 DOE Biomass Program Integrated Biorefinery Project Comprehensive Project Review Biomass IBR Fact Sheet: Abengoa Bioenergy Abengoa IBR Successes

  3. Engineering Cellulases for Biorefinery

    SciTech Connect (OSTI)

    Manoj Kumar, PhD

    2010-06-27

    Lignocellulosic biomass is the most abundant, least expensive renewable natural biological resource for the production of biobased products and bioenergy is important for the sustainable development of human civilization in 21st century. For making the fermentable sugars from lignocellulosic biomass, a reduction in cellulase production cost, an improvement in cellulase performance, and an increase in sugar yields are all vital to reduce the processing costs of biorefineries. Improvements in specific cellulase activities for non-complexed cellulase mixtures can be implemented through cellulase engineering based on rational design or directed evolution for each cellulase component enzyme, as well as on the reconstitution of cellulase components. In this paper, we will provide DSM's efforts in cellulase research and developments and focus on limitations. Cellulase improvement strategies based on directed evolution using screening on relevant substrates, screening for higher thermal tolerance based on activity screening approaches such as continuous culture using insoluble cellulosic substrates as a powerful selection tool for enriching beneficial cellulase mutants from the large library. We will illustrate why and how thermostable cellulases are vital for economic delivery of bioproducts from cellulosic biomass using biochemical conversion approach.

  4. Algal Integrated Biorefineries | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Research & Development » Algal Biofuels » Algal Integrated Biorefineries Algal Integrated Biorefineries The Algae Program works closely with the Demonstration and Deployment Program on projects that can validate advancements toward commercialization at increasing scales. Integrated biorefineries apply R&D to scale-up facilities to a degree relevant to commercial applications. U.S. Department of Energy funding of this work helps to advance the industry by minimizing the risk of these

  5. FOA for the Demonstration of an Integrated Biorefinery System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    FOA for the Demonstration of an Integrated Biorefinery System: Abengoa Bioenergy Biomass of Kansas, LLC FOA for the Demonstration of an Integrated Biorefinery System: Blue Fire ...

  6. FOA for the Demonstration of an Integrated Biorefinery System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    FOA for the Demonstration of an Integrated Biorefinery System: Abengoa Bioenergy Biomass of Kansas, LLC FOA for the Demonstration of an Integrated Biorefinery System: POET Project ...

  7. Biorefinery Grant Announcement | Department of Energy

    Office of Environmental Management (EM)

    for their "project liberty" facility in Emmetsburg, Iowa; Iogen Biorefinery Partners, for a facility in Idaho Falls, Idaho; and Range Fuels, for a facility in Soperton, Georgia. ...

  8. A Biorefinery Goes 'Mod' and Small

    Broader source: Energy.gov [DOE]

    Minnesota-based Easy Energy Systems sells small-scale, easy-to use biorefineries. The company expects to create 100 jobs because of new orders.

  9. Investigation of thermochemical biorefinery sizing and environmental...

    Office of Scientific and Technical Information (OSTI)

    Investigation of thermochemical biorefinery sizing and environmental sustainability impacts for conventional supply system and distributed pre-processing supply system designs...

  10. United Biorefineries Corp UBC | Open Energy Information

    Open Energy Info (EERE)

    physical & biological research. Involved in the project development of an Integrated Biorefinery Complex utilizing algae and cellulosic-based second generation biofuels technology....

  11. Feeding

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Feeding the Pipeline: The SNfactory Supernova Search Richard Scalzo NERSC User Group Meeting October 4, 2005 Outline Background ● Interest in supernova science ● Observational challenges in finding supernovae The SNfactory search pipeline ● Description of hardware ● Past searches and challenges in development ● Present and future Why supernovae are interesting Two types of SNe: "type Ia" and "core-collapse". SNe Ia ● Model: Thermonuclear explosion of degenerate

  12. EA-1790: Finding of No Significant Impact

    Broader source: Energy.gov [DOE]

    Construction and Operation of a Heterogeneous Feed Biorefinery, Enerkem Corporation, Pontotoc, Mississippi

  13. EA-1790: Supplement Analysis

    Broader source: Energy.gov [DOE]

    Construction and Operation of a Heterogeneous Feed Biorefinery, Enerkem Corporation, Pontotoc, Mississippi

  14. EA-1790: Final Environmental Assessment

    Broader source: Energy.gov [DOE]

    Construction and Operation of a Heterogeneous Feed Biorefinery Enerkem Corporation Pontotoc, Mississippi

  15. Integrated Biorefineries: Biofuels, Biopower, and Bioproducts

    SciTech Connect (OSTI)

    2013-05-06

    This fact sheet describes integrated biorefineries and the Program's work with them. A crucial step in developing the U.S. bioindustry is to establish integrated biorefineries capable of efficiently converting a broad range of biomass feedstocks into affordable biofuels, biopower, and other bioproducts.

  16. Flambeau River Biofuels Demonstration-Scale Biorefinery | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Flambeau River Biofuels Demonstration-Scale Biorefinery Flambeau River Biofuels Demonstration-Scale Biorefinery The Flambeau River biorefinery will be added to an existing pulp and paper mill to create green diesel. PDF icon ibr_demonstration_flambeau.pdf More Documents & Publications NewPage Demonstration-Scale Biorefinery Flambeau_River_Biofuels.pdf Pacific Ethanol, Inc

  17. American Process-Alpena Biorefinery Lessons | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Process-Alpena Biorefinery Lessons American Process-Alpena Biorefinery Lessons Breakout Session 1D-Building Market Confidence and Understanding I: Integrated Biorefinery (Lessons Learned and Best Practices) American Process-Alpena Biorefinery Lessons Theodora Retsina, Chief Executive Officer, America Process Inc. PDF icon retsina_biomass_2014.pdf More Documents & Publications Alpena Biorefinery EA-1789: Finding of No Significant Impact EA-1789: Final Environmental Assessment

  18. Multitasking mesoporous nanomaterials for biorefinery applications

    SciTech Connect (OSTI)

    Kandel, Kapil

    2013-05-02

    Mesoporous silica nanoparticles (MSNs) have attracted great interest for last two decades due to their unique and advantageous structural properties, such as high surface area, pore volume, stable mesostructure, tunable pore size and controllable particle morphology. The robust silica framework provides sites for organic modifications, making MSNs ideal platforms for adsorbents and supported organocatalysts. In addition, the pores of MSNs provide cavities/ channels for incorporation of metal and metal oxide nanoparticle catalysts. These supported metal nanoparticle catalysts benefit from confined local environments to enhance their activity and selectivity for various reactions. Biomass is considered as a sustainable feedstock with potential to replace diminishing fossil fuels for the production of biofuels. Among several strategies, one of the promising methods of biofuel production from biomass is to reduce the oxygen content of the feedstock in order to improve the energy density. This can be achieved by creating C-C bonds between biomass derived intermediates to increase the molecular weight of the final hydrocarbon molecules. In this context, pore size and organic functionality of MSNs are varied to obtain the ideal catalyst for a C-C bond forming reaction: the aldol condensation. The mechanistic aspects of this reaction in supported heterogeneous catalysts are explored. The modification of supported organocatalyst and the effect of solvent on the reaction are rationalized. The significance of two functional surfaces of MSNs is exploited by enzyme immobilization on the external surface and organo catalyst functionalization on the internal surface. Using this bifunctional catalyst, the tandem conversion of small chain alcohols into longer chain hydrocarbon molecules is demonstrated. The ability to incorporate metal and metal oxide nanoparticles in the pores and subsequent functionalization led to develop organic modified magnetic MSNs (OM-MSNs) for applications in microalgae biorefinery. Two different integrated biorefinery systems are highlighted. (i) OM-MSNs are used to harvest microalgae and selectively sequester free fatty acids (FFAs). (ii) OM-MSNs are shown to selectively sequester FFAs and convert them into diesel-range liquid hydrocarbon fuels. A similar MSN supported metal nanoparticle catalyst is demonstrated to transform FFAs into green diesel with even greater activity and selectivity. The incorporation of a different organic functional group into MSN provides a selective adsorbent for separation and purification of -tocopherol from microalgae oil. The functional group with electron deficient aromatic rings demonstrated high sequestration capacity and selectivity of {alpha}-tocopherol.

  19. POET-DSM biorefinery in Iowa

    Broader source: Energy.gov [DOE]

    POET-DSM’s Project LIBERTY biorefinery in Emmetsburg, Iowa is the nation’s first commercial-scale cellulosic ethanol plant to use corn waste as a feedstock.

  20. Five Things to Know about Biorefinery Investments

    Broader source: Energy.gov [DOE]

    This week, Abengoa’s cellulosic ethanol plant in Hugoton, Kansas, will have its grand opening—right on the heels of POET-DSM’s Project LIBERTY in September. Both biorefineries produce cellulosic...

  1. Integrated Biorefineries:Biofuels, Biopower, and Bioproducts

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    INTEGRATED BIOREFINERIES INEOS New Planet Bioenergy began production at its Indian River Bioenergy Center in Vero Beach, FL, in July 2013. Cost-shared funding from the Bioenergy Technologies Office contributed to the construction of this pioneer-scale plant, which converts waste biomass materials into 8 million gallons of cellulosic ethanol and produces 6 MW of power annually. Photo: INEOS Bio Integrated Biorefineries: Reducing Investment Risk in Novel Technology Achieving national energy and

  2. Integrated Biorefinery Process | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Process Integrated Biorefinery Process At the February 12, 2009 quarterly joint Web conference of DOE's Biomass and Clean Cities programs, Larry Russo (U.S. Department of Energy, Biomass Program) described the progress of DOEs Biorefinery Projects. PDF icon russo_20090212.pdf More Documents & Publications Quarterly Biomass Program/Clean Cities States Web Conference: January 21, 2010 The Current State of Technology for Cellulosic Ethanol Slide 1

  3. Integrated Biorefinery Research Facility | Bioenergy | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Integrated Biorefinery Research Facility NREL's Integrated Biorefinery Research Facility (IBRF) enables researchers and industry partners to develop, test, evaluate, and demonstrate processes and technologies for the production of bio-based products and fuels. Interior of industrial, two-story building with high-bay, piping, and large processing equipment. Three workers in hard hats. In addition to the facility itself, NREL's world-renowned expert staff works with IBRF partners at every stage of

  4. Integrated Biorefinery Research Facility (IBRF I-II) (Post CD...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Integrated Biorefinery Research Facility (IBRF I-II) (Post CD-4), EERE, Aug 2011 Integrated Biorefinery Research Facility (IBRF I-II) (Post CD-4), EERE, Aug 2011 PDF icon 000521 & ...

  5. NewPage Demonstration-Scale Biorefinery | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    NewPage Demonstration-Scale Biorefinery The NewPage biorefinery will be added to an existing pulp and paper mill to create renewable biofuels. PDF icon ibrdemonstrationnewpage.pd...

  6. Nationwide: The Nations First Commercial-Scale Biorefineries

    Broader source: Energy.gov [DOE]

    EERE's investment aids in the creation of the first commercial-scale biorefineries in the United States.

  7. Verenium Pilot- and Demonstration-Scale Biorefinery | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Verenium Pilot- and Demonstration-Scale Biorefinery Verenium Pilot- and Demonstration-Scale Biorefinery The Verenium facility will produce ethanol from lignocellulosic agricultural residuals. PDF icon ibr_demonstration_verenium.pdf More Documents & Publications Verenium Biofuels Fact Sheet Pacific Ethanol, Inc Integrated Biorefinery Process

  8. Second-Generation Biofuels from Multi-Product Biorefineries Combine

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Economic Sustainability With Environmental Sustainability | Department of Energy Second-Generation Biofuels from Multi-Product Biorefineries Combine Economic Sustainability With Environmental Sustainability Second-Generation Biofuels from Multi-Product Biorefineries Combine Economic Sustainability With Environmental Sustainability Breakout Session 3B-Integration of Supply Chains III: Algal Biofuels Strategy Second-Generation Biofuels from Multi-Product Biorefineries Combine Economic

  9. Solazyme Pilot-Scale Biorefinery | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solazyme Pilot-Scale Biorefinery Solazyme Pilot-Scale Biorefinery The Solazyme integrated biorefinery will use a heterotrophic algal oil biomanufacturing process to create biofuels. PDF icon ibr_arra_solazyme.pdf More Documents & Publications CX-005693: Categorical Exclusion Determination Algae Biofuels Technology 2013 Peer Review Presnentations-Plenaries

  10. Range Fuels Biorefinery Groundbreaking | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Range Fuels Biorefinery Groundbreaking Range Fuels Biorefinery Groundbreaking November 6, 2007 - 5:00pm Addthis Remarks as Prepared for Secretary Bodman Thank you. And let me say how much it means to have my old friend Vinodh here to introduce me. You are a true pioneer in this industry. I also want to thank Mitch for asking me to be here. It's good to see Tom Dorr from the U.S. Department of Agriculture, our partner in so much of the federal government's biomass research and development and

  11. Biorefinery and Hydrogen Fuel Cell Research

    SciTech Connect (OSTI)

    K.C. Das; Thomas T. Adams; Mark A. Eiteman; John Stickney; Joy Doran Peterson; James R. Kastner; Sudhagar Mani; Ryan Adolphson

    2012-06-12

    In this project we focused on several aspects of technology development that advances the formation of an integrated biorefinery. These focus areas include: [1] establishment of pyrolysis processing systems and characterization of the product oils for fuel applications, including engine testing of a preferred product and its pro forma economic analysis; [2] extraction of sugars through a novel hotwater extaction process, and the development of levoglucosan (a pyrolysis BioOil intermediate); [3] identification and testing of the use of biochar, the coproduct from pyrolysis, for soil applications; [4] developments in methods of atomic layer epitaxy (for efficient development of coatings as in fuel cells); [5] advancement in fermentation of lignocellulosics, [6] development of algal biomass as a potential substrate for the biorefinery, and [7] development of catalysts from coproducts. These advancements are intended to provide a diverse set of product choices within the biorefinery, thus improving the cost effectiveness of the system. Technical effectiveness was demonstrated in the pyrolysis biooil based diesel fuel supplement, sugar extraction from lignocelluose, use of biochar, production of algal biomass in wastewaters, and the development of catalysts. Economic feasibility of algal biomass production systems seems attractive, relative to the other options. However, further optimization in all paths, and testing/demonstration at larger scales are required to fully understand the economic viabilities. The various coproducts provide a clear picture that multiple streams of value can be generated within an integrated biorefinery, and these include fuels and products.

  12. Economy Through Product Diversity: Integrated Biorefineries

    Broader source: Energy.gov [DOE]

    Achieving national energy and climate goals will require an economically viable and environmentally sustainable U.S. bioindustry. A crucial step in developing this industry is to establish integrated biorefineries capable of efficiently converting a broad range of biomass feedstocks into affordable biofuels, biopower, and other products.

  13. Project LIBERTY Biorefinery Starts Cellulosic Ethanol Production

    Broader source: Energy.gov [DOE]

    Project LIBERTY, the nation’s first commercial-scale cellulosic ethanol plant to use corn waste as a feedstock, announced the start of production today. Once operating at full, commercial-scale, the biorefinery in Emmetsburg, Iowa will produce 25 million gallons of cellulosic ethanol per year - enough to avoid approximately 210,000 tons of CO2 emissions annually.

  14. 2009 Integrated Biorefinery Platform Review Report

    SciTech Connect (OSTI)

    Ferrell, John

    2009-12-01

    This document summarizes the recommendations and evaluations provided by an independent external panel of experts at the U.S. Department of Energy Biomass Program‘s Integrated Biorefinery (IBR) platform review meeting, held on February 18–19, 2009, at the Westin National Harbor, National Harbor, Maryland.

  15. Biorefinery and Carbon Cycling Research Project

    SciTech Connect (OSTI)

    Das, K. C., Adams; Thomas, T; Eiteman, Mark A; Kastner, James R; Mani, Sudhagar; Adolphson, Ryan

    2012-06-08

    In this project we focused on several aspects of technology development that advances the formation of an integrated biorefinery. These focus areas include: [ 1] pretreatment of biomass to enhance quality of products from thermochemical conversion; [2] characterization of and development of coproduct uses; [3] advancement in fermentation of lignocellulosics and particularly C5 and C6 sugars simultaneously, and [ 4] development of algal biomass as a potential substrate for the biorefinery. These advancements are intended to provide a diverse set of product choices within the biorefinery, thus improving the cost effectiveness of the system. Technical effectiveness was demonstrated in the thermochemical product quality in the form of lower tar production, simultaneous of use of multiple sugars in fermentation, use ofbiochar in environmental (ammonia adsorption) and agricultural applications, and production of algal biomass in wastewaters. Economic feasibility of algal biomass production systems seems attractive, relative to the other options. However, further optimization in all paths, and testing/demonstration at larger scales are required to fully understand the economic viabilities. The coproducts provide a clear picture that multiple streams of value can be generated within an integrated biorefinery, and these include fuels and products.

  16. Nanoparticle Technology for Biorefinery of Non-Food Source Feedstocks |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Nanoparticle Technology for Biorefinery of Non-Food Source Feedstocks Nanoparticle Technology for Biorefinery of Non-Food Source Feedstocks PDF icon nanoparticle_tech_biorefinery.pdf More Documents & Publications ITP Nanomanufacturing: Nanomanufacturing Portfolio: Manufacturing Processes and Applications to Accelerate Commercial Use of Nanomaterials, January 2011 2015 Peer Review Presentations-Algal Feedstocks National Alliance for Advanced Biofuels and Bioproducts

  17. 2011 Biomass Program Platform Peer Review: Integrated Biorefineries |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Integrated Biorefineries 2011 Biomass Program Platform Peer Review: Integrated Biorefineries "This document summarizes the recommendations and evaluations provided by an independent external panel of experts at the U.S. Department of Energy Biomass Programs Integrated Biorefinery Platform Review meeting, held on February 1...3, 2011, at the U.S. Department of Energy, Washington, D.C." PDF icon 2011_ibr_review.pdf More Documents & Publications 2011 Biomass

  18. 2013 Peer Review Presentations-Integrated Biorefineries | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Integrated Biorefineries 2013 Peer Review Presentations-Integrated Biorefineries The Bioenergy Technologies Office hosted its 2013 Project Peer Review on May 20-24, 2015, at the Hilton Mark Center in Alexandria, Virginia. The presentations from integrated biorefineries session are available to view and download below. For detailed session descriptions and presentation titles, view the 2013 Project Peer Review Program Booklet. PDF icon ibr_cesaek_55101.pdf PDF icon ibr_cherry_5141.pdf

  19. 2014 DOE Biomass Program Integrated Biorefinery Project Comprehensive

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Project Review | Department of Energy 4 DOE Biomass Program Integrated Biorefinery Project Comprehensive Project Review 2014 DOE Biomass Program Integrated Biorefinery Project Comprehensive Project Review Plenary I: Progress in Advanced Biofuels 2014 DOE Biomass Program Integrated Biorefinery Project Comprehensive Project Review Gerson Santos-Leon, Executive Vice President, Abengoa PDF icon santos-leon_biomass_2014.pdf More Documents & Publications Abengoa IBR Successes Applicant

  20. Integrated Biorefinery Lessons Learned and Best Practices | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Lessons Learned and Best Practices Integrated Biorefinery Lessons Learned and Best Practices Breakout Session 1D-Building Market Confidence and Understanding I: Integrated Biorefinery (Lessons Learned and Best Practices) Integrated Biorefinery Lessons Learned and Best Practices Glenn Doyle, Technology Manager, Bioenergy Technologies Office, U.S. Department of Energy PDF icon doyle_biomass_2014.pdf More Documents & Publications Demonstration and Deployment Workshop Day 1 2015 Peer

  1. Algenol Biofuels Inc., Integrated Pilot-Scale Biorefinery | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Algenol Biofuels Inc., Integrated Pilot-Scale Biorefinery Algenol Biofuels Inc., Integrated Pilot-Scale Biorefinery Algenol Biofuels Inc., will create a pilot-scale biorefinery that uses carbon dioxide from algae to create biofuel. PDF icon ibr_arra_algenol.pdf More Documents & Publications EA-1786: Final Environmental Assessment EA-1786: Finding of No Significant Impact Advance Patent Waiver W(A)2011-034

  2. ClearFuels-Rentech Pilot-Scale Biorefinery

    Broader source: Energy.gov [DOE]

    The ClearFuels-Rentech pilot-scale biorefinery will use Fisher-Tropsch gas-to-liquids technology to create diesel and jet fuel.

  3. Grand Opening of Abengoa's Biorefinery: Nation's Third Commercial...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The nation's third commercial-scale cellulosic ethanol biorefinery celebrates its grand opening on October 17, 2014, in Hugoton, Kansas. The Abengoa Bioenergy Biomass of Kansas ...

  4. FOA for the Demonstration of an Integrated Biorefinery System...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Abengoa Bioenergy Biomass of Kansas, LLC FOA for the Demonstration of an Integrated Biorefinery System: Abengoa Bioenergy Biomass of Kansas, LLC FOA for the Demonstration of an ...

  5. Nationwide: The Nation's First Commercial-Scale Biorefineries...

    Broader source: Energy.gov (indexed) [DOE]

    EERE supports 25 integrated biorefineries that are specifically focused on producing cellulosic ethanol, drop-in hydrocarbon biofuel, and bioproducts. As of July 2013, INEOS opened ...

  6. Integrated Biorefinery Research Facility: Advancing Biofuels Technology (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2009-03-01

    The Integrated Biorefinery Research Facility (IBRF) at the National Renewable Energy Laboratory (NREL) expands NREL's cellulosic ethanol research and development and collaboration capabilities.

  7. Advanced and Cellulosic Biofuels and Biorefineries: State of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced and Cellulosic Biofuels and Biorefineries: State of the Industry, Policy and Politics Afternoon Plenary Introduction Brent Erickson, Executive Vice President, BIO PDF icon ...

  8. FOA for the Demonstration of an Integrated Biorefinery System: Abengoa Bioenergy Biomass of Kansas, LLC

    Broader source: Energy.gov [DOE]

    FOA for the Demonstration of an Integrated Biorefinery System: Abengoa Bioenergy Biomass of Kansas, LLC.

  9. U.S. Department of Energy Small-Scale Biorefineries Project Overview |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Small-Scale Biorefineries Project Overview U.S. Department of Energy Small-Scale Biorefineries Project Overview A chart indicating round one and round two selections for the U.S. Department of Energy Small-Scale Biorefineries Project Overview. PDF icon U.S. Department of Energy Small-Scale Biorefineries Project Overview More Documents & Publications U.S. Department of Energy Small-Scale Biorefineries: Project Overview

  10. U.S. Department of Energy Small-Scale Biorefineries: Project Overview |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Small-Scale Biorefineries: Project Overview U.S. Department of Energy Small-Scale Biorefineries: Project Overview Chart that shows which small-scale biorefineries were approved to receive DOE funding in 2008, a summary of their fields of focus, their cost share, and how much DOE is investing in them. PDF icon small_scale_biorefinery_overview.pdf More Documents & Publications U.S. Department of Energy Small-Scale Biorefineries Project Overview

  11. Preprocessing Moist Lignocellulosic Biomass for Biorefinery Feedstocks

    SciTech Connect (OSTI)

    Neal Yancey; Christopher T. Wright; Craig Conner; J. Richard Hess

    2009-06-01

    Biomass preprocessing is one of the primary operations in the feedstock assembly system of a lignocellulosic biorefinery. Preprocessing is generally accomplished using industrial grinders to format biomass materials into a suitable biorefinery feedstock for conversion to ethanol and other bioproducts. Many factors affect machine efficiency and the physical characteristics of preprocessed biomass. For example, moisture content of the biomass as received from the point of production has a significant impact on overall system efficiency and can significantly affect the characteristics (particle size distribution, flowability, storability, etc.) of the size-reduced biomass. Many different grinder configurations are available on the market, each with advantages under specific conditions. Ultimately, the capacity and/or efficiency of the grinding process can be enhanced by selecting the grinder configuration that optimizes grinder performance based on moisture content and screen size. This paper discusses the relationships of biomass moisture with respect to preprocessing system performance and product physical characteristics and compares data obtained on corn stover, switchgrass, and wheat straw as model feedstocks during Vermeer HG 200 grinder testing. During the tests, grinder screen configuration and biomass moisture content were varied and tested to provide a better understanding of their relative impact on machine performance and the resulting feedstock physical characteristics and uniformity relative to each crop tested.

  12. New Biorefinery Will Bring Jobs to Northeastern Oregon

    Broader source: Energy.gov [DOE]

    In northeastern Oregon, ZeaChem, a Colorado-based biofuel company, recently broke ground on a 250,000 gallon integrated cellulosic biorefinery. The technology development project is expected to be operating in 2011.

  13. Wiki-based Techno Economic Analysis of a Lignocellulosic Biorefinery -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Energy Analysis Energy Analysis Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Wiki-based Techno Economic Analysis of a Lignocellulosic Biorefinery Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing Summary JBEI has developed a model for a lignocellulosic biorefinery and posted it on an open wiki, making it the first open and widely accessible tool of its kind. The model can be used to estimate

  14. DOE Announces $160 Million for Biorefinery Construction and Highlights New

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Agricultural Program to Promote Biofuels | Department of Energy 60 Million for Biorefinery Construction and Highlights New Agricultural Program to Promote Biofuels DOE Announces $160 Million for Biorefinery Construction and Highlights New Agricultural Program to Promote Biofuels February 22, 2006 - 12:11pm Addthis Funding Paves the Way for Diversifying America's Energy Mix DECATUR, IL - Energy Secretary Samuel W. Bodman, today announced $160 million in cost-shared funding over three years to

  15. Integrated Biorefineries:Biofuels, Biopower, and Bioproducts | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Integrated Biorefineries:Biofuels, Biopower, and Bioproducts Integrated Biorefineries:Biofuels, Biopower, and Bioproducts The U.S. goal to produce 21 billion gallons of advanced biofuels by 2022 creates an urgent need to bridge the gap between promising research and commercial large-scale production of advanced biofuels. PDF icon ibr_portfolio_overview.pdf More Documents & Publications Biochemical Conversion: Using Hydrolysis, Fermentation, and Catalysis to Make Fuels and

  16. NREL Report Provides Documentation of the Advanced Biorefinery Landscape |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy NREL Report Provides Documentation of the Advanced Biorefinery Landscape NREL Report Provides Documentation of the Advanced Biorefinery Landscape February 25, 2015 - 10:59am Addthis The National Renewable Energy Laboratory (NREL) released a report in January 2015 on the status of the non-starch ethanol and renewable hydrocarbon biofuels industry in the United States. The report, 2013 Survey of Non-Starch Ethanol and Renewable Hydrocarbon Biofuels Producers, is the first

  17. Advanced and Cellulosic Biofuels and Biorefineries: State of the Industry,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Policy and Politics | Department of Energy and Cellulosic Biofuels and Biorefineries: State of the Industry, Policy and Politics Advanced and Cellulosic Biofuels and Biorefineries: State of the Industry, Policy and Politics Afternoon Plenary Introduction Brent Erickson, Executive Vice President, BIO PDF icon b13_erickson_day2-apintro.pdf More Documents & Publications Biomass 2013 Agenda Biomass 2012 Agenda U.S. Biofuels Industry: Mind the Gap

  18. FOA for the Demonstration of an Integrated Biorefinery System: Blue Fire

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ethanol, Inc. | Department of Energy Blue Fire Ethanol, Inc. FOA for the Demonstration of an Integrated Biorefinery System: Blue Fire Ethanol, Inc. FOA for the Demonstration of an Integrated Biorefinery System: Blue Fire Ethanol, Inc. PDF icon Award No. DE-FC36-07GO17025 More Documents & Publications FOA for the Demonstration of an Integrated Biorefinery System: Abengoa Bioenergy Biomass of Kansas, LLC FOA for the Demonstration of an Integrated Biorefinery System: POET Project Liberty,

  19. Preliminary Economics for the Production of Pyrolysis Oil from Lignin in a Cellulosic Ethanol Biorefinery

    SciTech Connect (OSTI)

    Jones, Susanne B.; Zhu, Yunhua

    2009-04-01

    Cellulosic ethanol biorefinery economics can be potentially improved by converting by-product lignin into high valued products. Cellulosic biomass is composed mainly of cellulose, hemicellulose and lignin. In a cellulosic ethanol biorefinery, cellulose and hemicellullose are converted to ethanol via fermentation. The raw lignin portion is the partially dewatered stream that is separated from the product ethanol and contains lignin, unconverted feed and other by-products. It can be burned as fuel for the plant or can be diverted into higher-value products. One such higher-valued product is pyrolysis oil, a fuel that can be further upgraded into motor gasoline fuels. While pyrolysis of pure lignin is not a good source of pyrolysis liquids, raw lignin containing unconverted feed and by-products may have potential as a feedstock. This report considers only the production of the pyrolysis oil and does not estimate the cost of upgrading that oil into synthetic crude oil or finished gasoline and diesel. A techno-economic analysis for the production of pyrolysis oil from raw lignin was conducted. comparing two cellulosic ethanol fermentation based biorefineries. The base case is the NREL 2002 cellulosic ethanol design report case where 2000 MTPD of corn stover is fermented to ethanol (NREL 2002). In the base case, lignin is separated from the ethanol product, dewatered, and burned to produce steam and power. The alternate case considered in this report dries the lignin, and then uses fast pyrolysis to generate a bio-oil product. Steam and power are generated in this alternate case by burning some of the corn stover feed, rather than fermenting it. This reduces the annual ethanol production rate from 69 to 54 million gallons/year. Assuming a pyrolysis oil value similar to Btu-adjusted residual oil, the estimated ethanol selling price ranges from $1.40 to $1.48 (2007 $) depending upon the yield of pyrolysis oil. This is considerably above the target minimum ethanol selling price of $1.33 for the 2012 goal case process as reported in the 2007 State of Technology Model (NREL 2008). Hence, pyrolysis oil does not appear to be an economically attractive product in this scenario. Further research regarding fast pyrolysis of raw lignin from a cellulosic plant as an end product is not recommended. Other processes, such as high-pressure liquefaction or wet gasification, and higher value products, such as gasoline and diesel from fast pyrolysis oil should be considered in future studies.

  20. Membranes Key to Biorefinery Success | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Miming living organisms processes for biorefineries Click to email this to a friend (Opens in new window) Share on Facebook (Opens in new window) Click to share (Opens in new window) Click to share on LinkedIn (Opens in new window) Click to share on Tumblr (Opens in new window) Miming living organisms processes for biorefineries Jimmy Lopez 2015.09.10 Membranes play a key role in the human body, filtering out bacteria and viruses and also ensuring cells absorb essential nutrients. They are

  1. Biomass Program 2007 Peer Review - Integrated Biorefinery Platform Summary

    SciTech Connect (OSTI)

    none,

    2009-10-27

    This document discloses the comments provided by a review panel at the U.S. Department of Energy Office of the Biomass Program Peer Review held on November 15-16, 2007 in Baltimore, MD and the Integrated Biorefinery Platform Review held on August 13-15, 2007 in Golden, Colorado.

  2. EIS-0407: Abengoa Biorefinery Project Near Hugoton, Kansas

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy prepared an environmental impact statement to assess the potential environmental impacts associated with the proposed action of providing Federal financial assistance to Abengoa Bioenergy Biomass of Kansas, LLC (Abengoa Bioenergy) to support the design, construction, and startup of a commercial-scale integrated biorefinery to be located near the city of Hugoton in Stevens County, southwestern Kansas.

  3. Turning Waste Into Fuel: How the INEOS Biorefinery Is Changing the Clean

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Game | Department of Energy Waste Into Fuel: How the INEOS Biorefinery Is Changing the Clean Energy Game Turning Waste Into Fuel: How the INEOS Biorefinery Is Changing the Clean Energy Game February 9, 2011 - 1:40pm Addthis Turning Waste Into Fuel: How the INEOS Biorefinery Is Changing the Clean Energy Game Paul Bryan Biomass Program Manager, Office of Energy Efficiency & Renewable Energy How does it work? Vegetative and agricultural waste reacts with oxygen to produce synthesis

  4. Strategic supply system design - a holistic evaluation of operational and production cost for a biorefinery supply chain

    SciTech Connect (OSTI)

    Lamers, Patrick; Tan, Eric C.D.; Searcy, Erin M.; Scarlata, Christopher J.; Cafferty, Kara G.; Jacobson, Jacob J.

    2015-08-20

    Pioneer cellulosic biorefineries across the United States rely on a conventional feedstock supply system based on one-year contracts with local growers, who harvest, locally store, and deliver feed-stock in low-density format to the conversion facility. While the conventional system is designed for high biomass yield areas, pilot scale operations have experienced feedstock supply shortages and price volatilities due to reduced harvests and competition from other industries. Regional supply dependency and the inability to actively manage feedstock stability and quality, provide operational risks to the biorefinery, which translate into higher investment risk. The advanced feedstock supply system based on a network of depots can mitigate many of these risks and enable wider supply system benefits. This paper compares the two concepts from a system-level perspective beyond mere logistic costs. It shows that while processing operations at the depot increase feedstock supply costs initially, they enable wider system benefits including supply risk reduction (leading to lower interest rates on loans), industry scale-up, conversion yield improvements, and reduced handling equipment and storage costs at the biorefinery. When translating these benefits into cost reductions per liter of gasoline equivalent (LGE), we find that total cost reductions between -$0.46 to -$0.21 per LGE for biochemical and -$0.32 to -$0.12 per LGE for thermochemical conversion pathways are possible. Naturally, these system level benefits will differ between individual actors along the feedstock supply chain. Further research is required with respect to depot sizing, location, and ownership structures.

  5. Strategic supply system design - a holistic evaluation of operational and production cost for a biorefinery supply chain

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lamers, Patrick; Tan, Eric C.D.; Searcy, Erin M.; Scarlata, Christopher J.; Cafferty, Kara G.; Jacobson, Jacob J.

    2015-08-20

    Pioneer cellulosic biorefineries across the United States rely on a conventional feedstock supply system based on one-year contracts with local growers, who harvest, locally store, and deliver feed-stock in low-density format to the conversion facility. While the conventional system is designed for high biomass yield areas, pilot scale operations have experienced feedstock supply shortages and price volatilities due to reduced harvests and competition from other industries. Regional supply dependency and the inability to actively manage feedstock stability and quality, provide operational risks to the biorefinery, which translate into higher investment risk. The advanced feedstock supply system based on a networkmore » of depots can mitigate many of these risks and enable wider supply system benefits. This paper compares the two concepts from a system-level perspective beyond mere logistic costs. It shows that while processing operations at the depot increase feedstock supply costs initially, they enable wider system benefits including supply risk reduction (leading to lower interest rates on loans), industry scale-up, conversion yield improvements, and reduced handling equipment and storage costs at the biorefinery. When translating these benefits into cost reductions per liter of gasoline equivalent (LGE), we find that total cost reductions between -$0.46 to -$0.21 per LGE for biochemical and -$0.32 to -$0.12 per LGE for thermochemical conversion pathways are possible. Naturally, these system level benefits will differ between individual actors along the feedstock supply chain. Further research is required with respect to depot sizing, location, and ownership structures.« less

  6. Secretaries Chu and Vilsack Announce More Than $600 Million Investment in Advanced Biorefinery Projects

    Broader source: Energy.gov [DOE]

    Private company investment brings total to nearly $1.3 billion for 19 biorefinery projects to create jobs and new markets for rural America

  7. Partnering with Industry to Advance Biofuels, NREL's Integrated Biorefinery Research Facility (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2010-10-01

    Fact sheet describing NREL's Integrated Biorefinery Research Facility and its availability to biofuels' industry partners who want to operate, test, and develop biorefining technology and equipment.

  8. ClearFuels-Rentech Integrated Biorefinery Final Report

    SciTech Connect (OSTI)

    Pearson, Joshua

    2014-02-26

    The project Final Report describes the validation of the performance of the integration of two technologies that were proven individually on a pilot scale and were demonstrated as a pilot scale integrated biorefinery. The integrated technologies were a larger scale ClearFuels’ (CF) advanced flexible biomass to syngas thermochemical high efficiency hydrothermal reformer (HEHTR) technology with Rentech’s (RTK) existing synthetic gas to liquids (GTL) technology.

  9. 3.1.1.2 Feed Processing and Handling DL2 Final Report

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Magnuson, Jon K.; Wend, Christopher F.

    2006-09-30

    This milestone report is the deliverable for our Feed Processing and Handling project. It includes results of wet biomass feedstock analysis, slurry pumping information, fungal processing to produce a lignin-rich biorefinery residue and two subcontracted efforts to quantify the amount of wet biomass feedstocks currently available within the corn processing and paper processing industries.

  10. Jobs and Economic Development Impact (JEDI) User Reference Guide: Fast Pyrolysis Biorefinery Model

    SciTech Connect (OSTI)

    Zhang, Y.; Goldberg, M.

    2015-02-01

    This guide -- the JEDI Fast Pyrolysis Biorefinery Model User Reference Guide -- was developed to assist users in operating and understanding the JEDI Fast Pyrolysis Biorefinery Model. The guide provides information on the model's underlying methodology, as well as the parameters and data sources used to develop the cost data utilized in the model. This guide also provides basic instruction on model add-in features and a discussion of how the results should be interpreted. Based on project-specific inputs from the user, the JEDI Fast Pyrolysis Biorefinery Model estimates local (e.g., county- or state-level) job creation, earnings, and output from total economic activity for a given fast pyrolysis biorefinery. These estimates include the direct, indirect and induced economic impacts to the local economy associated with the construction and operation phases of biorefinery projects.Local revenue and supply chain impacts as well as induced impacts are estimated using economic multipliers derived from the IMPLAN software program. By determining the local economic impacts and job creation for a proposed biorefinery, the JEDI Fast Pyrolysis Biorefinery Model can be used to field questions about the added value biorefineries might bring to a local community.

  11. Conceptual design assessment for the co-firing of bio-refinery supplied lignin project. Quarterly report, June 23--July 1, 2000

    SciTech Connect (OSTI)

    Berglund, T.; Ranney, J.T.; Babb, C.L.

    2000-07-27

    The Conceptual Design Assessment for the Co-Firing of Bio-Refinery Supplied Lignin Project was successfully kicked off on July 23, 2000 during a meeting at the TVA-PPI facility in Muscle Shoals, AL. An initial timeline for the study was distributed, issues of concern were identified and a priority actions list was developed. Next steps include meeting with NETL to discuss de-watering and lignin fuel testing, the development of the mass balance model and ethanol facility design criteria, providing TVA-Colbert with preliminary lignin fuel analysis and the procurement of representative feed materials for the pilot and bench scale testing of the hydrolysis process.

  12. EA-1790: DOE Notice of Availability of the Draft Environmental...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE Notice of Availability of the Draft Environmental Assessment Heterogeneous Feed Biorefinery Pontotoc, MS The U.S. Department of Energy (DOE) has prepared a draft Environmental...

  13. U.S. Department of Energy Selects First Round of Small-Scale Biorefinery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Projects for Up to $114 Million in Federal Funding | Department of Energy First Round of Small-Scale Biorefinery Projects for Up to $114 Million in Federal Funding U.S. Department of Energy Selects First Round of Small-Scale Biorefinery Projects for Up to $114 Million in Federal Funding January 29, 2008 - 10:53am Addthis Ten percent commercial-scale biorefineries will help the nation meet new Renewable Fuels Standard WASHINGTON, DC - U.S. Department of Energy (DOE) Secretary Samuel W. Bodman

  14. FOA for the Demonstration of an Integrated Biorefinery System: POET Project

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Liberty, LLC | Department of Energy POET Project Liberty, LLC FOA for the Demonstration of an Integrated Biorefinery System: POET Project Liberty, LLC FOA for the Demonstration of an Integrated Biorefinery System: POET Project Liberty, LLC. PDF icon Award No. DE-FC36-07GO17026, Part 1 PDF icon Award No. DE-FC36-07GO17026, Part 2 PDF icon Technology Investment Agreement (TIA) Award No. DE-FO36-08GO18121 More Documents & Publications FOA for the Demonstration of an Integrated Biorefinery

  15. FOA for the Demonstration of an Integrated Biorefinery System: Range Fuels,

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Inc. | Department of Energy Range Fuels, Inc. FOA for the Demonstration of an Integrated Biorefinery System: Range Fuels, Inc. FOA for the Demonstration of an Integrated Biorefinery System: Range Fuels, Inc. PDF icon Technology Investment Agreement (TIA) Award No. DE-FO36-08GO17027, Part 1 PDF icon Technology Investment Agreement (TIA) Award No. DE-FO36-08GO17027, Part 2 More Documents & Publications FOA for the Demonstration of an Integrated Biorefinery System: POET Project Liberty,

  16. Secretary Bodman Touts Importance of Cellulosic Ethanol at Georgia Biorefinery Groundbreaking

    Broader source: Energy.gov [DOE]

    SOPERTON, GA - U.S. Secretary of Energy Samuel W. Bodman today attended a groundbreaking ceremony for Range Fuels' biorefinery - one of the nation's first commercial-scale cellulosic ethanol...

  17. EA-1705: Construction and Operation of a Proposed Cellulosic Biorefinery, Mascoma Corporation, Kinross Charter Township, Michigan

    Broader source: Energy.gov [DOE]

    The frontier Project consists of the design, construction and operation of a biorefinery producing ethanol and other co-products from cellulosic materials utilizing a proprietary pretreatment and fermentation process.

  18. DOE Selects 3 Small-Scale Biorefinery Projects for up to $86...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    On average, commercial-scale biorefineries input 700 tons of non-food based feedstock per day, with an output of approximately 20-30 million gallons a year (MMGY). These ...

  19. DOE Selects 3 Small-Scale Biorefinery Projects for up to $86 Million of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Federal Funding in Maine, Tennessee and Kentucky | Department of Energy 3 Small-Scale Biorefinery Projects for up to $86 Million of Federal Funding in Maine, Tennessee and Kentucky DOE Selects 3 Small-Scale Biorefinery Projects for up to $86 Million of Federal Funding in Maine, Tennessee and Kentucky April 18, 2008 - 10:49am Addthis Projects Demonstrate Continued Commitment to Advancing Development of Sustainable, Cost-Competitive Cellulosic Ethanol ALEXANDRIA, VA. - U.S. Department of

  20. RSS Feed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RSS Feed Los Alamos National Laboratory RSS Really Simple Syndication feeds providing LANL workers with news directly to your desktop. Los Alamos National Laboratory RSS Subscribe to LANL's RSS (Really Simple Syndication) feeds to get news delivered directly to your desktop! In addition to the feeds listed here, look for the small red feed icons across the site, or the orange auto-discovery icon in your browser bar, to subscribe to other feeds from www.lanl.gov. To view one of the LANL feeds in

  1. Amyris, Inc. Integrated Biorefinery Project Summary Final Report - Public Version

    SciTech Connect (OSTI)

    Gray, David; Sato, Suzanne; Garcia, Fernando; Eppler, Ross; Cherry, Joel

    2014-03-12

    The Amyris pilot-scale Integrated Biorefinery (IBR) leveraged Amyris synthetic biology and process technology experience to upgrade Amyris’s existing Emeryville, California pilot plant and fermentation labs to enable development of US-based production capabilities for renewable diesel fuel and alternative chemical products. These products were derived semi-synthetically from high-impact biomass feedstocks via microbial fermentation to the 15-carbon intermediate farnesene, with subsequent chemical finishing to farnesane. The Amyris IBR team tested and provided methods for production of diesel and alternative chemical products from sweet sorghum, and other high-impact lignocellulosic feedstocks, at pilot scale. This enabled robust techno-economic analysis (TEA), regulatory approvals, and a basis for full-scale manufacturing processes and facility design.

  2. MBI Biorefinery: Corn to Biomass, Ethanol to Biochemicals and Biomaterials

    SciTech Connect (OSTI)

    2006-02-17

    The project is a continuation of DOE-funded work (FY02 and FY03) that has focused on the development of the ammonia fiber explosion (AFEX) pretreatment technology, fermentation production of succinic acid and new processes and products to enhance dry mill profitability. The primary objective for work beginning in April 2004 and ending in November 2005 is focus on the key issues related to the: (1) design, costing and construction plan for a pilot AFEX pretreatment system, formation of a stakeholder development team to assist in the planning and design of a biorefinery pilot plant, continued evaluation of corn fractionation technologies, corn oil extraction, AFEX treatment of corn fiber/DDGs; (2) development of a process to fractionate AFEX-treated corn fiber and corn stover--cellulose and hemicellulose fractionation and sugar recovery; and (3) development of a scalable batch succinic acid production process at 500 L at or below $.42/lb, a laboratory scale fed-batch process for succinic acid production at or below $.40/lb, a recovery process for succinic acid that reduces the cost of succinic acid by $.02/lb and the development of an acid tolerant succinic acid production strain at lab scale (last objective not to be completed during this project time period).

  3. EA-1850: Flambeau River BioFuels, Inc. Proposed Wood Biomass-to-Liquid Fuel Biorefinery, Park Falls, Wisconsin

    Broader source: Energy.gov [DOE]

    NOTE: This EA has been cancelled. This EA will evaluate the environmental impacts of a proposal to provide federal funding to Flambeau River Biofuels (FRB) to construct and operate a biomass-to-liquid biorefinery in Park Falls, Wisconsin, on property currently used by Flambeau Rivers Paper, LLC (FRP) for a pulp and paper mill and Johnson Timber Corporation's (JTC) Summit Lake Yard for timber storage. This project would design a biorefinery which would produce up to 1,150 barrels per day (bpd) of clean syncrude. The biorefinery would also supply steam to the FRP mill, meeting the majority of the mill's steam demand and reducing or eliminating the need for the existing biomass/coal-fired boiler. The biorefinery would also include a steam turbine generator that will produce "green" electrical power for use by the biorefinery or for sale to the electric utility.

  4. Downloads Feed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Power http:www.anl.govdownloadstiny-particles-big-magnetic-power Magnetic nanofibers have wide-ranging applications October 6, 2015 Downloads Feed Harnessing Light in...

  5. RSS Feeds

    Broader source: Energy.gov [DOE]

    The Office of Energy Efficiency and Renewable Energy (EERE) offers RSS feeds covering news and other updates from EERE and its programs. Learn about RSS.

  6. Biomass Biorefinery for the production of Polymers and Fuels

    SciTech Connect (OSTI)

    Dr. Oliver P. Peoples

    2008-05-05

    The conversion of biomass crops to fuel is receiving considerable attention as a means to reduce our dependence on foreign oil imports and to meet future energy needs. Besides their use for fuel, biomass crops are an attractive vehicle for producing value added products such as biopolymers. Metabolix, Inc. of Cambridge proposes to develop methods for producing biodegradable polymers polyhydroxyalkanoates (PHAs) in green tissue plants as well as utilizating residual plant biomass after polymer extraction for fuel generation to offset the energy required for polymer extraction. The primary plant target is switchgrass, and backup targets are alfalfa and tobacco. The combined polymer and fuel production from the transgenic biomass crops establishes a biorefinery that has the potential to reduce the nation’s dependence on foreign oil imports for both the feedstocks and energy needed for plastic production. Concerns about the widespread use of transgenic crops and the grower’s ability to prevent the contamination of the surrounding environment with foreign genes will be addressed by incorporating and expanding on some of the latest plant biotechnology developed by the project partners of this proposal. This proposal also addresses extraction of PHAs from biomass, modification of PHAs so that they have suitable properties for large volume polymer applications, processing of the PHAs using conversion processes now practiced at large scale (e.g., to film, fiber, and molded parts), conversion of PHA polymers to chemical building blocks, and demonstration of the usefulness of PHAs in large volume applications. The biodegradability of PHAs can also help to reduce solid waste in our landfills. If successful, this program will reduce U.S. dependence on imported oil, as well as contribute jobs and revenue to the agricultural economy and reduce the overall emissions of carbon to the atmosphere.

  7. Second-Generation Biofuels from Multi-Product Biorefineries Combine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    model, which is anchored by high-value Omega-3s, permits the profitable production of crude oil & animal feed at market- competitive prices based on current yields, current ...

  8. Advanced Biorefinery of Distriller's Grain and Corn Stover Blends

    SciTech Connect (OSTI)

    2006-04-01

    Fuel ethanol can be produced via the dry milling process, which converts corn grain to ethanol. The co-product, distiller’s grain (DG), is sold as a low-cost, high-protein feed source for livestock.

  9. EERE Energy Impacts: Biorefineries Give Local Farmers Opportunities for Additional Income

    Broader source: Energy.gov [DOE]

    Selling corn stover—the non-edible corn stalks, husks, and leaves of a corn plant—after the corn harvest has generated a new revenue stream for many farmers. Biorefineries buy the corn plant residue from farmers and turn it into cellulosic ethanol, allowing farmers to "add revenue without adding acres."

  10. Grand Opening of Abengoa’s Biorefinery: Nation’s Third Commercial-Scale Facility

    Broader source: Energy.gov [DOE]

    The nation’s third commercial-scale cellulosic ethanol biorefinery celebrates its grand opening on October 17, 2014, in Hugoton, Kansas. The Abengoa Bioenergy Biomass of Kansas (ABBK) facility is the first of its kind to use a proprietary enzymatic hydrolysis process which turns cellulosic biomass into fermentable sugars that are then converted into transportation fuels.

  11. Development of efficient, integrated cellulosic biorefineries : LDRD final report.

    SciTech Connect (OSTI)

    Teh, Kwee-Yan; Hecht, Ethan S.; Shaddix, Christopher R.; Buffleben, George M.; Dibble, Dean C.; Lutz, Andrew E.

    2010-09-01

    Cellulosic ethanol, generated from lignocellulosic biomass sources such as grasses and trees, is a promising alternative to conventional starch- and sugar-based ethanol production in terms of potential production quantities, CO{sub 2} impact, and economic competitiveness. In addition, cellulosic ethanol can be generated (at least in principle) without competing with food production. However, approximately 1/3 of the lignocellulosic biomass material (including all of the lignin) cannot be converted to ethanol through biochemical means and must be extracted at some point in the biochemical process. In this project we gathered basic information on the prospects for utilizing this lignin residue material in thermochemical conversion processes to improve the overall energy efficiency or liquid fuel production capacity of cellulosic biorefineries. Two existing pretreatment approaches, soaking in aqueous ammonia (SAA) and the Arkenol (strong sulfuric acid) process, were implemented at Sandia and used to generated suitable quantities of residue material from corn stover and eucalyptus feedstocks for subsequent thermochemical research. A third, novel technique, using ionic liquids (IL) was investigated by Sandia researchers at the Joint Bioenergy Institute (JBEI), but was not successful in isolating sufficient lignin residue. Additional residue material for thermochemical research was supplied from the dilute-acid simultaneous saccharification/fermentation (SSF) pilot-scale process at the National Renewable Energy Laboratory (NREL). The high-temperature volatiles yields of the different residues were measured, as were the char combustion reactivities. The residue chars showed slightly lower reactivity than raw biomass char, except for the SSF residue, which had substantially lower reactivity. Exergy analysis was applied to the NREL standard process design model for thermochemical ethanol production and from a prototypical dedicated biochemical process, with process data supplied by a recent report from the National Research Council (NRC). The thermochemical system analysis revealed that most of the system inefficiency is associated with the gasification process and subsequent tar reforming step. For the biochemical process, the steam generation from residue combustion, providing the requisite heating for the conventional pretreatment and alcohol distillation processes, was shown to dominate the exergy loss. An overall energy balance with different potential distillation energy requirements shows that as much as 30% of the biomass energy content may be available in the future as a feedstock for thermochemical production of liquid fuels.

  12. EA-1865: Department of Energy Loan Guarantee to Kior, Inc., for Biorefinery Facilities in Georgia, Mississippi, and Texas

    Broader source: Energy.gov [DOE]

    This EA will evaluate the environmental impacts of a proposal to issue a Federal loan guarantee to Kior, Inc., for biorefinery facilities in Georgia, Mississippi, and Texas. This EA is on hold.

  13. Feed Processing, Handling, and Gasification

    SciTech Connect (OSTI)

    2006-04-01

    Both current and future sugar biorefineries will generate a wide variety of residue streams that can be used as feedstocks for thermochemical processes, including corn stover, corn fiber, lignin-rich materials, and distillers dried grain and solubles.

  14. Succinic acid production on xylose-enriched biorefinery streams by Actinobacillus succinogenes in batch fermentation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Salvachua, Davinia; Mohagheghi, Ali; Smith, Holly; Bradfield, Michael F. A.; Nicol, Willie; Black, Brenna A.; Biddy, Mary J.; Dowe, Nancy; Beckham, Gregg T.

    2016-02-02

    Co-production of chemicals from lignocellulosic biomass alongside fuels holds promise for improving the economic outlook of integrated biorefineries. In current biochemical conversion processes that use thermochemical pretreatment and enzymatic hydrolysis, fractionation of hemicellulose-derived and cellulose-derived sugar streams is possible using hydrothermal or dilute acid pretreatment (DAP), which then offers a route to parallel trains for fuel and chemical production from xylose- and glucose-enriched streams. Succinic acid (SA) is a co-product of particular interest in biorefineries because it could potentially displace petroleum-derived chemicals and polymer precursors for myriad applications. Furthermore, SA production from biomass-derived hydrolysates has not yet been fully exploredmore » or developed.« less

  15. Identification and genetic characterization of maize cell wall variation for improved biorefinery feedstock characteristics

    SciTech Connect (OSTI)

    Pauly, Markus; Hake, Sarah

    2013-10-31

    The objectives of this program are to 1) characterize novel maize mutants with altered cell walls for enhanced biorefinery characteristics and 2) find quantitative trait loci (QTLs) related to biorefinery characteristics by taking advantage of the genetic diversity of maize. As a result a novel non-transgenic maize plant (cal1) has been identified, whose stover (leaves and stalk) contain more glucan in their walls leading to a higher saccharification yield, when subjected to a standard enzymatic digestion cocktail. Stacking this trait with altered lignin mutants yielded evene higher saccharification yields. Cal-1 mutants do not show a loss of kernel and or biomass yield when grown in the field . Hence, cal1 biomass provides an excellent feedstock for the biofuel industry.

  16. Simulating Pelletization Strategies to Reduce the Biomass Supply Risk at America’s Biorefineries

    SciTech Connect (OSTI)

    Jacob J. Jacobson; Shane Carnohan; Andrew Ford; Allyson Beall

    2014-07-01

    Demand for cellulosic ethanol and other advanced biofuels has been on the rise, due in part to federal targets enacted in 2005 and extended in 2007. The industry faces major challenges in meeting these worthwhile and ambitious targets. The challenges are especially severe in the logistics of timely feedstock delivery to biorefineries. Logistical difficulties arise from seasonal production that forces the biomass to be stored in uncontrolled field-side environments. In this storage format physical difficulties arise; transportation is hindered by the low bulk density of baled biomass and the unprotected material can decay leading to unpredictable losses. Additionally, uncertain yields and contractual difficulties can exacerbate these challenges making biorefineries a high-risk venture. Investors’ risk could limit business entry and prevent America from reaching the targets. This paper explores pelletizer strategies to convert the lignocellulosic biomass into a denser form more suitable for storage. The densification of biomass would reduce supply risks, and the new system would outperform conventional biorefinery supply systems. Pelletizer strategies exhibit somewhat higher costs, but the reduction in risk is well worth the extra cost if America is to grow the advanced biofuels industry in a sustainable manner.

  17. Controlling Accumulation of Fermentation Inhibitors in Biorefinery Recycle Water Using Microbial Fuel Cells

    SciTech Connect (OSTI)

    Borole, Abhijeet P; Mielenz, Jonathan R; Leak, David; Vishnivetskaya, Tatiana A; Hamilton, Choo Yieng; Andras, Calin

    2009-01-01

    Background Microbial fuel cells (MFC) and microbial electrolysis cells are electrical devices that treat water using microorganisms and convert soluble organic matter into electricity and hydrogen, respectively. Emerging cellulosic biorefineries are expected to use large amounts of water during production of ethanol. Pretreatment of cellulosic biomass results in production of fermentation inhibitors which accumulate in process water and make the water recycle process difficult. Use of MFCs to remove the inhibitory sugar and lignin degradation products from recycle water is investigated in this study. Results Use of an MFC to reduce the levels of furfural, 5-hydroxymethylfurfural, vanillic acid, 4- hydroxybenzaldehyde and 4-hydroxyacetophenone while simultaneously producing electricity is demonstrated here. An integrated MFC design approach was used which resulted in high power densities for the MFC, reaching up to 3700mW/m2 (356W/m3 net anode volume) and a coulombic efficiency of 69%. The exoelectrogenic microbial consortium enriched in the anode was characterized using a 16S rRNA clone library method. A unique exoelectrogenic microbial consortium dominated by -Proteobacteria (50%), along with -Proteobacteria (28%), -Proteobacteria (14%), -Proteobacteria (6%) and others was identified. The consortium demonstrated broad substrate specificity, ability to handle high inhibitor concentrations (5 to 20mM) with near complete removal, while maintaining long-term stability with respect to power production. Conclusions Use of MFCs for removing fermentation inhibitors has implications for: 1) enabling higher ethanol yields at high biomass loading in cellulosic ethanol biorefineries, 2) improved water recycle and 3) electricity production up to 25% of total biorefinery power needs.

  18. Catalytic Hydrothermal Gasification of Lignin-Rich Biorefinery Residues and Algae Final Report

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Neuenschwander, Gary G.; Hart, Todd R.; Rotness, Leslie J.; Zacher, Alan H.; Santosa, Daniel M.; Valkenburt, Corinne; Jones, Susanne B.; Tjokro Rahardjo, Sandra A.

    2009-11-03

    This report describes the results of the work performed by PNNL using feedstock materials provided by the National Renewable Energy Laboratory, KL Energy and Lignol lignocellulosic ethanol pilot plants. Test results with algae feedstocks provided by Genifuel, which provided in-kind cost share to the project, are also included. The work conducted during this project involved developing and demonstrating on the bench-scale process technology at PNNL for catalytic hydrothermal gasification of lignin-rich biorefinery residues and algae. A technoeconomic assessment evaluated the use of the technology for energy recovery in a lignocellulosic ethanol plant.

  19. fed feed families | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    fed feed families

  20. EA-1888: Old Town Fuel and Fiber Proposed Demonstration-Scale Integrated Biorefinery in Old Town, Maine

    Broader source: Energy.gov [DOE]

    This EA evaluates the environmental impacts of a proposal by Old Town Fuel and Fiber to install and operate a demonstration-scale integrated biorefinery at their existing pulp mill in Old Town, Maine, demonstrating the production of n-butanol from lignocellulosic (wood) extract.

  1. Site Feeds - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Site Feeds Site Feeds Calendar Hanford Blog Archive Search Site Feeds Site Index Weather What's New Hanford RSS Feeds Email Email Page | Print Print Page |Text Increase Font Size Decrease Font Size RSS Feed Links Site News RSS Did You Know RSS What's New RSS Event Calendar RSS Recent Videos RSS Press Releases RSS What is a feed? A feed is a document that contains summaries of web content with web links to the original versions. It may be viewed with a feed reader or news aggregator. If you

  2. Departments of Energy, Navy, and Agriculture Invest $210 million in Three Commercial Biorefineries to Produce Drop-in Biofuel for the Military

    Broader source: Energy.gov [DOE]

    In 2014, the U.S. Departments of Energy, Navy, and Agriculture announced that Emerald Biofuels, Fulcrum Energy, and Red Rock Biofuels have been awarded contracts to construct biorefineries capable...

  3. EERE Success Story—Departments of Energy, Navy, and Agriculture Invest $210 million in Three Commercial Biorefineries to Produce Drop-in Biofuel for the Military

    Broader source: Energy.gov [DOE]

    In 2014, the U.S. Departments of Energy, Navy, and Agriculture announced that Emerald Biofuels, Fulcrum Energy, and Red Rock Biofuels have been awarded contracts to construct biorefineries capable...

  4. Integration of Biorefineries and Nuclear Cogeneration Power Plants - A Preliminary Analysis

    SciTech Connect (OSTI)

    Greene, Sherrell R; Flanagan, George F; Borole, Abhijeet P

    2009-03-01

    Biomass-based ethanol and nuclear power are two viable elements in the path to U.S. energy independence. Numerous studies suggest nuclear power could provide a practical carbon-free heat source alternative for the production of biomass-based ethanol. In order for this coupling to occur, it is necessary to examine the interfacial requirements of both nuclear power plants and bioethanol refineries. This report describes the proposed characteristics of a small cogeneration nuclear power plant, a biochemical process-based cellulosic bioethanol refinery, and a thermochemical process-based cellulosic biorefinery. Systemic and interfacial issues relating to the co-location of either type of bioethanol facility with a nuclear power plant are presented and discussed. Results indicate future co-location efforts will require a new optimized energy strategy focused on overcoming the interfacial challenges identified in the report.

  5. Integrated Biorefinery Project: Cooperative Research and Development Final Report, CRADA Number CRD-10-390

    SciTech Connect (OSTI)

    Chapeaux, A.; Schell, D.

    2013-06-01

    The Amyris-NREL CRADA is a sub-project of Amyris?s DOE-funded pilot-scale Integrated Biorefinery (IBR). The primary product of the Amyris IBR is Amyris Renewable Diesel. Secondary products will include lubricants, polymers and other petro-chemical substitutes. Amyris and its project partners will execute on a rapid project to integrate and leverage their collective expertise to enable the conversion of high-impact biomass feedstocks to these advanced, infrastructure-compatible products. The scope of the Amyris-NREL CRADA includes the laboratory development and pilot scale-up of bagasse pretreatment and enzymatic saccharification conditions by NREL for subsequent conversion of lignocellulosic sugar streams to Amyris Diesel and chemical products by Amyris. The CRADA scope also includes a techno-economic analysis of the overall production process of Amyris products from high-impact biomass feedstocks.

  6. Alpena Biorefinery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Comments Demonstrate concentration, hydrolysis, and simultaneous fermentation of five- and six carbon sugars in a near-scale industrial facility. Yes Results from Independent ...

  7. Conversion of residual organics in corn stover-derived biorefinery stream to bioenergy via microbial fuel cell

    SciTech Connect (OSTI)

    Borole, Abhijeet P; Hamilton, Choo Yieng; Schell, Daniel J

    2012-01-01

    A biorefinery process typically uses about 4-10 times as much water as the amount of biofuel generated. The wastewater produced in a biorefinery process contains residual sugars, 5-furfural, phenolics, and other pretreatment and fermentation byproducts. Treatment of the wastewater can reduce the need for fresh water and potentially add to the environmental benefits of the process. Use of microbial fuel cells (MFCs) for conversion of the various organics present in a post-fermentation biorefinery stream is reported here. The organic loading was varied over a wide range to assess removal efficiency, coulombic efficiency and power production. A coulombic efficiency of 40% was observed for a low loading of 1% (0.66 g/L) and decreased to 1.8% for the undiluted process stream (66.4 g/L organic loading). A maximum power density of 1180 mW/m2 was observed at a loading of 8%. Excessive loading was found to result in poor electrogenic performance. The results indicate that operation of an MFC at an intermediate loading using dilution and recirculation of the process stream can enable effective treatment with bioenergy recovery.

  8. Biomass Feed and Gasification

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Biomass Feed and Gasification The Biomass Feed and Gasification Key Technology will advance scientific knowledge of the feeding and conversion of biomass and coal-biomass mixtures as essential upstream steps for production of liquid transportation fuels with a lower net GHG emissions than conventional oil refining. Activities support research for handling and processing of coal-biomass mixtures, ensuring those mixtures are compatible with feed delivery systems, identifying potential impacts on

  9. Pilot-Scale Biorefinery: Sustainable Transport Fuels from Biomass via Integrated Pyrolysis and Catalytic Hydroconversion - Wastewater Cleanup by Catalytic Hydrothermal Gasification

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Olarte, Mariefel V.; Hart, Todd R.

    2015-06-19

    DOE-EE Bioenergy Technologies Office has set forth several goals to increase the use of bioenergy and bioproducts derived from renewable resources. One of these goals is to facilitate the implementation of the biorefinery. The biorefinery will include the production of liquid fuels, power and, in some cases, products. The integrated biorefinery should stand-alone from an economic perspective with fuels and power driving the economy of scale while the economics/profitability of the facility will be dependent on existing market conditions. UOP LLC proposed to demonstrate a fast pyrolysis based integrated biorefinery. Pacific Northwest National Laboratory (PNNL) has expertise in an important technology area of interest to UOP for use in their pyrolysis-based biorefinery. This CRADA project provides the supporting technology development and demonstration to allow incorporation of this technology into the biorefinery. PNNL developed catalytic hydrothermal gasification (CHG) for use with aqueous streams within the pyrolysis biorefinery. These aqueous streams included the aqueous phase separated from the fast pyrolysis bio-oil and the aqueous byproduct streams formed in the hydroprocessing of the bio-oil to finished products. The purpose of this project was to demonstrate a technically and economically viable technology for converting renewable biomass feedstocks to sustainable and fungible transportation fuels. To demonstrate the technology, UOP constructed and operated a pilot-scale biorefinery that processed one dry ton per day of biomass using fast pyrolysis. Specific objectives of the project were to: The anticipated outcomes of the project were a validated process technology, a range of validated feedstocks, product property and Life Cycle data, and technical and operating data upon which to base the design of a full-scale biorefinery. The anticipated long-term outcomes from successful commercialization of the technology were: (1) the replacement of a significant fraction of petroleum based fuels with advanced biofuels, leading to increased energy security and decreased carbon footprint; and (2) establishment of a new biofuel industry segment, leading to the creation of U.S. engineering, manufacturing, construction, operations and agricultural jobs. PNNL development of CHG progressed at two levels. Initial tests were made in the laboratory in both mini-scale and bench-scale continuous flow reactor systems. Following positive results, the next level of evaluation was in the scaled-up engineering development system, which was operated at PNNL.

  10. Final Technical Report: Improvement of Zymomonas mobilis for Commercial Use in Corn-based Biorefineries

    SciTech Connect (OSTI)

    Hitz, William D.

    2010-12-07

    Between 2007 and 2010 DuPont conducted a program under DOE award DE-FC36-07GO17056 to develop and improve Zymomonas mobilis as an ethanologen for commercial use in biorefineries to produce cellulosic ethanol. This program followed upon an earlier DOE funded program in which DuPont, in collaboration with the National Renewable Energy Laboratory (NREL) had developed a Zymomonas strain in conjunction with the development of an integrated cellulosic ethanol process. In the current project, we sought to maximize the utility of Zymomonas by adding the pathway to allow fermentation of the minor sugar arabinose, improve the utilization of xylose, improve tolerance to process hydrolysate and reduce the cost of producing the ethanologen. We undertook four major work streams to address these tasks, employing a range of approaches including genetic engineering, adaptation, metabolite and pathway analysis and fermentation process development. Through this project, we have developed a series of strains with improved characteristics versus the starting strain, and demonstrated robust scalability to at least the 200L scale. By a combination of improved ethanol fermentation yield and titer as well as reduced seed train costs, we have been able to reduce the capital investment and minimum ethanol selling price (MESP) by approximately 8.5% and 11% respectively vs. our starting point. Furthermore, the new strains we have developed, coupled with the learnings of this program, provide a platform for further strain improvements and advancement of cellulosic ethanol technology.

  11. Vertical Integration of Biomass Saccharification of Enzymes for Sustainable Cellulosic Biofuel Production in a Biorefinery

    SciTech Connect (OSTI)

    Manoj Kumar, PhD

    2011-05-09

    Lignocellulosic biomass is the most abundant, least expensive renewable natural biological resource for the production of biobased products and bioenergy is important for the sustainable development of human civilization in 21st century. For making the fermentable sugars from lignocellulosic biomass, a reduction in cellulase production cost, an improvement in cellulase performance, and an increase in sugar yields are all vital to reduce the processing costs of biorefineries. Improvements in specific cellulase activities for non-complexed cellulase mixtures can be implemented through cellulase engineering based on rational design or directed evolution for each cellulase component enzyme, as well as on the reconstitution of cellulase components. In this paper, we will provide DSM's efforts in cellulase research and developments and focus on limitations. Cellulase improvement strategies based on directed evolution using screening on relevant substrates, screening for higher thermal tolerance based on activity screening approaches such as continuous culture using insoluble cellulosic substrates as a powerful selection tool for enriching beneficial cellulase mutants from the large library. We will illustrate why and how thermostable cellulases are vital for economic delivery of bioproducts from cellulosic biomass using biochemical conversion approach.

  12. Fully Integrated Lignocellulosic Biorefinery with Onsite Production of Enzymes and Yeast

    SciTech Connect (OSTI)

    Manoj Kumar, PhD

    2010-06-14

    Lignocellulosic biomass is the most abundant, least expensive renewable natural biological resource for the production of biobased products and bioenergy is important for the sustainable development of human civilization in 21st century. For making the fermentable sugars from lignocellulosic biomass, a reduction in cellulase production cost, an improvement in cellulase performance, and an increase in sugar yields are all vital to reduce the processing costs of biorefineries. Improvements in specific cellulase activities for non-complexed cellulase mixtures can be implemented through cellulase engineering based on rational design or directed evolution for each cellulase component enzyme, as well as on the reconstitution of cellulase components. In this paper, we will provide DSM's efforts in cellulase research and developments and focus on limitations. Cellulase improvement strategies based on directed evolution using screening on relevant substrates, screening for higher thermal tolerance based on activity screening approaches such as continuous culture using insoluble cellulosic substrates as a powerful selection tool for enriching beneficial cellulase mutants from the large library. We will illustrate why and how thermostable cellulases are vital for economic delivery of bioproducts from cellulosic biomass using biochemical conversion approach.

  13. Integrated cellulosic enzymes hydrolysis and fermentative advanced yeast bioconversion solution ready for biomass biorefineries

    SciTech Connect (OSTI)

    Manoj Kumar, PhD

    2011-05-04

    Lignocellulosic biomass is the most abundant, least expensive renewable natural biological resource for the production of biobased products and bioenergy is important for the sustainable development of human civilization in 21st century. For making the fermentable sugars from lignocellulosic biomass, a reduction in cellulase production cost, an improvement in cellulase performance, and an increase in sugar yields are all vital to reduce the processing costs of biorefineries. Improvements in specific cellulase activities for non-complexed cellulase mixtures can be implemented through cellulase engineering based on rational design or directed evolution for each cellulase component enzyme, as well as on the reconstitution of cellulase components. In this paper, we will provide DSM's efforts in cellulase research and developments and focus on limitations. Cellulase improvement strategies based on directed evolution using screening on relevant substrates, screening for higher thermal tolerance based on activity screening approaches such as continuous culture using insoluble cellulosic substrates as a powerful selection tool for enriching beneficial cellulase mutants from the large library. We will illustrate why and how thermostable cellulases are vital for economic delivery of bioproducts from cellulosic biomass using biochemical conversion approach.

  14. Mixed feed evaporator

    DOE Patents [OSTI]

    Vakil, Himanshu B. (Schenectady, NY); Kosky, Philip G. (Ballston Lake, NY)

    1982-01-01

    In the preparation of the gaseous reactant feed to undergo a chemical reaction requiring the presence of steam, the efficiency of overall power utilization is improved by premixing the gaseous reactant feed with water and then heating to evaporate the water in the presence of the gaseous reactant feed, the heating fluid utilized being at a temperature below the boiling point of water at the pressure in the volume where the evaporation occurs.

  15. Biomass Feed and Gasification

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the feeding and conversion of biomass and coal-biomass mixtures as essential upstream ... Activities support research for handling and processing of coal-biomass mixtures, ensuring ...

  16. In The News Feed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    tion-affordable-alternative-platinum

    Microwave heat improves nanostructured molybdenum disulfide catalyst's ability to produce hydrogen.

    October 26, 2015 In The News Feed...

  17. Infectious waste feed system

    DOE Patents [OSTI]

    Coulthard, E. James

    1994-01-01

    An infectious waste feed system for comminuting infectious waste and feeding the comminuted waste to a combustor automatically without the need for human intervention. The system includes a receptacle for accepting waste materials. Preferably, the receptacle includes a first and second compartment and a means for sealing the first and second compartments from the atmosphere. A shredder is disposed to comminute waste materials accepted in the receptacle to a predetermined size. A trough is disposed to receive the comminuted waste materials from the shredder. A feeding means is disposed within the trough and is movable in a first and second direction for feeding the comminuted waste materials to a combustor.

  18. Investigation of thermochemical biorefinery sizing and environmental sustainability impacts for conventional supply system and distributed preprocessing supply system designs

    SciTech Connect (OSTI)

    Muth, jr., David J.; Langholtz, Matthew H.; Tan, Eric; Jacobson, Jacob; Schwab, Amy; Wu, May; Argo, Andrew; Brandt, Craig C.; Cafferty, Kara; Chiu, Yi-Wen; Dutta, Abhijit; Eaton, Laurence M.; Searcy, Erin

    2014-03-31

    The 2011 US Billion-Ton Update estimates that by 2030 there will be enough agricultural and forest resources to sustainably provide at least one billion dry tons of biomass annually, enough to displace approximately 30% of the country's current petroleum consumption. A portion of these resources are inaccessible at current cost targets with conventional feedstock supply systems because of their remoteness or low yields. Reliable analyses and projections of US biofuels production depend on assumptions about the supply system and biorefinery capacity, which, in turn, depend upon economic value, feedstock logistics, and sustainability. A cross-functional team has examined combinations of advances in feedstock supply systems and biorefinery capacities with rigorous design information, improved crop yield and agronomic practices, and improved estimates of sustainable biomass availability. A previous report on biochemical refinery capacity noted that under advanced feedstock logistic supply systems that include depots and pre-processing operations there are cost advantages that support larger biorefineries up to 10 000 DMT/day facilities compared to the smaller 2000 DMT/day facilities. This report focuses on analyzing conventional versus advanced depot biomass supply systems for a thermochemical conversion and refinery sizing based on woody biomass. The results of this analysis demonstrate that the economies of scale enabled by advanced logistics offsets much of the added logistics costs from additional depot processing and transportation, resulting in a small overall increase to the minimum ethanol selling price compared to the conventional logistic supply system. While the overall costs do increase slightly for the advanced logistic supply systems, the ability to mitigate moisture and ash in the system will improve the storage and conversion processes. In addition, being able to draw on feedstocks from further distances will decrease the risk of biomass supply to the conversion facility.

  19. Sustainable and efficient pathways for bioenergy recovery from low-value process streams via bioelectrochemical systems in biorefineries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Borole, Abhijeet P.

    2015-08-25

    Conversion of biomass into bioenergy is possible via multiple pathways resulting in production of biofuels, bioproducts and biopower. Efficient and sustainable conversion of biomass, however, requires consideration of many environmental and societal parameters in order to minimize negative impacts. Integration of multiple conversion technologies and inclusion of upcoming alternatives such as bioelectrochemical systems can minimize these impacts and improve conservation of resources such as hydrogen, water and nutrients via recycle and reuse. This report outlines alternate pathways integrating microbial electrolysis in biorefinery schemes to improve energy efficiency while evaluating environmental sustainability parameters.

  20. Top Value-Added Chemicals from Biomass - Volume IIResults of Screening for Potential Candidates from Biorefinery Lignin

    SciTech Connect (OSTI)

    Holladay, John E.; White, James F.; Bozell, Joseph J.; Johnson, David

    2007-10-01

    This report evaluates lignins role as a renewable raw material resource. Opportunities that arise from utilizing lignin fit into one of three categories: 1)power, fuel and syngas (generally near-term opportunities) 2) macromolecules (generally medium-term opportunities) 3) aromatics and miscellaneous monomers (long-term opportunities). Biorefineries will receive and process massive amounts of lignin. For this reason, how lignin can be best used to support the economic health of the biorefinery must be defined. An approach that only considers process heat would be shortsighted. Higher value products present economic opportunities and the potential to significantly increase the amount of liquid transportation fuel available from biomass. In this analysis a list of potential uses of lignin was compiled and sorted into product types which are broad classifications (listed above as powerfuelsyngas; macromolecules; and aromatics). In the first product type (powerfuelgasification) lignin is used purely as a carbon source and aggressive means are employed to break down its polymeric structure. In the second product type (macromolecules) the opposite extreme is considered and advantage of the macromolecular structure imparted by nature is retained in high-molecular weight applications. The third product type (aromatics) lies somewhere between the two extremes and employs technologies that would break up lignins macromolecular structure but maintain the aromatic nature of the building block molecules. The individual opportunities were evaluated based on their technical difficulty, market, market risk, building block utility, and whether a pure material or a mixture would be produced. Unlike the Sugars Top 10 report it was difficult to identify the ten best opportunities, however, the potential opportunities fell nicely into near-, medium- and long-term opportunities. Furthermore, the near-, medium- and long-term opportunities roughly align with the three product types. From this analysis a list of technical barriers was developed which can be used to identify research needs. Lignin presents many challenges for use in the biorefinery. Chemically it differs from sugars having a complex aromatic substructure. Unlike cellulose, which has a relatively simple substructure of glucose subunits, lignin has a high degree of variability in its structure which differs both from biomass source and from the recovery process used. In addition to its variability lignin is also reactive and to some degree less stable thermally and oxidatively to other biomass streams. What this means is that integrating a lignin process stream within the biorefinery will require identifying the best method to separate lignin from biomass cost-effectively.

  1. Recovery Act. Demonstration of a Pilot Integrated Biorefinery for the Efficient, Direct Conversion of Biomass to Diesel Fuel

    SciTech Connect (OSTI)

    Schuetzle, Dennis; Tamblyn, Greg; Caldwell, Matt; Hanbury, Orion; Schuetzle, Robert; Rodriguez, Ramer; Johnson, Alex; Deichert, Fred; Jorgensen, Roger; Struble, Doug

    2015-05-12

    The Renewable Energy Institute International, in collaboration with Greyrock Energy and Red Lion Bio-Energy (RLB) has successfully demonstrated operation of a 25 ton per day (tpd) nameplate capacity, pilot, pre-commercial-scale integrated biorefinery (IBR) plant for the direct production of premium, “drop-in”, synthetic fuels from agriculture and forest waste feedstocks using next-generation thermochemical and catalytic conversion technologies. The IBR plant was built and tested at the Energy Center, which is located in the University of Toledo Medical Campus in Toledo, Ohio.

  2. Sugar-Based Ethanol Biorefinery: Ethanol, Succinic Acid and By-Product Production

    SciTech Connect (OSTI)

    Donal F. Day

    2009-03-31

    The work conducted in this project is an extension of the developments itemized in DE-FG-36-04GO14236. This program is designed to help the development of a biorefinery based around a raw sugar mill, which in Louisiana is an underutilized asset. Some technical questions were answered regarding the addition of a biomass to ethanol facility to existing sugar mills. The focus of this work is on developing technology to produce ethanol and valuable by-products from bagasse. Three major areas are addressed, feedstock storage, potential by-products and the technology for producing ethanol from dilute ammonia pre-treated bagasse. Sugar mills normally store bagasse in a simple pile. During the off season there is a natural degradation of the bagasse, due to the composting action of microorganisms in the pile. This has serious implications if bagasse must be stored to operate a bagasse/biorefinery for a 300+ day operating cycle. Deterioration of the fermentables in bagasse was found to be 6.5% per month, on pile storage. This indicates that long term storage of adequate amounts of bagasse for year-round operation is probably not feasible. Lignin from pretreatment seemed to offer a potential source of valuable by-products. Although a wide range of phenolic compounds were present in the effluent from dilute ammonia pretreatment, the concentrations of each (except for benzoic acid) were too low to consider for extraction. The cellulosic hydrolysis system was modified to produce commercially recoverable quantities of cellobiose, which has a small but growing market in the food process industries. A spin-off of this led to the production of a specific oligosaccharide which appears to have both medical and commercial implications as a fungal growth inhibitor. An alternate use of sugars produced from biomass hydrolysis would be to produce succinic acid as a chemical feedstock for other conversions. An organism was developed which can do this bioconversion, but the economics of succinic acid production were such that it could not compete with current commercial practice. To allow recovery of commercial amounts of ethanol from bagasse fermentation, research was conducted on high solids loading fermentations (using S. cerevisiae) with commercial cellulase on pretreated material. A combination of SHF/SSF treatment with fed-batch operation allowed fermentation at 30% solids loading. Supplementation of the fermentation with a small amount of black-strap molasses had results beyond expectation. There was an enhancement of conversion as well as production of ethanol levels above 6.0% w/w, which is required both for efficient distillation as well as contaminant repression. The focus of fermentation development was only on converting the cellulose to ethanol, as this yeast is not capable of fermenting both glucose and xylose (from hemicellulose). In anticipation of the future development of such an organism, we screened the commercially available xylanases to find the optimum mix for conversion of both cellulose and hemicellulose. A different mixture than the spezyme/novozyme mix used in our fermentation research was found to be more efficient at converting both cellulose and hemicellulose. Efforts were made to select a mutant of Pichia stipitis for ability to co-ferment glucose and xylose to ethanol. New mutation technology was developed, but an appropriate mutant has not yet been isolated. The ability to convert to stillage from biomass fermentations were determined to be suitable for anaerobic degradation and methane production. An economic model of a current sugar factory was developed in order to provide a baseline for the cost/benefit analysis of adding cellulosic ethanol production.

  3. ORISE: RSS Feeds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RSS Feeds Stay informed of the latest news from the Oak Ridge Institute for Science and Education (ORISE) by signing up for one of our RSS feeds. RSS is short for Really Simple Syndication and it allows ORISE to signal to subscribers when news content has been added to the site. It provides you with the most up-to-date information about those topics that interest you most. To subscribe to one of our feeds, choose an RSS reader-such as Bloglines, SharpReader, or Google Reader-that will allow you

  4. Coal feed lock

    DOE Patents [OSTI]

    Pinkel, I. Irving

    1978-01-01

    A coal feed lock is provided for dispensing coal to a high pressure gas producer with nominal loss of high pressure gas. The coal feed lock comprises a rotor member with a diametral bore therethrough. A hydraulically activated piston is slidably mounted in the bore. With the feed lock in a charging position, coal is delivered to the bore and then the rotor member is rotated to a discharging position so as to communicate with the gas producer. The piston pushes the coal into the gas producer. The rotor member is then rotated to the charging position to receive the next load of coal.

  5. FRACTIONAL CRYSTALLIZATION FEED ENVELOPE

    SciTech Connect (OSTI)

    HERTING DL

    2008-03-19

    Laboratory work was completed on a set of evaporation tests designed to establish a feed envelope for the fractional crystallization process. The feed envelope defines chemical concentration limits within which the process can be operated successfully. All 38 runs in the half-factorial design matrix were completed successfully, based on the qualitative definition of success. There is no feed composition likely to be derived from saltcake dissolution that would cause the fractional crystallization process to not meet acceptable performance requirements. However, some compositions clearly would provide more successful operation than other compositions.

  6. Heterogeneous waste processing

    DOE Patents [OSTI]

    Vanderberg, Laura A.; Sauer, Nancy N.; Brainard, James R.; Foreman, Trudi M.; Hanners, John L.

    2000-01-01

    A combination of treatment methods are provided for treatment of heterogeneous waste including: (1) treatment for any organic compounds present; (2) removal of metals from the waste; and, (3) bulk volume reduction, with at least two of the three treatment methods employed and all three treatment methods emplyed where suitable.

  7. Departments of the Navy, Energy and Agriculture Invest in Construction of Three Biorefineries to Produce Drop-In Biofuel for Military

    Broader source: Energy.gov [DOE]

    As part of a 2011 Presidential directive, the Departments of Navy, Energy, and Agriculture announced today that three companies have been awarded contracts to construct and commission biorefineries capable of producing “drop-in” biofuels to meet the transportation needs of the military and private sector.

  8. Subscribe to RSS Feeds

    Broader source: Energy.gov [DOE]

    The Building Technologies Office RSS (real simple syndication) feed tracks news from the Department of Energy (DOE) and other sources, making it convenient and easy to stay up-to-date with the...

  9. News Releases Feed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    10 cool science and technology stories from Argonne in 2015 http:www.anl.govarticles10-cool-science-and-technology-stories-argonne-2015 December 23, 2015 News Releases Feed...

  10. Feed-in-Tariff

    Broader source: Energy.gov [DOE]

    Note: In August of 2013 the Hawaii Public Utility Commission (PUC) initiated an investigation into the Feed-In-Tariff Program in Docket No. 2013-0194. On December 5th, 2014 the Hawaii PUC issued...

  11. In The News Feed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    -just-won-t-die-1.18685 November 4, 2015 In The News Feed Perspective: The energy-storage revolution http:www.nature.comnaturejournalv526n7575suppfull526S92a.html November...

  12. NERSC User Announcements RSS Feed

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Announcements RSS Feed NERSC User Announcements RSS Feed June 30, 2014 by Richard Gerber NERSC's User Announcements (not these "Featured Announcements") are now available as an RSS...

  13. Dust feed mechanism

    DOE Patents [OSTI]

    Milliman, Edward M. (Benton City, WA)

    1984-01-01

    The invention is a dust feed device for delivery of a uniform supply of dust for long periods of time to an aerosolizing means for production of a dust suspension. The device utilizes at least two tandem containers having spiral brushes within the containers which transport the dust from a supply to the aerosolizer means.

  14. Widget:TwitterFeed | Open Energy Information

    Open Energy Info (EERE)

    TwitterFeed Jump to: navigation, search Twitter feed javascript app. Widget:TwitterFeed Retrieved from "http:en.openei.orgwindex.php?titleWidget:TwitterFeed&oldid416817...

  15. ARM - About RSS Feeds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CenterAbout RSS Feeds Media Contact Hanna Goss hanna-dot-goss-at-pnnl-dot-gov @armnewsteam Field Notes Blog Topics Field Notes110 AGU 3 AMIE 10 ARM Aerial Facility 2 ARM Mobile Facility 1 6 ARM Mobile Facility 2 47 ARM Mobile Facility 3 1 BAECC 1 BBOP 4 ENA 1 GOAMAZON 7 HI-SCALE 3 MAGIC 15 MC3E 17 PECAN 3 SGP 7 STORMVEX 29 TCAP 3 Search News Search Blog News Center All Categories What's this? Social Media Guidance News Center All Categories Features and Releases Facility News Field Notes Blog

  16. Multiple feed powder splitter

    DOE Patents [OSTI]

    Lewis, Gary K. (Los Alamos, NM); Less, Richard M. (Los Alamos, NM)

    2001-01-01

    A device for providing uniform powder flow to the nozzles when creating solid structures using a solid fabrication system such as the directed light fabrication (DLF) process. In the DLF process, gas entrained powders are passed through the focal point of a moving high-power laser light which fuses the particles in the powder to a surface being built up in layers. The invention is a device providing uniform flow of gas entrained powders to the nozzles of the DLF system. The device comprises a series of modular splitters which are slidably interconnected and contain an integral flow control mechanism. The device can take the gas entrained powder from between one to four hoppers and split the flow into eight tubular lines which feed the powder delivery nozzles of the DLF system.

  17. Multiple feed powder splitter

    DOE Patents [OSTI]

    Lewis, Gary K. (Los Alamos, NM); Less, Richard M. (Los Alamos, NM)

    2002-01-01

    A device for providing uniform powder flow to the nozzles when creating solid structures using a solid fabrication system such as the directed light fabrication (DLF) process. In the DLF process, gas entrained powders are passed through the focal point of a moving high-power laser light which fuses the particles in the powder to a surface being built up in layers. The invention is a device providing uniform flow of gas entrained powders to the nozzles of the DLF system. The device comprises a series of modular splitters which are slidably interconnected and contain an integral flow control mechanism. The device can take the gas entrained powder from between one to four hoppers and split the flow into eight tubular lines which feed the powder delivery nozzles of the DLF system.

  18. Investigation of thermochemical biorefinery sizing and environmental sustainability impacts for conventional supply system and distributed pre-processing supply system designs

    SciTech Connect (OSTI)

    David J. Muth, Jr.; Matthew H. Langholtz; Eric C. D. Tan; Jacob J. Jacobson; Amy Schwab; May M. Wu; Andrew Argo; Craig C. Brandt; Kara G. Cafferty; Yi-Wen Chiu; Abhijit Dutta; Laurence M. Eaton; Erin M. Searcy

    2014-08-01

    The 2011 US Billion-Ton Update estimates that by 2030 there will be enough agricultural and forest resources to sustainably provide at least one billion dry tons of biomass annually, enough to displace approximately 30% of the country's current petroleum consumption. A portion of these resources are inaccessible at current cost targets with conventional feedstock supply systems because of their remoteness or low yields. Reliable analyses and projections of US biofuels production depend on assumptions about the supply system and biorefinery capacity, which, in turn, depend upon economic value, feedstock logistics, and sustainability. A cross-functional team has examined combinations of advances in feedstock supply systems and biorefinery capacities with rigorous design information, improved crop yield and agronomic practices, and improved estimates of sustainable biomass availability. A previous report on biochemical refinery capacity noted that under advanced feedstock logistic supply systems that include depots and pre-processing operations there are cost advantages that support larger biorefineries up to 10 000 DMT/day facilities compared to the smaller 2000 DMT/day facilities. This report focuses on analyzing conventional versus advanced depot biomass supply systems for a thermochemical conversion and refinery sizing based on woody biomass. The results of this analysis demonstrate that the economies of scale enabled by advanced logistics offsets much of the added logistics costs from additional depot processing and transportation, resulting in a small overall increase to the minimum ethanol selling price compared to the conventional logistic supply system. While the overall costs do increase slightly for the advanced logistic supply systems, the ability to mitigate moisture and ash in the system will improve the storage and conversion processes. In addition, being able to draw on feedstocks from further distances will decrease the risk of biomass supply to the conversion facility.

  19. Strategic Biorefinery Analysis: Analysis of Biorefineries

    SciTech Connect (OSTI)

    Lynd, L. R.; Wyman, C.; Laser, M.; Johnson, D.; Landucci, R.

    2005-10-01

    Subcontract report prepared by Dartmouth College that identifies and discusses the advantages of producing ethanol in a biomass refinery as compared to a single-product facility.

  20. Reaction Selectivity in Heterogeneous Catalysis

    SciTech Connect (OSTI)

    Somorjai, Gabor A.; Kliewer, Christopher J.

    2009-02-02

    The understanding of selectivity in heterogeneous catalysis is of paramount importance to our society today. In this review we outline the current state of the art in research on selectivity in heterogeneous catalysis. Current in-situ surface science techniques have revealed several important features of catalytic selectivity. Sum frequency generation vibrational spectroscopy has shown us the importance of understanding the reaction intermediates and mechanism of a heterogeneous reaction, and can readily yield information as to the effect of temperature, pressure, catalyst geometry, surface promoters, and catalyst composition on the reaction mechanism. DFT calculations are quickly approaching the ability to assist in the interpretation of observed surface spectra, thereby making surface spectroscopy an even more powerful tool. HP-STM has revealed three vitally important parameters in heterogeneous selectivity: adsorbate mobility, catalyst mobility, and selective site-blocking. The development of size controlled nanoparticles from 0.8 to 10 nm, of controlled shape, and of controlled bimetallic composition has revealed several important variables for catalytic selectivity. Lastly, DFT calculations may be paving the way to guiding the composition choice for multi-metallic heterogeneous catalysis for the intelligent design of catalysts incorporating the many factors of selectivity we have learned.

  1. Feed-in Tariff Resources

    Broader source: Energy.gov [DOE]

    A feed-in tariff (FIT) is an energy-supply policy focused on supporting the development of new renewable power generation. In the United States, FIT policies provide a guarantee to eligible...

  2. NIPSCO- Feed-In Tariff

    Broader source: Energy.gov [DOE]

    NIPSCO is offering a feed-in tariff program for customers who generate electricity from solar, wind, biomass, or new hydroelectric facilities. All NIPSCO electric customers in good standing are...

  3. NIPSCO- Feed-In Tariff

    Broader source: Energy.gov [DOE]

    NIPSCO is offering a feed-in tariff program for customers who generate electricity from solar, wind, or biomass. All NIPSCO electric customers in good standing are eligible for the program....

  4. Rotary powder feed through apparatus

    DOE Patents [OSTI]

    Lewis, Gary K. (Los Alamos, NM); Less, Richard M. (Los Alamos, NM)

    2001-01-01

    A device for increasing the uniformity of solids within a solids fabrication system, such as a direct light fabrication (DLF) system in which gas entrained powders are passed through the focal point of a moving high-power light which fuses the particles in the powder to a surface being built up in layers. The invention provides a feed through interface wherein gas entrained powders input from stationary input lines are coupled to a rotating head of the fabrication system. The invention eliminates the need to provide additional slack in the feed lines to accommodate head rotation, and therefore reduces feed line bending movements which induce non-uniform feeding of gas entrained powder to a rotating head.

  5. The DOE Feeds Families Festival

    Broader source: Energy.gov [DOE]

    Department of Energy employees took a moment to give back to the Washington, D.C. community by holding our first "DOE Feeds Families Festival" outside of the Forrestal Building.

  6. Feds feed Families | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Feds feed Families Feds feed Families September 3, 2014 - 12:27pm Addthis Feds feed Families Feds feed Families September 2, 2014 Feds feed Families Representatives of the Office of Enterprise Assessments delivered more than 1,600 pounds of non-perishable food to the Manna Food Center on September 2, 2014 as part of the 2014 Feds Feed Families campaign. Manna feeds about 3,300 needy families in Montgomery County. Manna also provides food to 48 Montgomery County soup kitchens, food pantries,

  7. Fossil Energy RSS Feeds | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fossil Energy RSS Feeds Fossil Energy RSS Feeds RSS, sometimes known as Really Simple Syndication, is a popular means of sharing content (such as news headlines) without requiring readers to constantly visit a Web site to see what's new. RSS feeds contain headlines and hyperlinks to longer articles or Web pages. RSS feeds from the Office of Fossil Energy provide updates of specific interest to the fossil fuel community. Fossil Energy RSS feeds are free of charge. RSS content can be read using

  8. Apparatus for continuous feed material melting

    DOE Patents [OSTI]

    Surma, Jeffrey E.; Perez, Jr., Joseph M.

    1998-01-01

    The apparatus of the present invention is a melter housing having a pretreat chamber heated with a feed material heater that is partially isolated from a melter chamber. The method of the present invention has the steps of introducing feed material into a pretreat chamber and heating the feed material to a softening temperature of the feed material, and passing the pretreated feed material to a melter chamber.

  9. Thermochemical Conversion- Biorefinery Integration

    Broader source: Energy.gov [DOE]

    Fuels can be produced from bio-oils using processes similar to those found in a petroleum refinery, including hydrotreating and hydrocracking to create green gasoline, an alternative to alcohol...

  10. American Process - Alpena Biorefinery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... must be secured - There must be project management with knowledge of chain supply - Forest management and certification, feedstock gathering and procuring, E, P, C, sugar ...

  11. Fulton Cellulosic Ethanol Biorefinery

    SciTech Connect (OSTI)

    Sumait, Necy; Cuzens, John; Klann, Richard

    2015-07-24

    Final report on work performed by BlueFire on the deployment of acid hydrolysis technology to convert cellulosic waste materials into renewable fuels, power and chemicals in a production facility to be located in Fulton, Mississippi.

  12. Myriant Succinic Acid Biorefinery

    Broader source: Energy.gov [DOE]

    This American Recovery and Reinvestment Act project will focus on the production of bio-succinic acid from a variety of feedstocks.

  13. Feed mechanism and method for feeding minute items

    DOE Patents [OSTI]

    Stringer, Timothy Kent; Yerganian, Simon Scott

    2009-10-20

    A feeding mechanism and method for feeding minute items, such as capacitors, resistors, or solder preforms. The mechanism is adapted to receive a plurality of the randomly-positioned and randomly-oriented extremely small or minute items, and to isolate, orient, and position one or more of the items in a specific repeatable pickup location wherefrom they may be removed for use by, for example, a computer-controlled automated assembly machine. The mechanism comprises a sliding shelf adapted to receive and support the items; a wiper arm adapted to achieve a single even layer of the items; and a pushing arm adapted to push the items into the pickup location. The mechanism can be adapted for providing the items with a more exact orientation, and can also be adapted for use in a liquid environment.

  14. Feed mechanism and method for feeding minute items

    DOE Patents [OSTI]

    Stringer, Timothy Kent; Yerganian, Simon Scott

    2012-11-06

    A feeding mechanism and method for feeding minute items, such as capacitors, resistors, or solder preforms. The mechanism is adapted to receive a plurality of the randomly-positioned and randomly-oriented extremely small or minute items, and to isolate, orient, and position the items in a specific repeatable pickup location wherefrom they may be removed for use by, for example, a computer-controlled automated assembly machine. The mechanism comprises a sliding shelf adapted to receive and support the items; a wiper arm adapted to achieve a single even layer of the items; and a pushing arm adapted to push the items into the pickup location. The mechanism can be adapted for providing the items with a more exact orientation, and can also be adapted for use in a liquid environment.

  15. Waste feed delivery test and evaluation plan

    SciTech Connect (OSTI)

    O'TOOLE, S.M.

    1999-09-30

    This plan documents the Waste Feed Delivery Program test and evaluation planning and implementation approach. The purpose of this document is to define and communicate the Waste Feed Delivery Program Test and Evaluation scope, objectives, planning and implementation approach.

  16. Burco Farm and Feed | Open Energy Information

    Open Energy Info (EERE)

    Owner Burco Farm and Feed Energy Purchaser Burco Farm and Feed Location Independence IA Coordinates 42.5638438, -91.88753486 Show Map Loading map... "minzoom":false,"mappi...

  17. Upgrading of heavy hydrocarbonaceous feeds

    SciTech Connect (OSTI)

    Bhattacharya, A.K.; Storm, D.A.; DeRosa, T.F.

    1995-12-31

    This paper is based on our work in the area of upgrading of heavy hydrocarbonaceous feedstocks. The work involves the development of a method of catalytically hydroconverting a hydrocarbon feed stream containing a substantial quantity of components boiling above about 538{degrees}C to a substantial portion thereof to components boiling below 538{degrees}C. More particularly, an oil-miscible or oil-soluble poly(ether)diol or a derivative thereof and an aromatic additive oil, such as Heavy Cycle Gas oil, are added to a heavy hydrocarbon feed and the mixed stream is contacted at elevated temperatures with a solid catalyst such as a sulfided nickel molybdenum oxide on alumina in the presence of hydrogen under pressure. This method advantageously affords higher conversion to more valuable liquid products containing lower amounts of heteroatoms such as sulfur, substantially eliminates plugging of the hydroconversion reactor, and reduces the amount of insolubles in the total liquid product.

  18. Internal combustion engine fuel feed

    SciTech Connect (OSTI)

    Cochard, P.; Guicherd, C.

    1980-02-19

    In a method and apparatus for controlling the fuel feed to a stratified-charge internal combustion engine, from idle up to the position corresponding with the maximum flow of air, the overall richness (Rg) of the combustible mixture is reduced by acting simultaneously upon the flow of fuel feeding the main chamber and upon the flow of fuel injected into the auxiliary chamber. For higher loads the maximum flow of air is kept constant and rg is increased by continuing to act upon both fuel flows. By keeping the richness of the mixture in the auxiliary chamber substantially constant, it is possible to obtain the best compromise between the performance of the engine and the emission of pollutant gases.

  19. Fluidized bed boiler feed system

    DOE Patents [OSTI]

    Jones, Brian C.

    1981-01-01

    A fluidized bed boiler feed system for the combustion of pulverized coal. Coal is first screened to separate large from small particles. Large particles of coal are fed directly to the top of the fluidized bed while fine particles are first mixed with recycled char, preheated, and then fed into the interior of the fluidized bed to promote char burnout and to avoid elutriation and carryover.

  20. Analysis shows revamp route to naphtha feed

    SciTech Connect (OSTI)

    Aguilar, E.; Ortiz, C.H.; Arzate, E. )

    1988-11-21

    An existing ethylene plant was studied, using a computer-simulated flexibility analysis, to determine the changes required to convert one of the cracking furnaces from ethane feed to naphtha feed. The simulation determined the changes in flow rate, operating temperature, and steam/hydrocarbon ratio that would result from the liquid feed.

  1. Imaging Heterogeneous Ion Transfer: Lithium Ion Quantification...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    October 24, 2014, Research Highlights Imaging Heterogeneous Ion Transfer: Lithium Ion Quantification using Mercury Amalgams as In Situ Electrochemical Probes in Nonaqueous Media ...

  2. Comprehensive Monitoring for Heterogeneous Geographically Distributed...

    Office of Scientific and Technical Information (OSTI)

    Comprehensive Monitoring for Heterogeneous Geographically Distributed Storage Citation ... Sponsoring Org: USDOE Office of Science (SC), High Energy Physics (HEP) (SC-25) Country of ...

  3. Widget:TwitterFeed-CSC | Open Energy Information

    Open Energy Info (EERE)

    TwitterFeed-CSC Jump to: navigation, search Twitter feed related to Geothermal Case Study Challenge Widget:TwitterFeed-CSC Retrieved from "http:en.openei.orgw...

  4. Biomass IBR Fact Sheet: Enerkem

    Broader source: Energy.gov [DOE]

    Enerkems biorefinery in northern Mississippi will convert heterogeneous (mixed) sorted municipal solid waste into ethanol.

  5. Bedload sheets in heterogeneous sediment

    SciTech Connect (OSTI)

    Whiting, P.J.; Dietrich, W.E.; Leopold, L.B.; Drake, T.G.; Shreve, R.L.

    1988-02-01

    Field observations in streams with beds of coarse sand and fine gravel have revealed that bedload moves primarily as thin, migrating accumulations of sediment, and coarse grains cluster at their leading edge. These accumulations are one or two coarse grains high and are much longer (0.2-0.6 m long in sand; 0.5-2.0 m in fine gravel) than their height. The authors propose the term bedload sheet for these features, and the authors argue that they result from an instability inherent to bedload movement of moderately and poorly sorted sediment. In essence, coarse particles in the bedload slow or stop each other, trap finer particles in their interstices, and thus cause the coarse particles to become mobile again. Bedload sheets develop on the stoss side of dunes, causing the dune to advance incrementally with the arrival of each sheet. Successive deposition of coarse sediment from the leading edge followed by fine sediment may generate the grain-size sorting that distinguishes cross-bedding. Available flume experiments and field observations indicate that bedload sheets are a common, but generally unrecognized, feature of heterogeneous sediment transport.

  6. Integrated Waste Feed Delivery Plan - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Documents Integrated Waste Feed Delivery Plan Documents Documents Hanford Site Cleanup Completion Framework Tri-Party Agreement Freedom of Information and Privacy Act Hanford Site Budget Hanford Site Safety Standards DOE - ORP Contracts/Procurements DOE - RL Contracts/Procurements Integrated Waste Feed Delivery Plan Single-Shell Tank Evaluations Deep Vadose Zone 100-F RI/FS Sitewide Probabilistic Seismic Hazard Analysis Environmental Integrated Waste Feed Delivery Plan Email Email Page | Print

  7. Feed Resource Recovery | Open Energy Information

    Open Energy Info (EERE)

    search Name: Feed Resource Recovery Place: Wellesley, Massachusetts Product: Start-up planning to convert waste to fertilizer and biomethane gas. Coordinates: 42.29776,...

  8. 'Lollachilipalooza' benefits Feds Feed Families effort | National...

    National Nuclear Security Administration (NNSA)

    'Lollachilipalooza' benefits Feds Feed Families effort Deputy Secretary of Energy Daniel Poneman led his band, "Yellow Cake," at "Lollachilipalooza" today to benefit DOE's 2014 ...

  9. High voltage feed through bushing

    DOE Patents [OSTI]

    Brucker, J.P.

    1993-04-06

    A feed through bushing for a high voltage diode provides for using compression sealing for all sealing surfaces. A diode assembly includes a central conductor extending through the bushing and a grading ring assembly circumferentially surrounding and coaxial with the central conductor. A flexible conductive plate extends between and compressively seals against the central conductor and the grading ring assembly, wherein the flexibility of the plate allows inner and outer portions of the plate to axially translate for compression sealing against the central conductor and the grading ring assembly, respectively. The inner portion of the plate is bolted to the central conductor for affecting sealing. A compression beam is also bolted to the central conductor and engages the outer portion of the plate to urge the outer portion toward the grading ring assembly to obtain compression sealing therebetween.

  10. Applying Metal-Organic Frameworks in heterogeneous Catalyisis...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metal-Organic Frameworks in heterogeneous Catalyisis To control heterogeneous catalysis at atomic and electronic-level represents one of the most challenge research areas....

  11. Control Heterogeneous Catalysis at Atomic and Electronic-level...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Control Heterogeneous Catalysis at Atomic and Electronic-level Using Intermetallic Compounds Precious metals and metal alloys are important heterogeneous catalysts for renewable...

  12. The Role of Solvent Heterogeneity in Determining the Dispersion...

    Office of Scientific and Technical Information (OSTI)

    The Role of Solvent Heterogeneity in Determining the Dispersion Interaction Between Nanoassemblies Citation Details In-Document Search Title: The Role of Solvent Heterogeneity in ...

  13. Feed rate measuring method and system

    DOE Patents [OSTI]

    Novak, J.L.; Wiczer, J.J.

    1995-12-05

    A system and method are provided for establishing the feed rate of a workpiece along a feed path with respect to a machine device. First and second sensors each having first and second sensing electrodes which are electrically isolated from the workpiece are positioned above, and in proximity to the desired surfaces of the workpiece along a feed path. An electric field is developed between the first and second sensing electrodes of each sensor and capacitance signals are developed which are indicative of the contour of the workpiece. First and second image signals representative of the contour of the workpiece along the feed path are developed by an image processor. The time delay between corresponding portions of the first and second image signals are then used to determine the feed rate based upon the separation of the first and second sensors and the amount of time between corresponding portions of the first and second image signals. 18 figs.

  14. Feed rate measuring method and system

    DOE Patents [OSTI]

    Novak, James L.; Wiczer, James J.

    1995-01-01

    A system and method are provided for establishing the feed rate of a workpiece along a feed path with respect to a machine device. First and second sensors each having first and second sensing electrodes which are electrically isolated from the workpiece are positioned above, and in proximity to the desired surfaces of the workpiece along a feed path. An electric field is developed between the first and second sensing electrodes of each sensor and capacitance signals are developed which are indicative of the contour of the workpiece. First and second image signals representative of the contour of the workpiece along the feed path are developed by an image processor. The time delay between corresponding portions of the first and second image signals are then used to determine the feed rate based upon the separation of the first and second sensors and the amount of time between corresponding portions of the first and second image signals.

  15. National Geo-Database for Biofuel Simulations and Regional Analysis of Biorefinery Siting Based on Cellulosic Feedstock Grown on Marginal Lands

    SciTech Connect (OSTI)

    Izaurralde, Roberto C.; Zhang, Xuesong; Sahajpal, Ritvik; Manowitz, David H.

    2012-04-01

    The goal of this project undertaken by GLBRC (Great Lakes Bioenergy Research Center) Area 4 (Sustainability) modelers is to develop a national capability to model feedstock supply, ethanol production, and biogeochemical impacts of cellulosic biofuels. The results of this project contribute to sustainability goals of the GLBRC; i.e. to contribute to developing a sustainable bioenergy economy: one that is profitable to farmers and refiners, acceptable to society, and environmentally sound. A sustainable bioenergy economy will also contribute, in a fundamental way, to meeting national objectives on energy security and climate mitigation. The specific objectives of this study are to: (1) develop a spatially explicit national geodatabase for conducting biofuel simulation studies and (4) locate possible sites for the establishment of cellulosic ethanol biorefineries. To address the first objective, we developed SENGBEM (Spatially Explicit National Geodatabase for Biofuel and Environmental Modeling), a 60-m resolution geodatabase of the conterminous USA containing data on: (1) climate, (2) soils, (3) topography, (4) hydrography, (5) land cover/ land use (LCLU), and (6) ancillary data (e.g., road networks, federal and state lands, national and state parks, etc.). A unique feature of SENGBEM is its 2008-2010 crop rotation data, a crucially important component for simulating productivity and biogeochemical cycles as well as land-use changes associated with biofuel cropping. ARRA support for this project and to the PNNL Joint Global Change Research Institute enabled us to create an advanced computing infrastructure to execute millions of simulations, conduct post-processing calculations, store input and output data, and visualize results. These computing resources included two components installed at the Research Data Center of the University of Maryland. The first resource was 'deltac': an 8-core Linux server, dedicated to county-level and state-level simulations and PostgreSQL database hosting. The second resource was the DOE-JGCRI 'Evergreen' cluster, capable of executing millions of simulations in relatively short periods. ARRA funding also supported a PhD student from UMD who worked on creating the geodatabases and executing some of the simulations in this study. Using a physically based classification of marginal lands, we simulated production of cellulosic feedstocks from perennial mixtures grown on these lands in the US Midwest. Marginal lands in the western states of the US Midwest appear to have significant potential to supply feedstocks to a cellulosic biofuel industry. Similar results were obtained with simulations of N-fertilized perennial mixtures. A detailed spatial analysis allowed for the identification of possible locations for the establishment of 34 cellulosic ethanol biorefineries with an annual production capacity of 5.6 billion gallons. In summary, we have reported on the development of a spatially explicit national geodatabase to conduct biofuel simulation studies and provided simulation results on the potential of perennial cropping systems to serve as feedstocks for the production of cellulosic ethanol. To accomplish this, we have employed sophisticated spatial analysis methods in combination with the process-based biogeochemical model EPIC. The results of this study will be submitted to the USDOE Bioenergy Knowledge Discovery Framework as a way to contribute to the development of a sustainable bioenergy industry. This work provided the opportunity to test the hypothesis that marginal lands can serve as sources of cellulosic feedstocks and thus contribute to avoid potential conflicts between bioenergy and food production systems. This work, we believe, opens the door for further analysis on the characteristics of cellulosic feedstocks as major contributors to the development of a sustainable bioenergy economy.

  16. Waste feed delivery planning at Hanford

    SciTech Connect (OSTI)

    Certa, Paul J.; West, Elizha B.; Rodriguez, Juissepp S.; Hohl, Ted M.; Larsen, Douglas C.; Ritari, Jaakob S.; Kelly, James W.

    2013-01-10

    The Integrated Waste Feed Delivery Plan (IWFDP) describes how waste feed will be delivered to the Waste Treatment and Immobilization Plant (WTP) to safely and efficiently accomplish the River Protection Project (RPP) mission. The IWFDP, which is integrated with the Baseline Case operating scenario, is comprised of three volumes. Volume 1 - Process Strategy provides an overview of waste feed delivery (WFD) and describes how the WFD system will be used to prepare and deliver feed to the WTP based on the equipment configuration and functional capabilities of the WFD system. Volume 2 - Campaign Plan describes the plans for the first eight campaigns for delivery to the WTP, evaluates projected feed for systematic issues, projects 242-A Evaporator campaigns, and evaluates double-shell tank (DST) space and availability of contingency feed. Volume 3 - Project Plan identifies the scope and timing of the DST and infrastructure upgrade projects necessary to feed the WTP, and coordinates over 30 projectized projects and operational activities that comprise the needed WFD upgrades.

  17. Wetting of a Chemically Heterogeneous Surface

    SciTech Connect (OSTI)

    Frink, L.J.D.; Salinger, A.G.

    1998-11-20

    Theories for inhomogeneous fluids have focused in recent years on wetting, capillary conden- sation, and solvation forces for model systems where the surface(s) is(are) smooth homogeneous parallel plates, cylinders, or spherical drops. Unfortunately natural systems are more likely to be hetaogeneous both in surt%ce shape and surface chemistry. In this paper we discuss the conse- quences of chemical heterogeneity on wetting. Specifically, a 2-dimensional implementation of a nonlocal density functional theory is solved for a striped surface model. Both the strength and range of the heterogeneity are varied. Contact angles are calculated, and phase transitions (both the wetting transition and a local layering transition) are located. The wetting properties of the surface ase shown to be strongly dependent on the nature of the surface heterogeneity. In addition highly ordered nanoscopic phases are found, and the operational limits for formation of ordered or crystalline phases of nanoscopic extent are discussed.

  18. Plasma arc torch with coaxial wire feed

    DOE Patents [OSTI]

    Hooper, Frederick M

    2002-01-01

    A plasma arc welding apparatus having a coaxial wire feed. The apparatus includes a plasma arc welding torch, a wire guide disposed coaxially inside of the plasma arc welding torch, and a hollow non-consumable electrode. The coaxial wire guide feeds non-electrified filler wire through the tip of the hollow non-consumable electrode during plasma arc welding. Non-electrified filler wires as small as 0.010 inches can be used. This invention allows precision control of the positioning and feeding of the filler wire during plasma arc welding. Since the non-electrified filler wire is fed coaxially through the center of the plasma arc torch's electrode and nozzle, the wire is automatically aimed at the optimum point in the weld zone. Therefore, there is no need for additional equipment to position and feed the filler wire from the side before or during welding.

  19. Nantong BIOLUX Bioenergy Protein Feed Co Ltd | Open Energy Information

    Open Energy Info (EERE)

    Nantong BIOLUX Bioenergy Protein Feed Co Ltd Jump to: navigation, search Name: Nantong BIOLUX Bioenergy Protein Feed Co Ltd Place: Nantong, Jiangsu Province, China Product: BIOLUX...

  20. Tank 26 Evaporator Feed Pump Transfer Analysis

    SciTech Connect (OSTI)

    Tamburello, David; Dimenna, Richard; Lee, Si

    2009-02-11

    The transfer of liquid salt solution from Tank 26 to an evaporator is to be accomplished by activating the evaporator feed pump, located approximately 72 inches above the sludge layer, while simultaneously turning on the downcomer. Previously, activation of the evaporator feed pump was an isolated event without any other components running at the same time. An analysis of the dissolved solution transfer has been performed using computational fluid dynamics methods to determine the amount of entrained sludge solids pumped out of the tank to the evaporator with the downcomer turned on. The analysis results showed that, for the maximum and minimum supernate levels in Tank 26 (252.5 and 72 inches above the sludge layer, respectively), the evaporator feed pump will entrain between 0.03 and 0.1 wt% sludge undissolved solids weight fraction into the eductor, respectively, and therefore are an order of magnitude less than the 1.0 wt% undissolved solids loading criteria to feed the evaporator. Lower tank liquid levels, with respect to the sludge layer, result in higher amounts of sludge entrainment due to the increased velocity of the plunging jets from the downcomer and evaporator feed pump bypass as well as decreased dissipation depth. Revision 1 clarifies the analysis presented in Revision 0 and corrects a mathematical error in the calculations for Table 4.1 in Revision 0. However, the conclusions and recommendations of the analysis do not change for Revision 1.

  1. THERMAL ANALYSIS OF WASTE GLASS MELTER FEEDS

    SciTech Connect (OSTI)

    KRUGER AA; HRMA PR; POKORNY R; PIERCE DA

    2011-10-21

    Melter feeds for high-level nuclear waste (HLW) typically contain a large number of constituents that evolve gas on heating, Multiple gas-evolving reactions are both successive and simultaneous, and include the release of chemically bonded water, reactions of nitrates with organics, and reactions of molten salts with solid silica. Consequently, when a sample of a HLW feed is subjected to thermogravimetric analysis (TGA), the rate of change of the sample mass reveals multiple overlapping peaks. In this study, a melter feed, formulated for a simulated high-alumina HLW to be vitrified in the Waste Treatment and Immobilization Plant, currently under construction at the Hanford Site in Washington State, USA, was subjected to TGA. In addition, a modified melter feed was prepared as an all-nitrate version of the baseline feed to test the effect of sucrose addition on the gas-evolving reactions. Activation energies for major reactions were determined using the Kissinger method. The ultimate aim of TGA studies is to obtain a kinetic model of the gas-evolving reactions for use in mathematical modeling of the cold cap as an element of the overall model of the waste-glass melter. In this study, we focused on computing the kinetic parameters of individual reactions without identifying their actual chemistry, The rough provisional model presented is based on the first-order kinetics.

  2. Microgrids and Heterogeneous Power Quality and Reliability

    SciTech Connect (OSTI)

    LaCommare, Kristina; Marnay, Chris

    2007-10-01

    This paper describes two stylized alternative visions of how the power system might evolve to meet future requirements for the high quality electricity service that modern digital economies demand, a supergrids paradigm and a dispersed paradigm. Some of the economics of the dispersed vision are explored, and perspectives are presented on both the choice of homogeneous universal power quality upstream in the electricity supply chain and on the extremely heterogeneous requirements of end-use loads. It is argued that meeting the demanding requirements of sensitive loads by local provision of high quality power may be more cost effective than increasing the quality of universal homogeneous supply upstream in the legacy grid. Finally, the potential role of microgrids in delivering heterogeneous power quality is demonstrated by reference to two ongoing microgrid tests in the U.S. and Japan.

  3. Dedicated heterogeneous node scheduling including backfill scheduling

    DOE Patents [OSTI]

    Wood, Robert R. (Livermore, CA); Eckert, Philip D. (Livermore, CA); Hommes, Gregg (Pleasanton, CA)

    2006-07-25

    A method and system for job backfill scheduling dedicated heterogeneous nodes in a multi-node computing environment. Heterogeneous nodes are grouped into homogeneous node sub-pools. For each sub-pool, a free node schedule (FNS) is created so that the number of to chart the free nodes over time. For each prioritized job, using the FNS of sub-pools having nodes useable by a particular job, to determine the earliest time range (ETR) capable of running the job. Once determined for a particular job, scheduling the job to run in that ETR. If the ETR determined for a lower priority job (LPJ) has a start time earlier than a higher priority job (HPJ), then the LPJ is scheduled in that ETR if it would not disturb the anticipated start times of any HPJ previously scheduled for a future time. Thus, efficient utilization and throughput of such computing environments may be increased by utilizing resources otherwise remaining idle.

  4. Carbon-Based and Carbon-Supported Heterogeneous Catalysts for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon-Based and Carbon-Supported Heterogeneous Catalysts for the Conversion of Biomass Carbon-based heterogeneous catalysts play a central role in the conversion of biomass to...

  5. Heterogeneous Catalysis for Thermochemical Conversion | Bioenergy | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heterogeneous Catalysis for Thermochemical Conversion Our mission is to transform thermal biomass deconstruction products (syngas and pyrolysis oil) into the fuels and chemicals that keep society moving forward. Figure includes three panels. The first pane, labeled single-source precursors, depicts a bis(triphenylphosphine)rhodium(I) carbonyl chloride single-source precursor for producing rhodium phosphide nanoparticles, shown by a vertical line labeled PPh3 at the top, Rh in the middle, and

  6. Computational Spectroscopy of Heterogeneous Interfaces | Argonne Leadership

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Computing Facility Complex interfaces between nanoparticles and a solvent Complex interfaces between nanoparticles and a solvent. N. Brawand, University of Chicago Computational Spectroscopy of Heterogeneous Interfaces PI Name: Giulia Galli PI Email: gagalli@uchicago.edu Institution: University of Chicago Allocation Program: INCITE Allocation Hours at ALCF: 150 Million Year: 2016 Research Domain: Materials Science The interfaces between solids, nanoparticles and liquids play a fundamental

  7. Low-level waste feed staging plan

    SciTech Connect (OSTI)

    Certa, P.J.; Grams, W.H.; McConville, C.M.; L. W. Shelton, L.W.; Slaathaug, E.J., Westinghouse Hanford

    1996-08-12

    The `Preliminary Low-Level Waste Feed Staging Plan` was updated to reflect the latest requirement in the Tank Waste Remediation Privatization Request for Proposals (RFP) and amendments. The updated plan develops the sequence and transfer schedule for retrieval of DST supernate by the management and integration contractor and delivery of the staged supernate to the private low-activity waste contractors for treatment. Two DSTs are allocated as intermediate staging tanks. A transfer system conflict analysis provides part of the basis for determining transfer system upgrade requirements to support both low-activity and high-level waste feed delivery. The intermediate staging tank architecture and retrieval system equipment are provided as a planning basis until design requirements documents are prepared. The actions needed to successfully implement the plan are identified. These include resolution of safety issues and changes to the feed envelope limits, minimum order quantities, and desired batch sizes.

  8. Blog Feed: Vehicles | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Blog Feed: Vehicles Blog Feed: Vehicles RSS March 1, 2016 Our latest infographic explains how heavy-duty trucks are more getting more sustainable thanks to the Energy Department's SuperTruck initiative. | Infographic by <a href="/node/1332956">Carly Wilkins</a>, Energy Department. INFOGRAPHIC: How SuperTruck is Making Heavy Duty Vehicles More Efficient How the Energy Department's SuperTruck initiative is making America's heavy duty trucks more sustainable. December 30, 2015

  9. Compressor bleed cooling fluid feed system

    DOE Patents [OSTI]

    Donahoo, Eric E; Ross, Christopher W

    2014-11-25

    A compressor bleed cooling fluid feed system for a turbine engine for directing cooling fluids from a compressor to a turbine airfoil cooling system to supply cooling fluids to one or more airfoils of a rotor assembly is disclosed. The compressor bleed cooling fluid feed system may enable cooling fluids to be exhausted from a compressor exhaust plenum through a downstream compressor bleed collection chamber and into the turbine airfoil cooling system. As such, the suction created in the compressor exhaust plenum mitigates boundary layer growth along the inner surface while providing flow of cooling fluids to the turbine airfoils.

  10. TANK 26 EVAPORATOR FEED PUMP TRANSFER ANALYSIS

    SciTech Connect (OSTI)

    Tamburello, D; Si Lee, S; Richard Dimenna, R

    2008-09-30

    The transfer of liquid salt solution from Tank 26 to an evaporator is to be accomplished by activating the evaporator feed pump, located approximately 72 inches above the sludge layer, while simultaneously turning on the downcomer. Previously, activation of the evaporator feed pump was an isolated event without any other components running at the same time. An analysis of the dissolved solution transfer has been performed using computational fluid dynamics methods to determine the amount of entrained sludge solids pumped out of the tank to the evaporator with the downcomer turned on. The analysis results showed that, for the maximum and minimum supernate levels in Tank 26 (252.5 and 72 inches above the sludge layer, respectively), the evaporator feed pump will entrain between 0.05 and 0.1 wt% sludge solids weight fraction into the eductor, respectively. Lower tank liquid levels, with respect to the sludge layer, result in higher amounts of sludge entrainment due to the increased velocity of the plunging jets from the downcomer and evaporator feed pump bypass as well as decreased dissipation depth.

  11. TANK 32 EVAPORATOR FEED PUMP TRANSFER ANALYSIS

    SciTech Connect (OSTI)

    Tamburello, D; Richard Dimenna, R; Si Lee, S

    2009-01-27

    The transfer of liquid salt solution from Tank 32 to an evaporator is to be accomplished by activating the evaporator feed pump, with the supernate surface at a minimum height of approximately 74.4 inches above the sludge layer, while simultaneously turning on the downcomer with a flow rate of 110 gpm. Previously, activation of the evaporator feed pump was an isolated event without any other components running at the same time. An analysis of the dissolved solution transfer has been performed using computational fluid dynamics (CFD) methods to determine the amount of entrained sludge solids pumped out of the tank toward the evaporator with the downcomer turned on. The analysis results shows that, for the minimum tank liquid level of 105 inches above the tank bottom (which corresponds to a liquid depth of 74.4 inches above the sludge layer), the evaporator feed pump will contain less than 0.1 wt% sludge solids in the discharge stream, which is an order of magnitude less than the 1.0 wt% undissolved solids (UDS) loading criteria to feed the evaporator. Lower liquid levels with respect to the sludge layer will result in higher amounts of sludge entrainment due to the increased plunging jet velocity from the downcomer disturbing the sludge layer.

  12. Injectivity Testing for Vapour Dominated Feed Zones

    SciTech Connect (OSTI)

    Clotworthy, A.W.; Hingoyon, C.S.

    1995-01-01

    Wells with vapor dominated feed zones yield abnormal pressure data. This is caused by the condensation of vapor during water injection. A revised injectivity test procedure currently applied by PNOC at the Leyte Geothermal Power Project has improved the injectivity test results.

  13. Compression device for feeding a waste material to a reactor

    DOE Patents [OSTI]

    Williams, Paul M.; Faller, Kenneth M.; Bauer, Edward J.

    2001-08-21

    A compression device for feeding a waste material to a reactor includes a waste material feed assembly having a hopper, a supply tube and a compression tube. Each of the supply and compression tubes includes feed-inlet and feed-outlet ends. A feed-discharge valve assembly is located between the feed-outlet end of the compression tube and the reactor. A feed auger-screw extends axially in the supply tube between the feed-inlet and feed-outlet ends thereof. A compression auger-screw extends axially in the compression tube between the feed-inlet and feed-outlet ends thereof. The compression tube is sloped downwardly towards the reactor to drain fluid from the waste material to the reactor and is oriented at generally right angle to the supply tube such that the feed-outlet end of the supply tube is adjacent to the feed-inlet end of the compression tube. A programmable logic controller is provided for controlling the rotational speed of the feed and compression auger-screws for selectively varying the compression of the waste material and for overcoming jamming conditions within either the supply tube or the compression tube.

  14. Integrated Corn-Based Biorefinery

    Broader source: Energy.gov [DOE]

    This fact sheet summarizes a U.S. Department of Energy Biomass Program research and development project.

  15. USDA- Repowering Assistance Biorefinery Program

    Broader source: Energy.gov [DOE]

    The reimbursement amounts vary and are determined by the availability of funds, the project scope, and the ability of the proposed project to meet all the scoring criteria. In particular reimburs...

  16. Solazyme Pilot-Scale Biorefinery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    In Solazyme's process, algae grow efficiently in the dark in industrial fermentation vessels to very high cell densities. They ingest and metabolize carbon substrates provided in ...

  17. Sapphire Energy - Integrated Algal Biorefinery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... * Produced over 2,000 gallons of crude oil * Upgraded bio crude oil to produce on ... algae for 29 months in Columbus, New Mexico Produced Green Crude for 24 months in Las ...

  18. UOP Pilot-Scale Biorefinery

    Broader source: Energy.gov [DOE]

    This project by UOP will leverage two commercially proven core technologies, pyrolysis and hydroconversion, into an integrated platform.

  19. HIGH TEMPERATURE, HIGH POWER HETEROGENEOUS NUCLEAR REACTOR

    DOE Patents [OSTI]

    Hammond, R.P.; Wykoff, W.R.; Busey, H.M.

    1960-06-14

    A heterogeneous nuclear reactor is designed comprising a stationary housing and a rotatable annular core being supported for rotation about a vertical axis in the housing, the core containing a plurality of radial fuel- element supporting channels, the cylindrical empty space along the axis of the core providing a central plenum for the disposal of spent fuel elements, the core cross section outer periphery being vertically gradated in radius one end from the other to provide a coolant duct between the core and the housing, and means for inserting fresh fuel elements in the supporting channels under pressure and while the reactor is in operation.

  20. Heterogeneously integrated microsystem-on-a-chip

    DOE Patents [OSTI]

    Chanchani, Rajen

    2008-02-26

    A microsystem-on-a-chip comprises a bottom wafer of normal thickness and a series of thinned wafers can be stacked on the bottom wafer, glued and electrically interconnected. The interconnection layer comprises a compliant dielectric material, an interconnect structure, and can include embedded passives. The stacked wafer technology provides a heterogeneously integrated, ultra-miniaturized, higher performing, robust and cost-effective microsystem package. The highly integrated microsystem package, comprising electronics, sensors, optics, and MEMS, can be miniaturized both in volume and footprint to the size of a bottle-cap or less.

  1. High pressure electrical insulated feed thru connector

    DOE Patents [OSTI]

    Oeschger, Joseph E.; Berkeland, James E.

    1979-11-13

    A feed-thru type hermetic electrical connector including at least one connector pin feeding through an insulator block within the metallic body of the connector shell. A compression stop arrangement coaxially disposed about the insulator body is brazed to the shell, and the shoulder on the insulator block bears against this top in a compression mode, the high pressure or internal connector being at the opposite end of the shell. Seals between the pin and an internal bore at the high pressure end of the insulator block and between the insulator block and the metallic shell at the high pressure end are hermetically brazed in place, the first of these also functioning to transfer the axial compressive load without permitting appreciable shear action between the pin and insulator block.

  2. Crude oil as refinery feed stock

    SciTech Connect (OSTI)

    Boduszynski, M.M.; Farrell, T.R.

    1995-12-31

    This paper gives a brief overview of the integrated oil refinery. It illustrates that crude oil refining involves {open_quotes}molecular tailoring,{close_quotes} where feed stock molecules are {open_quotes}tailored{close_quotes} through catalytic processing to make products with the most desirable composition. Chemical composition of crude oil as refinery feed stock is discussed. The emphasis is on the understanding of molecular transformations which occur in refinery processes to manufacture light transportation fuels. Diesel fuel manufacturing is used as an example. Recent environmental legislation in the United States has necessitated a significant upgrade in the quality of diesel fuel used for highway transportation. Examples are given to illustrate the impact that petroleum chemistry may have on the industry`s response to government regulations.

  3. Energy Saver RSS Subscribers: Update Your Feed Address | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy RSS Subscribers: Update Your Feed Address Energy Saver RSS Subscribers: Update Your Feed Address September 28, 2015 - 12:46pm Addthis Just a short administrative note for Energy Saver RSS subscribers: our feed address is changing. To continue reading the Energy Saver Blog through your RSS feed reader, please update the link in your reader to http://energy.gov/rss/energysaver/1280681. Thanks for reading and subscribing to Energy Saver! Addthis Related Articles The Energy Savers Blog

  4. International Renewable Energy Agency (IRENA) Feed | Open Energy...

    Open Energy Info (EERE)

    International Renewable Energy Agency (IRENA) Feed Jump to: navigation, search Home | About | Inventory | Partnerships | Capacity Building | Webinars | Reports | Events | News |...

  5. 2013 Feds Feed Families: Your Generosity Counts | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3 Feds Feed Families: Your Generosity Counts 2013 Feds Feed Families: Your Generosity Counts July 2, 2013 - 5:58pm Addthis (L to R) Kevin Knobloch, DOE Chief of Staff; Fletcher Honemond, Chief Learning Officer; Doug Keeler, Feds Feeds Families National Program Manager; Ella Daniels of the Capital Area Food Bank; Jennifer Hirschorn; Rauland Sharp, 2013 Feds Feeds Families Deputy Champion. | Photo courtesy of Ella Daniels. (L to R) Kevin Knobloch, DOE Chief of Staff; Fletcher Honemond, Chief

  6. Feed-In Tariffs and similar programs

    Reports and Publications (EIA)

    2013-01-01

    Feed-in tariffs (FITs) are a policy mechanism used to encourage deployment of renewable electricity technologies. FITs are used to a limited extent around the United States as listed. A FIT program typically guarantees that customers who own a FIT-eligible renewable electricity generation facility, such as a roof-top solar photovoltaic system, will receive a set price from their utility for all of the electricity they generate and provide to the grid.

  7. Heterogeneous Catalyst for Improved Selectivity of Biomass-Derived

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Molecules - Energy Innovation Portal Biomass and Biofuels Biomass and Biofuels Advanced Materials Advanced Materials Find More Like This Return to Search Heterogeneous Catalyst for Improved Selectivity of Biomass-Derived Molecules University of Colorado Contact CU About This Technology Publications: PDF Document Publication CU2380B (Heterogenous Catalyst) Marketing Summary (137 KB) Technology Marketing Summary In today's industrial processes, heterogeneous catalysts are widely used because

  8. Assessing the relative permeability of heterogeneous reservoir rock

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Conference: Assessing the relative permeability of heterogeneous reservoir rock Citation Details In-Document Search Title: Assessing the relative permeability of heterogeneous reservoir rock Reservoir engineers are often faced with heterogeneous core material, for which conventional methods of estimating relative permeability are susceptible to error and may lead to incorrect conclusions regarding displacement efficiency, wettability and reservoir performance.

  9. Effect of heterogeneous aqueous reactions on the secondary formation of

    Office of Scientific and Technical Information (OSTI)

    inorganic aerosols during haze events (Journal Article) | SciTech Connect Effect of heterogeneous aqueous reactions on the secondary formation of inorganic aerosols during haze events Citation Details In-Document Search This content will become publicly available on September 30, 2016 Title: Effect of heterogeneous aqueous reactions on the secondary formation of inorganic aerosols during haze events In this study, the effect of heterogeneous aqueous reactions on the secondary formation of

  10. Dynamics on modular networks with heterogeneous correlations

    SciTech Connect (OSTI)

    Melnik, Sergey; Oxford Centre for Industrial and Applied Mathematics, Mathematical Institute, University of Oxford, Oxford OX2 6GG; CABDyN Complexity Centre, University of Oxford, Oxford OX1 1HP ; Porter, Mason A.; CABDyN Complexity Centre, University of Oxford, Oxford OX1 1HP ; Mucha, Peter J.; Institute for Advanced Materials, Nanoscience and Technology, University of North Carolina, Chapel Hill, North Carolina 27599-3216 ; Gleeson, James P.

    2014-06-15

    We develop a new ensemble of modular random graphs in which degree-degree correlations can be different in each module, and the inter-module connections are defined by the joint degree-degree distribution of nodes for each pair of modules. We present an analytical approach that allows one to analyze several types of binary dynamics operating on such networks, and we illustrate our approach using bond percolation, site percolation, and the Watts threshold model. The new network ensemble generalizes existing models (e.g., the well-known configuration model and Lancichinetti-Fortunato-Radicchi networks) by allowing a heterogeneous distribution of degree-degree correlations across modules, which is important for the consideration of nonidentical interacting networks.

  11. Comprehensive Monitoring for Heterogeneous Geographically Distributed Storage

    SciTech Connect (OSTI)

    Ratnikova, N.; Karavakis, E.; Lammel, S.; Wildish, T.

    2015-12-23

    Storage capacity at CMS Tier-1 and Tier-2 sites reached over 100 Petabytes in 2014, and will be substantially increased during Run 2 data taking. The allocation of storage for the individual users analysis data, which is not accounted as a centrally managed storage space, will be increased to up to 40%. For comprehensive tracking and monitoring of the storage utilization across all participating sites, CMS developed a space monitoring system, which provides a central view of the geographically dispersed heterogeneous storage systems. The first prototype was deployed at pilot sites in summer 2014, and has been substantially reworked since then. In this paper we discuss the functionality and our experience of system deployment and operation on the full CMS scale.

  12. Accelerating Subsurface Transport Simulation on Heterogeneous Clusters

    SciTech Connect (OSTI)

    Villa, Oreste; Gawande, Nitin A.; Tumeo, Antonino

    2013-09-23

    Reactive transport numerical models simulate chemical and microbiological reactions that occur along a flowpath. These models have to compute reactions for a large number of locations. They solve the set of ordinary differential equations (ODEs) that describes the reaction for each location through the Newton-Raphson technique. This technique involves computing a Jacobian matrix and a residual vector for each set of equation, and then solving iteratively the linearized system by performing Gaussian Elimination and LU decomposition until convergence. STOMP, a well known subsurface flow simulation tool, employs matrices with sizes in the order of 100x100 elements and, for numerical accuracy, LU factorization with full pivoting instead of the faster partial pivoting. Modern high performance computing systems are heterogeneous machines whose nodes integrate both CPUs and GPUs, exposing unprecedented amounts of parallelism. To exploit all their computational power, applications must use both the types of processing elements. For the case of subsurface flow simulation, this mainly requires implementing efficient batched LU-based solvers and identifying efficient solutions for enabling load balancing among the different processors of the system. In this paper we discuss two approaches that allows scaling STOMP's performance on heterogeneous clusters. We initially identify the challenges in implementing batched LU-based solvers for small matrices on GPUs, and propose an implementation that fulfills STOMP's requirements. We compare this implementation to other existing solutions. Then, we combine the batched GPU solver with an OpenMP-based CPU solver, and present an adaptive load balancer that dynamically distributes the linear systems to solve between the two components inside a node. We show how these approaches, integrated into the full application, provide speed ups from 6 to 7 times on large problems, executed on up to 16 nodes of a cluster with two AMD Opteron 6272 and a Tesla M2090 per node.

  13. Performance Modeling for 3D Visualization in a Heterogeneous...

    Office of Scientific and Technical Information (OSTI)

    The analytic models are shown to be accurate on a testbed of distributed heterogeneous systems. The prediction methodology will form the foundation of a more robust resource ...

  14. Plane wave method for elastic wave scattering by a heterogeneous...

    Office of Scientific and Technical Information (OSTI)

    Plane wave method for elastic wave scattering by a heterogeneous fracture Citation Details In-Document Search Title: Plane wave method for elastic wave scattering by a ...

  15. Simulation of CO2 Sequestration at Rock Spring Uplift, Wyoming: Heterogeneity and Uncertainties in Storage Capacity, Injectivity and Leakage

    SciTech Connect (OSTI)

    Deng, Hailin; Dai, Zhenxue; Jiao, Zunsheng; Stauffer, Philip H.; Surdam, Ronald C.

    2011-01-01

    Many geological, geochemical, geomechanical and hydrogeological factors control CO{sub 2} storage in subsurface. Among them heterogeneity in saline aquifer can seriously influence design of injection wells, CO{sub 2} injection rate, CO{sub 2} plume migration, storage capacity, and potential leakage and risk assessment. This study applies indicator geostatistics, transition probability and Markov chain model at the Rock Springs Uplift, Wyoming generating facies-based heterogeneous fields for porosity and permeability in target saline aquifer (Pennsylvanian Weber sandstone) and surrounding rocks (Phosphoria, Madison and cap-rock Chugwater). A multiphase flow simulator FEHM is then used to model injection of CO{sub 2} into the target saline aquifer involving field-scale heterogeneity. The results reveal that (1) CO{sub 2} injection rates in different injection wells significantly change with local permeability distributions; (2) brine production rates in different pumping wells are also significantly impacted by the spatial heterogeneity in permeability; (3) liquid pressure evolution during and after CO{sub 2} injection in saline aquifer varies greatly for different realizations of random permeability fields, and this has potential important effects on hydraulic fracturing of the reservoir rock, reactivation of pre-existing faults and the integrity of the cap-rock; (4) CO{sub 2} storage capacity estimate for Rock Springs Uplift is 6614 {+-} 256 Mt at 95% confidence interval, which is about 36% of previous estimate based on homogeneous and isotropic storage formation; (5) density profiles show that the density of injected CO{sub 2} below 3 km is close to that of the ambient brine with given geothermal gradient and brine concentration, which indicates CO{sub 2} plume can sink to the deep before reaching thermal equilibrium with brine. Finally, we present uncertainty analysis of CO{sub 2} leakage into overlying formations due to heterogeneity in both the target saline aquifer and surrounding formations. This uncertainty in leakage will be used to feed into risk assessment modeling.

  16. Fuel cell with electrolyte feed system

    DOE Patents [OSTI]

    Feigenbaum, Haim (Highland Park, NJ)

    1984-01-01

    A fuel cell having a pair of electrodes at the sites of electrochemical reactions of hydrogen and oxygen and a phosphoric acid electrolyte provided with an electrolyte supporting structure in the form of a laminated matrix assembly disposed between the electrodes. The matrix assembly is formed of a central layer disposed between two outer layers, each being permeable to the flow of the electrolyte. The central layer is provided with relatively large pores while the outer layers are provided with relatively small pores. An external reservoir supplies electrolyte via a feed means to the central layer to compensate for changes in electrolyte volume in the matrix assembly during the operation of fuel cell.

  17. The generation of efficient supported (Heterogeneous) olefin metathesis catalysts

    SciTech Connect (OSTI)

    Grubbs, Robert H

    2013-04-05

    Over the past decade, a new family of homogeneous metathesis catalysts has been developed that will tolerate most organic functionalities as well as water and air. These homogeneous catalysts are finding numerous applications in the pharmaceutical industry as well as in the production of functional polymers. In addition the catalysts are being used to convert seed oils into products that can substitute for those that are now made from petroleum products. Seed oils are unsaturated, contain double bonds, and are a ready source of linear hydrocarbon fragments that are specifically functionalized. To increase the number of applications in the area of biomaterial conversion to petrol chemicals, the activity and efficiency of the catalysts need to be as high as possible. The higher the efficiency of the catalysts, the lower the cost of the conversion and a larger number of practical applications become available. Active supported catalysts were prepared and tested in the conversion of seed oils and other important starting materials. The outcome of the work was successful and the technology has been transferred to a commercial operation to develop viable applications of the discovered systems. A biorefinery that converts seed oils is under construction in Indonesia. The catalysts developed in this study will be considered for the next generation of operations.

  18. RSS and Podcast News Feeds | OSTI, US Dept of Energy, Office of Scientific

    Office of Scientific and Technical Information (OSTI)

    and Technical Information RSS and Podcast News Feeds Use OSTI's RSS/Podcast feeds to Get OSTI news, announcements, and product or service updates delivered directly to your desktop or MP3 player. Subscribe to OSTI RSS News and Podcast Feeds: Copy and paste the appropriate URL in your feed reader OSTI News Feed OSTI News Feed http://www.osti.gov/home/sites/www.osti.gov.home/files/imported/newsfeeds/rss-osti.xml OSTI News Feed OSTI Blog News Feed

  19. Coordinated Collaboration between Heterogeneous Distributed Energy Resources

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Abdollahy, Shahin; Lavrova, Olga; Mammoli, Andrea

    2014-01-01

    A power distribution feeder, where a heterogeneous set of distributed energy resources is deployed, is examined by simulation. The energy resources include PV, battery storage, natural gas GenSet, fuel cells, and active thermal storage for commercial buildings. The resource scenario considered is one that may exist in a not too distant future. Two cases of interaction between different resources are examined. One interaction involves a GenSet used to partially offset the duty cycle of a smoothing battery connected to a large PV system. The other example involves the coordination of twenty thermal storage devices, each associated with a commercial building.more » Storage devices are intended to provide maximum benefit to the building, but it is shown that this can have a deleterious effect on the overall system, unless the action of the individual storage devices is coordinated. A network based approach is also introduced to calculate some type of effectiveness metric to all available resources which take part in coordinated operation. The main finding is that it is possible to achieve synergy between DERs on a system; however this required a unified strategy to coordinate the action of all devices in a decentralized way.« less

  20. NNSA Administrator Kicks Off DOE's 'Feds Feed Families' Campaign |

    Energy Savers [EERE]

    Department of Energy Administrator Kicks Off DOE's 'Feds Feed Families' Campaign NNSA Administrator Kicks Off DOE's 'Feds Feed Families' Campaign June 16, 2011 - 12:00am Addthis WASHINGTON, D.C. - National Nuclear Security Administration (NNSA) Administrator Thomas P. D'Agostino today helped the Department of Energy (DOE) kick off its third annual "Feds Feed Families" campaign to assist local food banks in replenishing supplies during the summer months. DOE and NNSA, in partnership

  1. Feeding Arteries of Primary Tongue Cancers on Intra-arterial...

    Office of Scientific and Technical Information (OSTI)

    on Intra-arterial Infusion Chemotherapy Citation Details In-Document Search Title: Feeding Arteries of Primary Tongue Cancers on Intra-arterial Infusion Chemotherapy PurposeTo ...

  2. The Children's Investment Fund Foundation Feed | Open Energy...

    Open Energy Info (EERE)

    The Children's Investment Fund Foundation Feed Jump to: navigation, search Home | About | Inventory | Partnerships | Capacity Building | Webinars | Reports | Events | News | List...

  3. Evaluation of the intermittent GTA cold wire feed weld system

    SciTech Connect (OSTI)

    Dereskiewicz, J.P.

    1991-08-01

    An intermittent gas tungsten arc cold wire feed process was statistically evaluated to determine the feasibility of applying this process to meet the 0.030-inch weld penetration and peak temperature requirements when unfavorable joint tolerances exist on a subassembly weld. The wire feed system was determined to only slightly benefit the welding process over normal pulsed gas tungsten arc welding using traditional wire feeding capabilities. However, the complexity of this process and extensive welding operator training and qualification does not outweigh the benefits of incorporating this synchronized pulse wire feed system in production. 2 refs., 43 figs., 11 tabs.

  4. National Renewable Energy Laboratory Feed | Open Energy Information

    Open Energy Info (EERE)

    Renewable Energy Laboratory Feed Jump to: navigation, search Home | About | Inventory | Partnerships | Capacity Building | Webinars | Reports | Events | News | List Serve CLEAN...

  5. Feed'Pump Hydraulic Performance and Design Improvement, Phase...

    Office of Scientific and Technical Information (OSTI)

    ... UVA464761MAE78150, Department of Mechanical and Aerospace Engi- neering, School of ... UPDATING OF STANDARDS FOR FEED PUMP APPLICATIONS 29.1 Introduction A review and ...

  6. International Atomic Energy Agency Feed | Open Energy Information

    Open Energy Info (EERE)

    Institute (WRI) World Watch Institute International Atomic Energy Agency Feed Nuclear Safety is a Continuum, not a Final Destination

    "There's this continuum with regard...

  7. NNSA Production Office tops Feds Feed Families campaign goal...

    National Nuclear Security Administration (NNSA)

    tops Feds Feed Families campaign goal | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation...

  8. Effect of Bubbles and Silica Dissolution on Melter Feed Rheology...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Effect of Bubbles and Silica Dissolution on Melter Feed Rheology during Conversion to Glass Citation Details In-Document Search Title: Effect of Bubbles and Silica ...

  9. Drone Detection, Video Feed Interception and Pilot Locating System...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Drone Detection, Video Feed Interception and Pilot Locating System The invention provides the capability of detecting commercially available and custom homemade remotely operated...

  10. Automatic feed system for ultrasonic machining

    DOE Patents [OSTI]

    Calkins, Noel C.

    1994-01-01

    Method and apparatus for ultrasonic machining in which feeding of a tool assembly holding a machining tool toward a workpiece is accomplished automatically. In ultrasonic machining, a tool located just above a workpiece and vibrating in a vertical direction imparts vertical movement to particles of abrasive material which then remove material from the workpiece. The tool does not contact the workpiece. Apparatus for moving the tool assembly vertically is provided such that it operates with a relatively small amount of friction. Adjustable counterbalance means is provided which allows the tool to be immobilized in its vertical travel. A downward force, termed overbalance force, is applied to the tool assembly. The overbalance force causes the tool to move toward the workpiece as material is removed from the workpiece.

  11. Department of Energy Manual 435.1-1 Waste Incidental To Reprocessing Determination For The West Valley Demonstration Project Concentrator Feed Makeup Tank and Melter Feed Hold Tank

    Broader source: Energy.gov [DOE]

    Department of Energy Manual 435.1-1 Waste Incidental To Reprocessing Determination For The West Valley Demonstration Project Concentrator Feed Makeup Tank and Melter Feed Hold Tank

  12. Discrete Feature Approach for Heterogeneous Reservoir Production Enhancement

    SciTech Connect (OSTI)

    Dershowitz, William S.; Curran, Brendan; Einstein, Herbert; LaPointe, Paul; Shuttle, Dawn; Klise, Kate

    2002-07-26

    The report presents summaries of technology development for discrete feature modeling in support of the improved oil recovery (IOR) for heterogeneous reservoirs. In addition, the report describes the demonstration of these technologies at project study sites.

  13. Ganglion dynamics of Supercritical CO2 in heterogeneous media. (Conference)

    Office of Scientific and Technical Information (OSTI)

    | SciTech Connect Ganglion dynamics of Supercritical CO2 in heterogeneous media. Citation Details In-Document Search Title: Ganglion dynamics of Supercritical CO2 in heterogeneous media. Abstract not provided. Authors: Wang, Yifeng Publication Date: 2015-04-01 OSTI Identifier: 1247107 Report Number(s): SAND2015-2548C 579865 DOE Contract Number: AC04-94AL85000 Resource Type: Conference Resource Relation: Conference: Proposed for presentation at the CFSES Carbon Sequestration PI meetings held

  14. Hot spot-derived shock initiation phenomena in heterogeneous nitromethane

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Conference: Hot spot-derived shock initiation phenomena in heterogeneous nitromethane Citation Details In-Document Search Title: Hot spot-derived shock initiation phenomena in heterogeneous nitromethane The addition of solid silica particles to gelled nitromethane offers a tractable model system for interrogating the role of impedance mismatches as one type of hot spot 'seed' on the initiation behaviors of explosive formulations. Gas gun-driven plate impact

  15. Performance Modeling for 3D Visualization in a Heterogeneous Computing

    Office of Scientific and Technical Information (OSTI)

    Environment (Technical Report) | SciTech Connect Performance Modeling for 3D Visualization in a Heterogeneous Computing Environment Citation Details In-Document Search Title: Performance Modeling for 3D Visualization in a Heterogeneous Computing Environment The visualization of large, remotely located data sets necessitates the development of a distributed computing pipeline in order to reduce the data, in stages, to a manageable size. The required baseline infrastructure for launching such

  16. The Role of Solvent Heterogeneity in Determining the Dispersion Interaction

    Office of Scientific and Technical Information (OSTI)

    Between Nanoassemblies (Journal Article) | SciTech Connect The Role of Solvent Heterogeneity in Determining the Dispersion Interaction Between Nanoassemblies Citation Details In-Document Search Title: The Role of Solvent Heterogeneity in Determining the Dispersion Interaction Between Nanoassemblies Understanding fundamental nanoassembly processes on intermediate scales beween the molecular and the continuum requires an in-depth analysis of the coupling between particle interactions and

  17. Chemical Heterogeneity of a Large Cluster CP IDP: Clues to its...

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Conference: Chemical Heterogeneity of a Large Cluster CP ... Citation Details In-Document Search Title: Chemical Heterogeneity of a Large Cluster CP ...

  18. Apparatus and method for feeding coal into a coal gasifier

    DOE Patents [OSTI]

    Bissett, Larry A.; Friggens, Gary R.; McGee, James P.

    1979-01-01

    This invention is directed to a system for feeding coal into a gasifier operating at high pressures. A coal-water slurry is pumped to the desired pressure and then the coal is "dried" prior to feeding the coal into the gasifier by contacting the slurry with superheated steam in an entrained bed dryer for vaporizing the water in the slurry.

  19. Waste feed delivery program systems engineering implementation plan

    SciTech Connect (OSTI)

    O`Toole, S.M.

    1998-09-24

    This document defines the systems engineering processes and products planned by the Waste Feed Delivery Program to develop the necessary and sufficient systems to provide waste feed to the Privatization Contractor for Phase 1. It defines roles and responsibilities for the performance of the systems engineering processes and generation of products.

  20. Inline evenflow material distributor for pneumatic material feed systems

    DOE Patents [OSTI]

    Thiry, Michael J. (Oakdale, CA)

    2007-02-20

    An apparatus for reducing clogs in a pneumatic material feed line, such as employed in abrasive waterjet machining systems, by providing an evenflow feed of material therethrough. The apparatus preferably includes a hollow housing defining a housing volume and having an inlet capable of connecting to an upstream portion of the pneumatic material feed line, an outlet capable of connecting to a downstream portion of the pneumatic material feed line, and an air vent located between the inlet and outlet for venting excess air pressure out from the housing volume. A diverter, i.e. an impingement object, is located at the inlet and in a path of incoming material from the upstream portion of the pneumatic material feed line, to break up clumps of ambient moisture-ridden material impinging on the diverter. And one or more filter screens is also preferably located in the housing volume to further break up clumps and provide filtering.

  1. BLACK HOLE FORAGING: FEEDBACK DRIVES FEEDING

    SciTech Connect (OSTI)

    Dehnen, Walter; King, Andrew, E-mail: wd11@leicester.ac.uk, E-mail: ark@astro.le.ac.uk [Theoretical Astrophysics Group, University of Leicester, Leicester LE1 7RH (United Kingdom)] [Theoretical Astrophysics Group, University of Leicester, Leicester LE1 7RH (United Kingdom)

    2013-11-10

    We suggest a new picture of supermassive black hole (SMBH) growth in galaxy centers. Momentum-driven feedback from an accreting hole gives significant orbital energy, but little angular momentum to the surrounding gas. Once central accretion drops, the feedback weakens and swept-up gas falls back toward the SMBH on near-parabolic orbits. These intersect near the black hole with partially opposed specific angular momenta, causing further infall and ultimately the formation of a small-scale accretion disk. The feeding rates into the disk typically exceed Eddington by factors of a few, growing the hole on the Salpeter timescale and stimulating further feedback. Natural consequences of this picture include (1) the formation and maintenance of a roughly toroidal distribution of obscuring matter near the hole; (2) random orientations of successive accretion disk episodes; (3) the possibility of rapid SMBH growth; (4) tidal disruption of stars and close binaries formed from infalling gas, resulting in visible flares and ejection of hypervelocity stars; (5) super-solar abundances of the matter accreting on to the SMBH; and (6) a lower central dark-matter density, and hence annihilation signal, than adiabatic SMBH growth implies. We also suggest a simple subgrid recipe for implementing this process in numerical simulations.

  2. Corn fiber hulls as a food additive or animal feed

    DOE Patents [OSTI]

    Abbas, Charles; Beery, Kyle E.; Cecava, Michael J.; Doane, Perry H.

    2010-12-21

    The present invention provides a novel animal feed or food additive that may be made from thermochemically hydrolyzed, solvent-extracted corn fiber hulls. The animal feed or food additive may be made, for instance, by thermochemically treating corn fiber hulls to hydrolyze and solubilize the hemicellulose and starch present in the corn fiber hulls to oligosaccharides. The residue may be extracted with a solvent to separate the oil from the corn fiber, leaving a solid residue that may be prepared, for instance by aggolmerating, and sold as a food additive or an animal feed.

  3. State-of-the-art in Heterogeneous Computing

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Brodtkorb, Andre R.; Dyken, Christopher; Hagen, Trond R.; Hjelmervik, Jon M.; Storaasli, Olaf O.

    2010-01-01

    Node level heterogeneous architectures have become attractive during the last decade for several reasons: compared to traditional symmetric CPUs, they offer high peak performance and are energy and/or cost efficient. With the increase of fine-grained parallelism in high-performance computing, as well as the introduction of parallelism in workstations, there is an acute need for a good overview and understanding of these architectures. We give an overview of the state-of-the-art in heterogeneous computing, focusing on three commonly found architectures: the Cell Broadband Engine Architecture, graphics processing units (GPUs), and field programmable gate arrays (FPGAs). We present a review of hardware, availablemore » software tools, and an overview of state-of-the-art techniques and algorithms. Furthermore, we present a qualitative and quantitative comparison of the architectures, and give our view on the future of heterogeneous computing.« less

  4. LADWP- Feed-in Tariff (FiT) Program

    Broader source: Energy.gov [DOE]

    LADWP is providing a Feed-in Tariff (FiT) program to support the development of renewable energy projects in its territory. All technologies eligible for compliance with the state's renewables po...

  5. PSEG Long Island- Solar Initiative Feed-in Tariff

    Broader source: Energy.gov [DOE]

    The PSEG Long Island Feed-in Tariff II (FIT II) program provides fixed payments for electricity produced by approved photovoltaic systems over a fixed period of time. The program operates under a...

  6. Time phased alternate blending of feed coals for liquefaction

    DOE Patents [OSTI]

    Schweigharett, Frank; Hoover, David S.; Garg, Diwaker

    1985-01-01

    The present invention is directed to a method for reducing process performance excursions during feed coal or process solvent changeover in a coal hydroliquefaction process by blending of feedstocks or solvents over time. ,

  7. The Effect of Foaming and Silica Dissolution on Melter Feed Rheology...

    Office of Scientific and Technical Information (OSTI)

    As the nuclear waste glass melter feed is converted to molten glass, the feed eventually ... Resource Type: Conference Resource Relation: Conference: Waste Management 2014 (WM2014 ...

  8. Modeling aspects of the dynamic response of heterogeneous materials

    SciTech Connect (OSTI)

    Ionita, Axinte; Clements, Brad; Mas, Eric

    2009-01-01

    In numerical simulations of engineering applications involving heterogeneous materials capturing the local response coming from a distribution of heterogeneities can lead to a very large model thus making simulations difficult. The use of homogenization techniques can reduce the size of the problem but will miss the local effects. Homogenization can also be difficult if the constituents obey different types of constitutive laws. Additional complications arise if inelastic deformation. In such cases a two-scale approach is prefened and tills work addresses these issues in the context of a two-scale Finite Element Method (FEM). Examples of using two-scale FEM approaches are presented.

  9. RSS Feeds | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    RSS Feeds Subscribe to EIA's RSS Feeds Subscribe RSS Today in Energy Short, timely articles with graphics on energy facts, issues, and trends. RSS What's New Notification of new EIA products as they are released. RSS EIA Radio Provides free short broadcast stories on EIA energy data reports and analysis to radio stations nationwide. RSS Press Releases Receive EIA press releases RSS Energy in Brief Articles that explain important energy topics in plain language. Each Brief answers a question

  10. RSS Feeds - U.S. Energy Information Administration (EIA)

    U.S. Energy Information Administration (EIA) Indexed Site

    RSS Feeds Subscribe to EIA's RSS Feeds Subscribe RSS Today in Energy Short, timely articles with graphics on energy facts, issues, and trends. RSS What's New Notification of new EIA products as they are released. RSS EIA Radio Provides free short broadcast stories on EIA energy data reports and analysis to radio stations nationwide. RSS Press Releases Receive EIA press releases RSS Energy in Brief Articles that explain important energy topics in plain language. Each Brief answers a question

  11. Tank Waste Feed Delivery System Readiness at the Hanford Site

    Energy Savers [EERE]

    Audit Report Tank Waste Feed Delivery System Readiness at the Hanford Site OAS-L-12-09 August 2012 Department of Energy Washington, DC 20585 August 23, 2012 MEMORANDUM FOR THE MANAGER, OFFICE OF RIVER PROTECTION FROM: David Sedillo, Director Western Audits Division Office of Audits and Inspections Office of Inspector General SUBJECT: INFORMATION: Audit Report on "Tank Waste Feed Delivery System Readiness at the Hanford Site" BACKGROUND The Department of Energy's largest cleanup task

  12. The Energy Department Feeds Families | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Energy Department Feeds Families The Energy Department Feeds Families August 13, 2015 - 2:35pm Addthis Oak Ridge Integrated Support Center employees Josh Clark (from left), Steve Martin, Katelynn Prutsman, Tom Rizzi and Hailey Beeler gave employees ice cream from a make-shift "ice cream truck" in exchange for non-perishable items. They even dressed the part! | Photo courtesy of Oak Ridge Integrated Support Center. Oak Ridge Integrated Support Center employees Josh Clark (from

  13. At tank Low Activity Feed Homogeneity Analysis Verification

    SciTech Connect (OSTI)

    DOUGLAS, J.G.

    2000-09-28

    This report evaluates the merit of selecting sodium, aluminum, and cesium-137 as analytes to indicate homogeneity of soluble species in low-activity waste (LAW) feed and recommends possible analytes and physical properties that could serve as rapid screening indicators for LAW feed homogeneity. The three analytes are adequate as screening indicators of soluble species homogeneity for tank waste when a mixing pump is used to thoroughly mix the waste in the waste feed staging tank and when all dissolved species are present at concentrations well below their solubility limits. If either of these conditions is violated, then the three indicators may not be sufficiently chemically representative of other waste constituents to reliably indicate homogeneity in the feed supernatant. Additional homogeneity indicators that should be considered are anions such as fluoride, sulfate, and phosphate, total organic carbon/total inorganic carbon, and total alpha to estimate the transuranic species. Physical property measurements such as gamma profiling, conductivity, specific gravity, and total suspended solids are recommended as possible at-tank methods for indicating homogeneity. Indicators of LAW feed homogeneity are needed to reduce the U.S. Department of Energy, Office of River Protection (ORP) Program's contractual risk by assuring that the waste feed is within the contractual composition and can be supplied to the waste treatment plant within the schedule requirements.

  14. Tank Farms and Waste Feed Delivery - 12507

    SciTech Connect (OSTI)

    Fletcher, Thomas; Charboneau, Stacy; Olds, Erik

    2012-07-01

    The mission of the Department of Energy's Office of River Protection (ORP) is to safely retrieve and treat the 56 million gallons of Hanford's tank waste and close the Tank Farms to protect the Columbia River. Our discussion of the Tank Farms and Waste Feed Delivery will cover progress made to date with Base and Recovery Act funding in reducing the risk posed by tank waste and in preparing for the initiation of waste treatment at Hanford. The millions of gallons of waste are a by-product of decades of plutonium production. After irradiated fuel rods were taken from the nuclear reactors to the processing facilities at Hanford they were exposed to a series of chemicals designed to dissolve away the rod, which enabled workers to retrieve the plutonium. Once those chemicals were exposed to the fuel rods they became radioactive and extremely hot. They also couldn't be used in this process more than once. Because the chemicals are caustic and extremely hazardous to humans and the environment, underground storage tanks were built to hold these chemicals until a more permanent solution could be found. The underground storage tanks range in capacity from 55,000 gallons to more than 1 million gallons. The tanks were constructed with carbon steel and reinforced concrete. There are eighteen groups of tanks, called 'tank farms', some having as few as two tanks and others up to sixteen tanks. Between 1943 and 1964, 149 single-shell tanks were built at Hanford in the 200 West and East Areas. Heat generated by the waste and the composition of the waste caused an estimated 67 of these single-shell tanks to leak into the ground. Washington River Protection Solutions is the prime contractor responsible for the safe management of this waste. WRPS' mission is to reduce the risk to the environment that is posed by the waste. All of the pumpable liquids have been removed from the single-shell tanks and transferred to the double-shell tanks. What remains in the single-shell tanks are solid and semi-solid wastes. Known as salt-cakes, they have the consistency of wet beach sand. Some of the waste resembles small broken ice, or whitish crystals. Because the original pumps inside the tanks were designed to remove only liquid waste, other methods have been developed to reach the remaining waste. Access to the tank waste is through long, typically skinny pipes, called risers, extending out of the tanks. It is through these pipes that crews are forced to send machines and devices into the tanks that are used to break up the waste or push it toward a pump. These pipes range in size from just a few inches to just over a foot in diameter because they were never intended to be used in this manner. As part of the agreement regulating Hanford cleanup, crews must remove at least 99% of the material in every tank on the site, or at least as much waste that can be removed based on available technology. To date, seven single-shell tanks have been emptied, and work is underway in another 10 tanks in preparation for additional retrieval activities. Two barriers have been installed over single-shell tanks to prevent the intrusion of surface water down to the tanks, with additional barriers planned for the future. Single and double-shell tank integrity analyses are ongoing. Because the volume of the waste generated through plutonium production exceeded the capacity of the single-shell tanks, between 1968 and 1986 Hanford engineers built 28 double-shell tanks. These tanks were studied and made with a second shell to surround the carbon steel and reinforced concrete. The double-shell tanks have not leaked any of their waste. (authors)

  15. Evaluation of defatted and whole algae as feed ingredients for the marine shrimp, litopenaeus vannamei

    SciTech Connect (OSTI)

    Morgan, J. L.; Patnaik, S.; Gatlin, III, D. M.; Lawrence, A. L.

    2012-06-13

    Evaluation of defatted and whole algae as feed ingredients for the marine shrimp, litopenaeus vannamei

  16. Low-head feeding system for thin section castings

    DOE Patents [OSTI]

    Daniel, Sabah S. (Allegheny County, PA); Kleeb, Thomas R. (Allegheny County, PA); Lewis, Thomas W. (Allegheny County, PA); McDermott, John F. (Allegheny County, PA); Ozgu, Mustafa R. (Northhampton County, PA); Padfield, Ralph C. (Lehigh County, PA); Rego, Donovan N. (Lehigh County, PA); Vassilicos, Achilles (Allegheny County, PA)

    1990-01-01

    A feed system is provided for conveying molten metal to a thin section caster having mold surfaces moving exclusively in the direction of casting. The feed system has a passage of circular cross section adjacent to one end thereof for receiving molten metal and a rectangular cross section at the delivery end thereof adjacent to the caster. The feed system is designed for supplying molten metal to the caster at low pressure for "closed-pool" type caster operation. The point of highest elevation in the metal flow passage of the feed system is on the upper surface of a transition portion where the cross section changes from circular to rectangular adjacent to the nozzle. The level or height of the high point above the centerline of the nozzle exit is selected so as to be less than the pressure of the metal measured in inches at the nozzle exit. This feature enables the maintenance of positive pressure in the metal within the feed system so that ingress of air into the metal is prevented.

  17. Feed-in Tariffs: Good Practices and Design Considerations. A Clean Energy Regulators Initiative Report

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Feed-Pump Hydraulic Performance and Design Improvement, Phase I: J2esearch Program Design Volume 2 EPRI EPRI CS-2323 Volume 2 Project 1884-6 Final Report March 1982 Keywords: Feed Pumps Feed Pump Reliability Feed Pump Hydraulics Feed Pump Design Feed Pump Research Feed Pump Specifications Prepared by Borg-Warner Corporation (Byron Jackson Pump Division and Borg-Warner Research Center) Carson, California and Massa^ f Technology Cambri__ . s ,-T. a a *a_^"nt.- ji^, w « ' jm.m

  18. Statistical Methods and Tools for Hanford Staged Feed Tank Sampling

    SciTech Connect (OSTI)

    Fountain, Matthew S.; Brigantic, Robert T.; Peterson, Reid A.

    2013-10-01

    This report summarizes work conducted by Pacific Northwest National Laboratory to technically evaluate the current approach to staged feed sampling of high-level waste (HLW) sludge to meet waste acceptance criteria (WAC) for transfer from tank farms to the Hanford Waste Treatment and Immobilization Plant (WTP). The current sampling and analysis approach is detailed in the document titled Initial Data Quality Objectives for WTP Feed Acceptance Criteria, 24590-WTP-RPT-MGT-11-014, Revision 0 (Arakali et al. 2011). The goal of this current work is to evaluate and provide recommendations to support a defensible, technical and statistical basis for the staged feed sampling approach that meets WAC data quality objectives (DQOs).

  19. Feed gas contaminant control in ion transport membrane systems

    DOE Patents [OSTI]

    Carolan, Michael Francis; Minford, Eric; Waldron, William Emil

    2009-07-07

    Ion transport membrane oxidation system comprising an enclosure having an interior and an interior surface, inlet piping having an internal surface and adapted to introduce a heated feed gas into the interior of the enclosure, and outlet piping adapted to withdraw a product gas from the interior of the enclosure; one or more planar ion transport membrane modules disposed in the interior of the enclosure, each membrane module comprising mixed metal oxide material; and a preheater adapted to heat a feed gas to provide the heated feed gas to the inlet piping, wherein the preheater comprises an interior surface. Any of the interior surfaces of the enclosure, the inlet piping, and the preheater may be lined with a copper-containing metal lining. Alternatively, any of the interior surfaces of the inlet piping and the preheater may be lined with a copper-containing metal lining and the enclosure may comprise copper.

  20. Earth melter and method of disposing of feed materials

    DOE Patents [OSTI]

    Chapman, C.C.

    1994-10-11

    An apparatus, and method of operating the apparatus is described, wherein a feed material is converted into a glassified condition for subsequent use or disposal. The apparatus is particularly useful for disposal of hazardous or noxious waste materials which are otherwise either difficult or expensive to dispose of. The apparatus is preferably constructed by excavating a melt zone in a quantity of soil or rock, and lining the melt zone with a back fill material if refractory properties are needed. The feed material is fed into the melt zone and, preferably, combusted to an ash, whereupon the heat of combustion is used to melt the ash to a molten condition. Electrodes may be used to maintain the molten feed material in a molten condition, and to maintain homogeneity of the molten materials. 3 figs.

  1. Earth melter and method of disposing of feed materials

    DOE Patents [OSTI]

    Chapman, Christopher C.

    1994-01-01

    An apparatus, and method of operating the apparatus, wherein a feed material is converted into a glassified condition for subsequent use or disposal. The apparatus is particularly useful for disposal of hazardous or noxious waste materials which are otherwise either difficult or expensive to dispose of. The apparatus is preferably constructed by excavating a melt zone in a quantity of soil or rock, and lining the melt zone with a back fill material if refractory properties are needed. The feed material is fed into the melt zone and, preferably, combusted to an ash, whereupon the heat of combustion is used to melt the ash to a molten condition. Electrodes may be used to maintain the molten feed material in a molten condition, and to maintain homogeneity of the molten materials.

  2. Mining Large Heterogeneous Graphs using Cray s Urika

    SciTech Connect (OSTI)

    Sukumar, Sreenivas R; Bond, Nathaniel A

    2013-01-01

    Pattern discovery and predictive modeling from seemingly related Big Data represented as massive, ad-hoc, heterogeneous networks (e.g., extremely large graphs with complex, possibly unknown structure) is an outstanding problem in many application domains. To address this problem, we are designing graph-mining algorithms capable of discovering relationship-patterns from such data and using those discovered patterns as features for classification and predictive modeling. Specifically, we are: (i) exploring statistical properties, mechanics and generative models of behavior patterns in heterogeneous information networks, (ii) developing novel, automated and scalable graph-pattern discovery algorithms and (iii) applying our relationship-analytics (data science + network science) expertise to domains spanning healthcare to homeland security.

  3. Computational Modeling of Heterogeneous Reactive Materials at the Mesoscale

    SciTech Connect (OSTI)

    BAER, MARVIN R.

    1999-09-22

    The mesoscopic processes of consolidation, deformation and reaction of shocked porous energetic materials are studied using shock physics analysis of impact on a collection of discrete ''crystals.'' Highly resolved three-dimensional CTH simulations indicate that rapid deformation occurs at material contact points causing large amplitude fluctuations of stress states with wavelengths of the order of several particle diameters. Localization of energy produces ''hot-spots'' due to shock focusing and plastic work near internal boundaries as material flows into interstitial regions. Numerical experiments indicate that ''hot-spots'' are strongly influenced by multiple crystal interactions. Chemical reaction processes also produce multiple wave structures associated with particle distribution effects. This study provides new insights into the micromechanical behavior of heterogeneous energetic materials strongly suggesting that initiation and sustained reaction of shocked heterogeneous materials involves states distinctly different from single jump state descriptions.

  4. Feed Composition for Sodium-Bearing Waste Treatment Process

    SciTech Connect (OSTI)

    Barnes, C.M.

    2000-10-30

    Treatment of sodium-bearing waste (SBW) at the Idaho Nuclear Technology and Engineering Center (INTEC) within the Idaho National Engineering and Environmental Laboratory is mandated by a Settlement Agreement between the Department of Energy and the State of Idaho. One of the requirements of the Settlement Agreement is to complete treatment of SBW by December 31, 2012. To support both design and development studies for the SBW treatment process, detailed feed compositions are needed. This report contains the expected compositions of these feed streams and the sources and methods used in obtaining these compositions.

  5. NREL: State and Local Governments - Feed-In Tariffs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Feed-In Tariffs A feed-in tariff (FIT) is an energy supply policy that promotes the rapid deployment of renewable energy resources. A FIT offers a guarantee of payments to renewable energy developers for the electricity they produce. Payments can be composed of electricity alone or of electricity bundled with renewable energy certificates. These payments are generally awarded as long-term contracts set over a period of 15-20 years. FIT policies are successful around the world, notably in Europe.

  6. An Update on Feds Feeds Families | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Feds Feeds Families An Update on Feds Feeds Families November 19, 2012 - 5:32pm Addthis As a result of DOE employee efforts, the Energy Department received an award from OPM for donating the highest amount of non-perishable food items within the “small agency” category of Federal agencies participating in this year’s Campaign. | Photo courtesy of OPM. As a result of DOE employee efforts, the Energy Department received an award from OPM for donating the highest amount of

  7. Coal-feeding mechanism for a fluidized bed combustion chamber

    DOE Patents [OSTI]

    Gall, Robert L.

    1981-01-01

    The present invention is directed to a fuel-feeding mechanism for a fluidized bed combustor. In accordance with the present invention a perforated conveyor belt is utilized in place of the fixed grid normally disposed at the lower end of the fluidized bed combustion zone. The conveyor belt is fed with fuel, e.g. coal, at one end thereof so that the air passing through the perforations dislodges the coal from the belt and feeds the coal into the fluidized zone in a substantially uniform manner.

  8. Liquid over-feeding air conditioning system and method

    DOE Patents [OSTI]

    Mei, Viung C.; Chen, Fang C.

    1993-01-01

    A refrigeration air conditioning system utilizing a liquid over-feeding operation is described. A liquid refrigerant accumulator-heat exchanger is placed in the system to provide a heat exchange relationship between hot liquid refrigerant discharged from condenser and a relatively cool mixture of liquid and vaporous refrigerant discharged from the evaporator. This heat exchange relationship substantially sub-cools the hot liquid refrigerant which undergoes little or no evaporation across the expansion device and provides a liquid over-feeding operation through the evaporator for effectively using 100 percent of evaporator for cooling purposes and for providing the aforementioned mixture of liquid and vaporous refrigerant.

  9. Feed gas contaminant removal in ion transport membrane systems

    DOE Patents [OSTI]

    Carolan, Michael Francis (Allentown, PA); Miller, Christopher Francis (Macungie, PA)

    2008-09-16

    Method for gas purification comprising (a) obtaining a feed gas stream containing one or more contaminants selected from the group consisting of volatile metal oxy-hydroxides, volatile metal oxides, and volatile silicon hydroxide; (b) contacting the feed gas stream with a reactive solid material in a guard bed and reacting at least a portion of the contaminants with the reactive solid material to form a solid reaction product in the guard bed; and (c) withdrawing from the guard bed a purified gas stream.

  10. Liquid over-feeding air conditioning system and method

    DOE Patents [OSTI]

    Mei, V.C.; Chen, F.C.

    1993-09-21

    A refrigeration air conditioning system utilizing a liquid over-feeding operation is described. A liquid refrigerant accumulator-heat exchanger is placed in the system to provide a heat exchange relationship between hot liquid refrigerant discharged from condenser and a relatively cool mixture of liquid and vaporous refrigerant discharged from the evaporator. This heat exchange relationship substantially sub-cools the hot liquid refrigerant which undergoes little or no evaporation across the expansion device and provides a liquid over-feeding operation through the evaporator for effectively using 100 percent of evaporator for cooling purposes and for providing the aforementioned mixture of liquid and vaporous refrigerant. 1 figure.

  11. Imaging Heterogeneous Ion Transfer: Lithium Ion Quantification using

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mercury Amalgams as In Situ Electrochemical Probes in Nonaqueous Media - Joint Center for Energy Storage Research October 24, 2014, Research Highlights Imaging Heterogeneous Ion Transfer: Lithium Ion Quantification using Mercury Amalgams as In Situ Electrochemical Probes in Nonaqueous Media Quantitative micro- and nano- probes were used for the in situ imaging of alkaline ion transfer processes at an electroactive surface. Detection of Li+, Na+ and K+ is possible. Scientific Achievement

  12. The Effect of Surface Heterogeneity on Cloud Absorption Estimates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Effect of Surface Heterogeneity on Cloud Absorption Estimates W. J. Wiscombe and A. Marshak National Aeronautics and Space Administration - Goddard Space Flight Center Climate and Radiation Branch Greenbelt, Maryland J.-Y. C. Chiu Joint Center for Earth Systems Technology University of Maryland Baltimore, Maryland Introduction "Enhanced shortwave cloud absorption" (the difference between measured and model-calculated absorptions) has been a major concern in the climate community. The

  13. Incorporating reservoir heterogeneity with geostatistics to investigate waterflood recoveries

    SciTech Connect (OSTI)

    Wolcott, D.S. ); Chopra, A.K. )

    1993-03-01

    This paper presents an investigation of infill drilling performance and reservoir continuity with geostatistics and a reservoir simulator. The geostatistical technique provides many possible realizations and realistic descriptions of reservoir heterogeneity. Correlation between recovery efficiency and thickness of individual sand subunits is shown. Additional recovery from infill drilling results from thin, discontinuous subunits. The technique may be applied to variations in continuity for other sandstone reservoirs.

  14. Instruments for preparation of heterogeneous catalysts by an impregnation method

    SciTech Connect (OSTI)

    Yamada, Yusuke; Akita, Tomoki; Ueda, Atsushi; Shioyama, Hiroshi; Kobayashi, Tetsuhiko

    2005-06-15

    Instruments for the preparation of heterogeneous catalysts in powder form have been developed. The instruments consist of powder dispensing robot and an automated liquid handling machine equipped with an ultrasonic and a vortex mixer. The combination of these two instruments achieves the catalyst preparation by incipient wetness and ion exchange methods. The catalyst library prepared with these instruments were tested for dimethyl ether steam reforming and characterized by transmission electron microscopy observations.

  15. Correlating Spatial Heterogeneities in Porosity and Permeability with Metal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Poisoning within an Individual Catalyst Particle using X-ray Microscopy | Stanford Synchrotron Radiation Lightsource Correlating Spatial Heterogeneities in Porosity and Permeability with Metal Poisoning within an Individual Catalyst Particle using X-ray Microscopy Wednesday, August 21, 2013 - 1:30pm SLAC, Conference Room 137-226 Presented by Darius Morris, Stanford Synchrotron Radiation Lightsource Fluid catalytic cracking (FCC) is a refining process for converting large and/or heavy

  16. Heterogeneous composite bodies with isolated lenticular shaped cermet regions

    DOE Patents [OSTI]

    Sherman, Andrew J.

    2009-12-22

    A heterogeneous body having ceramic rich cermet regions in a more ductile metal matrix. The heterogeneous bodies are formed by thermal spray operations on metal substrates. The thermal spray operations apply heat to a cermet powder and project it onto a solid substrate. The cermet powder is composed of complex composite particles in which a complex ceramic-metallic core particle is coated with a matrix precursor. The cermet regions are generally comprised of complex ceramic-metallic composites that correspond approximately to the core particles. The cermet regions are approximately lenticular shaped with an average width that is at least approximately twice the average thickness. The cermet regions are imbedded within the matrix phase and generally isolated from one another. They have obverse and reverse surfaces. The matrix phase is formed from the matrix precursor coating on the core particles. The amount of heat applied during the formation of the heterogeneous body is controlled so that the core particles soften but do not become so fluid that they disperse throughout the matrix phase. The force of the impact on the surface of the substrate tends to flatten them. The flattened cermet regions tend to be approximately aligned with one another in the body.

  17. HeNCE: A Heterogeneous Network Computing Environment

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Beguelin, Adam; Dongarra, Jack J.; Geist, George Al; Manchek, Robert; Moore, Keith

    1994-01-01

    Network computing seeks to utilize the aggregate resources of many networked computers to solve a single problem. In so doing it is often possible to obtain supercomputer performance from an inexpensive local area network. The drawback is that network computing is complicated and error prone when done by hand, especially if the computers have different operating systems and data formats and are thus heterogeneous. The heterogeneous network computing environment (HeNCE) is an integrated graphical environment for creating and running parallel programs over a heterogeneous collection of computers. It is built on a lower level package called parallel virtual machine (PVM).more » The HeNCE philosophy of parallel programming is to have the programmer graphically specify the parallelism of a computation and to automate, as much as possible, the tasks of writing, compiling, executing, debugging, and tracing the network computation. Key to HeNCE is a graphical language based on directed graphs that describe the parallelism and data dependencies of an application. Nodes in the graphs represent conventional Fortran or C subroutines and the arcs represent data and control flow. This article describes the present state of HeNCE, its capabilities, limitations, and areas of future research.« less

  18. Heterogeneity analysis in 40 X-linked retinitis pigmentosa families

    SciTech Connect (OSTI)

    Teague, P.W.; Aldred, M.A.; Dempster, M.; Harrison, C.; Carothers, A.D.; Hardwick, L.J.; Evans, H.J.; Wright, A.F.; Strain, L.; Brock, D.J.H. )

    1994-07-01

    Analysis of genetic heterogeneity in 40 kindreds with X-linked retinitis pigmentosa (XLRP), with 20 polymorphic markers, showed that significant heterogeneity is present (P=.001) and that 56% of kindreds are of RP3 type and that 26% are of RP2 type. The location of the RP3 locus was found to be 0.4 cM distal to OTC in the Xp21.1 region, and that of the RP2 locus was 6.5 cM proximal to DXS7 in Xp11.2-p11.3. Bayesian probabilities of linkage to RP2, RP3, or to neither locus were calculated. This showed that 20 of 40 kindreds could be assigned to one or the other locus, with a probability >.70 (14 kindreds with RP3 and 6 kindreds with RP2 disease). A further three kindreds were found to be unlinked to either locus, with a probability >.8. The remaining 17 kindreds could not be classified unambiguously. This highlights the difficulty of classifying families in the presence of genetic heterogeneity, where two loci are separated by an estimated 16 cM. 34 refs., 1 fig., 4 tabs.

  19. Modification of heterogeneous chemistry by complex substrate morphology

    SciTech Connect (OSTI)

    Henson, B.F.; Buelow, S.J.; Robinson, J.M.

    1998-12-31

    This is the final report of a one-year, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). Chemistry in many environmental systems is determined at some stage by heterogeneous reaction with a surface. Typically the surface exists as a dispersion or matrix of particulate matter or pores, and a determination of the heterogeneous chemistry of the system must address the extent to which the complexity of the environmental surface affects the reaction rates. Reactions that are of current interest are the series of chlorine nitrate reactions important in polar ozone depletion. The authors have applied surface spectroscopic techniques developed at LANL to address the chemistry of chlorine nitrate reactions on porous nitric and sulfuric acid ice surfaces as a model study of the measurement of complex, heterogeneous reaction rates. The result of the study is an experimental determination of the surface coverage of one adsorbed reagent and a mechanism of reactivity based on the dependence of this coverage on temperature and vapor pressure. The resulting mechanism allows the first comprehensive modeling of chlorine nitrate reaction probability data from several laboratories.

  20. LOW ACTIVITY WASTE FEED SOLIDS CARACTERIZATION AND FILTERABILITY TESTS

    SciTech Connect (OSTI)

    McCabe, D.; Crawford, C.; Duignan, M.; Williams, M.; Burket, P.

    2014-04-03

    The primary treatment of the tank waste at the DOE Hanford site will be done in the Waste Treatment and Immobilization Plant (WTP) that is currently under construction. The baseline plan for the WTP Pretreatment facility is to treat the waste, splitting it into High Level Waste (HLW) feed and Low Activity Waste (LAW) feed. Both waste streams are then separately vitrified as glass and sealed in canisters. The LAW glass will be disposed onsite in the Integrated Disposal Facility (IDF). There are currently no plans to treat the waste to remove technetium in the WTP Pretreatment facility, so its disposition path is the LAW glass. Options are being explored to immobilize the LAW portion of the tank waste, i.e., the LAW feed from the WTP Pretreatment facility. Removal of {sup 99}Tc from the LAW Feed, followed by off-site disposal of the {sup 99}Tc, would eliminate a key risk contributor for the IDF Performance Assessment (PA) for supplemental waste forms, and has potential to reduce treatment and disposal costs. Washington River Protection Solutions (WRPS) is developing some conceptual flow sheets for LAW treatment and disposal that could benefit from technetium removal. One of these flowsheets will specifically examine removing {sup 99}Tc from the LAW feed stream to supplemental immobilization. The conceptual flow sheet of the {sup 99}Tc removal process includes a filter to remove insoluble solids prior to processing the stream in an ion exchange column, but the characteristics and behavior of the liquid and solid phases has not previously been investigated. This report contains results of testing of a simulant that represents the projected composition of the feed to the Supplemental LAW process. This feed composition is not identical to the aqueous tank waste fed to the Waste Treatment Plant because it has been processed through WTP Pretreatment facility and therefore contains internal changes and recycle streams that will be generated within the WTP process. Although a Supplemental LAW feed simulant has previously been prepared, this feed composition differs from that simulant because those tests examined only the fully soluble aqueous solution at room temperature, not the composition formed after evaporation, including the insoluble solids that precipitate after it cools. The conceptual flow sheet for Supplemental LAW immobilization has an option for removal of {sup 99}Tc from the feed stream, if needed. Elutable ion exchange has been selected for that process. If implemented, the stream would need filtration to remove the insoluble solids prior to processing in an ion exchange column. The characteristics, chemical speciation, physical properties, and filterability of the solids are important to judge the feasibility of the concept, and to estimate the size and cost of a facility. The insoluble solids formed during these tests were primarily natrophosphate, natroxalate, and a sodium aluminosilicate compound. At the elevated temperature and 8 M [Na+], appreciable insoluble solids (1.39 wt%) were present. Cooling to room temperature and dilution of the slurry from 8 M to 5 M [Na+] resulted in a slurry containing 0.8 wt% insoluble solids. The solids (natrophosphate, natroxalate, sodium aluminum silicate, and a hydrated sodium phosphate) were relatively stable and settled quickly. Filtration rates were in the range of those observed with iron-based simulated Hanford tank sludge simulants, e.g., 6 M [Na+] Hanford tank 241-AN-102, even though their chemical speciation is considerably different. Chemical cleaning of the crossflow filter was readily accomplished with acid. As this simulant formulation was based on an average composition of a wide range of feeds using an integrated computer model, this exact composition may never be observed. But the test conditions were selected to enable comparison to the model to enable improving its chemical prediction capability.

  1. Large scale validation of the M5L lung CAD on heterogeneous CT datasets

    SciTech Connect (OSTI)

    Lopez Torres, E. E-mail: cerello@to.infn.it; Fiorina, E.; Pennazio, F.; Peroni, C.; Saletta, M.; Cerello, P. E-mail: cerello@to.infn.it; Camarlinghi, N.; Fantacci, M. E.

    2015-04-15

    Purpose: M5L, a fully automated computer-aided detection (CAD) system for the detection and segmentation of lung nodules in thoracic computed tomography (CT), is presented and validated on several image datasets. Methods: M5L is the combination of two independent subsystems, based on the Channeler Ant Model as a segmentation tool [lung channeler ant model (lungCAM)] and on the voxel-based neural approach. The lungCAM was upgraded with a scan equalization module and a new procedure to recover the nodules connected to other lung structures; its classification module, which makes use of a feed-forward neural network, is based of a small number of features (13), so as to minimize the risk of lacking generalization, which could be possible given the large difference between the size of the training and testing datasets, which contain 94 and 1019 CTs, respectively. The lungCAM (standalone) and M5L (combined) performance was extensively tested on 1043 CT scans from three independent datasets, including a detailed analysis of the full Lung Image Database Consortium/Image Database Resource Initiative database, which is not yet found in literature. Results: The lungCAM and M5L performance is consistent across the databases, with a sensitivity of about 70% and 80%, respectively, at eight false positive findings per scan, despite the variable annotation criteria and acquisition and reconstruction conditions. A reduced sensitivity is found for subtle nodules and ground glass opacities (GGO) structures. A comparison with other CAD systems is also presented. Conclusions: The M5L performance on a large and heterogeneous dataset is stable and satisfactory, although the development of a dedicated module for GGOs detection could further improve it, as well as an iterative optimization of the training procedure. The main aim of the present study was accomplished: M5L results do not deteriorate when increasing the dataset size, making it a candidate for supporting radiologists on large scale screenings and clinical programs.

  2. U.S. Virgin Islands Feed-In Tariff

    Broader source: Energy.gov [DOE]

    In May of 2014, AB 7586 created a feed-in-tariff that would allow owners of solar photovotaic systems ranging between 10 kWh and 500 kWh to sell their energy for approximately 26 cents per kWh. Two...

  3. Waste Feed Delivery Environmental Permits and Approvals Plan

    SciTech Connect (OSTI)

    TOLLEFSON, K.S.

    2000-01-18

    This plan describes the environmental permits approvals, and other requirements that may affect establishment of a waste feed delivery system for the Hanford Site's River Protection Project. This plan identifies and screens environmental standards for potential applicability, outlines alternatives for satisfying applicable standards, and describes preferred permitting and approval approaches.

  4. Data Quality Objectives for WTP Feed Acceptance Criteria - 12043

    SciTech Connect (OSTI)

    Arakali, Aruna V.; Benson, Peter A.; Duncan, Garth; Johnston, Jill C.; Lane, Thomas A.; Matis, George; Olson, John W.; Banning, Davey L.; Greer, Daniel A.; Seidel, Cary M.; Thien, Michael G.

    2012-07-01

    The Hanford Tank Waste Treatment and Immobilization Plant (WTP) is under construction for the U.S. Department of Energy by Bechtel National, Inc. and subcontractor URS Corporation (contract no. DE-AC27-01RV14136). The plant when completed will be the world's largest nuclear waste treatment facility. Bechtel and URS are tasked with designing, constructing, commissioning, and transitioning the plant to the long term operating contractor to process the legacy wastes that are stored in underground tanks (from nuclear weapons production between the 1940's and the 1980's). Approximately 56 million gallons of radioactive waste is currently stored in these tanks at the Hanford Site in southeastern Washington. There are three major WTP facilities being constructed for processing the tank waste feed. The Pretreatment (PT) facility receives feed where it is separated into a low activity waste (LAW) fraction and a high level waste (HLW) fraction. These fractions are transferred to the appropriate (HLW or LAW) facility, combined with glass former material, and sent to high temperature melters for formation of the glass product. In addition to PT, HLW and LAW, other facilities in WTP include the Laboratory (LAB) for analytical services and the Balance of Facilities (BOF) for plant maintenance, support and utility services. The transfer of staged feed from the waste storage tanks and acceptance in WTP receipt vessels require data for waste acceptance criteria (WAC) parameters from analysis of feed samples. The Data Quality Objectives (DQO) development was a joint team effort between WTP and Tank Operations Contractor (TOC) representatives. The focus of this DQO effort was to review WAC parameters and develop data quality requirements, the results of which will determine whether or not the staged feed can be transferred from the TOC to WTP receipt vessels. The approach involved systematic planning for data collection consistent with EPA guidance for the seven-step DQO process. Data quality requirements for sample collection and analysis of all WAC parameters were specified during the DQO process. There were eighteen key parameters identified with action limits to ensure the feed transfer and receipt would not exceed plant design, safety, permitting, and processing requirements. The remaining WAC parameters were grouped in the category for obtaining data according to WTP contract specifications, regulatory reporting requirements, and for developing the feed campaign processing sequence. (authors)

  5. Economy Through Product Diversity: Integrated Biorefineries

    Office of Environmental Management (EM)

    a range of products to optimize use of the feedstock and improve process economics. ... biobased co-products and power production can improve the economics of the facility. ...

  6. 2014 DOE Biomass Program Integrated Biorefinery Project

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Justin Nason Staff Accountant Carmina Marzo Gomez ABBK Controller Joe Abkemeier ABNT Controller Leroy Holmes R & D Manager Kevin Gross Process Engr. Evan Steiner Process Engr. ...

  7. NREL: Sustainable NREL - Integrated Biorefinery Research Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Efficiency Features Natural ventilation through operable windows Daylighting Open air cubicles LED lights with lighting control system Sustainability Features Composting and ...

  8. USDA - Biorefinery Assistance Program | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    must be an advanced biofuels Eligible advanced biofuels include: Biofuel derived from cellulose, hemicellulose, or lignin, or other fuels derived from cellulose Biofuel derived...

  9. NewPage Demonstration-Scale Biorefinery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in Wisconsin (NewPage Corporation in Wisconsin Rapids and Flambeau River Papers, LLC in Park Falls). NewPage and Flambeau River have demonstrated successful collaboration on...

  10. Flambeau River Biofuels Demonstration-Scale Biorefinery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    in Wisconsin (NewPage Corporation in Wisconsin Rapids and Flambeau River Papers, LLC in Park Falls). NewPage and Flambeau River have demonstrated successful collaboration on...

  11. A Second-Generation Dry Mill Biorefinery

    Broader source: Energy.gov [DOE]

    This fact sheet summarizes a U.S. Department of Energy Biomass Program research and development project.

  12. Demonstration of Pyrolysis Biorefinery Concept for Biopower,...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... * ISU ME Dept., * Power Systems * Non-transport biofuel blends * Combustion testing: furnace (heat) and stationary engine (power) * Emissions analysis * Cargill * Co-fire test ...

  13. NREL: Biomass Research - Capabilities in Integrated Biorefinery...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    U.S. Department of Energy. A yellow ladder is connected to the side of the right tank. A man at the far end of the room examines the pipes that lead to the tanks. In the...

  14. Southern Pine Based on Biorefinery Center

    SciTech Connect (OSTI)

    Ragauskas, Arthur J; Singh, Preet

    2014-01-10

    This program seeks to develop an integrated southern pine wood to biofuels/biomaterials processing facility on the Recipient’s campus, that will test advanced integrated wood processing technologies at the laboratory scale, including: • The generation of the bioethanol from pines residues and hemicelluloses extracted from pine woodchips; • The conversion of extracted woodchips to linerboard and bleach grade pulps; and • The efficient conversion of pine residues, bark and kraft cooking liquor into a useful pyrolysis oil.

  15. Myriant Succinic Acid BioRefinery

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    -based Succinic Acid * Life Cycle Analysis of Bio-succinic acid production using the IPCC 2007 (GWP) method 5 MySAB Quad Chart Overview * Project start date BP1 - 3...

  16. Integrated Biorefinery Lessons Learned and Best Practices

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... a positive result." - Secchi, P., Ciaschi, R., Spence, D. "A best practice is known as a ... * How will the plant start-up in a freeze? * Do heat traces need to be in place? * ...

  17. NREL: Biomass Research - Integrated Biorefinery Research Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The IBRF's 27,000-ft2, high-bay biochemical conversion pilot ... into end-to-end process integration and evaluation tests ... for staged feedstock pre-processing operations in one vessel ...

  18. DuPont Cellulosic Ethanol Biorefinery Opening

    Broader source: Energy.gov [DOE]

    The DuPont cellulosic ethanol facility, opening in Nevada, Iowa, on October 30, will be the largest cellulosic ethanol plant in the world. The U.S. Department of Energy Bioenergy Technologies Office Director, Jonathan Male, alongside senior government officials, DuPont leaders and staff, and local farmers will attend the grand opening ceremony and plant tour.

  19. Integrated Biorefineries:Biofuels, Biopower, and Bioproducts...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Solazyme, Inc. Peoria, IL Pilot Algae UOP, LLC Kapolei, HI Pilot Thermo - Pyrolysis ZeaChem, Inc. Boardman, OR Pilot Thermo - Pyrolysis Elevance* Boilingbrook, IL...

  20. MRI of Heterogeneous Hydrogenation Reactions Using Parahydrogen Polarization

    SciTech Connect (OSTI)

    Burt, Scott R; Burt, Scott R.

    2008-06-25

    The power of magnetic resonance imaging (MRI) is its ability to image the internal structure of optically opaque samples and provide detailed maps of a variety of important parameters, such as density, diffusion, velocity and temperature. However, one of the fundamental limitations of this technique is its inherent low sensitivity. For example, the low signal to noise ratio (SNR) is particularly problematic for imaging gases in porous materials due to the low density of the gas and the large volume occluded by the porous material. This is unfortunate, as many industrially relevant chemical reactions take place at gas-surface interfaces in porous media, such as packed catalyst beds. Because of this severe SNR problem, many techniques have been developed to directly increase the signal strength. These techniques work by manipulating the nuclear spin populations to produce polarized} (i.e., non-equilibrium) states with resulting signal strengths that are orders of magnitude larger than those available at thermal equilibrium. This dissertation is concerned with an extension of a polarization technique based on the properties of parahydrogen. Specifically, I report on the novel use of heterogeneous catalysis to produce parahydrogen induced polarization and applications of this new technique to gas phase MRI and the characterization of micro-reactors. First, I provide an overview of nuclear magnetic resonance (NMR) and how parahydrogen is used to improve the SNR of the NMR signal. I then present experimental results demonstrating that it is possible to use heterogeneous catalysis to produce parahydrogen-induced polarization. These results are extended to imaging void spaces using a parahydrogen polarized gas. In the second half of this dissertation, I demonstrate the use of parahydrogen-polarized gas-phase MRI for characterizing catalytic microreactors. Specifically, I show how the improved SNR allows one to map parameters important for characterizing the heat and mass transport in a heterogeneous catalyst bed. This is followed by appendices containing detailed information regarding the design and use of my experimental setup.

  1. A heterogeneous hierarchical architecture for real-time computing

    SciTech Connect (OSTI)

    Skroch, D.A.; Fornaro, R.J.

    1988-12-01

    The need for high-speed data acquisition and control algorithms has prompted continued research in the area of multiprocessor systems and related programming techniques. The result presented here is a unique hardware and software architecture for high-speed real-time computer systems. The implementation of a prototype of this architecture has required the integration of architecture, operating systems and programming languages into a cohesive unit. This report describes a Heterogeneous Hierarchial Architecture for Real-Time (H{sup 2} ART) and system software for program loading and interprocessor communication.

  2. Microgrids and Heterogeneous Security, Quality, Reliability, andAvailability

    SciTech Connect (OSTI)

    Marnay, Chris

    2007-01-31

    This paper describes two stylized alternative visions inpopular currencyof how the power system might evolve to meet futurerequirements for the high quality electricity service that modern digitaleconomies demand, a supergrids paradigm and a dispersed paradigm. Some ofthe economics of the dispersed vision are explored. Economic perspectivesare presented on both the choice of homogeneous universal power qualityupstream in the electricity supply, and also on the extremelyheterogeneous require-ments of end-use loads. Finally, the potential roleof microgrids in delivering heterogeneous power quality is demonstratedby reference to two ongoing microgrid tests in the U.S. andJapan.

  3. A Policymaker's Guide to Feed-In Tariff Policy Design | Open...

    Open Energy Info (EERE)

    Policymaker's Guide to Feed-In Tariff Policy Design Jump to: navigation, search Tool Summary LAUNCH TOOL Name: A Policymaker's Guide to Feed-In Tariff Policy Design AgencyCompany...

  4. Process for coal liquefaction employing selective coal feed

    DOE Patents [OSTI]

    Hoover, David S.; Givens, Edwin N.

    1983-01-01

    An improved coal liquefaction process is provided whereby coal conversion is improved and yields of pentane soluble liquefaction products are increased. In this process, selected feed coal is pulverized and slurried with a process derived solvent, passed through a preheater and one or more dissolvers in the presence of hydrogen-rich gases at elevated temperatures and pressures, following which solids, including mineral ash and unconverted coal macerals, are separated from the condensed reactor effluent. The selected feed coals comprise washed coals having a substantial amount of mineral matter, preferably from about 25-75%, by weight, based upon run-of-mine coal, removed with at least 1.0% by weight of pyritic sulfur remaining and exhibiting vitrinite reflectance of less than about 0.70%.

  5. Monodisperse Platinum and Rhodium Nanoparticles as Model Heterogeneous Catalysts

    SciTech Connect (OSTI)

    Coble, Inger M

    2008-08-15

    Model heterogeneous catalysts have been synthesized and studied to better understand how the surface structure of noble metal nanoparticles affects catalytic performance. In this project, monodisperse rhodium and platinum nanoparticles of controlled size and shape have been synthesized by solution phase polyol reduction, stabilized by polyvinylpyrrolidone (PVP). Model catalysts have been developed using these nanoparticles by two methods: synthesis of mesoporous silica (SBA-15) in the presence of nanoparticles (nanoparticle encapsulation, NE) to form a composite of metal nanoparticles supported on SBA-15 and by deposition of the particles onto a silicon wafer using Langmuir-Blodgett (LB) monolayer deposition. The particle shapes were analyzed by transmission electron microscopy (TEM) and high resolution TEM (HRTEM) and the sizes were determined by TEM, X-ray diffraction (XRD), and in the case of NE samples, room temperature H2 and CO adsorption isotherms. Catalytic studies were carried out in homebuilt gas-phase reactors. For the nanoparticles supported on SBA-15, the catalysts are in powder form and were studied using the homebuilt systems as plug-flow reactors. In the case of nanoparticles deposited on silicon wafers, the same systems were operated as batch reactors. This dissertation has focused on the synthesis, characterization, and reaction studies of model noble metal heterogeneous catalysts. Careful control of particle size and shape has been accomplished though solution phase synthesis of Pt and Rh nanoparticles in order to elucidate further structure-reactivity relationships in noble metal catalysis.

  6. Optimal utilization of heterogeneous resources for biomolecular simulations

    SciTech Connect (OSTI)

    Hampton, Scott S; Agarwal, Pratul K

    2010-01-01

    Biomolecular simulations have traditionally benefited from increases in the processor clock speed and coarse-grain inter-node parallelism on large-scale clusters. With stagnating clock frequencies, the evolutionary path for performance of microprocessors is maintained by virtue of core multiplication. Graphical processing units (GPUs) offer revolutionary performance potential at the cost of increased programming complexity. Furthermore, it has been extremely challenging to effectively utilize heterogeneous resources (host processor and GPU cores) for scientific simulations, as underlying systems, programming models and tools are continually evolving. In this paper, we present a parametric study demonstrating approaches to exploit resources of heterogeneous systems to reduce time-to-solution of a production-level application for biological simulations. By overlapping and pipelining computation and communication, we observe up to 10-fold application acceleration in multi-core and multi-GPU environments illustrating significant performance improvements over code acceleration approaches, where the host-to-accelerator ratio is static, and is constrained by a given algorithmic implementation.

  7. Optimal utilization of heterogeneous resources for biomolecular simulations.

    SciTech Connect (OSTI)

    Alam, Sadaf R.; Agarwal, Pratul K.; Hampton, Scott; Crozier, Paul Stewart

    2010-04-01

    Biomolecular simulations have traditionally benefited from increases in the processor clock speed and coarse-grain inter-node parallelism on large-scale clusters. With stagnating clock frequencies, the evolutionary path for performance of microprocessors is maintained by virtue of core multiplication. Graphical processing units (GPUs) offer revolutionary performance potential at the cost of increased programming complexity. Furthermore, it has been extremely challenging to effectively utilize heterogeneous resources (host processor and GPU cores) for scientific simulations, as underlying systems, programming models and tools are continually evolving. In this paper, we present a parametric study demonstrating approaches to exploit resources of heterogeneous systems to reduce time-to-solution of a production-level application for biological simulations. By overlapping and pipelining computation and communication, we observe up to 10-fold application acceleration in multi-core and multi-GPU environments illustrating significant performance improvements over code acceleration approaches, where the host-to-accelerator ratio is static, and is constrained by a given algorithmic implementation.

  8. Modeling flow in a pressure-sensitive, heterogeneous medium

    SciTech Connect (OSTI)

    Vasco, Donald W.; Minkoff, Susan E.

    2009-06-01

    Using an asymptotic methodology, including an expansion in inverse powers of {radical}{omega}, where {omega} is the frequency, we derive a solution for flow in a medium with pressure dependent properties. The solution is valid for a heterogeneous medium with smoothly varying properties. That is, the scale length of the heterogeneity must be significantly larger then the scale length over which the pressure increases from it initial value to its peak value. The resulting asymptotic expression is similar in form to the solution for pressure in a medium in which the flow properties are not functions of pressure. Both the expression for pseudo-phase, which is related to the 'travel time' of the transient pressure disturbance, and the expression for pressure amplitude contain modifications due to the pressure dependence of the medium. We apply the method to synthetic and observed pressure variations in a deforming medium. In the synthetic test we model one-dimensional propagation in a pressure-dependent medium. Comparisons with both an analytic self-similar solution and the results of a numerical simulation indicate general agreement. Furthermore, we are able to match pressure variations observed during a pulse test at the Coaraze Laboratory site in France.

  9. Effect of Bubbles and Silica Dissolution on Melter Feed Rheology during

    Office of Scientific and Technical Information (OSTI)

    Conversion to Glass (Journal Article) | SciTech Connect Journal Article: Effect of Bubbles and Silica Dissolution on Melter Feed Rheology during Conversion to Glass Citation Details In-Document Search Title: Effect of Bubbles and Silica Dissolution on Melter Feed Rheology during Conversion to Glass As the nuclear waste glass melter feed is converted to molten glass, the feed becomes a continuous glass-forming melt where dissolving refractory constituents are suspended together with numerous

  10. The Effect of Foaming and Silica Dissolution on Melter Feed Rheology during

    Office of Scientific and Technical Information (OSTI)

    Conversion to Glass (Conference) | SciTech Connect Conference: The Effect of Foaming and Silica Dissolution on Melter Feed Rheology during Conversion to Glass Citation Details In-Document Search Title: The Effect of Foaming and Silica Dissolution on Melter Feed Rheology during Conversion to Glass As the nuclear waste glass melter feed is converted to molten glass, the feed eventually becomes a continuous glass-forming melt in which dissolving refractory constituents are suspended together

  11. Final Technical Report - Investigation into the Relationship between Heterogeneity and Heavy-Tailed Solute Transport

    SciTech Connect (OSTI)

    Weissmann, Gary S

    2013-12-06

    The objective of this project was to characterize the influence that naturally complex geologic media has on anomalous dispersion and to determine if the nature of dispersion can be estimated from the underlying heterogeneous media. The UNM portion of this project was to provide detailed representations of aquifer heterogeneity through producing highly-resolved models of outcrop analogs to aquifer materials. This project combined outcrop-scale heterogeneity characterization (conducted at the University of New Mexico), laboratory experiments (conducted at Sandia National Laboratory), and numerical simulations (conducted at Sandia National Laboratory and Colorado School of Mines). The study was designed to test whether established dispersion theory accurately predicts the behavior of solute transport through heterogeneous media and to investigate the relationship between heterogeneity and the parameters that populate these models. The dispersion theory tested by this work was based upon the fractional advection-dispersion equation (fADE) model. Unlike most dispersion studies that develop a solute transport model by fitting the solute transport breakthrough curve, this project explored the nature of the heterogeneous media to better understand the connection between the model parameters and the aquifer heterogeneity. We also evaluated methods for simulating the heterogeneity to see whether these approaches (e.g., geostatistical) could reasonably replicate realistic heterogeneity. The UNM portion of this study focused on capturing realistic geologic heterogeneity of aquifer analogs using advanced outcrop mapping methods.

  12. Evaluating Feed Delivery Performance in Scaled Double-Shell Tanks

    SciTech Connect (OSTI)

    Lee, Kearn P.; Thien, Michael G.

    2013-11-07

    The Hanford Tank Operations Contractor (TOC) and the Hanford Waste Treatment and Immobilization Plant (WTP) contractor are both engaged in demonstrating mixing, sampling, and transfer system capability using simulated Hanford High-Level Waste (HLW) formulations. This work represents one of the remaining technical issues with the high-level waste treatment mission at Hanford. The TOCs' ability to adequately mix and sample high-level waste feed to meet the WTP WAC Data Quality Objectives must be demonstrated. The tank mixing and feed delivery must support both TOC and WTP operations. The tank mixing method must be able to remove settled solids from the tank and provide consistent feed to the WTP to facilitate waste treatment operations. Two geometrically scaled tanks were used with a broad spectrum of tank waste simulants to demonstrate that mixing using two rotating mixer jet pumps yields consistent slurry compositions as the tank is emptied in a series of sequential batch transfers. Testing showed that the concentration of slow settling solids in each transfer batch was consistent over a wide range of tank operating conditions. Although testing demonstrated that the concentration of fast settling solids decreased by up to 25% as the tank was emptied, batch-to-batch consistency improved as mixer jet nozzle velocity in the scaled tanks increased.

  13. Molecular-Level Design of Heterogeneous Chiral Catalysis

    SciTech Connect (OSTI)

    Francisco Zaera

    2012-03-21

    The following is a proposal to continue our multi-institutional research on heterogeneous chiral catalysis. Our team combines the use of surface-sensitive analytical techniques for the characterization of model systems with quantum and statistical mechanical calculations to interpret experimental data and guide the design of future research. Our investigation focuses on the interrelation among the three main mechanisms by which enantioselectivity can be bestowed to heterogeneous catalysts, namely: (1) by templating chirality via the adsorption of chiral supramolecular assemblies, (2) by using chiral modifiers capable of forming chiral complexes with the reactant and force enantioselective surface reactions, and (3) by forming naturally chiral surfaces using imprinting chiral agents. Individually, the members of our team are leaders in these various aspects of chiral catalysis, but the present program provides the vehicle to generate and exploit the synergies necessary to address the problem in a comprehensive manner. Our initial work has advanced the methodology needed for these studies, including an enantioselective titration procedure to identify surface chiral sites, infrared spectroscopy in situ at the interface between gases or liquids and solids to mimic realistic catalytic conditions, and DFT and Monte Carlo algorithms to simulate and understand chirality on surfaces. The next step, to be funded by the monies requested in this proposal, is to apply those methods to specific problems in chiral catalysis, including the identification of the requirements for the formation of supramolecular surface structures with enantioselective behavior, the search for better molecules to probe the chiral nature of the modified surfaces, the exploration of the transition from supramolecular to one-to-one chiral modification, the correlation of the adsorption characteristics of one-to-one chiral modifiers with their physical properties, in particular with their configuration, and the development of ways to imprint chiral centers on achiral solid surfaces. Chiral catalysis is not only a problem of great importance in its own right, but also the ultimate test of how to control selectivity in catalysis. The time is ripe for fundamental work in heterogeneous chiral catalysis to provide the U.S. with a leadership role in developing the next generation of catalytic processes for medicinal and agrochemical manufacturing. Our team provides the required expertise for a synergistic and comprehensive integration of physical and chemical experimentation with solid state and molecular reactivity theories to solve this problem.

  14. Modelling long-distance seed dispersal in heterogeneous landscapes.

    SciTech Connect (OSTI)

    Levey, Douglas, J.; Tewlsbury, Joshua, J.; Bolker, Benjamin, M.

    2008-01-01

    1. Long-distance seed dispersal is difficult to measure, yet key to understanding plant population dynamics and community composition. 2. We used a spatially explicit model to predict the distribution of seeds dispersed long distances by birds into habitat patches of different shapes. All patches were the same type of habitat and size, but varied in shape. They occurred in eight experimental landscapes, each with five patches of four different shapes, 150 m apart in a matrix of mature forest. The model was parameterized with smallscale movement data collected from field observations of birds. In a previous study we validated the model by testing its predictions against observed patterns of seed dispersal in real landscapes with the same types and spatial configuration of patches as in the model. 3. Here we apply the model more broadly, examining how patch shape influences the probability of seed deposition by birds into patches, how dispersal kernels (distributions of dispersal distances) vary with patch shape and starting location, and how movement of seeds between patches is affected by patch shape. 4. The model predicts that patches with corridors or other narrow extensions receive higher numbers of seeds than patches without corridors or extensions. This pattern is explained by edgefollowing behaviour of birds. Dispersal distances are generally shorter in heterogeneous landscapes (containing patchy habitat) than in homogeneous landscapes, suggesting that patches divert the movement of seed dispersers, holding them long enough to increase the probability of seed defecation in the patches. Dispersal kernels for seeds in homogeneous landscapes were smooth, whereas those in heterogenous landscapes were irregular. In both cases, long-distance (> 150 m) dispersal was surprisingly common, usually comprising approximately 50% of all dispersal events. 5. Synthesis . Landscape heterogeneity has a large influence on patterns of long-distance seed dispersal. Our results suggest that long-distance dispersal events can be predicted using spatially explicit modelling to scale-up local movements, placing them in a landscape context. Similar techniques are commonly used by landscape ecologists to model other types of movement; they offer much promise to the study of seed dispersal.

  15. RSS & Calender Feeds > News + Events > The Energy Materials Center at

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cornell News + Events In This Section EMC2 News Upcoming Events Calendar of Research Meetings Archived News RSS & Calender Feeds RSS & Calender Feeds News RSS: http://emc2.cornell.edu/rss/feed/news Events RSS: http://emc2.cornell.edu/events/rss_feed ICS: http://emc2.cornell.edu/events/ics_feed .ICS Directions: Copy the above URL Open Calender (iCal, etc.) Select "Subscribe" from the Calendar menu Paste URL into the pop-up window

  16. Tank waste remediation system phase I high-level waste feed processability assessment report

    SciTech Connect (OSTI)

    Lambert, S.L.; Stegen, G.E., Westinghouse Hanford

    1996-08-01

    This report evaluates the effects of feed composition on the Phase I high-level waste immobilization process and interim storage facility requirements for the high-level waste glass.Several different Phase I staging (retrieval, blending, and pretreatment) scenarios were used to generate example feed compositions for glass formulations, testing, and glass sensitivity analysis. Glass models and data form laboratory glass studies were used to estimate achievable waste loading and corresponding glass volumes for various Phase I feeds. Key issues related to feed process ability, feed composition, uncertainty, and immobilization process technology are identified for future consideration in other tank waste disposal program activities.

  17. High pressure feeder and method of operating to feed granular or fine materials

    DOE Patents [OSTI]

    Vimalchand, Pannalal; Liu, Guohai; Peng, Wan Wang

    2014-10-07

    A coal feed system to feed pulverized low rank coals containing up to 25 wt % moisture to gasifiers operating up to 1000 psig pressure is described. The system includes gas distributor and collector gas permeable pipes imbedded in the lock vessel. Different methods of operation of the feed system are disclosed to minimize feed problems associated with bridging and packing of the pulverized coal. The method of maintaining the feed system and feeder device exit pressures using gas addition or extraction with the pressure control device is also described.

  18. Heterogeneous nucleation of naphthalene vapor on water surface

    SciTech Connect (OSTI)

    Smolik, J.; Schwarz, J.

    1997-01-15

    Transfer processes between drops and gas play an important role in many natural and industrial processes, as absorption of gaseous pollutants by water drops in the atmosphere, combustion of fuel droplets, spray drying, synthesis of nanopowders, wet-dry desulfurization or extinguishing of hot combustion gases. The evaporation of a water drop into a ternary gaseous mixture of air, steam, and naphthalene vapor was investigated. The experimental results were compared with a theoretical prediction based on a numerical solution of coupled boundary layer equations for heat and mass transfer from a drop moving in ternary gas. In the experiments the naphthalene vapor condensed on the water drop as a supercooled liquid even at temperatures far below the melting point of naphthalene. The condensation on drop surface is discussed in terms of classical theory of heterogeneous nucleation on smooth surfaces.

  19. Ganglion dynamics of Supercritical CO2 in heterogeneous media

    Office of Scientific and Technical Information (OSTI)

    Ganglion dynamics of Supercritical CO2 in heterogeneous media SAND2015-2548C \ 1.E+01 Mobile 1.E+00 Trapped £ 1.E-01 1.E-02 1.0E-05 1.0E-04 1.0E-03 1.0E-02 Pore diameter (2rp) (m) 1.0 1.E+00 0.9 0.8 0.7 1.E-01 / / 1.E-02 £ 40 0.3 0.2 Ganglion size (cm) 0.1 0.0 1.E-03 1.E-04 1.E-03 1.E-02 Water Flow Velocity (Vw°) (m/s) Trapping efficiency Injectivity Permeability or porosity Research Team Y Wang, MJ Martinez & K Chojnicki Objectives of Research - Develop observationaNy-constrained models

  20. Cryogenic homogenization and sampling of heterogeneous multi-phase feedstock

    DOE Patents [OSTI]

    Doyle, Glenn Michael (Lakewood, CO); Ideker, Virgene Linda (Arvada, CO); Siegwarth, James David (Boulder, CO)

    2002-01-01

    An apparatus and process for producing a homogeneous analytical sample from a heterogenous feedstock by: providing the mixed feedstock, reducing the temperature of the feedstock to a temperature below a critical temperature, reducing the size of the feedstock components, blending the reduced size feedstock to form a homogeneous mixture; and obtaining a representative sample of the homogeneous mixture. The size reduction and blending steps are performed at temperatures below the critical temperature in order to retain organic compounds in the form of solvents, oils, or liquids that may be adsorbed onto or absorbed into the solid components of the mixture, while also improving the efficiency of the size reduction. Preferably, the critical temperature is less than 77 K (-196.degree. C.). Further, with the process of this invention the representative sample may be maintained below the critical temperature until being analyzed.

  1. On fluid flow in a heterogeneous medium under nonisothermal conditions

    SciTech Connect (OSTI)

    D.W., Vasco

    2010-11-01

    An asymptotic technique, valid in the presence of smoothly-varying heterogeneity, provides explicit expressions for the velocity of a propagating pressure and temperature disturbance. The governing equations contain nonlinear terms due to the presence of temperature-dependent coefficients and due to the advection of fluids with differing temperatures. Two cases give well-defined expressions in terms of the parameters of the porous medium: the uncoupled propagation of a pressure disturbance and the propagation of a fully coupled temperature and pressure disturbance. The velocity of the coupled disturbance or front, depends upon the medium parameters and upon the change in temperature and pressure across the front. For uncoupled flow, the semi-analytic expression for the front velocity reduces to that associated with a linear diffusion equation. A comparison of the asymptotic travel time estimates with calculations from a numerical simulator indicates reasonably good agreement for both uncoupled and coupled disturbances.

  2. Multiscale Universal Interface: A concurrent framework for coupling heterogeneous solvers

    SciTech Connect (OSTI)

    Tang, Yu-Hang; Kudo, Shuhei; Bian, Xin; Li, Zhen; Karniadakis, George Em

    2015-09-15

    Graphical abstract: - Abstract: Concurrently coupled numerical simulations using heterogeneous solvers are powerful tools for modeling multiscale phenomena. However, major modifications to existing codes are often required to enable such simulations, posing significant difficulties in practice. In this paper we present a C++ library, i.e. the Multiscale Universal Interface (MUI), which is capable of facilitating the coupling effort for a wide range of multiscale simulations. The library adopts a header-only form with minimal external dependency and hence can be easily dropped into existing codes. A data sampler concept is introduced, combined with a hybrid dynamic/static typing mechanism, to create an easily customizable framework for solver-independent data interpretation. The library integrates MPI MPMD support and an asynchronous communication protocol to handle inter-solver information exchange irrespective of the solvers' own MPI awareness. Template metaprogramming is heavily employed to simultaneously improve runtime performance and code flexibility. We validated the library by solving three different multiscale problems, which also serve to demonstrate the flexibility of the framework in handling heterogeneous models and solvers. In the first example, a Couette flow was simulated using two concurrently coupled Smoothed Particle Hydrodynamics (SPH) simulations of different spatial resolutions. In the second example, we coupled the deterministic SPH method with the stochastic Dissipative Particle Dynamics (DPD) method to study the effect of surface grafting on the hydrodynamics properties on the surface. In the third example, we consider conjugate heat transfer between a solid domain and a fluid domain by coupling the particle-based energy-conserving DPD (eDPD) method with the Finite Element Method (FEM)

  3. Impact of heterogeneous chemistry on model predictions of ozone changes

    SciTech Connect (OSTI)

    Granier, C.; Brasseur, G. )

    1992-11-20

    A two-dimensional chemical/transport model of the middle atmosphere is used to assess the importance of chemical heterogeneous processes in the polar regions (on polar stratospheric clouds (PSCs)) and at other latitudes (on sulfate aerosols). When conversion on type I and type II PSCs of N[sub 2]O[sub 5] into HNO[sub 3] and of CIONO[sub 2] into reactive forms of chlorine is taken into account, enhanced CIO concentrations lead to the formation of a springtime ozone hole over the Antarctic continent; no such major reduction in the ozone column is found in the Arctic region. When conversion of nitrogen and chlorine compounds is assumed to occur on sulfate particles in the lower stratosphere, significant perturbations in the chemistry are also found. For background aerosol conditions, the concentration of nitric acid is enhanced and agrees with observed values, while that of nitrogen oxides is reduced and agrees less than if heterogeneous processes are ignored in the calculations. The concentration of the OH radical is significantly increased. Ozone number density appears to become larger between 16 and 30 km but smaller below 16 km, especially at high latitudes. The ozone column is only slightly modified, except at high latitudes where it is substantially reduced if the CIONO[sub 2] conversion into reactive chlorine is considered. After a large volcanic eruption these changes are further exacerbated. The ozone budget in the lower stratrosphere becomes less affected by nitrogen oxides but is largely controlled by the CIO[sub x] and HO[sub x] chemistries. A substantial decrease in the ozone column is predicted as a result of the Pinatubo volcanic eruption, mostly in winter at middle and high latitudes. 62 refs., 18 figs., 3 tabs.

  4. Linkage heterogeneity among 59 Dutch hereditary breast cancer families

    SciTech Connect (OSTI)

    Cornelis, R.S.; Vliet, M. van; Leeuwen, I. van

    1994-09-01

    We have investigated 59 Dutch kindreds with at least three first-degree relatives with breast and/or ovarian cancer for linkage to BRCA1 on 17q12-q21, using at least 4 microsatellite markers flanking BRCA1 on either side. Assuming no heterogeneity, the overall multipoint lod score in this group of families was -7.59. A marked clustering of lod scores >0.5 was observed among the 13 families with a mean age of onset lower than 45 (total lod score: +3.36). Among the 8 kindreds with a mean age of onset lower than 45 and {ge}3 cases diagnosed under 45, the lod score was +4.43. Interestingly, most of the evidence against linkage was found in 17 families with a mean age of onset between 45 and 54 (total lod score of -8.72). It was estimated that 28% of the breast-only families might be caused by BRCA1. Over the 16 breast-ovarian cancer families a lod score of -3.78 was obtained under homogeneity. The highest lod score was +0.57, assuming heterogeneity with 33% of the families being linked to BRCA1. One family gave a multipoint lod score of -2.01 and thereby satisfies the conventional criterion of an unlinked family. Our results support the conclusions from earlier work by others, namely that BRCA1 predisposes particularly to early-onset breast cancer. The proportion of breast-ovarian cancer families we found linked to BRCA1 is much lower than that found by the Breast Cancer Linkage Consortium. This might be caused by the single unlinked family against an insufficient number of families able to give conclusive positive lod scores.

  5. X-ray micro-diffraction studies of heterogeneous interfaces between...

    Office of Scientific and Technical Information (OSTI)

    Article: X-ray micro-diffraction studies of heterogeneous interfaces between cementitious materials and geological formations Citation Details In-Document Search Title: X-ray ...

  6. An advanced feed pump based on magnetic bearings

    SciTech Connect (OSTI)

    Hanson, L.

    1996-11-01

    Pumps have not used magnetic bearings commercially due to their high initial cost and the perception of a high risk to reward ratio. However, by taking advantage of the capability of the bearings to operate submerged in the pumped liquid, an advanced boiler feed pump has been developed with measurably improved efficiency and reduced seal maintenance. When the economic value of these improvements are evaluated against the additional first cost of the bearing change, attractive paybacks are generated for most new plant applications and even for some retrofits where the first cost reductions from eliminating the oil system, bearings, and seals do not apply. These savings are in addition to the benefits long recognized for magnetic bearings: improved reliability; built-in remote monitoring and diagnostics; elimination of the pressure feed oil system and its maintenance and potential fire hazard. Based on these advantages a research and development prototype pump incorporating the new technology was built and tested. A commercial opportunity to demonstrate this new design arose in 1994 and resulted in the sale of an eight stage, 3500 HP feed pump to Tampa Electric Company for their new Polk Station Generating Plant. This is the largest known magnetic bearing pump delivered for commercial operation worldwide. The pump was shipped during August 1995 and is expected to enter service during the first half of 1996. This paper will briefly introduce magnetic bearings and then discuss the design of the advanced pump. The basis for predicting improved efficiency and estimating its value will be presented followed by the experience in manufacturing and testing the pump for Polk Generating Station.

  7. Microsoft Word - Title Page Wood Feeding Beetle 2013.docx

    Office of Scientific and Technical Information (OSTI)

    M etagenomic Profiling Reveals Lignocellulose Degrading System in a Microbial Community Associated w ith a Wood- Feeding Beetle July 2013 Correspondence should be addressed to: John E. Carlson - i e c l 6 @ p s u . e d u Scully, Erin D.1; Geib, Scott M.2; Hoover, Kelli3; Tien, Ming4; Tringe, S usannah G.5; Barry, Kerrie W.3 ; Glavina del Rio, Tijana5; Chovatia,M ansi5; Herr, Joshua R.6 7 ; and Carlson, John E .7' 8 1 Intercollege Program in Genetics a t the Huck Institutes of the Life Sciences,

  8. Feed-forward digital phase and amplitude correction system

    DOE Patents [OSTI]

    Yu, David U. L.; Conway, Patrick H.

    1994-01-01

    Phase and amplitude modifications in repeatable RF pulses at the output of a high power pulsed microwave amplifier are made utilizing a digital feed-forward correction system. A controlled amount of the output power is coupled to a correction system for processing of phase and amplitude information. The correction system comprises circuitry to compare the detected phase and amplitude with the desired phase and amplitude, respectively, and a digitally programmable phase shifter and attenuator and digital logic circuitry to control the phase shifter and attenuator. The Phase and amplitude of subsequent are modified by output signals from the correction system.

  9. Feed-forward digital phase and amplitude correction system

    DOE Patents [OSTI]

    Yu, D.U.L.; Conway, P.H.

    1994-11-15

    Phase and amplitude modifications in repeatable RF pulses at the output of a high power pulsed microwave amplifier are made utilizing a digital feed-forward correction system. A controlled amount of the output power is coupled to a correction system for processing of phase and amplitude information. The correction system comprises circuitry to compare the detected phase and amplitude with the desired phase and amplitude, respectively, and a digitally programmable phase shifter and attenuator and digital logic circuitry to control the phase shifter and attenuator. The phase and amplitude of subsequent are modified by output signals from the correction system. 11 figs.

  10. Privatization contractor transfer/feed line corridor obstructions

    SciTech Connect (OSTI)

    Parazin, R.J.

    1998-05-20

    One of the issues that came out of the Tank Waste Remediation System (TWRS) Privatization Interface Control Document (ICD) effort was the need to identify below grade obstructions that exist where the TWRS Privatization Phase 1 transfer/feed corridors pass through the former Grout complex (ICD Issue 9C). Due to the numerous phases of construction at the complex, and the lack of consolidated facility configuration drawings, as-built (or as-recorded) information on the area is difficult to find, let alone decipher. To resolve the issue, this study was commissioned to identify and consolidate the as-recorded information available (drawings and Engineering Change Notices, ECNS).

  11. Pressurized feed-injection spray-forming apparatus

    DOE Patents [OSTI]

    Berry, Ray A. (Idaho Falls, ID); Fincke, James R. (Idaho Falls, ID); McHugh, Kevin M. (Idaho Falls, ID)

    1995-01-01

    A spray apparatus and method for injecting a heated, pressurized liquid in a first predetermined direction into a pressurized gas flow that is flowing in a second predetermined direction, to provide for atomizing and admixing the liquid with the gas to form a two-phase mixture. A valve is also disposed within the injected liquid conduit to provide for a pulsed injection of the liquid and timed deposit of the atomized gas phase. Preferred embodiments include multiple liquid feed ports and reservoirs to provide for multiphase mixtures of metals, ceramics, and polymers.

  12. Pressurized feed-injection spray-forming apparatus

    DOE Patents [OSTI]

    Berry, R.A.; Fincke, J.R.; McHugh, K.M.

    1995-08-29

    A spray apparatus and method are disclosed for injecting a heated, pressurized liquid in a first predetermined direction into a pressurized gas flow that is flowing in a second predetermined direction, to provide for atomizing and admixing the liquid with the gas to form a two-phase mixture. A valve is also disposed within the injected liquid conduit to provide for a pulsed injection of the liquid and timed deposit of the atomized gas phase. Preferred embodiments include multiple liquid feed ports and reservoirs to provide for multiphase mixtures of metals, ceramics, and polymers. 22 figs.

  13. Solid fuel feed system for a fluidized bed

    DOE Patents [OSTI]

    Jones, Brian C.

    1982-01-01

    A fluidized bed for the combustion of coal, with limestone, is replenished with crushed coal from a system discharging the coal laterally from a station below the surface level of the bed. A compartment, or feed box, is mounted at one side of the bed and its interior separated from the bed by a weir plate beneath which the coal flows laterally into the bed while bed material is received into the compartment above the plate to maintain a predetermined minimum level of material in the compartment.

  14. Nitrite in feed: From Animal health to human health

    SciTech Connect (OSTI)

    Cockburn, Andrew; Brambilla, Gianfranco; Fernndez, Maria-Luisa; Arcella, Davide; Peteghem, Carlos van; Dorne, Jean-Lou

    2013-08-01

    Nitrite is widely consumed from the diet by animals and humans. However the largest contribution to exposure results from the in vivo conversion of exogenously derived nitrate to nitrite. Because of its potential to cause to methaemoglobin (MetHb) formation at excessive levels of intake, nitrite is regulated in feed and water as an undesirable substance. Forages and contaminated water have been shown to contain high levels of nitrate and represent the largest contributor to nitrite exposure for food-producing animals. Interspecies differences in sensitivity to nitrite intoxication principally result from physiological and anatomical differences in nitrite handling. In the case of livestock both pigs and cattle are relatively susceptible. With pigs this is due to a combination of low levels of bacterial nitrite reductase and hence potential to reduce nitrite to ammonia as well as reduced capacity to detoxify MetHb back to haemoglobin (Hb) due to intrinsically low levels of MetHb reductase. In cattle the sensitivity is due to the potential for high dietary intake and high levels of rumen conversion of nitrate to nitrite, and an adaptable gut flora which at normal loadings shunts nitrite to ammonia for biosynthesis. However when this escape mechanism gets overloaded, nitrite builds up and can enter the blood stream resulting in methemoglobinemia. Looking at livestock case histories reported in the literature no-observed-effect levels of 3.3 mg/kg body weight (b.w.) per day for nitrite in pigs and cattle were estimated and related to the total daily nitrite intake that would result from complete feed at the EU maximum permissible level. This resulted in margins of safety of 9-fold and 5-fold for pigs and cattle, respectively. Recognising that the bulkiness of animal feed limits their consumption, these margins in conjunction with good agricultural practise were considered satisfactory for the protection of livestock health. A human health risk assessment was also carried out taking into account all direct and indirect sources of nitrite from the human diet, including carry-over of nitrite in animal-based products such as milk, eggs and meat products. Human exposure was then compared with the acceptable daily intake (ADI) for nitrite of 0-0.07 mg/kg b.w. per day. Overall, the low levels of nitrite in fresh animal products represented only 2.9% of the total daily dietary exposure and thus were not considered to raise concerns for human health. It is concluded that the potential health risk to animals from the consumption of feed or to man from eating fresh animal products containing nitrite, is very low.

  15. THE HANFORD WASTE FEED DELIVERY OPERATIONS RESEARCH MODEL

    SciTech Connect (OSTI)

    BERRY J; GALLAHER BN

    2011-01-13

    Washington River Protection Solutions (WRPS), the Hanford tank farm contractor, is tasked with the long term planning of the cleanup mission. Cleanup plans do not explicitly reflect the mission effects associated with tank farm operating equipment failures. EnergySolutions, a subcontractor to WRPS has developed, in conjunction with WRPS tank farms staff, an Operations Research (OR) model to assess and identify areas to improve the performance of the Waste Feed Delivery Systems. This paper provides an example of how OR modeling can be used to help identify and mitigate operational risks at the Hanford tank farms.

  16. Molecular-level Design of Heterogeneous Chiral Catalysts

    SciTech Connect (OSTI)

    Gellman, Andrew John; Sholl, David S.; Tysoe, Wilfred T.; Zaera, Francisco

    2013-04-28

    Understanding and controlling selectivity is one of the key challenges in heterogeneous catalysis. Among problems in catalytic selectivity enantioselectivity is perhaps the most the most challenging. The primary goal of the project on Molecular-level Design of Heterogeneous Chiral Catalysts is to understand the origins of enantioselectivity on chiral heterogeneous surfaces and catalysts. The efforts of the project team include preparation of chiral surfaces, characterization of chiral surfaces, experimental detection of enantioselectivity on such surfaces and computational modeling of the interactions of chiral probe molecules with chiral surfaces. Over the course of the project period the team of PIs has made some of the most detailed and insightful studies of enantioselective chemistry on chiral surfaces. This includes the measurement of fundamental interactions and reaction mechanisms of chiral molecules on chiral surfaces and leads all the way to rationale design and synthesis of chiral surfaces and materials for enantioselective surface chemistry. The PIs have designed and prepared new materials for enantioselective adsorption and catalysis. Naturally Chiral Surfaces Completion of a systematic study of the enantiospecific desorption kinetics of R-3-methylcyclohexanone (R-3-MCHO) on 9 achiral and 7 enantiomeric pairs of chiral Cu surfaces with orientations that span the stereographic triangle. Discovery of super-enantioselective tartaric acid (TA) and aspartic acid (Asp) decomposition as a result of a surface explosion mechanism on Cu(643)R&S. Systematic study of super-enantiospecific TA and Asp decomposition on five enantiomeric pairs of chiral Cu surfaces. Initial observation of the enantiospecific desorption of R- and S-propylene oxide (PO) from Cu(100) imprinted with {3,1,17} facets by L-lysine adsorption. Templated Chiral Surfaces Initial observation of the enantiospecific desorption of R- and S-PO from Pt(111) and Pd(111) modified by a variety of chiral templates. Demonstrated enantioselective separation of racemic PO on chemically synthesized chiral gold nanoparticles. Discovery of zwitterionic adsorption states of amino acids on Pd(111). First structure determinations of adsorbed amino acids and identification of tetrameric chiral template structures. Exploration of the enantiospecific interaction of PO and R-3-MCHO adsorption on chirally modified Cu(100), Cu(110) and Cu(111). One-to-One Interactions Determination of cinchona orientation on Pt surfaces in situ at the solid-liquid interface using FT-IRAS. Systematic study of the influence of solution properties on the adsorption of modified cinchonas alkaloids onto Pt surfaces. Correlation of cinchona adsorption with catalytic activity, as affected by concentration, the nature of the solvent, and dissolved gases in the liquid phase. Measurement of enantioselective chemisorption on 1-(1-naphthyl) ethylamine (NEA) modified Pt(111) and Pd(111) surfaces. Imaging of chiral docking complexes between NEA and methyl pyruvate on Pd(111). Chiral Catalyst Synthesis Anchoring of cinchona alkaloid to surfaces Synthesis of chiral Au nanoparticles and demonstration of their enantiospecific interactions with R- and S-PO. Elucidation of the driving forces for chiral imprinting of Cu(100) by L- and D-lysine to form Cu(3,1,17)R&S facets.

  17. Vertical feed stick wood fuel burning furnace system

    DOE Patents [OSTI]

    Hill, Richard C.

    1984-01-01

    A new and improved stove or furnace for efficient combustion of wood fuel including a vertical feed combustion chamber for receiving and supporting wood fuel in a vertical attitude or stack, a major upper portion of the combustion chamber column comprising a water jacket for coupling to a source of water or heat transfer fluid and for convection circulation of the fluid for confining the locus of wood fuel combustion to the bottom of the vertical gravity feed combustion chamber. A flue gas propagation delay channel extending from the laterally directed draft outlet affords delayed travel time in a high temperature environment to assure substantially complete combustion of the gaseous products of wood burning with forced air as an actively induced draft draws the fuel gas and air mixture laterally through the combustion and high temperature zone. Active sources of forced air and induced draft are included, multiple use and circuit couplings for the recovered heat, and construction features in the refractory material substructure and metal component superstructure.

  18. Characteristics of the positive ion source at reduced gas feed

    SciTech Connect (OSTI)

    Sharma, S. K. Bharathi, P.; Prahlad, V.; Patel, P. J.; Choksi, B.; Jana, M. R.; Bansal, L. K.; Qureshi, K.; Sumod, C. B.; Vadher, V.; Thakkar, D.; Gupta, L. N.; Rambabu, S.; Parmar, S.; Contractor, N.; Sahu, A. K.; Pandya, B.; Sridhar, B.; Pandya, S.; Baruah, U. K.

    2014-11-15

    The neutral beam injector of steady state superconducting tokamak (SST1-NBI) at IPR is designed for injecting upto 1.7 MW of neutral beam (H, 3055 keV) power to the tokamak plasma for heating and current drive. Operations of the positive ion source (PINI or Plug-In-Neutral-Injector) of SST1-NBI were carried out on the NBI test stand. The PINI was operated at reduced gas feed rate of 23 Torr l/s, without using the high speed cryo pumps. Experiments were conducted to achieve a stable beam extraction by optimizing operational parameters namely, the arc current (120300 A), acceleration voltage (1640 kV), and a suitable control sequence. The beam divergence, power density profiles, and species fractions (H{sup +}:H{sub 2}{sup +}:H{sub 3}{sup +}) were measured by using the diagnostics such as thermal calorimetry, infrared thermography, and Doppler shift spectroscopy. The maximum extracted beam current was about 18 A. A further increase of beam current was found to be limited by the amount of gas feed rate to the ion source.

  19. Self-cleaning feed distributing delivery device for glass melters

    DOE Patents [OSTI]

    Mensink, Daniel L. (155 Gatewood Dr., Aiken, SC 29801)

    1992-01-01

    A self cleaning, plug resistant, adjustable parameter feed distributing and delivery apparatus for a glass melter comprising a housing with a passage therethrough for a glass slurry, a cold finger within the passage for creating a dispersion pattern of the slurry, a movable slotted tube for controlling the confluence of air propellant and slurry in the passage, and a plurality of ribs that extend through the slots in the slotted tube to urge the slurry forward if it becomes stuck or resists forward movement. Coolant passages in the housing and the cold finger maintain the slurry temperature below that of the melter plenum. The cold finger is axially movable to adjust the dispersion pattern to the desired consistency. Other design features of size can be applied for use in situations requiring different parameters of pattern, particle size, rate, and feed consistencies. The device utilizes air as both a propellant and a surface cleansing mechanism. Other fluids may be used as propellants where process compatibility requires.

  20. Utilizing interfaces: One-step forward for rational design of heterogeneous catalysts

    SciTech Connect (OSTI)

    Kim H. Y.

    2013-06-20

    As far as heterogeneous catalysts are a composite material, physicochemical properties of the interfaces between individual components should be extensively studied for rational design of catalysts with desired properties. Here, I will present recent computational achievements in following three heterogeneous catalysts where the interface between composing materials plays a critical role

  1. Converting Homogeneous to Heterogeneous in Electrophilic Catalysis using Monodisperse Metal Nanoparticles

    SciTech Connect (OSTI)

    Witham, Cole A.; Huang, Wenyu; Tsung, Chia-Kuang; Kuhn, John N.; Somorjai, Gabor A.; Toste, F. Dean

    2009-10-15

    A continuing goal in catalysis is the transformation of processes from homogeneous to heterogeneous. To this end, nanoparticles represent a new frontier in heterogeneous catalysis, where this conversion is supplemented by the ability to obtain new or divergent reactivity and selectivity. We report a novel method for applying heterogeneous catalysts to known homogeneous catalytic reactions through the design and synthesis of electrophilic platinum nanoparticles. These nanoparticles are selectively oxidized by the hypervalent iodine species PhICl{sub 2}, and catalyze a range of {pi}-bond activation reactions previously only homogeneously catalyzed. Multiple experimental methods are utilized to unambiguously verify the heterogeneity of the catalytic process. The discovery of treatments for nanoparticles that induce the desired homogeneous catalytic activity should lead to the further development of reactions previously inaccessible in heterogeneous catalysis. Furthermore, our size and capping agent study revealed that Pt PAMAM dendrimer-capped nanoparticles demonstrate superior activity and recyclability compared to larger, polymer-capped analogues.

  2. Heterogeneity and dynamics in villin headpiece crystal structures

    SciTech Connect (OSTI)

    Meng, Jianmin; McKnight, Christopher James, E-mail: cjmck@bu.edu [Boston University School of Medicine (United States)

    2009-05-01

    New crystal structures of the well studied protein-folding model system villin headpiece in a new space group provide insights into the conformations available in the folded state. The villin headpiece domain (HP67) is the C-terminal F-actin-binding motif that confers F-actin-bundling activity to villin, a component of the actin bundles that support the brush-border microvilli. It has been investigated extensively by both experimental and theoretical measurements. Our laboratory, for example, has determined both its NMR and its crystal structures. This study presents the structures of HP67 and its pH-stabilized mutant (H41Y) in a different crystal form and space group. For both constructs, two molecules are found in each asymmetric unit in the new space group P6{sub 1}. While one of the two structures (Mol A) is structurally similar to our previously determined structure (Mol X), the other (Mol B) has significant deviations, especially in the N-terminal subdomain, where lattice contacts do not appear to contribute to the difference. In addition, the structurally most different crystal structure, Mol B, is actually closer to the averaged NMR structure. Harmonic motions, as suggested by the B-factor profiles, differ between these crystal structures; crystal structures from the same space group share a similar pattern. Thus, heterogeneity and dynamics are observed in different crystal structures of the same protein even for a protein as small as villin headpiece.

  3. A Method for Correcting IMRT Optimizer Heterogeneity Dose Calculations

    SciTech Connect (OSTI)

    Zacarias, Albert S.; Brown, Mellonie F. Mills, Michael D.

    2010-04-01

    Radiation therapy treatment planning for volumes close to the patient's surface, in lung tissue and in the head and neck region, can be challenging for the planning system optimizer because of the complexity of the treatment and protected volumes, as well as striking heterogeneity corrections. Because it is often the goal of the planner to produce an isodose plan with uniform dose throughout the planning target volume (PTV), there is a need for improved planning optimization procedures for PTVs located in these anatomical regions. To illustrate such an improved procedure, we present a treatment planning case of a patient with a lung lesion located in the posterior right lung. The intensity-modulated radiation therapy (IMRT) plan generated using standard optimization procedures produced substantial dose nonuniformity across the tumor caused by the effect of lung tissue surrounding the tumor. We demonstrate a novel iterative method of dose correction performed on the initial IMRT plan to produce a more uniform dose distribution within the PTV. This optimization method corrected for the dose missing on the periphery of the PTV and reduced the maximum dose on the PTV to 106% from 120% on the representative IMRT plan.

  4. Inverse problems in heterogeneous and fractured media using peridynamics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Turner, Daniel Z.; van Bloemen Waanders, Bart G.; Parks, Michael L.

    2015-12-10

    The following work presents an adjoint-based methodology for solving inverse problems in heterogeneous and fractured media using state-based peridynamics. We show that the inner product involving the peridynamic operators is self-adjoint. The proposed method is illustrated for several numerical examples with constant and spatially varying material parameters as well as in the context of fractures. We also present a framework for obtaining material parameters by integrating digital image correlation (DIC) with inverse analysis. This framework is demonstrated by evaluating the bulk and shear moduli for a sample of nuclear graphite using digital photographs taken during the experiment. The resulting measuredmore » values correspond well with other results reported in the literature. Lastly, we show that this framework can be used to determine the load state given observed measurements of a crack opening. Furthermore, this type of analysis has many applications in characterizing subsurface stress-state conditions given fracture patterns in cores of geologic material.« less

  5. Application of solid ash based catalysts in heterogeneous catalysis

    SciTech Connect (OSTI)

    Shaobin Wang

    2008-10-01

    Solid wastes, fly ash, and bottom ash are generated from coal and biomass combustion. Fly ash is mainly composed of various metal oxides and possesses higher thermal stability. Utilization of fly ash for other industrial applications provides a cost-effective and environmentally friendly way of recycling this solid waste, significantly reducing its environmental effects. On the one hand, due to the higher stability of its major component, aluminosilicates, fly ash could be employed as catalyst support by impregnation of other active components for various reactions. On the other hand, other chemical compounds in fly ash such as Fe{sub 2}O{sub 3} could also provide an active component making fly ash a catalyst for some reactions. In this paper, physicochemical properties of fly ash and its applications for heterogeneous catalysis as a catalyst support or catalyst in a variety of catalytic reactions were reviewed. Fly-ash-supported catalysts have shown good catalytic activities for H{sub 2} production, deSOx, deNOx, hydrocarbon oxidation, and hydrocracking, which are comparable to commercially used catalysts. As a catalyst itself, fly ash can also be effective for gas-phase oxidation of volatile organic compounds, aqueous-phase oxidation of organics, solid plastic pyrolysis, and solvent-free organic synthesis. 107 refs., 4 figs., 2 tabs.

  6. Aggregate Model for Heterogeneous Thermostatically Controlled Loads with Demand Response

    SciTech Connect (OSTI)

    Zhang, Wei; Kalsi, Karanjit; Fuller, Jason C.; Elizondo, Marcelo A.; Chassin, David P.

    2012-07-22

    Due to the potentially large number of Distributed Energy Resources (DERs) demand response, distributed generation, distributed storage - that are expected to be deployed, it is impractical to use detailed models of these resources when integrated with the transmission system. Being able to accurately estimate the fast transients caused by demand response is especially important to analyze the stability of the system under different demand response strategies. On the other hand, a less complex model is more amenable to design feedback control strategies for the population of devices to provide ancillary services. The main contribution of this paper is to develop aggregated models for a heterogeneous population of Thermostatic Controlled Loads (TCLs) to accurately capture their collective behavior under demand response and other time varying effects of the system. The aggregated model efficiently includes statistical information of the population and accounts for a second order effect necessary to accurately capture the collective dynamic behavior. The developed aggregated models are validated against simulations of thousands of detailed building models using GridLAB-D (an open source distribution simulation software) under both steady state and severe dynamic conditions caused due to temperature set point changes.

  7. Supporting Dynamic Spectrum Access in Heterogeneous LTE+ Networks

    SciTech Connect (OSTI)

    Luiz A. DaSilva; Ryan E. Irwin; Mike Benonis

    2012-08-01

    As early as 2014, mobile network operators’ spectral capac- ity is expected to be overwhelmed by the demand brought on by new devices and applications. With Long Term Evo- lution Advanced (LTE+) networks likely as the future one world 4G standard, network operators may need to deploy a Dynamic Spectrum Access (DSA) overlay in Heterogeneous Networks (HetNets) to extend coverage, increase spectrum efficiency, and increase the capacity of these networks. In this paper, we propose three new management frameworks for DSA in an LTE+ HetNet: Spectrum Accountability Client, Cell Spectrum Management, and Domain Spectrum Man- agement. For these spectrum management frameworks, we define protocol interfaces and operational signaling scenar- ios to support cooperative sensing, spectrum lease manage- ment, and alarm scenarios for rule adjustment. We also quan- tify, through integer programs, the benefits of using DSA in an LTE+ HetNet, that can opportunistically reuse vacant TV and GSM spectrum. Using integer programs, we consider a topology using Geographic Information System data from the Blacksburg, VA metro area to assess the realistic benefits of DSA in an LTE+ HetNet.

  8. The Effect of Foaming and Silica Dissolution on Melter Feed Rheology during Conversion to Glass

    SciTech Connect (OSTI)

    Marcial, Jose; Chun, Jaehun; Hrma, Pavel R.; Schweiger, Michael J.

    2014-11-23

    As the nuclear waste glass melter feed is converted to molten glass, the feed eventually becomes a continuous glass-forming melt in which dissolving refractory constituents are suspended together with numerous gas bubbles. Knowledge of mechanical properties of the melter feed is crucial for understanding the feed-to-glass conversion as it occurs in the cold cap. We measured the viscosity during heating of the feed and correlated it with the independently determined volume fractions of dissolving quartz particles and the gas phase. The measurement was performed with a rotating spindle rheometer on the melter feed heated at 5 K/min starting at several different temperatures. The effect of quartz particles, gas bubbles, and compositional inhomogeneity on the glass-forming melt viscosity was determined by fitting a linear relationship between log viscosity and volume fractions of suspended phases to data.

  9. A Policymaker's Guide to Feed-in Tariff Policy Design (Technical Report) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect A Policymaker's Guide to Feed-in Tariff Policy Design Citation Details In-Document Search Title: A Policymaker's Guide to Feed-in Tariff Policy Design Feed-in tariffs (FITs) are the most widely used renewable energy policy in the world for driving accelerating renewable energy (RE) deployment, accounting for a greater share of RE development than either tax incentives or renewable portfolio standard (RPS) policies. FITs have generated significant RE deployment, helping bring

  10. Feeding Arteries of Primary Tongue Cancers on Intra-arterial Infusion

    Office of Scientific and Technical Information (OSTI)

    Chemotherapy (Journal Article) | SciTech Connect Feeding Arteries of Primary Tongue Cancers on Intra-arterial Infusion Chemotherapy Citation Details In-Document Search Title: Feeding Arteries of Primary Tongue Cancers on Intra-arterial Infusion Chemotherapy PurposeTo evaluate the frequency and the predictive factor of each feeding artery on intra-arterial infusion chemotherapy (IAIC) in primary tongue cancer.Materials and MethodsWe retrospectively evaluated 20 patients who received IAIC for

  11. Application of evolved gas analysis to cold-cap reactions of melter feeds

    Office of Scientific and Technical Information (OSTI)

    for nuclear waste vitrification (Journal Article) | SciTech Connect Application of evolved gas analysis to cold-cap reactions of melter feeds for nuclear waste vitrification Citation Details In-Document Search Title: Application of evolved gas analysis to cold-cap reactions of melter feeds for nuclear waste vitrification In the vitrification of nuclear wastes, the melter feed (a mixture of nuclear waste and glass forming and modifying additives) experiences multiple gas-evolving reactions in

  12. Process and apparatus for preheating heavy feed to a catalytic cracking

    Office of Scientific and Technical Information (OSTI)

    unit (Patent) | SciTech Connect Process and apparatus for preheating heavy feed to a catalytic cracking unit Citation Details In-Document Search Title: Process and apparatus for preheating heavy feed to a catalytic cracking unit This patent describes an improvement in a catalytic cracking process wherein a heavy hydrocarbon feed comprising hydrocarbons having a boiling point above about 650{degrees}F is catalytically cracked to cracked products. It comprises preheating at least a portion of

  13. Process and apparatus for split feed of spent catalyst to high efficiency

    Office of Scientific and Technical Information (OSTI)

    catalyst regenerator (Patent) | SciTech Connect Process and apparatus for split feed of spent catalyst to high efficiency catalyst regenerator Citation Details In-Document Search Title: Process and apparatus for split feed of spent catalyst to high efficiency catalyst regenerator This patent describes a fluidized catalytic cracking process for catalytic cracking of a heavy hydrocarbon feed. It comprises hydrocarbons having a boiling point above about 650{degrees} F to lighter products by

  14. Renewable Energy Prices in State-Level Feed-in Tariffs. Federal Law

    Office of Scientific and Technical Information (OSTI)

    Constraints and Possible Solutions (Technical Report) | SciTech Connect Prices in State-Level Feed-in Tariffs. Federal Law Constraints and Possible Solutions Citation Details In-Document Search Title: Renewable Energy Prices in State-Level Feed-in Tariffs. Federal Law Constraints and Possible Solutions This report details how state feed-in tariff (FIT) programs can be legally implemented and how they can comply with federal requirements. The report describes the federal constraints on FIT

  15. Innovative Feed-In Tariff Designs that Limit Policy Costs (Technical

    Office of Scientific and Technical Information (OSTI)

    Report) | SciTech Connect Innovative Feed-In Tariff Designs that Limit Policy Costs Citation Details In-Document Search Title: Innovative Feed-In Tariff Designs that Limit Policy Costs Feed-in tariffs (FITs) are the most prevalent policy used globally to reduce development risks, cut financing costs, and grow the renewable energy industry. However, concerns over escalating costs in jurisdictions with FIT policies have led to increased attention on cost control. Using case studies and

  16. Renewable Energy Prices in State-Level Feed-in Tariffs. Federal...

    Office of Scientific and Technical Information (OSTI)

    Renewable Energy Prices in State-Level Feed-in Tariffs. Federal Law Constraints and Possible Solutions Citation Details In-Document Search Title: Renewable Energy Prices in ...

  17. POLYMER ELECTROLYTE MEMBRANE ELECTROLYZER OPERATION WITH VARYING INLET WATER FEED CONFIGURATIONS

    SciTech Connect (OSTI)

    Fox, E

    2008-09-12

    Proton Exchange Membrane (PEM) electrolysis is a potential alternative technology to crack water in specialty applications where a dry gas stream is needed, such as isotope production. One design proposal is to feed the cathode of the electrolyzer with vapor phase water. This feed configuration would allow isotopic water to be isolated on the cathode side of the electrolyzer and the isotope recovery system could be operated in a closed loop. Tests were performed to characterize the difference in the current-voltage behavior between a PEM electrolyzer operated with a cathode water vapor feed and with an anode liquid water feed. The cathode water vapor feed cell had a maximum limiting current density of 100 mA/cm2 at 70 C compared to a current density of 800 mA/cm2 for the anode liquid feed cell at 70 C. The limiting current densities for the cathode water vapor feed cell were approximately 3 times lower than predicted by a water mass transfer model. It is estimated that a cathode water vapor feed electrolyzer system will need to be between 8-14 times larger in active area or number of cells than an anode liquid feed system.

  18. Large-Scale Production of Marine Microalgae for Fuel and Feeds

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bioenergy Technologies Office (BETO) 2015 Project Peer Review Large-Scale Production of Marine Microalgae for Fuel and Feeds March 24, 2015 Algae Platform Review Mark Huntley ...

  19. WPN 06-6: Weatherization Whole House Assessment Training Live Feed DVD

    Broader source: Energy.gov [DOE]

    To issue the Weatherization Whole-House Training Assessment Training Live Feed DVD to all grantees for use in the Weatherization Assistance Program (WAP).

  20. Air feed tube support system for a solid oxide fuel cell generator

    DOE Patents [OSTI]

    Doshi, Vinod B. (Monroeville, PA); Ruka, Roswell J. (Pittsburgh, PA); Hager, Charles A. (Zelienople, PA)

    2002-01-01

    A solid oxide fuel cell generator (12), containing tubular fuel cells (36) with interior air electrodes (18), where a supporting member (82) containing a plurality of holes (26) supports oxidant feed tubes (51), which pass from an oxidant plenum (52") into the center of the fuel cells, through the holes (26) in the supporting member (82), where a compliant gasket (86) around the top of the oxidant feed tubes and on top (28) of the supporting member (82) helps support the oxidant feed tubes and center them within the fuel cells, and loosen the tolerance for centering the air feed tubes.

  1. A Mock UF6 Feed and Withdrawal System for Testing Safeguards...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: A Mock UF6 Feed and Withdrawal System for Testing Safeguards Monitoring Systems and Strategies Intended for Nuclear Fuel Enrichment and Processing Plants Citation ...

  2. A Mock UF6 Feed and Withdrawal System for Testing Safeguards...

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Technical Report: A Mock UF6 Feed and Withdrawal System for Testing Safeguards Monitoring Systems and Strategies Intended for Nuclear Fuel Enrichment ...

  3. Best Practices and Design Options for Feed-in Tariffs | Open...

    Open Energy Info (EERE)

    Area: Renewable Energy Topics: Policiesdeployment programs Resource Type: Publications, Lessons learnedbest practices References: Evaluation of different feed-in tariff design...

  4. "Feds Feed Families" Events to Be Held at Department of Energy Facilities |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy "Feds Feed Families" Events to Be Held at Department of Energy Facilities "Feds Feed Families" Events to Be Held at Department of Energy Facilities August 4, 2011 - 9:23am Addthis Deputy Secretary Daniel Poneman and his band "Yellow Cake" at last year's Feds Feed Families event. | Energy Department photo Deputy Secretary Daniel Poneman and his band "Yellow Cake" at last year's Feds Feed Families event. | Energy Department photo

  5. Waste feed delivery environmental permits and approvals plan

    SciTech Connect (OSTI)

    Papp, I.G.

    1998-07-06

    This document describes the range of environmental actions, including required permits and other agency approvals, that may affect waste feed delivery (WFD) activities in the Hanford Site`s Tank Waste Remediation System (TWRS). This plan expands on the summary level information in the Tank Waste Remediation System Environmental Program Plan (HNF 1773) to address requirements that are most pertinent to WFD. This plan outlines alternative approaches to satisfying applicable environmental standards, and describes selected strategies for acquiring permits and other approvals needed for WFD to proceed. Appendices at the end of this plan provide preliminary cost and schedule estimates for implementing the selected strategies. The rest of this section summarizes the scope of WFD activities, including important TWRS operating information, and describes in more detail the objectives, structure, and content of this plan.

  6. HYPERSONIC BUCKSHOT: ASTROPHYSICAL JETS AS HETEROGENEOUS COLLIMATED PLASMOIDS

    SciTech Connect (OSTI)

    Yirak, Kristopher; Frank, Adam; Cunningham, Andrew J.; Mitran, Sorin

    2009-04-20

    Herbig-Haro jets are commonly thought of as homogeneous beams of plasma traveling at hypersonic velocities. Structure within jet beams is often attributed to periodic or 'pulsed' variations of conditions at the jet source. Simulations based on this scenario result in knots extending across the jet diameter. Observations and recent high energy density laboratory experiments shed new light on structures below this scale and indicate they may be important for understanding the fundamentals of jet dynamics. In this paper, we offer an alternative to 'pulsed' models of protostellar jets. Using direct numerical simulations we explore the possibility that jets are chains of subradial clumps propagating through a moving interclump medium. Our models explore an idealization of this scenario by injecting small (r < r {sub jet}), dense ({rho}>{rho}{sub jet}) spheres embedded in an otherwise smooth interclump jet flow. The spheres are initialized with velocities differing from the jet velocity by {approx}15%. We find that the consequences of shifting from homogeneous to heterogeneous flows are significant as clumps interact with each other and with the interclump medium in a variety of ways. Structures which mimic what is expected from pulsed-jet models can form, as can be previously unseen, 'subradial' behaviors including backward facing bow shocks and off-axis working surfaces. While these small-scale structures have not been seen before in simulation studies, they are found in high-resolution jet observations. We discuss implications of our simulations for the interpretation of protostellar jets with regard to characterization of knots by a 'lifetime' or 'velocity history' approach as well as linking observed structures with central engines which produce the jets.

  7. Complexity analysis of pipeline mapping problems in distributed heterogeneous networks

    SciTech Connect (OSTI)

    Lin, Ying; Wu, Qishi; Zhu, Mengxia; Rao, Nageswara S

    2009-04-01

    Largescale scientific applications require using various system resources to execute complex computing pipelines in distributed networks to support collaborative research. System resources are typically shared in the Internet or over dedicated connections based on their location, availability, capability, and capacity. Optimizing the network performance of computing pipelines in such distributed environments is critical to the success of these applications. We consider two types of largescale distributed applications: (1) interactive applications where a single dataset is sequentially processed along a pipeline; and (2) streaming applications where a series of datasets continuously flow through a pipeline. The computing pipelines of these applications consist of a number of modules executed in a linear order in network environments with heterogeneous resources under different constraints. Our goal is to find an efficient mapping scheme that allocates the modules of a pipeline to network nodes for minimum endtoend delay or maximum frame rate. We formulate the pipeline mappings in distributed environments as optimization problems and categorize them into six classes with different optimization goals and mapping constraints: (1) Minimum Endtoend Delay with No Node Reuse (MEDNNR), (2) Minimum Endtoend Delay with Contiguous Node Reuse (MEDCNR), (3) Minimum Endtoend Delay with Arbitrary Node Reuse (MEDANR), (4) Maximum Frame Rate with No Node Reuse or Share (MFRNNRS), (5) Maximum Frame Rate with Contiguous Node Reuse and Share (MFRCNRS), and (6) Maximum Frame Rate with Arbitrary Node Reuse and Share (MFRANRS). Here, 'contiguous node reuse' means that multiple contiguous modules along the pipeline may run on the same node and 'arbitrary node reuse' imposes no restriction on node reuse. Note that in interactive applications, a node can be reused but its resource is not shared. We prove that MEDANR is polynomially solvable and the rest are NP-complete. MEDANR, where either contiguous or noncontiguous modules in the pipeline can be mapped onto the same node, is essentially the Maximum n-hop Shortest Path problem, and can be solved using a dynamic programming method. In MEDNNR and MFRNNRS, any network node can be used only once, which requires selecting the same number of nodes for onetoone onto mapping. We show its NP-completeness by reducing from the Hamiltonian Path problem. Node reuse is allowed in MEDCNR, MFRCNRS and MFRANRS, which are similar to the Maximum n-hop Shortest Path problem that considers resource sharing. We prove their NP-completeness by reducing from the Disjoint-Connecting-Path Problem and Widest path with the Linear Capacity Constraints problem, respectively.

  8. Preliminary low-level waste feed definition guidance - LLW pretreatment interface

    SciTech Connect (OSTI)

    Shade, J.W.; Connor, J.M.; Hendrickson, D.W.; Powell, W.J.; Watrous, R.A.

    1995-02-01

    The document describes limits for key constituents in the LLW feed, and the bases for these limits. The potential variability in the stream is then estimated and compared to the limits. Approaches for accomodating uncertainty in feed inventory, processing strategies, and process design (melter and disposal system) are discussed. Finally, regulatory constraints are briefly addressed.

  9. Influence of heterogeneity on second-kind self-similar solutions...

    Office of Scientific and Technical Information (OSTI)

    a heterogeneous porous medium whose permeability and porosity have power-law variations. ... that propagate away from the origin (a point of zero permeability); (b) a second-kind ...

  10. Surfkin: A program to solve transient and steady state heterogeneous reaction kinetics

    SciTech Connect (OSTI)

    COLTRIN,MICHAEL E.; WIXOM,RYAN R.; DANDY,DAVID S.

    2000-05-01

    Heterogeneous chemical reactions occurring at a gas/surface interface are fundamental in a variety of important applications, such as combustion, catalysis, chemical vapor deposition and plasma processing. Detailed simulation of these processes may involve complex, coupled fluid flow, heat transfer, gas-phase chemistry, in addition to heterogeneous reaction chemistry. This report documents the Surfkin program, which simulates the kinetics of heterogeneous chemical reactions. The program is designed for use with the Chemkin and Surface Chemkin (heterogeneous chemistry) programs. It calculates time-dependent or steady state surface site fractions and bulk-species production/destruction rates. The surface temperature may be specified as a function of time to simulate a temperature-programmed desorption experiment, for example. This report serves as a user's manual for the program, explaining the required input and format of the output. Two detailed example problems are included to further illustrate the use of this program.

  11. Resolving Cancer Heterogeneity by Single Cell Sequencing (7th Annual SFAF Meeting, 2012)

    ScienceCinema (OSTI)

    Xu, Xun [BGI

    2013-02-11

    Xun Xu on "Resolving Cancer Heterogeneity by Single Cell Sequencing" at the 2012 Sequencing, Finishing, Analysis in the Future Meeting held June 5-7, 2012 in Santa Fe, New Mexico.

  12. New Helical Foldamers: Heterogeneous Backbones with 1:2 and 2...

    Office of Scientific and Technical Information (OSTI)

    New Helical Foldamers: Heterogeneous Backbones with 1:2 and 2:1 alpha:superscript beta-Amino Acid Residue Patterns Citation Details In-Document Search Title: New Helical ...

  13. X-ray micro-diffraction studies of heterogeneous interfaces between

    Office of Scientific and Technical Information (OSTI)

    cementitious materials and geological formations (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: X-ray micro-diffraction studies of heterogeneous interfaces between cementitious materials and geological formations Citation Details In-Document Search Title: X-ray micro-diffraction studies of heterogeneous interfaces between cementitious materials and geological formations Authors: Dähn, R. ; Popov, D. ; Schaub, Ph. ; Pattison, P. ; Grolimund, D. ; Mäder,

  14. EFFECTS OF PORE STRUCTURE CHANGE AND MULTI-SCALE HETEROGENEITY ON

    Office of Scientific and Technical Information (OSTI)

    CONTAMINANT TRANSPORT AND REACTION RATE UPSCALING (Technical Report) | SciTech Connect Technical Report: EFFECTS OF PORE STRUCTURE CHANGE AND MULTI-SCALE HETEROGENEITY ON CONTAMINANT TRANSPORT AND REACTION RATE UPSCALING Citation Details In-Document Search Title: EFFECTS OF PORE STRUCTURE CHANGE AND MULTI-SCALE HETEROGENEITY ON CONTAMINANT TRANSPORT AND REACTION RATE UPSCALING This project addressed the scaling of geochemical reactions to core and field scales, and the interrelationship

  15. The scale dependence of dispersivity in multi-faces heterogeneous sediments

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect The scale dependence of dispersivity in multi-faces heterogeneous sediments Citation Details In-Document Search Title: The scale dependence of dispersivity in multi-faces heterogeneous sediments Early work on stochastic modeling of the transport of inert solutes in porous media assumed that log conductivity could be characterized by a single, finite integral scale representing the spatial correlation of log conductivity. In this study, we focused on

  16. Molten metal feed system controlled with a traveling magnetic field

    DOE Patents [OSTI]

    Praeg, Walter F.

    1991-01-01

    A continuous metal casting system in which the feed of molten metal is controlled by means of a linear induction motor capable of producing a magnetic traveling wave in a duct that connects a reservoir of molten metal to a caster. The linear induction motor produces a traveling magnetic wave in the duct in opposition to the pressure exerted by the head of molten metal in the reservoir so that p.sub.c =p.sub.g -p.sub.m where p.sub.c is the desired pressure in the caster, p.sub.g is the gravitational pressure in the duct exerted by the force of the head of molten metal in the reservoir, and p.sub.m is the electromagnetic pressure exerted by the force of the magnetic field traveling wave produced by the linear induction motor. The invention also includes feedback loops to the linear induction motor to control the casting pressure in response to measured characteristics of the metal being cast.

  17. Policymaker's Guide to Feed-in Tariff Policy Design

    SciTech Connect (OSTI)

    Couture, T. D.; Cory, K.; Kreycik, C.; Williams, E.

    2010-07-01

    Feed-in tariffs (FITs) are the most widely used renewable energy policy in the world for driving accelerating renewable energy (RE) deployment, accounting for a greater share of RE development than either tax incentives or renewable portfolio standard (RPS) policies. FITs have generated significant RE deployment, helping bring the countries that have implemented them successfully to the forefront of the global RE industry. In the European Union (EU), FIT policies have led to the deployment of more than 15,000 MW of solar photovoltaic (PV) power and more than 55,000 MW of wind power between 2000 and the end of 2009. In total, FITs are responsible for approximately 75% of global PV and 45% of global wind deployment. Countries such as Germany, in particular, have demonstrated that FITs can be used as a powerful policy tool to drive RE deployment and help meet combined energy security and emissions reductions objectives. This policymaker's guide provides a detailed analysis of FIT policy design and implementation and identifies a set of best practices that have been effective at quickly stimulating the deployment of large amounts of RE generation. Although the discussion is aimed primarily at decision makers who have decided that a FIT policy best suits their needs, exploration of FIT policies can also help inform a choice among alternative renewable energy policies.

  18. A Policymaker's Guide to Feed-in Tariff Policy Design

    SciTech Connect (OSTI)

    Couture, Toby D.; Cory, Karlynn; Kreycik, Claire; Williams, Emily

    2010-07-01

    Feed-in tariffs (FITs) are the most widely used renewable energy policy in the world for driving accelerating renewable energy (RE) deployment, accounting for a greater share of RE development than either tax incentives or renewable portfolio standard (RPS) policies. FITs have generated significant RE deployment, helping bring the countries that have implemented them successfully to the forefront of the global RE industry. In the European Union (EU), FIT policies have led to the deployment of more than 15,000 MW of solar photovoltaic (PV) power and more than 55,000 MW of wind power between 2000 and the end of 2009. In total, FITs are responsible for approximately 75% of global PV and 45% of global wind deployment. Countries such as Germany, in particular, have demonstrated that FITs can be used as a powerful policy tool to drive RE deployment and help meet combined energy security and emissions reductions objectives. This policymaker’s guide provides a detailed analysis of FIT policy design and implementation and identifies a set of best practices that have been effective at quickly stimulating the deployment of large amounts of RE generation.

  19. Innovative Feed-In Tariff Designs that Limit Policy Costs

    SciTech Connect (OSTI)

    Kreycik, C.; Couture, T. D.; Cory, K. S.

    2011-06-01

    Feed-in tariffs (FITs) are the most prevalent renewable energy policy used globally to date, and there are many benefits to the certainty offered in the marketplace to reduce development risks and associated financing costs and to grow the renewable energy industry. However, concerns over escalating costs in jurisdictions with FIT policies have led to increased attention on cost control in renewable energy policy design. In recent years, policy mechanisms for containing FIT costs have become more refined, allowing policymakers to exert greater control on policy outcomes and on the resulting costs to ratepayers. As policymakers and regulators in the United States begin to explore the use of FITs, careful consideration must be given to the ways in which policy design can be used to balance the policies' advantages while bounding its costs. This report explores mechanisms that policymakers have implemented to limit FIT policy costs. If designed clearly and transparently, such mechanisms can align policymaker and market expectations for project deployment. Three different policy tools are evaluated: (1) caps, (2) payment level adjustment mechanisms, and (3) auction-based designs. The report employs case studies to explore the strengths and weaknesses of these three cost containment tools. These tools are then evaluated with a set of criteria including predictability for policymakers and the marketplace and the potential for unintended consequences.

  20. Vertical feed stick wood fuel burning furnace system

    DOE Patents [OSTI]

    Hill, Richard C.

    1982-01-01

    A stove or furnace for efficient combustion of wood fuel includes a vertical feed combustion chamber (15) for receiving and supporting wood fuel in a vertical attitude or stack. A major upper portion of the combustion chamber column comprises a water jacket (14) for coupling to a source of water or heat transfer fluid for convection circulation of the fluid. The locus (31) of wood fuel combustion is thereby confined to the refractory base of the combustion chamber. A flue gas propagation delay channel (34) extending laterally from the base of the chamber affords delayed travel time in a high temperature refractory environment sufficient to assure substantially complete combustion of the gaseous products of wood burning with forced air prior to extraction of heat in heat exchanger (16). Induced draft draws the fuel gas and air mixture laterally through the combustion chamber and refractory high temperature zone to the heat exchanger and flue. Also included are active sources of forced air and induced draft, multiple circuit couplings for the recovered heat, and construction features in the refractory material substructure and metal component superstructure.

  1. Environmental Survey preliminary report, Feed Materials Production Center, Fernald, Ohio

    SciTech Connect (OSTI)

    Not Available

    1987-03-01

    This report presents the preliminary findings from the first phase of the environmental survey of the United States Department of Energy (DOE) Feed Materials Production Center (FMPC), conducted June 16 through 27, 1986. The survey is being conducted by an interdisciplinary team of environmental specialists, led and managed by the Office of Environment, Safety and Health's Office of Environmental Audit. Individual team components are being supplied by a private contractor. The objective of the survey is to identify environmental problems and areas of environmental risk associated with the FMPC. The survey covers all environmental media and all areas of environmental regulation. It is being performed in accordance with the DOE Environmental Survey Manual. This phase of the survey involves the review of existing site environmental data, observations of the operations carried on at FMPC, and interviews with site personnel. The survey team developed a Sampling and Analysis Plan to assist in further assessing certain of the environmental problems identified during its onsite activities. The Sampling and Analysis Plan will be executed by a DOE national laboratory or a support contractor. When completed, the results will be incorporated into the FMPC Environmental Survey Interim Report. The Interim Report will reflect the final determinations of the FMPC survey. 41 refs., 20 figs., 25 tabs.

  2. Feed Materials Production Center annual environmental report for calendar 1989

    SciTech Connect (OSTI)

    Dugan, T.A.; Gels, G.L.; Oberjohn, J.S.; Rogers, L.K.

    1990-10-01

    The mission of the Department of Energy's (DOE) Feed Materials Production Center (FMPC) has been to process uranium for United States' defense programs. On July 10, 1989, the FMPC suspended production operations, but remains on standby for certain segments of production. The FMPC also manages the storage of some radioactive and hazardous materials. As part of its operations, the FMPC continuously monitors the environment to determine that it is operating within federal and state standards and guidelines regarding emission of radioactive and nonradioactive materials. Data collected from the FMPC monitoring program are used to calculate estimates of radiation dose for residents due to FMPC operations. For 1989, the estimate of dose through the air pathway, excluding radon, indicated that people in the area were exposed to less than 6% of the DOE guideline established to protect the public from radiation exposure. When radon emissions are included, the dose from FMPC operations during 1989 was less than 22% of the annual background radiation dose in the Greater Cincinnati area. This report is a summary of FMPC's environmental activities and monitoring program for 1989. An Environmental Compliance Self-Assessment presents the FMPC's efforts to comply with environmental regulations through June 1990. 44 refs., 48 figs.

  3. IMPROVING CO2 EFFICIENCY FOR RECOVERING OIL IN HETEROGENEOUS RESERVOIRS

    SciTech Connect (OSTI)

    Reid B. Grigg; Robert K. Svec

    2002-12-20

    This document is the First Annual Report for the U.S. Department of Energy under contract No., a three-year contract entitled: ''Improving CO{sub 2} Efficiency for Recovering Oil in Heterogeneous Reservoirs.'' The research improved our knowledge and understanding of CO{sub 2} flooding and includes work in the areas of injectivity and mobility control. The bulk of this work has been performed by the New Mexico Petroleum Recovery Research Center, a research division of New Mexico Institute of Mining and Technology. This report covers the reporting period of September 28, 2001 and September 27, 2002. Injectivity continues to be a concern to the industry. During this period we have contacted most of the CO{sub 2} operators in the Permian Basin and talked again about their problems in this area. This report has a summary of what we found. It is a given that carbonate mineral dissolution and deposition occur in a formation in geologic time and are expected to some degree in carbon dioxide (CO{sub 2}) floods. Water-alternating-gas (WAG) core flood experiments conducted on limestone and dolomite core plugs confirm that these processes can occur over relatively short time periods (hours to days) and in close proximity to each other. Results from laboratory CO{sub 2}-brine flow experiments performed in rock core were used to calibrate a reactive transport simulator. The calibrated model is being used to estimate in situ effects of a range of possible sequestration options in depleted oil/gas reservoirs. The code applied in this study is a combination of the well known TOUGH2 simulator, for coupled groundwater/brine and heat flow, with the chemistry code TRANS for chemically reactive transport. Variability in response among rock types suggests that CO{sub 2} injection will induce ranges of transient and spatially dependent changes in intrinsic rock permeability and porosity. Determining the effect of matrix changes on CO{sub 2} mobility is crucial in evaluating the efficacy and potential environmental implications of storing CO{sub 2} in the subsurface. Chemical cost reductions are identified that are derived from the synergistic effects of cosurfactant systems using a good foaming agent and a less expensive poor foaming agent. The required good foaming agent is reduced by at least 75%. Also the effect on injectivity is reduced by as much as 50% using the cosurfactant system, compared to a previously used surfactant system. Mobility control of injected CO{sub 2} for improved oil recovery can be achieved with significant reduction in the chemical cost of SAG, improved injectivity of SAG, and improved economics of CO{sub 2} injection project when compared to reported systems. Our past work has identified a number of mobility control agents to use for CO{sub 2}-foam flooding. In particular the combination of the good foaming agent CD 1045 and a sacrificial agent and cosurfactant lignosulfonate. This work scrutinizes the methods that we are using to determine the efficiency of the sacrificial agents and cosurfactant systems. These have required concentration determinations and reusing core samples. Here, we report some of the problems that have been found and some interesting effects that must be considered.

  4. Effect of Feeding Rate on the Cold Cap Configuration in a Laboratory-Scale Melter - 13362

    SciTech Connect (OSTI)

    Dixon, Derek R.; Schweiger, Michael J.; Hrma, Pavel; Division of Advanced Nuclear Engineering, Pohang University of Science and Technology, Pohang

    2013-07-01

    High-level-waste melter feed is converted into glass in a joule-heated melter, where it forms a floating layer of reacting feed, called the cold cap. After the glass-forming phase becomes connected, evolving gases produce bubbles that form a foam layer under the feed. The bubbles coalesce into cavities, from which most of the gases are released around the edges of the cold cap while gases also escape through small shafts in the reacting feed. The foam layer insulates the cold cap from the heat transferred from the molten glass below. The cold cap behavior was investigated in a laboratory-scale assembly with a fused silica crucible. A high-alumina waste simulant was fed into the crucible and the feed charging rate was varied from 3 to 7 mL min{sup -1}. After a fixed amount of time (35 min), feed charging was stopped and the crucible was removed from the furnace and quenched on a copper block to preserve the structure of the cold cap during cooling. During the rapid quenching, thermal cracking of the glass and cold cap allowed it to be broken up into sections for analysis. The effect of the charging rate on the height, area and volume of the cold cap was determined. The size of the bubbles collected in the foam layer under the feed increased as the cold cap expanded and the relationship between these bubbles and temperature will be determined for input into a mathematical model. (authors)

  5. Hanford Tank Waste Treatment and Immobilization Plant (WTP) Waste Feed Qualification Program Development Approach - 13114

    SciTech Connect (OSTI)

    Markillie, Jeffrey R.; Arakali, Aruna V.; Benson, Peter A.; Halverson, Thomas G.; Adamson, Duane J.; Herman, Connie C.; Peeler, David K.

    2013-07-01

    The Hanford Tank Waste Treatment and Immobilization Plant (WTP) is a nuclear waste treatment facility being designed and constructed for the U.S. Department of Energy by Bechtel National, Inc. and subcontractor URS Corporation (under contract DE-AC27-01RV14136 [1]) to process and vitrify radioactive waste that is currently stored in underground tanks at the Hanford Site. A wide range of planning is in progress to prepare for safe start-up, commissioning, and operation. The waste feed qualification program is being developed to protect the WTP design, safety basis, and technical basis by assuring acceptance requirements can be met before the transfer of waste. The WTP Project has partnered with Savannah River National Laboratory to develop the waste feed qualification program. The results of waste feed qualification activities will be implemented using a batch processing methodology, and will establish an acceptable range of operator controllable parameters needed to treat the staged waste. Waste feed qualification program development is being implemented in three separate phases. Phase 1 required identification of analytical methods and gaps. This activity has been completed, and provides the foundation for a technically defensible approach for waste feed qualification. Phase 2 of the program development is in progress. The activities in this phase include the closure of analytical methodology gaps identified during Phase 1, design and fabrication of laboratory-scale test apparatus, and determination of the waste feed qualification sample volume. Phase 3 will demonstrate waste feed qualification testing in support of Cold Commissioning. (authors)

  6. Algae culture for cattle feed and water purification. Final report

    SciTech Connect (OSTI)

    Varani, F.T.; Schellenbach, S.; Veatch, M.; Grover, P.; Benemann, J.

    1980-05-16

    The feasibility of algae growth on centrate from anaerobic digester effluent and the refeed of both effluent solids and the algae to feedlot cattle were investigated. The digester was operated with dirt feedlot manure. The study serves as a supplement for the work to design a utility sized digester for the City of Lamar to convert local feedlot manure into a fuel gas. The biogas produced would power the electrical generation plant already in service. Previous studies have established techniques of digester operation and the nutritional value for effluent solids as fed to cattle. The inclusion of a single-strain of algae, Chlorella pyrenidosa in the process was evaluated here for its capability (1) to be grown in both open and closed ponds of the discharge water from the solids separation part of the process, (2) to purify the discharge water, and (3) to act as a growth stimulant for cattle feed consumption and conversion when fed at a rate of 6 grams per head per day. Although it was found that the algae could be cultured and grown on the discharge water in the laboratory, the study was unable to show that algae could accomplish the other objectives successfully. However, the study yielded supplementary information useful to the overall process design of the utility plant. This was (1) measurement of undried digester solids fed to cattle in a silage finishing ration (without algae) at an economic value of $74.99 per dry ton based on nutritional qualities, (2) development of a centrate treatment system to decolorize and disinfect centrate to allow optimum algae growth, and (3) information on ionic and mass balances for the digestion system. It is the recommendation of this study that algae not be used in the process in the Lamar bioconversion plant.

  7. Scaling Effects of Cr(VI) Reduction Kinetics. The Role of Geochemical Heterogeneity

    SciTech Connect (OSTI)

    Wang, Li; Li, Li

    2015-10-22

    The natural subsurface is highly heterogeneous with minerals distributed in different spatial patterns. Fundamental understanding of how mineral spatial distribution patterns regulate sorption process is important for predicting the transport and fate of chemicals. Existing studies about the sorption was carried out in well-mixed batch reactors or uniformly packed columns, with few data available on the effects of spatial heterogeneities. As a result, there is a lack of data and understanding on how spatial heterogeneities control sorption processes. In this project, we aim to understand and develop modeling capabilities to predict the sorption of Cr(VI), an omnipresent contaminant in natural systems due to its natural occurrence and industrial utilization. We systematically examine the role of spatial patterns of illite, a common clay, in determining the extent of transport limitation and scaling effects associated with Cr(VI) sorption capacity and kinetics using column experiments and reactive transport modeling. Our results showed that the sorbed mass and rates can differ by an order of magnitude due to of the illite spatial heterogeneities and transport limitation. With constraints from data, we also developed the capabilities of modeling Cr(VI) in heterogeneous media. The developed model is then utilized to understand the general principles that govern the relationship between sorption and connectivity, a key measure of the spatial pattern characteristics. This correlation can be used to estimate Cr(VI) sorption characteristics in heterogeneous porous media. Insights gained here bridge gaps between laboratory and field application in hydrogeology and geochemical field, and advance predictive understanding of reactive transport processes in the natural heterogeneous subsurface. We believe that these findings will be of interest to a large number of environmental geochemists and engineers, hydrogeologists, and those interested in contaminant fate and transport, water quality and water composition, and natural attenuation processes in natural systems.

  8. The effect of reservoir heterogeneity on gas production from hydrate accumulations in the permafrost

    SciTech Connect (OSTI)

    Reagan, M. T.; Kowalsky, M B.; Moridis, G. J.; Silpngarmlert, S.

    2010-05-01

    The quantity of hydrocarbon gases trapped in natural hydrate accumulations is enormous, leading to significant interest in the evaluation of their potential as an energy source. Large volumes of gas can be readily produced at high rates for long times from methane hydrate accumulations in the permafrost by means of depressurization-induced dissociation combined with conventional technologies and horizontal or vertical well configurations. Initial studies on the possibility of natural gas production from permafrost hydrates assumed homogeneity in intrinsic reservoir properties and in the initial condition of the hydrate-bearing layers (either due to the coarseness of the model or due to simplifications in the definition of the system). These results showed great promise for gas recovery from Class 1, 2, and 3 systems in the permafrost. This work examines the consequences of inevitable heterogeneity in intrinsic properties, such as in the porosity of the hydrate-bearing formation, or heterogeneity in the initial state of hydrate saturation. Heterogeneous configurations are generated through multiple methods: (1) through defining heterogeneous layers via existing well-log data, (2) through randomized initialization of reservoir properties and initial conditions, and (3) through the use of geostatistical methods to create heterogeneous fields that extrapolate from the limited data available from cores and well-log data. These extrapolations use available information and established geophysical methods to capture a range of deposit properties and hydrate configurations. The results show that some forms of heterogeneity, such as horizontal stratification, can assist in production of hydrate-derived gas. However, more heterogeneous structures can lead to complex physical behavior within the deposit and near the wellbore that may obstruct the flow of fluids to the well, necessitating revised production strategies. The need for fine discretization is crucial in all cases to capture dynamic behavior during production.

  9. The Effects of Ethanol on Texas Food and Feed | Department of Energy

    Energy Savers [EERE]

    The Effects of Ethanol on Texas Food and Feed The Effects of Ethanol on Texas Food and Feed There are many related and difficult questions raised by the fuel vs. food vs. feed debate. Some of those questions may be irrelevant or of less importance when compared to the real issues to be addressed. Clearly, there are winners and losers in Texas and U.S. agriculture. This report addresses a series of the common questions raised in the debate. PDF icon RR-08-01.pdf More Documents & Publications

  10. A numerical homogenization method for heterogeneous, anisotropic elastic media based on multiscale theory

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gao, Kai; Chung, Eric T.; Gibson, Richard L.; Fu, Shubin; Efendiev, Yalchin

    2015-06-05

    The development of reliable methods for upscaling fine scale models of elastic media has long been an important topic for rock physics and applied seismology. Several effective medium theories have been developed to provide elastic parameters for materials such as finely layered media or randomly oriented or aligned fractures. In such cases, the analytic solutions for upscaled properties can be used for accurate prediction of wave propagation. However, such theories cannot be applied directly to homogenize elastic media with more complex, arbitrary spatial heterogeneity. We therefore propose a numerical homogenization algorithm based on multiscale finite element methods for simulating elasticmore » wave propagation in heterogeneous, anisotropic elastic media. Specifically, our method used multiscale basis functions obtained from a local linear elasticity problem with appropriately defined boundary conditions. Homogenized, effective medium parameters were then computed using these basis functions, and the approach applied a numerical discretization that is similar to the rotated staggered-grid finite difference scheme. Comparisons of the results from our method and from conventional, analytical approaches for finely layered media showed that the homogenization reliably estimated elastic parameters for this simple geometry. Additional tests examined anisotropic models with arbitrary spatial heterogeneity where the average size of the heterogeneities ranged from several centimeters to several meters, and the ratio between the dominant wavelength and the average size of the arbitrary heterogeneities ranged from 10 to 100. Comparisons to finite-difference simulations proved that the numerical homogenization was equally accurate for these complex cases.« less

  11. A New Equivalence Theory Method for Treating Doubly Heterogeneous Fuel - I. Theory

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Williams, Mark L.; Lee, Deokjung; Choi, Sooyoung

    2015-03-04

    A new methodology has been developed to treat resonance self-shielding in doubly heterogeneous very high temperature gas-cooled reactor systems in which the fuel compact region of a reactor lattice consists of small fuel grains dispersed in a graphite matrix. This new method first homogenizes the fuel grain and matrix materials using an analytically derived disadvantage factor from a two-region problem with equivalence theory and intermediate resonance method. This disadvantage factor accounts for spatial self-shielding effects inside each grain within the framework of an infinite array of grains. Then the homogenized fuel compact is self-shielded using a Bondarenko method to accountmore » for interactions between the fuel compact regions in the fuel lattice. In the final form of the equations for actual implementations, the double-heterogeneity effects are accounted for by simply using a modified definition of a background cross section, which includes geometry parameters and cross sections for both the grain and fuel compact regions. With the new method, the doubly heterogeneous resonance self-shielding effect can be treated easily even with legacy codes programmed only for a singly heterogeneous system by simple modifications in the background cross section for resonance integral interpolations. This paper presents a detailed derivation of the new method and a sensitivity study of double-heterogeneity parameters introduced during the derivation. The implementation of the method and verification results for various test cases are presented in the companion paper.« less

  12. A numerical homogenization method for heterogeneous, anisotropic elastic media based on multiscale theory

    SciTech Connect (OSTI)

    Gao, Kai; Chung, Eric T.; Gibson, Richard L.; Fu, Shubin; Efendiev, Yalchin

    2015-06-05

    The development of reliable methods for upscaling fine scale models of elastic media has long been an important topic for rock physics and applied seismology. Several effective medium theories have been developed to provide elastic parameters for materials such as finely layered media or randomly oriented or aligned fractures. In such cases, the analytic solutions for upscaled properties can be used for accurate prediction of wave propagation. However, such theories cannot be applied directly to homogenize elastic media with more complex, arbitrary spatial heterogeneity. We therefore propose a numerical homogenization algorithm based on multiscale finite element methods for simulating elastic wave propagation in heterogeneous, anisotropic elastic media. Specifically, our method used multiscale basis functions obtained from a local linear elasticity problem with appropriately defined boundary conditions. Homogenized, effective medium parameters were then computed using these basis functions, and the approach applied a numerical discretization that is similar to the rotated staggered-grid finite difference scheme. Comparisons of the results from our method and from conventional, analytical approaches for finely layered media showed that the homogenization reliably estimated elastic parameters for this simple geometry. Additional tests examined anisotropic models with arbitrary spatial heterogeneity where the average size of the heterogeneities ranged from several centimeters to several meters, and the ratio between the dominant wavelength and the average size of the arbitrary heterogeneities ranged from 10 to 100. Comparisons to finite-difference simulations proved that the numerical homogenization was equally accurate for these complex cases.

  13. In situ measurements of heterogeneous reactions on ambient aerosol particles: Impacts on atmospheric chemistry and climate

    SciTech Connect (OSTI)

    Bertram, Timothy

    2015-02-11

    Aerosol particles play a critical role in the Earth’s energy budget through the absorption and scattering of radiation, and/or through their ability to form clouds and alter cloud lifetime. Heterogeneous and multi-phase reactions alter the climate-relevant properties of aerosol particles and catalyze reaction pathways that are energetically unfavorable in the gas phase. The chemical composition of aerosol particles dictates the kinetics of heterogeneous and multi-phase reactions. At present, the vast majority of the molecular level information on these processes has been determined in laboratory investigations on model aerosol systems. The work described here provides a comprehensive investigation into the reactivity of complex, ambient aerosol particles is proposed to determine: 1) how representative laboratory investigations of heterogeneous and multi-phase processes conducted on model, simple systems are of the real atmosphere, and 2) the impact of heterogeneous and multi-phase processes on ambient particle optical properties and their ability to nucleate clouds. This work has focused on the uptake kinetics for ammonia (NH3) and dinitrogen pentoxide (N2O5). The results of these investigations will be used to directly improve the representation of heterogeneous and multi-phase processes in global climate models, by identifying the key mechanistic drivers that control the variability in the observed kinetics.

  14. A New Equivalence Theory Method for Treating Doubly Heterogeneous Fuel - I. Theory

    SciTech Connect (OSTI)

    Williams, Mark L.; Lee, Deokjung; Choi, Sooyoung

    2015-03-04

    A new methodology has been developed to treat resonance self-shielding in doubly heterogeneous very high temperature gas-cooled reactor systems in which the fuel compact region of a reactor lattice consists of small fuel grains dispersed in a graphite matrix. This new method first homogenizes the fuel grain and matrix materials using an analytically derived disadvantage factor from a two-region problem with equivalence theory and intermediate resonance method. This disadvantage factor accounts for spatial self-shielding effects inside each grain within the framework of an infinite array of grains. Then the homogenized fuel compact is self-shielded using a Bondarenko method to account for interactions between the fuel compact regions in the fuel lattice. In the final form of the equations for actual implementations, the double-heterogeneity effects are accounted for by simply using a modified definition of a background cross section, which includes geometry parameters and cross sections for both the grain and fuel compact regions. With the new method, the doubly heterogeneous resonance self-shielding effect can be treated easily even with legacy codes programmed only for a singly heterogeneous system by simple modifications in the background cross section for resonance integral interpolations. This paper presents a detailed derivation of the new method and a sensitivity study of double-heterogeneity parameters introduced during the derivation. The implementation of the method and verification results for various test cases are presented in the companion paper.

  15. Heterogeneity-corrected vs -uncorrected critical structure maximum point doses in breast balloon brachytherapy

    SciTech Connect (OSTI)

    Kim, Leonard; Narra, Venkat; Yue, Ning

    2013-07-01

    Recent studies have reported potentially clinically meaningful dose differences when heterogeneity correction is used in breast balloon brachytherapy. In this study, we report on the relationship between heterogeneity-corrected and -uncorrected doses for 2 commonly used plan evaluation metrics: maximum point dose to skin surface and maximum point dose to ribs. Maximum point doses to skin surface and ribs were calculated using TG-43 and Varian Acuros for 20 patients treated with breast balloon brachytherapy. The results were plotted against each other and fit with a zero-intercept line. Max skin dose (Acuros) = max skin dose (TG-43) ? 0.930 (R{sup 2} = 0.995). The average magnitude of difference from this relationship was 1.1% (max 2.8%). Max rib dose (Acuros) = max rib dose (TG-43) ? 0.955 (R{sup 2} = 0.9995). The average magnitude of difference from this relationship was 0.7% (max 1.6%). Heterogeneity-corrected maximum point doses to the skin surface and ribs were proportional to TG-43-calculated doses. The average deviation from proportionality was 1%. The proportional relationship suggests that a different metric other than maximum point dose may be needed to obtain a clinical advantage from heterogeneity correction. Alternatively, if maximum point dose continues to be used in recommended limits while incorporating heterogeneity correction, institutions without this capability may be able to accurately estimate these doses by use of a scaling factor.

  16. Tank waste remediation system retrieval and disposal mission waste feed delivery plan

    SciTech Connect (OSTI)

    Potter, R.D.

    1998-01-08

    This document is a plan presenting the objectives, organization, and management and technical approaches for the Waste Feed Delivery (WFD) Program. This WFD Plan focuses on the Tank Waste Remediation System (TWRS) Project`s Waste Retrieval and Disposal Mission.

  17. Feds Feed Families Wraps Up Successful Campaign to Stock Area Food Banks

    Broader source: Energy.gov [DOE]

    WASHINGTON, D.C. – The fourth annual Feds Feed Families, an effort by DOE and other federal agencies to stock area food banks, has entered the homestretch of its campaign that ends this month.

  18. A Catalyst Wire-feed Arc Discharge for Synthesis of Carbon Nanotubes...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A Catalyst Wire-feed Arc Discharge for Synthesis of Carbon Nanotubes and Graphene Particles This invention pertains to a highly effective arc-based synthesis of single wall carbon...

  19. U.S. Virgin Islands- Renewable Energy Feed-in-Tariff

    Broader source: Energy.gov [DOE]

    There is a 10 MW limit for aggregate production via feed-in-tariff contracts on the islands of St. Thomas, St. John, Water Island, and other offshore keys and islands and a similar 5 MW limit for...

  20. Feed-in Tariff Policy: Design, Implementation, and RPS Policy Interactions

    Broader source: Energy.gov [DOE]

    This report explores the design and implementation of feed-in tariff policies, including a policy definition, various payment structures, and payment differentiation options. The report also discusses the interaction between FIT and RPS policies.

  1. Renewable Energy Prices in State-Level Feed-in Tariffs. Federal...

    Office of Scientific and Technical Information (OSTI)

    Citation Details In-Document Search Title: Renewable Energy Prices in State-Level Feed-in ... DC (United States) National Renewable Energy Lab. (NREL), Golden, CO (United States) ...

  2. Feed-in Tariffs: Best Practices and Application in the U.S.

    Broader source: Energy.gov [DOE]

    This presentation, presented on Oct. 28, 2009, covered renewable energy feed-in tariffs and the lessons learned from the U.S. Presenter was Karlynn Cory of the National Renewable Energy Laboratory.

  3. Renewable Energy Feed-in Tariffs: Lessons Learned from the U...

    Open Energy Info (EERE)

    from the U.S. and Abroad Presentation Jump to: navigation, search Tool Summary Name: Renewable Energy Feed-in Tariffs: Lessons Learned from the U.S. and Abroad Presentation...

  4. ANALYSIS OF THE SALT FEED TANK CORE SAMPLE

    SciTech Connect (OSTI)

    Reigel, M.; Cheng, W.

    2012-01-26

    The Saltstone Production Facility (SPF) immobilizes and disposes of low-level radioactive and hazardous liquid waste (salt solution) remaining from the processing of radioactive material at the Savannah River Site (SRS). Low-level waste (LLW) streams from processes at SRS are stored in Tank 50 until the LLW can be transferred to the SPF for treatment and disposal. The Salt Feed Tank (SFT) at the Saltstone Production Facility (SPF) holds approximately 6500 gallons of low level waste from Tank 50 as well as drain water returned from the Saltstone Disposal Facility (SDF) vaults. Over the past several years, Saltstone Engineering has noted the accumulation of solids in the SFT. The solids are causing issues with pump performance, agitator performance, density/level monitoring, as well as taking up volume in the tank. The tank has been sounded at the same location multiple times to determine the level of the solids. The readings have been 12, 25 and 15 inches. The SFT is 8.5 feet high and 12 feet in diameter, therefore the solids account for approximately 10 % of the tank volume. Saltstone Engineering has unsuccessfully attempted to obtain scrape samples of the solids for analysis. As a result, Savannah River National Laboratory (SRNL) was tasked with developing a soft core sampler to obtain a sample of the solids and to analyze the core sample to aid in determining a path forward for removing the solids from the SFT. The source of the material in the SFT is the drain water return system where excess liquid from the Saltstone disposal vaults is pumped back to the SFT for reprocessing. It has been shown that fresh grout from the vault enter the drain water system piping. Once these grout solids return to the SFT, they settle in the tank, set up, and can't be reprocessed, causing buildup in the tank over time. The composition of the material indicates that it is potentially toxic for chromium and mercury and the primary radionuclide is cesium-137. Qualitative measurements show that the material is not cohesive and will break apart with some force.

  5. Animal feed compositions containing phytase derived from transgenic alfalfa and methods of use thereof

    DOE Patents [OSTI]

    Austin-Phillips, Sandra; Koegel, Richard G.; Straub, Richard J.; Cook, Mark

    2001-01-01

    A value-added composition of matter containing plant matter from transgenic alfalfa which expresses exogenous phytase activity is disclosed. The phytase activity is a gene product of an exogenous gene encoding for phytase which has been stably incorporated into the genome of alfalfa plants. The transgenic alfalfa expresses phytase activity in nutritionally-significant amounts, thereby enabling its use in animal feeds to eliminate the need for phosphorous supplementation of livestock, poultry, and fish feed rations.

  6. Animal feed compositions containing phytase derived from transgenic alfalfa and methods of use thereof

    DOE Patents [OSTI]

    Austin-Phillips, Sandra; Koegel, Richard G.; Straub, Richard J.; Cook, Mark

    1999-01-01

    A value-added composition of matter containing plant matter from transgenic alfalfa which expresses exogenous phytase activity is disclosed. The phytase activity is a gene product of an exogenous gene encoding for phytase which has been stably incorporated into the genome of alfalfa plants. The transgenic alfalfa expresses phytase activity in nutritionally-significant amounts, thereby enabling its use in animal feeds to eliminate the need for phosphorous supplementation of livestock, poultry, and fish feed rations.

  7. Results of Inspections of Operation of the ORNL Mock Feed/Withdrawal System

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect SciTech Connect Search Results Conference: Results of Inspections of Operation of the ORNL Mock Feed/Withdrawal System Citation Details In-Document Search Title: Results of Inspections of Operation of the ORNL Mock Feed/Withdrawal System Remote monitoring of process activities is one tool under consideration by the International Atomic Energy Agency (IAEA) to handle increasing demands for conducting verification inspections at safeguarded facilities. The

  8. A Mock UF6 Feed and Withdrawal System for Testing Safeguards Monitoring

    Office of Scientific and Technical Information (OSTI)

    Systems and Strategies Intended for Nuclear Fuel Enrichment and Processing Plants (Technical Report) | SciTech Connect SciTech Connect Search Results Technical Report: A Mock UF6 Feed and Withdrawal System for Testing Safeguards Monitoring Systems and Strategies Intended for Nuclear Fuel Enrichment and Processing Plants Citation Details In-Document Search Title: A Mock UF6 Feed and Withdrawal System for Testing Safeguards Monitoring Systems and Strategies Intended for Nuclear Fuel Enrichment

  9. Characterization of trapped gas saturation and heterogeneity in core sampling using miscible-displacement experiments

    SciTech Connect (OSTI)

    Smith, D.H.; Jikich, S.A.

    1994-12-31

    Trapped gas saturation and permeability heterogeneity were evaluated in Berea cores at reservoir conditions, using standard miscible displacement experiments, with and without surfactants. Pressure and production history were influenced by core heterogeneity and foam lamellae formation when aqueous surfactant was present in the core. The objective of the dispersion-capacitance model was to estimate trapped gas saturations; however longitudinal dispersion and mass transfer also were examined. The results show that the dispersion-capacitance model accurately fits trapped gas saturation controlled by rock heterogeneities and foam lamellae for lamella generating mechanisms that allow a continuous gas phase (leave-behind lamellae). The practical applications resulting from this study can aid in core sample selection and scaling short laboratory corefloods to field dimensions for applications to foam stimulation and underground storage of natural gas.

  10. Defining And Characterizing Sample Representativeness For DWPF Melter Feed Samples

    SciTech Connect (OSTI)

    Shine, E. P.; Poirier, M. R.

    2013-10-29

    Representative sampling is important throughout the Defense Waste Processing Facility (DWPF) process, and the demonstrated success of the DWPF process to achieve glass product quality over the past two decades is a direct result of the quality of information obtained from the process. The objective of this report was to present sampling methods that the Savannah River Site (SRS) used to qualify waste being dispositioned at the DWPF. The goal was to emphasize the methodology, not a list of outcomes from those studies. This methodology includes proven methods for taking representative samples, the use of controlled analytical methods, and data interpretation and reporting that considers the uncertainty of all error sources. Numerous sampling studies were conducted during the development of the DWPF process and still continue to be performed in order to evaluate options for process improvement. Study designs were based on use of statistical tools applicable to the determination of uncertainties associated with the data needs. Successful designs are apt to be repeated, so this report chose only to include prototypic case studies that typify the characteristics of frequently used designs. Case studies have been presented for studying in-tank homogeneity, evaluating the suitability of sampler systems, determining factors that affect mixing and sampling, comparing the final waste glass product chemical composition and durability to that of the glass pour stream sample and other samples from process vessels, and assessing the uniformity of the chemical composition in the waste glass product. Many of these studies efficiently addressed more than one of these areas of concern associated with demonstrating sample representativeness and provide examples of statistical tools in use for DWPF. The time when many of these designs were implemented was in an age when the sampling ideas of Pierre Gy were not as widespread as they are today. Nonetheless, the engineers and statisticians used carefully thought out designs that systematically and economically provided plans for data collection from the DWPF process. Key shared features of the sampling designs used at DWPF and the Gy sampling methodology were the specification of a standard for sample representativeness, an investigation that produced data from the process to study the sampling function, and a decision framework used to assess whether the specification was met based on the data. Without going into detail with regard to the seven errors identified by Pierre Gy, as excellent summaries are readily available such as Pitard [1989] and Smith [2001], SRS engineers understood, for example, that samplers can be biased (Gy�s extraction error), and developed plans to mitigate those biases. Experiments that compared installed samplers with more representative samples obtained directly from the tank may not have resulted in systematically partitioning sampling errors into the now well-known error categories of Gy, but did provide overall information on the suitability of sampling systems. Most of the designs in this report are related to the DWPF vessels, not the large SRS Tank Farm tanks. Samples from the DWPF Slurry Mix Evaporator (SME), which contains the feed to the DWPF melter, are characterized using standardized analytical methods with known uncertainty. The analytical error is combined with the established error from sampling and processing in DWPF to determine the melter feed composition. This composition is used with the known uncertainty of the models in the Product Composition Control System (PCCS) to ensure that the wasteform that is produced is comfortably within the acceptable processing and product performance region. Having the advantage of many years of processing that meets the waste glass product acceptance criteria, the DWPF process has provided a considerable amount of data about itself in addition to the data from many special studies. Demonstrating representative sampling directly from the large Tank Farm tanks is a difficult, if not unsolvable enterprise due to limited accessibility. However, the consistency and the adequacy of sampling and mixing at SRS could at least be studied under the controlled process conditions based on samples discussed by Ray and others [2012a] in Waste Form Qualification Report (WQR) Volume 2 and the transfers from Tanks 40H and 51H to the Sludge Receipt and Adjustment Tank (SRAT) within DWPF. It is important to realize that the need for sample representativeness becomes more stringent as the material gets closer to the melter, and the tanks within DWPF have been studied extensively to meet those needs.

  11. Laboratory-Scale Melter for Determination of Melting Rate of Waste Glass Feeds

    SciTech Connect (OSTI)

    Kim, Dong-Sang; Schweiger, Michael J.; Buchmiller, William C.; Matyas, Josef

    2012-01-09

    The purpose of this study was to develop the laboratory-scale melter (LSM) as a quick and inexpensive method to determine the processing rate of various waste glass slurry feeds. The LSM uses a 3 or 4 in. diameter-fused quartz crucible with feed and off-gas ports on top. This LSM setup allows cold-cap formation above the molten glass to be directly monitored to obtain a steady-state melting rate of the waste glass feeds. The melting rate data from extensive scaled-melter tests with Hanford Site high-level wastes performed for the Hanford Tank Waste Treatment and Immobilization Plant have been compiled. Preliminary empirical model that expresses the melting rate as a function of bubbling rate and glass yield were developed from the compiled database. The two waste glass feeds with most melter run data were selected for detailed evaluation and model development and for the LSM tests so the melting rates obtained from LSM tests can be compared with those from scaled-melter tests. The present LSM results suggest the LSM setup can be used to determine the glass production rates for the development of new glass compositions or feed makeups that are designed to increase the processing rate of the slurry feeds.

  12. New Helical Foldamers: Heterogeneous Backbones with 1:2 and 2:1

    Office of Scientific and Technical Information (OSTI)

    [alpha]:[superscript beta]-Amino Acid Residue Patterns (Journal Article) | SciTech Connect New Helical Foldamers: Heterogeneous Backbones with 1:2 and 2:1 [alpha]:[superscript beta]-Amino Acid Residue Patterns Citation Details In-Document Search Title: New Helical Foldamers: Heterogeneous Backbones with 1:2 and 2:1 [alpha]:[superscript beta]-Amino Acid Residue Patterns Authors: Schmitt, Margaret A. ; Choi, SooHyuk ; Guzei, Ilia A. ; Gellman, Samuel H. [1] + Show Author Affiliations (UW)

  13. Chemical Heterogeneity of a Large Cluster CP IDP: Clues to its Formation

    Office of Scientific and Technical Information (OSTI)

    History Using X-ray Fluoresence Mapping and Cr and Fe XANES Spectroscopy (Conference) | SciTech Connect SciTech Connect Search Results Conference: Chemical Heterogeneity of a Large Cluster CP IDP: Clues to its Formation History Using X-ray Fluoresence Mapping and Cr and Fe XANES Spectroscopy Citation Details In-Document Search Title: Chemical Heterogeneity of a Large Cluster CP IDP: Clues to its Formation History Using X-ray Fluoresence Mapping and Cr and Fe XANES Spectroscopy Authors:

  14. Risk management of undesirable substances in feed following updated risk assessments

    SciTech Connect (OSTI)

    Verstraete, Frans

    2013-08-01

    Directive 2002/32/EC of 7 May 2002 of the European Parliament and of the Council on undesirable substances in animal feed is the framework for the EU action on undesirable substances in feed. This framework Directive provides: ?that products intended for animal feed may enter for use in the Union from third countries, be put into circulation and/or used in the Union only if they are sound, genuine and of merchantable quality and therefore when correctly used do not represent any danger to human health, animal health or to the environment or could adversely affect livestock production. ?that in order to protect animal and public health and the environment, maximum levels for specific undesirable substances shall be established where necessary. ?for mandatory consultation of a scientific body (EFSA) for all provisions which may have an effect upon public health or animal health or on the environment. ?that products intended for animal feed containing levels of an undesirable substance that exceed the established maximum level may not be mixed for dilution purposes with the same, or other, products intended for animal feed and may not be used for the production of compound feed. Based on the provisions and principles laid down in this framework Directive, maximum levels for a whole range of undesirable substances have been established at EU level. During the discussions in view of the adoption of Directive 2002/32/EC, the European Commission made the commitment to review all existing provisions on undesirable substances on the basis of updated scientific risk assessments. Following requests of the European Commission, the Panel on Contaminants in the Food Chain (CONTAM) from the European Food Safety Authority (EFSA) has completed a series of 30 risk assessments undertaken over the last 5 years on undesirable substances in animal feed reviewing the possible risks for animal and human health due to the presence of these substances in animal feed. EU legislation on undesirable substances has undergone recently several changes to take account of these most recent scientific opinions. Furthermore EFSA has assessed the risks for public and animal health following the unavoidable carry-over of coccidiostats into non target feed. Maximum levels for the unavoidable carry-over have been established for the non-target feed and the food of animal origin from non-target animal species.

  15. A New Equivalence Theory Method for Treating Doubly Heterogeneous Fuel - II. Verifications

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Choi, Sooyoung; Kong, Chidong; Lee, Deokjung; Williams, Mark L.

    2015-03-09

    A new methodology has been developed recently to treat resonance self-shielding in systems for which the fuel compact region of a reactor lattice consists of small fuel grains dispersed in a graphite matrix. The theoretical development adopts equivalence theory in both micro- and macro-level heterogeneities to provide approximate analytical expressions for the shielded cross sections, which may be interpolated from a table of resonance integrals or Bondarenko factors using a modified background cross section as the interpolation parameter. This paper describes the first implementation of the theoretical equations in a reactor analysis code. In order to reduce discrepancies caused bymore » use of the rational approximation for collision probabilities in the original derivation, a new formulation for a doubly heterogeneous Bell factor is developed in this paper to improve the accuracy of doubly heterogeneous expressions. This methodology is applied to a wide range of pin cell and assembly test problems with varying geometry parameters, material compositions, and temperatures, and the results are compared with continuous-energy Monte Carlo simulations to establish the accuracy and range of applicability of the new approach. It is shown that the new doubly heterogeneous self-shielding method including the Bell factor correction gives good agreement with reference Monte Carlo results.« less

  16. An Experimental Investigation of Foam Flow in Homogeneous and Heterogeneous Porous Media, SUPRI TR-112

    SciTech Connect (OSTI)

    Apaydin, Osman G.; Bertin, Henri; Castanier, Louis M.; Kovscek, Anthony R.

    1999-08-09

    Foam is used to reduce the high mobility of gas-drive fluids and improve the contact between oil and these injected fluids. We require a better understanding of the effect of surfactant concentration on foam flow in porous media. Besides this, the literature on foam flow and transport in heterogeneous systems is sparse although the field situation is primarily heterogeneous and multidimensional. In this study, foam flow experiments were conducted first in homogeneous sand packs to investigate the effect of surfactant concentration on foam flow and then a heterogeneous experimental setup was prepared to observe heterogeneity and multidimensional flow effects on foam propagation. The homogeneous core experiments were conducted in a cylindrical aluminum core holder that was packed with a uniform Ottawa sand. Sand permeability is about 7.0 Darcy. The experiments were interpreted in terms of evolution of in-situ water saturation as a function of time by the usage of CT scanner, cumulative water, and pressure drop across the core. At very low surfactant concentration, no significant benefit was observed. But when stable foam generation started sweep efficiency (water recovery), breakthrough time, and pressure drop increased as surfactant concentration increased.

  17. High-throughput imaging of heterogeneous cell organelles with an X-ray laser

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Hantke, Max, F.

    2014-11-17

    Preprocessed detector images that were used for the paper "High-throughput imaging of heterogeneous cell organelles with an X-ray laser". The CXI file contains the entire recorded data - including both hits and blanks. It also includes down-sampled images and LCLS machine parameters. Additionally, the Cheetah configuration file is attached that was used to create the pre-processed data.

  18. Physics of DNAPL migration and remediation in the presence of heterogeneities. 1997 annual progress report

    SciTech Connect (OSTI)

    Conrad, S.; Glass, R.

    1997-01-01

    'The authors are in the process of conducting well-controlled laboratory experiments to better understand the physics of DNAPL migration and remediation in the presence of heterogeneities. These experiments are being used to develop and test an upscaled percolation model, a new approach for modeling DNAPL migration. In addition, numerical simulators under current use in evaluating remediation techniques will be compared against the remediation experiments. They are making use of their unique experimental capabilities in the Subsurface Flow and Transport Processes Laboratory at Sandia to conduct controlled, systematic, repeatable experiments that first consider the physics of DNAPL migration in initially water-saturated, heterogeneous porous media and then evaluate the efficacy of a suite of promising remediation techniques for remediating DNAPLs from heterogeneous aquifers. The results of the migration experiments are being used to test and continue development of new modeling approaches based on upscaled percolation theory developed by us. The remediation experiments include visual and quantitative measures of each remediation technique''s performance. The results of the remediation experiments will be used to test, for the first time, within heterogeneous media, the quantitative performance of remediation design codes (two-phase flow codes that incorporate compositional models).'

  19. A New Equivalence Theory Method for Treating Doubly Heterogeneous Fuel - II. Verifications

    SciTech Connect (OSTI)

    Choi, Sooyoung; Kong, Chidong; Lee, Deokjung; Williams, Mark L.

    2015-03-09

    A new methodology has been developed recently to treat resonance self-shielding in systems for which the fuel compact region of a reactor lattice consists of small fuel grains dispersed in a graphite matrix. The theoretical development adopts equivalence theory in both micro- and macro-level heterogeneities to provide approximate analytical expressions for the shielded cross sections, which may be interpolated from a table of resonance integrals or Bondarenko factors using a modified background cross section as the interpolation parameter. This paper describes the first implementation of the theoretical equations in a reactor analysis code. In order to reduce discrepancies caused by use of the rational approximation for collision probabilities in the original derivation, a new formulation for a doubly heterogeneous Bell factor is developed in this paper to improve the accuracy of doubly heterogeneous expressions. This methodology is applied to a wide range of pin cell and assembly test problems with varying geometry parameters, material compositions, and temperatures, and the results are compared with continuous-energy Monte Carlo simulations to establish the accuracy and range of applicability of the new approach. It is shown that the new doubly heterogeneous self-shielding method including the Bell factor correction gives good agreement with reference Monte Carlo results.

  20. Characterization of trapped gas saturation and heterogeneity in core samples using miscible-displacement experiments

    SciTech Connect (OSTI)

    Smith, D.H.; Jikich, S.A.

    1994-12-31

    Trapped gas saturation and permeability heterogeneity were evaluated in Berea cores at reservoir conditions, using standard miscible displacement experiments, with and without surfactants. Pressure and production history were influenced by core heterogeneity and foam lamellae formation when aqueous surfactant was present in the core. A simple dispersion model and a three-coefficient dispersion-capacitance model (Coates-Smith) were fit to the experimental data. The dispersion-capacitance model successfully matched the experiments in which foam lamella formed, while the simple dispersion model was used only for determining initial core flow heterogeneity. The objective of the dispersion-capacitance model was to estimate trapped gas saturations; however longitudinal dispersion and mass transfer also were examined. The results show that the dispersion-capacitance model accurately fits trapped gas saturation controlled by rock heterogeneities and foam lamellae for lamella generating mechanisms that allow a continuous gas phase (leave-behind lamellae). The practical applications resulting from this study can aid in core sample selection and scaling short laboratory corefloods to field dimensions for applications to foam stimulation and underground storage of natural gas.

  1. Long-term Differences in Tillage and Land Use Affect Intra-aggregate Pore Heterogeneity

    SciTech Connect (OSTI)

    Kravchenko, A.N.; Wang, A.N.W.; Smucker, A.J.M.; Rivers, M.L.

    2012-10-25

    Recent advances in computed tomography provide measurement tools to study internal structures of soil aggregates at micrometer resolutions and to improve our understanding of specific mechanisms of various soil processes. Fractal analysis is one of the data analysis tools that can be helpful in evaluating heterogeneity of the intra-aggregate internal structures. The goal of this study was to examine how long-term tillage and land use differences affect intra-aggregate pore heterogeneity. The specific objectives were: (i) to develop an approach to enhance utility of box-counting fractal dimension in characterizing intra-aggregate pore heterogeneity; (ii) to examine intra-aggregate pores in macro-aggregates (4-6 mm in size) using the computed tomography scanning and fractal analysis, and (iii) to compare heterogeneity of intra-aggregate pore space in aggregates from loamy Alfisol soil subjected to 20 yr of contrasting management practices, namely, conventional tillage (chisel plow) (CT), no-till (NT), and native succession vegetation (NS). Three-dimensional images of the intact aggregates were obtained with a resolution of 14.6 {micro}m at the Advanced Photon Source, Argonne National Laboratory, Argonne, IL. Proposed box-counting fractal dimension normalization was successfully implemented to estimate heterogeneity of pore voxel distributions without bias associated with different porosities in soil aggregates. The aggregates from all three studied treatments had higher porosity associated with large (>100 {micro}m) pores present in their centers than in their exteriors. Pores 15 to 60 {micro}m were equally abundant throughout entire aggregates but their distributions were more heterogeneous in aggregate interiors. The CT aggregates had greater numbers of pores 15 to 60 {micro}m than NT and NS. Distribution of pore voxels belonging to large pores was most heterogeneous in the aggregates from NS, followed by NT and by CT. This result was consistent with presence of very large pores associated with former root channels in NT and NS aggregates. Our findings indicate that mechanisms of macro-aggregate formation might differ in their importance in different land use and management practices.

  2. Data quality objectives for TWRS privatization phase 1: confirm tank T is an appropriate feed source for high-level waste feed batch X

    SciTech Connect (OSTI)

    NGUYEN, D.M.

    1999-06-01

    The U.S. Department of Energy-Richland Operations Office (DOE-RL) has initiated Phase 1 of a two-phase privatization strategy for treatment and immobilization of high-level waste (HLW) that is currently managed by the Hanford Tank Waste Remediation System (TWRS) Project. In this strategy, DOE will purchase services from a contractor-owned and operated facility under a fixed price. The Phase 1 TWRS privatization contract requires that the Project Hanford Management Contract (PHMC) contractors, on behalf of DOE, deliver HLW feed in specified quantities and composition to the Privatization Contractor in a timely manner (DOE-RL 1996). Additional requirements are imposed by the interface control document (ICD) for HLW feed (PHMC 1997). In response to these requirements, the Tank Waste Remediation System Operation and Utilization Plan (TWRSO and UP) (Kirkbride et al. 1997) was prepared by the PHMC. The TWRSO and UP, as updated by the Readiness-To-Proceed (RTP) deliverable (Payne et al. 1998), establishes the baseline operating scenario for the delivery of HLW feed to the Privatization Contractor. The scenario specifies tanks from which HLW will be provided for each feed batch, the operational activities needed to prepare and deliver each batch, and the timing of these activities. The operating scenario was developed based on current knowledge of waste composition and chemistry, waste transfer methods, and operating constraints such as tank farm logistics and availability of tank space. A project master baseline schedule (PMBS) has been developed to implement the operating scenario. The PMBS also includes activities aimed at reducing programmatic risks. One of the activities, ''Confirm Tank TI is Acceptable for Feed,'' was identified to verify the basis used to develop the scenario Additional data on waste quantity, physical and chemical characteristics, and transfer properties will be needed to support this activity. This document describes the data quality objective (DQO) process undertaken to assure appropriate data will be collected to support the activity, ''Confirm Tank T is Acceptable for HLW Feed.'' The DQO process was implemented in accordance with the TWRS DQO process (Banning 1997) with some modifications to accommodate project or tank-specific requirements and constraints.

  3. HIGH-LEVEL WASTE FEED CERTIFICATION IN HANFORD DOUBLE-SHELL TANKS

    SciTech Connect (OSTI)

    THIEN MG; WELLS BE; ADAMSON DJ

    2010-01-14

    The ability to effectively mix, sample, certify, and deliver consistent batches of High Level Waste (HLW) feed from the Hanford Double Shell Tanks (DST) to the Waste Treatment and Immobilization Plant (WTP) presents a significant mission risk with potential to impact mission length and the quantity of HLW glass produced. DOE's River Protection Project (RPP) mission modeling and WTP facility modeling assume that individual 3785 cubic meter (l million gallon) HLW feed tanks are homogenously mixed, representatively sampled, and consistently delivered to the WTP. It has been demonstrated that homogenous mixing ofHLW sludge in Hanford DSTs is not likely achievable with the baseline design thereby causing representative sampling and consistent feed delivery to be more difficult. Inconsistent feed to the WTP could cause additional batch-to-batch operational adjustments that reduce operating efficiency and have the potential to increase the overall mission length. The Hanford mixing and sampling demonstration program will identify DST mixing performance capability, will evaluate representative sampling techniques, and will estimate feed batch consistency. An evaluation of demonstration program results will identify potential mission improvement considerations that will help ensure successful mission completion. This paper will discuss the history, progress, and future activities that will define and mitigate the mission risk.

  4. Review Guidance for the TWRS FSAR amendment for Waste Retrieval and waste feed delivery

    SciTech Connect (OSTI)

    GRIFFITH, R.W.

    1999-10-01

    This review guidance (Guide) was developed for Office of River Protection (ORP) reviewers to use in reviewing the amendment to the Tank Waste Remediation System (TWRS) Final Safety Analysis Report (FSAR) covering waste retrieval and waste feed delivery. Waste retrieval and waste feed delivery are necessary to supply nuclear waste from TWRS storage tanks to the TWRS Privatization (TWRS-P) Contractor's vitrification facility and to receive intermediate waste from the vitrification facility back into the TWRS tank farms for interim storage. An amendment to the approved TWRS FSAR (HNF-SD-WM-SAR-067, Rev. 0) is necessary to change the authorization basis to accommodate waste retrieval and waste feed delivery. The ORP'S safety responsibility in reviewing the FSAR amendment is to determine that reasonable assurance exists that waste retrieval and waste feed delivery operations can be accomplished with adequate safety for the workers, the public, and the environment. To carry out this responsibility, the ORP will evaluate the Contractor's amendment to the TWRS FSAR for waste retrieval and waste feed delivery to determine whether the submittal provides adequate safety and complies with applicable regulatory requirements.

  5. Methods of removing a constituent from a feed stream using adsorption media

    DOE Patents [OSTI]

    Tranter, Troy J.; Mann, Nicholas R.; Todd, Terry A.; Herbst, Ronald S.

    2011-05-24

    A method of producing an adsorption medium to remove at least one constituent from a feed stream. The method comprises dissolving and/or suspending at least one metal compound in a solvent to form a metal solution, dissolving polyacrylonitrile into the metal solution to form a PAN-metal solution, and depositing the PAN-metal solution into a quenching bath to produce the adsorption medium. The at least one constituent, such as arsenic, selenium, or antimony, is removed from the feed stream by passing the feed stream through the adsorption medium. An adsorption medium having an increased metal loading and increased capacity for arresting the at least one constituent to be removed is also disclosed. The adsorption medium includes a polyacrylonitrile matrix and at least one metal hydroxide incorporated into the polyacrylonitrile matrix.

  6. Process for catalytic cracking of heavy hydrocarbon feed to lighter products

    SciTech Connect (OSTI)

    Herbst, J.A.; Owen, H.; Schipper, P.H.

    1990-05-29

    This patent describes a process for catalytic cracking of a feed of hydrocarbons boiling in the gas oil and heavier boiling range to lighter products by contacting the feed at catalytic cracking conditions and catalytically cracking the feed to lighter products with a cracking catalyst. It comprises: a mixture of separate particles of: a bulk conversion cracking catalyst containing at least one component with an equivalent pore size of at least about 7 angstroms in a matrix, the bulk conversion cracking catalyst having fluidization properties which permit use in a fluidized or moving bed catalytic cracking reactor; a light paraffin upgrading catalyst comprising at least one zeolite having a constraint index of 1--12 and paraffin cracking/isomerization activity; and, a light paraffin upgrading catalyst comprising at least one zeolite having a constraint index of 1--12 and paraffin aromatization activity; and wherein the upgrading catalysts have substantially the same fluidization properties as the bulk conversion cracking catalyst.

  7. NNSA Production Office tops Feds Feed Families campaign goal | Y-12

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Security Complex tops ... NNSA Production Office tops Feds Feed Families campaign goal Posted: September 16, 2013 - 9:45am Oak Ridge, Tenn. - Employees of the National Nuclear Security Administration Production Office have donated 17,348 pounds of food as part of the annual U.S. Department of Energy's "Feds Feed Families" campaign. The campaign, which ended on September 6, surpassed the goal of 17,000 pounds. "I am extremely proud and moved by the generosity of NPO

  8. FCC Pilot Plant Results with Vegetable Oil and Pyrolysis Oil Feeds |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy FCC Pilot Plant Results with Vegetable Oil and Pyrolysis Oil Feeds FCC Pilot Plant Results with Vegetable Oil and Pyrolysis Oil Feeds Breakout Session 2: Frontiers and Horizons Session 2-D: Working Together: Conventional Refineries and Bio-Oil R&D Technologies E. Thomas (Tom) Habib, Jr., Director, Customer Research Partnerships, W.R. Grace & Co. PDF icon biomass13_habib_2-d.pdf More Documents & Publications Opportunities for Biomass-Based Fuels and Products

  9. Analysis of gas centrifuge cascade for separation of multicomponent isotopes and optimal feed position

    SciTech Connect (OSTI)

    Chuntong Ying; Hongjiang Wu; Mingsheng Zhou; Yuguang Nie; Guangjun Liu

    1997-10-01

    Analysis of the concentration distribution in a gas centrifuge cascade for separation of multicomponent isotope mixtures is different from that in a cascade for separation of two-component mixtures. This paper presents the governing equations for a multicomponent isotope separation cascade. Numerically predicted separation factors for the gas centrifuge cascade agree well with the experimental data. A theoretical optimal feed position is derived for a short square cascade for a two-component mixture in a close-separation case. The optimal feed position for a gas centrifuge cascade for separation of multicomponent mixture is discussed.

  10. Innovative Feed-In Tariff Designs that Limit Policy Costs (Technical

    Office of Scientific and Technical Information (OSTI)

    Report) | SciTech Connect Innovative Feed-In Tariff Designs that Limit Policy Costs Citation Details In-Document Search Title: Innovative Feed-In Tariff Designs that Limit Policy Costs × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional information resources in energy science and technology. A paper copy

  11. Hanford Waste Vitrification Plant full-scale feed preparation testing with water and process simulant slurries

    SciTech Connect (OSTI)

    Gaskill, J.R.; Larson, D.E.; Abrigo, G.P.

    1996-03-01

    The Hanford Waste Vitrification Plant was intended to convert selected, pretreated defense high-level waste and transuranic waste from the Hanford Site into a borosilicate glass. A full-scale testing program was conducted with nonradioactive waste simulants to develop information for process and equipment design of the feed-preparation system. The equipment systems tested included the Slurry Receipt and Adjustment Tank, Slurry Mix Evaporator, and Melter-Feed Tank. The areas of data generation included heat transfer (boiling, heating, and cooling), slurry mixing, slurry pumping and transport, slurry sampling, and process chemistry. 13 refs., 129 figs., 68 tabs.

  12. ,"Catalytic Reforming Downstream Processing of Fresh Feed Input"

    U.S. Energy Information Administration (EIA) Indexed Site

    Catalytic Reforming Downstream Processing of Fresh Feed Input" ,"Click worksheet name or tab at bottom for data" ,"Worksheet Name","Description","# Of Series","Frequency","Latest Data for" ,"Data 1","Catalytic Reforming Downstream Processing of Fresh Feed Input",16,"Monthly","2/2016","1/15/2010" ,"Release Date:","4/29/2016" ,"Next Release

  13. Long-term desorption behavior of uranium and neptunium in heterogeneous volcanic tuff materials /

    SciTech Connect (OSTI)

    Dean, Cynthia A.

    2010-05-01

    Uranium and neptunium desorption were studied in long-term laboratory experiments using four well-characterized volcanic tuff cores collected from southeast of Yucca Mountain, Nevada. The objectives of the experiments were to 1. Demonstrate a methodology aimed at characterizing distributions of sorption parameters (attributes of multiple sorption sites) that can be applied to moderately-sorbing species in heterogeneous systems to provide more realistic reactive transport parameters and a more realistic approach to modeling transport in heterogeneous systems. 2. Focus on uranium and neptunium because of their high solubility, relatively weak sorption, and high contributions to predicted dose in Yucca Mountain performance assessments. Also, uranium is a contaminant of concern at many DOE legacy sites and uranium mining sites.

  14. Impact of heterogeneous ice nuclei on homogeneous freezing events in cirrus clouds

    SciTech Connect (OSTI)

    Spichtinger, Peter; Cziczo, Daniel J.

    2010-07-29

    The influence of initial heterogeneous nucleation on subsequent homogeneous nucleation events in cirrus clouds is investigated using a box model which includes the explicit impact of aerosols on the nucleation of ice crystals and sedimentation. Different effects are discussed, namely the impact of external mixtures of heterogeneous ice nuclei and the influence of size-dependent freezing thresholds. Several idealized experiments are carried out, which show that the treatment of external mixtures of ice nuclei can strongly change later homogeneous nucleation events (i.e., the ice crystal number densities) in different matters. The use of size-dependent freezing thresholds can also change the cloud prop erties when compared to more simple parameterizations. This size effect is most important for large IN concentrations. Based upon these findings, recommendations for future modeling and measurement efforts are presented.

  15. Wavelet-based surrogate time series for multiscale simulation of heterogeneous catalysis

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Savara, Aditya Ashi; Daw, C. Stuart; Xiong, Qingang; Gur, Sourav; Danielson, Thomas L.; Hin, Celine N.; Pannala, Sreekanth; Frantziskonis, George N.

    2016-01-28

    We propose a wavelet-based scheme that encodes the essential dynamics of discrete microscale surface reactions in a form that can be coupled with continuum macroscale flow simulations with high computational efficiency. This makes it possible to simulate the dynamic behavior of reactor-scale heterogeneous catalysis without requiring detailed concurrent simulations at both the surface and continuum scales using different models. Our scheme is based on the application of wavelet-based surrogate time series that encodes the essential temporal and/or spatial fine-scale dynamics at the catalyst surface. The encoded dynamics are then used to generate statistically equivalent, randomized surrogate time series, which canmore » be linked to the continuum scale simulation. As a result, we illustrate an application of this approach using two different kinetic Monte Carlo simulations with different characteristic behaviors typical for heterogeneous chemical reactions.« less

  16. Theory of ultrafast heterogeneous electron transfer: Contributions of direct charge transfer excitations to the absorbance

    SciTech Connect (OSTI)

    Wang, Luxia; Willig, Frank; May, Volkhard

    2007-04-07

    Absorption spectra related to heterogeneous electron transfer are analyzed with the focus on direct charge transfer transition from the surface attached molecule into the semiconductor band states. The computations are based on a model of reduced dimensionality with a single intramolecular vibrational coordinate but a complete account for the continuum of conduction band states. The applicability of this model to perylene on TiO{sub 2} has been demonstrated in a series of earlier papers. Here, based on a time-dependent formulation, the absorbance is calculated with the inclusion of charge transfer excitations. A broad parameter set inspired by the perylene TiO{sub 2} systems is considered. In particular, the description generalizes the Fano effect to heterogeneous electron transfer reactions. Preliminary simulations of measured spectra are presented for perylene-catechol attached to TiO{sub 2}.

  17. The performance of 3500 MWth homogeneous and heterogeneous metal fueled core designs

    SciTech Connect (OSTI)

    Turski, R.; Yang, Shi-tien

    1987-11-01

    Performance parameters are calculated for a representative 3500 MWth homogeneous and a heterogeneous metal fueled reactor design. The equilibrium cycle neutronic characteristics, safety coefficients, control system requirements, and control rod worths are evaluated. The thermal-hydraulic characteristics for both configurations are also compared. The heavy metal fuel loading requirements and neutronic performance characteristics are also evaluated for the uranium startup option. 14 refs., 14 figs., 20 tabs.

  18. Thermal Design and Characterization of Heterogeneously Integrated InGaP/GaAs HBTs

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Choi, Sukwon; Peake, Gregory M.; Keeler, Gordon A.; Geib, Kent M.; Briggs, Ronald D.; Beechem, Thomas E.; Shaffer, Ryan A.; Clevenger, Jascinda; Patrizi, Gary A.; Klem, John F.; et al

    2016-04-21

    Flip-chip heterogeneously integrated n-p-n InGaP/GaAs heterojunction bipolar transistors (HBTs) with integrated thermal management on wide-bandgap AlN substrates followed by GaAs substrate removal are demonstrated. Without thermal management, substrate removal after integration significantly aggravates self-heating effects, causing poor I–V characteristics due to excessive device self-heating. An electrothermal codesign scheme is demonstrated that involves simulation (design), thermal characterization, fabrication, and evaluation. Thermoreflectance thermal imaging, electrical-temperature sensitive parameter-based thermometry, and infrared thermography were utilized to assess the junction temperature rise in HBTs under diverse configurations. In order to reduce the thermal resistance of integrated devices, passive cooling schemes assisted by structural modification, i.e.,more » positioning indium bump heat sinks between the devices and the carrier, were employed. By implementing thermal heat sinks in close proximity to the active region of flip-chip integrated HBTs, the junction-to-baseplate thermal resistance was reduced over a factor of two, as revealed by junction temperature measurements and improvement of electrical performance. In conclusion, the suggested heterogeneous integration method accounts for not only electrical but also thermal requirements providing insight into realization of advanced and robust III–V/Si heterogeneously integrated electronics.« less

  19. Reservoir heterogeneity in carboniferous sandstone of the Black Warrior basin. Final report

    SciTech Connect (OSTI)

    Kugler, R.L.; Pashin, J.C.; Carroll, R.E.; Irvin, G.D.; Moore, H.E.

    1994-06-01

    Although oil production in the Black Warrior basin of Alabama is declining, additional oil may be produced through improved recovery strategies, such as waterflooding, chemical injection, strategic well placement, and infill drilling. High-quality characterization of reservoirs in the Black Warrior basin is necessary to utilize advanced technology to recover additional oil and to avoid premature abandonment of fields. This report documents controls on the distribution and producibility of oil from heterogeneous Carboniferous reservoirs in the Black Warrior basin of Alabama. The first part of the report summarizes the structural and depositional evolution of the Black Warrior basin and establishes the geochemical characteristics of hydrocarbon source rocks and oil in the basin. This second part characterizes facies heterogeneity and petrologic and petrophysical properties of Carter and Millerella sandstone reservoirs. This is followed by a summary of oil production in the Black Warrior basin and an evaluation of seven improved-recovery projects in Alabama. In the final part, controls on the producibility of oil from sandstone reservoirs are discussed in terms of a scale-dependent heterogeneity classification.

  20. Dynamics and heterogeneity of a fate determinant during transition towards cell differentiation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Peláez, Nicolás; Gavalda-Miralles, Arnau; Wang, Bao; Navarro, Heliodoro Tejedor; Gudjonson, Herman; Rebay, Ilaria; Dinner, Aaron R.; Katsaggelos, Aggelos K.; Amaral, Luís AN; Carthew, Richard W.

    2015-11-19

    Yan is an ETS-domain transcription factor responsible for maintaining Drosophila eye cells in a multipotent state. Yan is at the core of a regulatory network that determines the time and place in which cells transit from multipotency to one of several differentiated lineages. Using a fluorescent reporter for Yan expression, we observed a biphasic distribution of Yan in multipotent cells, with a rapid inductive phase and slow decay phase. Transitions to various differentiated states occurred over the course of this dynamic process, suggesting that Yan expression level does not strongly determine cell potential. Consistent with this conclusion, perturbing Yan expressionmore » by varying gene dosage had no effect on cell fate transitions. However, we observed that as cells transited to differentiation, Yan expression became highly heterogeneous and this heterogeneity was transient. Signals received via the EGF Receptor were necessary for the transience in Yan noise since genetic loss caused sustained noise. Since these signals are essential for eye cells to differentiate, we suggest that dynamic heterogeneity of Yan is a necessary element of the transition process, and cell states are stabilized through noise reduction.« less

  1. Reservoir heterogeneity in Carboniferous sandstone of the Black Warrior basin. Final report

    SciTech Connect (OSTI)

    Kugler, R.L.; Pashin, J.C.; Carroll, R.E.; Irvin, G.D.; Moore, H.E.

    1994-04-01

    Although oil production in the Black Warrior basin of Alabama is declining, additional oil may be produced through improved recovery strategies, such as waterflooding, chemical injection, strategic well placement, and infill drilling. High-quality characterization of reservoirs in the Black Warrior basin is necessary to utilize advanced technology to recover additional oil and to avoid premature abandonment of fields. This report documents controls on the distribution and producibility of oil from heterogeneous Carboniferous reservoirs in the Black Warrior basin of Alabama. The first part of the report summarizes the structural and depositional evolution of the Black Warrior basin and establishes the geochemical characteristics of hydrocarbon source rocks and oil in the basin. This second part characterizes facies heterogeneity and petrologic and petrophysical properties of Carter and Millerella sandstone reservoirs. This is followed by a summary of oil production in the Black Warrior basin and an evaluation of seven improved-recovery projects in Alabama. In the final part, controls on the producibility of oil from sandstone reservoirs are discussed in terms of a scale-dependent heterogeneity classification.

  2. Influence of heterogeneity on second-kind self-similar solutions for viscous gravity currents

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zheng, Zhong; Christov, Ivan  C.; Stone, Howard  A.

    2014-04-16

    We report experimental, theoretical and numerical results on the effects of horizontal heterogeneities on the propagation of viscous gravity currents. We use two geometries to highlight these effects: (a) a horizontal channel (or crack) whose gap thickness varies as a power-law function of the streamwise coordinate; (b) a heterogeneous porous medium whose permeability and porosity have power-law variations. We demonstrate that two types of self-similar behaviours emerge as a result of horizontal heterogeneity: (a) a first-kind self-similar solution is found using dimensional analysis (scaling) for viscous gravity currents that propagate away from the origin (a point of zero permeability); (b)more » a second-kind self-similar solution is found using a phase-plane analysis for viscous gravity currents that propagate toward the origin. These theoretical predictions, obtained using the ideas of self-similar intermediate asymptotics, are compared with experimental results and numerical solutions of the governing partial differential equation developed under the lubrication approximation. All three results are found to be in good agreement.« less

  3. DEFLECTION OF A HETEROGENEOUS WIDE-BEAM UNDER UNIFORM PRESSURE LOAD

    SciTech Connect (OSTI)

    T. V. Holschuh; T. K. Howard; W. R. Marcum

    2014-07-01

    Oregon State University (OSU) and the Idaho National Laboratory (INL) are currently collaborating on a test program which entails hydro-mechanical testing of a generic plate type fuel element, or generic test plate assembly (GTPA), for the purpose of qualitatively demonstrating mechanical integrity of uranium-molybdenum monolithic plates as compared to that of uranium aluminum dispersion, and aluminum fuel plates onset by hydraulic forces. This test program supports ongoing work conducted for/by the Global Threat Reduction Initiative (GTRI) Fuels Development Program. This study’s focus supports the ongoing collaborative effort by detailing the derivation of an analytic solution for deflection of a heterogeneous plate under a uniform, distributed load in order to predict the deflection of test plates in the GTPA. The resulting analytical solutions for three specific boundary condition sets are then presented against several test cases of a homogeneous plate. In all test cases considered, the results for both homogeneous and heterogeneous plates are numerically identical to one another, demonstrating correct derivation of the heterogeneous solution. Two additional problems are presents herein that provide a representative deflection profile for the plates under consideration within the GTPA. Furthermore, qualitative observations are made about the influence of a more-rigid internal fuel-meat region and its influence on the overall deflection profile of a plate. Present work is being directed to experimentally confirm the analytical solution’s results using select materials.

  4. Biogas management by controlled feeding and heating of a dairy manure digester

    SciTech Connect (OSTI)

    Chayovan, S.

    1984-01-01

    Gas production dynamics were investigated using laboratory scale digesters fed daily with dairy manure and operated both at constant temperature and with imposed temperature fluctuations of +/-3.3/sup 0/C about a mean of 35.8/sup 0/C. At constant temperature, a 14-liter control digester with a detention time of 19 days, fed with manure diluted to 25% and blended, behaved similarly to two 3-liter digesters fed hole manure at a detection time of 15 days. A second 14-liter digester fed with the diluted manure was operated with three phase relations between the 24 hour temperature cycle and the pulse feeding time. The higher the temperature at the time of feeding, the higher the peak gas production, up to 1.8 times the control. Gradually increasing the temperature after feeding results in sustained high gas production until the most rapidly degradable material is consumed. In all cases digester operation was stable as indicated by pH, alkalinity and total daily gas production. A mathematical model based on three substrate fractions having each first order kinetics and the Arrhenius temperature relationship successfully predicted gas production dynamics as long as hydrolysis remained the rate limiting step and the volatile acid pool did not change rapidly. Results show that gas storage can be reduced as much as 52% using managed heating and feeding for a situation in which gas is productively utilized for only eight hours of the day.

  5. Design of RF Feed System for Standing-Wave Accelerator Structures

    SciTech Connect (OSTI)

    Neilson, J.; Tantawi, S.; Dolgashev, V.; /SLAC

    2012-05-25

    We are investigating a standing wave accelerator structure that uses a rf feed to each individual cell. This approach minimizes rf power flow and electromagnetic energy absorbed by an rf breakdown. The objective of this work is a robust high-gradient (above 100 MV/m) X-band accelerator structure.

  6. FY14-Q1 1.2.1.3.ML.1 INL Biomass Feeding Survey Report

    SciTech Connect (OSTI)

    Tyler L. Westover

    2014-04-01

    Approximately 20 institutions were contacted by telephone and/or electronic mail and requested to provide responses to a survey on feeding biomass feedstock materials. Fourteen individuals responded. Responses from the participants, including information that was offered in addition to answers to the survey questions are summarized in this report, which fully meets the requirements of the milestone.

  7. Redox control of electric melters with complex feed compositions. Part I: analytical methods and models

    SciTech Connect (OSTI)

    Bickford, D F; Diemer, Jr, R B

    1985-01-01

    The redox state of glass from electric melters with complex feed compositions is determined by balance between gases above the melt, and transition metals and organic compounds in the feed. Part I discusses experimental and computational methods of relating flowrates and other melter operating conditions to the redox state of glass, and composition of the melter offgas. Computerized thermodynamic computational methods are useful in predicting the sequence and products of redox reactions and in assessing individual process variations. Melter redox state can be predicted by combining monitoring of melter operating conditions, redox measurement of fused melter feed samples, and periodic redox measurement of product. Mossbauer spectroscopy, and other methods which measure Fe(II)/Fe(III) in glass, can be used to measure melter redox state. Part II develops preliminary operating limits for the vitrification of High-Level Radioactive Waste. Limits on reducing potential to preclude the accumulation of combustible gases, accumulation of sulfides and selenides, and degradation of melter components are the most critical. Problems associated with excessively oxidizing conditions, such as glass foaming and potential ruthenium volatility, are controlled when sufficient formic acid is added to adjust melter feed rheology.

  8. A Fuzzy Feed-Forward/Feedback Control System for a Three-Phase Oil Field Centrifuge.

    SciTech Connect (OSTI)

    Parkinson, W. J. ,; Smith, R. E.; Mortensen, F. N.; Wantuck, P. J.; Ross, Timothy J.; Jamshidi, Mohammad; Miller, N.

    2002-01-01

    A set of fuzzy controllers was designed and applied to a commercial three-phase oil field centrifuge. This centrifuge is essentially a one of a kind unit. It is used to recover oil from tank bottoms and oil field and/or refinery sludge. It is unique because it can separate oily emulsions into three separate phases, oil, water, and solids, in one operation. The centrifuge is a large but portable device. It is moved form site to site and is used to separate a large variety of waste emulsions. The centrifuge feedstock varies significantly from site to site and often varies significantly during the daily operation. In this application, fuzzy logic was used on a class of problems not easily solved by classical control techniques. The oil field centrifuge is a highly nonlinear system, with a time varying input. We have been unable to develop a physical-mathematical model of the portion of the centrifuge operation that actually separates the oil, water, and solids. For this portion of the operation we developed a fuzzy feedback control system that modeled a skilled operator's knowledge and actions as opposed to the physical model of the centrifuge itself. Because of the variable feed we had to develop a feed-forward controller that would sense and react to feed changes prior to the time that the actual change reached the centrifuge separation unit. This portion of the control system was also a fuzzy controller designed around the knowledge of a skilled operator. In addition to the combined feed-forward and feedback control systems, we developed a soft-sensor that was used to determine the value of variables needed for the feed-forward control system. These variables could not actually be measured but were calculated from the measurement of other variables. The soft-sensor was developed with a combination of a physical model of the feed system and a skilled operator's expert knowledge. Finally the entire control system is tied together with a fuzzy-SPC (Statistical Process Control) filter, used to filter process and instrument noise and a fuzzy conflict resolution code used to keep the feed-forward and feedback control systems working well together.

  9. Scaling impacts on environmental controls and spatial heterogeneity of soil organic carbon stocks

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mishra, U.; Riley, W. J.

    2015-01-27

    The spatial heterogeneity of land surfaces affects energy, moisture, and greenhouse gas exchanges with the atmosphere. However, representing heterogeneity of terrestrial hydrological and biogeochemical processes in earth system models (ESMs) remains a critical scientific challenge. We report the impact of spatial scaling on environmental controls, spatial structure, and statistical properties of soil organic carbon (SOC) stocks across the US state of Alaska. We used soil profile observations and environmental factors such as topography, climate, land cover types, and surficial geology to predict the SOC stocks at a 50 m spatial scale. These spatially heterogeneous estimates provide a dataset with reasonablemore » fidelity to the observations at a sufficiently high resolution to examine the environmental controls on the spatial structure of SOC stocks. We upscaled both the predicted SOC stocks and environmental variables from finer to coarser spatial scales (s = 100, 200, 500 m, 1, 2, 5, 10 km) and generated various statistical properties of SOC stock estimates. We found different environmental factors to be statistically significant predictors at different spatial scales. Only elevation, temperature, potential evapotranspiration, and scrub land cover types were significant predictors at all scales. The strengths of control (the median value of geographically weighted regression coefficients) of these four environmental variables on SOC stocks decreased with increasing scale and were accurately represented using mathematical functions (R2 = 0.83–0.97). The spatial structure of SOC stocks across Alaska changed with spatial scale. Although the variance (sill) and unstructured variability (nugget) of the calculated variograms of SOC stocks decreased exponentially with scale, the correlation length (range) remained relatively constant across scale. The variance of predicted SOC stocks decreased with spatial scale over the range of 50 to ~ 500 m, and remained constant beyond this scale. The fitted exponential function accounted for 98% of variability in the variance of SOC stocks. We found moderately-accurate linear relationships between mean and higher-order moments of predicted SOC stocks (R2 ~ 0.55–0.63). Current ESMs operate at coarse spatial scales (50–100 km), and are therefore unable to represent environmental controllers and spatial heterogeneity of high-latitude SOC stocks consistent with observations. We conclude that improved understanding of the scaling behavior of environmental controls and statistical properties of SOC stocks can improve ESM land model benchmarking and perhaps allow representation of spatial heterogeneity of biogeochemistry at scales finer than those currently resolved by ESMs.« less

  10. Scaling impacts on environmental controls and spatial heterogeneity of soil organic carbon stocks

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mishra, U.; Riley, W. J.

    2015-07-02

    The spatial heterogeneity of land surfaces affects energy, moisture, and greenhouse gas exchanges with the atmosphere. However, representing the heterogeneity of terrestrial hydrological and biogeochemical processes in Earth system models (ESMs) remains a critical scientific challenge. We report the impact of spatial scaling on environmental controls, spatial structure, and statistical properties of soil organic carbon (SOC) stocks across the US state of Alaska. We used soil profile observations and environmental factors such as topography, climate, land cover types, and surficial geology to predict the SOC stocks at a 50 m spatial scale. These spatially heterogeneous estimates provide a data setmore » with reasonable fidelity to the observations at a sufficiently high resolution to examine the environmental controls on the spatial structure of SOC stocks. We upscaled both the predicted SOC stocks and environmental variables from finer to coarser spatial scales (s = 100, 200, and 500 m and 1, 2, 5, and 10 km) and generated various statistical properties of SOC stock estimates. We found different environmental factors to be statistically significant predictors at different spatial scales. Only elevation, temperature, potential evapotranspiration, and scrub land cover types were significant predictors at all scales. The strengths of control (the median value of geographically weighted regression coefficients) of these four environmental variables on SOC stocks decreased with increasing scale and were accurately represented using mathematical functions (R2 = 0.83–0.97). The spatial structure of SOC stocks across Alaska changed with spatial scale. Although the variance (sill) and unstructured variability (nugget) of the calculated variograms of SOC stocks decreased exponentially with scale, the correlation length (range) remained relatively constant across scale. The variance of predicted SOC stocks decreased with spatial scale over the range of 50 m to ~ 500 m, and remained constant beyond this scale. The fitted exponential function accounted for 98 % of variability in the variance of SOC stocks. We found moderately accurate linear relationships between mean and higher-order moments of predicted SOC stocks (R2 ∼ 0.55–0.63). Current ESMs operate at coarse spatial scales (50–100 km), and are therefore unable to represent environmental controllers and spatial heterogeneity of high-latitude SOC stocks consistent with observations. We conclude that improved understanding of the scaling behavior of environmental controls and statistical properties of SOC stocks could improve ESM land model benchmarking and perhaps allow representation of spatial heterogeneity of biogeochemistry at scales finer than those currently resolved by ESMs.« less

  11. Demonstration of a Piston Plug feed System for Feeding Coal/Biomass Mixtures across a Pressure Gradient for Application to a Commercial CBTL System

    SciTech Connect (OSTI)

    Santosh Gangwal

    2011-06-30

    Producing liquid transportation fuels and power via coal and biomass to liquids (CBTL) and integrated gasification combined cycle (IGCC) processes can significantly improve the nation's energy security. The Energy Independence and Security Act of 2007 mandates increasing renewable fuels nearly 10-fold to >2.3 million barrels per day by 2022. Coal is abundantly available and coal to liquids (CTL) plants can be deployed today, but they will not become sustainable without large scale CO{sub 2} capture and storage. Co-processing of coal and biomass in CBTL processes in a 60 to 40 ratio is an attractive option that has the potential to produce 4 million barrels of transportation fuels per day by 2020 at the same level of CO{sub 2} emission as petroleum. In this work, Southern Research Institute (Southern) has made an attempt to address one of the major barriers to the development of large scale CBTL processes - cost effective/reliable dry-feeding of coal-biomass mixtures into a high pressure vessel representative of commercial entrained-flow gasifiers. Present method for dry coal feeding involves the use of pressurized lock-hopper arrangements that are not only very expensive with large space requirements but also have not been proven for reliably feeding coal-biomass mixtures without the potential problems of segregation and bridging. The project involved the development of a pilot-scale 250 lb/h high pressure dry coal-biomass mixture feeder provided by TKEnergi and proven for feeding biomass at a scale up to 6 ton/day. The aim of this project is to demonstrate cost effective feeding of coal-biomass mixtures (50:50 to 70:30) made from a variety of coals (bituminous, lignite) and biomass (wood, corn stover, switch grass). The feeder uses a hydraulic piston-based approach to produce a series of plugs of the mixture that act as a seal against high back-pressure of the gasification vessel in to which the mixture is being fed. The plugs are then fed one by one via a plug breaker into the high pressure gasification vessel. A number of runs involving the feeding of coal and biomass mixtures containing 50 to 70 weight % coal into a high pressure gasification vessel simulator have shown that plugs of sufficient density can be formed to provide a seal against pressures up to 450 psig if homogeneity of the mixture can be maintained. However, the in-homogeneity of coal-biomass mixtures can occur during the mixing process because of density, particle size and moisture differences. Also, the much lower compressibility of coal as opposed to biomass can contribute to non-uniform plug formation which can result in weak plugs. Based on present information, the piston plug feeder offered marginal economic advantages over lock-hoppers. The results suggest a modification to the piston feeder that can potentially seal against pressure without the need for forming plugs. This modified design could result in lower power requirements and potentially better economics.

  12. Scoping Studies to Evaluate the Benefits of an Advanced Dry Feed System on the Use of Low-Rank Coal

    SciTech Connect (OSTI)

    Rader, Jeff; Aguilar, Kelly; Aldred, Derek; Chadwick, Ronald; Conchieri,; Dara, Satyadileep; Henson, Victor; Leininger, Tom; Liber, Pawel; Nakazono, Benito; Pan, Edward; Ramirez, Jennifer; Stevenson, John; Venkatraman, Vignesh

    2012-11-30

    This report describes the development of the design of an advanced dry feed system that was carried out under Task 4.0 of Cooperative Agreement DE-FE0007902 with the US DOE, “Scoping Studies to Evaluate the Benefits of an Advanced Dry Feed System on the use of Low- Rank Coal.” The resulting design will be used for the advanced technology IGCC case with 90% carbon capture for sequestration to be developed under Task 5.0 of the same agreement. The scope of work covered coal preparation and feeding up through the gasifier injector. Subcomponents have been broken down into feed preparation (including grinding and drying), low pressure conveyance, pressurization, high pressure conveyance, and injection. Pressurization of the coal feed is done using Posimetric1 Feeders sized for the application. In addition, a secondary feed system is described for preparing and feeding slag additive and recycle fines to the gasifier injector. This report includes information on the basis for the design, requirements for down selection of the key technologies used, the down selection methodology and the final, down selected design for the Posimetric Feed System, or PFS.

  13. Load requirements for maintaining structural integrity of Hanford single-shell tanks during waste feed delivery and retrieval activities

    SciTech Connect (OSTI)

    JULYK, L.J.

    1999-09-22

    This document provides structural load requirements and their basis for maintaining the structural integrity of the Hanford Single-Shell Tanks during waste feed delivery and retrieval activities. The requirements are based on a review of previous requirements and their basis documents as well as load histories with particular emphasis on the proposed lead transfer feed tanks for the privatized vitrification plant.

  14. Data quality objectives for TWRS privatization phase 1: confirm tank T is an appropriate feed source for low-activity waste feed batch X

    SciTech Connect (OSTI)

    NGUYEN, D.M.

    1999-06-01

    The US. Department of Energy, Richland Operations Office (DOE-RL) has initiated Phase 1 of a two-phase privatization strategy for treatment and immobilization of low-activity waste (LAW) currently being managed by the Hanford Tank Waste Remediation System (TWRS) Project. In this strategy, DOE will purchase services from a contractor-owned and operated facility under a fixed price. The Phase 1 TWRS privatization contract requires that the Project Hanford Management Contract (PHMC) contractors, on behalf of DOE, deliver LAW feed in specified quantities and composition to the Privatization Contractor in a timely manner (DOE-RL 1996). Additional requirements are imposed by the interface control document (ICD-19) for LAW feed (PHMC 1997). In response to these requirements, the Tank Waste Remediation System Operation and Utilization Plan (TWRSO and UP) (Kirkbride et al. 1997) was prepared by the PHMC. The TWRSO and UP, as updated by the Readiness-To-Proceed deliverable (Payne et al. 1998), establishes the baseline operating scenario for the delivery of LAW feed to the Privatization Contractor. The scenario specifies tanks from which LAW will be provided for each feed batch, the operational activities needed to prepare and deliver each batch, and the timing of these activities. The operating scenario was developed based on current knowledge of waste composition and chemistry, waste transfer methods, and operating constraints, such as tank farm logistics and availability of tank space. A project master baseline schedule (PMBS) has been developed to implement the operating scenario. The PMBS also includes activities aimed at reducing programmatic risks. One of the activities, ''Confirm Plans and Requirements,'' was identified to verify the basis used to develop the scenario. Additional data on waste quantity, physical and chemical characteristics, and transfer properties will be needed to support this activity. This document describes the data quality objective (DQO) process undertaken to assme appropriate data will be collected to support the activity, ''Confirm Tank Plans and Requirements.'' The DQO process was implemented in accordance with the TWRS DQO process (Banning 1997) with some modifications to accommodate project or tank-specific requirements and constraints.

  15. DOE Announces $160 Million for Biorefinery Construction and Highlights...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... strengthen education in math and science, and encourage entrepreneurship and innovation. ... John Shaw will deliver remarks at Sandia National Laboratory in Albuquerque, New Mexico. ...

  16. NREL Report Provides Documentation of the Advanced Biorefinery...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    national laboratories that conduct bioenergy research. ... Related Articles NREL Updates Survey of Advanced Biofuel ... Division exploring methods to pretreat biomass. | ...

  17. Pilot Integrated Cellulosic Biorefinery Operations to Fuel Ethanol

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Office(BETO) IBR Project Peer Review * 2015 ICM, Inc. All Rights Reserved. *1 Recovery ... All Rights Reserved. Project Relevance and Outcomes Demonstrate Fully Integrated ...

  18. 2011 Biomass Program Platform Peer Review: Integrated Biorefineries

    Energy Savers [EERE]

    Plaform Peer Review: Analysis 2011 Biomass Program Plaform Peer Review: Analysis This document summarizes the recommendations and evaluations provided by an independent external panel of experts at the U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Biomass Program's Analysis Platform Review meeting, held on April 4, 2011, at the Doubletree Hotel in Annapolis, Maryland. PDF icon 2011_analysis_review.pdf More Documents & Publications 2011 Biomass Program Platform

  19. Integrated Biorefinery for conversion of Biomass to Ethanol,...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    - St. Louis MO Subsidiary of Abengoa SA, Spain Ethanol facilities in Nebraska, Kansas, New Mexico, Illinois, Indiana, Spain, France, Netherlands and Brazil 2 Goal Statement ...

  20. Nanoparticle Technology for Biorefinery of Non-Food Source Feedstocks

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Upper right: Transmission electron microscope image of mesoporous silica nanoparticles sample. Lower right: The pilot plant for nanoparticle-catalyzed production of biodiesel. ...

  1. Pilot-Scale MixotrophicAlgae Integrated Biorefinery(IBR)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    short- and long-term job creation for construction, operators, biologists, chemists, ... Hydroprocessing 1 - PROJECT OVERVIEW * History: BioProcess Algae was formed in 2008 to ...

  2. Demonstration and Deployment Successes: Sapphire Integrated Algal Biorefinery

    Broader source: Energy.gov [DOE]

    Demonstration and Deployment Successes Jaime Moreno, Vice President of Projects, Sapphire Energy, Inc.

  3. Modeling Tomorrow's Biorefinery--the NREL Biochemical Pilot Plant

    SciTech Connect (OSTI)

    Not Available

    2008-03-01

    Brochure describing the capabilities of NREL's Biochemical Pilot Plant. In this facility, researchers test ideas for creating high-value products from cellulosic biomass.

  4. Pilot-Scale Biorefinery: Sustainable Transport Fuels from Biomass...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    coprocessing of pyrolysis oil (pyoil) in an FCC unit * Summer 2014, RTP unit restarted with plans to run UG1 at Kapolei and complete UG2 in UOP pilot plant in Des Plaines, IL * ...

  5. 2014 DOE Biomass Program Integrated Biorefinery Project Comprehensive...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Project Comprehensive Project Review Gerson Santos-Leon, Executive Vice President, Abengoa PDF icon santos-leonbiomass2014.pdf More Documents & Publications Abengoa IBR ...

  6. Second-Generation Biofuels from Multi-Product Biorefineries Combine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications 2015 Peer Review Presentations-Algal Feedstocks Algal Biofuels Strategy Workshop - Spring Event ATP3 Algae Testbed Public-Private Partnership

  7. NREL Biorefinery Analysis Process Models | Open Energy Information

    Open Energy Info (EERE)

    Tools Public Acceptability of Sustainable Transport Measures: A Review of the Literature Fuel Cell Economic Development Plan Hydrogen Roadmap Africa Infrastructure Country...

  8. EERE Energy Impacts: Biorefineries Give Local Farmers Opportunities...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bruce. Watch ... Bruce. Watch ...

  9. 2011 Biomass Program Platform Peer Review: Integrated Biorefineries...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    "This document summarizes the recommendations and evaluations provided by an independent external panel of experts at the U.S. Department of Energy Biomass Programs Integrated ...

  10. The National Bioenergy Center Laying the Foundation for Biorefineries

    SciTech Connect (OSTI)

    2005-08-01

    Advanced biomass conversion technology will play a major role in eliminating the need for imported oil and the generation of greenhouse gases from burning fossil fuels.

  11. DOE Announces up to $200 Million in Funding for Biorefineries...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    at ten percent of commercial scale that produce liquid transportation fuels such as ethanol, as well as bio-based chemicals and bioproducts used in industrial applications. ...

  12. Nanoparticle Technology for Biorefinery of Non-Food Source Feedstocks

    SciTech Connect (OSTI)

    Pruski, Marek; Trewyn, Brian; Lee, Young-Jin; Lin, Victor S.-Y.

    2013-01-22

    The goal of this proposed work is to develop and optimize the synthesis of mesoporous nanoparticle materials that are able to selectively sequester fatty acids from hexane extracts from algae, and to catalyze their transformation, as well as waste oils, into biodiesel. The project involves studies of the interactions between the functionalized MSN surface and the sequestering molecules. We investigate the mechanisms of selective extraction of fatty acids and conversion of triglycerides and fatty acids into biodiesel by the produced nanoparticles. This knowledge is used to further improve the properties of the mesoporous nanoparticle materials for both tasks. Furthermore, we investigate the strategies for scaling the synthesis of the catalytic nanomaterials up from the current pilot plant scale to industrial level, such that the biodiesel obtained with this technology can successfully compete with food crop-based biodiesel and petroleum diesel.

  13. 2011 Biomass Program Platform Peer Review. Integrated Biorefineries

    SciTech Connect (OSTI)

    Rossmeissl, Neil

    2012-02-01

    This document summarizes the recommendations and evaluations provided by an independent external panel of experts at the 2011 U.S. Department of Energy Biomass Program’s IBR Platform Review meeting.

  14. Industrial Membrane Filtration and Short-bed Fractal Separation Systems for Separating Monomers from Heterogeneous Plant Material

    SciTech Connect (OSTI)

    Kearney, M; Kochergin, V; Hess, R; Foust, T; Herbst, R; Mann, N

    2005-03-31

    Large-scale displacement of petroleum will come from low-cost cellulosic feedstocks such as straw and corn stover crop residues. This project has taken a step toward making this projection a reality by reducing capital and energy costs, the two largest cost factors associated with converting cellulosic biomass to chemicals and fuels. The technology exists for using acid or enzyme hydrolysis processes to convert biomass feedstock (i.e., waste cellulose such as straw, corn stover, and wood) into their base monomeric sugar building blocks, which can, in turn, be processed into chemicals and fuels using a number of innovative fermentation technologies. However, while these processes are technically possible, practical and economic barriers make these processes only marginally feasible or not feasible at all. These barriers are due in part to the complexity and large fixed and recurring capital costs of unit operations including filtration, chromatographic separation, and ion exchange. This project was designed to help remove these barriers by developing and implementing new purification and separation technologies that will reduce the capital costs of the purification and chromatographic separation units by 50% to 70%. The technologies fundamental to these improvements are: (a) highly efficient clarification and purification systems that use screening and membrane filtration to eliminate suspended solids and colloidal material from feed streams and (b) fractal technology based chromatographic separation and ion exchange systems that can substitute for conventional systems but at much smaller size and cost. A non-hazardous ''raw sugar beet juice'' stream (75 to 100 gal/min) was used for prototype testing of these technologies. This raw beet juice stream from the Amalgamated Sugar LLC plant in Twin Falls, Idaho contained abrasive materials and membrane foulants. Its characteristics were representative of an industrial-scale heterogeneous plant extract/hydrolysis stream, and therefore was an ideal model system for developing new separation equipment. Subsequent testing used both synthetic acid hydrolysate and corn stover derived weak acid hydrolysate (NREL produced). A two-phased approach was used for the research and development described in this project. The first level of study involved testing the new concepts at the bench level. The bench-scale evaluations provided fundamental understanding of the processes, building and testing small prototype systems, and determining the efficiency of the novel processes. The second level of study, macro-level, required building larger systems that directly simulated industrial operations and provided validation of performance to minimize financial risk during commercialization. The project goals and scope included: (1) Development of low-capital alternatives to conventional crop-based purification/separation processes; and (2) Development of each process to the point that transition to commercial operation is low risk. The project reporting period was January 2001 to December 2004. This included a one year extension of the project (without additional funding).

  15. Low-Activity Waste and High-Level Waste Feed Processing Data Quality Objectives

    SciTech Connect (OSTI)

    Patello, Gertrude K. ); Truex, Michael J. ); Wiemers, Karyn D.

    1999-04-15

    This document describes characterization needs for the DOE waste feed processing and disposal management of TWRS Privatization Phase I. The DOE must obtain information to evaluate and minimize risk associated with the private contractor's design phase deliverables (April 2000); authorization to proceed with Part B-2 (August 2000); and start of treatment facility construction (July 2001). Additionally, the DOE must ensure that the contract feed and product specifications are adequate and achievable, and that there is a sufficient basis for negotiating the price for. services. The purpose of this Data Quality Objective (DQO) is to provide data to accomplish the following: (1) update waste characterization information from source tanks to provide an independent assessment that the specifications and Interface Control Documents (ICDS) are adequate for DOE's management of the site M&I contractor and private contractor contracts; (2) provide preliminary information for the private contractor's process and facility designs and DOE's review of the designs in preparation for the authorization to proceed with Phase I Part B-2; (3) provide preliminary information for ILAW and IHLW storage and disposal design/specifications; (4) support update of the ILAW performance assessment (PA) for disposal; (5) help substantiate the ability to (1) comply with U.S. Nuclear Regulatory Commission (NRC) guidelines for incidental waste for LAW and (2) comply with the Office of Civilian Radioactive Waste Management (OCRWM) requirements for disposal of IHLW. The sampling and characterization implemented as a result of this DQO will be used for planning. As a result, a majority of the alternative actions fall into two major categories: either the DOE Privatization Contract is renegotiated or the process/facility designs are adjusted to accommodate increased capacity requirements, new technologies, additional waste stream volumes, etc. Impacts to the DOE are reduced when the need for these fallback positions are realized or eliminated early in the planning process. This DQO replaces earlier separate low-activity waste feed data quality objectives (Truex and Wiemers 1998) and high-level waste feed data quality objectives documents (Wiemers et,al. 1998). This combined DQO updates the data requirements based on the TWRS Privatization Contact issued August 1998 (DOE-RL 1998). Regulatory compliance for TWRS Privatization is addressed in a separate DQO (Wiemers et al. 1998). Additional characterization of the Phase I waste feed will be performed by DOE's contractors: the M&I contractor and the private contractor. Characterization for feed certification and waste acceptance will be completed before transfer of the feed to the private contractor facility. Characterization requirements for staged feed will be identified in other DQOS consistent with the Feed Certification Plans, ICDS 19 and 20, and applicable permits. Newly obtained analytical data and contract changes that have become available in parallel with or subsequent to preparation of this DQO update will be assessed and incorporated into the data needs optimization in the next revision of this DQO. Data available at the time of the tank waste sample request will be considered in the development of the Tank Sampling and Analysis Plan.

  16. Lattice Boltzmann simulation of immiscible fluid displacement in porous media: Homogeneous versus heterogeneous pore network

    SciTech Connect (OSTI)

    Liu, Haihu; Zhang, Yonghao; Valocchi, Albert J.

    2015-05-15

    Injection of anthropogenic carbon dioxide (CO{sub 2}) into geological formations is a promising approach to reduce greenhouse gas emissions into the atmosphere. Predicting the amount of CO{sub 2} that can be captured and its long-term storage stability in subsurface requires a fundamental understanding of multiphase displacement phenomena at the pore scale. In this paper, the lattice Boltzmann method is employed to simulate the immiscible displacement of a wetting fluid by a non-wetting one in two microfluidic flow cells, one with a homogeneous pore network and the other with a randomly heterogeneous pore network. We have identified three different displacement patterns, namely, stable displacement, capillary fingering, and viscous fingering, all of which are strongly dependent upon the capillary number (Ca), viscosity ratio (M), and the media heterogeneity. The non-wetting fluid saturation (S{sub nw}) is found to increase nearly linearly with logCa for each constant M. Increasing M (viscosity ratio of non-wetting fluid to wetting fluid) or decreasing the media heterogeneity can enhance the stability of the displacement process, resulting in an increase in S{sub nw}. In either pore networks, the specific interfacial length is linearly proportional to S{sub nw} during drainage with equal proportionality constant for all cases excluding those revealing considerable viscous fingering. Our numerical results confirm the previous experimental finding that the steady state specific interfacial length exhibits a linear dependence on S{sub nw} for either favorable (M ? 1) or unfavorable (M < 1) displacement, and the slope is slightly higher for the unfavorable displacement.

  17. Scale-up of miscible flood processes for heterogeneous reservoirs. Final report

    SciTech Connect (OSTI)

    Orr, F.M. Jr.

    1996-04-01

    Results of a wide-ranging investigation of the scaling of gas injection processes are reported. The research examines how the physical mechanisms at work during a gas injection project interact to determine process performance. In particular, the authors examine: the interactions of equilibrium phase behavior and two-phase flow that determine local displacement efficiency and minimum miscibility pressure, the combined effects of viscous fingering, gravity segregation and heterogeneity that control sweep efficiency in 2- and 3-dimensional porous media, the use of streamtube/streamline methods to create very efficient simulation technique for multiphase compositional displacements, the scaling of viscous, capillary and gravity forces for heterogeneous reservoirs, and the effects of the thin films and spreading behavior on three-phase flow. The following key results are documented: rigorous procedures for determination of minimum miscibility pressure (MMP) or minimum miscibility enrichment (MME) for miscibility have been developed for multicomponent systems; the complex dependence of MMP`s for nitrogen/methane floods on oil and injection gas composition observed experimentally is explained for the first time; the presence of layer-like heterogeneities strongly influences the interplay of gravity segregation and viscous fingering, as viscous fingers adapt to preferential flow paths and low permeability layers restrict vertical flow; streamtube/streamline simulation techniques are demonstrated for a variety of injection processes in 2 and 3 dimensions; quantitative scaling estimates for the transitions from capillary-dominated to gravity-dominated to viscous-dominated flows are reported; experimental results are given that demonstrate that high pressure CO{sub 2} can be used to generate low IFT gravity drainage in fractured reservoirs if fractures are suitably connected; and the effect of wetting and spreading behavior on three-phase flow is described. 209 refs.

  18. Heterogeneous ice nucleation and water uptake by field-collected atmospheric particles below 273 K

    SciTech Connect (OSTI)

    Wang, Bingbing; Laskin, Alexander; Roedel, Tobias R.; Gilles, Marry K.; Moffet, Ryan C.; Tivanski, Alexei V.; Knopf, Daniel A.

    2012-09-25

    Atmospheric ice formation induced by particles with complex chemical and physical properties through heterogeneous nucleation is not well understood. Heterogeneous ice nucleation and water uptake by ambient particles collected from urban environments in Los Angeles and Mexico City are presented. Using a vapour controlled cooling system equipped with an optical microscopy, the range of onset conditions for ice nucleation and water uptake by the collected particles was determined as a function of temperature (200{273 K) and relative humidity with respect to ice (RHice) up to water saturation. Three distinctly different types of authentic atmospheric particles were investigated including soot particles associated with organics/inorganics, inorganic particles of marine origin coated with organic material, and Pb/Zn containing inorganic particles apportioned to anthropogenic emissions relevant to waste incineration. Single particle characterization was provided by micro-spectroscopic analyses using computer controlled scanning electron microscopy with energy dispersive analysis of X-rays (CCSEM/EDX) and scanning transmission X-ray microscopy with near edge X-ray absorption ne structure spectroscopy (STXM/NEXAFS). Above 230 K, signicant differences in water uptake and immersion freezing effciencies of the different particle types were observed. Below 230 K, the particles exhibited high deposition ice nucleation effciencies and formed ice at RHice values well below homogeneous ice nucleation limits. The data show that the chemical composition of these eld{collected particles plays an important role in determining water uptake and immersion freezing. Heterogeneous ice nucleation rate coeffcients, cumulative ice nuclei (IN) spectrum, and IN activated fraction for deposition ice nucleation are derived. The presented ice nucleation data demonstrate that anthropogenic and marine particles comprising of various chemical and physical properties exhibit distinctly different ice nucleation effciencies and can serve as effcient IN at atmospheric conditions typical for cirrus and mixed phase clouds. This indicates a potential link between human activities and cloud formation, and thus climate.

  19. Effect of heterogeneous aqueous reactions on the secondary formation of inorganic aerosols during haze events

    SciTech Connect (OSTI)

    Quan, Jiannong; Liu, Yangang; Liu, Quan; Li, Xia; Gao, Yang; Jia, Xingcan; Sheng, Jiujiang

    2015-09-30

    In this study, the effect of heterogeneous aqueous reactions on the secondary formation of inorganic aerosols during haze events was investigated by analysis of comprehensive measurements of aerosol composition and concentrations [e.g., particular matters (PM2.5), nitrate (NO3), sulfate (SO4), ammonium (NH4)], gas-phase precursors [e.g., nitrogen oxides (NOx), sulfur dioxide (SO2), and ozone (O3)], and relevant meteorological parameters [e.g., visibility and relative humidity (RH)]. The measurements were conducted in Beijing, China from Sep. 07, 2012 to Jan. 16, 2013. The results show that the conversion ratios of N from NOx to nitrate (Nratio) and S from SO2 to sulfate (Sratio) both significantly increased in haze events, suggesting enhanced conversions from NOx and SO2 to their corresponding particle phases in the late haze period. Further analysis shows that Nratio and Sratio increased with increasing RH, with Nratio and Sratio being only 0.04 and 0.03, respectively, when RH < 40%, and increasing up to 0.16 and 0.12 when RH reached 60–80%, respectively. The enhanced conversion ratios of N and S in the late haze period is likely due to heterogeneous aqueous reactions, because solar radiation and thus the photochemical capacity are reduced by the increases in aerosols and RH. This point was further affirmed by the relationships of Nratio and Sratio to O3: the conversion ratios increase with decreasing O3 concentration when O3 concentration is lower than <15 ppb but increased with increasing O3 when O3 concentration is higher than 15 ppb. The results suggest that heterogeneous aqueous reactions likely changed aerosols and their precursors during the haze events: in the beginning of haze events, the precursor gases accumulated quickly due to high emission and low reaction rate; the occurrence of heterogeneous aqueous reactions in the late haze period, together with the accumulated high concentrations of precursor gases such as SO2 and NOx, accelerated the formation of secondary inorganic aerosols, and led to rapid increase of the PM2.5 concentration.

  20. Heterogeneous catalyst for the production of ethylidene diacetate from acetic anhydride

    DOE Patents [OSTI]

    Ramprasad, D.; Waller, F.J.

    1998-06-16

    This invention relates to a process for producing ethylidene diacetate by the reaction of acetic anhydride, acetic acid, hydrogen and carbon monoxide at elevated temperatures and pressures in the presence of an alkyl halide and a heterogeneous, bifunctional catalyst that is stable to hydrogenation and comprises an insoluble polymer having pendant quaternized heteroatoms, some of which heteroatoms are ionically bonded to anionic Group VIII metal complexes, the remainder of the heteroatoms being bonded to iodide. In contrast to prior art processes, no accelerator (promoter) is necessary to achieve the catalytic reaction and the products are easily separated from the catalyst by filtration. The catalyst can be recycled without loss in activity.