National Library of Energy BETA

Sample records for heavy oil deposits

  1. Process for converting heavy oil deposited on coal to distillable oil in a low severity process

    DOE Patents [OSTI]

    Ignasiak, Teresa; Strausz, Otto; Ignasiak, Boleslaw; Janiak, Jerzy; Pawlak, Wanda; Szymocha, Kazimierz; Turak, Ali A.

    1994-01-01

    A process for removing oil from coal fines that have been agglomerated or blended with heavy oil comprises the steps of heating the coal fines to temperatures over 350.degree. C. up to 450.degree. C. in an inert atmosphere, such as steam or nitrogen, to convert some of the heavy oil to lighter, and distilling and collecting the lighter oils. The pressure at which the process is carried out can be from atmospheric to 100 atmospheres. A hydrogen donor can be added to the oil prior to deposition on the coal surface to increase the yield of distillable oil.

  2. China shows increasing interest in heavy oil and oil sands

    SciTech Connect (OSTI)

    Not Available

    1986-12-01

    China and Canadian and US groups are cooperating in several areas to develop the heavy oil, asphalt, and oil sand deposits of China. The agreements dealing with exploration and upgrading are briefly described. The majority of the paper describes the occurrences of heavy oil, asphalt, and oil sands in China. 1 figure.

  3. Upgrading heavy gas oils

    SciTech Connect (OSTI)

    Ferguson, S.; Reese, D.D.

    1986-05-20

    A method is described of neutralizing the organic acidity in heavy gas oils to produce a neutralization number less than 1.0 whereby they are rendered suitable as lube oil feed stocks which consists essentially of treating the heavy gas oils with a neutralizing amount of monoethanolamine to form an amine salt with the organic acids and then heating the thus-neutralized heavy gas oil at a temperature at least about 25/sup 0/F greater than the boiling point of water and for a time sufficient to convert the amine salts to amides.

  4. Utah Heavy Oil Program

    SciTech Connect (OSTI)

    J. Bauman; S. Burian; M. Deo; E. Eddings; R. Gani; R. Goel; C.K. Huang; M. Hogue; R. Keiter; L. Li; J. Ruple; T. Ring; P. Rose; M. Skliar; P.J. Smith; J.P. Spinti; P. Tiwari; J. Wilkey; K. Uchitel

    2009-10-20

    The Utah Heavy Oil Program (UHOP) was established in June 2006 to provide multidisciplinary research support to federal and state constituents for addressing the wide-ranging issues surrounding the creation of an industry for unconventional oil production in the United States. Additionally, UHOP was to serve as an on-going source of unbiased information to the nation surrounding technical, economic, legal and environmental aspects of developing heavy oil, oil sands, and oil shale resources. UHOP fulGilled its role by completing three tasks. First, in response to the Energy Policy Act of 2005 Section 369(p), UHOP published an update report to the 1987 technical and economic assessment of domestic heavy oil resources that was prepared by the Interstate Oil and Gas Compact Commission. The UHOP report, entitled 'A Technical, Economic, and Legal Assessment of North American Heavy Oil, Oil Sands, and Oil Shale Resources' was published in electronic and hard copy form in October 2007. Second, UHOP developed of a comprehensive, publicly accessible online repository of unconventional oil resources in North America based on the DSpace software platform. An interactive map was also developed as a source of geospatial information and as a means to interact with the repository from a geospatial setting. All documents uploaded to the repository are fully searchable by author, title, and keywords. Third, UHOP sponsored Give research projects related to unconventional fuels development. Two projects looked at issues associated with oil shale production, including oil shale pyrolysis kinetics, resource heterogeneity, and reservoir simulation. One project evaluated in situ production from Utah oil sands. Another project focused on water availability and produced water treatments. The last project considered commercial oil shale leasing from a policy, environmental, and economic perspective.

  5. Process for upgrading heavy oils

    SciTech Connect (OSTI)

    LePage, J.F.; Marlino, G.

    1983-07-05

    The viscosity of heavy oils is reduced in order to facilitate pipe line transportation thereof. A fraction of the heavy oil is deasphalted in the presence of C/sub 5/-C/sub 7/ hydrocarbons, a portion of the separated asphalt is converted to synthesis gas, at least a portion of said gas is used to manufacture an alcohol mixture including methanol and C/sub 2/ to C/sub 10/ alcohols, which mixture is admixed with the heavy oil before transportation thereof. This procedure is more beneficial to the transported heavy oil than the prior processes which do not comprise the conversion of the asphalt fraction of the heavy oil.

  6. Retrofitting heavy oil processes

    SciTech Connect (OSTI)

    Hamilton, G.L.; Fitzgerald, M.; D'Amico, V.

    1986-01-01

    Refiners, faced with the need to process the bottom end of the heavy high sulfur crude oil barrel in today's uncertain economic environment, are reluctant to commit large amounts of money to expensive upgrading processes. In order to conserve scarce capital while improving operating margins, additional valuable products can be produced by retrofits such as conversion of an idle crude unit to visbreaking, delayed coking or deasphalting service, or conversion of hydrodesulfurizers to mild hydrocracking.

  7. Pipeline transportation of heavy crude oil

    SciTech Connect (OSTI)

    Kessick, M.A.; St. Denis, C.E.

    1982-08-10

    Heavy crude oils are transported by pipeline from deposit location to a remote upgrading location by emulsifying the crude oil using deaerated sodium hydroxide solution, conveying the oilin-water emulsion through the pipeline, and recovery of the oil from the oil-in-water emulsion by inverting the emulsion and dewatering the resulting water-in-oil emulsion. The emulsion inversion may be effected using slaked lime, resulting in recovery of a substantial proportion of the sodium hydroxide used in the initial emulsification. The sodium hydroxide solution may be recycled by a separate pipeline for reuse or treated for discharge.

  8. Conversion of heavy hydrocarbon oils

    SciTech Connect (OSTI)

    Chen, N.Y.; Pelrine, B.P.; Yan, T.Y.

    1982-12-14

    This invention provides a process for upgrading a heavy hydrocarbon oil to motor fuel products. The heavy hydrocarbon oil is admixed with a metal halide catalyst and a solvent component under supercritical conditions to form (1) a dense-gas solvent phase which contains refined hydrocarbon crackate, and which is substantially free of metal halide catalyst content; and (2) a residual asphaltic phase.

  9. Heavy oil transportation by pipeline

    SciTech Connect (OSTI)

    Gerez, J.M.; Pick, A.R.

    1996-12-31

    Worldwide there are a number of pipelines used to transport heavy crude oils. The operations are facilitated in a variety of ways. For example, the Alyeska pipeline is an insulated pipeline transporting warm oil over 800 miles. This 48-inch line experiences limited heat loss due to the insulation, volume of oil contained, and heat gain due to friction and pumping. Some European trunk lines periodically handle heavy and waxy crudes. This is achieved by proper sizing of batches, following waxy crudes with non-waxy crudes, and increased use of scrapers. In a former Soviet republic, the transportation of heavy crude oil by pipeline has been facilitated by blending with a lighter Siberian crude. The paper describes the pipeline transport of heavy crudes by Interprovincial Pipe Line Inc. The paper describes enhancing heavy oil transportation by emulsion formation, droplet suspension, dilution, drag reducing agents, and heating.

  10. Advances in heavy oil hydroprocessing

    SciTech Connect (OSTI)

    Mendizabal, O.B. )

    1988-06-01

    The world increase in heavy crudes has forced refiners to develop different processes that upgrade the yields and product properties recovered from these crudes. However, some of the optimized and new processes are not able to handle whole heavy crude oils, due to the high viscosity and corrosion of their long and short residues. The different processes for heavy crudes can be classified in two areas: physical (vg. Liquid Extraction) and chemical processes. The catalytic hydrotreating process, which belongs to this last classification, has demonstrated to be an economical upgrading process for heavy crude oil. This paper describes the development by the Mexican Petroleum Institute of the process to hydrotreat maya heavy crude. The effect of the operating conditions, the catalyst ---- development and the technical - economical analysis are presented. The product properties and yields are compared with the results obtained with light crude oil like isthmus.

  11. Process for removing heavy metal compounds from heavy crude oil

    DOE Patents [OSTI]

    Cha, Chang Y.; Boysen, John E.; Branthaver, Jan F.

    1991-01-01

    A process is provided for removing heavy metal compounds from heavy crude oil by mixing the heavy crude oil with tar sand; preheating the mixture to a temperature of about 650.degree. F.; heating said mixture to up to 800.degree. F.; and separating tar sand from the light oils formed during said heating. The heavy metals removed from the heavy oils can be recovered from the spent sand for other uses.

  12. Upgrading Orinoco belt heavy oil

    SciTech Connect (OSTI)

    Alcantara, J.; Castillo, O.

    1982-09-01

    The Orinoco Heavy Oil Belt of Venezuela is a subsurface geological formation of petroleum-bearing sands that is approximately 700 km long and between 60 and 80 km wide. The results of recent explorations have shown the area to contain over one trillion barrels of oil in-place, ranging from 8/sup 0/ API to 14/sup 0/ APE gravity. In an effort to develop these resources, Petroleos de Venezuela has undertaken a program to evaluate and develop this heavy oil belt. The objectives of this program are discussed along with the process technology selection, pilot plants, and environmental protection measures. (JMT)

  13. Fire flood recovery process effects upon heavy oil properties

    SciTech Connect (OSTI)

    Reichert, C.; Fuhr, B.; Sawatzky, H.; Lefleur, R.; Verkoczy, B.; Soveran, D.; Jha, K.

    1988-06-01

    The steady decline in proven conventional oil deposits world wide has increased the emphasis on the use of heavy oil and bitumen. Most of the heavy oil and oil sand deposits share the common problem of providing very little or no primary production. They require a reduction in viscosity of the oil to make it flow. The oil in place and the reservoir characteristics are generally studied carefully to determine the design of the recovery process most applicable to the deposit and to evaluate its potential. Many of these same characteristics are also used to evaluate the oil with respect to upgrading, refining and final usage in the form of products. A variety of processes have been developed most of which utilize heat either in the form of steam or combustion to mobolize the oil in the reservoir. These processes vary considerably from rather mild conditions for steam stimulation to quite severe for combustion recovery. Figure 1 shows a typical schematic of an insitu combustion process. Many variations of forward combustion are used in the field to produce oil. Depending upon the severity of the recovery process in the recovered oil may be similar to the oil in the deposit or may be highly modified (oxidized, polymerized or upgraded). A memorandum of Understanding was signed by the Governments of the United States of America, Canada and the Provinces of Saskatchewan and Alberta to study different aspects of the problems related to the recovery of oil from heavy oil and sand deposits. One phase of the study is to determine the effects of different methods of in-situ recovery on the composition of recovered bitumen and heavy oils. This paper describes the findings from a study of fireflood process in a heavy oil deposit located in the Cummings formation of the Eyehill Field in Saskatchewan, Canada.

  14. Heavy oil expansions gather momentum worldwide

    SciTech Connect (OSTI)

    Moritis, G.

    1995-08-14

    Cold production, wormholes, foamy oil mechanism, improvements in thermal methods, and horizontal wells are some of the processes and technologies enabling expansion of the world`s heavy oil/bitumen production. Such processes were the focus of the International Heavy Oil Symposium in Calgary, June 19--21. Unlike conventional oil production, heavy oil/bitumen extraction is more a manufacturing process where technology enables the business and does not just add value. The current low price spreads between heavy oil/light oil indicate that demand for heavy oil is high. The paper first discusses the price difference between heavy and light oils, then describes heavy oil production activities in Canada at Cold Lake, in Venezuela in the Orinoco belt, and at Kern River in California.

  15. Reactive plasma upgrade of squalane - a heavy oil simulant

    SciTech Connect (OSTI)

    Kong, P.C.; Watkins, A.D.; Detering, B.A.; Thomas, C.P.

    1995-10-01

    U.S. light crude oil production has steadily declined over the last two decades. However, huge known heavy oil deposits in the North American continent remain largely untapped. In the past 10 years, the API gravity of crude oils has been decreasing by about 0.17% per year, and the sulfur content has been increasing by about 0.027% per year. As the API gravity of crude oil decreases, there will be an urgent need for economically viable new technologies to upgrade the heavy oil to a high API gravity feed stock for the refineries. The Idaho National Engineering Laboratory is investigating an innovative plasma process to upgrade heavy oil and refinery residuum. This paper will present some of the results and the implications of this technology for heavy oil upgrade and conversion.

  16. Reactive plasma upgrade of squalane - a heavy oil simulant

    SciTech Connect (OSTI)

    Kong, P.C.; Watkins, A.D.; Detering, B.A.

    1995-07-01

    U.S. light crude oil production has steadily declined over the last two decades. However, huge known heavy oil deposits in the North American continent remain largely untapped. In the past 10 years, the API gravity of crude oils has been decreasing by about 0.17% per year, and the sulfur content has been increasing by about 0.027% per year. As the API gravity of crude oil decreases, there will be an urgent need for economically viable new technologies to ungrade the heavy oil to a high API gravity feed stock for the refineries. The Idaho National Engineering Laboratory is investigating an innovative plasma process to upgrade heavy oil and refinery residuum. This paper will present some of the results and the implications of this technology for heavy oil upgrade and conversion.

  17. heavy_oil | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heavy Oil Heavy oil is a vast U.S. oil resource that is underexploited because its highly viscous nature renders it difficult to produce and to refine. As higher-gravity crudes (lighter oil) become increasingly scarce in the U.S., American operators are looking more and more to low-gravity crudes (heavy oil) to prop up the Nation's declining oil output. Heavy oil generally is defined as having an API (American Petroleum Institute) gravity of 10-20 degrees. Oil sources with even lower gravities,

  18. Upgrading Orinoco Belt heavy oil

    SciTech Connect (OSTI)

    Aliantara, J.; Castillo, O.

    1982-05-01

    Petroleos de Venezuela, S.A. (PDVSA), in an effort to develop new oil resources, has undertaken a program to evaluate and develop the Orinoco Heavy Oil Belt, in the eastern part of Venezuela. Lagoven, S.A., a subsidiary of PDVSA, has been assigned the responsibility for developing and upgrading part of the Orinoco belt. This paper describes the most relevant aspects of Lagoven's first upgrading module, a facility that will convert Orinoco oil into a premium crude with a very high yield of products of great market demand.

  19. Impact and future of heavy oil produciton

    SciTech Connect (OSTI)

    Olsen, D.K, )

    1996-01-01

    Heavy oil resources are becoming increaingly important in meeting world oil demand. Heavy oil accounts for 10% of the worlds current oil production and is anticipated to grow significantly. Recent narrowing of the price margins between light and heavy oil and the development of regional heavy oil markets (production, refining and marketing) have prompted renewed investment in heavy oil. Production of well known heavy oil resources of Canada, Venezuela, United States, and elsewhere throughout the world will be expanded on a project-by-project basis. Custom refineries designed to process these heavy crudes are being expanded. Refined products from these crudes will be cleaner than ever before because of the huge investment. However, heavy oil still remains at a competitive disadvantage due to higher production, transportation and refining have to compete with other investment opportunities available in the industry. Expansion of the U.S. heavy oil industry is no exception. Relaxation of export restrictions on Alaskan North Slope crude has prompted renewed development of California's heavy oil resources. The location, resource volume, and oil properties of the more than 80-billion barrel U.S. heavy oil resource are well known. Our recent studies summarize the constraints on production, define the anticipated impact (volume, location and time frame) of development of U.S. heavy oil resources, and examines the $7-billion investment in refining units (bottoms conversion capacity) required to accommodate increased U.S. heavy oil production. Expansion of Canadian and Venezuelan heavy oil and tar sands production are anticipated to dramatically impact the U.S. petroleum market while displacing some imported Mideast crude.

  20. Impact and future of heavy oil produciton

    SciTech Connect (OSTI)

    Olsen, D.K,

    1996-12-31

    Heavy oil resources are becoming increaingly important in meeting world oil demand. Heavy oil accounts for 10% of the worlds current oil production and is anticipated to grow significantly. Recent narrowing of the price margins between light and heavy oil and the development of regional heavy oil markets (production, refining and marketing) have prompted renewed investment in heavy oil. Production of well known heavy oil resources of Canada, Venezuela, United States, and elsewhere throughout the world will be expanded on a project-by-project basis. Custom refineries designed to process these heavy crudes are being expanded. Refined products from these crudes will be cleaner than ever before because of the huge investment. However, heavy oil still remains at a competitive disadvantage due to higher production, transportation and refining have to compete with other investment opportunities available in the industry. Expansion of the U.S. heavy oil industry is no exception. Relaxation of export restrictions on Alaskan North Slope crude has prompted renewed development of California`s heavy oil resources. The location, resource volume, and oil properties of the more than 80-billion barrel U.S. heavy oil resource are well known. Our recent studies summarize the constraints on production, define the anticipated impact (volume, location and time frame) of development of U.S. heavy oil resources, and examines the $7-billion investment in refining units (bottoms conversion capacity) required to accommodate increased U.S. heavy oil production. Expansion of Canadian and Venezuelan heavy oil and tar sands production are anticipated to dramatically impact the U.S. petroleum market while displacing some imported Mideast crude.

  1. heavy_oil | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Much of America's heavy oil is produced via a costly steam injection enhanced oil recovery (EOR) method to produce a crude oil grade that is lower in quality and thus sells for ...

  2. Water issues associated with heavy oil production.

    SciTech Connect (OSTI)

    Veil, J. A.; Quinn, J. J.; Environmental Science Division

    2008-11-28

    Crude oil occurs in many different forms throughout the world. An important characteristic of crude oil that affects the ease with which it can be produced is its density and viscosity. Lighter crude oil typically can be produced more easily and at lower cost than heavier crude oil. Historically, much of the nation's oil supply came from domestic or international light or medium crude oil sources. California's extensive heavy oil production for more than a century is a notable exception. Oil and gas companies are actively looking toward heavier crude oil sources to help meet demands and to take advantage of large heavy oil reserves located in North and South America. Heavy oil includes very viscous oil resources like those found in some fields in California and Venezuela, oil shale, and tar sands (called oil sands in Canada). These are described in more detail in the next chapter. Water is integrally associated with conventional oil production. Produced water is the largest byproduct associated with oil production. The cost of managing large volumes of produced water is an important component of the overall cost of producing oil. Most mature oil fields rely on injected water to maintain formation pressure during production. The processes involved with heavy oil production often require external water supplies for steam generation, washing, and other steps. While some heavy oil processes generate produced water, others generate different types of industrial wastewater. Management and disposition of the wastewater presents challenges and costs for the operators. This report describes water requirements relating to heavy oil production and potential sources for that water. The report also describes how water is used and the resulting water quality impacts associated with heavy oil production.

  3. Design of heavy oil upgrading units

    SciTech Connect (OSTI)

    Farrell, W.D.; Phodes, R.P.; Zeno, D.Y.

    1985-01-01

    Heavy oil upgrading has become an increasingly important aspect of ER and E's research. Due to high costs of experimental catalysts, small catalyst charges are used (20-150cc). Tubular design and tree-stage stirred design are discussed with emphasis on the techniques and equipment used to handle heavy oil. Mechanical design and fluid mechanics are discussed.

  4. Heavy oil catalytic cracking process and apparatus (Patent) ...

    Office of Scientific and Technical Information (OSTI)

    Heavy oil catalytic cracking process and apparatus Citation Details In-Document Search Title: Heavy oil catalytic cracking process and apparatus This paper describes a fluidized ...

  5. EXPERIMENTAL AND THEORETICAL DETERMINATION OF HEAVY OIL VISCOSITY...

    Office of Scientific and Technical Information (OSTI)

    OF HEAVY OIL VISCOSITY UNDER RESERVOIR CONDITIONS Citation Details In-Document Search Title: EXPERIMENTAL AND THEORETICAL DETERMINATION OF HEAVY OIL VISCOSITY UNDER ...

  6. Feasibility study of heavy oil recovery in the Appalachian, Black Warrior, Illinois, and Michigan basins

    SciTech Connect (OSTI)

    Olsen, D.K.; Rawn-Schatzinger, V.; Ramzel, E.B.

    1992-07-01

    This report is one of a series of publications assessing the feasibility of increasing domestic heavy oil production. Each report covers select areas of the United States. The Appalachian, Black Warrior, Illinois, and Michigan basins cover most of the depositional basins in the Midwest and Eastern United States. These basins produce sweet, paraffinic light oil and are considered minor heavy oil (10{degrees} to 20{degrees} API gravity or 100 to 100,000 cP viscosity) producers. Heavy oil occurs in both carbonate and sandstone reservoirs of Paleozoic Age along the perimeters of the basins in the same sediments where light oil occurs. The oil is heavy because escape of light ends, water washing of the oil, and biodegradation of the oil have occurred over million of years. The Appalachian, Black Warrior, Illinois, and Michigan basins` heavy oil fields have produced some 450,000 bbl of heavy oil of an estimated 14,000,000 bbl originally in place. The basins have been long-term, major light-oil-producing areas and are served by an extensive pipeline network connected to refineries designed to process light sweet and with few exceptions limited volumes of sour or heavy crude oils. Since the light oil is principally paraffinic, it commands a higher price than the asphaltic heavy crude oils of California. The heavy oil that is refined in the Midwest and Eastern US is imported and refined at select refineries. Imports of crude of all grades accounts for 37 to >95% of the oil refined in these areas. Because of the nature of the resource, the Appalachian, Black Warrior, Illinois and Michigan basins are not expected to become major heavy oil producing areas. The crude oil collection system will continue to degrade as light oil production declines. The demand for crude oil will increase pipeline and tanker transport of imported crude to select large refineries to meet the areas` liquid fuels needs.

  7. Feasibility study of heavy oil recovery in the Appalachian, Black Warrior, Illinois, and Michigan basins

    SciTech Connect (OSTI)

    Olsen, D.K.; Rawn-Schatzinger, V.; Ramzel, E.B.

    1992-07-01

    This report is one of a series of publications assessing the feasibility of increasing domestic heavy oil production. Each report covers select areas of the United States. The Appalachian, Black Warrior, Illinois, and Michigan basins cover most of the depositional basins in the Midwest and Eastern United States. These basins produce sweet, paraffinic light oil and are considered minor heavy oil (10{degrees} to 20{degrees} API gravity or 100 to 100,000 cP viscosity) producers. Heavy oil occurs in both carbonate and sandstone reservoirs of Paleozoic Age along the perimeters of the basins in the same sediments where light oil occurs. The oil is heavy because escape of light ends, water washing of the oil, and biodegradation of the oil have occurred over million of years. The Appalachian, Black Warrior, Illinois, and Michigan basins' heavy oil fields have produced some 450,000 bbl of heavy oil of an estimated 14,000,000 bbl originally in place. The basins have been long-term, major light-oil-producing areas and are served by an extensive pipeline network connected to refineries designed to process light sweet and with few exceptions limited volumes of sour or heavy crude oils. Since the light oil is principally paraffinic, it commands a higher price than the asphaltic heavy crude oils of California. The heavy oil that is refined in the Midwest and Eastern US is imported and refined at select refineries. Imports of crude of all grades accounts for 37 to >95% of the oil refined in these areas. Because of the nature of the resource, the Appalachian, Black Warrior, Illinois and Michigan basins are not expected to become major heavy oil producing areas. The crude oil collection system will continue to degrade as light oil production declines. The demand for crude oil will increase pipeline and tanker transport of imported crude to select large refineries to meet the areas' liquid fuels needs.

  8. Upgrading petroleum residues and heavy oils

    SciTech Connect (OSTI)

    Gray, M.R.

    1994-01-01

    Here is an in-depth look at current techniques for converting heavy oils and residues into more valuable distillates. It examines the chemistry of heavy hydrocarbon feeds and their properties which are important to engineering design, including phase behavior, reaction kinetics, and thermodynamic and transport characteristics.

  9. The microbial upgrading of model heavy oils

    SciTech Connect (OSTI)

    Webster, I.A.; Patras, L.E. )

    1988-01-01

    The authors have isolated bacteria and used them to catalyze the removal of sulfur, nitrogen and nickel from model heavy oils and asphaltenes. Their paper will discuss their activity and reactor concepts. The concept of a membrane bioreactor for oil processing is introduced.

  10. Assessment of heavy oil conversion

    SciTech Connect (OSTI)

    Gleim, W.T.K.

    1983-08-01

    Removal of benzene insoluble asphaltene components greatly facilitates and improves the subsequent upgrading of residual oils, the desulfurization in particular. For the upgrading of Venezualean oils, the Aurobon process is still the only feasible solution.

  11. Fluvial-deltaic heavy oil reservoir, San Joaquin basin

    SciTech Connect (OSTI)

    Miller, D.D.; McPherson, J.G.; Covington, T.E.

    1989-03-01

    Unconsolidated arkosic sands deposited in a fluvial-deltaic geologic setting comprise the heavy oil (13/degree/ API gravity) reservoir at South Belridge field. The field is located along the western side of the San Joaquin basin in Kern County, California. More than 6000 closely spaced and shallow wells are the key to producing the estimated 1 billion bbl of ultimate recoverable oil production. Thousands of layered and laterally discontinuous reservoir sands produce from the Pleistocene Tulare Formation. The small scale of reservoir geometries is exploited by a high well density, required for optimal heavy oil production. Wells are typically spaced 200-500 ft (66-164 m) apart and drilled to 1000 ft (328 m) deep in the 14-mi/sup 2/ (36-km/sup 2/) producing area. Successful in-situ combustion, cyclic steaming, and steamflood projects have benefited from the shallow-depth, thick, layered sands, which exhibit excellent reservoir quality. The fundamental criterion for finding another South Belridge field is to realize the extraordinary development potential of shallow, heavy oil reservoirs, even when an unspectacular discovery well is drilled. The trap is a combination of structural and stratigraphic mechanisms plus influence from unconventional fluid-level and tar-seal traps. The depositional model is interpreted as a braid delta sequence that prograded from the nearby basin-margin highlands. A detailed fluvial-deltaic sedimentologic model establishes close correlation between depositional lithofacies, reservoir geometries, reservoir quality, and heavy oil producibility. Typical porosity is 35% and permeability is 3000 md.

  12. Kinetics of heavy oil/coal coprocessing

    SciTech Connect (OSTI)

    Szladow, A.J.; Chan, R.K.; Fouda, S.; Kelly, J.F. )

    1988-01-01

    A number of studies have been reported on coprocessing of coal and oil sand bitumen, petroleum residues and distillate fractions in catalytic and non-catalytic processes. The studies described the effects of feedstock characteristics, process chemistry and operating variables on the product yield and distribution; however, very few kinetic data were reported in these investigations. This paper presents the kinetic data and modeling of the CANMET coal/heavy oil coprocessing process. A number of reaction networks were evaluated for CANMET coprocessing. The final choice of model was a parallel model with some sequential characteristics. The model explained 90.0 percent of the total variance, which was considered satisfactory in view of the difficulties of modeling preasphaltenes. The models which were evaluated showed that the kinetic approach successfully applied to coal liquefaction and heavy oil upgrading can be also applied to coprocessing. The coal conversion networks and heavy oil upgrading networks are interrelated via the forward reaction paths of preasphaltenes, asphaltenes, and THFI and via the reverse kinetic paths of an adduct formation between preasphaltenes and heavy oil.

  13. RESEARCH OIL RECOVERY MECHANISMS IN HEAVY OIL RESERVOIRS

    SciTech Connect (OSTI)

    Anthony R. Kovscek; William E. Brigham

    1999-06-01

    The United States continues to rely heavily on petroleum fossil fuels as a primary energy source, while domestic reserves dwindle. However, so-called heavy oil (10 to 20{sup o}API) remains an underutilized resource of tremendous potential. Heavy oils are much more viscous than conventional oils. As a result, they are difficult to produce with conventional recovery methods such as pressure depletion and water injection. Thermal recovery is especially important for this class of reservoirs because adding heat, usually via steam injection, generally reduces oil viscosity dramatically. This improves displacement efficiency. The research described here was directed toward improved understanding of thermal and heavy-oil production mechanisms and is categorized into: (1) flow and rock properties; (2) in-situ combustion; (3) additives to improve mobility control; (4) reservoir definition; and (5) support services. The scope of activities extended over a three-year period. Significant work was accomplished in the area of flow properties of steam, water, and oil in consolidated and unconsolidated porous media, transport in fractured porous media, foam generation and flow in homogeneous and heterogeneous porous media, the effects of displacement pattern geometry and mobility ratio on oil recovery, and analytical representation of water influx. Significant results are described.

  14. Geothermal and heavy-oil resources in Texas (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    Geothermal and heavy-oil resources in Texas Citation Details In-Document Search Title: Geothermal and heavy-oil resources in Texas You are accessing a document from the ...

  15. Process for upgrading heavy hydrocarbonaceous oils

    SciTech Connect (OSTI)

    Fisher, I.P.; Souhrada, F.; Woods, H.J.

    1981-10-13

    An integrated upgrading process is disclosed which can be used to lower the specific gravity, viscosity and boiling range of heavy, viscous hydrocarbonaceous oil . The process consists of fractionally distilling the oil, treating its residuum with a hydrogen donor material under hydrocracking conditions, fractionally distilling the effluent from the hydrocracking zone and rehydrogenating that portion boiling from about 180/sup 0/ C to 350/sup 0/ C for recycling to the hydrocracking zone. The liquid portion of the oil not recycled can be recombined into a reconstituted crude suitable for transporting by normal crude pipelines.

  16. Hydroprocessing catalysts for heavy oil and coal

    SciTech Connect (OSTI)

    Satriana, M.J.

    1982-01-01

    Hydroprocessing catalysts, as described in over 230 processes covered in this book, are hydrogenation catalysts used in the upgrading of heavy crudes and coal to products expected to be in great demand as the world's primary oil supplies gradually dwindle. The techniques employed in hydroprocessing result in the removal of contaminants, the transformation of lower grade materials such as heavy crudes to valuable fuels, or the conversion of hydrocarbonaceous solids into gaseous or liquid fuel products. All of these techniques are, of course, carried out in the presence of hydrogen. Some of the brightest energy prospects for the future lie in heavy oil reservoirs and coal reserves. Heavy oils, defined in this book as having gravities of < 20/sup 0/API, are crudes so thick that they are not readily extracted from their reservoirs. However, processing of these crudes is of great importance, because the US resource alone is enormous. The main types of processing catalysts covered in the book are hydrorefining catalysts plus some combinations of the two. Catalysts for the conversion of hydrocarbonaceous materials to gaseous or liquid fuels are also covered. The primary starting material for these conversions is coal, but wood, lignin, oil shale, tar sands, and peat are other possibilities. The final chapter describes the preparation of various catalyst support systems.

  17. Kinetics of heavy oil/coal coprocessing

    SciTech Connect (OSTI)

    Szladow, A.J.; Chan, R.K. ); Foudu, S.; Kelly, J.F. )

    1988-06-01

    A number of studies have been reported on coprocessing of coal and oil sand bitumen, petroleum residues and distillate fractions in catalytic and non-catalytic processes. The studies described the effects of feedstock characteristics, process chemistry and operating variables on the product yield and distribution; however, very few kinetic data were reported in these investigations. This paper presents the kinetic data and modelling of the CANMET coal/heavy oil coprocessing process. CANMET has been conducting research and process development work on coprocessing of Canadian heavy oil/bitumen and coal since 1979 including studies of the kinetics and mechanisms of coprocessing. As a continuation of the program, CANMET and Lobbe Technologies undertook a project on mathematical modelling of coprocessing kinetics with emphasis on the development of reaction engineering models for improved process performance and operation.

  18. Heavy oil. upgrading integrated with steam drive

    SciTech Connect (OSTI)

    Van Driesen, R.; Viens, C.H.; Fornoff, L.L.

    1980-01-01

    A study of the upgrading of heavy oil from a representative Venezuelan Jobo crude (9.2/sup 0/API, 4.1% sulfur, and 500 ppm total metals) from the Orinoco area involved 110 computer simulations based on a modified C-E Lummus Refinery Linear Program model on the assumptions of a 125,000 bbl/day refinery built, starting at 1979 prices, for completion by 1986 near the producing field to supply the fuel oil needed to provide oil field steam. All of the upgrading systems were economically attractive; the per cent return-on-investment (ROI) before taxes for the methods studied were: for Lummus LC-Fining, 135.9%; for Exxon's FLEXICOKING, 132.4%; for delayed coking, 119.2%; and for deasphalting, 106.5%. LC-Fining provided the best over-all combination of flexibility, product yield, product quality, and return on investment. The economics favored upgrading to the maximum extent possible; there was a reduction in the ROI for all the upgrading systems when product specifications were lowered from the premium base case (1.2% SO/sub 2/ emitted per million Btu fired). The premium upgraded heavy crude oils should be worth $3.00-$3.50/bbl more than comparable conventional crude oils, could be of up to 27/sup 0/API, and could be substituted, at up to 50%, for conventional crude oils in a typical U.S. refinery.

  19. Recovery and upgrading of heavy oil analyzed

    SciTech Connect (OSTI)

    Fornoff, L.L.; Van Driesen, R.P.; Viens, C.H.

    1980-10-13

    An analysis has been made of recovery and upgrading of Venezuelan heavy crudes by integrating steam-drive production data with an upgraded computer processing program. A study used 110 computer cases to analyze a project using Venezuelan heavy crude from the Jobo field with gravity of 9.2 API and 4.1% by wt sulfur for the base case. Sensitivity cases used 12.2 API oil from the Lot 9 field, Monagas state, Venezuela, with sulfur content of 2.3%. Four upgrading methods were studied (deasphalting, delayed coking, flexicoking, and LC-fining), all with favorable resulting economics.

  20. Bitumen and heavy oil upgrading in Canada

    SciTech Connect (OSTI)

    Chrones, J. ); Germain, R.R. )

    1989-01-01

    A review is presented of the heavy oil upgrading industry in Canada. Up to now it has been based on the processing of bitumen extracted from oil sands mining operations at two sites, to produce a residue-free, low sulphur, synthetic crude. Carbon rejection has been the prime process technology with delayed coking being used by Suncor and FLUID COKING at Syncrude. Alternative processes for recovering greater amounts of synthetic crude are examined. These include a variety of hydrogen addition processes and combinations which produce pipelineable materials requiring further processing in downstream refineries with expanded capabilities. The Newgrade Energy Inc. upgrader now under construction in Regina, will use fixed-bed, catalytic, atmospheric-residue, hydrogen processing. Two additional projects, also based on hydrogenation, will use ebullated bed catalyst systems; the expansion of Syncrude, now underway, is using the LC Fining Process whereas the announced Husky Bi-Provincial upgrader is based on H-Oil.

  1. Bitumen and heavy oil upgrading in Canada

    SciTech Connect (OSTI)

    Chrones, J.

    1988-06-01

    A review is presented of the heavy oil upgrading industry in Canada. Up to now it has been based on the processing of bitumen extracted from oil sands mining operations at two sites, to produce a residue-free, low sulfur, synthetic crude. Carbon rejection has been the prime process technology with delayed coking being used by Suncor and FLUID COKING at Syncrude. Alternative processes for recovering greater amounts of synthetic crude are examined. These include a variety of hydrogen addition processes and combinations which produce pipelineable materials requiring further processing in downstream refineries with expanded capabilities. The Newgrade Energy Inc. upgrader, now under construction in Regina, will use fixed-bed, catalytic, atmospheric-residue, hydrogen processing. Two additional products, also based on hydrogenation, will use ebullated bed catalyst systems: the expansion of Syncrude, now underway, is using the LC Fining Process whereas the announced Husky Bi-Provincial upgrader is based on H-Oil.

  2. Combined process for heavy oil, upgrading and synthetic fuel production

    SciTech Connect (OSTI)

    Polomski, R.E.

    1984-06-05

    A process for upgrading heavy oil to fuel products comprises deasphalting the heavy oil with an oxygenated solvent and simultaneously converting the oxygenated solvent and deasphalted oil over a ZSM-5 type catalyst to produce gasoline and distillate boiling range hydrocarbons.

  3. Characterization of Venezuelan heavy oil vacuum residua

    SciTech Connect (OSTI)

    Izquierdo, A.; Carbognani, L.; Leon, V.; Parisi, A. )

    1988-06-01

    Characterization of abundant ''heavy'' feedstocks such as tar sands, heavy oils and vacuum residua will play a fundamental role in the use of these energy sources. Their physical and chemical properties vary from one feed to another, and this can have some consequences in their necessary upgrading processes. In this paper results on the characterization of 510/sup 0/C-vacuum residua (VR) obtained from Venezuelan Heavy and Medium Oils are presented. These are Morichal (Mo), Merey (Me), Guafita (Gu) and Barinas (Ba). The VR have all an API gravity between 3 and 6, more than 15% asphaltenes, metals above 200 ppm, as well as high contents of nitrogen, more than 6000 ppm, and sulphur, over 1%. It has been found that when these feeds are hydrotreated under similar conditions the processability improves in the order Ba

  4. Flexibility in heavy oil upgrading with unicracking/HDS technology

    SciTech Connect (OSTI)

    Hennig, H.; Baron, K.; Moorhead, E.L.; Smith, M.

    1984-03-01

    With petroleum reserves becoming heavier and the demand for bottom of the barrel products greatly reduced, refiners are increasing their capabilities to upgrade heavy oil. Many heavy oil upgrading options are available and the best strategy for each refiner is not obvious. The best approach will depend on the specific circumstances and goals of the refiner. This presentation discusses the relative merits of several heavy oil upgrading options utilizing the Unicracking/HDS process.

  5. Trends in heavy oil production and refining in California

    SciTech Connect (OSTI)

    Olsen, D.K.; Ramzel, E.B.; Pendergrass, R.A. II

    1992-07-01

    This report is one of a series of publications assessing the feasibility of increasing domestic heavy oil production and is part of a study being conducted for the US Department of Energy. This report summarizes trends in oil production and refining in Canada. Heavy oil (10{degrees} to 20{degrees} API gravity) production in California has increased from 20% of the state`s total oil production in the early 1940s to 70% in the late 1980s. In each of the three principal petroleum producing districts (Los Angeles Basin, Coastal Basin, and San Joaquin Valley) oil production has peaked then declined at different times throughout the past 30 years. Thermal production of heavy oil has contributed to making California the largest producer of oil by enhanced oil recovery processes in spite of low oil prices for heavy oil and stringent environmental regulation. Opening of Naval Petroleum Reserve No. 1, Elk Hills (CA) field in 1976, brought about a major new source of light oil at a time when light oil production had greatly declined. Although California is a major petroleum-consuming state, in 1989 the state used 13.3 billion gallons of gasoline or 11.5% of US demand but it contributed substantially to the Nation`s energy production and refining capability. California is the recipient and refines most of Alaska`s 1.7 million barrel per day oil production. With California production, Alaskan oil, and imports brought into California for refining, California has an excess of oil and refined products and is a net exporter to other states. The local surplus of oil inhibits exploitation of California heavy oil resources even though the heavy oil resources exist. Transportation, refining, and competition in the market limit full development of California heavy oil resources.

  6. Trends in heavy oil production and refining in California

    SciTech Connect (OSTI)

    Olsen, D.K.; Ramzel, E.B.; Pendergrass, R.A. II.

    1992-07-01

    This report is one of a series of publications assessing the feasibility of increasing domestic heavy oil production and is part of a study being conducted for the US Department of Energy. This report summarizes trends in oil production and refining in Canada. Heavy oil (10{degrees} to 20{degrees} API gravity) production in California has increased from 20% of the state's total oil production in the early 1940s to 70% in the late 1980s. In each of the three principal petroleum producing districts (Los Angeles Basin, Coastal Basin, and San Joaquin Valley) oil production has peaked then declined at different times throughout the past 30 years. Thermal production of heavy oil has contributed to making California the largest producer of oil by enhanced oil recovery processes in spite of low oil prices for heavy oil and stringent environmental regulation. Opening of Naval Petroleum Reserve No. 1, Elk Hills (CA) field in 1976, brought about a major new source of light oil at a time when light oil production had greatly declined. Although California is a major petroleum-consuming state, in 1989 the state used 13.3 billion gallons of gasoline or 11.5% of US demand but it contributed substantially to the Nation's energy production and refining capability. California is the recipient and refines most of Alaska's 1.7 million barrel per day oil production. With California production, Alaskan oil, and imports brought into California for refining, California has an excess of oil and refined products and is a net exporter to other states. The local surplus of oil inhibits exploitation of California heavy oil resources even though the heavy oil resources exist. Transportation, refining, and competition in the market limit full development of California heavy oil resources.

  7. 9000 wells planned for heavy oil field. [Canada

    SciTech Connect (OSTI)

    Not Available

    1981-05-01

    Beginning in 1983, Esso Resources Canada Ltd. will begin drilling the first of an estimated 9000 directional crude bitumen wells in the tar sands at Cold Lake, Alberta, Canada, the final wells being drilled in the year 2008. The area, covering 50 sq miles of extreme E. Alberta along the Saskatchewan border, contains one of the richest deposits of heavy oil sands in Canada. The company and future partners will drill the bitumen wells directionally into the shallow clearwater formation, which can be reached at approx. 100 m (330 ft). The formation contains an estimated 80 billion bbl of crude bitumen at a rate of 60,000 bpd for 25 yr. This volume of crude will be refined in an upgrading plant to 140,000 bpd of synthetic crude oil. When completed, the Cold Lake project will be one of the largest facilities for producing crude bitumen from wells in the world.

  8. Characteristics and upgrading technologies of Chinese heavy oil

    SciTech Connect (OSTI)

    Ghuang Yang; Jinsen Gao

    1995-12-31

    The characteristics of typical Chinese heavy oils produced in the eastern, northwestern, and northeastern parts of China are presented to show the uniqueness of heavy oils on the Chinese mainland. Henceforth, upgrading technologies of Chinese domestic heavy crudes are discussed along this line. Two main categories of upgrading technologies, decarbonization and hydrogenation, as realized or being developed in this country are presented. It is concluded that most Chinese heavy crudes are adaptable to conventional upgrading processes.

  9. Upgrading heavy oil using slurry processes

    SciTech Connect (OSTI)

    Del Bianco, A.; Panariti, N.; Marchionna, M.

    1995-11-01

    There is a growing interest in processes capable of converting heavy feedstocks (petroleum residues and heavy oils) into lower boiling products of high quality. The operational problems of upgrading heavy feeds relate to the presence of sulfur, nitrogen, metals, and considerable amounts of Conradson carbon residue. An efficient residue conversion process must be able to reduce the molecular weight of the feedstocks to material with boiling points below 550 C, increase the H-to-C ratio of the refined product, and remove heteroatoms and metals. Whereas the molecular weight reduction is normally achieved by C-C bond cracking above 400 C, often in the presence of acid catalysts, a higher H-to-C ratio can be obtained by either the rejection of carbon (as in coking) or the addition of hydrogen (as in hydrogenation processes). Slurry processes combine the flexibility of the carbon rejection with the high performance of the hydrogen addition processes. The origin of slurry processes is the Bergius-Pier technology (1920--1930) for the conversion of heavy oils and coal into distillates. Whereas the original Bergius-Pier technology did not use a catalyst, small amounts of inexpensive additives or finely dispersed hydrogenation catalysts can be used to increase the rates of the desired reactions. Catalysts can also inhibit coke formation by physically interfering with the coalescence of mesophase, which is the precursor of solid coke. Catalysts are used to reduce the severity of the process and to improve the quality of the products. Most of the research carried out in the past decade in the field of slurry processes has dealt with the identification of more effective and/or less expensive catalysts and the technological problems related to their use. Here the authors discuss both subjects, describing the path from the fundamental chemistry of dispersed catalytic systems to the development and initial commercialization of slurry processes.

  10. Sludge formation during heavy oil upgrading

    SciTech Connect (OSTI)

    Storm, D.A.; Decanio, S.J.; Edwards, J.C.

    1995-12-31

    A soft coke-like substance often forms in the liquid product of visbreaking and hydrocracking processes for upgrading vacuum residue of heavy crude oil. This material usually limits the severity or conversion of the process because it accumulates in downstream equipment. Although the amount of such material produced depends on the crude oil, it has not been possible to correlate its production rate to chemical characteristics of the vacuum residue in a quantitative manner In this work we show that the amount of sludge produced per unit weight of vacuum residue feed in laboratory hydrotreating experiments can be correlated with four chemical characteristic of the vacuum residue: the degree of condensed polynuclear aromaticity, the average number of alkyl-groups substituting the polynuclear aromatics, the ratio of heptane insolubles to pentane insoluble-heptane solubles, and the H/C ratio of the latter fraction. The correlation coefficient is 0.95.

  11. Heavy oil development in Canada - The need for upgrading

    SciTech Connect (OSTI)

    Quinn, P.C.

    1987-01-01

    The author first reviews Canada's petroleum reserves, then summarizes the problem facing Canada regarding dwindling supplies of conventional light and medium crude oils and briefly describes Canada's refining capability. With that background, he attempts to analyze the problems that face heavy oil producers in attempting to market their product and propose a potential solution to these problems as illustrated by Husky Oil's approach - the construction of a heavy oil upgrader. He closes by sharing his views on the future of heavy oil development and the policy issues facing our governments.

  12. Co-processing of heavy oil

    SciTech Connect (OSTI)

    Khan, M.R.

    1995-12-31

    In co-processing of petroleum and coal, the petroleum fraction may serve as the {open_quotes}liquefaction solvent,{close_quotes} or hydrogen donor, and the aromatics present in the coal liquid may serve as hydrogen {open_quotes}shuttlers{close_quotes} by efficiently transferring hydrogen moieties to places where they are most deficient. The important advantages of co-processing include the following: (1) upgrading of heavy petroleum in a reaction with coal and (2) conversion of coal to synthetic crudes which could be further upgraded to a premium liquid fuel. Co-processing of coal with petroleum, heavy crudes, and residues through catalytic hydrogenation or solvent extraction have been extensively investigated. The studies were typically conducted in the temperature range of 450{degrees}-500{degrees}C under pressurized hydrogen; catalysts are generally also added for hydroconversion of the feedstocks. However, relatively little has been reported in the literature regarding co-processing of coal with heavy petroleum by simple pyrolysis. In this study, co-processing of heavy oil and coal at relatively middle conditions was conducted without the complicating influences of pressurized hydrogen or catalysts. The resulted demonstrate that there is a synergism during co-processing of petroleum and coal. This synergism enhances both the yield and quality of the liquid products. In general, liquids from co-processing the mixture contain a higher content of alkane/alkene, neutral aromatics, lower content of monophenols, and other oxygen containing compounds as compared to the liquids from coal alone. The liquid from the mixture also contains a higher content of naphthenic carbon and naphthenic rings/molecules than those from coal liquid. This suggests that the product from the mixture can be easily upgraded to a premium quality fuel.

  13. Heavy oil and tar sands recovery and upgrading. International technology

    SciTech Connect (OSTI)

    Schumacher, M.M.

    1982-01-01

    This work provides an in-depth assessment of international technology for the recovery and upgrading of heavy crude oil and tar sands. The technologies included are currently in use, under development, or planned; emphasis is placed on post-1978 activities. The heavy oil technologies and processes considered include methods relating to the exploitation of heavy oil reservoirs, such as production from underground workings, all types of improved or enhanced recovery, subsurface extraction, and well rate stimulation. The tar sands section includes sizing the resource base and reviewing and evaluating past, present, and planned research and field developments on processes for mining, producing, extracting, and upgrading very heavy oils recovered from tar sands, e.g., bitumen recovery from tar sands where primary production was impossible because of the oil's high viscosity. 616 references.

  14. EXPERIMENTAL AND THEORETICAL DETERMINATION OF HEAVY OIL VISCOSITY...

    Office of Scientific and Technical Information (OSTI)

    EXPERIMENTAL AND THEORETICAL DETERMINATION OF HEAVY OIL VISCOSITY UNDER RESERVOIR CONDITIONS FINAL PROGRESS REPORT PERIOD: OCT 1999-MAY 2003 CONTRACT NUMBER: DE-FG26-99FT40615 ...

  15. Heavy and Thermal Oil Recovery Production Mechanisms, SUPRI TR-127

    SciTech Connect (OSTI)

    Kovscek, Anthony R.; Brigham, William E.; Castanier, Louis M.

    2001-09-07

    The program spans a spectrum of topics and is divided into five categories: (i) multiphase flow and rock properties, (ii) hot fluid injection, (iii) primary heavy-oil production, (iv) reservoir definition, and (v) in-situ combustion.

  16. 05663_AlaskaHeavyOil | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DE-NT0005663 Goal The goal of this project is to improve recovery of Alaskan North Slope (ANS) heavy oil resources in the Ugnu formation by improving our understanding of the ...

  17. 05663_AlaskaHeavyOil | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fluid and Rock Property Controls On Production and Seismic Monitoring Alaska Heavy Oils Last Reviewed 12/20/2012 DE-NT0005663 Goal The goal of this project is to improve recovery of Alaskan North Slope (ANS) heavy oil resources in the Ugnu formation by improving our understanding of the formation's vertical and lateral heterogeneities via core evaluation, evaluating possible recovery processes, and employing geophysical monitoring to assess production and modify production operations. Performers

  18. SOVENT BASED ENHANCED OIL RECOVERY FOR IN-SITU UPGRADING OF HEAVY OIL SANDS

    SciTech Connect (OSTI)

    Munroe, Norman

    2009-01-30

    With the depletion of conventional crude oil reserves in the world, heavy oil and bitumen resources have great potential to meet the future demand for petroleum products. However, oil recovery from heavy oil and bitumen reservoirs is much more difficult than that from conventional oil reservoirs. This is mainly because heavy oil or bitumen is partially or completely immobile under reservoir conditions due to its extremely high viscosity, which creates special production challenges. In order to overcome these challenges significant efforts were devoted by Applied Research Center (ARC) at Florida International University and The Center for Energy Economics (CEE) at the University of Texas. A simplified model was developed to assess the density of the upgraded crude depending on the ratio of solvent mass to crude oil mass, temperature, pressure and the properties of the crude oil. The simplified model incorporated the interaction dynamics into a homogeneous, porous heavy oil reservoir to simulate the dispersion and concentration of injected CO2. The model also incorporated the characteristic of a highly varying CO2 density near the critical point. Since the major challenge in heavy oil recovery is its high viscosity, most researchers have focused their investigations on this parameter in the laboratory as well as in the field resulting in disparaging results. This was attributed to oil being a complex poly-disperse blend of light and heavy paraffins, aromatics, resins and asphaltenes, which have diverse behaviors at reservoir temperature and pressures. The situation is exacerbated by a dearth of experimental data on gas diffusion coefficients in heavy oils due to the tedious nature of diffusivity measurements. Ultimately, the viscosity and thus oil recovery is regulated by pressure and its effect on the diffusion coefficient and oil swelling factors. The generation of a new phase within the crude and the differences in mobility between the new crude matrix and the

  19. Process for stimulating and upgrading the oil production from a heavy oil reservoir

    SciTech Connect (OSTI)

    Sweany, G.A.

    1981-08-18

    A process for thermally stimulating and upgrading oil production from a heavy oil reservoir wherein the heavy oil produced from the reservoir is combined with a hydrogen donor diluent and the mixture is subjected to thermal cracking to upgrade the heavy oil into more valuable hydrocarbon products. The cracked products are fractionated into a light end vapor fraction, an intermediate liquid fraction, a gas oil fraction and a pitch fraction, and at least a portion of the gas oil fraction is hydrogenated by contacting it with a hydrogen-containing gas stream to produce the hydrogen donor diluent combined with the heavy oil. The pitch fraction is subjected to partial oxidation to produce the hydrogen-containing gas stream and a by-product gas stream containing steam which is combined with additional steam and injected into the heavy oil reservoir to enhance the mobility of heavy oil contained therein. The light end vapor fraction and unreacted hydrogen-containing gas produced by the process are utilized as fuel in the process. The intermediate liquid fraction produce and portion of the gas oil fraction not hydrogenated are readily transportable from the process.

  20. Development Practices for Optimized MEOR in Shallow Heavy Oil Reservoirs

    SciTech Connect (OSTI)

    Shari Dunn-Norman

    2006-09-30

    The goal of this project is to demonstrate an economically viable and sustainable method of producing shallow heavy oil reserves in southwest Missouri and southeast Kansas using a combination of microbial enhanced oil recovery (MEOR) and hydraulic fracturing of vertical wells.

  1. Heavy oil and tar sands recovery and upgrading: international technology

    SciTech Connect (OSTI)

    Schumacher, M.M.

    1982-01-01

    This book provides an in-depth assessment of international technology for the recovery and upgrading of heavy crude oil and tar sands. The technologies included are currently in use, under development, or planned; emphasis is placed on post-1978 activities. The heavy oil technologies and processes considered in Part I include methods relating to the exploitation of heavy oil reservoirs, such as production from undergorun workings, all types of improved or enhanced recovery, subsurface extraction, and well rate stimulation. Furthermore, even though heavy crudes are understood to include only those liquid or semiliquid hydrocarbons with a gravity of 20/sup 0/API or less, technology applied to lighter crude oils with in situ viscosities of the same order of magnitude as some US heavy oils is also included. The scope of the tar sands section (Part II) includes sizing the resource base and reviewing and evaluatin past, present, and planned research and field developments on processes for mining, producing, extracting, and upgrading very heavy oils recovered from tar sands, e.g., bitumen recovery from tar sands where primary production was impossible because of the oil's high viscosity. On the production side, very heavy oil is defined as having a gravity less than 10/sup 0/ to 12/sup 0/API and greater than 100,000-centipoise viscosity at 50/sup 0/F. On the upgrading side, hydrocarbons whose characteristics dictated additional processing prior to conventional refining into salable products (1050+/sup 0/ material) were included, regardless of origin, in order to encompass all pertinent upgrading technologies.

  2. Heavy oil reservoirs recoverable by thermal technology. Annual report

    SciTech Connect (OSTI)

    Kujawa, P.

    1981-02-01

    The purpose of this study was to compile data on reservoirs that contain heavy oil in the 8 to 25/sup 0/ API gravity range, contain at least ten million barrels of oil currently in place, and are non-carbonate in lithology. The reservoirs within these constraints were then analyzed in light of applicable recovery technology, either steam-drive or in situ combustion, and then ranked hierarchically as candidate reservoirs. The study is presented in three volumes. Volume I presents the project background and approach, the screening analysis, ranking criteria, and listing of candidate reservoirs. The economic and environmental aspects of heavy oil recovery are included in appendices to this volume. This study provides an extensive basis for heavy oil development, but should be extended to include carbonate reservoirs and tar sands. It is imperative to look at heavy oil reservoirs and projects on an individual basis; it was discovered that operators, and industrial and government analysts will lump heavy oil reservoirs as poor producers, however, it was found that upon detailed analysis, a large number, so categorized, were producing very well. A study also should be conducted on abandoned reservoirs. To utilize heavy oil, refiners will have to add various unit operations to their processes, such as hydrotreaters and hydrodesulfurizers and will require, in most cases, a lighter blending stock. A big problem in producing heavy oil is that of regulation; specifically, it was found that the regulatory constraints are so fluid and changing that one cannot settle on a favorable recovery and production plan with enough confidence in the regulatory requirements to commit capital to the project.

  3. Process for demetallizing and desulfurizing heavy crude oil

    SciTech Connect (OSTI)

    Brown, R.E.; Hogan, R.J.; Combs, D.M.; Kukes, S.G.

    1989-12-05

    This patent describes a process for producing a synthetic crude oil of improved properties by desulfurizing, denitrogenating and demetallizing a heavy crude oil feed stock. The feed stock being a crude oil having an average boiling point at least as high as 500{degrees} F., an API gravity at 60{degrees} F. of less than 20, and containing at least about 1 weight percent sulfur.

  4. Lime addition to heavy crude oils prior to coking

    SciTech Connect (OSTI)

    Kessick, M. A.; George, Z. M.; Schneider, L. G.

    1985-06-04

    The sulphur emissive capability, on combustion, of coke which is formed during upgrading of sulphur-containing heavy crude oils, including oil sands bitumen, or residua is decreased by the addition of slaked lime or calcium oxide to the heavy crude oil prior to coking. The presence of the slaked lime or calcium oxide leads to an increased yield of liquid distillates at coking temperatures of about 450/sup 0/ to about 500/sup 0/ C. Ash remaining after combustion of the coke may be leached to recover nickel and vanadium values therefrom.

  5. Canada's heavy oil, bitumen upgrading activity is growing

    SciTech Connect (OSTI)

    Corbett, R.A.

    1989-06-26

    Heavy oil and bitumen upgrading activity in Canada is surging with the recent start-up of two new upgraders and with plans to build others. These new upgraders make use of modern hydrocracking technology. Articles in this special report on upgrading focus on Canada's oil and bitumen reserves, the promising technologies that upgrade them, and present details of some of the current upgrader projects. This article covers the following areas: Canada's heavy oils; Upgrading expands; Upgrading technologies; Test results; Regional upgraders; High-quality light product.

  6. Canadian oilsands, heavy oil adjusting to tough economics

    SciTech Connect (OSTI)

    Not Available

    1994-07-11

    Canadian oilsands and heavy oil operators are using operational upgrades and substantial research outlays as key weapons against an economic squeeze brought about largely by volatile oil prices. The Canadian Oilsands Network for Research and Development (Conrad) was formed late last year to coordinate nonproprietary research on oilsands technology among industry, government, and academic centers. The Alberta Oilsands Technology and Research Authority (Aostra), now part of Alberta's energy department, also is active with a number of industry partners in oilsands and heavy oil research. Aostra has made significant gains in demonstration projects. The paper discusses upgrader problems, key ingredients to improving operations and development of new technology, syncrude operations, cost, environmental upgrading, Imperials' heavy oil operation at Cold Lake, Shell's operation at Peace River and Amoco operations in Canada.

  7. Upgrading heavy oils by solvent dissolution and ultrafiltration

    SciTech Connect (OSTI)

    Osterhuber, E.J.

    1989-01-10

    A method is described for the separation of a heavy oil diluting the heavy oil with a solvent which is completely miscible with the heavy oil in an amount sufficient to completely dissolve the oil so as to produce an ultrafiltration feed; contacting the ultrafiltration feed with a first side of a continuous generally unswelled organic membrane selected from the group consisting of those comprising cellulose or polyvinylidine fluoride at a pressure between about 750 kPa and about 1500 kPa and at a temperature between 20/sup 0/C. and about 125/sup 0/C.; recovering a permeate fraction enriched in aromatic and saturated hydrocarbons from a second side of the membrane, and recovering a retentate fraction enriched in polar and metal-containing hydrocarbons from the first side of the membrane.

  8. A novel process for upgrading heavy oil emulsions

    SciTech Connect (OSTI)

    Ng, F.T.T.; Rintjema, R.T.

    1994-12-31

    Canada has extensive reserves of high sulfur heavy oils. These heavy oils are recovered primarily by steam injection techniques. As a result, the heavy oils are obtained as emulsions at well-heads. The heavy oils, being high in sulfur and metals, and low in hydrogen to carbon atomic ratio, require upgrading such as desulfurization and hydrocracking before it can be used in conventional refineries. Conventional emulsion treatment and desulfurization technology require multistage processing. Thus, alternative technologies for processing heavy oil emulsions would be attractive. The authors have recently developed a novel single stage process for upgrading emulsions via activation of water to provide hydrogen in situ for catalytic desulfurization and hydrocracking. Current work is focused on the desulfurization aspect of upgrading, using benzothiophene as the model sulfur compound and molybdic acid as the catalyst. At 340 C and a CO loading pressure of 600 psi, up to 86% sulfur removal was obtained. As well, in situ generated H{sub 2} was found to be more active than externally supplied molecular H{sub 2}. A likely pathway for desulfurization of benzothiophene was via the initial hydrogenation of benzothiophene to dihydrobenzothiophene followed by hydrogenolysis to give ethylbenzene and H{sub 2}S.

  9. Upgrading heavy hydrocarbon oils using sodium hypochlorite

    SciTech Connect (OSTI)

    Rankel, L.A.

    1986-07-22

    A process is described for demetallizing a residual hydrocarbon fraction comprising: (a) contacting the hydrocarbon fraction with an aqueous solution of a hypochlorite salt; (b) separating the mixture into an aqueous phase and an oil phase; (c) contacting the oil phase with a deasphalting solvent and (d) obtaining by separation a product comprising a demetallized oil fraction suitable for use as a feedstock for catalytic processing.

  10. A technical and economic assessment of petroleum, heavy oil, shale oil and coal liquid refining

    SciTech Connect (OSTI)

    Sikonia, J.G.; Shah, B.R.; Ulowetz, M.A.

    1983-11-01

    Decreasing availability of conventional crude oil will result in the utilization of alternative raw materials for the production of transportation fuels. Based on currently available processes and as a result of detailed pilot plant studies, the differences in the technical and economic aspects of refining alternative feedstocks of heavy oil, coal liquids and shale oil have indicated that heavy, hydrogen-deficient materials require more complex and costly upgrading techniques. Compared to the base case of Arabian Light crude oil, the Mexican Maya heavy oil is worth about $4.35/B less, the coal liquid about $2.38/B less and the shale oil about $5.98/B less. All of these alternative fuels can be upgraded into high quality transportation fuels.

  11. Field development options for a waterflooded heavy-oil reservoir

    SciTech Connect (OSTI)

    Kasraie, M. ); Sammon, P.H. ); Jespersen, P.J. )

    1993-09-01

    Battrum Unit 4 is a moderately heavy-oil reservoir in Saskatchewan producing under waterflood from a thin sand. This paper describes a history match of previous field behavior and systematically analyzes through the use of numerical simulation the potential benefits to production of further waterflooding (with and without infill drilling), steamflooding, and horizontal drilling. It is found that the remaining oil recovery potential of a steamflood with horizontal well is significantly higher than that of any of the waterflood options.

  12. Seismic properties of a Venezuelan heavy oil in water emulsion

    SciTech Connect (OSTI)

    Maldonado, F.; Liu, Y.; Mavko, G.; Mukerji, T.

    1996-08-01

    Several procedures for the production of low-viscosity, surfactant-stabilized, easy-transportable dispersions of heavy crude oil in water-briefly, oil in water (or o/w) emulsions - have been recently patented. Some of them propose to form the o/w emulsion in the reservoir, after the injection of a mixture of water and surfactants, increasing significantly the per well daily production. Progression of the o/w emulsion front, through the reservoir to the production wells, can be monitored in seismic planar slices with successive 3D seismic surveys (413 seismic), if enough contrast exists between the seismic velocity value of the o/w emulsion and the one of the oil in place. To facilitate the analysis of the contrast, this study presents high frequency acoustic velocity measurements performed in the laboratory. The experimental setup includes two reflectors and an ultrasonic transducer with double burst train emission. The estimated velocity precision is 0.02%. The measured samples are: a Venezuelan heavy o/w emulsion, a mixture of the same heavy oil and gasoil and a saturated sandstone core containing the o/w emulsion. Additionally, seismic velocities of the actual pore fluids - live oil and five o/w emulsion - and saturated sandstone are calculated using the above laboratory measurements, Wood`s equation, and Gassman`s and Biot`s models.

  13. Analysis of heavy oils: Method development and application to Cerro Negro heavy petroleum

    SciTech Connect (OSTI)

    Carbognani, L.; Hazos, M.; Sanchez, V. ); Green, J.A.; Green, J.B.; Grigsby, R.D.; Pearson, C.D.; Reynolds, J.W.; Shay, J.Y.; Sturm, G.P. Jr.; Thomson, J.S.; Vogh, J.W.; Vrana, R.P.; Yu, S.K.T.; Diehl, B.H.; Grizzle, P.L.; Hirsch, D.E; Hornung, K.W.; Tang, S.Y.

    1989-12-01

    On March 6, 1980, the US Department of Energy (DOE) and the Ministry of Energy and Mines of Venezuela (MEMV) entered into a joint agreement which included analysis of heavy crude oils from the Venezuelan Orinoco oil belt.The purpose of this report is to present compositional data and describe new analytical methods obtained from work on the Cerro Negro Orinoco belt crude oil since 1980. Most of the chapters focus on the methods rather than the resulting data on Cerro Negro oil, and results from other oils obtained during the verification of the method are included. In addition, published work on analysis of heavy oils, tar sand bitumens, and like materials is reviewed, and the overall state of the art in analytical methodology for heavy fossil liquids is assessed. The various phases of the work included: distillation and determination of routine'' physical/chemical properties (Chapter 1); preliminary separation of >200{degree}C distillates and the residue into acid, base, neutral, saturated hydrocarbon and neutral-aromatic concentrates (Chapter 2); further separation of acid, base, and neutral concentrates into subtypes (Chapters 3-5); and determination of the distribution of metal-containing compounds in all fractions (Chapter 6).

  14. Carbon sequestration in depleted oil shale deposits

    SciTech Connect (OSTI)

    Burnham, Alan K; Carroll, Susan A

    2014-12-02

    A method and apparatus are described for sequestering carbon dioxide underground by mineralizing the carbon dioxide with coinjected fluids and minerals remaining from the extraction shale oil. In one embodiment, the oil shale of an illite-rich oil shale is heated to pyrolyze the shale underground, and carbon dioxide is provided to the remaining depleted oil shale while at an elevated temperature. Conditions are sufficient to mineralize the carbon dioxide.

  15. System and method for preparing near-surface heavy oil for extraction using microbial degradation

    DOE Patents [OSTI]

    Busche, Frederick D.; Rollins, John B.; Noyes, Harold J.; Bush, James G.

    2011-04-12

    A system and method for enhancing the recovery of heavy oil in an oil extraction environment by feeding nutrients to a preferred microbial species (bacteria and/or fungi). A method is described that includes the steps of: sampling and identifying microbial species that reside in the oil extraction environment; collecting fluid property data from the oil extraction environment; collecting nutrient data from the oil extraction environment; identifying a preferred microbial species from the oil extraction environment that can transform the heavy oil into a lighter oil; identifying a nutrient from the oil extraction environment that promotes a proliferation of the preferred microbial species; and introducing the nutrient into the oil extraction environment.

  16. Heavy oil upgrading via fluidized bed processing and hydrogenation processing

    SciTech Connect (OSTI)

    Dawson, F.N. Jr.

    1995-09-01

    California is the second largest crude oil producer in the lower 48 states. Nearly half of its production is heavy oil, difficult to transport and costly to refine. Given better methods of processing, production could be expanded. Likewise, huge worldwide reserves of heavy oils could be better exploited if more attractive processing methods were available. Midway Sunset crude at 11.8 API gravity, is a fairly difficult crude to process. It has about 1.5 percent sulfur, a very high nitrogen content, in the range of 0.7--0.8%, and metals of approximately 120--170 ppm, vanadium plus nickel. The authors will be reporting here results of the pilot plant testing to see whether non-catalytic fluid bed cracking technology, operated at low conversion, followed by hydrogenation would be economically attractive. Results suggest that this approach is competitive with delayed coking and with atmospheric resid desulfurization. This approach successfully combines carbon removal and hydrogen addition techniques for heavy oil upgrading. Comparative yields, product quality and economic considerations are reviewed in this study.

  17. Processing of heavy oil utilizing the Aurabon process. Final report

    SciTech Connect (OSTI)

    Not Available

    1982-01-01

    This report contains estimates of the product yields and product properties from four separate, commercial-scale Aurabon heavy oil upgrading complexes capable of producing low-sulfur, hydrogen-rich products from various fractions of either a Venezuelan Boscan or a Canadian Lloydminster heavy oil feedstock. These estimates formed the basis for the development of the necessary process engineering work, including the general equipment specifications for the major equipment items included in each processing unit, required to determine cost and utilities estimates, construction labor requirements, and an estimated construction cost schedule for each of the four upgrading complexes. In addition to the above information, estimates of the yields and properties of the products produced during the upgrading of the heavy portion of the Aurabon product by both the hydrocracking and fluidized catalytic cracking processes are also included in this report. Consistent with the provisions of the executed contract for this work, those portions of the engineering work which were considered proprietary to UOP, including the heat and material balances, process flow diagrams, piping and instrument diagrams, and general equipment specifications developed for each process unit contained in the heavy oil upgrading facilities have not been included in this report. This report does, however, contain sufficient non-proprietary information to provide the reader with a general understanding of the Aurabon process and detailed information regarding the performance of the process when upgrading the two heavy oil feedstocks studied. UOP has allowed the consulting firms of Walk, Haydel and Associates of New Orleans, Louisiana and Texas Consultants, Inc. of Houston, Texas to review various portions of the engineering work developed by UOP under this contract. 1 reference, 13 figures, 22 tables.

  18. Heavy oil upgrading for the future

    SciTech Connect (OSTI)

    Reynolds, B.E.; Johnson, D.R.; Lasher, J.S.; Hung, C. )

    1989-01-01

    The Chevron RDS Hydrotreating Process and the Gulf Resid HDS Process were pioneers in this field, beginning with the startup of the first resid desulfurization unit in 1969. The merger of Chevron Corporation with Gulf Oil Corporation resulted in a versatile new RDS Hydrotreating technology which utilizes the best features of the original Chevron and Gulf processes. Continuing improvements in the catalyst and in process configuration have greatly increased the capability of combined Chevron RDS hydrotreating to provide deeper demetalation (HDM), denitrification (HDN), Ramscarbon removal (HDR), desulfurization (HDAS), and greater cracking conversion (HCR) while processing more difficult feedstocks. future. The process is detailed by the authors.

  19. Upgrading of heavy oils by asphaltenic bottom cracking

    SciTech Connect (OSTI)

    Sudoh, j.; Shiroto, Y.; Fukui, Y.; Takeuchi, C.

    1983-03-01

    Results of the pilot plant study of the conversion of heavy petroleum residues (Khafji VR) to lighter feedstocks deasphalted oil (DAO) by a combination process involving asphaltenic bottom cracking (ABC) and solvent deasphalting (SDA) are reported. In addition to correlations between DAO and asphalt yield under various hydrotreating conditions, a mathematical model describing quantitative relationships between recycle rate of SDA asphalt and ABC in extinction and recycle operations are described. Effects of process variations on product (DAO, asphalt) quality are also discussed.

  20. Saber's heavy oil cracking refinery project

    SciTech Connect (OSTI)

    Benefield, C.S.; Glasscock, W.L.

    1983-03-01

    Perhaps more than any other industry, petroleum refining has been subjected to the radical swings in business and political climates of the past several decades. Because of the huge investments and long lead times to construct refining facilities, stable government policies, predictable petroleum prices, secure feedstock supplies and markets, and reliable cost estimates are necessary ingredients to effectively plan new refinery projects. However, over the past ten years the political and economic climates have provided anything but these conditions. Yet, refiners have demonstrated a willingness to undertake risks by continuing to expand and modernize their refineries. The refining business -- just as most businesses -- responds to economic incentives. These incentives, when present, result in new technology and capacity additions. In the 1940's, significant technology advances were commercialized to refine higher-octane motor gasolines. Such processes as continuous catalytic cracking (Houdry Process Corporation), fluid catalytic cracking (Standard Oil Development Company), HF alkylation (UOP and Phillips Petroleum Company), and catalytic reforming (UOP) began to supply a growing gasoline market, generated from the war effort and the ever increasing numbers of automobiles on the road. The post-war economy of the 1950's and 1960's further escalated demand for refined products, products which had to meet higher performance specifications and be produced from a wider range of raw materials. The refining industry met the challenge by introducing hydro-processing technology, such as hydrocracking developed in 1960. But, the era must be characterized by the large crude processing capacity additions, required to meet demand from the rapidly expanding U.S. economy. In 1950, refining capacity was 6.2 million BPD. By 1970, capacity had grown to 11.9 million BPD, an increase of 91%.

  1. Petroleum geology of heavy oil in the Oriente basin of Ecuador: Exploration and exploitation challenge for the 1990s

    SciTech Connect (OSTI)

    Leadholm, R.H. )

    1990-05-01

    Published Ecuadorian government forecasts suggest that Oriente basin light oil (21-32{degree} API) production may start to decline in the early to mid-1990s. To maintain stabilized production into the next century, heavy oil reserves (10-20{degree} API) will have to be aggressively exploited. The Oriente's undeveloped proven plus probable heavy reserves are substantial and are expected to exceed 0.5 billion bbl. A recent discovery made by Conoc Ecuador Ltd., operator of Block 16 for a group which consists of O.P.I.C., Maxus, Nomeco, Murphy and Canam, is a good model for future exploration and exploitation of heavy oil in the remote eastern regions of the basin. Amo-1 tested a low-relief anticline (less than 100 ft vertical closure) and encountered 10-20{degree} API oil in five Cretaceous sandstone reservoirs (8,000-10,000 ft depth). Cumulative test production was 1,062 BOPD. Subsequent drilling along the trend resulted in three additional discoveries. The Cretaceous sands were transported from the Brazilian shield by the westward flowing proto-Amazon River and were deposited in fluviodeltaic, tidal, and high-energy marginal marine environments. Air permeabilities are high and geometric mean values approaching several darcies. Porosities average 18-22% in generally well-consolidated sands. The heavy oils are the result of mild biodegradation and/or expulsion from a thermally immature source. Oil-to-oil correlations suggest that all of the basin oils have the same or similar origin, probably marine calcareous shales of the Cretaceous Napo formation. The Block 16 project will provide a major step toward the strategic exploitation of the Oriente basin's heavy oil reserves, when it comes on stream in the early 1990s.

  2. Heavy oil upgrading using an integrated gasification process

    SciTech Connect (OSTI)

    Quintana, M.E.; Falsetti, J.S.

    1995-12-31

    The value of abundant, low-grade heavy crude oil reserves can be enhanced by appropriate upgrade processing at the production site to yield marketable refinery feedstocks or ultimate products. One of the upgrading process sequences most commonly considered involves vacuum distillation followed by a bottoms processing step such as solvent deasphalting or coking. These schemes can be further enhanced with the addition of a gasification step to convert the unsaleable, bottom-of-the-barrel residues into useful products, such as high-purity hydrogen for hydrotreating, electrical power, steam for enhanced oil recovery and distillation, etc. This paper describes the Texaco Gasification Process and the T-STARs hydrotreating process, and their application in an integrated upgrade processing scheme in which an optimal, virtually bottomless oil utilization can be achieved. Illustrative examples of this integration are provided with comparative economic information.

  3. Liquid fuels from co-processing coal with bitumen or heavy oil: A review

    SciTech Connect (OSTI)

    Moschopedis, S.E.; Hepler, L.G.

    1987-01-01

    Coal, bitumen and heavy oil (and various pitches, resids, etc.) are similar in that they require more substantial treatment than does conventional light oil to yield useful liquid fuels. The authors provide a brief and selective review of technologies for liquefying coal, followed by consideration of co-processing coal with bitumen/heavy oil. Such co-processing may be considered as use of bitumen/heavy oil as a solvent and/or hydrogen donor in liquefaction of coal, or as the use of coal to aid upgrading bitumen/heavy oil.

  4. Venezuelan projects advance to develop world`s largest heavy oil reserves

    SciTech Connect (OSTI)

    Croft, G.; Stauffer, K.

    1996-07-08

    A number of joint venture projects at varying stages of progress promise to greatly increase Venezuela`s production of extra heavy oil. Units of Conoco, Chevron, Total, Arco, and Mobil have either signed agreements or are pursuing negotiations with affiliates of state-owned Petroleos de Venezuela SA on the development of huge reserves of 8--10{degree} gravity crude. Large heavy oil resources are present in the oil producing areas of eastern and western Venezuela, and the largest are in eastern Venezuela`s Orinoco heavy oil belt. The paper discusses the Orinoco heavy oil belt geology and several joint ventures being implemented.

  5. Modeling a set of heavy oil aqueous pyrolysis experiments

    SciTech Connect (OSTI)

    Thorsness, C.B.; Reynolds, J.G.

    1996-11-01

    Aqueous pyrolysis experiments, aimed at mild upgrading of heavy oil, were analyzed using various computer models. The primary focus of the analysis was the pressure history of the closed autoclave reactors obtained during the heating of the autoclave to desired reaction temperatures. The models used included a means of estimating nonideal behavior of primary components with regard to vapor liquid equilibrium. The modeling indicated that to match measured autoclave pressures, which often were well below the vapor pressure of water at a given temperature, it was necessary to incorporate water solubility in the oil phase and an activity model for the water in the oil phase which reduced its fugacity below that of pure water. Analysis also indicated that the mild to moderate upgrading of the oil which occurred in experiments that reached 400{degrees}C or more using a FE(III) 2-ethylhexanoate could be reasonably well characterized by a simple first order rate constant of 1.7xl0{sup 8} exp(-20000/T)s{sup {minus}l}. Both gas production and API gravity increase were characterized by this rate constant. Models were able to match the complete pressure history of the autoclave experiments fairly well with relatively simple equilibria models. However, a consistent lower than measured buildup in pressure at peak temperatures was noted in the model calculations. This phenomena was tentatively attributed to an increase in the amount of water entering the vapor phase caused by a change in its activity in the oil phase.

  6. Influence of uplift on oil migration: Tulare heavy oil accumulations, west side San Joaquin Valley, California

    SciTech Connect (OSTI)

    Chamberlain, E.R.; Madrid, V.M.

    1986-07-01

    Shallow (2000 ft), heavy (11/sup 0/-14/sup 0/ API) oil accumulations within the Pleistocene, nonmarine, Tulare sands along the west side of the San Joaquin Valley represent major thermal enhanced oil recovery (EOR) objectives. These low-pressure reservoirs display a variety of petrophysical characteristics indicating a complex history of oil migration resulting from uplift of the Tulare reservoirs above the regional ground-water table (RGT). In the Cymric-McKittrick area, it is possible to correlate Tulare outcrops with subsurface log data and determine the relationship between oil saturation, structural elevation, and proximity to the present RGT. The observed relationship is that economic oil saturations (S/sub 0/ = 30-75%) occur in structural lows and grade updip to reduced oil saturations (S/sub 0/ = 0-30%). The equivalent sands above the RGT exhibit formation density log-compensated neutron log (FDC/CNL) cross-over. Basinward, as the entire Tulare reservoir dips below the RGT, it exhibits characteristics of conventional reservoirs, such as high water saturations in structural lows, grading upward to increased oil saturations in structural highs. The authors present the following model to explain these observations. (1) Oil migrated into Tulare sands and originally filled all stratigraphic/structural traps below the paleo-RGT. (2) Subsequent uplift of the Tulare reservoirs above the paleo-RGT resulted in gravity drainage of original accumulations into structural lows. (3) Washing of the oils by repeated ground-water fluctuations along with biodegradation resulted in the essentially immobile Tulare heavy oil accumulations observed today.

  7. Gulf Canada donor refined bitumen heavy oil upgrading process

    SciTech Connect (OSTI)

    Fisher, I.P.; Souhrada, F.; Woods, H.J.

    1982-09-01

    The method is a moderate-pressure, noncatalytic alternative which has been shown to be applicable to a wide range of bitumens and heavy oils. It offers the potential of efficiency and reliability at a low capitalized investment and operating cost. The raw distillates are separated from the bitumen or heavy oil and the vacuum residuum is blended with an efficient hydrogen donor stream containing a high proportion of substituted tetralins, and is thermally cracking in the liquid phase. The exhausted donor is recovered from the middle distillate reactor product, reactivated by fixed bed hydrogenation before being recycled to the reactor. The process can be self-sufficient in donor and is independent of the metal content of the feed. The products are blanded with the raw distillates and further hydrogenated to high quality petroleum products. While the primary hydrogen consumption is low, the reconstituted naphtha, distillate and gas oil fractions require less hydrogen than the coker liquids to achieve acceptable refinery feed quality. 1 figure, 9 tables.

  8. Feasibility study of heavy oil recovery in the Midcontinent region (Kansas, Missouri, Oklahoma)

    SciTech Connect (OSTI)

    Olsen, D.K.; Johnson, W.I.

    1993-08-01

    This report is one of a series of publications assessing the feasibility/constraints of increasing domestic heavy oil production. Each report covers a select area of the United States. The Midcontinent (Kansas, Nssouri, Oklahoma) has produced significant oil, but contrary to early reports, the area does not contain the huge volumes of heavy oil that, along with the development of steam and in situ combustion as oil production technologies, sparked the area`s oil boom of the 1960s. Recovery of this heavy oil has proven economically unfeasible for most operators due to the geology of the formations rather than the technology applied to recover the oil. The geology of the southern Midcontinent, as well as results of field projects using thermal enhanced oil recovery (TEOR) methods to produce the heavy oil, was examined based on analysis of data from secondary sources. Analysis of the performance of these projects showed that the technology recovered additional heavy oil above what was produced from primary production from the consolidated, compartmentalized, fluvial dominated deltaic sandstone formations in the Cherokee and Forest City basins. The only projects producing significant economic and environmentally acceptable heavy oil in the Midcontinent are in higher permeability, unconsolidated or friable, thick sands such as those found in south-central Oklahoma. There are domestic heavy oil reservoirs in other sedimentary basins that are in younger formations, are less consolidated, have higher permeability and can be economically produced with current TEOR technology. Heavy oil production from the carbonates of central and wester Kansas has not been adequately tested, but oil production is anticipated to remain low. Significant expansion of Midcontinent heavy oil production is not anticipated because the economics of oil production and processing are not favorable.

  9. Specific heavy oil processing market study. Final report

    SciTech Connect (OSTI)

    Not Available

    1984-06-01

    The market potential for two not-yet-commercialized, proprietary processes for upgrading heavy oil was evaluated. Dynacracking (TM) of Hydrocarbon Research Inc. (HRI) and Aurabon of UOP Process Division (UOP), including an integrated commercial hydrotreating unit were the processes studied. The report concludes that while a large market for Heavy Oil Processing (HOP) units was originally forecast as the result of the shift to heavier crudes by US refiners under a given demand slate and refinery configuration, this market has either eroded due to massive demand shifts (both in volumetric and relative product mix terms) or largely been satisfied on an accelerated basis (due to downstream restructuring pressures) by units already constructed or under firm commitment utilizing other HOP technology. Dynacracking or Aurabon does not appear to offer the substantial economic advantage needed to replace other HOP units already committed. However, additional demands for HOP units couold arise, particularly on a regional basis, if significant additional foreign or domestic sources of heavy crude are introduced into the supply picture or the demand structure moves dramatically away from that currently foreseen by the EIA. Expected profit margins were calculated for both processes, allowing $2/barrel extra credit to the Aurabon products because of their higher quality. Both processes appear to produce about the same fraction of vacuum bottoms when processing the same crude. Dynacracking produces a higher proportion of naphtha and Aurabon produces substantially more heavy distillate. This report is not intended to serve as a basis of selecting either process for a particular installation. 10 references, 7 figures, 29 tables.

  10. Hydroconversion of heavy oil residues with sulfided additives of catalysts

    SciTech Connect (OSTI)

    Le Perchec, P.; Fixari, B.; Vrinat, M.

    1995-12-31

    Improvements in Heavy oils conversion imply sulfur compounds. For medium conversion, side polycondensations and coke production were avoided by Hydrogen diluent donors (HDD), but conversions were partially inhibited. Sulfided radical activators used in association with HDD and H{sub 2} pressure overcome this effect by preventing coke formation up to 50-60% conversion into 500{degrees}C{sup -} light fractions with unchanged quality profile. Deeper conversions require dispersed sulfided catalyst. Phosphomolybdic acid or molybdenum naphtenate have been used as soluble precursors for such treatments. The state and fitness of sulfidation depend on the nature of precursors.

  11. Design considerations for heavy oil in situ pilots

    SciTech Connect (OSTI)

    Peachey, B.R.; Nodwell, J.A.

    1982-01-01

    Although the primary objectives of heavy oil in situ pilots are reservoir oriented in terms of production rate and recovery efficiency, considerable development of surface engineering technology is a necessary aspect of pilot operations. Esso's basic design philosophy is to use state-of-the-art technology with onsite operator interaction to sequentially develop improvements in surface equipment and processes without comprising reservoir based research objectives. This work reviews Esso's operating experience and technical developments in pilot design at Cold Lake, Alta. The considerations which led to the design basis for the Cold Lake commercial project are examined in the areas of well layout, steam and production distribution system design, oil and water separation, and produced water treatment.

  12. A new hydrocracking catalyst for heavy oil upgrading

    SciTech Connect (OSTI)

    Itoh, T. )

    1987-04-01

    In comparison with ordinary oil, tar sands bitumen and vacuum residue contain large quantities of impurities such as asphaltene, heavy metal compounds, sulfur, and nitrogen, which are obstacles to upgrading the refining process. Therefore, these types of materials are extremely difficult to treat with existing refining technologies. In order to upgrade oil feedstocks that are of poor quality, such as tar sands bitumen, new upgrading technologies must be established. In this paper, the author discusses first, the results of catalyst screening, second, the factors of the active catalyst, and finally, the performance of a semi-industrially produced catalyst. The catalyst has high middle-distillate yield, coke plus gum (coke precursors) suppressing ability, low hydrogen consumption and mechanical strength and high temperature stability in slurry reactors.

  13. Slurry catalyst for hydroprocessing heavy and refractory oils

    SciTech Connect (OSTI)

    Lopez, J.; Pasek, E.A.

    1992-03-10

    This patent describes a Group VIB metal sulfide slurry catalyst for the hydroprocessing of heavy hydrocarbonaceous oil or residue prepared by a process. It comprises sulfiding a Group VIB metal, ammonia-containing compound in an aqueous phase, in the substantial absence of hydrocarbon oil, with hydrogen sulfide, at a temperature less than about 350{degrees} F, to form a presulfided product without substantial loss of ammonia; separating ammonia from the presulfided product to form a sulfided product; charging the sulfided product into a hydroprocessing reactor zone at a temperature sufficient to convert the sulfided product into an active hydroprocessing catalyst; wherein the catalyst is characterized by a pore volume in the range of 10 to 300{Angstrom} radius pore size of from about 0.1 to about 1 cc/g and a surface area of from about 20 to about 400 m{sup 2}/g.

  14. Removal of metals from heavy oils with phosphorus - Alumina catalysts

    SciTech Connect (OSTI)

    Kukes, S.G.; Parrott, S.L.; Gardner, L.E. )

    1987-04-01

    Earlier it was found that various oil-soluble phosphorous compounds were active for vanadium removal from different crude oils. The phosphorous compounds preferentially reacted with low molecular weight vanadium species in the resin fraction and therefore the highest rate of vanadium removal was observed when the asphaltene fraction was partially or completely removed. Phosphorous compounds promoted the rate of vanadium removal during hydroprocessing over alumina in a trickle bed reactor. Some metal phosphates were prepared and tested for demetallization activity. Several mixed metal phosphates, such as Cr-Zr, Ni-Zr, Cu-Zr, V-Co-Zr, Fe-Co-Zr, Ni-Co-Zr, etc., exhibited high activity for both vanadium and nickel removal. These catalysts were found to possess HDM activity and activity maintenance comparable to conventional hydrotreating catalysts available commercially. The vanadium removal selectivity of the mixed metal phosphates was similar to that of the commercial catalyst, but much lower than that observed earlier for oil soluble phosphorous compounds. Since the lack of high vanadium selectivity for the mixed metal phosphates could be due to their transition metal component, they investigated the hydroprocessing of heavy oils over aluminas impregnated with different inorganic phosphorous compounds.

  15. Evaluating oil quality and monitoring production from heavy oil reservoirs using geochemical methods: Application to the Boscan Field, Venezuela

    SciTech Connect (OSTI)

    Kaufman, R.L.; Noguera, V.H.; Bantz, D.M.; Rodriguez, R.

    1996-08-01

    Many oil fields worldwide contain heavy oil in one or more reservoir units. The low gravity of these oils is most frequently due to biodegradation and/or low maturity. The challenge is to find ways to economically recover this oil. Methods which reduce the operating costs of producing heavy oil add significant value to such projects. Geochemical techniques which use the composition of the reservoir fluids as natural tracers offer cost effective methods to assist with reservoir management. The low viscosity and gravity of heavy oil, combined with frequent high water cuts, low flow rates, and the presence of downhole artificial lift equipment, make many conventional production logging methods difficult to apply. Therefore, monitoring production, especially if the produced oil is commingled from multiple reservoirs, can be difficult. Geochemical methods can be used to identify oil/water contacts, tubing string leaks and to allocate production to individual zones from commingled production. An example of a giant heavy oil field where geochemical methods may be applicable is the Boscan Field in Venezuela. Low maturity oil, averaging 10{degrees} API gravity, is produced from the Eocene Upper and Lower Boscan (Miosa) Sands. Geochemical, stratigraphic and engineering data have helped to better define the controls on oil quality within the field, identified new reservoir compartments and defined unique characteristics of the Upper and Lower Boscan oils. This information can be used to identify existing wells in need of workovers due to mechanical problems and to monitor production from new infill wells.

  16. Characterization of heavy oil by capillary supercritical fluid chromatography

    SciTech Connect (OSTI)

    Fuhr, B.J.; Holloway, L.R.; Reichert, C.

    1988-06-01

    The characterization of heavy oils and bitumen produced by thermal recovery methods may aid in bringing about the following benefits: improved recovery methods, promotion of upgrading in the reservoir, improved emulsion treatment and optimized use of diluent for transportation. Because of the high proportion of nonvolatile compounds in heavy oils, gas chromatography (GC) is not particularly useful for characterization purposes. High performance liquid chromatography, while capable of analyzing a larger proportion of the nonvolatiles, possesses considerably less resolution than GC. By utilizing mobile phases in their supercritical region it is possible to study compounds that cannot be vaporized for GC analysis, yet still attain the resolution approaching that of GC. Another advantage of supercritical fluid chromatography (SFC) with the commonly used mobile phase CO/sub 2/, is the ability to employ the flame ionization detector (FID) which provides a uniform response over a wide range of compound types. SFC methods used on packed columns are excellent for low resolution separations into hydrocarbon group types and can produce data in about 5 to 15 min. A number of workers have described the use of packed silica columns for the separation and quantitation of saturate and aromatic component types in gasolines and middle distillate fuels, and of saturates, aromatics and polars in high boiling residues. In these studies the mobile phase was CO/sub 2/ and the detector was the FID. Campbell and Lee reported a semi-preparative SFC method using a packed, amino-modified silica column for the separation of aromatics according to the number of rings in a coal tar and a solved refined coal heavy distillate.

  17. Feasibility study of heavy oil recovery in the Permian Basin (Texas and New Mexico)

    SciTech Connect (OSTI)

    Olsen, D.K.; Johnson, W.I.

    1993-05-01

    This report is one of a series of publications assessing the feasibility of increasing domestic heavy oil production. Each report covers select areas of the United States. The Permian Basin of West Texas and Southeastern New Mexico is made up of the Midland, Delaware, Val Verde, and Kerr Basins; the Northwestern, Eastern, and Southern shelves; the Central Basin Platform, and the Sheffield Channel. The present day Permian Basin was one sedimentary basin until uplift and subsidence occurred during Pennsylvanian and early Permian Age to create the configuration of the basins, shelves, and platform of today. The basin has been a major light oil producing area served by an extensive pipeline network connected to refineries designed to process light sweet and limited sour crude oil. Limited resources of heavy oil (10`` to 20`` API gravity) occurs in both carbonate and sandstone reservoirs of Permian and Cretaceous Age. The largest cumulative heavy oil production comes from fluvial sandstones of the Cretaceous Trinity Group. Permian heavy oil is principally paraffinic and thus commands a higher price than asphaltic California heavy oil. Heavy oil in deeper reservoirs has solution gas and low viscosity and thus can be produced by primary and by waterflooding. Because of the nature of the resource, the Permian Basin should not be considered a major heavy oil producing area.

  18. Feasibility study of heavy oil recovery in the Permian Basin (Texas and New Mexico)

    SciTech Connect (OSTI)

    Olsen, D.K.; Johnson, W.I.

    1993-05-01

    This report is one of a series of publications assessing the feasibility of increasing domestic heavy oil production. Each report covers select areas of the United States. The Permian Basin of West Texas and Southeastern New Mexico is made up of the Midland, Delaware, Val Verde, and Kerr Basins; the Northwestern, Eastern, and Southern shelves; the Central Basin Platform, and the Sheffield Channel. The present day Permian Basin was one sedimentary basin until uplift and subsidence occurred during Pennsylvanian and early Permian Age to create the configuration of the basins, shelves, and platform of today. The basin has been a major light oil producing area served by an extensive pipeline network connected to refineries designed to process light sweet and limited sour crude oil. Limited resources of heavy oil (10'' to 20'' API gravity) occurs in both carbonate and sandstone reservoirs of Permian and Cretaceous Age. The largest cumulative heavy oil production comes from fluvial sandstones of the Cretaceous Trinity Group. Permian heavy oil is principally paraffinic and thus commands a higher price than asphaltic California heavy oil. Heavy oil in deeper reservoirs has solution gas and low viscosity and thus can be produced by primary and by waterflooding. Because of the nature of the resource, the Permian Basin should not be considered a major heavy oil producing area.

  19. Heavy oil reservoirs recoverable by thermal technology. Annual report

    SciTech Connect (OSTI)

    Kujawa, P.

    1981-02-01

    This volume contains reservoir, production, and project data for target reservoirs which contain heavy oil in the 8 to 25/sup 0/ API gravity range and are susceptible to recovery by in situ combustion and steam drive. The reservoirs for steam recovery are less than 2500 feet deep to comply with state-of-the-art technology. In cases where one reservoir would be a target for in situ combustion or steam drive, that reservoir is reported in both sections. Data were collectd from three source types: hands-on (A), once-removed (B), and twice-removed (C). In all cases, data were sought depicting and characterizing individual reservoirs as opposed to data covering an entire field with more than one producing interval or reservoir. The data sources are listed at the end of each case. This volume also contains a complete listing of operators and projects, as well as a bibliography of source material.

  20. Dynacracking process first commerical application for upgrading heavy oils

    SciTech Connect (OSTI)

    Dawson, F.N. Jr.

    1981-01-01

    The Dynacracking process developed by Hydrocarbon Research, Inc., is a non-catalytic process capable of upgrading heavy oil whose sulfur, metal, and carbon contents may be high. It converts residual stocks to distillates with high naphtha yields, and to synthetic fuel gas of high quality (700-800 Btu/ft/sup 3/). It has esentially no air polution emissions and requires a relatively small amount of water and utilities. The process generates sufficient heat internally such that, except for start-up, no boilers, furnaces, or external heaters are required to operate the plant. Several aspects of the process are discussed: chemistry, hardware, feedstock, flexibility in the product mix, product quality, and economics.

  1. New noncatalytic heavy-oil process developed in Canada

    SciTech Connect (OSTI)

    Fisher, I.P.; Souhrada, F.; Woods, H.J.

    1982-11-22

    Describes Gulf Canada's hydrogen addition upgrading process, named Donor Refined Bitumen (DRB), which involves the pyrolysis of the residuum portion of the bitumen or heavy oil in the presence of an efficient hydrogen donor that stabilizes the intermediates from the pyrolyzing bitumen. Advantages are high operability and reliability, low capital and operating costs, high yields and good product quality, feedstock and independence, the use of conventional refinery equipment, and ready availability of high quality donor. Presents a schematic flow sheet of the DRB process showing how bitumen is upgraded sufficiently to allow easy pipelining to a central major upgrading plant. Tables give comparative compositional data on middle distillates; naptha compositions and qualities; and operating costs.

  2. Heavy oil reservoirs recoverable by thermal technology. Annual report

    SciTech Connect (OSTI)

    Kujawa, P.

    1981-02-01

    This volume contains reservoir, production, and project data for target reservoirs thermally recoverable by steam drive which are equal to or greater than 2500 feet deep and contain heavy oil in the 8 to 25/sup 0/ API gravity range. Data were collected from three source types: hands-on (A), once-removed (B), and twice-removed (C). In all cases, data were sought depicting and characterizing individual reservoirs as opposed to data covering an entire field with more than one producing interval or reservoir. The data sources are listed at the end of each case. This volume also contains a complete listing of operators and projects, as well as a bibliography of source material.

  3. Increasing Heavy Oil Reserves in the Wilmington Oil Field Through Advanced Reservoir Characterization and Thermal Production Technologies, Class III

    SciTech Connect (OSTI)

    City of Long Beach; Tidelands Oil Production Company; University of Southern California; David K. Davies and Associates

    2002-09-30

    The objective of this project was to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California through the testing and application of advanced reservoir characterization and thermal production technologies. It was hoped that the successful application of these technologies would result in their implementation throughout the Wilmington Field and, through technology transfer, will be extended to increase the recoverable oil reserves in other slope and basin clastic (SBC) reservoirs.

  4. EXPERIMENTAL AND THEORETICAL DETERMINATION OF HEAVY OIL VISCOSITY...

    Office of Scientific and Technical Information (OSTI)

    Language: English Subject: 02 PETROLEUM; 04 OIL SHALES AND TAR SANDS; API GRAVITY; BOILING POINTS; MOLECULAR WEIGHT; OIL SANDS; PETROLEUM; PHYSICAL PROPERTIES; STEAM; TESTING; ...

  5. Heavy oil processing utilizing the dynacracking process. Final report

    SciTech Connect (OSTI)

    Parthasarathy, R.

    1983-01-01

    This report covers preliminary design of a heavy oil conversion unit based on HRI's Dynacracking Process. The unit is designed for operation in any of the six cases described in this report. The six cases presented demonstrate the versatility of the unit to process three different feedstocks with different product objectives and at various process conditions while keeping the reactor configuration and design fixed. The reactor incorporated in the design is identical to the one proposed for a plant to be built in Pittsburg, CA., with California Synfuels Research Corporation as the operator. An evaluative study is presented of the product qualities and possible alternatives for product utilization and upgrading. An indicative summary is made of the quality of effluents from the unit. Estimated utilities and operating requirements are presented. Overall plant material balances are included for each of the six cases. Process equipment duty specifications and offsite tankage requirements are provided and a preliminary cost estimate presented. Basic operating principles (outside the reactor) for smooth plant operation are included. Suggestions plants arrangement and layout are provided. 18 tables.

  6. Residuum and heavy oil upgrading with the CANMET hydrocracking process

    SciTech Connect (OSTI)

    Patmore, D.J.; Khulbe, C.P.; Belinko, K.

    1981-03-01

    The advantages of the CANMET hydrocracking process are: Feed Flexibility - high levels of the main feed contaminants, sulfur, nitrogen and metals do not have a deleterious effect on the process. Hence, a wide range of feedstocks can be upgraded by this process including residuum from conventional crudes; Operability - extended runs indicate that the process will operate continuously with little sensitivity to operational problems even with difficult feedstocks such as Cold Lake and Boscan heavy oil. During extended operation nearly constant pitch conversion and product yields and qualities are obtained; High Distillate Yields - the CANMET Process can produce over 100 vol % distillate, compared to 83 vol % for coking process; Flexibility of Operation - the amount of pitch converted can easily be controlled by adjusting reactor temperature and liquid feed rate. Thus, the required product slate can be obtained by simply changing the operating conditions; Thermal Stability - because the process does not employ an active catalyst, the potential for thermal run-away and development of hot spots is considerably reduced; High Pitch Conversion - the CANMET additive permits sustained controlled and repeatable operation at pitch conversions higher than 90 wt % on a wide range of feedstocks; Reduced Operating Pressure - the action of the additive as a processing aid allows substantial reduction in operating pressure below that for competitive commercial technology; and Efficient Hydrogen Utilization - Since CANMET does not employ an active desulfurizing catalyst, overall hydrogen consumption for a given conversion is low. Almost all of the hydrogen goes to distillate product.

  7. Emissions from Heavy-Duty Diesel Engine with EGR using Oil Sands Derived

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuels | Department of Energy Heavy-Duty Diesel Engine with EGR using Oil Sands Derived Fuels Emissions from Heavy-Duty Diesel Engine with EGR using Oil Sands Derived Fuels 2003 DEER Conference Presentation: National Research Council Canada, Ottawa, Ontario, Canada 2003_deer_neill.pdf (860.57 KB) More Documents & Publications Development of Advanced Combustion Technologies for Increased Thermal Efficiency Biodiesel Research Update Effect of the Composition of Hydrocarbon Streams on HCCI

  8. Hydrotreating Uinta Basin bitumen-derived heavy oils

    SciTech Connect (OSTI)

    Longstaff, D.C.; Balaji, G.V.; Kim, J.W.

    1995-12-31

    Heavy oils derived from Uinta Basin bitumens have been hydrotreated under varying conditions. The process variables investigated included total reactor pressure (11.0-16.9 MPa), reactor temperature (616-711 K), feed rate (0.29-1.38 WHSV), and catalyst composition. The extent of heteroatom removal and residuum conversion were determined by the feed molecular weight and catalyst selection. Catalytic activity for heteroatom conversion removal was primarily influenced by metal loading. The heteroatom removal activity of the catalysts studied were ranked HDN catalysts > HDM catalysts > HDN-support. Catalytic activity for residuum conversion was influenced by both metal loading and catalyst surface area. The residuum conversion activity of HDN catalysts were always higher than the activity of HDM catalysts and HDN supports. The residuum conversion activity of HDN-supports surpassed the activity of HDM catalyst at higher temperatures. The conversions achieved with HDN catalysts relative to the HDM catalysts indicated that the low metals contents of the Uinta Basin bitumens obviate the need for hydrodemetallation as an initial upgrading step with these bitumens. The upgrading of Uinta Basin bitumens for integration into refinery feed slates should emphasize molecular weight and boiling range reduction first, followed by hydrotreating of the total liquid product produced in the pyrolysis process. Kinetics of residuum conversion can be modeled by invoking a consecutive-parallel mechanism in which native residuum in the feed is rapidly converted to volatile products and to product residuum. Deep conversion of residuum is only achieved when the more refractory product residuum is converted to volatile products.

  9. World heavy oil and bitumen riches - update 1983: Part two, production

    SciTech Connect (OSTI)

    Not Available

    1983-06-08

    Despite world recession, overabundance of conventional oil and light product supplies, softer oil prices, and certain important reversals in development policies, worldwide production of heavy and extra-heavy crude oil increased 11.3% in 1982 compared to 1981; latest 1983 data confirm this trend. For the top ten heavy-oil-producing nations, the increase was 17.7% over the same period, mainly due to increases in Venezuela, Mexico, and Nigeria. In 1981, world heavy and extra-heavy crude production was 6.1% of world conventional oil production; in 1982 it increased to 7.2%. Bitumen production in Canada, the only country with 1982 production figures, increased 46% over 1981. It is probable that further technological advances and experimentation in other countries, including the Soviet Union, have resulted in other bitumen production increases as well. Although multinational cooperation in research for extraction, upgrading, and transportation of heavy crudes and bitumens has not grown to the extent that many industry experts had hoped, several broad areas of cooperation stand supported and many of them have been strengthened. Such progress in the face of economic and political uncertainties are demonstrations of world leadership for the next petroleum age. This issue presents the Energy Detente fuel price/tax series and industrial fuel prices for June 1983 for countries of the Eastern Hemisphere.

  10. Formation of coke from heavy crude oils in the presence of calcium carbonate

    SciTech Connect (OSTI)

    Kessick, M. A.; George, Z. M.; Schneider, L. G.

    1985-06-04

    The sulphur emissive capability, on combustion, of coke which is formed during upgrading of sulphur-containing heavy crude oils, including oil sands bitumen, and residua, is decreased by the addition of calcium carbonate, preferably in the form of limestone, to the heavy crude oil prior to coking. The presence of the limestone leads to an increased yield of liquid distillates from the coking process under preferred coking conditions. Ash remaining after combustion of the coke may be leached to recover nickel and vanadium values therefrom.

  11. Increasing Heavy Oil Reserves in the Wilmington Oil Field Through Advanced Reservoir Characterization and Thermal Production Technologies, Class III

    SciTech Connect (OSTI)

    City of Long Beach; Tidelands Oil Production Company; University of Southern California; David K. Davies and Associates

    2002-09-30

    The objective of this project was to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California through the testing and application of advanced reservoir characterization and thermal production technologies. The successful application of these technologies would result in expanding their implementation throughout the Wilmington Field and, through technology transfer, to other slope and basin clastic (SBC) reservoirs.

  12. Inverted fractionation apparatus and use in a heavy oil catalytic...

    Office of Scientific and Technical Information (OSTI)

    cycle oil boiling range hydrocarbons and mixtures thereof into liquid product fractions, ... Subject: 02 PETROLEUM; PETROLEUM; CATALYTIC CRACKING; PETROLEUM FRACTIONS; VISCOSITY; ...

  13. In situ method for recovering hydrocarbon from subterranean oil shale deposits

    SciTech Connect (OSTI)

    Friedman, R.H.

    1987-11-03

    This patent describes in situ method for recovering hydrocarbons from subterranean oil shale deposits, the deposits comprising mineral rock and kerogen, comprising (a) penetrating the oil shale deposit with at least one well; (b) forming a zone of fractured and/or rubbilized oil shale material adjacent the well by hydraulic or explosive fracturing; (c) introducing a hydrogen donor solvent including tetralin into the portion of the oil shale formation treated in step (b) in a volume sufficient to fill substantially all of the void space created by the fracturing and rubbilizing treatment; (d) applying hydrogen to the tetralin and maintaining a predetermined pressure for a predetermined period of time sufficient to cause disintegration of the oil shale material; (e) thereafter introducing an oxidative environment into the portion of the oil shale deposit (f) producing the solvent in organic fragments to the surface of the earth, and (g) separating the organic fragments from the solvent.

  14. Upgrading heavy oils by non-catalytic treatment with hydrogen and hydrogen transfer solvent

    SciTech Connect (OSTI)

    Derbyshire, F.J.; Mitchell, T.O.; Whitehurst, D.D.

    1981-09-29

    Heavy liquid hydrocarbon oil, such as petroleum derived tars, predominantly boiling over 425/sup 0/C, are upgraded to products boiling below 425/sup 0/C, without substantial formation of insoluble char, by heating the heavy oil with hydrogen and a hydrogen transfer solvent in the absence of hydrogenation catalyst at temperatures of about 320/sup 0/C to 500/sup 0/C, and a pressure of 20 to 180 bar for 3 to 30 minutes. The hydrogen transfer solvents polycyclic compounds free of carbonyl groups, e.g., pyrene, and have a polarographic reduction potential which is less negative than phenanthrene and equal to or more negative than azapyrene.

  15. Process and economic model of in-field heavy oil upgrading using aqueous pyrolysis

    SciTech Connect (OSTI)

    Thorsness, C. B., LLNL

    1997-01-21

    A process and economic model for aqueous pyrolysis in-field upgrading of heavy oil has been developed. The model has been constructed using the ASPEN PLUS chemical process simulator. The process features cracking of heavy oil at moderate temperatures in the presence of water to increase oil quality and thus the value of the oil. Calculations with the model indicate that for a 464 Mg/day (3,000 bbl/day) process, which increases the oil API gravity of the processed oil from 13.5{degree} to 22.4{degree}, the required value increase of the oil would need to be at least $2.80/Mg{center_dot}{degree}API($0.40/bbl{center_dot}{degree}API) to make the process economically attractive. This level of upgrading has been demonstrated in preliminary experiments with candidate catalysts. For improved catalysts capable of having the coke make and increasing the pyrolysis rate, a required price increase for the oil as low as $1.34/Mg{center_dot}{degree}API ($0.21/bbl{center_dot}{degree}API)has been calculated.

  16. Use of hydrogen-free carbon monoxide with steam in recovery of heavy oil at low temperatures

    SciTech Connect (OSTI)

    Hyne, J. B.; Tyrer, J. D.

    1984-12-11

    A process for recovering oil from a subterranean heavy oil-containing reservoir is provided, wherein steam and carbon monoxide are injected into the reservoir at a temperature less than about 260/sup 0/ C. At these low temperatures, the steam and hydrogen-free carbon monoxide are found to react in the reservoir, by the water gas reaction, to form carbon dioxide and hydrogen. These products both have upgrading effects on the heavy oil, enhancing its quality and producibility. At the low temperatures of the process, gasification and polymerization of the heavy oil are minimized.

  17. Use of multiphase pumps in heavy and extra heavy oil production

    SciTech Connect (OSTI)

    Gonzalez, R.; Guevara, E.M.; Colmenares, J.D.

    1995-12-31

    The main results of a technical and economical feasibility study carried out to analyze the application of multiphase flow technologies in the production of heavy and extra heavy crudes from the Arecuna Field of Corpoven, S.A. in the Orinoco Belt, Venezuela, are presented. It was found that flow stations based on multiphase technologies such as multiphase pumping and metering were the most adequate both technically and economically.

  18. Transport and Phase Equilibria Properties for Steam Flooding of Heavy Oils

    SciTech Connect (OSTI)

    Gabitto, Jorge; Barrufet, Maria

    2002-11-20

    The objectives of this research included experimental determination and rigorous modeling and computation of phase equilibrium diagrams, volumetric, and transport properties of hydrocarbon/CO2/water mixtures at pressures and temperatures typical of steam injection processes for thermal recovery of heavy oils.

  19. Heavy Oil Database from the National Institute for Petroleum and Energy Research (NIPER)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Heavy Oil Database resulted from work funded by DOE and performed at the National Institute for Petroleum and Energy Research (NIPER). It contains information on more than 500 resevoirs in a Microsoft Excel spreadsheet. The information was collected in 1992 and updated periodically through 2003. Save the zipped file to your PC, then open to access the data.

  20. Fluid and Rock Property Controls On Production And Seismic Monitoring Alaska Heavy Oils

    SciTech Connect (OSTI)

    Liberatore, Matthew; Herring, Andy; Prasad, Manika; Dorgan, John; Batzle, Mike

    2012-10-30

    The goal of this project is to improve recovery of Alaskan North Slope (ANS) heavy oil resources in the Ugnu formation by improving our understanding of the formation's vertical and lateral heterogeneities via core evaluation, evaluating possible recovery processes, and employing geophysical monitoring to assess production and modify production operations.

  1. Method and apparatus for recovery of oil, gas and mineral deposits by panel opening

    SciTech Connect (OSTI)

    Wang, F. D.

    1984-10-30

    A method for oil, gas and mineral recovery by panel opening drilling including providing spaced injection and recovery drill holes which respectively straddle a deposit bearing underground region, each drill hole including a panel shaped opening substantially facing the deposit bearing region and injecting the injection hole with a fluid under sufficient pressure to uniformly sweep the deposits in the underground region to the recovery hole for recovery of the deposits therefrom. An apparatus for creating such panel shaped is also provided.

  2. Heavy oil and coal conversion via the Aurabon process

    SciTech Connect (OSTI)

    Luebke, C.P.; Humbach, M.J.; Thompson, G.J.; Gatsis, J.G.

    1986-01-01

    Although time estimates vary, all forecasts point to a reduction in the availability of light crude oils. As the light crude supplies diminish, the role of resid upgrading in the refinery flow scheme must increase to allow the refinery the ability to convert heavier crudes into transportation fuels.

  3. Application of electrical submersible pumps in heavy crude oil in Boscan Field

    SciTech Connect (OSTI)

    Bortolin, L.L.

    1995-12-31

    During recent years optimization of artificial lift methods has been applied in the oil industry, in order to evaluate the effect on oil well production and to establish a company`s optimal investment policies. Higher costs on new artificial lifting equipment and facilities for new fields have created the necessity to review the latest available technology of different lifting methods and specially that related to electrical submersible pumps (ESP). Few studies in the area of heavy crude oil production optimization using ESP as a lifting method have been published. This paper discusses the results of an ESP pilot project performed in 24 wells in Boscan field, and analyzes the performance of the equipment and its application range. The ESP equipment was installed in completions at depths ranging from 7000 to 9000 feet, with a 10{degrees}API gravity crude and bottomhole temperature of 180{degrees}F. It was concluded that despite a reduction of the pump`s efficiency, the ESP equipment does qualify as a good alternative lifting method for heavy oil production. It is also possible to obtain higher production rates. The results obtained in this pilot project, confirm that submersible pumps are an alternative method for lifting heavy crude oil from relatively deep reservoirs.

  4. Investigation of Multiscale and Multiphase Flow, Transport and Reaction in Heavy Oil Recovery Processes

    SciTech Connect (OSTI)

    Yortsos, Y.C.

    2001-05-29

    This report is an investigation of various multi-phase and multiscale transport and reaction processes associated with heavy oil recovery. The thrust areas of the project include the following: Internal drives, vapor-liquid flows, combustion and reaction processes, fluid displacements and the effect of instabilities and heterogeneities and the flow of fluids with yield stress. These find respective applications in foamy oils, the evolution of dissolved gas, internal steam drives, the mechanics of concurrent and countercurrent vapor-liquid flows, associated with thermal methods and steam injection, such as SAGD, the in-situ combustion, the upscaling of displacements in heterogeneous media and the flow of foams, Bingham plastics and heavy oils in porous media and the development of wormholes during cold production.

  5. Investigation of Multiscale and Multiphase Flow, Transport and Reaction in Heavy Oil Recovery Processes

    SciTech Connect (OSTI)

    Yortsos, Yanis C.

    2001-08-07

    This project is an investigation of various multi-phase and multiscale transport and reaction processes associated with heavy oil recovery. The thrust areas of the project include the following: Internal drives, vapor-liquid flows, combustion and reaction processes, fluid displacements and the effect of instabilities and heterogeneities and the flow of fluids with yield stress. These find respective applications in foamy oils, the evolution of dissolved gas, internal steam drives, the mechanics of concurrent and countercurrent vapor-liquid flows, associated with thermal methods and steam injection, such as SAGD, the in-situ combustion, the upscaling of displacements in heterogeneous media and the flow of foams, Bingham plastics and heavy oils in porous media and the development of wormholes during cold production.

  6. Transformation of Resources to Reserves: Next Generation Heavy-Oil Recovery Techniques

    SciTech Connect (OSTI)

    Stanford University; Department of Energy Resources Engineering Green Earth Sciences

    2007-09-30

    This final report and technical progress report describes work performed from October 1, 2004 through September 30, 2007 for the project 'Transformation of Resources to Reserves: Next Generation Heavy Oil Recovery Techniques', DE-FC26-04NT15526. Critical year 3 activities of this project were not undertaken because of reduced funding to the DOE Oil Program despite timely submission of a continuation package and progress on year 1 and 2 subtasks. A small amount of carried-over funds were used during June-August 2007 to complete some work in the area of foamed-gas mobility control. Completion of Year 3 activities and tasks would have led to a more thorough completion of the project and attainment of project goals. This progress report serves as a summary of activities and accomplishments for years 1 and 2. Experiments, theory development, and numerical modeling were employed to elucidate heavy-oil production mechanisms that provide the technical foundations for producing efficiently the abundant, discovered heavy-oil resources of the U.S. that are not accessible with current technology and recovery techniques. Work fell into two task areas: cold production of heavy oils and thermal recovery. Despite the emerging critical importance of the waterflooding of viscous oil in cold environments, work in this area was never sanctioned under this project. It is envisioned that heavy oil production is impacted by development of an understanding of the reservoir and reservoir fluid conditions leading to so-called foamy oil behavior, i.e, heavy-oil solution gas drive. This understanding should allow primary, cold production of heavy and viscous oils to be optimized. Accordingly, we evaluated the oil-phase chemistry of crude oil samples from Venezuela that give effective production by the heavy-oil solution gas drive mechanism. Laboratory-scale experiments show that recovery correlates with asphaltene contents as well as the so-called acid number (AN) and base number (BN) of the

  7. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2001-06-27

    The objective of this project is to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California through the testing and application of advanced reservoir characterization and thermal production technologies. The successful application of these technologies will result in expanding their implementation throughout the Wilmington Field and, through technology transfer, to other slope and basin clastic (SBC) reservoirs. The existing steamflood in the Tar zone of Fault Block II-A (Tar II-A) has been relatively inefficient because of several producibility problems which are common in SBC reservoirs: inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil and non-uniform distribution of the remaining oil. This has resulted in poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. A suite of advanced reservoir characterization and thermal production technologies are being applied during the project to improve oil recovery and reduce operating costs.

  8. Increasing Heavy Oil Reserves in the Wilmington Oil Field through Advanced Reservoir Characterization and Thermal Production Technologies

    SciTech Connect (OSTI)

    City of Long Beach; David K.Davies and Associates; Tidelands Oil Production Company; University of Southern California

    1999-06-25

    The objective of this project is to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California. This is realized through the testing and application of advanced reservoir characterization and thermal production technologies. It is hoped that the successful application of these technologies will result in their implementation throughout the Wilmington Field and through technology transfer, will be extended to increase the recoverable oil reserves in other slope and basin clastic (SBC) reservoirs. The existing steamflood in the Tar zone of Fault Block (FB) II-A has been relatively insufficient because of several producability problems which are common in SBC reservoir; inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil and non-uniform distribution of the remaining oil. This has resulted in poor sweep efficiency, high steam-oil ratios, and early breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves.

  9. Nuclear-energy application studied as source of injection steam for heavy-oil recovery

    SciTech Connect (OSTI)

    Perrett, R.J.; Gledhill, P.R.; Dawson, P.; Stephenson, D.J.

    1981-08-03

    This study into the feasibility of adapting a well-proven nuclear reactor as a centralized source of injection steam for the recovery of heavy oil has shown that the reactor modifications are practicable and well within the bounds of current technology. The gas-cooled reactor is capable of meeting the highest steam supply pressure requirement and it possesses a high degree of inherent safety. The injection of steam for the recovery of heavy oil is the most well developed of the available options. At current price levels of oil and uranium, nuclear heat can be generated at a fraction of the running costs of oil fired thermal plant. Taken over a project lifetime of 25 years for the field model used for this assessment, the improved earnings for the nuclear option could amount to as much as /10 billion. The program requirements for a typical development have been examined and the construction times for the gas reactor steam plant, the oil-field development and the upgrading plant are compatible at between five and six years. The economic advantage of steam generation by nuclear energy gives a further recovery breakthrough. It becomes possible to continue the steam drive process up to much more adverse recovery ratios of steam quantity injected for unit oil produced if nuclear energy is employed.

  10. Evaluation of solvent-based in situ processes for upgrading and recovery of heavy oil bitumen

    SciTech Connect (OSTI)

    Duerksen, J.H.; Eloyan, A.

    1995-12-31

    Solvent-based in situ recovery processes have been proposed as lower cost alternatives to thermal processes for recovery of heavy oil and bitumen. Advantages of solvent based processes are: reduced steam requirements, reduced water treating, and in situ upgrading of the produced oil. Lab results and process calculations show that low-pressure, low-energy solvent-based in situ processes have considerable technical and economic potential for upgrading and recovery of bitumen and heavy oil. In a lab flow test using Athabasca tar sand and propane as solvent, 50 percent of the bitumen was recovered as upgraded oil. Relative to the raw bitumen, API gravity increased by about 10{degrees}API, viscosity was reduced 30-fold, sulfur content was reduced about 50 percent, and metals content was also substantially reduced. Process uncertainties that will have a major impact on economics are: (1) oil production rate, (2) oil recovery, (3) extent of in situ upgrading, and (4) solvent losses. Additional lab development and field testing are required to reduce these process uncertainties and to predict commercial-scale economics.

  11. Beneficiation of oil shales by froth flotation and heavy media separation: Volume 1, Summary and main report: Final report

    SciTech Connect (OSTI)

    Krishnan, G.N.

    1987-08-01

    An experimental program was conducted to determine the feasibility of upgrading US oil shales by froth flotation and heavy media separation (HMS) techniques. The results of the experiments along with other available information were used to analyze technical and economic aspects of a process scheme in which a mined shale will be beneficiated and then retorted. The experimental program and economic analysis indicate that whereas beneficiation processes do not offer any clear incentive at the current time, these processes may become essential when lean deposits are to be exploited. Froth flotation process appears to be significantly superior than the HMS process. The significant deterrents to developing a beneficiation process based on froth flotation are grinding costs and lack of suitable retorts. 15 refs., 13 figs., 13 tabs.

  12. Catalysts deactivation during the hydrotreatment of heavy oils

    SciTech Connect (OSTI)

    Mochida, I.; Zhao, Z.Z.; Sakanishi, K. )

    1988-06-01

    The catalyst deactivation in the repeated hydrotreatments of asphaltene in petroleum residues, coal liquids and their mixture was comparatively studied in the single- and two-stage reactions, using the same commercial Ni-Mo/Al{sub 2}O{sub 3} catalysts in the batch autoclave. The less catalyst deactivation as well as higher performances in the denitrogenation (>80%) and upgrading of coal liquid were obtained in the two-stage hydrotreatment of 390{degree}C-2h and 430{degree}C-2h. The increase of the catalyst weight which causes the decrease of the activity was considerably less in the two-stage reaction. The two-stage hydrotreatment, which allows a combination of best catalysts in the respective stages under most appropriate conditions for their best performances, can be further effective in the upgrading of heavy residual hydrocarbons.

  13. VEBA-cracking-processes for upgrading heavy oils and refinery residues

    SciTech Connect (OSTI)

    Graeser, U.; Niemann, K.

    1983-03-01

    More than 20 different heavy oils and residues have been processed by the VEBA-Combi-Cracking and VEBA-LQ-Cracking high pressure hydrocracking processes, in a bench scale unit. Conversions up to 99 wt % of to a syncrude, consisting of naphtha middle distillate and vacuum gas oil were obtained. Conversions correlate with space velocity at a given temperature and product pattern depends upon degree of conversion. The VEBA-LQ-Cracking process produces a stable syncrude whereas the products of the VEBA-Combi process are very low in sulfur and nitrogen.

  14. Hydrofining of Athabasca derived heavy gas oil over Ni-W and Co-Mo catalysts

    SciTech Connect (OSTI)

    Mann, R.S.; Diaz-real, R.

    1987-01-01

    The hydrotreatment of heavy gas oil derived from Athabasca bitumen was studied in a trickle bed reactor over Ni-W and Co-Mo zeolite catalyst at 350-425/sup 0/C, 3.55 to 10.44 MPa, and LHSV of 1-4. The effects of temperature and liquid flow rates on the product were investigated. ASTM distillation, aniline point, viscosities and densities of the product oil were measured and correlated with various parameters. Activity of the catalysts for hydrodenitrogenation is compared.

  15. Investigation of Multiscale and Multiphase Flow, Transport and Reaction in Heavy Oil Recovery Processes

    SciTech Connect (OSTI)

    Yortsos, Yanis C.

    2002-10-08

    In this report, the thrust areas include the following: Internal drives, vapor-liquid flows, combustion and reaction processes, fluid displacements and the effect of instabilities and heterogeneities and the flow of fluids with yield stress. These find respective applications in foamy oils, the evolution of dissolved gas, internal steam drives, the mechanics of concurrent and countercurrent vapor-liquid flows, associated with thermal methods and steam injection, such as SAGD, the in-situ combustion, the upscaling of displacements in heterogeneous media and the flow of foams, Bingham plastics and heavy oils in porous media and the development of wormholes during cold production.

  16. Removal of heavy metal ions from oil shale beneficiation process water by ferrite process

    SciTech Connect (OSTI)

    Mehta, R.K.; Zhang, L.; Lamont, W.E.; Schultz, C.W.

    1991-12-31

    The ferrite process is an established technique for removing heavy metals from waste water. Because the process water resulting from oil shale beneficiation falls into the category of industrial waste water, it is anticipated that this process may turn out to be a potential viable treatment for oil shale beneficiation process water containing many heave metal ions. The process is chemoremedial because not only effluent water comply with quality standards, but harmful heavy metals are converted into a valuable, chemically stable by-product known as ferrite. These spinel ferrites have magnetic properties, and therefore can be use in applications such as magnetic marker, ferrofluid, microwave absorbing and scavenging material. Experimental results from this process are presented along with results of treatment technique such as sulfide precipitation.

  17. Removal of heavy metal ions from oil shale beneficiation process water by ferrite process

    SciTech Connect (OSTI)

    Mehta, R.K.; Zhang, L.; Lamont, W.E.; Schultz, C.W. . Mineral Resources Inst.)

    1991-01-01

    The ferrite process is an established technique for removing heavy metals from waste water. Because the process water resulting from oil shale beneficiation falls into the category of industrial waste water, it is anticipated that this process may turn out to be a potential viable treatment for oil shale beneficiation process water containing many heave metal ions. The process is chemoremedial because not only effluent water comply with quality standards, but harmful heavy metals are converted into a valuable, chemically stable by-product known as ferrite. These spinel ferrites have magnetic properties, and therefore can be use in applications such as magnetic marker, ferrofluid, microwave absorbing and scavenging material. Experimental results from this process are presented along with results of treatment technique such as sulfide precipitation.

  18. Heavy oil reservoirs in the Tulare Fold Belt, Cymric-McKittrick fields, Kern County, California

    SciTech Connect (OSTI)

    Farley, T. )

    1990-05-01

    The Tulare fold belt is a series of asymmetric, generally northeast-verging anticlines and synclines in the Pliocene-Pleistocene Tulare Formation that trend northwestward through the Cymric-McKittrick fields. Anticlines within the deformed belt generally originated as fault propagation folds above decollements, the most important of which is the regional decollement on top of the Amnicola sand, the basal Tulare unit. The Amnicola decollement is the northeast subsurface extension of the McKittrick thrust, a low-angle fault that has displaced the Miocene Antelope shale over the Pliocene San Joaquin Formation and locally over the Tulare Formation. The Amnicola decollement is itself deformed by folding related to a younger, deeper decollement near the base of the San Joaquin Formation that merges westward with the Amnicola decollement and defines a zone of faulting associated with the McKittrick thrust Heavy oil reservoirs in the Tulare Formation are currently undergoing active development by thermal recovery techniques. In general, the geometry of heavy oil reservoirs is determined by location within the Tulare fold belt combined with the position of a subhorizontal fluid level trap that forms the updip limit of fluid-saturated rock Reservoir geometry is complicated by complex local structure, discontinuous stratigraphy, and partial depletion of heavy oil reservoirs by fluid withdrawal due to gravity drainage. Proper resolution of fold geometry, fault geometry, and position of the fluid level trap is crucial to the design and monitoring of thermal recovery projects within the Tulare fold belt.

  19. Thermal upgrading of residual oil to light product and heavy residual fuel

    SciTech Connect (OSTI)

    Yan, T.Y.; Shu, P.

    1986-08-05

    The method is described of upgrading residual oil boiling in the range of 1050/sup 0/F+ comprising: thermally cracking the residual oil at a temperature of 650/sup 0/-900/sup 0/F, a pressure of 0-100 psig, and a residence time of 0.1 to 5 hours at the highest severity in the range between about 1,000-18,000 seconds, as expressed in equivalent reaction time at 800/sup 0/F, sufficient to convert at least about 50 wt% of the residual oil to light products, substantially without the formation of solid coke; recovering separate fractions of light product and emulsifiable heavy bottom product which has a fusion temperature below about 150/sup 0/C and a quinoline-insoluble content between about 10 wt% and 30 wt% and wherein the highest severity is determined by a functional relationship between the asphaltene content of the residual oil feedstock and the heavy bottom product yield and quinoline-insoluble content.

  20. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Unknown

    2001-08-08

    The objective of this project is to increase the recoverable heavy oil reserves within sections of the Wilmington Oil Field, near Long Beach, California, through the testing and application of advanced reservoir characterization and thermal production technologies. The hope is that successful application of these technologies will result in their implementation throughout the Wilmington Field and, through technology transfer, will be extended to increase the recoverable oil reserves in other slope and basin clastic (SBC) reservoirs. The existing steamflood in the Tar zone of Fault Block II-A (Tar II-A) has been relatively inefficient because of several producibility problems which are common in SBC reservoirs: inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil and non-uniform distribution of the remaining oil. This has resulted in poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. A suite of advanced reservoir characterization and thermal production technologies are being applied during the project to improve oil recovery and reduce operating costs, including: (1) Development of three-dimensional (3-D) deterministic and stochastic reservoir simulation models--thermal or otherwise--to aid in reservoir management of the steamflood and post-steamflood phases and subsequent development work. (2) Development of computerized 3-D visualizations of the geologic and reservoir simulation models to aid reservoir surveillance and operations. (3) Perform detailed studies of the geochemical interactions between the steam and the formation rock and fluids. (4) Testing and proposed application of a

  1. Use of coal liquefaction catalysts for coal/oil coprocessing and heavy oil upgrading

    SciTech Connect (OSTI)

    Cugini, A.V.; Krastman, D.; Thompson, R.L.; Gardner, T.J.; Ciocco, M.V.

    1997-04-01

    The catalytic hydrogenation of coal and model solvents using dispersed or supported catalysts at different pressures has been the focus of several recent studies at PETC. The effectiveness of these catalysts has been studied in coal liquefaction and coal-oil coprocessing. Coal-oil coprocessing involves the co-reaction of coal and petroleum-derived oil or resid. The results of these studies have indicated that both dispersed and supported catalysts are effective in these systems at elevated H{sub 2} pressures ({approximately}2,500 psig). Attempts to reduce pressure indicated that a combination of catalyst concentration and solvent quality could be used to compensate for reductions in H{sub 2} pressure. Comparison of the coal and coprocessing systems reveals many similarities in the catalytic requirements for both systems. Both hydrogenation and hydrogenolysis activities are required and the reactive environments are similar. Also, the use of catalysts in the two systems shares problems with similar types of inhibitors and poisons. The logical extension of this is that it may be reasonable to expect similar trends in catalyst activity for both systems. In fact, many of the catalysts selected for coal liquefaction were selected based on their effectiveness in petroleum systems. This study investigates the use of supported and dispersed coal liquefaction catalysts in coal-oil coprocessing and petroleum-only systems. The focus of the study was delineating the effects of coal concentration, pressure, and catalyst type.

  2. New short contact time processes upgrade residual oils and heavy crudes

    SciTech Connect (OSTI)

    Not Available

    1991-08-12

    This paper reports on new short contact time carbon rejection technology developed for upgrading residual oils and converting heavier crudes into high-quality synthetic crudes. The process, called discriminatory destructive distillation, or 3D, has been demonstrated in a Kansas refinery on feedstocks ranging from 13.5 to 30.6{degrees} API. For the past year, Coastal Derby Refining Co. has been operating a revolutionary, according to Bartholic, circulating fluid solids processing apparatus that can be run as either a 3D process unit, to virtually eliminate the residual oil component of crude, or as an MSCC process unit, to upgrade VGO residual oils. Because both of these processes circulate a fluid solid in a manner similar to the well known and commercially accepted fluid catalytic cracking (FCC) process, existing FCC-type units can be easily and economically converted to either 3D or MSCC operation. The 3D process is a low-pressure, carbon-rejection residual oil treating process for preparation of gas oils for fluid catalytic cracking (or MSCC), hydrotreating, mild hydrocracking, or full hydrocracking, says Bartholic. The process is also applicable, he says to upgrading heavy crudes or tar sands bitumen to high-quality reconstituted crudes for world markets.

  3. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2004-03-05

    The overall objective of this project is to increase heavy oil reserves in slope and basin clastic (SBC) reservoirs through the application of advanced reservoir characterization and thermal production technologies. The project involves improving thermal recovery techniques in the Tar Zone of Fault Blocks II-A and V (Tar II-A and Tar V) of the Wilmington Field in Los Angeles County, near Long Beach, California. A primary objective is to transfer technology which can be applied in other heavy oil formations of the Wilmington Field and other SBC reservoirs, including those under waterflood. The thermal recovery operations in the Tar II-A and Tar V have been relatively inefficient because of several producibility problems which are common in SBC reservoirs. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. The advanced technologies to be applied include: (1) Develop three-dimensional (3-D) deterministic and stochastic geologic models. (2) Develop 3-D deterministic and stochastic thermal reservoir simulation models to aid in reservoir management and subsequent development work. (3) Develop computerized 3-D visualizations of the geologic and reservoir simulation models to aid in analysis. (4) Perform detailed study on the geochemical interactions between the steam and the formation rock and fluids. (5) Pilot steam injection and production via four new horizontal wells (2 producers and 2 injectors). (6) Hot water alternating steam (WAS) drive pilot in the

  4. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2003-09-04

    The overall objective of this project is to increase heavy oil reserves in slope and basin clastic (SBC) reservoirs through the application of advanced reservoir characterization and thermal production technologies. The project involves improving thermal recovery techniques in the Tar Zone of Fault Blocks II-A and V (Tar II-A and Tar V) of the Wilmington Field in Los Angeles County, near Long Beach, California. A primary objective is to transfer technology which can be applied in other heavy oil formations of the Wilmington Field and other SBC reservoirs, including those under waterflood. The thermal recovery operations in the Tar II-A and Tar V have been relatively inefficient because of several producibility problems which are common in SBC reservoirs. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. The advanced technologies to be applied include: (1) Develop three-dimensional (3-D) deterministic and stochastic geologic models. (2) Develop 3-D deterministic and stochastic thermal reservoir simulation models to aid in reservoir management and subsequent development work. (3) Develop computerized 3-D visualizations of the geologic and reservoir simulation models to aid in analysis. (4) Perform detailed study on the geochemical interactions between the steam and the formation rock and fluids. (5) Pilot steam injection and production via four new horizontal wells (2 producers and 2 injectors). (6) Hot water alternating steam (WAS) drive pilot in the

  5. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2003-06-04

    The overall objective of this project is to increase heavy oil reserves in slope and basin clastic (SBC) reservoirs through the application of advanced reservoir characterization and thermal production technologies. The project involves improving thermal recovery techniques in the Tar Zone of Fault Blocks II-A and V (Tar II-A and Tar V) of the Wilmington Field in Los Angeles County, near Long Beach, California. A primary objective is to transfer technology which can be applied in other heavy oil formations of the Wilmington Field and other SBC reservoirs, including those under waterflood. The thermal recovery operations in the Tar II-A and Tar V have been relatively inefficient because of several producibility problems which are common in SBC reservoirs. Inadequate characterization of the heterogeneous turbidite sands, high permeability thief zones, low gravity oil, and nonuniform distribution of remaining oil have all contributed to poor sweep efficiency, high steam-oil ratios, and early steam breakthrough. Operational problems related to steam breakthrough, high reservoir pressure, and unconsolidated formation sands have caused premature well and downhole equipment failures. In aggregate, these reservoir and operational constraints have resulted in increased operating costs and decreased recoverable reserves. The advanced technologies to be applied include: (1) Develop three-dimensional (3-D) deterministic and stochastic geologic models. (2) Develop 3-D deterministic and stochastic thermal reservoir simulation models to aid in reservoir management and subsequent development work. (3) Develop computerized 3-D visualizations of the geologic and reservoir simulation models to aid in analysis. (4) Perform detailed study on the geochemical interactions between the steam and the formation rock and fluids. (5) Pilot steam injection and production via four new horizontal wells (2 producers and 2 injectors). (6) Hot water alternating steam (WAS) drive pilot in the

  6. Development of the Write Process for Pipeline-Ready Heavy Oil

    SciTech Connect (OSTI)

    Lee Brecher; Charles Mones; Frank Guffey

    2009-03-07

    Work completed under this program advances the goal of demonstrating Western Research Institute's (WRI's) WRITE{trademark} process for upgrading heavy oil at field scale. MEG Energy Corporation (MEG) located in Calgary, Alberta, Canada supported efforts at WRI to develop the WRITE{trademark} process as an oil sands, field-upgrading technology through this Task 51 Jointly Sponsored Research project. The project consisted of 6 tasks: (1) optimization of the distillate recovery unit (DRU), (2) demonstration and design of a continuous coker, (3) conceptual design and cost estimate for a commercial facility, (4) design of a WRITE{trademark} pilot plant, (5) hydrotreating studies, and (6) establish a petroleum analysis laboratory. WRITE{trademark} is a heavy oil and bitumen upgrading process that produces residuum-free, pipeline ready oil from heavy material with undiluted density and viscosity that exceed prevailing pipeline specifications. WRITE{trademark} uses two processing stages to achieve low and high temperature conversion of heavy oil or bitumen. The first stage DRU operates at mild thermal cracking conditions, yielding a light overhead product and a heavy residuum or bottoms material. These bottoms flow to the second stage continuous coker that operates at severe pyrolysis conditions, yielding light pyrolyzate and coke. The combined pyrolyzate and mildly cracked overhead streams form WRITE{trademark}'s synthetic crude oil (SCO) production. The main objectives of this project were to (1) complete testing and analysis at bench scale with the DRU and continuous coker reactors and provide results to MEG for process evaluation and scale-up determinations and (2) complete a technical and economic assessment of WRITE{trademark} technology to determine its viability. The DRU test program was completed and a processing envelope developed. These results were used for process assessment and for scaleup. Tests in the continuous coker were intended to determine the

  7. VEBA-Combi-cracking - A technology for upgrading of heavy oils and bitumen

    SciTech Connect (OSTI)

    Doehler, W.; Kretschmar, D.I.K.; Merz, L.; Niemann, K. )

    1987-04-01

    Based on experiences with liquid phase hydrogenation for coal liquefaction according to the Berguis-Pier-Process as well as crude oil residue hydrogenation in the Fifties and Sixties, VEBA OEL in recent years developed the VEBA-LQ-Cracking (VLC) and the VEBA-Combi-Cracking (VCC) Processes. Since 1978, more than 20 different feedstocks have been converted in small scale plants with a capacity of 3-20 kg/h. Together with LURGI GmbH, Frankfurt, the next steps were taken: the design and construction of a 1 t/h Pilot Plant located at the RUHR OEL refinery in Gelsenkirchen. After 18 months of construction, the heavy oil pilot plant was put on stream in May 1983. Since the beginning of 1983, the plant has been funded and owned by LURGI GmbH, VEBA OEL AG and INTEVEP S.A., the research institute of Petroleos de Venezuela, all of whom have participated in the development of the VLC/VCC process. Reported here are the results of the intensive experimental work for the development of the VLC/VCC-processes in a scale covering all aspects relevant for a scale-up, demonstrate the technical maturity of the processes developed by VEBA OEL to convert refinery residues and natural heavy crude oils.

  8. The Use of TaBoRR as a Heavy Oil Upgrader

    SciTech Connect (OSTI)

    Lee Brecher; Charles Mones

    2009-02-05

    Preliminary testing has shown that Western Research Institute's (WRI) Tank Bottom Recovery and Remediation (TaBoRR{reg_sign}) technology shows promise for heavy oil upgrading. Approximately 70 to 75 wt% of a Canadian Cold Lake bitumen feed was converted to a partially upgraded overhead product that could be transported directly by pipeline or blended with the parent bitumen to produce transportable crude. TaBoRR{reg_sign} was originally developed to remediate tank bottom wastes by producing a distillate product and solid waste. TaBoRR{reg_sign}'s processing steps include breaking a water-oil emulsion, recovering a light hydrocarbon fraction by distillation in a stripper unit, and pyrolyzing the residua reducing it to additional overhead and a benign coke for disposal. Cold Lake bitumen was tested in WRI's bench-scale equipment to evaluate the potential use of TaBoRR{reg_sign} technology for heavy oil upgrading to produce a stable, partially (or fully) upgraded product that will allow diluent-reduced or diluent-free transportation of bitumen or ultra-heavy crudes to market. Runs were conducted at temperatures of low, intermediate and high severity in the stripper to produce stripper overhead and bottoms. The bottoms from each of these runs were processed further in a 6-inch screw pyrolyzer to produce pyrolyzer overhead for blending with the corresponding stripper overheads. Proceeding in this fashion yielded three partially upgraded crudes. The products from TaBoRR{reg_sign} processing, the parent bitumen, and bitumen blends were subjected to stability and compatibility testing at the National Centre for Upgrading Technology (NCUT). Chemical analyses of the overhead product blends have met pipeline specifications for viscosity and density; however the bromine number does not, which might indicate the need for mild hydrotreating. Storage stability tests showed the blends to be stable. The blends were also soluble and compatible with most other Alberta crudes.

  9. SUPRI heavy oil research program. Annual report, October 1, 1991--September 30, 1992

    SciTech Connect (OSTI)

    Brigham, W.E.; Ramey, H.J. Jr.; Castanier, L.M.

    1993-08-01

    The goal of the Stanford University Petroleum Research Institute is to conduct research directed toward increasing the recovery of heavy oils. Presently, SUPRI is working in five main directions: (1) flow properties studies to assess the influence of different reservoir conditions (temperature and pressure) on the absolute and relative permeability to oil and water and on capillary pressure; (2) in-situ combustion to evaluate the effect of different reservoir parameters on the in-situ combustion process and to study the kinetics of the reactions; (3) steam with additives to develop and understand the mechanisms of the process using commercially available surfactants for reduction of gravity override and channeling of steam; (4) formation evaluation to develop and improve techniques of formation evaluation such as tracer tests and pressure transient tests; and field support services to provide technical support for design and monitoring of DOE sponsored or industry initiated field projects.

  10. Removal of heteroatoms and metals from heavy oils by bioconversion processes

    SciTech Connect (OSTI)

    Kaufman, E.N.

    1996-06-01

    Biocatalysts, either appropriate microorganisms or isolated enzymes, will be used in an aqueous phase in contact with the heavy oil phase to extract heteroatoms such as sulfur from the oil phase by bioconversion processes. Somewhat similar work on coal processing will be adapted and extended for this application. Bacteria such as Desulfovibrio desulfuricans will be studied for the reductive removal of organically-bound sulfur and bacteria such as Rhodococcus rhodochrum will be investigated for the oxidative removal of sulfur. Isolated bacteria from either oil field co-produced sour water or from soil contaminated by oil spills will also be tested. At a later time, bacteria that interact with organic nitrogen may also be studied. This type of interaction will be carried out in advanced bioreactor systems where organic and aqueous phases are contacted. One new concept of emulsion-phase contacting, which will be investigated, disperses the aqueous phase in the organic phase and is then recoalesced for removal of the contaminants and recycled back to the reactor. This program is a cooperative research and development program with the following companies: Baker Performance Chemicals, Chevron, Energy BioSystems, Exxon, Texaco, and UNOCAL. After verification of the bioprocessing concepts on a laboratory-scale, the end-product will be a demonstration of the technology at an industrial site. This should result in rapid transfer of the technology to industry.

  11. Evaluation of Wax Deposition and Its Control During Production of Alaska North Slope Oils

    SciTech Connect (OSTI)

    Tao Zhu; Jack A. Walker; J. Liang

    2008-12-31

    Due to increasing oil demand, oil companies are moving into arctic environments and deep-water areas for oil production. In these regions of lower temperatures, wax deposits begin to form when the temperature in the wellbore falls below wax appearance temperature (WAT). This condition leads to reduced production rates and larger pressure drops. Wax problems in production wells are very costly due to production down time for removal of wax. Therefore, it is necessary to develop a solution to wax deposition. In order to develop a solution to wax deposition, it is essential to characterize the crude oil and study phase behavior properties. The main objective of this project was to characterize Alaskan North Slope crude oil and study the phase behavior, which was further used to develop a dynamic wax deposition model. This report summarizes the results of the various experimental studies. The subtasks completed during this study include measurement of density, molecular weight, viscosity, pour point, wax appearance temperature, wax content, rate of wax deposition using cold finger, compositional characterization of crude oil and wax obtained from wax content, gas-oil ratio, and phase behavior experiments including constant composition expansion and differential liberation. Also, included in this report is the development of a thermodynamic model to predict wax precipitation. From the experimental study of wax appearance temperature, it was found that wax can start to precipitate at temperatures as high as 40.6 C. The WAT obtained from cross-polar microscopy and viscometry was compared, and it was discovered that WAT from viscometry is overestimated. From the pour point experiment it was found that crude oil can cease to flow at a temperature of 12 C. From the experimental results of wax content, it is evident that the wax content in Alaskan North Slope crude oil can be as high as 28.57%. The highest gas-oil ratio for a live oil sample was observed to be 619.26 SCF

  12. The feasibility of recovering medium to heavy oil using geopressured- geothermal fluids

    SciTech Connect (OSTI)

    Negus-de Wys, J.; Kimmell, C.E.; Hart, G.F.; Plum, M.M.

    1991-09-01

    The feasibility, economics and environmental concerns of producing more domestic oil using thermal enhanced oil recovery (TEOR) are reviewed and the unique nature of geopressured-geothermal (GPGT) fluids for thermal recovery are outlined. Current methods of TEOR are briefly discussed and it is noted that these methods are presently under scrutiny by both federal and state air quality agencies; and moreover, they often involve costly operational and mechanical problems associated with heating water on the surface for injection into the target reservoir. The characteristics of the GPGT resources as seen through previous Department of Energy (DOE) studies from sites in Louisiana and Texas are discussed. These studies indicate sufficient quantities of GPGT fluids can be produced to sustain a TEOR project. The Alworth Field in the south Texas Mirando Trend is proposed as a TEOR pilot site. The target reservoirs for injection of the GPGT fluids are the Jackson and Yegua sandstones of the upper Eocene Epoch. The reservoirs contain an estimated 4 MMbbls of heavy oil in place (OIP) (18.6{degree}API) of which it is estimated that at least 1 MMbbls could be recovered by TEOR. The problems associated with using the GPGT fluids for TEOR include those normally associated with hot water flooding but in addition the reaction of the brine from the geopressured-geothermal reservoir with the target reservoir is uncertain. Under the elevated temperatures associated with GPGT TEOR, actual increased porosity and permeability are possible. 120 refs., 40 figs., 13 tabs.

  13. Effect of asphaltene deposition on the internal corrosion in the oil and gas industry

    SciTech Connect (OSTI)

    Palacios T, C.A.; Morales, J.L.; Viloria, A.

    1997-08-01

    Crude oil from Norte de Monagas field, in Venezuela, contains large amounts of asphaltenes. Some of them are very unstable with a tendency to precipitate. Because liquid is carried over from the separation process in the flow stations, asphaltenes are also present in the gas gathering and transmission lines, precipitating on the inner wall of pipelines. The gas gathering and transmission lines contain gas with high partial pressures of CO{sub 2}, some H{sub 2}S and are water saturated; therefore, inhibitors are used to control internal corrosion. There is uncertainty on how inhibitors perform in the presence of asphaltene deposition. The purpose of this paper is to describe the causes that enhance asphaltene deposition in gas pipelines and present some results from an ongoing research project carried out by the Venezuelan Oil Companies.

  14. Hydropyrolysis process for upgrading heavy oils and solids into light liquid products

    SciTech Connect (OSTI)

    Oblad, A.G.; Ramakrishnan, R.; Shabtai, J.

    1981-11-03

    A hydropyrolysis process is disclosed for upgrading heavy, high molecular weight feedstocks such as coal-derived liquids, petroleum crudes, tar sand bitumens, shale oils, bottom residues from process streams, and the like, to lighter, lower molecular weight liquid products. The process includes subjecting the feedstocks to pyrolysis in the presence of hydrogen under carefully controlled conditions of temperature and pressure. The process can be defined as hydrogen-modified, thermal cracking in the specific temperature range of 450* C. To 650* C. And in the hydrogen pressure range of about 120 psi to 2250 psi. The amount of hydrogen present can be varied according to the type of feedstock and the liquid product desired. Although the hydrogen is not consumed in large amounts, it does participate in and modifies the process, and thereby provides a means of controlling the process as to the molecular weight range and structural type distribution of the liquid products. The presence of hydrogen also inhibits coke formation. The process also eliminates the requirement for a catalyst so that the reaction will proceed in the presence of heavy metal contaminants in the feedstock which contaminants would otherwise poison any catalyst.

  15. Thermal and catalytic upgrading of extra heavy crude oil using methane as a source of hydrogen

    SciTech Connect (OSTI)

    Ovalles, C.; Hamana, A.; Bolivar, R.A.

    1995-12-31

    The upgrading of Orinoco-belt extra-heavy crude oil by reaction with methane as a source of hydrogen was studied under thermal and catalytic conditions. The reactions were carried out in a 300-mL batch reactor at 380{degrees}C, 1600 psi of final pressure for a 4-h period. An alumina supported molybdenum-nickel catalyst was used and activated in situ using carbon disulfide at 350{degrees}C and 100 psi of hydrogen for 2 h. In the presence of an alumina supported molybdenum-nickel catalyst, higher percentage of desulfurization (28%) and lower percentage of asphaltenes (9.3%) were found than those found in the absence of the catalysts (11% and 11.8%, respectively). These results indicate that methane is, most probably, activated by the metal catalyst via oxidative addition producing hydrogen and methyl groups adsorbed on the surface. Finally, the observed relative order of reactivity for the thermal and catalytic upgrading of Hamaca crude oil is: H{sub 2} {>=} CH{sub 4} > N{sub 2}.

  16. Evaluation of heavy oil upgrading/refining process designs for HRI Dynacracking and UOP Aurabon Process. Final report

    SciTech Connect (OSTI)

    Davis, H.; Adams, D.G.; Fox, J.V.

    1984-04-01

    The process designs examined consist of two non-commercialized heavy oil upgrading processes; namely, the Hydrocarbon Research, Inc. (HRI) Dynacracking Process and the UOP Process Division (UOP) Aurabon Process. The latter process design includes, besides the Aurabon Process, an integrated hydrotreating section which does have commercial stature. The Dynacracking Process designs cover six cases involving three heavy crude feedstocks. The Aurabon Complex designs are based on four cases, two for each of two heavy crude feedstocks. The engineering support services involved engineering review and assessment of data, drawings, reports and other information generated by the two process designers. Background information, the review and assessment methodology employed for evaluating the process designs, and a detailed discussion of the process design data generated by both process contractors are presented in this report. Significant findings for both processes may be summarized as follows: (1) The process designs were executed using sound engineering principles and practices; (2) Both processes may be deemed to perform in accordance with their process design; (3) a wide variety of heavy oil charge stocks can be upgraded by either process to products generally suitable for further refinery processing; (4) no insurmountable operating or environmental problems are anticipated; (5) the estimated capital investments and operating utility requirements are indicative of the increased cost to process contaminated heavy crudes; (6) the cost differential between the higher quantity lighter crudes and the poorer quality heavy crudes must be sufficient to justify these higher expenditures; and (7) both processes merit consideration by refiners contemplating contaminated heavy oil upgrading. 53 references, 40 tables.

  17. QUANTITATIVE METHODS FOR RESERVOIR CHARACTERIZATION AND IMPROVED RECOVERY: APPLICATION TO HEAVY OIL SANDS

    SciTech Connect (OSTI)

    James W. Castle; Fred J. Molz; Ronald W. Falta; Cynthia L. Dinwiddie; Scott E. Brame; Robert A. Bridges

    2002-10-30

    Improved prediction of interwell reservoir heterogeneity has the potential to increase productivity and to reduce recovery cost for California's heavy oil sands, which contain approximately 2.3 billion barrels of remaining reserves in the Temblor Formation and in other formations of the San Joaquin Valley. This investigation involves application of advanced analytical property-distribution methods conditioned to continuous outcrop control for improved reservoir characterization and simulation, particularly in heavy oil sands. The investigation was performed in collaboration with Chevron Production Company U.S.A. as an industrial partner, and incorporates data from the Temblor Formation in Chevron's West Coalinga Field. Observations of lateral variability and vertical sequences observed in Temblor Formation outcrops has led to a better understanding of reservoir geology in West Coalinga Field. Based on the characteristics of stratigraphic bounding surfaces in the outcrops, these surfaces were identified in the subsurface using cores and logs. The bounding surfaces were mapped and then used as reference horizons in the reservoir modeling. Facies groups and facies tracts were recognized from outcrops and cores of the Temblor Formation and were applied to defining the stratigraphic framework and facies architecture for building 3D geological models. The following facies tracts were recognized: incised valley, estuarine, tide- to wave-dominated shoreline, diatomite, and subtidal. A new minipermeameter probe, which has important advantages over previous methods of measuring outcrop permeability, was developed during this project. The device, which measures permeability at the distal end of a small drillhole, avoids surface weathering effects and provides a superior seal compared with previous methods for measuring outcrop permeability. The new probe was used successfully for obtaining a high-quality permeability data set from an outcrop in southern Utah. Results obtained

  18. Method for rubblizing an oil shale deposit for in situ retorting

    DOE Patents [OSTI]

    Lewis, Arthur E.

    1977-01-01

    A method for rubblizing an oil shale deposit that has been formed in alternate horizontal layers of rich and lean shale, including the steps of driving a horizontal tunnel along the lower edge of a rich shale layer of the deposit, sublevel caving by fan drilling and blasting of both rich and lean overlying shale layers at the distal end of the tunnel to rubblize the layers, removing a substantial amount of the accessible rubblized rich shale to permit the overlying rubblized lean shale to drop to tunnel floor level to form a column of lean shale, performing additional sublevel caving of rich and lean shale towards the proximate end of the tunnel, removal of a substantial amount of the additionally rubblized rich shale to allow the overlying rubblized lean shale to drop to tunnel floor level to form another column of rubblized lean shale, similarly performing additional steps of sublevel caving and removal of rich rubble to form additional columns of lean shale rubble in the rich shale rubble in the tunnel, and driving additional horizontal tunnels in the deposit and similarly rubblizing the overlying layers of rich and lean shale and forming columns of rubblized lean shale in the rich, thereby forming an in situ oil shale retort having zones of lean shale that remain permeable to hot retorting fluids in the presence of high rubble pile pressures and high retorting temperatures.

  19. IMPROVED CATALYSTS FOR HEAVY OIL UPGRADING BASED ON ZEOLITE Y NANOPARTICLES ENCAPSULATED STABLE NANOPOROUS HOST

    SciTech Connect (OSTI)

    Conrad Ingram; Mark Mitchell

    2005-03-21

    The objectives of this project are to synthesis nanocrystals of highly acidic zeolite Y, encapsulate them within the channels of mesoporous (nanoporous) silicates or nanoporous organosilicates and evaluate the ''zeolite Y/Nanoporous host'' composites as catalysts for the upgrading of heavy petroleum feedstocks. Our results to date are summarized as follows. The synthesis of high surface ordered nanoporous silica of expanded pore diameter of 25 nm (larger than the standard size of 8.4 nm) using trimethylbenzene as a pore size expander was accomplished. The synthesis of zeolite Y nanoparticles with median pore size of approximately 50 nm (smaller than the 80 nm typically obtained with TMAOH) using combined TMABr/TMAOH as organic additives was also accomplished. The successful synthesis of zeoliteY/Nanoporous host composite materials by sequential combination of zeolite precursors and nanoporous material precursor mixtures was implied based on results from various characterization techniques such as X-Ray diffraction, infrared spectra, thermal analysis, porosimetry data. The resulting materials showed pore sizes up to 11 nm, and infrared band at 570 cm{sup -1} suggesting the presence of both phases. Work in the immediate future will be focused on the following three areas: (1) Further characterization of all-silica and aluminosilicate mesoporous materials with expanded pore sizes up to 30 nm will continue; (2) Research efforts to reduce the average particle size of zeolite nanoparticles down to 35-30 nm will continue; (3) Further synthesis of polymer-SBA15 nanocomposites will be conducted by changing the amount and chemistry of the zeolitic precursors added; and (4) Investigation on the catalytic properties of the materials using probe catalytic reactions (such as cumene cracking), followed by catalytic testing for heavy oil conversion.

  20. Ultrapyrolytic upgrading of plastic wastes and plastics/heavy oil mixtures to valuable light gas products

    SciTech Connect (OSTI)

    Lovett, S.; Berruti, F.; Behie, L.A.

    1997-11-01

    Viable operating conditions were identified experimentally for maximizing the production of high-value products such as ethylene, propylene, styrene, and benzene, from the ultrapyrolysis of waste plastics. Using both a batch microreactor and a pilot-plant-sized reactor, the key operating variables considered were pyrolysis temperature, product reaction time, and quench time. In the microreactor experiments, polystyrene (PS), a significant component of waste plastics, was pyrolyzed at temperatures ranging from 800 to 965 C, with total reaction times ranging from 500 to 1,000 ms. At a temperature of 965 C and 500 ms, the yields of styrene plus benzene were greater than 95 wt %. In the pilot-plant experiments, the recently patented internally circulating fluidized bed (ICFB) reactor (Milne et al., US Patent Number 5,370,789, 1994b) was used to ultrapyrolyze low-density polyethylene (LDPE) in addition to LDPE (5% by weight)/heavy oil mixtures at a residence time of 600 ms. Both experiments produced light olefin yields greater than 55 wt % at temperatures above 830 C.

  1. Heavy oil/plastic co-processing - subtask 4.1. Topical report, February 1, 1994--February 1, 1995

    SciTech Connect (OSTI)

    1998-12-31

    Western Research Institute (WRI) is developing a low-temperature thermal decomposition process to alleviate the problems associated with disposal of waste plastics and at the same time generate a product stream in the gasoline boiling range for use in the refining and petrochemical industries. The technology being developed by WRI is significantly different from conventional thermal decomposition processes used to recover distillates from waste plastics. The key to this difference is the application of a decomposition initiator concept that allows operation of the process at temperatures below those used in other thermal decomposition processes. The WRI technology utilizes the decomposition initiator to enhance thermal decomposition of waste plastics in the presence of a low-value heavy oil at temperatures below those normally used for thermal decomposition. Operation of the process at lower temperatures produces higher yields of distillate product and lower yields of gaseous and char products than conventional processes. The activity of the initiator was identified in earlier research studying the thermal decomposition of polymers. This activity was observed to result in a decrease in the temperature required to thermally decompose plastics in the presence of a heavy oil. These early experiments indicated that the initiator was native to the plastics matrix, but the identity and possible mode of action were not determined. This study was undertaken to identify the active initiator in the plastics matrix and define its activity. The experiments performed in this study were conducted in a batch-type reactor. The particular elements of the activity that were addressed included: (1) the kinetics of the reaction, (2) the effects of diluting the plastics with the heavy oil, and (3) the effects of using different types of heavy oil.

  2. IMPROVED CATALYSTS FOR HEAVY OIL UPGRADING BASED ON ZEOLITE Y NANOPARTICLES ENCAPSULATED IN STABLE NANOPOROUS HOST

    SciTech Connect (OSTI)

    Conrad Ingram; Mark Mitchell

    2005-03-31

    physicochemical characteristics will be conducted by changing the amount and chemistry of the zeolitic precursors added; and (4) Investigation on the catalytic properties of the materials using probe catalytic reactions (such as cumene cracking), followed by catalytic testing for heavy oil conversion.

  3. Projections of the impact of expansion of domestic heavy oil production on the U.S. refining industry from 1990 to 2010. Topical report

    SciTech Connect (OSTI)

    Olsen, D.K.; Ramzel, E.B.; Strycker, A.R.; Guariguata, G.; Salmen, F.G.

    1994-12-01

    This report is one of a series of publications assessing the feasibility of increasing domestic heavy oil (10{degrees} to 20{degrees} API gravity) production. This report provides a compendium of the United States refining industry and analyzes the industry by Petroleum Administration for Defense District (PADD) and by ten smaller refining areas. The refining capacity, oil source and oil quality are analyzed, and projections are made for the U.S. refining industry for the years 1990 to 2010. The study used publicly available data as background. A linear program model of the U.S. refining industry was constructed and validated using 1990 U.S. refinery performance. Projections of domestic oil production (decline) and import of crude oil (increases) were balanced to meet anticipated demand to establish a base case for years 1990 through 2010. The impact of additional domestic heavy oil production, (300 MB/D to 900 MB/D, originating in select areas of the U.S.) on the U.S. refining complex was evaluated. This heavy oil could reduce the import rate and the balance of payments by displacing some imported, principally Mid-east, medium crude. The construction cost for refining units to accommodate this additional domestic heavy oil production in both the low and high volume scenarios is about 7 billion dollars for bottoms conversion capacity (delayed coking) with about 50% of the cost attributed to compliance with the Clean Air Act Amendment of 1990.

  4. Beneficiation of oil shales by froth flotation and heavy media separation: Volume 2, Appendix A: Final Report

    SciTech Connect (OSTI)

    Not Available

    1987-08-01

    As a review, the hypothesis being tested in this program was that crushing to finer crush sizes liberates more high grade oil shale thereby allowing for increased oil recovery at higher grades. Heavy medium technology utilizing dynamic vessels can successfully upgrade properly sized oil shale. It should be stressed that the shale must be well screened to remove -28 mesh material to allow for successful plant operation. The fines if not removed an result in significant operating problems by increasing the viscosity of the medium being used. As a review, the medium mixes used for this study would suggest that, at necessary gravities of separation, a mixture between magnetite and ferrosilicon will be necessary in an operating plant. The pilot plant results suggest that some small advantage does exist in the grade recovery relationship as a function of top crush size. As the crust size decreases, a higher grade product can be recovered. For the 3/4'' and 3/8'' crust size, however, this product will not be better than 0.5 to 1.0 gallon per ton higher in grade as the crush size is decreased from 3/4'' to 3/8''. Judging only on the heavy liquid results, here appears to be no great advantage to crushing beyond 3'' for upgrading by heavy medium techniques. The true economic balance will be between final grade produced and the economics of retorting and handling of the tailings material. From the work presented herein it would appear as if no more than a two gallon per ton advantage will be achieved in the final product by crushing from say 1-1/2'' to 3/8''. It is apparent that within the +28 mesh fraction, higher grade samples at internally higher recoveries can be achieved; however, when compared to the total oil feeding the plant, i.e., total ore, these recovery grade improvements are diminished. 11 figs., 16 tabs.

  5. IMPROVED CATALYSTS FOR HEAVY OIL UPGRADING BASED ON ZEOLITE Y NANOPARTICLES ENCAPSULATED IN STABLE NANOPOROUS HOST

    SciTech Connect (OSTI)

    Conrad Ingram; Mark Mitchell

    2005-11-15

    Composite materials of SBA-15/zeolite Y were synthesized from zeolite Y precursor and a synthesis mixture of mesoporous silicate SBA-15 via a hydrothermal process in the presence of a slightly acidic media of pH 4-6 with 2M H{sub 2}SO{sub 4}. The SBA-15/ZY composites showed Type IV adsorption isotherms, narrow BJH average pore size distribution of 4.9 nm, surface areas up to 800 m{sup 2}2/g and pore volumes 1.03 cm{sup 3}, all comparable to pure SBA-15 synthesized under similar conditions. Chemical analysis revealed Si/Al ratio down to 8.5 in the most aluminated sample, and {sup 27}AlSS MAS NMR confirmed aluminum was in tetrahedral coordination. This method of introduction of Al in pure T{sub d} coordination is effective in comparison to other direct and post synthesis alumination methods. Bronsted acid sites were evident from a pyridinium peak at 1544 cm-1 in the FTIR spectrum after pyridine adsorption, and from NH{sub 3} -TPD experiments. SBA-15/ZY composites showed significant catalytic activities for the dealkylation of isopropylbenzene to benzene and propene, similar to those of commercial zeolite Y. It was observed that higher conversion for catalysts synthesized with high amount of ZY precursor mixture added to the SBA-15. Over all the composites has shown good catalytic activity. Further studies will be focused on gaining a better understand the nature of the precursor, and to characterize and to locate the acid sites in the composite material. The composite will also be evaluated for heavy oil conversion to naphtha and middle distillates.

  6. Class III Mid-Term Project, "Increasing Heavy Oil Reserves in the Wilmington Oil Field Through Advanced Reservoir Characterization and Thermal Production Technologies"

    SciTech Connect (OSTI)

    Scott Hara

    2007-03-31

    The overall objective of this project was to increase heavy oil reserves in slope and basin clastic (SBC) reservoirs through the application of advanced reservoir characterization and thermal production technologies. The project involved improving thermal recovery techniques in the Tar Zone of Fault Blocks II-A and V (Tar II-A and Tar V) of the Wilmington Field in Los Angeles County, near Long Beach, California. A primary objective has been to transfer technology that can be applied in other heavy oil formations of the Wilmington Field and other SBC reservoirs, including those under waterflood. The first budget period addressed several producibility problems in the Tar II-A and Tar V thermal recovery operations that are common in SBC reservoirs. A few of the advanced technologies developed include a three-dimensional (3-D) deterministic geologic model, a 3-D deterministic thermal reservoir simulation model to aid in reservoir management and subsequent post-steamflood development work, and a detailed study on the geochemical interactions between the steam and the formation rocks and fluids. State of the art operational work included drilling and performing a pilot steam injection and production project via four new horizontal wells (2 producers and 2 injectors), implementing a hot water alternating steam (WAS) drive pilot in the existing steamflood area to improve thermal efficiency, installing a 2400-foot insulated, subsurface harbor channel crossing to supply steam to an island location, testing a novel alkaline steam completion technique to control well sanding problems, and starting on an advanced reservoir management system through computer-aided access to production and geologic data to integrate reservoir characterization, engineering, monitoring, and evaluation. The second budget period phase (BP2) continued to implement state-of-the-art operational work to optimize thermal recovery processes, improve well drilling and completion practices, and evaluate the

  7. Phase Behavior, Solid Organic Precipitation, and Mobility Characterization Studies in Support of Enhanced Heavy Oil Recovery on the Alaska North Slope

    SciTech Connect (OSTI)

    Shirish Patil; Abhijit Dandekar; Santanu Khataniar

    2008-12-31

    The medium-heavy oil (viscous oil) resources in the Alaska North Slope are estimated at 20 to 25 billion barrels. These oils are viscous, flow sluggishly in the formations, and are difficult to recover. Recovery of this viscous oil requires carefully designed enhanced oil recovery processes. Success of these recovery processes is critically dependent on accurate knowledge of the phase behavior and fluid properties, especially viscosity, of these oils under variety of pressure and temperature conditions. This project focused on predicting phase behavior and viscosity of viscous oils using equations of state and semi-empirical correlations. An experimental study was conducted to quantify the phase behavior and physical properties of viscous oils from the Alaska North Slope oil field. The oil samples were compositionally characterized by the simulated distillation technique. Constant composition expansion and differential liberation tests were conducted on viscous oil samples. Experiment results for phase behavior and reservoir fluid properties were used to tune the Peng-Robinson equation of state and predict the phase behavior accurately. A comprehensive literature search was carried out to compile available compositional viscosity models and their modifications, for application to heavy or viscous oils. With the help of meticulously amassed new medium-heavy oil viscosity data from experiments, a comparative study was conducted to evaluate the potential of various models. The widely used corresponding state viscosity model predictions deteriorate when applied to heavy oil systems. Hence, a semi-empirical approach (the Lindeloff model) was adopted for modeling the viscosity behavior. Based on the analysis, appropriate adjustments have been suggested: the major one is the division of the pressure-viscosity profile into three distinct regions. New modifications have improved the overall fit, including the saturated viscosities at low pressures. However, with the limited

  8. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2002-11-08

    The project involves using advanced reservoir characterization and thermal production technologies to improve thermal recovery techniques and lower operating and capital costs in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., CA. Through June 2002, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar Zone (Tar II-A). Work is continuing on research to understand the geochemistry and process regarding the sand consolidation well completion technique, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V post-steamflood pilot and Tar II-A post-steamflood projects. During the Third Quarter 2002, the project team essentially completed implementing the accelerated oil recovery and reservoir cooling plan for the Tar II-A post-steamflood project developed in March 2002 and is proceeding with additional related work. The project team has completed developing laboratory research procedures to analyze the sand consolidation well completion technique and will initiate work in the fourth quarter. The Tar V pilot steamflood project terminated hot water injection and converted to post-steamflood cold water injection on April 19, 2002. Proposals have been approved to repair two sand consolidated horizontal wells that sanded up, Tar II-A well UP-955 and Tar V well J-205, with gravel-packed inner liner jobs to be performed next quarter. Other well work to be performed next quarter is to convert well L-337 to a Tar V water injector and to recomplete vertical well A-194 as a Tar V interior steamflood pattern producer. Plans have been approved to drill and

  9. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2001-05-07

    The project involves using advanced reservoir characterization and thermal production technologies to improve thermal recovery techniques and lower operating and capital costs in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., CA. Through September 2000, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar Zone (Tar II-A). Work is continuing on improving core analysis techniques, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V steamflood pilot and Tar II-A post steamflood projects. Work was discontinued on the stochastic geologic model and developing a 3-D stochastic thermal reservoir simulation model of the Tar II-A Zone so the project team could use the 3-D deterministic reservoir simulation model to provide alternatives for the Tar II-A post steamflood operations and shale compaction studies. The project team spent the fourth quarter 2000 performing well work and reservoir surveillance on the Tar II-A post-steamflood project and the Tar V horizontal well steamflood pilot. Expanding thermal recovery operations to other sections of the Wilmington Oil Field, including the Tar V horizontal well pilot steamflood project, is a critical part of the City of Long Beach and Tidelands Oil Production Company's development strategy for the field. The current steamflood operations in the Tar V pilot are economical, but recent performance is below projections because of wellbore mechanical limitations that are being evaluated.

  10. Upgrading of heavy oil from the San Joaquin Valley of California by aqueous pyrolysis

    SciTech Connect (OSTI)

    Reynolds, J.G.; Murray, A.M.; Nuxoll, E.V.; Fox, G.A.

    1995-10-01

    Midway Sunset crude oil and well-head oil were treated at elevated temperatures in a closed system with the presence of water. Mild to moderate upgrading, as measured by increase in API gravity, was observed at 400{degrees}C or above. Reduced pressure operation exhibited upgrading activity comparable to upgrading under normal aqueous pyrolysis conditions. Reduced pressure operation was obtained by the use of specific blending methods, a surfactant, and the proper amount of water. The use of additives provided additional upgrading. The best of the minimum set tested was Co(II) 2-ethylhexanoate. Fe(III) 2-ethylhexanoate also showed some activity under certain conditions.

  11. Upgrading of heavy oil from the San Joaquin valley of California by aqueous pyrolysis

    SciTech Connect (OSTI)

    Reynolds, J.G.; Murray, A.M.; Nuxoll, E.V.; Fox, G.A.; Thorsness, C.B.; Khan, M.R.

    1997-08-01

    Midway Sunset crude oil and well-head oil were treated at elevated temperatures in a closed system with the presence of water. Mild to moderate upgrading, as measured by increasing in API gravity, was observed at 400 C or above. Reduced pressure operation exhibited upgrading activity comparable to upgrading under normal aqueous pyrolysis conditions. Reduced pressure operation was obtained by the use of specific blending methods, a surfactant, and the proper amount of water. The use of metal complexes provided additional upgrading. The best of the minimum set tested was Co(II) 2-ethylhexanoate. Fe, Zn, Mo, Cu, and Ni complexes also showed some levels of activity.

  12. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2001-05-08

    The project involves using advanced reservoir characterization and thermal production technologies to improve thermal recovery techniques and lower operating and capital costs in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., CA. Through March 2001, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar Zone (Tar II-A). Work is continuing on research to understand the geochemistry and process regarding the sand consolidation well completion technique, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V steamflood pilot and Tar II-A post-steamflood projects. The project team spent the Second Quarter 2001 performing well work and reservoir surveillance on the Tar II-A post-steamflood project. The Tar II-A steamflood reservoirs have been operated over fifteen months at relatively stable pressures, due in large part to the bimonthly pressure monitoring program enacted at the start of the post-steamflood phase in January 1999. Starting in the Fourth Quarter 2000, the project team has ramped up activity to increase production and injection. This work will continue through 2001 as described in the Operational Management section. Expanding thermal recovery operations to other sections of the Wilmington Oil Field, including the Tar V horizontal well pilot steamflood project, is a critical part of the City of Long Beach and Tidelands Oil Production Company's development strategy for the field. The current steamflood operations in the Tar V pilot are economical, but recent performance is below projections because of wellbore mechanical

  13. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2001-11-01

    The project involves using advanced reservoir characterization and thermal production technologies to improve thermal recovery techniques and lower operating and capital costs in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., Calif. Through June 2001, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar Zone (Tar II-A). Work is continuing on research to understand the geochemistry and process regarding the sand consolidation well completion technique, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V steamflood pilot and Tar II-A post-steamflood projects. The project team spent the Third Quarter 2001 performing well work and reservoir surveillance on the Tar II-A post-steamflood project. The Tar II-A post-steamflood operation started in February 1999 and steam chest fillup occurred in September-October 1999. The targeted reservoir pressures in the ''T'' and ''D'' sands are maintained at 90 {+-} 5% hydrostatic levels by controlling water injection and gross fluid production and through the bimonthly pressure monitoring program enacted at the start of the post-steamflood phase. The project team ramped up well work activity from October 2000 to September 2001 to increase production and injection. This work will continue through 2001 as described in the Operational Management section. Expanding thermal recovery operations to other sections of the Wilmington Oil Field, including the Tar V horizontal well pilot steamflood project, is a critical part of the City of Long Beach and Tidelands Oil Production Company's development strategy for

  14. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2002-01-31

    to other sections of the Wilmington Oil Field, including the Tar V horizontal well pilot steamflood project, is a critical part of the City of Long Beach and Tidelands Oil Production Company's development strategy for the field. The steamflood operation in the Tar V pilot project is mature and profitable. Recent production performance is below projections because of wellbore mechanical limitations that were being addressed in 2001. As the fluid production is hot, the pilot steamflood was converted to a hot waterflood project in June 2001.

  15. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2002-04-30

    The project involves using advanced reservoir characterization and thermal production technologies to improve thermal recovery techniques and lower operating and capital costs in a slope and basin clastic (SBC) reservoir in the Wilmington field, Los Angeles Co., Calif. Through December 2001, project work has been completed on the following activities: data preparation; basic reservoir engineering; developing a deterministic three dimensional (3-D) geologic model, a 3-D deterministic reservoir simulation model and a rock-log model; well drilling and completions; and surface facilities on the Fault Block II-A Tar Zone (Tar II-A). Work is continuing on research to understand the geochemistry and process regarding the sand consolidation well completion technique, final reservoir tracer work, operational work and research studies to prevent thermal-related formation compaction in the Tar II-A steamflood area, and operational work on the Tar V steamflood pilot and Tar II-A post-steamflood projects. During the First Quarter 2002, the project team developed an accelerated oil recovery and reservoir cooling plan for the Tar II-A post-steamflood project and began implementing the associated well work in March. The Tar V pilot steamflood project will be converted to post-steamflood cold water injection in April 2002. The Tar II-A post-steamflood operation started in February 1999 and steam chest fillup occurred in September-October 1999. The targeted reservoir pressures in the ''T'' and ''D'' sands are maintained at 90 {+-} 5% hydrostatic levels by controlling water injection and gross fluid production and through the bimonthly pressure monitoring program enacted at the start of the post-steamflood phase. Most of the 2001 well work resulted in maintaining oil and gross fluid production and water injection rates. Reservoir pressures in the ''T'' and ''D'' sands are at 88% and 91% hydrostatic levels, respectively. Well work during the first quarter and plans for 2002 are

  16. Characterization of heavy crude oils and petroleum residues review of the results obtained by the ASVAHL analytical group

    SciTech Connect (OSTI)

    Colin, J.M.; Boulet, R.; Escalier, J.C.

    1988-06-01

    The creation of the ASHVAHL research facilities, with the aim of experimenting processes, successions of process or new catalysts, with a view to upgrade the heaviest constituents of oil, required extensive work in the field of analysis. Indeed, refiners have an analytic arsenal that is mainly suited for light or middle cuts, but is insufficient for tackling the processing or residual feeds. Therefore, the validity of existing methods has to be checked and new ones had to be developed. Likewise, the optimal upgrading of heavy feeds necessitates as fine an understanding as possible of their composition, to predict their capacity for conversion, to orient the choice of conversion processing, and even to predict the yield structures or the quality of products. Extensive work was done on comprehension analysis, often using sophisticated methods to reach this goal. To manage these activities, an Analysis Competence Group was formed that includes all the ASVAHL partners. All research concerning the development and improvement of methods for monitoring units was carried out in the respective research centers of the three partners after ad hoc working groups had been created. More fundamental research, aiming for an in-depth understanding of heavy products, was either carried out directly in Total, IFP and Elf laboratories or else in collaboration with university laboratories.

  17. Upgraging heavy crude oils to lighter products with a dispersed zeolite

    SciTech Connect (OSTI)

    Rollmann, L. D.

    1985-08-20

    This invention provides a process for upgrading a variety of hydrocarbon oils including low-grade crudes and fractions thereof. In this process, a hydrocarbon oil having an ASTM 50% temperature not higher than 550/sup 0/ F. is converted at low temperature and pressure to more volatile products by a dispersion of crystalline zeolite catalysts having a silica: aluminia ratio of at least 12 and a C.I. within 1-12. Initially, 0.02-10 wt % of the catalyst is dispersed in the feed until the catalyst inventory in the reactor stage accumulates. Thereafter, catalyst is added and removed to maintain a total catalyst content not greater than about 35 wt % of the feed in the reactor.

  18. Heavy Oil Process Monitor: Automated On-Column Asphaltene Precipitation and Re-Dissolution

    SciTech Connect (OSTI)

    John F. Schabron; Joseph F. Rovani; Mark Sanderson

    2007-03-31

    An automated separation technique was developed that provides a new approach to measuring the distribution profiles of the most polar, or asphaltenic components of an oil, using a continuous flow system to precipitate and re-dissolve asphaltenes from the oil. Methods of analysis based on this new technique were explored. One method based on the new technique involves precipitation of a portion of residua sample in heptane on a polytetrafluoroethylene-packed (PTFE) column. The precipitated material is re-dissolved in three steps using solvents of increasing polarity: cyclohexane, toluene, and methylene chloride. The amount of asphaltenes that dissolve in cyclohexane is a useful diagnostic of the thermal history of oil, and its proximity to coke formation. For example, about 40 % (w/w) of the heptane asphaltenes from unpyrolyzed residua dissolves in cyclohexane. As pyrolysis progresses, this number decrease to below 15% as coke and toluene insoluble pre-coke materials appear. Currently, the procedure for the isolation of heptane asphaltenes and the determination of the amount of asphaltenes soluble in cyclohexane spans three days. The automated procedure takes one hour. Another method uses a single solvent, methylene chloride, to re-dissolve the material that precipitates on heptane on the PTFE-packed column. The area of this second peak can be used to calculate a value which correlates with gravimetric asphaltene content. Currently the gravimetric procedure to determine asphaltenes takes about 24 hours. The automated procedure takes 30 minutes. Results for four series of original and pyrolyzed residua were compared with data from the gravimetric methods. Methods based on the new on-column precipitation and re-dissolution technique provide significantly more detail about the polar constituent's oils than the gravimetric determination of asphaltenes.

  19. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2000-02-18

    and net oil production rates of 7,700 BPD and 750 BOPD (injection to production ratio of 4) will occur in October 1999. At that time, the reservoir should act more like a waterflood and production and cold water injection can be operated at lower net injection rates to be determined. Modeling runs developed this quarter found that varying individual well injection rates to meet added production and local pressure problems by sub-zone could reduce steam chest fill-up by up to one month.

  20. Oil

    Broader source: Energy.gov [DOE]

    The Energy Department works to ensure domestic and global oil supplies are environmentally sustainable and invests in research and technology to make oil drilling cleaner and more efficient.

  1. INCREASING HEAVY OIL RESERVES IN THE WILMINGTON OIL FIELD THROUGH ADVANCED RESERVOIR CHARACTERIZATION AND THERMAL PRODUCTION TECHNOLOGIES

    SciTech Connect (OSTI)

    Scott Hara

    2000-12-06

    to accurately project reservoir steam chest fill-up by October 1999. A geomechanics study and a separate reservoir simulation study have been performed to determine the possible indicators of formation compaction, the temperatures at which specific indicators are affected and the projected temperature profiles in the over and underburden shales over a ten year period following steam injection. It was believed that once steam chest fill-up occurred, the reservoir would act more like a waterflood and production and cold water injection could be operated at lower Injection to production ratios (I/P) and net injection rates. In mid-September 1999, net water injection was reduced substantially in the ''D'' sands following steam chest fill-up. This caused reservoir pressures to plummet about 100 psi within six weeks. Starting in late-October 1999, net ''D'' sand injection was increased and reservoir pressures have slowly increased back to steam chest fill-up pressures as of the end of March 2000. When the ''T'' sands reached fill-up, net ''T'' sand injection was lowered only slightly and reservoir pressures stabilized. A more detailed discussion of the operational changes is in the Reservoir Management section of this report. A reservoir pressure monitoring program was developed as part of the poststeamflood reservoir management plan. This bi-monthly sonic fluid level program measures the static fluid levels in all idle wells an average of once a month. The fluid levels have been calibrated for liquid and gas density gradients by comparing a number of them with Amerada bomb pressures taken within a few days. This data allows engineering to respond quickly to rises or declines in reservoir pressure by either increasing injection or production or idling production. Expanding thermal recovery operations to other sections of the Wilmington Oil Field, including the Tar V horizontal well pilot steamflood project, is a critical part of the City of Long Beach and Tidelands Oil

  2. Improved Catalysts for Heavy Oil Upgrading Based on Zeolite Y Nanoparticles Encapsulated Stable Nanoporous Host

    SciTech Connect (OSTI)

    Conrad Ingram; Mark Mitchell

    2007-09-30

    The objective of this project is to synthesize nanocrystals of highly acidic zeolite Y nanoclusters, encapsulate them within the channels of mesoporous (nanoporous) silicates or nanoporous organosilicates, and evaluate the 'zeolite Y/Nanoporous host' composites as catalysts for the upgrading of heavy petroleum feedstocks. In comparison to conventionally-used zeolite Y catalysts of micron size particles, the nanocrystals (< 100 nm particle size) which contain shorter path lengths, are expected to allow faster diffusion of large hydrocarbon substrates and the catalysis products within and out of the zeolite's channels and cages (<1 nm size). This is expected to significantly reduce deactivation of the catalyst and to prolong their period of reactivity. Encapsulating zeolite Y nanocrystals within the nanoporous materials is expected to protect its external surfaces and pore entrances from being blocked by large hydrocarbon substrates, since these substrates will initially be converted to small molecules by the nanoporous host (a catalyst in its own right). The project consisted of four major tasks as follows: (1) synthesis of the nanoparticles of zeolite Y (of various chemical compositions) using various techniques such as the addition of organic additives to conventional zeolite Y synthesis mixtures to suppress zeolite Y crystal growth; (2) synthesis of nanoporous silicate host materials of up to 30 nm pore diameter, using poly (alkylene oxide) copolymers which when removed will yield a mesoporous material; (3) synthesis of zeolite Y/Nanoporous Host composite materials as potential catalysts; and (4) evaluation of the catalyst for the upgrading of heavy petroleum feedstocks.

  3. The examination of pretreatment and end use technologies for dirty fuels produced from coal gasification, coal pyrolysis, oil shale processing, and heavy oil recovery: Final technology status report

    SciTech Connect (OSTI)

    Raden, D.P.; Page, G.C.

    1987-01-01

    The objective of this study was to identify pretreatment (upgrading) and end use technologies which: (1) reduce environmental, health and safety impacts, (2) reduce pollution control costs, or (3) reduce upgrading costs of ''dirty fuels'' while producing higher value energy products. A comprehensive list of technologies was developed for upgrading the various dirty fuels to higher value and products. Fifty-two process flow concepts were examined and from these four process flow concepts were chosen for further development. These are: heavy oil recovery and in situ hydrotreating; wet air oxidation in a downhole reactor; total raw gas shift; and high density fuels via vacuum devolatilization. Each of these four process flow concepts described exhibit the potential for reducing environmental, health and safety impacts and/or pollution control costs. In addition these concepts utilize dirty fuels to produce an upgraded or higher value energy product. These concepts should be developed and evaluated in greater detail to assess their technical and economical viability. Therefore, it is recommended that a program plan be formulated and a proof-of-concept research program be performed for each process concept. 3 refs., 5 figs., 11 tabs.

  4. Improved Catalysts for Heavy Oil Upgrading Based on Zeolite Y Nanoparticles Encapsulated Stable Nanoporous Host

    SciTech Connect (OSTI)

    Conrad Ingram; Mark Mitchell

    2006-09-30

    The addition of hydrothermally-aged zeolite Y precursor to an SBA-15 synthesis mixture under a mildly acidic condition resulted in the formation of mesoporous aluminosilicate catalyst, Al-SBA-15, containing strong Broensted acid sites and aluminum (Al) stabilized in a totally tetrahedral coordination. The physicochemical characteristics of the catalyst varied as a function of the synthesis conditions. The catalyst possessed surface areas ranging between 690 and 850 m{sup 2}/g, pore sizes ranging from 5.6 to 7.5 nm, and pore volumes up 1.03 cm{sup 3}, which were comparable to the parent SBA-15 synthesized under similar conditions. Two wt% Al was present in the catalyst that was obtained from the reaction mixture that contained the highest Al content. The Al remained stable in totally tetrahedral coordination after calcination at 550 C. The Al-SBA-15 mesoporous catalyst showed significant catalytic activity for cumene dealkylation, and the activity increased as the amount of zeolite precursor added to the SBA-15 mixture was increased. In preparation for the final phase of the project, the catalyst was embedded into psuedoboemite alumina (catapal B) matrix and then formed into pellets. In the final phase of the project, the pelletized catalyst will be evaluated for the conversion of heavy petroleum feedstocks to naphtha and middle distillates.

  5. IMPROVED CATALYSTS FOR HEAVY OIL UPGRADING BASED ON ZEOLITE Y NANOPARTICLES ENCAPSULATED STABLE NANOPOROUS HOST

    SciTech Connect (OSTI)

    Conrad Ingram; Mark Mitchell

    2006-06-20

    Al-SBA-15 mesoporous catalysts with strong Broensted acid sites and Al stabilized in a totally tetrahedral coordination was synthesized from the addition of hydrothermally aged zeolite Y precursor to SBA-15 synthesis mixture under mildly acidic condition of pH 5.5. The materials possessed surface areas between 690 and 850 m{sup 2}/g, pore sizes ranging from 5.6 to 7.5 nm and pore volumes up 1.03 cm{sup 3}, which were comparable to parent SBA-15 synthesized under similar conditions. Up to 2 wt. % Al was present in the most aluminated sample that was investigated, and the Al remained stable in totally tetrahedral coordination, even after calcination at 550 C. The Al-SBA-15 mesoporous catalyst showed significant catalytic activity for cumene dealkylation, and activity increased as the amount of zeolite precursor added to the SBA-15 mixture was increased. The catalyst's activity was not affected by the aging time of the precursor for up to the 24 hr aging time investigated. This method of introducing Al and maintaining it in a total tetrahedral coordination is very effective, in comparison to other direct and post synthesis alumination methods reported. The catalytic performance of the zeolite Y/SBA-15 composite materials will be compared with that of pure SBA-15. The catalysts will then be evaluated for the conversion of heavy petroleum feedstocks.

  6. IMPROVED CATALYSTS FOR HEAVY OIL UPGRADING BASED ON ZEOLITE Y NANOPARTICLES ENCAPSULATED IN STABLE NANOPOROUS HOSTS

    SciTech Connect (OSTI)

    Conrad Ingram; Mark Mitchell

    2004-06-30

    The focus of this project is to improve the catalytic performance of zeolite Y for heavy petroleum hydrocracking by synthesizing nanoparticles of the zeolite ({approx}20-30 nm) inside nanoporous silicate or aluminosilicate hosts of similar pore diameters. The encapsulated zeolite nanoparticles are expected to possess pores of reduced diffusional path lengths, hence hydrocarbon substrates will diffuse in, are converted and the products quickly diffused out. This is expected to prevent over-reaction, hence minimizing pore blockage and active sites deactivation. In this phase of the project, research activities were focused on refining procedures to: (a) improve the synthesis of ordered, high surface area nanoporous silica, such as SBA-15, with expanded pore size using trimethylbenzene as additive to the parent SBA-15 synthesis mixture; and (b) reduce the particle size of zeolite Y such that they can be effectively incorporated into the nanoporous silicas. The synthesis of high surface ordered nanoporous silica containing enlarged pores of diameter of 25 nm (larger than the standard size of 8.4 nm) using trimethylbenzene as a pore size expander was accomplished. The synthesis of zeolite Y nanoparticles with median pore size of approximately 50 nm (smaller than the 80 nm typically obtained with TMAOH) using combined TMABr/TMAOH as organic additives was also accomplished.

  7. Turbine fuels from tar sands bitumen and heavy oil. Phase I. Preliminary process analysis. Interim report, 8 July 1983-9 April 1984

    SciTech Connect (OSTI)

    Talbot, A.F.; Elanchenny, V.; Macris, A.; Schwedock, J.P.

    1985-04-09

    The strategic potential of domestic bitumens and heavy crude oils as substitutes for imported crude rests with their efficient conversion into aviation turbine fuels. In this Phase I study, preliminary analyses of several processing schemes were performed. The comparison included both hydrogen-addition and carbon-rejection upgrading processes. Projected JP-4 yields, costs, and thermal efficiencies suggest further exploration of the hydrovisbreaking process. For Phase II, laboratory-scale demonstration of the recommended process is proposed.

  8. HEAVY OIL PROCESS MONITOR: AUTOMATED ON-COLUMN ASPHALTENE PRECIPITATION AND RE-DISSOLUTION

    SciTech Connect (OSTI)

    John F. Schabron; Joseph F. Rovani Jr; Mark Sanderson

    2006-06-01

    About 37-50% (w/w) of the heptane asphaltenes from unpyrolyzed residua dissolve in cyclohexane. As pyrolysis progresses, this number decrease to below 15% as coke and toluene insoluble pre-coke materials appear. This solubility measurement can be used after coke begins to form, unlike the flocculation titration, which cannot be applied to multi-phase systems. Currently, the procedure for the isolation of heptane asphaltenes and the determination of the amount of asphaltenes soluble in cyclohexane spans three days. A more rapid method to measure asphaltene solubility was explored using a novel on-column asphaltene precipitation and re-dissolution technique. This was automated using high performance liquid chromatography (HPLC) equipment with a step gradient sequence using the solvents: heptane, cyclohexane, toluene:methanol (98:2). Results for four series of original and pyrolyzed residua were compared with data from the gravimetric method. The measurement time was reduced from three days to forty minutes. The separation was expanded further with the use of four solvents: heptane, cyclohexane, toluene, and cyclohexanone or methylene chloride. This provides a fourth peak which represents the most polar components, in the oil.

  9. (HC){sub 3} process - An economical technology for upgrading bitumen and heavy oil

    SciTech Connect (OSTI)

    Padamsey, R.; Bailey, R.T.; Cyr, T.J.

    1995-12-31

    This paper discusses the development of the (HC){sub 3} Process. (HC){sub 3} is a high conversion hydro-cracking process with integrated hydro-treating that has been developed by Alberta Department of Energy, Oil Sands and Research Division. The (HC){sub 3} Process has been developed and demonstrated to achieve conversion in excess of 95% at moderate pressures and relatively high temperature in a very cost effective manner. This has been achieved with the aid of a colloidal catalyst that selectively converts the asphaltenes, and a proprietary recycle methodology that significantly reduces the catalyst consumption. Cost and economic studies indicate that capital and operating costs of the (HC){sub 3} upgrading scheme are lower than those of other high conversion schemes and are comparable to those of low and moderate conversion upgrading schemes. This cost advantage combined with the high yield gives the (HC){sub 3} a significant economic advantage over other upgrading schemes. The (HC){sub 3} process shows great promise at achieving high conversion efficiently and economically. The process is ready for commercial testing. Discussions are underway with regards to testing the process in a commercial facility designed to process nominally 5000 barrels per day (BPD).

  10. Fe{sub 3}O{sub 4}/Zeolite nanocomposites synthesized by microwave assisted coprecipitation and its performance in reducing viscosity of heavy oil

    SciTech Connect (OSTI)

    Iskandar, Ferry; Fitriani, Pipit; Merissa, Shanty; Khairurrijal,; Abdullah, Mikrajuddin; Mukti, Rino R.

    2014-02-24

    Fe{sub 3}O{sub 4}/Zeolite nanocomposites have been synthesized via microwave assisted coprecipitation method and show to be efficient in reducing viscosity of heavy oil compared to other Fe{sub 3}O{sub 4}/Zeolite nanocomposites prepared by conventional method. The following precursors such as FeCl{sub 3}⋅6H{sub 2}O, FeSO{sub 4}⋅7H{sub 2}O, NH{sub 4}OH, and natural zeolite of heulandite type were used in the sample preparation. In this study, the effect of Fe{sub 3}O{sub 4} composition in the composite and microwave time heating were investigated. Fe{sub 3}O{sub 4}/Zeolite nanocomposites were then characterized to study the influence on crystal structures, morphology and physicochemical properties. The characterization techniques include X-ray diffraction (XRD), scanning electron microscopy (SEM) and nitrogen physisorption. The results show that by increasing the microwave heating time, the degree of nanocomposite intergrowth can be enhanced. The nanocomposite was tested in catalytic aquathermolysis of heavy oil at 200°C for 6 h and the Fe{sub 3}O{sub 4}/zeolite of 1 to 4 ratios performed the highest viscosity reduction of heavy oil reaching 92%.

  11. Improved Catalysts for Heavy Oil Upgrading Based on Zeolite Y Nanoparticles Encapsulated Stable Nanoporous Host

    SciTech Connect (OSTI)

    Conrad Ingram; Mark Mitchell

    2007-03-31

    The addition of hydrothermally-aged zeolite Y precursor to an SBA-15 synthesis mixture under a mildly acidic condition resulted in the formation of a mesoporous aluminosilicate catalyst, AlSBA-15. The Al-SBA-15 mesoporous catalyst contains strong Br{umlt o}nsted acid sites and aluminum (Al) stabilized in a totally tetrahedral coordination. The physicochemical characteristics of the catalyst varied as a function of the synthesis conditions. The catalyst possessed surface areas ranging between 690 and 850 m{sup 2}/g, pore sizes ranging from 5.6 to 7.5 nm, and pore volumes up 1.03 cm{sup 3}, which were comparable to the parent SBA-15 synthesized under similar conditions. Two wt % Al was present in the catalyst that was obtained from the reaction mixture that contained the highest Al content. The Al remained stable in totally tetrahedral coordination after calcination at a temperature of 550 C. The Al-SBA-15 mesoporous catalyst showed significant catalytic activity for cumene dealkylation, and the activity increased as the amount of zeolite precursor added to the SBA-15 mixture was increased. In preparation for the final phase of the project, the catalyst was embedded into a psuedoboemite alumina (catapal B) matrix and then formed into pellets. In the final phase of the project, the pelletized catalyst is being evaluated for the conversion of a heavy petroleum feedstock to naphtha and middle distillates. This phase was significantly delayed during the past six months due to a serious malfunction of the fume hoods in the Clark Atlanta University's Research Center for Science and Technology, where the project is being conducted. The fume hood system was repaired and the catalyst evaluation is now underway.

  12. Study of hydrocarbon miscible solvent slug injection process for improved recovery of heavy oil from Schrader Bluff Pool, Milne Point Unit, Alaska. Annual report, January 1, 1994--December 31, 1994

    SciTech Connect (OSTI)

    Sharma, G.D.

    1995-07-01

    Alaska is the second largest oil producing state in the nation and currently contributes nearly 24% of the nations oil production. It is imperative that Alaskan heavy oil fields be brought into production. Schrader Bluff reservoir, located in the Milne Point Unit, which is part of the heavy oil field known as West Sak is estimated to contain 1.5 billion barrels of (14 to 21 degree API) oil-in-place. The field is currently under production by primary depletion. The eventual implementation of enhanced oil recovery (EOR) techniques will be vital for the recovery of additional oil from this reservoir. The availability of hydrocarbon gases (solvents) on the Alaska North Slope make the hydrocarbon miscible solvent injection process an important consideration for the EOR project in Schrader Bluff reservoir. Since Schrader Bluff oil is heavy and viscous, a water-alternating-gas (WAG) type of process for oil recovery is appropriate since such a process tends to derive synergetic benefits from both water injection (which provides mobility control and improvement in sweep efficiency) and miscible gas injection (which provides improved displacement efficiency). A miscible solvent slug injection process rather than continuous solvent injection is considered appropriate. Slim tube displacement studies, PVT data and asphaltene precipitation studies are needed for Schrader bluff heavy oil to define possible hydrocarbon solvent suitable for miscible solvent slug displacement process. Coreflood experiments are also needed to determine the effect of solvent slug size, WAG ratio and solvent composition on the recovery and solvent breakthrough. A compositional reservoir simulation study will be conducted later to evaluate the complete performance of the hydrocarbon solvent slug process and to assess the feasibility of this process for improving recovery of heavy oil from Schrader Bluff reservoir.

  13. Upgrading of heavy oil and residuum by the CANMET hydrocracking process: Comparison of pitch conversion from experiments using CSTR and tubular reactors

    SciTech Connect (OSTI)

    Liu, D.D.S.; Patmore, D.J.; Tscheng, J.S.H.

    1985-01-01

    A model was developed to derive rate of pitch (+524/sup 0/C) conversion as a function of temperature in the CANMET hydrocracking process for upgrading heavy oils and refinery residues using gas-liquid-solid concurrent slurry reactors. The model considered the gas void fraction and degree of vaporization to be important parameters. For the CSTR model, complete mixing in the liquid phase was assumed, whereas an axial dispersion model was used for tubular reactors. Rate constants can be derived from experimental data obtained from either continuous stirred tank reactor (CSTR) or tubular reactor experiments, or from both data simultaneously.

  14. Demonstrated Petroleum Reduction Using Oil Bypass Filter Technology...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Demonstrated Petroleum Reduction Using Oil Bypass Filter Technology on Heavy and Light Vehicles Demonstrated Petroleum Reduction Using Oil Bypass Filter Technology on Heavy and ...

  15. II international conference on heavy crude and tar sands. Summary report

    SciTech Connect (OSTI)

    Not Available

    1982-01-01

    The Second International Conference on Heavy Crude and Tar Sands clearly demonstrated that the world has abundant heavy and extra heavy crudes that will sustain the petroleum age for decades. Perhaps even more important for many developed and developing countries is that these resources are widely distributed throughout the world, for deposits are known to exist in at least forty-nine countries. Moreover, the rapid expansion over the last two and a half years of knowledge of the magnitude of these resources suggests there is much more to be added to the world's list of useful energy assets. The current ample supply of crude oil does not appear to have lessened the resolve to develop heavy crude and tar sands. Major industrial countries are eager to develop their heavy oil resources to free themselves from dependence on OPEC and the developing nations hope to reduce their cash outflows for imported oil which they can ill afford. Venezuela and Canada, which both have massive heavy crude reserves, are intent on developing their resources to supplement declining supplies of light oil. Despite the weakening international price of oil, the economics for many heavy crude ventures seem favorable. Statistics quoted at the conference suggest considerable heavy crude production can be brought on stream at costs approaching the finding costs of light conventional crude. At the same time, it has to be acknowledged that those large tar sands projects, like Alberta's multi-billion dollar ventures, are sufficiently marginal that they may be held back by current soft oil demand. This summary report covers the following areas: resources; international cooperation; production; environment; technological developments; upgrading and refining; marketing; and future of heavy crude oil and tar sands.

  16. Biochemical upgrading of oils

    DOE Patents [OSTI]

    Premuzic, E.T.; Lin, M.S.

    1999-01-12

    A process for biochemical conversion of heavy crude oils is provided. The process includes contacting heavy crude oils with adapted biocatalysts. The resulting upgraded oil shows, a relative increase in saturated hydrocarbons, emulsions and oxygenates and a decrease in compounds containing organic sulfur, organic nitrogen and trace metals. Adapted microorganisms which have been modified under challenged growth processes are also disclosed. 121 figs.

  17. Biochemical upgrading of oils

    DOE Patents [OSTI]

    Premuzic, Eugene T. (East Moriches, NY); Lin, Mow S. (Rocky Point, NY)

    1999-01-12

    A process for biochemical conversion of heavy crude oils is provided. The process includes contacting heavy crude oils with adapted biocatalysts. The resulting upgraded oil shows, a relative increase in saturated hydrocarbons, emulsions and oxygenates and a decrease in compounds containing in organic sulfur, organic nitrogen and trace metals. Adapted microorganisms which have been modified under challenged growth processes are also disclosed.

  18. Reactivation of an Idle Lease to Increase Heavy Oil Recovery through Application of Conventional Steam Drive Technology in a Low Dip Slope and Basin Reservoir in the Midway-Sunset Field, San Jaoquin Basin, California

    SciTech Connect (OSTI)

    Steven Schamel

    1998-02-27

    A previously idle portion of the Midway-Sunset field, the ARCO Western Energy Pru Fee property, is being brought back into commercial production through tight integration of geologic characterization, geostatistical modeling, reservoir simulation, and petroleum engineering. This property, shut-in over a decade ago as economically marginal using conventional cyclic steaming methods, has a 200-300 foot thick oil column in the Monarch Sand. However, the sand lacks effective steam barriers and has a thick water-saturation zone above the oil-water contact. These factors require an innovative approach to steam flood production design that will balance optimal total oil production against economically viable steam-oil ratios and production rates. The methods used in the Class III demonstration are accessible to most operators in the Midway-Sunset field and could be used to revitalize properties with declining production of heavy oils throughout the region. In January 1997 the project entered its second and main phase with the purpose of demonstrating whether steamflood can be a more effective mode of production of the heavy, viscous oils from the Monarch Sand reservoir than the more conventional cyclic steaming. The objective is not just to produce the pilot site within the Pru Fee property south of Taft, but to test which production parameters optimize total oil recovery at economically acceptable rates of production and production costs.

  19. U. S. Department of Energy (DOE) research and development programs for heavy oil and tar sand recovery

    SciTech Connect (OSTI)

    Anderson, H.R.

    1981-01-01

    The main emphasis of the DOE tar sand program described is to develop in situ techniques capable of recovering bitumen from domestic tar sand deposits. This program primarily involves field experiments of in situ techniques (in situ combustion and steam drive). Supporting activities include resource assessment, upgrading and surface processing research, and environmental permitting and control. 5 refs.

  20. Heavy liquid beneficiation developed for Alabama tar sands

    SciTech Connect (OSTI)

    Not Available

    1986-12-01

    The tar sand deposits in the State of Alabama contain about 1.8 billion barrels of measured and more than 4 billion barrels of speculative in-place bitumen. A comprehensive research program is in progress for the separation of bitumen from these deposits. In general, Alabama tar sands are oil wetted, low grade and highly viscous in nature. In view of these facts, a beneficiation strategy has been developed to recover bitumen enriched concentrate which can be used as a feed material for further processing. Heavy liquid separation tests and results are discussed. A 77% zinc bromide solution, specific gravity of 2.4, was used for the tests. 2 figures.

  1. U.S. Crude Oil Export Policy

    Gasoline and Diesel Fuel Update (EIA)

    Crude Oil Export Policy EIA Energy Conference Jason Bordoff July 14, 2014 Washington, DC ... Cook Inlet. * Heavy California crude oil. * Exports connected to refining or ...

  2. Evaluation of Wax Deposition and Its Control During Production...

    Office of Scientific and Technical Information (OSTI)

    Title: Evaluation of Wax Deposition and Its Control During Production of Alaska North Slope Oils Due to increasing oil demand, oil companies are moving into arctic environments and ...

  3. Chemical Methods for Ugnu Viscous Oils

    SciTech Connect (OSTI)

    Kishore Mohanty

    2012-03-31

    The North Slope of Alaska has large (about 20 billion barrels) deposits of viscous oil in Ugnu, West Sak and Shraeder Bluff reservoirs. These shallow reservoirs overlie existing productive reservoirs such as Kuparuk and Milne Point. The viscosity of the Ugnu reservoir on top of Milne Point varies from 200 cp to 10,000 cp and the depth is about 3300 ft. The same reservoir extends to the west on the top of the Kuparuk River Unit and onto the Beaufort Sea. The depth of the reservoir decreases and the viscosity increases towards the west. Currently, the operators are testing cold heavy oil production with sand (CHOPS) in Ugnu, but oil recovery is expected to be low (< 10%). Improved oil recovery techniques must be developed for these reservoirs. The proximity to the permafrost is an issue for thermal methods; thus nonthermal methods must be considered. The objective of this project is to develop chemical methods for the Ugnu reservoir on the top of Milne Point. An alkaline-surfactant-polymer (ASP) formulation was developed for a viscous oil (330 cp) where as an alkaline-surfactant formulation was developed for a heavy oil (10,000 cp). These formulations were tested in one-dimensional and quarter five-spot Ugnu sand packs. Micromodel studies were conducted to determine the mechanisms of high viscosity ratio displacements. Laboratory displacements were modeled and transport parameters (such as relative permeability) were determined that can be used in reservoir simulations. Ugnu oil is suitable for chemical flooding because it is biodegraded and contains some organic acids. The acids react with injected alkali to produce soap. This soap helps in lowering interfacial tension between water and oil which in turn helps in the formation of macro and micro emulsions. A lower amount of synthetic surfactant is needed because of the presence of organic acids in the oil. Tertiary ASP flooding is very effective for the 330 cp viscous oil in 1D sand pack. This chemical formulation

  4. System and method for the mitigation of paraffin wax deposition from crude oil by using ultrasonic waves

    DOE Patents [OSTI]

    Towler, Brian F. (Laramie, WY)

    2007-09-04

    A method for mitigating the deposition of wax on production tubing walls. The method comprises positioning at least one ultrasonic frequency generating device adjacent the production tubing walls and producing at least one ultrasonic frequency thereby disintegrating the wax and inhibiting the wax from attaching to the production tubing walls. A system for mitigating the deposition of wax on production tubing walls is also provided.

  5. Hydrodeoxygenation of heavy oils derived from low-temperature coal gasification over NiW catalysts-effect of pore structure

    SciTech Connect (OSTI)

    Dieter Leckel

    2008-01-15

    The effect of the pore structure on the hydroprocessing of heavy distillate oils derived from low-temperature coal gasification residues was studied using four NiW catalysts with different pore size distributions. The hydroprocessing was conducted at a pressure of 17.5 MPa, a temperature range of 370-410{sup o}C, and a 0.50 h{sup -1} space velocity. The degree of hydrodeoxygenation (HDO) in terms of phenolics removal was influenced by the catalyst pore structure, with the most preferable peak pore diameter for HDO ranging between 6.8 and 16 nm. The catalyst with the highest volume of pores in the 3.5-6 nm range showed the lowest HDO activity. The apparent activation energies for the HDO reaction varied between 59 and 87 kJ/mol, whereby the lowest values are obtained for the catalysts with a peak pore diameter of 11 and 16 nm. 30 refs., 5 figs., 6 tabs.

  6. The extraction of bitumen from western oil sands. Annual report, July 1991--July 1992

    SciTech Connect (OSTI)

    Oblad, A.G.; Bunger, J.W.; Dahlstrom, D.A.; Deo, M.D.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1992-08-01

    The University of Utah tar sand research and development program is concerned with research and development on Utah is extensive oil sands deposits. The program has been intended to develop a scientific and technological base required for eventual commercial recovery of the heavy oils from oil sands and processing these oils to produce synthetic crude oil and other products such as asphalt. The overall program is based on mining the oil sand, processing the mined sand to recover the heavy oils and upgrading them to products. Multiple deposits are being investigated since it is believed that a large scale (approximately 20,000 bbl/day) plant would require the use of resources from more than one deposit. The tasks or projects in the program are organized according to the following classification: Recovery technologies which includes thermal recovery methods, water extraction methods, and solvent extraction methods; upgrading and processing technologies which covers hydrotreating, hydrocracking, and hydropyrolysis; solvent extraction; production of specialty products; and environmental aspects of the production and processing technologies. These tasks are covered in this report.

  7. Literature survey and documentation on organic solid deposition problem. Status report

    SciTech Connect (OSTI)

    Chung, Ting-Horng

    1993-12-01

    Organic solid deposition is often a major problem in petroleum production and processing. Recently, this problem has attracted more attention because operating costs have become more critical to the profit of oil production. Also, in miscible gas flooding, asphaltene deposition often occurs in the wellbore region after gas breakthrough and causes plugging. The organic deposition problem is particularly serious in offshore oil production. Cooling of crude oil when it flows through long-distance pipelines under sea water may cause organic deposition in the pipeline and result in plugging. NIPER`s Gas EOR Research Project has been devoted to the study of the organic solid deposition problem for three years. NIPER has received many requests for technical support. Recently, the DeepStar project committee on thermo-technology development and standardization has asked NIPER to provide them with NIPER`s expertise and experience. To assist the oil industry, NIPER is preparing a state-of-the-art review on the technical development for the organic deposition problem. In the first quarter, this project has completed a literature survey and documentation. total of 258 publications (114 for wax, 124 for asphaltene, and 20 for related subjects) were collected and categorized. This literature survey was focused on the two subjects: wax and asphaltene. The subjects of bitumen, asphalt, and heavy oil are not included. Also, the collected publications are mostly related to production problems.

  8. The extraction of bitumen from western oil sands: Volume 1. Final report

    SciTech Connect (OSTI)

    Oblad, A.G.; Dahlstrom, D.A.; Deo, M.D.; Fletcher, J.V.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1997-11-26

    The program is composed of 20 projects, of which 17 are laboratory bench or laboratory pilot scale processes or computer process simulations that are performed in existing facilities on the University of Utah campus in north-east Salt Lake City. These tasks are: (1) coupled fluidized-bed bitumen recovery and coked sand combustion; (2) water-based recovery of bitumen; (3) oil sand pyrolysis in a continuous rotary kiln reactor; (4) oil sand pyrolysis in a large diameter fluidized bed reactor; (5) oil sand pyrolysis in a small diameter fluidized bed reactor; (6) combustion of spent sand in a transport reactor; (7) recovery and upgrading of oil sand bitumen using solvent extraction methods; (8) fixed-bed hydrotreating of Uinta Basin bitumens and bitumen-derived hydrocarbon liquids; (9) ebullieted bed hydrotreating of bitumen and bitumen derived liquids; (10) bitumen upgrading by hydropyrolysis; (11) evaluation of Utah`s major oil sand deposits for the production of asphalt, high-energy jet fuels and other specialty products; (12) characterization of the bitumens and reservoir rocks from the Uinta Basin oil sand deposits; (13) bitumen upgrading pilot plant recommendations; (14) liquid-solid separation and fine tailings thickening; (15) in-situ production of heavy oil from Uinta Basin oil sand deposits; (16) oil sand research and development group analytical facility; and (17) process economics. This volume contains an executive summary and reports for five of these projects. 137 figs., 49 tabs.

  9. The extraction of bitumen from western oil sands: Volume 2. Final report

    SciTech Connect (OSTI)

    Oblad, A.G.; Dahlstrom, D.A.; Deo, M.D.; Fletcher, J.V.; Hanson, F.V.; Miller, J.D.; Seader, J.D.

    1997-11-26

    The program is composed of 20 projects, of which 17 are laboratory bench or laboratory pilot scale processes or computer process simulations that are performed in existing facilities on the University of Utah campus in north-east Salt Lake City. These tasks are: (1) coupled fluidized-bed bitumen recovery and coked sand combustion; (2) water-based recovery of bitumen; (3) oil sand pyrolysis in a continuous rotary kiln reactor; (4) oil sand pyrolysis in a large diameter fluidized bed reactor; (5) oil sand pyrolysis in a small diameter fluidized bed reactor; (6) combustion of spent sand in a transport reactor; (7) recovery and upgrading of oil sand bitumen using solvent extraction methods; (8) fixed-bed hydrotreating of Uinta Basin bitumens and bitumen-derived hydrocarbon liquids; (9) ebullieted bed hydrotreating of bitumen and bitumen derived liquids; (10) bitumen upgrading by hydropyrolysis; (11) evaluation of Utah`s major oil sand deposits for the production of asphalt, high-energy jet fuels and other specialty products; (12) characterization of the bitumens and reservoir rocks from the Uinta Basin oil sand deposits; (13) bitumen upgrading pilot plant recommendations; (14) liquid-solid separation and fine tailings thickening; (15) in-situ production of heavy oil from Uinta Basin oil sand deposits; (16) oil sand research and development group analytical facility; and (17) process economics. This volume contains reports on nine of these projects, references, and a bibliography. 351 refs., 192 figs., 65 tabs.

  10. Upgrading of heavy hydrocarbonaceous feeds

    SciTech Connect (OSTI)

    Bhattacharya, A.K.; Storm, D.A.; DeRosa, T.F.

    1995-12-31

    This paper is based on our work in the area of upgrading of heavy hydrocarbonaceous feedstocks. The work involves the development of a method of catalytically hydroconverting a hydrocarbon feed stream containing a substantial quantity of components boiling above about 538{degrees}C to a substantial portion thereof to components boiling below 538{degrees}C. More particularly, an oil-miscible or oil-soluble poly(ether)diol or a derivative thereof and an aromatic additive oil, such as Heavy Cycle Gas oil, are added to a heavy hydrocarbon feed and the mixed stream is contacted at elevated temperatures with a solid catalyst such as a sulfided nickel molybdenum oxide on alumina in the presence of hydrogen under pressure. This method advantageously affords higher conversion to more valuable liquid products containing lower amounts of heteroatoms such as sulfur, substantially eliminates plugging of the hydroconversion reactor, and reduces the amount of insolubles in the total liquid product.

  11. Balancing oil and environment... responsibly.

    SciTech Connect (OSTI)

    Weimer, Walter C.; Teske, Lisa

    2007-01-25

    Balancing Oil and Environment…Responsibly As the price of oil continues to skyrocket and global oil production nears the brink, pursuing unconventional oil supplies, such as oil shale, oil sands, heavy oils, and oils from biomass and coal has become increasingly attractive. Of particular significance to the American way is that our continent has significant quantities of these resources. Tapping into these new resources, however, requires cutting-edge technologies for identification, production, processing and environmental management. This job needs a super hero or two for a job of this size and proportion…

  12. Crude Oil and Petroleum Products Total Stocks Stocks by Type

    U.S. Energy Information Administration (EIA) Indexed Site

    Product: Crude Oil and Petroleum Products Crude Oil All Oils (Excluding Crude Oil) Pentanes Plus Liquefied Petroleum Gases Ethane/Ethylene Propane/Propylene Normal Butane/Butylene Isobutane/Butylene Other Hydrocarbons Oxygenates (excluding Fuel Ethanol) MTBE Other Oxygenates Renewables (including Fuel Ethanol) Fuel Ethanol Renewable Diesel Fuel Other Renewable Fuels Unfinished Oils Unfinished Oils, Naphthas & Lighter Unfinished Oils, Kerosene & Light Gas Unfinished Oils, Heavy Gas Oils

  13. Practical hot oiling and hot watering for paraffin control (Conference...

    Office of Scientific and Technical Information (OSTI)

    VA at www.ntis.gov. One of the common oil-field wellbore problems is paraffin deposition. ... formation. (2) Hot oiling can vaporize oil in the tubing faster than the pump lifts oil. ...

  14. Running Out Of and Into Oil. Analyzing Global Oil Depletion and Transition Through 2050

    SciTech Connect (OSTI)

    Greene, David L.; Hopson, Janet L.; Li, Jia

    2003-10-01

    This report presents a risk analysis of world conventional oil resource production, depletion, expansion, and a possible transition to unconventional oil resources such as oil sands, heavy oil and shale oil over the period 2000 to 2050. Risk analysis uses Monte Carlo simulation methods to produce a probability distribution of outcomes rather than a single value.

  15. SOLVENT-BASED ENHANCED OIL RECOVERY PROCESSES TO DEVELOP WEST...

    Office of Scientific and Technical Information (OSTI)

    SOLVENT-BASED ENHANCED OIL RECOVERY PROCESSES TO DEVELOP WEST SAK ALASKA NORTH SLOPE HEAVY OIL RESOURCES Citation Details In-Document Search Title: SOLVENT-BASED ENHANCED OIL ...

  16. DOE - Fossil Energy: Soap, Bugs and Other Ways to Produce Oil

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    It hardly flows out of a jar, much less out of an oil reservoir. But if the oil is heated, it becomes thinner and more slippery. To heat heavy oil in a reservoir, oil companies ...

  17. Turbine fuels from tar sands bitumen and heavy oil. Volume 1. Phase 3. Pilot plant testing, final design, and economics. Final report, 1 June 1985-31 March 1987

    SciTech Connect (OSTI)

    Talbot, A.F.; Carson, T.C.; Magill, L.G.; Swesey, J.R.

    1987-08-01

    Pilot-plant-scale demonstration of an upgrading/refining scheme to convert bitumen or heavy crude oil into high yields of specification-quality aviation turbine fuel was performed. An atmospheric residue from San Ardo (California) crude was converted under hydrovisbreaking conditions to synthetic crude for further refining. Naphtha cuts from the straight run and synthetic crude were combined, catalytically hydrotreated, then hydrocracked. Products from these operations were combined to produce two prototype specification fuels (JP-4 and JP-8) as well as two heavier, variable-quality fuels. An engineering design (Volume II) was developed for a 50,000 BPSD grass-roots refinery, from the pilot-plant operations. Capital investment and operating costs were estimated, and fuel manufacturing costs projected. Conclusions and recommendations for further work are included.

  18. Evaluation of Wax Deposition and Its Control During Production...

    Office of Scientific and Technical Information (OSTI)

    Due to increasing oil demand, oil companies are moving into arctic environments and deep-water areas for oil production. In these regions of lower temperatures, wax deposits begin ...

  19. DEVELOPMENT OF SHALLOW VISCOUS OIL RESERVES IN NORTH SLOPE

    SciTech Connect (OSTI)

    Kishore K. Mohanty

    2003-07-01

    North Slope of Alaska has huge oil deposits in heavy oil reservoirs such as Ugnu, West Sak and Shrader Bluff etc. The viscosity of the last two reservoir oils vary from {approx}30 cp to {approx}3000 cp and the amount in the range of 10-20 billion barrels. High oil viscosity and low formation strength impose problems to high recovery and well productivity. Water-alternate-gas injection processes can be effective for the lower viscosity end of these deposits in West Sak and Shrader Bluff. Several gas streams are available in the North Slope containing NGL and CO{sub 2} (a greenhouse gas). The goal of this research is to develop tools to find optimum solvent, injection schedule and well-architecture for a WAG process in North Slope shallow sand viscous oil reservoirs. In the last quarter, we have developed streamline generation and convection subroutines for miscible gas injection. The WAG injection algorithms are being developed. We formulated a four-phase relative permeability model based on two-phase relative permeabilities. The new relative permeability formulations are being incorporated into the simulator. Wettabilities and relative permeabilities are being measured. Plans for the next quarter includes modeling of WAG injection in streamline based simulation, relative permeability studies with cores, incorporation of complex well-architecture.

  20. Methods of Managing Water in Oil Shale Development - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cost of producing potable water is low Reuse of water in drilling procedures Significant dewatering of the oil shale deposit Applications and Industries Oil shale drilling ...

  1. Modification of chemical and physical factors in steamflood to increase heavy oil recovery. Annual report, October 1, 1991--September 30, 1992

    SciTech Connect (OSTI)

    Yortsos, Y.C.

    1993-07-01

    This report covers work performed in the various physicochemical factors for the improvement of oil recovery efficiency. In this context, three general areas were studied: (i) The understanding of vapor-liquid flow in porous media, whether the flow is internal (boiling), external (steam injection) or countercurrent (as in vertical heat pipes); (ii) The effect of reservoir heterogeneity, particularly as it regards fractured systems; (iii) The flow properties of additives for the improvement of recovery efficiency, in particular the injection of caustic and foams. The studies completed under this contract involved ap three research tools, analysis, computation and experiments. We have focused on pore level modeling using pore networks and on flow visualization using Hele-Shaw cells. Experiments involving core samples were conducted for the chemical additives investigation. Finally, simulation at the pore scale, pore network scale and reservoir scale were also undertaken. Part of the work has been detailed in five DOE Technical Reports as shown at the end of this report.

  2. Nineteenth oil shale symposium proceedings

    SciTech Connect (OSTI)

    Gary, J.H.

    1986-01-01

    This book contains 23 selections. Some of the titles are: Effects of maturation on hydrocarbon recoveries from Canadian oil shale deposits; Dust and pressure generated during commercial oil shale mine blasting: Part II; The petrosix project in Brazil - An update; Pathway of some trace elements during fluidized-bed combustion of Israeli Oil Shale; and Decommissioning of the U.S. Department of Energy Anvil Points Oil Shale Research Facility.

  3. Chemical and Microbial Characterization of North Slope Viscous Oils to Assess Viscosity Reduction and Enhanced Recovery

    SciTech Connect (OSTI)

    Shirish Patil; Abhijit Dandekar; Mary Beth Leigh

    2008-12-31

    A large proportion of Alaska North Slope (ANS) oil exists in the form of viscous deposits, which cannot be produced entirely using conventional methods. Microbially enhanced oil recovery (MEOR) is a promising approach for improving oil recovery for viscous deposits. MEOR can be achieved using either ex situ approaches such as flooding with microbial biosurfactants or injection of exogenous surfactant-producing microbes into the reservoir, or by in situ approaches such as biostimulation of indigenous surfactant-producing microbes in the oil. Experimental work was performed to analyze the potential application of MEOR to the ANS oil fields through both ex situ and in situ approaches. A microbial formulation containing a known biosurfactant-producing strain of Bacillus licheniformis was developed in order to simulate MEOR. Coreflooding experiments were performed to simulate MEOR and quantify the incremental oil recovery. Properties like viscosity, density, and chemical composition of oil were monitored to propose a mechanism for oil recovery. The microbial formulation significantly increased incremental oil recovery, and molecular biological analyses indicated that the strain survived during the shut-in period. The indigenous microflora of ANS heavy oils was investigated to characterize the microbial communities and test for surfactant producers that are potentially useful for biostimulation. Bacteria that reduce the surface tension of aqueous media were isolated from one of the five ANS oils (Milne Point) and from rock oiled by the Exxon Valdez oil spill (EVOS), and may prove valuable for ex situ MEOR strategies. The total bacterial community composition of the six different oils was evaluated using molecular genetic tools, which revealed that each oil tested possessed a unique fingerprint indicating a diverse bacterial community and varied assemblages. Collectively we have demonstrated that there is potential for in situ and ex situ MEOR of ANS oils. Future work

  4. Fluid clathrate system for continuous removal of heavy noble gases from mixtures of lighter gases

    DOE Patents [OSTI]

    Gross, K.C.; Markun, F.; Zawadzki, M.T.

    1998-04-28

    An apparatus and method are disclosed for separation of heavy noble gas in a gas volume. An apparatus and method have been devised which includes a reservoir containing an oil exhibiting a clathrate effect for heavy noble gases with a reservoir input port and the reservoir is designed to enable the input gas volume to bubble through the oil with the heavy noble gas being absorbed by the oil exhibiting a clathrate effect. The gas having reduced amounts of heavy noble gas is output from the oil reservoir, and the oil having absorbed heavy noble gas can be treated by mechanical agitation and/or heating to desorb the heavy noble gas for analysis and/or containment and allow recycling of the oil to the reservoir. 6 figs.

  5. Fluid clathrate system for continuous removal of heavy noble gases from mixtures of lighter gases

    DOE Patents [OSTI]

    Gross, Kenneth C.; Markun, Francis; Zawadzki, Mary T.

    1998-01-01

    An apparatus and method for separation of heavy noble gas in a gas volume. An apparatus and method have been devised which includes a reservoir containing an oil exhibiting a clathrate effect for heavy noble gases with a reservoir input port and the reservoir is designed to enable the input gas volume to bubble through the oil with the heavy noble gas being absorbed by the oil exhibiting a clathrate effect. The gas having reduced amounts of heavy noble gas is output from the oil reservoir, and the oil having absorbed heavy noble gas can be treated by mechanical agitation and/or heating to desorb the heavy noble gas for analysis and/or containment and allow recycling of the oil to the reservoir.

  6. Unconventional Oil and Gas Resources

    SciTech Connect (OSTI)

    2006-09-15

    World oil use is projected to grow to 98 million b/d in 2015 and 118 million b/d in 2030. Total world natural gas consumption is projected to rise to 134 Tcf in 2015 and 182 Tcf in 2030. In an era of declining production and increasing demand, economically producing oil and gas from unconventional sources is a key challenge to maintaining global economic growth. Some unconventional hydrocarbon sources are already being developed, including gas shales, tight gas sands, heavy oil, oil sands, and coal bed methane. Roughly 20 years ago, gas production from tight sands, shales, and coals was considered uneconomic. Today, these resources provide 25% of the U.S. gas supply and that number is likely to increase. Venezuela has over 300 billion barrels of unproven extra-heavy oil reserves which would give it the largest reserves of any country in the world. It is currently producing over 550,000 b/d of heavy oil. Unconventional oil is also being produced in Canada from the Athabasca oil sands. 1.6 trillion barrels of oil are locked in the sands of which 175 billion barrels are proven reserves that can be recovered using current technology. Production from 29 companies now operating there exceeds 1 million barrels per day. The report provides an overview of continuous petroleum sources and gives a concise overview of the current status of varying types of unconventional oil and gas resources. Topics covered in the report include: an overview of the history of Oil and Natural Gas; an analysis of the Oil and Natural Gas industries, including current and future production, consumption, and reserves; a detailed description of the different types of unconventional oil and gas resources; an analysis of the key business factors that are driving the increased interest in unconventional resources; an analysis of the barriers that are hindering the development of unconventional resources; profiles of key producing regions; and, profiles of key unconventional oil and gas producers.

  7. Depositional and diagenetic controls on porosity permeability and oil production in McFarland/Magutex (Queen) reservoirs, Andrews County, west Texas

    SciTech Connect (OSTI)

    Holtz, M.H. )

    1991-03-01

    The McFarland/Magutex Queen reservoir complex lies along the northeastern edge of the Central basin platform in the west Texas Permian basin and produces oil from the Permian Queen Formation. Current production from this complex totals 42 million stock-tank barrels (MMSTB) of an estimated 219 MMSTB of original oil in place, with an estimated 90 MMSTB of remaining mobile oil (RMO). The gross pay interval contains two parasequences consisting of progradational, 30-ft-thick, upward-shoaling facies packages. Facies include shoreface, mixed tidal channel and intertidal flat, and supratidal. Elongate shoreface facies are characterized by poorly consolidated, massive to thinly laminated sandstones. The supratidal facies, which act as permeability barriers, are characterized by algal-laminated dolostone and nodular, laminated, and massive anhydrite containing halite and gypsum pseudomorphs. Highest production and the largest amount of the 90 MMSTB of RMO is associated with the shoreface and tidal-channel facies. Bulk pore volume storage capacity and permeability are also highest within these two facies. Sandstones are arkosic, containing anhydrite and dolomite cements. Accessory minerals are clays, authigenic feldspar, and dolomite. Three main pore types are recognized: interparticle, moldic and intraconstituent, and micropores. Moldic and intraconstituent porosity is associated with leached feldspars and anhydrite cement dissolution. Microporosity is associated with syndepositional, grain-coating corrensite, dissolution-enhanced feldspar cleavage planes, and authigenic multifaceted dolomite. Microporosity derived from clays and dolomite is formed preferentially in tidal-channel and intertidal flat facies.

  8. AVTA: Oil Bypass Filter Specifications and Test Procedures | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Oil Bypass Filter Specifications and Test Procedures AVTA: Oil Bypass Filter Specifications and Test Procedures PuraDYN Oil Bypass Filtration System Evaluation Test Plan methodology is used in the testing of all oil bypass filters on the buses at the Idaho National Laboratory. PuraDYN Oil Bypass Filtration System Evaluation Test Plan (732.1 KB) More Documents & Publications Demonstrated Petroleum Reduction Using Oil Bypass Filter Technology on Heavy and Light Vehicles Effects of

  9. Reactivation of an Idle Lease to Increase Heavy Oil Recovery through Application of Conventional Steam Drive Technology in a Low-Dip Slope and Reservoir in the Midway-Sunset Field, San Jaoquin Basin, California, Class III

    SciTech Connect (OSTI)

    Schamel, Steven; Deo, Milind; Deets, Mike

    2002-02-21

    The objective of the project is not just to commercially produce oil from the Pru Fee property, but rather to test which operational strategies best optimize total oil recovery at economically acceptable rates of production volumes and costs.

  10. Reactivation of an Idle Lease to Increase Heavy Oil Recovery through Application of Conventional Steam Drive Technology in a Low-Dip Slope and Reservoir in the Midway-Sunset Field, San Jaoquin Basin, California, Class III

    SciTech Connect (OSTI)

    Schamel, S.

    2001-01-09

    The objective of this project is not just to produce oil from the Pru Fee property, but rather to test which operational strategies best optimize total oil recovery at economically acceptable rates of production and production costs.

  11. Ecotoxicological study of used lubricating oil

    SciTech Connect (OSTI)

    Wong, P.K.; Chan, W.L.; Wang, J.; Wong, C.K.

    1995-12-31

    Used lubricating oil is more toxic than crude oil and fuel oil since it contains comparatively high levels of heavy metals and polycyclic aromatic hydrocarbons (PAHs). No detail toxicological study has been conducted to evaluate the hazards of used lubricating oil to the environment. This study reports a battery of bioassays using bacteria (Microtox test and Mutatox test), algae, amphipod and shrimp larvae to determine the toxicity of water soluble fraction of used lubricating oil. The results will be used to formulate a complete and extensive ecotoxicological assessment of the impacts of used lubricating oil on aquatic environment.

  12. Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons

    SciTech Connect (OSTI)

    Gordon, John Howard

    2014-09-09

    A method of upgrading an oil feedstock by removing heteroatoms and/or one or more heavy metals from the oil feedstock composition. This method reacts the oil feedstock with an alkali metal and an upgradant hydrocarbon. The alkali metal reacts with a portion of the heteroatoms and/or one or more heavy metals to form an inorganic phase separable from the organic oil feedstock material. The upgradant hydrocarbon bonds to the oil feedstock material and increases the number of carbon atoms in the product. This increase in the number of carbon atoms of the product increases the energy value of the resulting oil feedstock.

  13. TULSA UNIVERSITY PARAFFIN DEPOSITION PROJECTS

    SciTech Connect (OSTI)

    Cem Sarica; Michael Volk

    2004-06-01

    As oil and gas production moves to deeper and colder water, subsea multiphase production systems become critical for economic feasibility. It will also become increasingly imperative to adequately identify the conditions for paraffin precipitation and predict paraffin deposition rates to optimize the design and operation of these multi-phase production systems. Although several oil companies have paraffin deposition predictive capabilities for single-phase oil flow, these predictive capabilities are not suitable for the multiphase flow conditions encountered in most flowlines and wellbores. For deepwater applications in the Gulf of Mexico, it is likely that multiphase production streams consisting of crude oil, produced water and gas will be transported in a single multiphase pipeline to minimize capital cost and complexity at the mudline. Existing single-phase (crude oil) paraffin deposition predictive tools are clearly inadequate to accurately design these pipelines, because they do not account for the second and third phases, namely, produced water and gas. The objective of this program is to utilize the current test facilities at The University of Tulsa, as well as member company expertise, to accomplish the following: enhance our understanding of paraffin deposition in single and two-phase (gas-oil) flows; conduct focused experiments to better understand various aspects of deposition physics; and, utilize knowledge gained from experimental modeling studies to enhance the computer programs developed in the previous JIP for predicting paraffin deposition in single and two-phase flow environments. These refined computer models will then be tested against field data from member company pipelines.

  14. Heavy crudes and bitumen categorized to help assess resources, techniques

    SciTech Connect (OSTI)

    Byramjee, R.J.

    1982-07-04

    As conventional crude oil reserves decrease and prices go up, heavy crude oil (HCO) is getting more attention from oil companies and governments. It was felt that some clarification was needed regarding these products and a review of known fields was conducted to sort out ranges of physical and composition characteristics for definition and classification purposes. A summary of this review with a proposal for classification was presented at the Second International Conference on Heavy Crude and Tar Sands held in Caracas in Feb. 1982. This Caracas conference, organized jointly by the United Nations Institute for Training and Research (UNITAR) and Petroleos de Venezuela debated the definition, characteristics, reserves/resources, production/enhanced oil recovery, and upgrading of heavy crude oils. This work is based, in part, on some of the Caracas conference's discussions.

  15. Heavy loads

    SciTech Connect (OSTI)

    Metz, D.

    1982-01-01

    The extreme pressures on the roof and walls of an earth-sheltered residential home are discussed and the need for careful planning is stressed. Pertinent terms are defined. Footings and wall structure (reinforced concrete walls and concrete block walls) are described. Roofing systems are discussed in detail and illustrated: (1) poured-in-place concrete roof slabs; (2) pre-cast concrete planks; and (3) heavy timber roofs. Insulation of earth-sheltered homes is reviewed in terms of using: (1) urethanes; (2) extruded polystyrene; and (3) expanded polystyrene. Advantages, disadvantages, R-factors, costs, and installation are discussed. (MJJ)

  16. Process for tertiary oil recovery using tall oil pitch

    DOE Patents [OSTI]

    Radke, Clayton J.

    1985-01-01

    Compositions and process employing same for enhancing the recovery of residual acid crudes, particularly heavy crudes, by injecting a composition comprising caustic in an amount sufficient to maintain a pH of at least about 11, preferably at least about 13, and a small but effective amount of a multivalent cation for inhibiting alkaline silica dissolution with the reservoir. Preferably a tall oil pitch soap is included and particularly for the heavy crudes a polymeric mobility control agent.

  17. Process for upgrading heavy crude oils

    SciTech Connect (OSTI)

    Rankel, L. A.; Shu, P.

    1985-07-23

    A combination process of oxidation/mild coking and in-situ deasphalting provides a process wherein upgraded crude with high levels of demetalation and low solids rejection is produced.

  18. Viscous heavy brine completion fluids. [Oil wells

    SciTech Connect (OSTI)

    Darlington, R.K.; Hunter, D.V.

    1982-01-01

    An activated hydroxyethyl cellulose (HEC) has been developed which will viscosify brines of any density up to 19.2 lb/gal containing calcium chloride, calcium bromide and/or zinc bromide. The use of activated hydroxyethyl cellulose allows preparation of viscosified brines at ambient emperature and without undissolved polymer solids. The time required to prepare a viscosified brine is greatly reduced. In addition, the rheology of brines viscosified with activated HEC can be accurately predicted allowing brines with equivalent solution rheology properties to be prepared batch after batch. 29 refs.

  19. Catalyst and process for hydroprocessing heavy oils

    SciTech Connect (OSTI)

    Audeh, C.A.; Yan, T.Y.

    1984-09-04

    Disclosed is a catalyst and process for making same wherein sepiolite is ion exchanged with a Group Ib, IIb, IIIb, IVb, Vb, or VIIa metal, impregnated with VIa metal and exchanged with a magnesium salt with intervening processing steps of calcining. The catalyst composition is useful in removing metals and hydroprocessing of hydrocarbon feedstocks. The catalyst can also be mixed with a high silica/alumina ratio zeolite such as sodium ZSM-5 zeolite.

  20. Apparatus for upgrading heavy hydrocarbons employing a diluent

    SciTech Connect (OSTI)

    Calderon, J. L.; Layrisse, I.

    1985-06-04

    Apparatus for upgrading heavy hydrocarbonaceous materials for making coke suitable for metallurgical purposes comprises mixing the heavy hydrocarbonaceous materials with a diluent having a closely controlled boiling range so as to facilitate transport, dehydration and desalting of the crude oil. In addition, the diluent aids in controlling temperature and residence time of the crude thereby avoiding premature decomposition.

  1. Process for upgrading heavy hydrocarbons employing a diluent

    SciTech Connect (OSTI)

    Calderon, J.L.; Layrisse, I.

    1984-06-19

    A process for upgrading heavy hydrocarbonaceous materials for making coke suitable for metallurgical purposes comprises mixing the heavy hydrocarbonaceous materials with a diluent having a closely controlled boiling range so as to facilitate transport, dehydration and desalting of the crude oil. In addition, the diluent aids in controlling temperature and residence time of the crude thereby avoiding premature decomposition.

  2. Australian developments in oil shale processing

    SciTech Connect (OSTI)

    Baker, G.L.

    1981-01-01

    This study gives some background on Australian oil shale deposits, briefly records some history of oil shale processing in the country and looks at the current status of the various proposals being considered to produce syncrudes from Australian oil shales. 5 refs.

  3. Heavy crude upgrading using remote natural gas

    SciTech Connect (OSTI)

    Grosboll, M.P.

    1991-12-03

    This paper describes a method of forming an upgraded crude. It comprises: forming hydrogen from methane gas for hydroconverting heavy crude to form a better crude and reduce its viscosity; hydrogenating under hydroconverting conditions of 650 degrees Fahrenheit ({degrees}F)-1000{degrees}F; and 500-3000 pounds per square inch gauge (psig) only a first portion of a crude oil stream less than the total crude oil stream to produce a light oil that has a lowered viscosity; admixing the light oil with the remainder of the crude oil stream not hydrogenated to produce a flowable crude; and transporting the flowable crude to a refinery including a substep of flowing the crude through a pipeline.

  4. Catalytic hydroprocessing of aromatic compounds: Effects of nickel and vanadium sulfide deposits on reactivities and reaction networks

    SciTech Connect (OSTI)

    Yumoto, Mitsugu |; Kukes, S.G.; Klein, M.T.; Gates, B.C. |

    1996-09-01

    Ni-Mo/{gamma}-Al{sub 2}O{sub 3} hydroprocessing catalysts enriched in nickel and vanadium by contacting with solutions of the respective metal naphthenates were sulfided and tested for hydroprocessing of naphthalene, dibenzothiophene, and quinoline in a batch reactor at 350 C and 165 atm. Approximately reaction networks were determined for each reactant, and the data showed the dependence of the pseudo-first-order rate constants on the catalyst nickel and vanadium contents. The nickel sulfide deposits only slightly affected the rate constants for hydrogenation, but the vanadium sulfide deposits led to decreases in the rate constants for hydrogenation reactions in the naphthalene network and to increases in those for hydrogenation reactions in the dibenzothiophene network. Nickel sulfide deposits led to almost no change in the rate constants for hydrogenolysis of dibenzothiophene, but vanadium sulfide deposits led to decreased rate constant for this reaction. The nickel sulfide deposits have little activity for reactions giving lower-molecular-weight (cracking) products, but the vanadium sulfide deposits have a relatively high activity for cracking, which suggests that they are acidic; the effects are reversed by the presence of the basic quinoline in the reactants. The results indicate a need for representing the nickel and vanadium sulfide deposits separately in process models for heavy oil hydroprocessing.

  5. Oil coking propensity under hydroprocessing conditions

    SciTech Connect (OSTI)

    Kriz, J.F. )

    1991-01-01

    If the processability of heavy or residual oil is assessed in terms of conversion to distillate oils, the tendency to form carbonaceous (coke) deposits in the reactor would impose limits on the operating conditions, since any significant coke accumulation on a continuing basis would be prohibitive. Experimentally, one can evaluate the feedstock coking propensity in a bench-scale reactor for a set of typical hydroprocessing conditions by varying the temperature near the threshold of coking. For a number of different feedstocks examined by this method, an empirical function can be found correlating the coking propensity with some of the characteristic properties determined by routine analyses. The present approach used a combination of physical and chemical properties including density and contents of Conradson Carbon residue, pentane and toluene insolubles, fraction of high-boiling pitch, and carbon, hydrogen, nitrogen, sulfur and ash. Feedstocks were chosen to cover a wide but practical range of properties to establish their impact on the coking propensity. Although these relationships apply to thermal hydroprocessing, the role of catalysts is also indicated.

  6. High-Temperature Nuclear Reactors for In-Situ Recovery of Oil from Oil Shale

    SciTech Connect (OSTI)

    Forsberg, Charles W.

    2006-07-01

    The world is exhausting its supply of crude oil for the production of liquid fuels (gasoline, jet fuel, and diesel). However, the United States has sufficient oil shale deposits to meet our current oil demands for {approx}100 years. Shell Oil Corporation is developing a new potentially cost-effective in-situ process for oil recovery that involves drilling wells into oil shale, using electric heaters to raise the bulk temperature of the oil shale deposit to {approx}370 deg C to initiate chemical reactions that produce light crude oil, and then pumping the oil to the surface. The primary production cost is the cost of high-temperature electrical heating. Because of the low thermal conductivity of oil shale, high-temperature heat is required at the heater wells to obtain the required medium temperatures in the bulk oil shale within an economically practical two to three years. It is proposed to use high-temperature nuclear reactors to provide high-temperature heat to replace the electricity and avoid the factor-of-2 loss in converting high-temperature heat to electricity that is then used to heat oil shale. Nuclear heat is potentially viable because many oil shale deposits are thick (200 to 700 m) and can yield up to 2.5 million barrels of oil per acre, or about 125 million dollars/acre of oil at $50/barrel. The concentrated characteristics of oil-shale deposits make it practical to transfer high-temperature heat over limited distances from a reactor to the oil shale deposits. (author)

  7. Identification of silicone oil/PETN interaction. Quarterly report, January--March 1971

    SciTech Connect (OSTI)

    Faubion, B.D.

    1997-09-01

    Infrared and UV spectra have been obtained on oils pressed from GE5601 silicone rubber. A method for depositing oil on PETN has also been investigated. In order to determine if the oil was evenly deposited on the PETN, an analytical method was developed for determining the concentration of oil on PETN.

  8. Heavy Vehicle Simulator

    SciTech Connect (OSTI)

    2015-03-09

    Idaho National Laboratory Heavy Vehicle Simulator located at the Center for Advanced Energy Studies.

  9. Heavy metal biosensor

    DOE Patents [OSTI]

    Hillson, Nathan J; Shapiro, Lucille; Hu, Ping; Andersen, Gary L

    2014-04-15

    Compositions and methods are provided for detection of certain heavy metals using bacterial whole cell biosensors.

  10. Oil Bypass Filter and Diesel Engine Idling Wear-Rate Evaluations...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications Demonstrated Petroleum Reduction Using Oil Bypass Filter Technology on Heavy and Light Vehicles Development of Partial Filter Technology for HDD ...

  11. Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    1. Total Fuel Oil Consumption and Expenditures, 1999" ,"All Buildings Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures" ,"Number of Buildings (thousand)","Floorspac...

  12. The Road to Improved Heavy Duty Fuel Economy | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Road to Improved Heavy Duty Fuel Economy The Road to Improved Heavy Duty Fuel Economy Heavy duty diesel engine fuel economy is improved by lowering the viscosity of engine lubricant, especially when engine speed is increased or load is decreased, as in long distance on-highway driving deer10_miller.pdf (2.25 MB) More Documents & Publications Development of High Performance Heavy Duty Engine Oils Technical Demonstration of 2010 Emissions Regulations over Transient Operation Lubricants -

  13. Radical scavengers from heavy hydrocarbons

    SciTech Connect (OSTI)

    Kubo, Junichi

    1996-10-01

    The hydrogen-donating properties of some hydrocarbons form the basis for processes such as coal liquefaction and heavy oil upgrading. However, these hydrocarbons have seldom been used for other purposes, because their potential applications have not been well recognized. Research has indicated that these hydrogen-donating hydrocarbons can be used in important reactions as radical scavengers and have properties particular to those of pure hydrocarbons without functional groups containing heteroatoms. Over years of study researchers have found that pure hydrocarbons with radical-scavenging effects nearly as high as those in conventional hindered phenolic antioxidants can be produced from petroleum, and these hydrogen-donating hydrocarbons exhibit such effects even in oxidative atmospheres (i.e., they function as antioxidants). He has also shown that these mixtures have some properties particular to pure hydrocarbons without functional groups containing heteroatoms, and they`ve seen that a mechanism based on the steric effects appears when these hydrocarbons are used in heavy oil hydroprocessing. Hydrogen-donating hydrocarbons should be a viable resource in many applications. In this article, he presents radical-scavenging abilities, characteristics as pure hydrocarbons, and applications on the basis of the studies.

  14. Future of heavy crude and tar sands

    SciTech Connect (OSTI)

    Meyer, R.F.; Steele, C.T.

    1981-01-01

    The 106 papers which were presented at the First International Conference on the Future of Heavy Crude and Tar Sands, held in Edmonton, Alberta are incorporated in this volume. They are grouped under the following sections: (1) role of heavy crude oils and tar sands in world energy; (2) major known occurrences; (3) chemistry and geochemistry; (4) geology; (5) resource evaluation techniques; (6) production research and pilot projects; (7) current production; (8) upgrading and refining; (9) transportation; (10) environmental research; (11) economics; (12) technological problems; (13) institutional factors; and (14) bibliography. All papers have been abstracted and indexed. (ATT)

  15. METHOD OF OPERATING A HEAVY WATER MODERATED REACTOR

    DOE Patents [OSTI]

    Vernon, H.C.

    1962-08-14

    A method of removing fission products from the heavy water used in a slurry type nuclear reactor is described. According to the process the slurry is steam distilled with carbon tetrachloride so that at least a part of the heavy water and carbon tetrachloride are vaporized; the heavy water and carbon tetrachloride are separated; the carbon tetrachloride is returned to the steam distillation column at different points in the column to aid in depositing the slurry particles at the bottom of the column; and the heavy water portion of the condensate is purified. (AEC)

  16. Shale oil recovery process

    DOE Patents [OSTI]

    Zerga, Daniel P.

    1980-01-01

    A process of producing within a subterranean oil shale deposit a retort chamber containing permeable fragmented material wherein a series of explosive charges are emplaced in the deposit in a particular configuration comprising an initiating round which functions to produce an upward flexure of the overburden and to initiate fragmentation of the oil shale within the area of the retort chamber to be formed, the initiating round being followed in a predetermined time sequence by retreating lines of emplaced charges developing further fragmentation within the retort zone and continued lateral upward flexure of the overburden. The initiating round is characterized by a plurality of 5-spot patterns and the retreating lines of charges are positioned and fired along zigzag lines generally forming retreating rows of W's. Particular time delays in the firing of successive charges are disclosed.

  17. World oil trends

    SciTech Connect (OSTI)

    Anderson, A. )

    1991-01-01

    This book provides data on many facets of the world oil industry topics include; oil consumption; oils share of energy consumption; crude oil production; natural gas production; oil reserves; prices of oil; world refining capacity; and oil tankers.

  18. Controlling vanadium from high metals crude oils

    SciTech Connect (OSTI)

    Golden, S.W.; Martin, G.R.

    1995-09-01

    Processing heavier high metals crude oils continues to be an objective of many refiners. Refiners manage the vanadium and other contaminants with hydroprocessing and FCC catalysts that are more tolerant to metals. Although hydroprocessing and FCC catalyst formulations are critical and will be required for the bulk of the metals removal, many times primary distillation impacts on vanadium are ignored. Distillation system designs can significantly impact the metals content of the gas oil pool or the total gas yields for a targeted metals level. Commercial experience shows that total gas oil metals to the hydroprocessing unit can be reduced by 20 to 40% for a given gas yield or the total gas oil yield can be increased for a given metals target by optimizing primary distillation system performance. Total gas oil vanadium content has varied from 5 to 2 weight ppm depending on crude oil metals level, unit process design, distillation unit operation, and equipment design. An actual example using a 22.0 API Bochequero Field blend will be used to illustrate the points covered. The source of the vanadium in the various gas oil pool components will be evaluated and show potential gas oil quality improvements based on primary distillation system design and operation modifications. In the example, the refiner processes 145,000 bpd of crude oil through a conventional integrated atmospheric/vacuum unit and processes the vacuum residue in a delayed coker. The gas oil blend streams consists of atmospheric gas oil, light vacuum gas oil, and heavy vacuum gas oil from the crude unit and heavy coker gas oil from the delayed coker. All the modifications which will be discussed have been operating successfully for several years.

  19. Process for upgrading a heavy viscous hydrocarbon

    SciTech Connect (OSTI)

    Lutz, I.H.

    1984-06-12

    A process for upgrading a heavy viscous hydrocarbon, for example, rendering a heavy viscous crude pipelinable, includes visbreaking, distillation and solvent extraction steps. A heavy viscous hydrocarbon is fed through the visbreaker which forms a feed to the distillation step. A heavier fraction from distillation is fed to a solvent extraction unit which produces a fraction which contains resin. At least a portion of the resin containing fraction separated in the solvent extraction unit is recycled and combined with the feed which is to be subjected to visbreaking so that the total yield of products, residual and gas-free, is increased. The recycled resin reduces the tendency of the asphaltenes to separate from the oil and thereby reduces the tendency to lay down coke in the visbreaker; this allows higher conversion to upgraded liquid products.

  20. Nuclear stopping and energy deposition into the central rapidity region

    SciTech Connect (OSTI)

    Zingman, J.A.

    1987-08-03

    Nuclear stopping and energy deposition into the central rapidity region of ultrarelativistic heavy-ion collisions are studied through the application of a model incorporating hydrodynamic baryon flow coupled to a self-consistent field calculated in the flux tube model. Ultrarelativistic heavy ion collisions are modeled in which the nuclei have passed through each other and as a result are charged and heated.

  1. Process for upgrading arsenic-containing oils

    DOE Patents [OSTI]

    Sullivan, Richard F.

    1979-01-01

    A method is provided for avoiding feed-transfer-line plugging by a deposit comprising arsenic in hydroprocessing an oil containing an arsenic contaminant. In the method, a mixture of hydrogen gas and the oil is formed in situ in a bed of porous particulate contact material.

  2. Collaborative Lubricating Oil Study on Emissions (CLOSE) Project

    Broader source: Energy.gov [DOE]

    Extensive chemical and physical characterization performed on emissions from normal and high emitting light-, medium-, and heavy-duty vehicles to evaluate relative contributions of fuel and lubricating oil on tailpipe emissions.

  3. Reactivation of an Idle Lease to Increase Heavy Oil Recovery through Application of Conventional Steam Drive Technology in a Low Dip Slope and Basin Reservoir in the Midway-Sunset Field, San Jaoquin Basin, California

    SciTech Connect (OSTI)

    Deo, M.; Forster, C.; Jenkins, C.; Schamel, S.; Sprinkel, D.; and Swain, R.

    1999-02-01

    This project reactivates ARCO's idle Pru Fee lease in the Midway-Sunset field, California and conducts a continuous steamflood enhanced oil recovery demonstration aided by an integration of modern reservoir characterization and simulation methods. Cyclic steaming was used to reestablish baseline production within the reservoir characterization phase of the project completed in December 1996. During the demonstration phase begun in January 1997, a continuous steamflood enhanced oil recovery is testing the incremental value of this method as an alternative to cyclic steaming. Other economically marginal Class III reservoirs having simular producibility problems will benefit from insight gained in this project. The objectives of the project are: (1) to return the shut-in portion of the reservoir to optimal commercial production; (2) to accurately describe the reservoir and recovery process; and (3) to convey the details of this activity to the domestic petroleum industry, especially t o other producers in California, through an aggressive technology transfer program.

  4. Reactivation of an Idle Lease to Increase Heavy Oil Recovery Through Application of Conventional Steam Drive Technology in a Low Dip Slope and Basin Resrvoir in the Midway-Sunset Field, San Jaoquin Basin, California

    SciTech Connect (OSTI)

    Jenkins, Creties; Sprinkel, Doug; Deo, Milind; Wydrinski, Ray; Swain, Robert

    1997-10-21

    This project reactivates ARCO's idle Pru Fee lease in the Midway-Sunset field, California and conducts a continuous steamflood enhanced oil recovery demonstration aided by an integration of modern reservoir characterization and simulation methods. Cyclic steaming is being used to reestablish baseline production within the reservoir characterization phase of the project. During the demonstration phase scheduled to begin in January 1997, a continuous steamflood enhanced oil recovery will be initiated to test the incremental value of this method as an alternative to cyclic steaming. Other economically marginal Class III reservoirs having similar producibility problems will benefit from insight gained in this project. The objectives of the project are: (1) to return the shut-in portion of the reservoir to optimal commercial production; (2) to accurately describe the reservoir and recovery process; and (3) to convey the details of this activity to the domestic petroleum industry, especially to other producers in California, through an aggressive technology transfer program.

  5. Reactivation of an Idle Lease to Increase Heavy Oil Recovery Through Application of Conventional Steam Drive Technology in a Low Dip Slope and Basin Reservoir in the Midway-Sunset Field, San Jaoquin Basin, California

    SciTech Connect (OSTI)

    Schamel, Steven

    1997-07-29

    This project reactivates ARCO's idle Pru Fee property in the Midway-Sunset field, California and conducts a continuous steamflood enhanced oil recovery demonstration aided by an integration of modern reservoir characterization and simulation methods. Cyclic steaming was used to reestablish baseline production within the reservoir characterization phase of the project. During the demonstration phase begun in January 1997, a continuous steamflood enhanced oil recovery was initiated to test the incremental value of this method as an alternative to cyclic steaming. Other economically marginal Class III reservoirs having similar producibility problems will benefit from insight gained in this project. The objectives of the project are: (1) to return the shut-in portion of the reservoir to optimal commercial production; (2) to accurately describe the reservoir and the recovery process; and (3) to convey the details of this activity to the domestic petroleum industry, especially to other producers in California, through an aggressive technology transfer program.

  6. Conductivity heating a subterranean oil shale to create permeability and subsequently produce oil

    SciTech Connect (OSTI)

    Van Meurs, P.; DeRouffignac, E.P.; Vinegar, H.J.; Lucid, M.F.

    1989-12-12

    This patent describes an improvement in a process in which oil is produced from a subterranean oil shale deposit by extending at least one each of heat-injecting and fluid-producing wells into the deposit, establishing a heat-conductive fluid-impermeable barrier between the interior of each heat-injecting well and the adjacent deposit, and then heating the interior of each heat-injecting well at a temperature sufficient to conductively heat oil shale kerogen and cause pyrolysis products to form fractures within the oil shale deposit through which the pyrolysis products are displaced into at least one production well. The improvement is for enhancing the uniformity of the heat fronts moving through the oil shale deposit. Also described is a process for exploiting a target oil shale interval, by progressively expanding a heated treatment zone band from about a geometric center of the target oil shale interval outward, such that the formation or extension of vertical fractures from the heated treatment zone band to the periphery of the target oil shale interval is minimized.

  7. PIA - Northeast Home Heating Oil Reserve System (Heating Oil...

    Energy Savers [EERE]

    Northeast Home Heating Oil Reserve System (Heating Oil) PIA - Northeast Home Heating Oil Reserve System (Heating Oil) PIA - Northeast Home Heating Oil Reserve System (Heating Oil)...

  8. Venezuelan oil

    SciTech Connect (OSTI)

    Martinez, A.R. )

    1989-01-01

    Oil reserves have been known to exist in Venezuela since early historical records, however, it was not until the 20th century that the extensive search for new reserves began. The 1950's marked the height of oil exploration when 200 new oil fields were discovered, as well as over 60{percent} of proven reserves. Venezuela now produces one tone in seven of crude oil consumption and the country's abundant reserves such as the Bolivar Coastal field in the West of the country and the Orinoco Belt field in the East, will ensure it's continuing importance as an oil producer well into the 21st century. This book charts the historical development of Venezuela oil and provides a chronology of all the significant events which have shaped the oil industry of today. It covers all the technical, legal, economic and political factors which have contributed to the evolution of the industry and also gives information on current oil resources and production. Those events significant to the development of the industry, those which were influential in shaping future policy and those which precipitated further action are included. The book provides a source of reference to oil companies, oil economists and petroleum geologists.

  9. Heading off the permanent oil crisis

    SciTech Connect (OSTI)

    MacKenzie, J.J.

    1996-11-01

    The 1996 spike in gasoline prices was not a signal of any fundamental worldwide shortage of crude oil. But based on a review of many studies of recoverable crude oil that have been published since the 1950s, it looks as though such a shortfall is now within sight. With world demand for oil growing at 2 percent per year, global production is likely to peak between the years 2007 and 2014. As this time approaches, we can expect prices to rise markedly and, most likely, permanently. Policy changes are needed now to ease the transition to high-priced oil. Oil production will continue, though at a declining rate, for many decades after its peak, and there are enormous amounts of coal, oil sands, heavy oil, and oil shales worldwide that could be used to produce liquid or gaseous substitutes for crude oil, albeit at higher prices. But the facilities for making such synthetic fuels are costly to build and environmentally damaging to operate, and their use would substantially increase carbon dioxide emissions (compared to emissions from products made from conventional crude oil). This paper examines ways of heading of the impending oil crisis. 8 refs., 3 figs.

  10. Method of removal of heavy metal from molten salt in IFR fuel pyroprocessing

    DOE Patents [OSTI]

    Gay, Eddie C.

    1995-01-01

    An electrochemical method of separating heavy metal values from a radioactive molten salt including Li halide at temperatures of about 500.degree. C. The method comprises positioning a solid Li--Cd alloy anode in the molten salt containing the heavy metal values, positioning a Cd-containing cathode or a solid cathode positioned above a catch crucible in the molten salt to recover the heavy metal values, establishing a voltage drop between the anode and the cathode to deposit material at the cathode to reduce the concentration of heavy metals in the salt, and controlling the deposition rate at the cathode by controlling the current between the anode and cathode.

  11. Heavy Mobile Equipment Mechanic

    Broader source: Energy.gov [DOE]

    Join the Bonneville Power Administration (BPA) for a challenging and rewarding career, while working, living, and playing in the Pacific Northwest. The Heavy Mobile Equipment Mechanic (HMEM)...

  12. ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    4. Fuel Oil Consumption and Expenditure Intensities for Non-Mall Buildings, 2003" ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures" ,"per Building (gallons)","per Square Foot...

  13. ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures"

    U.S. Energy Information Administration (EIA) Indexed Site

    2. Fuel Oil Consumption and Expenditure Intensities, 1999" ,"Fuel Oil Consumption",,,"Fuel Oil Expenditures" ,"per Building (gallons)","per Square Foot (gallons)","per Worker...

  14. Crude Oil

    U.S. Energy Information Administration (EIA) Indexed Site

    Barrels) Product: Crude Oil Liquefied Petroleum Gases Distillate Fuel Oil Residual Fuel Oil Still Gas Petroleum Coke Marketable Petroleum Coke Catalyst Petroleum Coke Other Petroleum Products Natural Gas Coal Purchased Electricity Purchased Steam Period: Annual Download Series History Download Series History Definitions, Sources & Notes Definitions, Sources & Notes Show Data By: Product Area 2010 2011 2012 2013 2014 2015 View History U.S. 0 0 0 0 0 0 1986-2015 East Coast (PADD 1) 0 0 0 0

  15. Impacts of the Venezuelan Crude Oil Production Loss

    Reports and Publications (EIA)

    2003-01-01

    This assessment of the Venezuelan petroleum loss examines two areas. The first part of the analysis focuses on the impact of the loss of Venezuelan crude production on crude oil supply for U.S. refiners who normally run a significant fraction of Venezuelan crude oil. The second part of the analysis looks at the impact of the Venezuelan production loss on crude markets in general, with particular emphasis on crude oil imports, refinery crude oil throughput levels, stock levels, and the changes in price differences between light and heavy crude oils.

  16. Reactivation of an idle lease to increase heavy oil recovery through application of conventional steam drive technology in a low dip slope and basin reservoir in the Midway-Sunset Field, San Jaoquin Basin, California

    SciTech Connect (OSTI)

    Schamel, S.

    1996-11-01

    This project reactivates ARCO`s idle Pru Fee lease in the Midway- Sunset field, California and conducts a continuous steamflood enhanced oil recovery demonstration aided by an integration of modern reservoir characterization and simulation methods. Cyclic steaming is being used to reestablish baseline production within the reservoir characterization phase of the project. During the demonstration phase scheduled to begin in January 1997, a continuous steamflood enhanced oil recovery will be initiated to test the incremental value of this method as an alternative to cyclic steaming. Other economically marginal Class III reservoirs having similar producibility problems will benefit from insight gained in this project. The objectives of the project are: (1) to return the shut-in portion of the reservoir to optimal commercial production; (2) to accurately describe the reservoir and recovery process; and (3) to convey the details of this activity to the domestic petroleum industry, especially to other producers in California, through an aggressive technology transfer program. One of the main objectives of Budget Period I was to return the Pru Fee property to economic production and establish a baseline productivity with cyclic steaming. By the end of the second quarter 1996, all Pru producers except well 101 had been cyclic steamed two times. Each steam cycle was around 10,000 barrels of steam (BS) per well. No mechanical problems were found in the existing old wellbores. Conclusion is after several years of being shut-in, the existing producers on the Pru lease are in reasonable mechanical condition, and can therefore be utilized as viable producers in whatever development plan we determine is optimum. Production response to cyclic steam is very encouraging in the new producer, however productivity in the old producers appears to be limited in comparison.

  17. Sixty-sixth annual report of the state oil and gas supervisor

    SciTech Connect (OSTI)

    Not Available

    1981-01-01

    This report contains tabulated oil and gas statistics compiled during 1980 in California. On-shore and off-shore oil production, gas production, reserves, drilling activity, enhanced recovery activity, unconventional heavy oil recovery, geothermal operations and financial data are reported. (DMC)

  18. Super-Heavy Element Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Targets for Super-Heavy Element Research Presented at International Workshop on Super-Heavy Element Research SHE-15 J. B. Roberto Oak Ridge National Laboratory Oak Ridge,...

  19. Electromagnetic Imaging of CO2 Sequestration at an Enhanced Oil Recovery Site

    SciTech Connect (OSTI)

    Kirkendall, B.; Roberts, J.

    2001-02-28

    Lawrence Livermore National Laboratory (LLNL) is currently involved in a long term study using time-lapse multiple frequency electromagnetic (EM) characterization at a waterflood enhanced oil recovery (EOR) site in California operated by Chevron Heavy Oil Division in Lost Hills, California (Figure 1). The petroleum industry's interest and the successful imaging results from this project suggest that this technique be extended to monitor CO{sub 2} sequestration at an EOR site also operated by Chevron. The impetus for this study is to develop the ability to image subsurface injected CO{sub 2} during EOR processes while simultaneously discriminating between pre-existing petroleum and water deposits. The goals of this study are to combine laboratory and field methods to image a pilot CO{sub 2} sequestration EOR site using the cross-borehole EM technique, improve the inversion process in CO{sub 2} studies by coupling results with petrophysical laboratory measurements, and focus on new gas interpretation techniques. In this study we primarily focus on how joint field and laboratory results can provide information on subsurface CO{sub 2} detection, CO{sub 2} migration tracking, and displacement of petroleum and water over time. This study directly addresses national energy issues in two ways: (1) the development of field and laboratory techniques to improve in-situ analysis of oil and gas enhanced recovery operations and, (2) this research provides a tool for in-situ analysis of CO{sub 2} sequestration, an international technical issue of growing importance.

  20. Oil gravity distribution in the diatomite at South Belridge Field, Kern County, CA: Implications for oil sourcing and migration

    SciTech Connect (OSTI)

    Hill, D.W.; Sande, J.J.; Doe, P.H.

    1995-04-01

    Understanding oil gravity distribution in the Belridge Diatomite has led to economic infill development and specific enhanced recovery methods for targeted oil properties. To date more than 100 wells have provided samples used to determining vertical and areal distribution of oil gravity in the field. Detailed geochemical analyses were also conducted on many of the oil samples to establish different oil types, relative maturities, and to identify transformed oils. The geochemical analysis also helped identify source rock expulsion temperatures and depositional environments. The data suggests that the Belridge diatomite has been charged by a single hydrocarbon source rock type and was generated over a relatively wide range of temperatures. Map and statistical data support two distinct oil segregation processes occurring post expulsion. Normal gravity segregation within depositional cycles of diatomite have caused lightest oils to migrate to the crests of individual cycle structures. Some data suggests a loss of the light end oils in the uppermost cycles to the Tulare Formation above, or through early biodegradation. Structural rotation post early oil expulsion has also left older, heavier oils concentrated on the east flank of the structure. With the addition of other samples from the south central San Joaquin area, we have been able to tie the Belridge diatomite hydrocarbon charge into a regional framework. We have also enhanced our ability to predict oil gravity and well primary recovery by unraveling some key components of the diatomite oil source and migration history.

  1. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    . Fuel Oil Expenditures by Census Region for Non-Mall Buildings, 2003" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per...

  2. ,"Total Fuel Oil Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    0. Fuel Oil Consumption (gallons) and Energy Intensities by End Use for Non-Mall Buildings, 2003" ,"Total Fuel Oil Consumption (million gallons)",,,,,"Fuel Oil Energy Intensity...

  3. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    4. Fuel Oil Expenditures by Census Region, 1999" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per Gallon",,,,"per Square Foot"...

  4. ,"Total Fuel Oil Expenditures

    U.S. Energy Information Administration (EIA) Indexed Site

    A. Fuel Oil Expenditures by Census Region for All Buildings, 2003" ,"Total Fuel Oil Expenditures (million dollars)",,,,"Fuel Oil Expenditures (dollars)" ,,,,,"per Gallon",,,,"per...

  5. ,"Total Fuel Oil Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    A. Fuel Oil Consumption (gallons) and Energy Intensities by End Use for All Buildings, 2003" ,"Total Fuel Oil Consumption (million gallons)",,,,,"Fuel Oil Energy Intensity...

  6. Have We Run Out of Oil Yet? Oil Peaking Analysis from an Optimist's Perspective

    SciTech Connect (OSTI)

    Greene, David L; Hopson, Dr Janet L; Li, Jia

    2005-01-01

    This study addresses several questions concerning the peaking of conventional oil production from an optimist's perspective. Is the oil peak imminent? What is the range of uncertainty? What are the key determining factors? Will a transition to unconventional oil undermine or strengthen OPEC's influence over world oil markets? These issues are explored using a model combining alternative world energy scenarios with an accounting of resource depletion and a market-based simulation of transition to unconventional oil resources. No political or environmental constraints are allowed to hinder oil production, geological constraints on the rates at which oil can be produced are not represented, and when USGS resource estimates are used, more than the mean estimate of ultimately recoverable resources is assumed to exist. The issue is framed not as a question of "running out" of conventional oil, but in terms of the timing and rate of transition from conventional to unconventional oil resources. Unconventional oil is chosen because production from Venezuela's heavy-oil fields and Canada's Athabascan oil sands is already underway on a significant scale and unconventional oil is most consistent with the existing infrastructure for producing, refining, distributing and consuming petroleum. However, natural gas or even coal might also prove to be economical sources of liquid hydrocarbon fuels. These results indicate a high probability that production of conventional oil from outside of the Middle East region will peak, or that the rate of increase of production will become highly constrained before 2025. If world consumption of hydrocarbon fuels is to continue growing, massive development of unconventional resources will be required. While there are grounds for pessimism and optimism, it is certainly not too soon for extensive, detailed analysis of transitions to alternative energy sources.

  7. Heavy crude and tar sands: Hydrocarbons for the 21st century. Volume 2, Reservoir behavior, drilling and production

    SciTech Connect (OSTI)

    Meyer, R.F.

    1991-12-31

    Volume 2 is devoted to heavy oil reservoir behavior, production, and the drilling and completion of wells to meet the special needs of these fascinating but difficult oils and bitumens. The volume begins with four papers describing approaches to the recovery of heavy oil and to two fields subject to different recovery mechanisms. Although most heavy oil fields are produced with the assistance of steam stimulation, which commenced in Venezuela, or steam flood, many other methods for the improvement of recovery are potentially applicable. The seven reports on pilot projects examine mostly the results of studies on the dominant thermal recovery methods - steam stimulation, steam flood, and in situ combustion. The behavior of reservoirs under development through use of horizontal wells is the subject of three reports, of vertical wells, nine papers. Much is still to be teamed concerning the relative advantages of these two distinctive methods of reservoir development. The 18 reports on drilling and production are of great importance to the science and engineering of heavy oil because of the problems heavy oil causes after it is induced to flow to the well bore. Artificial lifting of the oil has traditionally centered on the use of sucker rods, but other methods, such as chamber or cavity-pump lift may prove to be efficacious. Horizontal well drilling is a logical approach to maximizing the amount of reservoir exposed to the well bore but this entails special problems in bore-hole clean-up. Heavy oils, too, pose special, frequently very difficult gravel packing problems. Sand production with heavy oil has always posed both economic and technological difficulties and major effort is devoted to overcoming them, as evidenced by the reports in this section. Individual papers have been processed separately for inclusion in the Energy Science and Technology Database.

  8. Expectations for Oil Shale Production (released in AEO2009)

    Reports and Publications (EIA)

    2009-01-01

    Oil shales are fine-grained sedimentary rocks that contain relatively large amounts of kerogen, which can be converted into liquid and gaseous hydrocarbons (petroleum liquids, natural gas liquids, and methane) by heating the rock, usually in the absence of oxygen, to 650 to 700 degrees Fahrenheit (in situ retorting) or 900 to 950 degrees Fahrenheit (surface retorting). (Oil shale is, strictly speaking, a misnomer in that the rock is not necessarily a shale and contains no crude oil.) The richest U.S. oil shale deposits are located in Northwest Colorado, Northeast Utah, and Southwest Wyoming. Currently, those deposits are the focus of petroleum industry research and potential future production. Among the three states, the richest oil shale deposits are on federal lands in northwest Colorado.

  9. Hydrocarbon and Deposit Morphology Effects on EGR Cooler Deposit...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Deposit Morphology Effects on EGR Cooler Deposit Stability and Removal Hydrocarbon and Deposit Morphology Effects on EGR Cooler Deposit Stability and Removal This paper reports ...

  10. Running Out of and Into Oil: Analyzing Global Oil Depletion and Transition Through 2050

    SciTech Connect (OSTI)

    Greene, D.L.

    2003-11-14

    This report presents a risk analysis of world conventional oil resource production, depletion, expansion, and a possible transition to unconventional oil resources such as oil sands, heavy oil and shale oil over the period 2000 to 2050. Risk analysis uses Monte Carlo simulation methods to produce a probability distribution of outcomes rather than a single value. Probability distributions are produced for the year in which conventional oil production peaks for the world as a whole and the year of peak production from regions outside the Middle East. Recent estimates of world oil resources by the United States Geological Survey (USGS), the International Institute of Applied Systems Analysis (IIASA), the World Energy Council (WEC) and Dr. C. Campbell provide alternative views of the extent of ultimate world oil resources. A model of oil resource depletion and expansion for twelve world regions is combined with a market equilibrium model of conventional and unconventional oil supply and demand to create a World Energy Scenarios Model (WESM). The model does not make use of Hubbert curves but instead relies on target reserve-to-production ratios to determine when regional output will begin to decline. The authors believe that their analysis has a bias toward optimism about oil resource availability because it does not attempt to incorporate political or environmental constraints on production, nor does it explicitly include geologic constraints on production rates. Global energy scenarios created by IIASA and WEC provide the context for the risk analysis. Key variables such as the quantity of undiscovered oil and rates of technological progress are treated as probability distributions, rather than constants. Analyses based on the USGS and IIASA resource assessments indicate that conventional oil production outside the Middle East is likely to peak sometime between 2010 and 2030. The most important determinants of the date are the quantity of undiscovered oil, the rate at

  11. Beginning of an oil shale industry in Australia

    SciTech Connect (OSTI)

    Wright, B. (Southern Pacific Petroleum NL, 143 Macquarie Street, Sydney (AU))

    1989-01-01

    This paper discusses how preparations are being made for the construction and operation of a semi commercial plant to process Australian oil shale. This plant is primarily designed to demonstrate the technical feasibility of processing these shales at low cost. Nevertheless it is expected to generate modest profits even at this demonstration level. This will be the first step in a three staged development of one of the major Australian oil shale deposits which may ultimately provide nearly 10% of Australia's anticipated oil requirements by the end of the century. In turn this development should provide the basis for a full scale oil shale industry in Australia based upon the advantageously disposed oil shale deposits there. New sources of oil are becoming critical since Australian production is declining rapidly while consumption is accelerating.

  12. Heavy Vehicle Systems

    SciTech Connect (OSTI)

    Sid Diamond; Richard Wares; Jules Routbort

    2000-04-11

    Heavy Vehicle (HV) systems are a necessary component of achieving OHVT goals. Elements are in place for a far-ranging program: short, intermediate, and long-term. Solicitation will bring industrial input and support. Future funding trend is positive, outlook for HV systems is good.

  13. Deposition head for laser

    DOE Patents [OSTI]

    Lewis, Gary K. (Los Alamos, NM); Less, Richard M. (Los Alamos, NM)

    1999-01-01

    A deposition head for use as a part of apparatus for forming articles from materials in particulate form in which the materials are melted by a laser beam and deposited at points along a tool path to form an article of the desired shape and dimensions. The deposition head delivers the laser beam and powder to a deposition zone, which is formed at the tip of the deposition head. A controller comprised of a digital computer directs movement of the deposition zone along the tool path and provides control signals to adjust apparatus functions, such as the speed at which the deposition head moves along the tool path.

  14. direct_deposit_111609

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PROTECT YOUR BANKING INFORMATION: DO NOT complete this form until you are ready to submit it to the Payroll Department. DIRECT DEPOSIT REQUEST Directions: 1. Provide required information neatly, legibly; 2. If Checking Account Direct Deposit, include a voided check. a. DO NOT submit a deposit slip! 3. If Savings Account Direct Deposit, include a copy of savings card. 4. Sign this form; 5. Inter-office mail it to Craft Payroll at "P238." DIRECT DEPOSITION AUTHORIZATION I hereby

  15. Oil Sands Feedstocks | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sands Feedstocks Oil Sands Feedstocks Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. 2006_deer_fairbridge.pdf (1.94 MB) More Documents & Publications Energy Independence for North America - Transition to the Hydrogen Economy Emissions from Heavy-Duty Diesel Engine with EGR using Oil Sands Derived Fuels The Influence of Molecular Structure of Distillate Fuels on HFRR

  16. Lifecycle-analysis for heavy vehicles.

    SciTech Connect (OSTI)

    Gaines, L.

    1998-04-16

    Various alternative fuels and improved engine and vehicle systems have been proposed in order to reduce emissions and energy use associated with heavy vehicles (predominantly trucks). For example, oil companies have proposed improved methods for converting natural gas to zero-aromatics, zero-sulfur diesel fuel via the Fischer-Tropsch process. Major heavy-duty diesel engine companies are working on ways to simultaneously reduce particulate-matter and NOX emissions. The trend in heavy vehicles is toward use of lightweight materials, tires with lower rolling resistance, and treatments to reduce aerodynamic drag. In this paper, we compare the Mecycle energy use and emissions from trucks using selected alternatives, such as Fisher-Tropsch diesel fuel and advanced fuel-efficient engines. We consider heavy-duty, Class 8 tractor-semitrailer combinations for this analysis. The total life cycle includes production and recycling of the vehicle itself, extraction, processing, and transportation of the fuel itself, and vehicle operation and maintenance. Energy use is considered in toto, as well as those portions that are imported, domestic, and renewable. Emissions of interest include greenhouse gases and criteria pollutants. Angonne's Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) model is used to generate per-vehicle fuel cycle impacts. Energy use and emissions for materials manufacturing and vehicle disposal are estimated by means of materials information from Argonne studies. We conclude that there are trade-offs among impacts. For example, the lowest fossil energy use does not necessarily result in lowest total energy use, and lower tailpipe emissions may not necessarily result in lower lifecycle emissions of all criteria pollutants.

  17. SECTION II: HEAVY ION REACTIONS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    II: HEAVY ION REACTIONS Experimental Determination of the Symmetry Energy of a Low Density Nuclear Gas ......II-1 S. ...

  18. PIA - Northeast Home Heating Oil Reserve System (Heating Oil...

    Broader source: Energy.gov (indexed) [DOE]

    Northeast Home Heating Oil Reserve System (Heating Oil) PIA - Northeast Home Heating Oil Reserve System (Heating Oil) (3.31 MB) More Documents & Publications PIA - WEB Physical ...

  19. FCC Pilot Plant Results with Vegetable Oil and Pyrolysis Oil...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    FCC Pilot Plant Results with Vegetable Oil and Pyrolysis Oil Feeds FCC Pilot Plant Results with Vegetable Oil and Pyrolysis Oil Feeds Breakout Session 2: Frontiers and Horizons ...

  20. Geochemistry and habitat of the oils in Italy

    SciTech Connect (OSTI)

    Mattavelli, L.; Novelli, L. )

    1990-10-01

    All varieties of liquid petroleum, ranging from condensates (> 50{degree}API) to immature sulfur-rich heavy oils (as low as 5{degree} API), have been found in Italy. However, nonbiodegraded heavy oils account for about 70% of the total original oil in place. Geochemical analyses indicate that 11 oil groups are present in the Italian basins and two main types of source rocks have been identified: Triassic carbonates and Tertiary shales. About 95% of the oils were originated from Middle and Upper Triassic carbonates containing type II kerogen (about 1% total organic carbon (TOC) and 500 mg hydrocarbon/g TOC). Only a relatively minor amount of oil was generated by Tertiary shales containing type III kerogen with TOC generally less than 1%. Timing of generation and migration and bulk properties of oils were controlled by geodynamic histories of the three main Italian geologic settings: (1) Apennine and Southern Alp thrust belts, (2) foredeep (depression bordering the thrust belts), and (3) foreland (nondeformed African continental margin). Within the Apennine thrust belts, deep burial during the Neogene resulted in the generation of substantially lighter oils, not only from deeply buried Triassic but sometimes also from Tertiary source rocks. In the late Neogene, foredeep depocenters located in the central Adriatic and southern Sicily, high subsidence (up to 1,000 m/m.y.), a low geothermal gradient (22C/km) and compressional tectonics caused the generation of immature heavy oils generally at depths below 5,000 m and temperatures greater than 100C. Rapid burial and higher geothermal gradients (32C/km), which occurred since the Jurassic, resulted in the generation of light oils from the Late Cretaceous to the Oligocene in the southern sector of Adriatic foreland.

  1. Solubilities of heavy fossil fuels in compressed gases

    SciTech Connect (OSTI)

    Monge, A. Jr.

    1982-01-01

    Design of processes for upgrading heavy fossil fuels such as coal-derived liquids, heavy petroleum fractions, tar sands, and shale oil, requires quantitative information for equilibrium properties of the fossil fuel in the presence of compressed light gases at elevated temperatures. Presented here are methods to predict and measure solubilities of heavy fossil fuels in compressed gases in the region ambient to 100 bar and 600 K. A molecular-thermodynamic model is used to predict heavy fossil-fuel solubilities. The heavy fuel is fractionated ina spinning-band column at low pressure and high reflux; each fraction is considered to be a pseudo-component. Each fraction is characterized by one vapor-pressure datum (obtained during fractionation), elemental analysis, and proton-NMR spectra (to determine aromaticity). Liquid-phase properties are obtained from the SWAP equation for vapor pressure and from a density correlation. Vapor-phase properties are obtained using the virial equation of state with virial coefficients from Kaul's correlation. The molecular-thermodynamic model has been used to establish a design-oriented computer program for calculating heavy, fossil-fuel solubility for general application in process design and, in particular, for isobaric condensation as a function of temperature as required for design of a continuous-flow heat exchanger. A total-vaporization technique is used to measure the solubilities of narrow-boiling, heavy fossil-fuel fractions in compressed gases. The solubility of a heavy fraction is determined from the volume of gas required to vaporize completely a small, measured mass of fossil-fuel sample. To test the molecular-thermodynamic model, the total-vaporization technique has been used to measure the solubilities of two Lurgi coal-tar fractions in compressed methane. Predicted and experimental solubilities agree well.

  2. Oil and gas development in East Siberia

    SciTech Connect (OSTI)

    Sagers, M.J.

    1994-03-01

    The East Siberian region, which comprises nearly 43% of Russia`s territory (including the Sakha (Yakut) republic), has substantial hydrocarbon potential that is impeded by significant logistical problems, the daunting physical environment, and technical challenges posed by the geological complexity of the region. The area`s three major oil and gas provinces are the Lena-Tunguska (with the greatest potential), Lena-Vilyuy, and Yenisey-Anabar. The paper focuses on assessment of reserves, production potential, and history, as well as joint-venture activity involving foreign capital. Foreign investment is targeting gas deposits in the Vilyuy basin and elsewhere in the Sakha republic and small oil deposits serving local markets in the Yakutsk and Noril`sk areas. Forecasts do not envisage substantial production of oil from the region before the year 2010. Future gas production levels are less predictable despite the ambitious plans to export gas from Sakha to South Korea. 14 refs., 1 fig., 1 tab.

  3. Heavy Vehicle Propulsion Materials

    SciTech Connect (OSTI)

    Ray Johnson

    2000-01-31

    The objectives are to Provide Key Enabling Materials Technologies to Increase Energy Efficiency and Reduce Exhaust Emissions. The following goals are listed: Goal 1: By 3rd quarter 2002, complete development of materials enabling the maintenance or improvement of fuel efficiency {ge} 45% of class 7-8 truck engines while meeting the EPA/Justice Department ''Consent Decree'' for emissions reduction. Goal 2: By 4th quarter 2004, complete development of enabling materials for light-duty (class 1-2) diesel truck engines with efficiency over 40%, over a wide range of loads and speeds, while meeting EPA Tier 2 emission regulations. Goal 3: By 4th quarter 2006, complete development of materials solutions to enable heavy-duty diesel engine efficiency of 50% while meeting the emission reduction goals identified in the EPA proposed rule for heavy-duty highway engines.''

  4. Viscous heavy brines

    SciTech Connect (OSTI)

    House, R.F.; Hoover, L.D.

    1984-07-10

    Hydroxyethyl cellulose and a sequestrant are added to a heavy brine containing one or more salts selected from calcium chloride, calcium bromide, and zinc bromide to increase the viscosity of the brine. Preferably the brine contains zinc bromide, has a density in the range from about 14.2-19.2 pounds per gallon, and the sequestrant is a polyphosphonic acid or water soluble salt thereof.

  5. Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures...

    U.S. Energy Information Administration (EIA) Indexed Site

    . Total Fuel Oil Consumption and Expenditures for Non-Mall Buildings, 2003" ,"All Buildings* Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures" ,"Number of Buildings...

  6. Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures...

    U.S. Energy Information Administration (EIA) Indexed Site

    A. Total Fuel Oil Consumption and Expenditures for All Buildings, 2003" ,"All Buildings Using Fuel Oil",,,"Fuel Oil Consumption",,"Fuel Oil Expenditures" ,"Number of Buildings...

  7. Heavy oil catalytic cracking process and apparatus (Patent) ...

    Office of Scientific and Technical Information (OSTI)

    Subject: 02 PETROLEUM; 42 ENGINEERING; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CATALYSTS; COOLING; PETROLEUM; CATALYTIC CRACKING; AIR POLLUTION CONTROL; COKE; ...

  8. Development of High Performance Heavy Duty Engine Oils

    Broader source: Energy.gov [DOE]

    FAME biodiesel will likely remain a part of the global diesel pool for the coming years and the use of biodiesel can lead to lubrication issues.

  9. Heavy oil upgrading using halide catalysts in a bubbling microautoclave

    SciTech Connect (OSTI)

    Chakma, A.; Chornet, E.; Overend, R.P.; Dawson, W. )

    1988-01-01

    Athabasca bitumen has been treated with halide catalysts under a continuous flow of H{sub 2} in a 15 ml microautoclave. The H{sub 2} was bubbled through the liquid using a microporous steel grid. ZnCl{sub 2}, CuCl and ZnCl{sub 2}/CuCl mixtures, with and without tetralin, were used as catalysts. The experimental conditions were: 13.8 MPa operating pressure, 1 liter STP/min as H{sub 2} flow rate, 425-450 C and 30 min as reaction temperature and time, respectively. ZnCl{sub 2} has been found effective for converting asphaltenes into maltenes while lowering the coke formation with respect to the uncatalyzed reaction. The addition of tetralin to the reaction mixture minimized coke and gas formation.

  10. Heavy oil upgrading using halide catalysts in a bubbling microautoclave

    SciTech Connect (OSTI)

    Chakma, A.; Chornet, E.; Overend, R.P. ); Dawson, W. )

    1988-06-01

    Athabasca bitumen with halide catalysts has been treated under a continuous flow of H/sub 2/ in a 15 mL microautoclave. The H/sub 2/ was bubbled through the liquid using a microporous steel grid. ZnCl/sub 2/, CuCl and ZnCl/sub 2//CuCl mixtures, with and without tetralin, were used as catalysts. The experimental conditions were: 13.8 MPa operating pressure, 1 L/sub STP/min/ as H/sub 2/ flowrate, 425 - 450/sup 0/C and 30 min as reaction temperature and time respectively. ZnCl/sub 2/ has been found effective for converting asphaltenes into maltenes while lowering the coke formation with respect to the uncatalyzed reaction. The addition of tetralin to the reaction mixture minimized coke and gas formation.

  11. Method for enhancing heavy oil production using hydraulic fracturing

    SciTech Connect (OSTI)

    Jennings, A.R. Jr.; Smith, R.C.

    1991-04-09

    This patent describes a method for producing viscous substantially fines-free hydrocarbonaceous fluids from an unconsolidated or loosely consolidated formation. It comprises drilling into the formation at least one well into a first productive interval of the formation; fracturing hydraulically the well with a viscous fracturing fluid containing a proppant therein which is of a size sufficient to prop a created fracture and restrict fines movement into the fracture which proppant comprises silicon carbide, silicon nitride, or garnet; injecting a pre-determined volume of steam into the well in an amount sufficient to soften the viscous fluid and lower the viscosity of the fluid adjacent a fracture face producing the well at a rate sufficient to allow formation fines to build up on a fracture face communicating with the well thereby resulting in a filter screen sufficient to substantially remove formation fines from the hydrocarbonaceous fluids; injecting a second volume of steam into the well and producing substantially fines free hydrocarbonaceous fluids to the surface; repeating steps until a desired amount of hydrocarbonaceous fluids have been produced from the first interval; and isolating mechanically the first interval and repeating steps in a second productive interval of the formation.

  12. Heavy oil catalytic cracking apparatus (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    It comprises a catalytic cracking reactor means; a separation means connective with the ... PETROLEUM REFINERIES; CATALYSTS; SEPARATION PROCESSES; CHEMICAL REACTIONS; ...

  13. Oil ash corrosion; A review of utility boiler experience

    SciTech Connect (OSTI)

    Paul, L.D. ); Seeley, R.R. )

    1991-02-01

    In this paper a review of experience with oil ash corrosion is presented along with current design practices used to avoid excessive tube wastage. Factors influencing oil ash corrosion include fuel chemistry, boiler operation, and boiler design. These factors are interdependent and determine the corrosion behavior in utility boilers. Oil ash corrosion occurs when vanadium-containing ash deposits on boiler tube surfaces become molten. These molten ash deposits dissolve protective oxides and scales causing accelerated tube wastage. Vanadium is the major fuel constituent responsible for oil ash corrosion. Vanadium reacts with sodium, sulfur, and chlorine during combustion to produce lower melting temperature ash compositions, which accelerate tube wastage. Limiting tube metal temperatures will prevent ash deposits from becoming molten, thereby avoiding the onset of oil ash corrosion. Tube metal temperatures are limited by the use of a parallel stream flow and by limiting steam outlet temperatures. Operating a boiler with low excess air has helped avoid oil ash corrosion by altering the corrosive combustion products. Air mixing and distribution are essential to the success of this palliative action. High chromium alloys and coatings form more stable protective scaled on tubing surfaces, which result in lower oil ash corrosion rates. However, there is not material totally resistant to oil ash corrosion.

  14. Heavy crudes, stocks pose desalting problems

    SciTech Connect (OSTI)

    Bartley, D.

    1982-02-02

    The design of electrostatic desalters for crudes lighter than 30 API is well established and is no longer considered a problem. However, since 1970, the number of desalting applications involving heavy crudes (less than 20 API), syncrudes, and residual fuels has increased markedly. These stocks present unique problems that require additional design considerations. All produced crude oils, including synthetic crude from shale, tar sands, and coal liquefaction, contain impurities that adversely affect production and refining processes, the equipment used in these processes, and the final products. The most common of these impurities are water, salt, solids, metals, and sulfur. The desalting process consists of (1) adding water with a low salt content (preferably fresh) to the feedstock; (2) adequately mixing this added water with the feedstock, which already contains some quantities of salty water, sediment, and/or crystalline salt; and (3) extracting as much water as possible from the feedstock.

  15. World Oil Prices and Production Trends in AEO2010 (released in AEO2010)

    Reports and Publications (EIA)

    2010-01-01

    In Annual Energy Outlook 2010, the price of light, low-sulfur (or "sweet") crude oil delivered at Cushing, Oklahoma, is tracked to represent movements in world oil prices. The Energy Information Administration makes projections of future supply and demand for "total liquids,"" which includes conventional petroleum liquids -- such as conventional crude oil, natural gas plant liquids, and refinery gain -- in addition to unconventional liquids, which include biofuels, bitumen, coal-to-liquids (CTL), gas-to-liquids (GTL), extra-heavy oils, and shale oil.

  16. World Oil Prices and Production Trends in AEO2009 (released in AEO2009)

    Reports and Publications (EIA)

    2009-01-01

    The oil prices reported in Annual Energy Outlook 2009 (AEO) represent the price of light, low-sulfur crude oil in 2007 dollars. Projections of future supply and demand are made for "liquids," a term used to refer to those liquids that after processing and refining can be used interchangeably with petroleum products. In AEO2009, liquids include conventional petroleum liquids -- such as conventional crude oil and natural gas plant liquids -- in addition to unconventional liquids, such as biofuels, bitumen, coal-to-liquids (CTL), gas-to-liquids (GTL), extra-heavy oils, and shale oil.

  17. Energy trump for Morocco: the oil shales

    SciTech Connect (OSTI)

    Rosa, S.D.

    1981-10-01

    The mainstays of the economy in Morocco are still agriculture and phosphates; the latter represent 34% of world exports. Energy demand in 1985 will be probably 3 times that in 1975. Most of the oil, which covers 82% of its energy needs, must be imported. Other possible sources are the rich oil shale deposits and nuclear energy. Four nuclear plants with a total of 600 MW are projected, but shale oil still will play an important role. A contract for building a pilot plant has been met recently. The plant is to be located at Timahdit and cost $13 million, for which a loan from the World Bank has been requested. If successful in the pilot plant, the process will be used in full scale plants scheduled to produce 400,000 tons/yr of oil. Tosco also has a contract for a feasibility study.

  18. Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Vehicle Technologies Office Merit Review 2014: Heavy-Duty ...

  19. Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Vehicle Technologies Office Merit Review 2014: Heavy-Duty Low-Temperature and Diesel ...

  20. Heavy Truck Engine Program

    SciTech Connect (OSTI)

    Nelson, Christopher

    2009-01-08

    The Heavy Duty Truck Engine Program at Cummins embodied three significant development phases. All phases of work strove to demonstrate a high level of diesel engine efficiency in the face of increasingly stringent emission requirements. Concurrently, aftertreatment system development and refinement was pursued in support of these efficiency demonstrations. The program's first phase focused on the demonstration in-vehicle of a high level of heavy duty diesel engine efficiency (45% Brake Thermal Efficiency) at a typical cruise condition while achieving composite emissions results which met the 2004 U.S. EPA legislated standards. With a combination of engine combustion calibration tuning and the development and application of Urea-based SCR and particulate aftertreatment, these demonstrations were successfully performed by Q4 of 2002. The second phase of the program directed efforts towards an in-vehicle demonstration of an engine system capable of meeting 2007 U.S. EPA legislated emissions requirements while achieving 45% Brake Thermal Efficiency at cruise conditions. Through further combustion optimization, the refinement of Cummins Cooled EGR architecture, the application of a high pressure common rail fuel system and the incorporation of optimized engine parasitics, Cummins Inc. successfully demonstrated these deliverables in Q2 of 2004. The program's final phase set a stretch goal of demonstrating 50% Brake Thermal Efficiency from a heavy duty diesel engine system capable of meeting 2010 U.S. EPA legislated emissions requirements. Cummins chose to pursue this goal through further combustion development and refinement of the Cooled EGR system architecture and also applied a Rankine cycle Waste Heat Recovery technique to convert otherwise wasted thermal energy to useful power. The engine and heat recovery system was demonstrated to achieve 50% Brake Thermal Efficiency while operating at a torque peak condition in second quarter, 2006. The 50% efficient engine

  1. Contracts for field projects and supporting research on enhanced oil recovery and improved drilling technology. Progress review No. 34, quarter ending March 31, 1983

    SciTech Connect (OSTI)

    Linville, B.

    1983-07-01

    Progress achieved for the quarter ending March 1983 are presented for field projects and supporting research for the following: chemical flooding; carbon dioxide injection; and thermal/heavy oil. In addition, progress reports are presented for: resource assessment technology; extraction technology; environmental and safety; microbial enhanced oil recovery; oil recovered by gravity mining; improved drilling technology; and general supporting research. (ATT)

  2. Oil and Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oil and Gas Oil and Gas R&D focus on the use of conventional and unconventional fossil fuels, including associated environmental challenges Contact thumbnail of Business ...

  3. Oil Security Metrics Model

    SciTech Connect (OSTI)

    Greene, David L.; Leiby, Paul N.

    2005-03-06

    A presentation to the IWG GPRA USDOE, March 6, 2005, Washington, DC. OSMM estimates oil security benefits of changes in the U.S. oil market.

  4. Oil & Gas Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oil & Gas Research Unconventional Resources NETL's onsite research in unconventional ... quantify potential risks associated with oil and gas resources in shale reservoirs that ...

  5. Characterizing Heavy Ion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heavy Ion Reactions in the 1980's Is there Treasure at the end of the Rainbow? & What happens and how do different modes compete? John Schiffer One of the three research areas for ATLAS, as stated in a 1984 document to Congress: Are there some new marvelous symmetries, hidden in resonances in heavier nuclei, beyond 12 C+ 12 C and its immediate vicinity? (s.c. linac work, pre-ATLAS) Other attempts to chase the rainbow 180 o elastic scattering of 12 C on 40 Ca shows structure Fusion of 16 O on

  6. Method of removal of heavy metal from molten salt in IFR fuel pyroprocessing

    DOE Patents [OSTI]

    Gay, E.C.

    1995-10-03

    An electrochemical method is described for separating heavy metal values from a radioactive molten salt including Li halide at temperatures of about 500 C. The method comprises positioning a solid Li--Cd alloy anode in the molten salt containing the heavy metal values, positioning a Cd-containing cathode or a solid cathode positioned above a catch crucible in the molten salt to recover the heavy metal values, establishing a voltage drop between the anode and the cathode to deposit material at the cathode to reduce the concentration of heavy metals in the salt, and controlling the deposition rate at the cathode by controlling the current between the anode and cathode. 3 figs.

  7. Focus on Venezuelan heavy crude: refining margins

    SciTech Connect (OSTI)

    Not Available

    1984-01-25

    Of six crudes refined in the US Gulf Coast, heavy Venezuelan crude Lagunillas (15/sup 0/ API) provides the best margin per barrel. Data for end of December 1983 and the first three weeks of January show that margins on all crudes are on the rise in this market, due to a turnaround in product prices. The lighter crudes are showing the greatest increase in Gross Product Worth. This is having a modest shrinking effect on the margin differential between light and heavy crudes in this market. The domestic crude West Texas Intermediate, at 40/sup 0/ API, provides the highest GPW in this crude slate sample, over US $31 per barrel, compared to GPW of under US $28 per barrel for Lagunillas. Still, as Lagunillas cost about US $8 less than does WTI, refiners with sufficient residue conversion capacity can be earning about US $3.50 more in margin per barrel than they can with WTI. Although few refiners would be using a 15/sup 0/ API crude exclusively for any length of time, heavier oil's inclusion in modern refiners' diets is enhancing their competitive position more than any other single factor. This issue of Energy Detente presents the fuel price/tax series and industrial fuel prices for January 1984 for countries of the Western Hemisphere.

  8. Biochemically enhanced oil recovery and oil treatment

    DOE Patents [OSTI]

    Premuzic, E.T.; Lin, M.

    1994-03-29

    This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil. 62 figures.

  9. Biochemically enhanced oil recovery and oil treatment

    DOE Patents [OSTI]

    Premuzic, Eugene T.; Lin, Mow

    1994-01-01

    This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil.

  10. Residual oil upgrading utilizing fixed bed hydroprocessing technology

    SciTech Connect (OSTI)

    Hohnholt, J.; Fausto, C.

    1985-01-01

    Saber Refinery embarked upon major residual oil upgrading project in an effort to convert heavy atmospheric resids into gasoline and other marketable products. Selection of resid hydroprocessing as an HOC feed preparation unit was necessary for removal of impurities which include organic metallic compounds, nitrogen and sulfur, while enhancing feedstock crackability.

  11. SECTION II: HEAVY ION REACTIONS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for heavy element production...II-1 P. K.Sahu, J. B. Natowitz, R. Wada, K. Hagel, T. Materna, Z. Chen, L. Qin, M. Barbui,...

  12. Heavy-flavor production overview

    SciTech Connect (OSTI)

    Jeffrey A. Appel

    2003-12-10

    This talk serves as an introduction to the Heavy-Flavor session of the XXXIII International Symposium on Multiparticle Dynamics. A major focus of this session is on the production of heavy quarks. The talks which follow review the latest results on heavy quark production in strong, electromagnetic, and weak interactions, as well as some of the physics of the heavy quarks themselves. This talk emphasizes what we can learn from the production measurements, both about underlying QCD theory and the partonic nature of the hadrons which we see in the laboratory.

  13. INL '@work' heavy equipment mechanic

    SciTech Connect (OSTI)

    Christensen, Cad

    2008-01-01

    INL's Cad Christensen is a heavy equipment mechanic. For more information about INL careers, visit http://www.facebook.com/idahonationallaboratory.

  14. INL '@work' heavy equipment mechanic

    ScienceCinema (OSTI)

    Christensen, Cad

    2013-05-28

    INL's Cad Christensen is a heavy equipment mechanic. For more information about INL careers, visit http://www.facebook.com/idahonationallaboratory.

  15. Heavy crude and tar sands: Hydrocarbons for the 21st century. Volume 4, Upgrading, government and environment

    SciTech Connect (OSTI)

    Meyer, R.F.

    1991-12-31

    The 46 reports in Volume 4 begin with a section in the all-important subject of upgrading. Seventeen papers deals with upgrading of heavy oil and bitumen involving either of two basic processes, hydrogen addition or carbon rejection. Another five reports deal with the treatment of the oil in upgrading process through demetallization and by coprocessing with coal or lignite. The two papers on the Imulsion process present both the technology and the field experiences developed to transport and produce ORIMULSION{trademark}, the fuel developed with the bitumen from the Orinoco Belt. Seven papers in the section on environmental impacts are directed specifically to heavy oil. These deal mostly with the upgrading process, although one addresses the vexing problems of the refusal of extraction fines to settle out of tailings ponds in oil sand processing. A principal objective of the Centre is the fostering of technical cooperation between countries and the transfer of technological expertise in the area of heavy oil and natural bitumens from countries with advanced technology to those with undeveloped resources. The five reports in the section on Marketing and Economics carefully consider the demand in the context of world oil supply. Economic incentives is the stage for the final section of the volume, Government Policies and Legal Considerations. One of these reports presents an excellent review of the Venezuelan oil industry and its major efforts to promote the exploitation and utilization of heavy crude oil. Another of the reports describes ways in which the leasing procedures in Alberta may be modified to make the development of oil sands more effective. A third paper outlines procedures a company may usefully follow in order to most efficiently undertake the entire process of obtaining and developing oil sands leases. Individual papers have been processed separately for the database.

  16. Expansion of the commercial output of Estonian oil shale mining and processing

    SciTech Connect (OSTI)

    Fraiman, J.; Kuzmiv, I. [Estonian Oil Shale State Co., Jyhvi (Estonia). Scientific Research Center

    1996-09-01

    Economic and ecological preconditions are considered for the transition from monoproduct oil shale mining to polyproduct Estonian oil shale deposits. Underground water, limestone, and underground heat found in oil shale mines with small reserves can be operated for a long time using chambers left after oil shale extraction. The adjacent fields of the closed mines can be connected to the operations of the mines that are still working. Complex usage of natural resources of Estonian oil shale deposits is made possible owing to the unique features of its geology and technology. Oil shale seam development is carried out at shallow depths (40--70 m) in stable limestones and does not require expensive maintenance. Such natural resources as underground water, carbonate rocks, heat of rock mass, and underground chambers are opened by mining and are ready for utilization. Room-and-pillar mining does not disturb the surface, and worked oil shale and greenery waste heaps do not breach its ecology. Technical decisions and economic evaluation are presented for the complex utilization of natural resources in the boundaries of mine take of the ``Tammiku`` underground mine and the adjacent closed mine N2. Ten countries have already experienced industrial utilization of oil shale in small volumes for many years. Usually oil shale deposits are not notable for complex geology of the strata and are not deeply bedded. Thus complex utilization of quite extensive natural resources of Estonian oil shale deposits is of both scientific and practical interest.

  17. Oil Production

    Energy Science and Technology Software Center (OSTI)

    1989-07-01

    A horizontal and slanted well model was developed and incorporated into BOAST, a black oil simulator, to predict the potential production rates for such wells. The HORIZONTAL/SLANTED WELL MODEL can be used to calculate the productivity index, based on the length and location of the wellbore within the block, for each reservoir grid block penetrated by the horizontal/slanted wellbore. The well model can be run under either pressure or rate constraints in which wellbore pressuresmore » can be calculated as an option of infinite-conductivity. The model can simulate the performance of multiple horizontal/slanted wells in any geometric combination within reservoirs.« less

  18. Geology and geochemistry of crude oils, Bolivar coastal fields, Venezuela

    SciTech Connect (OSTI)

    Bockmeulen, H.; Barker, C.; Dickey, P.A.

    1983-02-01

    The Bolivar Coastal Fields (BCF) are located on the eastern margin of Lake Maracaibo, Venezuela. They form the largest oil field outside of the Middle East and contain mostly heavy oil with a gravity less than 22/sup 0/ API. Thirty crude oils from the BCF were collected along two parallel and generally southwest-northeast trends. These oils were characterized by their API gravity, percent saturates, aromatics, NSO and asphalitic compounds, gas chromatograms for whole oils, C/sub 4/-C/sub 7/ fractions, and aromatics. Also, 24 associated waters were sampled and analyzed for Ca/sup + +/, Mg/sup + +/, Na/sup +/, HCO/sub 3//sup -/, CO/sub 3//sup - -/, SO/sub 4//sup - -/, pH, and total dissolved solids (TDS). The geological and geochemical significances of these analyses are discussed with particular emphasis on the genesis of the petroleum.

  19. Geochemistry and habitat of oils in Italy

    SciTech Connect (OSTI)

    Novelli, L.; Mattavelli, L.

    1988-02-01

    Most of the onshore and offshore oil occurrences found in Italy have been systematically analyzed by different techniques, i.e., capillary gas chromatography, biological markers, and stable isotopes composition. On the basis of the above analyses, ten different groups of oil have been identified and geographically located. Subsequently, the influence of the various geological settings on generation and migration of these different groups of oils was investigated and is discussed here. In a foredeep regime, the remarkably fast heating rates, due to the rapid burial during late Tertiary, caused a rapid generation of oil mainly in the Triassic carbonate source rocks. Such generation, combined with the high over-burden pressure and a contemporaneous development of an intense tectonic compression, resulted in the expulsion of immature, heavy oils. Examples of this are evident in the central Adriatic Sea, southern Italy, and southeastern Sicily. Due to its complex geological and tectonic history, the Alpine-Apennine chain behaved differently with regard to oil generation and migration in different areas. In fact, the high temperatures reached by the Mesozoic source rocks underneath a stack of allochthonous thrust sheets and the insulating thermal blanket effect exerted by the same sheets on other younger source rocks above gave rise to generally light oils. Furthermore, in this unique geological setting, the most external thrust sheets locally acted as reservoirs of the foredeep regime. Foreland sequences acted as both reservoirs of the foredeep oils and as generative kitchens of liquid hydrocarbons if suitable source rocks were present and adequate burial was reached.

  20. APBF-DEC Heavy Duty NOx Adsorber/DPF Project: Heavy Duty Linehaul...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy Duty NOx AdsorberDPF Project: Heavy Duty Linehaul Platform Project Update APBF-DEC Heavy Duty NOx AdsorberDPF Project: Heavy Duty Linehaul Platform Project Update 2003 DEER ...

  1. Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty ...

  2. Eco Oil 4

    SciTech Connect (OSTI)

    Brett Earl; Brenda Clark

    2009-10-26

    This article describes the processes, challenges, and achievements of researching and developing a biobased motor oil.

  3. World Crude Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    World Crude Oil Prices (Dollars per Barrel) The data on this page are no longer available.

  4. HEAVY ION LINEAR ACCELERATOR

    DOE Patents [OSTI]

    Van Atta, C.M.; Beringer, R.; Smith, L.

    1959-01-01

    A linear accelerator of heavy ions is described. The basic contributions of the invention consist of a method and apparatus for obtaining high energy particles of an element with an increased charge-to-mass ratio. The method comprises the steps of ionizing the atoms of an element, accelerating the resultant ions to an energy substantially equal to one Mev per nucleon, stripping orbital electrons from the accelerated ions by passing the ions through a curtain of elemental vapor disposed transversely of the path of the ions to provide a second charge-to-mass ratio, and finally accelerating the resultant stripped ions to a final energy of at least ten Mev per nucleon.

  5. ,"Total Fuel Oil Consumption (trillion Btu)",,,,,"Fuel Oil Energy...

    U.S. Energy Information Administration (EIA) Indexed Site

    A. Fuel Oil Consumption (Btu) and Energy Intensities by End Use for All Buildings, 2003" ,"Total Fuel Oil Consumption (trillion Btu)",,,,,"Fuel Oil Energy Intensity (thousand Btu...

  6. Crude oil and alternate energy production forecasts for the twenty-first century: The end of the hydrocarbon era

    SciTech Connect (OSTI)

    Edwards, J.D.

    1997-08-01

    Predictions of production rates and ultimate recovery of crude oil are needed for intelligent planning and timely action to ensure the continuous flow of energy required by the world`s increasing population and expanding economies. Crude oil will be able to supply increasing demand until peak world production is reached. The energy gap caused by declining conventional oil production must then be filled by expanding production of coal, heavy oil and oil shales, nuclear and hydroelectric power, and renewable energy sources (solar, wind, and geothermal). Declining oil production forecasts are based on current estimated ultimate recoverable conventional crude oil resources of 329 billion barrels for the United States and close to 3 trillion barrels for the world. Peak world crude oil production is forecast to occur in 2020 at 90 million barrels per day. Conventional crude oil production in the United States is forecast to terminate by about 2090, and world production will be close to exhaustion by 2100.

  7. GAO; Venezuelan reforms do little to spark oil investiment by U. S. firms

    SciTech Connect (OSTI)

    Not Available

    1992-02-03

    This paper reports that Venezuela's 1991 foreign investment reforms did little to encourage U.S. oil companies to invest there despite the overall investment attractiveness of the country's oil sector, says the U.S. General Accounting Office. In a report to Congress, GAO noted Venezuela's oil production peaked in 1970, declined through 1985, and since then has increased by about 21% through 1990. The primary factors affecting continued increases in production through 1996 include Petroleos de Venezuela SA's ability to encourage investment capital, the cost of producing and refining heavy and extra heavy crude oil., and the level of production quotas imposed by the Organization of Petroleum Exporting Countries, of which Venezuela is a member. GAO noted Venezuela implemented policy reforms in 1991 to encourage some foreign and private investment petroleum related ventures. However, these reforms have not yet succeeded in attracting U.S. investment in oil exploration, production, or refining in Venezuela.

  8. Ben South (Tannehill) oil field, Stonewall, County, Texas

    SciTech Connect (OSTI)

    Hillock, R.T.

    1984-01-01

    Ben South is one of 157 Tannehill oil fields on the northeastern shelf of the Permian basin. Texas Railroad Commission District 7B has 66 Tannehill oil fields while District 8A has 21. The discovery well for the Ben South field was the Ryder Scott Management (Sauder) 1 McMeans, completed in 1973. Ben South field production has totaled 749,340 bbl of oil through March 1983 from 13 wells. Oil production is from the lower Tannehill (lower Wolfcamp) sands underlying the Stockwether Limestone. These Tannehill sands were deposited in a fluvial environment. Channel-fill and point-bar deposits make up the pay sands. The trapping mechanism is both stratigraphic and structural.

  9. Heavy Isotopes Lead Materials Management Organization (LMMO)...

    Office of Scientific and Technical Information (OSTI)

    Heavy Isotopes Lead Materials Management Organization (LMMO) Update Citation Details In-Document Search Title: Heavy Isotopes Lead Materials Management Organization (LMMO) Update ...

  10. Policy Analysis of the Canadian Oil Sands Experience

    SciTech Connect (OSTI)

    None, None

    2013-09-01

    For those who support U.S. oil sands development, the Canadian oil sands industry is often identified as a model the U.S. might emulate, yielding financial and energy security benefits. For opponents of domestic oil sands development, the Canadian oil sands experience illustrates the risks that opponents of development believe should deter domestic policymakers from incenting U.S. oil sands development. This report does not seek to evaluate the particular underpinnings of either side of this policy argument, but rather attempts to delve into the question of whether the Canadian experience has relevance as a foundational model for U.S. oil sands development. More specifically, this report seeks to assess whether and how the Canadian oil sands experience might be predictive or instructive in the context of fashioning a framework for a U.S. oil sands industry. In evaluating the implications of these underpinnings for a prospective U.S. oil sands industry, this report concentrates on prospective development of the oil sands deposits found in Utah.

  11. Radionuclide deposition control

    DOE Patents [OSTI]

    Brehm, William F.; McGuire, Joseph C.

    1980-01-01

    The deposition of radionuclides manganese-54, cobalt-58 and cobalt-60 from liquid sodium coolant is controlled by providing surfaces of nickel or high nickel alloys to extract the radionuclides from the liquid sodium, and by providing surfaces of tungsten, molybdenum or tantalum to prevent or retard radionuclide deposition.

  12. Going Global: Tight Oil Production

    Gasoline and Diesel Fuel Update (EIA)

    GOING GLOBAL: TIGHT OIL PRODUCTION Leaping out of North America and onto the World Stage JULY 2014 GOING GLOBAL: TIGHT OIL PRODUCTION Jamie Webster, Senior Director Global Oil ...

  13. Processing heavy crudes: advances in fluid and flexicoking technology

    SciTech Connect (OSTI)

    Allan, D.E.; Metrailer, W.J.; King, R.C.; Wiechert, S.

    1981-12-01

    The authors are concerned with Exxon's Fluid and Flexicoking processes which allow the refiner to convert the bottom of the crude barrel to clean products. This article primarily discusses enhancement of liquid yields from both processes and reduction of low-Btu gas from Flexicoking. Also discussed are recent advances in coking technology, which could make these processes more attractive. Flexicoking is an integrated coking/gasification process for upgrading heavy feedstocks. The process converts these feeds to a 99% yield of fuel gas, naphtha, middle distillates, heavy gas oil, and a low-sulfur coke gas. The remaining 1% is petroleum coke containing metals and other ash components present in the feed. 6 refs.

  14. Solution deposition assembly

    DOE Patents [OSTI]

    Roussillon, Yann; Scholz, Jeremy H; Shelton, Addison; Green, Geoff T; Utthachoo, Piyaphant

    2014-01-21

    Methods and devices are provided for improved deposition systems. In one embodiment of the present invention, a deposition system is provided for use with a solution and a substrate. The system comprises of a solution deposition apparatus; at least one heating chamber, at least one assembly for holding a solution over the substrate; and a substrate curling apparatus for curling at least one edge of the substrate to define a zone capable of containing a volume of the solution over the substrate. In another embodiment of the present invention, a deposition system for use with a substrate, the system comprising a solution deposition apparatus; at heating chamber; and at least assembly for holding solution over the substrate to allow for a depth of at least about 0.5 microns to 10 mm.

  15. First joint SPE/DOE symposium on enhanced oil recovery, proceedings supplement

    SciTech Connect (OSTI)

    1980-01-01

    The First Joint Symposium on Enhanced Oil Recovery sponsored by the Society of Petroleum Engineers and the US Department of Energy was held in Tulsa, Oklahoma. Besides the thirty-three technical papers which covered all phases of enhanced oil recovery and were published in the Proceedings, the Symposium included a session on Enhanced Oil Recovery Incentives where ten papers were presented which discussed the status of enhanced oil recovery technology, and included papers on incentive programs of the United States, Canada and Venezuela. These papers are published in this Proceedings Supplement under the following titles: Federal Government Role in enhanced Oil Recovery; Financial Realities of an Adequate Petroleum Supply; Major Technology Constraints in Enhanced Oil Recovery; Decontrol-Opportunities and Dangers; Status of EOR Technology; Impact of Federal Incentives on US Production; Canadian Incentives Program; and Heavy Oil Incentives in Venezuela.

  16. Prospects for applications of electron beams in processing of gas and oil hydrocarbons

    SciTech Connect (OSTI)

    Ponomarev, A. V.; Pershukov, V. A.; Smirnov, V. P.

    2015-12-15

    Waste-free processing of oil and oil gases can be based on electron-beam technologies. Their major advantage is an opportunity of controlled manufacturing of a wide range of products with a higher utility value at moderate temperatures and pressures. The work considers certain key aspects of electron beam technologies applied for the chain cracking of heavy crude oil, for the synthesis of premium gasoline from oil gases, and also for the hydrogenation, alkylation, and isomerization of unsaturated oil products. Electronbeam processing of oil can be embodied via compact mobile modules which are applicable for direct usage at distant oil and gas fields. More cost-effective and reliable electron accelerators should be developed to realize the potential of electron-beam technologies.

  17. Waste oils utilized as coal liquefaction solvents on differing ranks of coal

    SciTech Connect (OSTI)

    Orr, E.C.; Shi, Y.; Liang, J.

    1995-12-31

    To determine the feasibility of using different waste oils as solvent media for coals of differing rank, oil from automobile crankcases, oil derived from the vacuum pyrolysis of waste rubber tires, and oil derived from the vacuum pyrolysis of waste plastics, have been heated to 430{degrees}C with coal in tubing reactors a hydrotreated for 1 hour. Analysis of the solvents indicates the presence of heavy metals in the waste automobile oil. Analysis of the plastic oil shows the presence of iron and calcium. The analysis of the tire oil shows the presence of zinc. Conversion yields are compared and results of analysis for the presence of metals in the liquid products are reported.

  18. Apparatus for distilling shale oil from oil shale

    SciTech Connect (OSTI)

    Shishido, T.; Sato, Y.

    1984-02-14

    An apparatus for distilling shale oil from oil shale comprises: a vertical type distilling furnace which is divided by two vertical partitions each provided with a plurality of vent apertures into an oil shale treating chamber and two gas chambers, said oil shale treating chamber being located between said two gas chambers in said vertical type distilling furnace, said vertical type distilling furnace being further divided by at least one horizontal partition into an oil shale distilling chamber in the lower part thereof and at least one oil shale preheating chamber in the upper part thereof, said oil shale distilling chamber and said oil shale preheating chamber communication with each other through a gap provided at an end of said horizontal partition, an oil shale supplied continuously from an oil shale supply port provided in said oil shale treating chamber at the top thereof into said oil shale treating chamber continuously moving from the oil shale preheating chamber to the oil shale distilling chamber, a high-temperature gas blown into an oil shale distilling chamber passing horizontally through said oil shale in said oil shale treating chamber, thereby said oil shale is preheated in said oil shale preheating chamber, and a gaseous shale oil is distilled from said preheated oil shale in said oil shale distilling chamber; and a separator for separating by liquefaction a gaseous shale oil from a gas containing the gaseous shale oil discharged from the oil shale preheating chamber.

  19. Crude Oil Characteristics Research

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SAE Plan June 29, 2015 Page 1 Crude Oil Characteristics Research Sampling, Analysis and Experiment (SAE) Plan The U.S. is experiencing a renaissance in oil and gas production. The Energy Information Administration projects that U.S. oil production will reach 9.3 million barrels per day in 2015 - the highest annual average level of oil production since 1972. This domestic energy boom is due primarily to new unconventional production of light sweet crude oil from tight-oil formations like the

  20. Creation and Testing of the ACES Heavy Heavy-Duty Diesel Engine Test

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Schedule for Representative Measurement of Heavy-Duty Engine Emissions | Department of Energy Creation and Testing of the ACES Heavy Heavy-Duty Diesel Engine Test Schedule for Representative Measurement of Heavy-Duty Engine Emissions Creation and Testing of the ACES Heavy Heavy-Duty Diesel Engine Test Schedule for Representative Measurement of Heavy-Duty Engine Emissions Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August,

  1. Method for controlling boiling point distribution of coal liquefaction oil product

    DOE Patents [OSTI]

    Anderson, Raymond P.; Schmalzer, David K.; Wright, Charles H.

    1982-12-21

    The relative ratio of heavy distillate to light distillate produced in a coal liquefaction process is continuously controlled by automatically and continuously controlling the ratio of heavy distillate to light distillate in a liquid solvent used to form the feed slurry to the coal liquefaction zone, and varying the weight ratio of heavy distillate to light distillate in the liquid solvent inversely with respect to the desired weight ratio of heavy distillate to light distillate in the distillate fuel oil product. The concentration of light distillate and heavy distillate in the liquid solvent is controlled by recycling predetermined amounts of light distillate and heavy distillate for admixture with feed coal to the process in accordance with the foregoing relationships.

  2. Method for controlling boiling point distribution of coal liquefaction oil product

    DOE Patents [OSTI]

    Anderson, R.P.; Schmalzer, D.K.; Wright, C.H.

    1982-12-21

    The relative ratio of heavy distillate to light distillate produced in a coal liquefaction process is continuously controlled by automatically and continuously controlling the ratio of heavy distillate to light distillate in a liquid solvent used to form the feed slurry to the coal liquefaction zone, and varying the weight ratio of heavy distillate to light distillate in the liquid solvent inversely with respect to the desired weight ratio of heavy distillate to light distillate in the distillate fuel oil product. The concentration of light distillate and heavy distillate in the liquid solvent is controlled by recycling predetermined amounts of light distillate and heavy distillate for admixture with feed coal to the process in accordance with the foregoing relationships. 3 figs.

  3. Fuel Oil Use in Manufacturing

    U.S. Energy Information Administration (EIA) Indexed Site

    logo Return to: Manufacturing Home Page Fuel Oil Facts Oil Price Effect Fuel Switching Actual Fuel Switching Storage Capacity Fuel Oil Use in Manufacturing Why Look at Fuel Oil?...

  4. Enhanced Oil Recovery

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enhanced Oil Recovery As much as two-thirds of conventional crude oil discovered in U.S. fields remains unproduced, left behind due to the physics of fluid flow. In addition, ...

  5. US Crude oil exports

    Gasoline and Diesel Fuel Update (EIA)

    2014 EIA Energy Conference U.S. Crude Oil Exports July 14, 2014 By Lynn D. Westfall U.S. Energy Information Administration U.S. crude oil production has grown by almost 50% since ...

  6. Crude Oil Characteristics Research

    Broader source: Energy.gov (indexed) [DOE]

    SAE Plan June 29, 2015 Page 1 Crude Oil Characteristics Research Sampling, Analysis and Experiment (SAE) Plan The U.S. is experiencing a renaissance in oil and gas production. The ...

  7. Sound Oil Company

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ... Ward Oil Co., 24 DOE 81,002 (1994); see also Belcher Oil Co., 15 DOE 81,018 (1987) ... months relief because of flood); Utilities Bd. of Citronelle-Gas, 4 DOE 81,205 (1979) ...

  8. South American oil

    SciTech Connect (OSTI)

    Not Available

    1992-06-01

    GAO reviewed the petroleum industries of the following eight South American Countries that produce petroleum but are not major exporters: Argentina, Bolivia, Brazil, Chile, Colombia, Ecuador, Peru, and Trinidad and Tobago. This report discusses the amount of crude oil the United States imports from the eight countries, expected crude oil production for these countries through the year 2010, and investment reforms that these countries have recently made in their petroleum industries. In general, although the United States imports some oil from these countries, as a group, the eight countries are currently net oil importers because combined domestic oil consumption exceeds oil production. Furthermore, the net oil imports are expected to continue to increase through the year 2010, making it unlikely that the United States will obtain increased oil shipments from these countries.

  9. CNEEC - Atomic Layer Deposition Tutorial by Stacey Bent

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Atomic Layer Deposition

  10. Vegetable oils for tractors

    SciTech Connect (OSTI)

    Moroney, M.

    1981-11-14

    Preliminary tests by the Agricultural Institute, show that tractors can be run on a 50:50 rape oil-diesel mixture or on pure rape oil. In fact, engine power actually increased slightly with the 50:50 blend but decreased fractionally with pure rape oil. Research at the North Dakota State University on using sunflower oil as an alternative to diesel fuel is also noted.

  11. Oil-futures markets

    SciTech Connect (OSTI)

    Prast, W.G.; Lax, H.L.

    1983-01-01

    This book on oil futures trading takes a look at a market and its various hedging strategies. Growing interest in trading of commodity futures has spread to petroleum, including crude oil, and key refined products such as gasoline and heating oil. This book describes how the international petroleum trade is structured, examines the working of oil futures markets in the United States and the United Kingdom, and assesses the possible courses of further developments.

  12. SRC residual fuel oils

    SciTech Connect (OSTI)

    Tewari, K.C.; Foster, E.P.

    1985-10-15

    Coal solids (SRC) and distillate oils are combined to afford single-phase blends of residual oils which have utility as fuel oils substitutes. The components are combined on the basis of their respective polarities, that is, on the basis of their heteroatom content, to assure complete solubilization of SRC. The resulting composition is a fuel oil blend which retains its stability and homogeneity over the long term.

  13. SRC Residual fuel oils

    DOE Patents [OSTI]

    Tewari, Krishna C.; Foster, Edward P.

    1985-01-01

    Coal solids (SRC) and distillate oils are combined to afford single-phase blends of residual oils which have utility as fuel oils substitutes. The components are combined on the basis of their respective polarities, that is, on the basis of their heteroatom content, to assure complete solubilization of SRC. The resulting composition is a fuel oil blend which retains its stability and homogeneity over the long term.

  14. Utilization of Estonian oil shale at power plants

    SciTech Connect (OSTI)

    Ots, A. [Tallin Technical Univ. (Estonia). Thermal Engineering Department

    1996-12-31

    Estonian oil shale belongs to the carbonate class and is characterized as a solid fuel with very high mineral matter content (60--70% in dry mass), moderate moisture content (9--12%) and low heating value (LHV 8--10 MJ/kg). Estonian oil shale deposits lie in layers interlacing mineral stratas. The main constituent in mineral stratas is limestone. Organic matter is joined with sandy-clay minerals in shale layers. Estonian oil shale at power plants with total capacity of 3060 MW{sub e} is utilized in pulverized form. Oil shale utilization as fuel, with high calcium oxide and alkali metal content, at power plants is connected with intensive fouling, high temperature corrosion and wear of steam boiler`s heat transfer surfaces. Utilization of Estonian oil shale is also associated with ash residue use in national economy and as absorbent for flue gas desulfurization system.

  15. Central Pacific Minerals and Southern Pacific Petroleum detail oil shale activities

    SciTech Connect (OSTI)

    Not Available

    1986-09-01

    These two affiliated companies have their major assets in Queensland. Brief summaries are given of the activities of the Rundle, Condor, and Yaamba oil shale projects and brief descriptions are given of the resources found in the Stuart, Nagoorin, Nagoorin South, Lowmead, and Duaringa oil shale deposits of Queensland. The companies also have, or are planning, oil shale projects in the US, Luxembourg, France, and the Federal Republic of Germany, and these are briefly described.

  16. Heavy ion fusion--Using heavy ions to make electricity

    SciTech Connect (OSTI)

    Celata, C.M.

    2004-03-15

    The idea of using nuclear fusion as a source of commercial electrical power has been pursued worldwide since the 1950s. Two approaches, using magnetic and inertial confinement of the reactants, are under study. This paper describes the difference between the two approaches, and discusses in more detail the heavy-ion-driven inertial fusion concept. A multibeam induction linear accelerator would be used to bring {approx}100 heavy ion beams to a few GeV. The beams would then heat and compress a target of solid D-T. This approach is unique among fusion concepts in its ability to protect the reaction chamber wall from neutrons and debris.

  17. Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Peer Evaluation PDF icon ace001musculus2011o.pdf More Documents & Publications Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Heavy-Duty ...

  18. Integration of upgrading in the production of extra heavy crudes from the orinoco belt

    SciTech Connect (OSTI)

    Solari, R.B.; Marzin, R.; Soler, L.

    1996-12-31

    Four heavy oil upgrading joint ventures with major oil players are currently being developed by Petroleos de Venezuela, S.A. (PDVSA) affiliates. Their objective is to build integrated production-upgrading complexes to transform the low quality heavy oil from the Orinoco Belt into valuable synthetic crude oil (SCO). One of this joint ventures, a partnership between Corpoven, S.A. and ARCO International Oil and Gas Co., thoroughly evaluated the new HDH{trademark} hydroprocessing technology of Intevep, S.A. as an option to upgrade 99 API Hamaca extraheavy crude. This paper summarizes the characteristics and economics of an integrated worldscale production-upgrading complex based on the HDH{trademark} technology as compared to a similar complex based on the well known delayed coking process. It concludes that whenever high liquid yields and/or feedstock cost drives the process economics, HDH{trademark} can compite advantageously with these more conventional technologies. At present, Maraven, S.A., another PDVSA affiliate, is developing the first HDH{trademark} commercial unit, to be built in its Cardon Refinery. It is anticipated that the 100 m{sup 3}/h unit will be in operation by 1998, allowing the demonstration of the process, as well as further optimizations of the scheme, thereby improving its economic competitiveness. 2 refs., 3 figs., 1 tab.

  19. Crude Oil Analysis Database

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Shay, Johanna Y.

    The composition and physical properties of crude oil vary widely from one reservoir to another within an oil field, as well as from one field or region to another. Although all oils consist of hydrocarbons and their derivatives, the proportions of various types of compounds differ greatly. This makes some oils more suitable than others for specific refining processes and uses. To take advantage of this diversity, one needs access to information in a large database of crude oil analyses. The Crude Oil Analysis Database (COADB) currently satisfies this need by offering 9,056 crude oil analyses. Of these, 8,500 are United States domestic oils. The database contains results of analysis of the general properties and chemical composition, as well as the field, formation, and geographic location of the crude oil sample. [Taken from the Introduction to COAMDATA_DESC.pdf, part of the zipped software and database file at http://www.netl.doe.gov/technologies/oil-gas/Software/database.html] Save the zipped file to your PC. When opened, it will contain PDF documents and a large Excel spreadsheet. It will also contain the database in Microsoft Access 2002.

  20. Oil Bypass Filter and Diesel Engine Idling Wear-Rate Evaluations |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Bypass Filter and Diesel Engine Idling Wear-Rate Evaluations Oil Bypass Filter and Diesel Engine Idling Wear-Rate Evaluations 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters 2005_deer_zirker.pdf (247.36 KB) More Documents & Publications Demonstrated Petroleum Reduction Using Oil Bypass Filter Technology on Heavy and Light Vehicles Development of Partial Filter Technology for HDD Retrofit Comparing Emissions Benefits from Regulating

  1. PURADYN Oil Bypass Filtration System Evaluation Test Plan

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technologies & Infrastructure Department PURADYN OIL BYPASS FILTRATION SYSTEM EVALUATION TEST PLAN October 2002 Reviewed: INEEL Fleet Maintenance Supervisor (Thomas) Date Reviewed: INEEL Bus & Heavy Equipment Foreman (Murdock) Date Reviewed: INEEL Fleet Maintenance Department Manager (Bullock) Date Approved: INEEL Central/Idaho Falls Facilities Director (Winn) Date Reviewed: INEEL Test Engineer (Zirker) Date Reviewed: INEEL Project Manager (Francfort) Date Approved: INEEL TT&I

  2. Shale oil dearsenation process

    SciTech Connect (OSTI)

    Brickman, F.E.; Degnan, T.F.; Weiss, C.S.

    1984-10-29

    This invention relates to processing shale oil and in particular to processing shale oil to reduce the arsenic content. Specifically, the invention relates to treating shale oil by a combination of processes - coking and water washing. Many shale oils produced by conventional retorting processes contain inorganic materials, such as arsenic, which interfere with subsequent refining or catalytic hydroprocessing operations. Examples of these hydroprocessing operations are hydrogenation, denitrogenation, and desulfurization. From an environmental standpoint, removal of such contaminants may be desirable even if the shale oil is to be used directly as a fuel. Hence, it is desirable that contaminants such as arsenic be removed, or reduced to low levels, prior to further processing of the shale oil or prior to its use as a fuel.

  3. Reactivation of an idle lease to increase heavy oil recovery through application of conventional steam drive technology in a low dip slope and basin reservoir in the Midway-Sunset field, San Jaoquin Basin, California. Annual report, June 13, 1995--June 13, 1996

    SciTech Connect (OSTI)

    Deo, M.; Jenkins, C.; Sprinkel, D.; Swain, R.; Wydrinski, R.; Schamel, S.

    1998-09-01

    This project reactivates ARCO`s idle Pru Fee lease in the Midway-Sunset field, California and conducts a continuous steamflood enhanced oil recovery demonstration aided by an integration of modern reservoir characterization and simulation methods. Cyclic steaming is being used to reestablish baseline production within the reservoir characterization phase of the project. During the demonstration phase scheduled to begin in January 1997, a continuous steamflood enhanced oil recovery will be initiated to test the incremental value of this method as an alternative to cyclic steaming. Other economically marginal Class III reservoirs having similar producibility problems will benefit from insight gained in this project. The objectives of the project are: (1) to return the shut-in portion of the reservoir to optimal commercial production; (2) to accurately describe the reservoir and recovery process; and (3) to convey the details of this activity to the domestic petroleum industry, especially to other producers in California, through an aggressive technology transfer program.

  4. Summary of heavy ion theory

    SciTech Connect (OSTI)

    Gavin, S.

    1994-09-01

    Can we study hot QCD using nuclear collisions? Can we learn about metallic hydrogen from the impact of comet Shoemaker-Levy 9 on Jupiter? The answer to both questions may surprise you! I summarize progress in relativistic heavy ion theory reported at DPF `94 in the parallel sessions.

  5. The Search for Heavy Elements

    ScienceCinema (OSTI)

    None

    2010-01-08

    The 1994 documentary "The Search for Heavy Elements" chronicles the expansion of the periodic table through the creation at Berkeley Lab of elements heavier than uranium. The documentary features a mix of rarely-seen archival footage, historical photos, and interviews with scientists who made history, such as Glenn Seaborg and Albert Ghiorso.

  6. Proton Distribution in Heavy Nuclei

    DOE R&D Accomplishments [OSTI]

    Johnson, M. H; Teller, E.

    1953-11-13

    It is reasoned that, from considerations connected with beta-decay stability and Coulomb repulsion forces, a neutron excess is developed on the surface of heavy nuclei. Several consequences of this qualitative analysis in nucleon interactions are briefly noted. (K.S.)

  7. The Search for Heavy Elements

    SciTech Connect (OSTI)

    2008-04-17

    The 1994 documentary "The Search for Heavy Elements" chronicles the expansion of the periodic table through the creation at Berkeley Lab of elements heavier than uranium. The documentary features a mix of rarely-seen archival footage, historical photos, and interviews with scientists who made history, such as Glenn Seaborg and Albert Ghiorso.

  8. Hot Oiling Spreadsheet

    Energy Science and Technology Software Center (OSTI)

    1993-10-22

    One of the most common oil-field treatments is hot oiling to remove paraffin from wells. Even though the practice is common, the thermal effectiveness of the process is not commonly understood. In order for producers to easily understand the thermodynamics of hot oiling, a simple tool is needed for estimating downhole temperatures. Such a tool has been developed that can be distributed as a compiled spreadsheet.

  9. Vegetable oil fuel

    SciTech Connect (OSTI)

    Bartholomew, D.

    1981-04-01

    In this article, the future role of renewable agricultural resources in providing fuel is discussed. it was only during this century that U.S. farmers began to use petroleum as a fuel for tractors as opposed to forage crop as fuel for work animals. Now farmers may again turn to crops as fuel for agricultural production - the possible use of sunflower oil, soybean oil and rapeseed oil as substitutes for diesel fuel is discussed.

  10. Residential heating oil price

    U.S. Energy Information Administration (EIA) Indexed Site

    heating oil price decreases The average retail price for home heating oil fell 7.6 cents from a week ago to $2.97 per gallon. That's down $1.05 from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $2.94 per gallon, down 6.7 cents from last week, and down $1.07

  11. Residential heating oil price

    U.S. Energy Information Administration (EIA) Indexed Site

    heating oil price decreases The average retail price for home heating oil fell 6.3 cents from a week ago to $2.91 per gallon. That's down $1.10 from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $2.88 per gallon, down 6.8 cents from last week, and down $1.13

  12. Residential heating oil price

    U.S. Energy Information Administration (EIA) Indexed Site

    heating oil price decreases The average retail price for home heating oil fell 7.5 cents from a week ago to $2.84 per gallon. That's down $1.22 from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $2.80 per gallon, down 7.4 cents from last week, and down $1.23

  13. Residential heating oil price

    U.S. Energy Information Administration (EIA) Indexed Site

    heating oil price decreases The average retail price for home heating oil fell 4.1 cents from a week ago to $2.89 per gallon, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $2.84 per gallon, down 5.4 cents from last week

  14. Residential heating oil price

    U.S. Energy Information Administration (EIA) Indexed Site

    heating oil price decreases The average retail price for home heating oil fell 3.6 cents from a week ago to $3.04 per gallon. That's down 99.4 cents from a year ago, based on the residential heating fuel survey by the U.S. Energy Information Administration. Heating oil prices in the New England region fell to $3.01 per gallon, down 3.6 cents from last week, and down $1.01

  15. Santa Fe Jets and Heavy Flavor Workshop

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Santa Fe Jets and Heavy Flavor Workshop Santa Fe Jets and Heavy Flavor Workshop WHEN: Jan 11, 2016 8:30 AM - Jan 13, 2016 5:30 PM WHERE: Inn and Spa at Loretto 211 Old Santa Fe...

  16. Lower oil prices also cutting winter heating oil and propane...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    see even lower natural gas and heating oil bills this winter than previously expected ... said the average household heating with oil will experience a 41% drop in heating oil ...

  17. Crude Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    Information AdministrationPetroleum Marketing Annual 2001 41 Table 21. Domestic Crude Oil First Purchase Prices (Dollars per Barrel) - Continued Year Month PAD District II...

  18. Crude Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    Information AdministrationPetroleum Marketing Annual 1998 41 Table 21. Domestic Crude Oil First Purchase Prices (Dollars per Barrel) - Continued Year Month PAD District II...

  19. Crude Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    Information AdministrationPetroleum Marketing Annual 1999 41 Table 21. Domestic Crude Oil First Purchase Prices (Dollars per Barrel) - Continued Year Month PAD District II...

  20. Horizontal oil well applications and oil recovery assessment. Volume 2: Applications overview, Final report

    SciTech Connect (OSTI)

    Deskins, W.G.; McDonald, W.J.; Knoll, R.G.; Springer, S.J.

    1995-03-01

    Horizontal technology has been applied in over 110 formations in the USA. Volume 1 of this study addresses the overall success of horizontal technology, especially in less-publicized formations, i.e., other than the Austin Chalk, Bakken, and Niobrara. Operators in the USA and Canada were surveyed on a formation-by-formation basis by means of a questionnaire. Response data were received describing horizontal well projects in 58 formations in the USA and 88 in Canada. Operators` responses were analyzed for trends in technical and economic success based on lithology (clastics and carbonates) and resource type (light oil, heavy oil, and gas). The potential impact of horizontal technology on reserves was also estimated. A forecast of horizontal drilling activity over the next decade was developed.

  1. Strangeness signals in heavy ion collisions

    SciTech Connect (OSTI)

    Remsberg, L.P.

    1992-11-01

    The experimental data on strange meson and strange baryon production in relativistic heavy ion collisions are reviewed.

  2. Strangeness signals in heavy ion collisions

    SciTech Connect (OSTI)

    Remsberg, L.P.

    1992-01-01

    The experimental data on strange meson and strange baryon production in relativistic heavy ion collisions are reviewed.

  3. Heavy Ion Inertial Fusion Energy: Summaries of Program Elements

    SciTech Connect (OSTI)

    Friedman, A; Barnard, J J; Kaganovich, I; Seidl, P A; Briggs, R J; Faltens, A; Kwan, J W; Lee, E P; Logan, B G

    2011-02-28

    The goal of the Heavy Ion Fusion (HIF) Program is to apply high-current accelerator technology to IFE power production. Ion beams of mass {approx}100 amu and kinetic energy {>=} 1 GeV provide efficient energy coupling into matter, and HIF enjoys R&D-supported favorable attributes of: (1) the driver, projected to be robust and efficient; see 'Heavy Ion Accelerator Drivers.'; (2) the targets, which span a continuum from full direct to full indirect drive (and perhaps fast ignition), and have metal exteriors that enable injection at {approx}10 Hz; see 'IFE Target Designs'; (3) the near-classical ion energy deposition in the targets; see 'Beam-Plasma Interactions'; (4) the magnetic final lens, robust against damage; see 'Final Optics-Heavy Ion Beams'; and (5) the fusion chamber, which may use neutronically-thick liquids; see 'Liquid-Wall Chambers.' Most studies of HIF power plants have assumed indirect drive and thick liquid wall protection, but other options are possible.

  4. Oil Shale and Oil Sands Development Robert Keiter; John Ruple...

    Office of Scientific and Technical Information (OSTI)

    Conjunctive Surface and Groundwater Management in Utah: Implications for Oil Shale and Oil Sands Development Robert Keiter; John Ruple; Heather Tanana; Rebecca Holt 29 ENERGY...

  5. Development of Extraction Techniques for the Detection of Signature Lipids from Oil

    SciTech Connect (OSTI)

    Borglin, Sharon; Geller, Jil; Chakraborty, Romy; Hazen, Terry; Mason, Olivia

    2010-05-17

    Pure cultures, including Desulfovibrio vulgaris and Methanococcus maripaludus, were combined with model oil samples and oil/diesel mixtures to optimize extraction techniques of signature lipids from oil in support of investigation of microbial communities in oil deposit samples targets for microbial enhanced hydrocarbon recovery. Several techniques were evaluated, including standard phospholipid extraction, ether linked lipid for Archaeal bacterial detection, and high pressure extractiontechniques. Recovery of lipids ranged from 50-80percent as compared to extraction of the pure culture. Extraction efficiency was evaluated by the use of internal standards. Field samples will also be tested for recovery of signature lipids with optimized extraction techniques.

  6. STEO September 2012 - oil production

    U.S. Energy Information Administration (EIA) Indexed Site

    EIA analyst Sam Gorgen explains: "Higher oil supplies, especially from North Dakota and Texas, boosted U.S. oil production. The number of on-shore drilling rigs targeting oil ...

  7. Opportunities to improve oil productivity in unstructured deltaic reservoirs

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    This report contains presentations presented at a technical symposium on oil production. Chapter 1 contains summaries of the presentations given at the Department of Energy (DOE)-sponsored symposium and key points of the discussions that followed. Chapter 2 characterizes the light oil resource from fluvial-dominated deltaic reservoirs in the Tertiary Oil Recovery Information System (TORIS). An analysis of enhanced oil recovery (EOR) and advanced secondary recovery (ASR) potential for fluvial-dominated deltaic reservoirs based on recovery performance and economic modeling as well as the potential resource loss due to well abandonments is presented. Chapter 3 provides a summary of the general reservoir characteristics and properties within deltaic deposits. It is not exhaustive treatise, rather it is intended to provide some basic information about geologic, reservoir, and production characteristics of deltaic reservoirs, and the resulting recovery problems.

  8. Oil shale technology

    SciTech Connect (OSTI)

    Lee, S. (Akron Univ., OH (United States). Dept. of Chemical Engineering)

    1991-01-01

    Oil shale is undoubtedly an excellent energy source that has great abundance and world-wide distribution. Oil shale industries have seen ups and downs over more than 100 years, depending on the availability and price of conventional petroleum crudes. Market forces as well as environmental factors will greatly affect the interest in development of oil shale. Besides competing with conventional crude oil and natural gas, shale oil will have to compete favorably with coal-derived fuels for similar markets. Crude shale oil is obtained from oil shale by a relatively simple process called retorting. However, the process economics are greatly affected by the thermal efficiencies, the richness of shale, the mass transfer effectiveness, the conversion efficiency, the design of retort, the environmental post-treatment, etc. A great many process ideas and patents related to the oil shale pyrolysis have been developed; however, relatively few field and engineering data have been published. Due to the vast heterogeneity of oil shale and to the complexities of physicochemical process mechanisms, scientific or technological generalization of oil shale retorting is difficult to achieve. Dwindling supplied of worldwide petroleum reserves, as well as the unprecedented appetite of mankind for clean liquid fuel, has made the public concern for future energy market grow rapidly. the clean coal technology and the alternate fuel technology are currently of great significance not only to policy makers, but also to process and chemical researchers. In this book, efforts have been made to make a comprehensive text for the science and technology of oil shale utilization. Therefore, subjects dealing with the terminological definitions, geology and petrology, chemistry, characterization, process engineering, mathematical modeling, chemical reaction engineering, experimental methods, and statistical experimental design, etc. are covered in detail.

  9. Low-rank coal oil agglomeration product and process

    DOE Patents [OSTI]

    Knudson, Curtis L.; Timpe, Ronald C.; Potas, Todd A.; DeWall, Raymond A.; Musich, Mark A.

    1992-01-01

    A selectively-sized, raw, low-rank coal is processed to produce a low ash and relative water-free agglomerate with an enhanced heating value and a hardness sufficient to produce a non-decrepitating, shippable fuel. The low-rank coal is treated, under high shear conditions, in the first stage to cause ash reduction and subsequent surface modification which is necessary to facilitate agglomerate formation. In the second stage the treated low-rank coal is contacted with bridging and binding oils under low shear conditions to produce agglomerates of selected size. The bridging and binding oils may be coal or petroleum derived. The process incorporates a thermal deoiling step whereby the bridging oil may be completely or partially recovered from the agglomerate; whereas, partial recovery of the bridging oil functions to leave as an agglomerate binder, the heavy constituents of the bridging oil. The recovered oil is suitable for recycling to the agglomeration step or can serve as a value-added product.

  10. Low-rank coal oil agglomeration product and process

    DOE Patents [OSTI]

    Knudson, C.L.; Timpe, R.C.; Potas, T.A.; DeWall, R.A.; Musich, M.A.

    1992-11-10

    A selectively-sized, raw, low-rank coal is processed to produce a low ash and relative water-free agglomerate with an enhanced heating value and a hardness sufficient to produce a non-degradable, shippable fuel. The low-rank coal is treated, under high shear conditions, in the first stage to cause ash reduction and subsequent surface modification which is necessary to facilitate agglomerate formation. In the second stage the treated low-rank coal is contacted with bridging and binding oils under low shear conditions to produce agglomerates of selected size. The bridging and binding oils may be coal or petroleum derived. The process incorporates a thermal deoiling step whereby the bridging oil may be completely or partially recovered from the agglomerate; whereas, partial recovery of the bridging oil functions to leave as an agglomerate binder, the heavy constituents of the bridging oil. The recovered oil is suitable for recycling to the agglomeration step or can serve as a value-added product.

  11. Vegetable oil as fuel

    SciTech Connect (OSTI)

    Not Available

    1980-11-01

    A review is presented of various experiments undertaken over the past few years in the U.S. to test the performance of vegetable oils in diesel engines, mainly with a view to on-farm energy self-sufficiency. The USDA Northern Regional Research Center in Peoria, Illinois, is screening native U.S. plant species as potential fuel oil sources.

  12. Heavy flavor production from photons and hadrons

    SciTech Connect (OSTI)

    Heusch, C.A.

    1982-01-01

    The present state of the production and observation of hadrons containing heavy quarks or antiquarks as valence constituents, in reactions initiated by real and (space-like) virtual photon or by hadron beams is discussed. Heavy flavor production in e/sup +/e/sup -/ annihilation, which is well covered in a number of recent review papers is not discussed, and similarly, neutrino production is omitted due to the different (flavor-changing) mechanisms that are involved in those reactions. Heavy flavors from spacelike photons, heavy flavors from real photons, and heavy flavors from hadron-hadron collisions are discussed. (WHK)

  13. Heavy Vehicle Propulsion Materials Program

    SciTech Connect (OSTI)

    Diamond, S.; Johnson, D.R.

    1999-04-26

    The objective of the Heavy Vehicle Propulsion Materials Program is to develop the enabling materials technology for the clean, high-efficiency diesel truck engines of the future. The development of cleaner, higher-efficiency diesel engines imposes greater mechanical, thermal, and tribological demands on materials of construction. Often the enabling technology for a new engine component is the material from which the part can be made. The Heavy Vehicle Propulsion Materials Program is a partnership between the Department of Energy (DOE), and the diesel engine companies in the United States, materials suppliers, national laboratories, and universities. A comprehensive research and development program has been developed to meet the enabling materials requirements for the diesel engines of the future. Advanced materials, including high-temperature metal alloys, intermetallics, cermets, ceramics, amorphous materials, metal- and ceramic-matrix composites, and coatings, are investigated for critical engine applications.

  14. Heavy quark production at CDF

    SciTech Connect (OSTI)

    C. Paus

    2002-11-13

    The contribution summarizes the latest results from CDF on heavy quark production. Results from top, bottom and charm production are included. Some new analysis using Run I (1991-1994) data have become available. More importantly there are a number of results using Run II data which began in April 2001. The data indicate the potential of CDF for bottom and charm production physics in the near future.

  15. Corrosivity Of Pyrolysis Oils

    SciTech Connect (OSTI)

    Keiser, James R; Bestor, Michael A; Lewis Sr, Samuel Arthur; Storey, John Morse

    2011-01-01

    Pyrolysis oils from several sources have been analyzed and used in corrosion studies which have consisted of exposing corrosion coupons and stress corrosion cracking U-bend samples. The chemical analyses have identified the carboxylic acid compounds as well as the other organic components which are primarily aromatic hydrocarbons. The corrosion studies have shown that raw pyrolysis oil is very corrosive to carbon steel and other alloys with relatively low chromium content. Stress corrosion cracking samples of carbon steel and several low alloy steels developed through-wall cracks after a few hundred hours of exposure at 50 C. Thermochemical processing of biomass can produce solid, liquid and/or gaseous products depending on the temperature and exposure time used for processing. The liquid product, known as pyrolysis oil or bio-oil, as produced contains a significant amount of oxygen, primarily as components of water, carboxylic acids, phenols, ketones and aldehydes. As a result of these constituents, these oils are generally quite acidic with a Total Acid Number (TAN) that can be around 100. Because of this acidity, bio-oil is reported to be corrosive to many common structural materials. Despite this corrosive nature, these oils have the potential to replace some imported petroleum. If the more acidic components can be removed from this bio-oil, it is expected that the oil could be blended with crude oil and then processed in existing petroleum refineries. The refinery products could be transported using customary routes - pipelines, barges, tanker trucks and rail cars - without a need for modification of existing hardware or construction of new infrastructure components - a feature not shared by ethanol.

  16. Technology experience and economics of oil shale mining in Estonia

    SciTech Connect (OSTI)

    Fraiman, J.; Kuzmiv, I. [Estonian Oil Shale State Co., Jyhvi (Estonia). Scientific Research Center

    1995-11-01

    The exhaustion of fuel-energy resources became an evident problem of the European continent in the 1960s. Careful utilization of their own reserves of coal, oil, and gas (Germany, France, Spain) and assigned shares of imports of these resources make up the strategy of economic development of the European countries. The expansion of oil shale utilization is the most topical problem. The experience of mining oil shale deposits in Estonia and Russia, in terms of the practice and the economic results, is reviewed in this article. The room-and-pillar method of underground mining and the open-cut technology of clearing the ground ensure the fertility of a soil. The economics of underground and open pit oil shale mines is analyzed in terms of natural, organizational, and technical factors. These analyses are used in the planning and management of oil shale mining enterprises. The perspectives of the oil shale mining industry of Estonia and the economic expediency of multiproduction are examined. Recommendations and guidelines for future industrial utilization of oil shale are given in the summary.

  17. Balanced-activity improved inverse emulsion to inhibit brittle lutite hydration in oil fields

    SciTech Connect (OSTI)

    Olmedo, E. P.; de J. Hernandez Alvarez, R.; Barrera, C. D.; Ramos, J. D. G.

    1984-10-02

    An improved inverse emulsion for use as a drilling fluid that inhibits brittle lutite hydration. The emulsion includes a heavy oil; brine; a viscosity agent with thermostabilizing properties; an emulsifying agent; a thickening agent; a gelatinizing additive; and an alkaline earth metal hydroxide. The emulsion avoids hole collapsing and improves well gage stability.

  18. ROSE{reg_sign} - A flexible process for upgrading heavy crude, atmospheric residue, or vaccum residue

    SciTech Connect (OSTI)

    Lynch, K.Z.; Hood, H.L.; Gomez, O.

    1995-12-31

    The ROSE{reg_sign} Pilot Plant was used to evaluate various fractions of Boscan and Zuata heavy crude oils. The results demonstrated the ability of the ROSE process to remove asphaltene fractions using n-pentane, n-butane, or propane as the solvent while leaving behind an oil that has been greatly reduced in its metal, nitrogen, sulfur, and Conradson carbon contents. The recovered oil could then be used as feedstock to a conventional hydrotreater/FCC process combination. The flexibility of the process is evidenced by its ability to process various feeds. Because of this flexibility, the opportunity exists to use the ROSE process at a wellhead location to reduce the diluent requirements for making a suitable pipeline feed. This technology is also able to process changing feeds when upstream units in a refinery are down during major turnarounds, for example, or when there are problems with a vacuum tower or downstream unit.

  19. MODELING OF THERMOPHORETIC SOOT DEPOSITION ANDHYDROCARBON CONDENSATION IN EGR COOLERS

    SciTech Connect (OSTI)

    Abarham, Mehdi; Hoard, John W.; Assanis, Dennis; Styles, Dan; Curtis, Eric W.; Ramesh, Nitia; Sluder, Scott; Storey, John Morse

    2009-01-01

    EGR coolers are effective to reduce NOx emissions from diesel engines due to lower intake charge temperature. EGR cooler fouling reduces heat transfer capacity of the cooler significantly and increases pressure drop across the cooler. Engine coolant provided at 40-90 C is used to cool EGR coolers. The presence of a cold surface in the cooler causes particulate soot deposition and hydrocarbon condensation. The experimental data also indicates that the fouling is mainly caused by soot and hydrocarbons. In this study, a 1-D model is extended to simulate particulate soot and hydrocarbon deposition on a concentric tube EGR cooler with a constant wall temperature. The soot deposition caused by thermophoresis phenomena is taken into account the model. Condensation of a wide range of hydrocarbon molecules are also modeled but the results show condensation of only heavy molecules at coolant temperature. Thermal properties of fouled layer are calculated based on mass fraction of deposited soot and hydrocarbons. The experiments with the same conditions ran to validate the model. Hot EGR gases flow through the inner pipe and the coolant circulates around it in the outer pipe to keep a constant wall temperature. Effectiveness, deposited soot mass, condensed hydrocarbon mass, and pressure drop across the cooler are the parameters that have been compared. The results of the model are in a reasonably good agreement with the experimental results although there are some fields that need to be studied in future to improve the model.

  20. Computer simulation of the probability that endangered whales will interact with oil spills

    SciTech Connect (OSTI)

    Reed, M.; Jayko, K.; Bowles, A.; Anderson, E.; Leatherwood, S.

    1987-03-01

    A numerical model system was developed to assess quantitatively the probability that endangered bowhead and gray whales will encounter spilled oil in Alaskan waters. Bowhead and gray whale migration and diving-surfacing models, and an oil-spill trajectory model comprise the system. The migration models were developed from conceptual considerations, then calibrated with and tested against observations. The movement of a whale point is governed by a random walk algorithm which stochastically follows a migratory pathway. The oil-spill model, developed under a series of other contracts, accounts for transport and spreading behavior in open water and in the presence of sea ice. Historical wind records and heavy, normal, or light ice cover data sets are selected at random to provide stochastic oil-spill scenarios for whale-oil interaction simulations.

  1. Multi-chamber deposition system

    DOE Patents [OSTI]

    Jacobson, Richard L.; Jeffrey, Frank R.; Westerberg, Roger K.

    1989-06-27

    A system for the simultaneous deposition of different coatings onto a thin web within a large volume vacuum chamber is disclosed which chamber is provided with a plurality of deposition chambers in which the different layers are deposited onto the film as its moves from a supply roll to a finished take-up roll of coated web. The deposition chambers provided within the large vacuum chamber are provided with separate seals which minimize back diffusion of any dopant gas from adjacent deposition chambers.

  2. Multi-chamber deposition system

    DOE Patents [OSTI]

    Jacobson, Richard L.; Jeffrey, Frank R.; Westerberg, Roger K.

    1989-10-17

    A system for the simultaneous deposition of different coatings onto a thin web within a large volume vacuum chamber is disclosed which chamber is provided with a plurality of deposition chambers in which the different layers are deposited onto the film as its moves from a supply roll to a finished take-up roll of coated web. The deposition chambers provided within the large vacuum chamber are provided with separate seals which minimize back diffusion of any dopant gas from adjacent deposition chambers.

  3. Hydrocarbon Liquid Production via Catalytic Hydroprocessing of Phenolic Oils Fractionated from Fast Pyrolysis of Red Oak and Corn Stover

    SciTech Connect (OSTI)

    Elliott, Douglas C.; Wang, Huamin; Rover, Majorie; Whitmer, Lysle; Smith, Ryan; Brown, Robert C.

    2015-04-13

    Phenolic oils were produced from fast pyrolysis of two different biomass feedstocks, red oak and corn stover and evaluated in hydroprocessing tests for production of liquid hydrocarbon products. The phenolic oils were produced with a bio-oil fractionating process in combination with a simple water wash of the heavy ends from the fractionating process. Phenolic oils derived from the pyrolysis of red oak and corn stover were recovered with yields (wet biomass basis) of 28.7 wt% and 14.9 wt%, respectively, and 54.3% and 58.6% on a carbon basis. Both precious metal catalysts and sulfided base metal catalyst were evaluated for hydrotreating the phenolic oils, as an extrapolation from whole bio-oil hydrotreatment. They were effective in removing heteroatoms with carbon yields as high as 81% (unadjusted for the 90% carbon balance). There was nearly complete heteroatom removal with residual O of only 0.4% to 5%, while N and S were reduced to less than 0.05%. Use of the precious metal catalysts resulted in more saturated products less completely hydrotreated compared to the sulfided base metal catalyst, which was operated at higher temperature. The liquid product was 42-52% gasoline range molecules and about 43% diesel range molecules. Particulate matter in the phenolic oils complicated operation of the reactors, causing plugging in the fixed-beds especially for the corn stover phenolic oil. This difficulty contrasts with the catalyst bed fouling and plugging, which is typically seen with hydrotreatment of whole bio-oil. This problem was substantially alleviated by filtering the phenolic oils before hydrotreating. More thorough washing of the phenolic oils during their preparation from the heavy ends of bio-oil or on-line filtration of pyrolysis vapors to remove particulate matter before condensation of the bio-oil fractions is recommended.

  4. Hydrocarbon Liquid Production via Catalytic Hydroprocessing of Phenolic Oils Fractionated from Fast Pyrolysis of Red Oak and Corn Stover

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Elliott, Douglas C.; Wang, Huamin; Rover, Majorie; Whitmer, Lysle; Smith, Ryan; Brown, Robert C.

    2015-04-13

    Phenolic oils were produced from fast pyrolysis of two different biomass feedstocks, red oak and corn stover and evaluated in hydroprocessing tests for production of liquid hydrocarbon products. The phenolic oils were produced with a bio-oil fractionating process in combination with a simple water wash of the heavy ends from the fractionating process. Phenolic oils derived from the pyrolysis of red oak and corn stover were recovered with yields (wet biomass basis) of 28.7 wt% and 14.9 wt%, respectively, and 54.3% and 58.6% on a carbon basis. Both precious metal catalysts and sulfided base metal catalyst were evaluated for hydrotreatingmore » the phenolic oils, as an extrapolation from whole bio-oil hydrotreatment. They were effective in removing heteroatoms with carbon yields as high as 81% (unadjusted for the 90% carbon balance). There was nearly complete heteroatom removal with residual O of only 0.4% to 5%, while N and S were reduced to less than 0.05%. Use of the precious metal catalysts resulted in more saturated products less completely hydrotreated compared to the sulfided base metal catalyst, which was operated at higher temperature. The liquid product was 42-52% gasoline range molecules and about 43% diesel range molecules. Particulate matter in the phenolic oils complicated operation of the reactors, causing plugging in the fixed-beds especially for the corn stover phenolic oil. This difficulty contrasts with the catalyst bed fouling and plugging, which is typically seen with hydrotreatment of whole bio-oil. This problem was substantially alleviated by filtering the phenolic oils before hydrotreating. More thorough washing of the phenolic oils during their preparation from the heavy ends of bio-oil or on-line filtration of pyrolysis vapors to remove particulate matter before condensation of the bio-oil fractions is recommended.« less

  5. CO2 Huff-n-Puff Process in a Light Oil Shallow Shelf Carbonate Reservoir

    SciTech Connect (OSTI)

    Kovar, Mark; Wehner, Scott

    1998-01-13

    The application of cyclic CO2, often referred to as the CO2 Huff-n-Puff process, may find its niche in the maturing waterfloods of the Permian Basin. Coupling the CO2 Huff-n-Puff process to miscible flooding applications could provide the needed revenue to sufficiently mitigate near-term negative cash flow concerns in the capital-intensive miscible projects. Texaco Exploration & Production Inc. and the U. S. Department of Energy have teamed up in an attempt to develop the CO2 Huff-n-Puff process in the Grayburg and San Andres formations which are light oil, shallow shelf carbonate reservoirs that exist throughout the Permian Basin. This cost-shared effort is intended to demonstrate the viability of this underutilized technology in a specific class of domestic reservoir. A significant amount of oil reserves are located in carbonate reservoirs. Specifically, the carbonates deposited in shallow shelf (SSC) environments make up the largest percentage of known reservoirs within the Permian Basin of North America. Many of these known resources have been under waterflooding operations for decades and are at risk of abandonment if crude oil recoveries cannot be economically enhanced. The selected sites for this demonstration project are the Central Vacuum Unit waterflood in Lea County, New Mexico and the Sundown Slaughter Field in Hockley County, Texas. Miscible CO2 flooding is the process of choice for enhancing recovery of light oils and already accounts for over 12% of the Permian Basin's daily production. There are significant probable reserves associated with future miscible CO2 projects. However, many are marginally economic at current market conditions due to large up-front capital commitments for a peak response, which may be several years in the future. The resulting negative cash-flow is sometimes too much for an operator to absorb. The CO2 Huff-n-Puff process is being investigated as a near

  6. Characterization of oil and gas reservoir heterogeneity

    SciTech Connect (OSTI)

    Tyler, N.; Barton, M.D.; Bebout, D.G.; Fisher, R.S.; Grigsby, J.D.; Guevara, E.; Holtz, M.; Kerans, C.; Nance, H.S.; Levey, R.A.

    1992-10-01

    Research described In this report addresses the internal architecture of two specific reservoir types: restricted-platform carbonates and fluvial-deltaic sandstones. Together, these two reservoir types contain more than two-thirds of the unrecovered mobile oil remaining ill Texas. The approach followed in this study was to develop a strong understanding of the styles of heterogeneity of these reservoir types based on a detailed outcrop description and a translation of these findings into optimized recovery strategies in select subsurface analogs. Research targeted Grayburg Formation restricted-platform carbonate outcrops along the Algerita Escarpment and In Stone Canyon In southeastern New Mexico and Ferron deltaic sandstones in central Utah as analogs for the North Foster (Grayburg) and Lake Creek (Wilcox) units, respectively. In both settings, sequence-stratigraphic style profoundly influenced between-well architectural fabric and permeability structure. It is concluded that reservoirs of different depositional origins can therefore be categorized Into a heterogeneity matrix'' based on varying intensity of vertical and lateral heterogeneity. The utility of the matrix is that it allows prediction of the nature and location of remaining mobile oil. Highly stratified reservoirs such as the Grayburg, for example, will contain a large proportion of vertically bypassed oil; thus, an appropriate recovery strategy will be waterflood optimization and profile modification. Laterally heterogeneous reservoirs such as deltaic distributary systems would benefit from targeted infill drilling (possibly with horizontal wells) and improved areal sweep efficiency. Potential for advanced recovery of remaining mobile oil through heterogeneity-based advanced secondary recovery strategies In Texas is projected to be an Incremental 16 Bbbl. In the Lower 48 States this target may be as much as 45 Bbbl at low to moderate oil prices over the near- to mid-term.

  7. Deposition System Controller

    Energy Science and Technology Software Center (OSTI)

    2005-10-01

    This software is a complete thin film deposition controller. The software takes as its input a script file that dictates enablinig/disabling of sputtering power supplies, pause times, velocities and distances to move a substrate. An emulator has been created and built into the software package that can debug in advance any deposition script and decide if there is an overrun condition, accidental infinite look, and can estimate a time for completion. All necessary process variablesmore » are data logged and recorded for later inspection. This emulator currently interfaces to a Parker-Compumotor SX6 stepper moror indexer, but the software is written in such a way that it is easily modifiable for interface to othe brand and models of motor drivers. Other process I/O variables may be easily added. The software uses any multifunction DAQ card from National Instruments via their free NIDAQ API package, but again, the software is written such that othe brand DAQ cards may be used.« less

  8. Oil & Natural Gas Technology

    Office of Scientific and Technical Information (OSTI)

    IN SITU THERMAL PROCESSING OF OIL SHALESANDS Authors: Michal Hradisky and Philip J. Smith DOE Award No.: DE-FE0001243 Reporting Period: October 1, 2009 - September 30, 2011 ...

  9. oil1987.xls

    Gasoline and Diesel Fuel Update (EIA)

    ... Average Fuel OilKerosene Consumption Expenditures Below Poverty Line 100 Percent 2.0 1.4 ... for 1987. (3) Below 150 percent of poverty line or 60 percent of median State ...

  10. Crude Oil Prices

    U.S. Energy Information Administration (EIA) Indexed Site

    20.86 20.67 20.47 20.24 20.32 19.57 See footnotes at end of table. 21. Domestic Crude Oil First Purchase Prices Energy Information Administration Petroleum Marketing Annual...

  11. Oil Market Assessment

    Reports and Publications (EIA)

    2001-01-01

    Based on Energy Information Administration (EIA) contacts and trade press reports, overall U.S. and global oil supplies appear to have been minimally impacted by yesterday's terrorist attacks on the World Trade Center and the Pentagon.

  12. Hydroprocessing hydrocarbon oils

    SciTech Connect (OSTI)

    Simpson, H.D.; Borgens, P.B.

    1990-07-10

    This patent describes a catalytic hydroprocess of a hydrocarbon oil containing nitrogen or sulfur. It comprises: contacting a catalytic composition with the hydrocarbon oil under hydroprocessing conditions so as to produce a product hydrocarbon oil containing less nitrogen or sulfur than the hydrocarbon oil, the catalytic composition prepared by the method comprising the steps of impregnating porous refractory support particles with an aqueous impregnating solution comprising one or more Group VIB metal components, one or more phosphorus components and citric acid, the citric acid in a mole ratio to the Group VIB metal components calculated as the Group VIB metal trioxide of less than 1 to 1. The solution has a pH less than 1.0 and calcining the impregnated support particles to produce a catalytic composition containing a Group VIB metal component and a phosphorous component on the porous refractory oxide support.

  13. APEX heavy-ion counters

    SciTech Connect (OSTI)

    Mercer, D.J.

    1993-10-01

    A large solid-angle array of low-pressure multi-wire proportional counters (LPMWPC) forms part of the APEX apparatus. Eight three-element trapezoidal counters provide 360{degrees} coverage in {phi} and 20{degrees} - 70{degrees} coverage in {phi}. Angle information is obtained from a transmission-line delay cathode ({phi}) and from the segmentation ({phi}). Time-of-flight information is obtained from the anode signals. These quantities are used to extract the center-of-mass scattering angle, reaction Q value, and masses of the scattered heavy ions. Design and performance of the counters will be discussed.

  14. Heavy Gas Dispersion Incompressible Flow

    Energy Science and Technology Software Center (OSTI)

    1992-01-27

    FEM3 is a numerical model developed primarily to simulate heavy gas dispersion in the atmosphere, such as the gravitational spread and vapor dispersion that result from an accidental spill of liquefied natural gas (LNG). FEM3 solves both two and three-dimensional problems and, in addition to the generalized anelastic formulation, includes options to use either the Boussinesq approximation or an isothermal assumption, when appropriate. The FEM3 model is composed of three parts: a preprocessor PREFEM3, themore » main code FEM3, and two postprocessors TESSERA and THPLOTX.« less

  15. Oil shale research in China

    SciTech Connect (OSTI)

    Jianqiu, W.; Jialin, Q. (Beijing Graduate School, Petroleum Univ., Beijing (CN))

    1989-01-01

    There have been continued efforts and new emergence in oil shale research in Chine since 1980. In this paper, the studies carried out in universities, academic, research and industrial laboratories in recent years are summarized. The research areas cover the chemical structure of kerogen; thermal behavior of oil shale; drying, pyrolysis and combustion of oil shale; shale oil upgrading; chemical utilization of oil shale; retorting waste water treatment and economic assessment.

  16. Pilot-plant automation for catalytic hydrotreating of heavy residua

    SciTech Connect (OSTI)

    Akimoto, O.; Iwamoto, Y.; Kodama, S.; Takeuchi, C.

    1983-08-01

    The research and development center of Chiyoda Chemical Engineering and Construction Co. has been investigating the catalytic hydrotreating of heavy residua via pilot plant technology. Chiyoda's 52 microreactors. bench-scale test units and pilot plants are each used depending on the purpose of the process development for heavy oil upgrading. The microreactors are effective for catalyst screening. Heavier fractions such as asphaltene and sludge materials often disturbed steady state operation. Many unique devices for the test units and improvement of operation procedures make extended operation easy as well as increasing reliability. The computerized data acquisition and data filing systems minimize the work not only for operators but for all research personnel. Currently, about 40 pilot plant units are continuously running while the others are in preparation. Fully automated operation requires only three for data checking at night. In the daytime, seven operators take care of feed supply, product removal and condition changes. For start-up and shut-down, one operator can handle three microreactos, but only one bench-scale unit or pilot plant. Planning is underway for an improved start-up system for the pilot plants using personal computers. This system automatically sets feed rate and raises reactor temperature. (JMT)

  17. NETL: Oil & Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Oil & Gas Efficient recovery of our nation's fossil fuel resources in an environmentally safe manner requires the development and application of new technologies that address the unique nature and challenging locations of many of our remaining oil and natural gas accumulations. The National Energy Technology Laboratory's (NETL) research projects are designed to help catalyze the development of these new technologies, provide objective data to help quantify the environmental and safety risks

  18. Crude Oil Domestic Production

    U.S. Energy Information Administration (EIA) Indexed Site

    Data Series: Crude Oil Domestic Production Refinery Crude Oil Inputs Refinery Gross Inputs Refinery Operable Capacity (Calendar Day) Refinery Percent Operable Utilization Net Inputs of Motor Gasoline Blending Components Net Inputs of RBOB Blending Components Net Inputs of CBOB Blending Components Net Inputs of GTAB Blending Components Net Inputs of All Other Blending Components Net Inputs of Fuel Ethanol Net Production - Finished Motor Gasoline Net Production - Finished Motor Gasoline (Excl.

  19. A review of the global emissions, transport and effects of heavy metals in the environment

    SciTech Connect (OSTI)

    Friedman, J.R.; Ashton, W.B.; Rapoport, R.D.

    1993-06-01

    The purpose of this report is to describe the current state of knowledge regarding the sources and quantities of heavy metal emissions, their transport and fate, their potential health and environmental effects, and strategies to control them. The approach is to review the literature on this topic and to consult with experts in the field. Ongoing research activities and research needs are discussed. Estimates of global anthropogenic and natural emissions indicate that anthropogenic emissions are responsible for most of the heavy metals released into the atmosphere and that industrial activities have had a significant impact on the global cycling of trace metals. The largest anthropogenic sources of trace metals are coal combustion and the nonferrous metal industry. Atmospheric deposition is an important pathway by which trace metals enter the environment. Atmospheric deposition varies according to the solubility of the element and the length of time it resides in the atmosphere. Evidence suggests that deposition is influenced by other chemicals in the atmosphere, such as ozone and sulfur dioxide. Trace metals also enter the environment through leaching. Existing emissions-control technologies such as electrostatic precipitators, baghouses, and scrubbers are designed to remove other particulates from the flue gas of coal-fired power plants and are only partially effective at removing heavy metals. Emerging technologies such as flue gas desulfurization, lignite coke, and fluidized bed combustion could further reduce emissions. 108 refs.

  20. DOE/BNL Liquid Natural Gas Heavy Vehicle Program

    SciTech Connect (OSTI)

    James E. Wegrzyn; Wai-Lin Litzke; Michael Gurevich

    1998-08-11

    As a means of lowering greenhouse gas emissions, increasing economic growth, and reducing the dependency on imported oil, the Department of Energy and Brookhaven National Laboratory (DOE/ BNL) is promoting the substitution of liquefied natural gas (LNG) in heavy-vehicles that are currently being fueled by diesel. Heavy vehicles are defined as Class 7 and 8 trucks (> 118,000 pounds GVVV), and transit buses that have a fuel usage greater than 10,000 gallons per year and driving range of more than 300 miles. The key in making LNG market-competitive with all types of diesel fuels is in improving energy efficiency and reducing costs of LNG technologies through systems integration. This paper integrates together the three LNG technologies of: (1) production from landfills and remote well sites; (2) cryogenic fuel delivery systems; and (3) state-of-the-art storage tank and refueling facilities, with market end-use strategies. The program's goal is to develop these technologies and strategies under a ''green'' and ''clean'' strategy. This ''green'' approach reduces the net contribution of global warming gases by reducing levels of methane and carbon dioxide released by heavy vehicles usage to below recoverable amounts of natural gas from landfills and other natural resources. Clean technology refers to efficient use of energy with low environmental emissions. The objective of the program is to promote fuel competition by having LNG priced between $0.40 - $0.50 per gallon with a combined production, fuel delivery and engine systems efficiency approaching 45%. This can make LNG a viable alternative to diesel.

  1. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Towards Heavy Fermions in Europium Intermetallic Compounds Towards Heavy Fermions in Europium Intermetallic Compounds Print Wednesday, 29 July 2009 00:00 For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in

  2. Development of a gas-promoted oil agglomeration process: Air-promoted oil agglomeration of moderately hydrophobic coals. 2: Effect of air dosage in a model mixing system

    SciTech Connect (OSTI)

    Drzymala, J.; Wheelock, T.D.

    1996-07-01

    In a selective oil agglomeration process for cleaning coal, fine-size particles are suspended in water and treated with a water-immiscible hydrocarbon which can range from pentane to heavy fuel oil. Vigorous agitation is applied to disperse the oil and to produce frequent contacts between oil-coated particles. In Part 1 of this series of papers, it was shown that a definite amount of air had to be present in a laboratory mixing unit which produced a moderate shear rate in order to form compact, spherical agglomerates in an aqueous suspension of moderately hydrophobic coal using heptane or hexadecane as an agglomerate. In this paper, the effects of different amounts of air including dissolved air are discussed. The results indicate that a small amount of air will trigger the process of agglomeration, and even the air dissolved in water under equilibrium conditions at room temperature and pressure is sufficient to promote agglomeration provided it is released from solution.

  3. Process for preparing lubricating oil from used waste lubricating oil

    DOE Patents [OSTI]

    Whisman, Marvin L.; Reynolds, James W.; Goetzinger, John W.; Cotton, Faye O.

    1978-01-01

    A re-refining process is described by which high-quality finished lubricating oils are prepared from used waste lubricating and crankcase oils. The used oils are stripped of water and low-boiling contaminants by vacuum distillation and then dissolved in a solvent of 1-butanol, 2-propanol and methylethyl ketone, which precipitates a sludge containing most of the solid and liquid contaminants, unspent additives, and oxidation products present in the used oil. After separating the purified oil-solvent mixture from the sludge and recovering the solvent for recycling, the purified oil is preferably fractional vacuum-distilled, forming lubricating oil distillate fractions which are then decolorized and deodorized to prepare blending stocks. The blending stocks are blended to obtain a lubricating oil base of appropriate viscosity before being mixed with an appropriate additive package to form the finished lubricating oil product.

  4. Oil/gas collector/separator for underwater oil leaks

    DOE Patents [OSTI]

    Henning, Carl D.

    1993-01-01

    An oil/gas collector/separator for recovery of oil leaking, for example, from an offshore or underwater oil well. The separator is floated over the point of the leak and tethered in place so as to receive oil/gas floating, or forced under pressure, toward the water surface from either a broken or leaking oil well casing, line, or sunken ship. The separator is provided with a downwardly extending skirt to contain the oil/gas which floats or is forced upward into a dome wherein the gas is separated from the oil/water, with the gas being flared (burned) at the top of the dome, and the oil is separated from water and pumped to a point of use. Since the density of oil is less than that of water it can be easily separated from any water entering the dome.

  5. Canadian incentives for oil and gas exploration. [Applicability to USA

    SciTech Connect (OSTI)

    Not Available

    1980-04-01

    During the 1970s a number of different exploration and production incentive programs were put in place in Canada, in particular in the Province of Alberta, Canada's principal oil- and gas-producing province. The DOE/RA is evaluating Canadian incentives for oil and gas exploration, and this study is intended to provide information that will help guide DOE/RA in determining the applicability of Canadian incentive programs in US energy policy. The study describes and documents the fiscal structure in which the Canadian oil industry operates. The incentive features of pricing policy, taxation policy, and provincial royalty systems are discussed. A principal focus of the study is on one of the most important of Canada's specific incentive programs, the Alberta Exploratory Drilling Incentive Credit Program (EDICP). The study describes and evaluates the effect of the EDICP on increased oil and gas exploration activity. Similarly, the study also reviews and evaluates other specific incentive programs such as the Alberta Geophysical Incentive Program, Frontier Exploration Allowances, and various tar sand and heavy oil development incentives. Finally the study evaluates the applicability of Canadian incentives to US energy policy.

  6. Heavy Mobile Equipment Mechanic (One Mechanic Shop)

    Broader source: Energy.gov [DOE]

    Join the Bonneville Power Administration (BPA) for a challenging and rewarding career, while working, living, and playing in the Pacific Northwest. The Heavy Mobile Equipment Mechanic (One Mechanic...

  7. Heavy Mobile Equipment Mechanic (1 Mechanic Shop)

    Broader source: Energy.gov [DOE]

    A successful candidate will perform preventative, predictive, and corrective maintenance on Bonneville Power Administration (BPA's) light and heavy mobile equipment in maintenance and filed...

  8. Mitsubishi Heavy Industries Ltd | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: Mitsubishi Heavy Industries Ltd Place: Tokyo, Tokyo, Japan Zip: 108 8215 Product: Integrated technology company and power equipment supplier....

  9. Heavy Water Test Reactor Dome Removal

    SciTech Connect (OSTI)

    2011-01-01

    A high speed look at the removal of the Heavy Water Test Reactor Dome Removal. A project sponsored by the Recovery Act on the Savannah River Site.

  10. Deasphalting and gasification - A new approach for converting heavy crudes into petrochemicals

    SciTech Connect (OSTI)

    Tellez, E.; Moca, N.; Gomez, O.

    1995-12-31

    The huge amount of heavy and extra-heavy crudes of Maraven has led our company to develop a medium/long term strategic plan for disposition and optimum use of these resources. One of these crudes, Boscan, has been used only in asphalt manufacturing and in some deep conversion refineries (with volumetric limits, 10-15 vol% as coker feed), due to its low quality for fuel manufacturing (10.2{degrees}API, 5.4 wt% sulphur, 1122 ppm vanadium) and high residuum yield (78% LV of 700{degrees}F+ residue). In 1992, Maraven undertook a series of studies that brought about the definition of an industrial complex to convert Boscan extra-heavy crude oil to higher value distillates and chemical products. The combination of Rose Solvent Deasphalting of the Boscan atmospheric residue with the gasification of the deasphalting raffinate produces 79% yield of high quality liquid distillates and clean syngas for chemical synthesis. Under this new approach syngas is used to produce 1600 tons/day of grade AA (99.9 wt%) methanol: 1330 tons/day are available for export and 270 tons/day are dedicated for the production of 500 tons/day of acetic acid. The remaining syngas is used to supply the hydrogen requirements of the Boscan extra heavy crude upgrading complex and for power generation. The technical feasibility of this route, based on commercially proven processes together with adequate economics for this type of business, will allow the conversion of extra-heavy crude oil into higher value distillates and chemical products.

  11. The overthrusted Zaza Terrane of middle Cretaceous over the North American continental carbonate rocks of upper Jurassic-Lower Cretaceous age - relationships to oil generation

    SciTech Connect (OSTI)

    Echevarria Rodriguez, G.; Castro, J.A.; Amaro, S.V.

    1996-08-01

    The Zaza Terrane is part of the Caribbean plate thrust over the southern edge of the North American basinal and platform carbonate rocks of upper Jurassic-Lower Cretaceous age. Zaza Terrane are volcanic and ophiolitic rocks of Cretaceous age. The ophiolites are mostly serpentines which behave as reservoirs and seals. All Cuban oil fields are either within Zaza Terrane or basinal carbonates underneath, or not far away to the north of the thrust contacts. It appears that the overthrusting of the Zaza Terrane caused the generation of oil in the basinal carbonate source rocks underneath, due to the increase of rock thickness which lowered the oil window to a deeper position and increased the geothermal gradient. Oil generation was after thrusting, during post-orogenic. API gravity of oil is light toward the south and heavy to very heavy to the north. Source rocks to the south are probably of terrigenous origin.

  12. Momentum Deposition in Curvilinear Coordinates

    SciTech Connect (OSTI)

    Cleveland, Mathew Allen; Lowrie, Robert Byron; Rockefeller, Gabriel M.; Thompson, Kelly Glen; Wollaber, Allan Benton

    2015-08-03

    The momentum imparted into a material by thermal radiation deposition is an important physical process in astrophysics and inertial confinement fusion (ICF) simulations. In recent work we presented a new method of evaluating momentum deposition that relies on the combination of a time-averaged approximation and a numerical integration scheme. This approach robustly and efficiently evaluates the momentum deposition in spherical geometry. Future work will look to extend this approach to 2D cylindrical geometries.

  13. Biocompatible Coating (Parylene) Deposition System

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metal Containing Diamond-Like Carbon Deposition System Varshni Singh and Jost Goettert Center for Advanced Microstructures & Devices, Louisiana State University, 6980 Jefferson Hwy., Baton Rouge, LA-70806 Summary CAMD/LSU received funds from the Board of Regents' Enhancement Program for modifying and upgrading of a diamond like carbon (DLC) deposition system. This included a magnetron with shield, DC power supply and pulsing unit, mass flow controllers and in-situ thin film deposition

  14. Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion

    Broader source: Energy.gov (indexed) [DOE]

    Modeling | Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation ace001_musculus_2011_o.pdf (1.84 MB) More Documents & Publications Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling High Efficiency Fuel Reactivity Controlled Compression Ignition Combustion

  15. Mathematical model for oil slick transport and mixing in rivers. Special report

    SciTech Connect (OSTI)

    Shen, H.T.; Yapa, P.D.; Wang, D.S.; Yang, X.Q.

    1993-08-01

    The growing concern over the impacts of oil spills on aquatic environments has led to the development of many computer models for simulating the transport and spreading of oil slicks in surface waters. Almost all of these models were developed for coastal environments. A few river models exist. These models only considered the movement of surface oil slicks. In this study a two-layer model, ROSS2, is developed for simulating oil spills in rivers. This model considers the oil in the river to consist of a surface slick and suspended oil droplets entrained over the depth of the flow. The oil transformation processes considered in the model include advection, mechanical spreading, turbulent diffusion and mixing, evaporation, dissolution, emulsification, shoreline deposition and sinking. The model can be used for simulating instantaneous or continuous spills either on or under the water surface in rivers with or without an ice cover. The model has been implemented for the Ohio-Monongahela-Allegheny river system and the upper St. Lawrence River. This report describes the model formulation and implementation. A case study is presented along with detailed explanations of the program structure and its input and output. Although it is developed for simulating oil spills, the model can be applied to spills of other hazardous materials. Computer models, Oil spills, Oil slicks, Rivers.

  16. Carbonate Deposition | Open Energy Information

    Open Energy Info (EERE)

    Alteration Products Carbonate deposits come in many forms and sometimes develop into spectacular colorful terraces such as these at Mammoth Hot Springs in Yellowstone National...

  17. Deepwater Oil & Gas Resources | Department of Energy

    Office of Environmental Management (EM)

    Deepwater Oil & Gas Resources Deepwater Oil & Gas Resources The United States has significant natural gas and oil reserves. But many of these resources are increasingly harder to ...

  18. Heating Oil Reserve History | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heating Oil Reserve History Heating Oil Reserve History Creation of an emergency reserve of heating oil was directed by President Clinton on July 10, 2000, when he directed ...

  19. Deepwater Oil & Gas Resources | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Deepwater Oil & Gas Resources Deepwater Oil & Gas Resources The United States has significant natural gas and oil reserves. But many of these resources are increasingly harder to...

  20. Finding Hidden Oil and Gas Reserves

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Finding Hidden Oil and Gas Reserves Finding Hidden Oil and Gas Reserves Key Challenges: Seismic imaging methods, vital in our continuing search for deep offshore oil and gas...

  1. United Oil Company | Open Energy Information

    Open Energy Info (EERE)

    Oil Company Jump to: navigation, search Name: United Oil Company Place: Pittsburgh, Pennsylvania Product: Vegetable-Oil producer Biodiesel producer based in Pittsburgh, PA...

  2. Microsoft Word - Heating Oil Season.docx

    Broader source: Energy.gov (indexed) [DOE]

    4-2015 Heating Oil Season Northeast Home Heating Oil Reserve Trigger Mechanism (Cents per Gallon, Except Where Noted) Week Residential Heating Oil Price Average Brent Spot Price ...

  3. Heavy ion induction linac drivers for inertial confinement fusion

    SciTech Connect (OSTI)

    Lee, E.P.; Hovingh, J.

    1988-10-01

    Intense beams of high energy heavy ions (e.g., 10 GeV Hg) are an attractive option for an ICF driver because of their favorable energy deposition characteristics. The accelerator systems to produce the beams at the required power level are a development from existing technologies of the induction linac, rf linac/storage ring, and synchrotron. The high repetition rate of the accelerator systems, and the high efficiency which can be realized at high current make this approach especially suitable for commercial ICF. The present report gives a summary of the main features of the induction linac driver system, which is the approach now pursued in the USA. The main subsystems, consisting of injector, multiple beam accelerator at low and high energy, transport and pulse compression lines, and final focus are described. Scale relations are given for the current limits and other features of these subsystems. 17 refs., 1 fig., 1 tab.

  4. Reactivation of an idle lease to increase heavy oil recovery through application of conventional steam drive technology in a low dip slope and basin reservoir in the Midway-Sunset field, San Joaquin basin, California. Quarterly report, January 1--March 31, 1996

    SciTech Connect (OSTI)

    Schamel, S.

    1996-06-28

    This project will reactivate ARCO`s idle Pru Fee lease in the Midway-Sunset field, California and conduct a continuous steamflood enhanced oil recovery demonstration aided by an integration of modern reservoir characterization and simulation methods. The objectives of the project are: (1) to return the shut-in portion of the reservoir to commercial production; (2) to accurately describe the reservoir and recovery process; and (3) convey the details of this activity to the domestic petroleum industry, especially to other producers in California, through an aggressive technology transfer program. The producibility problems initially thought to be responsible for the low recovery in the Pru Fee property are: (a) the shallow dip of the bedding; (b) complex reservoir structure, (c) thinning pay zone; and (d) the presence of bottom water. The project is using tight integration of reservoir characterization and simulation modeling to evaluate the magnitude of and alternative solutions to these problems. Two main activities were brought to completion during the first quarter of 1996: (1) lithologic and petrophysical description of the core taken form the new well Pru 101 near the center of the demonstration site and (2) development of a stratigraphic model for the Pru Fee project area. In addition, the first phase of baseline cyclic steaming of the Pru Fee demonstration site was continued with production tests and formation temperature monitoring.

  5. Abandoned Texas oil fields

    SciTech Connect (OSTI)

    Not Available

    1980-12-01

    Data for Texas abandoned oil fields were primarily derived from two sources: (1) Texas Railroad Commission (TRRC), and (2) Dwight's ENERGYDATA. For purposes of this report, abandoned oil fields are defined as those fields that had no production during 1977. The TRRC OILMASTER computer tapes were used to identify these abandoned oil fields. The tapes also provided data on formation depth, gravity of oil production, location (both district and county), discovery date, and the cumulative production of the field since its discovery. In all, the computer tapes identified 9211 abandoned fields, most of which had less than 250,000 barrel cumulative production. This report focuses on the 676 abandoned onshore Texas oil fields that had cumulative production of over 250,000 barrels. The Dwight's ENERGYDATA computer tapes provided production histories for approximately two-thirds of the larger fields abandoned in 1966 and thereafter. Fields which ceased production prior to 1966 will show no production history nor abandonment date in this report. The Department of Energy hopes the general availability of these data will catalyze the private sector recovery of this unproduced resource.

  6. A Heavy Flavor Tracker for STAR

    SciTech Connect (OSTI)

    Xu, Z.; Chen, Y.; Kleinfelder, S.; Koohi, A.; Li, S.; Huang, H.; Tai, A.; Kushpil, V.; Sumbera, M.; Colledani, C.; Dulinski, W.; Himmi,A.; Hu, C.; Shabetai, A.; Szelezniak, M.; Valin, I.; Winter, M.; Surrow,B.; Van Nieuwenhuizen, G.; Bieser, F.; Gareus, R.; Greiner, L.; Lesser,F.; Matis, H.S.; Oldenburg, M.; Ritter, H.G.; Pierpoint, L.; Retiere, F.; Rose, A.; Schweda, K.; Sichtermann, E.; Thomas, J.H.; Wieman, H.; Yamamoto, E.; Kotov, I.

    2005-03-14

    We propose to construct a Heavy Flavor Tracker (HFT) for the STAR experiment at RHIC. The HFT will bring new physics capabilities to STAR and it will significantly enhance the physics capabilities of the STAR detector at central rapidities. The HFT will ensure that STAR will be able to take heavy flavor data at all luminosities attainable throughout the proposed RHIC II era.

  7. Heavy Vehicle Technologies Program Retrospective and Outlook

    SciTech Connect (OSTI)

    James J. Eberhardt

    1999-04-10

    OHVT Mission is to conduct, in collaboration with our heavy vehicle industry partners and their suppliers, a customer-focused national program to research and develop technologies that will enable trucks and other heavy vehicles to be more energy efficient and able to use alternative fuels while simultaneously reducing emissions.

  8. Characterization of swift heavy ion irradiation damage in ceria

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yablinsky, Clarissa A.; Devanathan, Ram; Pakarinen, Janne; Gan, Jian; Severin, Daniel; Trautmann, Christina; Allen, Todd R.

    2015-03-04

    Swift heavy ion induced radiation damage is investigated for ceria (CeO2), which serves as a UO2 fuel surrogate. Microstructural changes resulting from an irradiation with 940 MeV gold ions of 42 keV/nm electronic energy loss are investigated by means of electron microscopy accompanied by electron energy loss spectroscopy showing that there exists a small density reduction in the ion track core. While chemical changes in the ion track are not precluded, evidence of them was not observed. Classical molecular dynamics simulations of thermal spikes in CeO2 with an energy deposition of 12 and 36 keV/nm show damage consisting of isolatedmore » point defects at 12 keV/nm, and defect clusters at 36 keV/nm, with no amorphization at either energy. Furthermore, inferences are drawn from modeling about density changes in the ion track and the formation of interstitial loops that shed light on features observed by electron microscopy of swift heavy ion irradiated ceria.« less

  9. Fate of asphaltenes during hydroprocessing of heavy petroleum residues

    SciTech Connect (OSTI)

    Stanislaus, A.; Absi-Halabi, M.; Khan, Z.

    1994-12-31

    Formation of coke like sediments or particulates is a serious problem in the hydroprocessing of heavy residues for high conversion. The sediments can cause both operability problems and rapid catalyst deactivation. The macromolecules of the heavy feedstocks such as asphaltenes are believed to contribute significantly to sediment formation and coke deposition. As part of an extensive research program on the factors which influence sludge or solids formation during residue hydroprocessing, the authors have examined the nature of changes that take place in the characteristics of the asphaltenic fraction of Kuwait vacuum residue under different operating conditions. The studies revealed that sediment formation is the result of reduction in solubilization efficiency of asphaltenes in the product medium compared with feedstock. Molecular size distribution of the product asphaltenes showed that operating at high temperatures enhanced depolymerization and fragmentation of asphaltenes to low molecular weight materials. A portion of the low molecular weight asphaltene fragments with relatively low H/C ratio resisted further cracking even at high temperatures and led to the formation of coke like sediments. Large pore catalysts were observed to reduce the problem of sediments formation. The role of catalyst pore size on asphaltenes conversion is discussed.

  10. Modeling the Kinetics of Deactivation of Catalysts during the Upgrading of Bio-Oil

    SciTech Connect (OSTI)

    Weber, Robert S.; Olarte, Mariefel V.; Wang, Huamin

    2015-01-25

    The fouling of catalysts for the upgrading of bio-oils appears to be very different from the fouling of catalysts for the hydroprocessing of petroleum-derived streams. There are two reasons for the differences: a) bio-oil contains polarizable components and phases that can stabilize reaction intermediates exhibiting charge separation and b) bio-oil components contain functional groups that contain O, notably carbonyls (>C=O). Aldol condensation of carbonyls affords very different pathways for the production of oligomeric, refractory deposits than does dehydrogenation/polymerization of petroleum-derived hydrocarbons. Colloquially, we refer to the bio-oil derived deposits as “gunk” to discriminate them from coke, the carbonaceous deposits encountered in petroleum refining. Classical gelation, appears to be a suitable model for the “gunking” reaction. Our work has helped explain the temperature range at which bio-oil should be pre-processed (“stabilized”) to confer longer lifetimes on the catalysts used for more severe processing. Stochastic modeling (kinetic Monte Carlo simulations) appears suitable to capture the rates of oligomerization of bio-oil. This work was supported by the US Department of Energy, Office of Energy Efficiency and Renewable Energy, Bioenergy Technologies Office. Pacific Northwest National Laboratory (PNNL) is a multiprogram national laboratory operated for DOE by Battelle.

  11. HEAVY WATER MODERATED NEUTRONIC REACTOR

    DOE Patents [OSTI]

    Szilard, L.

    1958-04-29

    A nuclear reactor of the type which utilizes uranium fuel elements and a liquid coolant is described. The fuel elements are in the form of elongated tubes and are disposed within outer tubes extending through a tank containing heavy water, which acts as a moderator. The ends of the fuel tubes are connected by inlet and discharge headers, and liquid bismuth is circulated between the headers and through the fuel tubes for cooling. Helium is circulated through the annular space between the outer tubes in the tank and the fuel tubes to cool the water moderator to prevent boiling. The fuel tubes are covered with a steel lining, and suitable control means, heat exchange means, and pumping means for the coolants are provided to complete the reactor assembly.

  12. Progress in Heavy Ion Fusion

    SciTech Connect (OSTI)

    Herrmannsfeldt, W.B.

    1988-09-01

    The progress of the field of Heavy Ion Fusion has been documented in the proceedings of the series of International Symposia that, in recent years, have occurred every second year. The latest of these conferences was hosted by Gesellshaft fuer Schwerionenforshung (GSI) in Darmstadt, West Germany, June 28-30, 1988. For this report, a few highlights from the conference are selected, stressing experimental progress and prospects for future advances. A little extra time is devoted to report on the developments at the Lawrence Berkeley Laboratory (LBL) which is the center for most of the HIFAR program. The Director of the HIFAR program at LBL is Denis Keefe, who presented the HIF report at the last two of the meetings in this series, and in whose place the author is appearing now. 4 refs., 1 fig.

  13. Heavy Duty Vehicle Futures Analysis.

    SciTech Connect (OSTI)

    Askin, Amanda Christine; Barter, Garrett.; West, Todd H.; Manley, Dawn Kataoka

    2014-05-01

    This report describes work performed for an Early Career Research and Development project. This project developed a heavy-duty vehicle (HDV) sector model to assess the factors influencing alternative fuel and efficiency technology adoption. This model builds on a Sandia light duty vehicle sector model and provides a platform for assessing potential impacts of technological advancements developed at the Combustion Research Facility. Alternative fuel and technology adoption modeling is typically developed around a small set of scenarios. This HDV sector model segments the HDV sector and parameterizes input values, such as fuel prices, efficiencies, and vehicle costs. This parameterization enables sensitivity and trade space analyses to identify the inputs that are most associated with outputs of interest, such as diesel consumption and greenhouse gas emissions. Thus this analysis tool enables identification of the most significant HDV sector drivers that can be used to support energy security and climate change goals.

  14. Heavy Gas Dispersion Incompressible Flow

    Energy Science and Technology Software Center (OSTI)

    1992-02-03

    FEM3 is a numerical model developed primarily to simulate heavy gas dispersion in the atmosphere, such as the gravitational spread and vapor dispersion that result from an accidental spill of liquefied natural gas (LNG). FEM3 solves both two and three-dimensional problems and, in addition to the generalized anelastic formulation, includes options to use either the Boussinesq approximation or an isothermal assumption, when appropriate. The FEM3 model is composed of three parts: a preprocessor PREFEM3, themore » main code FEM3, and two postprocessors TESSERA and THPLOTX. The DEC VAX11 version contains an auxiliary program, POLYREAD, which reads the polyplot file created by FEM3.« less

  15. APBF-DEC Heavy Duty NOx Adsorber/DPF Project: Heavy Duty Linehaul Platform

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Project Update | Department of Energy Heavy Duty NOx Adsorber/DPF Project: Heavy Duty Linehaul Platform Project Update APBF-DEC Heavy Duty NOx Adsorber/DPF Project: Heavy Duty Linehaul Platform Project Update 2003 DEER Conference Presentation: Ricardo Inc., Chicago Technical Center deer_2003_may.pdf (712.68 KB) More Documents & Publications Status of APBF-DEC NOx Adsorber/DPF Projects APBF- DEC Heavy-Duty NOx Adsorber/DPF Project: Catalyst Aging Study APBF-DEC Light-duty NOx Adsorber/DPF

  16. Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion

    Broader source: Energy.gov (indexed) [DOE]

    Modeling | Department of Energy 09 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. ace_01_musculus.pdf (2.77 MB) More Documents & Publications Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Vehicle Technologies Office Merit Review 2014: Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Heavy-Duty Low-Temperature and Diesel

  17. International Oil and Gas Board International Oil and Gas Board...

    Open Energy Info (EERE)

    Petroleum Company Syrian Petroleum Company Damascus Syria Syria http www spc sy com en production activities1 en php Yemen Ministry of Oil and Minerals Yemen Ministry of Oil and...

  18. Enhanced Oil Recovery to Fuel Future Oil Demands | GE Global...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enhanced Oil Recovery to Fuel Future Oil Demands Click to email this to a friend (Opens in new window) Share on Facebook (Opens in new window) Click to share (Opens in new window) ...

  19. Deposited films with improved microstructures

    DOE Patents [OSTI]

    Patten, James W.; Moss, Ronald W.; McClanahan, Edwin D.

    1984-01-01

    Methods for improving microstructures of line-of-sight deposited films are described. Columnar growth defects ordinarily produced by geometrical shadowing during deposition of such films are eliminated without resorting to post-deposition thermal or mechanical treatments. The native, as-deposited coating qualities, including homogeneity, fine grain size, and high coating-to-substrate adherence, can thus be retained. The preferred method includes the steps of emitting material from a source toward a substrate to deposit a coating non-uniformly on the substrate surface, removing a portion of the coating uniformly over the surface, again depositing material onto the surface, but from a different direction, and repeating the foregoing steps. The quality of line-of-sight deposited films such as those produced by sputtering, progressively deteriorates as the angle of incidence between the flux and the surface becomes increasingly acute. Depositing non-uniformly, so that the coating becomes progressively thinner as quality deteriorates, followed by uniformly removing some of the coating, such as by resputtering, eliminates the poor quality portions, leaving only high quality portions of the coating. Subsequently sputtering from a different direction applies a high quality coating to other regions of the surface. Such steps can be performed either simultaneously or sequentially to apply coatings of a uniformly high quality, closed microstructure to three-dimensional or large planar surfaces.

  20. Variable temperature semiconductor film deposition

    DOE Patents [OSTI]

    Li, Xiaonan; Sheldon, Peter

    1998-01-01

    A method of depositing a semiconductor material on a substrate. The method sequentially comprises (a) providing the semiconductor material in a depositable state such as a vapor for deposition on the substrate; (b) depositing the semiconductor material on the substrate while heating the substrate to a first temperature sufficient to cause the semiconductor material to form a first film layer having a first grain size; (c) continually depositing the semiconductor material on the substrate while cooling the substrate to a second temperature sufficient to cause the semiconductor material to form a second film layer deposited on the first film layer and having a second grain size smaller than the first grain size; and (d) raising the substrate temperature, while either continuing or not continuing to deposit semiconductor material to form a third film layer, to thereby anneal the film layers into a single layer having favorable efficiency characteristics in photovoltaic applications. A preferred semiconductor material is cadmium telluride deposited on a glass/tin oxide substrate already having thereon a film layer of cadmium sulfide.

  1. Variable temperature semiconductor film deposition

    DOE Patents [OSTI]

    Li, X.; Sheldon, P.

    1998-01-27

    A method of depositing a semiconductor material on a substrate is disclosed. The method sequentially comprises (a) providing the semiconductor material in a depositable state such as a vapor for deposition on the substrate; (b) depositing the semiconductor material on the substrate while heating the substrate to a first temperature sufficient to cause the semiconductor material to form a first film layer having a first grain size; (c) continually depositing the semiconductor material on the substrate while cooling the substrate to a second temperature sufficient to cause the semiconductor material to form a second film layer deposited on the first film layer and having a second grain size smaller than the first grain size; and (d) raising the substrate temperature, while either continuing or not continuing to deposit semiconductor material to form a third film layer, to thereby anneal the film layers into a single layer having favorable efficiency characteristics in photovoltaic applications. A preferred semiconductor material is cadmium telluride deposited on a glass/tin oxide substrate already having thereon a film layer of cadmium sulfide.

  2. Upper Permian lacustrine oil shales, southern Junggar basin, northwest China

    SciTech Connect (OSTI)

    Carroll, A.R.; Brassell, S.C.; Graham, S.A. )

    1992-12-01

    Upper Permian organic-rich lacustrine mudstones (oil shales) that crop out in the southern Junggar basin rank among the richest and thickest petroleum source rock intervals in the world, with maximum TOC values reaching 34% and Rock-Eval pyrolytic yields (S[sub 2]) up to 200 kg HC/t rock. Lacustrine sedimentary facies define an overall transgressive-regressive cycle of approximately 2000 m gross thickness, which includes approximately 800 m of source rocks averaging 4.1% TOC and 26.2 kg HC/t rock. Basinal facies comprise silicic, organic-rich, laminated lacustrine mudstones and interbedded siltstones; organic matter contained in the mudstones ranges in composition from type I to type III. Basinal facies were deposited in a deep, oxygen-deficient, stratified lake. Lake-margin facies consist of nonlaminated siliciclastic mudstones, rippled dolomitic silstones and sandstones, and minor limestones. Maximum TOC values are approximately 6%. Desiccation cracks are common in the marginal facies, but evaporite minerals are rare or absent. Biomarker correlation parameters measured from rock extracts exhibit significant stratigraphic variability, but strongly support the hypothesis that Upper Permian lacustrine oil shales charge the giant Karamay field in the northwestern Junggar basin. Karamay oils are characterized by high relative abundances of [beta]-carotane. This characteristic is restricted to desiccated facies in the outcrop sections, however. We therefore propose that an abundance of [beta]-carotane indicates elevated environmental salinities during deposition of the oil shales. 16 figs., 9 tabs.

  3. QCD mechanisms for heavy particle production

    SciTech Connect (OSTI)

    Brodsky, S.J.

    1985-09-01

    For very large pair mass, the production of heavy quarks and supersymmetric particles is expected to be governed by ACD fusion subprocesses. At lower mass scales other QCD mechanisms such as prebinding distortion and intrinsic heavy particle Fock states can become important, possibly accounting for the anomalies observed for charm hadroproduction. We emphasize the importance of final-state Coulomb interactions at low relative velocity in QCD and predict the existence of heavy narrow four quark resonances (c c-bar u u-bar) and (cc c-bar c-bar) in ..gamma gamma.. reactions. Coherent QCD contributions are discussed as a contribution to the non-additivity of nuclear structure functions and heavy particle production cross sections. We also predict a new type of amplitude zero for exclusive heavy meson pair production which follows from the tree-graph structure of QCD. 35 refs., 8 figs., 1 tab.

  4. History of western oil shale

    SciTech Connect (OSTI)

    Russell, P.L.

    1980-01-01

    The history of oil shale in the United States since the early 1900's is detailed. Research on western oil shale probably began with the work of Robert Catlin in 1915. During the next 15 years there was considerable interest in the oil shales, and oil shale claims were located, and a few recovery plants were erected in Colorado, Nevada, Utah, Wyoming, and Montana. Little shale soil was produced, however, and the major oil companies showed little interest in producing shale oil. The early boom in shale oil saw less than 15 plants produce a total of less than 15,000 barrels of shale oil, all but about 500 barrels of which was produced by the Catlin Operation in Nevada and by the US Bureau of Mines Rulison, Colorado operation. Between 1930 and 1944 plentiful petroleum supplies at reasonable prices prevent any significant interest in shale oil, but oil shortages during World War II caused a resurgence of interest in oil shale. Between 1940 and 1969, the first large-scale mining and retorting operations in soil shale, and the first attempts at true in situ recovery of shale oil began. Only 75,000 barrels of shale oil were produced, but major advancements were made in developing mine designs and technology, and in retort design and technology. The oil embargo of 1973 together with a new offering of oil shale leases by the Government in 1974 resulted in the most concentrated efforts for shale oil production to date. These efforts and the future prospects for shale oil as an energy source in the US are discussed.

  5. Too early to tell on $100 oil

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Confidential Presentation to: April 7, 2008 Middle East oil demand and Lehman Brothers oil price outlook Adam Robinson Middle East oil demand u Three pillars of Middle East oil ...

  6. Oil and Gas

    Office of Environmental Management (EM)

    RD&D Leases in the United States Oil Shale RD&D Leases in the United States This paper describes the original plans, progress and accomplishments, and future plans for nine oil shale research, development and demonstration (RD&D) projects on six existing RD&D leases awarded in 2006 and 2007 by the United States Department of the Interior, Bureau of Land Management (BLM) to Shell, Chevron, EGL (now AMSO), and OSEC (now Enefit American, respectively); as well as three pending

  7. Western Hemisphere Oil Products Balance

    U.S. Energy Information Administration (EIA) Indexed Site

    Western Hemisphere Oil Products Balance Ramn Espinasa, Ph.D. Lead Specialist July 2014 ... non-commercial purposes. 4 United States Oil Products Balance 5 Energy Matrix - USA 6 ...

  8. Distributed Bio-Oil Reforming

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Distributed Bio-Oil Reforming R. Evans, S. Czernik, R. French, M. Ratcliff National ... GAS 7 BIOMASS BIO-OIL CHAR For reactor or export Gas recycle For fluidization or export ...

  9. STEO December 2012 - oil production

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rise in 2012 U.S. oil production largest since 1859, output in 2013 seen topping 7 million bpd U.S. crude oil production is now expected to rise by about 760,000 barrels per day in ...

  10. Research Portfolio Report Unconventional Oil & Gas Resources...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Unconventional Oil & Gas Resources: Subsurface Geology and Engineering DOENETL-20151691 ... Research Portfolio Report: Unconventional Oil & Gas Resources Executive Summary S ...

  11. Heating Oil and Propane Update

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Maps of states participating in Winter Fuels Survey Residential propane PADD map Residential heating oil PADD map

  12. Acoustic Energy: An Innovative Technology for Stimulating Oil Wells

    SciTech Connect (OSTI)

    Edgar, Dorland E.; Peters, Robert W.; Johnson, Donald O.; Paulsen, P. David; Roberts, Wayne

    2006-04-30

    The objective of this investigation was to demonstrate the effectiveness of sonication in reducing the viscosity of heavy crude oils. Sonication is the use of acoustic or sound energy to produce physical and/or chemical changes in materials, usually fluids. The goal of the first project phase was to demonstrate a proof of concept for the project objective. Batch tests of three commercially available, single-weight oils (30-, 90-, and 120-wt) were performed in the laboratory. Several observations and conclusions were made from this series of experiments. These include the following: (1) In general, the lower the acoustic frequency, the greater the efficiency in reducing the viscosity of the oils; (2) Sonication treatment of the three oils resulted in reductions in viscosity that ranged from a low of 31% to a high of 75%; and (3) The results of the first phase of the project successfully demonstrated that sonication could reduce the viscosity of oils of differing viscosity. The goal of the second project phase was to demonstrate the ability of sonication to reduce the viscosity of three crude oils ranging from a light crude to a heavy crude. The experiments also were designed to examine the benefits of two proprietary chemical additives used in conjunction with sonication. Acoustic frequencies ranging from 800 Hz to 1.6 kHz were used in these tests, and a reactor chamber was designed for flow-through operation with a capacity of one gallon (3.8 liters). The three crude oils selected for use in the testing program were: (1) a heavy crude from California with a viscosity of approximately 65,000 cP (API gravity about 12{sup o}), (2) a crude from Alabama with a significant water content and a viscosity of approximately 6,000 cP (API gravity about 22 {sup o}), and (3) a light crude from the Middle East with a viscosity of approximately 700 cP (API gravity about 32{sup o}). The principal conclusions derived from the second project phase include the following: (1) The

  13. Heavy Quarks, QCD, and Effective Field Theory Thomas Mehen 72...

    Office of Scientific and Technical Information (OSTI)

    Heavy Quarks, QCD, and Effective Field Theory Thomas Mehen 72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS; 73 NUCLEAR PHYSICS AND RADIATION PHYSICS Heavy Quarks, Quarkonium,...

  14. The Silicon Vertex Tracker for the Heavy Photon Search Experiment...

    Office of Scientific and Technical Information (OSTI)

    Silicon Vertex Tracker for the Heavy Photon Search Experiment Citation Details In-Document Search Title: The Silicon Vertex Tracker for the Heavy Photon Search Experiment Authors: ...

  15. Hydrogen Production and Purification from Coal and Other Heavy...

    Office of Scientific and Technical Information (OSTI)

    Hydrogen Production and Purification from Coal and Other Heavy Feedstocks Year 6 - ... Title: Hydrogen Production and Purification from Coal and Other Heavy Feedstocks Year 6 - ...

  16. Heavy Quarks, QCD, and Effective Field Theory (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    Title: Heavy Quarks, QCD, and Effective Field Theory The research supported by this OJI award is in the area of heavy quark and quarkonium production, especially the application ...

  17. Implications of naturalness for the heavy Higgs bosons of supersymmetr...

    Office of Scientific and Technical Information (OSTI)

    Implications of naturalness for the heavy Higgs bosons of supersymmetry Citation Details In-Document Search Title: Implications of naturalness for the heavy Higgs bosons of ...

  18. Heavy quarkonium in a holographic basis (Journal Article) | DOE...

    Office of Scientific and Technical Information (OSTI)

    Heavy quarkonium in a holographic basis Title: Heavy quarkonium in a holographic basis Authors: Li, Yang Search DOE PAGES for author "Li, Yang" Search DOE PAGES for ORCID ...

  19. Design and Implementation of Silicon Nitride Valves for Heavy...

    Energy Savers [EERE]

    Design and Implementation of Silicon Nitride Valves for Heavy Duty Diesel Engines Design and Implementation of Silicon Nitride Valves for Heavy Duty Diesel Engines Poster ...

  20. A High Temperature Direct Vehicle Exhaust Flowmeter for Heavy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A High Temperature Direct Vehicle Exhaust Flowmeter for Heavy Duty Diesel Emission Measurements. A High Temperature Direct Vehicle Exhaust Flowmeter for Heavy Duty Diesel Emission ...