National Library of Energy BETA

Sample records for heavy metal mthm

  1. Heavy metal biosensor

    DOE Patents [OSTI]

    Hillson, Nathan J; Shapiro, Lucille; Hu, Ping; Andersen, Gary L

    2014-04-15

    Compositions and methods are provided for detection of certain heavy metals using bacterial whole cell biosensors.

  2. Process for removing heavy metal compounds from heavy crude oil

    DOE Patents [OSTI]

    Cha, Chang Y.; Boysen, John E.; Branthaver, Jan F.

    1991-01-01

    A process is provided for removing heavy metal compounds from heavy crude oil by mixing the heavy crude oil with tar sand; preheating the mixture to a temperature of about 650.degree. F.; heating said mixture to up to 800.degree. F.; and separating tar sand from the light oils formed during said heating. The heavy metals removed from the heavy oils can be recovered from the spent sand for other uses.

  3. Plant rhamnogalacturonan II complexation of heavy metal cations

    DOE Patents [OSTI]

    O'Neill, Malcolm A.; Pellerin, Patrice J. M.; Warrenfeltz, Dennis; Vidal, Stephane; Darvill, Alan G.; Albersheim, Peter

    1999-01-01

    The present invention provides rhamnogalacturonan-II (RG-II) and relates to its ability to complex specific multivalent heavy metal cations. In the presence of boric acid, RG-II monomers form dimers that are cross-linked by a borate ester. The yield of such borate ester cross-linked dimers of RG-II is enhanced in the presence of specific heavy metal cations. The present invention further relates to the utility of RG-II in assays for the detection of specific heavy metal contamination; as a reagent useful in the removal of specific heavy metal cations contaminating foods and liquids, for example, fish, wines, etc.; as a pharmaceutical composition useful as an antidote in specific heavy metal cation poisoning; as a treatment for the detoxification of specific heavy metal cations from blood and/or tissues; and in a method of remediation of waters and soils contaminated with specific heavy metal cations.

  4. Plant rhamnogalacturonan II complexation of heavy metal cations

    DOE Patents [OSTI]

    O`Neill, M.A.; Pellerin, P.J.M.; Warrenfeltz, D.; Vidal, S.; Darvill, A.G.; Albersheim, P.

    1999-03-02

    The present invention provides rhamnogalacturonan-II (RG-II) and relates to its ability to complex specific multivalent heavy metal cations. In the presence of boric acid, RG-II monomers form dimers that are cross-linked by a borate ester. The yield of such borate ester cross-linked dimers of RG-II is enhanced in the presence of specific heavy metal cations. The present invention further relates to the utility of RG-II in assays for the detection of specific heavy metal contamination; as a reagent useful in the removal of specific heavy metal cations contaminating foods and liquids, for example, fish, wines, etc.; as a pharmaceutical composition useful as an antidote in specific heavy metal cation poisoning; as a treatment for the detoxification of specific heavy metal cations from blood and/or tissues; and in a method of remediation of waters and soils contaminated with specific heavy metal cations. 15 figs.

  5. Heavy metal movement in metal-contaminated soil profiles

    SciTech Connect (OSTI)

    Li, Zhenbin; Shuman, L.M.

    1996-10-01

    Heavy metal movement in soil profiles is a major environmental concern because even slow transport through the soil may eventually lead to deterioration of groundwater quality. In this study, three metal-contaminated soil (Fuquay, Dothan, and Clarendon) were selected from cropland were a high-metal flue dust had been applied annually for 6 years to raise soil pH, with application ending 4 years before sampling. One uncontaminated soil (Tifton) from the same physiographic area was also sampled as a control. Soil samples were collected in 15-cm increments from the surface to 105 cm in depth. Total contents of Zn, Cd, and Pb in the soils samples were determined. To better understand metal movement in relation to metal fractions in the soil profile, soil samples were also extracted sequentially for exchangeable (EXC), organic matter (OM), Mn oxide (MNO), amorphous Fe oxide (AFEO), crystalline Fe oxide (CFEO), and residual (RES) fractions. 35 refs., 6 figs., 2 tabs.

  6. Mobility of Source Zone Heavy Metals and Radionuclides: The Mixed...

    Office of Scientific and Technical Information (OSTI)

    Various U. S. Department of Energy (DOE) low and medium-level radioactive waste sites contain mixtures of heavy metals, radionuclides and assorted organic materials. Over time, ...

  7. Metagenomic Insights into Evolution of a Heavy Metal-Contaminated...

    Office of Scientific and Technical Information (OSTI)

    exposure to high concentrations of heavy metals, nitric acid and organic solvents (;;50 ... metagenomics; microbial ecology; bioremediation Word Cloud More Like This Full Text ...

  8. Reducing volatilization of heavy metals in phosphate-pretreated municipal

    Office of Scientific and Technical Information (OSTI)

    solid waste incineration fly ash by forming pyromorphite-like minerals (Journal Article) | SciTech Connect Reducing volatilization of heavy metals in phosphate-pretreated municipal solid waste incineration fly ash by forming pyromorphite-like minerals Citation Details In-Document Search Title: Reducing volatilization of heavy metals in phosphate-pretreated municipal solid waste incineration fly ash by forming pyromorphite-like minerals This research investigated the feasibility of reducing

  9. Heavy metal ions are potent inhibitors of protein folding

    SciTech Connect (OSTI)

    Sharma, Sandeep K. [Biochemisches Institut, Universitaet Zuerich, CH-8057 Zuerich (Switzerland); Departement de Biologie Moleculaire Vegetale, Universite de Lausanne, CH-1015 Lausanne (Switzerland); Goloubinoff, Pierre [Departement de Biologie Moleculaire Vegetale, Universite de Lausanne, CH-1015 Lausanne (Switzerland); Christen, Philipp [Biochemisches Institut, Universitaet Zuerich, CH-8057 Zuerich (Switzerland)], E-mail: christen@bioc.uzh.ch

    2008-07-25

    Environmental and occupational exposure to heavy metals such as cadmium, mercury and lead results in severe health hazards including prenatal and developmental defects. The deleterious effects of heavy metal ions have hitherto been attributed to their interactions with specific, particularly susceptible native proteins. Here, we report an as yet undescribed mode of heavy metal toxicity. Cd{sup 2+}, Hg{sup 2+} and Pb{sup 2+} proved to inhibit very efficiently the spontaneous refolding of chemically denatured proteins by forming high-affinity multidentate complexes with thiol and other functional groups (IC{sub 50} in the nanomolar range). With similar efficacy, the heavy metal ions inhibited the chaperone-assisted refolding of chemically denatured and heat-denatured proteins. Thus, the toxic effects of heavy metal ions may result as well from their interaction with the more readily accessible functional groups of proteins in nascent and other non-native form. The toxic scope of heavy metals seems to be substantially larger than assumed so far.

  10. Magnetic process for removing heavy metals from water employing magnetites

    DOE Patents [OSTI]

    Prenger, F. Coyne; Hill, Dallas D.

    2006-12-26

    A process for removing heavy metals from water is provided. The process includes the steps of introducing magnetite to a quantity of water containing heavy metal. The magnetite is mixed with the water such that at least a portion of, and preferably the majority of, the heavy metal in the water is bound to the magnetite. Once this occurs the magnetite and absorbed metal is removed from the water by application of a magnetic field. In most applications the process is achieved by flowing the water through a solid magnetized matrix, such as steel wool, such that the magnetite magnetically binds to the solid matrix. The magnetized matrix preferably has remnant magnetism, but may also be subject to an externally applied magnetic field. Once the magnetite and associated heavy metal is bound to the matrix, it can be removed and disposed of, such as by reverse water or air and water flow through the matrix. The magnetite may be formed in-situ by the addition of the necessary quantities of Fe(II) and Fe(III) ions, or pre-formed magnetite may be added, or a combination of seed and in-situ formation may be used. The invention also relates to an apparatus for performing the removal of heavy metals from water using the process outlined above.

  11. Magnetic process for removing heavy metals from water employing magnetites

    DOE Patents [OSTI]

    Prenger, F. Coyne; Hill, Dallas D.; Padilla, Dennis D.; Wingo, Robert M.; Worl, Laura A.; Johnson, Michael D.

    2003-07-22

    A process for removing heavy metals from water is provided. The process includes the steps of introducing magnetite to a quantity of water containing heavy metal. The magnetite is mixed with the water such that at least a portion of, and preferably the majority of, the heavy metal in the water is bound to the magnetite. Once this occurs the magnetite and absorbed metal is removed from the water by application of a magnetic field. In most applications the process is achieved by flowing the water through a solid magnetized matrix, such as steel wool, such that the magnetite magnetically binds to the solid matrix. The magnetized matrix preferably has remnant magnetism, but may also be subject to an externally applied magnetic field. Once the magnetite and associated heavy metal is bound to the matrix, it can be removed and disposed of, such as by reverse water or air and water flow through the matrix. The magnetite may be formed in-situ by the addition of the necessary quantities of Fe(II) and Fe(III) ions, or pre-formed magnetite may be added, or a combination of seed and in-situ formation may be used. The invention also relates to an apparatus for performing the removal of heavy metals from water using the process outlined above.

  12. Situ formation of apatite for sequestering radionuclides and heavy metals

    DOE Patents [OSTI]

    Moore, Robert C.

    2003-07-15

    Methods for in situ formation in soil of a permeable reactive barrier or zone comprising a phosphate precipitate, such as apatite or hydroxyapatite, which is capable of selectively trapping and removing radionuclides and heavy metal contaminants from the soil, while allowing water or other compounds to pass through. A preparation of a phosphate reagent and a chelated calcium reagent is mixed aboveground and injected into the soil. Subsequently, the chelated calcium reagent biodegrades and slowly releases free calcium. The free calcium reacts with the phosphate reagent to form a phosphate precipitate. Under the proper chemical conditions, apatite or hydroxyapatite can form. Radionuclide and heavy metal contaminants, including lead, strontium, lanthanides, and uranium are then selectively sequestered by sorbing them onto the phosphate precipitate. A reducing agent can be added for reduction and selective sequestration of technetium or selenium contaminants.

  13. Surfactant biocatalyst for remediation of recalcitrant organics and heavy metals

    DOE Patents [OSTI]

    Brigmon, Robin L.; Story, Sandra; Altman, Denis J.; Berry, Christopher J.

    2011-03-15

    Novel strains of isolated and purified bacteria have been identified which have the ability to degrade petroleum hydrocarbons including a variety of PAHs. Several isolates also exhibit the ability to produce a biosurfactant. The combination of the biosurfactant-producing ability along with the ability to degrade PAHs enhances the efficiency with which PAHs may be degraded. Additionally, the biosurfactant also provides an additional ability to bind heavy metal ions for removal from a soil or aquatic environment.

  14. Surfactant biocatalyst for remediation of recalcitrant organics and heavy metals

    DOE Patents [OSTI]

    Brigmon, Robin L.; Story, Sandra; Altman, Denis J.; Berry, Christopher J.

    2011-05-03

    Novel strains of isolated and purified bacteria have been identified which have the ability to degrade petroleum hydrocarbons including a variety of PAHs. Several isolates also exhibit the ability to produce a biosurfactant. The combination of the biosurfactant-producing ability along with the ability to degrade PAHs enhances the efficiency with which PAHs may be degraded. Additionally, the biosurfactant also provides an additional ability to bind heavy metal ions for removal from a soil or aquatic environment.

  15. Surfactant biocatalyst for remediation of recalcitrant organics and heavy metals

    DOE Patents [OSTI]

    Brigmon, Robin L.; Story, Sandra; Altman; Denis J.; Berry, Christopher J.

    2011-03-29

    Novel strains of isolated and purified bacteria have been identified which have the ability to degrade petroleum hydrocarbons including a variety of PAHs. Several isolates also exhibit the ability to produce a biosurfactant. The combination of the biosurfactant-producing ability along with the ability to degrade PAHs enhances the efficiency with which PAHs may be degraded. Additionally, the biosurfactant also provides an additional ability to bind heavy metal ions for removal from a soil or aquatic environment.

  16. Surfactant biocatalyst for remediation of recalcitrant organics and heavy metals

    DOE Patents [OSTI]

    Brigmon, Robin L.; Story, Sandra; Altman, Denis; Berry, Christopher J.

    2009-01-06

    Novel strains of isolated and purified bacteria have been identified which have the ability to degrade petroleum hydrocarbons including a variety of PAHs. Several isolates also exhibit the ability to produce a biosurfactant. The combination of the biosurfactant-producing ability along with the ability to degrade PAHs enhances the efficiency with which PAHs may be degraded. Additionally, the biosurfactant also provides an additional ability to bind heavy metal ions for removal from a soil or aquatic environment.

  17. Extractability of heavy metals in wastewater solids undergoing anaerobic digestion

    SciTech Connect (OSTI)

    Chen, D.D.

    1983-01-01

    The extractability of heavy metals in wastewater sludge undergoing anaerobic digestion was investigated. Using batch laboratory digesters, raw wastewater sludge was anaerobically digested at different raw sludge solids loadings and two temperatures. From each of the laboratory digesters, wastewater sludge was sampled at three day intervals and sequentially separated into seven extraction fractions and analyzed for the metals Cu, Cr, Cd, Fe, Ni, and Pb. The seven step sequential extraction was for metal species: (a) soluble, (b) displaced-exchangeable, (c) adsorbed, (d) organic, (e) carbonate, (f) sulfide-acid soluble, and (g) residual. At the 35/sup 0/C digestion temperature the distribution of metals in the extractant fractions between the raw and anaerobically digested sludges were significantly different. For the 45/sup 0/C digestion temperature the distribution of metals in the raw and digested sludge extractant fractions were different and different compared to the 35/sup 0/C system. The 45/sup 0/C raw sludge showed greater percent metal in the organic and sulfide-acid soluble fraction than the digested sludge. At the 45/sup 0/C anaerobic digestion temperature the percent of raw sludge solids loading in the digester had a greater effect on changes in metal extractability and proposed metal species than the 35/sup 0/C.

  18. Bioaccumulation of heavy metals in macroinvertebrates living in stormwater wetlands

    SciTech Connect (OSTI)

    Karouna, N.K.; Sparling, D.W.

    1995-12-31

    The design of stormwater wetlands and ponds as wildlife habitats has prompted concern over the potential uptake of runoff contaminants by aquatic fauna. Stormwater wetlands provide a diverse array of habitat for aquatic macroinvertebrates. The importance of macroinvertebrates in aquatic communities has been well documented. Aquatic macroinvertebrates also serve as a major food source of many aquatic vertebrates, including fish and birds. The objectives of the study were to: (1) examine the responses of the macroinvertebrate community to water and sediment concentrations of heavy metals, and other water quality parameters; (2) determine whether macroinvertebrates living in stormwater wetlands bioaccumulate significant concentrations of heavy metals; (3) relate the concentrations of heavy metals in sediment, water and macroinvertebrates to land use in the surrounding watershed; (4) determine sediment and water toxicity to macroinvertebrates. Twenty stormwater wetlands, representing four land uses commercial, residential, highway and control, were monitored in this study. Water quality parameters, including pH, DO, turbidity, conductivity, hardness and metal concentrations were monitored bi-weekly for six months. Sediment samples were collected three times during the same period. Macroinvertebrate communities were sampled during alternate weeks after water collections. Ten-day sediment bioassays were conducted using the amphipod Hyalella azteca. Preliminary data analyses have indicated no significant difference in sediment and water metal concentrations between land uses. However, Zn concentrations in macroinvertebrates were significantly higher (p < 0.05) in wetlands serving commercial watersheds than in those serving the remaining three land uses. No differences have been detected in composition of invertebrate communities due to land use category.

  19. EXAFS of heavy metal coordination in acid mine drainage sediments

    SciTech Connect (OSTI)

    Carroll, S.; O`Day, P.; Waychunas, G.; Phillips, B.

    1995-12-01

    We use extended x-ray adsorption fine structure (EXAFS) spectroscopy to examine the chemical environment of zinc (1-2 wt. %), lead (300-600 ppm) and cadmium (50-200 ppm) in complex acid mine drainage sediments from the Tri-State Mining District (KS, MO, OK). The sediments in streams draining tailings piles and open mine shafts are dominated by quartz or amorphous iron hydroxides; accessory minerals include calcite. The bulk water chemistry is buffered by the limestone geology and is undersaturated with respect to pure heavy metal carbonates and hydroxides. EXAFS spectra of the sediment samples were taken at SSRL with a fluorescence detector at low temperature ({approximately}10 K). Heavy metals do not form pure carbonate or hydroxide phases, nor do they appear to sorb to quartz surfaces. In sediments near the mine source, the metals are present primarily as sulfides, the original host mineral. With increasing distance from the source, second-neighbor backscattering from Fe indicates that the metals leached from the sulfides are taken up with amorphous iron hydroxides.

  20. Removal of metals from heavy oils with phosphorus - Alumina catalysts

    SciTech Connect (OSTI)

    Kukes, S.G.; Parrott, S.L.; Gardner, L.E. )

    1987-04-01

    Earlier it was found that various oil-soluble phosphorous compounds were active for vanadium removal from different crude oils. The phosphorous compounds preferentially reacted with low molecular weight vanadium species in the resin fraction and therefore the highest rate of vanadium removal was observed when the asphaltene fraction was partially or completely removed. Phosphorous compounds promoted the rate of vanadium removal during hydroprocessing over alumina in a trickle bed reactor. Some metal phosphates were prepared and tested for demetallization activity. Several mixed metal phosphates, such as Cr-Zr, Ni-Zr, Cu-Zr, V-Co-Zr, Fe-Co-Zr, Ni-Co-Zr, etc., exhibited high activity for both vanadium and nickel removal. These catalysts were found to possess HDM activity and activity maintenance comparable to conventional hydrotreating catalysts available commercially. The vanadium removal selectivity of the mixed metal phosphates was similar to that of the commercial catalyst, but much lower than that observed earlier for oil soluble phosphorous compounds. Since the lack of high vanadium selectivity for the mixed metal phosphates could be due to their transition metal component, they investigated the hydroprocessing of heavy oils over aluminas impregnated with different inorganic phosphorous compounds.

  1. Assessment of heavy metals in seawater and fish tissues at Pulau Indah,

    Office of Scientific and Technical Information (OSTI)

    Selangor, Malaysia (Journal Article) | SciTech Connect Assessment of heavy metals in seawater and fish tissues at Pulau Indah, Selangor, Malaysia Citation Details In-Document Search Title: Assessment of heavy metals in seawater and fish tissues at Pulau Indah, Selangor, Malaysia This study focuses on the levels of heavy metals in seawater and selected fish tissue at Pulau Indah, Selangor, Malaysia. Pulau Indah primarily contains Westport (Malaysia's major port), and a host of full scales

  2. Method of removal of heavy metal from molten salt in IFR fuel pyroprocessing

    DOE Patents [OSTI]

    Gay, Eddie C.

    1995-01-01

    An electrochemical method of separating heavy metal values from a radioactive molten salt including Li halide at temperatures of about 500.degree. C. The method comprises positioning a solid Li--Cd alloy anode in the molten salt containing the heavy metal values, positioning a Cd-containing cathode or a solid cathode positioned above a catch crucible in the molten salt to recover the heavy metal values, establishing a voltage drop between the anode and the cathode to deposit material at the cathode to reduce the concentration of heavy metals in the salt, and controlling the deposition rate at the cathode by controlling the current between the anode and cathode.

  3. Attrition resistant catalysts and sorbents based on heavy metal poisoned FCC catalysts

    DOE Patents [OSTI]

    Gangwal, Santosh (Cary, NC); Jothimurugesan, Kandaswamy (Hampton, VA)

    1999-01-01

    A heavy metal poisoned, spent FCC catalyst is treated by chemically impregnating the poisoned catalyst with a new catalytic metal or metal salt to provide an attrition resistant catalyst or sorbent for a different catalytic or absorption processes, such as catalysts for Fischer-Tropsh Synthesis, and sorbents for removal of sulfur gasses from fuel gases and flue-gases. The heavy metal contaminated FCC catalyst is directly used as a support for preparing catalysts having new catalytic properties and sorbents having new sorbent properties, without removing or "passivating" the heavy metals on the spent FCC catalyst as an intermediate step.

  4. Attrition resistant catalysts and sorbents based on heavy metal poisoned FCC catalysts

    DOE Patents [OSTI]

    Gangwal, S.; Jothimurugesan, K.

    1999-07-27

    A heavy metal poisoned, spent FCC catalyst is treated by chemically impregnating the poisoned catalyst with a new catalytic metal or metal salt to provide an attrition resistant catalyst or sorbent for a different catalytic or absorption process, such as catalysts for Fischer-Tropsh Synthesis, and sorbents for removal of sulfur gases from fuel gases and flue-gases. The heavy metal contaminated FCC catalyst is directly used as a support for preparing catalysts having new catalytic properties and sorbents having new sorbent properties, without removing or passivating the heavy metals on the spent FCC catalyst as an intermediate step.

  5. Development of protein based bioremediation and drugs for heavy metal toxicity

    SciTech Connect (OSTI)

    Opella, Stanley J.

    2001-09-18

    Structural studies were performed on several proteins of the bacterial detoxification system. These proteins are responsible for binding (MerP) and transport of heavy metals, including mercury, across membranes. The structural information obtained from NMR experiments provides insight into the selectivity and sequestration processes towards heavy metal toxins.

  6. Mobility of Source Zone Heavy Metals and Radionuclides: The Mixed Roles of

    Office of Scientific and Technical Information (OSTI)

    Fermentative Activity on Fate and Transport of U and Cr (Technical Report) | SciTech Connect Mobility of Source Zone Heavy Metals and Radionuclides: The Mixed Roles of Fermentative Activity on Fate and Transport of U and Cr Citation Details In-Document Search Title: Mobility of Source Zone Heavy Metals and Radionuclides: The Mixed Roles of Fermentative Activity on Fate and Transport of U and Cr Predicting the potential migration of metals and radionuclides from waste pits and trenches will

  7. Process for sodium sulfide/ferrous sulfate treatment of hexavalent chromium and other heavy metals

    DOE Patents [OSTI]

    Suciu, Dan F. (Idaho Falls, ID); Wikoff, Penny M. (Idaho Falls, ID); Beller, John M. (Idaho Falls, ID); Carpenter, Charles J. (Lynn Haven, FL)

    1991-01-01

    433 of 9384 ) United States Patent 5,000,859 Suciu , et al. March 19, 1991 Process for sodium sulfide/ferrous sulfate treatment of hexavalent chromium and other heavy metals

  8. Method of removal of heavy metal from molten salt in IFR fuel pyroprocessing

    DOE Patents [OSTI]

    Gay, E.C.

    1995-10-03

    An electrochemical method is described for separating heavy metal values from a radioactive molten salt including Li halide at temperatures of about 500 C. The method comprises positioning a solid Li--Cd alloy anode in the molten salt containing the heavy metal values, positioning a Cd-containing cathode or a solid cathode positioned above a catch crucible in the molten salt to recover the heavy metal values, establishing a voltage drop between the anode and the cathode to deposit material at the cathode to reduce the concentration of heavy metals in the salt, and controlling the deposition rate at the cathode by controlling the current between the anode and cathode. 3 figs.

  9. Process for sodium sulfide/ferrous sulfate treatment of hexavalent chromium and other heavy metals

    DOE Patents [OSTI]

    Suciu, Dan F.; Wikoff, Penny M.; Beller, John M.; Carpenter, Charles J.

    1991-01-01

    433 of 9384 ) United States Patent 5,000,859 Suciu ,   et al. March 19, 1991 Process for sodium sulfide/ferrous sulfate treatment of hexavalent chromium and other heavy metals

  10. Pint-sized plants pack a punch in fight against heavy metals

    SciTech Connect (OSTI)

    Boyd, V.

    1996-05-01

    USDA researchers are experimenting with plants that naturally scavenge heavy metals such as cadmium and zinc from the soil. Known as hyperaccumulators, the plants can store up to 2.5% of their dry weight in heavy metals in leaves without yield reductions. They can be grown, harvested, and dried. The dried material is then burned, and the metal ore can be recovered. As well as discussing the history of hyperaccumulators, this article focuses on the plant pennycress and work on improving its metal uptake.

  11. Comparison of leaching characteristics of heavy metals from bottom and fly ashes in Korea and Japan

    SciTech Connect (OSTI)

    Shim, Young-Sook; Rhee, Seung-Whee; Lee, Woo-Keun . E-mail: woklee@kangwon.ac.kr

    2005-07-01

    The objective of this research was to compare the leaching characteristics of heavy metals such as cadmium, chromium, copper, nickel, lead, etc., in Korean and Japanese municipal solid waste incineration (MSWI) ash. The rate of leaching of heavy metal was measured by KSLT and JTL-13, and the amount of heavy metals leached was compared with the metal content in each waste component. Finally, bio-availability testing was performed to assess the risks associated with heavy metals leached from bottom ash and fly ash. From the results, the value of neutralization ability in Japanese fly ash was four times higher than that in Korean fly ash. The reason was the difference in the content of Ca(OH){sub 2} in fly ash. The amount of lead leached exceeded the regulatory level in both Japanese and Korean fly ash. The rate of leaching was relatively low in ash with a pH in the range of 6-10. The bio-availability test in fly ash demonstrated that the amount of heavy metals leached was Pb > Cd > Cr, but the order was changed to Pb > Cr > Cd in the bottom ash. The leaching concentration of lead exceeded the Japanese risk level in all fly ashes from the two countries, but the leaching concentration of cadmium exceeded the regulatory level in Korean fly ash only.

  12. Process for the enhanced capture of heavy metal emissions

    DOE Patents [OSTI]

    Biswas, Pratim; Wu, Chang-Yu

    2001-01-01

    This invention is directed to a process for forming a sorbent-metal complex. The process includes oxidizing a sorbent precursor and contacting the sorbent precursor with a metallic species. The process further includes chemically reacting the sorbent precursor and the metallic species, thereby forming a sorbent-metal complex. In one particular aspect of the invention, at least a portion of the sorbent precursor is transformed into sorbent particles during the oxidation step. These sorbent particles then are contacted with the metallic species and chemically reacted with the metallic species, thereby forming a sorbent-metal complex. Another aspect of the invention is directed to a process for forming a sorbent metal complex in a combustion system. The process includes introducing a sorbent precursor into a combustion system and subjecting the sorbent precursor to an elevated temperature sufficient to oxidize the sorbent precursor and transform the sorbent precursor into sorbent particles. The process further includes contacting the sorbent particles with a metallic species and exposing the sorbent particles and the metallic species to a complex-forming temperature whereby the metallic species reacts with the sorbent particles thereby forming a sorbent-metal complex under UV irradiation.

  13. Nonisothermal particle modeling of municipal solid waste combustion with heavy metal vaporization

    SciTech Connect (OSTI)

    Mazza, G.; Falcoz, Q.; Gauthier, D.; Flamant, G.; Soria, J.

    2010-12-15

    A particulate model was developed for municipal solid-waste incineration in a fluidized bed combining solid-waste-particle combustion and heavy metal vaporization from the burning particles. Based on a simpler, isothermal version presented previously, this model combines an asymptotic-combustion model for carbonaceous-solid combustion and a shrinking-core model to describe the heavy metal vaporization phenomenon, in which the particle is now considered nonisothermal. A parametric study is presented that shows the influence of temperature on the global metal-vaporization process. The simulation results are compared to experimental data obtained with a lab-scale fluid bed incinerator and to the results of the simpler isothermal model. It is shown that conduction in the particle strongly affects the variation of the vaporization rate with time and that the present version of the model well fits both the shape of the plots and the maximum heavy metal vaporization rates for all bed temperatures. (author)

  14. Method for fixating sludges and soils contaminated with mercury and other heavy metals

    DOE Patents [OSTI]

    Broderick, Thomas E.; Roth, Rachel L.; Carlson, Allan L.

    2005-06-28

    The invention relates to a method, composition and apparatus for stabilizing mercury and other heavy metals present in a particulate material such that the metals will not leach from the particulate material. The method generally involves the application of a metal reagent, a sulfur-containing compound, and the addition of oxygen to the particulate material, either through agitation, sparging or the addition of an oxygen-containing compound.

  15. A review of the global emissions, transport and effects of heavy metals in the environment

    SciTech Connect (OSTI)

    Friedman, J.R.; Ashton, W.B.; Rapoport, R.D.

    1993-06-01

    The purpose of this report is to describe the current state of knowledge regarding the sources and quantities of heavy metal emissions, their transport and fate, their potential health and environmental effects, and strategies to control them. The approach is to review the literature on this topic and to consult with experts in the field. Ongoing research activities and research needs are discussed. Estimates of global anthropogenic and natural emissions indicate that anthropogenic emissions are responsible for most of the heavy metals released into the atmosphere and that industrial activities have had a significant impact on the global cycling of trace metals. The largest anthropogenic sources of trace metals are coal combustion and the nonferrous metal industry. Atmospheric deposition is an important pathway by which trace metals enter the environment. Atmospheric deposition varies according to the solubility of the element and the length of time it resides in the atmosphere. Evidence suggests that deposition is influenced by other chemicals in the atmosphere, such as ozone and sulfur dioxide. Trace metals also enter the environment through leaching. Existing emissions-control technologies such as electrostatic precipitators, baghouses, and scrubbers are designed to remove other particulates from the flue gas of coal-fired power plants and are only partially effective at removing heavy metals. Emerging technologies such as flue gas desulfurization, lignite coke, and fluidized bed combustion could further reduce emissions. 108 refs.

  16. Mobility of Source Zone Heavy Metals and Radionuclides: The Mixed Roles of

    Office of Scientific and Technical Information (OSTI)

    Fermentative Activity on Fate and Transport of U and Cr (Conference) | SciTech Connect Conference: Mobility of Source Zone Heavy Metals and Radionuclides: The Mixed Roles of Fermentative Activity on Fate and Transport of U and Cr Citation Details In-Document Search Title: Mobility of Source Zone Heavy Metals and Radionuclides: The Mixed Roles of Fermentative Activity on Fate and Transport of U and Cr Various U. S. Department of Energy (DOE) low and medium-level radioactive waste sites

  17. Mobility of Source Zone Heavy Metals and Radionuclides: The Mixed Roles of

    Office of Scientific and Technical Information (OSTI)

    Fermentative Activity on Fate and Transport of U and Cr. Final Report (Technical Report) | SciTech Connect Mobility of Source Zone Heavy Metals and Radionuclides: The Mixed Roles of Fermentative Activity on Fate and Transport of U and Cr. Final Report Citation Details In-Document Search Title: Mobility of Source Zone Heavy Metals and Radionuclides: The Mixed Roles of Fermentative Activity on Fate and Transport of U and Cr. Final Report Various U. S. Department of Energy (DOE) low and

  18. Studies Concerning the Accumulation of Minerals and Heavy Metals in Fruiting Bodies of Wild Mushrooms

    SciTech Connect (OSTI)

    Stihi, Claudia; Radulescu, Cristiana; Gheboianu, Anca; Bancuta, Iulian; Popescu, Ion V.; Busuioc, Gabriela

    2011-10-03

    The minerals and heavy metals play an important role in the metabolic processes, during the growth and development of mushrooms, when they are available in appreciable concentration. In this work the concentrations of Cr, Mn, Fe, Ni, Cu, Zn, Se, Cd and Pb were analyzed using the Flame Atomic Absorption spectrometry (FAAS) together with Energy Dispersive X-ray Fluorescence spectrometry (EDXRF) in 3 wild mushrooms species and their growing substrate, collected from various forestry fields in Dambovita County, Romania. The analyzed mushrooms were: Amanita phalloides, Amanita rubescens and Armillariella mellea. The accumulation coefficients were calculated to assess the mobility of minerals and heavy metals from substrate to mushrooms [1].

  19. Heavy metal distribution in sediments from Calabar River, southeastern Nigeria

    SciTech Connect (OSTI)

    Ntekim, E.E.U.; Ekwere, S.J.; Ukpong, E.E.

    1993-08-01

    The concentration and areal distribution of selected metals (Pb, Zn, Cu, Cd, Ni, Fe, and Cr) in the sediments of the Calabar River were studied to determine the extent of anthropogenic input and to estimate the effects of dumping industrial waste materials into the river. The concentrations of Pb, Zn, and Cu indicate relatively moderate pollution mainly on the left-hand side of the river while Ni, Cr, Co, Cd, and Fe levels are below values found to have adverse effects on the lives of marine biota. High metal contents are found close to industrial establishments and so enhanced metal concentrations are related to industrial sewage and metal leaching from garbage and solid waste dumps. 15 refs., 6 figs., 5 tabs.

  20. Cone Penetrometer for Subsurface Heavy Metals Detection. Semiannual report, November 1, 1996--March 31, 1997

    SciTech Connect (OSTI)

    Grisanti, Ames A.; Timpe, Ronald C.; Foster, H.J.; Eylands, Kurt E.; Crocker, Charlene R.

    1997-12-31

    Surface and subsurface contamination of soils by heavy metals, including Pb, Cr, Cu, Zn, and Cd, has become an area of concern for many industrial and government organizations (1). Conventional sampling and analysis techniques for soil provide a high degree of sensitivity and selectivity for individual analytes. However, obtaining a representative sampling and analysis from a particular site using conventional techniques is time consuming and costly (2). Additionally, conventional methods are difficult to implement in the field for in situ and/or real-time applications. Therefore, there is a need for characterization and monitoring techniques for heavy metals in soils which allow cost-effective, rapid, in situ measurements. Laser-induced breakdown spectroscopy (LIBS) has been used to successfully measure metals content in a variety of matrices (3-15) including soil (16,17). Under the Department of Energy (DOE) Federal Energy Technology Center (FETC) Industry Program, Science {ampersand} Engineering Associates (SEA) is developing a subsurface cone penetrometer (CPT) probe for heavy metals detection that employs LIBS (18). The LIES-CPT unit is to be applied to in situ, real-time sampling and analysis of heavy metals in soil. As part of its contract with DOE FETC, SEA is scheduled to field test its LIBS-CPT system in September 1997.

  1. Thermal and hydrometallurgical recovery methods of heavy metals from municipal solid waste fly ash

    SciTech Connect (OSTI)

    Kubo?ov, L.

    2013-11-15

    Highlights: MSW fly ash was thermally and hydrometallurgically treated to remove heavy metals. More than 90% of easy volatile heavy metals (Cd and Pb) were removed thermally. More than 90% of Cd, Cr, Cu an Zn were removed by alkaline acid leaching. The best results were obtained for the solution of 3 M NaOH and 2 M H{sub 2}SO{sub 4}. - Abstract: Heavy metals in fly ash from municipal solid waste incinerators are present in high concentrations. Therefore fly ash must be treated as a hazardous material. On the other hand, it may be a potential source of heavy metals. Zinc, lead, cadmium, and copper can be relatively easily removed during the thermal treatment of fly ash, e.g. in the form of chlorides. In return, wet extraction methods could provide promising results for these elements including chromium and nickel. The aim of this study was to investigate and compare thermal and hydrometallurgical treatment of municipal solid waste fly ash. Thermal treatment of fly ash was performed in a rotary reactor at temperatures between 950 and 1050 C and in a muffle oven at temperatures from 500 to 1200 C. The removal more than 90% was reached by easy volatile heavy metals such as cadmium and lead and also by copper, however at higher temperature in the muffle oven. The alkaline (sodium hydroxide) and acid (sulphuric acid) leaching of the fly ash was carried out while the influence of temperature, time, concentration, and liquid/solid ratio were investigated. The combination of alkaline-acidic leaching enhanced the removal of, namely, zinc, chromium and nickel.

  2. Removal of heavy metal ions from oil shale beneficiation process water by ferrite process

    SciTech Connect (OSTI)

    Mehta, R.K.; Zhang, L.; Lamont, W.E.; Schultz, C.W.

    1991-12-31

    The ferrite process is an established technique for removing heavy metals from waste water. Because the process water resulting from oil shale beneficiation falls into the category of industrial waste water, it is anticipated that this process may turn out to be a potential viable treatment for oil shale beneficiation process water containing many heave metal ions. The process is chemoremedial because not only effluent water comply with quality standards, but harmful heavy metals are converted into a valuable, chemically stable by-product known as ferrite. These spinel ferrites have magnetic properties, and therefore can be use in applications such as magnetic marker, ferrofluid, microwave absorbing and scavenging material. Experimental results from this process are presented along with results of treatment technique such as sulfide precipitation.

  3. Removal of heavy metal ions from oil shale beneficiation process water by ferrite process

    SciTech Connect (OSTI)

    Mehta, R.K.; Zhang, L.; Lamont, W.E.; Schultz, C.W. . Mineral Resources Inst.)

    1991-01-01

    The ferrite process is an established technique for removing heavy metals from waste water. Because the process water resulting from oil shale beneficiation falls into the category of industrial waste water, it is anticipated that this process may turn out to be a potential viable treatment for oil shale beneficiation process water containing many heave metal ions. The process is chemoremedial because not only effluent water comply with quality standards, but harmful heavy metals are converted into a valuable, chemically stable by-product known as ferrite. These spinel ferrites have magnetic properties, and therefore can be use in applications such as magnetic marker, ferrofluid, microwave absorbing and scavenging material. Experimental results from this process are presented along with results of treatment technique such as sulfide precipitation.

  4. Method for removing heavy metal and nitrogen oxides from flue gas, device for removing heavy metal and nitrogen oxides from flue gas

    SciTech Connect (OSTI)

    Huang, Hann-Sheng; Livengood, Charles David

    1997-12-01

    A method for the simultaneous removal of oxides and heavy metals from a fluid is provided comprising combining the fluid with compounds containing alkali and sulfur to create a mixture; spray drying the mixture to create a vapor phase and a solid phase; and isolating the vapor phase from the solid phase. A device is also provided comprising a means for spray-drying flue gas with alkali-sulfide containing liquor at a temperature sufficient to cause the flue gas to react with the compounds so as to create a gaseous fraction and a solid fraction and a means for directing the gaseous fraction to a fabric filter.

  5. Means for obtaining a metal ion beam from a heavy-ion cyclotron source

    DOE Patents [OSTI]

    Hudson, E.D.; Mallory, M.L.

    1975-08-01

    A description is given of a modification to a cyclotron ion source used in producing a high intensity metal ion beam. A small amount of an inert support gas maintains the usual plasma arc, except that it is necessary for the support gas to have a heavy mass, e.g., xenon or krypton as opposed to neon. A plate, fabricated from the metal (or anything that can be sputtered) to be ionized, is mounted on the back wall of the ion source arc chamber and is bombarded by returning energetic low-charged gas ions that fail to cross the initial accelerating gap between the ion source and the accelerating electrode. Some of the atoms that are dislodged from the plate by the returning gas ions become ionized and are extracted as a useful beam of heavy ions. (auth)

  6. Qualitative evaluation of heavy metals in soils using portable XRF instruments

    SciTech Connect (OSTI)

    McCain, R.G.

    1993-10-01

    Portable isotope-source energy dispersive x-ray fluorescence (XRF) analyzers can provide rapid on site screening for heavy metals in soils. Their use generally involves empirical calibration to a suite of representative soil samples spiked with a range of concentrations of the analytes of interest. In most cases, only a limited number of analytes can be measured with this approach, because of constraints imposed by the operational software and costs associated with preparing the calibration suite. A simple approach is described that provides a qualitative indication of anomalous concentrations of heavy metals based on numeric comparison of gross count rates to background values. This approach can rapidly identify contaminated soils and does not depend on a suite of calibration samples. Direct measurements can be made to rapidly map soil contamination without sample collection, and the method can also be applied to other surfaces such as concrete.

  7. Heavy-metal contamination on training ranges at the Grafenwoehr Training Area, Germany

    SciTech Connect (OSTI)

    Zellmer, S.D.; Schneider, J.F.

    1993-05-01

    Large quantities of lead and other heavy metals are deposited in the environment of weapons ranges during training exercises. This study was conducted to determine the type, degree, and extent of heavy-metal contamination on selected handgun, rifle, and hand-grenade ranges at Grafenwoehr Training Area, Germany. Soil, vegetation, and surface-water samples were collected and analyzed using the inductively-coupled plasma atomic-emission spectroscopy (ICP-AES) method and the toxic characterization leaching procedure (TCLP). The ICP-AES results show that above-normal levels of lead and copper are in the surface soil at the handgun range, high concentrations of lead and copper are in the berm and soil surface at the rifle range, and elevated levels of cadmium and above-normal concentrations of arsenic, copper, and zinc are present in the surface soil at the hand-grenade range. The TCLP results show that surface soils can be considered hazardous waste because of lead content at the rifle range and because of cadmium concentration at the hand-grenade range. Vegetation at the handgun and rifle ranges has above-normal concentrations of lead. At the hand-grenade range, both vegetation and surface water have high levels of cadmium. A hand-held X-ray fluorescence (XRF) spectrum analyzer was used to measure lead concentrations in soils in a field test of the method. Comparison of XRF readings with ICP-AES results for lead indicate that the accuracy and precision of the hand-held XRF unit must improve before the unit can be used as more than a screening tool. Results of this study show that heavy-metal contamination at all three ranges is limited to the surface soil; heavy metals are not being leached into the soil profile or transported into adjacent areas.

  8. Removal of radioactive materials and heavy metals from water using magnetic resin

    DOE Patents [OSTI]

    Kochen, R.L.; Navratil, J.D.

    1997-01-21

    Magnetic polymer resins capable of efficient removal of actinides and heavy metals from contaminated water are disclosed together with methods for making, using, and regenerating them. The resins comprise polyamine-epichlorohydrin resin beads with ferrites attached to the surfaces of the beads. Markedly improved water decontamination is demonstrated using these magnetic polymer resins of the invention in the presence of a magnetic field, as compared with water decontamination methods employing ordinary ion exchange resins or ferrites taken separately. 9 figs.

  9. Removal of radioactive materials and heavy metals from water using magnetic resin

    DOE Patents [OSTI]

    Kochen, Robert L. (Boulder, CO); Navratil, James D. (Simi Valley, CA)

    1997-01-21

    Magnetic polymer resins capable of efficient removal of actinides and heavy metals from contaminated water are disclosed together with methods for making, using, and regenerating them. The resins comprise polyamine-epichlorohydrin resin beads with ferrites attached to the surfaces of the beads. Markedly improved water decontamination is demonstrated using these magnetic polymer resins of the invention in the presence of a magnetic field, as compared with water decontamination methods employing ordinary ion exchange resins or ferrites taken separately.

  10. Fractionation of heavy metals in sludge from anaerobic wastewater stabilization ponds in southern Spain

    SciTech Connect (OSTI)

    Alonso, E.

    2006-07-01

    The analysis of heavy metals is a very important task to assess the potential environmental and health risk associated with the sludge coming from wastewater treatment plants (WWTPs). However, it is necessary to apply sequential extraction techniques to obtain suitable information about their bioavailability or toxicity. In this paper, a sequential extraction scheme according to the Standard, Measurements and Testing Programme of the European Commission was applied to sludge samples collected from ten anaerobic wastewater stabilization ponds (WSPs) located in southern Spain. Al, Cd, Co, Cr, Cu, Fe, Hg, Mn, Mo, Ni, Pb, Ti and Zn were determined in the sludge extracts by inductively coupled plasma atomic emission spectrometry. In relation to current international legislation for the use of sludge for agricultural purposes, none of the metal concentrations exceeded maximum permitted levels. Overall, heavy metals were mainly associated with the two less-available fractions (34% oxidizable metal and 55% residual metal). Only Mn and Zn showed the highest share of the available (exchangeable and reducible) fractions (25-48%)

  11. Assessment of heavy metals in seawater and fish tissues at Pulau Indah, Selangor, Malaysia

    SciTech Connect (OSTI)

    Md Yunus, Sabarina Hamzah, Zaini; Wood, Ab. Khalik; Ahmad

    2015-04-29

    This study focuses on the levels of heavy metals in seawater and selected fish tissue at Pulau Indah, Selangor, Malaysia. Pulau Indah primarily contains Westport (Malaysia’s major port), and a host of full scales factories. Therefore, it is important to monitor the levels of pollution in this water body and the aquatic organisms in the long term effects, due to the human activities in this area. Water samples in this study were taken from 8 locations along the coastal area. The water samples were collected using water sampler and sampling locations were determined using a Global Positioning system (GPS). Similarly, in situ water quality parameters including temperature, dissolve oxygen (DO), salinity, total suspended solid (TSS), pH and turbidity were measured by using portable multi probes meter. Then, the samples were acidified until pH 2 and filtered. Fish samples were purchased from local fisherman along the Pulau Indah coastal area and samples were digested using concentrated nitric acid in wet digestion method. The levels of selected heavy metals in four species of fish and seawater from Pulau Indah coastal area were determined using Inductive Coupled Plasma Mass Spectrometer (ICPMS) after dilution to the samples. In general, the quality of water at Pulau Indah is lower than Malaysia Marine Water Quality Standard except for few locations were higher than the maximum permissible levels. The concentration of heavy metals which are lead (Pb), copper (Cu), zinc (Zn) and uranium (U) in water samples are in the range of 0.36-5.43 µg/L, 75.20-621.58 µg/L, 11.92-30.52 µg/L, and 4.00-4.65 µg/L respectively. While the results of the four selected fish showed the following order of abundance Zn> U> Cu> Pb. Transfer factor (TF) of heavy metals in fish tissue of selected fish species from the water was discussed. However, the observed metal concentration in the sample tissue did not exceed the allowable limit of Malaysian Food Act (1983) and Regulation (1985). Therefore, it is safe for human consumption. Moreover, the pollution levels of these heavy metals were also compared with other studies. This present study can also be used to evaluate the safety dose uptake level of marine biota as well as to monitor environmental health.

  12. Fixation and partitioning of heavy metals in slag after incineration of sewage sludge

    SciTech Connect (OSTI)

    Chen Tao; Yan Bo

    2012-05-15

    Highlights: Black-Right-Pointing-Pointer The contents and partitioning of HMs in slag of sludge incineration were examined. Black-Right-Pointing-Pointer The fixation rate decreases with residential time and finally keeps a constant. Black-Right-Pointing-Pointer Water mass fraction of 55% is optimal for the sediment for Ni, Mn, Zn, Cu and Cr. Black-Right-Pointing-Pointer Water mass fraction of 75% is optimal for the sediment for Pb. Black-Right-Pointing-Pointer We found higher temperature versus lower non-residual fraction except that of Pb. - Abstract: Fixation of heavy metals in the slag produced during incineration of sewage sludge will reduce emission of the metals to the atmosphere and make the incineration process more environmentally friendly. The effects of incineration conditions (incineration temperature 500-1100 Degree-Sign C, furnace residence time 0-60 min, mass fraction of water in the sludge 0-75%) on the fixation rates and species partitioning of Cd, Pb, Cr, Cu, Zn, Mn and Ni in slag were investigated. When the incineration temperature was increased from 500 to 1100 Degree-Sign C, the fixation rate of Cd decreased from 87% to 49%, while the fixation rates of Cu and Mn were stable. The maximum fixation rates for Pb and Zn and for Ni and Cr were reached at 900 and 1100 Degree-Sign C, respectively. The fixation rates of Cu, Ni, Cd, Cr and Zn decreased as the residence time increased. With a 20 min residence time, the fixation rates of Pb and Mn were low. The maximum fixation rates of Ni, Mn, Zn, Cu and Cr were achieved when the mass fraction of water in the sludge was 55%. The fixation rate of Cd decreased as the water mass fraction increased, while the fixation rate of Pb increased. Partitioning analysis of the metals contained in the slag showed that increasing the incineration temperature and residence time promoted complete oxidation of the metals. This reduced the non-residual fractions of the metals, which would lower the bioavailability of the metals. The mass fraction of water in the sludge had little effect on the partitioning of the metals. Correlation analysis indicated that the fixation rates of heavy metals in the sludge and the forms of heavy metals in the incinerator slag could be controlled by optimization of the incineration conditions. These results show how the bioavailability of the metals can be reduced for environmentally friendly disposal of the incinerator slag.

  13. Feasibility/treatability studies for removal of heavy metals from training range soils at the Grafenwoehr Training Area, Germany

    SciTech Connect (OSTI)

    Peters, R.W.

    1995-05-01

    A feasibility/treatability study was performed to investigate the leaching potential of heavy metals (particularly lead) from soils at the Grafenw6hr Training Area (GTA) in Germany. The study included an evaluation of the effectiveness of chelant extraction to remediate the heavy-metal-contarninated soils. Batch shaker tests indicated that ethylenediaminetetraacetic acid (EDTA) (0.01M) was more effective than citric acid (0.01M) at removing cadmium, copper, lead, and zinc. EDTA and citric acid were equally effective in mobilizing chromium and barium from the soil. The batch shaker technique with chelant extraction offers promise as a remediation technique for heavy-metal-contaninated soil at the GTA. Columnar flooding tests conducted as part of the study revealed that deionized water was the least effective leaching solution for mobilization of the heavy metals; the maximum solubilization obtained was 3.72% for cadmium. EDTA (0.05M) achieved the greatest removal of lead (average removal of 17.6%). The difficulty of extraction using deionized water indicates that all of the heavy metals are very tightly bound to the soil; therefore, they are very stable in the GTA soils and do not pose a serious threat to the groundwater system. Columnar flooding probably does not represent a viable remediation technique for in-situ cleanup of heavy-metal-contaminated soils at the GTA.

  14. Heavy metal bioaccumulation in lamb and sheep bred in smelting and mining areas of S. W. Sardinia (Italy)

    SciTech Connect (OSTI)

    Leita, L.; Nobili, M. de ); Enne, G. ); Baldini, M. ); Sequi, P. )

    1991-06-01

    It is widely known that anthropogenic activities strongly contributed to heavy metals contamination of the environment. For this reason, distribution of heavy metals in soils and plants around urban and industrial point sources have been the object of extensive studies. Lesser attention has been given to accumulation of heavy metals in animals bred in these polluted environments, and relatively few works are concerned with the accumulation of heavy metals through the food chain. The aim of this work is to examine the distribution of heavy metals in two contaminated environments, a smelter-refinery and a mine area situated in S.W. Sardinia. The first sampling area is located near one of the most important Pb and Zn smelting-refineries of Europe, and the second near abandoned and working mines. In this study, target organs of sheep and lamb were considered for their heavy metals accumulation. Samples of vegetation were collected throughout the vegetative period and analyzed for their Pb, Zn and Cd content. Winter forage and soil were also sampled.

  15. Separation of heavy metals: Removal from industrial wastewaters and contaminated soil

    SciTech Connect (OSTI)

    Peters, R.W.; Shem, L.

    1993-03-01

    This paper reviews the applicable separation technologies relating to removal of heavy metals from solution and from soils in order to present the state-of-the-art in the field. Each technology is briefly described and typical operating conditions and technology performance are presented. Technologies described include chemical precipitation (including hydroxide, carbonate, or sulfide reagents), coagulation/flocculation, ion exchange, solvent extraction, extraction with chelating agents, complexation, electrochemical operation, cementation, membrane operations, evaporation, adsorption, solidification/stabilization, and vitrification. Several case histories are described, with a focus on waste reduction techniques and remediation of lead-contaminated soils. The paper concludes with a short discussion of important research needs in the field.

  16. Remediation of heavy-metal-contaminated soil using chelant extraction: Feasibility studies

    SciTech Connect (OSTI)

    Peters, R.W.; Miller, G.; Taylor, J.D.; Schneider, J.F.; Zellmer, S.; Edgar, D.E.; Johnson, D.O.

    1993-08-01

    Results are presented of a laboratory investigation conducted to determine the efficacy of using chelating agents to extract heavy metals (Pb, Cd, Cr, Ba, Cu, and Zn) from soil, the primary focus being on the extraction of lead from the soil. Results from the batch-shaker studies and emphasizes the columnar extraction studies are described. The chelating agents studied included ethylenediaminetetraacetic acid (EDTA) and citric acid, in addition to water. Concentrations of the chelants ranged from 0.01 to 0.05 M; the suspension pH was varied between 3 and 8. Results showed that the removal of lead using citric acid and water was somewhat pH-dependent. For the batch-shaker studies, the results indicated that EDTA was more effective at removing Cd, Cu, Pb, and Zn than was citric acid (both present at 0.01 M). EDTA and citric acid were equally effective in mobilizing Cr and Ba from the soil. Heavy metals removal was slightly more effective in the more acidic region (pH {le} 5).

  17. Manganese Doping of Magnetic Iron Oxide Nanoparticles: Tailoring Surface Reactivity for a Regenerable Heavy Metal Sorbent

    SciTech Connect (OSTI)

    Warner, Cynthia L.; Chouyyok, Wilaiwan; Mackie, Katherine E.; Neiner, Doinita; Saraf, Laxmikant; Droubay, Timothy C.; Warner, Marvin G.; Addleman, Raymond S.

    2012-02-28

    A method for tuning the analyte affinity of magnetic, inorganic nanostructured sorbents for heavy metal contaminants is described. The manganese-doped iron oxide nanoparticle sorbents have a remarkably high affinity compared to the precursor material. Sorbent affinity can be tuned toward an analyte of interest simply by adjustment of the dopant quantity. The results show that following the Mn doping process there is a large increase in affinity and capacity for heavy metals (i.e., Co, Ni, Zn, As, Ag, Cd, Hg, and Tl). Capacity measurements were carried out for the removal of cadmium from river water and showed significantly higher loading than the relevant commercial sorbents tested for comparison. The reduction in Cd concentration from 100 ppb spiked river water to 1 ppb (less than the EPA drinking water limit of 5 ppb for Cd) was achieved following treatment with the Mn-doped iron oxide nanoparticles. The Mn-doped iron oxide nanoparticles were able to load 1 ppm of Cd followed by complete stripping and recovery of the Cd with a mild acid wash. The Cd loading and stripping is shown to be consistent through multiple cycles with no loss of sorbent performance.

  18. Metagenomic insights into evolution of a heavy metal-contaminated groundwater microbial community

    SciTech Connect (OSTI)

    Hemme, Christopher; Deng, Ye; Gentry, Terry; Fields, Matthew Wayne; Wu, Liyou; Barua, Soumitra; Barry, Kerry; Green-Tringe, Susannah; Watson, David B; He, Zhili; Hazen, Terry; Tiedje, James M.; Rubin, Edward M.; Zhou, Jizhong

    2010-02-01

    Understanding adaptation of biological communities to environmental change is a central issue in ecology and evolution. Metagenomic analysis of a stressed groundwater microbial community reveals that prolonged exposure to high concentrations of heavy metals, nitric acid and organic solvents (~50 years) has resulted in a massive decrease in species and allelic diversity as well as a significant loss of metabolic diversity. Although the surviving microbial community possesses all metabolic pathways necessary for survival and growth in such an extreme environment, its structure is very simple, primarily composed of clonal denitrifying - and -proteobacterial populations. The resulting community is overabundant in key genes conferring resistance to specific stresses including nitrate, heavy metals and acetone. Evolutionary analysis indicates that lateral gene transfer could have a key function in rapid response and adaptation to environmental contamination. The results presented in this study have important implications in understanding, assessing and predicting the impacts of human-induced activities on microbial communities ranging from human health to agriculture to environmental management, and their responses to environmental changes.

  19. Metagenomic insights into evolution of heavy metal-contaminated groundwater microbial community

    SciTech Connect (OSTI)

    Hemme, C.L.; Deng, Y.; Gentry, T.J.; Fields, M.W.; Wu, L.; Barua, S.; Barry, K.; Green-Tringe, S.; Watson, D.B.; He, Z.; Hazen, T.C.; Tiedje, J.M.; Rubin, E.M.; Zhou, J.

    2010-07-01

    Understanding adaptation of biological communities to environmental change is a central issue in ecology and evolution. Metagenomic analysis of a stressed groundwater microbial community reveals that prolonged exposure to high concentrations of heavy metals, nitric acid and organic solvents ({approx}50 years) has resulted in a massive decrease in species and allelic diversity as well as a significant loss of metabolic diversity. Although the surviving microbial community possesses all metabolic pathways necessary for survival and growth in such an extreme environment, its structure is very simple, primarily composed of clonal denitrifying {gamma}- and {beta}-proteobacterial populations. The resulting community is overabundant in key genes conferring resistance to specific stresses including nitrate, heavy metals and acetone. Evolutionary analysis indicates that lateral gene transfer could have a key function in rapid response and adaptation to environmental contamination. The results presented in this study have important implications in understanding, assessing and predicting the impacts of human-induced activities on microbial communities ranging from human health to agriculture to environmental management, and their responses to environmental changes.

  20. Method for hydrocracking a heavy polynuclear hydrocarbonaceous feedstock in the presence of a molten metal halide catalyst

    DOE Patents [OSTI]

    Gorin, Everett (San Rafael, CA)

    1981-01-01

    A method for hydrocracking a heavy polynuclear hydrocarbonaceous feedstock to produce lighter hydrocarbon fuels by contacting the feedstock with hydrogen in the presence of a molten metal halide catalyst, the method comprising: mixing the feedstock with a heavy naphtha fraction which has an initial boiling point from about 100.degree. to about 160.degree. C. with a boiling point difference between the initial boiling point and the final boiling point of no more than about 50.degree. C. to produce a mixture; thereafter contacting the mixture with partially spent molten metal halide and hydrogen under temperature and pressure conditions so that the temperature is near the critical temperature of the heavy naphtha fraction; separating at least a portion of the heavy naphtha fraction and lighter hydrocarbon fuels from the partially spent molten metal halide, unreacted feedstock and reaction products; thereafter contacting the partially spent molten metal halide, unreacted feedstock and reaction products with hydrogen and fresh molten metal halide in a hydrocracking zone to produce additional lighter hydrocarbon fuels and separating at least a major portion of the lighter hydrocarbon fuels from the spent molten metal halide.

  1. Evolution of heavy metals in municipal solid waste during bio-drying and implications of their subsequent transfer during combustion

    SciTech Connect (OSTI)

    Zhang Dongqing; Zhang Hua; Wu Changlin; Shao Liming; He Pinjing

    2011-08-15

    Bio-drying has been applied to improve the heating value of municipal solid waste (MSW) prior to combustion. In the present study, evolution of heavy metals in MSW during bio-drying and subsequent combustion was studied using one aerobic and two combined hydrolytic-aerobic scenarios. Heavy metals were concentrated during bio-drying and transformed between different metal fractions, namely the exchangeable, carbonate-bound, iron- and manganese-oxides-bound, organic-matter-bound and residual fractions. The amounts of heavy metals per kg of bio-dried MSW transferred into combustion flue gas increased with bio-drying time, primarily due to metals enrichment from organics degradation. Because of their volatility, the partitioning ratios of As and Hg in flue gas remained stable so that bio-drying and heavy metal speciation had little effect on their transfer and partitioning during combustion. In contrast, the partitioning ratios of Pb, Zn and Cu tended to increase after bio-drying, which likely enhanced their release potential during combustion.

  2. Volatilization of heavy metals and radionuclides from soil heated in an induction ``cold`` crucible melter

    SciTech Connect (OSTI)

    Aloy, A.S.; Belov, V.Z.; Trofimenko, A.S. [Khlopin Radium Inst., St. Petersburg (Russian Federation); Dmitriev, S.A.; Stefanovsky, S.V. [SIA Radon, Moscow (Russian Federation); Gombert, D.; Knecht, D.A. [Lockheed Martin Idaho Technologies Co., Idaho Falls, ID (United States)

    1997-12-31

    The behavior of heavy metals and radionuclides during high-temperature treatment is very important for the design and operational capabilities of the off-gas treatment system, as well as for a better understanding of the nature and forms of the secondary waste. In Russia, a process for high-temperature melting in an induction heated cold crucible system is being studied for vitrification of Low Level Waste (LLW) flyash and SYNROC production with simulated high level waste (HLW). This work was done as part of a Department of Energy (DOE) funded research project for thermal treatment of mixed low level waste (LLW). Soil spiked with heavy metals (Cd, Pb) and radionuclides (Cs-137, U-239, Pu-239) was used as a waste surrogate. The soil was melted in an experimental lab-scale system that consisted of a high-frequency generator (1.76 MHz, 60 kW), a cold crucible melter (300 mm high and 90 mm in diameter), a shield box, and an off-gas system. The process temperature was 1,350--1,400 C. Graphite and silicon carbide were used as sacrificial conductive materials to start heating and initial melting of the soil batch. The off-gas system was designed in such a manner that after each experiment, it can be disconnected to collect and analyze all deposits to determine the mass balance. The off-gases were also sampled during an experiment to analyze for hydrogen, NO{sub x}, carbon dioxide, carbon monoxide and chlorine formation. This paper describes distribution and mass balance of metals and radionuclides in various parts of the off-gas system. The leach rate of the solidified blocks identified by the PCT method is also reported.

  3. Placental concentrations of heavy metals in a mother-child cohort

    SciTech Connect (OSTI)

    Amaya, E.; Gil, F.; Freire, C.; National School of Public Health, Oswaldo Cruz Foundation , 21041-210 Rio de Janeiro ; Olmedo, P.; Fernandez-Rodriguez, M.; Fernandez, M.F.; Olea, N.; CIBER de Epidemiologia y Salud Publica

    2013-01-15

    Heavy metals are environmental contaminants with properties known to be toxic for wildlife and humans. Despite strong concerns about their harmful effects, little information is available on intrauterine exposure in humans. The aim of this study was to evaluate prenatal exposure to As, Cd, Cr, Hg, Mn, and Pb and its association with maternal factors in a population-based mother-child cohort in Southern Spain. Between 2000 and 2002, 700 pregnant women were recruited and 137 placentas from the cohort were randomly selected and analyzed for the selected metals by atomic absorption. Maternal sociodemographic and lifestyle factors were obtained by questionnaire after delivery. Bivariate analysis and multivariate linear regression were performed. Cd and Mn concentrations were detected in all placentas, while Cr, Pb, and Hg were found in 98.5%, 35.0%, and 30.7% of samples, respectively. The highest concentrations were observed for Pb (mean: 94.80 ng/g wet weight of placenta), followed by Mn (63.80 ng/g), Cr (63.70 ng/g), Cd (3.45 ng/g), and Hg (0.024 ng/g). Arsenic was not detected in any sample. Gestational age and smoking during pregnancy were associated with placental Cd concentrations, while no factor appeared to influence concentrations of Cr, Hg, Mn, or Pb. In comparison to results of European studies, these concentrations are in a low-intermediate position. Studies are required to investigate the factors contributing to early exposure to heavy metals and to determine how placental transfer of these toxic compounds may affect children's health.

  4. Method and device for electroextraction of heavy metals from technological solutions and wastewater

    DOE Patents [OSTI]

    Khalemsky, Aron Mikhailov; Payusov, Sergei Abramovic; Kelner, Leonid; Jo, Jae

    2005-05-03

    The basic principles of the method for heavy metals electroextraction from technological solutions and wastewater includes pretreating to remove Chromium-6 and high concentrations of heavy metals and periodically treating in a six-electrode bipolar cylindrical electroreactor made of non-conducting material to achieve lower accepted levels of impurities. Six cylindrical steel electrodes form two triode stacks and are fed with three-phase alternating current of commercial frequency (50-60 Hz), which can be pulsed. Each phase of the three-phase current is connected to three electrodes of one triode stack or in parallel to two triode stacks. The parallel connection of three-phase current to two triode stacks is performed so that the same phase of the three phase current is connected in parallel with each two opposite electrodes of six electrodes located along the periphery, or with two adjacent electrodes. A bipolar stationary aluminum electrode is situated in the inter-electrode space. In one of the embodiments, the bipolar electrode is made of a perforated heat-resistant plastic container filled with secondary aluminum and duralumin scrap. In another embodiment, the bipolar electrode of aluminum or duralumin scrap may be made without a perforated container and is placed in the inter-electrode space as a bulk scrap. In this case, to prevent shorts, each of six steel electrodes is placed in isolated perforated plastic shell with holes of 5 mm in diameter. Non-ferrous metals are extracted in a form of ferrite-chromites, and aluminates as well as hydroxyl salts deposited in the inter-electrode space without electrolysis deposits on electrodes. Deposits are separated from solution by known methods of filtration.

  5. Heavy metal leaching from coal fly ash amended container substrates during Syngonium production

    SciTech Connect (OSTI)

    Li, Q.S.; Chen, J.J.; Li, Y.C.

    2008-02-15

    Coal fly ash has been proposed to be an alternative to lime amendment and a nutrient source of container substrates for ornamental plant production. A great concern over this proposed beneficial use, however, is the potential contamination of surface and ground water by heavy metals. In this study, three fly ashes collected from Florida, Michigan, and North Carolina and a commercial dolomite were amended in a basal substrate. The formulated substrates were used to produce Syngonium podophyllum Schott 'Berry Allusion' in 15-cm diameter containers in a shaded greenhouse. Leachates from the containers were collected during the entire six months of plant production and analyzed for heavy metal concentrations. There were no detectable As, Cr, Hg, Pb, and Se in the leachates; Cd and Mo were only detected in few leachate samples. The metals constantly detected were Cu, Mn, Ni, and Zn. The total amounts of Cu, Mn, Ni, and Zn leached during the six-month production period were 95, 210, 44, and 337 {mu} g per container, indicating that such amounts in leachates may contribute little to contamination of surface and ground water. In addition, plant growth indices and fresh and dry weights of S. podophyllum 'Berry Allusion' produced from fly ash and dolomite-amended substrates were comparable except for the plants produced from the substrate amended with fly ash collected from Michigan which had reduced growth indices and fresh and dry weights. Thus, selected fly ashes can be alternatives to commercial dolomites as amendments to container substrates for ornamental plant production. The use of fly ashes as container substrate amendments should represent a new market for the beneficial use of this coal combustion byproduct.

  6. Studies on the content of heavy metals in Aries River using ICP-MS

    SciTech Connect (OSTI)

    Voica, Cezara Kovacs, Melinda Feher, Ioana

    2013-11-13

    Among the industrial branches, the mining industry has always been an important source of environmental pollution, both aesthetically and chemically. Through this paper results of ICP-MS characterization of Aries River Basin are reported. Mining activities from this area has resulted in contamination of environment and its surrounding biota. This is clearly evidenced in analyzed water samples, especially from Baia de Aries site where increased amount of trace elements as Cr, Zn, As, Se, Cd, Pb and U were founded. Also in this site greater amount of rare earth elements was evidenced also. Through monitoring of Aries River from other non-mining area it was observed that the quantitative content of heavy metals was below the maximum permissible levels which made us to conclude that the water table wasn't seriously affected (which possibly might be attributed to the cessation of mining activities in this area from a few years ago)

  7. Reducing volatilization of heavy metals in phosphate-pretreated municipal solid waste incineration fly ash by forming pyromorphite-like minerals

    SciTech Connect (OSTI)

    Sun Ying; Zheng Jianchang; Zou Luquan; Liu Qiang; Zhu Ping; Qian Guangren

    2011-02-15

    This research investigated the feasibility of reducing volatilization of heavy metals (lead, zinc and cadmium) in municipal solid waste incineration (MSWI) fly ash by forming pyromorphite-like minerals via phosphate pre-treatment. To evaluate the evaporation characteristics of three heavy metals from phosphate-pretreated MSWI fly ash, volatilization tests have been performed by means of a dedicated apparatus in the 100-1000 deg. C range. The toxicity characteristic leaching procedure (TCLP) test and BCR sequential extraction procedure were applied to assess phosphate stabilization process. The results showed that the volatilization behavior in phosphate-pretreated MSWI fly ash could be reduced effectively. Pyromorphite-like minerals formed in phosphate-pretreated MSWI fly ash were mainly responsible for the volatilization reduction of heavy metals in MSWI fly ash at higher temperature, due to their chemical fixation and thermal stabilization for heavy metals. The stabilization effects were encouraging for the potential reuse of MSWI fly ash.

  8. Heavy metal inventory and fuel sustainability of recycling TRU in FBR design

    SciTech Connect (OSTI)

    Permana, Sidik; Suzuki, Mitsutoshi; Su'ud, Zaki

    2012-06-06

    Nuclear fuel materials from spent fuel of light water reactors have a potential to be used for destructive devices with very huge energy release or in the same time, it can be utilized as a peaceful energy or civil applications, for generating electricity, desalination of water, medical application and others applications. Several research activities showed some recycled spent fuel can be used as additional fuel loading for increasing fuel breeding capability as well as improving intrinsic aspect of nuclear non-proliferation. The present investigation intends to evaluate the composition of heavy metals inventories and fuel breeding capability in the FBR design based on the loaded fuel of light water reactor (LWR) spent fuel (SF) of 33 GWd/t with 5 years cooling time by adopting depletion code of ORIGEN. Whole core analysis of FBR design is performed by adopting and coupling codes such as SLAROM code, JOINT and CITATION codes. Nuclear data library, JFS-3-J-3.2R which is based on the JENDL 3.2 has been used for nuclear data analysis. JSFR design is the basis design reference which basically adopted 800 days cycle length for 4 batches system. Higher inventories of plutonium of MOX fuel and TRU fuel types at equilibrium composition than initial composition have been shown. Minor actinide (MA) inventory compositions obtain a different inventory trends at equilibrium composition for both fuel types. Higher Inventory of MA is obtained by MOX fuel and less MA inventory for TRU fuel at equilibrium composition than initial composition. Some different MA inventories can be estimated from the different inventory trend of americium (Am). Higher americium inventory for MOX fuel and less americium inventory for TRU fuel at equilibrium condition. Breeding ratio of TRU fuel is relatively higher compared with MOX fuel type. It can be estimated from relatively higher production of Pu-238 (through converted MA) in TRU fuel, and Pu-238 converts through neutron capture to produce Pu-239. Higher breeding ratio of MOX fuel and TRU fuel types at equilibrium condition are estimated from converted fertile material during reactor operation into fissile material of plutonium such as converted uranium fuel (converted U-238 into Pu-239) or additional converted fuel from MA into Pu-238 and changes into Pu-239 by capturing neutron. Loading LWR SF gives better fuel breeding capability and increase inventory of MA for doping material of MOX fuel; however, it requires more supply MA inventory for TRU fuel type.

  9. The concentrations of radionuclides, heavy metals, and poloychlorinated biphenyls in field mice collected from regional background areas. Revision 3

    SciTech Connect (OSTI)

    Fresquez, Philip R.

    2015-12-18

    Field mice are effective indicators of contaminant presence. This paper reports the concentrations of various radionuclides, heavy metals, polychlorinated biphenyls, high explosives, perchlorate, and dioxin/furans in field mice (mostly deer mice) collected from regional background areas in northern New Mexico. These data, represented as the regional statistical reference level (the mean plus three standard deviations = 99% confidence level), are used to compare with data from field mice collected from areas potentially impacted by Laboratory operations, as per the Environmental Surveillance Program at Los Alamos National Laboratory.

  10. Selected heavy metals and other constituents in soil and stormwater runoff at the Interstate 95 interchange near Atlee, Virginia, April 1993--May 1997

    SciTech Connect (OSTI)

    Speiran, G.K.

    1998-12-31

    Concentrations of the heavy metals copper, lead, and zinc, and other constituents, were measured in soil and runoff before and after construction of a stormwater detention basin at the Interstate 95-State Route 656 interchange near Atlee, VA, from April 1993 through May 1997. The spatial and vertical distribution of heavy metals in soil indicate that the paved traffic lanes of the interstate highway are a source of the metals. Concentrations of the metals in soil decrease with increasing soil depth below the ground surface and with increasing distance from the highway lanes. Of the three metals for which samples were analyzed, lead was generally present at the greatest concentration, and copper was at the lowest concentration in the soil.

  11. Accumulation of several heavy metals and lanthanides in mushrooms (Agaricales) from the Chicago region.

    SciTech Connect (OSTI)

    Aruguete, D. M.; Aldstadt, J. H., III; Mueller, G. M.; Environmental Research; Univ. of Chicago; Field Museum of Natural History

    1998-01-01

    This study explored the differences in metal uptake in sporocarps of ectomycorrhizae-forming fungi relative to (1) fungal species; (2) collection location; (3) differential metal uptake and variation within single-species, single-area populations; and (4) mobile metal content of soil substrate for the fungi. In addition, this study examined levels of some of the lanthanides in these mushrooms, as lanthanide uptake in higher fungi has not been quantified to date. In 1995 and 1996, sporocarps from three species of ectomycorrhizal fungi (Amanita flavorubescens, Amanita rubescens, and Russula pectinatoides) were collected from Cowles Bog, Indiana Dunes National Lakeshore (near an industrial area) and the Palos forest preserves (near a residential area). Soil was also collected from the Cowles Bog plots; metals were extracted from the soil, either with local Lake Michigan water or with nitric acid. These two extractions were meant to simulate the natural soil equilibrium concentrations of soluble metals and the maximum possible effects of any fungal chelating chemicals, respectively. An inductively coupled plasma mass spectrometer was used to analyze soil extracts and nitric acid digests of whole sporocarps for the target analytes. The metals found at elevated levels in the mushrooms included four of environmental interest (Ag, Cd, Ba, and Pb) and three lanthanides (La, Ce, and Nd). Significant differences in uptake of metals were observed between A. rubescens and R. pectinatoides, while A. rubescens and A. flavorubescens were not significantly different. With regard to location, more cadmium was found in Cowles Bog collections of A. rubescens, while Palos forest A. rubescens had more of the lanthanides and barium. Significant specimen-to-specimen variation occurred in all populations examined. Correlation analysis between pairs of trace elements within each sporocarp population revealed strong positive correlations between the lanthanides. Sporocarps concentrated more metal than was made available by the lake water extraction of soil and less metal than was made available by the nitric acid extraction of soil.

  12. Radionuclides and heavy metals in rainbow trout from Tsichomo, Nana Ka, Wen Povi, and Pin De Lakes in Santa Clara Canyon

    SciTech Connect (OSTI)

    Fresquez, P.R.; Armstrong, D.R.; Naranjo, L. Jr.

    1998-04-01

    Radionuclide ({sup 3}H, {sup 90}Sr, {sup 137}Cs, {sup 238}Pu, {sup 239}Pu, and total uranium) and heavy metal (Ag, As, Ba, Be, Cd, Cr, Hg, Ni, Pb, Sb, Se, and TI) concentrations were determined in rainbow trout collected from Tsichomo, Nana Ka, Wen Povi, and Pin De lakes in Santa Clara Canyon in 1997. Most radionuclide and heavy metal concentrations in fish collected from these four lakes were within or just above upper limit background concentrations (Abiquiu reservoir), and as a group were statistically (p < 0.05) similar in most parameters to background.

  13. Proceedings of Soil Decon `93: Technology targeting radionuclides and heavy metals

    SciTech Connect (OSTI)

    Not Available

    1993-09-01

    The principal objective for convening this workshop was to exchange ideas and discuss with scientists and engineers methods for removing radionuclides and/or toxic metals from soils. Over the years there have been numerous symposia, conferences, and workshops directed at soil remediation. However, this may be the first where the scope was narrowed to the removal of radionuclides and toxic metals from soils. The intent was to focus on the separation processes controlling the removal of the radionuclide and/or metal from soil. Its purpose was not intended to be a soil washing/leaching workshop, but rather to identify a variety or combination of processes (chemical, physical, and biological) that can be used in concert with the applicable engineering approaches to decontaminate soils of radionuclides and toxic metals. Abstracts and visual aids used by the speakers of the workshop are presented in this document.

  14. Applicability of a field-portable toxic heavy metal detector, using a radioisotope-tagged metalloprotein, to DOE environmental remediation and waste minimization initiatives

    SciTech Connect (OSTI)

    Randles, K.E.; Bragg, D.J.; Bodette, D.E.; Lipinski, R.J.; Luera, T.F.

    1998-08-01

    A system based on the metal-binding kidney protein, metallothionein, bound with a trace quantity of radioactive metal, has been shown to be capable of detecting parts-per-million (ppm) to parts-per-billion (ppb) concentrations of some heavy metals in liquid solution. The main objective of this study was to determine if this type of system has adequate sensitivity and selectivity for application in detecting a number of metallic species of concern to DOE, such as mercury, lead, and chromium. An affinity-displacement study is reported here using the heavy metal radiotracers {sup 65}Zn and {sup 109}Cd bound to metallothionein immobilized on an Affi-Gel 10 filter support. When a heavy metal solution with a greater affinity than the tracer for the protein is poured through the filter the radiotracer is displaced by a mechanism similar to ion exchange. The main objective of this study was to verify previous internal experimental parameters and results, and to determine the specific affinities of metallothionein for the metallic species of most concern to DOE.

  15. Magnetocaloric effect in heavy rare-earth elements doped Fe-based bulk metallic glasses with tunable Curie temperature

    SciTech Connect (OSTI)

    Li, Jiawei; Huo, Juntao; Chang, Chuntao E-mail: dujun@nimte.ac.cn; Du, Juan E-mail: dujun@nimte.ac.cn; Man, Qikui; Wang, Xinmin; Li, Run-Wei; Law, Jiayan

    2014-08-14

    The effects of heavy rare earth (RE) additions on the Curie temperature (T{sub C}) and magnetocaloric effect of the Fe-RE-B-Nb (RE = Gd, Dy and Ho) bulk metallic glasses were studied. The type of dopping RE element and its concentration can easily tune T{sub C} in a large temperature range of 120 K without significantly decreasing the magnetic entropy change (ΔS{sub M}) and refrigerant capacity (RC) of the alloys. The observed values of ΔS{sub M} and RC of these alloys compare favorably with those of recently reported Fe-based metallic glasses with enhanced RC compared to Gd{sub 5}Ge{sub 1.9}Si{sub 2}Fe{sub 0.1}. The tunable T{sub C} and large glass-forming ability of these RE doped Fe-based bulk metallic glasses can be used in a wide temperature range with the final required shapes.

  16. Mobility of Source Zone Heavy Metals and Radionuclides: The Mixed Roles of Fermentative Activity on Fate and Transport of U and Cr

    Office of Scientific and Technical Information (OSTI)

    Mobility of Source Zone Heavy Metals and Radionuclides: The Mixed Roles of Fermentative Activity on Fate and Transport of U and Cr William Apel (INL), Brent Peyton (MSU), Robin Gerlach (MSU), Brady Lee (INL) 1. Research Objectives: Predicting the potential migration of metals and radionuclides from waste pits and trenches will require understanding the effects of carbon and electron flow through these environments. Important aspects of this flow include the physiological activity of cellulolytic

  17. Heavy metals in fish from the Aleutians: Interspecific and locational differences

    SciTech Connect (OSTI)

    Burger, Joanna; Gochfeld, Michael; Jeitner, Christian; Pittfield, Taryn; Donio, Mark

    2014-05-01

    The objectives of this study were to examine levels of arsenic, cadmium, lead, mercury and selenium in edible tissue of seven species of marine fish collected from several Aleutian islands (in 2004) to determine: (1) interspecific differences, (2) locational differences (among Aleutian Islands), (3) size-related differences in any metal levels within a species, and (4) potential risk to the fish or to predators on the fish, including humans. We also compared metals levels to those of three other fish species previously examined in detail, as well as examining metals in the edible tissue of octopus (Octopus dofleini). Octopus did not have the highest levels of any metal. There were significant interspecific differences in all metal levels among the fish species, although the differences were less than an order of magnitude, except for arsenic (mean of 19,500 ppb in Flathead sole, Hippoglossoides elassodon). Significant intraisland variation occurred among the four sites on Amchitka, but there was not a consistent pattern. There were significant interisland differences for some metals and species. Mercury levels increased significantly with size for several species; lead increased significantly for only one fish species; and cadmium and selenium decreased significantly with size for halibut (Hippoglossus stenolepis). The Alaskan Department of Health and Social Services supports unrestricted consumption of most Alaskan fish species for all people, including pregnant women. Most mean metal concentrations were well below the levels known to adversely affect the fish themselves, or predators that consume them (including humans), except for mercury in three fish species (mean levels just below 0.3 ppm), and arsenic in two fish species. However, even at low mercury levels, people who consume fish almost daily will exceed guideline values from the Centers for Disease Control and the Environmental Protection Agency. - Highlights: • Cadmium, lead, mercury and selenium levels differed among 10 fish species from the Aleutians. • Mean Arsenic was as high as 19,500 ppb (flathead sole, Hippoglossoides elassodon). • Mercury levels increased significantly with fish size for several species. • Metal levels were generally below adverse effects levels for fish and their predators. • Mercury and arsenic might pose a risk to human consumers, and require further examination.

  18. Magnetism and superconductivity driven by identical 4f states in a heavy-fermion metal

    SciTech Connect (OSTI)

    Thompson, Joe E; Nair, S; Stockert, O; Witte, U; Nicklas, M; Schedler, R; Bianchi, A; Fisk, Z; Wirth, S; Steglich, K

    2009-01-01

    The apparently inimical relationship between magnetism and superconductivity has come under increasing scrutiny in a wide range of material classes, where the free energy landscape conspires to bring them in close proximity to each other. Particularly enigmatic is the case when these phases microscopically interpenetrate, though the manner in which this can be accomplished remains to be fully comprehended. Here, we present combined measurements of elastic neutron scattering, magnetotransport, and heat capacity on a prototypical heavy fermion system, in which antiferromagnetism and superconductivity are observed. Monitoring the response of these states to the presence of the other, as well as to external thermal and magnetic perturbations, points to the possibility that they emerge from different parts of the Fermi surface. Therefore, a single 4f state could be both localized and itinerant, thus accounting for the coexistence of magnetism and superconductivity.

  19. Determining heavy metals in spent compact fluorescent lamps (CFLs) and their waste management challenges: Some strategies for improving current conditions

    SciTech Connect (OSTI)

    Taghipour, Hassan; Amjad, Zahra; Jafarabadi, Mohamad Asghari; Gholampour, Akbar; Norouz, Prviz

    2014-07-15

    Highlights: • Heavy metals in spent compact fluorescent lamps (CFLs) determined. • Current waste management condition of CFLs in Iran assessed. • Currently, waste of CFLs is disposed by municipal waste stream in waste landfills. • We propose extended producer responsibility (EPR) for CFLs waste management. - Abstract: From environmental viewpoint, the most important advantage of compact fluorescent lamps (CFLs) is reduction of green house gas emissions. But their significant disadvantage is disposal of spent lamps because of containing a few milligrams of toxic metals, especially mercury and lead. For a successful implementation of any waste management plan, availability of sufficient and accurate information on quantities and compositions of the generated waste and current management conditions is a fundamental prerequisite. In this study, CFLs were selected among 20 different brands in Iran. Content of heavy metals including mercury, lead, nickel, arsenic and chromium was determined by inductive coupled plasma (ICP). Two cities, Tehran and Tabriz, were selected for assessing the current waste management condition of CFLs. The study found that waste generation amount of CFLs in the country was about 159.80, 183.82 and 153.75 million per year in 2010, 2011 and 2012, respectively. Waste generation rate of CFLs in Iran was determined to be 2.05 per person in 2012. The average amount of mercury, lead, nickel, arsenic and chromium was 0.417, 2.33, 0.064, 0.056 and 0.012 mg per lamp, respectively. Currently, waste of CFLs is disposed by municipal waste stream in waste landfills. For improving the current conditions, we propose by considering the successful experience of extended producer responsibility (EPR) in other electronic waste management. The EPR program with advanced recycling fee (ARF) is implemented for collecting and then recycling CFLs. For encouraging consumers to take the spent CFLs back at the end of the products’ useful life, a proportion of ARF (for example, 50%) can be refunded. On the other hand, the government and Environmental Protection Agency should support and encourage recycling companies of CFLs both technically and financially in the first place.

  20. WasteWater Treatment And Heavy Metals Removal In The A-01 Constructed Wetland 2003 Report

    SciTech Connect (OSTI)

    ANNA, KNOX

    2004-08-01

    The A-01 wetland treatment system (WTS) was designed to remove metals from the effluent at the A-01 NPDES outfall. The purpose of research conducted during 2003 was to evaluate (1) the ability of the A-01 wetland treatment system to remediate waste water, (2) retention of the removed contaminants in wetland sediment, and (3) the potential remobilization of these contaminants from the sediment into the water column. Surface water and sediment samples were collected and analyzed in this study.

  1. Effects of heavy metals on biomarkers for oxidative stress in Griffon vulture (Gyps fulvus)

    SciTech Connect (OSTI)

    Espn, Silvia; Martnez-Lpez, Emma; Jimnez, Pedro; Mara-Mojica, Pedro; Garca-Fernndez, Antonio J.

    2014-02-01

    Metals are involved in the formation of reactive oxygen species (ROS) which may result in metal-related oxidative stress that can lead to oxidative damage to lipids, DNA and proteins. It is necessary to understand the mechanisms of metal toxicity in wild birds, and the concentrations that cause effects on oxidative stress biomarkers. The aim of this study is to assess the concentrations of lead (Pb), cadmium (Cd), mercury (Hg), copper (Cu) and zinc (Zn) with regards to oxidative stress in blood samples of 66 Griffon vultures (Gyps fulvus) from two areas of the Autonomous Community of Valencia (East of Spain). The two study areas (Alcoy n=36 and Cinctorres n=30) were selected as random locations of interest that had not yet been studied, and are feeding stations where supplementary food, mainly of pork origin, is provided for vultures. Given that the two study areas are not considered polluted sites, we expected to find low metal concentrations. However, there are no known threshold concentrations at which metals can affect antioxidant systems, and low metal levels may have an effect on antioxidant biomolecules. In this study, since sampling was done at the beginning of the hunting season, the low Pb levels found in most Griffon vultures from Alcoy and Cinctorres (median=12.37 and 16.26 ?g/dl, respectively) are suggestive of background levels usually found in vultures that feed on pork carcasses all year round. The ingestion of game meat with bullet fragments in carcasses or with Pb shots embedded in the flesh could be the cause of the high blood Pb concentrations found in three vultures from Cinctorres (83, 290 and 362 ?g/dl). Griffon vultures feeding in Cinctorres had enhanced CAT and GST activities and tGSH concentrations, which may be interpreted as protective response against the higher TBARS levels. This study provides threshold concentrations at which metals affect antioxidant system derived from 66 samples of Griffon vulture. Blood Cd concentrations greater than 0.05 ?g/dl produced an induction of 33% in GPx and of 44% in CAT activity in erythrocytes of vultures from Alcoy. Hg concentrations in blood higher than 3 ?g/dl produced an induction of 10% in SOD activity. Concentrations of Pb above 15 g/dl in blood produced an inhibition of 12.5% in GPx and 11.3% in CAT activity, and a TBARS induction of 10.7% in erythrocytes of Griffon vultures. - Highlights: Except for 3 Griffon vultures, lead levels could be considered background levels. Three vultures may be exposed to meat with bullet fragments (blood Pb=83362 ?g/dl). Blood Cd levels?0.05 ?g/dl caused an induction of GPx and CAT activity (33% and 44%). Blood Hg levels?3 ?g/dl caused an induction of 10% in SOD activity. Blood Pb?15 g/dl caused an inhibition of GPx and CAT activity and a TBARS induction.

  2. Use of Sequential Injection Analysis to construct a Potentiometric Electronic Tongue: Application to the Multidetermination of Heavy Metals

    SciTech Connect (OSTI)

    Mimendia, Aitor; Merkoci, Arben; Valle, Manel del; Legin, Andrey

    2009-05-23

    An automated potentiometric electronic tongue (ET) was developed for the quantitative determination of heavy metal mixtures. The Sequential Injection Analysis (SIA) technique was used in order to automate the obtaining of input data, and the combined response was modeled by means of Artificial Neural Networks (ANN). The sensor array was formed by four sensors: two based on chalcogenide glasses Cd sensor and Cu sensor, and the rest on poly(vinyl chloride) membranes Pb sensor and Zn sensor. The Ion Selective Electrode (ISE) sensors were first characterized with respect to one and two analytes, by means of high-dimensionality calibrations, thanks to the use of the automated flow system; this characterization enabled an interference study of great practical utility. To take profit of the dynamic nature of the sensor's response, the kinetic profile of each sensor was compacted by Fast Fourier Transform (FFT) and the extracted coefficients were used as inputs for the ANN in the multidetermination applications. In order to identify the ANN which provided the best model of the electrode responses, some of the network parameters were optimized. Finally analyses were performed employing synthetic samples and water samples of the river Ebro; obtained results were compared with reference methods.

  3. In Situ Tracer method for establishing the presence and predicting the activity of heavy metal-reducing microbes in the subsurface. Final Report

    SciTech Connect (OSTI)

    Hatfield, K.

    2003-07-01

    Tracer method to establish presence and distribution of chromium reducing microbes. The primary objective of this research was to establish an in situ tracer method for detecting the presence. distribution. and activity of subsurface heavy metal-reducing microorganisms. Research focused on microbial systems responsible for the reduction of chromium and a suite of biotracers coupled to the reduction process. The tracer method developed may be used to characterize sites contaminated with chromium or expedite bioremediation: and although research focused on chromium. the method can be easily extended to other metals, organics, and radionuclides. This brief final report contains three major sections. The first identifies specific products of the research effort such as students supported and publications. The second section briefly presents major research findings, while the last section summarizes the overall research effort.

  4. Conversion of heavy hydrocarbon oils

    SciTech Connect (OSTI)

    Chen, N.Y.; Pelrine, B.P.; Yan, T.Y.

    1982-12-14

    This invention provides a process for upgrading a heavy hydrocarbon oil to motor fuel products. The heavy hydrocarbon oil is admixed with a metal halide catalyst and a solvent component under supercritical conditions to form (1) a dense-gas solvent phase which contains refined hydrocarbon crackate, and which is substantially free of metal halide catalyst content; and (2) a residual asphaltic phase.

  5. THE ORIGINS OF LIGHT AND HEAVY R-PROCESS ELEMENTS IDENTIFIED BY CHEMICAL TAGGING OF METAL-POOR STARS

    SciTech Connect (OSTI)

    Tsujimoto, Takuji; Shigeyama, Toshikazu

    2014-11-01

    Growing interests in neutron star (NS) mergers as the origin of r-process elements have sprouted since the discovery of evidence for the ejection of these elements from a short-duration ?-ray burst. The hypothesis of a NS merger origin is reinforced by a theoretical update of nucleosynthesis in NS mergers successful in yielding r-process nuclides with A >130. On the other hand, whether the origin of light r-process elements are associated with nucleosynthesis in NS merger events remains unclear. We find a signature of nucleosynthesis in NS mergers from peculiar chemical abundances of stars belonging to the Galactic globular cluster M15. This finding combined with the recent nucleosynthesis results implies a potential diversity of nucleosynthesis in NS mergers. Based on these considerations, we are successful in the interpretation of an observed correlation between [light r-process/Eu] and [Eu/Fe] among Galactic halo stars and accordingly narrow down the role of supernova nucleosynthesis in the r-process production site. We conclude that the tight correlation by a large fraction of halo stars is attributable to the fact that core-collapse supernovae produce light r-process elements while heavy r-process elements such as Eu and Ba are produced by NS mergers. On the other hand, stars in the outlier, composed of r-enhanced stars ([Eu/Fe] ?+1) such as CS22892-052, were exclusively enriched by matter ejected by a subclass of NS mergers that is inclined to be massive and consist of both light and heavy r-process nuclides.

  6. Human bronchial epithelial BEAS-2B cells, an appropriate in vitro model to study heavy metals induced carcinogenesis

    SciTech Connect (OSTI)

    Park, Youn-hee; Kim, Donghern; Dai, Jin; Zhang, Zhuo

    2015-09-15

    Occupational and environmental exposure to arsenic (III) and chromium VI (Cr(VI)) have been confirmed to cause lung cancer. Mechanisms of these metals carcinogenesis are still under investigation. Selection of cell lines to be used is essential for the studies. Human bronchial epithelial BEAS-2B cells are the cells to be utilized by most of scientists. However, due to p53 missense mutation (CCG → TCG) at codon 47 and the codon 72 polymorphism (CGC → CCC) in BEAS-2B cells, its usage has frequently been questioned. The present study has examined activity and expression of 53 and its downstream target protein p21 upon acute or chronic exposure of BEAS-2B cells to arsenic and Cr(VI). The results show that short-term exposure of BEAS-2B cells to arsenic or Cr(VI) was able to activate both p53 and p21. Chronic exposure of BEAS-2B cells to these two metals caused malignant cell transformation and tumorigenesis. In arsenic-transformed BEAS-2B cells reductions in p53 promoter activity, mRNA expression, and phosphorylation of p53 at Ser392 were observed, while the total p53 protein level remained the same compared to those in passage-matched parent ones. p21 promoter activity and expression were decreased in arsenic-transformed cells. Cr(VI)-transformed cells exhibit elevated p53 promoter activity, mRNA expression, and phosphorylation at Ser15, but reduced phosphorylation at Ser392 and total p53 protein level compared to passage-matched parent ones. p21 promoter activity and expression were elevated in Cr(VI)-transformed cells. These results demonstrate that p53 is able to respond to exposure of arsenic or Cr(VI), suggesting that BEAS-2B cells are an appropriate in vitro model to investigate arsenic or Cr(VI) induced lung cancer. - Highlights: • Short-term exposure of BEAS-2B cells to arsenic or Cr(VI) activates p53 and p21. • Chronic exposure of BEAS-2B cells to arsenic or Cr(VI) causes cell transformation and tumorigenesis. • Arsenic-transformed cells exhibit reduced activities of p53 and p21. • Cr(VI)-transformed cells exhibit increased activities of p53 and p21.

  7. IUPAC-NIST Solubility Data Series. 100. Rare Earth Metal Fluorides in Water and Aqueous Systems. Part 3. Heavy Lanthanides (GdLu)

    SciTech Connect (OSTI)

    Mioduski, Tomasz; Gumi?ski, Cezary; Zeng, Dewen

    2015-06-15

    This is the third part of the volume devoted to solubility data for the rare earth metal (REM) fluorides in water and in aqueous ternary and multicomponent systems. It covers experimental results of trivalent fluorides of Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu (so-called heavy lanthanides), since no quantitative data on solubilities of TbF{sub 4} and YbF{sub 2} (the most stable compounds at these valencies) are available. The related literature has been covered through the end of 2014. Compilations of all available papers with the solubility data are introduced for each REM fluoride with a corresponding critical evaluation. Every such assessment contains a collection of all solubility results in aqueous solution, a selection of suggested solubility data, a solubility equation, and a brief discussion of the multicomponent systems. Only simple fluorides (no complexes or double salts) are treated as the input substances in this report. General features of the systems, such as nature of the equilibrium solid phases, solubility as a function of temperature, influence of ionic strength, solution pH, mixed solvent medium on the solubility, quality of the solubility results, and the solubility as a function of REM atomic number, have already been presented in Part 1 of the volume.

  8. Radionuclides, Heavy Metals, and Polychlorinated Biphenyls in Soils Collected Around the Perimeter of Low-Level Radioactive Waste Disposal Area G during 2006

    SciTech Connect (OSTI)

    P. R. Fresquez

    2007-02-28

    Twenty-one soil surface samples were collected in March around the perimeter of Area G, the primary disposal facility for low-level radioactive solid waste at Los Alamos National Laboratory (LANL). Three more samples were collected in October around the northwest corner after elevated tritium levels were detected on an AIRNET station located north of pit 38 in May. Also, four soil samples were collected along a transect at various distances (48, 154, 244, and 282 m) from Area G, starting from the northeast corner and extending to the Pueblo de San Ildefonso fence line in a northeasterly direction (this is the main wind direction). Most samples were analyzed for radionuclides ({sup 3}H, {sup 238}Pu, {sup 239,240}Pu, {sup 241}Am, {sup 234}U, {sup 235}U, and {sup 238}U), inorganic elements (Al, Ba, Be, Ca, Cr, Co, Cu, Fe, Mg, Mn, Ni, K, Na, V, Hg, Zn, Sb, As, Cd, Pb, Se, Ag, and Tl) and polychlorinated biphenyl (PCB) concentrations. As in previous years, the highest levels of {sup 3}H in soils (690 pCi/mL) were detected along the south portion of Area G near the {sup 3}H shafts; whereas, the highest concentrations of {sup 241}Am (1.2 pCi/g dry) and the Pu isotopes (1.9 pCi/g dry for {sup 238}Pu and 5 pCi/g dry for {sup 239,240}Pu) were detected along the northeastern portions near the transuranic waste pads. Concentrations of {sup 3}H in three soil samples and {sup 241}Am and Pu isotopes in one soil sample collected around the northwest corner in October increased over concentrations found in soils collected at the same locations earlier in the year. Almost all of the heavy metals, with the exception of Zn and Sb in one sample each, in soils around the perimeter of Area G were below regional statistical reference levels (mean plus three standard deviations) (RSRLs). Similarly, only one soil sample collected on the west side contained PCB concentrations--67 {micro}g/kg dry of aroclor-1254 and 94 {micro}g/kg dry of aroclor-1260. Radionuclide and inorganic element concentrations in soils collected along a transect from Area G to the Pueblo de San Ildefonso fence line show that most contained concentrations of {sup 241}Am, {sup 238}Pu, and {sup 239,240}Pu above the RSRLs. Overall, all concentrations of radionuclides, heavy metals, and PCBs that were detected above background levels in soils collected around the perimeter of Area G and towards the Pueblo de San Ildefonso boundary were still very low and far below LANL screening levels and regulatory standards.

  9. Accumulation of Pb and Cu heavy metals in sea water, sediment, and leaf and root tissue of Enhalus sp. in the seagrass bed of Banten Bay

    SciTech Connect (OSTI)

    Fauziah, Faiza Choesin, Devi N.

    2014-03-24

    Banten Bay in Indonesia is a coastal area which has been highly affected by human activity. Previous studies have reported the presence of lead (Pb) and copper (Cu) heavy metals in the seawater of this area. This study was conducted to measure the accumulation of Pb and Cu in seawater, sediment, leaf tissue, and root tissue of the seagrass species Enhalus sp. Sampling was conducted at two observation stations in Banten Bay: Station 1 (St.1) was located closer to the coastline and to industrial plants as source of pollution, while Station 2 (St.2) was located farther away offshore. At each station, three sampling points were established by random sampling. Field sampling was conducted at two different dates, i.e., on 29 May 2012 and 30 June 2012. Samples were processed by wet ashing using concentrated HNO{sub 3} acid and measured using Atomic Absorption Spectrometry (AAS). Accumulation of Pb was only detected in sediment samples in St.1, while Cu was detected in all samples. Average concentrations of Cu in May were as follows: sediment St.1 = 0.731 ppm, sediment St.2 = 0.383 ppm, seawater St.1 = 0.163 ppm, seawater St.2 = 0.174 ppm, leaf St.1 = 0.102 ppm, leaf St.2 = 0.132 ppm, root St.1= 0.139 ppm, and root St.2 = 0.075 ppm. Average measurements of Cu in June were: sediment St.1 = 0.260 ppm, leaf St.1 = 0.335 ppm, leaf St.2 = 0.301 ppm, root St.1= 0.047 ppm, and root St.2 = 0.060 ppm. In June, Cu was undetected in St.2 sediment and seawater at both stations. In May, Cu concentration in seawater exceeded the maximum allowable threshold for water as determined by the Ministry of the Environment. Spatial and temporal variation in Pb and Cu accumulation were most probably affected by distance from source and physical conditions of the environment (e.g., water current and mixing)

  10. FORMING PROTECTIVE FILMS ON METAL

    DOE Patents [OSTI]

    Gurinsky, D.H.; Kammerer, O.F.; Sadofsky, J.; Weeks, J.R.

    1958-12-16

    Methods are described of inhibiting the corrosion of ferrous metal by contact with heavy liquid metals such as bismuth and gallium at temperatures above 500 icient laborato C generally by bringing nltrogen and either the metal zirconium, hafnium, or titanium into reactlve contact with the ferrous metal to form a thin adherent layer of the nitride of the metal and thereafter maintaining a fractional percentage of the metal absorbed in the heavy liquid metal in contact with the ferrous metal container. The general purpose for uslng such high boiling liquid metals in ferrous contalners would be as heat transfer agents in liquid-metal-fueled nuclear reactors.

  11. Hydrogen Production and Purification from Coal and Other Heavy...

    Office of Scientific and Technical Information (OSTI)

    Hydrogen Production and Purification from Coal and Other Heavy Feedstocks Year 6 - Activity 1.4 - ... sour syngas exposure, as well as deposition of metals from carbonyl decomposition. ...

  12. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Towards Heavy Fermions in Europium Intermetallic Compounds Towards Heavy Fermions in Europium Intermetallic Compounds Print Wednesday, 29 July 2009 00:00 For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in

  13. Performance assessment of the direct disposal in unsaturated tuff or spent nuclear fuel and high-level waste owned by USDOE: Volume 2, Methodology and results

    SciTech Connect (OSTI)

    Rechard, R.P.

    1995-03-01

    This assessment studied the performance of high-level radioactive waste and spent nuclear fuel in a hypothetical repository in unsaturated tuff. The results of this 10-month study are intended to help guide the Office of Environment Management of the US Department of Energy (DOE) on how to prepare its wastes for eventual permanent disposal. The waste forms comprised spent fuel and high-level waste currently stored at the Idaho National Engineering Laboratory (INEL) and the Hanford reservations. About 700 metric tons heavy metal (MTHM) of the waste under study is stored at INEL, including graphite spent nuclear fuel, highly enriched uranium spent fuel, low enriched uranium spent fuel, and calcined high-level waste. About 2100 MTHM of weapons production fuel, currently stored on the Hanford reservation, was also included. The behavior of the waste was analyzed by waste form and also as a group of waste forms in the hypothetical tuff repository. When the waste forms were studied together, the repository was assumed also to contain about 9200 MTHM high-level waste in borosilicate glass from three DOE sites. The addition of the borosilicate glass, which has already been proposed as a final waste form, brought the total to about 12,000 MTHM.

  14. Savannah River Site Spent Nuclear Fuel Management Final Environmental Impact Statement

    SciTech Connect (OSTI)

    N /A

    2000-04-14

    The proposed DOE action considered in this environmental impact statement (EIS) is to implement appropriate processes for the safe and efficient management of spent nuclear fuel and targets at the Savannah River Site (SRS) in Aiken County, South Carolina, including placing these materials in forms suitable for ultimate disposition. Options to treat, package, and store this material are discussed. The material included in this EIS consists of approximately 68 metric tons heavy metal (MTHM) of spent nuclear fuel 20 MTHM of aluminum-based spent nuclear fuel at SRS, as much as 28 MTHM of aluminum-clad spent nuclear fuel from foreign and domestic research reactors to be shipped to SRS through 2035, and 20 MTHM of stainless-steel or zirconium-clad spent nuclear fuel and some Americium/Curium Targets stored at SRS. Alternatives considered in this EIS encompass a range of new packaging, new processing, and conventional processing technologies, as well as the No Action Alternative. A preferred alternative is identified in which DOE would prepare about 97% by volume (about 60% by mass) of the aluminum-based fuel for disposition using a melt and dilute treatment process. The remaining 3% by volume (about 40% by mass) would be managed using chemical separation. Impacts are assessed primarily in the areas of water resources, air resources, public and worker health, waste management, socioeconomic, and cumulative impacts.

  15. Nuclear Materials Research and Technology/Los Alamos National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Nuclear Fuels Storage & Transportation Planning Project Nuclear Fuels Storage & Transportation Planning Project Independent Spent Fuel Storage Installation (ISFSI) at the shutdown Connecticut Yankee site. The ISFSI includes 40 multi-purpose canisters, within vertical concrete storage casks, containing 1019 used nuclear fuel assemblies [412.3 metric ton heavy metal (MTHM)] and 3 canisters of greater-than-class-C (GTCC) low-level radioactive waste. Photo courtesy of Connecticut

  16. [Task 1.] Biodenitrification of low nitrate solar pond waters using sequencing batch reactors. [Task 2.] Solidification/stabilization of high strength and biodenitrified heavy metal sludges with a Portland cement/flyash system

    SciTech Connect (OSTI)

    Figueroa, L.; Cook, N.E.; Siegrist, R.L.; Mosher, J.; Terry, S.; Canonico, S.

    1995-09-22

    Process wastewater and sludges were accumulated on site in solar evaporation ponds during operations at the Department of Energy's Rocky Flats Plant (DOE/RF). Because of the extensive use of nitric acid in the processing of actinide metals, the process wastewater has high concentrations of nitrate. Solar pond waters at DOE/RF contain 300-60,000 mg NO{sub 3}{sup {minus}}/L. Additionally, the pond waters contain varying concentrations of many other aqueous constituents, including heavy metals, alkali salts, carbonates, and low level radioactivity. Solids, both from chemical precipitation and soil material deposition, are also present. Options for ultimate disposal of the pond waters are currently being evaluated and include stabilization and solidification (S/S) by cementation. Removal of nitrates can enhance a wastes amenability to S/S, or can be a unit operation in another treatment scheme. Nitrate removal is also a concern for other sources of pollution at DOE/RF, including contaminated groundwater collected by interceptor trench systems. Finally, nitrate pollution is a problem at many other DOE facilities where actinide metals were processed. The primary objective of this investigation was to optimize biological denitrification of solar pond waters with nitrate concentrations of 300--2,100 mg NO{sub 3}{sup {minus}}/L to below the drinking water standard of 45 mg NO{sub 3}{sup {minus}}/L (10 mg N/L). The effect of pH upon process stability and denitrification rate was determined. In addition, the effect Cr(VI) on denitrification and fate of Cr(VI) in the presence of denitrifying bacteria was evaluated.

  17. Heavy loads

    SciTech Connect (OSTI)

    Metz, D.

    1982-01-01

    The extreme pressures on the roof and walls of an earth-sheltered residential home are discussed and the need for careful planning is stressed. Pertinent terms are defined. Footings and wall structure (reinforced concrete walls and concrete block walls) are described. Roofing systems are discussed in detail and illustrated: (1) poured-in-place concrete roof slabs; (2) pre-cast concrete planks; and (3) heavy timber roofs. Insulation of earth-sheltered homes is reviewed in terms of using: (1) urethanes; (2) extruded polystyrene; and (3) expanded polystyrene. Advantages, disadvantages, R-factors, costs, and installation are discussed. (MJJ)

  18. Purification of alkali metal nitrates

    DOE Patents [OSTI]

    Fiorucci, Louis C.; Gregory, Kevin M.

    1985-05-14

    A process is disclosed for removing heavy metal contaminants from impure alkali metal nitrates containing them. The process comprises mixing the impure nitrates with sufficient water to form a concentrated aqueous solution of the impure nitrates, adjusting the pH of the resulting solution to within the range of between about 2 and about 7, adding sufficient reducing agent to react with heavy metal contaminants within said solution, adjusting the pH of the solution containing reducing agent to effect precipitation of heavy metal impurities and separating the solid impurities from the resulting purified aqueous solution of alkali metal nitrates. The resulting purified solution of alkali metal nitrates may be heated to evaporate water therefrom to produce purified molten alkali metal nitrate suitable for use as a heat transfer medium. If desired, the purified molten form may be granulated and cooled to form discrete solid particles of alkali metal nitrates.

  19. Heavy Vehicle Propulsion Materials Program

    SciTech Connect (OSTI)

    Diamond, S.; Johnson, D.R.

    1999-04-26

    The objective of the Heavy Vehicle Propulsion Materials Program is to develop the enabling materials technology for the clean, high-efficiency diesel truck engines of the future. The development of cleaner, higher-efficiency diesel engines imposes greater mechanical, thermal, and tribological demands on materials of construction. Often the enabling technology for a new engine component is the material from which the part can be made. The Heavy Vehicle Propulsion Materials Program is a partnership between the Department of Energy (DOE), and the diesel engine companies in the United States, materials suppliers, national laboratories, and universities. A comprehensive research and development program has been developed to meet the enabling materials requirements for the diesel engines of the future. Advanced materials, including high-temperature metal alloys, intermetallics, cermets, ceramics, amorphous materials, metal- and ceramic-matrix composites, and coatings, are investigated for critical engine applications.

  20. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass)

  1. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass)

  2. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass)

  3. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass)

  4. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass)

  5. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass)

  6. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass)

  7. PROCESS FOR THE SEPARATION OF HEAVY METALS

    DOE Patents [OSTI]

    Gofman, J.W.; Connick, R.E.; Wahl, A.C.

    1959-01-27

    A method is presented for thc separation of plutonium from uranium and the fission products with which it is associated. The method is based on the fact that hexavalent plutonium forms an insoluble complex precipitate with sodium acetate, as does the uranyl ion, while reduced plutonium is not precipitated by sodium acetate. Several embodiments are shown, e.g., a solution containing plutonium and uranium in the hexavalent state may be contacted with sodium acetate causing the formation of a sodium uranyl acetate precipitate which carries the plutonium values while the fission products remain in solution. If the original solution is treated with a reducing agent, so that the plutonium is reduced while the uranium remains in the hexavalent state, and sodium and acetate ions are added, the uranium will precipitutc while the plutonium remains in solution effecting separation of the Pu from urarium.

  8. HEAVY METAL LOADED PLASTIC SCINTILLATING COMPOSITIONS

    DOE Patents [OSTI]

    Hyman, M. Jr.

    1962-06-26

    Thls lnventlon relates to a plastlc sclntlllatlon composltlon havlng lncorporated ln the base plastlc a lead compound. Thls compound forms a haze- free sclntillator. The lead compound has the general formula (R/sub 4/) x from the group consisting of hydrogen, alky, and phenyl, R4 ls selected from the group conslstlng of acrylyl and methacryiyl radlcals, and x ls a number from 0,5 to 1; however, when R/sub 1/, R/sub 2/, and R/sub 3/ are all hydrogen the x ls equal to 1. The phosphor ln the sclntlllatlng compositlon and the lead compound can be dlssolved ln a polymerlc resln selected from the group conslsting of polyvinyl toluene and copolymers of vlnyl toluene and cyclohexyl methacrylate. (AEC)

  9. Upgrading platform using alkali metals

    SciTech Connect (OSTI)

    Gordon, John Howard

    2014-09-09

    A process for removing sulfur, nitrogen or metals from an oil feedstock (such as heavy oil, bitumen, shale oil, etc.) The method involves reacting the oil feedstock with an alkali metal and a radical capping substance. The alkali metal reacts with the metal, sulfur or nitrogen content to form one or more inorganic products and the radical capping substance reacts with the carbon and hydrogen content to form a hydrocarbon phase. The inorganic products may then be separated out from the hydrocarbon phase.

  10. Heavy Mobile Equipment Mechanic

    Broader source: Energy.gov [DOE]

    Join the Bonneville Power Administration (BPA) for a challenging and rewarding career, while working, living, and playing in the Pacific Northwest. The Heavy Mobile Equipment Mechanic (HMEM)...

  11. EXELFS of Metallic Glasses

    SciTech Connect (OSTI)

    Ito, Y.; Alamgir, F.M.; Schwarz, R.B.; Jain, H.; Williams, D.B.

    1999-11-30

    The feasibility of using extended energy-loss fine structure (EXELFS) obtained from {approximately}1 nm regions of metallic glasses to study their short-range order has been examined. Ionization edges of the metallic glasses in the electron energy-loss spectrum (EELS) have been obtained from PdNiP bulk metallic glass and Ni{sub 2}P polycrystalline powder in a transmission electron microscope. The complexity of EXELFS analysis of L- and M-ionization edges of heavy elements (Z>22, i.e. Ni and Pd) is addressed by theoretical calculations using an ab initio computer code, and its results are compared with the experimental data.

  12. Process for upgrading heavy petroleum feedstock

    SciTech Connect (OSTI)

    Rudnick, L.R.

    1987-02-10

    A method is described for reducing the coking tendency of a heavy hydrocarbon feedstock in a non-hydrogenative catalytic cracking process. The process comprises contacting the feedstock prior to catalytic cracking with a free radical removing catalyst comprising a transition metal napthenate at a temperature below 350/sup 0/C. for a time sufficient to reduce the free radical concentration of the feedstock whereby the coking tendency of the feedstock to the catalytic cracking process is reduced.

  13. EIS-0279-SA-01: Supplement Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    -SA-01: Supplement Analysis EIS-0279-SA-01: Supplement Analysis Savannah River Site Spent Nuclear Fuel Management (DOE/EIS-0279-SA-01 and DOE/EIS-0218-SA-06) This Supplement Analysis evaluates DOE's proposal to change the management method for approximately 3.3 metric tons of heavy metal (MTHM) of aluminum-clad spent nuclear fuel (SNF) from melt and dilute to conventional processing in H-Canyon at the Savannah River Site (SRS) and to down-blend the resultant highly-enriched uranium (HEU) to low

  14. Removal of metal ions from aqueous solution

    DOE Patents [OSTI]

    Jackson, Paul J.; Delhaize, Emmanuel; Robinson, Nigel J.; Unkefer, Clifford J.; Furlong, Clement

    1990-01-01

    A method of removing heavy metals from aqueous solution, a composition of matter used in effecting said removal, and apparatus used in effecting said removal. One or more of the polypeptides, poly (.gamma.-glutamylcysteinyl)glycines, is immobilized on an inert material in particulate form. Upon contact with an aqueous solution containing heavy metals, the polypeptides sequester the metals, removing them from the solution. There is selectivity of poly (.gamma.-glutamylcysteinyl)glycines having a particular number of monomer repeat units for particular metals. The polypeptides are easily regenerated by contact with a small amount of an organic acid, so that they can be used again to remove heavy metals from solution. This also results in the removal of the metals from the column in a concentrated form.

  15. Super-Heavy Element Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Targets for Super-Heavy Element Research Presented at International Workshop on Super-Heavy Element Research SHE-15 J. B. Roberto Oak Ridge National Laboratory Oak Ridge,...

  16. Upgrading heavy gas oils

    SciTech Connect (OSTI)

    Ferguson, S.; Reese, D.D.

    1986-05-20

    A method is described of neutralizing the organic acidity in heavy gas oils to produce a neutralization number less than 1.0 whereby they are rendered suitable as lube oil feed stocks which consists essentially of treating the heavy gas oils with a neutralizing amount of monoethanolamine to form an amine salt with the organic acids and then heating the thus-neutralized heavy gas oil at a temperature at least about 25/sup 0/F greater than the boiling point of water and for a time sufficient to convert the amine salts to amides.

  17. Peroxotitanates for Biodelivery of Metals

    SciTech Connect (OSTI)

    Hobbs, David; Elvington, M.

    2009-02-11

    Metal-based drugs are largely undeveloped in pharmacology. One limiting factor is the systemic toxicity of metal-based compounds. A solid-phase, sequestratable delivery agent for local delivery of metals could reduce systemic toxicity, facilitating new drug development in this nascent area. Amorphous peroxotitanates (APT) are ion exchange materials with high affinity for several heavy metal ions, and have been proposed to deliver or sequester metal ions in biological contexts. In the current study, we tested a hypothesis that APT are able to deliver metals or metal compounds to cells. We exposed fibroblasts (L929) or monocytes (THP1) to metal-APT materials for 72 h in vitro, then measured cellular mitochondrial activity (SDH-MTT method) to assess the biological impact of the metal-APT materials vs. metals or APT alone. APT alone did not significantly affect cellular mitochondrial activity, but all metal-APT materials suppressed the mitochondrial activity of fibroblasts (by 30-65% of controls). The concentration of metal-APT materials required to suppress cellular mitochondrial activity was below that required for metals alone, suggesting that simple extracellular release of the metals from the metal-APT materials was not the primary mechanism of mitochondrial suppression. In contrast to fibroblasts, no metal-APT material had a measurable effect on THP1 monocyte mitochondrial activity, despite potent suppression by metals alone. This latter result suggested that 'biodelivery' by metal-APT materials may be cell type-specific. Therefore, it appears that APT are plausible solid phase delivery agents of metals or metal compounds to some types of cells for potential therapeutic effect.

  18. Heavy fermions in an optical lattice

    SciTech Connect (OSTI)

    Foss-Feig, Michael; Hermele, Michael; Gurarie, Victor; Rey, Ana Maria

    2010-11-15

    We employ a mean-field theory to study ground-state properties and transport of a two-dimensional gas of ultracold alkaline-earth-metal atoms governed by the Kondo lattice Hamiltonian plus a parabolic confining potential. In a homogenous system, this mean-field theory is believed to give a qualitatively correct description of heavy-fermion metals and Kondo insulators: It reproduces the Kondo-like scaling of the quasiparticle mass in the former and the same scaling of the excitation gap in the latter. In order to understand ground-state properties in a trap, we extend this mean-field theory via local-density approximation. We find that the Kondo insulator gap manifests as a shell structure in the trapped density profile. In addition, a strong signature of the large Fermi surface expected for heavy-fermion systems survives the confinement and could be probed in time-of-flight experiments. From a full self-consistent diagonalization of the mean-field theory, we are able to study dynamics in the trap. We find that the mass enhancement of quasiparticle excitations in the heavy-Fermi liquid phase manifests as slowing of the dipole oscillations that result from a sudden displacement of the trap center.

  19. Upgrading heavy oil using slurry processes

    SciTech Connect (OSTI)

    Del Bianco, A.; Panariti, N.; Marchionna, M.

    1995-11-01

    There is a growing interest in processes capable of converting heavy feedstocks (petroleum residues and heavy oils) into lower boiling products of high quality. The operational problems of upgrading heavy feeds relate to the presence of sulfur, nitrogen, metals, and considerable amounts of Conradson carbon residue. An efficient residue conversion process must be able to reduce the molecular weight of the feedstocks to material with boiling points below 550 C, increase the H-to-C ratio of the refined product, and remove heteroatoms and metals. Whereas the molecular weight reduction is normally achieved by C-C bond cracking above 400 C, often in the presence of acid catalysts, a higher H-to-C ratio can be obtained by either the rejection of carbon (as in coking) or the addition of hydrogen (as in hydrogenation processes). Slurry processes combine the flexibility of the carbon rejection with the high performance of the hydrogen addition processes. The origin of slurry processes is the Bergius-Pier technology (1920--1930) for the conversion of heavy oils and coal into distillates. Whereas the original Bergius-Pier technology did not use a catalyst, small amounts of inexpensive additives or finely dispersed hydrogenation catalysts can be used to increase the rates of the desired reactions. Catalysts can also inhibit coke formation by physically interfering with the coalescence of mesophase, which is the precursor of solid coke. Catalysts are used to reduce the severity of the process and to improve the quality of the products. Most of the research carried out in the past decade in the field of slurry processes has dealt with the identification of more effective and/or less expensive catalysts and the technological problems related to their use. Here the authors discuss both subjects, describing the path from the fundamental chemistry of dispersed catalytic systems to the development and initial commercialization of slurry processes.

  20. Heavy Vehicle Systems

    SciTech Connect (OSTI)

    Sid Diamond; Richard Wares; Jules Routbort

    2000-04-11

    Heavy Vehicle (HV) systems are a necessary component of achieving OHVT goals. Elements are in place for a far-ranging program: short, intermediate, and long-term. Solicitation will bring industrial input and support. Future funding trend is positive, outlook for HV systems is good.

  1. SECTION II: HEAVY ION REACTIONS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    II: HEAVY ION REACTIONS Experimental Determination of the Symmetry Energy of a Low Density Nuclear Gas ......II-1 S. ...

  2. Removal of metal ions from aqueous solution

    DOE Patents [OSTI]

    Jackson, Paul J.; Delhaize, Emmanuel; Robinson, Nigel J.; Unkefer, Clifford J.; Furlong, Clement

    1990-11-13

    A method of removing heavy metals from aqueous solution, a composition of matter used in effecting said removal, and apparatus used in effecting said removal. One or more of the polypeptides, poly (.gamma.-glutamylcysteinyl)glycines, is immobilized on an inert material in particulate form. Upon contact with an aqueous solution containing heavy metals, the polypeptides sequester the metals, removing them from the solution. There is selectivity of poly (.gamma.-glutamylcysteinyl)glycines having a particular number of monomer repeat unit for particular metals. The polypeptides are easily regenerated by contact with a small amount of an organic acid, so that they can be used again to remove heayv metals from solution. This also results in the removal of the metals from the column in a concentrated form.

  3. DOE Science Showcase - Rare Earth Metal Research from DOE Databases |

    Office of Scientific and Technical Information (OSTI)

    OSTI, US Dept of Energy, Office of Scientific and Technical Information Rare Earth Metal Research from DOE Databases Information Bridge Energy Citations Database Highlighted documents of Rare Earth Metal research in DOE databases Information Bridge - Corrosion-resistant metal surfaces DOE R&D Project Summaries - Structural and magnetic studies on heavy rare earth metals at high pressures using designer diamonds Energy Citations Database - Intermultiplet transitions in rare-earth metals

  4. Nucleic acids encoding metal uptake transporters and their uses

    DOE Patents [OSTI]

    Schroeder, Julian I.; Antosiewicz, Danuta M.; Schachtman, Daniel P.; Clemens, Stephan

    1999-01-01

    The invention provides LCT1 nucleic acids which encode metal ion uptake transporters. The invention also provides methods of modulating heavy metal and alkali metal uptake in plants. The methods involve producing transgenic plants comprising a recombinant expression cassette containing an LCT1 nucleic acid linked to a plant promoter.

  5. Process for upgrading heavy oils

    SciTech Connect (OSTI)

    LePage, J.F.; Marlino, G.

    1983-07-05

    The viscosity of heavy oils is reduced in order to facilitate pipe line transportation thereof. A fraction of the heavy oil is deasphalted in the presence of C/sub 5/-C/sub 7/ hydrocarbons, a portion of the separated asphalt is converted to synthesis gas, at least a portion of said gas is used to manufacture an alcohol mixture including methanol and C/sub 2/ to C/sub 10/ alcohols, which mixture is admixed with the heavy oil before transportation thereof. This procedure is more beneficial to the transported heavy oil than the prior processes which do not comprise the conversion of the asphalt fraction of the heavy oil.

  6. Heavy Vehicle Propulsion Materials

    SciTech Connect (OSTI)

    Ray Johnson

    2000-01-31

    The objectives are to Provide Key Enabling Materials Technologies to Increase Energy Efficiency and Reduce Exhaust Emissions. The following goals are listed: Goal 1: By 3rd quarter 2002, complete development of materials enabling the maintenance or improvement of fuel efficiency {ge} 45% of class 7-8 truck engines while meeting the EPA/Justice Department ''Consent Decree'' for emissions reduction. Goal 2: By 4th quarter 2004, complete development of enabling materials for light-duty (class 1-2) diesel truck engines with efficiency over 40%, over a wide range of loads and speeds, while meeting EPA Tier 2 emission regulations. Goal 3: By 4th quarter 2006, complete development of materials solutions to enable heavy-duty diesel engine efficiency of 50% while meeting the emission reduction goals identified in the EPA proposed rule for heavy-duty highway engines.''

  7. Utah Heavy Oil Program

    SciTech Connect (OSTI)

    J. Bauman; S. Burian; M. Deo; E. Eddings; R. Gani; R. Goel; C.K. Huang; M. Hogue; R. Keiter; L. Li; J. Ruple; T. Ring; P. Rose; M. Skliar; P.J. Smith; J.P. Spinti; P. Tiwari; J. Wilkey; K. Uchitel

    2009-10-20

    The Utah Heavy Oil Program (UHOP) was established in June 2006 to provide multidisciplinary research support to federal and state constituents for addressing the wide-ranging issues surrounding the creation of an industry for unconventional oil production in the United States. Additionally, UHOP was to serve as an on-going source of unbiased information to the nation surrounding technical, economic, legal and environmental aspects of developing heavy oil, oil sands, and oil shale resources. UHOP fulGilled its role by completing three tasks. First, in response to the Energy Policy Act of 2005 Section 369(p), UHOP published an update report to the 1987 technical and economic assessment of domestic heavy oil resources that was prepared by the Interstate Oil and Gas Compact Commission. The UHOP report, entitled 'A Technical, Economic, and Legal Assessment of North American Heavy Oil, Oil Sands, and Oil Shale Resources' was published in electronic and hard copy form in October 2007. Second, UHOP developed of a comprehensive, publicly accessible online repository of unconventional oil resources in North America based on the DSpace software platform. An interactive map was also developed as a source of geospatial information and as a means to interact with the repository from a geospatial setting. All documents uploaded to the repository are fully searchable by author, title, and keywords. Third, UHOP sponsored Give research projects related to unconventional fuels development. Two projects looked at issues associated with oil shale production, including oil shale pyrolysis kinetics, resource heterogeneity, and reservoir simulation. One project evaluated in situ production from Utah oil sands. Another project focused on water availability and produced water treatments. The last project considered commercial oil shale leasing from a policy, environmental, and economic perspective.

  8. Retrofitting heavy oil processes

    SciTech Connect (OSTI)

    Hamilton, G.L.; Fitzgerald, M.; D'Amico, V.

    1986-01-01

    Refiners, faced with the need to process the bottom end of the heavy high sulfur crude oil barrel in today's uncertain economic environment, are reluctant to commit large amounts of money to expensive upgrading processes. In order to conserve scarce capital while improving operating margins, additional valuable products can be produced by retrofits such as conversion of an idle crude unit to visbreaking, delayed coking or deasphalting service, or conversion of hydrodesulfurizers to mild hydrocracking.

  9. Viscous heavy brines

    SciTech Connect (OSTI)

    House, R.F.; Hoover, L.D.

    1984-07-10

    Hydroxyethyl cellulose and a sequestrant are added to a heavy brine containing one or more salts selected from calcium chloride, calcium bromide, and zinc bromide to increase the viscosity of the brine. Preferably the brine contains zinc bromide, has a density in the range from about 14.2-19.2 pounds per gallon, and the sequestrant is a polyphosphonic acid or water soluble salt thereof.

  10. Characterization of Venezuelan heavy oil vacuum residua

    SciTech Connect (OSTI)

    Izquierdo, A.; Carbognani, L.; Leon, V.; Parisi, A. )

    1988-06-01

    Characterization of abundant ''heavy'' feedstocks such as tar sands, heavy oils and vacuum residua will play a fundamental role in the use of these energy sources. Their physical and chemical properties vary from one feed to another, and this can have some consequences in their necessary upgrading processes. In this paper results on the characterization of 510/sup 0/C-vacuum residua (VR) obtained from Venezuelan Heavy and Medium Oils are presented. These are Morichal (Mo), Merey (Me), Guafita (Gu) and Barinas (Ba). The VR have all an API gravity between 3 and 6, more than 15% asphaltenes, metals above 200 ppm, as well as high contents of nitrogen, more than 6000 ppm, and sulphur, over 1%. It has been found that when these feeds are hydrotreated under similar conditions the processability improves in the order Ba

  11. Metal aminoboranes

    DOE Patents [OSTI]

    Burrell, Anthony K.; Davis, Benjamin J.; Thorn, David L.; Gordon, John C.; Baker, R. Thomas; Semelsberger, Troy Allen; Tumas, William; Diyabalanage, Himashinie Vichalya Kaviraj; Shrestha, Roshan P.

    2010-05-11

    Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other metal aminoboranes. Metal aminoboranes can be dehydrogenated to form hydrogen and a reaction product. The reaction product can react with hydrogen to form a hydrogen storage material. Metal aminoboranes can be included in a kit.

  12. Metal Hydrides

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Metal Hydrides Theodore Motyka Savannah River National Laboratory Metal Hydride System Architect Jose-Miguel Pasini, & Bart van Hassel UTRC Claudio Corgnale & Bruce Hardy SRNL ...

  13. Single-layer transition metal sulfide catalysts

    DOE Patents [OSTI]

    Thoma, Steven G.

    2011-05-31

    Transition Metal Sulfides (TMS), such as molybdenum disulfide (MoS.sub.2), are the petroleum industry's "workhorse" catalysts for upgrading heavy petroleum feedstocks and removing sulfur, nitrogen and other pollutants from fuels. We have developed an improved synthesis technique to produce SLTMS catalysts, such as molybdenum disulfide, with potentially greater activity and specificity than those currently available. Applications for this technology include heavy feed upgrading, in-situ catalysis, bio-fuel conversion and coal liquefaction.

  14. Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Vehicle Technologies Office Merit Review 2014: Heavy-Duty Low-Temperature and Diesel ...

  15. Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Vehicle Technologies Office Merit Review 2014: Heavy-Duty ...

  16. Heavy Truck Engine Program

    SciTech Connect (OSTI)

    Nelson, Christopher

    2009-01-08

    The Heavy Duty Truck Engine Program at Cummins embodied three significant development phases. All phases of work strove to demonstrate a high level of diesel engine efficiency in the face of increasingly stringent emission requirements. Concurrently, aftertreatment system development and refinement was pursued in support of these efficiency demonstrations. The program's first phase focused on the demonstration in-vehicle of a high level of heavy duty diesel engine efficiency (45% Brake Thermal Efficiency) at a typical cruise condition while achieving composite emissions results which met the 2004 U.S. EPA legislated standards. With a combination of engine combustion calibration tuning and the development and application of Urea-based SCR and particulate aftertreatment, these demonstrations were successfully performed by Q4 of 2002. The second phase of the program directed efforts towards an in-vehicle demonstration of an engine system capable of meeting 2007 U.S. EPA legislated emissions requirements while achieving 45% Brake Thermal Efficiency at cruise conditions. Through further combustion optimization, the refinement of Cummins Cooled EGR architecture, the application of a high pressure common rail fuel system and the incorporation of optimized engine parasitics, Cummins Inc. successfully demonstrated these deliverables in Q2 of 2004. The program's final phase set a stretch goal of demonstrating 50% Brake Thermal Efficiency from a heavy duty diesel engine system capable of meeting 2010 U.S. EPA legislated emissions requirements. Cummins chose to pursue this goal through further combustion development and refinement of the Cooled EGR system architecture and also applied a Rankine cycle Waste Heat Recovery technique to convert otherwise wasted thermal energy to useful power. The engine and heat recovery system was demonstrated to achieve 50% Brake Thermal Efficiency while operating at a torque peak condition in second quarter, 2006. The 50% efficient engine system was capable of meeting 2010 emissions requirements through the application of NOx and particulate matter reduction techniques proven earlier in the program.

  17. Coordination chemistry of two heavy metals: I, Ligand preferences in lead(II) complexation, toward the development of therapeutic agents for lead poisoning: II, Plutonium solubility and speciation relevant to the environment

    SciTech Connect (OSTI)

    Neu, M.P.

    1993-11-01

    The coordination chemistry and solution behavior of the toxic ions lead(II) and plutonium(IV, V, VI) have been investigated. The ligand pK{sub a}s and ligand-lead(II) stability constants of one hydroxamic acid and four thiohydroaxamic acids were determined. Solution thermodynamic results indicate that thiohydroxamic acids are more acidic and slightly better lead chelators than hydroxamates, e.g., N-methylthioaceto-hydroxamic acid, pK{sub a} = 5.94, log{beta}{sub 120} = 10.92; acetohydroxamic acid, pK{sub a} = 9.34, log{beta}{sub l20} = 9.52. The syntheses of lead complexes of two bulky hydroxamate ligands are presented. The X-ray crystal structures show the lead hydroxamates are di-bridged dimers with irregular five-coordinate geometry about the metal atom and a stereochemically active lone pair of electrons. Molecular orbital calculations of a lead hydroxamate and a highly symmetric pseudo octahedral lead complex were performed. The thermodynamic stability of plutonium(IV) complexes of the siderophore, desferrioxamine B (DFO), and two octadentate derivatives of DFO were investigated using competition spectrophotometric titrations. The stability constant measured for the plutonium(IV) complex of DFO-methylterephthalamide is log{beta}{sub 110} = 41.7. The solubility limited speciation of {sup 242}Pu as a function of time in near neutral carbonate solution was measured. Individual solutions of plutonium in a single oxidation state were added to individual solutions at pH = 6.0, T = 30.0, 1.93 mM dissolved carbonate, and sampled over intervals up to 150 days. Plutonium solubility was measured, and speciation was investigated using laser photoacoustic spectroscopy and chemical methods.

  18. SECTION II: HEAVY ION REACTIONS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for heavy element production...II-1 P. K.Sahu, J. B. Natowitz, R. Wada, K. Hagel, T. Materna, Z. Chen, L. Qin, M. Barbui,...

  19. INL '@work' heavy equipment mechanic

    SciTech Connect (OSTI)

    Christensen, Cad

    2008-01-01

    INL's Cad Christensen is a heavy equipment mechanic. For more information about INL careers, visit http://www.facebook.com/idahonationallaboratory.

  20. INL '@work' heavy equipment mechanic

    ScienceCinema (OSTI)

    Christensen, Cad

    2013-05-28

    INL's Cad Christensen is a heavy equipment mechanic. For more information about INL careers, visit http://www.facebook.com/idahonationallaboratory.

  1. Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons

    DOE Patents [OSTI]

    Gordon, John Howard

    2014-09-09

    A method of upgrading an oil feedstock by removing heteroatoms and/or one or more heavy metals from the oil feedstock composition. This method reacts the oil feedstock with an alkali metal and an upgradant hydrocarbon. The alkali metal reacts with a portion of the heteroatoms and/or one or more heavy metals to form an inorganic phase separable from the organic oil feedstock material. The upgradant hydrocarbon bonds to the oil feedstock material and increases the number of carbon atoms in the product. This increase in the number of carbon atoms of the product increases the energy value of the resulting oil feedstock.

  2. Upgrading heavy oils by solvent dissolution and ultrafiltration

    SciTech Connect (OSTI)

    Osterhuber, E.J.

    1989-01-10

    A method is described for the separation of a heavy oil diluting the heavy oil with a solvent which is completely miscible with the heavy oil in an amount sufficient to completely dissolve the oil so as to produce an ultrafiltration feed; contacting the ultrafiltration feed with a first side of a continuous generally unswelled organic membrane selected from the group consisting of those comprising cellulose or polyvinylidine fluoride at a pressure between about 750 kPa and about 1500 kPa and at a temperature between 20/sup 0/C. and about 125/sup 0/C.; recovering a permeate fraction enriched in aromatic and saturated hydrocarbons from a second side of the membrane, and recovering a retentate fraction enriched in polar and metal-containing hydrocarbons from the first side of the membrane.

  3. Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty ...

  4. APBF-DEC Heavy Duty NOx Adsorber/DPF Project: Heavy Duty Linehaul...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy Duty NOx AdsorberDPF Project: Heavy Duty Linehaul Platform Project Update APBF-DEC Heavy Duty NOx AdsorberDPF Project: Heavy Duty Linehaul Platform Project Update 2003 DEER ...

  5. Final Technical Report, Grant DE-FG02-91ER45443: Heavy fermions and other highly correlated electron systems

    SciTech Connect (OSTI)

    Schlottmann, P.

    1998-10-12

    Properties of highly correlated electrons, such as heavy fermion compounds, metal-insulator transitions, one-dimensional conductors and systems of restricted dimensionality are studied theoretically. The main focus is on Kondo insulators and impurity bands due to Kondo holes, the low-temperature magnetoresistivity of heavy fermion alloys, the n-channel Kondo problem, mesoscopic systems and one-dimensional conductors.

  6. HEAVY ION LINEAR ACCELERATOR

    DOE Patents [OSTI]

    Van Atta, C.M.; Beringer, R.; Smith, L.

    1959-01-01

    A linear accelerator of heavy ions is described. The basic contributions of the invention consist of a method and apparatus for obtaining high energy particles of an element with an increased charge-to-mass ratio. The method comprises the steps of ionizing the atoms of an element, accelerating the resultant ions to an energy substantially equal to one Mev per nucleon, stripping orbital electrons from the accelerated ions by passing the ions through a curtain of elemental vapor disposed transversely of the path of the ions to provide a second charge-to-mass ratio, and finally accelerating the resultant stripped ions to a final energy of at least ten Mev per nucleon.

  7. Heavy Vehicle Propulsion Materials: Recent Progress and Future Plans

    SciTech Connect (OSTI)

    D. Ray Johnson; Sidney Diamond

    2001-05-14

    The Heavy Vehicle Propulsion Materials Program provides enabling materials technology for the U.S. DOE Office of Heavy Vehicle Technologies (OHVT). The technical agenda for the program is based on an industry assessment and the technology roadmap for the OHVT. A five-year program plan was published in 2000. Major efforts in the program are materials for diesel engine fuel systems, exhaust aftertreatment, and air handling. Additional efforts include diesel engine valve-train materials, structural components, and thermal management. Advanced materials, including high-temperature metal alloys, intermetallics, cermets, ceramics, amorphous materials, metal- and ceramic-matrix composites, and coatings, are investigated for critical engine applications. Selected technical issues and planned and ongoing projects as well as brief summaries of several technical highlights are given.

  8. Advances in heavy oil hydroprocessing

    SciTech Connect (OSTI)

    Mendizabal, O.B. )

    1988-06-01

    The world increase in heavy crudes has forced refiners to develop different processes that upgrade the yields and product properties recovered from these crudes. However, some of the optimized and new processes are not able to handle whole heavy crude oils, due to the high viscosity and corrosion of their long and short residues. The different processes for heavy crudes can be classified in two areas: physical (vg. Liquid Extraction) and chemical processes. The catalytic hydrotreating process, which belongs to this last classification, has demonstrated to be an economical upgrading process for heavy crude oil. This paper describes the development by the Mexican Petroleum Institute of the process to hydrotreat maya heavy crude. The effect of the operating conditions, the catalyst ---- development and the technical - economical analysis are presented. The product properties and yields are compared with the results obtained with light crude oil like isthmus.

  9. Metal inks

    DOE Patents [OSTI]

    Ginley, David S; Curtis, Calvin J; Miedaner, Alex; van Hest, Marinus Franciscus Antonius Maria; Kaydanova, Tatiana

    2014-02-04

    Self-reducing metal inks and systems and methods for producing and using the same are disclosed. In an exemplary embodiment, a method may comprise selecting metal-organic (MO) precursor, selecting a reducing agent, and dissolving the MO precursor and the reducing agent in an organic solvent to produce a metal ink that remains in a liquid phase at room temperature. Metal inks, including self-reducing and fire-through metal inks, are also disclosed, as are various applications of the metal inks.

  10. Analysis of heavy oils: Method development and application to Cerro Negro heavy petroleum

    SciTech Connect (OSTI)

    Carbognani, L.; Hazos, M.; Sanchez, V. ); Green, J.A.; Green, J.B.; Grigsby, R.D.; Pearson, C.D.; Reynolds, J.W.; Shay, J.Y.; Sturm, G.P. Jr.; Thomson, J.S.; Vogh, J.W.; Vrana, R.P.; Yu, S.K.T.; Diehl, B.H.; Grizzle, P.L.; Hirsch, D.E; Hornung, K.W.; Tang, S.Y.

    1989-12-01

    On March 6, 1980, the US Department of Energy (DOE) and the Ministry of Energy and Mines of Venezuela (MEMV) entered into a joint agreement which included analysis of heavy crude oils from the Venezuelan Orinoco oil belt.The purpose of this report is to present compositional data and describe new analytical methods obtained from work on the Cerro Negro Orinoco belt crude oil since 1980. Most of the chapters focus on the methods rather than the resulting data on Cerro Negro oil, and results from other oils obtained during the verification of the method are included. In addition, published work on analysis of heavy oils, tar sand bitumens, and like materials is reviewed, and the overall state of the art in analytical methodology for heavy fossil liquids is assessed. The various phases of the work included: distillation and determination of routine'' physical/chemical properties (Chapter 1); preliminary separation of >200{degree}C distillates and the residue into acid, base, neutral, saturated hydrocarbon and neutral-aromatic concentrates (Chapter 2); further separation of acid, base, and neutral concentrates into subtypes (Chapters 3-5); and determination of the distribution of metal-containing compounds in all fractions (Chapter 6).

  11. A novel process for upgrading heavy oil emulsions

    SciTech Connect (OSTI)

    Ng, F.T.T.; Rintjema, R.T.

    1994-12-31

    Canada has extensive reserves of high sulfur heavy oils. These heavy oils are recovered primarily by steam injection techniques. As a result, the heavy oils are obtained as emulsions at well-heads. The heavy oils, being high in sulfur and metals, and low in hydrogen to carbon atomic ratio, require upgrading such as desulfurization and hydrocracking before it can be used in conventional refineries. Conventional emulsion treatment and desulfurization technology require multistage processing. Thus, alternative technologies for processing heavy oil emulsions would be attractive. The authors have recently developed a novel single stage process for upgrading emulsions via activation of water to provide hydrogen in situ for catalytic desulfurization and hydrocracking. Current work is focused on the desulfurization aspect of upgrading, using benzothiophene as the model sulfur compound and molybdic acid as the catalyst. At 340 C and a CO loading pressure of 600 psi, up to 86% sulfur removal was obtained. As well, in situ generated H{sub 2} was found to be more active than externally supplied molecular H{sub 2}. A likely pathway for desulfurization of benzothiophene was via the initial hydrogenation of benzothiophene to dihydrobenzothiophene followed by hydrogenolysis to give ethylbenzene and H{sub 2}S.

  12. Heavy Isotopes Lead Materials Management Organization (LMMO)...

    Office of Scientific and Technical Information (OSTI)

    Heavy Isotopes Lead Materials Management Organization (LMMO) Update Citation Details In-Document Search Title: Heavy Isotopes Lead Materials Management Organization (LMMO) Update ...

  13. Heavy crudes, stocks pose desalting problems

    SciTech Connect (OSTI)

    Bartley, D.

    1982-02-02

    The design of electrostatic desalters for crudes lighter than 30 API is well established and is no longer considered a problem. However, since 1970, the number of desalting applications involving heavy crudes (less than 20 API), syncrudes, and residual fuels has increased markedly. These stocks present unique problems that require additional design considerations. All produced crude oils, including synthetic crude from shale, tar sands, and coal liquefaction, contain impurities that adversely affect production and refining processes, the equipment used in these processes, and the final products. The most common of these impurities are water, salt, solids, metals, and sulfur. The desalting process consists of (1) adding water with a low salt content (preferably fresh) to the feedstock; (2) adequately mixing this added water with the feedstock, which already contains some quantities of salty water, sediment, and/or crystalline salt; and (3) extracting as much water as possible from the feedstock.

  14. Silicone metalization

    DOE Patents [OSTI]

    Maghribi, Mariam N.; Krulevitch, Peter; Hamilton, Julie

    2008-12-09

    A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

  15. Silicone metalization

    DOE Patents [OSTI]

    Maghribi, Mariam N.; Krulevitch, Peter; Hamilton, Julie

    2006-12-05

    A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

  16. Heavy oil. upgrading integrated with steam drive

    SciTech Connect (OSTI)

    Van Driesen, R.; Viens, C.H.; Fornoff, L.L.

    1980-01-01

    A study of the upgrading of heavy oil from a representative Venezuelan Jobo crude (9.2/sup 0/API, 4.1% sulfur, and 500 ppm total metals) from the Orinoco area involved 110 computer simulations based on a modified C-E Lummus Refinery Linear Program model on the assumptions of a 125,000 bbl/day refinery built, starting at 1979 prices, for completion by 1986 near the producing field to supply the fuel oil needed to provide oil field steam. All of the upgrading systems were economically attractive; the per cent return-on-investment (ROI) before taxes for the methods studied were: for Lummus LC-Fining, 135.9%; for Exxon's FLEXICOKING, 132.4%; for delayed coking, 119.2%; and for deasphalting, 106.5%. LC-Fining provided the best over-all combination of flexibility, product yield, product quality, and return on investment. The economics favored upgrading to the maximum extent possible; there was a reduction in the ROI for all the upgrading systems when product specifications were lowered from the premium base case (1.2% SO/sub 2/ emitted per million Btu fired). The premium upgraded heavy crude oils should be worth $3.00-$3.50/bbl more than comparable conventional crude oils, could be of up to 27/sup 0/API, and could be substituted, at up to 50%, for conventional crude oils in a typical U.S. refinery.

  17. Method for improved decomposition of metal nitrate solutions

    DOE Patents [OSTI]

    Haas, P.A.; Stines, W.B.

    1981-01-21

    A method for co-conversion of aqueous solutions of one or more heavy metal nitrates is described, wherein thermal decomposition within a temperature range of about 300 to 800/sup 0/C is carried out in the presence of about 50 to 500% molar concentration of ammonium nitrate to total metal.

  18. Method for mobilization of hazardous metal ions in soils

    DOE Patents [OSTI]

    Dugan, Patrick R.; Pfister, Robert M.

    1995-01-01

    A microbial process for removing heavy metals such as bismuth, cadmium, lead, thorium, uranium and other transuranics from soils and sediments, utilizing indigenous, or isolates of indigenous, microorganisms and reducing agents, such as cysteine or sodium thioglycollate, or complexing agents such as the amino acid glycine, to effect the mobilization or release of the metals from the soil particles.

  19. METHOD OF COATING GRAPHITE WITH STABLE METAL CARBIDES AND NITRIDES

    DOE Patents [OSTI]

    Gurinsky, D.H.

    1959-10-27

    A method is presented for forming protective stable nitride and carbide compounds on the surface of graphite. This is accomplished by contacting the graphite surface with a fused heavy liquid metal such as bismuth or leadbismuth containing zirconium, titanium, and hafnium dissolved or finely dispersed therein to form a carbide and nitride of at least one of the dissolved metals on the graphite surface.

  20. Method for improved decomposition of metal nitrate solutions

    DOE Patents [OSTI]

    Haas, Paul A.; Stines, William B.

    1983-10-11

    A method for co-conversion of aqueous solutions of one or more heavy metal nitrates wherein thermal decomposition within a temperature range of about 300.degree. to 800.degree. C. is carried out in the presence of about 50 to 500% molar concentration of ammonium nitrate to total metal.

  1. Separation of heavy metals: Removal from industrial wastewaters...

    Office of Scientific and Technical Information (OSTI)

    WASTES; ION EXCHANGE; MEMBRANES; PRECIPITATION; VITRIFICATION; COMPLEXES; ELEMENTS; HYDROGEN COMPOUNDS; KINETICS; LIQUID WASTES; OXYGEN COMPOUNDS; REACTION KINETICS;...

  2. United abominations: Density functional studies of heavy metal chemistry

    SciTech Connect (OSTI)

    Schoendorff, George

    2012-04-02

    Carbonyl and nitrile addition to uranyl (UO{sup 2}{sup 2+}) are studied. The competition between nitrile and water ligands in the formation of uranyl complexes is investigated. The possibility of hypercoordinated uranyl with acetone ligands is examined. Uranyl is studied with diactone alcohol ligands as a means to explain the apparent hypercoordinated uranyl. A discussion of the formation of mesityl oxide ligands is also included. A joint theory/experimental study of reactions of zwitterionic boratoiridium(I) complexes with oxazoline-based scorpionate ligands is reported. A computational study was done of the catalytic hydroamination/cyclization of aminoalkenes with zirconium-based catalysts. Techniques are surveyed for programming for graphical processing units (GPUs) using Fortran.

  3. Mobility of Source Zone Heavy Metals and Radionuclides: The Mixed...

    Office of Scientific and Technical Information (OSTI)

    Authors: Gerlach, Robin 1 ; Peyton, Brent M. 1 ; Apel, William A. 2 + Show Author Affiliations Montana State Univ., Bozeman, MT (United States) Idaho National Lab., Idaho ...

  4. Mobility of Source Zone Heavy Metals and Radionuclides: The Mixed...

    Office of Scientific and Technical Information (OSTI)

    Authors: Apel, William ; Peyton, Brent ; Gerlach, Robin ; Lee, Brady Publication Date: 2006-06-01 OSTI Identifier: 896299 Report Number(s): ERSD-1027697-2006 R&D Project: ERSD ...

  5. SEPARATION OF HEAVY METALS: REMOVAL FROM INDUSTRIAL WASTEWATERS

    Office of Scientific and Technical Information (OSTI)

    ... with the high quality treated water ready for reuse* Because ion exchange is efficient in removal of dissolved solids from normally dilute spent rinse waters, it is well suited for ...

  6. SEPARATION OF HEAVY METALS: REMOVAL FROM INDUSTRIAL WASTEWATERS

    Office of Scientific and Technical Information (OSTI)

    ... Advantages of the cementation process include: * Simple control requirements. The demand ... Quaternized polyethylenimine had a good selectivity for Pd, Pt, Hg, and Au. Polythiourea ...

  7. Reducing volatilization of heavy metals in phosphate-pretreated...

    Office of Scientific and Technical Information (OSTI)

    The results showed that the volatilization behavior in phosphate-pretreated MSWI fly ash ... Resource Type: Journal Article Resource Relation: Journal Name: Waste Management; Journal ...

  8. Factors Affecting the Disposal Capacity of a Repository at Yucca Mountain

    SciTech Connect (OSTI)

    Nutt, W.M.; Peters, M.T.; Wigeland, R.A.; Kouts, C.; Kim, D.; Gomberg, S.

    2007-07-01

    The development of a repository at Yucca Mountain is proceeding in accordance with the Nuclear Waste Policy Act (NWPA). The current design of the proposed repository emplaces 63,000 metric tons of heavy metal (MTHM) of commercial spent nuclear fuel and 7,000 MTHM-equivalent of Department of Energy-owned spent nuclear fuel and high level nuclear waste. Efforts are underway to complete the pre-closure and postclosure safety analyses in accordance with 10 CFR 63. This will be included in a license application for construction of the repository that is currently planned to be submitted to the U.S. Nuclear Regulatory Commission (NRC) no later than June of 2008. The Global Nuclear Energy Partnership (GNEP) aims to 'recycle nuclear fuel using new proliferation-resistant technologies to recover more energy and reduce waste'. The Nation's decision to choose to recycle spent nuclear fuel in an advanced nuclear fuel cycle, such as that being considered under the GNEP, would present the opportunity to change the current approach for managing and disposing nuclear waste. The total amount of waste that could be disposed in a repository at Yucca Mountain would be a key component of a new waste management strategy should a decision be made in the future to utilize the proposed Yucca Mountain repository to dispose of wastes generated under the GNEP. (authors)

  9. Metal binding proteins, recombinant host cells and methods

    DOE Patents [OSTI]

    Summers, Anne O.; Caguiat, Jonathan J.

    2004-06-15

    The present disclosure provides artificial heavy metal binding proteins termed chelons by the inventors. These chelons bind cadmium and/or mercuric ions with relatively high affinity. Also disclosed are coding sequences, recombinant DNA molecules and recombinant host cells comprising those recombinant DNA molecules for expression of the chelon proteins. In the recombinant host cells or transgenic plants, the chelons can be used to bind heavy metals taken up from contaminated soil, groundwater or irrigation water and to concentrate and sequester those ions. Recombinant enteric bacteria can be used within the gastrointestinal tracts of animals or humans exposed to toxic metal ions such as mercury and/or cadmium, where the chelon recombinantly expressed in chosen in accordance with the ion to be rededicated. Alternatively, the chelons can be immobilized to solid supports to bind and concentrate heavy metals from a contaminated aqueous medium including biological fluids.

  10. Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Peer Evaluation PDF icon ace001musculus2011o.pdf More Documents & Publications Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Heavy-Duty ...

  11. Upgrading of heavy hydrocarbonaceous feeds

    SciTech Connect (OSTI)

    Bhattacharya, A.K.; Storm, D.A.; DeRosa, T.F.

    1995-12-31

    This paper is based on our work in the area of upgrading of heavy hydrocarbonaceous feedstocks. The work involves the development of a method of catalytically hydroconverting a hydrocarbon feed stream containing a substantial quantity of components boiling above about 538{degrees}C to a substantial portion thereof to components boiling below 538{degrees}C. More particularly, an oil-miscible or oil-soluble poly(ether)diol or a derivative thereof and an aromatic additive oil, such as Heavy Cycle Gas oil, are added to a heavy hydrocarbon feed and the mixed stream is contacted at elevated temperatures with a solid catalyst such as a sulfided nickel molybdenum oxide on alumina in the presence of hydrogen under pressure. This method advantageously affords higher conversion to more valuable liquid products containing lower amounts of heteroatoms such as sulfur, substantially eliminates plugging of the hydroconversion reactor, and reduces the amount of insolubles in the total liquid product.

  12. Heavy vehicle propulsion system materials program semiannual progress report for April 1999 through September 1999

    SciTech Connect (OSTI)

    Johnson, D.R.

    2000-01-01

    The purpose of the Heavy Vehicle Propulsion System Materials Program is the development of materials: ceramics, intermetallics, metal alloys, and metal and ceramic coatings, to support the dieselization of class 1-3 trucks to realize a 35% fuel-economy improvement over current gasoline-fueled trucks and to support commercialization of fuel-flexible LE-55 low-emissions, high-efficiency diesel engines for class 7-8 trucks.

  13. Upgrading Orinoco belt heavy oil

    SciTech Connect (OSTI)

    Alcantara, J.; Castillo, O.

    1982-09-01

    The Orinoco Heavy Oil Belt of Venezuela is a subsurface geological formation of petroleum-bearing sands that is approximately 700 km long and between 60 and 80 km wide. The results of recent explorations have shown the area to contain over one trillion barrels of oil in-place, ranging from 8/sup 0/ API to 14/sup 0/ APE gravity. In an effort to develop these resources, Petroleos de Venezuela has undertaken a program to evaluate and develop this heavy oil belt. The objectives of this program are discussed along with the process technology selection, pilot plants, and environmental protection measures. (JMT)

  14. Processing heavy crudes: advances in fluid and flexicoking technology

    SciTech Connect (OSTI)

    Allan, D.E.; Metrailer, W.J.; King, R.C.; Wiechert, S.

    1981-12-01

    The authors are concerned with Exxon's Fluid and Flexicoking processes which allow the refiner to convert the bottom of the crude barrel to clean products. This article primarily discusses enhancement of liquid yields from both processes and reduction of low-Btu gas from Flexicoking. Also discussed are recent advances in coking technology, which could make these processes more attractive. Flexicoking is an integrated coking/gasification process for upgrading heavy feedstocks. The process converts these feeds to a 99% yield of fuel gas, naphtha, middle distillates, heavy gas oil, and a low-sulfur coke gas. The remaining 1% is petroleum coke containing metals and other ash components present in the feed. 6 refs.

  15. Metal oxide films on metal

    DOE Patents [OSTI]

    Wu, Xin D. (Los Alamos, NM); Tiwari, Prabhat (Los Alamos, NM)

    1995-01-01

    A structure including a thin film of a conductive alkaline earth metal oxide selected from the group consisting of strontium ruthenium trioxide, calcium ruthenium trioxide, barium ruthenium trioxide, lanthanum-strontium cobalt oxide or mixed alkaline earth ruthenium trioxides thereof upon a thin film of a noble metal such as platinum is provided.

  16. Heavy Truck Engine Development & HECC | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications High Efficiency Clean Combustion for Heavy-Duty Engine High Efficiency Clean Combustion for Heavy-Duty Engine Heavy-Duty Engine Combustion ...

  17. The Search for Heavy Elements

    SciTech Connect (OSTI)

    2008-04-17

    The 1994 documentary "The Search for Heavy Elements" chronicles the expansion of the periodic table through the creation at Berkeley Lab of elements heavier than uranium. The documentary features a mix of rarely-seen archival footage, historical photos, and interviews with scientists who made history, such as Glenn Seaborg and Albert Ghiorso.

  18. The Search for Heavy Elements

    ScienceCinema (OSTI)

    None

    2010-01-08

    The 1994 documentary "The Search for Heavy Elements" chronicles the expansion of the periodic table through the creation at Berkeley Lab of elements heavier than uranium. The documentary features a mix of rarely-seen archival footage, historical photos, and interviews with scientists who made history, such as Glenn Seaborg and Albert Ghiorso.

  19. heavy_oil | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heavy Oil Heavy oil is a vast U.S. oil resource that is underexploited because its highly viscous nature renders it difficult to produce and to refine. As higher-gravity crudes ...

  20. Santa Fe Jets and Heavy Flavor Workshop

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Santa Fe Jets and Heavy Flavor Workshop Santa Fe Jets and Heavy Flavor Workshop WHEN: Jan 11, 2016 8:30 AM - Jan 13, 2016 5:30 PM WHERE: Inn and Spa at Loretto 211 Old Santa Fe...

  1. Strangeness signals in heavy ion collisions

    SciTech Connect (OSTI)

    Remsberg, L.P.

    1992-11-01

    The experimental data on strange meson and strange baryon production in relativistic heavy ion collisions are reviewed.

  2. Strangeness signals in heavy ion collisions

    SciTech Connect (OSTI)

    Remsberg, L.P.

    1992-01-01

    The experimental data on strange meson and strange baryon production in relativistic heavy ion collisions are reviewed.

  3. Dendritic metal nanostructures

    DOE Patents [OSTI]

    Shelnutt, John A.; Song, Yujiang; Pereira, Eulalia F.; Medforth, Craig J.

    2010-08-31

    Dendritic metal nanostructures made using a surfactant structure template, a metal salt, and electron donor species.

  4. Heavy flavor production from photons and hadrons

    SciTech Connect (OSTI)

    Heusch, C.A.

    1982-01-01

    The present state of the production and observation of hadrons containing heavy quarks or antiquarks as valence constituents, in reactions initiated by real and (space-like) virtual photon or by hadron beams is discussed. Heavy flavor production in e/sup +/e/sup -/ annihilation, which is well covered in a number of recent review papers is not discussed, and similarly, neutrino production is omitted due to the different (flavor-changing) mechanisms that are involved in those reactions. Heavy flavors from spacelike photons, heavy flavors from real photons, and heavy flavors from hadron-hadron collisions are discussed. (WHK)

  5. Evaluation of FSV-1 cask for the transport of LWR irradiated fuel assemblies

    SciTech Connect (OSTI)

    Not Available

    1980-05-01

    The Model FSV-1 spent fuel shipping cask was designed by General Atomic Company (GA) to service the Fort St. Vrain (FSV) nuclear generating station, a High Temperature Gas Reactor (HTGR) owned and operated by Public Service Company of Colorado (PSC). This report presents an evaluation of the suitability of the FSV-1 cask for the transport of irradiated Light Water Reactor (LWR) fuel assemblies from both Pressurized Water Reactors (PWR) and Boiling Water Reactors (BWR). The FSV-1 cask evaluation parameters covered a wide spectrum of LWR fuel assemblies, based on burnup in Megawatt Days/Metric Ton of Heavy Metal (MWD/MTHM) and years of decay since irradiation. The criteria for suitability included allowable radiation dose rates, cask surface and interior temperatures and the Gross Vehicle Weight (GVW) of the complete shipping system.

  6. Metal hydrides

    SciTech Connect (OSTI)

    Carnes, J.R.; Kherani, N.P.

    1987-11-01

    Metal hydride information is not available for most hydrides in a consolidated quick-reference source. This report's objective is to fill the need for such a document providing basic thermodynamic data for as many metal hydrides as possible. We conduced a computerized library search to access as many sources as possible and screened each source for such thermodynamic data as pressure-temperature graphs, van't Hoff curves, and impurity effects. We included any other relevant information and commented on it. A primary concern to be investigated in the future is the behavior of metal tritides. This would be important in the area of emergency tritium cleanup systems. The hydride graphs are useful, however, as tritides may be expected in most cases to behave similarly and at least follow trends of their respective hydrides. 42 refs., 40 figs., 5 tabs.

  7. Heavy Ion Inertial Fusion Energy: Summaries of Program Elements

    SciTech Connect (OSTI)

    Friedman, A; Barnard, J J; Kaganovich, I; Seidl, P A; Briggs, R J; Faltens, A; Kwan, J W; Lee, E P; Logan, B G

    2011-02-28

    The goal of the Heavy Ion Fusion (HIF) Program is to apply high-current accelerator technology to IFE power production. Ion beams of mass {approx}100 amu and kinetic energy {>=} 1 GeV provide efficient energy coupling into matter, and HIF enjoys R&D-supported favorable attributes of: (1) the driver, projected to be robust and efficient; see 'Heavy Ion Accelerator Drivers.'; (2) the targets, which span a continuum from full direct to full indirect drive (and perhaps fast ignition), and have metal exteriors that enable injection at {approx}10 Hz; see 'IFE Target Designs'; (3) the near-classical ion energy deposition in the targets; see 'Beam-Plasma Interactions'; (4) the magnetic final lens, robust against damage; see 'Final Optics-Heavy Ion Beams'; and (5) the fusion chamber, which may use neutronically-thick liquids; see 'Liquid-Wall Chambers.' Most studies of HIF power plants have assumed indirect drive and thick liquid wall protection, but other options are possible.

  8. Heavy oil upgrading via fluidized bed processing and hydrogenation processing

    SciTech Connect (OSTI)

    Dawson, F.N. Jr.

    1995-09-01

    California is the second largest crude oil producer in the lower 48 states. Nearly half of its production is heavy oil, difficult to transport and costly to refine. Given better methods of processing, production could be expanded. Likewise, huge worldwide reserves of heavy oils could be better exploited if more attractive processing methods were available. Midway Sunset crude at 11.8 API gravity, is a fairly difficult crude to process. It has about 1.5 percent sulfur, a very high nitrogen content, in the range of 0.7--0.8%, and metals of approximately 120--170 ppm, vanadium plus nickel. The authors will be reporting here results of the pilot plant testing to see whether non-catalytic fluid bed cracking technology, operated at low conversion, followed by hydrogenation would be economically attractive. Results suggest that this approach is competitive with delayed coking and with atmospheric resid desulfurization. This approach successfully combines carbon removal and hydrogen addition techniques for heavy oil upgrading. Comparative yields, product quality and economic considerations are reviewed in this study.

  9. METAL COMPOSITIONS

    DOE Patents [OSTI]

    Seybolt, A.U.

    1959-02-01

    Alloys of uranium which are strong, hard, and machinable are presented, These alloys of uranium contain bctween 0.1 to 5.0% by weight of at least one noble metal such as rhodium, palladium, and gold. The alloys may be heat treated to obtain a product with iniproved tensile and compression strengths,

  10. Heat-driven spin transport in a ferromagnetic metal

    SciTech Connect (OSTI)

    Xu, Yadong; Yang, Bowen; Tang, Chi; Jiang, Zilong; Shi, Jing; Schneider, Michael; Whig, Renu

    2014-12-15

    As a non-magnetic heavy metal is attached to a ferromagnet, a vertically flowing heat-driven spin current is converted to a transverse electric voltage, which is known as the longitudinal spin Seebeck effect (SSE). If the ferromagnet is a metal, this voltage is also accompanied by voltages from two other sources, i.e., the anomalous Nernst effect in both the ferromagnet and the proximity-induced ferromagnetic boundary layer. By properly identifying and carefully separating those different effects, we find that in this pure spin current circuit the additional spin current drawn by the heavy metal generates another significant voltage by the ferromagnetic metal itself which should be present in all relevant experiments.

  11. Composite metal membrane

    DOE Patents [OSTI]

    Peachey, N.M.; Dye, R.C.; Snow, R.C.; Birdsell, S.A.

    1998-04-14

    A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

  12. Composite metal membrane

    DOE Patents [OSTI]

    Peachey, Nathaniel M.; Dye, Robert C.; Snow, Ronny C.; Birdsell, Stephan A.

    1998-01-01

    A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

  13. Final Report: Role of microbial synergies in immobilization of metals

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Final Report: Role of microbial synergies in immobilization of metals Citation Details In-Document Search Title: Final Report: Role of microbial synergies in immobilization of metals This Subsurface Microbial Ecology and Community Dynamics project tested the following hypothesis: synergistic groups of microorganisms immobilize heavy elements more efficiently than do individual species. We focused on groundwater at several DOE FRC and their microbial

  14. Method for mobilization of hazardous metal ions in soils

    DOE Patents [OSTI]

    Dugan, P.R.; Pfister, R.M.

    1995-06-27

    A microbial process is revealed for removing heavy metals such as bismuth, cadmium, lead, thorium, uranium and other transuranics from soils and sediments. The method utilizes indigenous, or isolates of indigenous, microorganisms and reducing agents, such as cysteine or sodium thioglycollate, or complexing agents such as the amino acid glycine, to effect the mobilization or release of the metals from the soil particles. 5 figs.

  15. SECTION II. HEAVY ION REACTIONS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    II. HEAVY ION REACTIONS Dynamic Evolution and the Caloric Curve for Medium Mass Nuclei J. Cibor, R. Wada, K. Hagel, M. Lunardon, N. Marie, R. Alfaro, W. Shen, B. Xiao, Y. Zhao, J. Li, M. Murray, J.B. Natowitz, Z. Majka and P. Staszel Search for 5He Emission from Hot Compound Nuclei R. Charity and L.G. Sobotka for the Washington University, NSCL, Legnaro, Padova, TAMU Collaboration IMF Production in 64Zn + 58Ni at 35A-79A MeV R. Wada, K. Hagel, J. Cibor, J. Li, M. Murray, J.B. Natowitz, A. Ono

  16. Upgrading Orinoco Belt heavy oil

    SciTech Connect (OSTI)

    Aliantara, J.; Castillo, O.

    1982-05-01

    Petroleos de Venezuela, S.A. (PDVSA), in an effort to develop new oil resources, has undertaken a program to evaluate and develop the Orinoco Heavy Oil Belt, in the eastern part of Venezuela. Lagoven, S.A., a subsidiary of PDVSA, has been assigned the responsibility for developing and upgrading part of the Orinoco belt. This paper describes the most relevant aspects of Lagoven's first upgrading module, a facility that will convert Orinoco oil into a premium crude with a very high yield of products of great market demand.

  17. Heavy Gas Dispersion Incompressible Flow

    Energy Science and Technology Software Center (OSTI)

    1992-01-27

    FEM3 is a numerical model developed primarily to simulate heavy gas dispersion in the atmosphere, such as the gravitational spread and vapor dispersion that result from an accidental spill of liquefied natural gas (LNG). FEM3 solves both two and three-dimensional problems and, in addition to the generalized anelastic formulation, includes options to use either the Boussinesq approximation or an isothermal assumption, when appropriate. The FEM3 model is composed of three parts: a preprocessor PREFEM3, themore » main code FEM3, and two postprocessors TESSERA and THPLOTX.« less

  18. APEX heavy-ion counters

    SciTech Connect (OSTI)

    Mercer, D.J.

    1993-10-01

    A large solid-angle array of low-pressure multi-wire proportional counters (LPMWPC) forms part of the APEX apparatus. Eight three-element trapezoidal counters provide 360{degrees} coverage in {phi} and 20{degrees} - 70{degrees} coverage in {phi}. Angle information is obtained from a transmission-line delay cathode ({phi}) and from the segmentation ({phi}). Time-of-flight information is obtained from the anode signals. These quantities are used to extract the center-of-mass scattering angle, reaction Q value, and masses of the scattered heavy ions. Design and performance of the counters will be discussed.

  19. SOVENT BASED ENHANCED OIL RECOVERY FOR IN-SITU UPGRADING OF HEAVY OIL SANDS

    SciTech Connect (OSTI)

    Munroe, Norman

    2009-01-30

    With the depletion of conventional crude oil reserves in the world, heavy oil and bitumen resources have great potential to meet the future demand for petroleum products. However, oil recovery from heavy oil and bitumen reservoirs is much more difficult than that from conventional oil reservoirs. This is mainly because heavy oil or bitumen is partially or completely immobile under reservoir conditions due to its extremely high viscosity, which creates special production challenges. In order to overcome these challenges significant efforts were devoted by Applied Research Center (ARC) at Florida International University and The Center for Energy Economics (CEE) at the University of Texas. A simplified model was developed to assess the density of the upgraded crude depending on the ratio of solvent mass to crude oil mass, temperature, pressure and the properties of the crude oil. The simplified model incorporated the interaction dynamics into a homogeneous, porous heavy oil reservoir to simulate the dispersion and concentration of injected CO2. The model also incorporated the characteristic of a highly varying CO2 density near the critical point. Since the major challenge in heavy oil recovery is its high viscosity, most researchers have focused their investigations on this parameter in the laboratory as well as in the field resulting in disparaging results. This was attributed to oil being a complex poly-disperse blend of light and heavy paraffins, aromatics, resins and asphaltenes, which have diverse behaviors at reservoir temperature and pressures. The situation is exacerbated by a dearth of experimental data on gas diffusion coefficients in heavy oils due to the tedious nature of diffusivity measurements. Ultimately, the viscosity and thus oil recovery is regulated by pressure and its effect on the diffusion coefficient and oil swelling factors. The generation of a new phase within the crude and the differences in mobility between the new crude matrix and the precipitate readily enables removal of asphaltenes. Thus, an upgraded crude low in heavy metal, sulfur and nitrogen is more conducive for further purification.

  20. Mitsubishi Heavy Industries Ltd | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: Mitsubishi Heavy Industries Ltd Place: Tokyo, Tokyo, Japan Zip: 108 8215 Product: Integrated technology company and power equipment supplier....

  1. Heavy Water Test Reactor Dome Removal

    SciTech Connect (OSTI)

    2011-01-01

    A high speed look at the removal of the Heavy Water Test Reactor Dome Removal. A project sponsored by the Recovery Act on the Savannah River Site.

  2. Heavy Mobile Equipment Mechanic (1 Mechanic Shop)

    Broader source: Energy.gov [DOE]

    A successful candidate will perform preventative, predictive, and corrective maintenance on Bonneville Power Administration (BPA's) light and heavy mobile equipment in maintenance and filed...

  3. Heavy Mobile Equipment Mechanic (One Mechanic Shop)

    Broader source: Energy.gov [DOE]

    Join the Bonneville Power Administration (BPA) for a challenging and rewarding career, while working, living, and playing in the Pacific Northwest. The Heavy Mobile Equipment Mechanic (One Mechanic...

  4. Visualizing the Onset of "Heavy Electron" Superconductivity ...

    Office of Science (SC) Website

    Visualizing the Onset of "Heavy Electron" Superconductivity Basic Energy Sciences (BES) BES Home ... Funding DOE Office of Science, Basic Energy Sciences program provided primary ...

  5. Radical scavengers from heavy hydrocarbons

    SciTech Connect (OSTI)

    Kubo, Junichi

    1996-10-01

    The hydrogen-donating properties of some hydrocarbons form the basis for processes such as coal liquefaction and heavy oil upgrading. However, these hydrocarbons have seldom been used for other purposes, because their potential applications have not been well recognized. Research has indicated that these hydrogen-donating hydrocarbons can be used in important reactions as radical scavengers and have properties particular to those of pure hydrocarbons without functional groups containing heteroatoms. Over years of study researchers have found that pure hydrocarbons with radical-scavenging effects nearly as high as those in conventional hindered phenolic antioxidants can be produced from petroleum, and these hydrogen-donating hydrocarbons exhibit such effects even in oxidative atmospheres (i.e., they function as antioxidants). He has also shown that these mixtures have some properties particular to pure hydrocarbons without functional groups containing heteroatoms, and they`ve seen that a mechanism based on the steric effects appears when these hydrocarbons are used in heavy oil hydroprocessing. Hydrogen-donating hydrocarbons should be a viable resource in many applications. In this article, he presents radical-scavenging abilities, characteristics as pure hydrocarbons, and applications on the basis of the studies.

  6. Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion

    Broader source: Energy.gov (indexed) [DOE]

    Modeling | Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace001_musculus_2011_o.pdf More Documents & Publications Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling High Efficiency Fuel Reactivity Controlled Compression Ignition Combustion

  7. Metal dusting

    SciTech Connect (OSTI)

    Edited by K. Natesan

    2004-01-01

    This workshop was held soon after the September 11th incident under a climate of sorrow and uncertainty among the people of the world, in particular the Workshop participants and their host organizations. With considerable help from the partiicpants, the Workshop was conducted as planed and we had excellent participation in spite of the circumstances. A good fraction of the attendees in the Workshop were from abroad and from several industries, indicating the importance and relevance of the subject for the chemical process industry. Degradation of structural metallic alloys by metal dusting has been an issue for over 40 years in the chemical, petrochemical, syngas, and iron ore reduction plants. However, the fundamental scientific reasons for the degradation of complex alloys in high carbon activity environments are not clear. one of the major parameters of importance is the variation in gas chemistry in both the laboratory experiments and in the plant-service environments. the industry has questioned the applicability of the laboratory test data, obtained in low steam environments, in assessment and life prediction for the materials in plant service where the environments contain 25-35% steam. Several other variables such as system pressure, gas flow velocity, incubation time, alloy chemistry, surface finish, and weldments, were also identified in the literature as to having an effect on the initiatino and propagation of metal dusting attack. It is the purpose of this Workshop to establish a forum in which the researchers from scientific and industrial laboratories, alloy manufacturers, end users, and research and development sponsors can exchange information, discuss different points of view, prioritize the issues, and to elaborate on the trends in industry for the future. We believe that we accomplished these goals successfully and sincerely thank the participants for their contributions.

  8. Heavy Vehicle Technologies Program Retrospective and Outlook

    SciTech Connect (OSTI)

    James J. Eberhardt

    1999-04-10

    OHVT Mission is to conduct, in collaboration with our heavy vehicle industry partners and their suppliers, a customer-focused national program to research and develop technologies that will enable trucks and other heavy vehicles to be more energy efficient and able to use alternative fuels while simultaneously reducing emissions.

  9. A Heavy Flavor Tracker for STAR

    SciTech Connect (OSTI)

    Xu, Z.; Chen, Y.; Kleinfelder, S.; Koohi, A.; Li, S.; Huang, H.; Tai, A.; Kushpil, V.; Sumbera, M.; Colledani, C.; Dulinski, W.; Himmi,A.; Hu, C.; Shabetai, A.; Szelezniak, M.; Valin, I.; Winter, M.; Surrow,B.; Van Nieuwenhuizen, G.; Bieser, F.; Gareus, R.; Greiner, L.; Lesser,F.; Matis, H.S.; Oldenburg, M.; Ritter, H.G.; Pierpoint, L.; Retiere, F.; Rose, A.; Schweda, K.; Sichtermann, E.; Thomas, J.H.; Wieman, H.; Yamamoto, E.; Kotov, I.

    2005-03-14

    We propose to construct a Heavy Flavor Tracker (HFT) for the STAR experiment at RHIC. The HFT will bring new physics capabilities to STAR and it will significantly enhance the physics capabilities of the STAR detector at central rapidities. The HFT will ensure that STAR will be able to take heavy flavor data at all luminosities attainable throughout the proposed RHIC II era.

  10. Design of heavy oil upgrading units

    SciTech Connect (OSTI)

    Farrell, W.D.; Phodes, R.P.; Zeno, D.Y.

    1985-01-01

    Heavy oil upgrading has become an increasingly important aspect of ER and E's research. Due to high costs of experimental catalysts, small catalyst charges are used (20-150cc). Tubular design and tree-stage stirred design are discussed with emphasis on the techniques and equipment used to handle heavy oil. Mechanical design and fluid mechanics are discussed.

  11. Heavy Duty Vehicle Futures Analysis.

    SciTech Connect (OSTI)

    Askin, Amanda Christine; Barter, Garrett; West, Todd H.; Manley, Dawn Kataoka

    2014-05-01

    This report describes work performed for an Early Career Research and Development project. This project developed a heavy-duty vehicle (HDV) sector model to assess the factors influencing alternative fuel and efficiency technology adoption. This model builds on a Sandia light duty vehicle sector model and provides a platform for assessing potential impacts of technological advancements developed at the Combustion Research Facility. Alternative fuel and technology adoption modeling is typically developed around a small set of scenarios. This HDV sector model segments the HDV sector and parameterizes input values, such as fuel prices, efficiencies, and vehicle costs. This parameterization enables sensitivity and trade space analyses to identify the inputs that are most associated with outputs of interest, such as diesel consumption and greenhouse gas emissions. Thus this analysis tool enables identification of the most significant HDV sector drivers that can be used to support energy security and climate change goals.

  12. HEAVY WATER MODERATED NEUTRONIC REACTOR

    DOE Patents [OSTI]

    Szilard, L.

    1958-04-29

    A nuclear reactor of the type which utilizes uranium fuel elements and a liquid coolant is described. The fuel elements are in the form of elongated tubes and are disposed within outer tubes extending through a tank containing heavy water, which acts as a moderator. The ends of the fuel tubes are connected by inlet and discharge headers, and liquid bismuth is circulated between the headers and through the fuel tubes for cooling. Helium is circulated through the annular space between the outer tubes in the tank and the fuel tubes to cool the water moderator to prevent boiling. The fuel tubes are covered with a steel lining, and suitable control means, heat exchange means, and pumping means for the coolants are provided to complete the reactor assembly.

  13. Heavy Gas Dispersion Incompressible Flow

    Energy Science and Technology Software Center (OSTI)

    1992-02-03

    FEM3 is a numerical model developed primarily to simulate heavy gas dispersion in the atmosphere, such as the gravitational spread and vapor dispersion that result from an accidental spill of liquefied natural gas (LNG). FEM3 solves both two and three-dimensional problems and, in addition to the generalized anelastic formulation, includes options to use either the Boussinesq approximation or an isothermal assumption, when appropriate. The FEM3 model is composed of three parts: a preprocessor PREFEM3, themore » main code FEM3, and two postprocessors TESSERA and THPLOTX. The DEC VAX11 version contains an auxiliary program, POLYREAD, which reads the polyplot file created by FEM3.« less

  14. Progress in Heavy Ion Fusion

    SciTech Connect (OSTI)

    Herrmannsfeldt, W.B.

    1988-09-01

    The progress of the field of Heavy Ion Fusion has been documented in the proceedings of the series of International Symposia that, in recent years, have occurred every second year. The latest of these conferences was hosted by Gesellshaft fuer Schwerionenforshung (GSI) in Darmstadt, West Germany, June 28-30, 1988. For this report, a few highlights from the conference are selected, stressing experimental progress and prospects for future advances. A little extra time is devoted to report on the developments at the Lawrence Berkeley Laboratory (LBL) which is the center for most of the HIFAR program. The Director of the HIFAR program at LBL is Denis Keefe, who presented the HIF report at the last two of the meetings in this series, and in whose place the author is appearing now. 4 refs., 1 fig.

  15. Process for recovering evolved hydrogen enriched with at least one heavy hydrogen isotope

    DOE Patents [OSTI]

    Tanaka, John; Reilly, Jr., James J.

    1978-01-01

    This invention relates to a separation means and method for enriching a hydrogen atmosphere with at least one heavy hydrogen isotope by using a solid titaniun alloy hydride. To this end, the titanium alloy hydride containing at least one metal selected from the group consisting of vanadium, chromium, manganese, molybdenum, iron, cobalt and nickel is contacted with a circulating gaseous flow of hydrogen containing at least one heavy hydrogen isotope at a temperature in the range of -20.degree. to +40.degree. C and at a pressure above the dissociation pressure of the hydrided alloy selectively to concentrate at least one of the isotopes of hydrogen in the hydrided metal alloy. The contacting is continued until equilibrium is reached, and then the gaseous flow is isolated while the temperature and pressure of the enriched hydride remain undisturbed selectively to isolate the hydride. Thereafter, the enriched hydrogen is selectively recovered in accordance with the separation factor (S.F.) of the alloy hydride employed.

  16. QCD mechanisms for heavy particle production

    SciTech Connect (OSTI)

    Brodsky, S.J.

    1985-09-01

    For very large pair mass, the production of heavy quarks and supersymmetric particles is expected to be governed by ACD fusion subprocesses. At lower mass scales other QCD mechanisms such as prebinding distortion and intrinsic heavy particle Fock states can become important, possibly accounting for the anomalies observed for charm hadroproduction. We emphasize the importance of final-state Coulomb interactions at low relative velocity in QCD and predict the existence of heavy narrow four quark resonances (c c-bar u u-bar) and (cc c-bar c-bar) in ..gamma gamma.. reactions. Coherent QCD contributions are discussed as a contribution to the non-additivity of nuclear structure functions and heavy particle production cross sections. We also predict a new type of amplitude zero for exclusive heavy meson pair production which follows from the tree-graph structure of QCD. 35 refs., 8 figs., 1 tab.

  17. Mechanochemical processing for metals and metal alloys

    DOE Patents [OSTI]

    Froes, Francis H.; Eranezhuth, Baburaj G.; Prisbrey, Keith

    2001-01-01

    A set of processes for preparing metal powders, including metal alloy powders, by ambient temperature reduction of a reducible metal compound by a reactive metal or metal hydride through mechanochemical processing. The reduction process includes milling reactants to induce and complete the reduction reaction. The preferred reducing agents include magnesium and calcium hydride powders. A process of pre-milling magnesium as a reducing agent to increase the activity of the magnesium has been established as one part of the invention.

  18. Heavy vehicle propulsion system materials program semiannual progress report for April 1998 thru September 1998

    SciTech Connect (OSTI)

    Johnson, D.R.

    1999-01-01

    The purpose of the Heavy Vehicle Propulsion System Materials Program is the development of materials: ceramics, intermetallics, metal alloys, and metal and ceramic coatings, to support the dieselization of class 1--3 trucks to realize a 35{percent} fuel-economy improvement over current gasoline-fueled trucks and to support commercialization of fuel-flexible LE-55 low-emissions, high-efficiency diesel engines for class 7--8 trucks. The Office of Transportation Technologies, Office of Heavy Vehicle Technologies (OTT OHVT) has an active program to develop the technology for advanced LE-55 diesel engines with 55{percent} efficiency and low emissions levels of 2.0 g/bhp-h NO{sub x} and 0.05 g/bhp-h particulates. The goal is also for the LE-55 engine to run on natural gas with efficiency approaching that of diesel fuel. The LE-55 program is being completed in FY 1997 and, after approximately 10 years of effort, has largely met the program goals of 55{percent} efficiency and low emissions. However, the commercialization of the LE-55 technology requires more durable materials than those that have been used to demonstrate the goals. Heavy Vehicle Propulsion System Materials will, in concert with the heavy-duty diesel engine companies, develop the durable materials required to commercialize the LE-55 technologies.

  19. High Efficiency Clean Combustion for Heavy-Duty Engine | Department...

    Broader source: Energy.gov (indexed) [DOE]

    PDF icon deer09zhang.pdf More Documents & Publications Heavy Truck Engine Development & HECC High Efficiency Clean Combustion for Heavy-Duty Engine Heavy-Duty Engine Combustion ...

  20. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trending: Metal Oxo Bonds Trending: Metal Oxo Bonds Print Wednesday, 29 May 2013 00:00 Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides

  1. Metal filled porous carbon

    DOE Patents [OSTI]

    Gross, Adam F.; Vajo, John J.; Cumberland, Robert W.; Liu, Ping; Salguero, Tina T.

    2011-03-22

    A porous carbon scaffold with a surface and pores, the porous carbon scaffold containing a primary metal and a secondary metal, where the primary metal is a metal that does not wet the surface of the pores of the carbon scaffold but wets the surface of the secondary metal, and the secondary metal is interspersed between the surface of the pores of the carbon scaffold and the primary metal.

  2. Extracting metals directly from metal oxides

    DOE Patents [OSTI]

    Wai, Chien M.; Smart, Neil G.; Phelps, Cindy

    1997-01-01

    A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of .beta.-diketones, halogenated .beta.-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process.

  3. Extracting metals directly from metal oxides

    DOE Patents [OSTI]

    Wai, C.M.; Smart, N.G.; Phelps, C.

    1997-02-25

    A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of {beta}-diketones, halogenated {beta}-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process. 4 figs.

  4. Checkerboard seed-blanket thorium fuel core concepts for heavy...

    Office of Scientific and Technical Information (OSTI)

    concepts for heavy water moderated reactors Citation Details In-Document Search Title: Checkerboard seed-blanket thorium fuel core concepts for heavy water moderated reactors ...

  5. Accident analysis of heavy water cooled thorium breeder reactor...

    Office of Scientific and Technical Information (OSTI)

    Accident analysis of heavy water cooled thorium breeder reactor Citation Details In-Document Search Title: Accident analysis of heavy water cooled thorium breeder reactor ...

  6. The Silicon Vertex Tracker for the Heavy Photon Search Experiment...

    Office of Scientific and Technical Information (OSTI)

    Silicon Vertex Tracker for the Heavy Photon Search Experiment Citation Details In-Document Search Title: The Silicon Vertex Tracker for the Heavy Photon Search Experiment Authors: ...

  7. Heavy Duty Vehicle In-Use Emission Performance | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    Evaluating Exhaust Emission Performance of Urban Buses Using Transient Heavy-Duty Chassis Dynamometer Fuel Efficiency of New European HD Vehicles HEAVY-DUTY TRUCK EMISSIONS AND ...

  8. HEAVY-DUTY TRUCK EMISSIONS AND FUEL CONSUMPTION SIMULATING REAL...

    Broader source: Energy.gov (indexed) [DOE]

    Evaluating Exhaust Emission Performance of Urban Buses Using Transient Heavy-Duty Chassis Dynamometer Heavy Duty Vehicle In-Use Emission Performance Fuel Efficiency of New European ...

  9. QCD Prediction for Heavy Boson Transverse Momentum Distributions...

    Office of Scientific and Technical Information (OSTI)

    QCD Prediction for Heavy Boson Transverse Momentum Distributions Citation Details In-Document Search Title: QCD Prediction for Heavy Boson Transverse Momentum Distributions We ...

  10. Recent Developments in Heavy Quark and Quarkonium Production...

    Office of Scientific and Technical Information (OSTI)

    Conference: Recent Developments in Heavy Quark and Quarkonium Production Citation Details In-Document Search Title: Recent Developments in Heavy Quark and Quarkonium Production ...

  11. Triangularity and dipole asymmetry in relativistic heavy ion...

    Office of Scientific and Technical Information (OSTI)

    Triangularity and dipole asymmetry in relativistic heavy ion collisions Citation Details In-Document Search Title: Triangularity and dipole asymmetry in relativistic heavy ion ...

  12. Heavy Quarks, QCD, and Effective Field Theory Thomas Mehen 72...

    Office of Scientific and Technical Information (OSTI)

    Heavy Quarks, QCD, and Effective Field Theory Thomas Mehen 72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS; 73 NUCLEAR PHYSICS AND RADIATION PHYSICS Heavy Quarks, Quarkonium,...

  13. Heavy-Duty Powertrain and Vehicle Development - A Look Toward...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy-Duty Powertrain and Vehicle Development - A Look Toward 2020 Globalization in emissions regulation will be driving freight efficiency improvements and will require heavy-duty ...

  14. Two-dimensional heavy fermions on the strongly correlated boundaries...

    Office of Scientific and Technical Information (OSTI)

    Two-dimensional heavy fermions on the strongly correlated boundaries of Kondo topological insulators Prev Next Title: Two-dimensional heavy fermions on the strongly ...

  15. Vehicle Technologies Office Merit Review 2014: Advanced Heavy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Heavy-Duty Engine Systems and Emissions Control Modeling and Analysis Vehicle Technologies Office Merit Review 2014: Advanced Heavy-Duty Engine Systems and Emissions ...

  16. Development and Demonstration of Fischer-Tropsch Fueled Heavy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fischer-Tropsch Fueled Heavy-Duty Vehicles with Control Technologies for Reduced Diesel Exhaust Emissions Development and Demonstration of Fischer-Tropsch Fueled Heavy-Duty ...

  17. WORKSHOP REPORT: Trucks and Heavy-Duty Vehicles Technical Requirements...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Trucks and Heavy-Duty Vehicles Technical Requirements and Gaps for Lightweight and Propulsion Materials WORKSHOP REPORT: Trucks and Heavy-Duty Vehicles Technical Requirements and ...

  18. Fuel Efficiency and Emissions Optimization of Heavy-Duty Diesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Emissions Optimization of Heavy-Duty Diesel Engines using Model-Based Transient Calibration Fuel Efficiency and Emissions Optimization of Heavy-Duty Diesel Engines using ...

  19. Medium- and Heavy-Duty Electric Drive Vehicle Simulation and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Medium- and Heavy-Duty Electric Drive Vehicle Simulation and Analysis Medium- and Heavy-Duty Electric Drive Vehicle Simulation and Analysis 2011 DOE Hydrogen and Fuel Cells ...

  20. Implications of naturalness for the heavy Higgs bosons of supersymmetr...

    Office of Scientific and Technical Information (OSTI)

    Implications of naturalness for the heavy Higgs bosons of supersymmetry Citation Details In-Document Search Title: Implications of naturalness for the heavy Higgs bosons of ...

  1. Heavy quarkonium in a holographic basis (Journal Article) | DOE...

    Office of Scientific and Technical Information (OSTI)

    Heavy quarkonium in a holographic basis Title: Heavy quarkonium in a holographic basis Authors: Li, Yang Search DOE PAGES for author "Li, Yang" Search DOE PAGES for ORCID ...

  2. A new hydrocracking catalyst for heavy oil upgrading

    SciTech Connect (OSTI)

    Itoh, T. )

    1987-04-01

    In comparison with ordinary oil, tar sands bitumen and vacuum residue contain large quantities of impurities such as asphaltene, heavy metal compounds, sulfur, and nitrogen, which are obstacles to upgrading the refining process. Therefore, these types of materials are extremely difficult to treat with existing refining technologies. In order to upgrade oil feedstocks that are of poor quality, such as tar sands bitumen, new upgrading technologies must be established. In this paper, the author discusses first, the results of catalyst screening, second, the factors of the active catalyst, and finally, the performance of a semi-industrially produced catalyst. The catalyst has high middle-distillate yield, coke plus gum (coke precursors) suppressing ability, low hydrogen consumption and mechanical strength and high temperature stability in slurry reactors.

  3. Dynacracking process first commerical application for upgrading heavy oils

    SciTech Connect (OSTI)

    Dawson, F.N. Jr.

    1981-01-01

    The Dynacracking process developed by Hydrocarbon Research, Inc., is a non-catalytic process capable of upgrading heavy oil whose sulfur, metal, and carbon contents may be high. It converts residual stocks to distillates with high naphtha yields, and to synthetic fuel gas of high quality (700-800 Btu/ft/sup 3/). It has esentially no air polution emissions and requires a relatively small amount of water and utilities. The process generates sufficient heat internally such that, except for start-up, no boilers, furnaces, or external heaters are required to operate the plant. Several aspects of the process are discussed: chemistry, hardware, feedstock, flexibility in the product mix, product quality, and economics.

  4. Heavy-quark physics in quantum chromodynamics

    SciTech Connect (OSTI)

    Brodsky, S.J.

    1991-04-01

    Heavy quarks can expose new symmetries and novel phenomena in QCD not apparent in ordinary hadronic systems. In these lectures I discuss the use of effective-Lagrangian and light-cone Fock methods to analyze exclusive heavy hadron decays such as {Upsilon} {yields} p{bar p} and B {yields} {pi}{pi}, and also to derive effective Schroedinger and Dirac equations for heavy quark systems. Two contributions to the heavy quark structure functions of the proton and other light hadrons are identified: an extrinsic'' contribution associated with leading twist QCD evolution of the gluon distribution, and a higher twist intrinsic'' contribution due to the hardness of high-mass fluctuations of multi-gluon correlations in hadronic wavefunctions. A non-perturbative calculation of the heavy quark distribution of a meson in QCD in one space and one time is presented. The intrinsic higher twist contributions to the pion and proton structure functions can dominate the hadronic production of heavy quark systems at large longitudinal momentum fraction x{sub F} and give anomalous contributions to the quark structure functions of ordinary hadrons at large x{sub bj}. I also discuss a number of ways in which heavy quark production in nuclear targets can test fundamental QCD phenomena and provide constraints on hadronic wavefunctions. The topics include color transparency, finite formation time, and predictions for charm production at threshold, including nuclear-bound quarkonium. I also discuss a number of QCD mechanisms for the suppression of J/{psi} and {Upsilon} production in nuclear collisions, including gluon shadowing, the peripheral excitation of intrinsic heavy quark components at large x{sub F}, and the coalescence of heavy quarks with co-moving spectators at low x{sub F}.

  5. Gulf Canada donor refined bitumen heavy oil upgrading process

    SciTech Connect (OSTI)

    Fisher, I.P.; Souhrada, F.; Woods, H.J.

    1982-09-01

    The method is a moderate-pressure, noncatalytic alternative which has been shown to be applicable to a wide range of bitumens and heavy oils. It offers the potential of efficiency and reliability at a low capitalized investment and operating cost. The raw distillates are separated from the bitumen or heavy oil and the vacuum residuum is blended with an efficient hydrogen donor stream containing a high proportion of substituted tetralins, and is thermally cracking in the liquid phase. The exhausted donor is recovered from the middle distillate reactor product, reactivated by fixed bed hydrogenation before being recycled to the reactor. The process can be self-sufficient in donor and is independent of the metal content of the feed. The products are blanded with the raw distillates and further hydrogenated to high quality petroleum products. While the primary hydrogen consumption is low, the reconstituted naphtha, distillate and gas oil fractions require less hydrogen than the coker liquids to achieve acceptable refinery feed quality. 1 figure, 9 tables.

  6. Metal-phosphate binders

    DOE Patents [OSTI]

    Howe, Beth Ann [Lewistown, IL; Chaps-Cabrera, Jesus Guadalupe [Coahuila, MX

    2009-05-12

    A metal-phosphate binder is provided. The binder may include an aqueous phosphoric acid solution, a metal-cation donor including a metal other than aluminum, an aluminum-cation donor, and a non-carbohydrate electron donor.

  7. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide

  8. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide

  9. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide

  10. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide

  11. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trending: Metal Oxo Bonds Print Metal oxides are important for scientific and technical applications in a variety of disciplines, including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing on the oxide's desirable chemical, magnetic, electronic, and thermal properties. The lack of a more sophisticated grasp of bonding in metal oxides constitutes a roadblock to innovation in a wide

  12. Heavy hadrons in quark-gluon plasma

    SciTech Connect (OSTI)

    Narodetskii, I. M. Simonov, Yu. A.; Veselov, A. I.

    2011-03-15

    We use the nonperturbative quark-antiquark potential derived within the Field Correlator Method and the screened Coulomb potential to calculate binding energies and melting temperatures of heavy mesons and baryons in the deconfined phase of quark-gluon plasma.

  13. Santa Fe Jets and Heavy Flavor Workshop

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Santa Fe Jets and Heavy Flavor Workshop Santa Fe Jets and Heavy Flavor Workshop WHEN: Jan 11, 2016 8:30 AM - Jan 13, 2016 5:30 PM WHERE: Inn and Spa at Loretto 211 Old Santa Fe Trail Santa Fe, New Mexico 87501 USA CONTACT: Ivan Vitev CATEGORY: Science TYPE: Conference INTERNAL: Calendar Login Event Description This workshop will bring together senior researchers, postdoctoral fellows and talented graduate students to discuss the exciting recent developments and future directions in high energy

  14. Jets in relativistic heavy ion collisions

    SciTech Connect (OSTI)

    Wang, Xin-Nian; Gyulassy, M.

    1990-09-01

    Several aspects of hard and semihard QCD jets in relativistic heavy ion collisions are discussed, including multiproduction of minijets and the interaction of a jet with dense nuclear matter. The reduction of jet quenching effect in deconfined phase of nuclear matter is speculated to provide a signature of the formation of quark gluon plasma. HIJING Monte Carlo program which can simulate events of jets production and quenching in heavy ion collisions is briefly described. 35 refs., 13 figs.

  15. The physics and chemistry of heavy Fermions

    SciTech Connect (OSTI)

    Fisk, Z.; Sarrao, J.L. |; Smith, J.L.; Thompson, J.D.

    1994-12-31

    The heavy Fermions are a subset of the f-element intermetallics straddling the magnetic/non-magnetic boundary. Their low temperature properties are characterized by an electronic energy scale of order 1--10 K. Among the low temperature ground states observed in heavy Fermion compounds are exotic superconductors and magnets, as well as unusual semiconductors. We review here the current experimental and theoretical understanding of these systems.

  16. Heavy Ion Reactions - Research - Cyclotron Institute

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heavy Ion Reactions Fast and slow components of CsI #4 are plotted. Hydrogen, Helium and Lithium isotopes are visible. The availability of energetic, light- and heavy-ion beams from the K500 Superconducting Cyclotron provides many possibilities for exploring new aspects of nuclear behavior. Using a wide variety of projectiles and bombarding energies, we achieve a more detailed understanding of the dynamics of nuclear collisions, casting new light onto the temporal evolution of quantal systems

  17. 2.10 Heavy Element Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6 6/1/2011 2.10 Heavy Element Chemistry For more than 50 years, the Office of Science and predecessor agencies have supported the discovery and study of the actinide elements, in particular the transuranium elements-atoms that are heavier than uranium. Glenn Seaborg and Ed McMillan of the Lawrence Berkeley National Laboratory, 1951 Nobel Laureates in Chemistry for the discovery of plutonium and other actinide elements, began this quest. Today, the Heavy Element Chemistry program continues the

  18. REFRACTORY METAL TUBE DRAWING

    DOE Patents [OSTI]

    Bean, C.H.; Karasek, F.J.

    1963-01-29

    A lubricant for drawing Zr and other refractory metals is described. Metallic Cu powder is added to a solution of acrylic resin in chlorinated hydrocarbon solvent. (AEC)

  19. Water issues associated with heavy oil production.

    SciTech Connect (OSTI)

    Veil, J. A.; Quinn, J. J.; Environmental Science Division

    2008-11-28

    Crude oil occurs in many different forms throughout the world. An important characteristic of crude oil that affects the ease with which it can be produced is its density and viscosity. Lighter crude oil typically can be produced more easily and at lower cost than heavier crude oil. Historically, much of the nation's oil supply came from domestic or international light or medium crude oil sources. California's extensive heavy oil production for more than a century is a notable exception. Oil and gas companies are actively looking toward heavier crude oil sources to help meet demands and to take advantage of large heavy oil reserves located in North and South America. Heavy oil includes very viscous oil resources like those found in some fields in California and Venezuela, oil shale, and tar sands (called oil sands in Canada). These are described in more detail in the next chapter. Water is integrally associated with conventional oil production. Produced water is the largest byproduct associated with oil production. The cost of managing large volumes of produced water is an important component of the overall cost of producing oil. Most mature oil fields rely on injected water to maintain formation pressure during production. The processes involved with heavy oil production often require external water supplies for steam generation, washing, and other steps. While some heavy oil processes generate produced water, others generate different types of industrial wastewater. Management and disposition of the wastewater presents challenges and costs for the operators. This report describes water requirements relating to heavy oil production and potential sources for that water. The report also describes how water is used and the resulting water quality impacts associated with heavy oil production.

  20. METAL PRODUCTION AND CASTING

    DOE Patents [OSTI]

    Magel, T.T.

    1958-03-01

    This patent covers a method and apparatus for collecting the molten metal produced by high temperature metal salt reduction. It consists essentially of subjecting the reaction vessel to centrifugal force in order to force the liberatcd molten metal into a coherent molten mass, and allowing it to solidify there. The apparatus is particularly suitable for use with small quantities of rare metals.

  1. Ceramic to metal seal

    DOE Patents [OSTI]

    Snow, Gary S.; Wilcox, Paul D.

    1976-01-01

    Providing a high strength, hermetic ceramic to metal seal by essentially heating a wire-like metal gasket and a ceramic member, which have been chemically cleaned, while simultaneously deforming from about 50 to 95 percent the metal gasket against the ceramic member at a temperature of about 30 to 75 percent of the melting temperature of the metal gasket.

  2. Amorphous metal composites

    DOE Patents [OSTI]

    Byrne, Martin A. (Troy, NY); Lupinski, John H. (Scotia, NY)

    1984-01-01

    An improved amorphous metal composite and process of making the composite. The amorphous metal composite comprises amorphous metal (e.g. iron) and a low molecular weight thermosetting polymer binder. The process comprises placing an amorphous metal in particulate form and a thermosetting polymer binder powder into a container, mixing these materials, and applying heat and pressure to convert the mixture into an amorphous metal composite.

  3. Hydrotreating Uinta Basin bitumen-derived heavy oils

    SciTech Connect (OSTI)

    Longstaff, D.C.; Balaji, G.V.; Kim, J.W.

    1995-12-31

    Heavy oils derived from Uinta Basin bitumens have been hydrotreated under varying conditions. The process variables investigated included total reactor pressure (11.0-16.9 MPa), reactor temperature (616-711 K), feed rate (0.29-1.38 WHSV), and catalyst composition. The extent of heteroatom removal and residuum conversion were determined by the feed molecular weight and catalyst selection. Catalytic activity for heteroatom conversion removal was primarily influenced by metal loading. The heteroatom removal activity of the catalysts studied were ranked HDN catalysts > HDM catalysts > HDN-support. Catalytic activity for residuum conversion was influenced by both metal loading and catalyst surface area. The residuum conversion activity of HDN catalysts were always higher than the activity of HDM catalysts and HDN supports. The residuum conversion activity of HDN-supports surpassed the activity of HDM catalyst at higher temperatures. The conversions achieved with HDN catalysts relative to the HDM catalysts indicated that the low metals contents of the Uinta Basin bitumens obviate the need for hydrodemetallation as an initial upgrading step with these bitumens. The upgrading of Uinta Basin bitumens for integration into refinery feed slates should emphasize molecular weight and boiling range reduction first, followed by hydrotreating of the total liquid product produced in the pyrolysis process. Kinetics of residuum conversion can be modeled by invoking a consecutive-parallel mechanism in which native residuum in the feed is rapidly converted to volatile products and to product residuum. Deep conversion of residuum is only achieved when the more refractory product residuum is converted to volatile products.

  4. Heavy Truck Clean Diesel Cooperative Research Program

    SciTech Connect (OSTI)

    Milam, David

    2006-12-31

    This report is the final report for the Department of Energy on the Heavy Truck Engine Program (Contract No. DE-FC05-00OR22806) also known as Heavy Truck Clean Diesel (HTCD) Program. Originally, this was scoped to be a $38M project over 5 years, to be 50/50 co-funded by DOE and Caterpillar. The program started in June 2000. During the program the timeline was extended to a sixth year. The program completed in December 2006. The program goal was to develop and demonstrate the technologies required to enable compliance with the 2007 and 2010 (0.2g/bhph NOx, 0.01g/bhph PM) on-highway emission standards for Heavy Duty Trucks in the US with improvements in fuel efficiency compared to today's engines. Thermal efficiency improvement from a baseline of 43% to 50% was targeted.

  5. Process for upgrading a heavy viscous hydrocarbon

    SciTech Connect (OSTI)

    Lutz, I.H.

    1984-06-12

    A process for upgrading a heavy viscous hydrocarbon, for example, rendering a heavy viscous crude pipelinable, includes visbreaking, distillation and solvent extraction steps. A heavy viscous hydrocarbon is fed through the visbreaker which forms a feed to the distillation step. A heavier fraction from distillation is fed to a solvent extraction unit which produces a fraction which contains resin. At least a portion of the resin containing fraction separated in the solvent extraction unit is recycled and combined with the feed which is to be subjected to visbreaking so that the total yield of products, residual and gas-free, is increased. The recycled resin reduces the tendency of the asphaltenes to separate from the oil and thereby reduces the tendency to lay down coke in the visbreaker; this allows higher conversion to upgraded liquid products.

  6. Future of heavy crude and tar sands

    SciTech Connect (OSTI)

    Meyer, R.F.; Steele, C.T.

    1981-01-01

    The 106 papers which were presented at the First International Conference on the Future of Heavy Crude and Tar Sands, held in Edmonton, Alberta are incorporated in this volume. They are grouped under the following sections: (1) role of heavy crude oils and tar sands in world energy; (2) major known occurrences; (3) chemistry and geochemistry; (4) geology; (5) resource evaluation techniques; (6) production research and pilot projects; (7) current production; (8) upgrading and refining; (9) transportation; (10) environmental research; (11) economics; (12) technological problems; (13) institutional factors; and (14) bibliography. All papers have been abstracted and indexed. (ATT)

  7. Recovery and upgrading of heavy oil analyzed

    SciTech Connect (OSTI)

    Fornoff, L.L.; Van Driesen, R.P.; Viens, C.H.

    1980-10-13

    An analysis has been made of recovery and upgrading of Venezuelan heavy crudes by integrating steam-drive production data with an upgraded computer processing program. A study used 110 computer cases to analyze a project using Venezuelan heavy crude from the Jobo field with gravity of 9.2 API and 4.1% by wt sulfur for the base case. Sensitivity cases used 12.2 API oil from the Lot 9 field, Monagas state, Venezuela, with sulfur content of 2.3%. Four upgrading methods were studied (deasphalting, delayed coking, flexicoking, and LC-fining), all with favorable resulting economics.

  8. HOW MANY NUCLEOSYNTHESIS PROCESSES EXIST AT LOW METALLICITY?

    SciTech Connect (OSTI)

    Hansen, C. J. [Landessternwarte, ZAH, Heidelberg University, Knigstuhl 12, D-69117 Heidelberg (Germany); Montes, F. [Joint Institute for Nuclear Astrophysics, Michigan State University, East Lansing, MI 48824 (United States); Arcones, A., E-mail: cjhansen@lsw.uni-heidelberg.de, E-mail: cjhansen@dark-cosmology.dk, E-mail: montes@nscl.msu.edu, E-mail: almudena.arcones@physik.tu-darmstadt.de [Institut fr Kernphysik, Technische Universitt Darmstadt, Schlossgartenstr. 2, Darmstadt D-64289 (Germany)

    2014-12-20

    Abundances of low-metallicity stars offer a unique opportunity to understand the contribution and conditions of the different processes that synthesize heavy elements. Many old, metal-poor stars show a robust abundance pattern for elements heavier than Ba, and a less robust pattern between Sr and Ag. Here we probe if two nucleosynthesis processes are sufficient to explain the stellar abundances at low metallicity, and we carry out a site independent approach to separate the contribution from these two processes or components to the total observationally derived abundances. Our approach provides a method to determine the contribution of each process to the production of elements such as Sr, Zr, Ba, and Eu. We explore the observed star-to-star abundance scatter as a function of metallicity that each process leads to. Moreover, we use the deduced abundance pattern of one of the nucleosynthesis components to constrain the astrophysical conditions of neutrino-driven winds from core-collapse supernovae.

  9. Mapping Metals Incorporation of a Single Catalyst Particle Using Element

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Specific X-ray Nanotomography | Stanford Synchrotron Radiation Lightsource Mapping Metals Incorporation of a Single Catalyst Particle Using Element Specific X-ray Nanotomography Tuesday, March 31, 2015 Fluid catalytic cracking (FCC) is the refining process for converting large and/or heavy molecules of oil feedstock into smaller and lighter hydrocarbons, such as gasoline. The workhorse of the FCC process is a tiny catalyst particle of 50-150 µm diameter that consists of a complex mixture of

  10. Correlating Spatial Heterogeneities in Porosity and Permeability with Metal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Poisoning within an Individual Catalyst Particle using X-ray Microscopy | Stanford Synchrotron Radiation Lightsource Correlating Spatial Heterogeneities in Porosity and Permeability with Metal Poisoning within an Individual Catalyst Particle using X-ray Microscopy Wednesday, August 21, 2013 - 1:30pm SLAC, Conference Room 137-226 Presented by Darius Morris, Stanford Synchrotron Radiation Lightsource Fluid catalytic cracking (FCC) is a refining process for converting large and/or heavy

  11. Alkali metal nitrate purification

    DOE Patents [OSTI]

    Fiorucci, Louis C. (Hamden, CT); Morgan, Michael J. (Guilford, CT)

    1986-02-04

    A process is disclosed for removing contaminants from impure alkali metal nitrates containing them. The process comprises heating the impure alkali metal nitrates in solution form or molten form at a temperature and for a time sufficient to effect precipitation of solid impurities and separating the solid impurities from the resulting purified alkali metal nitrates. The resulting purified alkali metal nitrates in solution form may be heated to evaporate water therefrom to produce purified molten alkali metal nitrates suitable for use as a heat transfer medium. If desired, the purified molten form may be granulated and cooled to form discrete solid particles of purified alkali metal nitrates.

  12. Metal halogen electrochemical cell

    SciTech Connect (OSTI)

    Walsh, F.M.

    1986-06-03

    An electrochemical cell is described having a metal anode selected from the group consisting of zinc and cadmium; a bromine cathode; and, an aqueous electrolyte containing a metal bromide, the metal having the same metal as the metal of the anode, the improvement comprising: a bromine complexing agent in the aqueous metal bromide electrolyte consisting solely of a tetraorgano substituted ammonium salt, which salt is soluble of water and forms and substantially water immiscible liquid bromine complex at temperatures in the range of about 10/sup 0/C. to about 60/sup 0/C. and wherein the tetraorgano substituted ammonium salt is selected from asymmetric quaternary ammonium compounds.

  13. Metal-Air Batteries

    SciTech Connect (OSTI)

    Zhang, Jiguang; Bruce, Peter G.; Zhang, Gregory

    2011-08-01

    Metal-air batteries have much higher specific energies than most currently available primary and rechargeable batteries. Recent advances in electrode materials and electrolytes, as well as new designs on metal-air batteries, have attracted intensive effort in recent years, especially in the development of lithium-air batteries. The general principle in metal-air batteries will be reviewed in this chapter. The materials, preparation methods, and performances of metal-air batteries will be discussed. Two main metal-air batteries, Zn-air and Li-air batteries will be discussed in detail. Other type of metal-air batteries will also be described.

  14. Heavy vehicle propulsion system materials program: Semiannual progress report, April 1996--September 1996

    SciTech Connect (OSTI)

    Johnson, D.R.

    1997-04-01

    The purpose of the Heavy Vehicle Propulsion System Materials Program is the development of materials: ceramics, intermetallics, metal alloys, and metal and ceramic coatings, to support the dieselization of class 1-3 trucks to realize a 35% fuel-economy improvement over current gasoline-fueled trucks and to support commercialization of fuel-flexible LE-55 low-emissions, high-efficiency diesel engines for class 7-8 trucks. The Office of Transportation Technologies, Office of Heavy Vehicle Technologies (OTT OHVT) has an active program to develop the technology for advanced LE-55 diesel engines with 55% efficiency and low emissions levels of 2.0 g/bhp-h NO{sub x} and 0.05 g/bhp-h particulates. The goal is also for the LE-55 engine to run on natural gas with efficiency approaching that of diesel fuel. The LE-55 program is being completed in FY 1997 and, after approximately 10 years of effort, has largely met the program goals of 55% efficiency and low emissions. However, the commercialization of the LE-55 technology requires more durable materials than those that have been used to demonstrate the goals. Heavy Vehicle Propulsion System Materials will, in concert with the heavy duty diesel engine companies, develop the durable materials required to commercialize the LE-55 technologies. OTT OHVT also recognizes a significant opportunity for reduction in petroleum consumption by dieselization of pickup trucks, vans, and sport utility vehicles. Application of the diesel engine to class 1, 2, and 3 trucks is expected to yield a 35% increase in fuel economy per vehicle. The foremost barrier to diesel use in this market is emission control. Once an engine is made certifiable, subsequent challenges will be in cost; noise, vibration, and harshness (NVH); and performance. Separate abstracts have been submitted to the database for contributions to this report.

  15. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron...

  16. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Print Wednesday, 29 July 2009 00:00 For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron...

  17. Ecological Interactions Between Metals and Microbes That Impact Bioremediation

    SciTech Connect (OSTI)

    Konopka, Allan E.

    2003-06-01

    Previous work showed the correlation between bacterial biomass, population structure and the amount of lead, chromium and aromatic compounds present along a 21.6 m transect in which the concentrations of both heavy metals (Pb and Cr) and aromatic compounds varied 2-3 orders of magnitude. This work suggested that (a) biomass level was better correlated to the level of biodegradable organic C than the level of heavy metals, (b) microbial community composition differed between highly contaminated soils and uncontaminated ones, and (c) substantial microbial activity was found even in the highly contaminated soils. One confounding factor in these analyses was that the contaminated soils contained Pb, Cr, and aromatic hydrocarbons. Therefore, it was difficult to determine which factors were most important in the shifts of microbial community composition. Therefore, experiments were conducted in microcosms in which individual factors could be systematically varied. In this case, soils were used from the Seymour, IN site which had low levels of contamination, and the microbial community had little chance to adapt to heavy metals or aromatic compounds.

  18. Heavy vehicle propulsion system materials program semi-annual progress report for October 1997 through March 1998

    SciTech Connect (OSTI)

    Johnson, D.R.

    1998-06-01

    The purpose of the Heavy Vehicle Propulsion System materials Program is the development of materials: ceramics, intermetallics, metal alloys, and metal and ceramic coatings, to support the dieselization of class 1--3 trucks to realize a 35{percent} fuel-economy improvement over current gasoline-fueled trucks and to support commercialization of fuel-flexible LE-55 low-emissions, high-efficiency diesel engines for class 7--8 trucks. The Office of Transportation Technologies, Office of Heavy Vehicle Technologies (OTT OHVT) has an active program to develop the technology for advanced LE-55 diesel engines with 55{percent} efficiency and low emissions levels of 2.0 g/bhp-h NO{sub x} and 0.05 g/bhp-h particulates. The goal is also for the LE-55 engine to run on natural gas with efficiency approaching that of diesel fuel. The LE-55 program is being completed in FY 1997 and, after approximately 10 years of effort, has largely met the program goals of 55{percent} efficiency and low emissions. However, the commercialization of the LE-55 technology requires more durable materials than those that have been used to demonstrate the goals. Heavy Vehicle Propulsion System Materials will, in concert with the heavy-duty diesel engine companies, develop the durable materials required to commercialize the LE-55 technologies.

  19. Heavy particle production at the SSC

    SciTech Connect (OSTI)

    Brodsky, S.J.; Haber, H.E.; Gunion, J.F.

    1984-03-01

    Predictions for the production of heavy quarks, supersymmetric particles, and other colored systems at high energy due to intrinsic twist-six components in the proton wavefunction are given. We also suggest the possibility of using asymmetric collision energies (e.g., via intersecting rings at the SSC) in order to facilitate the study of forward and diffractive particle production processes. 9 references.

  20. Kinetics of heavy oil/coal coprocessing

    SciTech Connect (OSTI)

    Szladow, A.J.; Chan, R.K.; Fouda, S.; Kelly, J.F. )

    1988-01-01

    A number of studies have been reported on coprocessing of coal and oil sand bitumen, petroleum residues and distillate fractions in catalytic and non-catalytic processes. The studies described the effects of feedstock characteristics, process chemistry and operating variables on the product yield and distribution; however, very few kinetic data were reported in these investigations. This paper presents the kinetic data and modeling of the CANMET coal/heavy oil coprocessing process. A number of reaction networks were evaluated for CANMET coprocessing. The final choice of model was a parallel model with some sequential characteristics. The model explained 90.0 percent of the total variance, which was considered satisfactory in view of the difficulties of modeling preasphaltenes. The models which were evaluated showed that the kinetic approach successfully applied to coal liquefaction and heavy oil upgrading can be also applied to coprocessing. The coal conversion networks and heavy oil upgrading networks are interrelated via the forward reaction paths of preasphaltenes, asphaltenes, and THFI and via the reverse kinetic paths of an adduct formation between preasphaltenes and heavy oil.

  1. The microbial upgrading of model heavy oils

    SciTech Connect (OSTI)

    Webster, I.A.; Patras, L.E. )

    1988-01-01

    The authors have isolated bacteria and used them to catalyze the removal of sulfur, nitrogen and nickel from model heavy oils and asphaltenes. Their paper will discuss their activity and reactor concepts. The concept of a membrane bioreactor for oil processing is introduced.

  2. Hydroprocessing catalysts for heavy oil and coal

    SciTech Connect (OSTI)

    Satriana, M.J.

    1982-01-01

    Hydroprocessing catalysts, as described in over 230 processes covered in this book, are hydrogenation catalysts used in the upgrading of heavy crudes and coal to products expected to be in great demand as the world's primary oil supplies gradually dwindle. The techniques employed in hydroprocessing result in the removal of contaminants, the transformation of lower grade materials such as heavy crudes to valuable fuels, or the conversion of hydrocarbonaceous solids into gaseous or liquid fuel products. All of these techniques are, of course, carried out in the presence of hydrogen. Some of the brightest energy prospects for the future lie in heavy oil reservoirs and coal reserves. Heavy oils, defined in this book as having gravities of < 20/sup 0/API, are crudes so thick that they are not readily extracted from their reservoirs. However, processing of these crudes is of great importance, because the US resource alone is enormous. The main types of processing catalysts covered in the book are hydrorefining catalysts plus some combinations of the two. Catalysts for the conversion of hydrocarbonaceous materials to gaseous or liquid fuels are also covered. The primary starting material for these conversions is coal, but wood, lignin, oil shale, tar sands, and peat are other possibilities. The final chapter describes the preparation of various catalyst support systems.

  3. Metal to semiconductor transition in metallic transition metal dichalcogenides

    SciTech Connect (OSTI)

    Li, Yan; Kang, Jun; Li, Jingbo; Tongay, Sefaattin; Wu, Junqiao; Yue, Qu

    2013-11-07

    We report on tuning the electronic and magnetic properties of metallic transition metal dichalcogenides (mTMDCs) by 2D to 1D size confinement. The stability of the mTMDC monolayers and nanoribbons is demonstrated by the larger binding energy compared to the experimentally available semiconducting TMDCs. The 2D MX{sub 2} (M?=?Nb, Ta; X?=?S, Se) monolayers are non-ferromagnetic metals and mechanically softer compared to their semiconducting TMDCs counterparts. Interestingly, mTMDCs undergo metal-to-semiconductor transition when the ribbon width approaches to ?13? and ?7? for zigzag and armchair edge terminations, respectively; then these ribbons convert back to metal when the ribbon widths further decrease. Zigzag terminated nanoribbons are ferromagnetic semiconductors, and their magnetic properties can also be tuned by hydrogen edge passivation, whereas the armchair nanoribbons are non-ferromagnetic semiconductors. Our results display that the mTMDCs offer a broad range of physical properties spanning from metallic to semiconducting and non-ferromagnetic to ferromagnetic that is ideal for applications where stable narrow bandgap semiconductors with different magnetic properties are desired.

  4. Metal phthalocyanine catalysts

    DOE Patents [OSTI]

    Ellis, Jr., Paul E.; Lyons, James E.

    1994-01-01

    As a new composition of matter, alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

  5. Nitrided Metallic Bipolar Plates

    SciTech Connect (OSTI)

    Brady, Michael P; Toops, Todd J; Tortorelli, Peter F; More, Karren Leslie; Meyer III, Harry M; Pihl, Josh A; Wang, Heli; Turner, John; Garzon, Fernando; Rockward, Tommy; Gervasio, Don; Rakowski, Jim; EstevezGenCell, Francisco

    2010-01-01

    Effort devoted to scale up and demonstration of thin stamped metallic bipolar plates. Overall goal is to demonstrate potential for metallic bipolar plates to meet 5000 h automotive durability goal at a cost of less than $5/kW.

  6. Metal phthalocyanine catalysts

    DOE Patents [OSTI]

    Ellis, P.E. Jr.; Lyons, J.E.

    1994-10-11

    A new composition of matter is described which is an alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

  7. Making a Difference: Heavy-Duty Combustion Engine Research Saved...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy-Duty Combustion Engine Research Saved Billions Making a Difference: Heavy-Duty Combustion Engine Research Saved Billions December 29, 2015 - 12:22pm Addthis Sandia researcher ...

  8. Heavy-Duty Engine Combustion Optimization for High Thermal Efficiency...

    Broader source: Energy.gov (indexed) [DOE]

    PDF icon deer07zhang.pdf More Documents & Publications High Efficiency Clean Combustion for Heavy-Duty Engine Heavy Truck Engine Development & HECC A Micro-Variable Circular ...

  9. Heavy Quarks, QCD, and Effective Field Theory (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    Heavy Quarks, QCD, and Effective Field Theory Citation Details In-Document Search Title: Heavy Quarks, QCD, and Effective Field Theory The research supported by this OJI award is ...

  10. Geothermal and heavy-oil resources in Texas (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    Geothermal and heavy-oil resources in Texas Citation Details In-Document Search Title: Geothermal and heavy-oil resources in Texas You are accessing a document from the ...

  11. Transient Simulation of a 2007 Prototype Heavy-Duty Engine |...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Simulation of a 2007 Prototype Heavy-Duty Engine Transient Simulation of a 2007 Prototype Heavy-Duty Engine 2004 Diesel Engine Emissions Reduction (DEER) Conference PresentationL ...

  12. Difficulty of Measuring Emissions from Heavy-Duty Engines Equipped...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Difficulty of Measuring Emissions from Heavy-Duty Engines Equipped with SCR and DPF Difficulty of Measuring Emissions from Heavy-Duty Engines Equipped with SCR and DPF In reference ...

  13. Medium- and Heavy-Duty Electric Drive Vehicle Simulation and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Medium- and Heavy-Duty Electric Drive Vehicle Simulation and Analysis Medium- and Heavy-Duty Electric Drive Vehicle Simulation and Analysis 2012 DOE Hydrogen and Fuel Cells Program ...

  14. Creation and Testing of the ACES Heavy Heavy-Duty Diesel Engine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Advanced Collaborative Emissions Study (ACES):Phase 3 Evaluation of the European PMP Methodologies Using Chassis Dynamometer and On-road Testing of Heavy-duty Vehicles Advanced ...

  15. The performance of 3500 MWth homogeneous and heterogeneous metal fueled core designs

    SciTech Connect (OSTI)

    Turski, R.; Yang, Shi-tien

    1987-11-01

    Performance parameters are calculated for a representative 3500 MWth homogeneous and a heterogeneous metal fueled reactor design. The equilibrium cycle neutronic characteristics, safety coefficients, control system requirements, and control rod worths are evaluated. The thermal-hydraulic characteristics for both configurations are also compared. The heavy metal fuel loading requirements and neutronic performance characteristics are also evaluated for the uranium startup option. 14 refs., 14 figs., 20 tabs.

  16. Composition and process for organic and metal contaminant fixation in soil

    DOE Patents [OSTI]

    Schwitzgebel, Klaus

    1994-02-08

    A method and compositions using a first ferrous iron containing solution with the iron concentration in excess of theoretical requirements to treat a contaminated site to reduce hexavalent chromium to trivalent chromium and coprecipitate trivalent chromium with other heavy metals and using a second solution of silicate containing a destabilizing salt to form a relatively impermeable gel in the contaminated site thereby fixing metals and organics to the extent that there should be no detectable ground water contamination.

  17. Durable metallized polymer mirror

    DOE Patents [OSTI]

    Schissel, P.O.; Kennedy, C.E.; Jorgensen, G.J.; Shinton, Y.D.; Goggin, R.M.

    1994-11-01

    A metallized polymer mirror construction is disclosed having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate. 6 figs.

  18. Durable metallized polymer mirror

    DOE Patents [OSTI]

    Schissel, Paul O.; Kennedy, Cheryl E.; Jorgensen, Gary J.; Shinton, Yvonne D.; Goggin, Rita M.

    1994-01-01

    A metallized polymer mirror construction having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate.

  19. Flavor Physics Data from the Heavy Flavor Averaging Group (HFAG)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Heavy Flavor Averaging Group (HFAG) was established at the May 2002 Flavor Physics and CP Violation Conference in Philadelphia, and continues the LEP Heavy Flavor Steering Group's tradition of providing regular updates to the world averages of heavy flavor quantities. Data are provided by six subgroups that each focus on a different set of heavy flavor measurements: B lifetimes and oscillation parameters, Semi-leptonic B decays, Rare B decays, Unitarity triangle parameters, B decays to charm final states, and Charm Physics.

  20. Electron-State Hybridization in Heavy-Fermion Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron-State Hybridization in Heavy-Fermion Systems Electron-State Hybridization in Heavy-Fermion Systems Print Wednesday, 27 September 2006 00:00 Heavy-fermion systems are characterized by electrons with extremely large effective masses. The corresponding heavy-electron "quasiparticle" states are close to the Fermi energy and govern the thermodynamic, transport, and, in part, magnetic properties of these materials. In the case of rare-earth compounds, the quasiparticle states arise

  1. Managing Inventories of Heavy Actinides (Conference) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Conference: Managing Inventories of Heavy Actinides Citation Details In-Document Search Title: Managing Inventories of Heavy Actinides The Department of Energy (DOE) has stored a limited inventory of heavy actinides contained in irradiated targets, some partially processed, at the Savannah River Site (SRS) and Oak Ridge National Laboratory (ORNL). The 'heavy actinides' of interest include plutonium, americium, and curium isotopes; specifically 242Pu and 244Pu,

  2. Characteristics and upgrading technologies of Chinese heavy oil

    SciTech Connect (OSTI)

    Ghuang Yang; Jinsen Gao

    1995-12-31

    The characteristics of typical Chinese heavy oils produced in the eastern, northwestern, and northeastern parts of China are presented to show the uniqueness of heavy oils on the Chinese mainland. Henceforth, upgrading technologies of Chinese domestic heavy crudes are discussed along this line. Two main categories of upgrading technologies, decarbonization and hydrogenation, as realized or being developed in this country are presented. It is concluded that most Chinese heavy crudes are adaptable to conventional upgrading processes.

  3. MARTINI event generator for heavy quarks: Initialization, parton...

    Office of Scientific and Technical Information (OSTI)

    Initialization, parton evolution, and hadronization Prev Next Title: MARTINI event generator for heavy quarks: Initialization, parton evolution, and hadronization ...

  4. ITP Metal Casting: Implementation of Metal Casting Best Practices |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Implementation of Metal Casting Best Practices ITP Metal Casting: Implementation of Metal Casting Best Practices PDF icon implementation_final.pdf More Documents & Publications ITP Metal Casting: Advanced Melting Technologies: Energy Saving Concepts and Opportunities for the Metal Casting Industry ITP Metal Casting: Energy Use in Selected Metalcasting Facilities - 2003 ITP Metal Casting: Energy and Environmental Profile of the U.S. Metal casting

  5. Unicracking/hydrodesulfurization technology for upgrading California outer continental shelf heavy crudes

    SciTech Connect (OSTI)

    Lindsay, D.A.; Miller, J.W.; Simpson, H.D.; Skripek, M.

    1985-01-01

    California outer continental shelf crudes represent an important source of oil for energy future. They are difficult to refine, however, because of their high levels of sulfur, metals, and carbon residue. Improved Unicracking/HDS technology, made possible by a new HDM catalyst, now makes upgrading heavy crudes feasible. The authors extended this technology to upgrading California outer continental shelf crudes into a syncrude with properties similar to Alaskan North Slope crude. This is an attractive solution for handing outer continental shelf crudes in existing refineries.

  6. Experimental measurement of the 4-d transverse phase space map of a heavy ion beam

    SciTech Connect (OSTI)

    Hopkins, H S

    1997-12-01

    The development and employment of a new diagnostic instrument for characterizing intense, heavy ion beams is reported on. This instrument, the ''Gated Beam Imager'' or ''GBI'' was designed for use on Lawrence Livermore National Laboratory Heavy Ion Fusion Project's ''Small Recirculator'', an integrated, scaled physics experiment and engineering development project for studying the transport and control of intense heavy ion beams as inertial fusion drivers in the production of electric power. The GBI allows rapid measurement and calculation of a heavy ion beam's characteristics to include all the first and second moments of the transverse phase space distribution, transverse emittance, envelope parameters and beam centroid. The GBI, with appropriate gating produces a time history of the beam resulting in a 4-D phase-space and time ''map'' of the beam. A unique capability of the GBI over existing diagnostic instruments is its ability to measure the ''cross'' moments between the two transverse orthogonal directions. Non-zero ''cross'' moments in the alternating gradient lattice of the Small Recirculator are indicative of focusing element rotational misalignments contributing to beam emittance growth. This emittance growth, while having the same effect on the ability to focus a beam as emittance growth caused by non-linear effects, is in principle removable by an appropriate number of focusing elements. The instrument uses the pepperpot method of introducing a plate with many pinholes into the beam and observing the images of the resulting beamlets as they interact with a detector after an appropriate drift distance. In order to produce adequate optical signal and repeatability, the detector was chosen to be a microchannel plate (MCP) with a phosphor readout screen. The heavy ions in the pepperpot beamlets are stopped in the MCP's thin front metal anode and the resulting secondary electron signal is amplified and proximity-focused onto the phosphor while maintaining the spatial and intensity characteristics of the heavy ion beamlets. The MCP used in this manner is a sensitive, accurate, and long-lasting detector, resistant against signal degradation experienced by previous methods of intense heavy ion beam detection and imaging. The performance of the GBI was benchmarked against existing mechanical emittance diagnostics and the results of sophisticated beam transport numerical simulation codes to demonstrate its usefulness as a diagnostic tool. A method of beam correction to remove the effects of quadrupole focusing element rotational misalignments is proposed using data obtainable from a GBI. An optimizing code was written to determine the parameters of the correction system elements based on input from the GBI. The results of this code for the Small Recirculator beam are reported on.

  7. Progress on the Los Alamos heavy-ion injector

    SciTech Connect (OSTI)

    Wilson, D.C.; Riepe, K.B.; Ballard, E.O.; Meyer, E.A.; Shurter, R.P.; Van Haaften, F.W.; Humphries, S. Jr.

    1986-01-01

    Heavy-ion fusion using an induction linac requires injection of multiple high-current beams from a pulsed electrostatic accelerator at as high a voltage as practical. Los Alamos National Laboratory is developing a 16-beam, 2-MeV, pulsed electrostatic accelerator for Al/sup +/ ions. The ion source will use a pulsed metal vapor arc plasma. A biased grid will control plasma flux into the ion extraction region. This source has achieved a normalized emittance of epsilon/sub n/ < 3.10/sup -7/..pi..-m-rad with Al/sup +/ ions. An 800 kV Marx prototype with a laser fired diverter is being assembled. The ceramic accelerating column sections have been brazed and leak tested. Voltage hold off on a brazed sample was more than doubled by selective removal of the Ticusil braze fillet extending along the ceramic. A scaled test module held 250 kV for 50 ..mu..s, giving confidence that the full module can hold 175 kV per section. The pressure vessel should be received in June 1986. High-voltage testing of a 1 MV column will begin by early 1987.

  8. Residuum and heavy oil upgrading with the CANMET hydrocracking process

    SciTech Connect (OSTI)

    Patmore, D.J.; Khulbe, C.P.; Belinko, K.

    1981-03-01

    The advantages of the CANMET hydrocracking process are: Feed Flexibility - high levels of the main feed contaminants, sulfur, nitrogen and metals do not have a deleterious effect on the process. Hence, a wide range of feedstocks can be upgraded by this process including residuum from conventional crudes; Operability - extended runs indicate that the process will operate continuously with little sensitivity to operational problems even with difficult feedstocks such as Cold Lake and Boscan heavy oil. During extended operation nearly constant pitch conversion and product yields and qualities are obtained; High Distillate Yields - the CANMET Process can produce over 100 vol % distillate, compared to 83 vol % for coking process; Flexibility of Operation - the amount of pitch converted can easily be controlled by adjusting reactor temperature and liquid feed rate. Thus, the required product slate can be obtained by simply changing the operating conditions; Thermal Stability - because the process does not employ an active catalyst, the potential for thermal run-away and development of hot spots is considerably reduced; High Pitch Conversion - the CANMET additive permits sustained controlled and repeatable operation at pitch conversions higher than 90 wt % on a wide range of feedstocks; Reduced Operating Pressure - the action of the additive as a processing aid allows substantial reduction in operating pressure below that for competitive commercial technology; and Efficient Hydrogen Utilization - Since CANMET does not employ an active desulfurizing catalyst, overall hydrogen consumption for a given conversion is low. Almost all of the hydrogen goes to distillate product.

  9. Evaluation of a dilute chemical decontaminant for pressurized heavy water reactors

    SciTech Connect (OSTI)

    Velmurugan, S.; Narasimhan, S.V.; Mathur, P.K.; Venkateswarlu, K.S. )

    1991-12-01

    In this paper a dilute chemical decontamination formulation based on ethylene diamine tetraacetic acid, oxalic acid, and citric acid is evaluated for its efficacy in removing oxide layers in a pressurized heavy water reactor (PHWR). An ion exchange system that is specifically suited for fission product-dominated contamination in a PHWR is suggested for the reagent regeneration stage of the decontamination process. An attempt has been made to understand the redeposition behavior of various isotopes during the decontamination process. The polarographic method of identifying the species formed in the dissolution process is explained. Electrochemical measurements are employed to follow the course of oxide removal during the dissolution process. Scanning electron micrographs of metal coupons before and after the dissolution process exemplify the involvement of base metal in the formation of a ferrous oxalate layer. Material compatibility tests between the decontaminant and carbon steel, Monel-400, and Zircaloy-2 are reported.

  10. Extraction process for removing metallic impurities from alkalide metals

    DOE Patents [OSTI]

    Royer, L.T.

    1987-03-20

    A development is described for removing metallic impurities from alkali metals by employing an extraction process wherein the metallic impurities are extracted from a molten alkali metal into molten lithium metal due to the immiscibility of the alkali metals in lithium and the miscibility of the metallic contaminants or impurities in the lithium. The purified alkali metal may be readily separated from the contaminant-containing lithium metal by simple decanting due to the differences in densities and melting temperatures of the alkali metals as compared to lithium.

  11. The heavy top quark and supersymmetry

    SciTech Connect (OSTI)

    Hall, L.J.

    1997-01-01

    Three aspects of supersymmetric theories are discussed: electroweak symmetry breaking, the issues of flavor, and gauge unification. The heavy top quark plays an important, sometimes dominant, role in each case. Additional symmetries lead to extensions of the Standard Model which can provide an understanding for many of the outstanding problems of particle physics. A broken supersymmetric extension of spacetime allows electroweak symmetry breaking to follow from the dynamics of the heavy top quark; an extension of isospin provides a constrained framework for understanding the pattern of quark and lepton masses; and a grand unified extension of the Standard Model gauge group provides an elegant understanding of the gauge quantum numbers of the components of a generation. Experimental signatures for each of these additional symmetries are discussed.

  12. Kinetics of heavy oil/coal coprocessing

    SciTech Connect (OSTI)

    Szladow, A.J.; Chan, R.K. ); Foudu, S.; Kelly, J.F. )

    1988-06-01

    A number of studies have been reported on coprocessing of coal and oil sand bitumen, petroleum residues and distillate fractions in catalytic and non-catalytic processes. The studies described the effects of feedstock characteristics, process chemistry and operating variables on the product yield and distribution; however, very few kinetic data were reported in these investigations. This paper presents the kinetic data and modelling of the CANMET coal/heavy oil coprocessing process. CANMET has been conducting research and process development work on coprocessing of Canadian heavy oil/bitumen and coal since 1979 including studies of the kinetics and mechanisms of coprocessing. As a continuation of the program, CANMET and Lobbe Technologies undertook a project on mathematical modelling of coprocessing kinetics with emphasis on the development of reaction engineering models for improved process performance and operation.

  13. Medium energy heavy ion operations at RHIC

    SciTech Connect (OSTI)

    Drees, K.A.; Ahrens, L.; Bai, M.; Beebe-Wang, J.; Blackler, I.M.C.; Blaskiewicz, M.; Brown, K.A.; Brennan, M.; Bruno, D.; Butler, J.; Carlson, C.; Connolly, R.; D'Ottavio, T.; Fischer, W.; Fu, W.; Gassner, D.; Harvey, M.; Hayes, T.; Huang, H.; Hulsart, R.; Ingrassia, P.; Kling, N.; Lafky, M.; Laster, J.; Lee, R.C.; Litvinenko, V.; Luo, Y.; MacKay, W.W.; Marr, G.; Mapes. M.; Marusic, A.; Mernick, K.; Michnoff, R.; Minty, M.; Montag, C.; Morris, J.; Naylor, C.; Nemesure, S.; Pilat, F.; Ptitsyn, V.; Robert-Demolaize, G.; Roser, T.; Sampson, P.; Satogata, T.; Schoefer, V.; Schultheiss, C.; Severino, F.; Shrey, T.; Smith, K.S.; Tepikian, S.; Thieberger, P.; Trbojevic, D.; Tsoupas, N.; Tuozzolo, J.; van Kuik, B.; Wilinski, M.; Zaltsman, A.; Zeno, K.; Zhang, S.Y.

    2011-03-28

    As part of the search for a phase transition or critical point on the QCD phase diagram, an energy scan including 5 different energy settings was performed during the 2010 RHIC heavy ion run. While the top beam energy for heavy ions is at 100 GeV/n and the lowest achieved energy setpoint was significantly below RHICs injection energy of approximately 10 GeV/n, we also provided beams for data taking in a medium energy range above injection energy and below top beam energy. This paper reviews RHIC experience and challenges for RHIC medium energy operations that produced full experimental data sets at beam energies of 31.2 GeV/n and 19.5 GeV/n. The medium energy AuAu run covered two beam energies, both above the RHIC injection energy of 9.8 GeV but well below the standard store energy of 100 GeV (see table 1). The low energy and full energy runs with heavy ions in FY10 are summarized in [1] and [2]. Stochastic Cooling ([3]) was only used for 100 GeV beams and not used in the medium energy run. The efficiency of the transition from 100 GeV operation to 31.2 GeV and then to 19.5 GeV was remarkable. Setup took 32 h and 19 h respectively for the two energy settings. The time in store, defined to be the percentage of time RHIC provides beams in physics conditions versus calendar time, was approximately 52% for the entire FY10 heavy ion run. In both medium energy runs it was well above this average, 68% for 31.5 GeV and 82% for 19.5 GeV. For both energies RHIC was filled with 111 bunches with 1.2 10{sup 9} and 1.3 10{sup 9} ions per bunch respectively.

  14. COMMISSIONING OF THE RELATIVISTIC HEAVY ION COLLIDER.

    SciTech Connect (OSTI)

    TRBOJEVIC,D.; AHRENS,L.; BLASKIEWICZ,M.; BRENNAN,M.; BAI,M.; CAMERON,P.; CARDONA,J.; CONNOLLY,R.; ET AL; TSOUPAS,N.; VAN ZEIJTS,J.

    2001-06-18

    This report describes in detail steps performed in bringing the Relativistic Heavy Ion Collider (RHIC) from the commissioning into the operational stage when collisions between 60 bunches of fully striped gold ions, were routinely provided. Corrections of the few power supplies connections by the beam measurements are described. Beam lifetime improvements at injection, along the acceleration are shown. The beam diagnostic results; like Schottky detector, beam profile monitor, beam position monitors, tune meter and others, are shown [1].

  15. Holifield Heavy Ion Research Facility: Users handbook

    SciTech Connect (OSTI)

    Auble, R.L.

    1987-01-01

    The primary objective of this handbook is to provide information for those who plan to carry out research programs at the Holifield Heavy Ion Research Facility (HHIRF) at Oak Ridge National Laboratory. The accelerator systems and experimental apparatus available are described. The mechanism for obtaining accelerator time and the responsibilities of those users who are granted accelerator time are described. The names and phone numbers of ORNL personnel to call for information about specific areas are given. (LEW)

  16. Co-processing of heavy oil

    SciTech Connect (OSTI)

    Khan, M.R.

    1995-12-31

    In co-processing of petroleum and coal, the petroleum fraction may serve as the {open_quotes}liquefaction solvent,{close_quotes} or hydrogen donor, and the aromatics present in the coal liquid may serve as hydrogen {open_quotes}shuttlers{close_quotes} by efficiently transferring hydrogen moieties to places where they are most deficient. The important advantages of co-processing include the following: (1) upgrading of heavy petroleum in a reaction with coal and (2) conversion of coal to synthetic crudes which could be further upgraded to a premium liquid fuel. Co-processing of coal with petroleum, heavy crudes, and residues through catalytic hydrogenation or solvent extraction have been extensively investigated. The studies were typically conducted in the temperature range of 450{degrees}-500{degrees}C under pressurized hydrogen; catalysts are generally also added for hydroconversion of the feedstocks. However, relatively little has been reported in the literature regarding co-processing of coal with heavy petroleum by simple pyrolysis. In this study, co-processing of heavy oil and coal at relatively middle conditions was conducted without the complicating influences of pressurized hydrogen or catalysts. The resulted demonstrate that there is a synergism during co-processing of petroleum and coal. This synergism enhances both the yield and quality of the liquid products. In general, liquids from co-processing the mixture contain a higher content of alkane/alkene, neutral aromatics, lower content of monophenols, and other oxygen containing compounds as compared to the liquids from coal alone. The liquid from the mixture also contains a higher content of naphthenic carbon and naphthenic rings/molecules than those from coal liquid. This suggests that the product from the mixture can be easily upgraded to a premium quality fuel.

  17. Lifecycle-analysis for heavy vehicles.

    SciTech Connect (OSTI)

    Gaines, L.

    1998-04-16

    Various alternative fuels and improved engine and vehicle systems have been proposed in order to reduce emissions and energy use associated with heavy vehicles (predominantly trucks). For example, oil companies have proposed improved methods for converting natural gas to zero-aromatics, zero-sulfur diesel fuel via the Fischer-Tropsch process. Major heavy-duty diesel engine companies are working on ways to simultaneously reduce particulate-matter and NOX emissions. The trend in heavy vehicles is toward use of lightweight materials, tires with lower rolling resistance, and treatments to reduce aerodynamic drag. In this paper, we compare the Mecycle energy use and emissions from trucks using selected alternatives, such as Fisher-Tropsch diesel fuel and advanced fuel-efficient engines. We consider heavy-duty, Class 8 tractor-semitrailer combinations for this analysis. The total life cycle includes production and recycling of the vehicle itself, extraction, processing, and transportation of the fuel itself, and vehicle operation and maintenance. Energy use is considered in toto, as well as those portions that are imported, domestic, and renewable. Emissions of interest include greenhouse gases and criteria pollutants. Angonne's Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) model is used to generate per-vehicle fuel cycle impacts. Energy use and emissions for materials manufacturing and vehicle disposal are estimated by means of materials information from Argonne studies. We conclude that there are trade-offs among impacts. For example, the lowest fossil energy use does not necessarily result in lowest total energy use, and lower tailpipe emissions may not necessarily result in lower lifecycle emissions of all criteria pollutants.

  18. Heavy rains hamper Louisiana gas line

    SciTech Connect (OSTI)

    Horner, C.

    1983-06-01

    Despite heavy rains and flooding a 36-mile gas pipeline loop for Transcontinental Gas Pipe Line Corp. was completed from north of Starks (at the end of Transco's south Louisiana lateral) to the Lake Charles area. Somastic-coated, 42-in. grade X-60 pipe comprises 90% of the route. The contract included multiple 30-42 in. fabrications, installation of six 42-in. gate valves, and expansion of the Gillis compressor station.

  19. A Radiographic Technique With Heavy Ion Microbeams

    SciTech Connect (OSTI)

    Muscio, J.; Somacal, H.; Burlon, A. A.; Debray, M. E.; Valda, A. A.; Kreiner, A. J.; Kesque, J. M.; Minsky, D. M.

    2007-02-12

    In this work, we introduce a new technique to perform densitometric and multielemental analysis of samples at the same time using a simple detector with heavy ion micro-beams. It consists in the simultaneous analysis of X-rays induced in the sample and in a secondary target arranged behind the specimen. The X-rays originated in the secondary target are attenuated when crossing the specimen producing a radiographic image with a monochromatic source.

  20. CP violation in heavy MSSM Higgs scenarios

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Carena, M.; Ellis, J.; Lee, J. S.; Pilaftsis, A.; Wagner, C. E. M.

    2016-02-18

    We introduce and explore new heavy Higgs scenarios in the Minimal Supersymmetric Standard Model (MSSM) with explicit CP violation, which have important phenomenological implications that may be testable at the LHC. For soft supersymmetry-breaking scales MS above a few TeV and a charged Higgs boson mass MH+ above a few hundred GeV, new physics effects including those from explicit CP violation decouple from the light Higgs boson sector. However, such effects can significantly alter the phenomenology of the heavy Higgs bosons while still being consistent with constraints from low-energy observables, for instance electric dipole moments. To consider scenarios with amore » charged Higgs boson much heavier than the Standard Model (SM) particles but much lighter than the supersymmetric particles, we revisit previous calculations of the MSSM Higgs sector. We compute the Higgs boson masses in the presence of CP violating phases, implementing improved matching and renormalization-group (RG) effects, as well as two-loop RG effects from the effective two-Higgs Doublet Model (2HDM) scale MH± to the scale MS. Here, we illustrate the possibility of non-decoupling CP-violating effects in the heavy Higgs sector using new benchmark scenarios named.« less

  1. Multiple Electron Stripping of Heavy Ion Beams

    SciTech Connect (OSTI)

    D. Mueller; L. Grisham; I. Kaganovich; R. L. Watson; V. Horvat; K. E. Zaharakis; Y. Peng

    2002-06-25

    One approach being explored as a route to practical fusion energy uses heavy ion beams focused on an indirect drive target. Such beams will lose electrons while passing through background gas in the target chamber, and therefore it is necessary to assess the rate at which the charge state of the incident beam evolves on the way to the target. Accelerators designed primarily for nuclear physics or high energy physics experiments utilize ion sources that generate highly stripped ions in order to achieve high energies economically. As a result, accelerators capable of producing heavy ion beams of 10 to 40 Mev/amu with charge state 1 currently do not exist. Hence, the stripping cross-sections used to model the performance of heavy ion fusion driver beams have, up to now, been based upon theoretical calculations. We have investigated experimentally the stripping of 3.4 Mev/amu Kr 7+ and Xe +11 in N2; 10.2 MeV/amu Ar +6 in He, N2, Ar and Xe; 19 MeV/amu Ar +8 in He, N2, Ar and Xe; 30 MeV He 1 + in He, N2, Ar and Xe; and 38 MeV/amu N +6 in He, N2, Ar and Xe. The results of these measurements are compared with the theoretical calculations to assess their applicability over a wide range of parameters.

  2. Heavy-quark production in ultrarelativistic heavy-ion collisions within a partonic transport model

    SciTech Connect (OSTI)

    Uphoff, Jan; Fochler, Oliver; Greiner, Carsten; Xu Zhe

    2010-10-15

    The production and space-time evolution of charm and bottom quarks in nucleus-nucleus collisions at the BNL Relativistic Heavy Ion Collider (RHIC) and the CERN Large Hadron Collider (LHC) are investigated with the partonic transport model BAMPS (Boltzmann approach of multiparton scatterings). Heavy quarks, produced in primary hard parton scatterings during nucleon-nucleon collisions, are sampled using the Monte Carlo event generator pythia or the leading-order minijet model in conjunction with the Glauber model, revealing a strong sensitivity on the parton distribution functions, scales, and heavy-quark mass. In a comprehensive study exploring different charm masses, K factors, and possible initial gluon conditions, secondary production and the evolution of heavy quarks are examined within a fully dynamic BAMPS simulation for central heavy-ion collisions at RHIC and LHC. Although charm production in the quark-gluon plasma can be neglected at RHIC, it is significant at LHC but very sensitive to the initial conditions and the charm mass. Bottom production in the quark-gluon plasma, however, is negligible both at RHIC and LHC.

  3. Light metal production

    DOE Patents [OSTI]

    Fan, Qinbai

    2016-04-19

    An electrochemical process for the production of light metals, particularly aluminum. Such a process involves contacting a light metal source material with an inorganic acid to form a solution containing the light metal ions in high concentration. The solution is fed to an electrochemical reactor assembly having an anode side containing an anode and a cathode side containing a cathode, with anode side and the cathode side separated by a bipolar membrane, with the solution being fed to the anode side. Light metal ions are electrochemically transferred through the bipolar membrane to the cathode side. The process further involves reducing the light metal ions to light metal powder. An associated processing system is also provided.

  4. Method for removing metal ions from solution with titanate sorbents

    SciTech Connect (OSTI)

    Lundquist, S.H.; White, L.R.

    1999-11-23

    A method for removing metal ions from solution comprises the steps of providing titanate particles by spray-drying a solution or slurry comprising sorbent titanates having a particle size up to 20 micrometers, optionally in the presence of polymer free of cellulose functionality as binder. The sorbent is active towards heavy metals from Periodic Table (CAS version) Groups IA, IIA, IB, IIB, IIIB, and VIII, to provide monodisperse, substantially spherical particles in a yield of at least 70% of theoretical yield which have a particle size distribution in the range of 1 to 500 micrometers. The particles can be used free flowing in columns or beds, or entrapped in a nonwoven, fibrous web or matrix or a cast porous membrane, to selectively remove metal ions from aqueous or organic liquid.

  5. Method for removing metal ions from solution with titanate sorbents

    DOE Patents [OSTI]

    Lundquist, Susan H.; White, Lloyd R.

    1999-01-01

    A method for removing metal ions from solution comprises the steps of providing titanate particles by spray-drying a solution or slurry comprising sorbent titanates having a particle size up to 20 micrometers, optionally in the presence of polymer free of cellulose functionality as binder, said sorbent being active towards heavy metals from Periodic Table (CAS version) Groups IA, IIA, IB, IIB, IIIB, and VIII, to provide monodisperse, substantially spherical particles in a yield of at least 70 percent of theoretical yield and having a particle size distribution in the range of 1 to 500 micrometers. The particles can be used free flowing in columns or beds, or entrapped in a nonwoven, fibrous web or matrix or a cast porous membrane, to selectively remove metal ions from aqueous or organic liquid.

  6. Metal atomization spray nozzle

    DOE Patents [OSTI]

    Huxford, Theodore J.

    1993-01-01

    A spray nozzle for a magnetohydrodynamic atomization apparatus has a feed passage for molten metal and a pair of spray electrodes mounted in the feed passage. The electrodes, diverging surfaces which define a nozzle throat and diverge at an acute angle from the throat. Current passes through molten metal when fed through the throat which creates the Lorentz force necessary to provide atomization of the molten metal.

  7. Metal atomization spray nozzle

    DOE Patents [OSTI]

    Huxford, T.J.

    1993-11-16

    A spray nozzle for a magnetohydrodynamic atomization apparatus has a feed passage for molten metal and a pair of spray electrodes mounted in the feed passage. The electrodes, diverging surfaces which define a nozzle throat and diverge at an acute angle from the throat. Current passes through molten metal when fed through the throat which creates the Lorentz force necessary to provide atomization of the molten metal. 6 figures.

  8. Metal atom oxidation laser

    DOE Patents [OSTI]

    Jensen, R.J.; Rice, W.W.; Beattie, W.H.

    1975-10-28

    A chemical laser which operates by formation of metal or carbon atoms and reaction of such atoms with a gaseous oxidizer in an optical resonant cavity is described. The lasing species are diatomic or polyatomic in nature and are readily produced by exchange or other abstraction reactions between the metal or carbon atoms and the oxidizer. The lasing molecules may be metal or carbon monohalides or monoxides. (auth)

  9. Metal atom oxidation laser

    DOE Patents [OSTI]

    Jensen, R.J.; Rice, W.W.; Beattie, W.H.

    1975-10-28

    A chemical laser which operates by formation of metal or carbon atoms and reaction of such atoms with a gaseous oxidizer in an optical resonant cavity is described. The lasing species are diatomic or polyatomic in nature and are readily produced by exchange or other abstraction reactions between the metal or carbon atoms and the oxidizer. The lasing molecules may be metal or carbon monohalides or monoxides.

  10. Probing metal solidification nondestructively

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Probing metal solidification nondestructively Probing metal solidification nondestructively This is the first time that high-energy protons have been used to nondestructively image a large metal sample during melting and solidification. April 11, 2014 An x-ray image of a 200 micron thick aluminum-14 atomic percent copper alloy during directional solidification, highlighting the growth of an aluminum-rich branched structure (dendrite) and the advancing solid-liquid (planar) interface. The

  11. Supported metal alloy catalysts

    DOE Patents [OSTI]

    Barrera, Joseph; Smith, David C.

    2000-01-01

    A process of preparing a Group IV, V, or VI metal carbonitride including reacting a Group IV, V, or VI metal amide complex with ammonia to obtain an intermediate product; and, heating the intermediate product to temperatures and for times sufficient to form a Group IV, V, or VI metal carbonitride is provided together with the product of the process and a process of reforming an n-alkane by use of the product.

  12. Closed cell metal foam method

    DOE Patents [OSTI]

    Patten, James W.

    1978-01-01

    Foamed metals and metal alloys which have a closed cellular structure are prepared by heating a metal body containing entrapped inert gas uniformly distributed throughout to a temperature above the melting point of the metal and maintaining the body at this temperature a period of time sufficient to permit the entrapped gas to expand, forming individual cells within the molten metal, thus expanding and foaming the molten metal. After cell formation has reached the desired amount, the foamed molten metal body is cooled to below the melting temperature of the metal. The void area or density of the foamed metal is controlled by predetermining the amount of inert gas entrapped in the metal body and by the period of time the metal body is maintained in the molten state. This method is useful for preparing foamed metals and metal alloys from any metal or other material of which a body containing entrapped inert gas can be prepared.

  13. Nitrided Metallic Bipolar Plates

    Broader source: Energy.gov [DOE]

    This presentation, which focuses on nitrided metallic bipolar plates, was given by M. P. Brady of ORNL at a February 2007 meeting on new fuel cell projects.

  14. Method of producing homogeneous mixed metal oxides and metal-metal oxide mixtures

    DOE Patents [OSTI]

    Quinby, Thomas C.

    1978-01-01

    Metal powders, metal oxide powders, and mixtures thereof of controlled particle size are provided by reacting an aqueous solution containing dissolved metal values with excess urea. Upon heating, urea reacts with water from the solution leaving a molten urea solution containing the metal values. The molten urea solution is heated to above about 180.degree. C. whereupon metal values precipitate homogeneously as a powder. The powder is reduced to metal or calcined to form oxide particles. One or more metal oxides in a mixture can be selectively reduced to produce metal particles or a mixture of metal and metal oxide particles.

  15. Silicon metal-semiconductor-metal photodetector

    DOE Patents [OSTI]

    Brueck, Steven R. J.; Myers, David R.; Sharma, Ashwani K.

    1995-01-01

    Silicon MSM photodiodes sensitive to radiation in the visible to near infrared spectral range are produced by altering the absorption characteristics of crystalline Si by ion implantation. The implantation produces a defected region below the surface of the silicon with the highest concentration of defects at its base which acts to reduce the contribution of charge carriers formed below the defected layer. The charge carriers generated by the radiation in the upper regions of the defected layer are very quickly collected between biased Schottky barrier electrodes which form a metal-semiconductor-metal structure for the photodiode.

  16. Silicon metal-semiconductor-metal photodetector

    DOE Patents [OSTI]

    Brueck, Steven R. J.; Myers, David R.; Sharma, Ashwani K.

    1997-01-01

    Silicon MSM photodiodes sensitive to radiation in the visible to near infrared spectral range are produced by altering the absorption characteristics of crystalline Si by ion implantation. The implantation produces a defected region below the surface of the silicon with the highest concentration of defects at its base which acts to reduce the contribution of charge carriers formed below the defected layer. The charge carriers generated by the radiation in the upper regions of the defected layer are very quickly collected between biased Schottky barrier electrodes which form a metal-semiconductor-metal structure for the photodiode.

  17. PRODUCTION OF PLUTONIUM METAL

    DOE Patents [OSTI]

    Lyon, W.L.; Moore, R.H.

    1961-01-17

    A process is given for producing plutonium metal by the reduction of plutonium chloride, dissolved in alkali metal chloride plus or minus aluminum chloride, with magnesium or a magnesium-aluminum alloy at between 700 and 800 deg C and separating the plutonium or plutonium-aluminum alloy formed from the salt.

  18. METAL SURFACE TREATMENT

    DOE Patents [OSTI]

    Eubank, L.D.

    1958-08-12

    Improved flux baths are described for use in conjunction with hot dipped coatings for uranium. The flux bath consists of molten alkali metal, or alkaline earth metal halides. One preferred embodiment comprises a bath containing molten KCl, NaCl, and LiCl in proportions approximating the triple eutectic.

  19. Porous metallic bodies

    DOE Patents [OSTI]

    Landingham, R.L.

    1984-03-13

    Porous metallic bodies having a substantially uniform pore size of less than about 200 microns and a density of less than about 25 percent theoretical, as well as the method for making them, are disclosed. Group IIA, IIIB, IVB, VB, and rare earth metal hydrides a

  20. Heavy flavour phenomenology from lattice QCD

    SciTech Connect (OSTI)

    Gamiz, Elvira; /Fermilab

    2010-01-01

    Heavy quark quantities are useful for testing lattice techniques against well known experimental results, as well as for testing the StandardModel (SM), and searching for physics beyond the SM. I review the results of recent lattice calculations relevant for this program including those of B and D decay constants and semileptonic decay form factors, and neutral B mixing. The impact of future improvements of lattice results on the clarification of the origin of several disagreements between theory and experiment which are starting to show up are briefly discussed.

  1. Process for upgrading heavy hydrocarbonaceous oils

    SciTech Connect (OSTI)

    Fisher, I.P.; Souhrada, F.; Woods, H.J.

    1981-10-13

    An integrated upgrading process is disclosed which can be used to lower the specific gravity, viscosity and boiling range of heavy, viscous hydrocarbonaceous oil . The process consists of fractionally distilling the oil, treating its residuum with a hydrogen donor material under hydrocracking conditions, fractionally distilling the effluent from the hydrocracking zone and rehydrogenating that portion boiling from about 180/sup 0/ C to 350/sup 0/ C for recycling to the hydrocracking zone. The liquid portion of the oil not recycled can be recombined into a reconstituted crude suitable for transporting by normal crude pipelines.

  2. Pipeline transportation of heavy crude oil

    SciTech Connect (OSTI)

    Kessick, M.A.; St. Denis, C.E.

    1982-08-10

    Heavy crude oils are transported by pipeline from deposit location to a remote upgrading location by emulsifying the crude oil using deaerated sodium hydroxide solution, conveying the oilin-water emulsion through the pipeline, and recovery of the oil from the oil-in-water emulsion by inverting the emulsion and dewatering the resulting water-in-oil emulsion. The emulsion inversion may be effected using slaked lime, resulting in recovery of a substantial proportion of the sodium hydroxide used in the initial emulsification. The sodium hydroxide solution may be recycled by a separate pipeline for reuse or treated for discharge.

  3. HEAVY WATER COMPONENTS TEST REACTOR DECOMMISSIONING

    SciTech Connect (OSTI)

    Austin, W.; Brinkley, D.

    2011-10-13

    The Heavy Water Components Test Reactor (HWCTR) Decommissioning Project was initiated in 2009 as a Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) Removal Action with funding from the American Recovery and Reinvestment Act (ARRA). This paper summarizes the history prior to 2009, the major D&D activities, and final end state of the facility at completion of decommissioning in June 2011. The HWCTR facility was built in 1961, operated from 1962 to 1964, and is located in the northwest quadrant of the Savannah River Site (SRS) approximately three miles from the site boundary. The HWCTR was a pressurized heavy water test reactor used to develop candidate fuel designs for heavy water power reactors. In December of 1964, operations were terminated and the facility was placed in a standby condition as a result of the decision by the U.S. Atomic Energy Commission to redirect research and development work on heavy water power reactors to reactors cooled with organic materials. For about one year, site personnel maintained the facility in a standby status, and then retired the reactor in place. In the early 1990s, DOE began planning to decommission HWCTR. Yet, in the face of new budget constraints, DOE deferred dismantlement and placed HWCTR in an extended surveillance and maintenance mode. The doors of the reactor facility were welded shut to protect workers and discourage intruders. In 2009 the $1.6 billion allocation from the ARRA to SRS for site footprint reduction at SRS reopened the doors to HWCTR - this time for final decommissioning. Alternative studies concluded that the most environmentally safe, cost effective option for final decommissioning was to remove the reactor vessel, both steam generators, and all equipment above grade including the dome. The transfer coffin, originally above grade, was to be placed in the cavity vacated by the reactor vessel and the remaining below grade spaces would be grouted. Once all above equipment including the dome was removed, a concrete cover was to be placed over the remaining footprint and the groundwater monitored for an indefinite period to ensure compliance with environmental regulations.

  4. High-energy accelerator for beams of heavy ions

    DOE Patents [OSTI]

    Martin, Ronald L. (La Grange, IL); Arnold, Richard C. (Chicago, IL)

    1978-01-01

    An apparatus for accelerating heavy ions to high energies and directing the accelerated ions at a target comprises a source of singly ionized heavy ions of an element or compound of greater than 100 atomic mass units, means for accelerating the heavy ions, a storage ring for accumulating the accelerated heavy ions and switching means for switching the heavy ions from the storage ring to strike a target substantially simultaneously from a plurality of directions. In a particular embodiment the heavy ion that is accelerated is singly ionized hydrogen iodide. After acceleration, if the beam is of molecular ions, the ions are dissociated to leave an accelerated singly ionized atomic ion in a beam. Extraction of the beam may be accomplished by stripping all the electrons from the atomic ion to switch the beam from the storage ring by bending it in magnetic field of the storage ring.

  5. Production of magnesium metal

    DOE Patents [OSTI]

    Blencoe, James G. [Harriman, TN; Anovitz, Lawrence M. [Knoxville, TN; Palmer, Donald A. [Oliver Springs, TN; Beard, James S. [Martinsville, VA

    2010-02-23

    A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention further relates to a process for production of magnesium metal or a magnesium compound where an external source of carbon dioxide is not used in any of the reactions of the process. The invention also relates to the magnesium metal produced by the processes described herein.

  6. Metallization of electronic insulators

    DOE Patents [OSTI]

    Gottesfeld, Shimshon (Los Alamos, NM); Uribe, Francisco A. (Los Alamos, NM)

    1994-01-01

    An electroplated element is formed to include an insulating substrate, a conducting polymer polymerized in situ on the substrate, and a metal layer deposited on the conducting polymer. In one application a circuit board is formed by polymerizing pyrrole on an epoxy-fiberglass substrate in a single step process and then electrodepositing a metal over the resulting polypyrrole polymer. No chemical deposition of the metal is required prior to electroplating and the resulting layer of substrate-polymer-metal has excellent adhesion characteristics. The metal deposition is surprisingly smooth and uniform over the relatively high resistance film of polypyrrole. A continuous manufacturing process is obtained by filtering the solution between successive substrates to remove polymer formed in the solution, by maintaining the solution oxidizing potential within selected limits, and by adding a strong oxidant, such as KMnO.sub.4 at periodic intervals to maintain a low sheet resistivity in the resulting conducting polymer film.

  7. Energy 101: Heavy Duty Vehicle Efficiency | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy Duty Vehicle Efficiency Energy 101: Heavy Duty Vehicle Efficiency Addthis Description Although Class 8 Trucks only make up 4% of the vehicles on the road, they use about 20% of the nation's transportation fuel. In this video, learn how new fuel-efficient technologies are making our country's big rigs quieter, less polluting, more energy-efficient, and less expensive to operate over time. Topic Vehicles Text Version Below is the text version for the Energy 101: Heavy Duty Vehicle Efficiency

  8. Fragmentation, NRQCD and Factorization in Heavy Quarkonium Production

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Fragmentation, NRQCD and Factorization in Heavy Quarkonium Production Citation Details In-Document Search Title: Fragmentation, NRQCD and Factorization in Heavy Quarkonium Production We discuss factorization in heavy quarkonium production in high energy collisions using NRQCD. Infrared divergences at NNLO are not matched by conventional NRQCD matrix elements. However, we show that gauge invariance and factorization require that conventional NRQCD

  9. Heavy oil catalytic cracking apparatus (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Heavy oil catalytic cracking apparatus Citation Details In-Document Search Title: Heavy oil catalytic cracking apparatus This patent describes an apparatus for the fluidized catalytic cracking of a heavy hydrocarbon feed comprising hydrocarbons having a boiling point above about 650{degrees} F to lighter products by contact the feed with catalytic cracking catalyst. It comprises a catalytic cracking reactor means; a separation means connective with the reactor outlet; a primary stripping means

  10. Heavy pair production currents with general quantum numbers in

    Office of Scientific and Technical Information (OSTI)

    dimensionally regularized nonrelativistic QCD (Journal Article) | SciTech Connect Heavy pair production currents with general quantum numbers in dimensionally regularized nonrelativistic QCD Citation Details In-Document Search Title: Heavy pair production currents with general quantum numbers in dimensionally regularized nonrelativistic QCD We discuss the form and construction of general color singlet heavy particle-antiparticle pair production currents for arbitrary quantum numbers, and

  11. The Heavy Ion Fusion Science Virtual National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Heavy Ion Fusion Science Virtual National Laboratory Python in a Parallel Environment Dave Grote - LLNL & LBNL NUG2013 User Day Wednesday, February 15, 2013 Slide 2 The Heavy Ion Fusion Science Virtual National Laboratory Outline * Why we use Python * How we use Python * Parallel Python with pyMPI * Our graphics model with Pygist * Parallel Python drawbacks and resolutions - Start up time - Static building * Conclusions Slide 3 The Heavy Ion Fusion Science Virtual National Laboratory 3

  12. Electron-State Hybridization in Heavy-Fermion Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron-State Hybridization in Heavy-Fermion Systems Print Heavy-fermion systems are characterized by electrons with extremely large effective masses. The corresponding heavy-electron "quasiparticle" states are close to the Fermi energy and govern the thermodynamic, transport, and, in part, magnetic properties of these materials. In the case of rare-earth compounds, the quasiparticle states arise from the interactions (hybridization) of valence states with strongly localized 4f

  13. Electron-State Hybridization in Heavy-Fermion Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron-State Hybridization in Heavy-Fermion Systems Print Heavy-fermion systems are characterized by electrons with extremely large effective masses. The corresponding heavy-electron "quasiparticle" states are close to the Fermi energy and govern the thermodynamic, transport, and, in part, magnetic properties of these materials. In the case of rare-earth compounds, the quasiparticle states arise from the interactions (hybridization) of valence states with strongly localized 4f

  14. A predictive standard model for heavy electron systems (Conference) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect SciTech Connect Search Results Conference: A predictive standard model for heavy electron systems Citation Details In-Document Search Title: A predictive standard model for heavy electron systems We propose a predictive standard model for heavy electron systems based on a detailed phenomenological two-fluid description of existing experimental data. It leads to a new phase diagram that replaces the Doniach picture, describes the emergent anomalous scaling behavior of the

  15. Electron-State Hybridization in Heavy-Fermion Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron-State Hybridization in Heavy-Fermion Systems Print Heavy-fermion systems are characterized by electrons with extremely large effective masses. The corresponding heavy-electron "quasiparticle" states are close to the Fermi energy and govern the thermodynamic, transport, and, in part, magnetic properties of these materials. In the case of rare-earth compounds, the quasiparticle states arise from the interactions (hybridization) of valence states with strongly localized 4f

  16. Heavy Vehicle Systems Optimization Peer Review | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy Vehicle Systems Optimization Peer Review Heavy Vehicle Systems Optimization Peer Review This report is a summary and analysis of comments from the Review Panel at the FY 2006 DOE Heavy Vehicle Systems Optimization Merit Review and Peer Evaluation, held April 18-20, 2006. PDF icon Merit Review and Peer Evaluation More Documents & Publications Advanced Combustion Engine R&D and Fuels Technology Merit Review 2013 Annual Merit Review Results Report 2013 Annual Merit Review Results

  17. QCD Factorization for heavy quarkonium production at collider energies

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect QCD Factorization for heavy quarkonium production at collider energies Citation Details In-Document Search Title: QCD Factorization for heavy quarkonium production at collider energies In this talk, I briefly review several models of the heavy quarkonium production at collider energies, and discuss the status of QCD factorization for these production models. Authors: Qiu Jianwei [1] ; Physics Department, Brookhaven National Laboratory, Upton, New York

  18. Inhalation radiotoxicity of irradiated thorium as a heavy water reactor

    Office of Scientific and Technical Information (OSTI)

    fuel (Conference) | SciTech Connect Conference: Inhalation radiotoxicity of irradiated thorium as a heavy water reactor fuel Citation Details In-Document Search Title: Inhalation radiotoxicity of irradiated thorium as a heavy water reactor fuel The online refueling capability of Heavy Water Reactors (HWRs), and their good neutron economy, allows a relatively high amount of neutron absorption in breeding materials to occur during normal fuel irradiation. This characteristic makes HWRs

  19. Critical condition in gravitational shock wave collision and heavy ion

    Office of Scientific and Technical Information (OSTI)

    collisions (Journal Article) | SciTech Connect Critical condition in gravitational shock wave collision and heavy ion collisions Citation Details In-Document Search Title: Critical condition in gravitational shock wave collision and heavy ion collisions In this paper, we derive a critical condition for matter equilibration in heavy ion collisions using a holographic approach. Gravitational shock waves with infinite transverse extension are used to model an infinite nucleus. We construct the

  20. QCD Prediction for Heavy Boson Transverse Momentum Distributions (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect QCD Prediction for Heavy Boson Transverse Momentum Distributions Citation Details In-Document Search Title: QCD Prediction for Heavy Boson Transverse Momentum Distributions We investigate the predictive power of the Collins, Soper, and Sterman b -space QCD resummation formalism for transverse momentum (Q{sub T}) distributions of heavy boson production in hadronic collisions. We show that the predictive power has a strong dependence on the collision energy S in

  1. QCD Resummation for Heavy Quarkonium Production in High Energy Collisions

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect QCD Resummation for Heavy Quarkonium Production in High Energy Collisions Citation Details In-Document Search Title: QCD Resummation for Heavy Quarkonium Production in High Energy Collisions Using e{sup +}e{sup -}{yields}J/{psi}+X as a case study, we explicitly demonstrate that the perturbatively calculated cross section for heavy quarkonium production in terms of the NRQCD factorization formalism has large logarithms as the collision energy s>>M,

  2. Flexibility in heavy oil upgrading with unicracking/HDS technology

    SciTech Connect (OSTI)

    Hennig, H.; Baron, K.; Moorhead, E.L.; Smith, M.

    1984-03-01

    With petroleum reserves becoming heavier and the demand for bottom of the barrel products greatly reduced, refiners are increasing their capabilities to upgrade heavy oil. Many heavy oil upgrading options are available and the best strategy for each refiner is not obvious. The best approach will depend on the specific circumstances and goals of the refiner. This presentation discusses the relative merits of several heavy oil upgrading options utilizing the Unicracking/HDS process.

  3. Accident analysis of heavy water cooled thorium breeder reactor (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect SciTech Connect Search Results Journal Article: Accident analysis of heavy water cooled thorium breeder reactor Citation Details In-Document Search Title: Accident analysis of heavy water cooled thorium breeder reactor Thorium has lately attracted considerable attention because it is accumulating as a by-product of large scale rare earth mining. The objective of research is to analyze transient behavior of a heavy water cooled thorium breeder that is designed by

  4. Triangularity and dipole asymmetry in relativistic heavy ion collisions

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Triangularity and dipole asymmetry in relativistic heavy ion collisions Citation Details In-Document Search Title: Triangularity and dipole asymmetry in relativistic heavy ion collisions We introduce a cumulant expansion to parametrize possible initial conditions in relativistic heavy ion collisions. We show that the cumulant expansion converges and that it can systematically reproduce the results of Glauber type initial conditions. At third order in the

  5. APBF-DEC Heavy Duty NOx Adsorber/DPF Project: Heavy Duty Linehaul Platform

    Broader source: Energy.gov (indexed) [DOE]

    Project Update | Department of Energy Ricardo Inc., Chicago Technical Center PDF icon deer_2003_may.pdf More Documents & Publications Status of APBF-DEC NOx Adsorber/DPF Projects APBF- DEC Heavy-Duty NOx Adsorber/DPF Project: Catalyst Aging Study APBF-DEC Light-duty NOx Adsorber/DPF Project

  6. METHOD OF OPERATING A HEAVY WATER MODERATED REACTOR

    DOE Patents [OSTI]

    Vernon, H.C.

    1962-08-14

    A method of removing fission products from the heavy water used in a slurry type nuclear reactor is described. According to the process the slurry is steam distilled with carbon tetrachloride so that at least a part of the heavy water and carbon tetrachloride are vaporized; the heavy water and carbon tetrachloride are separated; the carbon tetrachloride is returned to the steam distillation column at different points in the column to aid in depositing the slurry particles at the bottom of the column; and the heavy water portion of the condensate is purified. (AEC)

  7. QCD Resummation for Heavy Quarkonium Production in High Energy...

    Office of Scientific and Technical Information (OSTI)

    formalism has large logarithms as the collision energy s>>M, the heavy quarkonium mass. ... Authors: Kang Zhongbo ; Qiu Jianwei 1 + Show Author Affiliations Department of Physics ...

  8. Design and Implementation of Silicon Nitride Valves for Heavy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Design and Implementation of Silicon Nitride Valves for Heavy Duty Diesel Engines Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER ...

  9. LNT + SCR Aftertreatment for Medium-Heavy Duty Applications:...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    LNT + SCR Aftertreatment for Medium-Heavy Duty Applications: A Systems Approach Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER ...

  10. An effective field theory for collinear and soft gluons: Heavy...

    Office of Scientific and Technical Information (OSTI)

    An effective field theory for collinear and soft gluons: Heavy to light decays Citation ... Subject: 72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS; 71 CLASSICAL AND QUANTUM ...

  11. Heavy-Duty HCCI Development Activities | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    and Posters PDF icon 2005deerduffy.pdf More Documents & Publications Heavy-Truck Clean Diesel (HTCD) Program Diesel HCCI Results at Caterpillar Diesel HCCI Results at ...

  12. Heavy-Truck Clean Diesel (HTCD) Program | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Caterpillar PDF icon 2004deerduffy.pdf More Documents & Publications Diesel HCCI Results at Caterpillar Diesel HCCI Results at Caterpillar Heavy-Duty HCCI Development Activities

  13. Heavy Duty & Medium Duty Drive Cycle Data Collection for Modeling...

    Broader source: Energy.gov (indexed) [DOE]

    Program Truck Duty Cycle and Performance Data Collection and Analysis Program Vehicle Technologies Office Merit Review 2014: Powertrain Controls Optimization for Heavy Duty ...

  14. Heavy Truck Clean Diesel (HTCD) Program: 2007 Demonstration Truck...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications Transient Simulation of a 2007 Prototype Heavy-Duty Engine Diesel Aftertreatment Systems development Demonstration of a 50% Thermal Efficient Diesel ...

  15. California Policy Stimulates Carbon Negative CNG for Heavy Duty...

    Broader source: Energy.gov (indexed) [DOE]

    Describes system for fueling truck fleet with biomethane generated from anaerobic ... Advanced Natural Gas Engine Technology for Heavy Duty Vehicles Technical Workshop: Annual ...

  16. Establishment of the Heavy Isotopes Lead Materials Management...

    Office of Scientific and Technical Information (OSTI)

    Lead Materials Management Organization (LMMO) Citation Details In-Document Search Title: Establishment of the Heavy Isotopes Lead Materials Management Organization (LMMO) ...

  17. Can CP violation be observed in heavy-ion collisions?

    SciTech Connect (OSTI)

    Khriplovich, I. B. Rudenko, A. S.

    2012-09-15

    We demonstrate that, at least at present, there is no convincing way to detect CP violation in heavy-ion collisions.

  18. The Role of Batteries in Auxiliary Power for Heavy Trucks

    SciTech Connect (OSTI)

    D. Crouch

    2001-12-12

    The problem that this paper deals with is that Heavy trucks leave their engines on while they are stopped and the driver is sleeping, eating, etc.

  19. Heavy-ion Accelerators for Testing Microelectronic Components...

    Office of Science (SC) Website

    Heavy-ion Accelerators for Testing Microelectronic Components at LBNL Nuclear Physics (NP) NP Home About Research Facilities Science Highlights Benefits of NP Applications of ...

  20. NOx Adsorber Regeneration Phenomena In Heavy Duty Applications...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Adsorber Regeneration Phenomena In Heavy Duty Applications NOx Adsorber Regeneration ... More Documents & Publications Fuel-Borne Reductants for NOx Aftertreatment: Preliminary ...

  1. Linear and cubic response to the initial eccentricity in heavy...

    Office of Scientific and Technical Information (OSTI)

    Title: Linear and cubic response to the initial eccentricity in heavy-ion collisions Authors: Noronha-Hostler, Jacquelyn ; Yan, Li ; Gardim, Fernando G. ; Ollitrault, Jean-Yves ...

  2. Heavy surface state in a possible topological Kondo insulator...

    Office of Scientific and Technical Information (OSTI)

    Heavy surface state in a possible topological Kondo insulator: Magnetothermoelectric transport on the (011) plane of SmB 6 This content will become publicly available on February...

  3. Off-Highway Heavy Vehicle Diesel Efficiency Improvement and Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Off-Highway Heavy Vehicle Diesel Efficiency Improvement and Emissions Reduction 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon...

  4. Synthesis of Metal-Metal Oxide Catalysts and Electrocatalysts...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synthesis of Metal-Metal Oxide Catalysts and Electrocatalysts Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication...

  5. Molecular Genetics of Metal Detoxification: Prospects for Phytoremediation

    SciTech Connect (OSTI)

    Ow, David W. ow@pgec.ams.usda.gov

    2000-09-01

    Unlike compounds that can be broken down, the remediation of most heavy metals and radionuclides requires physical extraction from contaminated sources. Plants can extract inorganics, but effective phytoextraction requires plants that produce high biomass, grow rapidly and possess high capacity-uptake for the inorganic substance. Either hyperaccumulator plants must be bred for increased growth and biomass or hyperaccumulation traits must be engineered into fast growing, high biomass plants. This latter approach requires fundamental knowledge of the molecular mechanisms in the uptake and storage of inorganics. Much has been learned in recent years on how plants and certain fungi chelate and transport selected heavy metals. This progress has been facilitated by the use of Schizosaccharomyces pombe as a model system. The use of a model organism for study permits rapid characterization of the molecular process. As target genes are identified in a model organism, their sequences can be modified for expression in a heterologous host or aid in the search of homologous genes in more complex organisms. Moreover, as plant nutrient uptake is intrinsically linked to the association with rhizospheric fungi, elucidating metal sequestration in this fungus permits additional opportunities for engineering rhizospheric microbes to assist in phytoextraction.

  6. Metal nanodisks using bicellar templates

    DOE Patents [OSTI]

    Song, Yujiang; Shelnutt, John A

    2013-12-03

    Metallic nanodisks and a method of making them. The metallic nanodisks are wheel-shaped structures that that provide large surface areas for catalytic applications. The metallic nanodisks are grown within bicelles (disk-like micelles) that template the growth of the metal in the form of approximately circular dendritic sheets. The zero-valent metal forming the nanodisks is formed by reduction of a metal ion using a suitable electron donor species.

  7. Metal Aminoboranes - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Materials Advanced Materials Find More Like This Return to Search Metal Aminoboranes Los Alamos National Laboratory Contact LANL About This Technology Technology Marketing Summary Metal aminoboranes of the formula M(NH.sub.2BH.sub.3).sub.n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other metal aminoboranes. Metal aminoboranes can be dehydrogenated to form hydrogen and a reaction product. The reaction

  8. Precious Metals | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Precious Metals General Information: The Materials Handling group provides Precious Metals receiving and documentation (PM's) for research programs funded by the Department of Energy (DOE). Precious metals are obtained from the DOE's Business Center for Precious Metals Sales and Recovery (BCPMSR). The return of scrap and excess precious metals to the BCPMSR is also provided by this group. Metals under this control are: GOLD - SILVER - PLATINUM - RHODIUM - PALLADIUM - IRIDIUM - OSMIUM - RUTHENIUM

  9. Method for producing metallic nanoparticles

    DOE Patents [OSTI]

    Phillips, Jonathan; Perry, William L.; Kroenke, William J.

    2004-02-10

    Method for producing metallic nanoparticles. The method includes generating an aerosol of solid metallic microparticles, generating non-oxidizing plasma with a plasma hot zone at a temperature sufficiently high to vaporize the microparticles into metal vapor, and directing the aerosol into the hot zone of the plasma. The microparticles vaporize in the hot zone to metal vapor. The metal vapor is directed away from the hot zone and to the plasma afterglow where it cools and condenses to form solid metallic nanoparticles.

  10. Method for producing metallic microparticles

    DOE Patents [OSTI]

    Phillips, Jonathan; Perry, William L.; Kroenke, William J.

    2004-06-29

    Method for producing metallic particles. The method converts metallic nanoparticles into larger, spherical metallic particles. An aerosol of solid metallic nanoparticles and a non-oxidizing plasma having a portion sufficiently hot to melt the nanoparticles are generated. The aerosol is directed into the plasma where the metallic nanoparticles melt, collide, join, and spheroidize. The molten spherical metallic particles are directed away from the plasma and enter the afterglow where they cool and solidify.

  11. Mobility of heavy metals through granitic soils using mini column infiltration test

    SciTech Connect (OSTI)

    Zarime, Nur 'Aishah; Yaacob, W. Z.W.

    2014-09-03

    This study is about the mobility of cadmium through compacted granitic soils. Two granitic soils namely the Broga (BGR) and Kajang (KGR) granitic soils were collected in Selangor, Malaysia. Physical and chemical tests were applied for both granitic soils to determine the physical and chemical properties of soil materials. Physical test results shows granitic soils (BGR and KGR) have high percentage of sand ranging between 54%–63% and 46%–54% respectively, an intermediate and intermediate to high plasticity index as well as high specific gravity ie; 2.50–2.59 and 2.45–2.66 respectively. For chemical test, granitic soils shows acidic pH values ranged from 5.35–5.85 for BGR and pH 5.32–5.54 for KGR. For organic matter, SSA and CEC test, it shows low values ranged from 0.22%–0.34% and 0.39%– 0.50% respectively for organic matter test, 17.96 m{sup 2}/g–21.93 m{sup 2}/g and 25.76 m{sup 2}/g–26.83 m{sup 2}/g respectively for SSA test and 0.79 meq/100g–1.35 meq/100g and 1.31 meq/100g–1.35 meq/100g respectively for CEC test. Mini column infiltration test was conducted to determine the retention of cadmium while flowing through granite soils. This test conducted based on the falling head permeability concepts. Different G-force ranging from 231G to 1442G was used in this test. The breakthrough curves show the concentration of Cd becomes higher with the increasing of G-force for both granitic samples (BGR and KGR). The selectivity sorption for both granites ranked in the following decreasing order of; 231G>519G>923G>1442G. Results demonstrated that granitic soils also have low buffering capacity due to low resist of pH changes.

  12. Assessment of heavy metals in seawater and fish tissues at Pulau...

    Office of Scientific and Technical Information (OSTI)

    did not exceed the allowable limit of Malaysian Food Act (1983) and Regulation (1985). ... Nuclear Science, Technology, and Engineering Conference 2014, Skudai, Johor ...

  13. Constructed Wetlands for Removal of Heavy Metals from NPDES Outfall Effluent

    SciTech Connect (OSTI)

    Nelson, E.A.

    2002-08-29

    The A-01 NPDES outfall at the Savannah River Site receives process wastewater discharges and stormwater runoff from the Savannah River Technology Center. Routine monitoring indicated that copper concentrations were regularly higher than discharge permit limit, necessitating treatment of nearly one million gallons of water each day plus storm runoff to meet compliance standards. A conceptual design for a constructed treatment wetland was developed as the most cost-effective alternative. A pilot study was conducted using mesocosms to confirm that the design concept would reduce copper to acceptable levels. After treatment in the mesocosms, effluent copper concentrations were routinely below permit limits, even though the influent concentrations varied widely.

  14. Transition Metal Switchable Mirror

    ScienceCinema (OSTI)

    None

    2010-01-08

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft.

  15. Transition Metal Switchable Mirror

    ScienceCinema (OSTI)

    None

    2013-05-29

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft. More information at: http://windows.lbl.gov/materials/chromogenics/default.htm

  16. Actinide metal processing

    DOE Patents [OSTI]

    Sauer, Nancy N. (Los Alamos, NM); Watkin, John G. (Los Alamos, NM)

    1992-01-01

    A process of converting an actinide metal such as thorium, uranium, or plnium to an actinide oxide material by admixing the actinide metal in an aqueous medium with a hypochlorite as an oxidizing agent for sufficient time to form the actinide oxide material and recovering the actinide oxide material is provided together with a low temperature process of preparing an actinide oxide nitrate such as uranyl nitrte. Additionally, a composition of matter comprising the reaction product of uranium metal and sodium hypochlorite is provided, the reaction product being an essentially insoluble uranium oxide material suitable for disposal or long term storage.

  17. Liquid metal electric pump

    DOE Patents [OSTI]

    Abbin, J.P.; Andraka, C.E.; Lukens, L.L.; Moreno, J.B.

    1992-01-14

    An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other. 3 figs.

  18. Liquid metal electric pump

    DOE Patents [OSTI]

    Abbin, Joseph P.; Andraka, Charles E.; Lukens, Laurance L.; Moreno, James B.

    1992-01-01

    An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other.

  19. Actinide metal processing

    DOE Patents [OSTI]

    Sauer, N.N.; Watkin, J.G.

    1992-03-24

    A process for converting an actinide metal such as thorium, uranium, or plutonium to an actinide oxide material by admixing the actinide metal in an aqueous medium with a hypochlorite as an oxidizing agent for sufficient time to form the actinide oxide material and recovering the actinide oxide material is described together with a low temperature process for preparing an actinide oxide nitrate such as uranyl nitrate. Additionally, a composition of matter comprising the reaction product of uranium metal and sodium hypochlorite is provided, the reaction product being an essentially insoluble uranium oxide material suitable for disposal or long term storage.

  20. Preparation of uniform nanoparticles of ultra-high purity metal oxides, mixed metal oxides, metals, and metal alloys

    DOE Patents [OSTI]

    Woodfield, Brian F.; Liu, Shengfeng; Boerio-Goates, Juliana; Liu, Qingyuan; Smith, Stacey Janel

    2012-07-03

    In preferred embodiments, metal nanoparticles, mixed-metal (alloy) nanoparticles, metal oxide nanoparticles and mixed-metal oxide nanoparticles are provided. According to embodiments, the nanoparticles may possess narrow size distributions and high purities. In certain preferred embodiments, methods of preparing metal nanoparticles, mixed-metal nanoparticles, metal oxide nanoparticles and mixed-metal nanoparticles are provided. These methods may provide tight control of particle size, size distribution, and oxidation state. Other preferred embodiments relate to a precursor material that may be used to form nanoparticles. In addition, products prepared from such nanoparticles are disclosed.

  1. Heavy Vehicle Propulsion System Materials Program Semiannual Progress Report for October 1998 Through March 1999

    SciTech Connect (OSTI)

    Johnson, R.D.

    1999-06-01

    The purpose of the Heavy Vehicle Propulsion System Materials Program is the development of materials: ceramics, intermetallics, metal alloys, and metal and ceramic coatings, to support the dieselization of class 1-3 trucks to realize a 35% fuel-economy improvement over current gasoline-fueled trucks and to support commercialization of fuel-flexible LE-55 low-emissions, high-efficiency diesel engines for class 7-8 trucks. The Office of Transportation Technologies, Office of Heavy Vehicle Technologies (OIT OHVT) has an active program to develop the technology for advanced LE-55 diesel engines with 55% efficiency and low emissions levels of 2.0 g/bhp-h NOX and 0.05 g/bhp-h particulate. The goal is also for the LE-55 engine to run on natural gas with efficiency approaching that of diesel fuel. The LE-55 program is being completed in FY 1997 and, after approximately 10 years of effort, has largely met the program goals of 55% efficiency and low emissions. However, the commercialization of the LE-55 technology requires more durable materials than those that have been used to demonstrate the goals. Heavy Vehicle Propulsion System Materials will, in concert with the heavy duty diesel engine companies, develop the durable materials required to commercialize the LE-55 technologies. OIT OHVT also recognizes a significant opportunity for reduction in petroleum consumption by dieselization of pickup trucks, vans, and sport utility vehicles. Application of the diesel engine to class 1,2, and 3 trucks is expected to yield a 35% increase in fuel economy per vehicle. The foremost barrier to diesel use in this market is emission control. Once an engine is made certifiable, subsequent challenges will be in cost; noise, vibration, and harshness (NVH); and performance. The design of advanced components for high-efficiency diesel engines has, in some cases, pushed the performance envelope for materials of construction past the point of reliable operation. Higher mechanical and tribological stresses and higher temperatures of advanced designs limit the engine designer; advanced materials allow the design of components that may operate reliably at higher stresses and temperatures, thus enabling more efficient engine designs. Advanced materials also offer the opportunity to improve the emissions, NVH, and performance of diesel engines for pickup trucks, vans, and sport utility vehicles. The principal areas of research are: (1) Cost Effective High Performance Materials and Processing; (2) Advanced Manufacturing Technology; (3)Testing and Characterization; and (4) Materials and Testing Standards.

  2. Oligocyclopentadienyl transition metal complexes

    SciTech Connect (OSTI)

    de Azevedo, Cristina G.; Vollhardt, K. Peter C.

    2002-01-18

    Synthesis, characterization, and reactivity studies of oligocyclopentadienyl transition metal complexes, namely those of fulvalene, tercyclopentadienyl, quatercyclopentadienyl, and pentacyclopentadienyl(cyclopentadienyl) are the subject of this account. Thermal-, photo-, and redox chemistries of homo- and heteropolynuclear complexes are described.

  3. Metal Hydride Storage Materials

    Broader source: Energy.gov [DOE]

    The Fuel Cell Technologies Office's (FCTO's) metal hydride storage materials research focuses on improving the volumetric and gravimetric capacities, hydrogen adsorption/desorption kinetics, cycle life, and reaction thermodynamics of potential material candidates.

  4. Production of magnesium metal

    DOE Patents [OSTI]

    Blencoe, James G.; Anovitz, Lawrence M.; Palmer, Donald A.; Beard, James S.

    2012-04-10

    A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention also relates to the magnesium metal produced by the processes described herein.

  5. Molten metal reactors

    DOE Patents [OSTI]

    Bingham, Dennis N; Klingler, Kerry M; Turner, Terry D; Wilding, Bruce M

    2013-11-05

    A molten metal reactor for converting a carbon material and steam into a gas comprising hydrogen, carbon monoxide, and carbon dioxide is disclosed. The reactor includes an interior crucible having a portion contained within an exterior crucible. The interior crucible includes an inlet and an outlet; the outlet leads to the exterior crucible and may comprise a diffuser. The exterior crucible may contain a molten alkaline metal compound. Contained between the exterior crucible and the interior crucible is at least one baffle.

  6. Coherent behavior in Heavy Fermion materials; Understanding and controlling

    Office of Scientific and Technical Information (OSTI)

    competing interactions in complex oxide heterostructures (Technical Report) | SciTech Connect Coherent behavior in Heavy Fermion materials; Understanding and controlling competing interactions in complex oxide heterostructures Citation Details In-Document Search Title: Coherent behavior in Heavy Fermion materials; Understanding and controlling competing interactions in complex oxide heterostructures Authors: Yarotski, Dmitry Anatolievitch [1] ; Sandberg, Richard L. [1] + Show Author

  7. Observation of heavy elements produced during explosive cold fusion

    SciTech Connect (OSTI)

    Matsumoto, T.; Kurokawa, K. )

    1991-11-01

    This paper reports on many-body fusion reactions that may take place during cold fusion. Heavy elements are observed that might have been produced by such reactions during electrolysis of heavy water. Elements such as sodium, magnesium, aluminum, and zinc are observed inside grain-shaped defects in a palladium rod used in a cold fusion experiment.

  8. NOx Adsorber Regeneration Phenomena In Heavy Duty Applications | Department

    Broader source: Energy.gov (indexed) [DOE]

    of Energy 3 DEER Conference Presentation: Oak Ridge National Laboratory PDF icon 2003_deer_west.pdf More Documents & Publications Fuel-Borne Reductants for NOx Aftertreatment: Preliminary EtOH SCR Study Fuels for Advanced CIDI Engines and Fuel Cells: 2000 Annual Progress Report APBF-DEC Heavy Duty NOx Adsorber/DPF Project: Heavy Duty Linehaul Platform Project Update

  9. Apparatus for upgrading heavy hydrocarbons employing a diluent

    SciTech Connect (OSTI)

    Calderon, J. L.; Layrisse, I.

    1985-06-04

    Apparatus for upgrading heavy hydrocarbonaceous materials for making coke suitable for metallurgical purposes comprises mixing the heavy hydrocarbonaceous materials with a diluent having a closely controlled boiling range so as to facilitate transport, dehydration and desalting of the crude oil. In addition, the diluent aids in controlling temperature and residence time of the crude thereby avoiding premature decomposition.

  10. Combined process for heavy oil, upgrading and synthetic fuel production

    SciTech Connect (OSTI)

    Polomski, R.E.

    1984-06-05

    A process for upgrading heavy oil to fuel products comprises deasphalting the heavy oil with an oxygenated solvent and simultaneously converting the oxygenated solvent and deasphalted oil over a ZSM-5 type catalyst to produce gasoline and distillate boiling range hydrocarbons.

  11. China shows increasing interest in heavy oil and oil sands

    SciTech Connect (OSTI)

    Not Available

    1986-12-01

    China and Canadian and US groups are cooperating in several areas to develop the heavy oil, asphalt, and oil sand deposits of China. The agreements dealing with exploration and upgrading are briefly described. The majority of the paper describes the occurrences of heavy oil, asphalt, and oil sands in China. 1 figure.

  12. Process for upgrading heavy hydrocarbons employing a diluent

    SciTech Connect (OSTI)

    Calderon, J.L.; Layrisse, I.

    1984-06-19

    A process for upgrading heavy hydrocarbonaceous materials for making coke suitable for metallurgical purposes comprises mixing the heavy hydrocarbonaceous materials with a diluent having a closely controlled boiling range so as to facilitate transport, dehydration and desalting of the crude oil. In addition, the diluent aids in controlling temperature and residence time of the crude thereby avoiding premature decomposition.

  13. Upgrading heavy hydrocarbons with supercritical water and light olefins

    SciTech Connect (OSTI)

    Paspek, S. C. Jr.

    1984-11-20

    Heavy hydrocarbons are upgraded and cracked in a process comprising contacting the heavy hydrocarbons with olefins containing 5 or less carbon atoms and a solvent, at a temperature both sufficient for cracking and greater than or equal to the critical temperature of the solvent.

  14. Draft Genome Sequence for Microbacterium laevaniformans Strain OR221, a Bacterium Tolerant to Metals, Nitrate, and Low pH

    SciTech Connect (OSTI)

    Brown, Steven D; Palumbo, Anthony Vito; Panikov, Nikolai; Ariyawansa, Thilini; Klingeman, Dawn Marie; Johnson, Courtney M; Land, Miriam L; Utturkar, Sagar M; Epstein, Slava

    2012-01-01

    Microbacterium laevaniformans strain OR221 was isolated from subsurface sediments obtained from the Field Research Center (FRC) in Oak Ridge, TN. It was characterized as a bacterium tolerant to heavy metals such as uranium, nickel, cobalt, cadmium, as well as nitrate and low pH. We present its draft genome sequence.

  15. Theory of hadronic production of heavy quarks

    SciTech Connect (OSTI)

    Peterson, C.

    1981-07-01

    Conventional theoretical predictions for hadronic production of heavy quarks (Q anti Q) are reviewed and confronted with data. Perturbative hard scattering predictions agree qualitatively well with hidden Q anti Q production (e.g., psi, chi, T) whereas for open Q anti Q-production (e.g., pp ..-->.. ..lambda../sub c//sup +/X) additional mechanisms or inputs are needed to explain the forwardly produced ..lambda../sub c//sup +/ at ISR. It is suggested that the presence of c anti c-pairs on the 1 to 2% level in the hadron Fock state decomposition (intrinsic charm) gives a natural description of the ISR data. The theoretical foundations of the intrinsic charm hypotheses together with its consequences for lepton-induced reactions is discussed in some detail.

  16. Lightweight Composite Materials for Heavy Duty Vehicles

    SciTech Connect (OSTI)

    Pruez, Jacky; Shoukry, Samir; Williams, Gergis; Shoukry, Mark

    2013-08-31

    The main objective of this project is to develop, analyze and validate data, methodologies and tools that support widespread applications of automotive lightweighting technologies. Two underlying principles are guiding the research efforts towards this objective: • Seamless integration between the lightweight materials selected for certain vehicle systems, cost-effective methods for their design and manufacturing, and practical means to enhance their durability while reducing their Life-Cycle-Costs (LCC). • Smooth migration of the experience and findings accumulated so far at WVU in the areas of designing with lightweight materials, innovative joining concepts and durability predictions, from applications to the area of weight savings for heavy vehicle systems and hydrogen storage tanks, to lightweighting applications of selected systems or assemblies in light–duty vehicles.

  17. Rapidity dependence in holographic heavy ion collisions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wilke van der Schee; Schenke, Bjorn

    2015-12-11

    We present an attempt to closely mimic the initial stage of heavy ion collisions within holography, assuming a decoupling of longitudinal and transverse dynamics in the very early stage. We subsequently evolve the obtained initial state using state-of-the-art hydrodynamic simulations and compare results with experimental data. We present results for charged hadron pseudorapidity spectra and directed and elliptic flow as functions of pseudorapidity for √sNN = 200GeV Au-Au and 2.76TeV Pb-Pb collisions. As a result, the directed flow interestingly turns out to be quite sensitive to the viscosity. The results can explain qualitative features of the collisions, but the rapiditymore » spectra in our current model is narrower than the experimental data.« less

  18. Heavy Ion Reaction Modeling for Hadrontherapy Applications

    SciTech Connect (OSTI)

    Cerutti, F.; Ferrari, A.; Enghardt, W.; Gadioli, E.; Mairani, A.; Parodi, K.; Sommerer, F.

    2007-10-26

    A comprehensive and reliable description of nucleus-nucleus interactions represents a crucial need in different interdisciplinary fields. In particular, hadrontherapy monitoring by means of in-beam positron emission tomography (PET) requires, in addition to measuring, the capability of calculating the activity of {beta}{sup +}-decaying nuclei produced in the irradiated tissue. For this purpose, in view of treatment monitoring at the Heidelberg Ion Therapy (HIT) facility, the transport and interaction Monte Carlo code FLUKA is a promising candidate. It is provided with the description of heavy ion reactions at intermediate and low energies by two specific event generators. In-beam PET experiments performed at GSI for a few beam-target combinations have been simulated and first comparisons between the measured and calculated {beta}{sup +}-activity are available.

  19. Heavy crude upgrading using remote natural gas

    SciTech Connect (OSTI)

    Grosboll, M.P.

    1991-12-03

    This paper describes a method of forming an upgraded crude. It comprises: forming hydrogen from methane gas for hydroconverting heavy crude to form a better crude and reduce its viscosity; hydrogenating under hydroconverting conditions of 650 degrees Fahrenheit ({degrees}F)-1000{degrees}F; and 500-3000 pounds per square inch gauge (psig) only a first portion of a crude oil stream less than the total crude oil stream to produce a light oil that has a lowered viscosity; admixing the light oil with the remainder of the crude oil stream not hydrogenated to produce a flowable crude; and transporting the flowable crude to a refinery including a substep of flowing the crude through a pipeline.

  20. Bitumen and heavy oil upgrading in Canada

    SciTech Connect (OSTI)

    Chrones, J. ); Germain, R.R. )

    1989-01-01

    A review is presented of the heavy oil upgrading industry in Canada. Up to now it has been based on the processing of bitumen extracted from oil sands mining operations at two sites, to produce a residue-free, low sulphur, synthetic crude. Carbon rejection has been the prime process technology with delayed coking being used by Suncor and FLUID COKING at Syncrude. Alternative processes for recovering greater amounts of synthetic crude are examined. These include a variety of hydrogen addition processes and combinations which produce pipelineable materials requiring further processing in downstream refineries with expanded capabilities. The Newgrade Energy Inc. upgrader now under construction in Regina, will use fixed-bed, catalytic, atmospheric-residue, hydrogen processing. Two additional projects, also based on hydrogenation, will use ebullated bed catalyst systems; the expansion of Syncrude, now underway, is using the LC Fining Process whereas the announced Husky Bi-Provincial upgrader is based on H-Oil.

  1. Sludge formation during heavy oil upgrading

    SciTech Connect (OSTI)

    Storm, D.A.; Decanio, S.J.; Edwards, J.C.

    1995-12-31

    A soft coke-like substance often forms in the liquid product of visbreaking and hydrocracking processes for upgrading vacuum residue of heavy crude oil. This material usually limits the severity or conversion of the process because it accumulates in downstream equipment. Although the amount of such material produced depends on the crude oil, it has not been possible to correlate its production rate to chemical characteristics of the vacuum residue in a quantitative manner In this work we show that the amount of sludge produced per unit weight of vacuum residue feed in laboratory hydrotreating experiments can be correlated with four chemical characteristic of the vacuum residue: the degree of condensed polynuclear aromaticity, the average number of alkyl-groups substituting the polynuclear aromatics, the ratio of heptane insolubles to pentane insoluble-heptane solubles, and the H/C ratio of the latter fraction. The correlation coefficient is 0.95.

  2. Bitumen and heavy oil upgrading in Canada

    SciTech Connect (OSTI)

    Chrones, J.

    1988-06-01

    A review is presented of the heavy oil upgrading industry in Canada. Up to now it has been based on the processing of bitumen extracted from oil sands mining operations at two sites, to produce a residue-free, low sulfur, synthetic crude. Carbon rejection has been the prime process technology with delayed coking being used by Suncor and FLUID COKING at Syncrude. Alternative processes for recovering greater amounts of synthetic crude are examined. These include a variety of hydrogen addition processes and combinations which produce pipelineable materials requiring further processing in downstream refineries with expanded capabilities. The Newgrade Energy Inc. upgrader, now under construction in Regina, will use fixed-bed, catalytic, atmospheric-residue, hydrogen processing. Two additional products, also based on hydrogenation, will use ebullated bed catalyst systems: the expansion of Syncrude, now underway, is using the LC Fining Process whereas the announced Husky Bi-Provincial upgrader is based on H-Oil.

  3. Gated beam imager for heavy ion beams

    SciTech Connect (OSTI)

    Ahle, Larry; Hopkins, Harvey S.

    1998-12-10

    As part of the work building a small heavy-ion induction accelerator ring, or recirculator, at Lawrence Livermore National Laboratory, a diagnostic device measuring the four-dimensional transverse phase space of the beam in just a single pulse has been developed. This device, the Gated Beam Imager (GBI), consists of a thin plate filled with an array of 100-micron diameter holes and uses a Micro Channel Plate (MCP), a phosphor screen, and a CCD camera to image the beam particles that pass through the holes after they have drifted for a short distance. By time gating the MCP, the time evolution of the beam can also be measured, with each time step requiring a new pulse.

  4. Gated beam imager for heavy ion beams

    SciTech Connect (OSTI)

    Ahle, L.; Hopkins, H.S.

    1998-12-01

    As part of the work building a small heavy-ion induction accelerator ring, or recirculator, at Lawrence Livermore National Laboratory, a diagnostic device measuring the four-dimensional transverse phase space of the beam in just a single pulse has been developed. This device, the Gated Beam Imager (GBI), consists of a thin plate filled with an array of 100-micron diameter holes and uses a Micro Channel Plate (MCP), a phosphor screen, and a CCD camera to image the beam particles that pass through the holes after they have drifted for a short distance. By time gating the MCP, the time evolution of the beam can also be measured, with each time step requiring a new pulse. {copyright} {ital 1998 American Institute of Physics.}

  5. Lithium metal reduction of plutonium oxide to produce plutonium metal

    DOE Patents [OSTI]

    Coops, Melvin S.

    1992-01-01

    A method is described for the chemical reduction of plutonium oxides to plutonium metal by the use of pure lithium metal. Lithium metal is used to reduce plutonium oxide to alpha plutonium metal (alpha-Pu). The lithium oxide by-product is reclaimed by sublimation and converted to the chloride salt, and after electrolysis, is removed as lithium metal. Zinc may be used as a solvent metal to improve thermodynamics of the reduction reaction at lower temperatures. Lithium metal reduction enables plutonium oxide reduction without the production of huge quantities of CaO--CaCl.sub.2 residues normally produced in conventional direct oxide reduction processes.

  6. The Heavy Photon Search experiment at Jefferson Laboratory

    SciTech Connect (OSTI)

    De Napoli, Marzio

    2015-06-01

    Many beyond Standard Model theories predict a new massive gauge boson, a.k.a. 'dark' or 'heavy photon', directly coupling to hidden sector particles with dark charge. The heavy photon is expected to mix with the Standard Model photon through kinetic mixing and therefore couple weakly to normal charge. The Heavy Photon Search (HPS) experiment will search for the heavy photon at the Thomas Jefferson National Accelerator Facility (JLab), in the mass range 20-1000 MeV/c2 and coupling to electric charge ϵ2 = α'/α in the range 10-5 to 10-10. HPS will look for the e+e- decay channel of heavy photons radiated by electron Bremsstrahlung, employing both invariant mass search and detached vertexing techniques. The experiment employs a compact forward spectrometer comprising silicon microstrip detectors for vertexing and tracking and an electromagnetic calorimeter for particle identification and triggering.

  7. Emissions from In-Use NG, Propane, and Diesel Fueled Heavy Duty...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    In-Use NG, Propane, and Diesel Fueled Heavy Duty Vehicles Emissions from In-Use NG, Propane, and Diesel Fueled Heavy Duty Vehicles Emissions tests of in-use heavy-duty vehicles ...

  8. Calculation of cross sections for binary reactions between heavy ion projectiles and heavy actinide targets

    SciTech Connect (OSTI)

    Hoffman, D.C.; Hoffman, M.M.

    1990-11-01

    The computer program, described in this report, is identified as PWAVED5. It was developed to calculate cross sections for nucleon transfer reactions in low energy heavy ion bombardments. The objective was to calculate cross sections that agree with experimental results for ions of different charge and mass and to develop a predictive capability. It was undertaken because previous heavy ion calculations, for which programs were readily available, appeared to focus primarily on reactions resulting in compound nucleus formation and were not particularly applicable to calculations of binary reaction cross sections at low interaction energies. There are to principal areas in which this computation differs from several other partial wave calculations of heavy-ion reaction cross sections. First, this program is designed specifically to calculate cross sections for nucleon exchange interactions and to exclude interactions that are expected to result in fusion of the two nuclei. A second major difference in this calculation is the use of a statistical distribution to assign the total interaction cross section to individual final mass states.

  9. Electrochemical nitridation of metal surfaces

    DOE Patents [OSTI]

    Wang, Heli; Turner, John A.

    2015-06-30

    Electrochemical nitridation of metals and the produced metals are disclosed. An exemplary method of electrochemical nitridation of metals comprises providing an electrochemical solution at low temperature. The method also comprises providing a three-electrode potentiostat system. The method also comprises stabilizing the three-electrode potentiostat system at open circuit potential. The method also comprises applying a cathodic potential to a metal.

  10. Thermally tolerant multilayer metal membrane

    DOE Patents [OSTI]

    Dye, Robert C. (Los Alamos, NM); Snow, Ronny C. (Los Alamos, NM)

    2001-01-01

    A composite metal membrane including a first metal layer of a Group IVB or Group VB metal sandwiched between two layers of a Group VIIIB metal selected from the group consisting of palladium, platinum, nickel, rhodium, iridium, cobalt, and alloys thereof, and a non-continuous layer of a metal chalcogenide upon one layer of the Group VIIIB metal is disclosed together with a process for the recovery of hydrogen from a gaseous mixture using such a composite membrane and a process for forming such a composite metal membrane.

  11. Alternative Fuels Data Center: Heavy-Duty Truck Idle Reduction Technologies

    Alternative Fuels and Advanced Vehicles Data Center [Office of Energy Efficiency and Renewable Energy (EERE)]

    Heavy-Duty Truck Idle Reduction Technologies to someone by E-mail Share Alternative Fuels Data Center: Heavy-Duty Truck Idle Reduction Technologies on Facebook Tweet about Alternative Fuels Data Center: Heavy-Duty Truck Idle Reduction Technologies on Twitter Bookmark Alternative Fuels Data Center: Heavy-Duty Truck Idle Reduction Technologies on Google Bookmark Alternative Fuels Data Center: Heavy-Duty Truck Idle Reduction Technologies on Delicious Rank Alternative Fuels Data Center: Heavy-Duty

  12. Method for forming metal contacts

    DOE Patents [OSTI]

    Reddington, Erik; Sutter, Thomas C; Bu, Lujia; Cannon, Alexandra; Habas, Susan E; Curtis, Calvin J; Miedaner, Alexander; Ginley, David S; Van Hest, Marinus Franciscus Antonius Maria

    2013-09-17

    Methods of forming metal contacts with metal inks in the manufacture of photovoltaic devices are disclosed. The metal inks are selectively deposited on semiconductor coatings by inkjet and aerosol apparatus. The composite is heated to selective temperatures where the metal inks burn through the coating to form an electrical contact with the semiconductor. Metal layers are then deposited on the electrical contacts by light induced or light assisted plating.

  13. Liquid metal thermal electric converter

    DOE Patents [OSTI]

    Abbin, Joseph P.; Andraka, Charles E.; Lukens, Laurance L.; Moreno, James B.

    1989-01-01

    A liquid metal thermal electric converter which converts heat energy to electrical energy. The design of the liquid metal thermal electric converter incorporates a unique configuration which directs the metal fluid pressure to the outside of the tube which results in the structural loads in the tube to be compressive. A liquid metal thermal electric converter refluxing boiler with series connection of tubes and a multiple cell liquid metal thermal electric converter are also provided.

  14. Damage-tolerant nanotwinned metals with nanovoids under radiation environments

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chen, Y.; Yu, K. Y.; Liu, Y.; Shao, S.; Wang, H.; Kirk, M. A.; Wang, J.; Zhang, X.

    2015-04-24

    Material performance in extreme radiation environments is central to the design of future nuclear reactors. Radiation induces significant damage in the form of dislocation loops and voids in irradiated materials, and continuous radiation often leads to void growth and subsequent void swelling in metals with low stacking fault energy. Here we show that by using in situ heavy ion irradiation in a transmission electron microscope, pre-introduced nanovoids in nanotwinned Cu efficiently absorb radiation-induced defects accompanied by gradual elimination of nanovoids, enhancing radiation tolerance of Cu. In situ studies and atomistic simulations reveal that such remarkable self-healing capability stems from highmore » density of coherent and incoherent twin boundaries that rapidly capture and transport point defects and dislocation loops to nanovoids, which act as storage bins for interstitial loops. This study describes a counterintuitive yet significant concept: deliberate introduction of nanovoids in conjunction with nanotwins enables unprecedented damage tolerance in metallic materials.« less

  15. Annular seed-blanket thorium fuel core concepts for heavy water...

    Office of Scientific and Technical Information (OSTI)

    core concepts for heavy water moderated reactors Citation Details In-Document Search Title: Annular seed-blanket thorium fuel core concepts for heavy water moderated reactors New ...

  16. Doubly heavy baryons and quark-diquark symmetry in quenched and...

    Office of Scientific and Technical Information (OSTI)

    A quark-diquark symmetry prediction for the hyperfine splittings of heavy mesons and doubly heavy baryons is rather insensitive to chiral corrections in both quenched and partially ...

  17. Fuel Effects on Advanced Combustion: Heavy-Duty Optical-Engine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Combustion: Heavy-Duty Optical-Engine Research Fuel Effects on Advanced Combustion: Heavy-Duty Optical-Engine Research 2009 DOE Hydrogen Program and Vehicle Technologies ...

  18. Variable Charge Motion for 2007-2010 Heavy Duty Diesel Engines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Charge Motion for 2007-2010 Heavy Duty Diesel Engines Variable Charge Motion for 2007-2010 Heavy Duty Diesel Engines 2003 DEER Conference Presentation: AVL Powertrain Engineering ...

  19. Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions Control Plasma-Activated Lean NOx Catalysis for Heavy-Duty Diesel Emissions Control PDF icon ...

  20. Alkali metal ionization detector

    DOE Patents [OSTI]

    Bauerle, James E.; Reed, William H.; Berkey, Edgar

    1978-01-01

    Variations in the conventional filament and collector electrodes of an alkali metal ionization detector, including the substitution of helical electrode configurations for either the conventional wire filament or flat plate collector; or, the substitution of a plurality of discrete filament electrodes providing an in situ capability for transferring from an operationally defective filament electrode to a previously unused filament electrode without removing the alkali metal ionization detector from the monitored environment. In particular, the helical collector arrangement which is coaxially disposed about the filament electrode, i.e. the thermal ionizer, provides an improved collection of positive ions developed by the filament electrode. The helical filament design, on the other hand, provides the advantage of an increased surface area for ionization of alkali metal-bearing species in a monitored gas environment as well as providing a relatively strong electric field for collecting the ions at the collector electrode about which the helical filament electrode is coaxially positioned. Alternatively, both the filament and collector electrodes can be helical. Furthermore, the operation of the conventional alkali metal ionization detector as a leak detector can be simplified as to cost and complexity, by operating the detector at a reduced collector potential while maintaining the sensitivity of the alkali metal ionization detector adequate for the relatively low concentration of alkali vapor and aerosol typically encountered in leak detection applications.

  1. ROSE{reg_sign} - A flexible process for upgrading heavy crude, atmospheric residue, or vaccum residue

    SciTech Connect (OSTI)

    Lynch, K.Z.; Hood, H.L.; Gomez, O.

    1995-12-31

    The ROSE{reg_sign} Pilot Plant was used to evaluate various fractions of Boscan and Zuata heavy crude oils. The results demonstrated the ability of the ROSE process to remove asphaltene fractions using n-pentane, n-butane, or propane as the solvent while leaving behind an oil that has been greatly reduced in its metal, nitrogen, sulfur, and Conradson carbon contents. The recovered oil could then be used as feedstock to a conventional hydrotreater/FCC process combination. The flexibility of the process is evidenced by its ability to process various feeds. Because of this flexibility, the opportunity exists to use the ROSE process at a wellhead location to reduce the diluent requirements for making a suitable pipeline feed. This technology is also able to process changing feeds when upstream units in a refinery are down during major turnarounds, for example, or when there are problems with a vacuum tower or downstream unit.

  2. Development of all-ceramic glow plugs for heavy-duty engines: Phase 2

    SciTech Connect (OSTI)

    Johar, S.; Das Gupta, S.

    1997-12-31

    Details the development work performed in phase 2 of a project to develop all-ceramic glow plugs for heavy-duty diesel engines. All-ceramic glow plugs, compared to traditional metallic plugs, offer a number of advantages including high corrosion resistance, operation at higher temperatures allowing for quicker start and improved engine performance, low power use, high dimensional stability, and longer service life. Work in phase 2 focused on increasing the operational voltage ratings of the proof-of-concept plugs developed in phase 1 in order to meet all commercial expectations in terms of performance, reliability, durability, and economic manufacture. The work involved optimization of the material composition to meet design specifications, development of a manufacturing process, fabrication of plugs, and bench and engine tests. Results compare the all-ceramic plugs to conventional plugs.

  3. METAL RESISTIVITY MEASURING DEVICE

    DOE Patents [OSTI]

    Renken, J. Jr.; Myers, R.G.

    1960-12-20

    An eddy current device is offered for detecting discontinuities in metal samples. Alternate short and long duration pulses are inductively applied to a metal sample via the outer coil of a probe. The long pulses give a resultant signal from the metal sample responsive to probe-tosample spacing and discontinuities within the sample and the shont pulses give a resultant signal responsive only to probe -to-sample spacing. The inner coil of the probe detects the two resultant signals and transmits them to a separation network where the two signals are separated. The two separated signals are then transmitted to a compensation network where the detected signals due to the short pulses are used to compensate for variations due to probe-to-sample spacing contained in the detected signals from the long pulses. Thus, a resultant signal is obtained responsive to discontinuities within the sample and independent of probe-to- sample spacing.

  4. Hydropyrolysis process for upgrading heavy oils and solids into light liquid products

    SciTech Connect (OSTI)

    Oblad, A.G.; Ramakrishnan, R.; Shabtai, J.

    1981-11-03

    A hydropyrolysis process is disclosed for upgrading heavy, high molecular weight feedstocks such as coal-derived liquids, petroleum crudes, tar sand bitumens, shale oils, bottom residues from process streams, and the like, to lighter, lower molecular weight liquid products. The process includes subjecting the feedstocks to pyrolysis in the presence of hydrogen under carefully controlled conditions of temperature and pressure. The process can be defined as hydrogen-modified, thermal cracking in the specific temperature range of 450* C. To 650* C. And in the hydrogen pressure range of about 120 psi to 2250 psi. The amount of hydrogen present can be varied according to the type of feedstock and the liquid product desired. Although the hydrogen is not consumed in large amounts, it does participate in and modifies the process, and thereby provides a means of controlling the process as to the molecular weight range and structural type distribution of the liquid products. The presence of hydrogen also inhibits coke formation. The process also eliminates the requirement for a catalyst so that the reaction will proceed in the presence of heavy metal contaminants in the feedstock which contaminants would otherwise poison any catalyst.

  5. Evaluation of solvent-based in situ processes for upgrading and recovery of heavy oil bitumen

    SciTech Connect (OSTI)

    Duerksen, J.H.; Eloyan, A.

    1995-12-31

    Solvent-based in situ recovery processes have been proposed as lower cost alternatives to thermal processes for recovery of heavy oil and bitumen. Advantages of solvent based processes are: reduced steam requirements, reduced water treating, and in situ upgrading of the produced oil. Lab results and process calculations show that low-pressure, low-energy solvent-based in situ processes have considerable technical and economic potential for upgrading and recovery of bitumen and heavy oil. In a lab flow test using Athabasca tar sand and propane as solvent, 50 percent of the bitumen was recovered as upgraded oil. Relative to the raw bitumen, API gravity increased by about 10{degrees}API, viscosity was reduced 30-fold, sulfur content was reduced about 50 percent, and metals content was also substantially reduced. Process uncertainties that will have a major impact on economics are: (1) oil production rate, (2) oil recovery, (3) extent of in situ upgrading, and (4) solvent losses. Additional lab development and field testing are required to reduce these process uncertainties and to predict commercial-scale economics.

  6. Method for locating metallic nitride inclusions in metallic alloy ingots

    DOE Patents [OSTI]

    White, Jack C.; Traut, Davis E.; Oden, Laurance L.; Schmitt, Roman A.

    1992-01-01

    A method of determining the location and history of metallic nitride and/or oxynitride inclusions in metallic melts. The method includes the steps of labeling metallic nitride and/or oxynitride inclusions by making a coreduced metallic-hafnium sponge from a mixture of hafnium chloride and the chloride of a metal, reducing the mixed chlorides with magnesium, nitriding the hafnium-labeled metallic-hafnium sponge, and seeding the sponge to be melted with hafnium-labeled nitride inclusions. The ingots are neutron activated and the hafnium is located by radiometric means. Hafnium possesses exactly the proper metallurgical and radiochemical properties for this use.

  7. Some engineering properties of heavy concrete added silica fume

    SciTech Connect (OSTI)

    Akka?, Ay?e; Ba?yi?it, Celalettin; Esen, Serap

    2013-12-16

    Many different types of building materials have been used in building construction for years. Heavy concretes can be used as a building material for critical building as it can contain a mixture of many heavy elements. The barite itself for radiation shielding can be used and also in concrete to produce the workable concrete with a maximum density and adequate structural strength. In this study, some engineering properties like compressive strength, elasticity modules and flexure strength of heavy concretes added Silica fume have been investigated.

  8. Heavy oil development in Canada - The need for upgrading

    SciTech Connect (OSTI)

    Quinn, P.C.

    1987-01-01

    The author first reviews Canada's petroleum reserves, then summarizes the problem facing Canada regarding dwindling supplies of conventional light and medium crude oils and briefly describes Canada's refining capability. With that background, he attempts to analyze the problems that face heavy oil producers in attempting to market their product and propose a potential solution to these problems as illustrated by Husky Oil's approach - the construction of a heavy oil upgrader. He closes by sharing his views on the future of heavy oil development and the policy issues facing our governments.

  9. Methods for natural gas and heavy hydrocarbon co-conversion

    DOE Patents [OSTI]

    Kong, Peter C.; Nelson, Lee O.; Detering, Brent A.

    2009-02-24

    A reactor for reactive co-conversion of heavy hydrocarbons and hydrocarbon gases and includes a dielectric barrier discharge plasma cell having a pair of electrodes separated by a dielectric material and passageway therebetween. An inlet is provided for feeding heavy hydrocarbons and other reactive materials to the passageway of the discharge plasma cell, and an outlet is provided for discharging reaction products from the reactor. A packed bed catalyst may optionally be used in the reactor to increase efficiency of conversion. The reactor can be modified to allow use of a variety of light sources for providing ultraviolet light within the discharge plasma cell. Methods for upgrading heavy hydrocarbons are also disclosed.

  10. Hard metal composition

    DOE Patents [OSTI]

    Sheinberg, Haskell (Los Alamos, NM)

    1986-01-01

    A composition of matter having a Rockwell A hardness of at least 85 is formed from a precursor mixture comprising between 3 and 10 weight percent boron carbide and the remainder a metal mixture comprising from 70 to 90 percent tungsten or molybdenum, with the remainder of the metal mixture comprising nickel and iron or a mixture thereof. The composition has a relatively low density of between 7 to 14 g/cc. The precursor is preferably hot pressed to yield a composition having greater than 100% of theoretical density.

  11. Hard metal composition

    DOE Patents [OSTI]

    Sheinberg, H.

    1983-07-26

    A composition of matter having a Rockwell A hardness of at least 85 is formed from a precursor mixture comprising between 3 and 10 wt % boron carbide and the remainder a metal mixture comprising from 70 to 90% tungsten or molybdenum, with the remainder of the metal mixture comprising nickel and iron or a mixture thereof. The composition has a relatively low density of between 7 and 14 g/cc. The precursor is preferably hot pressed to yield a composition having greater than 100% of theoretical density.

  12. Liquid metal pump

    DOE Patents [OSTI]

    Pennell, William E.

    1982-01-01

    The liquid metal pump comprises floating seal rings and attachment of the pump diffuser to the pump bowl for isolating structural deflections from the pump shaft bearings. The seal rings also eliminate precision machining on large assemblies by eliminating the need for a close tolerance fit between the mounting surfaces of the pump and the seals. The liquid metal pump also comprises a shaft support structure that is isolated from the pump housing for better preservation of alignment of shaft bearings. The shaft support structure also allows for complete removal of pump internals for inspection and repair.

  13. Metal alloy identifier

    DOE Patents [OSTI]

    Riley, William D. (Avondale, MD); Brown, Jr., Robert D. (Avondale, MD)

    1987-01-01

    To identify the composition of a metal alloy, sparks generated from the alloy are optically observed and spectrographically analyzed. The spectrographic data, in the form of a full-spectrum plot of intensity versus wavelength, provide the "signature" of the metal alloy. This signature can be compared with similar plots for alloys of known composition to establish the unknown composition by a positive match with a known alloy. An alternative method is to form intensity ratios for pairs of predetermined wavelengths within the observed spectrum and to then compare the values of such ratios with similar values for known alloy compositions, thereby to positively identify the unknown alloy composition.

  14. Metallic carbon materials

    DOE Patents [OSTI]

    Cohen, Marvin Lou; Crespi, Vincent Henry; Louie, Steven Gwon Sheng; Zettl, Alexander Karlwalter

    1999-01-01

    Novel metallic forms of planar carbon are described, as well as methods of designing and making them. Nonhexagonal arrangements of carbon are introduced into a graphite carbon network essentially without destroying the planar structure. Specifically a form of carbon comprising primarily pentagons and heptagons, and having a large density of states at the Fermi level is described. Other arrangements of pentagons and heptagons that include some hexagons, and structures incorporating squares and octagons are additionally disclosed. Reducing the bond angle symmetry associated with a hexagonal arrangement of carbons increases the likelihood that the carbon material will have a metallic electron structure.

  15. Exotic decays of heavy B quarks

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Fox, Patrick J.; Tucker-Smith, David

    2016-01-08

    Heavy vector-like quarks of charge –1/3, B, have been searched for at the LHC through the decays B → bZ, bh, tW. In models where the B quark also carries charge under a new gauge group, new decay channels may dominate. We focus on the case where the B is charged under a U(1)' and describe simple models where the dominant decay mode is B → bZ' → b(bb¯¯). With the inclusion of dark matter such models can explain the excess of gamma rays from the Galactic center. We develop a search strategy for this decay chain and estimate thatmore » with integrated luminosity of 300 fb–1 the LHC will have the potential to discover both the B and the Z' for B quarks with mass below ~ 1.6 TeV, for a broad range of Z' masses. Furthermore, a high-luminosity run can extend this reach to 2 TeV.« less

  16. Inertially confined fusion using heavy ion drivers

    SciTech Connect (OSTI)

    Herrmannsfeldt, W.B.; Bangerter, R.O.; Bock, R.; Hogan, W.J.; Lindl, J.D.

    1991-10-01

    The various technical issues of HIF will be briefly reviewed in this paper. It will be seen that there are numerous areas in common in all the approaches to HIF. In the recent International Symposium on Heavy Ion Inertial Fusion, the attendees met in specialized workshop sessions to consider the needs for research in each area. Each of the workshop groups considered the key questions of this report: (1) Is this an appropriate time for international collaboration in HIF? (2) Which problems are most appropriate for such collaboration? (3) Can the sharing of target design information be set aside until other driver and systems issues are better resolved, by which time it might be supposed that there could be a relaxation of classification of target issues? (4) What form(s) of collaboration are most appropriate, e.g., bilateral or multilateral? (5) Can international collaboration be sensibly attempted without significant increases in funding for HIF? The authors of this report share the conviction that collaboration on a broad scale is mandatory for HIF to have the resources, both financial and personnel, to progress to a demonstration experiment. Ultimately it may be possible for a single driver with the energy, power, focusibility, and pulse shape to satisfy the needs of the international community for target physics research. Such a facility could service multiple experimental chambers with a variety of beam geometries and target concepts.

  17. Inertially confined fusion using heavy ion drivers

    SciTech Connect (OSTI)

    Herrmannsfeldt, W.B. ); Bangerter, R.O. ); Bock, R. ); Hogan, W.J.; Lindl, J.D. )

    1991-10-01

    The various technical issues of HIF will be briefly reviewed in this paper. It will be seen that there are numerous areas in common in all the approaches to HIF. In the recent International Symposium on Heavy Ion Inertial Fusion, the attendees met in specialized workshop sessions to consider the needs for research in each area. Each of the workshop groups considered the key questions of this report: (1) Is this an appropriate time for international collaboration in HIF (2) Which problems are most appropriate for such collaboration (3) Can the sharing of target design information be set aside until other driver and systems issues are better resolved, by which time it might be supposed that there could be a relaxation of classification of target issues (4) What form(s) of collaboration are most appropriate, e.g., bilateral or multilateral (5) Can international collaboration be sensibly attempted without significant increases in funding for HIF The authors of this report share the conviction that collaboration on a broad scale is mandatory for HIF to have the resources, both financial and personnel, to progress to a demonstration experiment. Ultimately it may be possible for a single driver with the energy, power, focusibility, and pulse shape to satisfy the needs of the international community for target physics research. Such a facility could service multiple experimental chambers with a variety of beam geometries and target concepts.

  18. Shell effects in fusion of heavy nuclei

    SciTech Connect (OSTI)

    Moeller, P.; Nix, J.R.

    1997-12-31

    The spontaneous-fission properties of Fm isotopes undergo dramatic changes between {sup 256}Fm and {sup 258} Fm. The fission fragments of the former isotope are mass asymmetric with kinetic energies of about 200 MeV, whereas the fission fragments of the latter isotope are symmetric with kinetic energies of about 235 MeV. This rapid change occurs because the division into nearly doubly magic fragments near {sup 132}Sn becomes possible and opens up new valleys in the fission potential-energy surface. In the cold-fusion reactions leading to the heaviest elements, the nearly doubly magic targets and/or projectiles may give rise to important features associated with this magicity. Cold fusion is thought to favor heavy-element formation because it leads to low excitation energies of the compound nuclei. We investigate how near-magic targets and projectiles may lead to persistent survivability of the shells in the fusion valley as the ions merge, in addition to their effect on the compound-nucleus excitation energy.

  19. Probing the Kondo lattice model with alkaline-earth-metal atoms

    SciTech Connect (OSTI)

    Foss-Feig, Michael; Hermele, Michael; Rey, Ana Maria

    2010-05-15

    We study transport properties of alkaline-earth-metal atoms governed by the Kondo lattice Hamiltonian plus a harmonic confining potential, and suggest simple dynamical probes of several different regimes of the phase diagram that can be implemented with current experimental techniques. In particular, we show how Kondo physics at strong coupling, at low density, and in the heavy fermion phase is manifest in the dipole oscillations of the conduction band upon displacement of the trap center.

  20. Wick for metal vapor laser

    DOE Patents [OSTI]

    Duncan, David B. (Livermore, CA)

    1992-01-01

    An improved wick for a metal vapor laser is made of a refractory metal cylinder, preferably molybdenum or tungsten for a copper laser, which provides the wicking surface. Alternately, the inside surface of the ceramic laser tube can be metalized to form the wicking surface. Capillary action is enhanced by using wire screen, porous foam metal, or grooved surfaces. Graphite or carbon, in the form of chunks, strips, fibers or particles, is placed on the inside surface of the wick to reduce water, reduce metal oxides and form metal carbides.

  1. Metal Insertion in a Microporous Metal-Organic Framework Lined...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metal Insertion in a Microporous Metal-Organic Framework Lined with 2,2 '-Bipyridine Previous Next List E. D. Bloch, D. Britt, C. Lee, C. J. Doonan, F. J. Uribe-Romo, H. Furukawa,...

  2. STRIPPING METAL COATINGS

    DOE Patents [OSTI]

    Siefen, H.T.; Campbell, J.M.

    1959-02-01

    A method is described for removing aluminumuranium-silicon alloy bonded to metallic U comprising subjecting the Al-U -Si alloy to treatment with hot concentrated HNO/sun 3/ to partially dissolve and embrittle the alloy and shot- blasting the embrittled alloy to loosen it from the U.

  3. Metal working lubricant compositions

    SciTech Connect (OSTI)

    Andress, H.J.; Davis, R.H.; Schick, J.W.

    1981-08-11

    A lubricant concentrate for use in metal processing comprises a sulfur compound such as a sulfurized olefin or sulfurized mineral oil and an ester prepared from a fatty acid having 12 to 40 carbon atoms or the dimer thereof or a polyalkenylsuccinic acid or anhydride and a hydroxyl-containing amine.

  4. Serpentine metal gasket

    DOE Patents [OSTI]

    Rothgeb, Timothy Moore; Reece, Charles Edwin

    2009-06-02

    A metallic seal or gasket for use in the joining of cryogenic fluid conduits, the seal or gasket having a generally planar and serpentine periphery defining a central aperture. According to a preferred embodiment, the periphery has at least two opposing elongated serpentine sides and two opposing arcuate ends joining the opposing elongated serpentine sides and is of a hexagonal cross-section.

  5. Metal halogen electrochemical cell

    DOE Patents [OSTI]

    Bellows, Richard J. (Hampton, NJ); Kantner, Edward (E. Brunswick, NJ)

    1988-08-23

    It has now been discovered that reduction in the coulombic efficiency of metal halogen cells can be minimized if the microporous separator employed in such cells is selected from one which is preferably wet by the aqueous electrolyte and is not wet substantially by the cathodic halogen.

  6. Ductile transplutonium metal alloys

    DOE Patents [OSTI]

    Conner, W.V.

    1981-10-09

    Alloys of Ce with transplutonium metals such as Am, Cm, Bk and Cf have properties making them highly suitable as souces of the transplutonium element, e.g., for use in radiation detector technology or as radiation sources. The alloys are ductile, homogeneous, easy to prepare and have a fairly high density.

  7. Ductile transplutonium metal alloys

    DOE Patents [OSTI]

    Conner, William V.

    1983-01-01

    Alloys of Ce with transplutonium metals such as Am, Cm, Bk and Cf have properties making them highly suitable as sources of the transplutonium element, e.g., for use in radiation detector technology or as radiation sources. The alloys are ductile, homogeneous, easy to prepare and have a fairly high density.

  8. EXPERIMENTAL AND THEORETICAL DETERMINATION OF HEAVY OIL VISCOSITY...

    Office of Scientific and Technical Information (OSTI)

    EXPERIMENTAL AND THEORETICAL DETERMINATION OF HEAVY OIL VISCOSITY UNDER RESERVOIR CONDITIONS FINAL PROGRESS REPORT PERIOD: OCT 1999-MAY 2003 CONTRACT NUMBER: DE-FG26-99FT40615 ...

  9. 05663_AlaskaHeavyOil | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    DE-NT0005663 Goal The goal of this project is to improve recovery of Alaskan North Slope (ANS) heavy oil resources in the Ugnu formation by improving our understanding of the ...

  10. Actinide targets for the synthesis of super-heavy elements

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Roberto, J.; Alexander, Charles W.; Boll, Rose Ann; Ezold, Julie G.; Felker, Leslie Kevin; Rykaczewski, Krzysztof Piotr; Hogle, Susan L.

    2015-06-18

    Since 2000, six new super-heavy elements with atomic numbers 113 through 118 have been synthesized in hot fusion reactions of 48Ca beams on actinide targets. These target materials, including 242Pu, 244Pu, 243Am, 245Cm, 248Cm, 249Cf, and 249Bk, are available in very limited quantities and require specialized production and processing facilities resident in only a few research centers worldwide. This report describes the production and chemical processing of heavy actinide materials for super-heavy element research, current availabilities of these materials, and related target fabrication techniques. The impact of actinide materials in super-heavy element discovery is reviewed, and strategies for enhancing themore » production of rare actinides including 249Bk, 251Cf, and 254Es are described.« less

  11. Medium- and Heavy-Duty Electric Drive Vehicle Simulation and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Medium- and Heavy-Duty Electric Drive Vehicle Simulation and Analysis DOE VTP Annual Merit Review PI: Robb A. Barnitt Organization: NREL May 10, 2011 Project ID: VSS043 This ...

  12. Heavy and Thermal Oil Recovery Production Mechanisms, SUPRI TR-127

    SciTech Connect (OSTI)

    Kovscek, Anthony R.; Brigham, William E.; Castanier, Louis M.

    2001-09-07

    The program spans a spectrum of topics and is divided into five categories: (i) multiphase flow and rock properties, (ii) hot fluid injection, (iii) primary heavy-oil production, (iv) reservoir definition, and (v) in-situ combustion.

  13. Heavy Duty HCCI Development Activities - DOE High Efficiency...

    Broader source: Energy.gov (indexed) [DOE]

    Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck ... Compression Ignition (HCCI) Engines Heavy-Duty Low Temperature Combustion Development ...

  14. NAFTA Heavy Duty Engine and Aftertreatment Technology: Status...

    Broader source: Energy.gov (indexed) [DOE]

    Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006deerlysinger.pdf More Documents & Publications Heavy-Duty Engine ...

  15. The Road to Improved Heavy Duty Fuel Economy

    Broader source: Energy.gov [DOE]

    Heavy duty diesel engine fuel economy is improved by lowering the viscosity of engine lubricant, especially when engine speed is increased or load is decreased, as in long distance on-highway driving

  16. Heavy vehicle systems optimization merit review and peer evaluation

    SciTech Connect (OSTI)

    None, None

    2009-01-18

    This report is a summary and analysis of comments from the Review Panel at the FY 2006 DOE Heavy Vehicle Systems Optimization Merit Review and Peer Evaluation, held April 18-20, 2006.

  17. A High Temperature Direct Vehicle Exhaust Flowmeter for Heavy...

    Broader source: Energy.gov (indexed) [DOE]

    Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) ... of Real-World Emissions from Heavy-Duty Diesel Vehicles: The State-of-the-Art Emerging ...

  18. New Demands on Heavy Duty Engine Management Systems

    Broader source: Energy.gov [DOE]

    The purpose of this research was to investigate the potential of emissions-based process control to meet future heavy-duty emissions legislation by identifying suitable actuated variables and developing hardware and related controllers.

  19. Reactive plasma upgrade of squalane - a heavy oil simulant

    SciTech Connect (OSTI)

    Kong, P.C.; Watkins, A.D.; Detering, B.A.; Thomas, C.P.

    1995-10-01

    U.S. light crude oil production has steadily declined over the last two decades. However, huge known heavy oil deposits in the North American continent remain largely untapped. In the past 10 years, the API gravity of crude oils has been decreasing by about 0.17% per year, and the sulfur content has been increasing by about 0.027% per year. As the API gravity of crude oil decreases, there will be an urgent need for economically viable new technologies to upgrade the heavy oil to a high API gravity feed stock for the refineries. The Idaho National Engineering Laboratory is investigating an innovative plasma process to upgrade heavy oil and refinery residuum. This paper will present some of the results and the implications of this technology for heavy oil upgrade and conversion.

  20. Reactive plasma upgrade of squalane - a heavy oil simulant

    SciTech Connect (OSTI)

    Kong, P.C.; Watkins, A.D.; Detering, B.A.

    1995-07-01

    U.S. light crude oil production has steadily declined over the last two decades. However, huge known heavy oil deposits in the North American continent remain largely untapped. In the past 10 years, the API gravity of crude oils has been decreasing by about 0.17% per year, and the sulfur content has been increasing by about 0.027% per year. As the API gravity of crude oil decreases, there will be an urgent need for economically viable new technologies to ungrade the heavy oil to a high API gravity feed stock for the refineries. The Idaho National Engineering Laboratory is investigating an innovative plasma process to upgrade heavy oil and refinery residuum. This paper will present some of the results and the implications of this technology for heavy oil upgrade and conversion.

  1. Heavy oil and tar sands recovery and upgrading. International technology

    SciTech Connect (OSTI)

    Schumacher, M.M.

    1982-01-01

    This work provides an in-depth assessment of international technology for the recovery and upgrading of heavy crude oil and tar sands. The technologies included are currently in use, under development, or planned; emphasis is placed on post-1978 activities. The heavy oil technologies and processes considered include methods relating to the exploitation of heavy oil reservoirs, such as production from underground workings, all types of improved or enhanced recovery, subsurface extraction, and well rate stimulation. The tar sands section includes sizing the resource base and reviewing and evaluating past, present, and planned research and field developments on processes for mining, producing, extracting, and upgrading very heavy oils recovered from tar sands, e.g., bitumen recovery from tar sands where primary production was impossible because of the oil's high viscosity. 616 references.

  2. Exclusive heavy quarkonium +{gamma} production from e{sup +}e...

    Office of Scientific and Technical Information (OSTI)

    for the differential and total cross sections are obtained at leading order in the strong coupling and in the relative velocity of the heavy quark in the quarkonium rest frame. ...

  3. Heavy surface state in a possible topological Kondo insulator...

    Office of Scientific and Technical Information (OSTI)

    transport on the (011) plane of SmB 6 Citation Details In-Document Search Title: Heavy surface state in a possible topological Kondo insulator: Magnetothermoelectric transport on ...

  4. Fact #721: April 2, 2012 Heavy Trucks Move Freight Efficiently

    Broader source: Energy.gov [DOE]

    Though discussions of vehicle efficiency are often centered on a measurement of miles per gallon, it is also important to consider how efficiently a vehicle carries its payload. Although heavy...

  5. Dissociation of a heavy meson in the quark medium

    SciTech Connect (OSTI)

    Park, Chanyong

    2010-02-15

    We investigate the dissociation of a heavy meson in the medium composed of light quarks and gluons. In the quark-gluon plasma, the dissociation length of the heavy meson becomes short as the temperature or quark chemical potential increases. On the contrary, in the hadronic phase the dissociation length becomes large as the chemical potential increases, due to the different dissociation mechanism with one used in the quark-gluon plasma.

  6. Relativistic Heavy-Ion Collider (RHIC) physics overview

    SciTech Connect (OSTI)

    Ruan, L.J.; Ruan, L.; n /a

    2010-02-08

    The results from data taken during the last several years at the Relativistic Heavy-Ion Collider (RHIC) will be reviewed in the paper. Several selected topics that further our understanding of constituent quark scaling, jet quenching and color screening effect of heavy quarkonia in the hot dense medium will be presented. Detector upgrades will further probe the properties of Quark Gluon Plasma. Future measurements with upgraded detectors will be presented. The discovery perspectives from future measurements will also be discussed.

  7. Heavy Quarkonium: Progress, Puzzles, and Opportunities (Journal Article) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Journal Article: Heavy Quarkonium: Progress, Puzzles, and Opportunities Citation Details In-Document Search Title: Heavy Quarkonium: Progress, Puzzles, and Opportunities Authors: Brambilla, N. ; /Munich, Tech. U. ; Eidelman, S. ; /Novosibirsk, IYF /Novosibirsk State U. ; Heltsley, B.K. ; /Cornell U., Phys. Dept. ; Vogt, R. ; /LLNL, Livermore /UC, Davis ; Bodwin, G.T. ; /Argonne, HEP ; Eichten, E. ; /Fermilab ; Frawley, A.D. ; /Florida State U. ; Meyer, A.B. ; /DESY ;

  8. Hydrogen Production and Purification from Coal and Other Heavy Feedstocks

    Office of Scientific and Technical Information (OSTI)

    Year 6 - Activity 1.4 - Development of a National Center for Hydrogen Technology (Technical Report) | SciTech Connect Hydrogen Production and Purification from Coal and Other Heavy Feedstocks Year 6 - Activity 1.4 - Development of a National Center for Hydrogen Technology Citation Details In-Document Search Title: Hydrogen Production and Purification from Coal and Other Heavy Feedstocks Year 6 - Activity 1.4 - Development of a National Center for Hydrogen Technology Air Products and

  9. Hydrogen Production and Purification from Coal and Other Heavy Feedstocks

    Office of Scientific and Technical Information (OSTI)

    Year 6 - Activity 1.4 - Development of a National Center for Hydrogen Technology (Technical Report) | SciTech Connect Hydrogen Production and Purification from Coal and Other Heavy Feedstocks Year 6 - Activity 1.4 - Development of a National Center for Hydrogen Technology Citation Details In-Document Search Title: Hydrogen Production and Purification from Coal and Other Heavy Feedstocks Year 6 - Activity 1.4 - Development of a National Center for Hydrogen Technology × You are accessing a

  10. International safeguards recommendations for the Indian advanced heavy

    Office of Scientific and Technical Information (OSTI)

    water reactor (AHWR) (Conference) | SciTech Connect International safeguards recommendations for the Indian advanced heavy water reactor (AHWR) Citation Details In-Document Search Title: International safeguards recommendations for the Indian advanced heavy water reactor (AHWR) Authors: Murphy, Chantel L [1] ; Doyle, James E [1] ; Boyer, Brian D [1] ; Fane, Brian M [1] + Show Author Affiliations Los Alamos National Laboratory Publication Date: 2011-06-10 OSTI Identifier: 1072335 Report

  11. International safeguards recommendations for the Indian advanced heavy

    Office of Scientific and Technical Information (OSTI)

    water reactor (AHWR) (Conference) | SciTech Connect International safeguards recommendations for the Indian advanced heavy water reactor (AHWR) Citation Details In-Document Search Title: International safeguards recommendations for the Indian advanced heavy water reactor (AHWR) Authors: Murphy, Chantell L [1] ; Boyer, Brian D [1] ; Doyle, James E [1] ; Fane, Brian M [1] + Show Author Affiliations Los Alamos National Laboratory Publication Date: 2011-07-18 OSTI Identifier: 1083123 Report

  12. International safeguards recommendations for the Indian advanced heavy

    Office of Scientific and Technical Information (OSTI)

    water reactor (AHWR) (Conference) | SciTech Connect International safeguards recommendations for the Indian advanced heavy water reactor (AHWR) Citation Details In-Document Search Title: International safeguards recommendations for the Indian advanced heavy water reactor (AHWR) × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit

  13. International safeguards recommendations for the Indian advanced heavy

    Office of Scientific and Technical Information (OSTI)

    water reactor (AHWR) (Conference) | SciTech Connect International safeguards recommendations for the Indian advanced heavy water reactor (AHWR) Citation Details In-Document Search Title: International safeguards recommendations for the Indian advanced heavy water reactor (AHWR) × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit

  14. MARTINI event generator for heavy quarks: Initialization, parton evolution,

    Office of Scientific and Technical Information (OSTI)

    and hadronization (Journal Article) | DOE PAGES MARTINI event generator for heavy quarks: Initialization, parton evolution, and hadronization « Prev Next » Title: MARTINI event generator for heavy quarks: Initialization, parton evolution, and hadronization Authors: Young, Clint ; Schenke, Björn ; Jeon, Sangyong ; Gale, Charles Publication Date: 2012-09-10 OSTI Identifier: 1103304 Type: Publisher's Accepted Manuscript Journal Name: Physical Review C Additional Journal Information: Journal

  15. Viscous photons in relativistic heavy ion collisions (Journal Article) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect SciTech Connect Search Results Journal Article: Viscous photons in relativistic heavy ion collisions Citation Details In-Document Search Title: Viscous photons in relativistic heavy ion collisions Authors: Dion, Maxime ; Paquet, Jean-François ; Schenke, Björn ; Young, Clint ; Jeon, Sangyong ; Gale, Charles Publication Date: 2011-12-02 OSTI Identifier: 1098343 Type: Publisher's Accepted Manuscript Journal Name: Physical Review C Additional Journal Information: Journal

  16. The ethanol heavy-duty truck fleet demonstration project

    SciTech Connect (OSTI)

    1997-06-01

    This project was designed to test and demonstrate the use of a high- percentage ethanol-blended fuel in a fleet of heavy-duty, over-the- road trucks, paying particular attention to emissions, performance, and repair and maintenance costs. This project also represents the first public demonstration of the use of ethanol fuels as a viable alternative to conventional diesel fuel in heavy-duty engines.

  17. NREL: Transportation Research - Heavy-Duty Vehicle Thermal Management

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heavy-Duty Vehicle Thermal Management Infrared image of a semi cab and two people. NREL testing and modeling assess the energy saving impact of advanced climate control materials and equipment on heavy-duty vehicles. Photo by Dennis Schroeder, NREL Illustration of a truck with labeled energy-saving elements. NREL researchers assess the energy saving potential of films, paints, advanced insulation, micro-environmental design, and idle reduction technologies. Illustration by Ray David, NREL

  18. Quantum critical scaling and superconductivity in heavy electron materials

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Quantum critical scaling and superconductivity in heavy electron materials Citation Details In-Document Search This content will become publicly available on November 16, 2016 Title: Quantum critical scaling and superconductivity in heavy electron materials Authors: Yang, Yi-feng ; Pines, David ; Curro, N. J. Publication Date: 2015-11-17 OSTI Identifier: 1226180 Grant/Contract Number: de-na0001842-0 Type: Publisher's Accepted Manuscript Journal Name:

  19. Critical condition in gravitational shock wave collision and heavy ion

    Office of Scientific and Technical Information (OSTI)

    collisions (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: Critical condition in gravitational shock wave collision and heavy ion collisions Citation Details In-Document Search Title: Critical condition in gravitational shock wave collision and heavy ion collisions Authors: Lin, Shu ; Shuryak, Edward Publication Date: 2011-02-23 OSTI Identifier: 1099912 Type: Publisher's Accepted Manuscript Journal Name: Physical Review D Additional Journal Information:

  20. Establishment of the Heavy Isotopes Lead Materials Management Organization

    Office of Scientific and Technical Information (OSTI)

    (LMMO) (Conference) | SciTech Connect Establishment of the Heavy Isotopes Lead Materials Management Organization (LMMO) Citation Details In-Document Search Title: Establishment of the Heavy Isotopes Lead Materials Management Organization (LMMO) Authors: Patton, Bradley D [1] ; Robinson, Sharon M [1] ; Sherman, Steven R [1] + Show Author Affiliations ORNL [ORNL Publication Date: 2013-01-01 OSTI Identifier: 1110926 DOE Contract Number: DE-AC05-00OR22725 Resource Type: Conference Resource