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Note: This page contains sample records for the topic "heavy metal contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Heavy Metal Contamination in the Taimyr Peninsula, Siberian Arctic  

SciTech Connect (OSTI)

The Taimyr Peninsula is directly north of the world's largest heavy metal smelting complex (Norilsk, Russia). Despite this proximity, there has been little research to examine the extent of contamination of the Taimyr Peninsula. We analyzed heavy metal concentrations in lichen (Cetraria cucullata), moss (Hylocomium splendens), soils, lake sediment, freshwater fish (Salvelinus alpinus, Lota lota, and Coregonus spp.) and collared lemming (Dicrostonyx torquatus) from 13 sites between 30 and 300 km from Norilsk. Element concentrations were low in both C. cucullata and H. splendens, although concentrations of Al, Fe, Cu, Ni, and Pb were significantly higher than those in Arctic Alaska, probably due to natural differences in the geochemical environments. Inorganic surface soils had significantly higher concentrations of Cd, Zn, Pb, and Mg than inorganic soils at depth, although a lake sediment core from the eastern Taimyr Peninsula indicated no recent enrichment by atmospherically transported elements. Tissue concentrations of heavy metals in fish and lemming were not elevated relative to other Arctic sites. Our results show that the impact of the Norilsk smelting complex is primarily localized rather than regional, and does not extend northward beyond 100 km.

Allen-Gil, Susan M.; Ford, Jesse; Lasorsa, Brenda K.; Monetti, Matthew; Vlasova, Tamara; Landers, Dixon H.

2003-01-01T23:59:59.000Z

2

Heavy Metal Contaminated Sediments of Lower Passaic River, New Jersey USA Victor Onwueme1  

E-Print Network [OSTI]

Heavy Metal Contaminated Sediments of Lower Passaic River, New Jersey USA Victor Onwueme1 , Huan benchmarks and probable ecological stressors. Heavy metals remains chemicals of concern in the Passaic River of toxic chemicals throughout the river, whose concentrations greatly exceed the sediment quality

Brookhaven National Laboratory

3

Mercury and Other Heavy Metals Influence Bacterial Community Structure in Contaminated Streams  

E-Print Network [OSTI]

Mercury and Other Heavy Metals Influence Bacterial Community Structure in Contaminated Streams Research The influences of uranium (U), mercury (Hg) and methylmercury (MeHg) on the microbial community. #12;High concentrations of uranium, inorganic mercury, Hg(II) and methymercury (MeHg) have been

4

Plasma treatment of INEL soil contaminated with heavy metals  

SciTech Connect (OSTI)

INEL soil spiked with inorganic salts of chromium, lead, mercury, silver, and zinc was melted in a 150 kW plasma furnace to produce a glassy slag product. This glassy slag is an environmentally safe waste form. In order to reduce the melting temperature of the soil, sodium carbonate was added to half of the test batches. Random sample from each batch of glassy slag product were analyzed by an independent laboratory for total metals concentration and leachability of metals via the Environmental Protection Agency (EPA) toxicity characterization leaching procedure (RCLP) tests. These tests showed the residual metals were very tightly bound to the slag matrix and were within EPA TCLP limits under these test conditions. Additionally, scanning electron microscopy (SEM) and emissions dispersive spectroscopy (EDS) analysis of the vitrified soil also confirmed that the added metals present in the vitrified soil were totally contained in the crystalline phase as distinct oxide crystallites.

Detering, B.A.; Batdorf, J.A.

1992-01-01T23:59:59.000Z

5

Modeling of heavy metal transport in a contaminated soil  

SciTech Connect (OSTI)

Observed depth profiles in soils polluted by Zn and Cu that originate from a metal smelter are quantitatively interpreted by combining the production history of the smelter with established transport models. Using independent laboratory and field data, we were able to calculate the present depth profiles semiquantitatively by applying the pure convection model without parameter fitting. The agreement of the calculated depth profiles with the experimental data can be improved by including dispersion effects in the convection-dispersion model or the stochastic convection model. For the latter model, the depth profiles were calculated analytically. These models were used to calculate the expected depth profiles in the future and to judge possible remediation strategies. 48 refs., 12 figs., 1 tab.

Cernik, M.; Federer, P.; Borkovec, M.; Sticher, H. [Inst. of Terrestrial Ecology, Schlieren (Switzerland)

1994-11-01T23:59:59.000Z

6

Heavy-metal contamination on training ranges at the Grafenwoehr Training Area, Germany  

SciTech Connect (OSTI)

Large quantities of lead and other heavy metals are deposited in the environment of weapons ranges during training exercises. This study was conducted to determine the type, degree, and extent of heavy-metal contamination on selected handgun, rifle, and hand-grenade ranges at Grafenwoehr Training Area, Germany. Soil, vegetation, and surface-water samples were collected and analyzed using the inductively-coupled plasma atomic-emission spectroscopy (ICP-AES) method and the toxic characterization leaching procedure (TCLP). The ICP-AES results show that above-normal levels of lead and copper are in the surface soil at the handgun range, high concentrations of lead and copper are in the berm and soil surface at the rifle range, and elevated levels of cadmium and above-normal concentrations of arsenic, copper, and zinc are present in the surface soil at the hand-grenade range. The TCLP results show that surface soils can be considered hazardous waste because of lead content at the rifle range and because of cadmium concentration at the hand-grenade range. Vegetation at the handgun and rifle ranges has above-normal concentrations of lead. At the hand-grenade range, both vegetation and surface water have high levels of cadmium. A hand-held X-ray fluorescence (XRF) spectrum analyzer was used to measure lead concentrations in soils in a field test of the method. Comparison of XRF readings with ICP-AES results for lead indicate that the accuracy and precision of the hand-held XRF unit must improve before the unit can be used as more than a screening tool. Results of this study show that heavy-metal contamination at all three ranges is limited to the surface soil; heavy metals are not being leached into the soil profile or transported into adjacent areas.

Zellmer, S.D.; Schneider, J.F.

1993-05-01T23:59:59.000Z

7

Metagenomic Insights into Evolution of a Heavy Metal-Contaminated Groundwater Microbial Community  

E-Print Network [OSTI]

acetone). Finally, toxic heavy metal stress has resulted inby exporting toxic organics from the cell. (iv) Heavy metalheavy metal ions are relatively simple, typically involving: (a) conversion of the ion to a less toxic

Hemme, Christopher L.

2010-01-01T23:59:59.000Z

8

Temporal variation of heavy metal contamination in fish of the river lot in southern France  

E-Print Network [OSTI]

July 2009 Keywords: Heavy metals Historical pollution Freshwater fish Muscle Liver Quality index a b of intense heavy metal pollution and has been the focus of studies dating back to the 1970s (Audry et al Lot is derived from anthropogenic origin. As such, the main sources of heavy metal pollution

Grenouillet, Gael

9

High-Performance, Superparamagnetic, Nanoparticle-Based Heavy Metal Sorbents for Removal of Contaminants from Natural Waters  

SciTech Connect (OSTI)

We describe the synthesis and characterization of superparamagnetic iron oxide nanoparticle based heavy metal sorbents with various surface chemistries that demonstrate an excellent affinity for the separation of heavy metals in contaminated water systems (i.e. spiked Columbia river water). The magnetic nanoparticle sorbents are prepared from an easy to synthesize iron oxide precursor, followed by a simple, one-step ligand exchange technique to introduce the organic surface functionality of interest chosen to target either specific or broader classes of heavy metals. Functionalized superparamagnetic nanoparticles are excellent sorbent materials for the extraction of heavy metal contaminants from environmental and clinical samples since they are easily removed from the media once bound to the contaminant by simply applying a magnetic field. These engineered magnetic nanoparticle sorbents have an inherently high active surface area (often > 100 m2/g), allowing for increased binding capacity. To demonstrate the potential sorbent performance of each of the surface modified magnetic nanoparticles, river water was spiked with Hg, Pb, Cd, Ag, Co, Cu, and Tl and exposed to low concentrations of the functionalized nanoparticles. The samples were analyzed to determine the metal content before and after exposure to the magnetic nanoparticle sorbents. In almost all cases reported here the nanoparticles were found to be superior to commercially available sorbents binding a wide range of different heavy metals with extremely high affinity. Detailed characterization of the functionalized magnetic nanoparticle sorbents including FT-IR, BET surface analysis, TGA, XPS and VSM as well as the heavy metal removal experiments are presented.

Warner, Cynthia L.; Addleman, Shane; Cinson, Anthony D.; Droubay, Timothy C.; Engelhard, Mark H.; Nash, Michael A.; Yantasee, Wassana; Warner, Marvin G.

2010-06-01T23:59:59.000Z

10

Metagenomic Insights into Evolution of a Heavy Metal-Contaminated Groundwater Microbial Community  

SciTech Connect (OSTI)

Understanding adaptation of biological communities to environmental change is a central issue in ecology and evolution. Metagenomic analysis of a stressed groundwater microbial community reveals that prolonged exposure to high concentrations of heavy metals, nitric acid and organic solvents (~;;50 years) have resulted in a massive decrease in species and allelic diversity as well as a significant loss of metabolic diversity. Although the surviving microbial community possesses all metabolic pathways necessary for survival and growth in such an extreme environment, its structure is very simple, primarily composed of clonal denitrifying ?- and ?-proteobacterial populations. The resulting community is over-abundant in key genes conferring resistance to specific stresses including nitrate, heavy metals and acetone. Evolutionary analysis indicates that lateral gene transfer could be a key mechanism in rapidly responding and adapting to environmental contamination. The results presented in this study have important implications in understanding, assessing and predicting the impacts of human-induced activities on microbial communities ranging from human health to agriculture to environmental management, and their responses to environmental changes.

Hemme, Christopher L.; Deng, Ye; Gentry, Terry J.; Fields, Matthew W.; Wu, Liyou; Barua, Soumitra; Barry, Kerrie; Tringe, Susannah G.; Watson, David B.; He, Zhili; Hazen, Terry C.; Tiedje, James M.; Rubin, Edward M.; Zhou, Jizhong

2010-02-15T23:59:59.000Z

11

Metagenomic insights into evolution of a heavy metal-contaminated groundwater microbial community  

SciTech Connect (OSTI)

Understanding adaptation of biological communities to environmental change is a central issue in ecology and evolution. Metagenomic analysis of a stressed groundwater microbial community reveals that prolonged exposure to high concentrations of heavy metals, nitric acid and organic solvents (~50 years) has resulted in a massive decrease in species and allelic diversity as well as a significant loss of metabolic diversity. Although the surviving microbial community possesses all metabolic pathways necessary for survival and growth in such an extreme environment, its structure is very simple, primarily composed of clonal denitrifying - and -proteobacterial populations. The resulting community is overabundant in key genes conferring resistance to specific stresses including nitrate, heavy metals and acetone. Evolutionary analysis indicates that lateral gene transfer could have a key function in rapid response and adaptation to environmental contamination. The results presented in this study have important implications in understanding, assessing and predicting the impacts of human-induced activities on microbial communities ranging from human health to agriculture to environmental management, and their responses to environmental changes.

Hemme, Christopher [University of Oklahoma; Deng, Ye [University of Oklahoma; Gentry, Terry [Texas A& M University; Fields, Matthew Wayne [Miami University, Oxford, OH; Wu, Liyou [University of Oklahoma, Norman; Barua, Soumitra [University of Oklahoma; Barry, Kerry [Joint Genome Institute; Green-Tringe, Susannah [Joint Genome Institute, Walnut Creek, California; Watson, David B [ORNL; He, Zhili [University of Oklahoma; Hazen, Terry [Lawrence Berkeley National Laboratory (LBNL); Tiedje, James M. [Michigan State University, East Lansing; Rubin, Edward M. [Joint Genome Institute, Walnut Creek, California; Zhou, Jizhong [University of Oklahoma, Norman

2010-02-01T23:59:59.000Z

12

Heavy Metal Contamination In Soil Under The Application Of Polluted Sewage Water Across Vrishabhavathi River  

E-Print Network [OSTI]

The main aim in this study is to assess the level of heavy metals concentration in soil profile and their mobility in the presence of pH and organic carbon,where polluted water is used in agriculture. The samples of soil collected at different sites across Vrishabhavathi river valley have been analyzed for heavy metals, viz. Pb, Zn, Cd, Cr, Cu, Ni, Fe and Mn using atomic absorption spectrophotometer. These values assessed with respect to reference soil taken from unpolluted soil profile. The heavy metals studied at all sampling sites compared with Indian Standards and all heavy metals are below permissible limits. The concentration of all the metals is high compared to the soil sample taken from unpolluted site shows the build up of heavy metal concentration using polluted water in irrigation. The % of organic carbon varies from 1.9 to 2.9 % in top layer and 1 to 1.6 % in the subsequent layer. The pH value is higher on top layer soil and decreases in subsequent layer.

Jayadev E. T. Puttaih

13

Method for fixating sludges and soils contaminated with mercury and other heavy metals  

DOE Patents [OSTI]

The invention relates to a method, composition and apparatus for stabilizing mercury and other heavy metals present in a particulate material such that the metals will not leach from the particulate material. The method generally involves the application of a metal reagent, a sulfur-containing compound, and the addition of oxygen to the particulate material, either through agitation, sparging or the addition of an oxygen-containing compound.

Broderick, Thomas E.; Roth, Rachel L.; Carlson, Allan L.

2005-06-28T23:59:59.000Z

14

A Better Method for Evaluating Heavy Metal Water Pollution  

E-Print Network [OSTI]

Method for Evaluating Heavy Metal Water Pollution Janetheavy metal contamination would also help communities evaluate their water

Hering, Janet

2002-01-01T23:59:59.000Z

15

Utilization of a duckweed bioassay to evaluate leaching of heavy metals in smelter contaminated soils  

SciTech Connect (OSTI)

The purpose of this study was to determine whether a duckweed bioassay could be used to evaluate the downward migration of heavy metals in smelter soils. The duckweed bioassay was initially used to evaluate elutriates prepared from samples of smelter soils. These initial tests verified that the elutriates would elicit toxic responses. Elutriate testing was followed with an evaluation of leachate from untreated soil cores or soil cores that had been amended with organic matter either unplanted or planted to a grass-forb seed mixture. There was an inverse linear relationship between heavy-metal concentrations in leachate and NOEC and IC{sub 50} values expressed as percentages among all soil cores. Based on these preliminary duckweed bioassays, there were no differences between soil types or organic amended or non-amended soil, but leachate from vegetated soil cores were less toxic than were leachates from non-vegetated soil cores. Overall, the duckweed bioassays were useful in detecting heavy metal availability in elutriate and leachate samples from smelter soils.

Youngman, A.L.; Lydy, M.J. [Wichita State Univ., KS (United States). Dept. of Biological Sciences; Williams, T.L. [Laidlaw Environmental Services, Wichita, KS (United States)

1998-12-31T23:59:59.000Z

16

Heavy metal biosensor  

SciTech Connect (OSTI)

Compositions and methods are provided for detection of certain heavy metals using bacterial whole cell biosensors.

Hillson, Nathan J; Shapiro, Lucille; Hu, Ping; Andersen, Gary L

2014-04-15T23:59:59.000Z

17

Physiological responses of switchgrass (Panicum virgatum L.) to organic and inorganic amended heavy-metal contaminated chat tailings  

SciTech Connect (OSTI)

Study plots established at the Galena subsite of the Cherokee County Superfund Site in Southeastern Kansas by the US Bureau of Mines in 1990 were examined during the summer of 1996 to determine whether physiological criteria could be used to determine suitability of switchgrass for remediation of heavy-metal contaminated substrates. Switchgrass was chosen because it was the most frequently encountered species on these plots. Treatment plots included a treatment control, an organic residue treatment of 89.6 Mg Ha{sup {minus}1} composted cattle manure, and two inorganic fertilizer treatments recommended for either native grass or grass/legume mixtures. Plant response variables were photosynthetic rate, leaf conductance to water vapor, internal concentration of carbon dioxide in leaves, foliar transpiration rate, leaf water-use-efficiency, predawn leaf xylem water potential, and midday leaf xylem water potential. Predawn and midday xylem water potentials were higher for grass/legume inorganic treatment than for the other inorganic treatments. Leaf conductances were lower for organically treated plots than those plots not organically amended and both photosynthesis and transpiration were lower for organically treated plots. Leaf conductances and transpiration were higher for grass/legume treated plots than for plots lacking inorganic treatment. Water-use-efficiency was higher for native grass inorganically treated plots than for other inorganic treatments.

Youngman, A.L. [Wichita State Univ., KS (United States). Dept. of Biological Sciences

1997-12-31T23:59:59.000Z

18

Stabilization and reuse of heavy metal contaminated soils by means of quicklime sulfate salt treatment. Final report, September 1992--February 1995  

SciTech Connect (OSTI)

Capillary and hydraulic flows of water in porous media contaminated by heavy metal species often result in severe aquifer contamination. In the present study a chemical admixture stabilization approach is proposed, where heavy metal stabilization/immobilization is achieved by means of quicklime-based treatment. Both in-situ treatment by injection and on-site stabilization by excavation, mixing, and compaction will be investigated. In addition, the potential to reuse the resulting stabilized material as readily available construction material will also be investigated. The heavy metals under study include: arsenic, chromium, lead, and mercury. The proposed technical approach consists of three separate phases. During phase A, both artificial and naturally occurring contaminated soil mixes were treated, and then tested for stress-strain properties, leachability, micromorphology, mineralogical composition, permeability, setting time, and durability. In such a way, the effectiveness of the proposed remediation technology was verified, the treatment approach was optimized, and the underlying mechanisms responsible for stabilization were established. During phase B, the proposed technology will be tested for two DOE-site subscale systems, involving naturally occurring contaminated soil, using the same testing methodology as the one outlined for phase A. Provided that the proposed technology is proven effective for the subscale systems, a field application will be demonstrated. Again process quality monitoring will be performed by testing undisturbed samples collected from the treated sites, in the same fashion as for the previous phases. Following completion of the proposed study, a set of comprehensive guidelines for field applications will be developed. 42 refs., 196 figs., 26 tabs.

Dermatas, D.

1995-08-01T23:59:59.000Z

19

PHYTOEXTRACTION OF HEAVY METALS  

E-Print Network [OSTI]

) Type of phytoremediation Cost effective form of environmental remediation (Glass 1999) Chelating Agents: desorb heavy metals from soil matrix and form water-soluble metal complexes (Shen et al -using hyperaccumulator plant biomass to produce a bio-ore for commercial use -Li et al. look at using Ni

Blouin-Demers, Gabriel

20

Permeable Reactive Biobarriers for the Containment of Heavy Metal  

E-Print Network [OSTI]

. Heavy metals are leached as ground water reaches the exposed ores. Arizona has a rich historyPermeable Reactive Biobarriers for the Containment of Heavy Metal Contamination in Acid Mine) is defined as the presence heavy metals, increased acidity, and sulfate as a direct result of mining

Fay, Noah

Note: This page contains sample records for the topic "heavy metal contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Plant rhamnogalacturonan II complexation of heavy metal cations  

DOE Patents [OSTI]

The present invention provides rhamnogalacturonan-II (RG-II) and relates to its ability to complex specific multivalent heavy metal cations. In the presence of boric acid, RG-II monomers form dimers that are cross-linked by a borate ester. The yield of such borate ester cross-linked dimers of RG-II is enhanced in the presence of specific heavy metal cations. The present invention further relates to the utility of RG-II in assays for the detection of specific heavy metal contamination; as a reagent useful in the removal of specific heavy metal cations contaminating foods and liquids, for example, fish, wines, etc.; as a pharmaceutical composition useful as an antidote in specific heavy metal cation poisoning; as a treatment for the detoxification of specific heavy metal cations from blood and/or tissues; and in a method of remediation of waters and soils contaminated with specific heavy metal cations.

O'Neill, Malcolm A. (Winterville, GA); Pellerin, Patrice J. M. (Montpellier, FR); Warrenfeltz, Dennis (Athens, GA); Vidal, Stephane (Combaillaux, FR); Darvill, Alan G. (Athens, GA); Albersheim, Peter (Athens, GA)

1999-01-01T23:59:59.000Z

22

Plant rhamnogalacturonan II complexation of heavy metal cations  

DOE Patents [OSTI]

The present invention provides rhamnogalacturonan-II (RG-II) and relates to its ability to complex specific multivalent heavy metal cations. In the presence of boric acid, RG-II monomers form dimers that are cross-linked by a borate ester. The yield of such borate ester cross-linked dimers of RG-II is enhanced in the presence of specific heavy metal cations. The present invention further relates to the utility of RG-II in assays for the detection of specific heavy metal contamination; as a reagent useful in the removal of specific heavy metal cations contaminating foods and liquids, for example, fish, wines, etc.; as a pharmaceutical composition useful as an antidote in specific heavy metal cation poisoning; as a treatment for the detoxification of specific heavy metal cations from blood and/or tissues; and in a method of remediation of waters and soils contaminated with specific heavy metal cations. 15 figs.

O`Neill, M.A.; Pellerin, P.J.M.; Warrenfeltz, D.; Vidal, S.; Darvill, A.G.; Albersheim, P.

1999-03-02T23:59:59.000Z

23

OXFORD BIBLIOGRAPHIES IN ECOLOGY "HEAVY METAL TOLERANCE"  

E-Print Network [OSTI]

cellular mechanisms affected by heavy metals is Bánfalvi 2011. Pollution by heavy metals is an important environmental problem, and sources that focus on heavy metal pollution often contain information about heavyOXFORD BIBLIOGRAPHIES IN ECOLOGY "HEAVY METAL TOLERANCE" By Nishanta Rajakaruna and Robert S. Boyd

Rajakaruna, Nishanta

24

A Better Method for Evaluating Heavy Metal Water Pollution  

E-Print Network [OSTI]

efforts to control heavy metal pollution have focused oncomponent of heavy metal pollution, Dr. Hering found thatthat makes measuring heavy metal pollution a moving target.

Hering, Janet

2002-01-01T23:59:59.000Z

25

Process for removing heavy metal compounds from heavy crude oil  

DOE Patents [OSTI]

A process is provided for removing heavy metal compounds from heavy crude oil by mixing the heavy crude oil with tar sand; preheating the mixture to a temperature of about 650.degree. F.; heating said mixture to up to 800.degree. F.; and separating tar sand from the light oils formed during said heating. The heavy metals removed from the heavy oils can be recovered from the spent sand for other uses.

Cha, Chang Y. (Golden, CO); Boysen, John E. (Laramie, WY); Branthaver, Jan F. (Laramie, WY)

1991-01-01T23:59:59.000Z

26

Experimental investigation and thermodynamic modeling of extraction of heavy metal ions from aqueous solutions by chelation in supercritical carbon dioxide  

E-Print Network [OSTI]

Wastewater streams containing heavy metals are common in industry. To prevent the contamination of clean water sources, the Clean Water Act specifies limits on the heavy metal concentrations of industrial waste water. This creates a strong need...

Uyansoy, Hakki

1995-01-01T23:59:59.000Z

27

ORIGINAL ARTICLE The study of metal contamination in urban topsoils of Mexico City  

E-Print Network [OSTI]

- politan area of Mexico City. Keywords Heavy metals Á GIS Á Mexico City Á Urban topsoils Á Pollution ÁORIGINAL ARTICLE The study of metal contamination in urban topsoils of Mexico City using GIS Mari distribution of heavy metals (Pb, Cu, Zn, Ba, Co, Cr, Ni and V) in the urban environments of Mexico City using

Short, Daniel

28

INTERPRETING THE RESULTS OF SOIL TESTS FOR HEAVY METALS Vern Grubinger and Don Ross, University of Vermont  

E-Print Network [OSTI]

toxicity of a heavy metal will be affected by soil texture, organic matter, and pH. The health effects1 INTERPRETING THE RESULTS OF SOIL TESTS FOR HEAVY METALS Vern Grubinger and Don Ross, University of Vermont Agricultural soils normally contain low background levels of heavy metals. Contamination from

Hayden, Nancy J.

29

Heavy metals in Antarctic organisms  

SciTech Connect (OSTI)

To evaluate levels of essential (zinc and copper) and non-essential (mercury and cadmium) heavy metals, 34 species of organisms from different areas close to the Antarctic Peninsula were analysed. These included algae, filter-feeders, omnivorous invertebrates and vertebrates. Mercury was not detected, while cadmium was found in the majority of organisms analysed (detection limit was 0.05 ppm for both metals). The highest cadmium concentration was observed in the starfish Odontaster validus. Anthozoans, sipunculids and nudibranchs showed maximum levels of zinc, while the highest copper level was found in the gastropod Trophon brevispira. Mercury and cadmium levels in fishes were below the detection limit. Concentrations of essential and non-essential metals in birds were highest in liver followed by muscle and eggs. Cadmium and mercury levels in muscle of southern elephant seals were above the detection limit, whereas in Antarctic fur seals they were below it. The objective of the study was to gather baseline information for metals in Antarctic Ocean biota that may be needed to detect, measure and monitor future environmental changes. 46 refs., 7 figs., 8 tabs.

Moreno, J.E.A. de; Moreno, V.J. [Universidad Nacional de Mar del Plata (Argentina); Gerpe, M.S.; Vodopivez, C. [Instituto Antartico Argentino, Buenos Aires (Argentina)

1997-02-01T23:59:59.000Z

30

Phytoremediation of Heavy Metal Toxicity and Role of soil in Rhizobacteria  

E-Print Network [OSTI]

Abstract- Our surrounding is filled up with a large number of toxicants in different forms. They contaminate our water, land and atmosphere where we live. Heavy metal pollution of soil is a significant environmental problem and has its negative impact on human health and agriculture. Rhizosphere, as an important interface of soil and plant, plays a significant role in phytoremediation of contaminated soil by heavy metals, in which, microbial populations are known to affect heavy metal mobility and availability to the plant through release of chelating agents, acidification, phosphate solubilization and redox changes. Phytoremediation of toxic heavy metals could be carried out by using specific metallophytes. Green plants are the lungs of nature with unique ability to purifying impure air by photosynthesis and remove or minimize heavy metals toxicity from soil and water ecosystem by absorption, accumulation and biotransformation process. This article paper reviews some recent advances in effect and significance of rhizobacteria in phytoremediation of heavy metal toxicity in contaminated soils. There is also a need to improve our understanding of the mechanisms involved in the transfer and mobilization of heavy metals by rhizobacteria and to conduct research on the selection of microbial isolates from Rhizosphere of plants growing metal contaminated soils for specific restoration programmes. Index Terms- Environmental, heavy metal toxicity,

Rajendra Prasad Bharti; Abhilasha Shri Vastava; Kishor Soni; Asha Tiwari; Shivbhanu More

31

Situ formation of apatite for sequestering radionuclides and heavy metals  

DOE Patents [OSTI]

Methods for in situ formation in soil of a permeable reactive barrier or zone comprising a phosphate precipitate, such as apatite or hydroxyapatite, which is capable of selectively trapping and removing radionuclides and heavy metal contaminants from the soil, while allowing water or other compounds to pass through. A preparation of a phosphate reagent and a chelated calcium reagent is mixed aboveground and injected into the soil. Subsequently, the chelated calcium reagent biodegrades and slowly releases free calcium. The free calcium reacts with the phosphate reagent to form a phosphate precipitate. Under the proper chemical conditions, apatite or hydroxyapatite can form. Radionuclide and heavy metal contaminants, including lead, strontium, lanthanides, and uranium are then selectively sequestered by sorbing them onto the phosphate precipitate. A reducing agent can be added for reduction and selective sequestration of technetium or selenium contaminants.

Moore, Robert C. (Edgewood, NM)

2003-07-15T23:59:59.000Z

32

Ultrasensitive Voltammetric Detection of Trace Heavy Metal Ions...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Voltammetric Detection of Trace Heavy Metal Ions Using Carbon Nanotube Nanoelectrode Array. Ultrasensitive Voltammetric Detection of Trace Heavy Metal Ions Using Carbon Nanotube...

33

Composition and process for organic and metal contaminant fixation in soil  

DOE Patents [OSTI]

A method and compositions using a first ferrous iron containing solution with the iron concentration in excess of theoretical requirements to treat a contaminated site to reduce hexavalent chromium to trivalent chromium and coprecipitate trivalent chromium with other heavy metals and using a second solution of silicate containing a destabilizing salt to form a relatively impermeable gel in the contaminated site thereby fixing metals and organics to the extent that there should be no detectable ground water contamination.

Schwitzgebel, Klaus (7507 Chimney Corners, Austin, TX 78731)

1994-02-08T23:59:59.000Z

34

Enhanced Bioaccumulation of Heavy Metals by Bacterial Cells Displaying  

E-Print Network [OSTI]

Enhanced Bioaccumulation of Heavy Metals by Bacterial Cells Displaying Synthetic Phytochelatins for enhanced bioaccumulation of toxic metals. Synthetic genes encoding for several metal strategy for develop- ing high-affinity bioadsorbents suitable for heavy metal removal. © 2000 John Wiley

Chen, Wilfred

35

ENVIRONMENTAL IMPACT OF HEAVY METAL POLLUTION IN NATURAL AQUATIC SYSTEMS  

E-Print Network [OSTI]

He who taught the use of the pen, Taught man that which he knew not" The distribution of heavy metals between soil and soil solutions is a key issue in evaluating the environmental impact of long term applications of heavy metals to land. Contamination of soils by heavy metals has been reported by many workers. Metal adsorption is affected by many factors, including soil pH, clay mineralogy, abundance of oxides and organic matter, soil composition and solution ionic strength. The pH is one of the many factors affecting mobility of heavy metals in soils and it is likely to be the most easily managed and the most significant. To provide the appropriate level of protection for aquatic life and other uses of the resource, it is important to be able to predict the environmental distribution of important metals on spatial and temporal scales and to do so with particular emphasis on the water column concentrations. Regulatory levels reflected in water quality criteria or standards are based on

Muhammad Rehan Tayab

36

RESEARCH ARTICLE Assessment of metal contaminations leaching  

E-Print Network [OSTI]

RESEARCH ARTICLE Assessment of metal contaminations leaching out from recycling plastic bottles syntheses, partic- ularly antimony, human exposure to metal release from plastic bottles has been a serious from a series of recycling plastic bottles upon treatments. Methodology In this study, leaching

Short, Daniel

37

Attrition resistant catalysts and sorbents based on heavy metal poisoned FCC catalysts  

DOE Patents [OSTI]

A heavy metal poisoned, spent FCC catalyst is treated by chemically impregnating the poisoned catalyst with a new catalytic metal or metal salt to provide an attrition resistant catalyst or sorbent for a different catalytic or absorption process, such as catalysts for Fischer-Tropsh Synthesis, and sorbents for removal of sulfur gases from fuel gases and flue-gases. The heavy metal contaminated FCC catalyst is directly used as a support for preparing catalysts having new catalytic properties and sorbents having new sorbent properties, without removing or passivating the heavy metals on the spent FCC catalyst as an intermediate step.

Gangwal, S.; Jothimurugesan, K.

1999-07-27T23:59:59.000Z

38

Heavy Metal Tolerance Robert S. Boyd, Nishanta Rajakaruna  

E-Print Network [OSTI]

be useful to solve environmental problems caused by heavy metal pollution. General Overviews General: a recent example targeting cellular mechanisms affected by heavy metals is Bánfalvi 2011. Pollution by heavy metals is an important environmental problem, and sources that focus on heavy metal pollution

Rajakaruna, Nishanta

39

Detection of Heavy Metal Ions Based on Quantum Point Contacts  

E-Print Network [OSTI]

. The ability to detect trace amounts of metal ions is important because of the toxicity of heavy metal ionsDetection of Heavy Metal Ions Based on Quantum Point Contacts Vasanth Rajagopalan, Salah Boussaad on many living organisms and the consequence of heavy metal ions not being biodegradable. To date, heavy

Zhang, Yanchao

40

Gold Nanoparticle-Based Sensing of "Spectroscopically Silent" Heavy Metal  

E-Print Network [OSTI]

of aqueous heavy metal ions, including toxic metals such as lead, cadmium, and mercury, is describedLetters Gold Nanoparticle-Based Sensing of "Spectroscopically Silent" Heavy Metal Ions Youngjin Kim that by functionalizing metal nanoparticles with appropriate heavy-metal ion receptors, the particles might be coaxed

Note: This page contains sample records for the topic "heavy metal contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Chemistry 330 / Study Guide 217 Toxic Heavy Metals  

E-Print Network [OSTI]

Chemistry 330 / Study Guide 217 Unit 7 Toxic Heavy Metals Overview In ancient Rome wine was stored. Metals--especially heavy metals--pose a unique environmental pollution problem. Heavy metals are especially toxic because their ions are water-soluble and readily taken up by the body. Once in the body

Short, Daniel

42

Enrichment of Heavy Metals in Sediment Resulting from Soil  

E-Print Network [OSTI]

, Harpenden, Hertfordshire AL5 2JQ, U.K. Heavy metal pollution of soil and water is often associated of water erosion in detaching and transporting sediment-associated heavy metals from agri- cultural soils to surface waters has been overlooked. Heavy metals in arable soils are derived from the soil parent material

Quinton, John

43

Tons of Heavy Metals in Mill Creek Sediments Heather Freeman  

E-Print Network [OSTI]

objectives for this summer research were to: 1.) determine how much heavy metal pollution has accumulatedTons of Heavy Metals in Mill Creek Sediments Heather Freeman 8/30/99 Geology Department Advisors: Dr. Kees DeJong Dr. Barry Manyard Dr. David Nash #12;Tons of heavy metals in Mill Creek sediments

Maynard, J. Barry

44

REVIEW ARTICLE Heavy Metal Pollutants and Chemical Ecology: Exploring  

E-Print Network [OSTI]

REVIEW ARTICLE Heavy Metal Pollutants and Chemical Ecology: Exploring New Frontiers Robert S. Boyd to be learned about how heavy metal pollution impacts organisms, and that exciting new research frontiers as pollutants (Han et al. 2002), including Cd, Cu, Cr, Hg, Pb, Ni, and Zn. Much research on heavy metal

Boyd, Robert S.

45

Water Purification Using Functional Nanomaterials: Sequestering Toxic Heavy Metals  

SciTech Connect (OSTI)

Water, and water quality, are issues of critical importance to the future of humankind. Our water supply has been contaminated by a wide variety of industrial, military and natural sources. There is a serious need for technologies to remove toxic heavy metals and radionuclides from the worlds water supplies. Surfactant templated synthesis of mesoporous ceramics provides a versatile foundation upon which to create high efficiency environmental sorbents. These nanoporous ceramics condense a huge amount of surface area into a very small volume. These mesoporous architectures can be subsequently functionalized through molecular self-assembly. These functional mesoporous materials offer significant capabilities in terms of removal of heavy metals and radionuclides from groundwater and other liquid media. They are highly efficient sorbents, whose interfacial chemistry can be fine-tuned to selectively sequester a specific target species, such as heavy metals, tetrahedral oxometallate anions and radionuclides. Their rigid, open pore structure allows for rapid, efficient sorption kinetics. This manuscript provides an overview of the design, synthesis and performance of the sorbent materials.

Fryxell, Glen E.

2008-02-01T23:59:59.000Z

46

An assessment of metal contamination in mangrove sediments and leaves from Punta Mala Bay, Pacific Panama  

E-Print Network [OSTI]

Elsevier Ltd. All rights reserved. Keywords: Coastal pollution; Sediment; Heavy metals; Mangrove; Laguncularia racemosa; Panama 1. Introduction Elevated concentrations of heavy metals have been re- corded allows metal mobilisation and bioavailability (Clark et al., 1998). Concentrations of heavy metals

Bermingham, Eldredge

47

TOLERANCE OF HEAVY METALS IN VASCULAR PLANTS: ARSENIC HYPERACCUMULATIONBY  

E-Print Network [OSTI]

CHAPTER 28 b TOLERANCE OF HEAVY METALS IN VASCULAR PLANTS: ARSENIC HYPERACCUMULATIONBY CHINESE the roots take up colossal amounts of a toxic metal from soils and rapidly sequester into their above hyperaccumulation in the light of accumulated knowledge on heavy metal tolerance in higher plants. 1.INTRODUCTION

Ma, Lena

48

Heavy Metal Islands | The Ames Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun with Bigfront.jpgcommunity200cellHeat Transfer in GEoperation inHeavy Metal

49

Functionalized Nanoporous Silica for Removal of Heavy Metals...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(SAMMS) have previously demonstrated the ability to serve as very effective heavy metal sorbents in a range of aquatic and environmental systems suggesting they may be...

50

Portable X-Ray, K-Edge Heavy Metal Detector  

SciTech Connect (OSTI)

The X-Ray, K-Edge Heavy Metal Detection System was designed and built by Ames Laboratory and the Center for Nondestructive Evaluation at Iowa State University. The system uses a C-frame inspection head with an X-ray tube mounted on one side of the frame and an imaging unit and a high purity germanium detector on the other side. the inspection head is portable and can be easily positioned around ventilation ducts and pipes up to 36 inches in diameter. Wide angle and narrow beam X-ray shots are used to identify the type of holdup material and the amount of the contaminant. Precise assay data can be obtained within minutes of the interrogation. A profile of the containerized holdup material and a permanent record of the measurement are immediately available.

Fricke, V.

1999-10-25T23:59:59.000Z

51

Metal impacts on microbial biomass in the anoxic sediments of a contaminated lake  

E-Print Network [OSTI]

and J. I. Drever (1997), Toxicity of heavy metals (Ni,Zn) to2001), Acute toxicity of heavy metals to acetate-utilizing

Gough, Heidi L.

2011-01-01T23:59:59.000Z

52

Concentrations of Heavy Metals in Selected Tissues of Blue  

E-Print Network [OSTI]

Abstract: Persian Gulf supports diverse ecosystems and biota in need of remediation and protection and metal data from this region is needed. The levels of heavy metals (Fe, Hg, Ni and Pb) in tissues (hepatopancreas, muscle and exoskeleton) of blue swimming crab, Portunus pelagicus and sediments in the Persian Gulf coasts, south Iran were investigated. Heavy metals analysis was performed by Atomic Absorption Spectrophotometer. The concentration of heavy metals in sediments at all sampling stations occurs in descending order of Fe> Ni> Hg> Pb during both seasons. The distribution pattern of heavy metals in the tissues of crab and sediments was as follows: sediment> hepatopancreasn> muscle> exoskeleton. Maximum concentration of the total heavy metals in sediments and all tissues of P. pelagicus observes in Bahrekan station (Pheavy metals in the tissues of the crab P. pelagicus. In present study recorded that there was negligible differences in heavy metals levels between different seasons. Differences in heavy metals concentrations among the species is likely to have resulted from metal bioavailability, hydrodynamics of the environment, changes in tissue composition, stations of collection and sources of pollution within Persian Gulf.

Mehdi Hosseini; Afshin Abdi Bastami; Javad Kazemzadeh Khoei; Maryam Esmailian; Elmira Janmohammadi Songhori; Mina Najafzadeh

53

Detection of Heavy Metal Ions in Drinking Water Using a  

E-Print Network [OSTI]

Detection of Heavy Metal Ions in Drinking Water Using a High-Resolution Differential Surface-resolution differential surface plasmon resonance (SPR) sensor for heavy metal ion detection. The sensor surface the sensing surface with peptides NH2- Gly-Gly-His-COOH and NH2-(His)6-COOH. Cu2+ in drinking water was tested

Chen, Wilfred

54

Removal of Heavy Metals from Industrial Effluent Using Bacteria  

E-Print Network [OSTI]

Industrial development results in the generation of industrial effluents, and if untreated results in water, sediment and soil pollution. (Fakayode and Onianwa, 2002 ? Fakayode, 2005). Industrial wastes and emission contain toxic and hazardous substances, most of which are detrimental to human health (Jimena et al.,2008 ? Ogunfowokan et al.,2005 ? Rajaram et al.,2008). The key pollutants include heavy metals, chemical wastes and oil spills etc. Heavy metal resistant bacteria have significant role in bioremediation of heavy metals in wastewater. The objective of this work is to study the role of bacteria in removing the heavy metals present in the industrial effluent.Five effluent samples out of nine were selected for this study due to high content of heavy metals. The heavy metals Hg and Cu were removed by Bacillus sp. The average Hg reduction was 45 % and Cu reduction was recorded as 62%. The heavy metals Cd, As and Co were removed by Pseudomonas sp. The average Cd reduction was 56%, average As reduction was 34 % and average Co reduction was recorded as 53%. The heavy metals Cd and Cu were removed by Staphylococcus sp. The average Cd reduction was 44 % and average Cu reduction was recorded as 34 %.

Manisha N; Dinesh Sharma; Arun Kumar

55

A Fuzzy Model of Heavy Metal Loadings in Marine Environment  

E-Print Network [OSTI]

contaminants, questions have been raised as to the environmental impact of long-term disposal in coastal areas and Morecambe Bay). Each metal concentration is associated with a fuzzy set "contaminated", defined over a set indicates all highly contaminated sites. The proposed fuzzy model is easy to implement and the results

Kuncheva, Ludmila I.

56

E-Print Network 3.0 - avoid heavy metals Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

immobilization of heavy metals has been investigated as a promising method... capacity of heavy metals can be obtained and employed. ... Source: Ma, Lena - Soil and Water Science...

57

Mechanisms of metal release from contaminated coastal sediments  

E-Print Network [OSTI]

The fate of trace metals in contaminated coastal sediments is poorly understood, yet critical for effective coastal management. The aim of this thesis is to investigate and quantify the mechanisms leading to the release ...

Kalnejais, Linda H

2005-01-01T23:59:59.000Z

58

Heavy Metal Tolerance in Plants J.ANTONOVIOS  

E-Print Network [OSTI]

#12;Heavy Metal Tolerance in Plants J.ANTONOVIOS Department of Biology. University of Stirling to Sprays and Toxicants . . 33 3.Metal Tolerance in Laboratory Strains . . . 34 Present address: Department.K. I. Introduction . . . . . . . . . . . 2 I1. Ecology of Metal Tolerance . . . . . . . . . 4 A

Antonovics, Janis

59

REVIEW PAPER How metal-tolerant ecotypes of ectomycorrhizal fungi  

E-Print Network [OSTI]

with open access at Springerlink.com Abstract & Introduction Heavy metal pollution is a strong driver for heavy metal-contaminated soils. Keywords Heavy metal pollution . Heavy metal tolerance . EctomycorrhizalREVIEW PAPER How metal-tolerant ecotypes of ectomycorrhizal fungi protect plants from heavy metal

Boyer, Edmond

60

Removal of radioactive materials and heavy metals from water using magnetic resin  

DOE Patents [OSTI]

Magnetic polymer resins capable of efficient removal of actinides and heavy metals from contaminated water are disclosed together with methods for making, using, and regenerating them. The resins comprise polyamine-epichlorohydrin resin beads with ferrites attached to the surfaces of the beads. Markedly improved water decontamination is demonstrated using these magnetic polymer resins of the invention in the presence of a magnetic field, as compared with water decontamination methods employing ordinary ion exchange resins or ferrites taken separately. 9 figs.

Kochen, R.L.; Navratil, J.D.

1997-01-21T23:59:59.000Z

Note: This page contains sample records for the topic "heavy metal contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Removal of radioactive materials and heavy metals from water using magnetic resin  

DOE Patents [OSTI]

Magnetic polymer resins capable of efficient removal of actinides and heavy metals from contaminated water are disclosed together with methods for making, using, and regenerating them. The resins comprise polyamine-epichlorohydrin resin beads with ferrites attached to the surfaces of the beads. Markedly improved water decontamination is demonstrated using these magnetic polymer resins of the invention in the presence of a magnetic field, as compared with water decontamination methods employing ordinary ion exchange resins or ferrites taken separately.

Kochen, Robert L. (Boulder, CO); Navratil, James D. (Simi Valley, CA)

1997-01-21T23:59:59.000Z

62

Process for treating waste water having low concentrations of metallic contaminants  

DOE Patents [OSTI]

A process for treating waste water having a low level of metallic contaminants by reducing the toxicity level of metallic contaminants to an acceptable level and subsequently discharging the treated waste water into the environment without removing the treated contaminants.

Looney, Brian B; Millings, Margaret R; Nichols, Ralph L; Payne, William L

2014-12-16T23:59:59.000Z

63

Heavy metal characterization of municipal solid waste compost  

E-Print Network [OSTI]

Committee: Dr. Bill Batchelor Dr. Kirk W. Brown Waste incineration and composting create solid residues which are later applied to or buried under soils. Although incinerator ash has been studied extensively for heavy metal content, much less is known... Digestion of Sediments, Sludges, and Soils does not fully recover all heavy metals in MSW compost. Neutron activation analysis (NAA) of undigested solid residues remaining after Method 3050 digestion of MSW compost showed that residues contained...

Worsham, Michael Craig

1992-01-01T23:59:59.000Z

64

ORIGINAL ARTICLE Speciation and mobility of heavy metals in mud in coastal  

E-Print Network [OSTI]

and the properties of the pore water in the mud may induce the release of some heavy metals into the mud. Field, but the heavy metals in the groundwater are in- creased. The release of heavy metals into pore water dueORIGINAL ARTICLE Speciation and mobility of heavy metals in mud in coastal reclamation areas

Jiao, Jiu Jimmy

65

Heavy metal ions are potent inhibitors of protein folding  

SciTech Connect (OSTI)

Environmental and occupational exposure to heavy metals such as cadmium, mercury and lead results in severe health hazards including prenatal and developmental defects. The deleterious effects of heavy metal ions have hitherto been attributed to their interactions with specific, particularly susceptible native proteins. Here, we report an as yet undescribed mode of heavy metal toxicity. Cd{sup 2+}, Hg{sup 2+} and Pb{sup 2+} proved to inhibit very efficiently the spontaneous refolding of chemically denatured proteins by forming high-affinity multidentate complexes with thiol and other functional groups (IC{sub 50} in the nanomolar range). With similar efficacy, the heavy metal ions inhibited the chaperone-assisted refolding of chemically denatured and heat-denatured proteins. Thus, the toxic effects of heavy metal ions may result as well from their interaction with the more readily accessible functional groups of proteins in nascent and other non-native form. The toxic scope of heavy metals seems to be substantially larger than assumed so far.

Sharma, Sandeep K. [Biochemisches Institut, Universitaet Zuerich, CH-8057 Zuerich (Switzerland); Departement de Biologie Moleculaire Vegetale, Universite de Lausanne, CH-1015 Lausanne (Switzerland); Goloubinoff, Pierre [Departement de Biologie Moleculaire Vegetale, Universite de Lausanne, CH-1015 Lausanne (Switzerland); Christen, Philipp [Biochemisches Institut, Universitaet Zuerich, CH-8057 Zuerich (Switzerland)], E-mail: christen@bioc.uzh.ch

2008-07-25T23:59:59.000Z

66

Catalytic extraction processing of contaminated scrap metal  

SciTech Connect (OSTI)

Molten Metal Technology was awarded a contract to demonstrate the applicability of the Catalytic Extraction Process, a proprietary process that could be applied to US DOE`s inventory of low level mixed waste. This paper is a description of that technology, and included within this document are discussions of: (1) Program objectives, (2) Overall technology review, (3) Organic feed conversion to synthetic gas, (4) Metal, halogen, and transuranic recovery, (5) Demonstrations, (6) Design of the prototype facility, and (7) Results.

Griffin, T.P.; Johnston, J.E.; Payea, B.M.; Zeitoon, B.M.

1995-12-01T23:59:59.000Z

67

Limiting diffusion coefficients of heavy molecular weight organic contaminants in supercritical carbon dioxide  

E-Print Network [OSTI]

LIMITING DIFFUSION COEFFICIENTS OF HEAVY MOLECULAR WEIGHT ORGANIC CONTAMINANTS IN SUPERCRITICAL CARBON DIOXIDE A Thesis by MAURICIO OREJUELA Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE August 1994 Major Subject: Chemical Engineering LIMITING DIFFUSION COEFFICIENTS OF HEAVY MOLECULAR WEIGHT ORGANIC CONTAMINANTS IN SUPERCRITICAL CARBON DIOXIDE A Thesis by MAURICIO OREJUELA Submitted...

Orejuela, Mauricio

1994-01-01T23:59:59.000Z

68

Sorption of heavy metal ions on new metal-ligand complexes chemically derived from Lycopodium clavatum  

SciTech Connect (OSTI)

Sorption of heavy metal ions from aqueous solution has been investigated as a function of pH using a novel exchanger system whereby Lycopodium clavatum is functionalized with carboxylate and glyoxime metal-ligand complexes. The new ligand exchangers were prepared using a reaction of diaminosporopollenin with various metal-ligand complexes of glyoxime and monocarboxylic acid. The sorptive behavior of these metal-ligand exchangers and the possibilities to remove and to recover selectively heavy metal cations using these systems are discussed on the basis of their chemical natures and their complexing properties.

Pehlivan, E.; Ersoz, M.; Yildiz, S. [Univ. of Selcuk, Konya (Turkey); Duncan, H.J. [Univ. of Glasgow, Scotland (United Kingdom)

1994-08-01T23:59:59.000Z

69

Detection of Heavy Metal Ions in Water by High-Resolution Surface Plasmon Resonance  

E-Print Network [OSTI]

Detection of Heavy Metal Ions in Water by High-Resolution Surface Plasmon Resonance Spectroscopy voltammetry (ASV) capability has been demonstrated for detecting heavy metal ions in water. Metal ions in water from part-per-million to sub-part-per-billion levels with good linearity. Heavy metal poisoning

Zhang, Yanchao

70

Tunable Biopolymers for Heavy Metal Removal Jan Kostal, Ashok Mulchandani, and Wilfred Chen*  

E-Print Network [OSTI]

persistent nature, heavy metal ions are major contributors to pollution of the biosphere.1,2 These metalsTunable Biopolymers for Heavy Metal Removal Jan Kostal, Ashok Mulchandani, and Wilfred Chen synthesized for the removal of heavy metals from dilute waste streams. Protein-protein interaction

Chen, Wilfred

71

Recycle of contaminated scrap metal, Volume 2. Semi-annual report, September 1993--January 1996  

SciTech Connect (OSTI)

Catalytic Extraction Processing (CEP) has been demonstrated to be a robust, one-step process that is relatively insensitive to wide variations in waste composition and is applicable to a broad spectrum of DOE wastes. Catalytic Processing Unit (CPU) design models have been validated through experimentation to provide a high degree of confidence in our ability to design a bulk solids CPU for processing DOE wastes. Two commercial CEP facilities have been placed in commission and are currently processing mixed low level wastes. These facilities provide a compelling indication of the maturity, regulatory acceptance, and commercial viability of CEP. In concert with the DOE, Nolten Metal Technology designed a program which would challenge preconceptions of the limitations of waste processing technologies: demonstrate the recycling of ferrous and non-ferrous metals--to establish that radioactively contaminated scrap metal could be converted to high-grade, ferrous and non-ferrous alloys which can be reused by DOE or reintroduced into commerce; immobilize radionuclides--that CEP would concentrate the radionuclides in a durable vitreous phase, minimize secondary waste generation and stabilize and reduce waste volume; destroy hazardous organics--that CEP would convert hazardous organics to valuable industrial gases, which could be used as an energy source; recover volatile heavy metals--that CEP`s off-gas treatment system would capture volatile heavy metals, such as mercury and lead; and establish that CEP is economical for processing contaminated scrap metal in the DOE inventory. The execution of this program resulted in all objectives being met. Volume II contains: Task 1.4, optimization of the vitreous phase for stabilization of radioactive species; Task 1.5, experimental testing of Resource Conservation and Recovery Act (RCRA) wastes; and Task 1.6, conceptual design of a CEP facility.

NONE

1996-07-01T23:59:59.000Z

72

Heavy metals in composted municipal solid wastes for  

E-Print Network [OSTI]

Heavy metals in composted municipal solid wastes for amendment of agricultural soils/ Mtaux lourds dans le compost de dchets municipaux pour application agricole Valrie Duchesneau, #4634809 EVS4904 mtaux lourds des compostes de dchets municipaux? http://www.ecometiers.com/fiche/images/43.jpg La

Blouin-Demers, Gabriel

73

THERMODYNAMIC STUDY OF HEAVY METALS BEHAVIOUR DURING MUNICIPAL WASTE INCINERATION  

E-Print Network [OSTI]

, heat and mass transfer, drying, pyrolysis, combustion of pyrolysis gases, combustion and gasificationTHERMODYNAMIC STUDY OF HEAVY METALS BEHAVIOUR DURING MUNICIPAL WASTE INCINERATION Y. ME´ NARD, A Me´tallurgie (LSG2M) Nancy, France T he incineration of municipal solid waste (MSW) contributes

Boyer, Edmond

74

Feasibility of re-melting NORM-contaminated scrap metal  

SciTech Connect (OSTI)

Naturally occurring radioactive materials (NORM) sometimes accumulate inside pieces of equipment associated with oil and gas production and processing activities. Typically, the NORM accumulates when radium that is present in solution in produced water precipitates out in scale and sludge deposits. Scrap equipment containing residual quantities of these NORM-bearing scales and sludges can present a waste management problem if the radium concentrations exceed regulatory limits or activate the alarms on radiation screening devices installed at most scrap metal recycling facilities. Although NORM-contaminated scrap metal currently is not disposed of by re-melting, this form of recycling could present a viable disposition option for this waste stream. Studies indicate that re-melting NORM-contaminated scrap metal is a viable recycling option from a risk-based perspective. However, a myriad of economic, regulatory, and policy issues have caused the recyclers to turn away virtually all radioactive scrap metal. Until these issues can be resolved, re-melting of the petroleum industry's NORM-impacted scrap metal is unlikely to be a widespread practice. This paper summarizes the issues associated with re-melting radioactive scrap so that the petroleum industry and its regulators will understand the obstacles. This paper was prepared as part of a report being prepared by the Interstate Oil and Gas Compact Commission's NORM Subcommittee.

Winters, S. J.; Smith, K. P.

1999-10-26T23:59:59.000Z

75

Elevated sulfate reduction in metal-contaminated freshwater lake sediments  

SciTech Connect (OSTI)

Although sulfate-reducing prokaryotes have long been studied as agents of metals bioremediation, impacts of long-term metals exposure on biologically mediated sulfur cycling in natural systems remains poorly understood. The effects of long-term exposure to metal stress on the freshwater sulfur cycle were studied, with a focus on biologic sulfate reduction using a combination of microbial and chemical methods. To examine the effects after decades of adaptation time, a field-based experiment was conducted using multiple study sites in a natural system historically impacted by a nearby zinc smelter (Lake DePue, Illinois). Rates were highest at the most metals-contaminated sites (-35 {mu}mol/cm{sup 3}/day) and decreased with decreased pore water zinc and arsenic contamination levels, while other environmental characteristics (i.e., pH, nutrient concentrations and physical properties) showed little between-site variation. Correlations were established using an artificial neural network to evaluate potentially non-linear relationships between sulfate reduction rates (SRR) and measured environmental variables. SRR in Lake DePue were up to 50 times higher than rates previously reported for lake sediments and the chemical speciation of Zn was dominated by the presence of ZnS as shown by X-ray Absorption Spectroscopy (XAS). These results suggest that long-term metal stress of natural systems might alter the biogeochemical cycling of sulfur by contributing to higher rates of sulfate reduction.

Gough, H.L.; Dahl, A.L.; Tribou, E.; Noble, P.A.; Gaillard, J.-F.; Stahl, D.A. (UWASH); (NWU)

2009-01-06T23:59:59.000Z

76

Colonization of heavy metal polluted soils by Collembola: preliminary1 experiments in compartmented boxes2  

E-Print Network [OSTI]

1 Colonization of heavy metal polluted soils by Collembola: preliminary1 experiments;2 Keywords: Collembola, Acidophily, Heavy metals, Migration, Sensitivity.1 2 1. Introduction3 4 The sensitivity of Collembola (Hexapoda) to heavy metals has been the subject of recent5 investigations, pointing

Paris-Sud XI, Université de

77

Novel synthetic phytochelatin-based capacitive biosensor for heavy metal ion detection  

E-Print Network [OSTI]

to increasing levels of diverse pollutants. Heavy metals represent some of the most toxic ones not only to pollution by heavy metals, and is trying to remediate, control and minimize such pollution as muchNovel synthetic phytochelatin-based capacitive biosensor for heavy metal ion detection Ibolya

Chen, Wilfred

78

Macrobenthic Community in Tolo Harbour, Hong Kong and its Relations with Heavy Metals  

E-Print Network [OSTI]

the Pearson­Rosenberg model for succession along a pollution gradient. Keywords Macrobenthos . Heavy metalMacrobenthic Community in Tolo Harbour, Hong Kong and its Relations with Heavy Metals Kouping Chen study investigated the macrobenthic community in Tolo Harbour, Hong Kong, aiming at linking heavy metal

Jiao, Jiu Jimmy

79

IMPACT OF HEAVY METALS IN SEWAGE SLUDGE ON SOIL AND PLANTS (COLZA and WHEAT)  

E-Print Network [OSTI]

IMPACT OF HEAVY METALS IN SEWAGE SLUDGE ON SOIL AND PLANTS (COLZA and WHEAT) Najla LASSOUED1@emse.fr Abstract We are testing the impact of heavy metals in sludge from urban and industrial wastewater treatment> Cu> Ni> Co> Cd The contents of heavy metals in the sludge is made very high and exceed European

Paris-Sud XI, Universit de

80

Water Research 37 (2003) 43114330 A review of the biochemistry of heavy metal  

E-Print Network [OSTI]

of toxic heavy metals such as Cd2+ , Cu2+ , Zn2+ , Pb2+ , Cr3+ , and Hg2+ by inexpensive biomaterialsWater Research 37 (2003) 4311­4330 Review A review of the biochemistry of heavy metal biosorption and fucoidan, which are chiefly responsible for heavy metal chelation. In this comprehensive review

Long, Bernard

Note: This page contains sample records for the topic "heavy metal contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Heavy Metal Stress. Activation of Distinct Mitogen-Activated Protein Kinase Pathways  

E-Print Network [OSTI]

, 2003; Polle and Schu¨tzendu¨bel, 2003). Heavy metal toxicity comprises inactivation of biomole- culesHeavy Metal Stress. Activation of Distinct Mitogen-Activated Protein Kinase Pathways by Copper, Vienna Biocenter, A­1030 Vienna, Austria Excessive amounts of heavy metals adversely affect plant growth

Hirt, Heribert

82

Sequential Extraction Versus Comprehensive Characterization of Heavy Metal Species in Brownfield Soils  

SciTech Connect (OSTI)

The applicability of sequential extraction as a means to determine species of heavy-metals was examined by a study on soil samples from two Superfund sites: the National Lead Company site in Pedricktown, NJ, and the Roebling Steel, Inc., site in Florence, NJ. Data from a standard sequential extraction procedure were compared to those from a comprehensive study that combined optical- and scanning-electron microscopy, X-ray diffraction, and chemical analyses. The study shows that larger particles of contaminants, encapsulated contaminants, and/or man-made materials such as slags, coke, metals, and plastics are subject to incasement, non-selectivity, and redistribution in the sequential extraction process. The results indicate that standard sequential extraction procedures that were developed for characterizing species of contaminants in river sediments may be unsuitable for stand-alone determinative evaluations of contaminant species in industrial-site materials. However, if employed as part of a comprehensive, site-specific characterization study, sequential extraction could be a very useful tool.

Dahlin, Cheryl L.; Williamson, Connie A.; Collins, W. Keith; Dahlin, David C.

2002-06-01T23:59:59.000Z

83

Surfactant biocatalyst for remediation of recalcitrant organics and heavy metals  

DOE Patents [OSTI]

Novel strains of isolated and purified bacteria have been identified which have the ability to degrade petroleum hydrocarbons including a variety of PAHs. Several isolates also exhibit the ability to produce a biosurfactant. The combination of the biosurfactant-producing ability along with the ability to degrade PAHs enhances the efficiency with which PAHs may be degraded. Additionally, the biosurfactant also provides an additional ability to bind heavy metal ions for removal from a soil or aquatic environment.

Brigmon, Robin L. (North Augusta, SC); Story, Sandra (Greenville, SC); Altman; Denis J. (Evans, GA); Berry, Christopher J. (Aiken, SC)

2011-03-29T23:59:59.000Z

84

Surfactant biocatalyst for remediation of recalcitrant organics and heavy metals  

DOE Patents [OSTI]

Novel strains of isolated and purified bacteria have been identified which have the ability to degrade petroleum hydrocarbons including a variety of PAHs. Several isolates also exhibit the ability to produce a biosurfactant. The combination of the biosurfactant-producing ability along with the ability to degrade PAHs enhances the efficiency with which PAHs may be degraded. Additionally, the biosurfactant also provides an additional ability to bind heavy metal ions for removal from a soil or aquatic environment.

Brigmon, Robin L. (North Augusta, SC); Story, Sandra (Greenville, SC); Altman, Denis J. (Evans, GA); Berry, Christopher J. (Aiken, SC)

2011-03-15T23:59:59.000Z

85

Surfactant biocatalyst for remediation of recalcitrant organics and heavy metals  

DOE Patents [OSTI]

Novel strains of isolated and purified bacteria have been identified which have the ability to degrade petroleum hydrocarbons including a variety of PAHs. Several isolates also exhibit the ability to produce a biosurfactant. The combination of the biosurfactant-producing ability along with the ability to degrade PAHs enhances the efficiency with which PAHs may be degraded. Additionally, the biosurfactant also provides an additional ability to bind heavy metal ions for removal from a soil or aquatic environment.

Brigmon, Robin L. (North Augusta, SC); Story, Sandra (Greenville, SC); Altman, Denis (Evans, GA); Berry, Christopher J. (Aiken, SC)

2009-01-06T23:59:59.000Z

86

Surfactant biocatalyst for remediation of recalcitrant organics and heavy metals  

DOE Patents [OSTI]

Novel strains of isolated and purified bacteria have been identified which have the ability to degrade petroleum hydrocarbons including a variety of PAHs. Several isolates also exhibit the ability to produce a biosurfactant. The combination of the biosurfactant-producing ability along with the ability to degrade PAHs enhances the efficiency with which PAHs may be degraded. Additionally, the biosurfactant also provides an additional ability to bind heavy metal ions for removal from a soil or aquatic environment.

Brigmon, Robin L. (North Augusta, SC); Story, Sandra (Greenville, SC); Altman, Denis J. (Evans, GA); Berry, Christopher J. (Aiken, SC)

2011-05-03T23:59:59.000Z

87

Metal resistant plants and phytoremediation of environmental contamination  

DOE Patents [OSTI]

The present disclosure provides a method of producing transgenic plants which are resistant to at least one metal ion by transforming the plant with a recombinant DNA comprising a nucleic acid encoding a bacterial arsenic reductase under the control of a plant expressible promoter, and a nucleic acid encoding a nucleotide sequence encoding a phytochelatin biosynthetic enzyme under the control of a plant expressible promoter. The invention also relates a method of phytoremediation of a contaminated site by growing in the site a transgenic plant expressing a nucleic acid encoding a bacterial arsenate reductase and a nucleic acid encoding a phytochelatin biosynthetic enzyme.

Meagher, Richard B.; Li, Yujing; Dhankher, Om P.

2010-04-20T23:59:59.000Z

88

Soil & Sediment Contamination, 17:619629, 2008 Copyright Taylor & Francis Group, LLC  

E-Print Network [OSTI]

contamination, sewage lagoon Introduction Heavy metal pollution is one of the most pervasive and serious-0383 print / 1549-7887 online DOI: 10.1080/15320380802425121 Fate of Heavy Metal Contaminants in a Former in 1999, was an- alyzed to determine the subsequent mobility of heavy metals and their relationship

Neher, Deborah A.

89

Environmental Pollution (Series B) 6 (1983)309-318 Heavy Metals in the Centipede Lithobius variegatus  

E-Print Network [OSTI]

Environmental Pollution (Series B) 6 (1983)309-318 Heavy Metals in the Centipede Lithobius) may accumulate considerable amounts of heavy metals. These authors have suggested that the high concentrations of metals in these animals may have detrimental effects on predators. However, 309 Environ. Pollut

Hopkin, Steve

90

Short Communication Kinetics and thermodynamics of heavy metal ions sequestration onto novel  

E-Print Network [OSTI]

biomasses had been chosen and utilized by researchers to sequester toxic heavy metal ions from industrialShort Communication Kinetics and thermodynamics of heavy metal ions sequestration onto novel is generally considered as the most toxic metal in natural ecosystems (Clarkson, 1993). Over the years, various

Gong, Jian Ru

91

Trace metal contamination of waters, sediments, and organisms of the Swan Lake area of Galveston Bay  

E-Print Network [OSTI]

facility (Gulf Coast Waste Disposal Authority) is located north of the Wah Chang Ditch. Consequently there have been concerns about possible metal contamination in this area. I determined trace metal concentrations in water, sediments, and organisms (oyster...

Park, Junesoo

1995-01-01T23:59:59.000Z

92

Radioactively Contaminated Scrap Metal An International Approach to Monitoring, Interception & Managing  

E-Print Network [OSTI]

Customs Organization (WCO) · Scrap processing consultant · International Atomic Energy Agency (IAEARadioactively Contaminated Scrap Metal An International Approach to Monitoring, Interception of monitoring requirements and procedures Standardization of monitoring of scrap metal and response to alarms

93

Mobility of Source Zone Heavy Metals and Radionuclides: The Mixed Roles of Fermentative Activity on Fate and Transport of U and Cr. Final Report  

SciTech Connect (OSTI)

Various U. S. Department of Energy (DOE) low and medium-level radioactive waste sites contain mixtures of heavy metals, radionuclides and assorted organic materials. In addition, there are numerous sites around the world that are contaminated with a mixture of organic and inorganic contaminants. In most sites, over time, water infiltrates the wastes, and releases metals, radionuclides and other contaminants causing transport into the surrounding environment. We investigated the role of fermentative microorganisms in such sites that may control metal, radionuclide and organics migration from source zones. The project was initiated based on the following overarching hypothesis: Metals, radionuclides and other contaminants can be mobilized by infiltration of water into waste storage sites. Microbial communities of lignocellulose degrading and fermenting microorganisms present in the subsurface of contaminated DOE sites can significantly impact migration by directly reducing and immobilizing metals and radionuclides while degrading complex organic matter to low molecular weight organic compounds. These low molecular weight organic acids and alcohols can increase metal and radionuclide mobility by chelation (i.e., certain organic acids) or decrease mobility by stimulating respiratory metal reducing microorganisms. We demonstrated that fermentative organisms capable of affecting the fate of Cr6+, U6+ and trinitrotoluene can be isolated from organic-rich low level waste sites as well as from less organic rich subsurface environments. The mechanisms, pathways and extent of contaminant transformation depend on a variety of factors related to the type of organisms present, the aqueous chemistry as well as the geochemistry and mineralogy. This work provides observations and quantitative data across multiple scales that identify and predict the coupled effects of fermentative carbon and electron flow on the transport of radionuclides, heavy metals and organic contaminants in the subsurface; a primary concern of the DOE Environmental Remediation Science Division (ERSD) and Subsurface Geochemical Research (SBR) Program.

Gerlach, Robin [Montana State Univ., Bozeman, MT (United States); Peyton, Brent M. [Montana State Univ., Bozeman, MT (United States); Apel, William A. [Idaho National Lab., Idaho Falls, ID (United States)

2014-01-29T23:59:59.000Z

94

High-Performance, Superparamagnetic, Nanoparticle-Based Heavy...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

various surface chemistries that demonstrate an excellent affinity for the separation of heavy metals in contaminated water systems (i.e. spiked Columbia river water). The...

95

E-Print Network 3.0 - assess heavy metals Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Submitted to Summary: and organic pollutants that include heavy metals, PAHs, PCBs, dioxins, and furans that have deleterious... environmental effects. For example, sediment...

96

Practical Materials for Heavy Metal Ion Chelation: PolyethylenimPractical Materials for Heavy Metal Ion Chelation: Polyethyleniminesines tailored onto The Surface oftailored onto The Surface of Porous SilicaPorous Silica  

E-Print Network [OSTI]

Practical Materials for Heavy Metal Ion Chelation: PolyethylenimPractical Materials for Heavy Metal *presenting author INTRODUCTION As a result of heavy metal ion release from industrial wastewater, water pollution has become a serious problem. Waste streams contain solutions of metal ions, such as copper

Taralp, Alpay

97

Manganese Doping of Magnetic Iron Oxide Nanoparticles: Tailoring Surface Reactivity for a Regenerable Heavy Metal Sorbent  

SciTech Connect (OSTI)

A method for tuning the analyte affinity of magnetic, inorganic nanostructured sorbents for heavy metal contaminants is described. The manganese-doped iron oxide nanoparticle sorbents have a remarkably high affinity compared to the precursor material. Sorbent affinity can be tuned toward an analyte of interest simply by adjustment of the dopant quantity. The results show that following the Mn doping process there is a large increase in affinity and capacity for heavy metals (i.e., Co, Ni, Zn, As, Ag, Cd, Hg, and Tl). Capacity measurements were carried out for the removal of cadmium from river water and showed significantly higher loading than the relevant commercial sorbents tested for comparison. The reduction in Cd concentration from 100 ppb spiked river water to 1 ppb (less than the EPA drinking water limit of 5 ppb for Cd) was achieved following treatment with the Mn-doped iron oxide nanoparticles. The Mn-doped iron oxide nanoparticles were able to load 1 ppm of Cd followed by complete stripping and recovery of the Cd with a mild acid wash. The Cd loading and stripping is shown to be consistent through multiple cycles with no loss of sorbent performance.

Warner, Cynthia L.; Chouyyok, Wilaiwan; Mackie, Katherine E.; Neiner, Doinita; Saraf, Laxmikant; Droubay, Timothy C.; Warner, Marvin G.; Addleman, Raymond S.

2012-02-28T23:59:59.000Z

98

Studies on the content of heavy metals in Aries River using ICP-MS  

SciTech Connect (OSTI)

Among the industrial branches, the mining industry has always been an important source of environmental pollution, both aesthetically and chemically. Through this paper results of ICP-MS characterization of Aries River Basin are reported. Mining activities from this area has resulted in contamination of environment and its surrounding biota. This is clearly evidenced in analyzed water samples, especially from Baia de Aries site where increased amount of trace elements as Cr, Zn, As, Se, Cd, Pb and U were founded. Also in this site greater amount of rare earth elements was evidenced also. Through monitoring of Aries River from other non-mining area it was observed that the quantitative content of heavy metals was below the maximum permissible levels which made us to conclude that the water table wasn't seriously affected (which possibly might be attributed to the cessation of mining activities in this area from a few years ago)

Voica, Cezara, E-mail: Cezara.Voica@itim-cj.ro; Kovacs, Melinda, E-mail: Cezara.Voica@itim-cj.ro; Feher, Ioana, E-mail: Cezara.Voica@itim-cj.ro [National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103 Donath Str., 400293 Cluj-Napoca (Romania)] [National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103 Donath Str., 400293 Cluj-Napoca (Romania)

2013-11-13T23:59:59.000Z

99

Trends in heavy metal concentrations in the Western and Central Baltic Sea waters detected by using  

E-Print Network [OSTI]

Trends in heavy metal concentrations in the Western and Central Baltic Sea waters detected by using 2003; accepted 10 October 2003 Abstract Heavy metal concentrations from annual sampling in the period water, negative trends appear in cadmium SPM, lead SPM, and zinc SPM. However, positive trends can

Dippner, Joachim W.

100

Distribution of water extractable heavy metals (Cd, Co, Mn and Mo) in the topsoil of Osijek-Baranja County (Eastern Croatia)  

E-Print Network [OSTI]

of soil pH, DOC and water extractable heavy metals, for soilthe area regarding the water extractable heavy metals and toand discussion Water extraction of four heavy metals (Cd,

Ivezic, Vladimir; Alms, sgeir R.; Loncaric, Zdenko; Singh, Bal Ram

2009-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "heavy metal contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Uranium and other heavy metals in the plant-animal-human food chain near abandoned mining sites and structures in an American Indian community in northwestern New Mexico  

E-Print Network [OSTI]

Sheep1 For Sheep 1, heavy metal water toxicity levels weretwo mines. The sheep heavy metal water toxicity levels wereU & other Heavy Metals (HMs) in soil and water Interpersonal

Samuel-Nakamura, Christine

2013-01-01T23:59:59.000Z

102

Uranium and other heavy metals in the plant-animal-human food chain near abandoned mining sites and structures in an American Indian community in northwestern New Mexico  

E-Print Network [OSTI]

agent (U and other heavy metal toxicants). The environmentM=6.59, SD=3.87). The heavy metal toxicity levels for sheepFor Sheep 1, heavy metal water toxicity levels were not

Samuel-Nakamura, Christine

2013-01-01T23:59:59.000Z

103

Placental concentrations of heavy metals in a mother-child cohort  

SciTech Connect (OSTI)

Heavy metals are environmental contaminants with properties known to be toxic for wildlife and humans. Despite strong concerns about their harmful effects, little information is available on intrauterine exposure in humans. The aim of this study was to evaluate prenatal exposure to As, Cd, Cr, Hg, Mn, and Pb and its association with maternal factors in a population-based mother-child cohort in Southern Spain. Between 2000 and 2002, 700 pregnant women were recruited and 137 placentas from the cohort were randomly selected and analyzed for the selected metals by atomic absorption. Maternal sociodemographic and lifestyle factors were obtained by questionnaire after delivery. Bivariate analysis and multivariate linear regression were performed. Cd and Mn concentrations were detected in all placentas, while Cr, Pb, and Hg were found in 98.5%, 35.0%, and 30.7% of samples, respectively. The highest concentrations were observed for Pb (mean: 94.80 ng/g wet weight of placenta), followed by Mn (63.80 ng/g), Cr (63.70 ng/g), Cd (3.45 ng/g), and Hg (0.024 ng/g). Arsenic was not detected in any sample. Gestational age and smoking during pregnancy were associated with placental Cd concentrations, while no factor appeared to influence concentrations of Cr, Hg, Mn, or Pb. In comparison to results of European studies, these concentrations are in a low-intermediate position. Studies are required to investigate the factors contributing to early exposure to heavy metals and to determine how placental transfer of these toxic compounds may affect children's health.

Amaya, E., E-mail: eamayag@ugr.es [Laboratory of Medical Investigations, San Cecilio University Hospital, University of Granada, 18071 Granada (Spain); Gil, F. [Department of Legal Medicine, Toxicology and Physic Anthropology, Faculty of Medicine, University of Granada, 18071 Granada (Spain)] [Department of Legal Medicine, Toxicology and Physic Anthropology, Faculty of Medicine, University of Granada, 18071 Granada (Spain); Freire, C. [Laboratory of Medical Investigations, San Cecilio University Hospital, University of Granada, 18071 Granada (Spain) [Laboratory of Medical Investigations, San Cecilio University Hospital, University of Granada, 18071 Granada (Spain); National School of Public Health, Oswaldo Cruz Foundation (FIOCRUZ), 21041-210 Rio de Janeiro (Brazil); Olmedo, P. [Department of Legal Medicine, Toxicology and Physic Anthropology, Faculty of Medicine, University of Granada, 18071 Granada (Spain)] [Department of Legal Medicine, Toxicology and Physic Anthropology, Faculty of Medicine, University of Granada, 18071 Granada (Spain); Fernandez-Rodriguez, M. [Laboratory of Medical Investigations, San Cecilio University Hospital, University of Granada, 18071 Granada (Spain)] [Laboratory of Medical Investigations, San Cecilio University Hospital, University of Granada, 18071 Granada (Spain); Fernandez, M.F.; Olea, N. [Laboratory of Medical Investigations, San Cecilio University Hospital, University of Granada, 18071 Granada (Spain) [Laboratory of Medical Investigations, San Cecilio University Hospital, University of Granada, 18071 Granada (Spain); CIBER de Epidemiologia y Salud Publica (CIBERESP) (Spain)

2013-01-15T23:59:59.000Z

104

The effects of metal and nutrient addition on Ribbed Mussels, Geukensia demissa, in the Great Sippewissett Salt Marsh and Eel Pond  

E-Print Network [OSTI]

the potential effects of nutrient loading and heavy metal pollution on salt marshes, researchers established highly contaminated with heavy metals. Nutrient additions did not promote or deter the health of mussels Marsh plots, perhaps a result of metal contamination. Keywords Salt marsh, nutrients, heavy metals

Vallino, Joseph J.

105

A study of immobilization of four heavy metals by solidification/stabilization with portland cement  

E-Print Network [OSTI]

A STUDY OF IMMOBILIZATION OF FOUR HEAUY METALS BY SOLIDIFICATION/STABILIZATION WITH PORTLAND CEMEhK A Thesis by SUSAN ANN TRUSSELL Submitted to Texas AdcM University in partial fulfillment of the requirements for the degree of MASTER... of Immobilization of Four Heavy Metals By Solidification/Stabilization with Portland Cement. (May 1994) Susan Trussell, B. S. , Baylor University; M. A. , Texas ARM University Chair of Advisory Committee: Dr. Bill Batchelor Immobilization of four heavy metals...

Trussell, Susan A

1994-01-01T23:59:59.000Z

106

1. Coastal waters are often exposed to heavy metals (HM) introduced from point and diffusive sources. Chronic and  

E-Print Network [OSTI]

1. Coastal waters are often exposed to heavy metals (HM) introduced from point and diffusive higher than in sea water. Heavy metals concentration in seawater 4. Most of the dissolved heavy metals sources. Chronic and acute environmental criteria for water quality were developed (e.g. EPA) based

Einat, Aharonov

107

Environmental Pollution (Series B) 9 (1985) 239-254 Heavy Metals in Isopods from the Supra-littoral Zone  

E-Print Network [OSTI]

Environmental Pollution (Series B) 9 (1985) 239-254 Heavy Metals in Isopods from the Supra were very small. The hepatopancreas was the most important storage organ oj'heavy metals and, at all of heavy metals were compared in the tissues oiL. oceanica and in two 'more terrestrial' isopods, Oniscus

Hopkin, Steve

108

CHANGING THE LANDSCAPE--LOW-TECH SOLUTIONS TO THE PADUCAH SCRAP METAL REMOVAL PROJECT ARE PROVIDING SAFE, COST-EFFECTIVE REMEDIATION OF CONTAMINATED SCRAP YARDS  

SciTech Connect (OSTI)

Between 1974 and 1983, contaminated equipment was removed from the Paducah Gaseous Diffusion Plant (PGDP) process buildings as part of an enrichment process upgrade program. The upgrades consisted of the dismantlement, removal, and on-site storage of contaminated equipment, cell components, and scrap material (e.g., metal) from the cascade facilities. Scrap metal including other materials (e.g., drums, obsolete equipment) not related to this upgrade program have thus far accumulated in nine contiguous radiologically-contaminated and non-contaminated scrap yards covering 1.05E5 m2 (26 acres) located in the northwestern portion of the PGDP. This paper presents the sequencing of field operations and methods used to achieve the safe removal and disposition of over 47,000 tonnes (53,000 tons) of metal and miscellaneous items contained in these yards. The methods of accomplishment consist of mobilization, performing nuclear criticality safety evaluations, moving scrap metal to ground level, inspection and segregation, sampling and characterization, scrap metal sizing, packaging and disposal, and finally demobilization. Preventing the intermingling of characteristically hazardous and non-hazardous wastes promotes waste minimization, allowing for the metal and materials to be segregated into 13 separate waste streams. Low-tech solutions such as using heavy equipment to retrieve, size, and package scrap materials in conjunction with thorough planning that integrates safe work practices, commitment to teamwork, and incorporating lessons learned ensures that field operations will be conducted efficiently and safely.

Watson, Dan; Eyman, Jeff

2003-02-27T23:59:59.000Z

109

Heavy Metal Tolerance in Stenotrophomonas maltophilia Delphine Pages1,2,3  

E-Print Network [OSTI]

Heavy Metal Tolerance in Stenotrophomonas maltophilia Delphine Pages1,2,3 , Jerome Rose4 , Sandrine, this bacterium tolerates high levels (0.1 to 50 mM) of various toxic metals, such as Cd, Pb, Co, Zn, Hg, Ag mechanisms to overcome metal toxicity, reduction of oxyanions to non-toxic elemental ions and detoxification

Paris-Sud XI, Université de

110

Determining the Heavy Metal Pollution in Mascara (Algeria) by Using Casuarina equisetifolia  

E-Print Network [OSTI]

Abstract. In this study, Casuarina equisetifolia needles were evaluated as the possible biomonitors of heavy metal air pollution in Mascara (Algeria). The needles were sampled from seven locations with different degrees of metal pollution (near roads) and from a control site. The concentrations of lead, zinc, copper and nickel were measured by using a flame atomic absorption spectrophotometer. The maximal values of these four metals were found in the samples collected near the roads and the minimal values were found in the control site. Furthermore, sites with high traffic density and frequency of cars stoppage showed high heavy metal concentrations. However, the comparison of concentrations of all metals showed that the zinc one had the highest concentration of all. The cluster analysis divided the selected sampling sites in three distinct clusters. With regard to the results of this study, Casuarina equisetifolia can be successfully applied in biomonitoring of air pollution. Key words: Casuarina equisetifolia, Mascara, biomonitors, pollution, heavy metals.

Lakhdari Aissa; Benabdeli Kloufi

111

E-Print Network 3.0 - aquatic heavy metals Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Principles of Ecotoxicology, SCOPE Report 12, Chapter 11, pp 239-255. Heavy metals, Pollutants, Toxicity... fIJJ US Army Corps of Engineers AQUATIC PLANT CONTROL RESEARCH PROGRAM...

112

Silica coated magnetite nanoparticles for removal of heavy metal ions from polluted waters  

E-Print Network [OSTI]

Magnetic removal of Hg2+ and other heavy metal ions like Cd2+, Pb2+ etc. using silica coated magnetite particles from polluted waters is a current topic of active research to provide efficient water recycling and long term high quality water. The technique used to study the bonding characteristics of such kind of nanoparticles with the heavy metal ions is a very sensitive hyperfine specroscopy technique called the perturbed angular correlation technique (PAC).

Dash, Monika

2013-01-01T23:59:59.000Z

113

The role of mycorrhizal fungi in the uptake of heavy metals by Salix. A preproposal for the McIntire-Stennis Research Program  

E-Print Network [OSTI]

, either to protect the willow against heavy metal toxicity, or to sequester the heavy metals fromThe role of mycorrhizal fungi in the uptake of heavy metals by Salix. A preproposal for the Mc fungi produce bioactive peptides (e.g. siderophores or phytochelatins) in response to heavy metal stress

Chatterjee, Avik P.

114

TO THE 1979 CONVENTION ON LONG-RANGE TRANSBOUNDARY AIR POLLUTION ON HEAVY METALS The Parties,  

E-Print Network [OSTI]

Determined to implement the Convention on Long-range Transboundary Air Pollution, Concerned that emissions of certain heavy metals are transported across national boundaries and may cause damage to ecosystems of environmental and economic importance and may have harmful effects on human health, Considering that combustion and industrial processes are the predominant anthropogenic sources of emissions of heavy metals into the atmosphere, Acknowledging that heavy metals are natural constituents of the Earth's crust and that many heavy metals in certain forms and appropriate concentrations are essential to life, Taking into consideration existing scientific and technical data on the emissions, geochemical processes, atmospheric transport and effects on human health and the environment of heavy metals, as well as on abatement techniques and costs, Aware that techniques and management practices are available to reduce air pollution caused by the emissions of heavy metals, Recognizing that countries in the region of the United Nations Economic Commission for Europe (UNECE) have different economic conditions, and that in certain countries the economies are in transition,

unknown authors

115

High Pressure Phase Transformations in Heavy Rare Earth Metals and Connections to Actinide Crystal Structures  

SciTech Connect (OSTI)

High-pressure studies have been performed on heavy rare earth metals Terbium (Tb) to 155 GPa and Holmium (Ho) to 134 GPa in a diamond anvil cell at room temperature. The following crystal structure sequence was observed in both metals hcp {yields} Sm-type {yields} dhcp {yields} distorted fcc (hR-24) {yields} monoclinic (C2/m) with increasing pressure. The last transformation to a low symmetry monoclinic phase is accompanied by a volume collapse of 5 % for Tb at 51 GPa and a volume collapse of 3 % for Ho at 103 GPa. This volume collapse under high pressure is reminiscent of f-shell delocalization in light rare earth metal Cerium (Ce), Praseodymium (Pr), and heavy actinide metals Americium (Am) and Curium (Cm). The orthorhombic Pnma phase that has been reported in Am and Cm after f-shell delocalization is not observed in heavy rare earth metals under high pressures. (authors)

Vohra, Yogesh K.; Sangala, Bagvanth Reddy; Stemshorn, Andrew K. [Physics, University of Alabama at Birmingham (UAB), 310 Campbell Hall, 1300 University Boulevard, Birmingham, AL, 35294-1170 (United States); Hope, Kevin M. [Biology, Chemistry, and Mathematics, University of Montevallo, Harman Hall, Station 6480, Montevallo, AL, 35115 (United States)

2008-07-01T23:59:59.000Z

116

Comparative evaluation of several small mammal species as monitors of heavy metals, radionuclides, and selected organic compounds in the environment  

SciTech Connect (OSTI)

The primary purpose of this study was to evaluate which small mammal species are the best monitors of specific environmental contaminants. The evaluation is based on the published literature and on an analysis of small mammals trapped at several sites on the Oak Ridge National Laboratory (ORNL) Reservation in Oak Ridge, Tennessee. Studies on the uptake of heavy metals, radionuclides, and organic chemicals are reviewed in Chapter II to evaluate several small mammal species for their capacity to serve as sentinels for the presence, accumulation, and effects of various contaminants. Where several species were present at a site, a comparative evaluation was made and species are ranked for their capacity to serve as monitors of specific contaminants. Food chain accumulation and food habits of the species are used to establish a relationship with suitability as a biomonitor. Tissue-specific concentration factors were noted in order to establish target tissues. Life histories, habitat, and food habits are reviewed in order to make generalizations concerning the ability of similar taxa to serve as biomonitor. Finally, the usefulness of several small mammal species as monitors of three contaminants -- benzo(a)pyrene, mercury, and strontium-90 -- present on or near the ORNL facilities was investigated. 133 refs., 5 figs., 20 tabs.

Talmage, S.S. (Tennessee Univ., Knoxville, TN (USA) Oak Ridge National Lab., TN (USA)); Walton, B.T. (Oak Ridge National Lab., TN (USA))

1990-08-01T23:59:59.000Z

117

DOWN-STREAM SPATIAL DISTRIBUTION OF ANTIBIOTIC RESISTANCE TRAITS ALONG METAL CONTAMINATED STREAM REACHES  

SciTech Connect (OSTI)

Sediment bacteria samples were collected from three streams in South Carolina, two contaminated with multiple metals (Four Mile Creek and Castor Creek), one uncontaminated (Meyers Branch), and another metal contaminated stream (Lampert Creek) in northern Washington State. Growth plates inoculated with Four Mile Creek sample extracts show bacteria colony growth after incubation on plates containing either one of two aminoglycosides (kanamycin or streptomycin), tetracycline or chloramphenocol. This study analyzes the spatial pattern of antibiotic resistance in culturable sediment bacteria in all four streams that may be due to metal contamination. We summarize the two aminoglycoside resistance measures and the 10 metals concentrations by Principal Components Analysis. Respectively, 63% and 58% of the variability was explained in the 1st principal component of each variable set. We used the respective multivariate summary metrics (i.e. 1st principal component scores) as input measures for exploring the spatial correlation between antibiotic resistance and metal concentration for each stream reach sampled. Results show a significant and negative correlation between metals scores versus aminoglycoside resistance scores and suggest that selection for metal tolerance among sediment bacteria may influence selection for antibiotic resistance differently than previously supposed.. In addition, we borrow a method from geostatistics (variography) wherein a spatial cross-correlation analysis shows that decreasing metal concentrations scores are associated with increasing aminoglycoside resistance scores as the separation distance between sediment samples decreases, but for contaminated streams only. Since these results were counter to our initial expectation and to other experimental evidence for water column bacteria, we suspect our field results are influenced by metal bioavailability in the sediments and by a contaminant promoted interaction or ''cocktail effect'' from complex combinations of pollution mediated selection agents.

Tuckfield, C; J V Mcarthur (NOEMAIL), J

2007-04-16T23:59:59.000Z

118

Heavy metal balances of an Italian soil as affected by sewage sludge and Bordeaux mixture applications  

SciTech Connect (OSTI)

Applications of sewage sludge and Bordeaux mixture (Bm) (a mixture of copper sulfate and lime) add heavy metals to the soil. At an experimental farm in the Cremona district (Italy), the authors measured current heavy metal contents in soil and their removal via harvested products. They also measured heavy metal adsorption by soil from this farm. With these data, projections were made of the long-term development of heavy metal (Cd, Cu, and Zn) contents in soil, crop removal, and leaching at different application rates of sewage sludge and Bm. These projections were compared with existing quality standards of the European Union (EU) and Italy with regard to soil and groundwater. The calculations reveal that the permitted annual application rates of sewage sludge and Bm are likely to result in exceedance of groundwater and soil standards. Sewage sludge applications, complying with the Italian legal limits, may pose problems for Cd, Cu, and Zn within 30, 70, and 100 yr, respectively. Furthermore, severe Cu pollution of integrated and especially organic (Bm only) vineyards is unavoidable with the currently allowed application rates of Bm. The results suggest that the current Italian soil protection policy as well as the EU policy are not conducive of a sustainable heavy metal management in agroecosystems.

Moolenaar, S.W. [Wageningen Agricultural Univ. (Netherlands); Beltrami, P. [Univ. Cattolica del Sacro Cuore, Piacenza (Italy)

1998-07-01T23:59:59.000Z

119

A review of the global emissions, transport and effects of heavy metals in the environment  

SciTech Connect (OSTI)

The purpose of this report is to describe the current state of knowledge regarding the sources and quantities of heavy metal emissions, their transport and fate, their potential health and environmental effects, and strategies to control them. The approach is to review the literature on this topic and to consult with experts in the field. Ongoing research activities and research needs are discussed. Estimates of global anthropogenic and natural emissions indicate that anthropogenic emissions are responsible for most of the heavy metals released into the atmosphere and that industrial activities have had a significant impact on the global cycling of trace metals. The largest anthropogenic sources of trace metals are coal combustion and the nonferrous metal industry. Atmospheric deposition is an important pathway by which trace metals enter the environment. Atmospheric deposition varies according to the solubility of the element and the length of time it resides in the atmosphere. Evidence suggests that deposition is influenced by other chemicals in the atmosphere, such as ozone and sulfur dioxide. Trace metals also enter the environment through leaching. Existing emissions-control technologies such as electrostatic precipitators, baghouses, and scrubbers are designed to remove other particulates from the flue gas of coal-fired power plants and are only partially effective at removing heavy metals. Emerging technologies such as flue gas desulfurization, lignite coke, and fluidized bed combustion could further reduce emissions. 108 refs.

Friedman, J.R.; Ashton, W.B.; Rapoport, R.D.

1993-06-01T23:59:59.000Z

120

Relationship between meteorological variables and total suspended and heavy metal particulates in Little Rock, Arkansas  

E-Print Network [OSTI]

RELATIONSHIP BETWEEN METEOROLOGICAL VARIABLES AND TOTAL SUSPENDED AND HEAVY NFXAL PARTICULATES IN LITTLE ROCK, ARKANSAS A Thesis MARY GWENDOLl'N AVERY Submitted to the Graduate College of Texas ALM University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE May 1985 Major Subject: Meteorology RELATIONSHIP BETWEEN METEOROLOGICAL VARIABLES AND TOTAL SUSPENDED AND HEAVY METAL PARTICULATES IN LITTLE ROCK, ARKANSAS A Thesis MARY GWENDOLYN AVERY Approved...

Avery, Mary Gwendolyn

1985-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "heavy metal contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

SEPARATION OF HEAVY METALS: REMOVAL FROM INDUSTRIAL WASTEWATERS  

Office of Scientific and Technical Information (OSTI)

a two- or three-stage operation to remove the metals and 0il sepcrately). ComplexationSequestration Complexation involves the formation of a complex or chelating agent....

122

The Fate of Heavy Metals in Highway Stormwater Runoff: The Characterization of a Bioretention Basin in the Midwest  

E-Print Network [OSTI]

The usual wear of automobiles and road surfaces deposits numerous environmental pollutants on roadways and parking lots, including heavy metals such as copper, zinc, lead, nickel and cadmium. During rainfall and snow events, these metals are washed...

Lacy, Sarah

2009-01-01T23:59:59.000Z

123

Studies Concerning the Accumulation of Minerals and Heavy Metals in Fruiting Bodies of Wild Mushrooms  

SciTech Connect (OSTI)

The minerals and heavy metals play an important role in the metabolic processes, during the growth and development of mushrooms, when they are available in appreciable concentration. In this work the concentrations of Cr, Mn, Fe, Ni, Cu, Zn, Se, Cd and Pb were analyzed using the Flame Atomic Absorption spectrometry (FAAS) together with Energy Dispersive X-ray Fluorescence spectrometry (EDXRF) in 3 wild mushrooms species and their growing substrate, collected from various forestry fields in Dambovita County, Romania. The analyzed mushrooms were: Amanita phalloides, Amanita rubescens and Armillariella mellea. The accumulation coefficients were calculated to assess the mobility of minerals and heavy metals from substrate to mushrooms [1].

Stihi, Claudia; Radulescu, Cristiana [Valahia University of Targoviste, Faculty of Sciences and Arts, Sciences Department, Unirii street, 130082, Targoviste (Romania); Gheboianu, Anca; Bancuta, Iulian [Valahia University of Targoviste, Multidisciplinary Research Institute for Sciences and Technologies, Unirii street, 130082, Targoviste (Romania); Popescu, Ion V. [Valahia University of Targoviste, Faculty of Sciences and Arts, Sciences Department, Unirii street, 130082, Targoviste (Romania); Valahia University of Targoviste, Multidisciplinary Research Institute for Sciences and Technologies, Unirii street, 130082, Targoviste (Romania); Academy of Romanian Scientist, Bucharest (Romania); Busuioc, Gabriela [Valahia University of Targoviste, Faculty of Environmental Engineering and Biotechnologies, Environmental Engineering Department, Unirii street, 130082, Targoviste (Romania)

2011-10-03T23:59:59.000Z

124

Dissolved metal contamination in the East RiverLong Island sound system: potential biological effects  

E-Print Network [OSTI]

in the United States. The ERWLIS region receives treated sewage from 18 wastewater treatment plants in New YorkDissolved metal contamination in the East RiverLong Island sound system: potential biological sewage, and to assess its possible biological impact on local waters. The East RiverLong Island Sound

Johnsen, Snke

125

Pesticide and heavy metal residues in Louisiana river otter  

E-Print Network [OSTI]

of Hg pollution, and hypothesized that Hg was an important cause of the species' decline in Sweden since 1950. There has been no comparable work in North America, but two studies have provided information on tissue levels of contaminants in otter...

Beck, Debra Lynn

1977-01-01T23:59:59.000Z

126

HEAVY METAL POLLUTION IN A TROPICAL LAGOON CHILIKA LAKE, ORISSA, INDIA 1  

E-Print Network [OSTI]

Chilika lake, the largest costal lagoon of Asia is one of the most dynamic ecosystems along the Indian coast. The lagoon has undergone a considerable reduction in surface area due to input from natural process and human activities. The purpose of this investigation is to document the heavy metal concentration in sediment, surface water and possible entry to food chain. Concentration of all elements increase in the sediments in comparison to surface water. Metal ions are in the following order Mn> Mg> Ni> Cu>Zn> Cu> Pb> Cr. In the sediments heavy metals like Pb, Cd, Mn, Ni, Zn, Co are present in surface water and Mg was below detection limits. Metal concentrations in the sediment indicate an increase in the pollution load due to movement of fertilizers, agricultural water, prawn cultivation and Motor Boat operations. An immediate attention from the concerned authorities is required in order to protect the lake from further pollution.

Sagarika Nayak; Gayatri Nahak; Debyani Samantray; Rajani Kanta Sahu

127

Chemistry of Metal Contaminants in Water Project at NERSC  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to User Group and Userof a blast-resistantChemistry andChemistry of Metal

128

AMOUNT AND LEACHING POTENTIAL OF HEAVY METALS IN BARK MULCH AND COMPOST USED ON THE UNIVERSITY OF  

E-Print Network [OSTI]

AMOUNT AND LEACHING POTENTIAL OF HEAVY METALS IN BARK MULCH AND COMPOST USED ON THE UNIVERSITY mulch and compost, determine whether or not either of these substances could be significant contributors the presence of heavy metals in fresh bark mulch, soil (used in compost mixtures) and compost being used at UBC

129

Analysis of disposition alternatives for radioactively contaminated scrap metal  

SciTech Connect (OSTI)

Millions of tonnes of slightly radioactive, scrap iron and steel, stainless steel, and copper are likely to become available as nuclear and other facilities and equipment are withdrawn from service. Disposition of this material is an international policy issue under consideration currently. The major alternatives for managing this material are to either develop a regulatory process for decontamination and recycling that will safeguard human health or to dispose of the scrap and replace the metal stocks. To evaluate the alternatives, we estimate quantities of scrap arising from nuclear power plant decommissioning, evaluate potential price impacts of recycling on regional markets, and assess the health and environmental impacts of the management alternatives. We conclude that decontaminating and recycling the scrap is the superior alternative.

Nieves, L.A.; Chen, S.Y.; Kohout, E.J.; Nabelssi, B.; Tilbrook, R.W.; Wilson, S.E.

1997-01-01T23:59:59.000Z

130

Heavy Element Abundances in Presolar Silicon Carbide Grains from Low-Metallicity AGB Stars  

E-Print Network [OSTI]

Heavy Element Abundances in Presolar Silicon Carbide Grains from Low-Metallicity AGB Stars Peter explosions. Silicon carbide is the best studied presolar mineral. Based on its isotopic compositions the identified presolar minerals are diamond, silicon carbide (SiC), graphite, silicon nitride (Si3N4), corundum

131

Characterization of sperm motility in sea bass: the effect of heavy metals and physicochemical  

E-Print Network [OSTI]

to sperm motility in several fish species, including sea bass Dicentrarchus labrax (L.) (Fauvel et alCharacterization of sperm motility in sea bass: the effect of heavy metals and physicochemical) was used to characterize the motility of sea bass Dicentrarchus labrax spermatozoa and to study the effect

Villefranche sur mer

132

Declining metal levels at Foundry Cove (Hudson River, New York): Response to localized dredging of contaminated sediments  

E-Print Network [OSTI]

a well-recognized case of heavy metal pollution at Foundry Cove (FC), Hudson River, New York. This tidal River. ? 2007 Elsevier Ltd. All rights reserved. Keywords: River pollution; Cadmium; Metal removalDeclining metal levels at Foundry Cove (Hudson River, New York): Response to localized dredging

Levinton, Jeffrey

133

Micellar enhanced ultrafiltration of heavy metals using lecithin  

E-Print Network [OSTI]

, zinc, silver, copper, and mercury are reported to be above 98%. Chaufer and Deratiani presented complexation-ultrafiltration as a means of removing metal ions with water soluble macromolecules (13). Polymers which are known to bind to metals... from each of the seven characteristic wastewaters and the average percentage of plants that generate such wastes. Table 4. Wastewater Distribution (2). Percentage of plants ihthi wa ew t 100. 0 6. 3 n/a 24. 1 13. 9 12. 9 n/a Percentage...

Ahmadi, Saman Nameghi

1992-01-01T23:59:59.000Z

134

Metal impacts on microbial biomass in the anoxic sediments of a contaminated lake  

SciTech Connect (OSTI)

Little is known about the long-term impacts of metal contamination on the microbiota of anoxic lake sediments. In this study, we examined microbial biomass and metals (arsenic, cadmium, chromium, copper, iron, lead, manganese, and zinc) in the sediments of Lake DePue, a backwater lake located near a former zinc smelter. Sediment core samples were examined using two independent measures for microbial biomass (total microscopic counts and total phospholipid-phosphate concentrations), and for various fractions of each metal (pore water extracts, sequential extractions, and total extracts of all studied metals and zinc speciation by X-ray absorption fine structure (XAFS). Zinc concentrations were up to 1000 times higher than reported for sediments in the adjacent Illinois River, and ranged from 21,400 mg/kg near the source to 1,680 mg/kg near the river. However, solid metal fractions were not well correlated with pore water concentrations, and were not good predictors of biomass concentrations. Instead, biomass, which varied among sites by as much as two-times, was inversely correlated with concentrations of pore water zinc and arsenic as established by multiple linear regression. Monitoring of other parameters known to naturally influence biomass in sediments (e.g., organic carbon concentrations, nitrogen concentrations, pH, sediment texture, and macrophytes) revealed no differences that could explain observed biomass trends. This study provides strong support for control of microbial abundance by pore water metal concentrations in contaminated freshwater sediments.

Gough, Heidi L.; Dahl, Amy L.; Nolan, Melissa A.; Gaillard, Jean-Francois; Stahl, David A.

2008-04-26T23:59:59.000Z

135

Zn Speciation in the Organic Horizon of a Contaminated Soil by  

E-Print Network [OSTI]

, MS 6-2100, Berkeley, California 94720 Soils that have been acutely contaminated by heavy metals show to metal toxicity (5). Similar organic layers have been reported in many other contaminated sites (6 distinct characteristics, such as colonization by metal-tolerant plant species and topsoil enrichment

136

Heavy metals emission from controlled combustion of PVC  

E-Print Network [OSTI]

, oil, and household product containers (4). The r easons for its enormous versatility and range of application, besides its relatively low cost, derive from a combination of its basic structure which gives rise to a relatively tough and rigid... salts, and later on, inorganic lead salt derivatives were used as organometallic stabilizers. Organometallic stabilizers gained wide spread popularity in rigid and plasticized PVC applications. In the early 1950's, alkaline earth metal salts were...

El-Ayyoubi, Mohammed A.

1989-01-01T23:59:59.000Z

137

DECHEM: A remedial planning tool for metallic contaminants in soil at UMTRA Project sites  

SciTech Connect (OSTI)

The DECHEM (DEcontamination of CHEMicals) method was developed for the Uranium Mill Tailings Remedial Action (UMTRA) Project to guide characterization and remedial planning for metals contamination in soils. This is necessary because non-radiological hazardous constituents may be more mobile than radium-226 (Ra-226), and hence may migrate more deeply into subpile soils (beneath tailings that are to be relocated) or into adjacent contaminated soils at UMTRA Project sites. The result is that remedial action to the Ra-226 excavation limit, as specified in the US Environmental Protection Agency (EPA) standards, may not adequately remove hazardous non-radiological contamination. Unmitigated, these contaminants in soil may cause health risks because of their presence in resuspended particles, their uptake by crops or fodder their seepage into aquifers used for drinking water or other possible exposure pathways. The DECHEM method was developed in response to the need for advanced planning for the remediation of chemical contaminants at UMTRA Project sites, and includes the following elements: Establishment of acceptable exposure rates for humans to chemicals, based on EPA guidelines or other toxicological literature. Modeling of chemical migration through environmental pathways from a remediated UMTRA Project site to humans. Determination of allowable residual concentrations (i.e., cleanup guidelines) for chemicals in soils that results in doses to humans that are below established acceptable exposure rates. The initial development and application of the DECHEM method has focused upon hazardous metallic contaminants such as arsenic, lead, molybdenum, and selenium, which are known to occur in elevated concentrations at some UMTRA Project sites.

Not Available

1989-03-01T23:59:59.000Z

138

INL Internship:Modification of Metal Contaminants on Oxide Surfaces Modified by Laser Irradiation  

SciTech Connect (OSTI)

This project focuses on obtaining the optimal laser parameters needed for enhancing metal contaminants on cement, granite, and marble. The various parameters of the laser tested include the fluence, wavelength, and frequency. A chelating study was also performed in order to increase the volatility of cobalt. In the following paper each experiment is described in detail. No results are included in this report because their release is not approved and they could eventually become classified.

Michael J. Hansen; Robert Fox; Les Manner

2006-08-01T23:59:59.000Z

139

Use of wastewater ER sludges for the immobilization of heavy metals  

SciTech Connect (OSTI)

The distribution, mobility, and bioavailability of heavy metals in soils, surface water, and ground water have been of major interest and concern from both environmental and geochemical standpoints. Wastewater sludges represent an important anthropogenic factor whose impact on these processes is not fully understood. In the past, incineration and landfilling were common practices for discarding wastewater sludges. However, as local and state laws governing the disposal of these materials have become more stringent, land application has been used as an alternative. Reported studies have shown that the impact of land application of sludges can vary widely and is influenced by a number of factors, including the source of the sludge; the organic matter content of the sludge; the form in which the sludge is applied; and the prevailing conditions of the receiving soils. It has also been shown that sewage sludge can have solubilizing effects on solid-phase heavy metals, thereby causing geochemical shifts of the insoluble fractions of metals to the more soluble forms. The work presented in this paper utilized synthetic minerals, standard solutions, sludges, and agricultural soils obtained from different sources to determine the mechanisms involved in the mineralization of heavy metals by sludge; the influence of soil conditions; interelemental effects; the influence of natural organic matter; and possible microbial activity that may come into play. Several types of sludge were evaluated for lead binding capacity.

Macha, S.; Murray, D.; Urasa, I.T. [Hampton Univ., VA (United States)

1996-10-01T23:59:59.000Z

140

Identification and validation of heavy metal and radionuclide hyperaccumulating terrestrial plant species. Quarterly technical progress report, March 20, 1997--June 19, 1997  

SciTech Connect (OSTI)

This laboratory has been involved in a collaborative project focusing on a range of issues related to the phytoremediation of heavy metal-and radionuclide- contaminated soils. While much of the research has been fundamental in nature, involving physiological and molecular characterizations of the mechanisms of hyperaccumulation in plants, the laboratory is also investigating more practical issues related to phytoremediation. A central issue in this latter research has been the identification of amendments capable of increasing the bioavailability and subsequent phytoextraction of radionuclides. The results described here detail these efforts for uranium and Cs-137. A study was also conducted on a Cs-137 contaminated site at Brookhaven National Laboratory (BNL), which allowed application of the laboratory and greenhouse results to a field setting.

Kochian, L.

1997-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "heavy metal contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Oxidative stress in pied flycatcher (Ficedula hypoleuca) nestlings from metal contaminated environments in northern Sweden  

SciTech Connect (OSTI)

Metals have been shown to induce oxidative stress in animals. One of the most metal polluted terrestrial environments in Sweden is the surroundings of a sulfide ore smelter plant located in the northern part of the country. Pied flycatcher nestlings (Ficedula hypoleuca) that grew up close to the industry had accumulated amounts of arsenic, cadmium, mercury, lead, iron and zinc in their liver tissue. The aim of this study was to investigate if pied flycatcher nestlings in the pollution gradient of the industry were affected by oxidative stress using antioxidant molecules and enzyme activities. The antioxidant assays were also evaluated in search for useful biomarkers in pied flycatchers. This study indicated that nestlings in metal contaminated areas showed signs of oxidative stress evidenced by up regulated hepatic antioxidant defense given as increased glutathione reductase (GR) and catalase (CAT) activities and slightly but not significantly elevated lipid peroxidation and glutathione-S-transferase (GST) activities. Stepwise linear regression indicated that lipid peroxidation and CAT activities were influenced mostly by iron, but iron and lead influenced the CAT activity to a higher degree. Positive relationships were found between GST and lead as well as GR activities and cadmium. We conclude that GR, CAT, GST activities and lipid peroxidation levels may function as useful biomarkers for oxidative stress in free-living pied flycatcher nestlings exposed to metal contaminated environments.

Berglund, A.M.M. [Department of Ecology and Environmental Science, Umea University, SE-901 87 Umea (Sweden)], E-mail: asa.berglund@emg.umu.se; Sturve, J.; Foerlin, L. [Department of Zoology, Goeteborg University, Box 463, SE-405 30 Gothenburg (Sweden); Nyholm, N.E.I. [Department of Ecology and Environmental Science, Umea University, SE-901 87 Umea (Sweden)

2007-11-15T23:59:59.000Z

142

Metal contamination of soils and crops affected by the Chenzhou lead/zinc mine spill (Hunan, China)  

E-Print Network [OSTI]

Metal contamination of soils and crops affected by the Chenzhou lead/zinc mine spill (Hunan, China Avenue Edouard Belin, 31400 Toulouse, France b Department of Environmental Science, Hunan Agricultural polluted with As, Cd, Zn, Pb and Cu. The contamination levels were in the order of GYBNSZYNJTC showing

Mailhes, Corinne

143

Purification of alkali metal nitrates  

DOE Patents [OSTI]

A process is disclosed for removing heavy metal contaminants from impure alkali metal nitrates containing them. The process comprises mixing the impure nitrates with sufficient water to form a concentrated aqueous solution of the impure nitrates, adjusting the pH of the resulting solution to within the range of between about 2 and about 7, adding sufficient reducing agent to react with heavy metal contaminants within said solution, adjusting the pH of the solution containing reducing agent to effect precipitation of heavy metal impurities and separating the solid impurities from the resulting purified aqueous solution of alkali metal nitrates. The resulting purified solution of alkali metal nitrates may be heated to evaporate water therefrom to produce purified molten alkali metal nitrate suitable for use as a heat transfer medium. If desired, the purified molten form may be granulated and cooled to form discrete solid particles of alkali metal nitrates.

Fiorucci, Louis C. (Hamden, CT); Gregory, Kevin M. (Woodridge, IL)

1985-05-14T23:59:59.000Z

144

Fixation and partitioning of heavy metals in slag after incineration of sewage sludge  

SciTech Connect (OSTI)

Highlights: Black-Right-Pointing-Pointer The contents and partitioning of HMs in slag of sludge incineration were examined. Black-Right-Pointing-Pointer The fixation rate decreases with residential time and finally keeps a constant. Black-Right-Pointing-Pointer Water mass fraction of 55% is optimal for the sediment for Ni, Mn, Zn, Cu and Cr. Black-Right-Pointing-Pointer Water mass fraction of 75% is optimal for the sediment for Pb. Black-Right-Pointing-Pointer We found higher temperature versus lower non-residual fraction except that of Pb. - Abstract: Fixation of heavy metals in the slag produced during incineration of sewage sludge will reduce emission of the metals to the atmosphere and make the incineration process more environmentally friendly. The effects of incineration conditions (incineration temperature 500-1100 Degree-Sign C, furnace residence time 0-60 min, mass fraction of water in the sludge 0-75%) on the fixation rates and species partitioning of Cd, Pb, Cr, Cu, Zn, Mn and Ni in slag were investigated. When the incineration temperature was increased from 500 to 1100 Degree-Sign C, the fixation rate of Cd decreased from 87% to 49%, while the fixation rates of Cu and Mn were stable. The maximum fixation rates for Pb and Zn and for Ni and Cr were reached at 900 and 1100 Degree-Sign C, respectively. The fixation rates of Cu, Ni, Cd, Cr and Zn decreased as the residence time increased. With a 20 min residence time, the fixation rates of Pb and Mn were low. The maximum fixation rates of Ni, Mn, Zn, Cu and Cr were achieved when the mass fraction of water in the sludge was 55%. The fixation rate of Cd decreased as the water mass fraction increased, while the fixation rate of Pb increased. Partitioning analysis of the metals contained in the slag showed that increasing the incineration temperature and residence time promoted complete oxidation of the metals. This reduced the non-residual fractions of the metals, which would lower the bioavailability of the metals. The mass fraction of water in the sludge had little effect on the partitioning of the metals. Correlation analysis indicated that the fixation rates of heavy metals in the sludge and the forms of heavy metals in the incinerator slag could be controlled by optimization of the incineration conditions. These results show how the bioavailability of the metals can be reduced for environmentally friendly disposal of the incinerator slag.

Chen Tao [State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640 (China); Graduate School of Chinese Academy of Sciences, Beijing 100082 (China); Yan Bo, E-mail: yanbo2007@gig.ac.cn [State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640 (China)

2012-05-15T23:59:59.000Z

145

Quantitative analysis of heavy metals emission during the combustion and baling of polyvinyl chloride insulated copper wire  

E-Print Network [OSTI]

was conducted and compared to the airborne dust samples collected during the baling process. From these results, occupational exposures to heavy metals during the reclamation of PVC insulated copper wire were assessed. Bulk ash and dust samples were ?aken...

Pickard, David Paul

1996-01-01T23:59:59.000Z

146

Processing capabilties for the elimination of contaminated metal scrapyards at DOE/ORO-managed sites. [Metal smelting facility  

SciTech Connect (OSTI)

Capabilities exist for reducing all the contaminated nickel, aluminum, and copper scrap to ingot form by smelting. Processing these metals at existing facilities could be completed in about 5 or 6 years. However, these metals represent only about 20% of the total metal inventories currently on hand at the DOE/ORO-managed sites. No provisions have been made for the ferrous scrap. Most of the ferrous scrap is unclassified and does not require secured storage. Also, the potential resale value of the ferrous scrap at about $100 per ton is very low in comparison. Consequently, this scrap has been allowed to accumulate. With several modifications and equipment additions, the induction melter at PGDP could begin processing ferrous scrap after its commitment to nickel and aluminum. The PGDP smelter is a retrofit installation, and annual throughput capabilities are limited. Processing of the existing ferrous scrap inventories would not be completed until the FY 1995-2000 time frame. An alternative proposal has been the installation of induction melters at the other two enrichment facilities. Conceptual design of a generic metal smelting facility is under way. The design study includes capital and operating costs for scrap preparation through ingot storage at an annual throughput of 10,000 tons per year. Facility design includes an induction melter with the capability of melting both ferrous and nonferrous metals. After three years of operation with scrapyard feed, the smelter would have excess capacity to support on-site decontamination and decomissioning projects or upgrading programs. The metal smelting facility has been proposed for FY 1984 line item funding with start-up operations in FY 1986.

Mack, J.E.; Williams, L.C.

1982-01-01T23:59:59.000Z

147

Method and apparatus for removal of gaseous, liquid and particulate contaminants from molten metals  

DOE Patents [OSTI]

Method and apparatus for removal of nonelectrically-conducting gaseous, liquid, and particulate contaminants from molten metal compositions by applying a force thereto. The force (commonly referred to as the Lorentz Force) exerted by simultaneous application of an electric field and a magnetic field on a molten conductor causes an increase, in the same direction as the force, in the apparent specific gravity thereof, but does not affect the nonconducting materials. This difference in apparent densities cause the nonconducting materials to "float" in the opposite direction from the Lorentz Force at a rapid rate. Means are further provided for removal of the contaminants and prevention of stirring due to rotational forces generated by the applied fields.

Hobson, David O. (Oak Ridge, TN); Alexeff, Igor (Oak Ridge, TN); Sikka, Vinod K. (Clinton, TN)

1988-01-01T23:59:59.000Z

148

In situ removal of contamination from soil  

DOE Patents [OSTI]

A process of remediation of cationic heavy metal contamination from soil utilizes gas phase manipulation to inhibit biodegradation of a chelating agent that is used in an electrokinesis process to remove the contamination. The process also uses further gas phase manipulation to stimulate biodegradation of the chelating agent after the contamination has been removed. The process ensures that the chelating agent is not attacked by bioorganisms in the soil prior to removal of the contamination, and that the chelating agent does not remain as a new contaminant after the process is completed. 5 figs.

Lindgren, E.R.; Brady, P.V.

1997-10-14T23:59:59.000Z

149

In situ removal of contamination from soil  

DOE Patents [OSTI]

A process of remediation of cationic heavy metal contamination from soil utilizes gas phase manipulation to inhibit biodegradation of a chelating agent that is used in an electrokinesis process to remove the contamination, and further gas phase manipulation to stimulate biodegradation of the chelating agent after the contamination has been removed. The process ensures that the chelating agent is not attacked by bioorganisms in the soil prior to removal of the contamination, and that the chelating agent does not remain as a new contaminant after the process is completed.

Lindgren, Eric R. (Albuquerque, NM); Brady, Patrick V. (Albuquerque, NM)

1997-01-01T23:59:59.000Z

150

Lead in Your Drinking Water Lead (Pb) is an extremely toxic heavy metal that unfortunately occurs widely in  

E-Print Network [OSTI]

Lead in Your Drinking Water Lead (Pb) is an extremely toxic heavy metal that unfortunately occurs of metallic lead in the soil (4) Drinking water ­ water as it leaves the treatment plant has no lead plumbing components Your exposure to lead in drinking water is at the faucet, but the lead can come from

Maynard, J. Barry

151

Owen, R.B., Sandhu, N., 2000. Heavy metal accumulation and anthro-pogenic impacts on Tolo Harbour, Hong Kong. Mar. Pollut. Bull. 40,  

E-Print Network [OSTI]

.-M., 2003. Pollution history of the Masan Bay, southeast Korea, from heavy metals and foraminiferaOwen, R.B., Sandhu, N., 2000. Heavy metal accumulation and anthro- pogenic impacts on Tolo Harbour and tracer elements in sediments of the Ria de Vigo (NW Spain): an assessment of metal pollution. Mar. Pollut

Yu, K.N.

152

Air Pollution with Heavy Metals and Radionuclides in Slovakia Studied by the Moss Biomonitoring Technique  

E-Print Network [OSTI]

Applying the moss biomonitoring technique to air pollution studies in Slovakia, heavy metals, rare-earth elements, actinides (U and Th) were determined in 86 moss samples from the European moss survey 2000 by means of epithermal neutron activation analysis at the IBR-2 reactor (Dubna). Such elements as In, Cu, Cd, Hg and Pb were determined by AAS in the Forest Research Institute, Zvolen (Slovakia). The results of measurement of the natural radionuclides ^{210}Pb, ^{7}Be, ^{137}Cs and ^{40}K in 11 samples of moss are also reported. A comparison with the results from moss surveys 1991 and 1995 revealed previously unknown tendencies of air pollution in the examined areas.

Florek, M; Mankovska, B; Oprea, K; Pavlov, S S; Steinnes, E; Sykora, I

2001-01-01T23:59:59.000Z

153

Technologies Provide High-Resolution Subsurface Imaging of Vadose Zone Contamination at Hanford Site  

Broader source: Energy.gov [DOE]

RICHLAND, Wash. Cold War waste disposal practices resulted in both planned and unplanned releases of large amounts of radionuclide and heavy metal contamination into the subsurface throughout the DOE complex.

154

BIOMONITORING OF HEAVY METAL POLLUTION NEAR COPPER SMELTER IN BOR (SERBIA) USING ACACIA  

E-Print Network [OSTI]

The correlations between sampling sites situated in the close vicinity of copper smelter (Bor, Serbia) based on heavy metal (Pb, Cu, Zn) content in plant parts and soil of acacia (Robinia pseudoacacia L.) were determined. Very strong correlations (R 2>0.9) were observed between the sites Town park and Hospital in the urban-industiral zone due to high air pollution in this sampling area. The performed cluster analysis confirmed these results by grouping the sites with high metal content in plant and soil material of Robinia pseudoacacia into the same clusters. Also, strong correlations were noted between less polluted sampling sites (Bor lake and Brestovac spa) with the control site (Sumrakovac).

Ana A. Ilic; Snezana M. Serbula; Jelena V. Kalinovic; Tanja S. Kalinovic

155

Uranium and other heavy metals in the plant-animal-human food chain near abandoned mining sites and structures in an American Indian community in northwestern New Mexico  

E-Print Network [OSTI]

Resource Evaluation (NURE) sampling that was undertaken inabove those found in the NURE sampling conducted in the1970s (Mo not evaluated by NURE). The other heavy metals (

Samuel-Nakamura, Christine

2013-01-01T23:59:59.000Z

156

Recycling Of Uranium- And Plutonium-Contaminated Metals From Decommissioning Of The Hanau Fuel Fabrication Plant  

SciTech Connect (OSTI)

Decommissioning of a nuclear facility comprises not only actual dismantling but also, above all, management of the resulting residual materials and waste. Siemens Decommissioning Projects (DP) in Hanau has been involved in this task since 1995 when the decision was taken to decommission and dismantle the Hanau Fuel Fabrication Plant. Due to the decommissioning, large amounts of contaminated steel scrap have to be managed. The contamination of this metal scrap can be found almost exclusively in the form of surface contamination. Various decontamination technologies are involved, as there are blasting and wiping. Often these methods are not sufficient to meet the free release limits. In these cases, SIEMENS has decided to melt the scrap at Siempelkamp's melting plant. The plant is licensed according to the German Radiation Protection Ordinance Section 7 (issue of 20.07.2001). The furnace is a medium frequency induction type with a load capacity of 3.2 t and a throughput of 2 t/h for steel melting. For safety reasons, the furnace is widely operated by remote handling. A highly efficient filter system of cyclone, bag filter and HEPA-filter in two lines retains the dust and aerosol activity from the off-gas system. The slag is solidified at the surface of the melt and gripped before pouring the liquid iron into a chill. Since 1989, in total 15,000 t have been molten in the plant, 2,000 t of them having been contaminated steel scrap from the decommissioning of fuel fabrication plants. Decontamination factors could be achieved between 80 and 100 by the high affinity of the uranium to the slag former. The activity is transferred to the slag up to nearly 100 %. Samples taken from metal, slag and dust are analyzed by gamma measurements of the 186 keV line of U235 and the 1001 keV line of Pa234m for U238. All produced ingots showed a remaining activity less than 1 Bq/g and could be released for industrial reuse.

Kluth, T.; Quade, U.; Lederbrink, F. W.

2003-02-26T23:59:59.000Z

157

Cesium and heavy metal removal from flue dusts and other matrices  

SciTech Connect (OSTI)

A problem exists in the steel industry because of the generation of radioactive waste that is caused by the accidental destruction of nuclear detection instruments. The flue dust from electric Arc Furnaces (EAF) becomes contaminated with the radionuclide used. Typically the radionuclide is cesium 137. The problem is a concern to the industry since the contamination results in the generation of a mixed waste which is costly to dispose of properly. In the interest of providing a viable solution to the problem, Lockheed Environmental Systems and Technologies has developed a process for removal of cesium from flue dust. While removing the cesium from the treatment residue, the process also isolates the other major elements of concern and renders them innocuous, saleable, or readily disposable. However, several innovative techniques have been applied which make the process far more economical, and in addition, the changes simplify the operation and render it controllable. The process involves the dissolution of the various metallic and non-metallic constituents through the use of a mild mineral acid leach. This treatment solubilizes the majority of the constituents including the cesium.

Soderstrom, D.J.; May, R.; Spaulding, S. [Lockheed Environmental Systems and Technologies Co., Las Vegas, NV (United States). Technology Applications Div.

1994-12-31T23:59:59.000Z

158

Method and device for electroextraction of heavy metals from technological solutions and wastewater  

DOE Patents [OSTI]

The basic principles of the method for heavy metals electroextraction from technological solutions and wastewater includes pretreating to remove Chromium-6 and high concentrations of heavy metals and periodically treating in a six-electrode bipolar cylindrical electroreactor made of non-conducting material to achieve lower accepted levels of impurities. Six cylindrical steel electrodes form two triode stacks and are fed with three-phase alternating current of commercial frequency (50-60 Hz), which can be pulsed. Each phase of the three-phase current is connected to three electrodes of one triode stack or in parallel to two triode stacks. The parallel connection of three-phase current to two triode stacks is performed so that the same phase of the three phase current is connected in parallel with each two opposite electrodes of six electrodes located along the periphery, or with two adjacent electrodes. A bipolar stationary aluminum electrode is situated in the inter-electrode space. In one of the embodiments, the bipolar electrode is made of a perforated heat-resistant plastic container filled with secondary aluminum and duralumin scrap. In another embodiment, the bipolar electrode of aluminum or duralumin scrap may be made without a perforated container and is placed in the inter-electrode space as a bulk scrap. In this case, to prevent shorts, each of six steel electrodes is placed in isolated perforated plastic shell with holes of 5 mm in diameter. Non-ferrous metals are extracted in a form of ferrite-chromites, and aluminates as well as hydroxyl salts deposited in the inter-electrode space without electrolysis deposits on electrodes. Deposits are separated from solution by known methods of filtration.

Khalemsky, Aron Mikhailov; Payusov, Sergei Abramovic; Kelner, Leonid; Jo, Jae

2005-05-03T23:59:59.000Z

159

Technical assessment of processes to enable recycling of low-level contaminated metal waste  

SciTech Connect (OSTI)

Accumulations of metal waste exhibiting low levels of radioactivity (LLCMW) have become a national burden, both financially and environmentally. Much of this metal could be considered as a resource. The Department of Energy was assigned the task of inventorying and classifying LLCMW, identifying potential applications, and applying and/or developing the technology necessary to enable recycling. One application for recycled LLCMW is high-quality canisters for permanent repository storage of high-level waste (HLW). As many as 80,000 canisters will be needed by 2035. Much of the technology needed to decontaminate LLCMW has already been developed, but no integrated process has been described, even on a pilot scale, for recycling LLCMW into HLW canisters. This report reviews practices for removal of radionuclides and for producing low carbon stainless steel. Contaminants that readily form oxides may be reduced to below de minimis levels and combined with a slag. Most of the radioactivity remaining in the ingot is concentrated in the inclusions. Radionuclides that chemically resemble the elements that comprise stainless steel can not be removed effectively. Slag compositions, current melting practices, and canister fabrication techniques were reviewed.

Reimann, G.A.

1991-10-01T23:59:59.000Z

160

Mechanisms for the reduction of radionuclides and other metal contaminants in Geobacter sulfurreducens  

SciTech Connect (OSTI)

Many dissimilatory metal-reducing microorganisms can reduce the key radioactive contaminants, U and Tc from soluble high oxidation state forms to insoluble, low oxidation states forms (1). Little is known about the enzymatic mechanisms for these bioreductions. An understanding of these mechanisms is needed if these microorganisms are to be exploited in bioremediation technologies effectively and modeled accurately. G. sulfurreducens has been chosen for study because: It is an important component of subsurface biota (2); It's entire genome sequence is available (2); and A genetic system for this organism is available (3). The aims and objectives are: (1) To characterize the mechanisms of U(VI) and Tc(VII) reduction in G. sulfurreducens. (2) To confirm the identity of the genes encoding the relevant reductases in this organism. (3) To determine the range of other radionuclides (Np, Pu) and key metal pollutants (Cr, Hg, Co) reduced by G. sulfurreducens. (4) To identify the roles of the U(VI) and Tc(VII) reductases in the reduction of these other key pollutants.

Lloyd, Jon R.; Renshaw, Joanna C.; Law, Nick; May, Iain; Livens, Francis R.

2006-04-05T23:59:59.000Z

Note: This page contains sample records for the topic "heavy metal contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Montagnini, Florencia, Howard S. Neufeld and Christopher Uhl. 1984. Heavy metal concentrations in some non-vascular plants in an Amazonian rainforest. Water, Air, and  

E-Print Network [OSTI]

Montagnini, Florencia, Howard S. Neufeld and Christopher Uhl. 1984. Heavy metal concentrations in some non-vascular plants in an Amazonian rainforest. Water, Air, and Soil Pollution 21 the possibility of long-range transport of industrial pollutants to that region. Heavy metal concentrations were

Neufeld, Howard S.

162

An ecological study examining the correlation of end-stage renal disease and ground water heavy metal content in Texas counties  

E-Print Network [OSTI]

An ecological study was conducted to examine the correlation of end-stage renal disease (ESRD) and the ground water heavy metal level of lead, arsenic, cadmium, mercury and the cumulative level of all four metals in Texas counties. The heavy meal...

Bishop, Scott Alan

1999-01-01T23:59:59.000Z

163

Metal impacts on microbial biomass in the anoxic sediments of a contaminated lake  

E-Print Network [OSTI]

metal partitioning in sediments by a sequential extraction8), 836-840. Metals and sediment microbial biomass Ruxton,risk of metals in sediments, Environ. Toxicol. Chem. , 15(

Gough, Heidi L.

2011-01-01T23:59:59.000Z

164

Ion assisted deposition of optical and protective coatings for heavy metal fluoride glass  

SciTech Connect (OSTI)

Heavy metal fluoride glass materials are attractive for optical applications in the near UV through IR wavelength regions. However, many compositions are relatively soft and hygroscopic and possess low softening temperature (250--300/sup 0/C). We have applied ion assisted deposition (IAD) techniques to deposit MgF/sub 2/, SiO/sub 2/, and Al/sub 2/O/sub 3//SiO/sub 2/ thin film structures on fluoride glass substrates at ambient substrate temperature (--100/sup 0/C). The coatings deposited using IAD improve the environmental durability of the fluoride glass and appear to have reasonably good optical characteristics; without application of IAD, the deposited coatings are not durable and have poor adhesion.

McNally, J.J.; Al-Jumaily, G.A.; McNeil, J.R.

1986-06-15T23:59:59.000Z

165

Sedimentation and chronology of heavy metal pollution in Oslo harbor, Norway Aivo Lepland a,*, Thorbjrn J. Andersen b  

E-Print Network [OSTI]

Sedimentation and chronology of heavy metal pollution in Oslo harbor, Norway Aivo Lepland a,d , Anders Rindby e a Geological Survey of Norway, Leiv Eirikssons vei 39, 7491 Trondheim, Norway b Norwegian Geotechnical Institute, P.O. Box 3930 Ullevål Stadion, 0806 Oslo, Norway d Department

Alve, Elisabeth

166

14 Congresso Brasileiro de Geologia de Engenharia e Ambiental Transfer heavy metal from soil treated to colza  

E-Print Network [OSTI]

in sludge from urban and industrial wastewater treatment plants, trying to understand their influence in the roots of colza. Keywords: Mud, heavy metals, colza, bio-accumulator, wastewater Génie Rural Eaux et Forêts (INRGREF), Tunis. (lassoued_najla@yahoo.fr), 2 Ecole Nationale Supérieure des

Paris-Sud XI, Université de

167

Chemical and Mineralogical Characterization of Arsenic, Lead, Chromium, and Cadmium in a Metal-contaminated Histosol  

SciTech Connect (OSTI)

The chemical and mineralogical forms of As, Pb, Cr, and Cd were studied in a metal-contaminated organic soil (Histosol) that received runoff and seepage water from a site that was once occupied by a lead smelter. Soil samples were collected from different depth intervals during both wet and dry seasons and analyzed using bulk powder X-ray diffraction (XRD), synchrotron-based micro X-ray diffraction ({mu}-XRD), and micro X-ray fluorescence ({mu}-SXRF) spectroscopy. There was a clear pattern of mineral distribution with depth that indicated the presence of an intense redox gradient. The oxidized reddish brown surface layer (0-10 cm) was dominated by goethite ({alpha}-FeOOH) and poorly crystalline akaganeite ({beta}-FeOOH). Lead and arsenic were highly associated with these Fe oxides, possibly by forming inner-sphere surface complexes. Gypsum (CaSO{sub 4} {center_dot} 2H{sub 2}O) was abundant in the layer as well, particularly for samples collected during dry periods. Fe(II)-containing minerals, such as magnetite (Fe{sub 3}O{sub 4}) and siderite (FeCO{sub 3}), were identified in the intermediate layers (10-30 cm) where the reductive dissolution of Fe(III) oxides occurred. A number of high-temperature minerals, such as mullite (3Al{sub 2}O{sub 3} {center_dot} 2Si{sub 2}O), corundum ({alpha}-Al{sub 2}O{sub 3}), hematite ({alpha}-Fe{sub 2}O{sub 3}), and wustite (FeO) were identified in the subsurface and they probably formed as a result of a burning event. Several sulfide minerals were identified in the most reduced layers at depths > 30 cm. They included realgar (AsS), alacranite (As{sub 4}S{sub 4}), galena (PbS), and sphalerite (Zn, Fe{sup 2+})S, and a series of Fe sulfides, including greigite (Fe{sup 2+}Fe{sub 2}{sup 3+} S{sub 4}), pyrrhotite (Fe{sub 1-x}S), mackinawite (FeS), marcasite (FeS{sub 2}), and pyrite (FeS{sub 2}). Most of these minerals occurred as almost pure phases in sub-millimeter aggregates and appeared to be secondary phases that had precipitated from solution. Despite the elevated levels of Cd in the soil, no specific Cd phases were identified. The complex mineralogy has important implications for risk assessment and the design of in-situ remediation strategies for this and similar metal-contaminated sites.

Gao, X.; Schulze, D

2010-01-01T23:59:59.000Z

168

Subsurface contaminants focus area  

SciTech Connect (OSTI)

The US Department of Enregy (DOE) Subsurface Contaminants Focus Area is developing technologies to address environmental problems associated with hazardous and radioactive contaminants in soil and groundwater that exist throughout the DOE complex, including radionuclides, heavy metals; and dense non-aqueous phase liquids (DNAPLs). More than 5,700 known DOE groundwater plumes have contaminated over 600 billion gallons of water and 200 million cubic meters of soil. Migration of these plumes threatens local and regional water sources, and in some cases has already adversely impacted off-site rsources. In addition, the Subsurface Contaminants Focus Area is responsible for supplying technologies for the remediation of numerous landfills at DOE facilities. These landfills are estimated to contain over 3 million cubic meters of radioactive and hazardous buried Technology developed within this specialty area will provide efective methods to contain contaminant plumes and new or alternative technologies for development of in situ technologies to minimize waste disposal costs and potential worker exposure by treating plumes in place. While addressing contaminant plumes emanating from DOE landfills, the Subsurface Contaminants Focus Area is also working to develop new or alternative technologies for the in situ stabilization, and nonintrusive characterization of these disposal sites.

NONE

1996-08-01T23:59:59.000Z

169

An analysis of the composition and metal contamination of plastics from waste electrical and electronic equipment (WEEE)  

SciTech Connect (OSTI)

The compositions of three WEEE plastic batches of different origin were investigated using infrared spectroscopy, and the metal content was determined with inductively coupled plasma. The composition analysis of the plastics was based mainly on 14 samples collected from a real waste stream, and showed that the major constituents were high impact polystyrene (42 wt%), acrylonitrilebutadienestyrene copolymer (38 wt%) and polypropylene (10 wt%). Their respective standard deviations were 21.4%, 16.5% and 60.7%, indicating a considerable variation even within a single batch. The level of metal particle contamination was found to be low in all samples, whereas wood contamination and rubber contamination were found to be about 1 wt% each in most samples. In the metal content analysis, iron was detected at levels up to 700 ppm in the recyclable waste plastics fraction, which is of concern due to its potential to catalyse redox reactions during melt processing and thus accelerate the degradation of plastics during recycling. Toxic metals were found only at very low concentrations, with the exception of lead and cadmium which could be detected at 200 ppm and 70 ppm levels, respectively, but these values are below the current threshold limits of 1000 ppm and 100 ppm set by the Restriction of Hazardous Substances directive.

Stenvall, Erik, E-mail: erik.stenvall@chalmers.se [Department of Materials and Manufacturing Technology, Chalmers University of Technology, 41296 Gteborg (Sweden); Tostar, Sandra [Department of Industrial Materials Recycling, Chalmers University of Technology, 41296 Gteborg (Sweden); Boldizar, Antal [Department of Materials and Manufacturing Technology, Chalmers University of Technology, 41296 Gteborg (Sweden); Foreman, Mark R.StJ. [Department of Industrial Materials Recycling, Chalmers University of Technology, 41296 Gteborg (Sweden); Mller, Kenneth [Chemistry and Materials Technology, SP, 50115 Bors (Sweden)

2013-04-15T23:59:59.000Z

170

Sol-gel synthesis of high-quality heavy-metal fluoride glasses  

SciTech Connect (OSTI)

Fluoride glasses are excellent laser hosts and are very well suited for a broad spectrum of optical applications. However, current fluoride glass synthesis is expensive. The sol-gel method is an affordable alternative for producing high-performance, optical-quality heavy-metal fluoride glasses. The method involves forming a hydrous oxide gel of the constituent metal alkoxides and salts, polymerizing the solution to form a gel, fluorinating the gel with anhydrous HF, melting the amorphous material in an oxidizing atmosphere of SF[sub 6], and casting the melt into desired shapes. ZBLA (57ZrF[sub 4] [times] 36BaF[sub 2] [times] 4LaF[sub 3] [times] 3AlF[sub 3], in mol%) and Nd-doped (0.3 mol%) ZBLA glass rods were prepared by this process and their properties were measured. The sol-gel-based glasses had thermal and optical properties similar to those found in the literature for conventionally prepared fluorides.

Dejneka, M.; Riman, R.E.; Snitzer, E. (Rutgers, The State Univ. of New Jersey, Piscataway, NJ (United States). Dept. of Ceramics)

1993-12-01T23:59:59.000Z

171

Using alternative chemicals in the flotation of heavy metals from lead mill tailings  

SciTech Connect (OSTI)

The U.S. Bureau of Mines (USBM) investigated alternative chemicals for the flotation of heavy metal values from southeast Missouri lead mill tailings. The objectives of the study were to lower the Pb remaining in the reprocessed tailings to <500 ppm, concentrate the metal values, and lower the overall toxicity of the flotation reagent scheme. Due to the high toxicity of classic flotation chemicals, collectorless flotation, as well as nontoxic or less-toxic chemicals, was studied for use in the flotation process. The investigation centered on the National tailings pile in Flat River, MO. Advantages to using alternative chemicals for the flotation process are presented. Novel reagent schemes are discussed for the treatment of the tailings. Various nontoxic or less-toxic oils were tested, and a substitute for sodium sulfide was investigated. Using a food additive oil, soda ash, and a frother as the reagent scheme, froth flotation recovered 89% of the Pb values. Further scavenging lowered the Pb remaining in the reprocessed tailings to <500 ppm. A less-toxic substitute for sodium cyanide was also studied for use in the cleaner flotation stages. Preliminary results indicate that the food additive oil, canola oil, to be as effective as classic sulfide flotation reagents.

Benn, F.W. [Bureau of Mines, Rolla, MO (United States)

1995-04-01T23:59:59.000Z

172

Pulmonary toxicity after exposure to military-relevant heavy metal tungsten alloy particles  

SciTech Connect (OSTI)

Significant controversy over the environmental and public health impact of depleted uranium use in the Gulf War and the war in the Balkans has prompted the investigation and use of other materials including heavy metal tungsten alloys (HMTAs) as nontoxic alternatives. Interest in the health effects of HMTAs has peaked since the recent discovery that rats intramuscularly implanted with pellets containing 91.1% tungsten/6% nickel/2.9% cobalt rapidly developed aggressive metastatic tumors at the implantation site. Very little is known, however, regarding the cellular and molecular mechanisms associated with the effects of inhalation exposure to HMTAs despite the recognized risk of this route of exposure to military personnel. In the current study military-relevant metal powder mixtures consisting of 92% tungsten/5% nickel/3% cobalt (WNiCo) and 92% tungsten/5% nickel/3% iron (WNiFe), pure metals, or vehicle (saline) were instilled intratracheally in rats. Pulmonary toxicity was assessed by cytologic analysis, lactate dehydrogenase activity, albumin content, and inflammatory cytokine levels in bronchoalveolar lavage fluid 24 h after instillation. The expression of 84 stress and toxicity-related genes was profiled in lung tissue and bronchoalveolar lavage cells using real-time quantitative PCR arrays, and in vitro assays were performed to measure the oxidative burst response and phagocytosis by lung macrophages. Results from this study determined that exposure to WNiCo and WNiFe induces pulmonary inflammation and altered expression of genes associated with oxidative and metabolic stress and toxicity. Inhalation exposure to both HMTAs likely causes lung injury by inducing macrophage activation, neutrophilia, and the generation of toxic oxygen radicals. -- Highlights: ? Intratracheal instillation of WNiCo and WNiFe induces lung inflammation in rats. ? WNiCo and WNiFe alter expression of oxidative stress and toxicity genes. ? WNiCo induces a greater oxidative burst response than WNiFe in lung macrophages.

Roedel, Erik Q., E-mail: Erik.Roedel@amedd.army.mil [Department of General Surgery, Tripler Army Medical Center, Honolulu, HI 96859 (United States); Cafasso, Danielle E., E-mail: Danielle.Cafasso@amedd.army.mil [Department of General Surgery, Tripler Army Medical Center, Honolulu, HI 96859 (United States); Lee, Karen W.M., E-mail: Karen.W.Lee@amedd.army.mil [Department of Clinical Investigation, Tripler Army Medical Center, Honolulu, HI 96859 (United States); Pierce, Lisa M., E-mail: Lisa.Pierce@amedd.army.mil [Department of Clinical Investigation, Tripler Army Medical Center, Honolulu, HI 96859 (United States)

2012-02-15T23:59:59.000Z

173

A Lesson Learned on Determination of Radionuclides on Metal Surface Fixed Contamination  

SciTech Connect (OSTI)

A Measurement of fixed surface contamination required to determine classification as low-level or as transuranic waste.

MEZNARICH, H.K.

2000-02-01T23:59:59.000Z

174

A correlation between the heavy element content of transiting extrasolar planets and the metallicity of their parent stars  

E-Print Network [OSTI]

Nine extrasolar planets with masses between 110 and 430M are known to transit their star. The knowledge of their masses and radii allows an estimate of their composition, but uncertainties on equations of state, opacities and possible missing energy sources imply that only inaccurate constraints can be derived when considering each planet separately. Aims: We seek to better understand the composition of transiting extrasolar planets by considering them as an ensemble, and by comparing the obtained planetary properties to that of the parent stars. Methods: We use evolution models and constraints on the stellar ages to derive the mass of heavy elements present in the planets. Possible additional energy sources like tidal dissipation due to an inclined orbit or to downward kinetic energy transport are considered. Results: We show that the nine transiting planets discovered so far belong to a quite homogeneous ensemble that is characterized by a mass of heavy elements that is a relatively steep function of the stellar metallicity, from less than 20 earth masses of heavy elements around solar composition stars, to up to 100M for three times the solar metallicity (the precise values being model-dependant). The correlation is still to be ascertained however. Statistical tests imply a worst-case 1/3 probability of a false positive. Conclusions: Together with the observed lack of giant planets in close orbits around metal-poor stars, these results appear to imply that heavy elements play a key role in the formation of close-in giant planets. The large masses of heavy elements inferred for planets orbiting metal rich stars was not anticipated by planet formation models and shows the need for alternative theories including migration and subsequent collection of planetesimals.

Tristan Guillot; Nuno C. Santos; Frdric Pont; Nicolas Iro; Claudio Melo; Ignasi Ribas

2006-05-31T23:59:59.000Z

175

The development of coil short circuits when transformer windings become contaminated with metal-containing colloidal particles  

SciTech Connect (OSTI)

The radiational-thermal development of coil short circuits due to the action of partial discharges of the first kind when the windings of transformers, autotransformers and shunting reactors become contaminated with metal-containing colloidal particles, formed in the transformer oil as a result of the interaction of the oil with the constructional materials (the copper of the windings, the iron of the tank, the core etc.) is considered. Acriterion of dangerous contamination of the coil insulation of the windings by metal-containing colloidal particles is proposed, namely, 3% of the mass content of copper and iron in it, which, if exceeded, may serve as a basis for recognizing the state of transformers, autotransformers and shunting reactors at a voltage of 110 kV and above the limit. It is shown that filters for continuously cleaning the oil play a considerable role in prolonging the life of transformer equipment.

L'vov, S. Yu. ['Presselektro' Ltd. (Russian Federation); Lyut'ko, E. O. [JSC 'R and D Center for Power Engineering' (Russian Federation); Bondareva, V. N.; Komarov, V. B. [Russian Academy of Sciences, A. N. Frumkin Institute of Physical Chemistry and Electrochemistry (Russian Federation); L'vov, Yu. N. [JSC 'R and D Center for Power Engineering' (Russian Federation)

2012-01-15T23:59:59.000Z

176

DECHEM: A remedial planning tool for metallic contaminants in soil at UMTRA Project sites. Final report and users` guide  

SciTech Connect (OSTI)

The DECHEM (DEcontamination of CHEMicals) method was developed for the Uranium Mill Tailings Remedial Action (UMTRA) Project to guide characterization and remedial planning for metals contamination in soils. This is necessary because non-radiological hazardous constituents may be more mobile than radium-226 (Ra-226), and hence may migrate more deeply into subpile soils (beneath tailings that are to be relocated) or into adjacent contaminated soils at UMTRA Project sites. The result is that remedial action to the Ra-226 excavation limit, as specified in the US Environmental Protection Agency (EPA) standards, may not adequately remove hazardous non-radiological contamination. Unmitigated, these contaminants in soil may cause health risks because of their presence in resuspended particles, their uptake by crops or fodder their seepage into aquifers used for drinking water or other possible exposure pathways. The DECHEM method was developed in response to the need for advanced planning for the remediation of chemical contaminants at UMTRA Project sites, and includes the following elements: Establishment of acceptable exposure rates for humans to chemicals, based on EPA guidelines or other toxicological literature. Modeling of chemical migration through environmental pathways from a remediated UMTRA Project site to humans. Determination of allowable residual concentrations (i.e., cleanup guidelines) for chemicals in soils that results in doses to humans that are below established acceptable exposure rates. The initial development and application of the DECHEM method has focused upon hazardous metallic contaminants such as arsenic, lead, molybdenum, and selenium, which are known to occur in elevated concentrations at some UMTRA Project sites.

Not Available

1989-03-01T23:59:59.000Z

177

Portugaliae Electrochimica Acta (2006), 24(3), 367-376 Portuguese Electrochemical A Modified Electrodialytic Cell to Recover Heavy Metals from Wastewater  

E-Print Network [OSTI]

, A Modified Electrodialytic Cell to Recover Heavy Metals from Wastewater Abo-Ghander, N. S.; Rahman, S. U electrodialysis and redn. of metal ions. The cell is able to recover metallic copper from wastewater contg. 1000 of several parameters, namely, width of wastewater compartment, applied potential and concn. of anolyte

Zaidi, S. M. Javaid

178

Lead in Your Drinking Water Lead (Pb) is an extremely toxic heavy metal that unfortunately occurs widely in our environment. The  

E-Print Network [OSTI]

Lead in Your Drinking Water Lead (Pb) is an extremely toxic heavy metal that unfortunately occurs of metallic lead in the soil (4) Drinking water ­ water as it leaves the treatment plant has no lead of connection. (In some cases, the water meter as well as the curb stop is outside the house.) Common metals

Maynard, J. Barry

179

Trace metal fractionation as a mean to improve on the management of1 contaminated sediments from runoff water infiltration basins2  

E-Print Network [OSTI]

Trace metal fractionation as a mean to improve on the management of1 contaminated sediments from as a mean to improve on the management of21 contaminated sediments from runoff water infiltration basins22 The management of stormwater sediment is a key issue for local authorities due to their23 pollution load

Boyer, Edmond

180

Potential risks of metal toxicity in contaminated sediments of Dele river in Northern France  

E-Print Network [OSTI]

water-metal concentrations in the sediment allowed us to highlight the extent of toxicity caused by Cd for freshwater ecosystems. As for risks of toxicity from pore waters, metal concentrations reached their maxima to accumulate in sediments at the bottom of the water column; and if toxic levels are reached, metals can affect

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "heavy metal contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Isolation of heavy metal influx to the Cookeville sanitary sewer system and impact on municipal sludge management  

SciTech Connect (OSTI)

The city of Cookeville, Tennessee, has been experiencing problems with municipal sludge management. Of particular concern was the high concentration of regulated trace metals in the sludge. Primarily, cadmium limited the amount of sludge which was spread on the available cropland in 1985. The purpose of this project was to determine the major sources of heavy metal influx to the city's sanitary sewer system and the potential effects of heavy metals on sludge management. In general, the findings of the study indicate that city enforcement of existing State of Tennessee and city industrial pretreatment requirements will most likely extend the useful life of the currently available 388 ha land application sites to as much as ten years for certain sites. Cadmium governed the annual sludge application rates to the agricultural land. One plating industry discharged over 90% of the cadmium, copper, nickel, and zinc mass to the sanitary sewer. In addition, during 1986, the average concentration of most of the trace metals monitored in the municipal sludge deceased from levels reported in 1985.

George, D.B.; Borup, M.B.; Adams, V.D.; Prehn, M.P. (Tennessee Technological Univ., Cookeville (USA))

1989-04-01T23:59:59.000Z

182

Contamination sources of PCDD/Fs, dioxin-like PCBs, PAHs and trace metals in sediments of high and low impacted transboundary rivers (Belgium-France).  

E-Print Network [OSTI]

1 Contamination sources of PCDD/Fs, dioxin-like PCBs, PAHs and trace metals in sediments of high hydrocarbons (PAHs), dioxins (PCDD/Fs and dioxin-like PCBs) and trace metals have been assessed in sediment from pyrolytic (combustion) origin. For the PCDD/Fs and dioxin-like PCBs we compared the fingerprint

Boyer, Edmond

183

Cultivation, Capital, and Contamination: Urban Agriculture in Oakland, California  

E-Print Network [OSTI]

2011. Assessment of heavy metal pollution from a Fe-smeltingheavy metals sources in soils. Environmental Pollution 114:heavy metals in mining wastes Water, Air, and Soil Pollution

McClintock, Nathan

2011-01-01T23:59:59.000Z

184

Adaptation to metal-contaminated soils in populations of the moss, Ceratodon purpureus: Vegetative growth and reproductive expression  

SciTech Connect (OSTI)

Many observations suggest that morphological evolution occurs slowly in bryophytes, and this has been suggested to reflect low genetic diversity within species. Isozyme studies, however, stand in apparent contrast and have shown that bryophytes can contain high levels of genetic variability within and among populations. In light of this conflict, we tested the potential of the moss, Ceratodon purpureus, to undergo adaptive change (i.e., ecotypic differentiation) in response to soils that have been contaminated with high levels of metals for 90 years by measuring gametophytic growth and reproductive expression under experimental conditions. Variation in protonemal growth in sterile culture indicates that plants from one population growing on contaminated soil near a smelter are significantly more tolerant of zinc, cadmium, and lead than plants from uncontaminated sites. Results from a common garden experiment, in which plants were grown on soil from the smelter site, indicate that plants from near the smelter are significantly more tolerant of contaminated soils than plants from uncontaminated sites for vegetative growth. The same experiment suggests that plants from the smelter site are also more tolerant in terms of gametangial production (although we could not test this statistically). Our results demonstrate that C. purpureus has been able to undergo relatively rapid evolution in response to strong selective pressures. 29 refs., 4 figs., 5 tabs.

Jules, E.S.; Shaw, A.J. (Univ. of Michigan, Ann Arbor, MI (United States))

1994-06-01T23:59:59.000Z

185

Kinetics of Cd Release from Some Contaminated Calcareous Soils  

SciTech Connect (OSTI)

Contamination of soils with heavy metals may pose long-term risk to groundwater quality leading to health implications. Bioavailability of heavy metals, like cadmium (Cd) is strongly affected by sorption and desorption processes. The release of heavy metals from contaminated soils is a major contamination risks to natural waters. The release of Cd from contaminated soils is strongly influenced by its mobility and bioavailability. In this study, the kinetics of Cd desorption from ten samples of contaminated calcareous soils, with widely varying physicochemical properties, were studied using 0.01 M EDTA extraction. The median percentage of Cd released was about 27.7% of the total extractable Cd in the soils. The release of Cd was characterized by an initial fast release rate (of labile fractions) followed by a slower release rate (of less labile fractions) and a model of two first-order reactions adequately describes the observed release of Cd from the studied soil samples. There was positive correlation between the amount of Cd released at first phase of release and Cd in exchangeable fraction, indicating that this fraction of Cd is the main fraction controlling the Cd in the kinetic experiments. There was strongly negative correlation between the amount of Cd released at first and second phases of release and residual fraction, suggesting that this fraction did not contribute in Cd release in the kinetic experiments. The results can be used to provide information for evaluation of Cd potential toxicity and ecological risk from contaminated calcareous soils.

Sajadi Tabar, S.; Jalali, M., E-mail: jalali@basu.ac.ir [Bu-Ali Sina University, Department of Soil Science, College of Agriculture (Iran, Islamic Republic of)

2013-03-15T23:59:59.000Z

186

Copper-induced oxidative stress in three-spined stickleback : relationship with hepatic metal levels  

E-Print Network [OSTI]

contamination of aquatic ecosystems by heavy metals. Among them, copper is a widespread pollutant found, 1999). Although this metal is a required element, high concentrations appear to be toxic to freshwater1 Copper-induced oxidative stress in three-spined stickleback : relationship with hepatic metal

Paris-Sud XI, Université de

187

Heavy metal inventory and fuel sustainability of recycling TRU in FBR design  

SciTech Connect (OSTI)

Nuclear fuel materials from spent fuel of light water reactors have a potential to be used for destructive devices with very huge energy release or in the same time, it can be utilized as a peaceful energy or civil applications, for generating electricity, desalination of water, medical application and others applications. Several research activities showed some recycled spent fuel can be used as additional fuel loading for increasing fuel breeding capability as well as improving intrinsic aspect of nuclear non-proliferation. The present investigation intends to evaluate the composition of heavy metals inventories and fuel breeding capability in the FBR design based on the loaded fuel of light water reactor (LWR) spent fuel (SF) of 33 GWd/t with 5 years cooling time by adopting depletion code of ORIGEN. Whole core analysis of FBR design is performed by adopting and coupling codes such as SLAROM code, JOINT and CITATION codes. Nuclear data library, JFS-3-J-3.2R which is based on the JENDL 3.2 has been used for nuclear data analysis. JSFR design is the basis design reference which basically adopted 800 days cycle length for 4 batches system. Higher inventories of plutonium of MOX fuel and TRU fuel types at equilibrium composition than initial composition have been shown. Minor actinide (MA) inventory compositions obtain a different inventory trends at equilibrium composition for both fuel types. Higher Inventory of MA is obtained by MOX fuel and less MA inventory for TRU fuel at equilibrium composition than initial composition. Some different MA inventories can be estimated from the different inventory trend of americium (Am). Higher americium inventory for MOX fuel and less americium inventory for TRU fuel at equilibrium condition. Breeding ratio of TRU fuel is relatively higher compared with MOX fuel type. It can be estimated from relatively higher production of Pu-238 (through converted MA) in TRU fuel, and Pu-238 converts through neutron capture to produce Pu-239. Higher breeding ratio of MOX fuel and TRU fuel types at equilibrium condition are estimated from converted fertile material during reactor operation into fissile material of plutonium such as converted uranium fuel (converted U-238 into Pu-239) or additional converted fuel from MA into Pu-238 and changes into Pu-239 by capturing neutron. Loading LWR SF gives better fuel breeding capability and increase inventory of MA for doping material of MOX fuel; however, it requires more supply MA inventory for TRU fuel type.

Permana, Sidik; Suzuki, Mitsutoshi; Su'ud, Zaki [Department of Science and Technology for Nuclear Material Management (STNM), Japan Atomic Energy Agency (JAEA), 2-4 Shirane, Shirakata, Tokai Mura, Naka-gun, Ibaraki 319-1195 Nuclear Physics and Bio (Indonesia); Department of Science and Technology for Nuclear Material Management (STNM), Japan Atomic Energy Agency (JAEA), 2-4 Shirane, Shirakata, Tokai Mura, Naka-gun, Ibaraki 319-1195 (Japan); Nuclear Physics and Bio Physics Research Group, Department of Physics, Bandung Institute of Technology, Gedung Fisika, Jl. Ganesha 10, Bandung 40132 (Indonesia)

2012-06-06T23:59:59.000Z

188

Arsenic speciation in multiple metal environments II. Micro-spectroscopic investigation of a CCA contaminated soil  

E-Print Network [OSTI]

2006, Aus- tralia. stances (acid mine drainage, smelter wastes, pesticides, chro- mated copper arsenate January 2008 Abstract The speciation of arsenic (As) in a copper-chromated-arsenate (CCA) contaminated as a continuum of fully and poorly-ordered copper-arsenate precipitates with additional components being

189

The Influence of Metal Pollution on the Immune System A Potential Stressor for Marine Mammals in the North Sea  

E-Print Network [OSTI]

2003). Heavy metals in marine mammals, Toxicology of Marineand thymocytes to heavy metals. Environmental Toxicology and

Kakuschke, Antje; Prange, Andreas

2007-01-01T23:59:59.000Z

190

Radionuclide and heavy metal concentrations in soil, vegetation, and fish collected around and within Tsicoma Lake in Santa Clara Canyon  

SciTech Connect (OSTI)

Radionuclide ({sup 3}H, {sup 90}Sr, {sup 137}Cs, {sup 238}Pu, {sup 239}Pu, total U) and heavy metal (Ag, As, Ba, Be, Cd, Cr, Hg, Ni, Pb, Sb, Se, Tl) contents were determined in soil, vegetation (overstory and understory), and fish (rainbow trout) collected around and within Tsicoma Lake in Santa Clara Canyon in 1995. All heavy metal and most radionuclide contents around or within the lake, except for U in soil, vegetation, and fish, were within or just above upper limit background. Detectable levels (where the analytical result was greater than two times counting uncertainty) of U in soils, vegetation, and fish were found in slightly higher concentrations than in background samples. Overall, however, maximum total committed effective dose equivalent (CEDE)(95% confidence level)--based on consumption of 46 lb of fish--from Tsicoma Lake (0.066 mrem/y) was within the maximum total CEDE from the ingestion of fish from the Mescalero National Fish Hatchery (background)(0.113 mrem/y).

Fresquez, P.R.; Armstrong, D.R.; Naranjo, L. Jr.

1996-03-01T23:59:59.000Z

191

Radionuclides and heavy metals in rainbow trout from Tsichomo, Nana Ka, Wen Povi, and Pin De Lakes in Santa Clara Canyon  

SciTech Connect (OSTI)

Radionuclide ({sup 3}H, {sup 90}Sr, {sup 137}Cs, {sup 238}Pu, {sup 239}Pu, and total uranium) and heavy metal (Ag, As, Ba, Be, Cd, Cr, Hg, Ni, Pb, Sb, Se, and TI) concentrations were determined in rainbow trout collected from Tsichomo, Nana Ka, Wen Povi, and Pin De lakes in Santa Clara Canyon in 1997. Most radionuclide and heavy metal concentrations in fish collected from these four lakes were within or just above upper limit background concentrations (Abiquiu reservoir), and as a group were statistically (p < 0.05) similar in most parameters to background.

Fresquez, P.R.; Armstrong, D.R.; Naranjo, L. Jr.

1998-04-01T23:59:59.000Z

192

Four methods for determining the composition of trace radioactive surface contamination of low-radioactivity metal  

E-Print Network [OSTI]

Four methods for determining the composition of low-level uranium- and thorium-chain surface contamination are presented. One method is the observation of Cherenkov light production in water. In two additional methods a position-sensitive proportional counter surrounding the surface is used to make both a measurement of the energy spectrum of alpha particle emissions and also coincidence measurements to derive the thorium-chain content based on the presence of short-lived isotopes in that decay chain. The fourth method is a radiochemical technique in which the surface is eluted with a weak acid, the eluate is concentrated, added to liquid scintillator and assayed by recording beta-alpha coincidences. These methods were used to characterize two `hotspots' on the outer surface of one of the He-3 proportional counters in the Neutral Current Detection array of the Sudbury Neutrino Observatory experiment. The methods have similar sensitivities, of order tens of ng, to both thorium- and uranium-chain contamination.

O'Keeffe, H M; Cleveland, B T; Doucas, G; Gagnon, N; Jelley, N A; Kraus, C; Lawson, I T; Majerus, S; McGee, S R; Myers, A W; Poon, A W P; Rielage, K; Robertson, R G H; Rosten, R C; Stonehill, L C; VanDevender, B A; Van Wechel, T D

2011-01-01T23:59:59.000Z

193

Four methods for determining the composition of trace radioactive surface contamination of low-radioactivity metal  

E-Print Network [OSTI]

Four methods for determining the composition of low-level uranium- and thorium-chain surface contamination are presented. One method is the observation of Cherenkov light production in water. In two additional methods a position-sensitive proportional counter surrounding the surface is used to make both a measurement of the energy spectrum of alpha particle emissions and also coincidence measurements to derive the thorium-chain content based on the presence of short-lived isotopes in that decay chain. The fourth method is a radiochemical technique in which the surface is eluted with a weak acid, the eluate is concentrated, added to liquid scintillator and assayed by recording beta-alpha coincidences. These methods were used to characterize two `hotspots' on the outer surface of one of the He-3 proportional counters in the Neutral Current Detection array of the Sudbury Neutrino Observatory experiment. The methods have similar sensitivities, of order tens of ng, to both thorium- and uranium-chain contamination.

H. M. O'Keeffe; T. H. Burritt; B. T. Cleveland; G. Doucas; N. Gagnon; N. A. Jelley; C. Kraus; I. T. Lawson; S. Majerus; S. R. McGee; A. W. Myers; A. W. P. Poon; K. Rielage; R. G. H. Robertson; R. C. Rosten; L. C. Stonehill; B. A. VanDevender; T. D. Van Wechel

2011-03-29T23:59:59.000Z

194

Mobility of Source Zone Heavy Metals and Radionuclides: The Mixed Roles of Fermentative Activity on Fate and Transport of U and Cr  

SciTech Connect (OSTI)

Predicting the potential migration of metals and radionuclides from waste pits and trenches will require understanding the effects of carbon and electron flow through these environments. Important aspects of this flow include the physiological activity of cellulolytic and non-cellulolytic fermentative microbial populations, as well as the subsequent activity of metal and radionuclide reducing bacteria. The activity of subsurface fermentative microbial populations is significantly understudied even though these organisms can affect contaminant migration by at least two mechanisms. In the first mechanism, products of the fermentation process can act as chelators for metals and radionuclides increasing their transport through underlying geological media. The second mechanism is the reduction and immobilization of metals and radionuclides since some fermentative bacteria have been shown to directly reduce metals and radionuclides, while their fermentation products can provide carbon and energy for respiratory metal reducing bacteria that can also reduce oxidized metals and radionuclides.

Apel, William; Peyton, Brent; Gerlach, Robin; Lee, Brady

2006-06-01T23:59:59.000Z

195

In-situ spectroelectrochemical studies of radionuclide contaminated surface films on metals and the mechanism of their formation and dissolution. 1997 annual progress report  

SciTech Connect (OSTI)

'The incorporation of radioactive contaminants into corrosion product scales on metals is being investigated using in-situ spectroscopic and electrochemical techniques. To facilitate the study, stable isotopes are used initially, while the corrosion films are simulated by electrodeposition of the appropriate oxide (hydroxide) onto a graphite substrate. Synchrotron x-ray absorption spectroscopy (XAS) is used to determine the structure and composition of the host oxide film, as well as the local structure of the impurity ion. Results on the incorporation of Sr and Ce into surface films of Ni(OH){sub 2} and NiOOH are reported. Cathodically deposited Ni(OH){sub 2} was found to be mainly in the {alpha} form while anodically prepared NiOOH consists of Ni{sup +2} and Ni{sup +4} phases. Sr in the films consists mainly of Sr{sup 2+} which appears to be coordinated to oxygen atoms and is likely to exist as small domains of co-precipitated material. Ce in Ni(OH){sub 2} exists mainly as Ce{sup +3} and as a Ce{sup +4} species when co-deposited with NiOOH. The structure of the Ce{sup +4} phase appears similar to a Ce(OH){sub 4} standard. However, x-ray diffraction and laser Raman measurements indicate that the latter chemical formulation is probably incorrect and that the material is more likely to be a disordered hydrous cerium oxide. Ce chemisorbed on Ni(OH){sub 2} and NiOOH films is predominantly in the +3 valency state. Iron oxide films prepared by anodic deposition from borate buffer solution containing Fe{sup +2}, has been found by XAS to consist mainly of {alpha} FeOOH. The latter has been found by others to be the constituent of the corrosion film on iron; this lends credence to the present simulation approach. Future work will involve studies on the incorporation of radioactive Sr, Ce, and Cs, as well as U, into nickel and iron oxide films. Investigations on the structure and composition of chromium oxide films, the effect of temperature on the energetics and mechanism of incorporation of heavy metal ions, as well as the subsequent dissolution of the films by electroreduction and anodic oxidation, will be undertaken.'

Melendres, C.A.; Balasubramanian, M.; Papapanayiotou, D. [Argonne National Lab., IL (US). Chemical Technology Div.; Mini, S. [Northern Illinois Univ., DeKalb, IL (US). Physics Dept.; Mansour, A.N. [Naval Surface Warfare Center, Bethesda, MD (US). Carderock Div.

1997-09-01T23:59:59.000Z

196

Proceedings of Soil Decon `93: Technology targeting radionuclides and heavy metals  

SciTech Connect (OSTI)

The principal objective for convening this workshop was to exchange ideas and discuss with scientists and engineers methods for removing radionuclides and/or toxic metals from soils. Over the years there have been numerous symposia, conferences, and workshops directed at soil remediation. However, this may be the first where the scope was narrowed to the removal of radionuclides and toxic metals from soils. The intent was to focus on the separation processes controlling the removal of the radionuclide and/or metal from soil. Its purpose was not intended to be a soil washing/leaching workshop, but rather to identify a variety or combination of processes (chemical, physical, and biological) that can be used in concert with the applicable engineering approaches to decontaminate soils of radionuclides and toxic metals. Abstracts and visual aids used by the speakers of the workshop are presented in this document.

Not Available

1993-09-01T23:59:59.000Z

197

E-Print Network 3.0 - atmospheric heavy metal Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of metal in the atmosphere and into the river system (T1 to T4), (iv... ) to wastewater treatment plants (WWTP),5 the national ... Source: Ecole Polytechnique, Centre de...

198

MOVEMENT OF HEAVY METALS THROUGH UNDISTURBED AND HOMOGENIZED SOIL COLUMNS Vincent J. Camobreco , Brian K. Richards , Tammo S. Steenhuis , John H. Peverly , and Murray B. McBride1 1* 1 2 2  

E-Print Network [OSTI]

OF HEAVY METALS ..." 2 INTRODUCTION The application of sewage sludge to land is, in principle, an effective 161:740-750 1996 ABSTRACT Soils accumulate heavy metals when sewage sludge is applied to land, such as Cd, Zn, Cu, Ni, Cr and Pb, is the most critical long-term hazard when applying sludge to land (Logan

Walter, M.Todd

199

Baseline concentrations of radionuclides and heavy metals in soils and vegetation around the DARHT facility: Construction phase (1996)  

SciTech Connect (OSTI)

As part of the Department of Energy`s Mitigation Action Plan for the Dual Axis Radiographic Hydrodynamic Test (DARHT) Facility at Los Alamos National Laboratory (LANL), baseline concentrations of radionuclides ({sup 3}H, {sup 137}Cs, {sup 90}Sr, {sup 238}Pu, {sup 239}Pu, {sup 241}Am, total U), and heavy metals (Ag, As, Ba, Be, Cd, Cr, Cu, Hg, Ni, Pb, Sb, Se and Tl) in soil, sediment, and vegetation (overstory and understory) around the DARHT facility during the construction phase in 1996 were determined. Also, U and Be concentrations in soil samples collected in 1993 from within the proposed DARHT facility area are reported. Most radionuclides in soils, sediments, and vegetation were within current background and/or long-term regional statistical reference levels.

Fresquez, P.R.; Haagenstad, H.T.; Naranjo, L. Jr.

1997-04-01T23:59:59.000Z

200

MOLYBDENUM, RUTHENIUM, AND THE HEAVY r-PROCESS ELEMENTS IN MODERATELY METAL-POOR MAIN-SEQUENCE TURNOFF STARS  

SciTech Connect (OSTI)

The ratios of elemental abundances observed in metal-poor stars of the Galactic halo provide a unique present-day record of the nucleosynthesis products of its earliest stars. While the heaviest elements were synthesized by the r- and s-processes, dominant production mechanisms of light trans-ironic elements were obscure until recently. This work investigates further our 2011 conclusion that the low-entropy regime of a high-entropy wind (HEW) produced molybdenum and ruthenium in two moderately metal-poor turnoff stars that showed extreme overabundances of those elements with respect to iron. Only a few, rare nucleosynthesis events may have been involved. Here we determine abundances for Mo, Ru, and other trans-Fe elements for 28 similar stars by matching spectral calculations to well-exposed near-UV Keck HIRES spectra obtained for beryllium abundances. In each of the 26 turnoff stars with Mo or Ru line detections and no evidence for s-process production (therefore old), we find Mo and Ru to be three to six times overabundant. In contrast, the maximum overabundance is reduced to factors of three and two for the neighboring elements zirconium and palladium. Since the overproduction peaks sharply at Mo and Ru, a low-entropy HEW is confirmed as its origin. The overabundance level of the heavy r-process elements varies significantly, from none to a factor of four, but is uncorrelated with Mo and Ru overabundances. Despite their moderate metallicity, stars in this group trace the products of different nucleosynthetic events: possibly very few events, possibly events whose output depended on environment, metallicity, or time.

Peterson, Ruth C. [Astrophysical Advances, 607 Marion Place, Palo Alto, CA 94301 (United States)

2013-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "heavy metal contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Metal binding proteins, recombinant host cells and methods  

DOE Patents [OSTI]

The present disclosure provides artificial heavy metal binding proteins termed chelons by the inventors. These chelons bind cadmium and/or mercuric ions with relatively high affinity. Also disclosed are coding sequences, recombinant DNA molecules and recombinant host cells comprising those recombinant DNA molecules for expression of the chelon proteins. In the recombinant host cells or transgenic plants, the chelons can be used to bind heavy metals taken up from contaminated soil, groundwater or irrigation water and to concentrate and sequester those ions. Recombinant enteric bacteria can be used within the gastrointestinal tracts of animals or humans exposed to toxic metal ions such as mercury and/or cadmium, where the chelon recombinantly expressed in chosen in accordance with the ion to be rededicated. Alternatively, the chelons can be immobilized to solid supports to bind and concentrate heavy metals from a contaminated aqueous medium including biological fluids.

Summers, Anne O.; Caguiat, Jonathan J.

2004-06-15T23:59:59.000Z

202

Effects of Adding Sewage Sludge and Urea-Phosphate Fertilizers to the Great Sippewissett Salt Marsh, Falmouth, MA on Heavy Metals and Microbial N-Cycling  

E-Print Network [OSTI]

in the United States is in car and industrial lead- acid batteries (Wernick & Themelis 1998). Zinc is the least is important in regulating the exchange of nitrogen through the air, soil and organic matter. In this study, the Clean Water Act and Clean Air Act were passed to help combat the increase of metal contamination

Vallino, Joseph J.

203

Functional genomics of the bacterial degradation of the emerging water contaminants: 1,4-dioxane and N-nitrosodimethylamine (NDMA)  

E-Print Network [OSTI]

mechanisms to cope with heavy metal toxicity. Therefore, innature and extent of heavy metal toxicity that strain CB1190

Sales, Christopher Michael

2012-01-01T23:59:59.000Z

204

Levels of metals from salt marsh plants from Southern California, USA  

E-Print Network [OSTI]

sedimentary record of heavy metal pollution in the lagoon ofcapacity for heavy metals. Environmental Pollution, 146,heavy metals in experimental salt marsh ecosystems. Environmental Pollution,

Hoyt, Kimberly Ann

2009-01-01T23:59:59.000Z

205

Bioavailability of Cadmium and Zin to Two Earthworm Species in High-metal Soils  

E-Print Network [OSTI]

tolerance capacity for heavy metals pollution (Dez-Ortiz etof heavy metals in soils. Environmental Pollution 113, 135-heavy metals in terrestrial invertebrates. Environmental Pollution

Liu, Ying

2012-01-01T23:59:59.000Z

206

Effects of asphaltene precipitation and reprecipitation on the metal-containing compounds in heavy residua  

SciTech Connect (OSTI)

Boscan vacuum residuum (VR) has been separated into isooctane insoluble asphaltenes and isooctane soluble maltenes. The asphaltenes were dissolved in a minimum of toluene and were further separated by two additional reprecipitations using isooctane as the precipitating solvent. The authors examined the fractions, including the recovered isooctane soluble material, by size exclusion chromatography (SEC) with inductively coupled plasma (ICP) emission spectroscopy to determine the effects, if any, the reprecipitations have on the size distribution of the metal-containing compounds.

Reynolds, J.G.; Biggs, W.R.

1986-01-01T23:59:59.000Z

207

Magnetism and superconductivity driven by identical 4f states in a heavy-fermion metal  

SciTech Connect (OSTI)

The apparently inimical relationship between magnetism and superconductivity has come under increasing scrutiny in a wide range of material classes, where the free energy landscape conspires to bring them in close proximity to each other. Particularly enigmatic is the case when these phases microscopically interpenetrate, though the manner in which this can be accomplished remains to be fully comprehended. Here, we present combined measurements of elastic neutron scattering, magnetotransport, and heat capacity on a prototypical heavy fermion system, in which antiferromagnetism and superconductivity are observed. Monitoring the response of these states to the presence of the other, as well as to external thermal and magnetic perturbations, points to the possibility that they emerge from different parts of the Fermi surface. Therefore, a single 4f state could be both localized and itinerant, thus accounting for the coexistence of magnetism and superconductivity.

Thompson, Joe E [Los Alamos National Laboratory; Nair, S [MAX PLANCK INST.; Stockert, O [MAX PLANCK INST.; Witte, U [INST. FUR FESTKORPERPHYSIK; Nicklas, M [MAX PLANCK INST.; Schedler, R [HELMHOLTZ - ZENTRUM; Bianchi, A [UC, IRVINE; Fisk, Z [UC, IRVINE; Wirth, S [MAX PLANCK INST.; Steglich, K [HELMHOLTZ - ZENTRUM

2009-01-01T23:59:59.000Z

208

Method of improving fuel cell performance by removing at least one metal oxide contaminant from a fuel cell electrode  

DOE Patents [OSTI]

A method of removing contaminants from a fuel cell catalyst electrode. The method includes providing a getter electrode and a fuel cell catalyst electrode having at least one contaminant to a bath and applying a voltage sufficient to drive the contaminant from the fuel cell catalyst electrode to the getter electrode. Methods of removing contaminants from a membrane electrode assembly of a fuel cell and of improving performance of a fuel cell are also provided.

Kim, Yu Seung (Los Alamos, NM); Choi, Jong-Ho (Los Alamos, NM); Zelenay, Piotr (Los Alamos, NM)

2009-08-18T23:59:59.000Z

209

Functional Mesoporous Metal-Organic Frameworks for the Capture of Heavy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest Region service area. TheEPSCI HomeTours,Frequently AskedInformationMetal Ions

210

Coupling and Testing the Fate and Transport of Heavy Metals and Other Ionic Species in a Groundwater Setting at Oak Ridge, TN - 13498  

SciTech Connect (OSTI)

Historical data show that heavy metals (including mercury) were released from Y -12 National Security Complex (NSC) at Oak Ridge, Tennessee, to the surrounding environments during its operation in 1950's. Studies have also shown that metals accumulated in the soil, rock, and groundwater, and are, at the present time, sources of contamination to nearby rivers and creeks (e.g., East Fork Poplar Creek, Bear Creek). For instance, mercury (Hg), zinc (Zn), cadmium (Cd) and lead (Pb) have been found and reported on the site groundwater. The groundwater type at the site is Ca-Mg-HCO{sub 3}. This paper presents a modeling application of PHREEQC, a model that simulates geochemical processes and couples them to flow and transport settings. The objective was to assess the capability of PHREEQC to simulate the transport of ionic species in groundwater at Oak Ridge, Tennessee; data were available from core holes and monitoring wells over a 736-m distance, within 60-300 m depths. First, predictions of the transport of major ionic species (i.e., Ca{sup 2+} and Mg{sup 2+}) in the water were made between monitoring wells and for GW-131. Second, the model was used to assess hypotheses under two scenarios of transport for Zn, Cd, Pb and Hg, in Ca-Mg-HCO{sub 3} water, as influenced by the following solid-liquid interactions: a) the role of ion exchange and b) the role of both ion exchange and sorption, the latter via surface complexation with Fe(OH){sub 3}. The transport scenario with ion exchange suggests that significant ion exchange is expected to occur for Zn, Cd and Pb concentrations, with no significant impact on Hg, within the first 100 m. Predictions match the expected values of the exchange coefficients relative to Ca{sup 2+} and Mg{sup 2+} (e.g., K{sub Ca/Zn} = K{sub Ca/Cd} > K{sub Ca/Pb} > K{sub Ca/Hg}). The scenario with both ion exchange and sorption does affect the concentrations of Zn and Cd to a small extent within the first 100 m, but does more meaningfully reduce the concentration of Pb, within the same distance, and also decreases the concentration of Hg in between core holes. Analysis of the above results, in the light of available literature on the ions of this study, does fundamentally support the capability of PHREEQC to predict the transport of major ions in a groundwater setting; it also generally supports the hypothesized role of ion exchange and sorption. The results indicate the potential of the model as a tool in the screening, selection and monitoring of remediation technologies for contaminated groundwater sites. (authors)

Noosai, Nantaporn; Fuentes, Hector R. [CEE Florida International University, Miami, FL 33174 (United States)] [CEE Florida International University, Miami, FL 33174 (United States)

2013-07-01T23:59:59.000Z

211

Cadmium, copper, and lead in soils and garden produce near a metal smelter at Flin Flon, Manitoba  

SciTech Connect (OSTI)

Towns in the vicinity of base metal smelters are subject to contamination from atmospheric fallout containing heavy metals. Many smelters have been in operation for decades, and have resulted in substantial accumulation of metals in the surrounding soils. Metal contamination of edible vegetation near mines and smelters has been the source of health concerns in a number of countries. One smelter that has operated for more than half a century is located at Flin Flon, Manitoba. Many Flin Flon residents utilize home vegetable gardens year after year. However little is known regarding heavy metal contamination of locally grown garden produce. Since food can contribute as much as 90% of total body uptake of metals it is important to identify any sources which may account for the disproportionate share. The objective of the present study was to examine concentrations of cadmium, copper and lead in soils and garden produce in the vicinity of the Flin Flon smelter.

Pip, E. (Univ. of Winnipeg, Manitoba (Canada))

1991-05-01T23:59:59.000Z

212

Heavy Element Abundances in Presolar Silicon Carbide Grains from Low-Metallicity AGB Stars  

E-Print Network [OSTI]

Primitive meteorites contain small amounts of presolar minerals that formed in the winds of evolved stars or in the ejecta of stellar explosions. Silicon carbide is the best studied presolar mineral. Based on its isotopic compositions it was divided into distinct populations that have different origins: Most abundant are the mainstream grains which are believed to come from 1.5-3 Msun AGB stars of roughly solar metallicitiy. The rare Y and Z grains are likely to come from 1.5-3 Msun AGB stars as well, but with subsolar metallicities (0.3-0.5x solar). Here we report on C and Si isotope and trace element (Zr, Ba) studies of individual, submicrometer-sized SiC grains. The most striking results are: (1) Zr and Ba concentrations are higher in Y and Z grains than in mainstream grains, with enrichments relative to Si and solar of up to 70x (Zr) and 170x (Ba), respectively. (2) For the Y and Z grains there is a positive correlation between Ba concentrations and amount of s-process Si. This correlation is well explain...

Hoppe, P; Vollmer, C; Groener, E; Heck, P R; Gallino, R; Amari, S; 10.1071/AS08033

2009-01-01T23:59:59.000Z

213

The simulation of condensation removal of a heavy metal from exhaust gases onto sorbent particles  

SciTech Connect (OSTI)

A numerical model BAEROSOL for solving the general dynamic equation (GDE) of aerosols is presented. The goal was to model the capture of volatilized metals by sorbents under incinerator-like conditions. The model is based on algorithms presented by Jacobson and Turco [Aerosol Science and Technology 22 (1995) 73]. A hybrid size bin was used to model growth and formation of particles from the continuum phase and the coagulation of existing particles. Condensation and evaporation growth were calculated in a moving size bin approach, where coagulation and nucleation was modeled in the fixed size bin model of the hybrid grid. To account for the thermodynamic equilibrium in the gas phase, a thermodynamic equilibrium code CET89 was implemented. The particle size distribution (PSD) calculated with the model was then compared to analytical solutions provided for growth, coagulation and both combined. Finally, experimental findings by Rodriguez and Hall [Waste Management 21 (2001) 589-607] were compared to the PSD predicted by the developed model and the applicability of the model under incineration conditions is discussed.

Rodriguez, A.; Hall, M.J

2003-07-01T23:59:59.000Z

214

Functional gene array-based analysis of microbial community structure in groundwaters with a gradient of contaminant levels  

SciTech Connect (OSTI)

To understand how contaminants affect microbial community diversity, heterogeneity, and functional structure, six groundwater monitoring wells from the Field Research Center of the U.S. Department of Energy Environmental Remediation Science Program (ERSP; Oak Ridge, TN), with a wide range of pH, nitrate, and heavy metal contamination were investigated. DNA from the groundwater community was analyzed with a functional gene array containing 2006 probes to detect genes involved in metal resistance, sulfate reduction, organic contaminant degradation, and carbon and nitrogen cycling. Microbial diversity decreased in relation to the contamination levels of the wells. Highly contaminated wells had lower gene diversity but greater signal intensity than the pristine well. The microbial composition was heterogeneous, with 17-70% overlap between different wells. Metal-resistant and metal-reducing microorganisms were detected in both contaminated and pristine wells, suggesting the potential for successful bioremediation of metal-contaminated groundwaters. In addition, results of Mantel tests and canonical correspondence analysis indicate that nitrate, sulfate, pH, uranium, and technetium have a significant (p < 0.05) effect on microbial community structure. This study provides an overall picture of microbial community structure in contaminated environments with functional gene arrays by showing that diversity and heterogeneity can vary greatly in relation to contamination.

Waldron, P.J.; Wu, L.; Van Nostrand, J.D.; Schadt, C.W.; Watson, D.B.; Jardine, P.M.; Palumbo, A.V.; Hazen, T.C.; Zhou, J.

2009-06-15T23:59:59.000Z

215

Fundamental Studies of the Removal of Contaminants from Ground and Waste Waters via Reduction by Zero-Valent Metals  

SciTech Connect (OSTI)

Contaminated groundwater and surface waters are a problem throughout the United States and the world. In many instances, the types of contamination can be directly attributed to man's actions. For instance, the burial of chemical wastes, casual disposal of solvents in unlined pits, and the development of irrigated agriculture have all contributed to groundwater and surface water contamination. The kinds of contaminants include chlorinated solvents and toxic trace elements (including radioisotopes) that are soluble and mobile in soils and aquifers. Oxyanions of uranium, selenium, chromium, arsenic, technetium, and chlorine (as perchlorate) are frequently found as contaminants on many DOE sites. Uranium is a particularly widespread contaminant at most DOE sites including Oak Ridge, Rocky Flats, Hanford, Idaho (INEEL), and Fernald. The uranium contamination is associated with mining and milling of uranium ore (UMTRA sites), isotope separation and enrichment, and mixed waste and TRU waste burial. In addition, the careless disposal of halogenated solvents, such as carbon tetrachloride and trichloroethylene, has further contaminated many groundwaters at these sites. A potential remediation method for many of these oxyanions and chlorinated-solvents is to react the contaminated water with zero-valent iron. In this reaction, the iron serves as both an electron source and as a catalyst. Elemental iron is already being used on an experimental basis at many DOE sites. Both in situ reactive barriers and above-ground reactors are being developed for this purpose. However, the design and operation of these treatment systems requires a detailed process-level understanding of the interactions between the contaminants and the iron surfaces. We are performing fundamental investigations of the interactions of the relevant chlorinated solvents and trace element-containing compounds with single- and poly-crystalline Fe surfaces. The aim of this work is to develop th e fundamental physical and chemical understanding that is necessary for the development of cleanup techniques and procedures.

Yarmoff, Jory A.; Amrhein, Christopher

1999-06-01T23:59:59.000Z

216

X-ray absorption spectroscopy study of the local structure of heavy metal ions incorporated into electrodeposited nickel oxide films  

SciTech Connect (OSTI)

The incorporation of heavy metal ions into simulated corrosion films has been investigated using spectroscopic and electrochemical techniques. The films were formed by electrodeposition of the appropriate oxide (hydroxide) onto a graphite substrate. Synchrotron X-ray absorption spectroscopy (XAS) was used to determine the structure and composition of the host oxide film, as well as the local structure of the impurity ion. Results on the incorporation of Ce and Sr into surface films of Ni(OH){sub 2} and NiOOH are reported. Cathodically deposited Ni(OH){sub 2} was found to be mainly in the alpha form while anodically prepared NiOOH showed the presence of Ni{sup +2} and Ni{sup +4}. Cerium incorporated into Ni(OH){sub 2} exists as mixed Ce{sup +3} and Ce{sup +4} phases; a Ce{sup +4} species was found when Ce was codeposited with NiOOH. The structure of the Ce{sup +4} phase in anodic films appears similar to a Ce(OH){sub 4} standard. However, XAS, X-ray diffraction, and laser Raman measurements indicate that the latter chemical formulation is probably incorrect and that the material is really a disordered form of hydrous cerium oxide. The local structure of this material is similar to CeO{sub 2} but has much higher structural disorder. The significance of this finding on the question of the structure of Ce-based corrosion inhibitors in aluminum oxide films is pointed out. Moreover, the authors found it possible to form pure Ce oxide (hydroxide) films on graphite by both cathodic and anodic electrodeposition; their structures have also been elucidated. Strontium incorporated into nickel oxide films consists of Sr{sup +2} which is coordinated to oxygen atoms and is likely to exist as small domains of coprecipitated material.

Balasubramanian, M.; Melendres, C.A. [Argonne National Lab., IL (United States). Chemical Technology Div.] [Argonne National Lab., IL (United States). Chemical Technology Div.; Mansour, A.N. [Naval Surface Warfare Center, Bethesda, MD (United States). Carderock Div.] [Naval Surface Warfare Center, Bethesda, MD (United States). Carderock Div.

1999-02-01T23:59:59.000Z

217

Response to ISRP Comments for Project 35044 Determine the Effects of Contaminants on White Sturgeon Reproduction and Parental Transfer  

E-Print Network [OSTI]

, such as dioxins, furans, and heavy metals. Significant contamination of the upper Columbia River and the Kootenai was acutely toxic to rainbow trout (CRIEMP, 1994). Chlorinated dioxins and furans, although not detectable dioxin and furan regulations. Cominco has been operating since 1906 (MacDonald Environmental Sciences Ltd

218

Portable spotter for fluorescent contaminants on surfaces  

DOE Patents [OSTI]

A portable fluorescence-based spotter for polynuclear aromatic hydrocarbon contamination on personnel and work area surfaces under ambient lighting conditions is provided. This instrument employs beam modulation and phase sensitive detection for discriminating between fluorescence from organic materials from reflected background light and inorganic fluorescent material. The device uses excitation and emission filters to provide differentiation between classes of aromatic organic compounds. Certain inorganic fluorescent materials, including heavy metal compounds, may also be distinguished from the organic compounds, despite both having similar optical properties.

Schuresko, Daniel D. (Oak Ridge, TN)

1980-01-01T23:59:59.000Z

219

Lead and cadmium speciation in smelter-contaminated soil  

SciTech Connect (OSTI)

The design of a {open_quotes}washing{close_quotes} process for the removal and recovery of heavy metals from contaminated soil requires in-depth knowledge of the speciation of the metals. In addition to being present in their original forms (e.g. oxides particulates emitted by a smelter), the contaminating metals may come to be associated with a variety of solid phases commonly present in soil. The {open_quotes}standard{close_quotes} speciation analysis, a series of sequential chemical extractions, has been examined critically, and several improvements to the procedure have been examined. Also, the procedure has been used to characterize samples collected in the vicinity of a zinc smelter that has been in operation for nearly 80 years.

Bergers, M.; Harris, T. [Univ. of Tulsa, OK (United States)

1995-12-01T23:59:59.000Z

220

EVALUATION OF THE METALLIC CONTAMINATION IMPACT ON 'MYTILUS EDULIS' MUSSEL AT THE LEVEL OF THE MOUTH OF  

E-Print Network [OSTI]

for manganese, chromium and cadmium. Seven trace metals (Mn, Cu, Cr, Pb, Co, Fe and Cd) were detected selective way. Keywords: Mytilus edulis; Trace metals; Bioaccumulation; Bioindicator. 1. INTRODUCTION Oued slopes of the Rif range and from the north western slopes of the middle Atlas. It lies between the 33rd

Paris-Sud XI, Université de

Note: This page contains sample records for the topic "heavy metal contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Selected heavy metals in tissues of bottlenose dolphins (Tursiops truncatus) stranded along thr Texas and Florida Gulf coasts  

E-Print Network [OSTI]

of bottlenose dolphins in other geographic regions. Two metal-metal correlations were examined in liver, kidney and muscle tissue. Strong positive correlations were found between mercury and selenium in the three tissues. No correlations existed between cadmium...

Haubold, Elsa Maria

1995-01-01T23:59:59.000Z

222

Fundamental Studies of The Removal of Contaminants from Ground and Waste Waters Via Reduction By Zero-Valent metals  

SciTech Connect (OSTI)

Oxyanions of uranium, selenium, chromium, arsenic, technetium, and chlorine (as perchlorate) are frequently found as contaminants on many DOE sites, and in other areas of the U.S.. A potential remediation method is to react the contaminated water with zero-valent iron (ZVI). We are performing fundamental investigations of the interactions of the relevant compounds with Fe filings and single- and poly-crystalline surfaces. The aim of this work is to develop the physical and chemical understanding that is necessary for the development of cleanup techniques and procedures.

Jory A. Yarmoff; Christopher Amrhein

2002-04-23T23:59:59.000Z

223

Complete Genome Sequence of Rahnella sp Strain Y9602, a Gammaproteobacterium Isolate from Metal- and Radionuclide-Contaminated Soil  

SciTech Connect (OSTI)

Rahnella sp. strain Y9602 is a gammaproteobacterium isolated from contaminated subsurface soils that is capable of promoting uranium phosphate mineralization as a result of constitutive phosphatase activity. Here we report the first complete genome sequence of an isolate belonging to the genus Rahnella.

Martinez, Robert J [University of Alabama, Tuscaloosa; Bruce, David [Los Alamos National Laboratory (LANL); Detter, J. Chris [U.S. Department of Energy, Joint Genome Institute; Goodwin, Lynne A. [Los Alamos National Laboratory (LANL); Han, James [U.S. Department of Energy, Joint Genome Institute; Han, Cliff [Los Alamos National Laboratory (LANL); Held, Brittany [Los Alamos National Laboratory (LANL); Mikhailova, Natalia [U.S. Department of Energy, Joint Genome Institute; Nolan, Matt [U.S. Department of Energy, Joint Genome Institute; Pennacchio, Len [U.S. Department of Energy, Joint Genome Institute; Pitluck, Sam [U.S. Department of Energy, Joint Genome Institute; Tapia, Roxanne [Los Alamos National Laboratory (LANL); Woyke, Tanja [U.S. Department of Energy, Joint Genome Institute; Sobeckya, Patricia A. [University of Alabama, Tuscaloosa

2012-01-01T23:59:59.000Z

224

Batch sorption of divalent metal ions onto brown coal  

SciTech Connect (OSTI)

Brown coal, a relatively abundant and inexpensive material is currently being investigated as an adsorbent to remove some contaminants from aqueous solution. The adsorption of some heavy metals from aqueous solutions on the brown coals was studied as a function of pH, contact time, adsorbent dosage and concentration of metal solutions. A carboxyl, phenolic hydroxyl, and metoxyl functional group present on the coal surface was the adsorption site to remove metal ions from solution by means of ion exchange and hydrogen bonding. Effective removal of heavy metals was achieved at pH values of 4.0-5.0. The experimental data have been analyzed using the Langmuir isotherm models. Under optimized conditions, the percentage of metal removal by brown coal adsorption was over 80%.

Pehlivan, E.; Gode, F. [University of Selcuk, Konya (Turkey). Faculty of Engineering & Architecture

2006-12-15T23:59:59.000Z

225

anion heavy-atom salt: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of nutrients and heavy metals in experimental salt marsh ecosystems. Environmental Pollution,effects of nutrients and heavy metals in experimental salt marsh ecosystems....

226

Analytical and experimental investigations of the behavior of thermal neutrons in lattices of uranium metal rods in heavy water  

E-Print Network [OSTI]

Measurements of the intracellular distribution of the activation of foils by neutrons were made in lattices of 1/4-inch diameter, 1.03% U-235, uranium rods moderated by heavy water, with bare and cadmium-covered foils of ...

Simms, Richard

1963-01-01T23:59:59.000Z

227

ISSN 0378-4738 = Water SA Vol. 27 No. 1 January 2001 71Available on website http://www.wrc.org.za Plant-soil interactions of sludge-borne heavy metals and the  

E-Print Network [OSTI]

ISSN 0378-4738 = Water SA Vol. 27 No. 1 January 2001 71Available on website http://www.wrc.org.za Plant-soil interactions of sludge-borne heavy metals and the effect on maize (Zea mays L.) seedling, Pretoria 0001, South Africa 2 ERWAT Chair in Wastewater Management, Water Utilisation Section, Department

228

Treatment of Mercury Contaminated Oil from the Mound Site  

SciTech Connect (OSTI)

Over one thousand gallons of tritiated oil, at various contamination levels, are stored in the Main Hill Tritium Facility at the Miamisburg Environmental Management Project (MEMP), commonly referred to as Mound Site. This tritiated oil is to be characterized for hazardous materials and radioactive contamination. Most of the hazardous materials are expected to be in the form of heavy metals, i.e., mercury, silver, lead, chromium, etc, but transuranic materials and PCBs could also be in some oils. Waste oils, found to contain heavy metals as well as being radioactively contaminated, are considered as mixed wastes and are controlled by Resource Conservation and Recovery Act (RCRA) regulations. The SAMMS (Self-Assembled Mercaptan on Mesoporous Silica) technology was developed by the Pacific Northwest National Laboratory (PNNL) for removal and stabilization of RCRA metals (i.e., lead, mercury, cadmium, silver, etc.) and for removal of mercury from organic solvents. The SAMMS material is based on self-assembly of functionalized monolayers on mesoporous oxide surfaces. The unique mesoporous oxide supports provide a high surface area, thereby enhancing the metal-loading capacity. SAMMS material has high flexibility in that it binds with different forms of mercury, including metallic, inorganic, organic, charged, and neutral compounds. The material removes mercury from both organic wastes, such as pump oils, and from aqueous wastes. Mercury-loaded SAMMS not only passes TCLP tests, but also has good long-term durability as a waste form because: (1) the covalent binding between mercury and SAMMS has good resistance in ion-exchange, oxidation, and hydrolysis over a wide pH range and (2) the uniform and small pore size of the mesoporous silica prevents bacteria from solubilizing the bound mercury.

Klasson, KT

2000-11-09T23:59:59.000Z

229

Contamination of the agricultural land due to industrial activities southern of greater Cairo  

SciTech Connect (OSTI)

The industrial processes in the investigated area include ferrous and non-ferrous metallurgical work, ceramics, fire bricks, cement industry, etc. Soil, weeds, vegetation and dust samples were collected and analysed for several heavy metals. High levels of Pb, Cd, Ni, Cr, Mn and zinc found in the soil close to a lead, zinc smelter. In the heavy contaminated area concentrations of more than 500 ug/g Pb, 1200 ug/g zinc and 50 ug/g Ni and Cd were recorded in the surface soil at 1500 m from the smelter. The concentrations of the heavy metals in the contaminated area (3-5) km from the smelter reached more than 200 ug/g Pb and 25 ug/g Ni and Cd and 160 ug/g zinc. Higher levels of these toxic elements were found in the dust on the leaves of the examined vegetations. Furthermore, accumulated concentrations reached more than 100 ug/g Pb and 10 ug/g Cd in leaves of herbs and maize. Soil close to cement industry found enriched with heavy metals but it is much less pronounced. 10 refs., 3 figs., 5 tabs.

Ali, E.A.; Ibrahim, Y.H.; Nasralla, M.M. (National Research Centre, Cairo (Egypt))

1992-01-01T23:59:59.000Z

230

Effects of heavy metals in sediments on the macroinvertebrate community in the Short Creek/Empire Lake aquatic system, Cherokee County, Kansas: A recommendation for site-specific criteria. Technical report (Final)  

SciTech Connect (OSTI)

This study uses statistical analysis techniques to determine the effects of four heavy metals (cadmium, lead, manganese, and zinc) on the macroinvertebrate community using the data collected in the fall 1987. The concentrations of all four metals were found to be greatly elevated throughout Empire Lake and in both the Spring River and Shoal Creek arms of the reservoir. It is concluded that density and species richness were greatly reduced. The report also includes recommendations for the upper bounds for the sediment criteria of the four metals.

Jobe, J.

1988-10-01T23:59:59.000Z

231

A Heavy Metal Atmospheric Deposition Study Around the Lead and Copper-Zinc Smelters in Baia Mare, Romania, Employing the Moss Biomonitoring Technique, ENAA and FAAS  

E-Print Network [OSTI]

The mosses Pleurozium schreberi, Pseudoscleropodium purum and Rhytidiadelphus squarrosus were used as biomonitors to study the atmospheric deposition of metals around the lead and copper-zinc smelters in Baia Mare. Samples representing the last three years' growth of moss or its green part, collected on the ground at 28 sites located 2-20 km from the source area, were analyzed by instrumental neutron activation analysis using epithermal neutrons (ENAA) and by flame atomic absorption spectrometry (FAAS). A total of 30 elements were determined, including most of the heavy metals known to be released into the air from this kind of industry. Obtained concentrations for As and Cu are comparable with those observed in Karabash, South Ural Mountains, one of the most polluted regions in Europe. Besides, these two elements correlate very well with each other. The mean values for Zn (136 ppm) and Pb (41 ppm) are substantially higher than those normally found in the literature. The highest value for Pb (175 ppm) was obs...

Culicov, O A; Steinnes, E; Okina, O S; Santa, Z; Todoran, R

2001-01-01T23:59:59.000Z

232

Metal and arsenic impacts to soils, vegetation communities and wildlife habitat in southwest Montana uplands contaminated by smelter emissions. 2: Laboratory phytotoxicity studies  

SciTech Connect (OSTI)

Vegetation communities on metal- and arsenic-contaminated uplands surrounding a smelter in southwest Montana have been eliminated or highly modified. Laboratory toxicity tests were performed using site soils from the impacted areas to determine whether the soils limit the ability of plants to establish and grow. The germination and growth of alfalfa, lettuce, and wheat in impacted area soils was compared to germination and growth of the three species in reference soils. The degree of phytotoxicity was quantified using a species-endpoint toxicity score calculated on the magnitude of difference between germination and growth of plants in impacted and reference soils. The impacted soils exhibited substantial toxicity to plants: 5% of the sites were severely phytotoxic, 55% were highly phytotoxic, 10% were moderately phytotoxic, 20% were mildly phytotoxic, and 10% were nontoxic. Root growth was consistently the most affected endpoint (18 of 20 impacted soils) and reduction in root length and mass was observed. Correlation and partial correlation analysis was used to evaluate the causes of phytotoxicity. Concentrations of As, Cu, and Zn and, to a lesser extent, Pb and Cd were found to be positively correlated with phytotoxicity.

Kapustka, L.A. [Ecological Planning and Toxicology, Inc., Corvallis, OR (United States); Lipton, J.; Galbraith, H.; Cacela, D.; LeJeune, K. [Hagler Bailly Consulting, Inc., Boulder, CO (United States)

1995-11-01T23:59:59.000Z

233

Equilibrium metal concentration at zero net sorption (EMC{sub 0}): A new concept  

SciTech Connect (OSTI)

Heavy metals in soils and waters are of environmental concerns. Since total concentration of a metal in soil is not directly related to its bioavailability, soil tests rely on measurement of extractable or labile fractions of metals. However, reagents used in the measurements are significantly different from natural waters entering soils in terms of ionic strength, acidity, and heavy metal concentration, making the direct interpretation of test results difficult if correlation between chemical test data and plant response in the field is not available. It is suggested that EMC{sub 0} be used as an indicator of heavy metal status in soils. EMC{sub 0} can be determined as follows: solutions with various metal concentrations (C{sub 0}) in 0.005 M CaCl{sub 2} matrix are added to soil samples at a fixed soil/solution ratio. The suspensions are shaken 24 hrs to achieve equilibrium, and centrifuged. Metal concentrations in supernatants are analyzed and plotted against C{sub 0}. A regression line based on plotted data an da 1:1 line are drawn. The X-axis value corresponding t the intersection of the liens is EMC{sub 0}. At the intersection, metal concentration at equilibrium equals that in the initial solution; indicating net sorption of the metal is zero. A EMC{sub 0} value of 0.27 mg/kg Zn was determined in a soil sample from the Fraser Valley in British Columbia. The soil received heavy applications of poultry manure.This value is much greater than water soluble Zn (0.06 mg/kg) of the sample. The significance of EMC{sub 0} is when concentrations of a metal in natural waters are less than EMC{sub 0}, soil will release the metal to soil solution. EMC{sub 0} may be useful in comparing relative degrees of contamination in contaminated soils.

Yuan, G.; Lavkulich, L.M. [Univ. of British Columbia, Vancouver, British Columbia (Canada). Dept. of Soil Sciences

1995-12-31T23:59:59.000Z

234

Availability and distribution of heavy metals, nitrogen, and phosphorus from sewage sludge in the plant-soil-water continuum  

SciTech Connect (OSTI)

Research was conducted during 1984 and 1985 to determine Cd, Cu, N, Ni, P, and Zn availabilities to barley (Hordeum vulgare) and corn (Zea mays) grown on four sludge-amended soils. An aerobically digested sewage sludge, which was dewatered for approximately 2 years on sandbeds, was obtained from a sewage-treatment plant with major industrial inputs. A 14-day anaerobic N incubation study indicated that mineralization of sludge organic N varied from 9.2% at the 42 Mg ha(-1) sludge rate to 4.2% at the 210 Mg ha(-1) rate. This relatively low percentage of N mineralized from the sludge may reflect the inhibitory effects of the high sludge-metal levels on N transformations and the changes in sludge composition during long-term dewatering on sandbeds. Sludge application increased crop yields, except where the amounts of N mineralized from the sludge was inadequate to supply the N requirement of the crop. Crop yields were not decreased by either metal phytotoxity or P deficiency on the four sludge-amended soils.

Rappaport, B.D.; Scott, J.D.; Martens, D.C.; Reneau, R.B.; Simpson, T.W.

1987-01-01T23:59:59.000Z

235

Association of the sites of heavy metals with nanoscale carbon in a Kentucky electrostatic precipitator fly ash  

SciTech Connect (OSTI)

A combination of high-resolution transmission electron microscopy, scanning transmission electron microscopy, and electron energy-loss spectroscopy (HRTEM-STEM-EELS) was used to study fly ashes produced from the combustion of an eastern Kentucky coal at a southeastern-Kentucky wall-fired pulverized coal utility boiler retrofitted for low-NOx combustion. Fly ash was collected from individual hoppers in each row of the electrostatic precipitators (ESP) pollution-control system, with multiple hoppers sampled within each of the three rows. Temperatures within the ESP array range from about 200 {degree}C at the entry to the first row to <150{degree}C at the exit of the third row. HRTEM-STEM-EELS study demonstrated the presence of nanoscale (10 s nm) C agglomerates with typical soot-like appearance and others with graphitic fullerene-like nanocarbon structures. The minute carbon agglomerates are typically juxtaposed and intergrown with slightly larger aluminosilicate spheres and often form an ultrathin halo or deposit on the fly ash particles. The STEM-EELS analyses revealed that the nanocarbon agglomerates host even finer (<3 nm) metal and metal oxide particles. Elemental analysis indicated an association of Hg with the nanocarbon. Arsenic, Se, Pb, Co, and traces of Ti and Ba are often associated with Fe-rich particles within the nanocarbon deposits. 57 refs., 5 figs.

James C. Hower; Uschi M. Graham; Alan Dozier; Michael T. Tseng; Rajesh A. Khatri [University of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

2008-11-15T23:59:59.000Z

236

Bioavailability of Cadmium and Zin to Two Earthworm Species in High-metal Soils  

E-Print Network [OSTI]

S.P. 1998. Toxicity of heavy metals to microorganism andtoxicity (Kizilkaya, Earthworms influence on heavy metalsof heavy metals in soil, is crucial to predict metals toxic

Liu, Ying

2012-01-01T23:59:59.000Z

237

Metal behavior during fluidized bed thermal treatment of soil  

SciTech Connect (OSTI)

The Superfund dumpsites are frequently composed of soils contaminated with hazardous organic constituents and toxic heavy metals. While thermal treatment is an effective method of remediating the contaminated soils, the major environmental concerns are the emissions of toxic metal fumes during the treatment and the leaching of metals from the treated soil. The US EPA has reported that metals can account for almost all of the identified cancer risks from waste incineration systems. Research leading to better understanding of their behavior and better controlling of their emissions is urgently needed. In this study, the behavior of metals during the fluidized bed thermal treatment of artificially prepared metal-contaminated clay was experimentally and theoretically investigated. The objective of the study was to evaluate the effects of operating conditions on metal volatilization and metal leachability associated with the process. Metal experiments were carried out in a well instrumented 76 mm (3 inch) i.d. fluidized bed incinerator. The metals involved were compounds of lead and cadmium and the operating parameters included metal concentration, air flow rate, treatment temperature and treatment duration. The observed results indicated that metal volatilization is mainly a function of treatment temperature and treatment duration. The degree of volatilization was observed to range from 5 to 40% depending on the operating conditions. Cadmium leachability was observed to be relatively high compared to that of lead. In addition to the experimental study, a theoretical model based on the laws of heat and mass transfer operations and reaction kinetics was derived to simulate the metal volatilization process. The derived model was found to predict reasonably well the experimental observations.

Ho, T.C.; Lee, H.T.; Shiao, C.C.; Hopper, J.R. [Lamar Univ., Beaumont, TX (United States). Dept. of Chemical Engineering] [Lamar Univ., Beaumont, TX (United States). Dept. of Chemical Engineering; Bostick, W.D. [Martin Marietta Energy Systems, Inc., Oak Ridge, TN (United States). Chemistry Dept.] [Martin Marietta Energy Systems, Inc., Oak Ridge, TN (United States). Chemistry Dept.

1995-12-31T23:59:59.000Z

238

In vitro profiling of epigenetic modifications underlying heavy metal toxicity of tungsten-alloy and its components  

SciTech Connect (OSTI)

Tungsten-alloy has carcinogenic potential as demonstrated by cancer development in rats with intramuscular implanted tungsten-alloy pellets. This suggests a potential involvement of epigenetic events previously implicated as environmental triggers of cancer. Here, we tested metal induced cytotoxicity and epigenetic modifications including H3 acetylation, H3-Ser10 phosphorylation and H3-K4 trimethylation. We exposed human embryonic kidney (HEK293), human neuroepithelioma (SKNMC), and mouse myoblast (C2C12) cultures for 1-day and hippocampal primary neuronal cultures for 1-week to 50-200 {mu}g/ml of tungsten-alloy (91% tungsten/6% nickel/3% cobalt), tungsten, nickel, and cobalt. We also examined the potential role of intracellular calcium in metal mediated histone modifications by addition of calcium channel blockers/chelators to the metal solutions. Tungsten and its alloy showed cytotoxicity at concentrations > 50 {mu}g/ml, while we found significant toxicity with cobalt and nickel for most tested concentrations. Diverse cell-specific toxic effects were observed, with C2C12 being relatively resistant to tungsten-alloy mediated toxic impact. Tungsten-alloy, but not tungsten, caused almost complete dephosphorylation of H3-Ser10 in C2C12 and hippocampal primary neuronal cultures with H3-hypoacetylation in C2C12. Dramatic H3-Ser10 dephosphorylation was found in all cobalt treated cultures with a decrease in H3 pan-acetylation in C2C12, SKNMC and HEK293. Trimethylation of H3-K4 was not affected. Both tungsten-alloy and cobalt mediated H3-Ser10 dephosphorylation were reversed with BAPTA-AM, highlighting the role of intracellular calcium, confirmed with 2-photon calcium imaging. In summary, our results for the first time reveal epigenetic modifications triggered by tungsten-alloy exposure in C2C12 and hippocampal primary neuronal cultures suggesting the underlying synergistic effects of tungsten, nickel and cobalt mediated by changes in intracellular calcium homeostasis and buffering. - Highlights: > Tungsten-alloy caused H3-Ser10 dephosphorylation in C2C12 and hippocampal primary cultures. > Dramatic H3-Ser10 dephosphorylation was found in all cobalt treated cultures. > C2C12 cultures exposed to tungsten-alloy or cobalt exhibited decrease in H3 pan-acetylation. > Tungsten-alloy and cobalt mediated H3-Ser10 dephosphorylation was reversed with BAPTA-AM. > These epigenetic modifications were mediated by changes in calcium homeostasis and buffering.

Verma, Ranjana, E-mail: Ranjana.Verma.CTR@usuhs.mil [Anatomy, Physiology and Genetics, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Center for Neuroscience and Regenerative Medicine, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Xu, Xiufen, E-mail: Xiufen.Xu.CTR@usuhs.mil [Anatomy, Physiology and Genetics, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Jaiswal, Manoj K., E-mail: Manoj.Jaiswal.CTR@usuhs.mil [Anatomy, Physiology and Genetics, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Center for Neuroscience and Regenerative Medicine, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Olsen, Cara, E-mail: colsen@usuhs.mil [Department of Preventive Medicine and Biometrics, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Mears, David, E-mail: dmears@usuhs.mil [Anatomy, Physiology and Genetics, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Caretti, Giuseppina, E-mail: giuseppina.caretti@unimi.it [Department of Biomolecular Sciences and Biotechnology, University of Milan (Italy); Galdzicki, Zygmunt, E-mail: zgaldzicki@usuhs.mil [Anatomy, Physiology and Genetics, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Center for Neuroscience and Regenerative Medicine, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States)

2011-06-15T23:59:59.000Z

239

An Estimate of the Order of Magnitude of the Explosion During a Core Meltdown-Compaction Accident for Heavy Liquid Metal Fast Reactors: A disquieting result updating the Bethe-Tait model  

E-Print Network [OSTI]

but lasting over a timescale of milliseconds. The forms of the energy release and of the resulting struc- tural damage differ significantly between a high explosive detonation and a propellant conflagration. Considering the yield of TNT Containment Law... gravitational compaction of the 100 MWth core, the ves- sel could withstand the 60 kg TNT-equivalent explosion from a 100 $/s reactivity insertion if a bare core is as- sumed; however, allowing for the presence of the unboiled heavy liquid metal coolant...

Arias, Francisco J.; Parks, Geoffrey T.

2014-12-09T23:59:59.000Z

240

SciTech Connect: Metal-Organic Framework Templated Inorganic...  

Office of Scientific and Technical Information (OSTI)

Metal-Organic Framework Templated Inorganic Sorbents for Rapid and Efficient Extraction of Heavy Metals Citation Details In-Document Search Title: Metal-Organic Framework Templated...

Note: This page contains sample records for the topic "heavy metal contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

E-Print Network 3.0 - affecting metal concentration Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the water and often in concentrations several times higher than in the ambient water. Heavy metals are taken... of these heavy metals are concentrated at ... Source:...

242

Long-Term Stewardship of Mixed Wastes: Passive Reactive Barriers for Simultaneous In Situ Remediation of Chlorinated Solvent, Heavy Metal, and Radionuclide Contaminants  

SciTech Connect (OSTI)

This project report summarizes the results of a 3-way collaboration between researchers at Montana State Universitys (MSUs) Center for Biofilm Engineering (CBE) (Drs. Robin Gerlach and Al Cunningham), the WSU/NSF IGERT Center for Multiphase Environmental Research (CMER) at Washington State University (WSU) (Dr. Brent Peyton who recently moved to MSU), and the Idaho National Laboratory (INL) (Drs. William Apel and Frank Roberto). At WSU, removal of uranium (U) from aqueous solution was studied using Cellulomonas sp. strain ES6, under anaerobic, non-growth conditions. The Cellulomonadaceae are environmentally relevant subsurface bacteria, and strain ES6 was isolated from the DOE Hanford subsurface. To better understand the role of the pH buffer in the U immobilization process, both bicarbonate and PIPES buffers were used. Our results show for the first time the strain ES6 has multiple U immobilization mechanisms within one organism. Citations to resulting publications are included in the report.

Peyton, Brent, M.; Gerlach, Robin; Cunningham, Al, B.; Apel, William, A.; Roberto, Francisco

2007-12-04T23:59:59.000Z

243

Long-Term Stewardship of Mixed Wastes: Passive Reactive Barriers for Simultaneous In Situ Remediation of Chlorinated Solvent, Heavy Metal, and Radionuclide Contaminants  

SciTech Connect (OSTI)

The collaborative project was designed to evaluate the possibility developing a subsurface remediation technology for mixed wastes at Department of Energy sites using a group of common soil bacteria of the genus Cellulomonas. We have been gaining a better understanding of microbial transformation of chromium, uranium, iron minerals, and trinitrotoluene (TNT) by Cellulomonas spp. in simulated subsurface environments.

Gerlach, Robin; Cunningham, Al; Peyton, Brent

2005-06-01T23:59:59.000Z

244

Modeling Elution Histories of Copper and Lead from Contaminated Soil Treated by Poly,,amidoamine... Dendrimers  

E-Print Network [OSTI]

procedures; Heavy metals; Soil pollution; Soil treatment. In recent years, extraction of heavy metals from transport models do not simulate the dynamic leaching process of heavy metals desorbed by the water soluble soil treated by poly amidoamine dendrimers. In the model, the metal sorption sites of the soil were

Clement, Prabhakar

245

Mine waste contamination limits soil respiration rates: a case study using quantile regression  

E-Print Network [OSTI]

, the toxicity of heavy metals depends on soil acidity and organic matter because these factors strongly an environmental gradient. We quantified in situ soil respiration, pH, and heavy metal concentrations across a mine was limited with respect to both heavy metals and pH, and that both increased metals and increased acidity

Rilli, Matthias C.

246

Extraction process for removing metallic impurities from alkalide metals  

DOE Patents [OSTI]

A development is described for removing metallic impurities from alkali metals by employing an extraction process wherein the metallic impurities are extracted from a molten alkali metal into molten lithium metal due to the immiscibility of the alkali metals in lithium and the miscibility of the metallic contaminants or impurities in the lithium. The purified alkali metal may be readily separated from the contaminant-containing lithium metal by simple decanting due to the differences in densities and melting temperatures of the alkali metals as compared to lithium.

Royer, Lamar T. (Knoxville, TN)

1988-01-01T23:59:59.000Z

247

Radionuclides, Heavy Metals, and Polychlorinated Biphenyls in Soils Collected Around the Perimeter of Low-Level Radioactive Waste Disposal Area G during 2006  

SciTech Connect (OSTI)

Twenty-one soil surface samples were collected in March around the perimeter of Area G, the primary disposal facility for low-level radioactive solid waste at Los Alamos National Laboratory (LANL). Three more samples were collected in October around the northwest corner after elevated tritium levels were detected on an AIRNET station located north of pit 38 in May. Also, four soil samples were collected along a transect at various distances (48, 154, 244, and 282 m) from Area G, starting from the northeast corner and extending to the Pueblo de San Ildefonso fence line in a northeasterly direction (this is the main wind direction). Most samples were analyzed for radionuclides ({sup 3}H, {sup 238}Pu, {sup 239,240}Pu, {sup 241}Am, {sup 234}U, {sup 235}U, and {sup 238}U), inorganic elements (Al, Ba, Be, Ca, Cr, Co, Cu, Fe, Mg, Mn, Ni, K, Na, V, Hg, Zn, Sb, As, Cd, Pb, Se, Ag, and Tl) and polychlorinated biphenyl (PCB) concentrations. As in previous years, the highest levels of {sup 3}H in soils (690 pCi/mL) were detected along the south portion of Area G near the {sup 3}H shafts; whereas, the highest concentrations of {sup 241}Am (1.2 pCi/g dry) and the Pu isotopes (1.9 pCi/g dry for {sup 238}Pu and 5 pCi/g dry for {sup 239,240}Pu) were detected along the northeastern portions near the transuranic waste pads. Concentrations of {sup 3}H in three soil samples and {sup 241}Am and Pu isotopes in one soil sample collected around the northwest corner in October increased over concentrations found in soils collected at the same locations earlier in the year. Almost all of the heavy metals, with the exception of Zn and Sb in one sample each, in soils around the perimeter of Area G were below regional statistical reference levels (mean plus three standard deviations) (RSRLs). Similarly, only one soil sample collected on the west side contained PCB concentrations--67 {micro}g/kg dry of aroclor-1254 and 94 {micro}g/kg dry of aroclor-1260. Radionuclide and inorganic element concentrations in soils collected along a transect from Area G to the Pueblo de San Ildefonso fence line show that most contained concentrations of {sup 241}Am, {sup 238}Pu, and {sup 239,240}Pu above the RSRLs. Overall, all concentrations of radionuclides, heavy metals, and PCBs that were detected above background levels in soils collected around the perimeter of Area G and towards the Pueblo de San Ildefonso boundary were still very low and far below LANL screening levels and regulatory standards.

P. R. Fresquez

2007-02-28T23:59:59.000Z

248

Heavy Metal Humor: Reconsidering Carnival in Heavy Metal Culture  

E-Print Network [OSTI]

which is both serious and humorous at once, Anal Cunt draws on several carnivalesque behaviors. To dissect this bands performance, Powell augments Bakhtins carnivalesque theory with Richard Schechners theory of dark play and Johan Huizingas play...

Powell, Gary Botts

2013-06-05T23:59:59.000Z

249

Accumulation of Pb and Cu heavy metals in sea water, sediment, and leaf and root tissue of Enhalus sp. in the seagrass bed of Banten Bay  

SciTech Connect (OSTI)

Banten Bay in Indonesia is a coastal area which has been highly affected by human activity. Previous studies have reported the presence of lead (Pb) and copper (Cu) heavy metals in the seawater of this area. This study was conducted to measure the accumulation of Pb and Cu in seawater, sediment, leaf tissue, and root tissue of the seagrass species Enhalus sp. Sampling was conducted at two observation stations in Banten Bay: Station 1 (St.1) was located closer to the coastline and to industrial plants as source of pollution, while Station 2 (St.2) was located farther away offshore. At each station, three sampling points were established by random sampling. Field sampling was conducted at two different dates, i.e., on 29 May 2012 and 30 June 2012. Samples were processed by wet ashing using concentrated HNO{sub 3} acid and measured using Atomic Absorption Spectrometry (AAS). Accumulation of Pb was only detected in sediment samples in St.1, while Cu was detected in all samples. Average concentrations of Cu in May were as follows: sediment St.1 = 0.731 ppm, sediment St.2 = 0.383 ppm, seawater St.1 = 0.163 ppm, seawater St.2 = 0.174 ppm, leaf St.1 = 0.102 ppm, leaf St.2 = 0.132 ppm, root St.1= 0.139 ppm, and root St.2 = 0.075 ppm. Average measurements of Cu in June were: sediment St.1 = 0.260 ppm, leaf St.1 = 0.335 ppm, leaf St.2 = 0.301 ppm, root St.1= 0.047 ppm, and root St.2 = 0.060 ppm. In June, Cu was undetected in St.2 sediment and seawater at both stations. In May, Cu concentration in seawater exceeded the maximum allowable threshold for water as determined by the Ministry of the Environment. Spatial and temporal variation in Pb and Cu accumulation were most probably affected by distance from source and physical conditions of the environment (e.g., water current and mixing)

Fauziah, Faiza, E-mail: faiza.fauziah@gmail.com; Choesin, Devi N., E-mail: faiza.fauziah@gmail.com [School of Life Sciences and Technology, Institut Teknologi Bandung, Jalan Ganeca 10, Bandung 40132 (Indonesia)

2014-03-24T23:59:59.000Z

250

Method for decontamination of radioactive metal surfaces  

DOE Patents [OSTI]

Disclosed is a method for removing radioactive contaminants from metal surfaces by applying steam containing an inorganic acid and cerium IV. Cerium IV is applied to contaminated metal surfaces by introducing cerium IV in solution into a steam spray directed at contaminated metal surfaces. Cerium IV solution is converted to an essentially atomized or vapor phase by the steam.

Bray, L.A.

1996-08-13T23:59:59.000Z

251

Method for decontamination of radioactive metal surfaces  

DOE Patents [OSTI]

Disclosed is a method for removing radioactive contaminants from metal surfaces by applying steam containing an inorganic acid and cerium IV. Cerium IV is applied to contaminated metal surfaces by introducing cerium IV in solution into a steam spray directed at contaminated metal surfaces. Cerium IV solution is converted to an essentially atomized or vapor phase by the steam.

Bray, Lane A. (Richland, WA)

1996-01-01T23:59:59.000Z

252

Use of the high-energy x-ray microprobe at the Advanced Photon Source to investigate the interactions between metals and bacteria.  

SciTech Connect (OSTI)

Understanding the fate of heavy-metal contaminants in the environment is of fundamental importance in the development and evaluation of effective remediation and sequestration strategies. Among the factors influencing the transport of these contaminants are their chemical separation and the chemical and physical attributes of the surrounding medium. Bacteria and the extracellular material associated with them are thought to play a key role in determining a contaminant's speciation and thus its mobility in the environment. In addition, the microenvironment at and adjacent to actively metabolizing cell surfaces can be significantly different from the bulk environment. Thus, the spatial distribution and chemical separation of contaminants and elements that are key to biological processes must be characterized at micron and submicron resolution in order to understand the microscopic physical, geological, chemical, and biological interfaces that determine a contaminant's macroscopic fate. Hard X-ray microimaging is a powerful technique for the element-specific investigation of complex environmental samples at th needed micron and submicron resolution. An important advantage of this technique results from the large penetration depth of hard X-rays in water. This advantage minimizes the requirements for sample preparation and allows the detailed study of hydrated samples. This paper presents results of studies of the spatial distribution of naturally occurring metals and a heavy-metal contaminant (Cr) in and near hydrated bacteria (Pseudomonas fluorescens) in the early stages of biofilm development, performed at the Advanced Photon Source Sector 2 X-ray microscopy beamline.

Kemner, K. M.; Lai, B.; Maser, J.; Schneegurt, M. A.; Cai, Z.; Ilinski, P. P.; Kulpa, C. F.; Legnini, D. G.; Nealson, K. H.; Pratt, S. T.; Rodrigues, W.; Tischler, M. L.; Yun, W.

1999-09-30T23:59:59.000Z

253

Lead contamination in street soils of Nairobi City and Mombasa Island, Kenya  

SciTech Connect (OSTI)

The advent of modern industrialization and, in particular, the motor vehicle has witnessed dramatic increases in lead usage both as a component of lead-acid storage battery and from 1923 as organic lead alkyl anti-knock additive in petroleum. Several workers have established a correlation between increasing lead concentration in roadside soils and vehicular traffic density. Although researchers studied the heavy metal content in Lake Victoria sediments, no urban roadside soils were investigated. Since lead is used as a petrol additive in Kenya, it is necessary to document the extent and magnitude of lead contamination of roadside soils in inland and coastal urban environments and evaluate its environmental implications.

Onyari, J.M.; Wandiga, S.O.; Njenga, G.K.; Nyatebe, J.O. (Univ. of Nairobi (Kenya))

1991-05-01T23:59:59.000Z

254

Reversible photodeposition and dissolution of metal ions  

DOE Patents [OSTI]

A cyclic photocatalytic process for treating waste water containing metal and organic contaminants. In one embodiment of the method, metal ions are photoreduced onto the photocatalyst and the metal concentrated by resolubilization in a smaller volume. In another embodiment of the method, contaminant organics are first oxidized, then metal ions removed by photoreductive deposition. The present invention allows the photocatalyst to be recycled until nearly complete removal of metal ions and organic contaminants is achieved.

Foster, Nancy S. (Boulder, CO); Koval, Carl A. (Golden, CO); Noble, Richard D. (Boulder, CO)

1994-01-01T23:59:59.000Z

255

Oxygen and Nitrogen Contamination During Arc Welding  

E-Print Network [OSTI]

) ) : ,- Oxygen and Nitrogen Contamination During Arc Welding T. W. Eagar Department of }faterials, shielded metal arc, self-shielded metal arc, and submerged arc welding are reviewed. Calcu- lations upon heating is also discussed. Introduction Oxygen and nitrogen ~ontamination of weld metal

Eagar, Thomas W.

256

Effects of Incubation and Phosphate Rock on Lead Extractabilityand Speciation in Contaminated Soils  

E-Print Network [OSTI]

A HEAVY METAL and toxic to humans and ani- I -i mals, especially to young children (Paulozzi et al., 1995 reaction with excess posi- tive ions present. Finally, heavy metals chemically ad- sorbed or complexed represents the forms of heavy metals of greatest Abbreviations: EDTA, ethylenediaminetetraacetic acid; DPTA

Ma, Lena

257

Evaluation of soil washing for radiologically contaminated soils  

SciTech Connect (OSTI)

Soil washing has been applied internationally to decontaminate soils due to the widespread increase in environmental awareness manifested in the United States by promulgation of the Comprehensive Environmental Response, Compensation and Liability Act, yet we continue to lack understanding on why the technique works in one application and not in another. A soil washing process typically integrates a variety of modules, each designed to decontaminate the matrix by destroying a particular phase or segregating a particle size fraction in which the contaminants are concentrated. The more known about how the contaminants are fixed, the more likely the process will succeed. Much can be learned from bioavailability studies on heavy metals in soils. Sequential extraction experiments designed to destroy one fixation mechanism at a time can be used to determine how contaminants are bound. This knowledge provides a technical basis for designing a processing strategy to efficiently decontaminate soil while creating a minimum of secondary wastes. In this study, a soil from the Idaho National Engineering Laboratory was physically and chemically characterized, then sequentially extracted to determine if soil washing could be effectively used to remove cesium, cobalt and chromium.

Gombert, D. II

1994-03-01T23:59:59.000Z

258

Contaminant plumes containment and remediation focus area. Technology summary  

SciTech Connect (OSTI)

EM has established a new approach to managing environmental technology research and development in critical areas of interest to DOE. The Contaminant Plumes Containment and Remediation (Plumes) Focus Area is one of five areas targeted to implement the new approach, actively involving representatives from basic research, technology implementation, and regulatory communities in setting objectives and evaluating results. This document presents an overview of current EM activities within the Plumes Focus Area to describe to the appropriate organizations the current thrust of the program and developing input for its future direction. The Plumes Focus Area is developing remediation technologies that address environmental problems associated with certain priority contaminants found at DOE sites, including radionuclides, heavy metals, and dense non-aqueous phase liquids (DNAPLs). Technologies for cleaning up contaminants of concern to both DOE and other federal agencies, such as volatile organic compounds (VOCs), polychlorinated biphenyls (PCBs), and other organics and inorganic compounds, will be developed by leveraging resources in cooperation with industry and interagency programs.

NONE

1995-06-01T23:59:59.000Z

259

Modelling of contaminant release from a uranium mine tailings site  

SciTech Connect (OSTI)

Available in abstract form only. Full text of publication follows: Uranium mining and milling continuing from the early 1960's until 1990 close to the town of Seelingstaedt in Eastern Germany resulted in 4 tailings impoundments with a total tailings volume of about 105 Mio. m{sup 3}. Leakage from these tailings impoundments enters the underlying aquifers and is discharged into surface water streams. High concentration of salts, uranium and several heavy metals are released from the tailings. At present the tailings impoundments are reshaped and covered. For the identification of suitable remediation options predictions of the contaminant release for different remediation scenarios have to be made. A compartment model representing the tailings impoundments and the surrounding aquifers for the calculation of contaminant release and transport was set up using the software GOLDSIM. This compartment model describes the time dependent hydraulic conditions within the tailings and the surrounding aquifers taking into account hydraulic and geotechnical processes influencing the hydraulic properties of the tailings material. A simple geochemical approach taking into account sorption processes as well as retardation by applying a k{sub d}-approach was implemented to describe the contaminant release and transport within the hydraulic system. For uranium as the relevant contaminant the simple approach takes into account additional geochemical conditions influencing the mobility. Alternatively the model approach allows to include the results of detailed geochemical modelling of the individual tailings zones which is than used as source term for the modelling of the contaminant transport in the aquifer and to the receiving streams. (authors)

Kahnt, Rene [G.E.O.S. Freiberg Ingenieurgesellschaft mbH, P.O.Box 1162. D-09581 Freiberg (Germany); Metschies, Thomas [Wismut GmbH, Jagdschaenkenstrasse 29. D-09117 Chemnitz (Germany)

2007-07-01T23:59:59.000Z

260

Reliability and Consistency of Surface Contamination Measurements  

SciTech Connect (OSTI)

Surface contamination evaluation is a tough problem since it is difficult to isolate the radiations emitted by the surface, especially in a highly irradiating atmosphere. In that case the only possibility is to evaluate smearable (removeable) contamination since ex-situ countings are possible. Unfortunately, according to our experience at CEA, these values are not consistent and thus non relevant. In this study, we show, using in-situ Fourier Transform Infra Red spectrometry on contaminated metal samples, that fixed contamination seems to be chemisorbed and removeable contamination seems to be physisorbed. The distribution between fixed and removeable contamination appears to be variable. Chemical equilibria and reversible ion exchange mechanisms are involved and are closely linked to environmental conditions such as humidity and temperature. Measurements of smearable contamination only give an indication of the state of these equilibria between fixed and removeable contamination at the time and in the environmental conditions the measurements were made.

Rouppert, F.; Rivoallan, A.; Largeron, C.

2002-02-26T23:59:59.000Z

Note: This page contains sample records for the topic "heavy metal contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Metal and arsenic impacts to soils, vegetation communities and wildlife habitat in southwest Montana uplands contaminated by smelter emissions. 1: Field evaluation  

SciTech Connect (OSTI)

Concentrations of arsenic and metals in soils surrounding a smelter in southwest Montana were correlated with vegetative community structure and composition and wildlife habitat quality. Soils in the uplands surrounding the smelter were highly enriched with arsenic and metals. Concentrations of these analytes decreased with distance from the smelter and with soil depth, suggesting that the smelter is the source of the enrichment. In enriched areas, marked modifications to the native vegetation community structure and composition were observed. These included replacement of evergreen forest with bare unvegetated ground; species impoverishment and increased dominance by weed species in grasslands; and reductions in the vertical complexity of the habitat. Significant negative correlations existed between soil arsenic and metals concentrations and the extent of vegetative cover and the vertical diversity of plant communities. Loss of vegetative cover in the affected areas has been accompanied by reductions in their capacity to support indigenous wildlife populations.

Galbraith, H.; LeJeune, K.; Lipton, J. [Hagler Bailly Consulting, Inc., Boulder, CO (United States)

1995-11-01T23:59:59.000Z

262

Effect of a short weak prepulse on laser-triggered front-surface heavy-ion acceleration  

SciTech Connect (OSTI)

A suppression of light-ion acceleration (from surface water contaminants) was observed when a moderate-intensity subpicosecond laser pulse was focused on a thick metal target. Simultaneously, an effective generation of high-energy multicharge ions of the target material (Fe) was experimentally observed. A numerical simulation based on the Boltzmann-Vlasov-Poisson model revealed that this is due to the very specific regime of cleaning contaminants from the target surface by the short weak prepulse preceding the main pulse by more than 10 ns and having an intensity below the surface breakdown threshold. Because this prepulse causes the contaminant layer to boil explosively, a low-density gap forms above the target surface. These conditions are consequently favorable for boosting the energy of heavy ions.

Bochkarev, S. G.; Bychenkov, V. Yu. [P. N. Lebedev Physical Institute, Russian Academy of Sciences, Moscow (Russian Federation); Golovin, G. V.; Uryupina, D. S.; Shulyapov, S. A.; Savel'ev, A. B. [M. V. Lomonosov Moscow State University, International Laser Centre and Faculty of Physics, Moscow (Russian Federation); Andriyash, A. V. [The All-Russia Research Institute of Automatics, Moscow (Russian Federation)

2012-10-15T23:59:59.000Z

263

Soil washing as a potential remediation technology for contaminated DOE sites  

SciTech Connect (OSTI)

Frequently detected contaminants at US Department of Energy (DOE) sites include radionuclides, heavy metals, and chlorinated hydrocarbons. Remediation of these sites requires application of several technologies used in concert with each other, because no single technology is universally applicable. Special situations, such as mixed waste, generally require innovative technology development. This paper, however, focuses on contaminated soils, for which soil washing and vitrification technologies appear to have wide ranging application potential. Because the volumes of contaminated soils around the DOE complex are so large, soil washing can offer a potentially inexpensive way to effect remediation or to attain waste volume reduction. As costs for disposal of low-level and mixed wastes continue to rise, it is likely that volume-reduction techniques and in-situ containment techniques will become increasingly important. This paper reviews the status of the soil washing technology, examines the systems that are currently available, and discusses the potential application of this technology to some DOE sites, with a focus on radionuclide contamination and, primarily, uranium-contaminated soils

Devgun, J.S.; Beskid, N.J. (Argonne National Lab., IL (United States)); Natsis, M.E. (Princeton Univ., NJ (United States)); Walker, J.S. (USDOE, Washington, DC (United States))

1993-01-01T23:59:59.000Z

264

Soil washing as a potential remediation technology for contaminated DOE sites  

SciTech Connect (OSTI)

Frequently detected contaminants at US Department of Energy (DOE) sites include radionuclides, heavy metals, and chlorinated hydrocarbons. Remediation of these sites requires application of several technologies used in concert with each other, because no single technology is universally applicable. Special situations, such as mixed waste, generally require innovative technology development. This paper, however, focuses on contaminated soils, for which soil washing and vitrification technologies appear to have wide ranging application potential. Because the volumes of contaminated soils around the DOE complex are so large, soil washing can offer a potentially inexpensive way to effect remediation or to attain waste volume reduction. As costs for disposal of low-level and mixed wastes continue to rise, it is likely that volume-reduction techniques and in-situ containment techniques will become increasingly important. This paper reviews the status of the soil washing technology, examines the systems that are currently available, and discusses the potential application of this technology to some DOE sites, with a focus on radionuclide contamination and, primarily, uranium-contaminated soils

Devgun, J.S.; Beskid, N.J. [Argonne National Lab., IL (United States); Natsis, M.E. [Princeton Univ., NJ (United States); Walker, J.S. [USDOE, Washington, DC (United States)

1993-03-01T23:59:59.000Z

265

Comparative analyses of soil contaminant levels and plant species diversity at developing and disused oil well sites in Qianjiang oilfield, China  

SciTech Connect (OSTI)

Oilfield development contaminates soils and waters with crude oil, brine and heavy metals. Oil well sites are probably the most contaminated places in oilfields. During drilling and crude oil extraction from underground stores, a significant amount of oil and brine discharges into soils at oil well sites by blowouts, container spillages and pipeline ruptures. In oilfields in China, it was estimated that about 0.77 - 1.85% crude oil discharged into soils at oil well sites during oilfield development. Exposure to oil and salt contaminants could evoke toxicological effects in plants. Responses of plants to the contaminant exposure include inhibition of photosynthesis and nitrogen fixation, cessation of growth, reduced reproductive success and mortality. These harmful impacts on plants would be expected to result in remarkable loss of biodiversity. Qianjiang oilfield has been developed for about thirty-five years. Oil well sites in it have long been contaminated with oil and brine since, and plants at the well sites are rare. In the last three years however some wells have fallen into disuse. In result, a few plant species have intruded into the disuse well sites and formed new populations, and plant species diversity in these places has increased thereby. For benefit of restoration of the disuse well sites, it is interesting to know the relationships between contaminant levels and plant biodiversity. The present paper focuses the attention on comparative analyses of soil contaminations by crude oil, salt and some heavy metals and plant species diversity at developing and disuse oil well sites. 15 refs., 3 tabs.

Xiong, Z.T.; Hu, H.X.; Wang, Y.X. [Wuhan Univ., Hubei (China)] [and others] [Wuhan Univ., Hubei (China); and others

1997-04-01T23:59:59.000Z

266

Treatment of Mercury Contaminated Oil from Sandia National Laboratory  

SciTech Connect (OSTI)

First Article Tests of a stabilization method for greater than 260 mg mercury/kg oil were performed under a treatability study. This alternative treatment technology will address treatment of U.S. Department of Energy (DOE) organics (mainly used pump oil) contaminated with mercury and other heavy metals. Some of the oil is also co-contaminated with tritium, other radionuclides, and hazardous materials. The technology is based on contacting the oil with a sorbent powder (Self-Assembled Mercaptan on Mesoporous Support, SAMMS), proven to adsorb heavy metals, followed by stabilization of the oil/powder mixture using a stabilization agent (Nochar N990). Two variations of the treatment technology were included in the treatability study. The SAMMS (Self-Assembled Mercaptan on Mesoporous Silica) technology was developed by the Pacific Northwest National Laboratory for removal and stabilization of RCRA metals (i.e., lead, mercury, cadmium, silver, etc.) and for removal of mercury from organic solvents [1]. The SAMMS material is based on self-assembly of functionalized monolayers on mesoporous oxide surfaces. The unique mesoporous oxide supports provide a high surface area, thereby enhancing the metal-loading capacity. SAMMS material has high flexibility in that it binds with different forms of mercury, including metallic, inorganic, organic, charged, and neutral compounds [1] The material removes mercury from both organic wastes, such as pump oils, and from aqueous wastes. Mercury-loaded SAMMS not only passes TCLP tests, but also has good long-term durability as a waste form because: (1) the covalent binding between mercury and SAMMS has good resistance in ion-exchange, oxidation, and hydrolysis over a wide pH range and (2) the uniform and small pore size of the mesoporous silica prevents bacteria from solubilizing the bound mercury. Nochar's N990 Petrobond (Nochar, Inc., Indianapolis, IN) is an oil stabilization agent, specifically formulated for stabilizing vacuum pump oil, which has fewer volatile organics than many other oils. This material is a non-uniform granular powder that resembles ground Styrofoam plastics. This material has previously been used by itself and in combination with SAMMS to stabilize oil containing low levels of mercury {approx}50 mg/kg in surrogate waste studies [2].

Klasson, KT

2002-05-28T23:59:59.000Z

267

Heavy Duty Diesel Particulate Matter and Fuel Consumption Modeling for Transportation Analysis  

E-Print Network [OSTI]

Model for Heavy Duty Diesel Vehicles. TransportationAir Contaminant Emissions from Diesel- fueled Engines. Factfor Measuring Emissions from Diesel Engines. 1. Regulated

Scora, George Alexander

2011-01-01T23:59:59.000Z

268

Method for testing earth samples for contamination by organic contaminants  

DOE Patents [OSTI]

Provided is a method for testing earth samples for contamination by organic contaminants, and particularly for aromatic compounds such as those found in diesel fuel and other heavy fuel oils, kerosene, creosote, coal oil, tars and asphalts. A drying step is provided in which a drying agent is contacted with either the earth sample or a liquid extract phase to reduce to possibility of false indications of contamination that could occur when humic material is present in the earth sample. This is particularly a problem when using relatively safe, non-toxic and inexpensive polar solvents such as isopropyl alcohol since the humic material tends to be very soluble in those solvents when water is present. Also provided is an ultraviolet spectroscopic measuring technique for obtaining an indication as to whether a liquid extract phase contains aromatic organic contaminants. In one embodiment, the liquid extract phase is subjected to a narrow and discrete band of radiation including a desired wave length and the ability of the liquid extract phase to absorb that wavelength of ultraviolet radiation is measured to provide an indication of the presence of aromatic organic contaminants.

Schabron, John F. (Laramie, WY)

1996-01-01T23:59:59.000Z

269

Method for testing earth samples for contamination by organic contaminants  

DOE Patents [OSTI]

Provided is a method for testing earth samples for contamination by organic contaminants, and particularly for aromatic compounds such as those found in diesel fuel and other heavy fuel oils, kerosene, creosote, coal oil, tars and asphalts. A drying step is provided in which a drying agent is contacted with either the earth sample or a liquid extract phase to reduce to possibility of false indications of contamination that could occur when humic material is present in the earth sample. This is particularly a problem when using relatively safe, non-toxic and inexpensive polar solvents such as isopropyl alcohol since the humic material tends to be very soluble in those solvents when water is present. Also provided is an ultraviolet spectroscopic measuring technique for obtaining an indication as to whether a liquid extract phase contains aromatic organic contaminants. In one embodiment, the liquid extract phase is subjected to a narrow and discrete band of radiation including a desired wave length and the ability of the liquid extract phase to absorb that wavelength of ultraviolet radiation is measured to provide an indication of the presence of aromatic organic contaminants. 2 figs.

Schabron, J.F.

1996-10-01T23:59:59.000Z

270

The Influence of Metal Pollution on the Immune System A Potential Stressor for Marine Mammals in the North Sea  

E-Print Network [OSTI]

Kaliszan, R. (1996). Heavy metal pollution in surficialHeavy metals in Baltic herring and cod. Marine Pollutionheavy metals and infectious disease mortality in harbour porpoises from England and Wales. Environmental Pollution,

Kakuschke, Antje; Prange, Andreas

2007-01-01T23:59:59.000Z

271

Contaminated nickel scrap processing  

SciTech Connect (OSTI)

The DOE will soon choose between treating contaminated nickel scrap as a legacy waste and developing high-volume nickel decontamination processes. In addition to reducing the volume of legacy wastes, a decontamination process could make 200,000 tons of this strategic metal available for domestic use. Contaminants in DOE nickel scrap include {sup 234}Th, {sup 234}Pa, {sup 137}Cs, {sup 239}Pu (trace), {sup 60}Co, U, {sup 99}Tc, and {sup 237}Np (trace). This report reviews several industrial-scale processes -- electrorefining, electrowinning, vapormetallurgy, and leaching -- used for the purification of nickel. Conventional nickel electrolysis processes are particularly attractive because they use side-stream purification of process solutions to improve the purity of nickel metal. Additionally, nickel purification by electrolysis is effective in a variety of electrolyte systems, including sulfate, chloride, and nitrate. Conventional electrorefining processes typically use a mixed electrolyte which includes sulfate, chloride, and borate. The use of an electrorefining or electrowinning system for scrap nickel recovery could be combined effectively with a variety of processes, including cementation, solvent extraction, ion exchange, complex-formation, and surface sorption, developed for uranium and transuranic purification. Selected processes were reviewed and evaluated for use in nickel side-stream purification. 80 refs.

Compere, A.L.; Griffith, W.L.; Hayden, H.W.; Johnson, J.S. Jr.; Wilson, D.F.

1994-12-01T23:59:59.000Z

272

Method for separating constituents from solution employing a recyclable Lewis acid metal-hydroxy gel  

SciTech Connect (OSTI)

This invention permits radionuclides, heavy metals, and organics to be extracted from solution by scavenging them with an amorphous gel. In the preferred embodiment, a contaminated solution (e.g. from soil washing, decontamination, or groundwater pumping) is transferred to a reaction vessel. The contaminated solution is contacted by the sequestering reagent which might contain for example, aluminate and EDTA anions in a 2.5 M NaOH solution. The pH of the reagent bearing solution is lowered on contact with the contaminated solution, or for example by bubbling carbon dioxide through it, causing an aluminum hydroxide gel to precipitate as the solution drops below the range of 1.8 to 2.5 molar NaOH (less than pH 14). This precipitating gel scavenges waste contaminants as it settles through solution leaving a clean supernatant which is then separated from the gel residue by physical means such as centrifugation, or simple settling. The gel residue containing concentrated contaminants is then redissolved releasing contaminants for separations and processing. This is a critical point: the stabilized gel used in this invention is readily re-dissolved by merely increasing the pH above the gels phase transition to aqueous anions. Thus, concentrated contaminants trapped in the gel can be released for convenient separation from the sequestering reagent, and said reagent can then be recycled.

Alexander, D.H.

1995-12-31T23:59:59.000Z

273

Bioremediation of uranium contaminated soils and wastes  

SciTech Connect (OSTI)

Contamination of soils, water, and sediments by radionuclides and toxic metals from uranium mill tailings, nuclear fuel manufacturing and nuclear weapons production is a major concern. Studies of the mechanisms of biotransformation of uranium and toxic metals under various microbial process conditions has resulted in the development of two treatment processes: (1) stabilization of uranium and toxic metals with reduction in waste volume and (2) removal and recovery of uranium and toxic metals from wastes and contaminated soils. Stabilization of uranium and toxic metals in wastes is accomplished by exploiting the unique metabolic capabilities of the anaerobic bacterium, Clostridium sp. The radionuclides and toxic metals are solubilized by the bacteria directly by enzymatic reductive dissolution, or indirectly due to the production of organic acid metabolites. The radionuclides and toxic metals released into solution are immobilized by enzymatic reductive precipitation, biosorption and redistribution with stable mineral phases in the waste. Non-hazardous bulk components of the waste volume. In the second process uranium and toxic metals are removed from wastes or contaminated soils by extracting with the complexing agent citric acid. The citric-acid extract is subjected to biodegradation to recover the toxic metals, followed by photochemical degradation of the uranium citrate complex which is recalcitrant to biodegradation. The toxic metals and uranium are recovered in separate fractions for recycling or for disposal. The use of combined chemical and microbiological treatment process is more efficient than present methods and should result in considerable savings in clean-up and disposal costs.

Francis, A.J.

1998-12-31T23:59:59.000Z

274

Suppression of the phagocytic capabilities of coelomocytes from Lumbricus terrestris following an in-vitro exposure to heavy metals and evaluation of their metabolic activities by flow cytometry  

SciTech Connect (OSTI)

Immunotoxic effects of environmental exposure to chemical contaminants can be evaluated by monitoring cellular and functional parameters of the immune system of sentinel species. In this scope, the earthworm may represent a relevant sentinel species to determine the level of toxicity linked to soil contaminants or to test the efficacy of remediation protocols. In this work, coelomocytes were incubated in vitro for 18 hours with mercury, cadmium, zinc or lead at concentrations ranging from 10{sup {minus}9} to 10{sup {minus}4}M. The analysis of phagocytosis by flow cytometry revealed that this natural response was impaired at non cytotoxic concentrations of mercury, cadmium and zinc. Moreover, the analysis of cells obtained from coelomic fluid, based on the combination of low angle forward scatter (FSC) and side scatter (SSC) allowed to discriminate between two distinct populations of coelomocytes. With the use of fluorescent probes, such as carboxyfluorescin diacetate (CFDA), dichlorofluorescin diacetate (DCFDA) and chloromethyl fluorescin diacetate (CFDA), to study the esterase activity and Fluo-3 to measure free cytoplasmic calcium, the results showed that the first discrimination between the two populations of cells based on size and complexity could be further accentuated on the basis of their metabolic activities. In summary, the data make very attractive the use of flow cytometry to study cellular and functional parameters of the earthworm.

Brousseau, P.; Fugere, N.; Coderre, D.; Flipo, D.; Foumier, M. [Univ. du Quebec a Montreal, Montreal, Quebec (Canada)

1995-12-31T23:59:59.000Z

275

Cleaning Contaminated Water at Fukushima  

SciTech Connect (OSTI)

Crystalline Silico-Titanates (CSTs) are synthetic zeolites designed by Sandia National Laboratories scientists to selectively capture radioactive cesium and other group I metals. They are being used for cleanup of radiation-contaminated water at the Fukushima Daiichi nuclear power plant in Japan. Quick action by Sandia and its corporate partner UOP, A Honeywell Company, led to rapid licensing and deployment of the technology in Japan, where it continues to be used to clean up cesium contaminated water at the Fukushima power plant.

Rende, Dean; Nenoff, Tina

2013-11-21T23:59:59.000Z

276

Cleaning Contaminated Water at Fukushima  

ScienceCinema (OSTI)

Crystalline Silico-Titanates (CSTs) are synthetic zeolites designed by Sandia National Laboratories scientists to selectively capture radioactive cesium and other group I metals. They are being used for cleanup of radiation-contaminated water at the Fukushima Daiichi nuclear power plant in Japan. Quick action by Sandia and its corporate partner UOP, A Honeywell Company, led to rapid licensing and deployment of the technology in Japan, where it continues to be used to clean up cesium contaminated water at the Fukushima power plant.

Rende, Dean; Nenoff, Tina

2014-02-26T23:59:59.000Z

277

Modeling Multi-Metal Ion Exchange in Biosorption  

E-Print Network [OSTI]

, may serve as a means for purifying industrial wastewaters that contain toxic heavy metal ions heavy metals often through ion exchange. This biosorption can be used for purification of metalModeling Multi-Metal Ion Exchange in Biosorption S I L K E S C H I E W E R A N D B O H U M I L V O

Volesky, Bohumil

278

Adsorption of Chromium (VI) by metal hydroxide sludge from the metal finishing  

E-Print Network [OSTI]

and Management, United States (2008)" #12;2 1 Introduction Industrial aqueous pollution (heavy metals) accounts sludge (MHS) during the treatment of their liquid effluents charged with heavy metals. Generally, a small for 30 to 40% of industrial pollution. Metal finishing is one of the sectors which contributes mostly

Paris-Sud XI, Université de

279

Ecological Impacts of Contaminants in an Urban Watershed DOE FRAP 1998-25  

E-Print Network [OSTI]

of metals on a "pristine" stream community. The Brunette watershed has concentrations of heavy metals largely absent from the Brunette River watershed were also those species most sensitive to heavy metal (Burnaby, BC) was studied as an example. We studied sediment chemistry, direct toxicity of sediments

280

Integrated decontamination process for metals  

DOE Patents [OSTI]

An integrated process for decontamination of metals, particularly metals that are used in the nuclear energy industry contaminated with radioactive material. The process combines the processes of electrorefining and melt refining to purify metals that can be decontaminated using either electrorefining or melt refining processes.

Snyder, Thomas S. (Oakmont, PA); Whitlow, Graham A. (Murrysville, PA)

1991-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "heavy metal contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

E-Print Network 3.0 - affecting metal tolerance Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

417 May, M... 707xml BIJPA310229 June 13, 2008 19:8 BIJP 310229, VOL 10, ISS 5 HEAVY METAL TOLERANCE... will list your paper exactly as it appears below: HEAVY METAL ... Source:...

282

E-Print Network 3.0 - aluminum-fly ash metal Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

extent, bottom ash, contain elevated amounts of heavy metals, and fly ash... . The dioxinsfurans on ash then don't seem to create an environmental problem. Heavy metals are...

283

E-Print Network 3.0 - autometallography tissue metals Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

previously for localization of trace metals ions in tissues. By exploiting... to heavy metal toxicology. Pharmacol Toxicol 68:414-423 Danscher G (1984) Autometallography. A new......

284

E-Print Network 3.0 - alcali metal cations Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Vincent J. Camobreco... 161:740-750 1996 ABSTRACT Soils accumulate heavy metals when sewage sludge is applied to land... -borne metals could represent if mobilized, many...

285

E-Print Network 3.0 - aggregate structures metal Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

J. Camobreco... 161:740-750 1996 ABSTRACT Soils accumulate heavy metals when sewage sludge is applied to land... -borne metals could represent if mobilized, many studies have...

286

E-Print Network 3.0 - anionic metal complexes Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

2B2 *corresponding author Anionic metal complexes, are very effectively... containing toxic heavy metals, often in ... Source: Volesky, Bohumil - Department of Chemical...

287

1088 IEEE TRANSACTIONS ON GEOSCIENCE AND REMOTE SENSING, VOL. 42, NO. 5, MAY 2004 Classification of Contamination in Salt Marsh Plants  

E-Print Network [OSTI]

heavy metal or petroleum toxicity, with a control treatment for each experiment. If these method for classifying heavy-metal or petroleum exposed plants for the more complicated data from air- and spaceborne sensors. Index Terms--Heavy metals, hyperspectral, logistic discrimina- tion (LD), partial least squares

Rocke, David M.

288

USE OF APATITE FOR CHEMICAL STABILIZATION OF SUBSURFACE CONTAMINANTS  

SciTech Connect (OSTI)

Groundwater at many Federal and civilian industrial sites is often contaminated with toxic metals at levels that present a potential concern to regulatory agencies. The U.S. Department of Energy (DOE) has some unique problems associated with radionuclides (primarily uranium), but metal contaminants most likely drive risk-based cleanup decisions, from the perspective of human health, in groundwater at DOE and U.S. Environmental Protection Agency (EPA) Superfund Sites include lead (Pb), arsenic (As), cadmium (Cd), chromium (Cr), mercury (Hg), zinc (Zn), selenium (Se), antimony (Sb), copper (Cu) and nickel (Ni). Thus, the regulatory ''drivers'' for toxic metals in contaminated soils/groundwaters are very comparable for Federal and civilian industrial sites, and most sites have more than one metal above regulatory action limits. Thus improving the performance of remedial technologies for metal-contaminated groundwater will have ''dual use'' (Federal and civilian) benefit.

Dr. William D. Bostick

2003-05-01T23:59:59.000Z

289

Upgrading platform using alkali metals  

DOE Patents [OSTI]

A process for removing sulfur, nitrogen or metals from an oil feedstock (such as heavy oil, bitumen, shale oil, etc.) The method involves reacting the oil feedstock with an alkali metal and a radical capping substance. The alkali metal reacts with the metal, sulfur or nitrogen content to form one or more inorganic products and the radical capping substance reacts with the carbon and hydrogen content to form a hydrocarbon phase. The inorganic products may then be separated out from the hydrocarbon phase.

Gordon, John Howard

2014-09-09T23:59:59.000Z

290

Changes in species assemblages and diets of Collembola along a gradient of metal pollution  

E-Print Network [OSTI]

pollution. Keywords: Collembolan communities, Heavy metals, Gut contents 1. Introduction * Corresponding.1016/S0929-1393(02)00134-8 #12;2 Pollution by heavy metals, due to smelter, mining or agricultural the hypothesis that soil animal communities sampled along a gradient of heavy metal pollution show a) shifts

Paris-Sud XI, Université de

291

Humus forms and metal pollution in soil S. GILLET & J.F. PONGE  

E-Print Network [OSTI]

pollution by heavy metals. We have studied a poplar plantation downwind of an active zinc smelter. Three debris to assess the impact of heavy metal pollution on the humus forms and on soil faunal activity. We. Introduction Today, in northern France, numerous sites are polluted by heavy metals (Balabane et al., 1999

Paris-Sud XI, Université de

292

Bioremediation of Metals and Radionuclides: What It Is and How It Works (2nd Edition)  

SciTech Connect (OSTI)

This primer is intended for people interested in environmental problems of the U.S. Department of Energy (DOE) and in their potential solutions. It will specifically look at some of the more hazardous metal and radionuclide contaminants found on DOE lands and at the possibilities for using bioremediation technology to clean up these contaminants. The second edition of the primer incorporates recent findings by researchers in DOE's Natural and Accelerated Bioremediation Research (NABIR) Program. Bioremediation is a technology that can be used to reduce, eliminate, or contain hazardous waste. Over the past two decades, it has become widely accepted that microorganisms, and to a lesser extent plants, can transform and degrade many types of contaminants. These transformation and degradation processes vary, depending on the physical-chemical environment, microbial communities, and nature of the contaminant. This technology includes intrinsic bioremediation, which relies on naturally occurring processes, and accelerated bioremediation, which enhances microbial degradation or transformation through the addition of nutrients (biostimulation) or inoculation with microorganisms (bioaugmentation). Over the past few years, interest in bioremediation has increased. It has become clear that many organic contaminants such as hydrocarbon fuels can be degraded to relatively harmless products such as CO{sub 2} (the end result of the degradation process). Waste water managers and scientists have also found that microorganisms can interact with metals and convert them from one chemical form to another. Laboratory tests and ex situ bioremediation applications have shown that microorganisms can change the valence, or oxidation state, of some heavy metals (e.g., chromium and mercury) and radionuclides (e.g., uranium) by using them as electron acceptors. In some cases, the solubility of the altered species decreases and the contaminant is immobilized in situ, i.e., precipitated into an insoluble salt in the sediment. In other cases, the opposite occurs--the solubility of the altered species increases, increasing the mobility of the contaminant and allowing it to be more easily flushed from the environment. Both of these kinds of transformations present opportunities for bioremediation of metals and radionuclides--either to lock them in place, or to accelerate their removal. DOE's goal is to reduce the risk and related exposure to ground water, sediment, and soil contamination at Department of Energy facilities. Subsurface bioremediation of metals and radionuclides at the site of contamination (in situ bioremediation) is not yet in widespread use. However, successful in situ applications of bioremediation to petroleum products and chlorinated solvents provide experience from which scientists can draw. Taken together, the accomplishments in these areas have led scientists and engineers to be optimistic about applying this technology to the mixtures of metals and radionuclides that are found at some of the most contaminated DOE sites. This primer examines some of the basic microbial and chemical processes that are a part of bioremediation, specifically the bioremediation of metals and radionuclides. The primer is divided into six sections, with the information in each building on that of the previous. The sections include features that highlight topics of interest and provide background information on specific biological and chemical processes and reactions. The first section briefly examines the scope of the contamination problem at DOE facilities. The second section gives a summary of some of the most commonly used bioremediation technologies, including successful in situ and ex situ techniques. The third discusses chemical and physical properties of metals and radionuclides found in contaminant mixtures at DOE sites, including solubility and the most common oxidation states in which these materials are found. The fourth section is an overview of the basic microbial processes that occur in bioremediation. The fifth section looks at specific in s

Palmisano, Anna; Hazen, Terry

2003-09-30T23:59:59.000Z

293

IN SITU REMEDIATION OF CONTAMINATED SEDIMENTS - ACTIVE CAPPING TECHNOLOGY  

SciTech Connect (OSTI)

Active capping is a relatively new approach for treating contaminated sediments. It involves applying chemically reactive amendments to the sediment surface. The main role of active caps is to stabilize contaminants in contaminated sediments, lower the bioavailable pool of contaminants, and reduce the release of contaminants to the water column. Metals are common contaminants in many marine and fresh water environments as a result of industrial and military activities. The mobile, soluble forms of metals are generally considered toxic. Induced chemical precipitation of these metals can shift toxic metals from the aqueous phase to a solid, precipitated phase which is often less bioavailable. This approach can be achieved through application of sequestering agents such as rock phosphates, organoclays, zeolites, clay minerals, and biopolymers (e.g., chitosan) in active capping technology. Active capping holds great potential for a more permanent solution that avoids residual risks resulting from contaminant migration through the cap or breaching of the cap. In addition to identifying superior active capping agents, research is needed to optimize application techniques, application rates, and amendment combinations that maximize sequestration of contaminants. A selected set of active capping treatment technologies has been demonstrated at a few sites, including a field demonstration at the Savannah River Site, Aiken, SC. This demonstration has provided useful information on the effects of sequestering agents on metal immobilization, bioavailability, toxicity, and resistance to mechanical disturbance.

Knox, A.; Roberts, J.; Paller, M.; Reible, D.

2010-09-02T23:59:59.000Z

294

Aging of Iron (Hydr)oxides by Heat Treatment and Effects on Heavy  

E-Print Network [OSTI]

caused some volatilization of heavy metals (most notably, Hg). Leaching with water at pH 9 (L/S 10, 24 hAging of Iron (Hydr)oxides by Heat Treatment and Effects on Heavy Metal Binding M E T T E A . S ? R)oxides are used to remove heavy metals from wastewater and in the treatment of air pollution control residues

Frenkel, Anatoly

295

Final Technical Report: Viral Infection of Subsurface Microorganisms and Metal/Radionuclide Transport  

SciTech Connect (OSTI)

Microbially mediated metabolisms have been identified as a significant factor either directly or indirectly impacting the fate and transport of heavy metal/radionuclide contaminants. To date microorganisms have been isolated from contaminated environments. Examination of annotated finished genome sequences of many of these subsurface isolates from DOE sites, revealed evidence of prior viral infection. To date the role that viruses play influencing microbial mortality and the resulting community structure which directly influences biogeochemical cycling in soils and sedimentary environments remains poorly understood. The objective of this exploratory study was to investigate the role of viral infection of subsurface bacteria and the formation of contaminant-bearing viral particles. This objective was approached by examining the following working hypotheses: (i) subsurface microorganisms are susceptible to viral infections by the indigenous subsurface viral community, and (ii) viral surfaces will adsorb heavy metals and radionuclides. Our results have addressed basic research needed to accomplish the BER Long Term Measure to provide sufficient scientific understanding such that DOE sites would be able to incorporate coupled physical, chemical and biological processes into decision making for environmental remediation or natural attenuation and long-term stewardship by establishing viral-microbial relationships on the subsequent fate and transport of heavy metals and radionuclides. Here we demonstrated that viruses play a significant role in microbial mortality and community structure in terrestrial subsurface sedimentary systems. The production of viral-like particles within subsurface sediments in response to biostimulation with dissolved organic carbon and a terminal electron acceptor resulted in the production of viral-like particles. Organic carbon alone did not result in significant viral production and required the addition of a terminal electron acceptor (nitrate), indicating that nutrients are not limiting viral production, but rather substrates that can be converted into energy for host metabolism. Our results also revealed that cell abundance was not correlated to the mineralization of organic carbon, but rather viruses were positively correlated with carbon mineralization. This is a result of viral-mediated cell lysis and demonstrates that viruses are sensitive indicators of microbial activity. Viruses as an indicator of microbial activity was not unique to batch culture studies as results obtained from an in situ field experiment conducted at the DOE Old Rifle Field site. This study revealed that viral abundance increased in response to the injection of oxygenated groundwater and influx of dissolved organic carbon whereas cell abundance changes were minimal. However, the extent to which viral-mediated cell lysis alters organic matter pools subsequently influencing microbial community structure and biogeochemical function remains a critical question in subsurface biogeochemical cycling. The production of significant numbers of viruses in groundwater has implications for nanoparticulate metal as well as carbon transport in groundwater. We have demonstrated that the virus surface is reactive and will adsorb heavy metals. Thus viruses can promote colloidal contaminant mobility. Interestingly, the presence of heavy metals has a positive effect on infectivity of the phage, increasing phage infection which could lead to further production of viruses. Together, the results indicate that the sorption of metals to the surface of viruses could not only contribute to nanoparticulate metal as well as carbon transport but could also enhance infectivity further contributing to cell lysis which could subsequently influence biogeochemical cycling. As more viruses infect host microbial populations the high concentration of metals would enhance infection, resulting in cell lysis, and decreasing the metabolically active host population while yielding greater numbers of viruses capable of transporting contaminats. Additional studie

Weber, Karrie A.; Bender, Kelly S.; Li, Yusong

2013-09-28T23:59:59.000Z

296

BIOREMEDIATION OF URANIUM CONTAMINATED SOILS AND WASTES.  

SciTech Connect (OSTI)

Contamination of soils, water, and sediments by radionuclides and toxic metals from uranium mill tailings, nuclear fuel manufacturing and nuclear weapons production is a major concern. Studies of the mechanisms of biotransformation of uranium and toxic metals under various microbial process conditions has resulted in the development of two treatment processes: (i) stabilization of uranium and toxic metals with reduction in waste volume and (ii) removal and recovery of uranium and toxic metals from wastes and contaminated soils. Stabilization of uranium and toxic metals in wastes is accomplished by exploiting the unique metabolic capabilities of the anaerobic bacterium, Clostridium sp. The radionuclides and toxic metals are solubilized by the bacteria directly by enzymatic reductive dissolution, or indirectly due to the production of organic acid metabolites. The radionuclides and toxic metals released into solution are immobilized by enzymatic reductive precipitation, biosorption and redistribution with stable mineral phases in the waste. Non-hazardous bulk components of the waste such as Ca, Fe, K, Mg and Na released into solution are removed, thus reducing the waste volume. In the second process uranium and toxic metals are removed from wastes or contaminated soils by extracting with the complexing agent citric acid. The citric-acid extract is subjected to biodegradation to recover the toxic metals, followed by photochemical degradation of the uranium citrate complex which is recalcitrant to biodegradation. The toxic metals and uranium are recovered in separate fractions for recycling or for disposal. The use of combined chemical and microbiological treatment process is more efficient than present methods and should result in considerable savings in clean-up and disposal costs.

FRANCIS,A.J.

1998-09-17T23:59:59.000Z

297

Moving granular-bed filter development program, Option III: Development of moving granular-bed filter technology for multi-contaminant control. Task 14: Test plan; Topical report  

SciTech Connect (OSTI)

An experimental test plan has been prepared for DOE/METC review and approval to develop a filter media suitable for multi-contaminant control in granular-bed filter (GBF) applications. The plan includes identification, development, and demonstration of methods for enhanced media morphology, chemical reactivity, and mechanical strength. The test plan includes media preparation methods, physical and chemical characterization methods for fresh and reacted media, media evaluation criteria, details of test and analytical equipment, and test matrix of the proposed media testing. A filter media composed of agglomerated limestone and clay was determined to be the best candidate for multi-contaminate control in GBF operation. The combined limestone/clay agglomerate has the potential to remove sulfur and alkali species, in addition to particulate, and possibly halogens and trace heavy metals from coal process streams.

Haas, J.C.; Olivo, C.A.; Wilson, K.B.

1994-04-01T23:59:59.000Z

298

Colloids and Surfaces A: Physicochem. Eng. Aspects 281 (2006) 194201 Multi-metal biosorption in a fixed-bed flow-through column  

E-Print Network [OSTI]

-biosorbent biomass of Sargassum fluitans brown seaweed biomass is capable of effectively removing toxic heavy metals of toxic heavy metals from industrial metal-bearingeffluentshasbeenstudiedforsometime[1,19,28]. Biosorption is a process employing dead biomass to sorb heavy metals from aqueous solutions [18]. Low costs and relatively

Volesky, Bohumil

299

Method and apparatus for reclaiming metal values from electric arc furnace flue dust and sludge and rendering residual solids recyclable or non-hazardous  

SciTech Connect (OSTI)

This patent describes an apparatus for treating dust and sludge contaminated with heavy metals and heavy metal oxides, comprising: waste material storage means; a mixer; means communicating with the waste material storage means and the mixer for introducing the waste material, solid carbonaceous material, and an organic binder to the mixer; a pelletizing device; means for introducing material from the mixer into the pelletizing device; pelletizer discharge means; an inclined rotary reduction smelter vessel having a charging and pouring opening in one end thereof; means for introducing pellets from the pelletizer discharge means to the rotary reduction smelter vessel; retractable burner means for heating the interior of the smelter vessel; means for rotating the smelter vessel about its inclined axis; and means for tilting the smelter vessel about a horizontal axis.

Bishop, N.G.; Bottinelli, N.E.; Kotraba, N.L.

1988-07-19T23:59:59.000Z

300

In situ remediation of uranium contaminated groundwater  

SciTech Connect (OSTI)

In an effort to develop cost-efficient techniques for remediating uranium contaminated groundwater at DOE Uranium Mill Tailing Remedial Action (UMTRA) sites nationwide, Sandia National Laboratories (SNL) deployed a pilot scale research project at an UMTRA site in Durango, CO. Implementation included design, construction, and subsequent monitoring of an in situ passive reactive barrier to remove Uranium from the tailings pile effluent. A reactive subsurface barrier is produced by emplacing a reactant material (in this experiment - various forms of metallic iron) in the flow path of the contaminated groundwater. Conceptually the iron media reduces and/or adsorbs uranium in situ to acceptable regulatory levels. In addition, other metals such as Se, Mo, and As have been removed by the reductive/adsorptive process. The primary objective of the experiment was to eliminate the need for surface treatment of tailing pile effluent. Experimental design, and laboratory and field preliminary results are discussed with regard to other potential contaminated groundwater treatment applications.

Dwyer, B.P.; Marozas, D.C. [Sandia National Labs., Albuquerque, NM (United States)

1997-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "heavy metal contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

In situ remediation of uranium contaminated groundwater  

SciTech Connect (OSTI)

In an effort to develop cost-efficient techniques for remediating uranium contaminated groundwater at DOE Uranium Mill Tailing Remedial Action (UMTRA) sites nationwide, Sandia National Laboratories (SNL) deployed a pilot scale research project at an UMTRA site in Durango, CO. Implementation included design, construction, and subsequent monitoring of an in situ passive reactive barrier to remove Uranium from the tailings pile effluent. A reactive subsurface barrier is produced by emplacing a reactant material (in this experiment various forms of metallic iron) in the flow path of the contaminated groundwater. Conceptually the iron media reduces and/or adsorbs uranium in situ to acceptable regulatory levels. In addition, other metals such as Se, Mo, and As have been removed by the reductive/adsorptive process. The primary objective of the experiment was to eliminate the need for surface treatment of tailing pile effluent. Experimental design, and laboratory and field results are discussed with regard to other potential contaminated groundwater treatment applications.

Dwyer, B.P.; Marozas, D.C.

1997-02-01T23:59:59.000Z

302

Trace metal concentration and fish size: Variation among fish species in a Mediterranean river  

E-Print Network [OSTI]

29 April 2014 Accepted 12 May 2014 Keywords: Bioaccumulation Heavy metals Llobregat River species in an Iberian river with moderate metal pollution. Al, Fe and Zn were the most abundant metals trace elements (Bervoets and Blust, 2003; Noël et al., 2013). Heavy metals in fish represent a potential

García-Berthou, Emili

303

Nanoscale Biosensors for Environmental Monitoring and Biological Detection  

E-Print Network [OSTI]

Heavy metal ions were handled and disposed properly to avoid personal contamination and environmental pollution.

Yao, Jingjing

2012-01-01T23:59:59.000Z

304

5.0 R E S E A RC H R E S U LT S : I N T E G R AT I O N A N D C O N C LU S I O N S by Taina Tuominen and Colin Gray  

E-Print Network [OSTI]

OF THE BASINCURRENT STATUS Contaminants, including heavy metals, chlorinated phenolics, dioxins, furans

305

Biotechnology for the decontamination of Metal  

E-Print Network [OSTI]

Laurentian University SNO Science North #12;Problem: Pollution Heavy Metals Aluminium Lead Caesium CalciumBiotechnology for the decontamination of Metal Wastes Professor Vasu D. Appanna PhD Chair Yttrium #12;Accumulation of metals in living systems #12;Biological Effects #12;Adaptation #12;Aluminium

Appanna, Vasu

306

Recrystallization of heavy metals after cold deformation  

SciTech Connect (OSTI)

Rapid heating experiments, of the order of tens of seconds, were performed on a 90%W-7%Ni-3%Fe alloy, which was cold worked by rotary swaging to 50% reduction in diameter. It was found that even very short periods of heating brings to the separation of the elongated tungsten grains into small round ones, therefore refining the microstructure. The process involves melting of the matrix and its penetration into the tungsten grains. During cooling, very small, new grains are precipitated. It is suggested that grain refining is achieved by penetration of the molten matrix into the solid tungsten grains through subgrain boundaries.

Goren-Muginstein, G.R.; Rosen, A. [Israel Inst. of Tech., Haifa (Israel). Dept. of Materials Engineering

1996-06-01T23:59:59.000Z

307

E-Print Network 3.0 - active site metal Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: collected from a reference site and a site with a long-term history of heavy-metal pollution. Direct... the metal-polluted site were more tolerant of metals but less...

308

RCUT: A Non-Invasive Method for Detection, Location, and Quantification of Radiological Contaminants in Pipes and Ducts - 12514  

SciTech Connect (OSTI)

Radiological Characterization Using Tracers (RCUT) is a minimally invasive method for detection and location of residual radiological contamination in pipes and ducts. The RCUT technology utilizes reactive gaseous tracers that dissociate when exposed to gamma and/or beta radiation emitting from a radiological contaminant in a pipe or duct. Sulfur hexafluoride (SF{sub 6}) was selected as a tracer for this radiological application, because it is a chemically inert gas that is both nonflammable, nontoxic, and breaks down when exposed to gamma radiation. Laboratory tests demonstrated that the tracer pair of SF{sub 6} and O{sub 2} formed SO{sub 2}F{sub 2} when exposed to a gamma or beta radioactive field, which indicated the presence of radiological contamination. Field application of RCUT involves first injecting the reactive tracers into the pipe to fill the pipe being inspected and allowing sufficient time for the tracer to interact with any contaminants present. This is followed by the injection of an inert gas at one end of the pipe to push the reactive tracer at a known or constant flow velocity along the pipe and then out the exit and sampling port at the end of the pipeline where its concentration is measured by a gas chromatograph. If a radiological contaminant is present in the pipe being tested, the presence of SO{sub 2}F{sub 2} will be detected. The time of arrival of the SO{sub 2}F{sub 2} can be used to locate the contaminant. If the pipe is free of radiological contamination, no SO{sub 2}F{sub 2} will be detected. RCUT and PCUT are both effective technologies that can be used to detect contamination within pipelines without the need for mechanical or human inspection. These methods can be used to detect, locate, and/or estimate the volume of a variety of radioactive materials and hazardous chemicals such as chlorinated solvents, petroleum products, and heavy metals. While further optimization is needed for RCUT, the key first step of identification of a tracer compound appropriate for the application of detecting radioactive pipeline contamination through the detection of decomposition products of SF{sub 6} has been demonstrated. Other tracer gases that will also undergo radiolysis will be considered in the future. The next step for the RCUT development process is conducting laboratory scale tests using short pipelines to define analytical requirements, establish performance boundaries, and develop strategies for lower exposure levels. Studies to identify additional analytical techniques using equipment that is more field rugged than a GC/MS would also be beneficial. (authors)

Bratton, Wesley L.; Maresca, Joseph W. Jr.; Beck, Deborah A. [Vista Engineering Technologies, L.L.C., Richland, WA, 99352 (United States)

2012-07-01T23:59:59.000Z

309

Evaluation of fluoride-induced metal mobilization in soil columns  

SciTech Connect (OSTI)

Fluoride in soil solution may cause substantially increased leaching of dissolved organic carbon (DOC), Al, and heavy metals from soils. The authors objective was to examine whether increased metal solubility is attributable to formation of fluoro- or organo-complexes. The A horizon of a Slovak soil contaminated with heavy metals and F by Al smelter emissions was used to conduct two column experiments under saturated and steady-state water flow conditions. The columns were leached with 5 mM Na{sub 2}SO{sub 4}, 1 mM NaCl, and 9 mM NaF solutions at pH 5.5 and an electrical conductivity of 1,000 {micro}S cm{sup {minus}1}. Samples were collected in 70-min intervals for approximately 7 d. Two experiments were performed. In the first experiment (single F pulse), a fluoride (F) pulse was applied for 36 pore volumes (PVs), while in the second experiment (dual F pulse), two consecutive F pulses (each for 2.8 PVs) were applied. For both experiments, Cl breakthrough curves (BTCs) revealed a convection-dominated transport regime. The breakthrough of Cd, Cr, Fe, Ni, and Pb paralleled DOC breakthrough in both experiments indicating metal leaching as organocomplex. In the dual F pulse experiment, peak separation of the DOC and the complexed F (F{sub bound}) breakthrough was achieved. The highest F{sub bound} concentration occurred 3.8 PVs later than that of DOC. The AlBTC paralleled that of F{sub bound} but showed tailing with a turning point simultaneous to the highest DOC concentration. Thus, the increase in Al solubility was mainly caused by fluoro-complexation and only to a lesser extent by organo-complexation.

Totsche, K.U.; Wilcke, W.; Koerber, M.; Kobza, J.; Zech, W.

2000-04-01T23:59:59.000Z

310

Catalytic destruction of groundwater contaminants in reactive extraction wells  

DOE Patents [OSTI]

A system for remediating groundwater contaminated with halogenated solvents, certain metals and other inorganic species based on catalytic reduction reactions within reactive well bores. The groundwater treatment uses dissolved hydrogen as a reducing agent in the presence of a metal catalyst, such a palladium, to reduce halogenated solvents (as well as other substituted organic compounds) to harmless species (e.g., ethane or methane) and immobilize certain metals to low valence states. The reactive wells function by removing water from a contaminated water-bearing zone, treating contaminants with a well bore using catalytic reduction, and then reinjecting the treated effluent into an adjacent water-bearing zone. This system offers the advantages of a compact design with a minimal surface footprint (surface facilities) and the destruction of a broad suite of contaminants without generating secondary waste streams.

McNab, Jr., Walt W. (Concord, CA); Reinhard, Martin (Stanford, CA)

2002-01-01T23:59:59.000Z

311

Removal of metal ions from aqueous solution  

DOE Patents [OSTI]

A method of removing heavy metals from aqueous solution, a composition of matter used in effecting said removal, and apparatus used in effecting said removal. One or more of the polypeptides, poly (.gamma.-glutamylcysteinyl)glycines, is immobilized on an inert material in particulate form. Upon contact with an aqueous solution containing heavy metals, the polypeptides sequester the metals, removing them from the solution. There is selectivity of poly (.gamma.-glutamylcysteinyl)glycines having a particular number of monomer repeat units for particular metals. The polypeptides are easily regenerated by contact with a small amount of an organic acid, so that they can be used again to remove heavy metals from solution. This also results in the removal of the metals from the column in a concentrated form.

Jackson, Paul J. (Los Alamos, NM); Delhaize, Emmanuel (Los Alamos, NM); Robinson, Nigel J. (Durham, GB2); Unkefer, Clifford J. (Los Alamos, NM); Furlong, Clement (Seattle, WA)

1990-01-01T23:59:59.000Z

312

Bioremediation of contaminated groundwater  

DOE Patents [OSTI]

An apparatus and method are described for in situ remediation of contaminated subsurface soil or groundwater contaminated by chlorinated hydrocarbons. A nutrient fluid is selected to stimulate the growth and reproduction of indigenous subsurface microorganisms that are capable of degrading the contaminants. An oxygenated fluid is selected to create a generally aerobic environment for these microorganisms to degrade the contaminants, leaving only pockets that are anaerobic. The nutrient fluid is injected periodically while the oxygenated fluid is injected continuously and both are extracted so that both are drawn across the plume. The nutrient fluid stimulates microbial colony growth. Withholding it periodically forces the larger, healthy colony of microbes to degrade the contaminants. Treatment is continued until the subsurface concentration of contaminants is reduced to an acceptable, preselected level. The nutrient fluid can be methane and the oxygenated fluid air for stimulating production of methanotrophs to break down chlorohydrocarbons, especially trichloroethylene (TCE) and tetrachloroethylene. 3 figures.

Hazen, T.C.; Fliermans, C.B.

1995-01-24T23:59:59.000Z

313

Contamination analysis unit  

DOE Patents [OSTI]

The portable Contamination Analysis Unit (CAU) measures trace quantifies of surface contamination in real time. The detector head of the portable contamination analysis unit has an opening with an O-ring seal, one or more vacuum valves and a small mass spectrometer. With the valve closed, the mass spectrometer is evacuated with one or more pumps. The O-ring seal is placed against a surface to be tested and the vacuum valve is opened. Data is collected from the mass spectrometer and a portable computer provides contamination analysis. The CAU can be used to decontaminate and decommission hazardous and radioactive surface by measuring residual hazardous surface contamination, such as tritium and trace organics It provides surface contamination data for research and development applications as well as real-time process control feedback for industrial cleaning operations and can be used to determine the readiness of a surface to accept bonding or coatings.

Gregg, Hugh R. (Livermore, CA); Meltzer, Michael P. (Livermore, CA)

1996-01-01T23:59:59.000Z

314

Contamination analysis unit  

DOE Patents [OSTI]

The portable Contamination Analysis Unit (CAU) measures trace quantities of surface contamination in real time. The detector head of the portable contamination analysis unit has an opening with an O-ring seal, one or more vacuum valves and a small mass spectrometer. With the valve closed, the mass spectrometer is evacuated with one or more pumps. The O-ring seal is placed against a surface to be tested and the vacuum valve is opened. Data is collected from the mass spectrometer and a portable computer provides contamination analysis. The CAU can be used to decontaminate and decommission hazardous and radioactive surfaces by measuring residual hazardous surface contamination, such as tritium and trace organics. It provides surface contamination data for research and development applications as well as real-time process control feedback for industrial cleaning operations and can be used to determine the readiness of a surface to accept bonding or coatings. 1 fig.

Gregg, H.R.; Meltzer, M.P.

1996-05-28T23:59:59.000Z

315

Bioremediation of contaminated groundwater  

DOE Patents [OSTI]

An apparatus and method for in situ remediation of contaminated subsurface soil or groundwater contaminated by chlorinated hydrocarbons. A nutrient fluid is selected to stimulate the growth and reproduction of indigenous subsurface microorganisms that are capable of degrading the contaminants; an oxygenated fluid is selected to create a generally aerobic environment for these microorganisms to degrade the contaminants, leaving only pockets that are anaerobic. The nutrient fluid is injected periodically while the oxygenated fluid is injected continuously and both are extracted so that both are drawn across the plume. The nutrient fluid stimulates microbial colony growth; withholding it periodicially forces the larger, healthy colony of microbes to degrade the contaminants. Treatment is continued until the subsurface concentration of contaminants is reduced to an acceptable, preselected level. The nutrient fluid can be methane and the oxygenated fluid air for stimulating production of methanotrophs to break down chlorohydrocarbons, especially trichloroethylene (TCE) and tetrachloroethylene.

Hazen, Terry C. (Augusta, GA); Fliermans, Carl B. (Augusta, GA)

1995-01-01T23:59:59.000Z

316

The medieval metal industry was the cradle of modern large-scale atmospheric lead pollution in northern Europe  

SciTech Connect (OSTI)

There is great concern for contamination of sensitive ecosystems in high latitudes by long-range transport of heavy metals and other pollutants derived from industrial areas in lower latitudes. Atmospheric pollution of heavy metals has a very long history, and since metals accumulate in the environment, understanding of present-day pollution conditions requires knowledge of past atmospheric deposition. The authors use analyses of lead concentrations and stable lead isotopes ({sup 206}Pb/{sup 207}Pb ratios) of annually laminated sediments from four lakes in northern Sweden to provide a decadal record of atmospheric lead pollution for the last 3000 years. There is a clear signal in the sediments of airborne pollution from Greek and Roman cultures 2000 years ago, followed by a period of clean conditions 400--900 A.D. From 900 A.D. there was a conspicuous, permanent increase in atmospheric lead pollution fallout, The sediments reveal peaks in atmospheric lead pollution at 1200 and 1530 A.D. comparable to present-day levels. These peaks match the history of metal production in Europe. This study indicates that the contemporary atmospheric pollution climate in northern Europe was established in Medieval time, rather than in the industrial period. Atmospheric lead pollution deposition did not, when seen in a historical perspective, increase as much as usually assumed with the Industrial Revolution.

Braennvall, M.L.; Bindler, R.; Renberg, I.; Emteryd, O.; Bartnicki, J.; Billstroem, K.

1999-12-15T23:59:59.000Z

317

Definition of heavy oil and natural bitumen  

SciTech Connect (OSTI)

Definition and categorization of heavy oils and natural bitumens are generally based on physical or chemical attributes or on methods of extraction. Ultimately, the hydrocarbon's chemical composition will govern both its physical state and the extraction technique applicable. These oils and bitumens closely resemble the residuum from wholecrude distillation to about 1,000/degree/F; if the residuum constitutes at least 15% of the crude, it is considered to be heavy. In this material is concentrated most of the trace elements, such as sulfur, oxygen, and nitrogen, and metals, such as nickel and vanadium. A widely used definition separates heavy oil from natural bitumen by viscosity, crude oil being less, and bitumen more viscous than 10,000 cp. Heavy crude then falls in the range 10/degree/-20/degree/ API inclusive and extra-heavy oil less than 10/degree/ API. Most natural bitumen is natural asphalt (tar sands, oil sands) and has been defined as rock containing hydrocarbons more viscous than 10,000 cp or else hydrocarbons that may be extracted from mined or quarried rock. Other natural bitumens are solids, such as gilsonite, grahamite, and ozokerite, which are distinguished by streak, fusibility, and solubility. The upper limit for heavy oil may also be set at 18/degree/ API, the approximate limit for recovery by waterflood.

Meyer, R.F.

1988-08-01T23:59:59.000Z

318

Contamination Control Techniques  

SciTech Connect (OSTI)

Welcome to a workshop on contamination Control techniques. This work shop is designed for about two hours. Attendee participation is encouraged during the workshop. We will address different topics within contamination control techniques; present processes, products and equipment used here at Hanford and then open the floor to you, the attendees for your input on the topics.

EBY, J.L.

2000-05-16T23:59:59.000Z

319

Structural Basis for Metal Binding Specificity: the N-terminal Cadmium Binding Domain of the  

E-Print Network [OSTI]

In bacteria, P1-type ATPases are responsible for resistance to di- and monovalent toxic heavy metals by taking years and no common mechanism for resistance toward toxic heavy metals such as Cd(II), Zn(II), HgStructural Basis for Metal Binding Specificity: the N-terminal Cadmium Binding Domain of the P1

Scott, Robert A.

320

Bioremediation of contaminated groundwater  

DOE Patents [OSTI]

Disclosed is an apparatus and method for in situ remediation of contaminated subsurface soil or groundwater contaminated by chlorinated hydrocarbons. A nutrient fluid (NF) is selected to simulated the growth and reproduction of indigenous subsurface microorganisms capable of degrading the contaminants; an oxygenated fluid (OF) is selected to create an aerobic environment with anaerobic pockets. NF is injected periodically while OF is injected continuously and both are extracted so that both are drawn across the plume. NF stimulates microbial colony growth; withholding it periodically forces the larger, healthy colony of microbes to degrade the contaminants. Treatment is continued until the subsurface concentration of contaminants is acceptable. NF can be methane and OF be air, for stimulating production of methanotrophs to break down chlorohydrocarbons, especially TCE and tetrachloroethylene.

Hazen, T.C.; Fliermans, C.B.

1994-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "heavy metal contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Environmental Toxicology INTER-AND INTRASPECIFIC VARIATION IN MERCURY BIOACCUMULATION BY SNAKES  

E-Print Network [OSTI]

--Reptiles Heavy metals Pollution Trophic position Stable isotopes INTRODUCTION Although the ecological value change, and environmental pollution [6]. Heavy metal contaminants such as mercury (Hg) are a major

Willson. J.D.

322

Are plants useful as accumulation indicators of metal bioavailabity? E. Remonc,h  

E-Print Network [OSTI]

-mail address: ofaure@emse.fr 25 hal-00771221,version1-8Jan2013 Author manuscript, published in "Environmental at three contaminated30 and one uncontaminated site were compared. Results showed that for two contaminated metal bioavailability in contaminated soils. Keywords: Soil contamination; Phytoavailability

Boyer, Edmond

323

Assessment of biotechnological strategies for the valorization of metal bearing wastes  

SciTech Connect (OSTI)

Highlights: Black-Right-Pointing-Pointer We examine biological strategies to valorize different metal rich solid waste. Black-Right-Pointing-Pointer Bacteria play a key role in the mobilization of Zn and Y from fluorescent powders. Black-Right-Pointing-Pointer Ferrous iron is crucial for the bioleaching of Ni, V, Mo from spent catalysts. Black-Right-Pointing-Pointer No biological effect is observed for Ni, Zn, As, Cr mobilisation from sediments. - Abstract: The present work deals with the application of biotechnology for the mobilization of metals from different solid wastes: end of life industrial catalysts, heavy metal contaminated marine sediments and fluorescent powders coming from a cathode ray tube glass recycling process. Performed experiments were aimed at assessing the performance of acidophilic chemoautotrophic Fe/S-oxidizing bacteria for such different solid matrices, also focusing on the effect of solid concentration and of different substrata. The achieved results have evidenced that metal solubilization seems to be strongly influenced by the metal speciation and partitioning in the solid matrix. No biological effect was observed for Ni, Zn, As, Cr mobilization from marine sediments (34%, 44%, 15%, 10% yields, respectively) due to metal partitioning. On the other hand, for spent refinery catalysts (Ni, V, Mo extractions of 83%, 90% and 40%, respectively) and fluorescent powders (Zn and Y extraction of 55% and 70%, respectively), the improvement in metal extraction observed in the presence of a microbial activity confirms the key role of Fe/S oxidizing bacteria and ferrous iron. A negative effect of solid concentration was in general observed on bioleaching performances, due to the toxicity of dissolved metals and/or to the solid organic component.

Beolchini, Francesca, E-mail: f.beolchini@univpm.it [Department of Life and Environmental Sciences, Universita Politecnica delle Marche, via Brecce Bianche, 60131 Ancona (Italy); Fonti, Viviana; Dell'Anno, Antonio; Rocchetti, Laura [Department of Life and Environmental Sciences, Universita Politecnica delle Marche, via Brecce Bianche, 60131 Ancona (Italy); Veglio, Francesco [Department of Chemistry, Chemical Engineering and Materials, University of L'Aquila, Monteluco di Roio, 67040 L'Aquila (Italy)

2012-05-15T23:59:59.000Z

324

Stabilization of Electrocatalytic Metal Nanoparticles at Metal...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electrocatalytic Metal Nanoparticles at Metal-Metal Oxide-Graphene Triple Junction Points. Stabilization of Electrocatalytic Metal Nanoparticles at Metal-Metal Oxide-Graphene...

325

Bioconversion of Heavy oil.  

E-Print Network [OSTI]

??70 % of world?s oil reservoirs consist of heavy oil, and as the supply of conventional oil decreases, researchers are searching for new technologies to (more)

Steinbakk, Sandra

2011-01-01T23:59:59.000Z

326

Chemical tailoring of steam to remediate underground mixed waste contaminents  

DOE Patents [OSTI]

A method to simultaneously remediate mixed-waste underground contamination, such as organic liquids, metals, and radionuclides involves chemical tailoring of steam for underground injection. Gases or chemicals are injected into a high pressure steam flow being injected via one or more injection wells to contaminated soil located beyond a depth where excavation is possible. The injection of the steam with gases or chemicals mobilizes contaminants, such as metals and organics, as the steam pushes the waste through the ground toward an extraction well having subatmospheric pressure (vacuum). The steam and mobilized contaminants are drawn in a substantially horizontal direction to the extraction well and withdrawn to a treatment point above ground. The heat and boiling action of the front of the steam flow enhance the mobilizing effects of the chemical or gas additives. The method may also be utilized for immobilization of metals by using an additive in the steam which causes precipitation of the metals into clusters large enough to limit their future migration, while removing any organic contaminants.

Aines, Roger D. (Livermore, CA); Udell, Kent S. (Berkeley, CA); Bruton, Carol J. (Livermore, CA); Carrigan, Charles R. (Tracy, CA)

1999-01-01T23:59:59.000Z

327

Comparison and relationship between functional changes of macroinvertebrates and microbial communities in response to resuspension of contaminated sediment  

E-Print Network [OSTI]

communities in response to resuspension of contaminated sediment Fanny Colas1,*, Simon Devin1, & Virginie-mail:fanny.colas@umail.univ-metz.fr) Key words: sediment, metals contamination, resuspension, biomonitoring, macroinvertebrates, microbial contamination of sediments from surrounding industry and urbanization pose a serious ecological threat

Paris-Sud XI, Université de

328

Modeling for Airborne Contamination  

SciTech Connect (OSTI)

The objective of Modeling for Airborne Contamination (referred to from now on as ''this report'') is to provide a documented methodology, along with supporting information, for estimating the release, transport, and assessment of dose to workers from airborne radioactive contaminants within the Monitored Geologic Repository (MGR) subsurface during the pre-closure period. Specifically, this report provides engineers and scientists with methodologies for estimating how concentrations of contaminants might be distributed in the air and on the drift surfaces if released from waste packages inside the repository. This report also provides dose conversion factors for inhalation, air submersion, and ground exposure pathways used to derive doses to potentially exposed subsurface workers. The scope of this report is limited to radiological contaminants (particulate, volatile and gaseous) resulting from waste package leaks (if any) and surface contamination and their transport processes. Neutron activation of air, dust in the air and the rock walls of the drift during the preclosure time is not considered within the scope of this report. Any neutrons causing such activation are not themselves considered to be ''contaminants'' released from the waste package. This report: (1) Documents mathematical models and model parameters for evaluating airborne contaminant transport within the MGR subsurface; and (2) Provides tables of dose conversion factors for inhalation, air submersion, and ground exposure pathways for important radionuclides. The dose conversion factors for air submersion and ground exposure pathways are further limited to drift diameters of 7.62 m and 5.5 m, corresponding to the main and emplacement drifts, respectively. If the final repository design significantly deviates from these drift dimensions, the results in this report may require revision. The dose conversion factors are further derived by using concrete of sufficient thickness to simulate the drift walls. The gamma-ray scattering properties of concrete are sufficiently similar to those of the host rock and proposed insert material; use of concrete will have no significant impact on the conclusions. The information in this report is presented primarily for use in performing pre-closure radiological safety evaluations of radiological contaminants, but it may also be used to develop strategies for contaminant leak detection and monitoring in the MGR. Included in this report are the methods for determining the source terms and release fractions, and mathematical models and model parameters for contaminant transport and distribution within the repository. Various particle behavior mechanisms that affect the transport of contaminant are included. These particle behavior mechanisms include diffusion, settling, resuspension, agglomeration and other deposition mechanisms.

F.R. Faillace; Y. Yuan

2000-08-31T23:59:59.000Z

329

Feed gas contaminant removal in ion transport membrane systems  

DOE Patents [OSTI]

Method for gas purification comprising (a) obtaining a feed gas stream containing one or more contaminants selected from the group consisting of volatile metal oxy-hydroxides, volatile metal oxides, and volatile silicon hydroxide; (b) contacting the feed gas stream with a reactive solid material in a guard bed and reacting at least a portion of the contaminants with the reactive solid material to form a solid reaction product in the guard bed; and (c) withdrawing from the guard bed a purified gas stream.

Carolan, Michael Francis (Allentown, PA); Miller, Christopher Francis (Macungie, PA)

2008-09-16T23:59:59.000Z

330

Analysis of Zinc 65 Contamination after Vacuum Thermal Process  

SciTech Connect (OSTI)

Radioactive contamination with a gamma energy emission consistent with {sup 65}Zn was detected in a glovebox following a vacuum thermal process. The contaminated components were removed from the glovebox and subjected to examination. Selected analytical techniques were used to determine the nature of the precursor material, i.e., oxide or metallic, the relative transferability of the deposit and its nature. The deposit was determined to be borne from natural zinc and was further determined to be deposited as a metallic material from vapor.

Korinko, Paul S.; Tosten, Michael H.

2013-01-01T23:59:59.000Z

331

E-Print Network 3.0 - alkaline-earth metal cations Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

K. (2002): A novel group of alkaline earth metal amides: synthesis... ): Not just heavy "Grignards": Recent advances in the organometallic chemistry of the alkaline earth...

332

E-Print Network 3.0 - al-based metal matrix Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

sensitivity to an additional stressor, ultraviolet-B (UV... -B) radiation. Heavy metal pollution is recognized as a major environmental problem in Rocky Mountain streams...

333

E-Print Network 3.0 - activated metals 6-year Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

sensitivity to an additional stressor, ultraviolet-B (UV... -B) radiation. Heavy metal pollution is recognized as a major environmental problem in Rocky Mountain streams...

334

E-Print Network 3.0 - albumin metal interaction Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

STABILIZATION PONDS... Sheva, Israel (RecewedMay 1986) Abstract--The distribution of toxic heavy metals ... Source: Ben-Gurion University, Department of Electrical and Computer...

335

Organic contaminant separator  

DOE Patents [OSTI]

A process is presented of sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium by (a) passing an initial aqueous medium including a minor amount of the organic contaminant through a composite tube comprised of a blend of a polyolefin and a polyester, the composite tube having an internal diameter of from about 0.1 to about 2.0 millimeters and being of sufficient length to permit the organic contaminant to adhere to the composite tube, (b) passing a solvent through the composite tube. The solvent is capable of separating the adhered organic contaminant from the composite tube. Further, an extraction apparatus is presented for sample preparation prior to analysis for the concentration of an organic contaminant in an aqueous medium. The apparatus includes a composite tube comprised of a blend of a polyolefin and a polyester. The composite tube has an internal diameter of from about 0.1 to about 2.0 millimeters and has sufficient length to permit an organic contaminant contained within an aqueous medium passed therethrough to adhere to the composite tube. 2 figures.

Del Mar, P.

1993-12-28T23:59:59.000Z

336

Removal of metal ions from aqueous solution  

DOE Patents [OSTI]

A method of removing heavy metals from aqueous solution, a composition of matter used in effecting said removal, and apparatus used in effecting said removal. One or more of the polypeptides, poly (.gamma.-glutamylcysteinyl)glycines, is immobilized on an inert material in particulate form. Upon contact with an aqueous solution containing heavy metals, the polypeptides sequester the metals, removing them from the solution. There is selectivity of poly (.gamma.-glutamylcysteinyl)glycines having a particular number of monomer repeat unit for particular metals. The polypeptides are easily regenerated by contact with a small amount of an organic acid, so that they can be used again to remove heayv metals from solution. This also results in the removal of the metals from the column in a concentrated form.

Jackson, Paul J. (both Los Alamos, NM); Delhaize, Emmanuel (both Los Alamos, NM); Robinson, Nigel J. (Durham, GB2); Unkefer, Clifford J. (Los Alamos, NM); Furlong, Clement (Seattle, WA)

1990-11-13T23:59:59.000Z

337

Heavy-Section Steel Irradiation Program  

SciTech Connect (OSTI)

Maintaining the integrity of the reactor pressure vessel (RPV) in a light-water-cooled nuclear power plant is crucial in preventing and controlling severe accidents that have the potential for major contamination release. Because the RPV is the only key safety-related component of the plant for which a redundant backup system does not exist, it is imperative to fully understand the degree of irradiation-induced degradation of the RPV's fracture resistance that occurs during service. For this reason, the Heavy-Section Steel Irradiation (HSSI) Program has been established.

Rosseel, T.M.

2000-04-01T23:59:59.000Z

338

Dissimilatory Metal Reduction by Anaeromyxobacter Species  

SciTech Connect (OSTI)

Recent findings suggest that Anaeromyxobacter populations play relevant roles in metal and radionuclide reduction and immobilization at contaminated DOE sites. This research effort will characterize Anaeromyxobacter dehalogenans strain 2CP-C as well as other Anaeromyxobacter isolates in hand, and assess their contribution towards metal detoxification and plume stabilization under environmentally relevant conditions.

Qingzhong Wu; Cornell Gayle; Frank Lffler; Sanford, Robert

2004-03-17T23:59:59.000Z

339

RAHATE et al. Low Cost Efficient Treatment for Contaminated  

E-Print Network [OSTI]

sources due to geogenic activities, industries and agricultural sources. The removal of heavy metals e, mining, chemical manufacturing, pesticides, fertilizers, dyes, pigments, tanning and battery exposes human health to severe risks, as it can aggravate cancer, bone damage, vomiting, diarrhea, kidney

Paris-Sud XI, Université de

340

Biosorption of anionic metal complexes Hui Niu and Bohumil Volesky*  

E-Print Network [OSTI]

containing toxic heavy metals, often in anionic complex forms such as anionic chromate (CrO4 2- ), vanadate1 Biosorption of anionic metal complexes Hui Niu and Bohumil Volesky* http Street, MONTREAL, Canada H3A 2B2 *corresponding author Anionic metal complexes, are very effectively

Volesky, Bohumil

Note: This page contains sample records for the topic "heavy metal contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Interactions of microbes in terrestrial systems Initial studies on terrestrial systems focused on aquifer material that was analyzed for the  

E-Print Network [OSTI]

and effect of heavy metals in salt marsh sediments. Environmental Pollution 149, 79, for example, that heavy metal contamination leads to shifts in microbial evaluated the usefulness of S. patens in phytoremediation of heavy metal

Upchurch, Gary - Department of Biology, Texas State University

342

E-Print Network 3.0 - airbone trace metals Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and Loss of Heavy Metals from Experimental Salt Marsh Plots Summary: L of 12 M trace metal grade hydrochloric acid (HCl) and reheated the samples to 65-80 C in a water bath......

343

E-Print Network 3.0 - arabidopsis halleri metal Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Statistics, University of Warwick Collection: Mathematics 13 Humus forms and metal pollution in soil S. GILLET & J.F. PONGE Summary: . A sward of plants tolerant of heavy metals...

344

Managing contaminated sites  

SciTech Connect (OSTI)

This book summarizes the generic principles of contaminated site management. The book walks the reader through contaminated site identification, risk assessment and the evaluation of remediation alternatives. The book is divided into two major sections, problem diagnosis and development of site restoration. In problem diagnosis, the general principles of site investigation are discussed, including the objectives and differences between tier 1,2, and 3 investigations. The principles of data collection and analysis are presented. A small quantitative discussion of statistical analysis is presented but in keeping with the objectives of the text is not sufficient comprehensive or detailed to provide much of a guide for the practitioner. Chapters on contaminant fate and transport processes and risk assessment help the reader understand the role of these issues in site investigation and remedial planning. A chapter is also included on elements of a site characterization activity, which summarizes some of the key considerations in conducting a site investigation.

Asante-Duah, D.K.

1997-12-31T23:59:59.000Z

345

Nitrided Metallic Bipolar Plates  

SciTech Connect (OSTI)

The objectives are: (1) Develop and optimize stainless steel alloys amenable to formation of a protective Cr-nitride surface by gas nitridation, at a sufficiently low cost to meet DOE targets and with sufficient ductility to permit manufacture by stamping. (2) Demonstrate capability of nitridation to yield high-quality stainless steel bipolar plates from thin stamped alloy foils (no significant stamped foil warping or embrittlement). (3) Demonstrate single-cell fuel cell performance of stamped and nitrided alloy foils equivalent to that of machined graphite plates of the same flow-field design ({approx}750-1,000 h, cyclic conditions, to include quantification of metal ion contamination of the membrane electrode assembly [MEA] and contact resistance increase attributable to the bipolar plates). (4) Demonstrate potential for adoption in automotive fuel cell stacks. Thin stamped metallic bipolar plates offer the potential for (1) significantly lower cost than currently-used machined graphite bipolar plates, (2) reduced weight/volume, and (3) better performance and amenability to high volume manufacture than developmental polymer/carbon fiber and graphite composite bipolar plates. However, most metals exhibit inadequate corrosion resistance in proton exchange membrane fuel cell (PEMFC) environments. This behavior leads to high electrical resistance due to the formation of surface oxides and/or contamination of the MEA by metallic ions, both of which can significantly degrade fuel cell performance. Metal nitrides offer electrical conductivities up to an order of magnitude greater than that of graphite and are highly corrosion resistant. Unfortunately, most conventional coating methods (for metal nitrides) are too expensive for PEMFC stack commercialization or tend to leave pinhole defects, which result in accelerated local corrosion and unacceptable performance.

Brady, Michael P [ORNL; Tortorelli, Peter F [ORNL; Pihl, Josh A [ORNL; Toops, Todd J [ORNL; More, Karren Leslie [ORNL; Meyer III, Harry M [ORNL; Vitek, John Michael [ORNL; Wang, Heli [National Renewable Energy Laboratory (NREL); Turner, John [National Renewable Energy Laboratory (NREL); Wilson, Mahlon [Los Alamos National Laboratory (LANL); Garzon, Fernando [Los Alamos National Laboratory (LANL); Rockward, Tommy [Los Alamos National Laboratory (LANL); Connors, Dan [GenCell Corp; Rakowski, Jim [Allegheny Ludlum; Gervasio, Don [Arizona State University

2008-01-01T23:59:59.000Z

346

Development of an Integrated Multi-Contaminant Removal Process Applied to Warm Syngas Cleanup for Coal-Based Advanced Gasification Systems  

SciTech Connect (OSTI)

This project met the objective to further the development of an integrated multi-contaminant removal process in which H2S, NH3, HCl and heavy metals including Hg, As, Se and Cd present in the coal-derived syngas can be removed to specified levels in a single/integrated process step. The process supports the mission and goals of the Department of Energy??s Gasification Technologies Program, namely to enhance the performance of gasification systems, thus enabling U.S. industry to improve the competitiveness of gasification-based processes. The gasification program will reduce equipment costs, improve process environmental performance, and increase process reliability and flexibility. Two sulfur conversion concepts were tested in the laboratory under this project, i.e., the solventbased, high-pressure University of California Sulfur Recovery Process ?? High Pressure (UCSRP-HP) and the catalytic-based, direct oxidation (DO) section of the CrystaSulf-DO process. Each process required a polishing unit to meet the ultra-clean sulfur content goals of <50 ppbv (parts per billion by volume) as may be necessary for fuel cells or chemical production applications. UCSRP-HP was also tested for the removal of trace, non-sulfur contaminants, including ammonia, hydrogen chloride, and heavy metals. A bench-scale unit was commissioned and limited testing was performed with simulated syngas. Aspen-Plus®-based computer simulation models were prepared and the economics of the UCSRP-HP and CrystaSulf-DO processes were evaluated for a nominal 500 MWe, coal-based, IGCC power plant with carbon capture. This report covers the progress on the UCSRP-HP technology development and the CrystaSulf-DO technology.

Howard Meyer

2010-11-30T23:59:59.000Z

347

Metal aminoboranes  

DOE Patents [OSTI]

Metal aminoboranes of the formula M(NH2BH3)n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other metal aminoboranes. Metal aminoboranes can be dehydrogenated to form hydrogen and a reaction product. The reaction product can react with hydrogen to form a hydrogen storage material. Metal aminoboranes can be included in a kit.

Burrell, Anthony K.; Davis, Benjamin J.; Thorn, David L.; Gordon, John C.; Baker, R. Thomas; Semelsberger, Troy Allen; Tumas, William; Diyabalanage, Himashinie Vichalya; Shrestha, Roshan P.

2010-05-11T23:59:59.000Z

348

Directly susceptible, noncarbon metal ceramic composite crucible  

DOE Patents [OSTI]

A sintered metal ceramic crucible suitable for high temperature induction melting of reactive metals without appreciable carbon or silicon contamination of the melt. The crucible comprises a cast matrix of a thermally conductive ceramic material; a perforated metal sleeve, which serves as a susceptor for induction heating of the crucible, embedded within the ceramic cast matrix; and a thermal-shock-absorber barrier interposed between the metal sleeve and the ceramic cast matrix to allow for differential thermal expansions between the matrix and the metal sleeve and to act as a thermal-shock-absorber which moderates the effects of rapid changes of sleeve temperature on the matrix.

Holcombe, Jr., Cressie E. (Farragut, TN); Kiggans, Jr., James O. (Oak Ridge, TN); Morrow, S. Marvin (Kingston, TN); Rexford, Donald (Pattersonville, NY)

1999-01-01T23:59:59.000Z

349

Zinc Speciation in a Smelter-Contaminated Soil Profile  

E-Print Network [OSTI]

Zinc Speciation in a Smelter-Contaminated Soil Profile Using Bulk and Microspectroscopic Techniques minerals may have been aerially deposited from the smelter operation. Microspec- troscopy detected also in increased trace metal concentrations and acidic pH values in topsoils in the vicinity of smelter facilities

Sparks, Donald L.

350

EA-1919: Recycle of Scrap Metals Originating from Radiological Areas  

Broader source: Energy.gov [DOE]

This Programmatic EA evaluates alternatives for the management of scrap metal originating from DOE radiological control areas, including the proposed action to allow for the recycle of uncontaminated scrap metal that meets the requirements of DOE Order 458.1. (Metals with volumetric radioactive contamination are not included in the scope of this Programmatic EA.)

351

Author-produced version of the article published in Archives of Environmental Contamination and Toxicology, 2007, 53, 57-65.  

E-Print Network [OSTI]

. These results indicate that metallothionein is a more sensitive indicator of heavy metal pollution, compared;1 BIOACCUMULATION OF METALS IN SEDIMENT ELUTRIATES AND THEIR EFFECTS ON GROWTH, CONDITION INDEX AND METALLOTHIONEIN growth, Metal bioaccumulation, Metallothionein. Abstract: The bioavailability of Cd, Cu, Zn and Pb from

Paris-Sud XI, Université de

352

Heavy Hybrid mesons Masses  

E-Print Network [OSTI]

We estimate the ground state masses of the heavy hybrid mesons using a phenomenological QCD-type potential. 0^{- -},1^{- -},0^{- +},1^{- +} and 0^{+ -} J^{PC} states are considered.

F. Iddir; L. Semlala

2006-11-13T23:59:59.000Z

353

Mercury contamination extraction  

DOE Patents [OSTI]

Mercury is removed from contaminated waste by firstly applying a sulfur reagent to the waste. Mercury in the waste is then permitted to migrate to the reagent and is stabilized in a mercury sulfide compound. The stable compound may then be removed from the waste which itself remains in situ following mercury removal therefrom.

Fuhrmann, Mark (Silver Spring, MD); Heiser, John (Bayport, NY); Kalb, Paul (Wading River, NY)

2009-09-15T23:59:59.000Z

354

Subsurface Contamination Control  

SciTech Connect (OSTI)

There are two objectives of this report, ''Subsurface Contamination Control''. The first is to provide a technical basis for recommending limiting radioactive contamination levels (LRCL) on the external surfaces of waste packages (WP) for acceptance into the subsurface repository. The second is to provide an evaluation of the magnitude of potential releases from a defective WP and the detectability of the released contents. The technical basis for deriving LRCL has been established in ''Retrieval Equipment and Strategy for Wp on Pallet'' (CRWMS M and O 2000g, 6.3.1). This report updates the derivation by incorporating the latest design information of the subsurface repository for site recommendation. The derived LRCL on the external surface of WPs, therefore, supercede that described in CRWMS M and O 2000g. The derived LRCL represent the average concentrations of contamination on the external surfaces of each WP that must not be exceeded before the WP is to be transported to the subsurface facility for emplacement. The evaluation of potential releases is necessary to control the potential contamination of the subsurface repository and to detect prematurely failed WPs. The detection of failed WPs is required in order to provide reasonable assurance that the integrity of each WP is intact prior to MGR closure. An emplaced WP may become breached due to manufacturing defects or improper weld combined with failure to detect the defect, by corrosion, or by mechanical penetration due to accidents or rockfall conditions. The breached WP may release its gaseous and volatile radionuclide content to the subsurface environment and result in contaminating the subsurface facility. The scope of this analysis is limited to radioactive contaminants resulting from breached WPs during the preclosure period of the subsurface repository. This report: (1) documents a method for deriving LRCL on the external surfaces of WP for acceptance into the subsurface repository; (2) provides a table of derived LRCL for nuclides of radiological importance; (3) Provides an as low as is reasonably achievable (ALARA) evaluation of the derived LRCL by comparing potential onsite and offsite doses to documented ALARA requirements; (4) Provides a method for estimating potential releases from a defective WP; (5) Provides an evaluation of potential radioactive releases from a defective WP that may become airborne and result in contamination of the subsurface facility; and (6) Provides a preliminary analysis of the detectability of a potential WP leak to support the design of an airborne release monitoring system.

Y. Yuan

2001-11-16T23:59:59.000Z

355

Subsurface Contamination Control  

SciTech Connect (OSTI)

There are two objectives of this report, ''Subsurface Contamination Control''. The first is to provide a technical basis for recommending limiting radioactive contamination levels (LRCL) on the external surfaces of waste packages (WP) for acceptance into the subsurface repository. The second is to provide an evaluation of the magnitude of potential releases from a defective WP and the detectability of the released contents. The technical basis for deriving LRCL has been established in ''Retrieval Equipment and Strategy for Wp on Pallet'' (CRWMS M and O 2000g, 6.3.1). This report updates the derivation by incorporating the latest design information of the subsurface repository for site recommendation. The derived LRCL on the external surface of WPs, therefore, supercede that described in CRWMS M and O 2000g. The derived LRCL represent the average concentrations of contamination on the external surfaces of each WP that must not be exceeded before the WP is to be transported to the subsurface facility for emplacement. The evaluation of potential releases is necessary to control the potential contamination of the subsurface repository and to detect prematurely failed WPs. The detection of failed WPs is required in order to provide reasonable assurance that the integrity of each WP is intact prior to MGR closure. An emplaced WP may become breached due to manufacturing defects or improper weld combined with failure to detect the defect, by corrosion, or by mechanical penetration due to accidents or rockfall conditions. The breached WP may release its gaseous and volatile radionuclide content to the subsurface environment and result in contaminating the subsurface facility. The scope of this analysis is limited to radioactive contaminants resulting from breached WPs during the preclosure period of the subsurface repository. This report: (1) documents a method for deriving LRCL on the external surfaces of WP for acceptance into the subsurface repository; (2) provides a table of derived LRCL for nuclides of radiological importance; (3) Provides an as low as is reasonably achievable (ALARA) evaluation of the derived LRCL by comparing potential onsite and offsite doses to documented ALARA requirements; (4) Provides a method for estimating potential releases from a defective WP; (5) Provides an evaluation of potential radioactive releases from a defective WP that may become airborne and result in contamination of the subsurface facility; and (6) Provides a preliminary analysis of the detectability of a potential WP leak to support the design of an airborne release monitoring system.

Y. Yuan

2001-12-12T23:59:59.000Z

356

Single-layer transition metal sulfide catalysts  

DOE Patents [OSTI]

Transition Metal Sulfides (TMS), such as molybdenum disulfide (MoS.sub.2), are the petroleum industry's "workhorse" catalysts for upgrading heavy petroleum feedstocks and removing sulfur, nitrogen and other pollutants from fuels. We have developed an improved synthesis technique to produce SLTMS catalysts, such as molybdenum disulfide, with potentially greater activity and specificity than those currently available. Applications for this technology include heavy feed upgrading, in-situ catalysis, bio-fuel conversion and coal liquefaction.

Thoma, Steven G. (Albuquerque, NM)

2011-05-31T23:59:59.000Z

357

Photobiont diversity in lichens from metal-rich substrata based on ITS rDNA sequences  

E-Print Network [OSTI]

sensitive partner of lichen symbiosis in metal pollution. For this reason the presence of a metal tolerant photobiont in lichens may be a key factor of ecological success of lichens growing on metal polluted heavy metal content (in localities as well as lichen thalli) and photobiont diversity. Presence

358

Management of Transuranic Contaminated Material  

Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

To establish guidelines for the generation, treatment, packaging, storage, transportation, and disposal of transuranic (TRU) contaminated material.

1982-09-30T23:59:59.000Z

359

Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons  

DOE Patents [OSTI]

A method of upgrading an oil feedstock by removing heteroatoms and/or one or more heavy metals from the oil feedstock composition. This method reacts the oil feedstock with an alkali metal and an upgradant hydrocarbon. The alkali metal reacts with a portion of the heteroatoms and/or one or more heavy metals to form an inorganic phase separable from the organic oil feedstock material. The upgradant hydrocarbon bonds to the oil feedstock material and increases the number of carbon atoms in the product. This increase in the number of carbon atoms of the product increases the energy value of the resulting oil feedstock.

Gordon, John Howard

2014-09-09T23:59:59.000Z

360

Radioactive Contamination of Danish Territory  

E-Print Network [OSTI]

Risø-R-462 Radioactive Contamination of Danish Territory after Core-melt Accidents at the Barsebäck;#12;RIS0-R-462 RADIOACTIVE CONTAMINATION OF DANISH TERRITORY AFTER CORE-MELT ACCIDENTS AT THE BARSEBACK. An assessment is made of the radioactive contamination of Danish territory in the event of a core-melt accident

Note: This page contains sample records for the topic "heavy metal contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Containment of subsurface contaminants  

DOE Patents [OSTI]

A barrier is disclosed for reducing the spread of a plume of subsurface contaminants. The apparatus includes a well system for injecting a fluid, such as air, just outside and below the periphery of the plume. The fluid is injected at a pressure sufficient to lower the hydraulic conductivity of the soil from the point of injection to the surface thus establishing a curtain-like barrier to groundwater movement. The barrier is established upgradient of the plume to divert groundwater away, or preferably completely around the plume to reduce the flow of groundwater into or out of the plume. The barrier enables the remediation of the confined contamination and then, when the injection of the fluid is halted, the barrier quickly dissipates. 5 figs.

Corey, J.C.

1994-09-06T23:59:59.000Z

362

Containment of subsurface contaminants  

DOE Patents [OSTI]

A barrier for reducing the spread of a plume of subsurface contaminants. The apparatus includes a well system for injecting a fluid, such as air, just outside and below the periphery of the plume. The fluid is injected at a pressure sufficient to lower the hydraulic conductivity of the soil from the point of injection to the surface thus establishing a curtain-like barrier to groundwater movement. The barrier is established upgradient of the plume to divert groundwater away, or preferably completely around the plume to reduce the flow of groundwater into or out of the plume. The barrier enables the remediation of the confined contamination and then, when the injection of the fluid is halted, the barrier quickly dissipates.

Corey, John C. (Aiken, SC)

1994-01-01T23:59:59.000Z

363

GROUND WATER CONTAMINATION  

SciTech Connect (OSTI)

As required by the terms of the above referenced grant, the following summary serves as the Final Report for that grant. The grant relates to work performed at two separate sites, the Hoe Creek Underground Coal Gasification Site south of Gillette, Wyoming, and the Rock Springs In-Situ Oil Shale Retort Site near Rock Springs, Wyoming. The primary concern to the State of Wyoming at each site is ground water contamination (the primary contaminants of concern are benzene and related compounds), and the purpose of the grant has been to provide tiding for a Geohydrologist at the appropriate State agency, specifically the Land Quality Division (LQD) of the Wyoming Department of Environmental Quality. The LQD Geohydrologist has been responsible for providing technical and regulatory support to DOE for ground water remediation and subsequent surface reclamation. Substantial progress has been made toward remediation of the sites, and continuation of LQD involvement in the remediation and reclamation efforts is addressed.

Unknown

1999-09-01T23:59:59.000Z

364

Purifying contaminated water  

SciTech Connect (OSTI)

Process for removing biorefractory compounds from contaminated water (e.g., oil shale retort waste-water) by contacting same with fragmented raw oil shale. Biorefractory removal is enhanced by preactivating the oil shale with at least one member of the group of carboxylic, acids, alcohols, aldehydes, ketones, ethers, amines, amides, sulfoxides, mixed ether-esters and nitriles. Further purification is obtained by stripping, followed by biodegradation and removal of the cells.

Daughton, Christian G. (San Pablo, CA)

1983-01-01T23:59:59.000Z

365

Method for removing metal vapor from gas streams  

DOE Patents [OSTI]

A process for cleaning an inert gas contaminated with a metallic vapor, such as cadmium, involves withdrawing gas containing the metallic contaminant from a gas atmosphere of high purity argon; passing the gas containing the metallic contaminant to a mass transfer unit having a plurality of hot gas channels separated by a plurality of coolant gas channels; cooling the contaminated gas as it flows upward through the mass transfer unit to cause contaminated gas vapor to condense on the gas channel walls; regenerating the gas channels of the mass transfer unit; and, returning the cleaned gas to the gas atmosphere of high purity argon. The condensing of the contaminant-containing vapor occurs while suppressing contaminant particulate formation, and is promoted by providing a sufficient amount of surface area in the mass transfer unit to cause the vapor to condense and relieve supersaturation buildup such that contaminant particulates are not formed. Condensation of the contaminant is prevented on supply and return lines in which the contaminant containing gas is withdrawn and returned from and to the electrorefiner and mass transfer unit by heating and insulating the supply and return lines. 13 figs.

Ahluwalia, R.K.; Im, K.H.

1996-04-02T23:59:59.000Z

366

Method for removing metal vapor from gas streams  

DOE Patents [OSTI]

A process for cleaning an inert gas contaminated with a metallic vapor, such as cadmium, involves withdrawing gas containing the metallic contaminant from a gas atmosphere of high purity argon; passing the gas containing the metallic contaminant to a mass transfer unit having a plurality of hot gas channels separated by a plurality of coolant gas channels; cooling the contaminated gas as it flows upward through the mass transfer unit to cause contaminated gas vapor to condense on the gas channel walls; regenerating the gas channels of the mass transfer unit; and, returning the cleaned gas to the gas atmosphere of high purity argon. The condensing of the contaminant-containing vapor occurs while suppressing contaminant particulate formation, and is promoted by providing a sufficient amount of surface area in the mass transfer unit to cause the vapor to condense and relieve supersaturation buildup such that contaminant particulates are not formed. Condensation of the contaminant is prevented on supply and return lines in which the contaminant containing gas is withdrawn and returned from and to the electrorefiner and mass transfer unit by heating and insulating the supply and return lines.

Ahluwalia, R. K. (6440 Hillcrest Dr., Burr Ridge, IL 60521); Im, K. H. (925 Lehigh Cir., Naperville, IL 60565)

1996-01-01T23:59:59.000Z

367

Understanding Contamination; Twenty Years of Simulating Radiological Contamination  

SciTech Connect (OSTI)

A wide variety of simulated contamination methods have been developed by researchers to reproducibly test radiological decontamination methods. Some twenty years ago a method of non-radioactive contamination simulation was proposed at the Idaho National Laboratory (INL) that mimicked the character of radioactive cesium and zirconium contamination on stainless steel. It involved baking the contamination into the surface of the stainless steel in order to 'fix' it into a tenacious, tightly bound oxide layer. This type of contamination was particularly applicable to nuclear processing facilities (and nuclear reactors) where oxide growth and exchange of radioactive materials within the oxide layer became the predominant model for material/contaminant interaction. Additional simulation methods and their empirically derived basis (from a nuclear fuel reprocessing facility) are discussed. In the last ten years the INL, working with the Defense Advanced Research Projects Agency (DARPA) and the National Homeland Security Research Center (NHSRC), has continued to develop contamination simulation methodologies. The most notable of these newer methodologies was developed to compare the efficacy of different decontamination technologies against radiological dispersal device (RDD, 'dirty bomb') type of contamination. There are many different scenarios for how RDD contamination may be spread, but the most commonly used one at the INL involves the dispersal of an aqueous solution containing radioactive Cs-137. This method was chosen during the DARPA projects and has continued through the NHSRC series of decontamination trials and also gives a tenacious 'fixed' contamination. Much has been learned about the interaction of cesium contamination with building materials, particularly concrete, throughout these tests. The effects of porosity, cation-exchange capacity of the material and the amount of dirt and debris on the surface are very important factors. The interaction of the contaminant/substrate with the particular decontamination technology is also very important. Results of decontamination testing from hundreds of contaminated coupons have lead to certain conclusions about the contamination and the type of decontamination methods being deployed. A recent addition to the DARPA initiated methodology simulates the deposition of nuclear fallout. This contamination differs from previous tests in that it has been developed and validated purely to simulate a 'loose' type of contamination. This may represent the first time that a radiologically contaminated 'fallout' stimulant has been developed to reproducibly test decontamination methods. While no contaminant/methodology may serve as a complete example of all aspects that could be seen in the field, the study of this family of simulation methods provides insight into the nature of radiological contamination.

Emily Snyder; John Drake; Ryan James

2012-02-01T23:59:59.000Z

368

Surface Contamination Surface contamination from radioactive isotopes is a source of background in the Borex-  

E-Print Network [OSTI]

Chapter 5 Surface Contamination Surface contamination from radioactive isotopes is a source contamination is primarily a problem because the radioactive contaminants can be trans- ferred from the surfaces detector components that come in contact with the scintillator. Preventing radioactive contamination

369

Metal volatilization and separation during incineration  

SciTech Connect (OSTI)

The US Environmental Protection Agency (US EPA) has reported that metals can account for almost all of the identified risks from a thermal treatment process. Fundamental research leading to better understanding of their behavior and improved control of their emissions is greatly needed. This paper reports studies on metal volatilization and separation during incineration. Metal volatilization studies were carried out in two separate experiments. In the first experiment, the dynamic volatilization characteristics of various metals during the combustion of metal-containing wood pellets were investigated in a high-temperature electric furnace. In addition to uncontrolled volatilization, the potential of employing chemical additives to bind metals and prevent them from volatilizing during combustion was also investigated. The second experiment involved the investigation of metal volatilization characteristics during the thermal treatment of metal-contaminated clay in a fluidized bed unit. The metal species tested in both experiments were compounds of lead and cadmium. Metal capture/separation studies were also carried out in two separate experiments. The first involved the use of sorbents in the combustion chamber to capture metals during the fluidized bed incineration of metal-containing wood pellets. The second experiments, however, employed sorbents to absorb metal vapors in a fluidized-bed waste-heat boiler. The objective of both the experiments is to characterize the metal absorption efficiency associated with the processes.

Ho, T.C.; Chu, H.W.; Hopper, J.R. (Lamar Univ., Beaumont, TX (United States). Dept. of Chemical Engineering)

1993-01-01T23:59:59.000Z

370

In-situ generation of oxygen-releasing metal peroxides  

DOE Patents [OSTI]

A method for remediation of contaminants in soil and groundwater is disclosed. The method generates oxygen releasing solids in groundwater or soil by injecting an aqueous energetic oxidant solution containing free radicals, oxidative conditions can be created within or ahead of a contaminant plume. Some contaminants may be remediated directly by reaction with the free radicals. Additionally and more importantly, the free radicals create an oxidative condition whereby native or injected materials, especially metals, are converted to peroxides. These peroxides provide a long-term oxygen reservoir, releasing oxygen relatively slowly over time. The oxygen can enhance microbial metabolism to remediate contaminants, can react with contaminant metals either to form immobile precipitants or to mobilize other metals to permit remediation through leaching techniques. Various injection strategies for injecting the energetic oxidant solution are also disclosed.

Looney, Brian B. (Aiken, SC); Denham, Miles E. (Aiken, SC)

2007-01-09T23:59:59.000Z

371

Oxygen and Nitroaen Contamination During Submerged Arc Wel ding of Titanium  

E-Print Network [OSTI]

) ) ) ··- -~ Oxygen and Nitroaen Contamination During Submerged Arc Wel ding of Titanium T· \\v· Eagar* The oxygen content of ti tanium submerged arc wel ~ metal is primaril y derendent uron the purity of the fluo1~ ide fluxes, but it is shown here that the oxygen content of the weld metal may be affected

Eagar, Thomas W.

372

Understanding Mechanisms of Radiological Contamination  

SciTech Connect (OSTI)

Over the last 50 years, the study of radiological contamination and decontamination has expanded significantly. This paper addresses the mechanisms of radiological contamination that have been reported and then discusses which methods have recently been used during performance testing of several different decontamination technologies. About twenty years ago the Idaho Nuclear Technology Engineering Center (INTEC) at the INL began a search for decontamination processes which could minimize secondary waste. In order to test the effectiveness of these decontamination technologies, a new simulated contamination, termed SIMCON, was developed. SIMCON was designed to replicate the types of contamination found on stainless steel, spent fuel processing equipment. Ten years later, the INL began research into methods for simulating urban contamination resulting from a radiological dispersal device (RDD). This work was sponsored by the Defense Advanced Research Projects Agency (DARPA) and included the initial development an aqueous application of contaminant to substrate. Since 2007, research sponsored by the US Environmental Protection Agency (EPA) has advanced that effort and led to the development of a contamination method that simulates particulate fallout from an Improvised Nuclear Device (IND). The IND method diverges from previous efforts to create tenacious contamination by simulating a reproducible loose contamination. Examining these different types of contamination (and subsequent decontamination processes), which have included several different radionuclides and substrates, sheds light on contamination processes that occur throughout the nuclear industry and in the urban environment.

Rick Demmer; John Drake; Ryan James, PhD

2014-03-01T23:59:59.000Z

373

Transition metal interaction and Ni-Fe-Cu-Si phases in silicon T. Buonassisi,b  

E-Print Network [OSTI]

precipitation may reduce the lattice mismatch compared to single-metal precipitates, rendering mixed-metal-silicide recombination activity of metal silicide clusters. Common solar cell materials are not contaminated with justTransition metal interaction and Ni-Fe-Cu-Si phases in silicon M. Heuer,a T. Buonassisi,b A. A

374

Investigation of the possibility of decontamination of bitumen concrete pavement contaminated with radionuclides  

SciTech Connect (OSTI)

Radioactive contamination of the environment is possible during operation of nuclear power plants and the utilization of radionuclide sources in the economy. The problem of decontaminating the surfaces of industrial objects and environmental objects which are contaminated by radionuclides can be solved by different methods of depending on the character of the object: chemical treatment of metallic surfaces of equipment parts by application of different washing fluids, mechanical removal of contaminants or washing contaminants off with a jet of liquid, as well as adding different abrasive additives, the use of film-forming substances for sorption and removal of the decontaminating layer from the surface being cleaned, and other methods.

Karlina, O.K.; Ovchinnikov, A.V.; Ozhovan, M.I. [and others

1995-10-01T23:59:59.000Z

375

Metal inks  

DOE Patents [OSTI]

Self-reducing metal inks and systems and methods for producing and using the same are disclosed. In an exemplary embodiment, a method may comprise selecting metal-organic (MO) precursor, selecting a reducing agent, and dissolving the MO precursor and the reducing agent in an organic solvent to produce a metal ink that remains in a liquid phase at room temperature. Metal inks, including self-reducing and fire-through metal inks, are also disclosed, as are various applications of the metal inks.

Ginley, David S; Curtis, Calvin J; Miedaner, Alex; van Hest, Marinus Franciscus Antonius Maria; Kaydanova, Tatiana

2014-02-04T23:59:59.000Z

376

A comparison of genetic variation between Black-Crowned Night Heron (Nycticorax nycticorax) populations from contaminated and reference sites  

E-Print Network [OSTI]

I examined genetic variation for two populations of Black-crowned Night Herons using a 467 base pair region of the mitochondrial DNA. One population inhabits an environment highly impacted by industrial waste, heavy metals, and urbanization; while...

Bernard, Danielle Summer

2007-04-25T23:59:59.000Z

377

Gas: A Neglected Phase in Remediation of Metals and Radionuclides  

SciTech Connect (OSTI)

The gas phase is generally ignored in remediation of metals and radionuclides because it is assumed that there is no efficient way to exploit it. In the literal sense, all remediations involve the gas phase because this phase is linked to the liquid and solid phases by vapor pressure and thermodynamic relationships. Remediation methods that specifically use the gas phase as a central feature have primarily targeted volatile organic contaminants, not metals and radionuclides. Unlike many organic contaminants, the vapor pressure and Henry's Law constants of metals and radionuclides are not generally conducive to direct air stripping of dissolved contaminants. Nevertheless, the gas phase can play an important role in remediation of inorganic contaminants and provide opportunities for efficient, cost effective remediation. The objective here is to explore ways in which manipulation of the gas phase can be used to facilitate remediation of metals and radionuclides.

Denham, Miles E.; Looney, Brian B

2005-09-28T23:59:59.000Z

378

OPEN AIR DEMOLITION OF FACILITIES HIGHLY CONTAMINATED WITH PLUTONIUM  

SciTech Connect (OSTI)

The demolition of highly contaminated plutonium buildings usually is a long and expensive process that involves decontaminating the building to near free- release standards and then using conventional methods to remove the structure. It doesn't, however, have to be that way. Fluor has torn down buildings highly contaminated with plutonium without excessive decontamination. By removing the select source term and fixing the remaining contamination on the walls, ceilings, floors, and equipment surfaces; open-air demolition is not only feasible, but it can be done cheaper, better (safer), and faster. Open-air demolition techniques were used to demolish two highly contaminated buildings to slab-on-grade. These facilities on the Department of Energy's Hanford Site were located in, or very near, compounds of operating nuclear facilities that housed hundreds of people working on a daily basis. To keep the facilities operating and the personnel safe, the projects had to be creative in demolishing the structures. Several key techniques were used to control contamination and keep it within the confines of the demolition area: spraying fixatives before demolition; applying fixative and misting with a fine spray of water as the buildings were being taken down; and demolishing the buildings in a controlled and methodical manner. In addition, detailed air-dispersion modeling was done to establish necessary building and meteorological conditions and to confirm the adequacy of the proposed methods. Both demolition projects were accomplished without any spread of contamination outside the modest buffer areas established for contamination control. Furthermore, personnel exposure to radiological and physical hazards was significantly reduced by using heavy equipment rather than ''hands on'' techniques.

LLOYD, E.R.

2007-05-31T23:59:59.000Z

379

Explosive Contamination from Substrate Surfaces: Differences and Similarities in Contamination Techniques using RDX and C-4  

SciTech Connect (OSTI)

The amount of time that an explosive is present on the surface of a material is dependent upon the original amount of explosive on the surface, temperature, humidity, rain, etc. This laboratory study focused on looking at similarities and differences in three different surface contamination techniques that are used when performance testing explosive trace detection equipment in an attempt to determine how effective the techniques are at replicating actual field samples. The three techniques used were dry transfer deposition of solutions using the Transportation Security Laboratory (TSL) patented dry transfer techniques (US patent 6470730), direct deposition of explosive standards, and fingerprinting of actual explosives. Explosives were deposited on the surface of one of five substrates using one of the three different deposition techniques. The process was repeated for each surface type using each contamination technique. The surface types used were: 50% cotton/50% polyester as found in T-shirts, 100% cotton with a smooth surface such as that found in a cotton dress shirt, 100% cotton on a rough surface such as that found on canvas or denim, suede leather such as might be found on jackets, purses, or shoes, and metal obtained from a car hood at a junk yard. The samples were not pre-cleaned prior to testing and contained sizing agents, and in the case of the metal, oil and dirt. The substrates were photographed using a Zeiss Discover V12 stereoscope with Axiocam ICc1 3 megapixel digital camera to determine the difference in the crystalline structure and surface contamination in an attempt to determine differences and similarities associated with current contamination techniques.

C.J. Miller; T.S. Yoder

2010-06-01T23:59:59.000Z

380

Reduction of Vinyl Chloride in Metallic Iron-Water Systems  

E-Print Network [OSTI]

Reduction of Vinyl Chloride in Metallic Iron-Water Systems B A O L I N D E N G * Department to groundwater and soil contamination. In particular, VC can be produced as an intermediate in the reductive). Remediation of groundwater contaminated with chlori- nated ethylenes, including vinyl chloride, has been chal

Deng, Baolin

Note: This page contains sample records for the topic "heavy metal contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Silicone metalization  

DOE Patents [OSTI]

A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

Maghribi, Mariam N. (Livermore, CA); Krulevitch, Peter (Pleasanton, CA); Hamilton, Julie (Tracy, CA)

2008-12-09T23:59:59.000Z

382

Silicone metalization  

DOE Patents [OSTI]

A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

Maghribi, Mariam N. (Livermore, CA); Krulevitch, Peter (Pleasanton, CA); Hamilton, Julie (Tracy, CA)

2006-12-05T23:59:59.000Z

383

Exploiting heavy oil reserves  

E-Print Network [OSTI]

North Sea investment potential Exploiting heavy oil reserves Beneath the waves in 3D Aberdeen.hamptonassociates.com pRINTED BY nB GroUP Paper sourced from sustainable forests CONTENTS 3/5 does the north Sea still industry partnership drives research into sensor systems 11 Beneath the waves in 3d 12/13 does

Levi, Ran

384

Coordination chemistry of two heavy metals: I, Ligand preferences in lead(II) complexation, toward the development of therapeutic agents for lead poisoning: II, Plutonium solubility and speciation relevant to the environment  

SciTech Connect (OSTI)

The coordination chemistry and solution behavior of the toxic ions lead(II) and plutonium(IV, V, VI) have been investigated. The ligand pK{sub a}s and ligand-lead(II) stability constants of one hydroxamic acid and four thiohydroaxamic acids were determined. Solution thermodynamic results indicate that thiohydroxamic acids are more acidic and slightly better lead chelators than hydroxamates, e.g., N-methylthioaceto-hydroxamic acid, pK{sub a} = 5.94, log{beta}{sub 120} = 10.92; acetohydroxamic acid, pK{sub a} = 9.34, log{beta}{sub l20} = 9.52. The syntheses of lead complexes of two bulky hydroxamate ligands are presented. The X-ray crystal structures show the lead hydroxamates are di-bridged dimers with irregular five-coordinate geometry about the metal atom and a stereochemically active lone pair of electrons. Molecular orbital calculations of a lead hydroxamate and a highly symmetric pseudo octahedral lead complex were performed. The thermodynamic stability of plutonium(IV) complexes of the siderophore, desferrioxamine B (DFO), and two octadentate derivatives of DFO were investigated using competition spectrophotometric titrations. The stability constant measured for the plutonium(IV) complex of DFO-methylterephthalamide is log{beta}{sub 110} = 41.7. The solubility limited speciation of {sup 242}Pu as a function of time in near neutral carbonate solution was measured. Individual solutions of plutonium in a single oxidation state were added to individual solutions at pH = 6.0, T = 30.0, 1.93 mM dissolved carbonate, and sampled over intervals up to 150 days. Plutonium solubility was measured, and speciation was investigated using laser photoacoustic spectroscopy and chemical methods.

Neu, M.P. [Lawrence Berkeley Lab., CA (United States)

1993-11-01T23:59:59.000Z

385

Project no.: INCO-WBC-1-509173 Specific Target Research Project  

E-Print Network [OSTI]

are affected by coal ash deposits. Due to heavy metal contamination of this ash, water resources like ash deposits contaminate water pollution to big areas in the region. Heavy metals entering the food for their potential to clean-up contaminated water bodies and effluents from deposits. Immobilisation of heavy metals

386

Emission Standards for Contaminants (Iowa)  

Broader source: Energy.gov [DOE]

These regulations list emissions standards for various contaminants, and contain special requirements for anaerobic lagoons. These regulations also describe alternative emissions limits, which may...

387

Method for mobilization of hazardous metal ions in soils  

DOE Patents [OSTI]

A microbial process for removing heavy metals such as bismuth, cadmium, lead, thorium, uranium and other transuranics from soils and sediments, utilizing indigenous, or isolates of indigenous, microorganisms and reducing agents, such as cysteine or sodium thioglycollate, or complexing agents such as the amino acid glycine, to effect the mobilization or release of the metals from the soil particles.

Dugan, Patrick R. (Idaho Falls, ID); Pfister, Robert M. (Powell, OH)

1995-01-01T23:59:59.000Z

388

PHENIX recent heavy flavor results  

E-Print Network [OSTI]

Cold nuclear matter (CNM) effects provide an important baseline for the interpretation of data in heavy ion collisions. Such effects include nuclear shadowing, Cronin effect, and initial patron energy loss, and it is interesting to study the dependence on impact parameter and kinematic region. Heavy quark production is a good measurement to probe the CNM effects particularly on gluons, since heavy quarks are mainly produced via gluon fusions at RHIC energy. The PHENIX experiment has experiment has ability to study the CNM effects by measuring heavy quark production in $d$$+$Au collisions at variety of kinematic ranges. Comparisons of heavy quark production at different rapidities allow us to study modification of gluon density function in the Au nucleus depending on momentum fraction. Furthermore, comparisons to the results from heavy ion collisions (Au$+$Au and Cu$+$Cu) measured by PHENIX provide insight into the role of CNM effects in such collisions. Recent PHENIX results on heavy quark production are discussed.

Sanghoon Lim for the PHENIX collaboration

2014-02-28T23:59:59.000Z

389

Constitutive Expression of a High-Affinity Sulfate Transporter in Indian Mustard Affects Metal Tolerance and Accumulation  

E-Print Network [OSTI]

of a gene that confers enhanced metal translocation or tolerance. TOXIC METALS and metalloids of heavy metals there is an increased demand for reduced S compounds like GSH and PCs, and genes involvedConstitutive Expression of a High-Affinity Sulfate Transporter in Indian Mustard Affects Metal

390

Utah Heavy Oil Program  

SciTech Connect (OSTI)

The Utah Heavy Oil Program (UHOP) was established in June 2006 to provide multidisciplinary research support to federal and state constituents for addressing the wide-ranging issues surrounding the creation of an industry for unconventional oil production in the United States. Additionally, UHOP was to serve as an on-going source of unbiased information to the nation surrounding technical, economic, legal and environmental aspects of developing heavy oil, oil sands, and oil shale resources. UHOP fulGilled its role by completing three tasks. First, in response to the Energy Policy Act of 2005 Section 369(p), UHOP published an update report to the 1987 technical and economic assessment of domestic heavy oil resources that was prepared by the Interstate Oil and Gas Compact Commission. The UHOP report, entitled 'A Technical, Economic, and Legal Assessment of North American Heavy Oil, Oil Sands, and Oil Shale Resources' was published in electronic and hard copy form in October 2007. Second, UHOP developed of a comprehensive, publicly accessible online repository of unconventional oil resources in North America based on the DSpace software platform. An interactive map was also developed as a source of geospatial information and as a means to interact with the repository from a geospatial setting. All documents uploaded to the repository are fully searchable by author, title, and keywords. Third, UHOP sponsored Give research projects related to unconventional fuels development. Two projects looked at issues associated with oil shale production, including oil shale pyrolysis kinetics, resource heterogeneity, and reservoir simulation. One project evaluated in situ production from Utah oil sands. Another project focused on water availability and produced water treatments. The last project considered commercial oil shale leasing from a policy, environmental, and economic perspective.

J. Bauman; S. Burian; M. Deo; E. Eddings; R. Gani; R. Goel; C.K. Huang; M. Hogue; R. Keiter; L. Li; J. Ruple; T. Ring; P. Rose; M. Skliar; P.J. Smith; J.P. Spinti; P. Tiwari; J. Wilkey; K. Uchitel

2009-10-20T23:59:59.000Z

391

Radioactive Contamination of Danish Territory  

E-Print Network [OSTI]

» & Risø-R-462 Radioactive Contamination of Danish Territory after Core-melt Accidents 1982 Risø National Laboratory, DK-4000 Roskilde, Denmark #12;RIS?-R-462 RADIOACTIVE CONTAMINATION. Heikel Vinther, L. Warming and A. Aarkrog Abstract. An assessment is made of the radioactive

392

Trace metals in tap water from Tehran, Iran  

SciTech Connect (OSTI)

A total of 272 tap water samples were collected from 68 homes throughout the city of Tehran. Analysis for cadmium, zinc, lead, copper, arsenic, iron and manganese showed some accumulation of these metals in household piping overnight. However, the concentration of all metals was in the parts per billion (ug/l) range and well below international standards. Heavy metals in Tehran's drinking water therefore, do not pose a significant acute health hazard. 19 references, 2 tables.

Shariatpanahi, M.; Anderson, A.C.

1986-01-01T23:59:59.000Z

393

CONTAMINATION BY METALLIC ELEMENTS RELEASED FROM JOINT PROSTHESES  

E-Print Network [OSTI]

atom. A high energy given by a spark under argon with a 15-30 kV voltage volatilises a few quantity spectrometry. The principle of this technique consists in exciting an atom. When this atom returns #12;4 to the fundamental state, it releases energy as luminous radiation where the wave number characterises the respected

Boyer, Edmond

394

Microbial controls on contaminant metal transport in porous media  

E-Print Network [OSTI]

and IOCS materials were determined through batch adsorption experiments, providing a mechanistic explanation of the adsorption process. Reactive transport models incorporating kinetics and surface complexation are developed to describe zinc movement through...

Kapetas, Leon

2011-11-24T23:59:59.000Z

395

Title of the article MODELLING OF METAL POLLUTANT LEACHING THROUGH A SMECTITE  

E-Print Network [OSTI]

, such as heavy metals, in soil constitutes a potential source of groundwater pollution. In the literature, some1 Title of the article MODELLING OF METAL POLLUTANT LEACHING THROUGH A SMECTITE Authors Chantal as the clay CEC. Keywords Leaching; metals; clay; copper; kinetic; modelling; CEC insu-00665250,version1-9May

Paris-Sud XI, Université de

396

Study of two sampling procedures for the valorization of metal hydroxide sludge as pollutant trapper  

E-Print Network [OSTI]

treatment, CrVI 1 Introduction Industrial aqueous pollution (heavy metals) accounts for 30 to 40% of all1 Study of two sampling procedures for the valorization of metal hydroxide sludge as pollutant@emse.fr Abstract: For the valorisation of metal hydroxide sludge as adsorbent of pollutant, it is necessary to make

Boyer, Edmond

397

Historical trends of metal pollution recorded in the sediments of the Culiacan River Estuary, Northwestern Mexico  

E-Print Network [OSTI]

Historical trends of metal pollution recorded in the sediments of the Culiacan River Estuary indicated a slight pollution by all the trace metals examined, although levels of enrichment for Ni and Pb) is strongly recommended. # 2002 Elsevier Science Ltd. All rights reserved. 1. Introduction Heavy metals

Long, Bernard

398

Defining the Proton Topology of the Zr6Based Metal-Organic Framework NU-1000  

E-Print Network [OSTI]

,16-19 heavy metal capture,20,21 sensing,12 ionic conductivity,22 toxic industrial chemical capture,23Defining the Proton Topology of the Zr6Based Metal-Organic Framework NU-1000 Nora Planas,, Joseph E of Science, King Abdulaziz University, Jeddah, Saudi Arabia *S Supporting Information ABSTRACT: Metal

399

Heavy Vehicle Propulsion Materials: Recent Progress and Future Plans  

SciTech Connect (OSTI)

The Heavy Vehicle Propulsion Materials Program provides enabling materials technology for the U.S. DOE Office of Heavy Vehicle Technologies (OHVT). The technical agenda for the program is based on an industry assessment and the technology roadmap for the OHVT. A five-year program plan was published in 2000. Major efforts in the program are materials for diesel engine fuel systems, exhaust aftertreatment, and air handling. Additional efforts include diesel engine valve-train materials, structural components, and thermal management. Advanced materials, including high-temperature metal alloys, intermetallics, cermets, ceramics, amorphous materials, metal- and ceramic-matrix composites, and coatings, are investigated for critical engine applications. Selected technical issues and planned and ongoing projects as well as brief summaries of several technical highlights are given.

D. Ray Johnson; Sidney Diamond

2001-05-14T23:59:59.000Z

400

Metal resistance sequences and transgenic plants  

SciTech Connect (OSTI)

The present invention provides nucleic acid sequences encoding a metal ion resistance protein, which are expressible in plant cells. The metal resistance protein provides for the enzymatic reduction of metal ions including but not limited to divalent Cu, divalent mercury, trivalent gold, divalent cadmium, lead ions and monovalent silver ions. Transgenic plants which express these coding sequences exhibit increased resistance to metal ions in the environment as compared with plants which have not been so genetically modified. Transgenic plants with improved resistance to organometals including alkylmercury compounds, among others, are provided by the further inclusion of plant-expressible organometal lyase coding sequences, as specifically exemplified by the plant-expressible merB coding sequence. Furthermore, these transgenic plants which have been genetically modified to express the metal resistance coding sequences of the present invention can participate in the bioremediation of metal contamination via the enzymatic reduction of metal ions. Transgenic plants resistant to organometals can further mediate remediation of organic metal compounds, for example, alkylmetal compounds including but not limited to methyl mercury, methyl lead compounds, methyl cadmium and methyl arsenic compounds, in the environment by causing the freeing of mercuric or other metal ions and the reduction of the ionic mercury or other metal ions to the less toxic elemental mercury or other metals.

Meagher, Richard Brian (Athens, GA); Summers, Anne O. (Athens, GA); Rugh, Clayton L. (Athens, GA)

1999-10-12T23:59:59.000Z

Note: This page contains sample records for the topic "heavy metal contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Fish scale deformation analysis using scanning electron microscope: New potential biomarker in aquatic environmental monitoring of aluminum and iron contamination  

SciTech Connect (OSTI)

Fish scale has the potential to be a rapid biomarker due to its structure and high possibility to come into contact with any pollutant in the aquatic environment. The scale structure consists of osteoblastic cells and other bone materials such as collagen where it is possible to form a molecular complex with heavy metals such as aluminum and iron. Hence, aluminum and iron in water could possibly destroy the scale material and marked as a scale deformation that quantitatively could be analyzed by comparing it to the normal scale structure. Water sampling and fish cage experiment were performed between June and July 2011 in Porong river which represented the water body that has high aluminum and iron contamination. The filtered water samples were preserved and extracted using the acid-mixture procedure prior to measurement of the aluminum and iron concentrations using Inductively Coupled Plasma Atomic Emission Spectroscopy (ICP-AES), while samples for total suspended solid (TSS) analysis were kept at 4 C in cool-boxes. The scales were cleaned with sterile water, then dehydrated in 30, 50, 70, and 90% ethanol and dried on filter papers. They were then mounted on an aluminum stub and coated with gold in a sputter coater prior to Scanning Electron Microscope (SEM) observation. According to the SEM analysis, it was found that there were several deformations on the scale samples taken from sites that have high concentrations of aluminum and iron i.e. the increasing number of pits, deformation and decreasing number of spherules and ridges while the control scale exhibited the normal features. However, the site with higher TSS and pH indicated lower aluminum effect. A moderate correlation was found between the number of pits with aluminum (r=0.43) and iron (r=0.41) concentrations. Fish scale deformation using SEM analysis can potentially be a rapid biomarker in aquatic monitoring of aluminum and iron contamination. However, the measurement must be accompanied by pH and TSS observations.

Hidayati, Dewi; Sulaiman, Norela; Othman, Shuhaimi; Ismail, B. S. [School of Environmental and Natural Resource Sciences, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia)

2013-11-27T23:59:59.000Z

402

ACTIVE CAPPING TECHNOLOGY - NEW APPROACHES FOR IN SITU REMEDIATION OF CONTAMINATED SEDIMENTS  

SciTech Connect (OSTI)

This study evaluated pilot-scale active caps composed of apatite, organoclay, biopolymers, and sand for the remediation of metal-contaminated sediments. The active caps were constructed in Steel Creek, at the Savannah River Site near Aiken, South Carolina. Monitoring was conducted for 12 months. Effectiveness of the caps was based on an evaluation of contaminant bioavailability, resistance to erosion, and impacts on benthic organisms. Active caps lowered metal bioavailability in the sediment during the one-year test period. Biopolymers reduced sediment suspension during cap construction, increased the pool of carbon, and lowered the release of metals. This field validation showed that active caps can effectively treat contaminants by changing their speciation, and that caps can be constructed to include more than one type of amendment to achieve multiple goals.

Knox, A.; Paller, M.; Roberts, J.

2012-02-13T23:59:59.000Z

403

Heavy Truck Engine Program  

SciTech Connect (OSTI)

The Heavy Duty Truck Engine Program at Cummins embodied three significant development phases. All phases of work strove to demonstrate a high level of diesel engine efficiency in the face of increasingly stringent emission requirements. Concurrently, aftertreatment system development and refinement was pursued in support of these efficiency demonstrations. The program's first phase focused on the demonstration in-vehicle of a high level of heavy duty diesel engine efficiency (45% Brake Thermal Efficiency) at a typical cruise condition while achieving composite emissions results which met the 2004 U.S. EPA legislated standards. With a combination of engine combustion calibration tuning and the development and application of Urea-based SCR and particulate aftertreatment, these demonstrations were successfully performed by Q4 of 2002. The second phase of the program directed efforts towards an in-vehicle demonstration of an engine system capable of meeting 2007 U.S. EPA legislated emissions requirements while achieving 45% Brake Thermal Efficiency at cruise conditions. Through further combustion optimization, the refinement of Cummins Cooled EGR architecture, the application of a high pressure common rail fuel system and the incorporation of optimized engine parasitics, Cummins Inc. successfully demonstrated these deliverables in Q2 of 2004. The program's final phase set a stretch goal of demonstrating 50% Brake Thermal Efficiency from a heavy duty diesel engine system capable of meeting 2010 U.S. EPA legislated emissions requirements. Cummins chose to pursue this goal through further combustion development and refinement of the Cooled EGR system architecture and also applied a Rankine cycle Waste Heat Recovery technique to convert otherwise wasted thermal energy to useful power. The engine and heat recovery system was demonstrated to achieve 50% Brake Thermal Efficiency while operating at a torque peak condition in second quarter, 2006. The 50% efficient engine system was capable of meeting 2010 emissions requirements through the application of NOx and particulate matter reduction techniques proven earlier in the program.

Nelson, Christopher

2009-01-08T23:59:59.000Z

404

INL '@work' heavy equipment mechanic  

ScienceCinema (OSTI)

INL's Cad Christensen is a heavy equipment mechanic. For more information about INL careers, visit http://www.facebook.com/idahonationallaboratory.

Christensen, Cad

2013-05-28T23:59:59.000Z

405

Creation and Testing of the ACES Heavy Heavy-Duty Diesel Engine...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Creation and Testing of the ACES Heavy Heavy-Duty Diesel Engine Test Schedule for Representative Measurement of Heavy-Duty Engine Emissions Creation and Testing of the ACES Heavy...

406

Metal oxide films on metal  

DOE Patents [OSTI]

A structure including a thin film of a conductive alkaline earth metal oxide selected from the group consisting of strontium ruthenium trioxide, calcium ruthenium trioxide, barium ruthenium trioxide, lanthanum-strontium cobalt oxide or mixed alkaline earth ruthenium trioxides thereof upon a thin film of a noble metal such as platinum is provided.

Wu, Xin D. (Los Alamos, NM); Tiwari, Prabhat (Los Alamos, NM)

1995-01-01T23:59:59.000Z

407

Water Qual. Res. J. Canada, 2004 Volume 39, No. 3, 183189 Copyright 2004, CAWQ  

E-Print Network [OSTI]

of strategies to remediate toxic heavy metal contamination in effluents and drinking waters. This work focusses heavy metals due to the increased activities of metal min- ing and metal processing industries has and the heavy metals recovered. The use of nat- ural biomass as a substrate for metal-ion chelation has been

Long, Bernard

408

Metals 2000  

SciTech Connect (OSTI)

This strategic planning exercise identified and characterized new and emerging advanced metallic technologies in the context of the drastic changes in global politics and decreasing fiscal resources. In consideration of a hierarchy of technology thrusts stated by various Department of Defense (DOD) spokesmen, and the need to find new and creative ways to acquire and organize programs within an evolving Wright Laboratory, five major candidate programs identified are: C-17 Flap, Transport Fuselage, Mach 5 Aircraft, 4.Fighter Structures, and 5. Missile Structures. These results were formed by extensive discussion with selected major contractors and other experts, and a survey of advanced metallic structure materials. Candidate structural applications with detailed metal structure descriptions bracket a wide variety of uses which warrant consideration for the suggested programs. An analysis on implementing smart skins and structures concepts is given from a metal structures perspective.

Allison, S.W.; Rogers, L.C.; Slaughter, G. [Oak Ridge National Lab., TN (United States); Boensch, F.D. [6025 Oak Hill Lane, Centerville, OH (United States); Claus, R.O.; de Vries, M. [Virginia Polytechnic Inst. and State Univ., Blacksburg, VA (United States)

1993-05-01T23:59:59.000Z

409

Dendritic metal nanostructures  

DOE Patents [OSTI]

Dendritic metal nanostructures made using a surfactant structure template, a metal salt, and electron donor species.

Shelnutt, John A. (Tijeras, NM); Song, Yujiang (Albuquerque, NM); Pereira, Eulalia F. (Vila Nova de Gaia, PT); Medforth, Craig J. (Winters, CA)

2010-08-31T23:59:59.000Z

410

Managing Inventories of Heavy Actinides  

SciTech Connect (OSTI)

The Department of Energy (DOE) has stored a limited inventory of heavy actinides contained in irradiated targets, some partially processed, at the Savannah River Site (SRS) and Oak Ridge National Laboratory (ORNL). The 'heavy actinides' of interest include plutonium, americium, and curium isotopes; specifically 242Pu and 244Pu, 243Am, and 244/246/248Cm. No alternate supplies of these heavy actinides and no other capabilities for producing them are currently available. Some of these heavy actinide materials are important for use as feedstock for producing heavy isotopes and elements needed for research and commercial application. The rare isotope 244Pu is valuable for research, environmental safeguards, and nuclear forensics. Because the production of these heavy actinides was made possible only by the enormous investment of time and money associated with defense production efforts, the remaining inventories of these rare nuclear materials are an important part of the legacy of the Nuclear Weapons Program. Significant unique heavy actinide inventories reside in irradiated Mark-18A and Mark-42 targets at SRS and ORNL, with no plans to separate and store the isotopes for future use. Although the costs of preserving these heavy actinide materials would be considerable, for all practical purposes they are irreplaceable. The effort required to reproduce these heavy actinides today would likely cost billions of dollars and encompass a series of irradiation and chemical separation cycles for at least 50 years; thus, reproduction is virtually impossible. DOE has a limited window of opportunity to recover and preserve these heavy actinides before they are disposed of as waste. A path forward is presented to recover and manage these irreplaceable National Asset materials for future use in research, nuclear forensics, and other potential applications.

Wham, Robert M [ORNL; Patton, Bradley D [ORNL

2011-01-01T23:59:59.000Z

411

High-Level Treatment of Stormwater Heavy Metals  

E-Print Network [OSTI]

Capacities for Different Media CEC (meq/100 g) Peat Moss 22 Compost 19 Activated Carbon 5.4 Zeolite 6-Section The MCTT is comprised of three main sections: - an inlet having a conventional catchbasin with litter traps

Clark, Shirley E.

412

Heavy Metals in Glass Beads Used in Pavement Markings  

E-Print Network [OSTI]

Pavement markings are vital for safely navigating roadways. The nighttime visibility of pavement markings is enhanced by addition of retroreflective glass beads, most of which are made from recycled glass. Concern has been raised over the presence...

Mangalgiri, Kiranmayi

2012-07-16T23:59:59.000Z

413

Near-threshold photodetachment of heavy alkali-metal anions  

SciTech Connect (OSTI)

We calculate near-threshold photodetachment cross sections for Rb{sup -}, Cs{sup -}, and Fr{sup -} using the Pauli equation method with a model potential describing the effective electron-atom interaction. Parameters of the model potential are fitted to reproduce ab initio scattering phase shifts obtained from Dirac R-matrix calculations. Special care is taken to formulate the boundary conditions near the atomic nucleus for solving the Pauli equation, based on the analytic solution of the Dirac equation for a Coulomb potential. We find a {sup 3}P{sub 1}{sup o} resonance contribution to the photodetachment cross section of Rb{sup -}, Cs{sup -}, and Fr{sup -} ions. Our calculated total photodetachment cross sections for Cs agree with experiments after tuning the resonance position by 2.4 meV. For Rb{sup -} and Fr{sup -} the resonance contribution is much smaller than for Cs. We therefore also provide angle-differential cross sections and asymmetry parameters which are much more sensitive to the resonant contribution than total cross sections.

Bahrim, C.; Thumm, U.; Khuskivadze, A.A.; Fabrikant, I.I. [Department of Physics, Kansas State University, Manhattan, Kansas 66506-2604 (United States); Department of Chemistry and Physics, Lamar University, Beaumont, Texas 77710-10046 (United States); Department of Physics, Kansas State University, Manhattan, Kansas 66506-2604 (United States); Department of Physics and Astronomy, University of Nebraska, Lincoln, Nebraska 68588-0111 (United States)

2002-11-01T23:59:59.000Z

414

Ultrasensitive Voltammetric Detection of Trace Heavy Metal Ions Using  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layeredof2014 EIAUltrafast TransformationsCarbon Nanotube

415

SEPARATION OF HEAVY METALS: REMOVAL FROM INDUSTRIAL WASTEWATERS  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 -the Mid-Infrared0 ResourceAwards SAGE Awards ,# ,Schools When Storms link

416

High-Performance, Superparamagnetic, Nanoparticle-Based Heavy Metal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun withconfinement plasmas in thein the AssemblyHigh-Order MembraneSiteSorbents

417

Functionalized Nanoporous Silica for Removal of Heavy Metals from  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFun with Big Sky Learning Fun with Big Sky Learning WHEN:AmplificationBiological

418

Removal of Heavy Metals from Aqueous Systems with Thiol Functionalized  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 -the Mid-Infrared at 278, 298,NIST31 ORV 15051Soil Vapor Extraction Enhanced

419

Method and device for electroextraction of heavy metals from technological  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces andMapping theEnergy StorageAdvancedMetamaterialsInnovation

420

United abominations: Density functional studies of heavy metal chemistry  

SciTech Connect (OSTI)

Carbonyl and nitrile addition to uranyl (UO{sup 2}{sup 2+}) are studied. The competition between nitrile and water ligands in the formation of uranyl complexes is investigated. The possibility of hypercoordinated uranyl with acetone ligands is examined. Uranyl is studied with diactone alcohol ligands as a means to explain the apparent hypercoordinated uranyl. A discussion of the formation of mesityl oxide ligands is also included. A joint theory/experimental study of reactions of zwitterionic boratoiridium(I) complexes with oxazoline-based scorpionate ligands is reported. A computational study was done of the catalytic hydroamination/cyclization of aminoalkenes with zirconium-based catalysts. Techniques are surveyed for programming for graphical processing units (GPUs) using Fortran.

Schoendorff, George

2012-04-02T23:59:59.000Z

Note: This page contains sample records for the topic "heavy metal contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Effects of heavy metals on microorganisms application to process design  

E-Print Network [OSTI]

of Domestic Sewage. " Water Pollution Control, 1970, pp. 100-110. 3. Banerji, Shankha K. , discussion of "Toxicity Measurements in Activated Sludge. " by L. Hartmann and G, Laubenberger, Journal of the Sanitar En ineerin Division, ASCE, Vol. 95, No. SA4... in Aerobic Biolo ical Treatment of Waste Water Princi le and Practice. Oligodynamic Press, Houston, Texas, 1971, p. 130. 10. Hartmann, Ludwig, and Laubenberger, G. , "Toxicity Measure- ments in Activated Sludge. " Journal of the Sanita En i- neerin...

Heck, Robert Paul

1972-01-01T23:59:59.000Z

422

Developments in Bioremediation of Soils and Sediments Polluted with Metals and Radionuclides: 2. Field Research on Bioremediation of Metals and Radionuclides  

E-Print Network [OSTI]

lead, zinc, and cadmium in smelter-contaminated soils usingof metal availability in smelter soil using earthworms andnear a former Zn and Pb smelter to test the ability of soil

Hazen, Terry C.

2010-01-01T23:59:59.000Z

423

E-Print Network 3.0 - aastat metal travel Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

H. Peverly , and Murray B. McBride1 1* 1 2 2 Summary: ;CAMEBRECO, ET AL. "MOVEMENT OF HEAVY METALS ..." 3 infiltrating water will travel through the entire soil... MOVEMENT OF...

424

E-Print Network 3.0 - autonomous liquid metal-cooled Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Collection: Engineering 12 HIGH EFFICIENCY GENERATION OF HYDROGEN FUELS Summary: , Heavy metal-cooled, Gas-cooled, Molten salt-cooled, Liquid- core and Gas-core l Assessed...

425

E-Print Network 3.0 - alkali metal nitrate Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

0021-91930104.00 0 DOI: 10.1128JB.183.19.54915495.2001 Summary: for this heavy metal for its anaerobic growth mode on nitrate (1). However, also in this organism,...

426

Experimental Study of In Situ Combustion with Tetralin and Metallic Catalysts  

E-Print Network [OSTI]

Experimental studies showed the feasibility of adding metallic catalysts and tetralin for the upgrade and increased recovery of heavy oil during the in situ combustion process. Further experimental studies also showed the applicability of in situ...

Palmer-Ikuku, Emuobonuvie

2010-01-16T23:59:59.000Z

427

Cooperating Agencies: Rutgers, The State University of New Jersey, U.S. Department of Agriculture, and County Boards of Chosen Freeholders. The U.S. Department of Agriculture (USDA) prohibits discrimination in all programs on the basis of race, color, nat  

E-Print Network [OSTI]

presence of nonnutrient toxic substances, such as heavy metals. The application of fertilizer products that have a high content of heavy metals results in the build up of heavy metals in soil. This increases fertilizer products may be at risk for heavy metal contamination. Generally, the most serious cause

Goodman, Robert M.

428

Clean Metal Casting  

SciTech Connect (OSTI)

The objective of this project is to develop a technology for clean metal processing that is capable of consistently providing a metal cleanliness level that is fit for a given application. The program has five tasks: Development of melt cleanliness assessment technology, development of melt contamination avoidance technology, development of high temperature phase separation technology, establishment of a correlation between the level of melt cleanliness and as cast mechanical properties, and transfer of technology to the industrial sector. Within the context of the first task, WPI has developed a standardized Reduced Pressure Test that has been endorsed by AFS as a recommended practice. In addition, within the context of task1, WPI has developed a melt cleanliness sensor based on the principles of electromagnetic separation. An industrial partner is commercializing the sensor. Within the context of the second task, WPI has developed environmentally friendly fluxes that do not contain fluorine. Within the context of the third task, WPI modeled the process of rotary degassing and verified the model predictions with experimental data. This model may be used to optimize the performance of industrial rotary degassers. Within the context of the fourth task, WPI has correlated the level of melt cleanliness at various foundries, including a sand casting foundry, a permanent mold casting foundry, and a die casting foundry, to the casting process and the resultant mechanical properties. This is useful in tailoring the melt cleansing operations at foundries to the particular casting process and the desired properties of cast components.

Makhlouf M. Makhlouf; Diran Apelian

2002-02-05T23:59:59.000Z

429

Decontamination of metals using chemical etching  

DOE Patents [OSTI]

The invention relates to chemical etching process for reclaiming contaminated equipment wherein a reduction-oxidation system is included in a solution of nitric acid to contact the metal to be decontaminated and effect reduction of the reduction-oxidation system, and includes disposing a pair of electrodes in the reduced solution to permit passage of an electrical current between said electrodes and effect oxidation of the reduction-oxidation system to thereby regenerate the solution and provide decontaminated equipment that is essentially radioactive contamination-free.

Lerch, Ronald E. (Kennewick, WA); Partridge, Jerry A. (Richland, WA)

1980-01-01T23:59:59.000Z

430

Heavy vehicle propulsion system materials program semiannual progress report for April 1999 through September 1999  

SciTech Connect (OSTI)

The purpose of the Heavy Vehicle Propulsion System Materials Program is the development of materials: ceramics, intermetallics, metal alloys, and metal and ceramic coatings, to support the dieselization of class 1-3 trucks to realize a 35% fuel-economy improvement over current gasoline-fueled trucks and to support commercialization of fuel-flexible LE-55 low-emissions, high-efficiency diesel engines for class 7-8 trucks.

Johnson, D.R.

2000-01-01T23:59:59.000Z

431

Single-step multiplex detection of toxic metal ions by Au nanowires-on-chip sensor using reporter elimination  

E-Print Network [OSTI]

Single-step multiplex detection of toxic metal ions by Au nanowires-on-chip sensor using reporter sensitively detect multiple toxic metal ions. Most importantly, the reporter elimination method simplified by using this sensor. 1. Introduction Heavy metal ions such as mercury (Hg2+ ), silver (Ag+ ), and lead (Pb

Kim, Bongsoo

432

Geochemistry, toxicity, and sorption properties of contaminated sediments and pore waters  

E-Print Network [OSTI]

waters have neutralized on mixing with neutral-pH lake water, producing fine-grained, metal- richGeochemistry, toxicity, and sorption properties of contaminated sediments and pore waters from two Acid mine waters from the Iron Mountain Superfund Site, Shasta County, California, flow through Spring

433

Remediation of Uranium-contaminated Groundwater by Sorption onto Hydroxyapatite Derived  

E-Print Network [OSTI]

Remediation of Uranium-contaminated Groundwater by Sorption onto Hydroxyapatite Derived from of CFHA to remove uranium (U(VI)) from aqueous phase was investigated using both batch and column experi metals and radionuclides forming minerals that are stable across a wide range of geological conditions

Clement, Prabhakar

434

LCLS Heavy Met Outgassing Tests  

SciTech Connect (OSTI)

A Heavy Met that is 95% tungsten, 3% nickel and 2% iron and sintered to 100% density and is Ultra High Vacuum (UHV) compatible is proposed for use as the X-ray slit in the Front End Enclosure and the Fixed Mask for the Linac Coherent Light Source (LCLS). The Heavy Met was tested in the LLNL Vacuum Sciences and Engineering Lab (VSEL) to determine its outgassing rate and its overall compatibility with the vacuum requirements for LCLS.

Kishiyama, K. I.

2010-12-01T23:59:59.000Z

435

Trending: Metal Oxo Bonds  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing...

436

Composite metal membrane  

DOE Patents [OSTI]

A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

Peachey, Nathaniel M. (Espanola, NM); Dye, Robert C. (Los Alamos, NM); Snow, Ronny C. (Los Alamos, NM); Birdsell, Stephan A. (Los Alamos, NM)

1998-01-01T23:59:59.000Z

437

Composite metal membrane  

DOE Patents [OSTI]

A composite metal membrane including a first metal layer of Group IVB met or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof is provided together with a process for the recovery of hydrogen from a gaseous mixture including contacting a hydrogen-containing gaseous mixture with a first side of a nonporous composite metal membrane including a first metal of Group IVB metals or Group VB metals, the first metal layer sandwiched between two layers of an oriented metal of palladium, platinum or alloys thereof, and, separating hydrogen from a second side of the nonporous composite metal membrane.

Peachey, N.M.; Dye, R.C.; Snow, R.C.; Birdsell, S.A.

1998-04-14T23:59:59.000Z

438

APPLIED AND ENVIRONMENTAL MICROBIOLOGY, 0099-2240/00/$04.00 0  

E-Print Network [OSTI]

Heavy metal resistance by bacteria is a topic of much importance to the bioremediation of contaminated of systems contaminated by high levels of cadmium. Cadmium, a highly toxic metal and a group B1 human car the heavy metal resistance and growth of these bacteria in contaminated systems. Recent studies by Poulson

Frenkel, Anatoly

439

Method for refining contaminated iridium  

DOE Patents [OSTI]

Contaminated iridium is refined by alloying it with an alloying agent selected from the group consisting of manganese and an alloy of manganese and copper, and then dissolving the alloying agent from the formed alloy to provide a purified iridium powder.

Heshmatpour, B.; Heestand, R.L.

1982-08-31T23:59:59.000Z

440

Method for refining contaminated iridium  

DOE Patents [OSTI]

Contaminated iridium is refined by alloying it with an alloying agent selected from the group consisting of manganese and an alloy of manganese and copper, and then dissolving the alloying agent from the formed alloy to provide a purified iridium powder.

Heshmatpour, Bahman (Waltham, MA); Heestand, Richard L. (Oak Ridge, TN)

1983-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "heavy metal contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Systematics of cross sections for target K-vacancy production in heavy ion collisions  

E-Print Network [OSTI]

Cross sections for K-shell ionization by heavy ions have been determined from the measurements of target K x-ray yields. The measurements were performed with Ar, Kr, and Xe ions at energies from 2.5 to 25 MeV/amu and self-supported metallic foil...

Peng, Yong

2007-04-25T23:59:59.000Z

442

Journal of Applied Phycology 16: 275284, 2004. C 2004 Kluwer Academic Publishers. Printed in the Netherlands.  

E-Print Network [OSTI]

-through column systems that rely on a passive ion-exchange mechanism for the remediation of toxic heavy metals Contamination of aquatic environments by toxic heavy metals originating from metal mining and metal processing- pecially if the sorbed material can be re-used and the heavy metals recovered. The use of natural biomass

Long, Bernard

443

Heavy Water Components Test Reactor Decommissioning - Major Component Removal  

SciTech Connect (OSTI)

The Heavy Water Components Test Reactor (HWCTR) facility (Figure 1) was built in 1961, operated from 1962 to 1964, and is located in the northwest quadrant of the Savannah River Site (SRS) approximately three miles from the site boundary. The HWCTR facility is on high, well-drained ground, about 30 meters above the water table. The HWCTR was a pressurized heavy water test reactor used to develop candidate fuel designs for heavy water power reactors. It was not a defense-related facility like the materials production reactors at SRS. The reactor was moderated with heavy water and was rated at 50 megawatts thermal power. In December of 1964, operations were terminated and the facility was placed in a standby condition as a result of the decision by the U.S. Atomic Energy Commission to redirect research and development work on heavy water power reactors to reactors cooled with organic materials. For about one year, site personnel maintained the facility in a standby status, and then retired the reactor in place. In 1965, fuel assemblies were removed, systems that contained heavy water were drained, fluid piping systems were drained, deenergized and disconnected and the spent fuel basin was drained and dried. The doors of the reactor facility were shut and it wasn't until 10 years later that decommissioning plans were considered and ultimately postponed due to budget constraints. In the early 1990s, DOE began planning to decommission HWCTR again. Yet, in the face of new budget constraints, DOE deferred dismantlement and placed HWCTR in an extended surveillance and maintenance mode. The doors of the reactor facility were welded shut to protect workers and discourage intruders. The $1.6 billion allocation from the American Recovery and Reinvestment Act to SRS for site clean up at SRS has opened the doors to the HWCTR again - this time for final decommissioning. During the lifetime of HWCTR, 36 different fuel assemblies were tested in the facility. Ten of these experienced cladding failures as operational capabilities of the different designs were being established. In addition, numerous spills of heavy water occurred within the facility. Currently, radiation and radioactive contamination levels are low within HWCTR with most of the radioactivity contained within the reactor vessel. There are no known insults to the environment, however with the increasing deterioration of the facility, the possibility exists that contamination could spread outside the facility if it is not decommissioned. An interior panoramic view of the ground floor elevation taken in August 2009 is shown in Figure 2. The foreground shows the transfer coffin followed by the reactor vessel and control rod drive platform in the center. Behind the reactor vessel is the fuel pool. Above the ground level are the polar crane and the emergency deluge tank at the top of the dome. Note the considerable rust and degradation of the components and the interior of the containment building. Alternative studies have concluded that the most environmentally safe, cost effective option for final decommissioning is to remove the reactor vessel, steam generators, and all equipment above grade including the dome. Characterization studies along with transport models have concluded that the remaining below grade equipment that is left in place including the transfer coffin will not contribute any significant contamination to the environment in the future. The below grade space will be grouted in place. A concrete cover will be placed over the remaining footprint and the groundwater will be monitored for an indefinite period to ensure compliance with environmental regulations. The schedule for completion of decommissioning is late FY2011. This paper describes the concepts planned in order to remove the major components including the dome, the reactor vessel (RV), the two steam generators (SG), and relocating the transfer coffin (TC).

Austin, W.; Brinkley, D.

2010-05-05T23:59:59.000Z

444

Natural attenuation of metals and radionuclides: Report from a workshop held by Sandia National Laboratories  

SciTech Connect (OSTI)

Natural attenuation is increasingly applied to remediate contaminated soils and ground waters. Roughly 25% of Superfund groundwater remedies in 1995 involved some type of monitored natural attenuation, compared to almost none 5 years ago. Remediation by natural attenuation (RNA) requires clear evidence that contaminant levels are decreasing sufficiently over time, a defensible explanation of the attenuation mechanism, long-term monitoring, and a contingency plan at the very least. Although the primary focus of implementation has to date been the biodegradation of organic contaminants, there is a wealth of scientific evidence that natural processes reduce the bioavailability of contaminant metals and radionuclides. Natural attenuation of metals and radionuclides is likely to revolve around sorption, solubility, biologic uptake and dilution controls over contaminant availability. Some of these processes can be applied to actively remediate sites. Others, such as phytoremediation, are likely to be ineffective. RNA of metals and radionuclides is likely to require specialized site characterization to construct contaminant and site-specific conceptual models of contaminant behavior. Ideally, conceptual models should be refined such that contaminant attenuation can be confidently predicted into the future. The technical approach to RNA of metals and radionuclides is explored here.

Brady, P.V.; Borns, D.J. [Sandia National Labs., Albuquerque, NM (United States). Geochemistry Dept.

1997-11-01T23:59:59.000Z

445

Method for mobilization of hazardous metal ions in soils  

DOE Patents [OSTI]

A microbial process is revealed for removing heavy metals such as bismuth, cadmium, lead, thorium, uranium and other transuranics from soils and sediments. The method utilizes indigenous, or isolates of indigenous, microorganisms and reducing agents, such as cysteine or sodium thioglycollate, or complexing agents such as the amino acid glycine, to effect the mobilization or release of the metals from the soil particles. 5 figs.

Dugan, P.R.; Pfister, R.M.

1995-06-27T23:59:59.000Z

446

Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

ce001musculus2011o.pdf More Documents & Publications Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Heavy-Duty Low-Temperature and Diesel...

447

Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

ce001musculus2010o.pdf More Documents & Publications Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Heavy-Duty Low-Temperature and Diesel...

448

Chapter 2: Sources and Deposition of Trace Metals 2.1 Main Sources of Atmospheric Pollution...............................................7  

E-Print Network [OSTI]

5 Chapter 2: Sources and Deposition of Trace Metals 2.1 Main Sources of Atmospheric Pollution distances causing regional or global pollution. Fig. 2.1: Sources of trace metals in the environment. Contamination of the atmosphere by pollutant trace metals affects the environment directly through its impact

Short, Daniel

449

Metals purification by improved vacuum arc remelting  

DOE Patents [OSTI]

The invention relates to improved apparatuses and methods for remelting metal alloys in furnaces, particularly consumable electrode vacuum arc furnaces. Excited reactive gas is injected into a stationary furnace arc zone, thus accelerating the reduction reactions which purify the metal being melted. Additionally, a cooled condensation surface is disposed within the furnace to reduce the partial pressure of water in the furnace, which also fosters the reduction reactions which result in a purer produced ingot. Methods and means are provided for maintaining the stationary arc zone, thereby reducing the opportunity for contaminants evaporated from the arc zone to be reintroduced into the produced ingot.

Zanner, Frank J. (Sandia Park, NM); Williamson, Rodney L. (Albuquerque, NM); Smith, Mark F. (Albuquerque, NM)

1994-12-13T23:59:59.000Z

450

Emerging contaminants and microorganisms into the environment  

E-Print Network [OSTI]

Workshop Emerging contaminants and microorganisms into the environment: contamination pathways Environmental Engineering Division Surname _____________________Name____________________ Job Environmental Engineering Division (SEED) Department of Civil Engineering University of Salerno Via Ponte don

Costagliola, Gennaro

451

Land treatment of contaminated sludge with wastewater irrigation  

SciTech Connect (OSTI)

A large-scale field experiment was conducted to test the feasibility of land application of sludge from industrial and domestic wastewater treatment to determine the fate and environmental impact of the contaminants. The sludge contained 13 organic priority pollutants, 16 additional environmentally significant organic compounds, and high concentrations of several metals (zinc, copper, lead, nickel, and cadmium). Each compound was monitored as the irrigation water percolated through the soil and the groundwater over time. Most of the organic compounds diminished to non-detectable levels by the end of the study, and the metals proved harmless to the environment. The effectiveness of land application of sludge with wastewater irrigation was clearly demonstrated. 1 figure, 11 tables.

Demirjian, Y.A.; Westman, T.R.; Joshi, A.M.; Rop, D.J.; Buhl, R.V.; Clark, W.R.

1984-04-01T23:59:59.000Z

452

Webinar: NREL's Fuel Cell Contaminant Database  

Broader source: Energy.gov [DOE]

Video recording and text version of the webinar titled "NREL's Fuel Cell Contaminant Database," originally presented on May 27, 2014.

453

Metal Hydrides  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department of EnergyDevelopmentTechnologies |Charles Page -toMetabolic PathwaysMetal

454

Chemistry of heavy ion reactions  

SciTech Connect (OSTI)

The use of heavy ions to induce nuclear reactions was reported as early as 1950. Since that time it has been one of the most active areas of nuclear research. Intense beams of ions as heavy as uranium with energies high enough to overcome the Coulomb barriers of even the heaviest elements are available. The wide variety of possible reactions gives rise to a multitude of products which have been studied by many ingenious chemical and physical techniques. Chemical techniques have been of special value for the separation and unequivocal identification of low yield species from the plethora of other nuclides present. Heavy ion reactions have been essential for the production of the trans-Md elements and a host of new isotopes. The systematics of compound nucleus reactions, transfer reactions, and deeply inelastic reactions have been elucidated using chemical techniques. A review of the variety of chemical procedures and techniques which have been developed for the study of heavy ion reactions and their products is given. Determination of the chemical properties of the trans-Md elements, which are very short-lived and can only be produced an ''atom-at-a-time'' via heavy ion reactions, is discussed. 53 refs., 19 figs.

Hoffman, D.C.

1988-10-01T23:59:59.000Z

455

In situ bioremediation of petrol contaminated groundwater  

E-Print Network [OSTI]

) Bacterial Diversity and Aerobic Biodegradation Potential in a BTEX-Contaminated Aquifer Water Air Soil21/11/08 1 In situ bioremediation of petrol contaminated groundwater Guido Miguel Delgadillo EVS and facts · Likelihood of contamination · Benefits of in situ bioremediation So... Ask not what groundwater

Blouin-Demers, Gabriel

456

Review of soil contamination guidance  

SciTech Connect (OSTI)

A review of existing and proposed radioactive soil contamination standards and guidance was conducted for United Nuclear Corporation (UNC), Office of Surplus Facilities Management. Information was obtained from both government agencies and other sources during a literature survey. The more applicable standards were reviewed, evaluated, and summarized. Information pertaining to soil contamination for both facility operation and facility decommissioning was obtained from a variety of sources. These sources included: the Code of Federal Regulations, regulatory guides, the Federal Register, topical reports written by various government agencies, topical reports written by national laboratories, and publications from the American National Standards Institute (ANSI). It was difficult to directly compare the standards and guidance obtained from these sources since each was intended for a specific situation and different units or bases were used. However, most of the information reviewed was consistent with the philosophy of maintaining exposures at levels as low as reasonably achievable (ALARA).

Mueller, M.A.; Kennedy, W.E. Jr.; Soldat, J.K.

1981-08-01T23:59:59.000Z

457

Spatial, temporal and geographic considerations of the problem of rock varnish diagenesis  

E-Print Network [OSTI]

century time of heavy metal pollution. Evidence of nanometer-scale disequilibrium in three samples led-century contamination by lead and other heavy metals has led to claims of accumulation rates in the last century far

Dorn, Ron

458

PLATINUM-GROUP METALS (Platinum, palladium, rhodium, ruthenium, iridium, osmium)  

E-Print Network [OSTI]

for air-pollution abatement in both light- and heavy-duty vehicles. PGMs are also used in the chemical in kilograms unless otherwise noted) Domestic Production and Use: The Stillwater and East Boulder Mines in south-central Montana were the only primary platinum-group metals (PGMs) mines in the United States

459

PLATINUM-GROUP METALS (Platinum, palladium, rhodium, ruthenium, iridium, osmium)  

E-Print Network [OSTI]

for air-pollution abatement in both light- and heavy-duty vehicles. PGMs are also used in the chemical in kilograms unless otherwise noted) Domestic Production and Use: The Stillwater and East Boulder Mines in south-central Montana are the only primary platinum-group metals (PGMs) mines in the United States

460

Carbo-metallic oil-conversion process and catalysts  

SciTech Connect (OSTI)

This patent describes a continuous process for cracking of a residual hydrocarbon feedstock into lower molecular weight hydrocarbon transportation fuels. The cracking being carried out in the presence of a catalyst having catalyst parameters comprising porosity, metals content, rare earth content, and zeolite content. The residual hydrocarbon feedstock comprising metal contaminants, fractions boiling above 1025{degrees}F. comprising asphaltenes, polynuclear aromatics, naphthenes and prophyrins.

Hettinger, W.P.; Beck, W.

1989-10-31T23:59:59.000Z

Note: This page contains sample records for the topic "heavy metal contamination" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Advanced technologies for decomtamination and conversion of scrap metal  

SciTech Connect (OSTI)

The Department of Energy (DOE) faces the task of decommissioning much of the vast US weapons complex. One challenge of this effort includes the disposition of large amounts of radioactively contaminated scrap metal (RSM) including but not limited to steel, nickel, copper, and aluminum. The decontamination and recycling of RSM has become a key element in the DOE's strategy for cleanup of contaminated sites and facilities. Recycling helps to offset the cost of decommissioning and saves valuable space in the waste disposal facilities. It also reduces the amount of environmental effects associated with mining new metals. Work on this project is geared toward finding decontamination and/or recycling alternatives for the RSM contained in the decommissioned gaseous diffusion plants including approximately 40,000 tons of nickel. The nickel is contaminated with Technetium-99, and is difficult to remove using traditional decontamination technologies. The project, titled ``Advanced Technologies for Decontamination and Conversion of Scrap Metal'' was proposed as a four phase project. Phase 1 and 2 are complete and Phase 3 will complete May 31, 1999. Stainless steel made from contaminated nickel barrier was successfully produced in Phase 1. An economic evaluation was performed and a market study of potential products from the recycled metal was completed. Inducto-slag refining, after extensive testing, was eliminated as an alternative to remove technetium contamination from nickel. Phase 2 included successful lab scale and pilot scale demonstrations of electrorefining to separate technetium from nickel. This effort included a survey of available technologies to detect technetium in volumetrically contaminated metals. A new process to make sanitary drums from RSM was developed and implemented. Phase 3 included a full scale demonstration of electrorefining, an evaluation of electro-refining alternatives including direct dissolution, melting of nickel into anodes, a laser cutting demonstration, an investigation of commercial markets for RSM, and refinement of methods to quantify isotopic elements.

Valerie MacNair; Steve Sarten; Thomas Muth; Brajendra Mishra

1999-05-27T23:59:59.000Z

462

Pionic Fusion of Heavy Ions  

E-Print Network [OSTI]

We report the first experimental observation of the pionic fusion of two heavy ions. The 12C(12C,24Mg)pi0 and 12C(12C,24Na)pi+ cross sections have been measured to be 208 +/- 38 and 182 +/- 84 picobarns, respectively, at E_cm = 137 MeV. This cross section for heavy-ion pion production, at an energy just 6 MeV above the absolute energy-conservation limit, constrains possible production mechanisms to incorporate the kinetic energy of the entire projectile-target system as well as the binding energy gained in fusion.

D. Horn; G. C. Ball; D. R. Bowman; W. G. Davies; D. Fox; A. Galindo-Uribarri; A. C. Hayes; G. Savard; L. Beaulieu; Y. Larochelle; C. St-Pierre

1996-08-13T23:59:59.000Z

463

Central collisions of heavy ions  

SciTech Connect (OSTI)

This report describes the activities of the Heavy Ion Physics Group at the University of California, Riverside from October 1, 1990 to September 30, 1991. During this period, our program focuses on particle production at AGS energies, and correlation studies at the Bevalac in nucleus central collisions. We participated in the preparation of letters of intent for two RHIC experiments -- the OASIS proposal and the Di-Muon proposal -- and worked on two RHIC R D efforts -- a silicon strip detector project and a muon-identifier project. A small fraction of time was also devoted to physics programs outside the realm of heavy ion reactions by several individuals.

Fung, Sun-yiu.

1991-10-01T23:59:59.000Z

464

Heavy Ions - 88-Inch Cyclotron  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary)morphinanInformation Desert Southwest Region service area. TheEPSCIResearchGulfCenterHeavy Ions Heavy ions

465

Electrochemical Processes for In-Situ Treatment of Contaminated Soils - Final Report - 09/15/1996 - 01/31/2001  

SciTech Connect (OSTI)

This project will study electrochemical processes for the in situ treatment of soils contaminated by mixed wastes, i.e., organic and inorganic. Soil samples collected form selected DOE waste sites will be characterized for specific organic and metal contaminants and hydraulic permeability. The soil samples are then subject to desorption experiments under various physical-chemical conditions such as pH and the presence of surfactants. Batch electro-osmosis experiments will be conducted to study the transport of contaminants in the soil-water systems. Organic contaminants that are released from the soil substrate will be treated by an advanced oxidation process, i.e., electron-Fantan. Finally, laboratory reactor integrating the elector-osmosis and elector-Fantan processes will be used to study the treatment of contaminated soil in situ.

Huang, Chin-Pao

2001-05-31T23:59:59.000Z

466

Contaminant distributions at typical U.S. uranium milling facilities and their effect on remedial action decisions  

SciTech Connect (OSTI)

Past operations at uranium processing sites throughout the US have resulted in local contamination of soils and ground water by radionuclides, toxic metals, or both. Understanding the origin of contamination and how the constituents are distributed is a basic element for planning remedial action decisions. This report describes the radiological and nonradiological species found in ground water at a typical US uranium milling facility. The report will provide the audience with an understanding of the vast spectrum of contaminants that must be controlled in planning solutions to the long-term management of these waste materials.

Hamp, S. [USDOE Albuquerque Operations Office, NM (United States). Uranium Mill Tailings Remedial Action Project Office; Jackson, T.J. [Geraghty and Miller, Inc., Albuquerque, NM (United States); Dotson, P.W. [Roy F. Weston, Inc., Albuquerque, NM (United States)

1995-03-01T23:59:59.000Z

467

MERCURY CONTAMINATED MATERIAL DECONTAMINATION METHODS: INVESTIGATION AND ASSESSMENT  

SciTech Connect (OSTI)

Over the years mercury has been recognized as having serious impacts on human health and the environment. This recognition has led to numerous studies that deal with the properties of various mercury forms, the development of methods to quantify and speciate the forms, fate and transport, toxicology studies, and the development of site remediation and decontamination technologies. This report reviews several critical areas that will be used in developing technologies for cleaning mercury from mercury-contaminated surfaces of metals and porous materials found in many DOE facilities. The technologies used for decontamination of water and mixed wastes (solid) are specifically discussed. Many technologies that have recently appeared in the literature are included in the report. Current surface decontamination processes have been reviewed, and the limitations of these technologies for mercury decontamination are discussed. Based on the currently available technologies and the processes published recently in the literature, several processes, including strippable coatings, chemical cleaning with iodine/iodide lixiviant, chemisorbing surface wipes with forager sponge and grafted cotton, and surface/pore fixation through amalgamation or stabilization, have been identified as potential techniques for decontamination of mercury-contaminated metal and porous surfaces. Their potential merits and applicability are discussed. Finally, two processes, strippable coatings and chemical cleaning with iodine/iodide lixiviant, were experimentally investigated in Phase II of this project.

M.A. Ebadian, Ph.D.

2001-01-01T23:59:59.000Z

468

Mechanochemical processing for metals and metal alloys  

DOE Patents [OSTI]

A set of processes for preparing metal powders, including metal alloy powders, by ambient temperature reduction of a reducible metal compound by a reactive metal or metal hydride through mechanochemical processing. The reduction process includes milling reactants to induce and complete the reduction reaction. The preferred reducing agents include magnesium and calcium hydride powders. A process of pre-milling magnesium as a reducing agent to increase the activity of the magnesium has been established as one part of the invention.

Froes, Francis H. (Moscow, ID); Eranezhuth, Baburaj G. (Moscow, ID); Prisbrey, Keith (Moscow, ID)