National Library of Energy BETA

Sample records for heavy element chemistry

  1. 2.10 Heavy Element Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6 6/1/2011 2.10 Heavy Element Chemistry For more than 50 years, the Office of Science and predecessor agencies have supported the discovery and study of the actinide elements, in particular the transuranium elements-atoms that are heavier than uranium. Glenn Seaborg and Ed McMillan of the Lawrence Berkeley National Laboratory, 1951 Nobel Laureates in Chemistry for the discovery of plutonium and other actinide elements, began this quest. Today, the Heavy Element Chemistry program continues the

  2. Heavy Element Chemistry | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heavy Element Chemistry Chemical Sciences, Geosciences, & Biosciences (CSGB) Division CSGB Home About Research Areas Energy Frontier Research Centers (EFRCs) DOE Energy Innovation Hubs Reports and Activities Science Highlights Principal Investigators' Meetings BES Home Research Areas Heavy Element Chemistry Print Text Size: A A A FeedbackShare Page This activity supports basic research in the chemistry of the heavy elements, focused on the actinides, but also includes the transactinide

  3. Super-Heavy Element Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Targets for Super-Heavy Element Research Presented at International Workshop on Super-Heavy Element Research SHE-15 J. B. Roberto Oak Ridge National Laboratory Oak Ridge,...

  4. Heavy Element Synthesis Reactions W. Loveland Oregon State University

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reactions W. Loveland Oregon State University The role of ATLAS in helping us understand heavy element synthesis reactions and heavy element properties * Hot (E*=35-60 MeV) and Cold (E*=15 MeV) fusion reactions * Multi-nucleon transfer reactions * Fission * Atomic physics and chemistry of the heaviest elements * Structure of the heaviest nuclei The challenge of studying the heaviest elements at ATLAS * ATLAS beam time is oversubscribed * Low cross section studies - High luminosity - ATLAS has

  5. The Search for Heavy Elements

    SciTech Connect (OSTI)

    2008-04-17

    The 1994 documentary "The Search for Heavy Elements" chronicles the expansion of the periodic table through the creation at Berkeley Lab of elements heavier than uranium. The documentary features a mix of rarely-seen archival footage, historical photos, and interviews with scientists who made history, such as Glenn Seaborg and Albert Ghiorso.

  6. The Search for Heavy Elements

    ScienceCinema (OSTI)

    None

    2010-01-08

    The 1994 documentary "The Search for Heavy Elements" chronicles the expansion of the periodic table through the creation at Berkeley Lab of elements heavier than uranium. The documentary features a mix of rarely-seen archival footage, historical photos, and interviews with scientists who made history, such as Glenn Seaborg and Albert Ghiorso.

  7. The physics and chemistry of heavy Fermions

    SciTech Connect (OSTI)

    Fisk, Z.; Sarrao, J.L. |; Smith, J.L.; Thompson, J.D.

    1994-12-31

    The heavy Fermions are a subset of the f-element intermetallics straddling the magnetic/non-magnetic boundary. Their low temperature properties are characterized by an electronic energy scale of order 1--10 K. Among the low temperature ground states observed in heavy Fermion compounds are exotic superconductors and magnets, as well as unusual semiconductors. We review here the current experimental and theoretical understanding of these systems.

  8. Yb-based heavy fermion compounds and field tuned quantum chemistry...

    Office of Scientific and Technical Information (OSTI)

    and field tuned quantum chemistry Citation Details In-Document Search Title: Yb-based heavy fermion compounds and field tuned quantum chemistry You are accessing a ...

  9. Observation of heavy elements produced during explosive cold fusion

    SciTech Connect (OSTI)

    Matsumoto, T.; Kurokawa, K. )

    1991-11-01

    This paper reports on many-body fusion reactions that may take place during cold fusion. Heavy elements are observed that might have been produced by such reactions during electrolysis of heavy water. Elements such as sodium, magnesium, aluminum, and zinc are observed inside grain-shaped defects in a palladium rod used in a cold fusion experiment.

  10. Actinide targets for the synthesis of super-heavy elements

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Roberto, J.; Alexander, Charles W.; Boll, Rose Ann; Ezold, Julie G.; Felker, Leslie Kevin; Rykaczewski, Krzysztof Piotr; Hogle, Susan L.

    2015-06-18

    Since 2000, six new super-heavy elements with atomic numbers 113 through 118 have been synthesized in hot fusion reactions of 48Ca beams on actinide targets. These target materials, including 242Pu, 244Pu, 243Am, 245Cm, 248Cm, 249Cf, and 249Bk, are available in very limited quantities and require specialized production and processing facilities resident in only a few research centers worldwide. This report describes the production and chemical processing of heavy actinide materials for super-heavy element research, current availabilities of these materials, and related target fabrication techniques. The impact of actinide materials in super-heavy element discovery is reviewed, and strategies for enhancing themore » production of rare actinides including 249Bk, 251Cf, and 254Es are described.« less

  11. Formation of super-heavy elements in astrophysical nucleosynthesis

    SciTech Connect (OSTI)

    Zagrebaev, V. I.; Karpov, A. V.; Mishustin, I. N.; Greiner, Walter

    2012-10-20

    The unexplored area of heavy neutron-rich nuclides is extremely important for the understanding of the r process of astrophysical nucleogenesis. For elements with Z>100 only neutron deficient isotopes (located to the left of the stability line) have been synthesized so far. The 'north-east' area of the nuclear map can be reached neither in fusion reactions nor in fragmentation processes. Low energy multi-nucleon transfer reactions are quite promising for the production and study of neutron-rich heavy nuclei including those located at the superheavy (SH) island of stability [1]. The neutron capture process is considered here as an alternative method for the production of SH nuclei. Requirements for the pulsed reactors of the next generation that could be used for the synthesis of long-living neutron rich SH nuclei are formulated. Formation of SH nuclei in supernova explosions is also discussed and the abundance of SH elements in nature is estimated.

  12. Heavy Element Synthesis Reaction Mechanisms W. Loveland Oregon State University

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reaction Mechanisms W. Loveland Oregon State University Production of Heavy Elements in Complete Fusion Reactions * We need to know three spin-dependent quantities: (a) the capture cross section, (b) the fusion probability and (c) the survival probability, and their isospin dependence where Examples of cold fusion predictions The problem Hot fusion examples "How good are the model predictions of cross sections" * Very controversial Zagrebaev and Greiner (2015) Zagrebaev et al. (2001)

  13. Heavy-element fission barriers (Journal Article) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Journal Article: Heavy-element fission barriers Citation Details In-Document Search Title: Heavy-element fission barriers We present calculations of fission properties for heavy elements. The calculations are based on the macroscopic-microscopic finite-range liquid-drop model with a 2002 parameter set. For each nucleus we have calculated the potential energy in three different shape parametrizations: (1) for 5 009 325 different shapes in a five-dimensional

  14. Nations Work Together to Discover New Element

    DOE R&D Accomplishments [OSTI]

    Cabage, Bill

    2011-03-28

    The discovery of element 117 increases evidence for the "island of stability" in super-heavy nuclei, opening new frontiers of chemistry.

  15. PIK M.S. Onegin Petersburg Nuclear Physics Institute 2015 Super Heavy Elements Symposium

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    possibilities of heavy actinide isotopes production in high-flux reactor PIK M.S. Onegin Petersburg Nuclear Physics Institute 2015 Super Heavy Elements Symposium Reactor PIK 2011 - Criticality reached 2013 - Construction finished 2014 - 2017 Licensing and neutron stations and installation construction 2018 - Power operation scheduled The maximum heat output 100 MW Heat transfer agent water Reflector heavy water Number of horizontal experimental channels 10 Number inclined experimental channels 6

  16. Heavy Ion Inertial Fusion Energy: Summaries of Program Elements

    SciTech Connect (OSTI)

    Friedman, A; Barnard, J J; Kaganovich, I; Seidl, P A; Briggs, R J; Faltens, A; Kwan, J W; Lee, E P; Logan, B G

    2011-02-28

    The goal of the Heavy Ion Fusion (HIF) Program is to apply high-current accelerator technology to IFE power production. Ion beams of mass {approx}100 amu and kinetic energy {>=} 1 GeV provide efficient energy coupling into matter, and HIF enjoys R&D-supported favorable attributes of: (1) the driver, projected to be robust and efficient; see 'Heavy Ion Accelerator Drivers.'; (2) the targets, which span a continuum from full direct to full indirect drive (and perhaps fast ignition), and have metal exteriors that enable injection at {approx}10 Hz; see 'IFE Target Designs'; (3) the near-classical ion energy deposition in the targets; see 'Beam-Plasma Interactions'; (4) the magnetic final lens, robust against damage; see 'Final Optics-Heavy Ion Beams'; and (5) the fusion chamber, which may use neutronically-thick liquids; see 'Liquid-Wall Chambers.' Most studies of HIF power plants have assumed indirect drive and thick liquid wall protection, but other options are possible.

  17. Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry Print Chemical science at the ALS encompasses a broad range of approaches and specializations, including surfaces/interfaces, catalysis, chemical dynamics (gas-phase chemistry), crystallography, and physical chemistry. By one estimate, nearly 80% of all chemical reactions in nature and in human technology take place at boundaries between phases, i.e., at surfaces or interfaces. Atomic- and molecular-scale studies are needed to develop a thorough understanding of the relationships

  18. Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Industrial Chemistry Top Journals Journal of the American Chemical Society Angewandte Chemie & Angewandte Chemie, international edition in English Chemical Communications Chemical...

  19. Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry Chemistry Chemical science for a dynamic world Jonathan Ward Engle, is among 49 winners, of the US Department of Energy's Early Career Research Program awards for 2016. Physicist wins early-career award for isotope work READ MORE 3D printer is ideal tool to make cones of explosive material with finely controlled internal microstructure Explosiv3Design READ MORE Isotopes for cancer and cardiac care Isotopes for cancer and cardiac care READ MORE Contact Us Division Leader David Morris

  20. Effects of extreme pressure additive chemistry on rolling element bearing surface durability

    SciTech Connect (OSTI)

    Evans, Ryan D.; Nixon, H. P.; Darragh, Craig V.; Howe, Jane Y; Coffey, Dorothy W

    2007-01-01

    Lubricant additives have been known to affect rolling element bearing surface durability for many years. Tapered roller bearings were used in fatigue testing of lubricants formulated with gear oil type additive systems. These systems have sulfur- and phosphoruscontaining compounds used for gear protection as well as bearing lubrication. Several variations of a commercially available base additive formulation were tested having modified sulfur components. The variations represent a range of ''active'' extreme pressure (EP) chemistries. The bearing fatigue test results were compared with respect to EP formulation and test conditions. Inner ring near-surface material in selected test bearings was evaluated on two scales: the micrometer scale using optical metallography and the nanometer scale using transmission electron microscopy (TEM). Focused-ion beam (FIB) techniques were used for TEM specimen preparation. Imaging and chemical analysis of the bearing samples revealed near-surface material and tribofilm characteristics. These results are discussed with respect to the relative fatigue lives.

  1. Surveys of research in the Chemistry Division, Argonne National Laboratory

    SciTech Connect (OSTI)

    Grazis, B.M.

    1992-11-01

    Research reports are presented on reactive intermediates in condensed phase (radiation chemistry, photochemistry), electron transfer and energy conversion, photosynthesis and solar energy conversion, metal cluster chemistry, chemical dynamics in gas phase, photoionization-photoelectrons, characterization and reactivity of coal and coal macerals, premium coal sample program, chemical separations, heavy elements coordination chemistry, heavy elements photophysics/photochemistry, f-electron interactions, radiation chemistry of high-level wastes (gas generation in waste tanks), ultrafast molecular electronic devices, and nuclear medicine. Separate abstracts have been prepared. Accelerator activites and computer system/network services are also reported.

  2. Surveys of research in the Chemistry Division, Argonne National Laboratory

    SciTech Connect (OSTI)

    Grazis, B.M.

    1992-01-01

    Research reports are presented on reactive intermediates in condensed phase (radiation chemistry, photochemistry), electron transfer and energy conversion, photosynthesis and solar energy conversion, metal cluster chemistry, chemical dynamics in gas phase, photoionization-photoelectrons, characterization and reactivity of coal and coal macerals, premium coal sample program, chemical separations, heavy elements coordination chemistry, heavy elements photophysics/photochemistry, f-electron interactions, radiation chemistry of high-level wastes (gas generation in waste tanks), ultrafast molecular electronic devices, and nuclear medicine. Separate abstracts have been prepared. Accelerator activites and computer system/network services are also reported.

  3. Final Report: Main Group Element Chemistry in Service of Hydrogen Storage and Activation

    SciTech Connect (OSTI)

    David A. Dixon; Anthony J. Arduengo, III

    2010-09-30

    Replacing combustion of carbon-based fuels with alternative energy sources that have minimal environmental impact is one of the grand scientific and technological challenges of the early 21st century. Not only is it critical to capture energy from new, renewable sources, it is also necessary to store the captured energy efficiently and effectively for use at the point of service when and where it is needed, which may not be collocated with the collection site. There are many potential storage media but we focus on the storage of energy in chemical bonds. It is more efficient to store energy on a per weight basis in chemical bonds. This is because it is hard to pack electrons into small volumes with low weight without the use of chemical bonds. The focus of the project was the development of new chemistries to enable DOE to meet its technical objectives for hydrogen storage using chemical hydrogen storage systems. We provided computational chemistry support in terms of thermodynamics, kinetics, and properties prediction in support of the experimental efforts of the DOE Center of Excellence for Chemical Hydrogen Storage. The goal of the Center is to store energy in chemical bonds involving hydrogen atoms. Once the hydrogen is stored in a set of X-H/Y-H bonds, the hydrogen has to be easily released and the depleted fuel regenerated very efficiently. This differs substantially from our current use of fossil fuel energy sources where the reactant is converted to energy plus CO2 (coal) or CO2 and H2O (gasoline, natural gas), which are released into the atmosphere. In future energy storage scenarios, the spent fuel will be captured and the energy storage medium regenerated. This places substantial additional constraints on the chemistry. The goal of the computational chemistry work was to reduce the time to design new materials and develop materials that meet the 2010 and 2015 DOE objectives in terms of weight percent, volume, release time, and regeneration ability. This goal was met in terms of reducing the number of costly experiments and helping to focus the experimental effort on the potentially optimal targets. We have used computational chemistry approaches to predict the thermodynamic properties of a wide range of compounds containing boron, nitrogen, hydrogen, and other elements as appropriate including carbon. These calculations were done in most cases with high level molecular orbital theory methods that have small error bars on the order of 1 to 2 kcal/mol. The results were used to benchmark more approximate methods such as density functional theory for larger systems and for database development. We predicted reliable thermodynamics for thousands of compounds for release and regeneration schemes to aid/guide materials design and process design and simulation. These are the first reliable computed values for these compounds and for many represent the only available values. Overall, the computational results have provided us with new insights into the chemistry of main group and organic-base chemical hydrogen systems from the release of hydrogen to the regeneration of spent fuel. A number of experimental accomplishments were also made in this project. The experimental work on hydrogen storage materials centered on activated polarized ?- or ?-bonded frameworks that hold the potential for ready dihydrogen activation, uptake, and eventually release. To this end, a large number of non-traditional valence systems including carbenes, cyanocarbons, and C-B and and B-N systems were synthesized and examined. During the course of these studies an important lead arose from the novel valency of a class of stable organic singlet bi-radical systems. A synthetic strategy to an endless hydrogen storage polymer has been developed based on our cyanocarbon chemistry. A key issue with the synthetic efforts was being able to link the kinetics of release with the size of the substituents as it was difficult to develop a low molecular weight molecule with the right kinetics. A novel hydrogen activation process has been developed

  4. Actinide Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Actinide Chemistry Actinide Chemistry Research into alternative forms of energy, especially energy security, is one of the major national security imperatives of this century. Get Expertise David Gallimore Actinide Analytical Chemistry Email Rebecca Chamberlin Actinide Analytical Chemistry Email Josh Smith Chemistry Communications Email Along with the lanthanides, they are often called "the f-elements" because they have valence electrons in the f shell. Actinide chemistry serves a

  5. Heavy element effects in the diagonal Born–Oppenheimer correction within a relativistic spin-free Hamiltonian

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Imafuku, Yuji; Abe, Minori; Schmidt, Michael W.; Hada, Masahiko

    2016-03-22

    Methodologies beyond the Born–Oppenheimer (BO) approximation are nowadays important to explain high precision spectroscopic measurements. Most previous evaluations of the BO correction are, however, focused on light-element molecules and based on a nonrelativistic Hamiltonian, so no information about the BO approximation (BOA) breakdown in heavy-element molecules is available. The present work is the first to investigate the BOA breakdown for the entire periodic table, by considering scalar relativistic effects in the Diagonal BO correction (DBOC). In closed shell atoms, the relativistic EDBOC scales as Z1.25 and the nonrelativistic EDBOC scales as Z1.17, where Z is the atomic number. Hence, wemore » found that EDBOC becomes larger in heavy element atoms and molecules, and the relativistic EDBOC increases faster than nonrelativistic EDBOC. We have further investigated the DBOC effects on properties such as potential energy curves, spectroscopic parameters, and various energetic properties. The DBOC effects for these properties are mostly affected by the lightest atom in the molecule. Furthermore, in X2 or XAt molecule (X = H, Li, Na, K, Rb, and Cs) the effect of DBOC systematically decreases when X becomes heavier but in HX molecules, the effect of DBOC seems relatively similar among all the molecules.« less

  6. THE ORIGINS OF LIGHT AND HEAVY R-PROCESS ELEMENTS IDENTIFIED BY CHEMICAL TAGGING OF METAL-POOR STARS

    SciTech Connect (OSTI)

    Tsujimoto, Takuji; Shigeyama, Toshikazu

    2014-11-01

    Growing interests in neutron star (NS) mergers as the origin of r-process elements have sprouted since the discovery of evidence for the ejection of these elements from a short-duration ?-ray burst. The hypothesis of a NS merger origin is reinforced by a theoretical update of nucleosynthesis in NS mergers successful in yielding r-process nuclides with A >130. On the other hand, whether the origin of light r-process elements are associated with nucleosynthesis in NS merger events remains unclear. We find a signature of nucleosynthesis in NS mergers from peculiar chemical abundances of stars belonging to the Galactic globular cluster M15. This finding combined with the recent nucleosynthesis results implies a potential diversity of nucleosynthesis in NS mergers. Based on these considerations, we are successful in the interpretation of an observed correlation between [light r-process/Eu] and [Eu/Fe] among Galactic halo stars and accordingly narrow down the role of supernova nucleosynthesis in the r-process production site. We conclude that the tight correlation by a large fraction of halo stars is attributable to the fact that core-collapse supernovae produce light r-process elements while heavy r-process elements such as Eu and Ba are produced by NS mergers. On the other hand, stars in the outlier, composed of r-enhanced stars ([Eu/Fe] ?+1) such as CS22892-052, were exclusively enriched by matter ejected by a subclass of NS mergers that is inclined to be massive and consist of both light and heavy r-process nuclides.

  7. Glann Seaborg's Contributions to Heavy Element Science and the Periodic Table

    SciTech Connect (OSTI)

    Hobart, David E.

    2012-08-17

    In celebrating the centennial anniversary of the birth of Glenn T. Seaborg it is fitting that we recount and pay tribute to his legacy. Many know of the scientific accomplishments of this man who became a legend and anyone who has attended his lectures can attest to how informative, educational, and entertaining he was. He had a beguiling and whimsical sense of humor and used this to drive home his points and share his passion and quest for discovery. The periodic table is a fundamental cornerstone of science and remains a central unifying principal. Seaborg was the architect of the actinide series of elements and their proper placement in the periodic table and co-discoverer of ten transuranium elements - one of which bears his name, element 106, seaborgium. The work and achievements of this Nobel laureate have touched the lives of many and his legacy will continue for generations to come.

  8. Effect of minor chemistry elements on GTA weld fusion zone characteristics of a commercial grade titanium

    SciTech Connect (OSTI)

    Marya, S.K.

    1996-06-01

    Gas Tungsten Arc Welding (GTAW) is the most common technique employed in the fabrication of rolled thin tubes. One of the major manufacturing problems concerns the stability of weld fusion zone on materials from different casts, notwithstanding stringent monitoring of the process parameters -- current, voltage and travel speed. These parameters determine the theoretical weld heat and are expected to control the instantaneous mass of melt. According to the data compiled by Sahoo et al., oxygen is known to reduce the surface tension of most of the metals. However, investigations on the role of minor changes in concentrations of elements like sulphur, oxygen, selenium, bismuth, aluminium, and titanium in steels have very often attributed the cast to cast variations to different temperature gradients of surface tension over the weldpool. To the author`s knowledge, no reported work so far has revealed changing weld profiles in autogeneous mechanized GTA welds on titanium due to minor composition changes.

  9. Cetane Performance and Chemistry Comparing Conventional Fuels...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cetane Performance and Chemistry Comparing Conventional Fuels and Fuels Derived from Heavy Crude Sources Cetane Performance and Chemistry Comparing Conventional Fuels and Fuels ...

  10. Magnetocaloric effect in heavy rare-earth elements doped Fe-based bulk metallic glasses with tunable Curie temperature

    SciTech Connect (OSTI)

    Li, Jiawei; Huo, Juntao; Chang, Chuntao E-mail: dujun@nimte.ac.cn; Du, Juan E-mail: dujun@nimte.ac.cn; Man, Qikui; Wang, Xinmin; Li, Run-Wei; Law, Jiayan

    2014-08-14

    The effects of heavy rare earth (RE) additions on the Curie temperature (T{sub C}) and magnetocaloric effect of the Fe-RE-B-Nb (RE = Gd, Dy and Ho) bulk metallic glasses were studied. The type of dopping RE element and its concentration can easily tune T{sub C} in a large temperature range of 120 K without significantly decreasing the magnetic entropy change (ΔS{sub M}) and refrigerant capacity (RC) of the alloys. The observed values of ΔS{sub M} and RC of these alloys compare favorably with those of recently reported Fe-based metallic glasses with enhanced RC compared to Gd{sub 5}Ge{sub 1.9}Si{sub 2}Fe{sub 0.1}. The tunable T{sub C} and large glass-forming ability of these RE doped Fe-based bulk metallic glasses can be used in a wide temperature range with the final required shapes.

  11. Element

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Departmental Element 2. System Name/ Major Application Name 3. Location 4. Name of System Owner/ Information or Data Owner 5. Contact Information 6. Does the system collect or maintain Social Security numbers? 7. Source of Legal Requirement/Authority to Collect or Maintain Social Security Numbers? 8. Does the system have a Privacy Impact Assessment (PIA)? 9. Does the system have a System of Records Notice (SORN)? If yes, provide the name of the System of Records Notice. 10. Does the system

  12. Nucleosynthesis in helium-enriched asymptotic giant branch models: Implications for heavy element enrichment in ω Centauri

    SciTech Connect (OSTI)

    Karakas, Amanda I.; Marino, Anna F.; Nataf, David M.

    2014-03-20

    We investigate the effect of helium enrichment on the evolution and nucleosynthesis of low-mass asymptotic giant branch (AGB) stars of 1.7 M {sub ☉} and 2.36 M {sub ☉} with a metallicity of Z = 0.0006 ([Fe/H] ≈–1.4). We calculate evolutionary sequences with the primordial helium abundance (Y = 0.24) and with helium-enriched compositions (Y = 0.30, 0.35, 0.40). For comparison, we calculate models of the same mass but at a lower metallicity Z = 0.0003 ([Fe/H] ≈–1.8) with Y = 0.24. Post-processing nucleosynthesis calculations are performed on each of the evolutionary sequences to determine the production of elements from hydrogen to bismuth. Elemental surface abundance predictions and stellar yields are presented for each model. The models with enriched helium have shorter main sequence and AGB lifetimes, and they enter the AGB with a more massive hydrogen-exhausted core than the primordial helium model. The main consequences are as follows: (1) low-mass AGB models with enhanced helium will evolve more than twice as fast, giving them the chance to contribute sooner to the chemical evolution of the forming globular clusters, and (2) the stellar yields will be strongly reduced relative to their primordial helium counterparts. An increase of ΔY = 0.10 at a given mass decreases the yields of carbon by up to ≈60% and of fluorine by up to 80%; it also decreases the yields of the s-process elements barium and lanthanum by ≈45%. While the yields of first s-process peak elements strontium, yttrium, and zirconium decrease by up to 50%, the yields of rubidium either do not change or increase.

  13. Grain refinement in heavy rare earth element-free sintered Nd–Fe–B magnets by addition of a small amount of molybdenum

    SciTech Connect (OSTI)

    Kim, Jin Woo; Lee, Won Suk; Byun, Jong Min; Kim, Young Do; Kim, Se Hoon

    2015-05-07

    We employed a modified refractory-metal-addition method to achieve higher coercivity and remanence in heavy rare earth element (HREE)-free Nd–Fe–B sintered magnets. This process involved inducing the formation of a homogeneous secondary phase at the grain boundaries during sintering, making it possible to control the intergrain diffusion by adding small amounts of Mo, a refractory metal. To control the microstructure of the secondary phase effectively, a metal organic compound of the refractory metal was coated on the surfaces of the particles of an HREE-free Nd–Fe–B powder. The average grain size after this process was 5.60 μm, which was approximately 1.8 μm smaller than that of the HREE-free sintered Nd–Fe–B magnets (7.4 μm). The coercivity of the magnets prepared through this process could be increased from 11.88 kOe to 13.91 kOe without decreasing their remanence.

  14. SECTION II: HEAVY ION REACTIONS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for heavy element production...II-1 P. K.Sahu, J. B. Natowitz, R. Wada, K. Hagel, T. Materna, Z. Chen, L. Qin, M. Barbui,...

  15. Top Quark Produced Through the Electroweak Force: Discovery Using the Matrix Element Analysis and Search for Heavy Gauge Bosons Using Boosted Decision Trees

    SciTech Connect (OSTI)

    Pangilinan, Monica; /Brown U.

    2010-02-01

    The top quark produced through the electroweak channel provides a direct measurement of the V{sub tb} element in the CKM matrix which can be viewed as a transition rate of a top quark to a bottom quark. This production channel of top quark is also sensitive to different theories beyond the Standard Model such as heavy charged gauged bosons termed W{prime}. This thesis measures the cross section of the electroweak produced top quark using a technique based on using the matrix elements of the processes under consideration. The technique is applied to 2.3 fb{sup -1} of data from the D0 detector. From a comparison of the matrix element discriminants between data and the signal and background model using Bayesian statistics, we measure the cross section of the top quark produced through the electroweak mechanism {sigma}(p{bar p} {yields} tb + X, tqb + X) = 4.30{sub -1.20}{sup +0.98} pb. The measured result corresponds to a 4.9{sigma} Gaussian-equivalent significance. By combining this analysis with other analyses based on the Bayesian Neural Network (BNN) and Boosted Decision Tree (BDT) method, the measured cross section is 3.94 {+-} 0.88 pb with a significance of 5.0{sigma}, resulting in the discovery of electroweak produced top quarks. Using this measured cross section and constraining |V{sub tb}| < 1, the 95% confidence level (C.L.) lower limit is |V{sub tb}| > 0.78. Additionally, a search is made for the production of W{prime} using the same samples from the electroweak produced top quark. An analysis based on the BDT method is used to separate the signal from expected backgrounds. No significant excess is found and 95% C.L. upper limits on the production cross section are set for W{prime} with masses within 600-950 GeV. For four general models of W{prime} boson production using decay channel W{prime} {yields} t{bar b}, the lower mass limits are the following: M(W{prime}{sub L} with SM couplings) > 840 GeV; M(W{prime}{sub R}) > 880 GeV or 890 GeV if the right-handed neutrino is lighter or heavier than W{prime}{sub R}; and M(W{prime}{sub L+R}) > 915 GeV.

  16. Superheavy Elements - Achievements and Challenges

    SciTech Connect (OSTI)

    Ackermann, Dieter

    2009-03-04

    The search for superheavy elements (SHE) has yielded exciting results for both the 'cold fusion' approach with reactions employing Pb and Bi targets and the ''hot fusion'' reactions with {sup 48}Ca beams on actinide targets. The most recent activities at GSI were the successful production of a more neutron rich isotope of element 112 in the reaction {sup 48}Ca+{sup 238}U confirming earlier result from FLNR, and the attempt to synthesize an isotope with Z 120 in the reaction {sup 64}Ni+{sup 238}U. Apart from the synthesis of new elements, advanced nuclear structure studies for heavy and super heavy elements promise a detailed insight in the properties of nuclear matter under the extreme conditions of high Z and A. The means are evaporation residue(ER)-{alpha}-{alpha} and -{alpha}-{gamma} coincidence techniques applied after separation of the reaction products from the beam. Recent examples of interesting physics to be discovered in this region of the chart of nuclides are the investigation of K-isomers observed for {sup 252,254}No and indicated for {sup 270}Ds. Fast chemistry and precision mass measurements deliver in addition valuable information on the fundamental properties of the SHE.

  17. Chemistry of hydrotreating heavy crudes: II. Detailed analysis of polar compounds in Wilmington 650-1000 degree F distillate and hydrotreated products

    SciTech Connect (OSTI)

    Sturm, G.P. Jr.; Green, J.B.; Tang, S.Y.; Reynolds, J.W.; Yu, S.K.T. )

    1987-04-01

    Notwithstanding the current oversupply of crude oil, the future importance of heavy crude as a primary energy resource is widely recognized. In addition, with the market for resid declining, refiners are facing an increasing challenge to convert more of the bottom of the barrel to transportation fuels. The problems that have been predicted for refinery products made from heavier feedstocks are now beginning to surface. State-of-the-art upgrading procedures have proven to be inadequate for removal of many of the chemical compound types that cause problems in the processing sequence or adversely affect the quality of the end products. These problems include instability or incompatibility of process streams or products, corrosiveness and catalyst poisoning. Before new approaches can be intelligently developed to remove the problem components, it is necessary to know what compound types are causing the observed problems. This study is focused on determination of polar compounds in the feedstock and products from hydrotreating a distillate of a representative heavy crude, Wilmington. The ultimate objective is to acquire an understanding of the compound types and reaction mechanisms contributing to instability, incompatibility, corrosiveness, catalyst poisoning and other problems exhibited by some crude oil feedstocks, intermediate process streams and final products resulting from the processing of lower quality fossil fuel feedstocks.

  18. Chemistry Division annual progress report for period ending January 31, 1984

    SciTech Connect (OSTI)

    Not Available

    1984-05-01

    Progress is reported in the following fields: coal chemistry, aqueous chemistry at high temperatures and pressures, geochemistry, high-temperature chemistry and thermodynamics of structural materials, chemistry of transuranium elements and compounds, separations chemistry, elecrochemistry, catalysis, chemical physics, theoretical chemistry, nuclear waste chemistry, chemistry of hazardous chemicals, and thermal energy storage.

  19. Atmospheric Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    competencies Atmospheric Chemistry Atmospheric Chemistry is the study of the composition of the atmosphere, the sources and fates of gases and particles in air, and changes induced...

  20. Flame Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Software Computations Uncertainty Quantification Stochastic About CRF Transportation Energy Consortiums Engine Combustion Heavy Duty Heavy Duty Low-Temperature & Diesel Combustion ...

  1. Materials Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Software Computations Uncertainty Quantification Stochastic About CRF Transportation Energy Consortiums Engine Combustion Heavy Duty Heavy Duty Low-Temperature & Diesel Combustion ...

  2. Actinide Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Actinide Chemistry Actinide chemistry serves a critical role in addressing global threats Project Description At Los Alamos, scientists are using actinide analytical chemistry to identify and quantify the chemical and isotopic composition of materials. Since the Manhattan Project, such work has supported the Laboratory's mission. Today, actinide analytical chemistry plays a critical role in ensuring the national security of the United States through nuclear science and technology. The scope of

  3. Chemistry Division annual progress report for period ending July 31, 1981

    SciTech Connect (OSTI)

    Not Available

    1982-01-01

    Research is reported on: chemistry of coal liquefaction, aqueous chemistry at high temperatures, geosciences, high-temperature chemistry and thermodynamics of structural materials, chemistry of TRU elements and compounds, separations chemistry, electrochemistry, nuclear waste chemistry, chemical physics, theoretical chemistry, inorganic chemistry of hydrogen cycles, molten salt systems, and enhanced oil recovery. Separate abstracts were prepared for the sections dealing with coal liquefaction, TRU elements and compounds, separations, nuclear wastes, and enhanced oil recovery. (DLC)

  4. Chemistry-nuclear chemistry division. Progress report, October 1979-September 1980

    SciTech Connect (OSTI)

    Ryan, R.R. (comp.)

    1981-05-01

    This report presents the research and development programs pursued by the Chemistry-Nuclear Chemistry Division of the Los Alamos National Laboratory. Topics covered include advanced analytical methods, atmospheric chemistry and transport, biochemistry, biomedical research, element migration and fixation, inorganic chemistry, isotope separation and analysis, atomic and molecular collisions, molecular spectroscopy, muonic x rays, nuclear cosmochemistry, nuclear structure and reactions, radiochemical separations, theoretical chemistry, and unclassified weapons research.

  5. Heavy Vehicle Systems

    SciTech Connect (OSTI)

    Sid Diamond; Richard Wares; Jules Routbort

    2000-04-11

    Heavy Vehicle (HV) systems are a necessary component of achieving OHVT goals. Elements are in place for a far-ranging program: short, intermediate, and long-term. Solicitation will bring industrial input and support. Future funding trend is positive, outlook for HV systems is good.

  6. Chemistry Applications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry Chemistry Applications Gaussian 09 Gaussian 09 is a connected series of programs for performing semi-empirical, density functional theory and ab initio molecular orbital calculations. Read More » GAMESS GAMESS (General Atomic and Molecular Electronic Structure System) is a general ab initio quantum chemistry package. Read More » AMBER AMBER (Assisted Model Building with Energy Refinement) is the collective name for a suite of programs designed to carry out molecular dynamics

  7. Chemistry Division annual progress report for period ending January 31, 1986

    SciTech Connect (OSTI)

    Not Available

    1986-05-01

    This report has been indexed by 11 separate chapters. The subjects covered are: coal chemistry, aqueous chemistry at high temperatures and pressures, geochemistry, materials chemistry, chemistry of transuranium elements and compounds, separations chemistry, catalysis, electron spectroscopy, nuclear waste chemistry, heuristic modeling, and special topics. (PLG)

  8. Reaction chemistry of cerium

    SciTech Connect (OSTI)

    1997-01-01

    It is truly ironic that a synthetic organic chemist likely has far greater knowledge of the reaction chemistry of cerium(IV) than an inorganic colleague. Cerium(IV) reagents have long since been employed as oxidants in effecting a wide variety of organic transformations. Conversely, prior to the late 1980s, the number of well characterized cerium(IV) complexes did not extend past a handful of known species. Though in many other areas, interest in the molecular chemistry of the 4f-elements has undergone an explosive growth over the last twenty years, the chemistry of cerium(IV) has for the most part been overlooked. This report describes reactions of cerium complexes and structure.

  9. Ga, Ca, and 3d transition element (Cr through Zn) partitioning among spinel-lherzolite phases from the Lanzo massif, Italy: Analytical results and crystal chemistry

    SciTech Connect (OSTI)

    Wogelius, R.A.; Fraser, D.G.

    1994-06-01

    Ultramafic rocks exposed in Lanzo massif, Italy is a record of mantle geochemistry, melting, sub-solidus re-equilibration. Plagioclase(+ spinel)-lherzolite samples were analyzed by Scanning Proton Microscopy, other techniques. Previous work postulated partial melting events and a two-stage sub-solidus cooling history; this paper notes Ga enrichment on spinel-clinopyroxene grain boundaries, high Ga and transition element content of spinel, and pyroxene zonation in Ca and Al. Trace element levels in olivine and orthopyroxene are also presented. Zoning trends are interpreted as due to diffusion during cooling. Olivine-clinopyroxene Cr and Ca exchange as well as clinopyroxene and spinel zonation trends indicate that the massif experienced at least two sub-solidus cooling episodes, one at 20 kbar to 1000 C and one at 8 kbar <750C. Ga levels in cores of Lanzo high-Cr spinels are high (82-66 ppM) relative to other mantle spinels (66-40 ppM), indicating enrichment. Ga content of ultramafic spinels apparently increases with Cr content; this may be due to: increased Ga solubility stemming from crystal chemical effects and/or higher Ga activities in associated silicate melts. Thus, during melting, high-Cr residual spinel may tend to buffer solid-phase Ga level. These spinels are not only rich in Ga and Cr (max 26.37 el. wt %), but also in Fe (max 21.07 el. wt %), Mn (max 3400 ppM), and Zn (max 2430 ppM). These enrichments are again due to melt extraction and partitioning into spinel structure. Low Ni (min 1050 ppM) levels are due to unsuccessful competition of Ni with Cr for octahedral structural sites caused by crystal field. Comparisons of change in partitioning vs Cr content among several 3d transition elements for spinels from Lanzo, other localities allow us to separate crystal field effects from bulk chemical effects and to show that in typical assemblages, inversion of olivine-spinel partition coefficient for Ni from <1 to >1 should occur at 11% el. wt. Cr in spinel.

  10. HEAVY ION LINEAR ACCELERATOR

    DOE Patents [OSTI]

    Van Atta, C.M.; Beringer, R.; Smith, L.

    1959-01-01

    A linear accelerator of heavy ions is described. The basic contributions of the invention consist of a method and apparatus for obtaining high energy particles of an element with an increased charge-to-mass ratio. The method comprises the steps of ionizing the atoms of an element, accelerating the resultant ions to an energy substantially equal to one Mev per nucleon, stripping orbital electrons from the accelerated ions by passing the ions through a curtain of elemental vapor disposed transversely of the path of the ions to provide a second charge-to-mass ratio, and finally accelerating the resultant stripped ions to a final energy of at least ten Mev per nucleon.

  11. Flame Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy

  12. Materials Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy

  13. Combustion Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy

  14. Chemistry-Nuclear Chemistry Division. Progress report, October 1980-September 1981

    SciTech Connect (OSTI)

    Ryan, R.R.

    1982-05-01

    This report describes major progress in the research and development programs pursued by the Chemistry-Nuclear Chemistry Division of the Los Alamos National Laboratory during FY 1981. Topics covered include advanced analytical methods, atmospheric chemistry and transport, biochemistry, biomedical research, medical radioisotopes research, element migration and fixation, nuclear waste isolation research, inorganic and structural chemistry, isotope separation, analysis and applications, the newly established Nuclear Magnetic Resonance Center, atomic and molecular collisions, molecular spectroscopy, nuclear cosmochemistry, nuclear structure and reactions, pion charge exchange, radiochemical separations, theoretical chemistry, and unclassified weapons research.

  15. Challenges in explosive nucleosynthesis of heavy elements

    SciTech Connect (OSTI)

    Pinedo, Gabriel Martinez; Fischer, T.; Lohs, A.; Huther, L.

    2012-10-20

    We show that a treatment of charged-current neutrino interactions in hot and dense matter that is consistent with the nuclear equation of state has a strong impact on the spectra of the neutrinos emitted during the deleptonization period of a protoneutron star formed in a core-collapse supernova. We compare results of simulations including and neglecting mean field effects on the neutrino opacities. Their inclusion reduces the luminosities of all neutrino flavors and enhances the spectral differences between electron neutrino and antineutrino. The magnitude of the difference depends on the equation of state and in particular on the symmetry energy at sub-nuclear densities. These modifications reduce the proton-to-nucleon ratio of the neutrino-driven outflow, increasing slightly their entropy. They are expected to have a substantial impact on the nucleosynthesis in neutrino-driven winds, even though they do not result in conditions that favor an r-process. Contrarily to previous findings, our simulations show that the spectra of electron neutrinos remain substantially different from those of other (anti)neutrino flavors during the entire deleptonization phase of the protoneutron star. The obtained luminosity and spectral changes are also expected to have important consequences for neutrino flavor oscillations and neutrino detection on Earth.

  16. Combustion chemistry

    SciTech Connect (OSTI)

    Brown, N.J.

    1993-12-01

    This research is concerned with the development and use of sensitivity analysis tools to probe the response of dependent variables to model input variables. Sensitivity analysis is important at all levels of combustion modeling. This group`s research continues to be focused on elucidating the interrelationship between features in the underlying potential energy surface (obtained from ab initio quantum chemistry calculations) and their responses in the quantum dynamics, e.g., reactive transition probabilities, cross sections, and thermal rate coefficients. The goals of this research are: (i) to provide feedback information to quantum chemists in their potential surface refinement efforts, and (ii) to gain a better understanding of how various regions in the potential influence the dynamics. These investigations are carried out with the methodology of quantum functional sensitivity analysis (QFSA).

  17. The transuranium elements: From neptunium and plutonium to element 112

    SciTech Connect (OSTI)

    Hoffman, D.C. |

    1996-07-26

    Beginning in the 1930`s, both chemists and physicists became interested in synthesizing new artificial elements. The first transuranium element, Np, was synthesized in 1940. Over the past six decades, 20 transuranium elements have been produced. A review of the synthesis is given. The procedure of naming the heavy elements is also discussed. It appears feasible to produce elements 113 and 114. With the Berkeley Gas-filled Separator, it should be possible to reach the superheavy elements in the region of the spherical Z=114 shell, but with fewer neutrons than the N=184 spherical shell. 57 refs, 6 figs.

  18. Heavy loads

    SciTech Connect (OSTI)

    Metz, D.

    1982-01-01

    The extreme pressures on the roof and walls of an earth-sheltered residential home are discussed and the need for careful planning is stressed. Pertinent terms are defined. Footings and wall structure (reinforced concrete walls and concrete block walls) are described. Roofing systems are discussed in detail and illustrated: (1) poured-in-place concrete roof slabs; (2) pre-cast concrete planks; and (3) heavy timber roofs. Insulation of earth-sheltered homes is reviewed in terms of using: (1) urethanes; (2) extruded polystyrene; and (3) expanded polystyrene. Advantages, disadvantages, R-factors, costs, and installation are discussed. (MJJ)

  19. Elements in biological AMS

    SciTech Connect (OSTI)

    Vogel, J.S.; McAninch, J.; Freeman, S.

    1996-08-01

    AMS (Accelerator Mass Spectrometry) provides high detection sensitivity for isotopes whose half-lives are between 10 years and 100 million years. {sup 14}C is the most developed of such isotopes and is used in tracing natural and anthropogenic organic compounds in the Earth`s biosphere. Thirty-three elements in the main periodic table and 17 lanthanides or actinides have long lived isotopes, providing potential tracers for research in elemental biochemistry. Overlap of biologically interesting heavy elements and possible AMS tracers is discussed.

  20. High Pressure Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Software Computations Uncertainty Quantification Stochastic About CRF Transportation Energy Consortiums Engine Combustion Heavy Duty Heavy Duty Low-Temperature & Diesel Combustion ...

  1. Chemistry of Autoignition

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Software Computations Uncertainty Quantification Stochastic About CRF Transportation Energy Consortiums Engine Combustion Heavy Duty Heavy Duty Low-Temperature & Diesel Combustion ...

  2. Coordination chemistry of two heavy metals: I, Ligand preferences in lead(II) complexation, toward the development of therapeutic agents for lead poisoning: II, Plutonium solubility and speciation relevant to the environment

    SciTech Connect (OSTI)

    Neu, M.P.

    1993-11-01

    The coordination chemistry and solution behavior of the toxic ions lead(II) and plutonium(IV, V, VI) have been investigated. The ligand pK{sub a}s and ligand-lead(II) stability constants of one hydroxamic acid and four thiohydroaxamic acids were determined. Solution thermodynamic results indicate that thiohydroxamic acids are more acidic and slightly better lead chelators than hydroxamates, e.g., N-methylthioaceto-hydroxamic acid, pK{sub a} = 5.94, log{beta}{sub 120} = 10.92; acetohydroxamic acid, pK{sub a} = 9.34, log{beta}{sub l20} = 9.52. The syntheses of lead complexes of two bulky hydroxamate ligands are presented. The X-ray crystal structures show the lead hydroxamates are di-bridged dimers with irregular five-coordinate geometry about the metal atom and a stereochemically active lone pair of electrons. Molecular orbital calculations of a lead hydroxamate and a highly symmetric pseudo octahedral lead complex were performed. The thermodynamic stability of plutonium(IV) complexes of the siderophore, desferrioxamine B (DFO), and two octadentate derivatives of DFO were investigated using competition spectrophotometric titrations. The stability constant measured for the plutonium(IV) complex of DFO-methylterephthalamide is log{beta}{sub 110} = 41.7. The solubility limited speciation of {sup 242}Pu as a function of time in near neutral carbonate solution was measured. Individual solutions of plutonium in a single oxidation state were added to individual solutions at pH = 6.0, T = 30.0, 1.93 mM dissolved carbonate, and sampled over intervals up to 150 days. Plutonium solubility was measured, and speciation was investigated using laser photoacoustic spectroscopy and chemical methods.

  3. Future of heavy crude and tar sands

    SciTech Connect (OSTI)

    Meyer, R.F.; Steele, C.T.

    1981-01-01

    The 106 papers which were presented at the First International Conference on the Future of Heavy Crude and Tar Sands, held in Edmonton, Alberta are incorporated in this volume. They are grouped under the following sections: (1) role of heavy crude oils and tar sands in world energy; (2) major known occurrences; (3) chemistry and geochemistry; (4) geology; (5) resource evaluation techniques; (6) production research and pilot projects; (7) current production; (8) upgrading and refining; (9) transportation; (10) environmental research; (11) economics; (12) technological problems; (13) institutional factors; and (14) bibliography. All papers have been abstracted and indexed. (ATT)

  4. Compound and Elemental Analysis At Akutan Fumaroles Area (Kolker...

    Open Energy Info (EERE)

    and Elemental Analysis Activity Date Usefulness useful DOE-funding Unknown Notes The chemistry of the hot springs strongly suggests the existence of a neutral chloride reservoir...

  5. Adsorption of the Lighter Homologs of Element 104 and Element 105 on DGA Resin from Various Mineral Acids

    SciTech Connect (OSTI)

    Bennett, M E; Sudowe, R

    2008-11-17

    The goal of studying transactinide elements is to further understand the fundamental principles that govern the periodic table. The current periodic table arrangement allows for the prediction of the chemical behavior of elements. The correct position of a transactinide element can be assessed by investigating its chemical behavior and comparing it to that of the homologs and pseudo-homologs of a transactinide element. Homologs of a transactinide element are the elements in the same group of the periodic table as the transactinide. A pseudo-homolog of a transactinide element is an element with a similar main oxidation state and similar ionic radius to the transactinide element. For example, the homologs of rutherfordium, Rf, are titanium, zirconium and hafnium (Ti, Zr and Hf); the pseudo homologs of Rf are thorium, Th, and plutonium, Pu. Understanding the chemical behavior of a transactinide element compared to its homologs and pseudo-homologs also allows for the assessment of the role of relativistic effects. Relativistic effects occur when the velocity of the s orbital electrons closest to the nucleus approaches the speed of light. These electrons approach the speed of light because they have no orbital momentum. This causes two effects, first there is in a decrease in Bohr radius of the inner electronic orbitals because of this there is an increase in particle mass. A contraction of outer s and p orbitals is also seen. The contraction of these orbitals results in an energy destabilization of the outer most shell, in the case of transactinides this would be the 5f and 6d orbitals. The outer most d shell and all f shells can also experience a radial expansion due to these orbitals being screened from the effective nuclear charge. Another relativistic effect is the 'spin-orbit splitting' for p, d and f orbitals into j = 1 {+-} 1/2 states. Where j is the total angular momentum vector and 1 is angular quantum number. All of these effects have the same order of magnitude and increase roughly according to Z. This feature is what makes studying the heavy elements so interesting because the chemical properties of transactinide elements should strongly exhibit these effects. For this work the terms heavy element and transactinide elements will be used interchangeably and are defined as elements with an atomic number greater than 103, Z > 103. In order to study the transactinide elements they must be isolated once they have been produced and transported to a chemistry apparatus. The transactinide elements are produced either via 'hot' or 'cold' fusion reactions. 'Hot' fusion reactions result in excitation energies of the compound nucleus of 40-50 MeV and occur when an actinide target nuclei fuse with a projectile with A < 40, where A is the atomic mass number. 'Cold' fusion results in excitation energies of 10-15 MeV. Cold fusion conditions tend to occur when a target of a spherical nuclei (Pb or Bi) is bombarded with a heavy projectile (A > 40). Hot fusion generally leads to neutron rich isotopes and cold fusion tends to produce a compound nucleus that emits 1-2 neutrons upon de-excitation. If a sufficiently thin target is employed, then the products of the nuclear reaction will recoil out of the target and can either be transported to the chemistry setup, e.g. using a gas jet, or trapped by implementing them on a catcher. An example for a catcher setup using a copper block as a catcher is described here. The copper block is placed behind the target during the irradiation and all nuclei recoiling from the target position will implant themselves in the block. The copper block is subsequently dismounted and sputter cleaned. It is then shaved with a micro-lathe. The 7-10 {micro}m copper shavings are then subjected to chemical separation. The copper is dissolved in aqua regia. Lanthanum carrier is added to the aqua regia to precipitate tri-, tetra- and penta- valent cations when ammonium hydroxide is added. The precipitate is then washed and converted to the nitrate form. This solution is then added onto a cation exchange column, the eluent is deposited and dried on a polypropylene film and then counted on solid state detectors. There are several challenges when studying the chemical behavior of transactinide elements. The first challenge is the low production rate of transactinides. Transactinides are produced on an atom-at-a-time basis, meaning that only one atom is ever available for chemical study. Because of this the chemical system being used must be selective for only one chemical state. The second challenge in transactinide chemistry is the short half-lives of the elements. Half-lives of the transactinides range from nanoseconds to a few hours. This leads to the need for fast chemistry. Another challenge is the need for a high degree of separation from interfering radionuclides so that the event with the transactinide element can be detected.

  6. Heavy metal biosensor

    DOE Patents [OSTI]

    Hillson, Nathan J; Shapiro, Lucille; Hu, Ping; Andersen, Gary L

    2014-04-15

    Compositions and methods are provided for detection of certain heavy metals using bacterial whole cell biosensors.

  7. Advanced fuel chemistry for advanced engines.

    SciTech Connect (OSTI)

    Taatjes, Craig A.; Jusinski, Leonard E.; Zador, Judit; Fernandes, Ravi X.; Miller, James A.

    2009-09-01

    Autoignition chemistry is central to predictive modeling of many advanced engine designs that combine high efficiency and low inherent pollutant emissions. This chemistry, and especially its pressure dependence, is poorly known for fuels derived from heavy petroleum and for biofuels, both of which are becoming increasingly prominent in the nation's fuel stream. We have investigated the pressure dependence of key ignition reactions for a series of molecules representative of non-traditional and alternative fuels. These investigations combined experimental characterization of hydroxyl radical production in well-controlled photolytically initiated oxidation and a hybrid modeling strategy that linked detailed quantum chemistry and computational kinetics of critical reactions with rate-equation models of the global chemical system. Comprehensive mechanisms for autoignition generally ignore the pressure dependence of branching fractions in the important alkyl + O{sub 2} reaction systems; however we have demonstrated that pressure-dependent 'formally direct' pathways persist at in-cylinder pressures.

  8. Synthetic and Mechanistic Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Mechanistic Chemistry Security at center of chemical and mechanistic chemistry research at Lab Project Description Los Alamos scientists are using synthetic and mechanistic chemistry to address energy security and other emerging challenges, including global security and core weapons missions. Synthetic chemistry includes work in ligands for catalysts, fission-products separations for isotope delivery, and labeled substrates for reaction mechanisms. Other research addresses materials

  9. Synthetic and Mechanistic Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synthetic and Mechanistic Chemistry Synthetic and Mechanistic Chemistry Synthetic and mechanistic chemical sciences play an important role in Lab missions dedicated to energy security, emerging challenges, global security, and core weapons missions. Get Expertise Dave Thorn Chemistry Program Manager Email Josh Smith Chemistry Communications Email "Research into alternative forms of energy, of which biofuels is a key component, is one of the major national security imperatives of this

  10. ORNL, partners officially recognized for discovery of elements 115, 117

    ScienceCinema (OSTI)

    Roberto, Jim

    2016-01-15

    The International Union for Pure and Applied Chemistry has announced formal verification of four new chemical elements, recognizing the Department of Energy?s Oak Ridge National Laboratory and its collaborators for the discovery of elements 115 and 117.

  11. Fragmentation, NRQCD and Factorization in Heavy Quarkonium Production

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Fragmentation, NRQCD and Factorization in Heavy Quarkonium Production Citation Details In-Document Search Title: Fragmentation, NRQCD and Factorization in Heavy Quarkonium Production We discuss factorization in heavy quarkonium production in high energy collisions using NRQCD. Infrared divergences at NNLO are not matched by conventional NRQCD matrix elements. However, we show that gauge invariance and factorization require that conventional NRQCD

  12. Isotope and Nuclear Chemistry Division annual report, FY 1983

    SciTech Connect (OSTI)

    Heiken, J.H.; Lindberg, H.A.

    1984-05-01

    This report describes progress in the major research and development programs carried out in FY 1983 by the Isotope and Nuclear Chemistry Division. It covers radiochemical diagnostics of weapons tests; weapons radiochemical diagnostics research and development; other unclassified weapons research; stable and radioactive isotope production, separation, and applications (including biomedical applications); element and isotope transport and fixation; actinide and transition metal chemistry; structural chemistry, spectroscopy, and applications; nuclear structure and reactions; irradiation facilities; advanced analytical techniques; development and applications; atmospheric chemistry and transport; and earth and planetary processes.

  13. APEX heavy-ion counters

    SciTech Connect (OSTI)

    Mercer, D.J.

    1993-10-01

    A large solid-angle array of low-pressure multi-wire proportional counters (LPMWPC) forms part of the APEX apparatus. Eight three-element trapezoidal counters provide 360{degrees} coverage in {phi} and 20{degrees} - 70{degrees} coverage in {phi}. Angle information is obtained from a transmission-line delay cathode ({phi}) and from the segmentation ({phi}). Time-of-flight information is obtained from the anode signals. These quantities are used to extract the center-of-mass scattering angle, reaction Q value, and masses of the scattered heavy ions. Design and performance of the counters will be discussed.

  14. United abominations: Density functional studies of heavy metal chemistry

    SciTech Connect (OSTI)

    Schoendorff, George

    2012-04-02

    Carbonyl and nitrile addition to uranyl (UO{sup 2}{sup 2+}) are studied. The competition between nitrile and water ligands in the formation of uranyl complexes is investigated. The possibility of hypercoordinated uranyl with acetone ligands is examined. Uranyl is studied with diactone alcohol ligands as a means to explain the apparent hypercoordinated uranyl. A discussion of the formation of mesityl oxide ligands is also included. A joint theory/experimental study of reactions of zwitterionic boratoiridium(I) complexes with oxazoline-based scorpionate ligands is reported. A computational study was done of the catalytic hydroamination/cyclization of aminoalkenes with zirconium-based catalysts. Techniques are surveyed for programming for graphical processing units (GPUs) using Fortran.

  15. Synthetic and Mechanistic Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Jurgen G. Schmidt: Synthetic chemistry and stable isotopes for biological applications ... for monitoring and detecting chemical warfare agents" Journal of Labelled Compounds and ...

  16. Synthetic and Mechanistic Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Key Personnel * Jurgen G. Schmidt: Synthetic chemistry and stable isotopes for biological ... for monitoring and detecting chemical warfare agents" Journal of Labelled Compounds and ...

  17. ALS Chemistry Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    These spaces are dedicated for chemistry work that involves higher quantities, higher toxicity or reactivity, andor more complex work activity than is allowed on the ALS...

  18. DOE fundamentals handbook: Chemistry

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    This handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of chemistry. This volume contains the following modules: reactor water chemistry (effects of radiation on water chemistry, chemistry parameters), principles of water treatment (purpose; treatment processes [ion exchange]; dissolved gases, suspended solids, and pH control; water purity), and hazards of chemicals and gases (corrosives [acids, alkalies], toxic compounds, compressed gases, flammable/combustible liquids).

  19. HEAVY WATER MODERATED NEUTRONIC REACTOR

    DOE Patents [OSTI]

    Szilard, L.

    1958-04-29

    A nuclear reactor of the type which utilizes uranium fuel elements and a liquid coolant is described. The fuel elements are in the form of elongated tubes and are disposed within outer tubes extending through a tank containing heavy water, which acts as a moderator. The ends of the fuel tubes are connected by inlet and discharge headers, and liquid bismuth is circulated between the headers and through the fuel tubes for cooling. Helium is circulated through the annular space between the outer tubes in the tank and the fuel tubes to cool the water moderator to prevent boiling. The fuel tubes are covered with a steel lining, and suitable control means, heat exchange means, and pumping means for the coolants are provided to complete the reactor assembly.

  20. Heavy Mobile Equipment Mechanic

    Broader source: Energy.gov [DOE]

    Join the Bonneville Power Administration (BPA) for a challenging and rewarding career, while working, living, and playing in the Pacific Northwest. The Heavy Mobile Equipment Mechanic (HMEM)...

  1. High-energy accelerator for beams of heavy ions

    DOE Patents [OSTI]

    Martin, Ronald L. (La Grange, IL); Arnold, Richard C. (Chicago, IL)

    1978-01-01

    An apparatus for accelerating heavy ions to high energies and directing the accelerated ions at a target comprises a source of singly ionized heavy ions of an element or compound of greater than 100 atomic mass units, means for accelerating the heavy ions, a storage ring for accumulating the accelerated heavy ions and switching means for switching the heavy ions from the storage ring to strike a target substantially simultaneously from a plurality of directions. In a particular embodiment the heavy ion that is accelerated is singly ionized hydrogen iodide. After acceleration, if the beam is of molecular ions, the ions are dissociated to leave an accelerated singly ionized atomic ion in a beam. Extraction of the beam may be accomplished by stripping all the electrons from the atomic ion to switch the beam from the storage ring by bending it in magnetic field of the storage ring.

  2. Kinetics of heavy oil/coal coprocessing

    SciTech Connect (OSTI)

    Szladow, A.J.; Chan, R.K. ); Foudu, S.; Kelly, J.F. )

    1988-06-01

    A number of studies have been reported on coprocessing of coal and oil sand bitumen, petroleum residues and distillate fractions in catalytic and non-catalytic processes. The studies described the effects of feedstock characteristics, process chemistry and operating variables on the product yield and distribution; however, very few kinetic data were reported in these investigations. This paper presents the kinetic data and modelling of the CANMET coal/heavy oil coprocessing process. CANMET has been conducting research and process development work on coprocessing of Canadian heavy oil/bitumen and coal since 1979 including studies of the kinetics and mechanisms of coprocessing. As a continuation of the program, CANMET and Lobbe Technologies undertook a project on mathematical modelling of coprocessing kinetics with emphasis on the development of reaction engineering models for improved process performance and operation.

  3. Physics and Chemistry of Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1 Physics and Chemistry of Materials Developing new science and technologies needed for ... Fundamental and applied theoretical research on the physics and chemistry of materials The ...

  4. Moderator Chemistry Program

    SciTech Connect (OSTI)

    Dewitt, L.V.; Gibbs, A.; Lambert, D.P.; Bohrer, S.R.; Fanning, R.L.; Houston, M.W.; Stinson, S.L.; Deible, R.W.; Abdel-Khalik, S.I.

    1990-11-01

    Over the past fifteen months, the Systems Chemistry Group of the Reactor Engineering Department has undertaken a comprehensive study of the Department`s moderator chemistry program at Savannah River Site (SRS). An internal review was developed to formalize and document this program. Objectives were as outlined in a mission statement and action plan. In addition to the mission statement and action plan, nine separate task reports have been issued during the course of this study. Each of these task reports is included in this document as a chapter. This document is an organized compilation of the individual reports issued by the Systems Chemistry Group in assessment of SRS moderator chemistry to determine if there were significant gaps in the program as ft existed in October, 1989. While these reviews found no significant gaps in that mode of operation, or any items that adversely affected safety, items were identified that could be improved. Many of the items have already been dear with or are in the process of completion under this Moderator Chemistry Program and other Reactor Restart programs. A complete list of the items of improvement found under this assessment is found in Chapter 9, along with a proposed time table for correcting remaining items that can be improved for the chemistry program of SRS reactors. An additional external review of the moderator chemistry processes, recommendations, and responses to/from the Reactor Corrosion Mitigation Committee is included as Appendix to this compilation.

  5. Moderator Chemistry Program

    SciTech Connect (OSTI)

    Dewitt, L.V.; Gibbs, A.; Lambert, D.P.; Bohrer, S.R.; Fanning, R.L.; Houston, M.W.; Stinson, S.L.; Deible, R.W.; Abdel-Khalik, S.I.

    1990-11-01

    Over the past fifteen months, the Systems Chemistry Group of the Reactor Engineering Department has undertaken a comprehensive study of the Department's moderator chemistry program at Savannah River Site (SRS). An internal review was developed to formalize and document this program. Objectives were as outlined in a mission statement and action plan. In addition to the mission statement and action plan, nine separate task reports have been issued during the course of this study. Each of these task reports is included in this document as a chapter. This document is an organized compilation of the individual reports issued by the Systems Chemistry Group in assessment of SRS moderator chemistry to determine if there were significant gaps in the program as ft existed in October, 1989. While these reviews found no significant gaps in that mode of operation, or any items that adversely affected safety, items were identified that could be improved. Many of the items have already been dear with or are in the process of completion under this Moderator Chemistry Program and other Reactor Restart programs. A complete list of the items of improvement found under this assessment is found in Chapter 9, along with a proposed time table for correcting remaining items that can be improved for the chemistry program of SRS reactors. An additional external review of the moderator chemistry processes, recommendations, and responses to/from the Reactor Corrosion Mitigation Committee is included as Appendix to this compilation.

  6. Kinetics of heavy oil/coal coprocessing

    SciTech Connect (OSTI)

    Szladow, A.J.; Chan, R.K.; Fouda, S.; Kelly, J.F. )

    1988-01-01

    A number of studies have been reported on coprocessing of coal and oil sand bitumen, petroleum residues and distillate fractions in catalytic and non-catalytic processes. The studies described the effects of feedstock characteristics, process chemistry and operating variables on the product yield and distribution; however, very few kinetic data were reported in these investigations. This paper presents the kinetic data and modeling of the CANMET coal/heavy oil coprocessing process. A number of reaction networks were evaluated for CANMET coprocessing. The final choice of model was a parallel model with some sequential characteristics. The model explained 90.0 percent of the total variance, which was considered satisfactory in view of the difficulties of modeling preasphaltenes. The models which were evaluated showed that the kinetic approach successfully applied to coal liquefaction and heavy oil upgrading can be also applied to coprocessing. The coal conversion networks and heavy oil upgrading networks are interrelated via the forward reaction paths of preasphaltenes, asphaltenes, and THFI and via the reverse kinetic paths of an adduct formation between preasphaltenes and heavy oil.

  7. Seawater Chemistry Package

    Energy Science and Technology Software Center (OSTI)

    2005-11-23

    SeaChem Seawater Chemistry package provides routines to calculate pH, carbonate chemistry, density, and other quantities for seawater, based on the latest community standards. The chemistry is adapted from fortran routines provided by the OCMIP3/NOCES project, details of which are available at http://www.ipsl.jussieu.fr/OCMIP/. The SeaChem package can generate Fortran subroutines as well as Python wrappers for those routines. Thus the same code can be used by Python or Fortran analysis packages and Fortran ocean models alike.

  8. DOE fundamentals handbook: Chemistry

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The Chemistry Handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of chemistry. The handbook includes information on the atomic structure of matter; chemical bonding; chemical equations; chemical interactions involved with corrosion processes; water chemistry control, including the principles of water treatment; the hazards of chemicals and gases, and basic gaseous diffusion processes. This information will provide personnel with a foundation for understanding the chemical properties of materials and the way these properties can impose limitations on the operation of equipment and systems.

  9. ALS Chemistry Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    To Gain Access to the ALS Chemistry Labs Complete the online course: EHS0348 Chemical Hygiene and Safety. Use the non-LDAP login and enter your badge number (if you have one) as...

  10. Detection of rare earth elements in Powder River Basin sub-bituminous...

    Office of Scientific and Technical Information (OSTI)

    Report Number(s): NETL-PUB--20051 Journal ID: ISSN 0016-2361 Resource ... Language: English Subject: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY Rare earth elements; ...

  11. SC e-journals, Chemistry

    Office of Scientific and Technical Information (OSTI)

    Biogeochemistry Bioinorganic Chemistry and Applications - OAJ Biometals Biopolymers Bioresource Technology Bioscience Reports Biotechnology Advances Biotechnology ...

  12. Upgrading heavy gas oils

    SciTech Connect (OSTI)

    Ferguson, S.; Reese, D.D.

    1986-05-20

    A method is described of neutralizing the organic acidity in heavy gas oils to produce a neutralization number less than 1.0 whereby they are rendered suitable as lube oil feed stocks which consists essentially of treating the heavy gas oils with a neutralizing amount of monoethanolamine to form an amine salt with the organic acids and then heating the thus-neutralized heavy gas oil at a temperature at least about 25/sup 0/F greater than the boiling point of water and for a time sufficient to convert the amine salts to amides.

  13. Chemistry Division annual progress report for period ending April 30, 1993

    SciTech Connect (OSTI)

    Poutsma, M.L.; Ferris, L.M.; Mesmer, R.E.

    1993-08-01

    The Chemistry Division conducts basic and applied chemical research on projects important to DOE`s missions in sciences, energy technologies, advanced materials, and waste management/environmental restoration; it also conducts complementary research for other sponsors. The research are arranged according to: coal chemistry, aqueous chemistry at high temperatures and pressures, geochemistry, chemistry of advanced inorganic materials, structure and dynamics of advanced polymeric materials, chemistry of transuranium elements and compounds, chemical and structural principles in solvent extraction, surface science related to heterogeneous catalysis, photolytic transformations of hazardous organics, DNA sequencing and mapping, and special topics.

  14. Process for removing heavy metal compounds from heavy crude oil

    DOE Patents [OSTI]

    Cha, Chang Y.; Boysen, John E.; Branthaver, Jan F.

    1991-01-01

    A process is provided for removing heavy metal compounds from heavy crude oil by mixing the heavy crude oil with tar sand; preheating the mixture to a temperature of about 650.degree. F.; heating said mixture to up to 800.degree. F.; and separating tar sand from the light oils formed during said heating. The heavy metals removed from the heavy oils can be recovered from the spent sand for other uses.

  15. NREL: Transportation Research - Heavy-Duty Vehicle Thermal Management

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heavy-Duty Vehicle Thermal Management Infrared image of a semi cab and two people. NREL testing and modeling assess the energy saving impact of advanced climate control materials and equipment on heavy-duty vehicles. Photo by Dennis Schroeder, NREL Illustration of a truck with labeled energy-saving elements. NREL researchers assess the energy saving potential of films, paints, advanced insulation, micro-environmental design, and idle reduction technologies. Illustration by Ray David, NREL

  16. Thorium and Uranium: Elements of Opportunity in Actinide Organometalli...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Thorium and Uranium: Elements of Opportunity in Actinide Organometallic Chemistry January 12, 2016 11:00AM to 12:00PM Presenter Jaqueline L. Kiplinger, Los Alamos National...

  17. Some engineering properties of heavy concrete added silica fume

    SciTech Connect (OSTI)

    Akka?, Ay?e; Ba?yi?it, Celalettin; Esen, Serap

    2013-12-16

    Many different types of building materials have been used in building construction for years. Heavy concretes can be used as a building material for critical building as it can contain a mixture of many heavy elements. The barite itself for radiation shielding can be used and also in concrete to produce the workable concrete with a maximum density and adequate structural strength. In this study, some engineering properties like compressive strength, elasticity modules and flexure strength of heavy concretes added Silica fume have been investigated.

  18. FUEL ELEMENT

    DOE Patents [OSTI]

    Bean, R.W.

    1963-11-19

    A ceramic fuel element for a nuclear reactor that has improved structural stability as well as improved cooling and fission product retention characteristics is presented. The fuel element includes a plurality of stacked hollow ceramic moderator blocks arranged along a tubular raetallic shroud that encloses a series of axially apertured moderator cylinders spaced inwardly of the shroud. A plurality of ceramic nuclear fuel rods are arranged in the annular space between the shroud and cylinders of moderator and appropriate support means and means for directing gas coolant through the annular space are also provided. (AEC)

  19. CMR: Chemistry and Metallurgy Research Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CMR: Chemistry and Metallurgy Research Facility CMR: Chemistry and Metallurgy Research Facility The Los Alamos National Laboratory (LANL) Chemistry and Metallurgy Research (CMR)...

  20. Analytical Chemistry Laboratory | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry Laboratory provides a broad range of analytical chemistry support services to the scientific and engineering programs. AnalyticalChemistryLaboratoryfactsheet...

  1. Upgrading heavy oil using slurry processes

    SciTech Connect (OSTI)

    Del Bianco, A.; Panariti, N.; Marchionna, M.

    1995-11-01

    There is a growing interest in processes capable of converting heavy feedstocks (petroleum residues and heavy oils) into lower boiling products of high quality. The operational problems of upgrading heavy feeds relate to the presence of sulfur, nitrogen, metals, and considerable amounts of Conradson carbon residue. An efficient residue conversion process must be able to reduce the molecular weight of the feedstocks to material with boiling points below 550 C, increase the H-to-C ratio of the refined product, and remove heteroatoms and metals. Whereas the molecular weight reduction is normally achieved by C-C bond cracking above 400 C, often in the presence of acid catalysts, a higher H-to-C ratio can be obtained by either the rejection of carbon (as in coking) or the addition of hydrogen (as in hydrogenation processes). Slurry processes combine the flexibility of the carbon rejection with the high performance of the hydrogen addition processes. The origin of slurry processes is the Bergius-Pier technology (1920--1930) for the conversion of heavy oils and coal into distillates. Whereas the original Bergius-Pier technology did not use a catalyst, small amounts of inexpensive additives or finely dispersed hydrogenation catalysts can be used to increase the rates of the desired reactions. Catalysts can also inhibit coke formation by physically interfering with the coalescence of mesophase, which is the precursor of solid coke. Catalysts are used to reduce the severity of the process and to improve the quality of the products. Most of the research carried out in the past decade in the field of slurry processes has dealt with the identification of more effective and/or less expensive catalysts and the technological problems related to their use. Here the authors discuss both subjects, describing the path from the fundamental chemistry of dispersed catalytic systems to the development and initial commercialization of slurry processes.

  2. Heavy-element fission barriers Moeller, Peter; Sierk, Arnold...

    Office of Scientific and Technical Information (OSTI)

    Advanced Science Research Center, Japan Atomic Energy Agency (JAEA), Tokai-mura, Naka-gun, Ibaraki 319-1195 (Japan); Bengtsson, Ragnar; Uhrenholt, Henrik; Angstromberg, Sven...

  3. Magic nuclei unlock the secrets of heavy elements

    ScienceCinema (OSTI)

    Jones, Kate

    2014-08-13

    Kate Jones, an assistant professor at the University of Tennessee, describes her inquiries into the behavior of the somewhat enigmatic isotope tin-132.

  4. RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; NUCLEAR MEDICINE; HISTORICAL

    Office of Scientific and Technical Information (OSTI)

    The early days Richards, P. 38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY; NUCLEAR MEDICINE; HISTORICAL ASPECTS; TECHNETIUM 99; COLLOIDS; MOLYBDENUM...

  5. High Pressure Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Pressure Chemistry - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced

  6. High Temperature Aqueous Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Accurate knowledge of aqueous chemistry at high temperatures and pressures is important in many applications including nuclear waste disposal and energy extraction. Sandia's Defense Waste Management Programs is equipped with a state-of-the-art hydrothermal experimental system that allows us to obtain high quality kinetic and equilibrium data at temperatures and pressures of interest up to 600 o C and 1,000 bars (100 MPa). This state-of-the-art hydrothermal experimental system includes the

  7. Chemistry of Autoignition

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of Autoignition - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  8. Extensible Computational Chemistry Environment

    Energy Science and Technology Software Center (OSTI)

    2012-08-09

    ECCE provides a sophisticated graphical user interface, scientific visualization tools, and the underlying data management framework enabling scientists to efficiently set up calculations and store, retrieve, and analyze the rapidly growing volumes of data produced by computational chemistry studies. ECCE was conceived as part of the Environmental Molecular Sciences Laboratory construction to solve the problem of researchers being able to effectively utilize complex computational chemistry codes and massively parallel high performance compute resources. Bringing themore » power of these codes and resources to the desktops of researcher and thus enabling world class research without users needing a detailed understanding of the inner workings of either the theoretical codes or the supercomputers needed to run them was a grand challenge problem in the original version of the EMSL. ECCE allows collaboration among researchers using a web-based data repository where the inputs and results for all calculations done within ECCE are organized. ECCE is a first of kind end-to-end problem solving environment for all phases of computational chemistry research: setting up calculations with sophisticated GUI and direct manipulation visualization tools, submitting and monitoring calculations on remote high performance supercomputers without having to be familiar with the details of using these compute resources, and performing results visualization and analysis including creating publication quality images. ECCE is a suite of tightly integrated applications that are employed as the user moves through the modeling process.« less

  9. Programmatic Elements

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2007-07-11

    The Guide provides acceptable methods of meeting the requirements of DOE O 151.1C for programmatic elements that sustain the emergency management program and maintain the readiness of the program to respond to an emergency. Supersedes DOE G 151.1-1, Volume 5-1, DOE G 151.1-1, Volume 5-2, DOE G 151.1-1, Volume 5-3, DOE G 151.1-1, Volume 5-4, DOE G 151.1-1, Volume 7-1, and DOE G 151.1-1, Volume 7-3.

  10. SECTION II: HEAVY ION REACTIONS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    II: HEAVY ION REACTIONS Experimental Determination of the Symmetry Energy of a Low Density Nuclear Gas ......II-1 S. ...

  11. Process for upgrading heavy oils

    SciTech Connect (OSTI)

    LePage, J.F.; Marlino, G.

    1983-07-05

    The viscosity of heavy oils is reduced in order to facilitate pipe line transportation thereof. A fraction of the heavy oil is deasphalted in the presence of C/sub 5/-C/sub 7/ hydrocarbons, a portion of the separated asphalt is converted to synthesis gas, at least a portion of said gas is used to manufacture an alcohol mixture including methanol and C/sub 2/ to C/sub 10/ alcohols, which mixture is admixed with the heavy oil before transportation thereof. This procedure is more beneficial to the transported heavy oil than the prior processes which do not comprise the conversion of the asphalt fraction of the heavy oil.

  12. Isotope and Nuclear Chemistry Division annual report FY 1986, October 1985-September 1986

    SciTech Connect (OSTI)

    Heiken, J.H.

    1987-06-01

    This report describes progress in the major research and development programs carried out in FY 1986 by the Isotope and Nuclear Chemistry Division. The report includes articles on radiochemical diagnostics and weapons tests; weapons radiochemical diagnostics research and development; other unclassified weapons research; stable and radioactive isotope production and separation; chemical biology and nuclear medicine; element and isotope transport and fixation; actinide and transition metal chemistry; structural chemistry, spectroscopy, and applications; nuclear structure and reactions; irradiation facilities; advanced concepts and technology; and atmospheric chemistry.

  13. Response Elements

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2007-07-11

    The Guide provides acceptable methods for meeting the requirement of DOE O 151.1C for response elements that respond or contribute to response as needed in an emergency. Supersedes DOE G 151.1-1, Volume 3-1, DOE G 151.1-1, Volume 3-2, DOE G 151.1-1, Volume 3-3, DOE G 151.1-1, Volume 3-4, DOE G 151.1-1, Volume 4-1, DOE G 151.1-1, Volume 4-2, DOE G 151.1-1, Volume 4-3, DOE G 151.1-1, Volume 4-4, DOE G 151.1-1, Volume 4-5, and DOE G 151.1-1, Volume 4-6.

  14. Heavy Vehicle Propulsion Materials

    SciTech Connect (OSTI)

    Ray Johnson

    2000-01-31

    The objectives are to Provide Key Enabling Materials Technologies to Increase Energy Efficiency and Reduce Exhaust Emissions. The following goals are listed: Goal 1: By 3rd quarter 2002, complete development of materials enabling the maintenance or improvement of fuel efficiency {ge} 45% of class 7-8 truck engines while meeting the EPA/Justice Department ''Consent Decree'' for emissions reduction. Goal 2: By 4th quarter 2004, complete development of enabling materials for light-duty (class 1-2) diesel truck engines with efficiency over 40%, over a wide range of loads and speeds, while meeting EPA Tier 2 emission regulations. Goal 3: By 4th quarter 2006, complete development of materials solutions to enable heavy-duty diesel engine efficiency of 50% while meeting the emission reduction goals identified in the EPA proposed rule for heavy-duty highway engines.''

  15. Utah Heavy Oil Program

    SciTech Connect (OSTI)

    J. Bauman; S. Burian; M. Deo; E. Eddings; R. Gani; R. Goel; C.K. Huang; M. Hogue; R. Keiter; L. Li; J. Ruple; T. Ring; P. Rose; M. Skliar; P.J. Smith; J.P. Spinti; P. Tiwari; J. Wilkey; K. Uchitel

    2009-10-20

    The Utah Heavy Oil Program (UHOP) was established in June 2006 to provide multidisciplinary research support to federal and state constituents for addressing the wide-ranging issues surrounding the creation of an industry for unconventional oil production in the United States. Additionally, UHOP was to serve as an on-going source of unbiased information to the nation surrounding technical, economic, legal and environmental aspects of developing heavy oil, oil sands, and oil shale resources. UHOP fulGilled its role by completing three tasks. First, in response to the Energy Policy Act of 2005 Section 369(p), UHOP published an update report to the 1987 technical and economic assessment of domestic heavy oil resources that was prepared by the Interstate Oil and Gas Compact Commission. The UHOP report, entitled 'A Technical, Economic, and Legal Assessment of North American Heavy Oil, Oil Sands, and Oil Shale Resources' was published in electronic and hard copy form in October 2007. Second, UHOP developed of a comprehensive, publicly accessible online repository of unconventional oil resources in North America based on the DSpace software platform. An interactive map was also developed as a source of geospatial information and as a means to interact with the repository from a geospatial setting. All documents uploaded to the repository are fully searchable by author, title, and keywords. Third, UHOP sponsored Give research projects related to unconventional fuels development. Two projects looked at issues associated with oil shale production, including oil shale pyrolysis kinetics, resource heterogeneity, and reservoir simulation. One project evaluated in situ production from Utah oil sands. Another project focused on water availability and produced water treatments. The last project considered commercial oil shale leasing from a policy, environmental, and economic perspective.

  16. Retrofitting heavy oil processes

    SciTech Connect (OSTI)

    Hamilton, G.L.; Fitzgerald, M.; D'Amico, V.

    1986-01-01

    Refiners, faced with the need to process the bottom end of the heavy high sulfur crude oil barrel in today's uncertain economic environment, are reluctant to commit large amounts of money to expensive upgrading processes. In order to conserve scarce capital while improving operating margins, additional valuable products can be produced by retrofits such as conversion of an idle crude unit to visbreaking, delayed coking or deasphalting service, or conversion of hydrodesulfurizers to mild hydrocracking.

  17. Viscous heavy brines

    SciTech Connect (OSTI)

    House, R.F.; Hoover, L.D.

    1984-07-10

    Hydroxyethyl cellulose and a sequestrant are added to a heavy brine containing one or more salts selected from calcium chloride, calcium bromide, and zinc bromide to increase the viscosity of the brine. Preferably the brine contains zinc bromide, has a density in the range from about 14.2-19.2 pounds per gallon, and the sequestrant is a polyphosphonic acid or water soluble salt thereof.

  18. Henry Taube and Coordination Chemistry

    Office of Scientific and Technical Information (OSTI)

    Henry Taube and Coordination Chemistry Resources with Additional Information Henry Taube Chuck Painter/Stanford News Service Henry Taube, a Marguerite Blake Wilbur Professor of Chemistry, Emeritus, at Stanford University, received the 1983 Nobel Prize in Chemistry "for his work on the mechanisms of electron transfer reactions, especially in metal complexes" Taube 'received a doctorate from the University of California-Berkeley in 1940 and was an instructor there from 1940-41. "I

  19. Synthetic and Mechanistic Chemistry publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Synthetic and Mechanistic Chemistry » Synthetic and Mechanistic Synthetic and Mechanistic publications Research into alternative forms of energy, especially energy security, is one of the major national security imperatives of this century. Get Expertise Dave Thorn Chemistry Program Manager Email Josh Smith Chemistry Communications Email "Research into alternative forms of energy, of which biofuels is a key component, is one of the major national security imperatives of this century.

  20. Chemistry and Material Sciences Applications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry and Material Sciences Applications Chemistry and Material Sciences Applications June 26, 2012 Jack Zhengji NERSC Training Event 09:00 - 12:00 PST June 26, 2012 Concurrently presented on the web and at NERSC's Oakland Scientific Facility Attendance: 45 Chemistry and Material Sciences Applications Zhengji Zhao, NERSC User Services Group Jack Deslippe, NERSC User Services Group The first hour of the training is targeted at beginners. We will show you how to get started running material

  1. Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Vehicle Technologies Office Merit Review 2014: Heavy-Duty Low-Temperature and Diesel ...

  2. Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Vehicle Technologies Office Merit Review 2014: Heavy-Duty ...

  3. Heavy Truck Engine Program

    SciTech Connect (OSTI)

    Nelson, Christopher

    2009-01-08

    The Heavy Duty Truck Engine Program at Cummins embodied three significant development phases. All phases of work strove to demonstrate a high level of diesel engine efficiency in the face of increasingly stringent emission requirements. Concurrently, aftertreatment system development and refinement was pursued in support of these efficiency demonstrations. The program's first phase focused on the demonstration in-vehicle of a high level of heavy duty diesel engine efficiency (45% Brake Thermal Efficiency) at a typical cruise condition while achieving composite emissions results which met the 2004 U.S. EPA legislated standards. With a combination of engine combustion calibration tuning and the development and application of Urea-based SCR and particulate aftertreatment, these demonstrations were successfully performed by Q4 of 2002. The second phase of the program directed efforts towards an in-vehicle demonstration of an engine system capable of meeting 2007 U.S. EPA legislated emissions requirements while achieving 45% Brake Thermal Efficiency at cruise conditions. Through further combustion optimization, the refinement of Cummins Cooled EGR architecture, the application of a high pressure common rail fuel system and the incorporation of optimized engine parasitics, Cummins Inc. successfully demonstrated these deliverables in Q2 of 2004. The program's final phase set a stretch goal of demonstrating 50% Brake Thermal Efficiency from a heavy duty diesel engine system capable of meeting 2010 U.S. EPA legislated emissions requirements. Cummins chose to pursue this goal through further combustion development and refinement of the Cooled EGR system architecture and also applied a Rankine cycle Waste Heat Recovery technique to convert otherwise wasted thermal energy to useful power. The engine and heat recovery system was demonstrated to achieve 50% Brake Thermal Efficiency while operating at a torque peak condition in second quarter, 2006. The 50% efficient engine system was capable of meeting 2010 emissions requirements through the application of NOx and particulate matter reduction techniques proven earlier in the program.

  4. INL '@work' heavy equipment mechanic

    SciTech Connect (OSTI)

    Christensen, Cad

    2008-01-01

    INL's Cad Christensen is a heavy equipment mechanic. For more information about INL careers, visit http://www.facebook.com/idahonationallaboratory.

  5. INL '@work' heavy equipment mechanic

    ScienceCinema (OSTI)

    Christensen, Cad

    2013-05-28

    INL's Cad Christensen is a heavy equipment mechanic. For more information about INL careers, visit http://www.facebook.com/idahonationallaboratory.

  6. Chemistry for Measurement and Detection Science publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry for Measurement and Detection Science » Chemistry for Measurement and Detection Science publications Chemistry for Measurement and Detection Science publications Research into alternative forms of energy, especially energy security, is one of the major national security imperatives of this century. Get Expertise Randy Drake Actinide Analytical Chemistry Email Kirk Rector Physical Chemistry & Applied Spectroscopy Email Josh Smith Chemistry Communications Email Los Alamos is one of

  7. Solubilities of heavy fossil fuels in compressed gases

    SciTech Connect (OSTI)

    Monge, A. Jr.

    1982-01-01

    Design of processes for upgrading heavy fossil fuels such as coal-derived liquids, heavy petroleum fractions, tar sands, and shale oil, requires quantitative information for equilibrium properties of the fossil fuel in the presence of compressed light gases at elevated temperatures. Presented here are methods to predict and measure solubilities of heavy fossil fuels in compressed gases in the region ambient to 100 bar and 600 K. A molecular-thermodynamic model is used to predict heavy fossil-fuel solubilities. The heavy fuel is fractionated ina spinning-band column at low pressure and high reflux; each fraction is considered to be a pseudo-component. Each fraction is characterized by one vapor-pressure datum (obtained during fractionation), elemental analysis, and proton-NMR spectra (to determine aromaticity). Liquid-phase properties are obtained from the SWAP equation for vapor pressure and from a density correlation. Vapor-phase properties are obtained using the virial equation of state with virial coefficients from Kaul's correlation. The molecular-thermodynamic model has been used to establish a design-oriented computer program for calculating heavy, fossil-fuel solubility for general application in process design and, in particular, for isobaric condensation as a function of temperature as required for design of a continuous-flow heat exchanger. A total-vaporization technique is used to measure the solubilities of narrow-boiling, heavy fossil-fuel fractions in compressed gases. The solubility of a heavy fraction is determined from the volume of gas required to vaporize completely a small, measured mass of fossil-fuel sample. To test the molecular-thermodynamic model, the total-vaporization technique has been used to measure the solubilities of two Lurgi coal-tar fractions in compressed methane. Predicted and experimental solubilities agree well.

  8. Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty ...

  9. APBF-DEC Heavy Duty NOx Adsorber/DPF Project: Heavy Duty Linehaul...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy Duty NOx AdsorberDPF Project: Heavy Duty Linehaul Platform Project Update APBF-DEC Heavy Duty NOx AdsorberDPF Project: Heavy Duty Linehaul Platform Project Update 2003 DEER ...

  10. Chemistry and Material Sciences Codes at NERSC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry and Material Sciences Codes Chemistry and Material Sciences Codes at NERSC April 6, 2011 Last edited: 2016-04-29 11:35:1

  11. Martin Karplus Wins Nobel Prize in Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Home News & Publications NERSC News Center News Martin Karplus Wins Nobel Prize in Chemistry Martin Karplus Wins Nobel Prize in Chemistry October 9, 2013 Contact: Linda...

  12. Conversion of heavy hydrocarbon oils

    SciTech Connect (OSTI)

    Chen, N.Y.; Pelrine, B.P.; Yan, T.Y.

    1982-12-14

    This invention provides a process for upgrading a heavy hydrocarbon oil to motor fuel products. The heavy hydrocarbon oil is admixed with a metal halide catalyst and a solvent component under supercritical conditions to form (1) a dense-gas solvent phase which contains refined hydrocarbon crackate, and which is substantially free of metal halide catalyst content; and (2) a residual asphaltic phase.

  13. Advances in heavy oil hydroprocessing

    SciTech Connect (OSTI)

    Mendizabal, O.B. )

    1988-06-01

    The world increase in heavy crudes has forced refiners to develop different processes that upgrade the yields and product properties recovered from these crudes. However, some of the optimized and new processes are not able to handle whole heavy crude oils, due to the high viscosity and corrosion of their long and short residues. The different processes for heavy crudes can be classified in two areas: physical (vg. Liquid Extraction) and chemical processes. The catalytic hydrotreating process, which belongs to this last classification, has demonstrated to be an economical upgrading process for heavy crude oil. This paper describes the development by the Mexican Petroleum Institute of the process to hydrotreat maya heavy crude. The effect of the operating conditions, the catalyst ---- development and the technical - economical analysis are presented. The product properties and yields are compared with the results obtained with light crude oil like isthmus.

  14. Overview of actinide chemistry in the WIPP

    SciTech Connect (OSTI)

    Borkowski, Marian; Lucchini, Jean - Francois; Richmann, Michael K; Reed, Donald T; Khaing, Hnin; Swanson, Juliet

    2009-01-01

    The year 2009 celebrates 10 years of safe operations at the Waste Isolation Pilot Plant (WIPP), the only nuclear waste repository designated to dispose defense-related transuranic (TRU) waste in the United States. Many elements contributed to the success of this one-of-the-kind facility. One of the most important of these is the chemistry of the actinides under WIPP repository conditions. A reliable understanding of the potential release of actinides from the site to the accessible environment is important to the WIPP performance assessment (PA). The environmental chemistry of the major actinides disposed at the WIPP continues to be investigated as part of the ongoing recertification efforts of the WIPP project. This presentation provides an overview of the actinide chemistry for the WIPP repository conditions. The WIPP is a salt-based repository; therefore, the inflow of brine into the repository is minimized, due to the natural tendency of excavated salt to re-seal. Reducing anoxic conditions are expected in WIPP because of microbial activity and metal corrosion processes that consume the oxygen initially present. Should brine be introduced through an intrusion scenario, these same processes will re-establish reducing conditions. In the case of an intrusion scenario involving brine, the solubilization of actinides in brine is considered as a potential source of release to the accessible environment. The following key factors establish the concentrations of dissolved actinides under subsurface conditions: (1) Redox chemistry - The solubility of reduced actinides (III and IV oxidation states) is known to be significantly lower than the oxidized forms (V and/or VI oxidation states). In this context, the reducing conditions in the WIPP and the strong coupling of the chemistry for reduced metals and microbiological processes with actinides are important. (2) Complexation - For the anoxic, reducing and mildly basic brine systems in the WIPP, the most important inorganic complexants are expected to be carbonate/bicarbonate and hydroxide. There are also organic complexants in TRU waste with the potential to strongly influence actinide solubility. (3) Intrinsic and pseudo-actinide colloid formation - Many actinide species in their expected oxidation states tend to form colloids or strongly associate with non actinide colloids present (e.g., microbial, humic and organic). In this context, the relative importance of actinides, based on the TRU waste inventory, with respect to the potential release of actinides from the WIPP, is greater for plutonium and americium, and to less extent for uranium and thorium. The most important oxidation states for WIPP-relevant conditions are III and IV. We will present an update of the literature on WIPP-specific data, and a summary of the ongoing research related to actinide chemistry in the WIPP performed by the Los Alamos National Laboratory (LANL) Actinide Chemistry and Repository Science (ACRSP) team located in Carlsbad, NM [Reed 2007, Lucchini 2007, and Reed 2006].

  15. National Nuclear Chemistry Summer School

    Broader source: Energy.gov [DOE]

    The Division of Nuclear Chemistry and Technology of the American Chemical Society (ACS) is sponsoring two INTENSIVE six-week Summer Schools in Nuclear and Radiochemistry for undergraduates. Funding is provided by the US Department of Energy.

  16. Hot atom chemistry and radiopharmaceuticals

    SciTech Connect (OSTI)

    Krohn, Kenneth A.; Moerlein, Stephen M.; Link, Jeanne M.; Welch, Michael J.

    2012-12-19

    The chemical products made in a cyclotron target are a combined result of the chemical effects of the nuclear transformation that made the radioactive atom and the bulk radiolysis in the target. This review uses some well-known examples to understand how hot atom chemistry explains the primary products from a nuclear reaction and then how radiation chemistry is exploited to set up the optimal product for radiosynthesis. It also addresses the chemical effects of nuclear decay. There are important principles that are common to hot atom chemistry and radiopharmaceutical chemistry. Both emphasize short-lived radionuclides and manipulation of high specific activity nuclides. Furthermore, they both rely on radiochromatographic separation for identification of no-carrieradded products.

  17. National Nuclear Chemistry Summer School

    Broader source: Energy.gov [DOE]

    he Division of Nuclear Chemistry and Technology of the American Chemical Society (ACS) is sponsoring two INTENSIVE six-week Summer Schools in Nuclear and Radiochemistry for undergraduates. Funding...

  18. Chemistry, Life, and Earth Sciences

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ADCLES Chemistry, Life, and Earth Sciences The CLES Directorate is home to world class capabilities in chemistry, bioscience, and earth and environmental sciences. Structural protein research Structural protein research A wide range of protein folding research Field Instrument Deployments and Operations (FIDO) Field Instrument Deployments and Operations (FIDO) Atmospheric science research Quantum Dots Quantum Dots Quantum dot research for energy and light Contact Us Associate Director Nan Sauer

  19. Heavy Isotopes Lead Materials Management Organization (LMMO)...

    Office of Scientific and Technical Information (OSTI)

    Heavy Isotopes Lead Materials Management Organization (LMMO) Update Citation Details In-Document Search Title: Heavy Isotopes Lead Materials Management Organization (LMMO) Update ...

  20. Studies of Flerovium and Element 115 Homologs with Macrocyclic Extractants

    SciTech Connect (OSTI)

    Despotopulos, John D.

    2015-03-12

    Study of the chemistry of the heaviest elements, Z ≥ 104, poses a unique challenge due to their low production cross-sections and short half-lives. Chemistry also must be studied on the one-atom-at-a-time scale, requiring automated, fast, and very efficient chemical schemes. Recent studies of the chemical behavior of copernicium (Cn, element 112) and flerovium (Fl, element 114) together with the discovery of isotopes of these elements with half-lives suitable for chemical studies have spurred a renewed interest in the development of rapid systems designed to study the chemical properties of elements with Z ≥ 114. This dissertation explores both extraction chromatography and solvent extraction as methods for development of a rapid chemical separation scheme for the homologs of flerovium (Pb, Sn, Hg) and element 115 (Bi, Sb), with the goal of developing a chemical scheme that, in the future, can be applied to on-line chemistry of both Fl and element 115. Macrocyclic extractants, specifically crown ethers and their derivatives, were chosen for these studies.

  1. New Technique Gives a Deeper Look into the Chemistry of Interfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Technique Gives a Deeper Look into the Chemistry of Interfaces New Technique Gives a Deeper Look into the Chemistry of Interfaces Print Monday, 23 February 2015 10:48 A new technique developed at the ALS offers sub-nanometer depth resolution of every chemical element to be found at heterogeneous interfaces, such as those in batteries and fuel cells. The technique, Standing-Wave Ambient-Pressure Photoelectron Spectroscopy (SWAPPS), combines standing-wave photoelectron spectroscopy (SWPS) with

  2. Chemistry for Measurement and Detection Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry for Measurement and Detection Science Chemistry for Measurement and Detection Science Research into alternative forms of energy, especially energy security, is one of the major national security imperatives of this century. Get Expertise Randy Drake Actinide Analytical Chemistry Email Kirk Rector Physical Chemistry & Applied Spectroscopy Email Josh Smith Chemistry Communications Email Los Alamos is one of two FBI "hub" laboratories for analyzing bulk special nuclear

  3. Discrete Element Modeling

    SciTech Connect (OSTI)

    Morris, J; Johnson, S

    2007-12-03

    The Distinct Element Method (also frequently referred to as the Discrete Element Method) (DEM) is a Lagrangian numerical technique where the computational domain consists of discrete solid elements which interact via compliant contacts. This can be contrasted with Finite Element Methods where the computational domain is assumed to represent a continuum (although many modern implementations of the FEM can accommodate some Distinct Element capabilities). Often the terms Discrete Element Method and Distinct Element Method are used interchangeably in the literature, although Cundall and Hart (1992) suggested that Discrete Element Methods should be a more inclusive term covering Distinct Element Methods, Displacement Discontinuity Analysis and Modal Methods. In this work, DEM specifically refers to the Distinct Element Method, where the discrete elements interact via compliant contacts, in contrast with Displacement Discontinuity Analysis where the contacts are rigid and all compliance is taken up by the adjacent intact material.

  4. Heavy-ion Fusion Reactions with Neutron-rich Radioactive Ion Beams

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heavy-ion Fusion Reactions with Neutron-rich Radioactive Ion Beams A. Wakhle National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, Michigan 48824, USA The predicted shell closures forming the 'island of stability' [1-2] are beyond the reach of stable beams [3]. This dictates that future efforts towards the synthesis of super-heavy elements (SHEs) [4] must utilize neutron-rich radioactive ion beams (RIBs). The low intensities of RIBs puts this goal beyond the

  5. Atmospheric Chemistry and Air Pollution

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gaffney, Jeffrey S.; Marley, Nancy A.

    2003-01-01

    Atmospheric chemistry is an important discipline for understanding air pollution and its impacts. This mini-review gives a brief history of air pollution and presents an overview of some of the basic photochemistry involved in the production of ozone and other oxidants in the atmosphere. Urban air quality issues are reviewed with a specific focus on ozone and other oxidants, primary and secondary aerosols, alternative fuels, and the potential for chlorine releases to amplify oxidant chemistry in industrial areas. Regional air pollution issues such as acid rain, long-range transport of aerosols and visibility loss, and the connections of aerosols to ozonemore » and peroxyacetyl nitrate chemistry are examined. Finally, the potential impacts of air pollutants on the global-scale radiative balances of gases and aerosols are discussed briefly.« less

  6. Role of inorganic chemistry on nuclear energy examined

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Role of inorganic chemistry on nuclear energy examined Role of inorganic chemistry on nuclear energy examined Inorganic chemistry can provide insight and improve technical issues ...

  7. Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Peer Evaluation PDF icon ace001musculus2011o.pdf More Documents & Publications Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Heavy-Duty ...

  8. Appendix C Analytical Chemistry Data

    Office of Legacy Management (LM)

    Analytical Chemistry Data This page intentionally left blank Contents Section Analytical Data for Deleted Contaminants of Concern ............................................................. C1.O Mol~tezuma Creek Hardness Dat Surface Water Copper Data Summa ................ CI-9 Surface Water Radium-228 Dat Surface Water Radon-222 Data Summary ....................... ....................................... . . . . . . . . . . . C l - I 2 Alluvial Ground Water Aln~noniuu~ as Nitrogen Data

  9. Shell effects in fusion of heavy nuclei

    SciTech Connect (OSTI)

    Moeller, P.; Nix, J.R.

    1997-12-31

    The spontaneous-fission properties of Fm isotopes undergo dramatic changes between {sup 256}Fm and {sup 258} Fm. The fission fragments of the former isotope are mass asymmetric with kinetic energies of about 200 MeV, whereas the fission fragments of the latter isotope are symmetric with kinetic energies of about 235 MeV. This rapid change occurs because the division into nearly doubly magic fragments near {sup 132}Sn becomes possible and opens up new valleys in the fission potential-energy surface. In the cold-fusion reactions leading to the heaviest elements, the nearly doubly magic targets and/or projectiles may give rise to important features associated with this magicity. Cold fusion is thought to favor heavy-element formation because it leads to low excitation energies of the compound nuclei. We investigate how near-magic targets and projectiles may lead to persistent survivability of the shells in the fusion valley as the ions merge, in addition to their effect on the compound-nucleus excitation energy.

  10. Chemistry of Cobalt-Platinum Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of Cobalt-Platinum Nanocatalysts Chemistry of Cobalt-Platinum Nanocatalysts Print Monday, 25 February 2013 15:59 Bimetallic cobalt-platinum (CoPt) nanoparticles are...

  11. Upgrading of heavy hydrocarbonaceous feeds

    SciTech Connect (OSTI)

    Bhattacharya, A.K.; Storm, D.A.; DeRosa, T.F.

    1995-12-31

    This paper is based on our work in the area of upgrading of heavy hydrocarbonaceous feedstocks. The work involves the development of a method of catalytically hydroconverting a hydrocarbon feed stream containing a substantial quantity of components boiling above about 538{degrees}C to a substantial portion thereof to components boiling below 538{degrees}C. More particularly, an oil-miscible or oil-soluble poly(ether)diol or a derivative thereof and an aromatic additive oil, such as Heavy Cycle Gas oil, are added to a heavy hydrocarbon feed and the mixed stream is contacted at elevated temperatures with a solid catalyst such as a sulfided nickel molybdenum oxide on alumina in the presence of hydrogen under pressure. This method advantageously affords higher conversion to more valuable liquid products containing lower amounts of heteroatoms such as sulfur, substantially eliminates plugging of the hydroconversion reactor, and reduces the amount of insolubles in the total liquid product.

  12. George A. Olah, Carbocation and Hydrocarbon Chemistry

    Office of Scientific and Technical Information (OSTI)

    George A. Olah, Carbocation and Hydrocarbon Chemistry Resources with Additional Information * Patents George A. Olah Courtesy Rand Larson, Morningstar Productions George Olah received the 1994 Nobel Prize in Chemistry "for his contribution to carbocation chemistry" and his 'role in the chemistry of hydrocarbons. In particular, he developed superacids ... that are much stronger than ordinary acids, are non-nucleophilic, and are fluid at low temperatures. In such media ... carbocations

  13. Interfacial Chemistry and Engineering Annual Report 2000

    SciTech Connect (OSTI)

    Grate, Jay W.

    2001-08-01

    This annual report describes the research and staff accomplishments in 2000 for the EMSL Interfacial Chemistry and Engineering Directorate.

  14. Eleventh international symposium on radiopharmaceutical chemistry

    SciTech Connect (OSTI)

    1995-12-31

    This document contains abstracts of papers which were presented at the Eleventh International Symposium on Radiopharmaceutical Chemistry. Sessions included: radiopharmaceuticals for the dopaminergic system, strategies for the production and use of labelled reactive small molecules, radiopharmaceuticals for measuring metabolism, radiopharmaceuticals for the serotonin and sigma receptor systems, labelled probes for molecular biology applications, radiopharmaceuticals for receptor systems, radiopharmaceuticals utilizing coordination chemistry, radiolabelled antibodies, radiolabelling methods for small molecules, analytical techniques in radiopharmaceutical chemistry, and analytical techniques in radiopharmaceutical chemistry.

  15. CMR: Chemistry and Metallurgy Research Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CMR: Chemistry and Metallurgy Research Facility CMR: Chemistry and Metallurgy Research Facility The Los Alamos National Laboratory (LANL) Chemistry and Metallurgy Research (CMR) building supports research and experimental activities for plutonium and uranium analytical chemistry and metallurgy. CMR capabilities support a number of national security programs, such as non-proliferation and nuclear safeguards. The CMR Facility In 1952, the first LANL CMR facility was completed. At that time, the

  16. Martin Karplus Wins Nobel Prize in Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Home » News & Publications » NERSC News » Center News » Martin Karplus Wins Nobel Prize in Chemistry Martin Karplus Wins Nobel Prize in Chemistry October 9, 2013 Contact: Linda Vu, +1 510 495 2402, lvu@lbl.gov Karplus605v1.jpg Martin Karplus On Wednesday, the Nobel Prize in Chemistry was awarded to three scientists for pioneering methods in computational chemistry that have brought a deeper understanding of complex chemical structure and reactions in biochemical systems. These methods

  17. Upgrading Orinoco belt heavy oil

    SciTech Connect (OSTI)

    Alcantara, J.; Castillo, O.

    1982-09-01

    The Orinoco Heavy Oil Belt of Venezuela is a subsurface geological formation of petroleum-bearing sands that is approximately 700 km long and between 60 and 80 km wide. The results of recent explorations have shown the area to contain over one trillion barrels of oil in-place, ranging from 8/sup 0/ API to 14/sup 0/ APE gravity. In an effort to develop these resources, Petroleos de Venezuela has undertaken a program to evaluate and develop this heavy oil belt. The objectives of this program are discussed along with the process technology selection, pilot plants, and environmental protection measures. (JMT)

  18. Heavy Truck Engine Development & HECC | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications High Efficiency Clean Combustion for Heavy-Duty Engine High Efficiency Clean Combustion for Heavy-Duty Engine Heavy-Duty Engine Combustion ...

  19. Heaviest Nuclei: New Element with Atomic Number 117

    ScienceCinema (OSTI)

    Oganessian, Yuri [Flerov Laboratory of Nuclear Reactions, Russia and Joint Institute for Nuclear Research

    2010-09-01

    One of the fundamental outcomes of the nuclear shell model is the prediction of the 'stability islands' in the domain of the hypothetical super heavy elements. The talk is devoted to the experimental verification of these predictions - the synthesis and study of both the decay and chemical properties of the super heavy elements. The discovery of a new chemical element with atomic number Z=117 is reported. The isotopes 293117 and 294117 were produced in fusion reactions between 48Ca and 249Bk. Decay chains involving 11 new nuclei were identified by means of the Dubna gas-filled recoil separator. The measured decay properties show a strong rise of stability for heavier isotopes with Z =111, validating the concept of the long sought island of enhanced stability for heaviest nuclei.

  20. NEUTRONIC REACTOR CONTROL ELEMENT

    DOE Patents [OSTI]

    Beaver, R.J.; Leitten, C.F. Jr.

    1962-04-17

    A boron-10 containing reactor control element wherein the boron-10 is dispersed in a matrix material is describeri. The concentration of boron-10 in the matrix varies transversely across the element from a minimum at the surface to a maximum at the center of the element, prior to exposure to neutrons. (AEC)

  1. Final Report: Ionization chemistry of high temperature molecular...

    Office of Scientific and Technical Information (OSTI)

    Country of Publication: United States Language: English Subject: 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ACCURACY; CHEMICAL EXPLOSIVES; CHEMISTRY; EXPLOSIONS; ...

  2. Fragmentation production of triply heavy baryons at the CERN LHC

    SciTech Connect (OSTI)

    Nobary, M.A. Gomshi; Sepahvand, R.

    2005-02-01

    The triply heavy baryons in the standard model formed in direct c and b quark fragmentation are the {omega}{sub ccc}, {omega}{sub ccb}, {omega}{sub cbb} and {omega}{sub bbb} baryons. We calculate their fragmentation functions in leading order of perturbative QCD. The universal fragmentation probabilities fall within the range of 10{sup -5}-10{sup -7}.We also evaluate their cross section at the LHC ({radical}(s)=14 TeV) using next-to-leading order matrix elements for heavy quark-antiquark pair production. We present the differential cross sections as functions of the transverse momentum as well as the total cross sections. They range from a few nb to a few pb.

  3. The role of top in heavy flavor physics

    SciTech Connect (OSTI)

    Hewett, J.L.

    1997-01-01

    The implications of the massive top quark on heavy flavor transitions are explored. We review the generation of quark masses and mixings and the determination techniques, and present the status of the elements of the weak mixing matrix. Purely leptonic decays of heavy mesons are briefly summarized. We present a general introduction to flavor changing neutral currents and an extensive summary of radiative and other rare decay modes. The physics of neutral meson mixing is reviewed and applied to each meson system. We describe the phenomenology of CP violation and how it may be measured in meson decays. Standard Model predictions are given in each case and the effects of physics beyond the Standard Model are also discussed. Throughout, we contrast these transitions in the K and B meson systems to those in the D meson and top-quark sectors.

  4. Physical Chemistry and Applied Spectroscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    PCS Physical Chemistry and Applied Spectroscopy We perform basic and applied research in support of the Laboratory's national security mission and serve a wide range of customers. Contact Us Group Leader Kirk Rector Deputy Group Leader Jeff Pietryga Group Office (505) 667-7121 Postdoctoral researcher Young-Shin Park characterizing emission spectra of LEDs in the Los Alamos National Laboratory optical laboratory. Postdoctoral researcher Young-Shin Park characterizing emission spectra of LEDs in

  5. Journal of Physical Chemistry A

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Physical Chemistry A - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced

  6. IN-PACKAGE CHEMISTRY ABSTRACTION

    SciTech Connect (OSTI)

    E. Thomas

    2005-07-14

    This report was developed in accordance with the requirements in ''Technical Work Plan for Postclosure Waste Form Modeling'' (BSC 2005 [DIRS 173246]). The purpose of the in-package chemistry model is to predict the bulk chemistry inside of a breached waste package and to provide simplified expressions of that chemistry as a function of time after breach to Total Systems Performance Assessment for the License Application (TSPA-LA). The scope of this report is to describe the development and validation of the in-package chemistry model. The in-package model is a combination of two models, a batch reactor model, which uses the EQ3/6 geochemistry-modeling tool, and a surface complexation model, which is applied to the results of the batch reactor model. The batch reactor model considers chemical interactions of water with the waste package materials, and the waste form for commercial spent nuclear fuel (CSNF) waste packages and codisposed (CDSP) waste packages containing high-level waste glass (HLWG) and DOE spent fuel. The surface complexation model includes the impact of fluid-surface interactions (i.e., surface complexation) on the resulting fluid composition. The model examines two types of water influx: (1) the condensation of water vapor diffusing into the waste package, and (2) seepage water entering the waste package as a liquid from the drift. (1) Vapor-Influx Case: The condensation of vapor onto the waste package internals is simulated as pure H{sub 2}O and enters at a rate determined by the water vapor pressure for representative temperature and relative humidity conditions. (2) Liquid-Influx Case: The water entering a waste package from the drift is simulated as typical groundwater and enters at a rate determined by the amount of seepage available to flow through openings in a breached waste package.

  7. GAT-280 CHEMISTRY-GENERAL

    Office of Scientific and Technical Information (OSTI)

    GAT-280 CHEMISTRY-GENERAL 1 URANIUM HEXAFLUORIDE: A SURVEY O F THE PHYSICO-CHEMICAL PROPERTIES R. DeWitt Information and Records Subdivision August 1 2 , 1960 GOODYEAR ATOMIC CORPORATION Portsmouth, Ohio DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency Thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for

  8. UCRL-11359 UC-4 Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1359 UC-4 Chemistry TID-45 (27th Ed ) UNIVERSITY OF CALIFORNIA Lawrence Radiation Laboratory Berkeley, California AEC Contract No. W-7405-eng-48 PROPOSED MOLECULAR BEAM DETERMINATION OF ENERGY PARTITION IN THE PHOTO DISSOCIATION OF POLYATOMIC MOLECULES Richard N. Zare and Dudley R. Herschba.ch January 29, 1.964 DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of

  9. heavy_oil | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heavy Oil Heavy oil is a vast U.S. oil resource that is underexploited because its highly viscous nature renders it difficult to produce and to refine. As higher-gravity crudes ...

  10. Santa Fe Jets and Heavy Flavor Workshop

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Santa Fe Jets and Heavy Flavor Workshop Santa Fe Jets and Heavy Flavor Workshop WHEN: Jan 11, 2016 8:30 AM - Jan 13, 2016 5:30 PM WHERE: Inn and Spa at Loretto 211 Old Santa Fe...

  11. Strangeness signals in heavy ion collisions

    SciTech Connect (OSTI)

    Remsberg, L.P.

    1992-11-01

    The experimental data on strange meson and strange baryon production in relativistic heavy ion collisions are reviewed.

  12. Strangeness signals in heavy ion collisions

    SciTech Connect (OSTI)

    Remsberg, L.P.

    1992-01-01

    The experimental data on strange meson and strange baryon production in relativistic heavy ion collisions are reviewed.

  13. Dynacracking process first commerical application for upgrading heavy oils

    SciTech Connect (OSTI)

    Dawson, F.N. Jr.

    1981-01-01

    The Dynacracking process developed by Hydrocarbon Research, Inc., is a non-catalytic process capable of upgrading heavy oil whose sulfur, metal, and carbon contents may be high. It converts residual stocks to distillates with high naphtha yields, and to synthetic fuel gas of high quality (700-800 Btu/ft/sup 3/). It has esentially no air polution emissions and requires a relatively small amount of water and utilities. The process generates sufficient heat internally such that, except for start-up, no boilers, furnaces, or external heaters are required to operate the plant. Several aspects of the process are discussed: chemistry, hardware, feedstock, flexibility in the product mix, product quality, and economics.

  14. In-Package Chemistry Abstraction

    SciTech Connect (OSTI)

    E. Thomas

    2004-11-09

    This report was developed in accordance with the requirements in ''Technical Work Plan for: Regulatory Integration Modeling and Analysis of the Waste Form and Waste Package'' (BSC 2004 [DIRS 171583]). The purpose of the in-package chemistry model is to predict the bulk chemistry inside of a breached waste package and to provide simplified expressions of that chemistry as function of time after breach to Total Systems Performance Assessment for the License Application (TSPA-LA). The scope of this report is to describe the development and validation of the in-package chemistry model. The in-package model is a combination of two models, a batch reactor model that uses the EQ3/6 geochemistry-modeling tool, and a surface complexation model that is applied to the results of the batch reactor model. The batch reactor model considers chemical interactions of water with the waste package materials and the waste form for commercial spent nuclear fuel (CSNF) waste packages and codisposed waste packages that contain both high-level waste glass (HLWG) and DOE spent fuel. The surface complexation model includes the impact of fluid-surface interactions (i.e., surface complexation) on the resulting fluid composition. The model examines two types of water influx: (1) the condensation of water vapor that diffuses into the waste package, and (2) seepage water that enters the waste package from the drift as a liquid. (1) Vapor Influx Case: The condensation of vapor onto the waste package internals is simulated as pure H2O and enters at a rate determined by the water vapor pressure for representative temperature and relative humidity conditions. (2) Water Influx Case: The water entering a waste package from the drift is simulated as typical groundwater and enters at a rate determined by the amount of seepage available to flow through openings in a breached waste package. TSPA-LA uses the vapor influx case for the nominal scenario for simulations where the waste package has been breached but the drip shield remains intact, so all of the seepage flow is diverted from the waste package. The chemistry from the vapor influx case is used to determine the stability of colloids and the solubility of radionuclides available for transport by diffusion, and to determine the degradation rates for the waste forms. TSPA-LA uses the water influx case for the seismic scenario, where the waste package has been breached and the drip shield has been damaged such that seepage flow is actually directed into the waste package. The chemistry from the water influx case that is a function of the flow rate is used to determine the stability of colloids and the solubility of radionuclides available for transport by diffusion and advection, and to determine the degradation rates for the CSNF and HLW glass. TSPA-LA does not use this model for the igneous scenario. Outputs from the in-package chemistry model implemented inside TSPA-LA include pH, ionic strength, and total carbonate concentration. These inputs to TSPA-LA will be linked to the following principle factors: dissolution rates of the CSNF and HLWG, dissolved concentrations of radionuclides, and colloid generation.

  15. Continuous, real time microwave plasma element sensor

    DOE Patents [OSTI]

    Woskov, P.P.; Smatlak, D.L.; Cohn, D.R.; Wittle, J.K.; Titus, C.H.; Surma, J.E.

    1995-12-26

    Microwave-induced plasma is described for continuous, real time trace element monitoring under harsh and variable conditions. The sensor includes a source of high power microwave energy and a shorted waveguide made of a microwave conductive, refractory material communicating with the source of the microwave energy to generate a plasma. The high power waveguide is constructed to be robust in a hot, hostile environment. It includes an aperture for the passage of gases to be analyzed and a spectrometer is connected to receive light from the plasma. Provision is made for real time in situ calibration. The spectrometer disperses the light, which is then analyzed by a computer. The sensor is capable of making continuous, real time quantitative measurements of desired elements, such as the heavy metals lead and mercury. 3 figs.

  16. Continuous, real time microwave plasma element sensor

    DOE Patents [OSTI]

    Woskov, Paul P.; Smatlak, Donna L.; Cohn, Daniel R.; Wittle, J. Kenneth; Titus, Charles H.; Surma, Jeffrey E.

    1995-01-01

    Microwave-induced plasma for continuous, real time trace element monitoring under harsh and variable conditions. The sensor includes a source of high power microwave energy and a shorted waveguide made of a microwave conductive, refractory material communicating with the source of the microwave energy to generate a plasma. The high power waveguide is constructed to be robust in a hot, hostile environment. It includes an aperture for the passage of gases to be analyzed and a spectrometer is connected to receive light from the plasma. Provision is made for real time in situ calibration. The spectrometer disperses the light, which is then analyzed by a computer. The sensor is capable of making continuous, real time quantitative measurements of desired elements, such as the heavy metals lead and mercury.

  17. Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Catalysts play a central role in processes relevant to energy, the environment, and biology. Researchers are working to develop cheaper and smarter catalysts that are fine tuned...

  18. Heavy flavor production from photons and hadrons

    SciTech Connect (OSTI)

    Heusch, C.A.

    1982-01-01

    The present state of the production and observation of hadrons containing heavy quarks or antiquarks as valence constituents, in reactions initiated by real and (space-like) virtual photon or by hadron beams is discussed. Heavy flavor production in e/sup +/e/sup -/ annihilation, which is well covered in a number of recent review papers is not discussed, and similarly, neutrino production is omitted due to the different (flavor-changing) mechanisms that are involved in those reactions. Heavy flavors from spacelike photons, heavy flavors from real photons, and heavy flavors from hadron-hadron collisions are discussed. (WHK)

  19. The synthetic elements

    SciTech Connect (OSTI)

    Hoffman, D.C.

    1990-05-01

    Prior to 1940, the heaviest element known was uranium, discovered in 1789. Since that time the elements 93 through 109 have been synthesized and identified and the elements 43, 61, 85, and 87 which were missing form the periodic tables of the 1930's have been discovered. The techniques and problems involved in these discoveries and the placement of the transuranium elements in the periodic table will be discussed. The production and positive identification of elements heavier than Md (Z=101), which have very short half-lives and can only be produced an atom-at-a-time, are very difficult and there have been controversies concerning their discovery. Some of the new methods which have been developed and used in these studies will be described. The prospects for production of still heavier elements will be considered.

  20. Heavy Vehicle Propulsion Materials Program

    SciTech Connect (OSTI)

    Diamond, S.; Johnson, D.R.

    1999-04-26

    The objective of the Heavy Vehicle Propulsion Materials Program is to develop the enabling materials technology for the clean, high-efficiency diesel truck engines of the future. The development of cleaner, higher-efficiency diesel engines imposes greater mechanical, thermal, and tribological demands on materials of construction. Often the enabling technology for a new engine component is the material from which the part can be made. The Heavy Vehicle Propulsion Materials Program is a partnership between the Department of Energy (DOE), and the diesel engine companies in the United States, materials suppliers, national laboratories, and universities. A comprehensive research and development program has been developed to meet the enabling materials requirements for the diesel engines of the future. Advanced materials, including high-temperature metal alloys, intermetallics, cermets, ceramics, amorphous materials, metal- and ceramic-matrix composites, and coatings, are investigated for critical engine applications.

  1. Rate Case Elements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proceeding Rate Information Residential Exchange Program Surplus Power Sales Reports Rate Case Elements BPA's rate cases are decided "on the record." That is, in making a decision...

  2. Nuclear Science/Nuclear Chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nuclear Science/Nuclear Chemistry Nuclear Physics The 10-MV tandem accelerator at CAMS provides a platform for conducting nuclear physics experiment both for basic science and lab mission-related programs. For example, we performed a new cross section measurement of the astrophysically important reaction 40Ca(a,g)44Ti in which high purity CaO targets were irradiated with helium ions at several different discrete energies. The reaction rate was measured on-line via prompt gamma ray spectroscopy

  3. EXAFS of heavy metal coordination in acid mine drainage sediments

    SciTech Connect (OSTI)

    Carroll, S.; O`Day, P.; Waychunas, G.; Phillips, B.

    1995-12-01

    We use extended x-ray adsorption fine structure (EXAFS) spectroscopy to examine the chemical environment of zinc (1-2 wt. %), lead (300-600 ppm) and cadmium (50-200 ppm) in complex acid mine drainage sediments from the Tri-State Mining District (KS, MO, OK). The sediments in streams draining tailings piles and open mine shafts are dominated by quartz or amorphous iron hydroxides; accessory minerals include calcite. The bulk water chemistry is buffered by the limestone geology and is undersaturated with respect to pure heavy metal carbonates and hydroxides. EXAFS spectra of the sediment samples were taken at SSRL with a fluorescence detector at low temperature ({approximately}10 K). Heavy metals do not form pure carbonate or hydroxide phases, nor do they appear to sorb to quartz surfaces. In sediments near the mine source, the metals are present primarily as sulfides, the original host mineral. With increasing distance from the source, second-neighbor backscattering from Fe indicates that the metals leached from the sulfides are taken up with amorphous iron hydroxides.

  4. Yb-based heavy fermion compounds and field tuned quantum chemistry...

    Office of Scientific and Technical Information (OSTI)

    One of the topics of this work was the investigation of the interaction between the Kondo ... In these systems, the Kondo interaction and CEF excitations generally give rise to large ...

  5. Role of inorganic chemistry on nuclear energy examined

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Role of inorganic chemistry on nuclear energy examined Role of inorganic chemistry on nuclear energy examined Inorganic chemistry can provide insight and improve technical issues surrounding nuclear power production and waste disposition. July 31, 2013 Aspects of inorganic chemistry related to nuclear energy. Aspects of inorganic chemistry related to nuclear energy. John Gordon of LANL's Inorganic, Isotope and Actinide Chemistry group guest edited the issue. The journal Inorganic Chemistry

  6. Role of inorganic chemistry on nuclear energy examined

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Role of inorganic chemistry on nuclear energy examined Role of inorganic chemistry on nuclear energy examined Inorganic chemistry can provide insight and improve technical issues surrounding nuclear power production and waste disposition. July 31, 2013 Aspects of inorganic chemistry related to nuclear energy. Aspects of inorganic chemistry related to nuclear energy. John Gordon of LANL's Inorganic, Isotope and Actinide Chemistry group guest edited the issue. The journal Inorganic Chemistry

  7. Appendix SOTERM: Actinide Chemistry Source Term

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SOTERM-2014 Actinide Chemistry Source Term United States Department of Energy Waste Isolation Pilot Plant Carlsbad Field Office Carlsbad, New Mexico Compliance Recertification Application 2014 Appendix SOTERM-2014 Actinide Chemistry Source Term Table of Contents SOTERM-1.0 Introduction SOTERM-2.0 Expected WIPP Repository Conditions, Chemistry, and Processes SOTERM-2.1 Ambient Geochemical Conditions SOTERM-2.2 Repository Conditions SOTERM-2.2.1 Repository Pressure SOTERM-2.2.2 Repository

  8. Analytical Chemistry Laboratory Progress Report for FY 1994

    SciTech Connect (OSTI)

    Green, D.W.; Boparai, A.S.; Bowers, D.L.

    1994-12-01

    The purpose of this report is to summarize the activities of the Analytical Chemistry Laboratory (ACL) at Argonne National Laboratory (ANL) for Fiscal Year (FY) 1994 (October 1993 through September 1994). This annual report is the eleventh for the ACL and describes continuing effort on projects, work on new projects, and contributions of the ACL staff to various programs at ANL. The Analytical Chemistry Laboratory is a full-cost-recovery service center, with the primary mission of providing a broad range of analytical chemistry support services to the scientific and engineering programs at ANL. The ACL also has a research program in analytical chemistry, conducts instrumental and methods development, and provides analytical services for governmental, educational, and industrial organizations. The ACL handles a wide range of analytical problems. Some routine or standard analyses are done, but it is common for the Argonne programs to generate unique problems that require significant development of methods and adaption of techniques to obtain useful analytical data. The ACL has four technical groups -- Chemical Analysis, Instrumental Analysis, Organic Analysis, and Environmental Analysis -- which together include about 45 technical staff members. Talents and interests of staff members cross the group lines, as do many projects within the ACL. The Chemical Analysis Group uses wet- chemical and instrumental methods for elemental, compositional, and isotopic determinations in solid, liquid, and gaseous samples and provides specialized analytical services. Major instruments in this group include an ion chromatograph (IC), an inductively coupled plasma/atomic emission spectrometer (ICP/AES), spectrophotometers, mass spectrometers (including gas-analysis and thermal-ionization mass spectrometers), emission spectrographs, autotitrators, sulfur and carbon determinators, and a kinetic phosphorescence uranium analyzer.

  9. Screen Electrode Materials & Cell Chemistries and Streamlining...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Screening of Electrode Materials & Cell Chemistries and Streamlining Optimization of Electrodes Vehicle Technologies Office Merit Review 2015: Materials Benchmarking Activities for ...

  10. Nanostructure, Chemistry and Crystallography of Iron Nitride...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electron Microscopy and Related Methods Nanostructure, Chemistry and Crystallography of Iron Nitride Magnetic Materials by Ultra-High-Resolution Electron Microscopy and Related ...

  11. Categorical Exclusion 4497: Lithium Wet Chemistry Project

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Department of Energy Categorical Exclusion Detennination Form Proposed Action Tills: Lithium W@t Chemistry Project (4597) Program or Fild Oftke: Y-12 Site Office L&cationfs)...

  12. 2005 American Conference on Theoretical Chemistry

    SciTech Connect (OSTI)

    Carter, Emily A

    2006-11-19

    The materials uploaded are meant to serve as final report on the funds provided by DOE-BES to help sponsor the 2005 American Conference on Theoretical Chemistry.

  13. Introduction to Chemistry and Material Sciences Applications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Intro Chem and MatSci Apps Introduction to Chemistry and Material Sciences Applications June 26, 2012 Last edited: 2016-04-29 11:34:4

  14. Symposium on high temperature and materials chemistry

    SciTech Connect (OSTI)

    Not Available

    1989-10-01

    This volume contains the written proceedings of the Symposium on High Temperature and Materials Chemistry held in Berkeley, California on October 24--25, 1989. The Symposium was sponsored by the Materials and Chemical Sciences Division of Lawrence Berkeley Laboratory and by the College of Chemistry of the University of California at Berkeley to discuss directions, trends, and accomplishments in the field of high temperature and materials chemistry. Its purpose was to provide a snapshot of high temperature and materials chemistry and, in so doing, to define status and directions.

  15. Introduction to Chemistry and Material Sciences Applications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Intro Chem and MatSci Apps Introduction to Chemistry and Material Sciences Applications June 26, 2012 L ast edited: 2015-12-11 16:11:02...

  16. DOE fundamentals handbook: Chemistry. Volume 2

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    This handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of chemistry. This volume contains the following modules: reactor water chemistry (effects of radiation on water chemistry, chemistry parameters), principles of water treatment (purpose; treatment processes [ion exchange]; dissolved gases, suspended solids, and pH control; water purity), and hazards of chemicals and gases (corrosives [acids, alkalies], toxic compounds, compressed gases, flammable/combustible liquids).

  17. Chemistry of Cobalt-Platinum Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of Cobalt-Platinum Nanocatalysts Print Bimetallic cobalt-platinum (CoPt) nanoparticles are drawing attention in many areas of catalysis as scientists attempt to reduce...

  18. understanding the low-temperature combustion chemistry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    low-temperature combustion chemistry - Sandia Energy Energy Search Icon Sandia Home ... EnergyWater History Water Monitoring & Treatment Technology Decision Models for ...

  19. MOLDED SEALING ELEMENT

    DOE Patents [OSTI]

    Bradford, B.W.; Skinner, W.J.

    1959-03-24

    Molded sealing elements suitable for use under conditions involving exposure to uranium hexafluoride vapor are described. Such sealing elements are made by subjecting graphitic carbons to a preliminary treatment with uranium hexafluoride vapor, and then incorporating polytetrafluorethylene in them. The resulting composition has good wear resistant and frictional properties and is resistant to disintegration by uranium hexafluoride over long periods of exposure.

  20. ANALYTICAL CHEMISTRY AND MEASUREMENT SCIENCE (What Has DOE Done For Analytical Chemistry?) CONF-8904181--1

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    , . - - ANALYTICAL CHEMISTRY AND MEASUREMENT SCIENCE (What Has DOE Done For Analytical Chemistry?) CONF-8904181--1 DE89 009559 W. D. Shults Analytical Chemistry Division Oak Ridge National Laboratory* Oak Ridge, Tennessee 37831-6129 ABSTRACT Over the past forty years, analytical scientists within the DOE complex have had a tremendous impact on the field of analytical chemistry. This paper suggests six "high impact" research/development areas that either originated within or wcce

  1. Neutronic fuel element fabrication

    DOE Patents [OSTI]

    Korton, George

    2004-02-24

    This disclosure describes a method for metallurgically bonding a complete leak-tight enclosure to a matrix-type fuel element penetrated longitudinally by a multiplicity of coolant channels. Coolant tubes containing solid filler pins are disposed in the coolant channels. A leak-tight metal enclosure is then formed about the entire assembly of fuel matrix, coolant tubes and pins. The completely enclosed and sealed assembly is exposed to a high temperature and pressure gas environment to effect a metallurgical bond between all contacting surfaces therein. The ends of the assembly are then machined away to expose the pin ends which are chemically leached from the coolant tubes to leave the coolant tubes with internal coolant passageways. The invention described herein was made in the course of, or under, a contract with the U.S. Atomic Energy Commission. It relates generally to fuel elements for neutronic reactors and more particularly to a method for providing a leak-tight metal enclosure for a high-performance matrix-type fuel element penetrated longitudinally by a multiplicity of coolant tubes. The planned utilization of nuclear energy in high-performance, compact-propulsion and mobile power-generation systems has necessitated the development of fuel elements capable of operating at high power densities. High power densities in turn require fuel elements having high thermal conductivities and good fuel retention capabilities at high temperatures. A metal clad fuel element containing a ceramic phase of fuel intimately mixed with and bonded to a continuous refractory metal matrix has been found to satisfy the above requirements. Metal coolant tubes penetrate the matrix to afford internal cooling to the fuel element while providing positive fuel retention and containment of fission products generated within the fuel matrix. Metal header plates are bonded to the coolant tubes at each end of the fuel element and a metal cladding or can completes the fuel-matrix enclosure by encompassing the sides of the fuel element between the header plates.

  2. SECTION II. HEAVY ION REACTIONS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    II. HEAVY ION REACTIONS Dynamic Evolution and the Caloric Curve for Medium Mass Nuclei J. Cibor, R. Wada, K. Hagel, M. Lunardon, N. Marie, R. Alfaro, W. Shen, B. Xiao, Y. Zhao, J. Li, M. Murray, J.B. Natowitz, Z. Majka and P. Staszel Search for 5He Emission from Hot Compound Nuclei R. Charity and L.G. Sobotka for the Washington University, NSCL, Legnaro, Padova, TAMU Collaboration IMF Production in 64Zn + 58Ni at 35A-79A MeV R. Wada, K. Hagel, J. Cibor, J. Li, M. Murray, J.B. Natowitz, A. Ono

  3. Upgrading Orinoco Belt heavy oil

    SciTech Connect (OSTI)

    Aliantara, J.; Castillo, O.

    1982-05-01

    Petroleos de Venezuela, S.A. (PDVSA), in an effort to develop new oil resources, has undertaken a program to evaluate and develop the Orinoco Heavy Oil Belt, in the eastern part of Venezuela. Lagoven, S.A., a subsidiary of PDVSA, has been assigned the responsibility for developing and upgrading part of the Orinoco belt. This paper describes the most relevant aspects of Lagoven's first upgrading module, a facility that will convert Orinoco oil into a premium crude with a very high yield of products of great market demand.

  4. Heavy Gas Dispersion Incompressible Flow

    Energy Science and Technology Software Center (OSTI)

    1992-01-27

    FEM3 is a numerical model developed primarily to simulate heavy gas dispersion in the atmosphere, such as the gravitational spread and vapor dispersion that result from an accidental spill of liquefied natural gas (LNG). FEM3 solves both two and three-dimensional problems and, in addition to the generalized anelastic formulation, includes options to use either the Boussinesq approximation or an isothermal assumption, when appropriate. The FEM3 model is composed of three parts: a preprocessor PREFEM3, themore » main code FEM3, and two postprocessors TESSERA and THPLOTX.« less

  5. Mapping Metals Incorporation of a Single Catalyst Particle Using Element

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Specific X-ray Nanotomography | Stanford Synchrotron Radiation Lightsource Mapping Metals Incorporation of a Single Catalyst Particle Using Element Specific X-ray Nanotomography Tuesday, March 31, 2015 Fluid catalytic cracking (FCC) is the refining process for converting large and/or heavy molecules of oil feedstock into smaller and lighter hydrocarbons, such as gasoline. The workhorse of the FCC process is a tiny catalyst particle of 50-150 µm diameter that consists of a complex mixture of

  6. NUCLEAR REACTOR FUEL ELEMENT

    DOE Patents [OSTI]

    Anderson, W.F.; Tellefson, D.R.; Shimazaki, T.T.

    1962-04-10

    A plate type fuel element which is particularly useful for organic cooled reactors is described. Generally, the fuel element comprises a plurality of fissionable fuel bearing plates held in spaced relationship by a frame in which the plates are slidably mounted in grooves. Clearance is provided in the grooves to allow the plates to expand laterally. The plates may be rigidly interconnected but are floatingly supported at their ends within the frame to allow for longi-tudinal expansion. Thus, this fuel element is able to withstand large temperature differentials without great structural stresses. (AEC)

  7. Comparison of Muon Capture in Light and in Heavy Nuclei

    SciTech Connect (OSTI)

    Measday, David F.; Stocki, Trevor J.

    2007-10-26

    We have recently completed an experimental study at TRIUMF of muon capture in the following elements, N, Al, Si, Ca, Fe, Ni, I, Au, and Bi. We detected the nuclear gamma rays emitted by the product nuclei after muon capture. The energy of the gamma ray identifies the source nuclide, and thus the reaction which has occurred. Our data are of better quality, and more comprehensive than any other data set in the literature. The ({mu}{sup -},{nu}n) reaction is always dominant. In light nuclei, reactions such as ({mu}{sup -},{nu}p) and ({mu}{sup -},{nu}pn) can occur, but not for heavy nuclei. However the reverse is true for reactions such as ({mu}{sup -},{nu}3n) and ({mu}{sup -},{nu}4n), which are very rare in light nuclei, but easily detected in heavy elements. We shall discuss how such information can be useful in calculations of neutrino-nucleus interactions, and of electron-capture in supernovae.

  8. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Towards Heavy Fermions in Europium Intermetallic Compounds Towards Heavy Fermions in Europium Intermetallic Compounds Print Wednesday, 29 July 2009 00:00 For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in

  9. Chemistry: Theory - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Theory Chemistry: Theory Presentations from 2010 CEFRC First Annual Conference MultireferenceCorrelated WavefunctionCalculations and Reaction Flux Analyses of Methyl Ester Combustion Emily A. Carter, Princeton University Constructing Accurate Combustion Chemistry Models William H. Green, MIT Theoretical Gas Phase Chemical Kinetics Stephen J. Klippenstein, Argonne National Laboratory Theoretical Chemical Kinetics and Combustion Modeling James A. Miller, Argonne National Laboratory Computation of

  10. Mitsubishi Heavy Industries Ltd | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: Mitsubishi Heavy Industries Ltd Place: Tokyo, Tokyo, Japan Zip: 108 8215 Product: Integrated technology company and power equipment supplier....

  11. Heavy Water Test Reactor Dome Removal

    SciTech Connect (OSTI)

    2011-01-01

    A high speed look at the removal of the Heavy Water Test Reactor Dome Removal. A project sponsored by the Recovery Act on the Savannah River Site.

  12. Heavy Mobile Equipment Mechanic (1 Mechanic Shop)

    Broader source: Energy.gov [DOE]

    A successful candidate will perform preventative, predictive, and corrective maintenance on Bonneville Power Administration (BPA's) light and heavy mobile equipment in maintenance and filed...

  13. Heavy Mobile Equipment Mechanic (One Mechanic Shop)

    Broader source: Energy.gov [DOE]

    Join the Bonneville Power Administration (BPA) for a challenging and rewarding career, while working, living, and playing in the Pacific Northwest. The Heavy Mobile Equipment Mechanic (One Mechanic...

  14. Visualizing the Onset of "Heavy Electron" Superconductivity ...

    Office of Science (SC) Website

    Visualizing the Onset of "Heavy Electron" Superconductivity Basic Energy Sciences (BES) BES Home ... Funding DOE Office of Science, Basic Energy Sciences program provided primary ...

  15. OPTIMIZATION OF THE PARAMETERS IN THE RHIC SINGLE CRYSTAL HEAVY ION COLLIMATION.

    SciTech Connect (OSTI)

    BIRYUKOV,V.M.; CHESNOKOV,Y.A.; KOTOV,V.I.; TRBOJEVIC,D.; STEVENS,A.

    1999-03-29

    In the framework of the project to design and test a collimation system prototype using bent channeling crystal for cleaning of the RHIC heavy ion beam halo, we have studied the optimal length and bending angle of a silicon (110) single crystal proposed to be a primary element situated upstream of the traditional heavy amorphous collimator. Besides the matters of the channeling and collimation efficiency, we also looked into the impact the crystal may have on the non-channeled particles that go on circulating in the ring, so as to reduce the momentum offset of the particles scattered of the crystal.

  16. Radical scavengers from heavy hydrocarbons

    SciTech Connect (OSTI)

    Kubo, Junichi

    1996-10-01

    The hydrogen-donating properties of some hydrocarbons form the basis for processes such as coal liquefaction and heavy oil upgrading. However, these hydrocarbons have seldom been used for other purposes, because their potential applications have not been well recognized. Research has indicated that these hydrogen-donating hydrocarbons can be used in important reactions as radical scavengers and have properties particular to those of pure hydrocarbons without functional groups containing heteroatoms. Over years of study researchers have found that pure hydrocarbons with radical-scavenging effects nearly as high as those in conventional hindered phenolic antioxidants can be produced from petroleum, and these hydrogen-donating hydrocarbons exhibit such effects even in oxidative atmospheres (i.e., they function as antioxidants). He has also shown that these mixtures have some properties particular to pure hydrocarbons without functional groups containing heteroatoms, and they`ve seen that a mechanism based on the steric effects appears when these hydrocarbons are used in heavy oil hydroprocessing. Hydrogen-donating hydrocarbons should be a viable resource in many applications. In this article, he presents radical-scavenging abilities, characteristics as pure hydrocarbons, and applications on the basis of the studies.

  17. COMPOSITE FUEL ELEMENT

    DOE Patents [OSTI]

    Hurford, W.J.; Gordon, R.B.; Johnson, W.A.

    1962-12-25

    A sandwich-type fuel element for a reactor is described. This fuel element has the shape of an elongated flat plate and includes a filler plate having a plurality of compartments therein in which the fuel material is located. The filler plate is clad on both sides with a thin cladding material which is secured to the filler plate only to completely enclose the fuel material in each compartment. (AEC)

  18. Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion

    Broader source: Energy.gov (indexed) [DOE]

    Modeling | Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace001_musculus_2011_o.pdf More Documents & Publications Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling High Efficiency Fuel Reactivity Controlled Compression Ignition Combustion

  19. Foreword [Special Issue on Superheavy Elements

    SciTech Connect (OSTI)

    Düllmann, Christoph E.; Herzberg, Rolf -Dietmar; Nazarewicz, Witold; Oganessian, Yuri

    2015-12-07

    Reflecting the breadth of research opportunities in the field of superheavy element research, this special issue covers the range of topics in a comprehensive way, including synthesis of superheavy isotopes, nuclear structure, atomic shell structure, and chemical properties. The contributions detail the status of the field and lay out perspectives for the future. The prospects are bright: new isotopes are awaiting discovery, completing the landscape of superheavy nuclei and bridging the currently existing gap between nuclei synthesized in cold fusion reactions and those from 48Ca induced fusion reactions. The possibility that the limits of nuclear structure studies can be pushed even further in mass and charge has greatly motivated a number of new facilities. Advances in experimental techniques will allow studies on isotopes produced significantly below the 1 pb level. Chemical studies progressing to elements never studied to date are already being prepared. Ultra-fast chemistry setups are under development and it will be fascinating to see them at work, elucidating the influence of relativistic effects on superheavy elements. The richness of chemical systems available for transactinides will expand further, giving access to new chemical systems, giving more information on the architecture of the periodic table.

  20. Foreword [Special Issue on Superheavy Elements

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Düllmann, Christoph E.; Herzberg, Rolf -Dietmar; Nazarewicz, Witold; Oganessian, Yuri

    2015-12-07

    Reflecting the breadth of research opportunities in the field of superheavy element research, this special issue covers the range of topics in a comprehensive way, including synthesis of superheavy isotopes, nuclear structure, atomic shell structure, and chemical properties. The contributions detail the status of the field and lay out perspectives for the future. The prospects are bright: new isotopes are awaiting discovery, completing the landscape of superheavy nuclei and bridging the currently existing gap between nuclei synthesized in cold fusion reactions and those from 48Ca induced fusion reactions. The possibility that the limits of nuclear structure studies can be pushedmore » even further in mass and charge has greatly motivated a number of new facilities. Advances in experimental techniques will allow studies on isotopes produced significantly below the 1 pb level. Chemical studies progressing to elements never studied to date are already being prepared. Ultra-fast chemistry setups are under development and it will be fascinating to see them at work, elucidating the influence of relativistic effects on superheavy elements. The richness of chemical systems available for transactinides will expand further, giving access to new chemical systems, giving more information on the architecture of the periodic table.« less

  1. Octupole shapes in heavy nuclei

    SciTech Connect (OSTI)

    Ahmad, I.

    1994-08-01

    Theoretical calculations and measurements show the presence of strong octupole correlations in thecyround states and low-lying states of odd-mass and odd-odd nuclei in the RaPa region. Evidence for octupole correlations is provided by the observation of parity doublets and reductions in M1 matrix elements, decoupling parameters, and Coriolis matrix elements Involving high-j states. Enhancement of E1 transition rates has also been observed for some of the octupole deformed nuclei. The most convincing argument for octupole deformation is provided by the similarities of the reduced alpha decay rates to the two members of parity doublets.

  2. Fuel Chemistry and Cetane Effects on HCCI Performance, Combustion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Coal-Derived Liquids to Enable HCCI Technology Fuel Chemistry and Cetane Effects on HCCI Performance, Combustion, and Emissions Cetane Performance and Chemistry Comparing ...

  3. Plastic Bags to Batteries: A Green Chemistry Solution | Argonne...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Plastic Bags to Batteries: A Green Chemistry Solution Share Description Plastic bags are the scourge of roadsides, parking lots and landfills. But chemistry comes to the rescue At...

  4. Low-Temperature Combustion Chemistry of Biofuels: Pathways in...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Low-Temperature Combustion Chemistry of Biofuels: Pathways in the Initial Low-Temperature (550 K - 750 K) Oxidation Chemistry of Isopentanol. Citation Details ...

  5. Impact of small changes in particle surface chemistry for unentangled...

    Office of Scientific and Technical Information (OSTI)

    particle surface chemistry for unentangled polymer nanocomposites Citation Details In-Document Search Title: Impact of small changes in particle surface chemistry for unentangled ...

  6. AN EVALUATION OF PYROLYSIS OIL PROPERTIES AND CHEMISTRY AS RELATED...

    Office of Scientific and Technical Information (OSTI)

    AN EVALUATION OF PYROLYSIS OIL PROPERTIES AND CHEMISTRY AS RELATED TO PROCESS AND UPGRADE ... Title: AN EVALUATION OF PYROLYSIS OIL PROPERTIES AND CHEMISTRY AS RELATED TO PROCESS AND ...

  7. July 2013 Most Viewed Documents for Chemistry | OSTI, US Dept...

    Office of Scientific and Technical Information (OSTI)

    July 2013 Most Viewed Documents for Chemistry Science Subject Feed Lithium literature ... Grandy, J. (1997) 35 > Background chemistry for chemical warfare agents and ...

  8. March 2014 Most Viewed Documents for Chemistry | OSTI, US Dept...

    Office of Scientific and Technical Information (OSTI)

    4 Most Viewed Documents for Chemistry Science Subject Feed Flammability characteristics of ... Richards, P. (1989) 19 > Background chemistry for chemical warfare agents and ...

  9. Electrophilic Metal Alkyl Chemistry in New Ligand Environments...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Electrophilic Metal Alkyl Chemistry in New Ligand Environments Citation Details In-Document Search Title: Electrophilic Metal Alkyl Chemistry in New Ligand ...

  10. Most Viewed Documents - Chemistry | OSTI, US Dept of Energy,...

    Office of Scientific and Technical Information (OSTI)

    - Chemistry Flammability characteristics of combustible gases and vapors. 249 refs ... Electrophoresis Wenjun Xi (2008) Chemistry of americium Schulz, W.W. (1976) ...

  11. Private Company Uses EERE-Supported Chemistry Model to Substantially...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Private Company Uses EERE-Supported Chemistry Model to Substantially Improve Combustion Engine Simulation Software Private Company Uses EERE-Supported Chemistry Model to ...

  12. Bridging the Gap between Fundamental Physics and Chemistry and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bridging the Gap between Fundamental Physics and Chemistry and Applied Models for HCCI Engines Bridging the Gap between Fundamental Physics and Chemistry and Applied Models for HCCI ...

  13. Heat Transfer Salts for Nuclear Reactor Systems - Chemistry Control...

    Office of Scientific and Technical Information (OSTI)

    Heat Transfer Salts for Nuclear Reactor Systems - Chemistry Control, Corrosion Mitigation, ... guide to allow anyone to learn the fundamentals of chemistry, engineering, and safety ...

  14. Department of Chemistry | Center for Catalytic HydrocarbonFunctionali...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    expertise in catalysis, electrochemistry, bioinorganic chemistry, materials chemistry and quantum mechanics. To enable fundamental advancements in the design and development of...

  15. Role of inorganic chemistry on nuclear energy examined

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Actinide Chemistry group guest edited the issue. The journal Inorganic Chemistry published a special Forum issue on the ... fuel enrichment); the "service period" when the fuel ...

  16. Final Report: Ionization chemistry of high temperature molecular...

    Office of Scientific and Technical Information (OSTI)

    Final Report: Ionization chemistry of high temperature molecular fluids Citation Details In-Document Search Title: Final Report: Ionization chemistry of high temperature molecular ...

  17. Browse by Discipline -- E-print Network Subject Pathways: Chemistry...

    Office of Scientific and Technical Information (OSTI)

    State University Alavi, Ali (Ali Alavi) - Department of Chemistry, University of Cambridge Allen, Heather C.(Heather C.Allen).- Department of Chemistry, Ohio State University ...

  18. NERSC training events: Data Transfer and Archiving; Chemistry...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    training events: Data Transfer and Archiving; Chemistry and Material Sciences Applications NERSC training events: Data Transfer and Archiving; Chemistry and Material Sciences...

  19. Chemistry, phase formation, and catalytic activity of thinpalladium...

    Office of Scientific and Technical Information (OSTI)

    Title: Chemistry, phase formation, and catalytic activity of thin palladium-containing oxide films synthesized by plasma-assisted physical vapor deposition The chemistry, ...

  20. Browse by Discipline -- E-print Network Subject Pathways: Chemistry...

    Office of Scientific and Technical Information (OSTI)

    ... E.Smalley).- Departments of Chemistry & Physics, Rice University Smith III, Milton R (Milton R Smith III) - Department of Chemistry, Michigan State University Smith, Arthur ...

  1. New Chemistries Found for Liquid Batteries: Grid-scale approach...

    Office of Environmental Management (EM)

    New Chemistries Found for Liquid Batteries: Grid-scale approach to rechargeable power storage gets new arsenal of possible materials New Chemistries Found for Liquid Batteries: ...

  2. Coagulation chemistries for silica removal from cooling tower...

    Office of Scientific and Technical Information (OSTI)

    Coagulation chemistries for silica removal from cooling tower water. Citation Details In-Document Search Title: Coagulation chemistries for silica removal from cooling tower water. ...

  3. Heavy Vehicle Technologies Program Retrospective and Outlook

    SciTech Connect (OSTI)

    James J. Eberhardt

    1999-04-10

    OHVT Mission is to conduct, in collaboration with our heavy vehicle industry partners and their suppliers, a customer-focused national program to research and develop technologies that will enable trucks and other heavy vehicles to be more energy efficient and able to use alternative fuels while simultaneously reducing emissions.

  4. A Heavy Flavor Tracker for STAR

    SciTech Connect (OSTI)

    Xu, Z.; Chen, Y.; Kleinfelder, S.; Koohi, A.; Li, S.; Huang, H.; Tai, A.; Kushpil, V.; Sumbera, M.; Colledani, C.; Dulinski, W.; Himmi,A.; Hu, C.; Shabetai, A.; Szelezniak, M.; Valin, I.; Winter, M.; Surrow,B.; Van Nieuwenhuizen, G.; Bieser, F.; Gareus, R.; Greiner, L.; Lesser,F.; Matis, H.S.; Oldenburg, M.; Ritter, H.G.; Pierpoint, L.; Retiere, F.; Rose, A.; Schweda, K.; Sichtermann, E.; Thomas, J.H.; Wieman, H.; Yamamoto, E.; Kotov, I.

    2005-03-14

    We propose to construct a Heavy Flavor Tracker (HFT) for the STAR experiment at RHIC. The HFT will bring new physics capabilities to STAR and it will significantly enhance the physics capabilities of the STAR detector at central rapidities. The HFT will ensure that STAR will be able to take heavy flavor data at all luminosities attainable throughout the proposed RHIC II era.

  5. Design of heavy oil upgrading units

    SciTech Connect (OSTI)

    Farrell, W.D.; Phodes, R.P.; Zeno, D.Y.

    1985-01-01

    Heavy oil upgrading has become an increasingly important aspect of ER and E's research. Due to high costs of experimental catalysts, small catalyst charges are used (20-150cc). Tubular design and tree-stage stirred design are discussed with emphasis on the techniques and equipment used to handle heavy oil. Mechanical design and fluid mechanics are discussed.

  6. Heavy Duty Vehicle Futures Analysis.

    SciTech Connect (OSTI)

    Askin, Amanda Christine; Barter, Garrett; West, Todd H.; Manley, Dawn Kataoka

    2014-05-01

    This report describes work performed for an Early Career Research and Development project. This project developed a heavy-duty vehicle (HDV) sector model to assess the factors influencing alternative fuel and efficiency technology adoption. This model builds on a Sandia light duty vehicle sector model and provides a platform for assessing potential impacts of technological advancements developed at the Combustion Research Facility. Alternative fuel and technology adoption modeling is typically developed around a small set of scenarios. This HDV sector model segments the HDV sector and parameterizes input values, such as fuel prices, efficiencies, and vehicle costs. This parameterization enables sensitivity and trade space analyses to identify the inputs that are most associated with outputs of interest, such as diesel consumption and greenhouse gas emissions. Thus this analysis tool enables identification of the most significant HDV sector drivers that can be used to support energy security and climate change goals.

  7. Heavy Gas Dispersion Incompressible Flow

    Energy Science and Technology Software Center (OSTI)

    1992-02-03

    FEM3 is a numerical model developed primarily to simulate heavy gas dispersion in the atmosphere, such as the gravitational spread and vapor dispersion that result from an accidental spill of liquefied natural gas (LNG). FEM3 solves both two and three-dimensional problems and, in addition to the generalized anelastic formulation, includes options to use either the Boussinesq approximation or an isothermal assumption, when appropriate. The FEM3 model is composed of three parts: a preprocessor PREFEM3, themore » main code FEM3, and two postprocessors TESSERA and THPLOTX. The DEC VAX11 version contains an auxiliary program, POLYREAD, which reads the polyplot file created by FEM3.« less

  8. Progress in Heavy Ion Fusion

    SciTech Connect (OSTI)

    Herrmannsfeldt, W.B.

    1988-09-01

    The progress of the field of Heavy Ion Fusion has been documented in the proceedings of the series of International Symposia that, in recent years, have occurred every second year. The latest of these conferences was hosted by Gesellshaft fuer Schwerionenforshung (GSI) in Darmstadt, West Germany, June 28-30, 1988. For this report, a few highlights from the conference are selected, stressing experimental progress and prospects for future advances. A little extra time is devoted to report on the developments at the Lawrence Berkeley Laboratory (LBL) which is the center for most of the HIFAR program. The Director of the HIFAR program at LBL is Denis Keefe, who presented the HIF report at the last two of the meetings in this series, and in whose place the author is appearing now. 4 refs., 1 fig.

  9. Ames Lab Plays Elemental Role in New PBS Special | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lab Plays Elemental Role in New PBS Special Ames Lab Plays Elemental Role in New PBS Special April 4, 2012 - 2:34pm Addthis New York Times technology correspondent David Pogue -- host of NOVA’s popular “Making Stuff” series -- takes viewers on a quest to understand chemistry and all of the materials of life: the 118 unique elements that make up the amazing periodic table, including the 90 naturally-occurring elements and those created by scientists. | Photo courtesy of PBS. New

  10. DOE fundamentals handbook: Chemistry. Volume 1

    SciTech Connect (OSTI)

    Not Available

    1993-01-01

    The Chemistry Handbook was developed to assist nuclear facility operating contractors in providing operators, maintenance personnel, and the technical staff with the necessary fundamentals training to ensure a basic understanding of chemistry. The handbook includes information on the atomic structure of matter; chemical bonding; chemical equations; chemical interactions involved with corrosion processes; water chemistry control, including the principles of water treatment; the hazards of chemicals and gases, and basic gaseous diffusion processes. This information will provide personnel with a foundation for understanding the chemical properties of materials and the way these properties can impose limitations on the operation of equipment and systems.

  11. QCD mechanisms for heavy particle production

    SciTech Connect (OSTI)

    Brodsky, S.J.

    1985-09-01

    For very large pair mass, the production of heavy quarks and supersymmetric particles is expected to be governed by ACD fusion subprocesses. At lower mass scales other QCD mechanisms such as prebinding distortion and intrinsic heavy particle Fock states can become important, possibly accounting for the anomalies observed for charm hadroproduction. We emphasize the importance of final-state Coulomb interactions at low relative velocity in QCD and predict the existence of heavy narrow four quark resonances (c c-bar u u-bar) and (cc c-bar c-bar) in ..gamma gamma.. reactions. Coherent QCD contributions are discussed as a contribution to the non-additivity of nuclear structure functions and heavy particle production cross sections. We also predict a new type of amplitude zero for exclusive heavy meson pair production which follows from the tree-graph structure of QCD. 35 refs., 8 figs., 1 tab.

  12. Nuclear fuel element

    DOE Patents [OSTI]

    Zocher, Roy W.

    1991-01-01

    A nuclear fuel element and a method of manufacturing the element. The fuel element is comprised of a metal primary container and a fuel pellet which is located inside it and which is often fragmented. The primary container is subjected to elevated pressure and temperature to deform the container such that the container conforms to the fuel pellet, that is, such that the container is in substantial contact with the surface of the pellet. This conformance eliminates clearances which permit rubbing together of fuel pellet fragments and rubbing of fuel pellet fragments against the container, thus reducing the amount of dust inside the fuel container and the amount of dust which may escape in the event of container breach. Also, as a result of the inventive method, fuel pellet fragments tend to adhere to one another to form a coherent non-fragmented mass; this reduces the tendency of a fragment to pierce the container in the event of impact.

  13. Elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, Maria; Hu, Zhicheng

    1993-01-01

    An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO.sub.2 -containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO.sub.2 to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO.sub.2 in the regenerator off gas stream to elemental sulfur in the presence of a catalyst.

  14. Elemental sulfur recovery process

    DOE Patents [OSTI]

    Flytzani-Stephanopoulos, M.; Zhicheng Hu.

    1993-09-07

    An improved catalytic reduction process for the direct recovery of elemental sulfur from various SO[sub 2]-containing industrial gas streams. The catalytic process provides combined high activity and selectivity for the reduction of SO[sub 2] to elemental sulfur product with carbon monoxide or other reducing gases. The reaction of sulfur dioxide and reducing gas takes place over certain catalyst formulations based on cerium oxide. The process is a single-stage, catalytic sulfur recovery process in conjunction with regenerators, such as those used in dry, regenerative flue gas desulfurization or other processes, involving direct reduction of the SO[sub 2] in the regenerator off gas stream to elemental sulfur in the presence of a catalyst. 4 figures.

  15. Contained radiological analytical chemistry module

    DOE Patents [OSTI]

    Barney, David M.

    1990-01-01

    A system which provides analytical determination of a plurality of water chemistry parameters with respect to water samples subject to radiological contamination. The system includes a water sample analyzer disposed within a containment and comprising a sampling section for providing predetermined volumes of samples for analysis; a flow control section for controlling the flow through the system; and a gas analysis section for analyzing samples provided by the sampling system. The sampling section includes a controllable multiple port valve for, in one position, metering out sample of a predetermined volume and for, in a second position, delivering the material sample for analysis. The flow control section includes a regulator valve for reducing the pressure in a portion of the system to provide a low pressure region, and measurement devices located in the low pressure region for measuring sample parameters such as pH and conductivity, at low pressure. The gas analysis section which is of independent utility provides for isolating a small water sample and extracting the dissolved gases therefrom into a small expansion volume wherein the gas pressure and thermoconductivity of the extracted gas are measured.

  16. Contained radiological analytical chemistry module

    DOE Patents [OSTI]

    Barney, David M.

    1989-01-01

    A system which provides analytical determination of a plurality of water chemistry parameters with respect to water samples subject to radiological contamination. The system includes a water sample analyzer disposed within a containment and comprising a sampling section for providing predetermined volumes of samples for analysis; a flow control section for controlling the flow through the system; and a gas analysis section for analyzing samples provided by the sampling system. The sampling section includes a controllable multiple port valve for, in one position, metering out sample of a predetermined volume and for, in a second position, delivering the material sample for analysis. The flow control section includes a regulator valve for reducing the pressure in a portion of the system to provide a low pressure region, and measurement devices located in the low pressure region for measuring sample parameters such as pH and conductivity, at low pressure. The gas analysis section which is of independent utility provides for isolating a small water sample and extracting the dissolved gases therefrom into a small expansion volume wherein the gas pressure and thermoconductivity of the extracted gas are measured.

  17. Plasma chemistry in wire chambers

    SciTech Connect (OSTI)

    Wise, J.

    1990-05-01

    The phenomenology of wire chamber aging is discussed and fundamentals of proportional counters are presented. Free-radical polymerization and plasma polymerization are discussed. The chemistry of wire aging is reviewed. Similarities between wire chamber plasma (>1 atm dc-discharge) and low-pressure rf-discharge plasmas, which have been more widely studied, are suggested. Construction and use of a system to allow study of the plasma reactions occurring in wire chambers is reported. A proportional tube irradiated by an {sup 55}Fe source is used as a model wire chamber. Condensable species in the proportional tube effluent are concentrated in a cryotrap and analyzed by gas chromatography/mass spectrometry. Several different wire chamber gases (methane, argon/methane, ethane, argon/ethane, propane, argon/isobutane) are tested and their reaction products qualitatively identified. For all gases tested except those containing methane, use of hygroscopic filters to remove trace water and oxygen contaminants from the gas resulted in an increase in the average molecular weight of the products, consistent with results from low-pressure rf-discharge plasmas. It is suggested that because water and oxygen inhibit polymer growth in the gas phase that they may also reduce polymer deposition in proportional tubes and therefore retard wire aging processes. Mechanistic implications of the plasma reactions of hydrocarbons with oxygen are suggested. Unresolved issues in this work and proposals for further study are discussed.

  18. CRYSTAL CHEMISTRY OF HYDROUS MINERALS

    SciTech Connect (OSTI)

    Y. ZHAO; ET AL

    2001-02-01

    Hydrogen has long been appreciated for its role in geological processes of the Earth's crust. However, its role in Earth's deep interior has been neglected in most geophysical thinking. Yet it is now believed that most of our planet's hydrogen may be locked up in high pressure phases of hydrous silicate minerals within the Earth's mantle. This rocky interior (approximately 7/8 of Earth's volume) is conjectured to contain 1-2 orders of magnitude more water than the more obvious oceans (the ''hydrosphere'') and atmosphere. This project is aimed at using the capability of neutron scattering from hydrogen to study the crystal chemistry and stability of hydrogen-bearing minerals at high pressures and temperatures. At the most basic level this is a study of the atomic position and hydrogen bond itself. We have conducted experimental runs on hydrous minerals under high pressure and high temperature conditions. The crystallographic structure of hydrous minerals at extreme conditions and its structural stability, and hydrogen bond at high P-T conditions are the fundamental questions to be addressed. The behavior of the hydrous minerals in the deep interior of the Earth has been discussed.

  19. High Efficiency Clean Combustion for Heavy-Duty Engine | Department...

    Broader source: Energy.gov (indexed) [DOE]

    PDF icon deer09zhang.pdf More Documents & Publications Heavy Truck Engine Development & HECC High Efficiency Clean Combustion for Heavy-Duty Engine Heavy-Duty Engine Combustion ...

  20. Element Partners | Open Energy Information

    Open Energy Info (EERE)

    Product: DFJ Element, a partnership between Element Venture Partners and Draper Fisher Jurvetson, manages a venture capital fund focusing on investments in high growth,...

  1. American Elements | Open Energy Information

    Open Energy Info (EERE)

    Elements Jump to: navigation, search Name: American Elements Place: Los Angeles, California Zip: 90024 Product: US-based manufacturer and supplier of PV feedstocks such as silicon,...

  2. Elemental Energy | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Logo: Elemental Energy Name: Elemental Energy Address: 14500 SW 92nd Ave Place: Portland, Oregon Country: United States Zip: 97224 Region: Pacific...

  3. Experimental measurement of the 4-d transverse phase space map of a heavy ion beam

    SciTech Connect (OSTI)

    Hopkins, H S

    1997-12-01

    The development and employment of a new diagnostic instrument for characterizing intense, heavy ion beams is reported on. This instrument, the ''Gated Beam Imager'' or ''GBI'' was designed for use on Lawrence Livermore National Laboratory Heavy Ion Fusion Project's ''Small Recirculator'', an integrated, scaled physics experiment and engineering development project for studying the transport and control of intense heavy ion beams as inertial fusion drivers in the production of electric power. The GBI allows rapid measurement and calculation of a heavy ion beam's characteristics to include all the first and second moments of the transverse phase space distribution, transverse emittance, envelope parameters and beam centroid. The GBI, with appropriate gating produces a time history of the beam resulting in a 4-D phase-space and time ''map'' of the beam. A unique capability of the GBI over existing diagnostic instruments is its ability to measure the ''cross'' moments between the two transverse orthogonal directions. Non-zero ''cross'' moments in the alternating gradient lattice of the Small Recirculator are indicative of focusing element rotational misalignments contributing to beam emittance growth. This emittance growth, while having the same effect on the ability to focus a beam as emittance growth caused by non-linear effects, is in principle removable by an appropriate number of focusing elements. The instrument uses the pepperpot method of introducing a plate with many pinholes into the beam and observing the images of the resulting beamlets as they interact with a detector after an appropriate drift distance. In order to produce adequate optical signal and repeatability, the detector was chosen to be a microchannel plate (MCP) with a phosphor readout screen. The heavy ions in the pepperpot beamlets are stopped in the MCP's thin front metal anode and the resulting secondary electron signal is amplified and proximity-focused onto the phosphor while maintaining the spatial and intensity characteristics of the heavy ion beamlets. The MCP used in this manner is a sensitive, accurate, and long-lasting detector, resistant against signal degradation experienced by previous methods of intense heavy ion beam detection and imaging. The performance of the GBI was benchmarked against existing mechanical emittance diagnostics and the results of sophisticated beam transport numerical simulation codes to demonstrate its usefulness as a diagnostic tool. A method of beam correction to remove the effects of quadrupole focusing element rotational misalignments is proposed using data obtainable from a GBI. An optimizing code was written to determine the parameters of the correction system elements based on input from the GBI. The results of this code for the Small Recirculator beam are reported on.

  4. New Technique Gives a Deeper Look into the Chemistry of Interfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Technique Gives a Deeper Look into the Chemistry of Interfaces Print A new technique developed at the ALS offers sub-nanometer depth resolution of every chemical element to be found at heterogeneous interfaces, such as those in batteries and fuel cells. The technique, Standing-Wave Ambient-Pressure Photoelectron Spectroscopy (SWAPPS), combines standing-wave photoelectron spectroscopy (SWPS) with high-ambient-pressure photoelectron spectroscopy (APPS). The result is a technique that enables

  5. New Technique Gives a Deeper Look into the Chemistry of Interfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Technique Gives a Deeper Look into the Chemistry of Interfaces Print A new technique developed at the ALS offers sub-nanometer depth resolution of every chemical element to be found at heterogeneous interfaces, such as those in batteries and fuel cells. The technique, Standing-Wave Ambient-Pressure Photoelectron Spectroscopy (SWAPPS), combines standing-wave photoelectron spectroscopy (SWPS) with high-ambient-pressure photoelectron spectroscopy (APPS). The result is a technique that enables

  6. New Technique Gives a Deeper Look into the Chemistry of Interfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Technique Gives a Deeper Look into the Chemistry of Interfaces Print A new technique developed at the ALS offers sub-nanometer depth resolution of every chemical element to be found at heterogeneous interfaces, such as those in batteries and fuel cells. The technique, Standing-Wave Ambient-Pressure Photoelectron Spectroscopy (SWAPPS), combines standing-wave photoelectron spectroscopy (SWPS) with high-ambient-pressure photoelectron spectroscopy (APPS). The result is a technique that enables

  7. New Technique Gives a Deeper Look into the Chemistry of Interfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Technique Gives a Deeper Look into the Chemistry of Interfaces Print A new technique developed at the ALS offers sub-nanometer depth resolution of every chemical element to be found at heterogeneous interfaces, such as those in batteries and fuel cells. The technique, Standing-Wave Ambient-Pressure Photoelectron Spectroscopy (SWAPPS), combines standing-wave photoelectron spectroscopy (SWPS) with high-ambient-pressure photoelectron spectroscopy (APPS). The result is a technique that enables

  8. New Technique Gives a Deeper Look into the Chemistry of Interfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Technique Gives a Deeper Look into the Chemistry of Interfaces Print A new technique developed at the ALS offers sub-nanometer depth resolution of every chemical element to be found at heterogeneous interfaces, such as those in batteries and fuel cells. The technique, Standing-Wave Ambient-Pressure Photoelectron Spectroscopy (SWAPPS), combines standing-wave photoelectron spectroscopy (SWPS) with high-ambient-pressure photoelectron spectroscopy (APPS). The result is a technique that enables

  9. New Technique Gives a Deeper Look into the Chemistry of Interfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Technique Gives a Deeper Look into the Chemistry of Interfaces Print A new technique developed at the ALS offers sub-nanometer depth resolution of every chemical element to be found at heterogeneous interfaces, such as those in batteries and fuel cells. The technique, Standing-Wave Ambient-Pressure Photoelectron Spectroscopy (SWAPPS), combines standing-wave photoelectron spectroscopy (SWPS) with high-ambient-pressure photoelectron spectroscopy (APPS). The result is a technique that enables

  10. New Technique Gives a Deeper Look into the Chemistry of Interfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Technique Gives a Deeper Look into the Chemistry of Interfaces Print A new technique developed at the ALS offers sub-nanometer depth resolution of every chemical element to be found at heterogeneous interfaces, such as those in batteries and fuel cells. The technique, Standing-Wave Ambient-Pressure Photoelectron Spectroscopy (SWAPPS), combines standing-wave photoelectron spectroscopy (SWPS) with high-ambient-pressure photoelectron spectroscopy (APPS). The result is a technique that enables

  11. Perspective: Water cluster mediated atmospheric chemistry

    SciTech Connect (OSTI)

    Vaida, Veronica

    2011-07-14

    The importance of water in atmospheric and environmental chemistry initiated recent studies with results documenting catalysis, suppression and anti-catalysis of thermal and photochemical reactions due to hydrogen bonding of reagents with water. Water, even one water molecule in binary complexes, has been shown by quantum chemistry to stabilize the transition state and lower its energy. However, new results underscore the need to evaluate the relative competing rates between reaction and dissipation to elucidate the role of water in chemistry. Water clusters have been used successfully as models for reactions in gas-phase, in aqueous condensed phases and at aqueous surfaces. Opportunities for experimental and theoretical chemical physics to make fundamental new discoveries abound. Work in this field is timely given the importance of water in atmospheric and environmental chemistry.

  12. NREL: Transportation Research - Fuel Chemistry Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photo by Dennis Schroeder, NREL NREL's fuel chemistry research explores how biofuels, advanced petroleum-based fuels, fuel blends, and natural gas perform in vehicles as well as in ...

  13. DISSOLVED CONCENTRATION LIMITS OF RADIOACTIVE ELEMENTS

    SciTech Connect (OSTI)

    P. Bernot

    2005-07-13

    The purpose of this study is to evaluate dissolved concentration limits (also referred to as solubility limits) of elements with radioactive isotopes under probable repository conditions, based on geochemical modeling calculations using geochemical modeling tools, thermodynamic databases, field measurements, and laboratory experiments. The scope of this activity is to predict dissolved concentrations or solubility limits for elements with radioactive isotopes (actinium, americium, carbon, cesium, iodine, lead, neptunium, plutonium, protactinium, radium, strontium, technetium, thorium, and uranium) relevant to calculated dose. Model outputs for uranium, plutonium, neptunium, thorium, americium, and protactinium are provided in the form of tabulated functions with pH and log fCO{sub 2} as independent variables, plus one or more uncertainty terms. The solubility limits for the remaining elements are either in the form of distributions or single values. Even though selection of an appropriate set of radionuclides documented in Radionuclide Screening (BSC 2002 [DIRS 160059]) includes actinium, transport of Ac is not modeled in the total system performance assessment for the license application (TSPA-LA) model because of its extremely short half-life. Actinium dose is calculated in the TSPA-LA by assuming secular equilibrium with {sup 231}Pa (Section 6.10); therefore, Ac is not analyzed in this report. The output data from this report are fundamental inputs for TSPA-LA used to determine the estimated release of these elements from waste packages and the engineered barrier system. Consistent modeling approaches and environmental conditions were used to develop solubility models for the actinides discussed in this report. These models cover broad ranges of environmental conditions so they are applicable to both waste packages and the invert. Uncertainties from thermodynamic data, water chemistry, temperature variation, and activity coefficients have been quantified or otherwise addressed.

  14. JACKETED REACTOR FUEL ELEMENT

    DOE Patents [OSTI]

    Smith, K.F.; Van Thyne, R.J.

    1958-12-01

    A fuel element is described for fast reactors comprised of a core of uranium metal containing material and a jacket around the core, the jacket consisting of from 2.5 to 15 percent of titanium, from 1 to 5 percent of niobium, and from 80 to 96.5 percent of vanadium.

  15. Senescence responsive transcriptional element

    DOE Patents [OSTI]

    Campisi, Judith; Testori, Alessandro

    1999-01-01

    Recombinant polynucleotides have expression control sequences that have a senescence responsive element and a minimal promoter, and which are operatively linked to a heterologous nucleotide sequence. The molecules are useful for achieving high levels of expression of genes in senescent cells. Methods of inhibiting expression of genes in senescent cells also are provided.

  16. Photovoltaic radiation detector element

    DOE Patents [OSTI]

    Agouridis, Dimitrios C.

    1983-01-01

    A radiation detector element is formed of a body of semiconductor material, a coating on the body which forms a photovoltaic junction therewith, and a current collector consisting of narrow metallic strips, the aforesaid coating having an opening therein the edge of which closely approaches but is spaced from the current collector strips.

  17. Heating element support clip

    DOE Patents [OSTI]

    Sawyer, William C.

    1995-01-01

    An apparatus for supporting a heating element in a channel formed in a heater base is disclosed. A preferred embodiment includes a substantially U-shaped tantalum member. The U-shape is characterized by two substantially parallel portions of tantalum that each have an end connected to opposite ends of a base portion of tantalum. The parallel portions are each substantially perpendicular to the base portion and spaced apart a distance not larger than a width of the channel and not smaller than a width of a graphite heating element. The parallel portions each have a hole therein, and the centers of the holes define an axis that is substantially parallel to the base portion. An aluminum oxide ceramic retaining pin extends through the holes in the parallel portions and into a hole in a wall of the channel to retain the U-shaped member in the channel and to support the graphite heating element. The graphite heating element is confined by the parallel portions of tantalum, the base portion of tantalum, and the retaining pin. A tantalum tube surrounds the retaining pin between the parallel portions of tantalum.

  18. Heating element support clip

    DOE Patents [OSTI]

    Sawyer, W.C.

    1995-08-15

    An apparatus for supporting a heating element in a channel formed in a heater base is disclosed. A preferred embodiment includes a substantially U-shaped tantalum member. The U-shape is characterized by two substantially parallel portions of tantalum that each have an end connected to opposite ends of a base portion of tantalum. The parallel portions are each substantially perpendicular to the base portion and spaced apart a distance not larger than a width of the channel and not smaller than a width of a graphite heating element. The parallel portions each have a hole therein, and the centers of the holes define an axis that is substantially parallel to the base portion. An aluminum oxide ceramic retaining pin extends through the holes in the parallel portions and into a hole in a wall of the channel to retain the U-shaped member in the channel and to support the graphite heating element. The graphite heating element is confined by the parallel portions of tantalum, the base portion of tantalum, and the retaining pin. A tantalum tube surrounds the retaining pin between the parallel portions of tantalum. 6 figs.

  19. NEUTRONIC REACTOR FUEL ELEMENT

    DOE Patents [OSTI]

    Gurinsky, D.H.; Powell, R.W.; Fox, M.

    1959-11-24

    A nuclear fuel element comprising a plurality of nuclear fuel bearing strips is presented. The strips are folded along their longitudinal axes to an angle of about 60 deg and are secured at each end by ferrule to form an elongated assembly suitable for occupying a cylindrical coolant channel.

  20. Photovoltaic radiation detector element

    DOE Patents [OSTI]

    Agouridis, D.C.

    1980-12-17

    A radiation detector element is formed of a body of semiconductor material, a coating on the body which forms a photovoltaic junction therewith, and a current collector consisting of narrow metallic strips, the aforesaid coating having an opening therein in the edge of which closely approaches but is spaced from the current collector strips.

  1. NEUTRONIC REACTOR FUEL ELEMENT

    DOE Patents [OSTI]

    Stacy, J.T.

    1958-12-01

    A reactor fuel element having a core of molybdenum-uranium alloy jacketed in stainless steel is described. A barrier layer of tungsten, tantalum, molybdenum, columbium, or silver is interposed between the core and jacket to prevent formation of a low melting eutectic between uranium and the varlous alloy constituents of the stainless steel.

  2. Checkerboard seed-blanket thorium fuel core concepts for heavy...

    Office of Scientific and Technical Information (OSTI)

    concepts for heavy water moderated reactors Citation Details In-Document Search Title: Checkerboard seed-blanket thorium fuel core concepts for heavy water moderated reactors ...

  3. Accident analysis of heavy water cooled thorium breeder reactor...

    Office of Scientific and Technical Information (OSTI)

    Accident analysis of heavy water cooled thorium breeder reactor Citation Details In-Document Search Title: Accident analysis of heavy water cooled thorium breeder reactor ...

  4. The Silicon Vertex Tracker for the Heavy Photon Search Experiment...

    Office of Scientific and Technical Information (OSTI)

    Silicon Vertex Tracker for the Heavy Photon Search Experiment Citation Details In-Document Search Title: The Silicon Vertex Tracker for the Heavy Photon Search Experiment Authors: ...

  5. Heavy Duty Vehicle In-Use Emission Performance | Department of...

    Broader source: Energy.gov (indexed) [DOE]

    Evaluating Exhaust Emission Performance of Urban Buses Using Transient Heavy-Duty Chassis Dynamometer Fuel Efficiency of New European HD Vehicles HEAVY-DUTY TRUCK EMISSIONS AND ...

  6. HEAVY-DUTY TRUCK EMISSIONS AND FUEL CONSUMPTION SIMULATING REAL...

    Broader source: Energy.gov (indexed) [DOE]

    Evaluating Exhaust Emission Performance of Urban Buses Using Transient Heavy-Duty Chassis Dynamometer Heavy Duty Vehicle In-Use Emission Performance Fuel Efficiency of New European ...

  7. QCD Prediction for Heavy Boson Transverse Momentum Distributions...

    Office of Scientific and Technical Information (OSTI)

    QCD Prediction for Heavy Boson Transverse Momentum Distributions Citation Details In-Document Search Title: QCD Prediction for Heavy Boson Transverse Momentum Distributions We ...

  8. Recent Developments in Heavy Quark and Quarkonium Production...

    Office of Scientific and Technical Information (OSTI)

    Conference: Recent Developments in Heavy Quark and Quarkonium Production Citation Details In-Document Search Title: Recent Developments in Heavy Quark and Quarkonium Production ...

  9. Triangularity and dipole asymmetry in relativistic heavy ion...

    Office of Scientific and Technical Information (OSTI)

    Triangularity and dipole asymmetry in relativistic heavy ion collisions Citation Details In-Document Search Title: Triangularity and dipole asymmetry in relativistic heavy ion ...

  10. Heavy Quarks, QCD, and Effective Field Theory Thomas Mehen 72...

    Office of Scientific and Technical Information (OSTI)

    Heavy Quarks, QCD, and Effective Field Theory Thomas Mehen 72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS; 73 NUCLEAR PHYSICS AND RADIATION PHYSICS Heavy Quarks, Quarkonium,...

  11. Heavy-Duty Powertrain and Vehicle Development - A Look Toward...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy-Duty Powertrain and Vehicle Development - A Look Toward 2020 Globalization in emissions regulation will be driving freight efficiency improvements and will require heavy-duty ...

  12. Two-dimensional heavy fermions on the strongly correlated boundaries...

    Office of Scientific and Technical Information (OSTI)

    Two-dimensional heavy fermions on the strongly correlated boundaries of Kondo topological insulators Prev Next Title: Two-dimensional heavy fermions on the strongly ...

  13. Vehicle Technologies Office Merit Review 2014: Advanced Heavy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Heavy-Duty Engine Systems and Emissions Control Modeling and Analysis Vehicle Technologies Office Merit Review 2014: Advanced Heavy-Duty Engine Systems and Emissions ...

  14. Development and Demonstration of Fischer-Tropsch Fueled Heavy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fischer-Tropsch Fueled Heavy-Duty Vehicles with Control Technologies for Reduced Diesel Exhaust Emissions Development and Demonstration of Fischer-Tropsch Fueled Heavy-Duty ...

  15. WORKSHOP REPORT: Trucks and Heavy-Duty Vehicles Technical Requirements...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Trucks and Heavy-Duty Vehicles Technical Requirements and Gaps for Lightweight and Propulsion Materials WORKSHOP REPORT: Trucks and Heavy-Duty Vehicles Technical Requirements and ...

  16. Fuel Efficiency and Emissions Optimization of Heavy-Duty Diesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Emissions Optimization of Heavy-Duty Diesel Engines using Model-Based Transient Calibration Fuel Efficiency and Emissions Optimization of Heavy-Duty Diesel Engines using ...

  17. Medium- and Heavy-Duty Electric Drive Vehicle Simulation and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Medium- and Heavy-Duty Electric Drive Vehicle Simulation and Analysis Medium- and Heavy-Duty Electric Drive Vehicle Simulation and Analysis 2011 DOE Hydrogen and Fuel Cells ...

  18. Implications of naturalness for the heavy Higgs bosons of supersymmetr...

    Office of Scientific and Technical Information (OSTI)

    Implications of naturalness for the heavy Higgs bosons of supersymmetry Citation Details In-Document Search Title: Implications of naturalness for the heavy Higgs bosons of ...

  19. Heavy quarkonium in a holographic basis (Journal Article) | DOE...

    Office of Scientific and Technical Information (OSTI)

    Heavy quarkonium in a holographic basis Title: Heavy quarkonium in a holographic basis Authors: Li, Yang Search DOE PAGES for author "Li, Yang" Search DOE PAGES for ORCID ...

  20. Chemistry of Cobalt-Platinum Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of Cobalt-Platinum Nanocatalysts Chemistry of Cobalt-Platinum Nanocatalysts Print Monday, 25 February 2013 15:59 Bimetallic cobalt-platinum (CoPt) nanoparticles are drawing attention in many areas of catalysis as scientists attempt to reduce precious metal content while maintaining optimum catalytic selectivity and reactivity. Cobalt, an important transition metal used for catalytic hydrogenation reactions of CO and CO2 to produce gaseous or liquid hydrocarbons, has a long history of

  1. Heavy-quark physics in quantum chromodynamics

    SciTech Connect (OSTI)

    Brodsky, S.J.

    1991-04-01

    Heavy quarks can expose new symmetries and novel phenomena in QCD not apparent in ordinary hadronic systems. In these lectures I discuss the use of effective-Lagrangian and light-cone Fock methods to analyze exclusive heavy hadron decays such as {Upsilon} {yields} p{bar p} and B {yields} {pi}{pi}, and also to derive effective Schroedinger and Dirac equations for heavy quark systems. Two contributions to the heavy quark structure functions of the proton and other light hadrons are identified: an extrinsic'' contribution associated with leading twist QCD evolution of the gluon distribution, and a higher twist intrinsic'' contribution due to the hardness of high-mass fluctuations of multi-gluon correlations in hadronic wavefunctions. A non-perturbative calculation of the heavy quark distribution of a meson in QCD in one space and one time is presented. The intrinsic higher twist contributions to the pion and proton structure functions can dominate the hadronic production of heavy quark systems at large longitudinal momentum fraction x{sub F} and give anomalous contributions to the quark structure functions of ordinary hadrons at large x{sub bj}. I also discuss a number of ways in which heavy quark production in nuclear targets can test fundamental QCD phenomena and provide constraints on hadronic wavefunctions. The topics include color transparency, finite formation time, and predictions for charm production at threshold, including nuclear-bound quarkonium. I also discuss a number of QCD mechanisms for the suppression of J/{psi} and {Upsilon} production in nuclear collisions, including gluon shadowing, the peripheral excitation of intrinsic heavy quark components at large x{sub F}, and the coalescence of heavy quarks with co-moving spectators at low x{sub F}.

  2. Quark-gluon plasma in the early Universe and in ultra-relativistic heavy-ion collisions

    SciTech Connect (OSTI)

    Greco, V.

    2014-05-09

    We briefly give an elementary introduction to the expansion of the Early Universe till when the phase transition of the quark-gluon plasma to a hadronic matter takes place. Then we describe some main element of the study of QGP by mean of ultra-relativistic heavy-ion collisions (uRHIC's)

  3. Uncertainties in nuclear transition matrix elements of neutrinoless ?? decay

    SciTech Connect (OSTI)

    Rath, P. K.

    2013-12-30

    To estimate the uncertainties associated with the nuclear transition matrix elements M{sup (K)} (K=0?/0N) for the 0{sup +} ? 0{sup +} transitions of electron and positron emitting modes of the neutrinoless ?? decay, a statistical analysis has been performed by calculating sets of eight (twelve) different nuclear transition matrix elements M{sup (K)} in the PHFB model by employing four different parameterizations of a Hamiltonian with pairing plus multipolar effective two-body interaction and two (three) different parameterizations of Jastrow short range correlations. The averages in conjunction with their standard deviations provide an estimate of the uncertainties associated the nuclear transition matrix elements M{sup (K)} calculated within the PHFB model, the maximum of which turn out to be 13% and 19% owing to the exchange of light and heavy Majorana neutrinos, respectively.

  4. Rare Earth Elements Home Page

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Rare Earth Elements Rare Earth Elements from Coal and Coal By-Products logo. Download the 2016 Rare Earth Elements from Coal and Coal By-Products Project Portfolio Rare Earth Elements from Coal and Coal By-Products program overview slide. The REE Program is focused on developing technologies for the recovery of REEs from Coal and Coal By-Products. Rare Earth Elements from Coal and Coal By-Products background slide The 17-element group known as rare earth elements (REEs) provides significant

  5. Finite Element Analysis Code

    Energy Science and Technology Software Center (OSTI)

    2006-03-08

    MAPVAR-KD is designed to transfer solution results from one finite element mesh to another. MAPVAR-KD draws heavily from the structure and coding of MERLIN II, but it employs a new finite element data base, EXODUS II, and offers enhanced speed and new capabilities not available in MERLIN II. In keeping with the MERLIN II documentation, the computational algorithms used in MAPVAR-KD are described. User instructions are presented. Example problems are included to demonstrate the operationmore » of the code and the effects of various input options. MAPVAR-KD is a modification of MAPVAR in which the search algorithm was replaced by a kd-tree-based search for better performance on large problems.« less

  6. Chemistry Impacts in Gasoline HCCI

    SciTech Connect (OSTI)

    Szybist, James P; Bunting, Bruce G

    2006-09-01

    The use of homogeneous charge compression ignition (HCCI) combustion in internal combustion engines is of interest because it has the potential to produce low oxides of nitrogen (NOx) and particulate matter (PM) emissions while providing diesel-like efficiency. In HCCI combustion, a premixed charge of fuel and air auto-ignites at multiple points in the cylinder near top dead center (TDC), resulting in rapid combustion with very little flame propagation. In order to prevent excessive knocking during HCCI combustion, it must take place in a dilute environment, resulting from either operating fuel lean or providing high levels of either internal or external exhaust gas recirculation (EGR). Operating the engine in a dilute environment can substantially reduce the pumping losses, thus providing the main efficiency advantage compared to spark-ignition (SI) engines. Low NOx and PM emissions have been reported by virtually all researchers for operation under HCCI conditions. The precise emissions can vary depending on how well mixed the intake charge is, the fuel used, and the phasing of the HCCI combustion event; but it is common for there to be no measurable PM emissions and NOx emissions <10 ppm. Much of the early HCCI work was done on 2-stroke engines, and in these studies the CO and hydrocarbon emissions were reported to decrease [1]. However, in modern 4-stroke engines, the CO and hydrocarbon emissions from HCCI usually represent a marked increase compared with conventional SI combustion. This literature review does not report on HCCI emissions because the trends mentioned above are well established in the literature. The main focus of this literature review is the auto-ignition performance of gasoline-type fuels. It follows that this discussion relies heavily on the extensive information available about gasoline auto-ignition from studying knock in SI engines. Section 2 discusses hydrocarbon auto-ignition, the octane number scale, the chemistry behind it, its shortcomings, and its relevance to HCCI. Section 3 discusses the effects of fuel volatility on fuel and air mixing and the consequences it has on HCCI. The effects of alcohol fuels on HCCI performance, and specifically the effects that they have on the operable speed/load range, are reviewed in Section 4. Finally, conclusions are drawn in Section 5.

  7. OXIDATION OF TRANSURANIC ELEMENTS

    DOE Patents [OSTI]

    Moore, R.L.

    1959-02-17

    A method is reported for oxidizing neptunium or plutonium in the presence of cerous values without also oxidizing the cerous values. The method consists in treating an aqueous 1N nitric acid solution, containing such cerous values together with the trivalent transuranic elements, with a quantity of hydrogen peroxide stoichiometrically sufficient to oxidize the transuranic values to the hexavalent state, and digesting the solution at room temperature.

  8. Nuclear fuel element

    DOE Patents [OSTI]

    Meadowcroft, Ronald Ross; Bain, Alastair Stewart

    1977-01-01

    A nuclear fuel element wherein a tubular cladding of zirconium or a zirconium alloy has a fission gas plenum chamber which is held against collapse by the loops of a spacer in the form of a tube which has been deformed inwardly at three equally spaced, circumferential positions to provide three loops. A heat resistant disc of, say, graphite separates nuclear fuel pellets within the cladding from the plenum chamber. The spacer is of zirconium or a zirconium alloy.

  9. Time-of-flight detector for heavy ion backscattering spectrometry

    SciTech Connect (OSTI)

    Knapp, J.A.; Banks, J.C.; Doyle, B.L.

    1994-04-01

    This report describes the results of a two-year laboratory directed research and development project to explore advanced concepts in Heavy Ion Backscattering Spectrometry (HIBS), undertaken with the goal of extending the sensitivity of this relatively new technique to levels unattainable by any other existing trace element surface analysis. Improvements in sensitivity are required for the application of HIBS to contamination control in the microelectronics industry. Tools with sensitivity approaching 10{sup 8} atoms/cm{sup 2} are expected to be essential for enabling advanced IC production by the year 2000. During the project the authors developed a new analysis chamber with channeling goniometer and a prototype time-of-flight detector with a demonstrated sensitivity of {approximately} 5 {times} 10{sup 8} atoms/cm{sup 2} for Au on Si and {approximately} 5 {times} 10{sup 10} for Fe, and sufficient mass resolution to separate contributions from Fe and Cu.

  10. Heavy hadrons in quark-gluon plasma

    SciTech Connect (OSTI)

    Narodetskii, I. M. Simonov, Yu. A.; Veselov, A. I.

    2011-03-15

    We use the nonperturbative quark-antiquark potential derived within the Field Correlator Method and the screened Coulomb potential to calculate binding energies and melting temperatures of heavy mesons and baryons in the deconfined phase of quark-gluon plasma.

  11. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass)

  12. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass)

  13. Santa Fe Jets and Heavy Flavor Workshop

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Santa Fe Jets and Heavy Flavor Workshop Santa Fe Jets and Heavy Flavor Workshop WHEN: Jan 11, 2016 8:30 AM - Jan 13, 2016 5:30 PM WHERE: Inn and Spa at Loretto 211 Old Santa Fe Trail Santa Fe, New Mexico 87501 USA CONTACT: Ivan Vitev CATEGORY: Science TYPE: Conference INTERNAL: Calendar Login Event Description This workshop will bring together senior researchers, postdoctoral fellows and talented graduate students to discuss the exciting recent developments and future directions in high energy

  14. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass)

  15. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass)

  16. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass)

  17. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass)

  18. Towards Heavy Fermions in Europium Intermetallic Compounds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Towards Heavy Fermions in Europium Intermetallic Compounds Print For decades, intermetallic compounds of rare-earth metals have been favorite systems of the research community studying strong electron correlations in solids. Nowadays rare-earth intermetallics are often treated as model systems for studies of zero-temperature quantum critical phase transitions, since heavy-fermion rare-earth compounds (in which the electron effective mass is orders of magnitude larger than the bare electron mass)

  19. Jets in relativistic heavy ion collisions

    SciTech Connect (OSTI)

    Wang, Xin-Nian; Gyulassy, M.

    1990-09-01

    Several aspects of hard and semihard QCD jets in relativistic heavy ion collisions are discussed, including multiproduction of minijets and the interaction of a jet with dense nuclear matter. The reduction of jet quenching effect in deconfined phase of nuclear matter is speculated to provide a signature of the formation of quark gluon plasma. HIJING Monte Carlo program which can simulate events of jets production and quenching in heavy ion collisions is briefly described. 35 refs., 13 figs.

  20. Heavy Ion Reactions - Research - Cyclotron Institute

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heavy Ion Reactions Fast and slow components of CsI #4 are plotted. Hydrogen, Helium and Lithium isotopes are visible. The availability of energetic, light- and heavy-ion beams from the K500 Superconducting Cyclotron provides many possibilities for exploring new aspects of nuclear behavior. Using a wide variety of projectiles and bombarding energies, we achieve a more detailed understanding of the dynamics of nuclear collisions, casting new light onto the temporal evolution of quantal systems

  1. Uranium and thorium complexes of the phosphaethynolate ion

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    aHeavy Element Chemistry Group, Chemical Sciences Division, Lawrence Berkeley ... 2015 Chem. Sci. View Article Online Chemical Science Edge Article 1 .inmiuiN ...

  2. Dr Larry A Rahn | U.S. DOE Office of Science (SC)

    Office of Science (SC) Website

    Dr Larry A Rahn Chemical Sciences, Geosciences, & Biosciences (CSGB) Division CSGB Home ... with both the Gas-Phase Chemical Physics Program and the Heavy Element Chemistry Program. ...

  3. Atom-at-a-time radiochemical separations of the heaviest elements: Lawrencium chemistry

    SciTech Connect (OSTI)

    Hoffman, D.C.; Henderson, R.A.; Gregorich, K.E.; Bennett, D.A.; Chasteler, R.M.; Gannett, C.M.; Hall, H.L.; Lee, D.M.; Nurmia, M.J.; Silva, R.J.

    1987-04-01

    The isotope /sup 260/Lr produced in reactions of /sup 18/O with /sup 249/Bk was used to perform chemical experiments on lawrencium to learn more about its chemical properties. These experiments involved extractions with thenoyl trifluoroacetate (TTA), ammonium alpha-hydroxyisobutyrate (HIB) elution from a cation exchange resin column, and reverse-phase chromatography using hydrogen di(2-ethylhexyl)orthophosphoric acid (HDEHP) to investigate the chemical properties of Lr. The results from the HIB elutions also give information about the ionic radius of Lr(III) which was found to elute very close to Er. An attempt to reduce Lr(III) was also made.

  4. Nuclear reactor fuel element

    DOE Patents [OSTI]

    Johnson, Carl E. (Elk Grove, IL); Crouthamel, Carl E. (Richland, WA)

    1980-01-01

    A nuclear reactor fuel element is described which has an outer cladding, a central core of fissionable or mixed fissionable and fertile fuel material and a layer of oxygen gettering material on the inner surface of the cladding. The gettering material reacts with oxygen released by the fissionable material during irradiation of the core thereby preventing the oxygen from reacting with and corroding the cladding. Also described is an improved method for coating the inner surface of the cladding with a layer of gettering material.

  5. TWISTED RIBBON FUEL ELEMENT

    DOE Patents [OSTI]

    Breden, C.R.; Schultz, A.B.

    1961-06-01

    A reactor core formed of bundles of parallel fuel elements in the form of ribbons is patented. The fuel ribbons are twisted about their axes so as to have contact with one another at regions spaced lengthwise of the ribbons and to be out of contact with one another at locations between these spaced regions. The contact between the ribbons is sufficient to allow them to be held together in a stable bundle in a containing tube without intermediate support, while permitting enough space between the ribbon for coolant flowing.

  6. Finite Element Analysis Code

    Energy Science and Technology Software Center (OSTI)

    2005-06-26

    Exotxt is an analysis code that reads finite element results data stored in an exodusII file and generates a file in a structured text format. The text file can be edited or modified via a number of text formatting tools. Exotxt is used by analysis to translate data from the binary exodusII format into a structured text format which can then be edited or modified and then either translated back to exodusII format or tomore » another format.« less

  7. Finite Element Analysis Code

    Energy Science and Technology Software Center (OSTI)

    2005-05-07

    CONEX is a code for joining sequentially in time multiple exodusll database files which all represent the same base mesh topology and geometry. It is used to create a single results or restart file from multiple results or restart files which typically arise as the result of multiple restarted analyses. CONEX is used to postprocess the results from a series of finite element analyses. It can join sequentially the data from multiple results databases intomore » a single database which makes it easier to postprocess the results data.« less

  8. FUEL ELEMENT CONSTRUCTION

    DOE Patents [OSTI]

    Zumwalt, L.R.

    1961-08-01

    Fuel elements having a solid core of fissionable material encased in a cladding material are described. A conversion material is provided within the cladding to react with the fission products to form stable, relatively non- volatile compounds thereby minimizing the migration of the fission products into the coolant. The conversion material is preferably a metallic fluoride, such as lead difluoride, and may be in the form of a coating on the fuel core or interior of the cladding, or dispersed within the fuel core. (AEC)

  9. Structure, chemistry, and properties of mineral nanoparticles

    SciTech Connect (OSTI)

    Waychunas, G.A.; Zhang, H.; Gilbert, B.

    2008-12-02

    Nanoparticle properties can depart markedly from their bulk analog materials, including large differences in chemical reactivity, molecular and electronic structure, and mechanical behavior. The greatest changes are expected at the smallest sizes, e.g. 10 nm and below, where surface effects are expected to dominate bonding, shape and energy considerations. The precise chemistry at nanoparticle interfaces can have a profound effect on structure, phase transformations, strain, and reactivity. Certain phases may exist only as nanoparticles, requiring transformations in chemistry, stoichiometry and structure with evolution to larger sizes. In general, mineralogical nanoparticles have been little studied.

  10. Water issues associated with heavy oil production.

    SciTech Connect (OSTI)

    Veil, J. A.; Quinn, J. J.; Environmental Science Division

    2008-11-28

    Crude oil occurs in many different forms throughout the world. An important characteristic of crude oil that affects the ease with which it can be produced is its density and viscosity. Lighter crude oil typically can be produced more easily and at lower cost than heavier crude oil. Historically, much of the nation's oil supply came from domestic or international light or medium crude oil sources. California's extensive heavy oil production for more than a century is a notable exception. Oil and gas companies are actively looking toward heavier crude oil sources to help meet demands and to take advantage of large heavy oil reserves located in North and South America. Heavy oil includes very viscous oil resources like those found in some fields in California and Venezuela, oil shale, and tar sands (called oil sands in Canada). These are described in more detail in the next chapter. Water is integrally associated with conventional oil production. Produced water is the largest byproduct associated with oil production. The cost of managing large volumes of produced water is an important component of the overall cost of producing oil. Most mature oil fields rely on injected water to maintain formation pressure during production. The processes involved with heavy oil production often require external water supplies for steam generation, washing, and other steps. While some heavy oil processes generate produced water, others generate different types of industrial wastewater. Management and disposition of the wastewater presents challenges and costs for the operators. This report describes water requirements relating to heavy oil production and potential sources for that water. The report also describes how water is used and the resulting water quality impacts associated with heavy oil production.

  11. International team discovers element 117

    Broader source: Energy.gov [DOE]

    An international team of scientists from Russia and the United States, including two Department of Energy national laboratories and two universities, has discovered the newest superheavy element, element 117.

  12. DEPENDENCE OF NEBULAR HEAVY-ELEMENT ABUNDANCE ON H I CONTENT FOR SPIRAL GALAXIES

    SciTech Connect (OSTI)

    Robertson, Paul; Shields, Gregory A.; Wright, Audrey; Dave, Romeel; Blanc, Guillermo A.

    2013-08-10

    We analyze the galactic H I content and nebular log (O/H) for 60 spiral galaxies in the Moustakas et al. (2006a) spectral catalog. After correcting for the mass-metallicity relationship, we show that the spirals in cluster environments show a positive correlation for log (O/H) on DEF, the galactic H I deficiency parameter, extending the results of previous analyses of the Virgo and Pegasus I clusters. Additionally, we show for the first time that galaxies in the field obey a similar dependence. The observed relationship between H I deficiency and galactic metallicity resembles similar trends shown by cosmological simulations of galaxy formation including inflows and outflows. These results indicate the previously observed metallicity-DEF correlation has a more universal interpretation than simply a cluster's effects on its member galaxies. Rather, we observe in all environments the stochastic effects of metal-poor infall as minor mergers and accretion help to build giant spirals.

  13. Folden Group - Heavy Element Nuclear and Radiochemistry at Texas A&M

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Services » Outreach » Outreach Forums » Focus Group Activities Focus Group Activities Since February 2007, the Focus Group Forum has been a venue for communication among DOE managers, labor unions, and stakeholder representatives. The Focus Group Forum has resulted in integrated collaborative worker health and safety improvement activities in the areas of Training, 10 CFR 851 Implementation Improvement, Workforce Retention, and Strategic Initiatives. Learn more about the Focus Group FOCUS

  14. Cohesive Zone Model User Element

    Energy Science and Technology Software Center (OSTI)

    2007-04-17

    Cohesive Zone Model User Element (CZM UEL) is an implementation of a Cohesive Zone Model as an element for use in finite element simulations. CZM UEL computes a nodal force vector and stiffness matrix from a vector of nodal displacements. It is designed for structural analysts using finite element software to predict crack initiation, crack propagation, and the effect of a crack on the rest of a structure.

  15. Rare earth element patterns in biotite, muscovite and tourmaline minerals

    SciTech Connect (OSTI)

    Laul, J.C.; Lepel, E.A.

    1986-04-21

    Rare earth element concentrations in the minerals biotite and muscovite from the mica schist country rocks of the Etta pegmatite and tourmalines from the Bob Ingersoll pegmatite have been measured by INAA and CNAA. The concentrations range from 10/sup -4/ g/g to 10/sup -10g//sub g/. The REE patterns of biotite, muscovite and tourmaline reported herein are highly fractionated from light to heavy REE. The REE concentrations in biotite and muscovite are high and indigenous. The pegmatite tourmalines contain low concentrations of REE. Variations in tourmaline REE patterns reflect the geochemical evolution of pegmatite melt/fluid system during crystallization.

  16. REACTOR FUEL ELEMENTS TESTING CONTAINER

    DOE Patents [OSTI]

    Whitham, G.K.; Smith, R.R.

    1963-01-15

    This patent shows a method for detecting leaks in jacketed fuel elements. The element is placed in a sealed tank within a nuclear reactor, and, while the reactor operates, the element is sparged with gas. The gas is then led outside the reactor and monitored for radioactive Xe or Kr. (AEC)

  17. Multi-element microelectropolishing method

    DOE Patents [OSTI]

    Lee, Peter J.

    1994-01-01

    A method is provided for microelectropolishing a transmission electron microscopy nonhomogeneous multi-element compound foil. The foil is electrolyzed at different polishing rates for different elements by rapidly cycling between different current densities. During a first portion of each cycle at a first voltage a first element electrolyzes at a higher current density than a second element such that the material of the first element leaves the anode foil at a faster rate than the second element and creates a solid surface film, and such that the solid surface film is removed at a faster rate than the first element leaves the anode foil. During a second portion of each cycle at a second voltage the second element electrolyzes at a higher current density than the first element, and the material of the second element leaves the anode foil at a faster rate than the first element and creates a solid surface film, and the solid surface film is removed at a slower rate than the second element leaves the foil. The solid surface film is built up during the second portion of the cycle, and removed during the first portion of the cycle.

  18. Multi-element microelectropolishing method

    DOE Patents [OSTI]

    Lee, P.J.

    1994-10-11

    A method is provided for microelectropolishing a transmission electron microscopy nonhomogeneous multi-element compound foil. The foil is electrolyzed at different polishing rates for different elements by rapidly cycling between different current densities. During a first portion of each cycle at a first voltage a first element electrolyzes at a higher current density than a second element such that the material of the first element leaves the anode foil at a faster rate than the second element and creates a solid surface film, and such that the solid surface film is removed at a faster rate than the first element leaves the anode foil. During a second portion of each cycle at a second voltage the second element electrolyzes at a higher current density than the first element, and the material of the second element leaves the anode foil at a faster rate than the first element and creates a solid surface film, and the solid surface film is removed at a slower rate than the second element leaves the foil. The solid surface film is built up during the second portion of the cycle, and removed during the first portion of the cycle. 10 figs.

  19. RECONDITIONING FUEL ELEMENTS

    DOE Patents [OSTI]

    Brandt, H.L.

    1962-02-20

    A process is given for decanning fuel elements that consist of a uranium core, an intermediate section either of bronze, silicon, Al-Si, and uranium silicide layers or of lead, Al-Si, and uranium silicide layers around said core, and an aluminum can bonded to said intermediate section. The aluminum can is dissolved in a solution of sodium hydroxide (9 to 20 wt%) and sodium nitrate (35 to 12 wt %), and the layers of the intermediate section are dissolved in a boiling sodium hydroxide solution of a minimum concentration of 50 wt%. (AEC) A method of selectively reducing plutonium oxides and the rare earth oxides but not uranium oxides is described which comprises placing the oxides in a molten solvent of zinc or cadmium and then adding metallic uranium as a reducing agent. (AEC)

  20. Nuclear fuel element

    DOE Patents [OSTI]

    Armijo, Joseph S.; Coffin, Jr., Louis F.

    1983-01-01

    A nuclear fuel element for use in the core of a nuclear reactor is disclosed and has a composite cladding having a substrate and a metal barrier metallurgically bonded on the inside surface of the substrate so that the metal barrier forms a shield between the substrate and the nuclear fuel material held within the cladding. The metal barrier forms about 1 to about 30 percent of the thickness of the cladding and is comprised of a low neutron absorption metal of substantially pure zirconium. The metal barrier serves as a preferential reaction site for gaseous impurities and fission products and protects the substrate from contact and reaction with such impurities and fission products. The substrate of the composite cladding is selected from conventional cladding materials and preferably is a zirconium alloy. Methods of manufacturing the composite cladding are also disclosed.

  1. Nuclear fuel element

    DOE Patents [OSTI]

    Armijo, Joseph S.; Coffin, Jr., Louis F.

    1980-04-29

    A nuclear fuel element for use in the core of a nuclear reactor is disclosed and has an improved composite cladding comprised of a moderate purity metal barrier of zirconium metallurgically bonded on the inside surface of a zirconium alloy tube. The metal barrier forms a shield between the alloy tube and a core of nuclear fuel material enclosed in the composite cladding. There is a gap between the cladding and the core. The metal barrier forms about 1 to about 30 percent of the thickness of the composite cladding and has low neutron absorption characteristics. The metal barrier serves as a preferential reaction site for gaseous impurities and fission products and protects the alloy tube from contact and reaction with such impurities and fission products. Methods of manufacturing the composite cladding are also disclosed.

  2. Photoconductive circuit element reflectometer

    DOE Patents [OSTI]

    Rauscher, Christen (Alexandria, VA)

    1990-01-01

    A photoconductive reflectometer for characterizing semiconductor devices at millimeter wavelength frequencies where a first photoconductive circuit element (PCE) is biased by a direct current voltage source and produces short electrical pulses when excited into conductance by short first laser light pulses. The electrical pulses are electronically conditioned to improve the frequency related amplitude characteristics of the pulses which thereafter propagate along a transmission line to a device under test. Second PCEs are connected along the transmission line to sample the signals on the transmission line when excited into conductance by short second laser light pulses, spaced apart in time a variable period from the first laser light pulses. Electronic filters connected to each of the second PCEs act as low-pass filters and remove parasitic interference from the sampled signals and output the sampled signals in the form of slowed-motion images of the signals on the transmission line.

  3. Photoconductive circuit element reflectometer

    DOE Patents [OSTI]

    Rauscher, C.

    1987-12-07

    A photoconductive reflectometer for characterizing semiconductor devices at millimeter wavelength frequencies where a first photoconductive circuit element (PCE) is biased by a direct current voltage source and produces short electrical pulses when excited into conductance by short first laser light pulses. The electrical pulses are electronically conditioned to improve the frequency related amplitude characteristics of the pulses which thereafter propagate along a transmission line to a device under test. Second PCEs are connected along the transmission line to sample the signals on the transmission line when excited into conductance by short second laser light pulses, spaced apart in time a determinable period from the first laser light pulses. Electronic filters connected to each of the second PCEs act as low-pass filters and remove parasitic interference from the sampled signals and output the sampled signals in the form of slowed-motion images of the signals on the transmission line. 4 figs.

  4. Exhaust Phosphorous Chemistry | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    3 DEER Conference Presentation: Oak Ridge National Laboratory PDF icon deer_2003_bunting2.pdf More Documents & Publications Exhaust Phosphorous Chemistry and Catalyst Poisoning The Development of Rapid Aging and Poisoning Protocols for Diesel Aftertreatment Devices Vehicle Technologies Office: 2014 Fuel and Lubricant Technologies R&D Annual Progress Report

  5. Heavy Truck Clean Diesel Cooperative Research Program

    SciTech Connect (OSTI)

    Milam, David

    2006-12-31

    This report is the final report for the Department of Energy on the Heavy Truck Engine Program (Contract No. DE-FC05-00OR22806) also known as Heavy Truck Clean Diesel (HTCD) Program. Originally, this was scoped to be a $38M project over 5 years, to be 50/50 co-funded by DOE and Caterpillar. The program started in June 2000. During the program the timeline was extended to a sixth year. The program completed in December 2006. The program goal was to develop and demonstrate the technologies required to enable compliance with the 2007 and 2010 (0.2g/bhph NOx, 0.01g/bhph PM) on-highway emission standards for Heavy Duty Trucks in the US with improvements in fuel efficiency compared to today's engines. Thermal efficiency improvement from a baseline of 43% to 50% was targeted.

  6. Process for upgrading a heavy viscous hydrocarbon

    SciTech Connect (OSTI)

    Lutz, I.H.

    1984-06-12

    A process for upgrading a heavy viscous hydrocarbon, for example, rendering a heavy viscous crude pipelinable, includes visbreaking, distillation and solvent extraction steps. A heavy viscous hydrocarbon is fed through the visbreaker which forms a feed to the distillation step. A heavier fraction from distillation is fed to a solvent extraction unit which produces a fraction which contains resin. At least a portion of the resin containing fraction separated in the solvent extraction unit is recycled and combined with the feed which is to be subjected to visbreaking so that the total yield of products, residual and gas-free, is increased. The recycled resin reduces the tendency of the asphaltenes to separate from the oil and thereby reduces the tendency to lay down coke in the visbreaker; this allows higher conversion to upgraded liquid products.

  7. ITP Chemicals: Technology Roadmap for Computational Chemistry | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Chemistry ITP Chemicals: Technology Roadmap for Computational Chemistry PDF icon compchemistry_roadmap.pdf More Documents & Publications Summary Report from Theory Focus Session on Hydrogen Storage Materials Volume 4 FY 2014 LDRD Report

  8. John Marohn > ProfessorChemistry and Chemical Biology > Faculty...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Marohn Professor Chemistry and Chemical Biology Research Group Webpage jam99@cornell.edu John Marohn earned a B.S. in Chemistry and a B.A. in Physics from the University of...

  9. Recovery and upgrading of heavy oil analyzed

    SciTech Connect (OSTI)

    Fornoff, L.L.; Van Driesen, R.P.; Viens, C.H.

    1980-10-13

    An analysis has been made of recovery and upgrading of Venezuelan heavy crudes by integrating steam-drive production data with an upgraded computer processing program. A study used 110 computer cases to analyze a project using Venezuelan heavy crude from the Jobo field with gravity of 9.2 API and 4.1% by wt sulfur for the base case. Sensitivity cases used 12.2 API oil from the Lot 9 field, Monagas state, Venezuela, with sulfur content of 2.3%. Four upgrading methods were studied (deasphalting, delayed coking, flexicoking, and LC-fining), all with favorable resulting economics.

  10. Redox chemistry and metal-insulator transitions intertwined | Center for

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Redox chemistry and metal-insulator transitions intertwined

  11. Computational and Theoretical Chemistry | U.S. DOE Office of...

    Office of Science (SC) Website

    Computational and Theoretical Chemistry Chemical Sciences, Geosciences, & Biosciences ... Molecular Sciences and Gas Phase Chemical Physics programs-which together comprise ...

  12. Browse by Discipline -- E-print Network Subject Pathways: Chemistry...

    Office of Scientific and Technical Information (OSTI)

    of Engineering and Applied Sciences, Harvard University Hammel, Chris (Chris Hammel) - ... - Departments of Chemistry & Physics, Harvard University Hellman, Frances (Frances ...

  13. Zelenay receives professorship in chemistry from president of Poland

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Zelenay receives professorship in chemistry from president of Poland Zelenay receives professorship in chemistry from president of Poland Piotr Zelenay of Materials Synthesis and Integrated Devices (MPA-11) received the honorary title of Professor in Chemistry from Poland's President Bronisław Komorowski during a June 23 ceremony at the Presidential Palace in Warsaw. October 8, 2015 Zelenay receives professorship in chemistry from president of Poland Piotr Zelenay, right, shakes hands with

  14. Chemistry for Measurement and Detection Science

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... gas, solid, and liquid samples for elemental, isotopic, and structural information. ... small molecules to characterizing chemical-warfare agents to studying nucleic acids. ...

  15. Resistive hydrogen sensing element

    DOE Patents [OSTI]

    Lauf, Robert J.

    2000-01-01

    Systems and methods are described for providing a hydrogen sensing element with a more robust exposed metallization by application of a discontinuous or porous overlay to hold the metallization firmly on the substrate. An apparatus includes: a substantially inert, electrically-insulating substrate; a first Pd containing metallization deposited upon the substrate and completely covered by a substantially hydrogen-impermeable layer so as to form a reference resistor on the substrate; a second Pd containing metallization deposited upon the substrate and at least a partially accessible to a gas to be tested, so as to form a hydrogen-sensing resistor; a protective structure disposed upon at least a portion of the second Pd containing metallization and at least a portion of the substrate to improve the attachment of the second Pd containing metallization to the substrate while allowing the gas to contact said the second Pd containing metallization; and a resistance bridge circuit coupled to both the first and second Pd containing metallizations. The circuit determines the difference in electrical resistance between the first and second Pd containing metallizations. The hydrogen concentration in the gas may be determined. The systems and methods provide advantages because adhesion is improved without adversely effecting measurement speed or sensitivity.

  16. COMPARTMENTED REACTOR FUEL ELEMENT

    DOE Patents [OSTI]

    Cain, F.M. Jr.

    1962-09-11

    A method of making a nuclear reactor fuel element of the elongated red type is given wherein the fissionable fuel material is enclosed within a tubular metal cladding. The method comprises coating the metal cladding tube on its inside wall with a brazing alloy, inserting groups of cylindrical pellets of fissionable fuel material into the tube with spacing members between adjacent groups of pellets, sealing the ends of the tubes to leave a void space therewithin, heating the tube and its contents to an elevated temperature to melt the brazing alloy and to expand the pellets to their maximum dimensions under predetermined operating conditions thereby automatically positioning the spacing members along the tube, and finally cooling the tube to room temperature whereby the spacing disks become permanently fixed at their edges in the brazing alloy and define a hermetically sealed compartment for each fl group of fuel pellets. Upon cooling, the pellets contract thus leaving a space to accommodate thermal expansion of the pellets when in use in a reactor. The spacing members also provide lateral support for the tubular cladding to prevent collapse thereof when subjected to a reactor environment. (AEC)

  17. Heavy particle production at the SSC

    SciTech Connect (OSTI)

    Brodsky, S.J.; Haber, H.E.; Gunion, J.F.

    1984-03-01

    Predictions for the production of heavy quarks, supersymmetric particles, and other colored systems at high energy due to intrinsic twist-six components in the proton wavefunction are given. We also suggest the possibility of using asymmetric collision energies (e.g., via intersecting rings at the SSC) in order to facilitate the study of forward and diffractive particle production processes. 9 references.

  18. The microbial upgrading of model heavy oils

    SciTech Connect (OSTI)

    Webster, I.A.; Patras, L.E. )

    1988-01-01

    The authors have isolated bacteria and used them to catalyze the removal of sulfur, nitrogen and nickel from model heavy oils and asphaltenes. Their paper will discuss their activity and reactor concepts. The concept of a membrane bioreactor for oil processing is introduced.

  19. Hydroprocessing catalysts for heavy oil and coal

    SciTech Connect (OSTI)

    Satriana, M.J.

    1982-01-01

    Hydroprocessing catalysts, as described in over 230 processes covered in this book, are hydrogenation catalysts used in the upgrading of heavy crudes and coal to products expected to be in great demand as the world's primary oil supplies gradually dwindle. The techniques employed in hydroprocessing result in the removal of contaminants, the transformation of lower grade materials such as heavy crudes to valuable fuels, or the conversion of hydrocarbonaceous solids into gaseous or liquid fuel products. All of these techniques are, of course, carried out in the presence of hydrogen. Some of the brightest energy prospects for the future lie in heavy oil reservoirs and coal reserves. Heavy oils, defined in this book as having gravities of < 20/sup 0/API, are crudes so thick that they are not readily extracted from their reservoirs. However, processing of these crudes is of great importance, because the US resource alone is enormous. The main types of processing catalysts covered in the book are hydrorefining catalysts plus some combinations of the two. Catalysts for the conversion of hydrocarbonaceous materials to gaseous or liquid fuels are also covered. The primary starting material for these conversions is coal, but wood, lignin, oil shale, tar sands, and peat are other possibilities. The final chapter describes the preparation of various catalyst support systems.

  20. NUCLEAR REACTOR FUEL ELEMENT ASSEMBLY

    DOE Patents [OSTI]

    Stengel, F.G.

    1963-12-24

    A method of fabricating nuclear reactor fuel element assemblies having a plurality of longitudinally extending flat fuel elements in spaced parallel relation to each other to form channels is presented. One side of a flat side plate is held contiguous to the ends of the elements and a welding means is passed along the other side of the platertransverse to the direction of the longitudinal extension of the elements. The setting and speed of travel of the welding means is set to cause penetration of the side plate with welds at bridge the gap in each channel between adjacent fuel elements with a weld-through bubble of predetermined size. The fabrication of a high strength, dependable fuel element is provided, and the reduction of distortion and high production costs are facilitated by this method. (AEC)

  1. FUEL ELEMENT FOR NEUTRONIC REACTORS

    DOE Patents [OSTI]

    Evans, T.C.; Beasley, E.G.

    1961-01-17

    A fuel element for neutronic reactors, particularly the gas-cooled type of reactor, is described. The element comprises a fuel-bearing plate rolled to form a cylinder having a spiral passageway passing from its periphery to its center. In operation a coolant is admitted to the passageway at the periphery of the element, is passed through the spiral passageway, and emerges into a central channel defined by the inner turn of the rolled plate. The advantage of the element is that the fully heated coolant (i.e., coolant emerging into the central channel) is separated and thus insulated from the periphery of the element, which may be in contact with a low-temperature moderator, by the intermediate turns of the spiral fuel element.

  2. FUEL ELEMENT FOR NUCLEAR REACTORS

    DOE Patents [OSTI]

    Bassett, C.H.

    1961-05-16

    A fuel element particularly adapted for use in nuclear reactors of high power density is offered. It has fissionable fuel pellet segments mounted in a tubular housing and defining a central passage in the fuel element. A burnable poison element extends through the central passage, which is designed to contain more poison material at the median portion than at the end portions thereby providing a more uniform hurnup and longer reactivity life.

  3. Finite element modeling of lightning

    SciTech Connect (OSTI)

    Hwang, C.C.; Huang, S.R.; Bor, S.S.

    1995-12-31

    In this paper the transmission line equation which describes the transient voltage and current distributions of a lightning stroke is employed. Finite element method is used to derive the element equations and one-dimensional linear elements are used to discretize the field region. The implicit Newmark time integration technique is used to convert the resulting second-order ordinary differential equations into a set of recurrence equations which are then solved at each time step. Numerical example is included and discussed.

  4. High temperature solid lubricant materials for heavy duty and advanced heat engines

    SciTech Connect (OSTI)

    DellaCorte, C.; Wood, J.C.

    1994-10-01

    Advanced engine designs incorporate higher mechanical and thermal loading to achieve efficiency improvements. This approach often leads to higher operating temperatures of critical sliding elements (e.g. piston ring/cylinder wall contacts and valve guides) which compromise the use of conventional and even advanced synthetic liquid lubricants. For these applications solid lubricants must be considered. Several novel solid lubricant composites and coatings designated PS/PM200 have been employed to dry and marginally oil lubricated contacts in advanced heat engines. These applications include cylinder kits of heavy duty diesels, and high temperature sterling engines, sidewall seals of rotary engines and various exhaust valve and exhaust component applications. The following paper describes the tribological and thermophysical properties of these tribomaterials and reviews the results of applying them to engine applications. Other potential tribological materials and applications are also discussed with particular emphasis to heavy duty and advanced heat engines.

  5. Modular multi-element high energy particle detector

    DOE Patents [OSTI]

    Coon, Darryl D.; Elliott, John P.

    1990-01-02

    Multi-element high energy particle detector modules comprise a planar heavy metal carrier of tungsten alloy with planar detector units uniformly distributed over one planar surface. The detector units are secured to the heavy metal carrier by electrically conductive adhesive so that the carrier serves as a common ground. The other surface of each planar detector unit is electrically connected to a feedthrough electrical terminal extending through the carrier for front or rear readout. The feedthrough electrical terminals comprise sockets at one face of the carrier and mating pins porjecting from the other face, so that any number of modules may be plugged together to create a stack of modules of any desired number of radiation lengths. The detector units each comprise four, preferably rectangular, p-i-n diode chips arranged around the associated feedthrough terminal to form a square detector unit providing at least 90% detector element coverage of the carrier. Integral spacers projecting from the carriers extend at least partially along the boundaries between detector units to space the p-i-n diode chips from adjacent carriers in a stack. The spacers along the perimeters of the modules are one-half the width of the interior spacers so that when stacks of modules are arranged side by side to form a large array of any size or shape, distribution of the detector units is uniform over the entire array.

  6. Modular multi-element high energy particle detector

    DOE Patents [OSTI]

    Coon, D.D.; Elliott, J.P.

    1990-01-02

    Multi-element high energy particle detector modules comprise a planar heavy metal carrier of tungsten alloy with planar detector units uniformly distributed over one planar surface. The detector units are secured to the heavy metal carrier by electrically conductive adhesive so that the carrier serves as a common ground. The other surface of each planar detector unit is electrically connected to a feedthrough electrical terminal extending through the carrier for front or rear readout. The feedthrough electrical terminals comprise sockets at one face of the carrier and mating pins projecting from the other face, so that any number of modules may be plugged together to create a stack of modules of any desired number of radiation lengths. The detector units each comprise four, preferably rectangular, p-i-n diode chips arranged around the associated feedthrough terminal to form a square detector unit providing at least 90% detector element coverage of the carrier. Integral spacers projecting from the carriers extend at least partially along the boundaries between detector units to space the p-i-n diode chips from adjacent carriers in a stack. The spacers along the perimeters of the modules are one-half the width of the interior spacers so that when stacks of modules are arranged side by side to form a large array of any size or shape, distribution of the detector units is uniform over the entire array. 5 figs.

  7. Making a Difference: Heavy-Duty Combustion Engine Research Saved...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy-Duty Combustion Engine Research Saved Billions Making a Difference: Heavy-Duty Combustion Engine Research Saved Billions December 29, 2015 - 12:22pm Addthis Sandia researcher ...

  8. Heavy-Duty Engine Combustion Optimization for High Thermal Efficiency...

    Broader source: Energy.gov (indexed) [DOE]

    PDF icon deer07zhang.pdf More Documents & Publications High Efficiency Clean Combustion for Heavy-Duty Engine Heavy Truck Engine Development & HECC A Micro-Variable Circular ...

  9. Heavy Quarks, QCD, and Effective Field Theory (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    Heavy Quarks, QCD, and Effective Field Theory Citation Details In-Document Search Title: Heavy Quarks, QCD, and Effective Field Theory The research supported by this OJI award is ...

  10. Geothermal and heavy-oil resources in Texas (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    Geothermal and heavy-oil resources in Texas Citation Details In-Document Search Title: Geothermal and heavy-oil resources in Texas You are accessing a document from the ...

  11. Transient Simulation of a 2007 Prototype Heavy-Duty Engine |...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Simulation of a 2007 Prototype Heavy-Duty Engine Transient Simulation of a 2007 Prototype Heavy-Duty Engine 2004 Diesel Engine Emissions Reduction (DEER) Conference PresentationL ...

  12. Difficulty of Measuring Emissions from Heavy-Duty Engines Equipped...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Difficulty of Measuring Emissions from Heavy-Duty Engines Equipped with SCR and DPF Difficulty of Measuring Emissions from Heavy-Duty Engines Equipped with SCR and DPF In reference ...

  13. Medium- and Heavy-Duty Electric Drive Vehicle Simulation and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Medium- and Heavy-Duty Electric Drive Vehicle Simulation and Analysis Medium- and Heavy-Duty Electric Drive Vehicle Simulation and Analysis 2012 DOE Hydrogen and Fuel Cells Program ...

  14. Cycle chemistry related issues in fossil power plants

    SciTech Connect (OSTI)

    James, K.L.; Chhatre, R.M.

    1994-12-31

    Maximizing the availability and useful life of a fossil power plant can be achieved by the reduction of corrosion. Poorly defined chemistry limits and inadequate response to cycle chemistry excursions have cost the utility industry billions of dollars in lost revenue and repair/replacement costs of damage equipment. The Cycle Chemistry related corrosion problems can be minimized by maintaining feed water, boiler water, and steam purity. Pacific Gas and Electric Company`s approach to reduce cycle chemistry related damage, as well as their participation in the Electric Power Research Institute`s Cycle Chemistry Improvement Program demonstration are reviewed in this paper.

  15. Creation and Testing of the ACES Heavy Heavy-Duty Diesel Engine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Advanced Collaborative Emissions Study (ACES):Phase 3 Evaluation of the European PMP Methodologies Using Chassis Dynamometer and On-road Testing of Heavy-duty Vehicles Advanced ...

  16. Element Labs | Open Energy Information

    Open Energy Info (EERE)

    Labs Jump to: navigation, search Name: Element Labs Address: 3350 Scott Blvd Place: Santa Clara, California Zip: 95054 Region: Bay Area Sector: Efficiency Product: LED Producer...

  17. new chemistry to break down cell walls

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    new chemistry to break down cell walls - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management

  18. understanding the chemistries of ionic liquids

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    chemistries of ionic liquids - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs

  19. Chemistry of Cobalt-Platinum Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of Cobalt-Platinum Nanocatalysts Print Bimetallic cobalt-platinum (CoPt) nanoparticles are drawing attention in many areas of catalysis as scientists attempt to reduce precious metal content while maintaining optimum catalytic selectivity and reactivity. Cobalt, an important transition metal used for catalytic hydrogenation reactions of CO and CO2 to produce gaseous or liquid hydrocarbons, has a long history of use in the industrial process of producing synthetic fuels. Researchers

  20. Chemistry of Cobalt-Platinum Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of Cobalt-Platinum Nanocatalysts Print Bimetallic cobalt-platinum (CoPt) nanoparticles are drawing attention in many areas of catalysis as scientists attempt to reduce precious metal content while maintaining optimum catalytic selectivity and reactivity. Cobalt, an important transition metal used for catalytic hydrogenation reactions of CO and CO2 to produce gaseous or liquid hydrocarbons, has a long history of use in the industrial process of producing synthetic fuels. Researchers

  1. Chemistry of Cobalt-Platinum Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of Cobalt-Platinum Nanocatalysts Print Bimetallic cobalt-platinum (CoPt) nanoparticles are drawing attention in many areas of catalysis as scientists attempt to reduce precious metal content while maintaining optimum catalytic selectivity and reactivity. Cobalt, an important transition metal used for catalytic hydrogenation reactions of CO and CO2 to produce gaseous or liquid hydrocarbons, has a long history of use in the industrial process of producing synthetic fuels. Researchers

  2. Department of Chemistry | Center for Catalytic Hydrocarbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages

    Functionalization Department of Chemistry Faculty & Research Outreach Programs Graduate Studies Events & Seminars Undergraduate Studies Contact Us Faculty & Research > Research Centers & Programs > Center for Catalytic Hydrocarbon Functionalization CCHF Center for Catalytic Hydrocarbon Functionalization Catalysts are central to the efficient and clean utilization of energy resources, and they impact all aspects of the energy sector. With the University of Virginia as

  3. The Chemistry of Flammable Gas Generation

    SciTech Connect (OSTI)

    ZACH, J.J.

    2000-10-30

    The document collects information from field instrumentation, laboratory tests, and analytical models to provide a single source of information on the chemistry of flammable gas generation at the Hanford Site. It considers the 3 mechanisms of formation: radiolysis, chemical reactions, and thermal generation. An assessment of the current models for gas generation is then performed. The results are that the various phenomena are reasonably understood and modeled compared to field data.

  4. Chemistry of Cobalt-Platinum Nanocatalysts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry of Cobalt-Platinum Nanocatalysts Print Bimetallic cobalt-platinum (CoPt) nanoparticles are drawing attention in many areas of catalysis as scientists attempt to reduce precious metal content while maintaining optimum catalytic selectivity and reactivity. Cobalt, an important transition metal used for catalytic hydrogenation reactions of CO and CO2 to produce gaseous or liquid hydrocarbons, has a long history of use in the industrial process of producing synthetic fuels. Researchers

  5. Flavor Physics Data from the Heavy Flavor Averaging Group (HFAG)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Heavy Flavor Averaging Group (HFAG) was established at the May 2002 Flavor Physics and CP Violation Conference in Philadelphia, and continues the LEP Heavy Flavor Steering Group's tradition of providing regular updates to the world averages of heavy flavor quantities. Data are provided by six subgroups that each focus on a different set of heavy flavor measurements: B lifetimes and oscillation parameters, Semi-leptonic B decays, Rare B decays, Unitarity triangle parameters, B decays to charm final states, and Charm Physics.

  6. Electron-State Hybridization in Heavy-Fermion Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron-State Hybridization in Heavy-Fermion Systems Electron-State Hybridization in Heavy-Fermion Systems Print Wednesday, 27 September 2006 00:00 Heavy-fermion systems are characterized by electrons with extremely large effective masses. The corresponding heavy-electron "quasiparticle" states are close to the Fermi energy and govern the thermodynamic, transport, and, in part, magnetic properties of these materials. In the case of rare-earth compounds, the quasiparticle states arise

  7. Managing Inventories of Heavy Actinides (Conference) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Conference: Managing Inventories of Heavy Actinides Citation Details In-Document Search Title: Managing Inventories of Heavy Actinides The Department of Energy (DOE) has stored a limited inventory of heavy actinides contained in irradiated targets, some partially processed, at the Savannah River Site (SRS) and Oak Ridge National Laboratory (ORNL). The 'heavy actinides' of interest include plutonium, americium, and curium isotopes; specifically 242Pu and 244Pu,

  8. Characteristics and upgrading technologies of Chinese heavy oil

    SciTech Connect (OSTI)

    Ghuang Yang; Jinsen Gao

    1995-12-31

    The characteristics of typical Chinese heavy oils produced in the eastern, northwestern, and northeastern parts of China are presented to show the uniqueness of heavy oils on the Chinese mainland. Henceforth, upgrading technologies of Chinese domestic heavy crudes are discussed along this line. Two main categories of upgrading technologies, decarbonization and hydrogenation, as realized or being developed in this country are presented. It is concluded that most Chinese heavy crudes are adaptable to conventional upgrading processes.

  9. MARTINI event generator for heavy quarks: Initialization, parton...

    Office of Scientific and Technical Information (OSTI)

    Initialization, parton evolution, and hadronization Prev Next Title: MARTINI event generator for heavy quarks: Initialization, parton evolution, and hadronization ...

  10. Optimum cycle chemistry for fossil plants

    SciTech Connect (OSTI)

    Dooley, R.B.; Pate, R.

    1995-01-01

    At the time of the last International Fossil Plant Cycle Chemistry Conference in 1991, the vision for cycle chemistry indicated that the fossil plant would become a cleaner place for high purity water and steam, and that the boiler would cease to be the {open_quotes}filter{close_quotes} in the cycle. It was suggested that chemical cleans for drum boilers should be performed on a 10 year basis or greater, and that for once-through units cleans should be eliminated. Without full support of utility management and investment in carefully chosen chemistry and power cycle materials, there would be no chance of success. Three years later it is gratifying to report that the news and progress is very good. Advancements have been achieved in each area and the vision is becoming clearer and more believable by the utilities. This paper will provide the status on the major changes that have taken place and delineate the further needed activities to the end of the century and beyond. A continuing vision is also provided.

  11. Thermal and hydrometallurgical recovery methods of heavy metals from municipal solid waste fly ash

    SciTech Connect (OSTI)

    Kubo?ov, L.

    2013-11-15

    Highlights: MSW fly ash was thermally and hydrometallurgically treated to remove heavy metals. More than 90% of easy volatile heavy metals (Cd and Pb) were removed thermally. More than 90% of Cd, Cr, Cu an Zn were removed by alkaline acid leaching. The best results were obtained for the solution of 3 M NaOH and 2 M H{sub 2}SO{sub 4}. - Abstract: Heavy metals in fly ash from municipal solid waste incinerators are present in high concentrations. Therefore fly ash must be treated as a hazardous material. On the other hand, it may be a potential source of heavy metals. Zinc, lead, cadmium, and copper can be relatively easily removed during the thermal treatment of fly ash, e.g. in the form of chlorides. In return, wet extraction methods could provide promising results for these elements including chromium and nickel. The aim of this study was to investigate and compare thermal and hydrometallurgical treatment of municipal solid waste fly ash. Thermal treatment of fly ash was performed in a rotary reactor at temperatures between 950 and 1050 C and in a muffle oven at temperatures from 500 to 1200 C. The removal more than 90% was reached by easy volatile heavy metals such as cadmium and lead and also by copper, however at higher temperature in the muffle oven. The alkaline (sodium hydroxide) and acid (sulphuric acid) leaching of the fly ash was carried out while the influence of temperature, time, concentration, and liquid/solid ratio were investigated. The combination of alkaline-acidic leaching enhanced the removal of, namely, zinc, chromium and nickel.

  12. Research program to investigate the fundamental chemistry of technetium

    SciTech Connect (OSTI)

    McKeown, David A.; Buechele, Andrew C.; Lukens, Wayne W.; Muller, Isabelle S.; Shuh, David K.; Pegg, Ian L.

    2007-10-12

    The objective of this research is to increase the knowledge of the fundamental technetium chemistry necessary to address challenges to the safe, long-term disposal of high-level nuclear waste posed by this element. The primary issues examined during the course of this project were the behavior of technetium and its surrogate rhenium during waste vitrification and glass corrosion. Since the redox behavior of technetium can play a large role in determining its volatility, one goal of this research was to better understand the behavior of technetium in glass as a function of the redox potential of the glass melt. In addition, the behavior of rhenium was examined, since rhenium is commonly used as a surrogate for technetium in waste vitrification studies. A number of glasses similar to Hanford Low Activity Waste (LAW) glasses were prepared under controlled atmospheres. The redox state of the glass was determined from the Fe(II)/Fe(III) ratio in the cooled glass, and the speciation of technetium and rhenium was determined by x-ray absorption fine structure (XAFS) spectroscopy. The behavior of rhenium and technetium during glass alteration was also examined using the vapor hydration test (VHT).

  13. The heavy top quark and supersymmetry

    SciTech Connect (OSTI)

    Hall, L.J.

    1997-01-01

    Three aspects of supersymmetric theories are discussed: electroweak symmetry breaking, the issues of flavor, and gauge unification. The heavy top quark plays an important, sometimes dominant, role in each case. Additional symmetries lead to extensions of the Standard Model which can provide an understanding for many of the outstanding problems of particle physics. A broken supersymmetric extension of spacetime allows electroweak symmetry breaking to follow from the dynamics of the heavy top quark; an extension of isospin provides a constrained framework for understanding the pattern of quark and lepton masses; and a grand unified extension of the Standard Model gauge group provides an elegant understanding of the gauge quantum numbers of the components of a generation. Experimental signatures for each of these additional symmetries are discussed.

  14. Axial couplings of heavy hadrons from domain-wall lattice QCD

    SciTech Connect (OSTI)

    W. Detmold, C.J.D. Lin, S. Meinel

    2011-12-01

    We calculate matrix elements of the axial current for static-light mesons and baryons in lattice QCD with dynamical domain wall fermions. We use partially quenched heavy hadron chiral perturbation theory in a finite volume to extract the axial couplings g{sub 1}, g{sub 2}, and g{sub 3} from the data. These axial couplings allow the prediction of strong decay rates and enter chiral extrapolations of most lattice results in the b sector. Our calculations are performed with two lattice spacings and with pion masses down to 227 MeV.

  15. Medium energy heavy ion operations at RHIC

    SciTech Connect (OSTI)

    Drees, K.A.; Ahrens, L.; Bai, M.; Beebe-Wang, J.; Blackler, I.M.C.; Blaskiewicz, M.; Brown, K.A.; Brennan, M.; Bruno, D.; Butler, J.; Carlson, C.; Connolly, R.; D'Ottavio, T.; Fischer, W.; Fu, W.; Gassner, D.; Harvey, M.; Hayes, T.; Huang, H.; Hulsart, R.; Ingrassia, P.; Kling, N.; Lafky, M.; Laster, J.; Lee, R.C.; Litvinenko, V.; Luo, Y.; MacKay, W.W.; Marr, G.; Mapes. M.; Marusic, A.; Mernick, K.; Michnoff, R.; Minty, M.; Montag, C.; Morris, J.; Naylor, C.; Nemesure, S.; Pilat, F.; Ptitsyn, V.; Robert-Demolaize, G.; Roser, T.; Sampson, P.; Satogata, T.; Schoefer, V.; Schultheiss, C.; Severino, F.; Shrey, T.; Smith, K.S.; Tepikian, S.; Thieberger, P.; Trbojevic, D.; Tsoupas, N.; Tuozzolo, J.; van Kuik, B.; Wilinski, M.; Zaltsman, A.; Zeno, K.; Zhang, S.Y.

    2011-03-28

    As part of the search for a phase transition or critical point on the QCD phase diagram, an energy scan including 5 different energy settings was performed during the 2010 RHIC heavy ion run. While the top beam energy for heavy ions is at 100 GeV/n and the lowest achieved energy setpoint was significantly below RHICs injection energy of approximately 10 GeV/n, we also provided beams for data taking in a medium energy range above injection energy and below top beam energy. This paper reviews RHIC experience and challenges for RHIC medium energy operations that produced full experimental data sets at beam energies of 31.2 GeV/n and 19.5 GeV/n. The medium energy AuAu run covered two beam energies, both above the RHIC injection energy of 9.8 GeV but well below the standard store energy of 100 GeV (see table 1). The low energy and full energy runs with heavy ions in FY10 are summarized in [1] and [2]. Stochastic Cooling ([3]) was only used for 100 GeV beams and not used in the medium energy run. The efficiency of the transition from 100 GeV operation to 31.2 GeV and then to 19.5 GeV was remarkable. Setup took 32 h and 19 h respectively for the two energy settings. The time in store, defined to be the percentage of time RHIC provides beams in physics conditions versus calendar time, was approximately 52% for the entire FY10 heavy ion run. In both medium energy runs it was well above this average, 68% for 31.5 GeV and 82% for 19.5 GeV. For both energies RHIC was filled with 111 bunches with 1.2 10{sup 9} and 1.3 10{sup 9} ions per bunch respectively.

  16. COMMISSIONING OF THE RELATIVISTIC HEAVY ION COLLIDER.

    SciTech Connect (OSTI)

    TRBOJEVIC,D.; AHRENS,L.; BLASKIEWICZ,M.; BRENNAN,M.; BAI,M.; CAMERON,P.; CARDONA,J.; CONNOLLY,R.; ET AL; TSOUPAS,N.; VAN ZEIJTS,J.

    2001-06-18

    This report describes in detail steps performed in bringing the Relativistic Heavy Ion Collider (RHIC) from the commissioning into the operational stage when collisions between 60 bunches of fully striped gold ions, were routinely provided. Corrections of the few power supplies connections by the beam measurements are described. Beam lifetime improvements at injection, along the acceleration are shown. The beam diagnostic results; like Schottky detector, beam profile monitor, beam position monitors, tune meter and others, are shown [1].

  17. Holifield Heavy Ion Research Facility: Users handbook

    SciTech Connect (OSTI)

    Auble, R.L.

    1987-01-01

    The primary objective of this handbook is to provide information for those who plan to carry out research programs at the Holifield Heavy Ion Research Facility (HHIRF) at Oak Ridge National Laboratory. The accelerator systems and experimental apparatus available are described. The mechanism for obtaining accelerator time and the responsibilities of those users who are granted accelerator time are described. The names and phone numbers of ORNL personnel to call for information about specific areas are given. (LEW)

  18. Process for upgrading heavy petroleum feedstock

    SciTech Connect (OSTI)

    Rudnick, L.R.

    1987-02-10

    A method is described for reducing the coking tendency of a heavy hydrocarbon feedstock in a non-hydrogenative catalytic cracking process. The process comprises contacting the feedstock prior to catalytic cracking with a free radical removing catalyst comprising a transition metal napthenate at a temperature below 350/sup 0/C. for a time sufficient to reduce the free radical concentration of the feedstock whereby the coking tendency of the feedstock to the catalytic cracking process is reduced.

  19. Co-processing of heavy oil

    SciTech Connect (OSTI)

    Khan, M.R.

    1995-12-31

    In co-processing of petroleum and coal, the petroleum fraction may serve as the {open_quotes}liquefaction solvent,{close_quotes} or hydrogen donor, and the aromatics present in the coal liquid may serve as hydrogen {open_quotes}shuttlers{close_quotes} by efficiently transferring hydrogen moieties to places where they are most deficient. The important advantages of co-processing include the following: (1) upgrading of heavy petroleum in a reaction with coal and (2) conversion of coal to synthetic crudes which could be further upgraded to a premium liquid fuel. Co-processing of coal with petroleum, heavy crudes, and residues through catalytic hydrogenation or solvent extraction have been extensively investigated. The studies were typically conducted in the temperature range of 450{degrees}-500{degrees}C under pressurized hydrogen; catalysts are generally also added for hydroconversion of the feedstocks. However, relatively little has been reported in the literature regarding co-processing of coal with heavy petroleum by simple pyrolysis. In this study, co-processing of heavy oil and coal at relatively middle conditions was conducted without the complicating influences of pressurized hydrogen or catalysts. The resulted demonstrate that there is a synergism during co-processing of petroleum and coal. This synergism enhances both the yield and quality of the liquid products. In general, liquids from co-processing the mixture contain a higher content of alkane/alkene, neutral aromatics, lower content of monophenols, and other oxygen containing compounds as compared to the liquids from coal alone. The liquid from the mixture also contains a higher content of naphthenic carbon and naphthenic rings/molecules than those from coal liquid. This suggests that the product from the mixture can be easily upgraded to a premium quality fuel.

  20. Lifecycle-analysis for heavy vehicles.

    SciTech Connect (OSTI)

    Gaines, L.

    1998-04-16

    Various alternative fuels and improved engine and vehicle systems have been proposed in order to reduce emissions and energy use associated with heavy vehicles (predominantly trucks). For example, oil companies have proposed improved methods for converting natural gas to zero-aromatics, zero-sulfur diesel fuel via the Fischer-Tropsch process. Major heavy-duty diesel engine companies are working on ways to simultaneously reduce particulate-matter and NOX emissions. The trend in heavy vehicles is toward use of lightweight materials, tires with lower rolling resistance, and treatments to reduce aerodynamic drag. In this paper, we compare the Mecycle energy use and emissions from trucks using selected alternatives, such as Fisher-Tropsch diesel fuel and advanced fuel-efficient engines. We consider heavy-duty, Class 8 tractor-semitrailer combinations for this analysis. The total life cycle includes production and recycling of the vehicle itself, extraction, processing, and transportation of the fuel itself, and vehicle operation and maintenance. Energy use is considered in toto, as well as those portions that are imported, domestic, and renewable. Emissions of interest include greenhouse gases and criteria pollutants. Angonne's Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET) model is used to generate per-vehicle fuel cycle impacts. Energy use and emissions for materials manufacturing and vehicle disposal are estimated by means of materials information from Argonne studies. We conclude that there are trade-offs among impacts. For example, the lowest fossil energy use does not necessarily result in lowest total energy use, and lower tailpipe emissions may not necessarily result in lower lifecycle emissions of all criteria pollutants.

  1. Heavy rains hamper Louisiana gas line

    SciTech Connect (OSTI)

    Horner, C.

    1983-06-01

    Despite heavy rains and flooding a 36-mile gas pipeline loop for Transcontinental Gas Pipe Line Corp. was completed from north of Starks (at the end of Transco's south Louisiana lateral) to the Lake Charles area. Somastic-coated, 42-in. grade X-60 pipe comprises 90% of the route. The contract included multiple 30-42 in. fabrications, installation of six 42-in. gate valves, and expansion of the Gillis compressor station.

  2. A Radiographic Technique With Heavy Ion Microbeams

    SciTech Connect (OSTI)

    Muscio, J.; Somacal, H.; Burlon, A. A.; Debray, M. E.; Valda, A. A.; Kreiner, A. J.; Kesque, J. M.; Minsky, D. M.

    2007-02-12

    In this work, we introduce a new technique to perform densitometric and multielemental analysis of samples at the same time using a simple detector with heavy ion micro-beams. It consists in the simultaneous analysis of X-rays induced in the sample and in a secondary target arranged behind the specimen. The X-rays originated in the secondary target are attenuated when crossing the specimen producing a radiographic image with a monochromatic source.

  3. Plant rhamnogalacturonan II complexation of heavy metal cations

    DOE Patents [OSTI]

    O'Neill, Malcolm A.; Pellerin, Patrice J. M.; Warrenfeltz, Dennis; Vidal, Stephane; Darvill, Alan G.; Albersheim, Peter

    1999-01-01

    The present invention provides rhamnogalacturonan-II (RG-II) and relates to its ability to complex specific multivalent heavy metal cations. In the presence of boric acid, RG-II monomers form dimers that are cross-linked by a borate ester. The yield of such borate ester cross-linked dimers of RG-II is enhanced in the presence of specific heavy metal cations. The present invention further relates to the utility of RG-II in assays for the detection of specific heavy metal contamination; as a reagent useful in the removal of specific heavy metal cations contaminating foods and liquids, for example, fish, wines, etc.; as a pharmaceutical composition useful as an antidote in specific heavy metal cation poisoning; as a treatment for the detoxification of specific heavy metal cations from blood and/or tissues; and in a method of remediation of waters and soils contaminated with specific heavy metal cations.

  4. Plant rhamnogalacturonan II complexation of heavy metal cations

    DOE Patents [OSTI]

    O`Neill, M.A.; Pellerin, P.J.M.; Warrenfeltz, D.; Vidal, S.; Darvill, A.G.; Albersheim, P.

    1999-03-02

    The present invention provides rhamnogalacturonan-II (RG-II) and relates to its ability to complex specific multivalent heavy metal cations. In the presence of boric acid, RG-II monomers form dimers that are cross-linked by a borate ester. The yield of such borate ester cross-linked dimers of RG-II is enhanced in the presence of specific heavy metal cations. The present invention further relates to the utility of RG-II in assays for the detection of specific heavy metal contamination; as a reagent useful in the removal of specific heavy metal cations contaminating foods and liquids, for example, fish, wines, etc.; as a pharmaceutical composition useful as an antidote in specific heavy metal cation poisoning; as a treatment for the detoxification of specific heavy metal cations from blood and/or tissues; and in a method of remediation of waters and soils contaminated with specific heavy metal cations. 15 figs.

  5. CP violation in heavy MSSM Higgs scenarios

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Carena, M.; Ellis, J.; Lee, J. S.; Pilaftsis, A.; Wagner, C. E. M.

    2016-02-18

    We introduce and explore new heavy Higgs scenarios in the Minimal Supersymmetric Standard Model (MSSM) with explicit CP violation, which have important phenomenological implications that may be testable at the LHC. For soft supersymmetry-breaking scales MS above a few TeV and a charged Higgs boson mass MH+ above a few hundred GeV, new physics effects including those from explicit CP violation decouple from the light Higgs boson sector. However, such effects can significantly alter the phenomenology of the heavy Higgs bosons while still being consistent with constraints from low-energy observables, for instance electric dipole moments. To consider scenarios with amore » charged Higgs boson much heavier than the Standard Model (SM) particles but much lighter than the supersymmetric particles, we revisit previous calculations of the MSSM Higgs sector. We compute the Higgs boson masses in the presence of CP violating phases, implementing improved matching and renormalization-group (RG) effects, as well as two-loop RG effects from the effective two-Higgs Doublet Model (2HDM) scale MH± to the scale MS. Here, we illustrate the possibility of non-decoupling CP-violating effects in the heavy Higgs sector using new benchmark scenarios named.« less

  6. Multiple Electron Stripping of Heavy Ion Beams

    SciTech Connect (OSTI)

    D. Mueller; L. Grisham; I. Kaganovich; R. L. Watson; V. Horvat; K. E. Zaharakis; Y. Peng

    2002-06-25

    One approach being explored as a route to practical fusion energy uses heavy ion beams focused on an indirect drive target. Such beams will lose electrons while passing through background gas in the target chamber, and therefore it is necessary to assess the rate at which the charge state of the incident beam evolves on the way to the target. Accelerators designed primarily for nuclear physics or high energy physics experiments utilize ion sources that generate highly stripped ions in order to achieve high energies economically. As a result, accelerators capable of producing heavy ion beams of 10 to 40 Mev/amu with charge state 1 currently do not exist. Hence, the stripping cross-sections used to model the performance of heavy ion fusion driver beams have, up to now, been based upon theoretical calculations. We have investigated experimentally the stripping of 3.4 Mev/amu Kr 7+ and Xe +11 in N2; 10.2 MeV/amu Ar +6 in He, N2, Ar and Xe; 19 MeV/amu Ar +8 in He, N2, Ar and Xe; 30 MeV He 1 + in He, N2, Ar and Xe; and 38 MeV/amu N +6 in He, N2, Ar and Xe. The results of these measurements are compared with the theoretical calculations to assess their applicability over a wide range of parameters.

  7. Heavy fermions in an optical lattice

    SciTech Connect (OSTI)

    Foss-Feig, Michael; Hermele, Michael; Gurarie, Victor; Rey, Ana Maria

    2010-11-15

    We employ a mean-field theory to study ground-state properties and transport of a two-dimensional gas of ultracold alkaline-earth-metal atoms governed by the Kondo lattice Hamiltonian plus a parabolic confining potential. In a homogenous system, this mean-field theory is believed to give a qualitatively correct description of heavy-fermion metals and Kondo insulators: It reproduces the Kondo-like scaling of the quasiparticle mass in the former and the same scaling of the excitation gap in the latter. In order to understand ground-state properties in a trap, we extend this mean-field theory via local-density approximation. We find that the Kondo insulator gap manifests as a shell structure in the trapped density profile. In addition, a strong signature of the large Fermi surface expected for heavy-fermion systems survives the confinement and could be probed in time-of-flight experiments. From a full self-consistent diagonalization of the mean-field theory, we are able to study dynamics in the trap. We find that the mass enhancement of quasiparticle excitations in the heavy-Fermi liquid phase manifests as slowing of the dipole oscillations that result from a sudden displacement of the trap center.

  8. Characterization of Venezuelan heavy oil vacuum residua

    SciTech Connect (OSTI)

    Izquierdo, A.; Carbognani, L.; Leon, V.; Parisi, A. )

    1988-06-01

    Characterization of abundant ''heavy'' feedstocks such as tar sands, heavy oils and vacuum residua will play a fundamental role in the use of these energy sources. Their physical and chemical properties vary from one feed to another, and this can have some consequences in their necessary upgrading processes. In this paper results on the characterization of 510/sup 0/C-vacuum residua (VR) obtained from Venezuelan Heavy and Medium Oils are presented. These are Morichal (Mo), Merey (Me), Guafita (Gu) and Barinas (Ba). The VR have all an API gravity between 3 and 6, more than 15% asphaltenes, metals above 200 ppm, as well as high contents of nitrogen, more than 6000 ppm, and sulphur, over 1%. It has been found that when these feeds are hydrotreated under similar conditions the processability improves in the order Ba

  9. Extending Penning trap mass measurements with SHIPTRAP to the heaviest elements

    SciTech Connect (OSTI)

    Block, M.; Ackermann, D.; Herfurth, F.; Hofmann, S.; Blaum, K.; Droese, C.; Marx, G.; Schweikhard, L.; Duellmann, Ch. E.; Eibach, M.; Eliseev, S.; Haettner, E.; Plass, W. R.; Scheidenberger, C.; Hessberger, F. P.; Ramirez, E. Minaya; Nesterenko, D.; and others

    2013-03-19

    Penning-trap mass spectrometry of radionuclides provides accurate mass values and absolute binding energies. Such mass measurements are sensitive indicators of the nuclear structure evolution far away from stability. Recently, direct mass measurements have been extended to the heavy elements nobelium (Z=102) and lawrencium (Z=103) with the Penning-trap mass spectrometer SHIPTRAP. The results probe nuclear shell effects at N=152. New developments will pave the way to access even heavier nuclides.

  10. Role of short range correlations on nuclear matrix elements of neutrinoless double beta decay

    SciTech Connect (OSTI)

    Chandra, R. [Department of Applied Physics, B. B. Ambedkar University, Lucknow - 226025 (India); Chaturvedi, K. [Department of Physics, Bundelkhand University, Jhansi-284128 (India); Rath, P. K. [Department of Physics, University of Lucknow, Lucknow-226007 (India); Raina, P. K. [Department of Physics, Indian Institute of Technology, Ropar, Rupnagar - 140001, Punjab (India)

    2011-11-23

    Employing four different parametrization of the pairing plus multipolar type of effective two-body interaction and three different parametrizations of Jastrow-type of short range correlations, the uncertainties in the nuclear transition matrix elements due to the exchange of light as well as heavy Majorana neutrino for the 0{sup +}{yields}0{sup +} transition of neutrinoless positron {beta}{beta} decay are estimated in the PHFB model.

  11. Phase Chemistry of Tank Sludge Residual Components

    SciTech Connect (OSTI)

    KRUMHANSL,JAMES L.; LIU,JUN; NAGY,KATHRYN L.; BRADY,PATRICK V.

    1999-11-29

    We are attempting to understand the solid phase chemistry of the high level nuclear waste (HLW) stored in tanks at Hanford. Because this waste is compositionally complex, our approach is to study experimentally the aging dynamics of simplified systems whose bulk chemistry approximates that of the tank sludges. After a basic understanding of these dynamics has been attained we plan to increase the compositional complexities one component at a time, in order to assess the influence of each component. Results will allow for reliable prediction of sludge phase chemistry over a range of sludge compositions. Iron and aluminum comprise the bulk of most HLW sludges, so we chose to begin by studying the behavior of iron-aluminum systems. Fe/Al ratios were chosen to approximate those relevant to the solutions that produced the sludge. Aluminum and iron concentrations in the various process fluids are summarized and compared to our experimental starting solutions in Table 1 (process solution data from Krumhansl, personal communication, 1998). Our low aluminum experiments serve as direct analogues to both Bismuth Phosphate and low-Fe PUREX waste. Cornell and Giovanoli (1985) found that, in a pure iron system at 70 C, a 10-fold or even 50-fold increase in suspension concentration had only very slight effects on the final aged products. Since our experiments have similar Al/Fe ratios to some high Fe-PUREX process solutions our results are probably relevant to those wastes as well. However, our results may not apply to the high-Fe and high-Al PUREX wastes, as discussed below. The high Al experiments were designed specifically to simulate REDOX waste.

  12. HARNESSING THE CHEMISTRY OF CO2

    SciTech Connect (OSTI)

    Louie, Janis

    2010-05-11

    Our research program is broadly focused on activating CO{sub 2} through the use of organic and organometallic based catalysts. Some of our methods have centered on annulation reactions of unsaturated hydrocarbons (and carbonyl substrates) to provide a diverse array of carbocycles and heterocycles. We use a combination of catalyst discovery and optimization in conjunction with classical physical organic chemistry to elucidate the key mechanistic features of the cycloaddition reactions such that the next big advances in catalyst development can be made. Key to all of our cycloaddition reactions is the use of a sterically hindered, electron donating N heterocyclic carbene (NHC) ligand, namely IPr (or SIPr), in conjunction with a low valent nickel pre-catalyst. The efficacy of this ligand is two-fold: (1) the high {delta}-donating ability of the NHC increases the nucleophilicity of the metal center which thereby facilitates interaction with the electrophilic carbonyl and (2) the steric hindrance prevents an otherwise competitive side reaction involving only the alkyne substrate. Such a system has allowed for the facile cycloaddition to prepare highly functionalized pyrones, pyridones, pyrans, as well as novel carbocycles. Importantly, all reactions proceed under extremely mild conditions (room temperature, atmospheric pressures, and short reaction times), require only catalytic amounts of Ni/NHC and readily available starting materials, and afford annulated products in excellent yields. Our current focus revolves around understanding the fundamental processes that govern these cycloadditions such that the next big advance in the cyclization chemistry of CO{sub 2} can be made. Concurrent to our annulation chemistry is our investigation of the potential for imidazolylidenes to function as thermally-actuated CO{sub 2} sequestering and delivery agents.

  13. Cooperative Research in C1 Chemistry

    SciTech Connect (OSTI)

    Gerald P. Huffman

    2000-10-27

    C1 chemistry refers to the conversion of simple carbon-containing materials that contain one carbon atom per molecule into valuable products. The feedstocks for C1 chemistry include natural gas, carbon dioxide, carbon monoxide, methanol and synthesis gas (a mixture of carbon monoxide and hydrogen). Synthesis gas, or syngas, is produced primarily by the reaction of natural gas, which is principally methane, with steam. It can also be produced by gasification of coal, petroleum coke, or biomass. The availability of syngas from coal gasification is expected to increase significantly in the future because of increasing development of integrated gasification combined cycle (IGCC) power generation. Because of the abundance of remote natural gas, the advent of IGCC, and environmental advantages, C1 chemistry is expected to become a major area of interest for the transportation fuel and chemical industries in the relatively near future. The CFFLS will therefore perform a valuable national service by providing science and engineering graduates that are trained in this important area. Syngas is the source of most hydrogen. Approximately 10 trillion standard cubic feet (SCF) of hydrogen are manufactured annually in the world. Most of this hydrogen is currently used for the production of ammonia and in a variety of refining and chemical operations. However, utilization of hydrogen in fuel cells is expected to grow significantly in the next century. Syngas is also the feedstock for all methanol and Fischer-Tropsch plants. Currently, world consumption of methanol is over 25 million tons per year. There are many methanol plants in the U.S. and throughout the world. Methanol and oxygenated transportation fuel products play a significant role in the CFFLS C1 program. Currently, the only commercial Fischer-Tropsch plants are overseas, principally in South Africa (SASOL). However, new plants are being built or planned for a number of locations. One possible location for future F-T plant development in the U.S. is in the Alaskan oil fields.

  14. Method for detecting an element

    DOE Patents [OSTI]

    Blackwood, Larry G.; Reber, Edward L.; Rohde, Kenneth W.

    2007-02-06

    A method for detecting an element is disclosed and which includes the steps of providing a gamma-ray spectrum which depicts, at least in part, a test region having boundaries, and which has a small amount of the element to be detected; providing a calculation which detects the small amount of the element to be detected; and providing a moving window and performing the calculation within the moving window, and over a range of possible window boundaries within the test region to determine the location of the optimal test region within the gamma-ray spectrum.

  15. Heavy-quark production in ultrarelativistic heavy-ion collisions within a partonic transport model

    SciTech Connect (OSTI)

    Uphoff, Jan; Fochler, Oliver; Greiner, Carsten; Xu Zhe

    2010-10-15

    The production and space-time evolution of charm and bottom quarks in nucleus-nucleus collisions at the BNL Relativistic Heavy Ion Collider (RHIC) and the CERN Large Hadron Collider (LHC) are investigated with the partonic transport model BAMPS (Boltzmann approach of multiparton scatterings). Heavy quarks, produced in primary hard parton scatterings during nucleon-nucleon collisions, are sampled using the Monte Carlo event generator pythia or the leading-order minijet model in conjunction with the Glauber model, revealing a strong sensitivity on the parton distribution functions, scales, and heavy-quark mass. In a comprehensive study exploring different charm masses, K factors, and possible initial gluon conditions, secondary production and the evolution of heavy quarks are examined within a fully dynamic BAMPS simulation for central heavy-ion collisions at RHIC and LHC. Although charm production in the quark-gluon plasma can be neglected at RHIC, it is significant at LHC but very sensitive to the initial conditions and the charm mass. Bottom production in the quark-gluon plasma, however, is negligible both at RHIC and LHC.

  16. The B*Bπ coupling using relativistic heavy quarks

    SciTech Connect (OSTI)

    Flynn, J. M.; Fritzsch, P.; Kawanai, T.; Lehner, C.; Samways, B.; Sachrajda, C. T.; Van de Water, R. S.; Witzel, O.

    2015-06-23

    We report on a calculation of the B*Bπ coupling in lattice QCD. The strong matrix element (Bπ|B*) is directly related to the leading order low-energy constant in heavy meson chiral perturbation theory (HMΧPT) for B mesons. We carry out our calculation directly at the b-quark mass using a non-perturbatively tuned clover action that controls discretization effects of order |pa| and (ma)n for all n. Our analysis is performed on RBC/UKQCD gauge configurations using domain-wall fermions and the Iwasaki gauge action at two lattice spacings of a–1 = 1.729(25) GeV, a–1 = 2.281 (28) GeV, and unitary pion masses down to 290 MeV. We achieve good statistical precision and control all systematic uncertainties, giving a final result for the HMΧPT coupling gb = 0.56(3)stat(7)sys in the continuum and at the physical light-quark masses. Furthermore, this is the first calculation performed directly at the physical b-quark mass and lies in the region one would expect from carrying out an interpolation between previous results at the charm mass and at the static point.

  17. Radiation Chemistry of Advanced TALSPEAK Flowsheet

    SciTech Connect (OSTI)

    Mincher, Bruce; Peterman, Dean; Mcdowell, Rocklan; Olson, Lonnie; Lumetta, Gregg J.

    2013-08-28

    This report summarizes the results of initial experiments designed to understand the radiation chemistry of an Advanced TALSPEAK process for separating trivalent lanthanides form the actinides. Biphasic aerated samples were irradiated and then analyzed for post-irradiation constituent concentrations and solvent extraction distribution ratios. The effects of irradiation on the TALSPEAK and Advanced TALSPEAK solvents were similar, with very little degradation of the organic phase extractant. Decomposition products were detected, with a major product in common for both solvents. This product may be responsible for the slight increase in distribution ratios for Eu and Am with absorbed dose, however; separation factors were not greatly affected.

  18. Advances in Glass Chemistry - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    About Us Projects & Facilities Waste Treatment Plant Advances in Glass Chemistry About Us 100 Area 118-K-1 Burial Ground 200 Area 222-S Laboratory 242-A Evaporator 300 Area 324 Building 325 Building 400 Area/Fast Flux Test Facility 618-10 and 618-11 Burial Grounds 700 Area B Plant B Reactor C Reactor Canister Storage Building and Interim Storage Area Canyon Facilities Cold Test Facility D and DR Reactors Effluent Treatment Facility Environmental Restoration Disposal Facility F Reactor H

  19. FUEL ELEMENTS FOR NEUTRONIC REACTORS

    DOE Patents [OSTI]

    Foote, F.G.; Jette, E.R.

    1963-05-01

    A fuel element for a nuclear reactor is described that consists of a jacket containing a unitary core of fissionable material and a filling of a metal of the group consisting of sodium and sodium-potassium alloys. (AEC)

  20. Environmental research on actinide elements

    SciTech Connect (OSTI)

    Pinder, J.E. III; Alberts, J.J.; McLeod, K.W.; Schreckhise, R.G.

    1987-08-01

    The papers synthesize the results of research sponsored by DOE's Office of Health and Environmental Research on the behavior of transuranic and actinide elements in the environment. Separate abstracts have been prepared for the 21 individual papers. (ACR)

  1. Final Report: Ionization chemistry of high temperature molecular fluids

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Technical Report: Final Report: Ionization chemistry of high temperature molecular fluids Citation Details In-Document Search Title: Final Report: Ionization chemistry of high temperature molecular fluids With the advent of coupled chemical/hydrodynamic reactive flow models for high explosives, understanding detonation chemistry is of increasing importance to DNT. The accuracy of first principles detonation codes, such as CHEETAH, are dependent on an

  2. Sandia National Laboratories: Careers: Chemistry & Chemical Engineering

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry & Chemical Engineering Chemistry research photo Sandia's Combustion Research Facility pioneered the use of chemical-imaging tools, such as laser diagnostics, for combustion applications. Chemists at Sandia conduct research and development at the interface between biology, synthetic chemistry, and surface science to deliver prototype solutions in diverse applications. They provide knowledge about materials structure, properties, and performance and about the processes to produce,

  3. Training April 5 - Material Science and Chemistry Applications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    April 5 Training April 5 - Material Science and Chemistry Applications March 9, 2011 by Francesca Verdier Training on "Using Chemistry and Material Sciences Applications" will be held April 5, presented simultaneously on the web and at NERSC. See Chemistry and Material Sciences Applications. Subscribe via RSS Subscribe Browse by Date May 2016 April 2016 January 2016 December 2015 November 2015 October 2015 September 2015 August 2015 July 2015 April 2015 March 2015 January 2015 December

  4. NERSC training events: Data Transfer and Archiving; Chemistry and Material

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Sciences Applications training events: Data Transfer and Archiving; Chemistry and Material Sciences Applications NERSC training events: Data Transfer and Archiving; Chemistry and Material Sciences Applications February 21, 2011 by Richard Gerber NERSC will present two training events in March: Data Transfer and Archiving March 8, 2011 10:00-12:30 Pacific Time Using Chemistry and Material Sciences Applications at NERSC March 22, 2011 10:00-12:00 Pacific Time Each event will be held

  5. Chemistry and Transport - Combustion Energy Frontier Research Center

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry and Transport Chemistry and Transport The overall goal of the flame chemistry working group is to obtain fundamental combustion and emission properties of low and high pressure flames, to validate kinetic and transport models, and to develop accurate and computationally efficient models capable of predicting turbulent combustion of future transportation fuels. Experimental data of laminar and turbulent flame speeds, flame structures, extinction/ignition limits, and soot/NOx emissions

  6. Chemistry: Mechanism and Experiment - Combustion Energy Frontier Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center Chemistry: Mechanism and Experiment Chemistry: Mechanism and Experiment The Mechanism and Experiment DWG uses an array of advanced experimental apparatus to probe the combustion chemistry of fuels. Primary apparatus used include shock tube (Hanson/Davidson), variable-pressure turbulent flow reactor (Dryer), rapid compression machine (Sung), low-pressure burner stabilized flame coupled with synchrotron photoionization mass spectrometry (Hansen, Dryer), atmospheric-pressure burner

  7. Symposium on the Physical Chemistry of Solar Energy Conversion,

    Office of Scientific and Technical Information (OSTI)

    Indianapolis American Chemical Society Meetings, Fall 2013 (Technical Report) | SciTech Connect Symposium on the Physical Chemistry of Solar Energy Conversion, Indianapolis American Chemical Society Meetings, Fall 2013 Citation Details In-Document Search Title: Symposium on the Physical Chemistry of Solar Energy Conversion, Indianapolis American Chemical Society Meetings, Fall 2013 The Symposium on the Physical Chemistry of Solar Energy Conversion at the Fall ACS Meeting in Indianapolis, IN

  8. Physical Organic Chemistry of Reactive Intermediates | The Ames...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    by the photolysis of sulfur bearing precursors. Techniques and approaches involve synthesis, spectroscopy, and computational chemistry. The group also has some interest in...

  9. Browse by Discipline -- E-print Network Subject Pathways: Chemistry...

    Office of Scientific and Technical Information (OSTI)

    Barnes, Bill (Bill Barnes) - School of Physics, University of Exeter Barrett, Christopher (Christopher Barrett) - Department of Chemistry, McGill University Barron, Annelise E. ...

  10. The Chemistry and Applications of Metal-Organic Frameworks |...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Chemistry and Applications of Metal-Organic Frameworks Previous Next List Hiroyasu Furukawa, Kyle E. Cordova, Michael O'Keeffe, Omar M. Yaghi, Science, 341, 1230444 (2013) DOI:...

  11. Reductant Chemistry during LNT Regeneration for a Lean Gasoline...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reductant Chemistry during LNT Regeneration for a Lean Gasoline Engine Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in ...

  12. Redox chemistry and metal-insulator transitions intertwined in...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Redox chemistry and metal-insulator transitions intertwined in a nano-porous material Previous Next List Sergey N. Maximoff and Berend Smit, Nature Communications 5, 4032 (2014)...

  13. Solar Energy Education. Renewable energy activities for chemistry...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Citation Details In-Document Search Title: Solar Energy Education. Renewable energy activities for chemistry and physics You are accessing a document from the Department of ...

  14. Ultrafast Shock Initiation of Exothermic Chemistry in Hydrogen...

    Office of Scientific and Technical Information (OSTI)

    Language: English Subject: 71 CLASSICAL AND QUANTUMM MECHANICS, GENERAL PHYSICS; 36 MATERIALS SCIENCE; 42 ENGINEERING; 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY

  15. January 2013 Most Viewed Documents for Chemistry | OSTI, US Dept...

    Office of Scientific and Technical Information (OSTI)

    January 2013 Most Viewed Documents for Chemistry Dialkylenecarbonate-Bridged Polysilsesquioxanes. Hybrid Organic-Inorganic Sol-Gels with a Thermally Labile Bridging Group Assink, ...

  16. Control of Slag Chemistry for the Reduction of Viscosity and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of slag viscosity and refractory wear in gasification systems. Application of this methodology to control slag chemistry will minimize refractory corrosion caused by carbon...

  17. March 2015 Most Viewed Documents for Chemistry | OSTI, US Dept...

    Office of Scientific and Technical Information (OSTI)

    ... Dept. of Nuclear Chemistry (1995) 40 Recycling galvanized steel: Operating experience and benefits Dudek, F.J.; Daniels, E.J. Argonne National Lab., IL (United States); Morgan, ...

  18. Browse by Discipline -- E-print Network Subject Pathways: Chemistry...

    Office of Scientific and Technical Information (OSTI)

    Qi, Limin (Limin Qi) - College of Chemistry, Peking University Qiao, Pizhong (Pizhong Qiao) - Department of Civil Engineering, University of Akron Qin, Lu-Chang (Lu-Chang Qin) - ...

  19. Symposium on the Physical Chemistry of Solar Energy Conversion...

    Office of Scientific and Technical Information (OSTI)

    Chemical Society Meetings, Fall 2013 Citation Details In-Document Search Title: Symposium on the Physical Chemistry of Solar Energy Conversion, Indianapolis American Chemical ...

  20. High Level Computational Chemistry Approaches to the Prediction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energetic Properties of Chemical Hydrogen Storage Systems High Level Computational Chemistry Approaches to the Prediction of Energetic Properties of Chemical Hydrogen Storage ...

  1. Browse by Discipline -- E-print Network Subject Pathways: Chemistry...

    Office of Scientific and Technical Information (OSTI)

    - Division of Material Sciences, California Institute of Technology Eisenthal, Kenneth B. (Kenneth B. Eisenthal) - Department of Chemistry, Columbia University El-Naggar, Moh (Moh ...

  2. Atomic Scale Imaging of the Electronic Structure and Chemistry...

    Office of Scientific and Technical Information (OSTI)

    Imaging of the Electronic Structure and Chemistry of Graphene and Its Precursors on Metal Surfaces Re-direct Destination: Executive Summary of Final Report for Award...

  3. Characteristics and Effects of Lubricant Additive Chemistry and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Service Life and Vehicle Fuel Economy Characteristics and Effects of Lubricant Additive Chemistry and Exhaust Conditions on Diesel Particulate Filter Service Life and Vehicle ...

  4. ARM - Field Campaign - MASRAD: Cloud Condensate Nuclei Chemistry...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cloud Condensate Nuclei Chemistry Measurements Campaign Links AMF Point Reyes Website ARM Data Discovery Browse Data Related Campaigns MArine Stratus Radiation Aerosol and Drizzle...

  5. Screening of Electrode Materials & Cell Chemistries and Streamlining...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review ... Materials & Cell Chemistries and Streamlining Optimization of Electrodes Validation of

  6. Screening of Electrode Materials & Cell Chemistries and Streamlining...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit ... Screen Electrode Materials & Cell Chemistries and Streamlining Optimization of Electrode ...

  7. Computer-Aided Construction of Combustion Chemistry Models

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Constructing Accurate Combustion Chemistry Models: Butanols William H. Green & Michael Harper MIT Dept. of Chem. Eng. CEFRC Annual Meeting, Sept. 2010 The people who did this work:...

  8. Experience from the Short Course on Introduction to Nuclear Chemistry...

    Office of Environmental Management (EM)

    Short Course - Overview & Lessons Learned David Kosson, Vanderbilt & CRESP Introduction to Nuclear Chemistry and Fuel Cycle Separations December 16-18, 2008 Vanderbilt University...

  9. January 23, 2016: Science on Saturday: Using Physics and Chemistry...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    23, 2016 - 09:30 January 23, 2016: Science on Saturday: Using Physics and Chemistry to Understand the Genome PPPL, MBG Auditorium Speaker: Professor Mary Jo Ondrechen Northeastern...

  10. Development of a Stiffness-Based Chemistry Load Balancing Scheme...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of a Stiffness-Based Chemistry Load Balancing Scheme, and Optimization of IO and Communication, to Enable Massively Parallel High-Fidelity Internal Combustion Engine Simulations...

  11. Will Dichtel > Associate ProfessorChemistry and Chemical Biology...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    precise organic materials. Projects in the Dichtel Group involve organic and polymer chemistry, solution and solid-state characterization, nanofabrication, and electronic...

  12. Methodologies for Reservoir Characterization Using Fluid Inclusion Gas Chemistry

    Broader source: Energy.gov [DOE]

    Methodologies for Reservoir Characterization Using Fluid Inclusion Gas Chemistry presentation at the April 2013 peer review meeting held in Denver, Colorado.

  13. Interfacial Chemistry of III-V Semiconductors for Photoelectrochemical...

    Office of Scientific and Technical Information (OSTI)

    Photoelectrochemical Water Splitting Citation Details In-Document Search Title: Interfacial Chemistry of III-V Semiconductors for Photoelectrochemical Water Splitting You are ...

  14. Coagulation chemistries for silica removal from cooling tower...

    Office of Scientific and Technical Information (OSTI)

    removal from cooling tower water. Citation Details In-Document Search Title: Coagulation chemistries for silica removal from cooling tower water. You are accessing a ...

  15. Copper ionic liquids: Tunable ligand and anion chemistries to...

    Office of Scientific and Technical Information (OSTI)

    to control electrochemistry and deposition morphology. Citation Details In-Document Search Title: Copper ionic liquids: Tunable ligand and anion chemistries to control ...

  16. Time-Resolved Optical Measurements of Shock-Induced Chemistry...

    Office of Scientific and Technical Information (OSTI)

    Title: Time-Resolved Optical Measurements of Shock-Induced Chemistry in Energetic Materials. Abstract not provided. Authors: Wixom, Ryan R. ; Knepper, Robert ; Tappan, Alexander S. ...

  17. Radiation Chemistry and Photochemistry of Ionic Liquids

    SciTech Connect (OSTI)

    Wishart, J.F.; Takahaski, K.

    2010-12-01

    As our understanding of ionic liquids and their tunable properties has grown, it is possible to see many opportunities for ionic liquids to contribute to the sustainable use of energy. The potential safety and environmental benefits of ionic liquids, as compared to conventional solvents, have attracted interest in their use as processing media for the nuclear fuel cycle. Therefore, an understanding of the interactions of ionizing radiation and photons with ionic liquids is strongly needed. However, the radiation chemistry of ionic liquids is still a relatively unexplored topic although there has been a significant increase in the number of researchers in the field recently. This article provides a brief introduction to ionic liquids and their interesting properties, and recent advances in the radiation chemistry and photochemistry of ionic liquids. In this article, we will mainly focus on excess electron dynamics and radical reaction dynamics. Because solvation dynamics processes in ionic liquids are much slower than in molecular solvents, one of the distinguishing characteristics is that pre-solvated electrons play an important role in ionic liquid radiolysis. It will be also shown that the reaction dynamics of radical ions is significantly different from that observed in molecular solvents because of the Coulombic screening effects and electrostatic interactions in ionic liquids.

  18. Turbulence-chemistry interactions in reacting flows

    SciTech Connect (OSTI)

    Barlow, R.S.; Carter, C.D.

    1993-12-01

    Interactions between turbulence and chemistry in nonpremixed flames are investigated through multiscalar measurements. Simultaneous point measurements of major species, NO, OH, temperature, and mixture fraction are obtained by combining spontaneous Raman scattering, Rayleigh scattering, and laser-induced fluorescence (LIF). NO and OH fluorescence signals are converted to quantitative concentrations by applying shot-to-shot corrections for local variations of the Boltzmann fraction and collisional quenching rate. These measurements of instantaneous thermochemical states in turbulent flames provide insights into the fundamental nature of turbulence-chemistry interactions. The measurements also constitute a unique data base for evaluation and refinement of turbulent combustion models. Experimental work during the past year has focused on three areas: (1) investigation of the effects of differential molecular diffusion in turbulent combustion: (2) experiments on the effects of Halon CF{sub 3}Br, a fire retardant, on the structure of turbulent flames of CH{sub 4} and CO/H{sub 2}/N{sub 2}; and (3) experiments on NO formation in turbulent hydrogen jet flames.

  19. Studies on the content of heavy metals in Aries River using ICP-MS

    SciTech Connect (OSTI)

    Voica, Cezara Kovacs, Melinda Feher, Ioana

    2013-11-13

    Among the industrial branches, the mining industry has always been an important source of environmental pollution, both aesthetically and chemically. Through this paper results of ICP-MS characterization of Aries River Basin are reported. Mining activities from this area has resulted in contamination of environment and its surrounding biota. This is clearly evidenced in analyzed water samples, especially from Baia de Aries site where increased amount of trace elements as Cr, Zn, As, Se, Cd, Pb and U were founded. Also in this site greater amount of rare earth elements was evidenced also. Through monitoring of Aries River from other non-mining area it was observed that the quantitative content of heavy metals was below the maximum permissible levels which made us to conclude that the water table wasn't seriously affected (which possibly might be attributed to the cessation of mining activities in this area from a few years ago)

  20. Heavy Ion Fusion Accelerator Research (HIFAR) half-year report, October 1, 1988--March 31, 1989

    SciTech Connect (OSTI)

    Not Available

    1989-06-01

    The basic objective of the Heavy Ion Fusion Accelerator Research (HIFAR) program is to assess the suitability of heavy ion accelerators as igniters for Inertial Confinement Fusion (ICF). A specific accelerator technology, the induction linac, has been studied at the Lawrence Berkeley Laboratory and has reached the point at which its viability for ICF applications can be assessed over the next few years. The HIFAR program addresses the generation of high-power, high-brightness beams of heavy ions, the understanding of the scaling laws in this novel physics regime, and the validation of new accelerator strategies, to cut costs. Key elements to be addressed include: beam quality limits set by transverse and longitudinal beam physics; development of induction accelerating modules, and multiple-beam hardware, at affordable costs; acceleration of multiple beams with current amplification --both new features in a linac -- without significant dilution of the optical quality of the beams; and final bunching, transport, and accurate focusing on a small target.

  1. A review of the global emissions, transport and effects of heavy metals in the environment

    SciTech Connect (OSTI)

    Friedman, J.R.; Ashton, W.B.; Rapoport, R.D.

    1993-06-01

    The purpose of this report is to describe the current state of knowledge regarding the sources and quantities of heavy metal emissions, their transport and fate, their potential health and environmental effects, and strategies to control them. The approach is to review the literature on this topic and to consult with experts in the field. Ongoing research activities and research needs are discussed. Estimates of global anthropogenic and natural emissions indicate that anthropogenic emissions are responsible for most of the heavy metals released into the atmosphere and that industrial activities have had a significant impact on the global cycling of trace metals. The largest anthropogenic sources of trace metals are coal combustion and the nonferrous metal industry. Atmospheric deposition is an important pathway by which trace metals enter the environment. Atmospheric deposition varies according to the solubility of the element and the length of time it resides in the atmosphere. Evidence suggests that deposition is influenced by other chemicals in the atmosphere, such as ozone and sulfur dioxide. Trace metals also enter the environment through leaching. Existing emissions-control technologies such as electrostatic precipitators, baghouses, and scrubbers are designed to remove other particulates from the flue gas of coal-fired power plants and are only partially effective at removing heavy metals. Emerging technologies such as flue gas desulfurization, lignite coke, and fluidized bed combustion could further reduce emissions. 108 refs.

  2. Lattice cell and full core physics of internally cooled annular fuel in heavy water moderated reactors

    SciTech Connect (OSTI)

    Armstrong, J.; Hamilton, H.; Hyland, B.

    2013-07-01

    A program is underway at Atomic Energy of Canada Limited (AECL) to develop a new fuel bundle concept to enable greater burnups for PT-HWR (pressure tube heavy water reactor) cores. One option that AECL is investigating is an internally cooled annular fuel (ICAF) element concept. ICAF contains annular cylindrical pellets with cladding on the inner and outer diameters. Coolant flows along the outside of the element and through the centre. With such a concept, the maximum fuel temperature as a function of linear element rating is significantly reduced compared to conventional, solid-rod type fuel. The preliminary ICAF bundle concept considered in this study contains 24 half-metre long internally cooled annular fuel elements and one non-fuelled centre pin. The introduction of the non-fuelled centre pin reduces the coolant void reactivity (CVR), which is the increase in reactivity that occurs on voiding the coolant in accident scenarios. Lattice cell and full core physics calculations of the preliminary ICAF fuel bundle concept have been performed for medium burnups of approximately 18 GWd/tU using WIMS-AECL and reactor fuel simulation program (RFSP). The results will be used to assist in concept configuration optimization. The effects of radial and axial core power distributions, linear element power ratings, refuelling rates and operational power ramps have been analyzed. The results suggest that burnups of greater than 18 GWd/tU can be achieved in current reactor designs. At approximately 18 GWd/tU, expected maximum linear element ratings in a PT-HWR with online-refuelling are approximately 90 kW/m. These conditions would be prohibitive for solid-rod fuel, but may be possible in ICAF fuel given the reduced maximum fuel temperature as a function of linear element rating. (authors)

  3. Heavy flavour phenomenology from lattice QCD

    SciTech Connect (OSTI)

    Gamiz, Elvira; /Fermilab

    2010-01-01

    Heavy quark quantities are useful for testing lattice techniques against well known experimental results, as well as for testing the StandardModel (SM), and searching for physics beyond the SM. I review the results of recent lattice calculations relevant for this program including those of B and D decay constants and semileptonic decay form factors, and neutral B mixing. The impact of future improvements of lattice results on the clarification of the origin of several disagreements between theory and experiment which are starting to show up are briefly discussed.

  4. Process for upgrading heavy hydrocarbonaceous oils

    SciTech Connect (OSTI)

    Fisher, I.P.; Souhrada, F.; Woods, H.J.

    1981-10-13

    An integrated upgrading process is disclosed which can be used to lower the specific gravity, viscosity and boiling range of heavy, viscous hydrocarbonaceous oil . The process consists of fractionally distilling the oil, treating its residuum with a hydrogen donor material under hydrocracking conditions, fractionally distilling the effluent from the hydrocracking zone and rehydrogenating that portion boiling from about 180/sup 0/ C to 350/sup 0/ C for recycling to the hydrocracking zone. The liquid portion of the oil not recycled can be recombined into a reconstituted crude suitable for transporting by normal crude pipelines.

  5. Pipeline transportation of heavy crude oil

    SciTech Connect (OSTI)

    Kessick, M.A.; St. Denis, C.E.

    1982-08-10

    Heavy crude oils are transported by pipeline from deposit location to a remote upgrading location by emulsifying the crude oil using deaerated sodium hydroxide solution, conveying the oilin-water emulsion through the pipeline, and recovery of the oil from the oil-in-water emulsion by inverting the emulsion and dewatering the resulting water-in-oil emulsion. The emulsion inversion may be effected using slaked lime, resulting in recovery of a substantial proportion of the sodium hydroxide used in the initial emulsification. The sodium hydroxide solution may be recycled by a separate pipeline for reuse or treated for discharge.

  6. HEAVY WATER COMPONENTS TEST REACTOR DECOMMISSIONING

    SciTech Connect (OSTI)

    Austin, W.; Brinkley, D.

    2011-10-13

    The Heavy Water Components Test Reactor (HWCTR) Decommissioning Project was initiated in 2009 as a Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) Removal Action with funding from the American Recovery and Reinvestment Act (ARRA). This paper summarizes the history prior to 2009, the major D&D activities, and final end state of the facility at completion of decommissioning in June 2011. The HWCTR facility was built in 1961, operated from 1962 to 1964, and is located in the northwest quadrant of the Savannah River Site (SRS) approximately three miles from the site boundary. The HWCTR was a pressurized heavy water test reactor used to develop candidate fuel designs for heavy water power reactors. In December of 1964, operations were terminated and the facility was placed in a standby condition as a result of the decision by the U.S. Atomic Energy Commission to redirect research and development work on heavy water power reactors to reactors cooled with organic materials. For about one year, site personnel maintained the facility in a standby status, and then retired the reactor in place. In the early 1990s, DOE began planning to decommission HWCTR. Yet, in the face of new budget constraints, DOE deferred dismantlement and placed HWCTR in an extended surveillance and maintenance mode. The doors of the reactor facility were welded shut to protect workers and discourage intruders. In 2009 the $1.6 billion allocation from the ARRA to SRS for site footprint reduction at SRS reopened the doors to HWCTR - this time for final decommissioning. Alternative studies concluded that the most environmentally safe, cost effective option for final decommissioning was to remove the reactor vessel, both steam generators, and all equipment above grade including the dome. The transfer coffin, originally above grade, was to be placed in the cavity vacated by the reactor vessel and the remaining below grade spaces would be grouted. Once all above equipment including the dome was removed, a concrete cover was to be placed over the remaining footprint and the groundwater monitored for an indefinite period to ensure compliance with environmental regulations.

  7. Novel Aryne Chemistry in Organic Synthesis

    SciTech Connect (OSTI)

    Zhijian Liu

    2006-12-12

    Arynes are among the most intensively studied systems in chemistry. However, many aspects of the chemistry of these reactive intermediates are not well understood yet and their use as reagents in synthetic organic chemistry has been somewhat limited, due to the harsh conditions needed to generate arynes and the often uncontrolled reactivity exhibited by these species. Recently, o-silylaryl triflates, which can generate the corresponding arynes under very mild reaction conditions, have been found very useful in organic synthesis. This thesis describes several novel and useful methodologies by employing arynes, which generate from o-silylaryl triflates, in organic synthesis. An efficient, reliable method for the N-arylation of amines, sulfonamides and carbamates, and the O-arylation of phenols and carboxylic acids is described in Chapter 1. Amines, sulfonamides, phenols, and carboxylic acids are good nucleophiles, which can react with arynes generated from a-silylaryl triflates to afford the corresponding N- and O-arylated products in very high yields. The regioselectivity of unsymmetrical arynes has also been studied. A lot of useful, functional groups can tolerate our reaction conditions. Carbazoles and dibenzofurans are important heteroaromatic compounds, which have a variety of biological activities. A variety of substituted carbazoles and dibenzofwans are readily prepared in good to excellent yields starting with the corresponding o-iodoanilines or o-iodophenols and o-silylaryl triflates by a treatment with CsF, followed by a Pd-catalyzed cyclization, which overall provides a one-pot, two-step process. By using this methodology, the carbazole alkaloid mukonine has been concisely synthesized in a very good yield. Insertion of an aryne into a {sigma}-bond between a nucleophile and an electrophile (Nu-E) should potentially be a very beneficial process from the standpoint of organic synthesis. A variety of substituted ketones and sulfoxides have been synthesized in good yields via the intermolecular C-N {sigma}-bond addition of amides and S-N {sigma}-bond addition of sulfinamides to arynes under mild reaction conditions. The indazole moiety is a frequently found subunit in drug substances with important biological activities. Indazole analogues have been readily synthesized under mild reaction conditions by the [3+2] cycloaddition of a variety of diazo compounds with o-silylaryl triflates in the presence of CsF or TBAF. Polycyclic aromatic and heteroaromatic hydrocarbons have been synthesized in high yields by two different processes involving the Pd-catalyzed annulation of arynes. Both processes appear to involve the catalytic, stepwise coupling of two very reactive substrates, an aryne and an organopalladium species, to generate excellent yields of cross-coupled products.

  8. CHARACTERIZATION OF RADIOACTIVITY IN THE REACTOR VESSEL OF THE HEAVY WATER COMPONENT TEST REACTOR

    SciTech Connect (OSTI)

    Vinson, Dennis

    2010-06-01

    The Heavy Water Component Test Reactor (HWCTR) facility is a pressurized heavy water reactor that was used to test candidate fuel designs for heavy water power reactors. The reactor operated at nominal power of 50 MW{sub th}. The reactor coolant loop operated at 1200 psig and 250 C. Two isolated test loop were designed into the reactor to provide special test conditions. Fig. 1 shows a cut-away view of the reactor. The two loops are contained in four inch diameter stainless steel piping. The HWCTR was operated for only a short duration, from March 1962 to December 1964 in order to test the viability of test fuel elements and other reactor components for use in a heavy water power reactor. The reactor achieved 13,882 MWd of total power while testing 36 different fuel assemblies. In the course of operation, HWCTR experienced the cladding failures of 10 separate test fuel assemblies. In each case, the cladding was breached with some release of fuel core material into the isolated test loop, causing fission product and actinide contamination in the main coolant loop and the liquid and boiling test loops. Despite the contribution of the contamination from the failed fuel, the primary source of radioactivity in the HWCTR vessel and internals is the activation products in the thermal shields, and to a lesser degree, activation products in the reactor vessel walls and liner. A detailed facility characterization report of the HWCTR facility was completed in 1996. Many of the inputs and assumptions in the 1996 characterization report were derived from the HWCTR decommissioning plan published in 1975. The current paper provides an updated assessment of the radioisotopic characteristics of the HWCTR vessel and internals to support decommissioning activities on the facility.

  9. Energy 101: Heavy Duty Vehicle Efficiency | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy Duty Vehicle Efficiency Energy 101: Heavy Duty Vehicle Efficiency Addthis Description Although Class 8 Trucks only make up 4% of the vehicles on the road, they use about 20% of the nation's transportation fuel. In this video, learn how new fuel-efficient technologies are making our country's big rigs quieter, less polluting, more energy-efficient, and less expensive to operate over time. Topic Vehicles Text Version Below is the text version for the Energy 101: Heavy Duty Vehicle Efficiency

  10. Heavy oil catalytic cracking apparatus (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Heavy oil catalytic cracking apparatus Citation Details In-Document Search Title: Heavy oil catalytic cracking apparatus This patent describes an apparatus for the fluidized catalytic cracking of a heavy hydrocarbon feed comprising hydrocarbons having a boiling point above about 650{degrees} F to lighter products by contact the feed with catalytic cracking catalyst. It comprises a catalytic cracking reactor means; a separation means connective with the reactor outlet; a primary stripping means

  11. Heavy pair production currents with general quantum numbers in

    Office of Scientific and Technical Information (OSTI)

    dimensionally regularized nonrelativistic QCD (Journal Article) | SciTech Connect Heavy pair production currents with general quantum numbers in dimensionally regularized nonrelativistic QCD Citation Details In-Document Search Title: Heavy pair production currents with general quantum numbers in dimensionally regularized nonrelativistic QCD We discuss the form and construction of general color singlet heavy particle-antiparticle pair production currents for arbitrary quantum numbers, and

  12. The Heavy Ion Fusion Science Virtual National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Heavy Ion Fusion Science Virtual National Laboratory Python in a Parallel Environment Dave Grote - LLNL & LBNL NUG2013 User Day Wednesday, February 15, 2013 Slide 2 The Heavy Ion Fusion Science Virtual National Laboratory Outline * Why we use Python * How we use Python * Parallel Python with pyMPI * Our graphics model with Pygist * Parallel Python drawbacks and resolutions - Start up time - Static building * Conclusions Slide 3 The Heavy Ion Fusion Science Virtual National Laboratory 3

  13. Electron-State Hybridization in Heavy-Fermion Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron-State Hybridization in Heavy-Fermion Systems Print Heavy-fermion systems are characterized by electrons with extremely large effective masses. The corresponding heavy-electron "quasiparticle" states are close to the Fermi energy and govern the thermodynamic, transport, and, in part, magnetic properties of these materials. In the case of rare-earth compounds, the quasiparticle states arise from the interactions (hybridization) of valence states with strongly localized 4f

  14. Electron-State Hybridization in Heavy-Fermion Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron-State Hybridization in Heavy-Fermion Systems Print Heavy-fermion systems are characterized by electrons with extremely large effective masses. The corresponding heavy-electron "quasiparticle" states are close to the Fermi energy and govern the thermodynamic, transport, and, in part, magnetic properties of these materials. In the case of rare-earth compounds, the quasiparticle states arise from the interactions (hybridization) of valence states with strongly localized 4f

  15. A predictive standard model for heavy electron systems (Conference) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect SciTech Connect Search Results Conference: A predictive standard model for heavy electron systems Citation Details In-Document Search Title: A predictive standard model for heavy electron systems We propose a predictive standard model for heavy electron systems based on a detailed phenomenological two-fluid description of existing experimental data. It leads to a new phase diagram that replaces the Doniach picture, describes the emergent anomalous scaling behavior of the

  16. Electron-State Hybridization in Heavy-Fermion Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron-State Hybridization in Heavy-Fermion Systems Print Heavy-fermion systems are characterized by electrons with extremely large effective masses. The corresponding heavy-electron "quasiparticle" states are close to the Fermi energy and govern the thermodynamic, transport, and, in part, magnetic properties of these materials. In the case of rare-earth compounds, the quasiparticle states arise from the interactions (hybridization) of valence states with strongly localized 4f

  17. Heavy Vehicle Systems Optimization Peer Review | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy Vehicle Systems Optimization Peer Review Heavy Vehicle Systems Optimization Peer Review This report is a summary and analysis of comments from the Review Panel at the FY 2006 DOE Heavy Vehicle Systems Optimization Merit Review and Peer Evaluation, held April 18-20, 2006. PDF icon Merit Review and Peer Evaluation More Documents & Publications Advanced Combustion Engine R&D and Fuels Technology Merit Review 2013 Annual Merit Review Results Report 2013 Annual Merit Review Results

  18. QCD Factorization for heavy quarkonium production at collider energies

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect QCD Factorization for heavy quarkonium production at collider energies Citation Details In-Document Search Title: QCD Factorization for heavy quarkonium production at collider energies In this talk, I briefly review several models of the heavy quarkonium production at collider energies, and discuss the status of QCD factorization for these production models. Authors: Qiu Jianwei [1] ; Physics Department, Brookhaven National Laboratory, Upton, New York

  19. Inhalation radiotoxicity of irradiated thorium as a heavy water reactor

    Office of Scientific and Technical Information (OSTI)

    fuel (Conference) | SciTech Connect Conference: Inhalation radiotoxicity of irradiated thorium as a heavy water reactor fuel Citation Details In-Document Search Title: Inhalation radiotoxicity of irradiated thorium as a heavy water reactor fuel The online refueling capability of Heavy Water Reactors (HWRs), and their good neutron economy, allows a relatively high amount of neutron absorption in breeding materials to occur during normal fuel irradiation. This characteristic makes HWRs

  20. Critical condition in gravitational shock wave collision and heavy ion

    Office of Scientific and Technical Information (OSTI)

    collisions (Journal Article) | SciTech Connect Critical condition in gravitational shock wave collision and heavy ion collisions Citation Details In-Document Search Title: Critical condition in gravitational shock wave collision and heavy ion collisions In this paper, we derive a critical condition for matter equilibration in heavy ion collisions using a holographic approach. Gravitational shock waves with infinite transverse extension are used to model an infinite nucleus. We construct the

  1. QCD Prediction for Heavy Boson Transverse Momentum Distributions (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect QCD Prediction for Heavy Boson Transverse Momentum Distributions Citation Details In-Document Search Title: QCD Prediction for Heavy Boson Transverse Momentum Distributions We investigate the predictive power of the Collins, Soper, and Sterman b -space QCD resummation formalism for transverse momentum (Q{sub T}) distributions of heavy boson production in hadronic collisions. We show that the predictive power has a strong dependence on the collision energy S in

  2. QCD Resummation for Heavy Quarkonium Production in High Energy Collisions

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect QCD Resummation for Heavy Quarkonium Production in High Energy Collisions Citation Details In-Document Search Title: QCD Resummation for Heavy Quarkonium Production in High Energy Collisions Using e{sup +}e{sup -}{yields}J/{psi}+X as a case study, we explicitly demonstrate that the perturbatively calculated cross section for heavy quarkonium production in terms of the NRQCD factorization formalism has large logarithms as the collision energy s>>M,

  3. Flexibility in heavy oil upgrading with unicracking/HDS technology

    SciTech Connect (OSTI)

    Hennig, H.; Baron, K.; Moorhead, E.L.; Smith, M.

    1984-03-01

    With petroleum reserves becoming heavier and the demand for bottom of the barrel products greatly reduced, refiners are increasing their capabilities to upgrade heavy oil. Many heavy oil upgrading options are available and the best strategy for each refiner is not obvious. The best approach will depend on the specific circumstances and goals of the refiner. This presentation discusses the relative merits of several heavy oil upgrading options utilizing the Unicracking/HDS process.

  4. Accident analysis of heavy water cooled thorium breeder reactor (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect SciTech Connect Search Results Journal Article: Accident analysis of heavy water cooled thorium breeder reactor Citation Details In-Document Search Title: Accident analysis of heavy water cooled thorium breeder reactor Thorium has lately attracted considerable attention because it is accumulating as a by-product of large scale rare earth mining. The objective of research is to analyze transient behavior of a heavy water cooled thorium breeder that is designed by

  5. Triangularity and dipole asymmetry in relativistic heavy ion collisions

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Triangularity and dipole asymmetry in relativistic heavy ion collisions Citation Details In-Document Search Title: Triangularity and dipole asymmetry in relativistic heavy ion collisions We introduce a cumulant expansion to parametrize possible initial conditions in relativistic heavy ion collisions. We show that the cumulant expansion converges and that it can systematically reproduce the results of Glauber type initial conditions. At third order in the

  6. APBF-DEC Heavy Duty NOx Adsorber/DPF Project: Heavy Duty Linehaul Platform

    Broader source: Energy.gov (indexed) [DOE]

    Project Update | Department of Energy Ricardo Inc., Chicago Technical Center PDF icon deer_2003_may.pdf More Documents & Publications Status of APBF-DEC NOx Adsorber/DPF Projects APBF- DEC Heavy-Duty NOx Adsorber/DPF Project: Catalyst Aging Study APBF-DEC Light-duty NOx Adsorber/DPF Project

  7. TID-4500, UC-4 Chemistry Lawpenoe R

    Office of Scientific and Technical Information (OSTI)

    TID-4500, UC-4 Chemistry Lawpenoe R a d i a f i o m L&bor&fox-y U N I V E R S I T Y O F C A L I F O R N I A L I V E R M O R E UC R L - 5 04 2 2 CI ADIABATIC EXPANSION OF HIGH EXPLOSIVE DEPOMAPION PRODUCTS E. L. Lee H. C. Hornig J. W. K u r y May 2, 1 9 6 8 L E G A L N O T I C E This report was prepared as an account of Government sponsored work. Neither the United States. nor the Commission, nor any person acting on behalf of the Commission: A. Makes any warranty o r representation,

  8. The Organic Chemistry of Conducting Polymers

    SciTech Connect (OSTI)

    Tolbert, Laren Malcolm

    2014-12-01

    For the last several years, we have examined the fundamental principles of conduction in one-dimensional systems, i.e., molecular “wires”. It is, of course, widely recognized that such systems, as components of electronically conductive materials, function in a two- and three-dimensional milieu. Thus interchain hopping and grain-boundary resistivity are limiting conductivity factors in highly conductive materials, and overall conductivity is a function of through-chain and boundary hopping. We have given considerable attention to the basic principles underlying charge transport (the “rules of the game”) in two-dimensional systems by using model systems which allow direct observation of such processes, including the examination of tunneling and hopping as components of charge transfer. In related work, we have spent considerable effort on the chemistry of conjugated heteropolymers, most especially polythiophens, with the aim of using these most efficient of readily available electroactive polymers in photovoltaic devices.

  9. Mobility of Source Zone Heavy Metals and Radionuclides: The Mixed...

    Office of Scientific and Technical Information (OSTI)

    Various U. S. Department of Energy (DOE) low and medium-level radioactive waste sites contain mixtures of heavy metals, radionuclides and assorted organic materials. Over time, ...

  10. METHOD OF OPERATING A HEAVY WATER MODERATED REACTOR

    DOE Patents [OSTI]

    Vernon, H.C.

    1962-08-14

    A method of removing fission products from the heavy water used in a slurry type nuclear reactor is described. According to the process the slurry is steam distilled with carbon tetrachloride so that at least a part of the heavy water and carbon tetrachloride are vaporized; the heavy water and carbon tetrachloride are separated; the carbon tetrachloride is returned to the steam distillation column at different points in the column to aid in depositing the slurry particles at the bottom of the column; and the heavy water portion of the condensate is purified. (AEC)

  11. QCD Resummation for Heavy Quarkonium Production in High Energy...

    Office of Scientific and Technical Information (OSTI)

    formalism has large logarithms as the collision energy s>>M, the heavy quarkonium mass. ... Authors: Kang Zhongbo ; Qiu Jianwei 1 + Show Author Affiliations Department of Physics ...

  12. Design and Implementation of Silicon Nitride Valves for Heavy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Design and Implementation of Silicon Nitride Valves for Heavy Duty Diesel Engines Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER ...

  13. LNT + SCR Aftertreatment for Medium-Heavy Duty Applications:...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    LNT + SCR Aftertreatment for Medium-Heavy Duty Applications: A Systems Approach Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER ...

  14. An effective field theory for collinear and soft gluons: Heavy...

    Office of Scientific and Technical Information (OSTI)

    An effective field theory for collinear and soft gluons: Heavy to light decays Citation ... Subject: 72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS; 71 CLASSICAL AND QUANTUM ...

  15. Heavy-Duty HCCI Development Activities | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    and Posters PDF icon 2005deerduffy.pdf More Documents & Publications Heavy-Truck Clean Diesel (HTCD) Program Diesel HCCI Results at Caterpillar Diesel HCCI Results at ...

  16. Heavy-Truck Clean Diesel (HTCD) Program | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Caterpillar PDF icon 2004deerduffy.pdf More Documents & Publications Diesel HCCI Results at Caterpillar Diesel HCCI Results at Caterpillar Heavy-Duty HCCI Development Activities

  17. Heavy Duty & Medium Duty Drive Cycle Data Collection for Modeling...

    Broader source: Energy.gov (indexed) [DOE]

    Program Truck Duty Cycle and Performance Data Collection and Analysis Program Vehicle Technologies Office Merit Review 2014: Powertrain Controls Optimization for Heavy Duty ...

  18. Heavy Truck Clean Diesel (HTCD) Program: 2007 Demonstration Truck...

    Broader source: Energy.gov (indexed) [DOE]

    More Documents & Publications Transient Simulation of a 2007 Prototype Heavy-Duty Engine Diesel Aftertreatment Systems development Demonstration of a 50% Thermal Efficient Diesel ...

  19. California Policy Stimulates Carbon Negative CNG for Heavy Duty...

    Broader source: Energy.gov (indexed) [DOE]

    Describes system for fueling truck fleet with biomethane generated from anaerobic ... Advanced Natural Gas Engine Technology for Heavy Duty Vehicles Technical Workshop: Annual ...

  20. Establishment of the Heavy Isotopes Lead Materials Management...

    Office of Scientific and Technical Information (OSTI)

    Lead Materials Management Organization (LMMO) Citation Details In-Document Search Title: Establishment of the Heavy Isotopes Lead Materials Management Organization (LMMO) ...