Sample records for heat content coal

  1. Control of temperature and heat flux in a combustor using coal-derived gas of varying heat content. [Patent application

    SciTech Connect (OSTI)

    Loth, J.L.; Nakaishi, C.V.; Carpenter, L.K.; Bird, J.D.

    1981-06-03T23:59:59.000Z

    The present invention is directed to a fuel-air control system for a combustor in which coal-derived gas of varying heat content is used. To maintain the temperature in the combustor at an essentially constant value the fuel-to-air ratio is adjusted by using a temperature actuated variable pressure regulator in the gas feed line to compensate for the variability of the heat content of the gas. The velocity of the products of combustion is maintained at an essentially constant flow rate by controlling the mass flow of the air and fuel through linked valves on the gas and air feed lines.

  2. Aspects of coal pyrogenation with high heating rates

    SciTech Connect (OSTI)

    Panaitescu, C.; Barca, F. [Politehnica Univ., Bucharest (Romania); Predeanu, G.; Albastroiu, P. [Metallurgical Research Inst., Bucharest (Romania)

    1994-12-31T23:59:59.000Z

    The present paper describes the conversion of different rank coals into coke of required quality, influenced by heating rate variation. The study has been made for romanian coals and the imported coals too. Theoretical aspects of the coking process kinetics with special practical applications are shown. In Romania, classical coke making technology involves some theoretical and practical problems because of the local coal supply, weak in coking coals. Petrographical methods, as a complementary source of information for coking mechanisms understanding were used, for blends with high content of weakly coking coals. The results reveal the importance of rank and petrographical composition determinations for complex blends making. The paper continues previous studies of coke making kinetics, influenced by heating rate variation. On the basis of the relationship between coal charge composition and coke structure, including its use in the blast furnace, the influence of an increase in heating rate on the structure of the coke produced from different rank and petrographical composition coals, was studied. The heating rates ranged between 3 and 40 C/min. The structural changes produced during pyrogenation were more evident for the heating rates: 3, 6, 10 and 40 C/min. Table 2 reveals the optical aspects of coke matrix and inertinitic inclusions evolution, that is, the differences in structure arrangement by changing the plastic phase characteristics due to the increase in the heating rate.

  3. Process for heating coal-oil slurries

    DOE Patents [OSTI]

    Braunlin, W.A.; Gorski, A.; Jaehnig, L.J.; Moskal, C.J.; Naylor, J.D.; Parimi, K.; Ward, J.V.

    1984-01-03T23:59:59.000Z

    Controlling gas to slurry volume ratio to achieve a gas holdup of about 0.4 when heating a flowing coal-oil slurry and a hydrogen containing gas stream allows operation with virtually any coal to solvent ratio and permits operation with efficient heat transfer and satisfactory pressure drops. The critical minimum gas flow rate for any given coal-oil slurry will depend on numerous factors such as coal concentration, coal particle size distribution, composition of the solvent (including recycle slurries), and type of coal. Further system efficiency can be achieved by operating with multiple heating zones to provide a high heat flux when the apparent viscosity of the gas saturated slurry is highest. Operation with gas flow rates below the critical minimum results in system instability indicated by temperature excursions in the fluid and at the tube wall, by a rapid increase and then decrease in overall pressure drop with decreasing gas flow rate, and by increased temperature differences between the temperature of the bulk fluid and the tube wall. At the temperatures and pressures used in coal liquefaction preheaters the coal-oil slurry and hydrogen containing gas stream behaves essentially as a Newtonian fluid at shear rates in excess of 150 sec[sup [minus]1]. The gas to slurry volume ratio should also be controlled to assure that the flow regime does not shift from homogeneous flow to non-homogeneous flow. Stable operations have been observed with a maximum gas holdup as high as 0.72. 29 figs.

  4. Process for heating coal-oil slurries

    DOE Patents [OSTI]

    Braunlin, Walter A. (Spring, TX); Gorski, Alan (Lovington, NM); Jaehnig, Leo J. (New Orleans, LA); Moskal, Clifford J. (Oklahoma City, OK); Naylor, Joseph D. (Houston, TX); Parimi, Krishnia (Allison Park, PA); Ward, John V. (Arvada, CO)

    1984-01-03T23:59:59.000Z

    Controlling gas to slurry volume ratio to achieve a gas holdup of about 0.4 when heating a flowing coal-oil slurry and a hydrogen containing gas stream allows operation with virtually any coal to solvent ratio and permits operation with efficient heat transfer and satisfactory pressure drops. The critical minimum gas flow rate for any given coal-oil slurry will depend on numerous factors such as coal concentration, coal particle size distribution, composition of the solvent (including recycle slurries), and type of coal. Further system efficiency can be achieved by operating with multiple heating zones to provide a high heat flux when the apparent viscosity of the gas saturated slurry is highest. Operation with gas flow rates below the critical minimum results in system instability indicated by temperature excursions in the fluid and at the tube wall, by a rapid increase and then decrease in overall pressure drop with decreasing gas flow rate, and by increased temperature differences between the temperature of the bulk fluid and the tube wall. At the temperatures and pressures used in coal liquefaction preheaters the coal-oil slurry and hydrogen containing gas stream behaves essentially as a Newtonian fluid at shear rates in excess of 150 sec.sup. -1. The gas to slurry volume ratio should also be controlled to assure that the flow regime does not shift from homogeneous flow to non-homogeneous flow. Stable operations have been observed with a maximum gas holdup as high as 0.72.

  5. Advanced coal technologies in Czech heat and power systems

    SciTech Connect (OSTI)

    Noskievic, P.; Ochodek, T. [VSB-Technical Univ., Ostrava (Czechoslovakia)

    1998-04-01T23:59:59.000Z

    Coal is the only domestic source of fossil fuel in the Czech Republic. The coal reserves are substantial and their share in total energy use is about 60%. Presently necessary steps in making coal utilisation more friendly towards the environment have been taken and fairly well established, and an interest to develop and build advanced coal units has been observed. One IGCC system has been put into operation, and circa 10 AFBC units are in operation or under construction. Preparatory steps have been taken in building an advanced combustion unit fuelled by pulverised coal and retrofit action is taking place in many heating plants. An actual experience has shown two basic problems: (1) Different characteristic of domestic lignite, especially high content of ash, cause problems applying well-tried foreign technologies and apparently a more focused attention shall have to be paid to the quality of coal combusted. (2) Low prices of lignite (regarding energy, lignite is four times cheaper then coal) do not oblige to increase efficiency of the standing equipment applying advanced technologies. It will be of high interest to observe the effect of the effort of the European Union to establish a kind of carbon tax. It could dramatically change the existing scene in clean coal power generation by the logical pressure to increase the efficiency of energy transformation. In like manner the gradual liberalisation of energy prices might have similar consequences and it is a warranted expectation that, up to now not the best, energy balance will improve in near future.

  6. VAPOR PRESSURES AND HEATS OF VAPORIZATION OF PRIMARY COAL TARS

    SciTech Connect (OSTI)

    Eric M. Suuberg; Vahur Oja

    1997-07-01T23:59:59.000Z

    This project had as its main focus the determination of vapor pressures of coal pyrolysis tars. It involved performing measurements of these vapor pressures and from them, developing vapor pressure correlations suitable for use in advanced pyrolysis models (those models which explicitly account for mass transport limitations). This report is divided into five main chapters. Each chapter is a relatively stand-alone section. Chapter A reviews the general nature of coal tars and gives a summary of existing vapor pressure correlations for coal tars and model compounds. Chapter B summarizes the main experimental approaches for coal tar preparation and characterization which have been used throughout the project. Chapter C is concerned with the selection of the model compounds for coal pyrolysis tars and reviews the data available to us on the vapor pressures of high boiling point aromatic compounds. This chapter also deals with the question of identifying factors that govern the vapor pressures of coal tar model materials and their mixtures. Chapter D covers the vapor pressures and heats of vaporization of primary cellulose tars. Chapter E discusses the results of the main focus of this study. In summary, this work provides improved understanding of the volatility of coal and cellulose pyrolysis tars. It has resulted in new experimentally verified vapor pressure correlations for use in pyrolysis models. Further research on this topic should aim at developing general vapor pressure correlations for all coal tars, based on their molecular weight together with certain specific chemical characteristics i.e. hydroxyl group content.

  7. Coal plasticity at high heating rates and temperatures. Final technical progress report

    SciTech Connect (OSTI)

    Gerjarusak, S.; Peters, W.A.; Howard, J.B.

    1995-05-01T23:59:59.000Z

    Plastic coals are important feedstocks in coke manufacture, coal liquefaction, gasification, and combustion. During these processes, the thermoplastic behavior of these coals is also important since it may contribute to desirable or undesirable characteristics. For example, during liquefaction, the plastic behavior is desired since it leads to liquid-liquid reactions which are faster than solid-liquid reactions. During gasification, the elastic behavior is undesired since it leads to caking and agglomeration of coal particles which result in bed bogging in fixed or fluidized bed gasifiers. The plastic behavior of different coals was studied using a fast-response plastometer. A modified plastometer was used to measure the torque required to turn at constant angular speed a cone-shaped disk embedded in a thin layer of coal. The coal particles were packed between two metal plates which are heated electrically. Heating rates, final temperatures, pressures, and durations of experiment ranged from 200--800 K/s, 700--1300 K, vacuum-50 atm helium, and 0--40 s, respectively. The apparent viscosity of the molten coal was calculated from the measured torque using the governing equation of the cone-and-plate viscometer. Using a concentrated suspension model, the molten coal`s apparent viscosity was related to the quantity of the liquid metaplast present during pyrolysis. Seven coals from Argonne National Laboratory Premium Coal Sample Bank were studied. Five bituminous coals, from high-volatile to low-volatile bituminous, were found to have very good plastic behavior. Coal type strongly affects the magnitude and duration of plasticity. Hvb coals were most plastic. Mvb and lvb coals, though the maximum plasticity and plastic period were less. Low rank coals such as subbituminous and lignite did not exhibit any plasticity in the present studies. Coal plasticity is moderately well correlated with simple indices of coal type such as the elemental C,O, and H contents.

  8. Chemical composition and some trace element contents in coals and coal ash from Tamnava-Zapadno Polje Coal Field, Serbia

    SciTech Connect (OSTI)

    Vukasinovic-Pesic, V.; Rajakovic, L.J. [University of Montenegro, Podgorica (Montenegro)

    2009-07-01T23:59:59.000Z

    The chemical compositions and trace element contents (Zn, Cu, Co, Cr, Ni, Pb, Cd, As, B, Hg, Sr, Se, Be, Ba, Mn, Th, V, U) in coal and coal ash samples from Tamnava-Zapadno Polje coal field in Serbia were studied. The coal from this field belongs to lignite. This high volatility coal has high moisture and low S contents, moderate ash yield, and high calorific value. The coal ash is abundant in alumosilicates. Many trace elements such as Ni > Cd > Cr > B > As > Cu > Co > Pb > V > Zn > Mn in the coal and Ni > Cr > As > B > Cu > Co = Pb > V > Zn > Mn in the coal ash are enriched in comparison with Clarke concentrations.

  9. ,"Colorado Heat Content of Natural Gas Consumed"

    U.S. Energy Information Administration (EIA) Indexed Site

    Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","Colorado Heat Content of Natural Gas Consumed",1,"Monthly","112014","1152013" ,"Release...

  10. The effect of coal particle size on the heat of combustion

    SciTech Connect (OSTI)

    Xue Yongqiang; Yan Ruiping; Gao Yang [Dept. of Coal Processing and Utilization, Shanxi (China)

    1997-12-31T23:59:59.000Z

    The relations between integral heat and differential heat of combustion for pulverized coal, respectively, and the size of coal particle were derived in this paper. The results show that coal particle size has some effect on its heats of combustion; the smaller coal particle size, the greater the specific surface area and the specific surface energy, and the greater the heat value, also; and that the differential heat of combustion for pulverized coal differs from the integral one.

  11. Heat Content Changes in the Pacific Ocean

    E-Print Network [OSTI]

    Frandsen, Jannette B.

    Heat Content Changes in the Pacific Ocean The Acoustic Thermometry of Ocean Cli- mate (ATOC assimilating ocean observations and changes expected from surface heat fluxes as measured by the daily National are a result of advection of heat by ocean currents. We calculate that the most likely cause of the discrepancy

  12. Heat exchanger for coal gasification process

    DOE Patents [OSTI]

    Blasiole, George A. (Greensburg, PA)

    1984-06-19T23:59:59.000Z

    This invention provides a heat exchanger, particularly useful for systems requiring cooling of hot particulate solids, such as the separated fines from the product gas of a carbonaceous material gasification system. The invention allows effective cooling of a hot particulate in a particle stream (made up of hot particulate and a gas), using gravity as the motive source of the hot particulate. In a preferred form, the invention substitutes a tube structure for the single wall tube of a heat exchanger. The tube structure comprises a tube with a core disposed within, forming a cavity between the tube and the core, and vanes in the cavity which form a flow path through which the hot particulate falls. The outside of the tube is in contact with the cooling fluid of the heat exchanger.

  13. Heat removal from high temperature tubular solid oxide fuel cells utilizing product gas from coal gasifiers.

    SciTech Connect (OSTI)

    Parkinson, W. J. (William Jerry),

    2003-01-01T23:59:59.000Z

    In this work we describe the results of a computer study used to investigate the practicality of several heat exchanger configurations that could be used to extract heat from tubular solid oxide fuel cells (SOFCs) . Two SOFC feed gas compositions were used in this study. They represent product gases from two different coal gasifier designs from the Zero Emission Coal study at Los Alamos National Laboratory . Both plant designs rely on the efficient use of the heat produced by the SOFCs . Both feed streams are relatively rich in hydrogen with a very small hydrocarbon content . One feed stream has a significant carbon monoxide content with a bit less hydrogen . Since neither stream has a significant hydrocarbon content, the common use of the endothermic reforming reaction to reduce the process heat is not possible for these feed streams . The process, the method, the computer code, and the results are presented as well as a discussion of the pros and cons of each configuration for each process .

  14. TRACE METAL CONTENT OF COAL AND ASH AS DETERMINED USING SCANNINGELECTRON MICROSCOPYWITE

    E-Print Network [OSTI]

    Laughlin, Robert B.

    TRACE METAL CONTENT OF COAL AND ASH AS DETERMINED USING SCANNINGELECTRON MICROSCOPYWITE WAVELENGTH Grand Forks, ND 58202-9018 Keywords: scanning electron microscopy, trace metals, coal analysis ABSTRACT Scanningelectron microscopy with wavelength-dispersive spectrometry has been used to measure trace metals in coal

  15. Coal home heating and environmental tobacco smoke in relation to lower respiratory illness in Czech children, from birth to 3 years of age

    E-Print Network [OSTI]

    2006-01-01T23:59:59.000Z

    in the Czech setting, where coal is still com- monly used inwe found exposure to coal home heating and ETS increasewell studied, residential coal combustion in economically

  16. Geologic controls on sulfur content of the Blue Gem coal seam, southeastern Kentucky

    SciTech Connect (OSTI)

    Rimmer, S.M.; Moore, T.A.; Esterle, J.S.; Hower, J.C.

    1985-01-01T23:59:59.000Z

    Detailed petrographic and lithologic data on the Blue Gem coal seam for a local area in Knox County, Kentucky, suggest that a relationship may exist between overlying roof lithology, petrographic composition of the coal, and sulfur content. In the western part of the area, where thick (20-40 feet) shale sequences overlie the coal, sulfur contents are low (less than 1%). In isolated areas where discontinuous sandstones occur within 6 feet of the coal, sulfur contents range from 1% to over 3%. In the east, a sandstone body usually overlies and frequently scours out the coal, yet sulfur content varies independently of roof lithology. Towards the east, there is an increase in abundance, thickness and variability of fusain bands within the coal and an increase in pyrite and siderite either as cell fillings in fusinite or as masses within vitrinite; early emplacement of these minerals is indicated by compaction features. Data suggest the importance of depositional environment of the peat and overlying sediments as a control on sulfur occurrence. High sulfur contents in the west are related to sandstone bodies which may have allowed sulfate-bearing waters to permeate into the peat. In the east, where increases in pyrite, siderite and fusain content of the coal and coarsening of the overlying sediments suggest a change in environment, the presence or absence of pyrite-containing fusain bands may account for sulfur variability. Siderite occurrence may reflect local fluctuations in sulfate supply to the peat swamp.

  17. Observing ocean heat content using satellite gravity and altimetry

    E-Print Network [OSTI]

    Jayne, Steven

    : ocean heat content, altimetry, satellite gravity, steric height, remote sensing Citation: Jayne, S. RObserving ocean heat content using satellite gravity and altimetry Steven R. Jayne1,2 and John M with satellite measurements of the Earth's time-varying gravity to give improved estimates of the ocean's heat

  18. Composition and properties of coals from the Yurty coal occurrence

    SciTech Connect (OSTI)

    N.G. Vyazova; L.N. Belonogova; V.P. Latyshev; E.A. Pisar'kova [Irkutsk State University, Irkutsk (Russia). Research Institute of Oil and Coal Chemistry and Synthesis

    2008-10-15T23:59:59.000Z

    Coals from the Yurty coal occurrence were studied. It was found that the samples were brown non-coking coals with low sulfur contents (to 1%) and high yields of volatile substances. The high heat value of coals was 20.6-27.7 MJ/kg. The humic acid content varied from 5.45 to 77.62%. The mineral matter mainly consisted of kaolinite, a-quartz, and microcline. The concentration of toxic elements did not reach hazardous values.

  19. Cornell's conversion of a coal fired heating plant to natural Gas -BACKGROUND: In December 2009, the Combined Heat and Power Plant

    E-Print Network [OSTI]

    Keinan, Alon

    - BACKGROUND: In December 2009, the Combined Heat and Power Plant at Cornell Cornell's conversion of a coal fired heating plant to natural Gas the power plant #12;

  20. ,"New Mexico Heat Content of Natural Gas Consumed"

    U.S. Energy Information Administration (EIA) Indexed Site

    ,"Worksheet Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","New Mexico Heat Content of Natural Gas Consumed",1,"Monthly","12015","1152013"...

  1. ,"New York Heat Content of Natural Gas Consumed"

    U.S. Energy Information Administration (EIA) Indexed Site

    Name","Description"," Of Series","Frequency","Latest Data for" ,"Data 1","New York Heat Content of Natural Gas Consumed",1,"Monthly","102014","1152013" ,"Release...

  2. Thermodynamic properties of pulverized coal during rapid heating devolatilization processes. Quarterly progress report, April--June 1993

    SciTech Connect (OSTI)

    Proscia, W.M.; Freihaut, J.D.

    1993-08-01T23:59:59.000Z

    Knowledge of the thermodynamic and morphological properties of coal associated with rapid heating decomposition pathways is essential to progress in coal utilization technology. Specifically, knowledge of the heat of devolatilization, surface area and density of coal as a function of rank characteristics, temperature and extent of devolatilization in the context of rapid heating conditions is essential to the fundamental determination of kinetic parameters of coal devolatilization. These same properties are also needed to refine existing devolatilization sub-models utilized in large-scale modeling of coal combustion systems. The objective of this research is to obtain data on the thermodynamic properties and morphology of coal under conditions of rapid heating. Specifically, the total heat of devolatilization, external surface area, BET surface area and true density will be measured for representative coal samples. The coal ranks to be investigated will include a high volatile A bituminous (PSOC 1451 D) and a low volatile bituminous (PSOC 1516D). An anthracite (PSOC 1468) will be used as a non-volatile coal reference. In addition, for one coal, the contribution of each of the following components to the overall heat of devolatilization will be measured: the specific heat of coal/char during devolatilization, the heat of thermal decomposition of the coal, the specific heat capacity of tars, and the heat of vaporization of tars.

  3. Process for converting coal into liquid fuel and metallurgical coke

    DOE Patents [OSTI]

    Wolfe, Richard A. (Abingdon, VA); Im, Chang J. (Abingdon, VA); Wright, Robert E. (Bristol, TN)

    1994-01-01T23:59:59.000Z

    A method of recovering coal liquids and producing metallurgical coke utilizes low ash, low sulfur coal as a parent for a coal char formed by pyrolysis with a volatile content of less than 8%. The char is briquetted and heated in an inert gas over a prescribed heat history to yield a high strength briquette with less than 2% volatile content.

  4. Improved heat recovery and high-temperature clean-up for coal-gas fired combustion turbines

    SciTech Connect (OSTI)

    Barthelemy, N.M.; Lynn, S.

    1991-07-01T23:59:59.000Z

    This study investigates the performance of an Improved Heat Recovery Method (IHRM) applied to a coal-gas fired power-generating system using a high-temperature clean-up. This heat recovery process has been described by Higdon and Lynn (1990). The IHRM is an integrated heat-recovery network that significantly increases the thermal efficiency of a gas turbine in the generation of electric power. Its main feature is to recover both low- and high-temperature heat reclaimed from various gas streams by means of evaporating heated water into combustion air in an air saturation unit. This unit is a packed column where compressed air flows countercurrently to the heated water prior to being sent to the combustor, where it is mixed with coal-gas and burned. The high water content of the air stream thus obtained reduces the amount of excess air required to control the firing temperature of the combustor, which in turn lowers the total work of compression and results in a high thermal efficiency. Three designs of the IHRM were developed to accommodate three different gasifying process. The performances of those designs were evaluated and compared using computer simulations. The efficiencies obtained with the IHRM are substantially higher those yielded by other heat-recovery technologies using the same gasifying processes. The study also revealed that the IHRM compares advantageously to most advanced power-generation technologies currently available or tested commercially. 13 refs., 34 figs., 10 tabs.

  5. Passive cigarette smoke, coal heating, and respiratory symptoms of nonsmoking women in China

    SciTech Connect (OSTI)

    Pope, C.A. III (Harvard School of Public Health, Boston, MA (United States) Brigham Young Univ., Provo, UT (United States)); Xu, X. (Harvard School of Public Health, Boston, MA (United States))

    1993-09-01T23:59:59.000Z

    In this study the authors evaluated data from a sample of 973 never-smoking women, ages 20-40, who worked in three similar textile mills in Anhui Province, China. They compared prevalence rates of respiratory symptoms across homes with and without coal heating and homes with different numbers of smokers. Multiple logistic regression models that controlled for age, job title, and mill of employment were also estimated. Respiratory symptoms were associated with combined exposure to passive cigarette smoke and coal heating. Effects of passive cigarette smoke and coal heating on respiratory symptoms appeared to be nearly additive, suggesting a dose-response relationship between respiratory symptoms and home indoor air pollution from these two sources. The prevalence of chest illness, cough, phlegm, and shortness of breath (but not wheeze) was significantly elevated for women living in homes with both smokers and coal heating.

  6. Coal home heating and environmental tobacco smoke in relation to lower respiratory illness in Czech children, from birth to 3 years of age

    E-Print Network [OSTI]

    2006-01-01T23:59:59.000Z

    still com- monly used in home heating and smoking rates arefound exposure to coal home heating and ETS increase youngChildren’s Health Coal Home Heating and Environmental

  7. A study of the volatile matter of coal as a function of the heating rate

    SciTech Connect (OSTI)

    Yanes, E.; Wilhite, D.; Riley, J.M. Jr. [Western Kentucky Univ., Bowling Green, KY (United States)] [and others

    1996-12-31T23:59:59.000Z

    A study of the volatile matter yields as a function of the heating rate was conducted. A suite of 21 coal and coke samples varying in rank from anthracitic to lignitic and heating rates from 10{degrees}C/min to about 450{degrees}C/min were used in the study. Heating rates up to 60{degrees}C per minute, which are typically used in ASTM Test Method 5142 (instrumental Proximate Analysis), were achieved in a macro thermogravimetric analysis (TGA) system. Heating rates of 50-200{degrees}C/min were obtained in a micro TGA system. All measurements were made in a nitrogen atmosphere. The results of the study illustrate the dependence of the volatile matter yield on the heating rate. For most coals and cokes the optimum heating rate for determining volatile matter values that agree with those obtained by ASTM Method D 3175 appears to be in the 100-150{degrees}C range.

  8. Specific heat of apple at different moisture contents and temperatures

    E-Print Network [OSTI]

    Viacheslav Mykhailyk; Nikolai Lebovka

    2013-05-11T23:59:59.000Z

    This work discusses results of experimental investigations of the specific heat, $C$, of apple in a wide interval of moisture contents ($W=0-0.9$) and temperatures ($T = 283-363$ K). The obtained data reveal the important role of the bound water in determination of $C(W,T)$ behaviour. The additive model for description of $C(W)$ dependence in the moisture range of $0.1apple was considered as a mixture of water and hydrated apple material (water plasticised apple) with specific heat $C_h$. The difference between $C_h$ and specific heat of dry apple, $\\Delta Cb=C_h-C_d$, was proposed as a measure of the excess contribution of bound water to the specific heat. The estimated amounts of bound water $W_b$ were comparable with the monolayer moisture content in apple. The analytical equation was proposed for approximation of $C(W,T)$ dependencies in the studied intervals of moisture content and temperature.

  9. Water recovery using waste heat from coal fired power plants.

    SciTech Connect (OSTI)

    Webb, Stephen W.; Morrow, Charles W.; Altman, Susan Jeanne; Dwyer, Brian P.

    2011-01-01T23:59:59.000Z

    The potential to treat non-traditional water sources using power plant waste heat in conjunction with membrane distillation is assessed. Researchers and power plant designers continue to search for ways to use that waste heat from Rankine cycle power plants to recover water thereby reducing water net water consumption. Unfortunately, waste heat from a power plant is of poor quality. Membrane distillation (MD) systems may be a technology that can use the low temperature waste heat (<100 F) to treat water. By their nature, they operate at low temperature and usually low pressure. This study investigates the use of MD to recover water from typical power plants. It looks at recovery from three heat producing locations (boiler blow down, steam diverted from bleed streams, and the cooling water system) within a power plant, providing process sketches, heat and material balances and equipment sizing for recovery schemes using MD for each of these locations. It also provides insight into life cycle cost tradeoffs between power production and incremental capital costs.

  10. A compact XRF unit for determining total sulphur content in coals

    SciTech Connect (OSTI)

    Sumitra, T.; Chankow, N.; Punnachaiya, S.; Srisatit, S. [Chulalongkorn Univ., Bangkok (Thailand)

    1994-12-31T23:59:59.000Z

    A microcomputer based x-ray fluorescence (XRF) unit was developed for off-line determination of total sulphur content in coal samples. The unit consisted of the x-ray exciting/measuring set and the microcomputer with a plug-in interface card, An Fe-55 radioisotope was used as the exciting source while a krypton-filled proportional counter was used to measure x-rays from the samples. The x-ray spectrum was simultaneously displayed on the microcomputer screen. For quantitative determination of sulphur, the intensities of sulphur K x-rays as well as calcium K x-rays and scattered x-rays were taken into account. The unit was tested with finely-ground, dried and compressed lignite, subbituminous and bituminous samples. It was found that for low-calcium coals the results were in good agreement with those obtained from the standard chemical analysis method within {+-}0.2 %S and within {+-}0.5 %S for high-calcium coals.

  11. Moist caustic leaching of coal

    DOE Patents [OSTI]

    Nowak, Michael A. (Elizabeth, PA)

    1994-01-01T23:59:59.000Z

    A process for reducing the sulfur and ash content of coal. Particulate coal is introduced into a closed heated reaction chamber having an inert atmosphere to which is added 50 mole percent NaOH and 50 mole percent KOH moist caustic having a water content in the range of from about 15% by weight to about 35% by weight and in a caustic to coal weight ratio of about 5 to 1. The coal and moist caustic are kept at a temperature of about 300.degree. C. Then, water is added to the coal and caustic mixture to form an aqueous slurry, which is washed with water to remove caustic from the coal and to produce an aqueous caustic solution. Water is evaporated from the aqueous caustic solution until the water is in the range of from about 15% by weight to about 35% by weight and is reintroduced to the closed reaction chamber. Sufficient acid is added to the washed coal slurry to neutralize any remaining caustic present on the coal, which is thereafter dried to produce desulfurized coal having not less than about 90% by weight of the sulfur present in the coal feed removed and having an ash content of less than about 2% by weight.

  12. Conventional coal preparation in the United States

    SciTech Connect (OSTI)

    Beck, M.K.; Taylor, B.

    1993-12-31T23:59:59.000Z

    Processing of bituminous and anthracite coal is widely practiced in the United States and, as mentioned earlier, about 80 percent of the production of these coals is processed as clean coal in preparation plants. Subbituminous coal is not widely processed, primarily because these low rank raw coals are low in sulfur (0.5 to 1.0 percent) and relatively low in ash (8 to 15 percent). They are also relatively low in heat content due to their high inherent moisture. Lignite coals, to the best of the authors{close_quote} knowledge, are not presently being processed in Conventional Coal Preparation plants. This is due to their unstable nature and putting them in water in a coal preparation plant is likely to cause severe degradation in particle size and add to their already high inherent moisture content. The following are the benefits of clean coal processing: produces a uniform product which can be utilized more efficiently; produces a higher quality product which results in higher efficiency at the power station or the steel mill; reduces sulfur dioxide and other adverse stack emissions during coal firing which is a very important environmental consideration; reduces ash or slag handling costs by the user; reduces shipping costs; and reduces handling and storage costs. Processing any stable raw coal in a coal preparation plant will always produce a higher grade product which is a more efficient and a more environmentally acceptable fuel for use at power stations, steel mills, home heating or industrial boilers.

  13. Upgrading low rank coal using the Koppelman Series C process

    SciTech Connect (OSTI)

    Merriam, N.W., Western Research Institute

    1998-01-01T23:59:59.000Z

    Development of the K-Fuel technology began after the energy shortage of the early 1970s in the United States led energy producers to develop the huge deposits of low-sulfur coal in the Powder River Basin (PRB) of Wyoming. PRB coal is a subbituminous C coal containing about 30 wt % moisture and having heating values of about 18.6 megajoules/kg (8150 Btu/lb). PRB coal contains from 0.3 to 0.5 wt % sulfur, which is nearly all combined with the organic matrix in the coal. It is in much demand for boiler fuel because of the low-sulfur content and the low price. However, the low-heating value limits the markets for PRB coal to boilers specially designed for the high- moisture coal. Thus, the advantages of the low-sulfur content are not available to many potential customers having boilers that were designed for bituminous coal. This year about 250 million tons of coal is shipped from the Powder River Basin of Wyoming. The high- moisture content and, consequently, the low-heating value of this coal causes the transportation and combustion of the coal to be inefficient. When the moisture is removed and the heating value increased the same bundle of energy can be shipped using one- third less train loads. Also, the dried product can be burned much more efficiently in boiler systems. This increase in efficiency reduces the carbon dioxide emissions caused by use of the low-heating value coal. Also, the processing used to remove water and restructure the coal removes sulfur, nitrogen, mercury, and chlorides from the coal. This precombustion cleaning is much less costly than stack scrubbing. PRB coal, and other low-rank coals, tend to be highly reactive when freshly mined. These reactive coals must be mixed regularly (every week or two) when fresh, but become somewhat more stable after they have aged for several weeks. PRB coal is relatively dusty and subject to self-ignition compared to bituminous coals. When dried using conventional technology, PRB coal is even more dusty and more susceptible to spontaneous combustion than the raw coal. Also, PRB coal, if dried at low temperature, typically readsorbs about two- thirds of the moisture removed by drying. This readsorption of moisture releases the heat of adsorption of the water which is a major cause of self- heating of low-rank coals at low temperature.

  14. A coal-fired combustion system for industrial process heating applications

    SciTech Connect (OSTI)

    Not Available

    1992-09-03T23:59:59.000Z

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation's Phase III development contract DE-AC22-91PC91161 for a Coal-Fired Combustion System for Industrial Process Heating Applications'' is project funded under the DOE/PETC advanced combustion program. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelling and waste vitrification processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the current reporting period, approval of Vortec's Environmental Assessment (EA) required under the National Environmental Policy Act (NEPA) was approved. The EA approval cycle took approximately 9 months. The preliminary test program which was being held in abeyance pending approval of the EA was initiated. Six preliminary test runs were successfully competed during the period. Engineering and design activities in support of the Phase III proof of concept are continuing, and modifications to the existing test system configuration to allow performance of the preliminary tests were completed.

  15. The development of a coal-fired combustion system for industrial process heating applications

    SciTech Connect (OSTI)

    Not Available

    1992-07-16T23:59:59.000Z

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation's Coal-Fired Combustion System for Industrial Process Heating Applications has been selected for Phase III development under contract DE-AC22-91PC91161. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting, recycling, and refining processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase HI research effort is being focused on the development of a process heater system to be used for producing glass frits and wool fiber from boiler and incinerator ashes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. The economic evaluation of commercial scale CMS processes has begun. In order to accurately estimate the cost of the primary process vessels, preliminary designs for 25, 50, and 100 ton/day systems have been started under Task 1. This data will serve as input data for life cycle cost analysis performed as part of techno-economic evaluations. The economic evaluations of commercial CMS systems will be an integral part of the commercialization plan.

  16. Coal Severance Tax (North Dakota)

    Broader source: Energy.gov [DOE]

    The Coal Severance Tax is imposed on all coal severed for sale or industrial purposes, except coal used for heating buildings in the state, coal used by the state or any political subdivision of...

  17. Proposed finding of no significant impact for the Sakakawea Medical Center coal-fired heating plant

    SciTech Connect (OSTI)

    Not Available

    1994-07-01T23:59:59.000Z

    The Department of Energy (the Department) has prepared an environmental assessment (Assessment) (DOE/EA-0949) to identify and evaluate the potential environmental impacts of a proposed action at the Sakakawea Medical Center (the Center) in Hazen, North Dakota. The proposed action would replace the existing No. 2 fuel oil-fired boilers supplemented by electric reheat with a new coal-fired hot water heating plant, using funds provided from a grant under the Institutional Conservation Program. Based on the analysis in DOE/EA-0949, the Department has determined that the proposed action is not a major federal action significantly affecting the quality of the human environment, within the meaning of the National Environmental Policy Act (NEPA) of 1969, as amended. Therefore, preparation of an Environmental Impact Statement is not required, and the Department is issuing this Finding of No Significant Impact (Finding).

  18. Preparation and gasification of a Thailand coal-water fuel

    SciTech Connect (OSTI)

    Ness, R.O. Jr.; Anderson, C.M.; Musich, M.A.; Richter, J.J.; Dewall, R.A.; Young, B.C. [Univ. of North Dakota, Grand Forks, ND (United States). Energy and Environmental Research Center; Nakanart, A. [Ministry of Industry, Bangkok (Thailand)

    1996-12-31T23:59:59.000Z

    In response to an inquiry by the Department of Mineral Resources (DMR) in Thailand, the Energy and Environmental Research Center (EERC) prepared a four-task program to assess the responsiveness of Wiang Haeng coal to the temperature and pressure conditions of hot-water drying (HWD). The results indicate that HWD made several improvements in the coal, notably increases in heating value and carbon content and reductions in equilibrium moisture and oxygen content. The equilibrium moisture content decreased from 37.4 wt% for the raw coal to about 20 wt% for the HWD coals. The energy density, determined at 500 cP, indicates an increase from 4450 to 6650 Btu/lb by hydrothermal treatment. Raw and HWD coal were then gasified at various mild gasification conditions of 700 C and 30 psig. The tests indicated that the coal is probably similar to other low-rank coals and will produce high levels of hydrogen and be fairly reactive.

  19. Effects of moisture and hydrogen content on the heating value of fuels

    SciTech Connect (OSTI)

    Demirbas, A. [Selcuk University, Konya (Turkey). Dept. of Chemical Engineering

    2007-07-01T23:59:59.000Z

    In this work, effects of moisture and hydrogen contents on lower heating value (LHV) of fuels were investigated. The LHV at constant pressure measures the enthalpy change of combustion with and without water condensed, respectively. Moisture in biomass generally decreases its heating value. Moisture in biomass is stored in spaces within the dead cells and within the cell walls. Higher heating value (HHV) of a fuel decreases with increasing of its moisture content. The LHV of a fuel increases with increasing of its hydrogen content. The LHV of a fuel depends on its oxygen content and the LHV of a fuel decreases with increasing of its oxygen content. The LHV of a fuel increases with increasing the hydrogen content due to cause combustion water. Moisture in a fuel generally decreases its HHV. The LHV of a fuel increases with increasing the sulfur content due to SOx gases absorbed by water.

  20. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01T23:59:59.000Z

    generation systems. Coal energy density could be increasedfuel reserves were coal by energy content; 19% were oil, andConsumption, 2007 coal/primary energy consumption Source: BP

  1. Coal gasification apparatus

    DOE Patents [OSTI]

    Nagy, Charles K. (Monaca, PA)

    1982-01-01T23:59:59.000Z

    Coal hydrogenation vessel has hydrogen heating passages extending vertically through its wall and opening into its interior.

  2. Environmental data energy technology characterizations: coal

    SciTech Connect (OSTI)

    Not Available

    1980-04-01T23:59:59.000Z

    This document describes the activities leading to the conversion of coal to electricity. Specifically, the activities consist of coal mining and beneficiation, coal transport, electric power generation, and power transmission. To enhance the usefulness of the material presented, resource requirements, energy products, and residuals for each activity area are normalized in terms of 10/sup 12/ Btus of energy produced. Thus, the total effect of producing electricity from coal can be determined by combining the residuals associated with the appropriate activity areas. Emissions from the coal cycle are highly dependent upon the type of coal consumed as well as the control technology assigned to the activity area. Each area is assumed to be equipped with currently available control technologies that meet environmental regulations. The conventional boiler, for example, has an electrostatic precipitator and a flue gas desulfurization scrubber. While this results in the removal of most of the particulate matter and sulfur dioxide in the flue gas stream, it creates other new environmental residuals -- solid waste, sludge, and ash. There are many different types of mined coal. For informational purposes, two types from two major producing regions, the East and the West, are characterized here. The eastern coal is typical of the Northern Appalachian coal district with a high sulfur and heat content. The western coal, from the Powder River Basin, has much less sulfur, but also has a substantially lower heating value.

  3. Development of a coal fired pulse combustor for residential space heating. Technical progress report, July--September 1987

    SciTech Connect (OSTI)

    NONE

    1987-12-31T23:59:59.000Z

    The systematic development of the residential combustion system is divided into three phases. Only Phase I is detailed here. Phase I constitutes the design, fabrication, testing, and evaluation of a pulse combustor sized for residential space heating. Phase II is an optional phase to develop an integrated system including a heat exchanger. Phase III is projected as a field test of the integrated coal-fired residential space heater. The Phase I effort was nearing completion during this reporting period and a final report is in preparation. The configuration testing was completed early in the period and based upon results of the configuration tests, an optimized configuration for the experimental development testing was chosen. The refractory-lined chambers were fabricated and tested from mid-September through early October. The tandem unit was operated on dry micromized coal without support gas or excitation air for periods lasting from one to three hours. Performance was stable and turndown ratios of 3:1 were achieved during the first three-hour test. A early commercial residential heating system configuration has been identified on the basis of the development testing conducted throughout the first phase of this effort. The development effort indicates that the residential unit goals are achievable with some additional product improvement effort to increase carbon burn-out efficiency, reduce CO emissions and develop a reliable and compact dry, ultrafine coal feed system (not included in the present effort).

  4. Progressive flow cracking of coal/oil mixtures with high metals content catalyst

    SciTech Connect (OSTI)

    Zandona, O.J.

    1989-10-10T23:59:59.000Z

    This patent describes a process for economically producing liquid fuel products at least partly from coal. It comprises: introducing a progressive flow catalytic cracking zone a charge stock comprising a pumpable mixture of solid, particulate coal and carbo-metallic oil and forming within the zone a stream having a linear velocity of at least about 25 feet per second. The stream comprising the charge stock and a hydrocarbon zeolite cracking catalyst promoting dehydrogenation of the charge stock; forming mobile hydrogen within the zone by the dehydrogenation; introducing the mobile hydrogen into the stream by dehydrogenation of the charge stock in the absence of added molecular hydrogen, thereby producing liquid products from the charge stock while laying down coke on the hydrocarbon cracking catalyst in the range of about 0.3% to about 3% and thereby producing spent catalyst; separating from the spent catalyst the liquid products.

  5. X-ray Computed Tomography of coal: Final report

    SciTech Connect (OSTI)

    Maylotte, D.H.; Spiro, C.L.; Kosky, P.G.; Lamby, E.J.

    1986-12-01T23:59:59.000Z

    X-ray Computed Tomography (CT) is a method of mapping with x-rays the internal structures of coal. The technique normally produces 2-D images of the internal structures of an object. These images can be recast to create pseudo 3-D representations. CT of coal has been explored for a variety of different applications to coal and coal processing technology. In a comparison of CT data with conventional coal analyses and petrography, CT was found to offer a good indication of the total ash content of the coal. The spatial distribution of the coal mineral matter as seen with CT has been suggested as an indicator of coal washability. Studies of gas flow through coal using xenon gas as a tracer have shown the extremely complicated nature of the modes of penetration of gas through coal, with significant differences in the rates at which the gas can pass along and across the bedding planes of coal. In a special furnace designed to allow CT images to be taken while the coal was being heated, the pyrolysis and gasification of coal have been studied. Gasification rates with steam and CO/sub 2/ for a range of coal ranks have been obtained, and the location of the gasification reactions within the piece of coal can be seen. Coal drying and the progress of the pyrolysis wave into coal have been examined when the coal was subjected to the kind of sudden temperature jump that it might experience in fixed bed gasifier applications. CT has also been used to examine stable flow structures within model fluidized beds and the accessibility of lump coal to microbial desulfurization. 53 refs., 242 figs., 26 tabs.

  6. Design study of a coal-fired thermionic (THX) topped power plant. Volume IV. Thermionic heat exchanger design and costing

    SciTech Connect (OSTI)

    Dick, R.S.; Britt, E.J.

    1980-10-15T23:59:59.000Z

    This volume deals with the details of how thermionic conversion works, and how it is used in a coal-fired furnace to achieve power plant efficiencies of 45%, and overall costs of 36.3 mills/kWh. A review of the fundamental technical aspects of thermionic conversion is given. The overall Thermionic Heat Exchanger (THX) design, the heat pipe design, and the interaction of the heat pipes with the furnace are presented. Also, the operational characteristics of thermionic converters are described. Details on the computer program used to perform the parametric study are given. The overall program flow is reviewed along with the specifics of how the THX subroutine designed the converter to match the conditions imposed. Also, input costs and variables effecting the THX's performance are detailed. The efficiencies of the various power plants studied are given as a function of the air preheat temperature, size of the power plant, and thermionic level of performance.

  7. Production of High-Hydrogen Content Coal-Derived Liquids [Part 1 of 3

    SciTech Connect (OSTI)

    Stephen Bergin

    2011-03-30T23:59:59.000Z

    The primary goal of this project has been to evaluate and compare the effect of the intrinsic differences between cobalt (Co) and iron (Fe) catalysts for Fischer-Tropsch (FT) synthesis using coal-derived syngas. Crude oil, especially heavy, high-sulfur crude, is no longer the appropriate source for the additional, or marginal, amounts of middle-distillate fuels needed to meet growing US and world demand for diesel and jet fuels. Only about 1/3 of the marginal crude oil barrel can be made into diesel and jet fuels. The remaining 2/3 contributes further to global surpluses of by-products. FT can produce these needed marginal, low-sulfur middle-distillate fuels more efficiently, with less environmental impact, and from abundant US domestic resources. Cobalt FT catalyst is more efficient, and less expensive overall, than iron FT catalyst. Mechanisms of cobalt FT catalyst functioning, and poisoning, have been elucidated. Each of these primary findings is amplified by several secondary findings, and these are presented, and verified in detail. The most effective step the United States can take to begin building toward improved long-term national energy security, and to reduce dependence, over time, on imported crude oil from unfriendly and increasingly unstable areas of the world, is to begin producing additional, or marginal amounts of, middle-distillate-type fuels, such as ultralow sulfur diesel (ULSD) and jet fuel (not gasoline) from US domestic resources other than petroleum. FT synthesis of these middle distillate fuels offers the advantage of being able to use abundant and affordable US coal and biomass as the primary feedstocks. Use of the cobalt FT catalyst system has been shown conclusively to be more effective and less expensive than the use of iron FT catalyst with syngas derived from coal, or from coal and biomass combined. This finding is demonstrated in detail for the initial case of a relatively small FT plant of about 2000 barrels per day based upon coal and biomass. The primary feature of such a plant, in the current situation in which no commercial FT plants are operating in the US, is that it requires a relatively modest capital investment, meaning that such a plant could actually be built, operated, and replicated in the near term. This is in contrast to the several-billion dollar investment, and accompanying risk, that would be required for a plant of more than an order of magnitude greater capacity, which has been referred to in the technical literature on fuel production as the capacity required to be considered "commercial-scale." The effects of more than ten different potential poisons for cobalt FT catalyst have been studied extensively and in detail using laboratory continuous-stirred tank reactors (CSTRs) and bottled laboratory syngas "spiked" with precisely controlled amounts of the poisons, typically at the levels of 10s or 100s of parts per billion. This data set has been generated and interpreted by world-renowned experts on FT catalysis at the University of Kentucky Center for Applied Energy Research (UK-CAER), and has enabled unprecedented insight regarding the many molecular-scale mechanisms that can play a role in the "poisoning" of cobalt FT catalyst.

  8. Production of High-Hydrogen Content Coal-Derived Liquids [Part 2 of 3

    SciTech Connect (OSTI)

    Stephen Bergin

    2011-03-30T23:59:59.000Z

    The primary goal of this project has been to evaluate and compare the effect of the intrinsic differences between cobalt (Co) and iron (Fe) catalysts for Fischer-Tropsch (FT) synthesis using coal-derived syngas. Crude oil, especially heavy, high-sulfur crude, is no longer the appropriate source for the additional, or marginal, amounts of middle-distillate fuels needed to meet growing US and world demand for diesel and jet fuels. Only about 1/3 of the marginal crude oil barrel can be made into diesel and jet fuels. The remaining 2/3 contributes further to global surpluses of by-products. FT can produce these needed marginal, low-sulfur middle-distillate fuels more efficiently, with less environmental impact, and from abundant US domestic resources. Cobalt FT catalyst is more efficient, and less expensive overall, than iron FT catalyst. Mechanisms of cobalt FT catalyst functioning, and poisoning, have been elucidated. Each of these primary findings is amplified by several secondary findings, and these are presented, and verified in detail. The most effective step the United States can take to begin building toward improved long-term national energy security, and to reduce dependence, over time, on imported crude oil from unfriendly and increasingly unstable areas of the world, is to begin producing additional, or marginal amounts of, middle-distillate-type fuels, such as ultralow sulfur diesel (ULSD) and jet fuel (not gasoline) from US domestic resources other than petroleum. FT synthesis of these middle distillate fuels offers the advantage of being able to use abundant and affordable US coal and biomass as the primary feedstocks. Use of the cobalt FT catalyst system has been shown conclusively to be more effective and less expensive than the use of iron FT catalyst with syngas derived from coal, or from coal and biomass combined. This finding is demonstrated in detail for the initial case of a relatively small FT plant of about 2000 barrels per day based upon coal and biomass. The primary feature of such a plant, in the current situation in which no commercial FT plants are operating in the US, is that it requires a relatively modest capital investment, meaning that such a plant could actually be built, operated, and replicated in the near term. This is in contrast to the several-billion dollar investment, and accompanying risk, that would be required for a plant of more than an order of magnitude greater capacity, which has been referred to in the technical literature on fuel production as the capacity required to be considered "commercial-scale." The effects of more than ten different potential poisons for cobalt FT catalyst have been studied extensively and in detail using laboratory continuous-stirred tank reactors (CSTRs) and bottled laboratory syngas "spiked" with precisely controlled amounts of the poisons, typically at the levels of 10s or 100s of parts per billion. This data set has been generated and interpreted by world-renowned experts on FT catalysis at the University of Kentucky Center for Applied Energy Research (UK-CAER), and has enabled unprecedented insight regarding the many molecular-scale mechanisms that can play a role in the "poisoning" of cobalt FT catalyst.

  9. Production of High-Hydrogen Content Coal-Derived Liquids [Part 3 of 3

    SciTech Connect (OSTI)

    Stephen Bergin

    2011-03-30T23:59:59.000Z

    The primary goal of this project has been to evaluate and compare the effect of the intrinsic differences between cobalt (Co) and iron (Fe) catalysts for Fischer-Tropsch (FT) synthesis using coal-derived syngas. Crude oil, especially heavy, high-sulfur crude, is no longer the appropriate source for the additional, or marginal, amounts of middle-distillate fuels needed to meet growing US and world demand for diesel and jet fuels. Only about 1/3 of the marginal crude oil barrel can be made into diesel and jet fuels. The remaining 2/3 contributes further to global surpluses of by-products. FT can produce these needed marginal, low-sulfur middle-distillate fuels more efficiently, with less environmental impact, and from abundant US domestic resources. Cobalt FT catalyst is more efficient, and less expensive overall, than iron FT catalyst. Mechanisms of cobalt FT catalyst functioning, and poisoning, have been elucidated. Each of these primary findings is amplified by several secondary findings, and these are presented, and verified in detail. The most effective step the United States can take to begin building toward improved long-term national energy security, and to reduce dependence, over time, on imported crude oil from unfriendly and increasingly unstable areas of the world, is to begin producing additional, or marginal amounts of, middle-distillate-type fuels, such as ultralow sulfur diesel (ULSD) and jet fuel (not gasoline) from US domestic resources other than petroleum. FT synthesis of these middle distillate fuels offers the advantage of being able to use abundant and affordable US coal and biomass as the primary feedstocks. Use of the cobalt FT catalyst system has been shown conclusively to be more effective and less expensive than the use of iron FT catalyst with syngas derived from coal, or from coal and biomass combined. This finding is demonstrated in detail for the initial case of a relatively small FT plant of about 2000 barrels per day based upon coal and biomass. The primary feature of such a plant, in the current situation in which no commercial FT plants are operating in the US, is that it requires a relatively modest capital investment, meaning that such a plant could actually be built, operated, and replicated in the near term. This is in contrast to the several-billion dollar investment, and accompanying risk, that would be required for a plant of more than an order of magnitude greater capacity, which has been referred to in the technical literature on fuel production as the capacity required to be considered "commercial-scale." The effects of more than ten different potential poisons for cobalt FT catalyst have been studied extensively and in detail using laboratory continuous-stirred tank reactors (CSTRs) and bottled laboratory syngas "spiked" with precisely controlled amounts of the poisons, typically at the levels of 10s or 100s of parts per billion. This data set has been generated and interpreted by world-renowned experts on FT catalysis at the University of Kentucky Center for Applied Energy Research (UK-CAER), and has enabled unprecedented insight regarding the many molecular-scale mechanisms that can play a role in the "poisoning" of cobalt FT catalyst.

  10. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01T23:59:59.000Z

    delivered heating (district heating) (6%), and chemicalscoal growth. As district heating expands with urbanizationzone, coal use for district heating will depend on the

  11. Low-rank coal oil agglomeration

    DOE Patents [OSTI]

    Knudson, Curtis L. (Grand Forks, ND); Timpe, Ronald C. (Grand Forks, ND)

    1991-01-01T23:59:59.000Z

    A low-rank coal oil agglomeration process. High mineral content, a high ash content subbituminous coals are effectively agglomerated with a bridging oil which is partially water soluble and capable of entering the pore structure, and usually coal derived.

  12. COAL SLAGGING AND REACTIVITY TESTING

    SciTech Connect (OSTI)

    Donald P. McCollor; Kurt E. Eylands; Jason D. Laumb

    2003-10-01T23:59:59.000Z

    Union Fenosa's La Robla I Power Station is a 270-MW Foster Wheeler arch-fired system. The unit is located at the mine that provides a portion of the semianthracitic coal. The remaining coals used are from South Africa, Russia, Australia, and China. The challenges at the La Robla I Station stem from the various fuels used, the characteristics of which differ from the design coal. The University of North Dakota Energy & Environmental Research Center (EERC) and the Lehigh University Energy Research Center (LUERC) undertook a program to assess problematic slagging and unburned carbon issues occurring at the plant. Full-scale combustion tests were performed under baseline conditions, with elevated oxygen level and with redistribution of air during a site visit at the plant. During these tests, operating information, observations and temperature measurements, and coal, slag deposit, and fly ash samples were obtained to assess slagging and unburned carbon. The slagging in almost all cases appeared due to elevated temperatures rather than fuel chemistry. The most severe slagging occurred when the temperature at the sampling port was in excess of 1500 C, with problematic slagging where first-observed temperatures exceeded 1350 C. The presence of anorthite crystals in the bulk of the deposits analyzed indicates that the temperatures were in excess of 1350 C, consistent with temperature measurements during the sampling period. Elevated temperatures and ''hot spots'' are probably the result of poor mill performance, and a poor distribution of the coal from the mills to the specific burners causes elevated temperatures in the regions where the slag samples were extracted. A contributing cause appeared to be poor combustion air mixing and heating, resulting in oxygen stratification and increased temperatures in certain areas. Air preheater plugging was observed and reduces the temperature of the air in the windbox, which leads to poor combustion conditions, resulting in unburned carbon as well as slagging. A second phase of the project involved advanced analysis of the baseline coal along with an Australian coal fired at the plant. These analysis results were used in equilibrium thermodynamic modeling along with a coal quality model developed by the EERC to assess slagging, fouling, and opacity for the coals. Bench-scale carbon conversion testing was performed in a drop-tube furnace to assess the reactivity of the coals. The Australian coal had a higher mineral content with significantly more clay minerals present than the baseline coal. The presence of these clay minerals, which tend to melt at relatively low temperatures, indicated a higher potential for problematic slagging than the baseline coal. However, the pyritic minerals, comprising over 25% of the baseline mineral content, may form sticky iron sulfides, leading to severe slagging in the burner region if local areas with reducing conditions exist. Modeling results indicated that neither would present significant fouling problems. The Australian coal was expected to show slagging behavior much more severe than the baseline coal except at very high furnace temperatures. However, the baseline coal was predicted to exhibit opacity problems, as well as have a higher potential for problematic calcium sulfate-based low-temperature fouling. The baseline coal had a somewhat higher reactivity than the Australian coal, which was consistent with both the lower average activation energy for the baseline coal and the greater carbon conversion at a given temperature and residence time. The activation energy of the baseline coal showed some effect of oxygen on the activation energy, with E{sub a} increasing at the lower oxygen concentration, but may be due to the scatter in the baseline coal kinetic values at the higher oxygen level tested.

  13. Coal preparation: The essential clean coal technology

    SciTech Connect (OSTI)

    Cain, D.

    1993-12-31T23:59:59.000Z

    This chapter is a brief introduction to a broad topic which has many highly specialized areas. The aim is to summarize the essential elements of coal preparation and illustrate its important role in facilitating the clean use of coal. Conventional coal preparation is the essential first step in ensuring the economic and environmentally acceptable use of coal. The aim of coal preparation is to produce saleable products of consistent, specified quality which satisfy customer requirements while optimizing the utilization of the coal resource. Coal preparation covers all aspects of preparing coal for the market. It includes size reduction, blending and homogenization and, most importantly, the process of physical beneficiation or washing, which involves separation of undesirable mineral matter from the coal substance itself. Coal preparation can be performed at different levels of sophistication and cost. The degree of coal preparation required is decided by considering the quality of the raw coal, transport costs and, in particular, the coal quality specified by the consumer. However, the cost of coal beneficiation rises rapidly with the complexity of the process and some coal is lost with the waste matter because of process inefficiencies, therefore each situation requires individual study to determine the optimum coal preparation strategy. The necessary expertise is available within APEC countries such as Australia. Coals destined for iron making are almost always highly beneficiated. Physical beneficiation is mostly confined to the higher rank, hard coals, but all other aspects of coal preparation can be applied to subbituminous and lignitic coals to improve their utilization. Also, there are some interesting developments aimed specifically at reducing the water content of lower rank coals.

  14. COMBUSTION OF COAL IN AN OPPOSED FLOW DIFFUSION BURNER

    E-Print Network [OSTI]

    Chin, W.K.

    2010-01-01T23:59:59.000Z

    TABLE 1. Pittsburgh seam coal properties, Grosshandler (content of the Pittsburgh seam coal. As the ash layer beginsfrom Pittsburgh seam pulverized coal, screened through a 35

  15. Apparatus for fixed bed coal gasification

    DOE Patents [OSTI]

    Sadowski, Richard S. (Greenville, SC)

    1992-01-01T23:59:59.000Z

    An apparatus for fixed-bed coal gasification is described in which coal such as caking coal is continuously pyrolyzed with clump formation inhibited, by combining the coal with a combustible gas and an oxidant, and then continually feeding the pyrolyzed coal under pressure and elevated temperature into the gasification region of a pressure vessel. The materials in the pressure vessel are allowed to react with the gasifying agents in order to allow the carbon contents of the pyrolyzed coal to be completely oxidized. The combustion of gas produced from the combination of coal pyrolysis and gasification involves combining a combustible gas coal and an oxidant in a pyrolysis chamber and heating the components to a temperature of at least 1600.degree. F. The products of coal pyrolysis are dispersed from the pyrolyzer directly into the high temperature gasification region of a pressure vessel. Steam and air needed for gasification are introduced in the pressure vessel and the materials exiting the pyrolyzer flow down through the pressure vessel by gravity with sufficient residence time to allow any carbon to form carbon monoxide. Gas produced from these reactions are then released from the pressure vessel and ash is disposed of.

  16. USE OF COAL DRYING TO REDUCE WATER CONSUMED IN PULVERIZED COAL POWER PLANTS

    SciTech Connect (OSTI)

    Edward Levy

    2005-10-01T23:59:59.000Z

    Low rank fuels such as subbituminous coals and lignites contain significant amounts of moisture compared to higher rank coals. Typically, the moisture content of subbituminous coals ranges from 15 to 30 percent, while that for lignites is between 25 and 40 percent, where both are expressed on a wet coal basis. High fuel moisture has several adverse impacts on the operation of a pulverized coal generating unit. High fuel moisture results in fuel handling problems, and it affects heat rate, mass rate (tonnage) of emissions, and the consumption of water needed for evaporative cooling. This project deals with lignite and subbituminous coal-fired pulverized coal power plants, which are cooled by evaporative cooling towers. In particular, the project involves use of power plant waste heat to partially dry the coal before it is fed to the pulverizers. Done in a proper way, coal drying will reduce cooling tower makeup water requirements and also provide heat rate and emissions benefits. The technology addressed in this project makes use of the hot circulating cooling water leaving the condenser to heat the air used for drying the coal (Figure 1). The temperature of the circulating water leaving the condenser is usually about 49 C (120 F), and this can be used to produce an air stream at approximately 43 C (110 F). Figure 2 shows a variation of this approach, in which coal drying would be accomplished by both warm air, passing through the dryer, and a flow of hot circulating cooling water, passing through a heat exchanger located in the dryer. Higher temperature drying can be accomplished if hot flue gas from the boiler or extracted steam from the turbine cycle is used to supplement the thermal energy obtained from the circulating cooling water. Various options such as these are being examined in this investigation. This is the eleventh Quarterly Report for this project. The background and technical justification for the project are described, including potential benefits of reducing fuel moisture using power plant waste heat, prior to firing the coal in a pulverized coal boiler. During this last Quarter, the development of analyses to determine the costs and financial benefits of coal drying was continued. The details of the model and key assumptions being used in the economic evaluation are described in this report.

  17. USE OF COAL DRYING TO REDUCE WATER CONSUMED IN PULVERIZED COAL POWER PLANTS

    SciTech Connect (OSTI)

    Edward K. Levy; Nenad Sarunac; Harun Bilirgen; Hugo Caram

    2006-03-01T23:59:59.000Z

    U.S. low rank coals contain relatively large amounts of moisture, with the moisture content of subbituminous coals typically ranging from 15 to 30 percent and that for lignites from 25 and 40 percent. High fuel moisture has several adverse impacts on the operation of a pulverized coal generating unit, for it can result in fuel handling problems and it affects heat rate, stack emissions and maintenance costs. Theoretical analyses and coal test burns performed at a lignite fired power plant show that by reducing the fuel moisture, it is possible to improve boiler performance and unit heat rate, reduce emissions and reduce water consumption by the evaporative cooling tower. The economic viability of the approach and the actual impact of the drying system on water consumption, unit heat rate and stack emissions will depend critically on the design and operating conditions of the drying system. The present project evaluated the low temperature drying of high moisture coals using power plant waste heat to provide the energy required for drying. Coal drying studies were performed in a laboratory scale fluidized bed dryer to gather data and develop models on drying kinetics. In addition, analyses were carried out to determine the relative costs and performance impacts (in terms of heat rate, cooling tower water consumption and emissions) of drying along with the development of optimized drying system designs and recommended operating conditions.

  18. Characterization of ash deposition and heat transfer behavior of coals during combustion in a pilot-scale facility and full-scale utility

    SciTech Connect (OSTI)

    Sushil Gupta; Rajender Gupta; Gary Bryant; Terry Wall; Shinji Watanabe; Takashi Kiga; Kimihito Narukawa [University of New South Wales, Sydney, NSW (Australia). Centre for Sustainable Materials Research & Technology

    2009-05-15T23:59:59.000Z

    Experimental measurements as well as theoretical models were used to investigate the impact of mineral matter of three coals on ash deposition and heat transfer for pulverized coal fired boilers. The ash deposition experiments were conducted in a pulverized fuel combustion pilot-scale facility and a full-scale unit. A mathematical model with input from computer-controlled scanning electron microscopy analysis of coal minerals was used to predict the effect of ash deposition on heat transfer. The predicted deposit thickness and heat flux from the model are shown to be consistent with the measurements in the test facility. The model differentiates the coals according to the deposits they form and their effect on heat transfer. The heat transfer predictions in the full-scale unit were found to be most suitable for the water wall under the furnace nose. The study demonstrates that the measurements in a full-scale unit can differ significantly from those in pilot-scale furnaces due to soot-blowing operations. 9 refs., 12 figs., 3 tabs.

  19. Advanced coal conversion process demonstration. Progress report, January 1, 1992--December 31, 1992

    SciTech Connect (OSTI)

    NONE

    1993-12-01T23:59:59.000Z

    This report contains a description of the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from January 1, 1992, through December 31, 1992. This project demonstrates an advanced thermal coal drying process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal{reg_sign} process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After drying, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. The SynCoal{reg_sign} process enhances low-rank, western coals, usually with a moisture content of 25 to 55 percent, sulfur content of 0.5 to 1.5 percent, and heating value of 5,500 to 9,000 British thermal units per pound (Btu/lb), by producing a stable, upgraded, coal product with a moisture content as low as 1 percent, sulfur content as low as 0.3 percent, and heating value up to 12,000 Btu/lb. The 45-ton-per-hour unit is located adjacent to a unit train loadout facility at Western Energy Company`s Rosebud coal mine near Colstrip, Montana. The demonstration plant is sized at about one-tenth the projected throughput of a multiple processing train commercial facility. The demonstration drying and cooling equipment is currently near commercial size. Rosebud SynCoal Partnership`s ACCP Demonstration Facility entered Phase III, Demonstration Operation, in April 1992 and has been operating in an extended startup mode since that time. As with any new developing technology, a number of unforeseen obstacles have been encountered; however, Rosebud SynCoal Partnership has instituted an aggressive program to overcome these obstacles.

  20. Cycle simulation of coal-fueled engines utilizing low heat rejection concepts

    E-Print Network [OSTI]

    Roth, John M.

    1988-01-01T23:59:59.000Z

    time step (kg) Total mass of' exhaust gas expelled during exhaust process (kg) Mean Effective Pressure (kPa) Nitric Oxide Emissions Thermal Efficiency (%) Cylinder Pressure (kPa) Piston Reversal Point PSZ RHCE RPM +cog Tcoo! Tech Tg... calculations. Results from the model indicated that autoignition of solid, non-volatile coal particles would not occur in a conventional compression ignition engine. A diesel pilot of 10 percent of the total energy input was required to achieve stable...

  1. Study on the effect of heat treatment and gasification on the carbon structure of coal chars and metallurgical cokes using fourier transform Raman spectroscopy

    SciTech Connect (OSTI)

    S. Dong; P. Alvarez; N. Paterson; D.R. Dugwell; R. Kandiyoti [Imperial College London, London (United Kingdom). Department of Chemical Engineering

    2009-03-15T23:59:59.000Z

    Differences in the development of carbon structures between coal chars and metallurgical cokes during high-temperature reactions have been investigated using Raman spectroscopy. These are important to differentiate between different types of carbons in dust recovered from the top gas of the blast furnace. Coal chars have been prepared from a typical injectant coal under different heat-treatment conditions. These chars reflected the effect of peak temperature, residence time at peak temperature, heating rate and pressure on the evolution of their carbon structures. The independent effect of gasification on the development of the carbon structure of a representative coal char has also been studied. A similar investigation has also been carried out to study the effect of heat-treatment temperature (from 1300 to 2000{sup o}C) and gasification on the carbon structure of a typical metallurgical coke. Two Raman spectral parameters, the intensity ratio of the D band to the G band (I{sub D}/I{sub G}) and the intensity ratio of the valley between D and G bands to the G band (I{sub V}/I{sub G}), have been found useful in assessing changes in carbon structure. An increase in I{sub D}/I{sub G} indicates the growth of basic graphene structural units across the temperature range studied. A decrease in I{sub V}/I{sub G} appears to suggest the elimination of amorphous carbonaceous materials and ordering of the overall carbon structure. The Raman spectral differences observed between coal chars and metallurgical cokes are considered to result from the difference in the time-temperature history between the raw injectant coal and the metallurgical coke and may lay the basis for differentiation between metallurgical coke fines and coal char residues present in the dust carried over the top of the blast furnace. 41 refs., 17 figs., 3 tabs.

  2. A coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, April 1992--June 1992

    SciTech Connect (OSTI)

    Not Available

    1992-09-03T23:59:59.000Z

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation`s Phase III development contract DE-AC22-91PC91161 for a ``Coal-Fired Combustion System for Industrial Process Heating Applications`` is project funded under the DOE/PETC advanced combustion program. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelling and waste vitrification processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the current reporting period, approval of Vortec`s Environmental Assessment (EA) required under the National Environmental Policy Act (NEPA) was approved. The EA approval cycle took approximately 9 months. The preliminary test program which was being held in abeyance pending approval of the EA was initiated. Six preliminary test runs were successfully competed during the period. Engineering and design activities in support of the Phase III proof of concept are continuing, and modifications to the existing test system configuration to allow performance of the preliminary tests were completed.

  3. Development of a coal-fueled Internal Manifold Heat Exchanger (IMHEX reg sign ) molten carbonate fuel cell

    SciTech Connect (OSTI)

    Not Available

    1991-09-01T23:59:59.000Z

    The design of a CGMCFC electric generation plant that will provide a cost of eletricity (COE) which is lower than that of current electric generation technologies and which is competitive with other long-range electric generating systems is presented. This effort is based upon the Internal Manifold Heat Exchanger (IMHEX) technology as developed by the Institute of Gas Technology (IGT). The project was executed by selecting economic and performance objectives for alternative plant arrangements while considering process constraints identified during IMHEX fuel cell development activities at ICT. The four major subsystems of a coal-based MCFC power plant are coal gasification, gas purification, fuel cell power generation and the bottoming cycle. The design and method of operation of each subsystem can be varied, and, depending upon design choices, can have major impact on both the design of other subsystems and the resulting cost of electricity. The challenge of this project was to select, from a range of design parameters, those operating conditions that result in a preferred plant design. Computer modelling was thus used to perform sensitivity analyses of as many system variables as program resources and schedules would permit. In any systems analysis, it is imperative that the evaluation methodology be verifiable and comparable. The TAG Class I develops comparable (if imprecise) data on performance and costs for the alternative cases being studied. It identifies, from a range of options, those which merit more exacting scrutiny to be undertaken at the second level, TAG class II analysis.

  4. Proceedings of the joint contractors meeting: FE/EE Advanced Turbine Systems conference FE fuel cells and coal-fired heat engines conference

    SciTech Connect (OSTI)

    Geiling, D.W. [ed.

    1993-08-01T23:59:59.000Z

    The joint contractors meeting: FE/EE Advanced Turbine Systems conference FEE fuel cells and coal-fired heat engines conference; was sponsored by the US Department of Energy Office of Fossil Energy and held at the Morgantown Energy Technology Center, P.O. Box 880, Morgantown, West Virginia 26507-0880, August 3--5, 1993. Individual papers have been entered separately.

  5. Hydrodesulfurization and hydrodenitrogenation catalysts obtained from coal mineral matter

    DOE Patents [OSTI]

    Liu, Kindtoken H. D. (Newark, DE); Hamrin, Jr., Charles E. (Lexington, KY)

    1982-01-01T23:59:59.000Z

    A hydrotreating catalyst is prepared from coal mineral matter obtained by low temperature ashing coals of relatively low bassanite content by the steps of: (a) depositing on the low temperature ash 0.25-3 grams of an iron or nickel salt in water per gram of ash and drying a resulting slurry; (b) crushing and sizing a resulting solid; and (c) heating the thus-sized solid powder in hydrogen.

  6. Mathematical Modeling of Coal Gasification Processes in a Well-Stirred Reactor: Effects of Devolatilization and Moisture Content

    E-Print Network [OSTI]

    Qiao, Li

    Mathematical Modeling of Coal Gasification Processes in a Well- Stirred Reactor: Effects in coal and biomass play an important role on the gasification performance of these fuels to simulate the gasification processes in a well-stirred reactor. This model is a first

  7. Quarterly technical progress report No. 2, December 20-March 19, 1982. Second quarterly report on the effect of rapid heating rate on coal nitrogen and sulfur release

    SciTech Connect (OSTI)

    Gat, N.

    1982-04-26T23:59:59.000Z

    A laser pyrolysis technique is applied to the investigation of the effects of heating rate on release of coal-bound sulfur and nitrogen. An experimental system characterization and calibration has been completed. A detailed documentation was prepared describing the 3-color pyrometer and the data analysis technique. The coal particle feed system has been calibrated to provide accurate mass flow rate at pre-selected particle velocities. The first batch of samples submitted for chemical analysis will be used for the determination of kinetics parameters at a high heating rate (approximately equal to 10/sup 6/ K/s). The coal used presently is a Montana Rosebud. Two other coals are available; one is ILL No. 6 (through EERC) which will need to be pulverized and the second is a Pitt. hv-A (through KVB). It was confirmed that sieve and drag size distribution of coal differ significantly, and that particle shape effects may be significant in the modelling of particle dynamics.

  8. Advanced Coal Conversion Process Demonstration Project. Final technical progress report, January 1, 1995--December 31, 1995

    SciTech Connect (OSTI)

    NONE

    1997-05-01T23:59:59.000Z

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from January 1, 1995 through December 31, 1995. This project demonstrates an advanced, thermal, coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal Process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal upgrading, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. The SynCoal Process enhances low-rank, western coals, usually with a moisture content of 25 to 55 percent, sulfur content of 0.5 to 1.5 percent, and heating value of 5,5000 to 9,000 British thermal units per pound (Btu/lb), by producing a stable, upgraded, coal product with a moisture content as low as 1 percent, sulfur content as low as 0.3 percent, and heating value up to 12,000 Btu/lb. During this reporting period, the primary focus for the ACCP Demonstration Project team was to expand SynCoal market awareness and acceptability for both the products and the technology. The ACCP Project team continued to focus on improving the operation, developing commercial markets, and improving the SynCoal products as well as the product`s acceptance.

  9. Vapor pressures and heats of vaporization of primary coal tars. Quarterly technical progress report, 1 July 1993--30 September 1993

    SciTech Connect (OSTI)

    Suuberg, E.M.; Oja, V.; Lilly, W.D.

    1993-12-31T23:59:59.000Z

    There is significant current interest in general area of coal pyrolysis, particularly with respect to comprehensive models of this complicated phenomenon. This interest derives from the central role of pyrolysis in all thermally driven coal conversion processes -- gasification, combustion, liquefaction, mild gasification, or thermal benefication. There remain several key data needs in these application areas. Among them is a need for more reliable correlation for prediction of vapor pressure of heavy, primary coal tars. Such information is important in design of all coal conversion processes, in which the volatility of tarry products is of major concern. Only very limited correlations exist, and these are not considered reliable to even an order of magnitude when applied to tars. The present project seeks to address this important gap in the near term by direct measurement of vapor pressures of coal tar fractions, by application of well-established techniques and modifications thereof. The principal objectives of the program are to: (1) obtain data on the vapor pressures and heats of vaporization of tars from a range of ranks of coal, (2) develop correlations based on a minimum set of conveniently measurable characteristics of the tars, (3) develop equipment that would allow performing such measurements in a reliable, straightforward fashion. Results of the literature survey are compiled. The experimental tasks have been concerned with setup and calibration.

  10. Energy and environmental research emphasizing low-rank coal -- Task 5.1, Stability issues

    SciTech Connect (OSTI)

    Anderson, C.M.; Musich, M.A.; Dewall, R.A.; Richter, J.J.

    1995-04-01T23:59:59.000Z

    Low-sulfur subbituminous and lignite coals have high moisture content and, consequently, low heating value, leading to boiler derating in US midwestern and eastern utilities as well as switching and/or blending coals to achieve SO{sub 2} compliance. In the drive to develop cost-effective coal-drying processes, coal developers have focused on heat content of the products and generally neglected the critical stability issues of friability and dusting, moisture reabsorption, and spontaneous heating. The Energy and Environmental Research Center (EERC), in an effort to establish new standards for dried products, has used established methods and has developed new ones to evaluate the propensity of lump western coals, raw and dried, to produce dust and absorb water. Three drying methods--air, hydrothermal, and saturated steam--were used to generate low-moisture upgraded products. New indices for dust generation and friability were determined to assess the effects of moisture removal and upgrading methodology on coal stability. Analysis of the dried coals using various strength tests indicated that the reduction in moisture made the lump coal unstable, yielding substantially higher dust and friability indices relative to those of the raw coals.

  11. Influence of phosphorus content and heat treatment on the machinability of electroless nickel deposits

    SciTech Connect (OSTI)

    Syn, C.K.; Dini, J.W.; Taylor, J.S.; Mara, G.L.; Vandervoort, R.R.; Donaldson, R.R.

    1985-01-14T23:59:59.000Z

    Diamond turning is the use of a single point diamond tool on a precision lathe under very precisely controlled machine and environmental conditions to fabricate finished components. Coatings offer significant advantages for diamond turning applications inasmuch as they can be applied to light weight substrates such as aluminum or beryllium, or unusual substrates such as molybdenum or glass. One of the most used frequently employed coatings for diamond turning applications is electroless nickel. On occasions, electroless nickel deposits are not diamond turnable, e.g., tool life is shortened. This could be a function of phosphorus content, age of the solution, stress in the deposit, additives in the solution, heat treat conditions, etc. Efforts reported in this paper include machinability studies on electroless nickel deposits varying in composition from 1.8-13% phosphorus in the as-deposited condition, and after heating at 200, 400 and 600/sup 0/C.

  12. [Advanced Coal Conversion Process Demonstration Project]. Technical progress report: April 1, 1992--June 30, 1992

    SciTech Connect (OSTI)

    Not Available

    1993-10-01T23:59:59.000Z

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from April 1, 1992, through June 30, 1992. This project demonstrates an advanced thermal coal drying process coupled with physical cleaning techniques designed to upgrade high-moisture, low-rank coals into a high-quality, low-sulfur fuel, registered as the SynCoal{reg_sign} process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After drying, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. The SynCoal{reg_sign} process enhances low-rank, western coals, usually with a moisture content of 25 to 55 percent, sulfur content of 0.5 to 1.5 percent, and heating value of 5,500 to 9,000 British thermal units per pound (Btu/Ib), by producing a stable, upgraded coal product with a moisture content as low as 1 percent, sulfur content as low as 0.3 percent, and heating value up to 12,000 Btu/lb. The 45-ton-per-hour unit is located adjacent to a unit train loadout facility at Western Energy Company`s Rosebud coal mine near Colstrip, Montana. The demonstration plant is sized at about one-tenth the projected throughput of a multiple processing train commercial facility. The demonstration drying and cooling equipment is currently near commercial size.

  13. Coal Combustion Science

    SciTech Connect (OSTI)

    Hardesty, D.R. (ed.); Fletcher, T.H.; Hurt, R.H.; Baxter, L.L. (Sandia National Labs., Livermore, CA (United States))

    1991-08-01T23:59:59.000Z

    The objective of this activity is to support the Office of Fossil Energy in executing research on coal combustion science. This activity consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency Coal Combustion Science Project. Specific tasks for this activity include: (1) coal devolatilization - the objective of this risk is to characterize the physical and chemical processes that constitute the early devolatilization phase of coal combustion as a function of coal type, heating rate, particle size and temperature, and gas phase temperature and oxidizer concentration; (2) coal char combustion -the objective of this task is to characterize the physical and chemical processes involved during coal char combustion as a function of coal type, particle size and temperature, and gas phase temperature and oxygen concentration; (3) fate of mineral matter during coal combustion - the objective of this task is to establish a quantitative understanding of the mechanisms and rates of transformation, fragmentation, and deposition of mineral matter in coal combustion environments as a function of coal type, particle size and temperature, the initial forms and distribution of mineral species in the unreacted coal, and the local gas temperature and composition.

  14. ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE

    E-Print Network [OSTI]

    Ferrell, G.C.

    2010-01-01T23:59:59.000Z

    Synthetic Fuel from Coal," Federal Energy Administration,Chemical Refining of Coal," Battelle Energy Program Report,reserves coal characteristics energy content sulfur ash ni

  15. Measurement of gas species, temperatures, coal burnout, and wall heat fluxes in a 200 MWe lignite-fired boiler with different overfire air damper openings

    SciTech Connect (OSTI)

    Jianping Jing; Zhengqi Li; Guangkui Liu; Zhichao Chen; Chunlong Liu [Harbin Institute of Technology, Harbin (China). School of Energy Science and Engineering

    2009-07-15T23:59:59.000Z

    Measurements were performed on a 200 MWe, wall-fired, lignite utility boiler. For different overfire air (OFA) damper openings, the gas temperature, gas species concentration, coal burnout, release rates of components (C, H, and N), furnace temperature, and heat flux and boiler efficiency were measured. Cold air experiments for a single burner were conducted in the laboratory. The double-swirl flow pulverized-coal burner has two ring recirculation zones starting in the secondary air region in the burner. As the secondary air flow increases, the axial velocity of air flow increases, the maxima of radial velocity, tangential velocity and turbulence intensity all increase, and the swirl intensity of air flow and the size of recirculation zones increase slightly. In the central region of the burner, as the OFA damper opening widens, the gas temperature and CO concentration increase, while the O{sub 2} concentration, NOx concentration, coal burnout, and release rates of components (C, H, and N) decrease, and coal particles ignite earlier. In the secondary air region of the burner, the O{sub 2} concentration, NOx concentration, coal burnout, and release rates of components (C, H, and N) decrease, and the gas temperature and CO concentration vary slightly. In the sidewall region, the gas temperature, O{sub 2} concentration, and NOx concentration decrease, while the CO concentration increases and the gas temperature varies slightly. The furnace temperature and heat flux in the main burning region decrease appreciably, but increase slightly in the burnout region. The NOx emission decreases from 1203.6 mg/m{sup 3} (6% O{sub 2}) for a damper opening of 0% to 511.7 mg/m{sup 3} (6% O{sub 2}) for a damper opening of 80% and the boiler efficiency decreases from 92.59 to 91.9%. 15 refs., 17 figs., 3 tabs.

  16. Clean coal technologies market potential

    SciTech Connect (OSTI)

    Drazga, B. (ed.)

    2007-01-30T23:59:59.000Z

    Looking at the growing popularity of these technologies and of this industry, the report presents an in-depth analysis of all the various technologies involved in cleaning coal and protecting the environment. It analyzes upcoming and present day technologies such as gasification, combustion, and others. It looks at the various technological aspects, economic aspects, and the various programs involved in promoting these emerging green technologies. Contents: Industry background; What is coal?; Historical background of coal; Composition of coal; Types of coal; Environmental effects of coal; Managing wastes from coal; Introduction to clean coal; What is clean coal?; Byproducts of clean coal; Uses of clean coal; Support and opposition; Price of clean coal; Examining clean coal technologies; Coal washing; Advanced pollution control systems; Advanced power generating systems; Pulverized coal combustion (PCC); Carbon capture and storage; Capture and separation of carbon dioxide; Storage and sequestration of carbon dioxide; Economics and research and development; Industry initiatives; Clean Coal Power Initiative; Clean Coal Technology Program; Coal21; Outlook; Case Studies.

  17. Wiang Haeng coal-water fuel preparation and gasification, Thailand - task 39

    SciTech Connect (OSTI)

    Anderson, C.M.; Musich, M.A.; Young, B.C. [and others

    1996-07-01T23:59:59.000Z

    In response to an inquiry by the Department of Mineral Resources (DMR) in Thailand, the Energy & Environmental Research Center (EERC) prepared a four-task program to assess the responsiveness of Wiang Haeng coal to the temperature and pressure conditions of hot-water drying (HWD). The results indicate that HWD made several improvements in the coal, notably increases (HWD). The results indicate that HWD made several improvements in the coal, notably increases in heating value and carbon content and reductions in equilibrium moisture and oxygen content. The equilibrium moisture content decreased from 37.4 wt% for the raw coal to about 20 wt% for the HWD coals. The energy density for a pumpable coal-water fuel indicates an increase from 4450 to 6650 Btu/lb by hydrothermal treatment. Raw and HWD coal were then gasified at various mild gasification conditions of 700{degrees}C and 30 psig. The tests indicated that the coal is probably similar to other low-rank coals, will produce high levels of hydrogen, and be fairly reactive.

  18. State coal profiles, January 1994

    SciTech Connect (OSTI)

    Not Available

    1994-02-02T23:59:59.000Z

    The purpose of State Coal Profiles is to provide basic information about the deposits, production, and use of coal in each of the 27 States with coal production in 1992. Although considerable information on coal has been published on a national level, there is a lack of a uniform overview for the individual States. This report is intended to help fill that gap and also to serve as a framework for more detailed studies. While focusing on coal output, State Coal Profiles shows that the coal-producing States are major users of coal, together accounting for about three-fourths of total US coal consumption in 1992. Each coal-producing State is profiled with a description of its coal deposits and a discussion of the development of its coal industry. Estimates of coal reserves in 1992 are categorized by mining method and sulfur content. Trends, patterns, and other information concerning production, number of mines, miners, productivity, mine price of coal, disposition, and consumption of coal are detailed in statistical tables for selected years from 1980 through 1992. In addition, coal`s contribution to the State`s estimated total energy consumption is given for 1991, the latest year for which data are available. A US summary of all data is provided for comparing individual States with the Nation as a whole. Sources of information are given at the end of the tables.

  19. Validation/Uncertainty Quantification for Large Eddy Simulations of the heat flux in the Tangentially Fired Oxy-Coal Alstom Boiler Simulation Facility

    SciTech Connect (OSTI)

    Smith, P.J.; Eddings, E.G.; Ring, T.; Thornock, J.; Draper, T.; Isaac, B.; Rezeai, D.; Toth, P.; Wu, Y.; Kelly, K.

    2014-08-01T23:59:59.000Z

    The objective of this task is to produce predictive capability with quantified uncertainty bounds for the heat flux in commercial-scale, tangentially fired, oxy-coal boilers. Validation data came from the Alstom Boiler Simulation Facility (BSF) for tangentially fired, oxy-coal operation. This task brings together experimental data collected under Alstom’s DOE project for measuring oxy-firing performance parameters in the BSF with this University of Utah project for large eddy simulation (LES) and validation/uncertainty quantification (V/UQ). The Utah work includes V/UQ with measurements in the single-burner facility where advanced strategies for O2 injection can be more easily controlled and data more easily obtained. Highlights of the work include: • Simulations of Alstom’s 15 megawatt (MW) BSF, exploring the uncertainty in thermal boundary conditions. A V/UQ analysis showed consistency between experimental results and simulation results, identifying uncertainty bounds on the quantities of interest for this system (Subtask 9.1) • A simulation study of the University of Utah’s oxy-fuel combustor (OFC) focused on heat flux (Subtask 9.2). A V/UQ analysis was used to show consistency between experimental and simulation results. • Measurement of heat flux and temperature with new optical diagnostic techniques and comparison with conventional measurements (Subtask 9.3). Various optical diagnostics systems were created to provide experimental data to the simulation team. The final configuration utilized a mid-wave infrared (MWIR) camera to measure heat flux and temperature, which was synchronized with a high-speed, visible camera to utilize two-color pyrometry to measure temperature and soot concentration. • Collection of heat flux and temperature measurements in the University of Utah’s OFC for use is subtasks 9.2 and 9.3 (Subtask 9.4). Several replicates were carried to better assess the experimental error. Experiments were specifically designed for the generation of high-fidelity data from a turbulent oxy-coal flame for the validation of oxy-coal simulation models. Experiments were also conducted on the OFC to determine heat flux profiles using advanced strategies for O2 injection. This is important when considering retrofit of advanced O2 injection in retrofit configurations.

  20. Low-rank coal study : national needs for resource development. Volume 2. Resource characterization

    SciTech Connect (OSTI)

    Not Available

    1980-11-01T23:59:59.000Z

    Comprehensive data are presented on the quantity, quality, and distribution of low-rank coal (subbituminous and lignite) deposits in the United States. The major lignite-bearing areas are the Fort Union Region and the Gulf Lignite Region, with the predominant strippable reserves being in the states of North Dakota, Montana, and Texas. The largest subbituminous coal deposits are in the Powder River Region of Montana and Wyoming, The San Juan Basin of New Mexico, and in Northern Alaska. For each of the low-rank coal-bearing regions, descriptions are provided of the geology; strippable reserves; active and planned mines; classification of identified resources by depth, seam thickness, sulfur content, and ash content; overburden characteristics; aquifers; and coal properties and characteristics. Low-rank coals are distinguished from bituminous coals by unique chemical and physical properties that affect their behavior in extraction, utilization, or conversion processes. The most characteristic properties of the organic fraction of low-rank coals are the high inherent moisture and oxygen contents, and the correspondingly low heating value. Mineral matter (ash) contents and compositions of all coals are highly variable; however, low-rank coals tend to have a higher proportion of the alkali components CaO, MgO, and Na/sub 2/O. About 90% of the reserve base of US low-rank coal has less than one percent sulfur. Water resources in the major low-rank coal-bearing regions tend to have highly seasonal availabilities. Some areas appear to have ample water resources to support major new coal projects; in other areas such as Texas, water supplies may be constraining factor on development.

  1. Chemical comminution of coal

    SciTech Connect (OSTI)

    Mamaghani, A.H.; Beddow, J.K.; Vetter, A.F.

    1987-02-01T23:59:59.000Z

    The objective of the present research is to study the chemical reactivity of a mixture of methyl alcohol and aqueous sodium hydroxide solution in the temperature range 298 to 363 K, and a caustic concentration of 0 to 10 wt. %, on an Iowa bituminous coal. The sample studied was collected from coal zone 4, equivalent to most historical references to Laddsdale coal. The coals in this zone are typical high-sulfur, high-ash middle Pennsylvania Cherokee group coals. The apparent rank is high-volatile C bituminous coal. The relatively high content of sulfur and 23 other elements in these coals is related to near neutral (6-8) pH conditions in the depositional and early diagenetic environments, and to postdepositional sphalerite/calcite/pyrite/kaolinite/barite mineralization.

  2. Coal Cleaning Using Resonance Disintegration for Mercury and Sulfur Reduction Prior to Combustion

    SciTech Connect (OSTI)

    Andrew Lucero

    2005-04-01T23:59:59.000Z

    Coal-cleaning processes have been utilized to increase the heating value of coal by extracting ash-forming minerals in the coal. These processes involve the crushing or grinding of raw coal followed by physical separation processes, taking advantage of the density difference between carbonaceous particles and mineral particles. In addition to the desired increase in the heating value of coal, a significant reduction of the sulfur content of the coal fed to a combustion unit is effected by the removal of pyrite and other sulfides found in the mineral matter. WRI is assisting PulseWave to develop an alternate, more efficient method of liberating and separating the undesirable mineral matter from the carbonaceous matter in coal. The approach is based on PulseWave's patented resonance disintegration technology that reduces that particle size of materials by application of destructive resonance, shock waves, and vortex generating forces. Illinois No.5 coal, a Wyodak coal, and a Pittsburgh No.8 coal were processed using the resonance disintegration apparatus then subjected to conventional density separations. Initial microscopic results indicate that up to 90% of the pyrite could be liberated from the coal in the machine, but limitations in the density separations reduced overall effectiveness of contaminant removal. Approximately 30-80% of the pyritic sulfur and 30-50% of the mercury was removed from the coal. The three coals (both with and without the pyritic phase separated out) were tested in WRI's 250,000 Btu/hr Combustion Test Facility, designed to replicate a coal-fired utility boiler. The flue gases were characterized for elemental, particle bound, and total mercury in addition to sulfur. The results indicated that pre-combustion cleaning could reduce a large fraction of the mercury emissions.

  3. Influence of Romanian steam coal quality on power plants environmental impact

    SciTech Connect (OSTI)

    Matei, M. [Romanian Electricity Authority, Bucharest (Romania). Study, Research and Engineering Group

    1998-12-31T23:59:59.000Z

    Coal provides about 25% of primary energy resources for electricity generation in Romania. Coal is burned in pulverized coal (PC) boilers without flue gas desulfurization (FGD). The coal demands are 90% covered by country`s reserves out of which 80% is lignite. The lignite from Oltenia basin represents about 90% of the domestic lignite quantity used in Romanian power plants. The characteristics defining the typical Romanian lignite are: moisture 40--43%; ash dry basis 37--48%; low heat value 6.0--7.5 MJ/kg; sulfur 0.8--1.2%; volatile matter 17--23%. There are some sorts of lignite which have a higher content of sulfur, but these are used in smaller quantities. RENEL`s strategy includes the preferential utilization of domestic fuels (lignite, hard coal) with imported fuels priority in order natural gas, low sulfur content heavy oil and steam hard coal. Low grade quality of Romanian lignites creates many problems, and due to its high ash and water contents, large quantities of raw coal are required in order to generate energy. The high content of sulfur in coal produces high SO{sub 2} emissions. On the other hand, the very low power values of Romanian lignite generate a low flame temperature, so that, even using fuel oil or gas support for lignite combustion, the NOx emissions are low. Environmental laws have been in force in Romania since December 30, 1995. The Waters Forests and Environment Protection Ministry regulated the pollutant concentration for both new and existing coal fired boilers, beginning in January 1998. Comparing the measured values of SO{sub 2}, NOx and CO contents measured in flue gas from some boilers running on different coal types with the pollutants` emissions limits it is obvious that clean coal technologies (CCT) implementation is necessary, especially for SO{sub 2} reduction.

  4. Apparatus for reducing the moisture content in combustible material by utilizing the heat from combustion of such material

    SciTech Connect (OSTI)

    Williams, R.M.

    1992-03-17T23:59:59.000Z

    This patent describes apparatus for preparing moisture containing fuel material for combustion to produce heat energy and for applying the heat energy from the combustion for lowering the moisture content in the fuel material prior to combustion, the improvement comprising: boiler means for the combustion of the fuel material to produce heat energy, grinding apparatus for preparing the fuel material to produce heat energy; means for collecting prepared fuel material and for feeding the collected fuel material to the boiler means; a main gaseous fluid and fuel material conduit system; a second conduit system connecting the boiler means and the grinding apparatus to conduct heat energy to the grinding apparatus; connecting means between the returning side of the main conduit system and the boiler means for maintaining the main conduit system at a negative pressure to promote the flow of hot gaseous medium from the boiler means to the gringing apparatus.

  5. Coal science for the clean use of coal

    SciTech Connect (OSTI)

    Harrison, J.S. [Univ. of Leeds (United Kingdom)

    1994-12-31T23:59:59.000Z

    Coal will need to be retained as a major source of energy in the next century. It will need to be used more effectively and more cleanly. In order to achieve this, it is necessary to introduce new technology supported by a local community of science and technology. Only in this way can the full benefits of international advances in coal utilization be fully achieved. It is important that full advantage be taken of the advances that have been achieved in laboratory techniques and in the better understanding of fundamental coal science. This paper reviews available technologies in power generation, industrial process heat, coal combustion, coal gasification, and coal analytical procedures.

  6. Bio-coal briquette

    SciTech Connect (OSTI)

    Honda, Hiroshi

    1993-12-31T23:59:59.000Z

    Some of the developing nations aim to earn foreign currency by exporting oil and/or gas and to increase the domestic consumption of coal to ensure a secure energy supply. Therefore, it is very important to promote effective coal utilization in these nations. Currently, these countries experience problems associated with coal use for household cooking and household industries. For household cooking, coal creates too much smoke and smells unpleasant. In addition, illegally obtained firewood is almost free in local agricultural regions. Coal is also used in household industries; however, simple stoker boilers are inefficient, since unburned coal particles tend to drop through screens during the combustion process. The bio-coal briquette, on the other hand, is an effective and efficient fuel, since it utilizes coal, which is to be used extensively in households and in small and medium-scale industry sectors in some coal-producing countries, as a primary fuel and bamboos (agricultural waste) as a secondary fuel. In addition, the use of bio-coal briquettes will greatly help reduce unburned coal content.

  7. Fluorine in coal and coal by-products

    SciTech Connect (OSTI)

    Robertson, J.D.; Wong, A.S.; Hower, J.C. [Univ. of Kentucky, Lexington, KY (United States)

    1994-12-31T23:59:59.000Z

    Fluorine occurs in awe amounts in most coals. It is typically associated with minerals of the apatite group, principally fluorapatite and clays, and with fluorite, tourmaline, topaz, amphiboles and micas. The average fluorine content of US coal is, according to the tabulation of Swanson, 74 {mu}g/g. In the United States, the lowest average fluorine concentration of 30 {mu}g/g is found in coals from Eastern Kentucky and the highest average value of 160 {mu}g/g is found in coals from Wyoming and New Mexico. The concentration range of fluorine in European coals is similar to that found in the US while the average fluorine content of Australian coals ranges from 15 to 500 {mu}g/g. We have determined the fluorine content in coal and fly ash standards by proton-induced gamma ray emission analysis (PIGE).

  8. KINETIC STUDY OF COAL AND BIOMASS CO-PYROLYSIS USING THERMOGRAVIMETRY

    SciTech Connect (OSTI)

    Wang, Ping; Hedges, Sheila; Chaudharib, Kiran; Turtonb, Richard

    2013-10-29T23:59:59.000Z

    The objectives of this study are to investigate thermal behavior of coal and biomass blends in inert gas environment at low heating rates and to develop a simplified kinetic model using model fitting techniques based on TGA experimental data. Differences in thermal behavior and reactivity in co-pyrolysis of Powder River Basin (PRB) sub-bituminous coal and pelletized southern yellow pine wood sawdust blends at low heating rates are observed. Coal/wood blends have higher reactivity compared to coal alone in the lower temperature due to the high volatile matter content of wood. As heating rates increase, weight loss rates increase. The experiment data obtained from TGA has a better fit with proposed two step first order reactions model compared single first order reaction model.

  9. Sustainable development with clean coal

    SciTech Connect (OSTI)

    NONE

    1997-08-01T23:59:59.000Z

    This paper discusses the opportunities available with clean coal technologies. Applications include new power plants, retrofitting and repowering of existing power plants, steelmaking, cement making, paper manufacturing, cogeneration facilities, and district heating plants. An appendix describes the clean coal technologies. These include coal preparation (physical cleaning, low-rank upgrading, bituminous coal preparation); combustion technologies (fluidized-bed combustion and NOx control); post-combustion cleaning (particulate control, sulfur dioxide control, nitrogen oxide control); and conversion with the integrated gasification combined cycle.

  10. Clean coal technology applications

    SciTech Connect (OSTI)

    Bharucha, N.

    1993-12-31T23:59:59.000Z

    {open_quotes}Coal is a stratified rock formed of the more or less altered remains of plants (together with associated mineral matter) which flourished in past ages{hor_ellipsis} The problem of the origin and maturing of coal is complicated by the fact that every coal contains, in addition to carbon, hydrogen and oxygen, variable proportions of nitrogen and sulfur which are combined in unknown ways in the organic molecules...{close_quotes}. The challenge with coal has always been the management of its mineral matter, sulfur and nitrogen contents during use. The carbon content of fuels, including coal, is a more recent concern. With clean coal technologies, there are opportunities for ensuring the sustained use of coal for a very long time. The clean coal technologies of today are already capable of reducing, if not eliminating, harmful emissions. The technologies of the future will allow coal to be burned with greatly reduced emissions, thus eliminating the necessity to treat them after they occur.

  11. Research on thermophoretic and inertial aspects of ash particle deposition on heat exchanger surfaces in coal-fired equipment

    SciTech Connect (OSTI)

    Rosner, D.E.

    1990-05-01T23:59:59.000Z

    The overall goal of this research in the area of ash transport was to advance the capability of making reliable engineering predictions of the dynamics and consequences of net deposit growth for surfaces exposed to the products of coal combustion. To accomplish this for a wide variety of combustor types, coal types, and operating conditions, this capability must be based on a quantitative understanding of each of the important mechanisms of mineral matter transport, as well as the nature of the interactions between these substances and the prevailing fireside'' surface of the deposit. This level of understanding and predictive capability could ultimately be translated into very significant cost reductions for coal-fired equipment design, development and operation.

  12. Low-rank coal oil agglomeration

    DOE Patents [OSTI]

    Knudson, C.L.; Timpe, R.C.

    1991-07-16T23:59:59.000Z

    A low-rank coal oil agglomeration process is described. High mineral content, a high ash content subbituminous coals are effectively agglomerated with a bridging oil which is partially water soluble and capable of entering the pore structure, and is usually coal-derived.

  13. Process for forming coal compacts and product thereof

    DOE Patents [OSTI]

    Gunnink, Brett (Columbia, MO); Kanunar, Jayanth (Arlington, MA); Liang, Zhuoxiong (San Francisco, CA)

    2002-01-01T23:59:59.000Z

    A process for forming durable, mechanically strong compacts from coal particulates without use of a binder is disclosed. The process involves applying a compressive stress to a particulate feed comprising substantially water-saturated coal particles while the feed is heated to a final compaction temperature in excess of about 100.degree. C. The water present in the feed remains substantially in the liquid phase throughout the compact forming process. This is achieved by heating and compressing the particulate feed and cooling the formed compact at a pressure sufficient to prevent water present in the feed from boiling. The compacts produced by the process have a moisture content near their water saturation point. As a result, these compacts absorb little water and retain exceptional mechanical strength when immersed in high pressure water. The process can be used to form large, cylindrically-shaped compacts from coal particles (i.e., "coal logs") so that the coal can be transported in a hydraulic coal log pipeline.

  14. Preparation and combustion of coal-water fuel from the Sin Pun coal deposit, southern Thailand

    SciTech Connect (OSTI)

    NONE

    1997-05-01T23:59:59.000Z

    In response to an inquiry by the Department of Mineral Resources in Thailand, the Energy & Environmental Research Center (EERC) prepared a program to assess the responsiveness of Sin Pun lignite to the temperature and pressure conditions of hot-water drying. The results indicate that drying made several improvements in the coal, notably increases in heating value and carbon content and reductions in equilibrium moisture and oxygen content. The equilibrium moisture content decreased from 27 wt% for the raw coal to about 15 wt% for the hot-water-dried (HWD) coals. The energy density for a pumpable coal-water fuel (CWF) indicates an increase from 4500 to 6100 Btu/lb by hot-water drying. Approximately 650 lb of HWD Sin Pun CWF were fired in the EERC`s combustion test facility. The fuel burned extremely well, with no feed problems noted during the course of the test. Fouling and slagging deposits each indicated a very low rate of ash deposition, with only a dusty layer formed on the cooled metal surfaces. The combustor was operated at between 20% and 25% excess air, resulting in a flue gas SO{sub 2} concentration averaging approximately 6500 parts per million.

  15. Clean coal

    SciTech Connect (OSTI)

    Liang-Shih Fan; Fanxing Li [Ohio State University, OH (United States). Dept. of Chemical and Biomolecular Engineering

    2006-07-15T23:59:59.000Z

    The article describes the physics-based techniques that are helping in clean coal conversion processes. The major challenge is to find a cost- effective way to remove carbon dioxide from the flue gas of power plants. One industrially proven method is to dissolve CO{sub 2} in the solvent monoethanolamine (MEA) at a temperature of 38{sup o}C and then release it from the solvent in another unit when heated to 150{sup o}C. This produces CO{sub 2} ready for sequestration. Research is in progress with alternative solvents that require less energy. Another technique is to use enriched oxygen in place of air in the combustion process which produces CO{sub 2} ready for sequestration. A process that is more attractive from an energy management viewpoint is to gasify coal so that it is partially oxidized, producing a fuel while consuming significantly less oxygen. Several IGCC schemes are in operation which produce syngas for use as a feedstock, in addition to electricity and hydrogen. These schemes are costly as they require an air separation unit. Novel approaches to coal gasification based on 'membrane separation' or chemical looping could reduce the costs significantly while effectively capturing carbon dioxide. 1 ref., 2 figs., 1 photo.

  16. Coal-oil slurry preparation

    DOE Patents [OSTI]

    Tao, John C. (Perkiomenville, PA)

    1983-01-01T23:59:59.000Z

    A pumpable slurry of pulverized coal in a coal-derived hydrocarbon oil carrier which slurry is useful as a low-ash, low-sulfur clean fuel, is produced from a high sulfur-containing coal. The initial pulverized coal is separated by gravity differentiation into (1) a high density refuse fraction containing the major portion of non-coal mineral products and sulfur, (2) a lowest density fraction of low sulfur content and (3) a middlings fraction of intermediate sulfur and ash content. The refuse fraction (1) is gasified by partial combustion producing a crude gas product from which a hydrogen stream is separated for use in hydrogenative liquefaction of the middlings fraction (3). The lowest density fraction (2) is mixed with the liquefied coal product to provide the desired fuel slurry. Preferably there is also separately recovered from the coal liquefaction LPG and pipeline gas.

  17. Chemical comminution and deashing of low-rank coals

    DOE Patents [OSTI]

    Quigley, David R. (Idaho Falls, ID)

    1992-01-01T23:59:59.000Z

    A method of chemically comminuting a low-rank coal while at the same time increasing the heating value of the coal. A strong alkali solution is added to a low-rank coal to solubilize the carbonaceous portion of the coal, leaving behind the noncarbonaceous mineral matter portion. The solubilized coal is precipitated from solution by a multivalent cation, preferably calcium.

  18. Chemical comminution and deashing of low-rank coals

    DOE Patents [OSTI]

    Quigley, David R.

    1992-12-01T23:59:59.000Z

    A method of chemically comminuting a low-rank coal while at the same time increasing the heating value of the coal. A strong alkali solution is added to a low-rank coal to solubilize the carbonaceous portion of the coal, leaving behind the noncarbonaceous mineral matter portion. The solubilized coal is precipitated from solution by a multivalent cation, preferably calcium.

  19. System Analysis of Nuclear-Assisted Syngas Production from Coal

    SciTech Connect (OSTI)

    E. A. Harvego; M. G. McKellar; J. E. O'Brien

    2009-07-01T23:59:59.000Z

    A system analysis has been performed to assess the efficiency and carbon utilization of a nuclear-assisted coal gasification process. The nuclear reactor is a high-temperature helium-cooled reactor that is used primarily to provide power for hydrogen production via hightemperature electrolysis. The supplemental hydrogen is mixed with the outlet stream from an oxygen-blown coal gasifier to produce a hydrogen-rich gas mixture, allowing most of the carbon dioxide to be converted into carbon monoxide, with enough excess hydrogen to produce a syngas product stream with a hydrogen/carbon monoxide molar ratio of about 2:1. Oxygen for the gasifier is also provided by the high-temperature electrolysis process. Results of the analysis predict 90.5% carbon utilization with a syngas production efficiency (defined as the ratio of the heating value of the produced syngas to the sum of the heating value of the coal plus the high-temperature reactor heat input) of 64.4% at a gasifier temperature of 1866 K for the high-moisture-content lignite coal considered. Usage of lower moisture coals such as bituminous can yield carbon utilization approaching 100% and 70% syngas production efficiency.

  20. Method for desulfurization of coal

    DOE Patents [OSTI]

    Kelland, David R. (Lexington, MA)

    1987-01-01T23:59:59.000Z

    A process and apparatus for desulfurizing coal which removes sulfur in the inorganic and organic form by preferentially heating the inorganic iron sulfides in coal in a flowing gas to convert some of the inorganic iron sulfides from a pyrite form FeS.sub.2 to a troilite FeS form or a pyrrhotite form Fe.sub.1-x S and release some of the sulfur as a gaseous compound. The troilite and pyrrhotite forms are convenient catalyst for removing the organic sulfur in the next step, which is to react the coal with chemical agents such as alcohol, thus removing the organic sulfur as a liquid or a gas such as H.sub.2 S. The remaining inorganic sulfur is left in the predominantly higher magnetic form of pyrrhotite and is then removed by magnetic separation techniques. Optionally, an organic flocculant may be added after the organic sulfur has been removed and before magnetic separation. The flocculant attaches non-pyrite minerals with the pyrrhotite for removal by magnetic separation to reduce the ash-forming contents.

  1. Method for desulfurization of coal

    DOE Patents [OSTI]

    Kelland, D.R.

    1987-07-07T23:59:59.000Z

    A process and apparatus are disclosed for desulfurizing coal which removes sulfur in the inorganic and organic form by preferentially heating the inorganic iron sulfides in coal in a flowing gas to convert some of the inorganic iron sulfides from a pyrite form FeS[sub 2] to a troilite FeS form or a pyrrhotite form Fe[sub 1[minus]x]S and release some of the sulfur as a gaseous compound. The troilite and pyrrhotite forms are convenient catalyst for removing the organic sulfur in the next step, which is to react the coal with chemical agents such as alcohol, thus removing the organic sulfur as a liquid or a gas such as H[sub 2]S. The remaining inorganic sulfur is left in the predominantly higher magnetic form of pyrrhotite and is then removed by magnetic separation techniques. Optionally, an organic flocculant may be added after the organic sulfur has been removed and before magnetic separation. The flocculant attaches non-pyrite minerals with the pyrrhotite for removal by magnetic separation to reduce the ash-forming contents. 2 figs.

  2. The Use of English Coal in the Netherlands in the 17th and 18th Centuries

    E-Print Network [OSTI]

    Swain, Gregory

    2011-01-01T23:59:59.000Z

    preferred fuel for home heating (unlike in England, whereas a fuel for home heating) [18], in the Netherlands coal

  3. COMPCOAL{trademark}: A profitable process for production of a stable high-Btu fuel from Powder River Basin coal

    SciTech Connect (OSTI)

    Smith, V.E.; Merriam, N.W.

    1994-10-01T23:59:59.000Z

    Western Research Institute (WRI) is developing a process to produce a stable, clean-burning, premium fuel from Powder River Basin (PRB) coal and other low-rank coals. This process is designed to overcome the problems of spontaneous combustion, dust formation, and readsorption of moisture that are experienced with PRB coal and with processed PRB coal. This process, called COMPCOAL{trademark}, results in high-Btu product that is intended for burning in boilers designed for midwestern coals or for blending with other coals. In the COMPCOAL process, sized coal is dried to zero moisture content and additional oxygen is removed from the coal by partial decarboxylation as the coal is contacted by a stream of hot fluidizing gas in the dryer. The hot, dried coal particles flow into the pyrolyzer where they are contacted by a very small flow of air. The oxygen in the air reacts with active sites on the surface of the coal particles causing the temperature of the coal to be raised to about 700{degrees}F (371{degrees}C) and oxidizing the most reactive sites on the particles. This ``instant aging`` contributes to the stability of the product while only reducing the heating value of the product by about 50 Btu/lb. Less than 1 scf of air per pound of dried coal is used to avoid removing any of the condensible liquid or vapors from the coal particles. The pyrolyzed coal particles are mixed with fines from the dryer cyclone and dust filter and the resulting mixture at about 600{degrees}F (316{degrees}C) is fed into a briquettor. Briquettes are cooled to about 250{degrees}F (121{degrees}C) by contact with a mist of water in a gas-tight mixing conveyor. The cooled briquettes are transferred to a storage bin where they are accumulated for shipment.

  4. Alabama Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import CostsLiquids Reserve3.Revenue3ProvedYear Jan Feb Mar

  5. Alabama Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import CostsLiquids Reserve3.Revenue3ProvedYear Jan Feb

  6. Alaska Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import CostsLiquidsYear Jan FebProved ReservesYear Jan Feb

  7. Alaska Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import CostsLiquidsYear Jan FebProved ReservesYear Jan

  8. Arizona Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import CostsLiquidsYear JanYear Jan FebNaturalWorkingYear Jan

  9. Arizona Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import CostsLiquidsYear JanYear Jan FebNaturalWorkingYear

  10. Arkansas Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import CostsLiquidsYear JanYearVented andDecade Year-0

  11. Arkansas Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import CostsLiquidsYear JanYearVented andDecade Year-0Foot)

  12. California Heat Content of Natural Gas Deliveries to Consumers (BTU per

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import CostsLiquidsYearReservesmDecade Year-0Separation,

  13. California Heat Content of Natural Gas Deliveries to Consumers (BTU per

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import CostsLiquidsYearReservesmDecade Year-0Separation,Cubic

  14. Colorado Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import96 4.87 1967-2010 ImportsCubic Feet)+Foot) Decade

  15. Colorado Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import96 4.87 1967-2010 ImportsCubic Feet)+Foot)

  16. Connecticut Heat Content of Natural Gas Deliveries to Consumers (BTU per

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import96 4.87CBECS Public Use Data CBECSYear Jan Feb Mar

  17. Connecticut Heat Content of Natural Gas Deliveries to Consumers (BTU per

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import96 4.87CBECS Public Use Data CBECSYear Jan Feb MarCubic

  18. Delaware Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import96 4.87CBECS Public Use Data0 0 0 00/03) ElectricFoot)

  19. Delaware Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import96 4.87CBECS Public Use Data0 0 0 00/03)

  20. District of Columbia Heat Content of Natural Gas Deliveries to Consumers

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import96 4.87CBECS Public Use Data0 0(BTU per Cubic Foot)

  1. District of Columbia Heat Content of Natural Gas Deliveries to Consumers

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import96 4.87CBECS Public Use Data0 0(BTU per Cubic Foot)(BTU

  2. Florida Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import96NebraskaWells

  3. Georgia Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam Coal Import96NebraskaWellsFoot) Year Jan12,608SamplingSee See

  4. Hawaii Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam CoalReserves (Million Barrels)Reserves from GreaterDecadeFoot)

  5. Idaho Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam CoalReserves (Million Barrels)Reserves from%Year1.A2.Foot)

  6. Illinois Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam CoalReserves (Million Barrels)Reserves%

  7. Indiana Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam CoalReserves (MillionYear Jan Feb Mar Apr May JunApril

  8. Iowa Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam CoalReserves (MillionYear Jan Feb Mar

  9. Kansas Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam CoalReserves (MillionYear Jan FebFoot) Decade Year-0 Year-1 Year-2

  10. Kentucky Heat Content of Natural Gas Deliveries to Consumers (BTU per Cubic

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam CoalReserves (MillionYear JanDecade Year-0ProvedDecade Year-0

  11. Louisiana Heat Content of Natural Gas Deliveries to Consumers (BTU per

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteam CoalReserves (MillionYear(Billion Cubic Feet)ProvedDecade

  12. The development of a coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, January 1992--March 1992

    SciTech Connect (OSTI)

    Not Available

    1992-07-16T23:59:59.000Z

    PETC has implemented a number of advanced combustion research projects that will lead to the establishment of a broad, commercially acceptable engineering data base for the advancement of coal as the fuel of choice for boilers, furnaces, and process heaters. Vortec Corporation`s Coal-Fired Combustion System for Industrial Process Heating Applications has been selected for Phase III development under contract DE-AC22-91PC91161. This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting, recycling, and refining processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase HI research effort is being focused on the development of a process heater system to be used for producing glass frits and wool fiber from boiler and incinerator ashes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. The economic evaluation of commercial scale CMS processes has begun. In order to accurately estimate the cost of the primary process vessels, preliminary designs for 25, 50, and 100 ton/day systems have been started under Task 1. This data will serve as input data for life cycle cost analysis performed as part of techno-economic evaluations. The economic evaluations of commercial CMS systems will be an integral part of the commercialization plan.

  13. Development of a coal-fueled Internal Manifold Heat Exchanger (IMHEX{reg_sign}) molten carbonate fuel cell. Volumes 1--6, Final report

    SciTech Connect (OSTI)

    Not Available

    1991-09-01T23:59:59.000Z

    The design of a CGMCFC electric generation plant that will provide a cost of eletricity (COE) which is lower than that of current electric generation technologies and which is competitive with other long-range electric generating systems is presented. This effort is based upon the Internal Manifold Heat Exchanger (IMHEX) technology as developed by the Institute of Gas Technology (IGT). The project was executed by selecting economic and performance objectives for alternative plant arrangements while considering process constraints identified during IMHEX fuel cell development activities at ICT. The four major subsystems of a coal-based MCFC power plant are coal gasification, gas purification, fuel cell power generation and the bottoming cycle. The design and method of operation of each subsystem can be varied, and, depending upon design choices, can have major impact on both the design of other subsystems and the resulting cost of electricity. The challenge of this project was to select, from a range of design parameters, those operating conditions that result in a preferred plant design. Computer modelling was thus used to perform sensitivity analyses of as many system variables as program resources and schedules would permit. In any systems analysis, it is imperative that the evaluation methodology be verifiable and comparable. The TAG Class I develops comparable (if imprecise) data on performance and costs for the alternative cases being studied. It identifies, from a range of options, those which merit more exacting scrutiny to be undertaken at the second level, TAG class II analysis.

  14. Formation and retention of methane in coal

    SciTech Connect (OSTI)

    Hucka, V.J.; Bodily, D.M.; Huang, H.

    1992-05-15T23:59:59.000Z

    The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

  15. National Coal Quality Inventory (NACQI)

    SciTech Connect (OSTI)

    Robert Finkelman

    2005-09-30T23:59:59.000Z

    The U.S. Geological Survey (USGS) conducted the National Coal Quality Inventory (NaCQI) between 1999 and 2005 to address a need for quality information on coals that will be mined during the next 20-30 years. Collaboration between the USGS, State geological surveys, universities, coal burning utilities, and the coal mining industry plus funding support from the Electric Power Research Institute (EPRI) and the U.S. Department of Energy (DOE) permitted collection and submittal of coal samples for analysis. The chemical data (proximate and ultimate analyses; major, minor and trace element concentrations) for 729 samples of raw or prepared coal, coal associated shale, and coal combustion products (fly ash, hopper ash, bottom ash and gypsum) from nine coal producing States are included. In addition, the project identified a new coal reference analytical standard, to be designated CWE-1 (West Elk Mine, Gunnison County, Colorado) that is a high-volatile-B or high-volatile-A bituminous coal with low contents of ash yield and sulfur, and very low, but detectable contents of chlorine, mercury and other trace elements.

  16. Consensus Coal Production And Price Forecast For

    E-Print Network [OSTI]

    Mohaghegh, Shahab

    Consensus Coal Production And Price Forecast For West Virginia: 2011 Update Prepared for the West December 2011 © Copyright 2011 WVU Research Corporation #12;#12;W.Va. Consensus Coal Forecast Update 2011 i Table of Contents Executive Summary 1 Recent Developments 3 Consensus Coal Production And Price Forecast

  17. Process for low mercury coal

    DOE Patents [OSTI]

    Merriam, Norman W. (Laramie, WY); Grimes, R. William (Laramie, WY); Tweed, Robert E. (Laramie, WY)

    1995-01-01T23:59:59.000Z

    A process for producing low mercury coal during precombustion procedures by releasing mercury through discriminating mild heating that minimizes other burdensome constituents. Said mercury is recovered from the overhead gases by selective removal.

  18. Process for low mercury coal

    DOE Patents [OSTI]

    Merriam, N.W.; Grimes, R.W.; Tweed, R.E.

    1995-04-04T23:59:59.000Z

    A process is described for producing low mercury coal during precombustion procedures by releasing mercury through discriminating mild heating that minimizes other burdensome constituents. Said mercury is recovered from the overhead gases by selective removal. 4 figures.

  19. An Overview of Coal based

    E-Print Network [OSTI]

    An Overview of Coal based Integrated Gasification Combined Cycle (IGCC) Technology September 2005. LFEE 2005-002 WP #12;#12;Table of Contents 1 Integrated Gasification Combined Cycle (IGCC.......................................................................... 17 2.1 Gasification

  20. Tennessee Heat Content of Natural Gas Deliveries to Consumers (BTU per

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteamYear Jan FebThousand CubicinResidualU.S.contains contentDecade

  1. Tennessee Heat Content of Natural Gas Deliveries to Consumers (BTU per

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelines AboutDecemberSteamYear Jan FebThousand CubicinResidualU.S.contains contentDecadeCubic

  2. Coal pump

    DOE Patents [OSTI]

    Bonin, John H. (Sunnyvale, CA); Meyer, John W. (Palo Alto, CA); Daniel, Jr., Arnold D. (Alameda County, CA)

    1983-01-01T23:59:59.000Z

    A device for pressurizing pulverized coal and circulating a carrier gas is disclosed. This device has utility in a coal gasification process and eliminates the need for a separate collection hopper and eliminates the separate compressor.

  3. Coal surface control for advanced fine coal flotation

    SciTech Connect (OSTI)

    Fuerstenau, D.W.; Hanson, J.S.; Diao, J.; Harris, G.H.; De, A.; Sotillo, F. (California Univ., Berkeley, CA (United States)); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. (Columbia Univ., New York, NY (United States)); Hu, W.; Zou, Y.; Chen, W. (Utah Univ., Salt Lake City, UT (United States)); Choudhry, V.; Shea, S.; Ghosh, A.; Sehgal, R. (Praxis Engineers, Inc., Milpitas, CA (United States))

    1992-03-01T23:59:59.000Z

    The initial goal of the research project was to develop methods of coal surface control in advanced froth flotation to achieve 90% pyritic sulfur rejection, while operating at Btu recoveries above 90% based on run-of-mine quality coal. Moreover, the technology is to concomitantly reduce the ash content significantly (to six percent or less) to provide a high-quality fuel to the boiler (ash removal also increases Btu content, which in turn decreases a coal's emission potential in terms of lbs SO{sub 2}/million Btu). (VC)

  4. Preburn versus postburn mineralogical and geochemical characteristics of overburden and coal at the Hanna, Wyoming underground coal gasification site

    SciTech Connect (OSTI)

    Oliver, R.L.; Youngberg, A.D.

    1983-12-01T23:59:59.000Z

    Hundreds of mineralogic and geochemical tests were done under US Department of Energy contracts on core samples taken from the Hanna underground coal gasification site. These tests included x-ray diffraction studies of minerals in coal ash, overburden rocks, and heat-altered rocks; x-ray fluorescence analyses of oxides in coal ash and heat-altered rocks; semi-quantitative spectrographic analyses of elements in coal, overburden, and heat-altered rocks; chemical analyses of elements and compounds in coal, overburden, and heat-altered rocks and ASTM proximate and ultimate analyses of coal and heat-altered coal. These data sets were grouped, averaged, and analyzed to provide preburn and postburn mineralogic and geochemical characteristics of rock units at the site. Where possible, the changes in characteristics from the preburn to the postburn state are related to underground coal gasification processes. 11 references, 13 figures, 8 tables.

  5. Fluidized bed combustor and coal gun-tube assembly therefor

    DOE Patents [OSTI]

    Hosek, William S. (Mt. Tabor, NJ); Garruto, Edward J. (Wayne, NJ)

    1984-01-01T23:59:59.000Z

    A coal supply gun assembly for a fluidized bed combustor which includes heat exchange elements extending above the bed's distributor plate assembly and in which the gun's nozzles are disposed relative to the heat exchange elements to only discharge granular coal material between adjacent heat exchange elements and in a path which is substantially equidistant from adjacent heat exchange elements.

  6. Research on thermophoretic and inertial aspects of the ash particle deposition on heat exchanger surfaces in coal-fired equipment

    SciTech Connect (OSTI)

    Rosner, D.E.

    1986-12-01T23:59:59.000Z

    In support of the above mentioned objectives, we have initiated theoretical studies in the following three interrelated areas : (a) Interaction of inertial- and thermophoretic effects in well-defined laminar dusty-gas'' flows. (b) Self-regulated sticking and deposit erosion in the simultaneous presence of vapor or submicron glue'' (c) Use of packed bed and tube-bank heat transfer and friction correlations to provide the basis for future tube-bank fouling predictions.During the first three months of Grant DE-FG22-86 PC 90756, we have: (1) Designed and initiated construction of the microcombustor particle-laden jet facility described in Section 3.1. (2) Initiated theoretical studies of the interaction of inertial and thermophoretic effects, the role of simultaneous vapor arrival in determining particle sticking and erosion probabilities, and mass transport phenomena in deep tube banks.

  7. New developments in coal briquetting technology

    SciTech Connect (OSTI)

    Tucker, P.V. [Kilborn Inc., Ontario (Canada); Bosworth, G.B. [Kilborn Engineering Pacific Ltd., Vancouver, British Columbia (Canada); Kalb, G.W. [KKS Systems Inc., Wheeling, WV (United States)

    1993-12-31T23:59:59.000Z

    Briquetting of coal has been with us for well over a century. In the earliest applications of coal briquetting, less valuable fine coal was agglomerated into briquettes using a wide variety of binders, including coal tar, pitch and asphalt. Eventually, roll briquetters came into more widespread use, permitting the process to become a continuous one. Coal briquetting went out of favor during the 1950s in most of the industrialized world. The major reason for this decline in use was the discovery that the coal gas distillates used for binders were harmful to human health. Also, the abundance of cheap petroleum made coal briquettes a less attractive alternative as an industrial or domestic fuel. The re-emergence of coal as a primary industrial fuel and also its increased prominence as a fuel for thermal electric power stations led to a large increase in the annual volume of coal being mined worldwide. Coal preparation technology steadily improved over the years with the general exception of fine coal preparation. The processes available for treating this size range were considerably more expensive per unit mass of coal treated than coarse coal processes. Also, costly dewatering equipment was required after cleaning to remove surface moisture. Even with dewatering, the high surface area per unit mass of fine coal versus coarse coal resulted in high moisture contents. Therefore, little incentive existed to improve the performance of fine coal processes since this would only increase the amount of wet coal fines which would have to be dealt with. With such an ever-increasing volume of coal fines being created each year, there emerged an interest in recovering this valuable product. Several schemes were developed to recover coal fines discarded in abandoned tailings impoundments by previous operations.

  8. Research on thermophoretic and inertial aspects of ash particle deposition on heat exchanger surfaces in coal-fired equipment

    SciTech Connect (OSTI)

    Rosner, D.E.

    1987-03-01T23:59:59.000Z

    In support of the above mentioned objectives, we are carrying out theoretical studies in the following three interrelated areas: (a) Interaction of inertial- and thermophoretic effects in well-defined laminar dusty-gas'' flows; (b) Self-regulated sticking and deposit erosion in the simultaneous presence of vapor or submicron glue''; (c) Use of packed bed and tube-bank heat transfer and friction correlations to provide the basis for future tube-bank fouling predictions. During this second quarter of Grant DE-FG22-86 PC 90756. we have: (1) done preliminary gas velocity and temperature calibrations of the micro-combustor exit gas flow jet and initiated the development of both a monodispersed droplet feed system and powder feed system to provide monodispersed particle laden jets covering a broad spectrum of particle sizes (ca. 0.5--50 m diameter); and, (2) demonstrated the ability of impacting supermicron particles to remove predeposited submicron particles on a platinum target, using real-time optical reflectivity methods. These preliminary experiments will be extended and discussed in our next Quarterly Technical Report.

  9. Research on thermophoretic and inertial aspects of ash particle deposition on heat exchanger surfaces in coal-fired equipment

    SciTech Connect (OSTI)

    Rosner, D.E.

    1989-03-01T23:59:59.000Z

    Little is yet known (theoretically or experimentally) about the simultaneous effects of particle inertia, particle thermophoresis and high mass loading on the important engineering problem of predicting deposition rates from flowing dusty'' gases. For this reason, we investigate the motion of particles present at nonnegligible mass loading in a flowing nonisothermal gaseous medium and their deposition on strongly cooled or heated solid objects by examining the instructive case of steady axisymmetric dusty gas'' flow between two infinite disks: an inlet (porous) disk and the impermeable target'' disk -- a flow not unlike that encountered in recent seeded-flame experiments. Since this stagnation flow/geometry admits interesting self-similar solutions at all Reynolds numbers, we are able to predict laminar flow mass-, momentum- and energy-transfer rate coefficients over a wide range of particle mass loadings, dimensionless particle relaxation times (Stokes numbers), dimensionless thermophoretic diffusivities, and gas Reynolds numbers. As a by-product, we illustrate the accuracy and possible improvement of our previous diffusion model'' for tightly coupled dusty gas systems. Moreover, we report new results illustrating the dependence of the important critical'' Stokes number (for incipient particle impaction) on particle mass loading and wall/gas temperature ratio for dust-laden gas motion towards overheated'' solid surfaces. The present formulation and insulating transport coefficients should not only be useful in explaining/predicting recent deposition rate trends in seeded'' flame experiments, but also highly mass-loaded systems of technological interest.

  10. Research on thermophoretic and inertial aspects of ash particle deposition on heat exchanger surfaces in coal-fired equipment

    SciTech Connect (OSTI)

    Rosner, D.E.

    1988-03-01T23:59:59.000Z

    During the present reporting period, we have initiated work on (a) the interpretation of our recent data (see QTR5) on deposition rates under the simultaneous influence of inertia and thermophoresis, (b) the possible rate of particle photophoresis in environments characterized by high radiative heat loads. and (c) the influence of particle size distributions on total mass deposition rates. The fruits of these initiatives will be reported in subsequent quarterly technical reports. Here, we focus on our recent theoretical results in the important but previously uncharted area of the relations between particulate deposition mechanisms, deposit microstructure and deposit properties. Experimental verification of some of the most interesting predictions will be the subject of future HTCRE-Lab studies. Recent discussions with fouling engineers have convinced us that despite recent advances in our ability to predict particle deposition rates in convective-diffusion environments, the important connection between resulting deposit properties (effective thermal conductivity permeability, [hor ellipsis]) and deposition mechanism remain poorly understood and only scarcely studied. Accordingly, as part of this DOE-PETC program we have developed a discrete stochastic model to simulate particulate deposition processes resulting from a combination of deposition mechanisms.

  11. High-sulfur coals in the eastern Kentucky coal field

    SciTech Connect (OSTI)

    Hower, J.C.; Graham, U.M. (Univ. of Kentucky Center for Applied Energy Research, Lexington, KY (United States)); Eble, C.F. (Kentucky Geological Survey, Lexington, KY (United States))

    1993-08-01T23:59:59.000Z

    The Eastern Kentucky coal field is notable for relatively low-sulfur, [open quotes]compliance[close quotes] coals. Virtually all of the major coals in this area do have regions in which higher sulfur lithotypes are common, if not dominant, within the lithologic profile. Three Middle Pennsylvanian coals, each representing a major resource, exemplify this. The Clintwood coal bed is the stratigraphically lowest coal bed mined throughout the coal field. In Whitley County, the sulfur content increase from 0.6% at the base to nearly 12% in the top lithotype. Pyrite in the high-sulfur lithotype is a complex mixture of sub- to few-micron syngenetic forms and massive epigenetic growths. The stratigraphically higher Pond Creek coal bed is extensively mined in portions of the coal field. Although generally low in sulfur, in northern Pike and southern Martin counties the top one-third can have up to 6% sulfur. Uniformly low-sulfur profiles can occur within a few hundred meters of high-sulfur coal. Pyrite occurs as 10-50 [mu]m euhedra and coarser massive forms. In this case, sulfur distribution may have been controlled by sandstone channels in the overlying sediments. High-sulfur zones in the lower bench of the Fire Clay coal bed, the stratigraphically highest coal bed considered here, are more problematical. The lower bench, which is of highly variable thickness and quality, generally is overlain by a kaolinitic flint clay, the consequence of a volcanic ash fall into the peat swamp. In southern Perry and Letcher counties, a black, illite-chlorite clay directly overlies the lower bench. General lack of lateral continuity of lithotypes in the lower bench suggests that the precursor swamp consisted of discontinuous peat-forming environments that were spatially variable and regularly inundated by sediments. Some of the peat-forming areas may have been marshlike in character.

  12. Integrated coal cleaning, liquefaction, and gasification process

    DOE Patents [OSTI]

    Chervenak, Michael C. (Pennington, NJ)

    1980-01-01T23:59:59.000Z

    Coal is finely ground and cleaned so as to preferentially remove denser ash-containing particles along with some coal. The resulting cleaned coal portion having reduced ash content is then fed to a coal hydrogenation system for the production of desirable hydrocarbon gases and liquid products. The remaining ash-enriched coal portion is gasified to produce a synthesis gas, the ash is removed from the gasifier usually as slag, and the synthesis gas is shift converted with steam and purified to produce the high purity hydrogen needed in the coal hydrogenation system. This overall process increases the utilization of as-mined coal, reduces the problems associated with ash in the liquefaction-hydrogenation system, and permits a desirable simplification of a liquids-solids separation step otherwise required in the coal hydrogenation system.

  13. Formation and retention of methane in coal. Final report

    SciTech Connect (OSTI)

    Hucka, V.J.; Bodily, D.M.; Huang, H.

    1992-05-15T23:59:59.000Z

    The formation and retention of methane in coalbeds was studied for ten Utah coal samples, one Colorado coal sample and eight coal samples from the Argonne Premium Coal Sample Bank.Methane gas content of the Utah and Colorado coals varied from zero to 9 cm{sup 3}/g. The Utah coals were all high volatile bituminous coals. The Colorado coal was a gassy medium volatile bituminous coal. The Argonne coals cover a range or rank from lignite to low volatile bituminous coal and were used to determine the effect of rank in laboratory studies. The methane content of six selected Utah coal seams and the Colorado coal seam was measured in situ using a special sample collection device and a bubble desorbometer. Coal samples were collected at each measurement site for laboratory analysis. The cleat and joint system was evaluated for the coal and surrounding rocks and geological conditions were noted. Permeability measurements were performed on selected samples and all samples were analyzed for proximate and ultimate analysis, petrographic analysis, {sup 13}C NMR dipolar-dephasing spectroscopy, and density analysis. The observed methane adsorption behavior was correlated with the chemical structure and physical properties of the coals.

  14. Table of Contents Producing Hydrogen................1

    E-Print Network [OSTI]

    . It can store the energy from diverse domestic resources (including clean coal, nuclear renewable resources, nuclear energy, and coal with carbon capture and storage. 1 #12;Potential for clean1 #12;Table of Contents Producing Hydrogen................1 Hydrogen Production Technologies

  15. Coal extraction

    SciTech Connect (OSTI)

    Clarke, J.W.; Kimber, G.M.; Rantell, T.D.; Snape, C.E.

    1985-06-04T23:59:59.000Z

    Coal is extracted using a mixed solvent which includes a substantially aromatic component and a substantially naphthenic component, at a temperature of 400/sup 0/ to 500/sup 0/C. Although neither component is an especially good solvent for coal by itself, the use of mixed solvent gives greater flexibility to the process and offers efficiency gains.

  16. ENERGY UTILIZATION AND ENVIRONMENTAL CONTROL TECHNOLOGIES IN THE COAL-ELECTRIC CYCLE

    E-Print Network [OSTI]

    Ferrell, G.C.

    2010-01-01T23:59:59.000Z

    Kansas New Mexico Sulfur Content Feed Coal (%) Sulfurcoal from different sections of the Navajo mine in New Mexico (

  17. HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 Course contentCourse content

    E-Print Network [OSTI]

    Zevenhoven, Ron

    - firedPulverised coal- fired power plantpower plant #12;HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 Pulverised coal combustion and gas clean-upPulverised coal combustion and gas clean-up #12;HELSINKIHELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 ·· Course contentCourse content ·· Flue gases and fuel

  18. Compliance testing of Grissom Air Force Base Central Heating Plant coal-fired boilers 3, 4, and 5, Grissom Air Force Base, Indiana. Final technical report, 3-21 Feb 92

    SciTech Connect (OSTI)

    Cintron-Ocasio, R.A.

    1992-06-01T23:59:59.000Z

    A source emission testing for particulate matter and visible emissions was conducted on coal-fired boilers at the Grissom AFB Central Heating Plant during 3-21 February 1992 by the Air Quality Function of Armstrong Laboratory. The survey was conducted to determine compliance with regard to Indiana Administration Code, Title 325 Pollution Control Board, Article 5, Opacity Regulations, and Article 6, Particulate Regulations. All boilers were tested through the bypass stack. Results indicated that boilers 3 and 4 met applicable, visible, and particulate matter emissions standards. Boiler 5 exceeded the particulate standard.

  19. Method for producing catalysis from coal

    DOE Patents [OSTI]

    Farcasiu, Malvina (Pittsburgh, PA); Derbyshire, Frank (Lexington, KY); Kaufman, Phillip B. (Library, PA); Jagtoyen, Marit (Lexington, KY)

    1998-01-01T23:59:59.000Z

    A method for producing catalysts from coal is provided comprising mixing an aqueous alkali solution with the coal, heating the aqueous mixture to treat the coal, drying the now-heated aqueous mixture, reheating the mixture to form carbonized material, cooling the mixture, removing excess alkali from the carbonized material, and recovering the carbonized material, wherein the entire process is carried out in controlled atmospheres, and the carbonized material is a hydrocracking or hydrodehalogenation catalyst for liquid phase reactions. The invention also provides for a one-step method for producing catalysts from coal comprising mixing an aqueous alkali solution with the coal to create a mixture, heating the aqueous mixture from an ambient temperature to a predetermined temperature at a predetermined rate, cooling the mixture, and washing the mixture to remove excess alkali from the treated and carbonized material, wherein the entire process is carried out in a controlled atmosphere.

  20. Method for producing catalysts from coal

    DOE Patents [OSTI]

    Farcasiu, M.; Derbyshire, F.; Kaufman, P.B.; Jagtoyen, M.

    1998-02-24T23:59:59.000Z

    A method for producing catalysts from coal is provided comprising mixing an aqueous alkali solution with the coal, heating the aqueous mixture to treat the coal, drying the now-heated aqueous mixture, reheating the mixture to form carbonized material, cooling the mixture, removing excess alkali from the carbonized material, and recovering the carbonized material, wherein the entire process is carried out in controlled atmospheres, and the carbonized material is a hydrocracking or hydrodehalogenation catalyst for liquid phase reactions. The invention also provides for a one-step method for producing catalysts from coal comprising mixing an aqueous alkali solution with the coal to create a mixture, heating the aqueous mixture from an ambient temperature to a predetermined temperature at a predetermined rate, cooling the mixture, and washing the mixture to remove excess alkali from the treated and carbonized material, wherein the entire process is carried out in a controlled atmosphere. 1 fig.

  1. Heat Recovery from Coal Gasifiers

    E-Print Network [OSTI]

    Wen, H.; Lou, S. C.

    1981-01-01T23:59:59.000Z

    requirement of the gasification plant. The mechanical design for pressure vessel shell and boiler tubes is discussed. The design considers metallurgical requirements associated with hydrogen rich, high temperature, and high pressure atmosphere....

  2. Paradigm Shift: Burning Coal to Geothermal | Department of Energy

    Office of Environmental Management (EM)

    1120ballstatepresentation.pdf More Documents & Publications Indiana Recovery Act State Memo Coal Study Guide - Middle School BSU GHP District Heating and Cooling System (Phase I)...

  3. Cofiring waste biofuels and coal for emissions reduction

    SciTech Connect (OSTI)

    Brouwer, J.; Owens, W.D.; Harding, N.S. [Reaction Engineering International, Salt Lake City, UT (United States)] [and others

    1995-11-01T23:59:59.000Z

    Combustion tests have been performed in two pilot-scale combustion facilities to evaluate the emissions reduction possible while firing coal blended with several different biofuels. Two different boiler simulations, pulverized coal fired boilers and stoker coal fired boilers, were simulated. The pc-fired studies investigated the use of waste hardwood and softwood with pulverized coal, or using the biofuels as potential reburning fuels. The use of these wood waste is attractive because: wood contains little nitrogen and virtually no sulfur; wood is a regenerable biofuel; and wood utilization results in a net reduction in CO{sub 2} emissions. The wood reburning results indicate a reduction of 50-60% NO with approximately 10% wood heat input. Reburn stoichiometry was the most important variable. The NO reduction was strongly dependent upon initial NO and only slightly dependent upon temperature and wood moisture content. Cofiring of wood with pulverized coal; however, did not lead to significant NO reductions with the current NO{sub x} burner configuration. The stoker program investigated barriers for the successful blending of coal with waste railroad ties. Parameters evaluated included blending firing rate, chip size, optimum feed location, overfire/underfire air ratio, and natural gas addition. The results of this study demonstrate that NO emissions can be reduced by more than 50% without any significant increase in CO or THC emissions by the proper use of zoned reburning. Both programs demonstrated several benefits of biofuel cofiring, including: (1) lower operating costs due to reduced fuel prices; (2) reduced waste disposal; (3) reduced maintenance costs; (4) reduced environmental costs; and (5) extension of the useful life of existing equipment.

  4. Coal industry annual 1994

    SciTech Connect (OSTI)

    NONE

    1995-10-01T23:59:59.000Z

    This report presents data on coal consumption, distribution, coal stocks, quality, prices, coal production information, and emissions for a wide audience.

  5. Coal quality and estimated coal resources in the proposed Colville Mining District, central North Slope, Alaska

    SciTech Connect (OSTI)

    Stricker, G.D. [Geological Survey, Denver, CO (United States); Clough, J.G. [Alaska Department of Natural Resources, Fairbanks, AK (United States). Division of Geological and Geophysical Surveys

    1994-12-31T23:59:59.000Z

    The proposed Colville Mining District (CMD) encompasses 27,340 mi{sup 2} (70,800 km{sup 2}) in the central part of the North Slope. Known coal deposits within the proposed district range from Mississippian to Tertiary in age. Available information indicates that neither Mississippian and Tertiary coals in the CMD constitute a significant resource because they are excessively deep, thin, or high in ash content; however, considerable amount of low-sulfur Cretaceous coal is present. The paper briefly describes the geology and quality of these coal reserves. Difficult conditions will restrict mining of these coals in the near future.

  6. Research on thermophoretic and inertial aspects of ash particle deposition on heat exchanger surfaces in coal-fired equipment. Final technical report, September 1, 1986--April 30, 1990

    SciTech Connect (OSTI)

    Rosner, D.E.

    1990-05-01T23:59:59.000Z

    The overall goal of this research in the area of ash transport was to advance the capability of making reliable engineering predictions of the dynamics and consequences of net deposit growth for surfaces exposed to the products of coal combustion. To accomplish this for a wide variety of combustor types, coal types, and operating conditions, this capability must be based on a quantitative understanding of each of the important mechanisms of mineral matter transport, as well as the nature of the interactions between these substances and the prevailing ``fireside`` surface of the deposit. This level of understanding and predictive capability could ultimately be translated into very significant cost reductions for coal-fired equipment design, development and operation.

  7. Combined cycle power plant incorporating coal gasification

    DOE Patents [OSTI]

    Liljedahl, Gregory N. (Tariffville, CT); Moffat, Bruce K. (Simsbury, CT)

    1981-01-01T23:59:59.000Z

    A combined cycle power plant incorporating a coal gasifier as the energy source. The gases leaving the coal gasifier pass through a liquid couplant heat exchanger before being used to drive a gas turbine. The exhaust gases of the gas turbine are used to generate both high pressure and low pressure steam for driving a steam turbine, before being exhausted to the atmosphere.

  8. Rank enhancement of Permian Barakar and Raniganj coal measures in the western part of the Sohagpur coalfield, Madhya Pradesh, India

    SciTech Connect (OSTI)

    Warwick, P.D.; Milici, R.C.; Mukhopadyay, A.; Adhikari, S.

    1999-07-01T23:59:59.000Z

    The Geological Survey of India (GSI) and the U.S. Geological Survey (USGS) are engaged in a study of the coking coal deposits in the Sohagpur coalfield, near Shahdol, Madhya Pradesh. The major occurrences of coking coal in the Sohagpur coalfield are on the northern, down-thrown side of the regional Bamhani-Chilpa fault, where depths to the coking coal range generally from 100 to 500 m. These coal deposits are within the Permian Barakar Formation, which comprises the lower coal measures of the Gondwana Supergroup. Equivalent coal beds on the south side of the fault are generally non-coking, and are currently being mined in open-cast and underground mines, for use as fuel for electric power generation. In this paper, new data are presented which expands on data and ideas originally presented in Mukhopadyay and others. The purpose of this paper is to integrate thermal signatures (vitrinite reflectance and volatile matter) of the principal coal beds of the Sohagpur coalfield with stratigraphic and structural data. In order to characterize the coking coal deposits, the authors have collected more than 100 coal samples from both the Barakar and Raniganj Formations for analyses. The occurrence of coking coal in the Sohagpur coalfield is related primarily to the thermal alteration of the coal beds in the different geologic settings within the coalfield. In addition, differences in the maceral content of the various coal beds and in the chemical and physical composition within each bed depending upon location, play an important role in determining the existence of coking properties for a particular coal deposit. Potential heat sources for thermal alteration include the abundant dolerite intrusives in the region, and greater depth of burial of the coking coal beds on the down-thrown side of the Bamhani-Chilpa fault. Offset along the Bamhani-Chilpa system has been suggested to greater than 400 m. Hot water, similar to that found in other Permian coalfields in India, may have been the agent that metamorphosed the coal in some places but not in others.

  9. Coal surface control for advanced fine coal flotation. Final report, October 1, 1988--March 31, 1992

    SciTech Connect (OSTI)

    Fuerstenau, D.W.; Hanson, J.S.; Diao, J.; Harris, G.H.; De, A.; Sotillo, F. [California Univ., Berkeley, CA (United States); Somasundaran, P.; Harris, C.C.; Vasudevan, T.; Liu, D.; Li, C. [Columbia Univ., New York, NY (United States); Hu, W.; Zou, Y.; Chen, W. [Utah Univ., Salt Lake City, UT (United States); Choudhry, V.; Shea, S.; Ghosh, A.; Sehgal, R. [Praxis Engineers, Inc., Milpitas, CA (United States)

    1992-03-01T23:59:59.000Z

    The initial goal of the research project was to develop methods of coal surface control in advanced froth flotation to achieve 90% pyritic sulfur rejection, while operating at Btu recoveries above 90% based on run-of-mine quality coal. Moreover, the technology is to concomitantly reduce the ash content significantly (to six percent or less) to provide a high-quality fuel to the boiler (ash removal also increases Btu content, which in turn decreases a coal`s emission potential in terms of lbs SO{sub 2}/million Btu). (VC)

  10. Neutron based elemental characterization of coal

    SciTech Connect (OSTI)

    Dep, L.; Vourvopoulos, G. [Western Kentucky Univ., Bowling Green, KY (United States)

    1996-12-31T23:59:59.000Z

    An elemental characterization system based on a 14 MeV neutron generator is described. The results of sulfur content measurement in coal with a precision acceptable to the coal industry are presented. The preliminary results of measuring carbon, oxygen, and sodium are shown.

  11. Optimum Design of Coal Gasification Plants

    E-Print Network [OSTI]

    Pohani, B. P.; Ray, H. P.; Wen, H.

    1982-01-01T23:59:59.000Z

    This paper deals with the optimum design of heat recovery systems using the Texaco Coal Gasification Process (TCGP). TCGP uses an entrained type gasifier and produces hot gases at approximately 2500oF with high heat flux. This heat is removed...

  12. Process for removing pyritic sulfur from bituminous coals

    DOE Patents [OSTI]

    Pawlak, Wanda (Edmonton, CA); Janiak, Jerzy S. (Edmonton, CA); Turak, Ali A. (Edmonton, CA); Ignasiak, Boleslaw L. (Edmonton, CA)

    1990-01-01T23:59:59.000Z

    A process is provided for removing pyritic sulfur and lowering ash content of bituminous coals by grinding the feed coal, subjecting it to micro-agglomeration with a bridging liquid containing heavy oil, separating the microagglomerates and separating them to a water wash to remove suspended pyritic sulfur. In one embodiment the coal is subjected to a second micro-agglomeration step.

  13. Assessment of coal bed gas prospects

    SciTech Connect (OSTI)

    Moore, T.R. [Phillips Petroleum Co., Bartlesville, OK (United States)

    1996-12-31T23:59:59.000Z

    Coal bed gas is an often overlooked source of clean, methane-rich, H{sub 2}S-free natural gas. The economic development of coal bed gas requires a knowledge of coal gas reservoir characteristics and certain necessary departures from conventional evaluation, drilling, completion, and production practices. In many ways coal seam reservoirs are truly unconventional. Most coals sufficient rank have generated large volumes of gas that may be retained depth in varying amounts through adsorption. Coal gas production can take place only when the reservoir pressure is reduced sufficiently to allow the gas to desorb. Gas flow to the well bore takes place through a hierarchy of natural fractures, not the relatively impermeable coal matrix. Economic production is dependent upon critical factors intrinsic to the reservoir, including coal petrology, gas content, internal formation stratigraphy, fracture distribution, hydrogeology, in situ stress conditions, initial reservoir pressure and pressure regime, and the presence or absence of a {open_quote}free{close_quotes} gas saturation. Further, the coal bed reservoir is readily subject to formation damage through improper drilling, completion, or production techniques. This presentation will review the data types critical to the assessment of any coal seam gas prospect, suggest an outline method for screening such prospects, and point out some possible pitfalls to be considered in any coal bed gas development project.

  14. Kinetics of coal pyrolysis and devolatilization

    SciTech Connect (OSTI)

    Not Available

    1987-01-01T23:59:59.000Z

    An experimentally based, conceptual model of the devolatilization of a HV bituminous coal is outlined in this report. This model contends that the relative dominance of a process type-chemical kinetic, heat transport, mass transport -- varies with the extent of reaction for a given set of heating conditions and coal type and with experimental conditions for a given coal type and extent of reaction. The rate of devolatilization mass loss process is dominated initially by heat transfer processes, then coupled mass transfer and chemical kinetics, and finally by chemical processes alone. However, the chemical composition of the initial tars are determined primarily by the chemical characteristics of the parent coal. Chemically controlled gas phase reactions of the initial tars and coupled mass transfer and chemically controlled reactions of heavy tars determine the bulk of the light gas yields. For a HV bituminous coal this conceptual model serves to quantify the Two-Component Hypothesis'' of volatiles evolution. The model postulates that the overall rates of coal devolatilization should vary with coal type insofar as the characteristics of the parent coal determine the potential tar yield and the chemical characteristics of the initial tars. Experimental evidence indicates chemical characteristics and yields of primary'' tars vary significantly with coal type. Consequently, the conceptual model would indicate a shift from transport to chemical dominance of rate processes with variation in coal type. Using the conceptual model, United Technologies Research Center has been able to correlate initial mass loss with a heat transfer index for a wide range of conditions for high tar yielding coals. 33 refs., 30 figs., 6 tabs.

  15. Zero emission coal

    SciTech Connect (OSTI)

    Ziock, H.; Lackner, K.

    2000-08-01T23:59:59.000Z

    We discuss a novel, emission-free process for producing hydrogen or electricity from coal. Even though we focus on coal, the basic design is compatible with any carbonaceous fuel. The process uses cyclical carbonation of calcium oxide to promote the production of hydrogen from carbon and water. The carbonation of the calcium oxide removes carbon dioxide from the reaction products and provides the additional energy necessary to complete hydrogen production without additional combustion of carbon. The calcination of the resulting calcium carbonate is accomplished using the high temperature waste heat from solid oxide fuel cells (SOFC), which generate electricity from hydrogen fuel. Converting waste heat back to useful chemical energy allows the process to achieve very high conversion efficiency from fuel energy to electrical energy. As the process is essentially closed-loop, the process is able to achieve zero emissions if the concentrated exhaust stream of CO{sub 2} is sequestered. Carbon dioxide disposal is accomplished by the production of magnesium carbonate from ultramafic rock. The end products of the sequestration process are stable naturally occurring minerals. Sufficient rich ultramafic deposits exist to easily handle all the world's coal.

  16. Inclined fluidized bed system for drying fine coal

    DOE Patents [OSTI]

    Cha, Chang Y. (Golden, CO); Merriam, Norman W. (Laramie, WY); Boysen, John E. (Laramie, WY)

    1992-02-11T23:59:59.000Z

    Coal is processed in an inclined fluidized bed dryer operated in a plug-flow manner with zonal temperature and composition control, and an inert fluidizing gas, such as carbon dioxide or combustion gas. Recycled carbon dioxide, which is used for drying, pyrolysis, quenching, and cooling, is produced by partial decarboxylation of the coal. The coal is heated sufficiently to mobilize coal tar by further pyrolysis, which seals micropores upon quenching. Further cooling with carbon dioxide enhances stabilization.

  17. Underground Coal Thermal Treatment

    SciTech Connect (OSTI)

    P. Smith; M. Deo; E. Eddings; A. Sarofim; K. Gueishen; M. Hradisky; K. Kelly; P. Mandalaparty; H. Zhang

    2011-10-30T23:59:59.000Z

    The long-term objective of this work is to develop a transformational energy production technology by insitu thermal treatment of a coal seam for the production of substitute natural gas (SNG) while leaving much of the coalâ??s carbon in the ground. This process converts coal to a high-efficiency, low-GHG emitting gas fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This topical report discusses the development of experimental capabilities, the collection of available data, and the development of simulation tools to obtain process thermo-chemical and geo-thermal parameters in preparation for the eventual demonstration in a coal seam. It also includes experimental and modeling studies of CO{sub 2} sequestration. Efforts focused on: â?¢ Constructing a suite of three different coal pyrolysis reactors. These reactors offer the ability to gather heat transfer, mass transfer and kinetic data during coal pyrolysis under conditions that mimic in situ conditions (Subtask 6.1). â?¢ Studying the operational parameters for various underground thermal treatment processes for oil shale and coal and completing a design matrix analysis for the underground coal thermal treatment (UCTT). This analysis yielded recommendations for terms of targeted coal rank, well orientation, rubblization, presence of oxygen, temperature, pressure, and heating sources (Subtask 6.2). â?¢ Developing capabilities for simulating UCTT, including modifying the geometry as well as the solution algorithm to achieve long simulation times in a rubblized coal bed by resolving the convective channels occurring in the representative domain (Subtask 6.3). â?¢ Studying the reactive behavior of carbon dioxide (CO{sub 2}) with limestone, sandstone, arkose (a more complex sandstone) and peridotite, including mineralogical changes and brine chemistry for the different initial rock compositions (Subtask 6.4). Arkose exhibited the highest tendency of participating in mineral reactions, which can be attributed to the geochemical complexity of its initial mineral assemblage. In experiments with limestone, continuous dissolution was observed with the release of CO{sub 2} gas, indicated by the increasing pressure in the reactor (formation of a gas chamber). This occurred due to the lack of any source of alkali to buffer the solution. Arkose has the geochemical complexity for permanent sequestration of CO{sub 2} as carbonates and is also relatively abundant. The effect of including NH{sub 3} in the injected gas stream was also investigated in this study. Precipitation of calcite and trace amounts of ammonium zeolites was observed. A batch geochemical model was developed using Geochemists Workbench (GWB). Degassing effect in the experiments was corrected using the sliding fugacity model in GWB. Experimental and simulation results were compared and a reasonable agreement between the two was observed.

  18. A study of the interfacial chemistry of pyrite and coal in fine coal cleaning using flotation

    SciTech Connect (OSTI)

    Jiang, C.

    1993-12-31T23:59:59.000Z

    Surface oxidation, surface charge, and flotation properties have been systematically studied for coal, coal-pyrite and ore-pyrite. Electrochemical studies show that coal-pyrite exhibits much higher and more complex surface oxidation than ore-pyrite and its oxidation rate depends strongly on the carbon/coal content. Flotation studies indicate that pyrites have no self-induced floatability. Fuel oil significantly improves the floatability of coal and induces considerable flotation for coal-pyrite due to the hydrophobic interaction of fuel oil with the carbon/coal inclusions on the pyrite surface. Xanthate is a good collector for ore-pyrite but a poor collector for coal and coal-pyrite. The results from thermodynamic calculations, flotation and zeta potential measurements show that iron ions greatly affect the flotation of pyrite with xanthate and fuel oil. Various organic and inorganic chemicals have been examined for depressing coal-pyrite. It was found, for the first time, that sodium pyrophosphate is an effective depressant for coal-pyrite. Solution chemistry shows that pyrophosphate reacts with iron ions to form stable iron pyrophosphate complexes. Using pyrophosphate, the complete separation of pyrite from coal can be realized over a wide pH range at relatively low dosage.

  19. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul Aug SepAnnual",2013Annual",2014 ,"ReleaseAnnual",2014Bcf)"ImportsDeliveries toHeat ContentHeatHeatHeat

  20. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul Aug SepAnnual",2013Annual",2014 ,"ReleaseAnnual",2014Bcf)"ImportsDeliveries toHeatHeat ContentHeatHeat

  1. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul Aug SepAnnual",2013Annual",2014 ,"ReleaseAnnual",2014Bcf)"ImportsDeliveries toHeatHeatHeat ContentHeat

  2. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul Aug SepAnnual",2013Annual",2014 ,"ReleaseAnnual",2014Bcf)"ImportsDeliveries toHeatHeatHeatHeat Content

  3. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul Aug SepAnnual",2013Annual",2014 ,"ReleaseAnnual",2014Bcf)"ImportsDeliveriesHeat Content ofHeatHeatHeat

  4. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul Aug SepAnnual",2013Annual",2014 ,"ReleaseAnnual",2014Bcf)"ImportsDeliveriesHeat ContentHeatHeatHeat

  5. Multisolvent successive extractive refining of coal

    SciTech Connect (OSTI)

    Sharma, D.K.; Singh, S.K. [Indian Inst. of Tech., New Delhi (India)

    1996-01-01T23:59:59.000Z

    A selected group of commercial solvents, namely, anthracene oil (AO), ethylenediamine (EDA), and liquid paraffin (LP), were used for successive extraction of Assam coal. Hot AO provided a wide range of mixed solvents that dissociate chemically and interact favorably with dissociated and undissociated coal macromolecules (like dissolves like). This resulted in the enhancement of the EDA extractability of the AO-pretreated residual coal. EDA is a good swelling solvent and results in physical dissociation of coal molecules. The residual coal obtained after EDA extraction was subjected to extraction with LP, an H-donor, high-boiling (330--360 C) solvent. LP thermally dissociates coal macromolecules and interacts with the coal at its plastic stage at the free radical pockets. The mechanism and molecular dynamics of the multisolvent successive extraction of Assam coal using AO-EDA-LP solvents are discussed. In early attempts, successive extractions did not modify the extraction yield in the single solvent showing the maximum extraction. However, the AO-EDA-LP extraction resulted in the extraction of 70% coal, more than for any of the individual solvents used. Therefore, AO-EDA-LP extraction of coal affords a process yielding a superclean, high-heating value fuel from coal under milder conditions. Several uses of superclean coal have been recommended. Present studies have revealed a new concept concerning the structure of coal having 30% polyaromatic condensed entangled rings and 70% triaromatic-heterocyclic-naphthenic-aliphatic structure. The insolubility of coal is due to the polyfunctional-heterocyclic-condensed structure having a polyaromatic core with intermacromolecular entanglements.

  6. Structural group composition and thermodynamic properties of petroleum and coal tar fractions

    SciTech Connect (OSTI)

    Guilyazetdinov, L.P. [Gubkin State Academy of Oil and Gas, Moscow (Russian Federation). Dept. of Technology of Petroleum and Gas Processing

    1995-04-01T23:59:59.000Z

    The improved G-L method was developed for determining the structural group composition of petroleum and coal tar fractions by using experimental values of refraction index, density, molecular weight, and S, N, O, and olefinic group content. The method is useful for fractions boiling in the range 30--500 C containing S, N, O and in total up to 10%, not limiting the distribution of the carbon atoms between aromatic, naphthenic, and paraffinic structures. Several correlations are proposed for prediction of the thermodynamic properties of petroleum and coal tar fractions, i.e., molar volume; surface tension; heat capacity in gas, liquid, and solid phases as a function of temperature; and also critical properties standard heat and entropy of formation, and temperature and entropy of melting. The method and these correlations have been tested on hydrocarbons and other organic compounds with satisfactory accuracy.

  7. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    Pollutants Associated With Coal Combustion. • E.P.A.Control Guidelines for Coal-Derived Pollutants .Forms of Sulfur in Coal • . . . . Coal Desulfurization

  8. Development of a coal-fired combustion system for industrial process heating applications. Phase 3 final report, November 1992--December 1994

    SciTech Connect (OSTI)

    NONE

    1995-09-26T23:59:59.000Z

    A three phase research and development program has resulted in the development and commercialization of a Cyclone Melting System (CMS{trademark}), capable of being fueled by pulverized coal, natural gas, and other solid, gaseous, or liquid fuels, for the vitrification of industrial wastes. The Phase 3 research effort focused on the development of a process heater system to be used for producing value added glass products from the vitrification of boiler/incinerator ashes and industrial wastes. The primary objective of the Phase 3 project was to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential for successful commercialization. The demonstration test consisted of one test run with a duration of 105 hours, approximately one-half (46 hours) performed with coal as the primary fuel source (70% to 100%), the other half with natural gas. Approximately 50 hours of melting operation were performed vitrifying approximately 50,000 lbs of coal-fired utility boiler flyash/dolomite mixture, producing a fully-reacted vitrified product.

  9. CO-FIRING COAL: FEEDLOT AND LITTER BIOMASS (CFB AND CLB) FUELS IN PULVERIZED FUEL AND FIXED BED BURNERS

    SciTech Connect (OSTI)

    Kalyan Annamalai; John Sweeten; Saqib Mukhtar; Ben Thein; Gengsheng Wei; Soyuz Priyadarsan; Senthil Arumugam; Kevin Heflin

    2003-08-28T23:59:59.000Z

    Intensive animal feeding operations create large amounts of animal waste that must be safely disposed of in order to avoid environmental degradation. Cattle feedlots and chicken houses are two examples. In feedlots, cattle are confined to small pens and fed a high calorie grain-diet diet in preparation for slaughter. In chicken houses, thousands of chickens are kept in close proximity. In both of these operations, millions of tons of manure are produced every year. The manure could be used as a fuel by mixing it with coal in a 90:10 blend and firing it in an existing coal suspension fired combustion systems. This technique is known as co-firing, and the high temperatures produced by the coal will allow the biomass to be completely combusted. Reburn is a process where a small percentage of fuel called reburn fuel is injected above the NO{sub x} producing, conventional coal fired burners in order to reduce NO{sub x}. The manure could also be used as reburn fuel for reducing NO{sub x} in coal fired plants. An alternate approach of using animal waste is to adopt the gasification process using a fixed bed gasifier and then use the gases for firing in gas turbine combustors. In this report, the cattle manure is referred to as feedlot biomass (FB) and chicken manure as litter biomass (LB). The report generates data on FB and LB fuel characteristics. Co-firing, reburn, and gasification tests of coal, FB, LB, coal: FB blends, and coal: LB blends and modeling on cofiring, reburn systems and economics of use of FB and LB have also been conducted. The biomass fuels are higher in ash, lower in heat content, higher in moisture, and higher in nitrogen and sulfur (which can cause air pollution) compared to coal. Small-scale cofiring experiments revealed that the biomass blends can be successfully fired, and NO{sub x} emissions will be similar to or lower than pollutant emissions when firing coal. Further experiments showed that biomass is twice or more effective than coal when used in a reburning process. Computer simulations for coal: LB blends were performed by modifying an existing computer code to include the drying and phosphorus (P) oxidation models. The gasification studies revealed that there is bed agglomeration in the case of chicken litter biomass due to its higher alkaline oxide content in the ash. Finally, the results of the economic analysis show that considerable fuel cost savings can be achieved with the use of biomass. In the case of higher ash and moisture biomass, the fuel cost savings is reduced.

  10. Coal quality trends and distribution of Title III trace elements in Eastern Kentucky coals

    SciTech Connect (OSTI)

    Eble, C.F. [Kentucky Geological Survey, Lexington, KY (United States); Hower, J.C. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

    1995-12-31T23:59:59.000Z

    The quality characteristics of eastern Kentucky coal beds vary both spatially and stratigraphically. Average total sulfur contents are lowest, and calorific values highest, in the Big Sandy and Upper Cumberland Reserve Districts. Average coal thickness is greatest in these two districts as well. Conversely, the thinnest coal with the highest total sulfur content, and lowest calorific value, on average, occurs in the Princess and Southwest Reserve Districts. Several Title III trace elements, notably arsenic, cadmium, lead, mercury, and nickel, mirror this distribution (lower average concentrations in the Big Sandy and Upper Cumberland Districts, higher average concentrations in the Princess and Southwest Districts), probably because these elements are primarily associated with sulfide minerals in coal. Ash yields and total sulfur contents are observed to increase in a stratigraphically older to younger direction. Several Title III elements, notably cadmium, chromium, lead, and selenium follow this trend, with average concentrations being higher in younger coals. Average chlorine concentration shows a reciprocal distribution, being more abundant in older coals. Some elements, such as arsenic, manganese, mercury, cobalt, and, to a lesser extent, phosphorus show concentration spikes in coal beds directly above, or below, major marine zones. With a few exceptions, average Title III trace element concentrations for eastern Kentucky coals are comparable with element distributions in other Appalachian coal-producing states.

  11. RESEARCH & DEVELOPMENT TO PREPARE AND CHARACTERIZE ROBUST COAL/BIOMASS MIXTURES FOR DIRECT CO-FEEDING INTO GASIFICATION SYSTEMS

    SciTech Connect (OSTI)

    Felix, Larry; Farthing, William; Hoekman, S. Kent

    2014-12-31T23:59:59.000Z

    This project was initiated on October 1, 2010 and utilizes equipment and research supported by the Department of Energy, National Energy Technology Laboratory, under Award Number DE- FE0005349. It is also based upon previous work supported by the Department of Energy, National Energy Technology Laboratory, under Award Numbers DOE-DE-FG36-01GOl1082, DE-FG36-02G012011 or DE-EE0000272. The overall goal of the work performed was to demonstrate and assess the economic viability of fast hydrothermal carbonization (HTC) for transforming lignocellulosic biomass into a densified, friable fuel to gasify like coal that can be easily blended with ground coal and coal fines and then be formed into robust, weather-resistant pellets and briquettes. The specific objectives of the project include: • Demonstration of the continuous production of a uniform densified and formed feedstock from loblolly pine (a lignocellulosic, short rotation woody crop) in a hydrothermal carbonization (HTC) process development unit (PDU). • Demonstration that finely divided bituminous coal and HTC loblolly pine can be blended to form 90/10 and 70/30 weight-percent mixtures of coal and HTC biomass for further processing by pelletization and briquetting equipment to form robust weather resistant pellets and/or briquettes suitable for transportation and long term storage. • Characterization of the coal-biomass pellets and briquettes to quantify their physical properties (e.g. flow properties, homogeneity, moisture content, particle size and shape), bulk physical properties (e.g. compressibility, heat transfer and friability) and assess their suitability for use as fuels for commercially-available coal gasifiers. • Perform economic analyses using Aspen-based process simulations to determine the costs for deploying and operating HTC processing facilities for the production of robust coal/biomass fuels suitable for fueling commercially-available coal-fired gasifiers. This Final Project Scientific/Technical Report discusses and documents the project work required to meet each of these objectives.

  12. Photothermal method of determining calorific properties of coal

    DOE Patents [OSTI]

    Amer, Nabil M. (Berkeley, CA)

    1985-01-01T23:59:59.000Z

    Predetermined amounts of heat are generated within a coal sample (11) by directing pump light pulses (14) of predetermined energy content into a small surface region (16) of the sample (11). A beam (18) of probe light is directed along the sample surface (19) and deflection of the probe beam (18) from thermally induced changes of index of refraction in the fluid medium adjacent the heated region (16) are detected. Deflection amplitude and the phase lag of the deflection, relative to the initiating pump light pulse (14), are indicative of the calorific value and the porosity of the sample (11). The method provides rapid, accurate and non-destructive analysis of the heat producing capabilities of coal samples (11). In the preferred form, sequences of pump light pulses (14) of increasing durations are directed into the sample (11) at each of a series of minute regions (16) situated along a raster scan path (21) enabling detailed analysis of variations of thermal properties at different areas of the sample (11) and at different depths.

  13. Catalytic steam gasification reactivity of HyperCoals produced from different rank of coals at 600-775{degree}C

    SciTech Connect (OSTI)

    Atul Sharma; Ikuo Saito; Toshimasa Takanohashi [National Institute of Advanced Industrial Science and Technology, Ibaraki (Japan). Advanced Fuel Group, Energy Technology Research Institute

    2008-11-15T23:59:59.000Z

    HyperCoal is a clean coal with ash content <0.05 wt %. HyperCoals were prepared from a brown coal, a sub-bituminous coal, and a bituminous raw coal by solvent extraction method. Catalytic steam gasification of these HyperCoals was carried out with K{sub 2}CO{sub 3} at 775, 700, 650, and 600 {degree}C, and their rates were compared. HyperCoals produced from low-rank coals were more reactive than those produced from the high-rank coals. XRD measurements were carried out to understand the difference in gasification reactivity of HyperCoals. Arrhenius plot of ln (k) vs 1/T in the temperature range 600-825{degree}C was a curve rather than a straight line. The point of change was observed at 700{degree}C for HyperCoals from low-rank coals and at 775{degree}C for HyperCoals from high-rank coals. Using HyperCoal produced from low-rank coals as feedstock, steam gasification of coal may be possible at temperatures less than 650{degree}C. 22 refs., 6 figs., 2 tabs.

  14. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

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  15. Workbook Contents

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  16. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

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  17. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

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  18. Petrographic characterization of Kentucky coals. Final report. Part VI. The nature of pseudovitrinites in Kentucky coals

    SciTech Connect (OSTI)

    Trinkle, E.J.; Hower, J.C.

    1984-02-01T23:59:59.000Z

    Overall average pseudovitrinite content for 1055 eastern Kentucky coal samples is nearly 9% while average percentage of pseudovitrinite for 551 western Kentucky coals is approximately 4%. Examination of variation in pseudovitrinite content relative to rank changes shows uniformity in pseudovitrinite percentages within the 4 to 7 V-type interval for eastern Kentucky coals but a gradual increase in pseudovitrinite content for western Kentucky coals over the same rank interval. Coals from both coal fields show similar, distinct increases in pseudovitrinite percentage in the highest V-type categories. However, it is suggested here that these supposed increases in pseudovitrinite percentages are not real but rather, indicate distinct increase in the brightness of nitrinite resulting from increased alteration of vitrinite beginning at this stage of coalification and continuing into the higher rank stages. This conclusion is reached when it is found that differences between pseudovitrinite and vitrinite reflectance are least in coals at these high rank intervals of Kentucky and, also, when vitrinite particles are often visually observed having brightness equal to that of pseudovitrinite particles. Relation of pseudovitrinite to other sulfur forms and total sulfur in general shows no significant trends, although the relatively high pyritic sulfur content in western Kentucky coals, coupled with relatively low inert percentages suggest the existence of predominantly reducing, or at least non-oxidizing conditions in the Pennsylvanian peat swamps of western Kentucky. Initial work involving Vicker's microhardness testing of coals indicates that microhardness values for pseudovitrinite are higher than those for vitrinite within the same sample regardless of coal rank or coal field from which the sample was collected. 15 references, 9 figures, 9 tables.

  19. Coal industry annual 1997

    SciTech Connect (OSTI)

    NONE

    1998-12-01T23:59:59.000Z

    Coal Industry Annual 1997 provides comprehensive information about US coal production, number of mines, prices, productivity, employment, productive capacity, and recoverable reserves. US Coal production for 1997 and previous years is based on the annual survey EIA-7A, Coal Production Report. This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report includes a national total coal consumption for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. 14 figs., 145 tabs.

  20. Development of a coal-fired combustion system for industrial process heating applications. Quarterly technical progress report, January 1993--March 1993

    SciTech Connect (OSTI)

    Not Available

    1993-04-30T23:59:59.000Z

    This advanced combustion system research program is for the development of innovative coal-fired process heaters which can be used for high temperature melting, smelting and waste vitrification processes. The process heater concepts to be developed are based on advanced glass melting and ore smelting furnaces developed and patented by Vortec Corporation. The process heater systems to be developed have multiple use applications; however, the Phase III research effort is being focused on the development of a process heater system to be used for producing value added vitrified glass products from boiler/incinerator ashes and industrial wastes. The primary objective of the Phase III project is to develop and integrate all the system components, from fuel through total system controls, and then test the complete system in order to evaluate its potential marketability. During the current reporting period, a majority of the effort was spent performing the initial industrial proof-of-concept test and installing and integrating the Wet Electrostatic Precipitator (WESP). The other system modifications are well underway with the designs of the modifications to the batch/coal feed system being completed. A Purchase Order has been issued to a material conveying equipment vendor for the purchase of the batch/coal feeding equipment. The delivery and installation of the material conveying equipment is expected to occur in July and early August. The commercialization planning is continuing with the completion of a draft Business Plan. This plan is currently undergoing internal review, and will be submitted to Dawnbreaker, a DOE contracted small business consulting firm, for review.

  1. Coal Industry Annual 1995

    SciTech Connect (OSTI)

    NONE

    1996-10-01T23:59:59.000Z

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 21 million short tons for 1995.

  2. Coal industry annual 1996

    SciTech Connect (OSTI)

    NONE

    1997-11-01T23:59:59.000Z

    This report presents data on coal consumption, coal distribution, coal stocks, coal prices, and coal quality, and emissions for Congress, Federal and State agencies, the coal industry, and the general public. Appendix A contains a compilation of coal statistics for the major coal-producing States.This report does not include coal consumption data for nonutility power producers that are not in the manufacturing, agriculture, mining, construction, or commercial sectors. Consumption for nonutility power producers not included in this report is estimated to be 24 million short tons for 1996. 14 figs., 145 tabs.

  3. Research on thermophoretic and inertial aspects of ash particle deposition on heat exchanger surfaces in coal-fired equipment: Quarterly technical report, September 1, 1987-November 30, 1987

    SciTech Connect (OSTI)

    Rosner, D.E.

    1987-12-01T23:59:59.000Z

    DOE-PETC has initiated at the Yale HTCRE Laboratory a systematic three-year experimental and theoretical research program directed toward providing engineers with the data, methods, and rational correlations needed to dramatically improve the generality and accuracy of prediction of inorganic particle deposition rates under typical coal combustion conditions (i.e., those leading to the importance of thermophoretically-enhanced diffusion (submicron mode) and the inertially-enhanced ''impaction'' (supermicron mode)), often in the presence of simultaneous alkali salt vapor condensation. 9 refs., 1 fig.

  4. Waste Coal Fines Reburn for NOx and Mercury Emission Reduction

    SciTech Connect (OSTI)

    Stephen Johnson; Chetan Chothani; Bernard Breen

    2008-04-30T23:59:59.000Z

    Injection of coal-water slurries (CWS) made with both waste coal and bituminous coal was tested for enhanced reduction of NO{sub x} and Hg emissions at the AES Beaver Valley plant near Monaca, PA. Under this project, Breen Energy Solutions (BES) conducted field experiments on the these emission reduction technologies by mixing coal fines and/or pulverized coal, urea and water to form slurry, then injecting the slurry in the upper furnace region of a coal-fired boiler. The main focus of this project was use of waste coal fines as the carbon source; however, testing was also conducted using pulverized coal in conjunction with or instead of waste coal fines for conversion efficiency and economic comparisons. The host site for this research and development project was Unit No.2 at AES Beaver Valley cogeneration station. Unit No.2 is a 35 MW Babcock & Wilcox (B&W) front-wall fired boiler that burns eastern bituminous coal. It has low NO{sub x} burners, overfire air ports and a urea-based selective non-catalytic reduction (SNCR) system for NO{sub x} control. The back-end clean-up system includes a rotating mechanical ash particulate removal and electrostatic precipitator (ESP) and wet flue gas desulfurization (FGD) scrubber. Coal slurry injection was expected to help reduce NOx emissions in two ways: (1) Via fuel-lean reburning when the slurry is injected above the combustion zone. (2) Via enhanced SNCR reduction when urea is incorporated into the slurry. The mercury control process under research uses carbon/water slurry injection to produce reactive carbon in-situ in the upper furnace, promoting the oxidation of elemental mercury in flue gas from coal-fired power boilers. By controlling the water content of the slurry below the stoichiometric requirement for complete gasification, water activated carbon (WAC) can be generated in-situ in the upper furnace. As little as 1-2% coal/water slurry (heat input basis) can be injected and generate sufficient WAC for mercury capture. During July, August, and September 2007, BES designed, procured, installed, and tested the slurry injection system at Beaver Valley. Slurry production was performed by Penn State University using equipment that was moved from campus to the Beaver Valley site. Waste coal fines were procured from Headwaters Inc. and transported to the site in Super Sacks. In addition, bituminous coal was pulverized at Penn State and trucked to the site in 55-gallon drums. This system was operated for three weeks during August and September 2007. NO{sub x} emission data were obtained using the plant CEM system. Hg measurements were taken using EPA Method 30B (Sorbent Trap method) both downstream of the electrostatic precipitator and in the stack. Ohio Lumex Company was on site to provide rapid Hg analysis on the sorbent traps during the tests. Key results from these tests are: (1) Coal Fines reburn alone reduced NO{sub x} emissions by 0-10% with up to 4% heat input from the CWS. However, the NO{sub x} reduction was accompanied by higher CO emissions. The higher CO limited our ability to try higher reburn rates for further NO{sub x} reduction. (2) Coal Fines reburn with Urea (Carbon enhanced SNCR) decreased NO{sub x} emissions by an additional 30% compared to Urea injection only. (3) Coal slurry injection did not change Hg capture across the ESP at full load with an inlet temperature of 400-430 F. The Hg capture in the ESP averaged 40%, with or without slurry injection; low mercury particulate capture is normally expected across a higher temperature ESP because any oxidized mercury is thought to desorb from the particulate at ESP temperatures above 250 F. (4) Coal slurry injection with halogen salts added to the mixing tank increased the Hg capture in the ESP to 60%. This significant incremental mercury reduction is important to improved mercury capture with hot-side ESP operation and wherever hindrance from sulfur oxides limit mercury reduction, because the higher temperature is above sulfur oxide dew point interference.

  5. Microbial solubilization of coal

    DOE Patents [OSTI]

    Strandberg, G.W.; Lewis, S.N.

    1988-01-21T23:59:59.000Z

    The present invention relates to a cell-free preparation and process for the microbial solubilization of coal into solubilized coal products. More specifically, the present invention relates to bacterial solubilization of coal into solubilized coal products and a cell-free bacterial byproduct useful for solubilizing coal. 5 tabs.

  6. Comparative analysis of methods for determination of arsenic in coal and coal ash

    SciTech Connect (OSTI)

    Vukasinovic-Pesic, V.L.; Blagojevic, N.Z.; Rajakovic, L.V. [University of Montenegro, Podgorica (Montenegro)

    2009-07-01T23:59:59.000Z

    In this paper the comparative analysis of different methods for the preparation and analysis of arsenic content in coal and coal ash have been presented. The suggested method is coal digestion method, i.e., coal ash digestion using the mixture of acids: nitric and sulphuric in presence of vanadium-pentoxide as catalyzer. The comparative analysis of different recording techniques (AAS-GH, AAS-GF and ICP-AES) has also been presented. For arsenic recording the suggested technique is AAS-GF technique. The obtained results show that the method of high precision, high sensitivity and high reproductivity has been obtained.

  7. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

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  8. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

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  9. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

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  10. Workbook Contents

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  11. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

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  12. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

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  13. Workbook Contents

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  14. Workbook Contents

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  15. Coal production expansion: a selected bibliography

    SciTech Connect (OSTI)

    Grissom, M.C. (ed.)

    1980-07-01T23:59:59.000Z

    The expeditious and economic transport of coal from producing regions to consuming regions is essential to any policy designed to increase the use of coal as an energy source. Obtaining an optimal coal transportation system, including terminal facilities, is significant in providing US coal to its users in the United States and abroad. Rail, barge, truck, slurry pipeline, and ship are the modes used to move coal from the producer to the user. Transportation costs represent a large percentage of the delivered price. This bibliography includes 138 selected citations on coal export, transport, and production. The references are to reports from the Department of Energy and its contractors, reports from other government or private organizations, and journal articles, books, conference papers, and monographs from US originators. These citations and hundreds of additional citations on this subject are available for on-line searching and retrieval from the Technical Information Center's Energy Data Base using the DOE/RECON interactive system. Approximately 50,000 citations on coal and coal products are a part of this data base. Current additions to data base on this subject are announced monthly in Fossil Energy Update. DOE-sponsored work is also announced in Energy Research Abstracts. The citations in this publication are arranged in broad subject categories as shown in the table of contents. Five indexes are provided: Corporate, Author, Subject, Contract Number, and Report Number. Included as an appendix are some tables and figures from Energy Information Administration reports covering coal production and disposition.

  16. Calculation of calorific values of coals from ultimate analyses: theoretical basis and geochemical implications. Final report. Part 8

    SciTech Connect (OSTI)

    Given, P.H.; Weldon, D.; Zoeller, J.H.

    1984-03-01T23:59:59.000Z

    The various formulae for calculating calorific values for coals from ultimate analyses depend essentially on a propositon due to Dulong, that the heat of combustion of an organic compound is nearly equal to the heats of combustion of the elements in it, multiplied by their percentage content in the compound in question. This proposition assumes that the enthalpy of decomposition is negligible compared with the heat of combustion. The various published formulae, such as that due to Mott and Spooner, include empirical adjustments to allow for the fact that the enthalpy of formation or decomposition of no organic compound is zero (except rarely by chance). A new equation is proposed, which excludes empirical correction terms but includes a term explicitly related to the enthalpy of decomposition. As expected from the behavior of known compounds, this enthalpy varies with rank, but it also varies at the same level of rank with the geological history of the sample: rank is not the only source of variance in coal properties. The new equation is at least as effective in predicting calorific values for a set of 992 coals as equivalent equations derived for 6 subsets of the coals. On the whole, the distributions of differences between observed and calculated calorific values are skewed to only a small extent. About 86% of the differences lie between -300 and +300 Btu/lb (+- 700 kJ/kg). 10 references, 7 figures, 4 tables.

  17. Fired heater for coal liquefaction process

    DOE Patents [OSTI]

    Ying, David H. S. (Macungie, PA)

    1984-01-01T23:59:59.000Z

    A fired heater for a coal liquefaction process is constructed with a heat transfer tube having U-bends at regular intervals along the length thereof to increase the slug frequency of the multi-phase mixture flowing therethrough to thereby improve the heat transfer efficiency.

  18. USE OF COAL DRYING TO REDUCE WATER CONSUMED IN PULVERIZED COAL POWER PLANTS

    SciTech Connect (OSTI)

    Edward Levy; Harun Bilirgen; Ursla Levy; John Sale; Nenad Sarunac

    2006-01-01T23:59:59.000Z

    This is the twelfth Quarterly Report for this project. The background and technical justification for the project are described, including potential benefits of reducing fuel moisture using power plant waste heat, prior to firing the coal in a pulverized coal boiler. During this last Quarter, the development of analyses to determine the costs and financial benefits of coal drying was continued. The details of the model and key assumptions being used in the economic evaluation are described in this report and results are shown for a drying system utilizing a combination of waste heat from the condenser and thermal energy extracted from boiler flue gas.

  19. Compositional characteristics of the Fire Clay coal bed in a portion of eastern Kentucky

    SciTech Connect (OSTI)

    Hower, J.C.; Andrews, W.M. Jr.; Rimmer, S.M. (Univ. of Kentucky, Lexington (United States)); Eble, C.F. (Kentucky Geological Survey, Lexington (United States))

    1991-08-01T23:59:59.000Z

    The Fire Clay (Hazard No. 4) coal bed (Middle Pennsylvanian Breathitt Formation) is one of the most extensively mined coal in eastern Kentucky. The coal is used for metallurgical and steam end uses and, with its low sulfur content, should continue to be a prime steam coal. This study focuses on the petrology, mineralogy, ash geochemistry, and palynology of the coal in an eight 7.5-min quadrangle area of Leslie, Perry, Knott, and Letcher counties.

  20. Coal industry annual 1993

    SciTech Connect (OSTI)

    Not Available

    1994-12-06T23:59:59.000Z

    Coal Industry Annual 1993 replaces the publication Coal Production (DOE/FIA-0125). This report presents additional tables and expanded versions of tables previously presented in Coal Production, including production, number of mines, Productivity, employment, productive capacity, and recoverable reserves. This report also presents data on coal consumption, coal distribution, coal stocks, coal prices, coal quality, and emissions for a wide audience including the Congress, Federal and State agencies, the coal industry, and the general public. In addition, Appendix A contains a compilation of coal statistics for the major coal-producing States. This report does not include coal consumption data for nonutility Power Producers who are not in the manufacturing, agriculture, mining, construction, or commercial sectors. This consumption is estimated to be 5 million short tons in 1993.

  1. Coal liquefaction and hydrogenation

    DOE Patents [OSTI]

    Schindler, Harvey D. (Fair Lawn, NJ); Chen, James M. (Edison, NJ)

    1985-01-01T23:59:59.000Z

    Disclosed is a coal liquefaction process using two stages. The first stage liquefies the coal and maximizes the product while the second stage hydrocracks the remainder of the coal liquid to produce solvent.

  2. Coal storage hopper with vibrating-screen agitator

    DOE Patents [OSTI]

    Daw, C.S.; Lackey, M.E.; Sy, R.L.

    1982-04-27T23:59:59.000Z

    The present invention is directed to a vibrating screen agitator in a coal storage hopper for assuring the uniform feed of coal having sufficient moisture content to effect agglomeration and bridging thereof in the coal hopper from the latter onto a conveyer mechanism. The vibrating scrren agitator is provided by a plurality of transversely oriented and vertically spaced apart screens in the storage hopper with a plurality of vertically oriented rods attached to the screens. The rods are vibrated to effect the vibration of the screens and the breaking up of agglomerates in the coal which might impede the uniform flow of the coal from the hopper onto a conveyer.

  3. Alaska coal geology, resources, and coalbed methane potential

    SciTech Connect (OSTI)

    Romeo M. Flores; Gary D. Stricker; Scott A. Kinney

    2005-11-15T23:59:59.000Z

    Estimated Alaska coal resources are largely in Cretaceous and Tertiary rocks distributed in three major provinces, Northern Alaska-Slope, Central Alaska-Nenana, and Southern Alaska-Cook Inlet. Cretaceous resources, predominantly bituminous coal and lignite, are in the Northern Alaska-Slope coal province. Most of the Tertiary resources, mainly lignite to subbituminous coal with minor amounts of bituminous and semianthracite coals, are in the other two provinces. The combined measured, indicated, inferred, and hypothetical coal resources in the three areas are estimated to be 5,526 billion short tons (5,012 billion metric tons), which constitutes about 87 percent of Alaska's coal and surpasses the total coal resources of the conterminous United States by 40 percent. Coal mining has been intermittent in the Central Alaskan-Nenana and Southern Alaska-Cook Inlet coal provinces, with only a small fraction of the identified coal resource having been produced from some dozen underground and strip mines. Alaskan coals have a lower sulfur content (averaging 0.3 percent) than most coals in the conterminous United States and are within or below the minimum sulfur value mandated by the 1990 Clean Air Act amendments. Another untapped potential resource is coalbed methane estimated to total 1,000 trillion cubic feet (28 trillion cubic meters).

  4. Coal combustion science

    SciTech Connect (OSTI)

    Hardesty, D.R. (ed.); Baxter, L.L.; Fletcher, T.H.; Mitchell, R.E.

    1990-11-01T23:59:59.000Z

    The objective of this activity is to support the Office of Fossil Energy in executing research on coal combustion science. This activity consists of basic research on coal combustion that supports both the Pittsburgh Energy Technology Center (PETC) Direct Utilization Advanced Research and Technology Development Program, and the International Energy Agency (IEA) Coal Combustion Science Project. Specific tasks include: coal devolatilization, coal char combustion, and fate of mineral matter during coal combustion. 91 refs., 40 figs., 9 tabs.

  5. Fuel supply system and method for coal-fired prime mover

    DOE Patents [OSTI]

    Smith, William C. (Morgantown, WV); Paulson, Leland E. (Morgantown, WV)

    1995-01-01T23:59:59.000Z

    A coal-fired gas turbine engine is provided with an on-site coal preparation and engine feeding arrangement. With this arrangement, relatively large dry particles of coal from an on-site coal supply are micro-pulverized and the resulting dry, micron-sized, coal particulates are conveyed by steam or air into the combustion chamber of the engine. Thermal energy introduced into the coal particulates during the micro-pulverizing step is substantially recovered since the so-heated coal particulates are fed directly from the micro-pulverizer into the combustion chamber.

  6. Studies on the production of ultra-clean coal by alkali-acid leaching of low-grade coals

    SciTech Connect (OSTI)

    Nabeel, A.; Khan, T.A.; Sharma, D.K. [Jamia Millia Islamia, New Delhi (India). Dept. of Chemistry

    2009-07-01T23:59:59.000Z

    The use of low-grade coal in thermal power stations is leading to environmental pollution due to the generation of large amounts of fly ash, bottom ash, and CO{sub 2} besides other pollutants. It is therefore important to clean the coal before using it in thermal power stations, steel plants, or cement industries etc. Physical beneficiation of coal results in only limited cleaning of coal. The increasing environmental pollution problems from the use of coal have led to the development of clean coal technologies. In fact, the clean use of coal requires the cleaning of coal to ultra low ash contents, keeping environmental norms and problems in view and the ever-growing need to increase the efficiency of coal-based power generation. Therefore this requires the adaptation of chemical cleaning techniques for cleaning the coal to obtain ultra clean coal having ultra low ash contents. Presently the reaction conditions for chemical demineralization of low-grade coal using 20% aq NaOH treatment followed by 10% H{sub 2}SO{sub 4} leaching under reflux conditions have been optimized. In order to reduce the concentration of alkali and acid used in this process of chemical demineralization of low-grade coals, stepwise, i.e., three step process of chemical demineralization of coal using 1% or 5% aq NaOH treatment followed by 1% or 5% H{sub 2}SO{sub 4} leaching has been developed, which has shown good results in demineralization of low-grade coals. In order to conserve energy, the alkali-acid leaching of coal was also carried out at room temperature, which gave good results.

  7. Fluidized bed selective pyrolysis of coal

    DOE Patents [OSTI]

    Shang, J.Y.; Cha, C.Y.; Merriam, N.W.

    1992-12-15T23:59:59.000Z

    The present invention discloses a process for the pyrolysis of coal which comprises the effective utilization of two zonal inclined fluidized beds, where said zones can be selectively controlled as to temperature and heating rate. The first zonal inclined fluidized bed serves as a dryer for crushed coal and additionally is controlled to selectively pyrolyze said coal producing substantially carbon dioxide for recycle use. The second zonal inclined fluidized bed further pyrolyses the coal to gaseous, liquid and char products under controlled temperature and heating rate zones designed to economically integrate the product mix. The gas and liquid products are recovered from the gaseous effluent stream while the char which remains can be further treated or utilized in a subsequent process step. 9 figs.

  8. Coal Mining (Iowa)

    Broader source: Energy.gov [DOE]

    These sections describe procedures for coal exploration and extraction, as well as permitting requirements relating to surface and underground coal mining. These sections also address land...

  9. Research on thermophoretic and inertial aspects of ash particle: Deposition on heat exchanger surfaces in coal-fired equipment: Quarterly technical report, June 1, 1988--August 31, 1988

    SciTech Connect (OSTI)

    Rosner, D.E.

    1988-09-01T23:59:59.000Z

    DOE-PETC has initiated at the Yale HTCRE Laboratory a systematic three-year experimental and theoretical research program directed toward providing engineers with the data, methods, and rational correlations needed to improve the generality and accuracy of prediction of inorganic particle deposition rates under typical coal combustion conditions i.e., those leading to the importance of thermophoretically-enhanced diffusion (submicron mode) and the inertially-enhanced ''impaction'' (supermicron mode), often in the presence of simultaneous alkali salt vapor condensation. After a brief statement of objectives (Section 2) we outline our experimental and theoretical progress during this quarterly reporting period (Section 3), with our results summarized in the references documented in Section 5. Section 4 gives relevant administrative information (personnel, research plans). 15 refs., 3 figs.

  10. Ultrasound-promoted chemical desulfurization of Illinois coals

    SciTech Connect (OSTI)

    Chao, S.S.

    1991-01-01T23:59:59.000Z

    The overall objectives of the program were to investigate the use of ultrasound to promote coal desulfurization reactions and to evaluate chemical coal desulfurization schemes under mild conditions through a fundamental understanding of their reaction mechanisms and kinetics. The ultimate goal was to develop an economically feasible mild chemical process to reduce the total sulfur content of Illinois Basin Coals, while retaining their original physical characteristics, such as calorific value and volatile matter content. During the program, potential chemical reactions with coal were surveyed under various ultrasonic irradiation conditions for desulfurization, to formulate preliminary reaction pathways, and to select a few of the more promising chemical processes for more extensive study.

  11. Repowering with clean coal technologies

    SciTech Connect (OSTI)

    Freier, M.D. [USDOE Morgantown Energy Technology Center, WV (United States); Buchanan, T.L.; DeLallo, M.L.; Goldstein, H.N. [Parsons Power Group, Inc., Reading, PA (United States)

    1996-02-01T23:59:59.000Z

    Repowering with clean coal technology can offer significant advantages, including lower heat rates and production costs, environmental compliance, incremental capacity increases, and life extension of existing facilities. Significant savings of capital costs can result by refurbishing and reusing existing sites and infrastructure relative to a greenfield siting approach. This paper summarizes some key results of a study performed by Parsons Power Group, Inc., under a contract with DOE/METC, which investigates many of the promising advanced power generation technologies in a repowering application. The purpose of this study was to evaluate the technical and economic results of applying each of a menu of Clean Coal Technologies in a repowering of a hypothetical representative fossil fueled power station. Pittsburgh No. 8 coal is used as the fuel for most of the cases evaluated herein, as well as serving as the fuel for the original unrepowered station. The steam turbine-generator, condenser, and circulating water system are refurbished and reused in this study, as is most of the existing site infrastructure such as transmission lines, railroad, coal yard and coal handling equipment, etc. The technologies evaluated in this study consisted of an atmospheric fluidized bed combustor, several varieties of pressurized fluid bed combustors, several types of gasifiers, a refueling with a process derived fuel, and, for reference, a natural gas fired combustion turbine-combined cycle.

  12. Firing of pulverized solvent refined coal

    DOE Patents [OSTI]

    Lennon, Dennis R. (Allentown, PA); Snedden, Richard B. (McKeesport, PA); Foster, Edward P. (Macungie, PA); Bellas, George T. (Library, PA)

    1990-05-15T23:59:59.000Z

    A burner for the firing of pulverized solvent refined coal is constructed and operated such that the solvent refined coal can be fired successfully without any performance limitations and without the coking of the solvent refined coal on the burner components. The burner is provided with a tangential inlet of primary air and pulverized fuel, a vaned diffusion swirler for the mixture of primary air and fuel, a center water-cooled conical diffuser shielding the incoming fuel from the heat radiation from the flame and deflecting the primary air and fuel steam into the secondary air, and a watercooled annulus located between the primary air and secondary air flows.

  13. Coal log pipeline research at University of Missouri. 1. quarterly report for 1996, January 1--March 31, 1996

    SciTech Connect (OSTI)

    NONE

    1996-07-01T23:59:59.000Z

    This project consists of the following nine tasks: Machine design for coal log fabrication; Very rapid compaction of coal logs; Rapid compaction of coal logs; Fast-track experiments on coal log compaction; Coal log fabrication using hydrophobic binders; Drag reduction in large diameter hydraulic capsule pipeline; Automatic control of coal log pipeline system; Hydraulics of CLP (Coal Log Pipeline); and Coal heating system research. The purpose of the task, the work accomplished during this report period, and work proposed for the next quarter are described for each task.

  14. TABLE OF CONTENTS ABSTRACT . . .. . . .. . . . . . . . . . . . . . . . . . . . . . v

    E-Print Network [OSTI]

    Oak Ridge National Laboratory

    ............................................... 12 Water-Source Heat Pump Performance ............................ 18 Air-Source Heat Pump QUARTZ CONTENT OF SEDIMENTARY ROCK LAYERS ........ 17 TABLE 10. PROPERTIES OF SEDIMENTARY ROCK LAYERS OF PERFORMANCE OF WATER-SOURCE HEAT PUMP .............................. ................. 23 FIGURE 2. NODAL

  15. Preparation for upgrading western subbituminous coal

    SciTech Connect (OSTI)

    Grimes, R.W.; Cha, C.Y.; Sheesley, D.C.

    1990-11-01T23:59:59.000Z

    The objective of this project was to establish the physical and chemical characteristics of western coal and determine the best preparation technologies for upgrading this resource. Western coal was characterized as an abundant, easily mineable, clean, low-sulfur coal with low heating value, high moisture, susceptibility to spontaneous ignition, and considerable transit distances from major markets. Project support was provided by the Morgantown Energy Technology Center (METC) of the US Department of Energy (DOE). The research was conducted by the Western Research Institute, (WRI) in Laramie, Wyoming. The project scope of work required the completion of four tasks: (1) project planning, (2) literature searches and verbal contacts with consumers and producers of western coal, (3) selection of the best technologies to upgrade western coal, and (4) identification of research needed to develop the best technologies for upgrading western coals. The results of this research suggest that thermal drying is the best technology for upgrading western coals. There is a significant need for further research in areas involving physical and chemical stabilization of the dried coal product. Excessive particle-size degradation and resulting dustiness, moisture reabsorption, and high susceptibility to spontaneous combustion are key areas requiring further research. Improved testing methods for the determination of equilibrium moisture and susceptibility to spontaneous ignition under various ambient conditions are recommended.

  16. Structural characteristics and gasification reactivity of chars prepared from K{sub 2}CO{sub 3} mixed HyperCoals and coals

    SciTech Connect (OSTI)

    Atul Sharma; Hiroyuki Kawashima; Ikuo Saito; Toshimasa Takanohashi [National Institute of Advanced Industrial Science and Technology, Ibaraki (Japan). Advanced Fuel Group

    2009-04-15T23:59:59.000Z

    HyperCoal is a clean coal with mineral matter content <0.05 wt %. Oaky Creek (C = 82%), and Pasir (C = 68%) coals were subjected to solvent extraction method to prepare Oaky Creek HyperCoal, and Pasir HyperCoal. Experiments were carried out to compare the gasification reactivity of HyperCoals and parent raw coals with 20, 40, 50 and 60% K{sub 2}CO{sub 3} as a catalyst at 600, 650, 700, and 775{sup o}C with steam. Gasification rates of coals and HyperCoals were strongly influenced by the temperature and catalyst loading. Catalytic steam gasification of HyperCoal chars was found to be chemical reaction controlled in the 600-700{sup o}C temperature range for all catalyst loadings. Gasification rates of HyperCoal chars were found to be always higher than parent coals at any given temperature for all catalyst loadings. However, X-ray diffraction results showed that the microstructures of chars prepared from coals and HyperCoals were similar. Results from nuclear magnetic resonance spectroscopy show no significant difference between the chemical compositions of the chars. Significant differences were observed from scanning electron microscopy images, which showed that the chars from HyperCoals had coral-reef like structures whereas dense chars were observed for coals. 26 refs., 8 figs., 2 tabs.

  17. Compliance testing of Grissom AFB, Central Heating Plant coal-fired boilers 3, 4 and 5, Grissom AFB, Indiana. Final report, 3-13 Dec 90

    SciTech Connect (OSTI)

    Vaughn, R.W.

    1991-03-01T23:59:59.000Z

    Source compliance testing (particulates and visible emissions) of boiler 3, 4 and 5 in the Grissom AFB Central Heating Plant was accomplished 3-13 Dec 90. The boilers were all tested through the bypass stack. Visible emissions from the three boilers met applicable opacity regulations. However, particulate emissions from the three boilers were above their applicable emission standards.

  18. An efficient process for recovery of fine coal from tailings of coal washing plants

    SciTech Connect (OSTI)

    Cicek, T.; Cocen, I.; Engin, V.T.; Cengizler, H. [Dokuz Eylul University, Izmir (Turkey). Dept. for Mining Engineering

    2008-07-01T23:59:59.000Z

    Gravity concentration of hard lignites using conventional jigs and heavy media separation equipment is prone to produce coal-rich fine tailings. This study aims to establish a fine coal recovery process of very high efficiency at reasonable capital investment and operational costs. The technical feasibility to upgrade the properties of the predeslimed fine refuse of a lignite washing plant with 35.9% ash content was investigated by employing gravity separation methods. The laboratory tests carried out with the combination of shaking table and Mozley multi-gravity separator (MGS) revealed that the clean coal with 18% ash content on dry basis could be obtained with 58.9% clean coal recovery by the shaking table stage and 4.1% clean coal recovery by MGS stage, totaling to the sum of 63.0% clean coal recovery from a predeslimed feed. The combustible recovery and the organic efficiency of the shaking table + MGS combination were 79.5% and 95.5%, respectively. Based on the results of the study, a flow sheet of a high-efficiency fine coal recovery process was proposed, which is also applicable to the coal refuse pond slurry of a lignite washing plant.

  19. Coal systems analysis

    SciTech Connect (OSTI)

    Warwick, P.D. (ed.)

    2005-07-01T23:59:59.000Z

    This collection of papers provides an introduction to the concept of coal systems analysis and contains examples of how coal systems analysis can be used to understand, characterize, and evaluate coal and coal gas resources. Chapter are: Coal systems analysis: A new approach to the understanding of coal formation, coal quality and environmental considerations, and coal as a source rock for hydrocarbons by Peter D. Warwick. Appalachian coal assessment: Defining the coal systems of the Appalachian Basin by Robert C. Milici. Subtle structural influences on coal thickness and distribution: Examples from the Lower Broas-Stockton coal (Middle Pennsylvanian), Eastern Kentucky Coal Field, USA by Stephen F. Greb, Cortland F. Eble, and J.C. Hower. Palynology in coal systems analysis The key to floras, climate, and stratigraphy of coal-forming environments by Douglas J. Nichols. A comparison of late Paleocene and late Eocene lignite depositional systems using palynology, upper Wilcox and upper Jackson Groups, east-central Texas by Jennifer M.K. O'Keefe, Recep H. Sancay, Anne L. Raymond, and Thomas E. Yancey. New insights on the hydrocarbon system of the Fruitland Formation coal beds, northern San Juan Basin, Colorado and New Mexico, USA by W.C. Riese, William L. Pelzmann, and Glen T. Snyder.

  20. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    transportation component of coal price should also increase;investment. Coal costs and prices are functions of a numberto forecast coal demand, supply, and prices from now to

  1. Clean and Secure Energy from Coal

    SciTech Connect (OSTI)

    Smith, Philip; Davies, Lincoln; Kelly, Kerry; Lighty, JoAnn; Reitze, Arnold; Silcox, Geoffrey; Uchitel, Kirsten; Wendt, Jost; Whitty, Kevin

    2014-08-31T23:59:59.000Z

    The University of Utah, through their Institute for Clean and Secure Energy (ICSE), performed research to utilize the vast energy stored in our domestic coal resources and to do so in a manner that will capture CO2 from combustion from stationary power generation. The research was organized around the theme of validation and uncertainty quantification (V/UQ) through tightly coupled simulation and experimental designs and through the integration of legal, environment, economics and policy issues. The project included the following tasks: • Oxy-Coal Combustion – To ultimately produce predictive capability with quantified uncertainty bounds for pilot-scale, single-burner, oxy-coal operation. • High-Pressure, Entrained-Flow Coal Gasification – To ultimately provide a simulation tool for industrial entrained-flow integrated gasification combined cycle (IGCC) gasifier with quantified uncertainty. • Chemical Looping Combustion (CLC) – To develop a new carbon-capture technology for coal through CLC and to transfer this technology to industry through a numerical simulation tool with quantified uncertainty bounds. • Underground Coal Thermal Treatment – To explore the potential for creating new in-situ technologies for production of synthetic natural gas (SNG) from deep coal deposits and to demonstrate this in a new laboratory-scale reactor. • Mercury Control – To understand the effect of oxy-firing on the fate of mercury. • Environmental, Legal, and Policy Issues – To address the legal and policy issues associated with carbon management strategies in order to assess the appropriate role of these technologies in our evolving national energy portfolio. • Validation/Uncertainty Quantification for Large Eddy Simulations of the Heat Flux in the Tangentially Fired Oxy-Coal Alstom Boiler Simulation Facility – To produce predictive capability with quantified uncertainty bounds for the heat flux in commercial-scale, tangentially fired, oxy-coal boilers.

  2. Energy Policy Act transportation rate study: Interim report on coal transportation

    SciTech Connect (OSTI)

    NONE

    1995-10-01T23:59:59.000Z

    The primary purpose of this report is to examine changes in domestic coal distribution and railroad coal transportation rates since enactment of the Clean Air Act Amendments of 1990 (CAAA90). From 1988 through 1993, the demand for low-sulfur coal increased, as a the 1995 deadline for compliance with Phase 1 of CAAA90 approached. The shift toward low-sulfur coal came sooner than had been generally expected because many electric utilities switched early from high-sulfur coal to ``compliance`` (very low-sulfur) coal. They did so to accumulate emissions allowances that could be used to meet the stricter Phase 2 requirements. Thus, the demand for compliance coal increased the most. The report describes coal distribution and sulfur content, railroad coal transportation and transportation rates, and electric utility contract coal transportation trends from 1979 to 1993 including national trends, regional comparisons, distribution patterns and regional profiles. 14 figs., 76 tabs.

  3. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

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  4. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

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  5. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

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  6. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

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  7. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

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  8. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

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  9. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

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  10. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

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  11. Workbook Contents

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  12. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

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  13. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

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  14. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

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  15. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

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  16. Underground Coal Thermal Treatment Task 6 Topical Report, Utah Clean Coal Program

    SciTech Connect (OSTI)

    Smith, P.J.; Deo, M.; Edding, E.G.; Hradisky, M.; Kelly, K.E.; Krumm, R.; Sarofim, Adel; Wang, D.

    2014-08-15T23:59:59.000Z

    The long-term objective of this task is to develop a transformational energy production technology by in- situ thermal treatment of a coal seam for the production of substitute natural gas and/or liquid transportation fuels while leaving much of the coal’s carbon in the ground. This process converts coal to a high-efficiency, low-greenhouse gas (GHG) emitting fuel. It holds the potential of providing environmentally acceptable access to previously unusable coal resources. This task focused on three areas: • Experimental. The Underground Coal Thermal Treatment (UCTT) team focused on experiments at two scales, bench-top and slightly larger, to develop data to understand the feasibility of a UCTT process as well as to develop validation/uncertainty quantification (V/UQ) data for the simulation team. • Simulation. The investigators completed development of High Performance Computing (HPC) simulations of UCTT. This built on our simulation developments over the course of the task and included the application of Computational Fluid Dynamics (CFD)- based tools to perform HPC simulations of a realistically sized domain representative of an actual coal field located in Utah. • CO2 storage. In order to help determine the amount of CO2 that can be sequestered in a coal formation that has undergone UCTT, adsorption isotherms were performed on coals treated to 325, 450, and 600°C with slow heating rates. Raw material was sourced from the Sufco (Utah), Carlinville (Illinois), and North Antelope (Wyoming) mines. The study indicated that adsorptive capacity for the coals increased with treatment temperature and that coals treated to 325°C showed less or similar capacity to the untreated coals.

  17. COAL DESULFURIZATION PRIOR TO COMBUSTION

    E-Print Network [OSTI]

    Wrathall, J.

    2013-01-01T23:59:59.000Z

    90e COAL DESULFURIZATION PRIOR TO COMBUSTION J. Wrathall, T.of coal during combustion. The process involves the additionCOAL DESULFURIZATION PRIOR TO COMBUSTION Lawrence Berkeley

  18. Coal data: A reference

    SciTech Connect (OSTI)

    Not Available

    1995-02-01T23:59:59.000Z

    This report, Coal Data: A Reference, summarizes basic information on the mining and use of coal, an important source of energy in the US. This report is written for a general audience. The goal is to cover basic material and strike a reasonable compromise between overly generalized statements and detailed analyses. The section ``Supplemental Figures and Tables`` contains statistics, graphs, maps, and other illustrations that show trends, patterns, geographic locations, and similar coal-related information. The section ``Coal Terminology and Related Information`` provides additional information about terms mentioned in the text and introduces some new terms. The last edition of Coal Data: A Reference was published in 1991. The present edition contains updated data as well as expanded reviews and additional information. Added to the text are discussions of coal quality, coal prices, unions, and strikes. The appendix has been expanded to provide statistics on a variety of additional topics, such as: trends in coal production and royalties from Federal and Indian coal leases, hours worked and earnings for coal mine employment, railroad coal shipments and revenues, waterborne coal traffic, coal export loading terminals, utility coal combustion byproducts, and trace elements in coal. The information in this report has been gleaned mainly from the sources in the bibliography. The reader interested in going beyond the scope of this report should consult these sources. The statistics are largely from reports published by the Energy Information Administration.

  19. The use of NMR techniques for the analysis of water in coal and the effect of different coal drying techniques on the structure and reactivity of coal. Final report

    SciTech Connect (OSTI)

    Netzel, D.A.; Miknis, F.P.; Wallace, J.C. Jr.; Butcher, C.H.; Mitzel, J.M.; Turner, T.F.; Hurtubise, R.J.

    1995-02-01T23:59:59.000Z

    Western Research Institute has conducted a study of different methods of coal drying as pretreatment steps before liquefaction. The objectives of this study were to develop a combined chemical dehydration/nuclear magnetic resonance (NMR) method for measuring the moisture content of coal, to measure the changes in coal structure that occur during drying, and to determine the effects of different drying methods on liquefaction reactivity of coals. Different methods of drying were investigated to determine whether coal drying can be accomplished without reducing the reactivity of coals toward liquefaction. Drying methods included thermal, microwave, and chemical dehydration. Coals of rank lignite to high volatile bituminous were studied. Coals that were dried or partially dried thermally and with microwaves had lower liquefaction conversions than coals containing equilibrium moisture contents. However, chemically dried coals had conversions equal to or greater than the premoisturized coals. The conversion behavior is consistent with changes in the physical structure and cross linking reactions because of drying. Thermal and microwave drying appear to cause a collapse in the pore structure, thus preventing donor solvents such as tetralin from contacting reactive sites inside the coals. Chemical dehydration does not appear to collapse the pore structure. These results are supported by the solvent swelling measurements in which the swelling ratios of thermally dried and microwave-dried coals were lower than those of premoisturized coals, indicating a greater degree of cross linking in the dried coals. The swelling ratios of the chemically dried coals were greater than those of the premoisturized coals because the pore structure remaining unchanged or increased when water was removed. These results are consistent with the NMR results, which did not show significant changes in coal chemical structure.

  20. Heat Loss Measurement Using Infrared Imaging

    E-Print Network [OSTI]

    Seeber, S. A.

    1983-01-01T23:59:59.000Z

    in various applications. Examples of two applications are presented. The first describes the development of heat balance data for a solvent refined coal processing unit. The second describes the measurement of heat loss and thermal resistance in a double...

  1. Unraveling the Excess Air/Coal Fineness Enigma

    E-Print Network [OSTI]

    Laspe, C. G.

    1983-01-01T23:59:59.000Z

    In the use of powered coal as a boiler fuel, the factors involved in heat loss from unburnt carbon in the ash are but partially understood. More finely pulverized coal particles will result in lower carbon-in-ash losses. On the other hand, the finer...

  2. COAL LIQUEFACTION USING ZINC CHLORIDE CATALYST IN AN EXTRACTING SOLVENT MEDIUM

    E-Print Network [OSTI]

    Gandhi, Shamim Ahmed

    2013-01-01T23:59:59.000Z

    of Coal- derived Asphaltene, Fuel, Vol. 57, 676 (1978) Mayo,Castex, H. , Analysis of Asphaltenes by Carbon and Protonalso increased the asphaltene and preasphaltene content of

  3. Assessment of coal liquids as refinery feedstocks

    SciTech Connect (OSTI)

    Zhou, P.

    1992-02-01T23:59:59.000Z

    The R&D of direct coal liquefaction has reached such a stage that current two-stage processes can produce coal liquids with high yields and improved quality at a reasonable cost. To fully realize the potential value, these coal liquids should be refined into high-value liquid transportation fuels. The purpose of this study is to assess coal liquids as feedstocks to be processed by modern petroleum refining technologies. After the introduction, Section 2.0 summarizes ASTM specifications for major transportation fuels: gasoline, jet fuel, and diesel fuel, which serve as a target for coal-liquid refining. A concise description of modern refining processes follows with an emphasis on the requirements for the raw materials. These provide criteria to judge the quality of coal liquids as a refinery feedstock for the production of marketable liquid fuels. Section 3.0 surveys the properties of coal liquids produced by various liquefaction processes. Compared with typical petroleum oils, the current two-stage coal liquids are: Light in boiling range and free of resids and metals; very low in sulfur but relatively high in oxygen; relatively low in hydrogen and high in cyclics content; and essentially toxicologically inactive when end point is lower than 650{degrees}F, particularly after hydroprocessing. Despite these characteristics, the coal liquids are basically similar to petroleum. The modern refining technology is capable of processing coal liquids into transportation fuels meeting all specifications, and hydroprocessinq is obviously the major tool. The important point is the determination of a reasonable product slate and an appropriate refining scheme.

  4. Assessment of coal liquids as refinery feedstocks

    SciTech Connect (OSTI)

    Zhou, P.

    1992-02-01T23:59:59.000Z

    The R D of direct coal liquefaction has reached such a stage that current two-stage processes can produce coal liquids with high yields and improved quality at a reasonable cost. To fully realize the potential value, these coal liquids should be refined into high-value liquid transportation fuels. The purpose of this study is to assess coal liquids as feedstocks to be processed by modern petroleum refining technologies. After the introduction, Section 2.0 summarizes ASTM specifications for major transportation fuels: gasoline, jet fuel, and diesel fuel, which serve as a target for coal-liquid refining. A concise description of modern refining processes follows with an emphasis on the requirements for the raw materials. These provide criteria to judge the quality of coal liquids as a refinery feedstock for the production of marketable liquid fuels. Section 3.0 surveys the properties of coal liquids produced by various liquefaction processes. Compared with typical petroleum oils, the current two-stage coal liquids are: Light in boiling range and free of resids and metals; very low in sulfur but relatively high in oxygen; relatively low in hydrogen and high in cyclics content; and essentially toxicologically inactive when end point is lower than 650[degrees]F, particularly after hydroprocessing. Despite these characteristics, the coal liquids are basically similar to petroleum. The modern refining technology is capable of processing coal liquids into transportation fuels meeting all specifications, and hydroprocessinq is obviously the major tool. The important point is the determination of a reasonable product slate and an appropriate refining scheme.

  5. Compliance testing of Grissom AFB Central Heating Plant coal-fired boilers 3, 4, and 5, Grissom AFB, Indiana. Final report, 29 January-15 February 1989

    SciTech Connect (OSTI)

    Garrison, J.A.

    1989-06-01T23:59:59.000Z

    At the request of HQ, SAC/SGPB source compliance testing (particulate and visible emissions) of boilers 3, 4, and 5 in the Grissom AFB Central Heating Plant was accomplished 29 Jan-15 Feb 89. The survey was conducted to determine compliance with regards to Indiana Administrative Code, Title 325 - Air Pollution Control Board, Article 5, Opacity Regulations, and Article 6, Particulate Regulations. Boiler 3 was tested through scrubber B, Boiler 4 through scrubber A, and Boiler 5 through scrubber B and the bypass stack. Results indicate that each boiler met applicable visible and particulate emission standards.

  6. Low-rank coal research: Volume 3, Combustion research: Final report. [Great Plains

    SciTech Connect (OSTI)

    Mann, M. D.; Hajicek, D. R.; Zobeck, B. J.; Kalmanovitch, D. P.; Potas, T. A.; Maas, D. J.; Malterer, T. J.; DeWall, R. A.; Miller, B. G.; Johnson, M. D.

    1987-04-01T23:59:59.000Z

    Volume III, Combustion Research, contains articles on fluidized bed combustion, advanced processes for low-rank coal slurry production, low-rank coal slurry combustion, heat engine utilization of low-rank coals, and Great Plains Gasification Plant. These articles have been entered individually into EDB and ERA. (LTN)

  7. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    Coal Cleaning Costs Process Clean Coal Produced, * T/D (DryMM$ Net Operating Cost, $/T (Clean Coal Basis) Net OperatingCost, $/T (Clean Coal Bases) Case NA Hazen KVB Battelle

  8. Pulverized coal combustion characterization at the KEPRI

    SciTech Connect (OSTI)

    Cha, D.J.; Kim, S.C.; Bae, B.H.; Kim, T.H.; Shin, Y.J.; Lee, H.D.; Park, O.Y.; Choi, B.S.

    1997-12-31T23:59:59.000Z

    A pilot-scale combustion test facility that can be utilized to burn pulverized coals such as anthracite coals, bituminous coals, and their blends at the rate of 200 kg/hr has been constructed to study coal-related impacts on utility boiler operations. The impacts include pulverizer performance, combustion stability, slagging, fouling, heat transfer, erosion, corrosion, pollutant emission, etc. The facility, a scale-down model of an existing boiler in Korea, consists of all the necessary components for the boiler with a distributed control system except steam generation components which have been replaced with slag panels, fouling probes, and heat exchangers. The facility, in addition, incorporates the advanced boiler technologies including tangentially-fired burners, flue gas recirculation, direct sorbent injection for desulfurization, electrostatic precipitator, wet scrubber, etc., and employs an opacity meter and gas analyzers. Low NOx burners and gas reburning system will be facilitated in the future to study low emission boiler systems being demonstrated in the developed countries. This paper represents preliminary test results including flame shapes, fouling based on the fouling factor, and pollutant emission with different coals and combustion aerodynamics. Flow fields in the furnace have been changed by varying the swirl number and the burner configurations in terms of single-wall, opposed-wall, and corner firing mode. An extensive investigation will continue to find optimum conditions for various coals of interest.

  9. STRUCTURAL ELUCIDATION, MOLECULAR REPRESENTATION AND SOLVENT INTERACTIONS OF VITRINITE-RICH AND INERTINITE-RICH SOUTH AFRICAN COALS.

    E-Print Network [OSTI]

    Van Niekerk, Daniel

    2008-01-01T23:59:59.000Z

    ??Two Permian-aged South African coals, vitrinite-rich Waterberg and inertinite-rich Highveld coals (similar rank, carbon content and Permian age), were studied to determine the structural differences… (more)

  10. Influence of coal on coke properties and blast-furnace operation

    SciTech Connect (OSTI)

    G.R. Gainieva; L.D. Nikitin [OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (Russian Federation)

    2007-07-01T23:59:59.000Z

    With unstable coal supplies and properties and a fluctuating content of coking coal in the batch at OAO Zapadno-Sibirskii Metallurgicheskii Kombinat (ZSMK) and of bituminous coal at Kuznetskaya enrichment facility, it is important to optimize the rank composition of the batch for coke production.

  11. Correlation relations between mineralogical components in ash from Kaa-Khem coals

    SciTech Connect (OSTI)

    N.N. Yanchat; L.Kh. Tas-ool [Russian Academy of Sciences, Kyzyl (Russia). Tuvinian Institute for Complex Exploration of Natural Resources

    2008-08-15T23:59:59.000Z

    Regression analysis was used to study correlation relations between the mineral components of coals. Regularities in the variability of the concentrations of individual ash-forming elements with changing ash contents of coals and changing seam depth were found. The X-ray diffraction characteristics of coal ashes and the qualitative composition of their mineralogical components are presented.

  12. Low temperature pyrolysis of coal or oil shale in the presence of calcium compounds

    DOE Patents [OSTI]

    Khan, M. Rashid (Morgantown, WV)

    1988-01-01T23:59:59.000Z

    A coal pyrolysis technique or process is described in which particulate coal is pyrolyzed in the presence of about 5 to 21 wt. % of a calcium compound selected from calcium oxide, calcined (hydrate) dolomite, or calcined calcium hydrate to produce a high quality hydrocarbon liquid and a combustible product gas which are characterized by low sulfur content. The pyrolysis is achieved by heating the coal-calcium compound mixture at a relatively slow rate at a temperature of about 450.degree. to 700.degree. C. over a duration of about 10 to 60 minutes in a fixed or moving bed reactor. The gas exhibits an increased yield in hydrogen and C.sub.1 -C.sub.8 hydrocarbons and a reduction in H.sub.2 S over gas obtainable by pyrolyzing cola without the calcium compound. The liquid product obtained is of a sufficient quality to permit its use directly as a fuel and has a reduced sulfur and oxygen content which inhibits polymerization during storage.

  13. USE OF COAL DRYING TO REDUCE WATER CONSUMED IN PULVERIZED COAL POWER PLANTS

    SciTech Connect (OSTI)

    Nenad Sarunac; Edward Levy

    2005-03-01T23:59:59.000Z

    This is the eighth Quarterly Report for this project. The background and technical justification for the project are described, including potential benefits of reducing fuel moisture, prior to firing in a pulverized coal boiler. Analyses were performed to determine the effects of coal product moisture on unit performance. Results are given showing how the coal product moisture level affects parameters such as boiler efficiency, power required to drive the fluidizing air fan, other station service power needed for fans and pulverizers, net unit heat rate, thermal energy rejected by the cooling tower, and stack emissions.

  14. Apparatus and method for solar coal gasification

    DOE Patents [OSTI]

    Gregg, David W. (Moraga, CA)

    1980-01-01T23:59:59.000Z

    Apparatus for using focused solar radiation to gasify coal and other carbonaceous materials. Incident solar radiation is focused from an array of heliostats onto a tower-mounted secondary mirror which redirects the focused solar radiation down through a window onto the surface of a vertically-moving bed of coal, or a fluidized bed of coal, contained within a gasification reactor. The reactor is designed to minimize contact between the window and solids in the reactor. Steam introduced into the gasification reactor reacts with the heated coal to produce gas consisting mainly of carbon monoxide and hydrogen, commonly called "synthesis gas", which can be converted to methane, methanol, gasoline, and other useful products. One of the novel features of the invention is the generation of process steam at the rear surface of the secondary mirror.

  15. Characterization of feed coal and coal combustion products from power plants in Indiana and Kentucky

    SciTech Connect (OSTI)

    Brownfield, M.E.; Affolter, R.H.; Cathcart, J.D.; O'Connor, J.T.; Brownfield, I.K.

    1999-07-01T23:59:59.000Z

    The US Geological Survey, Kentucky Geological Survey, and the University of Kentucky Center for Applied Energy Research are collaborating with Indiana and Kentucky utilities to determine the physical and chemical properties of feed coal and coal combustion products (CCP) from three coal-fired power plants. These three plants are designated as Units K1, K2, and I1 and burn high-, moderate-, and low-sulfur coals, respectively. Over 200 samples of feed coal and CCP were analyzed by various chemical and mineralogical methods to determine mode of occurrence and distribution of trace elements in the CCP. Generally, feed coals from all 3 Units contain mostly well-crystallized kaolinite and quartz. Comparatively, Unit K1 feed coals have higher amounts of carbonates, pyrite and sphalerite. Unit K2 feed coals contain higher kaolinite and illite/muscovite when compared to Unit K1 coals. Unit I1 feed coals contain beta-form quartz and alumino-phosphates with minor amounts of calcite, micas, anatase, and zircon when compared to K1 and K2 feed coals. Mineralogy of feed coals indicate that the coal sources for Units K1 and K2 are highly variable, with Unit K1 displaying the greatest mineralogic variability; Unit I1 feed coal however, displayed little mineralogic variation supporting a single source. Similarly, element contents of Units K1 and K2 feed coals show more variability than those of Unit I1. Fly ash samples from Units K1 and K2 consist mostly of glass, mullite, quartz, and spines group minerals. Minor amounts of illite/muscovite, sulfates, hematite, and corundum are also present. Spinel group minerals identified include magnetite, franklinite, magnesioferrite, trevorite, jacobisite, and zincochromite. Scanning Electron Microscope analysis reveals that most of the spinel minerals are dendritic intergrowths within aluminum silicate glass. Unit I1 fly ash samples contain glass, quartz, perovskite, lime, gehlenite, and apatite with minor amounts of periclase, anhydrite, carbonates, pyroxenes, and spinels. The abundant Ca mineral phases in the Unit I1 fly ashes are attributed to the presence of carbonate, clay and phosphate minerals in the coal.

  16. Upgraded Coal Interest Group

    SciTech Connect (OSTI)

    Evan Hughes

    2009-01-08T23:59:59.000Z

    The Upgraded Coal Interest Group (UCIG) is an EPRI 'users group' that focuses on clean, low-cost options for coal-based power generation. The UCIG covers topics that involve (1) pre-combustion processes, (2) co-firing systems and fuels, and (3) reburn using coal-derived or biomass-derived fuels. The UCIG mission is to preserve and expand the economic use of coal for energy. By reducing the fuel costs and environmental impacts of coal-fired power generation, existing units become more cost effective and thus new units utilizing advanced combustion technologies are more likely to be coal-fired.

  17. Utilization ROLE OF COAL COMBUSTION

    E-Print Network [OSTI]

    Wisconsin-Milwaukee, University of

    , materials left after combustion of coal in conventional and/ or advanced clean-coal technology combustors and advanced clean-coal technology combustors. This paper describes various coal combustion products produced (FGD) products from pulverized coal and advanced clean-coal technology combustors. Over 70% of the CCPs

  18. CO2 SEQUESTRATION POTENTIAL OF TEXAS LOW-RANK COALS

    SciTech Connect (OSTI)

    Duane A. McVay; Walter B. Ayers, Jr.; Jerry L. Jensen

    2004-07-01T23:59:59.000Z

    The objectives of this project are to evaluate the feasibility of carbon dioxide (CO{sub 2}) sequestration in Texas low-rank coals and to determine the potential for enhanced coalbed methane (CBM) recovery as an added benefit of sequestration. The main tasks for this reporting period were to correlate well logs and refine coal property maps, evaluate methane content and gas composition of Wilcox Group coals, and initiate discussions concerning collection of additional, essential data with Anadarko. To assess the volume of CO{sub 2} that may be sequestered and volume of methane that can be produced in the vicinity of the proposed Sam Seymour sequestration site, we used approximately 200 additional wells logs from Anadarko Petroleum Corp. to correlate and map coal properties of the 3 coal-bearing intervals of Wilcox group. Among the maps we are making are maps of the number of coal beds, number of coal beds greater than 5 ft thick, and cumulative coal thickness for each coal interval. This stratigraphic analysis validates the presence of abundant coal for CO{sub 2} sequestration in the Wilcox Group in the vicinity of Sam Seymour power plant. A typical wellbore in this region may penetrate 20 to 40 coal beds with cumulative coal thickness between 80 and 110 ft. Gas desorption analyses of approximately 75 coal samples from the 3 Wilcox coal intervals indicate that average methane content of Wilcox coals in this area ranges between 216 and 276 scf/t, basinward of the freshwater boundary indicated on a regional hydrologic map. Vitrinite reflectance data indicate that Wilcox coals are thermally immature for gas generation in this area. Minor amounts of biogenic gas may be present, basinward of the freshwater line, but we infer that most of the Wilcox coalbed gas in the deep coal beds is migrated thermogenic gas. Analysis based on limited data suggest that sites for CO{sub 2} sequestration and enhanced coalbed gas recovery should be located basinward of the Wilcox freshwater contour, where methane content is high and the freshwater aquifer can be avoided.

  19. Low-rank coal research. Quarterly report, January--March 1990

    SciTech Connect (OSTI)

    Not Available

    1990-08-01T23:59:59.000Z

    This document contains several quarterly progress reports for low-rank coal research that was performed from January-March 1990. Reports in Control Technology and Coal Preparation Research are in Flue Gas Cleanup, Waste Management, and Regional Energy Policy Program for the Northern Great Plains. Reports in Advanced Research and Technology Development are presented in Turbine Combustion Phenomena, Combustion Inorganic Transformation (two sections), Liquefaction Reactivity of Low-Rank Coals, Gasification Ash and Slag Characterization, and Coal Science. Reports in Combustion Research cover Fluidized-Bed Combustion, Beneficiation of Low-Rank Coals, Combustion Characterization of Low-Rank Coal Fuels, Diesel Utilization of Low-Rank Coals, and Produce and Characterize HWD (hot-water drying) Fuels for Heat Engine Applications. Liquefaction Research is reported in Low-Rank Coal Direct Liquefaction. Gasification Research progress is discussed for Production of Hydrogen and By-Products from Coal and for Chemistry of Sulfur Removal in Mild Gas.

  20. Synergistic Effect of coal blends on thermoplasticity evaluated using a temperature-variable dynamic viscoelastic measurement

    SciTech Connect (OSTI)

    Toshimasa Takanohashi; Takahiro Shishido; Ikuo Saito; Kensuke Masaki; Atsushi Dobashi; Kiyoshi Fukada [National Institute of Advanced Industrial Science and Technology, Tsukuba (Japan)

    2006-12-15T23:59:59.000Z

    To maximize the conversion of low-quality coal into good coke, we investigated the thermoplasticity of various binary blends of caking coals with slightly or noncaking coals using a dynamic viscoelastic technique with a temperature-variable rheometer. Coal blend samples were prepared by mixing two coals (1:1 by weight), which were heated from room temperature to 600 C at a rate of 3-80{sup o}C/min. At the slow rate of 3{sup o}C/min, the blends had a tan {delta} that was generally lower than the calculated value, showing that a negative interaction caused a loss of thermoplasticity. In contrast, at the rapid heating rate of 80{sup o}C/min, the tan {delta} of some blends was higher than the calculated value, indicating a positive interaction that enhanced the thermoplasticity. With rapid heating, the thermoplasticity of each coal itself increased, and their thermoplastic temperature ranges widened with rapid heating. Therefore, rapid heating was effective at converting these coal blends into good cokes. Moreover, even with slow heating, when a combination of coals (Gregory:Enshu, 1:1) showing some thermoplasticity in nearly the same temperature range was blended, a desirable synergistic effect of the blend was obtained. This suggests that blending coal with an overlapping thermoplastic temperature range is important for the synergistic effect, regardless of the heating rate. 15 refs., 9 figs., 2 tabs.

  1. Microbial solubilization of coal

    DOE Patents [OSTI]

    Strandberg, Gerald W. (Farragut, TN); Lewis, Susan N. (Knoxville, TN)

    1990-01-01T23:59:59.000Z

    This invention deals with the solubilization of coal using species of Streptomyces. Also disclosed is an extracellular component from a species of Streptomyces, said component being able to solubilize coal.

  2. The status of coal briquetting technology in Korea

    SciTech Connect (OSTI)

    Choi, Woo-Zin

    1993-12-31T23:59:59.000Z

    Anthracite is the only indigenous fossil fuel resource produced in Korea and is an important main source of residential fuel. Due to its particular characteristics, the best way to use Korean coal is in the form of briquettes, called {open_quotes}Yontan.{close_quotes} The ability to use this coal as briquettes was a great discovery made nearly 50 years ago and since then, has made a great contribution to the energy consumption of low and middle income households. Korean anthracite in coal briquette form has been used widely for household heating purposes. Collieries in Korea produced no more than one million tons of anthracite annually in the 1960s. Production, however, increased substantially up to about 17 million tons per year in the mid-1970s. In 1986, Korea succeeded in raising its coal production to 24.2 million tons, which was the maximum production level achieved by the Korean coal industrial sector. Since then, anthracite production has fallen. In 1991, coal output dropped to 15.1 million tons, a decrease of 12.2 percent from the 17.2 million tons produced in 1990, due to falling coal demand and rising labor costs. The role of coal as an energy source will be more important in the future to meet projected economic growth in Korea. While the production of indigenous Korean anthracite is expected to decrease under a coal mining rationalization policy, imports of bituminous coal will increase rapidly and will be used as an oil substitute in industry and power generation. In this chapter, general aspects of the Korean coal industry and coal utilization for residential uses, especially the Yontan coal briquetting techniques, are discussed. In addition, coal briquetting technology applications suitable for the APEC region will be presented.

  3. Research on thermophoretic and inertial aspects of ash particle deposition on heat exchanger surfaces in coal-fired equipment. Quarterly techical report, December 1, 1986--February 28, 1987

    SciTech Connect (OSTI)

    Rosner, D.E.

    1987-03-01T23:59:59.000Z

    In support of the above mentioned objectives, we are carrying out theoretical studies in the following three interrelated areas: (a) Interaction of inertial- and thermophoretic effects in well-defined laminar ``dusty-gas`` flows; (b) Self-regulated sticking and deposit erosion in the simultaneous presence of vapor or submicron ``glue``; (c) Use of packed bed and tube-bank heat transfer and friction correlations to provide the basis for future tube-bank fouling predictions. During this second quarter of Grant DE-FG22-86 PC 90756. we have: (1) done preliminary gas velocity and temperature calibrations of the micro-combustor exit gas flow jet and initiated the development of both a monodispersed droplet feed system and powder feed system to provide monodispersed particle laden jets covering a broad spectrum of particle sizes (ca. 0.5--50 m diameter); and, (2) demonstrated the ability of impacting supermicron particles to remove predeposited submicron particles on a platinum target, using real-time optical reflectivity methods. These preliminary experiments will be extended and discussed in our next Quarterly Technical Report.

  4. Autothermal coal gasification

    SciTech Connect (OSTI)

    Konkol. W.; Ruprecht, P.; Cornils, B.; Duerrfeld, R.; Langhoff, J.

    1982-03-01T23:59:59.000Z

    Test data from the Ruhrchemie/Ruhrkohle Texaco coal gasification demonstration plant at Oberhausen are reported. (5 refs.)

  5. Simultaneous upgrading of tar sand bitumen and coal by corefining

    SciTech Connect (OSTI)

    Hsich, C.R.; Donaldson, W.I.

    1988-08-16T23:59:59.000Z

    A continuous process is described for simultaneously corefining a mixture of comminuted coal and tar sand bitumen to form a liquid refinery feed stock, having improved hydrocarbon content and viscosity and reduced organo-metallic and metal components, which process comprises: (a) combining bitumen substantially separated from tar sands with comminuted raw coal at a coal to liquid weight ratio of from about 1:2 to about 1 to 50 to form a slurry mixture; (b) subjecting the slurry mixture resulting from step (a) to hydrocracking conditions in the absence of added catalyst to produce off-gases and a mixture of co-refined bitumen and coal liquid and coal ash residues; and (c) recovering the corefined improve coal-bitumen liquid as a refinery feedstock.

  6. Wabash River coal gasification repowering project: Public design report

    SciTech Connect (OSTI)

    NONE

    1995-07-01T23:59:59.000Z

    The Wabash River Coal Gasification Repowering Project (the Project), conceived in October of 1990 and selected by the US Department of Energy as a Clean Coal IV demonstration project in September 1991, is expected to begin commercial operations in August of 1995. The Participants, Destec Energy, Inc., (Destec) of Houston, Texas and PSI Energy, Inc., (PSI) of Plainfield, Indiana, formed the Wabash River Coal Gasification Repowering Project Joint Venture (the JV) to participate in the DOE`s Clean Coal Technology (CCT) program by demonstrating the coal gasification repowering of an existing 1950`s vintage generating unit affected by the Clean Air Act Amendments (CAAA). The Participants, acting through the JV, signed the Cooperative Agreement with the DOE in July 1992. The Participants jointly developed, and separately designed, constructed, own, and will operate an integrated coal gasification combined cycle (CGCC) power plant using Destec`s coal gasification technology to repower Unit {number_sign}1 at PSI`s Wabash River Generating Station located in Terre Haute, Indiana. PSI is responsible for the new power generation facilities and modification of the existing unit, while Destec is responsible for the coal gasification plant. The Project demonstrates integration of the pre-existing steam turbine generator, auxiliaries, and coal handling facilities with a new combustion turbine generator/heat recovery steam generator tandem and the coal gasification facilities.

  7. Effects of structural rearrangements on sorption capacity of coals

    SciTech Connect (OSTI)

    Romanov, Vyacheslav; Soong, Yee; Warzinski, R.P.; Lynn, R.J.

    2006-09-01T23:59:59.000Z

    Recently, the problems in practical application of experimental data and modeling to the sequestration of carbon dioxide in coal seams and the concurrent enhanced coalbed methane (ECBM) recovery have underscored the need for new approaches that take into account the ability of coal for structural rearrangements. Areas of interest include plasticization of coal due to CO2 dissolution, the effect of coal swelling on estimation of the capacity of a coal-seam to adsorb CO2 (adsorption isotherm), and the stability of the CO2 saturated phase once formed, especially with respect to how it might be affected by changes in the post-sequestration environment (environmental effects). Coals are organic macromolecular systems well known to imbibe organic liquids and carbon dioxide. CO2 dissolves in coals and swells them. The problems become more prominent in the region of supercritical CO2. We investigated the effects of moisture content and pressure cycling history on temporal changes in the coal sorptive capacity for a set of Argonne premium coals. The samples were tested as received, dried at 80oC for 36 hours, and moisture equilibrated at 96-97% RH and 30oC for 48 hours. The powders were compared to core samples. Additionally, plasticization of coal powders was studied by high pressure dilatometer.

  8. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    Coal Prices..AEO 2007 forecast for coal prices for PRB coal. Transmissionregimes. Sensitivity to Coal Prices Figure 9 is similar to

  9. Coal recovery process

    DOE Patents [OSTI]

    Good, Robert J. (Grand Island, NY); Badgujar, Mohan (Williamsville, NY)

    1992-01-01T23:59:59.000Z

    A method for the beneficiation of coal by selective agglomeration and the beneficiated coal product thereof is disclosed wherein coal, comprising impurities, is comminuted to a particle size sufficient to allow impurities contained therein to disperse in water, an aqueous slurry is formed with the comminuted coal particles, treated with a compound, such as a polysaccharide and/or disaccharide, to increase the relative hydrophilicity of hydrophilic components, and thereafter the slurry is treated with sufficient liquid agglomerant to form a coagulum comprising reduced impurity coal.

  10. The environment of deposition of the Dalton Coal (Upper Pennsylvanian), Palo Pinto Co., TX.

    E-Print Network [OSTI]

    Lowenstein, Glenn Robert

    1986-01-01T23:59:59.000Z

    , dried them in an oven, and picked the fossils out of the residue under a binocular scope. Or. Thomas Yancey assisted in the identification. Coal balls and concretions - Coal balls are thought to preserve the original texture, detrital mineral... kane content. Three of the samples were sent to Core Lab to determine the B. T. U. , ash, and sulfur content of the coal. I analyzed the remaining twenty- one samples with the use of the Oceanography department's Leco Combustion Furnace...

  11. Combined Heat and Power: Expanding CHP in Your State

    Broader source: Energy.gov (indexed) [DOE]

    Turbines Electricity On-Site Consumption Sold to Utility Fuel Natural Gas Propane Biogas Landfill Gas Coal Steam Waste Products Others Generator Heat Exchanger Thermal Process...

  12. Combined Heat & Power Technology Overview and Federal Sector...

    Broader source: Energy.gov (indexed) [DOE]

    Fuel Cells Electricity On-Site Consumption Sold to Utility Fuel Natural Gas Propane Biogas Landfill Gas Coal Steam Waste Products Others Generator Heat Exchanger Thermal Steam...

  13. Coal: the new black

    SciTech Connect (OSTI)

    Tullo, A.H.; Tremblay, J.-F.

    2008-03-15T23:59:59.000Z

    Long eclipsed by oil and natural gas as a raw material for high-volume chemicals, coal is making a comeback, with oil priced at more than $100 per barrel. It is relatively cheap feedstock for chemicals such as methanol and China is building plants to convert coal to polyolefins on a large scale and interest is spreading worldwide. Over the years several companies in the US and China have made fertilizers via the gasification of coal. Eastman in Tennessee gasifies coal to make methanol which is then converted to acetic acid, acetic anhydride and acetate fiber. The future vision is to convert methanol to olefins. UOP and Lurgi are the major vendors of this technology. These companies are the respective chemical engineering arms of Honeywell and Air Liquide. The article reports developments in China, USA and India on coal-to-chemicals via coal gasification or coal liquefaction. 2 figs., 2 photo.

  14. Opportunities for coal to methanol conversion

    SciTech Connect (OSTI)

    Not Available

    1980-04-01T23:59:59.000Z

    The accumulations of mining residues in the anthracite coal regions of Pennsylvania offer a unique opportunity to convert the coal content into methanol that could be utilized in that area as an alternative to gasoline or to extend the supplies through blending. Additional demand may develop through the requirements of public utility gas turbines located in that region. The cost to run this refuse through coal preparation plants may result in a clean coal at about $17.00 per ton. After gasification and synthesis in a 5000 ton per day facility, a cost of methanol of approximately $3.84 per million Btu is obtained using utility financing. If the coal is to be brought in by truck or rail from a distance of approximately 60 miles, the cost of methanol would range between $4.64 and $5.50 per million Btu depending upon the mode of transportation. The distribution costs to move the methanol from the synthesis plant to the pump could add, at a minimum, $2.36 per million Btu to the cost. In total, the delivered cost at the pump for methanol produced from coal mining wastes could range between $6.20 and $7.86 per million Btu.

  15. Low rank coal upgrading in a flow of hot water

    SciTech Connect (OSTI)

    Masato Morimoto; Hiroyuki Nakagawa; Kouichi Miura [Kyoto University, Kyoto (Japan). Department of Chemical Engineering

    2009-09-15T23:59:59.000Z

    Simultaneous hydrothermal degradation and extraction at around 350{sup o}C using flowing solvent as a reaction/extraction medium were proposed for upgrading brown coal, more specifically, for converting brown coal into several fractions having different molecular weight and chemical structure under mild conditions. When an Australian brown coal, Loy Yang coal, was treated by water at 350{sup o}C under 18 MPa, the coal was separated into four fractions: gaseous product by 8% yield, water-soluble extract at room temperature (soluble) by 23% yield, extract precipitates as solid at room temperature (deposit) by 23% yield, and residual coal (upgraded coal) by 46% yield on daf basis. The separation was found to be realized by in situ extraction of low-molecular-weight substances released from coal macromolecular structure and/or those generated by hydrothermal decomposition reactions at 350{sup o}C. The solid products obtained, deposit and upgraded coal, were characterized in detail to examine the possibility of their effective utilization as solid fuel and chemical feed stock. The upgraded coal showed higher heating value and higher gasification reactivity than the parent coal, indicating that the upgraded coal can be a better solid fuel than the parent coal. The solid extract, deposit, was found to show thermoplasticity at less than 200{sup o}C, suggesting the possibility of utilizing the deposit as a raw material of high performance carbon materials. Several variables affecting the performance of the proposed method are also examined in detail in this paper. 12 refs., 8 figs., 3 tabs.

  16. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul Aug SepAnnual",2013Annual",2014 ,"ReleaseAnnual",2014Bcf)"ImportsDeliveries to ConsumersHeat Content

  17. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul Aug SepAnnual",2013Annual",2014 ,"ReleaseAnnual",2014Bcf)"ImportsDeliveries toHeat Content of Natural

  18. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul Aug SepAnnual",2013Annual",2014 ,"ReleaseAnnual",2014Bcf)"ImportsDeliveries toHeat Content of

  19. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul Aug SepAnnual",2013Annual",2014 ,"ReleaseAnnual",2014Bcf)"ImportsDeliveries toHeat Content

  20. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul Aug SepAnnual",2013Annual",2014 ,"ReleaseAnnual",2014Bcf)"ImportsDeliveriesHeat Content of Natural Gas

  1. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul Aug SepAnnual",2013Annual",2014 ,"ReleaseAnnual",2014Bcf)"ImportsDeliveriesHeat Content of Natural

  2. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul Aug SepAnnual",2013Annual",2014 ,"ReleaseAnnual",2014Bcf)"ImportsDeliveriesHeat Content of

  3. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul Aug SepAnnual",2013Annual",2014 ,"ReleaseAnnual",2014Bcf)"ImportsDeliveriesHeat Content

  4. Waste Heat Recovery

    Office of Environmental Management (EM)

    DRAFT - PRE-DECISIONAL - DRAFT 1 Waste Heat Recovery 1 Technology Assessment 2 Contents 3 1. Introduction to the TechnologySystem ......

  5. Slurry atomizer for a coal-feeder and dryer used to provide coal at gasifier pressure

    DOE Patents [OSTI]

    Loth, John L. (Morgantown, WV); Smith, William C. (Morgantown, WV); Friggens, Gary R. (Morgantown, WV)

    1982-01-01T23:59:59.000Z

    The present invention is directed to a coal-water slurry atomizer for use a high-pressure dryer employed in a pumping system utilized to feed coal into a pressurized coal gasifier. The slurry atomizer is provided with a venturi, constant area slurry injection conduit, and a plurality of tangentially disposed steam injection ports. Superheated steam is injected into the atomizer through these ports to provide a vortical flow of the steam, which, in turn, shears slurry emerging from the slurry injection conduit. The droplets of slurry are rapidly dispersed in the dryer through the venturi where the water is vaporized from the slurry by the steam prior to deleterious heating of the coal.

  6. Apparatus for solar coal gasification

    DOE Patents [OSTI]

    Gregg, D.W.

    1980-08-04T23:59:59.000Z

    Apparatus for using focused solar radiation to gasify coal and other carbonaceous materials is described. Incident solar radiation is focused from an array of heliostats through a window onto the surface of a moving bed of coal, contained within a gasification reactor. The reactor is designed to minimize contact between the window and solids in the reactor. Steam introduced into the gasification reactor reacts with the heated coal to produce gas consisting mainly of carbon monoxide and hydrogen, commonly called synthesis gas, which can be converted to methane, methanol, gasoline, and other useful products. One of the novel features of the invention is the generation of process steam in one embodiment at the rear surface of a secondary mirror used to redirect the focused sunlight. Another novel feature of the invention is the location and arrangement of the array of mirrors on an inclined surface (e.g., a hillside) to provide for direct optical communication of said mirrors and the carbonaceous feed without a secondary redirecting mirror.

  7. Petrology of Jurassic (Kimmeridgian) coals, Atlantic Continental Shelf, New Jersey

    SciTech Connect (OSTI)

    Hower, J.C.; Wild, G.D. (Univ. of Kentucky, Lexington, KY (United States))

    1993-08-01T23:59:59.000Z

    Ten coals of Kimmeridgian age were recovered from the COST B-3 borehole, offshore New Jersey. Separation of the coal from other cuttings was done at 1.8 specific gravity, meaning that partings and mineral-rich lithotypes were lost in processing. The coals are distributed over an interval of 3.49 to 3.93 km depth. Coal rank, by vitrinite maximum reflectance, spans the lower portion of the high volatile A bituminous range. A single Cretaceous coal with 0.32%R[sub max] occurs at 2.08 km depth. Vitrinite content ranges from 51 to over 90% with vitrinite content generally increasing upward in the section. Telinite with resinite cell fillings is an important vitrinite form. Resinite occurs in concentrations of up to 9% in the Jurassic coals and is nearly 12% in the Cretaceous lignite. Fusinite plus semifusinite ranges from 2 to 31%. Inertinite occurs in a wide variety of forms from low-reflectance semifusinite to massive, structureless fusinite. Inertodetrinite also is a component of the abundant detrital bands of some of the Jurassic coals. The gravity separation did not eliminate all mineral matter. Massive pyrite and marcasite occur in several coals and clay occurs with the detrital minerals.

  8. Coal-bench architecture as a means of understanding regional changes in coal thickness and quality

    SciTech Connect (OSTI)

    Greb, S.F.; Eble, C.F. [Kentucy Geological Survey, Lexington, KY (United States); Hower, J.C. [Center for Applied Research, Lexington, KY (United States)

    1996-09-01T23:59:59.000Z

    Analysis of the Fire Creek (Westphalian B), Pond Creek (lower Westphalian B), and Stockton (Westphalian B) coals, three of the most heavily mined coals in the Central Appalachian Basin, shows that all have a similar multiple-bench architecture of at least two benches split by a regional clastic parting or durain. Coal benches beneath regionally extensive partings are generally less continuous, thinner, more palynologically variable, higher in ash yield, and higher in sulfur content than coal benches above regional partings in all three coals. Where thick, benches above regional partings tend to exhibit temporal palynological changes from lycopod- to fern-dominant. Where inertinite-rich/fern-dominant benches are overlain by additional benches, the upper benches are limited in extent, variable in thickness, high in sulfur content and ash yield, and split away from the coal. The multiple-bench architecture exhibited by these coals is interpreted to represent a cyclic mire succession that was common in the Middle Pennsylvanian. Peats began as planar mires infilling an irregular topography during rising base level. When the topography was infilled, unconfined flooding was possible and resulted in widespread partings. Ponding above these clay-rich flood deposits led to re-establishment of new planar mires with greater continuity than the underlying mires. The extent of these mires provided buffers to clastic influx and, in many cases, allowed domed conditions to develop. Doming resulted in thick, high-quality coal benches. In some cases, a third stage of planar peats, with similar characteristics to the planar peats at the base of the beds, developed on the unevenly distributed clastics that buried underlying mires during continued base-level rise.

  9. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    Council (NCC), 2006, “Coal: America’s Energy Future”, VolumeAssessments to Inform Energy Policy, “Coal: Research andOF RAIL TRANSPORTATION OF COAL The Federal Energy Regulatory

  10. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    OF RAIL TRANSPORTATION OF COAL The Federal Energy RegulatoryPlants Due to Coal Shortages”, Federal Energy RegulatoryCouncil (NCC), 2006, “Coal: America’s Energy Future”, Volume

  11. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    of total electricity generation is because coal plants haveplants come to play an important role in the electricity generationplants will be built in the years around 2020, thereby increasing coal’s share of electricity generation

  12. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    a particular type of coal, each of which is inherentlyThere are four classes of coal: bituminous, sub-bituminous,minerals Metallic ores Coal Crude petroleum Gasoline Fuel

  13. CO2 Sequestration Potential of Texas Low-Rank Coals

    SciTech Connect (OSTI)

    Duane A. McVay; Walter B. Ayers, Jr.; Jerry L. Jensen

    2004-04-01T23:59:59.000Z

    The objectives of this project are to evaluate the feasibility of carbon dioxide (CO{sub 2}) sequestration in Texas low-rank coals and to determine the potential for enhanced coalbed methane (CBM) recovery as an added benefit of sequestration. The primary objectives for this reporting period were to construct a coal geological model for reservoir analysis and to continue acquisition of data pertinent to coal characterization that would help in determining the feasibility of carbon dioxide sequestration. Structural analysis and detailed correlation of coal zones are important for reservoir analysis and modeling. Evaluation of existing well logs indicates local structural complexity that complicates interpretations of continuity of the Wilcox Group coal zones. Therefore, we have begun searching for published structural maps for the areas of potential injection CO{sub 2}, near the coal-fired power plants. Preliminary evaluations of data received from Anadarko Petroleum Corporation suggest that coal properties and gas content and chemical composition vary greatly among coal seams. We are assessing the stratigraphic and geographic distributions and the weight of coal samples that Anadarko has provided to select samples for further laboratory analysis. Our goal is to perform additional isotherm analyses with various pure and/or mixed gases to enhance our characterization model. Additionally, we are evaluating opportunities for field determination of permeability with Anadarko, utilizing one of their wells.

  14. X-ray photoelectron emission spectromicroscopic analysis of arborescent lycopsid cell wall composition and Carboniferous coal ball preservation

    E-Print Network [OSTI]

    Boyce, C. Kevin

    composition and Carboniferous coal ball preservation C. Kevin Boyce a, , Mike Abrecht b , Dong Zhou b , P that were canopy dominants of many Pennsylvanian coal swamp forests. Its periderm or bark--the single greatest biomass contributor to many Late Paleozoic coals--is found to have a greater aliphatic content

  15. Pulverized coal fuel injector

    DOE Patents [OSTI]

    Rini, Michael J. (Hebron, CT); Towle, David P. (Windsor, CT)

    1992-01-01T23:59:59.000Z

    A pulverized coal fuel injector contains an acceleration section to improve the uniformity of a coal-air mixture to be burned. An integral splitter is provided which divides the coal-air mixture into a number separate streams or jets, and a center body directs the streams at a controlled angle into the primary zone of a burner. The injector provides for flame shaping and the control of NO/NO.sub.2 formation.

  16. Task II: evaluation of heat-exchanger and turbine materials for use in a coal-fired fluidized-bed-combustion environment. Final report, July 1, 1976-July 31, 1980

    SciTech Connect (OSTI)

    Not Available

    1981-09-30T23:59:59.000Z

    Specific alloys were tested as in-bed and above-bed heat exchanger materials in the fireside environment of a pressurized fluidized bed coal combustor (PFBCC). Corrosion conditions on the alloys exposed to normal and very low oxygen pressures in the presence of calcium sulfate deposits were simulated. Bayonet-type specimen probes of selected alloys were exposed in the Exxon Miniplant at probe control temperatures representative of conventional steam, advanced steam, helium and liquid metal energy conversion cycles. Corrosion/erosion testing of the air cooled, welded samples consisted of a 117-hour shakedown run followed by an incremental 1000-hour exposure. Metallurgical analyses were run on removed specimens. The test matrix for in-bed and above-bed exposure was: 1050/sup 0/F (566/sup 0/C): 2.25 Cr-1Mo and 9Cr-1Mo steels (in-bed only); 1200/sup 0/F (649/sup 0/C): 304 SS and Incoloy-800; 1400/sup 0/F (760/sup 0/C): Incoloy-800 and Hastelloy-X; and 1600/sup 0/F (871/sup 0/C); Hastelloy-X and Haynes-188. Subscale sulfides formed in most of the alloys. The most severe corrosion was noted in the ferritic 2.25Cr-1Mo and 9Cr-1Mo steels at a nominal control temperature of 1050/sup 0/F (566/sup 0/C) and in Hastelloy-X at 1400/sup 0/F (760/sup 0/C) exposed in-bed. The best overall behavior of in-bed alloys was observed for Incoloy-800, which had a maximum metal loss of about .007 in (.18 mm) in 1117 hours of exposure at both 1200/sup 0/F (649/sup 0/C) and 1400/sup 0/F (760/sup 0/C) but averaged more nearly .001 in (.025 mm) to .002 in (.051 mm) and in Haynes-188 which showed maximum wall thinning of less than .003 in (.076 mm) at 1600/sup 0/F (871/sup 0/C) in the longest time exposure.

  17. Process for fixed bed coal gasification

    DOE Patents [OSTI]

    Sadowski, Richard S. (Greenville, SC)

    1992-01-01T23:59:59.000Z

    The combustion of gas produced from the combination of coal pyrolysis and gasification involves combining a combustible gas coal and an oxidant in a pyrolysis chamber and heating the components to a temperature of at least 1600.degree. F. The products of coal pyrolysis are dispersed from the pyrolyzer directly into the high temperature gasification region of a pressure vessel. Steam and air needed for gasification are introduced in the pressure vessel and the materials exiting the pyrolyzer flow down through the pressure vessel by gravity with sufficient residence time to allow any carbon to form carbon monoxide. Gas produced from these reactions are then released from the pressure vessel and ash is disposed of.

  18. Future Impacts of Coal Distribution Constraints on Coal Cost

    E-Print Network [OSTI]

    McCollum, David L

    2007-01-01T23:59:59.000Z

    coal (PC) or integrated gasification combined cycle ( IGCC)coal (PC) or integrated gasification combined cycle (IGCC)will be integrated gasification combined cycle (IGCC) (Same

  19. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    Credit Extra Fuel Oil Coal to gasifier Na cost· Na processoiL Replace res. with coal as gasifier feed. 543 ton/day @$

  20. Coal Mining Tax Credit (Arkansas)

    Broader source: Energy.gov [DOE]

    The Coal Mining Tax Credit provides an income or insurance premium tax credit of $2.00 per ton of coal mined, produced or extracted on each ton of coal mined in Arkansas in a tax year. An...

  1. Illinois Coal Revival Program (Illinois)

    Broader source: Energy.gov [DOE]

    The Illinois Coal Revival Program is a grants program providing partial funding to assist with the development of new, coal-fueled electric generation capacity and coal gasification or IGCC units...

  2. COAL DESULFURIZATION PRIOR TO COMBUSTION

    E-Print Network [OSTI]

    Wrathall, J.

    2013-01-01T23:59:59.000Z

    Corporation, 5-25~79. on Coal Liquefaction at ChevronHamersma, et a L, "Meyers Process for Coal Desulfurization,"in Wheelock, Coal Desulfurization, ACS Symp. Ser 64 (1977(.

  3. Small-scale circulating fluidized bed combustor (CFBC) system for heat and power in remote areas

    SciTech Connect (OSTI)

    Stuart, J.M.; Korenberg, J. [DONLEE Technologies Inc., York, PA (United States)

    1995-12-31T23:59:59.000Z

    Demand for heating and electric power has steadily increased in remote areas. The use of locally available fuel to achieve self sufficiency has become an important objective. Energy demands may require steam generation for district heating, power generation and process consumption. In addition, the steam generation unit can also be required to burn waste that includes MSW and sewage sludge. To meet these demands, new systems must be installed that use local fuel. This paper describes a lower cost CFBC for use in remote areas. With the support of DOE METC, in late summer 1994, DONLEE performed a test burn at its 10 MM btu/hr pilot CFBC using subbituminous coal from Wyoming. The Wyoming coal`s sulfur dioxide emissions were very low due to the low sulfur content of the Wyoming coal and the excellent efficiency at temperatures as low as 1,500 F thereby indicating no limestone addition was needed for sulfur capture. The CFBC testing indicated emissions met all of the environmental requirements, both Federal and state. These requirements include: particulates, SO{sub 2}, CO, NO{sub x}, opacity, chlorinated dioxins/furans, etc. The unit can be fabricated in modules, making the installation easier and less expensive for use in remote areas. The design is highly reliable and can be fully automated thereby requiring limited staffing.

  4. US coal market softens

    SciTech Connect (OSTI)

    Fiscor, S.

    2007-01-15T23:59:59.000Z

    The operators table some near term expansion plans, meanwhile long-term fundamentals look strong. This is one of the findings of the Coal Age Forecast 2007 survey of readers predictions on production and consumption of coal and attitudes in the coal industry. 50% of respondents expected product levels in 2007 to be higher than in 2006 and 50% described the attitude in the coal industry to be more optimistic in 2007 than in 2006. Most expenditure is anticipated on going on new equipment but levels of expenditure will be less than in 2006. 7 figs.

  5. Coal Gasification Systems Solicitations

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Low Cost Coal Conversion to High Hydrogen Syngas; FE0023577 Alstom's Limestone Chemical Looping Gasification Process for High Hydrogen Syngas Generation; FE0023497 OTM-Enhanced...

  6. Coal extraction process

    SciTech Connect (OSTI)

    Hammack, R. W.; Sears, J. T.; Stiller, A. H.

    1981-06-09T23:59:59.000Z

    Sub-divided coal is extracted under non-thermally destructive conditions with a solvent liquid containing a compound having the general formula:

  7. Clean Coal Projects (Virginia)

    Broader source: Energy.gov [DOE]

    This legislation directs the Virginia Air Pollution Control Board to facilitate the construction and implementation of clean coal projects by expediting the permitting process for such projects.

  8. Coal Mining Regulations (Kentucky)

    Broader source: Energy.gov [DOE]

    Kentucky Administrative Regulation Title 405 chapters 1, 2, 3, 5, 7, 8, 10, 12, 16, 18 and 20 establish the laws governing coal mining in the state.

  9. Coal Development (Nebraska)

    Broader source: Energy.gov [DOE]

    This section provides for the development of newly-discovered coal veins in the state, and county aid for such development.

  10. Thermophysical properties of coal liquids. Seventh quarterly technical status report, April 1-June 30, 1981

    SciTech Connect (OSTI)

    Droege, J. W.; Venkateswar, R.; Chauhan, S. P.

    1981-07-17T23:59:59.000Z

    Measurements of rheological properties have been continued. Measurements at relatively low temperature (450 K) showed that a coarser coal grind shows substantially lower viscosity. It was also shown that coal and solvent obtained from the Fort Lewis plant give slurries of much higher viscosity than slurries from our reference coal and solvent. At higher temperatures (540 K) substantially the same relationships were shown. The effect of solvent-to-coal ratio was also found to be very great. Differential scanning calorimetry gave some low reliability specific heat results and showed indication of a probable heat effect at about 500 K. No indication of exothermic reaction with hydrogen was found.

  11. Development of a Coal Quality Expert

    SciTech Connect (OSTI)

    None

    1998-06-20T23:59:59.000Z

    ABB Power Plant Laboratories Combustion Engineering, Inc., (ABB CE) and CQ Inc. completed a broad, comprehensive program to demonstrate the economic and environmental benefits of using higher quality U.S. coals for electrical power generation and developed state-of-the-art user-friendly software--Coal Quality Expert (CQE)-to reliably predict/estimate these benefits in a consistent manner. The program was an essential extension and integration of R and D projects performed in the past under U.S. DOE and EPRI sponsorship and it expanded the available database of coal quality and power plant performance information. This software will permit utilities to purchase the lowest cost clean coals tailored to their specific requirements. Based on common interest and mutual benefit, the subject program was cosponsored by the U.S. DOE, EPRI, and eight U.S. coal-burning utilities. In addition to cosponsoring this program, EPN contributed its background research, data, and computer models, and managed some other supporting contracts under the terms of a project agreement established between CQ Inc. and EPRI. The essential work of the proposed project was performed under separate contracts to CQ Inc. by Electric Power Technologies (El?'T), Black and Veatch (B and V), ABB Combustion Engineering, Babcock and Wilcox (B and W), and Decision Focus, Inc. Although a significant quantity of the coals tied in the United States are now cleaned to some degree before firing, for many of these coals the residual sulfur content requires users to install expensive sulfur removal systems and the residual ash causes boilers to operate inefficiently and to require frequent maintenance. Disposal of the large quantities of slag and ash at utility plant sites can also be problematic and expensive. Improved and advanced coal cleaning processes can reduce the sulfur content of many coals to levels conforming to environmental standards without requiring post-combustion desulfurization systems. Also, some coals may be beneficiated or blended to a quality level where significantly less costly desulfurization systems are needed. Coal cleaning processes may also be used to remove the precursors of other troublesome emissions that can be identified now or in the future. An added benefit of coal cleaning and blending is the reduction in concentrations of mineral impurities in the fuel leading to improved performance and operation of the'' boiler in which it is fired. The ash removed during the pre-combustion cleaning process can be more easily and safely disposed of at the mine than at the utility plant after combustion. EPRI's Coal Quality Impact Model (CQIM) has shown that improved fuel quality can result in savings in unit capital and operating costs. This project produced new and improved software to select coal types and specifications resulting in the best quality and lowest cost fuel to meet specific environmental requirements.

  12. Cooperative research program in coal liquefaction

    SciTech Connect (OSTI)

    Huffman, G.P. (ed.)

    1991-01-01T23:59:59.000Z

    This Quarterly Report on coal liquefaction research includes discussion in the areas of (1) Iron Based Catalysts for Coal Liquefaction; (2) Exploratory Research on Coal Conversion; (3) Novel Coal Liquefaction Concepts; (4) Novel Catalysts for Coal Liquefaction. (VC)

  13. Cooperative research program in coal liquefaction

    SciTech Connect (OSTI)

    Huffman, G.P. (ed.)

    1992-01-01T23:59:59.000Z

    Research continues on coal liquefaction in the following areas: (1) Iron Based Catalysts for Coal Liquefaction; (2) Exploratory Research on Coal Conversion; (3) Novel Coal Liquefaction Concepts; (4) Novel Catalysts for Coal Liquefaction. (VC)

  14. A study of ignition and combustion characteristics of isolated coal water slurry droplet using digital image processing technique

    E-Print Network [OSTI]

    Bhadra, Tanmoy

    1998-01-01T23:59:59.000Z

    at constant pressure Coal water slurry Diffusion coefficient (Damkohler number) Activation energy Higher heating value Gasification rate constant Flame lift off distance Mass of CWS drop Number of coal particles in a single CWS drop Prandtl number... Parameters. . . II. 2. Coal Ignition and Combustion . . 13 II. 2. 1. Introduction. II. 2. 2. Pyrolysis. . . . . . II. 2. 3. Volatiles Oxidation. . . 13 . . 15 . . 16 II. 2. 4. Ignition. II. 2. 5. Coal Combustion . . . . 16 . . 17 CHAPTER Page 11...

  15. Coprocessing of Highvale coal with Athabasca bitumen in syngas mixtures

    SciTech Connect (OSTI)

    Parker, R.J.; Clark, P.D.; Ignasiak, B.L.; Lee, T.; Ohuchi, T.

    1986-04-01T23:59:59.000Z

    Coprocessing of Alberta subbituminous coal with bitumen is currently under investigation at the Alberta Research Council. The high oxygen content of the coal results in high hydrogen consumption. The present study compares the effectiveness of syngas/water mixtures catalyzed by potassium carbonate for coprocessing Highvale coal with Athabasca bitumen. Single-stage (solubilization) experiments were performed with syngas (5.1 MPa) at 390/sup 0/C in a stirred autoclave. In simulated two-stage experiments, the second (upgrading) stage employed hydrogen (8.5 MPa) at 440/sup 0/C with a potassium molybdate/dimethyl disulphide catalyst. Coal conversion improved from 47 to 78% systematically when the carbon monoxide: hydrogen ratio was varied from 1:3 to 7:1. The additional yield was confined to pyridine extractable material. In simulated two-stage experiments similar coal conversions were observed when using carbon monoxide/water (91%) or hydrogen (88%) in the first stage.

  16. Coal-to-liquids bill introduced in the Senate

    SciTech Connect (OSTI)

    Buchsbaum, L.

    2006-06-15T23:59:59.000Z

    Of immense importance to the coal industry is the announcement, on 7 June 2006 by US Senators Barack Obama (D-IL) and Jim Bunning (R-KY) of S.3325, the 'Coal-to-Liquid Fund Promotion Act of 2006'. This legislation creates tax incentives for coal-to-liquids (CTL) technologies and construction of CTL plants. If passed, this will create the infrastructure needed to make CTL a viable energy resource throughout America. The article gives comment and background to this proposed legislation. Illinois Basin coal is well suited for CTL because of its high Btu content. If Sasol constructs a proposed plant in Illinois it would increase coal production in the state by 10 mt. 1 fig.

  17. Evolving performance characteristics of clean coal technologies

    SciTech Connect (OSTI)

    Miller, C.L.

    1993-12-31T23:59:59.000Z

    The United States Department of Energy (US DOE) Clean Coal Technology Demonstration Program (also referred to as the CCT Program) is a government and industry cofunded technology development effort to demonstrate a new generation of innovative coal utilization processes in a series of {open_quotes}semicommercial{close_quotes} facilities. These demonstrations are on a scale large enough to generate all the data, from design, construction, and operation, that are necessary for the private sector to judge commercial potential and make informed, confident decisions on commercial readiness. The projects in the program are demonstrating technologies that will encompass advanced electric power generation systems, high-performance pollution control devices, coal processing for clean fuels and industrial applications. The innovative CCTs being demonstrated offer tremendous potential as solutions to many complex problems in a rapidly changing arena dominated by energy, economic, and environmental issues. These issues include the following: air quality; global climate change; energy security; international competitiveness; acid rain; power production; and technology awareness. These technologies are expected to be of particular importance to the utility industry. Power production in the United States, particularly in the form of electricity, is expected to increase rapidly during the next 20 years. The growth in electricity consumption between 1990 and 2000 translates into the need for at least an additional 200,000 MWe of capacity by 2010. The ability to continue to use coal to produce electricity and as a source of industrial heat and power is critical. In the United States approximately 86 percent of coal is critical. The CCT Program is developing through demonstration new power and steam production systems using coal-based technologies that will permit coal to be a clean, efficient, reliable source of affordable energy.

  18. Illinois Coal Development Program (Illinois)

    Broader source: Energy.gov [DOE]

    The Illinois Coal Development Program seeks to advance promising clean coal technologies beyond research and towards commercialization. The program provides a 50/50 match with private industry...

  19. Geochemistry of coal from Cretaceous Corwin and Chandler formations, National Petroleum Reserve in Alaska (NPRA)

    SciTech Connect (OSTI)

    Affolter, R.H.; Stricker, G.D.

    1985-04-01T23:59:59.000Z

    Ninety coal samples from these formations within NPRA were collected and analyzed in order to evaluate coal quality and elemental distribution. Their apparent rank ranges from lignite A in the northern part of NPRA to high-volatile AS bituminous coal in the southern part. Mean vitrinite reflectance values range from 0.65 to 0.74%. Some Corwin Formation coal samples west of NPRA have coking potential with free-swelling indexes between 3.0 and 5.0. Compared to other western United States Cretaceous coal, NPRA coal is significantly lower in ash, volatile matter, O, Si, Al, Ca, Fe, Ti, Cu, F, Li, Mn, Mo, Pb, Sb, Se, Th, and Zn. Statistical comparisons of element concentrations indicate that the mean content of Si, Al, K, Li, Sc, Y, and Yb increases as the mean ash content increases (correlation coefficient at least 0.7). Sulfur values are extremely low (0.1%), and elements that normally show positive correlation with sulfur, such as Fe, As, Cd, Co, Cu, Mo, Pb, and Zn, are also low. Therefore, coal from NPRA can be characterized by low ash and sulfur contents and low contents of elements of environmental concern, such as As, Be, Hg, Mo, Sb, and Se. The elements found to have positive correlations with ash content are probably present as aluminosilicate or stable oxide minerals. Variations in element content and quality of NPRA coal were probably influenced by the geochemical conditions that existed in the Corwin and Umiat delta systems.

  20. Thermodynamics of the solvent swelling of coal

    SciTech Connect (OSTI)

    Green, T.K.

    1990-01-01T23:59:59.000Z

    Sorption of pyridine by the pyridine-extracts of three premium Argonne coals was studied at several relative vapor pressures at 50{degree}C and 70{degree}C. The amount of pyridine sorbed by each extract increases linearly with pyridine vapor pressure. Heat of dilution were calculated from the slopes of the straight-line portions of the curves. In a related experiment, the pyridine sorption isotherms of the pyridine-extract, pyridine-insoluble residue, and the whole coal were determined at 50{degree}C. For all materials, the amount of pyridine sorbed increases linearly with pressure of pyridine, with similar slopes. However, the intercepts are different for each material. Finally, the sorption of benzene vapors by O-alkylated Illinois {number sign}6 coals were studied at 30{degree}C. The rate of benzene sorption increases dramatically upon O-methylation, indicating that coal-coal hydrogen bonds play a dominant role in controlling the rate of benzene sorption. 2 refs., 3 figs., 1 tab.

  1. Development of an Ultra-fine Coal Dewatering Technology and an Integrated Flotation-Dewatering System for Coal Preparation Plants

    SciTech Connect (OSTI)

    Wu Zhang; David Yang; Amar Amarnath; Iftikhar Huq; Scott O'Brien; Jim Williams

    2006-12-22T23:59:59.000Z

    The project proposal was approved for only the phase I period. The goal for this Phase I project was to develop an industrial model that can perform continuous and efficient dewatering of fine coal slurries of the previous flotation process to fine coal cake of {approx}15% water content from 50-70%. The feasibility of this model should be demonstrated experimentally using a lab scale setup. The Phase I project was originally for one year, from May 2005 to May 2006. With DOE approval, the project was extended to Dec. 2006 without additional cost from DOE to accomplish the work. Water has been used in mining for a number of purposes such as a carrier, washing liquid, dust-catching media, fire-retardation media, temperature-control media, and solvent. When coal is cleaned in wet-processing circuits, waste streams containing water, fine coal, and noncombustible particles (ash-forming minerals) are produced. In many coal preparation plants, the fine waste stream is fed into a series of selection processes where fine coal particles are recovered from the mixture to form diluted coal fine slurries. A dewatering process is then needed to reduce the water content to about 15%-20% so that the product is marketable. However, in the dewatering process currently used in coal preparation plants, coal fines smaller than 45 micrometers are lost, and in many other plants, coal fines up to 100 micrometers are also wasted. These not-recovered coal fines are mixed with water and mineral particles of the similar particle size range and discharged to impoundment. The wasted water from coal preparation plants containing unrecoverable coal fine and mineral particles are called tailings. With time the amount of wastewater accumulates occupying vast land space while it appears as threat to the environment. This project developed a special extruder and demonstrated its application in solid-liquid separation of coal slurry, tailings containing coal fines mostly less than 50 micron. The extruder is special because all of its auger surface and the internal barrier surface are covered with the membranes allowing water to drain and solid particles retained. It is believed that there are four mechanisms working together in the dewatering process. They are hydrophilic diffusion flow, pressure flow, agitation and air purging. Hydrophilic diffusion flow is effective with hydrophilic membrane. Pressure flow is due to the difference of hydraulic pressure between the two sides of the membrane. Agitation is provided by the rotation of the auger. Purging is achieved with the air blow from the near bottom of the extruder, which is in vertical direction.

  2. Fine Anthracite Coal Washing Using Spirals

    SciTech Connect (OSTI)

    R.P. Killmeyer; P.H. Zandhuis; M.V. Ciocco; W. Weldon; T. West; D. Petrunak

    2001-05-31T23:59:59.000Z

    The spiral performed well in cleaning the coarse 8 x 16 mesh size fraction, as demonstrated by the Ep ranging from 0.091 to 0.177. This is in line with typical spiral performance. In addition, the presence of the coarser size fraction did not significantly affect spiral performance on the typical 16 x 100 mesh fraction, in which the Ep ranged from 0.144 to 0.250. Changes in solids concentration and flow rate did not show a clear correlation with spiral performance. However, for difficult-to-clean coals with high near-gravity material, such as this anthracite, a single-stage spiral cleaning such a wide size fraction may not be able to achieve the clean coal ash and yield specifications required. In the first place, while the performance of the spiral on the coarse 8 x 16 mesh fraction is good with regard to Ep, the cutpoints (SG50s) are high (1.87 to 1.92), which may result in a clean coal with a higher-than-desired ash content. And second, the combination of the spiral's higher overall cutpoint (1.80) with the high near-gravity anthracite results in significant misplaced material that increases the clean coal ash error. In a case such as this, one solution may be to reclean the clean coal and middlings from the first-stage spiral in a second stage spiral.

  3. Process for removal of hazardous air pollutants from coal

    DOE Patents [OSTI]

    Akers, David J. (Indiana, PA); Ekechukwu, Kenneth N. (Silver Spring, MD); Aluko, Mobolaji E. (Burtonsville, MD); Lebowitz, Howard E. (Mountain View, CA)

    2000-01-01T23:59:59.000Z

    An improved process for removing mercury and other trace elements from coal containing pyrite by forming a slurry of finely divided coal in a liquid solvent capable of forming ions or radicals having a tendency to react with constituents of pyrite or to attack the bond between pyrite and coal and/or to react with mercury to form mercury vapors, and heating the slurry in a closed container to a temperature of at least about 50.degree. C. to produce vapors of the solvent and withdrawing vapors including solvent and mercury-containing vapors from the closed container, then separating mercury from the vapors withdrawn.

  4. Method for coal liquefaction

    DOE Patents [OSTI]

    Wiser, Wendell H. (Kaysville, UT); Oblad, Alex G. (Salt Lake City, UT); Shabtai, Joseph S. (Salt Lake City, UT)

    1994-01-01T23:59:59.000Z

    A process is disclosed for coal liquefaction in which minute particles of coal in intimate contact with a hydrogenation catalyst and hydrogen arc reacted for a very short time at a temperature in excess of 400.degree. C. at a pressure of at least 1500 psi to yield over 50% liquids with a liquid to gaseous hydrocarbon ratio in excess of 8:1.

  5. Determining coal permeabilities through constant pressure production interference testing

    E-Print Network [OSTI]

    Schubarth, Stephen Kurt

    2012-06-07T23:59:59.000Z

    DETERMINING COAL PERMEABILITIES THROUGH CONSTANT PRESSURE PRODUCTION INTERFERENCE TESTING A Thesis by STEPHEN KURT SCHUBARTH Submitted to the Graduate College of Texas ASM University fn Partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE December 1983 Major Subject: Petroleum Engineering DETERMINING COAL PERMEABILITIES THROUGH CONSTANT PRESSURE PRODUCTION INTERFERENCE TESTING A Thesis by STEPHEN KURT SCHUBARTH Approved as to style and content by: tephen A. Hold...

  6. Coal in China

    SciTech Connect (OSTI)

    Minchener, A.J. [IEA Clean Coal Centre, London (United Kingdom)

    2005-07-01T23:59:59.000Z

    The article gives an overview of the production and use of coal in China, for power generation and in other sectors. Coal use for power generation was 850 million tonnes in 2003 and 800 million tonnes in the non-power sector. The majority of power will continue to be produced from coal, with a trend towards new larger pulverised coal fired units and introduction of circulating fluidised bed combustors. Stricter regulations are forcing introduction of improved pollution control technologies. It seems likely that China will need international finance to supplement private and state investment to carry out a programme to develop and apply clean coal technologies. The author concludes that there is evidence of a market economy being established but there is a need to resolve inconsistencies with the planned aspects of the economy and that additional policies are needed in certain sectors to achieve sustainable development. 1 ref., 2 figs., 2 tabs.

  7. Solvent extraction of bituminous coals using light cycle oil: characterization of diaromatic products in liquids

    SciTech Connect (OSTI)

    Josefa M. Griffith; Caroline E. Burgess Clifford; Leslie R. Rudnick; Harold H. Schobert [Pennsylvania State University, University Park, PA (United States). EMS Energy Institute

    2009-09-15T23:59:59.000Z

    Many studies of the pyrolytic degradation of coal-derived and petroleum-derived aviation fuels have demonstrated that the coal-derived fuels show better thermal stability, both with respect to deposition of carbonaceous solids and cracking to gases. Much previous work at our institute has focused on the use of refined chemical oil (RCO), a distillate from the refining of coal tar, blended with light cycle oil (LCO) from catalytic cracking of vacuum gas oil. Hydroprocessing of this blend forms high concentrations of tetralin and decalin derivatives that confer particularly good thermal stability on the fuel. However, possible supply constraints for RCO make it important to consider alternative ways to produce an 'RCO-like' product from coal in an inexpensive process. This study shows the results of coal extraction using LCO as a solvent. At 350{sup o}C at a solvent-to-coal ratio of 10:1, the conversions were 30-50 wt % and extract yields 28-40 wt % when testing five different coals. When using lower LCO/coal ratios, conversions and extract yields were much smaller; lower LCO/coal ratios also caused mechanical issues. LCO is thought to behave similarly to a nonpolar, non-hydrogen donor solvent, which would facilitate heat-induced structural relaxation of the coal followed by solubilization. The main components contributed from the coal to the extract when using Pittsburgh coal are di- and triaromatic compounds. 41 refs., 3 figs., 12 tabs.

  8. Combustion characteristics of dry coal-powder-fueled adiabatic diesel engine: Final report

    SciTech Connect (OSTI)

    Kakwani, R.M.; Kamo, R.

    1989-01-01T23:59:59.000Z

    This report describes the progress and findings of a research program aimed at investigating the combustion characteristics of dry coal powder fueled diesel engine. During this program, significant achievements were made in overcoming many problems facing the coal-powder-fueled engine. The Thermal Ignition Combustion System (TICS) concept was used to enhance the combustion of coal powder fuel. The major coal-fueled engine test results and accomplishments are as follows: design, fabrication and engine testing of improved coal feed system for fumigation of coal powder to the intake air; design, fabrication and engine testing of the TICS chamber made from a superalloy material (Hastelloy X); design, fabrication and engine testing of wear resistant chrome oxide ceramic coated piston rings and cylinder liner; lubrication system was improved to separate coal particles from the contaminated lubricating oil; control of the ignition timing of fumigated coal powder by utilizing exhaust gas recirculation (EGR) and variable TICS chamber temperature; coal-fueled engine testing was conducted in two configurations: dual fuel (with diesel pilot) and 100% coal-fueled engine without diesel pilot or heated intake air; cold starting of the 100% coal-powder-fueled engine with a glow plug; and coal-fueled-engine was operated from 800 to 1800 rpm speed and idle to full load engine conditions.

  9. Dose assessment for various coals in the coal-fired power plant

    SciTech Connect (OSTI)

    Antic, D.; Sokcic-Kostic, M. (Institute of Nuclear Sciences Vinca, Belgrade (Yugoslavia))

    1993-01-01T23:59:59.000Z

    The radiation exposure of the public in the vicinity of a coal-fired power plant has been studied. The experimental data on uranium, thorium, and potassium content in selected coals from Serbia and Bosnia have been used to calculate the release rates of natural radionuclides from the power plant. A generalized model for analysis of radiological impact of an energy source that includes the two-dimensional version of the cloud model simulates the transport of radionuclides released to the atmosphere. The inhalation dose rates are assessed for various meteorological conditions.

  10. Particulate control for low rank coals

    SciTech Connect (OSTI)

    Touzel, R.McD.

    1993-12-31T23:59:59.000Z

    The power generating system in Victoria currently comprises a total capacity of 6650 MW. Eighty percent of this capacity consists of base load stations in the Latrobe Valley using brown coal. The Latrobe Valley brown coals have unique characteristics with high moisture content ranging from 58 percent to 70 percent and an ash content which is relatively low but very variable in nature. These and other factors associated with the coal have caused special problems in handling and combustion of the coal and the de-dusting of the boiler flue gases. In recent years, this has been the basis for the design parameters adopted for all the plants in the system. With respect to flue gas de-dusting, the SECV has carried out extensive laboratory studies to characterize the different ashes obtained from the Latrobe Valley brown coals, including precipitability and aerodynamic tests. It also carried out full-scale tests on operating plants and pilot tests have been conducted on inertial collectors, precipitators and bag filters. The Environmental Protection Authority of Victoria has established a particulate emission level of 0.150 grams/m{sup 3} n.t.p. dry for recent Latrobe Valley boilers. However, the mandated emission level takes into account wide variations in operating conditions, and the plants normally achieve much lower emission levels. The Latrobe Valley plants presently in operation include Yallourn W (2x350 MW + 2x375 MW), Morwell (170 MW total and briquette factory), Hazelwood (8x200 MW) and Loy Yang (4x500 MW). The Yalloum W boilers are supplied with coal from the Yalloum Open Cut, the Morwell and Hazelwood boilers from the Morwell Open Cut and Loy Yang boilers from the Loy Yang Open Cut. All boilers are pulverized coal fired (PCF) and incorporate special firing equipment to enable the as-mined wet coal to be fired directly into the furnaces. All boilers are fitted with electrostatic precipitators. The locations of the stations and open cuts are shown.

  11. Effects of paleolatitude on coal quality - model for organic sulfur distribution in US coal

    SciTech Connect (OSTI)

    Affolter, R.H.; Stricker, G.D.

    1989-03-01T23:59:59.000Z

    In the conterminous US, most Carboniferous peats accumulated at latitudes of 0/degrees/-15/degrees/S, Cretaceous Rocky Mountain province peats at 30/degrees/-45/degrees/N, Tertiary northern Great Plains peats at 40/degrees/-55/degrees/N, and Tertiary Gulf Coast peats at 30/degrees/-40/degrees/N. Alaskan Cretaceous and Tertiary peats accumulated at latitudes above 70/degrees/N. A comparison of paleolatitudes calculated from paleomagnetic poles and organic sulfur contents for more than 7000 coal samples indicates that the higher the latitude in which a peat swamp developed, the lower the mean organic sulfur content of the subsequent coal (correlation coefficient - 0.4; significant at the 99% confidence level). Mean organic sulfur contents range from 0.90% (range = 0.01-5.08%, standard deviation = 0.56) in low-latitude Carboniferous coal to 0.25% (range = 0.01-1.41%, standard deviation = 0.23) in high-latitude Alaskan Cretaceous and Tertiary coal.

  12. Formulation, Pretreatment, and Densification Options to Improve Biomass Specifications for Co-Firing High Percentages with Coal

    SciTech Connect (OSTI)

    Jaya Shankar Tumuluru; J Richard Hess; Richard D. Boardman; Shahab Sokhansanj; Christopher T. Wright; Tyler L. Westover

    2012-06-01T23:59:59.000Z

    There is a growing interest internationally to use more biomass for power generation, given the potential for significant environmental benefits and long-term fuel sustainability. However, the use of biomass alone for power generation is subject to serious challenges, such as feedstock supply reliability, quality, and stability, as well as comparative cost, except in situations in which biomass is locally sourced. In most countries, only a limited biomass supply infrastructure exists. Alternatively, co-firing biomass alongwith coal offers several advantages; these include reducing challenges related to biomass quality, buffering the system against insufficient feedstock quantity, and mitigating the costs of adapting existing coal power plants to feed biomass exclusively. There are some technical constraints, such as low heating values, low bulk density, and grindability or size-reduction challenges, as well as higher moisture, volatiles, and ash content, which limit the co-firing ratios in direct and indirect co-firing. To achieve successful co-firing of biomass with coal, biomass feedstock specifications must be established to direct pretreatment options in order to modify biomass materials into a format that is more compatible with coal co-firing. The impacts on particle transport systems, flame stability, pollutant formation, and boiler-tube fouling/corrosion must also be minimized by setting feedstock specifications, which may include developing new feedstock composition by formulation or blending. Some of the issues, like feeding, co-milling, and fouling, can be overcome by pretreatment methods including washing/leaching, steam explosion, hydrothermal carbonization, and torrefaction, and densification methods such as pelletizing and briquetting. Integrating formulation, pretreatment, and densification will help to overcome issues related to physical and chemical composition, storage, and logistics to successfully co-fire higher percentages of biomass ( > 40%) with coal.

  13. Coal market momentum converts skeptics

    SciTech Connect (OSTI)

    Fiscor, S.

    2006-01-15T23:59:59.000Z

    Tight supplies, soaring natural gas prices and an improving economy bode well for coal. Coal Age presents it 'Forecast 2006' a survey of 200 US coal industry executives. Questions asked included predicted production levels, attitudes, expenditure on coal mining, and rating of factors of importance. 7 figs.

  14. Conditioner for flotation of coal

    SciTech Connect (OSTI)

    Nimerick, K.H.

    1988-03-22T23:59:59.000Z

    A method for recovering coal is described which comprises the steps of floating coal in an aqueous frothing medium containing an amount of a condensation product of an alkanolamine and naphthenic acid sufficient to increase the recovery of coal as compared to the recovery of coal in an identical process using none of the condensation product.

  15. Report of Shelton wood-coal firing tests conducted March 16-April 2, 1980

    SciTech Connect (OSTI)

    Not Available

    1980-05-09T23:59:59.000Z

    Wood and coal combinations were tested at representative steam rates while boiler performance, gaseous and particulate emissions were measured. Wood and coal combinations were tested at representative steam rates while boiler performance, gaseous and particulate emissions were measured. Wood contributed up to 50% of the Btu requirements of the boilers during the tests. The Quinault-Pacific system will permit selected green mill residues to be used in place of coal at the rate of 2.5 tons of wood per ton of coal. Green wood and coal are compatible fuels. Heat provided by the coal and other combustion effects are enough to offset the effects of moisture in green wood and in some cases improve boiler performance. The combined firing of wood with coal at typical steam rates results in better flyash collection, lower emissions, improved opacity, better cinder recovery and lower steam costs.

  16. The relationship between the thermoplastic behavior of blends and their component coals

    SciTech Connect (OSTI)

    Sakurovs, R.

    1999-07-01T23:59:59.000Z

    The thermoplastic behaviors of a number of coking coal blends were measured using proton magnetic resonance thermal analysis (PMRTA) to determine to what extent they were affected by interactions between the component coals. Most blends showed evidence that at temperatures near their temperatures of maximum fluidity the extent to which they fused was different to that expected if the coals did not interact. Only blends of coking coals of different rank fused to a greater extent than expected in the absence of interactions. Semi-anthracite, low rank coals and charcoal reduced the extent of fusion of coking coals to values below those expected if they were acting as inert diluents. These interactions are interpreted as being mediated by transfer of volatile material between the coals on heating.

  17. Healy Clean Coal Project: A DOE Assessment

    SciTech Connect (OSTI)

    National Energy Technology Laboratory

    2003-09-01T23:59:59.000Z

    The goal of the U.S. Department of Energy's (DOE) Clean Coal Technology (CCT) Program is to provide the energy marketplace with advanced, more efficient, and environmentally responsible coal utilization options by conducting demonstrations of new technologies. These demonstration projects are intended to establish the commercial feasibility of promising advanced coal technologies that have been developed to a level at which they are ready for demonstration testing under commercial conditions. This document serves as a DOE post-project assessment (PPA) of the Healy Clean Coal Project (HCCP), selected under Round III of the CCT Program, and described in a Report to Congress (U.S. Department of Energy, 1991). The desire to demonstrate an innovative power plant that integrates an advanced slagging combustor, a heat recovery system, and both high- and low-temperature emissions control processes prompted the Alaska Industrial Development and Export Authority (AIDEA) to submit a proposal for this project. In April 1991, AIDEA entered into a cooperative agreement with DOE to conduct this project. Other team members included Golden Valley Electric Association (GVEA), host and operator; Usibelli Coal Mine, Inc., coal supplier; TRW, Inc., Space & Technology Division, combustor technology provider; Stone & Webster Engineering Corp. (S&W), engineer; Babcock & Wilcox Company (which acquired the assets of Joy Environmental Technologies, Inc.), supplier of the spray dryer absorber technology; and Steigers Corporation, provider of environmental and permitting support. Foster Wheeler Energy Corporation supplied the boiler. GVEA provided oversight of the design and provided operators during demonstration testing. The project was sited adjacent to GVEA's Healy Unit No. 1 in Healy, Alaska. The objective of this CCT project was to demonstrate the ability of the TRW Clean Coal Combustion System to operate on a blend of run-of-mine (ROM) coal and waste coal, while meeting strict environmental requirements. DOE provided $117,327,000 of the total project cost of $282,300,000, or 41.6 percent. Construction for the demonstration project was started in May 1995, and completed in November 1997. Operations were initiated in January 1998, and completed in December 1999. The evaluation contained herein is based primarily on information from the AIDEA's Final Report (Alaska Industrial Development and Export Authority, 2001), as well as other references cited.

  18. PressurePressure Indiana Coal Characteristics

    E-Print Network [OSTI]

    Fernández-Juricic, Esteban

    TimeTime PressurePressure · Indiana Coal Characteristics · Indiana Coals for Coke · Coal Indiana Total Consumption Electricity 59,664 Coke 4,716 Industrial 3,493 Major Coal- red power plantsTransportation in Indiana · Coal Slurry Ponds Evaluation · Site Selection for Coal Gasification · Coal-To-Liquids Study, CTL

  19. CO-FIRING COAL, FEEDLOT, AND LITTER BIOMASS (CFB AND LFB) FUELS IN PULVERIZED FUEL AND FIXED BED BURNERS

    SciTech Connect (OSTI)

    Kalyan Annamalai; John Sweeten; Saqib Mukhtar; Ben Thien; Gengsheng Wei; Soyuz Priyadarsan

    2002-01-15T23:59:59.000Z

    Intensive animal feeding operations create large amounts of animal waste that must be safely disposed of in order to avoid environmental degradation. Cattle feedlots and chicken houses are two examples. In feedlots, cattle are confined to small pens and fed a high calorie grain diet in preparation for slaughter. In chicken houses, thousands of chickens are kept in close proximity. In both of these operations, millions of tons of manure are produced every year. In this project a co-firing technology is proposed which would use manure that cannot be used for fertilizer, for power generation. Since the animal manure has economic uses as both a fertilizer and as a fuel, it is properly referred to as feedlot biomass (FB) for cow manure, or litter biomass (LB) for chicken manure. The biomass will be used a as a fuel by mixing it with coal in a 90:10 blend and firing it in existing coal fired combustion devices. This technique is known as co-firing, and the high temperatures produced by the coal will allow the biomass to be completely combusted. Therefore, it is the goal of the current research to develop an animal biomass cofiring technology. A cofiring technology is being developed by performing: (1) studies on fundamental fuel characteristics, (2) small scale boiler burner experiments, (3) gasifier experiments, (4) computer simulations, and (5) an economic analysis. The fundamental fuel studies reveal that biomass is not as high a quality fuel as coal. The biomass fuels are higher in ash, higher in moisture, higher in nitrogen and sulfur (which can cause air pollution), and lower in heat content than coal. Additionally, experiments indicate that the biomass fuels have higher gas content, release gases more readily than coal, and less homogeneous. Small-scale boiler experiments revealed that the biomass blends can be successfully fired, and NO{sub x} pollutant emissions produced will be similar to or lower than pollutant emissions when firing coal. This is a surprising result as the levels of N are higher in the biomass fuel than in coal. Further experiments showed that biomass is twice or more effective than coal when used in a reburning process to reduce NO{sub x} emissions. Since crushing costs of biomass fuels may be prohibitive, stoker firing may be cost effective; in order simulate such a firing, future work will investigate the performance of a gasifier when fired with larger sized coal and biomass. It will be a fixed bed gasifier, and will evaluate blends, coal, and biomass. Computer simulations were performed using the PCGC-2 code supplied by BYU and modified by A&M with three mixture fractions for handling animal based biomass fuels in order to include an improved moisture model for handling wet fuels and phosphorus oxidation. Finally the results of the economic analysis show that considerable savings can be achieved with the use of biomass. In the case of higher ash and moisture biomass, the fuel cost savings will be reduced, due to increased transportation costs. A spreadsheet program was created to analyze the fuel savings for a variety of different moisture levels, ash levels, and power plant operating parameters.

  20. Small boiler uses waste coal

    SciTech Connect (OSTI)

    Virr, M.J. [Spinheat Ltd. (United States)

    2009-07-15T23:59:59.000Z

    Burning coal waste in small boilers at low emissions poses considerable problem. While larger boiler suppliers have successfully installed designs in the 40 to 80 MW range for some years, the author has been developing small automated fluid bed boiler plants for 25 years that can be applied in the range of 10,000 to 140,000 lbs/hr of steam. Development has centered on the use of an internally circulating fluid bed (CFB) boiler, which will burn waste fuels of most types. The boiler is based on the traditional D-shaped watertable boiler, with a new type of combustion chamber that enables a three-to-one turndown to be achieved. The boilers have all the advantages of low emissions of the large fluid boilers while offering a much lower height incorporated into the package boiler concept. Recent tests with a waste coal that had a high nitrogen content of 1.45% demonstrated a NOx emission below the federal limit of 0.6 lbs/mm Btu. Thus a NOx reduction on the order of 85% can be demonstrate by combustion modification alone. Further reductions can be made by using a selective non-catalytic reduction (SNCR) system and sulfur absorption of up to 90% retention is possible. The article describes the operation of a 30,000 lbs/hr boiler at the Fayette Thermal LLC plant. Spinheat has installed three ICFB boilers at a nursing home and a prison, which has been tested on poor-grade anthracite and bituminous coal. 2 figs.

  1. Coal liquefaction process

    DOE Patents [OSTI]

    Wright, Charles H. (Overland Park, KS)

    1986-01-01T23:59:59.000Z

    A process for the liquefaction of coal wherein raw feed coal is dissolved in recycle solvent with a slurry containing recycle coal minerals in the presence of added hydrogen at elevated temperature and pressure. The highest boiling distillable dissolved liquid fraction is obtained from a vacuum distillation zone and is entirely recycled to extinction. Lower boiling distillable dissolved liquid is removed in vapor phase from the dissolver zone and passed without purification and essentially without reduction in pressure to a catalytic hydrogenation zone where it is converted to an essentially colorless liquid product boiling in the transportation fuel range.

  2. Coal liquefaction process

    DOE Patents [OSTI]

    Wright, C.H.

    1986-02-11T23:59:59.000Z

    A process is described for the liquefaction of coal wherein raw feed coal is dissolved in recycle solvent with a slurry containing recycle coal minerals in the presence of added hydrogen at elevated temperature and pressure. The highest boiling distillable dissolved liquid fraction is obtained from a vacuum distillation zone and is entirely recycled to extinction. Lower boiling distillable dissolved liquid is removed in vapor phase from the dissolver zone and passed without purification and essentially without reduction in pressure to a catalytic hydrogenation zone where it is converted to an essentially colorless liquid product boiling in the transportation fuel range. 1 fig.

  3. Blast furnace injection of massive quantities of coal with enriched air or pure oxygen

    SciTech Connect (OSTI)

    Ponghis, N.; Dufresne, P.; Vidal, R.; Poos, A. (Center de Recherches Metallurgiques, Liege (Belgium))

    1993-01-01T23:59:59.000Z

    An extensive study of the phenomena associated with the blast furnace injection of massive quantities of coal is described. Trials with conventional lances or oxy-coal injectors and hot blast at different oxygen contents - up to 40% - or with cold pure oxygen were realized at coal to oxygen ratios corresponding to a range of 150 to 440 kg. Pilot scale rigs, empty or filled with coke, as well as industrial blast furnaces were utilized.

  4. Multi-parameter on-line coal bulk analysis. Quarterly report, March 16--June 15, 1997

    SciTech Connect (OSTI)

    Vourvopoulos, G.

    1997-12-31T23:59:59.000Z

    An on-line coal analyzer is being developed as a joint venture between the French company SODERN which specializes in the manufacturing of neutron generators and associated electronics and the John B. Long Company which specializes in coal sampling equipment. Progress this quarter is summarized under the following topical headings: Measurement layout; Detector temperature stabilization; Raw coal library; and Determination of Btu content from elemental concentrations.

  5. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01T23:59:59.000Z

    19 3.4. Coking coal for iron & steels FOB export value for coking coal was relatively stables FOB export value for coking coal significantly increased

  6. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01T23:59:59.000Z

    12 2.6. International coal prices and18 International coal prices and trade In parallel with the2001, domestic Chinese coal prices moved from stable levels

  7. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    farms with advanced coal generation facilities and operatingfarms with advanced coal generation facilities and operatingin the stand-alone coal generation option (IGCC+CCS plant)

  8. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01T23:59:59.000Z

    services. Power generation Coal increasingly dominates28 Thermal coal electricity generation efficiency alsostudy examines four coal-thermal generation technology types

  9. Clean Coal Power Initiative | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Clean Coal Power Initiative Clean Coal Power Initiative "Clean coal technology" describes a new generation of energy processes that sharply reduce air emissions and other...

  10. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    of Figures Figure ES-1. Advanced Coal Wind Hybrid: Basicviii Figure 1. Advanced-Coal Wind Hybrid: Basic29 Figure 9. Sensitivity to Coal

  11. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01T23:59:59.000Z

    of deploying advanced coal power in the Chinese context,”12 2.6. International coal prices and12 III. Chinese Coal

  12. Wabash River Coal Gasification Repowering Project. Topical report, July 1992--December 1993

    SciTech Connect (OSTI)

    Not Available

    1994-01-01T23:59:59.000Z

    The Wabash River Coal Gasification Repowering Project (WRCGRP, or Wabash Project) is a joint venture of Destec Energy, Inc. of Houston, Texas and PSI Energy, Inc. of Plainfield, Indiana, who will jointly repower an existing 1950 vintage coal-fired steam generating plant with coal gasification combined cycle technology. The Project is located in West Terre Haute, Indiana at PSI`s existing Wabash River Generating Station. The Project will process locally-mined Indiana high-sulfur coal to produce 262 megawatts of electricity. PSI and Destec are participating in the Department of Energy Clean Coal Technology Program to demonstrate coal gasification repowering of an existing generating unit affected by the Clean Air Act Amendments. As a Clean Coal Round IV selection, the project will demonstrate integration of an existing PSI steam turbine generator and auxiliaries, a new combustion turbine generator, heat recovery steam generator tandem, and a coal gasification facility to achieve improved efficiency, reduced emissions, and reduced installation costs. Upon completion in 1995, the Project will not only represent the largest coal gasification combined cycle power plant in the United States, but will also emit lower emissions than other high sulfur coal-fired power plants and will result in a heat rate improvement of approximately 20% over the existing plant configuration. As of the end of December 1993, construction work is approximately 20% complete for the gasification portion of the Project and 25% complete for the power generation portion.

  13. Emissions tradeoffs associated with cofiring forest biomass with coal: A case study in Colorado, USA

    E-Print Network [OSTI]

    Fried, Jeremy S.

    3 July 2013 Keywords: Forest biomass Greenhouse gas emissions Air pollution Bioenergy Cofire a b mine and power plant. Model emissions tradeoffs of cofiring forest biomass with coal up to 20% by heat emissions sources: coal mining, power plant processes, forest biomass processes, boiler emissions

  14. Process for the production and recovery of fuel values from coal

    DOE Patents [OSTI]

    Sass, Allan (Los Angeles, CA); McCarthy, Harry E. (Golden, CO); Kaufman, Paul R. (North Canton, OH); Finney, Clement S. (Claremont, CA)

    1982-01-01T23:59:59.000Z

    A method of pyrolyzing and desulfurizing coal in a transport reactor to recover volatile fuel values and hydrogen by heating particulate coal entrained in a carrier gas substantially free of oxygen to a pyrolysis temperature in a zone within three seconds.

  15. Quantification of Variability and Uncertainty in Hourly NOx Emissions from Coal-Fired Power Plants

    E-Print Network [OSTI]

    Frey, H. Christopher

    to quantify variability and uncertainty for NOx emissions from coal-fired power plants. Data for hourly NOx emissions, heat rate, gross load and capacity factor of 32 units from 9 different power plants were analyzed Uncertainty, Variability, Emission Factors, Coal-Fired Power Plants, NOx emissions, Regression Models

  16. Fort Union coals of the northern Rockies and Great Plains: A linchpin toward a new approach to national coal resource assessment

    SciTech Connect (OSTI)

    Flores, R.M.; Stricker, G.D. [Geological Survey, Denver, CO (United States)

    1996-06-01T23:59:59.000Z

    The U.S. Geological Survey recently initiated a 5-year program to assess the Nation`s coal resources, which emphasizes a new approach relating coal quantity and quality. One assessment region includes the northern Rocky Mountains and Great Plains of Wyoming, Montana, and North Dakota, which contains a vast expanse of Paleocene Fort Union coal-bearing rocks that yielded about 30% (>299 million short tons) of the total coal produced (1.03 billion short tons) in the U.S. for 1994. Production is from 14 coal beds/zones (Wyodak-Anderson, Anderson-Dietz, Rosebud, Beulah-Zap, Hagel, Harmon, Ferris Nos. 23, 24, 25, 31, 38, 39, Hanna No. 80, and Deadman seams) mined in the Hanna, Green River, Powder River, and Williston Basins. About 254 million short tons produced from 25 mines are from the Wyodak-Anderson, Anderson-Dietz, and Rosebud coal beds/zones in the Powder River Basin (PRB). These coals are considered as clean and low contaminant compliance coals containing less sulfur and ash (arithmetic mean for sulfur is 0.58% and ash is 7%, as-received basis) than coals produced from other regions in the conterminous U.S. Preliminary elemental analysis of coal samples from the PRB for those hazardous air pollutants (HAPs) named in the Amendments to the 1990 Clean Air Act (including Sb, As, Be, Cd, Cr, Co, Pb, Mn, Hg, Ni, Se, and U), indicates that PRB coals are lower in HAPs contents than other coals from within the region and also other regions in the U.S. Arithmetic means of HAPs contents of these coals are: Sb=0.35, As=3.4, Be=0.6, Cd=0.08, Cr=6.1, Co=1.6, Pb=3.6, Mn=23.5, Hg=0.09, Ni=4.6, Se=0.9, and U=1.1 (in ppm, as-received, and on a whole-coal basis). These coal-quality parameters will be used to delineate coal quantity of the 14 Fort Union coal beds/zones defined in the resource assessment for expanded utilization of coals into the next several decades as controlled by present and future environmental constraints.

  17. Aqueous coal slurry

    DOE Patents [OSTI]

    Berggren, Mark H.; Smit, Francis J.; Swanson, Wilbur W.

    1993-04-06T23:59:59.000Z

    An aqueous slurry containing coal and dextrin as a dispersant. The slurry, in addition to containing dextrin, may contain a conventional dispersant or, alternatively, a pH controlling reagent.

  18. Coal markets squeeze producers

    SciTech Connect (OSTI)

    Ryan, M.

    2005-12-01T23:59:59.000Z

    Supply/demand fundamentals seem poised to keep prices of competing fossil fuels high, which could cushion coal prices, but increased mining and transportation costs may squeeze producer profits. Are markets ready for more volatility?

  19. Clean Coal Research

    Broader source: Energy.gov [DOE]

    DOE's clean coal R&D is focused on developing and demonstrating advanced power generation and carbon capture, utilization and storage technologies for existing facilities and new fossil-fueled...

  20. Clean Coal Technology (Indiana)

    Broader source: Energy.gov [DOE]

    A public utility may not use clean coal technology at a new or existing electric generating facility without first applying for and obtaining from the Utility Regulatory Commission a certificate...

  1. Coal Market Module

    Gasoline and Diesel Fuel Update (EIA)

    these provisions are assumed to result in 1 gigawatt of advanced coal-fired capacity with carbon capture and sequestration by 2017. Subtitle B which extends the phaseout of...

  2. Coal Market Module This

    Annual Energy Outlook 2013 [U.S. Energy Information Administration (EIA)]

    together, are assumed to result in about 1 gigawatt of advanced coal-fired capacity with carbon capture and sequestration by 2017. EIEA was passed in October 2008 as part of the...

  3. Quarterly coal report

    SciTech Connect (OSTI)

    Young, P.

    1996-05-01T23:59:59.000Z

    The Quarterly Coal Report (QCR) provides comprehensive information about U.S. coal production, distribution, exports, imports, receipts, prices, consumption, and stocks to a wide audience, including Congress, Federal and State agencies, the coal industry, and the general public. Coke production, consumption, distribution, imports, and exports data are also provided. The data presented in the QCR are collected and published by the Energy Information Administration (EIA) to fulfill data collection and dissemination responsibilities as specified in the Federal Energy Administration Act of 1974 (Public Law 93-275), as amended. This report presents detailed quarterly data for October through December 1995 and aggregated quarterly historical data for 1987 through the third quarter of 1995. Appendix A displays, from 1987 on, detailed quarterly historical coal imports data, as specified in Section 202 of the Energy Policy and Conservation Amendments Act of 1985 (Public Law 99-58). Appendix B gives selected quarterly tables converted to metric tons.

  4. Aqueous coal slurry

    DOE Patents [OSTI]

    Berggren, Mark H. (Golden, CO); Smit, Francis J. (Arvada, CO); Swanson, Wilbur W. (Golden, CO)

    1993-01-01T23:59:59.000Z

    An aqueous slurry containing coal and dextrin as a dispersant. The slurry, in addition to containing dextrin, may contain a conventional dispersant or, alternatively, a pH controlling reagent.

  5. Coal liquefaction process

    DOE Patents [OSTI]

    Skinner, Ronald W. (Allentown, PA); Tao, John C. (Perkiomenville, PA); Znaimer, Samuel (Vancouver, CA)

    1985-01-01T23:59:59.000Z

    This invention relates to an improved process for the production of liquid carbonaceous fuels and solvents from carbonaceous solid fuels, especially coal. The claimed improved process includes the hydrocracking of the light SRC mixed with a suitable hydrocracker solvent. The recycle of the resulting hydrocracked product, after separation and distillation, is used to produce a solvent for the hydrocracking of the light solvent refined coal.

  6. Coal Liquefaction desulfurization process

    DOE Patents [OSTI]

    Givens, Edwin N. (Bethlehem, PA)

    1983-01-01T23:59:59.000Z

    In a solvent refined coal liquefaction process, more effective desulfurization of the high boiling point components is effected by first stripping the solvent-coal reacted slurry of lower boiling point components, particularly including hydrogen sulfide and low molecular weight sulfur compounds, and then reacting the slurry with a solid sulfur getter material, such as iron. The sulfur getter compound, with reacted sulfur included, is then removed with other solids in the slurry.

  7. Method for coal liquefaction

    DOE Patents [OSTI]

    Wiser, W.H.; Oblad, A.G.; Shabtai, J.S.

    1994-05-03T23:59:59.000Z

    A process is disclosed for coal liquefaction in which minute particles of coal in intimate contact with a hydrogenation catalyst and hydrogen arc reacted for a very short time at a temperature in excess of 400 C at a pressure of at least 1500 psi to yield over 50% liquids with a liquid to gaseous hydrocarbon ratio in excess of 8:1. 1 figures.

  8. Advanced liquefaction using coal swelling and catalyst dispersion techniques. Volume 2, appendices. Final technical report, October 1, 1991--September 30, 1994

    SciTech Connect (OSTI)

    Curtis, C.W. [Auburn Univ., AL (United States); Chander, S. [Pennsylvania State Univ., College Park, PA (United States); Gutterman, C.

    1995-04-01T23:59:59.000Z

    Liquefaction experiments were undertaken using subbituminous Black Thunder mine coal to observe the effects of aqueous SO{sub 2} coal beneficiation and the introduction of various coal swelling solvents and catalyst precursors. Aqueous SO{sub 2} beneficiation of Black Thunder coal removed alkali metals and alkaline earth metals, increased the sulfur content and increased the catalytic liquefaction conversion to THF solubles compared to untreated Black Thunder coal. The liquefaction solvent had varying effects on coal conversion, depending upon the type of solvent added. The hydrogen donor solvent, dihydroanthracene, was most effective, while a coal-derived Wilsonville solvent promoted more coal conversion than did relatively inert 1-methylnaphthalene. Swelling of coal with hydrogen bonding solvents tetrahydrofuran (THF), isopropanol, and methanol, prior to reaction resulted in increased noncatalytic conversion of both untreated and SO{sub 2} treated Black Thunder coals, while dimethylsulfoxide (DMSO), which was absorbed more into the coal than any other swelling solvent, was detrimental to coal conversion. Swelling of SO{sub 2} treated coal before liquefaction resulted in the highest coal conversions; however, the untreated coal showed the most improvements in catalytic reactions when swelled in either THF, isopropanol, or methanol prior to liquefaction. The aprotic solvent DMSO was detrimental to coal conversion.

  9. Coal surface structure and thermodynamics. Final report

    SciTech Connect (OSTI)

    Larsen, J.W.; Wernett, P.C.; Glass, A.S.; Quay, D.; Roberts, J.

    1994-05-01T23:59:59.000Z

    Coals surfaces were studied using static surface adsorption measurements, low angle x-ray scattering (LAXS), inverse gas chromatography (IGC) and a new {sup 13}C NMR relaxation technique. A comparison of surface areas determined by hydrocarbon gas adsorption and LAXS led to the twin conclusions that the hydrocarbons had to diffuse through the solid to reach isolated pores and that the coal pores do not form interconnected networks, but are largely isolated. This conclusion was confirmed when IGC data for small hydrocarbons showed no discontinuities in their size dependence as usually observed with porous solids. IGC is capable of providing adsorption thermodynamics of gases on coal surfaces. The interactions of non-polar molecules and coal surfaces are directly proportioned to the gas molecular polarizability. For bases, the adsorption enthalpy is equal to the polarizability interaction plus the heat of hydrogen bond formation with phenol. Amphoteric molecules have more complex interactions. Mineral matter can have highly specific effects on surface interactions, but with most of the molecules studied is not an important factor.

  10. The magnetohydrodynamics Coal-Fired Flow Facility

    SciTech Connect (OSTI)

    Not Available

    1993-02-01T23:59:59.000Z

    In this quarterly technical progress report, UTSI reports on progress on a multi-task contract to develop the technology for the steam bottoming plant for an MHD Steam Combined Cycle power plant. Two proof-of-concept (POC) tests totaling 614 hours of coal fired operation were conducted during the quarter using low sulfur Montana Rosebud coal. The results of these tests are summarized. Operational aspects of the particulate control devices being evaluated, a dry electrostatic precipitator (ESP) and a reverse air baghouse, are discussed. A sootblowing control system for the convective heat transfer surfaces that senses the need to clean the tubes by temperatures is described. Environmental reporting includes measurement of levels of ground water wells over time and the remote air quality measurements of impact of the stack emissions from the two tests. Results of testing candidate ceramic tubes for a recuperative high temperature air heater are included. Analyses of the tube materials tested in the 2000 hour test series previously completed on high sulfur Illinois No. 6 coal are summarized. Facility maintenance and repair activities for the DOE Coal Fired Flow Facility are summarized. The major facility modification discussed is the completion of the installation of a Wet ESP with rotary vacuum filter which is replacing the venturi scrubber as the primary facility particulate control device for any exhaust gases that are not routed through the dry ESP or baghouse.

  11. Advanced Coal Conversion Process Demonstration Project. Quarterly technical progress report, January 1, 1994--March 31, 1994

    SciTech Connect (OSTI)

    NONE

    1996-02-01T23:59:59.000Z

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from January 1, 1994, through March 31, 1994. This project demonstrates an advanced, thermal, coal drying process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal{reg_sign} process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal processing, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. Rosebud SynCoal Partnership`s ACCP Demonstration Facility entered Phase III, Demonstration Operation, in April 1992 and operated in an extended startup mode through August 10, 1993, when the facility became commercial. Rosebud SynCoal Partnership instituted an aggressive program to overcome startup obstacles and now focuses on supplying product coal to customers. Significant accomplishments in the history of the SynCoal{reg_sign} process development are shown in Appendix A.

  12. Advanced Coal Conversion Process Demonstration Project. Technical progress report, January 1, 1993--December 31, 1993

    SciTech Connect (OSTI)

    NONE

    1995-02-01T23:59:59.000Z

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from January 1, 1993, through December 31, 1993. This project demonstrates an advanced, thermal, coal drying process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low- rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal{reg_sign} process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal processing, the coal is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal. Rosebud SynCoal Partnership`s ACCP Demonstration Facility entered Phase III, Demonstration Operation, in April 1992 and operated in an extended startup mode through August 10, 1993, when the facility became commercial. Rosebud SynCoal Partnership instituted an aggressive program to overcome startup obstacles and now focuses on supplying product coal to customers. Significant accomplishments in the history of the SynCoal{reg_sign} process development are shown in Appendix A.

  13. Engineering development of advanced physical fine coal cleaning for premium fuel applications

    SciTech Connect (OSTI)

    Shields, G.L.; Smit, F.J.; Jha, M.C.

    1997-08-28T23:59:59.000Z

    The primary goal of this project is the engineering development of two advanced physical fine coal cleaning processes, column flotation and selective agglomeration, for premium fuel applications. The project scope included laboratory research and bench-scale testing on six coals to optimize these processes, followed by the design, construction and operation of 2 t/hr process development unit (PDU). This report represents the findings of the PDU Advanced Column Flotation Testing and Evaluation phase of the program and includes a discussion of the design and construction of the PDU. Three compliance steam coals, Taggart, Indiana VII and Hiawatha, were processed in the PDU to determine performance and design parameters for commercial production of premium fuel by advanced flotation. Consistent, reliable performance of the PDU was demonstrated by 72-hr production runs on each of the test coals. Its capacity generally was limited by the dewatering capacity of the clean coal filters during the production runs rather than by the flotation capacity of the Microcel column. The residual concentrations of As, Pb, and Cl were reduced by at least 25% on a heating value basis from their concentrations in the test coals. The reduction in the concentrations of Be, Cd, Cr, Co, Mn, Hg, Ni and Se varied from coal to coal but the concentrations of most were greatly reduced from the concentrations in the ROM parent coals. The ash fusion temperatures of the Taggart and Indiana VII coals, and to a much lesser extent the Hiawatha coal, were decreased by the cleaning.

  14. Co-Firing Oil Shale with Coal and Other Fuels for Improved Efficiency and Multi-Pollutant Control

    SciTech Connect (OSTI)

    Robert A. Carrington; William C. Hecker; Reed Clayson

    2008-06-01T23:59:59.000Z

    Oil shale is an abundant, undeveloped natural resource which has natural sorbent properties, and its ash has natural cementitious properties. Oil shale may be blended with coal, biomass, municipal wastes, waste tires, or other waste feedstock materials to provide the joint benefit of adding energy content while adsorbing and removing sulfur, halides, and volatile metal pollutants, and while also reducing nitrogen oxide pollutants. Oil shale depolymerization-pyrolysis-devolatilization and sorption scoping studies indicate oil shale particle sorption rates and sorption capacity can be comparable to limestone sorbents for capture of SO2 and SO3. Additionally, kerogen released from the shale was shown to have the potential to reduce NOx emissions through the well established “reburning” chemistry similar to natural gas, fuel oil, and micronized coal. Productive mercury adsorption is also possible by the oil shale particles as a result of residual fixed-carbon and other observed mercury capture sorbent properties. Sorption properties were found to be a function particle heating rate, peak particle temperature, residence time, and gas-phase stoichmetry. High surface area sorbents with high calcium reactivity and with some adsorbent fixed/activated carbon can be produced in the corresponding reaction zones that exist in a standard pulverized-coal or in a fluidized-bed combustor.

  15. Correlation for the total sulfur content in char after devolatilization

    SciTech Connect (OSTI)

    Vasilije Manovic; Borislav Grubor [University of Belgrade, Belgrade (Serbia & Montenegro)

    2006-02-01T23:59:59.000Z

    The overall process of coal combustion takes place in two successive steps: devolatilization and char combustion. The fate of sulfur during the devolatilization of coal of different rank was investigated. The significance of the investigation is in fact that a major part of sulfur release occurs during devolatilization of coal, (i.e., emission of sulfur oxides during combustion of coal largely depends on sulfur release during devolatilization). The experimental investigations were conducted to obtain the data about the quantitative relation between sulfur content in the coal and sulfur content in the char. Standard procedures were used for obtaining the chars in a laboratory oven and determining the sulfur forms in the coal and char samples. The experiments were done with ground coal samples ({lt}0.2 mm), at the temperatures in the range of 500-1000{sup o}C. We showed that the amount of sulfur remaining in the char decreases, but not significantly in the temperature range 600-900{sup o}C. On the basis of the theoretical consideration of behavior of sulfur forms during devolatilization, certain simplifying assumptions, and obtained experimental data, we propose two correlations to associate the content of sulfur in the coal and in the char. The correlations are based on the results of the proximate analysis and sulfur forms in coal. Good agreement was found when the proposed correlations were compared with the experimental results obtained for investigated coals. Moreover, the correlations were verified by results found in the literature for numerous Polish, Albanian, and Turkish coals. Significant correlations (P {lt}0.05) between observed and calculated data with correlation coefficient, R {gt}0.9, were noticed in the case of all coals. 25 refs., 3 figs., 2 tabs.

  16. Slovak Centre of Biomass Use for Energy Wood Fired Heating Plant in Slovakia

    E-Print Network [OSTI]

    brown-coal fired boilers with low efficiency. The special furnace design ensures that woody biofuel authorities CHP Planning issues Transport companies District Heating Sustainable communities Utilities Solar

  17. Characterization of selected Ohio coals to predict their conversion behavior relative to 104 North American Coals. [Factors correlating with liquefaction behavior

    SciTech Connect (OSTI)

    Whitacre, T. P.; Hunt, T. J.; Kneller, W. A.

    1982-02-01T23:59:59.000Z

    Twenty-six coal samples from Ohio were collected as washed and seam samples, and lithobodies within the seams. Characterization of these samples included determination of % maceral, % anti R/sub max/, LTA, chlorine content and proximate/ultimate and qualitative mineral analyses. These data were compared to data from a similar project by Yarzab, R.F., et al., 1980 completed at Pennsylvania State University using tetralin as the hydrogen donor solvent. The characteristics of these coals were correlated with liquefaction conversion and other data accrued on 104 North American coals by statistical analyses. Utilizing percent carbon, sulfur, volatile matter, reflectance, vitrinite and total reactive macerals, Q-mode cluster analysis demonstrated that Ohio coals are more similar to the coals of the Interior province than to those of the Appalachian province. Linear multiple regression analysis for the 104 North American coals provided a prediction equation for conversion (R = .96). The predicted conversion values for the samples range from 58.8 to 79.6%, with the Lower Kittanning (No. 5) and the Middle Kittanning (No. 6) coal seams showing the highest predicted percent conversion (respectively, 73.4 and 72.2%). The moderately low FSI values for the No. 5 and No. 6 coals (respectively, 2.5 and 3) and their moderately high alkaline earth content (respectively, 0.69 and 0.74%) suggest that these coals possess the best overall properties for conversion. Stepwise regression has indicated that the most important coal characteristics affecting conversion are, in decreasing order of importance: % volatile matter, % vitrinite and % total sulfur. Conversion processes can be expected to produce higher yields with Ohio coals due to the presence of such mineral catalysts as pyrite and kaolinite. It is believed that the presence of these disposable catalysts increases the marketability of Ohio coals.

  18. Improving the technology of creating water-coal fuel from lignites

    SciTech Connect (OSTI)

    Gorlov, E.G.; Golovin, G.S.; Zotova, O.V. [Rossiiskaya Akadeiya, Nauk (Russian Federation)

    1994-12-31T23:59:59.000Z

    This paper describes the preparation of coal-water fuel slurries from lignite. The heat of combustion as related to the preparation of the lignite was investigated. The hydrobarothermal processing of suspensions of lignites was studied in autoclaves.

  19. COAL LOGISTICS. Tracking U.S. Coal Exports

    SciTech Connect (OSTI)

    Sall, G.W. [US Department of Energy, Office of Fossil Energy, Washington, DC (United States)

    1988-06-28T23:59:59.000Z

    COAL LOGISTICS has the capability to track coal from a U. S. mine or mining area to a foreign consumer`s receiving dock. The system contains substantial quantities of information about the types of coal available in different U. S. coalfields, present and potential inland transportation routes to tidewater piers, and shipping routes to and port capabilities in Italy, Japan, South Korea, Taiwan, and Thailand. It is designed to facilitate comparisons of coal quality and price at several stages of the export process, including delivered prices at a wide range of destinations. COAL LOGISTICS can be used to examine coal quality within or between any of 18 U. S. coalfields, including three in Alaska, or to compare alternative routes and associated service prices between coal-producing regions and ports-of-exit. It may be used to explore the possibilities of different ship sizes, marine routes, and foreign receiving terminals for coal exports. The system contains three types of information: records of coal quality, domestic coal transportation options, and descriptions of marine shipment routes. COAL LOGISTICS contains over 3100 proximate analyses of U. S. steam coals, usually supplemented by data for ash softening temperature and Hardgrove grindability; over 1100 proximate analyses for coals with metallurgical potential, usually including free swelling index values; 87 domestic coal transportation options: rail, barge, truck, and multi-mode routes that connect 18 coal regions with 15 U. S. ports and two Canadian terminals; and data on 22 Italian receiving ports for thermal and metallurgical coal and 24 coal receiving ports along the Asian Pacific Rim. An auxiliary program, CLINDEX, is included which is used to index the database files.

  20. Direct tuyere injection of oxygen for enhanced coal combustion

    SciTech Connect (OSTI)

    Riley, M.F. [Praxair, Inc., Tarrytown, NY (United States)

    1996-12-31T23:59:59.000Z

    Injecting oxygen directly into the tuyere blowpipe can enhance the ignition and combustion of injected pulverized coal, allowing the efficient use of higher coal rates at high furnace production levels. The effects of direct oxygen injection have been estimated from an analysis of the factors controlling the dispersion, heating, ignition, and combustion of injected coal. Injecting ambient temperature oxygen offers mechanical improvements in the dispersion of coal but provides little thermochemical benefit over increased blast enrichment. Injecting hot oxygen through a novel, patented thermal nozzle lance offers both mechanical and thermochemical benefits over increased enrichment or ambient oxygen injection. Plans for pilot-scale and commercial-scale testing of this new lance are described.

  1. Geology of coal fires: case studies from around the world

    SciTech Connect (OSTI)

    Glenn B. Stracher (ed.)

    2008-01-15T23:59:59.000Z

    Coal fires are preserved globally in the rock record as burnt and volume-reduced coal seams and by pyrometamorphic rocks, explosion breccias, clinker, gas-vent-mineral assemblages, fire-induced faulting, ground fissures, slump blocks, and sinkholes. Coal fires are responsible for coronary and respiratory diseases and fatalities in humans, as well as arsenic and fluorine poisoning. Their heat energy, toxic fumes, and solid by-products of combustion destroy floral and faunal habitats while polluting the air, water, and soil. This volume includes chapters devoted to spontaneous combustion and greenhouse gases, gas-vent mineralogy and petrology, paralavas and combustion metamorphic rocks, geochronology and landforms, magnetic signatures and geophysical modeling, remote-sensing detection and fire-depth estimation of concealed fires, and coal fires and public policy.

  2. 7-29 A coal-burning power plant produces 300 MW of power. The amount of coal consumed during a one-day period and the rate of air flowing through the furnace are to be determined.

    E-Print Network [OSTI]

    Bahrami, Majid

    7-11 7-29 A coal-burning power plant produces 300 MW of power. The amount of coal consumed during The heating value of the coal is given to be 28,000 kJ/kg. Analysis (a) The rate and the amount of heat inputs'tQQ The amount and rate of coal consumed during this period are kg/s48.33 s360024 kg10893.2 MJ/kg28 MJ101.8 6

  3. Origin of coal seam structures, Sullivan County, Indiana

    SciTech Connect (OSTI)

    Adams, S.C.; Kullerud, G.

    1983-09-01T23:59:59.000Z

    Structures of Pennsylvanian coal seams in Sullivan County, Indiana, reflect deeper structural components, of which regional dip is dominant. Other components of structure result form differential compaction. The effects of these components are characterized by their closure, size, shape, and orientation. (1) The Mississippian unconformity surface is characterized by parallel valley with up to 300 ft (91 m) of local relief. (2) The composite lower Pennsylvanian section below the Seelyville Coal has variable sandstone content. Some paleovalleys are filled with multistory sandstones, and others with claystone. (3) Silurian pinnacle reefs from small, circular features with a diameter of 1 to 2 mi (1.5 to 3 km) and closures of 25 tio 50 ft (8 to 15 m) on Pennsylvanian coal seams, 50 ft (15 m) on the Aux Vases Shale, and 150 ft (45 m) on the New Albany Shale. (4) The distributions and standard deviations of thicknesses, dips, and grain size of the sedimentary rocks between the coal seams demonstrate that seams above the Seelyville Coal were deposited in parallel and have concordant modern structures. Specific facies between seams have limited influence on the overall structure. Coal structures in the Illinois basin can be defined by a drilling program that penetrates only 150 ft (45 m) of Pennsylvanian strata. Below the Seelyville Coal, units examined demonstrate basin-margin convergence.

  4. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    2 Syngas (H2 + CO + CO2) Coal Gasifier coal Fuel Production/2 Syngas (H2 + CO + CO2) Coal Gasifier coal Fuel Production/this operational mode, the gasifiers and other parts of the

  5. Characterization of industrial process waste heat and input heat streams

    SciTech Connect (OSTI)

    Wilfert, G.L.; Huber, H.B.; Dodge, R.E.; Garrett-Price, B.A.; Fassbender, L.L.; Griffin, E.A.; Brown, D.R.; Moore, N.L.

    1984-05-01T23:59:59.000Z

    The nature and extent of industrial waste heat associated with the manufacturing sector of the US economy are identified. Industry energy information is reviewed and the energy content in waste heat streams emanating from 108 energy-intensive industrial processes is estimated. Generic types of process equipment are identified and the energy content in gaseous, liquid, and steam waste streams emanating from this equipment is evaluated. Matchups between the energy content of waste heat streams and candidate uses are identified. The resultant matrix identifies 256 source/sink (waste heat/candidate input heat) temperature combinations. (MHR)

  6. Decaking of coal or oil shale during pyrolysis in the presence of iron oxides

    DOE Patents [OSTI]

    Rashid Khan, M.

    1988-05-05T23:59:59.000Z

    A method for producing a fuel from the pyrolysis of coal or oil shale in the presence of iron oxide in an inert gas atmosphere is described. The method includes the steps of pulverizing feed coal or oil shale, pulverizing iron oxide, mixing the pulverized feed and iron oxide, and heating the mixture in a gas atmosphere which is substantially inert to the mixture so as to form a product fuel, which may be gaseous, liquid and/or solid. The method of the invention reduces the swelling of coals, such as bituminous coal and the like, which are otherwise known to swell during pyrolysis. 4 figs., 8 tabs.

  7. Decaking of coal or oil shale during pyrolysis in the presence of iron oxides

    DOE Patents [OSTI]

    Khan, M. Rashid (Morgantown, WV)

    1989-01-01T23:59:59.000Z

    A method for producing a fuel from the pyrolysis of coal or oil shale in the presence of iron oxide in an inert gas atmosphere. The method includes the steps of pulverizing feed coal or oil shale, pulverizing iron oxide, mixing the pulverized feed and iron oxide, and heating the mixture in a gas atmosphere which is substantially inert to the mixture so as to form a product fuel, which may be gaseous, liquid and/or solid. The method of the invention reduces the swelling of coals, such as bituminous coal and the like, which are otherwise known to swell during pyrolysis.

  8. Advanced Coal Wind Hybrid: Economic Analysis

    E-Print Network [OSTI]

    Phadke, Amol

    2008-01-01T23:59:59.000Z

    application of new clean coal technologies with near zeroapplication of new clean coal technologies with near zero

  9. Gasifier feed: Tailor-made from Illinois coals. Final technical report, September 1, 1991--December 31, 1992

    SciTech Connect (OSTI)

    Ehrlinger, H.P. III [Illinois State Geological Survey, Champaign, IL (United States); Lytle, J.M.; Frost, R.R.; Lizzio, A.A.; Kohlenberger, L.B.; Brewer, K.K. [Illinois State Geological Survey, Champaign, IL (United States)]|[DESTEC Energy (United States)]|[Williams Technologies, Inc. (United States)]|[Illinois Coal Association (United States)

    1992-12-31T23:59:59.000Z

    The main purpose of this project was to produce a feedstock from preparation plant fines from an Illinois (IL) coal that is ideal for a slurry fed, slagging, entrained-flow coal gasifier. The high-sulfur content and high-Btu value of IL coals are Particularly advantageous in such a gasifier; preliminary-calculations indicate that the increased cost of removing sulfur from the gas from a high-sulfur coal is more than offset b the increased revenue from the sale of the elemental sulfur; additionally the high-Btu IL coal concentrates more energy into the slurry of a given coal to water ratio. The Btu is--higher not only because of the hither Btu value of the coal but also because IL coal requires less water to produce a pumpable slurry than western coal, i.e., as little as 30--35% water may be used for IL coal as compared to approximately 45% for most western coals. During the contract extension, additional coal testing was completed confirming the fact that coal concentrates can be made from plant waste under a variety of flotation conditions 33 tests were conducted, yielding an average of 13326 Btu with 9.6% ash while recovering 86.0%-Of the energy value.

  10. DESULFURIZATION OF COAL MODEL COMPOUNDS AND COAL LIQUIDS

    E-Print Network [OSTI]

    Wrathall, James Anthony

    2011-01-01T23:59:59.000Z

    of coal sulfur K-T gasification process SRC I process U. S.flow sheet of a K-T coal gasification complex for producingProduction via K-T Gasification" © CEP Aug. 78. Feed

  11. Method of extracting coal from a coal refuse pile

    DOE Patents [OSTI]

    Yavorsky, Paul M. (Monongahela, PA)

    1991-01-01T23:59:59.000Z

    A method of extracting coal from a coal refuse pile comprises soaking the coal refuse pile with an aqueous alkali solution and distributing an oxygen-containing gas throughout the coal refuse pile for a time period sufficient to effect oxidation of coal contained in the coal refuse pile. The method further comprises leaching the coal refuse pile with an aqueous alkali solution to solubilize and extract the oxidized coal as alkali salts of humic acids and collecting the resulting solution containing the alkali salts of humic acids. Calcium hydroxide may be added to the solution of alkali salts of humic acid to form precipitated humates useable as a low-ash, low-sulfur solid fuel.

  12. Ultrasound-promoted chemical desulfurization of Illinois coals. Final technical report, September 1, 1990--August 31, 1991

    SciTech Connect (OSTI)

    Chao, S.S.

    1991-12-31T23:59:59.000Z

    The overall objectives of the program were to investigate the use of ultrasound to promote coal desulfurization reactions and to evaluate chemical coal desulfurization schemes under mild conditions through a fundamental understanding of their reaction mechanisms and kinetics. The ultimate goal was to develop an economically feasible mild chemical process to reduce the total sulfur content of Illinois Basin Coals, while retaining their original physical characteristics, such as calorific value and volatile matter content. During the program, potential chemical reactions with coal were surveyed under various ultrasonic irradiation conditions for desulfurization, to formulate preliminary reaction pathways, and to select a few of the more promising chemical processes for more extensive study.

  13. Coal combustion system

    DOE Patents [OSTI]

    Wilkes, Colin (Lebanon, IN); Mongia, Hukam C. (Carmel, IN); Tramm, Peter C. (Indianapolis, IN)

    1988-01-01T23:59:59.000Z

    In a coal combustion system suitable for a gas turbine engine, pulverized coal is transported to a rich zone combustor and burned at an equivalence ratio exceeding 1 at a temperature above the slagging temperature of the coal so that combustible hot gas and molten slag issue from the rich zone combustor. A coolant screen of water stretches across a throat of a quench stage and cools the combustible gas and molten slag to below the slagging temperature of the coal so that the slag freezes and shatters into small pellets. The pelletized slag is separated from the combustible gas in a first inertia separator. Residual ash is separated from the combustible gas in a second inertia separator. The combustible gas is mixed with secondary air in a lean zone combustor and burned at an equivalence ratio of less than 1 to produce hot gas motive at temperature above the coal slagging temperature. The motive fluid is cooled in a dilution stage to an acceptable turbine inlet temperature before being transported to the turbine.

  14. Results from the third LLL underground coal gasification experiment at Hoe Creek

    SciTech Connect (OSTI)

    Hill, R.W.; Thorsness, C.B.; Cena, R.J.; Aiman, W.R.; Stephens, D.R.

    1980-05-20T23:59:59.000Z

    A major objective of the US Energy Program is the development of processes to produce clean fuels from coal. Underground coal gasification is one of the most promising of these processes. If successful, underground coal gasification (UCG) would quadruple the proven reserves of the US coal. Cost for products produced from UCG are projected to be 65 to 75% of those from conventional coal conversion. Finally, UCG appears to possess environmental advantages since no mining is involved and there are less solid wastes produced. In this paper we describe results from the Hoe Creek No. 3 underground coal gasification test. The experiment employed a drilled channel between process wells spaced 130' apart. The drilled channel was enlarged by reverse combustion prior to forward gasification. The first week of forward gasification was carried out using air injection, during which 250 tons of coal were consumed yielding an average dry product gas heating value of 114 Btu/scf. Following this phase, steam and oxygen were injected (generally a 50-50 mixture) for 47 days, during which 3945 tons of coal were consumed at an average rate of 84 tons of coal per day and an average dry gas heating value of 217 Btu/scf. The average gas composition during the steam-oxygen phase was 37% H/sub 2/, 5% CH/sub 4/, 11% CO, and 44% CO/sub 2/. Gas recovery was approximately 82% during the test, and the average thermochemical efficiency was near 65%.

  15. The Caterpillar Coal Gasification Facility

    E-Print Network [OSTI]

    Welsh, J.; Coffeen, W. G., III

    1983-01-01T23:59:59.000Z

    This paper is a review of one of America's premier coal gasification installations. The caterpillar coal gasification facility located in York, Pennsylvania is an award winning facility. The plant was recognized as the 'pace setter plant of the year...

  16. Hydrogen from Coal Edward Schmetz

    E-Print Network [OSTI]

    Turbines Carbon Capture & Sequestration Carbon Capture & Sequestration The Hydrogen from Coal Program Cells, Turbines, and Carbon Capture & Sequestration #12;Production Goal for Hydrogen from Coal Central Separation System PSA Membrane Membrane Carbon Sequestration Yes (87%) Yes (100%) Yes (100%) Hydrogen

  17. The world price of coal

    E-Print Network [OSTI]

    Ellerman, A. Denny

    1994-01-01T23:59:59.000Z

    A significant increase in the seaborne trade for coal over the past twenty years has unified formerly separate coal markets into a world market in which prices move in tandem. Due to its large domestic market, the United ...

  18. Low-rank coal research

    SciTech Connect (OSTI)

    Weber, G. F.; Laudal, D. L.

    1989-01-01T23:59:59.000Z

    This work is a compilation of reports on ongoing research at the University of North Dakota. Topics include: Control Technology and Coal Preparation Research (SO{sub x}/NO{sub x} control, waste management), Advanced Research and Technology Development (turbine combustion phenomena, combustion inorganic transformation, coal/char reactivity, liquefaction reactivity of low-rank coals, gasification ash and slag characterization, fine particulate emissions), Combustion Research (fluidized bed combustion, beneficiation of low-rank coals, combustion characterization of low-rank coal fuels, diesel utilization of low-rank coals), Liquefaction Research (low-rank coal direct liquefaction), and Gasification Research (hydrogen production from low-rank coals, advanced wastewater treatment, mild gasification, color and residual COD removal from Synfuel wastewaters, Great Plains Gasification Plant, gasifier optimization).

  19. Surface Coal Mining Regulations (Mississippi)

    Broader source: Energy.gov [DOE]

    The Surface Coal Mining Regulations are a combination of permitting requirements and environmental regulations that limit how, where and when coal can be mined. It protects lands that are under...

  20. Montana Coal Mining Code (Montana)

    Broader source: Energy.gov [DOE]

    The Department of Labor and Industry is authorized to adopt rules pertaining to safety standards for all coal mines in the state. The Code requires coal mine operators to make an accurate map or...

  1. 2009 Coal Age Buyers Guide

    SciTech Connect (OSTI)

    NONE

    2009-07-15T23:59:59.000Z

    The buyers guide lists more than 1200 companies mainly based in the USA, that provide equipment and services to US coal mines and coal preparation plants. The guide is subdivided by product categories.

  2. The Asia-Pacific coal technology conference

    SciTech Connect (OSTI)

    Not Available

    1990-02-01T23:59:59.000Z

    The Asia-Pacific coal technology conference was held in Honolulu, Hawaii, November 14--16, 1989. Topics discussed included the following: Expanded Horizons for US Coal Technology and Coal Trade; Future Coal-Fired Generation and Capacity Requirements of the Philippines; Taiwan Presentation; Korean Presentation; Hong Kong Future Coal Requirements; Indonesian Presentation; Electric Power System in Thailand; Coal in Malaysia -- A Position Paper; The US and Asia: Pacific Partners in Coal and Coal Technology; US Coal Production and Export; US Clean Coal Technologies; Developments in Coal Transport and Utilization; Alternative/Innovative Transport; Electricity Generation in Asia and the Pacific: Power Sector Demand for Coal, Oil and Natural Gas; Role of Clean Coal Technology in the Energy Future of the World; Global Climate Change: A Fossil Energy Perspective; Speaker: The Role of Coal in Meeting Hawaii's Power Needs; and Workshops on Critical Issues Associated with Coal Usage. Individual topics are processed separately for the data bases.

  3. Ashing properties of coal blends

    SciTech Connect (OSTI)

    Biggs, D.L.

    1982-03-01T23:59:59.000Z

    The fusion properties of sulfur materials present in coals were investigated. The treatment of the samples of eleven different coals is described. Thermal treatment of low temperature ashing (LTA) concentrates of eight of the coals was performed, and raw and wash ashing curves were examined to determine what quantitative correlations, if any, exist between ashing parameters and rank of coal. The actual form of the function which describes the ashing curve is derived.

  4. DEVELOPMENT OF CONTINUOUS SOLVENT EXTRACTION PROCESSES FOR COAL DERIVED CARBON PRODUCTS

    SciTech Connect (OSTI)

    Elliot B. Kennel; Chong Chen; Dady Dadyburjor; Liviu Magean; Peter G. Stansberry; Alfred H. Stiller; John W. Zondlo

    2005-07-13T23:59:59.000Z

    The purpose of this DOE-funded effort is to develop continuous processes for solvent extraction of coal for the production of carbon products. These carbon products include materials used in metals smelting, especially in the aluminum and steel industries, as well as porous carbon structural material referred to as ''carbon foam'' and carbon fibers. The Hydrotreatment Facility is being prepared for trials with coal liquids. Raw coal tar distillate trials have been carried out by heating coal tar in the holding tank in the Hydrotreatment Facility. The liquids are centrifuged to warm the system up in preparation for the coal liquids. The coal tar distillate is then recycled to keep the centrifuge hot. In this way, the product has been distilled such that a softening point of approximately 110 C is reached. Then an ash test is conducted.

  5. Coal as a fuel: a user's viewpoint. [Bowling Green State University, Ohio

    SciTech Connect (OSTI)

    Clodding, C.L.

    1980-01-01T23:59:59.000Z

    The problems of a university heating plant burning 25,000 tons of coal per year are described. You cannot burn pulverized coal like the large electric utilities do, but have to use stoker-fed boilers. These have very specific requirements on the coal, so detailed specifications on the coal size, sulfur, volatile matter, ashes, moisture, etc. are required. There are several materials handling problems related to delivery of the coal, stockpiling, reclaiming, feeding, ash handling, etc. Truck delivery is relatively straightforward but expensive; rail delivery of one, or a few cars of coal, which is often frozen and hard to get out of the cars, presents several problems and is also somewhat expensive. (LTN)

  6. Conversion system overview assessment. Volume III. Solar thermal/coal or biomass derived fuels

    SciTech Connect (OSTI)

    Copeland, R. J.

    1980-02-01T23:59:59.000Z

    The three volumes of this report cover three distinct areas of solar energy research: solar thermoelectrics, solar-wind hybrid systems, and synthetic fuels derived with solar thermal energy. Volume III deals with the conversion of synthetic fuels with solar thermal heat. The method is a hybrid combination of solar energy with either coal or biomass. A preliminary assessment of this technology is made by calculating the cost of fuel produced as a function of the cost of coal and biomass. It is shown that within the projected ranges of coal, biomass, and solar thermal costs, there are conditions when solar synthetic fuels with solar thermal heat will become cost-competitive.

  7. Stabilized thermally beneficiated low rank coal and method of manufacture

    DOE Patents [OSTI]

    Viall, Arthur J. (Colstrip, MT); Richards, Jeff M. (Colstrip, MT)

    2000-01-01T23:59:59.000Z

    A process for reducing the spontaneous combustion tendencies of thermally beneficiated low rank coals employing heat, air or an oxygen containing gas followed by an optional moisture addition. Specific reaction conditions are supplied along with knowledge of equipment types that may be employed on a commercial scale to complete the process.

  8. Stabilized thermally beneficiated low rank coal and method of manufacture

    DOE Patents [OSTI]

    Viall, Arthur J. (Colstrip, MT); Richards, Jeff M. (Colstrip, MT)

    1999-01-01T23:59:59.000Z

    A process for reducing the spontaneous combustion tendencies of thermally beneficiated low rank coals employing heat, air or an oxygen containing gas followed by an optional moisture addition. Specific reaction conditions are supplied along with knowledge of equipment types that may be employed on a commercial scale to complete the process.

  9. Stabilized thermally beneficiated low rank coal and method of manufacture

    DOE Patents [OSTI]

    Viall, A.J.; Richards, J.M.

    1999-01-26T23:59:59.000Z

    A process is described for reducing the spontaneous combustion tendencies of thermally beneficiated low rank coals employing heat, air or an oxygen containing gas followed by an optional moisture addition. Specific reaction conditions are supplied along with knowledge of equipment types that may be employed on a commercial scale to complete the process. 3 figs.

  10. Mercury emission behavior during isolated coal particle combustion

    E-Print Network [OSTI]

    Puchakayala, Madhu Babu

    2009-05-15T23:59:59.000Z

    ppb and 140ppb. In order to understand the basic process of formulation of HgCl2 and Hg0 a numerical model is developed in the current work to simulate in the detail i) heating ii) transient pyrolysis of coal and evolution of mercury and chlorine, iii...

  11. Pricetown I underground coal gasification field test: operations report

    SciTech Connect (OSTI)

    Agarwal, A.K.; Seabaugh, P.W.; Zielinski, R.E.

    1981-01-01T23:59:59.000Z

    An Underground Coal Gasification (UCG) field test in bituminous coal was successfully completed near Pricetown, West Virginia. The primary objective of this field test was to determine the viability of the linked vertical well (LVV) technology to recover the 900 foot deep, 6 foot thick coal seam. A methane rich product gas with an average heating value of approximately 250 Btu/SCF was produced at low air injection flow rates during the reverse combustion linkage phase. Heating value of the gas produced during the linkage enhancement phase was 221 Btu/SCF with air injection. The high methane formation has been attributed to the thermal and hydrocracking of tars and oils along with hydropyrolysis and hydrogasification of coal char. The high heating value of the gas was the combined effect of residence time, flow pattern, injection flow rate, injection pressure, and back pressure. During the gasification phase, a gas with an average heating value of 125 Btu/SCF was produced with only air injection, which resulted in an average energy production of 362 MMBtu/day.

  12. Pyrolysis of coal

    DOE Patents [OSTI]

    Babu, Suresh P. (Willow Springs, IL); Bair, Wilford G. (Morton Grove, IL)

    1992-01-01T23:59:59.000Z

    A method for mild gasification of crushed coal in a single vertical elongated reaction vessel providing a fluidized bed reaction zone, a freeboard reaction zone, and an entrained reaction zone within the single vessel. Feed coal and gas may be fed separately to each of these reaction zones to provide different reaction temperatures and conditions in each reaction zone. The reactor and process of this invention provides for the complete utilization of a coal supply for gasification including utilization of caking and non-caking or agglomerating feeds in the same reactor. The products may be adjusted to provide significantly greater product economic value, especially with respect to desired production of char having high surface area.

  13. Healy Clean Coal Project

    SciTech Connect (OSTI)

    None

    1997-12-31T23:59:59.000Z

    The Healy Clean Coal Project, selected by the U.S. Department of Energy under Round 111 of the Clean Coal Technology Program, has been constructed and is currently in the Phase 111 Demonstration Testing. The project is owned and financed by the Alaska Industrial Development and Export Authority (AIDEA), and is cofunded by the U.S. Department of Energy. Construction was 100% completed in mid-November of 1997, with coal firing trials starting in early 1998. Demonstration testing and reporting of the results will take place in 1998, followed by commercial operation of the facility. The emission levels of nitrogen oxides (NOx), sulfur dioxide (S02), and particulate from this 50-megawatt plant are expected to be significantly lower than current standards.

  14. Co-combustion of refuse derived fuel and coal in a cyclone furnace at the Baltimore Gas and Electric Company, C. P. Crane Station

    SciTech Connect (OSTI)

    Not Available

    1982-03-01T23:59:59.000Z

    A co-combustion demonstration burn of coal and fluff refuse-derived fuel (RDF) was conducted by Teledyne National and Baltimore Gas and Electric Company. This utility has two B and W cyclone furnaces capable of generating 400 MW. The facility is under a prohibition order to convert from No. 6 oil to coal; as a result, it was desirable to demonstrate that RDF, which has a low sulfur content, can be burned in combination with coals containing up to 2% sulfur, thus reducing overall sulfur emissions without deleterious effects. Each furnace consists of four cyclones capable of generating 1,360,000 pounds per hour steam. The tertiary air inlet of one of the cyclones was modified with an adapter to permit fluff RDF to be pneumatically blown into the cyclone. At the same time, coal was fed into the cyclone furnace through the normal coal feeding duct, where it entered the burning chamber tangentially and mixed with the RDF during the burning process. Secondary shredded fluff RDF was prepared by the Baltimore County Resource Recovery Facility. The RDF was discharged into a receiving station consisting of a belt conveyor discharging into a lump breaker, which in turn, fed the RDF into a pneumatic line through an air-lock feeder. A total of 2316 tons were burned at an average rate of 5.6 tons per hour. The average heat replacement by RDF for the cyclone was 25%, based on Btu input for a period of forty days. The range of RDF burned was from 3 to 10 tons per hour, or 7 to 63% heat replacement. The average analysis of the RDF (39 samples) for moisture, ash, heat (HHV) and sulfur content were 18.9%, 13.4%, 6296 Btu/lb and 0.26% respectively. RDF used in the test was secondary shredded through 1-1/2 inch grates producing the particle size distribution of from 2 inches to .187 inches. Findings to date after inspection of the boiler and superheater indicate satisfactory results with no deleterious effects from the RDF.

  15. CONSORTIUM FOR CLEAN COAL UTILIZATION

    E-Print Network [OSTI]

    Subramanian, Venkat

    CONSORTIUM FOR CLEAN COAL UTILIZATION Call for Proposals Date of Issue: July 29, 2013 The Consortium for Clean Coal Utilization (CCCU) at Washington University in St. Louis was established in January of Clean Coal Utilization. The format may be a conference or workshop, or a seminar given by a leading

  16. Applications of micellar enzymology to clean coal technology. Tenth quarterly report

    SciTech Connect (OSTI)

    Walsh, C.T.

    1992-04-29T23:59:59.000Z

    Full implementation of coal fuel sources will require more effective methods of providing ``clean coal`` as a fuel source. Methods must be developed to reduce the sulfur content of coal which significantly contributes to environmental pollution. This project is designed to develop methods for pre-combustion coal remediation by implementing recent advances in enzyme biochemistry. The novel approach of this study is incorporation of hydrophilic oxidative enzymes in reverse micelles in an organic solvent. Enzymes from commercial sources or microbial extracts are being investigated for their capacity to remove organic sulfur from coal by oxidation of the sulfur groups, splitting of C-S bonds and loss of sulfur as sulfuric acid. Dibenzothiophene (DBT) and ethylphenylsulfide (EPS) are serving as models of organic sulfur-containing components of coal in initial studies.

  17. Photochemical oxidation of coals and some selected model compounds by using copper(II) chloride

    SciTech Connect (OSTI)

    Yilmaz, M.

    1999-12-01T23:59:59.000Z

    The H-donor ability of different rank coals was examined by using a copper(II)chloride-acetonitrile system as the dehydrogenator. A bituminous coal and two lignites were irradiated in the UV in the presence of copper(II)chloride in acetonitrile. The coal was dehydrogenated while the Cu(II) was reduced to CU(I). Considerable amounts of aliphatic or alicyclic hydrogen were removed from the coals. In the process, while the oxygen contents of coals do not increase, more condensed aromatic products occur. It was concluded that lignites are better reducing agents than bituminous coals. A photooxidation mechanism is proposed on the basis of the model compound reaction. Photooxidation of alcohols (ethanol, 2-propanol, benzyl alcohol, 4-hydroxybenzyl alcohol, and diphenyl carbinol), a hydroaromatic compound (tetrahydronaphthalene), and an aromatic ether (dibenzyl ether) was performed under similar reaction conditions.

  18. Petrographic and geochemical anatomy of lithotypes from the Blue Gem coal bed, Southeastern Kentucky

    SciTech Connect (OSTI)

    Hower, J.C.; Taulbee, D.N.; Morrell, L.G. [Univ. of Kentucky, Lexington, KY (United States)] [and others

    1994-12-31T23:59:59.000Z

    The nature of the association of major, minor, and trace elements with coal has been the subject of intensive research by coal scientists (Swaine; and references cited therein). Density gradient centrifugation (DGC) offers a technique with which ultrafine coal particles can be partitioned into a density spectrum, portions of which represent nearly pure monomaceral concentrates. DGC has been typically conducted on demineralized coals assuring, particularly at lower specific gravities, that the resulting DGC fractions would have very low ash contents. In order to determine trends in elemental composition, particularly with a view towards maceral vs. mineral association, it is necessary to avoid demineralization. To this end the low-ash, low-sulfur Blue Gem coal bed (Middle Pennsylvanian Breathitt Formation) from Knox County, Kentucky, was selected for study. The objective of this study was to determine the petrography and chemistry, with particular emphasis on the ash geochemistry, of DGC separates of lithotypes of the Blue Gem coal bed.

  19. PNNL Coal Gasification Research

    SciTech Connect (OSTI)

    Reid, Douglas J.; Cabe, James E.; Bearden, Mark D.

    2010-07-28T23:59:59.000Z

    This report explains the goals of PNNL in relation to coal gasification research. The long-term intent of this effort is to produce a syngas product for use by internal Pacific Northwest National Laboratory (PNNL) researchers in materials, catalysts, and instrumentation development. Future work on the project will focus on improving the reliability and performance of the gasifier, with a goal of continuous operation for 4 hours using coal feedstock. In addition, system modifications to increase operational flexibility and reliability or accommodate other fuel sources that can be used for syngas production could be useful.

  20. Clean Coal Power Initiative

    SciTech Connect (OSTI)

    Doug Bartlett; Rob James; John McDermott; Neel Parikh; Sanjay Patnaik; Camilla Podowski

    2006-03-31T23:59:59.000Z

    This report is the fifth quarterly Technical Progress Report submitted by NeuCo, Incorporated, under Award Identification Number, DE-FC26-04NT41768. This award is part of the Clean Coal Power Initiative (''CCPI''), the ten-year, $2B initiative to demonstrate new clean coal technologies in the field. This report is one of the required reports listed in Attachment B Federal Assistance Reporting Checklist, part of the Cooperative Agreement. The report covers the award period January 1, 2006 - March 31, 2006 and NeuCo's efforts within design, development, and deployment of on-line optimization systems during that period.

  1. E-Print Network 3.0 - anomalous specific heat Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    be important for redistributing the anomalous heat content in the hot spot region to the remote Tropics... . The anomalous heat content of ... Source: Sobel, Adam - Department of...

  2. Mining conditions and deposition in the Amburgy (Westphalian B) coal, Breathitt Group, central Appalachian basin

    SciTech Connect (OSTI)

    Greb, S.F.; Eble, C.F. [Kentucky Geological Survey, Lexington, KY (United States); Hower, J.C. [Center for Applied Research, Lexington, KY (United States); Phillips, T.L. [Univ. of illinois, Urbana, IL (United States)

    1996-09-01T23:59:59.000Z

    Carbonate concretions called clay balls are rare in the Central Appalachian Basin, but were found in the Amburgy coal overlain by the Kendrick Shale Member. In the study area, the Amburgy coal is 0.7 to 0.9 meters thick, moderate to high in sulfur content, moderate to high in ash yield, and mostly bright clarain, except at the top near the area of coal balls, where durain of limited extent occurs. The coal is co-dominated by lycopod and cordaites; tree spores, with subordinate Calamites. The local durain layer is dominated by Densosporites, produced by the shrubby lycopod Ompbalophloios. Coal balls were encountered where the durain is immediately overlain by a coquinoid hash of broken and whole marine fossils, along a trend of coal thinning. The coal balls contain permineralized cordaites, lycopods, calamites, and ferns. The Amburgy coal accumulated as a succession of planar mires. Local splits in the seam are common, indicating contemporaneous clastic influx. The abundance of Cordaites may indicate brackish mire waters related to a coastal position and initial eustatic rise of the marginal Kendrick seas. Near the end of the Amburgy mires, the high ash-Omphalopbloios association is interpreted as a local area that was being drowned by the Kendrick transgression. Ravinement within this local embayment, rapid inundation by marine waters, and concentration of carbonate-bearing waters within transgressive scours may have contributed to the formation of coal balls and pyritic concretions in the upper part of the coal bed.

  3. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul Aug SepAnnual",2013Annual",2014 ,"ReleaseAnnual",2014Bcf)"ImportsDeliveries toHeatHeatHeatHeatHeatHeat

  4. apec coal flow: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from pulverized coal pulverized-coal-fired furnaces, cyclone furnaces, or advanced clean-coal technology furnaces. The ash collected from pulverized-coal-fired furnaces is fly...

  5. alkaline coal ash: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from pulverized coal pulverized-coal-fired furnaces, cyclone furnaces, or advanced clean-coal technology furnaces. The ash collected from pulverized-coal-fired furnaces is fly...

  6. Advanced coal conversion process demonstration. Technical progress report for the period July 1, 1995--September 30, 1995

    SciTech Connect (OSTI)

    NONE

    1997-05-01T23:59:59.000Z

    This report describes the technical progress made on the Advanced Coal Conversion Process (ACCP) Demonstration Project from July 1, 1995 through September 30, 1995. The ACCP Demonstration Project is a US Department of Energy (DOE) Clean Coal Technology Project. This project demonstrates an advanced, thermal, coal upgrading process, coupled with physical cleaning techniques, that is designed to upgrade high-moisture, low-rank coals to a high-quality, low-sulfur fuel, registered as the SynCoal process. The coal is processed through three stages (two heating stages followed by an inert cooling stage) of vibrating fluidized bed reactors that remove chemically bound water, carboxyl groups, and volatile sulfur compounds. After thermal upgrading, the cola is put through a deep-bed stratifier cleaning process to separate the pyrite-rich ash from the coal.

  7. Air/water oxydesulfurization of coal: laboratory investigation

    SciTech Connect (OSTI)

    Warzinski, R. P.; Friedman, S.; Ruether, J. A.; LaCount, R. B.

    1980-08-01T23:59:59.000Z

    Air/water oxidative desulfurization has been demonstrated in autoclave experiments at the Pittsburgh Energy Technology Center for various coals representative of the major US coal basins. This experimentation has shown that the reaction proceeds effectively for pulverized coals at temperatures of 150 to 200/sup 0/C with air at a total system pressure of 500 to 1500 psig. Above 200/sup 0/C, the loss of coal and product heating value increases due to oxidative consumption of carbon and hydrogen. The pyritic sulfur solubilization reactions are typically complete (95 percent removal) within 15 to 40 minutes at temperature; however, significant apparent organic sulfur removal requires residence times of up to 60 minutes at the higher temperatures. The principal products of the reaction are sulfuric acid, which can be neutralized with limestone, and iron oxide. Under certain conditions, especially for high pyritic sulfur coals, the precipitation of sulfur-containing compounds from the products of the pyrite reaction may cause anomalous variations in the sulfur form data. The influence of various parameters on the efficiency of sulfur removal from coal by air/water oxydesulfurization has been studied.

  8. In-situ coal-gasification data look promising

    SciTech Connect (OSTI)

    Not Available

    1980-07-21T23:59:59.000Z

    According to a report given at the 6th Underground Coal Conversion Symposium (Afton, Oklahoma 1980), the Hoe Creek No. 3 underground coal-gasification experiments Oil Gas J. 77 sponsored by the U.S. Department of Energy and the Gas Research Institute and directed by the University of California Lawrence Livermore Laboratory demonstrated the feasibility of in-situ coal conversion and featured the use of a directionally drilled channel to connect the injection and production wells rather than the reverse-burn ordinarily used to produce the connecting channel. In the test, 2816 cu m of coal weighing (APPROX) 4200 tons was consumed, with (APPROX) 18% of the product gas escaping through the overburden or elsewhere. When air injection was used, the average heating value was 217 Btu/std cu ft. The average thermal efficiency of the burn was 65%, and the average gas composition was 35% hydrogen, 5% methane, 11% carbon monoxide, and 44% carbon dioxide. Subsidence occurred after completion of the test. The Uniwell gasification method, scheduled for use in the final experiment in the Deep-1 series of underground coal-gasification tests in Wyoming, seeks to prevent subsidence by use of concentric pipes which are inserted into the vertical well to control the combustion zone. Underground coal-gasification prospects and the mechanics of subsidence are discussed.

  9. CO2 SEQUESTRATION POTENTIAL OF TEXAS LOW-RANK COALS

    SciTech Connect (OSTI)

    Duane A. McVay; Walter B. Ayers Jr; Jerry L. Jensen

    2004-11-01T23:59:59.000Z

    The objectives of this project are to evaluate the feasibility of carbon dioxide (CO{sub 2}) sequestration in Texas low-rank coals and to determine the potential for enhanced coalbed methane (CBM) recovery as an added benefit of sequestration. there were two main objectives for this reporting period. first, they wanted to collect wilcox coal samples from depths similar to those of probable sequestration sites, with the objective of determining accurate parameters for reservoir model description and for reservoir simulation. The second objective was to pursue opportunities for determining permeability of deep Wilcox coal to use as additional, necessary data for modeling reservoir performance during CO{sub 2} sequestration and enhanced coalbed methane recovery. In mid-summer, Anadarko Petroleum Corporation agreed to allow the authors to collect Wilcox Group coal samples from a well that was to be drilled to the Austin Chalk, which is several thousand feet below the Wilcox. In addition, they agreed to allow them to perform permeability tests in coal beds in an existing shut-in well. Both wells are in the region of the Sam K. Seymour power station, a site that they earlier identified as a major point source of CO{sub 2}. They negotiated contracts for sidewall core collection and core analyses, and they began discussions with a service company to perform permeability testing. To collect sidewall core samples of the Wilcox coals, they made structure and isopach maps and cross sections to select coal beds and to determine their depths for coring. On September 29, 10 sidewall core samples were obtained from 3 coal beds of the Lower Calvert Bluff Formation of the Wilcox Group. The samples were desorbed in 4 sidewall core canisters. Desorbed gas samples were sent to a laboratory for gas compositional analyses, and the coal samples were sent to another laboratory to measure CO{sub 2}, CH{sub 4}, and N{sub 2} sorption isotherms. All analyses should be finished by the end of December. A preliminary report shows methane content values for the desorbed coal samples ranged between 330 and 388 scf/t., on ''as received'' basis. Residual gas content of the coals was not included in the analyses, which results in an approximate 5-10% underestimation of in-situ gas content. Coal maps indicate that total coal thickness is 40-70 ft in the Lower Calvert Bluff Formation of the Wilcox Group in the vicinity of the Sam K. Seymour power plant. A conservative estimate indicates that methane in place for a well on 160-acre spacing is approximately 3.5 Bcf in Lower Calvert Bluff coal beds. When they receive sorption isotherm data from the laboratory, they will determine the amount of CO{sub 2} that it may be possible to sequester in Wilcox coals. In December, when the final laboratory and field test data are available, they will complete the reservoir model and begin to simulate CO{sub 2} sequestration and enhanced CH{sub 4} production.

  10. Catalytic coal liquefaction process

    DOE Patents [OSTI]

    Garg, D.; Sunder, S.

    1986-12-02T23:59:59.000Z

    An improved process for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a solvent comprises using as catalyst a mixture of a 1,2- or 1,4-quinone and an alkaline compound, selected from ammonium, alkali metal, and alkaline earth metal oxides, hydroxides or salts of weak acids. 1 fig.

  11. Biochemical transformation of coals

    DOE Patents [OSTI]

    Lin, M.S.; Premuzic, E.T.

    1999-03-23T23:59:59.000Z

    A method of biochemically transforming macromolecular compounds found in solid carbonaceous materials, such as coal is provided. The preparation of new microorganisms, metabolically weaned through challenge growth processes to biochemically transform solid carbonaceous materials at extreme temperatures, pressures, pH, salt and toxic metal concentrations is also disclosed. 7 figs.

  12. Catalytic coal liquefaction process

    DOE Patents [OSTI]

    Garg, Diwakar (Macungie, PA); Sunder, Swaminathan (Allentown, PA)

    1986-01-01T23:59:59.000Z

    An improved process for catalytic solvent refining or hydroliquefaction of non-anthracitic coal at elevated temperatures under hydrogen pressure in a solvent comprises using as catalyst a mixture of a 1,2- or 1,4-quinone and an alkaline compound, selected from ammonium, alkali metal, and alkaline earth metal oxides, hydroxides or salts of weak acids.

  13. Catalytic coal hydroliquefaction process

    DOE Patents [OSTI]

    Garg, Diwakar (Macungie, PA)

    1984-01-01T23:59:59.000Z

    A process is described for the liquefaction of coal in a hydrogen donor solvent in the presence of hydrogen and a co-catalyst combination of iron and a Group VI or Group VIII non-ferrous metal or compounds of the catalysts.

  14. Heat pipe array heat exchanger

    DOE Patents [OSTI]

    Reimann, Robert C. (Lafayette, NY)

    1987-08-25T23:59:59.000Z

    A heat pipe arrangement for exchanging heat between two different temperature fluids. The heat pipe arrangement is in a ounterflow relationship to increase the efficiency of the coupling of the heat from a heat source to a heat sink.

  15. Coal mine methane global review

    SciTech Connect (OSTI)

    NONE

    2008-07-01T23:59:59.000Z

    This is the second edition of the Coal Mine Methane Global Overview, updated in the summer of 2008. This document contains individual, comprehensive profiles that characterize the coal and coal mine methane sectors of 33 countries - 22 methane to market partners and an additional 11 coal-producing nations. The executive summary provides summary tables that include statistics on coal reserves, coal production, methane emissions, and CMM projects activity. An International Coal Mine Methane Projects Database accompanies this overview. It contains more detailed and comprehensive information on over two hundred CMM recovery and utilization projects around the world. Project information in the database is updated regularly. This document will be updated annually. Suggestions for updates and revisions can be submitted to the Administrative Support Group and will be incorporate into the document as appropriate.

  16. Coal diesel combined-cycle project. Comprehensive report to Congress: Clean Coal Technology Program

    SciTech Connect (OSTI)

    Not Available

    1994-05-01T23:59:59.000Z

    One of the projects selected for funding is a project for the design, construction, and operation of a nominal 90 ton-per-day 14-megawatt electrical (MWe), diesel engine-based, combined-cycle demonstration plant using coal-water fuels (CWF). The project, named the Coal Diesel Combined-Cycle Project, is to be located at a power generation facility at Easton Utilities Commission`s Plant No. 2 in Easton, Talbot County, Maryland, and will use Cooper-Bessemer diesel engine technology. The integrated system performance to be demonstrated will involve all of the subsystems, including coal-cleaning and slurrying systems; a selective catalytic reduction (SCR) unit, a dry flue gas scrubber, and a baghouse; two modified diesel engines; a heat recovery steam generation system; a steam cycle; and the required balance of plant systems. The base feedstock for the project is bituminous coal from Ohio. The purpose of this Comprehensive Report is to comply with Public Law 102-154, which directs the DOE to prepare a full and comprehensive report to Congress on each project selected for award under the CCT-V Program.

  17. Thermal-Hydrological Sensitivity Analysis of Underground Coal Gasification

    SciTech Connect (OSTI)

    Buscheck, T A; Hao, Y; Morris, J P; Burton, E A

    2009-10-05T23:59:59.000Z

    This paper presents recent work from an ongoing project at Lawrence Livermore National Laboratory (LLNL) to develop a set of predictive tools for cavity/combustion-zone growth and to gain quantitative understanding of the processes and conditions (natural and engineered) affecting underground coal gasification (UCG). We discuss the application of coupled thermal-hydrologic simulation capabilities required for predicting UCG cavity growth, as well as for predicting potential environmental consequences of UCG operations. Simulation of UCG cavity evolution involves coupled thermal-hydrological-chemical-mechanical (THCM) processes in the host coal and adjoining rockmass (cap and bedrock). To represent these processes, the NUFT (Nonisothermal Unsaturated-saturated Flow and Transport) code is being customized to address the influence of coal combustion on the heating of the host coal and adjoining rock mass, and the resulting thermal-hydrological response in the host coal/rock. As described in a companion paper (Morris et al. 2009), the ability to model the influence of mechanical processes (spallation and cavity collapse) on UCG cavity evolution is being developed at LLNL with the use of the LDEC (Livermore Distinct Element Code) code. A methodology is also being developed (Morris et al. 2009) to interface the results of the NUFT and LDEC codes to simulate the interaction of mechanical and thermal-hydrological behavior in the host coal/rock, which influences UCG cavity growth. Conditions in the UCG cavity and combustion zone are strongly influenced by water influx, which is controlled by permeability of the host coal/rock and the difference between hydrostatic and cavity pressure. In this paper, we focus on thermal-hydrological processes, examining the relationship between combustion-driven heat generation, convective and conductive heat flow, and water influx, and examine how the thermal and hydrologic properties of the host coal/rock influence those relationships. Specifically, we conducted a parameter sensitivity analysis of the influence of thermal and hydrological properties of the host coal, caprock, and bedrock on cavity temperature and steam production.

  18. Eight Advanced Coal Projects Chosen for Further Development by DOE's University Coal Research Program

    Broader source: Energy.gov [DOE]

    DOE has selected eight new projects to further advanced coal research under the University Coal Research Program. The selected projects will improve coal conversion and use and will help propel technologies for future advanced coal power systems.

  19. Briquette comprising caking coal and municipal solid waste

    SciTech Connect (OSTI)

    Schulz, H.W.

    1980-09-30T23:59:59.000Z

    Briquettes of specified geometry and composition are produced to serve as feed material or ''burden'' in a moving-burden gasifier for the production of a synthesis or fuel gas from organic solid waste materials and coal, including especially, the so-called ''caking'' coals, as in the process of copending application number 675,918. The briquettes are formed from a well-blended mixture of shredded organic solid wastes, including especially, municipal solid waste (Msw) or biomass, and crushed caking coal, including coal fines. A binder material may or may not be required, depending on the coal/msw ratio and the compaction pressure employed. The briquettes may be extruded, stamped, or pressed, employing compaction pressures in excess of 1000 psi, and preferably in the range of 2000 to 10,000 psi. The briquettes may be circular, polygonal, or irregular in cross-section; they may be solid, or concentrically perforated to form a hollow cylinder or polygon; they may be formed into saddles, pillows or doughnuts. The ratio of caking coal to shredded municipal solid waste is controlled so that each part of the predominantly cellulosic organic solid waste will be blended with 0.5 to 3.0 parts of crushed coal. Suitable binder materials include dewatered sewage slude (Dss), ''black liquor'' rich in lignin derivatives, black strap molasses, waste oil, and starch. The binder concentration is preferably in the range of 2 to 6 percent. If coals high in sulfur content are to be processed, at least a stoichiometric equivalent of dolomite may be included in the briquette formulation to eliminate a major fraction of the sulfur with the slag.

  20. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul Aug SepAnnual",2013Annual",2014 ,"ReleaseAnnual",2014Bcf)"ImportsDeliveries toHeatHeatHeatHeatHeat

  1. Gasifier feed: Tailor-made from Illinois coals. Interim final technical report, September 1, 1991--August 31, 1992

    SciTech Connect (OSTI)

    Ehrlinger, H.P. III; Lytle, J.; Frost, R.R.; Lizzio, A.; Kohlenberger, L.; Brewer, K. [Illinois State Geological Survey, Champaign, IL (United States)

    1992-12-31T23:59:59.000Z

    The main purpose of this project is to produce a feedstock from preparation plant fines from an Illinois coal that is ideal for a slurry fed, slagging, entrained-flow coal gasifier. The high sulfur content and high Btu value of Illinois coals are particularly advantageous in such a gasifier; preliminary calculations indicate that the increased cost of removing sulfur from the gas from a high sulfur coal is more than offset by the increased revenue from the sale of the elemental sulfur; additionally the high Btu Illinois coal concentrates more energy into the slurry of a given coal to water ratio. The Btu is higher not only because of the higher Btu value of the coal but also because Illinois coal requires less water to produce a pumpable slurry than western coal, i.e., as little as 30--35% water may be used for Illinois coal as compared to approximately 45% for most western coals. Destec Energy, a wholly-owned subsidiary of Dow Chemical Company, will provide guidelines and test compatibility of the slurries developed for gasification feedstock. Williams Technologies, Inc., will provide their expertise in long distance slurry pumping, and test selected products for viscosity, pumpability, and handleability. The Illinois State Geological Survey will study methods for producing clean coal/water slurries from preparation plant wastes including the concentration of pyritic sulfur into the coal slurry to increase the revenue from elemental sulfur produced during gasification operations, and decrease the pyritic sulfur content of the waste streams. ISGS will also test the gasification reactivity of the coals.

  2. Method for recovering light hydrocarbons from coal agglomerates

    DOE Patents [OSTI]

    Huettenhain, Horst (Benicia, CA); Benz, August D. (Hillsborough, CA); Getsoian, John (Ann Arbor, MI)

    1991-01-01T23:59:59.000Z

    A method and apparatus for removing light hydrocarbons, such as heptane, from coal agglomerates includes an enclosed chamber having a substantially horizontal perforate surface therein. The coal agglomerates are introduced into a water bath within the chamber. The agglomerates are advanced over the surface while steam is substantially continuously introduced through the surface into the water bath. Steam heats the water and causes volatilization of the light hydrocarbons, which may be collected from the overhead of the chamber. The resulting agglomerates may be collected at the opposite end from the surface and subjected to final draining processes prior to transportation or use.

  3. Flotation machine and process for removing impurities from coals

    DOE Patents [OSTI]

    Szymocha, Kazimierz (Edmonton, CA); Ignasiak, Boleslaw (Edmonton, CA); Pawlak, Wanda (Edmonton, CA); Kulik, Conrad (Newark, CA); Lebowitz, Howard E. (Mountain View, CA)

    1997-01-01T23:59:59.000Z

    The present invention is directed to a type of flotation machine that combines three separate operations in a single unit. The flotation machine is a hydraulic separator that is capable of reducing the pyrite and other mineral matter content of a coal. When the hydraulic separator is used with a flotation system, the pyrite and certain other minerals particles that may have been entrained by hydrodynamic forces associated with conventional flotation machines and/or by the attachment forces associated with the formation of microagglomerates are washed and separated from the coal.

  4. Flotation machine and process for removing impurities from coals

    DOE Patents [OSTI]

    Szymocha, Kazimierz (Edmonton, CA); Ignasiak, Boleslaw (Edmonton, CA); Pawlak, Wanda (Edmonton, CA); Kulik, Conrad (Newark, CA); Lebowitz, Howard E. (Mountain View, CA)

    1995-01-01T23:59:59.000Z

    The present invention is directed to a type of flotation machine that combines three separate operations in a single unit. The flotation machine is a hydraulic separator that is capable of reducing the pyrite and other mineral matter content of a coal. When the hydraulic separator is used with a flotation system, the pyrite and certain other minerals particles that may have been entrained by hydrodynamic forces associated with conventional flotation machines and/or by the attachment forces associated with the formation of microagglomerates are washed and separated from the coal.

  5. Wood-Coal Fired "Small" Boiler Case Study

    E-Print Network [OSTI]

    Pincelli, R. D.

    1980-01-01T23:59:59.000Z

    extremely attrac t:i.ve to today's capital investment market. 7. Several states, including North Carolina, have enacted 15% State Tax Credits to further the use of wood fuel boilers. Specific examples of the utilization of wood as a boiler fuel include... on the fact that Galaxy would be purchasing all of its waste wood fuel, as well as supplemental coal if needed. Efficiency guarantees of 80% on wood waste with less than 10% moisture content were given, as well as 78.5% on coal. These efficiencies were...

  6. Integrated coal preparation and CWF processing plant: Conceptual design and costing

    SciTech Connect (OSTI)

    McHale, E.T.; Paul, A.D.; Bartis, J.T. (Science Applications International Corp., McLean, VA (United States)); Korkmaz, M. (Roberts and Schaefer Co., Salt Lake City, UT (United States))

    1992-12-01T23:59:59.000Z

    At the request of the US Department of Energy (DOE), Pittsburgh Energy Technology Center, a study was conducted to provide DOE with a reliable, documented estimate of the cost of producing coal-water fuel (CWF). The approach to the project was to specify a plant capacity and location, identify and analyze a suitable coal, and develop a conceptual design for an integrated coal preparation and CWF processing plant. Using this information, a definitive costing study was then conducted, on the basis of which an economic and sensitivity analysis was performed utilizing a financial evaluation model to determine a price for CWF in 1992. The design output of the integrated plant is 200 tons of coal (dry basis) per hour. Operating at a capacity factor of 83 percent, the baseline design yields approximately 1.5 million tons per year of coal on a dry basis. This is approximately equivalent to the fuel required to continuously generate 500 MW of electric power. The CWF produced by the plant is intended as a replacement for heavy oil or gas in electric utility and large industrial boilers. The particle size distribution, particularly the top size, and the ash content of the coal in the CWF are specified at significantly lower levels than is commonly found in typical pulverized coal grinds. The particle top size is 125 microns (vs typically 300m[mu] for pulverized coal) and the coal ash content is 3.8 percent. The lower top size is intended to promote complete carbon burnout at less derating in boilers that are not designed for coal firing. The reduced mineral matter content will produce ash of very fine particle size during combustion, which leads to less impaction and reduced fouling of tubes in convective passages.

  7. Integrated coal preparation and CWF processing plant: Conceptual design and costing. Final technical report

    SciTech Connect (OSTI)

    McHale, E.T.; Paul, A.D.; Bartis, J.T. [Science Applications International Corp., McLean, VA (United States); Korkmaz, M. [Roberts and Schaefer Co., Salt Lake City, UT (United States)

    1992-12-01T23:59:59.000Z

    At the request of the US Department of Energy (DOE), Pittsburgh Energy Technology Center, a study was conducted to provide DOE with a reliable, documented estimate of the cost of producing coal-water fuel (CWF). The approach to the project was to specify a plant capacity and location, identify and analyze a suitable coal, and develop a conceptual design for an integrated coal preparation and CWF processing plant. Using this information, a definitive costing study was then conducted, on the basis of which an economic and sensitivity analysis was performed utilizing a financial evaluation model to determine a price for CWF in 1992. The design output of the integrated plant is 200 tons of coal (dry basis) per hour. Operating at a capacity factor of 83 percent, the baseline design yields approximately 1.5 million tons per year of coal on a dry basis. This is approximately equivalent to the fuel required to continuously generate 500 MW of electric power. The CWF produced by the plant is intended as a replacement for heavy oil or gas in electric utility and large industrial boilers. The particle size distribution, particularly the top size, and the ash content of the coal in the CWF are specified at significantly lower levels than is commonly found in typical pulverized coal grinds. The particle top size is 125 microns (vs typically 300m{mu} for pulverized coal) and the coal ash content is 3.8 percent. The lower top size is intended to promote complete carbon burnout at less derating in boilers that are not designed for coal firing. The reduced mineral matter content will produce ash of very fine particle size during combustion, which leads to less impaction and reduced fouling of tubes in convective passages.

  8. Exxon Chemical's Coal-Fired Combined Cycle Power Technology

    E-Print Network [OSTI]

    Guide, J. J.

    turbine arrangement with indirect heating of the air in the boile; convection section. The turbine exhaust is then used as pre-heated combustion air for the boiler. The air coil heats the 150 psig air from the standard gas turbine axial compressor... premium fuel (up to 2000 0 F permissible gas turbine tempera ture), CAT-PAC savings would double to 20%. Today, in an industrial coal-fired cogeneration plant, CAT-PAC can produce up to 75% more power for a given steam load, while maintaining...

  9. Coal-bed methane production in eastern Kansas: Its potential and restraints

    SciTech Connect (OSTI)

    Stoeckinger, B.T.

    1989-08-01T23:59:59.000Z

    In 1921 and again in 1988, workers demonstrated that the high volatile A and B coals of the Pennsylvanian Cherokee Group can be produced economically from vertically drilled holes, and that some of these coals have a gas content as high as 200 ft{sup 3}/ton. Detailed subsurface mapping on a county-by-county basis using geophysical logs shows the Weir coal seam to be the thickest (up to 6 ft thick) and to exist in numerous amoeba-shaped pockets covering several thousand acres. Lateral pinch-out into deltaic sands offers a conventional gas source. New attention to geophysical logging shows most coals have a negative SP response, high resistivities, and densities of 1.6 g/cm{sup 3}. Highly permeable coals cause lost circulation during drilling and thief zones during cementing, and they are the source of abundant unwanted salt water. Low-permeability coals can be recognized by their high fracture gradients, which are difficult to explain but are documented to exceed 2.2. Current successful completions use both limited-entry, small-volume nitrogen stimulations or an open hole below production casing. Subsurface coals are at normal Mid-Continent pressures and may be free of water. Initially, some wells flow naturally without pumping. Saltwater disposal is often helped by the need for water in nearby waterflood projects and the easy availability of state-approved saltwater disposal wells in Mississippi and Arbuckle carbonates. Recent attempts to recomplete coal zones in slim-hole completions are having mixed results. The major restraints to coal-bed methane production are restricted to low permeability of the coals and engineering problems, not to the availability or gas content of the coals.

  10. The evaluation of a coal-derived liquid as a feedstock for the production of high-density aviation turbine fuel

    SciTech Connect (OSTI)

    Thomas, K.P.; Hunter, D.E.

    1989-08-01T23:59:59.000Z

    The conversion of coal-derived liquids to transportation fuels has been the subject of many studies sponsored by the US Department of Energy and the US Department of Defense. For the most part, these studies evaluated conventional petroleum processes for the production of specification-grade fuels. Recently, however, the interest of these two departments expanded to include the evaluation of alternate fossil fuels as a feedstock for the production of high-density aviation turbine fuel. In this study, we evaluated five processes for their ability to produce intermediates from a coal-derived liquid for the production of high-density turbine fuel. These processes include acid-base extraction to reduce the heteroatom content of the middle distillate and the atmospheric and vacuum gas oils, solvent dewaxing to reduce the paraffin (alkane) content of the atmospheric and vacuum gas oils, Attapulgus clay treatment to reduce the heteroatom content of the middle distillate, coking to reduce the distillate range of the vacuum gas oil, and hydrogenation to remove heteroatoms and to saturate aromatic rings in the middle distillate and atmospheric gas oil. The chemical and physical properties that the US Air Force considers critical for the development of high-denisty aviation turbine fuel are specific gravity and net heat of combustion. The target minimum values for these properties are a specific gravity of at least 0.85 and a net heat of combustion of at least 130,000 Btu/gal. In addition, the minimum hydrogen content is 13.0 wt %, the maximum freeze point is {minus}53{degrees}F ({minus}47{degrees}C), the maximum amount of aromatics is about 25 to 30 vol %, and the maximum amount of paraffins is 10 vol %. 13 refs., 20 tabs.

  11. Western Coal/Great Lakes Alternative export-coal conference

    SciTech Connect (OSTI)

    Not Available

    1981-01-01T23:59:59.000Z

    This conference dealt with using the Great Lakes/St. Lawrence Seaway as an alternative to the East and Gulf Coasts for the exporting of coal to Europe and the potential for a piece of the European market for the subbituminous coals of Montana and Wyoming. The topics discussed included: government policies on coal exports; the coal reserves of Montana; cost of rail transport from Western mines to Lake Superior; the planning, design, and operation of the Superior Midwest Energy Terminal at Superior, Wisconsin; direct transfer of coal from self-unloading lakers to large ocean vessels; concept of total transportation from mines to users; disadvantage of a nine month season on the Great Lakes; costs of maritime transport of coal through the Great Lakes to Europe; facilities at the ice-free, deep water port at Sept Iles; the use of Western coals from an environmental and economic viewpoint; the properties of Western coal and factors affecting its use; the feasibility of a slurry pipeline from the Powder River Basin to Lake Superior; a systems analysis of the complete hydraulic transport of coal from the mine to users in Europe; the performance of the COJA mill-burner for the combustion of superfine coal; demand for steam coal in Western Europe; and the effect the New Source Performance Standards will have on the production and use of Western coal. A separate abstract was prepared for each of the 19 papers for the Energy Data Base (EDB); 17 will appear in Energy Research Abstracts (ERA) and 11 in Energy Abstracts for Policy Analysis (EAPA). (CKK)

  12. Low-rank coal research, Task 5.1. Topical report, April 1986--December 1992

    SciTech Connect (OSTI)

    Not Available

    1993-02-01T23:59:59.000Z

    This document is a topical progress report for Low-Rank Coal Research performed April 1986 - December 1992. Control Technology and Coal Preparation Research is described for Flue Gas Cleanup, Waste Management, Regional Energy Policy Program for the Northern Great Plains, and Hot-Gas Cleanup. Advanced Research and Technology Development was conducted on Turbine Combustion Phenomena, Combustion Inorganic Transformation (two sections), Liquefaction Reactivity of Low-Rank Coals, Gasification Ash and Slag Characterization, and Coal Science. Combustion Research is described for Atmospheric Fluidized-Bed Combustion, Beneficiation of Low-Rank Coals, Combustion Characterization of Low-Rank Fuels (completed 10/31/90), Diesel Utilization of Low-Rank Coals (completed 12/31/90), Produce and Characterize HWD (hot-water drying) Fuels for Heat Engine Applications (completed 10/31/90), Nitrous Oxide Emission, and Pressurized Fluidized-Bed Combustion. Liquefaction Research in Low-Rank Coal Direct Liquefaction is discussed. Gasification Research was conducted in Production of Hydrogen and By-Products from Coals and in Sulfur Forms in Coal.

  13. Assessment of underground coal gasification in bituminous coals: catalog of bituminous coals and site selection. Appendix A. National coal resource data system: Ecoal, Wcoal, and Bmalyt. Final report, Phase I. [Bituminous coal; by state; coal seam depth and thickness; identification

    SciTech Connect (OSTI)

    None

    1982-01-31T23:59:59.000Z

    Appendix A is a catalog of the bituminous coal in 29 states of the contiguous United States which contain identified bituminous coal resources.

  14. Autothermal coal gasification

    SciTech Connect (OSTI)

    Konkol, W.; Ruprecht, P.; Cornils, B.; Duerrfeld, R.; Langhoff, J.

    1982-03-01T23:59:59.000Z

    This paper presents test results of a pilot plant study of coal gasification system based on the process developed by Texaco. This process has been improved by the project partners Ruhrchenie A.G. and Ruhrkohle A.C. in West Germany and tested in a demonstration plant that operated for more than 10,000 hours, converting over 50,000 tons of coal into gas. The aim was to develop a process that would be sufficiently flexible when used at the commercial level to incorporate all of the advantages inherent in the diverse processes of the 'first generation' - fixed bed, fluidized bed and entrained bed processes - but would be free of the disadvantages of these processes. Extensive test results are tabulated and evaluated. Forecast for future development is included. 5 refs.

  15. Coal upgrading program for Usti nad Labem, Czech Republic: Task 8.3. Topical report, October 1994--August 1995

    SciTech Connect (OSTI)

    Young, B.C.; Musich, M.A.

    1995-10-01T23:59:59.000Z

    Coal has been a major energy source in the Czech Republic given its large coal reserves, especially brown coal and lignite (almost 4000 million metric tons) and smaller reserves of hard, mainly bituminous, coal (over 800 million tons). Political changes since 1989 have led to the reassessment of the role of coal in the future economy as increasing environmental regulations affect the use of the high-sulfur and high-ash brown coal and lignite as well as the high-ash hard coal. Already, the production of brown coal has declined from 87 million metric tons per year in 1989 to 67 million metric tons in 1993 and is projected to decrease further to 50 million metric tons per year of brown coal by the year 2000. As a means of effectively utilizing its indigenous coal resources, the Czech Republic is upgrading various technologies, and these are available at different stages of development, demonstration, and commercialization. The purpose of this review is to provide a database of information on applicable technologies that reduce the impact of gaseous (SO{sub 2}, NO{sub x}, volatile organic compounds) and particulate emissions from the combustion of coal in district and residential heating systems.

  16. Coal combustion under conditions of blast furnace injection; [Quarterly] technical report, September 1--November 30, 1993

    SciTech Connect (OSTI)

    Crelling, J.C.

    1993-12-31T23:59:59.000Z

    A potentially new use for Illinois coal is its use as a fuel injected into a blast furnace to produce molten iron as the first step in steel production. Because of its increasing cost and decreasing availability, metallurgical coke is now being replaced by coal injected at the tuyere area of the furnace where the blast air enters. The purpose of this study is to evaluate the combustion of coal during the blast furnace injection process and to delineate the optimum properties of the feed coal. This investigation is significant to the use of Illinois coal in that the limited research to date suggests that coals of low fluidity and moderate to high sulfur and chlorine contents are suitable feedstocks for blast furnace injection. This study is unique in that it will be the first North American effort to directly determine the nature of the combustion of coal injected into a blast furnace. This proposal is a follow-up to one funded for the 1992--1993 period. It is intended to complete the study already underway with the Armco Inc. steel company and to initiate a new cooperative study along somewhat similar lines with the Inland Steel Company. The results of this study will lead to the development of a testing and evaluation protocol that will give a unique and much needed understanding of the behavior of coal in the injection process and prove the potential of Illinois coals f or such use.

  17. Coal Bed Methane Primer

    SciTech Connect (OSTI)

    Dan Arthur; Bruce Langhus; Jon Seekins

    2005-05-25T23:59:59.000Z

    During the second half of the 1990's Coal Bed Methane (CBM) production increased dramatically nationwide to represent a significant new source of income and natural gas for many independent and established producers. Matching these soaring production rates during this period was a heightened public awareness of environmental concerns. These concerns left unexplained and under-addressed have created a significant growth in public involvement generating literally thousands of unfocused project comments for various regional NEPA efforts resulting in the delayed development of public and fee lands. The accelerating interest in CBM development coupled to the growth in public involvement has prompted the conceptualization of this project for the development of a CBM Primer. The Primer is designed to serve as a summary document, which introduces and encapsulates information pertinent to the development of Coal Bed Methane (CBM), including focused discussions of coal deposits, methane as a natural formed gas, split mineral estates, development techniques, operational issues, producing methods, applicable regulatory frameworks, land and resource management, mitigation measures, preparation of project plans, data availability, Indian Trust issues and relevant environmental technologies. An important aspect of gaining access to federal, state, tribal, or fee lands involves education of a broad array of stakeholders, including land and mineral owners, regulators, conservationists, tribal governments, special interest groups, and numerous others that could be impacted by the development of coal bed methane. Perhaps the most crucial aspect of successfully developing CBM resources is stakeholder education. Currently, an inconsistent picture of CBM exists. There is a significant lack of understanding on the parts of nearly all stakeholders, including industry, government, special interest groups, and land owners. It is envisioned the Primer would being used by a variety of stakeholders to present a consistent and complete synopsis of the key issues involved with CBM. In light of the numerous CBM NEPA documents under development this Primer could be used to support various public scoping meetings and required public hearings throughout the Western States in the coming years.

  18. Coal | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating SolarElectricEnergyCTBarreisVolcanicPower Address:Climatic SolarInformationCoal

  19. Hardgrove grindability study of Powder River Basin and Appalachian coal components in the blend to a midwestern power station

    SciTech Connect (OSTI)

    Padgett, P.L.; Hower, J.C. [Univ. of Kentucky, Lexington, KY (United States)

    1996-12-31T23:59:59.000Z

    Five coals representing four distinct coal sources blended at a midwestern power station were subjected to detailed analysis of their Hardgrove grindability. The coals are: a low-sulfur, high volatile A bituminous Upper Elkhorn No. 3 coal (Pike County, KY); a medium-sulfur, high volatile A bituminous Pittsburgh coal (southwestern PA); a low-sulfur, subbituminous Wyodak coal from two mines in the eastern Powder River Basin (Campbell County, WY). The feed and all samples processed in the Hardgrove grindability test procedure were analyzed for their maceral and microlithotype content. The high-vitrinite Pittsburgh coal and the relatively more petrographically complex Upper Elkhorn No. 3 coal exhibit differing behavior in grindability. The Pittsburgh raw feed, 16x30 mesh fraction (HGI test fraction), and the {minus}30 mesh fraction (HGI reject) are relatively similar petrographically, suggesting that the HGI test fraction is reasonably representative of the whole feed. The eastern Kentucky coal is not as representative of the whole feed, the HGI test fraction having lower vitrinite than the rejected {minus}30 mesh fraction. The Powder River Basin coals are high vitrinite and show behavior similar to the Pittsburgh coal.

  20. Low-pressure-ratio regenerative exhaust-heated gas turbine

    SciTech Connect (OSTI)

    Tampe, L.A.; Frenkel, R.G.; Kowalick, D.J.; Nahatis, H.M.; Silverstein, S.M.; Wilson, D.G.

    1991-01-01T23:59:59.000Z

    A design study of coal-burning gas-turbine engines using the exhaust-heated cycle and state-of-the-art components has been completed. In addition, some initial experiments on a type of rotary ceramic-matrix regenerator that would be used to transfer heat from the products of coal combustion in the hot turbine exhaust to the cool compressed air have been conducted. Highly favorable results have been obtained on all aspects on which definite conclusions could be drawn.

  1. Liquid chromatographic analysis of coal surface properties

    SciTech Connect (OSTI)

    Kwon, K.C.

    1991-01-01T23:59:59.000Z

    The main objectives of this proposed research are to refine further the inverse liquid chromatography technique for the study of surface properties of raw coals, treated coals and coal minerals in water, to evaluate relatively surface properties of raw coals, treated coals and coal minerals by inverse liquid chromatography, and to evaluate floatability of various treated coals in conjunction with surface properties of coals. Alcohols such as methanol, ethanol, isopropanol, isobutanol, tert-butanol, heptanol, 1-hexadecanol, 2-methyl-pentanol, 4-methyl-2-penthanol (methylisobutyl carbinol), n-octanol, s-octanol, and cyclohexanol as probe compounds are utilized to evaluate hydrophilicity of coals and coal minerals. N-alkanes such as hexane, heptane and octane, and stearic acid are employed as probe compounds to evaluate hydrophobicity of coals and coal minerals. Aromatic compounds such as benzene and toluene as probe compounds are used to examine aromaticity of coal surface. Aromatic acids such as o-cresol, m-cresol, p-cresol, phenol and B-naphthol are used to detect aromatic acidic sites of coal surface. Hydrophilicity, hydrophobicity and aromaticity of surfaces for either raw coals or treated coals in water are relatively determined by evaluating both equilibrium physical/chemical adsorption and dynamic adsorption of probe compounds on various raw coals and treated coals to compare affinities of coals for water.

  2. Transporting export coal from Appalachia

    SciTech Connect (OSTI)

    Not Available

    1982-11-01T23:59:59.000Z

    This publication is part of a series titled Market Guide for Steam Coal Exports from Appalachia. It focuses on the transportation link in the steam-coal supply chain, enabling producers to further assess their transportation options and their ability to compete in the export-coal marketplace. Transportation alternatives and handling procedures are discussed, and information is provided on the costs associated with each element in the transportation network.

  3. Workbook Contents

    U.S. Energy Information Administration (EIA) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul Aug SepAnnual",2013Annual",2014 ,"ReleaseAnnual",2014Bcf)"ImportsDeliveries toHeatHeatHeatHeat

  4. Combustion of calcium-exchanged coal. First quarterly report

    SciTech Connect (OSTI)

    Gavalas, G.R.; Flagan, R.C.

    1984-02-10T23:59:59.000Z

    The work performed during this first period includes equipment modification, development of analytical methods, oxidative pretreatment runs and combustion runs. The coal feeding section of an existing furnace was modified for uninterrupted feeding and better control of residence time. Analytical methods for sulfur and calcium in the coal and ash and for gaseous SO/sub 2/ were standardized. Oxidative pretreatment experiments were conducted in a fluidized bed at temperatures about 200/sup 0/C to evaluate the potential of this method for increasing the ion exchange capacity of coals and determine the accompanying loss of heating value. Combustion experiments were carried out at very high particle temperatures (2000/sup 0/K) at which a large fraction of the calcium additive was vaporized while 50 to 80% of the sulfur evolved as sulfur oxide. Continuing combustion experiments will be conducted at lower particle temperatures.

  5. Production of Substitute Natural Gas from Coal

    SciTech Connect (OSTI)

    Andrew Lucero

    2009-01-31T23:59:59.000Z

    The goal of this research program was to develop and demonstrate a novel gasification technology to produce substitute natural gas (SNG) from coal. The technology relies on a continuous sequential processing method that differs substantially from the historic methanation or hydro-gasification processing technologies. The thermo-chemistry relies on all the same reactions, but the processing sequences are different. The proposed concept is appropriate for western sub-bituminous coals, which tend to be composed of about half fixed carbon and about half volatile matter (dry ash-free basis). In the most general terms the process requires four steps (1) separating the fixed carbon from the volatile matter (pyrolysis); (2) converting the volatile fraction into syngas (reforming); (3) reacting the syngas with heated carbon to make methane-rich fuel gas (methanation and hydro-gasification); and (4) generating process heat by combusting residual char (combustion). A key feature of this technology is that no oxygen plant is needed for char combustion.

  6. Volatile coal prices reflect supply, demand uncertainties

    SciTech Connect (OSTI)

    Ryan, M.

    2004-12-15T23:59:59.000Z

    Coal mine owners and investors say that supply and demand are now finally in balance. But coal consumers find that both spot tonnage and new contract coal come at a much higher price.

  7. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01T23:59:59.000Z

    of natural gas, along with the coal reserve base of 326s Fossil Fuel Reserve Base, 2007 Oil Natural Gas Coal 233ensured reserves”) of coal, oil and natural gas published in

  8. China's Coal: Demand, Constraints, and Externalities

    E-Print Network [OSTI]

    Aden, Nathaniel

    2010-01-01T23:59:59.000Z

    coal electricity generation efficiency also varies by plantplants. The unit water requirement of coal-fired electricity generationelectricity generation is comparatively low in China due to the prevalence of small, outdated coal-fired power plants.

  9. Carbon Dioxide Emission Factors for Coal

    Reports and Publications (EIA)

    1994-01-01T23:59:59.000Z

    The Energy Information Administration (EIA) has developed factors for estimating the amount of carbon dioxide emitted, accounting for differences among coals, to reflect the changing "mix" of coal in U.S. coal consumption.

  10. Commercialization of Coal-to-Liquids Technology

    SciTech Connect (OSTI)

    NONE

    2007-08-15T23:59:59.000Z

    The report provides an overview of the current status of coal-to-liquids (CTL) commercialization efforts, including an analysis of efforts to develop and implement large-scale, commercial coal-to-liquids projects to create transportation fuels. Topics covered include: an overview of the history of coal usage and the current market for coal; a detailed description of what coal-to-liquids technology is; the history of coal-to-liquids development and commercial application; an analysis of the key business factors that are driving the increased interest in coal-to-liquids; an analysis of the issues and challenges that are hindering the commercialization of coal-to-liquids technology; a review of available coal-to-liquids technology; a discussion of the economic drivers of coal-to-liquids project success; profiles of key coal-to-liquids developers; and profiles of key coal-to-liquids projects under development.

  11. Commercializing the H-Coal Process

    E-Print Network [OSTI]

    DeVaux, G. R.; Dutkiewicz, B.

    1982-01-01T23:59:59.000Z

    , Hydrocarbon Research, Inc. (HRI) has observed a decided swing in interest in commercial coal liquefaction. Project owners can select one of two paths for commercial coal liquefaction using H-Coal technology. The quantum strategy involves the construction of a...

  12. Coal Bed Methane Protection Act (Montana)

    Broader source: Energy.gov [DOE]

    The Coal Bed Methane Protection Act establishes a long-term coal bed methane protection account and a coal bed methane protection program for the purpose of compensating private landowners and...

  13. Coal gasification power generation, and product market study. Topical report, March 1, 1995--March 31, 1996

    SciTech Connect (OSTI)

    Sheesley, D.; King, S.B.

    1998-12-31T23:59:59.000Z

    This Western Research Institute (WRI) project was part of a WRI Energy Resource Utilization Program to stimulate pilot-scale improved technologies projects to add value to coal resources in the Rocky Mountain region. The intent of this program is to assess the application potential of emerging technologies to western resources. The focus of this project is on a coal resource near the Wyoming/Colorado border, in Colorado. Energy Fuels Corporation/Kerr Coal Company operates a coal mine in Jackson County, Colorado. The coal produces 10,500 Btu/lb and has very low sulfur and ash contents. Kerr Coal Company is seeking advanced technology for alternate uses for this coal. This project was to have included a significant cost-share from the Kerr Coal Company ownership for a market survey of potential products and technical alternatives to be studied in the Rocky Mountain Region. The Energy Fuels Corporation/Kerr Coal Company and WRI originally proposed this work on a cost reimbursable basis. The total cost of the project was priced at $117,035. The Kerr Coal Company had scheduled at least $60,000.00 to be spent on market research for the project that never developed because of product market changes for the company. WRI and Kerr explored potential markets and new technologies for this resource. The first phase of this project as a preliminary study had studied fuel and nonfuel technical alternatives. Through related projects conducted at WRI, resource utilization was studied to find high-value materials that can be targeted for fuel and nonfuel use and eventually include other low-sulfur coals in the Rocky Mountain region. The six-month project work was spread over about a three-year period to observe, measure, and confirm over time-any trends in technology development that would lead to economic benefits in northern Colorado and southern Wyoming from coal gasification and power generation.

  14. Multi-gravity separator: an alternate gravity concentrator to process coal fines

    SciTech Connect (OSTI)

    Majumder, A.K.; Bhoi, K.S.; Barnwal, J.P. [Regional Research Laboratories, Bhopal (India)

    2007-08-15T23:59:59.000Z

    The multi-gravity separator (MGS) is a novel piece of equipment for the separation of fine and ultra-fine minerals. However, the published literature does not demonstrate its use in the separation of coal fines. Therefore, an attempt was made to study the effects of different process variables on the performance of an MGS for the beneficiation of coal fines. The results obtained from this study revealed that among the parameters studied, drum rotation and feed solids concentration play dominating roles in controlling the yield and ash content of the clean coal. Mathematical modeling equations that correlate the variables studied and the yield and ash contents of the clean coal were developed to predict the performance of an MGS under different operating and design conditions. The entire exercise revealed that the MGS could produce a clean coal with an ash content of 14.67% and a yield of 71.23% from a feed coal having an ash content of 24.61 %.

  15. Process for electrochemically gasifying coal

    DOE Patents [OSTI]

    Botts, T.E.; Powell, J.R.

    1985-10-25T23:59:59.000Z

    A process is claimed for electrochemically gasifying coal by establishing a flowing stream of coal particulate slurry, electrolyte and electrode members through a transverse magnetic field that has sufficient strength to polarize the electrode members, thereby causing them to operate in combination with the electrolyte to electrochemically reduce the coal particulate in the slurry. Such electrochemical reduction of the coal produces hydrogen and carbon dioxide at opposite ends of the polarized electrode members. Gas collection means are operated in conjunction with the process to collect the evolved gases as they rise from the slurry and electrolyte solution. 7 figs.

  16. Coal Mine Safety Act (Virginia)

    Broader source: Energy.gov [DOE]

    This Act is the primary legislation pertaining to coal mine safety in Virginia. It contains information on safety rules, safety standards and required certifications for mine workers, prohibited...

  17. MS_Coal_Studyguide.indd

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    what about costs? Th e mining, transportation, electricity generation, and pollution-control costs associated with using coal are increasing, but both natural gas and oil are...

  18. Advanced coal-fueled gas turbine systems reference system definition update

    SciTech Connect (OSTI)

    Not Available

    1991-09-01T23:59:59.000Z

    The objective of the the Direct Coal-Fueled 80 MW Combustion Turbine Program is to establish the technology required for private sector use of an advanced coal-fueled combustion turbine power system. Under this program the technology for a direct coal-fueled 80 MW combustion turbine is to be developed. This unit would be an element in a 207 MW direct coal-fueled combustion turbine combined cycle which includes two combustion turbines, two heat recovery steam generators and a steam turbine. Key to meeting the program objectives is the development of a successful high pressure slagging combustor that burns coal, while removing sulfur, particulates, and corrosive alkali matter from the combustion products. Westinghouse and Textron (formerly AVCO Research Laboratory/Textron) have designed and fabricated a subscale slagging combustor. This slagging combustor, under test since September 1988, has been yielding important experimental data, while having undergone several design iterations.

  19. RESOURCE ASSESSMENT & PRODUCTION TESTING FOR COAL BED METHANE IN THE ILLINOIS BASIN

    SciTech Connect (OSTI)

    Cortland Eble; James Drahovzal; David Morse; Ilham Demir; John Rupp; Maria Mastalerz; Wilfrido Solano

    2004-06-01T23:59:59.000Z

    The geological surveys of Illinois, Indiana and Kentucky have completed the initial geologic assessment of their respective parts of the Illinois Basin. Cumulative thickness maps have been generated and target areas for drilling have been selected. The first well in the Illinois area of the Illinois Basin coal bed methane project was drilled in White County, Illinois in October 2003. This well was cored in the major coal interval from the Danville to the Davis Coals and provided a broad spectrum of samples for further analyses. Sixteen coal samples and three black shale samples were taken from these cores for canister desorption tests and were the subject of analyses that were completed over the following months, including desorbed gas volume, gas chemical and isotope composition, coal proximate, calorific content and sulfur analyses. Drilling programs in Indiana and Kentucky are expected to begin shortly.

  20. Clean Coal Technology Demonstration Program. Program update 1994

    SciTech Connect (OSTI)

    NONE

    1995-04-01T23:59:59.000Z

    The Clean Coal Technology Demonstration Program (CCT Program) is a $7.14 billion cost-shared industry/government technology development effort. The program is to demonstrate a new generation of advanced coal-based technologies, with the most promising technologies being moved into the domestic and international marketplace. Clean coal technologies being demonstrated under the CCT program are creating the technology base that allows the nation to meet its energy and environmental goals efficiently and reliably. The fact that most of the demonstrations are being conducted at commercial scale, in actual user environments, and under conditions typical of commercial operations allows the potential of the technologies to be evaluated in their intended commercial applications. The technologies are categorized into four market sectors: advanced electric power generation systems; environmental control devices; coal processing equipment for clean fuels; and industrial technologies. Sections of this report describe the following: Role of the Program; Program implementation; Funding and costs; The road to commercial realization; Results from completed projects; Results and accomplishments from ongoing projects; and Project fact sheets. Projects include fluidized-bed combustion, integrated gasification combined-cycle power plants, advanced combustion and heat engines, nitrogen oxide control technologies, sulfur dioxide control technologies, combined SO{sub 2} and NO{sub x} technologies, coal preparation techniques, mild gasification, and indirect liquefaction. Industrial applications include injection systems for blast furnaces, coke oven gas cleaning systems, power generation from coal/ore reduction, a cyclone combustor with S, N, and ash control, cement kiln flue gas scrubber, and pulse combustion for steam coal gasification.