National Library of Energy BETA

Sample records for hdpe high-density polyethylene

  1. High density polyethylene (HDPE) containers as an alternative to polyethylene terephthalate (PET) bottles for solar disinfection of drinking water in northern region, Ghana

    E-Print Network [OSTI]

    Yazdani, Iman

    2007-01-01

    The purpose of this study is to investigate the technical feasibility of high density polyethylene (HDPE) containers as an alternative to polyethylene terephthalate (PET) bottles for the solar disinfection of drinking water ...

  2. Thermal, tensile and rheological properties of high density polyethylene (HDPE) processed and irradiated by gamma-ray in different atmospheres

    SciTech Connect (OSTI)

    Ferreto, H. F. R. E-mail: ana-feitoza@yahoo.com.br; Oliveira, A. C. F. E-mail: ana-feitoza@yahoo.com.br; Parra, D. F. E-mail: ablugao@ipen.br; Lugćo, A. B. E-mail: ablugao@ipen.br; Gaia, R.

    2014-05-15

    The aim of this paper is to investigate structural changes of high density polyethylene (HDPE) modified by ionizing radiation (gamma rays) in different atmospheres. The gamma radiation process for modification of commercial polymers is a widely applied technique to promote new physical-chemical and mechanical properties. Gamma irradiation originates free radicals which can induce chain scission or recombination, providing its annihilation, branching or crosslinking. This polymer was irradiated with gamma source of {sup 60}Co at doses of 5, 10, 20, 50 or 100 kGy at a dose rate of 5 kGy/h. The changes in molecular structure of HDPE, after gamma irradiations were evaluated using thermogravimetric analysis (TGA) and tensile machine and oscillatory rheology. The results showed the variations of the properties depending on the dose at each atmosphere.

  3. ORIGINAL PAPER BambooFiber Filled High Density Polyethylene Composites

    E-Print Network [OSTI]

    strength, bending modulus and strength were improved with the use of MAPE. The use of the clayORIGINAL PAPER Bamboo­Fiber Filled High Density Polyethylene Composites: Effect of Coupling to achieve clay exfoliation. For pure HDPE system, both dynamic and static bending moduli increased, while

  4. Insight into the Molecular Arrangement of High-Density Polyethylene Polymer Chains in Blends of Polystyrene/High-

    E-Print Network [OSTI]

    Insight into the Molecular Arrangement of High-Density Polyethylene Polymer Chains in Blends of Polystyrene/High- Density Polyethylene from Differential Scanning Calorimetry and Raman Techniques JAYANT/high-density polyethylene (PS/HDPE) blends were synthe- sized by melt blending in a single screw extruder. Co

  5. Rice Straw Fiber Reinforced High Density Polyethylene Composite: Effect of Coupled Compatibilizating and

    E-Print Network [OSTI]

    Rice Straw Fiber Reinforced High Density Polyethylene Composite: Effect of Coupled polyethylene (HDPE) composites were manufactured by extrusion and injection molding. Three compatibilizers compatibilizers, ma- leic anhydride grafted polyethylene and polypropylene (PE-g-MA and PP-g-MA) are considered

  6. PORTSMOUTH ON-SITE DISPOSAL CELL HIGH DENSITY POLYETHYLENE GEOMEMBRANE LONGEVITY

    SciTech Connect (OSTI)

    Phifer, M.

    2012-01-31

    It is anticipated that high density polyethylene (HDPE) geomembranes will be utilized within the liner and closure cap of the proposed On-Site Disposal Cell (OSDC) at the Portsmouth Gaseous Diffusion Plant. The likely longevity (i.e. service life) of HDPE geomembranes in OSDC service is evaluated within the following sections of this report: (1) Section 2.0 provides an overview of HDPE geomembranes, (2) Section 3.0 outlines potential HDPE geomembranes degradation mechanisms, (3) Section 4.0 evaluates the applicability of HDPE geomembrane degradation mechanisms to the Portsmouth OSDC, (4) Section 5.0 provides a discussion of the current state of knowledge relative to the longevity (service life) of HDPE geomembranes, including the relation of this knowledge to the Portsmouth OSDC, and (5) Section 6.0 provides summary and conclusions relative to the anticipated service life of HDPE geomembranes in OSDC service. Based upon this evaluation it is anticipated that the service life of HDPE geomembranes in OSDC service would be significantly greater than the 200 year service life assumed for the OSDC closure cap and liner HDPE geomembranes. That is, a 200 year OSDC HDPE geomembrane service life is considered a conservative assumption.

  7. Shape stabilised phase change materials (SSPCMs): High density polyethylene and hydrocarbon waxes

    SciTech Connect (OSTI)

    Mu, Mulan, E-mail: mmu01@qub.ac.uk, E-mail: m.basheer@qub.ac.uk; Basheer, P. A. M., E-mail: mmu01@qub.ac.uk, E-mail: m.basheer@qub.ac.uk [School of Planning, Architecture and Civil Engineering, Queen's University Belfast, BT9 5AG (United Kingdom); Bai, Yun, E-mail: yun.bai@ucl.ac.uk [Department of Civil, Environmental and Geomatic Engineering, University College London, WC1E 6BT (United Kingdom); McNally, Tony, E-mail: t.mcnally@warwick.ac.uk [WMG, University of Warwick, CV4 7AL (United Kingdom)

    2014-05-15

    Shape stabilised phase change materials (SSPCMs) based on high density polyethylene (HDPE) with high (HPW, T{sub m}=56-58 °C) and low (L-PW, T{sub m}=18-23 °C) melting point waxes were prepared by melt-mixing in a twin-screw extruder and their potential in latent heat thermal energy storage (LHTES) applications for housing assessed. The structure and morphology of these blends were investigated by scanning electron microscopy (SEM). Both H-PW and L-PW were uniformly distributed throughout the HDPE matrix. The melting point and latent heat of the SSPCMs were determined by differential scanning calorimetry (DSC). The results demonstrated that both H-PW and L-PW have a plasticisation effect on the HDPE matrix. The tensile and flexural properties of the samples were measured at room temperature (RT, 20±2 °C) and 70 °C, respectively. All mechanical properties of HDPE/H-PW and HDPE/L-PW blends decreased from RT to 70 °C. In all instances at RT, modulus and stress, irrespective of the mode of deformation was greater for the HDPE/H-PW blends. However, at 70 °C, there was no significant difference in mechanical properties between the HDPE/H-PW and HDPE/L-PW blends.

  8. Wood-Fiber/High-Density-Polyethylene Composites: Compounding Process

    E-Print Network [OSTI]

    Wood-Fiber/High-Density-Polyethylene Composites: Compounding Process J. Z. Lu,1 Q. Wu,1 I. I parameters for the wood-fiber/high-density-polyethylene blends at 60 rpm were a temperature of 180°C

  9. Irradiation effects in high-density polyethylene Jussi Polvia

    E-Print Network [OSTI]

    Nordlund, Kai

    Irradiation effects in high-density polyethylene Jussi Polvia , Kai Nordlunda a simulations, we have studied the irradiation effects in high density polyethylene. We determined the threshold for the hydrogen atoms in the polyethylene chain. Keywords: molecular dynamics, irradiation, damage threshold

  10. Considerations for cold weather construction using high density polyethylene for corrosion control systems

    SciTech Connect (OSTI)

    Szklarz, K.E.; Baron, J.J.

    1995-12-01

    High Density Polyethylene (HDPE) is commonly used as material for corrosion-resistant piping in the petroleum industry. It is used as thick-walled self-supporting linepipes, as internal liners for steel linepipe, and as protective jackets for insulated linepipes. In Canada, it is not uncommon for operations, such as pipeline installation, to be performed during the winter season when temperatures are in the 0 C to {minus}20 C range. Brittle failures of HDPE materials have been experienced during such sub-zero operations, particularly when pipe handling and bending is involved. This study evaluated the changes in HDPE mechanical properties within the temperature range of 10 C to {minus}40 C to understand any embrittlement phenomena that may be occurring. HDPE undergoes substantial increases in modulus and strength at lower temperatures and increasing strain rate. The changes are gradual and over a wide range of temperature with no sharp cut-off temperature at which brittle behavior will occur. Flexural properties behave in a similar manner. A notch, causing a local increased strain rate, has a significant effect on the failure behavior of HDPE material with a gradual transition in behavior of ductility and load at below 0 C.

  11. Chemical compounds and toxicological assessments of drinking water stored in polyethylene terephthalate (PET)

    E-Print Network [OSTI]

    Short, Daniel

    Chemical compounds and toxicological assessments of drinking water stored in polyethyleneMS, gas chromatographyemass spectrometry; HDPE, high density polyethylene; HULYs, human blood lymphocytes

  12. Current Activities Assessing Butt Fusion Joint Integrity in High Density Polyethylene Piping

    SciTech Connect (OSTI)

    Crawford, Susan L.; Cinson, Anthony D.; Doctor, Steven R.; Denslow, Kayte M.

    2012-09-01

    The Pacific Northwest National Laboratory (PNNL) in Richland, Washington, conducted initial studies to evaluate the effectiveness of nondestructive examinations (NDE) coupled with mechanical testing for assessing butt fusion joint integrity in high density polyethylene (HDPE) pipe. The work provided insightful information to the United States Nuclear Regulatory Commission (NRC) on the effectiveness of volumetric inspection techniques for detecting lack of fusion (LOF) conditions in the fusion joints. HDPE has been installed on a limited basis in American Society of Mechanical Engineers (ASME) Class 3, buried piping systems at several operating U.S. nuclear power plants and has been proposed for use in new construction. A comparison was made between the results from ultrasonic and microwave nondestructive examinations and the results from mechanical destructive evaluations, specifically the high-speed tensile test and the side-bend test, for determining joint integrity. The data comparison revealed that none of the NDE techniques detected all of the lack-of-fusion conditions that were revealed by the destructive tests. Follow-on work has recently been initiated at PNNL to accurately characterize the NDE responses from machined flaws of varying size and location in PE 4710 materials as well as the LOF condition. This effort is directed at quantifying the ability of volumetric NDE techniques to detect flaws in relation to the critical flaw size associated with joint integrity. A status of these latest investigations is presented.

  13. Crystallographic texture evolution in high-density polyethylene during uniaxial tension

    E-Print Network [OSTI]

    Garmestani, Hamid

    Crystallographic texture evolution in high-density polyethylene during uniaxial tension D. Lia , H experimental measurements of crystallographic texture evolution in high-density polyethylene subjected to very straining of high-density polyethylene to large strains. There are at least three distinct preferred

  14. Selected Physical Characteristics of Polystyrene/High Density Polyethylene Composites Prepared from Virgin

    E-Print Network [OSTI]

    Virgin and Recycled Materials Jayant Joshi, Richard Lehman, Thomas Nosker Rutgers University School: Mixtures of polystyrene and high density polyethylene were injection molded from recycled and virgin polymers to generate cocontinuous structures. The mechanical properties of these blends were evaluated

  15. Phase Structure and Properties of Poly(ethylene terephthalate)/High-Density Polyethylene Based on

    E-Print Network [OSTI]

    University of Science and Technology, Shanghai 200237, People's Republic of China Received 12 June 2008 words: polyethylene; recycling; blends; poly(ethylene terephthalate) INTRODUCTION Plastics account-density polyethylene (LDPE), polypropylene (PP), Poly (ethylene terephthalate) (PET), etc. The plastic waste

  16. Steady-State and Dynamic Modeling of Commercial Slurry High-Density Polyethylene (HDPE) Processes

    E-Print Network [OSTI]

    Liu, Y. A.

    , solvent, and oligomeric species from the polymer. Sol- vent is separated from the oligomer and recycled, Polymers Plus and Aspen Dynamics. The discussion includes thermodynamic properties, phase equilibrium, reaction kinetics, polymer properties, and other modeling issues. We characterize a Ziegler- Natta catalyst

  17. Studies of protein adsorption on implant materials in relation to biofilm formation I. Activity of Pseudomonas aeruginosa on Polypropylene and High density Polyethylene in presence of serum albumin

    E-Print Network [OSTI]

    Sinha, S Dutta; Maity, P K; Tarafdar, S; Moulik, S P

    2014-01-01

    The surface of biomaterials used as implants are highly susceptible to bacterial colonization and subsequent infection. The amount of protein adsorption on biomaterials, among other factors, can affect the nature and quality of biofilms formed on them. The variation in the adsorption time of the protein on the biomaterial surface produces a phenotypic change in the bacteria by alteration of the production of EPS (exoplysaccharide) matrix. Knowledge of the effects of protein adsorption on implant infection will be very useful in understanding the chemistry of the biomaterial surfaces, which can deter the formation of biofilms. It is observed that the adsorption of BSA on the biomaterial surfaces increases with time and concentration, irrespective of their type and the nature of the EPS matrix of the bacterial biofilm is dependent on the amount of protein adsorbed on the biomaterial surface. The adsorption of protein (BSA) on the biomaterials, polypropylene (PP) and high density polyethylene (HDPE) has been stu...

  18. Preparation and Properties of Recycled HDPE/Clay Hybrids

    E-Print Network [OSTI]

    . The influence of blending method, compatibil- izers, and clay content on clay intercalation and exfoliation. RHDPE/clay hybrids containing completely exfoliated clay were obtained using a two-step blending method), high density polyethylene (HDPE), and polypropylene (PP) are the three largest components

  19. Optical Properties and Orientation in Polyethylene Blown Films

    E-Print Network [OSTI]

    Beaucage, Gregory

    Optical Properties and Orientation in Polyethylene Blown Films AYUSH BAFNA,1 GREGORY BEAUCAGE,1 properties of blown poly- ethylene films. Two types of blown polyethylene films of similar degrees of crystallinity were made from (1) single-site-catalyst high-density polyethylene (HDPE; STAR ) and (2) Ziegler

  20. Test method Evaluating the influence of contacting fluids on polyethylene

    E-Print Network [OSTI]

    Thompson, Michael

    Test method Evaluating the influence of contacting fluids on polyethylene using acoustic emissions emissions Polyethylene Penetrant Toluene Aqueous detergent a b s t r a c t Identifying microstructural) on the structure of a semi-crystalline polymer (high density polyethylene, HDPE) over different periods of exposure

  1. Studies of protein adsorption on implant materials in relation to biofilm formation I. Activity of Pseudomonas aeruginosa on Polypropylene and High density Polyethylene in presence of serum albumin

    E-Print Network [OSTI]

    S Dutta Sinha; Susmita Chatterjee; P. K. Maity; S. Tarafdar; S. P. Moulik

    2014-11-19

    The surface of biomaterials used as implants are highly susceptible to bacterial colonization and subsequent infection. The amount of protein adsorption on biomaterials, among other factors, can affect the nature and quality of biofilms formed on them. The variation in the adsorption time of the protein on the biomaterial surface produces a phenotypic change in the bacteria by alteration of the production of EPS (exoplysaccharide) matrix. Knowledge of the effects of protein adsorption on implant infection will be very useful in understanding the chemistry of the biomaterial surfaces, which can deter the formation of biofilms. It is observed that the adsorption of BSA on the biomaterial surfaces increases with time and concentration, irrespective of their type and the nature of the EPS matrix of the bacterial biofilm is dependent on the amount of protein adsorbed on the biomaterial surface. The adsorption of protein (BSA) on the biomaterials, polypropylene (PP) and high density polyethylene (HDPE) has been studied and the formation of the biofilms of Pseudomonas aeruginosa on them has been examined.

  2. Flow induced crystallisation of HDPE (DOW 96001) in cross-slot flow

    E-Print Network [OSTI]

    Scelsi, Lino

    2008-06-30

    Bright-field optical observation of supercooled high density polyethylene (HDPE) flowing in a cross-slot multi-pass rheometer (MPR) cell. The geometry generates a flow field with an extensional component at the centreline. If the no slip condition...

  3. Aging of HDPE Pipes Exposed to Diesel Lubricant Amelia H. U. Torres1

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Aging of HDPE Pipes Exposed to Diesel Lubricant Amelia H. U. Torres1 , José R. M. d'Almeida1 behavior of high-density polyethylene pipes by exposure to a diesel lubricant were investigated that diesel, which can be regarded as a model fluid to analyze the effects caused by aromatic unities present

  4. Transient current generation during wear of high-density polyethylene by a stainless-steel stylus

    E-Print Network [OSTI]

    Dickinson, J. Thomas

    by conducting styli of single-crystal inorganics including MgO and NaCl ,9 polymers including poly methylmethacrylate , polycarbonate, polystyrene, and polyethylene ,7 and metal surfaces in the presence when contact with other insulating or conducting surfaces is broken. This work describes the use

  5. Profiles in garbage: Polyethylene terephthalate

    SciTech Connect (OSTI)

    Miller, C. [Environmental Industry Associations, Washington, DC (United States)

    1997-11-01

    Polyethylene terephthalate (PET) is a plastic resin used primarily to make bottles. Soft drinks -- along with salad dressing, fruit juices, peanut butter, and other household and consumer products -- use PET bottles. PET also is used for film, sheeting for cups and food trays, oven-safe trays, and other uses. PET is a relatively new packaging resin, first commercialized in the early 1970s. Because it is an ``engineered`` resin, PET is more expensive than commodity resins such as high-density polyethylene (HDPE) and, for the same reason, it is usually the highest valued plastic recyclable.

  6. Waste product profile: Polyethylene terephthalate

    SciTech Connect (OSTI)

    Miller, C. [Environmental Industry Associations, Washington, DC (United States)

    1996-02-01

    Polyethylene terephthalate (PET) is a plastic resin used primarily to make bottles. Soft drinks are the primary product packaged in PET. Salad dressing, peanut butter, and other household and consumer products also use PET bottles. PET is also used for film, sheeting for cups and food trays, ovenable trays, and other uses. PET is a relatively new packaging resin, first commercialized in the early `70s. Because it is an ``engineered`` resin, it is more expensive than commodity resins such as high-density polyethylene (HDPE). The primary market for recycled PET is the fiber industry, which uses PET for carpet fiber, sweaters and other clothing, and for other uses. Recycled PET can also be used for food and beverage containers. Export markets, particularly Asian countries, are becoming increasingly important.

  7. Criticality Evaluation of Plutonium-239 Moderated by High-Density Polyethylene in Stainless Steel and Aluminum Containers Suitable for Non-Exclusive Use Transport

    SciTech Connect (OSTI)

    Watson, T T

    2007-08-10

    Research is conducted at the Joint Actinide Shock Physics Experimental Facility (JASPER) on the effects of high pressure and temperature environments on plutonium-239, in support of the stockpile stewardship program. Once an experiment has been completed, it is necessary to transport the end products for interim storage or final disposition. Federal shipping regulations for nonexclusive use transportation require that no more than 180 grams of fissile material are present in at least 360 kilograms of contiguous non-fissile material. To evaluate the conservatism of these regulatory requirements, a worst-case scenario of 180g {sup 239}Pu and a more realistic scenario of 100g {sup 239}Pu were modeled using one of Lawrence Livermore National Laboratory's Monte Carlo transport codes known as COG 10. The geometry consisted of {sup 239}Pu spheres homogeneously mixed with high-density polyethylene surrounded by a cube of either stainless steel 304 or aluminum. An optimized geometry for both cube materials and hydrogen-to-fissile isotope (H/X) ratio were determined for a single unit. Infinite and finite 3D arrays of these optimized units were then simulated to determine if the systems would exceed criticality. Completion of these simulations showed that the optimal H/X ratio for the most reactive units ranged from 800 to 1600. A single unit of either cube type for either scenario would not reach criticality. An infinite array was determined to reach criticality only for the 180g case. The offsetting of spheres in their respective cubes was also considered and showed a considerable decrease in the number of close-packed units needed to reach criticality. These results call into question the current regulations for fissile material transport, which under certain circumstances may not be sufficient in preventing the development of a critical system. However, a conservative, theoretical approach was taken in all assumptions and such idealized configurations may not be likely to be encountered in actual packaging, transportation, and storage configurations. Modeling of realistic, as-built configurations is beyond the scope of this study.

  8. Identification of the true elastic modulus of high density polyethylene from tensile tests using an appropriate reduced model of the elastoviscoplastic behavior

    E-Print Network [OSTI]

    Blaise, A; Delobelle, Patrick; Meshaka, Yves; Cunat, C

    2012-01-01

    The rheological parameters of materials are determined in the industry according to international standards established generally on the basis of widespread techniques and robust methods of estimation. Concerning solid polymers and the determination of Young's modulus in tensile tests, ISO 527-1 or ASTM D638 standards rely on protocols with poor scientific content: the determination of the slope of conventionally defined straight lines fitted to stress-strain curves in a given range of elongations. This paper describes the approach allowing for a correct measurement of the instantaneous elastic modulus of polymers in a tensile test. It is based on the use of an appropriate reduced model to describe the behavior of the material. The model comes a thermodynamical framework and allows to reproduce the behavior of an HDPE Polymer until large strains, covering the elastoviscoplastic and hardening regimes. Well-established principles of parameter estimation in engineering science are used to found the identificatio...

  9. Identification of the true elastic modulus of high density polyethylene from tensile tests using an appropriate reduced model of the elastoviscoplastic behavior

    E-Print Network [OSTI]

    A. Blaise; Stéphane André; Patrick Delobelle; Yves Meshaka; C. Cunat

    2012-06-19

    The rheological parameters of materials are determined in the industry according to international standards established generally on the basis of widespread techniques and robust methods of estimation. Concerning solid polymers and the determination of Young's modulus in tensile tests, ISO 527-1 or ASTM D638 standards rely on protocols with poor scientific content: the determination of the slope of conventionally defined straight lines fitted to stress-strain curves in a given range of elongations. This paper describes the approach allowing for a correct measurement of the instantaneous elastic modulus of polymers in a tensile test. It is based on the use of an appropriate reduced model to describe the behavior of the material. The model comes a thermodynamical framework and allows to reproduce the behavior of an HDPE Polymer until large strains, covering the elastoviscoplastic and hardening regimes. Well-established principles of parameter estimation in engineering science are used to found the identification procedure. It will be shown that three parameters only are necessary to model experimental tensile signals: the instantaneous ('Young's') modulus, the maximum relaxation time of a linear distribution (described with a universal shape) and a strain hardening modulus to describe the 'relaxed' state. The paper ends with an assessment of the methodology. Our results of instantaneous modulus measurements are compared with those obtained with other physical experiments operating at different temporal and length scales.

  10. A New Polyethylene Scattering Law Determined Using Inelastic Neutron Scattering

    SciTech Connect (OSTI)

    Lavelle, Christopher M [ORNL; Liu, C [Oak Ridge National Laboratory (ORNL); Stone, Matthew B [ORNL

    2013-01-01

    Monte Carlo neutron transport codes such as MCNP rely on accurate data for nuclear physics cross-sections to produce accurate results. At low energy, this takes the form of scattering laws based on the dynamic structure factor, S (Q, E). High density polyethylene (HDPE) is frequently employed as a neutron moderator at both high and low temperatures, however the only cross-sections available are for T =300 K, and the evaluation has not been updated in quite some time. In this paper we describe inelastic neutron scattering measurements on HDPE at 5 and 300 K which are used to improve the scattering law for HDPE. We describe the experimental methods, review some of the past HDPE scattering laws, and compare computations using these models to the measured S (Q, E). The total cross-section is compared to available data, and the treatment of the carbon secondary scatterer as a free gas is assessed. We also discuss the use of the measurement itself as a scattering law via the 1 phonon approximation. We show that a scattering law computed using a more detailed model for the Generalized Density of States (GDOS) compares more favorably to this experiment, suggesting that inelastic neutron scattering can play an important role in both the development and validation of new scattering laws for Monte Carlo work.

  11. Surface Cleaning Techniques: Ultra-Trace ICP-MS Sample Preparation and Assay of HDPE

    SciTech Connect (OSTI)

    Overman, Nicole R.; Hoppe, Eric W.; Addleman, Raymond S.

    2013-06-01

    The world’s most sensitive radiation detection and assay systems depend upon ultra-low background (ULB) materials to reduce unwanted radiological backgrounds. Herein, we evaluate methods to clean HDPE, a material of interest to ULB systems and the means to provide rapid assay of surface and bulk contamination. ULB level material and ultra-trace level detection of actinide elements is difficult to attain, due to the introduction of contamination from sample preparation equipment such as pipette tips, sample vials, forceps, etc. and airborne particulate. To date, literature available on the cleaning of such polymeric materials and equipment for ULB applications and ultra-trace analyses is limited. For these reasons, a study has been performed to identify an effective way to remove surface contamination from polymers in an effort to provide improved instrumental detection limits. Inductively Coupled Plasma Mass Spectroscopy (ICP-MS) was utilized to assess the effectiveness of a variety of leachate solutions for removal of inorganic uranium and thorium surface contamination from polymers, specifically high density polyethylene (HDPE). HDPE leaching procedures were tested to optimize contaminant removal of thorium and uranium. Calibration curves for thorium and uranium ranged from 15 ppq (fg/mL) to 1 ppt (pg/mL). Detection limits were calculated at 6 ppq for uranium and 7 ppq for thorium. Results showed the most effective leaching reagent to be clean 6 M nitric acid for 72 hour exposures. Contamination levels for uranium and thorium found in the leachate solutions were significant for ultralow level radiation detection applications.

  12. Damage to HDPE geomembrane from interface shear over gravelly compacted clay liner

    E-Print Network [OSTI]

    Thielmann, Stuart

    2012-01-01

    high-density polyethylene leachate collection and removalthe following requirements: leachate collection and removalLCRS) limiting the head of leachate on the liner system to

  13. DSC Evidence for Microstructure and Phase Transitions in Polyethylene Melts at High Temperatures

    E-Print Network [OSTI]

    Hussein, Ibnelwaleed A.

    DSC Evidence for Microstructure and Phase Transitions in Polyethylene Melts at High Temperatures polyethylenes of types HDPE, LDPE, and LLDPE. DSC data were obtained for a range of heating and cooling rates previous rheology findings of order and high-temperature transitions in polyethylene melts. Introduction

  14. Development of a modular directional and spectral neutron detection system using solid-state detectors

    E-Print Network [OSTI]

    Danon, Yaron

    resolution. The system used in this paper was comprised of a stack of five high-density polyethylene (HDPE was HDPE moderated, HDPE reflected, lead (Pb) shielded, and bare in order to benchmark the system

  15. Wood-Fiber/High-Density-Polyethylene Composites: Coupling Agent Performance

    E-Print Network [OSTI]

    -of-service thermoplastic products and plastic wastes in the world.3 Like other thermoplastic olefins, virgin and recycled and nonpolar thermoplastic ma- trix.5,6 Kokta and coworkers7 investigated the influ- ence of four different

  16. High-density fluid compositions

    SciTech Connect (OSTI)

    Sanders, D.C.

    1981-09-29

    Clear, high-density fluids suitable for use as well completion, packing, and perforation media comprise aqueous solutions of zinc bromide and calcium bromide having densities lying in the range of about 14.5 up to about 18.0 pounds per gallon and measured PH's lying in the range of about 3.5 up to about 6.0. Optionally, such fluids may also comprise calcium chloride and/or a soluble film-forming amine-based corrosion inhibitor. Such fluids under conditions of ordinary use exhibit low corrosion rates and have crystallization points lying well below the range of temperatures under which they are used.

  17. An Instability Leading to Failure of Polyethylene in Uniaxial Creep

    E-Print Network [OSTI]

    An Instability Leading to Failure of Polyethylene in Uniaxial Creep L. J. ZAPAS and J. M. CRISSMAN model, a point of instability is pre- dicted for the uniaxial creep of high density polyethylene. From dead load experiments it has been found that the instabil- ity occurs for linear -polyethylene

  18. Fracture mechanics analysis of slow crack growth in polyethylene 

    E-Print Network [OSTI]

    Self, Robert Alan

    1997-01-01

    Slow crack growth in polyethylene is often the limiting factor in long-term service of plastic pipe or other structural applications. A new test method and analysis method was developed to study slow crack growth in polyethylene. Two high density...

  19. Creep Failure and Fracture of Polyethylene in Uniaxial J. M. CRISSMAN and L. J. ZAPAS

    E-Print Network [OSTI]

    Creep Failure and Fracture of Polyethylene in Uniaxial Extension J. M. CRISSMAN and L. J. ZAPAS conditions of uniaxial creep the frac- ture of high density polyethylene can be categorized as one of three, this phenomenon is known as dead load fatigue. In the case of polyethylene the ultimate fracture can

  20. Macromolecules 1991,24, 5687-5694 5687 Characterization of Molecular Orientation in Polyethylene by

    E-Print Network [OSTI]

    Pezolet, Michel

    Macromolecules 1991,24, 5687-5694 5687 Characterization of Molecular Orientation in Polyethylene bonds in thick processed samples of polyethylene. Introduction In order to take full advantage to the production of high-modulusfibersandfilms. High-density polyethylene isoneof the polymers that has been used

  1. Aerodynamic Focusing Of High-Density Aerosols

    SciTech Connect (OSTI)

    Ruiz, D. E.; Fisch, Nathaniel

    2014-02-24

    High-density micron-sized particle aerosols might form the basis for a number of applications in which a material target with a particular shape might be quickly ionized to form a cylindrical or sheet shaped plasma. A simple experimental device was built in order to study the properties of high-density aerosol focusing for 1#22; m silica spheres. Preliminary results recover previous findings on aerodynamic focusing at low densities. At higher densities, it is demonstrated that the focusing properties change in a way which is consistent with a density dependent Stokes number.

  2. Method of high-density foil fabrication

    DOE Patents [OSTI]

    Blue, Craig A.; Sikka, Vinod K.; Ohriner, Evan K.

    2003-12-16

    A method for preparing flat foils having a high density includes the steps of mixing a powdered material with a binder to form a green sheet. The green sheet is exposed to a high intensity radiative source adapted to emit radiation of wavelengths corresponding to an absorption spectrum of the powdered material. The surface of the green sheet is heated while a lower sub-surface temperature is maintained. An apparatus for preparing a foil from a green sheet using a radiation source is also disclosed.

  3. Deformation-Induced Color Changes in Mechanochromic Polyethylene Brent R. Crenshaw, Mark Burnworth, Devang Khariwala, Anne Hiltner,

    E-Print Network [OSTI]

    Mather, Patrick T.

    Deformation-Induced Color Changes in Mechanochromic Polyethylene Blends Brent R. Crenshaw, Mark and systematic investigation of mechanochromic, melt-processed blends between a series of polyethylenes (PE-density polyethylene (LLDPE) of moderately high density (0.94 g cm-3). In samples that were slowly cooled from the melt

  4. Ultra-high density diffraction grating

    DOE Patents [OSTI]

    Padmore, Howard A.; Voronov, Dmytro L.; Cambie, Rossana; Yashchuk, Valeriy V.; Gullikson, Eric M.

    2012-12-11

    A diffraction grating structure having ultra-high density of grooves comprises an echellette substrate having periodically repeating recessed features, and a multi-layer stack of materials disposed on the echellette substrate. The surface of the diffraction grating is planarized, such that layers of the multi-layer stack form a plurality of lines disposed on the planarized surface of the structure in a periodical fashion, wherein lines having a first property alternate with lines having a dissimilar property on the surface of the substrate. For example, in one embodiment, lines comprising high-Z and low-Z materials alternate on the planarized surface providing a structure that is suitable as a diffraction grating for EUV and soft X-rays. In some embodiments, line density of between about 10,000 lines/mm to about 100,000 lines/mm is provided.

  5. Lanai high-density irradiance sensor network for characterizing...

    Office of Scientific and Technical Information (OSTI)

    Lanai high-density irradiance sensor network for characterizing solar resource variability of MW-scale PV system. Citation Details In-Document Search Title: Lanai high-density...

  6. Wood plastic composites based on microfibrillar blends of high density polyethylene/poly(ethylene terephthalate)

    E-Print Network [OSTI]

    profiles, boat hulls, and automotive compo- nents. The global WPC market in North America and Europe has., 2001). Ther- mal stability of cellulose is greater than lignin and hemicellulose, but unfortunately flour usually contains 40­45% cellulose, 20­25% hemicellulose, and 26­34% lignin (Han and Rowell, 1996

  7. Granular Dynamics in Pebble Bed Reactor Cores

    E-Print Network [OSTI]

    Laufer, Michael Robert

    2013-01-01

    Design Criteria for Nucler Power Plants,” U.S. NuclearDesign Criteria GRECO Granular Recirculation Code HDPE High-Density Polyethylene HTR High-Temperature Reactor NRC Nuclear

  8. Observable to explore high density behaviour of symmetry energy

    E-Print Network [OSTI]

    Aman D. Sood

    2011-09-28

    We aim to see the sensitivity of collective transverse in-plane flow to symmetry energy at low as well as high densities and also to see the effect of different density dependencies of symmetry energy on the same.

  9. Effects of Surface Properties on Adhesion of Protein to Biomaterials 

    E-Print Network [OSTI]

    Feng, Fangzhou

    2011-10-21

    of implants. The present research evaluates and analyzes the adhesive strength of proteins on pure High Density Polyethylene (HDPE), Single Wall Carbon Nanotube (SWCNT) enhanced HDPE composites, Ti-C:H coating and Ti6Al4V alloys (grade 2). The adhesive...

  10. Annealed high-density amorphous ice under pressure

    E-Print Network [OSTI]

    Loss, Daniel

    : 28 May 2006; doi:10.1038/nphys313 The well-known expansion of water on cooling below 277 K is one below 277 K responsible for lakes and seas freezing from the top down. This curious behaviour has been- order transition line between low- and high-density water below 220 K, but that cannot be tested

  11. Electron shielding of vortons in high-density quark matter

    E-Print Network [OSTI]

    Paulo F. Bedaque; Evan Berkowitz; Geoffrey Ji; Nathan Ng

    2011-12-06

    We consider the the effect of the electron cloud about a vorton in the CFL-$K^0$ high-density phase by numerically solving the ultrarelativistic Thomas-Fermi equation about a toroidal charge. Including electrons removes the electric monopole contribution to the energy, and noticeably decreases the equilibrium radius of these stable vortex loops.

  12. Magnetic confinement of a high-density cylindrical plasma

    SciTech Connect (OSTI)

    Ahedo, Eduardo [E. T. S. Ingenieros Aeronauticos, Universidad Politecnica de Madrid, Madrid 28040 (Spain)

    2011-10-15

    The stationary structure of a weakly collisional plasma column, confined by an axial magnetic field and a cylindrical vessel, is studied for the high-density case, when the diamagnetic azimuthal current is large enough to demagnetize partially the plasma. The plasma response is characterized mainly by two dimensionless parameters: the ratios of the electron gyroradius and the electron skin-depth to the plasma radius, and each of them measures the independent influence of the applied magnetic field and the plasma density on the plasma response. The strong magnetic confinement regime, characterized by very small wall losses, is limited to the small gyroradius and large skin-depth ranges. In the high-density case, when the electron skin-depth is smaller than the electron gyroradius, the skin-depth turns out to be the magnetic screening length, so that the bulk of the plasma behaves as unmagnetized.

  13. CHARACTERISATION OF AGED HDPE PIPES FROM DRINKING WATER DISTRIBUTION: INVESTIGATION OF CRACK DEPTH BY NOL RING

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    BY NOL RING TESTS UNDER CREEP LOADING C. Devilliers 1), 2), 3) , L. Laiarinandrasana 1) , B. Fayolle 2. KEYWORDS HDPE pipes, Nol Ring creep test, ageing effects, fracture mechanism, crack depth ratio, aged layer loading than a monotonic tensile loading. It is to be noticed that the Nol Ring test subjected to a creep

  14. High density electronic circuit and process for making

    DOE Patents [OSTI]

    Morgan, W.P.

    1999-06-29

    High density circuits with posts that protrude beyond one surface of a substrate to provide easy mounting of devices such as integrated circuits are disclosed. The posts also provide stress relief to accommodate differential thermal expansion. The process allows high interconnect density with fewer alignment restrictions and less wasted circuit area than previous processes. The resulting substrates can be test platforms for die testing and for multi-chip module substrate testing. The test platform can contain active components and emulate realistic operational conditions, replacing shorts/opens net testing. 8 figs.

  15. A Cherenkov Radiation Detector with High Density Aerogels

    E-Print Network [OSTI]

    Cremaldi, Lucien; Sonnek, Peter; Summers, Donald J; Reidy, Jim

    2009-01-01

    We have designed a threshold Cherenkov detector at the Rutherford-Appleton Laboratory to identify muons with momenta between 230 and 350 MeV/c. We investigated the properties of three aerogels for the design. The nominal indexes of refraction were n = 1.03, 1.07, 1.12, respectively. Two of the samples are of high density aerogel not commonly used for Cherenkov light detection. We present results of an examination of some optical properties of the aerogel samples and present basic test beam results.

  16. High-density percutaneous chronic connector for neural prosthetics

    SciTech Connect (OSTI)

    Shah, Kedar G.; Bennett, William J.; Pannu, Satinderpall S.

    2015-09-22

    A high density percutaneous chronic connector, having first and second connector structures each having an array of magnets surrounding a mounting cavity. A first electrical feedthrough array is seated in the mounting cavity of the first connector structure and a second electrical feedthrough array is seated in the mounting cavity of the second connector structure, with a feedthrough interconnect matrix positioned between a top side of the first electrical feedthrough array and a bottom side of the second electrical feedthrough array to electrically connect the first electrical feedthrough array to the second electrical feedthrough array. The two arrays of magnets are arranged to attract in a first angular position which connects the first and second connector structures together and electrically connects the percutaneously connected device to the external electronics, and to repel in a second angular position to facilitate removal of the second connector structure from the first connector structure.

  17. Methods and systems for rapid prototyping of high density circuits

    DOE Patents [OSTI]

    Palmer, Jeremy A. (Albuquerque, NM); Davis, Donald W. (Albuquerque, NM); Chavez, Bart D. (Albuquerque, NM); Gallegos, Phillip L. (Albuquerque, NM); Wicker, Ryan B. (El Paso, TX); Medina, Francisco R. (El Paso, TX)

    2008-09-02

    A preferred embodiment provides, for example, a system and method of integrating fluid media dispensing technology such as direct-write (DW) technologies with rapid prototyping (RP) technologies such as stereolithography (SL) to provide increased micro-fabrication and micro-stereolithography. A preferred embodiment of the present invention also provides, for example, a system and method for Rapid Prototyping High Density Circuit (RPHDC) manufacturing of solderless connectors and pilot devices with terminal geometries that are compatible with DW mechanisms and reduce contact resistance where the electrical system is encapsulated within structural members and manual electrical connections are eliminated in favor of automated DW traces. A preferred embodiment further provides, for example, a method of rapid prototyping comprising: fabricating a part layer using stereolithography and depositing thermally curable media onto the part layer using a fluid dispensing apparatus.

  18. Tilescope: online analysis pipeline for high-density tiling microarray data Zhengdong D. Zhang1

    E-Print Network [OSTI]

    Gerstein, Mark

    1 Tilescope: online analysis pipeline for high-density tiling microarray data Zhengdong D. Zhang1 pipeline Key words: high-density tiling microarray, high-density oligonucleotide microarray, microarray processing pipeline for analyzing tiling array data (http://tilescope.gersteinlab.org). In a completely

  19. Surface interactions involved in flashover with high density electronegative gases.

    SciTech Connect (OSTI)

    Hodge, Keith Conquest; Warne, Larry Kevin; Jorgenson, Roy Eberhardt; Wallace, Zachariah Red; Lehr, Jane Marie

    2010-01-01

    This report examines the interactions involved with flashover along a surface in high density electronegative gases. The focus is on fast ionization processes rather than the later time ionic drift or thermalization of the discharge. A kinetic simulation of the gas and surface is used to examine electron multiplication and includes gas collision, excitation and ionization, and attachment processes, gas photoionization and surface photoemission processes, as well as surface attachment. These rates are then used in a 1.5D fluid ionization wave (streamer) model to study streamer propagation with and without the surface in air and in SF6. The 1.5D model therefore includes rates for all these processes. To get a better estimate for the behavior of the radius we have studied radial expansion of the streamer in air and in SF6. The focus of the modeling is on voltage and field level changes (with and without a surface) rather than secondary effects, such as, velocities or changes in discharge path. An experiment has been set up to carry out measurements of threshold voltages, streamer velocities, and other discharge characteristics. This setup includes both electrical and photographic diagnostics (streak and framing cameras). We have observed little change in critical field levels (where avalanche multiplication sets in) in the gas alone versus with the surface. Comparisons between model calculations and experimental measurements are in agreement with this. We have examined streamer sustaining fields (field which maintains ionization wave propagation) in the gas and on the surface. Agreement of the gas levels with available literature is good and agreement between experiment and calculation is good also. Model calculations do not indicate much difference between the gas alone versus the surface levels. Experiments have identified differences in velocity between streamers on the surface and in the gas alone (the surface values being larger).

  20. Continuous Processing of High Thermal Conductivity Polyethylene...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Processing of High Thermal Conductivity Polyethylene Fibers and Sheets Continuous Processing of High Thermal Conductivity Polyethylene Fibers and Sheets Massachusetts Institute of...

  1. Topological Twistons in Crystalline Polyethylene

    E-Print Network [OSTI]

    D. Bazeia; E. Ventura

    1999-02-09

    We introduce an alternate model to describe twistons in crystalline polyethylene. The model couples torsional and longitudinal degrees of freedom and appears as an extension of a model that describes only the torsional motion. We find exact solutions that describe stable topological twistons, in good agreement with the torsional and longitudinal interactions in polyethylene.

  2. Flying-plate detonator using a high-density high explosive

    DOE Patents [OSTI]

    Stroud, John R. (Livermore, CA); Ornellas, Donald L. (Livermore, CA)

    1988-01-01

    A flying-plate detonator containing a high-density high explosive such as benzotrifuroxan (BTF). The detonator involves the electrical explosion of a thin metal foil which punches out a flyer from a layer overlying the foil, and the flyer striking a high-density explosive pellet of BTF, which is more thermally stable than the conventional detonator using pentaerythritol tetranitrate (PETN).

  3. Aerodynamic focusing of high-density aerosols D.E. Ruiz a,n

    E-Print Network [OSTI]

    be modeled by a simple drag force within a prescribed background flowing gas. The particle-to-gas feedback to study the properties of high-density aerosol focusing for 1 m silica spheres. Preliminary results

  4. Negatively Cooperative Binding of High-Density Lipoprotein to the HDL Receptor SR-BI

    E-Print Network [OSTI]

    Xu, Shangzhe

    Scavenger receptor class B, type I (SR-BI), is a high-density lipoprotein (HDL) receptor, which also binds low-density lipoprotein (LDL), and mediates the cellular selective uptake of cholesteryl esters from lipoproteins. ...

  5. Lower hybrid current drive at high density in Alcator C-Mod

    E-Print Network [OSTI]

    Harvey, R.W.

    Experimental observations of lower hybrid current drive (LHCD) at high density on the Alcator C-Mod tokamak are presented in this paper. Bremsstrahlung emission from relativistic fast electrons in the core plasma drops ...

  6. , 2003, 123, . 3, . 1 16 c INTERNAL ENERGY OF HIGH-DENSITY HYDROGEN

    E-Print Network [OSTI]

    Bonitz, Michael

    Ć?Ć¯Ć?Ć?, 2003, Ć²Ć®Ć¬ 123, Ć¢Ć»ĆÆ. 3, Ć±Ć²Ć°. 1#21;16 c 2003 INTERNAL ENERGY OF HIGH-DENSITY HYDROGEN 2002 The internal energy of high-density hydrogen plasmas in the temperature range T = 10000-UniversitƤt Berlin D-10115, Berlin, Germany b Institute for High Energy Density, Russian Academy of Sciences 127412

  7. High density, optically corrected, micro-channel cooled, v-groove monolithic laser diode array

    DOE Patents [OSTI]

    Freitas, Barry L. (Livermore, CA)

    1998-01-01

    An optically corrected, micro-channel cooled, high density laser diode array achieves stacking pitches to 33 bars/cm by mounting laser diodes into V-shaped grooves. This design will deliver>4kW/cm2 of directional pulsed laser power. This optically corrected, micro-channel cooled, high density laser is usable in all solid state laser systems which require efficient, directional, narrow bandwidth, high optical power density pump sources.

  8. Photon tunnelling microscopy of polyethylene single crystals

    E-Print Network [OSTI]

    Srinivasarao, Mohan

    Photon tunnelling microscopy of polyethylene single crystals Mohan Srinivasarao* and Richard S:photon tunnellingmicroscopy;single crystals; polyethylene) INTRODUCTION The study of morphology of polymers is an area

  9. Nanoscale Calorimetry of Isolated Polyethylene Single Crystals

    E-Print Network [OSTI]

    Allen, Leslie H.

    Nanoscale Calorimetry of Isolated Polyethylene Single Crystals A. T. KWAN, M. YU. EFREMOV, E. A-film differential scanning calorimetry to investigate the melt- ing of isolated polyethylene single crystals of lamellar single crystals of polyethylene (PE). We obtain thickness, diffraction, and calorimetry data

  10. This article appeared in a journal published by Elsevier. The attached copy is furnished to the author for internal non-commercial research

    E-Print Network [OSTI]

    15 April 2009 Keywords: A. Polymer­matrix composites A. Fibers A. Recycling E. Extrusion a b s t r's personal copy Morphology and properties of microfibrillar composites based on recycled poly (ethylene a c t Microfibrillar composites (MFCs) from recycled high density polyethylene (R-HDPE)/recycled poly

  11. I Designer's Forum I By Dr. Timothy Stark and Gregory N.

    E-Print Network [OSTI]

    of geonet or drainage composite, geotextile cushions and/or filters and a geomembrane. An important to investigate the shear behavior of flexible geomem- brane/nonwoven geotextile interfaces. Specifically,a 0 geotextiles and compared to l.5-mm-thick smooth and textured high-density polyethylene (HDPE) and very

  12. Conference 

    E-Print Network [OSTI]

    Unknown

    2011-08-17

    contemporary search techniques implemented in commercial software. The methodology is demonstrated on high-molecular-weight, high-density polyethylene (HMW/HDPE) cylinders arrayed in a single line to form a crash cushion which carries the trade name REACT® 350...

  13. The final stage of gravitational collapse for high density fluid medium

    SciTech Connect (OSTI)

    Souza, R. G.; De Campos, M.

    2013-03-25

    The High density high density fluids can be represented by a stiff matter state equation P={rho} and also by the Hagedorn state equation. The first is constructed using a lagrangian that allows bare nucleons to interact attractively via scalar meson exchange, and repulsively by a more massive vector meson exchange; the second consider that for large mass the spectrum of hadrons grows exponentially, namely {rho}(m) {approx}exp(m/T{sub H}), where T{sub H} is the Hagedorn temperature, resulting the state equation P = P{sub 0}+{rho}{sub 0}ln({rho}/{rho}{sub 0}). We study the gravitational collapse for a high density fluid, considering a Hagedorn state equation in a presence of a vacuum component.

  14. High Density Neutron Star Equation of State from 4U 1636-53 Observations

    E-Print Network [OSTI]

    T. S. Olson

    2002-01-07

    A bound on the compactness of the neutron star in the low mass x-ray binary 4U 1636-53 is used to estimate the equation of state of neutron star matter at high density. Observations of 580 Hz oscillations during the rising phase of x-ray bursts from this system appear to be due to two antipodal hot spots on the surface of an accreting neutron star rotating at 290 Hz, implying the compactness of the neutron star is less than 0.163 at the 90% confidence level. The equation of state of high density neutron star matter estimated from this compactness limit is significantly stiffer than extrapolations to high density of equations of state determined by fits of experimental nucleon-nucleon scattering data and properties of light nuclei to two- and three-body interaction potentials.

  15. LOW POWER SCANNER FOR HIGH-DENSITY ELECTRODE ARRAY NEURAL RECORDING

    E-Print Network [OSTI]

    Mahmoodi, Hamid

    of this research is to design a low power integrated system that can be used in vivo for scanning the electrode. A model created in Python provides input vectors and output comparison for the verification processLOW POWER SCANNER FOR HIGH-DENSITY ELECTRODE ARRAY NEURAL RECORDING A Thesis work submitted

  16. Non-contact Low Power EEG/ECG Electrode for High Density Wearable Biopotential Sensor

    E-Print Network [OSTI]

    Cauwenberghs, Gert

    Non-contact Low Power EEG/ECG Electrode for High Density Wearable Biopotential Sensor Networks Yu Mchi@ucsd.edu Abstract--A non-contact capacitive biopotential electrode with a common-mode noise senses the local biopotential with a differential gain of 46dB over a 1-100Hz bandwidth. Signals

  17. Understanding and Mitigating Refresh Overheads in High-Density DDR4 DRAM Systems

    E-Print Network [OSTI]

    Martķnez, José F.

    Understanding and Mitigating Refresh Overheads in High-Density DDR4 DRAM Systems Janani Mukundan as part of JEDEC's DDR4 DRAM specification that at- tempts to tackle this problem by creating a range conduct an analysis of DDR4 DRAM's FGR feature, and show that there is no one-size-fits-all option across

  18. Battery concepts for high density energy storage: Principles and practice. C. Austen Angell

    E-Print Network [OSTI]

    Angell, C. Austen

    of biblical times. Currently, success in this area is critical if solar energy harnessing is to become tolerate voltages above 5V, are needed. In this area, unlike materials science, the technology developedBattery concepts for high density energy storage: Principles and practice. C. Austen Angell Dept

  19. A Portable Low-Cost High Density Sensor Network for Air Quality at London Heathrow Airport

    E-Print Network [OSTI]

    Jackson, Sophie

    species: CO, NO, O3, SO2, NO2 (electrochemical (EC) at 2 s) CO2 and total VOCs (optical at 10 s). · Size stations outside LHR (all CO2, sizeA Portable Low-Cost High Density Sensor Network for Air Quality at London Heathrow Airport Olalekan

  20. Imprinted large-scale high density polymer nanopillars for organic solar cells

    E-Print Network [OSTI]

    Gao, Jinming

    Imprinted large-scale high density polymer nanopillars for organic solar cells Mukti Aryal used to make bulk heterojunction solar cells by depositing PCBM on top of the pillars. Imprinting provides a way to precisely control the interdigitized heterojunction morphology, leading to improved solar

  1. Electrostatically-driven elastomer components for user-reconfigurable high density microfluidics

    E-Print Network [OSTI]

    Maharbiz, Michel

    Electrostatically-driven elastomer components for user-reconfigurable high density microfluidics microfluidic system intended for very large scale integration (VLSI) microfluidics. By adding thin film metal with standard PDMS microfluidics, has actuation voltages low enough to be driven by commercial CMOS IC's and can

  2. Device and method for electron beam heating of a high density plasma

    DOE Patents [OSTI]

    Thode, Lester E. (Los Alamos, NM)

    1981-01-01

    A device and method for relativistic electron beam heating of a high density plasma in a small localized region. A relativistic electron beam generator produces a high voltage electron beam which propagates along a vacuum drift tube and is modulated to initiate electron bunching within the beam. The beam is then directed through a low density gas chamber which provides isolation between the vacuum modulator and the relativistic electron beam target. The relativistic beam is then applied to a high density target plasma which typically comprises DT, DD, hydrogen boron or similar thermonuclear gas at a density of 10.sup.17 to 10.sup.20 electrons per cubic centimeter. The target plasma is ionized prior to application of the electron beam by means of a laser or other preionization source. Utilizing a relativistic electron beam with an individual particle energy exceeding 3 MeV, classical scattering by relativistic electrons passing through isolation foils is negligible. As a result, relativistic streaming instabilities are initiated within the high density target plasma causing the relativistic electron beam to efficiently deposit its energy into a small localized region within the high density plasma target.

  3. Magnetic confinement of a high-density cylindrical plasma Eduardo Ahedoa)

    E-Print Network [OSTI]

    Carlos III de Madrid, Universidad

    collisional plasma column, confined by an axial magnetic field and a cylindrical vessel, is studiedMagnetic confinement of a high-density cylindrical plasma Eduardo Ahedoa) E. T. S. Ingenieros the independent influence of the applied magnetic field and the plasma density on the plasma response. The strong

  4. High Density H-Mode Discharges with Gas Fueling and Good Confinement on DIII-D

    SciTech Connect (OSTI)

    A.W. Leonard; T.H. Osborne; M.A. Mahdavi; M.E. Fenstermacher; C.J. Lasnier; T.W. Petrie; J.G.Watkins

    2000-08-01

    H-mode operation at high density is an attractive regime for future reactor-grade tokamaks [1]. High density maximizes fusion power output while the high confinement of H-mode keeps the plasma energy loss below the alpha heating power. One concern though is the energy released due to individual ELMs must be kept small to protect the diverter target from excess ablation. We report on discharges in DIII-D with electron densities as high as 1.45 times the Greenwald density, n{sub GW}(10{sup 20}m{sup -3})=I{sub p}(MA)/[{pi}{sup 2}(m)], with good confinement, H{sub ITER89P}=1.9, and ELMs with energy amplitude small enough to protect the divertor. These results were achieved at low triangularity single-null divertor, {delta}{approx}0.0 with a plasma current of 1.2 MA, q{sub 95} {approx} 3-4, and moderate neutral beam heating power of 2-4 MW. The density was controlled by moderate gas puffing and private flux pumping. A typical discharge is shown in Fig. 1 where upon gas puffing the pedestal density, n{sub e,epd}, quickly rises to {approx}0.8 x n{sub GW}. The confinement initially drops with the gas puff, on a longer timescale the central density rises, peaking the profile and increasing the confinement until an MHD instability terminates the high density and high confinement phase of the discharge. In this report we describe in detail edge pedestal changes and its effect on confinement as the density is increased. We then describe peaking of the density profile that offsets degradation of the pedestal at high density and restores good confinement. Finally we describe the small benign ELMs that result at these high densities.

  5. Continuous Processing of High Thermal Conductivity Polyethylene...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    conductivity polyethylene fibers and sheets will be developed to replace metals and ceramics in heat-transfer devices. Project innovations include using massively parallel...

  6. Laboratory and Field Performance of Buried Steel-Reinforced High Density Polyethylene (SRHDPE) Pipes in a Ditch Condition under a Shallow Cover

    E-Print Network [OSTI]

    Khatri, Deep Kumar

    2014-05-31

    during installation and loadings, and (6) the highest measured strains recorded in steel and plastic during the installation and loadings in all the tests were within the permissible values. The laboratory tests however have some limitations. For example...

  7. Branch content of metallocene polyethylene Ramnath Ramachandran, Gregory Beaucage*

    E-Print Network [OSTI]

    Beaucage, Gregory

    Branch content of metallocene polyethylene Ramnath Ramachandran, Gregory Beaucage* and Amit catalyzed polyethylene (PE). A novel scaling approach is applied to determine the mole fraction branch solutions of metallocene polyethylene samples, to quantify the LCB content in polymers previously studied

  8. Relativistic Mean-Field Theory and the High-Density Nuclear Equation of State

    E-Print Network [OSTI]

    Horst Mueller; Brian D. Serot

    1996-03-22

    The properties of high-density nuclear and neutron matter are studied using a relativistic mean-field approximation to the nuclear matter energy functional. Based on ideas of effective field theory, nonlinear interactions between the fields are introduced to parametrize the density dependence of the energy functional. Various types of nonlinearities involving scalar-isoscalar ($\\sigma$), vector-isoscalar ($\\omega$), and vector-isovector ($\\rho$) fields are studied. After calibrating the model parameters at equilibrium nuclear matter density, the model and parameter dependence of the resulting equation of state is examined in the neutron-rich and high-density regime. It is possible to build different models that reproduce the same observed properties at normal nuclear densities, but which yield maximum neutron star masses that differ by more than one solar mass. Implications for the existence of kaon condensates or quark cores in neutron stars are discussed.

  9. Poly(ethylene oxide) functionalization

    DOE Patents [OSTI]

    Pratt, Russell Clayton

    2014-04-08

    A simple procedure is provided by which the hydroxyl termini of poly(ethylene oxide) can be appended with functional groups to a useful extent by reaction and precipitation. The polymer is dissolved in warmed toluene, treated with an excess of organic base and somewhat less of an excess of a reactive acylating reagent, reacted for several hours, then precipitated in isopropanol so that the product can be isolated as a solid, and salt byproducts are washed away. This procedure enables functionalization of the polymer while not requiring laborious purification steps such as solvent-solvent extraction or dialysis to remove undesirable side products.

  10. A study of electromagnetic showers in the high density projection chamber

    SciTech Connect (OSTI)

    Albrecht, E.; Berggren, M.; Cattai, A.; Fischer, H.G.; Flammier, M.; Gerutti, G.; Innocenti, P.G.; Iversen, P.S.

    1983-02-01

    A prototype module of a High density Projection Chamber (HPC) has been tested in an electron beam. The HPC, with the shower conversion separated from the charge collection, offers a simple, homogeneous large volume detector with an energy resolution of 12.5%/..sqrt..E and an exceptionally fine granularity both along and transverse to the shower axis. The results from the test are presented together with a description of the calorimeter system.

  11. Effect of optically modified polyethylene terephthalate fiber socks on chronic foot pain

    E-Print Network [OSTI]

    York, Robyn MB; Gordon, Ian L

    2009-01-01

    of optically modified polyethylene terephthalate fiber sockswhether socks made from polyethylene terephthalate (PET)

  12. Z .Surface and Coatings Technology 130 2000 164 172 Production of high-density Ni-bonded tungsten carbide

    E-Print Network [OSTI]

    Ghoniem, Nasr M.

    Z .Surface and Coatings Technology 130 2000 164 172 Production of high-density Ni-bonded tungsten carbide coatings using an axially fed DC-plasmatron S. Sharafata,U , A. Kobayashib , S. Chena , N of high-density Ni WC coatings were produces with uniform distribution of WC particles. The small powder

  13. A Novel VLSI Technology to Manufacture High-Density Thermoelectric Cooling Devices

    E-Print Network [OSTI]

    H. Chen; L. Hsu; X. Wei

    2008-01-07

    This paper describes a novel integrated circuit technology to manufacture high-density thermoelectric devices on a semiconductor wafer. With no moving parts, a thermoelectric cooler operates quietly, allows cooling below ambient temperature, and may be used for temperature control or heating if the direction of current flow is reversed. By using a monolithic process to increase the number of thermoelectric couples, the proposed solid-state cooling technology can be combined with traditional air cooling, liquid cooling, and phase-change cooling to yield greater heat flux and provide better cooling capability.

  14. High-Density Plasma Arc Heating Studies of FePt Thin Films

    SciTech Connect (OSTI)

    Cole, Amanda C; Thompson, Gregory; Harrell, J. W.; Weston, James; Ott, Ronald D

    2006-01-01

    The effect of pulsed-thermal-processing with high-density plasma arc heating is discussed for 20 nm thick nanocrystalline FePt thin films. The dependence of the A1 {yields} L1{sub 0} phase transformation on pulsed time and radiant energy of the pulse is quantified through x-ray diffraction and alternating gradient magnetometry. For 100 ms and 250 ms pulse widths, the phase transformation was observed. Higher radiant energy densities resulted in a larger measured coercivity associated with the L1{sub 0} phase.

  15. Branch length distribution in TREF fractionated polyethylene Ramnath Ramachandran a

    E-Print Network [OSTI]

    Beaucage, Gregory

    Branch length distribution in TREF fractionated polyethylene Ramnath Ramachandran a , Gregory Keywords: Polyethylene Branching Neutron scattering a b s t r a c t Commercial polyethylene is typically and catalyst activity. Further, processing of polyethylene after polymerization may also result in changes

  16. Cryogenic THD and DT layer implosions with high density carbon ablators in near-vacuum hohlraums

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Meezan, N. B. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Berzak Hopkins, L. F. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)] (ORCID:0000000291875667); Le Pape, S. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Divol, L. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); MacKinnon, A. J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Döppner, T. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Ho, D. D. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Jones, O. S. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Khan, S. F. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Ma, T. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Milovich, J. L. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Pak, A. E. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Ross, J. S. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Thomas, C. A. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Benedetti, L. R. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Bradley, D. K. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Celliers, P. M. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Clark, D. S. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)] (ORCID:0000000272137538); Field, J. E. [Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94551-0808, USA; Haan, S. W. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)] (ORCID:0000000184045131); Izumi, N. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Kyrala, G. A. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Moody, J. D. [Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94551-0808, USA; Patel, P. K. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Ralph, J. E. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Rygg, J. R. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Sepke, S. M. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Spears, B. K. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Tommasini, R. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Town, R. P. J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Biener, J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Bionta, R. M. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Bond, E. J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Caggiano, J. A. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Eckart, M. J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Gatu Johnson, M. [MIT (Massachusetts Inst. of Technology), Cambridge, MA (United States); Grim, G. P. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Hamza, A. V. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Hartouni, E. P. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)] (ORCID:0000000198694351); Hatarik, R. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Hoover, D. E. [General Atomics, San Diego, CA (United States)] (ORCID:0000000195652551); Kilkenny, J. D. [General Atomics, San Diego, CA (United States); Kozioziemski, B. J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Kroll, J. J. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); McNaney, J. M. [General Atomics, San Diego, CA (United States); Nikroo, A. [General Atomics, San Diego, CA (United States); Sayre, D. B. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2015-06-01

    High Density Carbon (HDC or diamond) is a promising ablator material for use in near-vacuum hohlraums, as its high density allows for ignition designs with laser pulse durations of et al., Phys. Plasmas 16, 041006 (2009)] culminated in a DT layered implosion driven by a 6.8 ns, 2-shock laser pulse. This paper describes these experiments and comparisons with ICF design code simulations. Backlit radiography of a THD layered capsule demonstrated an ablator implosion velocity of 385 km/s with a slightly oblate hot spot shape. Other diagnostics suggested an asymmetric compressed fuel layer. A streak camera-based hot spot self-emission diagnostic (SPIDER) showed a double-peaked history of the capsule self-emission. Simulations suggest that this is a signature of low quality hot spot formation. Changes to the laser pulse and pointing for a subsequent DT implosion resulted in a higher temperature, prolate hot spot and a thermonuclear yield of 1.8 x 10¹? neutrons, 40% of the 1D simulated yield.

  17. Cryogenic THD and DT layer implosions with high density carbon ablators in near-vacuum hohlraums

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Meezan, N. B.; Berzak Hopkins, L. F.; Le Pape, S.; Divol, L.; MacKinnon, A. J.; Döppner, T.; Ho, D. D.; Jones, O. S.; Khan, S. F.; Ma, T.; et al

    2015-06-02

    High Density Carbon (HDC or diamond) is a promising ablator material for use in near-vacuum hohlraums, as its high density allows for ignition designs with laser pulse durations of et al., Phys. Plasmas 16, 041006 (2009)] culminated in a DT layered implosion driven by a 6.8 ns, 2-shock laser pulse. This paper describes these experiments and comparisons with ICF design code simulations. Backlit radiography of a THD layered capsule demonstrated an ablator implosion velocity of 385 km/s with a slightlymore »oblate hot spot shape. Other diagnostics suggested an asymmetric compressed fuel layer. A streak camera-based hot spot self-emission diagnostic (SPIDER) showed a double-peaked history of the capsule self-emission. Simulations suggest that this is a signature of low quality hot spot formation. Changes to the laser pulse and pointing for a subsequent DT implosion resulted in a higher temperature, prolate hot spot and a thermonuclear yield of 1.8 x 10¹? neutrons, 40% of the 1D simulated yield.« less

  18. Polyethylene as a Radiation Shielding Standard in Simulated Cosmic-Ray Environments

    E-Print Network [OSTI]

    2006-01-01

    on the ISS through polyethylene shielding augmentation ofnucleon Iron-56 in Polyethylene. II. , Comparisons betweenPolyethylene as a Radiation Shielding Standard in Simulated

  19. A strategy for the quantification of protein polyethylene glycol (PEG) derivatized sites using iTRAQ

    E-Print Network [OSTI]

    Monk, Rebecca Helen

    2011-01-01

    for characterization of polyethylene glycol-derivatizedof the attachment sites in polyethylene glycol-derivatizedfor the Quantification of Protein Polyethylene Glycol (PEG)

  20. Polyethylene as a Radiation Shielding Standard in Simulated Cosmic-Ray Environments

    E-Print Network [OSTI]

    2006-01-01

    on the ISS through polyethylene shielding augmentation offrom traversal of polyethylene shielding. We define theof the shielding properties of polyethylene and other

  1. High Density Hydrogen Storage System Demonstration Using NaAlH4 Based Complex Compound Hydrides

    SciTech Connect (OSTI)

    Daniel A. Mosher; Xia Tang; Ronald J. Brown; Sarah Arsenault; Salvatore Saitta; Bruce L. Laube; Robert H. Dold; Donald L. Anton

    2007-07-27

    This final report describes the motivations, activities and results of the hydrogen storage independent project "High Density Hydrogen Storage System Demonstration Using NaAlH4 Based Complex Compound Hydrides" performed by the United Technologies Research Center under the Department of Energy Hydrogen Program, contract # DE-FC36-02AL67610. The objectives of the project were to identify and address the key systems technologies associated with applying complex hydride materials, particularly ones which differ from those for conventional metal hydride based storage. This involved the design, fabrication and testing of two prototype systems based on the hydrogen storage material NaAlH4. Safety testing, catalysis studies, heat exchanger optimization, reaction kinetics modeling, thermochemical finite element analysis, powder densification development and material neutralization were elements included in the effort.

  2. A Model For the Formation of High Density Clumps in Proto-Planetary Nebulae

    E-Print Network [OSTI]

    Patrick A. Young; J. L. Highberger; David Arnett; L. M. Ziurys

    2003-09-19

    The detection of NaCl at large radii in the Egg Nebula, CRL 2688, requires densities of 10^7 - 10^8 cm^-3 in a thick shell of r ~ a few X 10^17 cm. To explain these results, a mechanism is needed for producing high densities at a considerable distance from the central star. In two dimensional simulations of the interaction of the fast wind with an ambient medium, the material becomes thermally unstable. The resulting clumps can achieve the requisite conditions for NaCl excitation. We present 2D models with simple physics as proof-of-principle calculations to show that the clumping behavior is robust. Clumping is a natural outcome of cooling in the colliding wind model and comparable to that inferred from observations.

  3. A Microelectromechanical High-Density Energy Storage/Rapid Release System

    SciTech Connect (OSTI)

    Rodgers, M. Steven; Allen, Jim J.; Meeks, Kent D.; Jensen, Brian D.; Miller, Sam L.

    1999-07-21

    One highly desirable characteristic of electrostatically driven microelectromechanical systems (MEMS) is that they consume very little power. The corresponding drawback is that the force they produce may be inadequate for many applications. It has previously been demonstrated that gear reduction units or microtransmissions can substantially increase the torque generated by microengines. Operating speed, however, is also reduced by the transmission gear ratio. Some applications require both high speed and high force. If this output is only required for a limited period of time, then energy could be stored in a mechanical system and rapidly released upon demand. We have designed, fabricated, and demonstrated a high-density energy storage/rapid release system that accomplishes this task. Built using a 5-level surface micromachining technology, the assembly closely resembles a medieval crossbow. Energy releases on the order of tens of nanojoules have already been demonstrated, and significantly higher energy systems are under development.

  4. Process and system for producing high-density pellets from a gaseous medium

    DOE Patents [OSTI]

    Foster, Christopher A. (Clinton, TN)

    1999-01-01

    A process and system for producing pellets of high density carbon dioxide or other gases utilize a chamber containing a plurality of cell-like freezing compartments within which ice is to be formed. A gas desired to be frozen into ice is introduced into the chamber while the internal pressure of the chamber is maintained at a level which is below the equilibrium triple pressure of the gas. The temperature of the freezing compartments is lowered to a temperature which is below the equilibrium vapor pressure temperature of the gas at the chamber pressure so that the gas condenses into ice within the compartments. The temperature of the freezing compartments is thereafter raised so that the ice is thereby released from and falls out of the compartments as pellets for collection.

  5. Thermodynamics and Structural Properties of the High Density Gaussian Core Model

    E-Print Network [OSTI]

    Atsushi Ikeda; Kunimasa Miyazaki

    2011-07-20

    We numerically study thermodynamic and structural properties of the one-component Gaussian core model (GCM) at very high densities. The solid-fluid phase boundary is carefully determined. We find that the density dependence of both the freezing and melting temperatures obey the asymptotic relation, $\\log T_f$, $\\log T_m \\propto -\\rho^{2/3}$, where $\\rho$ is the number density, which is consistent with Stillinger's conjecture. Thermodynamic quantities such as the energy and pressure and the structural functions such as the static structure factor are also investigated in the fluid phase for a wide range of temperature above the phase boundary. We compare the numerical results with the prediction of the liquid theory with the random phase approximation (RPA). At high temperatures, the results are in almost perfect agreement with RPA for a wide range of density, as it has been already shown in the previous studies. In the low temperature regime close to the phase boundary line, although RPA fails to describe the structure factors and the radial distribution functions at the length scales of the interparticle distance, it successfully predicts their behaviors at shorter length scales. RPA also predicts thermodynamic quantities such as the energy, pressure, and the temperature at which the thermal expansion coefficient becomes negative, almost perfectly. Striking ability of RPA to predict thermodynamic quantities even at high densities and low temperatures is understood in terms of the decoupling of the length scales which dictate thermodynamic quantities from the interparticle distance which dominates the peak structures of the static structure factor due to the softness of the Gaussian core potential.

  6. Polymeric compositions incorporating polyethylene glycol as a phase change material

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH); Griffen, Charles W. (Mason, OH)

    1989-01-01

    A polymeric composition comprising a polymeric material and polyethylene glycol or end-capped polyethylene glycol as a phase change material, said polyethylene glycol and said end-capped polyethylene glycol having a molecular weight greater than about 400 and a heat of fusion greater than about 30 cal/g; the composition is useful in making molded and/or coated materials such as flooring, tiles, wall panels and the like; paints containing polyethylene glycols or end-capped polyethylene glycols are also disclosed.

  7. Compact star constraints on the high-density EoS

    E-Print Network [OSTI]

    H. Grigorian; D. Blaschke; T. Klahn

    2006-11-19

    A new scheme for testing the nuclear matter (NM) equation of state (EoS) at high densities using constraints from compact star (CS) phenomenology is applied to neutron stars with a core of deconfined quark matter (QM). An acceptable EoS shall not to be in conflict with the mass measurement of 2.1 +/- 0.2 M_sun (1 sigma level) for PSR J0751+1807 and the mass-radius relation deduced from the thermal emission of RX J1856-3754. Further constraints for the state of matter in CS interiors come from temperature-age data for young, nearby objects. The CS cooling theory shall agree not only with these data, but also with the mass distribution inferred via population synthesis models as well as with LogN-LogS data. The scheme is applied to a set of hybrid EsoS with a phase transition to stiff, color superconducting QM which fulfills all above constraints and is constrained otherwise from NM saturation properties and flow data of heavy-ion collisions. We extrapolate our description to low temperatures and draw conclusions for the QCD phase diagram to be explored in heavy-ion collision experiments.

  8. Microslit Nod-shuffle Spectroscopy - a technique for achieving very high densities of spectra

    E-Print Network [OSTI]

    Glazebrook, K; Glazebrook, Karl; Bland-Hawthorn, Joss

    2000-01-01

    We describe a new approach to obtaining very high surface densities of optical spectra in astronomical observations with extremely accurate subtraction of night sky emission. The observing technique requires that the telescope is nodded rapidly between targets and adjacent sky positions; object and sky spectra are recorded on adjacent regions of a low-noise CCD through charge shuffling. This permits the use of extremely high densities of small slit apertures (`microslits') since an extended slit is not required for sky interpolation. The overall multi-object advantage of this technique is as large as 2.9x that of conventional multi-slit observing for an instrument configuration which has an underfilled CCD detector and is always >1.5 for high target densities. The `nod-shuffle' technique has been practically implemented at the Anglo-Australian Telescope as the `LDSS++ project' and achieves sky-subtraction accuracies as good as 0.04%, with even better performance possible. This is a factor of ten better than i...

  9. High-density carbon ablator experiments on the National Ignition Facilitya)

    SciTech Connect (OSTI)

    MacKinnon, A. J.; Meezan, N. B.; Ross, J. S.; Le Pape, S.; Berzak Hopkins, L.; Divol, L.; Ho, D.; Milovich, J.; Pak, A.; Ralph, J.; Döppner, T.; Patel, P. K.; Thomas, C.; Tommasini, R.; Haan, S.; MacPhee, A. G.; McNaney, J.; Caggiano, J.; Hatarik, R.; Bionta, R.; Ma, T.; Spears, B.; Rygg, J. R.; Benedetti, L. R.; Town, R. P. J.; Bradley, D. K.; Dewald, E. L.; Fittinghoff, D.; Jones, O. S.; Robey, H. R.; Moody, J. D.; Khan, S.; Callahan, D. A.; Hamza, A.; Biener, J.; Celliers, P. M.; Braun, D. G.; Erskine, D. J.; Prisbrey, S. T.; Wallace, R. J.; Kozioziemski, B.; Dylla-Spears, R.; Sater, J.; Collins, G.; Storm, E.; Hsing, W.; Landen, O.; Atherton, J. L.; Lindl, J. D.; Edwards, M. J.; Frenje, J. A.; Gatu-Johnson, M.; Li, C. K.; Petrasso, R.; Rinderknecht, H.; Rosenberg, M.; Séguin, F. H.; Zylstra, A.; Knauer, J. P.; Grim, G.; Guler, N.; Merrill, F.; Olson, R.; Kyrala, G. A.; Kilkenny, J. D.; Nikroo, A.; Moreno, K.; Hoover, D. E.; Wild, C.; Werner, E.

    2014-05-01

    High Density Carbon (HDC) is a leading candidate as an ablator material for Inertial Confinement Fusion (ICF) capsules in x-ray (indirect) drive implosions. HDC has a higher density (3.5?g/cc) than plastic (CH, 1?g/cc), which results in a thinner ablator with a larger inner radius for a given capsule scale. This leads to higher x-ray absorption and shorter laser pulses compared to equivalent CH designs. This paper will describe a series of experiments carried out to examine the feasibility of using HDC as an ablator using both gas filled hohlraums and lower density, near vacuum hohlraums. These experiments have shown that deuterium (DD) and deuterium-tritium gas filled HDC capsules driven by a hohlraum filled with 1.2?mg/cc He gas, produce neutron yields a factor of 2× higher than equivalent CH implosions, representing better than 50% Yield-over-Clean (YoC). In a near vacuum hohlraum (He?=?0.03?mg/cc) with 98% laser-to-hohlraum coupling, such a DD gas-filled capsule performed near 1D expectations. A cryogenic layered implosion version was consistent with a fuel velocity?=?410?±?20?km/s with no observed ablator mixing into the hot spot.

  10. High-density carbon ablator experiments on the National Ignition Facility

    SciTech Connect (OSTI)

    MacKinnon, A. J., E-mail: mackinnon2@llnl.gov; Meezan, N. B.; Ross, J. S.; Le Pape, S.; Berzak Hopkins, L.; Divol, L.; Ho, D.; Milovich, J.; Pak, A.; Ralph, J.; Döppner, T.; Patel, P. K.; Thomas, C.; Tommasini, R.; Haan, S.; MacPhee, A. G.; McNaney, J.; Caggiano, J.; Hatarik, R.; Bionta, R. [Lawrence Livermore National Laboratory, P.O. Box 808, Livermore, California 94551-0808 (United States); and others

    2014-05-15

    High Density Carbon (HDC) is a leading candidate as an ablator material for Inertial Confinement Fusion (ICF) capsules in x-ray (indirect) drive implosions. HDC has a higher density (3.5?g/cc) than plastic (CH, 1?g/cc), which results in a thinner ablator with a larger inner radius for a given capsule scale. This leads to higher x-ray absorption and shorter laser pulses compared to equivalent CH designs. This paper will describe a series of experiments carried out to examine the feasibility of using HDC as an ablator using both gas filled hohlraums and lower density, near vacuum hohlraums. These experiments have shown that deuterium (DD) and deuterium-tritium gas filled HDC capsules driven by a hohlraum filled with 1.2?mg/cc He gas, produce neutron yields a factor of 2× higher than equivalent CH implosions, representing better than 50% Yield-over-Clean (YoC). In a near vacuum hohlraum (He?=?0.03?mg/cc) with 98% laser-to-hohlraum coupling, such a DD gas-filled capsule performed near 1D expectations. A cryogenic layered implosion version was consistent with a fuel velocity?=?410?±?20?km/s with no observed ablator mixing into the hot spot.

  11. Enhancing DNA binding rate using optical trapping of high-density gold nanodisks

    SciTech Connect (OSTI)

    Lin, En-Hung; Pan, Ming-Yang [Institute of Photonics Technologies, National Tsing Hua University, Hsinchu, Taiwan 30013 (China) [Institute of Photonics Technologies, National Tsing Hua University, Hsinchu, Taiwan 30013 (China); Research Center for Applied Sciences, Academia Sinica, Taipei, Taiwan 11529 (China); Lee, Ming-Chang [Institute of Photonics Technologies, National Tsing Hua University, Hsinchu, Taiwan 30013 (China)] [Institute of Photonics Technologies, National Tsing Hua University, Hsinchu, Taiwan 30013 (China); Wei, Pei-Kuen, E-mail: pkwei@sinica.edu.tw [Research Center for Applied Sciences, Academia Sinica, Taipei, Taiwan 11529 (China) [Research Center for Applied Sciences, Academia Sinica, Taipei, Taiwan 11529 (China); Institute of Biophotonics, National Yang-Ming University, Taipei 11221, Taiwan (China)

    2014-03-15

    We present the dynamic study of optical trapping of fluorescent molecules using high-density gold nanodisk arrays. The gold nanodisks were fabricated by electron beam lithography with a diameter of 500 nm and a period of 1 ?m. Dark-field illumination showed ?15 times enhancement of fluorescence near edges of nanodisks. Such enhanced near-field generated an optical trapping force of ?10 fN under 3.58 × 10{sup 3} W/m{sup 2} illumination intensity as calculated from the Brownian motions of 590 nm polystyrene beads. Kinetic observation of thiolated DNA modified with Cy5 dye showed different binding rates of DNA under different illumination intensity. The binding rate increased from 2.14 × 10{sup 3} s{sup ?1} (I = 0.7 × 10{sup 3} W/m{sup 2}) to 1.15 × 10{sup 5} s{sup ?1} (I = 3.58 × 10{sup 3} W/m{sup 2}). Both enhanced fluorescence and binding rate indicate that gold nanodisks efficiently improve both detection limit and interaction time for microarrays.

  12. High Density Infrared (HDI) Transient Liquid Coatings for Improved Wear and Corrosion Resistance

    SciTech Connect (OSTI)

    Ronald W. Smith

    2007-07-05

    This report documents a collaborative effort between Oak Ridge National Laboratory (ORNL), Materials Resources International and an industry team of participants to develop, evaluate and understand how high density infrared heating technology could be used to improve infiltrated carbide wear coatings and/or to densify sprayed coatings. The research included HDI fusion evaluations of infiltrated carbide suspensions such (BrazeCoat® S), composite suspensions with tool steel powders, thermally sprayed Ni-Cr- B-Si (self fluxing alloy) and nickel powder layers. The applied work developed practical HDI / transient liquid coating (TLC) procedures on test plates that demonstrated the ability to fuse carbide coatings for industrial applications such as agricultural blades, construction and mining vehicles. Fundamental studies helped create process models that led to improved process understanding and control. The coating of agricultural blades was demonstrated and showed the HDI process to have the ability to fuse industrial scale components. Sliding and brasive wear tests showed that high degree of wear resistance could be achieved with the addition of tool steel powders to carbide particulate composites.

  13. Exact Topological Twistons in Crystalline Polyethylene

    E-Print Network [OSTI]

    E. Ventura; A. M. Simas; D. Bazeia

    2000-04-04

    We investigate the presence of topological twistons in crystalline polyethylene. We describe crystalline polyethylene with a model that couples the torsional and longitudinal degrees of freedom of the polymeric chain by means of a system of two real scalar fields. This model supports topological twistons, which are described by exact and stable topological solutions that appear when the interaction between torsional and longitudinal fields is polynomial, containing up to the sixth power in the fields. We calculate the energy of the topological twiston, and the result is in very good agreement with the value obtained via molecular simulation.

  14. Diamond Lattice Model of Semicrystalline Polyethylene in the Amorphous Region

    E-Print Network [OSTI]

    Diamond Lattice Model of Semicrystalline Polyethylene in the Amorphous Region Zhong­Hui Duan Abstract The statistics of polyethylene chains in the amorphous region between two crystallites have been as models of the chain molecules in the amorphous region of semicrystalline polyethylene, both

  15. Adsorption of Polypropylene and Polyethylene on Liquid Chromatographic

    E-Print Network [OSTI]

    Li, Jing

    Adsorption of Polypropylene and Polyethylene on Liquid Chromatographic Column Packings T. Macko1 tested as column packings for adsorption of isotactic polypropylene and linear polyethylene from dilute solutions. It was found that polyethylene is fully or partially retained from thermodynamically good sol

  16. NANO-SCALE CALORIMETRY OF ISOLATED POLYETHYLENE SINGLE CRYSTALS

    E-Print Network [OSTI]

    Allen, Leslie H.

    #12;NANO-SCALE CALORIMETRY OF ISOLATED POLYETHYLENE SINGLE CRYSTALS BY ALEX TAN KWAN B.S., Stanford) device, the nanocalorimeter, it was possible to investigate the melting of isolated polyethylene (PE, a simple Ni-foil calorimeter, to measure the heat capacity of a thin polyethylene film to verify

  17. Automated Assessment of Polyethylene Wear in Cemented Acetabular Components using

    E-Print Network [OSTI]

    Ulidowski, Irek

    Automated Assessment of Polyethylene Wear in Cemented Acetabular Components using Anteroposterior, Ninewells Hospital, Dundee, DD1 9SY, UK Abstract Polyethylene wear in the acetabular components of hip to the polyethylene acetabular component of a prosthesis so that both it and the metal femoral head component can

  18. High density matter in AGS, SPS and RHIC collisions: Proceedings. Volume 9

    SciTech Connect (OSTI)

    NONE

    1998-12-01

    This 1-day workshop focused on phenomenological models regarding the specific question of the maximum energy density achievable in collisions at AGS, SPS and RHIC. The idea was to have 30-minute (or less) presentations of each model--but not the model as a whole, rather then that strongly narrowed to the above physics question. The key topics addressed were: (1) to estimate the energy density in heavy-ion collisions within a model, and to discuss its physical implications; (2) to suggest experimental observables that may confirm the correctness of a model approach--with respect to the energy density estimate; (3) to compare with existing data from AGS and SPS heavy-ion collisions, and to give predictions for the future RHIC experiments. G. Ogilvie started up the workshop with a critical summary of experimental manifestations of high-density matter at the AGS, and gave a personal outlook on RHIC physics. R. Mattiello talked about his newly developed hadron cascade model for applications to AGS and SPS collisions. Next, D. Kharzeev gave a nice introduction of the Glauber approach to high-energy collisions and illustrated the predictive power of this approach in nucleus-nucleus collisions at the SPS. It followed S. Vance with a presentation of the baryon-junction model to explain the observed baryon stopping phenomenon in collisions of heavy nuclei. S. Bass continued with a broad perspective of the UrQMD model, and provided insight into the details of the microscopic dynamical features of nuclear collisions at high energy. J. Sandweiss and J. Kapusta addressed the interesting aspect of photon production in peripherical nuclear collisions due to intense electromagnetic bremstrahlung by the highly charged, fast moving ions. Finally, H. Sorge closed up the one-day workshop with a presentation of his recent work with the RQMD model. This report consists of a summary and vugraphs of the presentations.

  19. High density array fabrication and readout method for a fiber optic biosensor

    DOE Patents [OSTI]

    Pinkel, Daniel (Walnut Creek, CA); Gray, Joe (San Francisco, CA); Albertson, Donna G. (Lafayette, CA)

    2002-01-01

    The invention relates to the fabrication and use of biosensors comprising a plurality of optical fibers each fiber having attached to its "sensor end" biological "binding partners" (molecules that specifically bind other molecules to form a binding complex such as antibody-antigen, lectin-carbohydrate, nucleic acid-nucleic acid, biotin-avidin, etc.). The biosensor preferably bears two or more different species of biological binding partner. The sensor is fabricated by providing a plurality of groups of optical fibers. Each group is treated as a batch to attach a different species of biological binding partner to the sensor ends of the fibers comprising that bundle. Each fiber, or group of fibers within a bundle, may be uniquely identified so that the fibers, or group of fibers, when later combined in an array of different fibers, can be discretely addressed. Fibers or groups of fibers are then selected and discretely separated from different bundles. The discretely separated fibers are then combined at their sensor ends to produce a high density sensor array of fibers capable of assaying simultaneously the binding of components of a test sample to the various binding partners on the different fibers of the sensor array. The transmission ends of the optical fibers are then discretely addressed to detectors--such as a multiplicity of optical sensors. An optical signal, produced by binding of the binding partner to its substrate to form a binding complex, is conducted through the optical fiber or group of fibers to a detector for each discrete test. By examining the addressed transmission ends of fibers, or groups of fibers, the addressed transmission ends can transmit unique patterns assisting in rapid sample identification by the sensor.

  20. High density array fabrication and readout method for a fiber optic biosensor

    DOE Patents [OSTI]

    Pinkel, Daniel (Walnut Creek, CA); Gray, Joe (San Francisco, CA); Albertson, Donna G. (Lafayette, CA)

    2000-01-01

    The invention relates to the fabrication and use of biosensors comprising a plurality of optical fibers each fiber having attached to its "sensor end" biological "binding partners" (molecules that specifically bind other molecules to form a binding complex such as antibody-antigen, lectin-carbohydrate, nucleic acid-nucleic acid, biotin-avidin, etc.). The biosensor preferably bears two or more different species of biological binding partner. The sensor is fabricated by providing a plurality of groups of optical fibers. Each group is treated as a batch to attach a different species of biological binding partner to the sensor ends of the fibers comprising that bundle. Each fiber, or group of fibers within a bundle, may be uniquely identified so that the fibers, or group of fibers, when later combined in an array of different fibers, can be discretely addressed. Fibers or groups of fibers are then selected and discretely separated from different bundles. The discretely separated fibers are then combined at their sensor ends to produce a high density sensor array of fibers capable of assaying simultaneously the binding of components of a test sample to the various binding partners on the different fibers of the sensor array. The transmission ends of the optical fibers are then discretely addressed to detectors--such as a multiplicity of optical sensors. An optical signal, produced by binding of the binding partner to its substrate to form a binding complex, is conducted through the optical fiber or group of fibers to a detector for each discrete test. By examining the addressed transmission ends of fibers, or groups of fibers, the addressed transmission ends can transmit unique patterns assisting in rapid sample identification by the sensor.

  1. High density array fabrication and readout method for a fiber optic biosensor

    DOE Patents [OSTI]

    Pinkel, Daniel (Walnut Creek, CA); Gray, Joe (San Francisco, CA)

    1997-01-01

    The invention relates to the fabrication and use of biosensors comprising a plurality of optical fibers each fiber having attached to its "sensor end" biological "binding partners" (molecules that specifically bind other molecules to form a binding complex such as antibody-antigen, lectin-carbohydrate, nucleic acid-nucleic acid, biotin-avidin, etc.). The biosensor preferably bears two or more different species of biological binding partner. The sensor is fabricated by providing a plurality of groups of optical fibers. Each group is treated as a batch to attach a different species of biological binding partner to the sensor ends of the fibers comprising that bundle. Each fiber, or group of fibers within a bundle, may be uniquely identified so that the fibers, or group of fibers, when later combined in an array of different fibers, can be discretely addressed. Fibers or groups of fibers are then selected and discretely separated from different bundles. The discretely separated fibers are then combined at their sensor ends to produce a high density sensor array of fibers capable of assaying simultaneously the binding of components of a test sample to the various binding partners on the different fibers of the sensor array. The transmission ends of the optical fibers are then discretely addressed to detectors--such as a multiplicity of optical sensors. An optical signal, produced by binding of the binding partner to its substrate to form a binding complex, is conducted through the optical fiber or group of fibers to a detector for each discrete test. By examining the addressed transmission ends of fibers, or groups of fibers, the addressed transmission ends can transmit unique patterns assisting in rapid sample identification by the sensor.

  2. Microslit Nod-shuffle Spectroscopy - a technique for achieving very high densities of spectra

    E-Print Network [OSTI]

    Karl Glazebrook; Joss Bland-Hawthorn

    2000-11-04

    We describe a new approach to obtaining very high surface densities of optical spectra in astronomical observations with extremely accurate subtraction of night sky emission. The observing technique requires that the telescope is nodded rapidly between targets and adjacent sky positions; object and sky spectra are recorded on adjacent regions of a low-noise CCD through charge shuffling. This permits the use of extremely high densities of small slit apertures (`microslits') since an extended slit is not required for sky interpolation. The overall multi-object advantage of this technique is as large as 2.9x that of conventional multi-slit observing for an instrument configuration which has an underfilled CCD detector and is always >1.5 for high target densities. The `nod-shuffle' technique has been practically implemented at the Anglo-Australian Telescope as the `LDSS++ project' and achieves sky-subtraction accuracies as good as 0.04%, with even better performance possible. This is a factor of ten better than is routinely achieved with long-slits. LDSS++ has been used in various observational modes, which we describe, and for a wide variety of astronomical projects. The nod-shuffle approach should be of great benefit to most spectroscopic (e.g. long-slit, fiber, integral field) methods and would allow much deeper spectroscopy on very large telescopes (10m or greater) than is currently possible. Finally we discuss the prospects of using nod-shuffle to pursue extremely long spectroscopic exposures (many days) and of mimicking nod-shuffle observations with infrared arrays.

  3. High density array fabrication and readout method for a fiber optic biosensor

    DOE Patents [OSTI]

    Pinkel, D.; Gray, J.

    1997-11-25

    The invention relates to the fabrication and use of biosensors comprising a plurality of optical fibers each fiber having attached to its ``sensor end`` biological ``binding partners`` (molecules that specifically bind other molecules to form a binding complex such as antibody-antigen, lectin-carbohydrate, nucleic acid-nucleic acid, biotin-avidin, etc.). The biosensor preferably bears two or more different species of biological binding partner. The sensor is fabricated by providing a plurality of groups of optical fibers. Each group is treated as a batch to attach a different species of biological binding partner to the sensor ends of the fibers comprising that bundle. Each fiber, or group of fibers within a bundle, may be uniquely identified so that the fibers, or group of fibers, when later combined in an array of different fibers, can be discretely addressed. Fibers or groups of fibers are then selected and discretely separated from different bundles. The discretely separated fibers are then combined at their sensor ends to produce a high density sensor array of fibers capable of assaying simultaneously the binding of components of a test sample to the various binding partners on the different fibers of the sensor array. The transmission ends of the optical fibers are then discretely addressed to detectors--such as a multiplicity of optical sensors. An optical signal, produced by binding of the binding partner to its substrate to form a binding complex, is conducted through the optical fiber or group of fibers to a detector for each discrete test. By examining the addressed transmission ends of fibers, or groups of fibers, the addressed transmission ends can transmit unique patterns assisting in rapid sample identification by the sensor. 9 figs.

  4. High-density organic light emitting diodes by nanoimprint technology Krutarth Trivedi, Caleb Nelson, Li Tao, Mathew Goeckner, Walter Hua)

    E-Print Network [OSTI]

    Hu, Wenchuang "Walter"

    High-density organic light emitting diodes by nanoimprint technology Krutarth Trivedi, Caleb Nelson sources. Despite the considerable development of inorganic semiconductor based light emitting diodes of miniaturization to nanoscale. Organic light emitting diode (OLED) technology is immune to quantum confinement

  5. Olivine LiCoPO4 phase grown LiCoO2 cathode material for high density Li batteries

    E-Print Network [OSTI]

    Cho, Jaephil

    Olivine LiCoPO4 phase grown LiCoO2 cathode material for high density Li batteries Hyunjung Lee an increase in the cut-off voltage of the cell from 4.2 V to 4.4 V (vs. graphite). As an alterna- tive, we can

  6. Z .Diamond and Related Materials 10 2001 1947 1951 Synthesis of high-density carbon nanotube films by microwave

    E-Print Network [OSTI]

    Tomįnek, David

    and vertical growth rate of nanotubes. The growth rate on an iron-coated substrate is higher than on a nickel. Nanotubes in the present study are fabricated by MPCVD using iron Z . Z .Fe or nickel Ni as transition metalZ .Diamond and Related Materials 10 2001 1947 1951 Synthesis of high-density carbon nanotube films

  7. Self-Assembly of DNA Double-Double Crossover Complexes into High-Density, Doubly Connected, Planar Structures

    E-Print Network [OSTI]

    Brun, Yuriy

    consisting of two DNA double helices connected by two reciprocal exchanges (crossovers). In 1998, Winfree et connected by a total of six reciprocal exchanges. We use DDX complexes to self-assemble high-density, doubly reciprocal exchanges connecting each pair of adjacent helices. Figure 1b shows how the complexes might tile

  8. Device and method for relativistic electron beam heating of a high-density plasma to drive fast liners

    DOE Patents [OSTI]

    Thode, Lester E. (Los Alamos, NM)

    1981-01-01

    A device and method for relativistic electron beam heating of a high-density plasma in a small localized region. A relativistic electron beam generator or accelerator produces a high-voltage electron beam which propagates along a vacuum drift tube and is modulated to initiate electron bunching within the beam. The beam is then directed through a low-density gas chamber which provides isolation between the vacuum modulator and the relativistic electron beam target. The relativistic beam is then applied to a high-density target plasma which typically comprises DT, DD, hydrogen boron or similar thermonuclear gas at a density of 10.sup.17 to 10.sup.20 electrons per cubic centimeter. The target gas is ionized prior to application of the electron beam by means of a laser or other preionization source to form a plasma. Utilizing a relativistic electron beam with an individual particle energy exceeding 3 MeV, classical scattering by relativistic electrons passing through isolation foils is negligible. As a result, relativistic streaming instabilities are initiated within the high-density target plasma causing the relativistic electron beam to efficiently deposit its energy and momentum into a small localized region of the high-density plasma target. Fast liners disposed in the high-density target plasma are explosively or ablatively driven to implosion by a heated annular plasma surrounding the fast liner which is generated by an annular relativistic electron beam. An azimuthal magnetic field produced by axial current flow in the annular plasma, causes the energy in the heated annular plasma to converge on the fast liner.

  9. Relation Between Type-II ELMs, Edge Localized Turbulence, Washboard Modes and Energy Losses Between ELMs in High Density ELMy H-modes on JET

    E-Print Network [OSTI]

    Relation Between Type-II ELMs, Edge Localized Turbulence, Washboard Modes and Energy Losses Between ELMs in High Density ELMy H-modes on JET

  10. Surface modification of polyethylene by functionalized plasma

    SciTech Connect (OSTI)

    Yuan, S.; Marchant, R.E.

    1993-12-31

    The surface of low density polyethylene(PE) has been modified by functionalized plasma-polymerized N-vinyl-2-pyrrolidone (PPNVP) and allyl alcohol(PPAA) thin films, PPNVP and PPAA(approx. 100 nm). The surface structure and functional groups of modified surfaces were characterized by water contact angle, ATR/FTIR and ESCA techniques. Plasma polymer modified PE surfaces exhibited significant water contact angle hysteresis and a much lower value of advancing water contact angle than that of unmodified polyethylene. Reduction of PPNVP and PPAA modified surfaces by sodium borohydride coverted into hydroxyl groups. The determined concentrations of hydroxyl groups on the reduced PPNVP and PPAA modified surfaces by ESCA after gas-phase derivatization with trifluoroacetic anhydride (TFAA) were about 25% and 30% of total oxygen content, respectively. Finally, the amine containing molecules such as amine-terminated polyethylene oxide (PEO) and 3-aminopropyltriethoxysilane (APTS) were coupled to the hydroxylated surfaces. These novel modified PE surfaces are suitable for immobilization of biomolecules.

  11. Shear-horizontal surface acoustic wave phononic device with high density filling material for ultra-low power sensing applications

    SciTech Connect (OSTI)

    Richardson, M.; Bhethanabotla, V. R.; Sankaranarayanan, S. K. R. S.

    2014-06-23

    Finite element simulations of a phononic shear-horizontal surface acoustic wave (SAW) sensor based on ST 90°-X Quartz reveal a dramatic reduction in power consumption. The phononic sensor is realized by artificially structuring the delay path to form an acoustic meta-material comprised of a periodic microcavity array incorporating high-density materials such as tantalum or tungsten. Constructive interference of the scattered and secondary reflected waves at every microcavity interface leads to acoustic energy confinement in the high-density regions translating into reduced power loss. Tantalum filled cavities show the best performance while tungsten inclusions create a phononic bandgap. Based on our simulation results, SAW devices with tantalum filled microcavities were fabricated and shown to significantly decrease insertion loss. Our findings offer encouraging prospects for designing low power, highly sensitive portable biosensors.

  12. Microstructure, Mechanical Behavior, and Clinical Trade-offs in Ultra-High Molecular Weight Polyethylene for Total Joint Replacement

    E-Print Network [OSTI]

    Atwood, Sara Anne

    2010-01-01

    analysis of hylamer and polyethylene bearings from retrieved1995). Stresses in polyethylene components of contemporaryof cross-linked polyethylene materials for orthopaedic

  13. Probing topological relations between high-density and low-density regions of 2MASS with hexagon cells

    SciTech Connect (OSTI)

    Wu, Yongfeng; Xiao, Weike

    2014-02-01

    We introduced a new two-dimensional (2D) hexagon technique for probing the topological structure of the universe in which we mapped regions of the sky with high and low galaxy densities onto a 2D lattice of hexagonal unit cells. We defined filled cells as corresponding to high-density regions and empty cells as corresponding to low-density regions. The numbers of filled cells and empty cells were kept the same by controlling the size of the cells. By analyzing the six sides of each hexagon, we could obtain and compare the statistical topological properties of high-density and low-density regions of the universe in order to have a better understanding of the evolution of the universe. We applied this hexagonal method to Two Micron All Sky Survey data and discovered significant topological differences between the high-density and low-density regions. Both regions had significant (>5?) topological shifts from both the binomial distribution and the random distribution.

  14. Microstructural characterization of in situ MXCT images of high density foams under large strains

    SciTech Connect (OSTI)

    Patterson, Brian M; Gleiman, Seth; Marks, Trevor G; Milstein, Fredrick

    2009-01-01

    Foams are used in numerous applications, such as vibration damping and energy mitigation (e.g., packaging and helmets), wherein their mechanical properties are of critical importance. A typical compressive response of a high density elastomeric foam, shown in Fig 1, generally contains three regions of interest: (I) a linear-elastic region, governed by strut bending; (II) a relatively flat, or slowly increasing stress-strain response, accompanied by strut buckling and the localized collapse of pores; and (III) an exponentially increasing stress-strain curve wherein the collapse of the pore matrix leads to densification. Two material properties of interest, upon which considerable research has focused are the foam's Young's modulus, E{sub f}, defined as the slope of the stress-strain response in region I, and the collapse stress, {sigma}{sub f}, defined as the stress at which the response begins to deviate from linearity. It has been observed [1, 2, 3] that Young's modulus and the collapse stress are dependent on the material properties of the strut material and the non-dimensional relative-density of the foam, {rho}* = {rho}{sub f}/{rho}{sub m}, where {rho}{sub r} is the gross density of the foam and {rho}{sub m} is the density of the strut, or matrix, material. For foam of low relative-density, i.e, {rho}* < 0.1, the collapse stress and Young's modulus obey the relations {sigma}{sub c}/E{sub m} {proportional_to} ({rho}*){sup m} and E{sub f}/E{sub m} {proportional_to} ({rho}*){sup n} where E{sub m} is Young's modulus of the strut material and the bounds on the parameters m and n are 0.05 {le} m {le} 0.2 and 1 {le} n {le} 4 [4]. For open-celled foams, n = 2, whereas for closed-celled foams, n = 3. Theoretically, n = 1 for foams with an ''ideal strut'' configuration [6]. Foams of high relative-density ({rho}* > 0.1) require correcting terms to account for the axial contributions of the ''thick'' struts [5]. The above equations relate important foam properties to the relative-density of the foam; however, there exists a gap in the understanding of how the foam microstructure affects the mechanical response of the foam. This is due in large part to the difficulty of characterizing foam structures in 3D, especially foams of high relative-density. Most elastomeric foams are manufactured by the introduction of a gas into a cross-linking polymer. The developing foam microstructure has a complex dependence on the polymer viscosity and rate of polymerization, resulting in a randomly arranged pore structure with a large distribution of pore sizes. One approach is to characterize foam microstructures solely in terms of the cross-sectional shape and vector arrangement of the strut matrix, since it is this matrix that supports the stresses upon loading of the foam; yet as the density of a foam is increased, the very definition of what constitutes a strut brakes down. Another, perhaps easier to visualize, characterization of foam microstructure can come from a description of the pore shape and arrangement. Given the random nature of the microstructures of blown foam, both approaches are useful and valid. This paper describes our work aimed at linking the mechanical response and microstructural evolution of high relative-density foam as it undergoes large deformation. This work consists of several inter-related parts, including (i) measuring the compressive stress-strain response, as illustrated in Fig. 1, (ii) obtaining in situ micro X-ray computed tomography (MXCT) images of high relative-density foams undergoing large strains, and (iii) developing mathematical, computer aided, methodologies to perform image analysis and calculations of parameters that characterize the pores and struts. By using MXCT, a non-invasive technique for imaging the internal structure of materials, we are able to observe, internally, individual struts and pores as they undergo large deformation. Here we describe our computer aided image analysis methodologies and present examples of their application to the MXCT images of foams. Operations of the compute

  15. Crystallization of polyethylene by modified weighted density approximation(MWDA)

    E-Print Network [OSTI]

    Razeghizadeh, Alireza; Lavafpour, Farhad

    2015-01-01

    In this article, we use the modified weighted density approximation to study the crystallization of polyethylene. We also use a direct correlation function of polyethylene based on RISM theory. The free energy of a polyethylene is calculated using density functional theory. The crystallization and solid and liquid density are calculated and finally compared with the prism simulation and experimental results. That shown the result obtained by MWDA is in better agreement, compared with the experimental result than the prism.

  16. Crystallization of polyethylene by modified weighted density approximation(MWDA)

    E-Print Network [OSTI]

    Alireza Razeghizadeh; Vahdat Rafee; Farhad Lavafpour

    2015-02-07

    In this article, we use the modified weighted density approximation to study the crystallization of polyethylene. We also use a direct correlation function of polyethylene based on RISM theory. The free energy of a polyethylene is calculated using density functional theory. The crystallization and solid and liquid density are calculated and finally compared with the prism simulation and experimental results. That shown the result obtained by MWDA is in better agreement, compared with the experimental result than the prism.

  17. Metalized Polyethylene Mulch to Reduce Incidence of Huanglongbing and Improve Growth of New Citrus Plantings

    E-Print Network [OSTI]

    Croxton, S.; Stansly, P.

    2014-01-01

    7.14 P Metalized Polyethylene Mulch to Reduce Incidence ofNorth, Immokalee, FL, USA Polyethylene mulch was evaluatedUV reflective low density polyethylene mulch metalized with

  18. Leaching of antimony from polyethylene terephthalate (PET) bottles into mineral water

    E-Print Network [OSTI]

    Short, Daniel

    Leaching of antimony from polyethylene terephthalate (PET) bottles into mineral water Szilvia April 2009 Available online 21 May 2009 Keywords: Antimony Water Leaching Polyethylene terephthalate SODIS The Sb leaching from polyethylene terephthalate (PET) package material into 10 different brands

  19. Constraining the High-Density Behavior of Nuclear Symmetry Energy with the Tidal Polarizability of Neutron Stars

    E-Print Network [OSTI]

    F. J. Fattoyev; J. Carvajal; W. G. Newton; Bao-An Li

    2012-10-12

    Using a set of model equations of state satisfying the latest constraints from both terrestrial nuclear experiments and astrophysical observations as well as state-of-the-art nuclear many-body calculations of the pure neutron matter equation of state, the tidal polarizability of canonical neutron stars in coalescing binaries is found to be a very sensitive probe of the high-density behavior of nuclear symmetry energy which is among the most uncertain properties of dense neutron-rich nucleonic matter. Moreover, it changes less than $\\pm 10%$ by varying various properties of symmetric nuclear matter and symmetry energy around the saturation density within their respective ranges of remaining uncertainty.

  20. Constraining the High-Density Behavior of Nuclear Symmetry Energy with the Tidal Polarizability of Neutron Stars

    E-Print Network [OSTI]

    Fattoyev, F J; Newton, W G; Li, Bao-An

    2012-01-01

    Using a set of model equations of state satisfying the latest constraints from both terrestrial nuclear experiments and astrophysical observations as well as state-of-the-art nuclear many-body calculations of the pure neutron matter equation of state, the tidal polarizability of canonical neutron stars in coalescing binaries is found to be a very sensitive probe of the high-density behavior of nuclear symmetry energy which is among the most uncertain properties of dense neutron-rich nucleonic matter. Moreover, it changes less than $\\pm 10%$ by varying various properties of symmetric nuclear matter and symmetry energy around the saturation density within their respective ranges of remaining uncertainty.

  1. Microrheology of polyethylene oxide using diffusing wave spectroscopy and single scattering Bivash R. Dasgupta,1

    E-Print Network [OSTI]

    Microrheology of polyethylene oxide using diffusing wave spectroscopy and single scattering Bivash on polyethylene oxide solutions in the semidilute regime using polystyrene beads of varying sizes and surface

  2. Extensional rheology of shear-thickening fumed silica nanoparticles dispersed in an aqueous polyethylene

    E-Print Network [OSTI]

    Rothstein, Jonathan

    polyethylene oxide solution Sunilkumar Khandavalli and Jonathan P. Rothsteina) Mechanical and Industrial rheology of fumed silica nanoparticles dispersed in an aqueous polyethylene oxide (PEO) solution

  3. Eccentricity Error Correction for Automated Estimation of Polyethylene Wear after Total Hip Arthroplasty

    E-Print Network [OSTI]

    Ulidowski, Irek

    Eccentricity Error Correction for Automated Estimation of Polyethylene Wear after Total Hip. Wire markers are typically attached to the polyethylene acetabular component of the prosthesis so

  4. Single chain elasticity and thermoelasticity of polyethylene

    E-Print Network [OSTI]

    John T. Titantah; Carlo Pierleoni; Jean-Paul Ryckaert

    2002-09-05

    Single-chain elasticity of polyethylene at $\\theta$ point up to 90% of stretching with respect to its contour length is computed by Monte-Carlo simulation of an atomistic model in continuous space. The elasticity law together with the free-energy and the internal energy variations with stretching are found to be very well represented by the wormlike chain model up to 65% of the chain elongation, provided the persistence length is treated as a temperature dependent parameter. Beyond this value of elongation simple ideal chain models are not able to describe the Monte Carlo data in a thermodynamic consistent way. This study reinforces the use of the wormlike chain model to interpret experimental data on the elasticity of synthetic polymers in the finite extensibility regime, provided the chain is not yet in its fully stretched regime. Specific solvent effects on the elasticity law and the partition between energetic and entropic contributions to single chain elasticity are investigated.

  5. Annealing of single lamella nanoparticles of polyethylene

    E-Print Network [OSTI]

    Christophe N. Rochette; Sabine Rosenfeldt; Katja Henzler; Frank Polzer; Matthias Ballauff; Qiong Tong; Stefan Mecking; Markus Drechsler; Theyencheri Narayanan; Ludger Harnau

    2011-07-05

    We study the change of the size and structure of freely suspended single lamella nanoparticles of polyethylene during thermal annealing in aqueous solutions. Using small-angle x-ray scattering and cryogenic transmission electron microscopy, it is shown that a doubling of the crystalline lamella sandwiched between two amorphous polymer layers is obtained by annealing the nanoparticles at 125 C. This thickening of the crystalline lamella can be understood in terms of an unlooping of polymer chains within a single nanoparticle. In addition a variation of the annealing temperature from 90 C to 115 C demonstrates that the inverse of the crystalline lamellar thickness increases linearly with the annealing temperatures leading to a recrystallization line in a Gibbs-Thomson graph. Since the nanoparticles consist of about only eight polymer chains, they can be considered as a ideal candidates for the experimental realization of equilibrium polymer crystals.

  6. Collective renovation : case study on the public / private relationship in high-density low-rise residential areas of central Tokyo

    E-Print Network [OSTI]

    Mizuguchi, Saki

    2012-01-01

    This thesis starts with the interest in the undefined open spaces of high-density low-rise (HDLR) residential areas in Tokyo. In these spaces, one can witness numerous examples of overlapping public and private uses. For ...

  7. Tissue specific regulation of the high density lipoprotein (HDL) receptor, scavenger receptor Class B, Type I (SR-BI) by the scaffold protein PDZK1

    E-Print Network [OSTI]

    Fenske, Sara Anne

    2008-01-01

    PDZK1 is a four PDZ-domain containing cytoplasmic adaptor protein that binds the Cterminus of the high-density lipoprotein (HDL) receptor SR-BI. Abolishing PDZK1 expression in PDZK1 knockout (KO) mice leads to a ...

  8. Observation of a new high-? and high-density state of a magnetospheric plasma in RT-1

    SciTech Connect (OSTI)

    Saitoh, H.; Yano, Y.; Yoshida, Z.; Nishiura, M.; Morikawa, J.; Kawazura, Y.; Nogami, T.; Yamasaki, M. [Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8561 (Japan)

    2014-08-15

    A new high-? and high-density state is reported for a plasma confined in a laboratory magnetosphere. In order to expand the parameter regime of an electron cyclotron resonance heating experiment, the 8.2?GHz microwave power of the Ring Trap 1 device has been upgraded with the installation of a new waveguide system. The rated input power launched from a klystron was increased from 25 to 50?kW, which enabled the more stable formation of a hot-electron high-? plasma. The diamagnetic signal (the averaged value of four magnetic loops signals) of a plasma reached 5.2 mWb. According to a two-dimensional Grad-Shafranov analysis, the corresponding local ? value is close to 100%.

  9. Access to a New Plasma Edge State with High Density and Pressures using Quiescent H-mode

    SciTech Connect (OSTI)

    Solomon, Wayne M.; Snyder, P. B.; Burrell, K. H.; Fenstermacher, M. E.; Garofalo, A. M.; Grierson, B. A.; Loarte, A.; McKee, G. R.; Nazikian, R; Osborne, T. H.

    2014-07-01

    A path to a new high performance regime has been discovered in tokamaks that could improve the attractiveness of a fusion reactor. Experiments on DIII-D using a quiescent H-mode edge have navigated a valley of improved edge peeling-ballooning stability that opens up with strong plasma shaping at high density, leading to a doubling of the edge pressure over standard edge localized mode (ELM)ing H-mode at these parameters. The thermal energy confinement time increases both as a result of the increased pedestal height and improvements in the core transport and reduced low-k turbulence. Calculations of the pedestal height and width as a function of density using constraints imposed by peeling-ballooning and kinetic-ballooning theory are in quantitative agreement with the measurements.

  10. Silica Supported Single-Walled Carbon Nanotubes as a Modifier in Polyethylene Composites

    E-Print Network [OSTI]

    Resasco, Daniel

    Silica Supported Single-Walled Carbon Nanotubes as a Modifier in Polyethylene Composites Neal D. Mc.interscience.wiley.com). ABSTRACT: Composites have been made from single- wall carbon nanotubes in a polyethylene (PE) matrix: additives; composites; conducting polymers; nanocomposites; polyethylene INTRODUCTION Polyethylene (PE

  11. High-Molecular-Weight Polyethylene Glycol Prevents Lethal Sepsis Due to Intestinal Pseudomonas aeruginosa

    E-Print Network [OSTI]

    Lee, Ka Yee C.

    High-Molecular-Weight Polyethylene Glycol Prevents Lethal Sepsis Due to Intestinal Pseudomonas of this study were to test the ability of a high-molecular- weight polyethylene glycol compound, polyethylene: The ability of polyethylene glycol 15­20 to protect the intestinal epi- thelium against the opportunistic

  12. Quantification of branching in model 3-arm star polyethylene Ramnath Ramachandran, Gregory Beaucage*

    E-Print Network [OSTI]

    Beaucage, Gregory

    1 Quantification of branching in model 3-arm star polyethylene Ramnath Ramachandran, Gregory-arm star polyethylene molecules is presented. Many commercial polyethylenes have long side branches-density polyethylene (LDPE) is typically a highly branched structure with broad distributions in branch content, branch

  13. An exposure assessment survey of the Mont Belvieu polyethylene plant 

    E-Print Network [OSTI]

    Tucker, Thomas Franklin

    1997-01-01

    Evaluation of ever changing, complex workplaces can be accomplished with a sound, logical exposure assessment survey (EAS). An EAS was conducted at a polyethylene plant located in southeast Texas to determine the risk of adverse health effects...

  14. Exciton self-trapping in bulk polyethylene

    E-Print Network [OSTI]

    D. Ceresoli; M. C. Righi; E. Tosatti; S. Scandolo; G. Santoro; S. Serra

    2005-07-13

    We studied theoretically the behavior of an injected electron-hole pair in crystalline polyethylene. Time-dependent adiabatic evolution by ab-initio molecular dynamics simulations show that the pair will become self-trapped in the perfect crystal, with a trapping energy of about 0.38 eV, with formation of a pair of trans-gauche conformational defects, three C$_2$H$_4$ units apart on the same chain. The electron is confined in the inter-chain pocket created by a local, 120$^\\circ$ rotation of the chain between the two defects, while the hole resides on the chain and is much less bound. Despite the large energy stored in the trapped excitation, there does not appear to be a direct non-radiative channel for electron-hole recombination. This suggests that intrinsic self-trapping of electron-hole pairs inside the ideal quasi-crystalline fraction of PE might not be directly relevant for electrical damage in high-voltage cables.

  15. Time-resolved compression of a capsule with a cone to high density for fast-ignition laser fusion

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Theobald, W.; Solodov, A. A.; Stoeckl, C.; Anderson, K. S.; Beg, F. N.; Epstein, R.; Fiksel, G.; Giraldez, E. M.; Glebov, V. Yu.; Habara, H.; et al

    2014-12-12

    The advent of high-intensity lasers enables us to recreate and study the behaviour of matter under the extreme densities and pressures that exist in many astrophysical objects. It may also enable us to develop a power source based on laser-driven nuclear fusion. Achieving such conditions usually requires a target that is highly uniform and spherically symmetric. Here we show that it is possible to generate high densities in a so-called fast-ignition target that consists of a thin shell whose spherical symmetry is interrupted by the inclusion of a metal cone. Using picosecond-time-resolved X-ray radiography, we show that we can achievemore »areal densities in excess of 300 mg cm#2;-2 with a nanosecond-duration compression pulse -- the highest areal density ever reported for a cone-in-shell target. Such densities are high enough to stop MeV electrons, which is necessary for igniting the fuel with a subsequent picosecond pulse focused into the resulting plasma.« less

  16. Extension of the Nambu-Jona-Lasinio model predictions at high densities and temperatures using an implicit regularization scheme

    SciTech Connect (OSTI)

    Farias, R. L. S. [Departamento de Fisica Teorica, Universidade do Estado do Rio de Janeiro, Rio de Janeiro, RJ 20559-900 (Brazil); Dallabona, G. [Departamento de Ciencias Exatas, Universidade Federal de Lavras, Cx. Postal 37, 37200-000, Lavras, MG (Brazil); Krein, G. [Instituto de Fisica Teorica, Universidade Estadual Paulista, Rua Pamplona 145, Sao Paulo, SP 01405-900 (Brazil); Battistel, O. A. [CBPF, Centro Brasileiro de Pesquisas Fisicas Rua Xavier Sigaud 150, 22290-180 Urca Rio de Janeiro, RJ (Brazil)

    2008-06-15

    Traditional cutoff regularization schemes of the Nambu-Jona-Lasinio model limit the applicability of the model to energy-momentum scales much below the value of the regularizing cutoff. In particular, the model cannot be used to study quark matter with Fermi momenta larger than the cutoff. In the present work, an extension of the model to high temperatures and densities recently proposed by Casalbuoni, Gatto, Nardulli, and Ruggieri is used in connection with an implicit regularization scheme. This is done by making use of scaling relations of the divergent one-loop integrals that relate these integrals at different energy-momentum scales. Fixing the pion decay constant at the chiral symmetry breaking scale in the vacuum, the scaling relations predict a running coupling constant that decreases as the regularization scale increases, implementing in a schematic way the property of asymptotic freedom of quantum chromodynamics. If the regularization scale is allowed to increase with density and temperature, the coupling will decrease with density and temperature, extending in this way the applicability of the model to high densities and temperatures. These results are obtained without specifying an explicit regularization. As an illustration of the formalism, numerical results are obtained for the finite density and finite temperature quark condensate and applied to the problem of color superconductivity at high quark densities and finite temperature.

  17. Simulating x-ray Thomson scattering signals from high-density, millimetre-scale plasmas at the National Ignition Facility

    SciTech Connect (OSTI)

    Chapman, D. A., E-mail: david.chapman@awe.co.uk [Plasma Physics Group, Radiation Physics Department, AWE plc, Reading RG7 4PR (United Kingdom); Centre for Fusion, Space and Astrophysics, University of Warwick, Coventry CV4 7AL (United Kingdom); Kraus, D.; Falcone, R. W. [Department of Physics, University of California, Berkeley, California 94720 (United States); Kritcher, A. L.; Bachmann, B.; Collins, G. W.; Gaffney, J. A.; Hawreliak, J. A.; Landen, O. L.; Le Pape, S.; Ma, T.; Nilsen, J.; Pak, A.; Swift, D. C.; Döppner, T. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Gericke, D. O. [Centre for Fusion, Space and Astrophysics, University of Warwick, Coventry CV4 7AL (United Kingdom); Glenzer, S. H. [SLAC National Accelerator Laboratory, Menlo Park, California 94309 (United States); Guymer, T. M. [Plasma Physics Group, Radiation Physics Department, AWE plc, Reading RG7 4PR (United Kingdom); Neumayer, P. [Gesellschaft für Schwerionenforschung, 64291 Darmstadt (Germany); Redmer, R. [Institut für Physik, Universität Rostock, 18051 Rostock (Germany); and others

    2014-08-15

    We have developed a model for analysing x-ray Thomson scattering data from high-density, millimetre-scale inhomogeneous plasmas created during ultra-high pressure implosions at the National Ignition Facility in a spherically convergent geometry. The density weighting of the scattered signal and attenuation of the incident and scattered x-rays throughout the target are included using radial profiles of the density, opacity, ionization state, and temperature provided by radiation-hydrodynamics simulations. These simulations show that the scattered signal is strongly weighted toward the bulk of the shocked plasma and the Fermi degenerate material near the ablation front. We show that the scattered signal provides a good representation of the temperature of this highly nonuniform bulk plasma and can be determined to an accuracy of ca. 15% using typical data analysis techniques with simple 0D calculations. On the other hand, the mean ionization of the carbon in the bulk is underestimated. We suggest that this discrepancy is due to the convolution of scattering profiles from different regions of the target. Subsequently, we discuss modifications to the current platform to minimise the impact of inhomogeneities, as well as opacity, and also to enable probing of conditions more strongly weighted toward the compressed core.

  18. Time-resolved compression of a capsule with a cone to high density for fast-ignition laser fusion

    SciTech Connect (OSTI)

    Theobald, W.; Solodov, A. A.; Stoeckl, C.; Anderson, K. S.; Beg, F. N.; Epstein, R.; Fiksel, G.; Giraldez, E. M.; Glebov, V. Yu.; Habara, H.; Ivancic, S.; Jarrott, L. C.; Marshall, F. J.; McKiernan, G.; McLean, H. S.; Mileham, C.; Nilson, P. M.; Patel, P. K.; Pérez, F.; Sangster, T. C.; Santos, J. J.; Sawada, H.; Shvydky, A.; Stephens, R. B.; Wei, M. S.

    2014-12-12

    The advent of high-intensity lasers enables us to recreate and study the behaviour of matter under the extreme densities and pressures that exist in many astrophysical objects. It may also enable us to develop a power source based on laser-driven nuclear fusion. Achieving such conditions usually requires a target that is highly uniform and spherically symmetric. Here we show that it is possible to generate high densities in a so-called fast-ignition target that consists of a thin shell whose spherical symmetry is interrupted by the inclusion of a metal cone. Using picosecond-time-resolved X-ray radiography, we show that we can achieve areal densities in excess of 300 mg cm#2;-2 with a nanosecond-duration compression pulse -- the highest areal density ever reported for a cone-in-shell target. Such densities are high enough to stop MeV electrons, which is necessary for igniting the fuel with a subsequent picosecond pulse focused into the resulting plasma.

  19. Friction and Wear Behavior of Ultrahigh Molecular Weight Polyethylene as a Function of Crystallinity in the Presence of the

    E-Print Network [OSTI]

    Lin, Zhiqun

    Friction and Wear Behavior of Ultrahigh Molecular Weight Polyethylene as a Function: In this study, the friction and wear behavior of ultrahigh molecular weight polyethylene (UHMWPE) were evaluated Words: ultrahigh molecular weight polyethylene (UHMWPE), crystallinity, friction, wear, phospholipid

  20. Lanai high-density irradiance sensor network for characterizing solar resource variability of MW-scale PV system.

    SciTech Connect (OSTI)

    Stein, Joshua S.; Johnson, Lars; Ellis, Abraham; Kuszmaul, Scott S.

    2012-01-01

    Sandia National Laboratories (Sandia) and SunPower Corporation (SunPower) have completed design and deployment of an autonomous irradiance monitoring system based on wireless mesh communications and a battery operated data acquisition system. The Lanai High-Density Irradiance Sensor Network is comprised of 24 LI-COR{reg_sign} irradiance sensors (silicon pyranometers) polled by 19 RF Radios. The system was implemented with commercially available hardware and custom developed LabVIEW applications. The network of solar irradiance sensors was installed in January 2010 around the periphery and within the 1.2 MW ac La Ola PV plant on the island of Lanai, Hawaii. Data acquired at 1 second intervals is transmitted over wireless links to be time-stamped and recorded on SunPower data servers at the site for later analysis. The intent is to study power and solar resource data sets to correlate the movement of cloud shadows across the PV array and its effect on power output of the PV plant. The irradiance data sets recorded will be used to study the shape, size and velocity of cloud shadows. This data, along with time-correlated PV array output data, will support the development and validation of a PV performance model that can predict the short-term output characteristics (ramp rates) of PV systems of different sizes and designs. This analysis could also be used by the La Ola system operator to predict power ramp events and support the function of the future battery system. This experience could be used to validate short-term output forecasting methodologies.

  1. LA-UR-02-6305 1 10/4/2002 Overview of High-density FRC Research on FRX-L

    E-Print Network [OSTI]

    is compressed to fusion conditions. Our target plasma is an FRC because it has the required closedLA-UR-02-6305 1 10/4/2002 Overview of High-density FRC Research on FRX-L at Los Alamos National, Albuquerque, NM USA Abstract We present an overview of the FRC research on the Field Reversed configuration e

  2. High Density Packaging in 2010 and Beyond Rao R. Tunmala*, Venky Sundaram, Fuhan Liu, George White, Swapan Bhattacharya, Raj M. Pulugurtha, Madhavan

    E-Print Network [OSTI]

    Swaminathan, Madhavan

    High Density Packaging in 2010 and Beyond Rao R. Tunmala*, Venky Sundaram, Fuhan Liu, George White, Swapan Bhattacharya, Raj M. Pulugurtha, Madhavan Packaging Research Center, Georgia Institute and the package increases tremendously. With the shift towards nano ICs by 2003 with 100nm features, pitch of area

  3. Towards a detailed understanding of the NEXAFS spectra of bulk polyethylene copolymers and related alkanes

    E-Print Network [OSTI]

    Towards a detailed understanding of the NEXAFS spectra of bulk polyethylene copolymers and related interpretation has not yet emerged. Initially, the low energy peak of polyethylene (PE) and long- chain alkanes

  4. Synthesis and elaboration of polyethylene surfaces modified via anionic grafting chemistry 

    E-Print Network [OSTI]

    Bandella, Ashok Krishangopal

    1996-01-01

    such as contact angle goniometry, X-ray photoelectron spectroscopy, and ATR-IR spectroscopy showed that grafting took place mainly on the surface of polyethylene film. Detailed spectroscopic studies of the ungrafted and grafted polyethylene surfaces containing...

  5. Photoelectrochemical investigation of a poly(ethylene oxide) cell

    SciTech Connect (OSTI)

    Sammells, A.F.; Ang, G.P.

    1984-03-01

    The photoelectrochemical properties of cells based on the solid polymer electrolyte (SPE) poly(ethylene oxide)/NaSCN with Na2S/S as a redox species are investigated experimentally. The preparation of the SPE is described in detail. Current/voltage curves or voltage/time are shown for cells using p-InP/SPE/conducting-glass, n-GaAs/SPE/conducting-glass, and p-InP/SPE/n-CdS structures. It is concluded that practical cells based on SPE of this type will require increases in the ionic conductivity of poly(ethylene oxide). 13 references.

  6. Polyethylene composites containing a phase change material having a C14 straight chain hydrocarbon

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH)

    1987-01-01

    A composite useful in thermal energy storage, said composite being formed of a polyethylene matrix having a straight chain alkyl hydrocarbon incorporated therein, said polyethylene being crosslinked to such a degree that said polyethylene matrix is form stable and said polyethylene matrix is capable of absorbing at least 10% by weight of said straight chain alkyl hydrocarbon; the composite is useful in forming pellets or sheets having thermal energy storage characteristics.

  7. PHYSICAL REVIEW B 85, 094109 (2012) Electron dynamics of shocked polyethylene crystal

    E-Print Network [OSTI]

    Goddard III, William A.

    2012-01-01

    PHYSICAL REVIEW B 85, 094109 (2012) Electron dynamics of shocked polyethylene crystal Patrick L-dynamics simulations of the single shock Hugoniot are reported for a crystalline polyethylene (PE) model. The e. INTRODUCTION The material response of polyethylene (PE) to shock and its behavior in the warm dense matter (WDM

  8. Rheology of Low-Density Polyethylene Boehmite Piotr Blaszczak,1,2

    E-Print Network [OSTI]

    North Texas, University of

    Rheology of Low-Density Polyethylene ž Boehmite Composites Piotr Blaszczak,1,2 Witold Brostow,1), University of North Texas, Denton 76203-5017, Texas Polyethylene is already one of the most commonly used polymers due to its solvent resistance and easy processing. Low-density polyethylene (LDPE) also has

  9. Metalized Polyethylene Mulch to Reduce Incidence of Huanglongbing and Improve Growth of New Citrus Plantings

    E-Print Network [OSTI]

    Ma, Lena

    7.14 P Metalized Polyethylene Mulch to Reduce Incidence of Huanglongbing and Improve Growth of New and Education Center Polyethylene mulch was evaluated for deterring colonization by Asian citrus psyllid (ACP growth of young citrus. UV reflective low density polyethylene mulch metalized with aluminum, low density

  10. Reduced adhesion of human blood platelets to polyethylene tubing by microplasma surface modification

    E-Print Network [OSTI]

    von Andrian, Ulrich H.

    Reduced adhesion of human blood platelets to polyethylene tubing by microplasma surface of small-diameter polyethylene (PE) tubing. A microwave cavity diagnostic was used to measure the density tubing and the emitted light intensity was found. A poly(ethylene oxide) surfactant was immobilized

  11. Effect of polyethylene glycol on the liquidliquid phase transition in aqueous protein solutions

    E-Print Network [OSTI]

    Benedek, George B.

    Effect of polyethylene glycol on the liquid­liquid phase transition in aqueous protein solutions, 2002 We have studied the effect of polyethylene glycol (PEG) on the liquid­liquid phase separation. PEG ternary mixtures solubility partitioning Polyethylene glycol (PEG) is a hydrophilic nonionic

  12. Thermal rectification at silicon-amorphous polyethylene interface Ming Hu,1,a

    E-Print Network [OSTI]

    Li, Baowen

    Thermal rectification at silicon-amorphous polyethylene interface Ming Hu,1,a Pawel Keblinski,1,b heat currents. We estimate that in the limit of large heat currents, the silicon-amorphous polyethylene by amorphous polymer polyethylene PE and silicon crystal. We will also show that the mecha- nism governing

  13. Substrate Effect on the Melting Temperature of Thin Polyethylene Films M. Rafailovich,1,* J. Sokolov,1

    E-Print Network [OSTI]

    Substrate Effect on the Melting Temperature of Thin Polyethylene Films Y. Wang,1 M. Rafailovich,1 polyethylene thin films. The Tm decreases with the film thickness decrease when the film is thinner than that the degree of crystal- linity of polyethylene (PE) remained high even in films as thin as 15 nm [5]. A novel

  14. Comparison of low-energy radiation effects in polyethylene and cellulose Jussi Polvi, Kai Nordlund

    E-Print Network [OSTI]

    Nordlund, Kai

    Comparison of low-energy radiation effects in polyethylene and cellulose Jussi Polvi, Kai Nordlund, for a carbon atom in polyethylene chain, and for one of the carbon atoms in cellulose chain. Our analysis shows and on average slightly higher for the carbon atoms in the polyethylene chain than for the target carbon atom

  15. Leaf Area Distribution of Tomato Plants as Influenced by Polyethylene Mulch

    E-Print Network [OSTI]

    Decoteau, Dennis R.

    Leaf Area Distribution of Tomato Plants as Influenced by Polyethylene Mulch Surface Color Dennis R of polyethylene (plastic) mulch surface color (white versus black) on leaf area distribution of tomato and soil temperatures. These results suggest that the polyethylene mulch surface color can induce changes

  16. Defect controlled transverse compressive strength of polyethylene fiber M.R. O'Masta a,

    E-Print Network [OSTI]

    Wadley, Haydn

    Defect controlled transverse compressive strength of polyethylene fiber laminates M.R. O'Masta a: Laminate defects Voids Compressive strength Polyethylene composites a b s t r a c t Using a combination weight polyethylene (UHMWPE) fibers and thermoplastic resins, and investi- gated their effects upon

  17. Primary Radiation Defect Production in Polyethylene and Cellulose Jussi Polvi,* Petri Luukkonen, and Kai Nordlund

    E-Print Network [OSTI]

    Nordlund, Kai

    Primary Radiation Defect Production in Polyethylene and Cellulose Jussi Polvi,* Petri Luukkonen in polyethylene and cellulose were examined using molecular dynamics simulations. The governing reactions in both. Crystalline cellulose was found to be more resistant to radiation damage than crystalline polyethylene

  18. A study of the polyethylene membrane used in diffusion chambers for radon gas concentration measurements

    E-Print Network [OSTI]

    Yu, Peter K.N.

    A study of the polyethylene membrane used in diffusion chambers for radon gas concentration. Thoron can also be deterred from entering the diffusion chamber by using a polyethylene (PE) membrane rights reserved. PACS: 29.40; 23.60 Keywords: Diffusion chamber; Polyethylene membrane; Radon and thoron

  19. Hypothetical Thermodynamic Properties: The Boiling and Critical Temperatures of Polyethylene and Polytetrafluoroethylene

    E-Print Network [OSTI]

    Chickos, James S.

    Hypothetical Thermodynamic Properties: The Boiling and Critical Temperatures of Polyethylene value asymptotically approaches TB() ) (1217 ( 246) K for series related to polyethylene by the melting temperature of polyethylene.4,5 In this article, the question of whether the normal boiling tem

  20. MEASUREMENT OF HEAT TRANSFER DURING DROP-WISE CONDENSATION OF WATER ON POLYETHYLENE

    E-Print Network [OSTI]

    Khandekar, Sameer

    MEASUREMENT OF HEAT TRANSFER DURING DROP-WISE CONDENSATION OF WATER ON POLYETHYLENE Gagan Deep distribution of temperature during drop-wise condensation over a polyethylene substrate was measured using on the substrate was simultaneously visualized. Static contact angles of water on polyethylene are measured

  1. Density functional study of molecular crystals: Polyethylene and a crystalline analog of bisphenol-A polycarbonate

    E-Print Network [OSTI]

    Density functional study of molecular crystals: Polyethylene and a crystalline analog of bisphenol polyethylene comprising covalently bonded parallel chains with weak interchain interactions, and b reaction barriers.8 In a recent study of the interchain interactions in crystalline polyethylene PE ,9 we

  2. Thermal resistance and phonon scattering at the interface between carbon nanotube and amorphous polyethylene

    E-Print Network [OSTI]

    Elliott, James

    polyethylene Sho Hida a , Takuma Hori a , Takuma Shiga a , James Elliott b , Junichiro Shiomi a,c, a Department dynamics study of heat conduction in carbon nanotube (CNT)/polyethylene (PE) composites. Particular across the CNT/polyethylene interfaces ($1 Ā 10Ą7 m2 K WĄ1 ) and a moder- ate but non

  3. A MODIFIED GAMBLER'S RUIN MODEL POLYETHYLENE CHAINS IN THE AMORPHOUS REGION

    E-Print Network [OSTI]

    A MODIFIED GAMBLER'S RUIN MODEL OF POLYETHYLENE CHAINS IN THE AMORPHOUS REGION Zhong­Hui Duan and Louis N. Howard Department of Mathematics The Florida State University ABSTRACT. Polyethylene chainsM 3 +O(M 2 ). INTRODUCTION Semicrystalline polyethylene formed from melt generally consists

  4. P-7 / D. R. Cairns P-7: Wear Resistance of Indium Tin Oxide Coatings on Polyethylene

    E-Print Network [OSTI]

    Cairns, Darran

    P-7 / D. R. Cairns P-7: Wear Resistance of Indium Tin Oxide Coatings on Polyethylene Terephthalate The wear mechanisms of the Indium Tin Oxide (ITO) coated Polyethylene Terephthalate (PET) topsheet). The bottom substrate is typically glass and the top sheet a polyester such as Polyethylene Terephthalate (PET

  5. Association of hydrophobically-modified poly(ethylene glycol) with fusogenic liposomes

    E-Print Network [OSTI]

    Auguste, Debra T.

    interactions to shield liposomes by incorporating multiple hydrophobic anchoring sites on polyethylene glycolAssociation of hydrophobically-modified poly(ethylene glycol) with fusogenic liposomes Debra T, the equilibrium constant for distearoylphosphatidylethanolamine- poly(ethylene glycol) (DSPE-PEG5k) was 0.4F0

  6. Morphology of PolyethyleneCarbon Black Composites G. BEAUCAGE,1

    E-Print Network [OSTI]

    Beaucage, Gregory

    -ray scattering (SAXS) study of a conductive grade of carbon black and carbon black­polymer composites and a power-law scaling of polydispersity. One use of conductive black­polyethylene composites is in circuit(methyl methacrylate); carbon black; filler; composite; conductivity; percolation INTRODUCTION The morphology

  7. Optimization For Grade Transitions In Polyethylene Solution Polymerization

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    , Comonomer, Catalyst, Solvent, Hydrogen 2 1. Che I Kao et al. Non-adiabatic olefin solution polymerizationOptimization For Grade Transitions In Polyethylene Solution Polymerization Jun Shi1, Lorenz T of Advanced Process Decision-making Department of Chemical Engineering Carnegie Mellon University 2The Dow

  8. Optimization For Grade Transitions In Polyethylene Solution Polymerization

    E-Print Network [OSTI]

    Grossmann, Ignacio E.

    Optimization For Grade Transitions In Polyethylene Solution Polymerization Jun Shi1, Intan Hamdan2, Sarat Munjal2, Lorenz T. Biegler1 1Center of Advanced Process Decision-making Department of Chemical perfect mixing · Three types of variables · Manipulated variables · Ethylene, comonomer, hydrogen

  9. Hybrid Polyethylene Glycol Hydrogels for Tissue Engineering Applications 

    E-Print Network [OSTI]

    Munoz Pinto, Dany 1981-

    2012-07-11

    modification of poly(ethylene glycol) hydrogels for tissue engineering? by Junmin Zhu, 2010, Biomaterials 31(17):4639-4656, Copyright 2010, Elsevier Limited. 4 Poly (ethylene glycol) (PEG) hydrogels can be used as a platform in 3D environments in order...

  10. Poly(ethylene glycol)-Modified Ligninase Enhances Pentachlorophenol

    E-Print Network [OSTI]

    Wang, Ping

    Poly(ethylene glycol)-Modified Ligninase Enhances Pentachlorophenol Biodegradation in Water-mail: ekn@ornl.gov Received 7 May 1998; accepted 5 December 1998 Abstract: Polychlorinated hydrocarbons are prevalent environmental contaminants whose rates of biodegrada- tion are limited by their minimal

  11. RESEARCH ARTICLE Biodegradable mulch instead of polyethylene for weed

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    of biodegradable plastic mulch, black, 15 m, (6) oxo-degradable plastic mulch, black, 15 m, (7) paper mulch, black mulches and PE ranging between 80% and 100% for all of them; also, yield was similar for all plasticRESEARCH ARTICLE Biodegradable mulch instead of polyethylene for weed control of processing tomato

  12. Polymer geometry and Li+ conduction in poly(ethylene oxide)

    E-Print Network [OSTI]

    Averbuch, Amir

    Polymer geometry and Li+ conduction in poly(ethylene oxide) L. Gitelman a , M. Israeli b, , A: Lithium battery Polymer molecule Brownian motion Simulation Conductivity PEO a b s t r a c t We study of the amorphous PE structure is increased by mechanical stretching due to the unraveling of loops in the polymer

  13. Development of a high-density gas-jet target for nuclear astrophysics and reaction studies with rare isotope beams. Final Report

    SciTech Connect (OSTI)

    Uwe, Greife

    2014-08-12

    The purpose of this project was to develop a high-density gas jet target that will enable a new program of transfer reaction studies with rare isotope beams and targets of hydrogen and helium that is not currently possible and will have an important impact on our understanding of stellar explosions and of the evolution of nuclear shell structure away from stability. This is the final closeout report for the project.

  14. Versatile wide angle diffraction setup for simultaneous wide and small angle x-ray scattering measurements with synchrotron radiation

    SciTech Connect (OSTI)

    Rueda, D.R.; Garcia-Gutierrez, M.C.; Nogales, A.; Capitan, M.J.; Ezquerra, T.A.; Labrador, A.; Fraga, E.; Beltran, D.; Juanhuix, J.; Herranz, J.F.; Bordas, J. [Instituto de Estructura de la Materia, CSIC, Serrano 119, 28006 Madrid (Spain); LLS, BM16-ESRF, 6 rue Jules Horowitz, BP220, 38043 Grenoble (France)

    2006-03-15

    Here we present a novel, simple, and versatile experimental setup aimed to perform wide angle x-ray scattering (WAXS) measurements alone or in simultaneous combination with small angle x-ray scattering measurements. The design of the WAXS goniometer allows one to obtain high resolution diffraction patterns in a broad angular range. The setup can incorporate a hot stage in order to evaluate temperature resolved experiments. The performance of the equipment has been verified in the BM16 beam line of the European Synchrotron Radiation Facility with different well known samples such as alumina, isotropic film of high density polyethylene (HDPE), and oriented HPDE fiber.

  15. BMC{trademark}: Baseline report; Greenbook (chapter)

    SciTech Connect (OSTI)

    NONE

    1997-07-31

    Barrier Membrane Containment (BMC){trademark} is a high-density polyethylene membrane (HDPE) groundwater barrier and pass-through system, with applications ranging from plume control and containment to groundwater manipulation coupled with in-site treatment. BMC{trademark} system can function as a permeable or impermeable reaction wall, a cut-off wall, interceptor trenches, a barrier with collection and/or monitoring system, and a pass-through in a funnel and gate configuration. BMC{trademark} can be inspected with a down-hole video camera, producing a permanent VHS format tape, insuring the integrity of the wall and the interlocking joints.

  16. Non-laminated FRP Strap Elements for Reinforced Concrete, Timber and Masonry Applications

    E-Print Network [OSTI]

    Lees, Janet M.; Winistörfer, A. U.

    2010-05-11

    - metallic versions of support pads of the type shown in Fig. 5 have also been developed (Nägeli 2006). Straps consisting of 10 layers of 0.13 mm CFRP tape supported on high density polyethylene (HDPE), GFRP or CFRP prestressed concrete pads have been... for Reinforced Concrete Structures (FRPRCS-7). SP-230 , eds: C.K. Shield, J.P. Busel, S.L. Walkup and D.D. Gremel, ACI International SP-230-40, pp.685-704. 7. Hoult, N.A. and Lees, J.M. (2009), Efficient CFRP strap configurations for the shear...

  17. Evaluation of plastic materials for range shifting, range compensation, and solid-phantom dosimetry in carbon-ion radiotherapy

    SciTech Connect (OSTI)

    Kanematsu, Nobuyuki; Koba, Yusuke; Ogata, Risa [Research Center for Charged Particle Therapy, National Institute of Radiological Sciences, 4-9-1 Anagawa, Inage-ku, Chiba 263-8555 (Japan)

    2013-04-15

    Purpose: Beam range control is the essence of radiotherapy with heavy charged particles. In conventional broad-beam delivery, fine range adjustment is achieved by insertion of range shifting and compensating materials. In dosimetry, solid phantoms are often used for convenience. These materials should ideally be equivalent to water. In this study, the authors evaluated dosimetric water equivalence of four common plastics, high-density polyethylene (HDPE), polymethyl methacrylate (PMMA), polyethylene terephthalate (PET), and polyoxymethylene (POM). Methods: Using the Bethe formula for energy loss, the Gottschalk formula for multiple scattering, and the Sihver formula for nuclear interactions, the authors calculated the effective densities of the plastics for these interactions. The authors experimentally measured variation of the Bragg peak of carbon-ion beams by insertion of HDPE, PMMA, and POM, which were compared with analytical model calculations. Results: The theoretical calculation resulted in slightly reduced multiple scattering and severely increased nuclear interactions for HDPE, compared to water and the other plastics. The increase in attenuation of carbon ions for 20-cm range shift was experimentally measured to be 8.9% for HDPE, 2.5% for PMMA, and 0.0% for POM while PET was theoretically estimated to be in between PMMA and POM. The agreement between the measurements and the calculations was about 1% or better. Conclusions: For carbon-ion beams, POM was dosimetrically indistinguishable from water and the best of the plastics examined in this study. The poorest was HDPE, which would reduce the Bragg peak by 0.45% per cm range shift, although with marginal superiority for reduced multiple scattering. Between the two clear plastics, PET would be superior to PMMA in dosimetric water equivalence.

  18. Molecular dynamics simulation of chains mobility in polyethylene crystal

    E-Print Network [OSTI]

    V. I. Sultanov; V. V. Atrazhev; D. V. Dmitriev; S. F. Burlatsky

    2014-01-17

    The mobility of polymer chains in perfect polyethylene (PE) crystal was calculated as a function of temperature and chain length through Molecular dynamics (MD) in united atom approximation. The results demonstrate that the chain mobility drastically increases in the vicinity of the phase transition from the orthorhombic to quasi-hexagonal phase. In the quasi-hexagonal phase, the chain mobility is almost independent on temperature and inversely proportional to the chain length.

  19. Void morphology in polyethylene/carbon black composites

    SciTech Connect (OSTI)

    Marr, D.W.M.; Wartenberg, M.; Schwartz, K.B.

    1996-12-31

    A combination of small angle neutron scattering (SANS) and contrast matching techniques is used to determine the size and quantity of voids incorporated during fabrication of polyethylene/carbon black composites. The analysis used to extract void morphology from SANS data is based on the three-phase model of microcrack determination via small angle x-rayscattering (SAXS) developed by W.Wu{sup 12} and applied to particulate reinforced composites.

  20. Cementitious building material incorporating end-capped polyethylene glycol as a phase change material

    DOE Patents [OSTI]

    Salyer, Ival O. (Dayton, OH); Griffen, Charles W. (Mason, OH)

    1986-01-01

    A cementitious composition comprising a cementitious material and polyethylene glycol or end-capped polyethylene glycol as a phase change material, said polyethylene glycol and said end-capped polyethylene glycol having a molecular weight greater than about 400 and a heat of fusion greater than about 30 cal/g; the compositions are useful in making pre-formed building materials such as concrete blocks, brick, dry wall and the like or in making poured structures such as walls or floor pads; the glycols can be encapsulated to reduce their tendency to retard set.

  1. Schottky and other electrical phenomena in polyethylene crystals 

    E-Print Network [OSTI]

    Stoltz, Richard Joseph

    1970-01-01

    fields to 2&c applie&1 ac ros s the alumi? num-polyethylene-aluminum sandwich (I ig 7). Each step of sample preparation is photographed to allow determination of the area, of the crystal between the electrodes as well as to provide visual evidence... thickness can be calculated. 2 P i y[ if'yLf="I= ? ? --~ GLASS SLI!)i- ll; '/41. '-/~ / L~Z 1, ' / / //y. '. ', , j; / / / IAICA ~ ALIIlIIfIIIlI SUBSTRATF. Technique oi mas1 in' crystals. Top view. ALUfll NUi'i ALUf'l I 'JUIAI z 'J~ GLASS 9'ig. 7...

  2. Deuterated polyethylene coatings for ultra-cold neutron applications

    E-Print Network [OSTI]

    Altarev, I; Fierlinger, P; Geltenbort, P; Gutsmiedl, E; Kuchler, F; Lauer, T; Lins, T; Marino, M G; Niessen, B; Petzoldt, G; Ruhstorfer, D; Seeman, K M; Soltwedel, O; Stuiber, St; Taubenheim, B; Windmayer, D; Zechlau, T

    2015-01-01

    We report on the fabrication and use of deuterated polyethylene (dPE) as a coating material for ultra-cold neutron (UCN) storage and transport. The Fermi potential has been determined to be 214 neV and the wall loss coefficient $\\eta$ is 2$\\cdot$10$^4$ per wall collision. The coating technique allows for a wide range of applications and new possibilities in this field of physics. In particular, flexible and quasi-massless UCN guides with slit-less shutters and slit-less UCN storage volumes become possible. These properties enable the use in next-generation measurements of the electric dipole moment of the neutron.

  3. Production of Polyethylene Terephthalate using a Nonmetallic Catalyst Dr. Marsha Winston1, Jared Langson2, Angus Ferguson2, Dr. Robert Posey2

    E-Print Network [OSTI]

    Production of Polyethylene Terephthalate using a Nonmetallic Catalyst Dr. Marsha Winston1, Jared Department of Chemistry Polyethylene terephthalate (PET) is a condensation polymer of terephthalic acid (HOOC

  4. Polyethylene glycol (PEG) is a hydrophilic polymer that has been used for many years to fuse the membranes of various

    E-Print Network [OSTI]

    Duerstock, Bradley

    Polyethylene glycol (PEG) is a hydrophilic polymer that has been used for many years to fuse spinal cord injury. This involves a brief application of polyethylene glycol (PEG) to the site of injury

  5. Ion-Induced Nucleation of Dibutyl Phthalate Vapors on Spherical and Nonspherical Singly and Multiply Charged Polyethylene Glycol Ions

    E-Print Network [OSTI]

    and Multiply Charged Polyethylene Glycol Ions Albert G. Nasibulin,*, Juan Fernandez de la Mora, and Esko I by positive polyethylene glycol (PEG) ions with controlled sizes and charges was experimentally studied

  6. This article is protected by copyright. All rights reserved. Metalized Polyethylene Mulch to Repel Asian Citrus Psyllid, Slow Spread of

    E-Print Network [OSTI]

    Ma, Lena

    This article is protected by copyright. All rights reserved. Metalized Polyethylene Mulch to Repel to the disease. We tested the ability of metalized polyethylene mulch to repel adult ACP as well as effects

  7. Adhesion energy in carbon nanotube-polyethylene composite: Effect of chirality

    E-Print Network [OSTI]

    Garmestani, Hamid

    Adhesion energy in carbon nanotube-polyethylene composite: Effect of chirality M. Al-Haik and M. Y 2005 This work presents a study of the adhesion energy between carbon nanotube-polyethylene matrix nanotube chirality on adhesion energy. It is observed that composites that utilize nanotubes with smaller

  8. Composite Polymer Electrolytes Based on Poly(ethylene glycol) and Hydrophobic Fumed Silica: Dynamic

    E-Print Network [OSTI]

    Raghavan, Srinivasa

    Composite Polymer Electrolytes Based on Poly(ethylene glycol) and Hydrophobic Fumed Silica: Dynamic are used to probe the microstructures present in fumed silica-based composite polymer electrolytes electrolytes based on poly(ethylene oxide) (PEO).1 Solid polymer electrolytes can potentially eliminate battery

  9. Assessment of an ORION-based experimental platform for measuring the opacity of high-temperature and high-density plasma

    SciTech Connect (OSTI)

    Beiersdorfer, P; Schneider, M; Shepherd, R

    2012-06-11

    The following provides an assessment of an experimental platform based on the ORION laser at AWE Aldermasten, England, for measuring the opacity of high-temperature and high-density LTE plasmas. The specific points addressed are (1) the range of electron density and temperature that can be achieved with short-pulse beams alone, as well as (2) by means of compression with a long-pulse beam; (3) the accuracy with which electron density, electron temperature, and absolute emissivity can be measured; (4) the use of pulse shaping to increase the sample density to above solid density; (5) the effect that target materials and target design have on maintaining spatial uniformity of the sample, and (6) the need for additional diagnostics to produce and characterize samples for decisive measurements.

  10. Evidence of the existence of the high-density and low-density phases in deeply-cooled confined heavy water under high pressures

    SciTech Connect (OSTI)

    Wang, Zhe; Chen, Sow-Hsin; Liu, Kao-Hsiang; Harriger, Leland; Lećo, Juscelino B.

    2014-07-07

    The average density of D{sub 2}O confined in a nanoporous silica matrix (MCM-41-S) is studied with neutron scattering. We find that below ?210 K, the pressure-temperature plane of the system can be divided into two regions. The average density of the confined D{sub 2}O in the higher-pressure region is about 16% larger than that in the lower-pressure region. These two regions could represent the so-called “low-density liquid” and “high-density liquid” phases. The dividing line of these two regions, which could represent the associated 1st order liquid-liquid transition line, is also determined.

  11. MacroCapTM SP is a cation exchanger designed for the purification of large biomolecules such as polyethylene

    E-Print Network [OSTI]

    Lebendiker, Mario

    such as polyethylene glycol (PEG)-modified proteins (i.e., PEGylated proteins) that are intended for use

  12. Effects of storage temperature and duration on release of antimony and bisphenol A from polyethylene terephthalate drinking water

    E-Print Network [OSTI]

    Ma, Lena

    polyethylene terephthalate drinking water bottles of China Ying-Ying Fan a , Jian-Lun Zheng a , Jing-Hua Ren Accepted 9 May 2014 Available online xxx Keywords: Polyethylene terephthalate Antimony Bisphenol A Release of antimony (Sb) and bisphenol A (BPA) from 16 brands of polyethylene terephthalate (PET) drinking water

  13. Effects of polyethylene mulch in a short-rotation, poplar plantation vary with weed-control strategies,

    E-Print Network [OSTI]

    Green, Scott

    Effects of polyethylene mulch in a short-rotation, poplar plantation vary with weed polyethylene mulch (poly mulch) across a range of site conditions, weed-control treatments and genotypes rights reserved. Keywords: Polyethylene mulch; Woody crops; Weed control Forest Ecology and Management

  14. Crystallization in the Thin and Ultrathin Films of Poly(ethylene-vinyl acetate) and Linear Low-Density Polyethylene

    E-Print Network [OSTI]

    -Density Polyethylene Y. Wang, S. Ge, M. Rafailovich,*, J. Sokolov, Y. Zou, H. Ade, J. Lu1 ning,§ A. Lustiger, and G(ethylene-vinyl acetate) and linear low-density polyethylene (LLDPE) films spun-cast from the polymer/toluene solutions spherulite to sheaflike ag- gregates in polyethylene thin films at a critical thickness of 400 nm. Scho

  15. Friction and wear behavior of ultra-high molecular weight polyethylene as a function of polymer crystallinity

    E-Print Network [OSTI]

    Lin, Zhiqun

    Friction and wear behavior of ultra-high molecular weight polyethylene as a function of polymer-grade ultra-high molecular weight polyethylene (UHMWPE) (GUR 1050 resin) were evaluated as a function replacements; Ultra-high molecular weight polyethylene (UHMWPE); Crystallinity; Friction; Wear 1. Introduction

  16. Efficient high density train operations

    DOE Patents [OSTI]

    Gordon, Susanna P. (Oakland, CA); Evans, John A. (Hayward, CA)

    2001-01-01

    The present invention provides methods for preventing low train voltages and managing interference, thereby improving the efficiency, reliability, and passenger comfort associated with commuter trains. An algorithm implementing neural network technology is used to predict low voltages before they occur. Once voltages are predicted, then multiple trains can be controlled to prevent low voltage events. Further, algorithms for managing inference are presented in the present invention. Different types of interference problems are addressed in the present invention such as "Interference. During Acceleration", "Interference Near Station Stops", and "Interference During Delay Recovery." Managing such interference avoids unnecessary brake/acceleration cycles during acceleration, immediately before station stops, and after substantial delays. Algorithms are demonstrated to avoid oscillatory brake/acceleration cycles due to interference and to smooth the trajectories of closely following trains. This is achieved by maintaining sufficient following distances to avoid unnecessary braking/accelerating. These methods generate smooth train trajectories, making for a more comfortable ride, and improve train motor reliability by avoiding unnecessary mode-changes between propulsion and braking. These algorithms can also have a favorable impact on traction power system requirements and energy consumption.

  17. Polymer crystal-melt interfaces and nucleation in polyethylene

    E-Print Network [OSTI]

    Scott T. Milner

    2010-09-22

    Kinetic barriers cause polymers to crystallize incompletely, into nanoscale lamellae interleaved with amorphous regions. As a result, crystalline polymers are full of crystal-melt interfaces, which dominate their physical properties. The longstanding theoretical challenge to understand these interfaces has new relevance, because of accumulating evidence that polymer crystals often nucleate via a metastable, partially ordered "rotator" phase. To test this idea requires a theory of the bulk and interfacial free energies of the critical nucleus. We present a new approach to the crystal-melt interface, which represents the amorphous region as a grafted brush of loops in a self-consistent pressure field. We combine this theory with estimates of bulk free energy differences, to calculate nucleation barriers and rates via rotator versus crystal nuclei for polyethylene. We find rotator-phase nucleation is indeed favored throughout the temperature range where nucleation is observed. Our methods can be extended to other polymers.

  18. Giant Thermal Rectification from Polyethylene Nanofiber Thermal Diodes

    E-Print Network [OSTI]

    Zhang, Teng

    2015-01-01

    The realization of phononic computing is held hostage by the lack of high performance thermal devices. Here we show through theoretical analysis and molecular dynamics simulations that unprecedented thermal rectification factors (as large as 1.20) can be achieved utilizing the phase dependent thermal conductivity of polyethylene nanofibers. More importantly, such high thermal rectifications only need very small temperature differences (< 20 oC) across the device, which is a significant advantage over other thermal diodes which need temperature biases on the order of the operating temperature. Taking this into consideration, we show that the dimensionless temperature-scaled rectification factors of the polymer nanofiber diodes range from 12 to 25 - much larger than other thermal diodes (< 8). The polymer nanofiber thermal diode consists of a crystalline portion whose thermal conductivity is highly phase-sensitive and a cross-linked portion which has a stable phase. Nanoscale size effect can be utilized t...

  19. Accepted for Publication in J. Rheology (May/June 2005 Issue) March 1, 2005 Measuring the Transient Extensional Rheology of Polyethylene Melts

    E-Print Network [OSTI]

    Extensional Rheology of Polyethylene Melts Using the SER Universal Testing Platform Martin Sentmanat Senkhar stress growth in a number of different molten polyethylene samples including a linear low density polyethylene (Dow Affinity PL 1880), a low density polyethylene (Lupolen 1840H) and an ultrahigh molecular

  20. High density and taper-free boron doped Si{sub 1?x}Ge{sub x} nanowire via two-step growth process

    SciTech Connect (OSTI)

    Periwal, Priyanka; Salem, Bassem; Bassani, Franck; Baron, Thierry, E-mail: thierry.baron@cea.fr [University of Grenoble Alpes LTM, F-38000 Grenoble, France and CNRS LTM, UMR-5129, F-38000 Grenoble (France); Barnes, Jean-Paul [CEA-Leti, MINATEC Campus, 17 rue des Martyrs, 38054 Grenoble Cedex 9 (France)

    2014-07-01

    The authors study Au catalyzed chemical vapor growth of Si{sub 1?x}Ge{sub x} alloyed nanowires in the presence of diborane, serving as a dopant precursor. Our experiments reveal that introduction of diborane has a significant effect on doping and morphology. Boron exposure poisons the Au catalyst surface, suppresses catalyst activity, and causes significantly tapered wires, as a result of conformal growth. The authors develop here a two-step method to obtain high density and taper-free boron doped Si{sub 1?x}Ge{sub x} alloy nanowires. The two-step process consists of: (1) growth of a small undoped Si{sub 1?x}Ge{sub x} section and (2) introduction of diborane to form a boron doped Si{sub 1?x}Ge{sub x} section. The catalyst preparation step remarkably influences wire yield, quality and morphology. The authors show that dopant-ratio influences wire resistivity and morphology. Resistivity for high boron doped Si{sub 1?x}Ge{sub x} nanowire is 6 m?-cm. Four probe measurements show that it is possible to dope Si{sub 1?x}Ge{sub x} alloy nanowires with diborane.

  1. Plastic Deformation of Semicrystalline Polyethylene under Extension, Compression, and Shear Using Molecular Dynamics Simulation

    E-Print Network [OSTI]

    Kim, Jun Mo

    Plastic deformation of the stack of alternating crystal and amorphous layers typical of semicrystalline polyethylene is studied by molecular dynamics simulation. A previous investigation of the semicrystalline layered stack ...

  2. Methods for increasing the thermal conductivity of ultra-high molecular weight polyethylene (UHMWPE)

    E-Print Network [OSTI]

    Miler, Josef L

    2006-01-01

    A two-part study was conducted to determine methods for producing ultra-high molecular weight polyethylene with high thermal conductivity by way of polymer chain orientation. The first portion of this report surveys current ...

  3. A method for using polyethylene passive samplers to measure polycyclic aromatic hydrocarbon chemical activity in sediments

    E-Print Network [OSTI]

    Fernandez, Loretta A. (Loretta Ana)

    2005-01-01

    In order to aid in the determination of the hazards posed by hydrophobic organic compounds (HOCs) in sediment beds, a method for the use of polyethylene (PE) sheets as passive sampling devices for measuring chemical ...

  4. Comparative investigations of surface instabilities ("sharkskin") of a linear and a long-chain branched polyethylene

    E-Print Network [OSTI]

    Teodor I. Burghelea; Hans J. Griess; Helmut Muenstedt

    2010-01-15

    An experimental study of the physical origin and the mechanisms of the sharkskin instability is presented. Extrusion flows through a slit die are studied for two materials: a linear low density polyethylene (LLDPE) and a low density polyethylene (LDPE). By combining laser-Doppler velocimetry (LDV) with rheological measurements in both uniaxial extension and shear, the distributions of tensile and shear stresses in extrusion flows are measured for both materials.

  5. Electron capture and beta-decay rates for sd-shell nuclei in stellar environments relevant to high density O-Ne-Mg cores

    E-Print Network [OSTI]

    Toshio Suzuki; Hiroshi Toki; Ken'ichi Nomoto

    2015-12-01

    Electron capture and beta-decay rates for nuclear pairs in sd-shell are evaluated at high densities and high temperatures relevant to the final evolution of electron-degenerate O-Ne-Mg cores of stars with the initial masses of 8-10 solar mass. Electron capture induces a rapid contraction of the electron-degenerate O-Ne-Mg core. The outcome of rapid contraction depends on the evolutionary changes in the central density and temperature, which are determined by the competing processes of contraction, cooling, and heating. The fate of the stars are determined by these competitions, whether they end up with electron-capture supernovae or Fe core-collapse supernovae. Since the competing processes are induced by electron capture and beta-decay, the accurate weak rates are crucially important. The rates are obtained for pairs with A=20, 23, 24, 25 and 27 by shell-model calculations in sd-shell with the USDB Hamiltonian. Effects of Coulomb corrections on the rates are evaluated. The rates for pairs with A=23 and 25 are important for nuclear URCA processes that determine the cooling rate of O-Ne-Mg core, while those for pairs with A=20 and 24 are important for the core-contraction and heat generation rates in the core. We provide these nuclear rates at stellar environments in tables with fine enough meshes at various densities and temperatures for the studies of astrophysical processes sensitive to the rates. In particular, the accurate rate tables are crucially important for the final fates of not only O-Ne-Mg cores but also a wider range of stars such as C-O cores of lower mass stars.

  6. High-Temperature SiC Power Module with Integrated SiC Gate Drivers for Future High-Density Power Electronics Applications

    SciTech Connect (OSTI)

    Whitaker, Mr. Bret [APEI, Inc.; Cole, Mr. Zach [APEI, Inc.; Passmore, Mr. Brandon [APEI, Inc.; Martin, Daniel [APEI, Inc.; Mcnutt, Tyler [APEI, Inc.; Lostetter, Dr. Alex [APEI, Inc.; Ericson, Milton Nance [ORNL; Frank, Steven Shane [ORNL; Britton Jr, Charles L [ORNL; Marlino, Laura D [ORNL; Mantooth, Alan [University of Arkansas; Francis, Dr. Matt [University of Arkansas; Lamichhane, Ranjan [University of Arkansas; Shepherd, Dr. Paul [University of Arkansas; Glover, Dr. Michael [University of Arkansas

    2015-01-01

    This paper presents the testing results of an all-silicon carbide (SiC) intelligent power module (IPM) for use in future high-density power electronics applications. The IPM has high-temperature capability and contains both SiC power devices and SiC gate driver integrated circuits (ICs). The high-temperature capability of the SiC gate driver ICs allows for them to be packaged into the power module and be located physically close to the power devices. This provides a distinct advantage by reducing the gate driver loop inductance, which promotes high frequency operation, while also reducing the overall volume of the system through higher levels of integration. The power module was tested in a bridgeless-boost converter to showcase the performance of the module in a system level application. The converter was initially operated with a switching frequency of 200 kHz with a peak output power of approximately 5 kW. The efficiency of the converter was then evaluated experimentally and optimized by increasing the overdrive voltage on the SiC gate driver ICs. Overall a peak efficiency of 97.7% was measured at 3.0 kW output. The converter s switching frequency was then increased to 500 kHz to prove the high frequency capability of the power module was then pushed to its limits and operated at a switching frequency of 500 kHz. With no further optimization of components, the converter was able to operate under these conditions and showed a peak efficiency of 95.0% at an output power of 2.1 kW.

  7. Mesophases in polyethylene, polypropylene, and poly(1-butene)

    SciTech Connect (OSTI)

    Androsch, Rene J; Di Lorenzo, Maria; Schick, Christoph; Wunderlich, Bernhard {nmn}

    2010-01-01

    This paper contains new views about the amorphous and partially ordered phases of the three polymers listed in the title. The discussion is based on information on structure, thermodynamic stability, and large-amplitude molecular motion. Polyethylene is the basic backbone of all alkene polymers, and the other two are the first members of the vinyl polymers which have stereospecifically placed alkyl side chains. Their multiphase structures consist of metastable crystals, mesophases, and surrounding rigid and mobile amorphous fractions. All these phases have sizes ranging from micrometer dimensions down to nanometers. Besides the phase structures, information about the molecular coupling between the phases must be considered. Depending on temperature, the polymer phases can vary from solid (rigid) to liquid (mobile). New knowledge is also gained by cross-comparison of the title polymers. The experimental information was gained from (a) various forms of slow, fast, and temperature-modulated thermal analysis to identify equilibrium and non-equilibrium states, (b) measurement of structure and morphology at various length scales, and (c) tracing of the large-amplitude molecular motion, the kinetics of order/disorder changes, and the liquid/solid transitions (glass transitions). It is shown that much more needs to be known about the various phases and their coupling to characterize a given polymer and to fine-tune its properties for a given application.

  8. Molecular Dynamics Study of Stiffness in Polystyrene and Polyethylene

    E-Print Network [OSTI]

    Hamed Nazarpourfard; Mahdi Ahmadi Borji

    2015-04-26

    In this paper, we have studied polystyrene (PS) and polyethylene (PE) stiffness by 3-dimensional Langevin Molecular Dynamics simulation. Hard polymers have a very small bending, and thus, their end-to-end distance is more than soft polymers. Quantum dot lasers can be established as colloidal particles dipped in a liquid and grafted by polymer brushes to maintain the solution. Here by a study on molecular structures of PS and PE, we show that the principle reason lies on large phenyl groups around the backbone carbons of PS, rather than a PE with Hydrogen atoms. Our results show that the mean radius of PS random coil is more than PE which directly affects the quantum dot maintenance. In addition, effect of temperature increase on the mean radius is investigated. Our results show that by increasing temperature, both polymers tend to lengthen, and at all temperatures a more radius is predicted for PS rather than PE, but interestingly, with a difference in short and long chains. We show that stiffness enhancement is not the same at short and long polymers and the behavior is very different. Our results show a good consonance with both experimental and theoretical studies.

  9. Molecular Dynamics Study of Stiffness in Polystyrene and Polyethylene

    E-Print Network [OSTI]

    Mahdi Ahmadi Borji

    2015-10-10

    In this paper, we have studied polystyrene (PS) and polyethylene (PE) stiffness by 3-dimensional Langevin Molecular Dynamics simulation. Hard polymers have a very small bending, and thus, their end-to-end distance is more than soft polymers. Quantum dot lasers can be established as colloidal particles dipped in a liquid and grafted by polymer brushes to maintain the solution. Here by a study on molecular structures of PS and PE, we show that the principle reason lies on large phenyl groups around the backbone carbons of PS, rather than a PE with Hydrogen atoms. Our results show that the mean radius of PS random coil is more than PE which directly affects the quantum dot maintenance. In addition, effect of temperature increase on the mean radius is investigated. Our results show that by increasing temperature, both polymers tend to lengthen, and at all temperatures a more radius is predicted for PS rather than PE, but interestingly, with a difference in short and long chains. We show that stiffness enhancement is not the same at short and long polymers and the behavior is very different. Our results show a good consonance with both experimental and theoretical studies.

  10. Molecular Dynamics Study of Stiffness in Polystyrene and Polyethylene

    E-Print Network [OSTI]

    Nazarpourfard, Hamed

    2015-01-01

    In this paper, we have studied polystyrene (PS) and polyethylene (PE) stiffness by 3-dimensional Langevin Molecular Dynamics simulation. Hard polymers have a very small bending, and thus, their end-to-end distance is more than soft polymers. Quantum dot lasers can be established as colloidal particles dipped in a liquid and grafted by polymer brushes to maintain the solution. Here by a study on molecular structures of PS and PE, we show that the principle reason lies on large phenyl groups around the backbone carbons of PS, rather than a PE with Hydrogen atoms. Our results show that the mean radius of PS random coil is more than PE which directly affects the quantum dot maintenance. In addition, effect of temperature increase on the mean radius is investigated. Our results show that by increasing temperature, both polymers tend to lengthen, and at all temperatures a more radius is predicted for PS rather than PE, but interestingly, with a difference in short and long chains. We show that stiffness enhancement...

  11. Low-cost phase change material as an energy storage medium in building envelopes: Experimental and numerical analyses

    SciTech Connect (OSTI)

    Biswas, Kaushik; Abhari, Mr. Ramin

    2014-01-01

    A promising approach to increasing the energy efficiency of buildings is the implementation of a phase change material (PCM) in the building envelope. Numerous studies over the last two decades have reported the energy saving potential of PCMs in building envelopes, but their wide application has been inhibited, in part, by their high cost. This article describes a novel PCM made of naturally occurring fatty acids/glycerides trapped into high density polyethylene (HDPE) pellets and its performance in a building envelope application. The PCM-HDPE pellets were mixed with cellulose insulation and then added to an exterior wall of a test building in a hot and humid climate, and tested over a period of several months, To demonstrate the efficacy of the PCM-enhanced cellulose insulation in reducing the building envelope heat gains and losses, side-by-side comparison was performed with another wall section filled with cellulose-only insulation. Further, numerical modeling of the test wall was performed to determine the actual impact of the PCM-HDPE pellets on wall-generated heating and cooling loads and the associated electricity consumption. The model was first validated using experimental data and then used for annual simulations using typical meteorological year (TMY3) weather data. This article presents the experimental data and numerical analyses showing the energy-saving potential of the new PCM.

  12. Ultra-HighDensity Board Technologyfor suh-100pn Pitch nano-WaferLevel Packaging Venky Sundaram, Fuhan Liu, Ankur 0.Aggarwal, Seyed M. Hosseini, Sharath Mekala, George E. White, Rao R. Tummala,

    E-Print Network [OSTI]

    Swaminathan, Madhavan

    Ultra-HighDensity Board Technologyfor suh-100pn Pitch nano-WaferLevel Packaging Venky Sundaram, Packaging Research Center, Georgia Institute of Technology, 813 Ferst Dr, Atlanta, GA 30332-0560, USA and the package increases tremendously. With the shift towards nano ICs by 2004 with cl00 nm feature sizes

  13. A course-grained model for polyethylene glycol polymer

    SciTech Connect (OSTI)

    Nicholson, Don M [ORNL; Wang, Qifei [ORNL; Keffer, David J [ORNL

    2011-01-01

    A coarse-grained (CG) model of polyethylene glycol (PEG) was developed and implemented in CG molecular dynamics (MD) simulations of PEG chains with degree of polymerization (DP) 20 and 40. In the model, two repeat units of PEG are grouped as one CG bead. Atomistic MD simulation of PEG chains with DP = 20 was first conducted to obtain the bonded structural probability distribution functions (PDFs) and nonbonded pair correlation function (PCF) of the CG beads. The bonded CG potentials are obtained by simple inversion of the corresponding PDFs. The CG nonbonded potential is parameterized to the PCF using both an inversion procedure based on the Ornstein-Zernike equation with the Percus-Yevick approximation (OZPY{sup -1}) and a combination of OZPY{sup -1} with the iterative Boltzmann inversion (IBI) method (OZPY{sup -1}+IBI). As a simple one step method, the OZPY{sup -1} method possesses an advantage in computational efficiency. Using the potential from OZPY{sup -1} as an initial guess, the IBI method shows fast convergence. The coarse-grained molecular dynamics (CGMD) simulations of PEG chains with DP = 20 using potentials from both methods satisfactorily reproduce the structural properties from atomistic MD simulation of the same systems. The OZPY{sup -1}+IBI method yields better agreement than the OZPY{sup -1} method alone. The new CG model and CG potentials from OZPY{sup -1}+IBI method was further tested through CGMD simulation of PEG with DP = 40 system. No significant changes are observed in the comparison of PCFs from CGMD simulations of PEG with DP = 20 and 40 systems indicating that the potential is independent of chain length.

  14. Relative Biological Effectiveness of HZE Fe Ions for Induction of Micro-Nuclei at Low Doses

    E-Print Network [OSTI]

    Groesser, Torsten; Chun, Eugene; Rydberg, Bjorn

    2007-01-01

    with shielding, high density polyethylene plastic of variousshielding, various amounts (0–30 cm) of high-density (tissue- equivalent) polyethyleneshielding thickness. Various amounts of high-density polyethylene

  15. An atomistic description of the high-field degradation of dielectric polyethylene

    SciTech Connect (OSTI)

    Bealing, Clive R.; Ramprasad, R.

    2013-11-07

    A microscopic mechanism governing the initiating step in the high-field aging of crystalline polyethylene is proposed, based on density functional calculations and ab initio molecular dynamics simulations. It is assumed that electrons, holes, and excitons are present in the system. While the additional individual electrons or holes are not expected to lead to significant degradation, the presence of triplet excitons are concluded to be rather damaging. The electron and hole states of the exciton localize on a distorted region of polyethylene, significantly weakening nearby C–H bonds and facilitating C–H bond scission. The barrier to cleavage of the weakened C–H bonds is estimated and is comparable to the thermal energy, suggesting that this mechanism may be responsible for the degradation of polyethylene when placed under electrical stress, e.g., in high-voltage cables.

  16. Effect of nano-fibers on the stress-strain behavior of semi-crystalline poly(ethylene terephthalate) at different strain rates

    E-Print Network [OSTI]

    Cohen, Ellann

    2008-01-01

    Uniaxial compression tests were performed on amorphous poly(ethylene terephthalate) (PET), amorphous poly(ethylene terephthalate)- glycol (PETG), semi-crystalline PET, and semicrystalline PET with various amounts of ...

  17. A Neutron Reflectivity Study of Polymer-Modified Phospholipid Monolayers at the Solid-Solution Interface: Polyethylene Glycol-Lipids on

    E-Print Network [OSTI]

    Wong, Joyce

    -Solution Interface: Polyethylene Glycol-Lipids on Silane-Modified Substrates T. L. Kuhl,# J. Majewski,* J. Y. Wong amounts of DSPE-PEG (DSPE with polyethylene glycol covalently grafted to its headgroup). Mixed lipid

  18. Comparison between Protein-Polyethylene Glycol (PEG) Interactions and the Effect of PEG on Protein-Protein Interactions Using the Liquid-Liquid Phase Transition

    E-Print Network [OSTI]

    Benedek, George B.

    Comparison between Protein-Polyethylene Glycol (PEG) Interactions and the Effect of PEG on Protein transitions is the required presence of additives such as polyethylene glycol (PEG). To investigate

  19. Self-Assembly and Chain-Folding in Hybrid Coil-Coil-Cube Triblock Oligomers of Polyethylene-b-Poly(ethylene

    E-Print Network [OSTI]

    Mather, Patrick T.

    Self-Assembly and Chain-Folding in Hybrid Coil-Coil-Cube Triblock Oligomers of Polyethylene-defined oligomeric polyethylene-block-poly(ethylene oxide)- block-polyhedral oligomeric silsesquioxane (PE

  20. 350 Biophysical Journal Volume 84 January 2003 350355 Osmotic Properties of Poly(Ethylene Glycols): Quantitative Features

    E-Print Network [OSTI]

    Podgornik, Rudolf

    350 Biophysical Journal Volume 84 January 2003 350­355 Osmotic Properties of Poly(Ethylene Glycols the intermembrane distance versus applied osmotic stress data of Kenworthy et al. for poly(ethylene glycol, in a bulk solution of equivalent monomer density, the polymer osmotic pressure is independent of polymer

  1. Rod Lakes, University of Wisconsin, 1 Brandel, B. and Lakes, R. S., "Negative Poisson's ratio polyethylene foams",

    E-Print Network [OSTI]

    Lakes, Roderic

    ] by first saturating the polymer sample with a non-reactive gas, typically CO2 or N2, in a high pressure polyethylene foams", adapted from J. Materials Science, 36, 5885-5893, July (2001). Abstract Various polyethylene foams were subjected to thermo-mechanical processing with the aim of transforming them into re

  2. Capillary Break Beneath a Slab: Polyethylene Sheeting over Aggregate; Southwestern Pennsylvania (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-07-01

    This document provides content for three areas of the Building America Solution Center. First, "Insulating Closed Crawlspace Walls and Band Joist Area" describes how to install rigid foam insulation on the interior perimeter walls and band joist area in closed crawlspace foundations of homes. Second, "Removing Construction Debris from Flexible Ducts" describes how to clean flexible ducts after construction or major renovation of a home to remove debris resulting from building materials, particularly airborne dust and particulates. Third, images, CAD drawings, and a case study illustrate right and wrong ways to apply polyethylene sheeting over aggregate. Similarly, a CAD drawing is included that illustrates the use of a concrete slab over polyethylene.

  3. MD Simulation Study of the Influence of Branch Content on Relaxation and Crystallization of Branched Polyethylene Chains with Uniform Branch Distribution

    E-Print Network [OSTI]

    Hussein, Ibnelwaleed A.

    of Branched Polyethylene Chains with Uniform Branch Distribution I. A. HUSSEIN, B. F. ABU-SHARKH* Department-density polyethylene (LLDPE) chains with different levels of branch content (BC), ranging from 10 to 80 branches/1000 C words: MD simulation, Polyethylene, branch content, chain conformation, radius of gyration

  4. Coextruded Polyethylene and Wood-Flour Composite: Effect of Shell Thickness, Wood Loading, and Core

    E-Print Network [OSTI]

    Appl Polym Sci 118: 3594­3601, 2010 Key words: coextrusion; mechanical properties; recycling recycled polyethylene and wood-flour composites with core­shell structure were manufactured using a pilot to use recycled, low quality plastic-fiber blends in the core layer. VC 2010 Wiley Periodicals, Inc. J

  5. Thermal resistance and phonon scattering at the interface between carbon nanotube and amorphous polyethylene

    E-Print Network [OSTI]

    Elliott, James

    dynamics study of heat conduction in carbon nanotube (CNT)/polyethylene (PE) composites. Particular thermal conductivity of a macroscopic CNT/PE composite is quantified based on an effective medium approximation model. Ó 2013 Elsevier Ltd. All rights reserved. 1. Introduction Polymer composites are employed

  6. Semi-Crystalline Polymers Semi-crystalline polymers, such as polyethylene and polypropylene are common

    E-Print Network [OSTI]

    Beaucage, Gregory

    Semi-Crystalline Polymers Semi-crystalline polymers, such as polyethylene and polypropylene of 5 to 50 nm. Such highly asymmetric, plate like structures tend to stack when sufficient crystalline concentration, or degree of crystallinity, exists. Tie chains between crystallites serve to enhance stacking

  7. Single-site polymerization catalysts: branched polyethylene and syndiotactic poly(alpha-olefins) 

    E-Print Network [OSTI]

    Schwerdtfeger, Eric Dean

    2009-05-15

    (Oct-CGC) were found to melt at higher temperatures (55.9 and 43.1 °C, respectively) than any previously reported samples. The MAO-activated Oct-CGC was also used to produce polyethylene samples at a variety of polymerization temperatures and pressures...

  8. Stochastic model of lithium ion conduction in poly,,ethylene oxide... L. Gitelman,1

    E-Print Network [OSTI]

    Averbuch, Amir

    Stochastic model of lithium ion conduction in poly,,ethylene oxide... L. Gitelman,1 A. Averbuch,2,a. We calculate the energy of configurations of one or two lithium ions in the loop and derive developed a model of lithium ion conduction in dilute and concentrated polymer electrolytes LiI:P EO n 3 n

  9. Solidification of commercial and defense low-level radioactive waste in polyethylene

    SciTech Connect (OSTI)

    Franz, E.M.; Heiser, L.H.; Colombo, P.

    1987-08-01

    A process was developed for the solidification of salt wastes, incinerator ash and ion-exchange resins in polyethylene. Of the salt wastes, sodium sulfate and boric acid are representative of the wastes produced at commercial nuclear facilities while sodium nitrate in a typical high-volume waste generated at defense-related facilities. Ease of processibility and high loading efficiencies were obtained through the use of low-density polyethylene with melt indices ranging from 2.0 to 55.0 g/minute. The process utilized a commercially available single-screw extruder to incorporate the wastes into the polyethylene at about 120/sup 0/C to produce a homogeneous mixture. Although present studies utilize dry wastes, wet wastes can also be processed using vented extruders of the type used commercially for the bitumen solidification process. Tests were performed on the waste forms to determine leachability and mechanical properties. To confirm the compatibility of polyethylene and nitrate salt waste at elevated temperatures, the self-ignition temperatures were measured and a differential scanning calorimeter was used to characterize the thermal behavior of oxidizing compounds contained in the simulated waste, as well as the real Savannah River Plant waste. No exothermic reactions were observed over the temperature range studied from 50/sup 0/C to 400/sup 0/C. 18 refs., 7 figs., 8 tabs.

  10. Polyethylene encapsulatin of nitrate salt wastes: Waste form stability, process scale-up, and economics

    SciTech Connect (OSTI)

    Kalb, P.D.; Heiser, J.H. III; Colombo, P.

    1991-07-01

    A polyethylene encapsulation system for treatment of low-level radioactive, hazardous, and mixed wastes has been developed at Brookhaven National Laboratory. Polyethylene has several advantages compared with conventional solidification/stabilization materials such as hydraulic cements. Waste can be encapsulated with greater efficiency and with better waste form performance than is possible with hydraulic cement. The properties of polyethylene relevant to its long-term durability in storage and disposal environments are reviewed. Response to specific potential failure mechanisms including biodegradation, radiation, chemical attack, flammability, environmental stress cracking, and photodegradation are examined. These data are supported by results from extensive waste form performance testing including compressive yield strength, water immersion, thermal cycling, leachability of radioactive and hazardous species, irradiation, biodegradation, and flammability. The bench-scale process has been successfully tested for application with a number of specific problem'' waste streams. Quality assurance and performance testing of the resulting waste form confirmed scale-up feasibility. Use of this system at Rocky Flats Plant can result in over 70% fewer drums processed and shipped for disposal, compared with optimal cement formulations. Based on the current Rocky Flats production of nitrate salt per year, polyethylene encapsulation can yield an estimated annual savings between $1.5 million and $2.7 million, compared with conventional hydraulic cement systems. 72 refs., 23 figs., 16 tabs.

  11. Tribometer with programmable motion and load to investigate the influence of molecular structure on wear of orthopaedic polyethylene 

    E-Print Network [OSTI]

    Kilgour, Alastair Scott

    2010-01-01

    Total hip arthroplasty commonly involves a hard metallic/ceramic femoral ball component articulating against an acetabular ultra-high molecular weight polyethylene (UHMWPE) counter-bearing. A novel six-station, wear tribometer, featuring...

  12. Quantitative analysis of volatile organic compounds (VOCs) in soil via passive sampling : polyethylene sampler design and optimization

    E-Print Network [OSTI]

    Jensen, David G. (David Gannon)

    2015-01-01

    The potential for the release of volatile organic compounds (VOCs) to our natural environment is pervasive. However, the ability to accurately measure and predict VOC soil vapor concentrations is still limited. A polyethylene ...

  13. Benchtop testing of polyethylene passive sampling towards a quantitative analysis of volatile organic compounds (VOCs) in soil vapours

    E-Print Network [OSTI]

    Soo, Yu Xiang Jaren

    2015-01-01

    The feasibility of polyethylene (PE) as a passive sampler for quantitative analysis of volatile organic compounds (VOCs) was analysed in this work by means of a benchtop testing. A benchtop physical model was setup, which ...

  14. Method for making a low density polyethylene waste form for safe disposal of low level radioactive material

    DOE Patents [OSTI]

    Colombo, P.; Kalb, P.D.

    1984-06-05

    In the method of the invention low density polyethylene pellets are mixed in a predetermined ratio with radioactive particulate material, then the mixture is fed through a screw-type extruder that melts the low density polyethylene under a predetermined pressure and temperature to form a homogeneous matrix that is extruded and separated into solid monolithic waste forms. The solid waste forms are adapted to be safely handled, stored for a short time, and safely disposed of in approved depositories.

  15. Mechanisms for covalent immobilization of horseradish peroxi-dase on ion beam treated polyethylene

    E-Print Network [OSTI]

    Kondyurin, Alexey V; Tilley, Jennifer M R; Nosworthy, Neil J; Bilek, Marcela M M; McKenzie, David R

    2011-01-01

    The mechanism that provides the observed strong binding of biomolecules to polymer sur-faces modified by ion beams is investigated. The surface of polyethylene (PE) was modified by plasma immersion ion implantation with nitrogen ions. Structure changes including car-bonization and oxidation were observed in the modified surface layer of PE by Raman spec-troscopy, FTIR ATR spectroscopy, atomic force microscopy, surface energy measurement and XPS spectroscopy. An observed high surface energy of the modified polyethylene was attributed to the presence of free radicals on the surface. The surface energy decay with stor-age time after PIII treatment was explained by a decay of the free radical concentration while the concentration of oxygen-containing groups increased with storage time. Horseradish per-oxidase was covalently attached onto the modified PE surface. The enzymatic activity of co-valently attached protein remained high. A mechanism based on the covalent attachment by the reaction of protein with free r...

  16. Experiment summary for n/y attenuation through materials (Environments 1A).

    SciTech Connect (OSTI)

    DePriest, Kendall Russell

    2006-05-01

    The Radiation Effects Sciences (RES) program is responsible for conducting Neutron Gamma Energy Transport (NuGET) code validation. In support of this task, a series of experiments were conducted in the annular core research reactor (ACRR) to investigate the modification of the incident neutron/gamma environment by aluminum (Al6061) and high-density polyethylene (HDPE) spheres with 4-in and 7-in-diameter. The experiment series described in this report addresses several NuGET validation concerns. The validation experiment series also addresses the design and execution of proper reactor testing to match the hostile radiation environments and to match the component stresses that arise from the hostile radiation environments. This report summarizes the RES Validation: n/{gamma} Attenuation through Materials, Environments 1A, experiments conducted at the ACRR in FY 2003 using ACRR Experiment Plans 933 and 949.

  17. An In-situ Tensile Test Apparatus for Polymers in High Pressure Hydrogen

    SciTech Connect (OSTI)

    Alvine, Kyle J.; Kafentzis, Tyler A.; Pitman, Stan G.; Johnson, Kenneth I.; Skorski, Daniel C.; Tucker, Joseph C.; Roosendaal, Timothy J.; Dahl, Michael E.

    2014-10-10

    Degradation of material properties by high-pressure hydrogen is an important factor in determining the safety and reliability of materials used in high-pressure hydrogen storage and delivery. Hydrogen damage mechanisms have a time dependence that is linked to hydrogen outgassing after exposure to the hydrogen atmosphere that makes ex-situ measurements of mechanical properties problematic. Designing in-situ measurement instruments for high-pressure hydrogen is challenging due to known hydrogen incompatibility with many metals and standard high-power motor materials like Nd. Here we detail the design and operation of a solenoid based in-situ tensile tester under high-pressure hydrogen environments up to 5,000 psi. Modulus data from high-density polyethylene (HDPE) samples tested under high-pressure hydrogen are also reported as compared to baseline measurements taken in air.

  18. 2 x 2 Polyethylene Reflected and Moderated Highly Enriched Uranium System with Rhenium

    SciTech Connect (OSTI)

    A. Nichole Ellis; Jesson Hutchinson; John D. Bess; Dmitry N. Polyakov; Evgeny S. Glushkov; Alexey E. Glushkov

    2010-09-01

    The 2 × 2 array HEU-Re experiment was performed on the Planet universal critical assembly machine on November 4th, 2003 at the Los Alamos Critical Experiments Facility (LACEF) at Los Alamos National Laboratory (LANL). For this experiment, there were 10 ½ units, each full unit containing four HEU foils and two rhenium foils. The top unit contained only two HEU foils and two rhenium foils. A total of 42 HEU foils were used for this experiment. Rhenium is a desirable cladding material for space nuclear power applications. This experiment consisted of HEU foils interleaved with rhenium foils and is moderated and reflected by polyethylene plates. A unit consisted of a polyethylene plate, which has a recess for rhenium foils, and four HEU foils in a single layer in the top recess of each polyethylene plate. The Planet universal criticality assembly machine has been previously used in experiments containing HEU foils interspersed with SiO2 (HEU-MET-THERM-001), Al (HEU-MET-THERM-008), MgO (HEU-MET-THERM-009), Gd foils (HEU-MET-THERM-010), 2 × 2 × 26 Al (HEU-MET-THERM-012), Fe (HEU-MET-THERM-013 and HEU-MET-THERM-015), 2 × 2 × 23 SiO2 (HEU-MET-THERM-014), 2 × 2 × 11 hastalloy plates (HEU-MET-THERM-016), and concrete (HEU-MET-THERM-018). The 2 × 2 array of HEU-Re is considered acceptable for use as a benchmark critical experiment.

  19. Mapping the energy and diffusion landscapes of membrane proteins at the cell surface using high-density single-molecule imaging and Bayesian inference: application to the multi-scale dynamics of glycine receptors in the neuronal membrane

    E-Print Network [OSTI]

    Masson, Jean-Baptiste; Salvatico, Charlotte; Renner, Marianne; Specht, Christian G; Triller, Antoine; Dahan, Maxime

    2015-01-01

    Protein mobility is conventionally analyzed in terms of an effective diffusion. Yet, this description often fails to properly distinguish and evaluate the physical parameters (such as the membrane friction) and the biochemical interactions governing the motion. Here, we present a method combining high-density single-molecule imaging and statistical inference to separately map the diffusion and energy landscapes of membrane proteins across the cell surface at ~100 nm resolution (with acquisition of a few minutes). When applying these analytical tools to glycine neurotransmitter receptors (GlyRs) at inhibitory synapses, we find that gephyrin scaffolds act as shallow energy traps (~3 kBT) for GlyRs, with a depth modulated by the biochemical properties of the receptor-gephyrin interaction loop. In turn, the inferred maps can be used to simulate the dynamics of proteins in the membrane, from the level of individual receptors to that of the population, and thereby, to model the stochastic fluctuations of physiologi...

  20. Iron Air collision with high density QCD

    E-Print Network [OSTI]

    Hans-Joachim Drescher

    2006-12-08

    The color glass condensate approach describes successfully heavy ion collisions at RHIC. We investigate Iron-air collisions within this approach and compare results to event generators commonly used in air shower simulations. We estimate uncertainties in the extrapolation to GZK energies and discuss implications for air shower simulations.

  1. High-Density Wireless Neural Recording System

    E-Print Network [OSTI]

    Chae, Moo Sung

    2013-01-01

    wireless FM IC for biopotential recording applications,” inInterference in Biopotential Measurements,” Instrumentation

  2. Pulsed High Density Fusion John Slough#

    E-Print Network [OSTI]

    Washington at Seattle, University of

    configuration allowing for much longer energy confinement lifetimes. For this reason, the FRC plasma need. Essentially, the more massive the system required to confine and heat the fusion plasma, the larger the cost required for fusion gain with low steady state reactors ( being the ratio of the plasma to magnetic energy

  3. The Chemistry of Atherogenic High Density Lipoprotein 

    E-Print Network [OSTI]

    Moore, D'Vesharronne J.

    2012-07-16

    in the mass to charge ratios corresponding to apoC-I peaks in the serum subfractions from all CAD cohort patients. This shifting was not observed in the non-CAD cohort, which displayed apoC-I peaks in accordance with the known mass of this protein...

  4. A flexible high-density sensor network

    E-Print Network [OSTI]

    Mistree, Behram Farrokh Thomas

    2008-01-01

    This thesis explores building and deploying a scalable electronic sensate skin that was designed as a dense sensor network. Our skin is built from small (1" x 1") rigid circuit boards attached to their neighbors with ...

  5. High-Density Wireless Neural Recording System

    E-Print Network [OSTI]

    Chae, Moo Sung

    2013-01-01

    A 4-channel Wearable Wireless Neural Recording System,” inand J.C. Principe, “Wireless, In Vivo Neural Recording usingPower Integrated Circuit for a Wireless 100-Electrode Neural

  6. Durable high-density data storage

    SciTech Connect (OSTI)

    Stutz, R.A.; Lamartine, B.C.

    1996-09-01

    This paper will discuss the Focus Ion Beam (FIB) milling process, media life considerations, and methods of reading the micromilled data. The FIB process for data storage provides a new non-magnetic storage method for archiving large amounts of data. The process stores data on robust materials such as steel, silicon, and gold coated silicon. The storage process was developed to provide a method to insure the long term storage life of data. We estimate the useful life of data written on silicon or gold coated silicon to be a few thousand years. The process uses an ion beam to carve material from the surface much like stone cutting. The deeper information is carved into the media the longer the expected life of the information. The process can read information in three formats: (1) binary at densities of 3.5 Gbits/cm{sup 2}, (2) alphanumeric at optical or non-optical density, and (3) graphical at optical and non-optical density. The formats can be mixed on the same media; and thus it is possible to record, in a human readable format, instructions that can be read using an optical microscope. These instructions provide guidance on reading the higher density information.

  7. The compatibility of various polymeric liner and pipe materials with simulated double-shell slurry feed at 90/degree/C: Hanford Grout Technology Program

    SciTech Connect (OSTI)

    Farnsworth, R.K.; Hymas, C.R.

    1989-08-01

    The purpose of this study was to evaluate the compatibility of various polymeric liner and pipe materials with a low-level radioactive waste slurry called double-shell slurry feed (DSSF). The evaluation was necessary as part of the permitting process authorized by the Resource Conservation and Recovery Act (RCRA), PL-94-580. Materials that were examined included five flexible membrane liners (Hytrel/reg sign/ polyester, polyurethane, 8130 XR5/reg sign/, polypropylene, and high-density polyethylene) and high-density polyethylene (HDPE) pipe. The liner and pipe samples were immersed for 120 days in the synthetic DSSE at 90/degree/C, the maximum expected temperature in the waste disposal scenario. Physical properties of the liner and pipe samples were measured before immersion and every 30 days after immersion, in accordance with EPA Method 9090. In addition, some of the materials were exposed to four different radiation doses after 30 days of immersion. Physical properties of these materials were measured immediately after exposure and after an additional 90 days of immersion to determine each material's response to radiation, and whether radiation exposure affected the chemical compatibility of the material. 20 refs., 41 figs., 13 tabs.

  8. HANFORD SITE LOW EXPOSURE PIPELINE REPAIR USING A NON-METALLIC COMPOSITE SYSTEM

    SciTech Connect (OSTI)

    HUTH RJ

    2009-11-12

    At the Department of Energy, Richland Operations (DOE-RL) Hanford site in eastern Washington, a 350 mm (14 inch) diameter high density polyethylene (HDPE) pump recirculation pipeline failed at a bonded joint adjacent to a radiologically and chemically contaminated groundwater storage basin. The responsible DOE-RL contractor, CH2MHill Plateau Remediation Company, applied a fiberglass reinforced plastic (composite) field repair system to the failed joint. The system was devised specifically for the HDPE pipe repair at the Hanford site, and had not been used on this type of plastic piping previously. This paper introduces the pipe failure scenario, describes the options considered for repair and discusses the ultimate resolution of the problem. The failed pipeline was successfully returned to service with minimal impact on waste water treatment plant operating capacity. Additionally, radiological and chemical exposures to facility personnel were maintained as low as reasonably achievable (ALARA). The repair is considered a success for the near term, and future monitoring will prove whether the repair can be considered for long term service and as a viable alternative for similar piping failures at the Hanford site.

  9. US Department of Transportation (DOT) Spec 7A Type A evaluation document: Spec 17C 55-gal steel drum with RWMC/SWEPP drum venting system carbon filter assembly

    SciTech Connect (OSTI)

    Edling, D.A.

    1986-09-15

    As part of MRC-Mound's responsibility to coordinate DOE Spec 7A Type A Packaging testing, evaluation, and utilization, this document evaluates per 49CFR 173.415(a) the SWEPP packaging system: DOT Spec 17C steel drums - 30, 55 and 83-gal; High Density Polyethylene (HDPE) liners; and SWEPP DVS Filter Assemblies (two configurations) as a US DOT Spec 7A Type A packaging. A variety of Type A performance testing was done on: DOT Spec 17C 55-gal steel drums; DOT Spec 17C 55-gal steel drums with HDPE liners; and DOT Spec 17C 55-gal steel drums with ''Nucfil'' filters as part of MRC-Mound's Type A Packaging Evaluation Program funded by DOE/HQ, DP-4, Security Evaluations. The subject SWEPP packaging incorporates modifications to the ''Nucfil'' filter and installation assembly previously tested in conjunction with the Spec 17C 55-gal drums. Thus, additional testing was required on the new filter installation in order to evaluate the entire packaging system. This document presents the test data to demonstrate the SWEPP packaging system's performance against the DOT 7A Type A requirements.

  10. Calcagno, Lakes, Osswald, Crone Viscoplastic Properties Carl Hanser Verlag Zeitschrift Kunststofftechnik / Journal of Plastics Technology 6 (2010) 5

    E-Print Network [OSTI]

    Lakes, Roderic

    2010-01-01

    of viscoplastic Properties for Polycarbonate, Polypropylene, and High Density Polyethylene The viscoplastic behavior of high density polyethylene, polypropylene, and polycarbonate under uniaxial tensile loading molding were tested at room temperature and constant crosshead speed; testing was conducted in the range

  11. Clinical output factors for carbon-ion beams passing through polyethylene

    E-Print Network [OSTI]

    Kanematsu, Nobuyuki; Ogata, Risa; Himukai, Takeshi

    2013-01-01

    Purpose: A recent study suggested that polyethylene (PE) range compensators would cause extra carbon-ion attenuation by 0.45%/cm due to limitations in water equivalence. The present study aims to assess its influence on tumor dose in carbon-ion radiotherapy. Methods: Carbon-ion radiation was modeled to be composed of primary carbon ions and secondary particles. For these components, tumor dose fraction and relative biological effectiveness (RBE) were estimated at a reference depth in the middle of spread-out Bragg peak. The PE effect was estimated for clinical carbon-ion beams and was partially tested by experiment. The two-component model was integrated into a treatment-planning system, with which the PE effect on tumor dose was investigated in two clinical cases. Results: The fluence and clinical attenuation coefficients for dose decrease per polyethylene thickness were estimated to be 0.1%-0.3%/cm and 0.2%-0.4%/cm, depending on energy and modulation of clinical carbon-ion beams. In the treatment-planning s...

  12. Standard practice for measuring the ultrasonic velocity in polyethylene tank walls using lateral longitudinal (LCR) waves

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2011-01-01

    1.1 This practice covers a procedure for measuring the ultrasonic velocities in the outer wall of polyethylene storage tanks. An angle beam lateral longitudinal (LCR) wave is excited with wedges along a circumferential chord of the tank wall. A digital ultrasonic flaw detector is used with sending-receiving search units in through transmission mode. The observed velocity is temperature corrected and compared to the expected velocity for a new, unexposed sample of material which is the same as the material being evaluated. The difference between the observed and temperature corrected velocities determines the degree of UV exposure of the tank. 1.2 The practice is intended for application to the outer surfaces of the wall of polyethylene tanks. Degradation typically occurs in an outer layer approximately 3.2-mm (0.125-in.) thick. Since the technique does not interrogate the inside wall of the tank, wall thickness is not a consideration other than to be aware of possible guided (Lamb) wave effects or reflection...

  13. Polyethylene-Reflected Arrays of HEU(93.2) Metal Units Separated by Vermiculite

    SciTech Connect (OSTI)

    Mackenzie Gorham; J. Blair Briggs; John D. Bess; Virginia Dean; Davis Reed

    2010-09-01

    This benchmark details the results of an experiment performed in the early 1970s as part of a series testing critical configurations in three dimensional arrays. For this experiment, cylinders of 93.2% enriched uranium metal were arranged in a 2x2x2 array inside of a polyethylene reflector. Layers of vermiculite of varying heights were surrounding each cylinder to achieve criticality variations. A total of four experimental configurations were tested by D.W. Magnuson, and detailed in his experimental report “Critical Three-Dimensional Arrays of Neutron Interacting Units: Part IV. Arrays of U(93.2) Metal Reflected by Concrete and Arrays Separated by Vermiculite and Reflected by Polyethylene.” The benchmark HEU-MET-FAST054 is closely related; the results of both experiments are discussed in the same report (Ref. 1) Closely related work has been recorded in HEU-MET-FAST-053, which is a benchmark evaluation of a different series of three dimensional array experiments with four different moderator materials. HEU-MET-FAST-023 and HEU-MET-FAST-026 are also related because they utilize the same metal cylinders as these experiments.

  14. Macroencapsulation of mixed waste debris at the Hanford Nuclear Reservation -- Final project report by AST Environmental Services, LLC

    SciTech Connect (OSTI)

    Baker, T.L.

    1998-02-25

    This report summarizes the results of a full-scale demonstration of a high density polyethylene (HDPE) package, manufactured by Arrow Construction, Inc. of Montgomery, Alabama. The HDPE package, called ARROW-PAK, was designed and patented by Arrow as both a method to macroencapsulation of radioactively contaminated lead and as an improved form of waste package for treatment and interim and final storage and/or disposal of drums of mixed waste. Mixed waste is waste that is radioactive, and meets the criteria established by the United States Environmental Protection Agency (US EPA) for a hazardous material. Results from previous testing conducted for the Department of Energy (DOE) at the Idaho National Engineering Laboratory in 1994 found that the ARROW-PAK fabrication process produces an HDPE package that passes all helium leak tests and drop tests, and is fabricated with materials impervious to the types of environmental factors encountered during the lifetime of the ARROW-PAK, estimated to be from 100 to 300 years. Arrow Construction, Inc. has successfully completed full-scale demonstration of its ARROW-PAK mixed waste macroencapsulation treatment unit at the DOE Hanford Site. This testing was conducted in accordance with Radiological Work Permit No. T-860, applicable project plans and procedures, and in close consultation with Waste Management Federal Services of Hanford, Inc.`s project management, health and safety, and quality assurance representatives. The ARROW-PAK field demonstration successfully treated 880 drums of mixed waste debris feedstock which were compacted and placed in 149 70-gallon overpack drums prior to macroencapsulation in accordance with the US EPA Alternate Debris Treatment Standards, 40 CFR 268.45. Based on all of the results, the ARROW-PAK process provides an effective treatment, storage and/or disposal option that compares favorably with current mixed waste management practices.

  15. Task 3 - Pyrolysis of Plastic Waste. Semiannual report, November 1, 1996--March 31, 1997

    SciTech Connect (OSTI)

    Ness, Robert O.; Aulich, Ted R.

    1997-12-31

    Over the last 50 years, the U.S. Department of Energy (DOE) has produced a wide variety of radioactive wastes from activities associated with nuclear defense and nuclear power generation. These wastes include low-level radioactive solid wastes, mixed wastes, and transuranic (TRU) wastes. A portion of these wastes consists of high- organic-content materials, such as resins, plastics, and other polymers; synthetic and natural rubbers; cellulosic-based materials; and oils, organic solvents, and chlorinated organic solvents. Many of these wastes contain hazardous and/or pyrophoric materials in addition to radioactive species. Physical forms of the waste include ion-exchange resins used to remove radioactive elements from nuclear reactor cooling water, lab equipment and tools (e.g., measurement and containment vessels, hoses, wrappings, equipment coverings and components, and countertops), oil products (e.g., vacuum pump and lubrication oils), bags and other storage containers (for liquids, solids, and gases), solvents, gloves, lab coats and anti-contamination clothing, and other items. Major polymer and chemical groups found in high-organic-content radioactive wastes include polyvinyl chloride (PVC), low-density polyethylene (LDPE), polypropylene (PP), Teflon(TM), polystyrene (PS), nylon, latex, polyethylene terephthalate (PET), vinyl, high-density polyethylene (HDPE), polycarbonate, nitriles, Tygon(R), butyl, and Tyvec(R).

  16. An innovative high-power constant-current pulsed-arc power-supply for a high-density pulsed-arc-plasma ion-source using a LaB{sub 6}-filament

    SciTech Connect (OSTI)

    Ueno, A.; Oguri, H.; Ikegami, K.; Namekawa, Y.; Ohkoshi, K.; Tokuchi, A.

    2010-02-15

    An innovative high-power constant-current (CC) pulsed-arc (PA) power-supply (PS) indispensable for a high-density PA plasma ion-source using a lanthanum hexaboride (LaB{sub 6}) filament was devised by combining a constant-voltage (CV) PA-PS, which is composed of an insulated gate bipolar transistor (IGBT) switch, a CV direct-current (dc) PS and a 270 mF capacitor with a CC-PA-PS, which is composed of an IGBT-switch, a CC-dc-PS and a 400 {mu}H inductor, through the inductor. The hybrid-CC-PA-PS succeeded in producing a flat arc-pulse with a peak power of 56 kW (400 Ax140 V) and a duty factor of more than 1.5%(600 {mu}sx25 Hz) for Japan Proton Accelerator Research Complex (J-PARC) H{sup -} ion-source stably. It also succeeded in shortening the 99% rising-time of the arc-pulse-current to about 20 {mu}s and tilting up or down the arc-pulse-current arbitrarily and almost linearly by changing the setting voltage of its CV-dc-PS.

  17. 1D-to-3D transition of photon heat conduction in polyethylene using molecular dynamics simulations

    E-Print Network [OSTI]

    Henry, Asegun Sekou Famake

    2009-01-01

    Experiments have demonstrated that the mechanical stretching of bulk polyethylene can increase its thermal conductivity by more than two orders of magnitude, from 0.35 W/mK to over 40W/mK, which is comparable to steel. ...

  18. Nanostructure and Shape Control in Polymer-Ceramic Hybrids from Poly(ethylene oxide)-block-Poly(hexyl

    E-Print Network [OSTI]

    Gruner, Sol M.

    with ceramic precursors in sol-gel processes to obtain arrays of nanocomposite morphologies. These composites#12;Nanostructure and Shape Control in Polymer-Ceramic Hybrids from Poly(ethylene oxide, lamellae, and organic cylinders in an inorganic matrix, are obtained confirmed by a combination of small

  19. Local environment in poly(ethylene oxide)-zinc bromide complexes

    SciTech Connect (OSTI)

    Chintipalli, S.; Frech, R.; Grady, B.

    1996-12-31

    This study examines atomic-level local environments in Poly(ethylene oxide)-zinc bromide+lithium bromide (PEO){sub 20}[(ZnBr{sub 2}){sub 1-x} (LiBr){sub x}] complexes using Raman spectroscopy and x-ray absorption spectroscopy (XAS). Specific features in the Raman spectra were used to show that the zinc bromide species changes from ZnBr{sub 2} to ZnBr{sub 3}{sup -} to ZnBr{sub 4}{sup 2-} when x is varied from 0 to 0.8. XAS showed a similar change in oxygen coordination number from 4 to 0 when x is varied from 0 to 0.8. This study shows that lithium atoms displace zinc atoms from ether oxygen speciation indicating that lithium coordination to ether oxygens is thermodynamically favored. The effect of adding polar plasticizers is also discussed.

  20. Investigation of the suppression effect of polyethylene glycol on copper electroplating by electrochemical impedance spectroscopy

    SciTech Connect (OSTI)

    Hung, C.-C.; Lee, W.-H.; Wang, Y.-L.; Chan, D.-Y.; Hwang, G.-J. [Department of Electrical Engineering, National Cheng Kung University, Tainan 701, Taiwan (China); Department of Electrical Engineering, National Chiayi University, Chiayi, Taiwan (China); College of Science and Engineering, National University of Tainan, Tainan 700, Taiwan (China)

    2008-09-15

    Polyethylene glycol (PEG) is an additive that is commonly used as a suppressor in the semiconductor copper (Cu)-electroplating process. In this study, electrochemical impedance spectroscopy (EIS) was used to analyze the electrochemical behavior of PEG in the Cu-electroplating process. Polarization analysis, cyclic-voltammetry stripping, and cell voltage versus plating time were examined to clarify the suppression behavior of PEG. The equivalent circuit simulated from the EIS data shows that PEG inhibited the Cu-electroplating rate by increasing the charge-transfer resistance as well as the resistance of the adsorption layer. The presence of a large inductance demonstrated the strong adsorption of cuprous-PEG-chloride complexes on the Cu surface during the Cu-electroplating process. Increasing the PEG concentration appears to increase the resistances of charge transfer, the adsorption layer, and the inductance of the electroplating system.

  1. Production and characterization of a composite insulation material from waste polyethylene teraphtalates

    SciTech Connect (OSTI)

    Kurtulmus, Erhan; Karaboyac?, Mustafa; Yigitarslan, Sibel

    2013-12-16

    The pollution of polyethylene teraphtalate (PET) is in huge amounts due to the most widely usage as a packaging material in several industries. Regional pumice has several desirable characteristics such as porous structure, low-cost and light-weight. Considering the requirements approved by the Ministry of Public Works on isolation, composite insulation material consisting of PET and pumice was studied. Sheets of composites differing both in particle size of pumice and composition of polymer were produced by hot-molding technique. Characterization of new composite material was achieved by measuring its weight, density, flammability, endurance against both to common acids and bases, and to a force applied, heat insulation and water adsorption capacity. The results of the study showed that produced composite material is an alternative building material due to its desirable characteristics; low weight, capability of low heat conduction.

  2. Ferromagnetism of manganese-doped indium tin oxide films deposited on polyethylene naphthalate substrates

    SciTech Connect (OSTI)

    Nakamura, Toshihiro; Isozaki, Shinichi; Tanabe, Kohei; Tachibana, Kunihide

    2009-04-01

    Mn-doped indium tin oxide (ITO) films were deposited on polyethylene naphthalate (PEN) substrates using radio-frequency magnetron sputtering. The magnetic, electrical, and optical properties of the films deposited on PEN substrates were investigated by comparing with the properties of films grown on glass substrates at the same growth conditions. Thin films on PEN substrates exhibited low electrical resistivity of the order of 10{sup -4} {omega} cm and high optical transmittance between 75% and 90% in the visible region. Ferromagnetic hysteresis loops were observed at room temperature for the samples grown on PEN substrates. Mn-doped ITO films can be one of the most promising candidates of transparent ferromagnetic materials for flexible spintronic devices.

  3. Microscopic Description of Entanglements in Polyethylene Networks and Melts: Strong, Weak, Pairwise, and Collective Attributes

    E-Print Network [OSTI]

    Anogiannakis, Stefanos D; Theodorou, Doros N

    2012-01-01

    We present atomistic molecular dynamics simulations of two Polyethylene systems where all entanglements are trapped: a perfect network, and a melt with grafted chain ends. We examine microscopically at what level topological constraints can be considered as a collective entanglement effect, as in tube model theories, or as certain pairwise uncrossability interactions, as in slip-link models. A pairwise parameter, which varies between these limiting cases, shows that, for the systems studied, the character of the entanglement environment is more pairwise than collective. We employ a novel methodology, which analyzes entanglement constraints into a complete set of pairwise interactions, similar to slip links. Entanglement confinement is assembled by a plethora of links, with a spectrum of confinement strengths, from strong to weak. The strength of interactions is quantified through a link `persistence', which is the fraction of time for which the links are active. By weighting links according to their strength,...

  4. Microphase separated structures in the solid and molten states of double-crystal graft copolymers of polyethylene and poly(ethylene oxide)

    SciTech Connect (OSTI)

    Mark, P.R.; Murthy, N.S.; Weigand, S.; Breitenkamp, K.; Kade, M.; Emrick, T. (Vermont); (NWU); (UMASS, Amherst)

    2008-08-26

    Transitions from one microphase separated structure in the solid state to a different one in the molten state in polyethylene-graft-poly(ethylene oxide) copolymers, PE-g-PEO, were investigated by variable temperature X-ray scattering measurements and thermal analyses. Small-angle X-ray scattering patterns from polymers with PEO grafts with 25, 50 and 100 ethylene oxide (EO) units show that the polymer passes through three distinct structures at {approx}10 nm length scales with increase in temperature (T): lamellar structures of PE and PEO at T < T{sub m}{sup PEO}, PE lamellae surrounded by molten PEO at T{sub m}{sup PEO} < T < T{sub m}{sup PE}, and microphase separated structures at T > T{sub m}{sup PE} when both PE and PEO are molten (T{sub m} refers to the melting temperature). These phase transformations also occur during cooling but with hysteresis. Crystalline phases of PEO side chains and PE main chains could be identified in the wide-angle X-ray diffraction profiles indicating that the PE backbone and PEO grafts crystallize into separate domains, especially with longer grafted chains (50 and 100 units). At EO segment lengths >50, PEO shows the expected increase in melting and crystallization temperatures with the increase in the grafted chain length. PE does not affect T{sub m}{sup PEO} but does decrease the onset of crystallization upon cooling. PEO grafts result in fractionation of PE, decrease the melting point of PE and increase the undercooling for the onset of crystallization of PE.

  5. Aqueous Biphasic Systems Based on Salting-Out Polyethylene Glycol or Ionic Solutions: Strategies for Actinide or Fission Product Separations

    SciTech Connect (OSTI)

    Rogers, Robin D.; Gutowski, Keith E.; Griffin, Scott T.; Holbrey, John D.

    2004-03-29

    Aqueous biphasic systems can be formed by salting-out (with kosmotropic, waterstructuring salts) water soluble polymers (e.g., polyethylene glycol) or aqueous solutions of a wide range of hydrophilic ionic liquids based on imidazolium, pyridinium, phosphonium and ammonium cations. The use of these novel liquid/liquid biphases for separation of actinides or other fission products associated with nuclear wastes (e.g., pertechnetate salts) has been demonstrated and will be described in this presentation.

  6. Development of ultra-thin polyethylene balloons for high altitude research upto mesosphere

    E-Print Network [OSTI]

    Kumar, B Suneel; Ojha, D K; Peter, G Stalin; Vasudevan, R; Anand, D; Kulkarni, P M; Reddy, V Anmi; Rao, T V; Sreenivasan, S

    2014-01-01

    Ever since its inception four decades back, Balloon Facility of Tata Institute of Fundamental Research (TIFR), Hyderabad has been functioning with the needs of its user scientists at its focus. During the early nineties, when the X-ray astronomy group at TIFR expressed the need for balloons capable of carrying the X-ray telescopes to altitudes up to 42 km, the balloon group initiated research and development work on indigenous balloon grade films in various thickness not only for the main experiment but also in parallel, took up the development of thin films in thickness range 5 to 6 microns for fabrication of sounding balloons required for probing the stratosphere up to 42 km as the regular 2000 grams rubber balloon ascents could not reach altitudes higher than 38 km. By the year 1999, total indigenisation of sounding balloon manufacture was accomplished. The work on balloon grade ultra-thin polyethylene film in thickness range 2.8 to 3.8 microns for fabrication of balloons capable of penetrating mesosphere ...

  7. Microscopic Description of Entanglements in Polyethylene Networks and Melts: Strong, Weak, Pairwise, and Collective Attributes

    E-Print Network [OSTI]

    Stefanos D. Anogiannakis; Christos Tzoumanekas; Doros N. Theodorou

    2013-01-30

    We present atomistic molecular dynamics simulations of two Polyethylene systems where all entanglements are trapped: a perfect network, and a melt with grafted chain ends. We examine microscopically at what level topological constraints can be considered as a collective entanglement effect, as in tube model theories, or as certain pairwise uncrossability interactions, as in slip-link models. A pairwise parameter, which varies between these limiting cases, shows that, for the systems studied, the character of the entanglement environment is more pairwise than collective. We employ a novel methodology, which analyzes entanglement constraints into a complete set of pairwise interactions, similar to slip links. Entanglement confinement is assembled by a plethora of links, with a spectrum of confinement strengths, from strong to weak. The strength of interactions is quantified through a link `persistence', which is the fraction of time for which the links are active. By weighting links according to their strength, we show that confinement is imposed mainly by the strong ones, and that the weak, trapped, uncrossability interactions cannot contribute to the low frequency modulus of an elastomer, or the plateau modulus of a melt. A self-consistent scheme for mapping topological constraints to specific, strong binary links, according to a given entanglement density, is proposed and validated. Our results demonstrate that slip links can be viewed as the strongest pairwise interactions of a collective entanglement environment. The methodology developed provides a basis for bridging the gap between atomistic simulations and mesoscopic slip link models.

  8. Measurement and Analysis of Fission Rates in a Spherical Mockup of Uranium and Polyethylene

    E-Print Network [OSTI]

    Tong-Hua, Zhu; Xin-Xin, Lu; Rong, Liu; Zi-Jie, Han; Li, Jiang; Mei, Wang

    2013-01-01

    Measurements of the reaction rate distribution were carried out using two kinds of Plate Micro Fission Chamber(PMFC). The first is a depleted uranium chamber and the second an enriched uranium chamber. The material in the depleted uranium chamber is strictly the same as the material in the uranium assembly. With the equation solution to conduct the isotope contribution correction, the fission rate of 238U and 235U were obtained from the fission rate of depleted uranium and enriched uranium. And then, the fission count of 238U and 235U in an individual uranium shell was obtained. In this work, MCNP5 and continuous energy cross sections ENDF/BV.0 were used for the analysis of fission rate distribution and fission count. The calculated results were compared with the experimental ones. The calculation of fission rate of DU and EU were found to agree with the measured ones within 10% except at the positions in polyethylene region and the two positions near the outer surface. Beacause the fission chamber was not co...

  9. Radiation damage of polyethylene exposed in the stratosphere at an altitude of 40 km

    E-Print Network [OSTI]

    Kondyurin, Alexey; Bilek, Marcela

    2011-01-01

    Low Density Polyethylene (LDPE) films were exposed at an altitude of 40 km over a 3 day NASA stratospheric balloon mission from Alice Springs, Australia. The radiation damage, oxidation and nitration in the LDPE films exposed in stratosphere were measured using ESR, FTIR and XPS spectroscopy. The results were compared with those from samples stored on the ground and exposed in a laboratory plasma. The types of free radicals, unsaturated hydrocarbon groups, oxygen-containing and nitrogen-containing groups in LDPE film exposed in the stratosphere and at the Earth's surface are different. The radiation damage in films exposed in the stratosphere are observed in the entire film due to the penetration of high energy cosmic rays through their thickness, while the radiation damage in films exposed on the ground is caused by sunlight penetrating into only a thin surface layer. A similarly thin layer of the film is damaged by exposure to plasma due to the low energy of the plasma particles. The intensity of oxidation ...

  10. Effects of ionic liquids on cation dynamics in amorphous polyethylene oxide electrolytes

    SciTech Connect (OSTI)

    Chattoraj, Joyjit, E-mail: jchat-01@uni-muenster.de; Diddens, Diddo; Heuer, Andreas [Institut für Physikalische Chemie, Westfälische Wilhelms-Universität Münster, Corrensstrasse 28/30, D-48149 Münster (Germany)] [Institut für Physikalische Chemie, Westfälische Wilhelms-Universität Münster, Corrensstrasse 28/30, D-48149 Münster (Germany)

    2014-01-14

    We perform extensive molecular dynamics simulations of a poly(ethylene oxide)-based polymer electrolyte material containing lithium bis(trifluoromethanesulfonyl)imide salt for a wide temperature regime above and below the experimental crystallization temperature with and without N-methyl-N-propylpyrrolidinium bis(trifluoromethanesulfonyl)imide ionic liquid (IL). The impact of the IL-concentration on the cation dynamics is studied. The increase of the cation mobility upon addition of IL is significant but temperature-independent. This can be related to distinct variations of the underlying transport properties as expressed within the previously introduced transport model of polymer electrolytes. Even for the largest IL concentration the transport model perfectly predicts the non-trivial time-dependence of the cationic mean square displacement for all temperatures. Finally, we compare our numerical and theoretical findings with the results of recent nuclear magnetic resonance experiments. In this way we can exclusively relate the strong experimentally observed dependence of the low-temperature Li-diffusivity on the IL concentration to the impact of IL on crystallization.

  11. Effectiveness of organoclays as compatibilizers for multiphase polymer blends – A sustainable route for the mechanical recycling of co-mingled plastics

    SciTech Connect (OSTI)

    Causa, Andrea; Acierno, Domenico; Filippone, Giovanni [Dipartimento di Ingegneria Chimica, dei Materiali e della Produzione Industriale, Universitą di Napoli Federico II, Piazzale V. Tecchio, 80, 80125 Napoli (Italy); Mistretta, Maria Chiara [Dipartimento di Ingegneria Civile, Ambientale, Aerospaziale, dei Materiali, Universitą di Palermo, Viale delle Scienze, ed. 6, 90128 Palermo (Italy)

    2014-05-15

    We prepare and characterize multiphase systems in which small amounts of recycled polymer, namely polyethylene terephtalate (PET) ground from waste bottles, are dispersed in a co-continuous blend of high-density polyethylene (HDPE) and polypropylene (PP). Some of such ternary systems are also filled with plate-like clay nanoparticles with different polarities, in order to assess their influence on the morphology and mechanical behaviour of the blends. On the basis of preliminary wettability considerations and inspections by means of scanning electron microscopy (SEM), the PET is found to preferentially locate within the PP phase. Such a positioning is desirable in order to minimize the presence of multiple interfaces, which is one of the major issues in the recycling process of co-mingles plastics. By means of SEM, dynamic-mechanical analysis and tensile tests we show that the addition of a filler with low polarity, which locates at the PET-matrix interface, has relevant implications on the structure and properties of the ternary systems, refining their morphology at the micro-scale and enhancing their high-temperature mechanical behaviour.

  12. On the "viscosity maximum" during the uniaxial extension of a low density polyethylene

    E-Print Network [OSTI]

    Teodor I. Burghelea; Zdenek Stary; Helmut Muenstedt

    2010-01-13

    An experimental investigation of the viscosity overshoot phenomenon observed during uniaxial extension of a low density polyethylene is pre- sented. For this purpose, traditional integral viscosity measurements on a Muenstedt type extensional rheometer are combined with local mea- surements based on the in-situ visualization of the sample under exten- sion. For elongational experiments at constant strain rates within a wide range of Weissenberg numbers (Wi), three distinct deformation regimes are identified. Corresponding to low values of Wi (regime I), the tensile stress displays a broad maximum. This maximum can be explained by simple mathematical arguments as a result of low deformation rates and it should not be confused with the viscosity overshoot phenomenon. Corre- sponding to intermediate values of Wi (regime II), a local maximum of the integral extensional viscosity is systematically observed. However, within this regime, the local viscosity measurements reveal no maximum, but a plateau. Careful inspection of the images of samples within this regime shows that, corresponding to the maximum of the integral viscosity, sec- ondary necks develop along the sample. The emergence of a maximum of the integral elongational viscosity is thus related to the distinct in- homogeneity of deformation states and is not related to the rheological properties of the material. In the fast stretching limit (high Wi, regime III), the overall geometric uniformity of the sample is well preserved, no secondary necks are observed and both the integral and the local transient elongational viscosity show no maximum. A detailed comparison of the experimental findings with results from literature is presented.

  13. Modeling and simulation of Li-ion conduction in poly(ethylene oxide)

    SciTech Connect (OSTI)

    Gitelman, L. [Faculty of Applied Mathematics, Technion, Haifa 32000 (Israel); Israeli, M. [Faculty of Computer Science, Technion, Haifa 32000 (Israel); Averbuch, A. [School of Computer Science, Tel Aviv University, Tel Aviv 69978 (Israel)], E-mail: amir@math.tau.ac.il; Nathan, M. [School of Electrical Engineering, Tel Aviv University, Tel Aviv 69978 (Israel); Schuss, Z. [School of Mathematical Sciences, Department of Applied Mathematics, Tel Aviv University, Tel Aviv 69978 (Israel); Golodnitsky, D. [School of Chemistry, Tel Aviv University, Tel Aviv 69978 (Israel)

    2007-12-10

    Polyethylene oxide (PEO) containing a lithium salt (e.g., LiI) serves as a solid polymer electrolyte (SPE) in thin-film batteries and its ionic conductivity is a key parameter of their performance. We model and simulate Li{sup +} ion conduction in a single PEO molecule. Our simplified stochastic model of ionic motion is based on an analogy between protein channels of biological membranes that conduct Na{sup +}, K{sup +}, and other ions, and the PEO helical chain that conducts Li{sup +} ions. In contrast with protein channels and salt solutions, the PEO is both the channel and the solvent for the lithium salt (e.g., LiI). The mobile ions are treated as charged spherical Brownian particles. We simulate Smoluchowski dynamics in channels with a radius of ca. 0.1 nm and study the effect of stretching and temperature on ion conductivity. We assume that each helix (molecule) forms a random angle with the axis between these electrodes and the polymeric film is composed of many uniformly distributed oriented boxes that include molecules with the same direction. We further assume that mechanical stretching aligns the molecular structures in each box along the axis of stretching (intra-box alignment). Our model thus predicts the PEO conductivity as a function of the stretching, the salt concentration and the temperature. The computed enhancement of the ionic conductivity in the stretch direction is in good agreement with experimental results. The simulation results are also in qualitative agreement with recent theoretical and experimental results.

  14. Self-Consistent-Field Study of Adsorption and Desorption Kinetics of Polyethylene Melts on Graphite and Comparison with Atomistic Simulations

    E-Print Network [OSTI]

    Doros N. Theodorou; Georgios G. Vogiatzis; Georgios Kritikos

    2015-02-20

    A method is formulated, based on combining self-consistent field theory with dynamically corrected transition state theory, for estimating the rates of adsorption and desorption of end-constrained chains (e.g. by crosslinks or entanglements) from a polymer melt onto a solid substrate. This approach is tested on a polyethylene/graphite system, where the whole methodology is parametrized by atomistically detailed molecular simulations. For short-chain melts, which can still be addressed by molecular dynamics simulations with reasonable computational resources, the self-consistent field approach gives predictions of the adsorption and desorption rate constants which are gratifyingly close to molecular dynamics estimates.

  15. The effect of clay catalyst on the chemical composition of bio-oil obtained by co-pyrolysis of cellulose and polyethylene

    SciTech Connect (OSTI)

    Solak, Agnieszka; Rutkowski, Piotr

    2014-02-15

    Highlights: • Non-catalytic and catalytic fast pyrolysis of cellulose/polyethylene blend was carried out in a laboratory scale reactor. • Optimization of process temperature was done. • Optimization of clay catalyst type and amount for co-pyrolysis of cellulose and polyethylene was done. • The product yields and the chemical composition of bio-oil was investigated. - Abstract: Cellulose/polyethylene (CPE) mixture 3:1, w/w with and without three clay catalysts (K10 – montmorillonite K10, KSF – montmorillonite KSF, B – Bentonite) addition were subjected to pyrolysis at temperatures 400, 450 and 500 °C with heating rate of 100 °C/s to produce bio-oil with high yield. The pyrolytic oil yield was in the range of 41.3–79.5 wt% depending on the temperature, the type and the amount of catalyst. The non-catalytic fast pyrolysis at 500 °C gives the highest yield of bio-oil (79.5 wt%). The higher temperature of catalytic pyrolysis of cellulose/polyethylene mixture the higher yield of bio-oil is. Contrarily, increasing amount of montmorillonite results in significant, almost linear decrease in bio-oil yield followed by a significant increase of gas yield. The addition of clay catalysts to CPE mixture has a various influence on the distribution of bio-oil components. The addition of montmorillonite K10 to cellulose/polyethylene mixture promotes the deepest conversion of polyethylene and cellulose. Additionally, more saturated than unsaturated hydrocarbons are present in resultant bio-oils. The proportion of liquid hydrocarbons is the highest when a montmorillonite K10 is acting as a catalyst.

  16. Low-temperature atomic layer deposition of Al{sub 2}O{sub 3} on blown polyethylene films with plasma-treated surfaces

    SciTech Connect (OSTI)

    Beom Lee, Gyeong; Sik Son, Kyung; Won Park, Suk; Hyung Shim, Joon; Choi, Byoung-Ho

    2013-01-15

    In this study, a layer of Al{sub 2}O{sub 3} was deposited on blown polyethylene films by atomic layer deposition (ALD) at low temperatures, and the surface characteristics of these Al{sub 2}O{sub 3}-coated blown polyethylene films were analyzed. In order to examine the effects of the plasma treatment of the surfaces of the blown polyethylene films on the properties of the films, both untreated and plasma-treated film samples were prepared under various processing conditions. The surface characteristics of the samples were determined by x-ray photoelectron spectroscopy, as well as by measuring their surface contact angles. It was confirmed that the surfaces of the plasma-treated samples contained a hydroxyl group, which helped the precursor and the polyethylene substrate to bind. ALD of Al{sub 2}O{sub 3} was performed through sequential exposures to trimethylaluminum and H{sub 2}O at 60 Degree-Sign C. The surface morphologies of the Al{sub 2}O{sub 3}-coated blown polyethylene films were observed using atomic force microscopy and scanning electron microscopy/energy-dispersive x-ray spectroscopy. Further, it was confirmed that after ALD, the surface of the plasma-treated film was covered with alumina grains more uniformly than was the case for the surface of the untreated polymer film. It was also confirmed via the focused ion beam technique that the layer Al{sub 2}O{sub 3} conformed to the surface of the blown polyethylene film.

  17. Scattering of 64 eV to 3 keV Neutrons from Polyethylene and Graphite and the Coherence Length Problem

    E-Print Network [OSTI]

    Danon, Yaron

    Scattering of 64 eV to 3 keV Neutrons from Polyethylene and Graphite and the Coherence Length 12180, USA (Received 31 August 2005; published 8 February 2006) We measured the neutron scattering by the neutron coherence length. The scattered intensity ratios were found to conform to conventional

  18. Conductivity and optical band gaps of polyethylene oxide doped with Li{sub 2}SO{sub 4} salt

    SciTech Connect (OSTI)

    Chapi, Sharanappa, E-mail: dehu2010@gmail.com; Raghu, S., E-mail: dehu2010@gmail.com; Subramanya, K., E-mail: dehu2010@gmail.com; Archana, K., E-mail: dehu2010@gmail.com; Mini, V., E-mail: dehu2010@gmail.com; Devendrappa, H., E-mail: dehu2010@gmail.com [Dept. of Physics, Mangalore University, Mangalagangothri-574199 (India)

    2014-04-24

    The conductivity and optical properties of Li{sub 2}SO{sub 4} doped polyethylene oxide (PEO) films were studied. The polymer electrolyte films are prepared using solution casting technique. The material phase change was confirmed by X-ray diffraction (XRD) technique. Optical absorption study was conducted using UV- Vis. Spectroscopy in the wavelength range 190–1100nm on pure and doped PEO films. The direct and indirect optical band gaps were found decreased from 5.81–4.51eV and 4.84–3.43eV respectively with increasing the Li{sub 2}SO{sub 4}. The conductivity found to increases with increasing the dopant concentration due to strong hopping mechanism at room temperature.

  19. Neutron Reference Benchmark Field Specifications: ACRR Polyethylene-Lead-Graphite (PLG) Bucket Environment (ACRR-PLG-CC-32-CL).

    SciTech Connect (OSTI)

    Vega, Richard Manuel; Parm, Edward J.; Griffin, Patrick J.; Vehar, David W.

    2015-07-01

    This report was put together to support the International Atomic Energy Agency (IAEA) REAL- 2016 activity to validate the dosimetry community’s ability to use a consistent set of activation data and to derive consistent spectral characterizations. The report captures details of integral measurements taken in the Annular Core Research Reactor (ACRR) central cavity with the Polyethylene-Lead-Graphite (PLG) bucket, reference neutron benchmark field. The field is described and an “a priori” calculated neutron spectrum is reported, based on MCNP6 calculations, and a subject matter expert (SME) based covariance matrix is given for this “a priori” spectrum. The results of 37 integral dosimetry measurements in the neutron field are reported.

  20. The Advantages of HDPE Piping & Vaults in the

    E-Print Network [OSTI]

    First in the world to produce 1600mm PE pipes Production of district heating pipes starts 1984 & telecom · Waste water treatment · House drainage · Under ground ventilation · Renovation · District heating & cooling · Special constructions · Marine intakes and outfalls · Welding, extrusion and blown

  1. Plastic wastes as modifiers of the thermoplasticity of coal

    SciTech Connect (OSTI)

    M.A. Diez; C. Barriocanal; R. Alvarez [Instituto Nacional del Carbon (INCAR), Oviedo (Spain)

    2005-12-01

    Plastic waste recycling represents a major challenge in environmental protection with different routes now available for dealing with mechanical, chemical, and energy recycling. New concepts in plastic waste recycling have emerged so that now such wastes can be used to replace fossil fuels, either as an energy source or as a secondary raw material. Our objective is to explore the modification of the thermoplastic properties of coal in order to assess the possibility of adding plastic waste to coal for the production of metallurgical coke. Two bituminous coals of different rank and thermoplastic properties were used as a base component of blends with plastic wastes such as high-density polyethylene (HDPE), low-density polyethylene (LDPE), polypropylene (PP), polystyrene (PS), poly(ethylene terephthalate) (PET), and acrilonitrile-butadiene-styrene copolymer (ABS). In all cases, the addition of plastic waste led to a reduction in Gieseler maximum fluidity, the extent of the reduction depending on the fluidity of the base coal, and the amount, the molecular structure, and the thermal behavior of the polymer. As a consequence, the amount of volatile matter released by the plastic waste before, during, and after the maximum fluidity of the coal and the hydrogen-donor and hydrogen-acceptor capacities of the polymer were concluded to be key factors in influencing the extent of the reduction in fluidity and the development of anisotropic carbons. The incorporation of the plastic to the carbon matrix was clearly established in semicokes produced from blends of a high-fluid coal and the plastic tested by SEM examination. 42 refs., 10 figs., 7 tabs.

  2. Polyethylene passive samplers for measuring hydrophobic organic chemical concentrations in sediment porewaters and their use in predicting bioaccumulation in soft-shell clams (Mya arenaria) from sites near Boston, MA

    E-Print Network [OSTI]

    Fernandez, Loretta A. (Loretta Ana)

    2010-01-01

    In order to determine the hazards posed by hydrophobic organic compounds (HOCs) in sediment beds, the following areas of research were explored: (1) the use of polyethylene (PE) sheets as passive sampling devices in ...

  3. ARRA NEWS UPDATE_2-26-10.indd

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    includes installation of 65 road crossings that will protect high density polyethylene piping as it connects extraction and injection wells to the 200 West Groundwater...

  4. Anomalous specific heat in high-density QED and QCD

    E-Print Network [OSTI]

    A. Ipp; A. Gerhold; A. Rebhan

    2003-09-22

    Long-range quasi-static gauge-boson interactions lead to anomalous (non-Fermi-liquid) behavior of the specific heat in the low-temperature limit of an electron or quark gas with a leading $T\\ln T^{-1}$ term. We obtain perturbative results beyond the leading log approximation and find that dynamical screening gives rise to a low-temperature series involving also anomalous fractional powers $T^{(3+2n)/3}$. We determine their coefficients in perturbation theory up to and including order $T^{7/3}$ and compare with exact numerical results obtained in the large-$N_f$ limit of QED and QCD.

  5. High-density nanopore array for selective biomolecule transport.

    SciTech Connect (OSTI)

    Patel, Kamlesh D.

    2011-11-01

    Development of sophisticated tools capable of manipulating molecules at their own length scale enables new methods for chemical synthesis and detection. Although nanoscale devices have been developed to perform individual tasks, little work has been done on developing a truly scalable platform: a system that combines multiple components for sequential processing, as well as simultaneously processing and identifying the millions of potential species that may be present in a biological sample. The development of a scalable micro-nanofluidic device is limited in part by the ability to combine different materials (polymers, metals, semiconductors) onto a single chip, and the challenges with locally controlling the chemical, electrical, and mechanical properties within a micro or nanochannel. We have developed a unique construct known as a molecular gate: a multilayered polymer based device that combines microscale fluid channels with nanofluidic interconnects. Molecular gates have been demonstrated to selectively transport molecules between channels based on size or charge. In order to fully utilize these structures, we need to develop methods to actively control transport and identify species inside a nanopore. While previous work has been limited to creating electrical connections off-channel or metallizing the entire nanopore wall, we now have the ability to create multiple, separate conductive connections at the interior surface of a nanopore. These interior electrodes will be used for direct sensing of biological molecules, probing the electrical potential and charge distribution at the surface, and to actively turn on and off electrically driven transport of molecules through nanopores.

  6. Wireless Geophone Networks (WGN) for high density land acquisitions*

    E-Print Network [OSTI]

    Savazzi, Stefano

    on the grid size and the particular acquisition geometry (e.g., the intervals among two receivers is limited as for multiple micro-line based geometries in figure 1. These limiting constraints suggest the adoption of an acquisition system that do not rely on cables. Receiver line Sub-surface Storage UnitShot Point Geophone Sub

  7. Virtual electrodes for high-density electrode arrays

    DOE Patents [OSTI]

    Cela, Carlos J.; Lazzi, Gianluca

    2015-10-13

    The present embodiments are directed to implantable electrode arrays having virtual electrodes. The virtual electrodes may improve the resolution of the implantable electrode array without the burden of corresponding complexity of electronic circuitry and wiring. In a particular embodiment, a virtual electrode may include one or more passive elements to help steer current to a specific location between the active electrodes. For example, a passive element may be a metalized layer on a substrate that is adjacent to, but not directly connected to an active electrode. In certain embodiments, an active electrode may be directly coupled to a power source via a conductive connection. Beneficially, the passive elements may help to increase the overall resolution of the implantable array by providing additional stimulation points without requiring additional wiring or driver circuitry for the passive elements.

  8. Note: High density pulsed molecular beam for cold ion chemistry

    SciTech Connect (OSTI)

    Kokish, M. G.; Rajagopal, V.; Marler, J. P.; Odom, B. C.

    2014-08-15

    A recent expansion of cold and ultracold molecule applications has led to renewed focus on molecular species preparation under ultrahigh vacuum conditions. Meanwhile, molecular beams have been used to study gas phase chemical reactions for decades. In this paper, we describe an apparatus that uses pulsed molecular beam technology to achieve high local gas densities, leading to faster reaction rates with cold trapped ions. We characterize the beam's spatial profile using the trapped ions themselves. This apparatus could be used for preparation of molecular species by reactions requiring excitation of trapped ion precursors to states with short lifetimes or for obtaining a high reaction rate with minimal increase of background chamber pressure.

  9. Photon and dilepton emission rates from high density quark matter 

    E-Print Network [OSTI]

    Jaikumar, P.; Rapp, Ralf; Zahed, I.

    2002-01-01

    Methane conversion to heavier hydrocarbons was studied using electrical furnaces and a plasma apparatus. The experiments were performed with pure methane for the electrical furnace experiments while pure methane and additions such as hydrogen...

  10. Transport coefficients of soft sphere fluids at high densities

    E-Print Network [OSTI]

    Yu. D. Fomin; V. V. Brazhkin; V. N. Ryzhov

    2010-03-19

    Molecular dynamics computer simulation has been used to compute the self-diffusion coefficient, and shear viscosity of soft-sphere fluids, in which the particles interact through the soft-sphere or inverse power pair potential. The calculations have been made along the melting line in a wide range of pressures and temperatures. The validity of scaling relations for thermodynamic parameters and kinetic coefficients was checked. It was shown that the Stokes-Einstein relationship is obeyed if the Barker diameter is used as a characteristic length scale. It was also shown that the viscosity is non-monotonic along the isochores as predicted by Ya. Rosenfeld. It was shown that the viscosity is strongly growing along the melting line, however, this increase does not stimulate the glass transition because the relaxation time is decreasing.

  11. HIGH-DENSITY, BIO-COMPATIBLE, AND HERMETIC ELECTRICAL FEEDTHROUGHS...

    Office of Scientific and Technical Information (OSTI)

    mum pitch were conformally metallized and lithographically patterned. Hermetic electrical feedthroughs were formed by extruding metal studbumps partially through the vias....

  12. Method of fabricating high-density hermetic electrical feedthroughs

    DOE Patents [OSTI]

    Shah, Kedar G.; Pannu, Satinderpall S.; Delima, Terri L.

    2015-06-02

    A method of fabricating electrical feedthroughs selectively removes substrate material from a first side of an electrically conductive substrate (e.g. a bio-compatible metal) to form an array of electrically conductive posts in a substrate cavity. An electrically insulating material (e.g. a bio-compatible sealing glass) is then flowed to fill the substrate cavity and surround each post, and solidified. The solidified insulating material is then exposed from an opposite second side of the substrate so that each post is electrically isolated from each other as well as the bulk substrate. In this manner a hermetic electrically conductive feedthrough construction is formed having an array of electrical feedthroughs extending between the first and second sides of the substrate from which it was formed.

  13. The Nuclear Equation of State at high densities

    E-Print Network [OSTI]

    Christian Fuchs

    2006-10-10

    Ab inito calculations for the nuclear many-body problem make predictions for the density and isospin dependence of the nuclear equation-of-state (EOS) far away from the saturation point of nuclear matter. I compare predictions from microscopic and phenomenological approaches. Constraints on the EOS derived from heavy ion reactions, in particular from subthreshold kaon production, as well as constraints from neutron stars are discussed.

  14. LANAI HIGH-DENSITY IRRADIANCE SENSOR NETWORK FOR CHARACTERIZING...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    on-site RF communication coverage a National Instruments (NI) Wireless Sensor Network (WSN) module with data acquisition capabilities was selected. The NI WSN-3212 module...

  15. High Density Nano-Electrode Array for Radiation Detection

    SciTech Connect (OSTI)

    Mano Misra

    2010-05-07

    Bulk single crystals of Cd1-xZnxTe (x=0.04 to x=0.2) compound semiconductor is used for room temperature radiation detection. The production of large volume of Cd1-xZnxTe with low defect density is expensive. As a result there is a growing research interest in the production of nanostructured compound semiconductors such as Cd1-xZnxTe in an electrochemical route. In this investigation, Cd1-xZnxTe ternary compound semiconductor, referred as CZT, was electrodeposited in the form of nanowires onto a TiO2 nanotubular template from propylene carbonate as the non-aqueous electrolyte, using a pulse-reverse electrodeposition process at 130 ŗC. The template acted as a support in growing ordered nanowire of CZT which acts as a one dimensional conductor. Cyclic Voltammogram (CV) studies were conducted in determining the potentials for the growth of nanowires of uniform stoichiometry. The morphologies and composition of CZT were characterized by using SEM, TEM and XRD. The STEM mapping carried out on the nanowires showed the uniform distribution of Cd, Zn and Te elements. TEM image showed that the nanowires were polycrystalline in nature. The Mott-Schottky analysis carried on the nanowires showed that the nanowires were a p-type semiconductor. The carrier density, band gap and resistivity of the Cd0.9Zn0.1Te nanowires were 4.29x1013 cm-3, 1.56 eV and 2.76x1011?-cm respectively. The high resistivity was attributed to the presence of deep defect states such as cadmium vacancies or Te antisites which were created by the anodic cycle of the pulse-reverse electrodeposition process. Stacks of series connected CZT nanowire arrays were tested with different bias potentials. The background current was in the order of tens of picoamperes. When exposed to radiation source Amerecium-241 (60 KeV, 4 ?Ci), the stacked CZT nanowires arrays showed sensing behavior. The sensitivity of the nanowire arrays increased as the number of stacks increased. The preliminary results indicate that the CZT nanowire arrays can be used as a potential X-ray and low energy gamma ray detector material at room temperature with a much low bias potential (0.7 – 4V) as against 300 – 500 V applied in the commercial bulk detector materials.

  16. Quadrilateral Cooperation on High-density Low-enriched Uranium...

    National Nuclear Security Administration (NNSA)

    This Site Budget IG Web Policy Privacy No Fear Act Accessibility FOIA Sitemap Federal Government The White House DOE.gov USA.gov Jobs Apply for Our Jobs Our Jobs Working at NNSA...

  17. HIGH-DENSITY CIRCUMSTELLAR INTERACTION IN THE LUMINOUS TYPE IIn...

    Office of Scientific and Technical Information (OSTI)

    properties are consistent with the SN expanding into a CSM characteristic of a luminous blue variable progenitor with a bipolar geometry. The apparent absence of nuclear processing...

  18. Simulation of High Density Pedestrian Flow: Microscopic Model

    E-Print Network [OSTI]

    Dridi, Mohamed H

    2015-01-01

    In recent years modelling crowd and evacuation dynamics has become very important, with increasing huge numbers of people gathering around the world for many reasons and events. The fact that our global population grows dramatically every year and the current public transport systems are able to transport large amounts of people, heightens the risk of crowd panic or crush. Pedestrian models are based on macroscopic or microscopic behaviour. In this paper, we are interested in developing models that can be used for evacuation control strategies. This model will be based on microscopic pedestrian simulation models, and its evolution and design requires a lot of information and data. The people stream will be simulated, based on mathematical models derived from empirical data about pedestrian flows. This model is developed from image data bases, so called empirical data, taken from a video camera or data obtained using human detectors. We consider the individuals as autonomous particles interacting through socia...

  19. Method For Enhanced Gas Monitoring In High Density Flow Streams

    DOE Patents [OSTI]

    Von Drasek, William A. (Oak Forest, IL); Mulderink, Kenneth A. (Countryside, IL); Marin, Ovidiu (Lisle, IL)

    2005-09-13

    A method for conducting laser absorption measurements in high temperature process streams having high levels of particulate matter is disclosed. An impinger is positioned substantially parallel to a laser beam propagation path and at upstream position relative to the laser beam. Beam shielding pipes shield the beam from the surrounding environment. Measurement is conducted only in the gap between the two shielding pipes where the beam propagates through the process gas. The impinger facilitates reduced particle presence in the measurement beam, resulting in improved SNR (signal-to-noise) and improved sensitivity and dynamic range of the measurement.

  20. Analysis of high-density SNP data from complex populations 

    E-Print Network [OSTI]

    Floyd, James A.B.

    2011-06-27

    Data from a Croatian isolate population are analysed in a genome-wide association study (GWAS) for a variety of disease-related quantitative traits. A novel genomewide approach to analysing pedigree-based association ...

  1. Symmetry energy systematics and its high density behavior

    E-Print Network [OSTI]

    Lie-Wen Chen

    2015-06-30

    We explore the systematics of the density dependence of nuclear matter symmetry energy in the ambit of microscopic calculations with various energy density functionals, and find that the symmetry energy from subsaturation density to supra-saturation density can be well determined by three characteristic parameters of the symmetry energy at saturation density $\\rho_0 $, i.e., the magnitude $E_{\\text{sym}}({\\rho_0 })$, the density slope $L$ and the density curvature $K_{\\text{sym}}$. This finding opens a new window to constrain the supra-saturation density behavior of the symmetry energy from its (sub-)saturation density behavior. In particular, we obtain $L=46.7 \\pm 12.8$ MeV and $K_{\\text{sym}}=-166.9 \\pm 168.3$ MeV as well as $E_{\\text{sym}}({2\\rho _{0}}) \\approx 40.2 \\pm 12.8$ MeV and $L({2\\rho _{0}}) \\approx 8.9 \\pm 108.7$ MeV based on the present knowledge of $E_{\\text{sym}}({\\rho_{0}}) = 32.5 \\pm 0.5$ MeV, $E_{\\text{sym}}({\\rho_c}) = 26.65 \\pm 0.2$ MeV and $L({\\rho_c}) = 46.0 \\pm 4.5$ MeV at $\\rho_{\\rm{c}}= 0.11$ fm$^{-3}$ extracted from nuclear mass and the neutron skin thickness of Sn isotopes. Our results indicate that the symmetry energy cannot be stiffer than a linear density dependence.In addition, we also discuss the quark matter symmetry energy since the deconfined quarks could be the right degree of freedom in dense matter at high baryon densities.

  2. High-density thermoelectric power generation and nanoscale thermal metrology

    E-Print Network [OSTI]

    Mayer, Peter (Peter Matthew), 1978-

    2007-01-01

    Thermoelectric power generation has been around for over 50 years but has seen very little large scale implementation due to the inherently low efficiencies and powers available from known materials. Recent material advances ...

  3. Spectroscopic Feedback for High Density Data Storage and Micromachining

    DOE Patents [OSTI]

    Carr, Christopher W. (Livermore, CA); Demos, Stavros (Livermore, CA); Feit, Michael D. (Livermore, CA); Rubenchik, Alexander M. (Livermore, CA)

    2008-09-16

    Optical breakdown by predetermined laser pulses in transparent dielectrics produces an ionized region of dense plasma confined within the bulk of the material. Such an ionized region is responsible for broadband radiation that accompanies a desired breakdown process. Spectroscopic monitoring of the accompanying light in real-time is utilized to ascertain the morphology of the radiated interaction volume. Such a method and apparatus as presented herein, provides commercial realization of rapid prototyping of optoelectronic devices, optical three-dimensional data storage devices, and waveguide writing.

  4. Lanai high-density irradiance sensor network for characterizing solar

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(Journalspectroscopy of aerosols(Technical

  5. High Density Sensor Network Development | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journalvivo Low-DoseOptionsthroughput spectrometer forInnovationand FuelHigh

  6. Nuclear magnetic resonance investigation of dynamics in poly(ethylene oxide)-based lithium polyether-ester-sulfonate ionomers

    SciTech Connect (OSTI)

    Roach, David J. [Pennsylvania State University, University Park, PA (United States); Dou, Shichen [Pennsylvania State University, University Park, PA (United States); Colby, Ralph H. [Pennsylvania State University, University Park, PA (United States); Mueller, Karl T. [Pacific Northwest Lab., Richland, WA (United States). Environmental Molecular Sciences Lab.

    2012-01-01

    Nuclear magnetic resonance (NMR) spectroscopy has been utilized to investigate the dynamics of poly(ethylene oxide)-based lithium sulfonate ionomer samples that have low glass transition temperatures. 1H and 7Li spin-lattice relaxation times (T1) of the bulk polymer and lithium ions, respectively, were measured and analyzed in samples with a range of ion contents. The temperature dependence of T1 values along with the presence of minima in T1 as a function of temperature enabled correlation times and activation energies to be obtained for both the segmental motion of the polymer backbone and the hopping motion of lithium cations. Similar activation energies for motion of both the polymer and lithium ions in the samples with lower ion content indicate that the polymer segmental motion and lithium ion hopping motion are correlated in these samples, even though their respective correlation times differ significantly. A divergent trend is observed for correlation times and activation energies of the highest ion content sample with 100% lithium sulfonation due to the presence of ionic aggregation. Details of the polymer and cation dynamics on the nanosecond timescale are discussed and complement the findings of X-ray scattering and Quasi Elastic Neutron Scattering experiments.

  7. Nuclear magnetic resonance investigation of dynamics in poly(ethylene oxide)-based lithium polyether-ester-sulfonate ionomers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Roach, David J. [Pennsylvania State University, University Park, PA (United States); Dou, Shichen [Pennsylvania State University, University Park, PA (United States); Colby, Ralph H. [Pennsylvania State University, University Park, PA (United States); Mueller, Karl T. [Pacific Northwest Lab., Richland, WA (United States). Environmental Molecular Sciences Lab.

    2012-01-01

    Nuclear magnetic resonance (NMR) spectroscopy has been utilized to investigate the dynamics of poly(ethylene oxide)-based lithium sulfonate ionomer samples that have low glass transition temperatures. 1H and 7Li spin-lattice relaxation times (T1) of the bulk polymer and lithium ions, respectively, were measured and analyzed in samples with a range of ion contents. The temperature dependence of T1 values along with the presence of minima in T1 as a function of temperature enabled correlation times and activation energies to be obtained for both the segmental motion of the polymer backbone and the hopping motion of lithium cations. Similar activation energies for motion of both the polymer and lithium ions in the samples with lower ion content indicate that the polymer segmental motion and lithium ion hopping motion are correlated in these samples, even though their respective correlation times differ significantly. A divergent trend is observed for correlation times and activation energies of the highest ion content sample with 100% lithium sulfonation due to the presence of ionic aggregation. Details of the polymer and cation dynamics on the nanosecond timescale are discussed and complement the findings of X-ray scattering and Quasi Elastic Neutron Scattering experiments.

  8. Influence of ensemble boundary conditions (thermostat and barostat) on the deformation of amorphous polyethylene by molecular dynamics

    E-Print Network [OSTI]

    M. A. Tschopp; J. L. Bouvard; D. K. Ward; D. J. Bammann; M. F. Horstemeyer

    2013-10-02

    Molecular dynamics simulations are increasingly being used to investigate the structural evolution of polymers during mechanical deformation, but relatively few studies focus on the influence of boundary conditions on this evolution, in particular the dissipation of both heat and pressure through the periodic boundaries during deformation. The research herein explores how the tensile deformation of amorphous polyethylene, modelled with a united atom method potential, is influenced by heat and pressure dissipation. The stress-strain curves for the pressure dissipation cases (uniaxial tension) are in qualitative agreement with experiments and show that heat dissipation has a large effect on the strain hardening modulus calculated by molecular dynamics simulations. The evolution of the energy associated with bonded and non-bonded terms was quantified as a function of strain as well as the evolution of stress in both the loading and non-loading directions to give insight into how the stress state is altered within the elastic, yield, strain softening, and strain hardening regions. The stress partitioning shows a competition between `tensile' Van der Waal's interactions and `compressive' bond stretching forces, with the characteristic yield stress peak clearly associated with the non-bonded stress. The lack of heat dissipation had the largest effect on the strain hardening regime, where an increase in the calculated temperature correlated with faster chain alignment in the loading direction and more rapid conformation changes. In part, these observations demonstrate the role that heat and pressure dissipation play on deformation characteristics of amorphous polymers, particularly for the strain hardening regime.

  9. Poly(ethylene glycol)-conjugated multi-walled carbon nanotubes as an efficient drug carrier for overcoming multidrug resistance

    SciTech Connect (OSTI)

    Cheng Jinping [Department of Biology and Chemistry, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon (Hong Kong); Meziani, Mohammed J.; Sun Yaping [Department of Chemistry and Laboratory for Emerging Materials and Technology, Clemson University, Clemson, SC 29634-0973 (United States); Cheng, Shuk Han, E-mail: bhcheng@cityu.edu.hk [Department of Biology and Chemistry, City University of Hong Kong, 83 Tat Chee Avenue, Kowloon (Hong Kong)

    2011-01-15

    The acquisition of multidrug resistance poses a serious problem in chemotherapy, and new types of transporters have been actively sought to overcome it. In the present study, poly(ethylene glycol)-conjugated (PEGylated) multi-walled carbon nanotubes (MWCNTs) were prepared and explored as drug carrier to overcome multidrug resistance. The prepared PEGylated MWCNTs penetrated into mammalian cells without damage plasma membrane, and its accumulation did not affect cell proliferation and cell cycle distribution. More importantly, PEGylated MWCNTs accumulated in the multidrug-resistant cancer cells as efficient as in the sensitive cancer cells. Intracellular translocation of PEGylated MWCNTs was visualized in both multidrug-resistant HepG2-DR cells and sensitive HepG2 cells, as judged by both fluorescent and transmission electron microscopy. PEGylated MWCNTs targeted cancer cells efficiently and multidrug-resistant cells failed to remove the intracellular MWCNTs. However, if used in combination with drugs without conjugation, PEGylated MWCNTs prompted drug efflux in MDR cells by stimulating the ATPase activity of P-glycoprotein. This study suggests that PEGylated MWCNTs can be developed as an efficient drug carrier to conjugate drugs for overcoming multidrug resistance in cancer chemotherapy.

  10. Nuclear magnetic resonance investigation of dynamics in poly(ethylene oxide)-based lithium polyether-ester-sulfonate ionomers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Roach, David J.; Dou, Shichen; Colby, Ralph H.; Mueller, Karl T.

    2012-01-06

    Nuclear magnetic resonance (NMR) spectroscopy has been utilized to investigate the dynamics of poly(ethylene oxide)-based lithium sulfonate ionomer samples that have low glass transition temperatures. 1H and 7Li spin-lattice relaxation times (T1) of the bulk polymer and lithium ions, respectively, were measured and analyzed in samples with a range of ion contents. The temperature dependence of T1 values along with the presence of minima in T1 as a function of temperature enabled correlation times and activation energies to be obtained for both the segmental motion of the polymer backbone and the hopping motion of lithium cations. Similar activation energies formore »motion of both the polymer and lithium ions in the samples with lower ion content indicate that the polymer segmental motion and lithium ion hopping motion are correlated in these samples, even though their respective correlation times differ significantly. A divergent trend is observed for correlation times and activation energies of the highest ion content sample with 100% lithium sulfonation due to the presence of ionic aggregation. Details of the polymer and cation dynamics on the nanosecond timescale are discussed and complement the findings of X-ray scattering and Quasi Elastic Neutron Scattering experiments.« less

  11. 488-4D ASH LANDFILL CLOSURE CAP HELP MODELING

    SciTech Connect (OSTI)

    Phifer, M.

    2014-11-17

    At the request of Area Completion Projects (ACP) in support of the 488-4D Landfill closure, the Savannah River National Laboratory (SRNL) has performed Hydrologic Evaluation of Landfill Performance (HELP) modeling of the planned 488-4D Ash Landfill closure cap to ensure that the South Carolina Department of Health and Environmental Control (SCDHEC) limit of no more than 12 inches of head on top of the barrier layer (saturated hydraulic conductivity of no more than 1.0E-05 cm/s) in association with a 25-year, 24-hour storm event is not projected to be exceeded. Based upon Weber 1998 a 25-year, 24-hour storm event at the Savannah River Site (SRS) is 6.1 inches. The results of the HELP modeling indicate that the greatest peak daily head on top of the barrier layer (i.e. geosynthetic clay liner (GCL) or high density polyethylene (HDPE) geomembrane) for any of the runs made was 0.079 inches associated with a peak daily precipitation of 6.16 inches. This is well below the SCDHEC limit of 12 inches.

  12. Characterization of illuminated semiconductor/solid-electrolyte junctions. photoelectrochemical investigation of a poly(ethylene oxide) cell. Interim technical report 1 Mar-30 Apr 83

    SciTech Connect (OSTI)

    Sammells, A.F.; Ang, P.G.P.

    1983-05-01

    Photoelectrochemical effects have been observed with solid-state cells using a poly(ethylene oxide) .NaSCN solid polymer electrolyte containing a Na2S/S redox couple. Photoeffects were observed at the interface of this electrolyte with p-InP, n-GaAs, and in a two-photoelectrode cell of configuration p-InP/PEO-NaSCN, Na2S,S/n-CdS. In this latter cell, photopotentials of 540 mV were generated using 100 mW/cm2 quartz iodine illumination.

  13. Fragmentation cross sections of Fe^{26+}, Si^{14+} and C^{6+} ions of 0.3-10 A GeV on polyethylene, CR39 and aluminum targets

    E-Print Network [OSTI]

    S. Cecchini; T. Chiarusi; G. Giacomelli; M. Giorgini; A. Kumar; G. Mandrioli; S. Manzoor; A. R. Margiotta; E. Medinaceli; L. Patrizii; V. Popa; I. E. Qureshi; G. Sirri; M. Spurio; V. Togo

    2008-01-21

    We present new measurements of the total and partial fragmentation cross sections in the energy range 0.3-10 A GeV of 56Fe, 28Si and 12C beams on polyethylene, CR39 and aluminum targets. The exposures were made at BNL, USA and HIMAC, Japan. The CR39 nuclear track detectors were used to identify the incident and survived beams and their fragments. The total fragmentation cross sections for all targets are almost energy independent while they depend on the target mass. The measured partial fragmentation cross sections are also discussed.

  14. Polyethylene under tensile load: strain energy storage and breaking of linear and knotted alkanes probed by first-principles molecular dynamics calculations

    E-Print Network [OSTI]

    A. Marco Saitta; Michael L. Klein

    1999-09-01

    The mechanical resistance of a polyethylene strand subject to tension and the way its properties are affected by the presence of a knot is studied using first-principles molecular dynamics calculations. The distribution of strain energy for the knotted chains has a well-defined shape that is very different from the one found in the linear case. The presence of a knot significantly weakens the chain in which it is tied. Chain rupture invariably occurs just outside the entrance to the knot, as is the case for a macroscopic rope.

  15. Fragmentation cross sections of Fe^{26+}, Si^{14+} and C^{6+} ions of 0.3-10 A GeV on CR39, polyethylene and aluminum targets

    E-Print Network [OSTI]

    Miriam Giorgini

    2008-12-01

    New measurements of the total and partial fragmentation cross sections in the energy range 0.3-10 A GeV of Fe^{26+}, Si^{14+} and C^{6+} beams on polyethylene, CR39 and aluminum targets are presented. The exposures were made at Brookhaven National Laboratory (BNL), USA, and Heavy Ion Medical Accelerator in Chiba (HIMAC), Japan. The CR39 nuclear track detectors were used to identify the incident and survived beams and their fragments. The total fragmentation cross sections for all targets are almost energy independent while they depend on the target mass. The measured partial fragmentation cross sections are also discussed.

  16. Polyethylene fiber drawing optimization

    E-Print Network [OSTI]

    Chiloyan, Vazrik

    2011-01-01

    Polymer fiber drawing creates fibers with enhanced thermal conductivity and strength compared to bulk polymer because drawing aligns the molecular chains. I optimize the polymer fiber drawing method in order to achieve ...

  17. Pilot Demonstration of Technology for the Production of High Value Materials from the Ultra-Fine (PM2.5) Fraction of Coal Combustion Ash

    SciTech Connect (OSTI)

    T. L. Robl; J. G. Groppo; R. Rathbone; B. Marrs; R. Jewell

    2008-07-18

    The overall objective of this research was to determine the feasibility of recovering a very fine fraction of fly ash, that is 5 microns in diameter or less and examining the characteristics of these materials in new or at least less traditional applications. These applications included as a polymer filler or as a 'super' pozzolanic concrete additive. As part of the effort the ash from 6 power plants was investigated and characterized. This work included collection from ESP Hoppers and ponds. The ash was thoroughly characterized chemically and physically. Froth flotation was used to reduce the carbon and testing showed that flotation could effectively reduce carbon to acceptable levels (i.e. 0.5% LOI) for most of the substrates tested. in order to enable eventual use as fillers. Hydraulic classification was used in the separation of the fine ash from the coarse ash. Hydraulic classification requires the ash to be dispersed to be effective and a range of dispersants were tested for adsorption as well as sedimentation rate. A wide range of dosages were required (0.3 to 10 g/kg). In general the ponded ash required less dispersant. A model was developed for hydraulic classification. A pilot-scale hydraulic classifier was also designed and operated for the project. Product yields of up to 21% of feed solids were achieved with recoveries of <5 {micro}m particles as high as 64%. Mean particle sizes (D{sub 50}) of the ultra fine ash (UFA) products varied from 3.7 to 10 {micro}m. A patent was filed on the classifier design. A conceptual design of a Process Demonstration Unit (PDU) with a feed rate of 2 tons of raw ash feed per hour was also completed. Pozzolanic activity was determined for the UFA ashes in mortars. In general the overall strength index was excellent with values of 90% achieved in 3 days and {approx}100% in 7 days. Three types of thermoplastic polymers were evaluated with the UFA as a filler: high density polyethylene, thermoplastic elastomer and polyethylene terphthalate filled polymers were prepared and subjected to SEM analysis to verify that the UFA was well dispersed. The addition of fillers increased the modulus of the HDPE composite, but decreased both the offset yield stress and offset yield strain, showing that the fillers essentially made the composite stiffer but the transition to plastic deformation occurred earlier in filled HDPE as stress was applied. Similar results were obtained with TPE, however, the decrease in either stress or strain at offset yield were not as significant. Dynamic mechanical analyses (DMA) were also completed and showed that although there were some alterations in the properties of the HDPE and TPE, the alterations are small, and more importantly, transition temperatures are not altered. The UFA materials were also tested in expanded urethanes, were improvements were made in the composites strength and stiffness, particularly for lighter weight materials. The results of limited flammability and fire safety testing were encouraging. A flowsheet was developed to produce an Ultra-Fine Ash (UFA) product from reclaimed coal-fired utility pond ash. The flowsheet is for an entry level product development scenario and additional production can be accommodated by increasing operating hours and/or installing replicate circuits. Unit process design was based on experimental results obtained throughout the project and cost estimates were derived from single vendor quotes. The installation cost of this plant is estimated to be $2.1M.

  18. A study of the relationship between lithium ion transport and structure and dynamic behavior in polyethylene oxide-melt/LiClO4 battery electrolytes.

    SciTech Connect (OSTI)

    Selser, James C

    2009-07-07

    An experimental study of the canonical SPE (“solid” polymer electrolyte) for rechargeable “rocking chair” lithium/polymer batteries, viz. LiClO4 dissolved in molten poly(ethylene oxide) (PEO), was carried out under DOE grant FG02-04ER15573. In this study, an improved understanding was obtained of the relationship between lithium ion transport and polymer behavior in these SPEs. Among other applications, these sturdy temperature-tolerant and powerful light-weight batteries would be used in electric and electric-hybrid vehicles to reduce greenhouse gas emissions, to store unused electrical energy for peak demand loads and as compact, light-weight energy sources for aircraft and spacecraft. During the period of the grant, the American/Canadian partnership company “Avestor” fabricated and successfully demonstrated a telecommunications application of shoe-box sized batteries and representatives from Avestor visited our research lab at UNLV. They found our results interesting and relevant to their work and invited us to visit Avestor and present a talk about our efforts at UNLV. Unfortunately Avestor (who was scheduled to build a battery production facility in Apex, Nevada just North of Las Vegas) folded before the visit could be made. In the grant work, two well characterized PEO samples having molar masses distinctly below and distinctly above the melt entanglement molar mass were used and three laser light scattering techniques employed as the principal noninvasive methods of investigating liquid poly(ethylene oxide) (PEO)/LiClO4 SPEs. These investigations considered the effects of temperature, dissolved salt concentration and scattering wavevector on SPE behavior. Classical or “static” light scattering and the dynamic light scattering techniques of photon correlation spectroscopy (PCS) and Fabry-Perot interferometry (FPI) were used to study SPE static, low frequency and high frequency dynamic behaviors, respectively. Static measurements provided information about system structure while low frequency results provided information about slower (0.1-10s) more global behavior and high frequency results provided information about faster (~10-11s) more local behavior. In addition, viscometry, rheometry and thermal analysis provided vital complementary results. It was found that liquid PEO/lithium salt solutions for both PEO molar masses are random transient physical networks with measureable network and intra-network relaxation times using PCS and FPI. Thus novel and informative results addressing both large scale and small scale behavior were obtained. For example, the high sensitivity of liquid PEO electrolytes to the presence of presumably undesirable trace amounts of residual water and/or methanol was clearly evident in PCS measurements. In “unentangled” melts the activation energies for diffusive relaxation in liquid PEO/lithium salt electrolytes measured using PCS and the activation energies for viscous flow in these systems determined by viscometry were identical while thermal analyses detected no phase transitions for these systems. These results reinforced an earlier assumption that the liquid PEO/LiClO4 system is a liquid polymer “bimorph” (to our knowledge the first of its kind to be reported) with the network comprising one form of the polymer while the second form corresponds to that of a viscous damping liquid. At a given temperature, FPI characteristic relaxation times for local, between-chain motions were consistent with PCS results so that increases with increasing salt concentration were accompanied by increases in the elastic modulus and corresponding increases in system stiffness. Note that corresponding decreases in polymer segmental mobility are accompanied by reduced ion diffusivity. For entangled melts, PCS network relaxations were again observed and these systems were also considered to be bimorphs even though diffusion activation energies were distinctly larger than viscous flow activation energies - a difference attributed to the effects of entanglement. Moreover, SLS measurement

  19. Mechanical and transparent conductive properties of ZnO and Ga-doped ZnO films sputtered using electron-cyclotron-resonance plasma on polyethylene naphtalate substrates

    SciTech Connect (OSTI)

    Akazawa, Housei, E-mail: akazawa.housei@lab.ntt.co.jp [NTT Microsystem Integration Laboratories 3-1 Morinosato Wakamiya, Atsugi, Kanagawa 243-0198 (Japan)

    2014-03-15

    Transparent conductive ZnO and Ga-doped ZnO (GZO) films were deposited on polyethylene naphtalate (PEN) sheet substrates using electron cyclotron resonance plasma sputtering. Both ZnO and GZO films were highly adhesive to the PEN substrates without inserting an intermediate layer in the interface. When compared at the same thickness, the transparent conductive properties of GZO films on PEN substrates were only slightly inferior to those on glass substrates. However, the carrier concentration of ZnO films on PEN substrates was 1.5?times that of those on glass substrates, whereas their Hall mobility was only 60% at a thickness of 300?nm. The depth profile of elements measured by secondary ion mass spectroscopy revealed the diffusion of hydrocarbons out of the PEN substrate into the ZnO film. Hence, doped carbons may act as donors to enhance carrier concentration, and the intermixing of elements at the interface may deteriorate the crystallinity, resulting in the lower Hall mobility. When the ZnO films were thicker than 400?nm, cracks became prevalent because of the lattice mismatch strain between the film and the substrate, whereas GZO films were free of cracks. The authors investigated how rolling the films around a cylindrical pipe surface affected their conductive properties. Degraded conductivity occurred at a threshold pipe radius of 10?mm when tensile stress was applied to the film, but it occurred at a pipe radius of 5?mm when compressive stress was applied. These values are guidelines for bending actual devices fabricated on PEN substrates.

  20. Condensation of Self-assembled Lyotropic Chromonic Liquid Crystal Sunset Yellow in Aqueous Solutions Crowded with Polyethylene glycol and Doped with Salt

    E-Print Network [OSTI]

    Heung-Shik Park; Shin-Woong Kang; Luana Tortora; Satyendra Kumar; Oleg D. Lavrentovich

    2011-04-06

    We use optical and fluorescence microscopy, densitometry, cryo-transmission electron microscopy (cryo-TEM), spectroscopy, and synchrotron X-ray scattering, to study the phase behavior of the reversible self-assembled chromonic aggregates of an anionic dye Sunset Yellow (SSY) in aqueous solutions crowded with an electrically neutral polymer polyethylene glycol (PEG) and doped with the salt NaCl. PEG causes the isotropic SSY solutions to condense into a liquid-crystalline region with a high concentration of SSY aggregates, coexisting with a PEG-rich isotropic (I) region. PEG added to the homogeneous nematic (N) phase causes separation into the coexisting N and I domains; the SSY concentration in the N domains is higher than the original concentration of PEG-free N phase. Finally, addition of PEG to the highly concentrated homogeneous N phase causes separation into the coexisting columnar hexagonal (C) phase and I phase. This behavior can be qualitatively explained by the depletion (excluded volume) effects that act at two different levels: at the level of aggregate assembly from monomers and short aggregates and at the level of inter-aggregate packing. We also show a strong effect of a monovalent salt NaCl on phase diagrams that is different for high and low concentrations of SSY. Upon the addition of salt, dilute I solutions of SSY show appearance of the condensed N domains, but the highly concentrated C phase transforms into a coexisting I and N domains. We suggest that the salt-induced screening of electric charges at the surface of chromonic aggregates leads to two different effects: (a) increase of the scission energy and the contour length of aggregates, and (b) decrease of the persistence length of SSY aggregates.

  1. An XPS study on the chemical bond structure at the interface between SiO{sub x}N{sub y} and N doped polyethylene terephthalate

    SciTech Connect (OSTI)

    Ding Wanyu [School of Materials Science and Engineering, Dalian Jiaotong University, Dalian 116028 (China); Key Laboratory of Materials Modification by Laser, Ion and Electron Beams, Ministry of Education, Dalian University of Technology, Dalian 116024 (China); Li Li; Zhang Lina; Chai Weiping [School of Materials Science and Engineering, Dalian Jiaotong University, Dalian 116028 (China); Ju Dongying [Department of Material Science and Engineering, Saitama Institute of Technology, Fukaya 369-0293 (Japan); Peng Shou [China Triumph International Engineering Co., Ltd., 2000 Zhongshanbei Road, 200063 Shanghai (China)

    2013-03-14

    The super-thin silicon oxynitride (SiO{sub x}N{sub y}) films were deposited onto the N doped polyethylene terephthalate (PET) surface. Varying the N doping parameters, the different chemical bond structures were obtained at the interface between the SiO{sub x}N{sub y} film and the PET surface. X-ray photoelectron spectra results showed that at the initial stage of SiO{sub x}N{sub y} film growth, the C=N bonds could be broken and C-N-Si crosslink bonds could be formed at the interface of SiO{sub x}N{sub y}/PET, which C=N bonds could be formed onto the PET surface during the N doping process. At these positions, the SiO{sub x}N{sub y} film could be crosslinked well onto the PET surface. Meanwhile, the doped N could crosslink the [SiO{sub 4}] and [SiN{sub 4}] tetrahedrons, which could easily form the dense layer structure at the initial stage of SiO{sub x}N{sub y} film growth, instead of the ring and/or chain structures of [SiO{sub 4}] tetrahedrons crosslinked by O. Finally, from the point of applying SiO{sub x}N{sub y}/PET complex as the substrate, the present work reveals a simple way to crosslink them, as well as the crosslink model and physicochemical mechanism happened at the interface of complex.

  2. Idaho's Advanced Mixed Waste Treatment Project Details 2013Accomplish...

    Broader source: Energy.gov (indexed) [DOE]

    Articles A product drum of mixed low-level waste is lowered into a high-density polyethylene macro-pack. Innovative Technique Accelerates Waste Disposal at Idaho Site Only the...

  3. Science & Technology - 2014

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    In addition, DIXI is shielded by 1,300 pounds of lead and high-density borated polyethylene. Researchers Load DIXI Film Pack (Left) Mike Morris and Ken Piston install a film...

  4. PROPERTIES OF HDPE/CLAY/WOOD NANOCOMPOSITES , C. M. Clemons 2

    E-Print Network [OSTI]

    as biodegradable reinforcing materials alternative for the use of glass or carbon fiber and inorganic fillers/natural fibers composites, especially wood plastic composites (WPC) which have successfully proven their high materials. Natural organic fibers from renewable natural resources offer the potential to act

  5. Damage to HDPE geomembrane from interface shear over gravelly compacted clay liner

    E-Print Network [OSTI]

    Thielmann, Stuart

    2012-01-01

    Figure 2.15. As the water content and compressibility of theWater Contents Final water contents and dry unit weights areangularity), compaction water content, and magnitude of

  6. Damage to HDPE geomembrane from interface shear over gravelly compacted clay liner

    E-Print Network [OSTI]

    Thielmann, Stuart

    2012-01-01

    R. S. (2011). “Geomembrane damage due to static and cyclic66 Figure 4.10. GM damage results after shearing for Testsshear displacement on shear strength and GM damage for test

  7. Microwave-assisted pyrolysis of HDPE using an activated carbon bed

    E-Print Network [OSTI]

    Russell, Alan Donald

    2013-04-16

    away” into a landfill after a single use. Microwave-assisted pyrolysis is a recycling technique that allows the recovery of chemical value from plastic waste by breaking down polymers into useful smaller hydrocarbons using microwave heat in the absence...

  8. Damage to HDPE geomembrane from interface shear over gravelly compacted clay liner

    E-Print Network [OSTI]

    Thielmann, Stuart

    2012-01-01

    behavior using NW-NP geotextile protection layer (Narejo etPuncture behavior using geotextile-based GCL protectionmass per unit area of geotextile protective layer at various

  9. Weathering Effects on Mechanical Properties of Recycled HDPE Based Plastic Lumber

    E-Print Network [OSTI]

    was measured directly using a draw wire transducer. Both the exposed side and unexposed side of the deck boards powder developed on the ex- posed side that whitened the exposed surface while the unexposed surface

  10. The influence of processing aids on the melt rheological properties of HDPE for film blowing 

    E-Print Network [OSTI]

    Balmain, Jennifer Ann

    1999-01-01

    Additives serve a variety of purposes in polymer production from increasing stability during processing to improving the appearance of the final product. It is often necessary to include more than one additive to meet the processing and performance...

  11. Olive cultivars field-tested in super-high-density system in southern Italy

    E-Print Network [OSTI]

    Godini, Angelo

    2011-01-01

    oil output Cumulative oil production tons/acre 5.68b 5.83bsimilar cumulative oil production. Harvesting efficiency,and mean oil output and cumulative production Fruit

  12. Microfabrication of High-Density Microelectrode Arrays for Peripheral Intraneural Applications

    E-Print Network [OSTI]

    Tang, William C

    electroplated nickel and NiFe (Permalloy) [6]. Nevertheless, these state-of-the-art research electrode arrays coated with platinum thin film with a partial exposure method, which formed the metal

  13. Large area high density quantized magnetic disks fabricated using nanoimprint lithography

    E-Print Network [OSTI]

    for fabricating large area quantized magnetic disks QMDs using nanoimprint lithography NIL , electroplating or a via array. The other is that for high resolution an antireflection coating ARC layer is needed, which

  14. Potential impacts on advanced technologies on the ATC capacity of high-density terminal areas

    E-Print Network [OSTI]

    Simpson, R. W.

    1986-01-01

    Advanced technologies for airborne systems (automatic flight control, flight displays, navigation) and for ground ATC systems (digital communications, improved surveillance and tracking, automated decision-making) create ...

  15. An integrated view on high density opera2on and fuel cycle

    E-Print Network [OSTI]

    ;Workshop on MFE Roadmapping, Princeton 7- 10 September 2 Contents · Mo · Summary / workplan #12;Workshop on MFE Roadmapping, Princeton 7- 10 September 3 on MFE Roadmapping, Princeton 7- 10 September 4 Mo2va2on In addi?on · decrease

  16. Electrical protein detection in cell lysates using high-density peptide-aptamer microarrays

    E-Print Network [OSTI]

    Evans, David; Johnson, Steve; Laurenson, Sophie; Davies, Giles; Ko Ferrigno, Paul; Walti, Christoph

    2008-01-31

    , Davis J, Foulds G, Gold L, Greef C, Heil J, Heilig JS, Hicke B, Hurst MN, Husar GM, Miller D, Ostroff R, Petach H, Schneider D, Vant-Hull B, Waugh S, Weiss A, Wilcox SK, Zichi D: Photoaptamer arrays applied to multiplexed proteomic analysis. Proteomics...

  17. Alcator C-Mod is the only high-field, high-density divertor tokamak...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    open field lines, including baseline and advanced scenarios, with radiative divertor solutions * Interaction with plasma-facing materials, including heat-flux and particle control...

  18. Elastic Refresh: Techniques to Mitigate Refresh Penalties in High Density Memory

    E-Print Network [OSTI]

    John, Lizy Kurian

    -processor SRAM memory). In the server space, JEDEC- standardized DDR3 DRAMs are currently prevalent, and DDR4 frequencies for DDR, DDR2, DDR3, and DDR4 are 200­400 MHz, 400­1066 MHz, 800­1600 MHz, and 1600­3200 MHz

  19. Solution-based approaches for making high-density sodalite waste...

    Office of Scientific and Technical Information (OSTI)

    solution-based approaches were taken to make sodalite minerals as a host for a mixed salt simulating the waste generated during the electrochemical separations process of...

  20. High Density Three-Dimensional Nanomagnetic Logic Systems Composed of Material with Crystalline Anisotropy

    E-Print Network [OSTI]

    Tian, Yuan

    2013-01-01

    Ping Wang. “Programmable spintronics logic device based on aon [58] Kent, Andrew D. “Spintronics: Perpendicular all the

  1. High density growth of T7 expression strains with auto-induction option

    DOE Patents [OSTI]

    Studier, F. William (Stony Brook, NY)

    2010-07-20

    A bacterial growth medium for promoting auto-induction of transcription of cloned DNA in cultures of bacterial cells grown batchwise is disclosed. The transcription is under the control of a lac repressor. Also disclosed is a bacterial growth medium for improving the production of a selenomethionine-containing protein or polypeptide in a bacterial cell, the protein or polypeptide being produced by recombinant DNA techniques from a lac or T7lac promoter, the bacterial cell encoding a vitamin B12-dependent homocysteine methylase. Finally, disclosed is a bacterial growth medium for suppressing auto-induction of expression in cultures of bacterial cells grown batchwise, said transcription being under the control of lac repressor.

  2. DEGAS 2 Neutral Transport Modeling of High Density, Low Temperature Plasmas

    E-Print Network [OSTI]

    , the resulting fluid neutral momentum balance in a slab geometry is d dx ³ mnv 2 + nT ´ = # T n dT dx - m# cx nv.24, and the charge exchange frequency, # cx = 2.93# cx n(T/m) 1/2 . With a neutral source on one end of the slab (x density # # n(x)/n(L), d# dx = - 2 4 (1-# T ) T (L) dT (x) dx # + ##cx [T (L)/m] 1/2 T (x) T (L) - # 2 # 2

  3. Cell-Bridge-Based Connection of High Density Sensor Elements Akimasa Okada

    E-Print Network [OSTI]

    Shinoda, Hiroyuki

    , and waste the power for communication. In this paper, we propose a novel network system named "cell bridge a similar goal, "Two-Dimensional Signal Transmission"[3] is studied. This technology realizes the flexible , and Hiroyuki Shinoda In this paper, we propose a novel network system named "cell bridge system" for a high

  4. High density hexagonal boron nitride prepared by hot isostatic pressing in refractory metal containers

    DOE Patents [OSTI]

    Hoenig, Clarence L. (Livermore, CA)

    1992-01-01

    Boron nitride powder with less than or equal to the oxygen content of starting powder (down to 0.5% or less) is hot isostatically pressed in a refractory metal container to produce hexagonal boron nitride with a bulk density greater than 2.0 g/cc. The refractory metal container is formed of tantalum, niobium, tungsten, molybdenum or alloys thereof in the form of a canister or alternatively plasma sprayed or chemical vapor deposited onto a powder compact. Hot isostatic pressing at 1800.degree. C. and 30 KSI (206.8 MPa) argon pressure for four hours produces a bulk density of 2.21 g/cc. Complex shapes can be made.

  5. High density crystalline boron prepared by hot isostatic pressing in refractory metal containers

    DOE Patents [OSTI]

    Hoenig, C.L.

    1993-08-31

    Boron powder is hot isostatically pressed in a refractory metal container to produce a solid boron monolith with a bulk density at least 2.22 g/cc and up to or greater than 2.34 g/cc. The refractory metal container is formed of tantalum, niobium, tungsten, molybdenum or alloys thereof in the form of a canister or alternatively plasma sprayed or chemical vapor deposited onto a powder compact. Hot isostatic pressing at 1,800 C and 30 PSI (206.8 MPa) argon pressure for four hours produces a bulk density of 2.34 g/cc. Complex shapes can be made.

  6. High density-high purity graphite prepared by hot isostatic pressing in refractory metal containers

    DOE Patents [OSTI]

    Hoenig, Clarence L. (Livermore, CA)

    1994-01-01

    Porous graphite in solid form is hot isostatically pressed in a refractory metal container to produce a solid graphite monolith with a bulk density greater than or equal to 2.10 g/cc. The refractory metal container is formed of tantalum, niobium, tungsten, molybdenum or alloys thereof in the form of a canister or alternatively plasma sprayed, chemically vapor deposited, or coated by some other suitable means onto graphite. Hot isostatic pressing at 2200.degree. C. and 30 KSI (206.8 MPa) argon pressure for two hours produces a bulk density of 2.10 g/cc. Complex shapes can be made.

  7. High density crystalline boron prepared by hot isostatic pressing in refractory metal containers

    DOE Patents [OSTI]

    Hoenig, Clarence L. (Livermore, CA)

    1993-01-01

    Boron powder is hot isostatically pressed in a refractory metal container to produce a solid boron monolith with a bulk density at least 2.22 g/cc and up to or greater than 2.34 g/cc. The refractory metal container is formed of tantalum, niobium, tungsten, molybdenum or alloys thereof in the form of a canister or alternatively plasma sprayed or chemical vapor deposited onto a powder compact. Hot isostatic pressing at 1800.degree. C. and 30 KSI (206.8 MPa) argon pressure for four hours produces a bulk density of 2.34 g/cc. Complex shapes can be made.

  8. Olive cultivars field-tested in super-high-density system in southern Italy

    E-Print Network [OSTI]

    Godini, Angelo

    2011-01-01

    2009, in the third and fourth years after planting, respec-acre (table 2). In the fourth year, the average crop yieldmean of the third and fourth year after planting Harvesting

  9. Vertical Village : towards a new typology of high-density low-income urban housing

    E-Print Network [OSTI]

    Harper, Caleb Benjamin

    2014-01-01

    Apocalyptic global urbanization is old news. For generations statistically supported oracles have warned against the rising tide of rapid urban growth, one must only casually search the keywords "urban slum" on Goggle to ...

  10. Stellar Wind Accretion in GX301-2: Evidence for a High-density Stream

    E-Print Network [OSTI]

    D. A. Leahy; M. Kostka

    2007-09-04

    The X-ray binary system GX301-2 consists of a neutron star in an eccentric orbit accreting from the massive early-type star WRAY 977. It has previously been shown that the X-ray orbital light curve is consistent with existence of a gas stream flowing out from Wray 977 in addition to its strong stellar wind. Here, X-ray monitoring observations by the Rossi X-ray Timing Explorer (RXTE)/ All-Sky-Monitor (ASM) and pointed observations by the RXTE/ Proportional Counter Array (PCA) over the past decade are analyzed. We analyze both the flux and column density dependence on orbital phase. The wind and stream dynamics are calculated for various system inclinations, companion rotation rates and wind velocities, as well as parametrized by the stream width and density. These calculations are used as inputs to determine both the expected accretion luminosity and the column density along the line-of-sight to the neutron star. The model luminosity and column density are compared to observed flux and column density vs. orbital phase, to constrain the properties of the stellar wind and the gas stream. We find that the change between bright and medium intensity levels is primarily due to decreased mass loss in the stellar wind, but the change between medium and dim intensity levels is primarily due to decreased stream density. The mass-loss rate in the stream exceeds that in the stellar wind by a factor of 2.5. The quality of the model fits is significantly better for lower inclinations, favoring a mass for WRAY 977 of 53 to 62 Msun.

  11. Cooperative Enhancement of Energy Transfer in a High-Density Thermal Vapor

    E-Print Network [OSTI]

    L. Weller; R. J. Bettles; C. L. Vaillant; M. A. Zentile; R. M. Potvliege; C. S. Adams; I. G. Hughes

    2013-08-01

    We present an experimental study of energy transfer in a thermal vapor of atomic rubidium. We measure the fluorescence spectrum in the visible and near infra-red as a function of atomic density using confocal microscopy. At low density we observe energy transfer consistent with the well-known energy pooling process. In contrast, above a critical density we observe a dramatic enhancement of the fluorescence from high-lying states that is not to be expected from kinetic theory. We show that the density threshold for excitation on the D1 and D2 resonance line corresponds to the value at which the dipole-dipole interactions begins to dominate, thereby indicate the key role of these interactions in the enhanced emission.

  12. Supporting Information 3D High-Density Hierarchical Nanowire Architectures for

    E-Print Network [OSTI]

    Wang, Xudong

    . Separated exposures of gaseous TiCl4 and H2O vapors were controlled by solenoid valves and adjusted by fine, a constant flow of 40 sccm N2 was applied into the chamber as the carrier gas, which provided a background naturally under N2 flow. (2) Fabrication of patterned Si NW arrays by dry etching Patterned and vertically

  13. Jay E. Hammel memorial lecture: The high density Z-pinch

    SciTech Connect (OSTI)

    Dreicer, H.

    1990-01-01

    This report discusses the history and contributions of Jay E. Hammel to Z-pinch magnetic fission devices. (LSP)

  14. High density-high purity graphite prepared by hot isostatic pressing in refractory metal containers

    DOE Patents [OSTI]

    Hoenig, C.L.

    1994-08-09

    Porous graphite in solid form is hot isostatically pressed in a refractory metal container to produce a solid graphite monolith with a bulk density greater than or equal to 2.10 g/cc. The refractory metal container is formed of tantalum, niobium, tungsten, molybdenum or alloys thereof in the form of a canister or alternatively plasma sprayed, chemically vapor deposited, or coated by some other suitable means onto graphite. Hot isostatic pressing at 2,200 C and 30 KSI (206.8 MPa) argon pressure for two hours produces a bulk density of 2.10 g/cc. Complex shapes can be made. 1 fig.

  15. THERMAL ANNEALING OF ZNO FILMS USING HIGH-DENSITY PLASMA ARC LAMPS

    SciTech Connect (OSTI)

    Sabau, Adrian S; Dinwiddie, Ralph Barton; Xu, Jun; Angelini, Joseph Attilio; Harper, David C

    2011-01-01

    Nanostructured materials are rarely synthesized with appropriate phase and/or morphology. In this study, critical additional of as-synthesized nanostructured materials, such as annealing and/or activation of dopants, are addressed using infrared plasma arc lamps (PAL) over areas as large as 1,000 cm2. The broad spectral range of the PAL and the spectral variation of light absorption in nanostructured materials make the selection of processing parameters extremely difficult, posing a major technological barrier. In this study, the measurement of the surface temperature using various techniques for ZnO films on crystalline silicon wafers is discussed. An energy transport model for the simulation of rapid thermal processing using PAL is presented. The experimental and computational results show that the surface temperature cannot be measured directly and that computer simulation results are an effective tool for obtaining accurate data on processing temperatures.

  16. A Radiative Transport Model for Heating Paints using High Density Plasma Arc Lamps

    SciTech Connect (OSTI)

    Sabau, Adrian S; Duty, Chad E; Dinwiddie, Ralph Barton; Nichols, Mark; Blue, Craig A; Ott, Ronald D

    2009-01-01

    The energy distribution and ensuing temperature evolution within paint-like systems under the influence of infrared radiation was studied. Thermal radiation effects as well as those due to heat conduction were considered. A complete set of material properties was derived and discussed. Infrared measurements were conducted to obtain experimental data for the temperature in the paint film. The heat flux of the incident radiation from the plasma arc lamp was measured using a heat flux sensor with a very short response time. The comparison between the computed and experimental results for temperature show that the models that are based on spectral four-flux RTE and accurate optical properties yield accurate results for the black paint systems.

  17. Catalyzed Nano-Framework Stablized High Density Reversible Hydrogen Storage Systems

    SciTech Connect (OSTI)

    Tang, Xia; Opalka, Susanne M.; Mosher, Daniel A; Laube, Bruce L; Brown, Ronald J; Vanderspurt, Thomas H; Arsenault, Sarah; Wu, Robert; Strickler, Jamie; Ronnebro, Ewa; Boyle, Tim; Cordaro, Joseph

    2010-06-30

    A wide range of high capacity on-board rechargeable material candidates have exhibited non-ideal behavior related to irreversible hydrogen discharge / recharge behavior, and kinetic instability or retardation. This project addresses these issues by incorporating solvated and other forms of complex metal hydrides, with an emphasis on borohydrides, into nano-scale frameworks of low density, high surface area skeleton materials to stabilize, catalyze, and control desorption product formation associated with such complex metal hydrides. A variety of framework chemistries and hydride / framework combinations were investigated to make a relatively broad assessment of the method's potential. In this project, the hydride / framework interactions were tuned to decrease desorption temperatures for highly stable compounds or increase desorption temperatures for unstable high capacity compounds, and to influence desorption product formation for improved reversibility. First principle modeling was used to explore heterogeneous catalysis of hydride reversibility by modeling H2 dissociation, hydrogen migration, and rehydrogenation. Atomic modeling also demonstrated enhanced NaTi(BH4)4 stabilization at nano-framework surfaces modified with multi-functional agents. Amine multi-functional agents were found to have more balanced interactions with nano-framework and hydride clusters than other functional groups investigated. Experimentation demonstrated that incorporation of Ca(BH4)2 and Mg(BH4)2 in aerogels enhanced hydride desorption kinetics. Carbon aerogels were identified as the most suitable nano-frameworks for hydride kinetic enhancement and high hydride loading. High loading of NaTi(BH4)4 ligand complex in SiO2 aerogel was achieved and hydride stability was improved with the aerogel. Although improvements of desorption kinetics was observed, the incorporation of Ca(BH4)2 and Mg(BH4)2 in nano-frameworks did not improve their H2 absorption due to the formation of stable alkaline earth B12H12 intermediates upon rehydrogenation. This project primarily investigated the effect of nano-framework surface chemistry on hydride properties, while the effect of pore size is the focus area of other efforts (e.g., HRL, Sandia National Laboratories (SNL) etc.) within the Metal Hydride Center of Excellence (MHCoE). The projects were complementary in gaining an overall understanding of the influence of nano-frameworks on hydride behavior.

  18. High-Density Optical Data Storage Enabled by the Photonic Nanojet from a Dielectric Microsphere

    E-Print Network [OSTI]

    Taflove, Allen

    ossless dielectric cylinders and spheres under elec- tromagnetic wave illumination can generate a narrow data- storage capacity. # 2009 The Japan Society of Applied Physics DOI: 10.1143/JJAP.48.03A008 L : 1.3) The photonic nanojet is not an evanescent wave, despite its location in the near field

  19. High density growth of T7 expression strains with auto-induction option

    DOE Patents [OSTI]

    Studier, F. William (Stony Brook, NY)

    2009-07-14

    Disclosed is a method for promoting auto-induction of transcription of cloned DNA in cultures of bacterial cells grown batchwise, the transcription being under the control of a promoter whose activity can be induced by an exogenous inducer whose ability to induce said promoter is dependent on the metabolic state of said bacterial cells. Initially, a culture media is provided which includes: i) an inducer that causes induction of transcription from said promoter in said bacterial cells; and ii) a metabolite that prevents induction by said inducer, the concentration of said metabolite being adjusted so as to substantially preclude induction by said inducer in the early stages of growth of the bacterial culture, but such that said metabolite is depleted to a level that allows induction by said inducer at a later stage of growth. The culture medium is inoculated with a bacterial inoculum, the inoculum comprising bacterial cells containing cloned DNA, the transcription of which is induced by said inducer. The culture is then incubated under conditions appropriate for growth of the bacterial cells.

  20. Conformable actively multiplexed high-density surface electrode array for brain interfacing

    SciTech Connect (OSTI)

    Rogers, John; Kim, Dae-Hyeong; Litt, Brian; Viventi, Jonathan

    2015-01-13

    Provided are methods and devices for interfacing with brain tissue, specifically for monitoring and/or actuation of spatio-temporal electrical waveforms. The device is conformable having a high electrode density and high spatial and temporal resolution. A conformable substrate supports a conformable electronic circuit and a barrier layer. Electrodes are positioned to provide electrical contact with a brain tissue. A controller monitors or actuates the electrodes, thereby interfacing with the brain tissue. In an aspect, methods are provided to monitor or actuate spatio-temporal electrical waveform over large brain surface areas by any of the devices disclosed herein.

  1. Kaon condensate with trapped neutrinos and high-density symmetry energy behavior

    E-Print Network [OSTI]

    A. Odrzywolek; M. Kutschera

    2007-03-27

    Effects of the neutrino trapping and symmetry energy behavior are investigated in the framework of the chiral Kaplan-Nelson model with kaon condensation. Decrease in the condensation threshold during deleptonization if found to be generic regardless uncertainties in the nucleon-kaon interactions and symmetry energy. Quantitatively however, differences are shown to be important

  2. CURRENT PROGRESS IN DEVELOPING A FIXED-SPRAY APPLICATION SYTEM FOR HIGH-DENSITY PLANTINGS

    E-Print Network [OSTI]

    Agnello, Arthur M.

    in high levels of disease or insect activity. Air and water pollution is a major concern due to pesticide in high residues and environmental pollution. Inaccuracy, due to over/under application, may result the operator many advantages, including reduced environmental pollution and operator contamination (Landers

  3. Optimization of a Fixed Spraying System for Commercial High-Density Apple Plantings Final Report 2007

    E-Print Network [OSTI]

    Agnello, Arthur M.

    position at one side of the planting. Pipe diameters and pump requirements were calculated based upon-Morrisville) for irrigation purposes. In 2005, the system's original design employed direct pesticide injection. Injection sprayers eliminate tank rinsing and allow rapid changes in dose rate. The main tank of the sprayer holds

  4. High density growth of T7 expression strains with auto-induction option

    DOE Patents [OSTI]

    Studier, F. William

    2013-03-19

    A method for promoting and suppressing auto-induction of transcription of a cloned gene 1 of bacteriophage T7 in cultures of bacterial cells grown batchwise is disclosed. The transcription is under the control of a promoter whose activity can be induced by an exogenous inducer whose ability to induce said promoter is dependent on the metabolic state of said bacterial cells.

  5. Power Electronic Topologies with High Density Power Conversion and Galvanic Isolation for Utility Interface 

    E-Print Network [OSTI]

    Krishnamoorthy, Harish Sarma

    2015-01-26

    the transformers, inductors and DC electrolytic capacitors. Instead of using a line frequency transformer to interface any power electronic system with the utility grid directly, it is possible to use a power converter to transform the line frequency AC into a...

  6. Vehicle Technologies Office Merit Review 2014: Design and Scalable Assembly of High Density Low Tortuosity Electrodes

    Broader source: Energy.gov [DOE]

    Presentation given by Massachusetts Institute of Technology at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about design...

  7. SubstrateSubstrate Commercially available high density -alumina plate (14x14 mm2)

    E-Print Network [OSTI]

    Azad, Abdul-Majeed

    440 450 460 470 480 490 500 510 520 530 540 OHM SubstrateSubstrate Commercially available high followed by oxidation in a well-defined pO2 regime near the M-MOx proximity line by a suitable buffer gas Model. Fig. 4. Thermodynamic criteria for several M/MOx coexistence and practical pO2 regimes for phase

  8. Shared Early Pathways of Word and Pseudoword Processing: Evidence from High-density Electrocorticography

    E-Print Network [OSTI]

    Cibelli, Emily

    2012-01-01

    for pseudowords and real words: An event-related fMRI studySpatiotemporal dynamics of word processing in the humancascaded model of visual word recognition and reading aloud.

  9. A high-density genetic map of Arachis duranensis, a diploid ancestor of cultivated peanut

    E-Print Network [OSTI]

    2012-01-01

    a diploid ancestor of cultivated peanut. BMC Genomics 2012clusters spread across the peanut genome. A higher level ofthe diploid (2n = 2x = 20) peanut species. This polymorphism

  10. Metalloboranes from first-principles calculations: A candidate for high-density hydrogen storage

    E-Print Network [OSTI]

    Akbarzadeh, A R; Tymczak, C J

    2015-01-01

    Using first principles calculations, we show the high hydrogen storage capacity of a new class of compounds, metalloboranes. Metalloboranes are transition metal (TM) and borane compounds that obey a novel-bonding scheme. We have found that the transition metal atoms can bind up to 10 H2 molecules.

  11. Vehicle Technologies Office Merit Review 2015: Design and Scalable Assembly of High Density Low Tortuosity Electrodes

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by Massachusetts Institute of Technology at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about design...

  12. A High-Density Seismic Network for Earthquake Early Warning in Taiwan

    E-Print Network [OSTI]

    Wu, Yih-Min

    -balance seismometers is extremely high. Since the 1990s, the Micro Electro Mechanical Systems (MEMS) accelerometers) that uses MEMS accelerometers for onsite earthquake early warning. The cost of the Palert device is less

  13. Turbo-alternator-compressor design for supercritical high density working fluids

    DOE Patents [OSTI]

    Wright, Steven A.; Fuller, Robert L.

    2013-03-19

    Techniques for generating power are provided. Such techniques involve a thermodynamic system including a housing, a turbine positioned in a turbine cavity of the housing, a compressor positioned in a compressor cavity of the housing, and an alternator positioned in a rotor cavity between the turbine and compressor cavities. The compressor has a high-pressure face facing an inlet of the compressor cavity and a low-pressure face on an opposite side thereof. The alternator has a rotor shaft operatively connected to the turbine and compressor, and is supported in the housing by bearings. Ridges extending from the low-pressure face of the compressor may be provided for balancing thrust across the compressor. Seals may be positioned about the alternator for selectively leaking fluid into the rotor cavity to reduce the temperature therein.

  14. Kudzu (Pueraria montana) community responses to herbicides, burning, and high-density loblolly pine

    SciTech Connect (OSTI)

    T.B. Harrington; L.T. Rader-Dixon; J.W. Taylor, Jr.

    2003-11-01

    Kudzu is an aggressive, nonnative vine that currently dominates an estimated 810,000 ha of mesic forest communities in the eastern United States. To test an integrated method of weed control, abundances of kudzu and other plant species were compared during 4 yr after six herbicide treatments (clopyralid, triclopyr, metsulfuron, picloram 1 2,4-D, tebuthiuron, and a nonsprayed check), in which loblolly pines were planted at three densities (0, 1, and 4 seedlings m22) to induce competition and potentially delay kudzu recovery. This split-plot design was replicated on each of the four kudzu-dominated sites near Aiken, SC. Relative light intensity (RLI) and soil water content (SWC) were measured periodically to identify mechanisms of interference among plant species. Two years after treatment (1999), crown coverage of kudzu averaged , 2% in herbicide plots compared with 93% in the nonsprayed check, and these differences were maintained through 2001, except in clopyralid plots where kudzu cover increased to 15%. In 2001, pine interference was associated with 33, 56, and 67% reductions in biomass of kudzu, blackberry, and herbaceous vegetation, respectively. RLI in kudzu-dominated plots (4 to 15% of full sun) generally was less than half that of herbicide-treated plots. SWC was greatest in tebuthiuron plots, where total vegetation cover averaged 26% compared with 77 to 111% in other plots. None of the treatments eradicated kudzu, but combinations of herbicides and induced pine competition delayed its recovery.

  15. COMMENTS ON ANOMALOUS EFFECTS IN CHARGING OF PD POWDERS WITH HIGH DENSITY HYDROGEN ISOTOPES

    SciTech Connect (OSTI)

    Shanahan, K.

    2009-10-01

    In Kitamura, et al, Pd-containing materials are exposed to isotopes of hydrogen and anomalous results obtained. These are claimed to be a replication of another experiment conducted by Arata and Zhang. Erroneous basic assumptions are pointed out herein that alter the derived conclusions significantly. The final conclusion is that the reported results are likely normal chemistry combined with noise. Thus the claim to have proven that cold fusion is occurring in these systems is both premature and unlikely.

  16. THE PHYSICS OF HIGH-DENSITY, HIGH-Ī² REVERSED-FIELD PINCH PLASMAS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With LivermoreSustainableDEPARTMENT OF ENERGY Office ofPHYSICS OF

  17. Particle Gas Target for High Density Laser Produced Plasmas Charles H.

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass mapSpeeding access| Department ofStephenSkinner, Nathaniel Fisch, and Ernest Valeo |

  18. Discovery of Hidden Dimensions in Information Space and Ultra-High Density

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing BacteriaConnectlaser-solidSwitchgrass|FeTe0.55Se0.45SciTech

  19. HIGH-DENSITY CIRCUMSTELLAR INTERACTION IN THE LUMINOUS TYPE IIn SN 2010jl:

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(Journal Article)lasers (Journal Article) |different scalesTHE FIRST 1100 DAYS (Journal

  20. HIGH-DENSITY, BIO-COMPATIBLE, AND HERMETIC ELECTRICAL FEEDTHROUGHS USING

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(Journal Article)lasers (Journal Article) |different scalesTHE FIRST 1100 DAYS

  1. HIGH-DENSITY, BIO-COMPATIBLE, AND HERMETIC ELECTRICAL FEEDTHROUGHS USING

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(Journal Article)lasers (Journal Article) |different scalesTHE FIRST 1100 DAYSEXTRUDED

  2. HIGH-DENSITY, BIO-COMPATIBLE, AND HERMETIC ELECTRICAL FEEDTHROUGHS USING

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(Journal Article)lasers (Journal Article) |different scalesTHE FIRST 1100

  3. HIGH-DENSITY, BIO-COMPATIBLE, AND HERMETIC ELECTRICAL FEEDTHROUGHS USING

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfate Reducing(Journal Article)lasers (Journal Article) |different scalesTHE FIRST 1100EXTRUDED METAL

  4. Solution-based approaches for making high-density sodalite waste forms to

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail. (Conference)Feedback System in the CERNimmobilize spent electrochemical salts

  5. Vehicle Technologies Office Merit Review 2015: High-Efficiency High-Density

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirley Ann Jackson About1996HowFOAShowing YouNeedofDepartmentVOICES ofEfficiencyDive

  6. Quadrilateral Cooperation on High-density Low-enriched Uranium Fuel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation of Fe(II) by Carbon-RichProton Delivery and Removal PurchasingProduction: Fact

  7. Radiation Characterization Summary: ACRR Polyethylene-Lead-Graphite (PLG) Bucket Located in the Central Cavity on the 32-Inch Pedestal at the Core Centerline (ACRR-PLG-CC-32-cl).

    SciTech Connect (OSTI)

    Parma, Edward J.,; Vehar, David W.; Lippert, Lance L.; Griffin, Patrick J.; Naranjo, Gerald E.; Luker, Spencer M.

    2015-06-01

    This document presents the facility-recommended characterization of the neutron, prompt gamma-ray, and delayed gamma-ray radiation fields in the Annular Core Research Reactor (ACRR) for the polyethylene-lead-graphite (PLG) bucket in the central cavity on the 32-inch pedestal at the core centerline. The designation for this environment is ACRR-PLG-CC-32-cl. The neutron, prompt gamma-ray, and delayed gamma-ray energy spectra, uncertainties, and covariance matrices are presented as well as radial and axial neutron and gamma-ray fluence profiles within the experiment area of the bucket. Recommended constants are given to facilitate the conversion of various dosimetry readings into radiation metrics desired by experimenters. Representative pulse operations are presented with conversion examples. Acknowledgements The authors wish to thank the Annular Core Research Reactor staff and the Radiation Metrology Laboratory staff for their support of this work. Also thanks to David Ames for his assistance in running MCNP on the Sandia parallel machines.

  8. AREVA NP next generation fresh UO{sub 2} fuel assembly shipping cask: SCALE - CRISTAL comparisons lead to safety criticality confidence

    SciTech Connect (OSTI)

    Doucet, M.; Landrieu, M.; Montgomery, R.; O' Donnell, B.

    2007-07-01

    AREVA NP as a worldwide PWR fuel provider has to have a fleet of fresh UO{sub 2} shipping casks being agreed within a lot of countries including USA, France, Germany, Belgium, Sweden, China, and South Africa - and to accommodate foreseen EPR Nuclear Power Plants fuel buildings. To reach this target the AREVA NP Fuel Sector decided to develop an up-to-date shipping cask (so called MAP project) gathering experience feedback of the today fleet and an improved safety allowing the design to comply with international regulations (NRC and IAEA) and local Safety Authorities. Based on pre design features a safety case was set up to highlight safety margins. Criticality hypothetical accidental assumptions were defined: - Preferential flooding; - Fuel rod lattice pitch expansion for full length of fuel assemblies; - Neutron absorber penalty; -... Well known computer codes, American SCALE package and French CRISTAL package, were used to check configurations reactivity and to ensure that both codes lead to coherent results. Basic spectral calculations are based on similar algorithms with specific microscopic cross sections ENDF/BV for SCALE and JEF2.2 for CRISTAL. The main differences between the two packages is on one hand SCALE's three dimensional fuel assembly geometry is described by a pin by pin model while an homogenized fuel assembly description is used by CRISTAL and on the other hand SCALE is working with either 44 or 238 neutron energy groups while CRISTAL is with a 172 neutron energy groups. Those two computer packages rely on a wide validation process helping defining uncertainties as required by regulations in force. The shipping cask with two fuel assemblies is designed to maximize fuel isolation inside a cask and with neighboring ones even for large array configuration cases. Proven industrial products are used: - Boral{sup TM} as neutron absorber; - High density polyethylene (HDPE) or Nylon as neutron moderator; - Foam as thermal and mechanical protection. The cask is designed to handle the complete AREVA NP fuel assembly types from the 14x14 to the 18x18 design with a {sup 235}U enrichment up to 5.0% enriched natural uranium (ENU) and enriched reprocessed uranium (ERU). After a brief presentation of the computer codes and the description of the shipping cask, calculation results and comparisons between SCALE and CRISTAL will be discussed. (authors)

  9. UV degradation of hdpe and pvc geomembranes in laboratory exposure So Paulo State University (UNESP) -Ilha Solteira (Brazil)

    E-Print Network [OSTI]

    Zornberg, Jorge G.

    University (UNESP) - Ilha Solteira (Brazil) Bueno, B.S. University of State of Sćo Paulo (USP) at Sćo Carlos (Brazil) Zornberg, J.G. University of Texas (UT) at Austin (USA) Keywords: UV degradation, weathering International Conference on Geosynthetics, Brazil, 2010 821 3 #12;were used like a guide: ASTM D638 (Standard

  10. Polarizer design for millimeter-wave plasma diagnostics

    SciTech Connect (OSTI)

    Leipold, F.; Salewski, M.; Jacobsen, A. S.; Jessen, M.; Korsholm, S. B.; Michelsen, P. K.; Nielsen, S. K.; Stejner, M. [Department of Physics, Technical University of Denmark, DK-4000 Roskilde (Denmark)] [Department of Physics, Technical University of Denmark, DK-4000 Roskilde (Denmark)

    2013-08-15

    Radiation from magnetized plasmas is in general elliptically polarized. In order to convert the elliptical polarization to linear polarization, mirrors with grooved surfaces are currently employed in our collective Thomson scattering diagnostic at ASDEX Upgrade. If these mirrors can be substituted by birefringent windows, the microwave receivers can be designed to be more compact at lower cost. Sapphire windows (a-cut) as well as grooved high density polyethylene windows can serve this purpose. The sapphire window can be designed such that the calculated transmission of the wave energy is better than 99%, and that of the high density polyethylene can be better than 97%.

  11. Polyelectrolyte Multilayers Containing Polyethylene-based Ionomers 

    E-Print Network [OSTI]

    Huang, Hsiu-Chin

    2014-08-14

    Layer-by-Layer (LbL) assembly technique is a powerful approach to blend two or more materials to form new materials of thin films on any type of substrate, and the LbL film is called polyelectrolyte multilayers (PEMs). The assemblies are highly...

  12. Recycling and alloying of polyethylene terephthalate 

    E-Print Network [OSTI]

    Bugg, Marie Sandra

    1988-01-01

    polymeric material so as to align its chains parallel to a preferred direction. For most polymers this improves tensile strength, toughness, and flexibility, and decreases the gas and moisture permeability [5]. Orientation may be uniaxial or biaxial...-wall thickness profile [23]. 23 fBI ( t. 0) UNIAXIAL MACHINE DIRECTION PLANAR EQUAL BIAXIAL UNIAXIAL TRANSVERSE DIRECTION (D. t) ISOTROPIC Figure 7 Orientation Triangle Adapted from White and Agarwal (1981) t 1 8] 24 fBy 0, 0 0, 6 -0 6 -0. 6...

  13. High Density n-Si/n-TiO2 Core/Shell Nanowire Arrays with Enhanced Photoactivity

    E-Print Network [OSTI]

    Hwang, Yun Jeong

    2009-01-01

    19) Gerischer, H. Solar Energy Conversion; Springer Berlin:TEXT Direct solar energy conversion to storable fuels suchits conversion efficiency of solar energy to hydrogen is

  14. High Density n-Si/n-TiO2 Core/Shell Nanowire Arrays with Enhanced Photoactivity

    SciTech Connect (OSTI)

    Hwang, Yun Jeong; Boukai, Akram; Yang, Peidong

    2008-11-15

    There are currently great needs to develop low-cost inorganic materials that can efficiently perform solar water splitting as photoelectrolysis of water into hydrogen and oxygen has significant potential to provide clean energy. We investigate the Si/TiO2 nanowire heterostructures to determine their potential for the photooxidation of water. We observed that highly dense Si/TiO2 core/shell nanowire arrays enhanced the photocurrent by 2.5 times compared to planar Si/TiO2 structure due to their low reflectance and high surface area. We also showed that n-Si/n-TiO2 nanowire arrays exhibited a larger photocurrent and open circuit voltage than p-Si/n-TiO2 nanowires due to a barrier at the heterojunction.

  15. Courtyard housing, a solution for high-density, low-rise single-family housing in the U.S.

    E-Print Network [OSTI]

    Morton, Everett L. (Everett Livingston)

    1990-01-01

    This thesis examines the potential application of the L-shaped courtyard house in an American context. Privacy for the dwelling and its grounds is a key issue to be addressed. It is shown than a traditional single-family ...

  16. IEEE TRANSACTIONS ON BIOMEDICAL ENGINEERING, VOL. 46, NO. 4, APRIL 1999 471 A Modular Micromachined High-Density Connector

    E-Print Network [OSTI]

    Akin, Tayfun

    have also confirmed the establishment of multiple contacts and have produced simultaneous biopotential

  17. Design of low-power permanent-magnet synchronous motor for use in high-density heat pump

    E-Print Network [OSTI]

    Jenicek, David P. (David Pierre)

    2011-01-01

    An analytical model for the functionality of a permanent-magnet synchronous motor is developed. Taking as input a specific geometry, it predicts steady-state losses of a design at an average rate of 0.85 seconds per analysis, ...

  18. Use of high-density tiling microarrays to identify mutations globally and elucidate mechanisms of drug resistance in Plasmodium falciparum

    E-Print Network [OSTI]

    Dharia, Neekesh V

    Background: The identification of genetic changes that confer drug resistance or other phenotypic changes in pathogens can help optimize treatment strategies, support the development of new therapeutic agents, and provide ...

  19. Determination of the respective density distributions of low-and high-density lipoprotein particles in bovine plasma

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    .006-1.210 g/ml were separated by density gradient ultracentrifugation into 25 fractions. Their respective apo-I and apo B. Gradient distributions of apo A-I (d 1.046-1.180 g/ml; max at d 1.080 g/ml) and apo B (d 1: Intestinal Lipid and Lipoprotein Metabolism (Windler E, Greten H, eds), W Zuckschwerdt Verlag, Munchen, 50

  20. Different methods for particle diameter determination of low density and high density lipoproteins-Comparison and evaluation 

    E-Print Network [OSTI]

    Vaidyanathan, Vidya

    2009-05-15

    ) Evaluating the two methods in terms of their ability to identify bi-modal samples. A secondary purpose of this research was to investigate the effect of refrigerated plasma storage on particle diameter. Reproducibility was measured as Coefficient of Variance...

  1. Permanent magnet machine and method with reluctance poles and non-identical PM poles for high density operation

    SciTech Connect (OSTI)

    Hsu, John S.

    2010-05-18

    A method and apparatus in which a stator (11) and a rotor (12) define a primary air gap (20) for receiving AC flux and at least one source (23, 40), and preferably two sources (23, 24, 40) of DC excitation are positioned for inducing DC flux at opposite ends of the rotor (12). Portions of PM material (17, 17a) are provided as boundaries separating PM rotor pole portions from each other and from reluctance poles. The PM poles (18) and the reluctance poles (19) can be formed with poles of one polarity having enlarged flux paths in relation to flux paths for pole portions of an opposite polarity, the enlarged flux paths communicating with a core of the rotor (12) so as to increase reluctance torque produced by the electric machine. Reluctance torque is increased by providing asymmetrical pole faces. The DC excitation can also use asymmetric poles and asymmetric excitation sources. Several embodiments are disclosed with additional variations.

  2. Photovoltaic devices based on high density boron-doped single-walled carbon nanotube/n-Si heterojunctions

    SciTech Connect (OSTI)

    Saini, Viney [Univ. of Arkansas at Little Rock, Little Rock, AR (United States) Dept. of Applied Science; Li, Zhongrui [Univ. of Arkansas at Little Rock, Little Rock, AR (United States) Dept. of Applied Science; Bourdo, Shawn [Univ. of Arkansas at Little Rock, Little Rock, AR (United States) Dept. of Applied Science; Univ. of Arkansas at Little Rock, Little Rock, AR (United States) Dept. of Chemistry; Kunets, Vasyl P. [Univ. of Arkansas, Fayetteville, AR (United States) Dept. of Physics; Trigwell, Steven [NASA Kennedy Space Center, FL (United States); Couraud, Arthur [Univ. of Arkansas at Little Rock, Little Rock, AR (United States) Dept. of Applied Science; Ecole d'Ingenieurs du CESI-EIA, La Couronne (France); Rioux, Julien [Univ. of Arkansas at Little Rock, Little Rock, AR (United States) Dept. of Applied Science; Ecole d'Ingenieurs du CESI-EIA, La Couronne (France); Boyer, Cyril [Univ. of Arkansas at Little Rock, Little Rock, AR (United States) Dept. of Applied Science; Ecole d'Ingenieurs du CESI-EIA, La Couronne (France); Nteziyaremye, Valens [Univ. of Arkansas at Little Rock, Little Rock, AR (United States) Dept. of Applied Science; Dervishi, Enkeleda [Univ. of Arkansas at Little Rock, Little Rock, AR (United States) Dept. of Applied Science; Biris, Alexandru R. [National Institute for Research and Development of Isotopic and Molecular Technologies, Cluj-Napoca (Romania); Salamo, Gregory J. [Univ. of Arkansas, Fayetteville, AR (United States) Dept. of Physics; Viswanathan, Tito [Univ. of Arkansas at Little Rock, Little Rock, AR (United States) Dept. of Chemistry; Biris, Alexandru S. [Univ. of Arkansas at Little Rock, Little Rock, AR (United States) Dept. of Applied Science

    2011-01-01

    A simple and easily processible photovoltaic device has been developed based on borondoped single-walled carbon nanotubes (B-SWNTs) and n-type silicon (n-Si) heterojunctions. The single-walled carbon nanotubes (SWNTs) were substitutionally doped with boron atoms by thermal annealing, in the presence of B2O3. The samples used for these studies were characterized by Raman spectroscopy, thermal gravimetric analysis (TGA), transmission electron microscopy (TEM), and x-ray photoelectron spectroscopy (XPS). The fully functional solar cell devices were fabricated by airbrush deposition that generated uniform B-SWNT films on top of the n-Si substrates. The carbon nanotube films acted as exciton-generation sites, charge collection and transportation, while the heterojunctions formed between B-SWNTs and n-Si acted as charge dissociation centers. The current-voltage characteristics in the absence of light and under illumination, as well as optical transmittance spectrum are reported here. It should be noted that the device fabrication process can be made amenable to scalability by depositing direct and uniform films using airbrushing, inkjet printing, or spin-coating techniques.

  3. Controlled Assembly of High Density SWNT Networks on a Flexible Parylene-C C.-L. Chen1,*

    E-Print Network [OSTI]

    Dokmeci, Mehmet

    substrates has immediate applications in wearable electronics and sensors, flexible field effect transistors desirable to fabricate integrated nanotube- polymer flexible electronic devices at room temperature devices on flexible substrates potentially useful in numerous fields including flexible electronics

  4. HIGH-DENSITY CIRCUMSTELLAR INTERACTION IN THE LUMINOUS TYPE IIn SN 2010jl: THE FIRST 1100 DAYS

    SciTech Connect (OSTI)

    Fransson, Claes; Ergon, Mattias; Sollerman, Jesper [Oskar Klein Centre, Department of Astronomy, Stockholm University, AlbaNova, SE-106 91 Stockholm (Sweden); Challis, Peter J.; Kirshner, Robert P.; Marion, G. H.; Milisavljevic, Dan; Friedman, Andrew S.; Chornock, Ryan; Czekala, Ian; Soderberg, Alicia [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Chevalier, Roger A. [Department of Astronomy, University of Virginia, P.O. Box 400325, Charlottesville, VA 22904 (United States); France, Kevin [CASA, University of Colorado, 593UCB Boulder, CO 80309-0593 (United States); Smith, Nathan [Steward Observatory, University of Arizona, 933 North Cherry Avenue, Tucson, AZ 85721 (United States); Bufano, Filomena [Departamento de Ciencias Fisicas, Universidad Andres Bello, Avda. Republica 252, Santiago (Chile); Kangas, Tuomas [Tuorla Observatory, University of Turku, Väisäläntie 20 FI-21500 Piikkiö (Finland); Larsson, Josefin [KTH, Department of Physics, and the Oskar Klein Centre, AlbaNova, SE-106 91 Stockholm (Sweden); Mattila, Seppo [Finnish Centre for Astronomy with ESO (FINCA), University of Turku, Väisäläntie 20 FI-21500 Piikkiö (Finland); Benetti, Stefano [INAF-Osservatorio Astronomico di Padova, Vicolo dellOsservatorio 5, I-35122 Padova (Italy)

    2014-12-20

    Hubble Space Telescope and ground-based observations of the Type IIn supernova (SN) 2010jl are analyzed, including photometry and spectroscopy in the ultraviolet, optical, and near-IR bands, 26-1128 days after first detection. At maximum, the bolometric luminosity was ?3 × 10{sup 43} erg s{sup –1} and even at 850 days exceeds 10{sup 42} erg s{sup –1}. A near-IR excess, dominating after 400 days, probably originates in dust in the circumstellar medium (CSM). The total radiated energy is ? 6.5 × 10{sup 50} erg, excluding the dust component. The spectral lines can be separated into one broad component that is due to electron scattering and one narrow with expansion velocity ?100 km s{sup –1} from the CSM. The broad component is initially symmetric around zero velocity but becomes blueshifted after ?50 days, while remaining symmetric about a shifted centroid velocity. Dust absorption in the ejecta is unlikely to explain the line shifts, and we attribute the shift instead to acceleration by the SN radiation. From the optical lines and the X-ray and dust properties, there is strong evidence for large-scale asymmetries in the CSM. The ultraviolet lines indicate CNO processing in the progenitor, while the optical shows a number of narrow coronal lines excited by the X-rays. The bolometric light curve is consistent with a radiative shock in an r {sup –2} CSM with a mass-loss rate of M-dot ?0.1  M{sub ?} yr{sup ?1}. The total mass lost is ? 3 M {sub ?}. These properties are consistent with the SN expanding into a CSM characteristic of a luminous blue variable progenitor with a bipolar geometry. The apparent absence of nuclear processing is attributed to a CSM that is still opaque to electron scattering.

  5. The high-density Z-pinch as a pulsed fusion neutron source for fusion nuclear technology and materials testing

    SciTech Connect (OSTI)

    Krakowski, R.A.; Sethian, J.D.; Hagenson, R.L.

    1989-01-01

    The dense Z-pinch (DZP) is one of the earliest and simplest plasma heating and confinement schemes. Recent experimental advances based on plasma initiation from hair-like (10s ..mu..m in radius) solid hydrogen filaments have so far not encountered the usually devastating MHD instabilities that plagued early DZP experiments. These encouraging results along with debt of a number of proof-of principle, high-current (1--2 MA in 10--100 ns) experiments have prompted consideration of the DZP as a pulsed source of DT fusion neutrons of sufficient strength (/dot S//sub N/ greater than or equal to 10/sup 19/ n/s) to provide uncollided neutron fluxes in excess of I/sub ..omega../ = 5--10 MW/m/sup 2/ over test volumes of 10--30 litre or greater. While this neutron source would be pulsed (100s ns pulse widths, 10--100 Hz pulse rate), giving flux time compressions in the range 10/sup 5/--10/sup 6/, its simplicity, near-time feasibility, low cost, high-Q operation, and relevance to fusion systems that may provide a pulsed commercial end-product (e.g., inertial confinement or the DZP itself) together create the impetus for preliminary considerations as a neutron source for fusion nuclear technology and materials testings. The results of a preliminary parametric systems study (focusing primarily on physics issues), conceptual design, and cost versus performance analyses are presented. The DZP promises an expensive and efficient means to provide pulsed DT neutrons at an average rate in excess of 10/sup 19/ n/s, with neutron currents I/sub ..omega../ /approx lt/ 10 MW/m/sup 2/ over volumes V/sub exp/ greater than or equal to 30 litre using single-pulse technologies that differ little from those being used in present-day experiments. 34 refs., 17 figs., 6 tabs.

  6. FORMALDEHYDE AND METHANOL DEUTERATION IN PROTOSTARS: FOSSILS FROM A PAST FAST HIGH-DENSITY PRE-COLLAPSE PHASE

    SciTech Connect (OSTI)

    Taquet, V.; Ceccarelli, C.; Kahane, C. [UJF-Grenoble 1/CNRS-INSU, Institut de Planetologie et d'Astrophysique de Grenoble (IPAG) UMR 5274, F-38041 Grenoble (France)

    2012-03-20

    Extremely high deuteration of several molecules has been observed around low-mass protostars for a decade. Among them, formaldehyde and methanol present particularly high deuteration, with observations of abundant doubly and triply deuterated forms. Both species are thought to be mainly formed on interstellar grains during the low-temperature and dense pre-collapse phase by H and D atom additions on the iced CO. We present here a theoretical study of the formaldehyde and methanol deuteration obtained with our gas-grain model, GRAINOBLE. This model takes into account the multilayer nature of the mantle and explores the robustness of the results against the uncertainties of poorly constrained chemical and surface model parameters. The comparison of the model predictions with the observations leads to two major results: (1) the observed high deuteration is obtained during the last phase of the pre-collapse stage, when the density reaches {approx}5 Multiplication-Sign 10{sup 6} cm{sup -3}, and this phase is fast, lasting only several thousands years; and (2) D and H abstraction and substitution reactions are crucial in making up the observed deuteration ratios. This work shows the power of chemical composition as a tool to reconstruct the past history of protostars.

  7. Characterising the secondary structure changes occurring in high density systems of BLG dissolved in aqueous pH 3 buffer

    E-Print Network [OSTI]

    Ioannou, J. C.; Donald, A. M.; Tromp, R. H.

    2014-12-31

    in the mouth (i.e. feeling dry and hard to pro- cess). This is part of the reason why many high-protein food for- mulations have to be structured by adding starch and/or oil. Therefore, in-depth knowledge of protein folding/unfolding which can relate... . It illustrates the changes in sub-band peak intensity of the five main ascribed J.C. Ioannou et al. / Food Hydrocolloids 46 (2015) 216e225 221was firstly buffer-corrected by subtracting out the buffer signal and background noise spectrum. Each data spectrum...

  8. Optimization of a Fixed Spraying System for Commercial High-Density Apple Plantings Arthur Agnello and Andrew Landers

    E-Print Network [OSTI]

    Agnello, Arthur M.

    position at one side of the planting. Pipe diameters and pump requirements were calculated #12;based upon-Morrisville) for irrigation purposes. In 2005, the system's original design employed direct pesticide injection. Injection sprayers eliminate tank rinsing and allow rapid changes in dose rate. The main tank of the sprayer holds

  9. PROBING THE TRUNCATION OF GALAXY DARK MATTER HALOS IN HIGH-DENSITY ENVIRONMENTS FROM HYDRODYNAMICAL N-BODY SIMULATIONS

    SciTech Connect (OSTI)

    Limousin, Marceau; Sommer-Larsen, Jesper; Milvang-Jensen, Bo [Dark Cosmology Centre, Niels Bohr Institute, University of Copenhagen, Juliane Maries Vej 30, 2100 Copenhagen (Denmark); Natarajan, Priyamvada [Astronomy Department, Yale University, P.O. Box 208101, New Haven, CT 06520-8101 (United States)], E-mail: marceau.limousin@oamp.fr

    2009-05-10

    We analyze high-resolution, N-body hydrodynamical simulations of fiducial galaxy clusters to probe tidal stripping of the dark matter subhalos. These simulations include a prescription for star formation allowing us to track the fate of the stellar component as well. We investigate the effect of tidal stripping on cluster galaxies hosted in these dark matter subhalos as a function of projected cluster-centric radius. To quantify the extent of the dark matter halos of cluster galaxies, we introduce the half-mass radius r {sub 1/2} as a diagnostic, and study its evolution with projected cluster-centric distance R as a function of redshift. We find a well-defined trend for (r {sub 1/2}, R): the closer the galaxies are to the center of the cluster, the smaller the half-mass radius. Interestingly, this trend is inferred in all redshift frames examined in this work ranging from z = 0 to z = 0.7. At z = 0, galaxy halos in the central regions of clusters are found to be highly truncated, with the most compact half-mass radius of 10 kpc. We also find that r {sub 1/2} depends on luminosity and we present scaling relations of r {sub 1/2} with galaxy luminosity. The corresponding total mass of the cluster galaxies is also found to increase with projected cluster-centric distance and luminosity, but with more scatter than the (r {sub 1/2}, R) trend. Comparing the distribution of stellar mass to total mass for cluster galaxies, we find that the dark matter component is preferentially stripped, whereas the stellar component is much less affected by tidal forces. We compare these results with galaxy-galaxy lensing probes of r {sub 1/2} and find qualitative agreement. Future surveys with space-based telescopes such as DUNE and SNAP, that combine wide-field and high-resolution imaging, will be able to probe the predicted (r {sub 1/2}, R) relation observationally.

  10. Nanocomposites for ultra high density information storage, devices including the same, and methods of making the same

    DOE Patents [OSTI]

    Goyal, Amit; Shin, Junsoo

    2014-04-01

    A nanocomposite article that includes a single-crystal or single-crystal-like substrate and heteroepitaxial, phase-separated layer supported by a surface of the substrate and a method of making the same are described. The heteroepitaxial layer can include a continuous, non-magnetic, crystalline, matrix phase, and an ordered, magnetic magnetic phase disposed within the matrix phase. The ordered magnetic phase can include a plurality of self-assembled crystalline nanostructures of a magnetic material. The phase-separated layer and the single crystal substrate can be separated by a buffer layer. An electronic storage device that includes a read-write head and a nanocomposite article with a data storage density of 0.75 Tb/in.sup.2 is also described.

  11. Advanced Metal-Hydrides-Based Thermal Battery: A New Generation of High Density Thermal Battery Based on Advanced Metal Hydrides

    SciTech Connect (OSTI)

    2011-12-01

    HEATS Project: The University of Utah is developing a compact hot-and-cold thermal battery using advanced metal hydrides that could offer efficient climate control system for EVs. The team’s innovative designs of heating and cooling systems for EVs with high energy density, low-cost thermal batteries could significantly reduce the weight and eliminate the space constraint in automobiles. The thermal battery can be charged by plugging it into an electrical outlet while charging the electric battery and it produces heat and cold through a heat exchanger when discharging. The ultimate goal of the project is a climate-controlling thermal battery that can last up to 5,000 charge and discharge cycles while substantially increasing the driving range of EVs, thus reducing the drain on electric batteries.

  12. Multi-dimensional collective effects in high-current relativistic beams relevant to High Density Laboratory Plasmas

    SciTech Connect (OSTI)

    Shvets, Gennady

    2014-05-09

    In summary, an analytical model describing the self-pinching of a relativistic charge-neutralized electron beam undergoing the collisionless Weibel instability in an overdense plasma has been developed. The model accurately predicts the final temperature and size of the self-focused filament. It is found that the final temperature is primarily defined by the total beam’s current, while the filament’s radius is shown to be smaller than the collisionless skin depth in the plasma and primarily determined by the beam’s initial size. The model also accurately predicts the repartitioning ratio of the initial energy of the beam’s forward motion into the magnetic field energy and the kinetic energy of the surrounding plasma. The density profile of the final filament is shown to be a superposition of the standard Bennett pinch profile and a wide halo surrounding the pinch, which contains a significant fraction of the beam’s electrons. PIC simulations confirm the key assumption of the analytic theory: the collisionless merger of multiple current filaments in the course of the Weibel Instability provides the mechanism for Maxwellization of the beam’s distribution function. Deviations from the Maxwell-Boltzmann distribution are explained by incomplete thermalization of the deeply trapped and halo electrons. It is conjectured that the simple expression derived here can be used for understanding collsionless shock acceleration and magnetic field amplification in astrophysical plasmas.

  13. REDUCING THE ENVIRONMENTAL IMPACT OF HIGH-DENSITY FISH PRODUCTION: AN INTEGRATED APPROACH TO SOLIDS TREATMENT FOR RECIRCULATING

    E-Print Network [OSTI]

    waste discharges, improve quality control, and reduce costs. The crucial processes that must aquaculture systems (RASs) allow for systematic optimization of the environmental variables that control that integrate two or more of these processes. Expandable granular biofilters (EGBs) integrate solids capture

  14. Formaldehyde and methanol deuteration in protostars: fossiles from a past fast high density pre-collapse phase

    E-Print Network [OSTI]

    Taquet, Vianney; Kahane, Claudine

    2012-01-01

    Extremely high deuteration of several molecules have been observed around low mass protostars since a decade. Among them, formaldehyde and methanol present particularly high deuteration, with observations of abundant doubly and triply deuterated forms. Both species are thought to be mainly formed on interstellar grains during the low temperature and dense pre-collapse phase by H and D atom additions on the iced CO. We present here a theoretical study of the formaldehyde and methanol deuteration obtained with our gas-grain model, GRAINOBLE. This model takes into account the multilayer nature of the mantle and explores the robustness of the results against the uncertainties of poorly constrained chemical and surface model parameters. The comparison of the model predictions with the observations leads to two major results: i) the observed high deuteration is obtained during the last phase of the pre-collapse stage, when the density reaches 5 10^6 cm^-3, and this phase is fast, lasting only several thousands year...

  15. Photovoltaic devices based on high density boron-doped single-walled carbon nanotube/n-Si heterojunctions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Saini, Viney [Univ. of Arkansas, Little Rock, AR (United States); Li, Zhongrui [Univ. of Arkansas, Little Rock, AR (United States); Bourdo, Shawn [Univ. of Arkansas, Little Rock, AR (United States); Kunets, Vasyl P. [Univ. of Arkansas, Fayetteville, AR (United States); Trigwell, Steven [ASRC Aerospace Corp., Kennedy Space Center, FL (United States); Couraud, Arthur [Univ. of Arkansas, Little Rock, AR (United States) and Ecole d'Ingenieurs de CESI-EIA, La Couronne (France); Rioux, Julien [Univ. of Arkansas, Little Rock, AR (United States) and Ecole d'Ingenieurs du CESI-EIA, La Couronne (France); Boyer, Cyril [Univ. of Arkansas, Little Rock, AR (United States) and Ecole d'Ingenieurs du CESI-EIA, La Couronne (France); Nteziyaremye, Valens [Univ. of Arkansas, Little Rock, AR (United States); Dervishi, Enkeleda [Univ. of Arkansas, Little Rock, AR (United States); Biris, Alexandru R. [National Institute for Research and Development of Isotopic and Molecular Technologies, Cluj-Napoca (Romania); Salamo, Gregory J. [Univ. of Arkansas, Fayetteville, AR (United States); Viswanathan, Tito [Univ. of Arkansas, Little Rock, AR (United States); Biris, Alexandru S. [Univ. of Arkansas, Little Rock, AR (United States)

    2011-01-13

    A simple and easily processible photovoltaic device has been developed based on borondoped single-walled carbon nanotubes (B-SWNTs) and n-type silicon (n-Si) heterojunctions. The single-walled carbon nanotubes (SWNTs) were substitutionally doped with boron atoms by thermal annealing, in the presence of B2O3. The samples used for these studies were characterized by Raman spectroscopy, thermal gravimetric analysis (TGA), transmission electron microscopy (TEM), and x-ray photoelectron spectroscopy (XPS). The fully functional solar cell devices were fabricated by airbrush deposition that generated uniform B-SWNT films on top of the n-Si substrates. The carbon nanotube films acted as exciton-generation sites, charge collection and transportation, while the heterojunctions formed between B-SWNTs and n-Si acted as charge dissociation centers. The current-voltage characteristics in the absence of light and under illumination, as well as optical transmittance spectrum are reported here. It should be noted that the device fabrication process can be made amenable to scalability by depositing direct and uniform films using airbrushing, inkjet printing, or spin-coating techniques.

  16. 572 OPTICS LETTERS / Vol. 25, No. 8 / April 15, 2000 Subhertz spectral fluctuations from high-density

    E-Print Network [OSTI]

    Snoke, David

    low-frequency fluctuations at high excitation density. These were also interpreted as critical of the indirect excitons shifts strongly with electric field because of the quantum-confined Stark effect to record movies of the luminescence spec- trum in real time. In this way we observed a dra- matic onset

  17. Determination of the fracture parameters associated with mixed mode displacement fields and applications of high density geometric moire 

    E-Print Network [OSTI]

    Kmiec, Kenneth James

    1994-01-01

    . The analyses of the finite element models indicated that the algorithm developed could be used to determine the opening and shear mode fracture parameters, without being affected by the rigid body rotation. The numerical experiments demonstrated...

  18. The use of electrochemical sensors for monitoring urban air quality in low-cost, high-density networks.

    E-Print Network [OSTI]

    Mead, M. I.; Popoola, O. A. M.; Stewart, G. B.; Landshoff, P.; Calleja, M.; Hayes, M.; Baldovi, J. J.; Hodgson, T. F.; McLeod, M. W.; Dicks, J.; Lewis, A.; Cohen, J.; Baron, R.; Saffell, J. R.; Jones, R. L.

    interference, although there is still a downward bias of ~ 20%. ECC Sensor NO gain NO R2 NO2 gradient (uncorrected) NO2 gradient (corrected) NO2 R2 1 0.97 ± 0.04 0.80 0.36 ± 0.02 0.81 ± 0.03 0.89 2 1.00 ± 0.06 0.95 0.38 ± 0.02 0.81 ± 0.03 0.92 Table 3... . R. Saffell6, and R. L. Jones1*. 1 University Chemical Laboratory, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, UK. 2 Cambridge eScience Centre, Cavendish Laboratory, J. J. Thomson Avenue, Cambridge, CB3 0HE, UK. 3 Centre...

  19. Photovoltaic devices based on high density boron-doped single-walled carbon nanotube/n-Si heterojunctions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Saini, Viney; Li, Zhongrui; Bourdo, Shawn; Kunets, Vasyl P.; Trigwell, Steven; Couraud, Arthur; Ecole d'Ingenieurs du CESI-EIA, La Couronne; Rioux, Julien; Ecole d'Ingenieurs du CESI-EIA, La Couronne; Boyer, Cyril; et al

    2011-01-13

    A simple and easily processible photovoltaic device has been developed based on borondoped single-walled carbon nanotubes (B-SWNTs) and n-type silicon (n-Si) heterojunctions. The single-walled carbon nanotubes (SWNTs) were substitutionally doped with boron atoms by thermal annealing, in the presence of B2O3. The samples used for these studies were characterized by Raman spectroscopy, thermal gravimetric analysis (TGA), transmission electron microscopy (TEM), and x-ray photoelectron spectroscopy (XPS). The fully functional solar cell devices were fabricated by airbrush deposition that generated uniform B-SWNT films on top of the n-Si substrates. The carbon nanotube films acted as exciton-generation sites, charge collection and transportation, whilemore »the heterojunctions formed between B-SWNTs and n-Si acted as charge dissociation centers. The current-voltage characteristics in the absence of light and under illumination, as well as optical transmittance spectrum are reported here. It should be noted that the device fabrication process can be made amenable to scalability by depositing direct and uniform films using airbrushing, inkjet printing, or spin-coating techniques.« less

  20. LANAI HIGH-DENSITY IRRADIANCE SENSOR NETWORK FOR CHARACTERIZING SOLAR RESOURCE VARIABILITY OF MW-SCALE PV SYSTEM

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverseIMPACTThousand Cubic Feet)MultimaterialforLAESF

  1. Version 3.0 SOP 7 --October 12, 2007 (DOC) (TDN)

    E-Print Network [OSTI]

    ). (grease) . 6.1 60 ml (HDPE) 10% 4 . polycarbonate inline filter filter holder 60 ml HDPE . HDPE , Niskin - . filter holder . . 75 90 Reference Water (www.rsmas.miami.edu/groups/biogeochem/ CRM.html) . Sargasso (DSR) 10 ml . DOC

  2. Use of a unique mode switch test for the measurement of nonlinear viscoelastic shear properties of HDPE programmed-parison blow molding resins 

    E-Print Network [OSTI]

    Stanfill, Karen Anne Owens

    1992-01-01

    student and for his conversations about foreign lands and family life. I appreciate the support of Dow Chemical in this research. I must also acknowledge primarily the National Science Foundation as well as the E. I. DuPont Company and Texas A&M College... appreciated. In class and in meetings, he was invariably careful to make sure I and other students thoroughly understood his explanations. His suggestions for solving problems were always quite helpful. A number of other people provided assistance...

  3. High density and ligand affinity confer ultrasensitive signal detection by a guanylyl cyclase chemoreceptor Magdalena Pichlo, Stefanie Bungert-Plmke, Ingo Weyand, Reinhard Seifert, Wolfgang Bnigk, Timo Strnker,

    E-Print Network [OSTI]

    Enderlein, Jörg

    ,5-monophosphate; CNG, cyclic nucleotide gated; CNGK, K+ -selective CNG channel; GC, guanylyl cyclase; IBMX, 3

  4. Negative quasiclassical magnetoresistance in a high density two-dimensional electron gas in a AlxGa1-xN/GaN heterostructure

    E-Print Network [OSTI]

    Gusev, Guennady

    , Brazil Z. D. Kvon Institute of Semiconductor Physics, Novosibirsk, Russia V. T. Renard GHMFL, BP-166, F University, 1370, Sankyuk-Dong, Daegu C.P.702-701, Korea J-C. Portal GHMFL, BP-166, F-38042, Grenoble, Cedex

  5. Simulation of a two-dimensional sheath over a flat insulatorconductor interface on a radio-frequency biased electrode in a high-density plasma

    E-Print Network [OSTI]

    Economou, Demetre J.

    Simulation of a two-dimensional sheath over a flat insulator­conductor interface on a radio-frequency the two-dimensional 2D sheath over a flat insulator/conductor interface on a radio-frequency rf biased is no longer one dimen- sional. The extent of sheath ``disturbance'' depends on the thickness of the sheath

  6. High-Temperature SiC Power Module with Integrated SiC Gate Drivers for Future High-Density Power Electronics Applications

    SciTech Connect (OSTI)

    Whitaker, Mr. Bret [APEI, Inc.; Cole, Mr. Zach [APEI, Inc.; Passmore, Mr. Brandon [APEI, Inc.; Mcnutt, Tyler [APEI, Inc.; Lostetter, Dr. Alex [APEI, Inc.; Ericson, Milton Nance [ORNL; Frank, Steven [ORNL; Britton Jr, Charles L [ORNL; Marlino, Laura D [ORNL; Mantooth, Alan [University of Arkansas; Francis, Matt [APEI, Inc.; Lamichhane, Ranjan [APEI, Inc.; Shepherd, Paul [APEI, Inc.; Glover, Michael [APEI, Inc.

    2014-01-01

    This paper presents a high-temperature capable intelligent power module that contains SiC power devices and SiC gate driver integrated circuits (ICs). The high-temperature capability of the SiC gate driver ICs allows for them to be packaged into the power module and be located physically close to the power devices. This provides a distinct advantage by reducing the gate driver loop inductance, which promotes high frequency operation, while also reducing the overall volume of the system through higher levels of integration. The power module was tested in a bridgeless-boost converter (Fig. 1) to determine the performance of the module in a system level application. The converter was operated with a switching frequency of 200 kHz with a peak output power of approximately 5 kW. The peak efficiency was found to be 97.5% at 2.9 kW.

  7. Review on the effects of hydrogen at extreme pressures and temperatures on the mechanical behavior of polymers.

    SciTech Connect (OSTI)

    Hecht, Ethan S.

    2013-03-01

    The effects of hydrogen on the mechanics (e.g. strength, ductility, and fatigue resistance) of polymer materials are outlined in this report. There are a small number of studies reported in the literature on this topic, and even fewer at the extreme temperatures to which hydrogen service materials will be exposed. Several studies found little evidence that hydrogen affects the static tensile properties, long term creep, or ductile fracture of high density polyethylene or polyamide. However, there has been a report that a recoverable drop in the modulus of high density polyethylene is observable under high hydrogen pressure. A research need exists on the mechanical effects of hydrogen on the wide range of polymers used or considered for use in the hydrogen economy, due to the lack of data in the literature.

  8. Disstacking of Phthalocyanine in Water by Poly(ethylene Oxide)

    E-Print Network [OSTI]

    Wu, Chi

    -hexadecyltrimethylam- monium bromide (CTAB) greatly increases the excited- state lifetime of zinc(II) tetrasulfonated that cationic surfactant, e.g., n-hexadecyltrimethylammonium bromide, was more effective in disstacking nonaggregated in water as shown by UV-vis spectroscopy. Recently, we reported a series of zinc

  9. X-ray Characterizations of Polyethylene Polyhedral Oligomeric Silsesquioxane Copolymers

    E-Print Network [OSTI]

    , Alan J. Waddon,* Richard J. Farris, and E. Bryan Coughlin* Polymer Science and Engineering Department in the design of hydrid ma- terials.5,6,8-18 A typical POSS macromonomer has an inorganic Si8O12 core surrounded

  10. Molecular Dynamics Simulation of Homogeneous Crystal Nucleation in Polyethylene

    E-Print Network [OSTI]

    Yi, Peng

    Using a realistic united-atom force field, molecular dynamics simulations were performed to study homogeneous nucleation of the crystal phase at about 30% supercooling from the melts of n-pentacontahectane (C150) and a ...

  11. Mechanical Properties of Glassy Polyethylene Nanofibers via Molecular Dynamics Simulations

    E-Print Network [OSTI]

    Buell, Sezen

    The extent to which the intrinsic mechanical properties of polymer fibers depend on physical size has been a matter of dispute that is relevant to most nanofiber applications. Here, we report the elastic and plastic ...

  12. Extensional viscosity measurements of polyethylene using a melt flow indexer 

    E-Print Network [OSTI]

    Moffatt, Scott Gordon

    1999-01-01

    . . . . . . . . 142 APPENDIX C: CONSTANT STRESS RHEOMETER TESTING PROCEDURE. . . . . . APPENDIX D: MELT FLOW INDEXER DATA . . . . . 147 APPENDIX E: CAPILLARY RHEOMETER DATA. . . . . . 184 APPENDIX F: OSCILLATORY RHEOMETER DATA . . . . . . . . 213 APPENDIX G...) [Padmanabhan and Macosko (1997)] . . . . . 14 5 Bagley Correction Factor for the Capillary Rheometer. 23 6 Flow Index Determination. . . . . . . 28 7 Definitions of Lengths Used in the Darby Method. 8 Carreau-Yasuda Fit of Complex Viscosity Data for Resin E...

  13. Property determinants of dextran:polyethylene glycol adhesive sealants

    E-Print Network [OSTI]

    Shazly, Tarek (Tarek Michael)

    2007-01-01

    Internal surgical intervention necessitates the intentional wounding of tissue. In certain clinical procedures, the desired wound healing response requires the use of closure techniques, such as suturing or stapling of ...

  14. REVIEW ARTICLE Polyethylene and biodegradable mulches for agricultural

    E-Print Network [OSTI]

    Boyer, Edmond

    of plastic mulch in agriculture has increased dramatically in the last 10 years throughout the world- able and biodegradable mulches. Here we review the use of plastic mulches in agriculture, with special reference to biode- gradable mulches. Major topics discussed are (1) history of plastic mulch and impact

  15. Temperature-responsive surface-functionalized polyethylene films 

    E-Print Network [OSTI]

    Ponder, Bill C.

    1998-01-01

    (ethylene glycol) of Molecular Weight 600 g/mol. . . . . Measurement of ii/Iq for Modified Films at Varying Temperatures in Water, Ethanol and Toluene 36 38 38 . . . . . 39 . . . . . 39 . . 40 42 . . . . . 43 . . . . . 43 . . . . 44 . . 45 Page... FIGURE Page 9 I i/Iq values as a function of temperature through two heating and cooling cycles (5 'C m 65 'C m 5 'C) for PE/PEoas-PEGissp-OiC(CHq)qpyrene (0) and PE/PEoas-PEG6oo-OzC(CHq)qpyrene (V) films . 31 10 Plots of ii/Iq values obtained Irom...

  16. Continuous Processing of High Thermal Conductivity Polyethylene Fibers and

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p aDepartmentEnergy comparingDeep Vadose Zone - Professor Gang

  17. Continuous Processing of High Thermal Conductivity Polyethylene Fibers and Sheets

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergyTher i n c i p aDepartmentEnergy comparingDeep Vadose Zone - Professor

  18. Poly(ethylene oxide) functionalization (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTech ConnectSpeeding accessusers' guide.representationComplex Provides aPoly(ethylene

  19. Poly(ethylene oxide) functionalization (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTech ConnectSpeeding accessusers' guide.representationComplex Provides

  20. The quality assurance of heat fused thermoplastic pipeline joints 

    E-Print Network [OSTI]

    Earles, Larry Lee

    1982-01-01

    heat fusion cycle to oroduce an acceptable joint for a given material and determine those conditions for both medium- and high-density polyethylene pipe; and (3) inves- tigate the feasibility of monitoring acoustic emissions duirng the fusion... process and correlating those emissions with joint strength. Joints were constructed with controlled processing conditions. Acoustic emissions were monitored throughout the fusion process. Tensile tests were used to evaluate joint strength...

  1. Pyrolysis and hydrolysis of mixed polymer waste comprising polyethylene-terephthalate and polyethylene to sequentially recover [monomers

    DOE Patents [OSTI]

    Evans, R.J.; Chum, H.L.

    1998-10-13

    A process is described for using fast pyrolysis in a carrier gas to convert a plastic waste feed stream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents; selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feed stream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent. 83 figs.

  2. Ultra high vacuum broad band high power microwave window

    DOE Patents [OSTI]

    Nguyen-Tuong, Viet (Seaford, VA); Dylla, III, Henry Frederick (Yorktown, VA)

    1997-01-01

    An improved high vacuum microwave window has been developed that utilizes high density polyethylene coated on two sides with SiOx, SiNx, or a combination of the two. The resultant low dielectric and low loss tangent window creates a low outgassing, low permeation seal through which broad band, high power microwave energy may be passed. No matching device is necessary and the sealing technique is simple. The features of the window are broad band transmission, ultra-high vacuum compatibility with a simple sealing technique, low voltage standing wave ratio, high power transmission and low cost.

  3. New iron catalyst for preparation of polymethylene from synthesis gas

    DOE Patents [OSTI]

    Sapienza, R.S.; Slegeir, W.A.

    1988-03-31

    This invention relates to a process for synthesizing hydrocarbons; more particularly, the invention relates to a process for synthesizing long-chain hydrocarbons known as polymethylene from carbon monoxide and hydrogen or from carbon monoxide and water or mixtures thereof in the presence of a catalyst comprising iron and platinum or palladium or mixtures thereof which may be supported on a solid material, preferably an inorganic refractory oxide. This process may be used to convert a carbon monoxide containing gas to a product which could substitute for high density polyethylene.

  4. Iron catalyst for preparation of polymethylene from synthesis gas and method for producing the catalyst

    DOE Patents [OSTI]

    Sapienza, Richard S. (1 Miller Ave., Shoreham, NY 11786); Slegeir, William A. (7 Florence Rd., Hampton Bays, NY 11946)

    1990-01-01

    This invention relates to a process for synthesizing hydrocarbons; more particularly, the invention relates to a process for synthesizing long-chain hydrocarbons known as polymethylene from carbon monoxide and hydrogen or from carbon monoxide and water or mixtures thereof in the presence of a catalyst comprising iron and platinum or palladium or mixtures thereof which may be supported on a solid material, preferably an inorganic refractory oxide. This process may be used to convert a carbon monoxide containing gas to a product which could substitute for high density polyethylene.

  5. Iron catalyst for preparation of polymethylene from synthesis gas and method for producing the catalyst

    DOE Patents [OSTI]

    Sapienza, R.S.; Slegeir, W.A.

    1990-05-15

    This invention relates to a process for synthesizing hydrocarbons; more particularly, the invention relates to a process for synthesizing long-chain hydrocarbons known as polymethylene from carbon monoxide and hydrogen or from carbon monoxide and water or mixtures thereof in the presence of a catalyst comprising iron and platinum or palladium or mixtures thereof which may be supported on a solid material, preferably an inorganic refractory oxide. This process may be used to convert a carbon monoxide containing gas to a product which could substitute for high density polyethylene.

  6. Iron catalyst for preparation of polymethylene from synthesis gas

    DOE Patents [OSTI]

    Sapienza, Richard S. (Shoreham, NY); Slegeir, William A. (Hampton Bays, NY)

    1990-01-01

    This invention relates to a process for synthesizing hydrocarbons; more particularly, the invention relates to a process for synthesizing long-chain hydrocarbons known as polymethylene from carbon monoxide and hydrogen or from carbon monoxide and water or mixtures thereof in the presence of a catalyst comprising iron and platinum or palladium or mixtures thereof which may be supported on a solid material, preferably an inorganic refractory oxide. This process may be used to convert a cabon monoxide containing gas to a product which could substitute for high density polyethylene.

  7. Ultra high vacuum broad band high power microwave window

    DOE Patents [OSTI]

    Nguyen-Tuong, V.; Dylla, H.F. III

    1997-11-04

    An improved high vacuum microwave window has been developed that utilizes high density polyethylene coated on two sides with SiOx, SiNx, or a combination of the two. The resultant low dielectric and low loss tangent window creates a low outgassing, low permeation seal through which broad band, high power microwave energy may be passed. No matching device is necessary and the sealing technique is simple. The features of the window are broad band transmission, ultra-high vacuum compatibility with a simple sealing technique, low voltage standing wave ratio, high power transmission and low cost. 5 figs.

  8. High-density Er-implanted GaN optical memory devices Boon K. Lee, Robert Chih-Jen Chi, David Liang-Chiun Chao, Ji Cheng, Irving Yeong-Ning Chry,

    E-Print Network [OSTI]

    Cincinnati, University of

    . The integrated upconversion emission power was measured to be 40 pW when pumped by a 840-nm laser at 265 m, volumetric storage methods increase storage capacity by stacking data three dimension- ally. Based on optical larger than the existing optical disk technologies. First proposed in 1960, volumetric optical data

  9. High-density mapping of the MHC identifies a shared role for HLA-DRB1*01:03 in inflammatory bowel diseases and heterozygous advantage in ulcerative colitis

    E-Print Network [OSTI]

    Goyette, Philippe; Boucher, Gabrielle; Dermot, Mallon; Ellinghaus, Eva; Jostins, Luke; Huang, Hailiang; Ripke, Stephan; Gusareva, Elena S.; Annese, Vito; Hauser, Stephen L.; Oksenberg, Jorge R.; Thomsen, Ingo; Leslie, Stephen; International Inflammatory Bowel Disease Genetics Consortium; Daly, Mark J.; Van Steen, Kristel; Duerr, Richard H.; Barrett, Jeffrey C.; McGovern, Dermot P. B.; Schumm, L. Philip; Traherne, James A.; Carrington, Mary N.; Kosmoliaptsis, Vasilis; Karlsen, Tom H.; Franke, Andre; Rioux, John D.

    2015-01-05

    17, Christian Gieger46, Jürgen Glas34, Philippe Goyette23, Todd Green13, Katherine Hanigan69, Nicholas K Hayward101, Hakon Hakonarson80,81, Talin Haritunians7, Ailsa Hart47, Chris Hawkey48, Matija Hedl12, Xinli Hu20, Hailiang Huang3, Andrew...

  10. "TOF2H": A precision toolbox for rapid, high density/high coverage hydrogen-deuterium exchange mass spectrometry via an LC-MALDI approach, covering the data pipeline from spectral acquisition to HDX rate analysis

    E-Print Network [OSTI]

    Nikamanon, Pornpat; Pun, Elroy; Chou, Wayne; Koter, Marek D; Gershon, Paul D

    2008-01-01

    Chou - waynechou@gmail.com; Marek D Koter - mkoter@uci.edu; PaulPun 2 , Wayne Chou 1 , Marek D Koter 1 and Paul D Gershon* 1

  11. Ultrasonic signatures of idealized grout defects in polyethylene-sleeved cable stays 

    E-Print Network [OSTI]

    Nakirekanti, Sreenivas

    1992-01-01

    mechanical disturbance is generated, the elements of the matter or medium will be deformed and the disturbance is transmitted from one point to the next, thus progressing through the medium. During this process, the propagating wave must overcome...

  12. Molecular Orientation and Relaxation of Poly(ethylene terephthalate) by Polarization Modulation Infrared Spectroscopy

    E-Print Network [OSTI]

    Pezolet, Michel

    (ethylene terephthalate) (PET) is induced during its processing via fiber spinning or blow molding. This polymer can crystals. Finally, shrinkage experiments on oriented PET have demonstrated that, beyond a certain degree of orientation, shrinkage is hindered due to the development of crystallinity.8,9 To investigate the orientation

  13. Tensile True Stress - Strain Curves and Essential Work of Fracture Analysis of Polyethylene Blown Films 

    E-Print Network [OSTI]

    Lee, Chin-Fu

    2015-05-12

    the viscosity of the melt and leads to the film solidification. Simultaneously, the guide rolls above the die flatten the film, and the nip rolls apply tension to the film in the machine direction (MD). The draw down ratio (DDR) is an indicator... properties, the many processing factors, including the melt temperature, speed of cooling, DDR, and BUR, also have significant effects on bubble geometry and film properties. Blown film generally has a better balance of mechanical properties than cast...

  14. The impact of mechanical properties of poly(ethylene glycol) hydrogels on vocal fold fibroblasts' behavior 

    E-Print Network [OSTI]

    Liao, Huimin

    2009-05-15

    hydrogel. This study demonstrates that different levels of VFF ECM formation may be achieved by varying the mechanical properties of PEG hydrogels and validates a systematic and controlled platform for further research of cell-biomaterials interaction....

  15. Factors affecting degradation of polyethylene terephthalate (PET) during pre-flotation conditioning

    SciTech Connect (OSTI)

    Caparanga, Alvin R. Basilia, Blessie A.; Dagbay, Kevin B.; Salvacion, Jonathan W.L.

    2009-09-15

    In general, plastics are exposed to different degrading agents in every procedure involved in their recovery from waste mixture and from subsequent recycling. In this study, two methods of pre-flotation conditioning were used to determine how these methods affect the general properties of the pre-conditioned PET particles to be recovered from the PET-PVC mixture. The first method comprised the conditioning of PET samples using an alkaline solution of nonionic surfactant (Triton X-100) based on the patent by the Goodyear Tire and Rubber Company. The second method, developed in this study, was a conditioning process which used an alkali-less solution of the same nonionic surfactant (Triton X-100) used in the first method. The following analytical methods were used to characterize properties of the pre-conditioned PET samples that were correlated to relative degradation of the samples: differential scanning calorimetry (DSC), for thermal behavior of the samples; FT-IR spectroscopy, for functional groups present in the samples; and, Pohl's method, for carboxyl end-group concentration count. Results show that in addition to water the presence of NaOH in the conditioning solution contributes to the further degradation of the polymer.

  16. A strategy for the quantification of protein polyethylene glycol (PEG) derivatized sites using iTRAQ

    E-Print Network [OSTI]

    Monk, Rebecca Helen

    2011-01-01

    9 8. Sample Resuspension…………………………………… 10 9. Mass26 6. Sample Resuspension……………………………..…………. 26 7. MassQSTAR Elite. 8. Sample Resuspension Samples were resuspended

  17. Phosphate-Containing Polyethylene Glycol Polymers Prevent Lethal Sepsis by Multidrug-Resistant Pathogens

    SciTech Connect (OSTI)

    Zaborin, Alexander; Defazio, Jennifer; Kade, Matthew; Kaiser, Brooke LD; Belogortseva, Natalia; Camp, David G.; Smith, Richard D.; Adkins, Joshua N.; Kim, Sangman M.; Alverdy, Alexandria; Goldfeld, David; Firestone, Millicent; Collier, Joel; Jabri, Bana; Tirrell, Matthew; Zaborina, Olga; Alverdy, John C.

    2014-02-01

    The gastrointestinal tract is the primary site of colonization for multi-drug resistant healthcare associated pathogens (HAPs) that are the principal source and cause of life-threatening infections in critically ill patients. We previously identified a high molecular weight co-polymer (PEG15-20) with mucoadhesive and cytoprotective actions on the intestinal epithelium. In this report we covalently bonded phosphate (Pi) to PEG15-20 ( termed Pi-PEG15-20) to enhance its cytoprotective activity against microbial virulence activation and invasion based on our previous work showing that Pi is a key environmental cue regulating microbial virulence across pathogens of clinical importance to hospitalized patients. We demonstrated that Pi-PEG15-20 can suppress phosphate-, iron-, and quorum sensing signal- mediated activation of bacterial virulence as well as inhibit intestinal epithelial IL-8 release during lipopolysaccharide (LPS) exposure. Pi-PEG15-20 also prevented mortality in C. elegans and mice exposed to several highly virulent and antibiotic(?)-resistant health care acquired pathogens (HAPs) while preserving the normal microbiota. Intestinal application Pi-PEG 15-20 has the potential to be a useful agent to prevent the pathogenic activation of microbes during critical illness where exposure to HAPs is ubiquitous.

  18. Anomalous heat conduction in polyethylene chains: Theory and molecular dynamics simulations

    E-Print Network [OSTI]

    Henry, Asegun

    In 1955 Fermi, Pasta, and Ulam showed that a simple model for a nonlinear one-dimensional chain of particles can be nonergodic, which implied infinite thermal conductivity. A more recent investigation of a realistic model ...

  19. Viscoelasticity and primitive path analysis of entangled polymer liquids: From f-actin to polyethylene

    E-Print Network [OSTI]

    Nariya Uchida; Gary S. Grest; Ralf Everaers

    2007-11-28

    We combine computer simulations and scaling arguments to develop a unified view of polymer entanglement based on the primitive path analysis (PPA) of the microscopic topological state. Our results agree with experimentally measured plateau moduli for three different polymer classes over a wide rangeof reduced polymer densities: (i) semi-dilute theta solutions of synthetic polymers, (ii) the corresponding dense melts above the glass transition or crystallization temperature, and (iii) solutions of semi-flexible (bio)polymers such as f-actin or suspensions of rodlike viruses. Together these systems cover the entire range from loosely to tightly entangled polymers. In particular, we argue that the primitive path analysis renormalizes a loosely to a tightly entangled system and provide a new explanation of the successful Lin-Noolandi packing conjecture for polymer melts.

  20. Measurements of ultracold neutron upscattering and absorption in polyethylene and vanadium

    E-Print Network [OSTI]

    E. I. Sharapov; C. L. Morris; M. Makela; A. Saunders; Evan R. Adamek; Yelena Bagdasarova; L. J. Broussard; C. B. Cude-Woods; Deon E Fellers; Peter Geltenbort; S. I. Hasan; K. P. Hickerson; G. Hogan; A. T. Holley; Chen-Yu Liu; M. P. Mendenhall; J. Ortiz; R. W. Pattie Jr.; D. G. Phillips; J. Ramsey; D. J. Salvat; S. J. Seestrom; E. Shaw; Sky Sjue; W. E. Sondheim; B. VornDick; Z. Wang; T. L. Womack; A. R. Young; B. A. Zeck

    2013-06-05

    The study of neutron cross sections for elements used as efficient ``absorbers'' of ultracold neutrons (UCN) is crucial for many precision experiments in nuclear and particle physics, cosmology and gravity. In this context, ``absorption'' includes both the capture and upscattering of neutrons to the energies above the UCN energy region. The available data, especially for hydrogen, do not agree between themselves or with the theory. In this report we describe measurements performed at the Los Alamos National Laboratory UCN facility of the UCN upscattering cross sections for vanadium and for hydrogen in CH$_2$ using simultaneous measurements of the radiative capture cross sections for these elements. We measured $\\sigma_{up}=1972\\pm130$ b for hydrogen in CH$_2$, which is below theoretical expectations, and $\\sigma_{up} < 25\\pm9$ b for vanadium, in agreement with the expectation for the neutron heating by thermal excitations in solids.

  1. Measurements of ultracold neutron upscattering and absorption in polyethylene and vanadium

    E-Print Network [OSTI]

    Sharapov, E I; Makela, M; Saunders, A; Adamek, Evan R; Bagdasarova, Yelena; Broussard, L J; Cude-Woods, C B; Fellers, Deon E; Geltenbort, Peter; Hasan, S I; Hickerson, K P; Hogan, G; Holley, A T; Liu, Chen-Yu; Mendenhall, M P; Ortiz, J; Pattie, R W; Phillips, D G; Ramsey, J; Salvat, D J; Seestrom, S J; Shaw, E; Sjue, Sky; Sondheim, W E; VornDick, B; Wang, Z; Womack, T L; Young, A R; Zeck, B A

    2013-01-01

    The study of neutron cross sections for elements used as efficient ``absorbers'' of ultracold neutrons (UCN) is crucial for many precision experiments in nuclear and particle physics, cosmology and gravity. In this context, ``absorption'' includes both the capture and upscattering of neutrons to the energies above the UCN energy region. The available data, especially for hydrogen, do not agree between themselves or with the theory. In this report we describe measurements performed at the Los Alamos National Laboratory UCN facility of the UCN upscattering cross sections for vanadium and for hydrogen in CH$_2$ using simultaneous measurements of the radiative capture cross sections for these elements. We measured $\\sigma_{up}=1972\\pm130$ b for hydrogen in CH$_2$, which is below theoretical expectations, and $\\sigma_{up} < 25\\pm9$ b for vanadium, in agreement with the expectation for the neutron heating by thermal excitations in solids.

  2. Interfacial activity of phosphonated-polyethylene glycol functionalized cerium oxide nanoparticles

    E-Print Network [OSTI]

    L. Qi; J. Fresnais; P. Muller; O. Theodoly; J. -F. Berret; J. -P. Chapel

    2013-05-04

    In a recent publication, we have highlighted the potential of phosphonic acid terminated PEG oligomers to functionalize strong UV absorption cerium oxide nanoparticles[1], which yield suspensions that are stable in aqueous or organic solvents and are redispersible in different solvent after freeze-drying. In the present work, we highlight the interfacial activity of the functional ceria nanoparticles and their potential to modify hydrophobic surfaces. We first investigated Phosphonated-PEG amphiphilic oligomers behavior as strong surface active species forming irreversibly adsorbed layers. We then show that the oligomers interfacial properties translate to the functional nanoparticles. In particular, the addition of a small fraction of phosphonated-PEG oligomers with an extra C16 aliphatic chain (stickers) into the formulation enabled the tuning of i) the nanoparticles adsorption at the air/water, polystyrene/water, oil/water interfaces and ii) the particle/particle interaction in aqueous solutions. We also found that dense and closely packed two dimensional monolayers of nanoceria can be formed by spontaneous adsorption or surface compression using a Langmuir trough. A hexagonal organization controlled by reversible and repulsive repulsion has been characterized by GISAXS. Mono- or multilayers can also be stably formed or transferred on solid surfaces. Our results are key features in the field of polymer surface modification, solid stabilized emulsions (Pickering) or supracolloidal assemblies.

  3. Layer-by-layer assembly on polyethylene films via "click" chemistry 

    E-Print Network [OSTI]

    Chance, Brandon Scott

    2009-05-15

    Layer-by-layer assembly has received much attention over the last fifteen years. This assembly process can be carried out using different methods including hydrogen-bonding, electrostatic, and to a lesser extent, covalent ...

  4. Effect of micro-patterning on bacterial adhesion on PET (polyethylene terephthalate) surface

    E-Print Network [OSTI]

    Wang, Liyun; Chen, Wei; Terentjev, Eugene

    2014-12-16

    medical devices and food processing facilities 4 are prone to infections caused by the attached microbes, and eventually - biofilms, leading to a direct threat to 5 health and food contamination.3-6 Hence, a host of biological and chemical strategies... -Tasciuc DA, et al. Effect of micro-and nanoscale topography on the adhesion of 6 bacterial cells to solid surfaces. Appl Environ Microb 2013;79:2703-12. 7 4. Antoci Jr V, Adams CS, Parvizi J, et al. The inhibition of Staphylococcus epidermidis biofilm...

  5. Preparation and Properties of Poly(ethylene oxide) Star Nicholas A. Peppas, Ankush Argade, Saumitra Bhargava

    E-Print Network [OSTI]

    Peppas, Nicholas A.

    a multifunctional core containing bro- mine, carboxyl, amine, or hydroxyl groups with a stoichiometric amount

  6. Modeling and simulation of Li-ion conduction in poly(ethylene oxide)

    E-Print Network [OSTI]

    Averbuch, Amir

    rechargeable batteries for consumer portable applications. A lithium-ion battery employs a metal oxide/discharge voltage depends on the current and resistance of all battery components. In most solid-state lithium-ion of Computational Physics 227 (2007) 1162­1175 www.elsevier.com/locate/jcp #12;1. Introduction Lithium and lithium-ion

  7. Pyrolysis and hydrolysis of mixed polymer waste comprising polyethyleneterephthalate and polyethylene to sequentially recover

    DOE Patents [OSTI]

    Evans, Robert J. (Lakewood, CO); Chum, Helena L. (Arvada, CO)

    1998-01-01

    A process of using fast pyrolysis in a carrier gas to convert a plastic waste feedstream having a mixed polymeric composition in a manner such that pyrolysis of a given polymer to its high value monomeric constituent occurs prior to pyrolysis of other plastic components therein comprising: selecting a first temperature program range to cause pyrolysis of said given polymer to its high value monomeric constituent prior to a temperature range that causes pyrolysis of other plastic components; selecting a catalyst and support for treating said feed streams with said catalyst to effect acid or base catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said temperature program range; differentially heating said feed stream at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantities of the high value monomeric constituent prior to pyrolysis of other plastic components; separating the high value monomeric constituents; selecting a second higher temperature range to cause pyrolysis of a different high value monomeric constituent of said plastic waste and differentially heating the feedstream at the higher temperature program range to cause pyrolysis of the different high value monomeric constituent; and separating the different high value monomeric constituent.

  8. Synthesis and Thermal Behavior of New Poly(ethylene terephthalate-imide)s

    E-Print Network [OSTI]

    Wan, Xin-hua

    INTRODUCTION Polyimides are important, commercially avail- able, high-performance polymers. They have found;polyimides have been discussed in the literature, the thermal and mechanical properties and the rheological

  9. Poly(ethylene glycol) hydrogel microspheres as a controlled release device

    E-Print Network [OSTI]

    Gonzįlez, Sandra D. (Sandra Diane)

    2005-01-01

    Vaccines for infections such as measles, polio, or chicken pox contain live attenuated viruses, which can sometimes lead to infection. Our objective is to develop an improved strategy for vaccines that induces patent immune ...

  10. 1 Electrospun Polyethylene Oxide/Cellulose Nanocrystal Composite 2 Nanofibrous Mats with Homogeneous and Heterogeneous

    E-Print Network [OSTI]

    , Ithaca, New York 14853, United States 7 bS Supporting Information 1. INTRODUCTION 25 Electrospinning of an all-aqueous system for electrospinning based 64on a combination of CNCs with water-soluble polymers biodegradable, and Received: March 23, 2011 Revised: May 5, 2011 8 ABSTRACT: An electrospinning process

  11. Conserving Waterlogged Rope: A Review of Traditional Methods and Experimental Research with Polyethylene Glycol 

    E-Print Network [OSTI]

    McCaskill, Jennifer R.

    2010-01-16

    The excavation of Sieur de la Salle's ship, La Belle, yielded a large amount of waterlogged rope requiring conservation. A history of hemp and rope manufacture is reviewed to assist in the identification of the materials ...

  12. Effects of select fluids on the friction of metal-on-polyethylene joint replacement surfaces

    E-Print Network [OSTI]

    Chang, Timothy C. (Timothy Chan), 1979-

    2005-01-01

    Lubricants are important factors in the tribology of total joint arthroplasty (TJA) surfaces, which are primarily comprised of a polished metallic or ceramic component articulating on an Ultra-High Molecular Weight ...

  13. Chemoprevention of colon carcinogenesis by polyethylene glycol: suppression of epithelial proliferation via

    E-Print Network [OSTI]

    Bustamante, Fabiįn E.

    cancer is the second leading cause of cancer deaths in the United States (1). Because therapy. However, the modest neoplasia reduction rate (30­50%; refs. 5­7) and risk of toxicity (e.g., increased

  14. Biomedical Applications of Gold Nanoparticles Functionalized Using Hetero-Bifunctional Poly(ethylene glycol) Spacer

    E-Print Network [OSTI]

    Sridhar, Srinivas

    Biomedical Applications of Gold Nanoparticles Functionalized Using Hetero-Bifunctional Poly potential, circulation time, and the flexibility of surface-attached biomedically-relevant ligands on gold varieties of nanoparticles with biomedical relevance are available including, polymeric nanoparticles, metal

  15. Improved performance of ultra-high molecular weight polyethylene for orthopedic applications 

    E-Print Network [OSTI]

    Plumlee, Kevin Grant

    2009-05-15

    taken in a JOEL-6400 scanning electron microscope (SEM), and were prepared using a ruthenium vapor coating method [28], then lightly sputter-coated with gold-palladium. Sections of impact samples were cut with razor blades, and then imaged in both.... Samples were prepared for imaging first with a ruthenium vapor coating 29 technique [28], then with a light sputter coating of gold-palladium. The ruthenium vapor coating creates a more even coating on highly mottled surfaces than sputter coating would...

  16. UBC Social Ecological Economic Development Studies (SEEDS) Student Report An Tianyu, Arash Ahmadi, Jacob Sternig, Nicholas Beattie

    E-Print Network [OSTI]

    Investigation into Alternatives to PVC Drainage Pipelines APSC 261: Technology and Society I Instructor: Dr of plastics show HDPE, ABS, and recycled PVC are improvements to original PVC drain pipes in stormwater alternative to PVC for general applications; HDPE scores the best among the evaluated plastics in social

  17. Development of a Compact Neutron Generator to be Used For Associated Particle Imaging Utilizing a RF-Driven Ion Source

    E-Print Network [OSTI]

    Wu, Ying

    2009-01-01

    generator and no polyethylene shielding in the path of thegenerator, polyethylene and lead shielding were used to stopvarious shielding materials such as polyethylene and used in

  18. BMC{trademark}: Baseline report

    SciTech Connect (OSTI)

    NONE

    1997-07-31

    Barrier Membrane Containment (BMC){trademark} is a high-density polyethylene membrane (HOPE) groundwater barrier and pass-through system, with applications ranging from plume control and containment to groundwater manipulation coupled with in-site treatment. BMC{trademark} system can function as a permeable or impermeable reaction wall, a cut-off wall, interceptor trenches, a barrier with collection and/or monitoring system and a pass-through in a funnel and gate configuration. BMC{trademark} can be inspected with a down-hole video camera, producing a permanent VHS format tape, insuring the integrity of the wall and the interlocking joints. The joints are sealed with a ``U``-packing elastomeric gasket to prevent the flow of fluids or gases.

  19. SHIELDING AND DETECTOR RESPONSE CALCULATIONS PERTAINING TO CATEGORY 1 QUANTITIES OF PLUTONIUM AND HAND-HELD PLASTIC SCINTILLATORS

    SciTech Connect (OSTI)

    Couture, A.

    2013-06-07

    Nuclear facilities sometimes use hand-held plastic scintillator detectors to detect attempts to divert special nuclear material in situations where portal monitors are impractical. MCNP calculations have been performed to determine the neutron and gamma radiation field arising from a Category I quantity of weapons-grade plutonium in various shielding configurations. The shields considered were composed of combinations of lead and high-density polyethylene such that the mass of the plutonium plus shield was 22.7 kilograms. Monte-Carlo techniques were also used to determine the detector response to each of the shielding configurations. The detector response calculations were verified using field measurements of high-, medium-, and low- energy gamma-ray sources as well as a Cf-252 neutron source.

  20. An in situ tensile test apparatus for polymers in high pressure hydrogen

    SciTech Connect (OSTI)

    Alvine, K. J. Kafentzis, T. A.; Pitman, S. G.; Johnson, K. I.; Skorski, D.; Tucker, J. C.; Roosendaal, T. J.; Dahl, M. E.

    2014-10-15

    Degradation of material properties by high-pressure hydrogen is an important factor in determining the safety and reliability of materials used in high-pressure hydrogen storage and delivery. Hydrogen damage mechanisms have a time dependence that is linked to hydrogen outgassing after exposure to the hydrogen atmosphere that makes ex situ measurements of mechanical properties problematic. Designing in situ measurement instruments for high-pressure hydrogen is challenging due to known hydrogen incompatibility with many metals and standard high-power motor materials such as Nd. Here we detail the design and operation of a solenoid based in situ tensile tester under high-pressure hydrogen environments up to 42 MPa (6000 psi). Modulus data from high-density polyethylene samples tested under high-pressure hydrogen at 35 MPa (5000 psi) are also reported as compared to baseline measurements taken in air.