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Sample records for hc carbon monoxide

  1. Method of removing carbon monoxide from gases

    DOE Patents [OSTI]

    Gerstein, Bernard C.; Macaulay, David B.

    1976-06-01

    A process and catalyst are disclosed for purifying an atmosphere containing carbon monoxide by passing the atmosphere through a bed of a catalyst of TbO.sub.x, where x = 1.8 to 1.5, which oxidizes the carbon monoxide to carbon dioxide.

  2. CO (Carbon Monoxide Mixing Ratio System) Handbook (Technical...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: CO (Carbon Monoxide Mixing Ratio System) Handbook Citation Details In-Document Search Title: CO (Carbon Monoxide Mixing Ratio System) Handbook The main function of ...

  3. Device for staged carbon monoxide oxidation

    DOE Patents [OSTI]

    Vanderborgh, Nicholas E.; Nguyen, Trung V.; Guante, Jr., Joseph

    1993-01-01

    A method and apparatus for selectively oxidizing carbon monoxide in a hydrogen rich feed stream. The method comprises mixing a feed stream consisting essentially of hydrogen, carbon dioxide, water and carbon monoxide with a first predetermined quantity of oxygen (air). The temperature of the mixed feed/oxygen stream is adjusted in a first the heat exchanger assembly (20) to a first temperature. The mixed feed/oxygen stream is sent to reaction chambers (30,32) having an oxidation catalyst contained therein. The carbon monoxide of the feed stream preferentially absorbs on the catalyst at the first temperature to react with the oxygen in the chambers (30,32) with minimal simultaneous reaction of the hydrogen to form an intermediate hydrogen rich process stream having a lower carbon monoxide content than the feed stream. The elevated outlet temperature of the process stream is carefully controlled in a second heat exchanger assembly (42) to a second temperature above the first temperature. The process stream is then mixed with a second predetermined quantity of oxygen (air). The carbon monoxide of the process stream preferentially reacts with the second quantity of oxygen in a second stage reaction chamber (56) with minimal simultaneous reaction of the hydrogen in the process stream. The reaction produces a hydrogen rich product stream having a lower carbon monoxide content than the process stream. The product stream is then cooled in a third heat exchanger assembly (72) to a third predetermined temperature. Three or more stages may be desirable, each with metered oxygen injection.

  4. Carbon Monoxide Sensor - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon Monoxide Sensor Los Alamos National Laboratory Contact LANL About This Technology Technology Marketing SummaryScientists at Los Alamos National Laboratory (LANL) have developed an electrochemical carbon monoxide (CO) sensor that is more reliable and reproducible than any other CO sensor on the market today. The patented method for producing the sensor ensures reproducibility and reduces the need for calibration of every sensor coming off the production line.DescriptionInaccurate CO

  5. Carbon monoxide sensor and method of use

    DOE Patents [OSTI]

    Dutta, Prabir K.; Swartz, Scott L.; Holt, Christopher T.; Revur, Ramachandra Rao

    2006-01-10

    A sensor and method of use for detection of low levels of carbon monoxide in gas mixtures. The approach is based on the change in an electrical property (for example: resistance) that occurs when carbon monoxide is selectively absorbed by a film of copper chloride (or other metal halides). The electrical property change occurs rapidly with both increasing and decreasing CO contents, varies with the amount of CO from the gas stream, and is insensitive to the presence of hydrogen. To make a sensor using this approach, the metal halide film will deposited onto an alumina substrate with electrodes. The sensor may be maintained at the optimum temperature with a thick film platinum heater deposited onto the opposite face of the substrate. When the sensor is operating at an appropriate (and constant) temperature, the magnitude of the electrical property measured between the interdigital electrodes will provide a measure of the carbon monoxide content of the gas.

  6. Enhanced carbon monoxide utilization in methanation process

    DOE Patents [OSTI]

    Elek, Louis F.; Frost, Albert C.

    1984-01-01

    Carbon monoxide - containing gas streams are passed over a catalyst to deposit a surface layer of active surface carbon thereon essentially without the formation of inactive coke. The active carbon is subsequently reacted with steam or hydrogen to form methane. Surprisingly, hydrogen and water vapor present in the feed gas do not adversely affect CO utilization significantly, and such hydrogen actually results in a significant increase in CO utilization.

  7. Method and apparatus for selective removal of carbon monoxide

    DOE Patents [OSTI]

    Borup, Rodney L.; Skala, Glenn W.; Brundage, Mark A.; LaBarge, William J.

    2000-01-01

    There is provided a method and apparatus for treatment of a hydrogen-rich gas to reduce the carbon monoxide content thereof by reacting the carbon monoxide in the gas with an amount of oxygen sufficient to oxidize at least a portion of the carbon monoxide in the presence of a catalyst in a desired temperature range without substantial reaction of hydrogen. The catalyst is an iridium-based catalyst dispersed on, and supported on, a carrier. In the presence of the catalyst, carbon monoxide in a hydrogen-rich feed gas is selectively oxidized such that a product stream is produced with a very low carbon monoxide content.

  8. CO (Carbon Monoxide Mixing Ratio System) Handbook

    SciTech Connect (OSTI)

    Biraud, S

    2011-02-23

    The main function of the CO instrument is to provide continuous accurate measurements of carbon monoxide mixing ratio at the ARM SGP Central Facility (CF) 60-meter tower (36.607 °N, 97.489 °W, 314 meters above sea level). The essential feature of the control and data acquisition system is to record signals from a Thermo Electron 48C and periodically calibrate out zero and span drifts in the instrument using the combination of a CO scrubber and two concentrations of span gas (100 and 300 ppb CO in air). The system was deployed on May 25, 2005.

  9. Search of medical literature for indoor carbon monoxide exposure

    SciTech Connect (OSTI)

    Brennan, T.; Ivanovich, M.

    1995-12-01

    This report documents a literature search on carbon monoxide. The search was limited to the medical and toxicological databases at the National Library of Medicine (MEDLARS). The databases searched were Medline, Toxline and TOXNET. Searches were performed using a variety of strategies. Combinations of the following keywords were used: carbon, monoxide, accidental, residential, occult, diagnosis, misdiagnosis, heating, furnace, and indoor. The literature was searched from 1966 to the present. Over 1000 references were identified and summarized using the following abbreviations: The major findings of the search are: (1) Acute and subacute carbon monoxide exposures result in a large number of symptoms affecting the brain, kidneys, respiratory system, retina, and motor functions. (2) Acute and subacute carbon monoxide (CO) poisonings have been misdiagnosed on many occasions. (3) Very few systematic investigations have been made into the frequency and consequences of carbon monoxide poisonings.

  10. Reduction of Carbon Monoxide. Past Research Summary

    DOE R&D Accomplishments [OSTI]

    Schrock, R. R.

    1982-01-01

    Research programs for the year on the preparation, characterization, and reactions of binuclear tantalum complexes are described. All evidence to date suggest the following of these dimeric molecules: (1) the dimer does not break into monomers under mild conditions; (2) intermolecular hydride exchange is not negligible, but it is slow; (3) intermolecular non-ionic halide exchange is fast; (4) the ends of the dimers can rotate partially with respect to one another. The binuclear tantalum hydride complexes were found to react with carbon monoxide to give a molecule which is the only example of reduction of CO by a transition metal hydride to give a complex containing a CHO ligand. Isonitrides also reacted in a similar manner with dimeric tantalum hydride. (ATT)

  11. Carbon monoxide sensor and method of use thereof

    DOE Patents [OSTI]

    McDaniel; Anthony H. , Medlin; J. Will , Bastasz; Robert J.

    2007-09-04

    Carbon monoxide sensors suitable for use in hydrogen feed streams and methods of use thereof are disclosed. The sensors are palladium metal/insulator/semiconductor (Pd-MIS) sensors which may possess a gate metal layer having uniform, Type 1, or non-uniform, Type 2, film morphology. Type 1 sensors display an increased sensor response in the presence of carbon monoxide while Type 2 sensors display a decreased response to carbon monoxide. The methods and sensors disclosed herein are particularly suitable for use in proton exchange membrane fuel cells (PEMFCs).

  12. Gold-catalyzed synthesis of carbonates and carbamates from carbon monoxide

    SciTech Connect (OSTI)

    Friend, Cynthia M; Madix, Robert J; Xu, Bingjun

    2015-01-20

    The invention provides a method for producing organic carbonates via the reaction of alcohols and carbon monoxide with oxygen adsorbed on a metallic gold or gold alloy catalyst.

  13. The proposed revision to the NAAQS for carbon monoxide and its...

    Office of Scientific and Technical Information (OSTI)

    STANDARDS; CARBON MONOXIDE; BIOLOGICAL EFFECTS; NEW JERSEY; POLLUTION REGULATIONS; AIR POLLUTION; CARDIOVASCULAR DISEASES; HEALTH HAZARDS; PUBLIC HEALTH; SENSITIVITY; CARBON ...

  14. Terpolymerization of ethylene, sulfur dioxide and carbon monoxide

    DOE Patents [OSTI]

    Johnson, Richard; Steinberg, Meyer

    1981-01-01

    This invention relates to a high molecular weight terpolymer of ethylene, sulfur dioxide and carbon monoxide stable to 280.degree. C. and containing as little as 36 mol % ethylene and about 41-51 mol % sulfur dioxide; and to the method of producing said terpolymer by irradiation of a liquid and gaseous mixture of ethylene, sulfur dioxide and carbon monoxide by means of Co-60 gamma rays or an electron beam, at a temperature of about 10.degree.-50.degree. C., and at a pressure of about 140 to 680 atmospheres, to initiate polymerization.

  15. Terpolymerization of ethylene, sulfur dioxide and carbon monoxide

    DOE Patents [OSTI]

    Johnson, R.; Steinberg, M.

    This invention relates to high molecular weight terpolymer of ethylene, sulfur dioxide and carbon monoxide stable to 280/sup 0/C and containing as little as 36 mo1% ethylene and about 41 to 51 mo1% sulfur dioxide, and to the method of producing said terpolymer by irradiation of a liquid and gaseous mixture of ethylene, sulfur dioxide and carbon monoxide by means of Co-60 gamma rays or an electron beam, at a temperature of about 10 to 50/sup 0/C, and at a pressure of about 140 to 680 atmospheres, to initiate polymerization.

  16. Composite catalyst for carbon monoxide and hydrocarbon oxidation

    DOE Patents [OSTI]

    Liu, W.; Flytzani-Stephanopoulos, M.

    1996-03-19

    A method and composition are disclosed for the complete oxidation of carbon monoxide and/or hydrocarbon compounds. The method involves reacting the carbon monoxide and/or hydrocarbons with an oxidizing agent in the presence of a metal oxide composite catalyst. The catalyst is prepared by combining fluorite-type oxygen ion conductors with active transition metals. The fluorite oxide, selected from the group consisting of cerium oxide, zirconium oxide, thorium oxide, hafnium oxide, and uranium oxide, and may be doped by alkaline earth and rare earth oxides. The transition metals, selected from the group consisting of molybdenum, copper, cobalt, manganese, nickel, and silver, are used as additives. The atomic ratio of transition metal to fluorite oxide is less than one.

  17. Composite catalyst for carbon monoxide and hydrocarbon oxidation

    DOE Patents [OSTI]

    Liu, Wei; Flytzani-Stephanopoulos, Maria

    1996-01-01

    A method and composition for the complete oxidation of carbon monoxide and/or hydrocarbon compounds. The method involves reacting the carbon monoxide and/or hydrocarbons with an oxidizing agent in the presence of a metal oxide composite catalyst. The catalyst is prepared by combining fluorite-type oxygen ion conductors with active transition metals. The fluorite oxide, selected from the group consisting of cerium oxide, zirconium oxide, thorium oxide, hafnium oxide, and uranium oxide, and may be doped by alkaline earth and rare earth oxides. The transition metals, selected from the group consisting of molybdnum, copper, cobalt, maganese, nickel, and silver, are used as additives. The atomic ratio of transition metal to fluorite oxide is less than one.

  18. Catalyst for the methanation of carbon monoxide in sour gas

    DOE Patents [OSTI]

    Kustes, William A. (Louisville, KY); Hausberger, Arthur L. (Louisville, KY)

    1985-01-01

    The invention involves the synergistic effect of the specific catalytic constituents on a specific series of carriers for the methanation of carbon monoxide in the presence of sulfur at relatively high temperatures and at low steam to gas ratios in the range of 0.2:1 or less. This effect was obtained with catalysts comprising the mixed sulfides and oxides of nickel and chromium supported on carriers comprising magnesium aluminate and magnesium silicate. Conversion of carbon monoxide to methane was in the range of from 40 to 80%. Tests of this combination of metal oxides and sulfides on other carriers and tests of other metal oxides and sulfides on the same carrier produced a much lower level of conversion.

  19. Carbon Monoxide Tolerant Electrocatalyst with Low Platinum Loading and a

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Process for its Preparation - Energy Innovation Portal Startup America Startup America Hydrogen and Fuel Cell Hydrogen and Fuel Cell Find More Like This Return to Search Carbon Monoxide Tolerant Electrocatalyst with Low Platinum Loading and a Process for its Preparation Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication Pt Submonolayers on Ru Nanoparticles: A Novel Low Pt Loading, High CO Tolerance Fuel Cell Electrocatalyst (173 KB)

  20. Transient PrOx carbon monoxide measurement, control, and optimization

    SciTech Connect (OSTI)

    Inbody, M. A.; Borup, R. L.; Tafoya, J.

    2002-01-01

    Fuel processing systems for low temperature polymer electrolyte membrane (PEM) fuel cell systems require control of the carbon monoxide concentration to less than 100 ppm to 10 ppm in the anode feed. Conventional hydrocarbon fuel processors use a water-gas shift (WGS) reactor to react CO with water to form H2 and reduce the CO concentration. The CO conversion is limited by equilibrium at the outlet temperature of the WGS reactor. The WGS outlet CO concentration can range from over 1% to 2000 ppm depending on the system and its operating parameters. At these concentrations, CO poisons low temperature PEM fuel cells and the concentrations needs to be reduced further.

  1. Methanation of gas streams containing carbon monoxide and hydrogen

    DOE Patents [OSTI]

    Frost, Albert C.

    1983-01-01

    Carbon monoxide-containing gas streams having a relatively high concentration of hydrogen are pretreated so as to remove the hydrogen in a recoverable form for use in the second step of a cyclic, essentially two-step process for the production of methane. The thus-treated streams are then passed over a catalyst to deposit a surface layer of active surface carbon thereon essentially without the formation of inactive coke. This active carbon is reacted with said hydrogen removed from the feed gas stream to form methane. The utilization of the CO in the feed gas stream is appreciably increased, enhancing the overall process for the production of relatively pure, low-cost methane from CO-containing waste gas streams.

  2. The effect of carbon monoxide on planetary haze formation

    SciTech Connect (OSTI)

    Hörst, S. M.; Tolbert, M. A

    2014-01-20

    Organic haze plays a key role in many planetary processes ranging from influencing the radiation budget of an atmosphere to serving as a source of prebiotic molecules on the surface. Numerous experiments have investigated the aerosols produced by exposing mixtures of N{sub 2}/CH{sub 4} to a variety of energy sources. However, many N{sub 2}/CH{sub 4} atmospheres in both our solar system and extrasolar planetary systems also contain carbon monoxide (CO). We have conducted a series of atmosphere simulation experiments to investigate the effect of CO on the formation and particle size of planetary haze analogues for a range of CO mixing ratios using two different energy sources, spark discharge and UV. We find that CO strongly affects both number density and particle size of the aerosols produced in our experiments and indicates that CO may play an important, previously unexplored, role in aerosol chemistry in planetary atmospheres.

  3. Size Effect of Ruthenium Nanoparticles in Catalytic Carbon Monoxide Oxidation

    SciTech Connect (OSTI)

    Joo, Sang Hoon; Park, Jeong Y.; Renzas, J. Russell; Butcher, Derek R.; Huang, Wenyu; Somorjai, Gabor A.

    2010-04-04

    Carbon monoxide oxidation over ruthenium catalysts has shown an unusual catalytic behavior. Here we report a particle size effect on CO oxidation over Ru nanoparticle (NP) catalysts. Uniform Ru NPs with a tunable particle size from 2 to 6 nm were synthesized by a polyol reduction of Ru(acac){sub 3} precursor in the presence of poly(vinylpyrrolidone) stabilizer. The measurement of catalytic activity of CO oxidation over two-dimensional Ru NPs arrays under oxidizing reaction conditions (40 Torr CO and 100 Torr O{sub 2}) showed an activity dependence on the Ru NP size. The CO oxidation activity increases with NP size, and the 6 nm Ru NP catalyst shows 8-fold higher activity than the 2 nm catalysts. The results gained from this study will provide the scientific basis for future design of Ru-based oxidation catalysts.

  4. Cyclic process for producing methane from carbon monoxide with heat removal

    DOE Patents [OSTI]

    Frost, Albert C.; Yang, Chang-lee

    1982-01-01

    Carbon monoxide-containing gas streams are converted to methane by a cyclic, essentially two-step process in which said carbon monoxide is disproportionated to form carbon dioxide and active surface carbon deposited on the surface of a catalyst, and said carbon is reacted with steam to form product methane and by-product carbon dioxide. The exothermic heat of reaction generated in each step is effectively removed during each complete cycle so as to avoid a build up of heat from cycle-to-cycle, with particularly advantageous techniques being employed for fixed bed, tubular and fluidized bed reactor operations.

  5. Production of carbon monoxide-free hydrogen and helium from a high-purity source

    DOE Patents [OSTI]

    Golden, Timothy Christopher; Farris, Thomas Stephen

    2008-11-18

    The invention provides vacuum swing adsorption processes that produce an essentially carbon monoxide-free hydrogen or helium gas stream from, respectively, a high-purity (e.g., pipeline grade) hydrogen or helium gas stream using one or two adsorber beds. By using physical adsorbents with high heats of nitrogen adsorption, intermediate heats of carbon monoxide adsorption, and low heats of hydrogen and helium adsorption, and by using vacuum purging and high feed stream pressures (e.g., pressures of as high as around 1,000 bar), pipeline grade hydrogen or helium can purified to produce essentially carbon monoxide -free hydrogen and helium, or carbon monoxide, nitrogen, and methane-free hydrogen and helium.

  6. Carbon monoxide inhalation increases microparticles causing vascular and CNS dysfunction

    SciTech Connect (OSTI)

    Xu, Jiajun; Yang, Ming; Kosterin, Paul; Salzberg, Brian M.; Milovanova, Tatyana N.; Bhopale, Veena M.; Thom, Stephen R.

    2013-12-01

    We hypothesized that circulating microparticles (MPs) play a role in pro-inflammatory effects associated with carbon monoxide (CO) inhalation. Mice exposed for 1 h to 100 ppm CO or more exhibit increases in circulating MPs derived from a variety of vascular cells as well as neutrophil activation. Tissue injury was quantified as 2000 kDa dextran leakage from vessels and as neutrophil sequestration in the brain and skeletal muscle; and central nervous system nerve dysfunction was documented as broadening of the neurohypophysial action potential (AP). Indices of injury occurred following exposures to 1000 ppm for 1 h or to 1000 ppm for 40 min followed by 3000 ppm for 20 min. MPs were implicated in causing injuries because infusing the surfactant MP lytic agent, polyethylene glycol telomere B (PEGtB) abrogated elevations in MPs, vascular leak, neutrophil sequestration and AP prolongation. These manifestations of tissue injury also did not occur in mice lacking myeloperoxidase. Vascular leakage and AP prolongation were produced in nave mice infused with MPs that had been obtained from CO poisoned mice, but this did not occur with MPs obtained from control mice. We conclude that CO poisoning triggers elevations of MPs that activate neutrophils which subsequently cause tissue injuries. - Highlights: Circulating microparticles (MPs) increase in mice exposed to 100 ppm CO or more. MPs are lysed by infusing the surfactant polyethylene glycol telomere B. CO-induced MPs cause neutrophil activation, vascular leak and CNS dysfunction. Similar tissue injuries do not arise with MPs obtained from air-exposed, control mice.

  7. A population-based exposure assessment methodology for carbon monoxide: Development of a carbon monoxide passive sampler and occupational dosimeter

    SciTech Connect (OSTI)

    Apte, M.G.

    1997-09-01

    Two devices, an occupational carbon monoxide (CO) dosimeter (LOCD), and an indoor air quality (IAQ) passive sampler were developed for use in population-based CO exposure assessment studies. CO exposure is a serious public health problem in the U.S., causing both morbidity and mortality (lifetime mortality risk approximately 10{sup -4}). Sparse data from population-based CO exposure assessments indicate that approximately 10% of the U.S. population is exposed to CO above the national ambient air quality standard. No CO exposure measurement technology is presently available for affordable population-based CO exposure assessment studies. The LOCD and IAQ Passive Sampler were tested in the laboratory and field. The palladium-molybdenum based CO sensor was designed into a compact diffusion tube sampler that can be worn. Time-weighted-average (TWA) CO exposure of the device is quantified by a simple spectrophotometric measurement. The LOCD and IAQ Passive Sampler were tested over an exposure range of 40 to 700 ppm-hours and 200 to 4200 ppm-hours, respectively. Both devices were capable of measuring precisely (relative standard deviation <20%), with low bias (<10%). The LOCD was screened for interferences by temperature, humidity, and organic and inorganic gases. Temperature effects were small in the range of 10{degrees}C to 30{degrees}C. Humidity effects were low between 20% and 90% RH. Ethylene (200 ppm) caused a positive interference and nitric oxide (50 ppm) caused a negative response without the presence of CO but not with CO.

  8. New clean fuel from coal -- Direct dimethyl ether synthesis from hydrogen and carbon monoxide

    SciTech Connect (OSTI)

    Ogawa, T.; Ono, M.; Mizuguchi, M.; Tomura, K.; Shikada, T.; Ohono, Y.; Fujimoto, K.

    1997-12-31

    Dimethyl ether (DME), which has similar physical properties to propane and is easily liquefied at low pressure, has a significant possibility as a clean and non-toxic fuel from coal or coal bed methane. Equilibrium calculation also shows a big advantage of high carbon monoxide conversion of DME synthesis compared to methanol synthesis. By using a 50 kg/day DME bench scale test plant, direct synthesis of DME from hydrogen and carbon monoxide has been studied with newly developed catalysts which are very fine particles. This test plant features a high pressure three-phase slurry reactor and low temperature DME separator. DME is synthesized at temperatures around 533--553 K and at pressures around 3--5 MPa. According to the reaction stoichiometry, the same amount of hydrogen and carbon monoxide react to DME and carbon dioxide. Carbon conversion to DME is one third and the rest of carbon is converted to carbon dioxide. As a result of the experiments, make-up CO conversion is 35--50% on an once-through basis, which is extremely high compared to that of methanol synthesis from hydrogen and carbon monoxide. DME selectivity is around 60 c-mol %. Most of the by-product is CO{sub 2} with a small amount of methanol and water. No heavy by-products have been recognized. Effluent from the reactor is finally cooled to 233--253 K in a DME separator and liquid DME is recovered as a product.

  9. Substantially isotactic, linear, alternating copolymers of carbon monoxide and an olefin

    DOE Patents [OSTI]

    Sen, Ayusman; Jiang, Zhaozhong

    1996-01-01

    The compound, [Pd(Me-DUPHOS)(MeCN).sub.2 ](BF.sub.4).sub.2, [Me-DUPHOS: 1,2-bis(2,5-dimethylphospholano)benzene] is an effective catalyst for the highly enantioselective, alternating copolymerization of olefins, such as aliphatic .alpha.-olefins, with carbon monoxide to form optically active, isotactic polymers which can serve as excellent starting materials for the synthesis of other classes of chiral polymers. For example, the complete reduction of a propylene-carbon monoxide copolymer resulted in the formation of a novel, optically active poly(1,4-alcohol). Also, the previously described catalyst is a catalyst for the novel alternating isomerization cooligomerization of 2-butene with carbon monoxide to form optically active, isotactic poly(1,5-ketone)

  10. Substantially isotactic, linear, alternating copolymers of carbon monoxide and an olefin

    DOE Patents [OSTI]

    Sen, A.; Jiang, Z.

    1996-05-28

    The compound, [Pd(Me-DUPHOS)(MeCN){sub 2}](BF{sub 4}){sub 2}, [Me-DUPHOS: 1,2-bis(2,5-dimethylphospholano)benzene] is an effective catalyst for the highly enantioselective, alternating copolymerization of olefins, such as aliphatic {alpha}-olefins, with carbon monoxide to form optically active, isotactic polymers which can serve as excellent starting materials for the synthesis of other classes of chiral polymers. For example, the complete reduction of a propylene-carbon monoxide copolymer resulted in the formation of a novel, optically active poly(1,4-alcohol). Also, the previously described catalyst is a catalyst for the novel alternating isomerization cooligomerization of 2-butene with carbon monoxide to form optically active, isotactic poly(1,5-ketone).

  11. Process for producing methane from gas streams containing carbon monoxide and hydrogen

    DOE Patents [OSTI]

    Frost, Albert C.

    1980-01-01

    Carbon monoxide-containing gas streams are passed over a catalyst capable of catalyzing the disproportionation of carbon monoxide so as to deposit a surface layer of active surface carbon on the catalyst essentially without formation of inactive coke thereon. The surface layer is contacted with steam and is thus converted to methane and CO.sub.2, from which a relatively pure methane product may be obtained. While carbon monoxide-containing gas streams having hydrogen or water present therein can be used only the carbon monoxide available after reaction with said hydrogen or water is decomposed to form said active surface carbon. Although hydrogen or water will be converted, partially or completely, to methane that can be utilized in a combustion zone to generate heat for steam production or other energy recovery purposes, said hydrogen is selectively removed from a CO--H.sub.2 -containing feed stream by partial oxidation thereof prior to disproportionation of the CO content of said stream.

  12. Molten metal reactor and method of forming hydrogen, carbon monoxide and carbon dioxide using the molten alkaline metal reactor

    DOE Patents [OSTI]

    Bingham, Dennis N.; Klingler, Kerry M.; Turner, Terry D.; Wilding, Bruce M.

    2012-11-13

    A molten metal reactor for converting a carbon material and steam into a gas comprising hydrogen, carbon monoxide, and carbon dioxide is disclosed. The reactor includes an interior crucible having a portion contained within an exterior crucible. The interior crucible includes an inlet and an outlet; the outlet leads to the exterior crucible and may comprise a diffuser. The exterior crucible may contain a molten alkaline metal compound. Contained between the exterior crucible and the interior crucible is at least one baffle.

  13. In situ gasification process for producing product gas enriched in carbon monoxide and hydrogen

    DOE Patents [OSTI]

    Capp, John P.; Bissett, Larry A.

    1978-01-01

    The present invention is directed to an in situ coal gasification process wherein the combustion zone within the underground coal bed is fed with air at increasing pressure to increase pressure and temperature in the combustion zone for forcing product gases and water naturally present in the coal bed into the coal bed surrounding the combustion zone. No outflow of combustion products occurs during the build-up of pressure and temperature in the combustion zone. After the coal bed reaches a temperature of about 2000.degree. F and a pressure in the range of about 100-200 psi above pore pressure the airflow is terminated and the outflow of the combustion products from the combustion zone is initiated. The CO.sub.2 containing gaseous products and the water bleed back into the combustion zone to react endothermically with the hot carbon of the combustion zone to produce a burnable gas with a relatively high hydrogen and carbon monoxide content. About 11 to 29 percent of the gas recovered from the combustion zone is carbon monoxide which is considerably better than the 4 to 10 percent carbon monoxide obtained by employing previously known coal gasification techniques.

  14. Effects on carbon monoxide levels in mobile homes using unvented kerosene heaters for residential heating

    SciTech Connect (OSTI)

    Williams, R.; Walsh, D.; White, J.; Jackson, M.; Mumford, J.

    1992-01-01

    Carbon monoxide (CO) emission levels were continuously monitored in 8 mobile trailer homes less than 10 years old. These homes were monitored in an US EPA study on indoor air quality as affected by unvented portable kerosene heaters. Respondents were asked to operate their heaters in a normal fashion. CO, air exchange and temperature values were measured during the study in each home. Results indicate that consumers using unvented kerosene heaters may be unknowingly exposed to high CO levels without taking proper precautions.

  15. New analytical reagents for the determination of sulfur dioxide and carbon monoxide

    SciTech Connect (OSTI)

    Trump, E.L.

    1987-01-01

    Four solid reagent methods were developed for the determination of sulfur dioxide in air, and one method was developed to measure carbon monoxide. When applied to filter paper with acetamide as the humectant and 4-phenylcyclohexanone as a bisulfite absorbent, oxohydroxybis(8-hydroxyquinolinyl-) vanadium (V) changes from yellow to black in the presence of sulfur dioxide. The three other methods, also on a filter paper support, utilized the reduction of bromate to bromine which then changed 3-,3'-, 5-,5'-tetramethylbenzidine from yellow to blue, phenothiazine from white to green, and 4-dimethylamino-4'-,4/double prime/-dimethoxytriphenylmethanol from colorless to red-purple. Quantitative measurements were made by reflectance spectroscopy. The method for carbon monoxide involved the use of tetrakis (acetamide-) Pd(II) ditetrafluoroborate, sodium iodate, and leuco crystal violet all together on a filter paper support. Carbon monoxide reduced the Pd(II)-acetamide complex to metallic palladium. The metallic palladium then reduced iodate to hypoiodous acid, HOI, which, in turn, oxidized leuco crystal violet to crystal violet. The crystal violet color was then measured by reflectance.

  16. Transient control of carbon monoxide with staged PrOx reactors

    SciTech Connect (OSTI)

    Inbody, M. A.; Borup, R. L.; Tafoya, J.

    2002-01-01

    Fuel Processor systems generate hydrogen for fuel cell systems from hydrocarbon fuels such as gasoline for automotive fuel cell systems and natural gas for stationary fuel cell systems. These fuel processor systems must remove any contaminants to levels that won't poison the fuel cell before the outlet hydrogen-rich gas stream can be used by the fuel cell to generate electricity. Carbon monoxide is a contaminant that must be removed to levels of < 100 ppm or < 10 ppm depending on the CO tolerance of the fuel cell. Typically, the last unit operation in a fuel processor is a preferential oxidation reactor or a selective oxidation reactor, which removes CO by oxidizing it to form C02. These are catalytic reactors where the catalyst and operating conditions are selected so that the oxidation rate of the carbon monoxide is higher than the oxidation rate of hydrogen, even though the hydrogen is present at much higher concentrations (> 30%) than carbon monoxide which is present at trace concentrations (< 1%).

  17. Reaction of uranium oxides with chlorine and carbon or carbon monoxide to prepare uranium chlorides

    SciTech Connect (OSTI)

    Haas, P.A.; Lee, D.D.; Mailen, J.C.

    1991-11-01

    The preferred preparation concept of uranium metal for feed to an AVLIS uranium enrichment process requires preparation of uranium tetrachloride (UCI{sub 4}) by reacting uranium oxides (UO{sub 2}/UO{sub 3}) and chlorine (Cl{sub 2}) in a molten chloride salt medium. UO{sub 2} is a very stable metal oxide; thus, the chemical conversion requires both a chlorinating agent and a reducing agent that gives an oxide product which is much more stable than the corresponding chloride. Experimental studies in a quartz reactor of 4-cm ID have demonstrated the practically of some chemical flow sheets. Experimentation has illustrated a sequence of results concerning the chemical flow sheets. Tests with a graphite block at 850{degrees}C demonstrated rapid reactions of Cl{sub 2} and evolution of carbon dioxide (CO{sub 2}) as a product. Use of carbon monoxide (CO) as the reducing agent also gave rapid reactions of Cl{sub 2} and formation of CO{sub 2} at lower temperatures, but the reduction reactions were slower than the chlorinations. Carbon powder in the molten salt melt gave higher rates of reduction and better steady state utilization of Cl{sub 2}. Addition of UO{sub 2} feed while chlorination was in progress greatly improved the operation by avoiding the plugging effects from high UO{sub 2} concentrations and the poor Cl{sub 2} utilizations from low UO{sub 2} concentrations. An UO{sub 3} feed gave undesirable effects while a feed of UO{sub 2}-C spheres was excellent. The UO{sub 2}-C spheres also gave good rates of reaction as a fixed bed without any molten chloride salt. Results with a larger reactor and a bottom condenser for volatilized uranium show collection of condensed uranium chlorides as a loose powder and chlorine utilizations of 95--98% at high feed rates. 14 refs., 7 figs., 14 tabs.

  18. Thermal device and method for production of carbon monoxide and hydrogen by thermal dissociation of hydrocarbon gases

    DOE Patents [OSTI]

    Detering, Brent A.; Kong, Peter C.

    2001-01-01

    Carbon monoxide is produced in a fast quench reactor. The production of carbon monoxide includes injecting carbon dioxide and some air into a reactor chamber having a high temperature at its inlet and a rapidly expanding a reactant stream, such as a restrictive convergent-divergent nozzle at its outlet end. Carbon dioxide and other reactants such as methane and other low molecular weight hydrocarbons are injected into the reactor chamber. Other gas may be added at different stages in the process to form a desired end product and prevent back reactions. The resulting heated gaseous stream is then rapidly cooled by expansion of the gaseous stream.

  19. Effectiveness of Diesel Oxidation Catalyst in Reducing HC and CO Emissions from Reactivity Controlled Compression Ignition

    SciTech Connect (OSTI)

    Prikhodko, Vitaly Y; Curran, Scott; Parks, II, James E; Wagner, Robert M

    2013-01-01

    Reactivity Controlled Compression Ignition (RCCI) has been shown to allow for diesel-like or better brake thermal efficiency with significant reductions in nitrogen oxide (NOX) particulate matter (PM) emissions. Hydrocarbon (HC) and carbon monoxide (CO) emission levels, on the other hand, are similar to those of port fuel injected gasoline engines. The higher HC and CO emissions combined with the lower exhaust temperatures with RCCI operation present a challenge for current exhaust aftertreatments. The reduction of HC and CO emissions in a lean environment is typically achieved with an oxidation catalyst. In this work, several diesel oxidation catalysts (DOC) with different precious metal loadings were evaluated for effectiveness to control HC and CO emissions from RCCI combustion in a light-duty multi-cylinder engine operating on gasoline and diesel fuels. Each catalyst was evaluated in a steady-state engine operation with temperatures ranging from 160 to 260 C. A shift to a higher light-off temperature was observed during the RCCI operation. In addition to the steady-state experiments, the performances of the DOCs were evaluated during multi-mode engine operation by switching from diesel-like combustion at higher exhaust temperature and low HC/CO emissions to RCCI combustion at lower temperature and higher HC/CO emissions. High CO and HC emissions from RCCI generated an exotherm keeping the catalyst above the light-off temperature.

  20. Use of hydrogen-free carbon monoxide with steam in recovery of heavy oil at low temperatures

    SciTech Connect (OSTI)

    Hyne, J. B.; Tyrer, J. D.

    1984-12-11

    A process for recovering oil from a subterranean heavy oil-containing reservoir is provided, wherein steam and carbon monoxide are injected into the reservoir at a temperature less than about 260/sup 0/ C. At these low temperatures, the steam and hydrogen-free carbon monoxide are found to react in the reservoir, by the water gas reaction, to form carbon dioxide and hydrogen. These products both have upgrading effects on the heavy oil, enhancing its quality and producibility. At the low temperatures of the process, gasification and polymerization of the heavy oil are minimized.

  1. Carbon monoxide tolerant electrocatalyst with low platinum loading and a process for its preparation

    DOE Patents [OSTI]

    Adzic, Radoslav; Brankovic, Stanko; Wang, Jia

    2003-12-30

    An electrocatalyst is provided for use in a fuel cell that has low platinum loading and a high tolerance to carbon monoxide poisoning. The fuel cell anode includes an electrocatalyst that has a conductive support material, ruthenium nanoparticles reduced in H.sub.2 and a Group VIII noble metal in an amount of between about 0.1 and 25 wt % of the ruthenium nanoparticles, preferably between about 0.5 and 15 wt %. The preferred Group VIII noble metal is platinum. In one embodiment, the anode can also have a perfluorinated polymer membrane on its surface.

  2. An overview of carbon monoxide generation and release by home appliances

    SciTech Connect (OSTI)

    Batey, J.

    1997-09-01

    Carbon monoxide (CO) is an odorless, colorless and tasteless gas which is highly toxic and can be produced by many combustion sources commonly found within homes. Potential sources include boilers and furnaces, water heaters, space heaters, stoves, ovens, clothes dryers, wood stoves, fireplaces, charcoal grilles, automobiles, cigarettes, oil lamps, and candles. Any fuel that contains carbon can form CO including, natural gas, propane, kerosene, fuel oil, wood, and coal. Exposure to elevated CO levels typically requires its production by a combustion source and its release into the home through a venting system malfunction. The health effects of CO range from headaches and flue-like symptoms to loss of concentration, coma and death depending on the concentration of CO and the exposure time. At levels of only 1%, which is the order of magnitude produced by automobile exhaust, carbon monoxide can cause death in less than 3 minutes. While most combustion equipment operate with low CO levels, many operating factors can contribute to elevated CO levels in the home including: burner adjustment, combustion air supply, house air-tightness, exhaust fan operation, cracked heat exchangers, vent blockages, and flue pipe damage. Test data on CO emissions is presented from a wide range of sources including Brookhaven National Laboratory, Gas Research Institute, American Gas Association, the US Environmental Protection Agency, and the US Consumer Product Safety Commission for many potential CO sources in and near the home.

  3. Process for producing hydrogen and carbonyl sulfide from hydrogen sulfide and carbon monoxide using a heteropolyanionic metal complex catalyst

    SciTech Connect (OSTI)

    Kuch, Ph. L.

    1984-12-18

    Hydrogen and carbonyl sulfide are produced by a process comprising contracting gaseous hydrogen sulfide with gaseous carbon monoxide in the presence of a heteropolymolybdate or tungstate complex. Use of these catalysts reduce the amount of by-product carbon dioxide and methane formation and thus enhance the make of hydrogen and carbonyl sulfide.

  4. Effects of solar radiation on organic matter cycling: Formation of carbon monoxide and carbonyl sulfide (Chapter 11). Book chapter

    SciTech Connect (OSTI)

    Zepp, R.G.

    1994-01-01

    The effects of photoinduced processes on carbon cycling and the biospheric emission of two important trace carbon gases--carbon monoxide and carbonyl sulfide--are examined. Both of these gases are likely to play an important role in the biospheric feedbacks that may reinforce or attenuate future changes in climate. Evidence is presented to support the hypothesis that a significant fraction of the global sources of both of these gases derives from the photochemical fragmentation of decayed plant materials and other biogenic organic matter in terrestrial and marine environments.

  5. Heterologous production of an energy-conserving carbon monoxide dehydrogenase complex in the hyperthermophile Pyrococcus furiosus

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schut, Gerrit J.; Lipscomb, Gina L.; Nguyen, Diep M. N.; Kelly, Robert M.; Adams, Michael W. W.

    2016-01-29

    In this study, carbon monoxide (CO) is an important intermediate in anaerobic carbon fixation pathways in acetogenesis and methanogenesis. In addition, some anaerobes can utilize CO as an energy source. In the hyperthermophilic archaeon Thermococcus onnurineus, which grows optimally at 80°C, CO oxidation and energy conservation is accomplished by a respiratory complex encoded by a 16-gene cluster containing a CO dehydrogenase, a membrane-bound [NiFe]-hydrogenase and a Na+/H+ antiporter module. This complex oxidizes CO, evolves CO2 and H2, and generates a Na+ motive force that is used to conserve energy by a Na+-dependent ATP synthase. Herein we used a bacterial artificialmore » chromosome to insert the 13.2 kb gene cluster encoding the CO-oxidizing respiratory complex of T. onnurineus into the genome of the heterotrophic archaeon, Pyrococcus furiosus, which grows optimally at 100° C. P. furiosus is normally unable to utilize CO, however, the recombinant strain readily oxidized CO and generated H2 at 80° C. Moreover, CO also served as an energy source and allowed the P. furiosus strain to grow with a limiting concentration of sugar or with peptides as the carbon source. Moreover, CO oxidation by P. furiosus was also coupled to the re-utilization, presumably for biosynthesis, of acetate generated by fermentation. The functional transfer of CO utilization between Thermococcus and Pyrococcus species demonstrated herein is representative of the horizontal gene transfer of an environmentally relevant metabolic capability. The transfer of CO utilizing, hydrogen-producing genetic modules also has applications for biohydrogen production and a CO-based industrial platform for various thermophilic organisms.« less

  6. Oxygen isotope fractionation in the vacuum ultraviolet photodissociation of carbon monoxide: Wavelength, pressure and temperature dependency.

    SciTech Connect (OSTI)

    Chakraborty, Subrata; Davis, Ryan; Ahmed, Musahid; Jackson, Teresa L.; Thiemens, Mark H.

    2012-01-03

    Several absorption bands exist in the VUV region of Carbon monoxide (CO). Emission spectra indicate that these bands are all predissociative. An experimental investigation of CO photodissociation by vacuum ultraviolet photons (90 to 108 nm; ~13 to 11 eV) from the Advanced Light Source Synchrotron and direct measurement of the associated oxygen isotopic composition of the products are presented here. A wavelength dependency of the oxygen isotopic composition in the photodissociation product was observed. Slope values (δ'{sup 18}O/ δ'{sup 17}O) ranging from 0.76 to 1.32 were observed in oxygen three-isotope space (δ'{sup 18}O vs. δ'{sup 17}O) which correlated with increasing synchrotron photon energy, and indicate a dependency of the upper electronic state specific dissociation dynamics (e.g., perturbation and coupling associated with a particular state). An unprecedented magnitude in isotope separation was observed for photodissociation at the 105 and 107 nm synchrotron bands and are found to be associated with accidental predissociation of the vibrational states ({nu} = 0 and 1) of the upper electronic state E{sup 1}Π. For each synchrotron band, a large (few hundred per mil) extent of isotopic fractionation was observed and the range of fractionation is a combination of column density and exposure time. A significant temperature dependency in oxygen isotopic fractionation was observed, indicating a rotational level dependency in the predissociation process.

  7. Relationship of respiratory symptoms and pulmonary function to tar, nicotine, and carbon monoxide yield of cigarettes

    SciTech Connect (OSTI)

    Krzyzanowski, M.; Sherrill, D.L.; Paoletti, P.; Lebowitz, M.D. )

    1991-02-01

    The data from consecutive surveys of the Tucson Epidemiologic Study (1981-1988) were used to evaluate the relationship in cigarette smokers of respiratory symptoms and pulmonary function to tar, nicotine, and carbon monoxide (CO) yields of the cigarette. There were 690 subjects who reported smoking regularly in at least one survey, over age 15. After adjustment for intensity and duration of smoking and for depth of inhalation, the risk of chronic phlegm, cough, and dyspnea were not related to the tar and nicotine yields. In 414 subjects with pulmonary function tested in at least one of the three surveys the spirometric indices used were significantly related to the daily dose of tar, nicotine, and CO (product of the cigarette yield and daily number of cigarettes smoked). The effects were more pronounced for past than for current doses. However, the differentiation of pulmonary function due to various yields of cigarettes was small in comparison to the difference in pulmonary function between smokers and nonsmokers.

  8. Genome Annotation Provides Insight into Carbon Monoxide and Hydrogen Metabolism in Rubrivivax gelatinosus

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wawrousek, Karen; Noble, Scott; Korlach, Jonas; Chen, Jin; Eckert, Carrie; Yu, Jianping; Maness, Pin-Ching

    2014-12-05

    In this article, we report here the sequencing and analysis of the genome of the purple non-sulfur photosynthetic bacterium Rubrivivax gelatinosus CBS. This microbe is a model for studies of its carboxydotrophic life style under anaerobic condition, based on its ability to utilize carbon monoxide (CO) as the sole carbon substrate and water as the electron acceptor, yielding CO2 and H2 as the end products. The CO-oxidation reaction is known to be catalyzed by two enzyme complexes, the CO dehydrogenase and hydrogenase. As expected, analysis of the genome of Rx. gelatinosus CBS reveals the presence of genes encoding both enzymemore » complexes. The CO-oxidation reaction is CO-inducible, which is consistent with the presence of two putative CO-sensing transcription factors in its genome. Genome analysis also reveals the presence of two additional hydrogenases, an uptake hydrogenase that liberates the electrons in H2 in support of cell growth, and a regulatory hydrogenase that senses H2 and relays the signal to a two-component system that ultimately controls synthesis of the uptake hydrogenase. The genome also contains two sets of hydrogenase maturation genes which are known to assemble the catalytic metallocluster of the hydrogenase NiFe active site. Finally and collectively, the genome sequence and analysis information reveals the blueprint of an intricate network of signal transduction pathways and its underlying regulation that enables Rx. gelatinosus CBS to thrive on CO or H2 in support of cell growth.« less

  9. SOFT X-RAY IRRADIATION OF PURE CARBON MONOXIDE INTERSTELLAR ICE ANALOGUES

    SciTech Connect (OSTI)

    Ciaravella, A.; Candia, R.; Collura, A.; Jimenez-Escobar, A.; Munoz Caro, G. M.; Cecchi-Pestellini, C.; Giarrusso, S.; Barbera, M.

    2012-02-10

    There is an increasing evidence for the existence of large organic molecules in the interstellar and circumstellar medium. Very few among such species are readily formed in conventional gas-phase chemistry under typical conditions of interstellar clouds. Attention has therefore focused on interstellar ices as a potential source of these relatively complex species. Laboratory experiments show that irradiation of interstellar ice analogues by fast particles or ultraviolet radiation can induce significant chemical complexity. However, stars are sources of intense X-rays at almost every stage of their formation and evolution. Such radiation may thus provide chemical changes in regions where ultraviolet radiation is severely inhibited. After H{sub 2}O, CO is often the most abundant component of icy grain mantles in dense interstellar clouds and circumstellar disks. In this work we present irradiation of a pure carbon monoxide ice using a soft X-ray spectrum peaked at 0.3 keV. Analysis of irradiated samples shows formation of CO{sub 2}, C{sub 2}O, C{sub 3}O{sub 2}, C{sub 3}, C{sub 4}O, and CO{sub 3}/C{sub 5}. Comparison of X-rays and ultraviolet irradiation experiments, of the same energy dose, shows that X-rays are more efficient than ultraviolet radiation in producing new species. With the exception of CO{sub 2}, X-ray photolysis induces formation of a larger number of products with higher abundances, e.g., C{sub 3}O{sub 2} column density is about one order of magnitude higher in the X-ray experiment. To our knowledge this is the first report on X-ray photolysis of CO ices. The present results show that X-ray irradiation represents an efficient photo-chemical way to convert simple ices to more complex species.

  10. REFORMULATION OF COAL-DERIVED TRANSPORTATION FUELS: SELECTIVE OXIDATION OF CARBON MONOXIDE ON METAL FOAM CATALYSTS

    SciTech Connect (OSTI)

    Mr. Paul Chin; Dr. Xiaolei Sun; Professor George W. Roberts; Professor James J. Spivey; Mr. Amornmart Sirijarhuphan; Dr. James G. Goodwin, Jr.; Dr. Richard W. Rice

    2002-12-31

    Several different catalytic reactions must be carried out in order to convert hydrocarbons (or alcohols) into hydrogen for use as a fuel for polyelectrolyte membrane (PEM) fuel cells. Each reaction in the fuel-processing sequence has a different set of characteristics, which influences the type of catalyst support that should be used for that particular reaction. A wide range of supports are being evaluated for the various reactions in the fuel-processing scheme, including porous and non-porous particles, ceramic and metal straight-channel monoliths, and ceramic and metal monolithic foams. These different types of support have distinctly different transport characteristics. The best choice of support for a given reaction will depend on the design constraints for the system, e.g., allowable pressure drop, and on the characteristics of the reaction for which the catalyst is being designed. Three of the most important reaction characteristics are the intrinsic reaction rate, the exothermicity/endothermicity of the reaction, and the nature of the reaction network, e.g., whether more than one reaction takes place and, in the case of multiple reactions, the configuration of the network. Isotopic transient kinetic analysis was used to study the surface intermediates. The preferential oxidation of low concentrations of carbon monoxide in the presence of high concentrations of hydrogen (PROX) is an important final step in most fuel processor designs. Data on the behavior of straight-channel monoliths and foam monolith supports will be presented to illustrate some of the factors involved in choosing a support for this reaction.

  11. HC-NIDS

    Energy Science and Technology Software Center (OSTI)

    003182WKSTN00 HC-NIDS: signatures and simulations for detecting cyber-attacks aiming to cause damage against cyber-physical energy systems not yet decided

  12. Process for the production of hydrogen and carbonyl sulfide from hydrogen sulfide and carbon monoxide using a metal boride, nitride, carbide and/or silicide catalyst

    SciTech Connect (OSTI)

    McGuiggan, M.F.; Kuch, P.L.

    1984-05-08

    Hydrogen and carbonyl sulfide are produced by a process comprising contacting gaseous hydrogen sulfide with gaseous carbon monoxide in the presence of a metal boride, carbide, nitride and/or silicide catalyst, such as titanium carbide, vanadium boride, manganese nitride or molybdenum silicide.

  13. On the formation of carbonyl sulfide in the reduction of sulfur dioxide by carbon monoxide on lanthanum oxysulfide catalyst: A study by XPS and TPR/MS

    SciTech Connect (OSTI)

    Lau, N.T.; Fang, M. [Hong Kong Univ. of Science and Technology, Clear Water Bay (Hong Kong). Applied Technology Center] [Hong Kong Univ. of Science and Technology, Clear Water Bay (Hong Kong). Applied Technology Center

    1998-10-25

    Both the X-ray photoelectron spectroscopy (XPS) and temperature-programmed reaction, coupled with mass spectrometry (TPR/MS), are used to study the formation of carbonyl sulfide in the reduction of sulfur dioxide on lanthanum oxysulfide catalyst. It was found that the lattice sulfur of the oxysulfide is released and reacts with carbon monoxide to form carbonyl sulfide when the oxysulfide is heated. The oxysulfide is postulated to form sulfur vacancies at a temperature lower than that for the formation of carbonyl sulfide and atomic sulfur is released in the process. The atomic sulfur can either enter the gas phase and leave the oxysulfide catalyst or react with carbon monoxide to form carbonyl sulfide.

  14. Catalysts for the production of hydrocarbons from carbon monoxide and water

    DOE Patents [OSTI]

    Sapienza, R.S.; Slegeir, W.A.; Goldberg, R.I.

    1985-11-06

    A method of converting low H/sub 2//CO ratio syngas to carbonaceous products comprising reacting the syngas with water or steam at 200 to 350/sup 0/C in the presence of a metal catalyst supported on zinc oxide. Hydrocarbons are produced with a catalyst selected from cobalt, nickel or ruthenium and alcohols are produced with a catalyst selected from palladium, platinum, ruthenium or copper on the zinc oxide support. The ratio of the reactants are such that for alcohols and saturated hydrocarbons: (2n + 1) greater than or equal to x greater than or equal to O and for olefinic hydrocarbons: 2n greater than or equal to x greater than or equal to O where n is the number of carbon atoms in the product and x is the molar amount of water in the reaction mixture.

  15. Catalysts for the production of hydrocarbons from carbon monoxide and water

    DOE Patents [OSTI]

    Sapienza, Richard S.; Slegeir, William A.; Goldberg, Robert I.

    1987-01-01

    A method of converting low H.sub.2 /CO ratio syngas to carbonaceous products comprising reacting the syngas with water or steam at 200.degree. to 350.degree. C. in the presence of a metal catalyst supported on zinc oxide. Hydrocarbons are produced with a catalyst selected from cobalt, nickel or ruthenium and alcohols are produced with a catalyst selected from palladium, platinium, ruthenium or copper on the zinc oxide support. The ratio of the reactants are such that for alcohols and saturated hydrocarbons: (2n+1).gtoreq.x.gtoreq.O and for olefinic hydrocarbons: 2n.gtoreq.x.gtoreq.O where n is the number of carbon atoms in the product and x is the molar amount of water in the reaction mixture.

  16. Carbon monoxide alleviates ethanol-induced oxidative damage and inflammatory stress through activating p38 MAPK pathway

    SciTech Connect (OSTI)

    Li, Yanyan; Gao, Chao; Shi, Yanru; Tang, Yuhan; Liu, Liang; Xiong, Ting; Du, Min; Xing, Mingyou; Liu, Liegang; Yao, Ping

    2013-11-15

    Stress-inducible protein heme oxygenase-1(HO-1) is well-appreciative to counteract oxidative damage and inflammatory stress involving the pathogenesis of alcoholic liver diseases (ALD). The potential role and signaling pathways of HO-1 metabolite carbon monoxide (CO), however, still remained unclear. To explore the precise mechanisms, ethanol-dosed adult male Balb/c mice (5.0 g/kg.bw.) or ethanol-incubated primary rat hepatocytes (100 mmol/L) were pretreated by tricarbonyldichlororuthenium (II) dimmer (CORM-2, 8 mg/kg for mice or 20 μmol/L for hepatocytes), as well as other pharmacological reagents. Our data showed that CO released from HO-1 induction by quercetin prevented ethanol-derived oxidative injury, which was abolished by CO scavenger hemoglobin. The protection was mimicked by CORM-2 with the attenuation of GSH depletion, SOD inactivation, MDA overproduction, and the leakage of AST, ALT or LDH in serum and culture medium induced by ethanol. Moreover, CORM-2 injection or incubation stimulated p38 phosphorylation and suppressed abnormal Tnfa and IL-6, accompanying the alleviation of redox imbalance induced by ethanol and aggravated by inflammatory factors. The protective role of CORM-2 was abolished by SB203580 (p38 inhibitor) but not by PD98059 (ERK inhibitor) or SP600125 (JNK inhibitor). Thus, HO-1 released CO prevented ethanol-elicited hepatic oxidative damage and inflammatory stress through activating p38 MAPK pathway, suggesting a potential therapeutic role of gaseous signal molecule on ALD induced by naturally occurring phytochemicals. - Highlights: • CO alleviated ethanol-derived liver oxidative and inflammatory stress in mice. • CO eased ethanol and inflammatory factor-induced oxidative damage in hepatocytes. • The p38 MAPK is a key signaling mechanism for the protective function of CO in ALD.

  17. Process for the production of hydrogen and carbonyl sulfide from hydrogen sulfide and carbon monoxide using a multi-metal oxide/sulfide catalyst

    SciTech Connect (OSTI)

    Jevnikar, M. G.; Kuch, Ph. L.

    1985-02-19

    Hydrogen and carbonyl sulfide are produced by a process comprising contacting gaseous hydrogen sulfide with gaseous carbon monoxide in the presence of a catalytic composition containing an oxide and/or sulfide of at least one of molybdenum, tungsten, iron, chromium and vanadium in combination with at least one promoter metal, e.g. a catalyst of the formula Cs Cu /SUB 0.2/ Zn /SUB 0.5/ Mn /SUB 0.5/ Sn /SUB 2.4/ Mo O /SUB x/ S /SUB y/ .

  18. THE FAR-ULTRAVIOLET 'CONTINUUM' IN PROTOPLANETARY DISK SYSTEMS. II. CARBON MONOXIDE FOURTH POSITIVE EMISSION AND ABSORPTION

    SciTech Connect (OSTI)

    France, Kevin; Schindhelm, Eric; Burgh, Eric B.; Brown, Alexander; Green, James C.; Herczeg, Gregory J.; Brown, Joanna M.; Harper, Graham M.; Linsky, Jeffrey L.; Yang Hao; Abgrall, Herve; Ardila, David R.; Bergin, Edwin; Bethell, Thomas; Calvet, Nuria; Ingleby, Laura; Espaillat, Catherine; Gregory, Scott G.; Hillenbrand, Lynne A.; Hussain, Gaitee

    2011-06-10

    We exploit the high sensitivity and moderate spectral resolution of the Hubble Space Telescope Cosmic Origins Spectrograph to detect far-ultraviolet (UV) spectral features of carbon monoxide (CO) present in the inner regions of protoplanetary disks for the first time. We present spectra of the classical T Tauri stars HN Tau, RECX-11, and V4046 Sgr, representative of a range of CO radiative processes. HN Tau shows CO bands in absorption against the accretion continuum. The CO absorption most likely arises in warm inner disk gas. We measure a CO column density and rotational excitation temperature of N(CO) = (2 {+-} 1) x 10{sup 17} cm{sup -2} and T{sub rot}(CO) 500 {+-} 200 K for the absorbing gas. We also detect CO A-X band emission in RECX-11 and V4046 Sgr, excited by UV line photons, predominantly H I Ly{alpha}. All three objects show emission from CO bands at {lambda} > 1560 A, which may be excited by a combination of UV photons and collisions with non-thermal electrons. In previous observations these emission processes were not accounted for due to blending with emission from the accretion shock, collisionally excited H{sub 2}, and photo-excited H{sub 2}, all of which appeared as a 'continuum' whose components could not be separated. The CO emission spectrum is strongly dependent upon the shape of the incident stellar Ly{alpha} emission profile. We find CO parameters in the range: N(CO) {approx} 10{sup 18}-10{sup 19} cm{sup -2}, T{sub rot}(CO) {approx}> 300 K for the Ly{alpha}-pumped emission. We combine these results with recent work on photo-excited and collisionally excited H{sub 2} emission, concluding that the observations of UV-emitting CO and H{sub 2} are consistent with a common spatial origin. We suggest that the CO/H{sub 2} ratio ({identical_to} N(CO)/N(H{sub 2})) in the inner disk is {approx}1, a transition between the much lower interstellar value and the higher value observed in solar system comets today, a result that will require future

  19. HC Organization Chart | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    HC Organization Chart HC Organization Chart PDF version of the HC Organizational chart PDF icon 10-20-13 HCOrgChart.pdf More Documents & Publications Environmental Justice and ...

  20. Final Technical Report "Catalytic Hydrogenation of Carbon Monoxide and Olefin Oxidation" Grant number : DE-FG02-86ER13615

    SciTech Connect (OSTI)

    Wayland, B.B.

    2009-08-31

    Title: Catalytic Hydrogenation of Carbon Monoxide and Olefin Oxidation Grant No. DE-FG02-86ER13615 PI: Wayland, B. B. (wayland@sas.upenn.edu) Abstract Development of new mechanistic strategies and catalyst materials for activation of CO, H2, CH4, C2H4, O2, and related substrates relevant to the conversion of carbon monoxide, alkanes, and alkenes to organic oxygenates are central objectives encompassed by this program. Design and synthesis of metal complexes that manifest reactivity patterns associated with potential pathways for the hydrogenation of carbon monoxide through metallo-formyl (M-CHO), dimetal ketone (M-C(O)-M), and dimetal dionyl (M-C(O)-C(O)-M) species is one major focus. Hydrocarbon oxidation using molecular oxygen is a central goal for methane activation and functionalization as well as regioselective oxidation of olefins. Discovery of new reactivity patterns and control of selectivity are pursued through designing new metal complexes and adjusting reaction conditions. Variation of reaction media promotes distinct reaction pathways that control both reaction rates and selectivities. Dimetalloradical diporphyrin complexes preorganize transition states for substrate reactions that involve two metal centers and manifest large rate increases over mono-metalloradical reactions of hydrogen, methane, and other small molecule substrates. Another broad goal and recurring theme of this program is to contribute to the thermodynamic database for a wide scope of organo-metal transformations in a range of reaction media. One of the most complete descriptions of equilibrium thermodynamics for organometallic reactions in water and methanol is emerging from the study of rhodium porphyrin substrate reactions in aqueous and alcoholic media. Water soluble group nine metalloporphyrins manifest remarkably versatile substrate reactivity in aqueous and alcoholic media which includes producing rhodium formyl (Rh-CHO) and hydroxy methyl (Rh-CH2OH) species. Exploratory

  1. Near-ambient X-ray photoemission spectroscopy and kinetic approach to the mechanism of carbon monoxide oxidation over lanthanum substituted cobaltites

    SciTech Connect (OSTI)

    Hueso, J. L.; Martinez-Martinez, D.; Cabalerro, Alfonso; Gonzalez-Elipe, Agustin Rodriguez; Mun, Bongjin Simon; Salmeron, Miquel

    2009-07-31

    We have studied the oxidation of carbon monoxide over a lanthanum substituted perovskite (La0.5Sr0.5CoO3-d) catalyst prepared by spray pyrolysis. Under the assumption of a first-order kinetics mechanism for CO, it has been found that the activation energy barrier of the reaction changes from 80 to 40 kJ mol-1 at a threshold temperature of ca. 320 oC. In situ XPS near-ambient pressure ( 0.2 torr) shows that the gas phase oxygen concentration over the sample decreases sharply at ca. 300 oC. These two observations suggest that the oxidation of CO undergoes a change of mechanism at temperatures higher than 300 oC.

  2. TableHC2.7.xls

    Gasoline and Diesel Fuel Update (EIA)

    ... Table HC7.7 Air-Conditioning Usage Indicators by Household Income, 2005 Below Poverty Line ... Table HC7.7 Air-Conditioning Usage Indicators by Household Income, 2005 Below Poverty Line ...

  3. TableHC2.10.xls

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    ... Table HC7.10 Home Appliances Usage Indicators by Household Income, 2005 Below Poverty Line ... Table HC7.10 Home Appliances Usage Indicators by Household Income, 2005 Below Poverty Line ...

  4. Integrated Removal of NOx with Carbon Monoxide as Reductant, and Capture of Mercury in a Low Temperature Selective Catalytic and Adsorptive Reactor

    SciTech Connect (OSTI)

    Neville Pinto; Panagiotis Smirniotis; Stephen Thiel

    2010-08-31

    Coal will likely continue to be a dominant component of power generation in the foreseeable future. This project addresses the issue of environmental compliance for two important pollutants: NO{sub x} and mercury. Integration of emission control units is in principle possible through a Low Temperature Selective Catalytic and Adsorptive Reactor (LTSCAR) in which NO{sub x} removal is achieved in a traditional SCR mode but at low temperature, and, uniquely, using carbon monoxide as a reductant. The capture of mercury is integrated into the same process unit. Such an arrangement would reduce mercury removal costs significantly, and provide improved control for the ultimate disposal of mercury. The work completed in this project demonstrates that the use of CO as a reductant in LTSCR is technically feasible using supported manganese oxide catalysts, that the simultaneous warm-gas capture of elemental and oxidized mercury is technically feasible using both nanostructured chelating adsorbents and ceria-titania-based materials, and that integrated removal of mercury and NO{sub x} is technically feasible using ceria-titania-based materials.

  5. TableHC2.12.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    ... Table HC7.12 Home Electronics Usage Indicators by Household Income, 2005 Below Poverty ... Below Poverty Line Eligible for Federal Assistance 1 2005 Household Income Housing Units ...

  6. TableHC7.3.xls

    Gasoline and Diesel Fuel Update (EIA)

    Income Relative to Poverty Line Below 100 Percent...... Below Poverty Line Eligible for Federal Assistance 1 80,000 or More Table HC7.3 Household ...

  7. TableHC7.8.xls

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ... Table HC7.8 Water Heating Characteristics by Household Income, 2005 Below Poverty Line ... Below Poverty Line Eligible for Federal Assistance 1 Million U.S. Housing Units 80,000 or ...

  8. TableHC2.8.xls

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    ... Table HC7.8 Water Heating Characteristics by Household Income, 2005 Below Poverty Line ... Below Poverty Line Eligible for Federal Assistance 1 Million U.S. Housing Units 80,000 or ...

  9. TableHC2.13.xls

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    ... Table HC7.13 Lighting Usage Indicators by Household Income, 2005 Below Poverty Line ... Below Poverty Line Eligible for Federal Assistance 1 Million U.S. Housing Units 2005 ...

  10. TableHC7.13.xls

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    ... Table HC7.13 Lighting Usage Indicators by Household Income, 2005 Below Poverty Line ... Below Poverty Line Eligible for Federal Assistance 1 Million U.S. Housing Units 2005 ...

  11. HQ Employee/Labor Management Relations Division (HC-33) | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EmployeeLabor Management Relations Division (HC-33) HQ EmployeeLabor Management Relations Division (HC-33) Functions Provide laboremployee management relations advisory services ...

  12. Office of the Chief Human Capital Officer (HC-1) | Department...

    Broader source: Energy.gov (indexed) [DOE]

    HC-1 Mission and Function Statement The Office of the Chief Human Capital Officer (HC) ... agreementsrelationships related to all aspects of Human Capital Management (HCM). ...

  13. Formation of ketene (H{sub 2}CCO) in interstellar analogous methane (CH{sub 4})-carbon monoxide (CO) ices: A combined FTIR and reflectron time-of-flight mass spectroscopic study

    SciTech Connect (OSTI)

    Maity, Surajit; Kaiser, Ralf I.; Jones, Brant M.

    2014-07-01

    The formation of ketene (H{sub 2}CCO) in methane-carbon monoxide (CH{sub 4}-CO) ices was investigated upon its exposure to ionizing radiation in the form of energetic electrons at 5.5 K. The radiation-induced nonthermal equilibrium processing of these ices was monitored online and in situ via infrared spectroscopy complimented with post-irradiation temperature programmed desorption studies exploiting highly sensitive reflectron time-of-flight mass spectrometry (ReTOF) coupled with single photon fragment-free photo ionization (PI) at 10.49 eV. The detection of ketene in irradiated (isotopically labeled) methane-carbon monoxide ices was confirmed via the ?{sub 2} infrared absorption band and substantiated during the warm-up phase based on sublimation profiles obtained from the ReTOF-PI spectra of the corresponding isotopic masses. The experiments conducted with the mixed isotopic ices of {sup 12}CD{sub 4}-{sup 13}CO provide clear evidence of the formation of at least two ketene isotopomers (D{sub 2} {sup 12}C{sup 13}CO and D{sub 2} {sup 13}C{sup 13}CO), allowing for the derivation of two competing formation pathways. We have also proposed underlying reaction mechanisms to the formation of ketene based on kinetic fitting of the temporal evolution of the ketene isotopomers.

  14. Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N-Heterocyclic Carbene-Isoquinoline Complex

    SciTech Connect (OSTI)

    Thoi, VanSara; Kornienko, Nick; Margarit, C; Yang, Peidong; Chang, Christopher

    2013-06-07

    The solar-driven reduction of carbon dioxide to value-added chemical fuels is a longstanding challenge in the fields of catalysis, energy science, and green chemistry. In order to develop effective CO2 fixation, several key considerations must be balanced, including (1) catalyst selectivity for promoting CO2 reduction over competing hydrogen generation from proton reduction, (2) visible-light harvesting that matches the solar spectrum, and (3) the use of cheap and earth-abundant catalytic components. In this report, we present the synthesis and characterization of a new family of earth-abundant nickel complexes supported by N-heterocyclic carbene amine ligands that exhibit high selectivity and activity for the electrocatalytic and photocatalytic conversion of CO2 to CO. Systematic changes in the carbene and amine donors of the ligand have been surveyed, and [Ni(Prbimiq1)]2+ (1c, where Prbimiq1 = bis(3-(imidazolyl)isoquinolinyl)propane) emerges as a catalyst for electrochemical reduction of CO2 with the lowest cathodic onset potential (Ecat = 1.2 V vs SCE). Using this earth-abundant catalyst with Ir(ppy)3 (where ppy = 2-phenylpyridine) and an electron donor, we have developed a visible-light photoredox system for the catalytic conversion of CO2 to CO that proceeds with high selectivity and activity and achieves turnover numbers and turnover frequencies reaching 98,000 and 3.9 s1, respectively. Further studies reveal that the overall efficiency of this solar-to-fuel cycle may be limited by the formation of the active Ni catalyst and/or the chemical reduction of CO2 to CO at the reduced nickel center and provide a starting point for improved photoredox systems for sustainable carbon-neutral energy conversion.

  15. santa_fe-hc2.key

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Multiband superconductivity in interface superconductors Jonathan Edge edge@kth.se * Multiband superconductivity * STO and LAO/STO * Probes for multiband SC * Multiband signature in H c2 * Results for Hc2 in STO and LAO/STO JME & A.Balatsky arXiv:1401.5318 Multiband superconductivity in interface superconductors Jonathan Edge edge@kth.se * Multiband superconductivity * STO and LAO/STO * Probes for multiband SC * Multiband signature in H c2 * Results for Hc2 in STO and LAO/STO Ordinary single

  16. ZIRCONIA-BASED MIXED POTENTIAL CARBON MONOXIDE/HYDROCARBON SENSORS WITH LANTHANUM MAGNESIUM OXIDE, AND TERBIUM-DOPED YTTRIUM STABILIZED ZIRCONIA ELECTRODES

    SciTech Connect (OSTI)

    E. L. BROSHA; R. MUKUNDAN; ET AL

    2000-10-01

    We have investigated the performance of dual metal oxide electrode mixed potential sensors in an engine-out, dynamometer environment. Sensors were fabricated by sputtering thin films of LaMnO{sub 3} and Tb-doped YSZ onto YSZ electrolyte. Au gauze held onto the metal oxide thin films with Au ink was used for current collection. The exhaust gas from a 4.8L, V8 engine operated in open loop, steady-state mode around stoichiometry at 1500 RPM and 50 Nm. The sensor showed a stable EMF response (with no hysteresis) to varying concentrations of total exhaust gas HC content. The sensor response was measured at 620 and 670 C and shows temperature behavior characteristic of mixed potential-type sensors. The results of these engine-dynamometer tests are encouraging; however, the limitations associated with Au current collection present the biggest impediment to automotive use.

  17. Hydrocarbon Inhibition and HC Storage Modeling in Fe-Zeolite...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Inhibition and HC Storage Modeling in Fe-Zeolite Catalysts for HD Diesel Engines Hydrocarbon Inhibition and HC Storage Modeling in Fe-Zeolite Catalysts for HD Diesel Engines ...

  18. Administrative Management Staff (HC-1.5) | Department of Energy

    Energy Savers [EERE]

    Chief Human Capital Officer (HC-1) Administrative Management Staff (HC-1.5) ... for the day-to-day operations of the Office of the Chief Human Capital Officer. ...

  19. TableHC8.1.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    HC8.1 Housing Unit Characteristics by Urban/Rural Location, 2005 Total......................................................................... 111.1 47.1 19.0 22.7 22.3 Census Region and Division Northeast.............................................................. 20.6 6.9 6.0 4.4 3.2 New England..................................................... 5.5 2.2 1.9 0.5 0.9 Middle Atlantic................................................... 15.1 4.7 4.2 4.0 2.3

  20. Sulfur tolerant molten carbonate fuel cell anode and process

    DOE Patents [OSTI]

    Remick, Robert J.

    1990-01-01

    Molten carbonate fuel cell anodes incorporating a sulfur tolerant carbon monoxide to hydrogen water-gas-shift catalyst provide in situ conversion of carbon monoxide to hydrogen for improved fuel cell operation using fuel gas mixtures of over about 10 volume percent carbon monoxide and up to about 10 ppm hydrogen sulfide.

  1. The Impact of PM and HC on EGR Cooler Fouling

    Broader source: Energy.gov [DOE]

    Data were used to correlate an EGR cooling fouling model developed to test the impact of PM and HC on fouling

  2. Office of Human Resource Services (HC-30) | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    This organization provides a full range of human capital management (HCM) operational ... Leadership Rita M. Clinton Director, Office of Human Resource Services Read Bio HC-30 ...

  3. HQ Operations Division (HC-32) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Operations Division (HC-32) HQ Operations Division (HC-32) Functions Deliver employment operational and advisory services, including position management, recruitment, staffing and classification, reduction in force in Headquarters; Provide operational and advisory support for competitive sourcing initiatives and impacted serviced population; Provide information to HQ employee population on employee benefit programs (retirement; health, dental, vision, long-term care, and life insurance; thrift

  4. HC-21C off-gas test report

    SciTech Connect (OSTI)

    Cunningham, L.T.

    1995-09-12

    Test procedure WHC-SD-CP-TC-032, HC-21C Off-Gas Test Procedure, was performed to determine the cause and establish a method of the elimination of liquid formation in the HC-21C Furnace off-gas system. This report discusses the findings of the test procedure and the changes implemented.

  5. Distribution of CCS and HC{sub 3}N in L1147, an early phase dark cloud

    SciTech Connect (OSTI)

    Suzuki, Taiki; Ohishi, Masatoshi; Hirota, Tomoya

    2014-06-20

    We used the Nobeyama 45 m radio telescope to reveal spatial distributions of CCS and HC{sub 3}N in L1147, one of the carbon-chain producing region (CCPR) candidates, where carbon-chain molecules are dominant rather than NH{sub 3}. We found that three cores (two CCS cores and one HC{sub 3}N core), which are away from a very low luminosity object (a source that may turn into a sub-stellar mass brown dwarf), exist along the NE-SW filament traced by the 850 ?m dust continuum. The column densities of CCS are 3-7 10{sup 12} cm{sup 2} and those of HC{sub 3}N are 2-6 10{sup 12} cm{sup 2}, respectively, much lower than those previously reported toward other CCPRs. We also found that two CCS peaks are displaced from the peaks of HC{sub 3}N. In order to interpret such interleaved distributions, we conducted chemical reaction network simulations and found that slightly different gas densities could lead to large variation of the CCS-to-HC{sub 3}N ratio in the early phase of dark cloud evolution. Such a chemical 'variation' may be seen in other CCPRs. Finally, we were able to confirm that the L1147 filament can be regarded as a CCPR.

  6. HC Policy and Services - Points of Contact | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    HC Policy and Services - Points of Contact HC Policy and Services - Points of Contact Learning and Development Contact Email Phone Executive Learning Rosenmarkle, David P david.rosenmarkle@hq.doe.gov 202-586-7978 Technical and Professional Skills Dent, Cheri D cheri.dent@hq.doe.gov 202-586-9556 Supervisory Training Robinson, June V june.robinson@hq.doe.gov 202-586-9557 Competency Development Coleman, Eric eric.coleman@hq.doe.gov 202-586-8466 Organizational Development Coleman, Eric

  7. Engine-External HC-Dosing for Regeneration of Diesel Particulate...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine-External HC-Dosing for Regeneration of Diesel Particulate Filters for Heavy Duty and NRMM According to Annex XXVII StVZO Engine-External HC-Dosing for Regeneration of Diesel ...

  8. Ag-Al2O3 Catalyst HC-SCR: Performance with Light Alcohols and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ag-Al2O3 Catalyst HC-SCR: Performance with Light Alcohols and Other Reductants Ag-Al2O3 Catalyst HC-SCR: Performance with Light Alcohols and Other Reductants 2004 Diesel Engine ...

  9. Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction Engine and Reactor Evaluations of HC-SCR for Diesel NOx Reduction Focus is the heavy duty, US dynamometer ...

  10. Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate

    DOE Patents [OSTI]

    Liu, David K.; Chang, Shih-Ger

    1989-01-01

    A method of removing nitrogen monoxide from a nitrogen monoxide-containing gas, which method comprises: (a) contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate of the formula: ##STR1## wherein the water-soluble organic compound is selected from compounds of the formula: ##STR2## wherein: R is selected from hydrogen or an organic moiety having at least one polar functional group; Z is selected from oxygen, sulfur, or --N--A wherein N is nitrogen and A is hydrogen or lower alkyl having from one to four carbon atoms; and M is selected from hydrogen, sodium or potassium; and n is 1 or 2, in a contacting zone for a time and at a temperature effective to reduce the nitrogen monoxide. These mixtures are useful to provide an unexpensive method of removing NO from gases, thus reducing atmospheric pollution from flue gases.

  11. Engineering study on conveyor system for HC-21C project

    SciTech Connect (OSTI)

    De Vries, M.L.

    1995-02-02

    The sludge stabilization process thermally stabilizes reactive plutonium bearing materials in a muffle furnace. This process is used to prepare the material for long term storage in the vaults. The process is conducted in Room 230A and 230B. The furnaces are located in glovebox HC-21C. Glovebox HC-21A is used for preparation of the charge and packaging of the high fired oxide. The feed for the process is located throughout the PRF and RMC-line gloveboxes, with over half of the feedstock currently being located in HA-23S. For readiness assessment, the sludge stabilization process at PFP was reviewed by the ALARA team to see how the process could be improved. One suggestion was made that the conveyor system be used to transfer items from HA-23S to the process glovebox (HA-21A) instead of sealing items in and out of the gloveboxes. The following discussion describes and compares past and current methods. In addition, actions are addressed that would need to be completed before the conveyor method could be used. The transportation of the feedstock to the process and all the different influencing factors will be examined to determine the best method. This assessment is being performed considering only the current campaign for HC-21C. However, there is a possibility that in the future, additional furnaces will be installed and further campaigns done.

  12. Pre-Combustion Carbon Capture Research | Department of Energy

    Energy Savers [EERE]

    This synthesis gas, or syngas, is a mixture of hydrogen, carbon monoxide, CO2, and smaller ... closely with the gasification and hydrogen turbine programs to ensure that ...

  13. Hydrocarbon Inhibition and HC Storage Modeling in Fe-Zeolite Catalysts for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    HD Diesel Engines | Department of Energy Inhibition and HC Storage Modeling in Fe-Zeolite Catalysts for HD Diesel Engines Hydrocarbon Inhibition and HC Storage Modeling in Fe-Zeolite Catalysts for HD Diesel Engines Investigating the dynamics between various aftertreatment devices for overall optimal performance to simultaneously reduce NOx and PM. Ex: HC poisoning/inhibition on zeolites1, catalyst aging, etc. deer09_devarakonda.pdf (1.73 MB) More Documents & Publications The Effects of

  14. Microsoft PowerPoint - 10-20-13 HC_Org_Chart

    Energy Savers [EERE]

    HUMAN CAPITAL OFFICER CHIEF HUMAN CAPITAL OFFICER (CHCO) DEPUTY CHIEF HUMAN CAPITAL OFFICER DIRECTOR, HUMAN CAPITAL MANAGEMENT ADMINISTRATIVE MANAGEMENT STAFF (HC-1.5) SENIOR ...

  15. Project and Survey Staff (HC-50.1) | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    The Project and Survey Staff (HC-50.1) report to the Office of Human Capital Strategy, ... the Department to define and design Human Capital Management (HCM) implementation ...

  16. Addendum 2 to CSER 94-007 and CSER 94-008 Title: Burning one whole Pu button in muffle furnace in the HC-21C hood

    SciTech Connect (OSTI)

    Chiao, T., Westinghouse Hanford

    1996-09-24

    This addendum reviews the current CPS` and their supporting CSERs for HC-21A and HC-21C Hoods and provides the criticality safety analysis for burning a whole Pu button in HC-21C.

  17. H.C.; Reynolds, G.D.; Steinfort, T.D. 47 OTHER INSTRUMENTATION...

    Office of Scientific and Technical Information (OSTI)

    Triaxial thermopile array geo-heat-flow sensor Carrigan, C.R.; Hardee, H.C.; Reynolds, G.D.; Steinfort, T.D. 47 OTHER INSTRUMENTATION; 15 GEOTHERMAL ENERGY; HEAT FLOW; MONITORING;...

  18. HQ Employee/Labor Management Relations Division (HC-33) | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Employee/Labor Management Relations Division (HC-33) HQ Employee/Labor Management Relations Division (HC-33) Functions Provide labor/employee management relations advisory services to Headquarters staff, including union negotiations, adverse actions, grievances, and performance management; Represent management in third party situations or union negotiations; Provide work life information, referral and support services to Headquarters employees covering such areas as child care, elder

  19. Office of Learning and Workforce Development (HC-20) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Learning and Workforce Development (HC-20) Office of Learning and Workforce Development (HC-20) The mission of the Office of Learning and Workforce Development is to strengthen DOE's workforce capacity and build a culture of continual learning and knowledge sharing. To accomplish its mission, the Office of Learning and Workforce Development has developed the following goals: Grow our Leaders- Ensure leadership continuity and instill leadership skills to support the mission and support human

  20. (HC){sub 3} process - An economical technology for upgrading bitumen and heavy oil

    SciTech Connect (OSTI)

    Padamsey, R.; Bailey, R.T.; Cyr, T.J.

    1995-12-31

    This paper discusses the development of the (HC){sub 3} Process. (HC){sub 3} is a high conversion hydro-cracking process with integrated hydro-treating that has been developed by Alberta Department of Energy, Oil Sands and Research Division. The (HC){sub 3} Process has been developed and demonstrated to achieve conversion in excess of 95% at moderate pressures and relatively high temperature in a very cost effective manner. This has been achieved with the aid of a colloidal catalyst that selectively converts the asphaltenes, and a proprietary recycle methodology that significantly reduces the catalyst consumption. Cost and economic studies indicate that capital and operating costs of the (HC){sub 3} upgrading scheme are lower than those of other high conversion schemes and are comparable to those of low and moderate conversion upgrading schemes. This cost advantage combined with the high yield gives the (HC){sub 3} a significant economic advantage over other upgrading schemes. The (HC){sub 3} process shows great promise at achieving high conversion efficiently and economically. The process is ready for commercial testing. Discussions are underway with regards to testing the process in a commercial facility designed to process nominally 5000 barrels per day (BPD).

  1. Composite catalyst for carbon monoxide and hydrocarbon oxidation...

    Office of Scientific and Technical Information (OSTI)

    The atomic ratio of transition metal to fluorite oxide is less than one. Inventors: Liu, Wei 1 ; Flytzani-Stephanopoulos, Maria 2 + Show Author Affiliations (Cambridge, MA) ...

  2. Kinetics of the carbon monoxide oxidation reaction under microwave heating

    SciTech Connect (OSTI)

    Perry, W.L.; Katz, J.D.; Rees, D.; Paffett, M.T. [Los Alamos National Lab., NM (United States); Datye, A. [Univ. of New Mexico, Albuquerque, NM (United States)

    1996-06-01

    915 MHz microwave heating has been used to drive the CO oxidation reaction over Pd/Al{sub 2}O{sub 3} with out significantly affecting the reaction kinetics. As compared to an identical conventionally heated system, the activation energy, pre-exponential factor, and reaction order with respect to CO were unchanged. Temperature was measured using a thermocouple extrapolation technique. Microwave-induced thermal gradients were found to play a significant role in kinetic observations. The authors chose the CO oxidation reaction over a supported metal catalyst because the reaction kinetics are well known, and because of the diverse dielectric properties of the various elements in the system: CO is a polar molecule, O{sub 2} and CO{sub 2} are non-polar, Al{sub 2}O{sub 3} is a dielectric, and Pt and Pd are conductors.

  3. Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ratio Particulate Produced from Advanced Combustion Operation in a Compression Ignition Engine Performance Characteristics of Coal-to-Liquids (CTL) Diesel in a 50-State ...

  4. Heterologous production of an energy-conserving carbon monoxide...

    Office of Scientific and Technical Information (OSTI)

    ... GrantContract Number: SC0012518 Type: Accepted Manuscript Journal Name: Frontiers in Microbiology Additional Journal Information: Journal Volume: 7; Journal ID: ISSN 1664-302X ...

  5. Heterologous production of an energy-conserving carbon monoxide...

    Office of Scientific and Technical Information (OSTI)

    GrantContract Number: SC0012518 Type: Accepted Manuscript Journal Name: Frontiers in Microbiology Additional Journal Information: Journal Volume: 7; Journal ID: ISSN 1664-302X ...

  6. Advanced Diesel Combustion with Low Hydrocarbon and Carbon Monoxide Emissions

    Broader source: Energy.gov [DOE]

    Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010.

  7. Control of carbon balance in a silicon smelting furnace

    DOE Patents [OSTI]

    Dosaj, V.D.; Haines, C.M.; May, J.B.; Oleson, J.D.

    1992-12-29

    The present invention is a process for the carbothermic reduction of silicon dioxide to form elemental silicon. Carbon balance of the process is assessed by measuring the amount of carbon monoxide evolved in offgas exiting the furnace. A ratio of the amount of carbon monoxide evolved and the amount of silicon dioxide added to the furnace is determined. Based on this ratio, the carbon balance of the furnace can be determined and carbon feed can be adjusted to maintain the furnace in carbon balance.

  8. Method for producing carbon nanotubes

    DOE Patents [OSTI]

    Phillips, Jonathan; Perry, William L.; Chen, Chun-Ku

    2006-02-14

    Method for producing carbon nanotubes. Carbon nanotubes were prepared using a low power, atmospheric pressure, microwave-generated plasma torch system. After generating carbon monoxide microwave plasma, a flow of carbon monoxide was directed first through a bed of metal particles/glass beads and then along the outer surface of a ceramic tube located in the plasma. As a flow of argon was introduced into the plasma through the ceramic tube, ropes of entangled carbon nanotubes, attached to the surface of the tube, were produced. Of these, longer ropes formed on the surface portion of the tube located in the center of the plasma. Transmission electron micrographs of individual nanotubes revealed that many were single-walled.

  9. Simulation of spray drying absorber for removal of HC1 in flue gas from incinerators

    SciTech Connect (OSTI)

    Uchida, S.; Tsuchiga, K.

    1984-04-01

    A theoretical study on the spray drying absorber in an HC1 removal process by lime slurries has been performed with a mathematical model which describes heat and mass transfer and fluid flows in the absorber. From heat and mass balances and a force balance for a moving droplet in the absorber, a set of first-order, nonlinear differential equations relating the amount of water, the gas and droplet temperatures, the drop velocity, the HC1 partial pressure, etc., along the axial direction of the tower was formulated. These relationships were numerically solved to give characteristic profiles in the tower. The results of the simulation based on this model were compared with experimental data and showed satisfactory agreement.

  10. Assembly of large metagenome data sets using a Convey HC-1 hybrid core computer (7th Annual SFAF Meeting, 2012)

    ScienceCinema (OSTI)

    Copeland, Alex [DOE JGI

    2013-02-11

    Alex Copeland on "Assembly of large metagenome data sets using a Convey HC-1 hybrid core computer" at the 2012 Sequencing, Finishing, Analysis in the Future Meeting held June 5-7, 2012 in Santa Fe, New Mexico.

  11. Table HC6.9 Home Appliances Characteristics by Number of Household Members, 2005

    U.S. Energy Information Administration (EIA) Indexed Site

    HC6.9 Home Appliances Characteristics by Number of Household Members, 2005 Total U.S.............................................................. 111.1 30.0 34.8 18.4 15.9 12.0 Cooking Appliances Conventional Ovens Use an Oven.................................................. 109.6 29.5 34.4 18.2 15.7 11.8 1................................................................. 103.3 28.4 32.0 17.3 14.7 11.0 2 or More.................................................... 6.2 1.1 2.5 1.0 0.9 0.8 Do Not

  12. Thermochemical cyclic system for splitting water and/or carbon dioxide by means of cerium compounds and reactions useful therein

    DOE Patents [OSTI]

    Bamberger, C.E.; Robinson, P.R.

    A thermochemical cyclic process for producing hydrogen from water comprises reacting ceric oxide with monobasic or dibasic alkali metal phosphate to yield a solid reaction product, oxygen and water. The solid reaction product, alkali metal carbonate or bicarbonate, and water, are reacted to yield hydrogen, ceric oxide, carbon dioxide and trialkali metal phosphate. Ceric oxide is recycled. Trialkali metal phosphate, carbon dioxide and water are reacted to yield monobasic or dibasic alkali metal phosphate and alkali metal bicarbonate, which are recycled. The cyclic process can be modified for producing carbon monoxide from carbon dioxide by reacting the alkali metal cerous phosphate and alkali metal carbonate or bicarbonate in the absence of water to produce carbon monoxide, ceric oxide, carbon dioxide and trialkali metal phosphate. Carbon monoxide can be converted to hydrogen by the water gas shift reaction.

  13. Thermochemical cyclic system for splitting water and/or carbon dioxide by means of cerium compounds and reactions useful therein

    DOE Patents [OSTI]

    Bamberger, Carlos E.; Robinson, Paul R.

    1980-01-01

    A thermochemical cyclic process for producing hydrogen from water comprises reacting ceric oxide with monobasic or dibasic alkali metal phosphate to yield a solid reaction product, oxygen and water. The solid reaction product, alkali metal carbonate or bicarbonate, and water, are reacted to yield hydrogen, ceric oxide, carbon dioxide and trialkali metal phosphate. Ceric oxide is recycled. Trialkali metal phosphate, carbon dioxide and water are reacted to yield monobasic or dibasic alkali metal phosphate and alkali metal bicarbonate, which are recycled. The cylic process can be modified for producing carbon monoxide from carbon dioxide by reacting the alkali metal cerous phosphate and alkali metal carbonate or bicarbonate in the absence of water to produce carbon monoxide, ceric oxide, carbon dioxide and trialkali metal phosphate. Carbon monoxide can be converted to hydrogen by the water gas shift reaction.

  14. Generation and Solid Oxide Fuel Cell Carbon Sequestration in Northwest Indiana

    SciTech Connect (OSTI)

    Kevin Peavey; Norm Bessette

    2007-09-30

    The objective of the project is to develop the technology capable of capturing all carbon monoxide and carbon dioxide from natural gas fueled Solid Oxide Fuel Cell (SOFC) system. In addition, the technology to electrochemically oxidize any remaining carbon monoxide to carbon dioxide will be developed. Success of this R&D program would allow for the generation of electrical power and thermal power from a fossil fuel driven SOFC system without the carbon emissions resulting from any other fossil fueled power generationg system.

  15. Cobalt carbonyl catalyzed olefin hydroformylation in supercritical carbon dioxide

    DOE Patents [OSTI]

    Rathke, Jerome W. (Lockport, IL); Klingler, Robert J. (Westmount, IL)

    1993-01-01

    A method of olefin hydroformylation is provided wherein an olefin reacts with a carbonyl catalyst and with reaction gases such as hydrogen and carbon monoxide in the presence of a supercritical reaction solvent, such as carbon dioxide. The invention provides higher yields of n-isomer product without the gas-liquid mixing rate limitation seen in conventional Oxo processes using liquid media.

  16. Cobalt carbonyl catalyzed olefin hydroformylation in supercritical carbon dioxide

    DOE Patents [OSTI]

    Rathke, J.W.; Klingler, R.J.

    1993-03-30

    A method of olefin hydroformylation is provided wherein an olefin reacts with a carbonyl catalyst and with reaction gases such as hydrogen and carbon monoxide in the presence of a supercritical reaction solvent, such as carbon dioxide. The invention provides higher yields of n-isomer product without the gas-liquid mixing rate limitation seen in conventional Oxo processes using liquid media.

  17. file://C:\Documents%20and%20Settings\VM3\My%20Documents\hc6-1a_

    U.S. Energy Information Administration (EIA) Indexed Site

    Table HC6-1a. Usage Indicators by Climate Zone, Million U.S. Households, 2001 ________________________________________________________________________________________________________ | | | | | Climate Zone 1 | | |_________________________________________________| | | | | | | Fewer than 2,000 CDD and -- | | | |_______________________________________|2,000 CDD| | | | | | | or More | | | | | | Fewer |and Fewer| | |More than| 5,500 to| 4,000 to| than | than | Usage Indicators | Total |7,000

  18. Carbon dioxide capture process with regenerable sorbents

    DOE Patents [OSTI]

    Pennline, Henry W.; Hoffman, James S.

    2002-05-14

    A process to remove carbon dioxide from a gas stream using a cross-flow, or a moving-bed reactor. In the reactor the gas contacts an active material that is an alkali-metal compound, such as an alkali-metal carbonate, alkali-metal oxide, or alkali-metal hydroxide; or in the alternative, an alkaline-earth metal compound, such as an alkaline-earth metal carbonate, alkaline-earth metal oxide, or alkaline-earth metal hydroxide. The active material can be used by itself or supported on a substrate of carbon, alumina, silica, titania or aluminosilicate. When the active material is an alkali-metal compound, the carbon-dioxide reacts with the metal compound to generate bicarbonate. When the active material is an alkaline-earth metal, the carbon dioxide reacts with the metal compound to generate carbonate. Spent sorbent containing the bicarbonate or carbonate is moved to a second reactor where it is heated or treated with a reducing agent such as, natural gas, methane, carbon monoxide hydrogen, or a synthesis gas comprising of a combination of carbon monoxide and hydrogen. The heat or reducing agent releases carbon dioxide gas and regenerates the active material for use as the sorbent material in the first reactor. New sorbent may be added to the regenerated sorbent prior to subsequent passes in the carbon dioxide removal reactor.

  19. The electric dipole moment of cobalt monoxide, CoO

    SciTech Connect (OSTI)

    Zhuang, Xiujuan; Steimle, Timothy C.

    2014-03-28

    A number of low-rotational lines of the E{sup 4}?{sub 7/2}???X{sup 4}?{sub 7/2} (1,0) band system of cobalt monoxide, CoO, were recorded field free and in the presence of a static electric field. The magnetic hyperfine parameter, h{sub 7/2}, and the electron quadrupole parameter, eQq{sub 0}, for the E{sup 4}?{sub 7/2}(? = 1) state were optimized from the analysis of the field-free spectrum. The permanent electric dipole moment, ?{sup -vector}{sub el}, for the X{sup 4}?{sub 7/2} (? = 0) and E{sup 4}?{sub 7/2} (? = 1) states were determined to be 4.18 0.05 D and 3.28 0.05 D, respectively, from the analysis of the observed Stark spectra of F? = 7???F? = 6 branch feature in the Q(7/2) line and the F? = 8???F? = 7 branch feature in the R(7/2) line. The measured dipole moments of CoO are compared to those from theoretical predictions and the trend across the 3d-metal monoxide series discussed.

  20. Method of removing nitrogen monoxide from a nitrogen monoxide-containing gas using a water-soluble iron ion-dithiocarbamate, xanthate or thioxanthate

    DOE Patents [OSTI]

    Liu, D. Kwok-Keung; Chang, Shih-Ger

    1987-08-25

    The present invention relates to a method of removing of nitrogen monoxide from a nitrogen monoxide-containing gas which method comprises contacting a nitrogen oxide-containing gas with an aqueous solution of water soluble organic compound-iron ion chelate complex. The NO absorption efficiency of ferrous urea-dithiocarbamate and ferrous diethanolamine-xanthate as a function of time, oxygen content and solution ph is presented. 3 figs., 1 tab.

  1. "Table HC3.9 Home Appliances Characteristics by Owner-Occupied Housing Unit, 2005"

    U.S. Energy Information Administration (EIA) Indexed Site

    HC3.9 Home Appliances Characteristics by Owner-Occupied Housing Unit, 2005" " Million U.S. Housing Units" ,," Owner-Occupied Housing Units (millions)","Type of Owner-Occupied Housing Unit" ,"U.S. Housing Units (millions" ,,,"Single-Family Units",,"Apartments in Buildings With--" "Home Appliances Characteristics",,,"Detached","Attached","2 to 4 Units","5 or More Units","Mobile

  2. "Table HC4.9 Home Appliances Characteristics by Renter-Occupied Housing Unit, 2005"

    U.S. Energy Information Administration (EIA) Indexed Site

    HC4.9 Home Appliances Characteristics by Renter-Occupied Housing Unit, 2005" " Million U.S. Housing Units" ,," Renter-Occupied Housing Units (millions)","Type of Renter-Occupied Housing Unit" ,"U.S. Housing Units (millions" ,,,"Single-Family Units",,"Apartments in Buildings With--" "Home Appliances Characteristics",,,"Detached","Attached","2 to 4 Units","5 or More

  3. Monoxides of small terbium clusters: A density functional theory investigation

    SciTech Connect (OSTI)

    Zhang, G. L.; Yuan, H. K. Chen, H.; Kuang, A. L.; Li, Y.; Wang, J. Z.; Chen, J.

    2014-12-28

    To investigate the effect of oxygen atom on the geometrical structures, electronic, and magnetic properties of small terbium clusters, we carried out the first-principles calculations on Tb{sub n}O (n = 1-14) clusters. The capping of an oxygen atom on one trigonal-facet of Tb{sub n} structures is always favored energetically, which can significantly improve the structural stability. The far-infrared vibrational spectroscopies are found to be different from those of corresponding bare clusters, providing a distinct signal to detect the characteristic structures of Tb{sub n}O clusters. The primary effect of oxygen atom on magnetic properties is to change the magnetic orderings among Tb atoms and to reduce small of local magnetic moments of the O-coordinated Tb atoms, both of which serve as the key reasons for the experimental magnetic evolution of an oscillating behavior. These calculations are consistent with, and help to account for, the experimentally observed magnetic properties of monoxide Tb{sub n}O clusters [C. N. Van Dijk et al., J. Appl. Phys. 107, 09B526 (2010)].

  4. Carbonyl sulfide/carbon chemistry: Interim report, July 1, 1985-February 28, 1986

    SciTech Connect (OSTI)

    Hinckley, C.C.; Shiley, R.H.

    1986-05-01

    This interim report describes work performed during the first eight months of a continuing project, including descriptions of sample preparations and analyses. The objective of the study is to determine the effects of carbonyl sulfide, a product of the carbon monoxide/ethanol desulfurization process, on coal. A coal is first treated with carbon monoxide to reduce pyrite, and is then reacted with OCS and N/sub 2/ under various conditions. OCS is a potent resulfurization agent and appears to affect the formation of mesophase in chars derived from the coal. 8 refs., 1 fig., 8 tabs.

  5. Influence of solid fuel on the carbon-monoxide and nitrogen-oxide emissions on sintering

    SciTech Connect (OSTI)

    M.F. Vitushchenko; N.L. Tatarkin; A.I. Kuznetsov; A.E. Vilkov

    2007-07-01

    Laboratory and industrial research now underway at the sintering plant of AO Mittal Steel Temirtau is focusing on the preparation of fuel of optimal granulometric composition, the replacement of coke fines, and the adaptation of fuel-input technology so as to reduce fuel consumption and toxic emissions without loss of sinter quality.

  6. Peculiarities of high-overtone transition probabilities in carbon monoxide revealed by high-precision calculation

    SciTech Connect (OSTI)

    Medvedev, Emile S.; Meshkov, Vladimir V.; Stolyarov, Andrey V.

    2015-10-21

    In the recent work devoted to the calculation of the rovibrational line list of the CO molecule [G. Li et al., Astrophys. J., Suppl. Ser. 216, 15 (2015)], rigorous validation of the calculated parameters including intensities was carried out. In particular, the Normal Intensity Distribution Law (NIDL) [E. S. Medvedev, J. Chem. Phys. 137, 174307 (2012)] was employed for the validation purposes, and it was found that, in the original CO line list calculated for large changes of the vibrational quantum number up to Δn = 41, intensities with Δn > 11 were unphysical. Therefore, very high overtone transitions were removed from the published list in Li et al. Here, we show how this type of validation is carried out and prove that the quadruple precision is indispensably required to predict the reliable intensities using the conventional 32-bit computers. Based on these calculations, the NIDL is shown to hold up for the 0 → n transitions till the dissociation limit around n = 83, covering 45 orders of magnitude in the intensity. The low-intensity 0 → n transition predicted in the work of Medvedev [Determination of a new molecular constant for diatomic systems. Normal intensity distribution law for overtone spectra of diatomic and polyatomic molecules and anomalies in overtone absorption spectra of diatomic molecules, Institute of Chemical Physics, Russian Academy of Sciences, Chernogolovka, 1984] at n = 5 is confirmed, and two additional “abnormal” intensities are found at n = 14 and 23. Criteria for the appearance of such “anomalies” are formulated. The results could be useful to revise the high-overtone molecular transition probabilities provided in spectroscopic databases.

  7. Technology development for iron Fischer-Tropsch catalysis. [Pretreatment of catalyst in carbon monoxide

    SciTech Connect (OSTI)

    Not Available

    1991-01-01

    The present study shows that activation of a high surface area Fe{sub 2}O{sub 3} catalyst in CO in a (CSTR), continuously stirred tank reactor using tetralin as solvent results in an activated that is three times of material that is activated in H{sub 2} or directly in the syngas.

  8. REFORMULATION OF COAL-DERIVED TRANSPORTATION FUELS: SELECTIVE OXIDATION OF CARBON MONOXIDE ON METAL FOAM CATALYSTS

    SciTech Connect (OSTI)

    Paul Chin; Xiaolei Sun; George W. Roberts; Amornmart Sirijarhuphan; Sourabh Pansare; James G. Goodwin Jr; Richard W. Rice; James J. Spivey

    2005-06-01

    Hydrocarbon fuels must be reformed in a series of steps to provide hydrogen for use in proton exchange membrane fuel cells (PEMFCs). Preferential oxidation (PROX) is one method to reduce the CO concentration to less than 10 ppm in the presence of {approx}40% H{sub 2}, CO{sub 2}, and steam. This will prevent CO poisoning of the PEMFC anode. Structured supports, such as ceramic monoliths, can be used for the PROX reaction. Alternatively, metal foams offer a number of advantages over the traditional ceramic monolith.

  9. REFORMULATION OF COAL-DERIVED TRANSPORTATION FUELS: SELECTIVE OXIDATION OF CARBON MONOXIDE ON METAL FOAM CATALYSTS

    SciTech Connect (OSTI)

    Paul Chin; George W. Roberts; James J. Spivey

    2003-12-31

    Uses for structured catalytic supports, such as ceramic straight-channel monoliths and ceramic foams, have been established for a long time. One of the most prominent examples is the washcoated ceramic monolith as a three-way catalytic converter for gasoline-powered automobiles. A distinct alternative to the ceramic monolith is the metal foam, with potential use in fuel cell-powered automobiles. The metal foams are characterized by their pores per inch (ppi) and density ({rho}). In previous research, using 5 wt% platinum (Pt) and 0.5 wt% iron (Fe) catalysts, washcoated metal foams, 5.08 cm in length and 2.54 cm in diameter, of both varying and similar ppi and {rho} were tested for their activity (X{sub CO}) and selectivity (S{sub CO}) on a CO preferential oxidation (PROX) reaction in the presence of a H{sub 2}-rich gas stream. The variances in these metal foams' activity and selectivity were much larger than expected. Other structured supports with 5 wt% Pt, 0-1 wt% Fe weight loading were also examined. A theory for this phenomenon states that even though these structured supports have a similar nominal catalyst weight loading, only a certain percentage of the Pt/Fe catalyst is exposed on the surface as an active site for CO adsorption. We will use two techniques, pulse chemisorption and temperature programmed desorption (TPD), to characterize our structured supports. Active metal count, metal dispersion, and other calculations will help clarify the causes for the activity and selectivity variations between the supports. Results on ceramic monoliths show that a higher Fe loading yields a lower dispersion, potentially because of Fe inhibition of the Pt surface for CO adsorption. This theory is used to explain the reason for activity and selectivity differences for varying ppi and {rho} metal foams; less active and selective metal foams have a lower Fe loading, which justifies their higher metal dispersion. Data on the CO desorption temperature and average metal crystallite size for TPD are also collected.

  10. Quantum yield for carbon monoxide production in the 248 nm photodissociation of carbonyl sulfide (OCS)

    SciTech Connect (OSTI)

    Zhao, Z.; Stickel, R.E.; Wine, P.H. [Georgia Institute of Technology, Atlanta, GA (United States)] [Georgia Institute of Technology, Atlanta, GA (United States)

    1995-03-01

    Tunable diode laser absorption spectroscopy has been coupled with excimer laser flash photolysis to measure the quantum yield for CO production from 248 nm photodissociation of carbonyl sulfide (OCS) relative to the well known quantum yield for CO production from 248 nm photolysis of phosgene (Cl{sub 2}CO). The temporal resolution of the experiments was sufficient to distinguish CO formed directly by photodissociation from that formed by subsequent S({sup 3}P{sub j}) reaction with OCS. Under the experimental conditions employed, CO formation via the fast S({sup 1}D{sub 2})+OCS reaction was minimal. Measurements at 297K and total pressures from 4 to 100 Torr N{sub 2}+N{sub 2}O show the CO yield to be greater than 0.95 and most likely unity. This result suggests that the contribution of OCS as a precursor to the lower stratospheric sulfate aerosol layer is somewhat larger than previously thought. 25 refs., 1 fig., 2 tabs.

  11. Effect of Sodium Sulfide on Ni-Containing Carbon Monoxide Dehydrogenases

    SciTech Connect (OSTI)

    Jian Feng; Paul A. Lindahl

    2004-07-28

    OAK-B135 The structure of the active-site C-cluster in CO dehydrogenase from Carboxythermus hydrogenoformans includes a {mu}{sup 2}-sulfide ion bridged to the Ni and unique Fe, while the same cluster in enzymes from Rhodospirillum rubrum (CODH{sub Rr}) and Moorella thermoacetica (CODH{sub Mt}) lack this ion. This difference was investigated by exploring the effects of sodium sulfide on activity and spectral properties. Sulfide partially inhibited the CO oxidation activity of CODH{sub Rr} and generated a lag prior to steady-state. CODH{sub Mt} was inhibited similarly but without a lag. Adding sulfide to CODH{sub Mt} in the C{sub red1} state caused the g{sub av} = 1.82 EPR signal to decline and new features to appear, including one with g = 1.95, 1.85 and (1.70 or 1.62). Removing sulfide caused the g{sub av} = 1.82 signal to reappear and activity to recover. Sulfide did not affect the g{sub av} = 1.86 signal from the C{sub red2} state. A model was developed in which sulfide binds reversibly to C{sub red1}, inhibiting catalysis. Reducing this adduct causes sulfide to dissociate, C{sub red2} to develop, and activity to recover. Using this model, apparent K{sub I} values are 40 {+-} 10 nM for CODH{sub Rr} and 60 {+-} 30 {micro}M for CODH{sub Mt}. Effects of sulfide are analogous to those of other anions, including the substrate hydroxyl group, suggesting that these ions also bridge the Ni and unique Fe. This proposed arrangement raises the possibility that CO binding labilizes the bridging hydroxyl and increases its nucleophilic tendency towards attacking Ni-bound carbonyl.

  12. Methane, carbon monoxide, and ammonia in brown dwarfs and self-luminous giant planets

    SciTech Connect (OSTI)

    Zahnle, Kevin J.; Marley, Mark S. E-mail: Mark.S.Marley@NASA.gov

    2014-12-10

    We address disequilibrium abundances of some simple molecules in the atmospheres of solar composition brown dwarfs and self-luminous extrasolar giant planets using a kinetics-based one-dimensional atmospheric chemistry model. Our approach is to use the full kinetics model to survey the parameter space with effective temperatures between 500 K and 1100 K. In all of these worlds, equilibrium chemistry favors CH{sub 4} over CO in the parts of the atmosphere that can be seen from Earth, but in most disequilibrium favors CO. The small surface gravity of a planet strongly discriminates against CH{sub 4} when compared to an otherwise comparable brown dwarf. If vertical mixing is like Jupiter's, the transition from methane to CO occurs at 500 K in a planet. Sluggish vertical mixing can raise this to 600 K, but clouds or more vigorous vertical mixing could lower this to 400 K. The comparable thresholds in brown dwarfs are 1100 100 K. Ammonia is also sensitive to gravity, but, unlike CH{sub 4}/CO, the NH{sub 3}/N{sub 2} ratio is insensitive to mixing, which makes NH{sub 3} a potential proxy for gravity. HCN may become interesting in high-gravity brown dwarfs with very strong vertical mixing. Detailed analysis of the CO-CH{sub 4} reaction network reveals that the bottleneck to CO hydrogenation goes through methanol, in partial agreement with previous work. Simple, easy to use quenching relations are derived by fitting to the complete chemistry of the full ensemble of models. These relations are valid for determining CO, CH{sub 4}, NH{sub 3}, HCN, and CO{sub 2} abundances in the range of self-luminous worlds we have studied, but may not apply if atmospheres are strongly heated at high altitudes by processes not considered here (e.g., wave breaking).

  13. Carbon Monoxide Dehydrogenases and Acetyl-CoA Synthases: Light at the End of the Tunnel?

    SciTech Connect (OSTI)

    Paul A. Lindahl

    2002-02-19

    OAK-B135 Metalloenzymes seem to ''come of age'' when their structures are known at atomic resolution, spectroscopic and catalytic properties are basically understood, and genetic expression systems are available. Such foundations allow detailed mechanistic and spectroscopic properties to be probed and correlated to structure. The objective of this article is to summarize what is known about the title group of enzymes, and show that, to a large degree, they have come of age.

  14. Anisotropic Hc2 , thermodynamic and transport measurements, and pressure dependence of Tc in K2Cr3As3 single crystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kong, Tai; Bud'ko, Sergey L.; Canfield, Paul C.

    2015-01-30

    We present a detailed study of single crystalline K2Cr3As3 and analyze its thermodynamic and transport properties, anisotropic Hc2(T), and initial pressure dependence of Tc. In zero field, the temperature-dependent resistivity is metallic. Deviation from a linear temperature dependence is evident below 100 K and a T3 dependence is roughly followed from just above Tc (~10K) to ~40K. Anisotropic Hc2(T) data were measured up to 140 kOe with field applied along and perpendicular to the rodlike crystals. For the applied field perpendicular to the rod, Hc2(T) is linear with a slope ~–70 kOe/K. For field applied along the rod, the slopemore » is about –120 kOe/K below 70 kOe. Above 70 kOe, the magnitude of the slope decreases to ~–70 kOe/K. The electronic specific heat coefficient γ, just above Tc, is 73 mJ/mol K2; the Debye temperature ΘD is 220 K. As a result, the specific heat jump at the superconducting transition ΔC~2.2γTc. Finally, for hydrostatic pressures up to ~7 kbar, Tc decreases under pressure linearly at a rate of –0.034K/kbar.« less

  15. Vacancies in ordered and disordered titanium monoxide: Mechanism of B1 structure stabilization

    SciTech Connect (OSTI)

    Kostenko, M.G.; Lukoyanov, A.V.; Zhukov, V.P.; Rempel, A.A.

    2013-08-15

    The electronic structure and stability of three phases of titanium monoxide TiO{sub y} with B1 type of the basic structure have been studied. Cubic phase without structural vacancies, TiO, and two phases with structural vacancies, monoclinic Ti{sub 5}O{sub 5} and cubic disordered TiO{sub 1.0}, was treated by means of first-principles calculations within the density functional theory with pseudo-potential approach based on the plane wave's basis. The ordered monoclinic phase Ti{sub 5}O{sub 5} was found to be the most stable and the cubic TiO without vacancies the less stable one. The role of structural vacancies in the titanium sublattice is to decrease the Fermi energy, the role of vacancies in the oxygen sublattice is to contribute to the appearance of Ti–Ti bonding interactions through these vacancies and to reinforce the Ti–Ti interactions close to them. Listed effects are significantly pronounced if the vacancies in the titanium and oxygen sublattices are associated in the so called “vacancy channels” which determine the formation of vacancy ordered structure of monoclinic Ti{sub 5}O{sub 5}-type. - Graphical abstract: Changes in total DOS of titanium monoxide when going from vacancy-free TiO to TiO with disordered structural vacancies and to TiO with ordered structural vacancies. Highlights: • Ordered monoclinic Ti{sub 5}O{sub 5} is the most stable phase of titanium monoxide. • Vacancy-free TiO is the less stable phase of the titanium monoxide. • Ordering of oxygen vacancies leads to the appearance of Ti–Ti bonding interactions. • Titanium vacancies contribute significantly to the decreasing of the Fermi energy.

  16. A digital map of the high center (HC) and low center (LC) polygon boundaries delineated from high resolution LiDAR data for Barrow, Alaska

    SciTech Connect (OSTI)

    Gangodagamage, Chandana; Wullschleger, Stan

    2014-07-03

    This dataset represent a map of the high center (HC) and low center (LC) polygon boundaries delineated from high resolution LiDAR data for the arctic coastal plain at Barrow, Alaska. The polygon troughs are considered as the surface expression of the ice-wedges. The troughs are in lower elevations than the interior polygon. The trough widths were initially identified from LiDAR data, and the boundary between two polygons assumed to be located along the lowest elevations on trough widths between them.

  17. Ti{sub 5}O{sub 5} superstructures of cubic titanium monoxide

    SciTech Connect (OSTI)

    Gusev, A. I.

    2013-08-15

    A cubic model is proposed for the Ti{sub 5}O{sub 5} (Ti{sub 5} Black-Small-Square O{sub 5}{open_square} {identical_to} Ti{sub 90} Black-Small-Square {sub 18}O{sub 90}{open_square}{sub 18}) superstructure of nonstoichiometric titanium monoxide Ti{sub x}O{sub z} with double imperfection. The unit cell of the cubic Ti{sub 5}O{sub 5} superstructure has the threefold lattice parameter of the unit cell of the basis disordered B1 structure of Ti{sub x}O{sub z} monoxide and belongs to space group Pm 3-bar m . The channel of the disorder-order transition, i.e., Ti{sub x}O{sub z} (space group Fm 3-bar m)-Ti{sub 5}O{sub 5} (space group Pm 3-bar m), includes 75 superstructure vectors of seven stars (k{sub 10}), (k{sub 7}), (k{sub 6(1)}), (k{sub 6(2)}), (k{sub 4(1)}), (k{sub 4(2)}), and (k{sub 1}). The distribution functions of Ti and O atoms over the sites of the cubic Ti{sub 5}O{sub 5} superstructure are calculated. A comparison of the X-ray and electron diffraction data obtained for ordered TiO{sub 1.087} monoxide with the theoretical simulation results supports the existence of the cubic Ti{sub 5}O{sub 5} superstructure. The cubic (space group Pm 3-bar m) Ti{sub 5}O{sub 5} superstructure is shown to be a high-temperature structure relative to the well-known monoclinic (space group C2/m) superstructure of the same type.

  18. On the photoelectron velocity-map imaging of lutetium monoxide anion LuO{sup ?}

    SciTech Connect (OSTI)

    Liu, Zhiling; Xie, Hua; Qin, Zhengbo; Cong, Ran; Wu, Xia; Tang, Zichao, E-mail: zctang@dicp.ac.cn; Fan, Hongjun, E-mail: fanhj@dicp.ac.cn [State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China)] [State Key Laboratory of Molecular Reaction Dynamics, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023 (China); Li, Quanjiang [School of Physics and Optoelectronic Technology, and College of Advanced Science and Technology, Dalian University of Technology, Dalian 116024 (China)] [School of Physics and Optoelectronic Technology, and College of Advanced Science and Technology, Dalian University of Technology, Dalian 116024 (China)

    2014-01-21

    We report a combined photoelectron velocity-map imaging spectroscopy and density functional theory investigation on lutetium monoxide anion. Transition between the X {sup 1}?{sup +} anion electronic ground state and the neutral X {sup 2}?{sup +} electronic ground state is observed. Vibrationally resolved spectra were obtained at four different photon energies, providing a wealth of spectroscopic information for the electronic ground states of the anionic lutetium monoxide and corresponding neutral species. Franck-Condon simulations of the ground-state transition are performed to assign vibrational structure in the spectra and to assist in identifying the observed spectral bands. The electronic ground state of LuO{sup ?} is found to have a vibrational frequency of 743 10 cm{sup ?1} and an equilibrium bond length of 1.841 . The electron affinity of LuO is measured to be 1.624 0.002 eV. The fundamental frequency of ground-state LuO is estimated to be 839 10 cm{sup ?1}.

  19. Carbon Smackdown: Carbon Capture

    SciTech Connect (OSTI)

    Jeffrey Long

    2010-07-12

    In this July 9, 2010 Berkeley Lab summer lecture, Lab scientists Jeff Long of the Materials Sciences and Nancy Brown of the Environmental Energy Technologies Division discuss their efforts to fight climate change by capturing carbon from the flue gas of power plants, as well as directly from the air

  20. Carbon Smackdown: Carbon Capture

    ScienceCinema (OSTI)

    Jeffrey Long

    2010-09-01

    In this July 9, 2010 Berkeley Lab summer lecture, Lab scientists Jeff Long of the Materials Sciences and Nancy Brown of the Environmental Energy Technologies Division discuss their efforts to fight climate change by capturing carbon from the flue gas of power plants, as well as directly from the air

  1. Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol

    DOE Patents [OSTI]

    Steinberg, M.; Grohse, E.W.

    1995-06-27

    A process is described for the production of a pollutant-free particulate carbon (i.e., a substantially ash-, sulfur- and nitrogen-free carbon) from carbonaceous feedstocks. The basic process involves de-oxygenating one of the gas streams formed in a cyclic hydropyrolysis-methane pyrolysis process in order to improve conversion of the initial carbonaceous feedstock. De-oxygenation is effected by catalytically converting carbon monoxide, carbon dioxide, and hydrogen contained in one of the pyrolysis gas streams, preferably the latter, to a methanol co-product. There are thus produced two products whose use is known per se, viz., a substantially pollutant-free particulate carbon black and methanol. These products may be admixed in the form of a liquid slurry of carbon black in methanol. 3 figs.

  2. Process for the conversion of carbonaceous feedstocks to particulate carbon and methanol

    DOE Patents [OSTI]

    Steinberg, Meyer; Grohse, Edward W.

    1995-01-01

    A process for the production of a pollutant-free particulate carbon (i.e., a substantially ash-, sulfur- and nitrogen-free carbon) from carbonaceous feedstocks. The basic process involves de-oxygenating one of the gas streams formed in a cyclic hydropyrolysis-methane pyrolysis process in order to improve conversion of the initial carbonaceous feedstock. De-oxygenation is effected by catalytically converting carbon monoxide, carbon dioxide, and hydrogen contained in one of the pyrolysis gas streams, preferably the latter, to a methanol co-product. There are thus produced two products whose use is known per se, viz., a substantially pollutant-free particulate carbon black and methanol. These products may be admixed in the form of a liquid slurry of carbon black in methanol.

  3. Structural Changes in Self-Catalyzed Adsorption of Carbon Monoxide on 1,4-Phenylene Diisocyanide Modified Au(111)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kestell, John; Boscoboinik, J. Anibal; Cheng, Lanxia; Garvey, Michael; Bennett, Dennis W.; Tysoe, Wilfred T.

    2015-07-23

    The self-accelerated adsorption of CO on 1,4-phenylene diisocyanide (PDI)-derived oligomers on Au(111) is explored by reflection–absorption infrared spectroscopy and scanning tunneling microscopy. PDI incorporates gold adatoms from the Au(111) surface to form one-dimensional —(Au–PDI)n— chains that can also connect between gold nanoparticles on mica to form a conductive pathway between them. CO adsorption occurs in two stages; it first adsorbs adjacent to the oligomers that move to optimize CO adsorption. Further CO exposure induces PDI decoordination to form Au–PDI adatom complexes thereby causing the conductivity of a PDI-linked gold nanoparticle array on mica to decrease to act as a chemicallymore » drive molecular switch. This simple system enables the adsorption process to be explored in detail. DFT calculations reveal that both the —(Au–PDI)n— oligomer chain and the Au–PDI adatom complex are stabilized by coadsorbed CO. A kinetic “foot-in-the-door” model is proposed in which fluctuations in PDI coordination allow CO to diffuse into the gap between gold adatoms to prevent the PDI from reattaching, thereby allowing additional CO to adsorb, to provide kinetic model for allosteric CO adsorption on PDI-covered gold.« less

  4. Structural Changes in Self-Catalyzed Adsorption of Carbon Monoxide on 1,4-Phenylene Diisocyanide Modified Au(111)

    SciTech Connect (OSTI)

    Kestell, John; Boscoboinik, J. Anibal; Cheng, Lanxia; Garvey, Michael; Bennett, Dennis W.; Tysoe, Wilfred T.

    2015-07-23

    The self-accelerated adsorption of CO on 1,4-phenylene diisocyanide (PDI)-derived oligomers on Au(111) is explored by reflection–absorption infrared spectroscopy and scanning tunneling microscopy. PDI incorporates gold adatoms from the Au(111) surface to form one-dimensional —(Au–PDI)n— chains that can also connect between gold nanoparticles on mica to form a conductive pathway between them. CO adsorption occurs in two stages; it first adsorbs adjacent to the oligomers that move to optimize CO adsorption. Further CO exposure induces PDI decoordination to form Au–PDI adatom complexes thereby causing the conductivity of a PDI-linked gold nanoparticle array on mica to decrease to act as a chemically drive molecular switch. This simple system enables the adsorption process to be explored in detail. DFT calculations reveal that both the —(Au–PDI)n— oligomer chain and the Au–PDI adatom complex are stabilized by coadsorbed CO. A kinetic “foot-in-the-door” model is proposed in which fluctuations in PDI coordination allow CO to diffuse into the gap between gold adatoms to prevent the PDI from reattaching, thereby allowing additional CO to adsorb, to provide kinetic model for allosteric CO adsorption on PDI-covered gold.

  5. Effect of Organic Capping Layers over Monodisperse Platinum Nanoparticles upon Activity for Ethylene Hydrogenation and Carbon Monoxide Oxidation

    SciTech Connect (OSTI)

    Kuhn, John N.; Tsung, Chia-Kuang; Huang, Wenyu; Somorjai, Gabor A.

    2009-03-24

    The influence of oleylamine (OA), trimethyl tetradecyl ammonium bromide (TTAB), and polyvinlypyrrolidone (PVP) capping agents upon the catalytic properties of Pt/silica catalysts was evaluated. Pt nanoparticles that were 1.5 nm in size were synthesized by the same procedure (ethylene glycol reduction under basic conditions) with the various capping agents added afterward for stabilization. Before examining catalytic properties for ethylene hydrogenation and CO oxidation, the Pt NPs were deposited onto mesoporous silica (SBA-15) supports and characterized by transmission electron microscopy (TEM), H{sub 2} chemisorption, and elemental analysis (ICP-MS). PVP- and TTAB-capped Pt yielded mass-normalized reaction rates that decreased with increasing pretreatment temperature, and this trend was attributed to the partial coverage of the Pt surface with decomposition products from the organic capping agent. Once normalized to the Pt surface area, similar intrinsic activities were obtained regardless of the pretreatment temperature, which indicated no influence on the nature of the active sites. Consequently, a chemical probe technique using intrinsic activity for ethylene hydrogenation was demonstrated as an acceptable method for estimating the metallic surface areas of Pt. Amine (OA) capping exhibited a detrimental influence on the catalytic properties as severe deactivation and low activity were observed for ethylene hydrogenation and CO oxidation, respectively. These results were consistent with amine groups being strong poisons for Pt surfaces, and revealed the need to consider the effects of capping agents on the catalytic properties.

  6. Controlled synthesis of concave tetrahedral palladium nanocrystals by reducing Pd(acac){sub 2} with carbon monoxide

    SciTech Connect (OSTI)

    Zhu, Hai; Chi, Quan; Zhao, Yanxi; Li, Chunya; Tang, Heqing; Li, Jinlin; Huang, Tao; Liu, Hanfan; Institute of Chemistry, Chinese Academy of Science, Beijing 100080

    2012-11-15

    Graphical abstract: By using CO as a reducing agent, uniform and well-defined concave tetrahedral Pd nanocrystals were successfully synthesized. CO flow rate was the most essential for the formation of the concave tetrahedral nanostructures. The morphologies and sizes of the final products can be well controlled by adjusting the flow rate of CO. Highlights: ? By using CO as a reducing agent, concave tetrahedral Pd nanocrystals were obtained. ? CO flow rate is critical to the formation of concave tetrahedral Pd nanocrystals. ? The selective adsorption of CO on (1 1 0) facets is essential to concave Pd tetrahedra. -- Abstract: CO reducing strategy to control the morphologies of palladium nanocrystals was investigated. By using CO as a reducing agent, uniform and well-defined concave tetrahedral Pd nanocrystals with a mean size of about 55 2 nm were readily synthesized with Pd(acac){sub 2} as a precursor and PVP as a stabilizer. The structures of the as-prepared Pd nanocrystals were characterized by transmission electron microscopy (TEM), X-ray powder diffraction (XRD), ultravioletvisible (UVvis) absorption spectroscopy and electrochemical measurements. The results demonstrated that CO was the most essential for the formation of the concave tetrahedral Pd nanostructures. The morphologies and sizes of the final products can be well controlled by adjusting the flow rate of CO. The most appropriate CO flow rate, temperature and time for the formation of the ideal concave tetrahedral Pd nanocrystals was 0.033 mL s{sup ?1}, 100 C and 3 h, respectively.

  7. Structural Changes in Self-Catalyzed Adsorption of Carbon Monoxide on 1,4-Phenylene Diisocyanide Modified Au(111)

    SciTech Connect (OSTI)

    Kestell, John; Boscoboinik, J. Anibal; Cheng, Lanxia; Garvey, Michael; Bennett, Dennis W.; Tysoe, Wilfred T.

    2015-07-23

    The self-accelerated adsorption of CO on 1,4-phenylene diisocyanide (PDI)-derived oligomers on Au(111) is explored by reflectionabsorption infrared spectroscopy and scanning tunneling microscopy. PDI incorporates gold adatoms from the Au(111) surface to form one-dimensional (AuPDI)n chains that can also connect between gold nanoparticles on mica to form a conductive pathway between them. CO adsorption occurs in two stages; it first adsorbs adjacent to the oligomers that move to optimize CO adsorption. Further CO exposure induces PDI decoordination to form AuPDI adatom complexes thereby causing the conductivity of a PDI-linked gold nanoparticle array on mica to decrease to act as a chemically drive molecular switch. This simple system enables the adsorption process to be explored in detail. DFT calculations reveal that both the (AuPDI)n oligomer chain and the AuPDI adatom complex are stabilized by coadsorbed CO. A kinetic foot-in-the-door model is proposed in which fluctuations in PDI coordination allow CO to diffuse into the gap between gold adatoms to prevent the PDI from reattaching, thereby allowing additional CO to adsorb, to provide kinetic model for allosteric CO adsorption on PDI-covered gold.

  8. Acetaldehyde as an intermediate in the electroreduction of carbon monoxide to ethanol on oxide-derived copper

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bertheussen, Erlend; Verdaguer-Casadevall, Arnau; Ravasio, Davide; Montoya, Joseph H.; Trimarco, Daniel B.; Roy, Claudie; Meier, Sebastian; Wendland, Jürgen; Nørskov, Jens K.; Stephens, Ifan E. L.; et al

    2015-12-21

    Oxide-derived copper (OD-Cu) electrodes exhibit unprecedented CO reduction performance towards liquid fuels, producing ethanol and acetate with >50 % Faradaic efficiency at -0.3 V (vs. RHE). By using static headspace-gas chromatography for liquid phase analysis, we identify acetaldehyde as a minor product and key intermediate in the electroreduction of CO to ethanol on OD-Cu electrodes. Acetaldehyde is produced with a Faradaic efficiency of ≈5 % at -0.33 V (vs. RHE). We show that acetaldehyde forms at low steady-state concentrations, and that free acetaldehyde is difficult to detect in alkaline solutions using NMR spectroscopy, requiring alternative methods for detection and quantification.more » Our results indicate an important step towards understanding the CO reduction mechanism on OD-Cu electrodes.« less

  9. Acetaldehyde as an intermediate in the electroreduction of carbon monoxide to ethanol on oxide-derived copper

    SciTech Connect (OSTI)

    Bertheussen, Erlend; Verdaguer-Casadevall, Arnau; Ravasio, Davide; Montoya, Joseph H.; Trimarco, Daniel B.; Roy, Claudie; Meier, Sebastian; Wendland, Jürgen; Nørskov, Jens K.; Stephens, Ifan E. L.; Chorkendorff, Ib

    2015-12-21

    Oxide-derived copper (OD-Cu) electrodes exhibit unprecedented CO reduction performance towards liquid fuels, producing ethanol and acetate with >50 % Faradaic efficiency at -0.3 V (vs. RHE). By using static headspace-gas chromatography for liquid phase analysis, we identify acetaldehyde as a minor product and key intermediate in the electroreduction of CO to ethanol on OD-Cu electrodes. Acetaldehyde is produced with a Faradaic efficiency of ≈5 % at -0.33 V (vs. RHE). We show that acetaldehyde forms at low steady-state concentrations, and that free acetaldehyde is difficult to detect in alkaline solutions using NMR spectroscopy, requiring alternative methods for detection and quantification. Our results indicate an important step towards understanding the CO reduction mechanism on OD-Cu electrodes.

  10. Zirconia-based potentiometric sensor using a pair of oxide electrodes for selective detection of carbon monoxide

    SciTech Connect (OSTI)

    Miura, Norio; Raisen, Takahisa; Lu, Geyu; Yamazoe, Noboru

    1997-07-01

    A high-performance solid-state compact gas sensor to detect CO has been needed for monitoring and controlling the combustion condition of gas appliances. By using a pair of oxide electrodes, a stabilized-zirconia-based sensor was developed for selective detection of CO at high temperature. Among the oxide pair examined, the combination of CdO and SnO{sub 2} was best suited for the electrode couple, giving quick and selective response to CO in air at 600 C. The 90% response and the 90% recovery times of the sensor to 200 ppm CO was as short as ca. 8 and 10 s, respectively, at 600 C. The EMF value was linearly related with the logarithm of CO concentration in the range of 20 to 4,000 ppm. Moreover, the cross-sensitivities to other gases, such as H{sub 2}, NO, NO{sub 2}, CO{sub 2}, O{sub 2}, and H{sub 2}O, were small or insignificant.

  11. Carbon Capture

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carbon capture involves the separation of carbon dioxide (CO2) from coal-based power plant ... are not ready for implementation on coal-based power plants because they have not ...

  12. Predict carbonation rate on iron Fischer-Tropsch catalyst

    SciTech Connect (OSTI)

    Dry, M.E.

    1980-02-01

    An experimental study of the coking rate in 5 cm ID fluidized-bed reactors, in which the feed gas composition, the total pressure, and the fresh feed/recycle gas ratios were varied over wide ranges, showed a strong correlation between the carbon deposition rate and the ratio of carbon monoxide partial pressure to the square of the hydrogen partial pressure at the reactor inlet over a wide gas-composition range. At a given fresh gas composition, the combination rate varied inversely with the total pressure of the system. Coking decreased as the moles of CO + CO/sub 2/ converted to hydrocarbon increased. A Fischer-Tropsch reaction scheme is proposed and is used to derive a rate expression for catalyst carbonation that was approximately confirmed.

  13. Carbon Storage

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage Fact Sheet Research Team Members Key Contacts Carbon Storage Carbon capture and storage (CCS) is a key component of the U.S. carbon management portfolio. Numerous studies have shown that CCS can account for up to 55 percent of the emissions reductions needed to stabilize and ultimately reduce atmospheric concentrations of CO2. NETL's Carbon Storage Program is readying CCS technologies for widespread commercial deployment by 2020. The program's goals are: By 2015, develop technologies

  14. A Semi-Empirical Two Step Carbon Corrosion Reaction Model in PEM Fuel Cells

    SciTech Connect (OSTI)

    Young, Alan; Colbow, Vesna; Harvey, David; Rogers, Erin; Wessel, Silvia

    2013-01-01

    The cathode CL of a polymer electrolyte membrane fuel cell (PEMFC) was exposed to high potentials, 1.0 to 1.4 V versus a reversible hydrogen electrode (RHE), that are typically encountered during start up/shut down operation. While both platinum dissolution and carbon corrosion occurred, the carbon corrosion effects were isolated and modeled. The presented model separates the carbon corrosion process into two reaction steps; (1) oxidation of the carbon surface to carbon-oxygen groups, and (2) further corrosion of the oxidized surface to carbon dioxide/monoxide. To oxidize and corrode the cathode catalyst carbon support, the CL was subjected to an accelerated stress test cycled the potential from 0.6 VRHE to an upper potential limit (UPL) ranging from 0.9 to 1.4 VRHE at varying dwell times. The reaction rate constants and specific capacitances of carbon and platinum were fitted by evaluating the double layer capacitance (Cdl) trends. Carbon surface oxidation increased the Cdl due to increased specific capacitance for carbon surfaces with carbon-oxygen groups, while the second corrosion reaction decreased the Cdl due to loss of the overall carbon surface area. The first oxidation step differed between carbon types, while both reaction rate constants were found to have a dependency on UPL, temperature, and gas relative humidity.

  15. Atmospheric Trace Gases from the Carbon Dioxide Information Analysis Center (CDIAC)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    CDIAC products are indexed and searchable through a customized interface powered by ORNL's Mercury search engine. Products include numeric data packages, publications, trend data, atlases, models, etc. and can be searched for by subject area, keywords, authors, product numbers, time periods, collection sites, spatial references, etc. Some of the collections may also be included in the CDIAC publication, Trends Online: A Compendium of Global Change Data. Most data sets, many with numerous data files, are free to download from CDIAC's ftp area. The collections under the CDIAC heading of Atmospheric Trace Gases include: Atmospheric Carbon Dioxide, Atmospheric Methane, Atmospheric Carbon Monoxide, Atmospheric Hydrogen, Isotopes in Greenhouse Gases, Radionuclides, Aerosols, and Other Trace Gases.

  16. Gas-phase energies of actinide oxides -- an assessment of neutral and cationic monoxides and dioxides from thorium to curium

    SciTech Connect (OSTI)

    Marcalo, Joaquim; Gibson, John K.

    2009-08-10

    An assessment of the gas-phase energetics of neutral and singly and doubly charged cationic actinide monoxides and dioxides of thorium, protactinium, uranium, neptunium, plutonium, americium, and curium is presented. A consistent set of metal-oxygen bond dissociation enthalpies, ionization energies, and enthalpies of formation, including new or revised values, is proposed, mainly based on recent experimental data and on correlations with the electronic energetics of the atoms or cations and with condensed-phase thermochemistry.

  17. Laser hydrothermal reductive ablation of titanium monoxide: Hydrated TiO particles with modified Ti/O surface

    SciTech Connect (OSTI)

    Blazevska-Gilev, Jadranka; Jandova, Vera; Kupcik, Jaroslav; Bastl, Zdenek; Subrt, Jan; Bezdicka, Petr; Pola, Josef

    2013-01-15

    IR laser- and UV laser-induced ablation of titanium monoxide (TM) in hydrogen (50 Torr) is compared to the same process induced in vacuum and shown to result in deposition of hydrated surface modified nanostructured titanium suboxide films. Complementary analyses of the films deposited in vacuum and in hydrogen by Fourier transform infrared, Raman and X-ray photoelectron spectroscopy, X-ray diffraction and electron microscopy allowed to determine different features of both films and propose a mechanism of surface modification of ejected particles, which involves hydrothermal reduction of TM and subsequent reactions of evolved water. The films exert good adhesion to metal and quartz surfaces and are hydrophobic in spite of having their surface coated with adsorbed water. - Graphical abstract: Laser ablation of titanium monoxide (TiO) in hydrogen involves a sequence of H{sub 2} and H{sub 2}O eliminations and additions and yields hydrated amorphous nanostructured titanium suboxide which is richer in oxygen than TiO. Highlights: Black-Right-Pointing-Pointer IR and UV laser ablated particles of titanium monoxide (TiO) undergo amorphization. Black-Right-Pointing-Pointer Films deposited in vacuum have TiO stoichiometry and are oxidized in atmosphere. Black-Right-Pointing-Pointer Films deposited in hydrogen are hydrated and have more O in topmost layers. Black-Right-Pointing-Pointer Films modification in hydrogen is explained by reactions in hydrogen plasma.

  18. Office of HC Policy, Accountability, and Technology (HC-10)

    Broader source: Energy.gov [DOE]

    This organization supports the program objectives and missions of all Departmental components by (1) developing Department-level human capital management (HCM) and training/development policies, (2...

  19. Office of HC Strategy Budget and Performance Metrics (HC-50)

    Broader source: Energy.gov [DOE]

    The Office of Human Capital Strategy, Budget, and Performance Metrics provides strategic direction and advice to its stakeholders through the integration of budget analysis, workforce projections,...

  20. Office of HC Strategy Budget and Performance Metrics (HC-50)...

    Broader source: Energy.gov (indexed) [DOE]

    Statement and Function Statement The Office of Human Capital Strategy, Budget, and ... Provides analytical support and consultative advice to the Chief Human Capital Officer, ...

  1. Office of HC Policy, Accountability, and Technology (HC-10) ...

    Broader source: Energy.gov (indexed) [DOE]

    components by (1) developing Department-level human capital management (HCM) and trainingdevelopment policies, (2) developing human capital management strategies that provide the ...

  2. DEVELOPMENT OF ACTIVATED CARBONS FROM COAL COMBUSTION BY-PRODUCTS

    SciTech Connect (OSTI)

    Harold H. Schobert; M. Mercedes Maroto-Valer; Zhe Lu

    2003-09-30

    inferred from their physical and chemical properties. The developed porosity of the activated carbon was a function of the oxygen content, porosity and H/C ratio of the parent unburned carbon feedstock. It was observed that extended activation times and high activation temperatures increased the porosity of the produced activated carbon at the expense of the solid yield. The development of activated carbon from unburned carbon in fly ash has been proven to be a success by this study in terms of the higher surface areas of the resultant activated carbons, which are comparable with commercial activated carbons. However, unburned carbon samples obtained from coal-fired power plants as by-product have high ash content, which is unwanted for the production of activated carbons. Therefore, the separation of unburned carbon from the fly ash is expected to be beneficial for the utilization of unburned carbon to produce activated carbons with low ash content.

  3. Employment Solutions Division (HC-13)

    Broader source: Energy.gov [DOE]

    This division develops and implements innovative HCM business solutions relating to corporate recruiting, organizational and workforce development, workforce and succession planning, talent...

  4. Information Management Division (HC-14)

    Broader source: Energy.gov [DOE]

    This division provides operational support and consultative advice to the Chief Human Capital Officer and Departmental Senior Management on matters pertaining to the acquisition, deployment and...

  5. R93HC.PDF

    U.S. Energy Information Administration (EIA) Indexed Site

  6. R93HC.PDF

    U.S. Energy Information Administration (EIA) Indexed Site

    a. Space Heating by Census Region and Climate Zone, Million U.S. Households, 1993 Space Heating Characteristics RSE Column Factor: Total Census Region Climate Zone RSE Row Factors Northeast Midwest South West Fewer than 2,000 CDD and -- More than 2,000 CDD and Few- er than 4,000 HDD More than 7,000 HDD 5,500 to 7,000 HDD 4,000 to 5,499 HDD Few- er than 4,000 HDD 0.5 0.9 1.1 0.8 0.8 1.6 1.3 1.2 1.2 1.1 Total ................................................. 96.6 19.5 23.3 33.5 20.4 8.7 26.5 22.5

  7. R93HC.PDF

    U.S. Energy Information Administration (EIA) Indexed Site

    3. Total Air-Conditioning in U.S. Households, 1993 Housing Unit and Household Characteristics RSE Column Factor: Total Households (millions) Cooled Floorspace (square feet per household) Number of Cooling Degree-Days per Household Air-Conditioner Use in Summer 1993 1 (percent of households) RSE Row Factors 1993 Normal Total Not at All Only a Few Times Quite a Bit All Summer 0.8 0.6 0.6 0.6 3.5 0.9 1.4 1.2 Total .................................................... 66.1 1,416 1,536 1,438 100.0 3.4

  8. R93HC.PDF

    U.S. Energy Information Administration (EIA) Indexed Site

    6a. Appliances by Census Region and Climate Zone, Million U.S. Households, 1993 Appliance Types and Characteristics RSE Column Factor: Total Census Region Climate Zone RSE Row Factors Northeast Midwest South West Fewer than 2,000 CDD and -- More than 2,000 CDD and Few- er than 4,000 HDD More than 7,000 HDD 5,500 to 7,000 HDD 4,000 to 5,499 HDD Few- er than 4,000 HDD 0.4 0.9 0.8 0.7 0.8 2.3 1.3 1.3 1.4 1.1 Total ..................................................... 96.6 19.5 23.3 33.5 20.4 8.7

  9. R93HC.PDF

    U.S. Energy Information Administration (EIA) Indexed Site

    0a. Light Usage by Census Region and Climate Zone, Million U.S. Households, 1993 Light Usage RSE Column Factor: Total Census Region Climate Zone RSE Row Factors Northeast Midwest South West Fewer than 2,000 CDD and -- More than 2,000 CDD and Few- er than 4,000 HDD More than 7,000 HDD 5,500 to 7,000 HDD 4,000 to 5,499 HDD Few- er than 4,000 HDD 0.4 0.8 0.8 0.6 0.8 2.4 1.4 1.3 1.4 1.1 Total ..................................................... 96.6 19.5 23.3 33.5 20.4 8.7 26.5 22.5 17.8 21.2 6.6

  10. R93HC.PDF

    U.S. Energy Information Administration (EIA) Indexed Site

    3a. Usage Indicators by Census Region and Climate Zone, Million U.S. Households, 1993 Usage Indicators RSE Column Factor: Total Census Region Climate Zone RSE Row Factors Northeast Midwest South West Fewer than 2,000 CDD and -- More than 2,000 CDD and Few- er than 4,000 HDD More than 7,000 HDD 5,500 to 7,000 HDD 4,000 to 5,499 HDD Few- er than 4,000 HDD 0.4 0.8 0.8 0.7 0.7 2.5 1.4 1.3 1.5 1.2 Total ..................................................... 96.6 19.5 23.3 33.5 20.4 8.7 26.5 22.5 17.8

  11. R93HC.PDF

    U.S. Energy Information Administration (EIA) Indexed Site

    7a. Conservation by Census Region and Climate Zone, Million U.S. Households, 1993 Conservation-Related Items RSE Column Factor: Total Census Region Climate Zone RSE Row Factors Northeast Midwest South West Fewer than 2,000 CDD and -- More than 2,000 CDD and Few- er than 4,000 HDD More than 7,000 HDD 5,500 to 7,000 HDD 4,000 to 5,499 HDD Few- er than 4,000 HDD 0.4 0.8 0.8 0.7 0.8 2.3 1.4 1.3 1.5 1.2 Total ..................................................... 96.6 19.5 23.3 33.5 20.4 8.7 26.5 22.5

  12. R93HC.PDF

    U.S. Energy Information Administration (EIA) Indexed Site

    31a. Equipment Purchase by Census Region and Climate Zone, Million U.S. Households, 1993 Equipment Purchase and Purchase Considerations RSE Column Factor: Total Census Region Climate Zone RSE Row Factors Northeast Midwest South West Fewer than 2,000 CDD and -- More than 2,000 CDD and Few- er than 4,000 HDD More than 7,000 HDD 5,500 to 7,000 HDD 4,000 to 5,499 HDD Few- er than 4,000 HDD 0.5 1.0 0.8 0.7 0.9 2.1 1.1 1.1 1.4 1.1 Total ..................................................... 96.6 19.5

  13. R93HC.PDF

    U.S. Energy Information Administration (EIA) Indexed Site

    Table 3.7a. Space Heating by Census Region and Climate Zone, Million U.S. Households, 1993 Space Heating Characteristics RSE Column Factor: Total Census Region Climate Zone RSE Row Factors Northeast Midwest South West Fewer than 2,000 CDD and -- More than 2,000 CDD and Few- er than 4,000 HDD More than 7,000 HDD 5,500 to 7,000 HDD 4,000 to 5,499 HDD Few- er than 4,000 HDD 0.5 0.9 1.1 0.8 0.8 1.6 1.3 1.2 1.2 1.1 Total ................................................. 96.6 19.5 23.3 33.5 20.4 8.7

  14. Carbon Fiber

    ScienceCinema (OSTI)

    McGetrick, Lee

    2014-07-23

    Lee McGetrick leads ORNL's effort to produce light, durable carbon fiber at lower cost -- a key to improvements in manufacturing that will produce more fuel-efficient vehicles and other advances.

  15. Carbon Fiber

    SciTech Connect (OSTI)

    McGetrick, Lee

    2014-04-17

    Lee McGetrick leads ORNL's effort to produce light, durable carbon fiber at lower cost -- a key to improvements in manufacturing that will produce more fuel-efficient vehicles and other advances.

  16. Carbon Sequestration

    SciTech Connect (OSTI)

    2013-05-06

    Carbon Sequestration- the process of capturing the CO2 released by the burning of fossil fuels and storing it deep withing the Earth, trapped by a non-porous layer of rock.

  17. Carbon Capture

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Capture Fact Sheet Key Contacts Carbon Capture Research & Development Carbon capture and storage from fossil-based power generation is a critical component of realistic strategies for arresting the rise in atmospheric CO2 concentrations, but capturing substantial amounts of CO2 using current technology would result in a prohibitive rise in the cost of producing energy. The National Energy Technology Laboratory Office of Research and Development (NETL-ORD), in collaboration with researchers

  18. Growth direction of oblique angle electron beam deposited silicon monoxide thin films identified by optical second-harmonic generation

    SciTech Connect (OSTI)

    Vejling Andersen, Søren; Lund Trolle, Mads; Pedersen, Kjeld

    2013-12-02

    Oblique angle deposited (OAD) silicon monoxide (SiO) thin films forming tilted columnar structures have been characterized by second-harmonic generation. It was found that OAD SiO leads to a rotationally anisotropic second-harmonic response, depending on the optical angle of incidence. A model for the observed dependence of the second-harmonic signal on optical angle of incidence allows extraction of the growth direction of OAD films. The optically determined growth directions show convincing agreement with cross-sectional scanning electron microscopy images. In addition to a powerful characterization tool, these results demonstrate the possibilities for designing nonlinear optical devices through SiO OAD.

  19. Internal energy and parameters of the order-disorder phase transition in titanium monoxide TiO{sub y}

    SciTech Connect (OSTI)

    Kostenko, M. G.; Rempel, A. A.; Lukoyanov, A. V.

    2013-06-15

    Quantum-mechanical ab initio calculations are used to simulate the free energy functions for titanium monoxide TiO{sub y}. The effect of the long-range order of the Ti{sub 5}O{sub 5} type superstructure on the internal energy of the compound is studied by the supercell method. The dependences of the configuration entropy and free energy on the long-range order parameter are determined. It is found that the order-disorder phase transition in titanium monoxide must occur in accordance with the mechanism of the first-order phase transition with a critical value of the long-range order parameter of 0.971. The calculated parameters of the phase transition are compared with the experimental data and the results obtained using the model of point charges and by calculating the Madelung energy. It is concluded that the short-range order and the phonon entropy must be taken into account in calculating the equilibrium phase diagrams for strongly nonstoichiometric compounds.

  20. Carbon supercapacitors

    SciTech Connect (OSTI)

    Delnick, F.M.

    1993-11-01

    Carbon supercapacitors are represented as distributed RC networks with transmission line equivalent circuits. At low charge/discharge rates and low frequencies these networks approximate a simple series R{sub ESR}C circuit. The energy efficiency of the supercapacitor is limited by the voltage drop across the ESR. The pore structure of the carbon electrode defines the electrochemically active surface area which in turn establishes the volume specific capacitance of the carbon material. To date, the highest volume specific capacitance reported for a supercapacitor electrode is 220F/cm{sup 3} in aqueous H{sub 2}SO{sub 4} (10) and {approximately}60 F/cm{sup 3} in nonaqueous electrolyte (8).

  1. Carbon particles

    DOE Patents [OSTI]

    Hunt, Arlon J.

    1984-01-01

    A method and apparatus whereby small carbon particles are made by pyrolysis of a mixture of acetylene carried in argon. The mixture is injected through a nozzle into a heated tube. A small amount of air is added to the mixture. In order to prevent carbon build-up at the nozzle, the nozzle tip is externally cooled. The tube is also elongated sufficiently to assure efficient pyrolysis at the desired flow rates. A key feature of the method is that the acetylene and argon, for example, are premixed in a dilute ratio, and such mixture is injected while cool to minimize the agglomeration of the particles, which produces carbon particles with desired optical properties for use as a solar radiant heat absorber.

  2. Carbon microtubes

    DOE Patents [OSTI]

    Peng, Huisheng (Shanghai, CN); Zhu, Yuntian Theodore (Cary, NC); Peterson, Dean E. (Los Alamos, NM); Jia, Quanxi (Los Alamos, NM)

    2011-06-14

    A carbon microtube comprising a hollow, substantially tubular structure having a porous wall, wherein the microtube has a diameter of from about 10 .mu.m to about 150 .mu.m, and a density of less than 20 mg/cm.sup.3. Also described is a carbon microtube, having a diameter of at least 10 .mu.m and comprising a hollow, substantially tubular structure having a porous wall, wherein the porous wall comprises a plurality of voids, said voids substantially parallel to the length of the microtube, and defined by an inner surface, an outer surface, and a shared surface separating two adjacent voids.

  3. Carbon | Open Energy Information

    Open Energy Info (EERE)

    Carbon Jump to: navigation, search TODO: Add description Related Links List of Companies in Carbon Sector Retrieved from "http:en.openei.orgwindex.php?titleCarbon&oldid271960...

  4. Characteristics of carbonized sludge for co-combustion in pulverized coal power plants

    SciTech Connect (OSTI)

    Park, Sang-Woo; Jang, Cheol-Hyeon

    2011-03-15

    Co-combustion of sewage sludge can destabilize its combustion profile due to high volatility, which results in unstable flame. We carried out fuel reforming for sewage sludge by way of carbonization at pyrolysis temperature of 300-500 deg. C. Fuel characteristics of carbonized sludge at each temperature were analyzed. As carbonization temperature increased, fuel ratio increased, volatile content reduced, and atomic ratio relation of H/C and O/C was similar to that of lignite. The analysis result of FT-IR showed the decrease of aliphatic C-H bond and O-C bond in carbonization. In the analysis result of TG-DTG, the thermogravimetry reduction temperature of carbonized sludge (CS400) was proven to be higher than that of dried sludge, but lower than that of sub-bituminous coal. Hardgrove grindability index increased in proportion to fuel ratio increase, where the carbonized sludge value of 43-110 was similar or higher than the coal value of 49-63. As for ash deposits, slagging and fouling index were higher than that of coal. When carbonized sludge (CS400) and coal were co-combusted in 1-10% according to calorific value, slagging tendency was low in all conditions, and fouling tendency was medium or high according to the compositions of coal.

  5. Conversion of alkali metal sulfate to the carbonate

    DOE Patents [OSTI]

    Sheth, Atul C. (Woodridge, IL)

    1982-01-01

    A process for converting potassium sulfate to potassium carbonate in which a mixture of potassium sulfate and calcium oxide are reacted at a temperature in the range of between about 700.degree. C. and about 800.degree. C. with a gaseous mixture having a minor amount of hydrogen and/or carbon monoxide in a diluent with the calcium oxide being present in an amount not greater than about 20 percent by weight of the potassium sulfate to produce an aqueous mixture of potassium sulfide, potassium bisulfide, potassium hydroxide and calcium sulfide and a gaseous mixture of steam and hydrogen sulfide. The potassium and calcium salts are quenched to produce an aqueous slurry of soluble potassium salts and insoluble calcium salts and a gaseous mixture of steam and hydrogen sulfide. The insoluble calcium salts are then separated from the aqueous solution of soluble potassium salts. The calcium salts are dried to produce calcium sulfide, calcium bisulfide and steam, and then, the calcium sulfide and calcium bisulfide are converted to the oxide and recycled. The soluble potassium salts are carbonated to produce potassium carbonate which is concentrated and the precipitated crystals separated. The sulfur-containing compounds are further treated.

  6. Carbon investment funds

    SciTech Connect (OSTI)

    2007-01-15

    The report is a study of the development of funds to invest in the purchase of carbon credits. It takes a look at the growing market for carbon credits, the rise of carbon investment funds, and the current state of carbon investing. Topics covered in the report include: Overview of climate change, greenhouse gases, and the Kyoto Protocols. Analysis of the alternatives for reducing carbon emissions including nitrous oxide reduction, coal mine methane capture and carbon capture and storage; Discussion of the different types of carbon credits; Discussion of the basics of carbon trading; Evaluation of the current status of carbon investing; and Profiles of 37 major carbon investment funds worldwide.

  7. Incorporation of catalytic dehydrogenation into Fischer-Tropsch synthesis to lower carbon dioxide emissions

    DOE Patents [OSTI]

    Huffman, Gerald P

    2012-09-18

    A method for producing liquid fuels includes the steps of gasifying a starting material selected from a group consisting of coal, biomass, carbon nanotubes and mixtures thereof to produce a syngas, subjecting that syngas to Fischer-Tropsch synthesis (FTS) to produce a hyrdrocarbon product stream, separating that hydrocarbon product stream into C1-C4 hydrocarbons and C5+ hydrocarbons to be used as liquid fuels and subjecting the C1-C4 hydrocarbons to catalytic dehydrogenation (CDH) to produce hydrogen and carbon nanotubes. The hydrogen produced by CDH is recycled to be mixed with the syngas incident to the FTS reactor in order to raise the hydrogen to carbon monoxide ratio of the syngas to values of 2 or higher, which is required to produce liquid hydrocarbon fuels. This is accomplished with little or no production of carbon dioxide, a greenhouse gas. The carbon is captured in the form of a potentially valuable by-product, multi-walled carbon nanotubes (MWNT), while huge emissions of carbon dioxide are avoided and very large quantities of water employed for the water-gas shift in traditional FTS systems are saved.

  8. An unusual carbon-carbon bond cleavage reaction during phosphinothrici...

    Office of Scientific and Technical Information (OSTI)

    An unusual carbon-carbon bond cleavage reaction during phosphinothricin biosynthesis Citation Details In-Document Search Title: An unusual carbon-carbon bond cleavage reaction ...

  9. Carbon Capital | Open Energy Information

    Open Energy Info (EERE)

    Capital Jump to: navigation, search Name: Carbon Capital Place: United Kingdom Sector: Carbon Product: Manages a carbon fund specialised in forestry projects References: Carbon...

  10. Method of making carbon-carbon composites

    DOE Patents [OSTI]

    Engle, Glen B.

    1993-01-01

    A process for making 2D and 3D carbon-carbon composites having a combined high crystallinity, high strength, high modulus and high thermal and electrical conductivity. High-modulus/high-strength mesophase derived carbon fibers are woven into a suitable cloth. Layers of this easily graphitizible woven cloth are infiltrated with carbon material to form green composites. The carbonized composite is then impregnated several times with pitch by covering the composite with hot pitch under pressure. The composites are given a heat treatment between each impregnant step to crack up the infiltrated carbon and allow additional pitch to enter the microstructure during the next impregnation cycle. The impregnated composites are then given a final heat treatment in the range 2500.degree. to 3100.degree. C. to fully graphitize the fibers and the matrix carbon. The composites are then infiltrated with pyrolytic carbon by chemical vapor deposition in the range 1000.degree. C. to 1300.degree. C. at a reduced. pressure.

  11. Forest Carbon Cycle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    forest carbon cycle Forest Carbon Cycle Terrestrial carbon stocks above- and belowground (in humus and litter layers, woody debris, and mineral soil) are not only sensitive to physical environmental controls (e.g., temperature, precipitation, soil moisture) but also to land use history/management, disturbance, "quality" of carbon input (a reflection of plant carbon allocation and species controls), and the microbial community. The relative importance of these controls on soil carbon

  12. Carbon Capture (Carbon Cycle 2.0)

    ScienceCinema (OSTI)

    Smit, Berend

    2011-06-08

    Berend Smit speaks at the Carbon Cycle 2.0 kick-off symposium Feb. 3, 2010. We emit more carbon into the atmosphere than natural processes are able to remove - an imbalance with negative consequences. Carbon Cycle 2.0 is a Berkeley Lab initiative to provide the science needed to restore this balance by integrating the Labs diverse research activities and delivering creative solutions toward a carbon-neutral energy future. http://carboncycle2.lbl.gov/

  13. The surface chemistry of niobium monoxide: Three low miller index crystal faces

    SciTech Connect (OSTI)

    Womack, J.L.

    1989-01-01

    The stoichiometry, structure, and surface chemistry of the (100), (110), and (111) crystal facets of NbO have been investigated using ultrahigh-vacuum surface-science techniques. Single crystals of NbO were grown by the Czochralski technique for use in these experiments. Auger electron spectroscopy and X-ray photoelectron spectroscopy (XPS) have been used to determine the stoichiometry and chemical state of the three NbO surfaces. The structure of the three crystal faces was examined by low energy electron diffraction (LEED). Surface chemistry was probed by performing temperature programmed desorption (TPD) experiments with water, CO, alcohols, n-hexane, and ethene. The strength of the interactions of these molecules with the surfaces studied provide information on the types of chemistry taking place on the surface. The three, clean NbO surfaces showed a slight oxidation of the surface compared to bulk stoichiometry as determined by XPS. The LEED patterns of the three NbO crystal facets were consistent with surface structures expected from termination of the bulk NbO structure. The superlattice spots present in all the LEED patterns were consistent with the ordered vacancies in the bulk crystal structure. The surfaces could be oxidized, with high oxygen exposure, to a stoichiometry of NbO{sub 2.3}. We hypothesize NbO{sub 2} as the surface compound. The carbon peak shape of the Auger spectrum indicated formation of a carbide surface under certain surface conditions. The surface chemical studies indicated that the NbO surfaces interacted more strongly with alcohols than with water or CO. Hexane and ethene both bonded weakly to the surfaces as well. Interesting reforming or isomerization products were observed for a few adsorbate/surface systems. Some of these products have been tentatively identified.

  14. Composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, S.T.; Pekala, R.W.; Kaschmitter, J.L.

    1997-05-06

    Carbon aerogels used as a binder for granulated materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivity and power to system energy. 1 fig.

  15. Composite carbon foam electrode

    DOE Patents [OSTI]

    Mayer, Steven T.; Pekala, Richard W.; Kaschmitter, James L.

    1997-01-01

    Carbon aerogels used as a binder for granularized materials, including other forms of carbon and metal additives, are cast onto carbon or metal fiber substrates to form composite carbon thin film sheets. The thin film sheets are utilized in electrochemical energy storage applications, such as electrochemical double layer capacitors (aerocapacitors), lithium based battery insertion electrodes, fuel cell electrodes, and electrocapacitive deionization electrodes. The composite carbon foam may be formed by prior known processes, but with the solid particles being added during the liquid phase of the process, i.e. prior to gelation. The other forms of carbon may include carbon microspheres, carbon powder, carbon aerogel powder or particles, graphite carbons. Metal and/or carbon fibers may be added for increased conductivity. The choice of materials and fibers will depend on the electrolyte used and the relative trade off of system resistivty and power to system energy.

  16. Methanol Decomposition over Palladium Particles Supported on Silica: Role of Particle Size and Co-Feeding Carbon Dioxide on the Catalytic Properties

    SciTech Connect (OSTI)

    Hokenek, Selma; Kuhn, John N. (USF)

    2012-10-23

    Monodisperse palladium particles of six distinct and controlled sizes between 4-16 nm were synthesized in a one-pot polyol process by varying the molar ratios of the two palladium precursors used, which contained palladium in different oxidation states. This difference permitted size control by regulation of the nucleation rate because low oxidation state metals ions nucleate quickly relative to high oxidation state ions. After immobilization of the Pd particles on silica by mild sonication, the catalysts were characterized by X-ray absorption spectroscopy and applied toward catalytic methanol decomposition. This reaction was determined as structure sensitive with the intrinsic activity (turnover frequency) increasing with increasing particle size. Moreover, observed catalytic deactivation was linked to product (carbon monoxide) poisoning. Co-feeding carbon dioxide caused the activity and the amount of deactivation to decrease substantially. A reaction mechanism based on the formation of the {pi}-bond between carbon and oxygen as the rate-limiting step is in agreement with antipathetic structure sensitivity and product poisoning by carbon monoxide.

  17. Acetylenic carbon allotrope

    DOE Patents [OSTI]

    Lagow, Richard J.

    1998-01-01

    A fourth allotrope of carbon, an acetylenic carbon allotrope, is described. The acetylenic carbon allotropes of the present invention are more soluble than the other known carbon allotropes in many common organic solvents and possesses other desirable characteristics, e.g. high electron density, ability to burn cleanly, and electrical conductive properties. Many uses for this fourth allotrope are described herein.

  18. Acetylenic carbon allotrope

    DOE Patents [OSTI]

    Lagow, Richard J.

    1999-01-01

    A fourth allotrope of carbon, an acetylenic carbon allotrope, is described. The acetylenic carbon allotropes of the present invention are more soluble than the other known carbon allotropes in many common organic solvents and possesses other desirable characteristics, e.g. high electron density, ability to burn cleanly, and electrical conductive properties. Many uses for this fourth allotrope are described herein.

  19. Carbon Nanotube Based Sensors

    SciTech Connect (OSTI)

    Jiang, Mian; Lin, Yuehe

    2006-11-01

    This review article provides a comprehensive review on sensors and biosensors based on functionalized carbon nanotubes.

  20. Acetylenic carbon allotrope

    DOE Patents [OSTI]

    Lagow, R.J.

    1998-02-10

    A fourth allotrope of carbon, an acetylenic carbon allotrope, is described. The acetylenic carbon allotropes of the present invention are more soluble than the other known carbon allotropes in many common organic solvents and possesses other desirable characteristics, e.g. high electron density, ability to burn cleanly, and electrical conductive properties. Many uses for this fourth allotrope are described herein. 17 figs.

  1. Carbon nanotube composite materials

    DOE Patents [OSTI]

    O'Bryan, Gregory; Skinner, Jack L; Vance, Andrew; Yang, Elaine Lai; Zifer, Thomas

    2015-03-24

    A material consisting essentially of a vinyl thermoplastic polymer, un-functionalized carbon nanotubes and hydroxylated carbon nanotubes dissolved in a solvent. Un-functionalized carbon nanotube concentrations up to 30 wt % and hydroxylated carbon nanotube concentrations up to 40 wt % can be used with even small concentrations of each (less than 2 wt %) useful in producing enhanced conductivity properties of formed thin films.

  2. Mesoporous carbon materials

    DOE Patents [OSTI]

    Dai, Sheng; Fulvio, Pasquale Fernando; Mayes, Richard T.; Wang, Xiqing; Sun, Xiao-Guang; Guo, Bingkun

    2014-09-09

    A conductive mesoporous carbon composite comprising conductive carbon nanoparticles contained within a mesoporous carbon matrix, wherein the conductive mesoporous carbon composite possesses at least a portion of mesopores having a pore size of at least 10 nm and up to 50 nm, and wherein the mesopores are either within the mesoporous carbon matrix, or are spacings delineated by surfaces of said conductive carbon nanoparticles when said conductive carbon nanoparticles are fused with each other, or both. Methods for producing the above-described composite, devices incorporating them (e.g., lithium batteries), and methods of using them, are also described.

  3. A first principle study for the adsorption and absorption of carbon atom and the CO dissociation on Ir(100) surface

    SciTech Connect (OSTI)

    Erikat, I. A.; Hamad, B. A.

    2013-11-07

    We employ density functional theory to examine the adsorption and absorption of carbon atom as well as the dissociation of carbon monoxide on Ir(100) surface. We find that carbon atoms bind strongly with Ir(100) surface and prefer the high coordination hollow site for all coverages. In the case of 0.75 ML coverage of carbon, we obtain a bridging metal structure due to the balance between Ir–C and Ir–Ir interactions. In the subsurface region, the carbon atom prefers the octahedral site of Ir(100) surface. We find large diffusion barrier for carbon atom into Ir(100) surface (2.70 eV) due to the strong bonding between carbon atom and Ir(100) surface, whereas we find a very small segregation barrier (0.22 eV) from subsurface to the surface. The minimum energy path and energy barrier for the dissociation of CO on Ir(100) surface are obtained by using climbing image nudge elastic band. The energy barrier of CO dissociation on Ir(100) surface is found to be 3.01 eV, which is appreciably larger than the association energy (1.61 eV) of this molecule.

  4. Carbon fuel cells with carbon corrosion suppression

    DOE Patents [OSTI]

    Cooper, John F.

    2012-04-10

    An electrochemical cell apparatus that can operate as either a fuel cell or a battery includes a cathode compartment, an anode compartment operatively connected to the cathode compartment, and a carbon fuel cell section connected to the anode compartment and the cathode compartment. An effusion plate is operatively positioned adjacent the anode compartment or the cathode compartment. The effusion plate allows passage of carbon dioxide. Carbon dioxide exhaust channels are operatively positioned in the electrochemical cell to direct the carbon dioxide from the electrochemical cell.

  5. Metallic carbon materials

    DOE Patents [OSTI]

    Cohen, Marvin Lou; Crespi, Vincent Henry; Louie, Steven Gwon Sheng; Zettl, Alexander Karlwalter

    1999-01-01

    Novel metallic forms of planar carbon are described, as well as methods of designing and making them. Nonhexagonal arrangements of carbon are introduced into a graphite carbon network essentially without destroying the planar structure. Specifically a form of carbon comprising primarily pentagons and heptagons, and having a large density of states at the Fermi level is described. Other arrangements of pentagons and heptagons that include some hexagons, and structures incorporating squares and octagons are additionally disclosed. Reducing the bond angle symmetry associated with a hexagonal arrangement of carbons increases the likelihood that the carbon material will have a metallic electron structure.

  6. Carbon Jungle | Open Energy Information

    Open Energy Info (EERE)

    Jungle Jump to: navigation, search Name: Carbon Jungle Place: El Segundo, California Zip: 90246 Sector: Carbon Product: Carbon Jungle's mission is to decrease CO2 in the atmosphere...

  7. Carbon Connections | Open Energy Information

    Open Energy Info (EERE)

    Connections Jump to: navigation, search Name: Carbon Connections Place: Norfolk, England, United Kingdom Zip: NR4 7TJ Sector: Carbon Product: Carbon Connections links partner...

  8. Large Magnetization at Carbon Surfaces

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Large Magnetization at Carbon Surfaces Large Magnetization at Carbon Surfaces Print Wednesday, 31 August 2011 00:00 From organic matter to pencil lead, carbon is a versatile...

  9. Asset Carbon | Open Energy Information

    Open Energy Info (EERE)

    Carbon Jump to: navigation, search Name: Asset Carbon Place: United Kingdom Product: UK-based startup looking to invest in CDMJI projects. References: Asset Carbon1 This article...

  10. Jumpstarting the carbon capture industry

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Jumpstarting the carbon capture industry: Science on the Hill Jumpstarting the carbon capture industry: Science on the Hill Carbon capture, utilization, and storage can provide a...

  11. Carbon emissions and sequestration in forests: Case studies from seven developing countries

    SciTech Connect (OSTI)

    Makundi, W.; Sathaye, J. ); Fearnside, P.M. , Manaus, AM . Departmento de Ecologia)

    1992-08-01

    Deforestation in Brazilian Amazonia in 1990 was releasing approximately 281--282 X 10{sup 6} metric tons (MT) of carbon on conversion to a landscape of agriculture, productive pasture, degraded pasture, secondary forest and regenerated forest in the proportions corresponding to the equilibrium condition implied by current land-use patterns. Emissions are expressed as committed carbon,'' or the carbon released over a period of years as the carbon stock in each hectare deforested approaches a new equilibrium in the landscape that replaces the original forest. To the extent that deforestation rates have remained constant, current releases from the areas deforested in previous years will be equal to the future releases from the areas being cleared now. Considering the quantities of carbon dioxide, carbon monoxide, methane, nitrous oxide, NO{sub x} and non-methane hydrocarbons released raises the impact by 22--37%. The relative impact on the greenhouse effect of each gas is based on the Intergovernmental Panel on Climate Change (IPCC) calculations over a 20-year time period (including indirect effects). The six gases considered have a combined global warming impact equivalent to 343 to 386 million MT of C0{sub 2}-equivalent carbon, depending on assumptions regarding the release of methane and other gases from the various sources such as burning and termites. These emissions represent 7--8 times the 50 million MT annual carbon release from Brazil's use of fossil fuels, but bring little benefit to the country. Stopping deforestation in Brazil would prevent as much greenhouse emission as tripling the fuel efficiency of all the automobiles in the world. The relatively cheap measures needed to contain deforestation, together with the many complementary benefits of doing so, make this the first priority for funds intended to slow global warming.

  12. Organic carbon in Bakken Formation, United States portion of Williston Basin

    SciTech Connect (OSTI)

    Schmoker, J.W.; Hester, T.C.

    1983-12-01

    The upper and lower members of the Mississippian and Devonian Bakken Formation in the United States portion of the Williston basin are black shales that are extremely rich in organic matter and are the source of much of the oil found in the basin. Organic-carbon values are calculated from formationdensity logs using the equation: TOC = (154.497//rho/) -57.261, where TOC is organic-carbon content (wt. %) and /rho/ is formation density (g/cm/sup 3/). Test calculations comparing this equation to laboratory organic-carbon analyses from 39 wells in North Dakota show an average absolute difference of 1.1% in organic-carbon content. Organic-carbon content, calculated at 159 locations in North Dakota and 107 in Montana, averages 12.1% for the upper member of the Bakken Formation and 11.5% for the lower member. There is a regional depletion of organic carbon, paralleling present-day isotherms, that reflects the conversion of organic matter to oil and subsequent expulsion of the oil from the formation. The mass of organic carbon in the Bakken Formation is approximately evenly divided between the upper and lower members, and it totals about 126 X 10/sup 12/ kg in the study area, of which 102 X 10/sup 12/ kg are in the thermally mature region. The assumption that 167 mg HC/g TOC have migrated out of the mature Bakken shales leads to a tentative estimate that hydrocarbons equivalent to 132 billion bbl of 43/sup 0/ (API gravity) oil have been expelled from the United States portion of the upper and lower members of the Bakken Formation.

  13. Method of making carbon-carbon composites

    DOE Patents [OSTI]

    Engle, Glen B.

    1991-01-01

    A process for making a carbon-carbon composite having a combination of high crystallinity, high strength, high modulus and high thermal and electrical conductivity. High-modulus/high-strength mesophase derived carbon fibers are woven into a suitable cloth. Layers of this easily graphitizable woven cloth are covered with petroleum or coal tar pitch and pressed at a temperature a few degrees above the softening point of the pitch to form a green laminated composite. The green composite is restrained in a suitable fixture and heated slowly to carbonize the pitch binder. The carbonized composite is then impregnated several times with pitch by covering the composite with hot pitch under pressure. The composites are given a heat treatment between each impregnation step to crack up the infiltrated carbon and allow additional pitch to enter the microstructure during the next impregnation cycle. The impregnated composites are then given a final heat treatment in the range 2500.degree. to 3000.degree. C. to fully graphitize the fibers and the matrix carbon. The composites are then infiltrated with pyrolytic carbon by chemical vapor deposition in the range 1000.degree. to 1300.degree. C. at a reduced pressure for approximately one hundred and fifty (150) hours.

  14. Carbon Emissions: Food Industry

    U.S. Energy Information Administration (EIA) Indexed Site

    Food Industry Carbon Emissions in the Food Industry The Industry at a Glance, 1994 (SIC Code: 20) Total Energy-Related Emissions: 24.4 million metric tons of carbon (MMTC) -- Pct....

  15. Carbon nanotube nanoelectrode arrays

    DOE Patents [OSTI]

    Ren, Zhifeng; Lin, Yuehe; Yantasee, Wassana; Liu, Guodong; Lu, Fang; Tu, Yi

    2008-11-18

    The present invention relates to microelectode arrays (MEAs), and more particularly to carbon nanotube nanoelectrode arrays (CNT-NEAs) for chemical and biological sensing, and methods of use. A nanoelectrode array includes a carbon nanotube material comprising an array of substantially linear carbon nanotubes each having a proximal end and a distal end, the proximal end of the carbon nanotubes are attached to a catalyst substrate material so as to form the array with a pre-determined site density, wherein the carbon nanotubes are aligned with respect to one another within the array; an electrically insulating layer on the surface of the carbon nanotube material, whereby the distal end of the carbon nanotubes extend beyond the electrically insulating layer; a second adhesive electrically insulating layer on the surface of the electrically insulating layer, whereby the distal end of the carbon nanotubes extend beyond the second adhesive electrically insulating layer; and a metal wire attached to the catalyst substrate material.

  16. Metal filled porous carbon

    DOE Patents [OSTI]

    Gross, Adam F.; Vajo, John J.; Cumberland, Robert W.; Liu, Ping; Salguero, Tina T.

    2011-03-22

    A porous carbon scaffold with a surface and pores, the porous carbon scaffold containing a primary metal and a secondary metal, where the primary metal is a metal that does not wet the surface of the pores of the carbon scaffold but wets the surface of the secondary metal, and the secondary metal is interspersed between the surface of the pores of the carbon scaffold and the primary metal.

  17. Carbon Sequestration.ppt

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Concepts Current Sequestration Methods Novel Concepts * Glacial Storage * Biogenic Methane * Mineralization * Waste Streams Recycling * Calcium Carbonate Hydrates Glacial...

  18. ARM - Measurement - Total carbon

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carbon ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Total carbon The total concentration of carbon in all its organic and non-organic forms. Categories Atmospheric Carbon, Aerosols Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available measurements, including

  19. Big Sky Carbon Atlas

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    (Acknowledgment to the Big Sky Carbon Sequestration Partnership (BSCSP); see home page at http://www.bigskyco2.org/)

  20. Carbon Bearing Trace Gases

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    carbon bearing trace gases Carbon Bearing Trace Gases A critical scientific and policy oriented question is what are the present day sources and sinks of carbon dioxide (CO2) in the natural environment and how will these sinks evolve under rising CO2 concentrations and expected climate change and ecosystem response. Sources and sinks of carbon dioxide impart their signature on the distribution, concentration, and isotopic composition of CO2. Spatial and temporal trends (variability) provide

  1. Carbon Capture Simulation Initiative

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Capture R&D Carbon Capture R&D DOE's Carbon Capture Program, administered by the Office of Fossil Energy and the National Energy Technology Laboratory, is conducting research and development activities on Second Generation and Transformational carbon capture technologies that have the potential to provide step-change reductions in both cost and energy penalty as compared to currently available First Generation technologies. The Carbon Capture Program consists of two core research

  2. Wetland (peat) Carbon Cycle

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    wetland peat carbon cycle Wetland (peat) Carbon Cycle Methane (CH4) is an important greenhouse gas, twenty times more potent than CO2, but atmospheric concentrations of CH4 under future climate change are uncertain. This is in part because many climate-sensitive ecosystems release both CH4 and carbon dioxide (CO2) and it is unknown how these systems will partition future releases of carbon to the atmosphere. Ecosystem observations of CH4 emissions lack mechanistic links to the processes that

  3. Intro to Carbon Sequestration

    ScienceCinema (OSTI)

    None

    2010-01-08

    NETL's Carbon Sequestration Program is helping to develop technologies to capture, purify, and store carbon dioxide (CO2) in order to reduce greenhouse gas emissions without adversely influencing energy use or hindering economic growth. Carbon sequestration technologies capture and store CO2 that would otherwise reside in the atmosphere for long periods of time.

  4. Intro to Carbon Sequestration

    SciTech Connect (OSTI)

    2008-03-06

    NETL's Carbon Sequestration Program is helping to develop technologies to capture, purify, and store carbon dioxide (CO2) in order to reduce greenhouse gas emissions without adversely influencing energy use or hindering economic growth. Carbon sequestration technologies capture and store CO2 that would otherwise reside in the atmosphere for long periods of time.

  5. Office of Executive Resources (HC-40)

    Office of Energy Efficiency and Renewable Energy (EERE)

    This organization provides a full range of human capital management workforce services and support as well as policy guidance functions to senior level positions (SES, SL, and ST), excepted service...

  6. TableHC10.1.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    0.1 Housing Unit Characteristics by U.S. Census Region, 2005 Total......................................................................... 111.1 20.6 25.6 40.7 24.2 Census Region and Division Northeast.............................................................. 20.6 20.6 N N N New England..................................................... 5.5 5.5 N N N Middle Atlantic................................................... 15.1 15.1 N N N

  7. TableHC10.13.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    25.6 40.7 24.2 Indoor Lights Turned On During Summer Number of Lights Turned On Between 1 and 4 Hours per Day........................... 91.8 16.8 21.7 33.8 19.5 1.......................................................................... 28.6 5.0 6.3 11.2 6.1 2.......................................................................... 29.5 6.2 6.5 10.5 6.3 3.......................................................................... 14.7 2.5 4.0 5.0 3.1

  8. TableHC10.8.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    Number of Water Heaters 1............................................................................... 106.3 19.6 24.5 39.0 23.2 2 or More.................................................................. 3.7 0.3 0.9 1.5 1.0 Do Not Use Hot Water.............................................. 1.1 0.7 Q Q Q Housing Units Served by Main Water Heater One Housing Unit..................................................... 99.7 16.1 23.5 38.2 21.9 Two or More Housing

  9. TableHC11.12.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    15.1 5.5 Personal Computers Do Not Use a Personal Computer.................................. 35.5 6.9 5.3 1.6 Use a Personal Computer.............................................. 75.6 13.7 9.8 3.9 Most-Used Personal Computer Type of PC Desk-top Model......................................................... 58.6 10.4 7.3 3.1 Laptop Model............................................................. 16.9 3.3 2.6 0.7 Hours Turned on Per Week Less than 2

  10. TableHC11.13.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    15.1 5.5 Indoor Lights Turned On During Summer Number of Lights Turned On Between 1 and 4 Hours per Day........................... 91.8 16.8 12.2 4.6 1.......................................................................... 28.6 5.0 3.5 1.5 2.......................................................................... 29.5 6.2 4.8 1.4 3.......................................................................... 14.7 2.5 1.7 0.8

  11. TableHC11.8.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    Number of Water Heaters 1............................................................................... 106.3 19.6 14.4 5.2 2 or More.................................................................. 3.7 0.3 Q Q Do Not Use Hot Water.............................................. 1.1 0.7 0.6 Q Housing Units Served by Main Water Heater One Housing Unit..................................................... 99.7 16.1 11.7 4.5 Two or More Housing Units....................................... 10.3 3.7

  12. TableHC12.1.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    2.1 Housing Unit Characteristics by Midwest Census Region, 2005 Total......................................................................... 111.1 25.6 17.7 7.9 Urban/Rural Location (as Self-Reported) City....................................................................... 47.1 9.7 7.3 2.4 Town..................................................................... 19.0 5.0 2.9 2.1 Suburbs................................................................ 22.7 5.7 4.3 1.4

  13. TableHC12.13.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    5.6 17.7 7.9 Indoor Lights Turned On During Summer Number of Lights Turned On Between 1 and 4 Hours per Day........................... 91.8 21.7 14.5 7.2 1.......................................................................... 28.6 6.3 4.4 1.9 2.......................................................................... 29.5 6.5 4.2 2.3 3.......................................................................... 14.7 4.0 2.8 1.2

  14. TableHC12.8.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    Number of Water Heaters 1............................................................................... 106.3 24.5 17.1 7.4 2 or More.................................................................. 3.7 0.9 0.5 0.4 Do Not Use Hot Water.............................................. 1.1 Q Q Q Housing Units Served by Main Water Heater One Housing Unit..................................................... 99.7 23.5 16.2 7.3 Two or More Housing Units....................................... 10.3 1.9

  15. TableHC13.1.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    3.1 Housing Unit Characteristics by South Census Region, 2005 Total......................................................................... 111.1 40.7 21.7 6.9 12.1 Urban/Rural Location (as Self-Reported) City....................................................................... 47.1 17.8 10.5 2.2 5.1 Town..................................................................... 19.0 4.9 2.2 0.7 2.0 Suburbs................................................................ 22.7 7.6 4.1 1.1 2.4

  16. TableHC13.13.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    0.7 21.7 6.9 12.1 Indoor Lights Turned On During Summer Number of Lights Turned On Between 1 and 4 Hours per Day........................... 91.8 33.8 17.5 6.1 10.3 1.......................................................................... 28.6 11.2 6.5 1.5 3.2 2.......................................................................... 29.5 10.5 5.4 2.0 3.1 3.......................................................................... 14.7 5.0 2.1 1.2 1.7

  17. TableHC13.8.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    Number of Water Heaters 1............................................................................... 106.3 39.0 21.1 6.6 11.3 2 or More.................................................................. 3.7 1.5 0.5 0.3 0.7 Do Not Use Hot Water.............................................. 1.1 Q Q N Q Housing Units Served by Main Water Heater One Housing Unit..................................................... 99.7 38.2 20.2 6.7 11.3 Two or More Housing

  18. TableHC14.1.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    4.1 Housing Unit Characteristics by West Census Region, 2005 Total......................................................................... 111.1 24.2 7.6 16.6 Urban/Rural Location (as Self-Reported) City....................................................................... 47.1 12.8 3.2 9.6 Town..................................................................... 19.0 3.0 1.1 1.9 Suburbs................................................................ 22.7 4.9 1.6 3.3

  19. TableHC14.13.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    4.2 7.6 16.6 Indoor Lights Turned On During Summer Number of Lights Turned On Between 1 and 4 Hours per Day........................... 91.8 19.5 6.1 13.4 1.......................................................................... 28.6 6.1 1.7 4.4 2.......................................................................... 29.5 6.3 1.8 4.5 3.......................................................................... 14.7 3.1 1.1 2.0

  20. TableHC14.5.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    4.2 7.6 16.6 Do Not Have Heating Equpment............................ 1.2 0.7 Q 0.7 Have Space Heating Equpment............................. 109.8 23.4 7.5 16.0 Use Space Heating Equpment.............................. 109.1 22.9 7.4 15.4 Have But Do Not Use Equipment.......................... 0.8 0.6 Q 0.5 Space Heating Usage During 2005 Heated Floorspace (Square Feet) None................................................................. 3.6 2.1 Q 1.9 1 to

  1. TableHC14.8.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    Number of Water Heaters 1............................................................................... 106.3 23.2 7.1 16.1 2 or More.................................................................. 3.7 1.0 0.4 0.6 Do Not Use Hot Water.............................................. 1.1 Q Q N Housing Units Served by Main Water Heater One Housing Unit..................................................... 99.7 21.9 7.1 14.8 Two or More Housing Units....................................... 10.3 2.3

  2. TableHC15.8.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    8 Water Heating Characteristics by Four Most Populated States, 2005 Total............................................................................. 111.1 7.1 7.0 8.0 12.1 Number of Water Heaters 1............................................................................... 106.3 6.5 6.9 7.4 11.7 2 or More.................................................................. 3.7 Q Q 0.5 0.4 Do Not Use Hot Water.............................................. 1.1 0.5 N Q N Housing Units Served by

  3. TableHC2.1.xls

    U.S. Energy Information Administration (EIA) Indexed Site

  4. TableHC2.11.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    Million U.S. Housing Units Total................................................................... 111.1 72.1 7.6 7.8 16.7 6.9 Personal Computers Do Not Use a Personal Computer ............... 35.5 17.8 3.1 3.7 7.3 3.6 Use a Personal Computer............................. 75.6 54.2 4.5 4.0 9.4 3.4 Number of Desktop PCs 1.............................................................. 50.3 33.9 3.1 3.0 7.6 2.7 2.............................................................. 16.2 12.7 0.9 0.7 1.4

  5. TableHC2.13.xls

    U.S. Energy Information Administration (EIA) Indexed Site

  6. TableHC2.3.xls

    U.S. Energy Information Administration (EIA) Indexed Site

  7. TableHC2.4.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    81.5 72.1 7.6 N N 1.9 For Two Housing Units............................. 18.1 N N 1.4 16.7 N Heat Pump.................................................. 9.2 7.4 0.3 Q 0.7 0.5 Other Equipment......................................... 1.3 0.6 Q Q Q N Fuel Oil........................................................... 7.7 5.5 0.4 0.8 0.9 0.2 Steam or Hot Water System........................ 4.7 2.9 Q 0.7 0.8 N For One Housing Unit.............................. 3.3 2.9 Q Q Q N For Two Housing

  8. TableHC2.8.xls

    U.S. Energy Information Administration (EIA) Indexed Site

  9. TableHC2.9.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    9 Home Appliances Characteristics by Type of Housing Unit, 2005 Million U.S. Housing Units Total U.S............................................................ 111.1 72.1 7.6 7.8 16.7 6.9 Cooking Appliances Conventional Ovens Use an Oven............................................... 109.6 71.3 7.4 7.7 16.4 6.8 1.............................................................. 103.3 66.2 7.2 7.4 15.9 6.7 2 or More................................................. 6.2 5.1 Q 0.3 0.5 Q Do Not Use an

  10. TableHC3.1.xls

    U.S. Energy Information Administration (EIA) Indexed Site

    78.1 64.1 4.2 1.8 2.3 5.7 Census Region and Division Northeast.................................................... 20.6 13.4 10.4 1.4 1.0 0.3 0.4 New England........................................... 5.5 3.8 3.1 Q 0.3 Q Q Middle Atlantic........................................ 15.1 9.6 7.3 1.3 0.6 Q Q Midwest...................................................... 25.6 19.4 16.9 1.0 0.5 0.4 0.7 East North Central.................................. 17.7 13.6 11.7 0.7 0.5 Q 0.3 West North