Sample records for hazardous metals arsenic

  1. TOLERANCE OF HEAVY METALS IN VASCULAR PLANTS: ARSENIC HYPERACCUMULATIONBY

    E-Print Network [OSTI]

    Ma, Lena

    CHAPTER 28 b TOLERANCE OF HEAVY METALS IN VASCULAR PLANTS: ARSENIC HYPERACCUMULATIONBY CHINESE the roots take up colossal amounts of a toxic metal from soils and rapidly sequester into their above-ground hyperaccumulation in the light of accumulated knowledge on heavy metal tolerance in higher plants. 1.INTRODUCTION

  2. arsenic exposure arsenic: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  3. Scoping evaluation of the technical capabilities of DOE sites for disposal of hazardous metals in mixed low-level waste

    SciTech Connect (OSTI)

    Gruebel, M.M.; Waters, R.D.; Langkopf, B.S.

    1997-05-01T23:59:59.000Z

    A team of analysts designed and conducted a scoping evaluation to estimate the technical capabilities of fifteen Department of Energy sites for disposal of the hazardous metals in mixed low-level waste (i.e., waste that contains both low-level radioactive materials and hazardous constituents). Eight hazardous metals were evaluated: arsenic, barium, cadmium, chromium, lead, mercury, selenium, and silver. The analysis considered transport only through the groundwater pathway. The results are reported as site-specific estimates of maximum concentrations of each hazardous metal in treated mixed low-level waste that do not exceed the performance measures established for the analysis. Also reported are site-specific estimates of travel times of each hazardous metal to the point of compliance.

  4. arsenicals: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  5. arsenic: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  6. Use of MgO doped with a divalent or trivalent metal cation for removing arsenic from water

    DOE Patents [OSTI]

    Moore, Robert C; Holt-Larese, Kathleen C; Bontchev, Ranko

    2013-08-13T23:59:59.000Z

    Systems and methods for use of magnesium hydroxide, either directly or through one or more precursors, doped with a divalent or trivalent metal cation, for removing arsenic from drinking water, including water distribution systems. In one embodiment, magnesium hydroxide, Mg(OH).sub.2 (a strong adsorbent for arsenic) doped with a divalent or trivalent metal cation is used to adsorb arsenic. The complex consisting of arsenic adsorbed on Mg(OH).sub.2 doped with a divalent or trivalent metal cation is subsequently removed from the water by conventional means, including filtration, settling, skimming, vortexing, centrifugation, magnetic separation, or other well-known separation systems. In another embodiment, magnesium oxide, MgO, is employed, which reacts with water to form Mg(OH).sub.2. The resulting Mg(OH).sub.2 doped with a divalent or trivalent metal cation, then adsorbs arsenic, as set forth above. The method can also be used to treat human or animal poisoning with arsenic.

  7. arsenic 87: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  8. arsenic alloys: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  9. arsenic 89: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  10. arsenic trioxide cytotoxicity: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  11. arsenic additions: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  12. arsenic 90: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  13. arsenic complexes: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  14. arsenic trioxide modulates: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  15. arsenic trioxide synergistically: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  16. arsenic 78: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  17. arsenic 80: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  18. aluminium nickel arsenic: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  19. arsenic metabolites plasma: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  20. arsenic fluorides: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  1. arsenic 82: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  2. arsenic compounds: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  3. arsenic bromides: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  4. arsenic detoxification potential: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  5. amorphous nonannealed arsenic: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  6. arsenic mouse micronucleus: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  7. arsenic iodides: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  8. arsenic trioxide ato: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  9. arsenic 83: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  10. arsenic 84: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  11. arsenic 79: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  12. arsenic 92: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  13. arsenic 88: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  14. arsenic 76: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  15. arsenic ions: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  16. arsenic isotopes: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  17. arsenic chlorides: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  18. arsenic 74: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  19. arsenic 85: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  20. arsenic sulfides: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  1. arsenic 81: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  2. arsenic trisulphide thin: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  3. arsenic trioxide anticancer: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  4. arsenic 86: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  5. arsenic trioxide-induced apoptosis: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  6. arsenic trioxide-induced mitotic: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  7. arsenic diglutathione-binding proteins: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  8. arsenic trioxide-mediated notch: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  9. arsenite-and arsenic diglutathione-binding: Topics by E-print...

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  10. arsenic trioxide-resistant a549: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  11. arsenic induces mitochondria-dependent: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  12. arsenic trioxide as2o3-mediated: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  13. arsenic trioxide as2o3: Topics by E-print Network

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    arsenic uptake and heavy metals on arsenic distribution in an arsenic-contaminated soil Environmental Management and Restoration Websites Summary: Effects of plant arsenic uptake...

  14. Iron phosphate compositions for containment of hazardous metal waste

    DOE Patents [OSTI]

    Day, D.E.

    1998-05-12T23:59:59.000Z

    An improved iron phosphate waste form for the vitrification, containment and long-term disposition of hazardous metal waste such as radioactive nuclear waste is provided. The waste form comprises a rigid iron phosphate matrix resulting from the cooling of a melt formed by heating a batch mixture comprising the metal waste and a matrix-forming component. The waste form comprises from about 30 to about 70 weight percent P{sub 2}O{sub 5} and from about 25 to about 50 weight percent iron oxide and has metals present in the metal waste chemically dissolved therein. The concentration of iron oxide in the waste form along with a high proportion of the iron in the waste form being present as Fe{sup 3+} provide a waste form exhibiting improved chemical resistance to corrosive attack. A method for preparing the improved iron phosphate waste forms is also provided. 21 figs.

  15. Iron phosphate compositions for containment of hazardous metal waste

    DOE Patents [OSTI]

    Day, Delbert E. (Rolla, MO)

    1998-01-01T23:59:59.000Z

    An improved iron phosphate waste form for the vitrification, containment and long-term disposition of hazardous metal waste such as radioactive nuclear waste is provided. The waste form comprises a rigid iron phosphate matrix resulting from the cooling of a melt formed by heating a batch mixture comprising the metal waste and a matrix-forming component. The waste form comprises from about 30 to about 70 weight percent P.sub.2 O.sub.5 and from about 25 to about 50 weight percent iron oxide and has metals present in the metal waste chemically dissolved therein. The concentration of iron oxide in the waste form along with a high proportion of the iron in the waste form being present as Fe.sup.3+ provide a waste form exhibiting improved chemical resistance to corrosive attack. A method for preparing the improved iron phosphate waste forms is also provided.

  16. Composite Materials for Hazard Mitigation of Reactive Metal Hydrides.

    SciTech Connect (OSTI)

    Pratt, Joseph William; Cordaro, Joseph Gabriel; Sartor, George B.; Dedrick, Daniel E.; Reeder, Craig L.

    2012-02-01T23:59:59.000Z

    In an attempt to mitigate the hazards associated with storing large quantities of reactive metal hydrides, polymer composite materials were synthesized and tested under simulated usage and accident conditions. The composites were made by polymerizing vinyl monomers using free-radical polymerization chemistry, in the presence of the metal hydride. Composites with vinyl-containing siloxane oligomers were also polymerized with and without added styrene and divinyl benzene. Hydrogen capacity measurements revealed that addition of the polymer to the metal hydride reduced the inherent hydrogen storage capacity of the material. The composites were found to be initially effective at reducing the amount of heat released during oxidation. However, upon cycling the composites, the mitigating behavior was lost. While the polymer composites we investigated have mitigating potential and are physically robust, they undergo a chemical change upon cycling that makes them subsequently ineffective at mitigating heat release upon oxidation of the metal hydride. Acknowledgements The authors would like to thank the following people who participated in this project: Ned Stetson (U.S. Department of Energy) for sponsorship and support of the project. Ken Stewart (Sandia) for building the flow-through calorimeter and cycling test stations. Isidro Ruvalcaba, Jr. (Sandia) for qualitative experiments on the interaction of sodium alanate with water. Terry Johnson (Sandia) for sharing his expertise and knowledge of metal hydrides, and sodium alanate in particular. Marcina Moreno (Sandia) for programmatic assistance. John Khalil (United Technologies Research Corp) for insight into the hazards of reactive metal hydrides and real-world accident scenario experiments. Summary In an attempt to mitigate and/or manage hazards associated with storing bulk quantities of reactive metal hydrides, polymer composite materials (a mixture of a mitigating polymer and a metal hydride) were synthesized and tested under simulated usage and accident conditions. Mitigating the hazards associated with reactive metal hydrides during an accident while finding a way to keep the original capability of the active material intact during normal use has been the focus of this work. These composites were made by polymerizing vinyl monomers using free-radical polymerization chemistry, in the presence of the metal hydride, in this case a prepared sodium alanate (chosen as a representative reactive metal hydride). It was found that the polymerization of styrene and divinyl benzene could be initiated using AIBN in toluene at 70 degC. The resulting composite materials can be either hard or brittle solids depending on the cross-linking density. Thermal decomposition of these styrene-based composite materials is lower than neat polystyrene indicating that the chemical nature of the polymer is affected by the formation of the composite. The char-forming nature of cross-linked polystyrene is low and therefore, not an ideal polymer for hazard mitigation. To obtain composite materials containing a polymer with higher char-forming potential, siloxane-based monomers were investigated. Four vinyl-containing siloxane oligomers were polymerized with and without added styrene and divinyl benzene. Like the styrene materials, these composite materials exhibited thermal decomposition behavior significantly different than the neat polymers. Specifically, the thermal decomposition temperature was shifted approximately 100 degC lower than the neat polymer signifying a major chemical change to the polymer network. Thermal analysis of the cycled samples was performed on the siloxane-based composite materials. It was found that after 30 cycles the siloxane-containing polymer composite material has similar TGA/DSC-MS traces as the virgin composite material indicating that the polymer is physically intact upon cycling. Hydrogen capacity measurements revealed that addition of the polymer to the metal hydride in the form of a composite material reduced the inherent hydrogen storage capacity of the material. This

  17. Treatment of Arsenic, Heavy Metals, and Acidity Using a Mixed ZVI-Compost PRB

    SciTech Connect (OSTI)

    Ludwig, R.; Smyth, D; Blowes, D; Spink, L; Wilkin, R; Jewett, D; Weisener, C

    2009-01-01T23:59:59.000Z

    A 30-month performance evaluation of a pilot permeable reactive barrier (PRB) consisting of a mixture of leaf compost, zero-valent iron (ZVI), limestone, and pea gravel was conducted at a former phosphate fertilizer manufacturing facility in Charleston, SC. The PRB is designed to remove heavy metals and arsenic from groundwater by promoting microbially mediated sulfate reduction and sulfide-mineral precipitation and arsenic and heavy metal sorption. Performance monitoring showed effective treatment of As, Pb, Cd, Zn, and Ni from concentrations as high as 206 mg L{sup -1}, 2.02 mg L{sup -1}, 0.324 mg L{sup -1}, 1060 mg L{sup -1}, and 2.12 mg L{sup -1}, respectively, entering the PRB, to average concentrations of <0.03 mg L{sup -1}, < 0.003 mg L{sup -1}, < 0.001 mg L{sup -1}, < 0.23 mg L{sup -1}, and <0.003 mg L{sup -1}, respectively, within the PRB. Both As(III) and As(V) were effectively removed from solution with X-ray absorption near edge structure (XANES) analysis of core samples indicating the presence of As(V) in oxygen-bound form and As(III) in both oxygen- and sulfur-bound forms. XANES solid phase sulfur analysis indicated decreases in the peak amplitude of intermediate oxidized sulfur species and sulfate components with increasing distance and depth within the PRB.

  18. Preparation of waste oil for analysis to determine hazardous metals

    SciTech Connect (OSTI)

    Essling, A.M.; Huff, D.R.; Huff, E.A.; Fox, I.M.; Graczyk, D.G.

    1995-07-01T23:59:59.000Z

    Two methods for preparing waste-oil samples to permit measurement of their metals content were evaluated. For this evaluation, metals-in-oil standard reference materials were prepared by each method and the resulting solutions were analyzed for 20 metals, including those (As, Ba, Cd, Cr, Pb, Hg, Se, and Ag) regulated as hazardous under the Resource Conservation and Recovery Act. One preparation method involved combustion of the waste oil under oxygen at 25 atm pressure, as described in the American Society for Testing and Materials test method E926-88. As we applied it, this method gave recoveries well under 90% for most of the metals that we examined and, hence, proved unsatisfactory for routine application to waste-oil analysis. With the other method, nitric acid decomposition in a sealed vessel heated with microwave energy (analogous to US Environmental Protection Agency Method 3051), recoveries of all 20 metal contaminants were within 90 to 110% of the certified values. This microwave digestion procedure was also more efficient since it allowed six samples to be prepared together, whereas the oxygen combustion approach allowed processing of only one sample at a time.

  19. Metal and arsenic impacts to soils, vegetation communities and wildlife habitat in southwest Montana uplands contaminated by smelter emissions. 1: Field evaluation

    SciTech Connect (OSTI)

    Galbraith, H.; LeJeune, K.; Lipton, J. [Hagler Bailly Consulting, Inc., Boulder, CO (United States)

    1995-11-01T23:59:59.000Z

    Concentrations of arsenic and metals in soils surrounding a smelter in southwest Montana were correlated with vegetative community structure and composition and wildlife habitat quality. Soils in the uplands surrounding the smelter were highly enriched with arsenic and metals. Concentrations of these analytes decreased with distance from the smelter and with soil depth, suggesting that the smelter is the source of the enrichment. In enriched areas, marked modifications to the native vegetation community structure and composition were observed. These included replacement of evergreen forest with bare unvegetated ground; species impoverishment and increased dominance by weed species in grasslands; and reductions in the vertical complexity of the habitat. Significant negative correlations existed between soil arsenic and metals concentrations and the extent of vegetative cover and the vertical diversity of plant communities. Loss of vegetative cover in the affected areas has been accompanied by reductions in their capacity to support indigenous wildlife populations.

  20. Chemical and Mineralogical Characterization of Arsenic, Lead, Chromium, and Cadmium in a Metal-contaminated Histosol

    SciTech Connect (OSTI)

    Gao, X.; Schulze, D

    2010-01-01T23:59:59.000Z

    The chemical and mineralogical forms of As, Pb, Cr, and Cd were studied in a metal-contaminated organic soil (Histosol) that received runoff and seepage water from a site that was once occupied by a lead smelter. Soil samples were collected from different depth intervals during both wet and dry seasons and analyzed using bulk powder X-ray diffraction (XRD), synchrotron-based micro X-ray diffraction ({mu}-XRD), and micro X-ray fluorescence ({mu}-SXRF) spectroscopy. There was a clear pattern of mineral distribution with depth that indicated the presence of an intense redox gradient. The oxidized reddish brown surface layer (0-10 cm) was dominated by goethite ({alpha}-FeOOH) and poorly crystalline akaganeite ({beta}-FeOOH). Lead and arsenic were highly associated with these Fe oxides, possibly by forming inner-sphere surface complexes. Gypsum (CaSO{sub 4} {center_dot} 2H{sub 2}O) was abundant in the layer as well, particularly for samples collected during dry periods. Fe(II)-containing minerals, such as magnetite (Fe{sub 3}O{sub 4}) and siderite (FeCO{sub 3}), were identified in the intermediate layers (10-30 cm) where the reductive dissolution of Fe(III) oxides occurred. A number of high-temperature minerals, such as mullite (3Al{sub 2}O{sub 3} {center_dot} 2Si{sub 2}O), corundum ({alpha}-Al{sub 2}O{sub 3}), hematite ({alpha}-Fe{sub 2}O{sub 3}), and wustite (FeO) were identified in the subsurface and they probably formed as a result of a burning event. Several sulfide minerals were identified in the most reduced layers at depths > 30 cm. They included realgar (AsS), alacranite (As{sub 4}S{sub 4}), galena (PbS), and sphalerite (Zn, Fe{sup 2+})S, and a series of Fe sulfides, including greigite (Fe{sup 2+}Fe{sub 2}{sup 3+} S{sub 4}), pyrrhotite (Fe{sub 1-x}S), mackinawite (FeS), marcasite (FeS{sub 2}), and pyrite (FeS{sub 2}). Most of these minerals occurred as almost pure phases in sub-millimeter aggregates and appeared to be secondary phases that had precipitated from solution. Despite the elevated levels of Cd in the soil, no specific Cd phases were identified. The complex mineralogy has important implications for risk assessment and the design of in-situ remediation strategies for this and similar metal-contaminated sites.

  1. Method for mobilization of hazardous metal ions in soils

    DOE Patents [OSTI]

    Dugan, Patrick R. (Idaho Falls, ID); Pfister, Robert M. (Powell, OH)

    1995-01-01T23:59:59.000Z

    A microbial process for removing heavy metals such as bismuth, cadmium, lead, thorium, uranium and other transuranics from soils and sediments, utilizing indigenous, or isolates of indigenous, microorganisms and reducing agents, such as cysteine or sodium thioglycollate, or complexing agents such as the amino acid glycine, to effect the mobilization or release of the metals from the soil particles.

  2. Method for mobilization of hazardous metal ions in soils

    DOE Patents [OSTI]

    Dugan, P.R.; Pfister, R.M.

    1995-06-27T23:59:59.000Z

    A microbial process is revealed for removing heavy metals such as bismuth, cadmium, lead, thorium, uranium and other transuranics from soils and sediments. The method utilizes indigenous, or isolates of indigenous, microorganisms and reducing agents, such as cysteine or sodium thioglycollate, or complexing agents such as the amino acid glycine, to effect the mobilization or release of the metals from the soil particles. 5 figs.

  3. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    SciTech Connect (OSTI)

    James T. Cobb, Jr.

    2003-09-12T23:59:59.000Z

    Metal-laden wastes can be stabilized and solidified using advanced clean coal technology by-products (CCTBs)--fluid bed combustor ash and spray drier solids. These utility-generated treatment chemicals are available for purchase through brokers, and commercial applications of this process are being practiced by treaters of metal-laden hazardous waste. A complex of regulations governs this industry, and sensitivities to this complex has discouraged public documentation of treatment of metal-laden hazardous wastes with CCTBs. This report provides a comprehensive public documentation of laboratory studies that show the efficacy of the stabilization and solidification of metal-laden hazardous wastes--such as lead-contaminated soils and sandblast residues--through treatment with CCTBs. It then describes the extensive efforts that were made to obtain the permits allowing a commercial hazardous waste treater to utilize CCTBs as treatment chemicals and to install the equipment required to do so. It concludes with the effect of this lengthy process on the ability of the treatment company to realize the practical, physical outcome of this effort, leading to premature termination of the project.

  4. Systematic Engineering of Phytochelatin Synthesis and Arsenic Transport for Enhanced Arsenic

    E-Print Network [OSTI]

    Chen, Wilfred

    . KEYWORDS: heavy metals; arsenic; bioremediation; glutathione; phytochelatins Introduction Arsenic (As in surface water and As (III) in ground water. Arsenic exposure has been associated with many diseases a general structure of (g-Glu-Cys-)n-Gly (n ¼ 1­11) and have been shown to chelate heavy metals with higher

  5. Clean process to destroy arsenic-containing organic compounds with recovery of arsenic

    DOE Patents [OSTI]

    Upadhye, R.S.; Wang, F.T.

    1996-08-13T23:59:59.000Z

    A reduction method is provided for the treatment of arsenic-containing organic compounds with simultaneous recovery of pure arsenic. Arsenic-containing organic compounds include pesticides, herbicides, and chemical warfare agents such as Lewisite. The arsenic-containing compound is decomposed using a reducing agent. Arsine gas may be formed directly by using a hydrogen-rich reducing agent, or a metal arsenide may be formed using a pure metal reducing agent. In the latter case, the arsenide is reacted with an acid to form arsine gas. In either case, the arsine gas is then reduced to elemental arsenic. 1 fig.

  6. TREATMENT OF METAL-LADEN HAZARDOUS WASTES WITH ADVANCED CLEAN COAL TECHNOLOGY BY-PRODUCTS

    SciTech Connect (OSTI)

    James T. Cobb, Jr.; Ronald D. Neufeld; Jana Agostini

    1999-05-10T23:59:59.000Z

    This fourteenth quarterly report describes work done during the fourteenth three-month period of the University of Pittsburgh's project on the ''Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.'' This report describes the activities of the project team during the reporting period. The principal work has focused upon new laboratory evaluation of samples from Phase 1, discussions with MAX Environmental Technologies, Inc., on the field work of Phase 2, preparing presentations, and making and responding to two outside contacts.

  7. Drinking Water Problems: Arsenic

    E-Print Network [OSTI]

    Lesikar, Bruce J.; Melton, Rebecca; Hare, Michael; Hopkins, Janie; Dozier, Monty

    2005-12-02T23:59:59.000Z

    High levels of arsenic in drinking water can poison and even kill people. This publication explains the symptoms of arsenic poisoning and common treatment methods for removing arsenic from your water supply....

  8. Metal and arsenic impacts to soils, vegetation communities and wildlife habitat in southwest Montana uplands contaminated by smelter emissions. 2: Laboratory phytotoxicity studies

    SciTech Connect (OSTI)

    Kapustka, L.A. [Ecological Planning and Toxicology, Inc., Corvallis, OR (United States); Lipton, J.; Galbraith, H.; Cacela, D.; LeJeune, K. [Hagler Bailly Consulting, Inc., Boulder, CO (United States)

    1995-11-01T23:59:59.000Z

    Vegetation communities on metal- and arsenic-contaminated uplands surrounding a smelter in southwest Montana have been eliminated or highly modified. Laboratory toxicity tests were performed using site soils from the impacted areas to determine whether the soils limit the ability of plants to establish and grow. The germination and growth of alfalfa, lettuce, and wheat in impacted area soils was compared to germination and growth of the three species in reference soils. The degree of phytotoxicity was quantified using a species-endpoint toxicity score calculated on the magnitude of difference between germination and growth of plants in impacted and reference soils. The impacted soils exhibited substantial toxicity to plants: 5% of the sites were severely phytotoxic, 55% were highly phytotoxic, 10% were moderately phytotoxic, 20% were mildly phytotoxic, and 10% were nontoxic. Root growth was consistently the most affected endpoint (18 of 20 impacted soils) and reduction in root length and mass was observed. Correlation and partial correlation analysis was used to evaluate the causes of phytotoxicity. Concentrations of As, Cu, and Zn and, to a lesser extent, Pb and Cd were found to be positively correlated with phytotoxicity.

  9. Field implementation complexities of EPA developmental methods during remediation at hazardous waste sites: Case study

    SciTech Connect (OSTI)

    Green, E.L. [Eagle Environmental Health, Inc., Houston, TX (United States); Cunningham, E.A. [Tenneco, Inc., Houston, TX (United States); Grabinski, C. [Joslyn Corp., Chicago, IL (United States)

    1995-12-31T23:59:59.000Z

    The objective of this presentation is to provide insight into the complexities of field implementation of Environmental Protection Agency developmental methods for polynuclear aromatic hydrocarbons, pentachlorophenol, particulates and metals at hazardous waste site remediations. A remedial action plan developed for the site called for the development and subsequent execution of an air monitoring plan during the removal of affected subsurface soils. Ambient air monitoring for polynuclear aromatic hydrocarbons, pentachlorophenol, total particulates and arsenic, chromium and copper was conducted from February through May, 1992. After May, sampling for arsenic, chromium and copper was dropped from the plan because of the extremely low levels of metals associated with the soils. Real-time monitoring for total suspended particulates was conducted from February through September, 1992.

  10. Detecting Hazardous Gas Analytes Using Porous Silicon Sensors Coated with Metal Oxide Nanoparticles Eddie Goude, University of Florida Georgia Tech SURF 2011

    E-Print Network [OSTI]

    Li, Mo

    Detecting Hazardous Gas Analytes Using Porous Silicon Sensors Coated with Metal Oxide Nanoparticles oxide coatings and the Hard-Soft Acid-Base concept. This sensor is proposed to be a new, nanotechnology for this experiment, p-type and n-type. The wafers were first coated with silicon carbide and then etched with a mask

  11. arsenic contaminated soils: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    x-ray fluorescence and x-contaminating metal cations (Cu, Zn, & Cr) in the solid phase speciation of arsenic. Elemental maps from SXRF of this study show that As...

  12. Arsenic removal from water

    DOE Patents [OSTI]

    Moore, Robert C. (Edgewood, NM); Anderson, D. Richard (Albuquerque, NM)

    2007-07-24T23:59:59.000Z

    Methods for removing arsenic from water by addition of inexpensive and commonly available magnesium oxide, magnesium hydroxide, calcium oxide, or calcium hydroxide to the water. The hydroxide has a strong chemical affinity for arsenic and rapidly adsorbs arsenic, even in the presence of carbonate in the water. Simple and commercially available mechanical methods for removal of magnesium hydroxide particles with adsorbed arsenic from drinking water can be used, including filtration, dissolved air flotation, vortex separation, or centrifugal separation. A method for continuous removal of arsenic from water is provided. Also provided is a method for concentrating arsenic in a water sample to facilitate quantification of arsenic, by means of magnesium or calcium hydroxide adsorption.

  13. Characterizing arsenic in preserved hair for assessing exposure potential and discriminating poisoning

    SciTech Connect (OSTI)

    Kempson, Ivan M.; Henry, Dermot; Francis, James; (Museum Vic.); (U. South Australia); (UWO)

    2009-05-21T23:59:59.000Z

    Advanced analytical techniques have been used to characterize arsenic in taxidermy specimens. Arsenic was examined to aid in discriminating its use as a preservative from that incorporated by ingestion and hence indicate poisoning (in the case of historical figures). The results are relevant to museum curators, occupational and environmental exposure concerns, toxicological and anthropological investigations. Hair samples were obtained from six taxidermy specimens preserved with arsenic in the late 1800s and early 1900s to investigate the arsenic incorporation. The presence of arsenic poses a potential hazard in museum and private collections. For one sample, arsenic was confirmed to be present on the hair with time-of-flight secondary ion mass spectrometry and then measured with neutron activation analysis to comprise 176 {mu}g g{sup -1}. The hair cross section was analysed with synchrotron micro-X-ray fluorescence to investigate the transverse distribution of topically applied arsenic. It was found that the arsenic had significantly penetrated all hair samples. Association with melanin clusters and the medulla was observed. Lead and mercury were also identified in one sample. X-ray absorption near-edge spectroscopy of the As K-edge indicated that an arsenate species predominantly existed in all samples; however, analysis was hindered by very rapid photoreduction of the arsenic. It would be difficult to discriminate arsenic consumption from topically applied arsenic based on the physical transverse distribution. Longitudinal distributions and chemical speciation may still allow differentiation.

  14. Thermodynamic modeling of volatile hazardous metal behavior in the Vortec Vitrification System

    SciTech Connect (OSTI)

    Nowok, J.W.; Hurley, J.P.

    2000-07-31T23:59:59.000Z

    The thermochemical equilibrium calculations indicate that at the temperature of a propane--air flame, some volatilization of uranium, plutonium, technetium, and cesium will occur. The expected concentrations of plutonium, technetium, and cesium in the flame will be very low because of the small maximum concentration of these elements in the projected feed materials for the first 30-day test. The quantities volatilized can generally be decreased by operating the flame in a fuel-rich mode, although this will lead to greater carbon monoxide production, which may be more objectionable. The concentrations of chlorine and fluorine, at least at the maximum levels in the projected Vortec feed, are not projected to greatly influence the vaporization rates. Therefore, blending to reduce the concentrations of those elements would most likely not be effective in reducing metal vaporization. Most of the elements vaporized condense by the time the gas cools to 2000 F. These elements would condense either on surfaces near the front of the heat recuperator or on entrained particulates or homogeneously as relatively pure submicron particles. Cesium would be expected to condense at the lower temperatures near the rear of the recuperator, although the expected maximum concentration in the Vortec feed material is extremely low so it should be greatly diluted by other particulates. The elements that condense on other entrained particles will form enriched surface coatings. Particles larger than 10{micro}m or so will be collected in the scrubber. Smaller particles, especially the submicron particles formed from homogeneous nucleation, should be largely collected in the HEPA filter. Deposits formed in the heat recuperator can normally be handled via sootblowing. To reduce handling problems, we suggest that the recuperator be oriented vertically so that the deposits blown off of the heat exchanger fall directly into the molten glass. The large size of the deposits should help to reduce the rate of revaporization, allowing the volatile elements to be removed with the glass. The volatile elements that do not deposit on system surfaces will be concentrated in the smaller particles. Therefore, the HEPA ash will be greatly enriched in these elements. If the HEPA filter is itself sent to a melter, the elements may revaporize and multiply the problems related to metal vaporization significantly. Therefore, the HEPA filters should be disposed of without high-temperature processing. Also, to reduce the formation of these very small particles, it is helpful to include in the feed larger particles to act as condensation nuclei that can then be collected in the scrubber. This can be accomplished by using feed materials with a fraction consisting of particles small enough that they will not be collected in the cyclone in the melter, but large enough that they will easily be collected by the scrubber. This is one advantage that firing bituminous coal has over gas firing; it provides a source of ash particles of the right size range to serve as nucleation sites, but large enough (depending on the coal) so that they can usually be collected efficiently in the scrubber system.

  15. Arsenic activation neutron detector

    DOE Patents [OSTI]

    Jacobs, E.L.

    1980-01-28T23:59:59.000Z

    A detector of bursts of neutrons from a deuterium-deuteron reaction includes a quantity of arsenic adjacent a gamma detector such as a scintillator and photomultiplier tube. The arsenic is activated by the 2.5-MeV neutrons to release gamma radiation which is detected to give a quantitative representation of detected neutrons.

  16. Treatment of metal-laden hazardous wastes with advanced clean coal technology by-products. Quartery report, August 1994--November 1994

    SciTech Connect (OSTI)

    NONE

    1994-12-01T23:59:59.000Z

    This first quarterly report describes work during the first three months of the University of Pittsburgh`s (Pitt`s) project on the {open_quotes}Treatment of Metal-Laden Hazardous Wastes with Advanced Clean Coal Technology By-Products.{close_quotes} Participating with Pitt on this project are Dravo Lime Company (DLC), Mill Service, Inc. (MSO and the Center for Hazardous Materials Research (CHMR)). The report states the goals of the project - both general and specific - and then describes the activities of the project team during the reporting period. All of this work has been organizational and developmental in nature. No data has yet been collected. Technical details and data will appear for the first time in the second quarterly report and be the major topic of subsequent reports.

  17. Global atmospheric transport and source-receptor1 relationships for arsenic2

    E-Print Network [OSTI]

    Wu, Shiliang

    important anthropogenic arsenic sources7-10 with45 copper smelting being the dominant source6 contributions from anthropogenic sources. Metal (copper, zinc and lead)44 smelting and coal combustion are two 11 . In China and Chile, the dominated arsenic source55 #12;4 regions in northern and southern

  18. Method of recycling hazardous waste

    SciTech Connect (OSTI)

    NONE

    1999-11-11T23:59:59.000Z

    The production of primary metal from ores has long been a necessary, but environmentally devastating process. Over the past 20 years, in an effort to lessen environmental impacts, the metal processing industry has developed methods for recovering metal values from certain hazardous wastes. However, these processes leave residual molten slag that requires disposal in hazardous waste landfills. A new process recovers valuable metals, metal alloys, and metal oxides from hazardous wastes, such as electric arc furnace (EAF) dust from steel mills, mill scale, spent aluminum pot liners, and wastewater treatment sludge from electroplating. At the same time, the process does not create residual waste for disposal. This new method uses all wastes from metal production processes. These hazardous materials are converted to three valuable products - mineral wool, zinc oxide, and high-grade iron.

  19. Macroscopic and spectroscopic investigation of interactions of arsenic with synthesized pyrite

    E-Print Network [OSTI]

    Kim, Eun Jung

    2009-05-15T23:59:59.000Z

    Sulfide minerals have been suggested to play an important role in regulating dissolved metal concentrations in anoxic environments. Pyrite is the most common sulfide mineral and it has shown an affinity for arsenic, but little is known about...

  20. arsenic-contaminated pyrite wastes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    x-ray fluorescence and x-contaminating metal cations (Cu, Zn, & Cr) in the solid phase speciation of arsenic. Elemental maps from SXRF of this study show that As...

  1. Characterization of Arsenic Contamination on Rust from Ton Containers

    SciTech Connect (OSTI)

    Gary S. Groenewold; Recep Avci; Robert V. Fox; Muhammedin Deliorman; Jayson Suo; Laura Kellerman

    2013-01-01T23:59:59.000Z

    The speciation and spatial distribution of arsenic on rusted steel surfaces affects both measurement and removal approaches. The chemistry of arsenic residing in the rust of ton containers that held the chemical warfare agents bis(2-chloroethyl)sulfide (sulfur mustard) and 2-chlorovinyldichloroarsine (Lewisite) is of particular interest, because while the agents have been decontaminated, residual arsenic could pose a health or environmental risk. The chemistry and distribution of arsenic in rust samples was probed using imaging secondary ion mass spectrometry (SIMS), X-ray photoelectron spectroscopy (XPS), Auger electron spectroscopy, and scanning electron microscopy/energy dispersive X-ray spectroscopy (SEM/EDX). Arsenic in the +3 and or +5 oxidation state is homogeneously distributed at the very top-most layer of the rust samples, and is intimately associated with iron. Sputter depth profiling followed by SIMS and XPS shows As at a depth of several nm, in some cases in a reduced form. The SEM/EDX experiments show that As is present at a depth of several microns, but is inhomogeneously distributed; most locations contained oxidized As at concentrations of a few percent, however several locations showed very high As in a metallic form. These results indicate that the rust material must be removed if the steel containers are to be cleared of arsenic.

  2. Arsenic Speciation in Wastes Resulting From Pressure Oxidation, Roasting and Smelting

    SciTech Connect (OSTI)

    Paktunc, D. (CCM)

    2010-11-01T23:59:59.000Z

    Arsenic commonly occurs in elevated concentrations in some gold and base-metal deposits. Mining and metallurgical processing of gold and base-metal ores results in solid wastes, effluents, and air emissions containing high concentrations of arsenic. Such wastes form an important source of anthropogenic arsenic in the environment. The nature and occurrence of arsenic in solid wastes are complex and highly variable. A combination of microanalytical tools and techniques including XAFS were used to determine the form and speciation of arsenic in wastes resulting from pressure oxidation, roasting and smelting, and impacted soil. As K-edge and Fe K-edge XAFS analyses of the pressure oxidation residues indicate that arsenic in tetrahedral coordination is corner-linked to 5 to 6 FeO{sub 6} octahedra that are edge- and perhaps face-sharing. During roasting of refractory gold ores, oxidation of As to As{sub 2}O{sub 5} species may be incomplete, which is detrimental to not only gold recovery but also the tailings management options. As K-edge XANES spectra indicate that more than one-third of the arsenic released from a copper smelter stack is composed of As{sup 3+} species. Most likely arsenic species in the smelter-impacted soil include arsenolite, goethite with adsorbed As{sup 5+}, monomethylarsonic acidm, and tetramethylarsonium iodide.

  3. Arsenic removal and stabilization by synthesized pyrite

    E-Print Network [OSTI]

    Song, Jin Kun

    2009-05-15T23:59:59.000Z

    hydride generation atomic absorption spectrometry method for measuring arsenic species (As(III), As(V)). The synthesized pyrite was applied to remove arsenic and its maximum capacity for arsenic removal was measured in batch adsorption experiments to be 3...

  4. Removing Arsenic from Drinking Water

    ScienceCinema (OSTI)

    None

    2013-05-28T23:59:59.000Z

    See how INL scientists are using nanotechnology to remove arsenic from drinking water. For more INL research, visit http://www.facebook.com/idahonationallaboratory

  5. Removal of arsenic compounds from petroliferous liquids

    DOE Patents [OSTI]

    Fish, R.H.

    1984-04-06T23:59:59.000Z

    The present invention in one aspect comprises a process for removing arsenic from petroliferous-derived liquids by contacting said liquid with a divinylbenzene-crosslinked polystyrene polymer (i.e. PS-DVB) having catechol ligands anchored to said polymer, said contacting being at an elevated temperature. In another aspect, the invention is a process for regenerating spent catecholated polystyrene polymer by removal of the arsenic bound to it from contacting petroliferous liquid in accordance with the aspect described above which regenerating process comprises: (a) treating said spent catecholated polystyrene polymer with an aqueous solution of at least one member selected from the group consisting of carbonates and bicarbonates of ammonium, alkali metals, and alkaline earth metals, said solution having a pH between about 8 and 10, and said treating being at a temperature in the range of about 20/sup 0/ to 100/sup 0/C; (b) separating the solids and liquids from each other. In a preferred embodiment the regeneration treatment is in two steps wherein step: (a) is carried out with an aqueous alcoholic carbonate solution which includes at least one lower alkyl alcohol, and, steps (c) and (d) are added. Steps (c) and (d) comprise: (c) treating the solids with an aqueous alcoholic solution of at least one ammonium, alkali or alkaline earth metal bicarbonate at a temperature in the range of about 20 to 100/sup 0/C; and (d) separating the solids from the liquids.

  6. Production of selenium-72 and arsenic-72

    DOE Patents [OSTI]

    Phillips, D.R.

    1994-12-06T23:59:59.000Z

    Methods and apparatus are described for producing selenium-72, separating it from its daughter isotope arsenic-72, and generating multiple portions of a solution containing arsenic-72 from a reusable parent substance comprised of selenium-72. The invention provides apparatus which can be located at a site where arsenic-72 is used, for purposes such as PET imaging, to produce arsenic-72 as needed, since the half-life of arsenic-72 is very short. 2 figures.

  7. Production of selenium-72 and arsenic-72

    DOE Patents [OSTI]

    Phillips, Dennis R. (Los Alamos, NM)

    1994-01-01T23:59:59.000Z

    Methods and apparatus for producing selenium-72, separating it from its daughter isotope arsenic-72, and generating multiple portions of a solution containing arsenic-72 from a reusable parent substance comprised of selenium-72. The invention provides apparatus which can be located at a site where arsenic-72 is used, for purposes such as PET imaging, to produce arsenic-72 as needed, since the half-life of arsenic-72 is very short.

  8. Production of selenium-72 and arsenic-72

    DOE Patents [OSTI]

    Phillips, Dennis R. (Los Alamos, NM)

    1995-01-01T23:59:59.000Z

    Methods and apparatus for producing selenium-72, separating it from its daughter isotope arsenic-72, and generating multiple portions of a solution containing arsenic-72 from a reusable parent substance comprised of selenium-72. The invention provides apparatus which can be located at a site where arsenic-72 is used, for purposes such as PET imaging, to produce arsenic-72 as needed, since the half-life of arsenic-72 is very short.

  9. Electrical hazards

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and certification by ANL prior to use. The Control of Hazardous Energy Sources - LockoutTagout (LOTO) Types of Energy Sources 1. Electricity 2. Gas, steam & pressurized...

  10. Trace metal capture by various sorbents during fluidized bed coal combustion

    SciTech Connect (OSTI)

    Ho, T.C.; Ghebremeskel, A.N.; Hopper, J.R. [Lamar Univ., Beaumont, TX (United States)

    1996-12-31T23:59:59.000Z

    Toxic trace metallic elements such as arsenic, beryllium, cadmium, chromium, cobalt, lead, manganese, mercury, nickel, and selenium are usually contained in coal in various forms and trace amounts. These metals will either stay in the ash or be vaporized during high temperature combustion. Portions of the vaporized metals may eventually be emitted from a combustion system in the form of metal fumes or particulates with diameters less than 1 micron, which are potentially hazardous to the environment. Current practice of controlling trace metal emissions during coal combustion employs conventional air pollution control devices (APCDs), such as electrostatic precipitators and baghouses, to collect fly ash and metal fumes. The control may not always be effective on metal fumes due to their extremely fine sizes. This study is to explore the opportunities for improved control of toxic trace metal emissions from coal-fired combustion systems. Specifically, the technology proposed is to employ suitable sorbents to reduce the amount of metal volatilization and capture volatilized metal vapors during fluidized bed coal combustion. The objective of the study was to investigate experimentally and theoretically the metal capture process.

  11. Hazardous Waste Program (Alabama)

    Broader source: Energy.gov [DOE]

    This rule states criteria for identifying the characteristics of hazardous waste and for listing hazardous waste, lists of hazardous wastes, standards for the management of hazardous waste and...

  12. Hazards Survey and Hazards Assessments

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1997-08-21T23:59:59.000Z

    This volume is to assist DOE Operations/Field Offices and operating contractors in complying with the DOE O 151.1 requirement that Hazards Surveys and facility-specific Hazards Assessments be prepared, maintained, and used for emergency planning purposes. Canceled by DOE G 151.1-2.

  13. Production of selenium-72 and arsenic-72

    DOE Patents [OSTI]

    Phillips, D.R.

    1993-04-20T23:59:59.000Z

    Methods are described for producing selenium-72, separating it from its daughter isotope arsenic-72, and generating multiple portions of a solution containing arsenic-72 from a reusable parent substance comprised of selenium-72.

  14. Arsenic in your water?: Economists study perceptions of risks from drinking water high in arsenic

    E-Print Network [OSTI]

    Wythe, Kathy

    2010-01-01T23:59:59.000Z

    Arsenic in water?your tx H2O | pg. 27 Story by Kathy Wythe Economists study perceptions of risks from drinking water high in arsenic In several ?hot spots? across the United States people may be drinking water with high levels of naturally... occurring arsenic without understanding the associated risks, according to agricultural economists. ?Many households in arsenic ?hot spots? are in fact being exposed to harmful doses of arsenic,? said Dr. Douglass Shaw, professor of agricultural...

  15. Arsenic in human history and modern societies

    SciTech Connect (OSTI)

    Kevin R. Henke; David A. Atwood [University of Kentucky, Lexington, KY (United States). Dept. of Chemistry

    2009-03-15T23:59:59.000Z

    Chapter 5 contains a section titled: Arsenic in coal and oil shale utilization and their by-products.

  16. Surface characterizatin of palladium-alumina sorbents for high-temperature capture of mercury and arsenic from fuel gas

    SciTech Connect (OSTI)

    Baltrus, J.P.; Granite, E.J.; Pennline, H.W.; Stanko, D.; Hamilton, H.; Rowsell, L.; Poulston, S.; Smith, A.; Chu, W.

    2010-01-01T23:59:59.000Z

    Coal gasification with subsequent cleanup of the resulting fuel gas is a way to reduce the impact of mercury and arsenic in the environment during power generation and on downstream catalytic processes in chemical production, The interactions of mercury and arsenic with PdlAl2D3 model thin film sorbents and PdlAh03 powders have been studied to determine the relative affinities of palladium for mercury and arsenic, and how they are affected by temperature and the presence of hydrogen sulfide in the fuel gas. The implications of the results on strategies for capturing the toxic metals using a sorbent bed are discussed.

  17. Hazard evaluation

    SciTech Connect (OSTI)

    Vervalin, C.H.

    1986-12-01T23:59:59.000Z

    Recent major disasters in the hydrocarbon processing industry (HPI) have inspired renewed interest in the fine-tuning of hazard evaluation methods. In addition to traditional risk-study methods, the computer promises eventual expert systems to vastly improve the speed of assembling and using loss-prevention information. But currently, the computerization of hazard evaluation finds the HPI taking a back seat to aerospace/nuclear industries. The complexity of creating computer databases and expert systems has not-however-kept some HPI companies from plunging in. Arabian American Oil Co. (Aramco) has used computer-generated information in working with probabilistic risk analysis. Westinghouse has used its risk-analysis experience in the nuclear field to build a computer-based program for HPI clients. An Exxon plant has a huge data bank as the basis for its Hazard Loss Information System.

  18. HAZARDOUS MATERIALS INCIDENTS What are hazardous materials?

    E-Print Network [OSTI]

    Fernandez, Eduardo

    HAZARDOUS MATERIALS INCIDENTS What are hazardous materials? Hazardous materials are chemicals, accidentally spilled, or released. In addition to laboratory chemicals, hazardous materials may include common not involve highly toxic or noxious hazardous materials, a fire, or an injury requiring medical attention

  19. HAZARDOUS MATERIALS INCIDENTS What are hazardous materials?

    E-Print Network [OSTI]

    Fernandez, Eduardo

    HAZARDOUS MATERIALS INCIDENTS What are hazardous materials? Hazardous materials are chemicals I do if there is a small spill in the area and personnel trained in Hazardous Material clean up, or there is a small spill where personnel trained in Hazardous Material clean up or an appropriate spill kit

  20. HAZARDOUS MATERIALS INCIDENTS What are hazardous materials?

    E-Print Network [OSTI]

    Fernandez, Eduardo

    HAZARDOUS MATERIALS INCIDENTS What are hazardous materials? Hazardous materials are chemicals I do if there is a small spill in the area and personnel trained in Hazardous Material clean up spill where personnel trained in Hazardous Material clean up or an appropriate spill kit

  1. Reproductive Hazards in the Lab Reproductive Hazards

    E-Print Network [OSTI]

    de Lijser, Peter

    Reproductive Hazards in the Lab Reproductive Hazards The term reproductive hazard refers to agents healthy children. Reproductive hazards may have harmful effects on libido, sexual behavior, or sperm the effects of reproductive hazards may be reversible for the parent, the effects on the fetus or offspring

  2. HAZARDOUS MATERIALS INCIDENTS What are hazardous materials?

    E-Print Network [OSTI]

    Fernandez, Eduardo

    HAZARDOUS MATERIALS INCIDENTS What are hazardous materials? Hazardous materials are chemicals I do if there is a small spill in the area and personnel trained in Hazardous Material clean up personnel trained in Hazardous Material clean up or an appropriate spill kit is not available? Call 561

  3. The Hydrothermal Chemistry of Gold, Arsenic, Antimony, Mercury and Silver

    SciTech Connect (OSTI)

    Bessinger, Brad; Apps, John A.

    2003-03-23T23:59:59.000Z

    A comprehensive thermodynamic database based on the Helgeson-Kirkham-Flowers (HKF) equation of state was developed for metal complexes in hydrothermal systems. Because this equation of state has been shown to accurately predict standard partial molal thermodynamic properties of aqueous species at elevated temperatures and pressures, this study provides the necessary foundation for future exploration into transport and depositional processes in polymetallic ore deposits. The HKF equation of state parameters for gold, arsenic, antimony, mercury, and silver sulfide and hydroxide complexes were derived from experimental equilibrium constants using nonlinear regression calculations. In order to ensure that the resulting parameters were internally consistent, those experiments utilizing incompatible thermodynamic data were re-speciated prior to regression. Because new experimental studies were used to revise the HKF parameters for H2S0 and HS-1, those metal complexes for which HKF parameters had been previously derived were also updated. It was found that predicted thermodynamic properties of metal complexes are consistent with linear correlations between standard partial molal thermodynamic properties. This result allowed assessment of several complexes for which experimental data necessary to perform regression calculations was limited. Oxygen fugacity-temperature diagrams were calculated to illustrate how thermodynamic data improves our understanding of depositional processes. Predicted thermodynamic properties were used to investigate metal transport in Carlin-type gold deposits. Assuming a linear relationship between temperature and pressure, metals are predicted to predominantly be transported as sulfide complexes at a total aqueous sulfur concentration of 0.05 m. Also, the presence of arsenic and antimony mineral phases in the deposits are shown to restrict mineralization within a limited range of chemical conditions. Finally, at a lesser aqueous sulfur concentration of 0.01 m, host rock sulfidation can explain the origin of arsenic and antimony minerals within the paragenetic sequence.

  4. System for removal of arsenic from water

    DOE Patents [OSTI]

    Moore, Robert C.; Anderson, D. Richard

    2004-11-23T23:59:59.000Z

    Systems for removing arsenic from water by addition of inexpensive and commonly available magnesium oxide, magnesium hydroxide, calcium oxide, or calcium hydroxide to the water. The hydroxide has a strong chemical affinity for arsenic and rapidly adsorbs arsenic, even in the presence of carbonate in the water. Simple and commercially available mechanical systems for removal of magnesium hydroxide particles with adsorbed arsenic from drinking water can be used, including filtration, dissolved air flotation, vortex separation, or centrifugal separation. A system for continuous removal of arsenic from water is provided. Also provided is a system for concentrating arsenic in a water sample to facilitate quantification of arsenic, by means of magnesium or calcium hydroxide adsorption.

  5. HAZARDOUS WASTE [Written Program

    E-Print Network [OSTI]

    Pawlowski, Wojtek

    HAZARDOUS WASTE MANUAL [Written Program] Cornell University [10/7/13 #12;Hazardous Waste Program................................................... 8 3.0 MINIMIZING HAZARDOUS WASTE GENERATION.........................................................10 4.0 HAZARDOUS WASTE GENERATOR REQUIREMENTS.....................................................10

  6. Methyl arsenic adsorption and desorption behavior on iron oxides

    E-Print Network [OSTI]

    Lafferty, Brandon James

    2005-08-29T23:59:59.000Z

    of the widespread distribution and toxicity of arsenic and methyl-arsenic, their adsorption behavior on soil minerals is of great interest. Although considerable attention has been given to the behavior of inorganic arsenic on mineral surfaces, little research has...

  7. arsenic detoxification pump: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    implantation damageon lightly doped phosphorus and arsenic Florida, University of 109 Adsorption of Trace Levels of Arsenic from Aqueous Solutions by Conditioned LDH Computer...

  8. Controls on arsenic mobility in contaminated wetland and riverbed streams

    E-Print Network [OSTI]

    Keon, Nicole E. (Nicole Elise), 1974-

    2002-01-01T23:59:59.000Z

    Arsenic mobility and transport in the environment are strongly influenced by associations with solid phases. This dissertation investigates the mechanisms affecting arsenic retention in contaminated wetland and riverbed ...

  9. arsenic health effects: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Environmental Sciences and Ecology Websites Summary: HealthUC Berkeley, School of Public Health 12;WORLDWIDE ARSENIC EXPOSURE 12;Why Should You Care? 12ARSENIC IN...

  10. arsenic oxides: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    can Sparks, Donald L. 4 Bacteria-Mediated Arsenic Oxidation and Reduction in the Growth Media of Arsenic Hyperaccumulator Pteris vittata Environmental Management and Restoration...

  11. arsenic speciation analysis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and arsenic and phosphate distribution in arsenic hyperaccumulator Pteris vittata L. and Environmental Management and Restoration Websites Summary: is nec- essary to protect both...

  12. arsenic hyperaccumulator pteris: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    OF SOIL AND PLANT ON ARSENIC ACCUMULATION BY ARSENIC HYPERACCUMULATOR Pteris vittata L Environmental Management and Restoration Websites Summary: EFFECTS OF SOIL AND PLANT ON...

  13. arsenic hyperaccumulating fern: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    OF SOIL AND PLANT ON ARSENIC ACCUMULATION BY ARSENIC HYPERACCUMULATOR Pteris vittata L Environmental Management and Restoration Websites Summary: EFFECTS OF SOIL AND PLANT ON...

  14. arsenic selenides: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    OF SOIL AND PLANT ON ARSENIC ACCUMULATION BY ARSENIC HYPERACCUMULATOR Pteris vittata L Environmental Management and Restoration Websites Summary: EFFECTS OF SOIL AND PLANT ON...

  15. arsenic pilot plant: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    OF SOIL AND PLANT ON ARSENIC ACCUMULATION BY ARSENIC HYPERACCUMULATOR Pteris vittata L Environmental Management and Restoration Websites Summary: EFFECTS OF SOIL AND PLANT ON...

  16. What is Hazardous Hazardous waste is

    E-Print Network [OSTI]

    de Lijser, Peter

    What is Hazardous Waste? Hazardous waste is any product charac- terized or labeled as toxic may be harmful to human health and/ or the environment. Hazardous Waste Disposal EH&S x7233 E.calrecycle.ca.gov www.earth911.com Campus Hazardous Waste Roundup Roundups conducted the last week of: January April

  17. Method of arsenic removal from water

    DOE Patents [OSTI]

    Gadgil, Ashok (El Cerrito, CA)

    2010-10-26T23:59:59.000Z

    A method for low-cost arsenic removal from drinking water using chemically prepared bottom ash pre-treated with ferrous sulfate and then sodium hydroxide. Deposits on the surface of particles of bottom ash form of activated iron adsorbent with a high affinity for arsenic. In laboratory tests, a miniscule 5 grams of pre-treated bottom ash was sufficient to remove the arsenic from 2 liters of 2400 ppb (parts per billion) arsenic-laden water to a level below 50 ppb (the present United States Environmental Protection Agency limit). By increasing the amount of pre-treated bottom ash, even lower levels of post-treatment arsenic are expected. It is further expected that this invention supplies a very low-cost solution to arsenic poisoning for large population segments.

  18. Mineralogical characterization of steel industry hazardous waste and refractory sulfide ores for zinc and gold recovery processing

    SciTech Connect (OSTI)

    Hagni, A.M.; Hagni, R.D. (Univ. of Missouri, Rolla, MO (United States). Geology Geophysics Dept.)

    1994-04-01T23:59:59.000Z

    The steel industry generates dust as a waste product from high temperature electric arc furnaces (EAF), which is a major step in processing scrap metal into steel. The Environmental Protection Agency (EPA) has classified EAF dust as KO61 hazardous waste, due to its lead, cadmium, and chromium content. The dust also contains valuable zinc, averaging 19%. Detailed mineralogical characterization show the zinc is present as crystals of franklinite-magnetite-jacobsite solid solutions in calcium-iron-silicate glass spheres and as zincite mostly as very small individual spheres. Much of the chromium is present in an insoluble form in solid solution in the iron spinels. This microscopic research is a valuable tool in determining treatment processes for the 600,000 tons of dust generated annually in the US. Refractory gold ores, pyrite and arsenopyrite, have been studied to determine additional, cost-effective methods of processing. One technique under investigation involves roasting sulfide mineral particles to hematite to create porosity through which a leach can permeate to recover the gold. Portlandite, Ca(OH)[sub 2], is added to the roast for retention of hazardous sulfur and arsenic. Modern microscopic and spectroscopic techniques, such electron spectroscopy for chemical analysis, cathodoluminescence microscopy, and electron microprobe, have been applied, as well as reflected light and dark field microscopy, and scanning electron microscopy to determine the mineralogy of the sulfur, arsenic, and iron phases, and the extent of porosity, permeability, and oxidation state of the ore particles at various roasting temperatures. It is concluded that mineralogical techniques can be effectively applied to the solution of environmental problems.

  19. In-tank recirculating arsenic treatment system

    DOE Patents [OSTI]

    Brady, Patrick V. (Albuquerque, NM); Dwyer, Brian P. (Albuquerque, NM); Krumhansl, James L. (Albuquerque, NM); Chwirka, Joseph D. (Tijeras, NM)

    2009-04-07T23:59:59.000Z

    A low-cost, water treatment system and method for reducing arsenic contamination in small community water storage tanks. Arsenic is removed by using a submersible pump, sitting at the bottom of the tank, which continuously recirculates (at a low flow rate) arsenic-contaminated water through an attached and enclosed filter bed containing arsenic-sorbing media. The pump and treatment column can be either placed inside the tank (In-Tank) by manually-lowering through an access hole, or attached to the outside of the tank (Out-of-Tank), for easy replacement of the sorption media.

  20. Arsenic chemistry in soils and sediments

    E-Print Network [OSTI]

    Fendorf, S.

    2010-01-01T23:59:59.000Z

    retention mechanisms on goethite. 1. Surface structure.ion adsorbed on synthetic goethite (?-FeOOH). Soil Sci. 35:of arsenic(III) on goethite: spectroscopic evidence for

  1. HAZARD COMMUNICATION PROGRAM The______________________________ Department has developed a Hazard Communication

    E-Print Network [OSTI]

    Zhang, Yuanlin

    HAZARD COMMUNICATION PROGRAM The______________________________ Department has developed a Hazard about chemical hazards and other hazardous substances via our comprehensive Hazard Communication Program. The Hazard Communication Program will include: WORKPLACE CHEMICAL LIST MATERIAL SAFETY DATA SHEETS CONTAINER

  2. Ferrihydrite as an Enterosorbent for Arsenic

    E-Print Network [OSTI]

    Taylor, John Floyd

    2012-02-14T23:59:59.000Z

    Arsenic in drinking water is a problem in many developing nations such as Taiwan and Bangladesh. Currently, no oral binding agent exists for the mitigation of arsenic toxicity. The goals of this research were to 1) screen a variety of sorbents...

  3. Arsenic distribution in soils surrounding the Utah copper smelter

    SciTech Connect (OSTI)

    Ball, A.L. (Univ. of Utah Coll. of Engineering, Salt Lake City); Rom, W.N.; Glenne, B.

    1983-05-01T23:59:59.000Z

    We investigated the extent of arsenic contamination from a Utah copper smelter as reflected by arsenic residue accumulated in the surface soil. The highest arsenic concentrations occurred within 3 km of the smelter. Arsenic soil contamination was evident up to 10 km from the smelter, with the major transport direction being ESE. Data from the subsurface soil samples indicated that arsenic has also leached through the soil.

  4. Transporting Hazardous Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transporting Hazardous Materials The procedures given below apply to all materials that are considered to be hazardous by the U.S. Department of Transportation (DOT). Consult your...

  5. Hazard Baseline Documentation

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1995-12-04T23:59:59.000Z

    This standard establishes uniform Office of Environmental Management (EM) guidance on hazard baseline documents that identify and control radiological and non-radiological hazards for all EM facilities.

  6. On mobilization of lead and arsenic in groundwater in response to CO2 leakage from deep geological storage

    SciTech Connect (OSTI)

    Zheng, L.; Apps, J.A.; Zhang, Y.; Xu, T.; Birkholzer, J.T.

    2009-07-01T23:59:59.000Z

    If carbon dioxide stored in deep saline aquifers were to leak into an overlying aquifer containing potable groundwater, the intruding CO{sub 2} would change the geochemical conditions and cause secondary effects mainly induced by changes in pH In particular, hazardous trace elements such as lead and arsenic, which are present in the aquifer host rock, could be mobilized. In an effort to evaluate the potential risks to potable water quality, reactive transport simulations were conducted to evaluate to what extent and mechanisms through which lead and arsenic might be mobilized by intrusion of CO{sub 2}. An earlier geochemical evaluation of more than 38,000 groundwater quality analyses from aquifers throughout the United States and an associated literature review provided the basis for setting up a reactive transport model and examining its sensitivity to model variation. The evaluation included identification of potential mineral hosts containing hazardous trace elements, characterization of the modal bulk mineralogy for an arenaceous aquifer, and augmentation of the required thermodynamic data. The reactive transport simulations suggest that CO{sub 2} ingress into a shallow aquifer can mobilize significant lead and arsenic, contaminating the groundwater near the location of intrusion and further downstream. Although substantial increases in aqueous concentrations are predicted compared to the background values, the maximum permitted concentration for arsenic in drinking water was exceeded in only a few cases, whereas that for lead was never exceeded.

  7. Speciation of Arsenic in An Anaerobic Treatment System at a Pb-Zn Smelter Site, Gold Roaster Products, Cu Smelter Stack Dust And Impacted Soil

    SciTech Connect (OSTI)

    Paktunc, D.

    2009-05-28T23:59:59.000Z

    Mining and metallurgical processing of gold and base metal ores often results in solid wastes and effluents containing high concentrations of arsenic. In addition, arsenic can be released to the atmosphere from gold roasters and base metal smelters. Speciation of arsenic in roaster products, in a stack sample from a copper smelter, in organic soils impacted by smelter emissions, and in an anaerobic effluent treatment system at a smelter site was determined in order to broaden our understanding of the nature and occurrence of arsenic in a wider range of metallurgical wastes. Micro-XANES spectra obtained from iron oxide particles forming in a gold roaster indicate preferential enrichment of As{sup 3+} species in maghemite-rich domains and microlayers. In comparison, haematite-rich iron oxide particles are dominated by As{sup 5+} species. It appears that maghemite is retarding oxidation of arsenic and its volatilisation during roasting. Arsenic occurs as both As{sup 3+} and As{sup 5+} species in a stack sample emitted from a Cu smelter, confined to fine-grained secondary product layers accumulated on the surfaces of spherical Cu particles. This is probably resulting from condensation of As species upon cooling following their volatilisation during the combustion process. Soil samples collected at various distances from the Cu smelter are dominated by As{sup 5+} species including monomethylarsonic acid and tetramethylarsonium iodide as the organic arsenic species. The presence of reduced As{sup 3+} species highlights the importance of organic material influencing the speciation of arsenic and mineralogical transformations taking place within the soil profile. The XANES spectra indicate that arsenic occurs predominantly as aqueous arsenite species in the anaerobic treatment system, contrary to the conventional thinking of As retention by the formation of secondary sulfides.

  8. Speciation of arsenic in an anaerobic treatment system at a Pb-Zn smelter site, gold roaster products, Cu smelter stack dust and impacted soil

    SciTech Connect (OSTI)

    Paktunc, D. (CCM)

    2008-09-30T23:59:59.000Z

    Mining and metallurgical processing of gold and base metal ores often results in solid wastes and effluents containing high concentrations of arsenic. In addition, arsenic can be released to the atmosphere from gold roasters and base metal smelters. Speciation of arsenic in roaster products, in a stack sample from a copper smelter, in organic soils impacted by smelter emissions, and in an anaerobic effluent treatment system at a smelter site was determined in order to broaden our understanding of the nature and occurrence of arsenic in a wider range of metallurgical wastes. Micro-XANES spectra obtained from iron oxide particles forming in a gold roaster indicate preferential enrichment of As{sup 3+} species in maghemite-rich domains and microlayers. In comparison, haematite-rich iron oxide particles are dominated by As{sup 5+} species. It appears that maghemite is retarding oxidation of arsenic and its volatilisation during roasting. Arsenic occurs as both As{sup 3+} and As{sup 5+} species in a stack sample emitted from a Cu smelter, confined to fine-grained secondary product layers accumulated on the surfaces of spherical Cu particles. This is probably resulting from condensation of As species upon cooling following their volatilisation during the combustion process. Soil samples collected at various distances from the Cu smelter are dominated by As{sup 5+} species including monomethylarsonic acid and tetramethylarsonium iodide as the organic arsenic species. The presence of reduced As{sup 3+} species highlights the importance of organic material influencing the speciation of arsenic and mineralogical transformations taking place within the soil profile. The XANES spectra indicate that arsenic occurs predominantly as aqueous arsenite species in the anaerobic treatment system, contrary to the conventional thinking of As retention by the formation of secondary sulfides.

  9. Method and apparatus for reclaiming metal values from electric arc furnace flue dust and sludge and rendering residual solids recyclable or non-hazardous

    SciTech Connect (OSTI)

    Bishop, N.G.; Bottinelli, N.E.; Kotraba, N.L.

    1988-07-19T23:59:59.000Z

    This patent describes an apparatus for treating dust and sludge contaminated with heavy metals and heavy metal oxides, comprising: waste material storage means; a mixer; means communicating with the waste material storage means and the mixer for introducing the waste material, solid carbonaceous material, and an organic binder to the mixer; a pelletizing device; means for introducing material from the mixer into the pelletizing device; pelletizer discharge means; an inclined rotary reduction smelter vessel having a charging and pouring opening in one end thereof; means for introducing pellets from the pelletizer discharge means to the rotary reduction smelter vessel; retractable burner means for heating the interior of the smelter vessel; means for rotating the smelter vessel about its inclined axis; and means for tilting the smelter vessel about a horizontal axis.

  10. Metal articles having ultrafine particles dispersed therein

    SciTech Connect (OSTI)

    Alexander, G.B.; Nadkarni, R.A.

    1992-07-28T23:59:59.000Z

    This patent describes a metal article of manufacture. It comprises: a metal selected from the group consisting of copper, silver, gold, lead, tin, nickel, zinc, cobalt, antimony, bismuth, iron, cadmium, chromium, germanium, gallium, selenium, tellurium, mercury, tungsten arsenic, manganese, iridium, indium, ruthenium, rhenium, rhodium, molybdenum, palladium, osmium and platinum; and a plurality of ultrafine particles.

  11. HAZARDOUS MATERIALS EMERGENCY RESPONSE

    E-Print Network [OSTI]

    ANNEX Q HAZARDOUS MATERIALS EMERGENCY RESPONSE #12;ANNEX Q - HAZARDOUS MATERIALS EMERGENCY RESPONSE 03/10/2014 v.2.0 Page Q-1 PROMULGATION STATEMENT Annex Q: Hazardous Materials Emergency Response, and contents within, is a guide to how the University conducts a response specific to a hazardous materials

  12. Track 3: Exposure Hazards

    Broader source: Energy.gov [DOE]

    ISM Workshop Presentations Knoxville Convention Center, Knoxville, TN August 2009 Track 3: Exposure Hazards

  13. ARSENIC HYPERACCUMULATION BY Pteris vittata L. AND ITS POTENTIAL FOR PHYTOREMEDIATION OF ARSENIC-CONTAMINATED SOILS

    E-Print Network [OSTI]

    Ma, Lena

    needed assistance in harvesting ferns and soil sampling. I also wish to thank the past and present ...............................................................................................8 Arsenic in Water.................

  14. Electrochemical arsenic remediation for rural Bangladesh

    SciTech Connect (OSTI)

    Addy, Susan Amrose

    2009-01-01T23:59:59.000Z

    Arsenic in drinking water is a major public health problem threatening the lives of over 140 million people worldwide. In Bangladesh alone, up to 57 million people drink arsenic-laden water from shallow wells. ElectroChemical Arsenic Remediation(ECAR) overcomes many of the obstacles that plague current technologies and can be used affordably and on a small-scale, allowing for rapid dissemination into Bangladesh to address this arsenic crisis. In this work, ECAR was shown to effectively reduce 550 - 580 mu g=L arsenic (including both As[III]and As[V]in a 1:1 ratio) to below the WHO recommended maximum limit of 10 mu g=L in synthetic Bangladesh groundwater containing relevant concentrations of competitive ions such as phosphate, silicate, and bicarbonate. Arsenic removal capacity was found to be approximately constant within certain ranges of current density, but was found to change substantially between ranges. In order of decreasing arsenic removal capacity, the pattern was: 0.02 mA=cm2> 0.07 mA=cm2> 0.30 - 1.1 mA=cm2> 5.0 - 100 mA=cm2. Current processing time was found to effect arsenic removal capacity independent of either charge density or current density. Electrode polarization studies showed no passivation of the electrode in the tested range (up to current density 10 mA=cm2) and ruled out oxygen evolution as the cause of decreasing removal capacity with current density. Simple settling and decantation required approximately 3 days to achieve arsenic removal comparable to filtration with a 0.1 mu m membrane. X-ray Absorption Spectroscopy (XAS) showed that (1) there is no significant difference in the arsenic removal mechanism of ECAR during operation at different current densities and (2) the arsenic removal mechanism in ECAR is consistent with arsenate adsorption onto a homogenous Fe(III)oxyhydroxide similar in structure to 2-line ferrihydrite. ECAR effectively reduced high arsenic concentrations (100 - 500 mu g=L) in real Bangladesh tube well water collected from three regions to below the WHO limit of 10 mu g=L. Prototype fabrication and field testing are currently underway.

  15. Hazardous constituent source term. Revision 2

    SciTech Connect (OSTI)

    Not Available

    1994-11-17T23:59:59.000Z

    The Department of Energy (DOE) has several facilities that either generate and/or store transuranic (TRU)-waste from weapons program research and production. Much of this waste also contains hazardous waste constituents as regulated under Subtitle C of the Resource Conservation and Recovery Act (RCRA). Toxicity characteristic metals in the waste principally include lead, occurring in leaded rubber gloves and shielding. Other RCRA metals may occur as contaminants in pyrochemical salt, soil, debris, and sludge and solidified liquids, as well as in equipment resulting from decontamination and decommissioning activities. Volatile organic compounds (VOCS) contaminate many waste forms as a residue adsorbed on surfaces or occur in sludge and solidified liquids. Due to the presence of these hazardous constituents, applicable disposal regulations include land disposal restrictions established by Hazardous and Solid Waste Amendments (HSWA). The DOE plans to dispose of TRU-mixed waste from the weapons program in the Waste Isolation Pilot Plant (WIPP) by demonstrating no-migration of hazardous constituents. This paper documents the current technical basis for methodologies proposed to develop a post-closure RCRA hazardous constituent source term. For the purposes of demonstrating no-migration, the hazardous constituent source term is defined as the quantities of hazardous constituents that are available for transport after repository closure. Development of the source term is only one of several activities that will be involved in the no-migration demonstration. The demonstration will also include uncertainty and sensitivity analyses of contaminant transport.

  16. Urinary arsenic profile affects the risk of urothelial carcinoma even at low arsenic exposure

    SciTech Connect (OSTI)

    Pu, Y.-S. [Department of Urology, National Taiwan University College of Medicine, Taipei, Taiwan (China); Yang, S.-M. [Graduate Institute of Public Health, Taipei Medical University, Taipei, Taiwan (China); Huang, Y.-K. [Graduate Institute of Medical Sciences, Taipei Medical University, Taipei, Taiwan (China); Chung, C.-J. [Graduate Institute of Public Health, Taipei Medical University, Taipei, Taiwan (China); Huang, Steven K. [Graduate Institute of Medical Sciences, Taipei Medical University, Taipei, Taiwan (China); Department of Urology, Chi-Mei Medical Center, Tainan, Taiwan (China); Chiu, Allen Wen-Hsiang [Department of Urology, Chi-Mei Medical Center, Tainan, Taiwan (China); Department of Urology, Taipei City Hospital, Taipei, Taiwan (China); Yang, M.-H. [Department of Nuclear Science, National Tsing-Hua University, Hsinchu, Taiwan (China); Chen, C.-J. [Graduate Institute of Epidemiology, College of Public Health, National Taiwan University, Taipei, Taiwan (China); Hsueh, Y.-M. [Department of Public Health, School of Medicine, Taipei Medical University, Taipei, No. 250 Wu-Hsing Street, Taipei 110, Taiwan (China)]. E-mail: ymhsueh@tmu.edu.tw

    2007-01-15T23:59:59.000Z

    Arsenic exposure is associated with an increased risk of urothelial carcinoma (UC). To explore the association between individual risk and urinary arsenic profile in subjects without evident exposure, 177 UC cases and 313 age-matched controls were recruited between September 2002 and May 2004 for a case-control study. Urinary arsenic species including the following three categories, inorganic arsenic (As{sup III} + As{sup V}), monomethylarsonic acid (MMA{sup V}) and dimethylarsinic acid (DMA{sup V}), were determined with high-performance liquid chromatography-linked hydride generator and atomic absorption spectrometry. Arsenic methylation profile was assessed by percentages of various arsenic species in the sum of the three categories measured. The primary methylation index (PMI) was defined as the ratio between MMA{sup V} and inorganic arsenic. Secondary methylation index (SMI) was determined as the ratio between DMA{sup V} and MMA{sup V}. Smoking is associated with a significant risk of UC in a dose-dependent manner. After multivariate adjustment, UC cases had a significantly higher sum of all the urinary species measured, higher percent MMA{sup V}, lower percent DMA{sup V}, higher PMI and lower SMI values compared with controls. Smoking interacts with the urinary arsenic profile in modifying the UC risk. Differential carcinogenic effects of the urinary arsenic profile, however, were seen more prominently in non-smokers than in smokers, suggesting that smoking is not the only major environmental source of arsenic contamination since the UC risk differs in non-smokers. Subjects who have an unfavorable urinary arsenic profile have an increased UC risk even at low exposure levels.

  17. Toxicology 225 (2006) 225233 Blood arsenic as a biomarker of arsenic exposure

    E-Print Network [OSTI]

    van Geen, Alexander

    2006-01-01T23:59:59.000Z

    Toxicology 225 (2006) 225­233 Blood arsenic as a biomarker of arsenic exposure: Results from examined urinary As (UAs) (adjusted for urinary creatinine), hair or toenail As, but not blood As (BAs) since blood concentrations are exceedingly low and are not detectable by conventional atomic absorption

  18. Arsenic removal from gaseous streams

    SciTech Connect (OSTI)

    Russell, R.G.; Otey, M.G.

    1989-11-22T23:59:59.000Z

    Uranium feed materials, depending on the production process, have been found to contain arsenic (As) as a contaminant. Analyses show the As to be present as As pentafluoride (AsF{sub 5}) and/or hexafluoroarsenic acid (HAsF{sub 6}) and enter the enrichment cycle through contaminated hydrogen fluoride (HF). Problems related to corrosion of cylinder valves and plugging of feed lines and valves have been attributed to the As. Techniques to separate AsF{sub 5} from uranium hexafluoride (UF{sub 6}) using sodium fluoride (NaF) as a trapping media were successful and will be discussed. Procedures to significantly reduce (up to 97%) the level of As in HF will also be reported. 5 figs., 9 tabs.

  19. Georgia Hazardous Waste Management Act

    Broader source: Energy.gov [DOE]

    The Georgia Hazardous Waste Management Act (HWMA) describes a comprehensive, Statewide program to manage hazardous wastes through regulating hazardous waste generation, transportation, storage,...

  20. Factors influencing the efficiency of arsenic extraction by phosphate 

    E-Print Network [OSTI]

    Yean, Su Jin

    2005-11-01T23:59:59.000Z

    Extraction with sodium phosphate has been used as a method of accessing arsenic in soils. Arsenic extraction efficiency by phosphate from rice-paddy soils of Bangladesh usually has been low and highly variable between ...

  1. High-field As NMR Study of Arsenic Oxysalts. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    environment is wide-spread due to the historical use of arsenic-bearing chemicals in agriculture and industry as well as the occurrence of natural and anthropogenic arsenic-rich...

  2. In Situ Iron Oxide Emplacement for Groundwater Arsenic Remediation

    E-Print Network [OSTI]

    Abia, Thomas Sunday

    2012-02-14T23:59:59.000Z

    for additional arsenic removal. Several bench-scale experiments revealed that the resultant IOCS could treat arsenic-laden groundwater for extended periods of time before approaching its effective life cycle. The adsorption capacity for As(III) and As...

  3. Outcomes of Chronic Arsenic Exposure on Aquatic Insects

    E-Print Network [OSTI]

    Mogren, Christina Loraine

    2013-01-01T23:59:59.000Z

    sp. from an old arsenic smelter site. Applied Organometallicants from an old arsenic smelter site, Kuehnelt et al. (and a long history of smelters releasing copper as an air

  4. Hazardous Waste Management (Arkansas)

    Broader source: Energy.gov [DOE]

    The Hazardous Waste Program is carried out by the Arkansas Department of Environmental Quality which administers its' program under the Hazardous Waste management Act (Arkansas Code Annotated 8-7...

  5. Hazardous Waste Management (Delaware)

    Broader source: Energy.gov [DOE]

    The act authorizes the Delaware Department of Natural Resources and Environment Control (DNREC) to regulate hazardous waste and create a program to manage sources of hazardous waste. The act...

  6. Solid materials for removing arsenic and method thereof

    SciTech Connect (OSTI)

    Coronado, Paul R. (Livermore, CA); Coleman, Sabre J. (Oakland, CA); Sanner, Robert D. (Livermore, CA); Dias, Victoria L. (Livermore, CA); Reynolds, John G. (San Ramon, CA)

    2010-09-28T23:59:59.000Z

    Solid materials have been developed to remove arsenic compounds from aqueous media. The arsenic is removed by passing the aqueous phase through the solid materials which can be in molded, granular, or powder form. The solid materials adsorb the arsenic leaving a purified aqueous stream. The materials are aerogels or xerogels and aerogels or xerogels and solid support structure, e.g., granulated activated carbon (GAC), mixtures. The species-specific adsorption occurs through specific chemical modifications of the solids tailored towards arsenic.

  7. Solid materials for removing arsenic and method thereof

    DOE Patents [OSTI]

    Coronado, Paul R. (Livermore, CA); Coleman, Sabre J. (Oakland, CA); Sanner, Robert D. (Livermore, CA); Dias, Victoria L. (Livermore, CA); Reynolds, John G. (San Ramon, CA)

    2008-07-01T23:59:59.000Z

    Solid materials have been developed to remove arsenic compounds from aqueous media. The arsenic is removed by passing the aqueous phase through the solid materials which can be in molded, granular, or powder form. The solid materials adsorb the arsenic leaving a purified aqueous stream. The materials are aerogels or xerogels and aerogels or xerogels and solid support structure, e.g., granulated activated carbon (GAC), mixtures. The species-specific adsorption occurs through specific chemical modifications of the solids tailored towards arsenic.

  8. Hazard Analysis Database report

    SciTech Connect (OSTI)

    Niemi, B.J.

    1997-08-12T23:59:59.000Z

    This document describes and defines the Hazard Analysis Database for the Tank Waste Remediation System Final Safety Analysis Report.

  9. Hazard analysis results report

    SciTech Connect (OSTI)

    Niemi, B.J., Westinghouse Hanford

    1996-09-30T23:59:59.000Z

    This document describes and defines the Hazard Analysis Results for the Tank Waste Remediation System Final Safety Analysis Report.

  10. HAZARDOUS WASTE MANAGEMENT REFERENCE

    E-Print Network [OSTI]

    Faraon, Andrei

    Principal Investigators 7 Laboratory Personnel 8 EH&S Personnel 8 HAZARDOUS WASTE ACCUMULATION AREAS 9 Satellite Accumulation Area 9 Waste Accumulation Facility 10 HAZARDOUS WASTE CONTAINER MANAGEMENT LabelingHAZARDOUS WASTE MANAGEMENT REFERENCE GUIDE Prepared by Environment, Health and Safety Office

  11. WEATHER HAZARDS Basic Climatology

    E-Print Network [OSTI]

    Prediction Center (SPC) Watch Atmospheric conditions are right for hazardous weather ­ hazardous weather is likely to occur Issued by SPC Warning Hazardous weather is either imminent or occurring Issued by local NWS office #12;Outlooks--SPC Storm Prediction Center (SPC) Outlook=Convective Outlook Day 1 Day 2

  12. Hazardous Waste Management Training

    E-Print Network [OSTI]

    Dai, Pengcheng

    records. The initial training of Hazardous Waste Management and Waste Minimization is done in a classHazardous Waste Management Training Persons (including faculty, staff and students) working before handling hazardous waste. Departments are re- quired to keep records of training for as long

  13. Microbial Mobilization of Arsenic from Sediments of the Aberjona

    E-Print Network [OSTI]

    Morel, François M. M.

    Microbial Mobilization of Arsenic from Sediments of the Aberjona Watershed D I A N N E A H M A N N, University of Massachusetts, Amherst, Massachusetts 01003 Arsenic mobilization from aquatic sediments to this transport, mobilization of solid-phase arsenic was investigated in upper Aberjona sediment microcosms

  14. A Chemical Stain for Identifying Arsenic-Treated Wood

    E-Print Network [OSTI]

    Florida, University of

    A Chemical Stain for Identifying Arsenic-Treated Wood (FINAL) Submitted June 23, 2006 Amy Omae.2 Motivation 4 I.3 Objectives 5 CHAPTER II, DEVELOPMENT OF A CHEMICAL STAIN FOR IDENTIFYING ARSENIC-TREATED Applications 22 II.5 Resulting Stain to Identify Arsenic-Treated Wood and Methods of Testing 25 CHAPTER III

  15. ORIGINAL PAPER Fractionation and speciation of arsenic in fresh

    E-Print Network [OSTI]

    Hu, Qinhong "Max"

    , such as coal-mining activities, and to understand the fate of arsenic following environmen- tal releaseORIGINAL PAPER Fractionation and speciation of arsenic in fresh and combusted coal wastes from, the content and speciation of arsenic in coal waste and gas condensates from coal waste fires were

  16. Arsenic (+ 3 oxidation state) methyltransferase genotype affects steady-state distribution and clearance of arsenic in arsenate-treated mice

    SciTech Connect (OSTI)

    Hughes, Michael F.; Edwards, Brenda C.; Herbin-Davis, Karen M. [Pharmacokinetics Branch, Integrated Systems Toxicology Division, National Health and Environmental Effects Research Laboratory, Office of Research and Development, US Environmental Protection Agency, Research Triangle Park, NC 27711 (United States); Saunders, Jesse; Styblo, Miroslav [Department of Nutrition, University of North Carolina at Chapel Hill, Chapel Hill, NC 27599 (United States); Thomas, David J., E-mail: thomas.david@epa.gov [Pharmacokinetics Branch, Integrated Systems Toxicology Division, National Health and Environmental Effects Research Laboratory, Office of Research and Development, US Environmental Protection Agency, Research Triangle Park, NC 27711 (United States)

    2010-12-15T23:59:59.000Z

    Arsenic (+ 3 oxidation state) methyltransferase (As3mt) catalyzes formation of mono-, di-, and tri-methylated metabolites of inorganic arsenic. Distribution and retention of arsenic were compared in adult female As3mt knockout mice and wild-type C57BL/6 mice using a regimen in which mice received daily oral doses of 0.5 mg of arsenic as arsenate per kilogram of body weight. Regardless of genotype, arsenic body burdens attained steady state after 10 daily doses. At steady state, arsenic body burdens in As3mt knockout mice were 16 to 20 times greater than in wild-type mice. During the post dosing clearance period, arsenic body burdens declined in As3mt knockout mice to {approx} 35% and in wild-type mice to {approx} 10% of steady-state levels. Urinary concentration of arsenic was significantly lower in As3mt knockout mice than in wild-type mice. At steady state, As3mt knockout mice had significantly higher fractions of the body burden of arsenic in liver, kidney, and urinary bladder than did wild-type mice. These organs and lung had significantly higher arsenic concentrations than did corresponding organs from wild-type mice. Inorganic arsenic was the predominant species in tissues of As3mt knockout mice; tissues from wild-type mice contained mixtures of inorganic arsenic and its methylated metabolites. Diminished capacity for arsenic methylation in As3mt knockout mice prolongs retention of inorganic arsenic in tissues and affects whole body clearance of arsenic. Altered retention and tissue tropism of arsenic in As3mt knockout mice could affect the toxic or carcinogenic effects associated with exposure to this metalloid or its methylated metabolites.

  17. Hazard Analysis Database Report

    SciTech Connect (OSTI)

    GRAMS, W.H.

    2000-12-28T23:59:59.000Z

    The Hazard Analysis Database was developed in conjunction with the hazard analysis activities conducted in accordance with DOE-STD-3009-94, Preparation Guide for U S . Department of Energy Nonreactor Nuclear Facility Safety Analysis Reports, for HNF-SD-WM-SAR-067, Tank Farms Final Safety Analysis Report (FSAR). The FSAR is part of the approved Authorization Basis (AB) for the River Protection Project (RPP). This document describes, identifies, and defines the contents and structure of the Tank Farms FSAR Hazard Analysis Database and documents the configuration control changes made to the database. The Hazard Analysis Database contains the collection of information generated during the initial hazard evaluations and the subsequent hazard and accident analysis activities. The Hazard Analysis Database supports the preparation of Chapters 3 ,4 , and 5 of the Tank Farms FSAR and the Unreviewed Safety Question (USQ) process and consists of two major, interrelated data sets: (1) Hazard Analysis Database: Data from the results of the hazard evaluations, and (2) Hazard Topography Database: Data from the system familiarization and hazard identification.

  18. Hazardous Materials and Controlled Hazardous Substances (Maryland)

    Broader source: Energy.gov [DOE]

    A permit is required to own, establish, operate, or maintain a facility in the state of Maryland that transfers quantities of a single hazardous material in excess of 100,000 pounds at any time...

  19. Hazard baseline documentation

    SciTech Connect (OSTI)

    Not Available

    1994-08-01T23:59:59.000Z

    This DOE limited technical standard establishes uniform Office of Environmental Management (EM) guidance on hazards baseline documents that identify and control radiological and nonradiological hazards for all EM facilities. It provides a road map to the safety and health hazard identification and control requirements contained in the Department`s orders and provides EM guidance on the applicability and integration of these requirements. This includes a definition of four classes of facilities (nuclear, non-nuclear, radiological, and other industrial); the thresholds for facility hazard classification; and applicable safety and health hazard identification, controls, and documentation. The standard applies to the classification, development, review, and approval of hazard identification and control documentation for EM facilities.

  20. Surveillance Guides - Hazards Control

    Broader source: Energy.gov (indexed) [DOE]

    Facility Representative RL Facility Representative Program March 9, 1995 Surveillance Guide Revision 0 Hazard Controls Page 5 of Error Bookmark not defined....

  1. Hazardous Wastes Management (Alabama)

    Broader source: Energy.gov [DOE]

    This legislation gives regulatory authority to the Department of Environmental Management to monitor commercial sites for hazardous wastes; fees on waste received at such sites; hearings and...

  2. Safety Hazards of Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Safety Hazards of Batteries Battery technology is at the heart of much of our technological revolution. One of the most prevalent rechargeable batteries in use today is the...

  3. Radiation Hazards Program (Minnesota)

    Broader source: Energy.gov [DOE]

    These regulations, promulgated by the Department of Health, set allowable radiation standards and mitigation practices, as well as procedures for the transportation of hazardous material.

  4. Hazardous Material Security (Maryland)

    Broader source: Energy.gov [DOE]

    All facilities processing, storing, managing, or transporting hazardous materials must be evaluated every five years for security issues. A report must be submitted to the Department of the...

  5. HAZARDOUS MATERIALS Hazardous materials can be silent killers.

    E-Print Network [OSTI]

    Shinozuka, Masanobu

    HAZARDOUS MATERIALS #12;Hazardous materials can be silent killers. Almost every household they may be found, and what to do, or not do, about hazardous material spills. #12;Ways that hazardous or eyes · Ingestion; swallowing · Injection; penetrating skin #12;The key to dealing with hazardous

  6. Chapter 1 -Hazard Communication Hazard Communication and Training Act

    E-Print Network [OSTI]

    and Training Act require employers to inform workers about hazardous chemicals in their work areas13 Chapter 1 - Hazard Communication Hazard Communication and Training Act The Hazard Communication and Safety (EH&S) to administer a program to comply with this law. Hazardous Chemicals Index EH&S maintains

  7. Hazard Classification for Fuel Supply Shutdown Facility

    SciTech Connect (OSTI)

    BENECKE, M.W.

    2000-09-07T23:59:59.000Z

    Final hazard classification for the 300 Area N Reactor fuel storage facility resulted in the assignment of Nuclear Facility Hazard Category 3 for the uranium metal fuel and feed material storage buildings (303-A, 303-B, 303-G, 3712, and 3716). Radiological for the residual uranium and thorium oxide storage building and an empty former fuel storage building that may be used for limited radioactive material storage in the future (303-K/3707-G, and 303-E), and Industrial for the remainder of the Fuel Supply Shutdown buildings (303-F/311 Tank Farm, 303-M, 313-S, 333, 334 and Tank Farm, 334-A, and MO-052).

  8. E-Print Network 3.0 - acute arsenic exposure Sample Search Results

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    chloride 100-44-7) and benzoyl chloride 98-88-4 (combined exposures) IARC-2A Acrolein Acutely... OSHAReproToxin Arsenic 7440-38-2 and arsenic compounds IARC-1 Arsenic...

  9. The modeling of arsenic removal from contaminated water using coagulation and sorption

    E-Print Network [OSTI]

    Kim, Jin-Wook

    2005-11-01T23:59:59.000Z

    To achieve predictive capability for complex environmental systems with coagulation and arsenic sorption, a unified improved coagulation model coupled with arsenic sorption was developed. A unified coagulation model coupled with arsenic sorption...

  10. Stabilization solutions to hazardous metals laden waste

    SciTech Connect (OSTI)

    Kramer, M. [Ashland Chemical Co., Boonton, NJ (United States)

    1996-12-31T23:59:59.000Z

    This paper is limited to treatment of bottom and fly ash waste resulting from WTE and RTE Cogeneration plants, commonly known as trash burners. The body of the paper defines waste generation and conventional treatment schemes. This paper does not identify a best treatment, however, it does offer a general perspective of the treatments to lead the reader to further investigation. Advantages and disadvantages of the ash treatments is discussed in each treatment section. 29 refs., 1 fig.

  11. GEOC Andrew Stack Thursday, March 20, 2014 152 Kinetics of arsenic oxidation by manganese oxide minerals: The influence of origin and structure on reactivity

    E-Print Network [OSTI]

    Sparks, Donald L.

    minerals: The influence of origin and structure on reactivity Jason S. Fischel1, fischelj@udel.edu, Matthew. Their highly reactive surfaces allow manganese minerals to oxidize trace metals such as arsenic from the mobile of manganese minerals found in natural systems. Five Manganese oxide minerals manganese oxide (HMO), hexagonal

  12. Hazard Communication at Purdue University

    E-Print Network [OSTI]

    Holland, Jeffrey

    Hazard Communication at Purdue University Radiological and Environmental Management Written APPENDICES A OSHA Health Hazard Definitions B OSHA Method Of Hazard Determination C Expanded List Completed Work Area Forms HCP-4, HCP-5, HCP-8 I Health Hazard Warning Information 1. Health Hazard Rating 2

  13. DECHEM: A remedial planning tool for metallic contaminants in soil at UMTRA Project sites

    SciTech Connect (OSTI)

    Not Available

    1989-03-01T23:59:59.000Z

    The DECHEM (DEcontamination of CHEMicals) method was developed for the Uranium Mill Tailings Remedial Action (UMTRA) Project to guide characterization and remedial planning for metals contamination in soils. This is necessary because non-radiological hazardous constituents may be more mobile than radium-226 (Ra-226), and hence may migrate more deeply into subpile soils (beneath tailings that are to be relocated) or into adjacent contaminated soils at UMTRA Project sites. The result is that remedial action to the Ra-226 excavation limit, as specified in the US Environmental Protection Agency (EPA) standards, may not adequately remove hazardous non-radiological contamination. Unmitigated, these contaminants in soil may cause health risks because of their presence in resuspended particles, their uptake by crops or fodder their seepage into aquifers used for drinking water or other possible exposure pathways. The DECHEM method was developed in response to the need for advanced planning for the remediation of chemical contaminants at UMTRA Project sites, and includes the following elements: Establishment of acceptable exposure rates for humans to chemicals, based on EPA guidelines or other toxicological literature. Modeling of chemical migration through environmental pathways from a remediated UMTRA Project site to humans. Determination of allowable residual concentrations (i.e., cleanup guidelines) for chemicals in soils that results in doses to humans that are below established acceptable exposure rates. The initial development and application of the DECHEM method has focused upon hazardous metallic contaminants such as arsenic, lead, molybdenum, and selenium, which are known to occur in elevated concentrations at some UMTRA Project sites.

  14. Organic and inorganic hazardous waste stabilization using combusted oil shale

    SciTech Connect (OSTI)

    Sorini, S.S.; Lane, D.C.

    1991-04-01T23:59:59.000Z

    A laboratory study was conducted at the Western Research Institute to evaluate the ability of combusted oil shale to stabilize organic and inorganic constituents of hazardous wastes. The oil shale used in the research was a western oil shale retorted in an inclined fluidized-bed reactor. Two combustion temperatures were used, 1550{degrees}F and 1620{degrees}F (843{degrees}C and 882{degrees}C). The five wastes selected for experimentation were an API separator sludge, creosote-contaminated soil, mixed metal oxide/hydroxide waste, metal-plating sludge, and smelter dust. The API separator sludge and creosote-contaminated soil are US EPA-listed hazardous wastes and contain organic contaminants. The mixed metal oxide/hydroxide waste, metal-plating sludge (also an EPA-listed waste), and smelter dust contain high concentrations of heavy metals. The smelter dust and mixed metal oxide/hydroxide waste fail the Toxicity Characteristic Leaching Procedure (TCLP) for cadmium, and the metalplating sludge fails the TCLP for chromium. To evaluate the ability of the combusted oil shales to stabilize the hazardous wastes, mixtures involving varying amounts of each of the shales with each of the hazardous wastes were prepared, allowed to equilibrate, and then leached with deionized, distilled water. The leachates were analyzed for the hazardous constituent(s) of interest.

  15. The intricacies of UGT regulation : protein-protein interactions and environmental arsenic exposure

    E-Print Network [OSTI]

    Konopnicki, Camille Maria

    2012-01-01T23:59:59.000Z

    M, Cebrian ME and Ostrosky-Wegman P (2007) Arsenic-inducedM, Cebrian ME and Ostrosky-Wegman P (2007) Arsenic-induced

  16. Liquid metal ion source and alloy for ion emission of multiple ionic species

    DOE Patents [OSTI]

    Clark, Jr., William M. (Thousand Oaks, CA); Utlaut, Mark W. (Saugus, CA); Wysocki, Joseph A. (Oxnard, CA); Storms, Edmund K. (Los Alamos, NM); Szklarz, Eugene G. (Los Alamos, NM); Behrens, Robert G. (Los Alamos, NM); Swanson, Lynwood W. (McMinnville, OR); Bell, Anthony E. (McMinnville, OR)

    1987-06-02T23:59:59.000Z

    A liquid metal ion source and alloy for the simultaneous ion evaporation of arsenic and boron, arsenic and phosphorus, or arsenic, boron and phosphorus. The ionic species to be evaporated are contained in palladium-arsenic-boron and palladium-arsenic-boron-phosphorus alloys. The ion source, including an emitter means such as a needle emitter and a source means such as U-shaped heater element, is preferably constructed of rhenium and tungsten, both of which are readily fabricated. The ion sources emit continuous beams of ions having sufficiently high currents of the desired species to be useful in ion implantation of semiconductor wafers for preparing integrated circuit devices. The sources are stable in operation, experience little corrosion during operation, and have long operating lifetimes.

  17. Metabolites of arsenic and increased DNA damage of p53 gene in arsenic plant workers

    SciTech Connect (OSTI)

    Wen Weihua, E-mail: Dongsijiehua@sina.com [Department of Occupational Health, Yunnan Provincial Center for Disease Control and Prevention, No. 158, Dongsi Street, Kunming, Yunnan, 650022 (China); Public Health College, Huazhong University of Science and Technology, No. 13, Hangkong Road, Wuhan City, Hubei, 430030 (China); Wen Jinghua [Guizhou College of Finance and Economics, No. 276, Chongguan Road, Guiyang, Guizhou, 550004 (China); Lu Lin [Department of Occupational Health, Yunnan Provincial Center for Disease Control and Prevention, No. 158, Dongsi Street, Kunming, Yunnan, 650022 (China); Liu Hua [The First Affiliated Hospital of Kunming Medical College, No. 295 Xichang Road, Kunming, Yunnan, 650032 (China); Yang Jun; Cheng Huirong [Department of Occupational Health, Yunnan Provincial Center for Disease Control and Prevention, No. 158, Dongsi Street, Kunming, Yunnan, 650022 (China); Che Wangjun [The First Division of Public Health, Kunming Center for Disease Control and Prevention, No. 4, Ziyun Road, Xishan District, Kunming, Yunnan 650228 (China); Li Liang [Honghe Zhou Center for Disease Control and Prevention, No. 1, Guannan Road, Mengzi City, Yunnan, 661100 (China); Zhang Guanbei [Yunnan Institute for Drug Abuse, Kunming, 650028 (China)

    2011-07-01T23:59:59.000Z

    Recent studies have shown that monomethylarsonous acid is more cytotoxic and genotoxic than arsenate and arsenite, which may attribute to the increased levels of reactive oxygen species. In this study, we used hydride generation-atomic absorption spectrometry to determine three arsenic species in urine of workers who had been working in arsenic plants,and calculated primary and secondary methylation indexes. The damages of exon 5, 6, 8 of p53 gene were determined by the method developed by Sikorsky, et al. Results show that the concentrations of each urinary arsenic species,and damage indexes of exon 5 and 8 of p53 gene in the exposed population were significantly higher, but SMI was significantly lower than in the control group. The closely positive correlation between the damage index of exon 5 and PMI,MMA, DMA were found, but there was closely negative correlation between the damage index of exon 5 and SMI. Those findings suggested that DNA damage of exon 5 and 8 of p53 gene existed in the population occupationally exposed to arsenic. For exon 5, the important factors may include the model of arsenic metabolic transformation, the concentrations of MMA and DMA, and the MMA may be of great importance. - Research Highlights: > In our study, the mean SMI for workers came from arsenic plants is 4.06, so they may be in danger. > There are more MMA, there are more damage of exon 5 of p53 gene. > MMA and damage of exon 5 of p53 gene may be useful biomarkers to assess adverse health effects caused by arsenic.

  18. QUANTIFICATION OF POTENTIAL ARSENIC BIOAVAILABILITY IN SPATIALLY VARYING GEOLOGIC ENVIRONMENTS AT THE WATERSHED SCALE USING CHELATING RESINS

    E-Print Network [OSTI]

    LAKE, GRACIELA ESTHER

    as an evaluation process of potential ecological effects that may occur or may be occurring due to exposure to stressors (Gregorich et al., 2001). Stressors can be a result of natural geologic processes and/or, most often, results of anthropogenic activities... to be weathered and eroded, or erosion of undisturbed sediments containing metals such as arsenic, 9 sulfur, or iron. These eroded sediments can then be transported by wind, subjected to runoff, and/or anthropogenically relocated to areas of harsh...

  19. Removal of arsenic, vanadium and/or nickel compounds from spent catecholated polymer

    DOE Patents [OSTI]

    Fish, R.H.

    1987-04-21T23:59:59.000Z

    Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20 to 100 C with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

  20. Removal of arsenic, vanadium, and/or nickel compounds from petroliferous liquids

    DOE Patents [OSTI]

    Fish, R.H.

    1985-05-17T23:59:59.000Z

    Described is a process for removing arsenic, vanadium, and/or nickel from petroliferous derived liquids (shale oil, SRC, etc.) by contacting said liquid at an elevated temperature with a divinylbenzene-crosslinked polystyrene having catechol ligands anchored thereon. For vanadium and nickel removal an amine, preferably a diamine is included. Also, described is a process for regenerating spent catecholated polystyrene by removal of the arsenic, vanadium, and/or nickel bound to it from contacting petroliferous liquid as described above and involves: treating the spent polymer containing any vanadium and/or nickel with an aqueous acid to achieve an acid pH; and, separating the solids from the liquid; and then treating said spent catecholated polystyrene, at a temperature in the range of about 20/sup 0/ to 100/sup 0/C with an aqueous solution of at least one carbonate and/or bicarbonate of ammonium, alkali and alkaline earth metals, said solution having a pH between about 8 and 10; and, separating the solids and liquids from each other. Preferably the regeneration treatment of arsenic containing catecholated polymer is in two steps wherein the first step is carried out with an aqueous alcoholic carbonate solution containing lower alkyl alcohol, and, the steps are repeated using a bicarbonate.

  1. Geochemistry of arsenic and antimony in Galveston Bay, Texas

    E-Print Network [OSTI]

    Tripp, Anthony Roy

    1988-01-01T23:59:59.000Z

    as no concentration change in dissolved arsenic or antimony was measured due to adsorption or desorption when river water high in SPM and sea water were mixed over a time period of 72 hours. Though the bulk chemical character of the bayous of Galveston Island.... . . . . . . . . . . . . . . Dissolved arsenic profile for mixing experiment using Brazos River Water. . Data for dissolved arsenic and antimony from mixing experiments using Atchafalaya River Water. . . . . . . . . . . . . . . . . . . . . 54 57 58 59 29. Results of adsorption...

  2. Comparative alternative materials assessment to screen toxicity hazards in the life cycle of CIGS thin film photovoltaics

    E-Print Network [OSTI]

    Eisenberg, DA; Yu, M; Lam, CW; Ogunseitan, OA; Schoenung, JM

    2013-01-01T23:59:59.000Z

    nickel alloy Titanium Polyimide Flexible polymers Notes:hazard substrate material is: polyimide. The only metal backdioxide Molybdenum Polyimide Notes: This is a subset of all

  3. Author's personal copy Arsenic-resistant bacteria solubilized arsenic in the growth media

    E-Print Network [OSTI]

    Ma, Lena

    such as diabetes, skin diseases, and nervous and cardio- vascular problems (Vahter, 2007). The health hazards

  4. Hazardous Waste Management (New Mexico)

    Broader source: Energy.gov [DOE]

    The New Mexico Environment Department's Hazardous Waste Bureau is responsible for the management of hazardous waste in the state. The Bureau enforces the rules established by the Environmental...

  5. Hazardous Sites Cleanup Act (Pennsylvania)

    Broader source: Energy.gov [DOE]

    This Act tasks the Pennsylvania Department of Environmental Protection with regulating hazardous waste. The department is charged with siting, review, permitting and development of hazardous waste...

  6. ARSENIC IN PRIVATE WELLS IN NH YEAR 1 FINAL REPORT

    E-Print Network [OSTI]

    Bucci, David J.

    performed geospatial analysis of the well water arsenic estimates and survey results and produced the maps............................................................................................... 8 Well water treatment .................................................................................................. 7 Well water quality

  7. Arsenic in Drinking Water: Regulatory Developments and Issues

    National Nuclear Security Administration (NNSA)

    Order Code RS20672 Updated May 1, 2007 Arsenic in Drinking Water: Regulatory Developments and Issues Mary Tiemann Specialist in Environmental Policy Resources, Science, and...

  8. arsenic cadmium lead: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Lead Pellets at Shooting Ranges and Arsenical Herbicides onGolf Courses in Florida Environmental Management and Restoration Websites Summary: Environmental Impacts of Lead...

  9. arsenic cadmium chromium: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    10 Arsenic and chromium speciation in an urban contaminated soil Gautier Landrot a, Environmental Management and Restoration Websites Summary: to their close proximity to...

  10. arsenic contaminated water: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    mobility and transport in the environment are strongly influenced by associations with solid phases. This dissertation investigates the mechanisms affecting arsenic retention in...

  11. arsenic contaminated aquifer: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    areas. A number of studies have looked at the variation in nitrate Toran, Laura 13 Assessing Plants for Phytoremediation of Arsenic-Contaminated Soils Environmental Management...

  12. arsenic contaminated groundwater: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    mobility and transport in the environment are strongly influenced by associations with solid phases. This dissertation investigates the mechanisms affecting arsenic retention in...

  13. Performance of a zerovalent iron reactive barrier for the treatment of arsenic in groundwater: Part 2. Geochemical modeling and solid phase studies

    SciTech Connect (OSTI)

    Beak, Douglas G.; Wilkin, Richard T.; (EPA)

    2009-06-12T23:59:59.000Z

    Arsenic uptake processes were evaluated in a zerovalent iron reactive barrier installed at a lead smelting facility using geochemical modeling, solid-phase analysis, and X-ray absorption spectroscopy techniques. Aqueous speciation of arsenic is expected to play a key role in directing arsenic uptake processes. Geochemical modeling reveals contrasting pH-dependencies for As(III) and As(V) precipitation. At the moderately alkaline pH conditions typically encountered in zerovalent iron reactive barriers, As(III) is unlikely to precipitate as an oxide or a sulfide phase. Conversely, increasing pH is expected to drive precipitation of metal arsenates including ferrous arsenate. Bacterially mediated sulfate reduction plays an important role in field installations of granular iron. Neoformed iron sulfides provide surfaces for adsorption of oxyanion and thioarsenic species of As(III) and As(V) and are expected to provide enhanced arsenic removal capacity. X-ray absorption near edge structure (XANES) spectra indicate that arsenic is sequestered in the solid phase as both As(III) and As(V) in coordination environments with O and S. Arsenic removal in the PRB probably results from several pathways, including adsorption to iron oxide and iron sulfide surfaces, and possible precipitation of ferrous arsenate. Corrosion of granular iron appears to result in some As(III) oxidation to As(V) as the proportion of As(V) to As(III) in the solid phase is greater compared to influent groundwater. As(0) was not detected in the PRB materials. These results are broadly comparable to laboratory based studies of arsenic removal by zerovalent iron, but additional complexity is revealed in the field environment, which is largely due to the influence of subsurface microbiota.

  14. Hazard Communication Site Specific Information Sheet Hazard Communication Program (HCP)

    E-Print Network [OSTI]

    Slatton, Clint

    Hazard Communication Site Specific Information Sheet Hazard Communication Program (HCP) Site Specific Information The responsible party for a unit/area should complete this section to make the Hazard Communication Program site specific. The responsible party will ensure that the Hazard Communication Program

  15. Hazardous Waste Management (Michigan)

    Broader source: Energy.gov [DOE]

    A person shall not generate, dispose, store, treat, or transport hazardous waste in this state without complying with the requirements of this article. The department, in the conduct of its duties...

  16. Hazardous Waste Management (Oklahoma)

    Broader source: Energy.gov [DOE]

    This article states regulations for the disposal of hazardous waste. It also provides information about permit requirements for the transport, treatment and storage of such waste. It also mentions...

  17. Life Redefined: Microbes Built with Arsenic

    SciTech Connect (OSTI)

    Webb, Sam (SLAC and Felisa Wolfe-Simon, NASA and U.S. Geological Survey) [SLAC and Felisa Wolfe-Simon, NASA and U.S. Geological Survey

    2011-03-22T23:59:59.000Z

    Life can survive in many harsh environments, from extreme heat to the presence of deadly chemicals. However, life as we know it has always been based on the same six elements -- carbon, oxygen, nitrogen, hydrogen, sulfur and phosphorus. Now it appears that even this rule has an exception. In the saline and poisonous environment of Mono Lake, researchers have found a bacterium that can grow by incorporating arsenic into its structure in place of phosphorus. X-ray images taken at SLAC's synchrotron light source reveal that this microbe may even use arsenic as a building block for DNA. Please join us as we describe this discovery, which rewrites the textbook description of how living cells work.

  18. K Basin Hazard Analysis

    SciTech Connect (OSTI)

    PECH, S.H.

    2000-08-23T23:59:59.000Z

    This report describes the methodology used in conducting the K Basins Hazard Analysis, which provides the foundation for the K Basins Final Safety Analysis Report. This hazard analysis was performed in accordance with guidance provided by DOE-STD-3009-94, Preparation Guide for U. S. Department of Energy Nonreactor Nuclear Facility Safety Analysis Reports and implements the requirements of DOE Order 5480.23, Nuclear Safety Analysis Report.

  19. K Basins Hazard Analysis

    SciTech Connect (OSTI)

    WEBB, R.H.

    1999-12-29T23:59:59.000Z

    This report describes the methodology used in conducting the K Basins Hazard Analysis, which provides the foundation for the K Basins Safety Analysis Report (HNF-SD-WM-SAR-062, Rev.4). This hazard analysis was performed in accordance with guidance provided by DOE-STD-3009-94, Preparation Guide for U. S. Department of Energy Nonreactor Nuclear Facility Safety Analysis Reports and implements the requirements of DOE Order 5480.23, Nuclear Safety Analysis Report.

  20. Automated Job Hazards Analysis

    Broader source: Energy.gov [DOE]

    AJHA Program - The Automated Job Hazard Analysis (AJHA) computer program is part of an enhanced work planning process employed at the Department of Energy's Hanford worksite. The AJHA system is routinely used to performed evaluations for medium and high risk work, and in the development of corrective maintenance work packages at the site. The tool is designed to ensure that workers are fully involved in identifying the hazards, requirements, and controls associated with tasks.

  1. HAZARD ANALYSIS SOFTWARE

    SciTech Connect (OSTI)

    Sommer, S; Tinh Tran, T

    2008-04-08T23:59:59.000Z

    Washington Safety Management Solutions, LLC developed web-based software to improve the efficiency and consistency of hazard identification and analysis, control selection and classification, and to standardize analysis reporting at Savannah River Site. In the new nuclear age, information technology provides methods to improve the efficiency of the documented safety analysis development process which includes hazard analysis activities. This software provides a web interface that interacts with a relational database to support analysis, record data, and to ensure reporting consistency. A team of subject matter experts participated in a series of meetings to review the associated processes and procedures for requirements and standard practices. Through these meetings, a set of software requirements were developed and compiled into a requirements traceability matrix from which software could be developed. The software was tested to ensure compliance with the requirements. Training was provided to the hazard analysis leads. Hazard analysis teams using the software have verified its operability. The software has been classified as NQA-1, Level D, as it supports the analysis team but does not perform the analysis. The software can be transported to other sites with alternate risk schemes. The software is being used to support the development of 14 hazard analyses. User responses have been positive with a number of suggestions for improvement which are being incorporated as time permits. The software has enforced a uniform implementation of the site procedures. The software has significantly improved the efficiency and standardization of the hazard analysis process.

  2. Method of recovering hazardous waste from phenolic resin filters

    DOE Patents [OSTI]

    Meikrantz, David H. (Idaho Falls, ID); Bourne, Gary L. (Idaho Falls, ID); McFee, John N. (Albuquerque, NM); Burdge, Bradley G. (Idaho Falls, ID); McConnell, Jr., John W. (Idaho Falls, ID)

    1991-01-01T23:59:59.000Z

    The invention is a process for the recovery of hazardous wastes such as heavy metals and radioactive elements from phenolic resin filter by a circulating a solution of 8 to 16 molar nitric acid at a temperature of 110 to 190 degrees F. through the filter. The hot solution dissolves the filter material and releases the hazardous material so that it can be recovered or treated for long term storage in an environmentally safe manner.

  3. State of Colorado Wildfire Hazard

    E-Print Network [OSTI]

    State of Colorado Wildfire Hazard Mitigation Plan Colorado Multi-Hazards Mitigation Plan July 2002 and importance of the August 1995 Wildfire Hazard Mitigation Plan and its predecessors as foundation documents on which to build and judge progress in wildfire hazard mitigation. The text version of the 1995 Plan

  4. Hazardous Working Policy November 2012

    E-Print Network [OSTI]

    Doran, Simon J.

    for: The management of University workers performing hazardous tasks or working in hazardous areas;2 Hazardous Areas: are areas where a University worker may be exposed to risks that are considered greater1 Hazardous Working Policy November 2012 Introduction The University of Surrey acknowledges

  5. HAZARDOUS WASTE LABEL DEPAUL UNIVERSITY

    E-Print Network [OSTI]

    Schaefer, Marcus

    - Hazardous Ignitable Reactive Toxic Oxidizer Other ( explain ) Generator Building Dept. HAZARDOUS WASTE LABEL: Generator Building Dept. Please fill out the hazardous waste label on line and download labels on to a plainHAZARDOUS WASTE LABEL DEPAUL UNIVERSITY ENVIRONMENTAL HEALTH & SAFETY 5-4170 Corrosive Non

  6. WORKPLACE HAZARD ASSESSMENT Location: Task

    E-Print Network [OSTI]

    Rubloff, Gary W.

    /Eyes Hands Foot Body 7. THERMAL HAZARD DOES NOT EXIST DOES EXIST SOURCE OF HAZARD Welding Brazing Furnace/NON-IONIZING RADIATION HAZARD DOES NOT EXIST DOES EXIST SOURCE OF HAZARD Heat Treating Brazing Welding Oxygen Cutting Laser High Intensity Lighting Body Part Affected Head Face/Eyes Hands Foot Body #12;

  7. Hazardous Waste Disposal Sites (Iowa)

    Broader source: Energy.gov [DOE]

    These sections contain information on fees and monitoring relevant to operators of hazardous waste disposal sites.

  8. Increased lung cancer risks are similar whether arsenic is ingested ALLAN H. SMITHa

    E-Print Network [OSTI]

    California at Berkeley, University of

    Increased lung cancer risks are similar whether arsenic is ingested or inhaled ALLAN H. SMITHa that inorganic arsenic was a human lung carcinogen based on studies involving exposure through inhalation. In 2004, IARC listed arsenic in drinking water as a cause of lung cancer, making arsenic the first

  9. DECHEM: A remedial planning tool for metallic contaminants in soil at UMTRA Project sites. Final report and users` guide

    SciTech Connect (OSTI)

    Not Available

    1989-03-01T23:59:59.000Z

    The DECHEM (DEcontamination of CHEMicals) method was developed for the Uranium Mill Tailings Remedial Action (UMTRA) Project to guide characterization and remedial planning for metals contamination in soils. This is necessary because non-radiological hazardous constituents may be more mobile than radium-226 (Ra-226), and hence may migrate more deeply into subpile soils (beneath tailings that are to be relocated) or into adjacent contaminated soils at UMTRA Project sites. The result is that remedial action to the Ra-226 excavation limit, as specified in the US Environmental Protection Agency (EPA) standards, may not adequately remove hazardous non-radiological contamination. Unmitigated, these contaminants in soil may cause health risks because of their presence in resuspended particles, their uptake by crops or fodder their seepage into aquifers used for drinking water or other possible exposure pathways. The DECHEM method was developed in response to the need for advanced planning for the remediation of chemical contaminants at UMTRA Project sites, and includes the following elements: Establishment of acceptable exposure rates for humans to chemicals, based on EPA guidelines or other toxicological literature. Modeling of chemical migration through environmental pathways from a remediated UMTRA Project site to humans. Determination of allowable residual concentrations (i.e., cleanup guidelines) for chemicals in soils that results in doses to humans that are below established acceptable exposure rates. The initial development and application of the DECHEM method has focused upon hazardous metallic contaminants such as arsenic, lead, molybdenum, and selenium, which are known to occur in elevated concentrations at some UMTRA Project sites.

  10. The Adsorption of Arsenic Oxyacids to Iron Oxyhydroxide Columns

    E-Print Network [OSTI]

    The Adsorption of Arsenic Oxyacids to Iron Oxyhydroxide Columns Including Studies of Weakly. (photo: Mr. J. Mähler, image editing Dr. D. Lundberg) #12;The Adsorption of Arsenic Oxyacids to Iron of columns and iron content of the adsorbent material. Experiments have shown that adsorption does occur

  11. XAFS Study of Arsenical Nickel Hydroxide , Z. Arthur2

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    of arsenic(V) with ferric iron from hydrometallurgical solutions is widely used for the removal and immobilization of arsenic in uranium mine tailings. Other common co-ions in the industrial solutions formed under the similar conditions of the uranium mine tailings neutralization process. The samples

  12. Doctoral Defense "Biogeochemical evaluation of disposal options for arsenic-

    E-Print Network [OSTI]

    Kamat, Vineet R.

    generated during drinking water treatment" Tara Clancy Date: December 2, 2014 Time: 9:00 AM Location: GM Lutgarde Raskin Professor, Civil & Environmental Engineering Arsenic contamination of drinking water of arsenic removal technologies requires disposal options for produced wastes that limit the release

  13. Release of Arsenic to the Environment from CCA-Treated

    E-Print Network [OSTI]

    Florida, University of

    Release of Arsenic to the Environment from CCA-Treated Wood. 2. Leaching and Speciation during International University, Miami, Florida 33199 Wood treated with chromated copper arsenate (CCA) is primarily of arsenic leaching from landfills containing CCA-treated wood. In control lysimeters where untreated wood

  14. Lung Cancer and Arsenic Concentrations in Drinking Water in Chile

    E-Print Network [OSTI]

    California at Berkeley, University of

    Lung Cancer and Arsenic Concentrations in Drinking Water in Chile Catterina Ferreccio,1,2 Claudia- trations have since been reduced to 40 g/liter. We investi- gated the relation between lung cancer and arsenic in drinking water in northern Chile in a case-control study involving patients diagnosed with lung

  15. Chemical process hazards analysis

    SciTech Connect (OSTI)

    NONE

    1996-02-01T23:59:59.000Z

    The Office of Worker Health and Safety (EH-5) under the Assistant Secretary for the Environment, Safety and Health of the US Department (DOE) has published two handbooks for use by DOE contractors managing facilities and processes covered by the Occupational Safety and Health Administration (OSHA) Rule for Process Safety Management of Highly Hazardous Chemicals (29 CFR 1910.119), herein referred to as the PSM Rule. The PSM Rule contains an integrated set of chemical process safety management elements designed to prevent chemical releases that can lead to catastrophic fires, explosions, or toxic exposures. The purpose of the two handbooks, ``Process Safety Management for Highly Hazardous Chemicals`` and ``Chemical Process Hazards Analysis,`` is to facilitate implementation of the provisions of the PSM Rule within the DOE. The purpose of this handbook ``Chemical Process Hazards Analysis,`` is to facilitate, within the DOE, the performance of chemical process hazards analyses (PrHAs) as required under the PSM Rule. It provides basic information for the performance of PrHAs, and should not be considered a complete resource on PrHA methods. Likewise, to determine if a facility is covered by the PSM rule, the reader should refer to the handbook, ``Process Safety Management for Highly Hazardous Chemicals`` (DOE- HDBK-1101-96). Promulgation of the PSM Rule has heightened the awareness of chemical safety management issues within the DOE. This handbook is intended for use by DOE facilities and processes covered by the PSM rule to facilitate contractor implementation of the PrHA element of the PSM Rule. However, contractors whose facilities and processes not covered by the PSM Rule may also use this handbook as a basis for conducting process hazards analyses as part of their good management practices. This handbook explains the minimum requirements for PrHAs outlined in the PSM Rule. Nowhere have requirements been added beyond what is specifically required by the rule.

  16. Arsenic and diabetes and hypertension in human populations: A review

    SciTech Connect (OSTI)

    Chen, C.-J. [Genomics Research Center, Academia Sinica, 128 Academia Road Section 2, Nankang, Taipei 11529, Taiwan (China); Division of Environmental Health and Occupational Medicine, National Health Research Institutes, Miaoli, Taiwan Institute of Statistical Science, Academia Sinica, Taipei, Taiwan (China); Department of Internal Medicine, National Taiwan University, Taipei, Taiwan (China); School of Public Health, Taipei Medical University, Taipei, Taiwan (China); Department of Public Health, Tzu-Chi University, Hualien, Taiwan (China); Graduate Institute of Preventive Medicine, National Taiwan University, Taipei, Taiwan (China)], E-mail: cjchen@ha.mc.ntu.edu.tw; Wang, S.-L.; Chiou, J.-M.; Tseng, C.-H.; Chiou, H.-Y.; Hsueh, Y.-M.; Chen, S.-Y.; Wu, M.-M.; Lai, M.-S. [Genomics Research Center, Academia Sinica, 128 Academia Road Section 2, Nankang, Taipei 11529, Taiwan (China); Division of Environmental Health and Occupational Medicine, National Health Research Institutes, Miaoli, Taiwan Institute of Statistical Science, Academia Sinica, Taipei, Taiwan (China); Department of Internal Medicine, National Taiwan University, Taipei, Taiwan (China); School of Public Health, Taipei Medical University, Taipei, Taiwan (China); Department of Public Health, Tzu-Chi University, Hualien, Taiwan (China); Graduate Institute of Preventive Medicine, National Taiwan University, Taipei, Taiwan (China)

    2007-08-01T23:59:59.000Z

    Long-term exposure to ingested arsenic from drinking water has been well documented to be associated with an increased risk of diabetes mellitus and hypertension in a dose-response relationship among residents of arseniasis-endemic areas in southwestern Taiwan and Bangladesh. An increased risk of self-reported hypertension but not diabetes was reported in a community-based study of residents who consumed drinking water with a low level of arsenic. Increased glycosylated hemoglobin level and systolic blood pressure were observed in workers occupationally exposed to arsenic. Inconsistent findings of arsenic and diabetes in occupational studies may result from the healthy worker effect and the variation in exposure measurement, age composition, number of patients, accuracy in diagnosis and classification of underlying causes of death, competing causes of death, and method to detect diabetes. The dose-response relationship and toxicological mechanisms of arsenic-induced diabetes and hypertension need further elucidation.

  17. Multiple metals predict prolactin and thyrotropin (TSH) levels in men

    SciTech Connect (OSTI)

    Meeker, John D., E-mail: meekerj@umich.edu [Department of Environmental Health Sciences, University of Michigan School of Public Health, 6635 SPH Tower, 109 S. Observatory St., Ann Arbor, MI 48109 (United States); Rossano, Mary G. [Department of Animal and Food Sciences, University of Kentucky, Lexington, KY (United States)] [Department of Animal and Food Sciences, University of Kentucky, Lexington, KY (United States); Protas, Bridget [Department of Epidemiology, Michigan State University, East Lansing, MI (United States)] [Department of Epidemiology, Michigan State University, East Lansing, MI (United States); Diamond, Michael P.; Puscheck, Elizabeth [Department of Obstetrics and Gynecology, Wayne State University, Detroit, MI (United States)] [Department of Obstetrics and Gynecology, Wayne State University, Detroit, MI (United States); Daly, Douglas [Grand Rapids Fertility and IVF, Grand Rapids, MI (United States)] [Grand Rapids Fertility and IVF, Grand Rapids, MI (United States); Paneth, Nigel [Department of Obstetrics and Gynecology, Michigan State University, East Lansing, MI (United States)] [Department of Obstetrics and Gynecology, Michigan State University, East Lansing, MI (United States); Wirth, Julia J. [Department of Epidemiology, Michigan State University, East Lansing, MI (United States) [Department of Epidemiology, Michigan State University, East Lansing, MI (United States); Department of Obstetrics and Gynecology, Michigan State University, East Lansing, MI (United States)

    2009-10-15T23:59:59.000Z

    Exposure to a number of metals can affect neuroendocrine and thyroid signaling, which can result in adverse effects on development, behavior, metabolism, reproduction, and other functions. The present study assessed the relationship between metal concentrations in blood and serum prolactin (PRL) and thyrotropin (TSH) levels, markers of dopaminergic, and thyroid function, respectively, among men participating in a study of environmental influences on male reproductive health. Blood samples from 219 men were analyzed for concentrations of 11 metals and serum levels of PRL and TSH. In multiple linear regression models adjusted for age, BMI and smoking, PRL was inversely associated with arsenic, cadmium, copper, lead, manganese, molybdenum, and zinc, but positively associated with chromium. Several of these associations (Cd, Pb, Mo) are consistent with limited studies in humans or animals, and a number of the relationships (Cr, Cu, Pb, Mo) remained when additionally considering multiple metals in the model. Lead and copper were associated with non-monotonic decrease in TSH, while arsenic was associated with a dose-dependent increase in TSH. For arsenic these findings were consistent with recent experimental studies where arsenic inhibited enzymes involved in thyroid hormone synthesis and signaling. More research is needed for a better understanding of the role of metals in neuroendocrine and thyroid function and related health implications.

  18. Identification of Aircraft Hazards

    SciTech Connect (OSTI)

    K. Ashley

    2006-12-08T23:59:59.000Z

    Aircraft hazards were determined to be potentially applicable to a repository at Yucca Mountain in ''Monitored Geological Repository External Events Hazards Screening Analysis'' (BSC 2005 [DIRS 174235], Section 6.4.1). That determination was conservatively based upon limited knowledge of flight data in the area of concern and upon crash data for aircraft of the type flying near Yucca Mountain. The purpose of this report is to identify specific aircraft hazards that may be applicable to a monitored geologic repository (MGR) at Yucca Mountain, using NUREG-0800, ''Standard Review Plan for the Review of Safety Analysis Reports for Nuclear Power Plants'' (NRC 1987 [DIRS 103124], Section 3.5.1.6), as guidance for the inclusion or exclusion of identified aircraft hazards. The intended use of this report is to provide inputs for further screening and analysis of identified aircraft hazards based upon the criteria that apply to Category 1 and Category 2 event sequence analyses as defined in 10 CFR 63.2 [DIRS 176544] (Section 4). The scope of this report includes the evaluation of military, private, and commercial use of airspace in the 100-mile regional setting of the repository at Yucca Mountain with the potential for reducing the regional setting to a more manageable size after consideration of applicable screening criteria (Section 7).

  19. Effects of compost and phosphate amendments on arsenic mobility in soils and arsenic uptake by the hyperaccumulator,

    E-Print Network [OSTI]

    Ma, Lena

    Effects of compost and phosphate amendments on arsenic mobility in soils and arsenic uptake, or biosolid compost. Phosphate amendments sig- nificantly enhanced plant As uptake from the two tested soils was responsible for the enhanced mobility of As and subsequent increased plant uptake. Compost additions

  20. Abstract Arsenic hyperaccumulator Pteris vittata L. (Chinese brake fern) grows well in arsenic-contami-

    E-Print Network [OSTI]

    Ma, Lena

    and plated on medium containing 4 mM of arsenate, a common form of arsenic in the environment. The deduced ubiquitous in the environment. It is present both as arsenite (AsIII) and arsenate (AsV) in the environment

  1. Hazardous fluid leak detector

    DOE Patents [OSTI]

    Gray, Harold E. (Las Vegas, NV); McLaurin, Felder M. (Las Vegas, NV); Ortiz, Monico (Las Vegas, NV); Huth, William A. (Las Vegas, NV)

    1996-01-01T23:59:59.000Z

    A device or system for monitoring for the presence of leaks from a hazardous fluid is disclosed which uses two electrodes immersed in deionized water. A gas is passed through an enclosed space in which a hazardous fluid is contained. Any fumes, vapors, etc. escaping from the containment of the hazardous fluid in the enclosed space are entrained in the gas passing through the enclosed space and transported to a closed vessel containing deionized water and two electrodes partially immersed in the deionized water. The electrodes are connected in series with a power source and a signal, whereby when a sufficient number of ions enter the water from the gas being bubbled through it (indicative of a leak), the water will begin to conduct, thereby allowing current to flow through the water from one electrode to the other electrode to complete the circuit and activate the signal.

  2. Evaluation of innovative arsenic treatment technologies :the arsenic water technology partnership vendors forums summary report.

    SciTech Connect (OSTI)

    Everett, Randy L.; Siegel, Malcolm Dean; McConnell, Paul E.; Kirby, Carolyn (Comforce Technical Services, Inc.)

    2006-09-01T23:59:59.000Z

    The lowering of the drinking water standard (MCL) for arsenic from 50 {micro}g/L to 10 {micro}g/L in January 2006 could lead to significant increases in the cost of water for many rural systems throughout the United States. The Arsenic Water Technology Partnership (AWTP), a collaborative effort of Sandia National Laboratories, the Awwa Research Foundation (AwwaRF) and WERC: A Consortium for Environmental Education and Technology Development, was formed to address this problem by developing and testing novel treatment technologies that could potentially reduce the costs of arsenic treatment. As a member of the AWTP, Sandia National Laboratories evaluated cutting-edge commercial products in three annual Arsenic Treatment Technology Vendors Forums held during the annual New Mexico Environmental Health Conferences (NMEHC) in 2003, 2004 and 2005. The Forums were comprised of two parts. At the first session, open to all conference attendees, commercial developers of innovative treatment technologies gave 15-minute talks that described project histories demonstrating the effectiveness of their products. During the second part, these same technologies were evaluated and ranked in closed sessions by independent technical experts for possible use in pilot-scale field demonstrations being conducted by Sandia National Laboratories. The results of the evaluations including numerical rankings of the products, links to company websites and copies of presentations made by the representatives of the companies are posted on the project website at http://www.sandia.gov/water/arsenic.htm. This report summarizes the contents of the website by providing brief descriptions of the technologies represented at the Forums and the results of the evaluations.

  3. Arsenic exposure in children living near a former copper smelter

    SciTech Connect (OSTI)

    Binder, S.; Forney, D.; Kaye, W.; Paschal, D.

    1987-07-01T23:59:59.000Z

    About 10,000 people live in communities surrounding the former copper smelter at Anaconda, Montana. Most of these people live in the town of Anaconda, which is generally upwind of the smelter. The smelter ceased operations in 1980, after almost a century of ore processing. Soil and dust on the smelter site and in the vicinity remain contaminated with arsenic, although at this time air and drinking water arsenic levels are not elevated. Results of soil and dust sampling for arsenic in the communities around the smelter are reported. In the town of Anaconda, surface soil arsenic levels from residential sites have averaged around 100 ppm or greater. Young children are generally believed to be the population with the most nonoccupational exposure to soil. Several models of exposure to environmental arsenic in the Anaconda area have predicted that children living in all communities surrounding the smelter would be having significant and measurable exposure to arsenic. Two exposures surveys, conducted while the smelter was operative, demonstrated that excess exposure to arsenic was occurring in young children. Until the present surveys, no exposure data had been collected since the smelter was closed.

  4. Environmental Hazards and

    E-Print Network [OSTI]

    Murphy, Bob

    . 2. Pollution -Mexico. 3. Transboundary pollution. 4. Conservation of natural resources - UnitedEnvironmental Hazards and Bioresource Management in the United States- Mexico Borderlands Edited. -(Special studies ;v. 3) Includes bibliographical references. ISBN 0-87903-503-X 1. Pollution -United States

  5. Hazardous waste sites and housing appreciation rates

    E-Print Network [OSTI]

    McCluskey, Jill; Rausser, Gordon C.

    2000-01-01T23:59:59.000Z

    WORKING PAPER NO. 906 HAZARDOUS WASTE SITES AND HOUSINGEconomics January 2000 Hazardous Waste Sites and Housingand RF. Anderson, Hazardous waste sites: the credibility

  6. Missouri Hazardous Waste Management Law (Missouri)

    Broader source: Energy.gov [DOE]

    The Hazardous Waste Program, administered by the Hazardous Waste Management Commission in the Department of Natural Resources, regulates the processing, transportation, and disposal of hazardous...

  7. Heavy-metal contamination on training ranges at the Grafenwoehr Training Area, Germany

    SciTech Connect (OSTI)

    Zellmer, S.D.; Schneider, J.F.

    1993-05-01T23:59:59.000Z

    Large quantities of lead and other heavy metals are deposited in the environment of weapons ranges during training exercises. This study was conducted to determine the type, degree, and extent of heavy-metal contamination on selected handgun, rifle, and hand-grenade ranges at Grafenwoehr Training Area, Germany. Soil, vegetation, and surface-water samples were collected and analyzed using the inductively-coupled plasma atomic-emission spectroscopy (ICP-AES) method and the toxic characterization leaching procedure (TCLP). The ICP-AES results show that above-normal levels of lead and copper are in the surface soil at the handgun range, high concentrations of lead and copper are in the berm and soil surface at the rifle range, and elevated levels of cadmium and above-normal concentrations of arsenic, copper, and zinc are present in the surface soil at the hand-grenade range. The TCLP results show that surface soils can be considered hazardous waste because of lead content at the rifle range and because of cadmium concentration at the hand-grenade range. Vegetation at the handgun and rifle ranges has above-normal concentrations of lead. At the hand-grenade range, both vegetation and surface water have high levels of cadmium. A hand-held X-ray fluorescence (XRF) spectrum analyzer was used to measure lead concentrations in soils in a field test of the method. Comparison of XRF readings with ICP-AES results for lead indicate that the accuracy and precision of the hand-held XRF unit must improve before the unit can be used as more than a screening tool. Results of this study show that heavy-metal contamination at all three ranges is limited to the surface soil; heavy metals are not being leached into the soil profile or transported into adjacent areas.

  8. Hazardous Waste Management (North Dakota)

    Broader source: Energy.gov [DOE]

    The Department of Health is the designated agency to administer and coordinate a hazardous waste management program to provide for the reduction of hazardous waste generation, reuse, recovery, and...

  9. Montana Hazardous Waste Act (Montana)

    Broader source: Energy.gov [DOE]

    This Act addresses the safe and proper management of hazardous wastes and used oil, the permitting of hazardous waste facilities, and the siting of facilities. The Department of Environmental...

  10. Geological Hazards Labs Spring 2010

    E-Print Network [OSTI]

    Chen, Po

    Geological Hazards Labs Spring 2010 TA: En-Jui Lee (http://www.gg.uwyo.edu/ggstudent/elee8/site - An Indispensible Tool in Hazard Planning 3 26/1; 27/1 Lab 2: Geologic Maps - Mapping the Hazards 4 2/2; 3/2 Lab 3: Population - People at Risk 5 9/2; 10/2 Lab 4: Plate Tectonics - Locating Geologic Hazards 6 16/2; 17/2 Lab 5

  11. Factors affecting lead, cadmium, and arsenic levels in house dust in a smelter town in eastern Germany

    SciTech Connect (OSTI)

    Meyer, I.; Heinrich, J. (GSF-Forschungszentrum fuer Umwelt und Gesundheit, Neuherberg (Germany). Inst. fuer Epidemiologie); Lippold, U. (Inst. fuer Wasser-, Boden- und Lufthygiene des Umweltbundesamtes Berlin (Germany))

    1999-07-01T23:59:59.000Z

    Hettstedt, a city in eastern Germany with a long history of mining and smelting of nonferrous ores, has several industrial sources of heavy metals. The indoor exposure to metals of children (5 to 14 years old) in the Hettstedt area was assessed by measuring the levels of lead, cadmium, and arsenic contamination in sedimented house dust. Factors which influence the dust loading rate and the surface loading rates of these contaminants in house dust were investigated. The geometric mean of the dust loading rate was 8.9 mg/m[sup 2] day. The geometric means of surface loading rates were 1.14, 0.024, and 0.023 [micro]g/m[sup 2] day for lead, cadmium, and arsenic, respectively. Factors that were significantly associated with surface loading rates included the city area of residence, automobile traffic near home, parent with occupational exposure to heavy metals, type of heating, housing characteristics, whether child's home is damp, number of persons living in the child's home,and parents' education. The most significant of these factors was the city area of residence, which reflects the distance from the metal sources; this factor accounted for about half of the variances explained by the regression models.

  12. Hazard Sampling Dialog General Layout

    E-Print Network [OSTI]

    Zhang, Tao

    1 Hazard Sampling Dialog General Layout The dialog's purpose is to display information about the hazardous material being sampled by the UGV so either the system or the UV specialist can identify the risk level of the hazard. The dialog is associated with the hazmat reading icons (Table 1). Components

  13. Appendix C: Hazardous Property Assessment

    E-Print Network [OSTI]

    Siddharthan, Advaith

    Appendix C: Hazardous Property Assessment The aim of this appendix is to: · give advice on the hazards properties H1 to H14 identified in Annex III of the HWD; · provide assessment methods and threshold concentrations for the hazards; and · advise on which test methods should be considered

  14. LOG HAZARD REGRESSION Huiying Sun

    E-Print Network [OSTI]

    Heckman, Nancy E.

    LOG HAZARD REGRESSION by Huiying Sun Ph.D, Harbin Institute of Technology, Harbin, CHINA, 1991 regression splines to estimate the two log marginal hazard func­ tions of bivariate survival times, where, 1995) hazard regression for estimating a univariate survival time. We derive an approach to find

  15. Written Hazard Communication (HAZCOM) Program

    E-Print Network [OSTI]

    Jia, Songtao

    chemicals The potential hazards of chemicals in the work area How to protect yourself from these potential for their respective work areas MSDS's shall be maintained by each department for all hazardous chemicals&S office has developed several employee training modules for specific work areas and hazardous materials

  16. arsenic rich iron: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Carretta; Livia Origlia 2006-05-25 30 Arsenic and Bladder Cancer Mortality Kenneth G. Brown; Barbara D. Beck; Claudia Hopenhayn-Rich; Mary Lou Biggs; Allan H. Smith Biology and...

  17. Arsenic Trisulfide on Lithium Niobate Devices for Infrared Integrated Optics 

    E-Print Network [OSTI]

    Xia, Xin

    2012-07-16T23:59:59.000Z

    Arsenic trisulfide (As?S?) waveguide devices on lithium niobate substrates (LiNbO?) provide a set of compact and versatile means for guiding and manipulating optical modes in infrared integrated optical circuits, including the integrated trace gas...

  18. Treatment of arsenic-contaminated water using akaganeite adsorption

    DOE Patents [OSTI]

    Cadena C., Fernando (Las Cruces, NM); Johnson, Michael D. (Las Cruces, NM)

    2008-01-01T23:59:59.000Z

    The present invention comprises a method and composition using akaganeite, an iron oxide, as an ion adsorption medium for the removal of arsenic from water and affixing it onto carrier media so that it can be used in filtration systems.

  19. In Situ Iron Oxide Emplacement for Groundwater Arsenic Remediation 

    E-Print Network [OSTI]

    Abia, Thomas Sunday

    2012-02-14T23:59:59.000Z

    Iron oxide-bearing minerals have long been recognized as an effective reactive media for arsenic-contaminated groundwater remediation. This research aimed to develop a technique that could facilitate in situ oxidative precipitation of Fe3+ in a soil...

  20. Arsenic Trisulfide on Lithium Niobate Devices for Infrared Integrated Optics

    E-Print Network [OSTI]

    Xia, Xin

    2012-07-16T23:59:59.000Z

    Arsenic trisulfide (As?S?) waveguide devices on lithium niobate substrates (LiNbO?) provide a set of compact and versatile means for guiding and manipulating optical modes in infrared integrated optical circuits, including the integrated trace gas...

  1. Factors influencing the efficiency of arsenic extraction by phosphate

    E-Print Network [OSTI]

    Yean, Su Jin

    2005-11-01T23:59:59.000Z

    , phosphate concentration, principal counterion, reaction pH, and reaction time. The extraction efficiency was impacted by the influence of these individual factors on reaction kinetics and accessibility of arsenic adsorption sites for ligand exchange...

  2. arsenic groundwater system: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bangladesh" (II) Harvey et al. (1 with recent mobilization of arsenic by irri- gation pumping, if their model of vertical flow is taken at face mobilization if this feature was...

  3. A Terminal Molybdenum Arsenide Complex Synthesized from Yellow Arsenic

    E-Print Network [OSTI]

    Curley, John J.

    A terminal molybdenum arsenide complex is synthesized in one step from the reactive As4 molecule. The properties of this complex with its arsenic atom ligand are discussed in relation to the analogous nitride and phosphide ...

  4. Enhancing Railroad Hazardous Materials Transportation Safety...

    Office of Environmental Management (EM)

    Enhancing Railroad Hazardous Materials Transportation Safety Rail Routing Enhancing Railroad Hazardous Materials Transportation Safety Rail Routing Presentation made by Kevin...

  5. PUREX facility hazards assessment

    SciTech Connect (OSTI)

    Sutton, L.N.

    1994-09-23T23:59:59.000Z

    This report documents the hazards assessment for the Plutonium Uranium Extraction Plant (PUREX) located on the US Department of Energy (DOE) Hanford Site. Operation of PUREX is the responsibility of Westinghouse Hanford Company (WHC). This hazards assessment was conducted to provide the emergency planning technical basis for PUREX. DOE Order 5500.3A requires an emergency planning hazards assessment for each facility that has the potential to reach or exceed the lowest level emergency classification. In October of 1990, WHC was directed to place PUREX in standby. In December of 1992 the DOE Assistant Secretary for Environmental Restoration and Waste Management authorized the termination of PUREX and directed DOE-RL to proceed with shutdown planning and terminal clean out activities. Prior to this action, its mission was to reprocess irradiated fuels for the recovery of uranium and plutonium. The present mission is to establish a passively safe and environmentally secure configuration at the PUREX facility and to preserve that condition for 10 years. The ten year time frame represents the typical duration expended to define, authorize and initiate follow-on decommissioning and decontamination activities.

  6. Significance of the modes of occurrence of arsenic in coal

    SciTech Connect (OSTI)

    Ruppert, L.F. [Geological Survey, Reston, VA (United States); Hower, J.C. [Univ. of Kentucky, Lexington, KY (United States). Center for Applied Energy Research; Eble, C.F. [Kentucky Geological Survey, Lexington, KY (United States)

    1995-12-31T23:59:59.000Z

    Although modes of occurrence can be determined with a variety of techniques, electron microscopy allows documentation and quantification of trace elements in mineral phases. In these studies, the authors have used scanning electron and electron-beam microscopy to analyze pyrite grains in coal samples that contain high arsenic and to determine its mode of occurrence. Information obtained from these studies may prove valuable in predicting and modeling the fate of arsenic in coal utilization.

  7. Hazardous Waste Management Overview The Five L's

    E-Print Network [OSTI]

    Jia, Songtao

    Hazardous Waste Management Overview The Five L's CoLLect CoLLect all hazardous chemical waste are unsure if your chemical waste is a Hazardous Waste, consult EH&S at hazmat@columbia.edu. DO NOT - Dispose of Hazardous Waste inappropriately or prior to determining its hazards. Hazardous Waste must never

  8. Inorganic arsenic exposure and type 2 diabetes mellitus in Mexico

    SciTech Connect (OSTI)

    Coronado-Gonzalez, Jose Antonio [Clinical Epidemiologic Research Unit, General Regional Hospital 1 'Gabriel Mancera', Mexican Institute of the Social Security, Mexico, D.F. (Mexico); Razo, Luz Maria del [Toxicology Departament, Cinvestav, Mexico D.F. (Mexico); Garcia-Vargas, Gonzalo [School of Medicine, Durango State Juarez University, Gomez Palacio, Durango (Mexico); Biomedical Research Center, Coahuila, Autonomous University, Torreon, Coahuila (Mexico); Sanmiguel-Salazar, Francisca [Biomedical Research Center, Coahuila, Autonomous University, Torreon, Coahuila (Mexico); Escobedo-de la Pena, Jorge [Clinical Epidemiologic Research Unit, General Regional Hospital 1 'Gabriel Mancera', Mexican Institute of the Social Security, Mexico, D.F. (Mexico)]. E-mail: jorgeep@servidor.unam.mx

    2007-07-15T23:59:59.000Z

    Inorganic arsenic exposure in drinking water has been recently related to diabetes mellitus. To evaluate this relationship the authors conducted in 2003, a case-control study in an arseniasis-endemic region from Coahuila, a northern state of Mexico with a high incidence of diabetes. The present analysis includes 200 cases and 200 controls. Cases were obtained from a previous cross-sectional study conducted in that region. Diagnosis of diabetes was established following the American Diabetes Association criteria, with two fasting glucose values {>=}126 mg/100 ml ({>=}7.0 mmol/l) or a history of diabetes treated with insulin or oral hypoglycemic agents. The next subject studied, subsequent to the identification of a case in the cross-sectional study was taken as control. Inorganic arsenic exposure was measured through total arsenic concentrations in urine, measured by hydride-generation atomic absorption spectrophotometry. Subjects with intermediate total arsenic concentration in urine (63.5-104 {mu}g/g creatinine) had two-fold higher risk of having diabetes (odds ratio=2.16; 95% confidence interval: 1.23, 3.79), but the risk was almost three times greater in subjects with higher concentrations of total arsenic in urine (odds ratio=2.84; 95% confidence interval: 1.64, 4.92). This data provides additional evidence that inorganic arsenic exposure may be diabetogenic.

  9. Background Concentrations of Trace Metals in

    E-Print Network [OSTI]

    Ma, Lena

    of Florida State University System of Florida FLORIDA CENTER FOR SOLID AND HAZARDOUS WASTE MANAGEMENT 2207 NW for evaluating land application of non-hazardous waste materials and monitoring the mobility of trace metals from 8,000 archived samples. l To validate the sampling protocol used by the Florida Cooperative Soil

  10. The influence of calcium on the inhibition of arsenic desorption from treatment residuals in extreme environments

    E-Print Network [OSTI]

    Camacho, Julianna G.

    2006-04-12T23:59:59.000Z

    the surface properties of the oxy-hydroxide solid in solution. Results show that calcium enhances the removal by iron oxides and prevents the leaching of arsenic from the residuals. Isotherm experiments show that arsenic adsorption can be described...

  11. ORISE: Hazard Assessments

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)Integrated CodesTransparencyDOE ProjectCrisis and RiskEnvironment AtGraduateH1N1Hazard

  12. Artificial Cellulosomes and Arsenic Cleanup: From Single Cell Programming to Synthetic Yeast Consortium

    E-Print Network [OSTI]

    Tsai, Shen-Long

    2011-01-01T23:59:59.000Z

    biofuel production and arsenic bioremediation indicates that sophisticated metabolic techniques will continue to be implemented to advance

  13. In situ chemical fixation of arsenic-contaminated soils: An experimental study

    E-Print Network [OSTI]

    Yang, Li; Donahoe, Rona J.; Redwine, James C.

    2007-01-01T23:59:59.000Z

    retention mechanisms on goethite. 1. surface structure.of arsenic(III) on goethite: spectroscopic evidence for

  14. Environ. Sci. Techno/. 1997, 31,2923-2930 Microbial Mobilizationof Arsenic

    E-Print Network [OSTI]

    Lovley, Derek

    from aquatic sediments by specific microbial action. Arsenic mobilization from aquatic sediments to this transport, mobilization of solid-phase arsenic was investigated in upper Aberjona sediment microcosms oxyhydroxidesis almostexclusivelyAs(V).possibly due to the ability of theseoxyhydroxidesto oxidize arsenic (7),As

  15. In Situ Groundwater Arsenic Removal Using Iron Oxide-Coated Sand 

    E-Print Network [OSTI]

    Yu, Hongxu

    2010-10-12T23:59:59.000Z

    environment for in situ removal of arsenic. A sand filter with a fresh iron oxide coating can treat thousands of pore volumes of water contaminated with dozens of ppb arsenic before the coating needs to be regenerated. Arsenic breakthrough curves through...

  16. Contamination of drinking-water by arsenic in Bangladesh: a public health emergency

    E-Print Network [OSTI]

    California at Berkeley, University of

    Contamination of drinking-water by arsenic in Bangladesh: a public health emergency Allan H. Smith,1 Elena O. Lingas,2 & Mahfuzar Rahman3 The contamination of groundwater by arsenic in Bangladesh contamination. Studies in other countries where the population has had long-term exposure to arsenic

  17. THE ROLE OF IRON PLAQUES IN IMMOBILIZING ARSENIC IN THE RICE-ROOT ENVIRONMENT

    E-Print Network [OSTI]

    Sparks, Donald L.

    THE ROLE OF IRON PLAQUES IN IMMOBILIZING ARSENIC IN THE RICE-ROOT ENVIRONMENT by Cecily Eiko Moyer Rights Reserved #12;THE ROLE OF IRON PLAQUES IN IMMOBILIZING ARSENIC IN THE RICE-ROOT ENVIRONMENT 1.1 Arsenic in the Environment

  18. Geostatistical modeling of the spatial variability of arsenic in groundwater of southeast Michigan

    E-Print Network [OSTI]

    Geostatistical modeling of the spatial variability of arsenic in groundwater of southeast Michigan in groundwater of southeast Michigan, accounting for arsenic data collected at private residential wells and the hydrogeochemistry of the area. The arsenic data set, which was provided by the Michigan Department of Environmental

  19. Decrements in Lung Function Related to Arsenic in Drinking Water in West Bengal, India

    E-Print Network [OSTI]

    California at Berkeley, University of

    Decrements in Lung Function Related to Arsenic in Drinking Water in West Bengal, India Ondine S­2000, the authors investigated relations between lung function, respiratory symptoms, and arsenic in drinking water, consumption of arsenic-contaminated water was associated with respiratory symptoms and reduced lung function

  20. Surveillance Guides - Identification of Hazards

    Broader source: Energy.gov (indexed) [DOE]

    Date: Facility Representative RL Facility Representative Program March 9, 1995 Surveillance Guide Revision 0 Identification of hazards Page 1 of 5...

  1. Hazardous Waste Act (New Mexico)

    Broader source: Energy.gov [DOE]

    "Hazardous waste" means any solid waste or combination of solid wastes that because of their quantity, concentration or physical, chemical or infectious characteristics may:  cause or significantly...

  2. Hazardous Substances Act (South Carolina)

    Broader source: Energy.gov [DOE]

    The Commissioner of the Department of Agriculture has the authority to promulgate regulations declaring specified substances to be hazardous and establishing labeling, transportation, storage, and...

  3. Hazardous Waste Facilities Siting (Connecticut)

    Broader source: Energy.gov [DOE]

    These regulations describe the siting and permitting process for hazardous waste facilities and reference rules for construction, operation, closure, and post-closure of these facilities.

  4. Hazardous Waste Transporter Permits (Connecticut)

    Broader source: Energy.gov [DOE]

    Transportation of hazardous wastes into or through the State of Connecticut requires a permit. Some exceptions apply. The regulations provide information about obtaining permits and other permit...

  5. Nebraska Hazardous Waste Regulations (Nebraska)

    Broader source: Energy.gov [DOE]

    These regulations, promulgated by the Department of Environmental Quality, contain provisions pertaining to hazardous waste management, waste standards, permitting requirements, and land disposal...

  6. Repeated surveillance of exposure to cadmium, manganese, and arsenic in school-age children living in rural, urban, and nonferrous smelter areas in Belgium

    SciTech Connect (OSTI)

    Buchet, J.P. (Univ. of Louvain, Brussels, Belgium); Roels, H.; Lauwerys, R.; Bruaux, P.; Claeys-Thoreau, F.; Lafontaine, A.; Verduyn, G.

    1980-06-01T23:59:59.000Z

    The intensity of exposure to Cd, As, Mn in groups of school-age children living around a lead smelter was assessed. By comparison, groups of children living in an urban and a rural area were also examined. The metal content of blood, urine, hand-rinsing, air, dust, and dirt collected in the school-playground was compared. The urinary excretion of cadmium in children living around the lead smelter is greater than in those living in the urban and in the rural area. In the latter there seems to exist a time-dependent trend in the renal accumulation of cadmium. This suggests that the overall pollution of the environment by cadmium in Belgium is progressively increasing. In the smelter area, both the oral and pulmonary routes play a role in the children's exposure to cadmium. Their relative contribution to the amount of cadmium absorbed appears similar. The concentration of arsenic in urine of children living around the smelter is significantly higher than that of rural children. Speciation of the chemical forms of arsenic in urine indicates that the difference is not due to different dietary habits of the children examined but to different intensity of exposure to inorganic arsenic. The amount of arsenic on the hand of children living at less than 1 km from the smelter (anti X = 17.6 ..mu..g As/hand) was more than 10 times that found in children living at 2.5 km from the plant (anti X = 1.5 ..mu..g As/hand) whereas that found in children living in urban and rural areas was below 0.2 ..mu..g As/hand. The arsenic concentration of dust and dirt collected in the school-playground in the different areas follows the same trend.

  7. Standard test methods for arsenic in uranium hexafluoride

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2005-01-01T23:59:59.000Z

    1.1 These test methods are applicable to the determination of total arsenic in uranium hexafluoride (UF6) by atomic absorption spectrometry. Two test methods are given: Test Method A—Arsine Generation-Atomic Absorption (Sections 5-10), and Test Method B—Graphite Furnace Atomic Absorption (Appendix X1). 1.2 The test methods are equivalent. The limit of detection for each test method is 0.1 ?g As/g U when using a sample containing 0.5 to 1.0 g U. Test Method B does not have the complete collection details for precision and bias data thus the method appears as an appendix. 1.3 Test Method A covers the measurement of arsenic in uranyl fluoride (UO2F2) solutions by converting arsenic to arsine and measuring the arsine vapor by flame atomic absorption spectrometry. 1.4 Test Method B utilizes a solvent extraction to remove the uranium from the UO2F2 solution prior to measurement of the arsenic by graphite furnace atomic absorption spectrometry. 1.5 Both insoluble and soluble arsenic are measured when UF6 is...

  8. HAZARD ALERT ENVIRONMENT HEALTH AND SAFETY

    E-Print Network [OSTI]

    Calgary, University of

    HAZARD ALERT ENVIRONMENT HEALTH AND SAFETY EH&S Hazard Alert - 2010.06.18 HAZARD ALERT ­ Reaction Manual. http://www.ucalgary.ca/safety/files/safety/LaboratoryFumeHoodUserStandard.pdf #12;HAZARD ALERT ENVIRONMENT HEALTH AND SAFETY EH&S Hazard Alert - 2010.06.18 In the recent incident the sash was closed while

  9. Laboratory Waste Disposal HAZARDOUS GLASS

    E-Print Network [OSTI]

    Sheridan, Jennifer

    Laboratory Waste Disposal HAZARDOUS GLASS Items that could cut or puncture skin or trash- can without any treatment. Hazardous Glass and Plastic: Items that can puncture, cut or scratch if disposed of in normal trash containers. Pasteur pipettes Other pipettes and tips (glass or plastic) Slides and cover

  10. Hazardous and radioactive substances in

    E-Print Network [OSTI]

    , and a number of other organic substances, as well as some biological effects of hazardous substances. Chapter 3 substances in the marine food web ...12 1.3 Effects of hazardous substances in the marine environment ..........................................40 2.5 Other organic substances............................................

  11. Organic and inorganic hazardous waste stabilization utilizing fossil fuel combustion waste materials

    SciTech Connect (OSTI)

    Netzel, D.A.; Lane, D.C.; Brown, M.A.; Raska, K.A.; Clark, J.A.; Rovani, J.F.

    1993-09-01T23:59:59.000Z

    A laboratory study was conducted at the Western Research Institute to evaluate the ability of innovative clean coal technology (ICCT) waste to stabilize organic and inorganic constituents of hazardous wastes. The four ICCT wastes used in this study were: (1) the Tennessee Valley Authority (TVA) atmospheric fluidized bed combustor (AFBC) waste, (2) the TVA spray dryer waste, (3) the Laramie River Station spray dryer waste, and (4) the Colorado-Ute AFBC waste. Four types of hazardous waste stream materials were obtained and chemically characterized for use in evaluating the ability of the ICCT wastes to stabilize hazardous organic and inorganic wastes. The wastes included an API separator sludge, mixed metal oxide-hydroxide waste, metal-plating sludge, and creosote-contaminated soil. The API separator sludge and creosote-contaminated soil are US Environmental Protection Agency (EPA)-listed hazardous wastes and contain organic contaminants. The mixed metal oxide-hydroxide waste and metal-plating sludge (also an EPA-listed waste) contain high concentrations of heavy metals. The mixed metal oxide-hydroxide waste fails the Toxicity Characteristic Leaching Procedure (TCLP) for cadmium, and the metal-plating sludge fails the TCLP for chromium. To evaluate the ability of the ICCT wastes to stabilize the hazardous wastes, mixtures involving varying amounts of each of the ICCT wastes with each of the hazardous wastes were prepared, allowed to equilibrate, and then leached with deionized, distilled water. The leachates were analyzed for the hazardous constituent(s) of interest using the Toxicity Characteristic Leaching Procedure.

  12. Metal resistance sequences and transgenic plants

    DOE Patents [OSTI]

    Meagher, Richard Brian (Athens, GA); Summers, Anne O. (Athens, GA); Rugh, Clayton L. (Athens, GA)

    1999-10-12T23:59:59.000Z

    The present invention provides nucleic acid sequences encoding a metal ion resistance protein, which are expressible in plant cells. The metal resistance protein provides for the enzymatic reduction of metal ions including but not limited to divalent Cu, divalent mercury, trivalent gold, divalent cadmium, lead ions and monovalent silver ions. Transgenic plants which express these coding sequences exhibit increased resistance to metal ions in the environment as compared with plants which have not been so genetically modified. Transgenic plants with improved resistance to organometals including alkylmercury compounds, among others, are provided by the further inclusion of plant-expressible organometal lyase coding sequences, as specifically exemplified by the plant-expressible merB coding sequence. Furthermore, these transgenic plants which have been genetically modified to express the metal resistance coding sequences of the present invention can participate in the bioremediation of metal contamination via the enzymatic reduction of metal ions. Transgenic plants resistant to organometals can further mediate remediation of organic metal compounds, for example, alkylmetal compounds including but not limited to methyl mercury, methyl lead compounds, methyl cadmium and methyl arsenic compounds, in the environment by causing the freeing of mercuric or other metal ions and the reduction of the ionic mercury or other metal ions to the less toxic elemental mercury or other metals.

  13. Laboratory Hazard Assessment Tool UC Laboratory Hazard Assessment v11 UC Regents Page 1 of 28

    E-Print Network [OSTI]

    Aluwihare, Lihini

    Laboratory Hazard Assessment Tool UC Laboratory Hazard Assessment v11 © UC Regents Page 1 of 28 This Laboratory Hazard Assessment Tool (LHAT) facilitates identification of hazards and identifies the Personal as hazards and personnel change, and at least once every 12 months, irrespective of changes to hazards

  14. Columbia University Hazardous Waste Room Inspection Report

    E-Print Network [OSTI]

    Jia, Songtao

    Storage Area Hazardous Waste Room Inspection Report Location: Bldg. Room: Date: Inspected ByColumbia University Hazardous Waste Room Inspection Report Flammable Storage Area Lack Pack always closed while holding hazardous wastes? Comment: 12. Are containers labeled? Date

  15. Hazardous Waste Management Standards and Regulations (Kansas)

    Broader source: Energy.gov [DOE]

    This act states the standards and regulations for the management of hazardous waste. No person shall construct, modify or operate a hazardous waste facility or otherwise dispose of hazardous waste...

  16. Hazardous Waste Facility Siting Program (Maryland)

    Broader source: Energy.gov [DOE]

    The Hazardous Waste Facilities Siting Board is responsible for overseeing the siting of hazardous waste facilities in Maryland, and will treat hazardous waste facilities separately from low-level...

  17. COLORADO FRONT RANGE SEISMICITY AND SEISMIC HAZARD

    E-Print Network [OSTI]

    Sheehan, Anne F.

    COLORADO FRONT RANGE SEISMICITY AND SEISMIC HAZARD Anne F. Sheehan University of Colorado, seismic, seismicity, crust, fault, hazard ABSTRACT Construction of seismic hazard and risk maps depends upon carefully constrained input parameters including background seismicity, seismic attenuation

  18. Arsenic- and cadmium-induced toxicogenomic response in mouse embryos undergoing neurulation

    SciTech Connect (OSTI)

    Robinson, Joshua F.; Yu, Xiaozhong [Department of Environmental and Occupational Health Sciences, University of Washington, Seattle, WA 98195 (United States); Institute for Risk Analysis and Risk Communication, Seattle, WA 98195 (United States); Moreira, Estefania G. [Institute for Risk Analysis and Risk Communication, Seattle, WA 98195 (United States); Department of Physiological Sciences, State University of Londrina, Londrina, PR (Brazil); Hong, Sungwoo [Department of Environmental and Occupational Health Sciences, University of Washington, Seattle, WA 98195 (United States); Institute for Risk Analysis and Risk Communication, Seattle, WA 98195 (United States); Faustman, Elaine M., E-mail: faustman@u.washington.edu [Department of Environmental and Occupational Health Sciences, University of Washington, Seattle, WA 98195 (United States); Institute for Risk Analysis and Risk Communication, Seattle, WA 98195 (United States); Center for Ecogenetics and Environmental Health, Seattle, WA 98195 (United States); Center on Human Development and Disability, Seattle, WA 98195 (United States); Center for Child Environmental Health Risks Research, Seattle, WA 98195 (United States)

    2011-01-15T23:59:59.000Z

    Arsenic (As) and cadmium (Cd) are well-characterized teratogens in animal models inducing embryotoxicity and neural tube defects (NTDs) when exposed during neurulation. Toxicological research is needed to resolve the specific biological processes and associated molecular pathways underlying metal-induced toxicity during this timeframe in gestational development. In this study, we investigated the dose-dependent effects of As and Cd on gene expression in C57BL/6J mouse embryos exposed in utero during neurulation (GD8) to identify significantly altered genes and corresponding biological processes associated with embryotoxicity. We quantitatively examined the toxicogenomic dose-response relationship at the gene level. Our results suggest that As and Cd induce dose-dependent gene expression alterations representing shared (cell cycle, response to UV, glutathione metabolism, RNA processing) and unique (alcohol/sugar metabolism) biological processes, which serve as robust indicators of metal-induced developmental toxicity and indicate underlying embryotoxic effects. Our observations also correlate well with previously identified impacts of As and Cd on specific genes associated with metal-induced toxicity (Cdkn1a, Mt1). In summary, we have identified in a quantitative manner As and Cd induced dose-dependent effects on gene expression in mouse embryos during a peak window of sensitivity to embryotoxicity and NTDs in the sensitive C57BL/6J strain.

  19. Hazard Lewis Farms Collection Binghamton University Libraries

    E-Print Network [OSTI]

    Suzuki, Masatsugu

    Hazard Lewis Farms Collection Binghamton University Libraries Special Collections Hazard Lewis Farms Collection Finding Aid created 2012 Jean Green, Head of Special Collections, Preservation

  20. Advanced Membrane Systems: Recovering Wasteful and Hazardous...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Membrane Systems: Recovering Wasteful and Hazardous Fuel Vapors at the Gasoline Tank Advanced Membrane Systems: Recovering Wasteful and Hazardous Fuel Vapors at the...

  1. Process for electrolytically preparing uranium metal

    DOE Patents [OSTI]

    Haas, Paul A. (Knoxville, TN)

    1989-01-01T23:59:59.000Z

    A process for making uranium metal from uranium oxide by first fluorinating uranium oxide to form uranium tetrafluoride and next electrolytically reducing the uranium tetrafluoride with a carbon anode to form uranium metal and CF.sub.4. The CF.sub.4 is reused in the fluorination reaction rather than being disposed of as a hazardous waste.

  2. An ecological study examining the correlation of end-stage renal disease and ground water heavy metal content in Texas counties

    E-Print Network [OSTI]

    Bishop, Scott Alan

    1999-01-01T23:59:59.000Z

    An ecological study was conducted to examine the correlation of end-stage renal disease (ESRD) and the ground water heavy metal level of lead, arsenic, cadmium, mercury and the cumulative level of all four metals in Texas counties. The heavy meal...

  3. Interaction Between Trace Metals, Sodium and Sorbents in Combustion.

    SciTech Connect (OSTI)

    Wendt, O.L.; Davis, S.

    1997-10-17T23:59:59.000Z

    The proposed research is directed at an understanding of how to exploit interactions between sodium, toxic metals and sorbents, in order to optimize sorbents injection procedures, which can be used to capture and transform these metals into environmentally benign forms. The research will use a 17kW downflow, laboratory combustor, to yield data that can be interpreted in terms of fundamental kinetic mechanisms. Metals to be considered are lead, cadmium, and arsenic. Sorbents will be kaolinite, bauxite, and limestone. The role of sulfur will also be determined.

  4. The Hazard Posed by Depleted Uranium Munitions

    E-Print Network [OSTI]

    Steve Fetter And; Steve Fetter A

    This paper assesses the radiological and chemical hazards resulting from the use of depleted uranium (DU) munitions. Due to the low radioactivity of DU, radiological hazards to individuals would become significant in comparison to natural background radiation doses only in cases of prolonged contact---for example, when shards of a DU penetrator remain embedded in a soldier's body. Although the radiation doses to virtually all civilians would be very low, the cumulative "population dose" resulting from the dispersal of hundreds of tons of DU, as occurred during the Gulf War, could result in up to ten cancer deaths. It is highly unlikely that exposures of persons downwind from the use of DU munitions or consuming food or water contaminated by DU dust would reach the estimated threshold for chemical heavy-metal effects. The exposures of soldiers in vehicles struck by DU munitions could be much higher, however, and persons who subsequently enter such vehicles without adequate respiratory protection could potentially be at risk. Soldiers should be trained to avoid unnecessary exposure to DU, and vehicles struck by DU munitions should be made inaccessible to curious civilians. INTRODUCTION

  5. Toxic hazards of underground excavation

    SciTech Connect (OSTI)

    Smith, R.; Chitnis, V.; Damasian, M.; Lemm, M.; Popplesdorf, N.; Ryan, T.; Saban, C.; Cohen, J.; Smith, C.; Ciminesi, F.

    1982-09-01T23:59:59.000Z

    Inadvertent intrusion into natural or man-made toxic or hazardous material deposits as a consequence of activities such as mining, excavation or tunnelling has resulted in numerous deaths and injuries in this country. This study is a preliminary investigation to identify and document instances of such fatal or injurious intrusion. An objective is to provide useful insights and information related to potential hazards due to future intrusion into underground radioactive-waste-disposal facilities. The methodology used in this study includes literature review and correspondence with appropriate government agencies and organizations. Key categories of intrusion hazards are asphyxiation, methane, hydrogen sulfide, silica and asbestos, naturally occurring radionuclides, and various mine or waste dump related hazards.

  6. FIRE HAZARDS ANALYSIS - BUSTED BUTTE

    SciTech Connect (OSTI)

    R. Longwell; J. Keifer; S. Goodin

    2001-01-22T23:59:59.000Z

    The purpose of this fire hazards analysis (FHA) is to assess the risk from fire within individual fire areas at the Busted Butte Test Facility and to ascertain whether the DOE fire safety objectives are met. The objective, identified in DOE Order 420.1, Section 4.2, is to establish requirements for a comprehensive fire and related hazards protection program for facilities sufficient to minimize the potential for: (1) The occurrence of a fire related event. (2) A fire that causes an unacceptable on-site or off-site release of hazardous or radiological material that will threaten the health and safety of employees. (3) Vital DOE programs suffering unacceptable interruptions as a result of fire and related hazards. (4) Property losses from a fire and related events exceeding limits established by DOE. Critical process controls and safety class systems being damaged as a result of a fire and related events.

  7. Hazardous and Industrial Waste (Minnesota)

    Broader source: Energy.gov [DOE]

    This section describes standards that must be met by facilities generating and processing hazardous and industrial waste, as well as required permits for the construction and operation of such a...

  8. Hazardous Waste Management Regulations (Mississippi)

    Broader source: Energy.gov [DOE]

    The Hazardous Waste Management Regulations follow the EPA's definitions and guidelines for the most part, which are listed in 40 CFR parts 260-282. In addition to these federal regulations the...

  9. Hazardous Waste Management (North Carolina)

    Broader source: Energy.gov [DOE]

    These rules identify and list hazardous waste and set standards for the generators and operators of such waste as well as owners or operators of waste facilities. They also stats standards for...

  10. Health Hazards in Indoor Air

    E-Print Network [OSTI]

    Logue, Jennifer M.

    2012-01-01T23:59:59.000Z

    Health Hazards in Indoor Air. In Proceedings of the 2010for VOCs from post-1990 indoor air concentration studies inUnion project on indoor air pollutants. Allergy, 2008. 63(

  11. Preliminary hazards analysis -- vitrification process

    SciTech Connect (OSTI)

    Coordes, D.; Ruggieri, M.; Russell, J.; TenBrook, W.; Yimbo, P. [Science Applications International Corp., Pleasanton, CA (United States)] [Science Applications International Corp., Pleasanton, CA (United States)

    1994-06-01T23:59:59.000Z

    This paper presents a Preliminary Hazards Analysis (PHA) for mixed waste vitrification by joule heating. The purpose of performing a PHA is to establish an initial hazard categorization for a DOE nuclear facility and to identify those processes and structures which may have an impact on or be important to safety. The PHA is typically performed during and provides input to project conceptual design. The PHA is then followed by a Preliminary Safety Analysis Report (PSAR) performed during Title 1 and 2 design. The PSAR then leads to performance of the Final Safety Analysis Report performed during the facility`s construction and testing. It should be completed before routine operation of the facility commences. This PHA addresses the first four chapters of the safety analysis process, in accordance with the requirements of DOE Safety Guidelines in SG 830.110. The hazards associated with vitrification processes are evaluated using standard safety analysis methods which include: identification of credible potential hazardous energy sources; identification of preventative features of the facility or system; identification of mitigative features; and analyses of credible hazards. Maximal facility inventories of radioactive and hazardous materials are postulated to evaluate worst case accident consequences. These inventories were based on DOE-STD-1027-92 guidance and the surrogate waste streams defined by Mayberry, et al. Radiological assessments indicate that a facility, depending on the radioactive material inventory, may be an exempt, Category 3, or Category 2 facility. The calculated impacts would result in no significant impact to offsite personnel or the environment. Hazardous materials assessment indicates that a Mixed Waste Vitrification facility will be a Low Hazard facility having minimal impacts to offsite personnel and the environment.

  12. Remediation of arsenic-contaminated soils and groundwaters

    DOE Patents [OSTI]

    Peters, R.W.; Frank, J.R.; Feng, X.

    1998-06-23T23:59:59.000Z

    An in situ method is described for extraction of arsenic contaminants from a soil medium and remediation of the medium including contacting the medium with an extractant solution, directing the solution within and through the medium, and collecting the solution and contaminants. The method can also be used for arsenate and/or arsenite removal. 8 figs.

  13. Integration of Arsenic Trisulfide and Titanium Diffused Lithium Niobate Waveguides 

    E-Print Network [OSTI]

    Solmaz, Mehmet E.

    2011-08-08T23:59:59.000Z

    A chalcogenide glass (arsenic-trisulfide, As2S3) optical waveguide is vertically integrated onto titanium-diffused lithium-niobate (Ti:LiNbO3) waveguides to add optical feedback paths and to create more compact optical circuits. Lithium...

  14. Adsorption of Arsenic on Polyaluminum Granulate Jasmin Mertens,*,,

    E-Print Network [OSTI]

    Wehrli, Bernhard

    Adsorption of Arsenic on Polyaluminum Granulate Jasmin Mertens,*,, Jerome Rose,§,¶ Ralf Kagi to be meso- and macroporous, with a specific surface area of 35 ± 1 m2 g-1 . Adsorption experiments were-coprecipitation and adsorption processes using iron (Fe)- or aluminum (Al)-based materials are used most frequently to remove As

  15. Spatial and Temporal Variations of Groundwater Arsenic in South and

    E-Print Network [OSTI]

    van Geen, Alexander

    in rural areas throughout the major river basins draining the Himalayas have become the main source. Arsenic enters groundwater naturally from rocks and sediment by coupled biogeochemical and hydrologic population exposed to unsafe As levels by drinking untreated groundwater in India, China, Myanmar, Pakistan

  16. Integration of Arsenic Trisulfide and Titanium Diffused Lithium Niobate Waveguides

    E-Print Network [OSTI]

    Solmaz, Mehmet E.

    2011-08-08T23:59:59.000Z

    A chalcogenide glass (arsenic-trisulfide, As2S3) optical waveguide is vertically integrated onto titanium-diffused lithium-niobate (Ti:LiNbO3) waveguides to add optical feedback paths and to create more compact optical circuits. Lithium...

  17. Investigating the Use of Biosorbents to Remove Arsenic from Water

    E-Print Network [OSTI]

    Erapalli, Shreyas

    2011-02-22T23:59:59.000Z

    , As (III), and arsenate, As (V), from water. Batch reactors were employed to assess the percent removal, reaction kinetics, adsorption capacity, and desorption of each arsenic species onto/from biosorbents under pH buffered and non?buffered conditions...

  18. Remediation of arsenic-contaminated soils and groundwaters

    DOE Patents [OSTI]

    Peters, Robert W. (Naperville, IL); Frank, James R. (Glen Ellyn, IL); Feng, Xiandong (West Richland, WA)

    1998-01-01T23:59:59.000Z

    An in situ method for extraction of arsenic contaminants from a soil medium and remediation of the medium including contacting the medium with an extractant solution, directing the solution within and through the medium, and collecting the solution and contaminants. The method can also be used for arsenate and/or arsenite removal.

  19. Release of Arsenic to the Environment from CCA-Treated

    E-Print Network [OSTI]

    Florida, University of

    Release of Arsenic to the Environment from CCA-Treated Wood. 1. Leaching and Speciation during from in-service chromated copper arsenate (CCA)-treated products and the overall impact to soils and groundwater. To address this issue, two decks were constructed, one from CCA-treated wood and the other from

  20. Arsenic pilot plant operation and results:Weatherford, Oklahoma.

    SciTech Connect (OSTI)

    Aragon, Malynda Jo; Arora, H. (Narasimhan Consulting Services Inc., Phoenix, Arizona); Karori, Saqib (Narasimhan Consulting Services Inc., Phoenix, Arizona); Pathan, Sakib (Narasimhan Consulting Services Inc., Phoenix, Arizona)

    2007-05-01T23:59:59.000Z

    Narasimhan Consulting Services, Inc. (NCS), under a contract with the Sandia National Laboratories (SNL), designed and operated pilot scale evaluations of the adsorption and coagulation/filtration treatment technologies aimed at meeting the recently revised arsenic maximum contaminant level (MCL) for drinking water. The standard of 10 {micro}g/L (10 ppb) is effective as of January 2006. The pilot demonstration is a project of the Arsenic Water Technology Partnership program, a partnership between the American Water Works Association Research Foundation (AwwaRF), SNL and WERC (A Consortium for Environmental Education and Technology Development). The pilot evaluation was conducted at Well 30 of the City of Weatherford, OK, which supplies drinking water to a population of more than 10,400. Well water contained arsenic in the range of 16 to 29 ppb during the study. Four commercially available adsorption media were evaluated side by side for a period of three months. Both adsorption and coagulation/filtration effectively reduced arsenic from Well No.30. A preliminary economic analysis indicated that adsorption using an iron oxide media was more cost effective than the coagulation/ filtration technology.

  1. Characterization and stabilization of arsenic in water treatment residuals

    E-Print Network [OSTI]

    Wee, Hun Young

    2004-11-15T23:59:59.000Z

    -arsenic compounds. However, it is suggested that the ordinary Portland cement (OPC) should be added with the lime for the long term stabilization because lime can be slowly consumed when directly exposed to atmospheric CO2. The solidification and stabilization (S...

  2. Characterization and stabilization of arsenic in water treatment residuals 

    E-Print Network [OSTI]

    Wee, Hun Young

    2004-11-15T23:59:59.000Z

    to be underestimated by the toxicity characteristic leaching test (TCLP) due to the pH of the leachates being favorable for As(V) adsorption. Competitive desorption of arsenic with phosphate was significant because phosphate tends to compete with As(V) on the surface...

  3. Interactions of Arsenic and the Dissolved Substances Derived from

    E-Print Network [OSTI]

    Florida, University of

    As trapping and transport within porous soil media and in developing comprehensive plans for managingInteractions of Arsenic and the Dissolved Substances Derived from Turf Soils Z H A N G R O N G C H University, Miami, Florida 33199, Southeast Environmental Research Center, Florida International University

  4. Bulletin No. 233 Ergonomic Hazards of the

    E-Print Network [OSTI]

    Martin, Jeff

    July, 2004 Bulletin No. 233 Ergonomic Hazards of the Seated Posture Ergonomic Hazards of the Seated it is possible for these injuries to heal themselves when the ergonomic hazard is removed, cases do exist where;PAGE 2 ERGONOMIC HAZARDS of the SEATED POSTURE BULLETIN NO. 233 Ergonomic interventions to reduce

  5. LEARNERS GUIDE FOR RESPONSIBLE HAZARDOUS CHEMICAL WASTE

    E-Print Network [OSTI]

    Portman, Douglas

    1 LEARNERS GUIDE FOR RESPONSIBLE HAZARDOUS CHEMICAL WASTE MANAGEMENT UNIVERSITY OF ROCHESTER the effects of improper hazardous waste management and disposal. Each person who works with hazardous is managed by the Hazardous Waste Management Unit (HWMU) of Facilities and Services. To contact HWMU dial x

  6. Hazard % free free espresso Over Run

    E-Print Network [OSTI]

    Dill, David L.

    Total Products Hazard­ Hazard­ % free free espresso­ Over­ Run­ name in/out Method exact head time 5 0 1 dme­fast­opt 5/3 8 8 0 1 Table 2. Comparison of Hazard­Free Logic Minimization with espresso­level hazard­free minimization prob­ lem for several reasons: the general problem has not pre­ viously been

  7. CONTROL OF HAZARDOUS ENERGY 12.A GENERAL

    E-Print Network [OSTI]

    US Army Corps of Engineers

    EM 385-1-1 XX Jun 13 12-1 SECTION 12 CONTROL OF HAZARDOUS ENERGY 12.A GENERAL 12.A.01 When working on or near any system that produces, uses, or stores hazardous energy, a hazardous energy control program (HECP) is required see 12.B. Hazardous energy is any energy, including but not limited to mechanical (e

  8. GUIDELINES FOR HANDLING HAZARDOUS CHEMICAL WASTE

    E-Print Network [OSTI]

    Tennessee, University of

    GUIDELINES FOR HANDLING HAZARDOUS CHEMICAL WASTE The proper management of hazardous waste and regulatory compliance are achieved: 1. Make sure that no hazardous materials are placed into regular solid in the departmental chemical hygiene plan (CHP) before you begin to use hazardous substances. 3. Make sure you know

  9. Hazardous Materials Alert Departmental Contact(s)

    E-Print Network [OSTI]

    Hickman, Mark

    Hazardous Materials Alert Departmental Contact(s): Name ___________________________________________________________________________________ Hazardous Materials Alert If the release of a hazardous chemical or gas is affecting people in your area yourself at risk. 2. isOlATE the hazardous material by clearing the area, close the doors. If safe to do so

  10. CRAD, Hazardous Waste Management- December 4, 2007

    Broader source: Energy.gov [DOE]

    Hazardous Waste Management Implementation Inspection Criteria, Approach, and Lines of Inquiry (HSS CRAD 64-30)

  11. Arsenic pilot plant operation and results : Anthony, New Mexico.

    SciTech Connect (OSTI)

    Aragon, Malynda Jo; Everett, Randy L.; Siegel, Malcolm Dean; Aragon, Alicia R.; Kottenstette, Richard Joseph; Holub, William E., Jr.; Wright, Jerome L.; Dwyer, Brian P.

    2007-09-01T23:59:59.000Z

    Sandia National Laboratories (SNL) is conducting pilot scale evaluations of the performance and cost of innovative water treatment technologies aimed at meeting the recently revised arsenic maximum contaminant level (MCL) for drinking water. The standard of 10 {micro}g/L (10 ppb) is effective as of January 2006. The pilot tests have been conducted in New Mexico where over 90 sites that exceed the new MCL have been identified by the New Mexico Environment Department. The pilot test described in this report was conducted in Anthony, New Mexico between August 2005 and December 2006 at Desert Sands Mutual Domestic Water Consumers Association (MDWCA) (Desert Sands) Well No.3. The pilot demonstrations are a part of the Arsenic Water Technology Partnership program, a partnership between the American Water Works Association Research Foundation (AwwaRF), SNL and WERC (A Consortium for Environmental Education and Technology Development). The Sandia National Laboratories pilot demonstration at the Desert Sands site obtained arsenic removal performance data for fourteen different adsorptive media under intermittent flow conditions. Well water at Desert Sands has approximately 20 ppb arsenic in the unoxidized (arsenite-As(III)) redox state with moderately high total dissolved solids (TDS), mainly due to high sulfate, chloride, and varying concentrations of iron. The water is slightly alkaline with a pH near 8. The study provides estimates of the capacity (bed volumes until breakthrough at 10 ppb arsenic) of adsorptive media in the same chlorinated water. Adsorptive media were compared side-by-side in ambient pH water with intermittent flow operation. This pilot is broken down into four phases, which occurred sequentially, however the phases overlapped in most cases.

  12. Incorporating Perceived Mortality Risks from Arsenic into Models of Drinking Water Behavior and Valuation of Arsenic Risk Reductions: Preliminary Results

    E-Print Network [OSTI]

    Shaw, W. Douglass

    and estimating values for arsenic reduction risks. Several studies have been undertaken to examine the costs of compliance with the new standard, mainly in the form of capital cost for improved or new public system of Economics Texas A&M University Mark Walker, Associate Professor Dept. of Natural Resource and Environmental

  13. Increasing Resiliency to Natural Hazards: A Strategic Plan for the Multi-Hazards

    E-Print Network [OSTI]

    Fleskes, Joe

    Increasing Resiliency to Natural Hazards: A Strategic Plan for the Multi-Hazards Demonstration Survey #12;#12;Increasing Resiliency to Natural Hazards--A Strategic Plan for the Multi-Hazards on the USGS--the Federal source for science about the Earth, its natural and living resources, natural hazards

  14. Activity Hazard Assessment 6.0 Page 1 of 6 Activity Hazard

    E-Print Network [OSTI]

    Aluwihare, Lihini

    Activity Hazard Assessment 6.0 Page 1 of 6 Activity Hazard Assessment Tool This form must Hazard Assessment specific to activities in their laboratories. The Activity Hazard Assessment identifies hazards to employees and specifies personal protective equipment (PPE) to protect employees during work

  15. Household Hazardous Waste Household hazardous waste is the discarded, unused, or leftover portion of household products

    E-Print Network [OSTI]

    de Lijser, Peter

    over a larger area and releases them into the air. Pouring hazardous liquids on the ground can poisonHousehold Hazardous Waste Household hazardous waste is the discarded, unused, or leftover portion should be considered hazardous. You cannot treat hazardous wastes like other kinds of garbage

  16. SBAT: A Tool for Estimating Metal Bioaccessibility in Soils

    SciTech Connect (OSTI)

    Heuscher, S.A.

    2004-04-21T23:59:59.000Z

    Heavy metals such as chromium and arsenic are widespread in the environment due to their usage in many industrial processes. These metals may pose significant health risks to humans, especially children, due to their mutagenic and carcinogenic properties. Typically, the health risks associated with the ingestion of soil-bound metals are estimated by assuming that the metals are completely absorbed through the human intestinal tract (100% bioavailable). This assumption potentially overestimates the risk since soils are known to strongly sequester metals thereby potentially lowering their bioavailability. Beginning in 2000, researchers at Oak Ridge National Laboratory, with funding from the Strategic Environmental Research and Development Program (SERDP), studied the effect of soil properties on the bioaccessibility of soil-bound arsenic and chromium. Representative A and upper-B horizons from seven major U.S. soil orders were obtained from the U.S. Department of Agriculture's National Resources Conservation Service and the U.S. Department of Energy's Oak Ridge Reservation. The soils were spiked with known concentrations of arsenic (As(III) and As(V)) and chromium (Cr(III) and Cr(VI)), and the bioaccessibility was measured using a physiologically based extraction test that mimics the gastric activity of children. Linear regression models were then developed to relate the bioaccessibility measurements to the soil properties (Yang et al. 2002; Stewart et al. 2003a). Important results from these publications and other studies include: (1) Cr(VI) and As(III) are more toxic and bioavailable than Cr(III) and As(V) respectively. (2) Several favorable processes can occur in soils that promote the oxidation of As(III) to As(V) and the reduction of Cr(VI) to Cr(III), thereby lowering bioaccessibility. Iron and manganese oxides are capable of oxidizing As(III) to As(V), whereas organic matter and Fe(II)-bearing minerals are capable of reducing Cr(VI) to Cr(III). (3) The ubiquitous metal-sequestering properties of soils significantly lower the bioaccessibility of arsenic and chromium upon ingestion relative to the currently used 100% default values. (4) Key soil physical and chemical properties (particle size, pH, mineral oxide, clay, and organic matter contents) govern the extent of toxic metal bioaccessibility thus providing the necessary conceptual understanding for building accurate predictive models. (5) The As(V) regression model was able to predict the in vivo bioavailability in ten contaminated soils within a root mean square error of <10%. (6) Metal bioaccessibility is controlled by molecular-level speciation, where metal sequestration and solid phase stability are enhanced by increased soil-metal contact time.

  17. Stabilization of Electrocatalytic Metal Nanoparticles at Metal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electrocatalytic Metal Nanoparticles at Metal-Metal Oxide-Graphene Triple Junction Points. Stabilization of Electrocatalytic Metal Nanoparticles at Metal-Metal Oxide-Graphene...

  18. Volcano Hazards at Fuego and Acatenango, GuatemalaVolcano Hazards at Fuego and Acatenango, GuatemalaVolcano Hazards at Fuego and Acatenango, GuatemalaVolcano Hazards at Fuego and Acatenango, GuatemalaVolcano Hazards at Fuego and Acatenango, Guatemala 1111

    E-Print Network [OSTI]

    Rose, William I.

    Volcano Hazards at Fuego and Acatenango, GuatemalaVolcano Hazards at Fuego and Acatenango, GuatemalaVolcano Hazards at Fuego and Acatenango, GuatemalaVolcano Hazards at Fuego and Acatenango, GuatemalaVolcano Hazards at Fuego and Acatenango, Guatemala 11111 Open-File Report 01­431Open-File Report 01

  19. Arsenic species and leachability in the fronds of the hyperaccumulator Chinese brake (Pteris vittata L.)

    E-Print Network [OSTI]

    Ma, Lena

    coupled with atomic fluorescence spectrometry. The impacts of air-drying on arsenic species Science Ltd. doi:10.1016/S0269-7491(02)00470-0 Enviro

  20. INTERNAL HAZARDS ANALYSIS FOR LICENSE APPLICATION

    SciTech Connect (OSTI)

    R.J. Garrett

    2005-02-17T23:59:59.000Z

    The purpose of this internal hazards analysis is to identify and document the internal hazards and potential initiating events associated with preclosure operations of the repository at Yucca Mountain. Internal hazards are those hazards presented by the operation of the facility and by its associated processes that can potentially lead to a radioactive release or cause a radiological hazard. In contrast to external hazards, internal hazards do not involve natural phenomena and external man-made hazards. This internal hazards analysis was performed in support of the preclosure safety analysis and the License Application for the Yucca Mountain Project. The methodology for this analysis provides a systematic means to identify internal hazards and potential initiating events that may result in a radiological hazard or radiological release during the repository preclosure period. These hazards are documented in tables of potential internal hazards and potential initiating events (Section 6.6) for input to the repository event sequence categorization process. The results of this analysis will undergo further screening and analysis based on the criteria that apply to the performance of event sequence analyses for the repository preclosure period. The evolving design of the repository will be re-evaluated periodically to ensure that internal hazards that have not been previously evaluated are identified.

  1. In situ remediation process using divalent metal cations

    DOE Patents [OSTI]

    Brady, Patrick V.; Khandaker, Nadim R.; Krumhansl, James L.; Teter, David M.

    2004-12-14T23:59:59.000Z

    An in situ process for treating ambient solid materials (e.g., soils, aquifer solids, sludges) by adding one or more divalent metal cations to the ambient solid material. The added divalent metal cations, such as Cu.sup.2+ or Zn.sup.2+, combine with metal oxide/hydroxides (e.g., ferric oxide/hydroxide or aluminum oxide/hydroxide) already present in the ambient solid material to form an effective sorbent material having a large number of positively-charged surface complexes that binds and immobilizes anionic contaminant species (e.g., arsenic or chromate). Divalent metal cations can be added, for example, by injecting an aqueous solution of CuSO.sub.4 into an aquifer contaminated with arsenic or chromate. Also, sludges can be stabilized against leaching of anionic contaminants through the addition of divalent metal cations. Also, an inexpensive sorbent material can be easily formed by mixing divalent metal cations with soil that has been removed from the ground.

  2. Recovery of non-ferrous metals from smelter flue dusts and sludges

    SciTech Connect (OSTI)

    Bartlett, R.W.

    1993-08-10T23:59:59.000Z

    A method is described for treating a smelter by-product so as to recover copper, nickel, zinc, an cobalt metal therefrom and convert any arsenic and sulfur in the smelter by-product into non-leachable forms of arsenic and sulfur, the method comprising: (a) mixing the smelter by-product with hydrated lime to form a paste; (b) forming the paste into agglomerates, (c) roasting the agglomerates in air at a temperature sufficient to oxidize the arsenic and sulfur therein and cause said oxidized arsenic and sulfur to react with the lime in the agglomerates to form non-leachable arsenic-containing and sulfur-containing calcium compounds within the roasted agglomerates; and (d) contacting the roasted agglomerates with a basic aqueous lixiviant solution comprising dissolved ammonia and an ammonium salt so as to dissolve copper, nickel, zinc and cobalt from the roasted agglomerates into the lixiviant solution, thereby converting the lixiviant solution to a pregnant liquor enriched in said copper, nickel, zinc and cobalt.

  3. Metal hydrides as electrode/catalyst materials for oxygen evolution/reduction in electrochemical devices

    DOE Patents [OSTI]

    Bugga, Ratnakumar V. (Arcadia, CA); Halpert, Gerald (Pasadena, CA); Fultz, Brent (Pasadena, CA); Witham, Charles K. (Pasadena, CA); Bowman, Robert C. (La Mesa, CA); Hightower, Adrian (Whittier, CA)

    1997-01-01T23:59:59.000Z

    An at least ternary metal alloy of the formula, AB.sub.(5-Y)X(.sub.y), is claimed. In this formula, A is selected from the rare earth elements, B is selected from the elements of groups 8, 9, and 10 of the periodic table of the elements, and X includes at least one of the following: antimony, arsenic, and bismuth. Ternary or higher-order substitutions, to the base AB.sub.5 alloys, that form strong kinetic interactions with the predominant metals in the base metal hydride are used to form metal alloys with high structural integrity after multiple cycles of hydrogen sorption.

  4. Removing Arsenic from Contaminated Drinking Water in Rural Bangladesh: Recent Fieldwork Results and Policy Implications

    SciTech Connect (OSTI)

    Mathieu, Johanna L.; Gadgil, Ashok J.; Kowolik, Kristin; Addy, Susan E.A.

    2009-09-17T23:59:59.000Z

    ARUBA (Arsenic Removal Using Bottom Ash) has proven effective at removing high concentrations of arsenic from drinking water in Bangladesh. During fieldwork in four sub-districts of the country, ARUBA reduced arsenic levels ranging from 200 to 900 ppb to below the Bangladesh standard of 50 ppb. The technology is cost-effective because the substrate--bottom ash from coal fired power plants--is a waste material readily available in South Asia. In comparison to similar technologies, ARUBA uses less media for arsenic removal due to its high surface area to volume ratio. Hence, less waste is produced. A number of experiments were conducted in Bangladesh to determine the effectiveness of various water treatment protocols. It was found that (1) ARUBA removes more than half of the arsenic from water within five minutes of treatment, (2) ARUBA, that has settled at the bottom of a treatment vessel, continues to remove arsenic for 2-3 days, (3) ARUBA's arsenic removal efficiency can be improved through sequential partial dosing (adding a given amount of ARUBA in fractions versus all at once), and (4) allowing water to first stand for two to three days followed by treatment with ARUBA produced final arsenic levels ten times lower than treating water directly out of the well. Our findings imply a number of tradeoffs between ARUBA's effective arsenic removal capacity, treatment system costs, and waste output. These tradeoffs, some a function of arsenic-related policies in Bangladesh (e.g., waste disposal regulations), must be considered when designing an arsenic removal system. We propose that the most attractive option is to use ARUBA in communityscale water treatment centers, installed as public-private partnerships, in Bangladeshi villages.

  5. Sulfide-Driven Arsenic Mobilization from Arsenopyrite and Black Shale Pyrite

    SciTech Connect (OSTI)

    Zhu, W.; Young, L; Yee, N; Serfes, M; Rhine, E; Reinfelder, J

    2008-01-01T23:59:59.000Z

    We examined the hypothesis that sulfide drives arsenic mobilization from pyritic black shale by a sulfide-arsenide exchange and oxidation reaction in which sulfide replaces arsenic in arsenopyrite forming pyrite, and arsenide (As-1) is concurrently oxidized to soluble arsenite (As+3). This hypothesis was tested in a series of sulfide-arsenide exchange experiments with arsenopyrite (FeAsS), homogenized black shale from the Newark Basin (Lockatong formation), and pyrite isolated from Newark Basin black shale incubated under oxic (21% O2), hypoxic (2% O2, 98% N2), and anoxic (5% H2, 95% N2) conditions. The oxidation state of arsenic in Newark Basin black shale pyrite was determined using X-ray absorption-near edge structure spectroscopy (XANES). Incubation results show that sulfide (1 mM initial concentration) increases arsenic mobilization to the dissolved phase from all three solids under oxic and hypoxic, but not anoxic conditions. Indeed under oxic and hypoxic conditions, the presence of sulfide resulted in the mobilization in 48 h of 13-16 times more arsenic from arsenopyrite and 6-11 times more arsenic from isolated black shale pyrite than in sulfide-free controls. XANES results show that arsenic in Newark Basin black shale pyrite has the same oxidation state as that in FeAsS (-1) and thus extend the sulfide-arsenide exchange mechanism of arsenic mobilization to sedimentary rock, black shale pyrite. Biologically active incubations of whole black shale and its resident microorganisms under sulfate reducing conditions resulted in sevenfold higher mobilization of soluble arsenic than sterile controls. Taken together, our results indicate that sulfide-driven arsenic mobilization would be most important under conditions of redox disequilibrium, such as when sulfate-reducing bacteria release sulfide into oxic groundwater, and that microbial sulfide production is expected to enhance arsenic mobilization in sedimentary rock aquifers with major pyrite-bearing, black shale formations.

  6. Design of a rural water provision system to decrease arsenic exposure in Bangladesh

    SciTech Connect (OSTI)

    Mathieu, Johanna

    2009-01-07T23:59:59.000Z

    Researchers at the Lawrence Berkeley National Laboratory have invented ARUBA (Arsenic Removal Using Bottom Ash) a material that effectively and affordably removes high concentrations of arsenic from contaminated groundwater. The technology is cost-effective because the substrate?bottom ash from coal fired power plants?is a waste material readily available in South Asia. During fieldwork in four sub-districts ofBangladesh, ARUBA reduced groundwater arsenic concentrations as high as 680 ppb to below the Bangladesh standard of 50 ppb. Key results from three trips in Bangladesh and one trip to Cambodia include (1) ARUBA removes more than half of the arsenic from contaminated water within the first five minutes of contact, andcontinues removing arsenic for 2-3 days; (2) ARUBA?s arsenic removal efficiency can be improved through fractionated dosing (adding a given amount of ARUBA in fractions versus all at once); (3) allowing water to first stand for two to three days followed by treatment with ARUBA produced final arsenic concentrations ten times lower than treating water directly out of the well; and (4) the amount of arsenic removed per gram of ARUBA is linearly related to the initial arsenic concentrationof the water. Through analysis of existing studies, observations, and informal interviews in Bangladesh, eight design strategies have been developed and used in the design of a low-cost, community-scale water treatment system that uses ARUBA to remove arsenic from drinking water. We have constructed, tested, and analyzed a scale version of the system. Experiments have shown that the system is capable of reducing high levels of arsenic (nearly 600 ppb) to below 50 ppb, while remaining affordable to people living on less than $2 per day. The system could be sustainably implemented as a public-private partnership in rural Bangladesh.

  7. Assessing Arsenic Removal By Zero-Valent Iron Under

    E-Print Network [OSTI]

    6 8 10 12 14 ­.5 0 .5 1 pH Eh(volts) SO4 -- HS - H2S(aq) HSO4 - 20°C Dell Fri Feb 08 2008 DiagramSO4Assessing Arsenic Removal By Zero-Valent Iron Under Various Water Quality Conditions Paul Pepler and operate. #12;7 Best Available Technologies for As Removal (USEPA 2003) Ion exchange Activated alumina

  8. A Green Laser Pointer Hazard

    E-Print Network [OSTI]

    Jemellie Galang; Allesandro Restelli; Edward W. Hagley; Charles W. Clark

    2010-08-09T23:59:59.000Z

    An inexpensive green laser pointer was found to emit 20 mW of infrared radiation during normal use. This is potentially a serious hazard that would not be noticed by most users of such pointers. We find that this infrared emission derives from the design of the pointer, and describe a simple method of testing for infrared emissions using common household items.

  9. Title III hazardous air pollutants

    SciTech Connect (OSTI)

    Todd, R.

    1995-12-31T23:59:59.000Z

    The author presents an overview of the key provisions of Title III of the Clean Air Act Amendments of 1990. The key provisions include the following: 112(b) -- 189 Hazardous Air Pollutants (HAP); 112(a) -- Major Source: 10 TPY/25 TPY; 112(d) -- Application of MACT; 112(g) -- Modifications; 112(I) -- State Program; 112(j) -- The Hammer; and 112(r) -- Accidental Release Provisions.

  10. WHC fire hazards analysis policy

    SciTech Connect (OSTI)

    Evans, C.B.

    1994-04-01T23:59:59.000Z

    The purpose of this document is to establish the fire protection policy for Westinghouse Hanford Company (WHC) relative to US Department of Energy (DOE) directives for Fire Hazards Analyses (FHAs) and their relationship to facility Safety Analysis Reports (SARs) as promulgated by the DOE Richland Operations Office.

  11. Abatement of Air Pollution: Hazardous Air Pollutants (Connecticut...

    Broader source: Energy.gov (indexed) [DOE]

    allowable stack concentrations and hazard limiting values for the emission of hazardous air pollutants. The regulations also discuss sampling procedures for hazardous air...

  12. Chlorine Gas: An Evolving Hazardous Material Threat and Unconventional Weapon

    E-Print Network [OSTI]

    Jones, Robert; Wills, Brandon; Kang, Christopher

    2010-01-01T23:59:59.000Z

    Chlorine Gas: An Evolving Hazardous Material Threat andChlorine gas represents a hazardous material threat fromrepresents a persistent hazardous material (HAZMAT) threat.

  13. Association between As and Cu renal cortex accumulation and physiological and histological alterations after chronic arsenic intake

    SciTech Connect (OSTI)

    Rubatto Birri, Paolo N. [Instituto de Biologia Celular, Facultad de Ciencias Medicas (FCM), Universidad Nacional de Cordoba (UNC), Ciudad Universitaria, Cordoba (Argentina)] [Instituto de Biologia Celular, Facultad de Ciencias Medicas (FCM), Universidad Nacional de Cordoba (UNC), Ciudad Universitaria, Cordoba (Argentina); Perez, Roberto D. [Facultad de Matematica, Astronomia y Fisica (FAMAF-UNC), Ciudad Universitaria, Cordoba (Argentina) [Facultad de Matematica, Astronomia y Fisica (FAMAF-UNC), Ciudad Universitaria, Cordoba (Argentina); Consejo Nacional de Investigaciones Cientificas y Tecnologicas (CONICET), Buenos Aires (Argentina); Cremonezzi, David [Catedra Anatomia Patologica, Hospital Nacional de Clinicas (FCM-UNC), Cordoba (Argentina)] [Catedra Anatomia Patologica, Hospital Nacional de Clinicas (FCM-UNC), Cordoba (Argentina); Perez, Carlos A. [Laboratorio Nacional de Luz Sincrotron (LNLS), Linha D09B-XRF, Campinas SP (Brazil)] [Laboratorio Nacional de Luz Sincrotron (LNLS), Linha D09B-XRF, Campinas SP (Brazil); Rubio, Marcelo [Facultad de Matematica, Astronomia y Fisica (FAMAF-UNC), Ciudad Universitaria, Cordoba (Argentina) [Facultad de Matematica, Astronomia y Fisica (FAMAF-UNC), Ciudad Universitaria, Cordoba (Argentina); Consejo Nacional de Investigaciones Cientificas y Tecnologicas (CONICET), Buenos Aires (Argentina); Bongiovanni, Guillermina A., E-mail: gbongiovanni@conicet.gov.ar [Consejo Nacional de Investigaciones Cientificas y Tecnologicas (CONICET), Buenos Aires (Argentina); Laboratorio de Investigaciones Bioquimicas, Quimicas y de Medio Ambiente (LIBIQUIMA), Consejo Nacional de Investigaciones Cientificas y Tecnologicas (CONICET), Universidad Nacional del Comahue, Buenos Aires 1400, CP 8300 Neuquen (Argentina)

    2010-07-15T23:59:59.000Z

    Arsenic (As) is one of the most abundant hazards in the environment and it is a human carcinogen. Related to excretory functions, the kidneys in humans, animal models or naturally exposed fauna, are target organs for As accumulation and deleterious effects. Previous studies carried out using X-ray fluorescence spectrometry by synchrotron radiation (SR-{mu}XRF) showed a high concentration of As in the renal cortex of chronically exposed rats, suggesting that this is a suitable model for studies on renal As accumulation. This accumulation was accompanied by a significant increase in copper (Cu) concentration. The present study focused on the localization of these elements in the renal cortex and their correlation with physiological and histological As-related renal effects. Experiments were performed on nine male Wistar rats, divided into three experimental groups. Two groups received 100 {mu}g/ml sodium arsenite in drinking water for 60 and 120 consecutive days, respectively. The control group received water without sodium arsenite (<50 ppb As). For histological analysis, 5-{mu}m-thick sections of kidneys were stained with hematoxylin and eosin. Biochemical analyses were used to determine concentrations of plasma urea and creatinine. The As and Cu mapping were carried out by SR-{mu}XRF using a collimated white synchrotron spectrum (300 {mu}mx300 {mu}m) on kidney slices (2 mm thick) showing As and Cu co-distribution in the renal cortex. Then, renal cortical slices (100 {mu}m thick) were scanned with a focused white synchrotron spectrum (30 {mu}mx30 {mu}m). Peri-glomerular accumulation of As and Cu at 60 and 120 days was found. The effects of 60 days of arsenic consumption were seen in a decreased Bowman's space as well as a decreased plasma blood urea nitrogen (BUN)/creatinine ratio. Major deleterious effects; however, were seen on tubules at 120 days of exposition. This study supports the hypothesis that tubular accumulation of As-Cu may have some bearing on the arsenic-associated nephrotoxicological process.

  14. Owning Hazard, A Tragedy Barbara Young Welke*

    E-Print Network [OSTI]

    Barrett, Jeffrey A.

    693 Owning Hazard, A Tragedy Barbara Young Welke* In Memory of Frances Young Welke (March 21, 1992 in the ownership of hazard from the individuals who suffered injury, to the enterprises involved in manufacturing

  15. Georgia Hazardous Site Response Act (Georgia)

    Broader source: Energy.gov [DOE]

    The Georgia Hazardous Site Response Act is Georgia’s version of Superfund. The Act provides for graduated fees on the disposal of hazardous waste, a trust fund to enable the EPD to clean up or plan...

  16. Massachusetts Hazardous Waste Management Act (Massachusetts)

    Broader source: Energy.gov [DOE]

    This Act contains regulations for safe disposal of hazardous waste, and establishes that a valid license is required to collect, transport, store, treat, use, or dispose of hazardous waste. Short...

  17. Oklahoma Hazardous Waste Management Act (Oklahoma)

    Broader source: Energy.gov [DOE]

    A hazardous waste facility permit from the Department of Environmental Quality is required to store, treat or dispose of hazardous waste materials, or to construct, own or operate any facility...

  18. What is the Role of Arsenite-Oxidising Bacteria in Dissolving Arsenic Minerals?

    E-Print Network [OSTI]

    Crawford, Ian

    What is the Role of Arsenite-Oxidising Bacteria in Dissolving Arsenic Minerals? Supervisors: Dr through dissolution of arsenic-bearing minerals. This process is mediated by bacteria, which can break down the mineral lattice by extracting nutrient elements such as potassium, or by causing redox changes

  19. Natural arsenic contamination of Holocene alluvial aquifers by linked tectonic, weathering, and microbial processes

    E-Print Network [OSTI]

    Fayek, Mostafa

    Natural arsenic contamination of Holocene alluvial aquifers by linked tectonic, weathering tectonic, geochemical, and biologic processes lead to natural arsenic contamination of groundwater-bearing minerals occurs. We propose a ``GBH-As'' model that ties together all of the important tectonic, biologic

  20. Determination of Arsenic Poisoning and Metabolism in Hair by Synchrotron Radiation: The Case of Phar Lap

    SciTech Connect (OSTI)

    Kempson, Ivan M.; Henry, Dermot A. (Museum Vic.); (U. South Australia)

    2010-08-26T23:59:59.000Z

    Fresh physical evidence about the demise of the racehorse Phar Lap (see photograph) has been gathered from the study of mane hair samples by synchrotron radiation analysis with high resolution X-ray fluorescence (XRF) and X-ray absorption near edge structure (XANES) analyses. The results are indicative of arsenic ingestion and metabolism, and show that the racing champion died from arsenic poisoning.

  1. Arsenic-induced alteration in the expression of genes related to type 2 diabetes mellitus

    SciTech Connect (OSTI)

    Diaz-Villasenor, Andrea [Department of Genomic Medicine and Environmental Toxicology, Instituto de Investigaciones Biomedicas, Universidad Nacional Autonoma de Mexico, Circuito Escolar, Cd. Universitaria, Coyoacan 04510 Mexico, DF (Mexico)], E-mail: andreadv@biomedicas.unam.mx; Burns, Anna L. [Department of Genomic Medicine and Environmental Toxicology, Instituto de Investigaciones Biomedicas, Universidad Nacional Autonoma de Mexico, Circuito Escolar, Cd. Universitaria, Coyoacan 04510 Mexico, DF (Mexico); Facultad de Medicina, Universidad Nacional Autonoma de Mexico (Mexico); Hiriart, Marcia [Department of Biophysics, Instituto de Fisiologia Celular, Universidad Nacional Autonoma de Mexico (Mexico); Cebrian, Mariano E. [Seccion Externa de Toxicologia, CINVESTAV, IPN (Mexico); Ostrosky-Wegman, Patricia [Department of Genomic Medicine and Environmental Toxicology, Instituto de Investigaciones Biomedicas, Universidad Nacional Autonoma de Mexico, Circuito Escolar, Cd. Universitaria, Coyoacan 04510 Mexico, DF (Mexico)

    2007-12-01T23:59:59.000Z

    Chronic exposure to high concentrations of arsenic in drinking water is associated with an increased risk for developing type 2 diabetes. The present revision focuses on the effect of arsenic on tissues that participate directly in glucose homeostasis, integrating the most important published information about the impairment of the expression of genes related to type 2 diabetes by arsenic as one of the possible mechanisms by which it leads to the disease. Many factors are involved in the manner in which arsenic contributes to the occurrence of diabetes. The reviewed studies suggest that arsenic might increase the risk for type 2 diabetes via multiple mechanisms, affecting a cluster of regulated events, which in conjunction trigger the disease. Arsenic affects insulin sensitivity in peripheral tissue by modifying the expression of genes involved in insulin resistance and shifting away cells from differentiation to the proliferation pathway. In the liver arsenic disturbs glucose production, whereas in pancreatic beta-cells arsenic decreases insulin synthesis and secretion and reduces the expression of antioxidant enzymes. The consequences of these changes in gene expression include the reduction of insulin secretion, induction of oxidative stress in the pancreas, alteration of gluconeogenesis, abnormal proliferation and differentiation pattern of muscle and adipocytes as well as peripheral insulin resistance.

  2. DESIGN OF A RURAL WATER PROVISION SYSTEM TO DECREASE ARSENIC EXPOSURE IN BANGLADESH

    E-Print Network [OSTI]

    Agogino, Alice M.

    in fractions versus all at once); (3) allowing water to first stand for two to three days followed by treatment with ARUBA produced final arsenic concentrations ten times lower than treating water directly out of the well-scale water treatment system that uses ARUBA to remove arsenic from drinking water. We have constructed

  3. Quantities of Arsenic-Treated Wood in Demolition Debris Generated by

    E-Print Network [OSTI]

    Florida, University of

    Research Quantities of Arsenic-Treated Wood in Demolition Debris Generated by Hurricane Katrina B R of the demolition debris is wood waste of which a significant proportion is treated with preservatives, including preservatives containing arsenic. As a result of the large scale destruction of treated wood structures

  4. Use of handheld X-ray fluorescence spectrometry units for identification of arsenic in treated wood

    E-Print Network [OSTI]

    Florida, University of

    ; accepted 19 November 2006 Handheld XRF analyzers provided quantitative results for the amount of arsenic of handheld XRF analyzers on wood that has been treated with a preservative containing arsenic. Experiments of the XRF ar- senic readings. Results showed that the precision of the XRF improved with increased sample

  5. D-Area Preliminary Hazards Analysis

    SciTech Connect (OSTI)

    Blanchard, A. [Westinghouse Savannah River Company, AIKEN, SC (United States); Paik, I.R. [Westinghouse Safety Management Solutions, , ()

    1998-04-01T23:59:59.000Z

    A comprehensive review of hazards associated with the D-Area was performed to identify postulated event scenarios.

  6. CONTROL OF HAZARDOUS ENERGY Table Of Contents

    E-Print Network [OSTI]

    US Army Corps of Engineers

    EM 385-1-1 XX Sep 13 i Section 12 CONTROL OF HAZARDOUS ENERGY Table Of Contents Section: Page 12.A General.................. .............................................. ... .12-1 12.B Hazardous Energy.......................................................12-6 #12;EM 385-1-1 XX Sep 13 12-1 SECTION 12 CONTROL OF HAZARDOUS ENERGY 12.A GENERAL 12.A.01 When

  7. Hazard & Disaster Management College of Science

    E-Print Network [OSTI]

    Hickman, Mark

    Hazard & Disaster Management College of Science 09 For further information about the University Postgraduate Programmes #12;PostgraduateProgrammes in Hazard & Disaster Management Postgraduate Diploma - BSc by risk management. These programmes aim to develop skills of hazard and disaster management through

  8. Hazard Communication Program 1.0 REFERENCE

    E-Print Network [OSTI]

    de Lijser, Peter

    Hazard Communication Program 1.0 REFERENCE California Code of Regulations, Title 8, Sections 337 the properties and potential safety and health hazards of the materials which they use or to which they are exposed. Employees who use or may be exposed to potentially hazardous substances or harmful physical

  9. University of Florida Hazard Communication Program

    E-Print Network [OSTI]

    Slatton, Clint

    in the following areas with regard to the inventoried hazardous chemicals to which I am exposed: a. The chemical involving them in my work area. c. The proper and safe handling of the hazardous chemicals. d. The location chemicals. f. The physical and health hazards of the chemicals in my work area. g. Methods to protect myself

  10. Predicting arsenic concentrations in porewaters of buried uranium mill tailings

    SciTech Connect (OSTI)

    Langmuir, D.; Mahoney, J.; MacDonald, A.; Rowson, J.

    1999-10-01T23:59:59.000Z

    The proposed JEB Tailings Management Facility (TMF) to be emplaced below the groundwater table in northern Saskatchewan, Canada, will contain uranium mill tailings from McClean Lake, Midwest and Cigar Lake ore bodies, which are high in arsenic (up to 10%) and nickel (up to 5%). A serious concern is the possibility that high arsenic and nickel concentrations may be released from the buried tailings, contaminating adjacent groundwaters and a nearby lake. Laboratory tests and geochemical modeling were performed to examine ways to reduce the arsenic and nickel concentrations in TMF porewaters so as to minimize such contamination from tailings buried for 50 years and longer. The tests were designed to mimic conditions in the mill neutralization circuit (3 hr tests at 25 C), and in the TMF after burial (5--49 day aging tests). The aging tests were run at 50, 25 and 4 C (the temperature in the TMF). In order to optimize the removal of arsenic by adsorption and precipitation, ferric sulfate was added to tailings raffinates having Fe/As ratios of less than 3--5. The acid raffinates were then neutralized by addition of slaked lime to nominal pH values of 7, 8, or 9. Analysis and modeling of the test results showed that with slaked lime addition to acid tailings raffinates, relatively amorphous scorodite (ferric arsenate) precipitates near pH 1, and is the dominant form of arsenate in slake limed tailings solids except those high in Ni and As and low in Fe, in which cabrerite-annabergite (Ni, Mg, Fe(II) arsenate) may also precipitate near pH 5--6. In addition to the arsenate precipitates, smaller amounts of arsenate are also adsorbed onto tailings solids. The aging tests showed that after burial of the tailings, arsenic concentrations may increase with time from the breakdown of the arsenate phases (chiefly scorodite). However, the tests indicate that the rate of change decreases and approaches zero after 72 hrs at 25 C, and may equal zero at all times in the TMF at 4 C. Consistent with a kinetic model that describes the rate of breakdown of scorodite to form hydrous ferric oxide, the rate of release of dissolved arsenate to tailings porewaters from slake limed tailings: (1) is proportional to pH above pH 6--7; (2) decreases exponentially as the total molar Fe/As ratio of tailings raffinates is increased from 1/1 to greater than 5/1; and (3) is proportional to temperature with an average Arrhenius activation energy of 13.4 {+-} 4.2 kcal/mol. Study results suggest that if ferric sulfate and slaked lime are added in the tailings neutralization circuit to give a raffinate Fe/As molar ratio of at least 3--5 and a nominal (initial) pH of 8 (final pH of 7--8), arsenic and nickel concentrations of 2 mg/L or less, are probable in porewaters of individual tailings in the TMF for 50 to 10,000 yrs after tailings disposal. However, the tailings will be mixed in the TMF, which will contain about 35% tailings with Fe/As = 3.0, and 65% tailings with Fe/As = 5.0--7.7. Thus, it seems likely that average arsenic pore water concentrations in the TMF may not exceed 1 mg/L.

  11. Focus Sheet | Hazardous Waste Checklist How to be ready for state hazardous waste

    E-Print Network [OSTI]

    Wilcock, William

    storage cabinet. Avoid accumulating a lot of waste ­ keep areas clear. EPO ­ Hazardous Waste Checklist 07Focus Sheet | Hazardous Waste Checklist How to be ready for state hazardous waste inspectors. See a hazardous waste inspection. ons, rrosive. n hemicals? ical waste. Waste-like chemicals have als Are you

  12. HAZARDOUS DRUG SAFETY AND HEALTH PLAN FOR HANDLING ANTINEOPLASTIC OTHER HAZARDOUS DRUGS IN CLINICAL ENVIRONMENTS

    E-Print Network [OSTI]

    Kim, Duck O.

    containers, pickup hazardous drug waste and provide chemo spill kits to appropriate areas. The OfficeHAZARDOUS DRUG SAFETY AND HEALTH PLAN FOR HANDLING ANTINEOPLASTIC AND OTHER HAZARDOUS DRUGS, administration and disposal of drug residues. Drugs are classified as hazardous if studies in animals and

  13. ElectroChemical Arsenic Removal (ECAR) for Rural Bangladesh--Merging Technology with Sustainable Implementation

    SciTech Connect (OSTI)

    Addy, Susan E.A.; Gadgil, Ashok J.; Kowolik, Kristin; Kostecki, Robert

    2009-12-01T23:59:59.000Z

    Today, 35-77 million Bangladeshis drink arsenic-contaminated groundwater from shallow tube wells. Arsenic remediation efforts have focused on the development and dissemination of household filters that frequently fall into disuse due to the amount of attention and maintenance that they require. A community scale clean water center has many advantages over household filters and allows for both chemical and electricity-based technologies to be beneficial to rural areas. Full cost recovery would enable the treatment center to be sustainable over time. ElectroChemical Arsenic Remediation (ECAR) is compatible with community scale water treatment for rural Bangladesh. We demonstrate the ability of ECAR to reduce arsenic levels> 500 ppb to less than 10 ppb in synthetic and real Bangladesh groundwater samples and examine the influence of several operating parameters on arsenic removal effectiveness. Operating cost and waste estimates are provided. Policy implication recommendations that encourage sustainable community treatment centers are discussed.

  14. Health burden of skin lesions at low arsenic exposure through groundwater in Pakistan. Is river the source?

    SciTech Connect (OSTI)

    Fatmi, Zafar, E-mail: zafar.fatmi@aku.edu [Department of Community Health Sciences, Aga Khan University, Stadium Road, P.O. Box 3500, Karachi (Pakistan)] [Department of Community Health Sciences, Aga Khan University, Stadium Road, P.O. Box 3500, Karachi (Pakistan); Azam, Iqbal; Ahmed, Faiza; Kazi, Ambreen; Gill, Albert Bruce; Kadir, Muhmmad Masood; Ahmed, Mubashir; Ara, Naseem; Janjua, Naveed Zafar [Department of Community Health Sciences, Aga Khan University, Stadium Road, P.O. Box 3500, Karachi (Pakistan)] [Department of Community Health Sciences, Aga Khan University, Stadium Road, P.O. Box 3500, Karachi (Pakistan)

    2009-07-15T23:59:59.000Z

    A significant proportion of groundwater in south Asia is contaminated with arsenic. Pakistan has low levels of arsenic in groundwater compared with China, Bangladesh and India. A representative multi-stage cluster survey conducted among 3874 persons {>=}15 years of age to determine the prevalence of arsenic skin lesions, its relation with arsenic levels and cumulative arsenic dose in drinking water in a rural district (population: 1.82 million) in Pakistan. Spot-urine arsenic levels were compared among individuals with and without arsenic skin lesions. In addition, the relation of age, body mass index, smoking status with arsenic skin lesions was determined. The geographical distribution of the skin lesions and arsenic-contaminated wells in the district were ascertained using global positioning system. The total arsenic, inorganic and organic forms, in water and spot-urine samples were determined by atomic absorption spectrophotometry. The prevalence of skin lesions of arsenic was estimated for complex survey design, using surveyfreq and surveylogistic options of SAS 9.1 software.The prevalence of definitive cases i.e. hyperkeratosis of both palms and soles, was 3.4 per 1000 and suspected cases i.e. any sign of arsenic skin lesions (melanosis and/or keratosis), were 13.0 per 1000 among {>=}15-year-old persons in the district. Cumulative arsenic exposure (dose) was calculated from levels of arsenic in water and duration of use of current drinking water source. Prevalence of skin lesions increases with cumulative arsenic exposure (dose) in drinking water and arsenic levels in urine. Skin lesions were 2.5-fold among individuals with BMI <18.5 kg/m{sup 2}. Geographically, more arsenic-contaminated wells and skin lesions were alongside Indus River, suggests a strong link between arsenic contamination of groundwater with proximity to river.This is the first reported epidemiological and clinical evidence of arsenic skin lesions due to groundwater in Pakistan. Further investigations and focal mitigation measures for arsenic may be carried out alongside Indus River.

  15. Metal aminoboranes

    DOE Patents [OSTI]

    Burrell, Anthony K.; Davis, Benjamin J.; Thorn, David L.; Gordon, John C.; Baker, R. Thomas; Semelsberger, Troy Allen; Tumas, William; Diyabalanage, Himashinie Vichalya; Shrestha, Roshan P.

    2010-05-11T23:59:59.000Z

    Metal aminoboranes of the formula M(NH2BH3)n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other metal aminoboranes. Metal aminoboranes can be dehydrogenated to form hydrogen and a reaction product. The reaction product can react with hydrogen to form a hydrogen storage material. Metal aminoboranes can be included in a kit.

  16. Hazard Avoidance in Wireless Sensor and Actor Networks

    E-Print Network [OSTI]

    Sivakumar, Raghupathy

    Hazard Avoidance in Wireless Sensor and Actor Networks Ramanuja Vedantham Zhenyun Zhuang Prof [Akyildiz'04] Network Low bandwidth (Hazards Hazards undesirable changes in the environment Reason for hazards Different latencies For different sensors and actors

  17. Characterization and Transcription of Arsenic Respiration and Resistance Genes During In Situ Uranium Bioremediation

    SciTech Connect (OSTI)

    Giloteaux, L.; Holmes, Dawn E.; Williams, Kenneth H.; Wrighton, Kelly C.; Wilkins, Michael J.; Montgomery, Alison P.; Smith, Jessica A.; Orellana, Roberto; Thompson, Courtney A.; Roper, Thomas J.; Long, Philip E.; Lovley, Derek R.

    2013-02-04T23:59:59.000Z

    The possibility of arsenic release and the potential role of Geobacter in arsenic biogeochemistry during in situ uranium bioremediation was investigated because increased availability of organic matter has been associated with substantial releases of arsenic in other subsurface environments. In a field experiment conducted at the Rifle, CO study site, groundwater arsenic concentrations increased when acetate was added. The number of transcripts from arrA, which codes for the alpha subunit of dissimilatory As(V) reductase, and acr3, which codes for the arsenic pump protein Acr3, were determined with quantitative RT-PCR. Most of the arrA (> 60%) and acr3-1 (> 90%) sequences that were recovered were most similar to Geobacter species, while the majority of acr3-2 (>50%) sequences were most closely related to Rhodoferax ferrireducens. Analysis of transcript abundance demonstrated that transcription of acr3-1 by the subsurface Geobacter community was correlated with arsenic concentrations in the groundwater. In contrast, Geobacter arrA transcript numbers lagged behind the major arsenic release and remained high even after arsenic concentrations declined. This suggested that factors other than As(V) availability regulated transcription of arrA in situ even though the presence of As(V) increased transcription of arrA in cultures of G. lovleyi, which was capable of As(V) reduction. These results demonstrate that subsurface Geobacter species can tightly regulate their physiological response to changes in groundwater arsenic concentrations. The transcriptomic approach developed here should be useful for the study of a diversity of other environments in which Geobacter species are considered to have an important influence on arsenic biogeochemistry.

  18. Canister Storage Building (CSB) Hazard Analysis Report

    SciTech Connect (OSTI)

    POWERS, T.B.

    2000-03-16T23:59:59.000Z

    This report describes the methodology used in conducting the Canister Storage Building (CSB) Hazard Analysis to support the final CSB Safety Analysis Report and documents the results. This report describes the methodology used in conducting the Canister Storage Building (CSB) hazard analysis to support the CSB final safety analysis report (FSAR) and documents the results. The hazard analysis process identified hazardous conditions and material-at-risk, determined causes for potential accidents, identified preventive and mitigative features, and qualitatively estimated the frequencies and consequences of specific occurrences. The hazard analysis was performed by a team of cognizant CSB operations and design personnel, safety analysts familiar with the CSB, and technical experts in specialty areas. The material included in this report documents the final state of a nearly two-year long process. Attachment A provides two lists of hazard analysis team members and describes the background and experience of each. The first list is a complete list of the hazard analysis team members that have been involved over the two-year long process. The second list is a subset of the first list and consists of those hazard analysis team members that reviewed and agreed to the final hazard analysis documentation. The material included in this report documents the final state of a nearly two-year long process involving formal facilitated group sessions and independent hazard and accident analysis work. The hazard analysis process led to the selection of candidate accidents for further quantitative analysis. New information relative to the hazards, discovered during the accident analysis, was incorporated into the hazard analysis data in order to compile a complete profile of facility hazards. Through this process, the results of the hazard and accident analyses led directly to the identification of safety structures, systems, and components, technical safety requirements, and other controls required to protect the public, workers, and environment.

  19. Detection device for hazardous materials

    DOE Patents [OSTI]

    Partin, Judy K.; Grey, Alan E.

    1994-04-05T23:59:59.000Z

    A detection device that is activated by the interaction of a hazardous chcal with a coating interactive with said chemical on an optical fiber thereby reducing the amount of light passing through the fiber to a light detector. A combination of optical filters separates the light into a signal beam and a reference beam which after detection, appropriate amplification, and comparison with preset internal signals, activates an alarm means if a predetermined level of contaminant is observed.

  20. Detection device for hazardous materials

    DOE Patents [OSTI]

    Partin, Judy K. (Idaho Falls, ID); Grey, Alan E. (Idaho Falls, ID)

    1994-01-01T23:59:59.000Z

    A detection device that is activated by the interaction of a hazardous chcal with a coating interactive with said chemical on an optical fiber thereby reducing the amount of light passing through the fiber to a light detector. A combination of optical filters separates the light into a signal beam and a reference beam which after detection, appropriate amplification, and comparison with preset internal signals, activates an alarm means if a predetermined level of contaminant is observed.

  1. Training for hazardous waste workers

    SciTech Connect (OSTI)

    Favel, K.

    1990-10-26T23:59:59.000Z

    This implementation plan describes the system and provides the information and schedules that are necessary to comply with the Department of Energy (DOE) Albuquerque Operations Office (AL) Memorandum, Reference EPD dated September 11, 1990, Training for Hazardous Waste Workers. The memo establishes the need for identifying employees requiring environmental training, ensuring that the training is received, and meeting documentation and recordkeeping requirements for the training.

  2. Hazardous materials in Fresh Kills landfill

    SciTech Connect (OSTI)

    Hirschhorn, J.S. [Hirschhorn and Associates, Wheaton, MD (United States)

    1997-12-31T23:59:59.000Z

    No environmental monitoring and corrective action programs can pinpoint multiple locations of hazardous materials the total amount of them in a large landfill. Yet the consequences of hazardous materials in MSW landfills are considerable, in terms of public health concerns, environmental damage, and cleanup costs. In this paper a rough estimation is made of how much hazardous material may have been disposed in Fresh Kills landfill in Staten Island, New York. The logic and methods could be used for other MSW landfills. Fresh Kills has frequently been described as the world`s largest MSW landfill. While records of hazardous waste disposal at Fresh Kills over nearly 50 years of operation certainly do not exist, no reasonable person would argue with the conclusion that large quantities of hazardous waste surely have been disposed at Fresh Kills, both legally and illegally. This study found that at least 2 million tons of hazardous wastes and substances have been disposed at Fresh Kills since 1948. Major sources are: household hazardous waste, commercial RCRA hazardous waste, incinerator ash, and commercial non-RCRA hazardous waste, governmental RCRA hazardous waste. Illegal disposal of hazardous waste surely has contributed even more. This is a sufficient amount to cause serious environmental contamination and releases, especially from such a landfill without an engineered liner system, for example. This figure is roughly 1% of the total amount of waste disposed in Fresh Kills since 1948, probably at least 200 million tons.

  3. Effects of Soil Composition and Mineralogy on the Bioaccessibility of Arsenic from Tailings and Soil in Gold Mine Districts of Nova Scotia

    SciTech Connect (OSTI)

    Meunier, Louise; Walker, Stephen R.; Wragg, Joanna; Parsons, Michael B.; Koch, Iris; Jamieson, Heather E.; Reimer, Kenneth J. (Queens); (Brit. Geo.); (Royal); (NRC)

    2010-10-20T23:59:59.000Z

    Bioaccessibility tests and mineralogical analyses were performed on arsenic-contaminated tailings and soils from gold mine districts of Nova Scotia, Canada, to examine the links between soil composition, mineralogy, and arsenic bioaccessibility. Arsenic bioaccessibility ranges from 0.1% to 49%. A weak correlation was observed between total and bioaccessible arsenic concentrations, and the arsenic bioaccessibility was not correlated with other elements. Bulk X-ray absorption near-edge structure analysis shows arsenic in these near-surface samples is mainly in the pentavalent form, indicating that most of the arsenopyrite (As{sup 1-}) originally present in the tailings and soils has been oxidized during weathering reactions. Detailed mineralogical analyses of individual samples have identified up to seven arsenic species, the relative proportions of which appear to affect arsenic bioaccessibility. The highest arsenic bioaccessibility (up to 49%) is associated with the presence of calcium-iron arsenate. Samples containing arsenic predominantly as arsenopyrite or scorodite have the lowest bioaccessibility (<1%). Other arsenic species identified (predominantly amorphous iron arsenates and arsenic-bearing iron(oxy)hydroxides) are associated with intermediate bioaccessibility (1 to 10%). The presence of a more soluble arsenic phase, even at low concentrations, results in increased arsenic bioaccessibility from the mixed arsenic phases associated with tailings and mine-impacted soils.

  4. Arsenic methylation and lung and bladder cancer in a case-control study in northern Chile

    SciTech Connect (OSTI)

    Melak, Dawit [Global Health Sciences, University of California, San Francisco, San Francisco, CA (United States); Ferreccio, Catterina [Escuela de Medicina, Pontificia Universidad Catolica de Chile, Santiago (Chile); Kalman, David [School of Public Health and Community Medicine, University of Washington, Seattle, WA (United States); Parra, Roxana [Hospital Regional de Antofagasta, Antofagasta (Chile); Acevedo, Johanna; Pérez, Liliana; Cortés, Sandra [Escuela de Medicina, Pontificia Universidad Catolica de Chile, Santiago (Chile); Smith, Allan H.; Yuan, Yan; Liaw, Jane [Arsenic Health Effects Research Group, School of Public Health, University of California, Berkeley, Berkeley, CA (United States); Steinmaus, Craig, E-mail: craigs@berkeley.edu [Arsenic Health Effects Research Group, School of Public Health, University of California, Berkeley, Berkeley, CA (United States); Office of Environmental Health Hazard Assessment, California Environmental Protection Agency, Oakland, CA (United States)

    2014-01-15T23:59:59.000Z

    In humans, ingested inorganic arsenic is metabolized to monomethylarsenic (MMA) then to dimethylarsenic (DMA), although this process is not complete in most people. The trivalent form of MMA is highly toxic in vitro and previous studies have identified associations between the proportion of urinary arsenic as MMA (%MMA) and several arsenic-related diseases. To date, however, relatively little is known about its role in lung cancer, the most common cause of arsenic-related death, or about its impacts on people drinking water with lower arsenic concentrations (e.g., < 200 ?g/L). In this study, urinary arsenic metabolites were measured in 94 lung and 117 bladder cancer cases and 347 population-based controls from areas in northern Chile with a wide range of drinking water arsenic concentrations. Lung cancer odds ratios adjusted for age, sex, and smoking by increasing tertiles of %MMA were 1.00, 1.91 (95% confidence interval (CI), 0.99–3.67), and 3.26 (1.76–6.04) (p-trend < 0.001). Corresponding odds ratios for bladder cancer were 1.00, 1.81 (1.06–3.11), and 2.02 (1.15–3.54) (p-trend < 0.001). In analyses confined to subjects only with arsenic water concentrations < 200 ?g/L (median = 60 ?g/L), lung and bladder cancer odds ratios for subjects in the upper tertile of %MMA compared to subjects in the lower two tertiles were 2.48 (1.08–5.68) and 2.37 (1.01–5.57), respectively. Overall, these findings provide evidence that inter-individual differences in arsenic metabolism may be an important risk factor for arsenic-related lung cancer, and may play a role in cancer risks among people exposed to relatively low arsenic water concentrations. - Highlights: • Urine arsenic metabolites were measured in cancer cases and controls from Chile. • Higher urine %MMA values were associated with increased lung and bladder cancer. • %MMA-cancer associations were seen at drinking water arsenic levels < 200 ?g/L.

  5. Hazard Labeling Elements 1. Product identifier: how the hazardous chemical is identified. This can be (but is not

    E-Print Network [OSTI]

    Chapman, Michael S.

    Hazard Labeling Elements 1. Product identifier: how the hazardous chemical is identified. This can of severity of hazard and alert the reader to a potential hazard on the label. There are only two signal words, "Danger" and "Warning." Within a specific hazard class, "Danger" is used for the more severe hazards

  6. Experiment Hazard Class 6 - Chemicals

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (6.5) Corrosives (6.2) Alkali Metals Toxic (6.3) As determined by EQO-Industrial Hygiene As determined by EQO-Industrial Hygiene As determined by EQO-Industrial Hygiene As...

  7. Compositions and methods for removing arsenic in water

    DOE Patents [OSTI]

    Gadgil, Ashok Jagannth (El Cerrito, CA)

    2011-02-22T23:59:59.000Z

    Compositions and methods and for contaminants from water are provided. The compositions comprise ferric hydroxide and ferric oxyhydride coated substrates for use in removing the contaminant from the water. Contacting water bearing the contaminant with the substrates can substantially reduce contaminant levels therein. Methods of oxidizing the contaminants in water to facilitate their removal by the ferric hydroxide and ferric oxyhydride coated substrates are also provided. The contaminants include, but are not limited to, arsenic, selenium, uranium, lead, cadmium, nickel, copper, zinc, chromium and vanadium, their oxides and soluble salts thereof.

  8. Trace metal capture by various sorbents during fluidized bed coal combustion

    SciTech Connect (OSTI)

    Ho, T.C.; Ghebremeskel, A.; Wang, K.S.; Hopper, J.R. [Lamar Univ., Beaumont, TX (United States)

    1997-07-01T23:59:59.000Z

    This study investigated the potential of employing suitable sorbents to capture toxic trace metallic substances during fluidized bed coal combustion. Metal capture experiments were carried out in a 25.4 mm (1 inch) quartz fluidized bed combustor enclosed in an electric furnace. The metals involved were cadmium, lead, chromium, arsenic and selenium, and the sorbents tested included bauxite, zeolite and lime. In addition to the experimental investigations, potential metal-sorbent reactions were also identified through chemical equilibrium calculations based on the minimization of system free energy. The observed experimental results indicated that metal capture by sorbents can be as high as 88% depending on the metal species and sorbent involved. Results from thermodynamic equilibrium simulations suggested the formation of metal-sorbent compounds such as Pb{sub 2}SiO{sub 4}(s), CdAl{sub 2}O{sub 4}(s) and CdSiO{sub 3}(s) under the combustion conditions.

  9. Hazards assessment for the INEL Landfill Complex

    SciTech Connect (OSTI)

    Knudsen, J.K.; Calley, M.B.

    1994-02-01T23:59:59.000Z

    This report documents the hazards assessment for the INEL Landfill Complex (LC) located at the Idaho National Engineering Laboratory, which is operated by EG&G Idaho, Inc., for the US Department of Energy (DOE). The hazards assessment was performed to ensure that this facility complies with DOE and company requirements pertaining to emergency planning and preparedness for operational emergencies. DOE Order 5500.3A requires that a facility-specific hazards assessment be performed to provide the technical basis for facility emergency planning efforts. This hazards assessment was conducted in accordance with DOE Headquarters and the DOE Idaho Operations Office (DOE-ID) guidance to comply with DOE Order 5500.3A. The hazards assessment identifies and analyzes the hazards that are significant enough to warrant consideration in a facility`s operational emergency management program. The area surrounding the LC, the buildings and structures at the LC, and the processes that are used at the LC are described in this report. All hazardous materials, both radiological and nonradiological, at the LC were identified and screened against threshold quantities according to DOE Order 5500.3A guidance. Asbestos at the Asbestos Pit was the only hazardous material that exceeded its specified threshold quantity. However, the type of asbestos received and the packaging practices used are believed to limit the potential for an airborne release of asbestos fibers. Therefore, in accordance with DOE Order 5500.3A guidance, no further hazardous material characterization or analysis was required for this hazards assessment.

  10. Heavy metals in fish from the Aleutians: Interspecific and locational differences

    SciTech Connect (OSTI)

    Burger, Joanna, E-mail: burger@biology.rutgers.edu [Division of Life Sciences, Rutgers University, 604 Allison Road, Piscataway, NJ (United States); Environmental and Occupational Health Sciences Institute, Rutgers University, Piscataway, NJ (United States); Consortium for Risk Evaluation with Stakeholder Participation, Vanderbilt University, Nashville, TN 37235 (United States); Gochfeld, Michael [Environmental and Occupational Health Sciences Institute, Rutgers University, Piscataway, NJ (United States); Consortium for Risk Evaluation with Stakeholder Participation, Vanderbilt University, Nashville, TN 37235 (United States); Environmental and Occupational Medicine, Rutgers-Robert Wood Johnson Medical School, Piscataway, NJ 08854 (United States); Jeitner, Christian; Pittfield, Taryn [Division of Life Sciences, Rutgers University, 604 Allison Road, Piscataway, NJ (United States); Environmental and Occupational Health Sciences Institute, Rutgers University, Piscataway, NJ (United States); Consortium for Risk Evaluation with Stakeholder Participation, Vanderbilt University, Nashville, TN 37235 (United States); Donio, Mark [Division of Life Sciences, Rutgers University, 604 Allison Road, Piscataway, NJ (United States)

    2014-05-01T23:59:59.000Z

    The objectives of this study were to examine levels of arsenic, cadmium, lead, mercury and selenium in edible tissue of seven species of marine fish collected from several Aleutian islands (in 2004) to determine: (1) interspecific differences, (2) locational differences (among Aleutian Islands), (3) size-related differences in any metal levels within a species, and (4) potential risk to the fish or to predators on the fish, including humans. We also compared metals levels to those of three other fish species previously examined in detail, as well as examining metals in the edible tissue of octopus (Octopus dofleini). Octopus did not have the highest levels of any metal. There were significant interspecific differences in all metal levels among the fish species, although the differences were less than an order of magnitude, except for arsenic (mean of 19,500 ppb in Flathead sole, Hippoglossoides elassodon). Significant intraisland variation occurred among the four sites on Amchitka, but there was not a consistent pattern. There were significant interisland differences for some metals and species. Mercury levels increased significantly with size for several species; lead increased significantly for only one fish species; and cadmium and selenium decreased significantly with size for halibut (Hippoglossus stenolepis). The Alaskan Department of Health and Social Services supports unrestricted consumption of most Alaskan fish species for all people, including pregnant women. Most mean metal concentrations were well below the levels known to adversely affect the fish themselves, or predators that consume them (including humans), except for mercury in three fish species (mean levels just below 0.3 ppm), and arsenic in two fish species. However, even at low mercury levels, people who consume fish almost daily will exceed guideline values from the Centers for Disease Control and the Environmental Protection Agency. - Highlights: • Cadmium, lead, mercury and selenium levels differed among 10 fish species from the Aleutians. • Mean Arsenic was as high as 19,500 ppb (flathead sole, Hippoglossoides elassodon). • Mercury levels increased significantly with fish size for several species. • Metal levels were generally below adverse effects levels for fish and their predators. • Mercury and arsenic might pose a risk to human consumers, and require further examination.

  11. NGNP SITE 2 HAZARDS ASSESSMENT

    SciTech Connect (OSTI)

    Wayne Moe

    2011-10-01T23:59:59.000Z

    The Next Generation Nuclear Plant (NGNP) Project initiated at Idaho National Laboratory (INL) by the U.S. Department of Energy pursuant to the 2005 Energy Policy Act, is based on research and development activities supported by the Generation IV Nuclear Energy Systems Initiative. The principal objective of the NGNP Project is to support commercialization of the high temperature gas-cooled reactor (HTGR) technology. The HTGR is a helium-cooled and graphite-moderated reactor that can operate at temperatures much higher than those of conventional light water reactor (LWR) technologies. Accordingly, it can be applied in many industrial applications as a substitute for burning fossil fuels, such as natural gas, to generate process heat in addition to producing electricity, which is the principal application of current LWRs. Nuclear energy in the form of LWRs has been used in the U.S. and internationally principally for the generation of electricity. However, because the HTGR operates at higher temperatures than LWRs, it can be used to displace the use of fossil fuels in many industrial applications. It also provides a carbon emission-free energy supply. For example, the energy needs for the recovery and refining of petroleum, for the petrochemical industry and for production of transportation fuels and feedstocks using coal conversion processes require process heat provided at temperatures approaching 800 C. This temperature range is readily achieved by the HTGR technology. This report summarizes a site assessment authorized by INL under the NGNP Project to determine hazards and potential challenges that site owners and HTGR designers need to be aware of when developing the HTGR design for co-location at industrial facilities, and to evaluate the site for suitability considering certain site characteristics. The objectives of the NGNP site hazard assessments are to do an initial screening of representative sites in order to identify potential challenges and restraints to be addressed in design and licensing processes; assure the HTGR technology can be deployed at variety of sites for a range of applications; evaluate potential sites for potential hazards and describe some of the actions necessary to mitigate impacts of hazards; and, provide key insights that can inform the plant design process. The report presents a summary of the process methodology and the results of an assessment of hazards typical of a class of candidate sites for the potential deployment of HTGR reactor technology. The assessment considered health and safety, and other important siting characteristics to determine the potential impact of identified hazards and potential challenges presented by the location for this technology. A four reactor module nuclear plant (2000 to 2400 MW thermal), that co-generates steam, electricity for general use in the plant, and hot gas for use in a nearby chemical processing facility, to provide the requisite performance and reliability was assumed for the assessment.

  12. Hazardous and Radioactive Mixed Waste

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1982-12-31T23:59:59.000Z

    To establish hazardous waste management procedures for facilities operated under authority of the Atomic Energy Act of 1954, as amended (AEA). The procedures will follow. to the extent practicable, regulations issued by the Environmental Protection Agency (EPA) pursuant to the Resource Conservation and Recovery Act of 1976 (RCRA). Although Department of Energy (DOE) operations conducted under authority other than the AEA are subject to EPA or State regulations conforming with RCRA, facilities administered under the authority of the AEA are not bound by such requirements.

  13. Arsenic remediation of drinking water using iron-oxide coated coal bottom ash

    SciTech Connect (OSTI)

    MATHIEU, JOHANNA L.; GADGIL, ASHOK J.; ADDY, SUSAN E.A.; KOWOLIK, KRISTIN

    2010-06-01T23:59:59.000Z

    We describe laboratory and field results of a novel arsenic removal adsorbent called 'Arsenic Removal Using Bottom Ash' (ARUBA). ARUBA is prepared by coating particles of coal bottom ash, a waste material from coal fired power plants, with iron (hydr)oxide. The coating process is simple and conducted at room temperature and atmospheric pressure. Material costs for ARUBA are estimated to be low (~;;$0.08 per kg) and arsenic remediation with ARUBA has the potential to be affordable to resource-constrained communities. ARUBA is used for removing arsenic via a dispersal-and-removal process, and we envision that ARUBA would be used in community-scale water treatment centers. We show that ARUBA is able to reduce arsenic concentrations in contaminated Bangladesh groundwater to below the Bangladesh standard of 50 ppb. Using the Langmuir isotherm (R2 = 0.77) ARUBA's adsorption capacity in treating real groundwater is 2.6x10-6 mol/g (0.20 mg/g). Time-to-90percent (defined as the time interval for ARUBA to remove 90percent of the total amount of arsenic that is removed at equilibrium) is less than one hour. Reaction rates (pseudo-second-order kinetic model, R2>_ 0.99) increase from 2.4x105 to 7.2x105 g mol-1 min-1 as the groundwater arsenic concentration decreases from 560 to 170 ppb. We show that ARUBA's arsenic adsorption density (AAD), defined as the milligrams of arsenic removed at equilibrium per gram of ARUBA added, is linearly dependent on the initial arsenic concentration of the groundwater sample, for initial arsenic concentrations of up to 1600 ppb and an ARUBA dose of 4.0 g/L. This makes it easy to determine the amount of ARUBA required to treat a groundwater source when its arsenic concentration is known and less than 1600 ppb. Storing contaminated groundwater for two to three days before treatment is seen to significantly increase ARUBA's AAD. ARUBA can be separated from treated water by coagulation and clarification, which is expected to be less expensive than filtration of micron-scale particles, further contributing to the affordability of a community-scale water treatment center.

  14. Metal inks

    DOE Patents [OSTI]

    Ginley, David S; Curtis, Calvin J; Miedaner, Alex; van Hest, Marinus Franciscus Antonius Maria; Kaydanova, Tatiana

    2014-02-04T23:59:59.000Z

    Self-reducing metal inks and systems and methods for producing and using the same are disclosed. In an exemplary embodiment, a method may comprise selecting metal-organic (MO) precursor, selecting a reducing agent, and dissolving the MO precursor and the reducing agent in an organic solvent to produce a metal ink that remains in a liquid phase at room temperature. Metal inks, including self-reducing and fire-through metal inks, are also disclosed, as are various applications of the metal inks.

  15. Mission Support Alliance, LLC Volpentest Hazardous Materials...

    Broader source: Energy.gov (indexed) [DOE]

    should use caution to preclude an overreliance on individual expertise and ensure hazard analysis procedures and policies are fully integrated into the systematic approach...

  16. Canister storage building hazard analysis report

    SciTech Connect (OSTI)

    POWERS, T.B.

    1999-05-11T23:59:59.000Z

    This report describes the methodology used in conducting the Canister Storage Building (CSB) hazard analysis to support the CSB final safety analysis report (FSAR) and documents the results. The hazard analysis was performed in accordance with the DOE-STD-3009-94, ''Preparation Guide for US. Department of Energy Nonreactor Nuclear Facility Safety Analysis Reports'', and meets the intent of HNF-PRO-704, ''Hazard and Accident Analysis Process''. This hazard analysis implements the requirements of DOE Order 5480.23, ''Nuclear Safety Analysis Reports''.

  17. Identification of Hazards, 3/9/95

    Broader source: Energy.gov [DOE]

    The objective of this surveillance is to evaluate the effectiveness of the contractor's hazards identification programs.  Surveillance activities encompass maintenance and implementation of safety...

  18. Mr. James Bearzi Hazardous Waste Bureau

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bearzi Hazardous Waste Bureau Department of Energy Carlsbad Field Office P. O . Box 3090 Carlsbad. New Mexico 88221 May 26, 2009 New Mexico Environment Department 2905 E. Rodeo...

  19. Hazards Control, 3/9/35

    Broader source: Energy.gov [DOE]

    The objective of this surveillance is to evaluate the effectiveness of the contractor's programs and policy for establishing controls to mitigate hazards affecting the public, worker, and...

  20. Hazardous Material Packaging for Transport - Administrative Procedures

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1986-09-30T23:59:59.000Z

    To establ1sh administrative procedures for the certification and use of radioactive and other hazardous materials packaging by the Department of Energy (DOE).

  1. Hazardous Material Transportation Safety (South Dakota)

    Broader source: Energy.gov [DOE]

    This legislation authorizes the Division of Highway Safety, in the Department of Public Safety, to promulgate regulations pertaining to the safe transportation of hazardous materials by a motor...

  2. Fire hazards analysis of central waste complex

    SciTech Connect (OSTI)

    Irwin, R.M.

    1996-05-30T23:59:59.000Z

    This document analyzes the fire hazards associated with operational the Central Waste Complex. It provides the analysis and recommendations necessary to ensure compliance with applicable fire codes.

  3. BNL | CFN: Transport of Hazardous Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Transportation of Hazardous Materials and Nanomaterials The following contains guidance for transporting materials to and from BNL and for on-site transfers. All staff and users...

  4. DC Hazardous Waste Management (District of Columbia)

    Broader source: Energy.gov [DOE]

    This regulation regulates the generation, storage, transportation, treatment, and disposal of hazardous waste, and wherever feasible, reduces or eliminates waste at the source. It is the policy of...

  5. Hazardous Waste Management System-General (Ohio)

    Broader source: Energy.gov [DOE]

    This chapter of the law establishes that the Ohio Environmental Protection Agency provides general regulations regarding hazardous waste, including landfills. Specific passages refer to the...

  6. Chapter 38 Hazardous Waste Permitting Process (Kentucky)

    Broader source: Energy.gov [DOE]

    This administrative regulation establishes the general provisions for storage, treatment, recycling, or disposal of hazardous waste. It provides information about permits and specific requirements...

  7. Hazardous Waste Minimum Distance Requirements (Connecticut)

    Broader source: Energy.gov [DOE]

    These regulations set minimum distance requirements between certain types of facilities that generate, process, store, and dispose of hazardous waste and other land uses. The regulations require an...

  8. Louisiana Hazardous Waste Control Law (Louisiana)

    Broader source: Energy.gov [DOE]

    The Louisiana Department of Environmental Quality is responsible for administering the Louisiana Hazardous Waste Control Law and the regulations created under that law.

  9. Hazardous Liquid Pipelines and Storage Facilities (Iowa)

    Broader source: Energy.gov [DOE]

    This statute regulates the permitting, construction, monitoring, and operation of pipelines transporting hazardous liquids, including petroleum products and coal slurries. The definition used in...

  10. Extremely Hazardous Substances Risk Management Act (Delaware)

    Broader source: Energy.gov [DOE]

    This act lays out provisions for local governments to implement regulations and standards for the management of extremely hazardous substances, which are defined and categorized as follows:

  11. Oil and Hazardous Substance Discharge Preparedness (Minnesota)

    Broader source: Energy.gov [DOE]

    Anyone who owns or operates a vessel or facility that transports, stores, or otherwise handles hazardous wastes must take reasonable steps to prevent the discharge of those materials.

  12. Environmental justice implications of arsenic contamination in California¿s San Joaquin Valley: a cross-sectional, cluster-design examining exposure and compliance in community drinking water systems

    E-Print Network [OSTI]

    Balazs, Carolina L; Morello-Frosch, Rachel; Hubbard, Alan E; Ray, Isha

    2012-01-01T23:59:59.000Z

    implications of arsenic contamination in California’s SanHealth Impacts. In Water contamination and health. Edited byimplications of arsenic contamination in California’s San

  13. Review of The Arsenic Century: How Victorian Britain was Poisoned at Home, Work, and Play

    E-Print Network [OSTI]

    Ritvo, Harriet; Ritvo, Harriet

    In this disheartening chronicle, James C. Whorton fully justifies both his title and his subtitle. Of course arsenic was not a product of the nineteenth–century chemical imagination, as were, for example, aniline dyes and ...

  14. Arsenic remediation of drinking water using iron-oxide coated coal bottom ash

    E-Print Network [OSTI]

    MATHIEU, JOHANNA L.

    2010-01-01T23:59:59.000Z

    using Iron-oxide Coated Coal Ash. In Arsenic Contaminationwater using  iron?oxide coated coal bottom ash  Johanna L.  using iron-oxide coated coal bottom ash JOHANNA L. MATHIEU

  15. The influence of calcium on the inhibition of arsenic desorption from treatment residuals in extreme environments 

    E-Print Network [OSTI]

    Camacho, Julianna G.

    2006-04-12T23:59:59.000Z

    One of the most toxic environmentally mobile compounds found in water is arsenic. It has been used as a pesticide to control insects, fungi, weeds and rodents since the early part of this century because of its high toxicity. ...

  16. Impact of Two Water Management Systems on Arsenic Speciation and Microbial Populations in Rice Rhizosphere 

    E-Print Network [OSTI]

    Somenahally, Anil Kumar C.

    2012-02-14T23:59:59.000Z

    ., 2003). In the South-Central USA, arsenic in the form of sodium hydroxymethylarsinate (commonly known as monosodium methane-arsonate (MSMA)) and disodium methyl-dioxido- oxoarsorane (commonly known as disodium methane-arsonate (DSMA)), which were...

  17. Problems with low exposure Latency of arsenic caused cancer is 30 years or

    E-Print Network [OSTI]

    -MALIGNANT LUNG DISEASE? 150 people without arsenic-caused skin lesions Number with chronic cough 33 (31%) OR = 3 in Drinking Water in West Bengal, India (In press, Epidemiology) Those with chronic cough #12;Figure 2

  18. The hydrogeochemistry of pond and rice field recharge : implications for the arsenic contaminated aquifers in Bangladesh

    E-Print Network [OSTI]

    Neumann, Rebecca B

    2010-01-01T23:59:59.000Z

    The shallow aquifers in Bangladesh, which provide drinking water for millions and irrigation water for innumerable rice fields, are severely contaminated with geogenic arsenic. Water mass balance calculations show that ...

  19. Transformation of 2-line ferrihydrite and its effect on arsenic adsorption

    E-Print Network [OSTI]

    Her, Namryong

    2009-05-15T23:59:59.000Z

    Although the impacts of foreign species on aqueous transformations and arsenic adsorption by 2-line ferrihydrite (FH2) have been extensively studied, much less is known about the impact of transformation inhibitors on solid-state transformation...

  20. In Situ Groundwater Arsenic Removal Using Iron Oxide-Coated Sand

    E-Print Network [OSTI]

    Yu, Hongxu

    2010-10-12T23:59:59.000Z

    the sand filter suggest that both reversible adsorption and irreversible precipitation are responsible for removing arsenic from the water. Unlike conventional excavate-and-fill permeable reactive barriers, the treatment capacity of our in situ created...

  1. Impact of Two Water Management Systems on Arsenic Speciation and Microbial Populations in Rice Rhizosphere

    E-Print Network [OSTI]

    Somenahally, Anil Kumar C.

    2012-02-14T23:59:59.000Z

    ., 2003). In the South-Central USA, arsenic in the form of sodium hydroxymethylarsinate (commonly known as monosodium methane-arsonate (MSMA)) and disodium methyl-dioxido- oxoarsorane (commonly known as disodium methane-arsonate (DSMA)), which were...

  2. Effect of hydrological flow pattern on groundwater arsenic concentration in Bangladesh by Khandaker Ashfaque.

    E-Print Network [OSTI]

    Ashfaque, Khandaker

    2007-01-01T23:59:59.000Z

    Widespread arsenic contamination of groundwater has become a major concern in Bangladesh since the water supply, particularly in rural areas, is heavily dependent on groundwater. However, relative to the extent of research ...

  3. Cumulative exposure to arsenic and its relationship to respiratory cancer among copper-smelter employees

    SciTech Connect (OSTI)

    Lee-Feldstein, A.

    1986-01-01T23:59:59.000Z

    To explore the role of arsenic as a human carcinogen, the respiratory cancer-mortality experience (1938 to 1977) of 8045 white-male smelter employees in Montana was examined relative to cumulative exposure to arsenic trioxide and was compared with that of the white male population of the same region. Exposure to arsenic was estimated for various work areas from industrial-hygiene reports of average concentrations present in the smelter. Respiratory cancer mortality was analyzed further by time period of first employment and maximum lifetime exposure to arsenic trioxide. When exposure was estimated with arithmetic means of measured concentrations among men first employed prior to 1925, respiratory cancer mortality increased linearly with increasing cumulative exposure group, ranging from two to nine times expected; among those first employed in the period 1925 to 1947 it also increased linearly with increasing cumulative exposure group.

  4. Arsenic exposure, smoking, and lung cancer in smelter workers--a case-control study

    SciTech Connect (OSTI)

    Jaerup, L.P.; Pershagen, G. (Department of Environmental Hygiene, Karolinska Institutet, Stockholm (Sweden))

    1991-09-15T23:59:59.000Z

    A cohort of 3,916 Swedish copper smelter workers employed for at least 3 months between 1928 and 1967 was followed up through 1981. Arsenic exposure was estimated for different time periods at each workplace within the smelter. Detailed job records were linked to the exposure matrix, thus forming individual cumulative arsenic exposure measures for each smelter worker. Smoking history was collected for 107 lung cancer cases and 214 controls from the cohort. Lung cancer risks were positively related to cumulative arsenic exposure with smoking standardized relative risks ranging from 0.7 to 8.7 in different exposure groups. A negative confounding by smoking was suggested in the higher exposure categories. The interaction between arsenic and smoking for the risk of developing lung cancer was intermediate between additive and multiplicative and appeared less pronounced among heavy smokers.

  5. Cumulative exposure to arsenic and its relationship to respiratory cancer among copper smelter employees

    SciTech Connect (OSTI)

    Lee-Feldstein, A.

    1986-04-01T23:59:59.000Z

    To explore the role of arsenic as a human carcinogen, the respiratory cancer mortality experience (1938 to 1977) of 8,045 while male smelter employees in Montana was examined relative to cumulative exposure to arsenic trioxide and was compared with that of the white male population of the same region. Exposure to arsenic was estimated for various work areas from industrial hygiene reports of average concentrations present in the smelter. Respiratory cancer mortality was analyzed further by time period of first employment and maximum lifetime exposure to arsenic trioxide. When exposure was estimated with arithmetic means of measured concentrations among men first employed prior to 1925, respiratory cancer mortality increased linearly with increasing cumulative exposure group, ranging from two to nine times expected; among those first employed in the period 1925 to 1947 it also increased linearly with increasing cumulative exposure group.

  6. Development of a scalable model for predicting arsenic transport coupled with oxidation and adsorption reactions

    E-Print Network [OSTI]

    Clement, Prabhakar

    modeling; Contaminant transport; Scaling; Numerical modeling 1. Introduction Management of groundwaterDevelopment of a scalable model for predicting arsenic transport coupled with oxidation is critical for predicting its transport dynamics in groundwater systems. We completed batch experiments

  7. Hazardous Chemical Waste Management Reference Guide for Laboratories 9 1 Identification of Hazardous Chemical Waste

    E-Print Network [OSTI]

    Ford, James

    Hazardous Chemical Waste Management Reference Guide for Laboratories 9 1 · Identification of Hazardous Chemical Waste OBJECTIVES Do you know how to do the following? If you do, skip ahead to Minimization of Hazardous Waste section. If you do not, continue on in this section. · Determine whether

  8. Speciation of arsenic in pyrite by micro-X-ray absorption fine- structure spectroscopy (XAFS)

    SciTech Connect (OSTI)

    Paktunc, D. (CCM)

    2008-09-30T23:59:59.000Z

    Pyrite (FeS2) often contains variable levels of arsenic, regardless of the environment of formation. Arsenian pyrite has been reported in coals, sediments and ore deposits. Arsenian pyrite having As concentrations of up to 10 wt % in sedimentary rocks (Kolker et al. 1997), about 10 wt% in gold deposits (Fleet et al. 1993), 12 wt % in a refractory gold ore (Paktunc et al. 2006) and 20 wt % in a Carlin-type gold deposit in Nevada (Reich et al. 2005) have been reported. Arsenian pyrite is the carrier of gold in hydrothermal Carlin-type gold deposits, and gold concentrations of up to 0.9 wt % have been reported (Reich et al. 2005; Paktunc et al. 2006). In general, high Au concentrations correlate with As-rich zones in pyrite (Paktunc et al. 2006). Pyrite often ends up in mining and metallurgical wastes as an unwanted mineral and consititutes one of the primary sources of As in the wastes. Arsenic can be readily released to the environment due to rapid oxidative dissolution of host pyrite under atmospheric conditions. Pyrite is also the primary source of arsenic in emissions and dust resulting from combustion of bituminous coals. Despite the importance of arsenian pyrite as a primary source of anthropogenic arsenic in the environment and its economic significance as the primary carrier of gold in Carlin-type gold deposits, our understanding of the nature of arsenic in pyrite is limited. There are few papers dealing with the mode of occurrence of arsenic by bulk XAFS in a limited number of pyrite-bearing samples. The present study documents the analysis of pyrite particles displaying different morphologies and a range of arsenic and gold concentrations to determine the nature and speciation of arsenic.

  9. Urinary 8-hydroxydeoxyguanosine and urothelial carcinoma risk in low arsenic exposure area

    SciTech Connect (OSTI)

    Chung, C.-J.; Huang, C.-J. [Graduate Institute of Public Health, Taipei Medical University, Taipei, Taiwan (China); Pu, Y.-S. [Department of Urology, National Taiwan University Hospital, Taipei, Taiwan (China); Su, C.-T. [Department of Family Medicine, Taipei Medical University Hospital, Taipei, Taiwan (China); Huang, Y.-K.; Chen, Y.-T. [Graduate Institute of Medical Sciences, Taipei Medical University, Taipei, Taiwan (China); Hsueh, Y.-M. [Department of Public Health, School of Medicine, Taipei Medical University, No. 250 Wu-Hsing Street, Taipei 110, Taiwan (China)], E-mail: ymhsueh@tmu.edu.tw

    2008-01-01T23:59:59.000Z

    Arsenic is a well-documented human carcinogen and is known to cause oxidative stress in cultured cells and animals. A hospital-based case-control study was conducted to evaluate the relationship among the levels of urinary 8-hydroxydeoxyguanosine (8-OHdG), the arsenic profile, and urothelial carcinoma (UC). Urinary 8-OHdG was measured by using high-sensitivity enzyme-linked immunosorbent assay (ELISA) kits. The urinary species of inorganic arsenic and their metabolites were analyzed by high-performance liquid chromatography (HPLC) and hydride generator-atomic absorption spectrometry (HG-AAS). This study showed that the mean urinary concentration of total arsenics was significantly higher, at 37.67 {+-} 2.98 {mu}g/g creatinine, for UC patients than for healthy controls of 21.10 {+-} 0.79 {mu}g/g creatinine (p < 0.01). Urinary 8-OHdG levels correlated with urinary total arsenic concentrations (r = 0.19, p < 0.01). There were significantly higher 8-OHdG levels, of 7.48 {+-} 0.97 ng/mg creatinine in UC patients, compared to healthy controls of 5.95 {+-} 0.21 ng/mg creatinine. Furthermore, female UC patients had higher 8-OHdG levels of 9.22 {+-} 0.75 than those of males at 5.76 {+-} 0.25 ng/mg creatinine (p < 0.01). Multiple linear regression analyses revealed that high urinary 8-OHdG levels were associated with increased total arsenic concentrations, inorganic arsenite, monomethylarsonic acid (MMA), and dimethylarsenate (DMA) as well as the primary methylation index (PMI) even after adjusting for age, gender, and UC status. The results suggest that oxidative DNA damage was associated with arsenic exposure, even at low urinary level of arsenic.

  10. Variability of Grain Arsenic Concentration and Speciation in Rice (Oryza sativa L.)

    E-Print Network [OSTI]

    Pillai, Tushara Raghvan

    2011-02-22T23:59:59.000Z

    VARIABILITY OF GRAIN ARSENIC CONCENTRATION AND SPECIATION IN RICE (Oryza sativa L.) A Dissertation by TUSHARA RAGHVAN PILLAI Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of DOCTOR OF PHILOSOPHY December 2009 Major Subject: Molecular and Environmental Plant Sciences VARIABILITY OF GRAIN ARSENIC CONCENTRATION AND SPECIATION IN RICE (Oryza sativa L.) A Dissertation by TUSHARA...

  11. Comparison of Hazard Analysisp y Requirements of I&C

    E-Print Network [OSTI]

    ) M di l D i A id tShip Accident (Ferry Sewol) Medical Device Accident (Therac-25) 3 NPP Accident­ Software Fault Tree Analysis ­ By AECL, Nancy Leveson Name of Software Hazards No % Remarks For construct hazard 4 7For construct hazard 4 7 Initialization hazard 4 7 IF-THEN-ELSE construct hazard 38 67 CASE

  12. Silicone metalization

    DOE Patents [OSTI]

    Maghribi, Mariam N. (Livermore, CA); Krulevitch, Peter (Pleasanton, CA); Hamilton, Julie (Tracy, CA)

    2008-12-09T23:59:59.000Z

    A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

  13. Reactive oxygen species mediate arsenic induced cell transformation and tumorigenesis through Wnt/{beta}-catenin pathway in human colorectal adenocarcinoma DLD1 cells

    SciTech Connect (OSTI)

    Zhang Zhuo [Department of Preventive Medicine and Environmental Health, University of Kentucky, 121 Washington Avenue, Lexington, KY 40536 (United States); Wang Xin; Cheng Senping; Sun Lijuan; Son, Young-Ok [Graduate Center for Toxicology, University of Kentucky, 1095 VA Drive, Lexington, KY 40536 (United States); Yao Hua [Department of Stomatology, The First Affiliated Hospital, College of Medicine, Zhejiang University, Hangzhou, Zhejiang 310003 (China); Li Wenqi [Department of Preventive Medicine and Environmental Health, University of Kentucky, 121 Washington Avenue, Lexington, KY 40536 (United States); Budhraja, Amit [Graduate Center for Toxicology, University of Kentucky, 1095 VA Drive, Lexington, KY 40536 (United States); Li Li [Department of Family Medicine, Case Western Reserve University, Cleveland, OH 44106 (United States); Shelton, Brent J.; Tucker, Thomas [Markey Cancer Control Program, University of Kentucky, 2365 Harrodsburg Rd, Lexington, KY 40504 (United States); Arnold, Susanne M. [Markey Cancer Center, University of Kentucky, 800 Rose street, Lexington, KY 40536 (United States); Shi Xianglin, E-mail: Xianglin.sh@uky.edu [Graduate Center for Toxicology, University of Kentucky, 1095 VA Drive, Lexington, KY 40536 (United States)

    2011-10-15T23:59:59.000Z

    Long term exposure to arsenic can increase incidence of human cancers, such as skin, lung, and colon rectum. The mechanism of arsenic induced carcinogenesis is still unclear. It is generally believed that reactive oxygen species (ROS) may play an important role in this process. In the present study, we investigate the possible linkage between ROS, {beta}-catenin and arsenic induced transformation and tumorigenesis in human colorectal adenocarcinoma cell line, DLD1 cells. Our results show that arsenic was able to activate p47{sup phox} and p67{sup phox}, two key proteins for activation of NADPH oxidase. Arsenic was also able to generate ROS in DLD1 cells. Arsenic increased {beta}-catenin expression level and its promoter activity. ROS played a major role in arsenic-induced {beta}-catenin activation. Treatment of DLD1 cells by arsenic enhanced both transformation and tumorigenesis of these cells. The tumor volumes of arsenic treated group were much larger than those without arsenic treatment. Addition of either superoxide dismutase (SOD) or catalase reduced arsenic induced cell transformation and tumor formation. The results indicate that ROS are involved in arsenic induced cell transformation and tumor formation possible through Wnt/{beta}-catenin pathway in human colorectal adenocarcinoma cell line DLD1 cells. - Highlights: > Arsenic activates NADPH oxidase and increases reactive oxygen species generation in DLD1 cells. > Arsenic increases {beta}-catenin expression. > Inhibition of ROS induced by arsenic reduce {beta}-catenin expression. > Arsenic increases cell transformation in DLD1 cells and tumorigenesis in nude mice. > Blockage of ROS decrease cell transformation and tumorigenesis induced by arsenic.

  14. Association between body mass index and arsenic methylation efficiency in adult women from southwest U.S. and northwest Mexico

    SciTech Connect (OSTI)

    Gomez-Rubio, Paulina [Department of Pharmacology and Toxicology, University of Arizona, Tucson, AZ (United States); Roberge, Jason; Arendell, Leslie; Harris, Robin B.; O'Rourke, Mary K.; Chen, Zhao [Division of Epidemiology and Biostatistics, College of Public Health, University of Arizona, Tucson, AZ (United States); Cantu-Soto, Ernesto; Meza-Montenegro, Maria M. [Department of Environmental Sciences, Instituto Tecnologico de Sonora, Ciudad Obregon, Sonora (Mexico); Billheimer, Dean [Department of Agricultural and Biosystems Engineering, University of Arizona, Tucson, AZ (United States); Lu Zhenqiang [Arizona Statistical Consulting Laboratory, University of Arizona, Tucson, AZ (United States); Klimecki, Walter T., E-mail: klimecki@pharmacy.arizona.edu [Department of Pharmacology and Toxicology, University of Arizona, Tucson, AZ (United States)

    2011-04-15T23:59:59.000Z

    Human arsenic methylation efficiency has been consistently associated with arsenic-induced disease risk. Interindividual variation in arsenic methylation profiles is commonly observed in exposed populations, and great effort has been put into the study of potential determinants of this variability. Among the factors that have been evaluated, body mass index (BMI) has not been consistently associated with arsenic methylation efficiency; however, an underrepresentation of the upper BMI distribution was commonly observed in these studies. This study investigated potential factors contributing to variations in the metabolism of arsenic, with specific interest in the effect of BMI where more than half of the population was overweight or obese. We studied 624 adult women exposed to arsenic in drinking water from three independent populations. Multivariate regression models showed that higher BMI, arsenic (+ 3 oxidation state) methyltransferase (AS3MT) genetic variant 7388, and higher total urinary arsenic were significantly associated with low percentage of urinary arsenic excreted as monomethylarsonic acid (%uMMA) or high ratio between urinary dimethylarsinic acid and uMMA (uDMA/uMMA), while AS3MT genetic variant M287T was associated with high %uMMA and low uDMA/uMMA. The association between BMI and arsenic methylation efficiency was also evident in each of the three populations when studied separately. This strong association observed between high BMI and low %uMMA and high uDMA/uMMA underscores the importance of BMI as a potential arsenic-associated disease risk factor, and should be carefully considered in future studies associating human arsenic metabolism and toxicity.

  15. Distribution and metabolism of four different dimethylated arsenicals in hamsters

    SciTech Connect (OSTI)

    Naranmandura, Hua, E-mail: narenman@zju.edu.c [Institute of Pharmacology and Toxicology and Biochemical Pharmaceutics, College of Pharmaceutical Sciences, Zhejiang University, Hangzhou 310058 (China); Graduate School of Pharmaceutical Sciences, Chiba University, Chuo, Chiba 260-8675 (Japan); Iwata, Katsuya; Suzuki, Kazuo T. [Graduate School of Pharmaceutical Sciences, Chiba University, Chuo, Chiba 260-8675 (Japan); Ogra, Yasumitsu [Laboratory of Chemical Toxicology and Environmental Health, Showa Pharmaceutical University, Machida, Tokyo 194-8543 (Japan)

    2010-05-15T23:59:59.000Z

    Arsenic toxicity and distribution are highly dependent on animal species and its chemical species. Recently, thioarsenical has been recognized in highly toxic arsenic metabolites, which was commonly found in human and animal urine. In the present study, we revealed the mechanism underlying the distribution and metabolism of non-thiolated and thiolated dimethylarsenic compounds such as dimethylarsinic acid (DMA{sup V}), dimethylarsinous acid (DMA{sup III}), dimethylmonothioarsinic acid (DMMTA{sup V}), and dimethyldithioarsinic acid (DMDTA{sup V}) after the administration of them into femoral vein of hamsters. DMA{sup V} and DMDTA{sup V} distributed in organs and body fluids were in their unmodified form, while DMA{sup III} and DMMTA{sup V} were bound to proteins and transformed to DMA{sup V} in organs. On the other hand, DMA{sup V} and DMDTA{sup V} were mostly excreted into urine as their intact form 1 h after post-injection, and more than 70% of the doses were recovered in urine as their intact form. By contrast, less than 8-14% of doses were recovered in urine as DMA{sup V}, while more than 60% of doses were distributed in muscles and target organs (liver, kidney, and lung) of hamsters after the injection of DMMTA{sup V} and DMA{sup III}. However, in red blood cells (RBCs), only a small amount of the arsenicals was distributed (less than 4% of the doses) after the injection of DMA{sup III} and DMMTA{sup V}, suggesting that the DMA{sup III} and DMMTA{sup V} were hardly accumulated in hamster RBCs. Based on these observations, we suggest that although DMMTA{sup V} and DMDTA{sup V} are thioarsenicals, DMMTA{sup V} is taken up efficiently by organs, in a manner different from that of DMDTA{sup V}. In addition, the distribution and metabolism of DMMTA{sup V} are like in manner similar to DMA{sup III} in hamsters, while DMDTA{sup V} is in a manner similar to DMA{sup V}.

  16. Pathways of human exposure to arsenic in a community surrounding a copper smelter

    SciTech Connect (OSTI)

    Polissar, L.; Lowry-Coble, K.; Kalman, D.A.; Hughes, J.P.; van Belle, G.; Covert, D.S.; Burbacher, T.M.; Bolgiano, D.; Mottet, N.K. (Univ. of Washington, Seattle (USA))

    1990-10-01T23:59:59.000Z

    Several studies have found elevated levels of urinary arsenic among residents living near a copper smelter in Tacoma, Washington. To assess pathways of exposure to arsenic from the smelter, biological and environmental samples were collected longitudinally from 121 households up to 8 miles from the smelter. The concentration of inorganic and methylated arsenic compounds in spot urine samples was used as the primary measure of exposure to environmental arsenic. Urinary concentration of arsenic dropped off to a constant background level within one-half mile of the smelter in contrast to environmental concentrations, which decreased more steadily with increasing distance. Among all age-sex-specific groups in all areas, only children ages 0-6 living within one-half mile of the smelter had elevated levels of arsenic in urine. A separate analysis of data for these children suggests that hand-to-mouth activity was the primary source of exposure. Inhalation of ambient air and resuspension of contaminated soil were not important sources of exposure for children or adults.

  17. Energy and solid/hazardous waste

    SciTech Connect (OSTI)

    None

    1981-12-01T23:59:59.000Z

    This report addresses the past and potential future solid and hazardous waste impacts from energy development, and summarizes the major environmental, legislation applicable to solid and hazardous waste generation and disposal. A glossary of terms and acronyms used to describe and measure solid waste impacts of energy development is included. (PSB)

  18. CHEMICAL HYGIENE PLAN HAZARD COMMUNICATION PLAN

    E-Print Network [OSTI]

    Oliver, Douglas L.

    CHEMICAL HYGIENE PLAN AND HAZARD COMMUNICATION PLAN Occupational Exposures to Hazardous Chemicals Safety 2723 Environmental Health/Safety Chemical Hygiene Officer Radiation Safety Officer Biological (Accident Reports) 2204 Bioengineering 2965 #12;TABLE OF CONTENTS CHEMICAL HYGIENE PLAN (CHP) (4/2007) 1

  19. CHEMICAL HYGIENE PLAN HAZARD COMMUNICATION PLAN

    E-Print Network [OSTI]

    Kim, Duck O.

    CHEMICAL HYGIENE PLAN AND HAZARD COMMUNICATION PLAN Occupational Exposures to Hazardous Chemicals and Safety Numbers Research Safety 2723 Environmental Health/Safety Chemical Hygiene Officer Radiation Safety Human Resources (Accident Reports) 4589 Clinical Engineering 2964 #12;TABLE OF CONTENTS CHEMICAL HYGIENE

  20. CHEMICAL HYGIENE PLAN HAZARD COMMUNICATION PLAN

    E-Print Network [OSTI]

    Kim, Duck O.

    CHEMICAL HYGIENE PLAN AND HAZARD COMMUNICATION PLAN Occupational Exposures to Hazardous Chemicals and Safety Numbers Research Safety 2723 Environmental Health/Safety Chemical Hygiene Officer Radiation Safety Human Resources (Accident Reports) 4589 Bioengineering 2965 #12;TABLE OF CONTENTS CHEMICAL HYGIENE PLAN

  1. Frozen Ground 9 PERMAFROST HAZARDS IN MOUNTAINS

    E-Print Network [OSTI]

    Kääb, Andreas

    and other forms of creeping mountain permafrost may be the source of a number of hazards. Rock glaciers of large rock avalanche disasters are examples of mountain hazards. In the case of the September 20, 2002, rock-ice avalanche at Kolka-Karmadon in the Russian Caucasus, a combined rock-ice avalanche

  2. Fire and explosion hazards of oil shale

    SciTech Connect (OSTI)

    Not Available

    1989-01-01T23:59:59.000Z

    The US Bureau of Mines publication presents the results of investigations into the fire and explosion hazards of oil shale rocks and dust. Three areas have been examined: the explosibility and ignitability of oil shale dust clouds, the fire hazards of oil shale dust layers on hot surfaces, and the ignitability and extinguishment of oil shale rubble piles. 10 refs., 54 figs., 29 tabs.

  3. Why is Eastern Redcedar a Hazardous Fuel?

    E-Print Network [OSTI]

    Balasundaram, Balabhaskar "Baski"

    Why is Eastern Redcedar a Hazardous Fuel? Why is Eastern Redcedar a Hazardous Fuel? Homes built the destruction of fire-tolerant trees if a wildfire moves through the area. Creating fuel breaks (such ignite it. · When ERC grows in forests and wood- lands, it acts as a ladder fuel to allow fire to climb

  4. Technical basis document for natural event hazards

    SciTech Connect (OSTI)

    CARSON, D.M.

    2003-08-28T23:59:59.000Z

    This technical basis document was developed to support the documented safety analysis (DSA) and describes the risk binning process and the technical basis for assigning risk bins for natural event hazard (NEH)-initiated accidents. The purpose of the risk binning process is to determine the need for safety-significant structures, systems, and components (SSC) and technical safety requirement (TSR)-level controls for a given representative accident or represented hazardous conditions based on an evaluation of the frequency and consequence. Note that the risk binning process is not applied to facility workers, because all facility worker hazardous conditions are considered for safety-significant SSCs and/or TSR-level controls This report documents the technical basis for assigning risk bins for Natural Event Hazards Representative Accident and associated represented hazardous conditions.

  5. Ventura County hazardous waste minimization program

    SciTech Connect (OSTI)

    Hanlon, D.A.; Koepp, D.W.

    1987-05-01T23:59:59.000Z

    In 1985, Ventura County Environmental Health Department began a technical assistance program to encourage hazardous waste generators to reduce their dependence on land disposal. In order to accomplish this, information from the California State Hazardous Waste Manifest Information System was analyzed to identify the types, quantities and disposition of hazardous waste produced by companies in Ventura County. All generators that rely on land disposal were also surveyed to determine future waste management plans. Waste audits were conducted at each site to determine if alternative waste handling methods were feasible and to ensure that reuse, recycling and waste reduction methods are used when possible. This article summarizes these findings and projects future hazardous waste generation and disposal patterns for industries in Ventura County. It also identifies barriers to volume reduction and provides a framework for future local hazardous waste alternative technology/volume reduction program activities.

  6. Nat. Hazards Earth Syst. Sci., 8, 577586, 2008 www.nat-hazards-earth-syst-sci.net/8/577/2008/

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Nat. Hazards Earth Syst. Sci., 8, 577­586, 2008 www.nat-hazards-earth-syst-sci.net/8 Hazards and Earth System Sciences Integrated approach for coastal hazards and risks in Sri Lanka M. Garcin the importance of knowledge and the taking into account of coastal hazards. Sri Lanka was one of the countries

  7. Nat. Hazards Earth Syst. Sci., 6, 553561, 2006 www.nat-hazards-earth-syst-sci.net/6/553/2006/

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Nat. Hazards Earth Syst. Sci., 6, 553­561, 2006 www.nat-hazards-earth-syst-sci.net/6/553/2006/ © Author(s) 2006. This work is licensed under a Creative Commons License. Natural Hazards and Earth System Introduction Risk consists of hazard and vulnerability. We can define "hazard" like "a threatening event

  8. Nat. Hazards Earth Syst. Sci., 6, 637651, 2006 www.nat-hazards-earth-syst-sci.net/6/637/2006/

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Nat. Hazards Earth Syst. Sci., 6, 637­651, 2006 www.nat-hazards-earth-syst-sci.net/6/637/2006/ © Author(s) 2006. This work is licensed under a Creative Commons License. Natural Hazards and Earth System Hazards and Landscape (BFW), Department of Natural Hazards and Alpine Timberline, Innsbruck, Austria 3

  9. Hazard Priority and Remediation Hazards are prioritized according to the severity of the resulting injury, potential damage, and the

    E-Print Network [OSTI]

    de Lijser, Peter

    Hazard Priority and Remediation Hazards are prioritized according to the severity of the resulting injury, potential damage, and the probability of occurrence. Imminent and serious procedures or hazards Description Correction Date 1 EMERGENCY HAZARD Emergency Hazards threaten life safety or health, property

  10. Arsenic methylation capability and hypertension risk in subjects living in arseniasis-hyperendemic areas in southwestern Taiwan

    SciTech Connect (OSTI)

    Huang, Y.-K. [Graduate Institute of Medical Sciences, School of Medicine, Taipei Medical University, Taipei, Taiwan (China); Tseng, C.-H. [National Taiwan University College of Medicine, Taipei, Taiwan (China); Department of Internal Medicine, National Taiwan University Hospital, Taipei, Taiwan (China); Department of Medical Research and Development, National Taiwan University Hospital Yun-Lin Branch, Yun-Lin, Taiwan (China); Huang, Y.-L. [Department of Public Health, School of Medicine, Taipei Medical University, No. 250 Wu-Hsing Street, Taipei 110, Taiwan (China); Yang, M.-H. [Department of Nuclear Science, National Tsing-Hua University, Hsinchu, Taiwan (China); Chen, C.-J. [Genomic Research Center, Academia Sinica, Taipei, Taiwan (China); Graduate Institute of Epidemiology, College of Public Health, National Taiwan University Taipei, Taiwan (China); Hsueh, Y.-M. [Department of Public Health, School of Medicine, Taipei Medical University, No. 250 Wu-Hsing Street, Taipei 110, Taiwan (China)]. E-mail: ymhsueh@tmu.edu.tw

    2007-01-15T23:59:59.000Z

    Background: Cumulative arsenic exposure (CAE) from drinking water has been shown to be associated with hypertension in a dose-response pattern. This study further explored the association between arsenic methylation capability and hypertension risk among residents of arseniasis-hyperendemic areas in Taiwan considering the effect of CAE and other potential confounders. Method: There were 871 subjects (488 women and 383 men) and among them 372 were diagnosed as having hypertension based on a positive history or measured systolic blood pressure {>=} 140 mm Hg and/or diastolic blood pressure {>=} 90 mm Hg. Urinary arsenic species were determined by high-performance liquid chromatography-hydride generator and atomic absorption spectrometry. Primary arsenic methylation index [PMI, defined as monomethylarsonic acid (MMA{sup V}) divided by (As{sup III} + As{sup V})] and secondary arsenic methylation index (SMI, defined as dimethylarsinic acid divided by MMA{sup V}) were used as indicators for arsenic methylation capability. Results: The level of urinary arsenic was still significantly correlated with cumulative arsenic exposure (CAE) calculated from a questionnaire interview (p = 0.02) even after the residents stopped drinking the artesian well water for 2-3 decades. Hypertensive subjects had higher percentages of MMA{sup V} and lower SMI than subjects without hypertension. However, subjects having CAE > 0 mg/L-year had higher hypertension risk than those who had CAE = 0 mg/L-year disregard a high or low methylation index. Conclusion: Inefficient arsenic methylation ability may be related with hypertension risk.

  11. Sustainable System for Residual Hazards Management

    SciTech Connect (OSTI)

    Kevin M. Kostelnik; James H. Clarke; Jerry L. Harbour

    2004-06-01T23:59:59.000Z

    Hazardous, radioactive and other toxic substances have routinely been generated and subsequently disposed of in the shallow subsurface throughout the world. Many of today’s waste management techniques do not eliminate the problem, but rather only concentrate or contain the hazardous contaminants. Residual hazards result from the presence of hazardous and/or contaminated material that remains on-site following active operations or the completion of remedial actions. Residual hazards pose continued risk to humans and the environment and represent a significant and chronic problem that require continuous longterm management (i.e. >1000 years). To protect human health and safeguard the natural environment, a sustainable system is required for the proper management of residual hazards. A sustainable system for the management of residual hazards will require the integration of engineered, institutional and land-use controls to isolate residual contaminants and thus minimize the associated hazards. Engineered controls are physical modifications to the natural setting and ecosystem, including the site, facility, and/or the residual materials themselves, in order to reduce or eliminate the potential for exposure to contaminants of concern (COCs). Institutional controls are processes, instruments, and mechanisms designed to influence human behavior and activity. System failure can involve hazardous material escaping from the confinement because of system degradation (i.e., chronic or acute degradation) or by externalintrusion of the biosphere into the contaminated material because of the loss of institutional control. An ongoing analysis of contemporary and historic sites suggests that the significance of the loss of institutional controls is a critical pathway because decisions made during the operations/remedial action phase, as well as decisions made throughout the residual hazards management period, are key to the longterm success of the prescribed system. In fact, given that society has become more reliant on and confident of engineered controls, there may be a growing tendency to be even less concerned with institutional controls.

  12. E-Print Network 3.0 - arsenic-based antineoplastic drugs Sample...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: Occupational Exposures to Antineoplastic and Other Hazardous Drugs in Health Care Settings" (http... Group 1 Carcinogens, Chemotherapy Waste and other Hazardous Drug...

  13. Metal resistant plants and phytoremediation of environmental contamination

    DOE Patents [OSTI]

    Meagher, Richard B.; Li, Yujing; Dhankher, Om P.

    2010-04-20T23:59:59.000Z

    The present disclosure provides a method of producing transgenic plants which are resistant to at least one metal ion by transforming the plant with a recombinant DNA comprising a nucleic acid encoding a bacterial arsenic reductase under the control of a plant expressible promoter, and a nucleic acid encoding a nucleotide sequence encoding a phytochelatin biosynthetic enzyme under the control of a plant expressible promoter. The invention also relates a method of phytoremediation of a contaminated site by growing in the site a transgenic plant expressing a nucleic acid encoding a bacterial arsenate reductase and a nucleic acid encoding a phytochelatin biosynthetic enzyme.

  14. Audit of Selected Hazardous Waste Remedial Actions Program Costs...

    Office of Environmental Management (EM)

    of Selected Hazardous Waste Remedial Actions Program Costs, ER-B-97-04 Audit of Selected Hazardous Waste Remedial Actions Program Costs, ER-B-97-04 Audit of Selected Hazardous...

  15. Uintah -a scalable framework for hazard analysis Martin Berzins

    E-Print Network [OSTI]

    Utah, University of

    Uintah - a scalable framework for hazard analysis Martin Berzins Scientific Computing and Imaging of Uintah to a petascale problem in hazard analysis arising from "sympathetic" explosions in which. Devices containing such materials undergo extensive testing for hazard classification prior

  16. A Hazardous Inquiry: The Rashomon Effect at Love Canal

    E-Print Network [OSTI]

    Fortunato, Mary Beth

    2000-01-01T23:59:59.000Z

    Review: A Hazardous Inquiry: The Rashomon Effect at LoveUSA Mazur, Allan. A Hazardous Inquiry: The Rashomon EffectISBN 0674748336. A Hazardous Inquiry: The Rashomon Effect at

  17. Judging Hazard from Native Trees in California Recreational Areas

    E-Print Network [OSTI]

    Standiford, Richard B.

    Judging Hazard from Native Trees in California Recreational Areas : - -a Guide for Professional;Introduction . . . . . . . . . . . . . . . 1 . . . . . . . . . . . . . .The Problem of Hazard 1 Weather and Hazard . . . . . . . . . . . . . . 5 Types and Classes of Rot . . . . . 6 . . . . . . . . . . . .Trunk

  18. Rice Field Geochemistry and Hydrology: An Explanation for Why Groundwater Irrigated Fields in Bangladesh are Net Sinks of Arsenic from Groundwater

    E-Print Network [OSTI]

    Neumann, Rebecca B.

    Irrigation of rice fields in Bangladesh with arsenic-contaminated groundwater transfers tens of cubic kilometers of water and thousands of tons of arsenic from aquifers to rice fields each year. Here we combine observations ...

  19. Metal impacts on microbial biomass in the anoxic sediments of a contaminated lake

    SciTech Connect (OSTI)

    Gough, Heidi L.; Dahl, Amy L.; Nolan, Melissa A.; Gaillard, Jean-Francois; Stahl, David A.

    2008-04-26T23:59:59.000Z

    Little is known about the long-term impacts of metal contamination on the microbiota of anoxic lake sediments. In this study, we examined microbial biomass and metals (arsenic, cadmium, chromium, copper, iron, lead, manganese, and zinc) in the sediments of Lake DePue, a backwater lake located near a former zinc smelter. Sediment core samples were examined using two independent measures for microbial biomass (total microscopic counts and total phospholipid-phosphate concentrations), and for various fractions of each metal (pore water extracts, sequential extractions, and total extracts of all studied metals and zinc speciation by X-ray absorption fine structure (XAFS). Zinc concentrations were up to 1000 times higher than reported for sediments in the adjacent Illinois River, and ranged from 21,400 mg/kg near the source to 1,680 mg/kg near the river. However, solid metal fractions were not well correlated with pore water concentrations, and were not good predictors of biomass concentrations. Instead, biomass, which varied among sites by as much as two-times, was inversely correlated with concentrations of pore water zinc and arsenic as established by multiple linear regression. Monitoring of other parameters known to naturally influence biomass in sediments (e.g., organic carbon concentrations, nitrogen concentrations, pH, sediment texture, and macrophytes) revealed no differences that could explain observed biomass trends. This study provides strong support for control of microbial abundance by pore water metal concentrations in contaminated freshwater sediments.

  20. New Mexico: Solar Glare Hazard Analysis Tool Maximizes Energy...

    Office of Environmental Management (EM)

    National Laboratories developed the Solar Glare Hazard Analysis Tool (SGHAT), a free Web-based tool that can quickly calculate potential visual hazards from proposed solar...

  1. airflow hazard visualization: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    257 Brookhaven National Laboratory LIGHT SOURCES DIRECTORATE Subject: Building 725 Fire Hazard AnalysisFire Hazard Assessment Physics Websites Summary: Brookhaven National...

  2. CRAD, Packaging and Transfer of Hazardous Materials and Materials...

    Office of Environmental Management (EM)

    CRAD, Packaging and Transfer of Hazardous Materials and Materials of National Security Interest Assessment Plan CRAD, Packaging and Transfer of Hazardous Materials and Materials of...

  3. A Volcanologist'S Review Of Atmospheric Hazards Of Volcanic Activity...

    Open Energy Info (EERE)

    atmospheric hazards caused by explosive volcanic activity. The hazard posed by fine silicate ash with long residence time in the atmosphere is probably much less serious than...

  4. Hazardous and Nonhazardous Solid Waste Applicant Disclosure Regulations (Mississippi)

    Broader source: Energy.gov [DOE]

    The purpose of the Hazardous and Nonhazardous Solid Waste Applicant Disclosure Regulations is to help maintain accountability and track data on the hazardous and nonhazardous waste sites in...

  5. October 2014 Natural Phenomena Hazards (NPH) Meeting - Tuesday...

    Office of Environmental Management (EM)

    Seismic Hazard Analysis for Nuclear Facilities at the Hanford Site, Eastern Washington, USA Natural Phenomena Hazards DOE-STD 1020-2012 & DOE Handbook A Probabilistic Approach to...

  6. The Idaho National Laboratory (INL) Senior Seismic Hazard Analysis...

    Office of Environmental Management (EM)

    SEISMIC HAZARD ANALYSIS FOR NUCLEAR FACILITIES AT THE HANFORD SITE, EASTERN WASHINGTON, USA A Probabilistic Seismic Hazard Analysis Update Review for Two DOE Sites and NGA-East...

  7. Sandia National Laboratories: Solar Glare Hazard Analysis Tool

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Glare Hazard Analysis Tool Solar Glare Hazard Analysis Tool Available for Download On March 13, 2014, in Energy, News, News & Events, Photovoltaic, Renewable Energy, Solar, Solar...

  8. Assessment of Health Hazards of Repeated Inhalation of Diesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Health Hazards of Repeated Inhalation of Diesel Emissions, with Comparisons to Other Source Emissions Assessment of Health Hazards of Repeated Inhalation of Diesel Emissions, with...

  9. Protecting the Grid from All Hazards | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Protecting the Grid from All Hazards Protecting the Grid from All Hazards October 31, 2014 - 2:10pm Addthis Patricia Hoffman Patricia Hoffman Assistant Secretary The Energy...

  10. The Waste Isolation Pilot Plant Hazardous Waste Facility Permit...

    Office of Environmental Management (EM)

    The Waste Isolation Pilot Plant Hazardous Waste Facility Permit, Waste Analysis Plan The Waste Isolation Pilot Plant Hazardous Waste Facility Permit, Waste Analysis Plan This...

  11. Processing of solid mixed waste containing radioactive and hazardous materials

    DOE Patents [OSTI]

    Gotovchikov, V.T.; Ivanov, A.V.; Filippov, E.A.

    1998-05-12T23:59:59.000Z

    Apparatus for the continuous heating and melting of a solid mixed waste bearing radioactive and hazardous materials to form separate metallic, slag and gaseous phases for producing compact forms of the waste material to facilitate disposal includes a copper split water-cooled (cold) crucible as a reaction vessel for receiving the waste material. The waste material is heated by means of the combination of a plasma torch directed into the open upper portion of the cold crucible and an electromagnetic flux produced by induction coils disposed about the crucible which is transparent to electromagnetic fields. A metallic phase of the waste material is formed in a lower portion of the crucible and is removed in the form of a compact ingot suitable for recycling and further processing. A glass-like, non-metallic slag phase containing radioactive elements is also formed in the crucible and flows out of the open upper portion of the crucible into a slag ingot mold for disposal. The decomposition products of the organic and toxic materials are incinerated and converted to environmentally safe gases in the melter. 6 figs.

  12. Processing of solid mixed waste containing radioactive and hazardous materials

    DOE Patents [OSTI]

    Gotovchikov, Vitaly T. (Moscow, RU); Ivanov, Alexander V. (Moscow, RU); Filippov, Eugene A. (Moscow, RU)

    1998-05-12T23:59:59.000Z

    Apparatus for the continuous heating and melting of a solid mixed waste bearing radioactive and hazardous materials to form separate metallic, slag and gaseous phases for producing compact forms of the waste material to facilitate disposal includes a copper split water-cooled (cold) crucible as a reaction vessel for receiving the waste material. The waste material is heated by means of the combination of a plasma torch directed into the open upper portion of the cold crucible and an electromagnetic flux produced by induction coils disposed about the crucible which is transparent to electromagnetic fields. A metallic phase of the waste material is formed in a lower portion of the crucible and is removed in the form of a compact ingot suitable for recycling and further processing. A glass-like, non-metallic slag phase containing radioactive elements is also formed in the crucible and flows out of the open upper portion of the crucible into a slag ingot mold for disposal. The decomposition products of the organic and toxic materials are incinerated and converted to environmentally safe gases in the melter.

  13. Interactions between trace metals, sodium and sorbents in combustion. Quarterly report No. 4, July 1, 1995--September 30, 1995

    SciTech Connect (OSTI)

    Wendt, J.O.L.; Davis, S.

    1995-10-15T23:59:59.000Z

    The proposed research is directed at an understanding of how to exploit interactions between sodium, toxic metals and sorbents, in order to optimize sorbents injection procedures, which can be used to capture and transform these metals into environmentally benign forms. The research will use a 17kW downflow, laboratory combustor, to yield data that can be interpreted in terms of fundamental kinetic mechanisms. Metals to be considered are lead, cadmium, and arsenic. Sorbents will be kaolinite, bauxite, and limestone. The role of sulfur will also be determined.

  14. Interactions between trace metals, sodium and sorbents in combustion. Quarterly report No. 3, April 1, 1995--June 30, 1995

    SciTech Connect (OSTI)

    Wendt, J.O.L.

    1995-09-06T23:59:59.000Z

    The proposed research is directed at an understanding of how to exploit interactions between sodium, toxic metals and sorbents, in order to optimize sorbents injection procedures, which can be used to capture and transform these metals into environmentally benign forms. The research will use a 17kW downflow, laboratory combustor, to yield data that can be interpreted in terms of fundamental kinetic mechanisms. Metals to be considered are lead, cadmium, and arsenic. Sorbents will be kaolinite, bauxite, and limestone. The role of sulfur will also be determined.

  15. Total and Inorganic Arsenic in Mid-Atlantic Marine Fish and Shellfish and Implications for Fish Advisories

    SciTech Connect (OSTI)

    Greene, Richard; Crecelius, Eric A.

    2006-02-06T23:59:59.000Z

    Up to 33.3 metric tons of arsenic trioxide were spilled off the Middle Atlantic coast of the United States in January of 1992 during a shipping accident. Historical fish tissue data for samples collected in the Delaware Inland Bays before and after the spill reveal a prominent spike in total arsenic in summer flounder following the spill and a gradual decline ever since. In 2002, a small study was conducted to determine whether summer flounder migrating into the Delaware Inland Bays from the Continental Shelf in the spring contain higher body burdens of arsenic than summer flounder migrating out of the Inland Bays in the fall. Total arsenic was significantly higher in the incoming fish. Considering that summer flounder overwinter at the spill site, that arsenic trioxide is a dense powder of limited solubility that would tend to incorporate into the sediments, and that summer flounder are demersal fish, we conclude that summer flounder accumulate arsenic offshore and that the likely source of their extra body burden is the spilled arsenic. Speciation of arsenic in the summer flounder, as well as in Atlantic croaker, striped bass, and hard clam reveal low concentrations (0.5 ? 20 ug/kg ww) of toxic inorganic arsenic. DMA was more than an order of magnitude greater in hard clam meats than in the other species tested, a finding attributed to arsenic uptake by phytoplankton and subsequent dietary uptake by the clam. Risk assessment using the inorganic arsenic concentrations was used to conclude that a fish advisory is not warranted.

  16. Arsenic speciation in multiple metal environments II. Micro-spectroscopic investigation of a CCA contaminated soil

    E-Print Network [OSTI]

    2006, Aus- tralia. stances (acid mine drainage, smelter wastes, pesticides, chro- mated copper arsenate

  17. Apparatus for incinerating hazardous waste

    DOE Patents [OSTI]

    Chang, R.C.W.

    1994-12-20T23:59:59.000Z

    An apparatus is described for incinerating wastes, including an incinerator having a combustion chamber, a fluid-tight shell enclosing the combustion chamber, an afterburner, an off-gas particulate removal system and an emergency off-gas cooling system. The region between the inner surface of the shell and the outer surface of the combustion chamber forms a cavity. Air is supplied to the cavity and heated as it passes over the outer surface of the combustion chamber. Heated air is drawn from the cavity and mixed with fuel for input into the combustion chamber. The pressure in the cavity is maintained at least approximately 2.5 cm WC higher than the pressure in the combustion chamber. Gases cannot leak from the combustion chamber since the pressure outside the chamber (inside the cavity) is higher than the pressure inside the chamber. The apparatus can be used to treat any combustible wastes, including biological wastes, toxic materials, low level radioactive wastes, and mixed hazardous and low level transuranic wastes. 1 figure.

  18. WESF natural phenomena hazards survey

    SciTech Connect (OSTI)

    Wagenblast, G.R., Westinghouse Hanford

    1996-07-01T23:59:59.000Z

    A team of engineers conducted a systematic natural hazards phenomena (NPH) survey for the 225-B Waste Encapsulation and Storage Facility (WESF). The survey is an assessment of the existing design documentation to serve as the structural design basis for WESF, and the Interim Safety Basis (ISB). The lateral force resisting systems for the 225-B building structures, and the anchorages for the WESF safety related systems were evaluated. The original seismic and other design analyses were technically reviewed. Engineering judgment assessments were made of the probability of NPH survival, including seismic, for the 225-B structures and WESF safety systems. The method for the survey is based on the experience of the investigating engineers,and documented earthquake experience (expected response) data.The survey uses knowledge on NPH performance and engineering experience to determine the WESF strengths for NPH resistance, and uncover possible weak links. The survey, in general, concludes that the 225-B structures and WESF safety systems are designed and constructed commensurate with the current Hanford Site design criteria.

  19. Apparatus for transporting hazardous materials

    DOE Patents [OSTI]

    Osterman, Robert A. (Canonsburg, PA); Cox, Robert (West Mifflin, PA)

    1992-01-01T23:59:59.000Z

    An apparatus and method are provided for selectively receiving, transporting, and releasing one or more radioactive or other hazardous samples for analysis on a differential thermal analysis (DTA) apparatus. The apparatus includes a portable sample transporting apparatus for storing and transporting the samples and includes a support assembly for supporting the transporting apparatus when a sample is transferred to the DTA apparatus. The transporting apparatus includes a storage member which includes a plurality of storage chambers arrayed circumferentially with respect to a central axis. An adjustable top door is located on the top side of the storage member, and the top door includes a channel capable of being selectively placed in registration with the respective storage chambers thereby permitting the samples to selectively enter the respective storage chambers. The top door, when closed, isolates the respective samples within the storage chambers. A plurality of spring-biased bottom doors are located on the bottom sides of the respective storage chambers. The bottom doors isolate the samples in the respective storage chambers when the bottom doors are in the closed position. The bottom doors permit the samples to leave the respective storage chambers from the bottom side when the respective bottom doors are in respective open positions. The bottom doors permit the samples to be loaded into the respective storage chambers after the analysis for storage and transport to a permanent storage location.

  20. Hazardous Waste Compliance Program Plan

    SciTech Connect (OSTI)

    Potter, G.L.; Holstein, K.A.

    1994-05-01T23:59:59.000Z

    The Hazardous Waste Compliance Program Plan (HWCPP) describes how the Rocky Flats Plant institutes a more effective waste management program designed to achieve and maintain strict adherence to the Resource Conservation and Recovery Act (RCRA) requirements. Emphasis is given to improve integration of line operations with programmatic and functional support activities necessary to achieve physical compliance to RCRA regulated equipment, facilities and operations at the floor level. This program focuses on specific activities occurring or which need to occur within buildings containing RCRA regulated units and activities. The plan describes a new approach to achieving and maintaining compliance. This approach concentrates authority and accountability for compliance with the line operating personnel, with support provided from the programmatic functions. This approach requires a higher degree of integration and coordination between operating and program support organizations. The principal changes in emphases are; (1) increased line operations involvement, knowledge and accountability in compliance activities, (2) improved management systems to identify, correct and/or avoid deficiencies and (3) enhanced management attention and employee awareness of compliance related matters.

  1. Apparatus for incinerating hazardous waste

    DOE Patents [OSTI]

    Chang, Robert C. W. (Martinez, GA)

    1994-01-01T23:59:59.000Z

    An apparatus for incinerating wastes, including an incinerator having a combustion chamber, a fluidtight shell enclosing the combustion chamber, an afterburner, an off-gas particulate removal system and an emergency off-gas cooling system. The region between the inner surface of the shell and the outer surface of the combustion chamber forms a cavity. Air is supplied to the cavity and heated as it passes over the outer surface of the combustion chamber. Heated air is drawn from the cavity and mixed with fuel for input into the combustion chamber. The pressure in the cavity is maintained at least approximately 2.5 cm WC (about 1" WC) higher than the pressure in the combustion chamber. Gases cannot leak from the combustion chamber since the pressure outside the chamber (inside the cavity) is higher than the pressure inside the chamber. The apparatus can be used to treat any combustible wastes, including biological wastes, toxic materials, low level radioactive wastes, and mixed hazardous and low level transuranic wastes.

  2. Mobile machine hazardous working zone warning system

    DOE Patents [OSTI]

    Schiffbauer, W.H.; Ganoe, C.W.

    1999-08-17T23:59:59.000Z

    A warning system is provided for a mobile working machine to alert an individual of a potentially dangerous condition in the event the individual strays into a hazardous working zone of the machine. The warning system includes a transmitter mounted on the machine and operable to generate a uniform magnetic field projecting beyond an outer periphery of the machine in defining a hazardous working zone around the machine during operation. A receiver, carried by the individual and activated by the magnetic field, provides an alarm signal to alert the individual when he enters the hazardous working zone of the machine. 3 figs.

  3. 283-E and 283-W hazards assessment

    SciTech Connect (OSTI)

    Sutton, L.N.

    1994-09-26T23:59:59.000Z

    This report documents the hazards assessment for the 200 area water treatment plants 283-E and 283-W located on the US DOE Hanford Site. Operation of the water treatment plants is the responsibility of ICF Kaiser Hanford Company (ICF KH). This hazards assessment was conducted to provide emergency planning technical basis for the water treatment plants. This document represents an acceptable interpretation of the implementing guidance document for DOE ORDER 5500.3A which requires an emergency planning hazards assessment for each facility that has the potential to reach or exceed the lowest level emergency classification.

  4. Hazards Control Department annual technology review, 1987

    SciTech Connect (OSTI)

    Griffith, R.V.; Anderson, K.J. (eds.)

    1988-07-01T23:59:59.000Z

    This document describes some of the research performed in the LLNL Hazards Control Department from October 1986 to September 1987. The sections in the Annual report cover scientific concerns in the areas of Health Physics, Industrial Hygiene, Industrial Safety, Aerosol Science, Resource Management, Dosimetry and Radiation Physics, Criticality Safety, and Fire Science. For a broader overview of the types of work performed in the Hazards Control Department, we have also compiled a selection of abstracts of recent publications by Hazards Control employees. Individual reports are processed separately for the data base.

  5. Mobile machine hazardous working zone warning system

    DOE Patents [OSTI]

    Schiffbauer, William H. (Connellsville, PA); Ganoe, Carl W. (Pittsburgh, PA)

    1999-01-01T23:59:59.000Z

    A warning system is provided for a mobile working machine to alert an individual of a potentially dangerous condition in the event the individual strays into a hazardous working zone of the machine. The warning system includes a transmitter mounted on the machine and operable to generate a uniform magnetic field projecting beyond an outer periphery of the machine in defining a hazardous working zone around the machine during operation thereof. A receiver, carried by the individual and activated by the magnetic field, provides an alarm signal to alert the individual when he enters the hazardous working zone of the machine.

  6. Hazardous waste operational plan for site 300

    SciTech Connect (OSTI)

    Roberts, R.S.

    1982-02-12T23:59:59.000Z

    This plan outlines the procedures and operations used at LLNL's Site 300 for the management of the hazardous waste generated. This waste consists primarily of depleted uranium (a by-product of U-235 enrichment), beryllium, small quantities of analytical chemicals, industrial type waste such as solvents, cleaning acids, photographic chemicals, etc., and explosives. This plan details the operations generating this waste, the proper handling of this material and the procedures used to treat or dispose of the hazardous waste. A considerable amount of information found in this plan was extracted from the Site 300 Safety and Operational Manual written by Site 300 Facility personnel and the Hazards Control Department.

  7. Hazardous materials in aquatic environments of the Mississippi River Basin. Quarterly project status report, 1 April--30 June 1994

    SciTech Connect (OSTI)

    Not Available

    1994-08-01T23:59:59.000Z

    This report contains a cluster of twenty separate project reports concerning the fate, environmental transport, and toxicity of hazardous wastes in the Mississippi River Basin. Some of topics investigated involve: biological uptake and metabolism; heavy metal immobilization; biological indicators; toxicity; and mathematical models.

  8. Hazard Categorization Reduction via Nature of the Process Argument

    SciTech Connect (OSTI)

    Chelise A. Van De Graaff; Dr. Chad Pope; J. Todd Taylor

    2012-05-01T23:59:59.000Z

    This paper documents the Hazard Categorization (HC) and Critical Safety Evaluation (CSE) for activities performed using an Inspection Object (IO) in excess of the single parameter subcritical limit of 700 g of U-235. By virtue of exceeding the single parameter subcritical limit and the subsequent potential for criticality, the IO HC is initially categorized as HC2. However, a novel application of the nature of the process argument was employed to reduce the IO HC from HC2 to less than HC3 (LTHC3). The IO is composed of five separate uranium metal plates that total no greater than 3.82 kg of U-235 (U(20)). The IO is planned to be arranged in various configurations. As the IO serves as a standard for experimentation aimed at establishing techniques for detection of fissionable materials, it may be placed in close proximity to various reflectors, moderators, or both. The most reactive configurations of the IO were systematically evaluated and shown that despite the mass of U-235 and potential positioning near various reflectors and moderators, the IO cannot be assembled into a critical configuration. Therefore, the potential for criticality does not exist. With Department of Energy approval, a Hazards Assessment Document with high-level (facility-level) controls on the plates negates the potential for criticality and satisfies the nature of the process argument to reduce the HC from HC2 to LTHC3.

  9. Design characteristics for facilities which process hazardous particulate

    SciTech Connect (OSTI)

    Abeln, S.P.; Creek, K.; Salisbury, S.

    1998-12-01T23:59:59.000Z

    Los Alamos National Laboratory is establishing a research and processing capability for beryllium. The unique properties of beryllium, including light weight, rigidity, thermal conductivity, heat capacity, and nuclear properties make it critical to a number of US defense and aerospace programs. Concomitant with the unique engineering properties are the health hazards associated with processing beryllium in a particulate form and the potential for worker inhalation of aerosolized beryllium. Beryllium has the lowest airborne standard for worker protection compared to all other nonradioactive metals by more than an order of magnitude. This paper describes the design characteristics of the new beryllium facility at Los Alamos as they relate to protection of the workforce. Design characteristics to be reviewed include; facility layout, support systems to minimize aerosol exposure and spread, and detailed review of the ventilation system design for general room air cleanliness and extraction of particulate at the source.

  10. Hazards Control Department 1995 annual report

    SciTech Connect (OSTI)

    Campbell, G.W.

    1996-09-19T23:59:59.000Z

    This annual report of the Hazards Control Department activities in 1995 is part of the department`s efforts to foster a working environment at Lawrence Livermore National Laboratory (LLNL) where every person desire to work safely.

  11. Rainfall-induced Landslide Hazard Rating System

    E-Print Network [OSTI]

    Chen, Yi-Ting, Civ. E., Massachusetts Institute of Technology

    2011-01-01T23:59:59.000Z

    This research develops a Landslide Hazard Rating System for the rainfall-induced landslides in the Chenyulan River basin area in central Taiwan. This system is designed to provide a simplified and quick evaluation of the ...

  12. Hazardous materials transportation and emergency response programs

    SciTech Connect (OSTI)

    Joy, D.S.; Fore, C.S.

    1983-01-01T23:59:59.000Z

    This presentation consists of the following visual aids; (1) detailed routing capabilities of truck, rail, barge; (2) legislative data base for hazardous materials; and (3) emergency response of accident site Eddyville, Kentucky (airports in vicinity of Eddyville, KY).

  13. Wireless, automated monitoring for potential landslide hazards 

    E-Print Network [OSTI]

    Garich, Evan Andrew

    2007-09-17T23:59:59.000Z

    . Commercially available soil moisture probes and soil tilt sensors were combined with low-power, wireless data transmitters to form a self-configuring network of soil monitoring sensors. The remote locations of many slope stability hazard sites eliminates...

  14. Improving Tamper Detection for Hazardous Waste Security

    SciTech Connect (OSTI)

    Johnston, R. G.; Garcia, A. R. E.; Pacheco, N.; Martinez, R. K.; Martinez, D. D.; Trujillo, S. J.; Lopez, L. N.

    2003-02-26T23:59:59.000Z

    Since September 11, waste managers are increasingly expected to provide effective security for their hazardous wastes. Tamper-indicating seals can help. This paper discusses seals, and offers recommendations for how to choose and use them.

  15. Exploratory Studies Facility Subsurface Fire Hazards Analysis

    SciTech Connect (OSTI)

    Richard C. Logan

    2002-03-28T23:59:59.000Z

    The primary objective of this Fire Hazard Analysis (FHA) is to confirm the requirements for a comprehensive fire and related hazards protection program for the Exploratory Studies Facility (ESF) are sufficient to minimize the potential for: The occurrence of a fire or related event; A fire that causes an unacceptable on-site or off-site release of hazardous or radiological material that will threaten the health and safety of employees, the public or the environment; Vital U.S. Department of Energy (DOE) programs suffering unacceptable interruptions as a result of fire and related hazards; Property losses from a fire and related events exceeding limits established by DOE; and Critical process controls and safety class systems being damaged as a result of a fire and related events.

  16. Exploratory Studies Facility Subsurface Fire Hazards Analysis

    SciTech Connect (OSTI)

    J. L. Kubicek

    2001-09-07T23:59:59.000Z

    The primary objective of this Fire Hazard Analysis (FHA) is to confirm the requirements for a comprehensive fire and related hazards protection program for the Exploratory Studies Facility (ESF) are sufficient to minimize the potential for: (1) The occurrence of a fire or related event. (2) A fire that causes an unacceptable on-site or off-site release of hazardous or radiological material that will threaten the health and safety of employees, the public or the environment. (3) Vital US. Department of Energy (DOE) programs suffering unacceptable interruptions as a result of fire and related hazards. (4) Property losses from a fire and related events exceeding limits established by DOE. (5) Critical process controls and safety class systems being damaged as a result of a fire and related events.

  17. Massachusetts Hazardous Waste Facility Siting Act (Massachusetts)

    Broader source: Energy.gov [DOE]

    This Act establishes the means by which developers of proposed hazardous waste facilities will work with the community in which they wish to construct a facility. When the intent to construct,...

  18. Hazardous Waste Management Act (South Dakota)

    Broader source: Energy.gov [DOE]

    It is the public policy of the state of South Dakota to regulate the control and generation, transportation, treatment, storage, and disposal of hazardous wastes. The state operates a comprehensive...

  19. Hazardous Materials Packaging and Transportation Safety

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2015-04-20T23:59:59.000Z

    The Order establishes safety requirements for the proper packaging and transportation of Department of offsite shipments and onsite transfers of radioactive and other hazardous materials, and for modal transportation.

  20. Oil or Hazardous Spills Releases Law (Georgia)

    Broader source: Energy.gov [DOE]

    The Oil or Hazardous Spills Law requires notice to the Environmental Protection Division of the State Department of Natural Resources Emergency Operations Center when there is a spill or release of...

  1. Technical basis document for natural event hazards

    SciTech Connect (OSTI)

    CARSON, D.M.

    2003-03-20T23:59:59.000Z

    This technical basis document was developed to support the Tank Farms Documented Safety Analysis (DSA), and describes the risk binning process and the technical basis for assigning risk bins for natural event hazards (NEH)-initiated representative accident and associated represented hazardous conditions. The purpose of the risk binning process is to determine the need for safety-significant structures, systems, and components (SSC) and technical safety requirement (TSR)-level controls for a given representative accident or represented hazardous conditions based on an evaluation of the frequency and consequence. Note that the risk binning process is not applied to facility workers, because all facility worker hazardous conditions are considered for safety-significant SSCs and/or TSR-level controls. Determination of the need for safety-class SSCs was performed in accordance with DOE-STD-3009-94, ''Preparation Guide for US Department of Energy Nonreactor Nuclear Facility Documented Safety Analyses'', as described in this report.

  2. Evaluation of the serum catalase and myeloperoxidase activities in chronic arsenic-exposed individuals and concomitant cytogenetic damage

    SciTech Connect (OSTI)

    Banerjee, Mayukh; Banerjee, Nilanjana; Ghosh, Pritha [Molecular and Human Genetics Division, Indian Institute of Chemical Biology, Kolkata (India); Das, Jayanta K. [Department of Dermatology, West Bank Hospital, Howrah (India); Basu, Santanu [Department of General Medicine, Sri Aurobindo Seva Kendra, Kolkata (India); Sarkar, Ajoy K. [Peerless Hospital and B.K Roy Research Centre, Kolkata (India); States, J. Christopher, E-mail: jcstates@louisville.ed [Department of Pharmacology and Toxicology, University of Louisville, Louisville, KY (United States); Center for Environmental Genomics and Integrative Biology, University of Louisville, Louisville, KY (United States); Giri, Ashok K., E-mail: akgiri15@yahoo.co [Molecular and Human Genetics Division, Indian Institute of Chemical Biology, Kolkata (India)

    2010-11-15T23:59:59.000Z

    Chronic arsenic exposure through contaminated drinking water is a major environmental health issue. Chronic arsenic exposure is known to exert its toxic effects by a variety of mechanisms, of which generation of reactive oxygen species (ROS) is one of the most important. A high level of ROS, in turn, leads to DNA damage that might ultimately culminate in cancer. In order to keep the level of ROS in balance, an array of enzymes is present, of which catalase (CAT) and myeloperoxidase (MPO) are important members. Hence, in this study, we determined the activities of these two enzymes in the sera and chromosomal aberrations (CA) in peripheral blood lymphocytes in individuals exposed and unexposed to arsenic in drinking water. Arsenic in drinking water and in urine was used as a measure of exposure. Our results show that individuals chronically exposed to arsenic have significantly higher CAT and MPO activities and higher incidence of CA. We found moderate positive correlations between CAT and MPO activities, induction of CA and arsenic in urine and water. These results indicate that chronic arsenic exposure causes higher CAT and MPO activities in serum that correlates with induction of genetic damage. We conclude that the serum levels of these enzymes might be used as biomarkers of early arsenic exposure induced disease much before the classical dermatological symptoms of arsenicosis begin to appear.

  3. Enhanced Adsorption of Arsenic onto Maghemites Nanoparticles: As(III) as a Probe of the Surface Structure and Heterogeneity

    E-Print Network [OSTI]

    van Geen, Alexander

    Enhanced Adsorption of Arsenic onto Maghemites Nanoparticles: As(III) as a Probe of the Surface between 300 and 20 nm. However, nanoparticles smaller than 20 nm exhibit enhanced adsorption capacity. The origin of this observed size-dependence for adsorption or "nano effect" is unclear. Arsenic was chosen

  4. Mobilisation of arsenic from bauxite residue (red mud) affected soils: Effect of pH and redox conditions

    E-Print Network [OSTI]

    Burke, Ian

    ). Typically, it comprises residual iron oxides, quartz, sodium aluminosilicates, titanium dioxide, calciumMobilisation of arsenic from bauxite residue (red mud) affected soils: Effect of pH and redox elements, including arsenic. Aerobic and anaer- obic batch experiments were prepared using soils from near

  5. arsenic 77: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    leachate. Open Access Theses and Dissertations Summary: ??Transformation of heavy metals in landfill environment is currently not regulated by waste disposal guidelines....

  6. arsenic 91: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    leachate. Open Access Theses and Dissertations Summary: ??Transformation of heavy metals in landfill environment is currently not regulated by waste disposal guidelines....

  7. arsenic 75: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    leachate. Open Access Theses and Dissertations Summary: ??Transformation of heavy metals in landfill environment is currently not regulated by waste disposal guidelines....

  8. arsenic 72: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Open Access Theses and Dissertations Summary: ??Transformation of heavy metals in landfill environment is currently not regulated by waste disposal guidelines. Chromium,...

  9. arsenic cadmium cobalt: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    leachate. Open Access Theses and Dissertations Summary: ??Transformation of heavy metals in landfill environment is currently not regulated by waste disposal guidelines....

  10. Cold Vacuum Drying Facility hazard analysis report

    SciTech Connect (OSTI)

    Krahn, D.E.

    1998-02-23T23:59:59.000Z

    This report describes the methodology used in conducting the Cold Vacuum Drying Facility (CVDF) hazard analysis to support the CVDF phase 2 safety analysis report (SAR), and documents the results. The hazard analysis was performed in accordance with DOE-STD-3009-94, Preparation Guide for US Department of Energy Nonreactor Nuclear Facility Safety Analysis Reports, and implements the requirements of US Department of Energy (DOE) Order 5480.23, Nuclear Safety Analysis Reports.

  11. Process safety management for highly hazardous chemicals

    SciTech Connect (OSTI)

    NONE

    1996-02-01T23:59:59.000Z

    Purpose of this document is to assist US DOE contractors who work with threshold quantities of highly hazardous chemicals (HHCs), flammable liquids or gases, or explosives in successfully implementing the requirements of OSHA Rule for Process Safety Management of Highly Hazardous Chemicals (29 CFR 1910.119). Purpose of this rule is to prevent releases of HHCs that have the potential to cause catastrophic fires, explosions, or toxic exposures.

  12. Hazard Baseline Downgrade Effluent Treatment Facility

    SciTech Connect (OSTI)

    Blanchard, A.

    1998-10-21T23:59:59.000Z

    This Hazard Baseline Downgrade reviews the Effluent Treatment Facility, in accordance with Department of Energy Order 5480.23, WSRC11Q Facility Safety Document Manual, DOE-STD-1027-92, and DOE-EM-STD-5502-94. It provides a baseline grouping based on the chemical and radiological hazards associated with the facility. The Determination of the baseline grouping for ETF will aid in establishing the appropriate set of standards for the facility.

  13. Canister storage building hazard analysis report

    SciTech Connect (OSTI)

    Krahn, D.E.; Garvin, L.J.

    1997-07-01T23:59:59.000Z

    This report describes the methodology used in conducting the Canister Storage Building (CSB) hazard analysis to support the final CSB safety analysis report (SAR) and documents the results. The hazard analysis was performed in accordance with DOE-STD-3009-94, Preparation Guide for US Department of Energy Nonreactor Nuclear Facility Safety Analysis Report, and implements the requirements of DOE Order 5480.23, Nuclear Safety Analysis Report.

  14. Advanced Technology for Railway Hydraulic Hazard Forecasting

    E-Print Network [OSTI]

    Huff, William Edward 1988-

    2012-12-05T23:59:59.000Z

    Page 1.1 Map of Total Railway Hydraulic Hazard Events from 1982-2011 ............ 2 1.2 90 mi Effective Radar Coverage for Reliable Rainfall Rate Determination ....................................................................... 5 3... Administration (FRA) for the period of 1982-2011. This data was compiled from the FRA Office of Safety Analysis website (FRA, 2011). A map of the railway hydraulic hazard events over the same time period is displayed in Figure 1.1. Table 1.1. U.S. Railway...

  15. Arsenic pilot plant operation and results - Socorro Springs, New Mexico - phase 1.

    SciTech Connect (OSTI)

    Aragon, Malynda Jo; Everett, Randy L.; Siegel, Malcolm Dean; Kottenstette, Richard Joseph; Holub, William E. Jr; Wright, Jeremy B.; Dwyer, Brian P.

    2007-05-01T23:59:59.000Z

    Sandia National Laboratories (SNL) is conducting pilot scale evaluations of the performance and cost of innovative water treatment technologies aimed at meeting the recently revised arsenic maximum contaminant level (MCL) for drinking water. The standard of 10 {micro}g/L (10 ppb) is effective as of January 2006. The first pilot tests have been conducted in New Mexico where over 90 sites that exceed the new MCL have been identified by the New Mexico Environment Department. The pilot test described in this report was conducted in Socorro New Mexico between January 2005 and July 2005. The pilot demonstration is a project of the Arsenic Water Technology Partnership program, a partnership between the American Water Works Association Research Foundation (AwwaRF), SNL and WERC (A Consortium for Environmental Education and Technology Development). The Sandia National Laboratories pilot demonstration at the Socorro Springs site obtained arsenic removal performance data for five different adsorptive media under constant ambient flow conditions. Well water at Socorro Springs has approximately 42 ppb arsenic in the oxidized (arsenate-As(V)) redox state with moderate amounts of silica, low concentrations of iron and manganese and a slightly alkaline pH (8). The study provides estimates of the capacity (bed volumes until breakthrough at 10 ppb arsenic) of adsorptive media in the same chlorinated water. Near the end of the test the feedwater pH was lowered to assess the affect on bed capacity and as a prelude to a controlled pH study (Socorro Springs Phase 2).

  16. Cumulative arsenic exposure and lung cancer in smelter workers: a dose-response study

    SciTech Connect (OSTI)

    Jaerup, L.P.; Pershagen, G.; Wall, S.

    1989-01-01T23:59:59.000Z

    The cause-specific mortality was followed through 1981 in a cohort of 3,916 male Swedish smelter workers employed for at least 3 months from 1928 through 1967. Arsenic levels in the air of all workplaces within the smelter were estimated for three different time periods. Using this exposure matrix and detailed information of the work history, cumulative arsenic exposure could be computed for each worker. Standardized mortality ratios (SMRs) were calculated for several dose categories using age-specific mortality rates from the county where the smelter was situated. A positive dose-response relationship was found between cumulative arsenic exposure and lung cancer mortality with an overall SMR of 372 (304-450, 95% confidence interval). The lung cancer mortality was related to the estimated average intensity of exposure to arsenic but not to the duration. No positive dose-response relationship was found between arsenic and ischemic heart disease or cerebrovascular disease. There was also no evident dose-response relationship between estimated exposure to sulfur dioxide and lung cancer.

  17. Homogeneous and Heterogeneous Reaction and Transformation of Hg and Trace Metals in Combustion Systems

    SciTech Connect (OSTI)

    J. Helble; Clara Smith; David Miller

    2009-08-31T23:59:59.000Z

    The overall goal of this project was to produce a working dynamic model to predict the transformation and partitioning of trace metals resulting from combustion of a broad range of fuels. The information provided from this model will be instrumental in efforts to identify fuels and conditions that can be varied to reduce metal emissions. Through the course of this project, it was determined that mercury (Hg) and arsenic (As) would be the focus of the experimental investigation. Experiments were therefore conducted to examine homogeneous and heterogeneous mercury oxidation pathways, and to assess potential interactions between arsenic and calcium. As described in this report, results indicated that the role of SO{sub 2} on Hg oxidation was complex and depended upon overall gas phase chemistry, that iron oxide (hematite) particles contributed directly to heterogeneous Hg oxidation, and that As-Ca interactions occurred through both gas-solid and within-char reaction pathways. Modeling based on this study indicated that, depending upon coal type and fly ash particle size, vaporization-condensation, vaporization-surface reaction, and As-CaO in-char reaction all play a role in arsenic transformations under combustion conditions.

  18. Maternal exposure to metals—Concentrations and predictors of exposure

    SciTech Connect (OSTI)

    Callan, A.C., E-mail: a.callan@ecu.edu.au [Centre for Ecosystem Management, Edith Cowan University, 270 Joondalup Drive, Joondalup, WA 6027 (Australia); Hinwood, A.L.; Ramalingam, M.; Boyce, M. [Centre for Ecosystem Management, Edith Cowan University, 270 Joondalup Drive, Joondalup, WA 6027 (Australia)] [Centre for Ecosystem Management, Edith Cowan University, 270 Joondalup Drive, Joondalup, WA 6027 (Australia); Heyworth, J. [School Population Health, The University of Western Australia, 35 Stirling Highway Crawley, WA 6009 (Australia)] [School Population Health, The University of Western Australia, 35 Stirling Highway Crawley, WA 6009 (Australia); McCafferty, P. [ChemCentre, PO Box 1250, Bentley, WA 6983 (Australia)] [ChemCentre, PO Box 1250, Bentley, WA 6983 (Australia); Odland, J.Ø. [Department of Community Medicine, University of Tromsø, N-9037 Tromsø (Norway)] [Department of Community Medicine, University of Tromsø, N-9037 Tromsø (Norway)

    2013-10-15T23:59:59.000Z

    A variety of metals are important for biological function but have also been shown to impact health at elevated concentrations, whereas others have no known biological function. Pregnant women are a vulnerable population and measures to reduce exposure in this group are important. We undertook a study of maternal exposure to the metals, aluminium, arsenic, copper, cobalt, chromium, lithium, manganese, nickel, selenium, tin, uranium and zinc in 173 participants across Western Australia. Each participant provided a whole blood and urine sample, as well as drinking water, residential soil and dust samples and completed a questionnaire. In general the concentrations of metals in all samples were low with the notable exception of uranium (blood U mean 0.07 µg/L, range <0.01–0.25 µg/L; urinary U mean 0.018 µg/g creatinine, range <0.01–0.199 µg/g creatinine). Factors that influenced biological concentrations were consumption of fish which increased urinary arsenic concentrations, hobbies (including mechanics and welding) which increased blood manganese concentrations and iron/folic acid supplement use which was associated with decreased concentrations of aluminium and nickel in urine and manganese in blood. Environmental concentrations of aluminium, copper and lithium were found to influence biological concentrations, but this was not the case for other environmental metals concentrations. Further work is underway to explore the influence of diet on biological metals concentrations in more detail. The high concentrations of uranium require further investigation. -- Highlights: • High concentrations of uranium with respect to international literature. • Environmental concentrations of Al, Cu and Li influenced urinary concentrations. • Exposure to mechanics/welding hobbies increased blood Mn concentrations. • Iron/Folic acid supplements reduced biological concentrations of Al, Ni and Mn.

  19. The University of Texas at Dallas Texas Hazardous Communication Act

    E-Print Network [OSTI]

    O'Toole, Alice J.

    The University of Texas at Dallas Texas Hazardous Communication Act Handbook #12;TEXAS HAZARDOUS IV. Texas Hazard Communication Act Exemptions V. Implementation A. Employee Rights Under the Act Explanation IX. Written Hazard Communication Program A. Manufacturers' Labels and Other Forms of Warning B

  20. Hazardous Material Code Identification NFPA 704, 1996 Edition

    E-Print Network [OSTI]

    Slatton, Clint

    Hazardous Material Code Identification NFPA 704, 1996 Edition Identification of Health Hazard Color offer no hazard. 00 Materials that will not burn. 00 Materials that in themselves are normally stable DAMAGE TO LIVING TISSUE. MATERIALS POSSESSING RADIOACTIVITY HAZARDS. The identification systems