National Library of Energy BETA

Sample records for half-sample stratum pair402

  1. --No Title--

    U.S. Energy Information Administration (EIA) Indexed Site

    File02: (file02cb83.csv) BLDGID2 Building ID STR402 Half-sample stratum PAIR402 Half-sample pair number SQFTC2 Square footage SQFTC17. BCWM2C Principal activity BCWOM25. ...

  2. U.S. Energy Information Administration (EIA) Indexed Site

    File02: (file02_cb83.csv) BLDGID2 Building ID STR402 Half-sample stratum PAIR402 Half-sample pair number SQFTC2 Square footage $SQFTC17. BCWM2C Principal activity $BCWOM25. YRCONC2C Year constructed $YRCONC15 REGION2 Census region $REGION13 XSECWT2 Cross-sectional weight ELSUPL2N Supplier reported electricity use $YESNO15. NGSUPL2N Supplier reported natural gas use $YESNO15. FKSUPL2N Supplier reported fuel oil use $YESNO15. STSUPL2N Supplier reported steam use $YESNO15. PRSUPL2N Supplier

  3. Y-12s Training and Technology instructors story ? Terry...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    storied about things that took place at TAT. There were people from every race, every religion and every social stratum there so you can imagine. Most of them, however, can't be...

  4. Method for in situ heating of hydrocarbonaceous formations

    DOE Patents [OSTI]

    Little, William E. (Morgantown, WV); McLendon, Thomas R. (Laramie, WY)

    1987-01-01

    A method for extracting valuable constituents from underground hydrocarbonaceous deposits such as heavy crude tar sands and oil shale is disclosed. Initially, a stratum containing a rich deposit is hydraulically fractured to form a horizontally extending fracture plane. A conducting liquid and proppant is then injected into the fracture plane to form a conducting plane. Electrical excitations are then introduced into the stratum adjacent the conducting plate to retort the rich stratum along the conducting plane. The valuable constituents from the stratum adjacent the conducting plate are then recovered. Subsequently, the remainder of the deposit is also combustion retorted to further recover valuable constituents from the deposit. Various R.F. heating systems are also disclosed for use in the present invention.

  5. EVENT TREE ANALYSIS AT THE SAVANNAH RIVER SITE: A CASE HISTORY

    SciTech Connect (OSTI)

    Williams, R

    2009-05-25

    At the Savannah River Site (SRS), a Department of Energy (DOE) installation in west-central South Carolina there is a unique geologic stratum that exists at depth that has the potential to cause surface settlement resulting from a seismic event. In the past the particular stratum in question has been remediated via pressure grouting, however the benefits of remediation have always been debatable. Recently the SRS has attempted to frame the issue in terms of risk via an event tree or logic tree analysis. This paper describes that analysis, including the input data required.

  6. U.S. Energy Information Administration (EIA) Indexed Site

    File 3: Operating Hours (cb86f03.csv) Ques- tion- naire Variable Variable Variable Variable item Description Name Position Format Building identifier BLDGID3 1- 5 Adjusted weight ADJWT3 7- 14 Variance stratum STRATUM3 16- 17 Pair member PAIR3 19- 19 Census region REGION3 21- 21 $REGION. Census division CENDIV3 23- 23 $CENDIV. B-2 Square footage SQFTC3 25- 26 $SQFTC. Principal building activity PBA3 28- 29 $ACTIVTY. Regular operating hours REGHRS3 31- 31 $YESNO. C-5 Monday thru Friday opening

  7. U.S. Energy Information Administration (EIA) Indexed Site

    File 4: Building Shell, Equipment, Energy Audits, and "Ohter" Conservation Features (cb86f04.csv) Ques- tion- naire Variable Variable Variable Variable item Description Name Position Format Building identifier BLDGID3 1- 5 Adjusted weight ADJWT3 7- 14 Variance stratum STRATUM3 16- 17 Pair member PAIR3 19- 19 Census region REGION3 21- 21 $REGION. Census division CENDIV3 23- 23 $CENDIV. B-2 Square footage SQFTC3 25- 26 $SQFTC. Principal building activity PBA3 28- 29 $ACTIVTY. D-2 Year

  8. U.S. Energy Information Administration (EIA) Indexed Site

    6: End Uses of Minor Energy Sources (cb86f06.csv) Ques- tion- naire Variable Variable Variable Variable item Description Name Position Format Building identifier BLDGID3 1- 5 Adjusted weight ADJWT3 7- 14 Variance stratum STRATUM3 16- 17 Pair member PAIR3 19- 19 Census region REGION3 21- 21 $REGION. Census division CENDIV3 23- 23 $CENDIV. B-2 Square footage SQFTC3 25- 26 $SQFTC. Principal building activity PBA3 28- 29 $ACTIVTY. D-2 Year construction was completed YRCONC3 31- 32 $YRCONC.

  9. U.S. Energy Information Administration (EIA) Indexed Site

    File12: Imputation Flags for Summary Data, Building Activity, Operating Hours, Shell and Equipment (cb86f12.csv) Ques- tion- naire Variable Variable Variable Variable item Description Name Position Format Building identifier BLDGID3 1- 5 Adjusted weight ADJWT3 7- 14 Variance stratum STRATUM3 16- 17 Pair member PAIR3 19- 19 Census region REGION3 21- 21 $REGION. Census division CENDIV3 23- 23 $CENDIV. B-2 Square footage SQFTC3 25- 26 $SQFTC. Principal building activity PBA3 28- 29 $ACTIVTY. D-2

  10. T:\ClearanceEMEUConsumption\cbecs\pubuse86\txt\cb86sasfmt&layout.txt

    U.S. Energy Information Administration (EIA) Indexed Site

    6/txt/cb86sasfmt&layout.txt[3/17/2009 4:43:14 PM] File 1: Summary File (cb86f01.csv) Ques- tion- naire Variable Variable Variable Variable item Description Name Position Format Building identifier BLDGID3 1- 5 Adjusted weight ADJWT3 7- 14 Variance stratum STRATUM3 16- 17 Pair member PAIR3 19- 19 Census region REGION3 21- 21 $REGION. Census division CENDIV3 23- 23 $CENDIV. Metropolitan statistical area MSA3 25- 25 $MSA. Climate zone CLIMATE3 27- 27 $CLIMAT. B-1 Square footage SQFT3 29- 35

  11. Determination of Dusty Particle Charge Taking into Account Ion Drag

    SciTech Connect (OSTI)

    Ramazanov, T. S.; Dosbolayev, M. K.; Jumabekov, A. N.; Amangaliyeva, R. Zh.; Orazbayev, S. A.; Petrov, O. F.; Antipov, S. N.

    2008-09-07

    This work is devoted to the experimental estimation of charge of dust particle that levitates in the stratum of dc glow discharge. Particle charge is determined on the basis of the balance between ion drag force, gravitational and electric forces. Electric force is obtained from the axial distribution of the light intensity of strata.

  12. Breakthrough antibacterial approach could resolve serious skin infections

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Antibacterial approach could resolve skin infections Breakthrough antibacterial approach could resolve serious skin infections Like a protective tent over a colony of harmful bacteria, biofilms make the treatment of skin infections especially difficult. August 26, 2014 Artist's rendition of a cross section of skin layers (stratum corneum, epidermis and dermis) showing topical application of an ionic liquid for combating a skin-borne bacterial infection. The ionic liquid can be formulated with

  13. Gauging apparatus and method, particularly for controlling mining by a mining machine

    SciTech Connect (OSTI)

    Campbell, J.A.; Moynihan, D.J.

    1980-04-29

    Apparatus for and method are claimed for controlling the mining by a mining machine of a seam of material (e.g., coal) overlying or underlying a stratum of undesired material (e.g., clay) to reduce the quantity of undesired material mined with the desired material, the machine comprising a cutter movable up and down and adapted to cut down into a seam of coal on being lowered. The control apparatus comprises a first electrical signal constituting a slow-down signal adapted to be automatically operated to signal when the cutter has cut down into a seam of desired material generally to a predetermined depth short of the interface between the seam and the underlying stratum for slowing down the cutting rate as the cutter approaches the interface, and a second electrical signal adapted to be automatically operated subsequent to the first signal for signalling when the cutter has cut down through the seam to the interface for stopping the cutting operation, thereby to avoid mining undesired material with the desired material. Similar signalling may be provided on an upward cut to avoid cutting into the overlying stratum.

  14. A BASIS FOR MODIFYING THE TANK 12 COMPOSITE SAMPLING DESIGN

    SciTech Connect (OSTI)

    Shine, G.

    2014-11-25

    The SRR sampling campaign to obtain residual solids material from the Savannah River Site (SRS) Tank Farm Tank 12 primary vessel resulted in obtaining appreciable material in all 6 planned source samples from the mound strata but only in 5 of the 6 planned source samples from the floor stratum. Consequently, the design of the compositing scheme presented in the Tank 12 Sampling and Analysis Plan, Pavletich (2014a), must be revised. Analytical Development of SRNL statistically evaluated the sampling uncertainty associated with using various compositing arrays and splitting one or more samples for compositing. The variance of the simple mean of composite sample concentrations is a reasonable standard to investigate the impact of the following sampling options. Composite Sample Design Option (a). Assign only 1 source sample from the floor stratum and 1 source sample from each of the mound strata to each of the composite samples. Each source sample contributes material to only 1 composite sample. Two source samples from the floor stratum would not be used. Composite Sample Design Option (b). Assign 2 source samples from the floor stratum and 1 source sample from each of the mound strata to each composite sample. This infers that one source sample from the floor must be used twice, with 2 composite samples sharing material from this particular source sample. All five source samples from the floor would be used. Composite Sample Design Option (c). Assign 3 source samples from the floor stratum and 1 source sample from each of the mound strata to each composite sample. This infers that several of the source samples from the floor stratum must be assigned to more than one composite sample. All 5 source samples from the floor would be used. Using fewer than 12 source samples will increase the sampling variability over that of the Basic Composite Sample Design, Pavletich (2013). Considering the impact to the variance of the simple mean of the composite sample concentrations, the recommendation is to construct each sample composite using four or five source samples. Although the variance using 5 source samples per composite sample (Composite Sample Design Option (c)) was slightly less than the variance using 4 source samples per composite sample (Composite Sample Design Option (b)), there is no practical difference between those variances. This does not consider that the measurement error variance, which is the same for all composite sample design options considered in this report, will further dilute any differences. Composite Sample Design Option (a) had the largest variance for the mean concentration in the three composite samples and should be avoided. These results are consistent with Pavletich (2014b) which utilizes a low elevation and a high elevation mound source sample and two floor source samples for each composite sample. Utilizing the four source samples per composite design, Pavletich (2014b) utilizes aliquots of Floor Sample 4 for two composite samples.

  15. Geothermal Glossary | Department of Energy

    Office of Environmental Management (EM)

    Glossary Geothermal Glossary This list contains terms related to geothermal energy and technologies./ A | B | C | D | E | F | G | H | I | J | K | L | M | N | O | P | Q | R | S | T | U | V | W | X | Y | Z A Ambient Natural condition of the environment at any given time. / Aquifer Water-bearing stratum of permeable sand, rock, or gravel./ Back to Top/ B Baseload Plants Electricity-generating units that are operated to meet the constant or minimum load on the system. The cost of energy from such

  16. Structure and method for controlling band offset and alignment at a crystalline oxide-on-semiconductor interface

    DOE Patents [OSTI]

    McKee, Rodney A.; Walker, Frederick J.

    2003-11-25

    A crystalline oxide-on-semiconductor structure and a process for constructing the structure involves a substrate of silicon, germanium or a silicon-germanium alloy and an epitaxial thin film overlying the surface of the substrate wherein the thin film consists of a first epitaxial stratum of single atomic plane layers of an alkaline earth oxide designated generally as (AO).sub.n and a second stratum of single unit cell layers of an oxide material designated as (A'BO.sub.3).sub.m so that the multilayer film arranged upon the substrate surface is designated (AO).sub.n (A'BO.sub.3).sub.m wherein n is an integer repeat of single atomic plane layers of the alkaline earth oxide AO and m is an integer repeat of single unit cell layers of the A'BO.sub.3 oxide material. Within the multilayer film, the values of n and m have been selected to provide the structure with a desired electrical structure at the substrate/thin film interface that can be optimized to control band offset and alignment.

  17. Detailed Studies of Hydrocarbon Radicals: C2H Dissociation

    SciTech Connect (OSTI)

    Wittig, Curt

    2014-10-06

    A novel experimental technique was examined whose goal was the ejection of radical species into the gas phase from a platform (film) of cold non-reactive material. The underlying principle was one of photo-initiated heat release in a stratum that lies below a layer of CO2 or a layer of amorphous solid water (ASW) and CO2. A molecular precursor to the radical species of interest is deposited near or on the film's surface, where it can be photo-dissociated. It proved unfeasible to avoid the rampant formation of fissures, as opposed to large "flakes." This led to many interesting results, but resulted in our aborting the scheme as a means of launching cold C2H radical into the gas phase. A journal article resulted that is germane to astrophysics but not combustion chemistry.

  18. Fuel injector system

    DOE Patents [OSTI]

    Hsu, Bertrand D. (Erie, PA); Leonard, Gary L. (Schenctady, NY)

    1988-01-01

    A fuel injection system particularly adapted for injecting coal slurry fuels at high pressures includes an accumulator-type fuel injector which utilizes high-pressure pilot fuel as a purging fluid to prevent hard particles in the fuel from impeding the opening and closing movement of a needle valve, and as a hydraulic medium to hold the needle valve in its closed position. A fluid passage in the injector delivers an appropriately small amount of the ignition-aiding pilot fuel to an appropriate region of a chamber in the injector's nozzle so that at the beginning of each injection interval the first stratum of fuel to be discharged consists essentially of pilot fuel and thereafter mostly slurry fuel is injected.

  19. Absorption of ethanol, acetone, benzene and 1,2-dichloroethane through human skin in vitro: a test of diffusion model predictions

    SciTech Connect (OSTI)

    Gajjar, Rachna M.; Kasting, Gerald B.

    2014-11-15

    The overall goal of this research was to further develop and improve an existing skin diffusion model by experimentally confirming the predicted absorption rates of topically-applied volatile organic compounds (VOCs) based on their physicochemical properties, the skin surface temperature, and the wind velocity. In vitro human skin permeation of two hydrophilic solvents (acetone and ethanol) and two lipophilic solvents (benzene and 1,2-dichloroethane) was studied in Franz cells placed in a fume hood. Four doses of each {sup 14}C-radiolabed compound were tested 5, 10, 20, and 40 ?L cm{sup ?2}, corresponding to specific doses ranging in mass from 5.0 to 63 mg cm{sup ?2}. The maximum percentage of radiolabel absorbed into the receptor solutions for all test conditions was 0.3%. Although the absolute absorption of each solvent increased with dose, percentage absorption decreased. This decrease was consistent with the concept of a stratum corneum deposition region, which traps small amounts of solvent in the upper skin layers, decreasing the evaporation rate. The diffusion model satisfactorily described the cumulative absorption of ethanol; however, values for the other VOCs were underpredicted in a manner related to their ability to disrupt or solubilize skin lipids. In order to more closely describe the permeation data, significant increases in the stratum corneum/water partition coefficients, K{sub sc}, and modest changes to the diffusion coefficients, D{sub sc}, were required. The analysis provided strong evidence for both skin swelling and barrier disruption by VOCs, even by the minute amounts absorbed under these in vitro test conditions. - Highlights: Human skin absorption of small doses of VOCs was measured in vitro in a fume hood. The VOCs tested were ethanol, acetone, benzene and 1,2-dichloroethane. Fraction of dose absorbed for all compounds at all doses tested was less than 0.3%. The more aggressive VOCs absorbed at higher levels than diffusion model predictions. We conclude that even small exposures to VOCs temporarily alter skin permeability.

  20. Statistical Analysis of Tank 5 Floor Sample Results

    SciTech Connect (OSTI)

    Shine, E. P.

    2013-01-31

    Sampling has been completed for the characterization of the residual material on the floor of Tank 5 in the F-Area Tank Farm at the Savannah River Site (SRS), near Aiken, SC. The sampling was performed by Savannah River Remediation (SRR) LLC using a stratified random sampling plan with volume-proportional compositing. The plan consisted of partitioning the residual material on the floor of Tank 5 into three non-overlapping strata: two strata enclosed accumulations, and a third stratum consisted of a thin layer of material outside the regions of the two accumulations. Each of three composite samples was constructed from five primary sample locations of residual material on the floor of Tank 5. Three of the primary samples were obtained from the stratum containing the thin layer of material, and one primary sample was obtained from each of the two strata containing an accumulation. This report documents the statistical analyses of the analytical results for the composite samples. The objective of the analysis is to determine the mean concentrations and upper 95% confidence (UCL95) bounds for the mean concentrations for a set of analytes in the tank residuals. The statistical procedures employed in the analyses were consistent with the Environmental Protection Agency (EPA) technical guidance by Singh and others [2010]. Savannah River National Laboratory (SRNL) measured the sample bulk density, nonvolatile beta, gross alpha, and the radionuclide1, elemental, and chemical concentrations three times for each of the composite samples. The analyte concentration data were partitioned into three separate groups for further analysis: analytes with every measurement above their minimum detectable concentrations (MDCs), analytes with no measurements above their MDCs, and analytes with a mixture of some measurement results above and below their MDCs. The means, standard deviations, and UCL95s were computed for the analytes in the two groups that had at least some measurements above their MDCs. The identification of distributions and the selection of UCL95 procedures generally followed the protocol in Singh, Armbya, and Singh [2010]. When all of an analyte's measurements lie below their MDCs, only a summary of the MDCs can be provided. The measurement results reported by SRNL are listed, and the results of this analysis are reported. The data were generally found to follow a normal distribution, and to be homogenous across composite samples.

  1. Portable measurement system for soil resistivity and application to Quaternary clayey sediment

    SciTech Connect (OSTI)

    Nakagawa, Koichi; Morii, Takeo

    1999-07-01

    A simple device to measure electrical resistivity has been developed for field and laboratory use. The measurement system comprises a probe unit, current wave generator, amplified, A/D converter, data acquisition unit with RS-232C interface and notebook personal computer. The system is applicable to soils and soft rocks as long as the probe needles can pierce into them. Frequency range of the measurement system extends from 100 Hz to 10 MHz. The total error of the system is less than 5%. In situ measurements of the resistivity and shear resistance by means of pocket-sized penetrometer were applied to Pleistocene clayey beds. Some laboratory tests were also conducted to examine the interpretation of the in situ resistivity. Marine and non-marine clayey sediments are different in their resistivities of the stratum by in situ test and the clay suspension sampled from the strata. Physical and mechanical properties were compared with the resistivity and general relationships among them were explored to clarify the characteristics of inter-particle bonding. Some possible mechanism regarding the peculiar weathering of clayey sediment or mudstone beds is discussed from the viewpoint of physico-chemical process, which is conspicuous especially near the ground surface.

  2. Conversion of borehole Stoneley waves to channel waves in coal

    SciTech Connect (OSTI)

    Johnson, P.A.; Albright, J.N.

    1987-01-01

    Evidence for the mode conversion of borehole Stoneley waves to stratigraphically guided channel waves was discovered in data from a crosswell acoustic experiment conducted between wells penetrating thin coal strata located near Rifle, Colorado. Traveltime moveout observations show that borehole Stoneley waves, excited by a transmitter positioned at substantial distances in one well above and below a coal stratum at 2025 m depth, underwent partial conversion to a channel wave propagating away from the well through the coal. In an adjacent well the channel wave was detected at receiver locations within the coal, and borehole Stoneley waves, arising from a second partial conversion of channel waves, were detected at locations above and below the coal. The observed channel wave is inferred to be the third-higher Rayleigh mode based on comparison of the measured group velocity with theoretically derived dispersion curves. The identification of the mode conversion between borehole and stratigraphically guided waves is significant because coal penetrated by multiple wells may be detected without placing an acoustic transmitter or receiver within the waveguide. 13 refs., 6 figs., 1 tab.

  3. Relationship of adiposity to the population distribution of plasma triglyceride concentrations in vigorously active men and women

    SciTech Connect (OSTI)

    Williams, Paul T.

    2002-12-21

    Context and Objective: Vigorous exercise, alcohol and weight loss are all known to increase HDL-cholesterol, however, it is not known whether these interventions raise low HDL as effectively as has been demonstrated for normal HDL. Design: Physician-supplied medical data from 7,288 male and 2,359 female runners were divided into five strata according to their self-reported usual running distance, reported alcohol intake, body mass index (BMI) or waist circumference. Within each stratum, the 5th, 10th, 25th, 50th, 75th, 90th, and 95th percentiles for HDL-cholesterol were then determined. Bootstrap resampling of least-squares regression was applied to determine the cross-sectional relationships between these factors and each percentile of the HDL-cholesterol distribution. Results: In both sexes, the rise in HDL-cholesterol per unit of vigorous exercise or alcohol intake was at least twice as great at the 95th percentile as at the 5th percentile of the HDL-distribution. There was also a significant graded increase in the slopes relating exercise (km run) and alcohol intake to HDL between the 5th and the 95th percentile. Men's HDL-cholesterol decreased in association with fatness (BMI and waist circumference) more sharply at the 95th than at the 5th percentile of the HDL-distribution. Conclusions: Although exercise, alcohol and adiposity were all related to HDL-cholesterol, the elevation in HDL per km run or ounce of alcohol consumed, and reduction in HDL per kg of body weight (men only), was least when HDL was low and greatest when HDL was high. These cross-sectional relationships support the hypothesis that men and women who have low HDL-cholesterol will be less responsive to exercise and alcohol (and weight loss in men) as compared to those who have high HDL-cholesterol.

  4. Studying methane migration mechanisms at Walker Ridge, Gulf of Mexico, via 3D methane hydrate reservoir modeling

    SciTech Connect (OSTI)

    Nole, Michael; Daigle, Hugh; Mohanty, Kishore; Cook, Ann; Hillman, Jess

    2015-12-15

    We have developed a 3D methane hydrate reservoir simulator to model marine methane hydrate systems. Our simulator couples highly nonlinear heat and mass transport equations and includes heterogeneous sedimentation, in-situ microbial methanogenesis, the influence of pore size contrast on solubility gradients, and the impact of salt exclusion from the hydrate phase on dissolved methane equilibrium in pore water. Using environmental parameters from Walker Ridge in the Gulf of Mexico, we first simulate hydrate formation in and around a thin, dipping, planar sand stratum surrounded by clay lithology as it is buried to 295mbsf. We find that with sufficient methane being supplied by organic methanogenesis in the clays, a 200x pore size contrast between clays and sands allows for a strong enough concentration gradient to significantly drop the concentration of methane hydrate in clays immediately surrounding a thin sand layer, a phenomenon that is observed in well log data. Building upon previous work, our simulations account for the increase in sand-clay solubility contrast with depth from about 1.6% near the top of the sediment column to 8.6% at depth, which leads to a progressive strengthening of the diffusive flux of methane with time. By including an exponentially decaying organic methanogenesis input to the clay lithology with depth, we see a decrease in the aqueous methane supplied to the clays surrounding the sand layer with time, which works to further enhance the contrast in hydrate saturation between the sand and surrounding clays. Significant diffusive methane transport is observed in a clay interval of about 11m above the sand layer and about 4m below it, which matches well log observations. The clay-sand pore size contrast alone is not enough to completely eliminate hydrate (as observed in logs), because the diffusive flux of aqueous methane due to a contrast in pore size occurs slower than the rate at which methane is supplied via organic methanogenesis. Therefore, it is likely that additional mechanisms are at play, notably bound water activity reduction in clays. Three-dimensionality allows for inclusion of lithologic heterogeneities, which focus fluid flow and subsequently allow for heterogeneity in the methane migration mechanisms that dominate in marine sediments at a local scale. Incorporating recently acquired 3D seismic data from Walker Ridge to inform the lithologic structure of our modeled reservoir, we show that even with deep adjective sourcing of methane along highly permeable pathways, local hydrate accumulations can be sourced either by diffusive or advective methane flux; advectively-sourced hydrates accumulate evenly in highly permeable strata, while diffusively-sourced hydrates are characterized by thin strata-bound intervals with high clay-sand pore size contrasts.

  5. Statistical techniques for characterizing residual waste in single-shell and double-shell tanks

    SciTech Connect (OSTI)

    Jensen, L., Fluor Daniel Hanford

    1997-02-13

    A primary objective of the Hanford Tank Initiative (HTI) project is to develop methods to estimate the inventory of residual waste in single-shell and double-shell tanks. A second objective is to develop methods to determine the boundaries of waste that may be in the waste plume in the vadose zone. This document presents statistical sampling plans that can be used to estimate the inventory of analytes within the residual waste within a tank. Sampling plans for estimating the inventory of analytes within the waste plume in the vadose zone are also presented. Inventory estimates can be used to classify the residual waste with respect to chemical and radiological hazards. Based on these estimates, it will be possible to make decisions regarding the final disposition of the residual waste. Four sampling plans for the residual waste in a tank are presented. The first plan is based on the assumption that, based on some physical characteristic, the residual waste can be divided into disjoint strata, and waste samples obtained from randomly selected locations within each stratum. The second plan is that waste samples are obtained from randomly selected locations within the waste. The third and fourth plans are similar to the first two, except that composite samples are formed from multiple samples. Common to the four plans is that, in the laboratory, replicate analytical measurements are obtained from homogenized waste samples. The statistical sampling plans for the residual waste are similar to the statistical sampling plans developed for the tank waste characterization program. In that program, the statistical sampling plans required multiple core samples of waste, and replicate analytical measurements from homogenized core segments. A statistical analysis of the analytical data, obtained from use of the statistical sampling plans developed for the characterization program or from the HTI project, provide estimates of mean analyte concentrations and confidence intervals on the mean. In addition, the statistical analysis provides estimates of spatial and measurement variabilities. The magnitude of these sources of variability are used to determine how well the inventory of the analytes in the waste have been estimated. This document provides statistical sampling plans that can be used to estimate the inventory of the analytes in the residual waste in single-shell and double-shell tanks and in the waste plume in the vadose zone.

  6. Temporary Cementitious Sealers in Enhanced Geothermal Systems

    SciTech Connect (OSTI)

    Sugama T.; Pyatina, T.; Butcher, T.; Brothers, L.; Bour, D.

    2011-12-31

    Unlike conventional hydrothennal geothermal technology that utilizes hot water as the energy conversion resources tapped from natural hydrothermal reservoir located at {approx}10 km below the ground surface, Enhanced Geothermal System (EGS) must create a hydrothermal reservoir in a hot rock stratum at temperatures {ge}200 C, present in {approx}5 km deep underground by employing hydraulic fracturing. This is the process of initiating and propagating a fracture as well as opening pre-existing fractures in a rock layer. In this operation, a considerable attention is paid to the pre-existing fractures and pressure-generated ones made in the underground foundation during drilling and logging. These fractures in terms of lost circulation zones often cause the wastage of a substantial amount of the circulated water-based drilling fluid or mud. Thus, such lost circulation zones must be plugged by sealing materials, so that the drilling operation can resume and continue. Next, one important consideration is the fact that the sealers must be disintegrated by highly pressured water to reopen the plugged fractures and to promote the propagation of reopened fractures. In response to this need, the objective of this phase I project in FYs 2009-2011 was to develop temporary cementitious fracture sealing materials possessing self-degradable properties generating when {ge} 200 C-heated scalers came in contact with water. At BNL, we formulated two types of non-Portland cementitious systems using inexpensive industrial by-products with pozzolanic properties, such as granulated blast-furnace slag from the steel industries, and fly ashes from coal-combustion power plants. These byproducts were activated by sodium silicate to initiate their pozzolanic reactions, and to create a cemetitious structure. One developed system was sodium silicate alkali-activated slag/Class C fly ash (AASC); the other was sodium silicate alkali-activated slag/Class F fly ash (AASF) as the binder of temper-try sealers. Two specific additives without sodium silicate as alkaline additive were developed in this project: One additive was the sodium carboxymethyl cellulose (CMC) as self-degradation promoting additive; the other was the hard-burned magnesium oxide (MgO) made from calcinating at 1,000-1,500 C as an expansive additive. The AASC and AASF cementitious sealers made by incorporating an appropriate amount of these additives met the following six criteria: 1) One dry mix component product; 2) plastic viscosity, 20 to 70 cp at 300 rpm; 3) maintenance of pumpability for at least 1 hour at 85 C; 4) compressive strength >2000 psi; 5) self-degradable by injection with water at a certain pressure; and 6) expandable and swelling properties; {ge}0.5% of total volume of the sealer.