Sample records for h2 hydrogen hungary

  1. H2 and You: The Hydrogen Education Foundation's Outreach Program...

    Energy Savers [EERE]

    H2 and You: The Hydrogen Education Foundation's Outreach Program (Presentation) H2 and You: The Hydrogen Education Foundation's Outreach Program (Presentation) The Hydrogen...

  2. H2A Hydrogen Delivery Infrastructure Analysis Models and Conventional...

    Energy Savers [EERE]

    H2A Hydrogen Delivery Infrastructure Analysis Models and Conventional Pathway Options Analysis Results - Interim Report H2A Hydrogen Delivery Infrastructure Analysis Models and...

  3. Upcoming H2USA Workshop: Hydrogen Fueling Station Component Listings...

    Office of Environmental Management (EM)

    H2USA Workshop: Hydrogen Fueling Station Component Listings Upcoming H2USA Workshop: Hydrogen Fueling Station Component Listings April 21, 2015 - 1:04pm Addthis H2USA will host an...

  4. Hydrogen (H2) Production by Anoxygenic Purple Nonsulfur Bacteria...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Anoxygenic Purple Nonsulfur Bacteria Hydrogen (H2) Production by Anoxygenic Purple Nonsulfur Bacteria Presentation by Jake McKinlay, Indiana University, at the Biological Hydrogen...

  5. Critical Updates to the Hydrogen Analysis Production Model (H2A...

    Broader source: Energy.gov (indexed) [DOE]

    Fuel Cell Technologies Program webinar, "Critical Updates to the Hydrogen Analysis Production Model (H2A v3)." Critical Updates to the Hydrogen Analysis Production Model (H2A v3)...

  6. H2A: Hydrogen Analysis Margaret K. Mann

    E-Print Network [OSTI]

    , Eastman Chemical, Entergy, Exxon Mobil, FERCO, GE, Praxair, Shell, Stuart Energy, Thermochem #12;H2A Skill

  7. H2FIRST Hydrogen Contaminant Detector Task: Requirements Document...

    Broader source: Energy.gov (indexed) [DOE]

    contamination detection and identifies the technical requirements for implementing a hydrogen contaminant detector (HCD) at a station. The rollout of hydrogen fueling stations,...

  8. Leak Detection and H2 Sensor Development for Hydrogen Applications

    SciTech Connect (OSTI)

    Brosha, Eric L. [Los Alamos National Laboratory

    2012-07-10T23:59:59.000Z

    The objectives of this report are: (1) Develop a low cost, low power, durable, and reliable hydrogen safety sensor for a wide range of vehicle and infrastructure applications; (2) Continually advance test prototypes guided by materials selection, sensor design, electrochemical R&D investigation, fabrication, and rigorous life testing; (3) Disseminate packaged sensor prototypes and control systems to DOE Laboratories and commercial parties interested in testing and fielding advanced prototypes for cross-validation; (4) Evaluate manufacturing approaches for commercialization; and (5) Engage an industrial partner and execute technology transfer. Recent developments in the search for sustainable and renewable energy coupled with the advancements in fuel cell powered vehicles (FCVs) have augmented the demand for hydrogen safety sensors. There are several sensor technologies that have been developed to detect hydrogen, including deployed systems to detect leaks in manned space systems and hydrogen safety sensors for laboratory and industrial usage. Among the several sensing methods electrochemical devices that utilize high temperature-based ceramic electrolytes are largely unaffected by changes in humidity and are more resilient to electrode or electrolyte poisoning. The desired sensing technique should meet a detection threshold of 1% (10,000 ppm) H{sub 2} and response time of {approx_equal}1 min, which is a target for infrastructure and vehicular uses. Further, a review of electrochemical hydrogen sensors by Korotcenkov et.al and the report by Glass et.al suggest the need for inexpensive, low power, and compact sensors with long-term stability, minimal cross-sensitivity, and fast response. This view has been largely validated and supported by the fuel cell and hydrogen infrastructure industries by the NREL/DOE Hydrogen Sensor Workshop held on June 8, 2011. Many of the issues preventing widespread adoption of best-available hydrogen sensing technologies available today outside of cost, derive from excessive false positives and false negatives arising from signal drift and unstable sensor baseline; both of these problems necessitate the need for unacceptable frequent calibration.

  9. H2FIRST: A partnership to advance hydrogen fueling station technology driving an optimal consumer experience.

    SciTech Connect (OSTI)

    Moen, Christopher D.; Dedrick, Daniel E.; Pratt, Joseph William; Balfour, Bruce; Noma, Edwin Yoichi; Somerday, Brian P.; San Marchi, Christopher W.; K. Wipke; J. Kurtz; D. Terlip; K. Harrison; S. Sprik

    2014-03-01T23:59:59.000Z

    The US Department of Energy (DOE) Energy Efficiency and Renewable Energy (EERE) Office of Fuel Cell Technologies Office (FCTO) is establishing the Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) partnership, led by the National Renewable Energy Laboratory (NREL) and Sandia National Laboratories (SNL). FCTO is establishing this partnership and the associated capabilities in support of H2USA, the public/private partnership launched in 2013. The H2FIRST partnership provides the research and technology acceleration support to enable the widespread deployment of hydrogen infrastructure for the robust fueling of light-duty fuel cell electric vehicles (FCEV). H2FIRST will focus on improving private-sector economics, safety, availability and reliability, and consumer confidence for hydrogen fueling. This whitepaper outlines the goals, scope, activities associated with the H2FIRST partnership.

  10. Analyzing the Levelized Cost of Centralized and Distributed Hydrogen Production Using the H2A Production Model, Version 2

    SciTech Connect (OSTI)

    Ramsden, T.; Steward, D.; Zuboy, J.

    2009-09-01T23:59:59.000Z

    Analysis of the levelized cost of producing hydrogen via different pathways using the National Renewable Energy Laboratory's H2A Hydrogen Production Model, Version 2.

  11. Webinar: Overview of the Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) Project

    Broader source: Energy.gov [DOE]

    Text version and video recording of the webinar titled "An Overview of the Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) Project," originally presented on November 18, 2014.

  12. Webinar: An Overview of the Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) Project

    Broader source: Energy.gov [DOE]

    The Energy Department will present a live webinar entitled "An Overview of the Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) Project" on Tuesday, November 18, from 12:00...

  13. H2 Hydrogen Hungary Ltd aka Integral Energy | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are8COaBulkTransmissionSitingProcess.pdfGetec AG| Open EnergyGuntersville ElectricControlon State - Land

  14. Hydrogen effects on materials for CNG/H2 blends.

    SciTech Connect (OSTI)

    Farese, David (Air Products, USA); Keller, Jay O.; Somerday, Brian P.

    2010-09-01T23:59:59.000Z

    No concerns for Hydrogen-Enriched Compressed Natural gas (HCNG) in steel storage tanks if material strength is < 950 MPa. Recommend evaluating H{sub 2}-assisted fatigue cracking in higher strength steels at H{sub 2} partial pressure in blend. Limited fatigue testing on higher strength steel cylinders in H{sub 2} shows promising results. Impurities in Compressed Natural Gas (CNG) (e.g., CO) may provide extrinsic mechanism for mitigating H{sub 2}-assisted fatigue cracking in steel tanks.

  15. Hydrogen Financial Analysis Scenario Tool (H2FAST)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh School footballHydrogen and Fuel CellFew-Layer Graphene |Vehicles

  16. H2 formation on PAHs in photodissociation regions: a high-temperature pathway to molecular hydrogen

    E-Print Network [OSTI]

    Boschman, Leon; Spaans, Marco; Hoekstra, Ronnie; Schlathölter, Thomas

    2015-01-01T23:59:59.000Z

    Molecular hydrogen is the most abundant molecule in the Universe. It is thought that a large portion of H2 forms by association of hydrogen atoms to polycyclic aromatic hydrocarbons (PAHs). We model the influence of PAHs on total H2 formation rates in photodissociation regions (PDRs) and assess the effect of these formation rates on the total cloud structure. We set up a chemical kinetic model at steady state in a PDR environment and included adiative transfer to calculate the chemistry at different depths in the PDR. This model includes known dust grain chemistry for the formation of H2 and a H2 formation mechanism on PAHs. Since H2 formation on PAHs is impeded by thermal barriers, this pathway is only efficient at higher temperatures (T > 200 K). At these temperatures the conventional route of H2 formation via H atoms physisorbed on dust grains is no longer feasible, so the PAH mechanism enlarges the region where H2 formation is possible. We find that PAHs have a significant influence on the structure of PD...

  17. Interested in Hydrogen and Fuel Cell Technologies? Help Shape the H2 Refuel H-Prize Competition

    Office of Energy Efficiency and Renewable Energy (EERE)

    Find out how you can help improve the H-Prize H2 Refuel competition, which involves designing a small-scale hydrogen refueler system for homes, community centers, or businesses.

  18. Webinar November 18: An Overview of the Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) Project

    Broader source: Energy.gov [DOE]

    The Energy Department will present a live webinar entitled "An Overview of the Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) Project" on Tuesday, November 18, from 12:00 to 1:00 Eastern Standard Time (EST).

  19. Distance-dependent radiation chemistry: Oxidation versus hydrogenation of CO in electron-irradiated H2O/CO/H2O ices

    SciTech Connect (OSTI)

    Petrik, Nikolay G.; Monckton, Rhiannon J.; Koehler, Sven; Kimmel, Gregory A.

    2014-11-26T23:59:59.000Z

    Electron-stimulated oxidation of CO in layered H2O/CO/H2O ices was investigated with infrared reflection-absorption spectroscopy (IRAS) as function of the distance of the CO layer from the water/vacuum interface. The results show that while both oxidation and reduction reactions occur within the irradiated water films, there are distinct regions where either oxidation or reduction reactions are dominant. At depths less than ~ 15 ML, CO oxidation dominates over the sequential hydrogenation of CO to methanol (CH3OH), and CO2 is the major product of CO oxidation, consistent with previous observations. At its highest yield, CO2 accounts for ~45% of all the reacted CO. Another oxidation product is identified as the formate anion (HCO2-). In contrast, for CO buried more than ~ 35 ML below the water/vacuum interface, the CO-to-methanol conversion efficiency is close to 100%. Production of CO2 and formate are not observed for the more deeply buried CO layers, where hydrogenation dominates. Experiments with CO dosed on pre-irradiated ASW samples suggest that OH radicals are primarily responsible for the oxidation reactions. Possible mechanisms of CO oxidation, involving primary and secondary processes of water radiolysis at low temperature, are discussed. The observed distance-dependent radiation chemistry results from the higher mobility of hydrogen atoms that are created by the interaction of the 100 eV electrons with the water films. These hydrogen atoms, which are primarily created at or near the water/vacuum interface, can desorb from or diffuse into the water films, while the less-mobile OH radicals remain in the near-surface zone resulting in preferential oxidation reactions there. The diffusing hydrogen atoms are responsible for the hydrogenation reactions that are dominant for the more deeply buried CO layers.

  20. Optimized Pathways for Regional H2 Infrastructure Transitions: The Least-Cost Hydrogen for Southern California

    E-Print Network [OSTI]

    Lin, Zhenhong; Chen, Chien-Wei; Fan, Yueyue; Ogden, Joan M.

    2008-01-01T23:59:59.000Z

    P. Rutter, et al. Hydrogen infrastructure strategic planningModelling of Hydrogen infrastructure for vehicle refuellingof building up a hydrogen infrastructure in Southern

  1. Analyzing Natural Gas Based Hydrogen Infrastructure - Optimizing Transitions from Distributed to Centralized H2 Production

    E-Print Network [OSTI]

    Yang, Christopher; Ogden, Joan M

    2005-01-01T23:59:59.000Z

    for building up hydrogen infrastructure that are guided byModeling Regional Hydrogen Infrastructure Development . inNATURAL GAS BASED HYDROGEN INFRASTRUCTURE – OPTIMIZING

  2. Electron-stimulated reactions in layered CO/H2O films: Hydrogen atom diffusion and the sequential hydrogenation of CO to methanol

    SciTech Connect (OSTI)

    Petrik, Nikolay G.; Monckton, Rhiannon J.; Koehler, Sven; Kimmel, Gregory A.

    2014-05-28T23:59:59.000Z

    Low-energy (100 eV) electron-stimulated reactions in layered H2O/CO/H2O ices are investigated. For CO trapped within approximately 50 ML of the vacuum interface in the amorphous solid water (ASW) films, both oxidation and reduction reactions are observed. However for CO buried more deeply in the film, only the reduction of CO to methanol is observed. Experiments with layered films of H2O and D2O show that the hydrogen atoms participating in the reduction of the buried CO originate in region from ~10 – 40 ML below the surface of the ASW films and subsequently diffuse through the film. For deeply buried CO layers, the CO reduction reactions quickly increase with temperature above ~60 K. We present a simple chemical kinetic model that treats the diffusion of hydrogen atoms in the ASW and sequential hydrogenation of the CO to methanol that accounts for the observations.

  3. Optimized Pathways for Regional H2 Infrastructure Transitions: The Least-Cost Hydrogen for Southern California

    E-Print Network [OSTI]

    Lin, Zhenhong; Chen, Chien-Wei; Fan, Yueyue; Ogden, Joan M.

    2008-01-01T23:59:59.000Z

    gasification, coal gasification, natural gas reforming, andgasification and then coal gasification with carbon captureproduction of H2 via coal gasification with CCS C-SMR, C-

  4. Optimized Pathways for Regional H2 Infrastructure Transitions: The Least-Cost Hydrogen for Southern California

    E-Print Network [OSTI]

    Lin, Zhenhong; Chen, Chien-Wei; Fan, Yueyue; Ogden, Joan M.

    2008-01-01T23:59:59.000Z

    Costs to Estimate Hydrogen Pipeline Costs. University ofPipeline network gradually expands and eventually takes over all hydrogenpipelines. These technologies compete with each other to meet an exogenously estimated hydrogen

  5. Technical Analysis of Hydrogen Production: Evaluation of H2 Mini-Grids

    SciTech Connect (OSTI)

    Lasher, Stephen; Sinha, Jayanti

    2005-05-03T23:59:59.000Z

    We have assessed the transportation of hydrogen as a metal hydride slurry through pipelines over a short distance from a neighborhood hydrogen production facility to local points of use. The assessment was conducted in the context of a hydrogen "mini-grid" serving both vehicle fueling and stationary fuel cell power systems for local building heat and power. The concept was compared to a compressed gaseous hydrogen mini-grid option and to a stand-alone hydrogen fueling station. Based on our analysis results we have concluded that the metal hydride slurry concept has potential to provide significant reductions in overall energy use compared to liquid or chemical hydride delivery, but only modest reductions in overall energy use, hydrogen cost, and GHG emissions compared to a compressed gaseous hydrogen delivery. However, given the inherent (and perceived) safety and reasonable cost/efficiency of the metal hydride slurry systems, additional research and analysis is warranted. The concept could potentially overcome the public acceptance barrier associated with the perceptions about hydrogen delivery (including liquid hydrogen tanker trucks and high-pressure gaseous hydrogen pipelines or tube trailers) and facilitate the development of a near-term hydrogen infrastructure.

  6. Improved Hydrogen Storage Performance of MgH2-LiAlH4 Composite by Addition of MnFe2O4

    E-Print Network [OSTI]

    Volinsky, Alex A.

    Improved Hydrogen Storage Performance of MgH2-LiAlH4 Composite by Addition of MnFe2O4 Qi Wan, Ping States *S Supporting Information ABSTRACT: The catalytic effects of MnFe2O4 nanoparticles on the hydrogen storage properties of MgH2-LiAlH4, prepared by ball milling, are studied for the first time. The hydrogen

  7. Final Technical Report: Hydrogen Energy in Engineering Education (H2E3)

    SciTech Connect (OSTI)

    Lehman, Peter A.; Cashman, Eileen; Lipman, Timothy; Engel, Richard A.

    2011-09-15T23:59:59.000Z

    Schatz Energy Research Center's Hydrogen Energy in Engineering Education curriculum development project delivered hydrogen energy and fuel cell learning experiences to over 1,000 undergraduate engineering students at five California universities, provided follow-on internships for students at a fuel cell company; and developed commercializable hydrogen teaching tools including a fuel cell test station and a fuel cell/electrolyzer experiment kit. Monitoring and evaluation tracked student learning and faculty and student opinions of the curriculum, showing that use of the curriculum did advance student comprehension of hydrogen fundamentals. The project web site (hydrogencurriculum.org) provides more information.

  8. IEA/H2/TR-02/001 Hydrogen from Biomass

    E-Print Network [OSTI]

    ............................................................................................ 7 Thermal/Steam/Partial Oxidation........................................................... 7................................................. 19 Hydrogen from Biomass-Derived Ethanol.................................................... 21 and Carbon......................................................... 25 Reforming of Methane (and Natural Gas

  9. Hydrogen Production Analysis Using the H2A v3 Model (Text Version...

    Broader source: Energy.gov (indexed) [DOE]

    25 years of professional experience working on high technology projects and alternative energy analysis. Particular specialties include fuel cell power systems, hydrogen reformer...

  10. Formation of Calcium Phosphate Whiskers in Hydrogen Peroxide (H2O2) Solutions at 901C

    E-Print Network [OSTI]

    Tas, A. Cuneyt

    )2) powders were aged in unstirred 30% H2O2 solutions at 901C for 48 h in ordinary glass media bottlesH, Buchs, Switzerland) were placed in a 250 mL capacity Pyrex s glass media bottle (Catalog No: 215 into the bottle. The bottle was tight- ly capped and manually shaken for 1 min, followed by keeping the bottle

  11. US DOE Hydrogen and Fuel Cell Technology - Composites in H2 Storage...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PhD Representing: U.S. Department of Energy Fuel Cell Technologies Office 4 Hydrogen and Fuel Cells Program Overview Mission: Enable widespread commercialization of a portfolio of...

  12. H2L3: Hydrogen Learning for Local Leaders | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGrid Integration0-1 MarchH-TankModelsMarketL3: Hydrogen

  13. Hydrogen Transition Sensitivity Studies using H2Sim | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGridHYDROGEND D eReview |Panel HydrogenM MTankSensitivity

  14. H2 ICE Combustion | Argonne National Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    H2 ICE Combustion Share Description Hydrogen combustion inside a direct injection H2 engine Topic Energy Energy efficiency Vehicles Hydrogen & fuel cells Credit S. Ciatti This...

  15. Economic Analysis of Hydrogen Energy Station Concepts: Are "H 2E-Stations" a Key Link to a Hydrogen Fuel Cell Vehicle Infrastructure?

    E-Print Network [OSTI]

    Lipman, Timothy E.; Edwards, Jennifer L.; Kammen, Daniel M.

    2002-01-01T23:59:59.000Z

    Ideally a robust hydrogen infrastructure would rapidlya serviceable hydrogen infrastructure that is extensiveadding hydrogen dispensing infrastructure to a gasoline

  16. Two-dimensional protonic diffusion in a hydrogen-bonded compound CsOH . H2O, studied by solid state NMR

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    949 Two-dimensional protonic diffusion in a hydrogen-bonded compound CsOH . H2O, studied by solid césium hydroxide monohydrate CsH3O2 polycristallin révèle une diffusion protonique rapide dans ses phases hautes températures. Par mesure directe, la constante de diffusion est trouvée D = 1.2 10-5 exp(-1700/T

  17. Economic Analysis of Hydrogen Energy Station Concepts: Are "H 2E-Stations" a Key Link to a Hydrogen Fuel Cell Vehicle Infrastructure?

    E-Print Network [OSTI]

    Lipman, Timothy E.; Edwards, Jennifer L.; Kammen, Daniel M.

    2002-01-01T23:59:59.000Z

    in the analysis of hydrogen energy stations, additionalattractiveness of the hydrogen energy station scheme in bothECONOMIC ANALYSIS OF HYDROGEN ENERGY STATION CONCEPTS: ARE '

  18. Insight into methanol synthesis from CO2 hydrogenation on Cu(111): Complex reaction network and the effects of H2O

    SciTech Connect (OSTI)

    Zhao, Yafan; Yang, Yong; Mims, Charles A.; Peden, Charles HF; Li, Jun; Mei, Donghai

    2011-05-31T23:59:59.000Z

    Methanol synthesis from CO2 hydrogenation on supported Cu catalysts is of considerable importance in the chemical and energy industries. Although extensive experimental and theoretical efforts have been carried out in the past decades, the most fundamental questions such as the reaction mechanisms and the key reaction intermediates are still in debate. In the present work, a comprehensive reaction network for CO2 hydrogenation to methanol on Cu(111) was studied using periodic density functional theory (DFT) calculations. All of the elementary reaction steps in the reaction network were identified in an unbiased way with the dimer method. Our calculation results show that methanol synthesis from direct hydrogenation of formate on Cu(111) is not feasible due to the high activation barriers for some of the elementary steps. Instead, we find that CO2 hydrogenation to hydrocarboxyl (trans-COOH) is kinetically more favorable than formate in the presence of H2O via a unique proton transfer mechanism. The trans-COOH is then converted into hydroxymethylidyne (COH) via dihydroxycarbene (COHOH) intermediates, followed by three consecutive hydrogenation steps to form hydroxymethylene (HCOH), hydroxymethyl (H2COH), and methanol. This is consistent with recent experimental observations [1], which indicate that direct hydrogenation of formate will not produce methanol under dry hydrogen conditions. Thus, both experiment and computational modeling clearly demonstrate the important role of trace amounts of water in methanol synthesis from CO2 hydrogenation on Cu catalysts. The proposed methanol synthesis route on Cu(111) not only provides new insights into methanol synthesis chemistry, but also demonstrates again that spectroscopically observed surface species are often not critical reaction intermediates but rather spectator species. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  19. H2 Educate Teacher Guide

    Broader source: Energy.gov [DOE]

    This H2 Educate Teacher Guide provides information about hydrogen energy and was developed by the National Energy Education Development (NEED) Project for the U.S. Department of Energy's Hydrogen Program.

  20. Detection of a vibration-rotation emission line of hydrogen deuteride toward Orion Peak 1 excitation coupling of HD to H_2

    E-Print Network [OSTI]

    Howat, S K R; Geballe, T R; Bertoldi, F; Mountain, C M

    2002-01-01T23:59:59.000Z

    The 2.46um v=1-0 R(5) line of deuterated molecular hydrogen, HD, has been detected in the Orion Peak~1 shock emission region, at a surface brightness of (8.5 +/- 2.1) x 10^(-9) W m^(-2)sr^(-1) over a 6 arcsec^2 area. Comparison of the column density of HD(v=1,J=6) with the column density of HD(v=0,J=6) previously observed from ISO and the H_2 level column densities toward the same region implies that the excitation of HD is similar to that of H_2 for these energy levels, despite much higher spontaneous transition rates for HD. We suggest that this rough equality is caused by the coupling of the HD levels to those of H_2, due to strong reactive collisions, HD + H -> H_2 + D, in warm, partially dissociated gas. The deuterium abundance implied by the combined ISO and UKIRT measurements toward Orion Peak 1 is [D]/[H] = (5.1 +/- 1.9)x10^(-6).

  1. Detection of a vibration-rotation emission line of hydrogen deuteride toward Orion Peak 1: excitation coupling of HD to H_2

    E-Print Network [OSTI]

    S. K Ramsay Howat; R. Timmermann; T. R. Geballe; F. Bertoldi; C. M. Mountain

    2001-10-25T23:59:59.000Z

    The 2.46um v=1-0 R(5) line of deuterated molecular hydrogen, HD, has been detected in the Orion Peak~1 shock emission region, at a surface brightness of (8.5 +/- 2.1) x 10^(-9) W m^(-2)sr^(-1) over a 6 arcsec^2 area. Comparison of the column density of HD(v=1,J=6) with the column density of HD(v=0,J=6) previously observed from ISO and the H_2 level column densities toward the same region implies that the excitation of HD is similar to that of H_2 for these energy levels, despite much higher spontaneous transition rates for HD. We suggest that this rough equality is caused by the coupling of the HD levels to those of H_2, due to strong reactive collisions, HD + H -> H_2 + D, in warm, partially dissociated gas. The deuterium abundance implied by the combined ISO and UKIRT measurements toward Orion Peak 1 is [D]/[H] = (5.1 +/- 1.9)x10^(-6).

  2. H2 Educate! Student Guide

    Fuel Cell Technologies Publication and Product Library (EERE)

    H2 Educate! Teacher and Student Guides - These new guides were developed by the National Energy Education Development (NEED) Project's Teacher Advisory Board for the DOE Hydrogen Program. Sentech, Inc

  3. H2 Educate! Teacher Guide

    Fuel Cell Technologies Publication and Product Library (EERE)

    H2 Educate! Teacher and Student Guides - These new guides were developed by the National Energy Education Development (NEED) Project's Teacher Advisory Board for the DOE Hydrogen Program. Sentech, Inc

  4. H2A Delivery: Forecourt Compression & Storage Optimization (Part...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    H2A Delivery: H2A Delivery: Forecourt Compression & Forecourt Compression & Storage Optimization (Part II) Storage Optimization (Part II) Hydrogen Delivery Analysis Meeting May...

  5. Sandia National Laboratories: H2FAST

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and the National Renewable Energy Laboratory (NREL) announce the publication of two new Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) reports on...

  6. Sandia National Laboratories: H2USA

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and the National Renewable Energy Laboratory (NREL) announce the publication of two new Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) reports on...

  7. Country profile: Hungary

    SciTech Connect (OSTI)

    Not Available

    1991-09-01T23:59:59.000Z

    Country Profile: Hungary has been prepared as a background document for use by US Government agencies and US businesses interested in becoming involved with the new democracies of Eastern Europe as they pursue sustainable economic development. The focus of the Profile is on energy and highlights information on Hungary`s energy supply, demand, and utilization. It identifies patterns of energy usage in the important economic sectors, especially industry, and provides a preliminary assessment for opportunities to improve efficiencies in energy production, distribution and use by introducing more efficient technologies. The use of more efficient technologies would have the added benefit of reducing the environmental impact which, although is not the focus of the report, is an issue that effects energy choices. The Profile also presents considerable economic information, primarily in the context of how economic restructuring may affect energy supply, demand, and the introduction of more efficient technologies.

  8. A Crossed Beam and ab Initio Investigation of the Reaction of Hydrogen Sulfide, H2S(X1A1), with Dicarbon Molecules, C2(X1g

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    alternative pathways, the elimination of atomic and molecular hydrogen from a thioketene (H2CCS) intermediate, to synthesize HCCS and CCS are also discussed. 1. Introduction Investigating the formation of sulfur bearing molecules.11 However. despite the potential key role of HCnS isomers to understand the organosulfur

  9. Country profile: Hungary

    SciTech Connect (OSTI)

    Not Available

    1991-09-01T23:59:59.000Z

    Country Profile: Hungary has been prepared as a background document for use by US Government agencies and US businesses interested in becoming involved with the new democracies of Eastern Europe as they pursue sustainable economic development. The focus of the Profile is on energy and highlights information on Hungary's energy supply, demand, and utilization. It identifies patterns of energy usage in the important economic sectors, especially industry, and provides a preliminary assessment for opportunities to improve efficiencies in energy production, distribution and use by introducing more efficient technologies. The use of more efficient technologies would have the added benefit of reducing the environmental impact which, although is not the focus of the report, is an issue that effects energy choices. The Profile also presents considerable economic information, primarily in the context of how economic restructuring may affect energy supply, demand, and the introduction of more efficient technologies.

  10. DOE Hydrogen Program Overview

    Broader source: Energy.gov (indexed) [DOE]

    Hydrogen Program A Prospectus for Biological H 2 Production The Hydrogen Economy The hydrogen economy pertains to a world fundamentally different from the one we now know. Hydrogen...

  11. www.praxair.com H2 Storage and

    E-Print Network [OSTI]

    to Pipeline) First industry-financed liquid hydrogen facility (1959) Six large LH2 plants designed- R0.ppt H2 Fueling Station Agenda Praxair Hydrogen Program Structure Program Overview Program H2 Fueling Station Praxair Hydrogen Only Hydrogen Supplier in All Sizes (Cylinders to Liquid

  12. Hydrogen Analysis

    Broader source: Energy.gov (indexed) [DOE]

    A H2A: Hydrogen Analysis Margaret K. Mann DOE Hydrogen, Fuel Cells, and Infrastructure Technologies Program Systems Analysis Workshop July 28-29, 2004 Washington, D.C. H2A Charter...

  13. Energy ForesightNordic H2 Building the Nordic Research

    E-Print Network [OSTI]

    H2 Energy ForesightNordic H2 Building the Nordic Research and Innovation Area in Hydrogen Summary Report January 2005 #12;#12;Energy ForesightNordic H2 Building the Nordic Research and Innovation Area Region 7 Competitiveness of Nordic Countries 7 Research and Development in New Energy Technologies 8

  14. Development of a Turnkey H2 Fueling

    E-Print Network [OSTI]

    fuel equivalent to gasoline prices · Completed, on-schedule. Phase 3: System Deployment · Scale-up of a stand-alone, fully integrated H2 Fueling Station based on reforming of natural gas To build technologies for small scale reforming applications used in hydrogen fueling stations SMR's tend to have lower

  15. Hydrogen | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Sources Hydrogen Hydrogen September 30, 2014 Developed by Sandia National Laboratories and several industry partners, the fuel cell mobile light (H2LT) offers a cleaner, quieter...

  16. A Reversible Structural Interconversion Involving [M(H2pdc)2(H2O)2] 2H2O (M Mn, Fe, Co, Ni, Zn, H3pdc 3,5-pyrazoledicarboxylic acid) and the Role

    E-Print Network [OSTI]

    Li, Jing

    A Reversible Structural Interconversion Involving [M(H2pdc)2(H2O)2] ´ 2H2O (M Mn, Fe, Co, Ni, Zn, H3pdc 3,5-pyrazoledicarboxylic acid) and the Role of A Reactive Intermediate [Co(H2pdc)2] Long Pan, Nancy Ching, Xiaoying Huang, and Jing Li*[a] Abstract: A new type of hydrogen bonded networks [M(H2pdc)2

  17. H2A Delivery Scenario Model and Analyses

    Broader source: Energy.gov (indexed) [DOE]

    H2A Delivery Scenario Model and Analyses Marianne Mintz and Jerry Gillette DOE Hydrogen Delivery Analysis and High Pressure Tanks R&D Project Review Meeting February 8, 2005 2...

  18. Overview of NEMS-H2, Version 1.0

    Broader source: Energy.gov [DOE]

    Presentation on Overview of NEMS-H2, Version 1.0 given by Frances Wood of OnLocation during the DOE Hydrogen Transition Analysis Workshop on January 26, 2006.

  19. H2 R&D Activities in the Nordic Countries

    E-Print Network [OSTI]

    R&D Activities in the Nordic Countries Department: Department of Systems Analysis, Risø National is given on the R&D projects at national, EU and Nordic levels. Risø National Laboratory Information National Research in Hydrogen and Fuel Cells 6 3.1 Danish H2 Energy R&D 6 3.2 Finnish H2 related R&D 7 3

  20. State-to-state rotational transitions in H$_2$+H$_2$ collisions at low temperatures

    E-Print Network [OSTI]

    Teck-Ghee Lee; N. Balakrishnan; R. C. Forrey; P. C. Stancil; D. R. Schultz; Gary J. Ferland

    2006-07-18T23:59:59.000Z

    We present quantum mechanical close-coupling calculations of collisions between two hydrogen molecules over a wide range of energies, extending from the ultracold limit to the super-thermal region. The two most recently published potential energy surfaces for the H$_2$-H$_2$ complex, the so-called DJ (Diep and Johnson, 2000) and BMKP (Boothroyd et al., 2002) surfaces, are quantitatively evaluated and compared through the investigation of rotational transitions in H$_2$+H$_2$ collisions within rigid rotor approximation. The BMKP surface is expected to be an improvement, approaching chemical accuracy, over all conformations of the potential energy surface compared to previous calculations of H$_2$-H$_2$ interaction. We found significant differences in rotational excitation/de-excitation cross sections computed on the two surfaces in collisions between two para-H$_2$ molecules. The discrepancy persists over a large range of energies from the ultracold regime to thermal energies and occurs for several low-lying initial rotational levels. Good agreement is found with experiment (Mat\\'e et al., 2005) for the lowest rotational excitation process, but only with the use of the DJ potential. Rate coefficients computed with the BMKP potential are an order of magnitude smaller.

  1. Hydrogen Production & Delivery | Department of Energy

    Energy Savers [EERE]

    Hydrogen Production & Delivery Hydrogen Production & Delivery "2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation H2...

  2. 2nd International Hydrogen Infrastructure Challenges Webinar

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    issues facing hydrogen infrastructure fuel cell electric vehicles in the U.S. Europe, Germany, Scandinavia, and Japan. o H2 Fueling o H2 Quality o H2 metering o H2 Station...

  3. Hydrogen Delivery Technologies and Pipeline Transmission of Hydrogen

    E-Print Network [OSTI]

    Hydrogen Delivery Technologies and Systems Pipeline Transmission of Hydrogen Strategic Initiatives, and Infrastructure Technologies Program #12;Pipeline Transmission of Hydrogen --- 2 Copyright: Design & Operation development) #12;Pipeline Transmission of Hydrogen --- 3 Copyright: Future H2 Infrastructure Wind Powered

  4. Author's personal copy Coexisting silicate melt inclusions and H2O-bearing, CO2-rich fluid inclusions in mantle

    E-Print Network [OSTI]

    Bodnar, Robert J.

    Author's personal copy Coexisting silicate melt inclusions and H2O-bearing, CO2-rich fluid­Pannonian region Hungary C­O­H­S fluid inclusions Peridotite xenoliths Silicate melt inclusions Volatile (fluid)­silicate melt immiscibility Coexisting fluid inclusions and silicate melt inclusions, trapped as primary

  5. H2A Delivery: H2A Delivery

    E-Print Network [OSTI]

    forecourt Number of dispensers Capacity of hydrogen storage Size of hydrogen compressor or pump Optimize (Part II) Storage Optimization (Part II) Hydrogen Delivery Analysis Meeting May 8-9, 2007 Columbia. 408-517-1550 Reference: D0348 © 2007 TIAX LLC #12;Objectives Define the attributes of a hydrogen

  6. Sandia National Laboratories: Hydrogen Infrastructure

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Infrastructure Widespread Hydrogen Fueling Infrastructure Is the Goal of H2FIRST Project On June 4, 2014, in Capabilities, Center for Infrastructure Research and...

  7. Solid-State Hydriding Mechanism in the LiBH4 + MgH2 System. ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The LiBH4+MgH2 system has great potential in reversible hydrogen storage for fuel cell vehicles. However, it has always been dehydrogenated and re-hydrogenated in the liquid...

  8. Improvements to Hydrogen Delivery Scenario Analysis

    E-Print Network [OSTI]

    Improvements to Hydrogen Delivery Scenario Analysis Model (HDSAM) and Results May 8, 2007 Amgad and storage are at or adjacent to Liquid Hydrogen (LH) TruckH2 Production 100 or 1500 kg/d Compressed H2 (CH) Truck H2 Production 3 or 7 kpsi 100 or 1500 kg/d H2 Production Gaseous H2 Pipeline 100 or 1500 kg

  9. Selective and Rapid Room Temperature Detection of H2S Using Gold Nanoparticle Chain Arrays

    E-Print Network [OSTI]

    Chen, Wilfred

    Selective and Rapid Room Temperature Detection of H2S Using Gold Nanoparticle Chain Arrays Joun Lee conductometric hydrogen sulfide (H2S) sensor was fabricated by AC dielectrophoretic assembly of amino acid-ppm level, the upper detection limit of 2 ppm, and a response time ofH2S was achieved

  10. ITM Syngas and ITM H2: Engineering Development of Ceramic Membrane Reactor Systems for

    E-Print Network [OSTI]

    ITM Syngas and ITM H2: Engineering Development of Ceramic Membrane Reactor Systems for Converting (U.S. DOE) and other members of the ITM Syngas/ITM H2 Team, is developing Ion Transport Membrane (ITM-scale centralized hydrogen production facilities with CO2 capture. The major goals of the ITM Syngas and ITM H2

  11. Hydrogen Storage Properties of New Hydrogen-Rich BH3NH3-Metal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Storage Properties of New Hydrogen-Rich BH3NH3-Metal Hydride (TiH2, ZrH2, MgH2, andor CaH2) Composite Systems. Hydrogen Storage Properties of New Hydrogen-Rich BH3NH3-Metal...

  12. H2A Delivery: H2A Delivery

    E-Print Network [OSTI]

    and surroundings 5/8/2007 3 #12;Setback Distances Setback distances specified by NFPA 55 Compressed Hydrogen: 75ft. Public Way: 50 ft. Lot Line: 50 ft. The large setback distances associated with LH2 have

  13. Hydrogen Fueling Infrastructure Research and Station Technology...

    Broader source: Energy.gov (indexed) [DOE]

    An Overview of the Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) Project" held on November 18, 2014. Hydrogen Fueling Infrastructure Research and...

  14. OEM Perspective on Cryogenic H2 Storage

    Broader source: Energy.gov (indexed) [DOE]

    to upcoming infrastructure standard V12 PFI engine Power density Dynamics Durability & cost Efficiency H 2 Drive train H 2 -Storage...

  15. Inexpensive delivery of compressed hydrogen with advanced vessel technology

    E-Print Network [OSTI]

    of flexible refueling (compressed/cryogenic H2/(L)H2) #12;The PVT properties of H2 drive storage and delivery) Explore station demand from 70 kg H2/day to 1000 kg H2/day · Real hydrogen thermodynamic and PVT diagram and vessel characteristics to minimize delivery cost · Hydrogen and material properties Increased

  16. H2A Production Model, Version 2 User Guide

    SciTech Connect (OSTI)

    Steward, D.; Ramsden, T.; Zuboy, J.

    2008-09-01T23:59:59.000Z

    The H2A Production Model analyzes the technical and economic aspects of central and forecourt hydrogen production technologies. Using a standard discounted cash flow rate of return methodology, it determines the minimum hydrogen selling price, including a specified after-tax internal rate of return from the production technology. Users have the option of accepting default technology input values--such as capital costs, operating costs, and capacity factor--from established H2A production technology cases or entering custom values. Users can also modify the model's financial inputs. This new version of the H2A Production Model features enhanced usability and functionality. Input fields are consolidated and simplified. New capabilities include performing sensitivity analyses and scaling analyses to various plant sizes. This User Guide helps users already familiar with the basic tenets of H2A hydrogen production cost analysis get started using the new version of the model. It introduces the basic elements of the model then describes the function and use of each of its worksheets.

  17. Hydrogen Delivery Analysis Amgad Elgowainy (ANL), Marianne Mintz

    E-Print Network [OSTI]

    Hydrogen Truck Liquid Hydrogen Truck Terminal H2 Transmission Compressor H2 Forecourt Compressor HydrogenHydrogen Delivery Analysis Models Amgad Elgowainy (ANL), Marianne Mintz (ANL), Jerry Gillette (ANL Components Compressed Hydrogen Gas Truck (Tube trailer) Compressed Hydrogen Gas Truck Terminal Liquid

  18. Understanding dopant and defect effect on H2S sensing performances of graphene: A first-principles study

    E-Print Network [OSTI]

    Guo, John Zhanhu

    Understanding dopant and defect effect on H2S sensing performances of graphene: A first November 2012 Accepted 29 November 2012 Keywords: Graphene H2S Sensor Electron transport a b s t r a c t The interaction between hydrogen sulfite (H2S) and graphene was investigated by density functional the- ory

  19. Hydrogen Supply: Cost Estimate for Hydrogen Pathways?Scoping...

    Broader source: Energy.gov (indexed) [DOE]

    Central Methanol Methanol Forecourt Gasoline Gasoline Forecourt H 2 from ethylene or refinery Residuepitch Central The by-product source of hydrogen defined by IHIG in the...

  20. A ATM I Materials Lifecycle Solutions Micro-Machined Thin Film H2 Gas Sensors

    E-Print Network [OSTI]

    of better components for existing delivery systems, including hydrogen sensors... · Storage ­ Emerging of this technology for life safety and processing monitoring · Approach ­ MEMS based platform coupled with multilayer seconds off 0.25% H2 in dry air On Off 100 80 60 40 20 0 Resistance(ohms) 304302300298296 Time (s) H2 on t

  1. ECONOMIC FEASIBILITY ANALYSIS OF HYDROGEN PRODUCTION BY

    E-Print Network [OSTI]

    steps (syngas generation, shift conversion and hydrogen purification) necessary for hydrogen production for this process option. O2 H2 air N.G. + Steam Hydrogen H2-depleted syngas OTM Reactor HTM Reactor syngas Figure 1- gas. A portion of natural gas also reacts with steam to form syngas. Additional hydrogen is formed

  2. Hydrogen Permeation Barrier Coatings

    SciTech Connect (OSTI)

    Henager, Charles H.

    2008-01-01T23:59:59.000Z

    Gaseous hydrogen, H2, has many physical properties that allow it to move rapidly into and through materials, which causes problems in keeping hydrogen from materials that are sensitive to hydrogen-induced degradation. Hydrogen molecules are the smallest diatomic molecules, with a molecular radius of about 37 x 10-12 m and the hydrogen atom is smaller still. Since it is small and light it is easily transported within materials by diffusion processes. The process of hydrogen entering and transporting through a materials is generally known as permeation and this section reviews the development of hydrogen permeation barriers and barrier coatings for the upcoming hydrogen economy.

  3. AOI [3] High-Temperature Nano-Derived Micro-H2 and - H2S Sensors

    SciTech Connect (OSTI)

    Perepezko, John; Lu-Steffes, Otto

    2014-08-31T23:59:59.000Z

    The emissions from coal-fired power plants remain a significant concern for air quality. This environmental challenge must be overcome by controlling the emission of sulfur dioxide (SO2) and hydrogen sulfide (H2S) throughout the entire coal combustion process. One of the processes which could specifically benefit from robust, low cost, and high temperature compatible gas sensors is the coal gasification process which converts coal and/or biomass into syngas. Hydrogen (H2), carbon monoxide (CO) and sulfur compounds make up 33%, 43% and 2% of syngas, respectively. Therefore, development of a high temperature (>500°C) chemical sensor for in-situ monitoring of H2, H2S and SO2 levels during coal gasification is strongly desired. The selective detection of SO2/H2S in the presence of H2, is a formidable task for a sensor designer. In order to ensure effective operation of these chemical sensors, the sensor system must inexpensively function within harsh temperature and chemical environment. Currently available sensing approaches, which are based on gas chromatography, electrochemistry, and IR-spectroscopy, do not satisfy the required cost and performance targets. This work focused on the development microsensors that can be applied to this application. In order to develop the high- temperature compatible microsensor, this work addressed various issues related to sensor stability, selectivity, and miniaturization. In the research project entitled “High-Temperature Nano-Derived Micro-H2 and -H2S Sensors”, the team worked to develop micro-scale, chemical sensors and sensor arrays composed of nano-derived, metal-oxide composite materials to detect gases like H2, SO2, and H2S within high-temperature environments (>500?C). The research was completed in collaboration with NexTech Materials, Ltd. (Lewis Center, Ohio). NexTech assisted in the testing of the sensors in syngas with contaminate levels of H2S. The idea of including nanomaterials as the sensing material within resistive-type chemical sensor platforms was to increase the sensitivity (as shown for room temperature applications). Unfortunately, nanomaterials are not stable at high temperatures due to sintering and coarsening processes that are driven by their high surface to volume ratio. Therefore, new hydrogen and sulfur selective nanomaterial systems with high selectivity and stability properties in the proposed harsh environment were investigated. Different nano-morphologies of zirconate, molybdate, and tungstate compounds were investigated. The fabrication of the microsensors consisted of the deposition of the selective nanomaterial systems over metal based interconnects on an inert substrate. This work utilized the chemi-resistive (resistive- type) microsensor architecture where the chemically and structurally stable, high temperature compatible electrodes were sputtered onto a ceramic substrate. The nanomaterial sensing systems were deposited over the electrodes using a lost mold method patterned by conventional optical lithography. The microsensor configuration with optimized nanomaterial system was tested and compared to a millimeter-size sensor e outcomes of this research will contribute to the economical application of sensor arrays for simultaneous sensing of H2, H2S, and SO2.

  4. Hydrogen Delivery Options and Issues

    Broader source: Energy.gov (indexed) [DOE]

    stationary power site - GH2 Pipelines and Trucks, LH2 Trucks, Carriers <1.00kg of Hydrogen by 2017 Hydrogen Delivery H2 Delivery Current Status * Technology - GH2 Tube...

  5. WASTE/BY-PRODUCT HYDROGEN DOE/DOD Workshop

    E-Print Network [OSTI]

    ; 6 Waste/Byproduct HydrogenWaste/By product Hydrogen Waste H2 sources include: Waste biomass: biogas Waste/Byproduct Hydrogen Waste/By product Hydrogen Fuel FlexibilityFuel Flexibility Biogas: generated

  6. Improvements to Hydrogen Delivery Scenario Analysis Model (HDSAM...

    Broader source: Energy.gov (indexed) [DOE]

    for 3 pathways with single mode. conditioning and storage are at or adjacent to Liquid Hydrogen (LH) Truck H2 Production 100 or 1500 kgd Compressed H2 (CH) Truck H2 Production...

  7. Overview of NEMS-H2, Version 1.0 Frances Wood

    E-Print Network [OSTI]

    ConsumptionForm/Place Transformations Electricity Generation and Transmission Hydrogen Oil and Gas ProductionOverview of NEMS-H2, Version 1.0 Frances Wood OnLocation, Inc., Energy Systems Consulting (fwood markets ­ Focus is on economic, not engineering, aspects of hydrogen production, delivery, and consumption

  8. Author's personal copy Maximizing the solar to H2 energy conversion efficiency

    E-Print Network [OSTI]

    Pilon, Laurent

    to thermochemical or electrolytic hydrogen production technologies [1­3]. However, solar to hydrogen energyAuthor's personal copy Maximizing the solar to H2 energy conversion efficiency of outdoor, Cockrell School of Engineering, The University of Texas at Austin ­ Austin, TX 78712, USA b Mechanical

  9. Interested in Hydrogen and Fuel Cell Technologies? Help Shape...

    Broader source: Energy.gov (indexed) [DOE]

    Interested in Hydrogen and Fuel Cell Technologies? Help Shape the H2 Refuel H-Prize Competition Interested in Hydrogen and Fuel Cell Technologies? Help Shape the H2 Refuel H-Prize...

  10. Webinar November 18: An Overview of the Hydrogen Fueling Infrastructur...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    18: An Overview of the Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) Project Webinar November 18: An Overview of the Hydrogen Fueling Infrastructure...

  11. Overview hazard analysis for the H2Fuel Bus Program

    SciTech Connect (OSTI)

    Hovis, G.L.

    1996-06-18T23:59:59.000Z

    The H2Fuel Bus project is a joint development effort to produce a safe, near-zero emission, 32 passenger bus that is propelled by electric power with continuous on-board hydrogen powered battery recharging. A key initiative in the hydrogen bus development effort is a rigorous evaluation of operational safety. Westinghouse Savannah River Co., the prime contractor at the Department of Energy`s Savannah River Site, has developed a hazard analysis methodology designed to provide a systematic, comprehensive identification and evaluation of hazards. Although originally developed to support nuclear/chemical facility safety basis documentation, the SRS Methodology has widespread applicability to operations and/or systems that utilize hazardous materials and energy. This methodology was used to perform an overview hazard analysis for the H2Fuel Bus project to focus attention on those hypothetical circumstances that pose the greatest threat to the populace and property. The hazard analysis yields a listing of all known H2Fuel Bus hazards, postulated accident scenarios describing possible hazardous releases or conditions, an assessment of the scenarios in terms of frequency of occurrence and consequence, and binning in frequency-consequence space to assess the relative severity of postulated scenarios.

  12. NASA Perspectives on Cryo H2 DOE Hydrogen Storage Workshop

    E-Print Network [OSTI]

    -space, MMOD protection) -Vapor/cryocooler cooled shields - Sun shades - Low conductivity/ cooled support propellant - Inventory (Bookkeeping) - Pressure-volume-temperature (PVT) - High accuracy low-g techniques;7 NASA Cryogenic Technology Objectives · To develop storage and distribution technologies for cryogens

  13. H2FIRST Hydrogen Contaminant Detector Task: Requirements Document...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ainscough, William Buttner National Renewable Energy Laboratory Scott McWhorter Savannah River National Laboratory NREL is a national laboratory of the U.S. Department of Energy,...

  14. H2 and You: The Hydrogen Education Foundation's Outreach Program

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742Energy ChinaofSchaefer To: CongestionDevelopment ofofthePerformanceof

  15. H2A Hydrogen Delivery Infrastructure Analysis Models and Conventional

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742Energy ChinaofSchaefer To: CongestionDevelopment ofofthePerformanceofPathway Options Analysis

  16. H2FIRST: Hydrogen Fueling Infrastructure Research and Station Technology |

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742Energy ChinaofSchaefer To: CongestionDevelopment ofofthePerformanceofPathway Options

  17. H2USA Accomplishments Push Hydrogen Infrastructure Forward | Department of

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742Energy ChinaofSchaefer To: CongestionDevelopment ofofthePerformanceofPathway OptionsEnergy A

  18. H2USA Accomplishments Push Hydrogen Infrastructure Forward | Department of

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed off Energy.gov.Energy02.pdf7 OPAM Flash2011-37 OPAMResource Guideand Contractors |andEnergy

  19. Hydrogen Analysis (H2A) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are8COaBulkTransmissionSitingProcess.pdfGetecGtel JumpCounty, Texas: EnergyHy9 CorporationHydraA) Jump to: navigation,

  20. H2FIRST Hydrogen Contaminant Detector Task: Requirements Document and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreaking of Blythe Solar Power Project Groundof|than Ever | Department

  1. H2FIRST: Hydrogen Fueling Infrastructure Research and Station Technology |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreaking of Blythe Solar Power Project Groundof|than Ever | Departmentof

  2. Hydrogen Analysis (H2A) Production Component Model

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreaking of Blythe Solar PowerCommercialEnergySandy-Nor'easterHybrid

  3. Material Testing Priorities for Hydrogen (H2) Infrastructure | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(FactDepartment3311, 3312), October 20122 DOE Hydrogenis Winding6 *of Energy

  4. Upcoming H2USA Workshop: Hydrogen Fueling Station Component Listings |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your DensityEnergy U.S.-China Electric Vehicle and03/02 TUE 08:59 FAX 423 241 3897ExtendingImpact

  5. H2 and You: The Hydrogen Education Foundation's Outreach Program

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGrid Integration0-1 MarchH-Tank FarmRefuel(Presentation) |

  6. H2FIRST Hydrogen Contaminant Detector Task: Requirements Document and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGrid Integration0-1 MarchH-TankModelsMarket Survey |

  7. Hydrogen (H2) Production by Anoxygenic Purple Nonsulfur Bacteria |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGridHYDROGEND D e e& Fuel Cells Program& Our

  8. Hydrogen (H2) Production by Oxygenic Phototrophs | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGridHYDROGEND D e e& Fuel Cells Program&

  9. H2 Internal Combustion Engine Research

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    H 2 Internal Combustion Engine Research* H Internal Combustion Engine Research 2 Thomas Wallner Argonne National Laboratory 2008 DOE Merit Review Bethesda, Maryland February 25 th...

  10. Hydrogen for X-group exchange in CH3X, X = Cl, Br, I, OMe and NMe2 by Monomeric [1,2,4-(Me3C)3C5H2]2CeH: Experimental and Computational Support for a Carbenoid Mechanism

    E-Print Network [OSTI]

    Werkema, Evan

    2010-01-01T23:59:59.000Z

    Hydrogen for X-group exchange in CH 3 X, X = Cl, Br, I, OMespectrum in which a single hydrogen atom is statisticallyprobability ellipsoids. The non-hydrogen atoms are refined

  11. CATALYST CATALYSTADSORBENT ADSORBENT HCS + H2O H2 + CO2

    E-Print Network [OSTI]

    Southern California, University of

    - CO2 Adsorbent Effect of Membrane Properties On HAMR performance 3.190.3883--H2O --54.30.0248Ar --67 CATALYST CATALYSTADSORBENT ADSORBENT C O 2CO2 CO2 CO2 HCS + H2O H2 + CO2 Mork Family Department of Chemical using hydrotalcite-type CO2 adsorbents and nanoporous H2-selective carbon molecular sieve membranes (CMS

  12. Sandia National Laboratories: hydrogen fuel expertise

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    expertise Widespread Hydrogen Fueling Infrastructure Is the Goal of H2FIRST Project On June 4, 2014, in Capabilities, Center for Infrastructure Research and Innovation (CIRI),...

  13. Sandia National Laboratories: Hydrogen Contaminant Detection

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and the National Renewable Energy Laboratory (NREL) announce the publication of two new Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) reports on...

  14. Sandia National Laboratories: Hydrogen Financial Analysis Tool

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and the National Renewable Energy Laboratory (NREL) announce the publication of two new Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) reports on...

  15. Sandia National Laboratories: hydrogen fueling station

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    station Widespread Hydrogen Fueling Infrastructure Is the Goal of H2FIRST Project On June 4, 2014, in Capabilities, Center for Infrastructure Research and Innovation (CIRI),...

  16. Hunt for cold H2 molecules

    E-Print Network [OSTI]

    F. Combes

    2006-01-30T23:59:59.000Z

    The bulk of the molecular component in galaxies is made of cold H2, which is not observed directly, but which abundance is derived from indirect tracers such as CO emission. The CO to H2 conversion ratio remains uncertain, and may vary by large factors in special environments with different excitation or metallicity. Recent cold gas discoveries (through gamma-rays or cold dust emission) are reviewed and the most promising tracers in the future are discussed, such as the primordial molecules HD and LiH, or the pure rotational lines of excited H2*.

  17. A crossed molecular beams study of the reaction of the ethynyl radical )) with allene (H2CCCH2(X1

    E-Print Network [OSTI]

    Kaiser, Ralf I.

    molecular hydrogen (H2),8,9 molecular oxygen (O2),10 and water (H2O)11 via hydrocarbons 2,12­16 to nitrogen role in the synthesis of polyynes, polycyclic aromatic hydrocarbons (PAHs), and soot particles;1 (PAHs) and aerosol particles.22,23 Since the macroscopic alteration of combustion systems and planetary

  18. Kinetically Relevant Steps and H2/D2 Isotope Effects in Fischer-Tropsch Synthesis on Fe and Co Catalysts

    E-Print Network [OSTI]

    Iglesia, Enrique

    Kinetically Relevant Steps and H2/D2 Isotope Effects in Fischer-Tropsch Synthesis on Fe and CoVed: August 4, 2010; ReVised Manuscript ReceiVed: October 3, 2010 H2/D2 isotope effects on Fischer-Tropsch by theory and experiment for the specific case of CO hydrogenation. 1. Introduction Fischer-Tropsch

  19. Assessment of kinetic modeling for lean H2/CH4/O2/diluent flames at high pressures

    E-Print Network [OSTI]

    Ju, Yiguang

    : Hydrogen; Methane; Syngas; Flame speed; Chemical mechanism 1. Introduction The H2/O2 reaction system CO, CO2, H2O, CH4 and other small hydrocarbons (synthetic gas or "syngas") from coal or biomass gasification [2]. Typical syngas mixtures can contain significant amounts of small molecular weight

  20. Hawaii hydrogen power park Hawaii Hydrogen Power Park

    E-Print Network [OSTI]

    energy source. (Barrier V-Renewable Integration) Hydrogen storage & distribution system. (Barrier V Vent AC Power Reformer Low Pressure H2 Storage Propane Hydrogen Optional Reformer System Optional Wind. Low pressure hydrogen storage utilizing propane tanks. High pressure storage using lightweight

  1. June 15-16, 2001 SPLST 2001 -Szeged, Hungary 1 Columbus -Tool for Reverse Engineering

    E-Print Network [OSTI]

    Ferenc, Rudolf

    June 15-16, 2001 SPLST 2001 - Szeged, Hungary 1 Columbus - Tool for Reverse Engineering Large;June 15-16, 2001 SPLST 2001 - Szeged, Hungary 2 Introduction · Software systems are rapidly growing" [Chikofsky et al.] #12;June 15-16, 2001 SPLST 2001 - Szeged, Hungary 3 Assessment of RE tools · Analysis

  2. June 15-16, 2001 SPLST 2001 -Szeged, Hungary 1 Recognizing Design Patterns in

    E-Print Network [OSTI]

    Ferenc, Rudolf

    June 15-16, 2001 SPLST 2001 - Szeged, Hungary 1 Recognizing Design Patterns in C++ programs of Helsinki #12;June 15-16, 2001 SPLST 2001 - Szeged, Hungary 2 Introduction Experiments with two software of abstraction ­ Visualization of software architectures #12;June 15-16, 2001 SPLST 2001 - Szeged, Hungary 3

  3. Metallization of Fluid Hydrogen 3.1 Introduction to Metallic Hydrogen

    E-Print Network [OSTI]

    Louis, Ard

    Chapter 3 Metallization of Fluid Hydrogen 3.1 Introduction to Metallic Hydrogen 3.1.1 Some background on dense hydrogen Hydrogen, out of it the Universe evolved, every atom and leaf, marine iguana and apricot­smelling chanterelle. But my, my, what alchemy: nondescript H 2 --Diane Ackerman 1 -- Hydrogen

  4. Uncertainties in H2 and HD Chemistry and Cooling and their Role in Early Structure Formation

    E-Print Network [OSTI]

    S. C. O. Glover; T. Abel

    2008-03-12T23:59:59.000Z

    At low temperatures, the main coolant in primordial gas is molecular hydrogen, H2. Recent work has shown that primordial gas that is not collapsing gravitationally but is cooling from an initially ionized state forms hydrogen deuteride, HD, in sufficient amounts to cool the gas to the temperature of the cosmic microwave background. This extra cooling can reduce the characteristic mass for gravitational fragmentation and may cause a shift in the characteristic masses of population III stars. Motivated by the importance of the atomic and molecular data for the cosmological question, we assess several chemical and radiative processes that have hitherto been neglected: the sensitivity of the low temperature H2 cooling rate to the ratio of ortho-H2 to para-H2, the uncertainty in the low temperature cooling rate of H2 excited by collisions with H, the effects of cooling from H2 excited by collisions with H+ and e-, and the large uncertainties in the rates of several of the reactions responsible for determining the H2 fraction in the gas. We show that the most important of the neglected processes is the excitation of H2 by collisions with protons and electrons. This cools the gas more rapidly at early times, and so it forms less H2 and HD at late times. This fact, as well as several of the chemical uncertainties presented here, significantly affects the thermal evolution of the gas. We anticipate that this may lead to clear differences in future detailed 3D studies of first structure formation. Finally, we show that although the thermal evolution of the gas is in principle sensitive to the ortho-para ratio, in practice the standard assumption of a 3:1 ratio produces results that are almost indistinguishable from those produced by a more detailed treatment. (abridged)

  5. H2A Delivery Models and Results

    Broader source: Energy.gov (indexed) [DOE]

    Single delivery mode - 100 kgd or 1500 kgd forecourts * Delivery mode defined by user - Pipeline with geologic storage - Liquid hydrogen (LH2) via terminal and truck - Compressed...

  6. An Assessment of the Near-Term Costs of Hydrogen Refueling Stations and Station Components

    E-Print Network [OSTI]

    Lipman, T E; Weinert, Jonathan X.

    2006-01-01T23:59:59.000Z

    a fuel cell or hydrogen combustion engine “gen-set. ” ByCell H 2 = hydrogen ICE = internal-combustion engine kg =

  7. Uncertainties in H2 and HD Chemistry and Cooling and their Role in Early Structure Formation

    E-Print Network [OSTI]

    Glover, S C O

    2008-01-01T23:59:59.000Z

    At low temperatures, the main coolant in primordial gas is molecular hydrogen, H2. Recent work has shown that primordial gas that is not collapsing gravitationally but is cooling from an initially ionized state forms hydrogen deuteride, HD, in sufficient amounts to cool the gas to the temperature of the cosmic microwave background. This extra cooling can reduce the characteristic mass for gravitational fragmentation and may cause a shift in the characteristic masses of population III stars. Motivated by the importance of the atomic and molecular data for the cosmological question, we assess several chemical and radiative processes that have hitherto been neglected: the sensitivity of the low temperature H2 cooling rate to the ratio of ortho-H2 to para-H2, the uncertainty in the low temperature cooling rate of H2 excited by collisions with H, the effects of cooling from H2 excited by collisions with H+ and e-, and the large uncertainties in the rates of several of the reactions responsible for determining the ...

  8. Molecular Hydrogen in Infrared Cirrus

    E-Print Network [OSTI]

    Kristen Gillmon; J. Michael Shull

    2005-07-25T23:59:59.000Z

    We combine data from our recent FUSE survey of interstellar molecular hydrogen absorption toward 50 high-latitude AGN with COBE-corrected IRAS 100 micron emission maps to study the correlation of infrared cirrus with H2. A plot of the H2 column density vs. IR cirrus intensity shows the same transition in molecular fraction, f_H2, as seen with total hydrogen column density, N_H. This transition is usually attributed to H2 self-shielding, and it suggests that many diffuse cirrus clouds contain H2 in significant fractions, f_H2 = 1-30%. These clouds cover approximately 50% of the northern sky at latitudes b > 30 degrees, at temperature-corrected 100 micron intensities D_100 > 1.5 MJy/sr. The sheetlike cirrus clouds, with hydrogen densities n_H > 30 cm^-3, may be compressed by dynamical processes at the disk-halo interface, and they are conducive to H2 formation on grain surfaces. Exploiting the correlation between N(H2) and 100 micron intensity, we estimate that cirrus clouds at b > 30 contain approximately 3000 M_sun in H2. Extrapolated over the inner Milky Way, the cirrus may contain 10^7 M_sun of H2 and 10^8 M_sun in total gas mass. If elevated to 100 pc, their gravitational potential energy is ~10^53 erg.

  9. EFFECT OF H2 PRODUCED THROUGH STEAM-METHANE REFORMING ON CHP PLANT EFFICIENCY

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 EFFECT OF H2 PRODUCED THROUGH STEAM-METHANE REFORMING ON CHP PLANT EFFICIENCY O. Le Corre1 , C for a CHP plant based on spark ignition engine running under lean conditions. An overall auto-fire or knock occurred. Keywords: Hydrogen, CHP, natural gas, power, efficiency, environmental impact. 1

  10. Mass Production Cost Estimation of Direct H2 PEM Fuel Cell Systems for

    E-Print Network [OSTI]

    1 Mass Production Cost Estimation of Direct H2 PEM Fuel Cell Systems for Transportation (2012), annually updated costs analyses will be conducted for PEM fuel cell passenger buses as well to eliminate the need for oil in the transportation sector. Fuel cell vehicles can operate on hydrogen, which

  11. Structure and vibrational spectra of H ,,H2O...8: Is the excess proton

    E-Print Network [OSTI]

    Ciobanu, Cristian

    Structure and vibrational spectra of H¿ ,,H2O...8: Is the excess proton in a symmetrical hydrogen environment of the excess proton sometimes resembles a symmetric H5O2 structure and sometimes H3O , but many to which the excess proton resembles H5O2 or H3O . Other bond lengths and, perhaps most useful

  12. Hydrogen, Fuel Cells, and Infrastructure Technologies FY 2002 Progress Report II.C Fossil-Based

    E-Print Network [OSTI]

    , noncatalytic decomposition of hydrogen sulfide (H2S) in H2S-rich waste streams into hydrogen and elemental at an industrial site. Approach · Develop a numerical model for the superadiabatic H2S decomposition reactor viability of the concept. · Designed and constructed a state-of-the-art superadiabatic H2S decomposition

  13. H2USA | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreaking of Blythe Solar Power Project Groundof|than Ever | DepartmentofH2USA H2USA

  14. DOE Hydrogen Pipeline Working Group Workshop

    E-Print Network [OSTI]

    Laporte, TX to near Lake Charles, LA. This system has approximately 228 miles of DOT regulated H2 pipeline of DOT regulated H2 pipeline. Portions of this system operating since early 1983. Pipeline sizeDOE Hydrogen Pipeline Working Group Workshop August 31, 2005 Augusta, Georgia #12;Hydrogen Pipeline

  15. On the decentralized H2 optimal control

    E-Print Network [OSTI]

    On the decentralized H2 optimal control of bilateral teleoperation systems with time delays Maxim Kristalny and Jang Ho Cho Abstract-- Decentralized control of bilateral teleoperation systems with time multiplicative delay. The recent loop shifting techniques for delayed systems control are used then to find

  16. Mineralization of Basalts in the CO2-H2O-H2S System. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    HT, BP McGrail, AT Owen, and BW Arey.2013."Mineralization of Basalts in the CO2-H2O-H2S System."International Journal of Greenhouse Gas Control 16:187-196. doi:10.1016...

  17. H2-Assisted NOx Traps: Test Cell Results Vehicle Installations

    Broader source: Energy.gov (indexed) [DOE]

    Sam Crane August 28, 2003 H 2 -Assisted NOx Traps: Test Cell Results Vehicle Installations 2 Project Objectives * Determine Advantages of H 2 Assisted NO x Trap Regeneration *...

  18. H2A Delivery: Forecourt Compression & Storage Optimization (Part...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    H2A Delivery: Forecourt Compression & Storage Optimization (Part II) H2A Delivery: Forecourt Compression & Storage Optimization (Part II) Presentation by Matthew Hooks of TIAX at...

  19. THERMOCATALYTIC CO2-FREE PRODUCTION OF HYDROGEN FROM HYDROCARBON FUELS

    E-Print Network [OSTI]

    for the process efficiency. However these impurities may result in contamination of hydrogen by CO, CO2 and H2S which should be removed from the product gas using methanation and H2S scrubbing steps, respectively. 11

  20. C. Plennevaux et al., Electrochemistry Communications 26 (2013) 1720 Contribution of CO2 on hydrogen evolution and hydrogen permeation in low

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    2013-01-01T23:59:59.000Z

    on hydrogen evolution and hydrogen permeation in low alloy steels exposed to H2S environment C. Plennevauxa Cedex 69621, FRANCE Summary Hydrogen charging in low alloy steels is a major problem in oil and gas environments containing hydrogen sulfide (H2S). The risk of sulfide stress cracking (SSC) is usually determined

  1. Removal of Headspace CO2 Increases Biological Hydrogen

    E-Print Network [OSTI]

    For biological hydrogen production by fermentation to be a useful method of hydrogen generation, molar yields loss of hydrogen to methanogenesis, hydrogen is still lost to acetic acid generation from hydrogen.4 to 2.0 mol of H2/mol of glucose). The soluble byproducts in all tests consisted primarily of acetate

  2. H2A Biomethane Model Documentation and a Case Study for Biogas From Dairy Farms

    SciTech Connect (OSTI)

    Saur, G.; Jalalzadeh, A.

    2010-12-01T23:59:59.000Z

    The new H2A Biomethane model was developed to estimate the levelized cost of biomethane by using the framework of the vetted original H2A models for hydrogen production and delivery. For biomethane production, biogas from sources such as dairy farms and landfills is upgraded by a cleanup process. The model also estimates the cost to compress and transport the product gas via the pipeline to export it to the natural gas grid or any other potential end-use site. Inputs include feed biogas composition and cost, required biomethane quality, cleanup equipment capital and operations and maintenance costs, process electricity usage and costs, and pipeline delivery specifications.

  3. H2-MHR Pre-Conceptual Design Report: SI-Based Plant; HTE-Based Plant

    SciTech Connect (OSTI)

    Matt Richards; A.S. Shenoy; L.C. Brown; R.T. Buckingham; E.A. Harvego; K.L. Peddicord; S.M.M. Reza; J.P. Coupey

    2006-04-19T23:59:59.000Z

    Hydrogen and electricity are expected to dominate the world energy system in the long term. The world currently consumes about 50 million metric tons of hydrogen per year, with the bulk of it being consumed by the chemical and refining industries. The demand for hydrogen is expected to increase, especially if the U.S. and other countries shift their energy usage towards a hydrogen economy, with hydrogen consumed as an energy commodity by the transportation, residential, and commercial sectors. However, there is strong motivation to not use fossil fuels in the future as a feedstock for hydrogen production, because the greenhouse gas carbon dioxide is a byproduct and fossil fuel prices are expected to increase significantly. For electricity and hydrogen production, an advanced reactor technology receiving considerable international interest is a modular, passively-safe version of the high-temperature, gas-cooled reactor (HTGR), known in the U.S. as the Modular Helium Reactor (MHR), which operates at a power level of 600 MW(t). For electricity production, the MHR operates with an outlet helium temperature of 850 C to drive a direct, Brayton-cycle power-conversion system (PCS) with a thermal-to-electrical conversion efficiency of 48 percent. This concept is referred to as the Gas Turbine MHR (GT-MHR). For hydrogen production, the process heat from the MHR is used to produce hydrogen. This concept is referred to as the H2-MHR.

  4. Historical Information H.2 Biological Studies

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group currentBradleyTableSelling7111AWell:F E ," POSTGranite_-_ . - H.2

  5. Distance-dependent radiation chemistry: Oxidation versus hydrogenation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Distance-dependent radiation chemistry: Oxidation versus hydrogenation of CO in electron-irradiated H2OCOH2O ices. Distance-dependent radiation chemistry: Oxidation versus...

  6. Sandia National Laboratories: critical R&D barriers to hydrogen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and the National Renewable Energy Laboratory (NREL) announce the publication of two new Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) reports on...

  7. HYDROGEN-ASSISTED FAILURE OF ALLOYS X-750 AND 625 UNDER SLOW STRAIN-RATE CONDITIONS

    E-Print Network [OSTI]

    Motta, Arthur T.

    HYDROGEN-ASSISTED FAILURE OF ALLOYS X-750 AND 625 UNDER SLOW STRAIN-RATE CONDITIONS R.S. Daum, A-purity, deaerated water in order to determine whether hydrogen embrittlement occurs in these alloys at room psig nitrogen (0 cc H2/kg H2O STP) and 40 psig hydrogen (60 cc H2/kg H2O STP), on Alloy X-750 in two

  8. Integrated Hydrogen Production, Purification and Compression System

    E-Print Network [OSTI]

    -system complexity. · Increase efficiency by: ­ directly producing high-purity hydrogen using high temperature, H2 in hot water or hot air. 100 50 Step 2: Hot fluid heats the alloy causing the hydrogen to be released Hydride Alloy 2 Hydride Alloy 3 Hydride Alloy 4 Hot Fluid Cold Fluid Metal Hydride Hydrogen Compressor

  9. The Status of Renewable Hydrogen and Energy Station Technologies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (H2E3) Basic Research for the Hydrogen Fuel Initiative Status and Prospects of the Global Automotive Fuel Cell Industry and Plans for Deployment of Fuel Cell Vehicles and Hydrogen...

  10. Upper limits for PH3 and H2S in Titan's Atmosphere from Cassini CIRS

    E-Print Network [OSTI]

    Nixon, Conor A; Irwin, Patrick G J; Horst, Sarah M; 10.1016/j.icarus.2013.02.024

    2013-01-01T23:59:59.000Z

    We have searched for the presence of simple P and S-bearing molecules in Titan's atmosphere, by looking for the characteristic signatures of phosphine and hydrogen sulfide in infrared spectra obtained by Cassini CIRS. As a result we have placed the first upper limits on the stratospheric abundances, which are 1 ppb (PH3) and 330 ppb (H2S), at the 2-sigma significance level.

  11. Orbits in the H2O molecule

    E-Print Network [OSTI]

    K. Efstathiou; G. Contopoulos

    2001-02-07T23:59:59.000Z

    We study the forms of the orbits in a symmetric configuration of a realistic model of the H2O molecule with particular emphasis on the periodic orbits. We use an appropriate Poincar\\'e surface of section (PSS) and study the distribution of the orbits on this PSS for various energies. We find both ordered and chaotic orbits. The proportion of ordered orbits is almost 100% for small energies, but decreases abruptly beyond a critical energy. When the energy exceeds the escape energy there are still non-escaping orbits around stable periodic orbits. We study in detail the forms of the various periodic orbits, and their connections, by providing appropriate stability and bifurcation diagrams.

  12. Highly Selective H2 Separation Zeolite Membranes for Coal Gasification Membrane Reactor Applications

    SciTech Connect (OSTI)

    Mei Hong; Richard Noble; John Falconer

    2007-09-24T23:59:59.000Z

    Zeolite membranes are thermally, chemically, and mechanically stable. They also have tunable molecular sieving and catalytic ability. These unique properties make zeolite membrane an excellent candidate for use in catalytic membrane reactor applications related to coal conversion and gasification, which need high temperature and high pressure range separation in chemically challenging environment where existing technologies are inefficient or unable to operate. Small pore, good quality, and thin zeolite membranes are needed for highly selective H2 separation from other light gases (CO2, CH4, CO). However, current zeolite membranes have either too big zeolite pores or a large number of defects and have not been successful for H2 separation from light gases. The objective of this study is to develop zeolite membranes that are more suitable for H2 separation. In an effort to tune the size of zeolite pores and/or to decrease the number of defects, medium-pore zeolite B-ZSM-5 (MFI) membranes were synthesized and silylated. Silylation on B-ZSM-5 crystals reduced MFI-zeolite pore volume, but had little effect on CO2 and CH4 adsorption. Silylation on B-ZSM-5 membranes increased H2 selectivity both in single component and in mixtures with CO2, CH4, or N2. Single gas and binary mixtures of H2/CO2 and H2/CH4 were permeated through silylated B-ZSM-5 membranes at feed pressures up to 1.7 MPa and temperatures up to 773 K. For one B-ZSM-5 membrane after silylation, the H2/CO2 separation selectivity at 473 K increased from 1.4 to 37, whereas the H2/CH4 separation selectivity increased from 1.6 to 33. Hydrogen permeance through a silylated BZSM-5 membrane was activated with activation energy of {approx}10 kJ/mol, but the CO2 and CH4 permeances decreased slightly with temperature in both single gas and in mixtures. Therefore, the H2 permeance and H2/CO2 and H2/CH4 separation selectivities increased with temperature. At 673 K, the H2 permeance was 1.0x10-7 mol{center_dot}m-2{center_dot}s-1{center_dot}Pa-1, and the H2/CO2 separation selectivity was 47. Above 673 K, the silylated membrane catalyzed reverse water gas shift reaction and still separated H2 with high selectivity; and it was thermally stable. However, silylation decreased H2 permeance more than one order of magnitude. Increasing the membrane feed pressure increased the H2 flux and the H2 mole fraction in the permeate stream for both H2/CO2 and H2/CH4 mixtures. The H2 separation performance of the silylated B-ZSM-5 membranes depended on the initial membrane quality and acidity, as well as the silane precursors. Another approach used in this study is optimizing the synthesis of small-pore SAPO-34 (CHA) membranes and/or modifying SAPO-34 membranes by silylation or ion exchange. For SAPO-34 membranes, strong CO2 adsorption inhibited H2 adsorption and decreased H2 permeances, especially at low temperatures. At 253 K, CO2/H2 separation selectivities of a SAPO-34 membrane were greater than 100 with CO2 permeances of about 3 x 10-8 mol{center_dot}m-2{center_dot}s-1{center_dot}Pa-1. The high reverse-selectivity of the SAPO-34 membranes can minimize H2 recompression because H2 remained in the retentate stream at a higher pressure. The CO2/H2 separation selectivity exhibited a maximum with CO2 feed concentration possibly caused by a maximum in the CO2/H2 sorption selectivity with increased CO2 partial pressure. The SAPO-34 membrane separated H2 from CH4 because CH4 is close to the SAPO-34 pore size so its diffusivity (ABSTRACT TRUNCATED)

  13. H2 Energy LLC | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, search OpenEI ReferenceJumpEnergyStrategy | Open Energy Sector: Hydro, Hydrogen

  14. Adsorption, Desorption, and Displacement Kinetics of H2O and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Displacement Kinetics of H2O and CO2 on TiO2(110). Adsorption, Desorption, and Displacement Kinetics of H2O and CO2 on TiO2(110). Abstract: The adsorption, desorption, and...

  15. Analysis of the Activation and Heterolytic Dissociation of H2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dissociation of H2 by Frustrated Lewis Pairs: NH3BX3 (X H, F, and Cl) . Analysis of the Activation and Heterolytic Dissociation of H2 by Frustrated Lewis Pairs: NH3...

  16. Minimal Proton Channel Enables H2 Oxidation and Production with...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Minimal Proton Channel Enables H2 Oxidation and Production with a Water-Soluble Nickel-Based Catalyst. Minimal Proton Channel Enables H2 Oxidation and Production with a...

  17. Optimization of Direct-Injection H2 Combustion Engine Performance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2010 -- Washington D.C. ace009wallner2010o.pdf More Documents & Publications Optimization of Direct-Injection H2 Combustion Engine Performance, Efficiency, and Emissions H2...

  18. Roadmap for H2 in the Nordic Countries

    E-Print Network [OSTI]

    Roadmap for H2 in the Nordic Countries Per Dannemand Andersen, Ole Greve, Stefan Krüger Nielsen: Per Dannemand Andersen, Ole Greve, Stefan Krûger Niel- sen Title: Roadmaps for H2 in the Nordic char.): This report reports on a roadmap workshop held in Roskilde in 2004 as a part of the Nordic H2

  19. Laboratory-measured H2SO4-H2O-NH3 ternary homogeneous nucleation rates: Initial observations

    E-Print Network [OSTI]

    Lee, Shan-Hu

    -ammonia (H2SO4-H2O-NH3) ternary homogeneous nucleation (THN), with a fast flow nucleation reactor attached. 1. Introduction [2] Nucleation is a gas-to-particle conversion process [Seinfeld and Pandis, 2006

  20. Biological Hydrogen Production Using Synthetic Wastewater Biotin and glutamic acid are not required for biological hydrogen production.

    E-Print Network [OSTI]

    Barthelat, Francois

    Biological Hydrogen Production Using Synthetic Wastewater Conclusion ·Biotin and glutamic acid are not required for biological hydrogen production. ·MgSO4 .7H2O is a required nutrient, but hydrogen production work should focus on minimizing the lag time in biological hydrogen production, by varying nutrient

  1. Journal of Power Sources 165 (2007) 509516 Direct NaBH4/H2O2 fuel cells

    E-Print Network [OSTI]

    Carroll, David L.

    2007-01-01T23:59:59.000Z

    Journal of Power Sources 165 (2007) 509­516 Direct NaBH4/H2O2 fuel cells George H. Mileya,e,, Nie online 5 December 2006 Abstract A fuel cell (FC) using liquid fuel and oxidizer is under investigation. H Published by Elsevier B.V. Keywords: Fuel cell; Hydrogen peroxide; Regenerative fuel cell; Sodium

  2. A Simplified Solution For Gas Flow During a Blow-out in an H2 or Air Storage Cavern

    E-Print Network [OSTI]

    Boyer, Edmond

    A Simplified Solution For Gas Flow During a Blow-out in an H2 or Air Storage Cavern Pierre Bérest, Milano, Italy Abstract A small number of blow-outs from gas storage caverns (for example, in Moss Bluff and hydrogen storage in salt caverns. Compressed Air Energy Storage (CAES) is experiencing a rise in interest

  3. A calorimetric analysis of a polymer electrolyte fuel cell and the production of H2O2 at the cathode

    E-Print Network [OSTI]

    Kjelstrup, Signe

    31.08.2009 1 A calorimetric analysis of a polymer electrolyte fuel cell and the production of H2O2 fuel cell that is operated on hydrogen and oxygen at 50 °C and 1 bar. The cell had a SolviCore Catalyst 1. INTRODUCTION The energy that is dissipated as heat in fuel cells is interesting for several

  4. LLNL input to FY94 hydrogen annual report

    SciTech Connect (OSTI)

    Schock, R.N.; Smith, J.R.; Rambach, G.; Pekala, R.W.; Westbrook, C.K.; Richardson, J.H.

    1994-12-16T23:59:59.000Z

    This report summarizes the FY 1994 progress made in hydrogen research at the Lawrence Livermore National Laboratory. Research programs covered include: Technical and Economic Assessment of the Transport and Storage of Hydrogen; Research and Development of an Optimized Hydrogen-Fueled Internal Combustion Engine; Hydrogen Storage in Engineered Microspheres; Synthesis, Characterization and Modeling of Carbon Aerogels for Hydrogen Storage; Chemical Kinetic Modeling of H2 Applications; and, Municipal Solid Waste to Hydrogen.

  5. Green Energy: Advancing Bio-Hydrogen (Presentation)

    SciTech Connect (OSTI)

    Alber, D.

    2007-07-01T23:59:59.000Z

    Developing a model of metabolism linked to H2 production in green algae. Develop tools for parameter discovery and optimization at organism level and advance knowledge of hydrogen-producting photosynthetic organisms.

  6. Hydrogen Fueling Infrastructure Research and Station Technology

    Broader source: Energy.gov [DOE]

    Presentation slides from the DOE Fuel Cell Technologies Office webinar "An Overview of the Hydrogen Fueling Infrastructure Research and Station Technology (H2FIRST) Project" held on November 18, 2014.

  7. Microchannel Reactor System Design & Demonstration For On-Site H2O2 Production by Controlled H2/O2 Reaction

    SciTech Connect (OSTI)

    Adeniyi Lawal

    2008-12-09T23:59:59.000Z

    We successfully demonstrated an innovative hydrogen peroxide (H2O2) production concept which involved the development of flame- and explosion-resistant microchannel reactor system for energy efficient, cost-saving, on-site H2O2 production. We designed, fabricated, evaluated, and optimized a laboratory-scale microchannel reactor system for controlled direct combination of H2 and O2 in all proportions including explosive regime, at a low pressure and a low temperature to produce about 1.5 wt% H2O2 as proposed. In the second phase of the program, as a prelude to full-scale commercialization, we demonstrated our H2O2 production approach by ‘numbering up’ the channels in a multi-channel microreactor-based pilot plant to produce 1 kg/h of H2O2 at 1.5 wt% as demanded by end-users of the developed technology. To our knowledge, we are the first group to accomplish this significant milestone. We identified the reaction pathways that comprise the process, and implemented rigorous mechanistic kinetic studies to obtain the kinetics of the three main dominant reactions. We are not aware of any such comprehensive kinetic studies for the direct combination process, either in a microreactor or any other reactor system. We showed that the mass transfer parameter in our microreactor system is several orders of magnitude higher than what obtains in the macroreactor, attesting to the superior performance of microreactor. A one-dimensional reactor model incorporating the kinetics information enabled us to clarify certain important aspects of the chemistry of the direct combination process as detailed in section 5 of this report. Also, through mathematical modeling and simulation using sophisticated and robust commercial software packages, we were able to elucidate the hydrodynamics of the complex multiphase flows that take place in the microchannel. In conjunction with the kinetics information, we were able to validate the experimental data. If fully implemented across the whole industry as a result of our technology demonstration, our production concept is expected to save >5 trillion Btu/year of steam usage and >3 trillion Btu/year in electric power consumption. Our analysis also indicates >50 % reduction in waste disposal cost and ~10% reduction in feedstock energy. These savings translate to ~30% reduction in overall production and transportation costs for the $1B annual H2O2 market.

  8. Modeling H2 adsorption in carbon-based structures 

    E-Print Network [OSTI]

    Lamonte, Kevin Anthony

    2009-05-15T23:59:59.000Z

    Hydrogen storage has been identified as a primary bottleneck in the large-scale implementation of a hydrogen-based economy. Many research efforts are underway to both improve the capacity of existing hydrogen storage systems ...

  9. IONICALLY CONDUCTING MEMBRANES FOR HYDROGEN PRODUCTION AND

    E-Print Network [OSTI]

    SEQUESTRATION Oxygen Transport Membrane Hydrogen Transport Membrane Natural Gas Coal Biomass Syngas CO/H2 WGS H2 operating experience. #12;ELTRON RESEARCH INC. Syngas Production Rate ­ 60 mL/min cm2 @ 900°C Equivalent O2 Operational Experience Under High Pressure Differential SUMMARY OF ELTRON OXYGEN TRANSPORT MEMBRANE SYNGAS

  10. H2FIRST Reference Station Design Task: Project Deliverable 2...

    Broader source: Energy.gov (indexed) [DOE]

    layouts. This work presents the hydrogen community with a uniform, cost-optimal formula for designing and building hydrogen stations. The piping and instrumentation diagrams...

  11. Laboratory evidence for the non-detection of excited nascent H2 in dark clouds

    E-Print Network [OSTI]

    Congiu, Emanuele; Kristensen, Lars E; Dulieu, Francois; Lemaire, Jean Louis

    2009-01-01T23:59:59.000Z

    There has always been a great deal of interest in the formation of H2 as well as in the binding energy released upon its formation on the surface of dust grains. The present work aims at collecting experimental evidence for how the bond energy budget of H2 is distributed between the reaction site and the internal energy of the molecule. So far, the non-detection of excited nascent H2 in dense quiescent clouds could be a sign that either predictions of emission line intensities are not correct or the de-excitation of the newly formed molecules proceeds rapidly on the grain surface itself. In this letter we present experimental evidence that interstellar molecular hydrogen is formed and then rapidly de-excited on the surface of porous water ice mantles. In addition, although we detect ro-vibrationally excited nascent molecules desorbing from a bare non-porous (compact) water ice film, we demonstrate that the amount of excited nascent hydrogen molecules is significantly reduced no matter the morphology of the wa...

  12. HI-to-H2 Transitions in the Perseus Molecular Cloud

    E-Print Network [OSTI]

    Bialy, Shmuel; Lee, Min-Young; Petit, Franck Le; Roueff, Evelyne

    2015-01-01T23:59:59.000Z

    We use the Sternberg et al. (2014) theory for interstellar atomic to molecular (HI-to-H$_2$) conversion to analyze HI-to-H$_2$ transitions in five (low-mass) star-forming and dark regions in the Perseus molecular cloud, B1, B1E, B5, IC348, and NGC1333. The observed HI mass surface densities of 6.3 to 9.2 M$_{\\odot}$ pc$^{-2}$ are consistent with HI-to-H$_2$ transitions dominated by HI-dust shielding in predominantly atomic envelopes. For each source, we constrain the dimensionless parameter $\\alpha G$, and the effective ratio, $I_{\\rm UV}/n$, of the FUV intensity to hydrogen gas density. We find $\\alpha G$ values from 5.0 to 47.0, implying characteristic atomic hydrogen densities 11.8 to 1.0 cm$^{-3}$, for $I_{\\rm UV} \\approx 1$ appropriate for Perseus. Our analysis implies that the dusty HI shielding layers are probably multiphased, with thermally unstable UNM gas in addition to cold CNM within the 21 cm kinematic radius.

  13. Roadmap for Hydrogen and Fuel Cell Vehicles in California: A Transition Strategy through 2017

    E-Print Network [OSTI]

    Ogden, J; Cunningham, Joshua M; Nicholas, Michael A

    2010-01-01T23:59:59.000Z

    new partnerships? H2-FCV Roadmap Report - FINAL December 21,Roadmap for Hydrogen and Fuel Cell Vehicles in California: ACalifornia, Davis H2-FCV Roadmap Report - FINAL December 21,

  14. NPP training simulators in Hungary experience in development and utilization

    SciTech Connect (OSTI)

    Janosy, J.S. [Atomic Energy Research Institute, Budapest (Hungary)

    1996-11-01T23:59:59.000Z

    The construction of the only NPP in Hungary - the Paks NPP - started in 1975. The four units of VVER-440/213 were connected to the grid in 1982, 1984, 1986 and 1987. During the construction no simulator has been delivered with the power plant. Moreover, there were no state-of-art simulators in Central and Eastern Europe and in the former Soviet Union; not for the given type, not for civil use. The only simulator for the VVER-440 existing that time was made for the Loviisa NPP in Finland. This plant is not very similar to the Paks NPP; moreover, the pressure suppression system in the hermetical part of the primary circuit, the instrumentation and control systems, the main control room and the secondary circuit are completely different. Anyway, the training of Paks operators on this simulator was out of question - regardless the similarity problems. The design of the Paks NPP was made in the Soviet Union, therefore not too much design information was available in Hungary. During the creation of simulation models the authors had to rely mostly on common theory and measured performance. Besides the efforts to create a basic principle, full-scope replica and compact simulators there was a great need to use verified codes with more detailed models for better understanding the behavior and for evaluation of the safety. Thanks to these great efforts, the simulators were expanded to evaluate the performance of the trainees, for simulation of SBLOCA and LBLOCA events; the authors are checking and validating the operational procedures; soon they start the design of the functions of a new reactor protection system and they participate in international efforts to deliver training simulators to other VVER-440 power plants. The paper gives an overview of all these activities, referring to some key publications for each of them.

  15. H2 Refuel H-Prize Technical Data Collection Requirements

    Broader source: Energy.gov [DOE]

    Download the presentation slides from the Fuel Cell Technologies Office webinar "H2 Refuel H-Prize Technical Data Collection Requirements Webinar Slides" held on May 14, 2015.

  16. H2 -optimal model reduction of MIMO systems

    E-Print Network [OSTI]

    2007-09-28T23:59:59.000Z

    Keyword Multivariable systems, model reduction, optimal H2 approximation, tangential interpolation. 1 Introduction. In this paper we will consider the problem of ...

  17. Photocatalytic Formic Acid Conversion on CdS Nanocrystals with Controllable Selectivity for H_2 or CO

    E-Print Network [OSTI]

    Kuehnel, Moritz F.; Wakerley, David W.; Orchard, Katherine L.; Reisner, Erwin

    2015-01-01T23:59:59.000Z

    in fuel cells but its safe storage and transport remain the subject of intense research.[1] Formic acid (HCO2H, FA) has received considerable attention as a potential renewable fuel of high energy density. Its low toxicity and high gravimetric hydrogen... ?1 h?1 (Fig. 1A, Table 1). Addition of up to 0.5 mM CoCl2·6H2O resulted in enhanced rates of up to 116±14 mmol H2 gcat?1 h?1 (QD:Co ratio approx. 500:1, see Fig. S2 and Tables S1-S2 for optimization details). Only traces of CO were detected...

  18. Boundary Analysis for H2 Production by Fermentation

    E-Print Network [OSTI]

    Price, $/kg H2 2.08 where the required H2 price is defined as the price required for a 10% after sugar cane or sugar beet processing, wood fiber hydrolyzates from pulp mills, or biomass hydrolyzates from agricultural resides, energy crops and other biomass sources are among the many possible sources

  19. Improved Photobiological H2 Production in Engineered Green Algal Cells*

    E-Print Network [OSTI]

    of Queensland, Queensland 4072, Australia Oxygenic photosynthetic organisms use solar energy to split water (H2O of photosynthetic organisms have evolved the ability to harness the huge solar energy resource to drive H2 fuel. Lucia Campus, Queensland 4072, Australia, and ¶ Faculty of Biological and Chemical Sciences, University

  20. Autothermal Cyclic Reforming Based H2 Generating & Dispensing System

    E-Print Network [OSTI]

    Pressure Reforming Comp- ressor 100 psig 100 psig Reformer H2 PSA SyngasNatural Gas Low Pressure Reforming CMP Syngas 5 psig5 psig Reformer CMP 100 psig H2 PSA Natural Gas Syngas CMP HX CMP HX Thermal Reliability (Eliminates Syngas Compressor) Advantages 70-80%70-80%Thermal Efficiency (Excludes Electricity

  1. Modeling of durability of polyelectrolyte membrane of O2/H2 fuel cell

    E-Print Network [OSTI]

    Atrazhev, Vadim V

    2014-01-01T23:59:59.000Z

    In this paper, we discuss critical aspects of the mechanisms and features of polymer proton exchange membrane (PEM) degradation in low-temperature H2/O2 fuel cell. In this paper, we focused on chemical mechanism of OH radical generation and their distribution in operational fuel cell. According to the current concept, free radicals are generated from hydrogen and oxygen crossover gases at the surface of Pt particles that precipitated in the membrane. We explicitly calculate Pt precipitation rate and electrochemical potential distribution in the membrane that controls it. Based on radical generation rate and Pt distribution we calculate degradation rate of the membrane taking advantage of simple kinetics equations.

  2. Heavy-duty H2-Diesel Dual Fuel Engines | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGridHYDROGEN TO THEHudsonTargetingduty H2-Diesel Dual Fuel

  3. Assessment of existing H2/O2 chemical reaction mechanisms at reheat gas turbine conditions

    E-Print Network [OSTI]

    Weydahl, Torleif; Seljeskog, Morten; Haugen, Nils Erland L

    2011-01-01T23:59:59.000Z

    This paper provides detailed comparisons of chemical reaction mechanisms of H2 applicable at high preheat temperatures and pressures relevant to gas turbine and particularly Alstom's reheat gas turbine conditions. It is shown that the available reaction mechanisms exhibit large differences in several important elementary reaction coefficients. The reaction mechanisms are assessed by comparing ignition delay and laminar flame speed results obtained from CHEMKIN with available data, however, the amount of data at these conditions is scarce and a recommended candidate among the mechanisms can presently not be selected. Generally, the results with the GRI-Mech and Leeds mechanisms deviate from the Davis, Li, O'Conaire, Konnov and San Diego mechanisms, but there are also significant deviations between the latter five mechanisms that altogether are better adapted to hydrogen. The differences in ignition delay times between the dedicated hydrogen mechanisms (O'Conaire, Li and Konnov) range from approximately a maxim...

  4. Bulk Hydrogen Strategic Directions for

    E-Print Network [OSTI]

    Economics Storage Performance Issues Market and Institutional Issues Storage Devices and Technologies-board) Develop new materials to address unique H2 leakage and Embrittlement Considerations Develop Smart Sensors Formations. #12;Breakout Session - Bulk Hydrogen Storage "Take home" messages Economics Cost of Storage vis

  5. Alkaline Biofiltration of H2S Odors A R M A N D O G O N Z A L E Z -S A N C H E Z , ,

    E-Print Network [OSTI]

    Alkaline Biofiltration of H2S Odors A R M A N D O G O N Z ´A L E Z - S ´A N C H E Z , , S E R G I. Accepted July 8, 2008. Hydrogen sulfide (H2S) is a very common odor nuisance which is best controlled by chemical or biological scrubbing. Under alkaline pH, the amount of H2S that can be solubilized

  6. BIOMASS FOR HYDROGEN AND OTHER TRANSPORT FUELS -POTENTIALS, LIMITATIONS & COSTS

    E-Print Network [OSTI]

    BIOMASS FOR HYDROGEN AND OTHER TRANSPORT FUELS - POTENTIALS, LIMITATIONS & COSTS Senior scientist - "Towards Hydrogen Society" ·biomass resources - potentials, limits ·biomass carbon cycle ·biomass for hydrogen - as compared to other H2- sources and to other biomass paths #12;BIOMASS - THE CARBON CYCLE

  7. AT A GLANCE Title: Hydrogen, Methane and Nitrous oxide: Trend

    E-Print Network [OSTI]

    Haak, Hein

    ) and nitrous oxide (N2O). The possible future transition to a `hydrogen economy' is expected to lead to a hydrogen economy will affect H2, CH4 and O3 6) Evaluate simulations with a coupled atmospheric chemistry. - The effects of a possible future transfer to a hydrogen economy and the associated reduction in fossil fuel

  8. The Role of H2 Molecules in Cosmological Structure Formation

    E-Print Network [OSTI]

    Tom Abel; Zoltan Haiman

    2000-02-08T23:59:59.000Z

    We review the relevance of H2 molecules for structure formation in cosmology. Molecules are important at high redshifts, when the first collapsed structures appear with typical temperatures of a few hundred Kelvin. In these chemically pristine clouds, radiative cooling is dominated H2 molecules. As a result, H2 ``astro-chemistry'' is likely to determine the epoch when the first astrophysical objects appear. We summarize results of recent three-dimensional simulations. A discussion of the effects of feedback, and implications for the reionization of the universe is also given.

  9. Water-Steel Canister Interaction and H2 Gas Pressure Buildup in aNuclear Waste Repository

    SciTech Connect (OSTI)

    Xu, Tianfu; Senger, Rainer; Finstele, Stefan

    2007-01-02T23:59:59.000Z

    Corrosion of steel canisters, stored in a repository forspent fuel and high-level waste, leads to hydrogen gas generation in thebackfilled emplacement tunnels, which may significantly affect long-termrepository safety. Previous modeling studies used a constant H2generation rate. However, iron corrosion and H2 generation rates varywith time, depending on factors such as water chemistry, wateravailability, and water contact area. To account for these factors andfeedback mechanisms, we developed a chemistry model related to ironcorrosion, coupled with two-phase (liquid and gas) flow phenomena thatare driven by gas pressure buildup and water consumption. Resultsindicate that if H2 generation rates are dynamically calculated based ona chemistry model, the degree and extent of gas pressure buildup are muchsmaller compared to a simulation in which the coupling between flow andreactive transport mechansism is neglected.

  10. Joint Meeting on Hydrogen Delivery Modeling and Analysis FreedomCAR and Fuels Partnership Hydrogen Delivery, Storage and

    E-Print Network [OSTI]

    . ­ The current capital costs for the hydrogen pipelines in the model are based on 1.1X the price of steel naturalJoint Meeting on Hydrogen Delivery Modeling and Analysis FreedomCAR and Fuels Partnership Hydrogen be prioritized) by mid-2008 H2A Delivery Model: Discussion Items, Comments, and Follow-up Actions 1. Pipeline

  11. Production of H2 at Fast Rates Using a Nickel Electrocatalyst in Water/Acetonitrile Solutions

    SciTech Connect (OSTI)

    Hoffert, Wesley A.; Roberts, John A.; Bullock, R. Morris; Helm, Monte L.

    2013-09-14T23:59:59.000Z

    Efficient production of molecular hydrogen for storage of energy from renewable sources is crucial for the development of wind and solar power. Hydrogenase enzymes in nature catalyze H2 production using earth-abundant metals (iron and nickel) using precise delivery of protons to the metal center. Here we report a synthetic nickel complex containing proton relays, [Ni(PPh2NC6H4OH2)2](BF4)2 (PPh2NC6H4OH2 = 1,5-bis(p-hydroxyphenyl)-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane), that catalyzes the production of H2 in an aqueous environment with turnover frequencies of 750-170,000 s-1 at directly measured overpotentials of 310-470 mV. The remarkable performance of this catalyst in aqueous environments exceeds the requirements necessary for molecular catalytic production of H2 by energy derived from photovoltaic solar cells. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

  12. Detroit Commuter Hydrogen Project

    SciTech Connect (OSTI)

    Brooks, Jerry; Prebo, Brendan

    2010-07-31T23:59:59.000Z

    This project was undertaken to demonstrate the viability of using hydrogen as a fuel in an internal combustion engine vehicle for use as a part of a mass transit system. The advantages of hydrogen as a fuel include renew-ability, minimal environmental impact on air quality and the environment, and potential to reduce dependence on foreign energy sources for the transportation sector. Recognizing the potential for the hydrogen fuel concept, the Southeast Michigan Congress of Governments (SEMCOG) determined to consider it in the study of a proposed regional mass transit rail system for southeast Michigan. SEMCOG wanted to evaluate the feasibility of using hydrogen fueled internal combustion engine (H2ICE) vehicles in shuttle buses to connect the Detroit Metro Airport to a proposed, nearby rail station. Shuttle buses are in current use on the airport for passenger parking and inter-terminal transport. This duty cycle is well suited to the application of hydrogen fuel at this time because of the ability to re-fuel vehicles at a single nearby facility, overcoming the challenge of restricted fuel availability in the undeveloped hydrogen fuel infrastructure. A cooperative agreement between SEMCOG and the DOE was initiated and two H2ICE buses were placed in regular passenger service on March 29, 2009 and operated for six months in regular passenger service. The buses were developed and built by the Ford Motor Company. Wayne County Airport Authority provided the location for the demonstration with the airport transportation contractor, Metro Cars Inc. operating the buses. The buses were built on Ford E450 chassis and incorporated a modified a 6.8L V-10 engine with specially designed supercharger, fuel rails and injectors among other sophisticated control systems. Up to 30 kg of on-board gaseous hydrogen were stored in a modular six tank, 350 bar (5000 psi) system to provide a 150 mile driving range. The bus chassis and body were configured to carry nine passengers with luggage. By collecting fuel use data for the two H2ICE buses, with both written driver logs and onboard telemetry devices, and for two conventional propane-gasoline powered buses in the same service, comparisons of operating efficiency and maintenance requirements were completed. Public opinion about the concept of hydrogen fuel was sampled with a rider survey throughout the demonstration. The demonstration was very effective in adding to the understanding of the application of hydrogen as a transportation fuel. The two 9 passenger H2ICE buses accumulated nearly 50,000 miles and carried 14,285 passengers. Data indicated the H2ICE bus fuel economy to be 9.4 miles/ gallon of gasoline equivalent (m/GGE) compared to the 10 passenger propane-gasoline bus average of 9.8 m/GGE over 32,400 miles. The 23- passenger bus averaged 7.4 m/GGE over 40,700 miles. Rider feedback from 1050 on-board survey cards was overwhelmingly positive with 99.6% indicating they would ride again on a hydrogen powered vehicle. Minimal maintenance was required for theses buses during the demonstration project, but a longer duration demonstration would be required to more adequately assess this aspect of the concept.

  13. Impact of Hydrogen Production onImpact of Hydrogen Production on U.S. Energy MarketsU.S. Energy Markets

    E-Print Network [OSTI]

    prices. · Evaluate impacts on U.S. energy markets including price and consumption changes for coal demands for hydrogen as a fuel, and impacts on feedstock price and supplies under alternative at ½ level of gasoline. H2IOSTE - H2IOSTE + H2 FCV assumed to be 3.0 times as efficient as gasoline ICE

  14. H2 Internal Combustion Engine Research Towards 45% efficiency...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Internal Combustion Engine Research Towards 45% efficiency and Tier2-Bin5 emissions H2 Internal Combustion Engine Research Towards 45% efficiency and Tier2-Bin5 emissions 2009 DOE...

  15. Quantum dynamics of CO-H$_2$ in full dimensionality

    E-Print Network [OSTI]

    Yang, Benhui; Wang, X; Stancil, P C; Bowman, J M; Balakrishnan, N; Forrey, R C

    2015-01-01T23:59:59.000Z

    Accurate rate coefficients for molecular vibrational transitions due to collisions with H$_2$, critical for interpreting infrared astronomical observations, are lacking for most molecules. Quantum calculations are the primary source of such data, but reliable values that consider all internal degrees of freedom of the collision complex have only been reported for H$_2$-H$_2$ due to the difficulty of the computations. Here we present essentially exact full-dimensional dynamics computations for rovibrational quenching of CO due to H$_2$ impact. Using a high-level six-dimensional potential surface, time-independent scattering calculations, within a full angular-momentum-coupling formulation, were performed for the deexcitation of vibrationally excited CO. Agreement with experimentally-determined results confirms the accuracy of the potential and scattering computations, representing the largest of such calculations performed to date. This investigation advances computational quantum dynamics studies representing...

  16. txH2O: Volume 3, Number 2 (Complete) 

    E-Print Network [OSTI]

    Texas Water Resources Institute

    2007-01-01T23:59:59.000Z

    H 2 Otx Fall 2007 A Publication of the Texas Water Resources Institute Texas Water Resources Institute | Texas Agricultural Experiment Station | Texas Cooperative Extension ?? ?? ?? ?? ?? ?? ?? In This Issue: MANAGING BACTERIA POLLUTION IN TEXAS... Kari Miller Assistant Editors Texas Water Resources Institute Visit our Web site at http://twri.tamu.edu for more information and to subscribe to tx H 2 O On the cover: Low-temperature electron micrograph of a cluster of E. coli bacteria. Each...

  17. Hydrogen Cryomagnetics

    E-Print Network [OSTI]

    Glowacki, B. A.; Hanely, E.; Nuttall, W. J.

    2014-01-01T23:59:59.000Z

    in our current approach. The liquefaction of hydrogen allows also for its use in transport applications for example BMW developed a car that utilises liquid hydrogen instead of compressed gas hydrogen making the use of cryogenic hydrogen even more... efficient. 11     Figure 13. Decentralised production of hydrogen pathways for Energy and Hydrogen Cryomagnetic solutions for a hospital environment. The shaded region in the figure represents the decentralised production of hydrogen using renewable...

  18. Examining hydrogen transitions.

    SciTech Connect (OSTI)

    Plotkin, S. E.; Energy Systems

    2007-03-01T23:59:59.000Z

    This report describes the results of an effort to identify key analytic issues associated with modeling a transition to hydrogen as a fuel for light duty vehicles, and using insights gained from this effort to suggest ways to improve ongoing modeling efforts. The study reported on here examined multiple hydrogen scenarios reported in the literature, identified modeling issues associated with those scenario analyses, and examined three DOE-sponsored hydrogen transition models in the context of those modeling issues. The three hydrogen transition models are HyTrans (contractor: Oak Ridge National Laboratory), MARKAL/DOE* (Brookhaven National Laboratory), and NEMS-H2 (OnLocation, Inc). The goals of these models are (1) to help DOE improve its R&D effort by identifying key technology and other roadblocks to a transition and testing its technical program goals to determine whether they are likely to lead to the market success of hydrogen technologies, (2) to evaluate alternative policies to promote a transition, and (3) to estimate the costs and benefits of alternative pathways to hydrogen development.

  19. Florida Hydrogen Initiative

    SciTech Connect (OSTI)

    Block, David L

    2013-06-30T23:59:59.000Z

    The Florida Hydrogen Initiative (FHI) was a research, development and demonstration hydrogen and fuel cell program. The FHI program objectives were to develop Florida?s hydrogen and fuel cell infrastructure and to assist DOE in its hydrogen and fuel cell activities The FHI program funded 12 RD&D projects as follows: Hydrogen Refueling Infrastructure and Rental Car Strategies -- L. Lines, Rollins College This project analyzes strategies for Florida's early stage adaptation of hydrogen-powered public transportation. In particular, the report investigates urban and statewide network of refueling stations and the feasibility of establishing a hydrogen rental-car fleet based in Orlando. Methanol Fuel Cell Vehicle Charging Station at Florida Atlantic University ? M. Fuchs, EnerFuel, Inc. The project objectives were to design, and demonstrate a 10 kWnet proton exchange membrane fuel cell stationary power plant operating on methanol, to achieve an electrical energy efficiency of 32% and to demonstrate transient response time of less than 3 milliseconds. Assessment of Public Understanding of the Hydrogen Economy Through Science Center Exhibits, J. Newman, Orlando Science Center The project objective was to design and build an interactive Science Center exhibit called: ?H2Now: the Great Hydrogen Xchange?. On-site Reformation of Diesel Fuel for Hydrogen Fueling Station Applications ? A. Raissi, Florida Solar Energy Center This project developed an on-demand forecourt hydrogen production technology by catalytically converting high-sulfur hydrocarbon fuels to an essentially sulfur-free gas. The removal of sulfur from reformate is critical since most catalysts used for the steam reformation have limited sulfur tolerance. Chemochromic Hydrogen Leak Detectors for Safety Monitoring ? N. Mohajeri and N. Muradov, Florida Solar Energy Center This project developed and demonstrated a cost-effective and highly selective chemochromic (visual) hydrogen leak detector for safety monitoring at any facility engaged in transport, handling and use of hydrogen. Development of High Efficiency Low Cost Electrocatalysts for Hydrogen Production and PEM Fuel Cell Applications ? M. Rodgers, Florida Solar Energy Center The objective of this project was to decrease platinum usage in fuel cells by conducting experiments to improve catalyst activity while lowering platinum loading through pulse electrodeposition. Optimum values of several variables during electrodeposition were selected to achieve the highest electrode performance, which was related to catalyst morphology. Understanding Mechanical and Chemical Durability of Fuel Cell Membrane Electrode Assemblies ? D. Slattery, Florida Solar Energy Center The objective of this project was to increase the knowledge base of the degradation mechanisms for membranes used in proton exchange membrane fuel cells. The results show the addition of ceria (cerium oxide) has given durability improvements by reducing fluoride emissions by an order of magnitude during an accelerated durability test. Production of Low-Cost Hydrogen from Biowaste (HyBrTec?) ? R. Parker, SRT Group, Inc., Miami, FL This project developed a hydrogen bromide (HyBrTec?) process which produces hydrogen bromide from wet-cellulosic waste and co-produces carbon dioxide. Eelectrolysis dissociates hydrogen bromide producing recyclable bromine and hydrogen. A demonstration reactor and electrolysis vessel was designed, built and operated. Development of a Low-Cost and High-Efficiency 500 W Portable PEMFC System ? J. Zheng, Florida State University, H. Chen, Bing Energy, Inc. The objectives of this project were to develop a new catalyst structures comprised of highly conductive buckypaper and Pt catalyst nanoparticles coated on its surface and to demonstrate fuel cell efficiency improvement and durability and cell cost reductions in the buckypaper based electrodes. Development of an Interdisciplinary Hydrogen and Fuel Cell Technology Academic Program ? J. Politano, Florida Institute of Technology, Melbourne, FL This project developed a hydrogen and fuel cel

  20. Ionic strength dependence of the oxidation of SO2 by H2O2 in sodium chloride particles

    SciTech Connect (OSTI)

    Ali, Hashim M.; Iedema, Martin J.; Yu, Xiao-Ying; Cowin, James P.

    2014-06-20T23:59:59.000Z

    The reaction of sulfur dioxide and hydrogen peroxide in the presence of deliquesced (>75% RH) sodium particles was studied by utilizing a crossflow-mini reactor. The reaction kinetics was followed by observing chloride depletion in particles by computer-controlled scanning electron microscope with energy dispersive X-ray analysis, namely SEM/EDX. The reactions take place in concentrated mixed salt brine aerosols, for which no complete kinetic equilibrium data previously existed. We measured the Henry’s law solubility of H2O2 to close that gap. We also calculated the reaction rate as the particle transforms continuously from concentrated NaCl brine to eventually a mixed NaHSO4 plus H2SO4 brine solution. The reaction rate of the SO2 oxidation by H2O2 was found to be influenced by the change in ionic strength as the particle undergoes compositional transformation, following closely the dependence of the third order rate constant on ionic strength as predicted rates using previously established rate equations. This is the first study that has measured the ionic strength dependence of sulfate formation (in non-aqueous media) from oxidation of mixed salt brine aerosols in the presence of H2O2. It also gives the first report of the Henry’s law constant of H2O2 dependence on ionic strength.

  1. Hydrogen Technology Research at SRNL

    SciTech Connect (OSTI)

    Danko, E.

    2011-02-13T23:59:59.000Z

    The Savannah River National Laboratory (SRNL) is a U.S. Department of Energy research and development laboratory located at the Savannah River Site (SRS) near Aiken, South Carolina. SRNL has over 50 years of experience in developing and applying hydrogen technology, both through its national defense activities as well as through its recent activities with the DOE Hydrogen Programs. The hydrogen technical staff at SRNL comprises over 90 scientists, engineers and technologists. SRNL has ongoing R&D initiatives in a variety of hydrogen storage areas, including metal hydrides, complex hydrides, chemical hydrides and carbon nanotubes. SRNL has over 25 years of experience in metal hydrides and solid-state hydrogen storage research, development and demonstration. As part of its defense mission at SRS, SRNL developed, designed, demonstrated and provides ongoing technical support for the largest hydrogen processing facility in the world based on the integrated use of metal hydrides for hydrogen storage, separation, and compression. The SRNL has been active in teaming with academic and industrial partners to advance hydrogen technology. A primary focus of SRNL's R&D has been hydrogen storage using metal and complex hydrides. SRNL and its Hydrogen Technology Research Laboratory have been very successful in leveraging their defense infrastructure, capabilities and investments to help solve this country's energy problems. SRNL has participated in projects to convert public transit and utility vehicles for operation using hydrogen fuel. Two major projects include the H2Fuel Bus and an Industrial Fuel Cell Vehicle (IFCV) also known as the GATOR{trademark}. Both of these projects were funded by DOE and cost shared by industry. These are discussed further in Section 3.0, Demonstration Projects. In addition to metal hydrides technology, the SRNL Hydrogen group has done extensive R&D in other hydrogen technologies, including membrane filters for H2 separation, doped carbon nanotubes, storage vessel design and optimization, chemical hydrides, hydrogen compressors and hydrogen production using nuclear energy. Several of these are discussed further in Section 2, SRNL Hydrogen Research and Development.

  2. HYDROGEN SULFIDE KINETICS ON PEM FUEL CELL ELECTRODES V. A. Sethuramana

    E-Print Network [OSTI]

    Sethuraman, Vijay A.

    for the poisoning kinetics of hydrogen sulfide (H2S) on composite solid polymer electrolyte Pt (SPE-Pt) electrode and theoretically by a model, which predicts the oxidation current as a function of the applied potential. H2S) fuel cells, there is much less in the literature on H2S poisoning. Uribe et al showed

  3. H_2D^+: a light on baryonic dark matter?

    E-Print Network [OSTI]

    Cecilia Ceccarelli; Carsten Dominik

    2006-02-27T23:59:59.000Z

    It has been suggested that the dark halos of galaxies are constituted by cloudlets of cold ( 10^7$ cm^{-3}) molecular gas. Such gas is extremely difficult to detect, because the classical tracers of molecular gas, CO and/or dust grains, have very low abundances and their emission is exceedingly weak. For this reason, the cloudlet hypothesis remains so far substantially unproven. In this Letter we propose a new method to probe the presence of cold H_2 clouds in galactic halos: the ground transition of ortho-H_2D^+ at 372 GHz. We discuss why the H_2D^+ is abundant under the physical conditions appropriate for the cloudlets, and present a chemical model that predicts the H_2D^+ abundance as function of four key parameters: gas density and metallicity, cosmic ray ionization rate and dust grain size. We conclude that current ground-based instruments might detect the ortho-H_2D^+ line emitted by the cloudlets halo, and prove, therefore, the existence of large quantities of dark baryonic matter around galaxies.

  4. CO diffusion into amorphous H2O ices

    E-Print Network [OSTI]

    Lauck, Trish; Shulenberger, Katherine; Rajappan, Mahesh; Oberg, Karin I; Cuppen, Herma M

    2015-01-01T23:59:59.000Z

    The mobility of atoms, molecules and radicals in icy grain mantles regulate ice restructuring, desorption, and chemistry in astrophysical environments. Interstellar ices are dominated by H2O, and diffusion on external and internal (pore) surfaces of H2O-rich ices is therefore a key process to constrain. This study aims to quantify the diffusion kinetics and barrier of the abundant ice constituent CO into H2O dominated ices at low temperatures (15-23 K), by measuring the mixing rate of initially layered H2O(:CO2)/CO ices. The mixed fraction of CO as a function of time is determined by monitoring the shape of the infrared CO stretching band. Mixing is observed at all investigated temperatures on minute time scales, and can be ascribed to CO diffusion in H2O ice pores. The diffusion coefficient and final mixed fraction depend on ice temperature, porosity, thickness and composition. The experiments are analyzed by applying Fick's diffusion equation under the assumption that mixing is due to CO diffusion into an i...

  5. H2 Internal Combustion Engine Research Towards 45% efficiency...

    Broader source: Energy.gov (indexed) [DOE]

    Funding in FY09: 500k Funding for FY10: 840k request Barriers Understand and optimize hydrogen direct injection engine operation Evaluate in-cylinder emissions reduction...

  6. WinDS-H2 Model and Analysis (Presentation)

    SciTech Connect (OSTI)

    Short, W.; Blair, N.; Heimiller, D.; Parks, K.

    2005-05-01T23:59:59.000Z

    A PowerPoint presentation given as part of the 2005 Hydrogen Program Review, May 23-26, 2005, in Washington, D.C.

  7. H2A Delivery Components Model and Analysis

    Broader source: Energy.gov (indexed) [DOE]

    forms Storage Components Delivery Components -Compressed Gas Tube System -Bulk Liquid Hydrogen System -Geologic -Forecourt -Truck - Tube Trailer -Truck - LH2 -Pipeline...

  8. Optimization of Direct-Injection H2 Combustion Engine Performance...

    Broader source: Energy.gov (indexed) [DOE]

    100 bar injection pressure Simulated turbocharging based on hydrogen PFI turbo results Operation limited due to peak cylinder pressure Only early DI possible...

  9. Optimization of Direct-Injection H2 Combustion Engine Performance...

    Broader source: Energy.gov (indexed) [DOE]

    Engine friction Values derived from measurement on multi-cylinder engine Turbo-charger performance Derived from results of turbo-charged multi-cylinder hydrogen...

  10. Optimization of Direct-Injection H2 Combustion Engine Performance...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation ace009wallner2011o.pdf More Documents & Publications Optimization...

  11. Calorimetric study of the heat effects induced by the fixation of hydrogen sulphide on the surface of modified activated carbon fibres

    E-Print Network [OSTI]

    Boyer, Edmond

    -Etienne, France, meljac@emse.fr ABSTRACT In order to improve their efficiency for the removal of H2S contained vapour, H2S is not simply physically adsorbed on the surface of the treated cloths but several reactions with a gas mixture of H2O and H2S. KEY-WORDS Calorimetry; activated carbon fibres; hydrogen sulphide

  12. Hydrogen sensor

    DOE Patents [OSTI]

    Duan, Yixiang (Los Alamos, NM); Jia, Quanxi (Los Alamos, NM); Cao, Wenqing (Katy, TX)

    2010-11-23T23:59:59.000Z

    A hydrogen sensor for detecting/quantitating hydrogen and hydrogen isotopes includes a sampling line and a microplasma generator that excites hydrogen from a gas sample and produces light emission from excited hydrogen. A power supply provides power to the microplasma generator, and a spectrometer generates an emission spectrum from the light emission. A programmable computer is adapted for determining whether or not the gas sample includes hydrogen, and for quantitating the amount of hydrogen and/or hydrogen isotopes are present in the gas sample.

  13. Hydrogen and electricity: Parallels, interactions,and convergence

    E-Print Network [OSTI]

    Yang, Christopher

    2008-01-01T23:59:59.000Z

    coal and natural gas-based H 2 production plants showing annual costcost of hydrogen) is less expensive than for a coal gasi?cation plant,plants and would lead to an increase in coal costs that

  14. Hydrogen and electricity: Parallels, interactions,and convergence

    E-Print Network [OSTI]

    Yang, Christopher

    2008-01-01T23:59:59.000Z

    a synthetic gas or ‘‘syngas’’, which can then be convertedand hydrogen. 4.2.1.1. Syngas-based co-production options.of a synthesis gas (‘‘syngas’’), which is a mixture of H 2 ,

  15. Successful Adoption of CNG and Energing CNG-Hydrogen Program...

    Broader source: Energy.gov (indexed) [DOE]

    Emerging CNG-H 2 Program in India US DOT and DOE Workshop Compressed Natural Gas and Hydrogen Fuels: Lesson Learned for the Safe Development of Vehicles Washington DC, December,...

  16. NREL Improves System Efficiency and Increases Energy Transfer with Wind2H2 Project, Enabling Reduced Cost Electrolysis Production (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2010-11-01T23:59:59.000Z

    This fact sheet describes NREL's accomplishments in improving energy transfer within a wind turbine-based hydrogen production system. Work was performed by the Wind2H2 Project team at the National Wind Technology Center in partnership with Xcel Energy.

  17. txH2O: Volume 5, Number 2 (Complete)

    E-Print Network [OSTI]

    Texas Water Resources Institute

    2009-01-01T23:59:59.000Z

    Supercinski Leslie Jordan Assistant Editors Texas Water Resources Institute Visit our Web site at http://twri.tamu.edu for more information and to subscribe to tx H2O On the cover: The Nueces River and Nueces Bay (pictured) is one of six priority... site at http://twri.tamu.edu for more information and to subscribe to tx H2O On the cover: The Nueces River and Nueces Bay (pictured) is one of six priority river basins for which a environmental flows regime will be established. Photo...

  18. Modeling H2 adsorption in carbon-based structures

    E-Print Network [OSTI]

    Lamonte, Kevin Anthony

    2009-05-15T23:59:59.000Z

    MODELING H2 ADSORPTION IN CARBON-BASED STRUCTURES A Thesis by KEVIN ANTHONY LAMONTE Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE May 2008 Major... Subject: Chemical Engineering MODELING H2 ADSORPTION IN CARBON-BASED STRUCTURES A Thesis by KEVIN ANTHONY LAMONTE Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER...

  19. The Modular Helium Reactor for Hydrogen Production

    SciTech Connect (OSTI)

    E. Harvego; M. Richards; A. Shenoy; K. Schultz; L. Brown; M. Fukuie

    2006-10-01T23:59:59.000Z

    For electricity and hydrogen production, an advanced reactor technology receiving considerable international interest is a modular, passively-safe version of the high-temperature, gas-cooled reactor (HTGR), known in the U.S. as the Modular Helium Reactor (MHR), which operates at a power level of 600 MW(t). For hydrogen production, the concept is referred to as the H2-MHR. Two concepts that make direct use of the MHR high-temperature process heat are being investigated in order to improve the efficiency and economics of hydrogen production. The first concept involves coupling the MHR to the Sulfur-Iodine (SI) thermochemical water splitting process and is referred to as the SI-Based H2-MHR. The second concept involves coupling the MHR to high-temperature electrolysis (HTE) and is referred to as the HTE-Based H2-MHR.

  20. Rotational quenching rate coefficients for H_2 in collisions with H_2 from 2 to 10,000 K

    E-Print Network [OSTI]

    T. -G. Lee; N. Balakrishnan; R. C. Forrey; P. C. Stancil; G. Shaw; D. R. Schultz; G. J. Ferland

    2008-05-12T23:59:59.000Z

    Rate coefficients for rotational transitions in H_2 induced by H_2 impact are presented. Extensive quantum mechanical coupled-channel calculations based on a recently published (H_2)_2 potential energy surface were performed. The potential energy surface used here is presumed to be more reliable than surfaces used in previous work. Rotational transition cross sections with initial levels J <= 8 were computed for collision energies ranging between 0.0001 and 2.5 eV, and the corresponding rate coefficients were calculated for the temperature range 2 < T <10,000 K. In general, agreement with earlier calculations, which were limited to 100-6000 K, is good though discrepancies are found at the lowest and highest temperatures. Low-density-limit cooling functions due to para- and ortho-H_2 collisions are obtained from the collisional rate coefficients. Implications of the new results for non-thermal H_2 rotational distributions in molecular regions are also investigated.

  1. First-Principles Prediction of Thermodynamically Reversible Hydrogen...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (into CaB6 and CaH2, and into CaB12H12 and CaH2) are found to have nearly equal free energies. We predict two new hydrogen storage reactions that are some of the most...

  2. Hydrogen-Assisted Fracture: Materials Testing and Variables Governing Fracture

    E-Print Network [OSTI]

    stainless steels ­ Cold-worked and annealed 316 stainless steel ­ Cold-worked and annealed SAF 2507 duplex-pressure hydrogen gas on materials · Design and maintenance of welded stainless steel pressure vessels for containment of high-pressure H2 isotopes ­ Extensive testing of stainless steels exposed to high-pressure H2

  3. Project Title: Advanced Thermal Hydrogen Compression Contractor: Ergenics, Inc.

    E-Print Network [OSTI]

    goals of: Long Term: $1.50/gallon of gasoline equivalent (2010) Near Term: $3.00/gallon of gasoline development. H2 Purity: Increase H2 quality to protect both fuel cell catalyst and advanced hydrogen storage a baseline for understanding impurity impact on advanced storage materials (alanates & carbon nanomaterials

  4. Wind-To-Hydrogen Project: Operational Experience, Performance Testing, and Systems Integration

    SciTech Connect (OSTI)

    Harrison, K. W.; Martin, G. D.; Ramsden, T. G.; Kramer, W. E.; Novachek, F. J.

    2009-03-01T23:59:59.000Z

    The Wind2H2 system is fully functional and continues to gather performance data. In this report, specifications of the Wind2H2 equipment (electrolyzers, compressor, hydrogen storage tanks, and the hydrogen fueled generator) are summarized. System operational experience and lessons learned are discussed. Valuable operational experience is shared through running, testing, daily operations, and troubleshooting the Wind2H2 system and equipment errors are being logged to help evaluate the reliability of the system.

  5. Optimized Pathways for Regional H2 Infrastructure Transitions: The Least-Cost Hydrogen for Southern California

    E-Print Network [OSTI]

    Lin, Zhenhong; Chen, Chien-Wei; Fan, Yueyue; Ogden, Joan M.

    2008-01-01T23:59:59.000Z

    ind. natural gas coal biomass Price 11.92 ¢/kWh 9.55 ¢/kWhprices (Table 2), which are assumed to be constant over time. For biomass,

  6. Hydrogen isotopic fractionation in lipid biosynthesis by H2-consuming Desulfobacterium autotrophicum

    E-Print Network [OSTI]

    Sessions, Alex L.

    @geol.ucsb.edu (D.L. Valentine). 1 Present address: Stantec Consulting Corporation, 446 Eisen- hower Lane North

  7. H2A Hydrogen Delivery Infrastructure Analysis Models and Conventional Pathway Options Analysis Results

    E-Print Network [OSTI]

    and Distribution Pipeline Pressures 2.1.7 .........................................................2-13 Gaseous Technology Venture, Gas Technology Institute, National Renewable Energy Laboratory, Pacific Northwest

  8. Optimized Pathways for Regional H2 Infrastructure Transitions: The Least-Cost Hydrogen for Southern California

    E-Print Network [OSTI]

    Lin, Zhenhong; Chen, Chien-Wei; Fan, Yueyue; Ogden, Joan M.

    2008-01-01T23:59:59.000Z

    CCS is not adopted, the transition sequence, dominated by coal gasification, provides positive but little CO2 mitigation potential.

  9. H2 Refuel H-Prize Aims to Make Fueling Hydrogen Powered Vehicles...

    Broader source: Energy.gov (indexed) [DOE]

    what about bringing other fuels to this market? Many gaseous fuels, including propane for your grill and compressed gases at paintball parties, are safe and popular, and...

  10. Reaction of formaldehyde cation with molecular hydrogen: Effects of collision energy and H2CO

    E-Print Network [OSTI]

    Anderson, Scott L.

    from 0.1 to 2.3 eV. Electronic structure and Rice­ Ramsperger­Kassel­Marcus calculations were usedV, consistent with a transition state found in the electronic structure calculations. A precursor complex on the reaction probabil- ity should provide insight into the barrier crossing dynamics. We are able to probe

  11. Optimized Pathways for Regional H2 Infrastructure Transitions: The Least-Cost Hydrogen for Southern California

    E-Print Network [OSTI]

    Lin, Zhenhong; Chen, Chien-Wei; Fan, Yueyue; Ogden, Joan M.

    2008-01-01T23:59:59.000Z

    production technologies including biomass gasification,coal gasification, natural gas reforming, and waterby biomass central gasification and then coal gasification

  12. Critical Updates to the Hydrogen Analysis Production Model (H2A...

    Broader source: Energy.gov (indexed) [DOE]

    of information. There are fuel prices that have been downloaded from the AEO (Annual Energy Outlook) website. There are fuel properties that were taken from the HyARC...

  13. Critical Updates to the Hydrogen Analysis Production Model (H2A v3) |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the YouTube platformBuildingCoalComplex(GC-72)Columbia Government |Energyl n t liA

  14. Critical Updates to the Hydrogen Analysis Production Model (H2A v3)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: Theof"Wave theJuly 30,Crafty Gifts for theof Energy 1:Department

  15. US DOE Hydrogen and Fuel Cell Technology - Composites in H2 Storage and Delivery

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA group current C3E Ambassadors and U.S.MANAGEMENTNotice forFederalof EnergyDOE

  16. JOBS Models: JOBS FC (Fuel Cells) and JOBS H2 (Hydrogen)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreaking ofOil & Gas » Methane HydrateEnergyIs a SmallJ. E.at13,Models JOBS

  17. H2 Refuel H-Prize Aims to Make Fueling Hydrogen Powered Vehicles Easier

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreaking of Blythe Solar Power Project Groundof|than Ever | Department of Energy

  18. Microbial Electrolysis Cells (MECs) for High Yield Hydrogen (H2) Production

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(FactDepartment3311, 3312), OctoberMayEnergyInstituteMicro3

  19. Webinar: Critical Updates to the Hydrogen Analysis Production Model (H2A

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: SinceDevelopment | Department ofPartnerships ToolkitWaste Heatv3) | Department of Energy

  20. H2 Educate! Hydrogen Education for Middle Schools | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGrid Integration0-1 MarchH-Tank Farm WasteEducate

  1. H2 and You: The Hydrogen Education Foundation's Outreach Program (Presentation)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGrid Integration0-1 MarchH-Tank FarmRefuel(Presentation)

  2. H2A Hydrogen Production Analysis Tool (Presentation) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGrid Integration0-1 MarchH-TankModels

  3. H2FIRST Hydrogen Contaminant Detector Task: Requirements Document and Market Survey

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGrid Integration0-1 MarchH-TankModelsMarket Survey

  4. Hydrogen Energy in Engineering Education (H2E3) | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGridHYDROGEND D e e& FuelInvitedinEnergy in Engineering

  5. National Energy Modeling System with Hydrogen Model (NEMS-H2)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreaking ofOilNEW HAMPSHIRE BUILDS OFFNanolens WindowDepartmentRFI |Energy

  6. Geochemistry and arsenic behaviour in groundwater resources of the Pannonian Basin (Hungary and Romania)

    E-Print Network [OSTI]

    Wehrli, Bernhard

    and Romania) Helen A.L. Rowland a,d, , Enoma O. Omoregie b , Romain Millot c , Cristina Jimenez d,e , Jasmin Faculty of Environmental Sciences, University of Babes-Bolyai, Cluj Napoca, Romania e Institute handling by R. Fuge a b s t r a c t Groundwater resources in the Pannonian Basin (Hungary, Romania, Croatia

  7. Radioactive Waste Management on Hungary at the Turn of the Millennium II

    SciTech Connect (OSTI)

    Temesi, A.; Pellet, S.; Fritz, A.

    2003-02-24T23:59:59.000Z

    The paper describes the challenging situation related to the radioactive waste management in Hungary. It is also discussing the legal and financial background and overviewing the developed strategy and the steps to be taken to find a reliable and safe disposal for L/ILW.

  8. Budapest, Hungary, 17-19 September 2007 Flexible Profile Approach to the Steady Conjugate

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    in heat transfer in which coupling between two heat transfer modes (convection and conduction) is observed undergoing forced convection, heat transfer boundary conditions are in reality never as ideal as those usedBudapest, Hungary, 17-19 September 2007 Flexible Profile Approach to the Steady Conjugate Heat

  9. Influences of Water Vapor on Cr(VI) Reduction by Gaseous Hydrogen

    E-Print Network [OSTI]

    Deng, Baolin

    Columbia, Columbia, Missouri 65211 In Situ Gaseous Reduction (ISGR) using hydrogen sulfide (H2S) is a technology the contaminants, H2S, and various soil components. In this study, Cr(VI) reduction by gaseous H2S was examined under various relative humidities (0-96.7%), concentrations of Cr(VI) (127-475 µg/g of solid), and H2S

  10. Doped H(2)-Filled RF Cavities for Muon Beam Cooling

    SciTech Connect (OSTI)

    Yonehara, K.; Chung, M.; Jansson, A.; Hu, M.; Moretti, A.; Popovic, M.; /Fermilab; Alsharo'a, M.; Johnson, R.P.; Neubauer, M.; Sah, R.; /Muons Inc., Batavia; Rose, D.V.; /Voss Sci., Albuquerque

    2009-05-01T23:59:59.000Z

    RF cavities pressurized with hydrogen gas may provide effective muon beam ionization cooling needed for muon colliders. Recent 805 MHz test cell studies reported below include the first use of SF{sub 6} dopant to reduce the effects of the electrons that will be produced by the ionization cooling process in hydrogen or helium. Measurements of maximum gradient in the Paschen region are compared to a simulation model for a 0.01% SF{sub 6} doping of hydrogen. The observed good agreement of the model with the measurements is a prerequisite to the investigation of other dopants.

  11. Using HyTrans to Study H2 Transition Scenarios | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Using HyTrans to Study H2 Transition Scenarios Using HyTrans to Study H2 Transition Scenarios Presentation on Using HyTrans to Study H2 Transition Scenarios given by David Greene...

  12. Code for Hydrogen Hydrogen Pipeline

    E-Print Network [OSTI]

    #12;2 Code for Hydrogen Pipelines Hydrogen Pipeline Working Group Workshop Augusta, Georgia August development · Charge from BPTCS to B31 Standards Committee for Hydrogen Piping/Pipeline code development · B31.12 Status & Structure · Hydrogen Pipeline issues · Research Needs · Where Do We Go From Here? #12;4 Code

  13. Effects of CO2 on H2O band profiles and band strengths in mixed H2O:CO2 ices

    E-Print Network [OSTI]

    Karin I. Oberg; Helen J. Fraser; A. C. Adwin Boogert; Suzanne E. Bisschop; Guido W. Fuchs; Ewine F. van Dishoeck; Harold Linnartz

    2006-10-25T23:59:59.000Z

    H2O is the most abundant component of astrophysical ices. In most lines of sight it is not possible to fit both the H2O 3 um stretching, the 6 um bending and the 13 um libration band intensities with a single pure H2O spectrum. Recent Spitzer observations have revealed CO2 ice in high abundances and it has been suggested that CO2 mixed into H2O ice can affect relative strengths of the 3 um and 6 um bands. We used laboratory infrared transmission spectroscopy of H2O:CO2 ice mixtures to investigate the effects of CO2 on H2O ice spectral features at 15-135 K. We find that the H2O peak profiles and band strengths are significantly different in H2O:CO2 ice mixtures compared to pure H2O ice. In all H2O:CO2 mixtures, a strong free-OH stretching band appears around 2.73 um, which can be used to put an upper limit on the CO2 concentration in the H2O ice. The H2O bending mode profile also changes drastically with CO2 concentration; the broad pure H2O band gives way to two narrow bands as the CO2 concentration is increased. This makes it crucial to constrain the environment of H2O ice to enable correct assignments of other species contributing to the interstellar 6 um absorption band. The amount of CO2 present in the H2O ice of B5:IRS1 is estimated by simultaneously comparing the H2O stretching and bending regions and the CO2 bending mode to laboratory spectra of H2O, CO2, H2O:CO2 and HCOOH.

  14. Final Technical Report for the Period September 2002 through September 2005; H2-MHR Pre-Conceptual Design Report: SI-Based Plant; H2-MHR Pre-Conceptual Design Report: HTE-Based Plant

    SciTech Connect (OSTI)

    M. Richards; A. Shenoy; L. Brown; R. Buckingham; E. Harvego; K. Peddicord; M. Reza; J. Coupey

    2006-04-19T23:59:59.000Z

    For electricity and hydrogen production, an advanced reactor technology receiving considerable international interest is a modular, passively-safe version of the high-temperature, gas-cooled reactor, known in the U.S. as the Modular Helium Reactor (MHR), which operates at a power level of 600 MW(t). For electricity production, the MHR operates with an outlet helium temperature of 850 C to drive a direct, Brayton-cycle power-conversion system with a thermal-to-electrical conversion efficiency of 48 percent. This concept is referred to as the Gas Turbine MHR (GT-MHR). For hydrogen production, both electricity and process heat from the MHR are used to produce hydrogen. This concept is referred to as the H2-MHR. This report provides pre-conceptual design descriptions of full-scale, nth-of-a-kind H2 MHR plants based on thermochemical water splitting using the Sulfur-Iodine process and High-Temperature Electrolysis.

  15. Liquid Hydrogen Delivery - Strategic Directions for Hydrogen...

    Broader source: Energy.gov (indexed) [DOE]

    Liquid Hydrogen Delivery - Strategic Directions for Hydrogen Delivery Workshop Liquid Hydrogen Delivery - Strategic Directions for Hydrogen Delivery Workshop Targets, barriers and...

  16. Proton ordering dynamics of H2O ice

    E-Print Network [OSTI]

    Yen, Fei

    2015-01-01T23:59:59.000Z

    From high precision measurements of the complex dielectric constant of H2O ice, we identify the critical temperatures of the phase transition into and out of ice XI from ice Ih to occur at T_Ih-IX=58.9 K and T_IX-Ih=73.4 K. For D2O, T_Ih-IX=63.7 K and T_IX-Ih=78.2 K. A triple point is identified to exist at 0.07 GPa and 73.4 K for H2O and 0.08 GPa and 78.2 K for D2O where ices Ih, II and XI coexist. A first order phase transition with kinetic broadening associated to proton ordering dynamics is identified at 100 K.

  17. Rotational quenching of CO due to H$_2$ collisions

    E-Print Network [OSTI]

    Yang, Benhui; Balakrishnan, N; Forrey, R C

    2010-01-01T23:59:59.000Z

    Rate coefficients for state-to-state rotational transitions in CO induced by both para- and ortho-H$_2$ collisions are presented. The results were obtained using the close-coupling method and the coupled-states approximation, with the CO-H$_2$ interaction potential of Jankowski & Szalewicz (2005). Rate coefficients are presented for temperatures between 1 and 3000 K, and for CO($v=0,j$) quenching from $j=1-40$ to all lower $j^\\prime$ levels. Comparisons with previous calculations using an earlier potential show some discrepancies, especially at low temperatures and for rotational transitions involving large $|\\Delta j|$. The differences in the well depths of the van der Waals interactions in the two potential surfaces lead to different resonance structures in the energy dependence of the cross sections which influence the low temperature rate coefficients. Applications to far infrared observations of astrophysical environments are briefly discussed.

  18. IX International Materials Research Congress: Cancun 2002 A Hybrid Multijunction Photoelectrode for Hydrogen ProductionA Hybrid Multijunction Photoelectrode for Hydrogen Production

    E-Print Network [OSTI]

    for Hydrogen ProductionA Hybrid Multijunction Photoelectrode for Hydrogen Production Fabricated with Amorphous light H2 O2 Good Hydrogen Efficiency Long Term Chemical Stability Low Cost Materials ­ SS substrates....Bandgap engineered TiO2? SOME CHOICES: Fe2O3 Selected for Initial Hybrid Photoelectrode Development #12;6IX IMRC

  19. txH2O: Volume 4, Number 2 (Complete)

    E-Print Network [OSTI]

    Texas Water Resources Institute

    2008-01-01T23:59:59.000Z

    Farmer Art Director AgriLife Communications & Marketing Danielle Supercinski Assistant Editor Texas Water Resources Institute Visit our web site at http://twri.tamu.edu for more information and to subscribe to tx H 2 O On the cover: The Rio Grande one... Texas Water Resources Institute Tammisha Farmer Art Director AgriLife Communications & Marketing Danielle Supercinski Assistant Editor Texas Water Resources Institute Visit our web site at http://twri.tamu.edu for more information and to subscribe to tx...

  20. txH2O: Volume 6, Number 1 (Complete)

    E-Print Network [OSTI]

    Texas Water Resources Institute

    2010-01-01T23:59:59.000Z

    , watershed coordinator and Extension program specialist, coordinate specific projects in the Lower Rio Grande Valley and the Pecos River Basin, respectively. The institute has established many partnerships that, in addition to the colleges, units... Parks and Wildlife Department (TPWD), U.S. Fish and Wildlife Service, Synergistic eradication Center?s First Project Tackles Invasive Plant at Treasured Lake txH2O | pg. 5 U.S. Army Corps of Engineers, NRCS, Cypress Valley Navigation District...

  1. Calabi-Yau threefolds with large h^{2, 1}

    E-Print Network [OSTI]

    Samuel B. Johnson; Washington Taylor

    2015-01-06T23:59:59.000Z

    We carry out a systematic analysis of Calabi-Yau threefolds that are elliptically fibered with section ("EFS") and have a large Hodge number h^{2, 1}. EFS Calabi-Yau threefolds live in a single connected space, with regions of moduli space associated with different topologies connected through transitions that can be understood in terms of singular Weierstrass models. We determine the complete set of such threefolds that have h^{2, 1} >= 350 by tuning coefficients in Weierstrass models over Hirzebruch surfaces. The resulting set of Hodge numbers includes those of all known Calabi-Yau threefolds with h^{2, 1} >= 350, as well as three apparently new Calabi-Yau threefolds. We speculate that there are no other Calabi-Yau threefolds (elliptically fibered or not) with Hodge numbers that exceed this bound. We summarize the theoretical and practical obstacles to a complete enumeration of all possible EFS Calabi-Yau threefolds and fourfolds, including those with small Hodge numbers, using this approach.

  2. Infrared Studies of Molecular Shocks in the Supernova Remnant HB21: I. Thermal Admixture of Shocked H_2 Gas in the North

    E-Print Network [OSTI]

    Jong-Ho Shinn; Bon-Chul Koo; Michael G. Burton; Ho-Gyu Lee; Dae-Sik Moon

    2008-12-10T23:59:59.000Z

    We present near- and mid-infrared observations on the shock-cloud interaction region in the northern part of the supernova remnant HB21, performed with the InfraRed Camera (IRC) aboard AKARI satellite and the Wide InfraRed Camera (WIRC) at the Palomar 5 m telescope. The IRC 7 um (S7), 11 um (S11), and 15 um (L15) band images and the WIRC H2 v = 1 -> 0 S(1) 2.12 um image show similar shock-cloud interaction features. We chose three representative regions, and analyzed their IRC emissions through comparison with H2 line emissions of several shock models. The IRC colors are well explained by the thermal admixture model of H2 gas--whose infinitesimal H2 column density has a power-law relation with the temperature T, dN ~ T^-b dT--with n(H2) ~ 10^3 cm^-3, b ~ 3, and N(H2 ;T > 100K) ~ 3x10^20 cm^-2. The derived b value may be understood by a bow shock picture, whose shape is cycloidal (cuspy) rather than paraboloidal. However, this picture raises another issue that the bow shocks must reside within ~0.01 pc size-scale, smaller than the theoretically expected. Instead, we conjectured a shocked clumpy interstellar medium picture, which may avoid the sizescale issue while explaining the similar model parameters. The observed H2 v = 1 -> 0 S(1) intensities are a factor of ~17 - 33 greater than the prediction from the power-law admixture model. This excess may be attributed to either an extra component of hot H2 gas or to the effects of collisions with hydrogen atoms, omitted in our power-law admixture model, both of which would increase the population in the v = 1 level of H2.

  3. Development of Molecular Electrocatalysts for CO2 Reduction and H2 Production/Oxidation

    SciTech Connect (OSTI)

    Rakowski DuBois, Mary; DuBois, Daniel L.

    2009-12-15T23:59:59.000Z

    The conversion of solar energy to fuels in both natural and artificial photosynthesis requires components for both light harvesting and catalysis. The light-harvesting component generates the electrochemical potentials required to drive fuel-generating reactions that would otherwise be thermodynamically uphill. This review focuses on work from our laboratories on developing molecular electrocatalysts for CO2 reduction and for hydrogen production. A true analog of natural photosynthesis will require the ability to capture CO2 from the atmosphere and reduce it to a useful fuel. Work in our laboratories has focused on both aspects of this problem. Organic compounds such as quinones and inorganic metal complexes can serve as redox active CO2 carriers for concentrating CO2. Catalysts for CO2 reduction to form CO have also been developed based on a [Pd(triphosphine)(solvent)]2+ platform. A required feature for catalytic activity is the presence of a weakly coordinating solvent molecule that can dissociate during the catalytic cycle and provide a vacant coordination site for binding water and assisting C-O bond cleavage. Participation of a second metal in CO2 binding also appears to be required for achieving very active catalysts as suggested by structures of [NiFe] CO dehydrogenase enzymes and the results of studies on complexes containing two [Pd(triphosphine)(solvent)]2+ units. Molecular electrocatalysts for H2 production and oxidation based on [Ni(diphosphine)2]2+ complexes are also described. These catalysts require the optimization of both first and second coordination spheres similar to that of the palladium CO2 reduction catalysts. In this case, structural features of the first coordination sphere can be used to optimize the hydride acceptor ability of nickel needed to achieve heterolytic cleavage of H2. The second coordination sphere can be used to incorporate pendant bases that assist in a number of important functions including H2 binding, H2 cleavage, and the transfer of protons between nickel and solution. These pendant bases or proton relays are likely to be important in the design of catalysts for a wide range of fuel production and fuel utilization reactions involving multiple electron and proton transfer steps. The work described in this review has been supported by the Chemical Sciences program of the Office of Basic Energy Sciences of the Department of Energy. The Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

  4. Optimization of electrode characteristics for the Br2/H2 redox flow cell

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tucker, Michael C.; Cho, Kyu Taek; Weber, Adam Z.; Lin, Guangyu; Nguyen, Trung V.

    2014-10-01T23:59:59.000Z

    The Br2/H2 redox flow cell shows promise as a high-power, low-cost energy storage device. The effect of various aspects of material selection, processing, and assembly of electrodes on the operation, performance, and efficiency of the system is determined. In particular, (+) electrode thickness, cell compression, hydrogen pressure, and (?) electrode architecture are investigated. Increasing hydrogen pressure and depositing the (?) catalyst layer on the membrane instead of on the carbon paper backing layers have a large positive impact on performance, enabling a limiting current density above 2 A cm?2 and a peak power density of 1.4 W cm?2. Maximum energymore »efficiency of 79 % is achieved. In addition, the root cause of limiting-current behavior in this system is elucidated, where it is found that Br? reversibly adsorbs at the Pt (?) electrode for potentials exceeding a critical value, and the extent of Br? coverage is potential-dependent. This phenomenon limits maximum cell current density and must be addressed in system modeling and design. These findings are expected to lower system cost and enable higher efficiency.« less

  5. Optimization of electrode characteristics for the Br2/H2 redox flow cell

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tucker, Michael C.; Cho, Kyu Taek; Weber, Adam Z.; Lin, Guangyu; Nguyen, Trung V.

    2014-10-01T23:59:59.000Z

    The Br2/H2 redox flow cell shows promise as a high-power, low-cost energy storage device. The effect of various aspects of material selection, processing, and assembly of electrodes on the operation, performance, and efficiency of the system is determined. In particular, (+) electrode thickness, cell compression, hydrogen pressure, and (?) electrode architecture are investigated. Increasing hydrogen pressure and depositing the (?) catalyst layer on the membrane instead of on the carbon paper backing layers have a large positive impact on performance, enabling a limiting current density above 2 A cm?2 and a peak power density of 1.4 W cm?2. Maximum energy efficiency of 79 % is achieved. In addition, the root cause of limiting-current behavior in this system is elucidated, where it is found that Br? reversibly adsorbs at the Pt (?) electrode for potentials exceeding a critical value, and the extent of Br? coverage is potential-dependent. This phenomenon limits maximum cell current density and must be addressed in system modeling and design. These findings are expected to lower system cost and enable higher efficiency.

  6. PVTx properties of the CO2H2O and CO2H2ONaCl systems below 647 K: Assessment of experimental data

    E-Print Network [OSTI]

    Polly, David

    PVTx properties of the CO2­H2O and CO2­H2O­NaCl systems below 647 K: Assessment of experimental-composition (PVTx) properties for the CO2­H2O and CO2­H2O­NaCl systems. This paper presents a comprehensive review. Keywords: CO2 sequestration; PVTx properties; Volume; Density; Thermodynamic modeling 1. Introduction CO2­H

  7. Wave Packet Simulations of Antiproton Scattering on Molecular Hydrogen

    E-Print Network [OSTI]

    Stegeby, Henrik; Piszczatowski, Konrad; Karlsson, Hans O

    2015-01-01T23:59:59.000Z

    The problem of antiproton scattering on the molecular Hydrogen is investigated by means of wave packet dynamics. The electronically potential energy surfaces of the antiproton H2 system are presented within this work. Excitation and dissociation probabilities of the molecular Hydrogen for collision energies in the ultra low energy regime below 10 eV are computed.

  8. Hydrogen Storage

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet provides a brief introduction to hydrogen storage technologies. Intended for a non-technical audience, it explains the different ways in which hydrogen can be stored, as well a

  9. Hydrogen Safety

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet, intended for a non-technical audience, explains the basic properties of hydrogen and provides an overview of issues related to the safe use of hydrogen as an energy carrier.

  10. Conversion of Steel Mill's Surface Waste into Zero Valent Iron (ZVI) Nanoparticles for Hydrogen Generation for PEMFCs

    E-Print Network [OSTI]

    Azad, Abdul-Majeed

    . The currently pursued modes of hydrogen generation include autothermal and/ or steam reforming of fossil fuels metal-steam reforming (MSR, 3M+4H2OM3O4+4H2). From the standpoint of favorable thermodynamics friendly method of generating high purity hydrogen is by the reaction of certain metals with steam, called

  11. Generation of DNA-Damaging Reactive Oxygen Species via the Autoxidation of Hydrogen Sulfide under Physiologically Relevant

    E-Print Network [OSTI]

    Gates, Kent. S.

    Generation of DNA-Damaging Reactive Oxygen Species via the Autoxidation of Hydrogen Sulfide under found that micromolar concentrations of H2S generated single-strand DNA cleavage. Mechanistic studies indicate that this process involved autoxidation of H2S to generate superoxide, hydrogen peroxide, and

  12. Complete Photo-Induced Breakup of the H2 Molecule as a Probe ofMolecular Electron Correlation

    SciTech Connect (OSTI)

    Vanroose, Wim; Martin, Fernando; Rescigno, Thomas N.; McCurdy, C.William

    2005-11-17T23:59:59.000Z

    Despite decades of progress in quantum mechanics, electron correlation effects are still only partially understood. Experiments in which both electrons are ejected from an oriented hydrogen molecule by absorption of a single photon have recently demonstrated a puzzling phenomenon: The ejection pattern of the electrons depends sensitively on the bond distance between the two nuclei as they vibrate in their ground state. Here we report a complete numerical solution of the Schrodinger equation for the double photoionization of H2. The results suggest that the distribution of photoelectrons emitted from aligned molecules reflects electron correlation effects that are purely molecular in origin.

  13. First principles study of H2S adsorption and dissociation D.E. Jiang a

    E-Print Network [OSTI]

    Carter, Emily A.

    First principles study of H2S adsorption and dissociation on Fe(110) D.E. Jiang a , Emily A. Carter functional theory (DFT) results of H2S and HS adsorption and dissociation on the Fe(110) surface. We investigate the site preference of H2S, HS, and S on Fe(110). H2S is found to weakly adsorb on either

  14. txH2O: Volume 4, Number 1 (Complete)

    E-Print Network [OSTI]

    Texas Water Resources Institute

    2008-01-01T23:59:59.000Z

    developed about on-site conditions before a well was drilled and installed can be downloaded. ? U. S. Geological Survey?s Groundwater Data for the Nation program http://waterdata.usgs.gov/nwis/gw A variety of groundwater data, including information... at NASA?s Goddard Space Flight Center, Greenbelt, MD, using data from three different Earth-observing satellite instruments. The presence of the Moon in this image is an artistic addition. Inside volume 4 number 1, Winter 2008 tx H 2 O...

  15. Fine structure transitions of C+ in collisions with H2

    E-Print Network [OSTI]

    Chu, Shih-I; Dalgarno, A.

    1975-01-01T23:59:59.000Z

    ://scitation.aip.org/content/aip/journal/jcp/62/10?ver=pdfcov Published by the AIP Publishing Articles you may be interested in ?doublet substate specific investigation of rotational and fine structure transitions in collisions of OH with H2 and D2 J. Chem. Phys. 95, 5763 (1991); 10... for Astrophysics, Harvard College Observatory and Smithsonian Astrophysical Observatory, Cambridge, Massachusetts 02138 (Received 7 November 1974) Close-coupling calculations are described of the cross sections for the fine-structure excitation of C...

  16. txH2O: Volume 6, Number 2 (Complete) 

    E-Print Network [OSTI]

    Texas Water Resources Institute

    2011-01-01T23:59:59.000Z

    drop in the bucket? Texas scientists on the real effects of the Deepwater Horizon oil spill 7 I Developing solutions for sustainable living?the Urban Living Laboratory The world?s largest ?living laboratory? for research on green living 10 I... 26 I Controlling invasive weed Center begins studying giant salvinia-eating weevils 28 I TWRI Briefs 2 tx H2O Winter 2011 Story by Leslie Lee Texas scientists on the real e#31;ects of the Deepwater Horizon oil spill Environmental disaster...

  17. txH2O: Volume 9, Number 1 (Complete)

    E-Print Network [OSTI]

    Wythe, Kathy

    2014-01-01T23:59:59.000Z

    , was integral in establishing the start of the EARIP project and served as the former program coordinator for EARIP. 10 txH2O Summer 2014 Story by Danielle Kalisek El Paso Water Utilities uses an infiltration or spreading basin to recharge the Hueco... needs. In the 2012 state water plan, accessing new sources of ground- water is projected to provide more than 800,000 acre-feet of water annually by 2060. With the growing water needs in the state and the continuing drought, many are predicting...

  18. txH2O: Volume 4, Number 3 (Complete) 

    E-Print Network [OSTI]

    Texas Water Resources Institute

    2008-01-01T23:59:59.000Z

    On the cover: The City of Kerrville stores excess water from the Guadalupe River in its Aquifer Storage and Recovery facility. Photo by Earl Nottingham, Texas Parks and Wildlife Department. C. Allan Jones Message from the Director Working to Make Every...Life. TWRI is funded in part by the U.S. Geological Survey and authorized by the Water Resources Research Act. To subscribe to tx H2O or New Waves, TWRI?s monthly e-mail newsletter, visit http://twri.tamu.edu. 2 I Saving for dry days Aquifer storage...

  19. H2 Storage Solutions Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, search OpenEI ReferenceJumpEnergyStrategy | Open Energy Sector: Hydro,H2 Storage

  20. H2Gen Innovations Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, search OpenEI ReferenceJumpEnergyStrategy | Open Energy Sector: Hydro,H2

  1. H2Go Solutions Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, search OpenEI ReferenceJumpEnergyStrategy | Open Energy Sector: Hydro,H2Solutions

  2. DOE H2A Analysis | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the YouTube| Department of Energy -StateOffshoreFuelCleanup10 AllDOE H2A Analysis DOE

  3. Panel 2, H2 Grid Integration: Tools and Analyses

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin of Contamination in235-1 Termoelectrica U.SPRESS FACTBiofuels1ofHanno Butsch | Head H 2

  4. H2 Safety Snapshot Newsletter | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreaking of Blythe Solar Power Project Groundof|than Ever | Department of1, Nov.H2

  5. H2FIRST Frequently Asked Questions | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onYouTube YouTube Note: Since the.pdfBreaking of Blythe Solar Power Project Groundof|than Ever | Department of1,H2FIRST

  6. H2 Safety Snapshot - Vol. 2, Issue 2, July 2011

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGrid Integration0-1 MarchH-Tank FarmRefuel H-PrizeH2

  7. H2A Delivery Models and Results | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGrid Integration0-1 MarchH-TankModels and Results H2A

  8. A Hydrogen Isotope of Mass 2 Before the publication of this definitive paper on the

    E-Print Network [OSTI]

    A Hydrogen Isotope of Mass 2 Before the publication of this definitive paper on the discovery of deuterium [1,2], the existence of a heavy isotope of hydrogen had been suspected even though Aston [3 at a hydrogen abundance ratio 1 H/2 H

  9. Hydrogen, Methane and Nitrous oxide Trend variability, budgets, and interactions with the biosphere

    E-Print Network [OSTI]

    Haak, Hein

    emission regulations on CH4 and N2 O, and future impacts of a transition to a `hydrogen economy', taking transition to a `hydrogen economy' in the coming de- cades is likely to cause a significant increaseCH4 H2 N2O ............ ........ Hymn Hydrogen, Methane and Nitrous oxide Trend variability

  10. Effects of Hydrogen Sulfide on the Performance of a PEMFC R. Mohtadi,a,

    E-Print Network [OSTI]

    Van Zee, John W.

    October 7, 2003. In a ``hydrogen challenged'' economy, the fuel for proton ex- change membrane fuel cellsEffects of Hydrogen Sulfide on the Performance of a PEMFC R. Mohtadi,a, * W.-k. Lee,a, ** S. Cowan-products, such as carbon monoxide, ammonia, and hydrogen sulfide. While it is well known that H2S severely poisons Pt

  11. Ris Energy Report 3 Hydrogen is a gas at ambient temperatures and pressures,

    E-Print Network [OSTI]

    be stored as a gas, a liquid or a solid. In the case of solid storage, the hydrogen exists as a chemical. Compared to fossil fuels such as gasoline, hydrogen has a very obvious shortfall in the amount of energy.5% hydrogen by weight or 62 kg H2/m3 and several storage techniques are able to meet these requirements

  12. Hydrogen Storage Technologies Hydrogen Delivery

    E-Print Network [OSTI]

    Hydrogen Storage Technologies Roadmap Hydrogen Delivery Technical Team Roadmap June 2013 #12;This). The Hydrogen Delivery Technical Team is one of 12 U.S. DRIVE technical teams ("tech teams") whose mission and clean advanced lightduty vehicles, as well as related energy infrastructure. For more information about

  13. Amineborane Based Chemical Hydrogen Storage - Final Report

    SciTech Connect (OSTI)

    Sneddon, Larry G.

    2011-04-21T23:59:59.000Z

    The development of efficient and safe methods for hydrogen storage is a major hurdle that must be overcome to enable the use of hydrogen as an alternative energy carrier. The objectives of this project in the DOE Center of Excellence in Chemical Hydride Storage were both to develop new methods for on-demand, low temperature hydrogen release from chemical hydrides and to design high-conversion off-board methods for chemical hydride regeneration. Because of their reactive protic (N-H) and hydridic (B-H) hydrogens and high hydrogen contents, amineboranes such as ammonia borane, NH3BH3 (AB), 19.6-wt% H2, and ammonia triborane NH3B3H7 (AT), 17.7-wt% H2, were initially identified by the Center as promising, high-capacity chemical hydrogen storage materials with the potential to store and deliver molecular hydrogen through dehydrogenation and hydrolysis reactions. In collaboration with other Center partners, the Penn project focused both on new methods to induce amineborane H2-release and on new strategies for the regeneration the amineborane spent-fuel materials. The Penn approach to improving amineborane H2-release focused on the use of ionic liquids, base additives and metal catalysts to activate AB dehydrogenation and these studies successfully demonstrated that in ionic liquids the AB induction period that had been observed in the solid-state was eliminated and both the rate and extent of AB H2-release were significantly increased. These results have clearly shown that, while improvements are still necessary, many of these systems have the potential to achieve DOE hydrogen-storage goals. The high extent of their H2­-release, the tunability of both their H2 materials weight-percents and release rates, and their product control that is attained by either trapping or suppressing unwanted volatile side products, such as borazine, continue to make AB/ionic­-liquid based systems attractive candidates for chemical hydrogen storage applications. These studies also demonstrated that H2-­release from chemical hydrides can occur by a number of different mechanistic pathways and strongly suggest that optimal chemical ­hydride based H2­release systems may require the use of synergistic dehydrogenation methods to induce H2­-loss from chemically different intermediates formed during release reactions. The efficient regeneration of ammonia borane from BNHx spent fuel is one of the most challenging problems that will have to be overcome in order to utilize AB-based hydrogen storage. Three Center partners, LANL, PNNL and Penn, each took different complimentary approaches to AB regeneration. The Penn approach focused on a strategy involving spent-fuel digestion with superacidic acids to produce boron-halides (BX3) that could then be converted to AB by coordination/reduction/displacement processes. While the Penn boron-halide reduction studies successfully demonstrated that a dialkylsulfide-based coordination/reduction/displacement process gave quantitative conversions of BBr3 to ammonia borane with efficient and safe product separations, the fact that AB spent-fuels could not be digested in good yields to BX3 halides led to a No-Go decision on this overall AB-regeneration strategy.

  14. Modeling Studies on the Transport of Benzene and H2S in CO2-Water Systems

    E-Print Network [OSTI]

    Zheng, L.

    2011-01-01T23:59:59.000Z

    Germann, 1969. Physical properties of hydrogen sulfide waterequilibrium properties of system carbon dioxide-hydrogenA thermodynamic property model for fluid phase hydrogen

  15. Optimized Pathways for Regional H2 Infrastructure Transitions: A Case Study for Southern California

    E-Print Network [OSTI]

    Lin, Zhenhong; Fan, Yueyue; Ogden, Joan M; Chen, Chien-Wei

    2008-01-01T23:59:59.000Z

    P. Rutter, et al. Hydrogen infrastructure strategic planningModelling of Hydrogen infrastructure for vehicle refuellingof building up a hydrogen infrastructure in Southern

  16. Proton ordering in tetragonal and monoclinic H2O ice

    E-Print Network [OSTI]

    Yen, Fei; Berlie, Adam; Liu, Xiaodi; Goncharov, Alexander F

    2015-01-01T23:59:59.000Z

    H2O ice remains one of the most enigmatic materials as its phase diagram reveals up to sixteen solid phases. While the crystal structure of these phases has been determined, the phase boundaries and mechanisms of formation of the proton-ordered phases remain unclear. From high precision measurements of the complex dielectric constant, we probe directly the degree of ordering of the protons in H2O tetragonal ice III and monoclinic ice V down to 80 K. A broadened first-order phase transition is found to occur near 202 K we attribute to a quenched disorder of the protons which causes a continuous disordering of the protons during cooling and metastable behavior. At 126 K the protons in ice III become fully ordered, and for the case of ice V becoming fully ordered at 113 K forming ice XIII. Two triple points are proposed to exist: one at 0.35 GPa and 126 K where ices III, IX and V coexist; and another at 0.35 GPa and 113 K where ices V, IX and XIII coexist. Our findings unravel the underlying mechanism driving th...

  17. Sulfur depletion in dense clouds and circumstellar regions I. H2S ice abundance and UV-photochemical reactions in the H2O-matrix

    E-Print Network [OSTI]

    Jiménez-Escobar, A

    2011-01-01T23:59:59.000Z

    This work aims to study the unexplained sulfur depletion observed toward dense clouds and protostars. We made simulation experiments of the UV-photoprocessing and sublimation of H2S and H2S:H2O ice in dense clouds and circumstellar regions, using the Interstellar Astrochemistry Chamber (ISAC), a state-of-the-art ultra-high-vacuum setup. The ice was monitored in situ by mid-infrared spectroscopy in transmittance. Temperature-programmed desorption (TPD) of the ice was performed using a quadrupole mass spectrometer (QMS) to detect the volatiles desorbing from the ice. Comparing our laboratory data to infrared observations of protostars we obtained a more accurate upper limit of the abundance of H2S ice toward these objects. We determined the desorption temperature of H2S ice, which depends on the initial H2S:H2O ratio. UV-photoprocessing of H2S:H2O ice led to the formation of several species. Among them, H2S2 was found to photodissociate forming S2 and, by elongation, other species up to S8, which are refractory...

  18. Sandia National Laboratories: Hydrogen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in Materials & Components Compatibility Hydrogen Behavior Quantitative Risk Assessment Hydrogen Infrastructure Solar Thermochemical Hydrogen Production Market Transformation...

  19. 3D CFD Model of High Temperature H2O/CO2 Co-electrolysis

    SciTech Connect (OSTI)

    Grant Hawkes; James O'Brien; Carl Stoots; Stephen Herring; Joe Hartvigsen

    2007-06-01T23:59:59.000Z

    3D CFD Model of High Temperature H2O/CO2 Co-Electrolysis Grant Hawkes1, James O’Brien1, Carl Stoots1, Stephen Herring1 Joe Hartvigsen2 1 Idaho National Laboratory, Idaho Falls, Idaho, grant.hawkes@inl.gov 2 Ceramatec Inc, Salt Lake City, Utah INTRODUCTION A three-dimensional computational fluid dynamics (CFD) model has been created to model high temperature co-electrolysis of steam and carbon dioxide in a planar solid oxide electrolyzer (SOE) using solid oxide fuel cell technology. A research program is under way at the Idaho National Laboratory (INL) to simultaneously address the research and scale-up issues associated with the implementation of planar solid-oxide electrolysis cell technology for syn-gas production from CO2 and steam. Various runs have been performed under different run conditions to help assess the performance of the SOE. This paper presents CFD results of this model compared with experimental results. The Idaho National Laboratory (INL), in conjunction with Ceramatec Inc. (Salt Lake City, USA) has been researching for several years the use of solid-oxide fuel cell technology to electrolyze steam for large-scale nuclear-powered hydrogen production. Now, an experimental research project is underway at the INL to produce syngas by simultaneously electrolyzing at high-temperature steam and carbon dioxide (CO2) using solid oxide fuel cell technology. A strong interest exists in the large-scale production of syn-gas from CO2 and steam to be reformed into a usable transportation fuel. If biomass is used as the carbon source, the overall process is climate neutral. Consequently, there is a high level of interest in production of syn-gas from CO2 and steam electrolysis. With the price of oil currently around $60 / barrel, synthetically-derived hydrocarbon fuels (synfuels) have become economical. Synfuels are typically produced from syngas – hydrogen (H2) and carbon monoxide (CO) -- using the Fischer-Tropsch process, discovered by Germany before World War II. High-temperature nuclear reactors have the potential for substantially increasing the efficiency of syn-gas production from CO2 and water, with no consumption of fossil fuels, and no production of greenhouse gases. Thermal CO2-splitting and water splitting for syn-gas production can be accomplished via high-temperature electrolysis, using high-temperature nuclear process heat and electricity. A high-temperature advanced nuclear reactor coupled with a high-efficiency high-temperature electrolyzer could achieve a competitive thermal-to-syn-gas conversion efficiency of 45 to 55%.

  20. HYDROGEN TECHNOLOGY RESEARCH AT THE SAVANNAH RIVER NATIONAL LABORATORY, CENTER FOR HYDROGEN RESEARCH, AND THE HYDROGEN TECHNOLOGY RESEARCH LABORATORY

    SciTech Connect (OSTI)

    Danko, E

    2007-02-26T23:59:59.000Z

    The Savannah River National Laboratory (SRNL) is a U.S. Department of Energy research and development laboratory located at the Savannah River Site (SRS) near Aiken, South Carolina. SRNL has over 50 years of experience in developing and applying hydrogen technology, both through its national defense activities as well as through its recent activities with the DOE Hydrogen Programs. The hydrogen technical staff at SRNL comprises over 90 scientists, engineers and technologists, and it is believed to be the largest such staff in the U.S. SRNL has ongoing R&D initiatives in a variety of hydrogen storage areas, including metal hydrides, complex hydrides, chemical hydrides and carbon nanotubes. SRNL has over 25 years of experience in metal hydrides and solid-state hydrogen storage research, development and demonstration. As part of its defense mission at SRS, SRNL developed, designed, demonstrated and provides ongoing technical support for the largest hydrogen processing facility in the world based on the integrated use of metal hydrides for hydrogen storage, separation and compression. The SRNL has been active in teaming with academic and industrial partners to advance hydrogen technology. A primary focus of SRNL's R&D has been hydrogen storage using metal and complex hydrides. SRNL and its Hydrogen Technology Laboratory have been very successful in leveraging their defense infrastructure, capabilities and investments to help solve this country's energy problems. Many of SRNL's programs support dual-use applications. SRNL has participated in projects to convert public transit and utility vehicles for operation on hydrogen fuel. Two major projects include the H2Fuel Bus and an Industrial Fuel Cell Vehicle (IFCV) also known as the GATOR{trademark}. Both of these projects were funded by DOE and cost shared by industry. These are discussed further in Section 3.0, Demonstration Projects. In addition to metal hydrides technology, the SRNL Hydrogen group has done extensive R&D in other hydrogen technologies, including membrane filters for H2 separation, doped carbon nanotubes, storage vessel design and optimization, chemical hydrides, hydrogen compressors and hydrogen production using nuclear energy. Several of these are discussed further in Section 2, SRNL Hydrogen Research and Development.

  1. SAVANNAH RIVER NATIONAL LABORATORY HYDROGEN TECHNOLOGY RESEARCH

    SciTech Connect (OSTI)

    Danko, E

    2008-02-08T23:59:59.000Z

    The Savannah River National Laboratory (SRNL) is a U.S. Department of Energy research and development laboratory located at the Savannah River Site (SRS) near Aiken, South Carolina. SRNL has over 50 years of experience in developing and applying hydrogen technology, both through its national defense activities as well as through its recent activities with the DOE Hydrogen Programs. The hydrogen technical staff at SRNL comprises over 90 scientists, engineers and technologists, and it is believed to be the largest such staff in the U.S. SRNL has ongoing R&D initiatives in a variety of hydrogen storage areas, including metal hydrides, complex hydrides, chemical hydrides and carbon nanotubes. SRNL has over 25 years of experience in metal hydrides and solid-state hydrogen storage research, development and demonstration. As part of its defense mission at SRS, SRNL developed, designed, demonstrated and provides ongoing technical support for the largest hydrogen processing facility in the world based on the integrated use of metal hydrides for hydrogen storage, separation, and compression. The SRNL has been active in teaming with academic and industrial partners to advance hydrogen technology. A primary focus of SRNL's R&D has been hydrogen storage using metal and complex hydrides. SRNL and its Hydrogen Technology Research Laboratory have been very successful in leveraging their defense infrastructure, capabilities and investments to help solve this country's energy problems. SRNL has participated in projects to convert public transit and utility vehicles for operation using hydrogen fuel. Two major projects include the H2Fuel Bus and an Industrial Fuel Cell Vehicle (IFCV) also known as the GATOR{trademark}. Both of these projects were funded by DOE and cost shared by industry. These are discussed further in Section 3.0, Demonstration Projects. In addition to metal hydrides technology, the SRNL Hydrogen group has done extensive R&D in other hydrogen technologies, including membrane filters for H2 separation, doped carbon nanotubes, storage vessel design and optimization, chemical hydrides, hydrogen compressors and hydrogen production using nuclear energy. Several of these are discussed further in Section 2, SRNL Hydrogen Research and Development.

  2. A THEORETICAL INVESTIGATION OF RADIOLYTIC H2 GENERATION FROM SOLIDS

    SciTech Connect (OSTI)

    Westbrook, M.; Sindelar, R.; Fisher, D.

    2012-02-01T23:59:59.000Z

    Hydrogen generation from materials in nuclear materials storage is of critical interest due to the potential for pressurization and/or flammability issues. Studies have focused on aqueous systems or those with minor amounts of physisorbed water, since conventional knowledge identifies the radiolytic decomposition of water as the source of H{sub 2} gas. Furthermore, the approach to characterize gas generation is typically strictly empirical, relying on determination of G-values from which production in systems is estimated. Interestingly, exploratory work at SRNL1 on gamma exposure to fully-dried solids with chemically-bound water that are typical of those produced on aluminium-clad nuclear fuel in reactor and post-discharge storage has shown a profound production of hydrogen (as the sole gaseous species) from fully dried boehmite ({gamma}-AlOOH or Al{sub 2}O{sub 3} {center_dot} H{sub 2}O) powders and no observable hydrogen from gibbsite ({gamma}-Al(OH){sub 3} or Al{sub 2}O{sub 3} {center_dot} 3H{sub 2}O) under gamma irradiation from cobalt-60. This observation is significant in that gibbsite is known to thermally decompose at 80 C whereas boehmite is stable to 400 C. Radiation damage can have various effects on solids, including heating, bond breaking, and rearrangements in the bonding structure. For example, a molecule can be ionized resulting in the generation of free electrons which can, in turn, ionize another molecule. Alternately, reactive radical species such as {lg_bullet}OH or cation species may be formed, which can go on to change bonding structures.

  3. High Temperature Fuel Cell Tri-Generation of Power, Heat & H2...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Temperature Fuel Cell Tri-Generation of Power, Heat & H2 from Biogas High Temperature Fuel Cell Tri-Generation of Power, Heat & H2 from Biogas Success story about using waste water...

  4. DOE Fuel Cell Technologies Office Record 13013: H2 Delivery Cost...

    Office of Environmental Management (EM)

    3013: H2 Delivery Cost Projections - 2013 DOE Fuel Cell Technologies Office Record 13013: H2 Delivery Cost Projections - 2013 This program record from the U.S. Department of...

  5. The Role of a Dipeptide Outer-Coordination Sphere on H2 -Production...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dipeptide Outer-Coordination Sphere on H2 -Production Catalysts: Influence on Catalytic Rates and Electron The Role of a Dipeptide Outer-Coordination Sphere on H2 -Production...

  6. Structure and Dynamics of Forsterite-scCO2/H2O Interfaces as...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Forsterite-scCO2H2O Interfaces as a Function of Water Content. Structure and Dynamics of Forsterite-scCO2H2O Interfaces as a Function of Water Content. Abstract: Molecular...

  7. HCI Adsorption and Ionization on Amorphous and Crystalline H2O...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    HCI Adsorption and Ionization on Amorphous and Crystalline H2O Films below 50 K. HCI Adsorption and Ionization on Amorphous and Crystalline H2O Films below 50 K. Abstract:...

  8. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Applications: 2008 Update Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for...

  9. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    for Direct H2 PEM Fuel Cell Systems for Automotive Application: 2009 Update Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Application: 2009...

  10. Mass Production Cost Estimation of Direct H2 PEM Fuel Cell Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mass Production Cost Estimation of Direct H2 PEM Fuel Cell Systems for Transportation Applications: 2013 Update Mass Production Cost Estimation of Direct H2 PEM Fuel Cell Systems...

  11. Crystallization Kinetics and Excess Free Energy of H2O and D2O...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Crystallization Kinetics and Excess Free Energy of H2O and D2O Nanoscale Films of Amorphous Solid Water. Crystallization Kinetics and Excess Free Energy of H2O and D2O Nanoscale...

  12. H2O and Cation Structure and Dynamics in Expandable Clays: 2H...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    H2O and Cation Structure and Dynamics in Expandable Clays: 2H and 39K NMR Investigations of Hectorite. H2O and Cation Structure and Dynamics in Expandable Clays: 2H and 39K NMR...

  13. The Molecular Hydrogen Deficit in Gamma-Ray Burst Afterglows

    E-Print Network [OSTI]

    Daniel Whalen; Jason X. Prochaska; Alexander Heger; Jason Tumlinson

    2008-04-15T23:59:59.000Z

    Recent analysis of five gamma-ray burst (GRB) afterglow spectra reveal the absence of molecular hydrogen absorption lines, a surprising result in light of their large neutral hydrogen column densities and the detection of H$_2$ in similar, more local star-forming regions like 30 Doradus in the Large Magellanic Cloud (LMC). Observational evidence further indicates that the bulk of the neutral hydrogen column in these sight lines lies 100 pc beyond the progenitor and that H$_2$ was absent prior to the burst, suggesting that direct flux from the star, FUV background fields, or both suppressed its formation. We present one-dimensional radiation hydrodynamical models of GRB host galaxy environments, including self-consistent radiative transfer of both ionizing and Lyman-Werner photons, nine-species primordial chemistry with dust formation of H$_2$, and dust extinction of UV photons. We find that a single GRB progenitor is sufficient to ionize neutral hydrogen to distances of 50 - 100 pc but that a galactic Lyman-Werner background is required to dissociate the molecular hydrogen in the ambient ISM. Intensities of 0.1 - 100 times the Galactic mean are necessary to destroy H$_2$ in the cloud, depending on its density and metallicity. The minimum radii at which neutral hydrogen will be found in afterglow spectra is insensitive to the mass of the progenitor or the initial mass function (IMF) of its cluster, if present.

  14. Solar-thermal Water Splitting Using the Sodium Manganese Oxide Process & Preliminary H2A Analysis

    SciTech Connect (OSTI)

    Todd M. Francis, Paul R. Lichty, Christopher Perkins, Melinda Tucker, Peter B. Kreider, Hans H. Funke, Allan Lewandowski, and Alan W. Weimer

    2012-10-24T23:59:59.000Z

    There are three primary reactions in the sodium manganese oxide high temperature water splitting cycle. In the first reaction, Mn2O3 is decomposed to MnO at 1,500°C and 50 psig. This reaction occurs in a high temperature solar reactor and has a heat of reaction of 173,212 J/mol. Hydrogen is produced in the next step of this cycle. This step occurs at 700°C and 1 atm in the presence of sodium hydroxide. Finally, water is added in the hydrolysis step, which removes NaOH and regenerates the original reactant, Mn2O3. The high temperature solar�driven step for decomposing Mn2O3 to MnO can be carried out to high conversion without major complication in an inert environment. The second step to produce H2 in the presence of sodium hydroxide is also straightforward and can be completed. The third step, the low temperature step to recover the sodium hydroxide is the most difficult. The amount of energy required to essentially distill water to recover sodium hydroxide is prohibitive and too costly. Methods must be found for lower cost recovery. This report provides information on the use of ZnO as an additive to improve the recovery of sodium hydroxide.

  15. Knock behavior of a lean-burn hydrogen-enhanced engine concept

    E-Print Network [OSTI]

    Topinka, Jennifer A. (Jennifer Ann), 1977-

    2003-01-01T23:59:59.000Z

    Experiments to identify the knock trends of lean gasoline-air mixtures, and such mixtures enhanced with hydrogen (H2) and carbon monoxide (CO), were performed on a single-cylinder research engine with boosting capability. ...

  16. Hydrogen Bond Rearrangements in Water Probed with Temperature-Dependent 2D IR

    E-Print Network [OSTI]

    Nicodemus, Rebecca A.

    We use temperature-dependent two-dimensional infrared spectroscopy (2D IR) of dilute HOD in H2O to investigate hydrogen bond rearrangements in water. The OD stretching frequency is sensitive to its environment, and loss ...

  17. Electrochemical hydrogenation of aromatic compounds chemisorbed at polycrystalline and single-crystal Pd surfaces

    E-Print Network [OSTI]

    Sanabria-Chinchilla, Jean

    2009-06-02T23:59:59.000Z

    The chemisorption and electrochemical hydrogenation of hydroquinone (H2Q) at polycrystalline (pc) Pd, well-ordered Pd(100), and Pd-modified Au(hkl) electrodes were studied using a combination of ultra-high vacuum (UHV) surface spectroscopy...

  18. Collective Hydrogen Bond Reorganization in Water Studied with Temperature-Dependent Ultrafast Infrared Spectroscopy

    E-Print Network [OSTI]

    Nicodemus, Rebecca A.

    We use temperature-dependent ultrafast infrared spectroscopy of dilute HOD in H2O to study the picosecond reorganization of the hydrogen bond network of liquid water. Temperature-dependent two-dimensional infrared (2D IR), ...

  19. H2S Induces a Suspended AnimationLike State in Mice

    E-Print Network [OSTI]

    Storey, Kenneth B.

    H2S Induces a Suspended Animation­Like State in Mice Eric Blackstone,1,2 Mike Morrison,2 Mark B sulfide (H2S) is a specific, potent, and reversible inhibitor of complex IV (cytochrome c oxidase and CBT in mammals. When mice were exposed to 80 ppm of H2S, their oxygen (O2) consumption dropped by È50

  20. Chemical Engineering Journal 113 (2005) 119126 Understanding the limits of H2S degrading biotrickling filters

    E-Print Network [OSTI]

    2005-01-01T23:59:59.000Z

    Chemical Engineering Journal 113 (2005) 119­126 Understanding the limits of H2S degrading January 2005; received in revised form 29 April 2005; accepted 1 May 2005 Abstract The removal of H2S-controlled performance above 4000 m h-1 . The effect of the liquid trickling rate on H2S elimination was found to be nil

  1. H2S adsorption on chromium, chromia, and gold/chromia surfaces: Photoemission studies

    E-Print Network [OSTI]

    Diebold, Ulrike

    H2S adsorption on chromium, chromia, and gold/chromia surfaces: Photoemission studies J. A, New Orleans, Louisiana 70148 Received 10 June 1997; accepted 26 August 1997 The reaction of H2S-based high-resolution photoemission spectroscopy. At 300 K, H2S completely decomposes on polycrystalline

  2. Review of H2S Abatement in Geothermal Plants and Laboratory Scale Design of

    E-Print Network [OSTI]

    Karlsson, Brynjar

    Review of H2S Abatement in Geothermal Plants and Laboratory Scale Design of Tray Plate Distillation Engineering ­ ISE December 2013 #12;ii Review of H2S Abatement Methods in Geothermal Plants and Laboratory) such as CO2 and H2S within geothermal fluids have led to increased interest in developing methods

  3. Lighting Up Enzymes for Solar Hydrogen Production (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2011-02-01T23:59:59.000Z

    Scientists at the National Renewable Energy Laboratory (NREL) have combined quantum dots, which are spherical nanoparticles that possess unique size-tunable photophysical properties, with the high substrate selectivity and fast turnover of hydrogenase enzymes to achieve light-driven hydrogen (H2) production. They found that quantum dots of cadmium telluride coated in carboxylic acids easily formed highly stable complexes with the hydrogenase and that these hybrid assemblies functioned to catalyze H2 production using the energy of sunlight.

  4. REGULAR PAPER Photoproduction of hydrogen by sulfur-deprived C. reinhardtii

    E-Print Network [OSTI]

    Meier, Iris

    dramatic was the effect of sulfur deprivation on the H2-production process, which depends both on the presREGULAR PAPER Photoproduction of hydrogen by sulfur-deprived C. reinhardtii mutants with impaired+Business Media B.V. 2007 Abstract Photoproduction of H2 was examined in a series of sulfur-deprived Chlamydomonas

  5. High hydrogen production from glycerol or glucose by electrohydrogenesis using microbial electrolysis cells

    E-Print Network [OSTI]

    if acetate is the main soluble fermentation end product. Further conver- sion to hydrogen without additional of 3.9 mol-H2/mol was obtained using glycerol, which is higher than that possible by fermentation by anaerobic fermentation [2­4]. However, only a maximum of 3 mol of H2 can be produced per mole of glycerol

  6. A step towards the hydrogen economy by using the existing natural gas grid

    E-Print Network [OSTI]

    - end use · Pipeline durability · Pipeline integrity · End user appliances' performance Prepared by O by O. Florisson Gasunie #12;NATURALHY Prepared by Burner, max 12% H2 Pipeline (safety zone), max 10% H2-Platform for hydrogen and fuel cells, Wuppertal Institute, US Department of Energy, EU-Parliament Regulations: CEN

  7. Dynamic viscosity estimation of hydrogen sulfide using a predictive scheme based on molecular dynamics.

    E-Print Network [OSTI]

    Boyer, Edmond

    natural gases containing hydrogen sulfide H2S and/or carbon dioxide CO2) are often encountered properties are very scarce because of the very high toxicity of H2S which leads to very complicated safety procedures for the experimentalists. This is especially true for the high pressures and temperatures

  8. Final Report: Metal Perhydrides for Hydrogen Storage

    SciTech Connect (OSTI)

    Hwang, J-Y.; Shi, S.; Hackney, S.; Swenson, D.; Hu, Y.

    2011-07-26T23:59:59.000Z

    Hydrogen is a promising energy source for the future economy due to its environmental friendliness. One of the important obstacles for the utilization of hydrogen as a fuel source for applications such as fuel cells is the storage of hydrogen. In the infrastructure of the expected hydrogen economy, hydrogen storage is one of the key enabling technologies. Although hydrogen possesses the highest gravimetric energy content (142 KJ/g) of all fuels, its volumetric energy density (8 MJ/L) is very low. It is desired to increase the volumetric energy density of hydrogen in a system to satisfy various applications. Research on hydrogen storage has been pursed for many years. Various storage technologies, including liquefaction, compression, metal hydride, chemical hydride, and adsorption, have been examined. Liquefaction and high pressure compression are not desired due to concerns related to complicated devices, high energy cost and safety. Metal hydrides and chemical hydrides have high gravimetric and volumetric energy densities but encounter issues because high temperature is required for the release of hydrogen, due to the strong bonding of hydrogen in the compounds. Reversibility of hydrogen loading and unloading is another concern. Adsorption of hydrogen on high surface area sorbents such as activated carbon and organic metal frameworks does not have the reversibility problem. But on the other hand, the weak force (primarily the van der Waals force) between hydrogen and the sorbent yields a very small amount of adsorption capacity at ambient temperature. Significant storage capacity can only be achieved at low temperatures such as 77K. The use of liquid nitrogen in a hydrogen storage system is not practical. Perhydrides are proposed as novel hydrogen storage materials that may overcome barriers slowing advances to a hydrogen fuel economy. In conventional hydrides, e.g. metal hydrides, the number of hydrogen atoms equals the total valence of the metal ions. One LiH molecule contains one hydrogen atom because the valence of a Li ion is +1. One MgH2 molecule contains two hydrogen atoms because the valence of a Mg ion is +2. In metal perhydrides, a molecule could contain more hydrogen atoms than expected based on the metal valance, i.e. LiH1+n and MgH2+n (n is equal to or greater than 1). When n is sufficiently high, there will be plenty of hydrogen storage capacity to meet future requirements. The existence of hydrogen clusters, Hn+ (n = 5, 7, 9, 11, 13, 15) and transition metal ion-hydrogen clusters, M+(H2)n (n = 1-6), such as Sc(H2)n+, Co(H2)n+, etc., have assisted the development of this concept. Clusters are not stable species. However, their existence stimulates our approach on using electric charges to enhance the hydrogen adsorption in a hydrogen storage system in this study. The experimental and modeling work to verify it are reported here. Experimental work included the generation of cold hydrogen plasma through a microwave approach, synthesis of sorbent materials, design and construction of lab devices, and the determination of hydrogen adsorption capacities on various sorbent materials under various electric field potentials and various temperatures. The results consistently show that electric potential enhances the adsorption of hydrogen on sorbents. NiO, MgO, activated carbon, MOF, and MOF and platinum coated activated carbon are some of the materials studied. Enhancements up to a few hundred percents have been found. In general, the enhancement increases with the electrical potential, the pressure applied, and the temperature lowered. Theoretical modeling of the hydrogen adsorption on the sorbents under the electric potential has been investigated with the density functional theory (DFT) approach. It was found that the interaction energy between hydrogen and sorbent is increased remarkably when an electric field is applied. This increase of binding energy offers a potential solution for DOE when looking for a compromise between chemisorption and physisorption for hydrogen storage. Bonding of chemisorption is too

  9. Hydrogen Fueling Systems and Infrastructure

    E-Print Network [OSTI]

    ;Projects Hydrogen Infrastructure Development · Turnkey Commercial Hydrogen Fueling Station · Autothermal

  10. Toxic hydrogen sulphide and dark caves: pronounced male life-history divergence among locally adapted Poecilia mexicana

    E-Print Network [OSTI]

    Schlupp, Ingo

    Toxic hydrogen sulphide and dark caves: pronounced male life-history divergence among locally are characterized by exceptionally high concentrations of hydrogen sulphide (H2S): deep-sea hydrothermal vents, hydrocarbon seeps, as well as intertidal zones, salt marshes, mudflats and sewage outfalls, where hydrogen

  11. Evidence For The Production Of Slow Antiprotonic Hydrogen In Vacuum

    E-Print Network [OSTI]

    N. Zurlo; M. Amoretti; C. Amsler; G. Bonomi; C. Carraro; C. L. Cesar; M. Charlton; M. Doser; A. Fontana; R. Funakoshi; P. Genova; R. S. Hayano; L. V. Jorgensen; A. Kellerbauer; V. Lagomarsino; R. Landua; E. Lodi Rizzini; M. Macrì; N. Madsen; G. Manuzio; D. Mitchard; P. Montagna; L. G. Posada; H. Pruys; C. Regenfus; A. Rotondi; G. Testera; D. P. Van der Werf; A. Variola; L. Venturelli; Y. Yamazaki

    2007-08-28T23:59:59.000Z

    We present evidence showing how antiprotonic hydrogen, the quasistable antiproton-proton (pbar-p) bound system, has been synthesized following the interaction of antiprotons with the hydrogen molecular ion (H2+) in a nested Penning trap environment. From a careful analysis of the spatial distributions of antiproton annihilation events, evidence is presented for antiprotonic hydrogen production with sub-eV kinetic energies in states around n=70, and with low angular momenta. The slow antiprotonic hydrogen may be studied using laser spectroscopic techniques.

  12. Hydrogen Production Cost Estimate Using Biomass Gasification: Independent Review

    SciTech Connect (OSTI)

    Ruth, M.

    2011-10-01T23:59:59.000Z

    This independent review is the conclusion arrived at from data collection, document reviews, interviews and deliberation from December 2010 through April 2011 and the technical potential of Hydrogen Production Cost Estimate Using Biomass Gasification. The Panel reviewed the current H2A case (Version 2.12, Case 01D) for hydrogen production via biomass gasification and identified four principal components of hydrogen levelized cost: CapEx; feedstock costs; project financing structure; efficiency/hydrogen yield. The panel reexamined the assumptions around these components and arrived at new estimates and approaches that better reflect the current technology and business environments.

  13. Hydrogen Production

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet provides a brief introduction to hydrogen production technologies. Intended for a non-technical audience, it explains how different resources and processes can be used to produ

  14. Hydrogen Production from Methane Using Oxygen-permeable Ceramic Membranes

    E-Print Network [OSTI]

    Faraji, Sedigheh

    2010-06-08T23:59:59.000Z

    in the production of both fuel-cell quality hydrogen and ultra-clean liquid fuels (Fischer-Tropsch Synthesis), which are easier to transport and store than natural gas [6, 7]. The Fischer-Tropsch process has received significant attention in the quest to produce...:1 ratio of H2:CO which is beneficial to Fischer–Tropsch process and methanol synthesis [4]. Also, this reaction is exothermic which can reduce the overall hydrogen production plant cost [5]. CH4 + ½ O2 ? CO + 2 H2...

  15. Membranes for H2 generation from nuclear powered thermochemical cycles.

    SciTech Connect (OSTI)

    Nenoff, Tina Maria; Ambrosini, Andrea; Garino, Terry J.; Gelbard, Fred; Leung, Kevin; Navrotsky, Alexandra (University of California, Davis, CA); Iyer, Ratnasabapathy G. (University of California, Davis, CA); Axness, Marlene

    2006-11-01T23:59:59.000Z

    In an effort to produce hydrogen without the unwanted greenhouse gas byproducts, high-temperature thermochemical cycles driven by heat from solar energy or next-generation nuclear power plants are being explored. The process being developed is the thermochemical production of Hydrogen. The Sulfur-Iodide (SI) cycle was deemed to be one of the most promising cycles to explore. The first step of the SI cycle involves the decomposition of H{sub 2}SO{sub 4} into O{sub 2}, SO{sub 2}, and H{sub 2}O at temperatures around 850 C. In-situ removal of O{sub 2} from this reaction pushes the equilibrium towards dissociation, thus increasing the overall efficiency of the decomposition reaction. A membrane is required for this oxygen separation step that is capable of withstanding the high temperatures and corrosive conditions inherent in this process. Mixed ionic-electronic perovskites and perovskite-related structures are potential materials for oxygen separation membranes owing to their robustness, ability to form dense ceramics, capacity to stabilize oxygen nonstoichiometry, and mixed ionic/electronic conductivity. Two oxide families with promising results were studied: the double-substituted perovskite A{sub x}Sr{sub 1-x}Co{sub 1-y}B{sub y}O{sub 3-{delta}} (A=La, Y; B=Cr-Ni), in particular the family La{sub x}Sr{sub 1-x}Co{sub 1-y}Mn{sub y}O{sub 3-{delta}} (LSCM), and doped La{sub 2}Ni{sub 1-x}M{sub x}O{sub 4} (M = Cu, Zn). Materials and membranes were synthesized by solid state methods and characterized by X-ray and neutron diffraction, SEM, thermal analyses, calorimetry and conductivity. Furthermore, we were able to leverage our program with a DOE/NE sponsored H{sub 2}SO{sub 4} decomposition reactor study (at Sandia), in which our membranes were tested in the actual H{sub 2}SO{sub 4} decomposition step.

  16. Research Support in Hungary Machine scheduling LED public lighting Microsimulation in public transportation Finally Optimization and Operation Research methods for

    E-Print Network [OSTI]

    Balázs, Bánhelyi

    Euros per full time researcher year. The Hungarian research support scheme has several other smallerResearch Support in Hungary Machine scheduling LED public lighting Microsimulation in public transportation Finally Optimization and Operation Research methods for Real Life Industrial Problems Tibor

  17. Hydrogen program overview

    SciTech Connect (OSTI)

    Gronich, S. [Dept. of Energy, Washington, DC (United States). Office of Utility Technologies

    1997-12-31T23:59:59.000Z

    This paper consists of viewgraphs which summarize the following: Hydrogen program structure; Goals for hydrogen production research; Goals for hydrogen storage and utilization research; Technology validation; DOE technology validation activities supporting hydrogen pathways; Near-term opportunities for hydrogen; Market for hydrogen; and List of solicitation awards. It is concluded that a full transition toward a hydrogen economy can begin in the next decade.

  18. Receptor Specificity and Transmission of H2N2 Subtype Viruses Isolated from the Pandemic of 1957

    E-Print Network [OSTI]

    Pappas, Claudia

    Influenza viruses of the H2N2 subtype have not circulated among humans in over 40 years. The occasional isolation of avian H2 strains from swine and avian species coupled with waning population immunity to H2 hemagglutinin ...

  19. Angular dependence of dissociative electron attachment topolyatomic molecules: application to the 2B1 metastable state of the H2Oand H2S anions

    SciTech Connect (OSTI)

    Haxton, Daniel J.; McCurdy, C. William; Rescigno, Thomas N.

    2006-01-12T23:59:59.000Z

    The angular dependence of dissociative electron attachment (DEA) to polyatomic targets is formulated in the local complex potential model, under the assumption that the axial recoil approximation describes the dissociation dynamics. An additional approximation, which is found to be valid in the case of H2O but not in the case of H2S, makes it possible to describe the angular dependence of DEA solely from an analysis of the fixed-nuclei entrance amplitude, without carrying out nuclear dynamics calculations. For H2S, the final-vibrational-state-specific angular dependence of DEA is obtained by incorporating the variation of the angular dependence of the entrance amplitude with nuclear geometry into the nuclear dynamics. Scattering calculations using the complex Kohn method and, for H2S, full quantum calculations of the nuclear dynamics using the Multi-Configuration Time-Dependent Hartree method, are performed.

  20. The Hype About Hydrogen

    E-Print Network [OSTI]

    Mirza, Umar Karim

    2006-01-01T23:59:59.000Z

    economy based on the hydrogen fuel cell, but this cannot beus to look toward hydrogen. Fuel cell basics, simplifiedthe path to fuel cell commercialization. Hydrogen production

  1. Hydrogen Technologies Group

    SciTech Connect (OSTI)

    Not Available

    2008-03-01T23:59:59.000Z

    The Hydrogen Technologies Group at the National Renewable Energy Laboratory advances the Hydrogen Technologies and Systems Center's mission by researching a variety of hydrogen technologies.

  2. Hydrogen Transition Infrastructure Analysis

    SciTech Connect (OSTI)

    Melendez, M.; Milbrandt, A.

    2005-05-01T23:59:59.000Z

    Presentation for the 2005 U.S. Department of Energy Hydrogen Program review analyzes the hydrogen infrastructure needed to accommodate a transitional hydrogen fuel cell vehicle demand.

  3. Hydrogen Delivery Analysis Models

    Broader source: Energy.gov (indexed) [DOE]

    insert our Research Targets to see the impact List of Delivery Components Compressed Hydrogen Gas Truck (Tube trailer) Compressed Hydrogen Gas Truck Terminal Liquid Hydrogen Truck...

  4. Molecular hydrogen abundances of galaxies in the EAGLE simulations

    E-Print Network [OSTI]

    Lagos, Claudia del P; Schaye, Joop; Furlong, Michelle; Frenk, Carlos S; Bower, Richard G; Schaller, Matthieu; Theuns, Tom; Trayford, James W; Bahe, Yannick M; Vecchia, Claudio Dalla

    2015-01-01T23:59:59.000Z

    We investigate the abundance of galactic molecular hydrogen (H$_2$) in the "Evolution and Assembly of GaLaxies and their Environments" (EAGLE) cosmological hydrodynamic simulations. We assign H$_2$ masses to gas particles in the simulations in post-processing using two different prescriptions that depend on the local dust-to-gas ratio and the interstellar radiation field. Both result in H$_2$ galaxy mass functions that agree well with observations in the local and high-redshift Universe. The simulations reproduce the observed scaling relations between the mass of H$_2$ and the stellar mass, star formation rate and stellar surface density. Towards high edshifts, galaxies in the simulations display larger H$_2$ mass fractions, and correspondingly lower H$_2$ depletion timescales, also in good agreement with observations. The comoving mass density of H$_2$ in units of the critical density, $\\Omega_{\\rm H_2}$, peaks at $z\\approx 1.2-1.5$, later than the predicted peak of the cosmic star formation rate activity, a...

  5. Webinar: Guidance for Filling Out a Detailed H2A Production Case Study

    Broader source: Energy.gov [DOE]

    Video recording and text version of the webinar titled, Guidance for Filling Out a Detailed H2A Production Case Study, originally presented on July 9, 2013.

  6. Isotope Effect on Adsorbed Quantum Phases: Diffusion of H2 and D2 in Nanoporous Carbon

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Contescu, Cristian I.; Zhang, Hongxin; Olsen, Raina J.; Mamontov, Eugene; Morris, James R.; Gallego, Nidia C.

    2013-06-01T23:59:59.000Z

    Quasielastic neutron scattering of H2 and D2 in the same nanoporous carbon at 10–40 K demonstrates extreme quantum sieving, with D2 diffusing up to 76 times faster. D2 also shows liquidlike diffusion while H2 exhibits Chudley-Elliott jump diffusion, evidence of their different relationships with the local lattice of adsorption sites due to quantum effects on intermolecular interactions. The onset of diffusion occurs at 22–25 K for H2 and 10–13 K for D2. At these temperatures, H2 and D2 have identical thermal de Broglie wavelengths that correlate with the dominant pore size.

  7. Closer Look Reveals New Insights on Enzymatic Catalysts for H2 Production (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2014-01-01T23:59:59.000Z

    Researchers use spectroscopic tools to analyze H2 activation by [FeFe]-Hydrogenase HydA1 from Chlamydomonas reinhardtii.

  8. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Application Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Application This presentation reports on the status of mass production cost...

  9. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications: 2007 Update Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Applications: 2007 Update This report estimates fuel cell system cost...

  10. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems...

    Broader source: Energy.gov (indexed) [DOE]

    Application Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Application This report estimates fuel cell system cost for systems produced in the...

  11. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems...

    Broader source: Energy.gov (indexed) [DOE]

    07 Update Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Applications: 2007 Update This report estimates fuel cell system cost for systems...

  12. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mass Production Cost Estimation for Direct H 2 PEM Fuel Cell Systems for Automotive Applications: 2007 Update February 29, 2008 Final Version Brian D. James Jeffrey A. Kalinoski...

  13. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mass Production Cost Estimation for Direct H 2 PEM Fuel Cell Systems for Automotive Applications: 2010 Update September 30, 2010 Prepared by: Brian D. James, Jeffrey A. Kalinoski...

  14. mMass Production Cost Estimation for Direct H2 PEM Fuel Cell...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mass Production Cost Estimation for Direct H 2 PEM Fuel Cell Systems for Automotive Applications: 2009 Update January 1, 2010 Prepared by: Brian D. James, Jeffrey A. Kalinoski &...

  15. Optimized Pathways for Regional H2 Infrastructure Transitions: A Case Study for Southern California

    E-Print Network [OSTI]

    Lin, Zhenhong; Fan, Yueyue; Ogden, Joan M; Chen, Chien-Wei

    2008-01-01T23:59:59.000Z

    gasification, coal gasification, natural gas reforming, andgasification and then coal gasification with carbon captureproduction of H2 via coal gasification with CCS C-SMR, C-

  16. Hydrogen Generation From Electrolysis

    SciTech Connect (OSTI)

    Steven Cohen; Stephen Porter; Oscar Chow; David Henderson

    2009-03-06T23:59:59.000Z

    Small-scale (100-500 kg H2/day) electrolysis is an important step in increasing the use of hydrogen as fuel. Until there is a large population of hydrogen fueled vehicles, the smaller production systems will be the most cost-effective. Performing conceptual designs and analyses in this size range enables identification of issues and/or opportunities for improvement in approach on the path to 1500 kg H2/day and larger systems. The objectives of this program are to establish the possible pathways to cost effective larger Proton Exchange Membrane (PEM) water electrolysis systems and to identify areas where future research and development efforts have the opportunity for the greatest impact in terms of capital cost reduction and efficiency improvements. System design and analysis was conducted to determine the overall electrolysis system component architecture and develop a life cycle cost estimate. A design trade study identified subsystem components and configurations based on the trade-offs between system efficiency, cost and lifetime. Laboratory testing of components was conducted to optimize performance and decrease cost, and this data was used as input to modeling of system performance and cost. PEM electrolysis has historically been burdened by high capital costs and lower efficiency than required for large-scale hydrogen production. This was known going into the program and solutions to these issues were the focus of the work. The program provided insights to significant cost reduction and efficiency improvement opportunities for PEM electrolysis. The work performed revealed many improvement ideas that when utilized together can make significant progress towards the technical and cost targets of the DOE program. The cell stack capital cost requires reduction to approximately 25% of today’s technology. The pathway to achieve this is through part count reduction, use of thinner membranes, and catalyst loading reduction. Large-scale power supplies are available today that perform in a range of efficiencies, >95%, that are suitable for the overall operational goals. The balance of plant scales well both operationally and in terms of cost becoming a smaller portion of the overall cost equation as the systems get larger. Capital cost reduction of the cell stack power supplies is achievable by modifying the system configuration to have the cell stacks in electrical series driving up the DC bus voltage, thereby allowing the use of large-scale DC power supply technologies. The single power supply approach reduces cost. Elements of the cell stack cost reduction and efficiency improvement work performed in the early stage of the program is being continued in subsequent DOE sponsored programs and through internal investment by Proton. The results of the trade study of the 100 kg H2/day system have established a conceptual platform for design and development of a next generation electrolyzer for Proton. The advancements started by this program have the possibility of being realized in systems for the developing fueling markets in 2010 period.

  17. Towards measuring the ionisation and dissociation energies of molecular hydrogen with

    E-Print Network [OSTI]

    Towards measuring the ionisation and dissociation energies of molecular hydrogen with sub and dissociation energies of molecular hydrogen H2 was carried out recently by measuring three intervals independently: the X / EF interval, the EF / n ¼ 54p interval, and the electron binding energy of the n ¼ 54p

  18. Opening of a PhD studentship Development and characterization of composite materials for hydrogen storage

    E-Print Network [OSTI]

    Opening of a PhD studentship Development and characterization of composite materials for hydrogen "Demokritos", is seeking a pre-doctoral researcher to work on hydrogen storage studies in porous and composite materials in connection with the «H2FC-Integrating European Infrastructure to support science

  19. An experimental investigation of the ignition properties of hydrogen and carbon monoxide

    E-Print Network [OSTI]

    Wooldridge, Margaret S.

    for syngas turbine applications S.M. Walton *, X. He, B.T. Zigler, M.S. Wooldridge Department of Mechanical of simulated syngas mixtures of hydrogen (H2), carbon monoxide (CO), oxygen (O2), nitrogen (N2), and carbon. Keywords: Carbon monoxide; Hydrogen; Syngas; Ignition; Rapid compression facility 1. Introduction Syngas

  20. HYDROGEN REGIONAL INFRASTRUCTURE PROGRAM

    E-Print Network [OSTI]

    HYDROGEN REGIONAL INFRASTRUCTURE PROGRAM IN PENNSYLVANIA HYDROGEN REGIONAL INFRASTRUCTURE PROGRAM date ­ November 23, 2004 · Contract end date ­ March 31, 2006 #12;Hydrogen Regional Infrastructure Program in Pennsylvania Hydrogen Regional Infrastructure Program in Pennsylvania · Objectives ­ Capture

  1. C-H..O Hydrogen Bonds in Minor Groove of A-tracts in DNA Double Helices

    E-Print Network [OSTI]

    Bansal, Manju

    C-H..O Hydrogen Bonds in Minor Groove of A-tracts in DNA Double Helices Anirban Ghosh and Manju-pair as well as cross-strand C-H..O hydrogen bonds in the minor groove. The C2-H2..O2 hydrogen bonds within leads to a narrow minor groove in these regions. # 1999 Academic Press Keywords: C-H..O hydrogen bonds

  2. Hydrogen Technology Validation

    Fuel Cell Technologies Publication and Product Library (EERE)

    This fact sheet provides a basic introduction to the DOE Hydrogen National Hydrogen Learning Demonstration for non-technical audiences.

  3. Hydrogen Analysis Group

    SciTech Connect (OSTI)

    Not Available

    2008-03-01T23:59:59.000Z

    NREL factsheet that describes the general activites of the Hydrogen Analysis Group within NREL's Hydrogen Technologies and Systems Center.

  4. GFOC Project results: High Temperature / High Pressure, Hydrogen Tolerant Optical Fiber

    SciTech Connect (OSTI)

    E. Burov; A. Pastouret; E. Aldea; B. Overton; F. Gooijer; A. Bergonzo

    2012-02-12T23:59:59.000Z

    Tests results are given for exposure of multimode optical fiber to high temperatures (300 deg. C) and high partial pressure (15 bar) hydrogen. These results demonstrate that fluorine down doped optical fibers are much more hydrogen tolerant than traditional germanium doped multimode optical fibers. Also demonstrated is the similar hydrogen tolerance of carbon coated and non-carbon coated fibers. Model for reversible H2 impact in fiber versus T{sup o}C and H2 pressure is given. These results have significant impact for the longevity of use for distributed temperature sensing applications in harsh environments such as geothermal wells.

  5. Integrated Mirco-Machined Hydrogen Gas Sensors

    SciTech Connect (OSTI)

    Frank DiMeoJr. Ing--shin Chen

    2005-12-15T23:59:59.000Z

    The widespread use of hydrogen as both an industrial process gas and an energy storage medium requires fast, selective detection of hydrogen gas. This report discusses the development of a new type of solid-state hydrogen gas sensor that couples novel metal hydride thin films with a MEMS (Micro-Electro-Mechanical System) structure known as a micro-hotplate. In this project, Micro-hotplate structures were overcoated with engineered multilayers that serve as the active hydrogen-sensing layer. The change in electrical resistance of these layers when exposed to hydrogen gas was the measured sensor output. This project focused on achieving the following objectives: (1) Demonstrating the capabilities of micro-machined H2 sensors; (2) Developing an understanding of their performance; (3) Critically evaluating the utility and viability of this technology for life safety and process monitoring applications. In order to efficiently achieve these objectives, the following four tasks were identified: (1) Sensor Design and Fabrication; (2) Short Term Response Testing; (3) Long Term Behavior Investigation; (4) Systems Development. Key findings in the project include: The demonstration of sub-second response times to hydrogen; measured sensitivity to hydrogen concentrations below 200 ppm; a dramatic improvement in the sensor fabrication process and increased understanding of the processing properties and performance relationships of the devices; the development of improved sensing multilayers; and the discovery of a novel strain based hydrogen detection mechanism. The results of this program suggest that this hydrogen sensor technology has exceptional potential to meet the stringent demands of life safety applications as hydrogen utilization and infrastructure becomes more prevalent.

  6. Fuel Cell Vehicles and Hydrogen in Preparing for market launch

    E-Print Network [OSTI]

    California at Davis, University of

    Fuel Cell Vehicles and Hydrogen in California Preparing for market launch Catherine Dunwoody June 27, 2012 #12;2 A fuel cell vehicle is electric! 2 · 300-400 mile range · Zero-tailpipe emissions · To launch market and build capacity #12;12 H2 stations and vehicle growth #12;13 California Fuel Cell

  7. Societal lifetime cost of hydrogen fuel cell vehicles

    E-Print Network [OSTI]

    Sun, Yongling; Ogden, J; Delucchi, Mark

    2010-01-01T23:59:59.000Z

    Gasoline Feedstock activities Fuel production Fuel storage,gasoline vehicle ORNL Fuel cell vehicle DOE fuel cell target: $45/kW by 2015, $30/kW by 2020 (onboard H2 storagegasoline vehicle (Table 3) Component – manufacturing cost Electric Powertrain (Motor + controller + transmission) Fuel cell system (stack + BOP) Hydrogen storage

  8. Excitation-energy dependence of the mechanism for two-photon ionization of liquid H2O and D2O from 8.3to12.4eV

    E-Print Network [OSTI]

    Elles, Christopher G.; Jailaubekov, Askat E.; Crowell, Robert A.; Bradforth, Stephen E.

    2006-07-28T23:59:59.000Z

    or gener- ate dangerous amounts of hydrogen gas in radioactive waste storage tanks.1 Radiolysis and photolysis experiments pro- vide a window on the underlying chemistry in such systems by revealing information about the important reactions that occur... following ionization in a controlled environment. Each ionization event produces a hydroxyl radical, a hydronium ion, and a solvated electron within the first few picoseconds, as in the case of two-photon ionization. H2O#1;aq#2; + 2h#2;? OH#1;aq#2; + H3O #1...

  9. Accurate Thermodynamic Model for the Calculation of H2S Solubility in Pure Water and Brines

    E-Print Network [OSTI]

    Zhu, Chen

    Accurate Thermodynamic Model for the Calculation of H2S Solubility in Pure Water and Brines Zhenhao mineral solubility in H2S saturated brines. An example calculation for galena solubility is given. 1 gasification process.5,6 Sequestration of the gases into geological brine formation is one of the promising

  10. Photoelectron imaging spectroscopy of Cu (H2O)1,2 anion complexes

    E-Print Network [OSTI]

    Lineberger, W. Carl

    structure calculations for the neutral, the adiabatic electron affinity is derived. Ó 2004 Elsevier B.V. All rights reserved. 1. Introduction Recent experiments [1] and calculations [2,3] of the structure and rearrangement dynamics of CuH2O fol- lowing electron photodetachment from CuÀ H2O have afforded considerable

  11. Fischer-Tropsch Database Calculations Conversions: CO, H2, and Syngas

    E-Print Network [OSTI]

    Kentucky, University of

    Fischer-Tropsch Database Calculations Conversions: CO, H2, and Syngas f in out in n n n = - 100 n contraction (%) #12;Syngas ratio (H2:CO): sr H in CO in n n = 2 _ _ n: (mols per hour) sr: Syngas ratio Rates active metal (g) r: Rate (mols / hr / g metal) #12;Rate Syngas: syngas H COr r r= +2 r syngas: Syngas

  12. Above- and below-ground Litter Manipulation: Effect on Retention and Release of DOC, DON and DIN in the Sikfokut Forest, Hungary

    E-Print Network [OSTI]

    Evetts, Elizabeth A.; Peterson, Jacqueline A.

    2009-09-30T23:59:59.000Z

    ABOVE- AND BELOW-GROUND LITTER MANIPULATION: EFFECT ON RETENTION AND RELEASE OF DOC, DON AND DIN IN THE SIKFOKUT FOREST, HUNGARY A Senior Scholars Thesis by ELIZABETH A. EVETTS Submitted to the Office...: EFFECT ON RETENTION AND RELEASE OF DOC, DON AND DIN IN THE SIKFOKUT FOREST, HUNGARY A Senior Scholars Thesis by ELIZABETH A. EVETTS Submitted to the Office of Undergraduate Research Texas A&M University in partial...

  13. Hydrogen, Fuel Cells, and Infrastructure Technologies FY 2002 Progress Report Section V. Integrated Hydrogen and Fuel Cell

    E-Print Network [OSTI]

    (NH3) as a chemical carrier for H2. · Evaluate the viability of autothermal NH3 reformation onSage Program to calculate and optimize the performance parameters for the autothermal reformation of ammonia Thermochemistry to determine the performance parameters for the autothermal reformation of NH3 gas to hydrogen

  14. A C-H...O Hydrogen Bond Stabilized Polypeptide Chain Reversal Motif

    E-Print Network [OSTI]

    Babu, M. Madan

    A C-H...O Hydrogen Bond Stabilized Polypeptide Chain Reversal Motif at the C-terminus of Helices between the C atom of residue Ala 4 (T-4) and the backbone oxygen atom of DLeu 9. The C-H...O hydrogen Nitrogenase MoFe protein (PDB: 1qh8). The N-H...O hydrogen bond parameters are: O...N = 3.19Ã?; O...H = 2.48 Ã?

  15. Dirac-Fock calculation for H, H2+ and H2 in a strong magnetic field by the Hermitian basis of B-splines

    E-Print Network [OSTI]

    G. B. Deineka

    1999-09-14T23:59:59.000Z

    A two-dimensional, fully numerical approach to the solution of four-component Dirac-Fock equation using the moderately long Hermitian basis of B-splines is applied to H, H2+ and H2 in a strong magnetic field. The geometric parameters, including different behavior of wave-functions relativistic components are analyzed. The accuracy of the solutions as a function of the basis lenght is estimated. The relativistic corrections are calculated by transformation of the matrix equations to the equations for large relativistic components. Application of the finite-element method to solution of the Dirac-Fock equation without supplementary assumption about exchange in case of the H2 excited states is discussed. The maximum localization of the basis functions provides applicability of the quadrature formulae for five-dimensional two-electron integral calculations within reasonable period.

  16. Hydrogen Fueling Station in Honolulu, Hawaii Feasibility Analysis

    SciTech Connect (OSTI)

    Porter Hill; Michael Penev

    2014-08-01T23:59:59.000Z

    The Department of Energy Hydrogen & Fuel Cells Program Plan (September 2011) identifies the use of hydrogen for government and fleet electric vehicles as a key step for achieving “reduced greenhouse gas emissions; reduced oil consumption; expanded use of renewable power …; highly efficient energy conversion; fuel flexibility …; reduced air pollution; and highly reliable grid-support.” This report synthesizes several pieces of existing information that can inform a decision regarding the viability of deploying a hydrogen (H2) fueling station at the Fort Armstrong site in Honolulu, Hawaii.

  17. A RhxSy/C Catalyst for the Hydrogen Oxidation and Hydrogen Evolution Reactions in HBr

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Masud, Jahangir [Univ. of Kansas, Lawrence, KS (United States); Nguyena, Trung V. [Univ. of Kansas, Lawrence, KS (United States); Singh, Nirala [Univ. of California, Santa Barbara, CA (United States); McFarland, Eric [Univ. of California, Santa Barbara, CA (United States); Ikenberry, Myles [Kansas State Univ., Manhattan, KS (United States); Hohn, Keith [Kansas State Univ., Manhattan, KS (United States); Pan, Chun-Jern [National Taiwan University of Science & Technology, Tapei (Taiwan); Hwang, Bing-Joe [National Taiwan University of Science & Technology, Tapei (Taiwan)

    2015-01-01T23:59:59.000Z

    Rhodium sulfide (Rh2S3) on carbon support was synthesized by refluxing rhodium chloride with ammonium thiosulfate. Thermal treatment of Rh2S3 at high temperatures (600°C to 850°C) in presence of argon resulted in the transformation of Rh2S3 into Rh3S4, Rh17S15 and Rh which were characterized by TGA/DTA, XRD, EDX, and deconvolved XPS analyses. The catalyst particle size distribution ranged from 3 to 12 nm. Cyclic voltammetry and rotating disk electrode measurements were used to evaluate the catalytic activity for hydrogen oxidation and evolution reactions in H2SO4 and HBr solutions. The thermally treated catalysts show high activity for the hydrogen reactions. The exchange current densities (io) of the synthesized RhxSy catalysts in H2-saturated 1M H2SO4 and 1M HBr for HER and HOR were 0.9 mA/cm2 to 1.0 mA/cm2 and 0.8 to 0.9 mA/cm2, respectively. The lower io values obtained in 1M HBr solution compared to in H2SO4 might be due to the adsorption of Br- on the active surface. Stable electrochemical active surface area (ECSA) of RhxSy catalyst was obtained for CV scan limits between 0 V and 0.65 V vs. RHE. Scans with upper voltage limit beyond 0.65 V led to decreased and unreproducible ECSA measurements.

  18. Renewable Hydrogen Carrier Carbohydrate: Constructing the Carbon-Neutral Carbohydrate Economy

    SciTech Connect (OSTI)

    Zhang, Y.-H. Percival [Virginia Polytechnic Institute and State University (Virginia Tech); Mielenz, Jonathan R [ORNL

    2011-01-01T23:59:59.000Z

    Abstract The hydrogen economy presents an appealing energy future but its implementation must solve numerous problems ranging from low-cost sustainable production, high-density storage, costly infrastructure, to eliminating safety concern. The use of renewable carbohydrate as a high-density hydrogen carrier and energy source for hydrogen production is possible due to emerging cell-free synthetic biology technology called cell-free synthetic pathway biotransformation (SyPaB). Assembly of numerous enzymes and co-enzymes in vitro can create complicated set of biological reactions or pathways that microorganisms cannot complete, for example, C6H10O5 (aq) + 7 H2O (l) 12 H2 (g) + 6 CO2 (g) (PLoS One 2007, 2:e456). Thanks to 100% selectivity of enzymes, modest reaction conditions, and high-purity of generated hydrogen, carbohydrate is a promising hydrogen carrier for end users. Gravimetric density of carbohydrate is 14.8 H2 mass% if water can be recycled from PEM fuel cells or 8.33% H2 mass% without water recycling. Renewable carbohydrate can be isolated from plant biomass or would be produced from a combination of solar electricity/hydrogen and carbon dioxide fixation mediated by high-efficiency artificial photosynthesis mediated by SyPaB. The construction of this carbon-neutral carbohydrate economy would address numerous sustainability challenges, such as electricity and hydrogen storage, CO2 fixation and long-term storage, water conservation, transportation fuel production, plus feed and food production.

  19. 2H2A Hydrogen Delivery Infrastructure Analysis Models and Conventional Pathway Options Analysis Results - Interim Report

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't Your Destiny: The Future of BadTHEEnergyReliability2015 Peer Review. d r a m a1, in:

  20. Diffusive and rotational dynamics of condensed n-H2 confined in MCM-41

    SciTech Connect (OSTI)

    Prisk, Timothy R [ORNL; Bryan, Matthew [Indiana University; Sokol, Paul E [ORNL

    2014-01-01T23:59:59.000Z

    In this paper, we report an inelastic neutron scattering study of liquid and solid n-H2 confined within MCM-41. This is a high surface area, mesoporous silica glass with a narrow pore size distribution centered at 3.5 nm. The scattering data provides information about the diffusive and rotational dynamics of the adsorbed n-H2 at low temperatures. In the liquid state, the neutron scattering data demonstrates that only a fraction of the adsorbed o-H2 is mobile on the picosecond time scale. This mobile fraction undergoes liquid-like jump diffusion, and values for the residence time t and effective mean-squared displacement hu2i are reported as a function of pore filling. In the solid state, the rotational energy levels of adsorbed H2 are strongly perturbed from their free quantum rotor behavior in the bulk solid. The underlying orientational potential of the hindered rotors is due to the surface roughness and heterogeneity of the MCM-41 pore walls. This potential is compared to the hindering potential of other porous silicas, such as Vycor. Strong selective adsorption makes the interfacial layer rich in o-H2, leaving the inner core volume consisting of a depleted mixture of o-H2 and p-H2.

  1. Safety and Regulatory Structure for CNG, CNG-Hydrogen, Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen, Hydrogen Vehicles and Fuels in China Safety and Regulatory Structure for CNG, CNG-Hydrogen, Hydrogen Vehicles and Fuels in China Presentation given by Jinyang Zheng of...

  2. Hydrogen Bonded Arrays: The Power of Multiple Hydrogen Bonds...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Bonded Arrays: The Power of Multiple Hydrogen Bonds. Hydrogen Bonded Arrays: The Power of Multiple Hydrogen Bonds. Abstract: Hydrogen bond interactions in small covalent model...

  3. Hydrogen permeability and Integrity of hydrogen transfer pipelines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    permeability and Integrity of hydrogen transfer pipelines Hydrogen permeability and Integrity of hydrogen transfer pipelines Presentation by 03-Babu for the DOE Hydrogen Pipeline...

  4. CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties...

    Office of Environmental Management (EM)

    CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties and Behavior CNG, Hydrogen, CNG-Hydrogen Blends - Critical Fuel Properties and Behavior Presentation given by Jay...

  5. NREL Wind to Hydrogen Project: Renewable Hydrogen Production...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage & Transportation NREL Wind to Hydrogen Project: Renewable Hydrogen Production for Energy Storage &...

  6. Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery...

    Broader source: Energy.gov (indexed) [DOE]

    Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery Workshop Bulk Hydrogen Storage - Strategic Directions for Hydrogen Delivery Workshop Targets, barriers and...

  7. Optimized Pathways for Regional H2 Infrastructure Transitions: A Case Study for Southern California

    E-Print Network [OSTI]

    Lin, Zhenhong; Fan, Yueyue; Ogden, Joan M; Chen, Chien-Wei

    2008-01-01T23:59:59.000Z

    Costs to Estimate Hydrogen Pipeline Costs. University ofPipeline network gradually expands and eventually takes over all hydrogenpipelines. These technologies compete with each other to meet an exogenously estimated hydrogen

  8. Preparation of oriented and aligned H2 and HD by stimulated Raman pumping

    E-Print Network [OSTI]

    Zare, Richard N.

    of hydrogen deuteride was prepared by SRP to investigate the effects of alignment on the reactivity for the Cl

  9. Evaluation of the Role of Water in the H2 Bond Formation by Ni(II)-based Electrocatalysts

    SciTech Connect (OSTI)

    Ho, Ming-Hsun; Raugei, Simone; Rousseau, Roger J.; Dupuis, Michel; Bullock, R. Morris

    2013-07-17T23:59:59.000Z

    We investigate the role of water in the H-H bond formation by a family of nickel molecular catalysts that exhibit high rates for H2 production in acetonitrile solvent. A key feature leading to the high reactivity is the Lewis acidity of the Ni(II) center and pendant amines in the diphosphine ligand that function as Lewis bases, facilitating H-H bond formation or cleavage. Significant increases in the rate of H2 production have been reported in the presence of added water. Our calculations show that molecular water can displace an acetonitrile solvent molecule in the first solvation shell of the metal. One or two water molecules can also participate in shuttling a proton that can combine with a metal hydride to form the H-H bond. However the participation of the water molecules does not lower the barrier to H-H bond formation. Thus these calculations suggest that the rate increase due to water in these electrocatalysts is not associated with the elementary step of H-H bond formation or cleavage, but rather with the proton delivery steps. We attribute the higher barrier in the H-H bond formation in the presence of water to a decrease in direct interaction between the protic and hydridic hydrogen atoms forced by the water molecules. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US Department of Energy, Office of Science, Office of Basic Energy Sciences. Computational resources were provided at W. R. Wiley Environmental Molecular Science Laboratory - Pacific Northwest National Laboratory, the National Energy Research Scientific Computing Center (NERSC) at Lawrence Berkeley National Laboratory, and the Jaguar supercomputer at Oak Ridge National Laboratory.

  10. Hydrogen Delivery Mark Paster

    E-Print Network [OSTI]

    Liquids (e.g. ethanol etc.) ­ Truck: HP Gas & Liquid Hydrogen ­ Regional Pipelines ­ Breakthrough Hydrogen;Delivery Key Challenges · Pipelines ­ Retro-fitting existing NG pipeline for hydrogen ­ Utilizing existing NG pipeline for Hythane with cost effective hydrogen separation technology ­ New hydrogen pipeline

  11. Wind-To-Hydrogen Project: Electrolyzer Capital Cost Study

    SciTech Connect (OSTI)

    Saur, G.

    2008-12-01T23:59:59.000Z

    This study is being performed as part of the U.S. Department of Energy and Xcel Energy's Wind-to-Hydrogen Project (Wind2H2) at the National Renewable Energy Laboratory. The general aim of the project is to identify areas for improving the production of hydrogen from renewable energy sources. These areas include both technical development and cost analysis of systems that convert renewable energy to hydrogen via water electrolysis. Increased efficiency and reduced cost will bring about greater market penetration for hydrogen production and application. There are different issues for isolated versus grid-connected systems, however, and these issues must be considered. The manner in which hydrogen production is integrated in the larger energy system will determine its cost feasibility and energy efficiency.

  12. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Applications: 2010 Update Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Applications: 2010 Update This report is the fourth annual update of a...

  13. Evaluation of the Role of Water in the H2 Bond Formation by Ni...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    . Abstract: We investigate the role of water in the H-H bond formation by a family of nickel molecular catalysts that exhibit high rates for H2 production in acetonitrile solvent....

  14. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Mass Production Cost Estimation for Direct H 2 PEM Fuel Cell Systems for Automotive Applications: 2008 Update March 26, 2009 v.30.2021.052209 Prepared by: Brian D. James & Jeffrey...

  15. Overview of Station Analysis Tools Developed in Support of H2USA

    Broader source: Energy.gov [DOE]

    Access the recording and download presentation slides from the Fuel Cell Technologies Office webinar "Overview of Station Analysis Tools Developed in Support of H2USA" held on May 12, 2015.

  16. Highly Selective H2 Separation Zeolite Membranes for Coal Gasification Membrane Reactor Applications

    SciTech Connect (OSTI)

    Mei Hong; Richard D. Noble; John L. Falconer

    2006-09-24T23:59:59.000Z

    Zeolite membranes are thermally, chemically, and mechanically stable. They also have tunable molecular sieving and catalytic ability. These unique properties make zeolite membrane an excellent candidate for use in catalytic membrane reactor applications related to coal conversion and gasification, which need high temperature and high pressure range separation in chemically challenging environment where existing technologies are inefficient or unable to operate. Small pore, good quality, and thin zeolite membranes are needed for highly selective H{sub 2} separation from other light gases (CO{sub 2}, CH{sub 4}, CO). However, zeolite membranes have not been successful for H{sub 2} separation from light gases because the zeolite pores are either too big or the membranes have a large number of defects. The objective of this study is to develop zeolite membranes that are more suitable for H{sub 2} separation. In an effort to tune the size of zeolite pores and/or to decrease the number of defects, medium-pore zeolite B-ZSM-5 (MFI) membranes were synthesized and silylated. Silylation on B-ZSM-5 crystals reduced MFI-zeolite pore volume, but had little effect on CO{sub 2} and CH{sub 4} adsorption. Silylation on B-ZSM-5 membranes increased H{sub 2} selectivity both in single component and in mixtures with CO{sub 2}CO{sub 2}, CH{sub 4}, or N2. Single gas and binary mixtures of H{sub 2}/CO{sub 2} and H{sub 2}/CH{sub 4} were separated through silylated B-ZSM-5 membranes at feed pressures up to 1.7 MPa and temperatures up to 773 K. For one BZSM-5 membrane after silylation, the H2/CO{sub 2} separation selectivity at 473 K increased from 1.4 to 37, whereas the H{sub 2}/CH{sub 4} separation selectivity increased from 1.6 to 33. Hydrogen permeance through a silylated B-ZSM-5 membrane was activated, but the CO{sub 2} and CH4 permeances decreased slightly with temperature in both single gas and in mixtures. Therefore, the H{sub 2} permeance and H{sub 2}/CO{sub 2} and H{sup 2} /CH{sub 4} separation selectivities increased with temperature. At 673 K, the H2 permeance was 1.0x10-7 molxm-2xs-1xPa-1, and the H{sub 2}/CO{sub 2} separation selectivity was 47. Above 673 K, the silylated membrane catalyzed reverse water gas shift reaction and still separated H{sub 2} with high selectivity; and it was thermally stable. However, silylation decreased H{sub 2} permeance more than one order of magnitude. The H{sub 2} separation performance of the silylated B-ZSM-5 membranes depended on the initial membrane quality and acidity, as well as the silane precursors. Increasing the membrane feed pressure also increased the H{sub 2} flux and the H{sub 2} mole fraction in the permeate stream for both mixtures. Another approach used in this study is optimizing the synthesis of small-pore SAPO-34 (CHA) membranes and/or modifying SAPO-34 membranes by silylation or ion exchange. For SAPO-34 membranes, strong CO{sub 2} adsorption inhibited H{sub 2} adsorption and decreased H2 permeances, especially at low temperatures. At 253 K, CO{sub 2}/H{sub 2} separation selectivities of a SAPO-34 membrane were greater than 100 with CO{sub 2} permeances of about 3 x 10-8 mol m-2 s-1 Pa-1. The high reverse-selectivity of the SAPO-34 membranes can minimize H{sub 2} recompression because H{sub 2} remained in the retentate stream at a higher pressure. The CO{sub 2}/H{sub 2} separation selectivity exhibited a maximum with CO{sub 2} feed concentration possibly caused by a maximum in the CO{sub 2}/H{sub 2} sorption selectivity with increased CO{sub 2} partial pressure. The SAPO-34 membrane separated H{sub 2} from CH{sub 4} because CH{sub 4} is close to the SAPO-34 pore size so its diffusivity is much lower than the H{sup 2} diffusivity. The H{sub 2}/CH{sub 4} separation selectivity was almost independent of temperature, pressure, and feed composition. Silylation on SAPO-34 membranes increased H{sup 2}/CH{sub 4} and CO{sub 2}/CH{sub 4} selectivities but did not increase H{sub 2}/CO{sub 2} and H{sub 2}/N{sub 2} selectivities because silylation only blocked defects in SAPO-34 membranes. Hydr

  17. Adsorption and thermal decomposition of H2S on Si(100) Ying-Huang Lai a

    E-Print Network [OSTI]

    Wu, Shin-Tson

    Adsorption and thermal decomposition of H2S on Si(100) Ying-Huang Lai a , Chuin-Tih Yeh a , Yi Adsorption and thermal decomposition of H2S on Si(1 0 0)-2 Â 1 are studied by means of temperature- sociates to form H and HS on the Si surface at adsorption temperature of 115 K. The Si(1 0 0)-2 Â 1 surface

  18. HYDROGEN TECHNOLOGY RESEARCH AT THE SAVANNAH RIVER NATIONAL LABORATORY

    SciTech Connect (OSTI)

    Danko, E

    2009-03-02T23:59:59.000Z

    The Savannah River National Laboratory (SRNL) is a U.S. Department of Energy research and development laboratory located at the Savannah River Site (SRS) near Aiken, South Carolina. SRNL has over 50 years of experience in developing and applying hydrogen technology, both through its national defense activities as well as through its recent activities with the DOE Hydrogen Programs. The hydrogen technical staff at SRNL comprises over 90 scientists, engineers and technologists, and it is believed to be the largest such staff in the U.S. SRNL has ongoing R&D initiatives in a variety of hydrogen storage areas, including metal hydrides, complex hydrides, chemical hydrides and carbon nanotubes. SRNL has over 25 years of experience in metal hydrides and solid-state hydrogen storage research, development and demonstration. As part of its defense mission at SRS, SRNL developed, designed, demonstrated and provides ongoing technical support for the largest hydrogen processing facility in the world based on the integrated use of metal hydrides for hydrogen storage, separation, and compression. The SRNL has been active in teaming with academic and industrial partners to advance hydrogen technology. A primary focus of SRNL's R&D has been hydrogen storage using metal and complex hydrides. SRNL and its Hydrogen Technology Research Laboratory have been very successful in leveraging their defense infrastructure, capabilities and investments to help solve this country's energy problems. SRNL has participated in projects to convert public transit and utility vehicles for operation using hydrogen fuel. Two major projects include the H2Fuel Bus and an Industrial Fuel Cell Vehicle (IFCV) also known as the GATOR{trademark}. Both of these projects were funded by DOE and cost shared by industry. These are discussed further in Section 3.0, Demonstration Projects. In addition to metal hydrides technology, the SRNL Hydrogen group has done extensive R&D in other hydrogen technologies, including membrane filters for H2 separation, doped carbon nanotubes, storage vessel design and optimization, chemical hydrides, hydrogen compressors and hydrogen production using nuclear energy. Several of these are discussed further in Section 2, SRNL Hydrogen Research and Development.

  19. Sustained H2 Production Driven by Photosynthetic Water Splitting in a Unicellular Cyanobacterium

    SciTech Connect (OSTI)

    Melnicki, Matthew R.; Pinchuk, Grigoriy E.; Hill, Eric A.; Kucek, Leo A.; Fredrickson, Jim K.; Konopka, Allan; Beliaev, Alex S.

    2012-08-07T23:59:59.000Z

    Continuously illuminated nitrogen-deprived Cyanothece sp. ATCC 51142 evolved H2 via dinitrogenase at rates up to 400 ?mol•mg Chl-1•h-1 in parallel with photosynthetic O2 production. Notably, sustained co-production of H2 and O2 occurred over 100 h in the presence of CO2, with both gases displaying inverse oscillations which eventually dampened to stable rates. Oscillations were not observed when CO2 was omitted, while H2 and O2 evolution rates were positively correlated. In situ light saturation analyses of H2 production displayed dose-dependence and lack of O2 inhibition. Inactivation of photosystem II had substantial long-term effects but did not affect the short-term H2 production indicating that the process is also supported by photosystem I activity and oxidation of endogenous glycogen. Collectively, our results demonstrate that uninterrupted H2 production in unicellular diazotrophic cyanobacteria can be fueled by water photolysis without the detrimental effects of O2 and have important implications for sustainable production of biofuels.

  20. Qualitative determination of H2S crossover rates in nation membranes using ion-probe techniques

    SciTech Connect (OSTI)

    Brosha, Eric L [Los Alamos National Laboratory; Rockward, Tommy [Los Alamos National Laboratory; Uribe, Francisco A [Los Alamos National Laboratory; Garzon, Fernando H [Los Alamos National Laboratory

    2008-01-01T23:59:59.000Z

    Polymer electrolyte membrane fuel cells are sensitive to impurities that may be present in either the oxidizer or fuel. H2S, even at the ppb level, will have a dramatic and adverse affect on fuel cell performance. The H2S permeability through dry and humidified Nafion PEMFC membranes was studied using ion probe techniques. A sulfide anti-oxidant buffer solution was used to trap and concentrate trace quantities of H2S that permeated through 50 cm2samples of Nafion 117 and 212 membranes using a partial pressure difference up to I030ppm at room temperature. Experiments were conducted for up to 24 hours in order to achieve sulfide ion concentrations high enough to be precisely determined by subsequent titration with Pb(N03)2. The rate of H2S crossover for dry 117 and 212 were identical at 1.2e-7 g/min. Humidification increased the crossover rate to 5.ge-7 glmin and 1.8e-6 glmin for 117 and 212 respectively. Although the data collected in this work show that the rate of H2S crossover increases with water content and reduced membrane thickness, an accurate determination of permeation constants from this work was not possible because the H2S partial pressure was not constant throughout the experiment.

  1. The infrared dielectric function of solid para-hydrogen

    E-Print Network [OSTI]

    Kettwich, Cassie; Walker, Mark; Tuntsov, Artem

    2015-01-01T23:59:59.000Z

    We report laboratory measurements of the absorption coefficient of solid para-H2, within the wavelength range from 1 to 16.7 micron, at high spectral resolution. In addition to the narrow rovibrational lines of H2 which are familiar from gas phase spectroscopy, the data manifest double transitions and broad phonon branches that are characteristic specifically of hydrogen in the solid phase. These transitions are of interest because they provide a spectral signature which is independent of the impurity content of the matrix. We have used our data, in combination with a model of the ultraviolet absorptions of the H2 molecule, to construct the dielectric function of solid para-H2 over a broad range of frequencies. Our results will be useful in determining the electromagnetic response of small particles of solid hydrogen. The dielectric function makes it clear that pure H2 dust would contribute to IR extinction predominantly by scattering starlight, rather than absorbing it, and the characteristic IR absorption s...

  2. Hydrogen Fuel Cell Vehicles

    E-Print Network [OSTI]

    Delucchi, Mark

    1992-01-01T23:59:59.000Z

    Hydrogen Fuel Cell Vehicles UCD-ITS-RR-92-14 September bycost than both. Solar-hydrogen fuel- cell vehicles would becost than both. Solar-hydrogen fuel- cell vehicles would be

  3. HYDROGEN IN GERMANIUM

    E-Print Network [OSTI]

    Haller, E.E.

    2011-01-01T23:59:59.000Z

    •^f-1? c^4--^ LBL-7996 HYDROGEN IN GERMANIUM E. E. HallerW-7405-ENG-48 LBL-7996 HYDROGEN IN GERMANIUM* E. E. Haller48. LBL-7996 Abstract Hydrogen is shown to form molecular

  4. President's Hydrogen Fuel Initiative

    Broader source: Energy.gov (indexed) [DOE]

    Hydrogen Fuel Initiative Workshop on Manufacturing R&D for the Hydrogen Economy Washington, DC July 13, 2005 JoAnn Milliken DOE Hydrogen Program Planning U.S. Energy Dependence is...

  5. Spitzer observations of hydrogen deuteride

    E-Print Network [OSTI]

    Neufeld, D A; Hollenbach, D J; Sonnentrucker, P; Melnick, G J; Bergin, E A; Snell, R L; Forrest, W J; Watson, D M; Kaufman, M J; Neufeld, David A.; Green, Joel D.; Hollenbach, David J.; Sonnentrucker, Paule; Melnick, Gary J.; Bergin, Edwin A.; Snell, Ronald L.; Forrest, William J.; Watson, Dan M.; Kaufman, and Michael J.

    2006-01-01T23:59:59.000Z

    We report the detection of interstellar hydrogen deuteride (HD) toward the supernova remnant IC443, and the tentative detection of HD toward the Herbig Haro objects HH54 and HH7 and the star forming region GGD37 (Cepheus A West). Our detections are based upon spectral line mapping observations of the R(3) and R(4) rotational lines of HD, at rest wavelengths of 28.502 and 23.034 micron respectively, obtained using the Infrared Spectrograph onboard the Spitzer Space Telescope. The HD R(4)/R(3) line intensity ratio promises to be a valuable probe of the gas pressure in regions where it can be observed. The derived HD/H2 abundance ratios are 1.19(+0.35/-0.24)E-5, 1.80(+0.54/-0.32)E-5, and 1.41(+0.46/-0.33)E-5 respectively (68.3% confidence limits, based upon statistical errors alone) for IC443 (clump C), HH54, and HH7. If HD is the only significant reservoir of gas-phase deuterium in these sources, the inferred HD/H2 ratios are all consistent with a gas-phase elemental abundance [n(D)/n(H)](gas) ~ 7.5E-6, a facto...

  6. Abstract ID: P2-66 Hydrogen production during the irradiation of gaseous organic compounds: advantage of an

    E-Print Network [OSTI]

    Boyer, Edmond

    of propane, the radiolytic yield value of hydrogen G(H2) is equal to 3.7 for total doses in the range of 0, hydrogen production, propane radiolysis. Corresponding author: C. Pichon Institut de Physique Nucléaire de be explained by the instability of some organics materials under vacuum. In order to analyse samples in air

  7. Sandia Hydrogen Combustion Research

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen Combustion Research Sandia Hydrogen Combustion Research Sebastian A. Kaiser (PI) Sandia National Laboratories Christopher M. White University of New Hampshire Sponsor: DoE...

  8. Sandia National Laboratories: Hydrogen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hydrogen Solar Thermochemical Hydrogen Production On June 13, 2014, in SNL maintains the equipment, experts, and partnerships required to develop technology for solar...

  9. Hydrogen Program Overview

    Fuel Cell Technologies Publication and Product Library (EERE)

    This 2-page fact sheet provides a brief introduction to the DOE Hydrogen Program. It describes the program mission and answers the question: “Why Hydrogen

  10. Hydrogen | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    for clean energy technology manufacturers. March 28, 2014 Sales Tax Exemption for Hydrogen Generation Facilities In North Dakota, the sale of hydrogen used to power an internal...

  11. Hydrogen | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    with a catalyst of molybdenum sulfide and exposed to sunlight, these pillars generate hydrogen gas from the hydrogen ions liberated by splitting water. Each pillar is approximately...

  12. Why Hydrogen? Hydrogen from Diverse Domestic Resources

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Gas Pipelines * Nuclear Energy * Office of Science Extending Collaborations * Other Federal Agencies - DOT, EPA, Others * International Collaborations Hydrogen from Diverse...

  13. NREL Showcases Hydrogen Internal Combustion Engine Bus, Helps DOE Set Standards for Outreach (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2010-11-01T23:59:59.000Z

    This fact sheet describes the National Renewable Energy Laboratory's (NREL's) accomplishments in showcasing a Ford hydrogen-powered internal combustion engine (H2ICE) bus at The Taste of Colorado festival in Denver. NREL started using its U.S. Department of Energy-funded H2ICE bus in May 2010 as the primary shuttle vehicle for VIP visitors, members of the media, and new employees. In September 2010, NREL featured the bus at The Taste of Colorado. This was the first major outreach event for the bus. NREL's educational brochure, vehicle wrap designs, and outreach efforts serve as a model for other organizations with DOE-funded H2ICE buses. Work was performed by the Hydrogen Education Group and Market Transformation Group in the Hydrogen Technologies and Systems Center.

  14. Magnetic properties of a metal-organic antiferromagnet Mn,,hfipbb...py,,H2O...0.5

    E-Print Network [OSTI]

    Li, Jing

    Magnetic properties of a metal-organic antiferromagnet Mn,,hfipbb...py,,H2O...0.5 Tan Yuena and C Jersey 08854 Presented on 2 November 2005; published online 18 April 2006 Mn hfipbb py H2O 0.5 H2hfipbb=4 as on powder samples of Mn hfipbb py H2O 0.5. Antiferromagnetic ordering was observed below a transition

  15. High-bandwidth Modulation of H2/Syngas Fuel to Control Combustion Dynamics in Micro-Mixing Lean Premix Systems

    SciTech Connect (OSTI)

    Jeff Melzak; Tim Lieuwen; Adel Mansour

    2012-01-31T23:59:59.000Z

    The goal of this program was to develop and demonstrate fuel injection technologies that will facilitate the development of cost-effective turbine engines for Integrated Gasification Combined Cycle (IGCC) power plants, while improving efficiency and reducing emissions. The program involved developing a next-generation multi-point injector with enhanced stability performance for lean premix turbine systems that burn hydrogen (H2) or synthesis gas (syngas) fuels. A previously developed injector that demonstrated superior emissions performance was improved to enhance static flame stability through zone staging and pilot sheltering. In addition, piezo valve technology was implemented to investigate the potential for enhanced dynamic stability through high-bandwidth modulation of the fuel supply. Prototype injector and valve hardware were tested in an atmospheric combustion facility. The program was successful in meeting its objectives. Specifically, the following was accomplished: Demonstrated improvement of lean operability of the Parker multi-point injector through staging of fuel flow and primary zone sheltering; Developed a piezo valve capable of proportional and high-bandwidth modulation of gaseous fuel flow at frequencies as high as 500 Hz; The valve was shown to be capable of effecting changes to flame dynamics, heat release, and acoustic signature of an atmospheric combustor. The latter achievement indicates the viability of the Parker piezo valve technology for use in future adaptively controlled systems for the mitigation of combustion instabilities, particularly for attenuating combustion dynamics under ultra-lean conditions.

  16. Hydrogen Storage in Metal-Organic Frameworks

    SciTech Connect (OSTI)

    Omar M. Yaghi

    2012-04-26T23:59:59.000Z

    Conventional storage of large amounts of hydrogen in its molecular form is difficult and expensive because it requires employing either extremely high pressure gas or very low temperature liquid. Because of the importance of hydrogen as a fuel, the DOE has set system targets for hydrogen storage of gravimetric (5.5 wt%) and volumetric (40 g L-1) densities to be achieved by 2015. Given that these are system goals, a practical material will need to have higher capacity when the weight of the tank and associated cooling or regeneration system is considered. The size and weight of these components will vary substantially depending on whether the material operates by a chemisorption or physisorption mechanism. In the latter case, metal-organic frameworks (MOFs) have recently been identified as promising adsorbents for hydrogen storage, although little data is available for their sorption behavior. This grant was focused on the study of MOFs with these specific objectives. (1) To examine the effects of functionalization, catenation, and variation of the metal oxide and organic linkers on the low-pressure hydrogen adsorption properties of MOFs. (2) To develop a strategy for producing MOFs with high surface area and porosity to reduce the dead space and increase the hydrogen storage capacity per unit volume. (3) To functionalize MOFs by post synthetic functionalization with metals to improve the adsorption enthalpy of hydrogen for the room temperature hydrogen storage. This effort demonstrated the importance of open metal sites to improve the adsorption enthalpy by the systematic study, and this is also the origin of the new strategy, which termed isoreticular functionalization and metalation. However, a large pore volume is still a prerequisite feature. Based on our principle to design highly porous MOFs, guest-free MOFs with ultrahigh porosity have been experimentally synthesized. MOF-210, whose BET surface area is 6240 m2 g-1 (the highest among porous solids), takes up 15 wt% of total H2 uptake at 80 bar and 77 K. More importantly, the total H2 uptake by MOF-210 was 2.7 wt% at 80 bar and 298 K, which is the highest number reported for physisorptive materials.

  17. Rate-Based Modeling of Reactive Absorption of CO2 and H2S into Aqueous Methyldiethanolamine

    E-Print Network [OSTI]

    Rochelle, Gary T.

    Rate-Based Modeling of Reactive Absorption of CO2 and H2S into Aqueous Methyldiethanolamine Manuel in the liquid phase. This framework was applied to the selective absorption of H2S from fuel gas containing CO2 primarily by physical absorption. Gas-film resistance is never significant for CO2 absorption. For H2S

  18. Chemical Engineering Journal 87 (2002) 101110 Co-treatment of H2S and toluene in a biotrickling filter

    E-Print Network [OSTI]

    2002-01-01T23:59:59.000Z

    Chemical Engineering Journal 87 (2002) 101­110 Co-treatment of H2S and toluene in a biotrickling-gases contain H2S and a wide range of volatile organic compounds (VOCs). Since co-treatment of odors and VOCs in biotrickling filters is a relatively unexplored area, the simultaneous biotreatment of H2S and toluene (as

  19. An "adiabatic-hindered-rotor" treatment allows para-H2 to be treated as if it were spherical

    E-Print Network [OSTI]

    Le Roy, Robert J.

    An "adiabatic-hindered-rotor" treatment allows para-H2 to be treated as if it were spherical Hui Li­ molecule interactions, the common assumption that para-H2 may be treated as a spherical particle is often K , it is often considered a good approximation to treat para-H2 as a spherical particle.1

  20. Controlled Hydrogen Fleet and Infrastructure Demonstration Project

    SciTech Connect (OSTI)

    Dr. Scott Staley

    2010-03-31T23:59:59.000Z

    This program was undertaken in response to the US Department of Energy Solicitation DE-PS30-03GO93010, resulting in this Cooperative Agreement with the Ford Motor Company and BP to demonstrate and evaluate hydrogen fuel cell vehicles and required fueling infrastructure. Ford initially placed 18 hydrogen fuel cell vehicles (FCV) in three geographic regions of the US (Sacramento, CA; Orlando, FL; and southeast Michigan). Subsequently, 8 advanced technology vehicles were developed and evaluated by the Ford engineering team in Michigan. BP is Ford's principal partner and co-applicant on this project and provided the hydrogen infrastructure to support the fuel cell vehicles. BP ultimately provided three new fueling stations. The Ford-BP program consists of two overlapping phases. The deliverables of this project, combined with those of other industry consortia, are to be used to provide critical input to hydrogen economy commercialization decisions by 2015. The program's goal is to support industry efforts of the US President's Hydrogen Fuel Initiative in developing a path to a hydrogen economy. This program was designed to seek complete systems solutions to address hydrogen infrastructure and vehicle development, and possible synergies between hydrogen fuel electricity generation and transportation applications. This project, in support of that national goal, was designed to gain real world experience with Hydrogen powered Fuel Cell Vehicles (H2FCV) 'on the road' used in everyday activities, and further, to begin the development of the required supporting H2 infrastructure. Implementation of a new hydrogen vehicle technology is, as expected, complex because of the need for parallel introduction of a viable, available fuel delivery system and sufficient numbers of vehicles to buy fuel to justify expansion of the fueling infrastructure. Viability of the fuel structure means widespread, affordable hydrogen which can return a reasonable profit to the fuel provider, while viability of the vehicle requires an expected level of cost, comfort, safety and operation, especially driving range, that consumers require. This presents a classic 'chicken and egg' problem, which Ford believes can be solved with thoughtful implementation plans. The eighteen Ford Focus FCV vehicles that were operated for this demonstration project provided the desired real world experience. Some things worked better than expected. Most notable was the robustness and life of the fuel cell. This is thought to be the result of the full hybrid configuration of the drive system where the battery helps to overcome the performance reduction associated with time related fuel cell degradation. In addition, customer satisfaction surveys indicated that people like the cars and the concept and operated them with little hesitation. Although the demonstrated range of the cars was near 200 miles, operators felt constrained because of the lack of a number of conveniently located fueling stations. Overcoming this major concern requires overcoming a key roadblock, fuel storage, in a manner that permits sufficient quantity of fuel without sacrificing passenger or cargo capability. Fueling infrastructure, on the other hand, has been problematic. Only three of a planned seven stations were opened. The difficulty in obtaining public approval and local government support for hydrogen fuel, based largely on the fear of hydrogen that grew from past disasters and atomic weaponry, has inhibited progress and presents a major roadblock to implementation. In addition the cost of hydrogen production, in any of the methodologies used in this program, does not show a rapid reduction to commercially viable rates. On the positive side of this issue was the demonstrated safety of the fueling station, equipment and process. In the Ford program, there were no reported safety incidents.

  1. Light transfer in bubble sparged photobioreactors for H2 production and CO2 mitigation

    E-Print Network [OSTI]

    Berberoglu, Halil; Yin, Juan; Pilon, Laurent

    2007-01-01T23:59:59.000Z

    carbon dioxide mitigation, ge- netically modi?ed bacteria, reduced pigment, algae, cyanobacteria, bubblebubble sparged photobioreac- tor in order to maximize hydrogen production and carbon

  2. Looking Ahead - Biofuels, H2, & Vehicles: 21st Industry Growth Forum

    SciTech Connect (OSTI)

    Gardner, D.

    2008-10-28T23:59:59.000Z

    This presentation on the future of biofuels, hydrogen, and hybrid vehicles was presented at NREL's 21st Industry Growth Forum in Denver, Colorado, on October 28, 2008.

  3. Hydrogen Generation for Refineries

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Single Cycle Shown for ATB SteamCarbon 3 * ATB reforming * Steamcarbon 3 * Syngas generated during reforming * 70% H 2 * 20% CO * Syngas composition agrees with...

  4. High Temperature Separation of Carbon Dioxide/Hydrogen Mixtures Using Facilitated Supported Ionic Liquid Membranes

    SciTech Connect (OSTI)

    Myers, C.R.; Pennline, H.W.; Luebke, D.R.; Ilconich, J.B.; Dixon, J.K. (Univ. of Notre Dame, Notre Dame, IN); Maginn, E.J. (Univ. of Notre Dame, Notre Dame, IN); Brennecke, J.F. (Univ. of Notre Dame, Notre Dame, IN)

    2008-09-01T23:59:59.000Z

    Efficiently separating CO2 from H2 is one of the key steps in the environmentally responsible uses of fossil fuel for energy production. A wide variety of resources, including petroleum coke, coal, and even biomass, can be gasified to produce syngas (a mixture of COand H2). This gas stream can be further reacted with water to produce CO2 and more H2. Once separated, the CO2 can be stored in a variety of geological formations or sequestered by other means. The H2 can be combusted to operate a turbine, producing electricity, or used to power hydrogen fuel cells. In both cases, onlywater is produced as waste. An amine functionalized ionic liquid encapsulated in a supported ionic liquid membrane (SILM) can separate CO2 from H2 with a higher permeability and selectivity than any known membrane system. This separation is accomplished at elevated temperatures using facilitated transport supported ionic liquid membranes.

  5. Gaseous Hydrogen Delivery Breakout - Strategic Directions for...

    Broader source: Energy.gov (indexed) [DOE]

    Gaseous Hydrogen Delivery Breakout - Strategic Directions for Hydrogen Delivery Workshop Gaseous Hydrogen Delivery Breakout - Strategic Directions for Hydrogen Delivery Workshop...

  6. NATIONAL HYDROGEN ENERGY ROADMAP

    E-Print Network [OSTI]

    NATIONAL HYDROGEN ENERGY ROADMAP NATIONAL HYDROGEN ENERGY ROADMAP . . Toward a More Secure and Cleaner Energy Future for America Based on the results of the National Hydrogen Energy Roadmap Workshop to make it a reality. This Roadmap provides a framework that can make a hydrogen economy a reality

  7. Safetygram #9- Liquid Hydrogen

    Broader source: Energy.gov [DOE]

    Hydrogen is colorless as a liquid. Its vapors are colorless, odorless, tasteless, and highly flammable.

  8. Renewable Hydrogen Production from Biological Systems

    Broader source: Energy.gov (indexed) [DOE]

    Workshop September 24 th , 2013 H 2 production PSIIPSI pathway PSInonphotochemical PQ Dark fermentation H 2 uptake oxyhydrogen reaction photoreduction Photosynthetic H 2 pathways...

  9. Feasibility Study of Hydrogen Production at Existing Nuclear Power Plants

    SciTech Connect (OSTI)

    Stephen Schey

    2009-07-01T23:59:59.000Z

    Cooperative Agreement DE-FC07-06ID14788 was executed between the U.S. Department of Energy, Electric Transportation Applications, and Idaho National Laboratory to investigate the economics of producing hydrogen by electrolysis using electricity generated by nuclear power. The work under this agreement is divided into the following four tasks: Task 1 – Produce Data and Analyses Task 2 – Economic Analysis of Large-Scale Alkaline Electrolysis Task 3 – Commercial-Scale Hydrogen Production Task 4 – Disseminate Data and Analyses. Reports exist on the prospect that utility companies may benefit from having the option to produce electricity or produce hydrogen, depending on market conditions for both. This study advances that discussion in the affirmative by providing data and suggesting further areas of study. While some reports have identified issues related to licensing hydrogen plants with nuclear plants, this study provides more specifics and could be a resource guide for further study and clarifications. At the same time, this report identifies other area of risks and uncertainties associated with hydrogen production on this scale. Suggestions for further study in some of these topics, including water availability, are included in the report. The goals and objectives of the original project description have been met. Lack of industry design for proton exchange membrane electrolysis hydrogen production facilities of this magnitude was a roadblock for a significant period. However, recent design breakthroughs have made costing this facility much more accurate. In fact, the new design information on proton exchange membrane electrolyzers scaled to the 1 kg of hydrogen per second electrolyzer reduced the model costs from $500 to $100 million. Task 1 was delayed when the original electrolyzer failed at the end of its economic life. However, additional valuable information was obtained when the new electrolyzer was installed. Products developed during this study include a process model and a N2H2 economic assessment model (both developed by the Idaho National Laboratory). Both models are described in this report. The N2H2 model closely tracked and provided similar results as the H2A model and was instrumental in assessing the effects of plant availability on price when operated in the shoulder mode for electrical pricing. Differences between the H2A and N2H2 model are included in this report.

  10. The development of a fullerene based hydrogen storage system

    SciTech Connect (OSTI)

    Brosha, E.L.; Davey, J.R.; Garzon, F.H.; Gottesfeld, S.

    1998-11-01T23:59:59.000Z

    This is the final report of a three-year, Laboratory Directed Research and Development (LDRD) project at Los Alamos National Laboratory (LANL). The project objective was to evaluate hydrogen uptake by fullerene substrates and to probe the potential of the hydrogen/fullerene system for hydrogen fuel storage. As part of this project, the authors have completed and tested a fully automated, computer controlled system for measuring hydrogen uptake that is capable of handling both a vacuum of 1 x 10{sup -6} torr and pressures greater than 200 bars. The authors have first established conditions for significant uptake of hydrogen by fullerenes. Subsequently, hydrogenation and dehydrogenation of pure and catalyst-doped C60 was further studied to probe suitability for hydrogen storage applications. C60 {center_dot} H18.7 was prepared at 100 bar H2 and 400 C, corresponding to hydrogen uptake of 2.6 wt%. Dehydrogenation of C60 {center_dot} H18.7 was studied using thermogravimetric and powder x-ray diffraction analysis. The C60 {center_dot} H18.7 molecule was found to be stable up to 430 C in Ar, at which point the release of hydrogen took place simultaneously with the collapse of the fullerene structure. X-ray diffraction analysis performed on C60 {center_dot} H18.7 samples dehydrogenated at 454 C, 475 C, and 600 C showed an increasing volume fraction of amorphous material due to randomly oriented, single-layer graphine sheets. Evolved gas analysis using gas chromatography and mass spectroscopy confirmed the presence of both H{sub 2} and methane upon dehydrogenation, indicating decomposition of the fullerene. The remaining carbon could not be re-hydrogenated. These results provide the first complete evidence for the irreversible nature of fullerene hydrogenation and for limitations imposed on the hydrogenation/dehydrogenation cycle by the limited thermal stability of the molecular crystal of fullerene.

  11. The H$_{2}$ density within spiral and irregular galaxies at high redshift: estimating CO detection limits

    E-Print Network [OSTI]

    Mercedes Mollá; Eduardo Hardy; '{A}ngeles I. Díaz

    2007-01-24T23:59:59.000Z

    We have computed a grid of chemical evolution models for a large set of spiral and irregular theoretical galaxies of different total mass. In our models, the gas phase has two components, the diffuse and the molecular one ($\\rm H_{2}$). It is possible, therefore, to follow the time (or redshift) evolution of the expected density of the $\\rm H_{2}$ phase. We will show the predictions of this gas density at hight redshift, which might be detected with ALMA, in this type of galaxies.

  12. The H2 Double-Slit Experiment: Where Quantum and Classical Physics Meet

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over Our InstagramStructureProposedPAGESafetyTed5,AuditThe FiveBiofuelsGEThe H2The H2

  13. H2 Safety Snapshot - Vol. 2, Issue 2, July 2011 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(Fact Sheet), GeothermalGrid Integration0-1 MarchH-Tank FarmRefuel H-PrizeH2H2

  14. Investigation of H2 Diaphragm Compressors to Enable Low-Cost Long-Life Operation

    SciTech Connect (OSTI)

    Rohatgi, Aashish; Johnson, Kenneth I.

    2013-12-01T23:59:59.000Z

    This is a “short” annual report to DOE Fuel Cell Technology Office describing the research on modeling and materials analysis of diaphragms in a diaphragm-type hydrogen compressor. The compressor design details and diaphragm materials were provided by PDC Machines, Inc., a commercial manufacturer of diaphragm-type hydrogen compressors that PNNL is partnering with in this project

  15. Integrated Ceramic Membrane System for Hydrogen Production

    SciTech Connect (OSTI)

    Schwartz, Joseph; Lim, Hankwon; Drnevich, Raymond

    2010-08-05T23:59:59.000Z

    Phase I was a technoeconomic feasibility study that defined the process scheme for the integrated ceramic membrane system for hydrogen production and determined the plan for Phase II. The hydrogen production system is comprised of an oxygen transport membrane (OTM) and a hydrogen transport membrane (HTM). Two process options were evaluated: 1) Integrated OTM-HTM reactor – in this configuration, the HTM was a ceramic proton conductor operating at temperatures up to 900°C, and 2) Sequential OTM and HTM reactors – in this configuration, the HTM was assumed to be a Pd alloy operating at less than 600°C. The analysis suggested that there are no technical issues related to either system that cannot be managed. The process with the sequential reactors was found to be more efficient, less expensive, and more likely to be commercialized in a shorter time than the single reactor. Therefore, Phase II focused on the sequential reactor system, specifically, the second stage, or the HTM portion. Work on the OTM portion was conducted in a separate program. Phase IIA began in February 2003. Candidate substrate materials and alloys were identified and porous ceramic tubes were produced and coated with Pd. Much effort was made to develop porous substrates with reasonable pore sizes suitable for Pd alloy coating. The second generation of tubes showed some improvement in pore size control, but this was not enough to get a viable membrane. Further improvements were made to the porous ceramic tube manufacturing process. When a support tube was successfully coated, the membrane was tested to determine the hydrogen flux. The results from all these tests were used to update the technoeconomic analysis from Phase I to confirm that the sequential membrane reactor system can potentially be a low-cost hydrogen supply option when using an existing membrane on a larger scale. Phase IIB began in October 2004 and focused on demonstrating an integrated HTM/water gas shift (WGS) reactor to increase CO conversion and produce more hydrogen than a standard water gas shift reactor would. Substantial improvements in substrate and membrane performance were achieved in another DOE project (DE-FC26-07NT43054). These improved membranes were used for testing in a water gas shift environment in this program. The amount of net H2 generated (defined as the difference of hydrogen produced and fed) was greater than would be produced at equilibrium using conventional water gas shift reactors up to 75 psig because of the shift in equilibrium caused by continuous hydrogen removal. However, methanation happened at higher pressures, 100 and 125 psig, and resulted in less net H2 generated than would be expected by equilibrium conversion alone. An effort to avoid methanation by testing in more oxidizing conditions (by increasing CO2/CO ratio in a feed gas) was successful and net H2 generated was higher (40-60%) than a conventional reactor at equilibrium at all pressures tested (up to 125 psig). A model was developed to predict reactor performance in both cases with and without methanation. The required membrane area depends on conditions, but the required membrane area is about 10 ft2 to produce about 2000 scfh of hydrogen. The maximum amount of hydrogen that can be produced in a membrane reactor decreased significantly due to methanation from about 2600 scfh to about 2400 scfh. Therefore, it is critical to eliminate methanation to fully benefit from the use of a membrane in the reaction. Other modeling work showed that operating a membrane reactor at higher temperature provides an opportunity to make the reactor smaller and potentially provides a significant capital cost savings compared to a shift reactor/PSA combination.

  16. Analysis of H2 storage needs for early market non-motive fuel cell applications.

    SciTech Connect (OSTI)

    Johnson, Terry Alan; Moreno, Marcina; Arienti, Marco; Pratt, Joseph William; Shaw, Leo; Klebanoff, Leonard E.

    2012-03-01T23:59:59.000Z

    Hydrogen fuel cells can potentially reduce greenhouse gas emissions and the United States dependence on foreign oil, but issues with hydrogen storage are impeding their widespread use. To help overcome these challenges, this study analyzes opportunities for their near-term deployment in five categories of non-motive equipment: portable power, construction equipment, airport ground support equipment, telecom backup power, and man-portable power and personal electronics. To this end, researchers engaged end users, equipment manufacturers, and technical experts via workshops, interviews, and electronic means, and then compiled these data into meaningful and realistic requirements for hydrogen storage in specific target applications. In addition to developing these requirements, end-user benefits (e.g., low noise and emissions, high efficiency, potentially lower maintenance costs) and concerns (e.g., capital cost, hydrogen availability) of hydrogen fuel cells in these applications were identified. Market data show potential deployments vary with application from hundreds to hundreds of thousands of units.

  17. Hydrogen Permeability and Integrity of Hydrogen Delivery Pipelines...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Permeability and Integrity of Hydrogen Delivery Pipelines Hydrogen Permeability and Integrity of Hydrogen Delivery Pipelines Project Objectives: To gain basic understanding of...

  18. Hydrogen Delivery Technologies and Systems- Pipeline Transmission of Hydrogen

    Broader source: Energy.gov [DOE]

    Hydrogen Delivery Technologies and Systems - Pipeline Transmission of Hydrogen. Design and operations standards and materials for hydrogen and natural gas pipelines.

  19. Hydrogen Fuel Cell Bus Evaluation: Report for the 2001 Hydrogen...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Bus Evaluation: Report for the 2001 Hydrogen Program Review Hydrogen Fuel Cell Bus Evaluation: Report for the 2001 Hydrogen Program Review This paper, presented at the 2001 DOE...

  20. DOE Hydrogen and Fuel Cells Program Record 5037: Hydrogen Storage...

    Broader source: Energy.gov (indexed) [DOE]

    5037: Hydrogen Storage Materials - 2004 vs. 2006 DOE Hydrogen and Fuel Cells Program Record 5037: Hydrogen Storage Materials - 2004 vs. 2006 This program record from the Department...

  1. Hydrogen Supply: Cost Estimate for Hydrogen Pathways-Scoping...

    Broader source: Energy.gov (indexed) [DOE]

    Supply: Cost Estimate for Hydrogen Pathways-Scoping Analysis. January 22, 2002-July 22, 2002 Hydrogen Supply: Cost Estimate for Hydrogen Pathways-Scoping Analysis. January 22,...

  2. Hydrogen Delivery Liquefaction & Compression

    E-Print Network [OSTI]

    temperature refrigeration Magnetic refrigerators Acoustic refrigerators #12;12 Challenges: More cost effective Refrigeration GN2 to N2 Liquefier To Feed H2 Flash Compressor H2 Recycle Compressor LN2 Add. To Storage/Fill #12 Higher efficiency compressors and expanders More efficient refrigeration Lower cost high

  3. Formation of molecular hydrogen on amorphous silicate surfaces

    E-Print Network [OSTI]

    Ling Li; Giulio Manico; Emanuele Congiu; Joe Roser; Sol Swords; Hagai B. Perets; Adina Lederhendler; Ofer Biham; John Robert Brucato; Valerio Pirronello; Gianfranco Vidali

    2007-09-16T23:59:59.000Z

    Experimental results on the formation of molecular hydrogen on amorphous silicate surfaces are presented and analyzed using a rate equation model. The energy barriers for the relevant diffusion and desorption processes are obtained. They turn out to be significantly higher than those obtained for polycrystalline silicates, demonstrating the importance of grain morphology. Using these barriers we evaluate the efficiency of molecular hydrogen formation on amorphous silicate grains under interstellar conditions. It is found that unlike polycrystalline silicates, amorphous silicate grains are efficient catalysts of H_2 formation in diffuse interstellar clouds.

  4. Electron-Nuclear Energy Sharing in Above-Threshold Multiphoton Dissociative Ionization of H2

    E-Print Network [OSTI]

    Thumm, Uwe

    Electron-Nuclear Energy Sharing in Above-Threshold Multiphoton Dissociative Ionization of H2 J. Wu­4], where the photon energy is shared by the freed electrons and the nuclear fragments. For the molecular ionization [10­15], and the imaging of inter- nuclear distance using nuclear kinetic energy release spec- tra

  5. Conductivity measurements on H2O-bearing CO2-rich fluids

    SciTech Connect (OSTI)

    Capobianco, Ryan [Virginia Polytechnic Institute and State University; Gruszkiewicz, Miroslaw {Mirek} S [ORNL; Bodnar, Robert [Virginia Polytechnic Institute and State University; Rimstidt, J. Donald [Virginia Polytechnic Institute and State University

    2015-01-01T23:59:59.000Z

    Recent studies report rapid corrosion of metals and carbonation of minerals in contact with carbon dioxide containing trace amounts of dissolved water. One explanation for this behavior is that addition of small amounts of H2O to CO2 leads to significant ionization within the fluid, thus promoting reactions at the fluid-solid interface analogous to corrosion associated with aqueous fluids. The extent of ionization in the bulk CO2 fluid was determined using a flow-through conductivity cell capable of detecting very low conductivities. Experiments were conducted from 298 to 473 K and 7.39 to 20 MPa with H2O concentrations up to ~1600 ppmw (xH2O 3.9 10-3), corresponding to the H2O solubility limit in liquid CO2 at ambient temperature. All solutions showed conductivities <10 nS/cm, indicating that the solutions were essentially ion-free. This observation suggests that the observed corrosion and carbonation reactions are not the result of ionization in CO2-rich bulk phase, but does not preclude ionization in the fluid at the fluid-solid interface.

  6. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for

    E-Print Network [OSTI]

    Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Applications for transportation. Fuel cell systems will have to be cost-competitive with conventional and advanced vehicle cell vehicles have the potential to eliminate the need for oil in the transportation sector. Fuel cell

  7. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for

    E-Print Network [OSTI]

    Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Applications: 2010 Update fuel cell vehicles have the potential to eliminate the need for oil in the transportation sector. Fuel, and biomass. Thus, fuel cell vehicles offer an environmentally clean and energysecure transportation pathway

  8. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for

    E-Print Network [OSTI]

    Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems for Automotive Applications vehicles offer an environmentally clean and energy-secure transportation pathway. Fuel cell systems number of vehicles it represents, DOE has established detailed cost targets for automotive fuel cell

  9. DC H2O: What's on Tap? Annual Progress Report for FY 2004

    E-Print Network [OSTI]

    District of Columbia, University of the

    for distributing treated water to DC residents has taken the brunt of the blame and has developed mechanisms. Project resources have secured a GPS unit and additional resources have already been allocated for GIS as a part of the 4-H Youth Cyber Camp. And as such, will incorporate the technological aspects of the DC H2O

  10. Gibbs Free Energy of Formation of Zircon from Measurement of Solubility in H2O

    E-Print Network [OSTI]

    Manning, Craig

    Gibbs Free Energy of Formation of Zircon from Measurement of Solubility in H2O Robert C. Newton, the data constrain the Gibbs free energy of zircon from its oxides at 298 K, 105 Pa, to be À19.3071.16 k

  11. Quenching of metastable states of antiprotonic helium atoms by collisions with H$_2$ molecules

    E-Print Network [OSTI]

    Ketzer, B; Von Egidy, T; Maierl, C; Pohl, R; Eades, John; Widmann, E; Yamazaki, T; Kumakura, M; Morita, N; Hayano, R S; Hori, Masaki; Ishikawa, T; Torii, H A; Sugai, I; Horváth, D

    1998-01-01T23:59:59.000Z

    Laser resonance transitions between normally metastable states of antiprotonic helium atoms were induced making use of state dependent quenching effects caused by trace admixtures of \\mbox{H$_2$}\\ to the target helium gas. With this method of ``\\mbox{H$_2$}-assisted inverse resonances'' the decay rates of the states $(n,l)=(39,l),\\ l=36,37,38$ and $(38,l),\\ l=35,36,37$ of \\mbox{$\\overline{\\mathrm{p}}$}\\mbox{He$^{+}$}\\ were determined as a function of the \\mbox{H$_2$}\\ admixture. The quenching cross sections at 30~K deduced therefrom for the states with $n=39$ were found to be of the order of the geometrical cross section for \\mbox{$\\overline{\\mathrm{p}}$}\\mbox{He$^{+}$}-\\mbox{H$_2$}\\ collisions ($2\\cdot 10^{-15}$~cm$^2$), with a moderate decrease with increasing $l$. Within a given cascade with constant $v=n-l-1$, the quenching cross sections for states with $n=38$ are smaller by a factor of 4--6 than those for states with $n=39$.

  12. ENVIRONMENTAL BIOTECHNOLOGY Influence of trace erythromycin and erythromycin-H2O

    E-Print Network [OSTI]

    Alvarez-Cohen, Lisa

    ENVIRONMENTAL BIOTECHNOLOGY Influence of trace erythromycin and erythromycin-H2O on carbon # The Author(s) 2009. This article is published with open access at Springerlink.com Abstract Three sequencing supplementary material The online version of this article (doi:10.1007/s00253-009-2201-7) contains supplementary

  13. Molecular H2O as carrier for oxygen diffusion in hydrous silicate melts

    E-Print Network [OSTI]

    Zhang, Youxue

    Molecular H2O as carrier for oxygen diffusion in hydrous silicate melts H. Behrens a,, Y. Zhang b water is known to dramatically enhance oxygen diffusion in silicate melts, glasses and minerals in the diffusion of water and oxygen in silicates, Earth Planet. Sci. Lett., 103 (1991) 228­240.]. Here we report

  14. 11/19/2013 Quick Start Guide Mentor 103013 Huskie-2-Huskie (H2H) Mentor

    E-Print Network [OSTI]

    Karonis, Nicholas T.

    11/19/2013 Quick Start Guide Mentor 103013 Huskie-2-Huskie (H2H) Mentor Quick Start Guide Create a Mentor Account 1. Go to http://niumentor.experience.com. 2. Click the Create Mentor Account link . . . Create a Mentor account. You must use a different email than you use to post jobs to Huskies Get Hired. 3

  15. Retrofitting existing chemical scrubbers to biotrickling filters for H2S emission control

    E-Print Network [OSTI]

    sulfide (H2S) in the converted scrubber was possible even at gas contact times as low as 1.6 s. That is 8 of objectionable odors from these facilities is a major problem. Odors emitted by publicly owned treatment works scrubbing in packed-bed towers is an estab- lished technique and is effective at gas contact times as short

  16. Formation of CO precursors during char gasification with O2, CO2 and H2O

    E-Print Network [OSTI]

    Truong, Thanh N.

    Formation of CO precursors during char gasification with O2, CO2 and H2O Alejandro Montoya a are presented to get insight into an unified mechanism of uncatalyzed carbon gasification. D 2002 Elsevier Science B.V. All rights reserved. Keywords: Gasification; Chemisorption; Molecular simulation; Surface

  17. H_2 Absorption and Fluorescence for Gamma Ray Bursts in Molecular Clouds

    E-Print Network [OSTI]

    B. T. Draine

    1999-07-16T23:59:59.000Z

    If a gamma ray burst with strong UV emission occurs in a molecular cloud, there will be observable consequences resulting from excitation of the surrounding H2. The UV pulse from the GRB will pump H2 into vibrationally-excited levels which produce strong absorption at wavelengths < 1650 A. As a result, both the prompt flash and later afterglow will exhibit strong absorption shortward of 1650 A, with specific spectroscopic features. Such a cutoff in the emission from GRB 980329 may already have been observed by Fruchter et al.; if so, GRB 980329 was at redshift 3.0 < z < 4.4 . BVRI photometry of GRB 990510 could also be explained by H2 absorption if GRB 990510 is at redshift 1.6 < z < 2.3. The fluorescence accompanying the UV pumping of the H2 will result in UV emission from the GRB which can extend over days or months, depending on parameters of the ambient medium and beaming of the GRB flash. The 7.5-13.6 eV fluorescent luminosity is \\sim 10^{41.7} erg/s for standard estimates of the parameters of the GRB and the ambient medium. Spectroscopy can distinguish this fluorescent emission from other possible sources of transient optical emission, such as a supernova.

  18. On the likelihood of decompression sickness during H2 biochemical decompression in pigs

    E-Print Network [OSTI]

    Fahlman, Andreas

    dt, where Pamb is ambient pressure and is a time constant. The probability of DCS [P by influencing the gas kinetics. The measure of H2 metabolism was based on either the total microbial activity injected into the animals (Inj), or as the CH4 release rate (V CH4) from individual animals, assuming

  19. aisi-348 h2o b4c: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    200 ml 60 g Acrylamide 1.6 g Methylene Bis acrylamide (1:37.5) Bring to 200 27.5 g Boric Acid 3.72 g Na2EDTA-2dH2O (ultrapure) 40% Acrylamide Stock Solution For Nucleic Acid...

  20. Evaluation of Protected Metal Hydride Slurries in a H2 Mini-

    E-Print Network [OSTI]

    waste heat can be used for hot water or space heating in buildings (i.e. "cogen") Distributed FCPS if dehydrogenation heat can be supplied by waste heat (e.g. fuel cell) Requires less space than low pressure cH2

  1. Critical Review Microbial Electrolysis Cells for High Yield Hydrogen Gas

    E-Print Network [OSTI]

    sources such as wind, solar or biomass, but the energy requirements are high (5.6 kWh/ m3H2) and typical A S S E , , § A N D R E N ´E A . R O Z E N D A L | Hydrogen Energy Center, and Department of Civil, The Netherlands, and Advanced Water Management Centre (AWMC), The University of Queensland, Qld 4072, Australia

  2. Tetrakis(acetonitrile)copper(I) hydrogen oxalateoxalic acidacetonitrile

    E-Print Network [OSTI]

    Müller, Peter

    Tetrakis(acetonitrile)copper(I) hydrogen oxalate­oxalic acid­acetonitrile (1/0.5/0.5) A. Timothy)Á0.5C2H2O4Á- 0.5CH3CN, the CuI ion is coordinated by the N atoms of four acetonitrile ligands. The acetonitrile solvent molecule is disordered across an inversion center and was refined with half occupancy

  3. Hydrogen energy systems studies

    SciTech Connect (OSTI)

    Ogden, J.M.; Kreutz, T.G.; Steinbugler, M. [Princeton Univ., NJ (United States)] [and others

    1996-10-01T23:59:59.000Z

    In this report the authors describe results from technical and economic assessments carried out during the past year with support from the USDOE Hydrogen R&D Program. (1) Assessment of technologies for small scale production of hydrogen from natural gas. Because of the cost and logistics of transporting and storing hydrogen, it may be preferable to produce hydrogen at the point of use from more readily available energy carriers such as natural gas or electricity. In this task the authors assess near term technologies for producing hydrogen from natural gas at small scale including steam reforming, partial oxidation and autothermal reforming. (2) Case study of developing a hydrogen vehicle refueling infrastructure in Southern California. Many analysts suggest that the first widespread use of hydrogen energy is likely to be in zero emission vehicles in Southern California. Several hundred thousand zero emission automobiles are projected for the Los Angeles Basin alone by 2010, if mandated levels are implemented. Assuming that hydrogen vehicles capture a significant fraction of this market, a large demand for hydrogen fuel could evolve over the next few decades. Refueling a large number of hydrogen vehicles poses significant challenges. In this task the authors assess near term options for producing and delivering gaseous hydrogen transportation fuel to users in Southern California including: (1) hydrogen produced from natural gas in a large, centralized steam reforming plant, and delivered to refueling stations via liquid hydrogen truck or small scale hydrogen gas pipeline, (2) hydrogen produced at the refueling station via small scale steam reforming of natural gas, (3) hydrogen produced via small scale electrolysis at the refueling station, and (4) hydrogen from low cost chemical industry sources (e.g. excess capacity in refineries which have recently upgraded their hydrogen production capacity, etc.).

  4. H2 Enrichment with Simultaneous CO2 Concentration in a Membrane Reactor

    SciTech Connect (OSTI)

    Taylor, C.E.; Morreale, B.; Howard, B.H.; Killmeyer, R.P

    2007-01-01T23:59:59.000Z

    NETL envisions that the gasification of carbonaceous feedstocks may be the near- to mid-term sources of hydrogen for the transition to a renewable, hydrogen-based economy. However, the environmental impacts associated with the generation and emission of greenhouses gases from the gasification process remains a substantial concern. Therefore, NETL has devoted substantial resources towards the identification of efficient hydrogen separation and carbon capture/sequestration technologies. Hydrogen membranes integrated into a water-gas shift membrane reactor have been identified as a promising means of maximizing the production of pure hydrogen while simultaneously yielding a high-pressure, concentrated CO2 containing stream ready for sequestration. Research groups, including NETL, are exploring the viability of dense metal hydrogen membrane technologies to enhance the production and separation of hydrogen as well as the capture of carbon dioxide from the coal gasification process. Areas of research to ensure the success of dense metal membrane technologies for implementation into the gasification scheme includes the fabrication of thin metallic films and support materials, an understanding of the interaction of membrane materials in the presence of both major and minor gas constituents, chemical and temperature induced morphological changes and the identification of new membrane materials through experimental and computational exploration.

  5. The Bumpy Road to Hydrogen

    E-Print Network [OSTI]

    Sperling, Dan; Ogden, Joan M

    2006-01-01T23:59:59.000Z

    will trump hydrogen and fuel cell vehicles. Advocates ofbenefits sooner than hydrogen and fuel cells ever could.emissions from a hydrogen fuel cell vehicle will be about

  6. Liquid Hydrogen Absorber for MICE

    E-Print Network [OSTI]

    Ishimoto, S.

    2010-01-01T23:59:59.000Z

    REFERENCES Figure 5: Liquid hydrogen absorber and test6: Cooling time of liquid hydrogen absorber. Eight CernoxLIQUID HYDROGEN ABSORBER FOR MICE S. Ishimoto, S. Suzuki, M.

  7. Hydrogen Bus Technology Validation Program

    E-Print Network [OSTI]

    Burke, Andy; McCaffrey, Zach; Miller, Marshall; Collier, Kirk; Mulligan, Neal

    2005-01-01T23:59:59.000Z

    and evaluate hydrogen enriched natural gas (HCNG) enginewas to demonstrate that hydrogen enriched natural gas (HCNG)characteristics of hydrogen enriched natural gas combustion,

  8. Hydrogen in semiconductors and insulators

    E-Print Network [OSTI]

    Van de Walle, Chris G.

    2007-01-01T23:59:59.000Z

    the electronic level of hydrogen (thick red bar) was notdescribing the behavior of hydrogen atoms as impuritiesenergy of interstitial hydrogen as a function of Fermi level

  9. Wind-To-Hydrogen Energy Pilot Project

    SciTech Connect (OSTI)

    Ron Rebenitsch; Randall Bush; Allen Boushee; Brad G. Stevens; Kirk D. Williams; Jeremy Woeste; Ronda Peters; Keith Bennett

    2009-04-24T23:59:59.000Z

    WIND-TO-HYDROGEN ENERGY PILOT PROJECT: BASIN ELECTRIC POWER COOPERATIVE In an effort to address the hurdles of wind-generated electricity (specifically wind's intermittency and transmission capacity limitations) and support development of electrolysis technology, Basin Electric Power Cooperative (BEPC) conducted a research project involving a wind-to-hydrogen system. Through this effort, BEPC, with the support of the Energy & Environmental Research Center at the University of North Dakota, evaluated the feasibility of dynamically scheduling wind energy to power an electrolysis-based hydrogen production system. The goal of this project was to research the application of hydrogen production from wind energy, allowing for continued wind energy development in remote wind-rich areas and mitigating the necessity for electrical transmission expansion. Prior to expending significant funding on equipment and site development, a feasibility study was performed. The primary objective of the feasibility study was to provide BEPC and The U.S. Department of Energy (DOE) with sufficient information to make a determination whether or not to proceed with Phase II of the project, which was equipment procurement, installation, and operation. Four modes of operation were considered in the feasibility report to evaluate technical and economic merits. Mode 1 - scaled wind, Mode 2 - scaled wind with off-peak, Mode 3 - full wind, and Mode 4 - full wind with off-peak In summary, the feasibility report, completed on August 11, 2005, found that the proposed hydrogen production system would produce between 8000 and 20,000 kg of hydrogen annually depending on the mode of operation. This estimate was based on actual wind energy production from one of the North Dakota (ND) wind farms of which BEPC is the electrical off-taker. The cost of the hydrogen produced ranged from $20 to $10 per kg (depending on the mode of operation). The economic sensitivity analysis performed as part of the feasibility study showed that several factors can greatly affect, both positively and negatively, the "per kg" cost of hydrogen. After a September 15, 2005, meeting to evaluate the advisability of funding Phase II of the project DOE concurred with BEPC that Phase I results did warrant a "go" recommendation to proceed with Phase II activities. The hydrogen production system was built by Hydrogenics and consisted of several main components: hydrogen production system, gas control panel, hydrogen storage assembly and hydrogen-fueling dispenser The hydrogen production system utilizes a bipolar alkaline electrolyzer nominally capable of producing 30 Nm3/h (2.7 kg/h). The hydrogen is compressed to 6000 psi and delivered to an on-site three-bank cascading storage assembly with 80 kg of storage capacity. Vehicle fueling is made possible through a Hydrogenics-provided gas control panel and dispenser able to fuel vehicles to 5000 psi. A key component of this project was the development of a dynamic scheduling system to control the wind energy's variable output to the electrolyzer cell stacks. The dynamic scheduling system received an output signal from the wind farm, processed this signal based on the operational mode, and dispatched the appropriate signal to the electrolyzer cell stacks. For the study BEPC chose to utilize output from the Wilton wind farm located in central ND. Site design was performed from May 2006 through August 2006. Site construction activities were from August to November 2006 which involved earthwork, infrastructure installation, and concrete slab construction. From April - October 2007, the system components were installed and connected. Beginning in November 2007, the system was operated in a start-up/shakedown mode. Because of numerous issues, the start-up/shakedown period essentially lasted until the end of January 2008, at which time a site acceptance test was performed. Official system operation began on February 14, 2008, and continued through the end of December 2008. Several issues continued to prevent consistent operation, resulting in operation o

  10. A RhxSy/C Catalyst for the Hydrogen Oxidation and Hydrogen Evolution Reactions in HBr

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Masud, Jahangir; Nguyena, Trung V.; Singh, Nirala; McFarland, Eric; Ikenberry, Myles; Hohn, Keith; Pan, Chun-Jern; Hwang, Bing-Joe

    2015-01-01T23:59:59.000Z

    Rhodium sulfide (Rh2S3) on carbon support was synthesized by refluxing rhodium chloride with ammonium thiosulfate. Thermal treatment of Rh2S3 at high temperatures (600°C to 850°C) in presence of argon resulted in the transformation of Rh2S3 into Rh3S4, Rh17S15 and Rh which were characterized by TGA/DTA, XRD, EDX, and deconvolved XPS analyses. The catalyst particle size distribution ranged from 3 to 12 nm. Cyclic voltammetry and rotating disk electrode measurements were used to evaluate the catalytic activity for hydrogen oxidation and evolution reactions in H2SO4 and HBr solutions. The thermally treated catalysts show high activity for the hydrogen reactions. The exchangemore »current densities (io) of the synthesized RhxSy catalysts in H2-saturated 1M H2SO4 and 1M HBr for HER and HOR were 0.9 mA/cm2 to 1.0 mA/cm2 and 0.8 to 0.9 mA/cm2, respectively. The lower io values obtained in 1M HBr solution compared to in H2SO4 might be due to the adsorption of Br- on the active surface. Stable electrochemical active surface area (ECSA) of RhxSy catalyst was obtained for CV scan limits between 0 V and 0.65 V vs. RHE. Scans with upper voltage limit beyond 0.65 V led to decreased and unreproducible ECSA measurements.« less

  11. Acidic Ionic Liquid/Water Solution as Both Medium and Proton Source for Electrocatalytic H2 Evolution by [Ni(P2N2)2]2+ Complexes

    SciTech Connect (OSTI)

    Pool, Douglas H.; Stewart, Michael P.; O'Hagan, Molly J.; Shaw, Wendy J.; Roberts, John A.; Bullock, R. Morris; DuBois, Daniel L.

    2012-09-25T23:59:59.000Z

    The electrocatalytic reduction of protons to H2 by [Ni(PPh2NC6H4-hex2)2](BF4)2 (where PPh2NC6H4-hex2 = 1,5-di(4-n-hexylphenyl)-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane) in the highly acidic ionic liquid dibutylformamidium bis(trifluoromethanesulfonyl)amide shows a strong dependence on added water. A turnover frequency of 43,000-53,000 s-1 has been measured for hydrogen production at 25 °C when the mole fraction of water (?H2O) is 0.72. The same catalyst in acetonitrile with added dimethylformamidium trifluoromethanesulfonate and water has a turnover frequency of 720 s?1. Thus the use of an ionic liquid/aqueous solution enhances the observed catalytic rates by more than a factor of 50 compared to acids in traditional organic solvents such as acetonitrile. Complexes [Ni(PPh2NC6H4X2)2](BF4)2 (X = H, OMe, CH2P(O)(OEt)2, Br) are also catalysts in the ionic liquid/water mixture, and the observed catalytic rates correlate with the hydrophobicity of X. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

  12. Fluidizable Catalysts for Hydrogen Production from Biomass

    E-Print Network [OSTI]

    HyOz + H2O(g) H2 + xCO Water gas shift: H2O + CO CO2 + H2 Gasification: C + H2O(g) COx + H2 #12;Steam/Deactivation Mechanisms Add pyrolysis microreactor capability Coking and gasification Water gas shift Reforming.7 Catalyst Improvements: K2O Improves Gasification Milestone: Improve catalyst gasification performance

  13. Spitzer observations of hydrogen deuteride

    E-Print Network [OSTI]

    David A. Neufeld; Joel D. Green; David J. Hollenbach; Paule Sonnentrucker; Gary J. Melnick; Edwin A. Bergin; Ronald L. Snell; William J. Forrest; Dan M. Watson; Michael J. Kaufman

    2006-06-26T23:59:59.000Z

    We report the detection of interstellar hydrogen deuteride (HD) toward the supernova remnant IC443, and the tentative detection of HD toward the Herbig Haro objects HH54 and HH7 and the star forming region GGD37 (Cepheus A West). Our detections are based upon spectral line mapping observations of the R(3) and R(4) rotational lines of HD, at rest wavelengths of 28.502 and 23.034 micron respectively, obtained using the Infrared Spectrograph onboard the Spitzer Space Telescope. The HD R(4)/R(3) line intensity ratio promises to be a valuable probe of the gas pressure in regions where it can be observed. The derived HD/H2 abundance ratios are 1.19(+0.35/-0.24)E-5, 1.80(+0.54/-0.32)E-5, and 1.41(+0.46/-0.33)E-5 respectively (68.3% confidence limits, based upon statistical errors alone) for IC443 (clump C), HH54, and HH7. If HD is the only significant reservoir of gas-phase deuterium in these sources, the inferred HD/H2 ratios are all consistent with a gas-phase elemental abundance [n(D)/n(H)](gas) ~ 7.5E-6, a factor 2 - 3 below the values obtained previously from observations of atomic deuterium in the local bubble and the Galactic halo. However, similarly low gas-phase deuterium abundances have been inferred previously for molecular gas clouds in the Orion region, and in atomic clouds along sight-lines within the Galactic disk to stars more distant than 500 pc from the Sun.

  14. Gaseous Hydrogen Delivery Breakout- Strategic Directions for Hydrogen Delivery Workshop

    Broader source: Energy.gov [DOE]

    Targets, barriers and research and development priorities for gaseous delivery of hydrogen through hydrogen and natural gas pipelines.

  15. The H2 Double-Slit Experiment: Where Quantum and Classical Physics...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4.0 and 11.0.1, the researchers used electrons instead of light and the nuclei of the hydrogen molecule as the slits. The experiment revealed that only one "observing" electron...

  16. Mass Production Cost Estimation for Direct H2 PEM Fuel Cell Systems...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    estimates for material and manufacturing costs of complete 80 kWnet direct-hydrogen proton exchange membrane fuel cell systems suitable for powering light-duty automobiles. Mass...

  17. Method and Pd/V2 O5 device for H2 detection

    DOE Patents [OSTI]

    Liu, Ping (San Diego, CA); Tracy, C. Edwin (Golden, CO); Pitts, J. Roland (Lakewood, CO); Smith, II, R. Davis (Golden, CO); Lee, Se-Hee (Lakewood, CO)

    2011-12-27T23:59:59.000Z

    Methods and Pd/V.sub.2O.sub.5 devices for hydrogen detection are disclosed. An exemplary method of preparing an improved sensor for chemochromic detection of hydrogen gas over a wide response range exhibits stability during repeated coloring/bleaching cycles upon exposure and removal of hydrogen gas. The method may include providing a substrate. The method may also include depositing a V.sub.20.sub.5 layer that functions as a H.sub.2 insertion host in a Pd/V.sub.20.sub.5 hydrogen sensor to be formed on said substrate. The method may also include depositing a Pd layer onto said V.sub.20.sub.5 layer; said Pd layer functioning as an optical modulator.

  18. DOE Hydrogen, Fuel Cells and Infrastructure Technologies Program Integrated Hydrogen Production, Purification and Compression System

    SciTech Connect (OSTI)

    Tamhankar, Satish; Gulamhusein, Ali; Boyd, Tony; DaCosta, David; Golben, Mark

    2011-06-30T23:59:59.000Z

    The project was started in April 2005 with the objective to meet the DOE target of delivered hydrogen of <$1.50/gge, which was later revised by DOE to $2-$3/gge range for hydrogen to be competitive with gasoline as a fuel for vehicles. For small, on-site hydrogen plants being evaluated at the time for refueling stations (the 'forecourt'), it was determined that capital cost is the main contributor to the high cost of delivered hydrogen. The concept of this project was to reduce the cost by combining unit operations for the entire generation, purification, and compression system (refer to Figure 1). To accomplish this, the Fluid Bed Membrane Reactor (FBMR) developed by MRT was used. The FBMR has hydrogen selective, palladium-alloy membrane modules immersed in the reformer vessel, thereby directly producing high purity hydrogen in a single step. The continuous removal of pure hydrogen from the reformer pushes the equilibrium 'forward', thereby maximizing the productivity with an associated reduction in the cost of product hydrogen. Additional gains were envisaged by the integration of the novel Metal Hydride Hydrogen Compressor (MHC) developed by Ergenics, which compresses hydrogen from 0.5 bar (7 psia) to 350 bar (5,076 psia) or higher in a single unit using thermal energy. Excess energy from the reformer provides up to 25% of the power used for driving the hydride compressor so that system integration improved efficiency. Hydrogen from the membrane reformer is of very high, fuel cell vehicle (FCV) quality (purity over 99.99%), eliminating the need for a separate purification step. The hydride compressor maintains hydrogen purity because it does not have dynamic seals or lubricating oil. The project team set out to integrate the membrane reformer developed by MRT and the hydride compression system developed by Ergenics in a single package. This was expected to result in lower cost and higher efficiency compared to conventional hydrogen production technologies. The overall objective was to develop an integrated system to directly produce high pressure, high-purity hydrogen from a single unit, which can meet the DOE cost H2 cost target of $2 - $3/gge when mass produced. The project was divided into two phases with the following tasks and corresponding milestones, targets and decision points. Phase 1 - Task 1 - Verify feasibility of the concept, perform a detailed techno-economic analysis, and develop a test plan; and Task 2: Build and experimentally test a Proof of Concept (POC) integrated membrane reformer/metal hydride compressor system. Phase 2 - Task 3: Build an Advanced Prototype (AP) system with modifications based on POC learning and demonstrate at a commercial site; and Task 4: Complete final product design for mass manufacturing units capable of achieving DOE 2010 H2 cost and performance targets.

  19. Gaseous Hydrogen Delivery Breakout

    E-Print Network [OSTI]

    Gaseous Hydrogen Delivery Breakout Strategic Directions for Hydrogen Delivery Workshop May 7 detection Pipeline Safety: odorants, flame visibility Compression: cost, reliability #12;Breakout Session goal of a realistic, multi-energy distribution network model Pipeline Technology Improved field

  20. Hydrogen transport membranes

    DOE Patents [OSTI]

    Mundschau, Michael V.

    2005-05-31T23:59:59.000Z

    Composite hydrogen transport membranes, which are used for extraction of hydrogen from gas mixtures are provided. Methods are described for supporting metals and metal alloys which have high hydrogen permeability, but which are either too thin to be self supporting, too weak to resist differential pressures across the membrane, or which become embrittled by hydrogen. Support materials are chosen to be lattice matched to the metals and metal alloys. Preferred metals with high permeability for hydrogen include vanadium, niobium, tantalum, zirconium, palladium, and alloys thereof. Hydrogen-permeable membranes include those in which the pores of a porous support matrix are blocked by hydrogen-permeable metals and metal alloys, those in which the pores of a porous metal matrix are blocked with materials which make the membrane impervious to gases other than hydrogen, and cermets fabricated by sintering powders of metals with powders of lattice-matched ceramic.

  1. Hydrogen Fuel Quality (Presentation)

    SciTech Connect (OSTI)

    Ohi, J.

    2007-05-17T23:59:59.000Z

    Jim Ohi of NREL's presentation on Hydrogen Fuel Quality at the 2007 DOE Hydrogen Program Annual Merit Review and Peer Evaluation on May 15-18, 2007 in Arlington, Virginia.

  2. Questions and Issues on Hydrogen Pipeline Transmission of Hydrogen

    E-Print Network [OSTI]

    Questions and Issues on Hydrogen Pipelines Pipeline Transmission of Hydrogen Doe Hydrogen Pipeline Working Group Meeting August 31, 2005 #12;Pipeline Transmission of Hydrogen --- 2 Copyright: Air Liquide Transmission of Hydrogen --- 3 Copyright: #12;Pipeline Transmission of Hydrogen --- 4 Copyright: 3. Special

  3. High H2 Storage of Hexagonal Metal-Organic Frameworks from First-Principles-Based Grand Canonical Monte Carlo Simulations

    E-Print Network [OSTI]

    Goddard III, William A.

    High H2 Storage of Hexagonal Metal-Organic Frameworks from First-Principles-Based Grand Canonical IRMOF-2-60, which we calculate to bind 9.7 wt % H2 storage at 77 K and 70 bar, the highest known value even at ambient temperatures. For example, IRMOF-2-96-Li leads to 6.0 wt % H2 storage at 273 K and 100

  4. Webinar: Hydrogen Refueling Protocols

    Broader source: Energy.gov [DOE]

    Video recording and text version of the webinar titled, Hydrogen Refueling Protocols, originally presented on February 22, 2013.

  5. Hydrogen Technologies Safety Guide

    SciTech Connect (OSTI)

    Rivkin, C.; Burgess, R.; Buttner, W.

    2015-01-01T23:59:59.000Z

    The purpose of this guide is to provide basic background information on hydrogen technologies. It is intended to provide project developers, code officials, and other interested parties the background information to be able to put hydrogen safety in context. For example, code officials reviewing permit applications for hydrogen projects will get an understanding of the industrial history of hydrogen, basic safety concerns, and safety requirements.

  6. Sensitive hydrogen leak detector

    DOE Patents [OSTI]

    Myneni, Ganapati Rao (Yorktown, VA)

    1999-01-01T23:59:59.000Z

    A sensitive hydrogen leak detector system using passivation of a stainless steel vacuum chamber for low hydrogen outgassing, a high compression ratio vacuum system, a getter operating at 77.5 K and a residual gas analyzer as a quantitative hydrogen sensor.

  7. A Herschel/HIFI Legacy Survey of HF and H2O in the Galaxy: Probing Diffuse Molecular Cloud Chemistry

    E-Print Network [OSTI]

    Sonnentrucker, P; Neufeld, D A; Flagey, N; Gerin, M; Goldsmith, P; Lis, D; Monje, R

    2015-01-01T23:59:59.000Z

    We combine Herschel observations of a total of 12 sources to construct the most uniform survey of HF and H2O in our Galactic disk. Both molecules are detected in absorption along all sight lines. The high spectral resolution of the Heterodyne Instrument for the Far-Infrared (HIFI) allows us to compare the HF and H2O distributions in 47 diffuse cloud components sampling the disk. We find that the HF and H2O velocity distributions follow each other almost perfectly and establish that HF and H2O probe the same gas-phase volume. Our observations corroborate theoretical predictions that HF is a sensitive tracer of H2 in diffuse clouds, down to molecular fractions of only a few percent. Using HF to trace H2 in our sample, we find that the N(H2O)-to-N(HF) ratio shows a narrow distribution with a median value of 1.51. Our results further suggest that H2O might be used as a tracer of H2 -within a factor 2.5- in the diffuse interstellar medium. We show that the measured factor of ~2.5 variation around the median is dri...

  8. Hydrogen Delivery Liquefaction and Compression

    Broader source: Energy.gov [DOE]

    Hydrogen Delivery Liquefaction and Compression - Overview of commercial hydrogen liquefaction and compression and opportunities to improve efficiencies and reduce cost.

  9. Hydrogen Permeability and Integrity of Hydrogen

    E-Print Network [OSTI]

    .G. Blencoe*, S. Babu*, and P. S. Korinko** * Oak Ridge National Laboratory * Savannah River National and Collaborators · Oak Ridge National Laboratory - Project lead · Savannah River National Laboratory - Low H2 Laboratory August 30, 2005 #12;2 OAK RIDGE NATIONAL LABORATORY U. S. DEPARTMENT OF ENERGY Partners

  10. Adaptive differentiation of H-2- and Igh-restricted B lymphocyte in tetraparental bone marrow chimera

    SciTech Connect (OSTI)

    Yamamoto, H.; Bitoh, S.; Fujimoto, S.

    1987-01-15T23:59:59.000Z

    Immunization of BALB/c mice with MOPC-104E myeloma protein induced idiotype-specific enhancing B cells that acted on anti-dextran antibody producing B cells. The enhancing cells have the surface phenotype of B cells. With the use of several H-2 or Igh congenic mice, it was found that the cooperation among B cells was controlled by both the major histocompatibility complex (MHC) and Igh. The capability to generate enhancing B cell activity was analyzed by using tetraparental bone marrow chimeras. (C57BL/6 X BALB/c)F1 mice, for example, were lethally irradiated and were reconstituted with C57BL/6 and BALB/c bone marrow cells. Nine to 12 wk after the reconstitution, the chimeras were immunized with the myeloma protein and were tested for their enhancing B cell activity. After the removal of C57BL/6 origin cells by treatment with anti-H-2b + complement, residual cells exhibited enhancing B cell activity on BALB.B, as well as BALB/c antidextran antibody response. This indicates that the generation of H-2-restricted, idiotype-specific enhancing B cell activity differentiated adaptively so as to recognize foreign MHC as self under chimeric conditions. On the other hand, splenic B cells treated with anti-H-2d + complement did not enhance the responses of BALB/c or BALB.B. Even in a chimeric environment, the B cells of C57BL/6 origin could not obtain the ability to generate enhancing B cell activity upon immunization of the idiotype. The results described here, taken in conjunction with our previous studies, suggest that the Ig heavy chain gene(s) predominantly control the Igh restriction properties of enhancing B cells, and the capability of MHC recognition by B cells is selected under chimeric conditions.

  11. ANSI X3H2-97-010 INTERNATIONAL ORGANIZATION FOR STANDARDIZATION

    E-Print Network [OSTI]

    Snodgrass, Richard T.

    IEC JTC 1 SC 21 WG 3 DBL MAD-221. 3 Melton, J. ed. SQL Temporal. July, 1996. ISO IEC JTC 1 SC 21 WG 3 Temporal. 1996. ISO IEC JTC1 SC21 WG3 DBL MAD-146r2, ANSI X3H2-96-501r2. 5 Snodgrass, R. T., M. H. Bohlen, C. S. Jensen and A. Steiner. Adding Transaction Time to SQL Temporal. 1996. ISO IEC JTC1 SC21 WG3

  12. Anti-Hydrogen Jonny Martinez

    E-Print Network [OSTI]

    Budker, Dmitry

    Anti-Hydrogen Jonny Martinez University of California, Berkeley #12;OUTLINE WHAT IS ANTI-HYDROGEN? HISTORY IMPORTANCE THEORY HOW TO MAKE ANTI-HYDROGEN OTHER ANTI-MATTER EXPERIMENTS CONCLUSION #12;WHAT IS ANTI-HYDROGEN? Anti-hydrogen is composed of a Positron(anti-electron) and anti-Proton. Anti-Hydrogen

  13. Control of Hydrogen Photoproduction by the Proton Gradient Generated by Cyclic Electron Flow in

    E-Print Network [OSTI]

    Saint-Paul-lez-Durance, France Hydrogen photoproduction by eukaryotic microalgae results from pgrl1 expression opens new perspectives toward reprogramming the cellular metabolism of microalgae for enhanced H2 production. INTRODUCTION A few microalgae species, including the model species Chlamy- domonas

  14. Performance of Sulfur Tolerant Reforming Catalysts for Production of Hydrogen from Jet Fuel Simulants

    E-Print Network [OSTI]

    Azad, Abdul-Majeed

    (SOFCs) running on jet fuel reformates for its uninhabited aerial vehicle (UAV) and low emission, military missions can be enhanced and made more effective. Reports indicate that an SOFC operating with jet of hydrogen sulfide (H2S), which poisons the anode in the fuel cell stack, leading to low SOFC efficiency

  15. Hydrogen production from cellulose in a two-stage process combining fermentation and electrohydrogenesis

    E-Print Network [OSTI]

    primarily of: acetic, lactic, succinic, and formic acids and ethanol. An additional 800 Æ 290 mL H2/gHydrogen production from cellulose in a two-stage process combining fermentation Electrolysis cell Fermentation Lignocellulose a b s t r a c t A two-stage dark-fermentation

  16. An Integrated Assessment of the Impacts of Hydrogen Economy on Transportation, Energy Use, and Air Emissions

    E-Print Network [OSTI]

    Yeh, Sonia; Loughlin, Daniel H.; Shay, Carol; Gage, Cynthia

    2007-01-01T23:59:59.000Z

    Economy on Transportation, Energy Use, and Air Emissions fossil fuel imports such as natural gas.Economy on Transportation, Energy Use, and Air Emissions penetration of H 2 -FCVs could increase the use of natural gasEconomy on Transportation, Energy Use, and Air Emissions With the most cost-effective sources of hydrogen likely to be natural gas

  17. Discovery of molecular hydrogen line emission associated with methanol maser emission

    E-Print Network [OSTI]

    Ashley, Michael C. B.

    Discovery of molecular hydrogen line emission associated with methanol maser emission J.-K. Lee March 9 A B S T R AC T We report the discovery of H2 line emission associated with 6.67-GHz methanol emission was found associated with an ultracompact H II region IRAS 14567­5846 and isolated methanol maser

  18. I. INTRODUCTION A lot of studies show that hydrogen has a high

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    to the plasma steam-reforming of various alcohols: methanol, ethanol and phenol. The plasma reactor vegetable or ethanol) H2 yields and energetic cost in function of hydrogen sources are presented. The non alcohols diluted in water have been studied in this paper: methanol, ethanol and phenol. The mole fractions

  19. An Assessment of the Near-Term Costs of Hydrogen Refueling Stations and Station Components

    E-Print Network [OSTI]

    Weinert, Jonathan X.; Lipman, Timothy

    2006-01-01T23:59:59.000Z

    station. H2Gen’s estimates for capital costs are also lowerestimates and show high variability (26%-117% of capital costs).capital costs of about $250,000. Existing hydrogen station cost analyses tend to under-estimate

  20. NREL's Hydrogen-Powered Bus Serves as Showcase for Advanced Vehicle Technologies (AVT) (Brochure)

    SciTech Connect (OSTI)

    Not Available

    2010-08-01T23:59:59.000Z

    Brochure describes the hydrogen-powered internal combustion engine (H2ICE) shuttle bus at NREL. The U.S. Department of Energy (DOE) is funding the lease of the bus from Ford to demonstrate market-ready advanced technology vehicles to visitors at NREL.